Powered by Deep Web Technologies
Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

VARIOUS APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY  

E-Print Network [OSTI]

APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPYthe Zeeman effect to atomic absorption spectroscopy has beenthe Zeeman effect on atomic absorption spectrometry has been

Koizumi, Hideaki

2011-01-01T23:59:59.000Z

2

Self-corrected Sensors Based On Atomic Absorption Spectroscopy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy. Self-corrected Sensors Based On Atomic Absorption Spectroscopy For...

3

SPECIES DETERMINATION OF ORGANOMETALLIC COMPOUNDS USING ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY WITH LIQUID CHROMATOGRAPHY  

E-Print Network [OSTI]

Compounds Using Zeeman Atomic Absorption Spectroscopy WithCompounds Using Zeeman ,Atomic Absorption Spectroscopy withcapabilities of Zeeman atomic absorption spectroscopy (ZAA)

Koizumi, H.

2011-01-01T23:59:59.000Z

4

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

Isotope Zeeman Atomic Absorption; A new approach to chemical6782 Use of Zeeman Atomic Absorption Spectroscopy for theb:l r I USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE

Girvin, D.G.

2011-01-01T23:59:59.000Z

5

Atomic flux measurement by diode-laser-based atomic absorption spectroscopy  

E-Print Network [OSTI]

Atomic flux measurement by diode-laser-based atomic absorption spectroscopy Weizhi Wang,a) R. H, California 94305 Received 5 May 1999; accepted 6 June 1999 Diode-laser-based atomic absorption AA sensors- quirements, and only the QCM measures the flux. Lamp- based atomic absorption AA sensors have been success

Fejer, Martin M.

6

Transient x-ray absorption spectroscopy of hydrated halogen atom  

E-Print Network [OSTI]

Time-resolved x-ray absorption spectroscopy has been used to observe the transient species generated by one-photon detachment of an electron from aqueous bromide. The K-edge spectrum of the short-lived Br(0) atom exhibits a resonant 1s-4p transition...

Elles, Christopher G.; Shkrob, Ilya A.; Crowell, Robert A.; Arms, Dohn A.; Landahl, Eric C.

2008-02-11T23:59:59.000Z

7

Determination of Tellurium by Atomic-absorption Spectroscopy with Electrothermal Atomisation  

E-Print Network [OSTI]

305 Determination of Tellurium by Atomic-absorption Spectroscopy with Electrothermal Atomisation at sub-microgram levels by atomic-absorption spectroscopy ,,'ith electrothermal atomisation after the e generation -atomic-absorption spectroscopy. The prior con- version of tellurium into hydrogen telluride

Canberra, University of

8

Determination of lead in gasoline by atomic absorption spectroscopy  

Science Journals Connector (OSTI)

A procedure has been developed for the direct determination of lead in gasoline by atomic absorption spectroscopy. This procedure is rapid, does not require expensive equipment, is remarkably free from interference by other trace elements present, and allows considerable variation in the sulfur and nitrogen content of the gasoline. It compares favorably with other existing procedures for this determination, such as X-ray fluorescence, wet chemical methods, and flame photometry.

J.W. Robinson

1961-01-01T23:59:59.000Z

9

Diode-laser-based atomic absorption monitor using frequency-modulation spectroscopy for physical vapor deposition process control  

E-Print Network [OSTI]

Diode-laser-based atomic absorption monitor using frequency-modulation spectroscopy for physical, and the dynamic events occur- ring as vapors condense on a substrate. Atomic absorption AA spectroscopy also been measured by means of the Doppler frequency shifts of the atomic absorption with respect

Fejer, Martin M.

10

Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy  

SciTech Connect (OSTI)

Atom flux sensors based on atomic absorption (AA) spectroscopy are of significant interest in thin film growth as they can provide unobtrusive, element specific, real-time flux sensing and control. The ultimate sensitivity and performance of the sensors are strongly affected by the long-term and short term baseline drift. Here we demonstrate that an etalon effect resulting from temperature changes in optical viewport housings is a major source of signal instability which has not been previously considered or corrected by existing methods. We show that small temperature variations in the fused silica viewports can introduce intensity modulations of up to 1.5%, which in turn significantly deteriorate AA sensor performance. This undesirable effect can be at least partially eliminated by reducing the size of the beam and tilting the incident light beam off the viewport normal.

Du, Yingge; Chambers, Scott A.

2014-10-20T23:59:59.000Z

11

Atomic structure of machined semiconducting chips: An x-ray absorption spectroscopy study  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) has been used to examine the atomic structure of chips of germanium that were produced by single point diamond machining. It is demonstrated that although the local (nearest neighbor) atomic structure is experimentally quite similar to that of single crystal specimens information from more distant atoms indicates the presence of considerable stress. An outline of the technique is given and the strength of XAS in studying the machining process is demonstrated.

Paesler, M.; Sayers, D.

1988-12-01T23:59:59.000Z

12

Double-resonant x-ray and microwave absorption: Atomic spectroscopy of precessional orbital and spin dynamics  

E-Print Network [OSTI]

Double-resonant x-ray and microwave absorption: Atomic spectroscopy of precessional orbital of atomic species driven to ferromagnetic resonance. X-ray absorption measurements performed as a function of paramagnetic atoms can be determined by de- tecting the absorption or emission of light modulated by a MW field

Brune, Harald

13

E-Print Network 3.0 - analytical atomic spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Atomic emission spectroscopy Atomic fluorescence...

14

E-Print Network 3.0 - atomic spectroscopy technologies Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Atomic emission spectroscopy Atomic fluorescence...

15

E-Print Network 3.0 - atomic absorption spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Such powers are sufficient for laser atomic absorption spectrometry (LAAS... in graphite tube atomizers and analytical flames by wavelength modulation-laser ... Source: Ecole...

16

Self-corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy  

SciTech Connect (OSTI)

A high sensitivity atom flux sensor based on atomic absorption spectroscopy has been designed and implemented to control electron beam evaporators and effusion cells in a molecular beam epitaxy system. Using a high-resolution spectrometer and a two-dimensional charge coupled device (CCD) detector in a double-beam configuration, we employ a non-resonant line or a resonant line with lower absorbance from the same hollow cathode lamp as the reference for nearly perfect background correction and baseline drift removal. This setup also significantly shortens the warm-up time needed compared to other sensor technologies and drastically reduces the noise coming from the surrounding environment. In addition, the high-resolution spectrometer allows the most sensitive resonant line to be isolated and used to provide excellent signal-to-noise ratio.

Du, Yingge; Droubay, Timothy C.; Liyu, Andrey V.; Li, Guosheng; Chambers, Scott A.

2014-04-24T23:59:59.000Z

17

E-Print Network 3.0 - atomic spectroscopy study Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Atomic emission ... Source: Yucca Mountain Project,...

18

E-Print Network 3.0 - absorption spectroscopy measurements Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Auger electron ... Source: Yucca Mountain Project, US...

19

Harmonic wavelet analysis of modulated tunable diode laser absorption spectroscopy signals  

E-Print Network [OSTI]

of the direct absorption characteristics of atomic or molecular absorption lines. This is accomplishedHarmonic wavelet analysis of modulated tunable diode laser absorption spectroscopy signals Hong analyses of tunable diode laser absorption spectroscopy signals were performed. The absorption spectroscopy

Cheng, Harry H.

20

X-ray absorption spectroscopy  

E-Print Network [OSTI]

009-9473-8 REVIEW X-ray absorption spectroscopy Junko Yano Æand application of X-ray absorption spectroscopy, bothX-ray absorption near-edge structure (XANES) and extended X-

Yano, Junko; Yachandra, Vittal K.

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

X-ray Absorption Spectroscopy  

E-Print Network [OSTI]

type: Review X-ray Absorption Spectroscopy Junko Yano andPhotosystem II; XAS, X-ray absorption spectroscopy; EXAFS,X-ray absorption fine structure; EPR, electron paramagnetic

Yano, Junko

2010-01-01T23:59:59.000Z

22

Transient Absorption Spectroscopy with Isolated Attosecond Pulses  

E-Print Network [OSTI]

viii Attosecond transient absorption instrument. . . . . .5.2.2 AbsorptionTransient absorption spectroscopy . . . . . . . . . . . .

Bell, Marie Justine

2013-01-01T23:59:59.000Z

23

SMB, X-ray Absorption Spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Absorption Spectroscopy X-ray Absorption Spectroscopy X-ray absorption spectroscopy (XAS) is a well-established technique for simultaneous local geometric and electronic structure...

24

Hyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

the frequency of a laser with respect to an atomic spectral feature.[20] As such, saturated absorptionHyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 Broadening Mechanisms . . . . . . . . . . . . . . . . . . . . . 15 3.4 Saturated Absorption

Cronin, Alex D.

25

E-Print Network 3.0 - absorption spectroscopy techniques Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... 109 3.4 Spectroscopic Sensors Spectroscopy is the scientific study of...

26

Absorption-Line Spectroscopy of Planetary Nebulae with FUSE: Probing the Molecular, Atomic, and Ionized Gas  

E-Print Network [OSTI]

The central stars of planetary nebulae (PNe) are natural targets for FUSE due to their UV brightness. The FUSE spectra of many PNe show absorption features due to circumstellar material in species ranging from H_2 and neutrals in the photodissociation region (PDR) to ions resident in the H II region. We report results from a program designed to search for nebular components in the H_2 Lyman and Werner resonance lines that are responsible for the fluorescent excitation of H_2 in strong FUV radiation fields. Our failure to detect H_2 in absorption in several PNe with strong near-infrared H_2 emission indicates that the molecular material has an asymmetrical or clumpy distribution. We also detect enrichments in the s-process product Ge, find that Fe is not depleted into dust along at least one line of sight through a PN, and show that starlight fluorescence can affect the populations of the excited fine-structure levels of O I.

Harriet L. Dinerstein; N. C. Sterling; Charles W. Bowers

2004-10-25T23:59:59.000Z

27

A passive measurement of dissociated atom densities in atmospheric pressure air discharge plasmas using vacuum ultraviolet self-absorption spectroscopy  

SciTech Connect (OSTI)

We demonstrate a method for determining the dissociation degree of atmospheric pressure air discharges by measuring the self-absorption characteristics of vacuum ultraviolet radiation from O and N atoms in the plasma. The atom densities are determined by modeling the amount of radiation trapping present in the discharge, without the use of typical optical absorption diagnostic techniques which require external sources of probing radiation into the experiment. For an 8.0?mm spark discharge between needle electrodes at atmospheric pressure, typical peak O atom densities of 8.5?×?10{sup 17}?cm{sup ?3} and peak N atom densities of 9.9?×?10{sup 17}?cm{sup ?3} are observed within the first ?1.0?mm of plasma near the anode tip by analyzing the OI and NI transitions in the 130.0–132.0?nm band of the vacuum ultraviolet spectrum.

Laity, George [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering and Department of Physics, Texas Tech University, Lubbock, Texas 79409 (United States); Applied Science and Technology Maturation Department, Sandia National Laboratories, Albuquerque, New Mexico 87123 (United States); Fierro, Andrew; Dickens, James; Neuber, Andreas [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering and Department of Physics, Texas Tech University, Lubbock, Texas 79409 (United States); Frank, Klaus [Erlangen Centre for Astroparticle Physics, Department of Physics, Friedrich–Alexander University at Erlangen-Nürnberg, 91058 Erlangen (Germany)

2014-03-28T23:59:59.000Z

28

Laser Locking with Doppler-free Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

there are many ways to stabilize the frequency of a laser, atomic absorption lines are particularly accurate are made, it becomes possible to resolve the saturated absorption lines that correspond to specific atomic absorption spectroscopy. This affects the number of atoms in the ground state and excited state

Novikova, Irina

29

Atomic absorption spectroscopy  

Science Journals Connector (OSTI)

... is given to the relatively little used hydride technique,whereas the very important area of flameless electrothermal AAS is relegated to the chapter on "Some further techniques"; and it ...

M. A. Ford

1979-04-05T23:59:59.000Z

30

Absorption properties of identical atoms  

SciTech Connect (OSTI)

Emission rates and other optical properties of multi-particle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas. -- Highlights: •The absorption rates of a pair of identical atoms in product and (anti)symmetrized states are different. •The modifications of the optical properties are essentially determined by the overlapping between the atoms. •The absorption properties differ, in some cases, for bosons and fermions.

Sancho, Pedro, E-mail: psanchos@aemet.es

2013-09-15T23:59:59.000Z

31

X-ray Absorption Spectroscopy  

SciTech Connect (OSTI)

This review gives a brief description of the theory and application of X-ray absorption spectroscopy, both X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), especially, pertaining to photosynthesis. The advantages and limitations of the methods are discussed. Recent advances in extended EXAFS and polarized EXAFS using oriented membranes and single crystals are explained. Developments in theory in understanding the XANES spectra are described. The application of X-ray absorption spectroscopy to the study of the Mn4Ca cluster in Photosystem II is presented.

Yano, Junko; Yachandra, Vittal K.

2009-07-09T23:59:59.000Z

32

Absorption properties of identical atoms  

E-Print Network [OSTI]

Emission rates and other optical properties of multiparticle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas.

Pedro Sancho

2013-07-31T23:59:59.000Z

33

E-Print Network 3.0 - absorption spectroscopy Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

.619 nm Calculate the energy of the photon: h 1.633 aJ Absorption Spectroscopy In absorption... Atomic Spectroscopy Planck's constant: h 6.62608 10 34- joule sec: Speed of...

34

E-Print Network 3.0 - absorption spectroscopy q-xas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

.619 nm Calculate the energy of the photon: h 1.633 aJ Absorption Spectroscopy In absorption... Atomic Spectroscopy Planck's constant: h 6.62608 10 34- joule sec: Speed of...

35

E-Print Network 3.0 - atomic fluorescence spectroscopy Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

total reflectance... increasing. A partial sampling of these techniques includes: Absorption spectroscopy Atomic ... Source: Yucca Mountain Project, US EPA Collection:...

36

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network [OSTI]

2/9/07 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 9, 07] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

37

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network [OSTI]

9/6/09 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 6, 09] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

38

E-Print Network 3.0 - atomic spectroscopy programacion Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... coordinated to...

39

E-Print Network 3.0 - atomic spectroscopy sympsoium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... coordinated to...

40

Ultrafast X-ray Absorption Spectroscopy using Laser-Driven Electron X-ray Sources (LEXS)  

E-Print Network [OSTI]

: ultrafast x-rays, x-ray absorption spectroscopy, terawatt lasers, ultrafast reaction dynamics, atomic motion atomic motion by scrutinizing the changes in x- ray absorption spectra during reactions. FirstUltrafast X-ray Absorption Spectroscopy using Laser-Driven Electron X-ray Sources (LEXS) Guangjun

Guo, Ting

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Combining Feedback Absorption Spectroscopy, Amplified Resonance...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling Cummins...

42

X-ray Absorption Spectroscopy of Biologically Relevant Systems  

E-Print Network [OSTI]

308, Messer, B. M. X-ray Absorption Spectroscopy of AqueousSarcosine via X-ray Absorption Spectroscopy 5.1 Introductionwith Carboxylate by X-Ray Absorption Spectroscopy of Liquid

Uejio, Janel Sunayo

2010-01-01T23:59:59.000Z

43

3.4 Spectroscopic Sensors Spectroscopy is the scientific study of the absorption, emission, or scattering of  

E-Print Network [OSTI]

increasing. A partial sampling of these techniques includes: · Absorption spectroscopy · Atomic absorption109 3.4 Spectroscopic Sensors Spectroscopy is the scientific study of the absorption, emission, or scattering of electromagnetic radiation by atoms, molecules, ions, solids, liquids, or gases. The underlying

44

E-Print Network 3.0 - atomization atomic absorption Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic absorption Search Powered by Explorit Topic List Advanced Search Sample search results for: atomization atomic absorption Page: << < 1 2 3 4 5 > >> 1 :coherently trapped in...

45

Stark spectroscopy on rare gas atoms  

E-Print Network [OSTI]

Stark spectroscopy on rare gas atoms PROEFSCHRIFT ter verkrijging van de graad van doctor aan de-DATA LIBRARY TECHNISCHE UNIVERSITEIT EINDHOVEN Jiang, Tao Stark spectroscopy on rare gas atoms / by Tao Jiang / gasontladingen Subject headings : plasma diagnostics / Stark effect / optogalvanic spectroscopy / atomic emission

Eindhoven, Technische Universiteit

46

Atomic Spectroscopy and Separated Isotopes  

Science Journals Connector (OSTI)

The advantages in the use of separated isotopes in atomic spectroscopy for the determination of nuclear momentsI ? Q and for studies of the isotope-shift phenomena are discussed. Illustrations of spectra are given for mercury uranium and samarium. In addition a summary is given of twenty-two so-called problem nuclei i.e. those naturally occurring isotopes for which the nuclear moments are completely uncertain. Concluding remarks are made on such problems as the evaluation of the absolute magnitude of isotope shifts the role of “forbidden transitions” in isotope spectra and the potential future value of spectro-isotopic assay techniques.

J. R. McNally Jr.

1952-01-01T23:59:59.000Z

47

Methods for measurement of heterogeneous materials with laser-induced breakdown spectroscopy (LIBS)  

E-Print Network [OSTI]

2000. 15) Welz B, Atomic Absorption Spectrometry, ThirdFor elemental analyses atomic absorption spectroscopy iscommonly used (15). Atomic absorption spectroscopy works by

Effenberger, Andrew Jay

2009-01-01T23:59:59.000Z

48

Polarization-enhanced absorption spectroscopy for laser stabilization  

Science Journals Connector (OSTI)

We demonstrate a variation of pump-probe spectroscopy that is particularly useful for laser frequency stabilization. The polarization-enhanced absorption spectroscopy (POLEAS) signal...

Kunz, Paul D; Heavner, Thomas P; Jefferts, Steven R

2013-01-01T23:59:59.000Z

49

X-RAY ABSORPTION SPECTROSCOPY FOR THE CHEMICAL CHARACTERIZATION OF ATMOSPHERIC AEROSOLS  

E-Print Network [OSTI]

November 11-16 9 1979 X-RAY ABSORPTION SPECTROSCOPY FOR THEUniversity of California. ABSORPTION SPECTROSCOPY FOR THEand x-ray emission and absorption spectroscopy. The first

Jaklevic, J. M.

2011-01-01T23:59:59.000Z

50

Geek-Up[6.10.10]: Attosecond Absorption Spectroscopy and Kinked Nanopores |  

Broader source: Energy.gov (indexed) [DOE]

6.10.10]: Attosecond Absorption Spectroscopy and Kinked 6.10.10]: Attosecond Absorption Spectroscopy and Kinked Nanopores Geek-Up[6.10.10]: Attosecond Absorption Spectroscopy and Kinked Nanopores August 6, 2010 - 6:07pm Addthis A classical diagram of a krypton atom shows its 36 electrons arranged in shells. | Photo Courtesy of: Berkeley Lab. A classical diagram of a krypton atom shows its 36 electrons arranged in shells. | Photo Courtesy of: Berkeley Lab. Elizabeth Meckes Elizabeth Meckes Director of User Experience & Digital Technologies, Office of Public Affairs Thanks to the attosecond absorption spectroscopy process, an international team of scientists from Max Planck Institute of Quantum Optics (MPQ), Lawrence Berkeley National Laboratory and the University of California at Berkeley were able to observe an atom's electrons moving in real time -

51

Determination of Mercury in Soils by Flameless Atomic Absorption Spectrometry  

Science Journals Connector (OSTI)

...chemical analysis exploration flameless geochemical methods mercury...Determination of Mercury in Soils by Flameless Atomic Absorption Spectrometry...Determinationof Mercury in Soilsby Flameless Atomic AbsorptionSpectrometry...the mercuryre- RF Induction Heater work coils 1. Carriergas...

B. G. Weissberg

52

Atomic Absorption Method Guide Zn in Copper Alloys  

E-Print Network [OSTI]

Atomic Absorption Method Guide Zn in Copper Alloys Principle The sample is digested in nitric/hydrochloric acid, and zinc is determined by flame atomic absorption spectrometry using an air-acetylene flame · Copper Alloys · Zinc · Flame · Atomic Absorption Method Guide: 40158 #12;©2008 Thermo Fisher Scientific

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

53

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films  

E-Print Network [OSTI]

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic

54

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network [OSTI]

A. B. Optical System Absorption Signal C. Small SignalNoise . Sensitivity of Absorption Spectroscopy EXPERIMENTSINFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

55

Atomic Absorption Spectrometry Perkin Elmer 500, Chemistry & Biochemistry  

E-Print Network [OSTI]

Atomic Absorption Spectrometry · Perkin Elmer 500, Chemistry & Biochemistry · Perkin Elmer 560 AA-star stopped flow with absorption, fluorescence and circular dichroism detection · KinTek quench flow apparatus

Gruner, Daniel S.

56

Silicon Photonics for chemical sensing and spectroscopy, diagnosis and therapy  

E-Print Network [OSTI]

5.5. Single-shot atomic absorption spectroscopy of rubidium26] time-wavelength atomic absorption spectroscopy of the D5.5. Single-shot atomic absorption spectroscopy of rubidium

Hon, Kam Yan

2012-01-01T23:59:59.000Z

57

Spectroscopy and atomic force microscopy of biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy Spectroscopy and atomic force microscopy of biomass L. Tetard a,b , A. Passian a,b,n , R.H. Farahi a , U.C. Kalluri c , B.H. Davison c , T. Thundat a,b a Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA b Department of Physics, University of Tennessee, Knoxville, TN 37996, USA c Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA a r t i c l e i n f o Keywords: Atomic force microscopy Spectroscopy Plant cells Biomass Nanomechanics a b s t r a c t Scanning probe microscopy has emerged as a powerful approach to a broader understanding of the molecular architecture of cell walls, which may shed light on the challenge of efficient cellulosic ethanol production. We have obtained preliminary images of both Populus and switchgrass samples using atomic force microscopy (AFM). The results show distinctive features that are shared by switchgrass

58

Relativistic atomic beam spectroscopy II  

SciTech Connect (OSTI)

The negative ion of H is one of the simplest 3-body atomic systems. The techniques we have developed for experimental study of atoms moving near speed of light have been productive. This proposal request continuing support for experimental studies of the H{sup -} system, principally at the 800 MeV linear accelerator (LAMPF) at Los Alamos. Four experiments are currently planned: photodetachment of H{sup -} near threshold in electric field, interaction of relativistic H{sup -} ions with matter, high excitations and double charge escape in H{sup -}, and multiphoton detachment of electrons from H{sup -}.

NONE

1989-12-31T23:59:59.000Z

59

Collection of atomic mercury by electrostatic precipitators  

Science Journals Connector (OSTI)

... Flameless atomic absorption spectroscopy was used to measure the difference in the mercury concentration of gas ...

O. M. G. NEWMAN; D. J. PALMER

1978-10-12T23:59:59.000Z

60

Direct and quantitative absorptive spectroscopy of nanowires  

E-Print Network [OSTI]

Photonic nanostructures exhibit unique optical properties that are attractive in many different applications. However, measuring the optical properties of individual nanostructures, in particular the absorptive properties, ...

Tong, Jonathan Kien-Kwok

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Multiplexed absorption tomography with calibration-free wavelength modulation spectroscopy  

SciTech Connect (OSTI)

We propose a multiplexed absorption tomography technique, which uses calibration-free wavelength modulation spectroscopy with tunable semiconductor lasers for the simultaneous imaging of temperature and species concentration in harsh combustion environments. Compared with the commonly used direct absorption spectroscopy (DAS) counterpart, the present variant enjoys better signal-to-noise ratios and requires no baseline fitting, a particularly desirable feature for high-pressure applications, where adjacent absorption features overlap and interfere severely. We present proof-of-concept numerical demonstrations of the technique using realistic phantom models of harsh combustion environments and prove that the proposed techniques outperform currently available tomography techniques based on DAS.

Cai, Weiwei; Kaminski, Clemens F., E-mail: cfk23@cam.ac.uk [Department of Chemical Engineering and Biotechnology, University of Cambridge, Cambridge CB2 3RA (United Kingdom)

2014-04-14T23:59:59.000Z

62

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Title X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Publication Type Journal Article LBNL Report Number LBNL-50574 Year of Publication 2002 Authors Richardson, Thomas J., Baker Farangis, Jonathan L. Slack, Ponnusamy Nachimuthu, Rupert C. C. Perera, Nobumichi Tamura, and Michael D. Rubin Journal Journal of Alloys and Compounds Volume 356-357 Start Page 204 Pagination 204-207 Date Published 08/2003 Keywords A. hydrogen storage materials, NEXAFS, thin film s; C. EXAFS, x-ray diffraction Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption spectroscopy. Mg K-edge and Ni, Co, and Ti L-edge spectra reflect both reversible and irreversible changes in the metal environments. A significant shift in the nickel L absorption edge shows it to be an active participant in hydride formation. The effect on cobalt and titanium is much less dramatic, suggesting that these metals act primarily as catalysts for formation of magnesium hydride.

63

X-ray Absorption Spectroscopy Study of Prototype Chemical Systems: Theory vs. Experiment  

E-Print Network [OSTI]

acids by Near Edge X-ray Absorption Fine Structure (NEXAFS)X-ray Absorption Spectroscopy Study of Prototype ChemicalGlaeser Spring 2010 X-ray Absorption Spectroscopy Study of

Schwartz, Craig Philip

2010-01-01T23:59:59.000Z

64

X-ray absorption spectroscopy at the Ni-K edge in Stackhousia tryonii Bailey hyperaccumulator  

E-Print Network [OSTI]

X-ray absorption spectroscopy at the Ni–K edge inin vivo by micro x-ray absorption spectroscopy (XAS) at theNi–K edge. Both x-ray absorption near edge structure and

Kachenko, A.

2009-01-01T23:59:59.000Z

65

Atomic and Molecular Absorption at High Redshift  

E-Print Network [OSTI]

Strong constraints on possible variations in fundamental constants can be derived from HI 21-cm and molecular rotational absorption lines observed towards quasars. With the aim of forming a statistical sample of constraints we have begun a program of systematic searches for such absorption systems. Here we describe molecular rotational searches in 25 damped Lyman-alpha systems where, in many cases, we set optical depth limits an order of magnitude better than that required to detect the 4 known redshifted millimeter-wave absorbers. We also discuss the contributory factors in the detectability of HI 21-cm absorption, focusing on possible biases (e.g.low covering factors) in the currently known sample of absorbers and non-detections.

S. J. Curran; J. K. Webb; M. T. Murphy; Y. M. Pihlström

2004-05-14T23:59:59.000Z

66

Absolute absorption spectroscopy based on molecule interferometry  

E-Print Network [OSTI]

We propose a new method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photo-induced fragmentation or ionization. The method is based on resolving the recoil resulting from photon absorption by means of near-field matter-wave interference, and it thus applies even to very dilute beams with low optical densities. Our discussion includes the possibility of internal state conversion as well as fluorescence. We assess the influence of various experimental uncertainties and show that the measurement of absolute absorption cross sections is conceivable with high precision and using existing technologies.

Stefan Nimmrichter; Klaus Hornberger; Hendrik Ulbricht; Markus Arndt

2008-11-07T23:59:59.000Z

67

Neutrino Spectroscopy with Atoms and Molecules  

E-Print Network [OSTI]

We give a comprehensive account of our proposed experimental method of using atoms or molecules in order to measure parameters of neutrinos still undetermined; the absolute mass scale, the mass hierarchy pattern (normal or inverted), the neutrino mass type (Majorana or Dirac), and the CP violating phases including Majorana phases. There are advantages of atomic targets, due to the closeness of available atomic energies to anticipated neutrino masses, over nuclear target experiments. Disadvantage of using atomic targets, the smallness of rates, is overcome by the macro-coherent amplification mechanism. The atomic or molecular process we use is a cooperative deexcitation of a collective body of atoms in a metastable level |e> emitting a neutrino pair and a photon; |e> -> |g> + gamma + nu_i nu_j where nu_i's are neutrino mass eigenstates. The macro-coherence is developed by trigger laser irradiation. We discuss aspects of the macro-coherence development by setting up the master equation for the target quantum state and propagating electric field. With a choice of heavy target atom or molecule such as Xe or I_2 that has a large M1 x E1 matrix element between |e> and |g>, we show that one can determine three neutrino masses along with the mass hierarchy pattern by measuring the photon spectral shape. If one uses a target of available energy of a fraction of 1 eV, Majorana CP phases may be determined. Our master equation, when applied to E1 x E1 transition such as pH_2 vibrational transition Xv=1 -> 0, can describe explosive PSR events in which most of the energy stored in |e> is released within a few nanoseconds. The present paper is intended to be self-contained explaining some details related theoretical works in the past, and further reports new simulations and our ongoing experimental efforts of the project to realize the neutrino mass spectroscopy using atoms/molecules.

Atsushi Fukumi; Susumu Kuma; Yuki Miyamoto; Kyo Nakajima; Itsuo Nakano; Hajime Nanjo; Chiaki Ohae; Noboru Sasao; Minoru Tanaka; Takashi Taniguchi; Satoshi Uetake; Tomonari Wakabayashi; Takuya Yamaguchi; Akihiro Yoshimi; Motohiko Yoshimura

2012-11-21T23:59:59.000Z

68

Cavity-induced two-photon absorption in unidentical atoms M. S. Kim1,  

E-Print Network [OSTI]

Cavity-induced two-photon absorption in unidentical atoms M. S. Kim1, * and G. S. Agarwal1,2 1 Max-photon absorption in unidentical atoms, and demonstrate the nonclassical character of this two-photon absorption. We-photon absorption in two unidentical atoms in a cavity. In a cavity the atoms interact with a common quantized

Kim, Myungshik

69

E-Print Network 3.0 - atomic absorption method Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

method Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption method...

70

E-Print Network 3.0 - atomic absorption spectrometr Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectrometr Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometr...

71

E-Print Network 3.0 - atomic absorption spectrometric Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectrometric Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometric...

72

E-Print Network 3.0 - atomic absorption methods Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

methods Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption methods...

73

Optical Spectroscopy of Hydrogenic Atoms MIT Department of Physics  

E-Print Network [OSTI]

Optical Spectroscopy of Hydrogenic Atoms MIT Department of Physics (Dated: September 1, 2013) This experiment is an exercise in optical spectroscopy in a study of the spectra of "hydrogenic" atoms, i.e. atoms with one "optical" electron outside a closed shell of other electrons. Measurements include finding

Seager, Sara

74

Molecular shock response of explosives: electronic absorption spectroscopy  

SciTech Connect (OSTI)

Electronic absorption spectroscopy in the range 400-800 nm was coupled to ultrafast laser generated shocks to begin addressing the question of the extent to which electronic excitations are involved in shock induced reactions. Data are presented on shocked polymethylmethacrylate (PMMA) thin films and single crystal pentaerythritol tetranitrate (PETN). Shocked PMMA exhibited thin film interference effects from the shock front. Shocked PETN exhibited interference from the shock front as well as broadband increased absorption. Relation to shock initiation hypotheses and the need for time dependent absorption data (future experiments) is briefly discussed.

Mcgrne, Shawn D [Los Alamos National Laboratory; Moore, David S [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Bolme, Cindy A [Los Alamos National Laboratory; Eakins, Daniel E [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

75

Quantized Media with Absorptive Scatterers and Modified Atomic Emission Rates  

E-Print Network [OSTI]

Modifications in the spontaneous emission rate of an excited atom that are caused by extinction effects in a nearby dielectric medium are analyzed in a quantummechanical model, in which the medium consists of spherical scatterers with absorptive properties. Use of the dyadic Green function of the electromagnetic field near a a dielectric sphere leads to an expression for the change in the emission rate as a series of multipole contributions for which analytical formulas are obtained. The results for the modified emission rate as a function of the distance between the excited atom and the dielectric medium show the influence of both absorption and scattering processes.

L. G. Suttorp; A. J. van Wonderen

2011-02-14T23:59:59.000Z

76

Absorption spectroscopy of individual single-walled carbon nanotubes  

E-Print Network [OSTI]

Absorption spectroscopy of individual single-walled carbon nanotubes Stéphane Berciaud,a Laurent-walled carbon nanotubes (SWNTs) lead to heterogeneous samples containing mixtures of metallic and semiconducting species with a variety of lengths and defects. Optical detection at the single nanotube level should thus

Boyer, Edmond

77

Laser photothermal spectroscopy of light-induced absorption  

SciTech Connect (OSTI)

Basic methods of laser photothermal spectroscopy, which are used to study photoinduced absorption in various media, are briefly considered. Comparative analysis of these methods is performed and the latest results obtained in this field are discussed. Different schemes and examples of their practical implementation are considered. (review)

Skvortsov, L A [Institute of Cryptography, Communications and Informatics, Moscow (Russian Federation)

2013-01-31T23:59:59.000Z

78

Heralded single photon absorption by a single atom  

E-Print Network [OSTI]

The emission and absorption of single photons by single atomic particles is a fundamental limit of matter-light interaction, manifesting its quantum mechanical nature. At the same time, as a controlled process it is a key enabling tool for quantum technologies, such as quantum optical information technology [1, 2] and quantum metrology [3, 4, 5, 6]. Controlling both emission and absorption will allow implementing quantum networking scenarios [1, 7, 8, 9], where photonic communication of quantum information is interfaced with its local processing in atoms. In studies of single-photon emission, recent progress includes control of the shape, bandwidth, frequency, and polarization of single-photon sources [10, 11, 12, 13, 14, 15, 16, 17], and the demonstration of atom-photon entanglement [18, 19, 20]. Controlled absorption of a single photon by a single atom is much less investigated; proposals exist but only very preliminary steps have been taken experimentally such as detecting the attenuation and phase shift of a weak laser beam by a single atom [21, 22], and designing an optical system that covers a large fraction of the full solid angle [23, 24, 25]. Here we report the interaction of single heralded photons with a single trapped atom. We find strong correlations of the detection of a heralding photon with a change in the quantum state of the atom marking absorption of the quantum-correlated heralded photon. In coupling a single absorber with a quantum light source, our experiment demonstrates previously unexplored matter-light interaction, while opening up new avenues towards photon-atom entanglement conversion in quantum technology.

Nicolas Piro; Felix Rohde; Carsten Schuck; Marc Almendros; Jan Huwer; Joyee Ghosh; Albrecht Haase; Markus Hennrich; Francois Dubin; Jürgen Eschner

2010-04-23T23:59:59.000Z

79

Dual structure of saturated absorption resonance at an open atomic transition  

SciTech Connect (OSTI)

Experiments on open transitions of the D{sub 1} line of alkali metals (Cs and Rb isotopes) reveal the dual structure of saturated absorption resonance in the signal of a high-intensity optical wave in the presence of a low-intensity counterpropagating wave. Theoretical analysis shows that the observed shape of the resonance is associated with the openness of the atomic transition as well as with the Doppler effect for atoms in a gas. The results are of general physical significance for nonlinear spectroscopy and can also find application in metrology (frequency and time standards on open transitions).

Vasil'ev, V. V., E-mail: vlvlab@okb.lpi.troitsk.ru; Velichanskii, V. L., E-mail: vlvlab@okb.lpi.troitsk.ru; Zibrov, S. A., E-mail: vlvlab@okb.lpi.troitsk.ru [Russian Academy of Sciences, Lebedev Physical Institute (Russian Federation); Sivak, A. V., E-mail: vlvlab@okb.lpi.troitsk.ru [National Research Nuclear University (Moscow Institute of Engineering Physics) (Russian Federation); Brazhnikov, D. V., E-mail: LLF@laser.nsc.ru; Taichenachev, A. V., E-mail: LLF@laser.nsc.ru; Yudin, V. I., E-mail: LLF@laser.nsc.ru [Russian Academy of Sciences, Institute of Laser Physics, Siberian Branch (Russian Federation)

2011-05-15T23:59:59.000Z

80

INFRARED ABSORPTION SPECTROSCOPY AND CHEMICAL KINETICS OF FREE RADICALS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mNAL PERFORMANCE REPORT mNAL PERFORMANCE REPORT for INFRARED ABSORPTION SPECTROSCOPY AND CHEMICAL KINETICS OF FREE RADICALS DE-FG05-85ER13439 1-AUG-1985 to 31-JUL-1994 Robert F. Curl and Graham P. Glass Principal Investigators Introduction This research was directed at the detection, monitoring, and study (by infrared absorption spectroscopy) of the chemical kinetic behavior of small free radical species thought to be important intermediates in combustion. The work typically progressed from the detection and analysis of the infrared spectrum of combustion radical to the utilization of the infrared spectrum thus obtained in the investigation of chemical kinetics of the radical species. The methodology employed was infrared kinetic spectroscopy. In this technique the radical is produced by UV flash photolysis using an excimer laser and then

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

E-Print Network 3.0 - absorption spectroscopies progress Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nanoantenna arrays Summary: absorption (SEIRA) spectroscopy (7-14). Until recently, the bulk of SEIRA studies have revolved around... collectively en- hanced IR absorption...

82

Absorption spectrum of Ca atoms attached to $^4$He nanodroplets  

E-Print Network [OSTI]

Within density functional theory, we have obtained the structure of $^4$He droplets doped with neutral calcium atoms. These results have been used, in conjunction with newly determined {\\it ab-initio} $^1\\Sigma$ and $^1\\Pi$ Ca-He pair potentials, to address the $4s4p$ $^1$P$_1 \\leftarrow 4s^2$ $^1$S$_0$ transition of the attached Ca atom, finding a fairly good agreement with absorption experimental data. We have studied the drop structure as a function of the position of the Ca atom with respect of the center of mass of the helium moiety. The interplay between the density oscillations arising from the helium intrinsic structure and the density oscillations produced by the impurity in its neighborhood plays a role in the determination of the equilibrium state, and hence in the solvation properties of alkaline earth atoms. In a case of study, the thermal motion of the impurity within the drop surface region has been analyzed in a semi-quantitative way. We have found that, although the atomic shift shows a sizeable dependence on the impurity location, the thermal effect is statistically small, contributing by about a 10% to the line broadening. The structure of vortices attached to the calcium atom has been also addressed, and its effect on the calcium absorption spectrum discussed. At variance with previous theoretical predictions, we conclude that spectroscopic experiments on Ca atoms attached to $^4$He drops will be likely unable to detect the presence of quantized vortices in helium nanodrops.

Alberto Hernando; Manuel Barranco; Marek Kro?nicki; Ricardo Mayol; Martí Pi

2007-11-12T23:59:59.000Z

83

E-Print Network 3.0 - atomic absorption technique Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption technique Page: << < 1 2 3 4 5 > >> 1 Xray Absorption Near Edge...

84

E-Print Network 3.0 - atomic absorption determination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption determination Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine...

85

Infrared absorption spectroscopy and chemical kinetics of free radicals  

SciTech Connect (OSTI)

This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

Curl, R.F.; Glass, G.P. [Rice Univ., Houston, TX (United States)

1993-12-01T23:59:59.000Z

86

X-RAY ABSORPTION SPECTROSCOPY OF TRANSITION METAL-MAGNESIUM HYDRIDE FILMS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy of Transition Metal-Magnesium Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardson a, *, B. Farangis a , J. L. Slack a , P. Nachimuthu b , R. Pereira b , N. Tamura b , and M. Rubin a a Environmental Energy Technologies Division, b Advanced Light Source, Ernest Orlando Lawrence Berkeley National Laboratory Berkeley, California 94720, USA *Corresponding author, E-mail address: tjrichardson@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption

87

AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS  

E-Print Network [OSTI]

II. Extended X-ray Absorption Fine Structure (EXAFS) TheoryIII. X-ray Absorption Spectroscopy (XAS) ExperimentIII. EXTENDED X-RAY ABSORPTION FINE STRUCTURE (EXAFS) DATA

Kirby, Jon Allan

2012-01-01T23:59:59.000Z

88

Single-Photon Absorption in Coupled Atom-Cavity Systems  

E-Print Network [OSTI]

We show how to capture a single photon of arbitrary temporal shape with one atom coupled to an optical cavity. Our model applies to Raman transitions in three-level atoms with one branch of the transition controlled by a (classical) laser pulse, and the other coupled to the cavity. Photons impinging on the cavity normally exhibit partial reflection, transmission, and/or absorption by the atom. Only a control pulse of suitable temporal shape ensures impedance matching throughout the pulse, which is necessary for complete state mapping from photon to atom. For most possible photon shapes, we derive an unambiguous analytic expression for the shape of this control pulse, and we discuss how this relates to a quantum memory.

Jerome Dilley; Peter Nisbet-Jones; Bruce W. Shore; Axel Kuhn

2012-03-01T23:59:59.000Z

89

Model for verification of measurement results in electrothermal atomic absorption spectrometry  

Science Journals Connector (OSTI)

We present a practical application of a phenomenological model for physicochemical atomization processes in determining heavy metal content by electrothermal atomic absorption spectrometry. Comparison of the a...

V. Yu. Ilyashenko; Yu. V. Rogulsky; A. N. Kulik

2011-03-01T23:59:59.000Z

90

A survey for redshifted molecular and atomic absorption lines I  

E-Print Network [OSTI]

We are currently undertaking a large survey for redshifted atomic and molecular absorption ... only one clear and one tentative detection were obtained: HI absorption at z = 0.097 in PKS 1555-140 and OH absorption at z =0.126 in PKS 2300-189, respectively... In order to determine why no clear molecular absorption was detected in any of the 13 sources searched, we investigate the properties of the five redshifted systems currently known to exhibit OH absorption. In four of these, molecules were first detected via millimetre-wave transitions and the flat radio spectra indicate compact background continuum sources, which may suggest a high degree of coverage of the background source by the molecular clouds in the absorber. Furthermore, for these systems we find a relationship between the molecular line strength and red optical--near infrared (V-K) colours, thus supporting the notion that the reddening of these sources is due to dust, which provides an environment conducive to the formation of molecules. Upon comparison with the V-K colours of our sample, this relationship suggests that, presuming the reddening occurs at the host galaxy redshift at least in some of the targets, many of our observations still fall short of the sensitivityrequired to detect OH absorption, although a confirmation of the ``detection'' of OH in 2300-189 could contravene this.

S. J. Curran; M. T. Whiting; M. T. Murphy; J. K. Webb; S. N. Longmore; Y. M. Pihlstroem; R. Athreya; C. Blake

2006-07-26T23:59:59.000Z

91

Non-coincident multi-wavelength emission absorption spectroscopy  

SciTech Connect (OSTI)

An analysis is presented of the effect of noncoincident sampling on the measurement of atomic number density and temperature by multiwavelength emission absorption. The assumption is made that the two signals, emission and transmitted lamp, are time resolved but not coincident. The analysis demonstrates the validity of averages of such measurements despite fluctuations in temperature and optical depth. At potassium-seeded MHD conditions, the fluctuations introduce additional uncertainty into measurements of potassium atom number density and temperature but do not significantly bias the average results. Experimental measurements in the CFFF aerodynamic duct with coincident and noncoincident sampling support the analysis.

Baumann, L.E.

1995-02-01T23:59:59.000Z

92

Absorption by cold Fermi atoms in a harmonic trap  

E-Print Network [OSTI]

We study the absorption spectrum for a strongly degenerate Fermi gas confined in a harmonic trap. The spectrum is calculated using both the exact summation and also the Thomas-Fermi (TF) approximation. In the latter case, relatively simple analytical expressions are obtained for the absorption lineshape at large number of trapped atoms. At zero temperature, the approximated lineshape is characterized by a $(1-z^2)^{5/2}$ dependence which agrees well with the exact numerical calculations. At non-zero temperature, the spectrum becomes broader, although remains non-Gaussian as long as the fermion gas is degenerate. The changes in the trap frequency for an electronically excited atom can introduce an additional line broadening.

Gediminas Juzeliunas; Marius Masalas

2000-11-10T23:59:59.000Z

93

E-Print Network 3.0 - active potassium absorption Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

decomposed in a heated carbon-tube furnace, and arsenic determined by measurement of its atomic-absorption... in its determination by atomic- absorption spectroscopy. Various...

94

E-Print Network 3.0 - atomic force spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Langmuir trough Atomic force microscope Optical microscope... W ultrasonic horn Atomic absorption spectrophotometer UVVIS spectrophotometer Centrifuge p......

95

PHYSICAL REVIEW A 88, 043428 (2013) Transient absorption spectra of the laser-dressed hydrogen atom  

E-Print Network [OSTI]

PHYSICAL REVIEW A 88, 043428 (2013) Transient absorption spectra of the laser-dressed hydrogen atom.043428 PACS number(s): 32.80.Rm, 42.65.Ky I. INTRODUCTION Transient absorption spectra of laser-dressed atoms absorption spectra of hydrogen atoms based on numerical solutions of the time-dependent Schr¨odinger equation

Chu, Shih-I

96

ABSORPTION ET DIFFUSION DE PHOTONS OPTIQUES PAR UN ATOME EN INTERACTION AVEC DES PHOTONS DE RADIOFRQUENCE  

E-Print Network [OSTI]

153. ABSORPTION ET DIFFUSION DE PHOTONS OPTIQUES PAR UN ATOME EN INTERACTION AVEC DES PHOTONS DE'annuler. Ceci modifie de façon importante le spectre d'absorption de l'atome « habillé» en champ faible et l of the absorption spectrum of the "dressed" atom in a weak magnetic field and of the magnetic depolarization effect

Paris-Sud XI, Université de

97

FINGERPRINTING INORGANIC ARSENIC AND ORGANOARSENIC COMPOUNDS IN IN SITU OIL SHALE RETORT AND PROCESS VOTERS USING A LIQUID CHROMATOGRAPH COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR  

E-Print Network [OSTI]

COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTORCoupled with an Atomic Absorption Spectrometer as a DetectorcOUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR

Fish, Richard H.

2013-01-01T23:59:59.000Z

98

Emission and Absorption Spectroscopy of Carbon Arc Plasma during Formation of Carbon Magnetic Encapsulates  

SciTech Connect (OSTI)

Plasma diagnostics of carbon arc discharge under conditions of carbon magnetic encapsulates formation was performed by emission and absorption spectroscopy. Content of C{sub 2} and Fe species, rotational temperatures of excited (d {sup 3} product {sub g}) and non-excited (a {sup 3} product {sub u}) states, and excitation temperatures of a {sup 5}F and a {sup 3}F levels relatively to the a {sup 5}D level of Fe atoms were determined. The results pointed to a non-equilibrium state of carbon arc plasma under prevailing discharge conditions.

Lange, H.; Labedz, O.; Huczko, A.; Bystrzejewski, M. [Faculty of Chemistry, Warsaw University, Pasteur str. 1,02-093 Warsaw (Poland)

2011-11-29T23:59:59.000Z

99

Spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy Spectroscopy Spectroscopy Print In spectroscopy experiments, a sample is illuminated with light and the various product particles (electrons, ions, or fluorescent photons) are detected and analyzed.The unifying feature is that some "property" of a material is measured as the x-ray (photon) energy is swept though a range of values. At the most basic level, one measures the absorption, transmission, or reflectivity of a sample as a function of photon energy. Probes that use the vacuum ultraviolet (VUV) region of the spectrum (10-100 eV) are very well matched to the elucidation of bonding in solids, surfaces, and molecules; to the investigation of electron-electron correlations in solids, atoms, and ions; and to the study of reaction pathways in chemical dynamics. At the lowest end of this energy range (below 1 eV) we have infrared, far-infrared, and terahertz spectroscopies, which are well matched to vibrational modes and other modes of excitation.

100

Optical Absorption and Photoluminescence Excitation Spectroscopy of SWNTs S. Maruyama1  

E-Print Network [OSTI]

Optical Absorption and Photoluminescence Excitation Spectroscopy of SWNTs S. Maruyama1 , Y-mail: maruyama@photon.t.u-tokyo.ac.jp Optical absorption and photoluminescence excitation (PLE) spectroscopy to the physical interest in unique excitonic features of 1-D material [3-5], clear identification of absorption

Maruyama, Shigeo

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Absorption and photoluminescence spectroscopy on a single self-assembled charge-tunable quantum dot  

E-Print Network [OSTI]

Absorption and photoluminescence spectroscopy on a single self-assembled charge-tunable quantum dot PL and absorption spectroscopy on the same single self- assembled quantum dot in a charge the corresponding transition in absorption. We have developed a model of the Coulomb blockade to account

Ludwig-Maximilians-Universität, München

102

Absorption spectroscopy of a laboratory photoionized plasma experiment at Z  

SciTech Connect (OSTI)

The Z facility at the Sandia National Laboratories is the most energetic terrestrial source of X-rays and provides an opportunity to produce photoionized plasmas in a relatively well characterised radiation environment. We use detailed atomic-kinetic and spectral simulations to analyze the absorption spectra of a photoionized neon plasma driven by the x-ray flux from a z-pinch. The broadband x-ray flux both photoionizes and backlights the plasma. In particular, we focus on extracting the charge state distribution of the plasma and the characteristics of the radiation field driving the plasma in order to estimate the ionisation parameter.

Hall, I. M.; Durmaz, T.; Mancini, R. C. [Physics Department, University of Nevada, Reno, Nevada 89557 (United States)] [Physics Department, University of Nevada, Reno, Nevada 89557 (United States); Bailey, J. E.; Rochau, G. A. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)] [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); Golovkin, I. E.; MacFarlane, J. J. [Prism Computational Sciences, Madison, Wisconsin 53711 (United States)] [Prism Computational Sciences, Madison, Wisconsin 53711 (United States)

2014-03-15T23:59:59.000Z

103

Ge doped HfO{sub 2} thin films investigated by x-ray absorption spectroscopy  

SciTech Connect (OSTI)

The stability of the tetragonal phase of Ge doped HfO{sub 2} thin films on Si(100) was investigated. Hf(Ge)O{sub 2} films with Ge atomic concentrations varying from 0% to 15% were deposited by remote plasma chemical vapor deposition. The atomic structure on the oxide after rapid thermal annealing was investigated by x-ray absorption spectroscopy of the O and Ge K edges and by Rutherford backscattering spectrometry. The authors found that Ge concentrations as low as 5 at. % effectively stabilize the tetragonal phase of 5 nm thick Hf(Ge)O{sub 2} on Si and that higher concentrations are not stable to rapid thermal annealing at temperatures above 750 deg. C.

Miotti, Leonardo; Bastos, Karen P.; Lucovsky, Gerald; Radtke, Claudio; Nordlund, Dennis [Department of Physics, North Carolina State University, Box 8202, Raleigh, North Carolina 27695-8202 (United States); Instituto de Quimica, Universidade Federal do Rio Grande do Sul, 91509-900 Porto Alegre (Brazil); Stanford Synchrotron Radiation Lightsource, Menlo Park, California 94025 (United States)

2010-07-15T23:59:59.000Z

104

Direct atomic flux measurement of electron-beam evaporated yttrium with a diode-laser-based atomic absorption monitor at 668 nm  

E-Print Network [OSTI]

with a diode-laser-based atomic absorption AA monitor at 668 nm. Atomic number density and velocity were measured through absorption and Doppler shift measurements to provide the atomic flux. The AA previously developed diode-laser-based atomic absorption AA monitors for atomic density measurements

Fejer, Martin M.

105

E-Print Network 3.0 - absorption gamma-ray spectroscopy Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: absorption gamma-ray spectroscopy Page: << < 1 2 3 4 5 > >> 1 1090 IEEE TRANSACTIONS ON NUCLEAR SCIENCE,...

106

The Use of UV–Vis Absorption Spectroscopy for Studies of Natively Disordered Proteins  

Science Journals Connector (OSTI)

Absorption spectroscopy can be used to monitor structural changes upon transitions from ordered to disordered state in proteins. Changes in environment of tryptophan, tyrosine,...

Eugene A. Permyakov

2012-01-01T23:59:59.000Z

107

E-Print Network 3.0 - absorption spectroscopy principles Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas analysis Alexander Fateev, Snnik Clausen Summary: applications and in particular in atomicmolecular absorption spectroscopy, the transition moment is replaced... +CO+CO2)....

108

E-Print Network 3.0 - absorption spectroscopy establishes Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas analysis Alexander Fateev, Snnik Clausen Summary: applications and in particular in atomicmolecular absorption spectroscopy, the transition moment is replaced... +CO+CO2)....

109

Spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy Print Spectroscopy Print In spectroscopy experiments, a sample is illuminated with light and the various product particles (electrons, ions, or fluorescent photons) are detected and analyzed.The unifying feature is that some "property" of a material is measured as the x-ray (photon) energy is swept though a range of values. At the most basic level, one measures the absorption, transmission, or reflectivity of a sample as a function of photon energy. Probes that use the vacuum ultraviolet (VUV) region of the spectrum (10-100 eV) are very well matched to the elucidation of bonding in solids, surfaces, and molecules; to the investigation of electron-electron correlations in solids, atoms, and ions; and to the study of reaction pathways in chemical dynamics. At the lowest end of this energy range (below 1 eV) we have infrared, far-infrared, and terahertz spectroscopies, which are well matched to vibrational modes and other modes of excitation.

110

Spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy Print Spectroscopy Print In spectroscopy experiments, a sample is illuminated with light and the various product particles (electrons, ions, or fluorescent photons) are detected and analyzed.The unifying feature is that some "property" of a material is measured as the x-ray (photon) energy is swept though a range of values. At the most basic level, one measures the absorption, transmission, or reflectivity of a sample as a function of photon energy. Probes that use the vacuum ultraviolet (VUV) region of the spectrum (10-100 eV) are very well matched to the elucidation of bonding in solids, surfaces, and molecules; to the investigation of electron-electron correlations in solids, atoms, and ions; and to the study of reaction pathways in chemical dynamics. At the lowest end of this energy range (below 1 eV) we have infrared, far-infrared, and terahertz spectroscopies, which are well matched to vibrational modes and other modes of excitation.

111

Observables in Neutrino Mass Spectroscopy Using Atoms  

E-Print Network [OSTI]

The process of collective de-excitation of atoms in a metastable level into emission mode of a single photon plus a neutrino pair, called radiative emission of neutrino pair (RENP), is sensitive to the absolute neutrino mass scale, to the neutrino mass hierarchy and to the nature (Dirac or Majorana) of massive neutrinos. We investigate how the indicated neutrino mass and mixing observables can be determined from the measurement of the corresponding continuous photon spectrum taking the example of a transition between specific levels of the Yb atom. The possibility of determining the nature of massive neutrinos and, if neutrinos are Majorana fermions, of obtaining information about the Majorana phases in the neutrino mixing matrix, is analyzed in the cases of normal hierarchical, inverted hierarchical and quasi-degenerate types of neutrino mass spectrum. We find, in particular, that the sensitivity to the nature of massive neutrinos depends critically on the atomic level energy difference relevant in the RENP.

D. N. Dinh; S. T. Petcov; N. Sasao; M. Tanaka; M. Yoshimura

2012-09-21T23:59:59.000Z

112

E-Print Network 3.0 - atomic absorption spectrophotometric Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrophotometric Page: << < 1 2 3 4 5 > >> 1 Building up a database of...

113

E-Print Network 3.0 - atomic-absorption flame photometry Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic-absorption flame photometry Page: << < 1 2 3 4 5 > >> 1 MICROCHEMICALJOURNAL33,304-...

114

E-Print Network 3.0 - atomic-absorption spectrometry determinacion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic-absorption spectrometry determinacion Page: << < 1 2 3 4 5 > >> 1...

115

E-Print Network 3.0 - atomic absorption spectrophotometry Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrophotometry Page: << < 1 2 3 4 5 > >> 1 QUARTERLY PROGRESS REPORT...

116

E-Print Network 3.0 - atomic absorption spectroscopic Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectroscopic Page: << < 1 2 3 4 5 > >> 1 BURCIN BAYRAM ASSOCIATE...

117

E-Print Network 3.0 - atomic absorption analysis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

analysis Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption analysis Page: << < 1 2 3 4 5 > >> 1 JOURNAL DE PHYSIQUEIV Colloque...

118

E-Print Network 3.0 - atomic absorption spectrometry-determination...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometry-determination Page: << < 1 2 3 4 5 > >> 1 Extended Xray...

119

E-Print Network 3.0 - atomic absorption spectrophotometer Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrophotometer Page: << < 1 2 3 4 5 > >> 1 ChemicalSample...

120

E-Print Network 3.0 - atomic absorption flame Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

flame Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption flame Page: << < 1 2 3 4 5 > >> 1 Appendix 1: Experimental Studies...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

E-Print Network 3.0 - atomic absorption spectrom- Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrom- Page: << < 1 2 3 4 5 > >> 1 Mechanism for Increased Yield with...

122

E-Print Network 3.0 - atomic absorption spectrometry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometry Page: << < 1 2 3 4 5 > >> 1 JOURNAL DE PHYSIQUEIV Colloque...

123

Subwavelength atom localization via amplitude and phase control of the absorption spectrum  

E-Print Network [OSTI]

We propose a scheme for subwavelength localization of an atom conditioned upon the absorption of a weak probe field at a particular frequency. Manipulating atom-field interaction on a certain transition by applying drive fields on nearby coupled...

Sahrai, M.; Tajalli, H.; Kapale, KT; Zubairy, M. Suhail.

2005-01-01T23:59:59.000Z

124

Iron Species in Argonne Premium Coal Samples:? An Investigation Using X-ray Absorption Spectroscopy  

Science Journals Connector (OSTI)

Iron Species in Argonne Premium Coal Samples:? An Investigation Using X-ray Absorption Spectroscopy ... Chemistry Division, Argonne National Laboratory, 9700 S. Cass Ave., Argonne, Illinois 60439 ... Iron K-edge X-ray absorption spectroscopy (XAS) has been used to examine the iron species that are present within the Argonne Premium Coal Samples. ...

Stephen R. Wasserman; Randall E. Winans; Robert McBeth

1996-03-20T23:59:59.000Z

125

External Cavity Quantum Cascade Laser for Quartz Tuning Fork Photoacoustic Spectroscopy of Broad Absorption Features  

SciTech Connect (OSTI)

We demonstrate mid-infrared spectroscopy of large molecules with broad absorption features using a tunable external cavity quantum cascade laser. Absorption spectra for two different Freons are measured over the range 1130-1185 cm-1 with 0.2 cm-1 resolution via laser photoacoustic spectroscopy with quartz tuning forks as acoustic transducers. The measured spectra are in excellent agreement with published reference absorption spectra.

Phillips, Mark C.; Myers, Tanya L.; Wojcik, Michael D.; Cannon, Bret D.

2007-05-01T23:59:59.000Z

126

Broadband absorption spectroscopy in turbid media by combined frequency-domain and  

E-Print Network [OSTI]

Broadband absorption spectroscopy in turbid media by combined frequency-domain and steady. Tromberg A technique for measuring broadband near-infrared absorption spectra of turbid media that uses selected wavelengths. Coefficients of absorption a and reduced scattering s derived from the FD data

Berger, Andrew J.

127

Single atom identification by energy dispersive x-ray spectroscopy  

SciTech Connect (OSTI)

Using aberration-corrected scanning transmission electron microscope and energy dispersive x-ray spectroscopy, single, isolated impurity atoms of silicon and platinum in monolayer and multilayer graphene are identified. Simultaneously acquired electron energy loss spectra confirm the elemental identification. Contamination difficulties are overcome by employing near-UHV sample conditions. Signal intensities agree within a factor of two with standardless estimates.

Lovejoy, T. C.; Dellby, N.; Krivanek, O. L. [Nion, 1102 8th St., Kirkland, Washington 98033 (United States); Ramasse, Q. M. [SuperSTEM Laboratory, STFC Daresbury, Keckwick Lane, Daresbury WA4 4AD (United Kingdom); Falke, M.; Kaeppel, A.; Terborg, R. [Bruker Nano GmbH, Schwarzschildstr. 12, 12489 Berlin (Germany); Zan, R. [School of Physics and Astronomy, University of Manchester, Manchester M13 9PL (United Kingdom)

2012-04-09T23:59:59.000Z

128

High resolution laser induced fluorescence Doppler velocimetry utilizing saturated absorption spectroscopy  

SciTech Connect (OSTI)

A high resolution laser induced fluorescence (LIF) system has been developed to measure the flow velocity field of neutral particles in an electron-cyclotron-resonance argon plasma. The flow velocity has been determined by the Doppler shift of the LIF spectrum, which is proportional to the velocity distribution function. Very high accuracy in velocity determination has been achieved by installing a saturated absorption spectroscopy unit into the LIF system, where the absolute value and scale of laser wavelength are determined by using the Lamb dip and the fringes of a Fabry-Perot interferometer. The minimum detectable flow velocity of a newly developed LIF system is {+-}2 m/s, and this performance remains unchanged in a long-time experiment. From the radial measurements of LIF spectra of argon metastable atoms, it is found that there exists an inward flow of neutral particles associated with neutral depletion.

Aramaki, Mitsutoshi [Department of Electrical Engineering and Computer Science, Nagoya University, Nagoya 464-8603 (Japan); Ogiwara, Kohei; Etoh, Shuzo [Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, Kasuga 816-8580 (Japan); Yoshimura, Shinji [National Institute for Fusion Science, Toki 509-5292 (Japan); Tanaka, Masayoshi Y. [Department of Advanced Energy Engineering Science, Kyushu University, Kasuga 816-8580 (Japan)

2009-05-15T23:59:59.000Z

129

Autler-Townes triplet absorption spectroscopy, controllable electromagnetically induced transparency and nonlinear coherence Kerr effect  

E-Print Network [OSTI]

A Field Generated Coherence (FGC)' based 3-field cyclically-driven 4-level atomic system, which is an extended version of $\\Lambda$ type schemes, is investigated for Autler-Townes triplet absorption (ATT) spectroscopy. Two dark lines which appear in the ATT spectrum, are the essence of the generated multiple controllable EIT windows for a superluminal Gaussian light pulse. We also investigate enhancement in the group velocity for the Gaussian light pulse, using a nonlinear coherence Kerr effect. Consequently, the superluminal probing pulse leaves a steep anomalous region of the medium by $28 \\mu s$ sooner than the light pulse of the Kerr-free system. A co-linear propagation of the driving fields is suggested to minimize our explored Doppler broadening incoherence effect on the probe pulse. Indeed, the analytically observed undistorted retrieved light pulse, which is a necessary and useful requirement for realization of the results in laboratory, is also shown and analyzed explicitly.

Bacha, Bakht Amin; Nazmidinov, Rashid G

2014-01-01T23:59:59.000Z

130

Etalon-induced Baseline Drift And Correction In Atom Flux Sensors...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based...

131

Correlated single-crystal electronic absorption spectroscopy and X-ray crystallography at NSLS beamline X26-C  

SciTech Connect (OSTI)

The research philosophy and new capabilities installed at NSLS beamline X26-C to support electronic absorption and Raman spectroscopies coupled with X-ray diffraction are reviewed. This beamline is dedicated full time to multidisciplinary studies with goals that include revealing the relationship between the electronic and atomic structures in macromolecules. The beamline instrumentation has been fully integrated such that optical absorption spectra and X-ray diffraction images are interlaced. Therefore, optical changes induced by X-ray exposure can be correlated with X-ray diffraction data collection. The installation of Raman spectroscopy into the beamline is also briefly reviewed. Data are now routinely generated almost simultaneously from three complementary types of experiments from the same sample. The beamline is available now to the NSLS general user population.

Orville, A.M.; Buono, R.; Cowan, M.; Heroux, A.; Shea-McCarthy, G.; Schneider, D. K.; Skinner, J. M.; Skinner, M. J.; Stoner-Ma, D.; Sweet, R. M.

2011-05-01T23:59:59.000Z

132

Correlated Single-Crystal Electronic Absorption Spectroscopy and X-ray Crystallography at NSLS Beamline X26-C  

SciTech Connect (OSTI)

The research philosophy and new capabilities installed at NSLS beamline X26-C to support electronic absorption and Raman spectroscopies coupled with X-ray diffraction are reviewed. This beamline is dedicated full time to multidisciplinary studies with goals that include revealing the relationship between the electronic and atomic structures in macromolecules. The beamline instrumentation has been fully integrated such that optical absorption spectra and X-ray diffraction images are interlaced. Therefore, optical changes induced by X-ray exposure can be correlated with X-ray diffraction data collection. The installation of Raman spectroscopy into the beamline is also briefly reviewed. Data are now routinely generated almost simultaneously from three complementary types of experiments from the same sample. The beamline is available now to the NSLS general user population.

A Orville; R Buono; M Cowan; A Heroux; G Shea-McCarthy; D Schneider; J Skinner; M Skinner; D Stoner-Ma; R Sweet

2011-12-31T23:59:59.000Z

133

E-Print Network 3.0 - atomic emission spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy of an Atomic Nucleus: The Thorium-229 Nuclear Clock Dr... spectroscopy of an atomic nucleus. Host: Mansoor Sheik-Bahae 12;... of 7.6 0.5 eV. This makes it...

134

Structural analysis of sulfur in natural rubber using X-ray absorption near-edge spectroscopy  

Science Journals Connector (OSTI)

The opportunity to employ X-ray absorption near-edge spectroscopy techniques to investigate the alteration of the structural properties of sulfur in various vulcanized rubber sheets is presented.

Pattanasiriwisawa, W.

2008-07-11T23:59:59.000Z

135

E-Print Network 3.0 - absorption spectroscopy identifies Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorptions were found ranging from... crystals of 1,3,5-trinitro-S-triazine (RDX) using terahertz time-domain spectroscopy V. H. Whitley & D. E... of the incident radiation....

136

Atomic absorption monitor for deposition process control of aluminum at 394 nm using frequency-doubled diode laser  

E-Print Network [OSTI]

Atomic absorption monitor for deposition process control of aluminum at 394 nm using frequency November 1995 A monitor for Al vapor density based on atomic absorption AA using a frequency of atomic absorption AA as a monitor for thickness and composition control in physical vapor deposi- tion

Fejer, Martin M.

137

Coherent Control of Single-Photon Absorption and Reemission in a Two-Level Atomic Ensemble Shanchao Zhang,1  

E-Print Network [OSTI]

Coherent Control of Single-Photon Absorption and Reemission in a Two-Level Atomic Ensemble Shanchao-photon absorption and reemission in a two-level cold atomic ensemble. This is achieved by interfering the incident-level atomic medium, the absorption and emission usually both occur within the photon pulse duration. Recently

Du, Shengwang

138

Measurement of Water Vapor Concentration using Tunable Diode Laser Absorption Spectroscopy  

E-Print Network [OSTI]

Tunable diode laser spectroscopy and the Beer-Lambert relation has been used to measure the absorption of water vapor both in an absorption cell and in a shock tube. The purpose of this thesis is to develop a laser diagnostic capable of determining...

Barrett, Alexander B.

2010-07-14T23:59:59.000Z

139

E-Print Network 3.0 - atomic absorption spectrometer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometer Page: << < 1 2 3 4 5 > >> 1 In the post-genome era, the...

140

E-Print Network 3.0 - atomic absorption lines Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

lines Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption lines Page: << < 1 2 3 4 5 > >> 1 An output coupler for Bose condensed...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

E-Print Network 3.0 - atomic absorption faa Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

faa Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption faa Page: << < 1 2 3 4 5 > >> 1 Through-Space Charge Transfer and Nonlinear...

142

E-Print Network 3.0 - absorption spatial profiles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Rico, Mayaguez Collection: Geosciences 36 Atomic flux measurement by diode-laser-based atomic absorption spectroscopy Summary: the basic AA spectroscopic feature, i.e., the...

143

E-Print Network 3.0 - absorption spectroscopy exafs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Colloque C9, supplement au n012, Tome 48, dkcembre 1987 Summary: -shaped model for the atomic absorption resulted in a large improvement in the EXAFS shape. In Fig. 2 we...

144

Graphite Furnance Atomic Absorption as a detector for High Performance Liquid Chromatography  

E-Print Network [OSTI]

GRAPHITE FURNACE ATOMIC ABSORPTION AS A DETECTOR FOR HIGH PERFORMANCE LIQUID CHROMATOGRAPHy A Thesis by HUSTON EDWARD HOWELL, JR. Submitted to the Graduate College oi' Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1980 Major Subject: Chemistry GRAPHITE FURNACE ATOMIC ABSORPTION AS A DETECTOR FOR HIGH PERFORMANCE LIQUID CHROMATOGRAPHY A Thesis by HUSTON EDWARD HOWELL, JR. Approved as to style and content by: (Chairman...

Howell, Huston Edward

1980-01-01T23:59:59.000Z

145

E-Print Network 3.0 - ablation mass spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

implants into rat livers after radiofrequency ablation were quantified by atomic absorption spectroscopy... Local carboplatin delivery and tissue distribution in...

146

Direct and quantitative photothermal absorption spectroscopy of individual particulates  

SciTech Connect (OSTI)

Photonic structures can exhibit significant absorption enhancement when an object's length scale is comparable to or smaller than the wavelength of light. This property has enabled photonic structures to be an integral component in many applications such as solar cells, light emitting diodes, and photothermal therapy. To characterize this enhancement at the single particulate level, conventional methods have consisted of indirect or qualitative approaches which are often limited to certain sample types. To overcome these limitations, we used a bilayer cantilever to directly and quantitatively measure the spectral absorption efficiency of a single silicon microwire in the visible wavelength range. We demonstrate an absorption enhancement on a per unit volume basis compared to a thin film, which shows good agreement with Mie theory calculations. This approach offers a quantitative approach for broadband absorption measurements on a wide range of photonic structures of different geometric and material compositions.

Tong, Jonathan K.; Hsu, Wei-Chun; Eon Han, Sang; Burg, Brian R.; Chen, Gang, E-mail: gchen2@mit.edu [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Zheng, Ruiting [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China)] [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Shen, Sheng [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)] [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)

2013-12-23T23:59:59.000Z

147

Scattering and absorption of ultracold atoms by nanotubes  

E-Print Network [OSTI]

We investigate theoretically how cold atoms, including Bose-Einstein condensates, are scattered from, or absorbed by nanotubes with a view to analysing recent experiments. In particular we consider the role of potential strength, quantum reflection, atomic interactions and tube vibrations on atom loss rates. Lifshitz theory calculations deliver a significantly stronger scattering potential than that found in experiment and we discuss possible reasons for this. We find that the scattering potential for dielectric tubes can be calculated to a good approximation using a modified pairwise summation approach, which is efficient and easily extendable to arbitrary geometries. Quantum reflection of atoms from a nanotube may become a significant factor at low temperatures, especially for non-metallic tubes. Interatomic interactions are shown to increase the rate at which atoms are lost to the nanotube and lead to non-trivial dynamics. Thermal nanotube vibrations do not significantly increase loss rates or reduce condensate fractions, but lower frequency oscillations can dramatically heat the cloud.

B. Jetter; J. Märkle; P. Schneeweiss; M. Gierling; S. Scheel; A. Günther; J. Fortágh; T. E. Judd

2012-05-28T23:59:59.000Z

148

X-ray Absorption and Emission Spectroscopy Study of the Effect of Doping on the Low Energy Electronic Structure of PrFeAsO1-[delta  

E-Print Network [OSTI]

X-ray Absorption and Emission Spectroscopy Study of theusing soft X-ray absorption and emission spectroscopy. The2. (a) Oxygen 1s x-ray absorption spectra of PrFeAsO 1-? (?

Freelon, Byron

2010-01-01T23:59:59.000Z

149

Method and apparatus for aerosol particle absorption spectroscopy  

DOE Patents [OSTI]

A method and apparatus for determining the absorption spectra, and other properties, of aerosol particles. A heating beam source provides a beam of electromagnetic energy which is scanned through the region of the spectrum which is of interest. Particles exposed to the heating beam which have absorption bands within the band width of the heating beam absorb energy from the beam. The particles are also illuminated by light of a wave length such that the light is scattered by the particles. The absorption spectra of the particles can thus be determined from an analysis of the scattered light since the absorption of energy by the particles will affect the way the light is scattered. Preferably the heating beam is modulated to simplify the analysis of the scattered light. In one embodiment the heating beam is intensity modulated so that the scattered light will also be intensity modulated when the particles absorb energy. In another embodiment the heating beam passes through an interferometer and the scattered light reflects the Fourier Transform of the absorption spectra.

Campillo, Anthony J. (Nesconset, NY); Lin, Horn-Bond (Manorville, NY)

1983-11-15T23:59:59.000Z

150

Results from Point Contact Tunnelling Spectroscopy and Atomic Layer Deposition  

SciTech Connect (OSTI)

We have shown previously that magnetic niobium oxides can influence the superconducting density of states at the surface of cavity-grade niobium coupons. We will present recent results obtained by Point Contact Tunneling spectroscopy (PCT) on coupons removed from hot and cold spots in a niobium cavity, as well as a comparative study of magnetic oxides on mild baked/unbaked electropolished coupons. We will also describe recent results obtained from coated cavities, ALD films properties and new materials using Atomic Layer Deposition (ALD).

Proslier, Th. [Illinois Institute of Technology; Zasadzinski, J. [Illinois Institute of Technology; Ciovati, Gianluigi [JLAB; Kneisel, Peter K. [JLAB; Elam, J. W. [ANL; Norem, J. [ANL; Pellin, M. J. [ANL

2009-11-01T23:59:59.000Z

151

Three-photon-absorption resonance for all-optical atomic clocks Sergei Zibrov,1,2,3,4  

E-Print Network [OSTI]

Three-photon-absorption resonance for all-optical atomic clocks Sergei Zibrov,1,2,3,4 Irina, driving atoms coherently from state c to b , fol- lowed by a one-photon absorption from field P, which January 2005; published 7 July 2005 We report an experimental study of an all-optical three-photon-absorption

Walsworth, Ronald L.

152

E-Print Network 3.0 - atomic ions Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... ion will form a...

153

E-Print Network 3.0 - atoms ions electrons Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... ion will form a...

154

Autler-Townes triplet absorption spectroscopy, controllable electromagnetically induced transparency and nonlinear coherence Kerr effect  

E-Print Network [OSTI]

A Field Generated Coherence (FGC)' based 3-field cyclically-driven 4-level atomic system, which is an extended version of $\\Lambda$ type schemes, is investigated for Autler-Townes Triplet (ATT) absorption spectroscopy. Two dark lines which appear in the ATT spectrum, are the essence of the generated multiple controllable Electromagnetically Induced Transparency (EIT) windows for a superluminal Gaussian light pulse. We also investigate enhancement in the group advance time for a probe superluminal Gaussian light pulse even with no additional losses while generating nonlinear coherence Kerr effect through an intense monochrmatic laser field. Consequently, the pulse leaves the steep anomalous region of the medium by $38 \\mu s$ sooner than the pulse when retrieved from the Kerr-free system. A co-linear propagation of the driving fields is suggested to minimize our explored incoherence Doppler broadening effect on the probe pulse. Indeed, the analytically observed undistorted retrieved Gaussian light pulse, which is a necessary and useful requirement for realization of the results in laboratory, is also shown and analyzed explicitly.

Bakht Amin Bacha; Fazal Ghafoor; Rashid G Nazmidinov

2014-01-09T23:59:59.000Z

155

Two-photon absorption and emission by Rydberg atoms in coupled cavities  

E-Print Network [OSTI]

We study the dynamics of a system composed of two coupled cavities, each containing a single Rydberg atom. The interplay between Rydberg-Rydberg interaction and photon hopping enables the transition of the atoms from the collective ground state to the double Rydberg excitation state by individually interacting with the hybrid cavity modes and suppressing the up conversion process between them. The atomic transition is accompanied by the two-photon absorption and emission of the hybrid modes. Since the energy level structure of the atom-cavity system is photon number dependent, there is only a pair of states being in the two-photon resonance. Therefore, the system can act as a quantum nonlinear absorption filter through the nonclassical quantum process, converting coherent light field into a non-classical state. Meanwhile, the vacuum field in the cavity inspires the Rydberg atoms to simultaneously emit two photons into the hybrid mode, resulting in obvious emission enhancement of the mode.

Huaizhi Wu; Zhen-Biao Yang; Shi-Biao Zheng

2013-10-10T23:59:59.000Z

156

Precision recording of near-edge profiles of x-ray absorption edges: an improved x-ray spectroscopy  

SciTech Connect (OSTI)

The intense, highly monochromatized X-ray beams available at the Cornell High Energy Synchroton Source facility permit one to plot the fine structure at absorption edges of elements with atomic number Z > 18. With the simple device described in this report, the authors have recorded distinctive features in absorption profiles, with a reproducibility better than +/- 50 meV for the major jumps, when measured with reference to a selected material, generally the metal. These spectra, which reflect locations of the upper states into which the photoelectrons are propelled, can be obtained without pretreatment of the sample (other than grinding to a fine powder) under ambient atmospheric conditions. Of course, spectra at low or high temperatures, under controlled atmospheres, can also be recorded with a more elaborative device. This technique complements information derived from electron energy loss spectroscopy and provides a fingerprint of modifications in the electronic structure of the element induced by the coordinating shell of surrounding atoms. It is a discriminating analytical probe for characterizing compositional changes in the first coordination shell around the selected atomic centers, due to processing of amorphous (or very finely divided) materials.

Chiu, N.S.; Bauer, S.H.

1988-08-01T23:59:59.000Z

157

Kaon Absorption from Kaonic Atoms and Formation Spectra of Kaonic Nuclei  

E-Print Network [OSTI]

We considered the kaon absorption from atomic states into nucleus. We found that the nuclear density probed by the atomic kaon significantly depends on the kaon orbit. Then, we reexamined the meanings of the observed strengths of one-body and two-body kaon absorption, and investigated the effects to the formation spectra of kaon bound states by in-flight ($K^-,p$) reactions. As a natural consequence, if the atomic kaon probes the smaller nuclear density, the ratio of the two-body absorption at nuclear center is larger than the observed value, and the depth of the imaginary potential is deeper even at smaller kaon energies as in kaonic nuclear states because of the large phase space for the two-body processes.

Junko Yamagata; Satoru Hirenzaki

2006-12-09T23:59:59.000Z

158

E-Print Network 3.0 - atom re-evaporation method Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

method Page: << < 1 2 3 4 5 > >> 1 Atomic flux measurement by diode-laser-based atomic absorption spectroscopy Summary: in the absorp- tion profile indicates that barium...

159

Theory for optical absorption in small clusters: Dependence on atomic surface structure and cluster size  

Science Journals Connector (OSTI)

We present a theory which permits for the first time a detailed analysis of the dependence of the absorption spectrum on atomic structure and cluster size. Thus, we determine the development of the collective excitations in small clusters and show that their broadening depends sensitively on the atomic structure, in particular at the surface. Results for Hgn+ clusters show that the plasmon energy is close to its jellium value in the case of spherical-like structures, but is in general between ?p/ ?3 and ?p/ ?2 for compact clusters. A particular success of our theory is the identification of the excitations contributing to the absorption peaks.

S. Grabowski, M. E. Garcia, and K. H. Bennemann

1994-06-20T23:59:59.000Z

160

Subwavelength atom localization via amplitude and phase control of the absorption spectrum  

E-Print Network [OSTI]

We propose a scheme for subwavelength localization of an atom conditioned upon the absorption of a weak probe field at a particular frequency. Manipulating atom-field interaction on a certain transition by applying drive fields on nearby coupled transitions leads to interesting effects in the absorption spectrum of the weak probe field. We exploit this fact and employ a four-level system with three driving fields and a weak probe field, where one of the drive fields is a standing-wave field of a cavity. We show that the position of an atom along this standing wave is determined when probe field absorption is measured. We find that absorption of the weak probe field at a certain frequency leads to subwavelength localization of the atom in either of the two half-wavelength regions of the cavity field by appropriate choice of the system parameters. We term this result as sub-half-wavelength localization to contrast it with the usual atom localization result of four peaks spread over one wavelength of the standing wave. We observe two localization peaks in either of the two half-wavelength regions along the cavity axis.

Mostafa Sahrai; Habib Tajalli; Kishore T. Kapale; M. Suhail Zubairy

2005-07-21T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

A Neutral Atom and a Charged Wire: From Elastic scattering to Absorption  

E-Print Network [OSTI]

We solve the problem of a neutral atom interacting with a charged wire, giving rise to an attractive 1/r^2 potential in two dimensions. We show how a suitable average over all possible self-adjoint extensions of the radial Schroedinger Hamiltonian eventually leads to the classical formula for absorption of the atom, a formula shown to be in agreement with a recent experiment.

M. Bawin; S. A. Coon

2000-12-08T23:59:59.000Z

162

Vibrational spectra of N2: An advanced undergraduate laboratory in atomic and molecular spectroscopy  

E-Print Network [OSTI]

an advanced laboratory course focused on spectroscopy of atoms and molecules, for a diverse and solid#12;Vibrational spectra of N2: An advanced undergraduate laboratory in atomic and molecular to demonstrate molecular spectroscopy by measuring the vibrational energy spacing of nitrogen molecules

Bayram, S. Burçin

163

Lamb-Dicke spectroscopy of atoms in a hollow-core photonic crystal fibre  

E-Print Network [OSTI]

Unlike photons, which are conveniently handled by mirrors and optical fibres without loss of coherence, atoms lose their coherence via atom-atom and atom-wall interactions. This decoherence of atoms deteriorates the performance of atomic clocks and magnetometers, and also hinders their miniaturisation. Here we report a novel platform for precision spectroscopy. Ultracold strontium atoms inside a kKagome-lattice hollow-core photonic crystal fibre (HC-PCF) are transversely confined by an optical lattice to prevent atoms from interacting with the fibre wall. By confining at most one atom in each lattice site, to avoid atom-atom interactions and Doppler effect, a 7.8-kHz-wide spectrum is observed for the $^1 S_0-{}^3P_1$ (m=0) transition. Atoms singly trapped in a magic lattice in hollow-core photonic crystal fibresHC-PCFs improve the optical depth while preserving atomic coherence time.

Okaba, Shoichi; Benabid, Fetah; Bradley, Tom; Vincetti, Luca; Maizelis, Zakhar; Yampol'skii, Valery; Nori, Franco; Katori, Hidetoshi

2014-01-01T23:59:59.000Z

164

X-ray absorption spectroscopy of the cubic and hexagonal polytypes of zinc sulfide B. Gilbert,1,  

E-Print Network [OSTI]

X-ray absorption spectroscopy of the cubic and hexagonal polytypes of zinc sulfide B. Gilbert,1 Received 18 June 2002; published 26 December 2002 We investigate the sensitivity of x-ray absorption. Experimental spectra and multiple-scattering calculations are reported at the major absorption edges

Haskel, Daniel

165

Total Mercury in the Hair of Children by Combustion Atomic Absorption Spectrometry (Comb-AAS)  

Science Journals Connector (OSTI)

......sample catalytic combustion, preconcentration...Feasibility Studies Hair chemistry Humans Mercury analysis...samplecatalytic combustion,preconcentrationby...associated with a coal-fired power plant...and animal fur by combustion atomic absorption...A study of three coal-fired electric-gen......

Sergi Diez; Paolo Montuori; Xavier Querol; Josep M. Bayona

2007-04-01T23:59:59.000Z

166

Negative refraction with tunable absorption in an active dense gas of atoms  

E-Print Network [OSTI]

Applications of negative index materials (NIM) presently are severely limited by absorption. Next to improvements of metamaterial designs, it has been suggested that dense gases of atoms could form a NIM with negligible losses. In such gases, the low absorption is facilitated by quantum interference. Here, we show that additional gain mechanisms can be used to tune and effectively remove absorption in a dense gas NIM. In our setup, the atoms are coherently prepared by control laser fields, and further driven by a weak incoherent pump field to induce gain. We employ nonlinear optical Bloch equations to analyze the optical response. Metastable Neon is identified as a suitable experimental candidate at infrared frequencies to implement a lossless active negative index material.

P. P. Orth; R. Hennig; C. H. Keitel; J. Evers

2012-10-17T23:59:59.000Z

167

Photocarrier dynamics in anatase TiO{sub 2} investigated by pump-probe absorption spectroscopy  

SciTech Connect (OSTI)

The dynamics of photogenerated electrons and holes in undoped anatase TiO{sub 2} were studied by femtosecond absorption spectroscopy from the visible to mid-infrared region (0.1–2.0?eV). The transient absorption spectra exhibited clear metallic responses, which were well reproduced by a simple Drude model. No mid-gap absorptions originating from photocarrier localization were observed. The reduced optical mass of the photocarriers obtained from the Drude-model analysis is comparable to theoretically expected one. These results demonstrate that both photogenerated holes and electrons act as mobile carriers in anatase TiO{sub 2}. We also discuss scattering and recombination dynamics of photogenerated electrons and holes on the basis of the time dependence of absorption changes.

Matsuzaki, H., E-mail: hiroyuki-matsuzaki@aist.go.jp, E-mail: okamotoh@k.u-tokyo.ac.jp; Matsui, Y.; Uchida, R.; Yada, H.; Terashige, T. [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Li, B.-S. [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology (HIT), Harbin City 150080 (China); Sawa, A. [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8562 (Japan); Kawasaki, M. [Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Tokura, Y. [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8562 (Japan); Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Okamoto, H., E-mail: hiroyuki-matsuzaki@aist.go.jp, E-mail: okamotoh@k.u-tokyo.ac.jp [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); CREST, Japan Science and Technology Agency, Chiyoda-ku, Tokyo 102-0075 (Japan)

2014-02-07T23:59:59.000Z

168

Entangling two atoms in spatially separated cavities through both photon emission and absorption processes  

E-Print Network [OSTI]

We consider a system consisting of a $\\Lambda$-type atom and a V-type atom, which are individually trapped in two spatially separated cavities that are connected by an optical fibre. We show that an extremely entangled state of the two atoms can be deterministically generated through both photon emission of the $\\Lambda$-type atom and photon absorption of the V-type atom in an ideal situation. The influence of various decoherence processes such as spontaneous emission and photon loss on the fidelity of the entangled state is also investigated. We find that the effect of photon leakage out of the fibre on the fidelity can be greatly diminished in some special cases. As regards the effect of spontaneous emission and photon loss from the cavities, we find that the present scheme with a fidelity higher than 0.98 may be realized under current experiment conditions.

Peng Peng; Fu-li Li

2006-12-29T23:59:59.000Z

169

Condensed phase spectroscopy from mixed-order semiclassical molecular dynamics: Absorption, emission, and resonant Raman spectra of I2  

E-Print Network [OSTI]

Condensed phase spectroscopy from mixed-order semiclassical molecular dynamics: Absorption, as a prototype of spectroscopy in condensed media in general. The method relies on constructing quantum correlations into system and bath are used to provide perspectives about condensed phase spectroscopy

Apkarian, V. Ara

170

X-ray absorption spectroscopy on solid krypton up to 20 GPa  

Science Journals Connector (OSTI)

High-pressure properties of krypton were investigated by energy-dispersive extended x-ray absorption fine-structure spectroscopy in a diamond anvil cell at room temperature. The equation of state agrees very well with x-ray diffraction data. The pressure dependence of the Debye-Waller factor was determined and compared with calculations using pair potentials. The analysis of the x-ray absorption near-edge structure part of the spectrum shows the possibility of measuring the pressure in bubbles of krypton implanted in metallic matrices.

A. Polian; J. P. Itie; E. Dartyge; A. Fontaine; G. Tourillon

1989-02-15T23:59:59.000Z

171

ABSORPTION PHOTOLECTRIQUE DES RAYONS 03B3 DANS LA COUCHE L DES ATOMES Par Mme NADINE MARTY.  

E-Print Network [OSTI]

401. ABSORPTION PHOTO�LECTRIQUE DES RAYONS 03B3 DANS LA COUCHE L DES ATOMES Par Mme NADINE MARTY la suite, comme la section efficace totale d'absorption photoélectrique par atome. Les résultats de. Laboratoire dé Chimie nucléaire, Collège de France. Sommaire. - On rappelle la valeur des sections efficaces d'absorption

Boyer, Edmond

172

Mechanism of Pb Adsorption to Fatty Acid Langmuir Monolayers Studied by X-ray Absorption Fine Structure Spectroscopy  

SciTech Connect (OSTI)

The local atomic environment of lead (Pb) adsorbed to a CH{sub 3}(CH{sub 2}){sub 19}COOH Langmuir monolayer was investigated in situ using grazing-incidence X-ray absorption fine structure (GI-XAFS) spectroscopy at the Pb L{sub III} edge. Measurements were performed at pH 6.5 of the 10{sup -5} M PbCl{sub 2} solution subphase, a condition under which grazing incidence diffraction (GID) revealed a large-area commensurate superstructure underneath the close-packed organic monolayer. The XAFS results indicate covalent binding of the Pb cations to the carboxyl headgroups, and the observed Pb-Pb coordination suggests that the metal is adsorbed as a hydrolysis polymer, rather than as individual Pb{sup 2+} ions. The data are consistent with a bidentate chelating mechanism and a one Pb atom to one carboxyl headgroup binding stoichiometry. We discuss how this adsorption model can explain the peculiarities observed with Pb in previous metal-Langmuir monolayer studies. A systematic study of lead perchlorate and lead acetate aqueous solutions is presented and used in the analysis. XAFS multiple scattering effects from alignment of the Pb-C-C atoms in the lead acetate solutions are reported.

Boyanov, M.I.; Kmetko, J.; Shibata, T.; Datta, A.; Dutta, P.; Bunker, B.A. (NWU); (Notre)

2010-09-30T23:59:59.000Z

173

Comment on ``Resonance-fluorescence and absorption spectra of a two-level atom driven by a strong bichromatic field''  

E-Print Network [OSTI]

Comment on ``Resonance-fluorescence and absorption spectra of a two-level atom driven by a strong predictions of the resonance fluorescence from a two-level atom driven by a strong bichromatic field J. Opt.50.Hz, 33.50.Dq, 32.80. t In studying the resonance fluorescence from a driven two- level atom, we

Boyd, Robert W.

174

Image stack alignment in full-field X-ray absorption spectroscopy using SIFT_PyOCL  

Science Journals Connector (OSTI)

An application of the Scale-Invariant Feature Transform (SIFT) algorithm for image stack alignment in full-field X-ray absorption spectroscopy is described and a Python-OpenCL implementation of this algorithm is presented.

Paleo, P.

2014-02-04T23:59:59.000Z

175

Symposium on atomic spectroscopy (SAS-83): abstracts and program  

SciTech Connect (OSTI)

Abstracts of papers given at the symposium are presented. Session topics include: Rydbergs, optical radiators, and planetary atoms; highly ionized atoms; ultraviolet radiation; theory, ion traps, and laser cooling; beam foil; and astronomy. (GHT)

Not Available

1983-09-01T23:59:59.000Z

176

Determination of the concentrations of magnesium and aluminum in alloys by laser produced atomic emission spectroscopy  

E-Print Network [OSTI]

DETERMINATION OF THE CONCENTRATIONS OF MAGNESIUM AND ALUiiINUM IN ALLOYS BY LASER PRODUCED ATOMIC EMISSION SPECTROSCOPY A Thesis by WILLIAM MONROE ASHE Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the reqmrements for the degree of MASTER OF SCIENCE December 1997 Major Subject: Physics DETERMINATION OF THE CONCENTRATIONS OF MAGNESIUM AND ALUMINUM ALLOYS BY LASER PRODUCED ATOMIC EMISSION SPECTROSCOPY A Thesis by WILLIAM MONROE ASHE...

Ashe, William Monroe

2012-06-07T23:59:59.000Z

177

Projections of local atomic structure revealed by wavelet analysis of x-ray absorption anisotropy P. Korecki,1,* D. V. Novikov,2 and M. Tolkiehn2  

E-Print Network [OSTI]

Projections of local atomic structure revealed by wavelet analysis of x-ray absorption anisotropy P x-ray field amplitude at the sites of absorbing atoms and effectively changes the atomic absorption in an experiment a wavelet transform approach for analysis of x-ray absorption anisotropy XAA patterns recorded

Korecki, Pawe³

178

GALACTIC OUTFLOWS IN ABSORPTION AND EMISSION: NEAR-ULTRAVIOLET SPECTROSCOPY OF GALAXIES AT 1 < z < 2  

SciTech Connect (OSTI)

We study large-scale outflows in a sample of 96 star-forming galaxies at 1 {approx}< z {approx}< 2, using near-UV spectroscopy of Fe II and Mg II absorption and emission. The average blueshift of the Fe II interstellar absorption lines with respect to the systemic velocity is -85 {+-} 10 km s{sup -1} at z {approx} 1.5, with standard deviation 87 km s{sup -1}; this is a decrease of a factor of two from the average blueshift measured for far-UV interstellar absorption lines in similarly selected galaxies at z {approx} 2. The profiles of the Mg II {lambda}{lambda}2796, 2803 lines show much more variety than the Fe II profiles, which are always seen in absorption; Mg II ranges from strong emission to pure absorption, with emission more common in galaxies with blue UV slopes and at lower stellar masses. Outflow velocities, as traced by the centroids and maximum extent of the absorption lines, increase with increasing stellar mass with 2{sigma}-3{sigma} significance, in agreement with previous results. We study fine structure emission from Fe II*, finding several lines of evidence in support of the model in which this emission is generated by the re-emission of continuum photons absorbed in the Fe II resonance transitions in outflowing gas. In contrast, photoionization models indicate that Mg II emission arises from the resonant scattering of photons produced in H II regions, accounting for the differing profiles of the Mg II and Fe II lines. A comparison of the strengths of the Fe II absorption and Fe II* emission lines indicates that massive galaxies have more extended outflows and/or greater extinction, while two-dimensional composite spectra indicate that emission from the outflow is stronger at a radius of {approx}10 kpc in high-mass galaxies than in low-mass galaxies.

Erb, Dawn K. [Department of Physics, University of Wisconsin Milwaukee, Milwaukee, WI 53211 (United States); Quider, Anna M. [Institute of Astronomy, Madingley Road, Cambridge CB3 0HA (United Kingdom); Henry, Alaina L.; Martin, Crystal L., E-mail: erbd@uwm.edu, E-mail: aquider@gmail.com, E-mail: ahenry@physics.ucsb.edu, E-mail: cmartin@physics.ucsb.edu [Department of Physics, University of California Santa Barbara, Santa Barbara, CA 93106 (United States)

2012-11-01T23:59:59.000Z

179

High Speed H2O Concentration Measurements Using Absorption Spectroscopy to Monitor Exhaust Gas  

SciTech Connect (OSTI)

This paper demonstrates the potential for fast absorption spectroscopy measurements in diesel-engine exhaust to track H2O concentration transients. Wavelength-agile absorption spectroscopy is an optical technique that measures broadband absorption spectra between 10kHz and 100 MHz. From these measured spectra, gas temperature and absorber concentration can be determined. The Fourier-domain mode-locking (FDML) laser is becoming recognized as one of the most robust and reliable wavelength-agile sources available. H2O concentration measurements during combustion events at crank angle resolved speeds are beneficial for a wide variety of applications, such as product improvements for industry, control and reliability checks for experimental researchers, and measures of fit for numerical simulations. The difficulties associated with measuring diesel exhaust compared to in-cylinder measurements are discussed. A full description of the experimental configuration and data processing is explained. Measurements of engine exhaust H2O transients with 10- s temporal resolution are presented for a range of engine conditions.

Kranendonk, Laura [ORNL; Parks, II, James E [ORNL; Prikhodko, Vitaly Y [ORNL; Partridge Jr, William P [ORNL

2008-01-01T23:59:59.000Z

180

Femtosecond x-ray absorption spectroscopy with hard x-ray free electron laser  

SciTech Connect (OSTI)

We have developed a method of dispersive x-ray absorption spectroscopy with a hard x-ray free electron laser (XFEL), generated by a self-amplified spontaneous emission (SASE) mechanism. A transmission grating was utilized for splitting SASE-XFEL light, which has a relatively large bandwidth (?E/E ? 5 × 10{sup ?3}), into several branches. Two primary split beams were introduced into a dispersive spectrometer for measuring signal and reference spectra simultaneously. After normalization, we obtained a Zn K-edge absorption spectrum with a photon-energy range of 210 eV, which is in excellent agreement with that measured by a conventional wavelength-scanning method. From the analysis of the difference spectra, the noise ratio was evaluated to be ?3 × 10{sup ?3}, which is sufficiently small to trace minute changes in transient spectra induced by an ultrafast optical laser. This scheme enables us to perform single-shot, high-accuracy x-ray absorption spectroscopy with femtosecond time resolution.

Katayama, Tetsuo; Togashi, Tadashi; Tono, Kensuke; Kameshima, Takashi [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)] [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Inubushi, Yuichi; Sato, Takahiro; Hatsui, Takaki; Yabashi, Makina [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan)] [RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan); Obara, Yuki; Misawa, Kazuhiko [Department of Applied Physics, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588 (Japan)] [Department of Applied Physics, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588 (Japan); Bhattacharya, Atanu; Kurahashi, Naoya [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan)] [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Ogi, Yoshihiro [Molecular Reaction Dynamics Research Team, RIKEN Center for Advanced Photonics, 2-1 Hirosawa, Wako 351-0198 (Japan)] [Molecular Reaction Dynamics Research Team, RIKEN Center for Advanced Photonics, 2-1 Hirosawa, Wako 351-0198 (Japan); Suzuki, Toshinori [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan) [Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Molecular Reaction Dynamics Research Team, RIKEN Center for Advanced Photonics, 2-1 Hirosawa, Wako 351-0198 (Japan)

2013-09-23T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

E-Print Network 3.0 - absorption spectrometric detection Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is achieved using two... microbalance QCM , multichannel spectro- scopic ellipsometry,2,3 atomic absorption spectroscopy AAS , electron Source: Rubloff, Gary W. - Institute for...

182

Probing photochemical transformations at TiO{sub 2}/Pt and TiO{sub 2}/Ir interfaces using x-ray absorption spectroscopy  

SciTech Connect (OSTI)

Structural transformations at the TiO{sub 2}/Pt and TiO{sub 2}/Ir interfaces during UV-irradiation have been probed by X-ray absorption spectroscopy. Oxidation by the photogenerated holes results in the intercalation of Pt and Ir into the Titania matrix. The structural transformations observed with Pt and Ir nanoparticles anchored on TiO{sub 2} is different than the clustering of gold atoms observed in the TiO{sub 2}/Au system. Implications of such structural transformations on the photocatalytic activity of semiconductor photocatalyts are discussed.

Lahiri, Debdutta; Subramanian, V.; Bunker, Bruce A.; Kamat, Prashant V. [Synchrotron Radiation Section, Physics Group, Bhabha Atomic Research Centre, Mumbai 400085 (India); Department of Chemical Engineering, University of Illinois at Urbana-Champaign, Illinois 61801 (United States); Department of Physics, University of Notre Dame, Indiana 46556 (United States); Radiation Laboratory, University of Notre Dame, Indiana 46556 (United States)

2006-05-28T23:59:59.000Z

183

Absolute CF{sub 2} density and gas temperature measurements by absorption spectroscopy in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas  

SciTech Connect (OSTI)

Broadband ultraviolet absorption spectroscopy has been used to determine the CF{sub 2} radical density in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas, using the CF{sub 2} A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system of absorption spectrum. The rotational temperature of ground state CF{sub 2} and excited state CF was also estimated by using A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system and B{sup 2}??X{sup 2}? system, respectively. The translational gas temperature was deduced from the Doppler width of the Ar{sup *}({sup 3}P{sub 2}) and Ar{sup *}({sup 3}P{sub 0}) metastable atoms absorption line by using the tunable diode laser absorption spectroscopy. The rotational temperatures of the excited state CF are about 100?K higher than those of ground state CF{sub 2}, and about 200?K higher than the translational gas temperatures. The dependences of the radical CF{sub 2} density, electron density, electron temperature, rotational temperature, and gas temperature on the high frequency power and pressure have been analyzed. Furthermore, the production and loss mechanisms of CF{sub 2} radical and the gas heating mechanisms have also been discussed.

Liu, Wen-Yao; Xu, Yong, E-mail: yongxu@dlut.edu.cn; Peng, Fei; Gong, Fa-Ping; Li, Xiao-Song; Zhu, Ai-Min [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China); Liu, Yong-Xin; Wang, You-Nian [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

2014-10-15T23:59:59.000Z

184

Detection of single atoms by resonance ionization spectroscopy  

SciTech Connect (OSTI)

Rutherford's idea for counting individual atoms can, in principle, be implemented for nearly any type of atom, whether stable or radioactive, by using methods of resonance ionization. With the RIS technique, a laser is tuned to a wavelength which will promote a valence electron in a Z-selected atom to an excited level. Additional resonance or nonresonance photoabsorption steps are used to achieve nearly 100% ionization efficiencies. Hence, the RIS process can be saturated for the Z-selected atoms; and since detectors are available for counting either single electrons or positive ions, one-atom detection is possible. Some examples are given of one-atom detection, including that of the noble gases, in order to show complementarity with AMS methods. For instance, the detection of /sup 81/Kr using RIS has interesting applications for solar neutrino research, ice-cap dating, and groundwater dating. 39 refs., 7 figs., 2 tabs.

Hurst, G.S.

1986-01-01T23:59:59.000Z

185

The determination of some anions using ion chromatography and ion chromatography-graphite furnace atomic absorption spectrometry  

E-Print Network [OSTI]

THE DETERMINATION OF SOME ANIONS USING ION CHROMATOGRAPHY AND ION CHROMATOGRAPHY-GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY A Thesis by DANIEL C. J. HILLMAN Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1981 Major Subject: Chemistry THE DETERMINATION OF SOME ANIONS USING ION CHROMATOGRAPHY AND ION CHROMATOGRAPHY-GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY A Thesis by DANIEL C. J. HILLMAN...

Hillman, Daniel C

1981-01-01T23:59:59.000Z

186

Differential Optical Absorption Spectroscopy (DOAS) using Targets: SO 2 and NO 2 Measurements in Montevideo City  

Science Journals Connector (OSTI)

SO 2 and NO 2 were remotely measured in a main street of Montevideo city using Multiaxis?Differential Optical Absorption Spectroscopy (MAX?DOAS) combined with on?field selected targets. Target?based measurements are the basis of a new experimental procedure called Topographic Target Light scattering?DOAS (TOTAL?DOAS) that provides a well define absorption path to measure the near surface distribution of trace gases in the boundary layer. It combines the measurement principles of the long?path DOAS and zenith?scattered sunlight DOAS within the near UV and VIS spectral range. We give a general description of the procedure and present first results of the 2006 campaign at Montevideo.

Ilia Louban; Gustavo Píriz; Ulrich Platt; Erna Frins

2008-01-01T23:59:59.000Z

187

Reflection-Absorption Infrared Spectroscopy of Thin Films Using an External Cavity Quantum Cascade Laser  

SciTech Connect (OSTI)

We present experimental demonstrations using a broadly tunable external cavity quantum cascade laser (ECQCL) to perform Reflection-Absorption InfraRed Spectroscopy (RAIRS) of thin layers and residues on surfaces. The ECQCL compliance voltage was used to measure fluctuations in the ECQCL output power and improve the performance of the RAIRS measurements. Absorption spectra from self-assembled monolayers of a fluorinated alkane thiol and a thiol carboxylic acid were measured and compared with FTIR measurements. RAIRS spectra of the explosive compounds PETN, RDX, and tetryl deposited on gold substrates were also measured. Rapid measurement times and low noise were demonstrated, with < 1E-3 absorbance noise for a 10 second measurement time.

Phillips, Mark C.; Craig, Ian M.; Blake, Thomas A.

2013-02-04T23:59:59.000Z

188

Automated system for x-ray absorption spectroscopy of nanoparticle nucleation and growth  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) is a useful tool for studying nanoparticle synthesis and growth. Described here is a system for automating synthesis and data collection, allowing time-resolved XAS measurements at a synchrotron to be accurately combined with measurements made under identical conditions elsewhere, and promising the ability to use XAS with experiments in combinatorial chemistry. The primary components of this system are a commercial parallel processor and a custom flow cell. The system has been used to collect data on the synthesis of iron oxides from iron(II) acetylacetonate.

Calvin, S.; Carpenter, E.E.; Cestone, V.; Kurihara, L.K.; Harris, V.G.; Brown, E.C. [Naval Research Lab, Code 6360, Washington, DC 20375 (United States); Sarah Lawrence College, 1 Mead Way, Bronxville, New York 10708 (United States)

2005-01-01T23:59:59.000Z

189

SpectroWeb: Oscillator Strength Measurements of Atomic Absorption Lines in the Sun and Procyon  

E-Print Network [OSTI]

We update the online SpectroWeb database of spectral standard reference stars with 1178 oscillator strength values of atomic absorption lines observed in the optical spectrum of the Sun and Procyon (Alpha CMi A). The updated line oscillator strengths are measured with best fits to the disk-integrated KPNO-FTS spectrum of the Sun observed between 4000 A and 6800 A using state-of-the-art detailed spectral synthesis calculations. A subset of 660 line oscillator strengths is validated with synthetic spectrum calculations of Procyon observed with ESO-UVES between 4700 A and 6800 A. The new log(gf)-values in SpectroWeb are improved over the values offered in the online Vienna Atomic Line Database (VALD). We find for neutral iron-group elements, such as Fe I, Ni I, Cr I, and Ti I, a statistically significant over-estimation of the VALD log(gf)-values for weak absorption lines with normalized central line depths below 15 %. For abundant lighter elements (e.g. Mg I and Ca I) this trend is statistically not significantly detectable, with the exception of Si I for which the log(gf)-values of 60 weak and medium-strong lines are substantially decreased to best fit the observed spectra. The newly measured log(gf)-values are available in the SpectroWeb database at http://spectra.freeshell.org which interactively displays the observed and computed stellar spectra, together with corresponding atomic line data.

A. Lobel

2007-12-07T23:59:59.000Z

190

Effect of Atomic Coherence on Absorption in Four-level Systems: an Analytical study  

E-Print Network [OSTI]

Absorption profile of a four-level ladder atomic system interacting with three driving fields is studied perturbatively and analytical results are presented. Numerical results where the driving field strengths are treated upto all orders are presented. The absorption features is studied in two regimes, i) the weak middle transition coupling, i.e. $\\Omega_2 >\\Omega_{1,3}$. In case i), it is shown that the ground state absorption and the saturation characteristics of the population of level 2 reveal deviation due to the presence of upper level couplings. In particular, the saturation curve for the population of level 2 shows a dip for $\\Omega_1 = \\Omega_3$. While the populations of levels 3 and 4 show a maxima when this resonance condition is satisfied. Thus the resonance condition provides a criterion for maximally populating the upper levels. A second order perturbation calculation reveals the nature of this minima (maxima). In the second case, I report two important features: a) Filtering of the Aulter-Townes doublet in the three-peak absorption profile of the ground state, which is achieved by detuning only the upper most coupling field, and b) control of line-width by controlling the strength of the upper coupling fields. This filtering technique coupled with the control of linewidth could prove to be very useful for high resolution studies.

S N Sandhya

2006-10-09T23:59:59.000Z

191

Determination of boron isotope ratios by Zeeman effect background correction-graphite furnace atomic absorption spectrometry  

Science Journals Connector (OSTI)

A new method for the determination of isotopic ratio of boron using Zeeman effect background correction-graphite furnace atomic absorption spectrometry with conventional atomizer and natural-boron hollow cathode source is described. The isotope-shift Zeeman effect at 208.9 nm is utilized for isotopic ratio determination. At a given concentration of total boron, the net absorbance decreases linearly with increasing 10B/11B ratio. The absorbances are recorded at the field strength of 1.0 T. The isotope ratios measured by the proposed method were in good agreement with the results obtained by inductively coupled plasma-quadruple mass spectrometry or thermal ionization mass spectrometry. The present method is fairly fast and less expensive compared to the above techniques and is quite suitable for plant environments.

S. Thangavel; S.V. Rao; K. Dash; J. Arunachalam

2006-01-01T23:59:59.000Z

192

A Fern Fatale - X-ray Absorption Spectroscopy Imaging an Arsenic-Loving  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fern Fatale - X-ray Absorption Spectroscopy Imaging of an Arsenic-Loving Fern Fatale - X-ray Absorption Spectroscopy Imaging of an Arsenic-Loving Fern For many people, arsenic is synonymous with poison, so it is perhaps a surprise that some plants, such as the fern Pteris vittata (Figure 1) seem to quite deliberately accumulate large amounts of it. What is more, the plant converts it to the most toxic inorganic form known. How does it do this? First some background; while there is some evidence that arsenic is required for health [1], this is debatable. On the other hand, the poisonous nature of arsenic compounds was understood by the ancient Greeks and Romans, and it has been used throughout history as a homicidal and suicidal agent. It is found in two environmentally common oxy acids; arsenous acid (H3AsO3), and arsenic acid (H3AsO4), whose salts are known as arsenites and arsenates, respectively. Of these, the trivalent arsenic species are the most toxic. The infamous agent of murder is arsenic trioxide (white arsenic or As2O3), which is simply the (reputedly tasteless) anhydride of arsenous acid.

193

Resonant Absorption between Moving Atoms due to Doppler Frequency Shift and Quantum Energy Variation  

E-Print Network [OSTI]

By taking both the Doppler frequency shift for electromagnetic wave and the quantum energy variation of matter wave into consideration, a resonant-absorption condition based on the local-ether wave equation is presented to account for a variety of phenomena consistently, including the Ives-Stilwell experiment, the output frequency from ammonia masers, and the M\\"{o}ssbauer rotor experiment. It is found that in the resonant-absorption condition, the major term associated with the laboratory velocity is a dot-product term between this velocity and that of the emitting or absorbing atom. This term appears both in the Doppler frequency shift and the transition frequency variation and then cancels out. Thereby, the experimental results can be independent of the laboratory velocity and hence comply with Galilean relativity, despite the restriction that the involved velocities are referred specifically to the local-ether frame. However, by examining the resonant-absorption condition in the M\\"{o}ssbauer rotor experiment to a higher order, it is found that Galilean relativity breaks down.

Ching-Chuan Su

2002-08-23T23:59:59.000Z

194

Electron Spectroscopy for Atoms, Molecules, and Condensed Matter  

Science Journals Connector (OSTI)

...COPPER + SILVER - THEORY, PHYSICAL REVIEW...GASES, ARKIV FOR FYSIK 37 : 355 ( 1968...MOLECULAR CLUSTER THEORY OF CO CHEMISORPTION...NUMBER, ARKIV FOR FYSIK 26 : 248 ( 1964...interme-diate coupling theory as compared to the...electrons. Much of this basic work on atomic energy...

Kai Siegbahn

1982-07-09T23:59:59.000Z

195

Atomic Spectroscopy Planck's constant: h 6.62608 10  

E-Print Network [OSTI]

m sec := Conversion factors: nm 10 9- m:= pm 10 12- m:= aJ 10 18- joule:= Energy of a photon: Ephoton h= hc = Energy of the hydrogen atom: where n is a quantum number and can have integer values undergoes a transition from a higher to a lower energy state. Energy conservation requires Eatom initial

Rioux, Frank

196

E-Print Network 3.0 - atoms prevent degradation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Grafts Summary: control exhibited the most intense phosphate peaks. Strength Degradation Atomic Absorption Spectroscopy... @gmail.com Objective: To develop a ceramic material with...

197

E-Print Network 3.0 - argon plasma atomic Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

importance. A recent study of kineticsand decayprocesses in argon has shown that the 4s atomic... of an argon plasma by transient visible absorption spectroscopy from...

198

Instrument for x-ray absorption spectroscopy with in situ electrical control characterizations  

SciTech Connect (OSTI)

We report a synchrotron-based setup capable of performing x-ray absorption spectroscopy and x-ray magnetic circular dichroism with simultaneous electrical control characterizations. The setup can enable research concerning electrical transport, element- and orbital-selective magnetization with an in situ fashion. It is a unique approach to the real-time change of spin-polarized electronic state of a material/device exhibiting magneto-electric responses. The performance of the setup was tested by probing the spin-polarized states of cobalt and oxygen of Zn{sub 1-x}Co{sub x}O dilute magnetic semiconductor under applied voltages, both at low (?20 K) and room temperatures, and signal variations upon the change of applied voltage were clearly detected.

Huang, Chun-Chao; Chang, Shu-Jui; Yang, Chao-Yao; Tseng, Yuan-Chieh [Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan (China)] [Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan (China); Chou, Hsiung [Department of Physics, National Sun Yat-sen University, Kaohsiung, Taiwan (China)] [Department of Physics, National Sun Yat-sen University, Kaohsiung, Taiwan (China)

2013-12-15T23:59:59.000Z

199

Diamond sensors and polycapillary lenses for X-ray absorption spectroscopy  

SciTech Connect (OSTI)

Diamond sensors are evaluated as incident beam monitors for X-ray absorption spectroscopy experiments. These single crystal devices pose a challenge for an energy-scanning experiment using hard X-rays due to the effect of diffraction from the crystalline sensor at energies which meet the Bragg condition. This problem is eliminated by combination with polycapillary lenses. The convergence angle of the beam exiting the lens is large compared to rocking curve widths of the diamond. A ray exiting one capillary from the lens meets the Bragg condition for any reflection at a different energy from the rays exiting adjacent capillaries. This serves to broaden each diffraction peak over a wide energy range, allowing linear measurement of incident intensity over the range of the energy scan. Extended X-ray absorption fine structure data are measured with a combination of a polycapillary lens and a diamond incident beam monitor. These data are of comparable quality to data measured without a lens and with an ionization chamber monitoring the incident beam intensity.

Ravel, B. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States)] [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Attenkofer, K. [Photon Sciences Division, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States)] [Photon Sciences Division, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States); Bohon, J. [Center for Synchrotron Biosciences, Case Western Reserve University, Cleveland, Ohio 44106 (United States)] [Center for Synchrotron Biosciences, Case Western Reserve University, Cleveland, Ohio 44106 (United States); Muller, E. [Department of Physics and Astronomy, Stony Brook University, Stony Brook, New York 11974-3800 (United States)] [Department of Physics and Astronomy, Stony Brook University, Stony Brook, New York 11974-3800 (United States); Smedley, J. [Instrumentation Division, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States)] [Instrumentation Division, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States)

2013-10-15T23:59:59.000Z

200

An atomic hydrogen beam to test ASACUSA's apparatus for antihydrogen spectroscopy  

E-Print Network [OSTI]

The ASACUSA collaboration aims to measure the ground state hyperfine splitting (GS-HFS) of antihydrogen, the antimatter pendant to atomic hydrogen. Comparisons of the corresponding transitions in those two systems will provide sensitive tests of the CPT symmetry, the combination of the three discrete symmetries charge conjugation, parity, and time reversal. For offline tests of the GS-HFS spectroscopy apparatus we constructed a source of cold polarised atomic hydrogen. In these proceedings we report the successful observation of the hyperfine structure transitions of atomic hydrogen with our apparatus in the earth's magnetic field.

Diermaier, Martin; Kolbinger, Bernadette; Malbrunot, Chloé; Massiczek, Oswald; Sauerzopf, Clemens; Simon, Martin C; Wolf, Michael; Zmeskal, Johann; Widmann, Eberhard

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Indirect determination of microquantities of bromide ions in niobium germanide films by atomic absorption  

SciTech Connect (OSTI)

This paper presents a procedure for the determination of bromide ions in niobium germanide films on a copper support, prepared by the reduction of niobium and germanium bromides with hydrogen. The amount of bromine in the analyzed solutions after sorption was assessed from the mercury content by multiplying the mercury concentration by a factor of 2. An atomic-absorption spectrophotometer was used in the work and the photocurrent was recorded by means of a standard compensation recorder. A high-frequency electrodeless mercury lamp served as the light source. In order to check the correctness of analysis and to determine the error of the developed procedure, ''added found'' tests were carried out with the use of six quartz columns.

Chuchalina, L.S.

1986-08-01T23:59:59.000Z

202

State of Ni in catalysts for glycerol hydrogenation and methane steam reforming as studied by X-ray absorption spectroscopy  

Science Journals Connector (OSTI)

X-ray absorption spectroscopy is used to study 1% Ni/Al2O3, 5% Ni/Al2O3, and 5% Ni/TiO2 catalysts for glycerol and methane conversion. The effect of treatment in H2 under microwave irradiation on the reduction of...

O. P. Tkachenko; L. M. Kustov

2013-06-01T23:59:59.000Z

203

JW2A.78.pdf CLEO:2013 Technical Digest OSA 2013 Photonic Crystal Chemical Absorption Spectroscopy for  

E-Print Network [OSTI]

JW2A.78.pdf CLEO:2013 Technical Digest © OSA 2013 Photonic Crystal Chemical Absorption Spectroscopy crystals Techniques to detect and identify chemical and biological analytes based on photonic crystal (PC) platform have been investigated extensively in recent years. Many applications are working on the detection

Chen, Ray

204

PHYSICAL REVIEW A 89, 023408 (2014) High-spectral-resolution attosecond absorption spectroscopy of autoionization in xenon  

E-Print Network [OSTI]

formalism is introduced that correctly accounts for the observed energy dependence. DOI: 10.1103/PhysRevA.89PHYSICAL REVIEW A 89, 023408 (2014) High-spectral-resolution attosecond absorption spectroscopy Department of Physics, University of California, Berkeley, California, USA (Received 25 November 2013

Neumark, Daniel M.

205

SUBARU HIGH-RESOLUTION SPECTROSCOPY OF COMPLEX METAL ABSORPTION LINES OF THE QUASAR HS 1603+38201  

E-Print Network [OSTI]

SUBARU HIGH-RESOLUTION SPECTROSCOPY OF COMPLEX METAL ABSORPTION LINES OF THE QUASAR HS 1603-resolution spectrum of the quasar HS 1603+3820 (zem = 2.542), observed with the High Dispersion Spectrograph -- quasars: individual (HS 1603+3820) 1. INTRODUCTION The bright quasar HS 1603+3820 (zem = 2.542, B = 15

Iye, Masanori

206

Communications: Near edge x-ray absorption fine structure spectroscopy of aqueous adenosine triphosphate at the carbon and nitrogen  

E-Print Network [OSTI]

triphosphate at the carbon and nitrogen K-edges Daniel N. Kelly,1 Craig P. Schwartz,1,2 Janel S. Uejio,1 online xx xx xxxx Near edge x-ray absorption fine structure NEXAFS spectroscopy at the nitrogen-sphere association of Cu2+ did create observable broadening of the nitrogen spectrum, whereas outer

Cohen, Ronald C.

207

Light-induced polarization effects in atoms with partially resolved hyperfine structure and applications to absorption, fluorescence, and nonlinear magneto-optical rotation  

E-Print Network [OSTI]

Light-induced polarization effects in atoms with partially resolved hyperfine structure and applications to absorption, fluorescence, and nonlinear magneto-optical rotation M. Auzinsh* Department 9 November 2009 The creation and detection of atomic polarization is examined theoretically through

Auzinsh, Marcis

208

Aharonov-Bohm scattering of charged particles and neutral atoms: the role of absorption  

E-Print Network [OSTI]

The Aharonov-Bohm scattering of charged particles by the magnetic field of an infinitely long and infinitely thin solenoid (magnetic string) in an absorbing medium is studied. We discuss the partial-wave approach to this problem and show that standard partial-wave method can be adjusted to this case. The effect of absorption leads to oscillations of the AB cross section. Based on this we investigate the scattering of neutral atoms with induced electric dipole moments by a charge wire of finite radius which is placed in an uniform magnetic field. The physical realistic and practically important case that all atoms which collide with the wire are totally absorbed at its surface, is studied in detail. The dominating terms of the scattering amplitude are evaluated analytically for different physical constellations. The rest terms are written in a form suitable for a numerical computation. We show that if the magnetic field is absent, the absorbing charged wire causes oscillations of the cross section. In the presence of the magnetic field the cross section increases and the dominating Aharonov--Bohm peak appears in the forward direction, suppressing the oscillations.

Juergen Audretsch; Vladimir Skarzhinsky

1999-01-25T23:59:59.000Z

209

Low-Dimensional Water on Ru(0001)Model System for X-ray Absorption Spectroscopy Studies of Liquid Water  

SciTech Connect (OSTI)

We present an x-ray absorption spectroscopy results for fully broken to a complete H-bond network of water molecules on Ru(0001) by varying the morphology from isolated water molecules via two-dimensional clusters to a fully covered monolayer as probed by scanning tunneling microscopy. The sensitivity of x-ray absorption to the symmetry of H-bonding is further elucidated for the amino (-NH{sub 2}) group in glycine adsorbed on Cu(110) where the E-vector is parallel either to the NH donating an H-bond or to the non-H-bonded NH. The results give further evidence for the interpretation of the various spectral features of liquid water and for the general applicability of x-ray absorption spectroscopy to analyze H-bonded systems.

Nordlund, D

2012-02-14T23:59:59.000Z

210

Low-Dimensional Water on Ru(0001); Model System for X-ray Absorption Spectroscopy Studies of Liquid Water  

SciTech Connect (OSTI)

We present an x-ray absorption spectroscopy results for fully broken to a complete H-bond network of water molecules on Ru(0001) by varying the morphology from isolated water molecules via two-dimensional clusters to a fully covered monolayer as probed by scanning tunneling microscopy. The sensitivity of x-ray absorption to the symmetry of H-bonding is further elucidated for the amino (-NH{sub 2}) group in glycine adsorbed on Cu(110) where the E-vector is parallel either to the NH donating an H-bond or to the non-H-bonded NH. The results give further evidence for the interpretation of the various spectral features of liquid water and for the general applicability of x-ray absorption spectroscopy to analyze H-bonded systems.

Nordlund, D.; Ogasawara, H.; Andersson, K.J.; Tatarkhanov, M.; Salmeron, M.; Pettersson, L. G. M.; Nilsson, A.

2009-05-11T23:59:59.000Z

211

INFRARED ABSORPTION SPECTROSCOPY OF SURFACES: A LOW TEMPERATURE THERMAL DETECTION SCHEME  

E-Print Network [OSTI]

Frequency (l/CM) Fig. 5. Absorption spectrum of chemicallyFilm Frequency (l/CM) Fig. 6, Absorption spectrum of benzenei Fig. 7. -JU— (l/CM) Absorption spectrum of methane

Bailey, R. B.

2011-01-01T23:59:59.000Z

212

X-ray Absorption Spectroscopy Identifies Calcium-Uranyl-Carbonate Complexes at Environmental Concentrations  

SciTech Connect (OSTI)

Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO2-CO3 complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO2-CO3 complex. Such a complex might exist even at high calcium concentrations, as some UO2-CO3 complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 lM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO2-CO3 complex to approximately 0.6 and enables spectroscopic identification of the Na-UO2-CO3 complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations.

Kelly, Shelly D [Argonne National Laboratory (ANL); Kemner, Kenneth M [Argonne National Laboratory (ANL); Brooks, Scott C [ORNL

2007-01-01T23:59:59.000Z

213

Combined low-temperature scanning tunneling/atomic force microscope for atomic resolution imaging and site-specific force spectroscopy  

SciTech Connect (OSTI)

The authors present the design and first results of a low-temperature, ultrahigh vacuum scanning probe microscope enabling atomic resolution imaging in both scanning tunneling microscopy (STM) and noncontact atomic force microscopy (NC-AFM) modes. A tuning-fork-based sensor provides flexibility in selecting probe tip materials, which can be either metallic or nonmetallic. When choosing a conducting tip and sample, simultaneous STM/NC-AFM data acquisition is possible. Noticeable characteristics that distinguish this setup from similar systems providing simultaneous STM/NC-AFM capabilities are its combination of relative compactness (on-top bath cryostat needs no pit), in situ exchange of tip and sample at low temperatures, short turnaround times, modest helium consumption, and unrestricted access from dedicated flanges. The latter permits not only the optical surveillance of the tip during approach but also the direct deposition of molecules or atoms on either tip or sample while they remain cold. Atomic corrugations as low as 1 pm could successfully be resolved. In addition, lateral drifts rates of below 15 pm/h allow long-term data acquisition series and the recording of site-specific spectroscopy maps. Results obtained on Cu(111) and graphite illustrate the microscope's performance.

Schwarz, Udo; Albers, Boris J.; Liebmann, Marcus; Schwendemann, Todd C.; Baykara, Mehmet Z.; Heyde, Markus; Salmeron, Miquel; Altman, Eric I.; Schwarz, Udo D.

2008-02-27T23:59:59.000Z

214

Cavity induced modifications to the resonance fluorescence and probe absorption of a laser-dressed V atom  

E-Print Network [OSTI]

A cavity-modified master equation is derived for a coherently driven, V-type three-level atom coupled to a single-mode cavity in the bad cavity limit. We show that population inversion in both the bare and dressed-state bases may be achieved, originating from the enhancement of the atom-cavity interaction when the cavity is resonant with an atomic dressed-state transition. The atomic populations in the dressed state representation are analysed in terms of the cavity-modified transition rates. The atomic fluorescence spectrum and probe absorption spectrum also investigated, and it is found that the spectral profiles may be controlled by adjusting the cavity frequency. Peak suppression and line narrowing occur under appropriate conditions.

Jin-Sheng Peng; Gao-Xiang Li; Peng Zhou; S. Swain

2000-03-20T23:59:59.000Z

215

E-Print Network 3.0 - absorption spectroscopy diagnostics Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Domain Spectroscopy From... Industrial applications: spectroscopy, imaging and security Terahertz: Research and Applications 12... in a volume Measuring of moisture in a volume...

216

The Chemistry os Spent Nuclear Fuel From X-Ray Absorption Spectroscopy  

SciTech Connect (OSTI)

Present and future nuclear fuel cycles will require an understanding of the complex chemistry of trace fission products and transuranium actinides in spent nuclear fuel (SNF). Because of the unique analytical challenges presented by SNF to the materials scientist, many of its fundamental physical and chemical properties remain poorly understood, especially on the microscopic scale. Such an understanding of the chemical states of radionuclides in SNF would benefit development of technologies for fuel monitoring, fuel performance improvement and modeling, fuel reprocessing, and spent fuel storage and disposal. We have recently demonstrated the use of synchrotron x-ray absorption spectroscopy (XAS) to examine crystal chemical properties of actinides and fission products in extracted specimens of SNF. Information obtained includes oxidation state, chemical bond coordination, and quantitative elemental concentration and distribution. We have also used XAS in a scanning mode to obtain x-ray spectral micrographs with resolution approaching 1 micron. A brief overview of the technique will be presented, along with findings on uranium, plutonium, neptunium, technetium, and molybdenum in commercial PWR SNF specimens.

F.A. Fortner; A.J. Kropf; J.C. Cunnane

2006-09-21T23:59:59.000Z

217

Polarization of absorption lines as a diagnostics of circumstellar, interstellar and intergalactic magnetic fields: Fine structure atoms  

E-Print Network [OSTI]

The relative population of the fine structure sublevels of an atom's ground state is affected by radiative transitions induced by an anisotropic radiation flux. This causes the alignment of atomic angular momentum. In terms of observational consequences for the interstellar and intergalactic medium, this results in the polarization of the absorption lines. In the paper we consider the conditions necessary for this effect and provide calculations of polarization from a few astrophysically important atoms and ions with multiple upper and lower levels for an arbitrary orientation of magnetic fields to the a) source of optical pumping, b) direction of observation, c) absorbed source. We also consider an astrophysically important ``degenerate'' case when the source of optical pumping coincides with the source of the absorbed radiation. We present analytical expressions that relate the degree of linear polarization and the intensity of absorption to the 3D orientation of the magnetic field with respect to the pumping source, the source of the absorbed radiation, and the direction of observations. We discuss how all these parameters can be determined via simultaneous observations of several absorption lines and suggest graphical means that are helpful in practical data interpretation. We prove that studies of absorption line polarization provide a unique tool to study 3D magnetic field topology in various astrophysical conditions.

Huirong Yan; A. Lazarian

2006-11-09T23:59:59.000Z

218

Subwavelength atom localization via amplitude and phase control of the absorption spectrum. II  

E-Print Network [OSTI]

Interaction of the internal states of an atom with spatially dependent standing-wave cavity field can impart position information of the atom passing through it leading to subwavelength atom localization. We recently demonstrated a different regime...

Kapale, KT; Zubairy, M. Suhail.

2006-01-01T23:59:59.000Z

219

Time-resolved surface infrared spectroscopy during atomic layer deposition of TiO{sub 2} using tetrakis(dimethylamido)titanium and water  

SciTech Connect (OSTI)

Atomic layer deposition of titanium dioxide using tetrakis(dimethylamido)titanium (TDMAT) and water vapor is studied by reflection-absorption infrared spectroscopy (RAIRS) with a time resolution of 120?ms. At 190?°C and 240?°C, a decrease in the absorption from adsorbed TDMAT is observed without any evidence of an adsorbed product. Ex situ measurements indicate that this behavior is not associated with an increase in the impurity concentration or a dramatic change in the growth rate. A desorbing decomposition product is consistent with these observations. RAIRS also indicates that dehydroxylation of the growth surface occurs only among one type of surface hydroxyl groups. Molecular water is observed to remain on the surface and participates in reactions even at a relatively high temperature (110?°C) and with long purge times (30?s)

Sperling, Brent A., E-mail: brent.sperling@nist.gov; Hoang, John; Kimes, William A.; Maslar, James E. [Chemical Sciences Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8320, Gaithersburg, Maryland 20899-8320 (United States); Steffens, Kristen L. [Biomolecular Measurement Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8362, Gaithersburg, Maryland 20899-8362 (United States); Nguyen, Nhan V. [Semiconductor and Dimensional Metrology Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8120, Gaithersburg, Maryland 20899-8120 (United States)

2014-05-15T23:59:59.000Z

220

Differential laser absorption spectroscopy of uranium in an atmospheric pressure laser-induced plasma  

Science Journals Connector (OSTI)

A two-beam differential laser absorption technique is used to measure U238 absorption spectra with high signal-to-noise ratios in an atmospheric pressure laser-induced plasma....

Taylor, N R; Phillips, M C

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Chapter 1 - The Impacts of X-Ray Absorption Spectroscopy on Understanding Soil Processes and Reaction Mechanisms  

SciTech Connect (OSTI)

During the last two decades, X-ray absorption spectroscopy (XAS) has developed into a mature technique for obtaining the speciation (e.g., oxidation state) and short-range structure of elements present in soils and sediments. XAS encompasses both X-ray absorption near-edge structure (XANES) spectroscopy and extended X-ray absorption fine structure (EXAFS) spectroscopy. XAS has a number of advantageous qualities for studying soils and sediments, which include elemental specificity, sensitivity to the local chemical and structural state of an element, and the ability to analyze materials in situ. This information allows accurate determination of oxidation state, type of nearest neighbors, coordination number, bond distance, and orbital symmetries of the X-ray absorbing element. In this review, we examine the application of a wide variety of synchrotron X-ray techniques to fundamental issues in environmental soil chemistry. Additionally, we examine the application of microfocused and time-resolved XAS to determine speciation (e.g., oxidation state and/or local coordination environment) and transformation kinetics of contaminants in heterogeneous environmental systems. During the last three decades, XAS has a played a critical role in furthering our understanding of a myriad of environmental systems and will continue to do so into the foreseeable future.

Ginder-Vogel, Matthew; Sparks, Donald L. (Delaware)

2011-11-17T23:59:59.000Z

222

Combining Feedback Absorption Spectroscopy, Amplified Resonance and Low Pressure Sampling for the Measurement of Nitrogen-Containing Compounds in Automotive Emissions  

Broader source: Energy.gov [DOE]

Discusses a novel combination of multi-component scanning direct absorption spectroscopy, resonant cavity and low-pressure sampling to systematically improve the performance of a specific gas analyzer.

223

A tomographic technique for the simultaneous imaging of temperature, chemical species, and pressure in reactive flows using absorption spectroscopy with frequency-agile lasers  

E-Print Network [OSTI]

This paper proposes a technique that can simultaneously retrieve distributions of temperature, concentration of chemical species, and pressure based on broad bandwidth, frequency-agile tomographic absorption spectroscopy. The technique holds...

Cai, Weiwei; Kaminski, Clemens F.

2014-01-21T23:59:59.000Z

224

AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS  

E-Print Network [OSTI]

oxygen evolving capabilities. These preparations are reported to have 4-6 manganese atoms per photochemical reaction center(

Kirby, Jon Allan

2012-01-01T23:59:59.000Z

225

Proposed method for laser spectroscopy of pionic helium atoms to determine the charged-pion mass  

E-Print Network [OSTI]

Metastable pionic helium ($\\pi{\\rm He}^+$) is a three-body atom composed of a helium nucleus, an electron occupying the $1s$ ground state, and a negatively charged pion $\\pi^-$ in a Rydberg state with principal- and orbital angular momentum quantum numbers of $n\\sim \\ell+1\\sim 16$. We calculate the spin-independent energies of the $\\pi{\\rm ^3He}^+$ and $\\pi{\\rm ^4He}^+$ isotopes in the region $n=15$--19. These include relativistic and quantum electrodynamics corrections of orders $R_{\\infty}\\alpha^2$ and $R_{\\infty}\\alpha^3$ in atomic units, where $R_{\\infty}$ and $\\alpha$ denote the Rydberg and fine structure constants. The fine-structure splitting due to the coupling between the electron spin and the orbital angular momentum of the $\\pi^-$, and the radiative and Auger decay rates of the states are also calculated. Some states $(n,\\ell)=(16,15)$ and $(17,16)$ retain nanosecond-scale lifetimes against $\\pi^-$ absorption into the helium nucleus. We propose to use laser pulses to induce $\\pi^-$ transitions from these metastable states, to states with large ($\\sim 10^{11}$ s$^{-1}$) Auger rates. The $\\pi{\\rm He}^{2+}$ ion that remains after Auger emission of the $1s$ electron undergoes Stark mixing with the $s$, $p$, and $d$ states during collisions with the helium atoms in the experimental target. This leads to immediate nuclear absorption of the $\\pi^-$. The resonance condition between the laser beam and the atom is thus revealed as a sharp spike in the rates of neutrons, protons, deuterons, and tritons that emerge....(continued)

Masaki Hori; Anna Sótér; Vladimir I. Korobov

2014-04-30T23:59:59.000Z

226

Polarized X-Ray Absorption Spectroscopy of Single-Crystal Mn(V) Complexes Relevant to the Oxygen-Evolving Complex of Photosystem II  

SciTech Connect (OSTI)

High-valent Mn-oxo species have been suggested to have a catalytically important role in the water splitting reaction which occurs in the Photosystem II membrane protein. In this study, five- and six-coordinate mononuclear Mn(V) compounds were investigated by polarized X-ray absorption spectroscopy in order to understand the electronic structure and spectroscopic characteristics of high-valent Mn species. Single crystals of the Mn(V)-nitrido and Mn(V)-oxo compounds were aligned along selected molecular vectors with respect to the X-ray polarization vector using X-ray diffraction. The local electronic structure of the metal site was then studied by measuring the polarization dependence of X-ray absorption near-edge spectroscopy (XANES) pre-edge spectra (1s to 3d transition) and comparing with the results of density functional theory (DFT) calculations. The Mn(V)-nitrido compound, in which the manganese is coordinated in a tetragonally distorted octahedral environment, showed a single dominant pre-edge peak along the MnN axis that can be assigned to a strong 3dz2-4pz mixing mechanism. In the square pyramidal Mn(V)-oxo system, on the other hand, an additional peak was observed at 1 eV below the main pre-edge peak. This component was interpreted as a 1s to 3dxz,yz transition with 4px,y mixing, due to the displacement of the Mn atom out of the equatorial plane. The XANES results have been correlated to DFT calculations, and the spectra have been simulated using a TD (time-dependent)-DFT approach. The relevance of these results to understanding the mechanism of the photosynthetic water oxidation is discussed.

Yano, J.K.; Robblee, J.; Pushkar, Y.; Marcus, M.A.; Bendix, J.; Workman, J.M.; Collins, T.J.; Solomon, E.I.; George, S.D.; Yachandra, V.K.; /LBL, Berkeley /Copenhagen U. /Stanford U., Chem. Dept. /SLAC, SSRL

2007-10-16T23:59:59.000Z

227

Atomic-scale chemical quantification of oxide interfaces using energy-dispersive X-ray spectroscopy  

SciTech Connect (OSTI)

Atomic-scale quantification of chemical composition across oxide interfaces is important for understanding physical properties of epitaxial oxide nanostructures. Energy-dispersive X-ray spectroscopy (EDS) in an aberration-corrected scanning transmission electron microscope was used to quantify chemical composition across the interface of ferromagnetic La{sub 0.7}Sr{sub 0.3}MnO{sub 3} and antiferromagnetic BiFeO{sub 3} quantum structure. This research demonstrates that chemical composition at atomic columns can be quantified by Gaussian peak-fitting of EDS compositional profiles across the interface. Cation diffusion was observed at both A- and B-sublattice sites; and asymmetric chemical profiles exist across the interface, consistent with the previous studies.

Lu, Ping; Van Benthem, Mark [Sandia National Laboratories, P.O. Box 5800, MS 1411, Albuquerque, New Mexico 87185-1411 (United States)] [Sandia National Laboratories, P.O. Box 5800, MS 1411, Albuquerque, New Mexico 87185-1411 (United States); Xiong, Jie; Jia, Quanxi [Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2013-04-29T23:59:59.000Z

228

E-Print Network 3.0 - absorption infrared spectroscopy Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electron paramagnetic resonance spectroscopy to establish the technology needed... , terahertz radiation is between microwave and infrared. the dynamics of many important ......

229

Advances in X-Ray Chemical Analysis, Japan, 45 (2014) ISSN 0911-7806 Role of Infrared Absorption Spectroscopy in the Forensic Analysis of  

E-Print Network [OSTI]

Spectroscopy in the Forensic Analysis of Wakayama Curry Arsenic Poisoning Case Anthony T. TU and Jun KAWAI #12 80523, U. S. A. 606-8501 Role of Infrared Absorption Spectroscopy in the Forensic Analysis of Wakayama-8 X-ray fluorescence analysis was the key scientific evidence for the forensic analysis

Jun, Kawai

230

Design of a continuous-flow reactor for in situ x-ray absorption spectroscopy of solids in supercritical fluids  

SciTech Connect (OSTI)

This paper presents the design and performance of a novel high-temperature and high-pressure continuous-flow reactor, which allows for x-ray absorption spectroscopy or diffraction in supercritical water and other fluids under high pressure and temperature. The in situ cell consists of a tube of sintered, polycrystalline aluminum nitride, which is tolerant to corrosive chemical media, and was designed to be stable at temperatures up to 500 deg. C and pressures up to 30 MPa. The performance of the reactor is demonstrated by the measurement of extended x-ray absorption fine structure spectra of a carbon-supported ruthenium catalyst during the continuous hydrothermal gasification of ethanol in supercritical water at 400 deg. C and 24 MPa.

Dreher, M.; De Boni, E.; Nachtegaal, M.; Wambach, J.; Vogel, F. [Paul Scherrer Institut, 5232 Villigen PSI (Switzerland)

2012-05-15T23:59:59.000Z

231

X-ray-absorption spectroscopy investigation of the martensitic structural transformation in the RCu (R=rare earth) series  

Science Journals Connector (OSTI)

We present an x-ray-absorption spectroscopy (XAS) investigation performed at the L1,3 edges of the rare earth Y K edge and K and L2,3 edges of copper in several R-Cu intermetallic compounds: RCu (R=Y,Gd,Tb), Y1-xTbxCu, and Y1-xTbxCuyAg1-y. XAS spectra at the different absorption edges evidence the apparition of a strong electronic perturbation in the systems after the martensitic transformation. The dynamics of the structural transformation is discussed in terms of the interplay between the modification of both d-band widening and s-d transfer pressure.

Jesús Chaboy and M. R. Ibarra

1995-08-01T23:59:59.000Z

232

High energy resolution five-crystal spectrometer for high quality fluorescence and absorption measurements on an x-ray absorption spectroscopy beamline  

SciTech Connect (OSTI)

Fluorescence detection is classically achieved with a solid state detector (SSD) on x-ray absorption spectroscopy (XAS) beamlines. This kind of detection however presents some limitations related to the limited energy resolution and saturation. Crystal analyzer spectrometers (CAS) based on a Johann-type geometry have been developed to overcome these limitations. We have tested and installed such a system on the BM30B/CRG-FAME XAS beamline at the ESRF dedicated to the structural investigation of very dilute systems in environmental, material and biological sciences. The spectrometer has been designed to be a mobile device for easy integration in multi-purpose hard x-ray synchrotron beamlines or even with a laboratory x-ray source. The CAS allows to collect x-ray photons from a large solid angle with five spherically bent crystals. It will cover a large energy range allowing to probe fluorescence lines characteristic of all the elements from Ca (Z = 20) to U (Z = 92). It provides an energy resolution of 1-2 eV. XAS spectroscopy is the main application of this device even if other spectroscopic techniques (RIXS, XES, XRS, etc.) can be also achieved with it. The performances of the CAS are illustrated by two experiments that are difficult or impossible to perform with SSD and the complementarity of the CAS vs SSD detectors is discussed.

Llorens, Isabelle [CEA/DSM/INAC/SP2M/NRS, F-38054 Grenoble cedex 9 (France); Synchrotron SOLEIL - MARS beamline, L'Orme des Merisiers, F-91192 Gif sur Yvette (France); Lahera, Eric; Delnet, William; Proux, Olivier [Observatoire des Sciences de l'Univers de Grenoble, UMS 832 CNRS Universite Joseph Fourier, F-38041 Grenoble cedex 9 (France); BM30B/FAME beamline, ESRF, F-38043 Grenoble cedex 9 (France); Braillard, Aurelien; Hazemann, Jean-Louis; Prat, Alain; Testemale, Denis [BM30B/FAME beamline, ESRF, F-38043 Grenoble cedex 9 (France); Institut Neel, UPR 2940 CNRS, F-38042 Grenoble cedex 9 (France); Dermigny, Quentin; Gelebart, Frederic; Morand, Marc; Shukla, Abhay [Institut de Mineralogie et de Physique des Milieux Condenses, UMR 7590, 4 place Jussieu, F-75005 Paris (France); Bardou, Nathalie [Laboratoire de Photonique et de Nanostructures, UPR 20 CNRS, Route de Nozay, F-91460 Marcoussis (France); Ulrich, Olivier [CEA/DSM/INAC/SP2M/NRS, F-38054 Grenoble cedex 9 (France); BM32/IF beamline, ESRF, F-38043 Grenoble cedex 9 (France); Arnaud, Stephan; Berar, Jean-Francois; Boudet, Nathalie; Caillot, Bernard [Institut Neel, UPR 2940 CNRS, F-38042 Grenoble cedex 9 (France); BM02/D2AM beamline, ESRF, F-38043 Grenoble cedex 9 (France); Chaurand, Perrine; Rose, Jerome [Centre Europeen de Recherche et d'Enseignement des Geosciences de l'Environnement, UMR 7730, F-13545 Aix en Provence (France); and others

2012-06-15T23:59:59.000Z

233

A first principle study for the adsorption and absorption of carbon atom and the CO dissociation on Ir(100) surface  

SciTech Connect (OSTI)

We employ density functional theory to examine the adsorption and absorption of carbon atom as well as the dissociation of carbon monoxide on Ir(100) surface. We find that carbon atoms bind strongly with Ir(100) surface and prefer the high coordination hollow site for all coverages. In the case of 0.75?ML coverage of carbon, we obtain a bridging metal structure due to the balance between Ir–C and Ir–Ir interactions. In the subsurface region, the carbon atom prefers the octahedral site of Ir(100) surface. We find large diffusion barrier for carbon atom into Ir(100) surface (2.70 eV) due to the strong bonding between carbon atom and Ir(100) surface, whereas we find a very small segregation barrier (0.22 eV) from subsurface to the surface. The minimum energy path and energy barrier for the dissociation of CO on Ir(100) surface are obtained by using climbing image nudge elastic band. The energy barrier of CO dissociation on Ir(100) surface is found to be 3.01 eV, which is appreciably larger than the association energy (1.61 eV) of this molecule.

Erikat, I. A., E-mail: ihsanas@yahoo.com [Department of Physics, Jerash University, Jerash-26150 (Jordan); Hamad, B. A. [Department of Physics, The University of Jordan, Amman-11942 (Jordan)] [Department of Physics, The University of Jordan, Amman-11942 (Jordan)

2013-11-07T23:59:59.000Z

234

Atomic-Scale Imaging and Spectroscopy for In Situ Liquid Scanning Transmission Electron Microscopy  

SciTech Connect (OSTI)

Observation of growth, synthesis, dynamics and electrochemical reactions in the liquid state is an important yet largely unstudied aspect of nanotechnology. The only techniques that can potentially provide the insights necessary to advance our understanding of these mechanisms is simultaneous atomic-scale imaging and quantitative chemical analysis (through spectroscopy) under environmental conditions in the transmission electron microscope (TEM). In this study we describe the experimental and technical conditions necessary to obtain electron energy loss (EEL) spectra from a nanoparticle in colloidal suspension using aberration corrected scanning transmission electron microscopy (STEM) combined with the environmental liquid stage. At a fluid path length below 400 nm, atomic resolution images can be obtained and simultaneous compositional analysis can be achieved. We show that EEL spectroscopy can be used to quantify the total fluid path length around the nanoparticle, and demonstrate characteristic core-loss signals from the suspended nanoparticles can be resolved and analyzed to provide information on the local interfacial chemistry with the surrounding environment. The combined approach using aberration corrected STEM and EEL spectra with the in situ fluid stage demonstrates a plenary platform for detailed investigations of solution based catalysis and biological research.

Jungjohann, K. L.; Evans, James E.; Aguiar, Jeff; Arslan, Ilke; Browning, Nigel D.

2012-06-04T23:59:59.000Z

235

Direct and quantitative broadband absorptance micro/nano spectroscopy using FTIR and bilayer cantilever probes  

E-Print Network [OSTI]

Optical properties of micro/nano materials are important for many applications in biology, optoelectronics, and energy. In this thesis, a method is described to directly measure the quantitative absorptance spectra of ...

Hsu, Wei-Chun

2012-01-01T23:59:59.000Z

236

Spontaneous absorption of an accelerated hydrogen atom near a conducting plane in vacuum  

E-Print Network [OSTI]

We study, in the multipolar coupling scheme, a uniformly accelerated multilevel hydrogen atom in interaction with the quantum electromagnetic field near a conducting boundary and separately calculate the contributions of the vacuum fluctuation and radiation reaction to the rate of change of the mean atomic energy. It is found that the perfect balance between the contributions of vacuum fluctuations and radiation reaction that ensures the stability of ground-state atoms is disturbed, making spontaneous transition of ground-state atoms to excited states possible in vacuum with a conducting boundary. The boundary-induced contribution is effectively a nonthermal correction, which enhances or weakens the nonthermal effect already present in the unbounded case, thus possibly making the effect easier to observe. An interesting feature worth being noted is that the nonthermal corrections may vanish for atoms on some particular trajectories.

Hongwei Yu; Zhiying Zhu

2006-08-23T23:59:59.000Z

237

Subwavelength atom localization via amplitude and phase control of the absorption spectrum-II  

E-Print Network [OSTI]

Interaction of the internal states of an atom with spatially dependent standing-wave cavity field can impart position information of the atom passing through it leading to subwavelength atom localization. We recently demonstrated a new regime of atom localization [Sahrai {\\it et al.}, Phys. Rev. A {\\bf 72}, 013820 (2005)], namely sub-half-wavelength localization through phase control of electromagnetically induced transparency. This regime corresponds to extreme localization of atoms within a chosen half-wavelength region of the standing-wave cavity field. Here we present further investigation of the simplified model considered earlier and show interesting features of the proposal. We show how the model can be used to simulate variety of energy level schemes. Furthermore, the dressed-state analysis is employed to explain the emergence and suppression of the localization peaks, and the peak positions and widths. The range of parameters for obtaining clean sub-half-wavelength localization is identified.

Kishore T. Kapale; M. Suhail Zubairy

2005-09-09T23:59:59.000Z

238

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

W. A. Robb, and T. J. Spedding. Minor Elements in Oil Shaleand Oil-Shale Products. LERC RI 77-1, 1977. Bertine, K. K.From A Simulated In-Situ Oil Shale Retort. In: Procedings of

Girvin, D.G.

2011-01-01T23:59:59.000Z

239

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

Minor Elements in Oil Shale and Oil-Shale Products. LERC RIChemistry of Tar Sands and Oil Shale, ACS, New Orleans.Constituent Analysis of Oil Shale and Solvent-Refined Coal

Girvin, D.G.

2011-01-01T23:59:59.000Z

240

Atomic Resolution Mapping of the Excited-State Electronic Structure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mapping of the Excited-State Electronic Structure of Cu2O with Time-Resolved X-Ray Absorption Spectroscopy. Atomic Resolution Mapping of the Excited-State Electronic Structure of...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Atomic scattering spectroscopy for determination of the polarity of semipolar AlN grown on ZnO  

SciTech Connect (OSTI)

Determination of the polarity of insulating semipolar AlN layers was achieved via atomic scattering spectroscopy. The back scattering of neutralized He atoms on AlN surfaces revealed the atomic alignment of the topmost layers of semipolar AlN and the ZnO substrate. Pole figures of the scattering intensity were used to readily determine the polarity of these wurtzite-type semipolar materials. In addition, we found that +R-plane AlN epitaxially grows on ?R-plane ZnO, indicating that the polarity flips at the semipolar AlN/ZnO interface. This polarity flipping is possibly explained by the appearance of ?c and m-faces on the ?R ZnO surfaces, which was also revealed by atomic scattering spectroscopy.

Kobayashi, Atsushi; Ohta, Jitsuo [Institute of Industrial Science, The University of Tokyo, Tokyo 153-8505 (Japan)] [Institute of Industrial Science, The University of Tokyo, Tokyo 153-8505 (Japan); Ueno, Kohei; Oshima, Masaharu [Department of Applied Chemistry, The University of Tokyo, Tokyo 113-8656 (Japan) [Department of Applied Chemistry, The University of Tokyo, Tokyo 113-8656 (Japan); Synchrotron Radiation Research Organization, The University of Tokyo, Tokyo 113-8656 (Japan); Fujioka, Hiroshi, E-mail: hfujioka@iis.u-tokyo.ac.jp [Institute of Industrial Science, The University of Tokyo, Tokyo 153-8505 (Japan) [Institute of Industrial Science, The University of Tokyo, Tokyo 153-8505 (Japan); CREST, Japan Science and Technology Agency (JST), Tokyo 102-0076 (Japan)

2013-11-04T23:59:59.000Z

242

Improved graphite furnace atomizer  

DOE Patents [OSTI]

A graphite furnace atomizer for use in graphite furnace atomic absorption spectroscopy is described wherein the heating elements are affixed near the optical path and away from the point of sample deposition, so that when the sample is volatilized the spectroscopic temperature at the optical path is at least that of the volatilization temperature, whereby analyteconcomitant complex formation is advantageously reduced. The atomizer may be elongated along its axis to increase the distance between the optical path and the sample deposition point. Also, the atomizer may be elongated along the axis of the optical path, whereby its analytical sensitivity is greatly increased.

Siemer, D.D.

1983-05-18T23:59:59.000Z

243

Aspects of Graviton Detection: Graviton Emission and Absorption by Atomic Hydrogen  

E-Print Network [OSTI]

Graviton absorption cross sections and emission rates for hydrogen are calculated by both semi-classical and field theoretic methods. We point out several mistakes in the literature concerning spontaneous emission of gravitons and related phenomena, some of which are due to a subtle issue concerning gauge invariance of the linearized interaction Hamiltonian.

Stephen Boughn; Tony Rothman

2006-09-27T23:59:59.000Z

244

Absorption in Ultra-Peripheral Nucleus-Atom Collisions in Crystal  

E-Print Network [OSTI]

The Glauber theory description of particle- and nucleus-crystal Coulomb interactions at high-energy is developed. The allowance for the lattice thermal vibrations is shown to produce strong absorption effect which is of prime importance for quantitative understanding of the coherent Coulomb excitation of ultra-relativistic particles and nuclei passing through the crystal.

V. R. Zoller

2004-05-07T23:59:59.000Z

245

E-Print Network 3.0 - absorption rate mapping Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geosciences Page: << < 1 2 3 4 5 > >> Page: << < 1 2 3 4 5 > >> 41 Diode-laser-based atomic absorption monitor using frequency-modulation spectroscopy for physical vapor...

246

E-Print Network 3.0 - absorption spectrometry et-aas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

plant mitochon- Summary: -digested samples were analyzed for selenium by electrother- mal atomic absorption spectroscopy (ET-AAS; Perkin... -ICP-MS, and 166 (17) gL by ET-AAS vs...

247

Estimation of boron isotope ratios using high resolution continuum source atomic absorption spectrometry  

Science Journals Connector (OSTI)

In the production of 10B enriched steels, the production–recycling process needs to be closely monitored for inadvertent mix-up of materials with different B isotope levels. A quick and simple method for the estimation of boron isotope ratios in high alloyed steels using high resolution continuum source flame AAS (HR-CS-FAAS) was developed. On the 208.9 nm B line the wavelength of the peak absorption of 10B and 11B differs by 2.5 pm. The wavelength of the peak absorption of boron was determined by fitting a Gauss function through spectra simultaneously recorded by HR-CS-FAAS. It was shown that a linear correlation between the wavelength of the peak absorption and the isotope ratio exists and that this correlation is independent of the total boron concentration. Internal spectroscopic standards were used to compensate for monochromator drift and monochromator resolution changes. Accuracy and precision of the analyzed samples were thereby increased by a factor of up to 1.3. Three steel reference materials and one boric acid CRM, each certified for the boron isotope ratio were used to validate the procedure.

Helmar Wiltsche; Karl Prattes; Michael Zischka; Günter Knapp

2009-01-01T23:59:59.000Z

248

Atomic and Molecular Photoelectron and Auger Electron SpectroscopyStudies Using Synchrotron Radiation  

SciTech Connect (OSTI)

Electron spectroscopy, combined with synchrotron radiation, was used to measure the angular distributions of photoelectrons and Auger electrons from atoms and molecules as functions of photon energy. The branching ratios and partial cross sections were a 130 measured in certain cases. By comparison with theoretical calculations, the experimental results are interpreted in terms of the characteristic electronic structure and ionization dynamics of the atomic or molecular sample. The time structure of the synchrotron radiation source was used to record time-of-flight (TOF) spectra o f the ejected electrons. The ''a double-angle-TOF'' method for the measurement of photoelectron angular distributions is discussed. This technique offers the advantages of increased electron collect ion efficiency and the elimination of certain systematic errors. Several results were obtained for Xe using photon energies in the range hv {approx_equal} 60-190 eV, where excitation and ionization of the inner-subshell 4d electrons dominates. The 4d asymmetry parameter {beta} exhibits strong oscillations with energy, in agreement with several theoretical calculations. As predicted, the 5p asymmetry parameter was observed to deviate strongly from that calculated using the independent-electron model, due to intershell correlation with the 4d electrons.

Southworth, Stephen H.

1982-01-01T23:59:59.000Z

249

A method for measuring the rate of reaction by molecular microwave absorption spectroscopy  

E-Print Network [OSTI]

HsZcyHa Eyaew hlde ceaclcydeEn meea lwwy$aeJ cH che J w ywHues laJ c:H cH che cslaw ywHuesj LH lmwHsZcyHa Eyaew HO che ywHuesyo JyohEHsechnEeaew lse seZHsceJ ya che ldlyElmEe EyceslctseM 62 TABLE XII SOME ABSORPTION LINES CF CIS-l-CHLOROPROPENE-1...

Brown, Allan Neil

2013-10-04T23:59:59.000Z

250

X-ray absorption spectroscopy from H-passivated porous Si and oxidized Si nanocrystals  

SciTech Connect (OSTI)

Quantum confinement in nanoscale Si structures is widely believed to be responsible for the visible luminescence observed from anodically etched porous silicon (por-Si), but little is known about the actual size or shape of these structures. Extended x-ray absorption fine structure data from a wide variety of por-Si samples show significantly reduced average Si coordination numbers due to the sizable contribution of surface-coordinated H. (The IUSI ratios, as large as 1.2, were independently confirmed by ir-absorption and {alpha}-recoil measurements.) The Si coordinations imply very large surface/volume ratios, enabling the average Si structures to be identified as crystalline particles (not wires) whose dimensions are typically <15 {Angstrom}. Comparison of the size-dependent peak luminescence energies with those of oxidized Si nanocrystals, whose shapes are known, shows remarkable agreement. Furthermore, near-edge x-ray absorption fine structure measurements of the nanocrystals shows the outer oxide and interfacial suboxide layers to be constant over a wide range of nanocrystal sizes. The combination of these results effectively rules out surface species as being responsible for the observed visible luminescence in por-Si, and strongly supports quantum confinement as the dominant mechanism occurring in Si particles which are substantially smaller than previously reported or proposed.

Schuppler, S.; Marcus, M.A. [AT and T Bell Labs., Murray Hill, NJ (United States); Friedman, S.L. [Stanford Univ., Palo Alto, CA (United States). Dept. of Applied Physics] [and others

1994-11-01T23:59:59.000Z

251

Microsoft PowerPoint - SpectroscopyTechniques_EXAFS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

X-ray Absorption Fine Structure Spectroscopy (EXAFS) X-ray Absorption Fine Structure Spectroscopy (EXAFS) * Provides details on how x rays are absorbed by an atom at energies near X18A,B,X19A * Provides details on how x-rays are absorbed by an atom at energies near and above the core-level binding energies of that atom * Gives the modulation of an atom's x-ray absorption probability due to the chemical and physical state of the atom * Especially sensitive to the formal oxidation state, coordination chemistry, and the distances, coordination numbers, and species of the atoms immediately surrounding the selected element * Provides a practical, and relatively simple, way to determine the chemical state and local atomic structure for a selected atomic species

252

Three-photon-absorption spectroscopy in an indirect-gap material: CdI2  

Science Journals Connector (OSTI)

The three-photon absorption (3PA) spectrum of an indirect-gap material (CdI2) has been measured at 10 K by monitoring the resulting self-trapped-exciton emission. The contribution of excitonic transitions has been evidenced for excitation energies near the indirect gap, while the contribution of allowed and forbidden indirect transitions has been shown for excitation energies far from the gap. The spectral behavior of the 3PA coefficient has been described by parametric formulas, which are analogous to the ones successfully applied for 3PA in direct-gap materials.

M. Lepore; R. Tommasi; I. M. Catalano

1993-03-15T23:59:59.000Z

253

Nitrogen Doping and Thermal Stability in HfSiOxNy Studied by Photoemission and X-ray Absorption Spectroscopy  

SciTech Connect (OSTI)

We have investigated nitrogen-doping effects into HfSiO{sub x} films on Si and their thermal stability using synchrotron-radiation photoemission and x-ray absorption spectroscopy. N 1s core-level photoemission and N K-edge absorption spectra have revealed that chemical-bonding states of N-Si{sub 3-x}O{sub x} and interstitial N{sub 2}-gas-like features are clearly observed in as-grown HfSiO{sub x}N{sub y} film and they decrease upon ultrahigh vacuum (UHV) annealing due to a thermal instability, which can be related to the device performance. Annealing-temperature dependence in Hf 4f and Si 2p photoemission spectra suggests that the Hf-silicidation temperature is effectively increased by nitrogen doping into the HfSiO{sub x} although the interfacial SiO{sub 2} layer is selectively reduced. No change in valence-band spectra upon UHV annealing suggests that crystallization of the HfSiO{sub x}N{sub y} films is also hindered by nitrogen doping into the HfSiO{sub x}.

Toyoda, Satoshi; Okabayashi, Jun; Takahashi, Haruhiko; Oshima, Masaharu; /Tokyo U.; Lee, Dong-Ick; Sun, Shiyu; sun, Steven; Pianetta, Piero A.; /SLAC, SSRL; Ando, Takashi; Fukuda, Seiichi; /SONY, Atsugi

2005-12-14T23:59:59.000Z

254

Improvements on Decay Heat Summation Calculations by Means of Total Absorption Gamma-ray Spectroscopy Measurements  

SciTech Connect (OSTI)

The decay heat of fission products plays an important role in predictions of the heat released by nuclear fuel in reactors. In this contribution we present results of the analysis of the measurement of the beta decay of some refractory isotopes that were considered possible important contributors to the decay heat in reactors. The measurements presented here were performed at the IGISOL facility of the University of Jyvaeskylae, Finland. In our measurements we have combined for the first time a Penning trap (JYFLTRAP), which was used as a high resolution isobaric separator, with a total absorption spectrometer. The results of the measurements as well as their consequences for decay heat summation calculations are discussed.

Algora, A.; Sonzogni, A.; Algora, A.; Jordan, D.; Tain, J. L.; Rubio, B.; Agramunt, J.; Caballero, L.; Nacher, E.; Perez-Cerdan, A. B.; Molina, F.; Krasznahorkay, A.; Hunyadi, M. D.; Gulyas, J.; Vitez, A.; Csatlos, M.; Csige, L.; Aysto, J.; Penttila, H.; Rinta-Antila, S.; Moore, I.; Eronen, T.; Jokinen, A.; Nieminen, A.; Hakala, J.; Karvonen, P.; Kankainen, A.; Hager, U.; Sonoda, T.; Saastamoinen, A.; Rissanen, J.; Kessler, T.; Weber, C.; Ronkainen, J.; Rahaman, S.; Elomaa, V.; Burkard, K.; Hueller, W.; Batist, L.; Gelletly, W.; Yoshida, T.; Nichols, A. L.; Sonzogni, A.; Perajarvi, K.

2011-08-01T23:59:59.000Z

255

Auto-oligomerization and hydration of pyrrole revealed by x-ray absorption spectroscopy  

SciTech Connect (OSTI)

Near edge x-ray absorption fine structure (NEXAFS) spectra have been measured at the carbon and nitrogen K-edges of the prototypical aromatic molecule, pyrrole, both in the gas phase and when solvated in water, and compared with spectra simulated using a combination of classical molecular dynamics and first principles density functional theory in the excited state core hole approximation. The excellent agreement enabled detailed assignments. Pyrrole is highly reactive, particularly in water, and reaction products formed by the auto-oligomerization of pyrrole are identified. The solvated spectra have been measured at two different temperatures, indicating that the final states remain largely unaffected by both hydration and temperature. This is somewhat unexpected, since the nitrogen in pyrrole can donate a hydrogen bond to water.

Advanced Light Source; Schwartz, Craig P.; Uejio, Janel S.; Duffin, Andrew M.; England, Alice H.; Prendergast, David; Saykally, Richard J

2009-05-29T23:59:59.000Z

256

Polarized x-ray-absorption spectroscopy of the uranyl ion: Comparison of experiment and theory  

SciTech Connect (OSTI)

The x-ray linear dichroism of the uranyl ion (UO{sub 2}{sup 2+}) in uranium {ital L}{sub 3}-edge extended x-ray-absorption fine structure (EXAFS), and {ital L}{sub 1}- and {ital L}{sub 3}-edge x-ray-absorption near-edge structure (XANES), has been investigated both by experiment and theory. A striking polarization dependence is observed in the experimental XANES and EXAFS for an oriented single crystal of uranyl acetate dihydrate [UO{sub 2}(CH{sub 3}CO{sub 2}){sub 2}{center_dot}2H{sub 2}O], with the x-ray polarization vector aligned either parallel or perpendicular to the bond axis of the linear uranyl cation (O-U-O). Single-crystal results are compared to experimental spectra for a polycrystalline uranyl acetate sample and to calculations using the {ital ab} {ital initio} multiple-scattering (MS) code FEFF 6. Theoretical XANES spectra for uranyl fluoride (UO{sub 2}F{sub 2}) reproduce all the features of the measured uranyl acetate spectra. By identifying scattering paths which contribute to individual features in the calculated spectrum, a detailed understanding of the {ital L}{sub 1}-edge XANES is obtained. MS paths within the uranyl cation have a notable influence upon the XANES. The measured {ital L}{sub 3}-edge EXAFS is also influenced by MS, especially when the x-ray polarization is parallel to the uranyl species. These MS contributions are extracted from the total EXAFS and compared to calculations. The best agreement with the isolated MS signal is obtained by using nonoverlapped muffin-tin spheres in the FEFF 6 calculation. This contrasts the {ital L}{sub 1}-edge XANES calculations, in which overlapping was required for the best agreement with experiment. {copyright} {ital 1996 The American Physical Society.}

Hudson, E.A.; Allen, P.G.; Terminello, L.J. [Glenn T. Seaborg Institute for Transactinium Science, Lawrence Livermore National Laboratory, University of California, Livermore, California 94551 (United States)] [Glenn T. Seaborg Institute for Transactinium Science, Lawrence Livermore National Laboratory, University of California, Livermore, California 94551 (United States); Denecke, M.A.; Reich, T. [Institut fuer Radiochemie, Forschungszentrum Rossendorf, Postfach 510119, D-01314 Dresden (Germany)] [Institut fuer Radiochemie, Forschungszentrum Rossendorf, Postfach 510119, D-01314 Dresden (Germany)

1996-07-01T23:59:59.000Z

257

Direct Determination of Pyrite Content in Argonne Premium Coals by the Use of Sulfur X-ray Near Edge Absorption Spectroscopy (S-XANES)  

Science Journals Connector (OSTI)

Direct Determination of Pyrite Content in Argonne Premium Coals by the Use of Sulfur X-ray Near Edge Absorption Spectroscopy (S-XANES) ... Argonne National Laboratory, Argonne, Illinois 60439 ... Argonne premium coal samples are used by researchers worldwide as standards in coal research. ...

Trudy B. Bolin

2010-10-01T23:59:59.000Z

258

H-atom high-n Rydberg time-of-flight spectroscopy of CH bond fission in acrolein dissociated at 193 nm  

E-Print Network [OSTI]

H-atom high-n Rydberg time-of-flight spectroscopy of C­H bond fission in acrolein dissociated-atom velocity distribution from one- and multiple-photon dissociation processes in acrolein following excitation at 193 nm. The one-photon H-atom signal is dominated by primary C­H bond fission in acrolein. We compare

Butler, Laurie J.

259

Atomic-Scale Chemical Imaging via Combination of Scanning Tunneling and Electron Energy Loss Spectroscopies  

E-Print Network [OSTI]

systems at atomic level Develop atomically resolved chemical imaging platform via combination of lowAtomic-Scale Chemical Imaging via Combination of Scanning Tunneling and Electron Energy Loss visualization of chemical reaction pathways to provide mechanistic understanding for catalytically important

260

Arsine Evolution-Electrothermal Atomic Absorption Method for the Determination of Nanogram Levels of Total Arsenic in Urine and Water  

Science Journals Connector (OSTI)

......generator, and an electric-heated absorption...tion; and (d) an electric-heated absorption...arsenic electrodeless discharge lamp and a deuterium arc background corrector...of 20 mm/min. An electric-heated absorption......

Dennis H. Cox

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Reverse Monte Carlo analysis of the local order in liquid Ge{sub 0.15}Te{sub 0.85} alloys combining neutron scattering and x-ray absorption spectroscopy  

SciTech Connect (OSTI)

The structure of liquid Ge{sub 0.15}Te{sub 0.85} alloys that exhibit a density anomaly between 633 K and 733 K at ambient pressure was investigated using x-ray absorption spectroscopy at the Ge K edge. Using a reverse Monte Carlo method to combine the present results with neutron scattering data, we show that the volume contraction is associated with an increase of the first neighbor coordination number around both Ge and Te by about one atom. The coordination number of Ge increases from 3{+-}0.3 to 4.1{+-}0.3. These results support an interpretation of the density anomaly in terms of the same Peierls-like distortion mechanism acting in the liquid state and in the neighboring (pure Te and GeTe compound) phases.

Coulet, Marie-Vanessa; Testemale, Denis; Hazemann, Jean-Louis; Gaspard, Jean-Pierre; Bichara, Christophe [Laboratoire TECSEN, UMR 6122, CNRS-Universite Paul Cezanne, Campus de St Jerome, 13397 Marseille Cedex 20 (France); SNBL/ESRF, 6 rue Jules Horowitz, Boite Postale 220, 38043, Grenoble (France); Laboratoire de Cristallographie, 25 Avenue des Martyrs, Boite Postale 166, 38043 Grenoble (France) and European Synchroton Radiation Facility, 6 rue Jules Horowitz, Boite Postale 220, 38043 Grenoble (France); Physique de la Matiere Condensee, B5, Universite de Liege, B4000 Sart-Tilman (Belgium); Centre de Recherches en Matiere Condensee et Nanosciences-CNRS, Campus de Luminy, Case 913, F13288 Marseille (France)

2005-11-01T23:59:59.000Z

262

In Situ X-ray Absorption Near-Edge Structure Spectroscopy of ZnO Nanowire Growth During Chemical Bath Deposition  

SciTech Connect (OSTI)

Chemical bath deposition (CBD) offers a simple and inexpensive route to deposit semiconductor nanostructures, but lack of fundamental understanding and control of the underlying chemistry has limited its versatility. Here we report the first use of in situ X-ray absorption spectroscopy during CBD, enabling detailed investigation of both reaction mechanisms and kinetics of ZnO nanowire growth from zinc nitrate and hexamethylenetetramine (HMTA) precursors. Time-resolved X-ray absorption near-edge structure (XANES) spectra were used to quantify Zn(II) speciation in both solution and solid phases. ZnO crystallizes directly from [Zn(H{sub 2}O){sub 6}]{sup 2+} without long-lived intermediates. Using ZnO nanowire deposition as an example, this study establishes in situ XANES spectroscopy as an excellent quantitative tool to understand CBD of nanomaterials.

McPeak, Kevin M.; Becker, Matthew A.; Britton, Nathan G.; Majidi, Hasti; Bunker, Bruce A.; Baxter, Jason B. (Drexel); (Notre)

2010-12-03T23:59:59.000Z

263

Complexation of Lactate with Nd(III) and Eu(III) at Variable Temperatures: Studies by Potentiometry, Microcalorimetry, Optical Absorption and Luminescence Spectroscopy  

SciTech Connect (OSTI)

Complexation of neodymium(III) and europium(III) with lactate was studied at variable temperatures by potentiometry, absorption spectrophotometry, luminescence spectroscopy and microcalorimetry. Stability constants of three successive lactate complexes (ML{sup 2+}, ML{sup 2+} and ML{sub 3}(aq), where M stands for Nd and Eu, and L stands for lactate) at 10, 25, 40, 55 and 70 C were determined. The enthalpies of complexation at 25 C were determined by microcalorimetry. Thermodynamic data show that the complexation of trivalent lanthanides (Nd{sup 3+} and Eu{sup 3+}) with lactate is exothermic, and the complexation becomes weaker at higher temperatures. Results from optical absorption and luminescence spectroscopy suggest that the complexes are inner-sphere chelate complexes in which the protonated {alpha}-hydroxyl group of lactate participates in the complexation.

Tian, Guoxin; Martin, Leigh R.; Rao, Linfeng

2010-10-01T23:59:59.000Z

264

The BioCAT undulator beamline 18ID: A facility for biological non-crystalline diffraction and x-ray absorption spectroscopy at the APS  

SciTech Connect (OSTI)

The 18ID undulator beamline of the Biophysics Collaborative Access Team at the Advanced Photon Source, Argonne, IL, USA, is a high-performance instrument designed for, and dedicated to, the study of partially ordered and disordered biological materials using the techniques of small-angle X-ray scattering, fiber diffraction, and X-ray absorption spectroscopy. The beamline and associated instrumentation are described in detail and examples of the representative experimental results are presented.

Fischetti, R.; Stepanov, S.; Rosenbaum, G.; Barrea, R.; Black, E.; Gore, D.; Heurich, R.; Kondrashkina, E.; Kropf, A.J.; Wang, S.; Zhang, K.; Irving, T.C.; Bunker, G.B. (IIT); (Georgia)

2008-07-02T23:59:59.000Z

265

Limits on the temporal variation of the fine structure constant, quark masses and strong interaction from quasar absorption spectra and atomic clock experiments  

E-Print Network [OSTI]

We perform calculations of the dependence of nuclear magnetic moments on quark masses and obtain limits on the variation of $(m_q/\\Lambda_{QCD})$ from recent measurements of hydrogen hyperfine (21 cm) and molecular rotational transitions in quasar absorption systems, atomic clock experiments with hyperfine transitions in H, Rb, Cs, Yb$^+$, Hg$^+$ and optical transition in Hg$^+$. Experiments with Cd$^+$, deuterium/hydrogen, molecular SF$_6$ and Zeeman transitions in $^3$He/Xe are also discussed.

V. V. Flambaum; D. B. Leinweber; A. W. Thomas; R. D. Young

2004-02-10T23:59:59.000Z

266

Structure of the c(22) coverage of Cl on Ag(100): A controversy resolved by surface extended x-ray-absorption fine-structure spectroscopy  

Science Journals Connector (OSTI)

By performing surface extended x-ray-absorption fine-structure measurements, we have resolved the discrepancies between previously reported results for the adsorbate-substrate bond length in Ag(100)c(2×2)-Cl. The Cl atoms form a simple overlayer occupying the fourfold hollows of the silver surface with a Cl-Ag distance of 2.69±0.03 A?, in agreement with a published low-energy electron diffraction study, though with greater precision.

G. M. Lamble, R. S. Brooks, J. C. Campuzano, D. A. King, and D. Norman

1987-07-15T23:59:59.000Z

267

Characterization of gold nanoparticle films: Rutherford backscattering spectroscopy, scanning electron microscopy with image analysis, and atomic force microscopy  

SciTech Connect (OSTI)

Gold nanoparticle films are of interest in several branches of science and technology, and accurate sample characterization is needed but technically demanding. We prepared such films by DC magnetron sputtering and recorded their mass thickness by Rutherford backscattering spectroscopy. The geometric thickness d{sub g}—from the substrate to the tops of the nanoparticles—was obtained by scanning electron microscopy (SEM) combined with image analysis as well as by atomic force microscopy (AFM). The various techniques yielded an internally consistent characterization of the films. In particular, very similar results for d{sub g} were obtained by SEM with image analysis and by AFM.

Lansåker, Pia C., E-mail: pia.lansaker@angstrom.uu.se; Niklasson, Gunnar A.; Granqvist, Claes G. [Department of Engineering Sciences, The Ångström Laboratory, Uppsala University, P. O. Box 534, SE-751 21 Uppsala (Sweden); Hallén, Anders [Royal Institute of Technology, KTH-ICT, Elektrum 229, Kista, SE-164 40 Stockholm (Sweden)

2014-10-15T23:59:59.000Z

268

ETTORE MAJORANA FOUNDATION AND CENTRE FOR SCIENTIFIC CULTURE INTERNATIONAL SCHOOL OF ATOMIC AND MOLECULAR SPECTROSCOPY  

E-Print Network [OSTI]

. Spectroscopy with neutrons 13. Andries Meijerink, University of Utrecht, Utrecht, Doping the Dots 14. Gonul on the understanding luminescence phenomena using high pressure 20. Jingwen Zhang, Boston Applied Technologies, Inc

Huang, Jianyu

269

Multiplexed Selective Detection and Identification of TCE and Xylene in Water by On-Chip Absorption Spectroscopy  

E-Print Network [OSTI]

and identify chemical and biological analytes based on photonic crystal platform has been investigated more can do multiplexed detection of two different chemicals on one chip by using infrared absorption. Consequently, the absorption of these two chemicals can be enhanced by the slow light effect. The MMI structure

Chen, Ray

270

Infrared reflection absorption spectroscopy studies of CO adsorption on titania thin films and gold clusters supported on titania  

E-Print Network [OSTI]

absorptions at 2180cm?¹ and 2110cm?¹. The 2180cm?¹ peak is assigned to CO adsorbed on Ti?? sites The absorption at 2110cm?¹ appears to have at least two component peaks that may be from CO adsorbed on top of gold clusters and CO adsorbed at Au-TiO? interface...

White, Kevin Rodney

2012-06-07T23:59:59.000Z

271

Spatial Variability in the Ratio of Interstellar Atomic Deuterium to Hydrogen. I. Observations toward delta Orionis by the Interstellar Medium Absorption Profile Spectrograph  

E-Print Network [OSTI]

Studies of the abundances of deuterium in different astrophysical sites are of fundamental importance to answering the question about how much deuterium was produced during big bang nucleosynthesis and what fraction of it was destroyed later. With this in mind, we used the Interstellar Medium Absorption Profile Spectrograph (IMAPS) on the ORFEUS-SPAS II mission to observe at a wavelength resolution of 4 km/s (FWHM) the L-delta and L-epsilon absorption features produced by interstellar atomic deuterium in the spectrum of delta Ori A. A chi-square analysis indicated that 0.96 atomic ratio of D to H, we measured the L-alpha absorption features in 57 spectra of delta Ori in the IUE archive. From our measurement of N(H I)= 1.56e20 cm^{-2}, we found that N(D I)/N(H I)= 7.4(+1.9,-1.3)e-6 (90% confidence). Our result for D/H contrasts with the more general finding along other lines of sight that D/H is approximately 1.5e-5. The underabundance of D toward delta Ori A is not accompanied by an overabundance of N or O relative to H, as one might expect if the gas were subjected to more stellar processing than usual.

Edward B. Jenkins; Todd M. Tripp; Przemyslaw R. Wozniak; Ulysses J. Sofia; G. Sonneborn

1999-01-28T23:59:59.000Z

272

The electronic structure of poly(pyridine-2,5-diyl) investigated by soft x-ray absorption and emission spectroscopies  

E-Print Network [OSTI]

The electronic structure of the poly-pyridine conjugated polymer has been investigated by resonant and nonresonant inelastic X-ray scattering and X-ray absorption spectroscopies using synchrotron radiation. The measurements were made for both the carbon and nitrogen contents of the polymer. The analysis of the spectra has been carried out in comparison with molecular orbital calculations taking the repeat-unit cell as a model molecule of the polymer chain. The simulations indicate no significant differences in the absorption and in the non-resonant X-ray scattering spectra for the different isomeric geometries, while some isomeric dependence of the resonant spectra is predicted. The resonant emission spectra show depletion of the {\\pi} electron bands in line with symmetry selection and momentum conservation rules. The effect is most vizual for the carbon spectra; the nitrogen spectra are dominated by lone pair n orbital emission of {\\sigma} symmetry and are less frequency dependent.

Magnuson, M; Guo, J - H; Såthe, C; Agui, A; Nordgren, J; Luo, Y; Ågren, H; Johansson, N; Salaneck, W R; Horsburgh, L E; Monkman, A P; 10.1016/S0301-0104(98)00262-6

2012-01-01T23:59:59.000Z

273

Femtosecond laser-induced modification of potassium-magnesium silicate glasses: An analysis of structural changes by near edge x-ray absorption spectroscopy  

SciTech Connect (OSTI)

The effects of femtosecond laser pulse irradiation on the glass structure of alkaline silicate glasses were investigated by x-ray absorption near edge structure spectroscopy using the beamline of the Physikalisch-Technische Bundesanstalt at the electron synchrotron BESSY II in Berlin (Germany) by analyzing the magnesium K-edge absorption peak for different laser fluences. The application of fluences above the material modification threshold (2.1 J/cm{sup 2}) leads to a characteristic shift of {approx}1.0 eV in the K-edge revealing a reduced ({approx}3%) mean magnesium bond length to the ligated oxygen ions (Mg-O) along with a reduced average coordination number of the Mg ions.

Seuthe, T.; Eberstein, M. [Fraunhofer-Institut fuer Keramische Technologien und Systeme (IKTS), Winterbergstrasse 28, 01277 Dresden (Germany); Hoefner, M.; Eichler, H. J.; Grehn, M. [Technische Universitaet Berlin, Institut fuer Optik und Atomare Physik, Strasse des 17. Juni 135, 10623 Berlin (Germany); Reinhardt, F. [Physikalisch-Technische Bundesanstalt (PTB), Abbestr. 2-12, 10587 Berlin (Germany); Tsai, W. J. [ITRI South, Industrial Technology Research Institute, 8 Gongyan Rd., Liu-jia District, Tainan City 73445, Taiwan (China); Bonse, J. [BAM Bundesanstalt fuer Materialforschung und - pruefung, Unter den Eichen 87, 12205 Berlin (Germany)

2012-05-28T23:59:59.000Z

274

Spin noise spectroscopy to probe quantum states of ultracold fermionic atom gases  

SciTech Connect (OSTI)

We theoretically demonstrate that optical measurements of electron spin noise can be a spectroscopic probe of the entangled quantum states of ultracold fermionic atom gases and unambiguously reveal the detailed nature of the underlying interatomic correlations. Different models of the effective interatomic interactions predict entirely new sets of resonances in the spin noise spectrum. Once the correct effective interatomic interaction model is identified, the detailed noise line shapes of the spin noise can be used to constrain this model. We estimate the magnitude of spin noise signals expected in ultracold fermionic atom gases via noise measurements in classical alkali vapors, which demonstrate the feasibility of this approach.

Mihaila, Bogdan; Blagoev, Krastan B.; Smith, Darryl L. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Crooker, Scott A.; Rickel, Dwight G. [National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Littlewood, Peter B. [Cavendish Laboratory, Madingley Road, Cambridge CB3 0HE (United Kingdom)

2006-12-15T23:59:59.000Z

275

Quantitative broadband absorption and scattering spectroscopy in turbid media by combined frequency-domain and steady state methodologies  

DOE Patents [OSTI]

A technique for measuring broadband near-infrared absorption spectra of turbid media that uses a combination of frequency-domain and steady-state reflectance methods. Most of the wavelength coverage is provided by a white-light steady-state measurement, whereas the frequency-domain data are acquired at a few selected wavelengths. Coefficients of absorption and reduced scattering derived from the frequency-domain data are used to calibrate the intensity of the steady-state measurements and to determine the reduced scattering coefficient at all wavelengths in the spectral window of interest. The absorption coefficient spectrum is determined by comparing the steady-state reflectance values with the predictions of diffusion theory, wavelength by wavelength. Absorption spectra of a turbid phantom and of human breast tissue in vivo, derived with the combined frequency-domain and steady-state technique, agree well with expected reference values.

Tromberg, Bruce J. (Irvine, CA); Berger, Andrew J. (Rochester, NY); Cerussi, Albert E. (Lake Forest, CA); Bevilacqua, Frederic (Costa Mesa, CA); Jakubowski, Dorota (Irvine, CA)

2008-09-23T23:59:59.000Z

276

The Radio to Infrared Emission of Very High Redshift Gamma-Ray Bursts: Probing Early Star Formation through Molecular and Atomic Absorption Lines  

E-Print Network [OSTI]

We evaluate the broadband afterglow emission of very high redshift gamma-ray bursts (GRBs) using standard relativistic blastwave models with both forward and reverse shock components. For a broad range of parameters, a generic property for GRBs at redshifts $z \\sim$ 5--30 is that the emission peaks in the millimeter to far-infrared bands with milli-Jansky flux levels, first at a few hours after the burst due to the reverse shock, and then again for several days afterwards with somewhat lower flux due to the forward shock. The radio, submillimeter and infrared continuum emission should be readily detectable out to $z \\ga 30$ by the Atacama Large Millimeter Array (ALMA), Extended Very Large Array (EVLA), Square Kilometer Array (SKA) and other facilities. For relatively bright bursts, spectroscopic measurements of molecular and atomic absorption lines due to ambient protostellar gas may be possible. Utilizing models of primordial protostellar clouds, we show that under certain conditions, appreciable absorption may be caused by HD rotational transitions even in metal-free environments. After sufficient metal enrichment, absorption from CO rotational transitions and [OI] fine-structure transitions can also become strong. With appropriate observing strategies in combination with optical telescopes, ALMA and/or SKA may be able to detect such lines, offering a unique probe of physical conditions in individual Pop III and early Pop II star forming regions. We also remark on potential near-infrared absorption features due to electronic transitions of H$_2$.

Susumu Inoue; Kazuyuki Omukai; Benedetta Ciardi

2007-07-14T23:59:59.000Z

277

Atomic force microscope with combined FTIR-Raman spectroscopy having a micro thermal analyzer  

DOE Patents [OSTI]

An atomic force microscope is provided that includes a micro thermal analyzer with a tip. The micro thermal analyzer is configured for obtaining topographical data from a sample. A raman spectrometer is included and is configured for use in obtaining chemical data from the sample.

Fink, Samuel D. (Aiken, SC); Fondeur, Fernando F. (North Augusta, SC)

2011-10-18T23:59:59.000Z

278

Precision Spectroscopy of Deeply Bound Pionic Atoms and Partial Restoration of Chiral Symmetry in Medium  

Science Journals Connector (OSTI)

......Atoms in (d,3He) Nuclear Reactions. Exp. proposal...in 122Sn(d,3He) Nuclear Reaction. Exp. proposal...4Nishina Center for Accelerator-Based Science, RIKEN...5School of Physics and Nuclear Energy Engineering...the study of the QCD vacuum structure.1) One......

Natsumi Ikeno; Rie Kimura; Junko Yamagata-Sekihara; Hideko Nagahiro; Daisuke Jido; Kenta Itahashi; Li Sheng Geng; Satoru Hirenzaki

2011-09-01T23:59:59.000Z

279

Experimental Projects for Spectroscopy of Pionic Atoms and N*(1535) in Nuclei  

Science Journals Connector (OSTI)

......Atoms in (d, 3He) Nuclear Reactions (2006...deeply-bound kaonic nuclear states by in-flight...RIKEN Nishina Center for Accelerator-Based Science, Wako...link between QCD and nuclear physics in the lowest...nuclear density to that in vacuum.9)11) This article......

Kenta Itahashi

2010-10-01T23:59:59.000Z

280

Atomic Resolution Coordination Mapping in Ca2FeCoO5 Brownmillerite by Spatially Resolved Electron Energy-Loss Spectroscopy  

Science Journals Connector (OSTI)

Using a combination of high-angle annular dark field scanning transmission electron microscopy and atomically resolved electron energy-loss spectroscopy at high energy resolution in an aberration-corrected electron microscope, we demonstrate the capability of coordination mapping in complex oxides. ... (b) Survey image indicating the area used for octahedral (red) and tetrahedral (blue) data summation (3 pixel width). ... B atoms that have energetic preference for tetrahedral coordination geometry are esp. ...

Stuart Turner; Johan Verbeeck; Farshid Ramezanipour; John E. Greedan; Gustaaf Van Tendeloo; Gianluigi A. Botton

2012-04-25T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

U. Thumm et al., to appear in "Handbook of Photonics" (Wiley Blackwell 2014) Resubmitted 10/4/2013 Attosecond Physics: Attosecond Streaking Spectroscopy of Atoms  

E-Print Network [OSTI]

U. Thumm et al., to appear in "Handbook of Photonics" (Wiley Blackwell 2014) ­ Resubmitted 10/4/2013 1 Chapter x Attosecond Physics: Attosecond Streaking Spectroscopy of Atoms and Solids Uwe Thumm1 Kienberger2,4 1 J.R. Macdonald Laboratory, Physics Department, Kansas-State University, Manhattan, KS66506

Thumm, Uwe

282

Quantitative study of spin noise spectroscopy in a classical gas of {sup 41}K atoms  

SciTech Connect (OSTI)

We present a general derivation of the electron spin noise power spectrum in alkali gases as measured by optical Faraday rotation, which applies to both classical gases at high temperatures as well as ultracold quantum gases. We show that the spin-noise power spectrum is determined by an electron spin-spin correlation function, and we find that measurements of the spin-noise power spectra for a classical gas of {sup 41}K atoms are in good agreement with the predicted values. Experimental and theoretical spin noise spectra are directly and quantitatively compared in both longitudinal and transverse magnetic fields up to the high magnetic-field regime (where Zeeman energies exceed the intrinsic hyperfine energy splitting of the {sup 41}K ground state)

Mihaila, Bogdan [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Crooker, Scott A.; Rickel, Dwight G. [National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Blagoev, Krastan B.; Smith, Darryl L. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Littlewood, Peter B. [Cavendish Laboratory, Madingley Road, Cambridge CB3 0HE (United Kingdom)

2006-10-15T23:59:59.000Z

283

Quantitative study of spin noise spectroscopy in a classical gas of K41 atoms  

Science Journals Connector (OSTI)

We present a general derivation of the electron spin noise power spectrum in alkali gases as measured by optical Faraday rotation, which applies to both classical gases at high temperatures as well as ultracold quantum gases. We show that the spin-noise power spectrum is determined by an electron spin-spin correlation function, and we find that measurements of the spin-noise power spectra for a classical gas of K41 atoms are in good agreement with the predicted values. Experimental and theoretical spin noise spectra are directly and quantitatively compared in both longitudinal and transverse magnetic fields up to the high magnetic-field regime (where Zeeman energies exceed the intrinsic hyperfine energy splitting of the K41 ground state).

Bogdan Mihaila; Scott A. Crooker; Dwight G. Rickel; Krastan B. Blagoev; Peter B. Littlewood; Darryl L. Smith

2006-10-30T23:59:59.000Z

284

Electron Core-Hole Interaction in the X-Ray Absorption Spectroscopy of 3d Transition Metals  

Science Journals Connector (OSTI)

A fully relativistic scheme is presented that allows one to deal with the electronic band structure of a solid and the influence of the electron core-hole interaction on its x-ray absorption spectra on the same level. This is achieved in a parameter-free way by working throughout in the framework of the time-dependent density functional theory and linear response formalism. Application to the L2,3-absorption spectra of 3d transition metals demonstrates that the electron core-hole interaction intermixes the L2 and L3 partial spectra, strongly affecting the so-called branching ratio. The consequences of this for the magnetic circular x-ray dichroism sum rules are discussed.

J. Schwitalla and H. Ebert

1998-05-18T23:59:59.000Z

285

Inner-shell electron spectroscopy and chemical properties of atoms and small molecules  

SciTech Connect (OSTI)

The program has been concerned with gas-phase carbon 1s photoelectron spectroscopy of a number of molecules of potential chemical interest. The primary goals have been to determine carbon 1s ionization energies with a view of relating these to other chemical properties such as electronegativity, acidity, basicity, and reactivity, in order to provide a better understanding of these fundamental properties. The role of electron-donating (methyl) and electron-withdrawing (fluoro) substituents on the carbon 1s ionization energies of substituted benzenes has been studied., and these results have been related to measurements of the reactivities of the same molecule as well as to their affinities for protons (basicity). Opportunities for investigation in unplanned areas have arisen, and the program has been modified to take advantage of these. One has been the realization that, under certain circumstances, inner-shell ionization energies may depend on the molecular conformation. Several examples of this phenomenon have been investigated and it has been shown that this technique provides a tool for the measurement of the energy differences between different conformers of the same substance. The other has been the demonstration that photoelectron recoil can lead to the excitation of vibrational modes that are forbidden in the normal view of photoemission and to rotational heating of the molecule that increases with the energy of the exciting radiation.

T. Darrah Thomas

2009-01-21T23:59:59.000Z

287

Neutron spectroscopy of H impurities in PdD: Covibrations of the H and D atoms  

Science Journals Connector (OSTI)

Three powder samples of solid isotopic solutions PdD1?xHx with x=0.050, 0.072, and 0.091 are prepared under high pressure, and the spectra of their optical vibrations are studied by inelastic neutron scattering at ambient pressure and 5 K using the high-luminosity IN1-BeF spectrometer at ILL, Grenoble. These spectra are shown to be well represented by a linear combination of a contribution from the undisturbed matrix of stoichiometric PdD and a contribution due to the H impurity. The optical spectrum of PdD consists of a strong peak at 37 meV with a shoulder extending to 65 meV. The spectrum due to the H impurity is composed of a broad peak of defect H modes centered at 68 meV and superimposed on a broad N-shaped feature with a range of negative intensity near 36 meV and a shallow maximum at 45 meV. Simulations using the Born-von Kármán model show that this unusual feature is a result of the formation of a band of optical vibrations of the D and H atoms with equal frequencies (covibrations) caused by H-D interactions.

V. E. Antonov; A. I. Davydov; V. K. Fedotov; A. S. Ivanov; A. I. Kolesnikov; M. A. Kuzovnikov

2009-10-15T23:59:59.000Z

288

Study of hard disk and slider surfaces using X-ray photoemission electron microscopy and near-edge X-ray absorption fine structure spectroscopy  

SciTech Connect (OSTI)

X-ray Photo Emission Electron Microscopy (X-PEEM) and Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy were applied to study the properties of amorphous hard carbon overcoats on disks and sliders, and the properties of the lubricant. The modification of lubricants after performing thermal desorption studies was measured by NEXAFS, and the results are compared to the thermal desorption data. The study of lubricant degradation in wear tracks is described. Sliders were investigated before and after wear test, and the modification of the slider coating as well as the transfer of lubricant to the slider was studied. The studies show that the lubricant is altered chemically during the wear. Fluorine is removed and carboxyl groups are formed.

Anders, S.; Stammler, T. [Lawrence Berkeley National lab., CA (United States). Advanced Light Source Div.; Bhatia, C.S. [SSD/IBM, San Jose, CA (United States); Stoehr, J. [IBM Research Div., San Jose, CA (United States). Almaden Research Center; Fong, W.; Chen, C.Y.; Bogy, D.B. [Univ. of California, Berkeley, CA (United States)

1998-04-01T23:59:59.000Z

289

Setup for in situ investigation of gases and gas/solid interfaces by soft x-ray emission and absorption spectroscopy  

SciTech Connect (OSTI)

We present a novel gas cell designed to study the electronic structure of gases and gas/solid interfaces using soft x-ray emission and absorption spectroscopies. In this cell, the sample gas is separated from the vacuum of the analysis chamber by a thin window membrane, allowing in situ measurements under atmospheric pressure. The temperature of the gas can be regulated from room temperature up to approximately 600?°C. To avoid beam damage, a constant mass flow can be maintained to continuously refresh the gaseous sample. Furthermore, the gas cell provides space for solid-state samples, allowing to study the gas/solid interface for surface catalytic reactions at elevated temperatures. To demonstrate the capabilities of the cell, we have investigated a TiO{sub 2} sample behind a mixture of N{sub 2} and He gas at atmospheric pressure.

Benkert, A., E-mail: andreas.benkert@kit.edu, E-mail: l.weinhardt@kit.edu [Institute for Photon Science and Synchrotron Radiation, Karlsruhe Institute of Technology (KIT), Hermann-v.-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Gemeinschaftslabor für Nanoanalytik, Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe (Germany); Blum, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Meyer, F. [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany)] [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Wilks, R. G. [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany)] [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Yang, W. [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)] [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Bär, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Insitut für Physik und Chemie, Brandenburgische Technische Universität Cottbus-Senftenberg, Konrad-Wachsmann-Allee 1, 03046 Cottbus (Germany); and others

2014-01-15T23:59:59.000Z

290

The Journey from Classical to Quantum Thinking: An Analysis of Student Understanding Through the Lens of Atomic Spectra  

E-Print Network [OSTI]

certain  aspects  of  atomic  absorption  of  light  in  About  Atomic  Absorption  of  Light……………..…………. …  71  questions  about  atomic   absorption  and  emission  of  

Rao, Sandhya Kolla

2012-01-01T23:59:59.000Z

291

Note: Application of a pixel-array area detector to simultaneous single crystal x-ray diffraction and x-ray absorption spectroscopy measurements  

SciTech Connect (OSTI)

X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are two main x-ray techniques in synchrotron radiation facilities. In this Note, we present an experimental setup capable of performing simultaneous XRD and XAS measurements by the application of a pixel-array area detector. For XRD, the momentum transfer in specular diffraction was measured by scanning the X-ray energy with fixed incoming and outgoing x-ray angles. By selecting a small fixed region of the detector to collect the XRD signal, the rest of the area was available for collecting the x-ray fluorescence for XAS measurements. The simultaneous measurement of XRD and X-ray absorption near edge structure for Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film was demonstrated as a proof of principle for future time-resolved pump-probe measurements. A static sample makes it easy to maintain an accurate overlap of the X-ray spot and laser pump beam.

Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov; Brewe, Dale L.; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Chen, Jing-Sheng; Chow, G. M. [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore)] [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore) [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Department of Physics, National University of Singapore, 117542 Singapore (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, 117575 Singapore (Singapore)

2014-04-15T23:59:59.000Z

292

7 -ATOMIC PROCESSES Atomic processes can be  

E-Print Network [OSTI]

1 7 - ATOMIC PROCESSES Atomic processes can be: 1. Scattering 2. Absorption/Thermal Emission scattering, although the results won't change much when this condition is relaxed. Absorption/Thermal Emission Free-free (continuum) ("Bremsstrahlung") Emission/Absorption #12;2 Bound-Bound & Bound

Sitko, Michael L.

293

7 -ATOMIC PROCESSES Atomic processes can be  

E-Print Network [OSTI]

1 7 - ATOMIC PROCESSES Atomic processes can be: 1. Scattering 2. Absorption/Thermal Emission scattering, although the results won't change much when this condition is relaxed. #12;2 Absorption/Thermal Emission Free-free (continuum) ("Bremsstrahlung") Emission/Absorption Bound-Bound & Bound-Free Processes

Sitko, Michael L.

294

A Laboratory-based Hard X-ray Monochromator for High-Resolution X-ray Emission Spectroscopy and X-ray Absorption Near Edge Structure Measurements  

E-Print Network [OSTI]

We report the development of a laboratory-based Rowland-circle monochromator that incorporates a low poer x-ray (bremsstrahlung) tube source, a spherically-bent crystal analyzer (SBCA), and an energy-resolving solid-state detector. This relatively inexpensive, introductory level instrument achieves 1-eV energy resolution for photon energies of 5 keV to 10 keV while also dmeonstrating a net efficiency previously seen only in laboratory monochromators having much coarser energy resolution. Despite the use of only a compact, air-cooled 10 W x-ray tube, we find count rates for nonresonant x-ray emission spectroscopy (XES) comparable to those achived at monochromatized spectroscopy beamlines at synchrotron light sources. For x-ray absorption near edge structure (XANES), the monochromatized flux is small (due to the use of a low-powered x-ray generator) but still useful for routine transmission-mode studies of concentrated samples. These results indicate that upgrading to a standard commercial high-powered line-foc...

Seidler, G T; Remesnik, A J; Pacold, J I; Ball, N A; Barry, N; Styczinski, M; Hoidn, O R

2014-01-01T23:59:59.000Z

295

Tunneling spectroscopy of superconducting MoN and NbTiN grown by atomic layer deposition  

SciTech Connect (OSTI)

A tunneling spectroscopy study is presented of superconducting MoN and Nb{sub 0.8}Ti{sub 0.2}N thin films grown by atomic layer deposition (ALD). The films exhibited a superconducting gap of 2?meV and 2.4?meV, respectively, with a corresponding critical temperature of 11.5?K and 13.4?K, among the highest reported T{sub c} values achieved by the ALD technique. Tunnel junctions were obtained using a mechanical contact method with a Au tip. While the native oxides of these films provided poor tunnel barriers, high quality tunnel junctions with low zero bias conductance (below ?10%) were obtained using an artificial tunnel barrier of Al{sub 2}O{sub 3} on the film's surface grown ex situ by ALD. We find a large critical current density on the order of 4?×?10{sup 6}?A/cm{sup 2} at T?=?0.8T{sub c} for a 60?nm MoN film and demonstrate conformal coating capabilities of ALD onto high aspect ratio geometries. These results suggest that the ALD technique offers significant promise for thin film superconducting device applications.

Groll, Nickolas R., E-mail: ngroll@anl.gov; Klug, Jeffrey A.; Claus, Helmut; Pellin, Michael J.; Proslier, Thomas, E-mail: proslier@anl.gov [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Cao, Chaoyue; Becker, Nicholas G.; Zasadzinski, John F. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Physics, Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Altin, Serdar [Fen Edebiyat Fakultesi, Fizik Bolumu, Inonu Universitesi, 44280 Malatya (Turkey)

2014-03-03T23:59:59.000Z

296

Simulating Cl K-edge X-ray absorption spectroscopy in MCl62- (M= U, Np, Pu) complexes and UOCl5- using time-dependent density functional theory  

SciTech Connect (OSTI)

We report simulations of the X-ray absorption near edge structure (XANES) at the Cl K-edge of actinide hexahalides MCl62- (M = U, Np, Pu) and the UOCl5- complex using linear-response time-dependent density functional theory (LR-TDDFT) extended for core excitations. To the best of our knowledge, these are the first calculations of the Cl K-edge spectra of NpCl62- and PuCl62-. In addition, the spectra are simulated with and without the environmental effects of the host crystal as well as ab initio molecular dynamics (AIMD) to capture the dynamical effects due to atomic motion. The calculated spectra are compared with experimental results, where available and the observed trends are discussed.

Govind, Niranjan; De Jong, Wibe A.

2014-02-21T23:59:59.000Z

297

Direct solid sample analysis with graphite furnace atomic absorption spectrometry—A fast and reliable screening procedure for the determination of inorganic arsenic in fish and seafood  

Science Journals Connector (OSTI)

Abstract Direct solid sample analysis with graphite furnace atomic absorption spectrometry (SS-GF AAS) was investigated initially with the intention of developing a method for the determination of total As in fish and other seafood. A mixture of 0.1% Pd+0.06% Mg+0.06% Triton X-100 was used as the chemical modifier, added in solution over the solid samples, making possible the use of pyrolysis and atomization temperatures of 1200 °C and 2400 °C, respectively. The sample mass had to be limited to 0.25 mg, as the integrated absorbance did not increase further with increasing sample mass. Nevertheless, the recovery of As from several certified reference materials was of the order of 50% lower than the certified value. Strong molecular absorption due to the phosphorus monoxide molecule (PO) was observed with high-resolution continuum source AAS (HR CS AAS), which, however, did not cause any spectral interference. A microwave-assisted digestion with HNO3/H2O2 was also investigated to solve the problem; however, the results obtained for several certified reference materials were statistically not different from those found with direct SS-GF AAS. Accurate values were obtained using inductively coupled plasma mass spectrometry (ICP-MS) to analyze the digested samples, which suggested that organic As compounds are responsible for the low recoveries. HPLC–ICP-MS was used to determine the arsenobetaine (AB) concentration. Accurate results that were not different from the certified values were obtained when the AB concentration was added to the As concentration found by SS-GF AAS for most certified reference materials (CRM) and samples, suggesting that SS-GF AAS could be used as a fast screening procedure for inorganic As determination in fish and seafood.

Ariane V. Zmozinski; Toni Llorente-Mirandes; Isabel C.F. Damin; José F. López-Sánchez; Maria Goreti R. Vale; Bernhard Welz; Márcia M. Silva

2015-01-01T23:59:59.000Z

298

Laser produced plasma diagnostics by cavity ringdown spectroscopy and applications  

SciTech Connect (OSTI)

Laser-produced plasmas have many applications for which detailed characterization of the plume is requested. Cavity ring-down spectroscopy is a versatile absorption method which provides data on the plume and its surroundings, with spatial and temporal resolution. The measured absorption line shapes contain information about angular and velocity distributions within the plume. In various plasmas we have observed molecules or metastable atoms which were not present in the emission spectra.

Milosevic, S. [Institute of Physics, Zagreb (Croatia)

2012-05-25T23:59:59.000Z

299

Photocatalytic Activity of Bulk TiO{sub 2} Anatase and Rutile Single Crystals Using Infrared Absorption Spectroscopy  

SciTech Connect (OSTI)

A systematic study on the photocatalytic activity of well-defined, macroscopic bulk single-crystal TiO{sub 2} anatase and rutile samples has been carried out, which allows us to link photoreactions at surfaces of well-defined oxide semiconductors to an important bulk property with regard to photochemistry, the life time of e-h pairs generated in the bulk of the oxides by photon absorption. The anatase (101) surface shows a substantially higher activity, by an order of magnitude, for CO photo-oxidation to CO{sub 2} than the rutile (110) surface. This surprisingly large difference in activity tracks the bulk e-h pair lifetime difference for the two TiO{sub 2} modifications as determined by contactless transient photoconductance measurements on the corresponding bulk materials.

Xu Mingchun; Gao Youkun [Department of Physical Chemistry I, Ruhr-Universitaet Bochum, 44780 (Germany); Moreno, Elias Martinez; Kunst, Marinus [Hahn-Meitner-Institut, Glienicker Strasse 100, D-1000 Berlin 39 (Germany); Muhler, Martin [Laboratory of Industrial Chemistry, Ruhr-Universitaet Bochum, 44780 (Germany); Wang Yuemin [Department of Physical Chemistry I, Ruhr-Universitaet Bochum, 44780 (Germany); Laboratory of Industrial Chemistry, Ruhr-Universitaet Bochum, 44780 (Germany); Idriss, Hicham [Department of Chemistry, University of Aberdeen and School of Engineering, Robert Gordon University, AB24 3EU Aberdeen, Scotland (United Kingdom); Woell, Christof [Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe (Germany)

2011-04-01T23:59:59.000Z

300

Educational Multiwavelength Atomic Emission Spectrometer  

E-Print Network [OSTI]

atomic absorption is the capability for simultaneous multielement analysis. It can be used colleges had acquired atomic absorption instruments by the year 1990.[2] In contrast, atomic emission with the acetylene-air flame source taken from an existing atomic absorption instrument. Two spectrometer units

Nazarenko, Alexander

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Hydrogen absorption in epitaxial W/Nb(001) and polycrystalline Fe/Nb(110) multilayers studied in-situ by X-ray/neutron scattering techniques and X-ray absorption spectroscopy  

SciTech Connect (OSTI)

Hydrogen can be absorbed in large quantities by 100 {angstrom} thin Nb layers embedded in epitaxial W/Nb and polycrystalline Fe/Nb multilayers. The solubility and the hydrogen-induced structural changes of the host lattice are explored in-situ by small-angle neutron/X-ray reflectometry and high-angle diffraction. These measurements reveal for both systems that the relative out-of-plane expansion of the Nb layers is considerably larger than the relative increase of the Nb interplanar spacing indicating two distinctly different mechanisms of hydrogen absorption. In Fe/Nb multilayers, hydrogen expands the Nb interplanar spacing in a continuous way as function of the external pressure. In contrast, the Nb lattice expansion is discontinuous in epitaxial W/Nb multilayers: A jump in the Nb(002) Bragg reflection position occurs at a critical hydrogen pressure of 1 mbar. In-situ EXAFS spectroscopy also exhibits an irreversible expansion of the Nb lattice in the film plane for p{sub H{sub 2}}> 1 mbar. This can be regarded as a structural phase transition from an exclusively out-of-plane to a three-dimensionally expanded state at low and high hydrogen pressures, respectively.

Klose, F.; Rehm, C.; Fieber-Erdmann, M.; Holub-Krappe, E.; Bleif, H. J.; Sowers, H.; Goyette, R.; Troger, L.; Maletta, H.

1999-11-02T23:59:59.000Z

302

Echelle Spectroscopy of QSO Absorption Line Systems with Metals in the Direction of HS 1700+6416  

E-Print Network [OSTI]

We present a high signal-to-noise high resolution spectrum of the radio-quiet QSO HS1700+6416 (z = 2.72). Analysis of the absorption line systems with metals yields the following results. (1) The dense cluster of C IV doublets at 2.432 -0.95 and [Al/H] > -0.96 for the strongest component of this absorber. Abundances of three other Lyman limit absorbers are also derived from photoionization models. (3) Unsaturated C IV and rather strong N V are detected in the associated absorber at z(abs) = 2.7125. The apparent column density profiles indicate that N V is affected by unresolved saturation or that the N V absorbing gas does not completely cover the QSO flux source. From photoionization models we derive [N/H] > -0.65 and [C/H] > -0.82. (4) We tentatively conclude that the number of Mg II systems detected per unit redshift is dominated by weak Mg II lines with rest equivalent width less than 0.3 A.

Tripp, T M; Savage, B D; Tripp, Todd M.; Lu, Limin; Savage, Blair D.

1997-01-01T23:59:59.000Z

303

Outcomes of Chronic Arsenic Exposure on Aquatic Insects  

E-Print Network [OSTI]

electrothermal atomic absorption spectrometry. AnalyticaHydride Generated Atomic Absorption Spectroscopy (HGAAS) andHydride Generated Atomic Absorption Spectroscopy (HGAAS).

Mogren, Christina Loraine

2013-01-01T23:59:59.000Z

304

Validity of automated x-ray photoelectron spectroscopy algorithm to determine the amount of substance and the depth distribution of atoms  

Science Journals Connector (OSTI)

The author reports a systematic study of the range of validity of a previously developed algorithm for automated x-ray photoelectron spectroscopy analysis which takes into account the variation in both peak intensity and the intensity in the background of inelastically scattered electrons. This test was done by first simulating spectra for the Au4d peak with gold atoms distributed in the form of a wide range of nanostructures which includes overlayers with varying thickness a 5?Å layer of atoms buried at varying depths and a substrate covered with an overlayer of varying thickness. Next the algorithm was applied to analyze these spectra. The algorithm determines the number of atoms within the outermost 3 ? of the surface. This amount of substance is denoted AOS 3 ? (where ?   is the electron inelastic mean free path). In general the determined AOS 3 ? is found to be accurate to within ?10–20% depending on the depth distribution of the atoms. The algorithm also determines a characteristic length L which was found to give unambiguous information on the depth distribution of the atoms for practically all studied cases. A set of rules for this parameter which relates the value of L to the depths where the atoms are distributed was tested and these rules were found to be generally valid with only a few exceptions. The results were found to be rather independent of the spectral energy range (from 20 to 40?eV below the peak energy) used in the analysis.

Sven Tougaard

2013-01-01T23:59:59.000Z

305

Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite I: X-ray absorption extended fine structure spectroscopy analysis  

Science Journals Connector (OSTI)

“Two-line” ferrihydrite samples precipitated and then exposed to a range of aqueous Zn solutions (10?5 to 10?3 M), and also coprecipitated in similar Zn solutions (pH 6.5), have been examined by Zn and Fe K-edge X-ray absorption spectroscopy. Typical Zn complexes on the surface have Zn-O distances of 1.97(.02) Å and coordination numbers of about 4.0(0.5), consistent with tetrahedral oxygen coordination. This contrasts with Zn-O distances of 2.11(.02) Å and coordination numbers of 6 to 7 in the aqueous Zn solutions used in sample preparation. X-ray absorption extended fine structure spectroscopy (EXAFS) fits to the second shell of cation neighbors indicate as many as 4 Zn-Fe neighbors at 3.44(.04) Å in coprecipitated samples, and about two Zn-Fe neighbors at the same distance in adsorption samples. In both sets of samples, the fitted coordination number of second shell cations decreases as sorption density increases, indicating changes in the number and type of available complexing sites or the onset of competitive precipitation processes. Comparison of our results with the possible geometries for surface complexes and precipitates suggests that the Zn sorption complexes are inner sphere and at lowest adsorption densities are bidentate, sharing apical oxygens with adjacent edge-sharing Fe(O,OH)6 octahedra. Coprecipitation samples have complexes with similar geometry, but these are polydentate, sharing apices with more than two adjacent edge-sharing Fe(O,OH)6 polyhedra. The results are inconsistent with Zn entering the ferrihydrite structure (i.e., solid solution formation) or formation of other Zn-Fe precipitates. The fitted Zn-Fe coordination numbers drop with increasing Zn density with a minimum of about 0.8(.2) at Zn/(Zn + Fe) of 0.08 or more. This change appears to be attributable to the onset of precipitation of zinc hydroxide polymers with mainly tetrahedral Zn coordination. At the highest loadings studied, the nature of the complexes changes further, and a second type of precipitate forms. This has a structure based on a brucite layer topology, with mainly octahedral Zn coordination. Amorphous zinc hydroxide samples prepared for comparison had a closely similar local structure. Analysis of the Fe K-edge EXAFS is consistent with surface complexation reactions and surface precipitation at high Zn loadings with little or no Fe-Zn solid solution formation. The formation of Zn-containing precipitates at solution conditions two or more orders of magnitude below their solubility limit is compared with other sorption and spectroscopic studies that describe similar behavior.

G.A Waychunas; C.C Fuller; J.A Davis

2002-01-01T23:59:59.000Z

306

Time-Resolved Quantitative Measurement of OH HO2 and CH2O in Fuel Oxidation Reactions by High Resolution IR Absorption Spectroscopy.  

SciTech Connect (OSTI)

Combined with a Herriott-type multi-pass slow flow reactor, high-resolution differential direct absorption spectroscopy has been used to probe, in situ and quantitatively, hydroxyl (OH), hydroperoxy (HO 2 ) and formaldehyde (CH 2 O) molecules in fuel oxidation reactions in the reactor, with a time resolution of about 1 micro-second. While OH and CH 2 O are probed in the mid-infrared (MIR) region near 2870nm and 3574nm respectively, HO 2 can be probed in both regions: near-infrared (NIR) at 1509nm and MIR at 2870nm. Typical sensitivities are on the order of 10 10 - 10 11 molecule cm -3 for OH at 2870nm, 10 11 molecule cm -3 for HO 2 at 1509nm, and 10 11 molecule cm -3 for CH 2 O at 3574nm. Measurements of multiple important intermediates (OH and HO 2 ) and product (CH 2 O) facilitate to understand and further validate chemical mechanisms of fuel oxidation chemistry.

Huang, Haifeng; Rotavera, Brandon; Taatjes, Craig A.

2014-08-01T23:59:59.000Z

307

Determination of extractable arsenic in soils using slurry sampling-on-line microwave extraction-hydride generation-atomic absorption spectrometry  

Science Journals Connector (OSTI)

A flow injection procedure has been developed for the determination of acid-extractable arsenic in soils by hydride generation atomic absorption spectrometry. Several parameters, including acid and borohydride concentrations, exposure time to microwave energy, and the microwave power applied, were optimized. The on-line microwave extraction increased the recovery of the adsorbed arsenic significantly; whereas, preparation of the slurry in 10% hydrochloric acid instead of water increased the recovery only when the microwave oven was off. Low recoveries, which were investigated by removing the hydride generation manifold and connecting the system via an on-line filter to an inductively coupled plasma mass spectrometer, were due to the irreversible adsorption of arsenic on the soil. This irreversible adsorption does not allow standard additions calibration. The solution detection limit was 0.2 ?g l?1 for a 212-?l injection loop, corresponding to 7 ng g?1 in solid for a 2.5% m/v slurry prepared in 25 ml.

Hakan Gürleyük; Julian F. Tyson; Peter C Uden

2000-01-01T23:59:59.000Z

308

E-Print Network 3.0 - absorption spectrometry etaas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

With Confirmation of Accuracy by Inductively Coupled Plasma Mass Spectrometry and Atomic Absorption Spectrometry... -LEAFS uses absorption; graphite furnace; inductively...

309

Femtosecond Absorption Spectroscopy of Transition  

E-Print Network [OSTI]

Department of Chemistry, Michigan State University, East Lansing, Michigan 48824 Received May 6, 2003 in the study of photoinduced charge-transfer processes2 as well as the quest for achieving efficient solar

McCusker, James K.

310

E-Print Network 3.0 - absorption spectrometry faas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Marco A. Z. Arruda* Summary: for metal determination is normally carried out by flame atomic absorption spectrometry (FAAS). The main... atomic absorption spectrometry (FAAS)...

311

E-Print Network 3.0 - absorption spectrom- etry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Summary: is used to digest samples and elements are determined by spike-height flame atomic absorption spectrom... Block Digestion and Spike-Height Flame Atomic Absorption...

312

Pressure Broadening of H2O Absorption Lines in the 1.3 ?m Region Measured by Continuous Wave-Cavity Ring-Down Spectroscopy: Application in the Trace Detection of Water Vapor in N2, SiH4, CF4, and PH3  

Science Journals Connector (OSTI)

A continuous wave cavity ring-down (cw-CRD) spectrometer has been developed for the measurement of trace levels of water vapor by absorption spectroscopy at wavelengths in the...

Fiadzomor, Phyllis A Y; Baker, Derek M; Keen, Anthony M; Grant, Robert B; Orr-Ewing, Andrew J

2008-01-01T23:59:59.000Z

313

E-Print Network 3.0 - absorption spectrometry configurations...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

314

E-Print Network 3.0 - absorption spectrometry analyticalmethod...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

315

EMSL - Spectroscopy and Diffraction  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

loss spectroscopy and electron backscatter diffraction Local Electrode Atom Probe tomography system with 355 nm UV laser and reflectron flight path for high mass resolution...

316

X-RAY ABSORPTION STUDIES OF GRAPHITE INTERCALATES AND METAL-AMMONIA SOLUTION  

E-Print Network [OSTI]

I. INTRODUCTION A. X-Ray Absorption Spectroscopy B. Graphiteacknowledged. The X-Ray absorption data could not have beenI INTRODUCTION X-ray absorption, spectroscopy (XAS) has been

Robertson, A.S.

2010-01-01T23:59:59.000Z

317

Transient Xray absorption features in GRBs 1 Transient XRay Absorption in GRBs  

E-Print Network [OSTI]

due to photoelectric absorption or other atomic processes.) The transient nature of the absorptionTransient X­ray absorption features in GRBs 1 Transient X­Ray Absorption in GRBs and its Abstract The recent detection of a transient absorption feature in the prompt emission of GRB 990705 has

Boettcher, Markus

318

Precision Atomic Spectroscopy for Improved Limits on Variation of the Fine Structure Constant and Local Position Invariance  

E-Print Network [OSTI]

Alamos National Laboratory, Los Alamos, New Mexico 87545, USA 2 Time and Frequency Division MS 847 in normalized solar gravitational potential. The same frequency ratio is also used to obtain 20-fold improvement between well-resolved and relatively unperturbed atomic energy levels currently report among the highest

319

Relativistic atomic beam spectroscopy 2. Appendix A: Progress report, July 1, 1989--June 30, 1992: Final report  

SciTech Connect (OSTI)

This work supported by the Division of Chemical Sciences, Office of Basic Energy Services, Office of Energy Research, US Department of Energy during the period July 1, 1989 to June 30, 1992, resulted in noteworthy scientific results in three categories which we shall discuss in turn: The spectroscopy of high-lying doubly-excited states of H{sup {minus}}, interactions with thin foils, and multiphoton processes. Radiological safety concerns and slow beam studies are also briefly discussed.

Bryant, H.C.

1992-07-01T23:59:59.000Z

320

Synchrotron x-ray absorption spectroscopy study of self-assembled nanoparticles synthesized from Fe(acac)3 and Pt(acac)2  

Science Journals Connector (OSTI)

The synchrotron X-ray absorption technique was used to complement electron microscopy in the investigation of nanoparticles synthesized from the coreduction of iron acetylacetonate, Fe(acac)3 and platinum acetylacetonate, Pt(acac)2. ...

K. Chokprasombat; C. Sirisathitkul; P. Harding; S. Chandarak; R. Yimnirun

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

High-resolution X-ray spectroscopy of hollow atoms created in plasma heated by subpicosecond laser radiation  

SciTech Connect (OSTI)

The investigations of ultrashort (0.4-0.6 ps) laser pulse radiation interaction with solid targets have been carried out. The Trident subpicosecond laser system was used for plasma creation. The X-ray plasma emission was investigated with the help of high-resolution spectrographs with spherically bent mica crystals. It is shown that when high contrast ultrashort laser pulses were used for plasma heating its emission spectra could not be explained in terms of commonly used theoretical models, and transitions in so called {open_quotes}hollow atoms{close_quotes} must be taken into account for adequate description of plasma radiation.

Faenov, A.Ya.; Magunov, A.I.; Pikuz, T.A. [Multicharged Ions Spectra Data Center of VNIIFTRI, Moscow (Russian Federation)] [and others

1997-10-01T23:59:59.000Z

322

Nuclear inelastic scattering spectroscopy of tris(acetylacetonate)iron(III); A vibrational probe via the iron atom  

Science Journals Connector (OSTI)

We report application of nuclear inelastic scattering (NIS) spectroscopy to the compound tris(acetylacetonate)iron(III), [Fe(III)(acac)3] enriched in 57Fe. Experimental results are compared with the simulated spectrum based on the normal mode analysis of the isolated [57Fe(III)(acac)3] molecule using DFT calculations. Good agreement between the peak positions and intensities of the simulated and experimental spectra enables complete and reliable assignment of the Fe-selective vibrational modes. It is concluded that in the solid state E modes are enhanced by coupling with the lattice modes. Additionally, infrared and Raman spectra of [Fe(III)(acac)3] are calculated from DFT and compared with experiment thus demonstrating the complementarity of these three vibrational spectroscopic techniques.

Upali A. Jayasooriya; Jamie N.T. Peck; J. Elaine Barclay; Sinead M. Hardy; Aleksandr I. Chumakov; David J. Evans; Christopher J. Pickett; Vasily S. Oganesyan

2011-01-01T23:59:59.000Z

323

Charge Resonance Effects on Electronic Absorption Line Shapes: Application to the Heterodimer Absorption of Bacterial Photosynthetic Reaction Centers  

E-Print Network [OSTI]

to the formalism of Fano's treatment for atomic absorption line shapes associated with autoionization (Fano, UCharge Resonance Effects on Electronic Absorption Line Shapes: Application to the Heterodimer Absorption of Bacterial Photosynthetic Reaction Centers Huilin Zhou and Steven G. Boxer* Department

Boxer, Steven G.

324

ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1978  

E-Print Network [OSTI]

Offgas Using Zeeman Atomic Absorption Spectroscopy D. C.spectro- metry, Zeeman atomic absorption spectroscopy andOffgass Using Zeeman Atomic Absorption Spectroscopy D. C.

Cairns, E.L.

2011-01-01T23:59:59.000Z

325

INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER  

E-Print Network [OSTI]

1970. Analytical Methods for Atomic Absorption Spectroscopy.1973. Analytical Methods for Atomic Absorption Spectroscopy.analysis; AAS =atomic absorption spectroscopy. EXPERIMENTAL

Farrier, D.S.

2011-01-01T23:59:59.000Z

326

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network [OSTI]

zinc and chloride by atomic absorption by the spectroscopy.College The atomic absorption spectroscopy was performed ofrandom error is about atomic absorption spectroscopy. Many

Mc Vay, L.

2011-01-01T23:59:59.000Z

327

Multiphoton Absorption and Coherence  

Science Journals Connector (OSTI)

We study the probability for multiphoton absorption processes induced by both laser and thermal light acting on an atomic system. When the thermal radiation, suitably filtered, has the same frequency spectrum and the same total energy as the laser packet, we find that the ratio between the relative probabilities for s-photon absorption can be expressed by (4?)-12(s-1)s!s12(?c?)s-1, where ? is the time during which the atomic system is illuminated by thermal radiation with coherence time ?c. This shows that multiphoton absorption processes depend on the statistical properties of the incident light, and that the probability induced by the laser packet is certainly greater than that induced by the thermal light if s

S. Carusotto; G. Fornaca; E. Polacco

1968-01-25T23:59:59.000Z

328

Atomic and molecular interstellar absorption lines toward the high galactic latitude stars HD~141569 and HD~157841 at ultra-high resolution  

E-Print Network [OSTI]

We present ultra-high resolution (0.32 km/s) spectra obtained with the 3.9m Anglo-Australian Telescope (AAT) and Ultra-High-Resolution Facility (UHRF), of interstellar NaI D1, D2, Ca II K, K I and CH absorption toward two high galactic latitude stars HD141569 and HD157841. We have compared our data with 21-cm observations obtained from the Leiden/Dwingeloo HI survey. We derive the velocity structure, column densities of the clouds represented by the various components and identify the clouds with ISM structures seen in the region at other wavelengths. We further derive abundances, linear depletions and H2 fractional abundances for these clouds, wherever possible. Toward HD141569, we detect two components in our UHRF spectra : a weak, broad component at - 15 km/s, seen only in CaII K absorption and another component at 0 km/s, seen in NaI D1, D2, Ca II K, KI and CH absorption. In the case of the HD157841 sightline, a total of 6 components are seen on our UHRF spectra in NaI D1, D2 Ca II K, K I and CH absorption. 2 of these 6 components are seen only in a single species.

M. S. Sahu; J. C. Blades; L. He; D. Hartmann; M. J. Barlow; I. A. Crawford

1998-03-31T23:59:59.000Z

329

A survey for redshifted molecular and atomic absorption lines - II. Associated HI, OH and millimetre lines in the z >~ 3 Parkes quarter-Jansky flat-spectrum sample  

E-Print Network [OSTI]

We present the results of a z>2.9 survey for HI 21-cm and molecular absorption in the hosts of radio quasars using the GMRT and the Tidbinbilla 70-m telescope. Previously published searches, which are overwhelmingly at redshifts of z2.5. We therefore believe that our high redshift selection is responsible for our exclusive non-detections, and find that at ultra-violet luminosities of >10e23 W/Hz, 21-cm absorption has never been detected. We also find this to not only apply to our targets, but also those at low redshift exhibiting similar luminosities, giving zero detections out of a total of 16 sources over z=0.24 to 3.8. This is in contrast to the absorption. The mix of 21-cm detections and non-detections is currently attributed to orientation effects, where according to unified schemes of active galactic nuclei, 21-cm absorption is more likely to occur in sources designated as radio galaxies (type-2 objects, where the nucleus is viewed through dense obscuring circumnuclear gas) than in quasars(type-1 objects, where we have a direct view to the nucleus). However, due to the exclusively high ultra-violet luminosities of our targets it is not clear whether orientation effects alone can wholly account for the distribution, although there exists the possibility that the large luminosities are indicative of a changing demographic of galaxy types. We also find that below luminosities of ~10e23 W/Hz, both type-1 and type-2 objects have a 50% likelihood of exhibiting 21-cm absorption.

S. J. Curran; M. T. Whiting; T. Wiklind; J. K. Webb; M. T. Murphy; C. R. Purcell

2012-01-07T23:59:59.000Z

330

In Situ X-ray Near-Edge Absorption Spectroscopy Investigation of the State of Charge of All-Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

all-vanadium flow battery; X-ray near-edge adsorption spectroscopy; synchrotron; in situ; state of charge; electrolyte ... Among different types of RFBs, the all-vanadium redox flow battery (VRB) displays excellent electrochemical activity and reversibility. ... To the best of our knowledge, this is the first report to use the in situ synchrotron techniques to study the redox flow battery. ...

Chuankun Jia; Qi Liu; Cheng-Jun Sun; Fan Yang; Yang Ren; Steve M. Heald; Yadong Liu; Zhe-Fei Li; Wenquan Lu; Jian Xie

2014-09-05T23:59:59.000Z

331

Infrared Spectroscopy and Optical Constants of Porous Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy and Optical Constants of Porous Amorphous Solid Water. Infrared Spectroscopy and Optical Constants of Porous Amorphous Solid Water. Abstract: Reflection-absorption...

332

Chemical State and Local Structure around Titanium Atoms in NaAlH4 Doped with TiCl3 Using X-ray Absorption Spectroscopy  

Science Journals Connector (OSTI)

Financial support by the “Forschungsallianz Brennstoffzelle Baden-Württemberg” is gratefully acknowledged. ...

Aline Léon; Oliver Kircher; Jörg Rothe; Maximilian Fichtner

2004-09-29T23:59:59.000Z

333

Quick-scanning x-ray absorption spectroscopy system with a servo-motor-driven channel-cut monochromator with a temporal resolution of 10 ms  

SciTech Connect (OSTI)

We have developed a quick-scanning x-ray absorption fine structure (QXAFS) system and installed it at the recently constructed synchrotron radiation beamline BL33XU at the SPring-8. Rapid acquisition of high-quality QXAFS data was realized by combining a servo-motor-driven Si channel-cut monochromator with a tapered undulator. Two tandemly aligned monochromators with channel-cut Si(111) and Si(220) crystals covered energy ranges of 4.0-28.2 keV and 6.6-46.0 keV, respectively. The system allows the users to adjust instantly the energy ranges of scans, the starting angles of oscillations, and the frequencies. The channel-cut crystals are cooled with liquid nitrogen to enable them to withstand the high heat load from the undulator radiation. Deformation of the reflecting planes is reduced by clamping each crystal with two cooling blocks. Performance tests at the Cu K-edge demonstrated sufficiently high data quality for x-ray absorption near-edge structure and extended x-ray absorption fine-structure analyses with temporal resolutions of up to 10 and 25 ms, respectively.

Nonaka, T.; Dohmae, K.; Araki, T.; Hayashi, Y.; Hirose, Y. [Toyota Central R and D Labs., Inc., Nagakute, Aichi 480-1192 (Japan); Uruga, T.; Yamazaki, H.; Tanida, H.; Goto, S. [JASRI/Spring-8, 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Mochizuki, T. [JASRI/Spring-8, 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Toyama Corp., Zama, Kanagawa 228-0003 (Japan)

2012-08-15T23:59:59.000Z

334

Woodhead Publishing Limited, 2013 Tunable mid-infrared laser absorption  

E-Print Network [OSTI]

absorption spectroscopy F. K. TITTEL and R. LEWICKI, Rice University, USA DOI: 10 absorption spectroscopy (LAS) and recent examples of their use in field deployable optical instruments detection methods that include several types of multipass gas absorption cells with the option to apply

335

Origin of improved scintillation efficiency in (Lu,Gd){sub 3}(Ga,Al){sub 5}O{sub 12}:Ce multicomponent garnets: An X-ray absorption near edge spectroscopy study  

SciTech Connect (OSTI)

In the recent successful improvement of scintillation efficiency in Lu{sub 3}Al{sub 5}O{sub 12}:Ce driven by Ga{sup 3+} and Gd{sup 3+} admixture, the “band-gap engineering” and energy level positioning have been considered the valid strategies so far. This study revealed that this improvement was also associated with the cerium valence instability along with the changes of chemical composition. By utilizing X-ray absorption near edge spectroscopy technique, tuning the Ce{sup 3+}/Ce{sup 4+} ratio by Ga{sup 3+} admixture was evidenced, while it was kept nearly stable with the Gd{sup 3+} admixture. Ce valence instability and Ce{sup 3+}/Ce{sup 4+} ratio in multicomponent garnets can be driven by the energy separation between 4f ground state of Ce{sup 3+} and Fermi level.

Wu, Yuntao, E-mail: caswyt@hotmail.com; Luo, Jialiang; Ren, Guohao [Shanghai Institute of Ceramics, Chinese Academy of Sciences, No.215 Road, Jiading, Shanghai 201899 (China); Nikl, Martin [Institute of Physics, Academy of Sciences of the Czech Republic, Cukrovarnická 10, 16253 Prague 6 (Czech Republic)

2014-01-01T23:59:59.000Z

336

In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution  

SciTech Connect (OSTI)

A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the way for in situ investigations of electrochemical processes, photovoltaics, batteries, fuel cells, water splitting, corrosion, electrodeposition, and a variety of important biological processes.

Jiang, Peng; Chen, Jeng-Lung; Borondics, Ferenc; Glans, Per-Anders; West, Mark W.; Chang, Ching-Lin; Salmeron, Miquel; Guo, Jinghua

2010-03-31T23:59:59.000Z

337

E-Print Network 3.0 - atomic recoil spectra Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

recoil spectra Page: << < 1 2 3 4 5 > >> 1 Nonlinear Spectroscopy of Cold, Trapped Atoms: Atomic Recoil and Localization Effects in a MOT Summary: Nonlinear Spectroscopy of...

338

Superconductivity suppression of R(Ba1-zRz)2Cu3O7+? (R=Nd, Pr) probed by soft-x-ray absorption spectroscopy  

Science Journals Connector (OSTI)

O K-edge x-ray-absorption near-edge-structure (XANES) spectra of (Nd1-xPrx)1.05Ba1.95Cu3O7 for x=0–0.5 and Nd1.05(Ba1-zPrz)1.95Cu3O7+? for z=0–0.25 were performed to search for microstructural features and hole distribution related to the superconducting properties. Near the O 1s edge, prepeaks at ?527.6 and ?528.3 eV are assigned to transitions into O 2p holes located in the CuO3 ribbons and CuO2 planes, respectively. As deduced from O 1s absorption spectra of (Nd1-xPrx)1.05Ba1.95Cu3O7 for x=0–0.5, the hole concentrations in the CuO2 planes and CuO3 ribbons decrease monotonically with increasing Pr doping. The present XANES results clearly reveal that the suppression of superconductivity with Pr doping in (Nd1-xPrx)1.05Ba1.95Cu3O7 results predominantly from the hole depletion effect. The effect of Pr on the Ba site in Nd1.05(Ba1-zPrz)1.95Cu3O7+? is to reduce the hole concentration in the CuO2 planes and to create localized fivefold Cu chain sites. Tc of Nd1.05(Ba1-zPrz)1.95Cu3O7+? is depressed upon Pr doping, primarily due to hole filling and hole localization. Compared to (Nd1-xPrx)1.05Ba1.95Cu3O7, the enhanced suppression of Tc in Nd1.05(Ba1-zPrz)1.95Cu3O7+? is primarily due to the hole localization.

J. M. Chen; R. S. Liu; P. Nachimuthu; M. J. Kramer; K. W. Dennis; R. W. McCallum

1999-02-01T23:59:59.000Z

339

E-Print Network 3.0 - absorption spectrometry detection Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

340

E-Print Network 3.0 - absorption spectrometry fi-aas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

E-Print Network 3.0 - absorption spectrometry technique Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

342

E-Print Network 3.0 - absorption va vibrational Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of a protein, which deviate only... direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

343

E-Print Network 3.0 - acid absorption acceleration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

acids, the ligands and specific... direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

344

E-Print Network 3.0 - absorption protein npc1l1 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

345

E-Print Network 3.0 - absorption spectrometry f-aas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

346

E-Print Network 3.0 - absorption spectrum aided Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

347

E-Print Network 3.0 - absorption Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

348

E-Print Network 3.0 - absorptivity Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

349

E-Print Network 3.0 - absorption spectrometry method Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

350

E-Print Network 3.0 - atomic emission detection Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

38 Dissipative atom optics PIERRE DESBIOLLES, MARKUS ARNDT, Summary: , if we neglect the atomic recoil during absorption and emission. However, the atom may also fa11 into Fg......

351

E-Print Network 3.0 - atomic spectrometry update Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

techniques that also measure concentration using atom properties... , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

352

E-Print Network 3.0 - atomic spectrometry techniques Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

techniques that also measure concentration using atom properties... , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

353

Relativistic atomic beam spectroscopy II  

SciTech Connect (OSTI)

We are requesting support for a postdoctoral person to participate in H{sup -} studies at Los Alamos. In addition, we are requesting funding for a state-of-the-art YAG laser system that would allow us to obtain data at three times our present rate with improved beam quality.

NONE

1991-12-31T23:59:59.000Z

354

Temperature-dependent collision-broadening parameters of H[sub 2]O lines in the 1. 4-[mu]m region using diode laser absorption spectroscopy  

SciTech Connect (OSTI)

Radiative properties of water vapor in the infrared spectrum are important in a variety of applications, including atmospheric sounding experiments, radiative sensing of combustion processes, and optical diagnostics for gasdynamic and aerodynamic studies. Here, spectrally resolved measurements of water vapor absorption spectra near 1.4 [mu]m have been performed with a tunable, distributed-feedback InGaAsP diode laser. A lineshape analysis was used to infer the collision-broadening coefficient of 11 rovibrational transitions in the [nu] + [nu][sub 3] and 2[nu][sub 1] vibration bands perturbed separately by N[sub 2], O[sub 2], CO[sub 2], and H[sub 2]. The temperature dependence of the broadening coefficients was determined using a temperature-controlled static cell and a pressure-driven shock tube over the range 300--1,200 K. The measured coefficients are in good agreement with the previous calculations of Delaye. Also, agreement is found between prior experimental data, obtained for the same rotational transitions but different vibration bands, and the results.

Langlois, S.; Birbeck, T.P.; Hanson, R.K. (Stanford Univ., CA (United States). Dept. of Mechanical Engineering)

1994-10-01T23:59:59.000Z

355

X-ray absorption study of the electronic structure of Mn-doped amorphous Si  

E-Print Network [OSTI]

X-ray absorption study of the electronic structure of Mn-?x ) is studied by X-ray absorption spectroscopy at the Mn Land featureless L 3,2 absorption peaks, corresponding to an

Zeng, Li

2008-01-01T23:59:59.000Z

356

Soft X-Ray and Vacuum Ultraviolet Based Spectroscopy of the Actinides  

SciTech Connect (OSTI)

The subjects of discussion included: VUV photoelectron spectroscopy, X-ray photoelectron spectroscopy, Synchrotron-radiation-based photoelectron spectroscopy, Soft x-ray absorption spectroscopy, Soft x-ray emission spectroscopy, Inverse photoelectron spectroscopy, Bremstrahlung Isochromat Spectroscopy, Low energy IPES, Resonant inverse photoelectron spectroscopy.

Tobin, J G

2011-03-17T23:59:59.000Z

357

Terahertz spectroscopy for quantifying refined oil mixtures  

Science Journals Connector (OSTI)

In this paper, the absorption coefficient spectra of samples prepared as mixtures of gasoline and diesel in different proportions are obtained by terahertz time-domain spectroscopy. To...

Li, Yi-nan; Li, Jian; Zeng, Zhou-mo; Li, Jie; Tian, Zhen; Wang, Wei-kui

2012-01-01T23:59:59.000Z

358

Flash photolysis kinetic absorption spectroscopy study of the gas-phase reaction HO/sub 2/ + C/sub 2/H/sub 5/O/sub 2/ over the temperature range 228-380 K  

SciTech Connect (OSTI)

Flash photolysis kinetic absorption spectroscopy was used to investigate the gas-phase reaction between hydroperoxy and ethylperoxy radicals between 228 and 380 K in the pressure range 25-400 Torr: HO/sub 2/ + C/sub 2/H/sub 5/O/sub 2/ ..-->.. products (1). Due to the large difference between the self-reactivities of the two radicals, first- or second-order kinetic conditions could not be maintained for either species. Thus, the rate constant for reaction 1 was determined from computer-modeled fits of the radical absorption decay curves recorded at wavelengths between 230 and 280 nm. This procedure yielded a value for k/sub 1/ at 298 K of (5.3 +/- 1.0) x 10/sup -12/ cm/sup 3/ molecule/sup -1/ s/sup -1/ independent of total pressure (using N/sub 2/) between 25 and 400 Torr. The Arrhenius expression derived from the present study over the temperature range 248-380 K is k/sub 1/ = (5.6 +/- 2.4) x 10/sup -13/ exp((650 +/- 125)/T) cm/sup 3/ molecule/sup -1/ s/sup -1/, where the quoted errors are 2 sigma from linear least-squares analyses. A reanalysis of the authors earlier measurements of the C/sub 2/H/sub 5/O/sub 2/ self-reaction, C/sub 2/H/sub 5/O/sub 2/ + C/sub 2/H/sub 5/O/sub 2/ ..-->.. products (2), using this expression for k/sub 1/ results in the revised Arrhenius equation: k/sub 2/ = (8.5 +/- 1.1) x 10/sup -14/ exp(-(110 +/- 40)/T) cm/sup 3/ molecule/sup -1/ s/sup -1/.

Dagaut, P.; Wallington, T.J.; Kurylo, M.J.

1988-06-30T23:59:59.000Z

359

A SURVEY OF INSTRUMENTATION USED FOR MONITORING METALS IN WATER  

E-Print Network [OSTI]

diagram of an atomic absorption spectrometer. SimplifiedTrace Analysis by Atomic Absorption Spectroscopy and Anodicin Table 1. They are atomic absorption spectroscopy, botl1

Quinby-Hunt, M.S.

2011-01-01T23:59:59.000Z

360

ENERGY & ENVIRONMENT DIVISION. ANNUAL REPORT FY 1980  

E-Print Network [OSTI]

Offgases by Zeeman Atomic Absorption Spectroscopy D. C.Offgases by Zeeman Atomic Absorption Spectroscopy," Energya graphite furnace atomic absorption detector (HPLC-GFAA).

Authors, Various

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

ENERGY & ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

Offgases by Zeeman Atomic Absorption Spectroscopy D. C.Products by Zeeman Atomic Absorption Spectroscopy E. Cuellarwith a F1ame1ess Atomic Absorption Detector for Speciation

Cairns, E.J.

2010-01-01T23:59:59.000Z

362

RETORT WATER PARTICULATES  

E-Print Network [OSTI]

Analysis, Isotope Zeeman Atomic Absorption, a Am Lab, Augustfor the Zeeman atomic absorption spectroscopy measurements,determined by Zeeman atomic absorption spectroscopy.4 X~ray

2011-01-01T23:59:59.000Z

363

COMBUSTION RESEARCH - FY-1979  

E-Print Network [OSTI]

Products by Zeeman Atomic Absorption Spectroscopy E. Cuellarand R. McLaughlin, "Zeeman atomic absorption spectrometry,"to be used is Zeeman Atomic Absorption Spectroscopy (ZAA)

,

2012-01-01T23:59:59.000Z

364

Crystal structure of Thermotoga maritima TM0439: implications for the mechanism of bacterial GntR transcription regulators with Zn2+-binding FCD domains  

E-Print Network [OSTI]

binding site. Using atomic absorption spectroscopy and TrpElmer AAnalyst 400 atomic absorption spectrometer (AAS) withthe metal, we employed atomic absorption spectroscopy on the

Zheng, Meiying

2009-01-01T23:59:59.000Z

365

An experimental study of magnesium-isotope fractionation in chlorophyll-a photosynthesis  

E-Print Network [OSTI]

of chlorophyll standards by atomic absorption spectroscopy.were determined by Atomic Absorption Spectrometry and/or bymedium, as determined by atomic absorption spectroscopy. The

Black, J R; Yin, Q Z; Casey, W H

2006-01-01T23:59:59.000Z

366

THE MINICOMPUTER AND COMPUTATIONS IN CHEMISTRY. REPORT ON THE WORKSHOP  

E-Print Network [OSTI]

W. G. Boyle, Jr. , Atomic Absorption Instrument FunctionalBASIC Language for Atomic Absorption Flame Spectroscopy PartBASIC Language for Atomic Absorption Flame Spectroscopy Part

Authors, Various

2011-01-01T23:59:59.000Z

367

E-Print Network 3.0 - absorption spectrometry coupled Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... in graphite tube atomizers and analytical flames...

368

E-Print Network 3.0 - absorption spectrometry system Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... in graphite tube atomizers and analytical flames...

369

E-Print Network 3.0 - absorption spectrometry part Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Summary: . References 1 B. Welz, Conference report: first Rio Symposium on Furnace Atomic Absorption Spectrometry... , Special Issue 7th Rio Symposium on Atomic...

370

E-Print Network 3.0 - absorption spectrometry comparing Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... in graphite tube atomizers and analytical flames...

371

Core Level Spectroscopies Surface Science and X-Ray Spectroscopy Group  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Core Level Spectroscopy Creation and Decay of Core Holes Spectroscopic Techniques X-ray Photoelectron (XPS) X-ray Absorption (XAS) X-ray Emission (XES) Auger Electron (AES) Core holes are created by the ionization of a core electron in XPS and by excitation in XAS . The XPS and XAS final states are highly unstable and the core hole decays by non-radiant Auger relaxation (AES) or by radiant x-ray emission processes (XES). XPS and AES probe the unoccupied electronic stru cture, while XAS projects the unoccupied valence states of the system onto a particular atom. A brief description of the each of the different spectroscopies illustrated by schematic pictures of the creation and decay with data measured for N2 adsorbed on Ni(100) can be found by scrolling

372

Structural Analysis of the Mn(IV)/Fe(III) Cofactor of Chlamydia Trachomatis Ribonucleotide Reductase By Extended X-Ray Absorption Fine Structure Spectroscopy And Density Functional Theory Calculations  

SciTech Connect (OSTI)

The class Ic ribonucleotide reductase from Chlamydia trachomatis (C{bar A}) uses a stable Mn(lV)/ Fe(lll) cofactor to initiate nucleotide reduction by a free-radical mechanism. Extended X-ray absorption fine structure (EXAFS) spectroscopy and density functional theory (DFT) calculations are used to postulate a structure for this cofactor. Fe and Mn K-edge EXAFS data yield an intermetallic distance of -2.92 {angstrom}. The Mn data also suggest the presence of a short 1.74 {angstrom} Mn-O bond. These metrics are compared to the results of DFT calculations on 12 cofactor models derived from the crystal structure of the inactive Fe2(lll/ III) form of the protein. Models are differentiated by the protonation states of their bridging and terminal OH{sub x} ligands as well as the location of the Mn(lV) ion (site 1 or 2). The models that agree best with experimental observation feature a{mu}-1, 3-carboxylate bridge (E120), terminal solvent (H{sub 2}O/OH) to site 1, one {mu}-O bridge, and one {mu}-OH bridge. The site-placement of the metal ions cannot be discerned from the available data.

Younker, J.M.; Krest, C.M.; Jiang, W.; Krebs, C.; Bollinger, J.M.Jr.; Green, M.T.

2009-05-28T23:59:59.000Z

373

Suppression of a Recoil Component in Nonlinear Doppler-Free Spectroscopy  

Science Journals Connector (OSTI)

A new method to suppress one of the two recoil components in saturation and Ramsey spectroscopy is presented. It is applied to the calcium intercombination line S01-P13 (??675 nm) by optical pumping of the calcium atoms from the metastable P13 state through the S13 state into the P03 or the P23 states. The suppression of the low-frequency recoil component could be deduced in saturated absorption from a narrowing and shift of the Lamb dip as well as observed directly in Ramsey fringe spectroscopy when the recoil doublet was resovled.

F. Riehle; J. Ishikawa; J. Helmcke

1988-10-31T23:59:59.000Z

374

Enhanced absorption Hanle effect in the configuration of crossed laser beam and magnetic field F. Renzoni,1,  

E-Print Network [OSTI]

modifications of the absorptive and dispersive properties of atomic media 2­4 , and are responsible for the sub that increases the atomic absorption 8,9 . The increased atomic absorption, denoted as electromagnetic induced abEnhanced absorption Hanle effect in the configuration of crossed laser beam and magnetic field F

375

E-Print Network 3.0 - absorption spectra response Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at Santa Barbara Collection: Geosciences 6 Nonlinear Spectroscopy of Cold, Trapped Atoms: Atomic Recoil and Localization Effects in a MOT Summary: mixing |r |eg Different shapes...

376

Directional fine structure in absorption of white x rays: A tomographic interpretation P. Korecki,1,  

E-Print Network [OSTI]

structure in absorption of white x rays can be interpreted as real-space projections of atomic structure from neigh- boring atoms.1 A straightforward analysis of the extended x-ray absorption fine structure of the absorbing atoms. Thus, the absorption cross section is effectively modulated by the x-ray scattering

Korecki, Pawe³

377

Electromagnetically Induced Transparency from a Single Atom in Free Space  

E-Print Network [OSTI]

We report an absorption spectroscopy experiment and the observation of electromagnetically induced transparency from a single trapped atom. We focus a weak and narrowband Gaussian light beam onto an optically cooled Barium ion using a high numerical aperture lens. Extinction of this beam is observed with measured values of up to 1.3 %. We demonstrate electromagnetically induced transparency of the ion by tuning a strong control beam over a two-photon resonance in a three-level lambda-type system. The probe beam extinction is inhibited by more than 75 % due to population trapping.

L. Slodicka; G. Hetet; S. Gerber; M. Hennrich; R. Blatt

2010-05-18T23:59:59.000Z

378

Accelerated guided atomic pulse  

Science Journals Connector (OSTI)

The deleterious effects of dispersion on a propagating coherent atomic pulse, along the axis of a traveling-wave laser beam, can be ameliorated by the nonlinear self-interacting force due to dipole-dipole coupling between atoms. We show that a wide atomic pulse with a particular profile can retain its shape during propagation and, moreover, the momentum of the pulse increases due to photon absorption. For the wide soliton case, we demonstrate analytically that the self-interacting atomic force scales inversely with the third power of the pulse width.

S. Dyrting; Weiping Zhang; B. C. Sanders

1997-09-01T23:59:59.000Z

379

First-time remote sensing of NO2 vertical distributions in an urban street canyon using Topographic Target Light scattering Differential Optical Absorption Spectroscopy (ToTaL-DOAS)  

Science Journals Connector (OSTI)

Topographic Target Light scattering Differential Optical Absorption Spectroscopy (ToTaL-DOAS) measurements were performed in a street canyon in Gwangju, Korea (35°10?51.43?N, 126°52?53.74?E) during a period of 10 days in October 2010. NO2 slant volume mixing ratios (VMRs) at the lowest elevation angle (EL) of 1°, as obtained from ToTaL-DOAS measurements, were validated via comparisons with collocated in situ ground data, showing good agreement within a scatter range of 20% during the entire measurement period, and within a scatter range of 15% when cloudy days were excluded. For the first time, based on inversion calculations using ToTaL-DOAS data, we retrieved NO2 vertical distributions that consist of five layers (from 6 to 118 m) for three measurement days. We obtained generally decreasing NO2 \\{VMRs\\} with altitude, whereas increased NO2 \\{VMRs\\} at two elevated layers (6–19 m and 19–33 m) were observed on 26 and 27 October. We obtained a coefficient of determination (R2) of 0.87 (0.61) between slant \\{VMRs\\} at 1° EL (retrieved NO2 \\{VMRs\\} in the layer from 6 m to 19 m) and in situ data, with the scatter of the correlation being within the 15% (10%) range. The relation between retrieved NO2 \\{VMRs\\} at 6–19 m and slant \\{VMRs\\} at 1° EL yielded an R2 value of 0.97, with the scatter of the correlation being within the 5% range. The results demonstrate that the ToTaL-DOAS technique is a useful tool in identifying the temporal and vertical characteristics of NO2 \\{VMRs\\} in an urban street canyon with a complex geometry.

Hanlim Lee; Myojeong Gu; Young J. Kim; Jungbae Hwang; Ukkyo Jung

2012-01-01T23:59:59.000Z

380

Root Absorption  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Root Absorption Root Absorption Name: Carolyn Location: N/A Country: N/A Date: N/A Question: MY Neice is doing a science fair project on plants. More specifically she needs to know if you water your flowering plants with colored water, does the flower change colors and if so, why? Replies: Dear Carolyn, Dyeing flowers works best on cut stems in water: http://youth.net/nsrc/sci/sci032.html#anchor598182 Title: The Effect Of Color On The Speed Of Dyeing Flowers Some rooted plants can change flower color by altering the soil pH: http://www.cahe.nmsu.edu/pubs/yard/1996/120996.html Sincerely, Anthony R. Brach This sounds like a good question for a science project. I think she should do the project first and get some data and then try to answer the question herself. If she can't figure it out, then she should look for some help.

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Single molecule level absorption spectroscopy in solution  

Science Journals Connector (OSTI)

Until today the detection and identification of molecules in extremely low concentration or quantity is ... In particular this is the case if the molecules must be detected among of a multitude ... Today, devices...

R. Bornemann; E. Thiel

1999-01-01T23:59:59.000Z

382

Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass  

DOE Patents [OSTI]

Photoionization via autoionizing atomic levels combined with conventional mass spectroscopy provides a technique for quantitative analysis of trace quantities of chemical elements in the presence of much larger amounts of other elements with substantially the same atomic mass. Ytterbium samples smaller than 10 ng have been detected using an ArF* excimer laser which provides the atomic ions for a time-of-flight mass spectrometer. Elemental selectivity of greater than 5:1 with respect to lutetium impurity has been obtained. Autoionization via a single photon process permits greater photon utilization efficiency because of its greater absorption cross section than bound-free transitions, while maintaining sufficient spectroscopic structure to allow significant photoionization selectivity between different atomic species. Separation of atomic species from others of substantially the same atomic mass is also described.

Miller, C.M.; Nogar, N.S.

1982-09-02T23:59:59.000Z

383

Absorption line shape recovery beyond the detection bandwidth limit: application to the Boltzmann constant determination  

E-Print Network [OSTI]

1 Absorption line shape recovery beyond the detection bandwidth limit: application to the Boltzmann of the influence of detection bandwidth properties on observed line shapes in laser absorption spectroscopy the Boltzmann constant (kB) [10, 11]. Based upon laser absorption spectroscopy in the linear regime

384

Pressurised xenon as scintillator for gamma spectroscopy  

E-Print Network [OSTI]

Detectors based on liquid or gas xenon have been used and are in use for a number of applications, in particular for the detection of gamma rays. Xenon is a well-suited medium for gamma spectroscopy thanks to its high atomic number and, consequently, large cross-section for photo-electric absorption. This paper presents experimental studies of high pressure xenon as a scintillator, with the aim of developing a gamma ray detector for the detection of Special Nuclear Materials (SNM). The first goal was to study the dependence of the light yield and of the energy resolution on the thermodynamic conditions. We present preliminary results from an optimised version of the detector.

Resnati, F

2013-01-01T23:59:59.000Z

385

LATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION  

E-Print Network [OSTI]

crystalline domains are taken. Absorption studies of the dynamics of atomic motions in condensed matterLATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION AND COHERENT DECAY MODES Institut Max von Laue-Paul Langevin, Grenoble, France R6sumb. -La section efficace pour l'absorption nucleaire

Paris-Sud XI, Université de

386

Silicate absorption in heavily obscured galaxy nuclei  

E-Print Network [OSTI]

Spectroscopy at 8-13 microns with T-ReCS on Gemini-S is presented for 3 galaxies with substantial silicate absorption features, NGC 3094, NGC 7172 and NGC 5506. In the galaxies with the deepest absorption bands, the silicate profile towards the nuclei is well represented by the emissivity function derived from the circumstellar emission from the red supergiant, mu Cephei which is also representative of the mid-infrared absorption in the diffuse interstellar medium in the Galaxy. There is spectral structure near 11.2 microns in NGC 3094 which may be due to a component of crystalline silicates. In NGC 5506, the depth of the silicate absorption increases from north to south across the nucleus, suggestive of a dusty structure on scales of 10s of parsecs. We discuss the profile of the silicate absorption band towards galaxy nuclei and the relationship between the 9.7 micron silicate and 3.4 micron hydrocarbon absorption bands.

P. F. Roche; C. Packham; D. K. Aitken; R. E. Mason

2006-10-19T23:59:59.000Z

387

Iron Absorption  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iron Absorption Iron Absorption Name: Mary Location: N/A Country: N/A Date: N/A Question: I wrote before to Steve and got a answer back. I would like more information. The cirmcustances were that I first had anaemia and then I went for a gastroscopy. The results of which were I had insufficient acid been produced in the stomach. I was told that acid was nessary for the absorbion of iron and it was because of this that I became anaemic. I was told to eat plently of red meat not too many vegetables. Is there any other information you can give me? Replies: It is very difficult to say for sure without seeing you chart and I am not your doctor. But it sounds to me like you are deficient in the vitamin B12. In your stomach you have 3 basic types of cells. One is called chief cells which secrete the precursor of the enzyme pepsin which begins the breakdown of protein. Another is called the parietal cells which secrete your stomach acid and a substance called intrinsic factor. Now-switch to your bone marrow which is where your red blood cells are made. In order for your red blood cells to mature in the bone marrow, vitamin B12 is necessary. B12 can only be obtained from animal food sources such as meat, milk and eggs. Unfortunately, B12 cannot be absorbed in the stomach without intrinsic factor. If there is sufficient B12 present in the diet, it can be stored in the liver. If you aren't eating enough animal sources your B12 will be taken from your liver until you run out. You could also be deficient in intrinsic factor. So while the outcome is anemia (not enough red blood cells) the problem could be from a few different things. Follow your doctor's recommendations and eat more sources of B12

388

E-Print Network 3.0 - atomic spectroscopic detection Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic flux measurement of electron-beam evaporated yttrium with a diode-laser-based atomic absorption monitor at 668 nm Summary: . The spectroscopic technique, based on...

389

E-Print Network 3.0 - analytical atomic spectrometry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: in graphite tube atomizers and analytical flames by wavelength modulation-laser atomic absorption spectrometry... down to about 310 nm. Such powers are sufficient for...

390

E-Print Network 3.0 - atom vapor cells Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rotation in the vapor cell due to inten- sity-induced birefringence in the rubidium atomic vapor. While... Super efficient absorption filter for quantum memory using atomic...

391

E-Print Network 3.0 - atomic emission spectrometry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Basics Review Quadrupole ICP-MS: Introduction to Instrumentation, Summary: , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

392

E-Print Network 3.0 - atomic beam frequency Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

laser and characterization of the atomic beam... is to measure the frequency dependent absorption of a laser beam intersecting the atomic beam. Depending... the ... Source:...

393

High-lying bound Rydberg states of excited Hg(6s6p {sup 3}P{sub 1}) atoms from two-color resonance ionization mass spectroscopy  

SciTech Connect (OSTI)

Mercury isotopes are investigated with two-color resonance ionization mass spectroscopy (RIMS). Isotope shifts, hyperfine structure splittings, and the lifetime of the intermediate 6s6p {sup 3}P{sub 1} state are determined by RIMS. Ion yields at the threshold region in various static electric fields are measured in order to determine an extrapolated ionization energy value at zero field strength. New energy values for high-lying bound 6s nd {sup 3}D (21

Bisling, Peter; Dederichs, Jan; Neidhart, Bernd; Weitkamp, Claus [GKSS-Forschungszentrum Geesthacht GmbH, Postfach 11 60, D-21494 Geesthacht (Germany)

1998-12-16T23:59:59.000Z

394

Characterizing Absorption Spectrum of Natural Rubidium by Using a Directly Modulated VCSEL  

E-Print Network [OSTI]

in the absorption profile of a medium containing system atoms. Moreover, the change leads to a very narrow the absorption spectrum of the atomic vapor. Identifying the correct spectral placing is a major taskCharacterizing Absorption Spectrum of Natural Rubidium by Using a Directly Modulated VCSEL Ido Ben

Eisenstein, Gadi

395

E-Print Network 3.0 - atomic force ultrasonic Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

laboratories, you must attend the safety orientation. Summary: W ultrasonic horn Atomic absorption spectrophotometer UVVIS spectrophotometer Centrifuge p... ,...

396

E-Print Network 3.0 - absorption edge detector Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

XAFS , x-ray ab- sorption near-edge spectroscopy XANES and diffraction anomalous... of a standard sample, with known absorption edge features at tabulated energies, and 3...

397

E-Print Network 3.0 - atomic structure reveals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure, thus revealing very subtle... Nonlinear Spectroscopy of Cold, Trapped Atoms: Atomic Recoil and Localization Effects in a MOT T... .if.uj.edu.plplZOAgrupywg.htm...

398

Two-Photon Absorption and Coherence  

Science Journals Connector (OSTI)

We study the probabilities for two-photon absorption processes induced by both coherent and thermal light when acting on an atomic system. Calculations are performed with quantum electrodynamics, and we find results similar to those obtained with semiclassical methods; that is, the two-photon absorption probability depends on the statistical properties of the light used. This probability assumes its maximum value for coherent light.

S. Carusotto; G. Fornaca; E. Polacco

1967-05-25T23:59:59.000Z

399

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

Offgases by Zeeman Atomic Absorption Spectroscopy D. C.~ Graphite Furnace Atomic Absorption Spectrometry," J.vd.th a Flameless Atomic Absorption Detector for Speciation

,

2012-01-01T23:59:59.000Z

400

Pharmacokinetics and Efficacy of Oxytetracycline in RLP-infected Abalone  

E-Print Network [OSTI]

to pathogen. Atomic absorption spectroscopy conducted onwe assessed, via atomic absorption/emission spectrometry,microwave digestion and atomic absorption spectrometry (

Tjeerdema, Ronald S.; Friedman, Carolyn S.; Moore, James D.; Viant, Mark R.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

COMBUSTION RESEARCH Chapter from the Energy and Environment Division Annual Report 1980  

E-Print Network [OSTI]

Hyperfine Zeeman Effect Atomic Absorption Spectrometry forthe Zeeman Effect to Atomic Absorption Spectrometry: A NewA Novel Method for Atomic Absorption Spectroscopy based on

Authors, Various

2013-01-01T23:59:59.000Z

402

Design of a rural water provision system to decrease arsenic exposure in Bangladesh  

E-Print Network [OSTI]

Hydride Generation Atomic Absorption Spectrophotomery (HG-Graphite Furnace Atomic Absorption Spectrometry (GF-Graphite Furnace - Atomic Absorption Spectroscopy (GF-AAS),

Mathieu, Johanna

2009-01-01T23:59:59.000Z

403

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

and Goda, L. Y. , atomic absorption spectrometry: Pergamonoil 1, p. 62. Zeeman atomic absorption, a new approach toranges studied Zeeman atomic absorption spectroscopy was

Fox, J. P.

2011-01-01T23:59:59.000Z

404

ENERGY & ENVIRONMENT DIVISION ANNUAL REPORT, 1977  

E-Print Network [OSTI]

of the Zeeman Atomic Absorption Technique to Fifteenfurnace for flameless atomic absorption spectrometry," Anal.and analyzed by flameless atomic absorption spectroscopy.

Budnitz, R.J.

2011-01-01T23:59:59.000Z

405

Moments of Absorption.  

E-Print Network [OSTI]

??Moments of Absorption explores the conceptual and visual themes that are presented in my MFA thesis exhibition. The research looks into the absorption of the… (more)

Kaufman, Sarah K.

2008-01-01T23:59:59.000Z

406

Soil Sampling At Valley Of Ten Thousand Smokes Region Area (Kodosky...  

Open Energy Info (EERE)

analytical techniques employed included instrumental neutron activation analysis (INAA), atomic absorption spectroscopy (AAS), direct-current plasma atomic emission spectroscopy...

407

Compound and Elemental Analysis At Valley Of Ten Thousand Smokes...  

Open Energy Info (EERE)

analytical techniques employed included instrumental neutron activation analysis (INAA), atomic absorption spectroscopy (AAS), direct-current plasma atomic emission spectroscopy...

408

E-Print Network 3.0 - absorption du cesium Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of SPIE Vol. 6871, 87112, (2008) Summary: from 9.192 GHz - of the fundamental Cesium atomic level have been scanned on a saturated absorption set... of the absorption line...

409

Oral Drug Absorption  

E-Print Network [OSTI]

properties ? membrane permeability ? metabolic stability ? enzyme inhibition or induction ? protein binding ? transporter affinity ?. Chemical Optimization DDS technology 4 Strategy of Drug Delivery Absorption Distribution Metabolism Excretion Improve of drug... absorption absorption enhancement controlled releasecontrolled release new administration route Drug targeting to the tissue to the cell to the organelle Dr. Shinji Yamashita (Setsunan University) Issue: Oral Drug Absorption Dr. Valentino J. Stella...

Yamashita, Shinji

2006-10-26T23:59:59.000Z

410

E-Print Network 3.0 - absorption spectrometry determination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... is used to digest...

411

E-Print Network 3.0 - absorption spectrometric method Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Selenium by Fluorescence Spectrometry Summary: MATERIALS 129 5. Ihnat. M.. Atomic absorption spectrometric determination of selenium with carbon furnace... , and...

412

E-Print Network 3.0 - absolute two-photon absorption Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

photoassociation Summary: shifted. These results for coherent control of two-photon absorption in atomic systems serve as our... . To the lowest order, the two-photon...

413

E-Print Network 3.0 - absorption spectra Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of a protein, which deviate only... direct insights into the reaction mechanism at the atomic level. Absorption ... Source: Gerwert, Klaus - Fakultt fr Biologie,...

414

E-Print Network 3.0 - absorption spectrometry feasibility Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Franc&o, CA 94101&fM, USA Laser Microprobe Mass Spectrometry Summary: graphite fur- nace atomic absorption spectrometry (ETAAS) measurement of tin in sulfate matrices were......

415

E-Print Network 3.0 - absorption difference spectra Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: these spectra show a large difference of the fine structure near the absorption edges of the inner atomic shells... . One of the specific feature of the...

416

E-Print Network 3.0 - absorption vapour samplers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Autodiluter system and ASX-510 Auto Sampler Capability: Analysis of most elements... atomic absorption spectrometer with longitudinal Zeeman graphite furnace, and AS-800...

417

E-Print Network 3.0 - absorption spectrometry combination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analytical combining RINH and IMS facilities RINH Genomics will re locate... absorption spectrometry Atomic fluorescence spectrometry (As, Se, Hg) Contact Joerg...

418

E-Print Network 3.0 - atomic shells m Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

edges, the calculations have been performed for clusters size up to 99 atoms (eight atomic shells... absorption spectnun. With two and three shells (17 and 29 atoms) the main...

419

E-Print Network 3.0 - atomic shells k Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

edges, the calculations have been performed for clusters size up to 99 atoms (eight atomic shells... absorption spectnun. With two and three shells (17 and 29 atoms) the main...

420

E-Print Network 3.0 - alpha-emitting atoms released Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic... Appendix B. Glossary 12;12;Appendix B. Glossary B-3 Appendix B. Glossary absorption, atomic... the nucleus of an atom; it has the same charge and mass as that of a...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

E-Print Network 3.0 - atomic shells l Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

edges, the calculations have been performed for clusters size up to 99 atoms (eight atomic shells... absorption spectnun. With two and three shells (17 and 29 atoms) the main...

422

Computing: Cascade (Atipa 1440 Intel Xeon-Phi Node FDR-Infiniband...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Atom flux sensors based on atomic absorption (AA)...

423

epitaxy system | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MnTi Oxides. Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Abstract: Atom flux sensors based on atomic absorption...

424

oxygen-plasma | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MnTi Oxides. Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Abstract: Atom flux sensors based on atomic absorption...

425

Computing: Cascade (Atipa 1440 Intel Xeon-Phi Node FDR-Infiniband...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

synthesized... Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Atom flux sensors based on atomic absorption (AA)...

426

Inductively Coupled Plasma Mass Spectrometry and Atomic Emission Spectrometry Coupled to High-Performance Liquid Chromatography for Speciation and Detection of Organotin Compounds  

Science Journals Connector (OSTI)

......graphite furnace atomic absorption ( G F A A ) , flame atomic...fluent is monitored by atomic absorption (20-22). In this study...8 C with a re frigerated chiller (Neslab Instrument, Inc...gas chromatography atomic absorption spectrometry. Anal. Chem......

Hamzar Suyani; John Creed; Tim Davidson; Joseph Caruso

1989-03-01T23:59:59.000Z

427

X-ray Absorption Spectroscopic Analysis of Reductive [2Fe-2S] Cluster Degradation in Hyperthermophilic Archaeal Succinate:Caldariellaquinone  

E-Print Network [OSTI]

X-ray Absorption Spectroscopic Analysis of Reductive [2Fe-2S] Cluster Degradation, but moderately sensitive to reduction with excess dithionite. We used iron K-edge X-ray absorption spectroscopy

Scott, Robert A.

428

Optical absorption intensity of semiconductor single-wall carbon nanotubes  

E-Print Network [OSTI]

Optical absorption intensity of semiconductor single-wall carbon nanotubes Y. Oyama1 , R. Saito1. The optical absorption intensity is inversely proportional to the diameter in the unit of per carbon atom of single-wall carbon nanotubes (SWNT) synthesized by alcohol CCVD (ACCVD) method and HiPco method [1

Maruyama, Shigeo

429

High resolution x-ray fluorescence spectroscopy - a new technique for site- and spin-selectivity  

SciTech Connect (OSTI)

X-ray spectroscopy has long been used to elucidate electronic and structural information of molecules. One of the weaknesses of x-ray absorption is its sensitivity to all of the atoms of a particular element in a sample. Through out this thesis, a new technique for enhancing the site- and spin-selectivity of the x-ray absorption has been developed. By high resolution fluorescence detection, the chemical sensitivity of K emission spectra can be used to identify oxidation and spin states; it can also be used to facilitate site-selective X-ray Absorption Near Edge Structure (XANES) and site-selective Extended X-ray Absorption Fine Structure (EXAFS). The spin polarization in K fluorescence could be used to generate spin selective XANES or spin-polarized EXAFS, which provides a new measure of the spin density, or the nature of magnetic neighboring atoms. Finally, dramatic line-sharpening effects by the combination of absorption and emission processes allow observation of structure that is normally unobservable. All these unique characters can enormously simplify a complex x-ray spectrum. Applications of this novel technique have generated information from various transition-metal model compounds to metalloproteins. The absorption and emission spectra by high resolution fluorescence detection are interdependent. The ligand field multiplet model has been used for the analysis of K{alpha} and K{beta} emission spectra. First demonstration on different chemical states of Fe compounds has shown the applicability of site selectivity and spin polarization. Different interatomic distances of the same element in different chemical forms have been detected using site-selective EXAFS.

Wang, Xin [Univ. of California, Davis, CA (United States). Dept. of Applied Science]|[Lawrence Berkeley National Lab., CA (United States)

1996-12-01T23:59:59.000Z

430

Spectroscopy (XSD) | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Useful Links Useful Links Spectroscopy Group (X-ray Science Division) The Spectroscopy Group operates the Sector-20 bending magnet (BM) and insertion device (ID) beamlines, and the bending magnet beamline at Sector-9. Beamlines 20-ID (Undulator A) Supported Techniques ·X-ray absorption fine structure (XAFS) ·Surface Diffraction ·X-ray Raman Scattering ·Resonant X-ray Emission Spectroscopy ·Micro-XAFS ·Confocal X-ray microscopy ·Micro-fluorescence ·Micro-XRD Discipline ·Material Science ·Environmental Science ·Chemistry Click [20-ID] under "Beamlines" above for technical information 20-BM Supported Techniques X-ray absorption fine structure (XAFS) Micro-fluorescence Micro-XAFS Micro-diffraction Discipline ·Material Science ·Environmental Science ·Chemistry Click [20-BM] under "Beamlines" above for technical information

431

Molecular absorption in transition region spectral lines  

E-Print Network [OSTI]

Aims: We present observations from the Interface Region Imaging Spectrograph (IRIS) of absorption features from a multitude of cool atomic and molecular lines within the profiles of Si IV transition region lines. Many of these spectral lines have not previously been detected in solar spectra. Methods: We examined spectra taken from deep exposures of plage on 12 October 2013. We observed unique absorption spectra over a magnetic element which is bright in transition region line emission and the ultraviolet continuum. We compared the absorption spectra with emission spectra that is likely related to fluorescence. Results: The absorption features require a population of sub-5000 K plasma to exist above the transition region. This peculiar stratification is an extreme deviation from the canonical structure of the chromosphere-corona boundary . The cool material is not associated with a filament or discernible coronal rain. This suggests that molecules may form in the upper solar atmosphere on small spatial scales...

Schmit, Donald; Ayres, Thomas; Peter, Hardi; Curdt, Werner; Jaeggli, Sarah

2014-01-01T23:59:59.000Z

432

A Laser System for the Spectroscopy of Highly-Charged Bismuth Ions  

E-Print Network [OSTI]

We present and characterize a laser system for the spectroscopy on highly-charged ^209Bi^82+ ions at a wavelength of 243.87 nm. For absolute frequency stabilization, the laser system is locked to a near-infra-red laser stabilized to a rubidium transition line using a transfer cavity based locking scheme. Tuning of the output frequency with high precision is achieved via a tunable rf offset lock. A sample-and-hold technique gives an extended tuning range of several THz in the UV. This scheme is universally applicable to the stabilization of laser systems at wavelengths not directly accessible to atomic or molecular resonances. We determine the frequency accuracy of the laser system using Doppler-free absorption spectroscopy of Te_2 vapour at 488 nm. Scaled to the target wavelength of 244 nm, we achieve a frequency uncertainty of \\sigma_{244nm} = 6.14 MHz (one standard deviation) over six days of operation.

S. Albrecht; S. Altenburg; C. Siegel; N. Herschbach; G. Birkl

2011-08-25T23:59:59.000Z

433

HII Absorption Bill Erickson  

E-Print Network [OSTI]

HII Absorption Bill Erickson November 10, 2006 It would make all of the drift curve simulations.8 dB above the data. One reason for this might be HII absorption which is not modeled in simulations. There are a number of ways that one might try to estimate the absorption. One might use optical maps of HII

Ellingson, Steven W.

434

Chemical factors influencing selenium atomization  

E-Print Network [OSTI]

Atomization. (August 1980) Mary Sue Buren, B, S. , Angelo State University Chairman of Advisory Comm1ttee: Dr. Thomas M. Vickrey Selenium in an acid1c matrix was analyzed using graphite furnace atom1c absorption with Zeeman-effect background correct1on.... Nickel(II} and lanthanum( III) were introduced as matrix modifiers to determine their effect on interferences 1n selenium atom1zation. In add1tion to matr1x mod1ficat1on, surface coating the graphite furnace with z1rconium and tantalum salts was also...

Buren, Mary Sue

2012-06-07T23:59:59.000Z

435

Hadronic Atoms  

E-Print Network [OSTI]

We review the theory of hadronic atoms in QCD+QED. The non-relativistic effective Lagrangian approach, used to describe this type of bound states, is illustrated with the case of pi+pi- atoms. In addition, we discuss the evaluation of isospin-breaking corrections to hadronic atom observables by invoking chiral perturbation theory.

J. Gasser; V. E. Lyubovitskij; A. Rusetsky

2009-03-02T23:59:59.000Z

436

Absolute atomic oxygen density profiles in the discharge core of a microscale atmospheric pressure plasma jet  

Science Journals Connector (OSTI)

The micro atmospheric pressure plasma jet is an rf driven (13.56 MHz ? 20 ? W ) capacitively coupled discharge producing a homogeneous plasma at ambient pressure when fed with a gas flow of helium (1.4 slm) containing small admixtures of oxygen ( ? 0.5 % ) . The design provides excellent optical access to the plasma core. Ground state atomic oxygen densities up to 3 × 10 16 ? cm ? 3 are measured spatially resolved in the discharge core by absolutely calibrated two-photon absorption laser-induced fluorescence spectroscopy. The atomic oxygen density builds up over the first 8 mm of the discharge channel before saturating at a maximum level. The absolute value increases linearly with applied power.

Nikolas Knake; Kari Niemi; Stephan Reuter; Volker Schulz-von der Gathen; Jörg Winter

2008-01-01T23:59:59.000Z

437

Spectroscopy peculiarities of thermal plasma of electric arc discharge between electrodes with Zn admixtures  

Science Journals Connector (OSTI)

Abstract Plasma of the free burning electric arc between Ag–SnO2–ZnO composite electrodes as well as brass electrodes were investigated. The plasma temperature distributions were obtained by Boltzmann plot method involving Cu I, Ag I or Zn I spectral line emissions. The electron density distributions were obtained from the width and from absolute intensity of spectral lines. The laser absorption spectroscopy was used for measurement of copper atom concentration in plasma. Plasma equilibrium composition was calculated using two independent groups of experimental values (temperature and copper atom concentration, temperature and electron density). It was found that plasma of the free burning electric arc between brass electrodes is in local thermodynamical equilibrium. The experimental verification of the spectroscopic data of Zn I spectral lines was carried out.

R.V. Semenyshyn; A.N. Veklich; I.L. Babich; V.F. Boretskij

2014-01-01T23:59:59.000Z

438

Influence of pp ions on pion absorption in H2 S. Jonsell,1  

E-Print Network [OSTI]

of experiments measuring the mass difference m m 0 from pion absorption in pionic atoms. These mechanismsInfluence of pp ions on pion absorption in H2 S. Jonsell,1 J. Wallenius,2 and P. Froelich1 1 Institute for Theoretical Atomic and Molecular Physics, Harvard-Smithsonian Center for Astrophysics, 60

439

Electronic states of NO{sub 2}-exposed H-terminated diamond/Al{sub 2}O{sub 3} heterointerface studied by synchrotron radiation photoemission and X-ray absorption spectroscopy  

SciTech Connect (OSTI)

The energy band-lineup and the electronic structure of NO{sub 2}-exposed H-terminated diamond/Al{sub 2}O{sub 3} heterointerface have been investigated by synchrotron radiation photoemission and x-ray absorption near-edge structure (XANES) measurements. It is found that the energy band-lineup is stagger-type, so-called type-II, with its valence band discontinuity of as high as 3.9?eV and its conduction band discontinuity of 2.7?eV. The valence band maximum of the H-terminated diamond surface is positioned at Fermi level as a result of high-density hole accumulation on the diamond side. The XANES measurement has shown that the oxygen-derived interface state locates at about 1–3?eV above the Fermi level.

Takahashi, Kazutoshi; Imamura, Masaki [Synchrotron Light Application Center, Saga University, Saga 840-8502 (Japan); Hirama, Kazuyuki [NTT Basic Research Laboratories, NTT Corporation, Atsugi 243-0198 (Japan); Kasu, Makoto [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan)

2014-02-17T23:59:59.000Z

440

EMSL - spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectroscopy en Behavior of nanoceria in biologically-relevant environments. http:www.emsl.pnl.govemslwebpublicationsbehavior-nanoceria-biologically-relevant-environments

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

WAVELENGTH MEASUREMENTS OF K TRANSITIONS OF OXYGEN, NEON, AND MAGNESIUM WITH X-RAY ABSORPTION LINES  

SciTech Connect (OSTI)

Accurate atomic transition data are important in many astronomical research areas, especially for studies of line spectroscopy. Whereas transition data of He-like and H-like ions (i.e., ions in high-charge states) have been accurately calculated, the corresponding data of K transitions of neutral or low-ionized metal elements are still very uncertain. Spectroscopy of absorption lines produced in the interstellar medium (ISM) has been proven to be an effective way to measure the central wavelengths of these atomic transitions. In this work, we analyze 36 Chandra High Energy Transmission Grating observations to search for and measure the ISM absorption lines along sight lines to 11 low-mass X-ray binaries. We correct the Galactic rotation velocity to the rest frame for every observation and then use two different methods to merge all the corrected spectra to a co-added spectrum. However, the co-added spectra obtained by this method exhibit biases, toward to either observations with high counts or lines with high signal-to-noise ratios. We do a Bayesian analysis of several significantly detected lines to obtain the systematic uncertainty and the bias correction for other lines. Compared to previous studies, our results improve the wavelength accuracy by a factor of two to five and significantly reduce the systematic uncertainties and biases. Several weak transitions (e.g., 1s-2p of Mg IV and Mg V; 1s-3p of Mg III and Mg V) are also detected for the first time, albeit with low significance; future observations with improved accuracy are required to confirm these detections.

Liao Jinyuan; Zhang Shuangnan [Key Laboratory of Particle Astrophysics, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Yao Yangsen, E-mail: zhangsn@ihep.ac.cn [Eureka Scientific, 2452 Delmer Street Suite 100, Oakland, CA 94602 (United States)

2013-09-10T23:59:59.000Z

442

Accepted Manuscript Laboratory-based recording of holographic fine structure in x-ray absorption  

E-Print Network [OSTI]

be only performed using synchrotron radiation. Keywords: x-ray absorption, atomic structure, xAccepted Manuscript Laboratory-based recording of holographic fine structure in x-ray absorption structure in x-ray absorption anisotropy using polycapillary optics, Nucl. Instr. and Meth. in Phys. Res. B

Korecki, Pawe³

443

New section of the HITRAN database: Collision-induced absorption (CIA)  

E-Print Network [OSTI]

New section of the HITRAN database: Collision-induced absorption (CIA) C. Richard a , I.E. Gordon for Astrophysics, Atomic and Molecular Physics Division, Cambridge, MA 02138, USA b University of Texas, Physics Keywords: Collision-induced absorption HITRAN Atmospheric absorption Interacting molecular pairs a b s t r

Chance, Kelly

444

Integration of an Atomic Force Microscope in a Beamline Sample Environment  

SciTech Connect (OSTI)

We developed and optimised an optics-free Atomic Force Microscope (AFM) that can be directly installed on most of the synchrotron radiation end-stations. The combination of Scanning Probe Microscopies with X-ray microbeams adds new possibilities to the variety of synchrotron radiation techniques. The instrument can be used for atomic force imaging of the investigated sample or to locally measure the X-ray absorption or diffraction, or it can also be used to mechanically interact with the sample while simultaneously taking spectroscopy or diffraction measurements. The local character of these measurements is intrinsically linked with the use of the Atomic Force Microscope tip. It is the sharpness of the tip that gives the opportunity to measure the photons flux impinging on it giving beam position monitor features, or allows to locally measure the absorption coefficient or the shape of the diffraction pattern. As an example of the possibilities opened by the instrument we will show diffraction measurements performed on a Ge/Si island while being indented with the AFM tip providing local measure of the Young coefficient. Three ESRF beamlines are going to be equipped with this new instrument.

Rodrigues, M. S.; Hrouzek, M.; Dhez, O.; Comin, F. [ESRF, 6 rue Horowitz 38042 Grenoble Cedex (France); Chevrier, J. [Institut Neel-CNRS and Universite Joseph Fourier, 38042 Grenoble (France)

2010-06-23T23:59:59.000Z

445

Measurements of scattering and absorption in mammalian cell suspensions  

SciTech Connect (OSTI)

During the past several years a range of spectroscopies, including fluorescence and elastic-scatter spectroscopy, have been investigated for optically based detection of cancer and other tissue pathologies. Both elastic-scatter and fluorescence signals depend, in part, on scattering and absorption properties of the cells in the tissue. Therefore an understanding of the scattering and absorption properties of cells is a necessary prerequisite for understanding and developing these techniques. Cell suspensions provide a simple model with which to begin studying the absorption and scattering properties of cells. In this study we have made preliminary measurements of the scattering and absorption properties of suspensions of mouse mammary carcinoma cells (EMT6) over a broad wavelength range (380 nm to 800 nm).

Mourant, J.R.; Johnson, T.M.; Freyer, J.P.

1996-03-01T23:59:59.000Z

446

E-Print Network 3.0 - atomic spectra Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1... in alternate points between emission and absorption peaks. 2Figure b. In EIT or absorption spectra, Input... , aa>bb. atomic coherence , , aa< Source: Wang, Wei Hua - Key...

447

Introduction of coherence in astrophysical spectroscopy  

E-Print Network [OSTI]

By confusing the radiance of a single mode light beam, constant in a transparent medium, with the irradiance which decreases away from the source, Menzel purports to show that coherent interactions of light with the diluted media of astrophysics, are negligible. Therefore, to study the interaction of light with gases, astrophysicists use Monte Carlo computations which work to study nuclear systems, but not optics: optical modes which may be defined in inhomogeneous media or for the emissions of single atoms interact coherently with these systems: a unique formula represents, according to the sign of a parameter, absorption and coherent emission. The optical and spectroscopic properties of a very simple model, an extremely hot source in an isotropic cloud of pure, low pressure, initially cold, huge hydrogen cloud are studied using Planck's and Einstein's theories. The similarities of the images and the spectra of this simple model with astronomical observations, for instance of SNR1987A, Einstein cross, lyman break galaxies, quasars,... is so large that this model may be an elementary first step in the study of many astrophysical objects. Adaptations of the model to complex astrophysical systems could represent them using only the old, standard theories of physics commonly used in laser spectroscopy.

Jacques Moret-Bailly

2010-02-08T23:59:59.000Z

448

Semiclassical atom  

Science Journals Connector (OSTI)

Semiclassical quantization is incorporated into the average potential approach to atomic physics. The stationary energy functional is shown to be the sum of the Thomas-Fermi functional and a mainly oscillatory part. The latter turns out to be a small correction for sufficiently large atomic numbers, allowing perturbative treatment. Further, a detailed study of semiclassical spectra, with emphasis on energy degeneracy, is performed.

Berthold-Georg Englert and Julian Schwinger

1985-07-01T23:59:59.000Z

449

Li et al., Aerosol and Air Quality Research, Vol. 6, No. 4, pp. 418-429, 2006 UV-Absorption-Based Measurements of Ozone and Mercury  

E-Print Network [OSTI]

interferences. For example, CMMs based on atomic absorption spectrometry (AAS) are subject to interferences of the Hg detection technique. Atomic absorption spectrometry (AAS) is one of the major techniques appliedLi et al., Aerosol and Air Quality Research, Vol. 6, No. 4, pp. 418-429, 2006 UV-Absorption

Li, Ying

450

Magneto-optical spectroscopy of metallic carbon nanotubes.  

E-Print Network [OSTI]

??Through polarization-dependent magneto-optical absorption spectroscopy, the magnetic susceptibility anisotropy for metallic single-walled carbon nanotubes has been extracted and found to be up to 4x greater… (more)

Searles, Thomas A., Jr

2010-01-01T23:59:59.000Z

451

The Application of IR Spectroscopy to the Investigation of Minerals  

Science Journals Connector (OSTI)

Traditionally, the application of IR spectroscopy in mineralogy is reduced to the determination of wavelengths or frequencies of discrete absorption maxima. These values are brought in correspondence with normal ...

Nikita V. Chukanov

2014-01-01T23:59:59.000Z

452

Laser Spectroscopy and Optical Diagnostics of Combustion Processes  

Science Journals Connector (OSTI)

Tunable diode laser absorption spectroscopy of temperature and species (NO,H2O,CO,CO2,UHC) with applications in coal fired powerplants, gasifiers and IC engines. Wavelength modulation...

Hanson, Ronald K

453

A quantum cascade laser-based optical feedback cavity-enhanced absorption spectrometer for the simultaneous measurement of CH4 and N2O in air  

Science Journals Connector (OSTI)

Optical feedback cavity-enhanced absorption spectroscopy (OF CEAS) has been demonstrated with a thermoelectrically cooled continuous wave distributed feedback quantum cascade laser (QCL) operating at wavelengths ...

D. J. Hamilton; A. J. Orr-Ewing

2011-03-01T23:59:59.000Z

454

E-Print Network 3.0 - atomic scale structure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic scale structure Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine Structure...

455

E-Print Network 3.0 - atomic explosions Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Within... to Coulomb explosion (Last and Jortner, 2000). Calculation of the energy absorption of atomic clusters... these results with kinetic energy of the ions coming from...

456

E-Print Network 3.0 - atomic fluorescence spectrometry Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... spectrometry where the low-frequency noise of the...

457

E-Print Network 3.0 - absorber-materials atomic numbers Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

. With two laser sources, however, quantum interference can be used to ensure that atomic absorption... is eliminated, while retaining a large nonlinear response. A downside...

458

E-Print Network 3.0 - atoms two-photon above-threshold Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

created, which can be considered above threshold ionization ATI . Unlike in the seminal atomic ATI studies... absorption of four laser photons, equivalent to 20 eV excitation...

459

E-Print Network 3.0 - atomic vapor laser Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with the exception of pagination. IEEE TRANSACTIONS ON PLASMA SCIENCE 1 Summary: vapor, atomic physics and vapor ionization, absorption reflection in a heated plasma layer, and...

460

E-Print Network 3.0 - atomic number materials Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic number materials Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

E-Print Network 3.0 - atomic emission determination Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emission... cool- ing. The spontaneous emission events produce unpre- dictable changes in atomic momenta so... of absorption and emission can cause a large change of the ......

462

E-Print Network 3.0 - atomic orbitals calculation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

THE EUROPEAN Summary: Stark eects 1 Introduction Periodic-orbit theory and, variant atomic photo-absorption spectra, closed-orbit... calculated classical properties closed...

463

E-Print Network 3.0 - atomic binding energy Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

energy Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic binding energy Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine Structure...

464

E-Print Network 3.0 - atomic photoabsorption process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

process Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic photoabsorption process Page: << < 1 2 3 4 5 > >> 1 Absorption Spectra and...

465

E-Print Network 3.0 - atomic radiation unscear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Acronyms, Abbreviations, Symbols, and Notation A.1.0 Acronyms And Abbreviations AA Atomic absorption ASCII... -hydroxyethyl) ethylenedinitrilotriacetic acid HLW High level...

466

E-Print Network 3.0 - atomic fluorescence spectrometric Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Selenium by Fluorescence Spectrometry Summary: MATERIALS 129 5. Ihnat. M.. Atomic absorption spectrometric determination of selenium with carbon furnace... I...

467

E-Print Network 3.0 - atomic emission analysis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emission... cool- ing. The spontaneous emission events produce unpre- dictable changes in atomic momenta so... of absorption and emission can cause a large change of the ......

468

Balmer Absorption Lines in FeLoBALs  

E-Print Network [OSTI]

We discovered non-stellar Balmer absorption lines in two many-narrow-trough FeLoBALs (mntBALs) by the near-infrared spectroscopy with Subaru/CISCO. Presence of the non-stellar Balmer absorption lines is known to date only in the Seyfert galaxy NGC 4151, thus our discovery is the first cases for quasars. Since all known active galactic nuclei with Balmer absorption lines share characteristics, it is suggested that there is a population of BAL quasars which have unique structures at their nuclei or unique evolutionary phase.

K. Aoki; I. Iwata; K. Ohta; N. Tamura; M. Ando; M. Akiyama; G. Kiuchi; K. Nakanishi

2006-12-14T23:59:59.000Z

469

Scattering of light and atoms in a Fermi-Dirac gas with Bardeen-Cooper-Schrieffer pairing  

Science Journals Connector (OSTI)

We theoretically study the optical properties of a Fermi-Dirac gas in the presence of a superfluid state. We calculate the leading quantum-statistical corrections to the standard column density result of the electric susceptibility. We also consider the Bragg diffraction of atoms by means of light-stimulated transitions of photons between two intersecting laser beams. Bardeen-Cooper-Schrieffer pairing between atoms in different internal levels magnifies incoherent scattering processes. The absorption linewidth of a Fermi-Dirac gas is broadened and shifted. Bardeen-Cooper-Schrieffer pairing introduces a collisional local-field shift that may dramatically dominate the Lorentz-Lorenz shift. For the case of the Bragg spectroscopy the static structure function may be significantly increased due to superfluidity in the near-forward scattering.

J. Ruostekoski

2000-02-10T23:59:59.000Z

470

E-Print Network 3.0 - atomic scale images Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in the scattering of light by a condensate Summary: , and atoms at 45 degrees. (b-g) Absorption images after 20 ms time-of-flight show the atomic momentum... appears to be...

471

E-Print Network 3.0 - all-optical miniature atomic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Instituut, Quantum Gases and Atom Optics Group Collection: Physics 5 Three-photon-absorption resonance for all-optical atomic clocks Sergei Zibrov,1,2,3,4 Summary:...

472

Double core-hole spectroscopy of transient plasmas produced in the interaction of ultraintense x-ray pulses with neon  

E-Print Network [OSTI]

Double core-hole (DCH) spectroscopy is investigated systematically for neon atomic system in the interaction with ultraintense x-ray pulses with photon energy from 937 eV to 2000 eV. A time-dependent rate equation, implemented in the detailed level accounting approximation, is utilized to study the dynamical evolution of the level population and emission properties of the highly transient plasmas. For x-ray pulses with photon energy in the range of 937-1030 eV, where $1s\\rightarrow 2p$ resonance absorption from single core-hole (SCH) states of neon charge states exist, inner-shell resonant absorption (IRA) effects play important roles in the time evolution of population and DCH spectroscopy. Such IRA physical effects are illustrated in detail by investigating the interaction of x-ray pulses at a photon energy of 944 eV, which corresponds to the $1s\\rightarrow 2p$ resonant absorption from the SCH states ($1s2s^22p^4$, $1s2s2p^5$ and $1s2p^6$) of Ne$^{3+}$. After averaging over the space and time distribution o...

Gao, Cheng; Yuan, Jianmin

2015-01-01T23:59:59.000Z

473

TENDER ENERGY X-RAY ABSORPTION  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TENDER ENERGY X-RAY ABSORPTION TENDER ENERGY X-RAY ABSORPTION SPECTROSCOPY (TES) Project Team: S. Bare 1,2 , J. Brandes 3 , T. Buonassisi 4 , J. Chen 5,2 , M. Croft 6 , E. DiMasi 7 , A. Frenkel 8,2 , D. Hesterberg 9 , S. Hulbert 7,2 , S. Khalid 7 , S. Myneni 10 , P. Northrup 7,11 , E.T. Rasbury 11 , B. Ravel 12 , R. Reeder 11 , J. Rodriguez 7,2 , D. Sparks 5,13 , V. Stojanoff 7 , G. Waychunas 14 1 UOP LLC, 2 Synchrotron Catalysis Consortium, 3 Skidaway Inst. of Oceanography, 4 MIT Laboratory for Photovoltaics Research, 5 Univ. of Delaware, 6 Rutgers Univ., 7 Brookhaven National Lab, 8 Yeshiva Univ., 9 North Carolina State Univ., 10 Princeton Univ., 11 Stony Brook Univ., 12 NIST, 13 Delaware Environmental Inst., 14 Lawrence Berkeley National Lab TECHNIQUES: High performance and in-situ X-ray absorption spectroscopy and spatially-resolved XAS of

474

ARM - Measurement - Aerosol absorption  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption absorption ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Aerosol absorption The process in which radiation energy is retained by aerosols. Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments AOS : Aerosol Observing System CSPHOT : Cimel Sunphotometer IAP : In-situ Aerosol Profiles (Cessna Aerosol Flights) PSAP : Particle Soot Absorption Photometer PASS : Photoacoustic Soot Spectrometer External Instruments OMI : Ozone Monitoring Instrument

475

Magneto-optical resonance of electromagnetically induced absorption with high contrast and narrow width in a vapour cell with buffer gas  

E-Print Network [OSTI]

The method for observing the high-contrast and narrow-width resonances of electromagnetically induced absorption (EIA) in the Hanle configuration under counterpropagating light waves is proposed. We theoretically analyze the absorption of a probe light wave in presence of counterpropagating one with the same frequency as the function of a static magnetic field applied along the vectors of light waves, propagating in a vapour cell. Here, as an example, we study a "dark" type of atomic dipole transition Fg=1-->Fe=1 in D1 line of 87Rb, where usually the electromagnetically induced transparency (EIT) can be observed. To obtain the EIA signal one should proper chose the polarizations of light waves and intensities. In contrast of regular schemes for observing EIA signals (in a single travelling light wave in the Hanle configuration or in a bichromatic light field consisted of two travelling waves), the proposed scheme allows one to use buffer gas to significantly enhance properties of the resonance. Also the dramatic influence of atomic transition openness on contrast of the resonance is revealed, that gives great advantage in comparison with cyclic atomic transitions. The obtained results can be interesting in high-resolution spectroscopy, nonlinear and magneto-optics.

D. V. Brazhnikov; A. V. Taichenachev; V. I. Yudin

2014-08-11T23:59:59.000Z

476

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2003-10-14T23:59:59.000Z

477

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2004-08-31T23:59:59.000Z

478

Fourier Transform Photothermal Deflection Spectroscopy of Impurity Centres in CdS Films: Doping and Annealing Effects  

Science Journals Connector (OSTI)

The subgap optical absorption of polycrystalline thin films was measured by Fourier Transform Photothermal Deflection Spectroscopy. Some impurity levels were identified : copper doping and annealing effects we...

M. Fathallah; B. Rezig; M. Zouaghi; N. M. Amer…

1988-01-01T23:59:59.000Z

479

Seven-effect absorption refrigeration  

DOE Patents [OSTI]

A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit. 1 fig.

DeVault, R.C.; Biermann, W.J.

1989-05-09T23:59:59.000Z

480

Seven-effect absorption refrigeration  

DOE Patents [OSTI]

A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit.

DeVault, Robert C. (Knoxville, TN); Biermann, Wendell J. (Fayetteville, NY)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

1 - Fundamentals of optical spectroscopy  

Science Journals Connector (OSTI)

Abstract: This chapter discusses the electronic, vibrational, and rotational spectroscopy of atoms and molecules, and the relationship between the concentration of a species and its spectral intensities. The different types of radiative transitions and spectral broadening mechanisms are discussed. A brief review of energy levels and selection rules for radiative transitions and hence allowed spectroscopic transitions for both atoms and molecules are presented. The determination of the plasma temperature and the temperatures of molecular degrees of freedom from spectroscopic observations is addressed. The effect of spectral congestion is illustrated through the display of simulated spectra at different resolutions.

P.J. Dagdigian

2014-01-01T23:59:59.000Z

482

Quantitative tunneling spectroscopy of nanocrystals  

SciTech Connect (OSTI)

The proposed goals of this collaborative work were to systematically characterize the electronic structure and dynamics of 3-dimensional metal and semiconducting nanocrystals using scanning tunneling microscopy/spectroscopy (STM/STS) and ballistic electron emission spectroscopy (BEES). This report describes progress in the spectroscopic work and in the development of methods for creating and characterizing gold nanocrystals. During the grant period, substantial effort also was devoted to the development of epitaxial graphene (EG), a very promising materials system with outstanding potential for nanometer-scale ballistic and coherent devices ("graphene" refers to one atomic layer of graphitic, sp2 -bonded carbon atoms [or more loosely, few layers]). Funding from this DOE grant was critical for the initial development of epitaxial graphene for nanoelectronics

First, Phillip N; Whetten, Robert L; Schaaff, T Gregory

2007-05-25T23:59:59.000Z

483

Atom Interferometry  

ScienceCinema (OSTI)

Atom de Broglie wave interferometry has emerged as a tool capable of addressing a diverse set of questions in gravitational and condensed matter physics, and as an enabling technology for advanced sensors in geodesy and navigation. This talk will review basic principles, then discuss recent applications and future directions. Scientific applications to be discussed include measurement of G (Newton?s constant), tests of the Equivalence Principle and post-Newtonian gravity, and study of the Kosterlitz-Thouless phase transition in layered superfluids. Technology applications include development of precision gryoscopes and gravity gradiometers. The talk will conclude with speculative remarks looking to the future: Can atom interference methods be sued to detect gravity waves? Can non-classical (entangled/squeezed state) atom sources lead to meaningful sensor performance improvements?

Mark Kasevich

2010-01-08T23:59:59.000Z

484

Atomic Level Spatial Variations of Energy States along Graphene Edges  

Science Journals Connector (OSTI)

Atomic Level Spatial Variations of Energy States along Graphene Edges ... The local atomic bonding of carbon atoms around the edge of graphene is examined by aberration-corrected scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). ... We show that energy states of graphene edges vary across individual atoms along the edge according to their specific C–C bonding, as well as perpendicular to the edge. ...

Jamie H. Warner; Yung-Chang Lin; Kuang He; Masanori Koshino; Kazu Suenaga

2014-10-23T23:59:59.000Z

485

Photon interference effect in x-ray absorption spectra over a wide energy range Y. Nishino and T. Ishikawa  

E-Print Network [OSTI]

. Therefore the atomic absorption coeffi- cient a is given by a a PI a ES a Incoh , 1 where a PI , a ESPhoton interference effect in x-ray absorption spectra over a wide energy range Y. Nishino and T Received 3 July 2002; published 12 September 2002 We consider fundamental structures in x-ray absorption

Korecki, Pawe³

486

Laboratory-based recording of holographic fine structure in X-ray absorption anisotropy using polycapillary optics  

E-Print Network [OSTI]

10 April 2012 Available online 17 May 2012 Keywords: X-ray absorption Atomic structure XLaboratory-based recording of holographic fine structure in X-ray absorption anisotropy using) was characterized and used for recording two-dimensional maps of X-ray absorption anisotropy (XAA). XAA originates

Korecki, Pawe³

487

96 $+& &%XS&~S*#* % (Fi) 28 W**+#*) .~R*%A**% #+a +4fi4ti % #+El&% 2603 % 3 R % 1 R *$v*&%%%B4+%  

E-Print Network [OSTI]

measurement (j) Spectral interferenceand chemicalinterferencefor atomic absorption spectroscopy. 2. (10 absorption spectrometry, the absorption behavior of atoms or ions are also caused by the promotion results, the absorption spectraof atomic and molecular species are quiet different, which one is line

Huang, Haimei

488

Potassium emission absorption system. Topical report 12  

SciTech Connect (OSTI)

The Potassium Emission Absorption System is one of the advanced optical diagnostics developed at Mississippi State University to provide support for the demonstration of prototype-scale coal-fired combustion magnetohydrodynamic (MHD) electrical power generation. Intended for application in the upstream of an MHD flow, the system directly measures gas temperature and neutral potassium atom number density through spectroscopic emission absorption techniques. From these measurements the electron density can be inferred from a statistical equilibrium calculation and the electron conductivity in the MHD channel found by use of an electron mobility model. The instrument has been utilized for field test measurements on MHD facilities for almost a decade and has been proven to provide useful measurements as designed for MHD nozzle, channel, and diffuser test sections. The theory of the measurements, a system description, its capabilities, and field test measurement results are reported here. During the development and application of the instrument several technical issues arose which when addressed advanced the state of the art in emission absorption measurement. Studies of these issues are also reported here and include: two-wavelength measurements for particle-laden flows, potassium D-line far wing absorption coefficient, bias in emission absorption measurements arising from dirty windows and misalignments, non-coincident multiwavelength emission absorption sampling errors, and lineshape fitting for boundary layer flow profile information. Although developed for NLHD application, the instrument could be applied to any high temperature flow with a resonance line in the 300 to 800 nm range, for instance other types of flames, rocket plumes or low temperature plasmas.

Bauman, L.E.

1995-04-01T23:59:59.000Z

489

Spectroscopic Observation of Resonant Electric Dipole-Dipole Interactions between Cold Rydberg Atoms  

E-Print Network [OSTI]

Atoms K. Afrousheh, P. Bohlouli-Zanjani, D. Vagale, A. Mugford, M. Fedorov, and J. D. D. Martin between cold Rydberg atoms were observed using microwave spectroscopy. Laser-cooled 85Rb atoms pulse transferred a fraction of these Rydberg atoms to the 46p3=2 state. A second microwave pulse

Le Roy, Robert J.

490

E-Print Network 3.0 - absorption spectrophotometry fi-faas Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

method 7060A) Arsenic concentrations in the plants were relatively low... furnace atomic absorption spectrophotometry. . The samples will also be analyzed to pH using a pH...

491

E-Print Network 3.0 - absorption line survey Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Printed in U.S.A. Summary: . They also found a hint of the expected narrow 1s2p absorption line in atomic O. We obtained a high... cant line emission. Instead, a number...

492

E-Print Network 3.0 - angle x-ray absorption Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FROM PLANETS AND COMETS: RELATIONSHIP WITH SOLAR X-RAYS AND SOLAR WIND Summary: in the atomic and molecular constituents of the atmosphere, and 2) the absorption of incident...

493

Nuclear absorption of low energy pions and the pion-nucleus optical potential  

SciTech Connect (OSTI)

The energy dependence of the optical model parameters for low energy, 0--50 MeV, pions was determined by a compromise fit to pionic atoms, ..pi../sup +/ elastic scattering and ..pi../sup - +/ absorption mesurements.

Carr, J.A.; McManus, H.; Stricker-Bauer, K.

1982-02-01T23:59:59.000Z

494

Polarization from aligned atoms as a diagnostics of circumstellar, AGN and interstellar magnetic fields: II. Atoms with Hyperfine Structure  

E-Print Network [OSTI]

We show that atomic alignment presents a reliable way to study topology of astrophysical magnetic fields. The effect of atomic alignment arises from modulation of the relative population of the sublevels of atomic ground state pumped by anisotropic radiation flux. As such aligned atoms precess in the external magnetic field and this affects the properties of the polarized radiation arising from both scattering and absorption by the atoms. As the result the polarizations of emission and absorption lines depend on the 3D geometry of the magnetic field as well as the direction and anisotropy of incident radiation. We consider a subset of astrophysically important atoms with hyperfine structure. For emission lines we obtain the dependencies of the direction of linear polarization on the directions of magnetic field and the incident pumping radiation. For absorption lines we establish when the polarization is perpendicular and parallel to magnetic field. For both emission and absorption lines we find the dependence on the degree of polarization on the 3D geometry of magnetic field. We claim that atomic alignment provides a unique tool to study magnetic fields in circumstellar regions, AGN, interplanetary and interstellar medium. This tool allows studying of 3D topology of magnetic fields and establish other important astrophysical parameters. We consider polarization arising from both atoms in the steady state and also as they undergo individual scattering of photons. We exemplify the utility of atomic alignment for studies of astrophysical magnetic fields by considering a case of Na alignment in a comet wake.

Huirong Yan; A. Lazarian

2006-11-09T23:59:59.000Z

495

Atomic layer deposition of ZnO on ultralow-density nanoporous silica aerogel monoliths  

Science Journals Connector (OSTI)

We report on atomic layer deposition of an ? 2 -nm-thick ZnO layer on the inner surface of ultralow-density ( ? 0.5 % of the full density) nanoporoussilica aerogel monoliths with an extremely large effective aspect ratio of ? 10 5 (defined as the ratio of the monolith thickness to the average pore size). The resultant monoliths are formed by amorphous- SiO 2 core/wurtzite-ZnO shell nanoparticles which are randomly oriented and interconnected into an open-cell network with an apparent density of ? 3 % and a surface area of ? 10 0 m 2 g ? 1 . Secondary ion mass spectrometry and high-resolution transmission electron microscopy imaging reveal excellent uniformity and crystallinity of ZnO coating. Oxygen K -edge and Zn L 3 -edge soft x-ray absorption near-edge structure spectroscopy shows broadened O p - as well as Zn s - and d -projected densities of states in the conduction band.

S. O. Kucheyev; J. Biener; Y. M. Wang; T. F. Baumann; K. J. Wu; T. van Buuren; A. V. Hamza; J. H. Satcher Jr.; J. W. Elam; M. J. Pellin

2005-01-01T23:59:59.000Z

496

AAS, see Atomic absorption spectrometry Acanthes lanceolata, 138  

E-Print Network [OSTI]

hydrocarbons AIDS patients, 625 Air pollution monitoring equipment, 312 sources, 475 Air handling, 271 mine drainage, 74 precipitation, 74 storage cabinets, 738 volatile sulfides (AVS grunniens, 415 Applied statistics, 576 Aquarium air stone, suction using, 329 Aquatic assessments

Pitt, Robert E.

497

H I Self Absorption Toward Molecular Clouds: Theoretical Models  

E-Print Network [OSTI]

information and available data, visit the GRS web page at www.bu.eduwww.bu.edu/G/GRSRS References chemistry deep inside the molecular clouds. We study H I self- absorption toward molecular clouds is dominated by cold atomic hydrogen formed by cosmic ray chemistry deep in the interiors of clouds. If all

498

Arsenic Speciation in Solids Using X-ray Absorption Spectroscopy  

Science Journals Connector (OSTI)

...drugs voluntarily withdrawn from the US market by its manufacturer in 2013 (only nitarsone...used for industrial heat production or in diesel engines (Huffman et al. 2000). XANES...oxidation states. The authors postulated diesel exhaust, residential central heating...

Andrea L. Foster; Christopher S. Kim

499

Arsenic Speciation in Solids Using X-ray Absorption Spectroscopy  

Science Journals Connector (OSTI)

...strongly-bound polymerized species whose fundamental repeating unit contains AsO4 bound...industrial heat production or in diesel engines (Huffman et al. 2000). XANES...states. The authors postulated diesel exhaust, residential central heating...

Andrea L. Foster; Christopher S. Kim

500

Absorption Spectroscopy of Individual Single-Walled Carbon Nanotubes  

Science Journals Connector (OSTI)

Stéphane Berciaud ,† Laurent Cognet ,† Philippe Poulin ,‡ R. Bruce Weisman ,§ and Brahim Lounis *† ...

Stéphane Berciaud; Laurent Cognet; Philippe Poulin; R. Bruce Weisman; Brahim Lounis

2007-03-27T23:59:59.000Z