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Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
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1

VARIOUS APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY  

E-Print Network [OSTI]

APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPYthe Zeeman effect to atomic absorption spectroscopy has beenthe Zeeman effect on atomic absorption spectrometry has been

Koizumi, Hideaki

2011-01-01T23:59:59.000Z

2

Self-corrected Sensors Based On Atomic Absorption Spectroscopy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy. Self-corrected Sensors Based On Atomic Absorption Spectroscopy For...

3

SPECIES DETERMINATION OF ORGANOMETALLIC COMPOUNDS USING ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY WITH LIQUID CHROMATOGRAPHY  

E-Print Network [OSTI]

Compounds Using Zeeman Atomic Absorption Spectroscopy WithCompounds Using Zeeman ,Atomic Absorption Spectroscopy withcapabilities of Zeeman atomic absorption spectroscopy (ZAA)

Koizumi, H.

2011-01-01T23:59:59.000Z

4

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

Isotope Zeeman Atomic Absorption; A new approach to chemical6782 Use of Zeeman Atomic Absorption Spectroscopy for theb:l r I USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE

Girvin, D.G.

2011-01-01T23:59:59.000Z

5

Atomic flux measurement by diode-laser-based atomic absorption spectroscopy  

E-Print Network [OSTI]

Atomic flux measurement by diode-laser-based atomic absorption spectroscopy Weizhi Wang,a) R. H, California 94305 Received 5 May 1999; accepted 6 June 1999 Diode-laser-based atomic absorption AA sensors- quirements, and only the QCM measures the flux. Lamp- based atomic absorption AA sensors have been success

Fejer, Martin M.

6

Transient x-ray absorption spectroscopy of hydrated halogen atom  

E-Print Network [OSTI]

Time-resolved x-ray absorption spectroscopy has been used to observe the transient species generated by one-photon detachment of an electron from aqueous bromide. The K-edge spectrum of the short-lived Br(0) atom exhibits a resonant 1s-4p transition...

Elles, Christopher G.; Shkrob, Ilya A.; Crowell, Robert A.; Arms, Dohn A.; Landahl, Eric C.

2008-02-11T23:59:59.000Z

7

Determination of Tellurium by Atomic-absorption Spectroscopy with Electrothermal Atomisation  

E-Print Network [OSTI]

305 Determination of Tellurium by Atomic-absorption Spectroscopy with Electrothermal Atomisation at sub-microgram levels by atomic-absorption spectroscopy ,,'ith electrothermal atomisation after the e generation -atomic-absorption spectroscopy. The prior con- version of tellurium into hydrogen telluride

Canberra, University of

8

E-Print Network 3.0 - atomic absorption spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectroscopy Page: << < 1 2 3 4 5 > >> 1 Xray Absorption Near Edge...

9

Diode-laser-based atomic absorption monitor using frequency-modulation spectroscopy for physical vapor deposition process control  

E-Print Network [OSTI]

Diode-laser-based atomic absorption monitor using frequency-modulation spectroscopy for physical, and the dynamic events occur- ring as vapors condense on a substrate. Atomic absorption AA spectroscopy also been measured by means of the Doppler frequency shifts of the atomic absorption with respect

Fejer, Martin M.

10

Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy  

SciTech Connect (OSTI)

Atom flux sensors based on atomic absorption (AA) spectroscopy are of significant interest in thin film growth as they can provide unobtrusive, element specific, real-time flux sensing and control. The ultimate sensitivity and performance of the sensors are strongly affected by the long-term and short term baseline drift. Here we demonstrate that an etalon effect resulting from temperature changes in optical viewport housings is a major source of signal instability which has not been previously considered or corrected by existing methods. We show that small temperature variations in the fused silica viewports can introduce intensity modulations of up to 1.5%, which in turn significantly deteriorate AA sensor performance. This undesirable effect can be at least partially eliminated by reducing the size of the beam and tilting the incident light beam off the viewport normal.

Du, Yingge; Chambers, Scott A.

2014-10-20T23:59:59.000Z

11

Atomic structure of machined semiconducting chips: An x-ray absorption spectroscopy study  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) has been used to examine the atomic structure of chips of germanium that were produced by single point diamond machining. It is demonstrated that although the local (nearest neighbor) atomic structure is experimentally quite similar to that of single crystal specimens information from more distant atoms indicates the presence of considerable stress. An outline of the technique is given and the strength of XAS in studying the machining process is demonstrated.

Paesler, M.; Sayers, D.

1988-12-01T23:59:59.000Z

12

Double-resonant x-ray and microwave absorption: Atomic spectroscopy of precessional orbital and spin dynamics  

E-Print Network [OSTI]

Double-resonant x-ray and microwave absorption: Atomic spectroscopy of precessional orbital of atomic species driven to ferromagnetic resonance. X-ray absorption measurements performed as a function of paramagnetic atoms can be determined by de- tecting the absorption or emission of light modulated by a MW field

Brune, Harald

13

E-Print Network 3.0 - analytical atomic spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Atomic emission spectroscopy Atomic fluorescence...

14

E-Print Network 3.0 - atomic spectroscopy technologies Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Atomic emission spectroscopy Atomic fluorescence...

15

Self-corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy  

SciTech Connect (OSTI)

A high sensitivity atom flux sensor based on atomic absorption spectroscopy has been designed and implemented to control electron beam evaporators and effusion cells in a molecular beam epitaxy system. Using a high-resolution spectrometer and a two-dimensional charge coupled device (CCD) detector in a double-beam configuration, we employ a non-resonant line or a resonant line with lower absorbance from the same hollow cathode lamp as the reference for nearly perfect background correction and baseline drift removal. This setup also significantly shortens the warm-up time needed compared to other sensor technologies and drastically reduces the noise coming from the surrounding environment. In addition, the high-resolution spectrometer allows the most sensitive resonant line to be isolated and used to provide excellent signal-to-noise ratio.

Du, Yingge; Droubay, Timothy C.; Liyu, Andrey V.; Li, Guosheng; Chambers, Scott A.

2014-04-24T23:59:59.000Z

16

E-Print Network 3.0 - atomic spectroscopy study Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Atomic emission ... Source: Yucca Mountain Project,...

17

E-Print Network 3.0 - absorption spectroscopy measurements Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Auger electron ... Source: Yucca Mountain Project, US...

18

New Homogeneous Standards by Atomic Layer Deposition for Synchrotron X-ray Fluorescence and Absorption Spectroscopies.  

SciTech Connect (OSTI)

Quantification of synchrotron XRF analyses is typically done through comparisons with measurements on the NIST SRM 1832/1833 thin film standards. Unfortunately, these standards are inhomogeneous on small scales at the tens of percent level. We are synthesizing new homogeneous multilayer standards using the Atomic Layer Deposition technique and characterizing them using multiple analytical methods, including ellipsometry, Rutherford Back Scattering at Evans Analytical, Synchrotron X-ray Fluorescence (SXRF) at Advanced Photon Source (APS) Beamline 13-ID, Synchrotron X-ray Absorption Spectroscopy (XAS) at Advanced Light Source (ALS) Beamlines 11.0.2 and 5.3.2.1 and by electron microscopy techniques. Our motivation for developing much-needed cross-calibration of synchrotron techniques is borne from coordinated analyses of particles captured in the aerogel of the NASA Stardust Interstellar Dust Collector (SIDC). The Stardust Interstellar Dust Preliminary Examination (ISPE) team have characterized three sub-nanogram, {approx}1{micro}m-sized fragments considered as candidates to be the first contemporary interstellar dust ever collected, based on their chemistries and trajectories. The candidates were analyzed in small wedges of aerogel in which they were extracted from the larger collector, using high sensitivity, high spatial resolution >3 keV synchrotron x-ray fluorescence spectroscopy (SXRF) and <2 keV synchrotron x-ray transmission microscopy (STXM) during Stardust ISPE. The ISPE synchrotron techniques have complementary capabilities. Hard X-ray SXRF is sensitive to sub-fg mass of elements Z {ge} 20 (calcium) and has a spatial resolution as low as 90nm. X-ray Diffraction data were collected simultaneously with SXRF data. Soft X-ray STXM at ALS beamline 11.0.2 can detect fg-mass of most elements, including cosmochemically important oxygen, magnesium, aluminum and silicon, which are invisible to SXRF in this application. ALS beamline 11.0.2 has spatial resolution better than 25 nm. Limiting factors for Stardust STXM analyses were self-imposed limits of photon dose due to radiation damage concerns, and significant attenuation of <1500 eV X-rays by {approx}80{micro}m thick, {approx}25 mg/cm{sup 3} density silica aerogel capture medium. In practice, the ISPE team characterized the major, light elements using STXM (O, Mg, Al, Si) and the heavier minor and trace elements using SXRF. The two data sets overlapped only with minor Fe and Ni ({approx}1% mass abundance), providing few quantitative cross-checks. New improved standards for cross calibration are essential for consortium-based analyses of Stardust interstellar and cometary particles, IDPs. Indeed, they have far reaching application across the whole synchrotron-based analytical community. We have synthesized three ALD multilayers simultaneously on silicon nitride membranes and silicon and characterized them using RBS (on Si), XRF (on Si{sub 3}N{sub 4}) and STXM/XAS (holey Si{sub 3}N{sub 4}). The systems we have started to work with are Al-Zn-Fe and Y-Mg-Er. We have found these ALD multi-layers to be uniform at {micro}m- to nm scales, and have found excellent consistency between four analytical techniques so far. The ALD films can also be used as a standard for e-beam instruments, eg., TEM EELS or EDX. After some early issues with the consistency of coatings to the back-side of the membrane windows, we are confident to be able to show multi-analytical agreement to within 10%. As the precision improves, we can use the new standards to verify or improve the tabulated cross-sections.

Butterworth, A.L.; Becker, N.; Gainsforth, Z.; Lanzirotti, A.; Newville, M.; Proslier, T.; Stodolna, J.; Sutton, S.; Tyliszczak, T.; Westphal, A.J.; Zasadzinski, J. (UCB)

2012-03-13T23:59:59.000Z

19

Harmonic wavelet analysis of modulated tunable diode laser absorption spectroscopy signals  

E-Print Network [OSTI]

of the direct absorption characteristics of atomic or molecular absorption lines. This is accomplishedHarmonic wavelet analysis of modulated tunable diode laser absorption spectroscopy signals Hong analyses of tunable diode laser absorption spectroscopy signals were performed. The absorption spectroscopy

Cheng, Harry H.

20

X-ray absorption spectroscopy  

E-Print Network [OSTI]

009-9473-8 REVIEW X-ray absorption spectroscopy Junko Yano Æand application of X-ray absorption spectroscopy, bothX-ray absorption near-edge structure (XANES) and extended X-

Yano, Junko; Yachandra, Vittal K.

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

X-ray Absorption Spectroscopy  

E-Print Network [OSTI]

type: Review X-ray Absorption Spectroscopy Junko Yano andPhotosystem II; XAS, X-ray absorption spectroscopy; EXAFS,X-ray absorption fine structure; EPR, electron paramagnetic

Yano, Junko

2010-01-01T23:59:59.000Z

22

Transient Absorption Spectroscopy with Isolated Attosecond Pulses  

E-Print Network [OSTI]

viii Attosecond transient absorption instrument. . . . . .5.2.2 AbsorptionTransient absorption spectroscopy . . . . . . . . . . . .

Bell, Marie Justine

2013-01-01T23:59:59.000Z

23

Hyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

the frequency of a laser with respect to an atomic spectral feature.[20] As such, saturated absorptionHyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 Broadening Mechanisms . . . . . . . . . . . . . . . . . . . . . 15 3.4 Saturated Absorption

Cronin, Alex D.

24

E-Print Network 3.0 - absorption spectroscopy techniques Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... 109 3.4 Spectroscopic Sensors Spectroscopy is the scientific study of...

25

Absorption-Line Spectroscopy of Planetary Nebulae with FUSE: Probing the Molecular, Atomic, and Ionized Gas  

E-Print Network [OSTI]

The central stars of planetary nebulae (PNe) are natural targets for FUSE due to their UV brightness. The FUSE spectra of many PNe show absorption features due to circumstellar material in species ranging from H_2 and neutrals in the photodissociation region (PDR) to ions resident in the H II region. We report results from a program designed to search for nebular components in the H_2 Lyman and Werner resonance lines that are responsible for the fluorescent excitation of H_2 in strong FUV radiation fields. Our failure to detect H_2 in absorption in several PNe with strong near-infrared H_2 emission indicates that the molecular material has an asymmetrical or clumpy distribution. We also detect enrichments in the s-process product Ge, find that Fe is not depleted into dust along at least one line of sight through a PN, and show that starlight fluorescence can affect the populations of the excited fine-structure levels of O I.

Harriet L. Dinerstein; N. C. Sterling; Charles W. Bowers

2004-10-25T23:59:59.000Z

26

Low temperature hydrogen plasma-assisted atomic layer deposition of copper studied using in situ infrared reflection absorption spectroscopy  

SciTech Connect (OSTI)

Atomic layer deposition (ALD) is an ideal technique to deposit ultrathin, conformal, and continuous metal thin films. However, compared to the ALD of binary materials such as metal oxides and metal nitrides, the surface reaction mechanisms during metal ALD are not well understood. In this study, the authors have designed and implemented an in situ reflection-absorption infrared spectroscopy (IRAS) setup to study the surface reactions during the ALD of Cu on Al{sub 2}O{sub 3} using Cu hexafluoroacetylacetonate [Cu(hfac){sub 2}] and a remote H{sub 2} plasma. Our infrared data show that complete ligand-exchange reactions occur at a substrate temperature of 80?°C in the absence of surface hydroxyl groups. Based on infrared data and previous studies, the authors propose that Cu(hfac){sub 2} dissociatively chemisorbs on the Al{sub 2}O{sub 3} surface, where the Al-O-Al bridge acts as the surface reactive site, leading to surface O-Cu-hfac and O-Al-hfac species. Surface saturation during the Cu(hfac){sub 2} half-cycle occurs through blocking of the available chemisorption sites. In the next half-reaction cycle, H radicals from an H{sub 2} plasma completely remove these surface hfac ligands. Through this study, the authors have demonstrated the capability of in situ IRAS as a tool to study surface reactions during ALD of metals. While transmission and internal reflection infrared spectroscopy are limited to the first few ALD cycles, IRAS can be used to probe all stages of metal ALD starting from initial nucleation to the formation of a continuous film.

Chaukulkar, Rohan P.; Rai, Vikrant R.; Agarwal, Sumit, E-mail: sagarwal@mines.edu [Department of Chemical and Biological Engineering, Colorado School of Mines, Golden, Colorado 80401 (United States); Thissen, Nick F. W. [Department of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven (Netherlands)

2014-01-15T23:59:59.000Z

27

A passive measurement of dissociated atom densities in atmospheric pressure air discharge plasmas using vacuum ultraviolet self-absorption spectroscopy  

SciTech Connect (OSTI)

We demonstrate a method for determining the dissociation degree of atmospheric pressure air discharges by measuring the self-absorption characteristics of vacuum ultraviolet radiation from O and N atoms in the plasma. The atom densities are determined by modeling the amount of radiation trapping present in the discharge, without the use of typical optical absorption diagnostic techniques which require external sources of probing radiation into the experiment. For an 8.0?mm spark discharge between needle electrodes at atmospheric pressure, typical peak O atom densities of 8.5?×?10{sup 17}?cm{sup ?3} and peak N atom densities of 9.9?×?10{sup 17}?cm{sup ?3} are observed within the first ?1.0?mm of plasma near the anode tip by analyzing the OI and NI transitions in the 130.0–132.0?nm band of the vacuum ultraviolet spectrum.

Laity, George [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering and Department of Physics, Texas Tech University, Lubbock, Texas 79409 (United States); Applied Science and Technology Maturation Department, Sandia National Laboratories, Albuquerque, New Mexico 87123 (United States); Fierro, Andrew; Dickens, James; Neuber, Andreas [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering and Department of Physics, Texas Tech University, Lubbock, Texas 79409 (United States); Frank, Klaus [Erlangen Centre for Astroparticle Physics, Department of Physics, Friedrich–Alexander University at Erlangen-Nürnberg, 91058 Erlangen (Germany)

2014-03-28T23:59:59.000Z

28

Laser Locking with Doppler-free Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

there are many ways to stabilize the frequency of a laser, atomic absorption lines are particularly accurate are made, it becomes possible to resolve the saturated absorption lines that correspond to specific atomic absorption spectroscopy. This affects the number of atoms in the ground state and excited state

Novikova, Irina

29

Absorption properties of identical atoms  

SciTech Connect (OSTI)

Emission rates and other optical properties of multi-particle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas. -- Highlights: •The absorption rates of a pair of identical atoms in product and (anti)symmetrized states are different. •The modifications of the optical properties are essentially determined by the overlapping between the atoms. •The absorption properties differ, in some cases, for bosons and fermions.

Sancho, Pedro, E-mail: psanchos@aemet.es

2013-09-15T23:59:59.000Z

30

Extended Xray Absorption Fine Structure Spectroscopy (EXAFS) Provides details on how x rays are absorbed by an atom at energies near X18A,B,X19A Provides details on how xrays are absorbed by an atom at energies near  

E-Print Network [OSTI]

's xray absorption probability due to the chemical and physical state of the atom · Especially sensitiveExtended Xray Absorption Fine Structure Spectroscopy (EXAFS) · Provides details on how x rays are absorbed by an atom at energies near X18A,B,X19A· Provides details on how xrays are absorbed by an atom

Ohta, Shigemi

31

Absorption properties of identical atoms  

E-Print Network [OSTI]

Emission rates and other optical properties of multiparticle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas.

Pedro Sancho

2013-07-31T23:59:59.000Z

32

E-Print Network 3.0 - atomic fluorescence spectroscopy Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

total reflectance... increasing. A partial sampling of these techniques includes: Absorption spectroscopy Atomic ... Source: Yucca Mountain Project, US EPA Collection:...

33

E-Print Network 3.0 - absorption spectroscopy Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

.619 nm Calculate the energy of the photon: h 1.633 aJ Absorption Spectroscopy In absorption... Atomic Spectroscopy Planck's constant: h 6.62608 10 34- joule sec: Speed of...

34

E-Print Network 3.0 - absorption spectroscopy q-xas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

.619 nm Calculate the energy of the photon: h 1.633 aJ Absorption Spectroscopy In absorption... Atomic Spectroscopy Planck's constant: h 6.62608 10 34- joule sec: Speed of...

35

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network [OSTI]

2/9/07 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 9, 07] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

36

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network [OSTI]

9/6/09 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 6, 09] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

37

E-Print Network 3.0 - atomic spectroscopy programacion Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... coordinated to...

38

E-Print Network 3.0 - atomic spectroscopy sympsoium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... coordinated to...

39

Ultrafast X-ray Absorption Spectroscopy using Laser-Driven Electron X-ray Sources (LEXS)  

E-Print Network [OSTI]

: ultrafast x-rays, x-ray absorption spectroscopy, terawatt lasers, ultrafast reaction dynamics, atomic motion atomic motion by scrutinizing the changes in x- ray absorption spectra during reactions. FirstUltrafast X-ray Absorption Spectroscopy using Laser-Driven Electron X-ray Sources (LEXS) Guangjun

Guo, Ting

40

Combining Feedback Absorption Spectroscopy, Amplified Resonance...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling Cummins...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Atomic resolution mapping of the excited-state electronic structure of Cu2O with time-resolved x-ray absorption spectroscopy  

SciTech Connect (OSTI)

We have used time-resolved soft x-ray spectroscopy to investigate the electronic structure of optically excited cuprous oxide at the O K-edge and the Cu L3-edge. The 400 nm optical excitation shifts the Cu and O absorptions to lower energy, but does not change the integrated x-ray absorption significantly for either edge. The constant integrated x-ray absorption cross-section indicates that the conduction-band and valence-band edges have very similar Cu 3d and O 2p orbital contributions. The 2.1 eV optical band gap of Cu2O significantly exceeds the one eV shift in the Cu L3- and O K-edges absorption edges induced by optical excitation, demonstrating the importance of core-hole excitonic effects and valence electron screening in the x-ray absorption process.

Hillyard, P. W.; Kuchibhatla, S. V. N. T.; Glover, T. E.; Hertlein, M. P.; Huse, Nils; Nachimuthu, P.; Saraf, L. V.; Thevuthasan, S.; Gaffney, K. J.

2010-05-02T23:59:59.000Z

42

X-ray Absorption Spectroscopy of Biologically Relevant Systems  

E-Print Network [OSTI]

308, Messer, B. M. X-ray Absorption Spectroscopy of AqueousSarcosine via X-ray Absorption Spectroscopy 5.1 Introductionwith Carboxylate by X-Ray Absorption Spectroscopy of Liquid

Uejio, Janel Sunayo

2010-01-01T23:59:59.000Z

43

E-Print Network 3.0 - atomization atomic absorption Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic absorption Search Powered by Explorit Topic List Advanced Search Sample search results for: atomization atomic absorption Page: << < 1 2 3 4 5 > >> 1 :coherently trapped in...

44

3.4 Spectroscopic Sensors Spectroscopy is the scientific study of the absorption, emission, or scattering of  

E-Print Network [OSTI]

increasing. A partial sampling of these techniques includes: · Absorption spectroscopy · Atomic absorption109 3.4 Spectroscopic Sensors Spectroscopy is the scientific study of the absorption, emission, or scattering of electromagnetic radiation by atoms, molecules, ions, solids, liquids, or gases. The underlying

45

Stark spectroscopy on rare gas atoms  

E-Print Network [OSTI]

Stark spectroscopy on rare gas atoms PROEFSCHRIFT ter verkrijging van de graad van doctor aan de-DATA LIBRARY TECHNISCHE UNIVERSITEIT EINDHOVEN Jiang, Tao Stark spectroscopy on rare gas atoms / by Tao Jiang / gasontladingen Subject headings : plasma diagnostics / Stark effect / optogalvanic spectroscopy / atomic emission

Eindhoven, Technische Universiteit

46

Methods for measurement of heterogeneous materials with laser-induced breakdown spectroscopy (LIBS)  

E-Print Network [OSTI]

2000. 15) Welz B, Atomic Absorption Spectrometry, ThirdFor elemental analyses atomic absorption spectroscopy iscommonly used (15). Atomic absorption spectroscopy works by

Effenberger, Andrew Jay

2009-01-01T23:59:59.000Z

47

X-RAY ABSORPTION SPECTROSCOPY FOR THE CHEMICAL CHARACTERIZATION OF ATMOSPHERIC AEROSOLS  

E-Print Network [OSTI]

November 11-16 9 1979 X-RAY ABSORPTION SPECTROSCOPY FOR THEUniversity of California. ABSORPTION SPECTROSCOPY FOR THEand x-ray emission and absorption spectroscopy. The first

Jaklevic, J. M.

2011-01-01T23:59:59.000Z

48

Atomic Absorption Method Guide Zn in Copper Alloys  

E-Print Network [OSTI]

Atomic Absorption Method Guide Zn in Copper Alloys Principle The sample is digested in nitric/hydrochloric acid, and zinc is determined by flame atomic absorption spectrometry using an air-acetylene flame · Copper Alloys · Zinc · Flame · Atomic Absorption Method Guide: 40158 #12;©2008 Thermo Fisher Scientific

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

49

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films  

E-Print Network [OSTI]

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic

50

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network [OSTI]

A. B. Optical System Absorption Signal C. Small SignalNoise . Sensitivity of Absorption Spectroscopy EXPERIMENTSINFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

51

Photoassociative molecular spectroscopy for atomic radiative lifetimes.  

E-Print Network [OSTI]

very far apart, in so-called long- range molecular states, their mutual interaction is ruled by plain atomic properties. The high- resolution spectroscopic study of some molecular excited states populated by photoassociation of cold atoms (photoassociative spectroscopy) gives a good illustration of this property

Boyer, Edmond

52

E-Print Network 3.0 - absorption spectroscopy characterization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Restoration Technologies 87 Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky* Summary: absorption...

53

Atomic Absorption Spectrometry Perkin Elmer 500, Chemistry & Biochemistry  

E-Print Network [OSTI]

Atomic Absorption Spectrometry · Perkin Elmer 500, Chemistry & Biochemistry · Perkin Elmer 560 AA-star stopped flow with absorption, fluorescence and circular dichroism detection · KinTek quench flow apparatus

Gruner, Daniel S.

54

Silicon Photonics for chemical sensing and spectroscopy, diagnosis and therapy  

E-Print Network [OSTI]

5.5. Single-shot atomic absorption spectroscopy of rubidium26] time-wavelength atomic absorption spectroscopy of the D5.5. Single-shot atomic absorption spectroscopy of rubidium

Hon, Kam Yan

2012-01-01T23:59:59.000Z

55

Transient absorption spectroscopy of laser shocked explosives  

SciTech Connect (OSTI)

Transient absorption spectra from 390-890 nm of laser shocked RDX, PETN, sapphire, and polyvinylnitrate (PVN) at sub-nanosecond time scales are reported. RDX shows a nearly linear increase in absorption with time after shock at {approx}23 GPa. PETN is similar, but with smaller total absorption. A broad visible absorption in sapphire begins nearly immediately upon shock loading but does not build over time. PVN exhibits thin film interference in the absorption spectra along with increased absorption with time. The absorptions in RDX and PETN are suggested to originate in chemical reactions happening on picosecond time scales at these shock stresses, although further diagnostics are required to prove this interpretation.

Mcgrane, Shawn D [Los Alamos National Laboratory; Dang, Nhan C [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Bolome, Cindy A [Los Alamos National Laboratory; Moore, D S [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

56

absorption spectroscopy study: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 On Automatic Absorption Detection for Imaging Spectroscopy: A Comparative Study Computer Technologies and...

57

Direct and quantitative absorptive spectroscopy of nanowires  

E-Print Network [OSTI]

Photonic nanostructures exhibit unique optical properties that are attractive in many different applications. However, measuring the optical properties of individual nanostructures, in particular the absorptive properties, ...

Tong, Jonathan Kien-Kwok

2012-01-01T23:59:59.000Z

58

absorption spectroscopy studies: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption spectroscopy studies First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 On Automatic Absorption...

59

Multiplexed absorption tomography with calibration-free wavelength modulation spectroscopy  

SciTech Connect (OSTI)

We propose a multiplexed absorption tomography technique, which uses calibration-free wavelength modulation spectroscopy with tunable semiconductor lasers for the simultaneous imaging of temperature and species concentration in harsh combustion environments. Compared with the commonly used direct absorption spectroscopy (DAS) counterpart, the present variant enjoys better signal-to-noise ratios and requires no baseline fitting, a particularly desirable feature for high-pressure applications, where adjacent absorption features overlap and interfere severely. We present proof-of-concept numerical demonstrations of the technique using realistic phantom models of harsh combustion environments and prove that the proposed techniques outperform currently available tomography techniques based on DAS.

Cai, Weiwei; Kaminski, Clemens F., E-mail: cfk23@cam.ac.uk [Department of Chemical Engineering and Biotechnology, University of Cambridge, Cambridge CB2 3RA (United Kingdom)

2014-04-14T23:59:59.000Z

60

Atomic and Molecular Absorption at High Redshift  

E-Print Network [OSTI]

Strong constraints on possible variations in fundamental constants can be derived from HI 21-cm and molecular rotational absorption lines observed towards quasars. With the aim of forming a statistical sample of constraints we have begun a program of systematic searches for such absorption systems. Here we describe molecular rotational searches in 25 damped Lyman-alpha systems where, in many cases, we set optical depth limits an order of magnitude better than that required to detect the 4 known redshifted millimeter-wave absorbers. We also discuss the contributory factors in the detectability of HI 21-cm absorption, focusing on possible biases (e.g.low covering factors) in the currently known sample of absorbers and non-detections.

S. J. Curran; J. K. Webb; M. T. Murphy; Y. M. Pihlström

2004-05-14T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

X-ray Absorption Spectroscopy Study of Prototype Chemical Systems: Theory vs. Experiment  

E-Print Network [OSTI]

acids by Near Edge X-ray Absorption Fine Structure (NEXAFS)X-ray Absorption Spectroscopy Study of Prototype ChemicalGlaeser Spring 2010 X-ray Absorption Spectroscopy Study of

Schwartz, Craig Philip

2010-01-01T23:59:59.000Z

62

X-ray absorption spectroscopy at the Ni-K edge in Stackhousia tryonii Bailey hyperaccumulator  

E-Print Network [OSTI]

X-ray absorption spectroscopy at the Ni–K edge inin vivo by micro x-ray absorption spectroscopy (XAS) at theNi–K edge. Both x-ray absorption near edge structure and

Kachenko, A.

2009-01-01T23:59:59.000Z

63

Absolute absorption spectroscopy based on molecule interferometry  

E-Print Network [OSTI]

We propose a new method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photo-induced fragmentation or ionization. The method is based on resolving the recoil resulting from photon absorption by means of near-field matter-wave interference, and it thus applies even to very dilute beams with low optical densities. Our discussion includes the possibility of internal state conversion as well as fluorescence. We assess the influence of various experimental uncertainties and show that the measurement of absolute absorption cross sections is conceivable with high precision and using existing technologies.

Stefan Nimmrichter; Klaus Hornberger; Hendrik Ulbricht; Markus Arndt

2008-11-07T23:59:59.000Z

64

Cavity-induced two-photon absorption in unidentical atoms M. S. Kim1,  

E-Print Network [OSTI]

Cavity-induced two-photon absorption in unidentical atoms M. S. Kim1, * and G. S. Agarwal1,2 1 Max-photon absorption in unidentical atoms, and demonstrate the nonclassical character of this two-photon absorption. We-photon absorption in two unidentical atoms in a cavity. In a cavity the atoms interact with a common quantized

Kim, Myungshik

65

E-Print Network 3.0 - atomic absorption method Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

method Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption method...

66

E-Print Network 3.0 - atomic absorption spectrometr Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectrometr Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometr...

67

E-Print Network 3.0 - atomic absorption spectrometric Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectrometric Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometric...

68

E-Print Network 3.0 - atomic absorption methods Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

methods Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption methods...

69

Optical Spectroscopy of Hydrogenic Atoms MIT Department of Physics  

E-Print Network [OSTI]

Optical Spectroscopy of Hydrogenic Atoms MIT Department of Physics (Dated: September 1, 2013) This experiment is an exercise in optical spectroscopy in a study of the spectra of "hydrogenic" atoms, i.e. atoms with one "optical" electron outside a closed shell of other electrons. Measurements include finding

Seager, Sara

70

Quantized Media with Absorptive Scatterers and Modified Atomic Emission Rates  

E-Print Network [OSTI]

Modifications in the spontaneous emission rate of an excited atom that are caused by extinction effects in a nearby dielectric medium are analyzed in a quantummechanical model, in which the medium consists of spherical scatterers with absorptive properties. Use of the dyadic Green function of the electromagnetic field near a a dielectric sphere leads to an expression for the change in the emission rate as a series of multipole contributions for which analytical formulas are obtained. The results for the modified emission rate as a function of the distance between the excited atom and the dielectric medium show the influence of both absorption and scattering processes.

L. G. Suttorp; A. J. van Wonderen

2011-02-14T23:59:59.000Z

71

Molecular shock response of explosives: electronic absorption spectroscopy  

SciTech Connect (OSTI)

Electronic absorption spectroscopy in the range 400-800 nm was coupled to ultrafast laser generated shocks to begin addressing the question of the extent to which electronic excitations are involved in shock induced reactions. Data are presented on shocked polymethylmethacrylate (PMMA) thin films and single crystal pentaerythritol tetranitrate (PETN). Shocked PMMA exhibited thin film interference effects from the shock front. Shocked PETN exhibited interference from the shock front as well as broadband increased absorption. Relation to shock initiation hypotheses and the need for time dependent absorption data (future experiments) is briefly discussed.

Mcgrne, Shawn D [Los Alamos National Laboratory; Moore, David S [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Bolme, Cindy A [Los Alamos National Laboratory; Eakins, Daniel E [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

72

Heralded single photon absorption by a single atom  

E-Print Network [OSTI]

The emission and absorption of single photons by single atomic particles is a fundamental limit of matter-light interaction, manifesting its quantum mechanical nature. At the same time, as a controlled process it is a key enabling tool for quantum technologies, such as quantum optical information technology [1, 2] and quantum metrology [3, 4, 5, 6]. Controlling both emission and absorption will allow implementing quantum networking scenarios [1, 7, 8, 9], where photonic communication of quantum information is interfaced with its local processing in atoms. In studies of single-photon emission, recent progress includes control of the shape, bandwidth, frequency, and polarization of single-photon sources [10, 11, 12, 13, 14, 15, 16, 17], and the demonstration of atom-photon entanglement [18, 19, 20]. Controlled absorption of a single photon by a single atom is much less investigated; proposals exist but only very preliminary steps have been taken experimentally such as detecting the attenuation and phase shift of a weak laser beam by a single atom [21, 22], and designing an optical system that covers a large fraction of the full solid angle [23, 24, 25]. Here we report the interaction of single heralded photons with a single trapped atom. We find strong correlations of the detection of a heralding photon with a change in the quantum state of the atom marking absorption of the quantum-correlated heralded photon. In coupling a single absorber with a quantum light source, our experiment demonstrates previously unexplored matter-light interaction, while opening up new avenues towards photon-atom entanglement conversion in quantum technology.

Nicolas Piro; Felix Rohde; Carsten Schuck; Marc Almendros; Jan Huwer; Joyee Ghosh; Albrecht Haase; Markus Hennrich; Francois Dubin; Jürgen Eschner

2010-04-23T23:59:59.000Z

73

Absorption spectroscopy of individual single-walled carbon nanotubes  

E-Print Network [OSTI]

Absorption spectroscopy of individual single-walled carbon nanotubes Stéphane Berciaud,a Laurent-walled carbon nanotubes (SWNTs) lead to heterogeneous samples containing mixtures of metallic and semiconducting species with a variety of lengths and defects. Optical detection at the single nanotube level should thus

Boyer, Edmond

74

Laser photothermal spectroscopy of light-induced absorption  

SciTech Connect (OSTI)

Basic methods of laser photothermal spectroscopy, which are used to study photoinduced absorption in various media, are briefly considered. Comparative analysis of these methods is performed and the latest results obtained in this field are discussed. Different schemes and examples of their practical implementation are considered. (review)

Skvortsov, L A [Institute of Cryptography, Communications and Informatics, Moscow (Russian Federation)

2013-01-31T23:59:59.000Z

75

Time resolved ultraviolet absorption spectroscopy of pulsed fluorocarbon plasmas  

E-Print Network [OSTI]

Time resolved ultraviolet absorption spectroscopy of pulsed fluorocarbon plasmas Brett A. Cruden.1063/1.1334936 I. INTRODUCTION The study of fluorocarbon plasmas is of great interest for their applications in silicon dioxide etching.1,2 Recently, at- tention has been paid to using fluorocarbon plasmas to pro- duce

Gleason, Karen K.

76

absorption spectroscopy xas: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption spectroscopy xas First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Time Resolved X-Ray...

77

E-Print Network 3.0 - absorption spectroscopies progress Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nanoantenna arrays Summary: absorption (SEIRA) spectroscopy (7-14). Until recently, the bulk of SEIRA studies have revolved around... collectively en- hanced IR absorption...

78

Absorption spectrum of Ca atoms attached to $^4$He nanodroplets  

E-Print Network [OSTI]

Within density functional theory, we have obtained the structure of $^4$He droplets doped with neutral calcium atoms. These results have been used, in conjunction with newly determined {\\it ab-initio} $^1\\Sigma$ and $^1\\Pi$ Ca-He pair potentials, to address the $4s4p$ $^1$P$_1 \\leftarrow 4s^2$ $^1$S$_0$ transition of the attached Ca atom, finding a fairly good agreement with absorption experimental data. We have studied the drop structure as a function of the position of the Ca atom with respect of the center of mass of the helium moiety. The interplay between the density oscillations arising from the helium intrinsic structure and the density oscillations produced by the impurity in its neighborhood plays a role in the determination of the equilibrium state, and hence in the solvation properties of alkaline earth atoms. In a case of study, the thermal motion of the impurity within the drop surface region has been analyzed in a semi-quantitative way. We have found that, although the atomic shift shows a sizeable dependence on the impurity location, the thermal effect is statistically small, contributing by about a 10% to the line broadening. The structure of vortices attached to the calcium atom has been also addressed, and its effect on the calcium absorption spectrum discussed. At variance with previous theoretical predictions, we conclude that spectroscopic experiments on Ca atoms attached to $^4$He drops will be likely unable to detect the presence of quantized vortices in helium nanodrops.

Alberto Hernando; Manuel Barranco; Marek Kro?nicki; Ricardo Mayol; Martí Pi

2007-11-12T23:59:59.000Z

79

Role of transient processes in resonance line spectroscopy of caesium atoms in cells with antirelaxation coating  

SciTech Connect (OSTI)

We study the peculiarities of the absorption spectra in D{sub 1,2}-lines of Cs, caused by optical pumping in cells with antirelaxation coating. In these cells the internal state of the atom, which arose under optical pumping by a monochromatic laser field, is preserved with a high probability in a collision with the wall. As a result, the optical pumping action extends to the entire volume of the cell and to all the velocities of the atoms. This leads to the speed-dependent scanning distortions of the absorption line profile. The detected features should be considered when using laserpumped quantum magnetometers with antirelaxation-coated cells. (laser spectroscopy)

Sevost'yanov, D I; Yakovlev, V P; Kozlov, A N; Vasil'ev, V V; Zibrov, S A; Velichansky, Vladimir L

2013-07-31T23:59:59.000Z

80

E-Print Network 3.0 - atomic absorption technique Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption technique Page: << < 1 2 3 4 5 > >> 1 Xray Absorption Near Edge...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

E-Print Network 3.0 - atomic absorption determination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption determination Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine...

82

SciTech Connect: The determination of aluminum by atomic absorption...  

Office of Scientific and Technical Information (OSTI)

Language: English Subject: CHEMISTRY; ABSORPTION; ALUMINUM; CEMENTS; CHLORIDES; COMBUSTION; PHOTOMETRY; QUANTITATIVE ANALYSIS; SILICON OXIDES; SOLUTIONS; SPECTROSCOPY; STEELS...

83

Single photon absorption by a single atom: from heralded absorption to polarization state mapping  

E-Print Network [OSTI]

Together with photon emission, the absorption of a single photon by a single atom is a fundamental process in matter-light interaction that manifests its quantum mechanical nature. As an experimentally controlled process, it is a key tool for the realization of quantum technologies. In particular, in an atom/photon based quantum network scenario, in which localized atomic particles are used as quantum information processing nodes while photons are used as carriers of quantum information between distant nodes, controlling both emission and absorption of single photons by single atoms is required for quantum coherent state mapping between the two entities. Most experimental efforts to date have focused on establishing the control of single photon emission by single trapped atoms, and the implementation of quantum networking protocols using this interaction. In this chapter, we describe experimental efforts to control the process of single photon absorption by single trapped ions. We describe a series of experiments in which polarization entangled photon pairs, generated by a spontaneous parametric down-conversion source, are coupled to a single ion. First the source is operated to generate heralded single photons, and coincidences between the absorption event of one photon of the pair and the detection of the heralding partner photon are observed. We then show how polarization control in the process is established, leading to the manifestation of the photonic polarization entanglement in the absorption process. Finally, we introduce protocols in which this interaction scheme is harnessed to perform tasks in a quantum network, such as entanglement distribution among distant nodes of the network, and we demonstrate a specific protocol for heralded, high-fidelity photon-to-atom quantum state transfer.

Nicolas Piro; Jürgen Eschner

2015-02-19T23:59:59.000Z

84

Infrared absorption spectroscopy and chemical kinetics of free radicals  

SciTech Connect (OSTI)

This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

Curl, R.F.; Glass, G.P. [Rice Univ., Houston, TX (United States)

1993-12-01T23:59:59.000Z

85

Single-Photon Absorption in Coupled Atom-Cavity Systems  

E-Print Network [OSTI]

We show how to capture a single photon of arbitrary temporal shape with one atom coupled to an optical cavity. Our model applies to Raman transitions in three-level atoms with one branch of the transition controlled by a (classical) laser pulse, and the other coupled to the cavity. Photons impinging on the cavity normally exhibit partial reflection, transmission, and/or absorption by the atom. Only a control pulse of suitable temporal shape ensures impedance matching throughout the pulse, which is necessary for complete state mapping from photon to atom. For most possible photon shapes, we derive an unambiguous analytic expression for the shape of this control pulse, and we discuss how this relates to a quantum memory.

Jerome Dilley; Peter Nisbet-Jones; Bruce W. Shore; Axel Kuhn

2012-03-01T23:59:59.000Z

86

AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS  

E-Print Network [OSTI]

II. Extended X-ray Absorption Fine Structure (EXAFS) TheoryIII. X-ray Absorption Spectroscopy (XAS) ExperimentIII. EXTENDED X-RAY ABSORPTION FINE STRUCTURE (EXAFS) DATA

Kirby, Jon Allan

2012-01-01T23:59:59.000Z

87

A survey for redshifted molecular and atomic absorption lines I  

E-Print Network [OSTI]

We are currently undertaking a large survey for redshifted atomic and molecular absorption ... only one clear and one tentative detection were obtained: HI absorption at z = 0.097 in PKS 1555-140 and OH absorption at z =0.126 in PKS 2300-189, respectively... In order to determine why no clear molecular absorption was detected in any of the 13 sources searched, we investigate the properties of the five redshifted systems currently known to exhibit OH absorption. In four of these, molecules were first detected via millimetre-wave transitions and the flat radio spectra indicate compact background continuum sources, which may suggest a high degree of coverage of the background source by the molecular clouds in the absorber. Furthermore, for these systems we find a relationship between the molecular line strength and red optical--near infrared (V-K) colours, thus supporting the notion that the reddening of these sources is due to dust, which provides an environment conducive to the formation of molecules. Upon comparison with the V-K colours of our sample, this relationship suggests that, presuming the reddening occurs at the host galaxy redshift at least in some of the targets, many of our observations still fall short of the sensitivityrequired to detect OH absorption, although a confirmation of the ``detection'' of OH in 2300-189 could contravene this.

S. J. Curran; M. T. Whiting; M. T. Murphy; J. K. Webb; S. N. Longmore; Y. M. Pihlstroem; R. Athreya; C. Blake

2006-07-26T23:59:59.000Z

88

E-Print Network 3.0 - active potassium absorption Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

decomposed in a heated carbon-tube furnace, and arsenic determined by measurement of its atomic-absorption... in its determination by atomic- absorption spectroscopy. Various...

89

Absorption by cold Fermi atoms in a harmonic trap  

E-Print Network [OSTI]

We study the absorption spectrum for a strongly degenerate Fermi gas confined in a harmonic trap. The spectrum is calculated using both the exact summation and also the Thomas-Fermi (TF) approximation. In the latter case, relatively simple analytical expressions are obtained for the absorption lineshape at large number of trapped atoms. At zero temperature, the approximated lineshape is characterized by a $(1-z^2)^{5/2}$ dependence which agrees well with the exact numerical calculations. At non-zero temperature, the spectrum becomes broader, although remains non-Gaussian as long as the fermion gas is degenerate. The changes in the trap frequency for an electronically excited atom can introduce an additional line broadening.

Gediminas Juzeliunas; Marius Masalas

2000-11-10T23:59:59.000Z

90

E-Print Network 3.0 - atomic force spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Langmuir trough Atomic force microscope Optical microscope... W ultrasonic horn Atomic absorption spectrophotometer UVVIS spectrophotometer Centrifuge p......

91

PHYSICAL REVIEW A 88, 043428 (2013) Transient absorption spectra of the laser-dressed hydrogen atom  

E-Print Network [OSTI]

PHYSICAL REVIEW A 88, 043428 (2013) Transient absorption spectra of the laser-dressed hydrogen atom.043428 PACS number(s): 32.80.Rm, 42.65.Ky I. INTRODUCTION Transient absorption spectra of laser-dressed atoms absorption spectra of hydrogen atoms based on numerical solutions of the time-dependent Schr¨odinger equation

Chu, Shih-I

92

ABSORPTION ET DIFFUSION DE PHOTONS OPTIQUES PAR UN ATOME EN INTERACTION AVEC DES PHOTONS DE RADIOFRQUENCE  

E-Print Network [OSTI]

153. ABSORPTION ET DIFFUSION DE PHOTONS OPTIQUES PAR UN ATOME EN INTERACTION AVEC DES PHOTONS DE'annuler. Ceci modifie de façon importante le spectre d'absorption de l'atome « habillé» en champ faible et l of the absorption spectrum of the "dressed" atom in a weak magnetic field and of the magnetic depolarization effect

Paris-Sud XI, Université de

93

FINGERPRINTING INORGANIC ARSENIC AND ORGANOARSENIC COMPOUNDS IN IN SITU OIL SHALE RETORT AND PROCESS VOTERS USING A LIQUID CHROMATOGRAPH COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR  

E-Print Network [OSTI]

COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTORCoupled with an Atomic Absorption Spectrometer as a DetectorcOUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR

Fish, Richard H.

2013-01-01T23:59:59.000Z

94

Optical Absorption and Photoluminescence Excitation Spectroscopy of SWNTs S. Maruyama1  

E-Print Network [OSTI]

Optical Absorption and Photoluminescence Excitation Spectroscopy of SWNTs S. Maruyama1 , Y-mail: maruyama@photon.t.u-tokyo.ac.jp Optical absorption and photoluminescence excitation (PLE) spectroscopy to the physical interest in unique excitonic features of 1-D material [3-5], clear identification of absorption

Maruyama, Shigeo

95

Absorption and photoluminescence spectroscopy on a single self-assembled charge-tunable quantum dot  

E-Print Network [OSTI]

Absorption and photoluminescence spectroscopy on a single self-assembled charge-tunable quantum dot PL and absorption spectroscopy on the same single self- assembled quantum dot in a charge the corresponding transition in absorption. We have developed a model of the Coulomb blockade to account

Ludwig-Maximilians-Universität, München

96

X-ray Absorption Spectroscopy: a powerful tool for the investigation  

E-Print Network [OSTI]

X-ray Absorption Spectroscopy: a powerful tool for the investigation of the role of metals is to illustrate the potentialities of X-ray Absorption Spectroscopy (XAS) to investigate structural properties Protein and Zinc ions 2 Introduction to the X-ray Absorption Spec- troscopy XAS uses Synchrotron Radiation

Morante, Silvia

97

Absorption spectroscopy of a laboratory photoionized plasma experiment at Z  

SciTech Connect (OSTI)

The Z facility at the Sandia National Laboratories is the most energetic terrestrial source of X-rays and provides an opportunity to produce photoionized plasmas in a relatively well characterised radiation environment. We use detailed atomic-kinetic and spectral simulations to analyze the absorption spectra of a photoionized neon plasma driven by the x-ray flux from a z-pinch. The broadband x-ray flux both photoionizes and backlights the plasma. In particular, we focus on extracting the charge state distribution of the plasma and the characteristics of the radiation field driving the plasma in order to estimate the ionisation parameter.

Hall, I. M.; Durmaz, T.; Mancini, R. C. [Physics Department, University of Nevada, Reno, Nevada 89557 (United States)] [Physics Department, University of Nevada, Reno, Nevada 89557 (United States); Bailey, J. E.; Rochau, G. A. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)] [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); Golovkin, I. E.; MacFarlane, J. J. [Prism Computational Sciences, Madison, Wisconsin 53711 (United States)] [Prism Computational Sciences, Madison, Wisconsin 53711 (United States)

2014-03-15T23:59:59.000Z

98

Direct atomic flux measurement of electron-beam evaporated yttrium with a diode-laser-based atomic absorption monitor at 668 nm  

E-Print Network [OSTI]

with a diode-laser-based atomic absorption AA monitor at 668 nm. Atomic number density and velocity were measured through absorption and Doppler shift measurements to provide the atomic flux. The AA previously developed diode-laser-based atomic absorption AA monitors for atomic density measurements

Fejer, Martin M.

99

Ge doped HfO{sub 2} thin films investigated by x-ray absorption spectroscopy  

SciTech Connect (OSTI)

The stability of the tetragonal phase of Ge doped HfO{sub 2} thin films on Si(100) was investigated. Hf(Ge)O{sub 2} films with Ge atomic concentrations varying from 0% to 15% were deposited by remote plasma chemical vapor deposition. The atomic structure on the oxide after rapid thermal annealing was investigated by x-ray absorption spectroscopy of the O and Ge K edges and by Rutherford backscattering spectrometry. The authors found that Ge concentrations as low as 5 at. % effectively stabilize the tetragonal phase of 5 nm thick Hf(Ge)O{sub 2} on Si and that higher concentrations are not stable to rapid thermal annealing at temperatures above 750 deg. C.

Miotti, Leonardo; Bastos, Karen P.; Lucovsky, Gerald; Radtke, Claudio; Nordlund, Dennis [Department of Physics, North Carolina State University, Box 8202, Raleigh, North Carolina 27695-8202 (United States); Instituto de Quimica, Universidade Federal do Rio Grande do Sul, 91509-900 Porto Alegre (Brazil); Stanford Synchrotron Radiation Lightsource, Menlo Park, California 94025 (United States)

2010-07-15T23:59:59.000Z

100

Optical re-injection in cavity-enhanced absorption spectroscopy  

SciTech Connect (OSTI)

Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10{sup ?10} cm{sup ?1}/?(Hz;) an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features.

Leen, J. Brian, E-mail: b.leen@lgrinc.com; O’Keefe, Anthony [Los Gatos Research, 67 E. Evelyn Avenue, Suite 3, Mountain View, California 94041 (United States)

2014-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

E-Print Network 3.0 - absorption line spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University Collection: Physics 88 Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky* Summary: absorption...

102

E-Print Network 3.0 - absorption spectroscopy aas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 18 Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky* Summary: absorption...

103

E-Print Network 3.0 - absorption spectroscopy investigation Sample...  

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Collection: Mathematics 79 Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky* Summary: absorption...

104

E-Print Network 3.0 - absorption spectroscopy distance Sample...  

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> >> Page: << < 1 2 3 4 5 > >> 41 Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky* Summary: absorption...

105

E-Print Network 3.0 - absorption spectroscopy principles Sample...  

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gas analysis Alexander Fateev, Snnik Clausen Summary: applications and in particular in atomicmolecular absorption spectroscopy, the transition moment is replaced... +CO+CO2)....

106

E-Print Network 3.0 - absorption spectroscopy establishes Sample...  

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gas analysis Alexander Fateev, Snnik Clausen Summary: applications and in particular in atomicmolecular absorption spectroscopy, the transition moment is replaced... +CO+CO2)....

107

E-Print Network 3.0 - absorption gamma-ray spectroscopy Sample...  

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by Explorit Topic List Advanced Search Sample search results for: absorption gamma-ray spectroscopy Page: << < 1 2 3 4 5 > >> 1 1090 IEEE TRANSACTIONS ON NUCLEAR SCIENCE,...

108

X-ray absorption spectroscopy elucidates the impact of structural disorder on electron mobility in amorphous zinc-tin-oxide thin films  

SciTech Connect (OSTI)

We investigate the correlation between the atomic structures of amorphous zinc-tin-oxide (a-ZTO) thin films grown by atomic layer deposition (ALD) and their electronic transport properties. We perform synchrotron-based X-ray absorption spectroscopy at the K-edges of Zn and Sn with varying [Zn]/[Sn] compositions in a-ZTO thin films. In extended X-ray absorption fine structure (EXAFS) measurements, signal attenuation from higher-order shells confirms the amorphous structure of a-ZTO thin films. Both quantitative EXAFS modeling and X-ray absorption near edge spectroscopy (XANES) reveal that structural disorder around Zn atoms increases with increasing [Sn]. Field- and Hall-effect mobilities are observed to decrease with increasing structural disorder around Zn atoms, suggesting that the degradation in electron mobility may be correlated with structural changes.

Siah, Sin Cheng, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu; Lee, Yun Seog; Buonassisi, Tonio, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Lee, Sang Woon; Gordon, Roy G. [Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138 (United States); Heo, Jaeyeong [Department of Materials Science and Engineering, Chonnam National University, Gwangju 500-757 (Korea, Republic of); Shibata, Tomohiro; Segre, Carlo U. [Physics Department and CSRRI, Illinois Institute of Technology, Chicago, Illinois 606016 (United States)

2014-06-16T23:59:59.000Z

109

Observables in Neutrino Mass Spectroscopy Using Atoms  

E-Print Network [OSTI]

The process of collective de-excitation of atoms in a metastable level into emission mode of a single photon plus a neutrino pair, called radiative emission of neutrino pair (RENP), is sensitive to the absolute neutrino mass scale, to the neutrino mass hierarchy and to the nature (Dirac or Majorana) of massive neutrinos. We investigate how the indicated neutrino mass and mixing observables can be determined from the measurement of the corresponding continuous photon spectrum taking the example of a transition between specific levels of the Yb atom. The possibility of determining the nature of massive neutrinos and, if neutrinos are Majorana fermions, of obtaining information about the Majorana phases in the neutrino mixing matrix, is analyzed in the cases of normal hierarchical, inverted hierarchical and quasi-degenerate types of neutrino mass spectrum. We find, in particular, that the sensitivity to the nature of massive neutrinos depends critically on the atomic level energy difference relevant in the RENP.

D. N. Dinh; S. T. Petcov; N. Sasao; M. Tanaka; M. Yoshimura

2012-09-21T23:59:59.000Z

110

Quantum Limits and Robustness of Nonlinear Intracavity Absorption Spectroscopy  

E-Print Network [OSTI]

We investigate the limits of intracavity absorption spectroscopy with nonlinear media. Using a common theoretical framework, we compare the detection of a trace gas within an undriven cavity with gain near and above threshold, a driven cavity with gain kept just below threshold, and a cavity driven close to the saturation point of a saturable absorber. These phase-transition-based metrology methods are typically quantum-limited by spontaneous emission, and we compare them to the empty cavity shotnoise-limited case. Although the fundamental limits achievable with nonlinear media do not surpass the empty cavity limits, we show that nonlinear methods are more robust against certain technical noise models. This recognition may have applications in spectrometer design for devices operating in non-ideal field environments.

John K. Stockton; Ari K. Tuchman

2008-10-23T23:59:59.000Z

111

E-Print Network 3.0 - atomic absorption spectrophotometric Sample...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrophotometric Page: << < 1 2 3 4 5 > >> 1 Building up a database of...

112

E-Print Network 3.0 - atomic-absorption flame photometry Sample...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic-absorption flame photometry Page: << < 1 2 3 4 5 > >> 1 MICROCHEMICALJOURNAL33,304-...

113

E-Print Network 3.0 - atomic-absorption spectrometry determinacion...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic-absorption spectrometry determinacion Page: << < 1 2 3 4 5 > >> 1...

114

E-Print Network 3.0 - atomic absorption spectrophotometry Sample...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrophotometry Page: << < 1 2 3 4 5 > >> 1 QUARTERLY PROGRESS REPORT...

115

E-Print Network 3.0 - atomic absorption spectroscopic Sample...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectroscopic Page: << < 1 2 3 4 5 > >> 1 BURCIN BAYRAM ASSOCIATE...

116

E-Print Network 3.0 - atomic absorption analysis Sample Search...  

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analysis Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption analysis Page: << < 1 2 3 4 5 > >> 1 JOURNAL DE PHYSIQUEIV Colloque...

117

E-Print Network 3.0 - atomic absorption spectrometry-determination...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometry-determination Page: << < 1 2 3 4 5 > >> 1 Extended Xray...

118

E-Print Network 3.0 - atomic absorption spectrophotometer Sample...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrophotometer Page: << < 1 2 3 4 5 > >> 1 ChemicalSample...

119

E-Print Network 3.0 - atomic absorption flame Sample Search Results  

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flame Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption flame Page: << < 1 2 3 4 5 > >> 1 Appendix 1: Experimental Studies...

120

E-Print Network 3.0 - atomic absorption spectrom- Sample Search...  

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Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrom- Page: << < 1 2 3 4 5 > >> 1 Mechanism for Increased Yield with...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

E-Print Network 3.0 - atomic absorption spectrometry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometry Page: << < 1 2 3 4 5 > >> 1 JOURNAL DE PHYSIQUEIV Colloque...

122

Subwavelength atom localization via amplitude and phase control of the absorption spectrum  

E-Print Network [OSTI]

We propose a scheme for subwavelength localization of an atom conditioned upon the absorption of a weak probe field at a particular frequency. Manipulating atom-field interaction on a certain transition by applying drive fields on nearby coupled...

Sahrai, M.; Tajalli, H.; Kapale, KT; Zubairy, M. Suhail.

2005-01-01T23:59:59.000Z

123

Etalon-induced Baseline Drift And Correction In Atom Flux Sensors...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based...

124

Broadband absorption spectroscopy in turbid media by combined frequency-domain and  

E-Print Network [OSTI]

Broadband absorption spectroscopy in turbid media by combined frequency-domain and steady. Tromberg A technique for measuring broadband near-infrared absorption spectra of turbid media that uses selected wavelengths. Coefficients of absorption a and reduced scattering s derived from the FD data

Berger, Andrew J.

125

ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING CONFIGURATIONS OF  

E-Print Network [OSTI]

ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING Rights Reserved #12;ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE

Sparks, Donald L.

126

Ionization and dissociation dynamics of vinyl bromide probed by femtosecond extreme ultraviolet transient absorption spectroscopy  

SciTech Connect (OSTI)

Strong-field induced ionization and dissociation dynamics of vinyl bromide, CH{sub 2}=CHBr, are probed using femtosecond extreme ultraviolet (XUV) transient absorption spectroscopy. Strong-field ionization is initiated with an intense femtosecond, near infrared (NIR, 775 nm) laser field. Femtosecond XUV pulses covering the photon energy range of 50-72 eV probe the subsequent dynamics by measuring the time-dependent spectroscopic features associated with transitions of the Br (3d) inner-shell electrons to vacancies in molecular and atomic valence orbitals. Spectral signatures are observed for the depletion of neutral C{sub 2}H{sub 3}Br, the formation of C{sub 2}H{sub 3}Br{sup +} ions in their ground (X{sup ~}) and first excited (A{sup ~}) states, the production of C{sub 2}H{sub 3}Br{sup ++} ions, and the appearance of neutral Br ({sup 2}P{sub 3/2}) atoms by dissociative ionization. The formation of free Br ({sup 2}P{sub 3/2}) atoms occurs on a timescale of 330 ± 150 fs. The ionic A{sup ~} state exhibits a time-dependent XUV absorption energy shift of ?0.4 eV within the time window of the atomic Br formation. The yield of Br atoms correlates with the yield of parent ions in the A{sup ~} state as a function of NIR peak intensity. The observations suggest that a fraction of vibrationally excited C{sub 2}H{sub 3}Br{sup +} (A{sup ~}) ions undergoes intramolecular vibrational energy redistribution followed by the C–Br bond dissociation. The C{sub 2}H{sub 3}Br{sup +} (X{sup ~}) products and the majority of the C{sub 2}H{sub 3}Br{sup ++} ions are relatively stable due to a deeper potential well and a high dissociation barrier, respectively. The results offer powerful new insights about orbital-specific electronic processes in high field ionization, coupled vibrational relaxation and dissociation dynamics, and the correlation of valence hole-state location and dissociation in polyatomic molecules, all probed simultaneously by ultrafast table-top XUV spectroscopy.

Lin, Ming-Fu; Neumark, Daniel M. [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States) [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Chemistry, University of California, Berkeley, California 94720 (United States); Gessner, Oliver [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)] [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Leone, Stephen R. [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States) [Ultrafast X-ray Science Laboratory, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Chemistry, University of California, Berkeley, California 94720 (United States); Department of Physics, University of California, Berkeley, California 94720 (United States)

2014-02-14T23:59:59.000Z

127

E-Print Network 3.0 - atomic emission spectroscopy Sample Search...  

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Spectroscopy of an Atomic Nucleus: The Thorium-229 Nuclear Clock Dr... spectroscopy of an atomic nucleus. Host: Mansoor Sheik-Bahae 12;... of 7.6 0.5 eV. This makes it...

128

Correlated single-crystal electronic absorption spectroscopy and X-ray crystallography at NSLS beamline X26-C  

SciTech Connect (OSTI)

The research philosophy and new capabilities installed at NSLS beamline X26-C to support electronic absorption and Raman spectroscopies coupled with X-ray diffraction are reviewed. This beamline is dedicated full time to multidisciplinary studies with goals that include revealing the relationship between the electronic and atomic structures in macromolecules. The beamline instrumentation has been fully integrated such that optical absorption spectra and X-ray diffraction images are interlaced. Therefore, optical changes induced by X-ray exposure can be correlated with X-ray diffraction data collection. The installation of Raman spectroscopy into the beamline is also briefly reviewed. Data are now routinely generated almost simultaneously from three complementary types of experiments from the same sample. The beamline is available now to the NSLS general user population.

Orville, A.M.; Buono, R.; Cowan, M.; Heroux, A.; Shea-McCarthy, G.; Schneider, D. K.; Skinner, J. M.; Skinner, M. J.; Stoner-Ma, D.; Sweet, R. M.

2011-05-01T23:59:59.000Z

129

Correlated Single-Crystal Electronic Absorption Spectroscopy and X-ray Crystallography at NSLS Beamline X26-C  

SciTech Connect (OSTI)

The research philosophy and new capabilities installed at NSLS beamline X26-C to support electronic absorption and Raman spectroscopies coupled with X-ray diffraction are reviewed. This beamline is dedicated full time to multidisciplinary studies with goals that include revealing the relationship between the electronic and atomic structures in macromolecules. The beamline instrumentation has been fully integrated such that optical absorption spectra and X-ray diffraction images are interlaced. Therefore, optical changes induced by X-ray exposure can be correlated with X-ray diffraction data collection. The installation of Raman spectroscopy into the beamline is also briefly reviewed. Data are now routinely generated almost simultaneously from three complementary types of experiments from the same sample. The beamline is available now to the NSLS general user population.

A Orville; R Buono; M Cowan; A Heroux; G Shea-McCarthy; D Schneider; J Skinner; M Skinner; D Stoner-Ma; R Sweet

2011-12-31T23:59:59.000Z

130

Spectroscopy of barium atoms in liquid and solid helium matrices  

SciTech Connect (OSTI)

We present an exhaustive overview of optical absorption and laser-induced fluorescence lines of Ba atoms in liquid and solid helium matrices in visible and near-infrared spectral ranges. Due to the increased density of isolated atoms, we have found a large number of spectral lines that were not observed in condensed helium matrices before. We have also measured the lifetimes of metastable states. The lowest {sup 3}D{sub 1} metastable state has lifetime of 2.6 s and can be used as an intermediate state in two-step excitations of high-lying states. Various matrix-induced radiationless population transfer channels have been identified.

Lebedev, V.; Moroshkin, P.; Weis, A. [Departement de Physique, Universite de Fribourg, Chemin du Musee 3, CH-1700 Fribourg (Switzerland)

2011-08-15T23:59:59.000Z

131

E-Print Network 3.0 - absorption spectroscopy identifies Sample...  

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absorptions were found ranging from... crystals of 1,3,5-trinitro-S-triazine (RDX) using terahertz time-domain spectroscopy V. H. Whitley & D. E... of the incident radiation....

132

Atomic absorption monitor for deposition process control of aluminum at 394 nm using frequency-doubled diode laser  

E-Print Network [OSTI]

Atomic absorption monitor for deposition process control of aluminum at 394 nm using frequency November 1995 A monitor for Al vapor density based on atomic absorption AA using a frequency of atomic absorption AA as a monitor for thickness and composition control in physical vapor deposi- tion

Fejer, Martin M.

133

Coherent Control of Single-Photon Absorption and Reemission in a Two-Level Atomic Ensemble Shanchao Zhang,1  

E-Print Network [OSTI]

Coherent Control of Single-Photon Absorption and Reemission in a Two-Level Atomic Ensemble Shanchao-photon absorption and reemission in a two-level cold atomic ensemble. This is achieved by interfering the incident-level atomic medium, the absorption and emission usually both occur within the photon pulse duration. Recently

Du, Shengwang

134

Calculation of the spatial resolution in two-photon absorption spectroscopy applied to plasma diagnosis  

SciTech Connect (OSTI)

We report a detailed characterization of the spatial resolution provided by two-photon absorption spectroscopy suited for plasma diagnosis via the 1S-2S transition of atomic hydrogen for optogalvanic detection and laser induced fluorescence (LIF). A precise knowledge of the spatial resolution is crucial for a correct interpretation of measurements, if the plasma parameters to be analysed undergo strong spatial variations. The present study is based on a novel approach which provides a reliable and realistic determination of the spatial resolution. Measured irradiance distribution of laser beam waists in the overlap volume, provided by a high resolution UV camera, are employed to resolve coupled rate equations accounting for two-photon excitation, fluorescence decay and ionization. The resulting three-dimensional yield distributions reveal in detail the spatial resolution for optogalvanic and LIF detection and related saturation due to depletion. Two-photon absorption profiles broader than the Fourier transform-limited laser bandwidth are also incorporated in the calculations. The approach allows an accurate analysis of the spatial resolution present in recent and future measurements.

Garcia-Lechuga, M. [Departamento de Física Teórica, Atómica y Óptica, Universidad de Valladolid, 47011-Valladolid (Spain); Laser Processing Group, Instituto de Óptica “Daza de Valdés,” CSIC, 28006-Madrid (Spain); Fuentes, L. M. [Departamento de Física Aplicada, Universidad de Valladolid, 47011-Valladolid (Spain); Grützmacher, K.; Pérez, C., E-mail: concha@opt.uva.es; Rosa, M. I. de la [Departamento de Física Teórica, Atómica y Óptica, Universidad de Valladolid, 47011-Valladolid (Spain)

2014-10-07T23:59:59.000Z

135

E-Print Network 3.0 - absorption spatial profiles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Rico, Mayaguez Collection: Geosciences 36 Atomic flux measurement by diode-laser-based atomic absorption spectroscopy Summary: the basic AA spectroscopic feature, i.e., the...

136

Measurement of Water Vapor Concentration using Tunable Diode Laser Absorption Spectroscopy  

E-Print Network [OSTI]

Tunable diode laser spectroscopy and the Beer-Lambert relation has been used to measure the absorption of water vapor both in an absorption cell and in a shock tube. The purpose of this thesis is to develop a laser diagnostic capable of determining...

Barrett, Alexander B.

2010-07-14T23:59:59.000Z

137

E-Print Network 3.0 - atomic absorption spectrometer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometer Page: << < 1 2 3 4 5 > >> 1 In the post-genome era, the...

138

E-Print Network 3.0 - atomic absorption lines Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

lines Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption lines Page: << < 1 2 3 4 5 > >> 1 An output coupler for Bose condensed...

139

E-Print Network 3.0 - atomic absorption faa Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

faa Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption faa Page: << < 1 2 3 4 5 > >> 1 Through-Space Charge Transfer and Nonlinear...

140

E-Print Network 3.0 - ablation mass spectroscopy Sample Search...  

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implants into rat livers after radiofrequency ablation were quantified by atomic absorption spectroscopy... Local carboplatin delivery and tissue distribution in...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Graphite Furnance Atomic Absorption as a detector for High Performance Liquid Chromatography  

E-Print Network [OSTI]

GRAPHITE FURNACE ATOMIC ABSORPTION AS A DETECTOR FOR HIGH PERFORMANCE LIQUID CHROMATOGRAPHy A Thesis by HUSTON EDWARD HOWELL, JR. Submitted to the Graduate College oi' Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1980 Major Subject: Chemistry GRAPHITE FURNACE ATOMIC ABSORPTION AS A DETECTOR FOR HIGH PERFORMANCE LIQUID CHROMATOGRAPHY A Thesis by HUSTON EDWARD HOWELL, JR. Approved as to style and content by: (Chairman...

Howell, Huston Edward

1980-01-01T23:59:59.000Z

142

E-Print Network 3.0 - absorption spectroscopy exafs Sample Search...  

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Colloque C9, supplement au n012, Tome 48, dkcembre 1987 Summary: -shaped model for the atomic absorption resulted in a large improvement in the EXAFS shape. In Fig. 2 we...

143

Direct and quantitative photothermal absorption spectroscopy of individual particulates  

SciTech Connect (OSTI)

Photonic structures can exhibit significant absorption enhancement when an object's length scale is comparable to or smaller than the wavelength of light. This property has enabled photonic structures to be an integral component in many applications such as solar cells, light emitting diodes, and photothermal therapy. To characterize this enhancement at the single particulate level, conventional methods have consisted of indirect or qualitative approaches which are often limited to certain sample types. To overcome these limitations, we used a bilayer cantilever to directly and quantitatively measure the spectral absorption efficiency of a single silicon microwire in the visible wavelength range. We demonstrate an absorption enhancement on a per unit volume basis compared to a thin film, which shows good agreement with Mie theory calculations. This approach offers a quantitative approach for broadband absorption measurements on a wide range of photonic structures of different geometric and material compositions.

Tong, Jonathan K.; Hsu, Wei-Chun; Eon Han, Sang; Burg, Brian R.; Chen, Gang, E-mail: gchen2@mit.edu [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Zheng, Ruiting [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China)] [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Shen, Sheng [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)] [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)

2013-12-23T23:59:59.000Z

144

X-ray Absorption and Emission Spectroscopy Study of the Effect of Doping on the Low Energy Electronic Structure of PrFeAsO1-[delta  

E-Print Network [OSTI]

X-ray Absorption and Emission Spectroscopy Study of theusing soft X-ray absorption and emission spectroscopy. The2. (a) Oxygen 1s x-ray absorption spectra of PrFeAsO 1-? (?

Freelon, Byron

2010-01-01T23:59:59.000Z

145

Local versus global electronic properties of chalcopyrite alloys: X-ray absorption spectroscopy and ab initio calculations  

SciTech Connect (OSTI)

Element-specific unoccupied electronic states of Cu(In, Ga)S{sub 2} were studied as a function of the In/Ga ratio by combining X-ray absorption spectroscopy with density functional theory calculations. The S absorption edge shifts with changing In/Ga ratio as expected from the variation of the band gap. In contrast, the cation edge positions are largely independent of composition despite the changing band gap. This unexpected behavior is well reproduced by our calculations and originates from the dependence of the electronic states on the local atomic environment. The changing band gap arises from a changing spatial average of these localized states with changing alloy composition.

Sarmiento-Pérez, Rafael; Botti, Silvana, E-mail: silvana.botti@univ-lyon1.fr [Institut Lumière Matière and ETSF, UMR5306 Université Lyon 1-CNRS, Université de Lyon, F-69622 Villeurbanne Cedex (France); Schnohr, Claudia S., E-mail: c.schnohr@uni-jena.de [Institut für Festkörperphysik, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Lauermann, Iver [Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner Platz 1, 14109 Berlin (Germany); Rubio, Angel [Nano-Bio Spectroscopy Group and ETSF Scientific Development Centre, Departamento de Física de Materiales, Centro de Física de Materiales CSIC-MPC and DIPC, Universidad del País Vasco UPV/EHU, Avenida de Tolosa 72, E-20018 San Sebastián (Spain); Fritz Haber Institute, Max Planck Society, Faradayweg 4-6, 14195 Berlin (Germany); Johnson, Benjamin, E-mail: benjamin.johnson@alumni.tu-berlin.de [Fritz Haber Institute, Max Planck Society, Faradayweg 4-6, 14195 Berlin (Germany)

2014-09-07T23:59:59.000Z

146

Method and apparatus for aerosol particle absorption spectroscopy  

DOE Patents [OSTI]

A method and apparatus for determining the absorption spectra, and other properties, of aerosol particles. A heating beam source provides a beam of electromagnetic energy which is scanned through the region of the spectrum which is of interest. Particles exposed to the heating beam which have absorption bands within the band width of the heating beam absorb energy from the beam. The particles are also illuminated by light of a wave length such that the light is scattered by the particles. The absorption spectra of the particles can thus be determined from an analysis of the scattered light since the absorption of energy by the particles will affect the way the light is scattered. Preferably the heating beam is modulated to simplify the analysis of the scattered light. In one embodiment the heating beam is intensity modulated so that the scattered light will also be intensity modulated when the particles absorb energy. In another embodiment the heating beam passes through an interferometer and the scattered light reflects the Fourier Transform of the absorption spectra.

Campillo, Anthony J. (Nesconset, NY); Lin, Horn-Bond (Manorville, NY)

1983-11-15T23:59:59.000Z

147

E-Print Network 3.0 - atomic ions Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... ion will form a...

148

E-Print Network 3.0 - atoms ions electrons Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... ion will form a...

149

E-Print Network 3.0 - atomic negative ions Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Name Summary: of an unknown metal ion in a biomolecule Atomic absorption spectroscopy or ICP spectroscopy (b) the presence... ion will form a...

150

Three-photon-absorption resonance for all-optical atomic clocks Sergei Zibrov,1,2,3,4  

E-Print Network [OSTI]

Three-photon-absorption resonance for all-optical atomic clocks Sergei Zibrov,1,2,3,4 Irina, driving atoms coherently from state c to b , fol- lowed by a one-photon absorption from field P, which January 2005; published 7 July 2005 We report an experimental study of an all-optical three-photon-absorption

Walsworth, Ronald L.

151

Use of X-ray Absorption Spectroscopy to Distinguish Between Inner And Outer-sphere Pb Adsorption Complexes on Montmorillonite  

E-Print Network [OSTI]

Use of X-ray Absorption Spectroscopy to Distinguish Between Inner And Outer-sphere Pb Adsorption on the functional groups at the edges of the montmorillonite. At I = 0.002 M Pb absorption was less dependent

Sparks, Donald L.

152

Two-photon absorption and emission by Rydberg atoms in coupled cavities  

E-Print Network [OSTI]

We study the dynamics of a system composed of two coupled cavities, each containing a single Rydberg atom. The interplay between Rydberg-Rydberg interaction and photon hopping enables the transition of the atoms from the collective ground state to the double Rydberg excitation state by individually interacting with the hybrid cavity modes and suppressing the up conversion process between them. The atomic transition is accompanied by the two-photon absorption and emission of the hybrid modes. Since the energy level structure of the atom-cavity system is photon number dependent, there is only a pair of states being in the two-photon resonance. Therefore, the system can act as a quantum nonlinear absorption filter through the nonclassical quantum process, converting coherent light field into a non-classical state. Meanwhile, the vacuum field in the cavity inspires the Rydberg atoms to simultaneously emit two photons into the hybrid mode, resulting in obvious emission enhancement of the mode.

Huaizhi Wu; Zhen-Biao Yang; Shi-Biao Zheng

2013-10-10T23:59:59.000Z

153

E-Print Network 3.0 - atom re-evaporation method Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

method Page: << < 1 2 3 4 5 > >> 1 Atomic flux measurement by diode-laser-based atomic absorption spectroscopy Summary: in the absorp- tion profile indicates that barium...

154

Kaon Absorption from Kaonic Atoms and Formation Spectra of Kaonic Nuclei  

E-Print Network [OSTI]

We considered the kaon absorption from atomic states into nucleus. We found that the nuclear density probed by the atomic kaon significantly depends on the kaon orbit. Then, we reexamined the meanings of the observed strengths of one-body and two-body kaon absorption, and investigated the effects to the formation spectra of kaon bound states by in-flight ($K^-,p$) reactions. As a natural consequence, if the atomic kaon probes the smaller nuclear density, the ratio of the two-body absorption at nuclear center is larger than the observed value, and the depth of the imaginary potential is deeper even at smaller kaon energies as in kaonic nuclear states because of the large phase space for the two-body processes.

Junko Yamagata; Satoru Hirenzaki

2006-12-09T23:59:59.000Z

155

Absolute atomic oxygen and nitrogen densities in radio-frequency driven atmospheric pressure cold plasmas: Synchrotron vacuum ultra-violet high-resolution Fourier-transform absorption measurements  

SciTech Connect (OSTI)

Reactive atomic species play a key role in emerging cold atmospheric pressure plasma applications, in particular, in plasma medicine. Absolute densities of atomic oxygen and atomic nitrogen were measured in a radio-frequency driven non-equilibrium plasma operated at atmospheric pressure using vacuum ultra-violet (VUV) absorption spectroscopy. The experiment was conducted on the DESIRS synchrotron beamline using a unique VUV Fourier-transform spectrometer. Measurements were carried out in plasmas operated in helium with air-like N{sub 2}/O{sub 2} (4:1) admixtures. A maximum in the O-atom concentration of (9.1 {+-} 0.7) Multiplication-Sign 10{sup 20} m{sup -3} was found at admixtures of 0.35 vol. %, while the N-atom concentration exhibits a maximum of (5.7 {+-} 0.4) Multiplication-Sign 10{sup 19} m{sup -3} at 0.1 vol. %.

Niemi, K.; O'Connell, D.; Gans, T. [York Plasma Institute, Department of Physics, University of York, York YO10 5DD (United Kingdom); Oliveira, N. de; Joyeux, D.; Nahon, L. [Synchrotron Soleil, l'Orme des Merisiers, St. Aubin BP 48, 91192 Gif sur Yvette Cedex (France); Booth, J. P. [Laboratoire de Physique des Plasmas-CNRS, Ecole Polytechnique, 91128 Palaiseau (France)

2013-07-15T23:59:59.000Z

156

Subwavelength atom localization via amplitude and phase control of the absorption spectrum  

E-Print Network [OSTI]

We propose a scheme for subwavelength localization of an atom conditioned upon the absorption of a weak probe field at a particular frequency. Manipulating atom-field interaction on a certain transition by applying drive fields on nearby coupled transitions leads to interesting effects in the absorption spectrum of the weak probe field. We exploit this fact and employ a four-level system with three driving fields and a weak probe field, where one of the drive fields is a standing-wave field of a cavity. We show that the position of an atom along this standing wave is determined when probe field absorption is measured. We find that absorption of the weak probe field at a certain frequency leads to subwavelength localization of the atom in either of the two half-wavelength regions of the cavity field by appropriate choice of the system parameters. We term this result as sub-half-wavelength localization to contrast it with the usual atom localization result of four peaks spread over one wavelength of the standing wave. We observe two localization peaks in either of the two half-wavelength regions along the cavity axis.

Mostafa Sahrai; Habib Tajalli; Kishore T. Kapale; M. Suhail Zubairy

2005-07-21T23:59:59.000Z

157

Vibrational spectra of N2: An advanced undergraduate laboratory in atomic and molecular spectroscopy  

E-Print Network [OSTI]

an advanced laboratory course focused on spectroscopy of atoms and molecules, for a diverse and solid#12;Vibrational spectra of N2: An advanced undergraduate laboratory in atomic and molecular to demonstrate molecular spectroscopy by measuring the vibrational energy spacing of nitrogen molecules

Bayram, S. Burçin

158

A Neutral Atom and a Charged Wire: From Elastic scattering to Absorption  

E-Print Network [OSTI]

We solve the problem of a neutral atom interacting with a charged wire, giving rise to an attractive 1/r^2 potential in two dimensions. We show how a suitable average over all possible self-adjoint extensions of the radial Schroedinger Hamiltonian eventually leads to the classical formula for absorption of the atom, a formula shown to be in agreement with a recent experiment.

M. Bawin; S. A. Coon

2000-12-08T23:59:59.000Z

159

X-ray absorption spectroscopy of biomimetic dye molecules for solar cells Peter L. Cook,1  

E-Print Network [OSTI]

X-ray absorption spectroscopy of biomimetic dye molecules for solar cells Peter L. Cook,1 Xiaosong November 2009 Dye-sensitized solar cells are potentially inexpensive alternatives to traditional semiconductor solar cells. In order to optimize dyes for solar cells we systematically investigate

Himpsel, Franz J.

160

absorption near-edge spectroscopy: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption near-edge spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

absorption fine-structure spectroscopy: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption fine-structure spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of...

162

Negative refraction with tunable absorption in an active dense gas of atoms  

E-Print Network [OSTI]

Applications of negative index materials (NIM) presently are severely limited by absorption. Next to improvements of metamaterial designs, it has been suggested that dense gases of atoms could form a NIM with negligible losses. In such gases, the low absorption is facilitated by quantum interference. Here, we show that additional gain mechanisms can be used to tune and effectively remove absorption in a dense gas NIM. In our setup, the atoms are coherently prepared by control laser fields, and further driven by a weak incoherent pump field to induce gain. We employ nonlinear optical Bloch equations to analyze the optical response. Metastable Neon is identified as a suitable experimental candidate at infrared frequencies to implement a lossless active negative index material.

P. P. Orth; R. Hennig; C. H. Keitel; J. Evers

2012-10-17T23:59:59.000Z

163

X-ray absorption spectroscopy of the cubic and hexagonal polytypes of zinc sulfide B. Gilbert,1,  

E-Print Network [OSTI]

X-ray absorption spectroscopy of the cubic and hexagonal polytypes of zinc sulfide B. Gilbert,1 Received 18 June 2002; published 26 December 2002 We investigate the sensitivity of x-ray absorption. Experimental spectra and multiple-scattering calculations are reported at the major absorption edges

Haskel, Daniel

164

Entangling two atoms in spatially separated cavities through both photon emission and absorption processes  

E-Print Network [OSTI]

We consider a system consisting of a $\\Lambda$-type atom and a V-type atom, which are individually trapped in two spatially separated cavities that are connected by an optical fibre. We show that an extremely entangled state of the two atoms can be deterministically generated through both photon emission of the $\\Lambda$-type atom and photon absorption of the V-type atom in an ideal situation. The influence of various decoherence processes such as spontaneous emission and photon loss on the fidelity of the entangled state is also investigated. We find that the effect of photon leakage out of the fibre on the fidelity can be greatly diminished in some special cases. As regards the effect of spontaneous emission and photon loss from the cavities, we find that the present scheme with a fidelity higher than 0.98 may be realized under current experiment conditions.

Peng Peng; Fu-li Li

2006-12-29T23:59:59.000Z

165

Photocarrier dynamics in anatase TiO{sub 2} investigated by pump-probe absorption spectroscopy  

SciTech Connect (OSTI)

The dynamics of photogenerated electrons and holes in undoped anatase TiO{sub 2} were studied by femtosecond absorption spectroscopy from the visible to mid-infrared region (0.1–2.0?eV). The transient absorption spectra exhibited clear metallic responses, which were well reproduced by a simple Drude model. No mid-gap absorptions originating from photocarrier localization were observed. The reduced optical mass of the photocarriers obtained from the Drude-model analysis is comparable to theoretically expected one. These results demonstrate that both photogenerated holes and electrons act as mobile carriers in anatase TiO{sub 2}. We also discuss scattering and recombination dynamics of photogenerated electrons and holes on the basis of the time dependence of absorption changes.

Matsuzaki, H., E-mail: hiroyuki-matsuzaki@aist.go.jp, E-mail: okamotoh@k.u-tokyo.ac.jp; Matsui, Y.; Uchida, R.; Yada, H.; Terashige, T. [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Li, B.-S. [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology (HIT), Harbin City 150080 (China); Sawa, A. [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8562 (Japan); Kawasaki, M. [Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Tokura, Y. [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8562 (Japan); Department of Applied Physics and Quantum Phase Electronics Center (QPEC), University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Okamoto, H., E-mail: hiroyuki-matsuzaki@aist.go.jp, E-mail: okamotoh@k.u-tokyo.ac.jp [Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); CREST, Japan Science and Technology Agency, Chiyoda-ku, Tokyo 102-0075 (Japan)

2014-02-07T23:59:59.000Z

166

Condensed phase spectroscopy from mixed-order semiclassical molecular dynamics: Absorption, emission, and resonant Raman spectra of I2  

E-Print Network [OSTI]

Condensed phase spectroscopy from mixed-order semiclassical molecular dynamics: Absorption, as a prototype of spectroscopy in condensed media in general. The method relies on constructing quantum correlations into system and bath are used to provide perspectives about condensed phase spectroscopy

Apkarian, V. Ara

167

ABSORPTION PHOTOLECTRIQUE DES RAYONS 03B3 DANS LA COUCHE L DES ATOMES Par Mme NADINE MARTY.  

E-Print Network [OSTI]

401. ABSORPTION PHOTO�LECTRIQUE DES RAYONS 03B3 DANS LA COUCHE L DES ATOMES Par Mme NADINE MARTY la suite, comme la section efficace totale d'absorption photoélectrique par atome. Les résultats de. Laboratoire dé Chimie nucléaire, Collège de France. Sommaire. - On rappelle la valeur des sections efficaces d'absorption

Boyer, Edmond

168

Ultra-sensitive surface absorption spectroscopy using sub-wavelength diameter optical fibers  

E-Print Network [OSTI]

The guided modes of sub-wavelength diameter air-clad optical fibers exhibit a pronounced evanescent field. The absorption of particles on the fiber surface is therefore readily detected via the fiber transmission. We show that the resulting absorption for a given surface coverage can be orders of magnitude higher than for conventional surface spectroscopy. As a demonstration, we present measurements on sub-monolayers of 3,4,9,10-perylene-tetracarboxylic dianhydride (PTCDA) molecules at ambient conditions, revealing the agglomeration dynamics on a second to minutes timescale.

F. Warken; E. Vetsch; D. Meschede; M. Sokolowski; A. Rauschenbeutel

2007-06-22T23:59:59.000Z

169

Electrochemical flowcell for in-situ investigations by soft x-ray absorption and emission spectroscopy  

SciTech Connect (OSTI)

A new liquid flow-cell designed for electronic structure investigations at the liquid-solid interface by soft X-ray absorption and emission spectroscopy is presented. A thin membrane serves simultaneously as a substrate for the working electrode and solid state samples as well as for separating the liquid from the surrounding vacuum conditions. In combination with counter and reference electrodes this approach allows in-situ studies of electrochemical deposition processes and catalytic reactions at the liquid-solid interface in combination with potentiostatic measurements. As model system in-situ monitoring of the deposition process of Co metal from a 10 mM CoCl{sub 2} aqueous solution by X-ray absorption and emission spectroscopy is presented.

Schwanke, C.; Lange, K. M., E-mail: Kathrin.lange@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Solar Fuels, Albert-Einstein-Straße 15, 12489 Berlin (Germany); Golnak, R.; Xiao, J. [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Methods for Material Development, Albert-Einstein-Straße 15, 12489 Berlin (Germany)

2014-10-15T23:59:59.000Z

170

A method for measuring the rate of reaction by molecular microwave absorption spectroscopy  

E-Print Network [OSTI]

A METHOD FOR MEASURING THE RATE OF REACTION BT MOLECULAR MICROWAVE ABSORPTION SPECTROSCOPY A Dissertation 9$r Allan Neil Brown Approved as to style and content by: Head of the Departme Chairman of Committee June AM ET LIBRARY A A M COLLEGE... Amplifier ............. ET Figure 8. The Oscilloscope . . . . . . . . . . . . . . . . . 1H Figure 9. The Voltage Integrator.......................... 17 Figure 10. Diagram of Voltage Inte g r a t o r................... 18 Figure 11. The Recording Unit...

Brown, Allan Neil

1954-01-01T23:59:59.000Z

171

Comment on ``Resonance-fluorescence and absorption spectra of a two-level atom driven by a strong bichromatic field''  

E-Print Network [OSTI]

Comment on ``Resonance-fluorescence and absorption spectra of a two-level atom driven by a strong predictions of the resonance fluorescence from a two-level atom driven by a strong bichromatic field J. Opt.50.Hz, 33.50.Dq, 32.80. t In studying the resonance fluorescence from a driven two- level atom, we

Boyd, Robert W.

172

Symposium on atomic spectroscopy (SAS-83): abstracts and program  

SciTech Connect (OSTI)

Abstracts of papers given at the symposium are presented. Session topics include: Rydbergs, optical radiators, and planetary atoms; highly ionized atoms; ultraviolet radiation; theory, ion traps, and laser cooling; beam foil; and astronomy. (GHT)

Not Available

1983-09-01T23:59:59.000Z

173

Nuclear-Motion Effects in Attosecond Transient Absorption Spectroscopy of Molecules  

E-Print Network [OSTI]

We investigate the characteristic effects of nuclear motion on attosecond transient absorption spectra in molecules by calculating the spectrum for different model systems. Two models of the hydrogen molecular ion are considered: one where the internuclear separation is fixed, and one where the nuclei are free to vibrate. The spectra for the fixed nuclei model are similar to atomic spectra reported elsewhere, while the spectra obtained in the model including nuclear motion are very different and dominated by extremely broad absorption features. These broad absorption features are analyzed and their relation to molecular dissociation investigated. The study of the hydrogen molecular ion validates an approach based on the Born-Oppenheimer approximation and a finite electronic basis. This latter approach is then used to study the three-dimensional hydrogen molecule including nuclear vibration. The spectrum obtained from H$_2$ is compared to the result of a fixed-nuclei calculation. In the attosecond transient ab...

Bækhøj, Jens E; Madsen, Lars Bojer

2015-01-01T23:59:59.000Z

174

Projections of local atomic structure revealed by wavelet analysis of x-ray absorption anisotropy P. Korecki,1,* D. V. Novikov,2 and M. Tolkiehn2  

E-Print Network [OSTI]

Projections of local atomic structure revealed by wavelet analysis of x-ray absorption anisotropy P x-ray field amplitude at the sites of absorbing atoms and effectively changes the atomic absorption in an experiment a wavelet transform approach for analysis of x-ray absorption anisotropy XAA patterns recorded

Korecki, Pawe³

175

A split imaging spectrometer for temporally and spatially resolved titanium absorption spectroscopy  

SciTech Connect (OSTI)

We present a temporally and a spatially resolved spectrometer for titanium x-ray absorption spectroscopy along 2 axial symmetric lines-of-sight. Each line-of-sight of the instrument uses an elliptical crystal to acquire both the 2p and 3p Ti absorption lines on a single, time gated channel of the instrument. The 2 axial symmetric lines-of-sight allow the 2p and 3p absorption features to be measured through the same point in space using both channels of the instrument. The spatially dependent material temperature can be inferred by observing the 2p and the 3p Ti absorption features. The data are recorded on a two strip framing camera with each strip collecting data from a single line-of-sight. The design is compatible for use at both the OMEGA laser and the National Ignition Facility. The spectrometer is intended to measure the material temperature behind a Marshak wave in a radiatively driven SiO{sub 2} foam with a Ti foam tracer. In this configuration, a broad band CsI backlighter will be used for a source and the Ti absorption spectrum measured.

Hager, J. D., E-mail: hager@lanl.gov; Lanier, N. E.; Kline, J. L.; Flippo, K. A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Bruns, H. C.; Schneider, M.; Saculla, M.; McCarville, T. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

2014-11-15T23:59:59.000Z

176

E-Print Network 3.0 - absorption spectrometric detection Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is achieved using two... microbalance QCM , multichannel spectro- scopic ellipsometry,2,3 atomic absorption spectroscopy AAS , electron Source: Rubloff, Gary W. - Institute for...

177

Ligand-field symmetry effects in Fe(II) polypyridyl compounds probed by transient X-ray absorption spectroscopy  

SciTech Connect (OSTI)

Ultrafast excited-state evolution in polypyridyl FeII complexes are of fundamental interest for understanding the origins of the sub-ps spin-state changes that occur upon photoexcitation of this class of compounds as well as for the potential impact such ultrafast dynamics have on incorporation of these compounds in solar energy conversion schemes or switchable optical storage technologies. We have demonstrated that ground-state and, more importantly, ultrafast time-resolved x-ray absorption methods can offer unique insights into the interplay between electronic and geometric structure that underpin the photo-induced dynamics of this class of compounds. The present contribution examines in greater detail how the symmetry of the ligand field surrounding the metal ion can be probed using these x-ray techniques. In particular, we show that steady-state K-edge spectroscopy of the nearest-neighbour nitrogen atoms reveals the characteristic chemical environment of the respective ligands and suggests an interesting target for future charge-transfer femtosecond and attosecond spectroscopy in the x-ray water window.

Cho, Hana; Strader, Matthew L.; Hong, Kiryong; Jamula, Lindsey; Kim, Tae Kyu; Groot, Frank M. F. de; McCusker, James K.; Schoenlein, Robert W.; Huse, Nils

2012-02-28T23:59:59.000Z

178

Self-corrected Sensors Based On Atomic Absorption Spectroscopy For Atom  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) SrEvaluating the SeasonalswFlux Measurements In Molecular

179

Absolute CF{sub 2} density and gas temperature measurements by absorption spectroscopy in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas  

SciTech Connect (OSTI)

Broadband ultraviolet absorption spectroscopy has been used to determine the CF{sub 2} radical density in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas, using the CF{sub 2} A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system of absorption spectrum. The rotational temperature of ground state CF{sub 2} and excited state CF was also estimated by using A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system and B{sup 2}??X{sup 2}? system, respectively. The translational gas temperature was deduced from the Doppler width of the Ar{sup *}({sup 3}P{sub 2}) and Ar{sup *}({sup 3}P{sub 0}) metastable atoms absorption line by using the tunable diode laser absorption spectroscopy. The rotational temperatures of the excited state CF are about 100?K higher than those of ground state CF{sub 2}, and about 200?K higher than the translational gas temperatures. The dependences of the radical CF{sub 2} density, electron density, electron temperature, rotational temperature, and gas temperature on the high frequency power and pressure have been analyzed. Furthermore, the production and loss mechanisms of CF{sub 2} radical and the gas heating mechanisms have also been discussed.

Liu, Wen-Yao; Xu, Yong, E-mail: yongxu@dlut.edu.cn; Peng, Fei; Gong, Fa-Ping; Li, Xiao-Song; Zhu, Ai-Min [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China); Liu, Yong-Xin; Wang, You-Nian [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

2014-10-15T23:59:59.000Z

180

The determination of some anions using ion chromatography and ion chromatography-graphite furnace atomic absorption spectrometry  

E-Print Network [OSTI]

THE DETERMINATION OF SOME ANIONS USING ION CHROMATOGRAPHY AND ION CHROMATOGRAPHY-GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY A Thesis by DANIEL C. J. HILLMAN Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1981 Major Subject: Chemistry THE DETERMINATION OF SOME ANIONS USING ION CHROMATOGRAPHY AND ION CHROMATOGRAPHY-GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY A Thesis by DANIEL C. J. HILLMAN...

Hillman, Daniel C

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

SpectroWeb: Oscillator Strength Measurements of Atomic Absorption Lines in the Sun and Procyon  

E-Print Network [OSTI]

We update the online SpectroWeb database of spectral standard reference stars with 1178 oscillator strength values of atomic absorption lines observed in the optical spectrum of the Sun and Procyon (Alpha CMi A). The updated line oscillator strengths are measured with best fits to the disk-integrated KPNO-FTS spectrum of the Sun observed between 4000 A and 6800 A using state-of-the-art detailed spectral synthesis calculations. A subset of 660 line oscillator strengths is validated with synthetic spectrum calculations of Procyon observed with ESO-UVES between 4700 A and 6800 A. The new log(gf)-values in SpectroWeb are improved over the values offered in the online Vienna Atomic Line Database (VALD). We find for neutral iron-group elements, such as Fe I, Ni I, Cr I, and Ti I, a statistically significant over-estimation of the VALD log(gf)-values for weak absorption lines with normalized central line depths below 15 %. For abundant lighter elements (e.g. Mg I and Ca I) this trend is statistically not significantly detectable, with the exception of Si I for which the log(gf)-values of 60 weak and medium-strong lines are substantially decreased to best fit the observed spectra. The newly measured log(gf)-values are available in the SpectroWeb database at http://spectra.freeshell.org which interactively displays the observed and computed stellar spectra, together with corresponding atomic line data.

A. Lobel

2007-12-07T23:59:59.000Z

182

Effect of Atomic Coherence on Absorption in Four-level Systems: an Analytical study  

E-Print Network [OSTI]

Absorption profile of a four-level ladder atomic system interacting with three driving fields is studied perturbatively and analytical results are presented. Numerical results where the driving field strengths are treated upto all orders are presented. The absorption features is studied in two regimes, i) the weak middle transition coupling, i.e. $\\Omega_2 >\\Omega_{1,3}$. In case i), it is shown that the ground state absorption and the saturation characteristics of the population of level 2 reveal deviation due to the presence of upper level couplings. In particular, the saturation curve for the population of level 2 shows a dip for $\\Omega_1 = \\Omega_3$. While the populations of levels 3 and 4 show a maxima when this resonance condition is satisfied. Thus the resonance condition provides a criterion for maximally populating the upper levels. A second order perturbation calculation reveals the nature of this minima (maxima). In the second case, I report two important features: a) Filtering of the Aulter-Townes doublet in the three-peak absorption profile of the ground state, which is achieved by detuning only the upper most coupling field, and b) control of line-width by controlling the strength of the upper coupling fields. This filtering technique coupled with the control of linewidth could prove to be very useful for high resolution studies.

S N Sandhya

2006-10-09T23:59:59.000Z

183

X-ray absorption spectroscopy studies of electrochemically deposited thin oxide films.  

SciTech Connect (OSTI)

We have utilized ''in situ'' X-ray Absorption Fine Structure Spectroscopy to investigate the structure and composition of thin oxide films of nickel and iron that have been prepared by electrodeposition on a graphite substrate from aqueous solutions. The films are generally disordered. Structural information has been obtained from the analysis of the data. We also present initial findings on the local structure of heavy metal ions, e.g. Sr and Ce, incorporated into the electrodeposited nickel oxide films. Our results are of importance in a number of technological applications, among them, batteries, fuel cells, electrochromic and ferroelectric materials, corrosion protection, as well as environmental speciation and remediation.

Balasubramanian, M.

1998-06-02T23:59:59.000Z

184

GEOC Thursday, March 25, 2010 192 -In situ characterization of environmental redox reactions using quick-scanning X-ray absorption spectroscopy  

E-Print Network [OSTI]

quick-scanning X-ray absorption spectroscopy (Q-XAS) Donald L Sparks, Dr. Matthew Ginder-Vogel, Dr. In this presentation, we will describe the use of quick X-ray absorption spectroscopy (Q-XAS), at a subsecond time by calculated rate constants that do not change with concentration. In addition to using X-ray absorption near

Sparks, Donald L.

185

Theory of attosecond transient absorption spectroscopy of strong-field-generated ions  

SciTech Connect (OSTI)

Strong-field ionization generally produces ions in a superposition of ionic eigenstates. This superposition is generally not fully coherent and must be described in terms of a density matrix. A recent experiment [E. Goulielmakis et al., Nature (London) 466, 739 (2010)] employed attosecond transient absorption spectroscopy to determine the density matrix of strong-field-generated Kr{sup +} ions. The experimentally observed degree of coherence of the strong-field-generated Kr{sup +} ions is well reproduced by a recently developed multichannel strong-field-ionization theory, but there is significant disagreement between experiment and theory with respect to the degree of alignment of the Kr{sup +} ions. In the present paper, the theory underlying attosecond transient absorption spectroscopy of strong-field-generated ions is developed. The theory is formulated in such a way that the nonperturbative nature of the strong-field-ionization process is systematically taken into account. The impact of attosecond pulse propagation effects on the interpretation of experimental data is investigated both analytically and numerically. It is shown that attosecond pulse propagation effects cannot explain why the experimentally determined degree of alignment of strong-field-generated Kr{sup +} ions is much smaller than predicted by existing theory.

Santra, Robin [Center for Free-Electron Laser Science, DESY, Notkestrasse 85, D-22607 Hamburg (Germany); Department of Physics, University of Hamburg, Jungiusstrasse 9, D-20355 Hamburg (Germany); Kavli Institute for Theoretical Physics, University of California, Santa Barbara, California 93106 (United States); Yakovlev, Vladislav S. [Department fuer Physik, Ludwig-Maximilians-Universitaet, Am Coulombwall 1, D-85748 Garching (Germany); Max-Planck-Institut fuer Quantenoptik, Hans-Kopfermann-Strasse 1, D-85748 Garching (Germany); Pfeifer, Thomas [Max Planck Institute for Nuclear Physics, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Loh, Zhi-Heng [Departments of Chemistry and Physics, University of California, Berkeley, California 94720 (United States); Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2011-03-15T23:59:59.000Z

186

Investigation of polarization spectroscopy for detecting atomic hydrogen in flames  

E-Print Network [OSTI]

. The probe beam was tuned to the single-photon 486-nm n = 2 --> n = 4 resonance of the hydrogen atom by fundamental and frequency-doubled beams from a single 486-nm dye laser were used. The probe beam was linearly polarized entering the flame...

Kulatilaka, Waruna Dasal

2002-01-01T23:59:59.000Z

187

Resonant Absorption between Moving Atoms due to Doppler Frequency Shift and Quantum Energy Variation  

E-Print Network [OSTI]

By taking both the Doppler frequency shift for electromagnetic wave and the quantum energy variation of matter wave into consideration, a resonant-absorption condition based on the local-ether wave equation is presented to account for a variety of phenomena consistently, including the Ives-Stilwell experiment, the output frequency from ammonia masers, and the M\\"{o}ssbauer rotor experiment. It is found that in the resonant-absorption condition, the major term associated with the laboratory velocity is a dot-product term between this velocity and that of the emitting or absorbing atom. This term appears both in the Doppler frequency shift and the transition frequency variation and then cancels out. Thereby, the experimental results can be independent of the laboratory velocity and hence comply with Galilean relativity, despite the restriction that the involved velocities are referred specifically to the local-ether frame. However, by examining the resonant-absorption condition in the M\\"{o}ssbauer rotor experiment to a higher order, it is found that Galilean relativity breaks down.

Ching-Chuan Su

2002-08-23T23:59:59.000Z

188

Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions at the Soil/Water Interface  

E-Print Network [OSTI]

Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions on the surface coordination environment of Ni sorbed onto clays and aluminum oxides using X-ray absorption fine

Sparks, Donald L.

189

E-Print Network 3.0 - atoms prevent degradation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Grafts Summary: control exhibited the most intense phosphate peaks. Strength Degradation Atomic Absorption Spectroscopy... @gmail.com Objective: To develop a ceramic material with...

190

E-Print Network 3.0 - argon plasma atomic Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

importance. A recent study of kineticsand decayprocesses in argon has shown that the 4s atomic... of an argon plasma by transient visible absorption spectroscopy from...

191

Spectroscopy of Mn atoms isolated in solid {sup 4}He  

SciTech Connect (OSTI)

We present an experimental study of the laser-induced luminescence spectra of Mn atoms in solid helium matrices. We observe transitions of the valence electron and of inner-shell electrons. We find that the Mn-He interaction perturbs the inner-shell transitions to a lesser extent than the valence-electron transitions. The observed lineshapes of the inner-shell transitions of Mn are similar to those of an inner-shell transition in Ba studied earlier. At the same time, they are more strongly perturbed than the corresponding transitions in Au and Cu under the same conditions. We suggest a qualitative explanation of these observations based on the atomic bubble model. Our results also suggest that the inner-shell transitions of Mn in solid He are more strongly perturbed than the same lines of Mn isolated in solid Ar or Kr matrices.

Moroshkin, P., E-mail: petr.moroshkin@riken.jp; Lebedev, V.; Weis, A. [Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg (Switzerland)

2014-06-07T23:59:59.000Z

192

Spectroscopy and Diffraction | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Techniques Electron spectroscopy Electron backscatter diffraction Atom probe tomography Ionmolecular beam spectroscopy 57Fe-Mssbauer spectroscopy Optical spectroscopy...

193

An atomic hydrogen beam to test ASACUSA's apparatus for antihydrogen spectroscopy  

E-Print Network [OSTI]

The ASACUSA collaboration aims to measure the ground state hyperfine splitting (GS-HFS) of antihydrogen, the antimatter pendant to atomic hydrogen. Comparisons of the corresponding transitions in those two systems will provide sensitive tests of the CPT symmetry, the combination of the three discrete symmetries charge conjugation, parity, and time reversal. For offline tests of the GS-HFS spectroscopy apparatus we constructed a source of cold polarised atomic hydrogen. In these proceedings we report the successful observation of the hyperfine structure transitions of atomic hydrogen with our apparatus in the earth's magnetic field.

Diermaier, Martin; Kolbinger, Bernadette; Malbrunot, Chloé; Massiczek, Oswald; Sauerzopf, Clemens; Simon, Martin C; Wolf, Michael; Zmeskal, Johann; Widmann, Eberhard

2015-01-01T23:59:59.000Z

194

Electronic Structure of Transition Metal-Cysteine Complexes From X-Ray Absorption Spectroscopy  

SciTech Connect (OSTI)

The electronic structures of Hg{sup II}, Ni{sup II}, Cr{sup III}, and Mo{sup V} complexes with cysteine were investigated by sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy and density functional theory. The covalency in the metal-sulfur bond was determined by analyzing the intensities of the electric-dipole allowed pre-edge features appearing in the XANES spectra below the ionization threshold. Because of the well-defined structures of the selected cysteine complexes, the current work provides a reference set for further sulfur K-edge XAS studies of bioinorganic active sites with transition metal-sulfur bonds from cysteine residues as well as more complex coordination compounds with thiolate ligands.

Leung, B.O.; Jalilehvand, F.; Szilagyi, R.K.

2009-05-19T23:59:59.000Z

195

Gas cell for in situ soft X-ray transmission-absorption spectroscopy of materials  

SciTech Connect (OSTI)

A simple gas cell design, constructed primarily from commercially available components, enables in situ soft X-ray transmission-absorption spectroscopy of materials in contact with gas at ambient temperature. The cell has a minimum X-ray path length of 1 mm and can hold gas pressures up to ?300 Torr, and could support higher pressures with simple modifications. The design enables cycling between vacuum and gas environments without interrupting the X-ray beam, and can be fully sealed to allow for measurements of air-sensitive samples. The cell can attach to the downstream port of any appropriate synchrotron beamline, and offers a robust and versatile method for in situ measurements of certain materials. The construction and operation of the cell are discussed, as well as sample preparation and proper spectral analysis, illustrated by examples of spectral measurements. Potential areas for improvement and modification for specialized applications are also mentioned.

Drisdell, W. S.; Kortright, J. B. [Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2014-07-15T23:59:59.000Z

196

Development of mixed-waste analysis capability for graphite furnace atomic absorption spectrophotometry  

SciTech Connect (OSTI)

Graphite furnace atomic absorption spectrophotometer (GFAAS) are typically configured with ventilation to capture potentially toxic and corrosive gases emitted from the vaporization of sample aliquots. When radioactive elements are present, additional concerns (such as meeting safety guidelines and ALARA principles) must be addressed. This report describes a modification to a GFAAS that provides additional containment of vaporized sample aliquots. The modification was found to increase containment by a factor of 80, given expected operating conditions. The use of the modification allows more mixed-waste samples to be analyzed, permits higher levels of radioactive samples to be analyzed, or exposes the analyst to less airborne radioactivity. The containment apparatus was attached to a Perkin-Elmer Zeeman 5000 spectrophotometer for analysis of mixed-waste samples; however, it could also be used on other systems and in other applications where greater containment of vaporized material is desired.

Bass, D.A.; TenKate, L.B.; Wroblewski, A.

1995-03-01T23:59:59.000Z

197

Indirect determination of microquantities of bromide ions in niobium germanide films by atomic absorption  

SciTech Connect (OSTI)

This paper presents a procedure for the determination of bromide ions in niobium germanide films on a copper support, prepared by the reduction of niobium and germanium bromides with hydrogen. The amount of bromine in the analyzed solutions after sorption was assessed from the mercury content by multiplying the mercury concentration by a factor of 2. An atomic-absorption spectrophotometer was used in the work and the photocurrent was recorded by means of a standard compensation recorder. A high-frequency electrodeless mercury lamp served as the light source. In order to check the correctness of analysis and to determine the error of the developed procedure, ''added found'' tests were carried out with the use of six quartz columns.

Chuchalina, L.S.

1986-08-01T23:59:59.000Z

198

Vacuum-UV absorption spectroscopy of interstellar ice analogues. III. Isotopic effects  

E-Print Network [OSTI]

This paper reports the first measurements of solid-phase vacuum-ultraviolet (VUV) absorption cross-sections of heavy isotopologues present in icy dust grain mantles of dense interstellar clouds and cold circumstellar environments. Pure ices composed of D2O, CD3OD, 13CO2, and 15N15N were deposited at 8 K, a value similar to the coldest dust temperatures in space. The column density of the ice samples was measured in situ by infrared spectroscopy in transmittance. VUV spectra of the ice samples were collected in the 120-160 nm (10.33-7.74 eV) range using a commercial microwave discharged hydrogen flow lamp as the VUV source. Prior to this work, we have recently submitted a similar study of the light isotopologues (Cruz-Diaz, Mu\\~noz Caro and Chen). The VUV spectra are compared to those of the light isotopologues in the solid phase, and to the gas phase spectra of the same molecules. Our study is expected to improve very significantly the models that estimate the VUV absorption of ice mantles in space, which hav...

Cruz-Diaz, G A; Chen, Y -J

2014-01-01T23:59:59.000Z

199

X-ray absorption spectroscopy and EPR studies of oriented spinach thylakoid preparations  

SciTech Connect (OSTI)

In this study, oriented Photosystem II (PS II) particles from spinach chloroplasts are studied with electron paramagnetic resonance (EPR) and x-ray absorption spectroscopy (XAS) to determine more details of the structure of the oxygen evolving complex (OEC). The nature of halide binding to Mn is also studied with Cl K-edge and Mn EXAFS (extended x-ray absorption fine structure) of Mn-Cl model compounds, and with Mn EXAFS of oriented PS II in which Br has replaced Cl. Attention is focused on the following: photosynthesis and the oxygen evolving complex; determination of mosaic spread in oriented photosystem II particles from signal II EPR measurement; oriented EXAFS--studies of PS II in the S{sub 2} state; structural changes in PS II as a result of treatment with ammonia: EPR and XAS studies; studies of halide binding to Mn: Cl K-edge and Mn EXAFS of Mn-Cl model compounds and Mn EXAFS of oriented Br-treated photosystem II.

Andrews, J.C. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Structural Biology Div.

1995-08-01T23:59:59.000Z

200

Millisecond Kinetics of Nanocrystal Cation Exchange UsingMicrofluidic X-ray Absorption Spectroscopy  

SciTech Connect (OSTI)

We describe the use of a flow-focusing microfluidic reactorto measure the kinetics of theCdSe-to-Ag2Se nanocrystal cation exchangereaction using micro-X-ray absorption spectroscopy (mu XAS). The smallmicroreactor dimensions facilitate the millisecond mixing of CdSenanocrystal and Ag+ reactant solutions, and the transposition of thereaction time onto spatial coordinates enables the in situ observation ofthe millisecond reaction with mu XAS. XAS spectra show the progression ofCdSe nanocrystals to Ag2Se over the course of 100 ms without the presenceof long-lived intermediates. These results, along with supporting stoppedflow absorption experiments, suggest that this nanocrystal cationexchange reaction is highly efficient and provide insight into how thereaction progresses in individual particles. This experiment illustratesthe value and potential of in situ microfluidic X-ray synchrotrontechniques for detailed studies of the millisecond structuraltransformations of nanoparticles and other solution-phase reactions inwhich diffusive mixing initiates changes in local bond structures oroxidation states.

Chan, Emory M.; Marcus, Matthew A.; Fakra, Sirine; Elnaggar,Mariam S.; Mathies, Richard A.; Alivisatos, A. Paul

2007-05-07T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
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201

E-Print Network 3.0 - absorption edge spectroscopy Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Domain Spectroscopy From... Industrial applications: spectroscopy, imaging and security Terahertz: Research and Applications 12... of Photonic THz Radiation transmission &...

202

Light-induced polarization effects in atoms with partially resolved hyperfine structure and applications to absorption, fluorescence, and nonlinear magneto-optical rotation  

E-Print Network [OSTI]

Light-induced polarization effects in atoms with partially resolved hyperfine structure and applications to absorption, fluorescence, and nonlinear magneto-optical rotation M. Auzinsh* Department 9 November 2009 The creation and detection of atomic polarization is examined theoretically through

Auzinsh, Marcis

203

Aharonov-Bohm scattering of charged particles and neutral atoms: the role of absorption  

E-Print Network [OSTI]

The Aharonov-Bohm scattering of charged particles by the magnetic field of an infinitely long and infinitely thin solenoid (magnetic string) in an absorbing medium is studied. We discuss the partial-wave approach to this problem and show that standard partial-wave method can be adjusted to this case. The effect of absorption leads to oscillations of the AB cross section. Based on this we investigate the scattering of neutral atoms with induced electric dipole moments by a charge wire of finite radius which is placed in an uniform magnetic field. The physical realistic and practically important case that all atoms which collide with the wire are totally absorbed at its surface, is studied in detail. The dominating terms of the scattering amplitude are evaluated analytically for different physical constellations. The rest terms are written in a form suitable for a numerical computation. We show that if the magnetic field is absent, the absorbing charged wire causes oscillations of the cross section. In the presence of the magnetic field the cross section increases and the dominating Aharonov--Bohm peak appears in the forward direction, suppressing the oscillations.

Juergen Audretsch; Vladimir Skarzhinsky

1999-01-25T23:59:59.000Z

204

SUBARU HIGH-RESOLUTION SPECTROSCOPY OF COMPLEX METAL ABSORPTION LINES OF THE QUASAR HS 1603+38201  

E-Print Network [OSTI]

SUBARU HIGH-RESOLUTION SPECTROSCOPY OF COMPLEX METAL ABSORPTION LINES OF THE QUASAR HS 1603-resolution spectrum of the quasar HS 1603+3820 (zem = 2.542), observed with the High Dispersion Spectrograph -- quasars: individual (HS 1603+3820) 1. INTRODUCTION The bright quasar HS 1603+3820 (zem = 2.542, B = 15

Iye, Masanori

205

PHYSICAL REVIEW A 89, 023408 (2014) High-spectral-resolution attosecond absorption spectroscopy of autoionization in xenon  

E-Print Network [OSTI]

formalism is introduced that correctly accounts for the observed energy dependence. DOI: 10.1103/PhysRevA.89PHYSICAL REVIEW A 89, 023408 (2014) High-spectral-resolution attosecond absorption spectroscopy Department of Physics, University of California, Berkeley, California, USA (Received 25 November 2013

Neumark, Daniel M.

206

Reaction Kinetics and Polarization-Modulation Infrared Reflection Absorption Spectroscopy (PM-IRAS) Investigation of CO Oxidation over Supported Pd-Au Alloy Catalysts  

E-Print Network [OSTI]

dissociation, using polarization-modula- tion infrared reflection absorption spectroscopy (PM-IRAS). At nearReaction Kinetics and Polarization-Modulation Infrared Reflection Absorption Spectroscopy (PM automotive converter catalysis, that is, reactions at or near stoichiometry, CO pressures of 0.01 atm

Goodman, Wayne

207

X-ray Absorption Spectroscopy Identifies Calcium-Uranyl-Carbonate Complexes at Environmental Concentrations  

SciTech Connect (OSTI)

Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO2-CO3 complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO2-CO3 complex. Such a complex might exist even at high calcium concentrations, as some UO2-CO3 complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 lM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO2-CO3 complex to approximately 0.6 and enables spectroscopic identification of the Na-UO2-CO3 complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations.

Kelly, Shelly D [Argonne National Laboratory (ANL); Kemner, Kenneth M [Argonne National Laboratory (ANL); Brooks, Scott C [ORNL

2007-01-01T23:59:59.000Z

208

INFRARED ABSORPTION SPECTROSCOPY OF SURFACES: A LOW TEMPERATURE THERMAL DETECTION SCHEME  

E-Print Network [OSTI]

Frequency (l/CM) Fig. 5. Absorption spectrum of chemicallyFilm Frequency (l/CM) Fig. 6, Absorption spectrum of benzenei Fig. 7. -JU— (l/CM) Absorption spectrum of methane

Bailey, R. B.

2011-01-01T23:59:59.000Z

209

Cavity induced modifications to the resonance fluorescence and probe absorption of a laser-dressed V atom  

E-Print Network [OSTI]

A cavity-modified master equation is derived for a coherently driven, V-type three-level atom coupled to a single-mode cavity in the bad cavity limit. We show that population inversion in both the bare and dressed-state bases may be achieved, originating from the enhancement of the atom-cavity interaction when the cavity is resonant with an atomic dressed-state transition. The atomic populations in the dressed state representation are analysed in terms of the cavity-modified transition rates. The atomic fluorescence spectrum and probe absorption spectrum also investigated, and it is found that the spectral profiles may be controlled by adjusting the cavity frequency. Peak suppression and line narrowing occur under appropriate conditions.

Jin-Sheng Peng; Gao-Xiang Li; Peng Zhou; S. Swain

2000-03-20T23:59:59.000Z

210

X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films  

SciTech Connect (OSTI)

The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

1999-02-01T23:59:59.000Z

211

Cation distribution in Ni{sub 1?x}Zn{sub x}Fe{sub 2}O{sub 4} using X-ray absorption spectroscopy  

SciTech Connect (OSTI)

Spinel ferrite samples of Ni{sub 1?x}Zn{sub x}Fe{sub 2}O{sub 4} (for x=0.2, 0.4, 0.5, 0.6 and 0.8) nanoparticles prepared by a novel chemical synthesis method have been characterized by X-ray Absorption Spectroscopy (XAS) technique to investigate the distribution of cations in the unit cell. XANES region clearly shows that as Ni concentration increases, the pre-edge feature, which is a characteristic of tetrahedral coordination of Fe, is enhanced. A quantitative determination of the relative occupancy of iron cation in the octahedral and tetrahedral sites of the spinel structure was obtained from EXAFS data analysis. It has been found that as atomic fraction of Ni is increased from 0.2 to 0.8, Fe occupancy at tetrahedral to octahedral sites is increased from 13:87 and to 39:61.

Yadav, A. K., E-mail: akyadav@barc.gov.in; Jha, S. N.; Bhattacharyya, D.; Sahoo, N. K. [Atomic and Molecular Physics Division, Bhabha Atomic Research Centre, Mumbai - 400094 (India); Jadhav, J.; Biswas, S. [Department of Physics, The LNM Institute of Information Technology, Jaipur-302031 (India)

2014-04-24T23:59:59.000Z

212

E-Print Network 3.0 - absorption spectroscopy diagnostics Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Domain Spectroscopy From... Industrial applications: spectroscopy, imaging and security Terahertz: Research and Applications 12... in a volume Measuring of moisture in a volume...

213

Quantum cascade laser absorption spectroscopy with the amplitude-to-time conversion technique for atmospheric-pressure plasmas  

SciTech Connect (OSTI)

The NO{sub 2} concentration, i.e., density, in a small plasma of a nitrogen oxide (NOx) treatment reactor has been measured by highly sensitive laser absorption spectroscopy. The absorption spectroscopy uses a single path of a quantum cascade laser beam passing through a plasma whose dimension is about 1 cm. The high sensitivity of spectroscopy is achieved by the amplitude-to-time conversion technique. Although the plasma reactor is designed to convert NO in the input gas to NO{sub 2}, it has been demonstrated by this highly sensitive absorption spectroscopy that NO{sub 2} in a simulated exhaust gas that enters the reactor is decomposed by the plasma first and then NO{sub 2} is formed again, possibly more than it was decomposed, through a series of gas-phase reactions by the time the gas exits the reactor. The observation is consistent with that of an earlier study on NO decomposition by the same type of a plasma reactor [T. Yumii et al., J. Phys. D 46, 135202 (2013)], in which a high concentration of NO{sub 2} was observed at the exit of the reactor.

Yumii, Takayoshi; Kimura, Noriaki [Mitsui Engineering and Shipbuilding Co., Ltd., Tamahara 3-16-1, Tamano, Okayama 706-0014 (Japan) [Mitsui Engineering and Shipbuilding Co., Ltd., Tamahara 3-16-1, Tamano, Okayama 706-0014 (Japan); Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan); Hamaguchi, Satoshi [Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan)] [Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan)

2013-06-07T23:59:59.000Z

214

Understanding Sulfur Poisoning and Regeneration of Nickel Biomass Conditioning Catalysts using X-Ray Absorption Spectroscopy  

SciTech Connect (OSTI)

The production of biofuels can proceed via a biomass gasification to produce syngas, which can then undergo catalytic conditioning and reforming reactions prior to being sent to a fuel synthesis reactor. Catalysts used for biomass conditioning are plagued by short lifetimes which are a result of, among other things, poisoning. Syngas produced from biomass gasification may contain between 30-300 ppm H2S, depending on the feedstock and gasification conditions, and H2S is a key catalyst poison. In order to overcome catalyst poisoning, either an H2S-tolerant catalyst or an efficient regeneration protocol should be employed. In this study, sulfur K-edge X-ray absorption near edge spectroscopy (XANES) was used to monitor sulfur species on spent catalyst samples and the transformation of these species from sulfides to sulfates during steam and air regeneration on a Ni/Mg/K/Al2O3 catalyst used to condition biomass-derived syngas. Additionally, nickel K-edge EXAFS and XANES are used to examine the state of nickel species on the catalysts. Post-reaction samples showed the presence of sulfides on the H2S-poisoned nickel catalyst and although some gaseous sulfur species were observed to leave the catalyst bed during regeneration, sulfur remained on the catalyst and a transformation from sulfides to sulfates was observed. The subsequent H2 reduction led to a partial reduction of sulfates back to sulfides. A proposed reaction sequence is presented and recommended regeneration strategies are discussed.

Yung, M. M.; Cheah, S.; Kuhn, J. N.

2013-01-01T23:59:59.000Z

215

Identification of lead chemical form in mine waste materials by X-ray absorption spectroscopy  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) provides a direct means for measuring lead chemical forms in complex samples. In this study, XAS was used to identify the presence of plumbojarosite (PbFe{sub 6}(SO{sub 4}){sub 4}(OH){sub 12}) by lead L{sub 3}-edge XANES spectra in mine waste from a small gold mining operation in Fiji. The presence of plumbojarosite in tailings was confirmed by XRD but XANES gave better resolution. The potential for human uptake of Pb from tailings was measured using a physiologically based extract test (PBET), an in-vitro bioaccessibility (BAc) method. The BAc of Pb was 55%. Particle size distribution of tailings indicated that 40% of PM{sub 10} particulates exist which could be a potential risk for respiratory effects via the inhalation route. Food items collected in the proximity of the mine site had lead concentrations which exceed food standard guidelines. Lead within the mining lease exceeded sediment guidelines. The results from this study are used to investigate exposure pathways via ingestion and inhalation for potential risk exposure pathways of Pb in that locality. The highest Pb concentration in soil and tailings was 25,839 mg/kg, exceeding the Australian National Environment Protection Measure (NEPM) soil health investigation levels.

Taga, Raijeli L.; Ng, Jack [University of Queensland, National Research Centre for Environmental Toxicology (EnTox), Brisbane, 4108 (Australia); Zheng Jiajia; Huynh, Trang; Noller, Barry [University of Queensland, Centre for Mined Land Rehabilitation, Brisbane, 4072 (Australia); Harris, Hugh H. [School of Chemistry and Physics, University of Adelaide, Adelaide, 5005 (Australia)

2010-06-23T23:59:59.000Z

216

A new endstation at the Swiss Light Source for ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy measurements of liquid solutions  

SciTech Connect (OSTI)

A new liquid microjet endstation designed for ultraviolet (UPS) and X-ray (XPS) photoelectron, and partial electron yield X-ray absorption (XAS) spectroscopies at the Swiss Light Source is presented. The new endstation, which is based on a Scienta HiPP-2 R4000 electron spectrometer, is the first liquid microjet endstation capable of operating in vacuum and in ambient pressures up to the equilibrium vapor pressure of liquid water at room temperature. In addition, the Scienta HiPP-2 R4000 energy analyzer of this new endstation allows for XPS measurements up to 7000 eV electron kinetic energy that will enable electronic structure measurements of bulk solutions and buried interfaces from liquid microjet samples. The endstation is designed to operate at the soft X-ray SIM beamline and at the tender X-ray Phoenix beamline. The endstation can also be operated using a Scienta 5 K ultraviolet helium lamp for dedicated UPS measurements at the vapor-liquid interface using either He I or He II ? lines. The design concept, first results from UPS, soft X-ray XPS, and partial electron yield XAS measurements, and an outlook to the potential of this endstation are presented.

Brown, Matthew A.; Redondo, Amaia Beloqui; Duyckaerts, Nicolas; Mächler, Jean-Pierre [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland)] [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland); Jordan, Inga; Wörner, Hans Jakob [Laboratory of Physical Chemistry, ETH Zürich, CH-8093 Zürich (Switzerland)] [Laboratory of Physical Chemistry, ETH Zürich, CH-8093 Zürich (Switzerland); Lee, Ming-Tao; Ammann, Markus; Nolting, Frithjof; Kleibert, Armin; Huthwelker, Thomas; Birrer, Mario; Honegger, Juri; Wetter, Reto [Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland)] [Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland); Bokhoven, Jeroen A. van [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland) [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland); Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland)

2013-07-15T23:59:59.000Z

217

Time-resolved surface infrared spectroscopy during atomic layer deposition of TiO{sub 2} using tetrakis(dimethylamido)titanium and water  

SciTech Connect (OSTI)

Atomic layer deposition of titanium dioxide using tetrakis(dimethylamido)titanium (TDMAT) and water vapor is studied by reflection-absorption infrared spectroscopy (RAIRS) with a time resolution of 120?ms. At 190?°C and 240?°C, a decrease in the absorption from adsorbed TDMAT is observed without any evidence of an adsorbed product. Ex situ measurements indicate that this behavior is not associated with an increase in the impurity concentration or a dramatic change in the growth rate. A desorbing decomposition product is consistent with these observations. RAIRS also indicates that dehydroxylation of the growth surface occurs only among one type of surface hydroxyl groups. Molecular water is observed to remain on the surface and participates in reactions even at a relatively high temperature (110?°C) and with long purge times (30?s)

Sperling, Brent A., E-mail: brent.sperling@nist.gov; Hoang, John; Kimes, William A.; Maslar, James E. [Chemical Sciences Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8320, Gaithersburg, Maryland 20899-8320 (United States); Steffens, Kristen L. [Biomolecular Measurement Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8362, Gaithersburg, Maryland 20899-8362 (United States); Nguyen, Nhan V. [Semiconductor and Dimensional Metrology Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8120, Gaithersburg, Maryland 20899-8120 (United States)

2014-05-15T23:59:59.000Z

218

Subwavelength atom localization via amplitude and phase control of the absorption spectrum. II  

E-Print Network [OSTI]

Interaction of the internal states of an atom with spatially dependent standing-wave cavity field can impart position information of the atom passing through it leading to subwavelength atom localization. We recently demonstrated a different regime...

Kapale, KT; Zubairy, M. Suhail.

2006-01-01T23:59:59.000Z

219

Polarization of absorption lines as a diagnostics of circumstellar, interstellar and intergalactic magnetic fields: Fine structure atoms  

E-Print Network [OSTI]

The relative population of the fine structure sublevels of an atom's ground state is affected by radiative transitions induced by an anisotropic radiation flux. This causes the alignment of atomic angular momentum. In terms of observational consequences for the interstellar and intergalactic medium, this results in the polarization of the absorption lines. In the paper we consider the conditions necessary for this effect and provide calculations of polarization from a few astrophysically important atoms and ions with multiple upper and lower levels for an arbitrary orientation of magnetic fields to the a) source of optical pumping, b) direction of observation, c) absorbed source. We also consider an astrophysically important ``degenerate'' case when the source of optical pumping coincides with the source of the absorbed radiation. We present analytical expressions that relate the degree of linear polarization and the intensity of absorption to the 3D orientation of the magnetic field with respect to the pumping source, the source of the absorbed radiation, and the direction of observations. We discuss how all these parameters can be determined via simultaneous observations of several absorption lines and suggest graphical means that are helpful in practical data interpretation. We prove that studies of absorption line polarization provide a unique tool to study 3D magnetic field topology in various astrophysical conditions.

Huirong Yan; A. Lazarian

2006-11-09T23:59:59.000Z

220

Chapter 1 - The Impacts of X-Ray Absorption Spectroscopy on Understanding Soil Processes and Reaction Mechanisms  

SciTech Connect (OSTI)

During the last two decades, X-ray absorption spectroscopy (XAS) has developed into a mature technique for obtaining the speciation (e.g., oxidation state) and short-range structure of elements present in soils and sediments. XAS encompasses both X-ray absorption near-edge structure (XANES) spectroscopy and extended X-ray absorption fine structure (EXAFS) spectroscopy. XAS has a number of advantageous qualities for studying soils and sediments, which include elemental specificity, sensitivity to the local chemical and structural state of an element, and the ability to analyze materials in situ. This information allows accurate determination of oxidation state, type of nearest neighbors, coordination number, bond distance, and orbital symmetries of the X-ray absorbing element. In this review, we examine the application of a wide variety of synchrotron X-ray techniques to fundamental issues in environmental soil chemistry. Additionally, we examine the application of microfocused and time-resolved XAS to determine speciation (e.g., oxidation state and/or local coordination environment) and transformation kinetics of contaminants in heterogeneous environmental systems. During the last three decades, XAS has a played a critical role in furthering our understanding of a myriad of environmental systems and will continue to do so into the foreseeable future.

Ginder-Vogel, Matthew; Sparks, Donald L. (Delaware)

2011-11-17T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

A tomographic technique for the simultaneous imaging of temperature, chemical species, and pressure in reactive flows using absorption spectroscopy with frequency-agile lasers  

E-Print Network [OSTI]

This paper proposes a technique that can simultaneously retrieve distributions of temperature, concentration of chemical species, and pressure based on broad bandwidth, frequency-agile tomographic absorption spectroscopy. The technique holds...

Cai, Weiwei; Kaminski, Clemens F.

2014-01-21T23:59:59.000Z

222

Proposed method for laser spectroscopy of pionic helium atoms to determine the charged-pion mass  

E-Print Network [OSTI]

Metastable pionic helium ($\\pi{\\rm He}^+$) is a three-body atom composed of a helium nucleus, an electron occupying the $1s$ ground state, and a negatively charged pion $\\pi^-$ in a Rydberg state with principal- and orbital angular momentum quantum numbers of $n\\sim \\ell+1\\sim 16$. We calculate the spin-independent energies of the $\\pi{\\rm ^3He}^+$ and $\\pi{\\rm ^4He}^+$ isotopes in the region $n=15$--19. These include relativistic and quantum electrodynamics corrections of orders $R_{\\infty}\\alpha^2$ and $R_{\\infty}\\alpha^3$ in atomic units, where $R_{\\infty}$ and $\\alpha$ denote the Rydberg and fine structure constants. The fine-structure splitting due to the coupling between the electron spin and the orbital angular momentum of the $\\pi^-$, and the radiative and Auger decay rates of the states are also calculated. Some states $(n,\\ell)=(16,15)$ and $(17,16)$ retain nanosecond-scale lifetimes against $\\pi^-$ absorption into the helium nucleus. We propose to use laser pulses to induce $\\pi^-$ transitions from these metastable states, to states with large ($\\sim 10^{11}$ s$^{-1}$) Auger rates. The $\\pi{\\rm He}^{2+}$ ion that remains after Auger emission of the $1s$ electron undergoes Stark mixing with the $s$, $p$, and $d$ states during collisions with the helium atoms in the experimental target. This leads to immediate nuclear absorption of the $\\pi^-$. The resonance condition between the laser beam and the atom is thus revealed as a sharp spike in the rates of neutrons, protons, deuterons, and tritons that emerge....(continued)

Masaki Hori; Anna Sótér; Vladimir I. Korobov

2014-04-30T23:59:59.000Z

223

AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS  

E-Print Network [OSTI]

oxygen evolving capabilities. These preparations are reported to have 4-6 manganese atoms per photochemical reaction center(

Kirby, Jon Allan

2012-01-01T23:59:59.000Z

224

Polarized X-Ray Absorption Spectroscopy of Single-Crystal Mn(V) Complexes Relevant to the Oxygen-Evolving Complex of Photosystem II  

SciTech Connect (OSTI)

High-valent Mn-oxo species have been suggested to have a catalytically important role in the water splitting reaction which occurs in the Photosystem II membrane protein. In this study, five- and six-coordinate mononuclear Mn(V) compounds were investigated by polarized X-ray absorption spectroscopy in order to understand the electronic structure and spectroscopic characteristics of high-valent Mn species. Single crystals of the Mn(V)-nitrido and Mn(V)-oxo compounds were aligned along selected molecular vectors with respect to the X-ray polarization vector using X-ray diffraction. The local electronic structure of the metal site was then studied by measuring the polarization dependence of X-ray absorption near-edge spectroscopy (XANES) pre-edge spectra (1s to 3d transition) and comparing with the results of density functional theory (DFT) calculations. The Mn(V)-nitrido compound, in which the manganese is coordinated in a tetragonally distorted octahedral environment, showed a single dominant pre-edge peak along the MnN axis that can be assigned to a strong 3dz2-4pz mixing mechanism. In the square pyramidal Mn(V)-oxo system, on the other hand, an additional peak was observed at 1 eV below the main pre-edge peak. This component was interpreted as a 1s to 3dxz,yz transition with 4px,y mixing, due to the displacement of the Mn atom out of the equatorial plane. The XANES results have been correlated to DFT calculations, and the spectra have been simulated using a TD (time-dependent)-DFT approach. The relevance of these results to understanding the mechanism of the photosynthetic water oxidation is discussed.

Yano, J.K.; Robblee, J.; Pushkar, Y.; Marcus, M.A.; Bendix, J.; Workman, J.M.; Collins, T.J.; Solomon, E.I.; George, S.D.; Yachandra, V.K.; /LBL, Berkeley /Copenhagen U. /Stanford U., Chem. Dept. /SLAC, SSRL

2007-10-16T23:59:59.000Z

225

Advances in X-Ray Chemical Analysis, Japan, 45 (2014) ISSN 0911-7806 Role of Infrared Absorption Spectroscopy in the Forensic Analysis of  

E-Print Network [OSTI]

Spectroscopy in the Forensic Analysis of Wakayama Curry Arsenic Poisoning Case Anthony T. TU and Jun KAWAI #12 80523, U. S. A. 606-8501 Role of Infrared Absorption Spectroscopy in the Forensic Analysis of Wakayama-8 X-ray fluorescence analysis was the key scientific evidence for the forensic analysis

Jun, Kawai

226

E-Print Network 3.0 - absorption spectroscopy method Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Mathematics 83 Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky* Summary: , but different...

227

E-Print Network 3.0 - absorption infrared spectroscopy Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electron paramagnetic resonance spectroscopy to establish the technology needed... , terahertz radiation is between microwave and infrared. the dynamics of many important ......

228

A first principle study for the adsorption and absorption of carbon atom and the CO dissociation on Ir(100) surface  

SciTech Connect (OSTI)

We employ density functional theory to examine the adsorption and absorption of carbon atom as well as the dissociation of carbon monoxide on Ir(100) surface. We find that carbon atoms bind strongly with Ir(100) surface and prefer the high coordination hollow site for all coverages. In the case of 0.75?ML coverage of carbon, we obtain a bridging metal structure due to the balance between Ir–C and Ir–Ir interactions. In the subsurface region, the carbon atom prefers the octahedral site of Ir(100) surface. We find large diffusion barrier for carbon atom into Ir(100) surface (2.70 eV) due to the strong bonding between carbon atom and Ir(100) surface, whereas we find a very small segregation barrier (0.22 eV) from subsurface to the surface. The minimum energy path and energy barrier for the dissociation of CO on Ir(100) surface are obtained by using climbing image nudge elastic band. The energy barrier of CO dissociation on Ir(100) surface is found to be 3.01 eV, which is appreciably larger than the association energy (1.61 eV) of this molecule.

Erikat, I. A., E-mail: ihsanas@yahoo.com [Department of Physics, Jerash University, Jerash-26150 (Jordan); Hamad, B. A. [Department of Physics, The University of Jordan, Amman-11942 (Jordan)] [Department of Physics, The University of Jordan, Amman-11942 (Jordan)

2013-11-07T23:59:59.000Z

229

Vacuum-UV spectroscopy of interstellar ice analogs. II. Absorption cross-sections of nonpolar ice molecules  

E-Print Network [OSTI]

Dust grains in cold circumstellar regions and dark-cloud interiors at 10-20 K are covered by ice mantles. A nonthermal desorption mechanism is invoked to explain the presence of gas-phase molecules in these environments, such as the photodesorption induced by irradiation of ice due to secondary ultraviolet photons. To quantify the effects of ice photoprocessing, an estimate of the photon absorption in ice mantles is required. In a recent work, we reported the vacuum-ultraviolet (VUV) absorption cross sections of nonpolar molecules in the solid phase. The aim was to estimate the VUV-absorption cross sections of nonpolar molecular ice components, including CH4, CO2, N2, and O2. The column densities of the ice samples deposited at 8 K were measured in situ by infrared spectroscopy in transmittance. VUV spectra of the ice samples were collected in the 120-160 nm (10.33-7.74 eV) range using a commercial microwave-discharged hydrogen flow lamp. We found that, as expected, solid N2 has the lowest VUV-absorption cros...

Cruz-Diaz, G A; Chen, Y -J; Yih, T -S

2014-01-01T23:59:59.000Z

230

Design and Operation of an In Situ High Pressure Reaction Cell for X-Ray Absorption Spectroscopy  

SciTech Connect (OSTI)

The design and initial operation of an in situ catalysis reaction cell for x-ray absorption spectroscopy measurements at high pressure is described. The design is based on an x-ray transparent tube fabricated from beryllium. This forms a true plug flow reactor for catalysis studies. The reactor is coupled to a portable microprocessor-controlled versatile feed system, and incorporates on-line analysis of reaction products. XAFS data recorded during the reduction of a NiRe/carbon catalyst at 4 bar are used to illustrate the performance of the reactor.

Bare, Simon R.; Mickelson, G. E.; Modica, F. S. [UOP LLC, Des Plaines, IL, 60016 (United States); Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 6044 (United States)

2007-02-02T23:59:59.000Z

231

Spontaneous absorption of an accelerated hydrogen atom near a conducting plane in vacuum  

E-Print Network [OSTI]

We study, in the multipolar coupling scheme, a uniformly accelerated multilevel hydrogen atom in interaction with the quantum electromagnetic field near a conducting boundary and separately calculate the contributions of the vacuum fluctuation and radiation reaction to the rate of change of the mean atomic energy. It is found that the perfect balance between the contributions of vacuum fluctuations and radiation reaction that ensures the stability of ground-state atoms is disturbed, making spontaneous transition of ground-state atoms to excited states possible in vacuum with a conducting boundary. The boundary-induced contribution is effectively a nonthermal correction, which enhances or weakens the nonthermal effect already present in the unbounded case, thus possibly making the effect easier to observe. An interesting feature worth being noted is that the nonthermal corrections may vanish for atoms on some particular trajectories.

Hongwei Yu; Zhiying Zhu

2006-08-23T23:59:59.000Z

232

Subwavelength atom localization via amplitude and phase control of the absorption spectrum-II  

E-Print Network [OSTI]

Interaction of the internal states of an atom with spatially dependent standing-wave cavity field can impart position information of the atom passing through it leading to subwavelength atom localization. We recently demonstrated a new regime of atom localization [Sahrai {\\it et al.}, Phys. Rev. A {\\bf 72}, 013820 (2005)], namely sub-half-wavelength localization through phase control of electromagnetically induced transparency. This regime corresponds to extreme localization of atoms within a chosen half-wavelength region of the standing-wave cavity field. Here we present further investigation of the simplified model considered earlier and show interesting features of the proposal. We show how the model can be used to simulate variety of energy level schemes. Furthermore, the dressed-state analysis is employed to explain the emergence and suppression of the localization peaks, and the peak positions and widths. The range of parameters for obtaining clean sub-half-wavelength localization is identified.

Kishore T. Kapale; M. Suhail Zubairy

2005-09-09T23:59:59.000Z

233

Two photon absorption and third harmonic generation micro- spectroscopy : hemoglobin and other compounds  

E-Print Network [OSTI]

As the absorption of ultrafast pulses in the vessel lumen isfocussed, ultrafast, ~2 nano-joule laser pulses at selectedwith ultrafast ( ~100-200 fs in duration) laser pulses at

Clay, Gabriel Omar

2006-01-01T23:59:59.000Z

234

Direct and quantitative broadband absorptance micro/nano spectroscopy using FTIR and bilayer cantilever probes  

E-Print Network [OSTI]

Optical properties of micro/nano materials are important for many applications in biology, optoelectronics, and energy. In this thesis, a method is described to directly measure the quantitative absorptance spectra of ...

Hsu, Wei-Chun

2012-01-01T23:59:59.000Z

235

Atomic Resolution Mapping of the Excited-State Electronic Structure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mapping of the Excited-State Electronic Structure of Cu2O with Time-Resolved X-Ray Absorption Spectroscopy. Atomic Resolution Mapping of the Excited-State Electronic Structure of...

236

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

Minor Elements in Oil Shale and Oil-Shale Products. LERC RIChemistry of Tar Sands and Oil Shale, ACS, New Orleans.Constituent Analysis of Oil Shale and Solvent-Refined Coal

Girvin, D.G.

2011-01-01T23:59:59.000Z

237

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

A. Robb, and T. J. Spedding. Minor Elements in Oil Shale andOil-Shale Products. LERC RI 77-1, 1977. Bertine, K. K. andFrom A Simulated In-Situ Oil Shale Retort. In: Procedings of

Girvin, D.G.

2011-01-01T23:59:59.000Z

238

The use of solvent extraction in trace metal analysis by atomic absorption spectroscopy  

E-Print Network [OSTI]

. , reagen4 grade. NamHPOn ~ 7H-. . G T ' Till 68 08 Fe . ?. 0. 0003'Ii. S~ diun; di. hy;!i'cg=n phosphate, J. T. Baker, rcag?nt grade. F. W. 138. 00. Sodium tartrate, J. T. Baker, reagent grade. Nae04H40e 2HnO F. W. 250. 08 Fe = 0. 0002/0. d... the sta!&dards ;&ere prepared. The solutions werc pipeti, ed. into a 125&-ml pear-sba d. separatory funnel and. 5 ml of 41 reagen4 sclurion &;as added. '!ne rsixture was shaken for I'ive s&inutes. 'The layers were allowed to separate snd th or- ganic...

Eddy, Raymond Douglas

1968-01-01T23:59:59.000Z

239

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

W. A. Robb, and T. J. Spedding. Minor Elements in Oil Shaleand Oil-Shale Products. LERC RI 77-1, 1977. Bertine, K. K.From A Simulated In-Situ Oil Shale Retort. In: Procedings of

Girvin, D.G.

2011-01-01T23:59:59.000Z

240

Improved graphite furnace atomizer  

DOE Patents [OSTI]

A graphite furnace atomizer for use in graphite furnace atomic absorption spectroscopy is described wherein the heating elements are affixed near the optical path and away from the point of sample deposition, so that when the sample is volatilized the spectroscopic temperature at the optical path is at least that of the volatilization temperature, whereby analyteconcomitant complex formation is advantageously reduced. The atomizer may be elongated along its axis to increase the distance between the optical path and the sample deposition point. Also, the atomizer may be elongated along the axis of the optical path, whereby its analytical sensitivity is greatly increased.

Siemer, D.D.

1983-05-18T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Measurement of lanthanum and technetium in uranium fuels by inductively coupled plasma atomic emission spectroscopy.  

SciTech Connect (OSTI)

An important parameter in characterizing an irradiated nuclear fuel is determining the amount of uranium fissioned. By determining the amount of uranium fissioned in the fuel a burnup performance parameter can be calculated, and the amount of fission products left in the fuel can be predicted. The quantity of uranium fissioned can be calculated from the amount of lanthanum and technetium present in the fuel. Lanthanum and technetium were measured in irradiated fuel samples using an Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES) instrument and separation equipment located in a shielded glove-box. A discussion of the method, interferences, detection limits, quality control and a comparison to other work will be presented.

Carney, K.; Crane, P.; Cummings, D.; Krsul, J.; McKnight, R.

1999-06-10T23:59:59.000Z

242

E-Print Network 3.0 - absorption rate mapping Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geosciences Page: << < 1 2 3 4 5 > >> Page: << < 1 2 3 4 5 > >> 41 Diode-laser-based atomic absorption monitor using frequency-modulation spectroscopy for physical vapor...

243

E-Print Network 3.0 - absorption spectrometry et-aas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

plant mitochon- Summary: -digested samples were analyzed for selenium by electrother- mal atomic absorption spectroscopy (ET-AAS; Perkin... -ICP-MS, and 166 (17) gL by ET-AAS vs...

244

Aspects of Graviton Detection: Graviton Emission and Absorption by Atomic Hydrogen  

E-Print Network [OSTI]

Graviton absorption cross sections and emission rates for hydrogen are calculated by both semi-classical and field theoretic methods. We point out several mistakes in the literature concerning spontaneous emission of gravitons and related phenomena, some of which are due to a subtle issue concerning gauge invariance of the linearized interaction Hamiltonian.

Stephen Boughn; Tony Rothman

2006-09-27T23:59:59.000Z

245

Absorption in Ultra-Peripheral Nucleus-Atom Collisions in Crystal  

E-Print Network [OSTI]

The Glauber theory description of particle- and nucleus-crystal Coulomb interactions at high-energy is developed. The allowance for the lattice thermal vibrations is shown to produce strong absorption effect which is of prime importance for quantitative understanding of the coherent Coulomb excitation of ultra-relativistic particles and nuclei passing through the crystal.

V. R. Zoller

2004-05-07T23:59:59.000Z

246

Theory of the Energy Levels and Precise Two--Photon Spectroscopy of Atomic Hydrogen and Deuterium 1  

E-Print Network [OSTI]

Theory of the Energy Levels and Precise Two--Photon Spectroscopy of Atomic Hydrogen and Deuterium 1 of the energy levels of simple hydrogenic systems. We review recent two­photon spectroscopic measurements performed in Garching and the relevant theoretical predictions for the hydrogen energy levels. A good

Pachucki, Krzysztof

247

Total absorption {gamma}-ray spectroscopy of beta delayed neutron emitters  

SciTech Connect (OSTI)

Preliminary results of the data analysis of the beta decay of {sup 94}Rb using a novel - segmented- total absorption spectrometer are shown in this contribution. This result is part of a systematic study of important contributors to the decay heat problem in nuclear reactors. In this particular case the goal is to determine the beta intensity distribution below the neutron separation energy and the gamma/beta competition above.

Valencia, E.; Algora, A.; Tain, J. L.; Agramunt, J.; Jordan, M. D.; Molina, F.; Estevez, E.; Rubio, B.; Perez, A. [IFIC, CSIC - Univ. Valencia, Valencia (Spain); Rice, S.; Bowry, M.; Gelletly, W.; Podolyak, Zs.; Regan, P. H.; Farrelly, G. F. [Univ. Surrey, Guildford (United Kingdom); Zakari-Issoufou, A.-A.; Porta, A.; Fallot, M.; Bui, V. M. [Subatech, CNRS/INP2P3, Nantes, EMN, Nantes (France); Caballero-Folch, R. [Univ. Pol. Catalunya, Barcelona (Spain); and others

2013-06-10T23:59:59.000Z

248

Polarization modulation infrared reflection absorption spectroscopy for heterogeneous catalytic applications at elevated pressures  

E-Print Network [OSTI]

])..................................................................................4 Fig. 2 Particle size effects on the electronic structure of adsorbed metallic particles (adapted from Ref.[6]).................................................................... 6 Fig. 3 Electronic interactions during the adsorption... of (a-c) an atomic adsorbate on a jellium metal, (d) a diatomic molecule on a metal with d and s bands (adapted from Ref. [1]) ....................................................................... 8 Fig. 4 Schematic representing a...

Ozensoy, Emrah

2005-08-29T23:59:59.000Z

249

Sulfur K-edge X-ray absorption spectroscopy as an experimental probe for S-nitroso proteins  

SciTech Connect (OSTI)

X-ray absorption spectroscopy at the sulfur K-edge (2.4-2.6 keV) provides a sensitive and specific technique to identify S-nitroso compounds, which have significance in nitric oxide-based cell signaling. Unique spectral features clearly distinguish the S-nitroso-form of a cysteine residue from the sulfhydryl-form or from a methionine thioether. Comparison of the sulfur K-edge spectra of thiolate, thiol, thioether, and S-nitroso thiolate compounds indicates high sensitivity of energy positions and intensities of XAS pre-edge features as determined by the electronic environment of the sulfur absorber. A new experimental setup is being developed for reaching the in vivo concentration range of S-nitroso thiol levels in biological samples.

Szilagyi, Robert K. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)]. E-mail: Szilagyi@Montana.EDU; Schwab, David E. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)

2005-04-29T23:59:59.000Z

250

H-atom high-n Rydberg time-of-flight spectroscopy of CH bond fission in acrolein dissociated at 193 nm  

E-Print Network [OSTI]

H-atom high-n Rydberg time-of-flight spectroscopy of C­H bond fission in acrolein dissociated-atom velocity distribution from one- and multiple-photon dissociation processes in acrolein following excitation at 193 nm. The one-photon H-atom signal is dominated by primary C­H bond fission in acrolein. We compare

Butler, Laurie J.

251

Beyond the single-atom response in absorption lineshapes: Probing a dense, laser-dressed helium gas with attosecond pulse trains  

E-Print Network [OSTI]

We investigate the absorption line shapes of laser-dressed atoms beyond the single-atom response, by using extreme ultraviolet (XUV) attosecond pulse trains to probe an optically thick helium target under the influence of a strong infrared (IR) field. We study the interplay between the IR-induced phase shift of the microscopic time-dependent dipole moment and the resonant-propagation-induced reshaping of the macroscopic XUV pulse. Our experimental and theoretical results show that as the optical depth increases, this interplay leads initially to a broadening of the IR-modified line shape, and subsequently to the appearance of new, narrow features in the absorption line.

Liao, Chen-Ting; Camp, Seth; Schafer, Kenneth J; Gaarde, Mette B

2015-01-01T23:59:59.000Z

252

Nitrogen Doping and Thermal Stability in HfSiOxNy Studied by Photoemission and X-ray Absorption Spectroscopy  

SciTech Connect (OSTI)

We have investigated nitrogen-doping effects into HfSiO{sub x} films on Si and their thermal stability using synchrotron-radiation photoemission and x-ray absorption spectroscopy. N 1s core-level photoemission and N K-edge absorption spectra have revealed that chemical-bonding states of N-Si{sub 3-x}O{sub x} and interstitial N{sub 2}-gas-like features are clearly observed in as-grown HfSiO{sub x}N{sub y} film and they decrease upon ultrahigh vacuum (UHV) annealing due to a thermal instability, which can be related to the device performance. Annealing-temperature dependence in Hf 4f and Si 2p photoemission spectra suggests that the Hf-silicidation temperature is effectively increased by nitrogen doping into the HfSiO{sub x} although the interfacial SiO{sub 2} layer is selectively reduced. No change in valence-band spectra upon UHV annealing suggests that crystallization of the HfSiO{sub x}N{sub y} films is also hindered by nitrogen doping into the HfSiO{sub x}.

Toyoda, Satoshi; Okabayashi, Jun; Takahashi, Haruhiko; Oshima, Masaharu; /Tokyo U.; Lee, Dong-Ick; Sun, Shiyu; sun, Steven; Pianetta, Piero A.; /SLAC, SSRL; Ando, Takashi; Fukuda, Seiichi; /SONY, Atsugi

2005-12-14T23:59:59.000Z

253

In operando observation system for electrochemical reaction by soft X-ray absorption spectroscopy with potential modulation method  

SciTech Connect (OSTI)

In order to investigate local structures of electrolytes in electrochemical reactions under the same scan rate as a typical value 100 mV/s in cyclic voltammetry (CV), we have developed an in operando observation system for electrochemical reactions by soft X-ray absorption spectroscopy (XAS) with a potential modulation method. XAS spectra of electrolytes are measured by using a transmission-type liquid flow cell with built-in electrodes. The electrode potential is swept with a scan rate of 100 mV/s at a fixed photon energy, and soft X-ray absorption coefficients at different potentials are measured at the same time. By repeating the potential modulation at each fixed photon energy, it is possible to measure XAS of electrochemical reaction at the same scan rate as in CV. We have demonstrated successful measurement of the Fe L-edge XAS spectra of aqueous iron sulfate solutions and of the change in valence of Fe ions at different potentials in the Fe redox reaction. The mechanism of these Fe redox processes is discussed by correlating the XAS results with those at different scan rates.

Nagasaka, Masanari, E-mail: nagasaka@ims.ac.jp; Kosugi, Nobuhiro [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan); The Graduate University for Advanced Studies, Myodaiji, Okazaki 444-8585 (Japan); Yuzawa, Hayato; Horigome, Toshio [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan)

2014-10-15T23:59:59.000Z

254

In-situ X-ray absorption spectroscopy analysis of capacity fade in nanoscale-LiCoO{sub 2}  

SciTech Connect (OSTI)

The local structure of nanoscale (?10–40 nm) LiCoO{sub 2} is monitored during electrochemical cycling utilizing in-situ X-ray absorption spectroscopy (XAS). The high surface area of the LiCoO{sub 2} nanoparticles not only enhances capacity fade, but also provides a large signal from the particle surface relative to the bulk. Changes in the nanoscale LiCoO{sub 2} metal-oxide bond lengths, structural disorder, and chemical state are tracked during cycling by adapting the delta mu (??) technique in complement with comprehensive extended X-ray absorption fine structure (EXAFS) modeling. For the first time, we use a ?? EXAFS method, and by comparison of the difference EXAFS spectra, extrapolate significant coordination changes and reduction of cobalt species with cycling. This combined approach suggests Li–Co site exchange at the surface of the nanoscale LiCoO{sub 2} as a likely factor in the capacity fade and irreversible losses in practical, microscale LiCoO{sub 2}. - Graphical abstract: Electrochemical cycling of Li-ion batteries has strong impact on the structure and integrity of the cathode active material particularly near the surface/electrolyte interface. In developing a new method, we have used in-situ X-ray absorption spectroscopy during electrochemical cycling of nanoscale LiCoO{sub 2} to track changes during charge and discharge and between subsequent cycles. Using difference spectra, several small changes in Co-O bond length, Co-O and Co-Co coordination, and site exchange between Co and Li sites can be tracked. These methods show promise as a new technique to better understand processes which lead to capacity fade and loss in Li-ion batteries. - Highlights: • A new method is developed to understand capacity fade in Li-ion battery cathodes. • Structural changes are tracked during Li intercalation/deintercalation of LiCoO{sub 2}. • Surface structural changes are emphasized using nanoscale-LiCoO{sub 2} and difference spectra. • Full multiple scattering calculations are used to support ?? analysis.

Patridge, Christopher J. [NRC/NRL Cooperative Research Associate, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Love, Corey T., E-mail: corey.love@nrl.navy.mil [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Swider-Lyons, Karen E. [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Twigg, Mark E. [Electronics Science and Technology Division, Code 6812, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Ramaker, David E. [Chemistry Division, Code 6189, U.S. Naval Research laboratory, Washington, DC 20375 (United States)

2013-07-15T23:59:59.000Z

255

Start | View At a Glance | Author Index 220-1 Kinetics of Rapid Redox Processes at the Mineral/Water Interface Using Quick-Scanning X-Ray Absorption Spectroscopy  

E-Print Network [OSTI]

at the Mineral/Water Interface Using Quick-Scanning X-Ray Absorption Spectroscopy (Q-XAS). See more from-situ synchrotron-based technique, quick scanning X-ray absorption spectroscopy (Q-XAS), at sub-second time scales

Sparks, Donald L.

256

Auto-oligomerization and hydration of pyrrole revealed by x-ray absorption spectroscopy  

SciTech Connect (OSTI)

Near edge x-ray absorption fine structure (NEXAFS) spectra have been measured at the carbon and nitrogen K-edges of the prototypical aromatic molecule, pyrrole, both in the gas phase and when solvated in water, and compared with spectra simulated using a combination of classical molecular dynamics and first principles density functional theory in the excited state core hole approximation. The excellent agreement enabled detailed assignments. Pyrrole is highly reactive, particularly in water, and reaction products formed by the auto-oligomerization of pyrrole are identified. The solvated spectra have been measured at two different temperatures, indicating that the final states remain largely unaffected by both hydration and temperature. This is somewhat unexpected, since the nitrogen in pyrrole can donate a hydrogen bond to water.

Advanced Light Source; Schwartz, Craig P.; Uejio, Janel S.; Duffin, Andrew M.; England, Alice H.; Prendergast, David; Saykally, Richard J

2009-05-29T23:59:59.000Z

257

Magnetic-dipolar-mode Fano resonances for microwave spectroscopy of high absorption matter  

E-Print Network [OSTI]

Study of interaction between high absorption matter and microwave radiated energy is a subject of great importance. Especially, this concerns microwave spectroscopic characterization of biological liquids. Use of effective testing methods to obtain information about physical properties of different liquids on the molecular level is one of the most important problems in biophysics. However, the standard methods based on the microwave resonant techniques are not sufficiently suitable for biological liquids because the resonance peak in a resonator with high-loss liquids is so broad that the material parameters cannot be measured correctly. Although molecular vibrations of biomolecules may have microwave frequencies, it is not thought that such resonant coupling is significant due to their low energy compared with thermal energy and the strongly dampening aqueous environment. This paper presents an innovative microwave sensing technique for different types of lossy materials, including biological liquids. The te...

Vaisman, G; Shavit, R

2015-01-01T23:59:59.000Z

258

Dielectric spectroscopy at the nanoscale by atomic force microscopy: A simple model linking materials properties and experimental response  

SciTech Connect (OSTI)

The use of an atomic force microscope for studying molecular dynamics through dielectric spectroscopy with spatial resolution in the nanometer scale is a recently developed approach. However, difficulties in the quantitative connection of the obtained data and the material dielectric properties, namely, frequency dependent dielectric permittivity, have limited its application. In this work, we develop a simple electrical model based on physically meaningful parameters to connect the atomic force microscopy (AFM) based dielectric spectroscopy experimental results with the material dielectric properties. We have tested the accuracy of the model and analyzed the relevance of the forces arising from the electrical interaction with the AFM probe cantilever. In this way, by using this model, it is now possible to obtain quantitative information of the local dielectric material properties in a broad frequency range. Furthermore, it is also possible to determine the experimental setup providing the best sensitivity in the detected signal.

Miccio, Luis A., E-mail: luisalejandro-miccio@ehu.es; Colmenero, Juan [Centro de Física de Materiales (CSIC-UPV/EHU), P. M. de Lardizabal 5, 20018 San Sebastián (Spain); Donostia International Physics Center, P. M. de Lardizabal 4, 20018 San Sebastián (Spain); Departamento de Física de Materiales (UPV/EHU), 20080 San Sebastián (Spain); Kummali, Mohammed M.; Alegría, Ángel [Centro de Física de Materiales (CSIC-UPV/EHU), P. M. de Lardizabal 5, 20018 San Sebastián (Spain); Departamento de Física de Materiales (UPV/EHU), 20080 San Sebastián (Spain); Schwartz, Gustavo A. [Centro de Física de Materiales (CSIC-UPV/EHU), P. M. de Lardizabal 5, 20018 San Sebastián (Spain); Donostia International Physics Center, P. M. de Lardizabal 4, 20018 San Sebastián (Spain)

2014-05-14T23:59:59.000Z

259

Iron near absorption edge X-ray spectroscopy at aqueous-membrane interfaces  

SciTech Connect (OSTI)

Employing synchrotron X-ray scattering, we systematically determine the absorption near-edge spectra (XANES) of iron in its ferrous (Fe2+) and ferric (Fe3+) states both as ions in aqueous solutions and as they bind to form a single layer to anionic templates that consist of carboxyl or phosphate groups at aqueous/vapor interfaces. While the XANES of bulk iron ions show that the electronic state and coordination of iron complexes in the bulk are isotropic, the interfacial bound ions show a signature of a broken inversion-symmetry environment. The XANES of Fe2+ and Fe3+ in the bulk possess distinct profiles however, upon binding they practically exhibit similar patterns. This indicates that both bound ions settle into a stable electronic and coordination configuration with an effective fractional valence (for example, Fe[2+nu]+, 0 < nu < 1) at charged organic templates. Such two dimensional properties may render interfacial iron, abundant in living organisms, a more efficient and versatile catalytic behavior.

Wang, Wenjie; Kuzmenko, Ivan; Vaknin, David

2014-01-01T23:59:59.000Z

260

Coupling MD Simulations and X-ray Absorption Spectroscopy to Study Ions in Solution  

SciTech Connect (OSTI)

The structure of ionic solutions is a key-point in understanding physicochemical properties of electrolyte solutions. Among the reduced number of experimental techniques which can supply direct information on the ion environment, X-ray Absorption techniques (XAS) have gained importance during the last decades although they are not free of difficulties associated to the data analysis leading to provide reliable structures. Computer simulations of ions in solution is a theoretical alternative to provide information on the solvation structure. Thus, the use of computational chemistry can increase the understanding of these systems although an accurate description of ionic solvation phenomena represents nowadays a significant challenge to theoretical chemistry. We present: (a) the assignment of features in the XANES spectrum to well defined structural motif in the ion environment, (b) MD-based evaluation of EXAFS parameters used in the fitting procedure to make easier the structural resolution, and (c) the use of the agreement between experimental and simulated XANES spectra to help in the choice of a given intermolecular potential for Computer Simulations. Chemical problems examined are: (a) the identification of the second hydration shell in dilute aqueous solutions of highly-charged cations, such as Cr{sup 3+}, Rh{sup 3+}, Ir{sup 3+}, (b) the invisibility by XAS of certain structures characterized by Computer Simulations but exhibiting high dynamical behavior and (c) the solvation of Br{sup -} in acetonitrile.

Marcos, E. Sanchez; Beret, E. C.; Martinez, J. M.; Pappalardo, R. R. [University of Seville, Dept. of Physical Chemistry (Spain); Ayala, R.; Munoz-Paez, A. [University of Seville, CSIC-ICMSE. Dept. of Inorganic Chemistry (Spain)

2007-11-29T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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261

Development of Palladium L-Edge X-Ray Absorption Spectroscopy And Its Application for Chloropalladium Complexes  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) is a synchrotron-based experimental technique that provides information about geometric and electronic structures of transition metal complexes. Combination of metal L-edge and ligand K-edge XAS has the potential to define the complete experimental ground state electronic structures for metal complexes with unoccupied d manifolds. We developed a quantitative treatment for Pd L-edge spectroscopy on the basis of the well-established chlorine K-edge XAS for a series of chloropalladium complexes that are pre-catalysts in various organic transformations. We found that Pd-Cl bonds are highly covalent, such as 24 {+-} 2%, 34 {+-} 3%, and 48 {+-} 4% chloride 3p character for each Pd-Cl bond in [PdCl{sub 4}]{sup 2-}, [PdCl{sub 6}]{sup 2-}, and PdCl{sub 2}, respectively. Pd(2p {yields} 4d) transition dipole integrals of 20.8 (SSRL)/16.9 (ALS) eV and 14.1 (SSRL)/11.9 (ALS) eV were determined using various combinations of L-edges for Pd(II) and Pd(IV), respectively. Application of metal-ligand covalency and transition dipole integrals were demonstrated for the example of bridging chloride ligands in PdCl{sub 2}. Our work lays the foundation for extending the quantitative treatment to other catalytically important ligands, such as phosphine, phosphite, olefin, amine, and alkyl in order to correlate the electronic structures of palladium complexes with their catalytic activity.

Boysen, R.B.; Szilagyi, R.K.

2009-05-12T23:59:59.000Z

262

An x-ray absorption near-edge spectroscopy study of the oxidation state of chromium in electrodeposited oxide films.  

SciTech Connect (OSTI)

The oxidation state of chromium incorporated into simulated corrosion films of nickel has been investigated using the technique of 'in situ' X-ray Absorption Near-Edge Spectroscopy (XANES). The films were prepared by electrochemical deposition of the appropriate oxide (hydroxide) onto a graphite substrate. Cathodic deposition from a 0.01 M Cr(NO{sub 3}){sub 3} solution at constant current results in a Cr{sup 3+} oxide (hydroxide) film. Deposition from a 0.01 M K{sub 2}CrO{sub 4} solution produces a film which is predominantly Cr{sup 3+} but with some Cr{sup 6+}. This material is air-sensitive and the ratio of Cr{sup 6+} to Cr{sup 3+} increases with time of exposure to ambient. Cathodic codeposition of Cr{sup 3+} with nickel hydroxide from Cr(NO{sub 3}){sub 3} solution results in a film with chromium in the 3+ oxidation state. On the other hand, cathodic codeposition from a Cr{sup 6+} solution of K{sub 2}CrO{sub 4} with nickel hydroxide leads to a film containing Cr{sup 6+}.

Balasubramanian, M.; Melendres, C. A.; Chemical Engineering

1999-01-01T23:59:59.000Z

263

Near-infrared photoluminescence and ligand K-edge x-ray absorption spectroscopies of AnO2Cl42-(An:u, NP, Pu)  

SciTech Connect (OSTI)

We have used photoluminescence and X-ray absorption spectroscopies to investigate electronic structures and metal-ligand bonding of a series of An02CI/ ' (An = U, Np, Pu) compounds. Specifically, we will discuss time-resolved near-infrared emission spectra of crystalline Cs2U(An)02C14 (An = Np and Pu) both at 23 K and 75 K, as well as chlorine Kedge X-ray absorption spectra ofCs2An02CI4 (An = U, Np).

Wilkerson, Marianne P [Los Alamos National Laboratory; Berg, John M [Los Alamos National Laboratory; Clark, David L [Los Alamos National Laboratory; Conradson, Steven D [Los Alamos National Laboratory; Hobart, David E [Los Alamos National Laboratory; Kozimor, Stosh A [Los Alamos National Laboratory; Scott, Brian L [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

264

Mid- and Far-Infrared Reflection/Absorption Spectroscopy (IRAS) Studies of NO on Rh Single Crystal Surfaces  

SciTech Connect (OSTI)

The NO/CO reaction over Rh metal in automobile catalytic converters is critical to the control of emissions of these pollutant molecules. As part of a program to determine the elementary mechanism(s) of this reaction, we have been performing mid- and far-infrared reflection/absorption spectroscopic (IRAS) measurements of the adsorption and co-adsorption and co-adsorption of NO and CO on Rh single crystal surfaces. Of particular interest is the low-frequency range of the IRAS spectra where we hoped to observe features due to metal-N stretching and/or bending vibrational motions. In particular, we hoped to obtain information regarding the site-requirements for the dissociation of the NO molecule on various Rh single crystal surfaces. An important result from our earlier work is that the selectivity of the reaction for the two nitrogen-containing products, N2 and N2O, is a strong function of the Rh surface structure. On the basis of ancillary data, we suggested that the location of adsorbed NO and N-atoms (formed from dissociation of adsorbed NO) on various Rh surfaces could, perhaps account for the selectivity differences.

Peden, Charles HF; He, Ting; Pilling, M.; Hirschmugl, Carol J.; Gardner, P.

2001-02-01T23:59:59.000Z

265

Conduction-band electronic states of YbInCu{sub 4} studied by photoemission and soft x-ray absorption spectroscopies  

SciTech Connect (OSTI)

We have studied conduction-band (CB) electronic states of a typical valence-transition compound YbInCu{sub 4} by means of temperature-dependent hard x-ray photoemission spectroscopy (HX-PES) of the Cu 2p{sub 3/2} and In 3d{sub 5/2} core states taken at h{nu}=5.95 keV, soft x-ray absorption spectroscopy (XAS) of the Cu 2p{sub 3/2} core absorption region around h{nu}{approx}935 eV, and soft x-ray photoemission spectroscopy (SX-PES) of the valence band at the Cu 2p{sub 3/2} absorption edge of h{nu}=933.0 eV. With decreasing temperature below the valence transition at T{sub V}=42 K, we have found that (1) the Cu 2p{sub 3/2} and In 3d{sub 5/2} peaks in the HX-PES spectra exhibit the energy shift toward the lower binding-energy side by {approx}40 and {approx}30 meV, respectively, (2) an energy position of the Cu 2p{sub 3/2} main absorption peak in the XAS spectrum is shifted toward higher photon-energy side by {approx}100 meV, with an appearance of a shoulder structure below the Cu 2p{sub 3/2} main absorption peak, and (3) an intensity of the Cu L{sub 3}VV Auger spectrum is abruptly enhanced. These experimental results suggest that the Fermi level of the CB-derived density of states is shifted toward the lower binding-energy side. We have described the valence transition in YbInCu{sub 4} in terms of the charge transfer from the CB to Yb 4f states.

Utsumi, Yuki; Kurihara, Hidenao; Maso, Hiroyuki; Tobimatsu, Komei [Graduate School of Science, Hiroshima University, Higashi-Hiroshima 739-8526 (Japan); Sato, Hitoshi; Shimada, Kenya; Namatame, Hirofumi [Hiroshima Synchrotron Radiation Center, Hiroshima University, Higashi-Hiroshima 739-0046 (Japan); Hiraoka, Koichi [Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577 (Japan); Kojima, Kenichi [Graduate School of Integrated Arts and Sciences, Hiroshima University, Higashi-Hiroshima 739-8521 (Japan); Ohkochi, Takuo; Fujimori, Shin-ichi; Takeda, Yukiharu; Saitoh, Yuji [Synchrotron Radiation Research Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Mimura, Kojiro [Graduate School of Engineering, Osaka Prefecture University, Sakai 599-8531 (Japan); Ueda, Shigenori; Yamashita, Yoshiyuki; Yoshikawa, Hideki; Kobayashi, Keisuke [NIMS Beamline Station at SPring-8, National Institute for Materials Science, Hyogo 679-5148 (Japan); Oguchi, Tamio [ISIR, Osaka University, Ibaraki 567-0047 (Japan); Taniguchi, Masaki [Graduate School of Science, Hiroshima University, Higashi-Hiroshima 739-8526 (Japan); Hiroshima Synchrotron Radiation Center, Hiroshima University, Higashi-Hiroshima 739-0046 (Japan)

2011-09-15T23:59:59.000Z

266

Characterization of gold nanoparticle films: Rutherford backscattering spectroscopy, scanning electron microscopy with image analysis, and atomic force microscopy  

SciTech Connect (OSTI)

Gold nanoparticle films are of interest in several branches of science and technology, and accurate sample characterization is needed but technically demanding. We prepared such films by DC magnetron sputtering and recorded their mass thickness by Rutherford backscattering spectroscopy. The geometric thickness d{sub g}—from the substrate to the tops of the nanoparticles—was obtained by scanning electron microscopy (SEM) combined with image analysis as well as by atomic force microscopy (AFM). The various techniques yielded an internally consistent characterization of the films. In particular, very similar results for d{sub g} were obtained by SEM with image analysis and by AFM.

Lansåker, Pia C., E-mail: pia.lansaker@angstrom.uu.se; Niklasson, Gunnar A.; Granqvist, Claes G. [Department of Engineering Sciences, The Ångström Laboratory, Uppsala University, P. O. Box 534, SE-751 21 Uppsala (Sweden); Hallén, Anders [Royal Institute of Technology, KTH-ICT, Elektrum 229, Kista, SE-164 40 Stockholm (Sweden)

2014-10-15T23:59:59.000Z

267

Limits on the temporal variation of the fine structure constant, quark masses and strong interaction from quasar absorption spectra and atomic clock experiments  

E-Print Network [OSTI]

We perform calculations of the dependence of nuclear magnetic moments on quark masses and obtain limits on the variation of $(m_q/\\Lambda_{QCD})$ from recent measurements of hydrogen hyperfine (21 cm) and molecular rotational transitions in quasar absorption systems, atomic clock experiments with hyperfine transitions in H, Rb, Cs, Yb$^+$, Hg$^+$ and optical transition in Hg$^+$. Experiments with Cd$^+$, deuterium/hydrogen, molecular SF$_6$ and Zeeman transitions in $^3$He/Xe are also discussed.

V. V. Flambaum; D. B. Leinweber; A. W. Thomas; R. D. Young

2004-02-10T23:59:59.000Z

268

Dissimilar behavior of technetium and rhenium in borosilicate waste glass as determined by X-ray absorption spectroscopy  

E-Print Network [OSTI]

by X-ray fluorescence (XRF) spectroscopy with a relativeuncertainty of 4%. XRF analyses utilized an ARL 9400X-ray fluorescence spectrometer with XRF composition values

Lukens, Wayne W.; McKeown, David A.; Buechele, Andrew C.; Muller, Isabelle S.; Shuh, David K.; Pegg, Ian L.

2006-01-01T23:59:59.000Z

269

Infrared reflection absorption spectroscopy studies of CO adsorption on titania thin films and gold clusters supported on titania  

E-Print Network [OSTI]

absorptions at 2180cm?¹ and 2110cm?¹. The 2180cm?¹ peak is assigned to CO adsorbed on Ti?? sites The absorption at 2110cm?¹ appears to have at least two component peaks that may be from CO adsorbed on top of gold clusters and CO adsorbed at Au-TiO? interface...

White, Kevin Rodney

1999-01-01T23:59:59.000Z

270

Spin noise spectroscopy to probe quantum states of ultracold fermionic atom gases  

SciTech Connect (OSTI)

We theoretically demonstrate that optical measurements of electron spin noise can be a spectroscopic probe of the entangled quantum states of ultracold fermionic atom gases and unambiguously reveal the detailed nature of the underlying interatomic correlations. Different models of the effective interatomic interactions predict entirely new sets of resonances in the spin noise spectrum. Once the correct effective interatomic interaction model is identified, the detailed noise line shapes of the spin noise can be used to constrain this model. We estimate the magnitude of spin noise signals expected in ultracold fermionic atom gases via noise measurements in classical alkali vapors, which demonstrate the feasibility of this approach.

Mihaila, Bogdan; Blagoev, Krastan B.; Smith, Darryl L. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Crooker, Scott A.; Rickel, Dwight G. [National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Littlewood, Peter B. [Cavendish Laboratory, Madingley Road, Cambridge CB3 0HE (United Kingdom)

2006-12-15T23:59:59.000Z

271

Spatial Variability in the Ratio of Interstellar Atomic Deuterium to Hydrogen. I. Observations toward delta Orionis by the Interstellar Medium Absorption Profile Spectrograph  

E-Print Network [OSTI]

Studies of the abundances of deuterium in different astrophysical sites are of fundamental importance to answering the question about how much deuterium was produced during big bang nucleosynthesis and what fraction of it was destroyed later. With this in mind, we used the Interstellar Medium Absorption Profile Spectrograph (IMAPS) on the ORFEUS-SPAS II mission to observe at a wavelength resolution of 4 km/s (FWHM) the L-delta and L-epsilon absorption features produced by interstellar atomic deuterium in the spectrum of delta Ori A. A chi-square analysis indicated that 0.96 atomic ratio of D to H, we measured the L-alpha absorption features in 57 spectra of delta Ori in the IUE archive. From our measurement of N(H I)= 1.56e20 cm^{-2}, we found that N(D I)/N(H I)= 7.4(+1.9,-1.3)e-6 (90% confidence). Our result for D/H contrasts with the more general finding along other lines of sight that D/H is approximately 1.5e-5. The underabundance of D toward delta Ori A is not accompanied by an overabundance of N or O relative to H, as one might expect if the gas were subjected to more stellar processing than usual.

Edward B. Jenkins; Todd M. Tripp; Przemyslaw R. Wozniak; Ulysses J. Sofia; G. Sonneborn

1999-01-28T23:59:59.000Z

272

Femtosecond laser-induced modification of potassium-magnesium silicate glasses: An analysis of structural changes by near edge x-ray absorption spectroscopy  

SciTech Connect (OSTI)

The effects of femtosecond laser pulse irradiation on the glass structure of alkaline silicate glasses were investigated by x-ray absorption near edge structure spectroscopy using the beamline of the Physikalisch-Technische Bundesanstalt at the electron synchrotron BESSY II in Berlin (Germany) by analyzing the magnesium K-edge absorption peak for different laser fluences. The application of fluences above the material modification threshold (2.1 J/cm{sup 2}) leads to a characteristic shift of {approx}1.0 eV in the K-edge revealing a reduced ({approx}3%) mean magnesium bond length to the ligated oxygen ions (Mg-O) along with a reduced average coordination number of the Mg ions.

Seuthe, T.; Eberstein, M. [Fraunhofer-Institut fuer Keramische Technologien und Systeme (IKTS), Winterbergstrasse 28, 01277 Dresden (Germany); Hoefner, M.; Eichler, H. J.; Grehn, M. [Technische Universitaet Berlin, Institut fuer Optik und Atomare Physik, Strasse des 17. Juni 135, 10623 Berlin (Germany); Reinhardt, F. [Physikalisch-Technische Bundesanstalt (PTB), Abbestr. 2-12, 10587 Berlin (Germany); Tsai, W. J. [ITRI South, Industrial Technology Research Institute, 8 Gongyan Rd., Liu-jia District, Tainan City 73445, Taiwan (China); Bonse, J. [BAM Bundesanstalt fuer Materialforschung und - pruefung, Unter den Eichen 87, 12205 Berlin (Germany)

2012-05-28T23:59:59.000Z

273

The Radio to Infrared Emission of Very High Redshift Gamma-Ray Bursts: Probing Early Star Formation through Molecular and Atomic Absorption Lines  

E-Print Network [OSTI]

We evaluate the broadband afterglow emission of very high redshift gamma-ray bursts (GRBs) using standard relativistic blastwave models with both forward and reverse shock components. For a broad range of parameters, a generic property for GRBs at redshifts $z \\sim$ 5--30 is that the emission peaks in the millimeter to far-infrared bands with milli-Jansky flux levels, first at a few hours after the burst due to the reverse shock, and then again for several days afterwards with somewhat lower flux due to the forward shock. The radio, submillimeter and infrared continuum emission should be readily detectable out to $z \\ga 30$ by the Atacama Large Millimeter Array (ALMA), Extended Very Large Array (EVLA), Square Kilometer Array (SKA) and other facilities. For relatively bright bursts, spectroscopic measurements of molecular and atomic absorption lines due to ambient protostellar gas may be possible. Utilizing models of primordial protostellar clouds, we show that under certain conditions, appreciable absorption may be caused by HD rotational transitions even in metal-free environments. After sufficient metal enrichment, absorption from CO rotational transitions and [OI] fine-structure transitions can also become strong. With appropriate observing strategies in combination with optical telescopes, ALMA and/or SKA may be able to detect such lines, offering a unique probe of physical conditions in individual Pop III and early Pop II star forming regions. We also remark on potential near-infrared absorption features due to electronic transitions of H$_2$.

Susumu Inoue; Kazuyuki Omukai; Benedetta Ciardi

2007-07-14T23:59:59.000Z

274

Simultaneous measurement of nitrogen and hydrogen dissociation from vacuum ultraviolet self-absorption spectroscopy in a developing low temperature plasma at atmospheric pressure  

SciTech Connect (OSTI)

We demonstrate a method for determining the dissociation density of N and H atoms present in a developing low temperature plasma, based on the emission and self-absorption of vacuum ultraviolet radiation produced from the plasma. Spark plasmas are produced via pulsed discharge in N{sub 2}/H{sub 2} mixtures at atmospheric pressure, where information on the dissociated densities of the constituent gas molecules is desired without employing invasive diagnostic techniques. By analyzing the self-absorption line profile of 121.5 nm Lyman-{alpha} H radiation emitted within the first {approx}1.0 mm of plasma near the anode tip, a peak dissociated H atom concentration of 5.6 Multiplication-Sign 10{sup 17} cm{sup -3} was observed {approx}100 ns into spark formation, with an estimated electron density of 2.65 Multiplication-Sign 10{sup 18} cm{sup -3} determined from Stark broadening. Similarly, simultaneous line fitting of the N 120.0/124.3 nm emission profiles revealed a peak dissociated N atom concentration of 3.8 Multiplication-Sign 10{sup 17} cm{sup -3} during the same discharge period.

Laity, George; Fierro, Andrew; Dickens, James; Neuber, Andreas [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering and Department of Physics, Texas Tech University, Lubbock, Texas 79409 (United States)] [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering and Department of Physics, Texas Tech University, Lubbock, Texas 79409 (United States); Frank, Klaus [Erlangen Centre for Astroparticle Physics, Department of Physics, Friedrich-Alexander University at Erlangen - Nuernberg, 91058 Erlangen (Germany)] [Erlangen Centre for Astroparticle Physics, Department of Physics, Friedrich-Alexander University at Erlangen - Nuernberg, 91058 Erlangen (Germany)

2013-05-06T23:59:59.000Z

275

Quantitative broadband absorption and scattering spectroscopy in turbid media by combined frequency-domain and steady state methodologies  

DOE Patents [OSTI]

A technique for measuring broadband near-infrared absorption spectra of turbid media that uses a combination of frequency-domain and steady-state reflectance methods. Most of the wavelength coverage is provided by a white-light steady-state measurement, whereas the frequency-domain data are acquired at a few selected wavelengths. Coefficients of absorption and reduced scattering derived from the frequency-domain data are used to calibrate the intensity of the steady-state measurements and to determine the reduced scattering coefficient at all wavelengths in the spectral window of interest. The absorption coefficient spectrum is determined by comparing the steady-state reflectance values with the predictions of diffusion theory, wavelength by wavelength. Absorption spectra of a turbid phantom and of human breast tissue in vivo, derived with the combined frequency-domain and steady-state technique, agree well with expected reference values.

Tromberg, Bruce J. (Irvine, CA); Berger, Andrew J. (Rochester, NY); Cerussi, Albert E. (Lake Forest, CA); Bevilacqua, Frederic (Costa Mesa, CA); Jakubowski, Dorota (Irvine, CA)

2008-09-23T23:59:59.000Z

276

An experimental set-up to apply polarization modulation to infrared reflection absorption spectroscopy for improved in situ studies of atmospheric corrosion processes  

SciTech Connect (OSTI)

A new set-up for improved monitoring of atmospheric corrosion processes in situ and in real-time is presented. To characterize chemical structures of thin films on metal surfaces surface sensitive analytical techniques are required. One possible technique is Infrared Reflection Absorption Spectroscopy (IRRAS) which has become an established method to investigate surface corrosion films of thicknesses less than 200 nm. However, there are limitations related to the sensitivity of these measurements, in case of investigating ultrathin films or absorption bands of interest, surface species are superimposed by atmospheric background absorption, which changes during in situ measurements in ambient atmospheres. These difficulties of in situ surface reflection measurements can be eliminated by availing the polarization selectivity of adsorbed surface species. At grazing angles of incidence the absorption of p-polarized infrared radiation by thin surface films on metals is enhanced, while the absorption of s-polarized light by this film is nearly zero. This different behavior of the polarization properties leads to strong selection rules at the surface and can therefore be used to identify molecules adsorbed on metal surfaces. Polarization Modulation (PM) of the infrared (IR) light takes advantage of this disparity of polarization on sample surfaces and in combination with IRRAS yielding a very sensitive and surface-selective method for obtaining IR spectra of ultra-thin films on metal surfaces. An already existing in situ IRRAS/Quartz Crystal Microbalance weathering cell was combined with PM and evaluated according to its applicability to study in situ atmospheric corrosion processes. First real-time measurements on silver samples exposed to different atmospheres were performed showing the advantage of PM-IRRAS compared to conventional IRRAS for such investigations.

Wiesinger, R. [Institute of Science and Technology in Art, Academy of Fine Arts, 1010 Vienna (Austria); Schade, U. [Helmholtz-Zentrum für Materialien und Energy GmbH, Elektronenspeicherring BESSY II, 12489 Berlin (Germany); Kleber, Ch. [Centre for Electrochemical Surface Technology, 2700 Wiener Neustadt (Austria); Schreiner, M. [Institute of Science and Technology in Art, Academy of Fine Arts, 1010 Vienna (Austria); Institute for Chemical Technologies and Analytics, Vienna University of Technology, 1060 Vienna (Austria)

2014-06-15T23:59:59.000Z

277

Spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus Tom Fletcher,Future |CarlosSpeakersSpectroscopy Print In

278

Determination of the concentrations of magnesium and aluminum in alloys by laser produced atomic emission spectroscopy  

E-Print Network [OSTI]

in forensic studies. It would be able to analyze the residue left at a crime scene, or analyze the layers of paint on the ceiling of the Sistine Chapel. ~ It can be used to analyze the ratio of ionic to atomic species ejected by a sample that has been... density per pulse at the focus point of the laser are important. A "short" laser pulse will eject a relatively small amount of material. However, pulses that have a duration on the order of a millisecond can dig deep holes into the sample. In OES a...

Ashe, William Monroe

1997-01-01T23:59:59.000Z

279

Quantitative study of spin noise spectroscopy in a classical gas of {sup 41}K atoms  

SciTech Connect (OSTI)

We present a general derivation of the electron spin noise power spectrum in alkali gases as measured by optical Faraday rotation, which applies to both classical gases at high temperatures as well as ultracold quantum gases. We show that the spin-noise power spectrum is determined by an electron spin-spin correlation function, and we find that measurements of the spin-noise power spectra for a classical gas of {sup 41}K atoms are in good agreement with the predicted values. Experimental and theoretical spin noise spectra are directly and quantitatively compared in both longitudinal and transverse magnetic fields up to the high magnetic-field regime (where Zeeman energies exceed the intrinsic hyperfine energy splitting of the {sup 41}K ground state)

Mihaila, Bogdan [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Crooker, Scott A.; Rickel, Dwight G. [National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Blagoev, Krastan B.; Smith, Darryl L. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Littlewood, Peter B. [Cavendish Laboratory, Madingley Road, Cambridge CB3 0HE (United Kingdom)

2006-10-15T23:59:59.000Z

280

Measuring Hydroxyl Radicals during the Oxidation of Methane, Ethane, Ethylene, and Acetylene in a Shock Tube Using UV Absorption Spectroscopy  

E-Print Network [OSTI]

transition region. Experiments have been performed in the shock-tube facility at Texas A&M University using this OH absorption diagnostic. A calibration mixture of stoichiometric H2/O2 diluted in 98% argon by volume was tested initially and compared with a...

Aul, Christopher J

2013-05-02T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Time-resolved x-ray absorption spectroscopy of photoinduced insulator-metal transition in a colossal magnetoresistive manganite  

SciTech Connect (OSTI)

We studied the ultrafast insulator-metal transition in a manganite by means of picosecond X-ray absorption at the O K- and Mn L-edges, probing photoinduced changes in O-2p and Mn-3d electronic states near the Fermi level.

Rini, M.; Tobey, R.; Wall, S.; Zhu, Y.; Tomioka, Y.; Tokura, Y.; Cavalleri, A.; Schoenlein, R.W.

2008-08-01T23:59:59.000Z

282

Development of ultralow energy (1–10 eV) ion scattering spectrometry coupled with reflection absorption infrared spectroscopy and temperature programmed desorption for the investigation of molecular solids  

SciTech Connect (OSTI)

Extremely surface specific information, limited to the first atomic layer of molecular surfaces, is essential to understand the chemistry and physics in upper atmospheric and interstellar environments. Ultra low energy ion scattering in the 1–10 eV window with mass selected ions can reveal extremely surface specific information which when coupled with reflection absorption infrared (RAIR) and temperature programmed desorption (TPD) spectroscopies, diverse chemical and physical properties of molecular species at surfaces could be derived. These experiments have to be performed at cryogenic temperatures and at ultra high vacuum conditions without the possibility of collisions of neutrals and background deposition in view of the poor ion intensities and consequent need for longer exposure times. Here we combine a highly optimized low energy ion optical system designed for such studies coupled with RAIR and TPD and its initial characterization. Despite the ultralow collision energies and long ion path lengths employed, the ion intensities at 1 eV have been significant to collect a scattered ion spectrum of 1000 counts/s for mass selected CH{sub 2}{sup +}.

Bag, Soumabha; Bhuin, Radha Gobinda; Methikkalam, Rabin Rajan J.; Pradeep, T., E-mail: pradeep@iitm.ac.in [DST Unit of Nanoscience (DST UNS), Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036 (India); Kephart, Luke; Walker, Jeff; Kuchta, Kevin; Martin, Dave; Wei, Jian [Extrel CMS, LLC, 575 Epsilon Drive, Pittsburgh, Pennsylvania 15238 (United States)] [Extrel CMS, LLC, 575 Epsilon Drive, Pittsburgh, Pennsylvania 15238 (United States)

2014-01-15T23:59:59.000Z

283

Intersublevel optical transitions in InAs nanocrystals probed by photoinduced absorption spectroscopy: The role of thermal activation  

E-Print Network [OSTI]

of well-defined envelope-state symmetry relations while the second attributes the thermal activation spectroscopy: The role of thermal activation D. Krapf,1 S.-H. Kan,2 U. Banin,2 O. Millo,3 and A. Sa'ar1,3, * 1 have found that the valence intersublevel transitions are thermally activated and cannot be observed

Krapf, Diego

285

The Journey from Classical to Quantum Thinking: An Analysis of Student Understanding Through the Lens of Atomic Spectra  

E-Print Network [OSTI]

certain  aspects  of  atomic  absorption  of  light  in  About  Atomic  Absorption  of  Light……………..…………. …  71  questions  about  atomic   absorption  and  emission  of  

Rao, Sandhya Kolla

2012-01-01T23:59:59.000Z

286

7 -ATOMIC PROCESSES Atomic processes can be  

E-Print Network [OSTI]

1 7 - ATOMIC PROCESSES Atomic processes can be: 1. Scattering 2. Absorption/Thermal Emission scattering, although the results won't change much when this condition is relaxed. Absorption/Thermal Emission Free-free (continuum) ("Bremsstrahlung") Emission/Absorption #12;2 Bound-Bound & Bound

Sitko, Michael L.

287

7 -ATOMIC PROCESSES Atomic processes can be  

E-Print Network [OSTI]

1 7 - ATOMIC PROCESSES Atomic processes can be: 1. Scattering 2. Absorption/Thermal Emission scattering, although the results won't change much when this condition is relaxed. #12;2 Absorption/Thermal Emission Free-free (continuum) ("Bremsstrahlung") Emission/Absorption Bound-Bound & Bound-Free Processes

Sitko, Michael L.

288

Investigation of Temperature Dependent Optical Modes in GexAs35-xSe65 Thin Films: Structure Specific Raman, FIR and Optical Absorption Spectroscopy  

E-Print Network [OSTI]

In this article, we present a comprehensive study of temperature and composition dependent Raman spectroscopy of GexAs35-xSe65 thin films to understand different structural units responsible for optical properties. Strikingly, our experimental results uncover the ratio of GeSe4/2 tetrahedral and AsSe3/2 pyramidal units in GexAs35-xSe65 thin films and their linear scaling relationship with temperature and x. An important notable outcome of our study is the formation of Se8 rings at lower temperatures. Our experimental results further provide interesting optical features, thermally and compositionally tunable optical absorption spectra. Detailed structure specific FIR data at room temperature also present direct information on the structural units in consistent with Raman data. We foresee that our studies are useful in determining the lightinduced response of these films and also for their potential applications in optics and optoelectronics.

Khan, Pritam; Joshy, Abin; Sathe, Vasant; Deshpande, Uday; Adarsh, K V

2015-01-01T23:59:59.000Z

289

Setup for in situ investigation of gases and gas/solid interfaces by soft x-ray emission and absorption spectroscopy  

SciTech Connect (OSTI)

We present a novel gas cell designed to study the electronic structure of gases and gas/solid interfaces using soft x-ray emission and absorption spectroscopies. In this cell, the sample gas is separated from the vacuum of the analysis chamber by a thin window membrane, allowing in situ measurements under atmospheric pressure. The temperature of the gas can be regulated from room temperature up to approximately 600?°C. To avoid beam damage, a constant mass flow can be maintained to continuously refresh the gaseous sample. Furthermore, the gas cell provides space for solid-state samples, allowing to study the gas/solid interface for surface catalytic reactions at elevated temperatures. To demonstrate the capabilities of the cell, we have investigated a TiO{sub 2} sample behind a mixture of N{sub 2} and He gas at atmospheric pressure.

Benkert, A., E-mail: andreas.benkert@kit.edu, E-mail: l.weinhardt@kit.edu [Institute for Photon Science and Synchrotron Radiation, Karlsruhe Institute of Technology (KIT), Hermann-v.-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Gemeinschaftslabor für Nanoanalytik, Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe (Germany); Blum, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Meyer, F. [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany)] [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Wilks, R. G. [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany)] [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Yang, W. [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)] [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Bär, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Insitut für Physik und Chemie, Brandenburgische Technische Universität Cottbus-Senftenberg, Konrad-Wachsmann-Allee 1, 03046 Cottbus (Germany); and others

2014-01-15T23:59:59.000Z

290

Study of hard disk and slider surfaces using X-ray photoemission electron microscopy and near-edge X-ray absorption fine structure spectroscopy  

SciTech Connect (OSTI)

X-ray Photo Emission Electron Microscopy (X-PEEM) and Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy were applied to study the properties of amorphous hard carbon overcoats on disks and sliders, and the properties of the lubricant. The modification of lubricants after performing thermal desorption studies was measured by NEXAFS, and the results are compared to the thermal desorption data. The study of lubricant degradation in wear tracks is described. Sliders were investigated before and after wear test, and the modification of the slider coating as well as the transfer of lubricant to the slider was studied. The studies show that the lubricant is altered chemically during the wear. Fluorine is removed and carboxyl groups are formed.

Anders, S.; Stammler, T. [Lawrence Berkeley National lab., CA (United States). Advanced Light Source Div.; Bhatia, C.S. [SSD/IBM, San Jose, CA (United States); Stoehr, J. [IBM Research Div., San Jose, CA (United States). Almaden Research Center; Fong, W.; Chen, C.Y.; Bogy, D.B. [Univ. of California, Berkeley, CA (United States)

1998-04-01T23:59:59.000Z

291

Tunneling spectroscopy of superconducting MoN and NbTiN grown by atomic layer deposition  

SciTech Connect (OSTI)

A tunneling spectroscopy study is presented of superconducting MoN and Nb{sub 0.8}Ti{sub 0.2}N thin films grown by atomic layer deposition (ALD). The films exhibited a superconducting gap of 2?meV and 2.4?meV, respectively, with a corresponding critical temperature of 11.5?K and 13.4?K, among the highest reported T{sub c} values achieved by the ALD technique. Tunnel junctions were obtained using a mechanical contact method with a Au tip. While the native oxides of these films provided poor tunnel barriers, high quality tunnel junctions with low zero bias conductance (below ?10%) were obtained using an artificial tunnel barrier of Al{sub 2}O{sub 3} on the film's surface grown ex situ by ALD. We find a large critical current density on the order of 4?×?10{sup 6}?A/cm{sup 2} at T?=?0.8T{sub c} for a 60?nm MoN film and demonstrate conformal coating capabilities of ALD onto high aspect ratio geometries. These results suggest that the ALD technique offers significant promise for thin film superconducting device applications.

Groll, Nickolas R., E-mail: ngroll@anl.gov; Klug, Jeffrey A.; Claus, Helmut; Pellin, Michael J.; Proslier, Thomas, E-mail: proslier@anl.gov [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Cao, Chaoyue; Becker, Nicholas G.; Zasadzinski, John F. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Physics, Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Altin, Serdar [Fen Edebiyat Fakultesi, Fizik Bolumu, Inonu Universitesi, 44280 Malatya (Turkey)

2014-03-03T23:59:59.000Z

292

Laser produced plasma diagnostics by cavity ringdown spectroscopy and applications  

SciTech Connect (OSTI)

Laser-produced plasmas have many applications for which detailed characterization of the plume is requested. Cavity ring-down spectroscopy is a versatile absorption method which provides data on the plume and its surroundings, with spatial and temporal resolution. The measured absorption line shapes contain information about angular and velocity distributions within the plume. In various plasmas we have observed molecules or metastable atoms which were not present in the emission spectra.

Milosevic, S. [Institute of Physics, Zagreb (Croatia)

2012-05-25T23:59:59.000Z

293

FINGERPRINTING INORGANIC ARSENIC AND ORGANOARSENIC COMPOUNDS IN IN SITU OIL SHALE RETORT AND PROCESS VOTERS USING A LIQUID CHROMATOGRAPH COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR  

SciTech Connect (OSTI)

Inorganic arsenic and organoarsenic compounds were speciated in seven oil shale retort and process waters, including samples from simulated, true and modified in situ processes, using a high performance liquid chromatograph automatically coupled to a graphite furnace atomic absorption detector. The molecular forms of arsenic at ppm levels (({micro}g/mL) in these waters are identified for the first time, and shown to include arsenate, methylarsonic acid and phenylarsonic acid. An arsenic-specific fingerprint chromatogram of each retort or process water studied has significant impliestions regarding those arsenical species found and those marginally detected, such as dimethylarsinic acid and the suspected carcinogen arsenite. The method demonstrated suggests future means for quantifying environmental impacts of bioactive organometal species involved in oil shale retorting technology.

Fish, Richard H.; Brinckman, Frederick E.; Jewett, Kenneth L.

1981-07-01T23:59:59.000Z

294

Note: Application of a pixel-array area detector to simultaneous single crystal x-ray diffraction and x-ray absorption spectroscopy measurements  

SciTech Connect (OSTI)

X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are two main x-ray techniques in synchrotron radiation facilities. In this Note, we present an experimental setup capable of performing simultaneous XRD and XAS measurements by the application of a pixel-array area detector. For XRD, the momentum transfer in specular diffraction was measured by scanning the X-ray energy with fixed incoming and outgoing x-ray angles. By selecting a small fixed region of the detector to collect the XRD signal, the rest of the area was available for collecting the x-ray fluorescence for XAS measurements. The simultaneous measurement of XRD and X-ray absorption near edge structure for Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film was demonstrated as a proof of principle for future time-resolved pump-probe measurements. A static sample makes it easy to maintain an accurate overlap of the X-ray spot and laser pump beam.

Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov; Brewe, Dale L.; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Chen, Jing-Sheng; Chow, G. M. [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore)] [Department of Materials Science and Engineering, National University of Singapore, 117575 Singapore (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore) [NUSNNI-Nanocore, National University of Singapore, 117411 Singapore (Singapore); Department of Physics, National University of Singapore, 117542 Singapore (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, 117575 Singapore (Singapore)

2014-04-15T23:59:59.000Z

295

Educational Multiwavelength Atomic Emission Spectrometer  

E-Print Network [OSTI]

atomic absorption is the capability for simultaneous multielement analysis. It can be used colleges had acquired atomic absorption instruments by the year 1990.[2] In contrast, atomic emission with the acetylene-air flame source taken from an existing atomic absorption instrument. Two spectrometer units

Nazarenko, Alexander

296

Simulating Cl K-edge X-ray absorption spectroscopy in MCl62- (M= U, Np, Pu) complexes and UOCl5- using time-dependent density functional theory  

SciTech Connect (OSTI)

We report simulations of the X-ray absorption near edge structure (XANES) at the Cl K-edge of actinide hexahalides MCl62- (M = U, Np, Pu) and the UOCl5- complex using linear-response time-dependent density functional theory (LR-TDDFT) extended for core excitations. To the best of our knowledge, these are the first calculations of the Cl K-edge spectra of NpCl62- and PuCl62-. In addition, the spectra are simulated with and without the environmental effects of the host crystal as well as ab initio molecular dynamics (AIMD) to capture the dynamical effects due to atomic motion. The calculated spectra are compared with experimental results, where available and the observed trends are discussed.

Govind, Niranjan; De Jong, Wibe A.

2014-02-21T23:59:59.000Z

297

Photocatalytic Activity of Bulk TiO{sub 2} Anatase and Rutile Single Crystals Using Infrared Absorption Spectroscopy  

SciTech Connect (OSTI)

A systematic study on the photocatalytic activity of well-defined, macroscopic bulk single-crystal TiO{sub 2} anatase and rutile samples has been carried out, which allows us to link photoreactions at surfaces of well-defined oxide semiconductors to an important bulk property with regard to photochemistry, the life time of e-h pairs generated in the bulk of the oxides by photon absorption. The anatase (101) surface shows a substantially higher activity, by an order of magnitude, for CO photo-oxidation to CO{sub 2} than the rutile (110) surface. This surprisingly large difference in activity tracks the bulk e-h pair lifetime difference for the two TiO{sub 2} modifications as determined by contactless transient photoconductance measurements on the corresponding bulk materials.

Xu Mingchun; Gao Youkun [Department of Physical Chemistry I, Ruhr-Universitaet Bochum, 44780 (Germany); Moreno, Elias Martinez; Kunst, Marinus [Hahn-Meitner-Institut, Glienicker Strasse 100, D-1000 Berlin 39 (Germany); Muhler, Martin [Laboratory of Industrial Chemistry, Ruhr-Universitaet Bochum, 44780 (Germany); Wang Yuemin [Department of Physical Chemistry I, Ruhr-Universitaet Bochum, 44780 (Germany); Laboratory of Industrial Chemistry, Ruhr-Universitaet Bochum, 44780 (Germany); Idriss, Hicham [Department of Chemistry, University of Aberdeen and School of Engineering, Robert Gordon University, AB24 3EU Aberdeen, Scotland (United Kingdom); Woell, Christof [Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe (Germany)

2011-04-01T23:59:59.000Z

298

Portable sample preparation and analysis system for micron and sub-micron particle characterization using light scattering and absorption spectroscopy  

DOE Patents [OSTI]

There is provided a method and device for remote sampling, preparation and optical interrogation of a sample using light scattering and light absorption methods. The portable device is a filtration-based device that removes interfering background particle material from the sample matrix by segregating or filtering the chosen analyte from the sample solution or matrix while allowing the interfering background particles to be pumped out of the device. The segregated analyte is then suspended in a diluent for analysis. The device is capable of calculating an initial concentration of the analyte, as well as diluting the analyte such that reliable optical measurements can be made. Suitable analytes include cells, microorganisms, bioparticles, pathogens and diseases. Sample matrixes include biological fluids such as blood and urine, as well as environmental samples including waste water.

Stark, Peter C. (Los Alamos, NM); Zurek, Eduardo (Barranquilla, CO); Wheat, Jeffrey V. (Fort Walton Beach, FL); Dunbar, John M. (Santa Fe, NM); Olivares, Jose A. (Los Alamos, NM); Garcia-Rubio, Luis H. (Temple Terrace, FL); Ward, Michael D. (Los Alamos, NM)

2011-07-26T23:59:59.000Z

299

Outcomes of Chronic Arsenic Exposure on Aquatic Insects  

E-Print Network [OSTI]

electrothermal atomic absorption spectrometry. AnalyticaHydride Generated Atomic Absorption Spectroscopy (HGAAS) andHydride Generated Atomic Absorption Spectroscopy (HGAAS).

Mogren, Christina Loraine

2013-01-01T23:59:59.000Z

300

Echelle Spectroscopy of QSO Absorption Line Systems with Metals in the Direction of HS 1700+6416  

E-Print Network [OSTI]

We present a high signal-to-noise high resolution spectrum of the radio-quiet QSO HS1700+6416 (z = 2.72). Analysis of the absorption line systems with metals yields the following results. (1) The dense cluster of C IV doublets at 2.432 -0.95 and [Al/H] > -0.96 for the strongest component of this absorber. Abundances of three other Lyman limit absorbers are also derived from photoionization models. (3) Unsaturated C IV and rather strong N V are detected in the associated absorber at z(abs) = 2.7125. The apparent column density profiles indicate that N V is affected by unresolved saturation or that the N V absorbing gas does not completely cover the QSO flux source. From photoionization models we derive [N/H] > -0.65 and [C/H] > -0.82. (4) We tentatively conclude that the number of Mg II systems detected per unit redshift is dominated by weak Mg II lines with rest equivalent width less than 0.3 A.

Tripp, T M; Savage, B D; Tripp, Todd M.; Lu, Limin; Savage, Blair D.

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Time-Resolved Quantitative Measurement of OH HO2 and CH2O in Fuel Oxidation Reactions by High Resolution IR Absorption Spectroscopy.  

SciTech Connect (OSTI)

Combined with a Herriott-type multi-pass slow flow reactor, high-resolution differential direct absorption spectroscopy has been used to probe, in situ and quantitatively, hydroxyl (OH), hydroperoxy (HO 2 ) and formaldehyde (CH 2 O) molecules in fuel oxidation reactions in the reactor, with a time resolution of about 1 micro-second. While OH and CH 2 O are probed in the mid-infrared (MIR) region near 2870nm and 3574nm respectively, HO 2 can be probed in both regions: near-infrared (NIR) at 1509nm and MIR at 2870nm. Typical sensitivities are on the order of 10 10 - 10 11 molecule cm -3 for OH at 2870nm, 10 11 molecule cm -3 for HO 2 at 1509nm, and 10 11 molecule cm -3 for CH 2 O at 3574nm. Measurements of multiple important intermediates (OH and HO 2 ) and product (CH 2 O) facilitate to understand and further validate chemical mechanisms of fuel oxidation chemistry.

Huang, Haifeng; Rotavera, Brandon; Taatjes, Craig A.

2014-08-01T23:59:59.000Z

302

E-Print Network 3.0 - absorption spectrometry etaas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

With Confirmation of Accuracy by Inductively Coupled Plasma Mass Spectrometry and Atomic Absorption Spectrometry... -LEAFS uses absorption; graphite furnace; inductively...

303

E-Print Network 3.0 - absorption spectrometry faas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Marco A. Z. Arruda* Summary: for metal determination is normally carried out by flame atomic absorption spectrometry (FAAS). The main... atomic absorption spectrometry (FAAS)...

304

E-Print Network 3.0 - absorption spectrom- etry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Summary: is used to digest samples and elements are determined by spike-height flame atomic absorption spectrom... Block Digestion and Spike-Height Flame Atomic Absorption...

305

Femtosecond Absorption Spectroscopy of Transition  

E-Print Network [OSTI]

Department of Chemistry, Michigan State University, East Lansing, Michigan 48824 Received May 6, 2003 in the study of photoinduced charge-transfer processes2 as well as the quest for achieving efficient solar

McCusker, James K.

306

E-Print Network 3.0 - absorption spectrometry configurations...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

307

E-Print Network 3.0 - absorption spectrometry analyticalmethod...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

308

X-RAY ABSORPTION STUDIES OF GRAPHITE INTERCALATES AND METAL-AMMONIA SOLUTION  

E-Print Network [OSTI]

I. INTRODUCTION A. X-Ray Absorption Spectroscopy B. Graphiteacknowledged. The X-Ray absorption data could not have beenI INTRODUCTION X-ray absorption, spectroscopy (XAS) has been

Robertson, A.S.

2010-01-01T23:59:59.000Z

309

Transient Xray absorption features in GRBs 1 Transient XRay Absorption in GRBs  

E-Print Network [OSTI]

due to photoelectric absorption or other atomic processes.) The transient nature of the absorptionTransient X­ray absorption features in GRBs 1 Transient X­Ray Absorption in GRBs and its Abstract The recent detection of a transient absorption feature in the prompt emission of GRB 990705 has

Boettcher, Markus

310

ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1978  

E-Print Network [OSTI]

Offgas Using Zeeman Atomic Absorption Spectroscopy D. C.spectro- metry, Zeeman atomic absorption spectroscopy andOffgass Using Zeeman Atomic Absorption Spectroscopy D. C.

Cairns, E.L.

2011-01-01T23:59:59.000Z

311

INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER  

E-Print Network [OSTI]

1970. Analytical Methods for Atomic Absorption Spectroscopy.1973. Analytical Methods for Atomic Absorption Spectroscopy.analysis; AAS =atomic absorption spectroscopy. EXPERIMENTAL

Farrier, D.S.

2011-01-01T23:59:59.000Z

312

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network [OSTI]

zinc and chloride by atomic absorption by the spectroscopy.College The atomic absorption spectroscopy was performed ofrandom error is about atomic absorption spectroscopy. Many

Mc Vay, L.

2011-01-01T23:59:59.000Z

313

Charge Resonance Effects on Electronic Absorption Line Shapes: Application to the Heterodimer Absorption of Bacterial Photosynthetic Reaction Centers  

E-Print Network [OSTI]

to the formalism of Fano's treatment for atomic absorption line shapes associated with autoionization (Fano, UCharge Resonance Effects on Electronic Absorption Line Shapes: Application to the Heterodimer Absorption of Bacterial Photosynthetic Reaction Centers Huilin Zhou and Steven G. Boxer* Department

Boxer, Steven G.

314

Atomic and molecular interstellar absorption lines toward the high galactic latitude stars HD~141569 and HD~157841 at ultra-high resolution  

E-Print Network [OSTI]

We present ultra-high resolution (0.32 km/s) spectra obtained with the 3.9m Anglo-Australian Telescope (AAT) and Ultra-High-Resolution Facility (UHRF), of interstellar NaI D1, D2, Ca II K, K I and CH absorption toward two high galactic latitude stars HD141569 and HD157841. We have compared our data with 21-cm observations obtained from the Leiden/Dwingeloo HI survey. We derive the velocity structure, column densities of the clouds represented by the various components and identify the clouds with ISM structures seen in the region at other wavelengths. We further derive abundances, linear depletions and H2 fractional abundances for these clouds, wherever possible. Toward HD141569, we detect two components in our UHRF spectra : a weak, broad component at - 15 km/s, seen only in CaII K absorption and another component at 0 km/s, seen in NaI D1, D2, Ca II K, KI and CH absorption. In the case of the HD157841 sightline, a total of 6 components are seen on our UHRF spectra in NaI D1, D2 Ca II K, K I and CH absorption. 2 of these 6 components are seen only in a single species.

M. S. Sahu; J. C. Blades; L. He; D. Hartmann; M. J. Barlow; I. A. Crawford

1998-03-31T23:59:59.000Z

315

A survey for redshifted molecular and atomic absorption lines - II. Associated HI, OH and millimetre lines in the z >~ 3 Parkes quarter-Jansky flat-spectrum sample  

E-Print Network [OSTI]

We present the results of a z>2.9 survey for HI 21-cm and molecular absorption in the hosts of radio quasars using the GMRT and the Tidbinbilla 70-m telescope. Previously published searches, which are overwhelmingly at redshifts of z2.5. We therefore believe that our high redshift selection is responsible for our exclusive non-detections, and find that at ultra-violet luminosities of >10e23 W/Hz, 21-cm absorption has never been detected. We also find this to not only apply to our targets, but also those at low redshift exhibiting similar luminosities, giving zero detections out of a total of 16 sources over z=0.24 to 3.8. This is in contrast to the absorption. The mix of 21-cm detections and non-detections is currently attributed to orientation effects, where according to unified schemes of active galactic nuclei, 21-cm absorption is more likely to occur in sources designated as radio galaxies (type-2 objects, where the nucleus is viewed through dense obscuring circumnuclear gas) than in quasars(type-1 objects, where we have a direct view to the nucleus). However, due to the exclusively high ultra-violet luminosities of our targets it is not clear whether orientation effects alone can wholly account for the distribution, although there exists the possibility that the large luminosities are indicative of a changing demographic of galaxy types. We also find that below luminosities of ~10e23 W/Hz, both type-1 and type-2 objects have a 50% likelihood of exhibiting 21-cm absorption.

S. J. Curran; M. T. Whiting; T. Wiklind; J. K. Webb; M. T. Murphy; C. R. Purcell

2012-01-07T23:59:59.000Z

316

High Resolution Spectroscopy of X-ray Quasars: Searching for the X-ray Absorption from the Warm-Hot Intergalactic Medium  

E-Print Network [OSTI]

We present a survey of six low- to moderate-redshift quasars with Chandra and XMM-Newton. The primary goal is to search for the narrow X-ray absorption lines produced by highly ionized metals in the warm-hot intergalactic ...

Fang, Taotao

317

Scientific innovation and resonance ionization spectroscopy  

SciTech Connect (OSTI)

An account is presented of the development and appliations of resonance ionization spectroscopy and one atom detection.

Richmond, C.R.

1981-01-01T23:59:59.000Z

318

Infrared Spectroscopy and Optical Constants of Porous Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy and Optical Constants of Porous Amorphous Solid Water. Infrared Spectroscopy and Optical Constants of Porous Amorphous Solid Water. Abstract: Reflection-absorption...

319

Woodhead Publishing Limited, 2013 Tunable mid-infrared laser absorption  

E-Print Network [OSTI]

absorption spectroscopy F. K. TITTEL and R. LEWICKI, Rice University, USA DOI: 10 absorption spectroscopy (LAS) and recent examples of their use in field deployable optical instruments detection methods that include several types of multipass gas absorption cells with the option to apply

320

In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution  

SciTech Connect (OSTI)

A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the way for in situ investigations of electrochemical processes, photovoltaics, batteries, fuel cells, water splitting, corrosion, electrodeposition, and a variety of important biological processes.

Jiang, Peng; Chen, Jeng-Lung; Borondics, Ferenc; Glans, Per-Anders; West, Mark W.; Chang, Ching-Lin; Salmeron, Miquel; Guo, Jinghua

2010-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Role of defects in BiFeO{sub 3} multiferroic films and their local electronic structure by x-ray absorption spectroscopy  

SciTech Connect (OSTI)

Present study reports the role of defects in the electrical transport in BiFeO{sub 3} (BFO) multiferroic films and its local electronic structure investigated by near-edge X-ray absorption fine structure. Defects created by high energy 200?MeV Ag{sup +15} ion irradiation with a fluence of ?5?×?10{sup 11} ions/cm{sup 2} results in the increase in structural strain and reduction in the mobility of charge carriers and enhancement in resistive (I-V) and polarization (P-E) switching behaviour. At higher fluence of ?5?×?10{sup 12} ions/cm{sup 2}, there is a release in the structural strain due to local annealing effect, resulting in an increase in the mobility of charge carriers, which are released from oxygen vacancies and hence suppression in resistive and polarization switching. Near-edge X-ray absorption fine structure studies at Fe L{sub 3,2}- and O K-edges show a significant change in the spectral features suggesting the modifications in the local electronic structure responsible for changes in the intrinsic magnetic moment and electrical transport properties of BFO.

Ravalia, Ashish; Vagadia, Megha; Solanki, P. S.; Shah, N. A.; Kuberkar, D. G., E-mail: dgkuberkar@rediffmail.com [Department of Physics, Saurashtra University, Rajkot 360 005 (India); Gautam, S.; Chae, K. H. [Nano Material Analysis Centre, Korean Institute of Science and Technology, Seoul 136-79 (Korea, Republic of); Asokan, K. [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

2014-10-21T23:59:59.000Z

322

E-Print Network 3.0 - atomic emission detection Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

38 Dissipative atom optics PIERRE DESBIOLLES, MARKUS ARNDT, Summary: , if we neglect the atomic recoil during absorption and emission. However, the atom may also fa11 into Fg......

323

E-Print Network 3.0 - atomic spectrometry update Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

techniques that also measure concentration using atom properties... , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

324

E-Print Network 3.0 - atomic spectrometry techniques Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

techniques that also measure concentration using atom properties... , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

325

Statistically meaningful data on the chemical state of ironprecipitates in processed multicrystalline silicon usingsynchrotron-based X-ray absorption spectroscopy  

SciTech Connect (OSTI)

X-ray fluorescence microscopy (mu-XRF), x-ray beam induced current (XBIC), and x-ray absorption spectromicroscopy (mu-XAS) were performed on fully-processed Bay Six cast multicrystalline silicon and aluminum-gettered AstroPower Silicon-Film(TM) sheet material. Over ten iron precipitates--predominantly of iron silicide--were identified at low lifetime regions in both materials, both at grain boundaries and intragranular defects identified by XBIC. In addition, large (micron-sized) particles containing oxidized iron and other impurities (Ca, Cr, Mn) were found in BaySix material. The smaller iron silicide precipitates were more numerous and spatially distributed than their larger oxidized iron counterparts, and thus deemed more detrimental to minority carrier diffusion length.

Buonassisi, T.; Heuer, M.; Istratov, A.A.; Weber, E.R.; Cai, Z.; Lai, B.; Marcus, M.; Lu, J.; Rozgonyi, G.; Schindler, R.; Jonczyk, R.; Rand, J.

2004-11-08T23:59:59.000Z

326

E-Print Network 3.0 - absorption spectrometry detection Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

327

E-Print Network 3.0 - absorption spectrometry fi-aas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

328

E-Print Network 3.0 - absorption spectrometry technique Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

329

E-Print Network 3.0 - absorption va vibrational Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of a protein, which deviate only... direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

330

E-Print Network 3.0 - acid absorption acceleration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

acids, the ligands and specific... direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

331

E-Print Network 3.0 - absorption protein npc1l1 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

332

E-Print Network 3.0 - absorption spectrometry f-aas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

333

E-Print Network 3.0 - absorption spectrum aided Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

334

E-Print Network 3.0 - absorption Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

335

E-Print Network 3.0 - absorptivity Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to proteins. Based on Summary: direct insights into the reaction mechanism at the atomic level. Absorption spectrum of a protein... In Figure 1 a typical absorption...

336

E-Print Network 3.0 - absorption spectrometry method Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

337

A SURVEY OF INSTRUMENTATION USED FOR MONITORING METALS IN WATER  

E-Print Network [OSTI]

diagram of an atomic absorption spectrometer. SimplifiedTrace Analysis by Atomic Absorption Spectroscopy and Anodicin Table 1. They are atomic absorption spectroscopy, botl1

Quinby-Hunt, M.S.

2011-01-01T23:59:59.000Z

338

ENERGY & ENVIRONMENT DIVISION. ANNUAL REPORT FY 1980  

E-Print Network [OSTI]

Offgases by Zeeman Atomic Absorption Spectroscopy D. C.Offgases by Zeeman Atomic Absorption Spectroscopy," Energya graphite furnace atomic absorption detector (HPLC-GFAA).

Authors, Various

2010-01-01T23:59:59.000Z

339

ENERGY & ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

Offgases by Zeeman Atomic Absorption Spectroscopy D. C.Products by Zeeman Atomic Absorption Spectroscopy E. Cuellarwith a F1ame1ess Atomic Absorption Detector for Speciation

Cairns, E.J.

2010-01-01T23:59:59.000Z

340

RETORT WATER PARTICULATES  

E-Print Network [OSTI]

Analysis, Isotope Zeeman Atomic Absorption, a Am Lab, Augustfor the Zeeman atomic absorption spectroscopy measurements,determined by Zeeman atomic absorption spectroscopy.4 X~ray

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

COMBUSTION RESEARCH - FY-1979  

E-Print Network [OSTI]

Products by Zeeman Atomic Absorption Spectroscopy E. Cuellarand R. McLaughlin, "Zeeman atomic absorption spectrometry,"to be used is Zeeman Atomic Absorption Spectroscopy (ZAA)

,

2012-01-01T23:59:59.000Z

342

Crystal structure of Thermotoga maritima TM0439: implications for the mechanism of bacterial GntR transcription regulators with Zn2+-binding FCD domains  

E-Print Network [OSTI]

binding site. Using atomic absorption spectroscopy and TrpElmer AAnalyst 400 atomic absorption spectrometer (AAS) withthe metal, we employed atomic absorption spectroscopy on the

Zheng, Meiying

2009-01-01T23:59:59.000Z

343

An experimental study of magnesium-isotope fractionation in chlorophyll-a photosynthesis  

E-Print Network [OSTI]

of chlorophyll standards by atomic absorption spectroscopy.were determined by Atomic Absorption Spectrometry and/or bymedium, as determined by atomic absorption spectroscopy. The

Black, J R; Yin, Q Z; Casey, W H

2006-01-01T23:59:59.000Z

344

THE MINICOMPUTER AND COMPUTATIONS IN CHEMISTRY. REPORT ON THE WORKSHOP  

E-Print Network [OSTI]

W. G. Boyle, Jr. , Atomic Absorption Instrument FunctionalBASIC Language for Atomic Absorption Flame Spectroscopy PartBASIC Language for Atomic Absorption Flame Spectroscopy Part

Authors, Various

2011-01-01T23:59:59.000Z

345

X-ray absorption study of the electronic structure of Mn-doped amorphous Si  

E-Print Network [OSTI]

X-ray absorption study of the electronic structure of Mn-?x ) is studied by X-ray absorption spectroscopy at the Mn Land featureless L 3,2 absorption peaks, corresponding to an

Zeng, Li

2008-01-01T23:59:59.000Z

346

Temperature-dependent collision-broadening parameters of H[sub 2]O lines in the 1. 4-[mu]m region using diode laser absorption spectroscopy  

SciTech Connect (OSTI)

Radiative properties of water vapor in the infrared spectrum are important in a variety of applications, including atmospheric sounding experiments, radiative sensing of combustion processes, and optical diagnostics for gasdynamic and aerodynamic studies. Here, spectrally resolved measurements of water vapor absorption spectra near 1.4 [mu]m have been performed with a tunable, distributed-feedback InGaAsP diode laser. A lineshape analysis was used to infer the collision-broadening coefficient of 11 rovibrational transitions in the [nu] + [nu][sub 3] and 2[nu][sub 1] vibration bands perturbed separately by N[sub 2], O[sub 2], CO[sub 2], and H[sub 2]. The temperature dependence of the broadening coefficients was determined using a temperature-controlled static cell and a pressure-driven shock tube over the range 300--1,200 K. The measured coefficients are in good agreement with the previous calculations of Delaye. Also, agreement is found between prior experimental data, obtained for the same rotational transitions but different vibration bands, and the results.

Langlois, S.; Birbeck, T.P.; Hanson, R.K. (Stanford Univ., CA (United States). Dept. of Mechanical Engineering)

1994-10-01T23:59:59.000Z

347

Quantification of rapid environmental redox processes with quick-scanning x-ray absorption  

E-Print Network [OSTI]

Quantification of rapid environmental redox processes with quick-scanning x-ray absorption. Here we apply quick-scanning x-ray absorption spectroscopy (Q-XAS), at sub-second time that can be measured using x-ray absorption spectroscopy. arsenic extended x-ray absorption fine structure

Sparks, Donald L.

348

E-Print Network 3.0 - absorption spectrometry coupled Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... in graphite tube atomizers and analytical flames...

349

E-Print Network 3.0 - absorption spectrometry system Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... in graphite tube atomizers and analytical flames...

350

E-Print Network 3.0 - absorption spectrometry part Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Summary: . References 1 B. Welz, Conference report: first Rio Symposium on Furnace Atomic Absorption Spectrometry... , Special Issue 7th Rio Symposium on Atomic...

351

E-Print Network 3.0 - absorption cycle cooling Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cooling of an atomic beam in a sealed vapor cell C. J. Valea) Summary: to Doppler-free atomic absorption references using synchronous frequency feedback locking.19 The...

352

E-Print Network 3.0 - absorption spectrometry comparing Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... in graphite tube atomizers and analytical flames...

353

Cu K-edge X-ray Absorption Spectroscopy Reveals Differential Copper Coordimation Within Amyloid-beta Oligomers Compared to Amyloid-beta Monomers  

SciTech Connect (OSTI)

The fatal neurodegenerative disorder Alzheimer's disease (AD) has been linked to the formation of soluble neurotoxic oligomers of amyloid-{beta} (A{beta}) peptides. These peptides have high affinities for copper cations. Despite their potential importance in AD neurodegeneration few studies have focused on probing the Cu{sup 2+/1+} coordination environment within A{beta} oligomers. Herein we present a Cu K-edge X-ray absorption spectroscopic study probing the copper-coordination environment within oligomers of A{beta}(42) (sequence: DAEFRHDSGYEVHHQKLVFFAEDVGSNKGAIIGLMVGGVVIA). We find that the Cu{sup 2+} cation is contained within a square planar mixed N/O ligand environment within A{beta}(42) oligomers, which is similar to the copper coordination environment of the monomeric forms of {l_brace}Cu{sup II}A{beta}(40){r_brace} and {l_brace}Cu{sup II}A{beta}(16){r_brace}. Reduction of the Cu{sup 2+} cation within the A{beta}(42) oligomers to Cu{sup 1+} yields a highly dioxygen sensitive copper-species that contains Cu{sup 1+} in a tetrahedral coordination geometry. This can be contrasted with monomers of {l_brace}Cu{sup I}A{beta}(40){r_brace} and {l_brace}Cu{sup I}A{beta}(16){r_brace}, which contain copper in a dioxygen inert linear bis-histidine ligand environment [Shearer and Szalai, J. Am. Chem. Soc., 2008, 130, 17826]. The biological implications of these findings are discussed.

J Shearer; P Callan; T Tran; V Szalai

2011-12-31T23:59:59.000Z

354

Enhanced absorption Hanle effect in the configuration of crossed laser beam and magnetic field F. Renzoni,1,  

E-Print Network [OSTI]

modifications of the absorptive and dispersive properties of atomic media 2­4 , and are responsible for the sub that increases the atomic absorption 8,9 . The increased atomic absorption, denoted as electromagnetic induced abEnhanced absorption Hanle effect in the configuration of crossed laser beam and magnetic field F

355

Electromagnetically Induced Transparency from a Single Atom in Free Space  

E-Print Network [OSTI]

We report an absorption spectroscopy experiment and the observation of electromagnetically induced transparency from a single trapped atom. We focus a weak and narrowband Gaussian light beam onto an optically cooled Barium ion using a high numerical aperture lens. Extinction of this beam is observed with measured values of up to 1.3 %. We demonstrate electromagnetically induced transparency of the ion by tuning a strong control beam over a two-photon resonance in a three-level lambda-type system. The probe beam extinction is inhibited by more than 75 % due to population trapping.

L. Slodicka; G. Hetet; S. Gerber; M. Hennrich; R. Blatt

2010-05-18T23:59:59.000Z

356

E-Print Network 3.0 - absorption spectra response Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at Santa Barbara Collection: Geosciences 6 Nonlinear Spectroscopy of Cold, Trapped Atoms: Atomic Recoil and Localization Effects in a MOT Summary: mixing |r |eg Different shapes...

357

Characterization of the molecular structure and mechanical properties of polymer surfaces and protein/polymer interfaces by sum frequency generation vibrational spectroscopy and atomic force microscopy  

SciTech Connect (OSTI)

Sum frequency generation (SFG) vibrational spectroscopy, atomic force microscopy (AFM), and other complementary surface-sensitive techniques have been used to study the surface molecular structure and surface mechanical behavior of biologically-relevant polymer systems. SFG and AFM have emerged as powerful analytical tools to deduce structure/property relationships, in situ, for polymers at air, liquid and solid interfaces. The experiments described in this dissertation have been performed to understand how polymer surface properties are linked to polymer bulk composition, substrate hydrophobicity, changes in the ambient environment (e.g., humidity and temperature), or the adsorption of macromolecules. The correlation of spectroscopic and mechanical data by SFG and AFM can become a powerful methodology to study and engineer materials with tailored surface properties. The overarching theme of this research is the interrogation of systems of increasing structural complexity, which allows us to extend conclusions made on simpler model systems. We begin by systematically describing the surface molecular composition and mechanical properties of polymers, copolymers, and blends having simple linear architectures. Subsequent chapters focus on networked hydrogel materials used as soft contact lenses and the adsorption of protein and surfactant at the polymer/liquid interface. The power of SFG is immediately demonstrated in experiments which identify the chemical parameters that influence the molecular composition and ordering of a polymer chain's side groups at the polymer/air and polymer/liquid interfaces. In general, side groups with increasingly greater hydrophobic character will be more surface active in air. Larger side groups impose steric restrictions, thus they will tend to be more randomly ordered than smaller hydrophobic groups. If exposed to a hydrophilic environment, such as water, the polymer chain will attempt to orient more of its hydrophilic groups to the surface in order to minimize the total surface energy. With an understanding of the structural and environmental parameters which govern polymer surface structure, SFG is then used to explore the effects of surface hydrophobicity and solvent polarity on the orientation and ordering of amphiphilic neutral polymers adsorbed at the solid/liquid interface. SFG spectra show that poly(propylene glycol) (PPG) and poly(ethylene glycol) (PEG) adsorb with their hydrophobic moieties preferentially oriented toward hydrophobic polystyrene surfaces. These same moieties, however, disorder when adsorbed onto a hydrophilic silica/water interface. Water is identified as a critical factor for mediating the orientation and ordering of hydrophobic moieties in polymers adsorbed at hydrophobic interfaces. The role of bulk water content and water vapor, as they influence hydrogel surface structure and mechanics, continues to be explored in the next series of experiments. A method was developed to probe the surface viscoelastic properties of hydroxylethyl methacrylate (HEMA) based contact lens materials by analyzing AFM force-distance curves. AFM analysis indicates that the interfacial region is dehydrated, relative to the bulk. Experiments performed on poly(HEMA+MA) (MA = methacrylic acid), a more hydrophilic copolymer with greater bulk water content, show even greater water depletion at the surface. SFG spectra, as well as surface energy arguments, suggest that the more hydrophilic polymer component (such as MA) is not favored at the air interface; this may explain anomalies in water retention at the hydrogel surface. Adsorption of lysozyme onto poly(HEMA+MA) was found to further reduce near-surface viscous behavior, suggesting lower surface water content. Lastly, protein adsorption is studied using a model polymer system of polystyrene covalently bound with a monolayer of bovine serum albumin. SFG results indicate that some amino acid residues in proteins adopt preferred orientations. SFG spectra also show that the phenyl rings of the bare polystyrene substrate in contact with air or

Koffas, Telly Stelianos

2004-05-15T23:59:59.000Z

358

X-ray absorption spectroscopic studies of the active sites of nickel- and copper-containing metalloproteins  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) is a useful tool for obtaining structural and chemical information about the active sites of metalloproteins and metalloenzymes. Information may be obtained from both the edge region and the extended X-ray absorption fine structure (EXAFS) or post-edge region of the K-edge X-ray absorption spectrum of a metal center in a compound. The edge contains information about the valence electronic structure of the atom that absorbs the X-rays. It is possible in some systems to infer the redox state of the metal atom in question, as well as the geometry and nature of ligands connected to it, from the features in the edge in a straightforward manner. The EXAFS modulations, being produced by the backscattering of the ejected photoelectron from the atoms surrounding the metal atom, provide, when analyzed, information about the number and type of neighbouring atoms, and the distances at which they occur. In this thesis, analysis of both the edge and EXAFS regions has been used to gain information about the active sites of various metalloproteins. The metalloproteins studied were plastocyanin (Pc), laccase and nickel carbon monoxide dehydrogenase (Ni CODH). Studies of Cu(I)-imidazole compounds, related to the protein hemocyanin, are also reported here.

Tan, G.O.

1993-06-01T23:59:59.000Z

359

Directional fine structure in absorption of white x rays: A tomographic interpretation P. Korecki,1,  

E-Print Network [OSTI]

structure in absorption of white x rays can be interpreted as real-space projections of atomic structure from neigh- boring atoms.1 A straightforward analysis of the extended x-ray absorption fine structure of the absorbing atoms. Thus, the absorption cross section is effectively modulated by the x-ray scattering

Korecki, Pawe³

360

X-ray Absorption Spectroscopy and Density Functional Theory Studies of [(H3buea)FeIII-X]n1 (X= S2-, O2-,OH-): Comparison of Bonding and Hydrogen Bonding in Oxo and Sulfido Complexes  

SciTech Connect (OSTI)

Iron L-edge, iron K-edge, and sulfur K-edge X-ray absorption spectroscopy was performed on a series of compounds [Fe{sup III}H{sub 3}buea(X)]{sup n-} (X = S{sup 2-}, O{sup 2-}, OH{sup -}). The experimentally determined electronic structures were used to correlate to density functional theory calculations. Calculations supported by the data were then used to compare the metal-ligand bonding and to evaluate the effects of H-bonding in Fe{sup III}-O vs Fe{sup III-}S complexes. It was found that the Fe{sup III-}O bond, while less covalent, is stronger than the FeIII-S bond. This dominantly reflects the larger ionic contribution to the Fe{sup III-}O bond. The H-bonding energy (for three H-bonds) was estimated to be -25 kcal/mol for the oxo as compared to -12 kcal/mol for the sulfide ligand. This difference is attributed to the larger charge density on the oxo ligand resulting from the lower covalency of the Fe-O bond. These results were extended to consider an Fe{sup IV-}O complex with the same ligand environment. It was found that hydrogen bonding to Fe{sup IV-}O is less energetically favorable than that to Fe{sup III-}O, which reflects the highly covalent nature of the Fe{sup IV-}O bond.

Dey, Abhishek; Hocking, Rosalie K.; /Stanford U., Chem. Dept.; Larsen, Peter; Borovik, Andrew S.; /Kansas U.; Hodgson, Keith O.; Hedman, Britt; Solomon, Edward I.; /SLAC,

2006-09-27T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass  

DOE Patents [OSTI]

Photoionization via autoionizing atomic levels combined with conventional mass spectroscopy provides a technique for quantitative analysis of trace quantities of chemical elements in the presence of much larger amounts of other elements with substantially the same atomic mass. Ytterbium samples smaller than 10 ng have been detected using an ArF* excimer laser which provides the atomic ions for a time-of-flight mass spectrometer. Elemental selectivity of greater than 5:1 with respect to lutetium impurity has been obtained. Autoionization via a single photon process permits greater photon utilization efficiency because of its greater absorption cross section than bound-free transitions, while maintaining sufficient spectroscopic structure to allow significant photoionization selectivity between different atomic species. Separation of atomic species from others of substantially the same atomic mass is also described.

Miller, C.M.; Nogar, N.S.

1982-09-02T23:59:59.000Z

362

Dynamics of production of iodine atoms by dissociation of iodides in a pulsed self-sustained discharge  

SciTech Connect (OSTI)

Absorption at the laser transition has been used for the first time to assess the evolution of concentration of iodine atoms in a pulsed self-sustained discharge in mixtures of iodides with a buffer gas such as molecular nitrogen and helium. Dynamics of the iodine atom production is studied by the method of absorption spectroscopy. The dissociation of C{sub n}F{sub 2n+1}I and CnH{sub 2n+1}I (n = 1, 2) iodides is investigated. The energy required to produce atomic iodine is evaluated. The experimental data obtained for CF{sub 3}I are compared with the results of numerical simulations, their reasonable agreement being demonstrated. (active media)

Vagin, Nikolai P; Kochetov, Igor' V; Napartovich, A P; Yuryshev, Nikolai N

2013-07-31T23:59:59.000Z

363

Atomic-Scale Investigation of Epitaxial Graphene Grown on 6H-SiC(0001) Using Scanning Tunneling Microscopy and Spectroscopy  

E-Print Network [OSTI]

Atomic-Scale Investigation of Epitaxial Graphene Grown on 6H-SiC(0001) Using Scanning Tunneling ReceiVed: June 26, 2010 Graphene was epitaxially grown on a 6H-SiC(0001) substrate by thermal the evolution of the graphene growth as a function of the temperature. We found that the evaporation of Si

Kim, Sehun

364

SMB, X-ray Absorption Spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 ResourceAwards SAGE Awards ,#2446Small Angle X-Ray

365

Absorption line shape recovery beyond the detection bandwidth limit: application to the Boltzmann constant determination  

E-Print Network [OSTI]

1 Absorption line shape recovery beyond the detection bandwidth limit: application to the Boltzmann of the influence of detection bandwidth properties on observed line shapes in laser absorption spectroscopy the Boltzmann constant (kB) [10, 11]. Based upon laser absorption spectroscopy in the linear regime

366

Pressurised xenon as scintillator for gamma spectroscopy  

E-Print Network [OSTI]

Detectors based on liquid or gas xenon have been used and are in use for a number of applications, in particular for the detection of gamma rays. Xenon is a well-suited medium for gamma spectroscopy thanks to its high atomic number and, consequently, large cross-section for photo-electric absorption. This paper presents experimental studies of high pressure xenon as a scintillator, with the aim of developing a gamma ray detector for the detection of Special Nuclear Materials (SNM). The first goal was to study the dependence of the light yield and of the energy resolution on the thermodynamic conditions. We present preliminary results from an optimised version of the detector.

Resnati, F

2013-01-01T23:59:59.000Z

367

LATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION  

E-Print Network [OSTI]

crystalline domains are taken. Absorption studies of the dynamics of atomic motions in condensed matterLATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION AND COHERENT DECAY MODES Institut Max von Laue-Paul Langevin, Grenoble, France R6sumb. -La section efficace pour l'absorption nucleaire

Paris-Sud XI, Université de

368

E-Print Network 3.0 - atomic spectroscopic detection Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic flux measurement of electron-beam evaporated yttrium with a diode-laser-based atomic absorption monitor at 668 nm Summary: . The spectroscopic technique, based on...

369

E-Print Network 3.0 - analytical atomic spectrometry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: in graphite tube atomizers and analytical flames by wavelength modulation-laser atomic absorption spectrometry... down to about 310 nm. Such powers are sufficient for...

370

E-Print Network 3.0 - atom vapor cells Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rotation in the vapor cell due to inten- sity-induced birefringence in the rubidium atomic vapor. While... Super efficient absorption filter for quantum memory using atomic...

371

E-Print Network 3.0 - atomic emission spectrometry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Basics Review Quadrupole ICP-MS: Introduction to Instrumentation, Summary: , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

372

E-Print Network 3.0 - atomic beam frequency Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

laser and characterization of the atomic beam... is to measure the frequency dependent absorption of a laser beam intersecting the atomic beam. Depending... the ... Source:...

373

Silicate absorption in heavily obscured galaxy nuclei  

E-Print Network [OSTI]

Spectroscopy at 8-13 microns with T-ReCS on Gemini-S is presented for 3 galaxies with substantial silicate absorption features, NGC 3094, NGC 7172 and NGC 5506. In the galaxies with the deepest absorption bands, the silicate profile towards the nuclei is well represented by the emissivity function derived from the circumstellar emission from the red supergiant, mu Cephei which is also representative of the mid-infrared absorption in the diffuse interstellar medium in the Galaxy. There is spectral structure near 11.2 microns in NGC 3094 which may be due to a component of crystalline silicates. In NGC 5506, the depth of the silicate absorption increases from north to south across the nucleus, suggestive of a dusty structure on scales of 10s of parsecs. We discuss the profile of the silicate absorption band towards galaxy nuclei and the relationship between the 9.7 micron silicate and 3.4 micron hydrocarbon absorption bands.

P. F. Roche; C. Packham; D. K. Aitken; R. E. Mason

2006-10-19T23:59:59.000Z

374

E-Print Network 3.0 - atomic force ultrasonic Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

laboratories, you must attend the safety orientation. Summary: W ultrasonic horn Atomic absorption spectrophotometer UVVIS spectrophotometer Centrifuge p... ,...

375

E-Print Network 3.0 - atomic structure reveals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure, thus revealing very subtle... Nonlinear Spectroscopy of Cold, Trapped Atoms: Atomic Recoil and Localization Effects in a MOT T... .if.uj.edu.plplZOAgrupywg.htm...

376

E-Print Network 3.0 - atomic nucleus Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nucleus Summary: PhysicsOptics Seminar Optical Spectroscopy of an Atomic Nucleus: The Thorium-229 Nuclear Clock Dr... an atomic nucleus at optical (vacuum ultraviolet)...

377

Characterizing Absorption Spectrum of Natural Rubidium by Using a Directly Modulated VCSEL  

E-Print Network [OSTI]

in the absorption profile of a medium containing system atoms. Moreover, the change leads to a very narrow the absorption spectrum of the atomic vapor. Identifying the correct spectral placing is a major taskCharacterizing Absorption Spectrum of Natural Rubidium by Using a Directly Modulated VCSEL Ido Ben

Eisenstein, Gadi

378

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

Offgases by Zeeman Atomic Absorption Spectroscopy D. C.~ Graphite Furnace Atomic Absorption Spectrometry," J.vd.th a Flameless Atomic Absorption Detector for Speciation

,

2012-01-01T23:59:59.000Z

379

Pharmacokinetics and Efficacy of Oxytetracycline in RLP-infected Abalone  

E-Print Network [OSTI]

to pathogen. Atomic absorption spectroscopy conducted onwe assessed, via atomic absorption/emission spectrometry,microwave digestion and atomic absorption spectrometry (

Tjeerdema, Ronald S.; Friedman, Carolyn S.; Moore, James D.; Viant, Mark R.

2007-01-01T23:59:59.000Z

380

COMBUSTION RESEARCH Chapter from the Energy and Environment Division Annual Report 1980  

E-Print Network [OSTI]

Hyperfine Zeeman Effect Atomic Absorption Spectrometry forthe Zeeman Effect to Atomic Absorption Spectrometry: A NewA Novel Method for Atomic Absorption Spectroscopy based on

Authors, Various

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Design of a rural water provision system to decrease arsenic exposure in Bangladesh  

E-Print Network [OSTI]

Hydride Generation Atomic Absorption Spectrophotomery (HG-Graphite Furnace Atomic Absorption Spectrometry (GF-Graphite Furnace - Atomic Absorption Spectroscopy (GF-AAS),

Mathieu, Johanna

2009-01-01T23:59:59.000Z

382

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

and Goda, L. Y. , atomic absorption spectrometry: Pergamonoil 1, p. 62. Zeeman atomic absorption, a new approach toranges studied Zeeman atomic absorption spectroscopy was

Fox, J. P.

2011-01-01T23:59:59.000Z

383

ENERGY & ENVIRONMENT DIVISION ANNUAL REPORT, 1977  

E-Print Network [OSTI]

of the Zeeman Atomic Absorption Technique to Fifteenfurnace for flameless atomic absorption spectrometry," Anal.and analyzed by flameless atomic absorption spectroscopy.

Budnitz, R.J.

2011-01-01T23:59:59.000Z

384

Soil Sampling At Valley Of Ten Thousand Smokes Region Area (Kodosky...  

Open Energy Info (EERE)

analytical techniques employed included instrumental neutron activation analysis (INAA), atomic absorption spectroscopy (AAS), direct-current plasma atomic emission spectroscopy...

385

Compound and Elemental Analysis At Valley Of Ten Thousand Smokes...  

Open Energy Info (EERE)

analytical techniques employed included instrumental neutron activation analysis (INAA), atomic absorption spectroscopy (AAS), direct-current plasma atomic emission spectroscopy...

386

E-Print Network 3.0 - alkali-metal atoms li Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

93 Educational Multiwavelength Atomic Emission Spectrometer Summary: detector; Fiber optics; Alkali metals; Alkaline earth metals; Flame spectroscopy; Chemical education....

387

E-Print Network 3.0 - absorption du cesium Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of SPIE Vol. 6871, 87112, (2008) Summary: from 9.192 GHz - of the fundamental Cesium atomic level have been scanned on a saturated absorption set... of the absorption line...

388

Moments of Absorption.  

E-Print Network [OSTI]

??Moments of Absorption explores the conceptual and visual themes that are presented in my MFA thesis exhibition. The research looks into the absorption of the… (more)

Kaufman, Sarah K.

2008-01-01T23:59:59.000Z

389

E-Print Network 3.0 - atomic shells m Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

edges, the calculations have been performed for clusters size up to 99 atoms (eight atomic shells... absorption spectnun. With two and three shells (17 and 29 atoms) the main...

390

E-Print Network 3.0 - atomic shells k Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

edges, the calculations have been performed for clusters size up to 99 atoms (eight atomic shells... absorption spectnun. With two and three shells (17 and 29 atoms) the main...

391

E-Print Network 3.0 - alpha-emitting atoms released Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic... Appendix B. Glossary 12;12;Appendix B. Glossary B-3 Appendix B. Glossary absorption, atomic... the nucleus of an atom; it has the same charge and mass as that of a...

392

E-Print Network 3.0 - atomic shells l Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

edges, the calculations have been performed for clusters size up to 99 atoms (eight atomic shells... absorption spectnun. With two and three shells (17 and 29 atoms) the main...

393

E-Print Network 3.0 - atomic shells Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

edges, the calculations have been performed for clusters size up to 99 atoms (eight atomic shells... absorption spectnun. With two and three shells (17 and 29 atoms) the main...

394

epitaxy system | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MnTi Oxides. Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Abstract: Atom flux sensors based on atomic absorption...

395

oxygen-plasma | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MnTi Oxides. Etalon-induced Baseline Drift And Correction In Atom Flux Sensors Based On Atomic Absorption Spectroscopy. Abstract: Atom flux sensors based on atomic absorption...

396

E-Print Network 3.0 - absorption spectrometry determination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... is used to digest...

397

E-Print Network 3.0 - absorption spectrometric method Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Selenium by Fluorescence Spectrometry Summary: MATERIALS 129 5. Ihnat. M.. Atomic absorption spectrometric determination of selenium with carbon furnace... , and...

398

E-Print Network 3.0 - absolute two-photon absorption Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

photoassociation Summary: shifted. These results for coherent control of two-photon absorption in atomic systems serve as our... . To the lowest order, the two-photon...

399

E-Print Network 3.0 - absorption spectra Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of a protein, which deviate only... direct insights into the reaction mechanism at the atomic level. Absorption ... Source: Gerwert, Klaus - Fakultt fr Biologie,...

400

E-Print Network 3.0 - absorption difference spectra Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: these spectra show a large difference of the fine structure near the absorption edges of the inner atomic shells... . One of the specific feature of the...

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

E-Print Network 3.0 - absorption vapour samplers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Autodiluter system and ASX-510 Auto Sampler Capability: Analysis of most elements... atomic absorption spectrometer with longitudinal Zeeman graphite furnace, and AS-800...

402

E-Print Network 3.0 - absorption line key Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Line Shapes: Application to the Heterodimer... to the formalism of Fano's treatment for atomic absorption line shapes associated with autoionization (Fano, U... bands are...

403

E-Print Network 3.0 - absorption spectrometry combination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analytical combining RINH and IMS facilities RINH Genomics will re locate... absorption spectrometry Atomic fluorescence spectrometry (As, Se, Hg) Contact Joerg...

404

Oral Drug Absorption  

E-Print Network [OSTI]

properties ? membrane permeability ? metabolic stability ? enzyme inhibition or induction ? protein binding ? transporter affinity ?. Chemical Optimization DDS technology 4 Strategy of Drug Delivery Absorption Distribution Metabolism Excretion Improve of drug... absorption absorption enhancement controlled releasecontrolled release new administration route Drug targeting to the tissue to the cell to the organelle Dr. Shinji Yamashita (Setsunan University) Issue: Oral Drug Absorption Dr. Valentino J. Stella...

Yamashita, Shinji

2006-10-26T23:59:59.000Z

405

Optical control of nuclear resonant absorption: theory and experiment  

E-Print Network [OSTI]

Modification of nuclear resonant absorption by means of laser radiation is analyzed both theoretically and experimentally. Theoretical analysis is done on the basis of four-level model of atom. This model includes both electronic and nuclear...

Kolesov, Roman L.

2004-09-30T23:59:59.000Z

406

absorption des wasserstoffs: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

. . . . . . . . 41 3.2.2 Kristallines Eis im Volumen Wolf, Martin 5 ABSORPTION PHOTOLECTRIQUE DES RAYONS 03B3 DANS LA COUCHE L DES ATOMES Par Mme NADINE MARTY....

407

Lyman-alpha Absorption from Heliosheath Neutrals  

E-Print Network [OSTI]

We assess what information HST observations of stellar Ly-alpha lines can provide on the heliosheath, the region of the heliosphere between the termination shock and heliopause. To search for evidence of heliosheath absorption, we conduct a systematic inspection of stellar Ly-alpha lines reconstructed after correcting for ISM absorption (and heliospheric/astrospheric absorption, if present). Most of the stellar lines are well centered on the stellar radial velocity, as expected, but the three lines of sight with the most downwind orientations relative to the ISM flow (Chi1 Ori, HD 28205, and HD 28568) have significantly blueshifted Ly-alpha lines. Since it is in downwind directions where heliosheath absorption should be strongest, the blueshifts are almost certainly caused by previously undetected heliosheath absorption. We make an initial comparison between the heliosheath absorption and the predictions of a pair of heliospheric models. A model with a complex multi-component treatment of plasma within the heliosphere predicts less absorption than a model with a simple single-fluid treatment, which leads to better agreement with the data. Finally, we find that nonplanetary energetic neutral atom (ENA) fluxes measured by the ASPERA-3 instrument on board Mars Express, which have been interpreted as being from the heliosheath, are probably too high to be consistent with the relative lack of heliosheath absorption seen by HST. This would argue for a local interplanetary source for these ENAs instead of a heliosheath source.

Brian E. Wood; Vladislav V. Izmodenov; Jeffrey L. Linsky; Yury G. Malama

2006-11-30T23:59:59.000Z

408

Soft-x-ray spectroscopy study of nanoscale materials  

SciTech Connect (OSTI)

The ability to control the particle size and morphology of nanoparticles is of crucial importance nowadays both from a fundamental and industrial point of view considering the tremendous amount of high-tech applications. Controlling the crystallographic structure and the arrangement of atoms along the surface of nanostructured material will determine most of its physical properties. In general, electronic structure ultimately determines the properties of matter. Soft X-ray spectroscopy has some basic features that are important to consider. X-ray is originating from an electronic transition between a localized core state and a valence state. As a core state is involved, elemental selectivity is obtained because the core levels of different elements are well separated in energy, meaning that the involvement of the inner level makes this probe localized to one specific atomic site around which the electronic structure is reflected as a partial density-of-states contribution. The participation of valence electrons gives the method chemical state sensitivity and further, the dipole nature of the transitions gives particular symmetry information. The new generation synchrotron radiation sources producing intensive tunable monochromatized soft X-ray beams have opened up new possibilities for soft X-ray spectroscopy. The introduction of selectively excited soft X-ray emission has opened a new field of study by disclosing many new possibilities of soft X-ray resonant inelastic scattering. In this paper, some recent findings regarding soft X-ray absorption and emission studies of various nanostructured systems are presented.

Guo, J.-H.

2005-07-30T23:59:59.000Z

409

X-ray Absorption Spectroscopic Analysis of Reductive [2Fe-2S] Cluster Degradation in Hyperthermophilic Archaeal Succinate:Caldariellaquinone  

E-Print Network [OSTI]

X-ray Absorption Spectroscopic Analysis of Reductive [2Fe-2S] Cluster Degradation, but moderately sensitive to reduction with excess dithionite. We used iron K-edge X-ray absorption spectroscopy

Scott, Robert A.

410

Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications  

E-Print Network [OSTI]

Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized of quick extended x-ray absorption fine structure QEXAFS and quick x-ray absorption near edge structure- tion spectroscopy XAS was developed in energy dispersive and quick extended x-ray absorption fine

Sparks, Donald L.

411

Atomic force microscopy and x-ray photoelectron spectroscopy investigations of the morphology and chemistry of a PdCl{sub 2}/SnCl{sub 2} electroless plating catalysis system adsorbed onto shape memory alloy particles  

SciTech Connect (OSTI)

A study of the different stages of the electroless deposition of copper on micronic NiTi shape memory alloy particles activated by one-step and two-step methods has been conducted from both a chemical and a morphological point of view. The combination of x-ray photoelectron spectroscopy (XPS) measurements and atomic force microscopy (AFM) imaging has allowed detection of the distribution of the formed compounds and depth quantification and estimation of the surface topographic parameters. For the two-step method, at the sensitization of the early stages, it is observed by AFM that Sn is absorbed in form of clusters that tend to completely cover the surface and form a continuous film. XPS analysis have shown that Sn and Pd are first absorbed in form of oxide (SnO{sub 2} and PdO) and hydroxide [Sn(OH){sub 4}]. After the entire sensitization step, the NiTi substrate is covered with Sn-based compounds. After the sensitization and the activation steps the powder roughness increases. Behavior of the Sn and Pd growth for the one-step method does not follow the behavior found for the two-step method. Indeed, XPS analysis shows a three-dimensional (3D) growth of Pd clusters on top of a mixture of metallic tin, oxide (SnO) and hydroxide [Sn(OH){sub 2}]. These Pd clusters are covered with a thin layer of Pd-oxide contamination induced by the electroless process. The mean roughness for the one-step and two-step processes are equivalent. After copper deposition, the decrease of mean roughness is attributed to a filling of surface valleys, observed after the Sn-Pd coating step.

Silvain, J.F.; Fouassier, O.; Lescaux, S. [Institut de Chimie de la Matiere Condensee de Bordeaux (ICMCB) - CNRS, Universite de Bordeaux 1, 87 Avenue du Dr A. Schweitzer, F-33608 PESSAC (France); Veeco, Z.I. de la Gaudree, 11 Rue Marie Poussepin, F-91412 Dourdain (France)

2004-11-01T23:59:59.000Z

412

Optical absorption intensity of semiconductor single-wall carbon nanotubes  

E-Print Network [OSTI]

Optical absorption intensity of semiconductor single-wall carbon nanotubes Y. Oyama1 , R. Saito1. The optical absorption intensity is inversely proportional to the diameter in the unit of per carbon atom of single-wall carbon nanotubes (SWNT) synthesized by alcohol CCVD (ACCVD) method and HiPco method [1

Maruyama, Shigeo

413

Chemical factors influencing selenium atomization  

E-Print Network [OSTI]

Atomization. (August 1980) Mary Sue Buren, B, S. , Angelo State University Chairman of Advisory Comm1ttee: Dr. Thomas M. Vickrey Selenium in an acid1c matrix was analyzed using graphite furnace atom1c absorption with Zeeman-effect background correct1on.... Nickel(II} and lanthanum( III) were introduced as matrix modifiers to determine their effect on interferences 1n selenium atom1zation. In add1tion to matr1x mod1ficat1on, surface coating the graphite furnace with z1rconium and tantalum salts was also...

Buren, Mary Sue

1980-01-01T23:59:59.000Z

414

A Laser System for the Spectroscopy of Highly-Charged Bismuth Ions  

E-Print Network [OSTI]

We present and characterize a laser system for the spectroscopy on highly-charged ^209Bi^82+ ions at a wavelength of 243.87 nm. For absolute frequency stabilization, the laser system is locked to a near-infra-red laser stabilized to a rubidium transition line using a transfer cavity based locking scheme. Tuning of the output frequency with high precision is achieved via a tunable rf offset lock. A sample-and-hold technique gives an extended tuning range of several THz in the UV. This scheme is universally applicable to the stabilization of laser systems at wavelengths not directly accessible to atomic or molecular resonances. We determine the frequency accuracy of the laser system using Doppler-free absorption spectroscopy of Te_2 vapour at 488 nm. Scaled to the target wavelength of 244 nm, we achieve a frequency uncertainty of \\sigma_{244nm} = 6.14 MHz (one standard deviation) over six days of operation.

S. Albrecht; S. Altenburg; C. Siegel; N. Herschbach; G. Birkl

2011-08-25T23:59:59.000Z

415

Hadronic Atoms  

E-Print Network [OSTI]

We review the theory of hadronic atoms in QCD+QED. The non-relativistic effective Lagrangian approach, used to describe this type of bound states, is illustrated with the case of pi+pi- atoms. In addition, we discuss the evaluation of isospin-breaking corrections to hadronic atom observables by invoking chiral perturbation theory.

J. Gasser; V. E. Lyubovitskij; A. Rusetsky

2009-03-02T23:59:59.000Z

416

PHOTOELECTRON SPECTROSCOPY OF HEAVY ATOMS AND MOLECULES  

E-Print Network [OSTI]

s*:* .l»l«. .ii>s .W'i .ni" .pir- .KO: . im. .mm .4M\\ .mis .smaller than for the I (pir) I states, in variance withi c state-. Secondly, the H(pir) asymmetry parameters are in

White, M.G.

2010-01-01T23:59:59.000Z

417

Analysis of interference in attosecond transient absorption in adiabatic condition  

E-Print Network [OSTI]

We simulate the transient absorption of attosecond pulses of infrared laser-dressed atoms by considering a three-level system with the adiabatic approximation. We study the delay-dependent interference features in the transient absorption spectra of helium atoms from the perspective of the coherent interaction processes between the attosecond pulse and the quasi-harmonics, and find that many features of the interference fringes in the absorption spectra of the attosecond pulse can be attributed to the coherence phase difference. And the modulation signals of laser-induced sidebands of the dark state is found related to the dark state with population modulated by the dressing field.

Dong, Wenpu; Wang, Xiaowei; Zhao, Zengxiu

2015-01-01T23:59:59.000Z

418

HII Absorption Bill Erickson  

E-Print Network [OSTI]

HII Absorption Bill Erickson November 10, 2006 It would make all of the drift curve simulations.8 dB above the data. One reason for this might be HII absorption which is not modeled in simulations. There are a number of ways that one might try to estimate the absorption. One might use optical maps of HII

Ellingson, Steven W.

419

GEOC Sunday, March 21, 2010 47 -Speciation and release kinetics of cadmium and zinc in paddy soils: Application of X-ray absorption  

E-Print Network [OSTI]

: Application of X-ray absorption spectroscopy (XAS) Saengdao Khaokaew, Rufus L Chaney, PhD Matt Ginder kinetics, which is the aim of this research. X-ray absorption spectroscopy (XAS) was used to investigate Cd-ray absorption fine structure (EXAFS) spectroscopic data indicates that CdCO3 and Cd-humic complexes

Sparks, Donald L.

420

Influence of pp ions on pion absorption in H2 S. Jonsell,1  

E-Print Network [OSTI]

of experiments measuring the mass difference m m 0 from pion absorption in pionic atoms. These mechanismsInfluence of pp ions on pion absorption in H2 S. Jonsell,1 J. Wallenius,2 and P. Froelich1 1 Institute for Theoretical Atomic and Molecular Physics, Harvard-Smithsonian Center for Astrophysics, 60

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Collision--induced absorption in dense atmospheres of cool stars  

SciTech Connect (OSTI)

In the atmosphere of the Sun the major interaction between the matter and the radiation is through light absorption by ions (predominantly the negative ion of hydrogen atoms), neutral atoms and a small amount of polar molecules. The majority of stars in the universe are, however, cooler and denser than our Sun, and for a large fraction of these, the above absorption processes are very weak. Here, collision-induced absorption (CIA) becomes the dominant opacity source. The radiation is absorbed during very short mutual passages ('collisions') of two non-polar molecules (and/or atoms), while their electric charge distributions are temporarily distorted which gives rise to a transient dipole moment. We present here a review of the present-day knowledge about the impact of collision-induced absorption processes on the structure and the spectrum of such stars.

Borysow, Aleksandra; Joergensen, Uffe Graae [Niels Bohr Institute, for Astronomy, Physics and Geophysics, University Observatory, Juliane Maries vej 30, DK-2100 Copenhagen (Denmark)

1999-04-01T23:59:59.000Z

422

EMSL - spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectroscopy en Behavior of nanoceria in biologically-relevant environments. http:www.emsl.pnl.govemslwebpublicationsbehavior-nanoceria-biologically-relevant-environments

423

WAVELENGTH MEASUREMENTS OF K TRANSITIONS OF OXYGEN, NEON, AND MAGNESIUM WITH X-RAY ABSORPTION LINES  

SciTech Connect (OSTI)

Accurate atomic transition data are important in many astronomical research areas, especially for studies of line spectroscopy. Whereas transition data of He-like and H-like ions (i.e., ions in high-charge states) have been accurately calculated, the corresponding data of K transitions of neutral or low-ionized metal elements are still very uncertain. Spectroscopy of absorption lines produced in the interstellar medium (ISM) has been proven to be an effective way to measure the central wavelengths of these atomic transitions. In this work, we analyze 36 Chandra High Energy Transmission Grating observations to search for and measure the ISM absorption lines along sight lines to 11 low-mass X-ray binaries. We correct the Galactic rotation velocity to the rest frame for every observation and then use two different methods to merge all the corrected spectra to a co-added spectrum. However, the co-added spectra obtained by this method exhibit biases, toward to either observations with high counts or lines with high signal-to-noise ratios. We do a Bayesian analysis of several significantly detected lines to obtain the systematic uncertainty and the bias correction for other lines. Compared to previous studies, our results improve the wavelength accuracy by a factor of two to five and significantly reduce the systematic uncertainties and biases. Several weak transitions (e.g., 1s-2p of Mg IV and Mg V; 1s-3p of Mg III and Mg V) are also detected for the first time, albeit with low significance; future observations with improved accuracy are required to confirm these detections.

Liao Jinyuan; Zhang Shuangnan [Key Laboratory of Particle Astrophysics, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Yao Yangsen, E-mail: zhangsn@ihep.ac.cn [Eureka Scientific, 2452 Delmer Street Suite 100, Oakland, CA 94602 (United States)

2013-09-10T23:59:59.000Z

424

Electronic states of NO{sub 2}-exposed H-terminated diamond/Al{sub 2}O{sub 3} heterointerface studied by synchrotron radiation photoemission and X-ray absorption spectroscopy  

SciTech Connect (OSTI)

The energy band-lineup and the electronic structure of NO{sub 2}-exposed H-terminated diamond/Al{sub 2}O{sub 3} heterointerface have been investigated by synchrotron radiation photoemission and x-ray absorption near-edge structure (XANES) measurements. It is found that the energy band-lineup is stagger-type, so-called type-II, with its valence band discontinuity of as high as 3.9?eV and its conduction band discontinuity of 2.7?eV. The valence band maximum of the H-terminated diamond surface is positioned at Fermi level as a result of high-density hole accumulation on the diamond side. The XANES measurement has shown that the oxygen-derived interface state locates at about 1–3?eV above the Fermi level.

Takahashi, Kazutoshi; Imamura, Masaki [Synchrotron Light Application Center, Saga University, Saga 840-8502 (Japan); Hirama, Kazuyuki [NTT Basic Research Laboratories, NTT Corporation, Atsugi 243-0198 (Japan); Kasu, Makoto [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan)

2014-02-17T23:59:59.000Z

425

Accepted Manuscript Laboratory-based recording of holographic fine structure in x-ray absorption  

E-Print Network [OSTI]

be only performed using synchrotron radiation. Keywords: x-ray absorption, atomic structure, xAccepted Manuscript Laboratory-based recording of holographic fine structure in x-ray absorption structure in x-ray absorption anisotropy using polycapillary optics, Nucl. Instr. and Meth. in Phys. Res. B

Korecki, Pawe³

426

New section of the HITRAN database: Collision-induced absorption (CIA)  

E-Print Network [OSTI]

New section of the HITRAN database: Collision-induced absorption (CIA) C. Richard a , I.E. Gordon for Astrophysics, Atomic and Molecular Physics Division, Cambridge, MA 02138, USA b University of Texas, Physics Keywords: Collision-induced absorption HITRAN Atmospheric absorption Interacting molecular pairs a b s t r

Chance, Kelly

427

Delay in Atomic Photoionization  

SciTech Connect (OSTI)

We analyze the time delay between emission of photoelectrons from the outer valence ns and np subshells in noble gas atoms following absorption of an attosecond extreme ultraviolet pulse. Various processes such as elastic scattering of the photoelectron on the parent ion and many-electron correlation affect the apparent 'time zero' when the photoelectron leaves the atom. This qualitatively explains the time delay between photoemission from the 2s and 2p subshells of Ne as determined experimentally by attosecond streaking [Science 328, 1658 (2010)]. However, with our extensive numerical modeling, we were only able to account for less than half of the measured time delay of 21{+-}5 as. We argue that the extreme ultraviolet pulse alone cannot produce such a large time delay and it is the streaking IR field that is most likely responsible for this effect.

Kheifets, A. S. [Research School of Physical Sciences, Australian National University, Canberra ACT 0200 (Australia); Kavli Institute for Theoretical Physics, University of California, Santa Barbara, California 93106-4030 (United States); Ivanov, I. A. [Research School of Physical Sciences, Australian National University, Canberra ACT 0200 (Australia)

2010-12-03T23:59:59.000Z

428

Using in situ X-ray absorption spectroscopy to study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}}  

SciTech Connect (OSTI)

To study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF) as a function of the oxygen partial pressure (P(O{sub 2})), in situ the Co and Fe K-edge X-ray absorption spectroscopy (XAS) was measured at elevated temperatures of 900 and 1000 K. The reduction of the Co and Fe valence, i.e., the oxygen content (3-{delta}) in LSCF, followed the change of P(O{sub 2}) from 1 to 10{sup -4} atm during{approx}4000 s. The quantitative analysis of the X-ray absorption near edge structure (XANES) and the extended X-ray absorption fine structure (EXAFS) indicated that the Fe valence was higher than the Co valence at oxidative condition ({delta} Almost-Equal-To 0) in LSCF. Whereas the Co valence decreased more than the Fe valence after reduction of P(O{sub 2}) at both 900 and 1000 K. From the relaxation plots of the valence and the oxygen content (3-{delta}) for Co and Fe after changing P(O{sub 2}), we successfully determined D{sub chem} and E{sub a} of an oxygen ion migration around Co and Fe in LSCF. A structural model with and without oxygen vacancies and an oxygen ion conduction mechanism for LSCF are proposed based on these results. - Graphical abstract: A structural model with and without oxygen vacancies, and the oxygen ion conduction mechanism of LSCF were speculated. In other words, oxygen vacancies would form more preferentially around Co than Fe from the results of in situ XAS analysis during reduction, and oxygen ions needs to pass through at the vicinity of Fe from the results of D{sub chem} and E{sub a}. Highlights: Black-Right-Pointing-Pointer Study of the oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF). Black-Right-Pointing-Pointer Using in situ X-ray absorption for study of valence and oxygen diffusion coefficient. Black-Right-Pointing-Pointer The oxygen vacancies should be preferentially localized around Co in LSCF. Black-Right-Pointing-Pointer The values of the dynamics parameters for Co and Fe are close to each other.

Itoh, Takanori, E-mail: tknitoh@seimichemical.co.jp [AGC SeimiChemical Co., Ltd., 3-2-10 Chigasaki, Chigasaki City, Kanagawa 253-8585 (Japan); Nakayama, Masanobu [Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya-city, Aichi 466-8555 (Japan)

2012-08-15T23:59:59.000Z

429

Study of clusters using negative ion photodetachment spectroscopy  

SciTech Connect (OSTI)

The weak van der Waals interaction between an open-shell halogen atom and a closed-shell atom or molecule has been investigated using zero electron kinetic energy (ZEKE) spectroscopy. This technique is also applied to study the low-lying electronic states in GaAs and GaAs{sup {minus}}. In addition, the spectroscopy and electron detachment dynamics of several small carbon cluster anions are studied using resonant multiphoton detachment spectroscopy.

Zhao, Yuexing

1995-12-01T23:59:59.000Z

430

E-Print Network 3.0 - atomic spectra Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1... in alternate points between emission and absorption peaks. 2Figure b. In EIT or absorption spectra, Input... , aa>bb. atomic coherence , , aa< Source: Wang, Wei Hua - Key...

431

Li et al., Aerosol and Air Quality Research, Vol. 6, No. 4, pp. 418-429, 2006 UV-Absorption-Based Measurements of Ozone and Mercury  

E-Print Network [OSTI]

interferences. For example, CMMs based on atomic absorption spectrometry (AAS) are subject to interferences of the Hg detection technique. Atomic absorption spectrometry (AAS) is one of the major techniques appliedLi et al., Aerosol and Air Quality Research, Vol. 6, No. 4, pp. 418-429, 2006 UV-Absorption

Li, Ying

432

E-Print Network 3.0 - atomic scale structure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic scale structure Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine Structure...

433

E-Print Network 3.0 - atomic explosions Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Within... to Coulomb explosion (Last and Jortner, 2000). Calculation of the energy absorption of atomic clusters... these results with kinetic energy of the ions coming from...

434

E-Print Network 3.0 - atomic dark resonances Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ronald L. - Department of Physics, Harvard University Collection: Physics 10 A Novel Absorption Resonance for Atomic Clocks David F. Phillips , Irina Novikova, Sergei Zibrov,...

435

E-Print Network 3.0 - atomic fluorescence spectrometry Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avril1994 Summary: down to about 310 nm. Such powers are sufficient for laser atomic absorption spectrometry (LAAS... spectrometry where the low-frequency noise of the...

436

E-Print Network 3.0 - absorber-materials atomic numbers Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

. With two laser sources, however, quantum interference can be used to ensure that atomic absorption... is eliminated, while retaining a large nonlinear response. A downside...

437

E-Print Network 3.0 - atoms two-photon above-threshold Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

created, which can be considered above threshold ionization ATI . Unlike in the seminal atomic ATI studies... absorption of four laser photons, equivalent to 20 eV excitation...

438

E-Print Network 3.0 - atomic vapor laser Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with the exception of pagination. IEEE TRANSACTIONS ON PLASMA SCIENCE 1 Summary: vapor, atomic physics and vapor ionization, absorption reflection in a heated plasma layer, and...

439

E-Print Network 3.0 - atomic number materials Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic number materials Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine...

440

E-Print Network 3.0 - atomic emission determination Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emission... cool- ing. The spontaneous emission events produce unpre- dictable changes in atomic momenta so... of absorption and emission can cause a large change of the ......

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

E-Print Network 3.0 - atomic orbitals calculation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

THE EUROPEAN Summary: Stark eects 1 Introduction Periodic-orbit theory and, variant atomic photo-absorption spectra, closed-orbit... calculated classical properties closed...

442

E-Print Network 3.0 - atomic binding energy Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

energy Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic binding energy Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine Structure...

443

E-Print Network 3.0 - atomic photoabsorption process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

process Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic photoabsorption process Page: << < 1 2 3 4 5 > >> 1 Absorption Spectra and...

444

E-Print Network 3.0 - atomic radiation unscear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Acronyms, Abbreviations, Symbols, and Notation A.1.0 Acronyms And Abbreviations AA Atomic absorption ASCII... -hydroxyethyl) ethylenedinitrilotriacetic acid HLW High level...

445

E-Print Network 3.0 - atomic fluorescence spectrometric Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Selenium by Fluorescence Spectrometry Summary: MATERIALS 129 5. Ihnat. M.. Atomic absorption spectrometric determination of selenium with carbon furnace... I...

446

E-Print Network 3.0 - atomic emission analysis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emission... cool- ing. The spontaneous emission events produce unpre- dictable changes in atomic momenta so... of absorption and emission can cause a large change of the ......

447

E-Print Network 3.0 - atomic scale images Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in the scattering of light by a condensate Summary: , and atoms at 45 degrees. (b-g) Absorption images after 20 ms time-of-flight show the atomic momentum... appears to be...

448

E-Print Network 3.0 - all-optical miniature atomic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Instituut, Quantum Gases and Atom Optics Group Collection: Physics 5 Three-photon-absorption resonance for all-optical atomic clocks Sergei Zibrov,1,2,3,4 Summary:...

449

Double core-hole spectroscopy of transient plasmas produced in the interaction of ultraintense x-ray pulses with neon  

E-Print Network [OSTI]

Double core-hole (DCH) spectroscopy is investigated systematically for neon atomic system in the interaction with ultraintense x-ray pulses with photon energy from 937 eV to 2000 eV. A time-dependent rate equation, implemented in the detailed level accounting approximation, is utilized to study the dynamical evolution of the level population and emission properties of the highly transient plasmas. For x-ray pulses with photon energy in the range of 937-1030 eV, where $1s\\rightarrow 2p$ resonance absorption from single core-hole (SCH) states of neon charge states exist, inner-shell resonant absorption (IRA) effects play important roles in the time evolution of population and DCH spectroscopy. Such IRA physical effects are illustrated in detail by investigating the interaction of x-ray pulses at a photon energy of 944 eV, which corresponds to the $1s\\rightarrow 2p$ resonant absorption from the SCH states ($1s2s^22p^4$, $1s2s2p^5$ and $1s2p^6$) of Ne$^{3+}$. After averaging over the space and time distribution o...

Gao, Cheng; Yuan, Jianmin

2015-01-01T23:59:59.000Z

450

Balmer Absorption Lines in FeLoBALs  

E-Print Network [OSTI]

We discovered non-stellar Balmer absorption lines in two many-narrow-trough FeLoBALs (mntBALs) by the near-infrared spectroscopy with Subaru/CISCO. Presence of the non-stellar Balmer absorption lines is known to date only in the Seyfert galaxy NGC 4151, thus our discovery is the first cases for quasars. Since all known active galactic nuclei with Balmer absorption lines share characteristics, it is suggested that there is a population of BAL quasars which have unique structures at their nuclei or unique evolutionary phase.

K. Aoki; I. Iwata; K. Ohta; N. Tamura; M. Ando; M. Akiyama; G. Kiuchi; K. Nakanishi

2006-12-14T23:59:59.000Z

451

Magneto-optical resonance of electromagnetically induced absorption with high contrast and narrow width in a vapour cell with buffer gas  

E-Print Network [OSTI]

The method for observing the high-contrast and narrow-width resonances of electromagnetically induced absorption (EIA) in the Hanle configuration under counterpropagating light waves is proposed. We theoretically analyze the absorption of a probe light wave in presence of counterpropagating one with the same frequency as the function of a static magnetic field applied along the vectors of light waves, propagating in a vapour cell. Here, as an example, we study a "dark" type of atomic dipole transition Fg=1-->Fe=1 in D1 line of 87Rb, where usually the electromagnetically induced transparency (EIT) can be observed. To obtain the EIA signal one should proper chose the polarizations of light waves and intensities. In contrast of regular schemes for observing EIA signals (in a single travelling light wave in the Hanle configuration or in a bichromatic light field consisted of two travelling waves), the proposed scheme allows one to use buffer gas to significantly enhance properties of the resonance. Also the dramatic influence of atomic transition openness on contrast of the resonance is revealed, that gives great advantage in comparison with cyclic atomic transitions. The obtained results can be interesting in high-resolution spectroscopy, nonlinear and magneto-optics.

D. V. Brazhnikov; A. V. Taichenachev; V. I. Yudin

2014-08-11T23:59:59.000Z

452

Resonance ionization for analytical spectroscopy  

DOE Patents [OSTI]

This invention relates to a method for the sensitive and selective analysis of an atomic or molecular component of a gas. According to this method, the desired neutral component is ionized by one or more resonance photon absorptions, and the resultant ions are measured in a sensitive counter. Numerous energy pathways are described for accomplishing the ionization including the use of one or two tunable pulsed dye lasers.

Hurst, George S. (Oak Ridge, TN); Payne, Marvin G. (Harriman, TN); Wagner, Edward B. (Burchfield Heights, TN)

1976-01-01T23:59:59.000Z

453

Atom Interferometry  

ScienceCinema (OSTI)

Atom de Broglie wave interferometry has emerged as a tool capable of addressing a diverse set of questions in gravitational and condensed matter physics, and as an enabling technology for advanced sensors in geodesy and navigation. This talk will review basic principles, then discuss recent applications and future directions. Scientific applications to be discussed include measurement of G (Newton?s constant), tests of the Equivalence Principle and post-Newtonian gravity, and study of the Kosterlitz-Thouless phase transition in layered superfluids. Technology applications include development of precision gryoscopes and gravity gradiometers. The talk will conclude with speculative remarks looking to the future: Can atom interference methods be sued to detect gravity waves? Can non-classical (entangled/squeezed state) atom sources lead to meaningful sensor performance improvements?

Mark Kasevich

2010-01-08T23:59:59.000Z

454

Rotational Spectroscopy of PAHs: Acenaphthene, Acenaphthylene and Fluorene  

E-Print Network [OSTI]

Pure rotational spectra of three polycyclic aromatic hydrocarbons - acenaphthene, acenaphthylene and fluorene - have been obtained by Fourier transform microwave spectroscopy of a molecular beam and subsequently by millimeter wave absorption spectroscopy for acenaphthene and fluorene. The data presented here will be useful for deep radio astronomical searches for PAHs employing large radio telecopes.

Thorwirth, S; Gottlieb, C A; McCarthy, M C; Thaddeus, P

2005-01-01T23:59:59.000Z

455

Rotational Spectroscopy of PAHs: Acenaphthene, Acenaphthylene and Fluorene  

E-Print Network [OSTI]

Pure rotational spectra of three polycyclic aromatic hydrocarbons - acenaphthene, acenaphthylene and fluorene - have been obtained by Fourier transform microwave spectroscopy of a molecular beam and subsequently by millimeter wave absorption spectroscopy for acenaphthene and fluorene. The data presented here will be useful for deep radio astronomical searches for PAHs employing large radio telecopes.

S. Thorwirth; P. Theule; C. A. Gottlieb; M. C. McCarthy; P. Thaddeus

2005-09-23T23:59:59.000Z

456

Absorption heat pump system  

DOE Patents [OSTI]

The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

Grossman, G.

1982-06-16T23:59:59.000Z

457

Absorption heat pump system  

DOE Patents [OSTI]

The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

Grossman, Gershon (Oak Ridge, TN)

1984-01-01T23:59:59.000Z

458

Quantitative tunneling spectroscopy of nanocrystals  

SciTech Connect (OSTI)

The proposed goals of this collaborative work were to systematically characterize the electronic structure and dynamics of 3-dimensional metal and semiconducting nanocrystals using scanning tunneling microscopy/spectroscopy (STM/STS) and ballistic electron emission spectroscopy (BEES). This report describes progress in the spectroscopic work and in the development of methods for creating and characterizing gold nanocrystals. During the grant period, substantial effort also was devoted to the development of epitaxial graphene (EG), a very promising materials system with outstanding potential for nanometer-scale ballistic and coherent devices ("graphene" refers to one atomic layer of graphitic, sp2 -bonded carbon atoms [or more loosely, few layers]). Funding from this DOE grant was critical for the initial development of epitaxial graphene for nanoelectronics

First, Phillip N; Whetten, Robert L; Schaaff, T Gregory

2007-05-25T23:59:59.000Z

459

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2003-10-14T23:59:59.000Z

460

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2004-08-31T23:59:59.000Z

Note: This page contains sample records for the topic "atomic absorption spectroscopy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Seven-effect absorption refrigeration  

DOE Patents [OSTI]

A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit. 1 fig.

DeVault, R.C.; Biermann, W.J.

1989-05-09T23:59:59.000Z

462

Seven-effect absorption refrigeration  

DOE Patents [OSTI]

A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit.

DeVault, Robert C. (Knoxville, TN); Biermann, Wendell J. (Fayetteville, NY)

1989-01-01T23:59:59.000Z

463

96 $+& &%XS&~S*#* % (Fi) 28 W**+#*) .~R*%A**% #+a +4fi4ti % #+El&% 2603 % 3 R % 1 R *$v*&%%%B4+%  

E-Print Network [OSTI]

measurement (j) Spectral interferenceand chemicalinterferencefor atomic absorption spectroscopy. 2. (10 absorption spectrometry, the absorption behavior of atoms or ions are also caused by the promotion results, the absorption spectraof atomic and molecular species are quiet different, which one is line

Huang, Haimei

464

Spectroscopic Observation of Resonant Electric Dipole-Dipole Interactions between Cold Rydberg Atoms  

E-Print Network [OSTI]

Atoms K. Afrousheh, P. Bohlouli-Zanjani, D. Vagale, A. Mugford, M. Fedorov, and J. D. D. Martin between cold Rydberg atoms were observed using microwave spectroscopy. Laser-cooled 85Rb atoms pulse transferred a fraction of these Rydberg atoms to the 46p3=2 state. A second microwave pulse

Le Roy, Robert J.

465

Photon interference effect in x-ray absorption spectra over a wide energy range Y. Nishino and T. Ishikawa  

E-Print Network [OSTI]

. Therefore the atomic absorption coeffi- cient a is given by a a PI a ES a Incoh , 1 where a PI , a ESPhoton interference effect in x-ray absorption spectra over a wide energy range Y. Nishino and T Received 3 July 2002; published 12 September 2002 We consider fundamental structures in x-ray absorption

Korecki, Pawe³

466

Laboratory-based recording of holographic fine structure in X-ray absorption anisotropy using polycapillary optics  

E-Print Network [OSTI]

10 April 2012 Available online 17 May 2012 Keywords: X-ray absorption Atomic structure XLaboratory-based recording of holographic fine structure in X-ray absorption anisotropy using) was characterized and used for recording two-dimensional maps of X-ray absorption anisotropy (XAA). XAA originates

Korecki, Pawe³

467

Ultrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations  

E-Print Network [OSTI]

13­20 to generate ultrafast x-ray pulses, however, the prospect of ultrafast EXAFS seems encouragingUltrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations Frank L by the recent experimental demonstration of ultrafast x-ray absorption spectroscopy, we present a framework

Cao, Jianshu

468

Polarization from aligned atoms as a diagnostics of circumstellar, AGN and interstellar magnetic fields: II. Atoms with Hyperfine Structure  

E-Print Network [OSTI]

We show that atomic alignment presents a reliable way to study topology of astrophysical magnetic fields. The effect of atomic alignment arises from modulation of the relative population of the sublevels of atomic ground state pumped by anisotropic radiation flux. As such aligned atoms precess in the external magnetic field and this affects the properties of the polarized radiation arising from both scattering and absorption by the atoms. As the result the polarizations of emission and absorption lines depend on the 3D geometry of the magnetic field as well as the direction and anisotropy of incident radiation. We consider a subset of astrophysically important atoms with hyperfine structure. For emission lines we obtain the dependencies of the direction of linear polarization on the directions of magnetic field and the incident pumping radiation. For absorption lines we establish when the polarization is perpendicular and parallel to magnetic field. For both emission and absorption lines we find the dependence on the degree of polarization on the 3D geometry of magnetic field. We claim that atomic alignment provides a unique tool to study magnetic fields in circumstellar regions, AGN, interplanetary and interstellar medium. This tool allows studying of 3D topology of magnetic fields and establish other important astrophysical parameters. We consider polarization arising from both atoms in the steady state and also as they undergo individual scattering of photons. We exemplify the utility of atomic alignment for studies of astrophysical magnetic fields by considering a case of Na alignment in a comet wake.

Huirong Yan; A. Lazarian

2006-11-09T23:59:59.000Z

469

Potassium emission absorption system. Topical report 12  

SciTech Connect (OSTI)

The Potassium Emission Absorption System is one of the advanced optical diagnostics developed at Mississippi State University to provide support for the demonstration of prototype-scale coal-fired combustion magnetohydrodynamic (MHD) electrical power generation. Intended for application in the upstream of an MHD flow, the system directly measures gas temperature and neutral potassium atom number density through spectroscopic emission absorption techniques. From these measurements the electron density can be inferred from a statistical equilibrium calculation and the electron conductivity in the MHD channel found by use of an electron mobility model. The instrument has been utilized for field test measurements on MHD facilities for almost a decade and has been proven to provide useful measurements as designed for MHD nozzle, channel, and diffuser test sections. The theory of the measurements, a system description, its capabilities, and field test measurement results are reported here. During the development and application of the instrument several technical issues arose which when addressed advanced the state of the art in emission absorption measurement. Studies of these issues are also reported here and include: two-wavelength measurements for particle-laden flows, potassium D-line far wing absorption coefficient, bias in emission absorption measurements arising from dirty windows and misalignments, non-coincident multiwavelength emission absorption sampling errors, and lineshape fitting for boundary layer flow profile information. Although developed for NLHD application, the instrument could be applied to any high temperature flow with a resonance line in the 300 to 800 nm range, for instance other types of flames, rocket plumes or low temperature plasmas.

Bauman, L.E.

1995-04-01T23:59:59.000Z

470

E-Print Network 3.0 - absorption spectrophotometry fi-faas Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

method 7060A) Arsenic concentrations in the plants were relatively low... furnace atomic absorption spectrophotometry. . The samples will also be analyzed to pH using a pH...

471

E-Print Network 3.0 - absorption line survey Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Printed in U.S.A. Summary: . They also found a hint of the expected narrow 1s2p absorption line in atomic O. We obtained a high... cant line emission. Instead, a number...

472

E-Print Network 3.0 - angle x-ray absorption Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FROM PLANETS AND COMETS: RELATIONSHIP WITH SOLAR X-RAYS AND SOLAR WIND Summary: in the atomic and molecular constituents of the atmosphere, and 2) the absorption of incident...

473

Nuclear absorption of low energy pions and the pion-nucleus optical potential  

SciTech Connect (OSTI)

The energy dependence of the optical model parameters for low energy, 0--50 MeV, pions was determined by a compromise fit to pionic atoms, ..pi../sup +/ elastic scattering and ..pi../sup - +/ absorption mesurements.

Carr, J.A.; McManus, H.; Stricker-Bauer, K.

1982-02-01T23:59:59.000Z

474

Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned...

475

AAS, see Atomic absorption spectrometry Acanthes lanceolata, 138  

E-Print Network [OSTI]

hydrocarbons AIDS patients, 625 Air pollution monitoring equipment, 312 sources, 475 Air handling, 271 mine drainage, 74 precipitation, 74 storage cabinets, 738 volatile sulfides (AVS grunniens, 415 Applied statistics, 576 Aquarium air stone, suction using, 329 Aquatic assessments

Pitt, Robert E.

476

Absorption heat pump system  

DOE Patents [OSTI]

An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

Grossman, Gershon (Oak Ridge, TN); Perez-Blanco, Horacio (Knoxville, TN)

1984-01-01T23:59:59.000Z

477

H I Self Absorption Toward Molecular Clouds: Theoretical Models  

E-Print Network [OSTI]

information and available data, visit the GRS web page at www.bu.eduwww.bu.edu/G/GRSRS References chemistry deep inside the molecular clouds. We study H I self- absorption toward molecular clouds is dominated by cold atomic hydrogen formed by cosmic ray chemistry deep in the interiors of clouds. If all

478

The physical interest in kaonic- and antiprotonic-deuterium atoms  

E-Print Network [OSTI]

Exotic deuterium and helium are discussed. The S, P and D levels of antiprotonic and kaonic atoms are calculated. Absorptive, subthreshold antiproton-nucleon amplitudes are extracted from experimental data and compared to model calculations. The existence of a quasi-bound state in the antiproton-nucleon system is indicated. In the kaonic atoms some effects of the Sigma(1385) resonance are evaluated.

S. Wycech; B. Loiseau

2005-08-05T23:59:59.000Z

479

Solar Spectroscopy at ARIES  

E-Print Network [OSTI]

Identification of Fraunhofer lines with the known atomic and molecular absorbers and predictions leading to such an effort has been a challenging area of study crowned with occasional success. Such studies have also lead, amongst other things to (i) a determination of abundances of elements and that of their isotopes (ii) valuable information on model atmospheres and (iii) use of Sun as a laboratory source. We summarize and review here the work done in the last four decades in the area of solar spectroscopy at Aryabhatta Research Institute of observational sciencES (ARIES in short) with a view to pick up new and interesting areas for future investigations in the light of the tremendous progress made elsewhere in observations of the sun and in the laboratory studies.

K. Sinha

2006-10-10T23:59:59.000Z

480

Progress towards an accurate determination of the Boltzmann constant by Doppler spectroscopy  

E-Print Network [OSTI]

, 27] consists in recording the Doppler profile of a well- isolated absorption line of an atomic absorption profile of a line in a gas of ammonia at thermal equilibrium. This optical method based) ppm broadening of the absorption linewidth. We also show that, in our well chosen experimental

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481

TENDER ENERGY X-RAY ABSORPTION SPECTROSCOPY (TES)  

E-Print Network [OSTI]

productivity at the earliest possible date. · Strategy combines in-house and external aspects to create world IMPACT: · Energy Materials: Photovoltaic, fuel-cell, battery and superconducting (nano

Ohta, Shigemi

482

X-ray Absorption Spectroscopy of Biologically Relevant Systems  

E-Print Network [OSTI]

of the interaction of the carboxylate with lithium; this isinteractions of carboxylate with the monovalent cations lithium,lithium acetate revealing distinct shifts between the cations, indicative of preferential interactions.

Uejio, Janel Sunayo

2010-01-01T23:59:59.000Z

483

Absorption spectroscopy in solid hydrogen: challenges to experimentalists and theorists  

E-Print Network [OSTI]

-rotational spectra. However, when they interact in the gas, liquid, or solid, there are induced dipoles that can comparisons between theory and experiment. From this analysis, we can draw a number of conclusions about-forbidden exhibits an infrared spectrum in the condensed phase caused by multipolar induction. Solid hydrogens

484

Combining Feedback Absorption Spectroscopy, Amplified Resonance and Low  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth Codes andDepartment ofPressure Sampling for the

485

INFRARED ABSORPTION SPECTROSCOPY AND CHEMICAL KINETICS OF FREE RADICALS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching. | EMSL Bubblesstructure linkLet's Get to67006

486

Intrinsic AGN Absorption Lines  

E-Print Network [OSTI]

Strong absorption lines are common in rest-frame UV spectra of AGNs due to a variety of resonant transitions, for example the HI Lyman series lines (most notably Ly-alpha 1216) and high-ionization doublets like CIV 1549,1551. The lines are called ``intrinsic'' if the absorbing gas is physically related to the AGN, e.g. if the absorber resides broadly within the radius of the AGN's surrounding ``host'' galaxy. Intrinsic absorption lines are thus valuable probes of the kinematics, physical conditions and elemental abundances in the gas near AGNs. Studies of intrinsic absorbers have historically emphasized the broad absorption lines (BALs) in quasars. Today we recognize a wider variety of intrinsic lines in a wider range of objects. For example, we now know that Seyfert 1 galaxies (the less luminous cousins of quasars) have intrinsic absorption. We also realize that intrinsic lines can form in a range of AGN environments --- from the dynamic inner regions like the BALs, to the more quiescent outer host galaxies >10 kpc away. This article provides a brief introduction to current observational and theoretical work on intrinsic AGN absorbers.

Fred Hamann

2000-06-12T23:59:59.000Z

487

Where Water is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster from X-ray Spectroscopy  

SciTech Connect (OSTI)

Light-driven oxidation of water to dioxygen in plants, algae and cyanobacteria iscatalyzed within photosystem II (PS II) by a Mn4Ca cluster. Although the cluster has been studied by many different methods, the structure and the mechanism have remained elusive. X-ray absorption and emission spectroscopy and EXAFS studies have been particularly useful in probing the electronic and geometric structure, and the mechanism of the water oxidation reaction. Recent progress, reviewed here, includes polarized X-ray absorption spectroscopy measurements of PS II single crystals. Analysis of those results has constrained the Mn4Ca cluster geometry to a setof three similar high-resolution structures. The structure of the cluster from the present study is unlike either the 3.0 or 3.5 Angstrom-resolution X-ray structures or other previously proposed models. The differences between the models derived from X-rayspectroscopy and crystallography are predominantly because of damage to the Mn4Ca cluster by X-rays under the conditions used for structure determination by X-ray crystallography. X-ray spectroscopy studies are also used for studying the changes in the structure of the Mn4Ca catalytic center as it cycles through the five intermediate states known as the Si-states (i=0-4). The electronic structure of the Mn4Ca cluster has been studied more recently using resonant inelastic X-ray scattering spectroscopy (RIXS), in addition to the earlier X-ray absorption and emission spectroscopy methods. These studies are revealing that the assignment of formaloxidation states is overly simplistic. A more accurate description should consider the charge density on the Mn atoms that includes the covalency of the bonds and delocalization of the charge over the cluster. The geometric and electronic structure of the Mn4Ca cluster in the S-states derived from X-ray spectroscopy are leading to a detailed understanding of the mechanism of the O-O bond formation during the photosynthetic water splitting process.

Yano, Junko; Yano, Junko; Yachandra, Vittal K.

2007-10-24T23:59:59.000Z

488

E-Print Network 3.0 - absorption gas imaging Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NUMBER 16 P H Y S I C A L R E V I E W L E T T E R S 21 APRIL 1997 High Intensity Laser Absorption by Gases of Atomic Clusters Summary: backing pressure the absorption fraction...

489

Absorption free superluminal light propagation in a three level pump-probe system  

E-Print Network [OSTI]

We investigate the dispersion and the absorption properties of a weak probe field in a three-level pump-probe atomic system. It is shown that the slope of dispersion changes from positive to negative just with the intensity of the coherent or indirect incoherent pumping fields. It is demonstrated that the absorption free superluminal light propagation is appeared in this system.

M. Mahmoudi; S. Worya Rabiei; L. Ebrahimi Zohravi; M. Sahrai

2007-11-21T23:59:59.000Z

490

Ligand effects on the X-ray absorption of a nickel porphyrin complex: a simulation study  

E-Print Network [OSTI]

.elsevier.com/locate/chemphys #12;where W l PP stands for the atomic absorption spectrum for the lth site: W l PP ¼ 1 2 1 X2 x R ZLigand effects on the X-ray absorption of a nickel porphyrin complex: a simulation study Luke Abstract We present a simulation of the X-ray absorption near-edge spectrum (XANES) of the metal porphyrin

Mukamel, Shaul

491

Observation of relativistic antihydrogen atoms  

SciTech Connect (OSTI)

An observation of relativistic antihydrogen atoms is reported in this dissertation. Experiment 862 at Fermi National Accelerator Laboratory observed antihydrogen atoms produced by the interaction of a circulating beam of high momentum (3 < p < 9 GeV/c) antiprotons and a jet of molecular hydrogen gas. Since the neutral antihydrogen does not bend in the antiproton source magnets, the detectors could be located far from the interaction point on a beamline tangent to the storage ring. The detection of the antihydrogen is accomplished by ionizing the atoms far from the interaction point. The positron is deflected by a magnetic spectrometer and detected, as are the back to back photons resulting from its annihilation. The antiproton travels a distance long enough for its momentum and time of flight to be measured accurately. A statistically significant sample of 101 antihydrogen atoms has been observed. A measurement of the cross section for {bar H}{sup 0} production is outlined within. The cross section corresponds to the process where a high momentum antiproton causes e{sup +} e{sup -} pair creation near a nucleus with the e{sup +} being captured by the antiproton. Antihydrogen is the first atom made exclusively of antimatter to be detected. The observation experiment's results are the first step towards an antihydrogen spectroscopy experiment which would measure the n = 2 Lamb shift and fine structure.

Blanford, Glenn DelFosse

1998-01-01T23:59:59.000Z

492

Novel rubidium atomic beam with an alkali dispenser source  

SciTech Connect (OSTI)

We describe a novel atomic beam apparatus with a resistively heated alkali dispenser source and a cold-pumped intermediate chamber. Using laser fluorescence spectroscopy we have measured the atomic density to be 3x10{sup 11} atoms/m{sup 3} and the total flux to be 5x10{sup 8} atoms/s in a 0.3 cm diameter beam. We have also characterized the velocity distribution of the source based on the Doppler-shifted fluorescence spectrum. The compact geometry, flexibility, and simplicity of the beam may make it useful as an optical frequency reference or for experiments on atom-cooling.

Roach, Timothy M.; Henclewood, Dwayne [College of the Holy Cross, Worcester, Massachusetts 01610 (United States)

2004-11-01T23:59:59.000Z

493

The Quantum Absorption Refrigerator  

E-Print Network [OSTI]

A quantum absorption refrigerator driven by noise is studied with the purpose of determining the limitations of cooling to absolute zero. The model consists of a working medium coupled simultaneously to hot, cold and noise baths. Explicit expressions for the cooling power are obtained for Gaussian and Poisson white noise. The quantum model is consistent with the first and second laws of thermodynamics. The third law is quantified, the cooling power J_c vanishes as J_c proportional to T_c^{alpha}, when T_c approach 0, where alpha =d+1 for dissipation by emission and absorption of quanta described by a linear coupling to a thermal bosonic field, where d is the dimension of the bath.

Amikam Levy; Ronnie Kosloff

2011-11-09T23:59:59.000Z

494

Atomic magnetometer  

DOE Patents [OSTI]

An atomic magnetometer is disclosed which uses a pump light beam at a D1 or D2 transition of an alkali metal vapor to magnetically polarize the vapor in a heated cell, and a probe light beam at a different D2 or D1 transition to sense the magnetic field via a polarization rotation of the probe light beam. The pump and probe light beams are both directed along substantially the same optical path through an optical waveplate and through the heated cell to an optical filter which blocks the pump light beam while transmitting the probe light beam to one or more photodetectors which generate electrical signals to sense the magnetic field. The optical waveplate functions as a quarter waveplate to circularly polarize the pump light beam, and as a half waveplate to maintain the probe light beam linearly polarized.

Schwindt, Peter (Albuquerque, NM); Johnson, Cort N. (Albuquerque, NM)

2012-07-03T23:59:59.000Z

495

Theoretical standards in x-ray spectroscopies  

SciTech Connect (OSTI)

We propose to extend our state-of-the-art, ab initio XAFS (X-ray absorption fine structure) codes, FEFF. Our current work has been highly successful in achieving accurate, user-friendly XAFS standards, exceeding the performance of both tabulated standards and other codes by a considerable margin. We now propose to add the capability to treat more complex materials. This includes multiple-scattering, polarization dependence, an approximate treatment of XANES (x-ray absorption near edge structure), and other improvements. We also plan to adapt FEFF to other spectroscopies, e.g. photoelectron diffraction (PD) and diffraction anomalous fine structure (DAFS).

Not Available

1992-01-01T23:59:59.000Z

496

favour of atoms must be interpreted as evi-dence for their inner complexity. The pres-  

E-Print Network [OSTI]

favour of atoms must be interpreted as evi- dence for their inner complexity. The pres- ence of absorption and plasma spectra alone suggests that atoms must contain vibrating elements. Another problem presented by atomic theory concerns the possibility of extending the concepts of our

Rose, William I.

497

Moisture absorption modeling using design of experiments  

E-Print Network [OSTI]

Moisture Absorption Modeling Using Design of Experimentssurface pro?les of moisture absorption for the two laminatetheir amounts of moisture absorption are different. The

Yong, Virginia; Hahn, H. Thomas

2006-01-01T23:59:59.000Z

498

X-ray absorption spectroscopic studies of the dinuclear iron center in methane monooxygenase and the sulfure and chlorine centers in photographic materials  

SciTech Connect (OSTI)

The dinuclear iron center of the hydroxylase component of soluble methane monooxygenase (MMO) from Methylococcus capsulatus and Methylosinus trichosporiwn has been studied by X-ray absorption spectroscopy. Analysis of the Fe K-edge EXAFS revealed that the first shell coordination of the Fe(HI)Fe(IH) oxidized state of the hydroxylase from M. capsulatus consists of approximately 6 N and 0 atoms at an average distance of 2.04 {Angstrom}. The Fe-Fe distance was determined to be 3.4 {Angstrom}. No evidence for the presence of a short oxo bridge in the iron center of the oxidized hydroxylase was found, suggesting that the active site of MMO is significantly different from the active sites of the dinuclear iron proteins hemery and ribonucleotide reductase. In addition, the results of the first shell fits suggest that there are more oxygen than nitrogen donor ligands.

DeWitt, J.G.

1992-12-01T23:59:59.000Z

499

X-ray absorption spectroscopic studies of the dinuclear iron center in methane monooxygenase and the sulfure and chlorine centers in photographic materials  

SciTech Connect (OSTI)

The dinuclear iron center of the hydroxylase component of soluble methane monooxygenase (MMO) from Methylococcus capsulatus and Methylosinus trichosporiwn has been studied by X-ray absorption spectroscopy. Analysis of the Fe K-edge EXAFS revealed that the first shell coordination of the Fe(HI)Fe(IH) oxidized state of the hydroxylase from M. capsulatus consists of approximately 6 N and 0 atoms at an average distance of 2.04 [Angstrom]. The Fe-Fe distance was determined to be 3.4 [Angstrom]. No evidence for the presence of a short oxo bridge in the iron center of the oxidized hydroxylase was found, suggesting that the active site of MMO is significantly different from the active sites of the dinuclear iron proteins hemery and ribonucleotide reductase. In addition, the results of the first shell fits suggest that there are more oxygen than nitrogen donor ligands.

DeWitt, J.G.

1992-12-01T23:59:59.000Z

500

Antiproton Absorption in Nuclei  

E-Print Network [OSTI]

We present the analysis of experimental data on forward antiproton production on nuclei. The calculations are done in the framework of a folding model which takes properly into account both incoherent direct proton-nucleon and cascade pion-nucleon antiproton production processes as well as internal nucleon momentum distribution. The effective antiproton-nucleon cross section in nuclear matter and the imaginary part of the antiproton nuclear optical potential are estimated to be 25-45 mb and -(38-56) MeV at normal nuclear matter density, respectively. The results of the performed analysis evidence for the decreasing of antiproton absorption in the nuclear medium.

Yu. T. Kiselev; E. Ya. Paryev

2006-01-24T23:59:59.000Z