Sample records for atmospheric trace gas

  1. Role of trace impurities in large-volume noble gas atmospheric-pressure glow discharges

    E-Print Network [OSTI]

    Raja, Laxminarayan L.

    Role of trace impurities in large-volume noble gas atmospheric-pressure glow discharges Xiaohui. Large-volume APG discharges find numerous applications in processing of material surfaces,1 ozone-purity helium is presented, and the role of trace impurities in such noble gas plasmas is established. Trace

  2. atmospheric trace gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: enrichments of 22.8 f 2.2 in the concentrations of Ir, SC and the rare earths relative to Cl chondrites of refractory trace metals from a gas of solar...

  3. Laser Spectroscopic Trace-Gas Sensor Networks for Atmospheric Monitoring Applications

    E-Print Network [OSTI]

    Zhong, Lin

    a laser based chemical sensing technology with wide-area autonomous wireless sensor networking@princeton.edu ABSTRACT Laser-based atmospheric trace-gas sensors have great potential for long-term, real such as CO2, NOx, and methane with exceptionally high specificity. Categories and Subject Descriptors C.3

  4. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R. (Littleton, CO); Weimer, Carl S. (Littleton, CO); Nelson, Loren D. (Evergreen, CO); O'Brien, Martin J. (Pine, CO)

    2003-01-01T23:59:59.000Z

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  5. Laboratory measurements and modeling of trace atmospheric species

    E-Print Network [OSTI]

    Sheehy, Philip M. (Philip Michael)

    2005-01-01T23:59:59.000Z

    Trace species play a major role in many physical and chemical processes in the atmosphere. Improving our understanding of the impact of each species requires a combination of laboratory exper- imentation, field measurements, ...

  6. Tracing Noble Gas Radionuclides in the Environment

    E-Print Network [OSTI]

    P. Collon; W. Kutschera; Z. -T. Lu

    2004-02-11T23:59:59.000Z

    Trace analysis of radionuclides is an essential and versatile tool in modern science and technology. Due to their ideal geophysical and geochemical properties, long-lived noble gas radionuclides, in particular, 39Ar (t1/2 = 269 yr), 81Kr (t1/2 = 2.3x10^5 yr) and 85Kr (t1/2 = 10.8 yr), have long been recognized to have a wide range of important applications in Earth sciences. In recent years, significant progress has been made in the development of practical analytical methods, and has led to applications of these isotopes in the hydrosphere (tracing the flow of groundwater and ocean water). In this article, we introduce the applications of these isotopes and review three leading analytical methods: Low-Level Counting (LLC), Accelerator Mass Spectrometry (AMS) and Atom Trap Trace Analysis (ATTA).

  7. Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors in France: Implications for Atmospheric Lead Source Tracing.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors@crpg.cnrs-nancy.fr _______________________________________________________________________________________ Fly ash and flue gas residues from eight municipal solid waste combusters (MSWC) in France (1992 of "industrial Pb" is not an easy task because of its possible extreme heterogeneity. Municipal solid waste

  8. Trace analysis of atmospheric organic bases

    E-Print Network [OSTI]

    Clark, Dwayne C.

    1984-01-01T23:59:59.000Z

    chromatographic fractions for NS analyses ( 121) and its use as a thin layer chromatography (TLC) adsorbent ( 122). The National Institute of Occupational Safety and Health (NIOSH) recommends its use in the analysis of many industrial vapors ( 113 - 120... analysis of atmospheric organic bases were investigated; the study included (1) the analysis of submarine charcoal filter bed samples for nitrogen bases and (2) the use of metallic tetraphenylporphines (TPP) as specific adsorbents for atmospheric...

  9. Project AIRSTREAM: Trace gas final report

    SciTech Connect (OSTI)

    Leifer, R.

    1992-12-01T23:59:59.000Z

    The results of 10 years of sampling for trace gases in the upper troposphere and lower stratosphere are presented. These samples were collected under the auspices of the Atomic Energy Commission (AEC), the Energy Research and Development Administration (ERDA) and the Department of Energy (DOE). Almost 1000 whole air samples were collected during the years 1973 to 1983 under Project AIRSTREAM. Project AIRSTREAM was part of the Environmental Measurements Laboratory's (EML, at that time called the Health and Safety Laboratory/HASL) research effort to investigate the impact of the injection of radionuclides and stable compounds into the stratosphere. One or more of the following compounds were analyzed: CCl[sub 3]F, CCl[sub 2]F[sub 2], CCl[sub 4], N[sub 2]O, SF[sub 6], CO[sub 2], CH[sub 4], CH[sub 3]CCl[sub 3], and COS. Details of the Project's quality assurance program are discussed. Also included in the report are two-dimensional plots of the concentration of CCl[sub 3]F and a complete tabulation of the data.

  10. Project AIRSTREAM: Trace gas final report

    SciTech Connect (OSTI)

    Leifer, R.

    1992-12-01T23:59:59.000Z

    The results of 10 years of sampling for trace gases in the upper troposphere and lower stratosphere are presented. These samples were collected under the auspices of the Atomic Energy Commission (AEC), the Energy Research and Development Administration (ERDA) and the Department of Energy (DOE). Almost 1000 whole air samples were collected during the years 1973 to 1983 under Project AIRSTREAM. Project AIRSTREAM was part of the Environmental Measurements Laboratory`s (EML, at that time called the Health and Safety Laboratory/HASL) research effort to investigate the impact of the injection of radionuclides and stable compounds into the stratosphere. One or more of the following compounds were analyzed: CCl{sub 3}F, CCl{sub 2}F{sub 2}, CCl{sub 4}, N{sub 2}O, SF{sub 6}, CO{sub 2}, CH{sub 4}, CH{sub 3}CCl{sub 3}, and COS. Details of the Project`s quality assurance program are discussed. Also included in the report are two-dimensional plots of the concentration of CCl{sub 3}F and a complete tabulation of the data.

  11. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  12. Gas Source Tracing With a Mobile Robot Using an Adapted Moth Strategy

    E-Print Network [OSTI]

    Zell, Andreas

    Gas Source Tracing With a Mobile Robot Using an Adapted Moth Strategy Achim Lilienthal, Denis,reiman,zell}@informatik.uni-tuebingen.de Abstract. As a sub-task of the general gas source localisation problem, gas source tracing is supposed to guide a gas-sensitive mobile system towards a source by using the cues determined from the gas

  13. A field study on the trace metal behavior in atmospheric circulating fluidized-bed coal combustion

    SciTech Connect (OSTI)

    Lind, T.; Kauppinen, E.I.; Jokiniemi, J.K.; Maenhaut, W.

    1994-12-31T23:59:59.000Z

    Trace element behavior in atmospheric circulating fluidized-bed combustion (CFBC) of Venezuelan bituminous coal was studied by determining particle size distributions in the CFBC flue gas. The size distributions of calcium, iron, aluminium, and 21 trace elements, Sc, V, Cr, Mn, Co, Ni, Zn, Ga, As, Se, Sr, Cd, Sb, Cs, Ba, La, Ce, Sm, Lu, Pb, and Th, in the size range 0.01--70{micro}m, were determined by collecting aerosols with a low-pressure impactor-cyclone sampling train from the flue gases of an 80-MW(th) CFBC boiler upstream of the electrostatic precipitator. The collected samples were analyzed gravimetrically and with instrumental neutron activation analysis (INAA), particle-induced X-ray emission analysis (PIXE), and inductively coupled plasma mass spectrometry (ICP-MS). The number size distributions of the aerosols were determined with a differential electrical mobility method in the size range 0.01--0.8 {micro}m. In the ultrafine particle mode, i.e., D{sub p} < 0.1 {micro}m, the CFBC number concentrations varied strongly during the experiments, being one to two orders of magnitude lower than those observed in pulverized coal combustion. For all of the elements studied, 75% or more were found in particles larger than 5{micro}m. None of the studied elements showed significant vaporization and subsequent chemical surface reaction or condensation in the CFBC. The Sr, Se, V, Zn, Ga, Cs, Ba, La, Sm, Lu, and Th size distributions resembled those of aluminium, suggesting their occurrence in aluminosilicate-rich particles in the fly ash. The association of the trace elements with aluminium in the fly ash particles may result from reactions of the trace elements with the aluminosilicate mineral particles inside the burning coal particles, or their initial occurrence in association with these minerals.

  14. Chapter 2: Sources and Deposition of Trace Metals 2.1 Main Sources of Atmospheric Pollution...............................................7

    E-Print Network [OSTI]

    Short, Daniel

    5 Chapter 2: Sources and Deposition of Trace Metals 2.1 Main Sources of Atmospheric Pollution distances causing regional or global pollution. Fig. 2.1: Sources of trace metals in the environment. Contamination of the atmosphere by pollutant trace metals affects the environment directly through its impact

  15. Electrical apparatus for explosive gas atmospheres, Part 0: General introduction 

    E-Print Network [OSTI]

    IEC Technical Committee

    1971-01-01T23:59:59.000Z

    This Recommendation has been prepared by IEC Technical Committee No. 31, Electrical Apparatus for Explosive Atmospheres; It forms one of a series of publications dealing with electrical apparatus for use in explosive gas atmospheres. This particular...

  16. "Trace Analysis of Speciality and Electronic Gases," Chapter 4, "Emerging Infrared Laser Absorption Spectroscopic Techniques for Gas Analysis"

    SciTech Connect (OSTI)

    Lascola, R.; McWhorter, S.; Tittel, F.; Lewicki, R.

    2013-07-01T23:59:59.000Z

    This chapter covers Laser Absorption Spectroscopic Techniques and Applications of Semiconductor LAS Based Trace Gas Sensor Systems.

  17. Room-temperature mid-infrared laser sensor for trace gas detection

    E-Print Network [OSTI]

    , and pipeline leak detection. Applications such as landfill emissions monitoring require measurements of gasRoom-temperature mid-infrared laser sensor for trace gas detection Thomas To¨ pfer, Konstantin P of a compact, portable, room-temperature mid-infrared gas sensor is reported. The sensor is based on continuous

  18. Atmospheric pressure helium afterglow discharge detector for gas chromatography

    DOE Patents [OSTI]

    Rice, Gary (Gloucester, VA); D'Silva, Arthur P. (Ames, IA); Fassel, Velmer A. (Ames, IA)

    1986-05-06T23:59:59.000Z

    An apparatus for providing a simple, low-frequency electrodeless discharge system for atmospheric pressure afterglow generation. A single quartz tube through which a gas mixture is passed is extended beyond a concentric electrode positioned thereabout. A grounding rod is placed directly above the tube outlet to permit optical viewing of the discharge between the electrodes.

  19. Atmospheric pressure helium afterglow discharge detector for gas chromatography

    DOE Patents [OSTI]

    Rice, G.; D'Silva, A.P.; Fassel, V.A.

    1985-04-05T23:59:59.000Z

    An apparatus for providing a simple, low-frequency, electrodeless discharge system for atmospheric pressure afterglow generation. A single quartz tube through which a gas mixture is passed is extended beyond a concentric electrode positioned thereabout. A grounding rod is placed directly above the tube outlet to permit optical viewing of the discharge between the electrodes.

  20. Validation of a Model of a Resonant Optothermoacoustic Trace Gas Sensor

    E-Print Network [OSTI]

    Minkoff, Susan E.

    Validation of a Model of a Resonant Optothermoacoustic Trace Gas Sensor N. Petra1, J. Zweck1, S. E optothermoacoustic sensor is validated by comparison with experiments performed with 0.5% acetylene in nitrogen Optical Society of America OCIS codes: 300.6430, 300.6340. 1. Introduction Quartz-Enhanced Photo

  1. Evolution of the geothermal fluids at Los Azufres, Mexico, as traced by noble gas isotopes, 18

    E-Print Network [OSTI]

    Long, Bernard

    following over 25 years of geothermal fluid exploitation. Mantle helium dominates in fluids from the north field has been extensively studied in the past 30 years for its geological and tectonic features (DobsonEvolution of the geothermal fluids at Los Azufres, Mexico, as traced by noble gas isotopes, 18 O, D

  2. Carbon dioxide Information Analysis Center and World Data Center: A for Atmospheric trace gases. Annual progress report, FY 1994

    SciTech Connect (OSTI)

    Burtis, M.D. [comp.] [Tennessee Univ., Knoxville, TN (United States). Energy, Environment and Resources Center; Cushman, R.M.; Boden, T.A.; Jones, S.B.; Nelson, T.R.; Stoss, F.W. [Oak Ridge National Lab., TN (United States)

    1995-03-01T23:59:59.000Z

    This report summarizes the activities and accomplishments made by the Carbon Dioxide Information Analysis Center and World Data Center-A for Atmospheric Trace Gases during the fiscal year 1994. Topics discussed in this report include; organization and staff, user services, systems, communications, Collaborative efforts with China, networking, ocean data and activities of the World Data Center-A.

  3. Tracing high density gas in M 82 and NGC 4038

    E-Print Network [OSTI]

    E. Bayet; C. Lintott; S. Viti; J. Martín-Pintado; S. Martín; D. A. Williams; J. M. C. Rawlings

    2008-08-20T23:59:59.000Z

    We present the first detection of CS in the Antennae galaxies towards the NGC 4038 nucleus, as well as the first detections of two high-J (5-4 and 7-6) CS lines in the center of M 82. The CS(7-6) line in M 82 shows a profile that is surprisingly different to those of other low-J CS transitions we observed. This implies the presence of a separate, denser and warmer molecular gas component. The derived physical properties and the likely location of the CS(7-6) emission suggests an association with the supershell in the centre of M 82.

  4. Electrical apparatus for explosive gas atmospheres, Part 10: Classification of hazardous areas 

    E-Print Network [OSTI]

    IEC Technical Committee

    1972-01-01T23:59:59.000Z

    This Report has been prepared by IEC Technical Committee No. 31, Electrical Apparatus for Explosive Atmospheres. It forms one of a series of publications dealing with electrical apparatus for use in explosive gas atmospheres. ...

  5. Recuperated atmosphere SOFC/gas turbine hybrid cycle

    DOE Patents [OSTI]

    Lundberg, Wayne (Pittsburgh, PA)

    2010-08-24T23:59:59.000Z

    A method of operating an atmospheric-pressure solid oxide fuel cell generator (6) in combination with a gas turbine comprising a compressor (1) and expander (2) where an inlet oxidant (20) is passed through the compressor (1) and exits as a first stream (60) and a second stream (62) the first stream passing through a flow control valve (56) to control flow and then through a heat exchanger (54) followed by mixing with the second stream (62) where the mixed streams are passed through a combustor (8) and expander (2) and the first heat exchanger for temperature control before entry into the solid oxide fuel cell generator (6), which generator (6) is also supplied with fuel (40).

  6. Recuperated atmospheric SOFC/gas turbine hybrid cycle

    DOE Patents [OSTI]

    Lundberg, Wayne

    2010-05-04T23:59:59.000Z

    A method of operating an atmospheric-pressure solid oxide fuel cell generator (6) in combination with a gas turbine comprising a compressor (1) and expander (2) where an inlet oxidant (20) is passed through the compressor (1) and exits as a first stream (60) and a second stream (62) the first stream passing through a flow control valve (56) to control flow and then through a heat exchanger (54) followed by mixing with the second stream (62) where the mixed streams are passed through a combustor (8) and expander (2) and the first heat exchanger for temperature control before entry into the solid oxide fuel cell generator (6), which generator (6) is also supplied with fuel (40).

  7. Trace Gas Emissions Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Collections under the broad heading of Trace Gas Emissions are organized as Fossil-Fuel CO2 Emissions, Land-Use CO2 Emissions, Soil CO2 Emissions, and Methane.

  8. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere

    E-Print Network [OSTI]

    Montes-Hernandez, German

    Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere of anthropogenic emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions to reflect, adsorb and emit the solar energy. However, the continuous emissions of CO2 into the atmosphere

  9. Relation between plasma plume density and gas flow velocity in atmospheric pressure plasma

    SciTech Connect (OSTI)

    Yambe, Kiyoyuki; Taka, Shogo; Ogura, Kazuo [Graduate School of Science and Technology, Niigata University, Niigata 950-2181 (Japan)] [Graduate School of Science and Technology, Niigata University, Niigata 950-2181 (Japan)

    2014-04-15T23:59:59.000Z

    We have studied atmospheric pressure plasma generated using a quartz tube, helium gas, and copper foil electrode by applying RF high voltage. The atmospheric pressure plasma in the form of a bullet is released as a plume into the atmosphere. To study the properties of the plasma plume, the plasma plume current is estimated from the difference in currents on the circuit, and the drift velocity is measured using a photodetector. The relation of the plasma plume density n{sub plu}, which is estimated from the current and the drift velocity, and the gas flow velocity v{sub gas} is examined. It is found that the dependence of the density on the gas flow velocity has relations of n{sub plu} ? log(v{sub gas}). However, the plasma plume density in the laminar flow is higher than that in the turbulent flow. Consequently, in the laminar flow, the density increases with increasing the gas flow velocity.

  10. Trace-element evidence for the origin of desert varnish by direct aqueous atmospheric deposition

    E-Print Network [OSTI]

    Lee, Cin-Ty Aeolus

    , Ni, Pb and the rare-earth elements (REEs). In particular, they have anomalously high Ce/La and low Y Nivedita Thiagarajan, Cin-Ty Aeolus Lee* Department of Earth Science, MS-126, Rice University, Houston, TX elemental fractionations. One remaining possibility is that the Fe, Mn and trace metals in varnish

  11. atmospheric gas annual: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  12. atmospheric gas analyzer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  13. atmospheric tritium gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  14. Carbon Dioxide Information Analysis Center and World Data Center-A for atmospheric trace gases: FY 1993 activities

    SciTech Connect (OSTI)

    Cushman, R.M. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center; Stoss, F.W. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center]|[Univ. of Tennessee, Knoxville, TN (United States). Energy, Environment, and Resources Center

    1994-01-01T23:59:59.000Z

    During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specialty publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIAC`s staff also provide technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC (including World Data Center-A for Atmospheric Trace Gases) during the period October 1, 1992, to September 30, 1993. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. An analysis and description of the preparation and distribution of NDPS, CMPS, technical reports, newsletters, fact sheets, specialty publications, and reprints are provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also presented.

  15. Trace element chemistry of coal bed natural gas produced water in the Powder River Basin, Wyoming

    SciTech Connect (OSTI)

    Richard E. Jackson; K.J. Reddy [University of Wyoming, Laramie, WY (United States). Department of Renewable Resources

    2007-09-15T23:59:59.000Z

    Coal bed natural gas (CBNG) produced water is usually disposed into nearby constructed disposal ponds. Geochemistry of produced water, particularly trace elements interacting with a semiarid environment, is not clearly understood. The objective of this study was to collect produced water samples at outfalls and corresponding disposal ponds and monitor pH, iron (Fe), aluminum (Al), chromium (Cr), manganese (Mn), lead (Pb), copper (Cu), zinc (Zn), arsenic (As), boron (B), selenium (Se), molybdenum (Mo), cadmium (Cd), and barium (Ba). Outfalls and corresponding disposal ponds were sampled from five different watersheds including Cheyenne River (CHR), Belle Fourche River (BFR), Little Powder River (LPR), Powder River (PR), and Tongue River (TR) within the Powder River Basin (PRB), Wyoming from 2003 to 2005. Paired tests were conducted between CBNG outfalls and corresponding disposal ponds for each watershed. Results suggest that produced water from CBNG outfalls is chemically different from the produced water from corresponding disposal ponds. Most trace metal concentrations in the produced water increased from outfall to disposal pond except for Ba. In disposal ponds, Ba, As, and B concentrations increased from 2003 to 2005. Geochemical modeling predicted precipitation and dissolution reactions as controlling processes for Al, Cu, and Ba concentrations in CBNG produced water. Adsorption and desorption reactions appear to control As, Mo, and B concentrations in CBNG water in disposal ponds. Overall, results of this study will be important to determine beneficial uses (e.g., irrigation, livestock/wildlife water, and aquatic life) for CBNG produced water in the PRB, Wyoming. 18 refs., 4 figs., 3 tabs.

  16. Laboratory scale studies of Pd/y-Al2O3 sorbents for the removal of trace contaminents from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J.; Stanko, Dennis C.

    2010-12-31T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150-540 C) to hot (>540 C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/{gamma}-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  17. Effective destruction of CO by cosmic rays: implications for tracing H$_2$ gas in the Universe

    E-Print Network [OSTI]

    Bisbas, Thomas G; Viti, Serena

    2015-01-01T23:59:59.000Z

    We report on the effects of cosmic rays (CRs) on the abundance of CO in $\\rm H_2$ clouds under conditions typical for star-forming galaxies in the Universe. We discover that this most important molecule for tracing H$_2$ gas is very effectively destroyed in ISM environments with CR energy densities $\\rm U_{CR}\\sim(50-10^{3})\\times U_{CR,Gal}$, a range expected in numerous star-forming systems throughout the Universe. This density-dependent effect operates volumetrically rather than only on molecular cloud surfaces (i.e. unlike FUV radiation that also destroys CO), and is facilitated by: a) the direct destruction of CO by CRs, and b) a reaction channel activated by CR-produced He$^{+}$. The effect we uncover is strong enough to render Milky-Way type Giant Molecular Clouds (GMCs) very CO-poor (and thus CO-untraceable), even in ISM environments with rather modestly enhanced average CR energy densities of $\\rm U_{CR}\\sim(10-50)\\times\\rm U_{CR,Gal}$. We conclude that the CR-induced destruction of CO in molecular c...

  18. Atmosphere-soil-stream greenhouse gas fluxes from peatlands 

    E-Print Network [OSTI]

    Dinsmore, Kerry J.

    2009-01-01T23:59:59.000Z

    Peatlands cover approximately 2-3% of the world’s land area yet represent approximately a third of the worlds estimated total soil carbon pool. They therefore play an important role in regulating global atmospheric CO2 and CH4 concentrations...

  19. Headspace profiles of modified atmosphere packaged fresh red snapper (Lutjanus campechanus) by gas liquid chromatography

    E-Print Network [OSTI]

    Scorah, Craig Darrell Allen

    1988-01-01T23:59:59.000Z

    fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1988 Major Subject: Food Science and Technology HEADSPACE PROFILES OF MODIFIED ATMOSPHERE PACKAGED FRESH RED SNAPPER (LUJANUS CAMPECHANUS) BY GAS LIQUID CHROMATOGRAPHY A Thesis... of this research indicate that headspace analysis can potentially be very useful in determining the microbial activity in fresh seafoods and other raw proteinaceous foods packaged in vacuum or modified atmospheres. This technique could find its place...

  20. Fluorine Gas Management Guidelines Fluorine is a highly toxic, pale yellow gas about 1.3 times as heavy as air at atmospheric

    E-Print Network [OSTI]

    de Lijser, Peter

    Fluorine Gas Management Guidelines Overview Fluorine is a highly toxic, pale yellow gas about 1.3 times as heavy as air at atmospheric temperature and pressure. Fluorine gas is the most powerful oxidizing agent known, reacting with practically all organic and inorganic substances. Fluorine gas

  1. Batch methods for enriching trace impurities in hydrogen gas for their further analysis

    DOE Patents [OSTI]

    Ahmed, Shabbir; Lee, Sheldon H.D.; Kumar, Romesh; Papdias, Dionissios D.

    2014-07-15T23:59:59.000Z

    Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio P.sub.hi/P.sub.lo and the volume ratio V.sub.1/V.sub.2, with following detection of the impurities using commonly-available detection methods.

  2. Flow injection trace gas analysis method for on-site determination of organoarsenicals

    DOE Patents [OSTI]

    Aldstadt, III, Joseph H. (Orland Park, IL)

    1997-01-01T23:59:59.000Z

    A method for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere.

  3. Flow injection trace gas analysis method for on-site determination of organoarsenicals

    DOE Patents [OSTI]

    Aldstadt, J.H. III

    1997-06-24T23:59:59.000Z

    A method is described for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere. 2 figs.

  4. Estimation of mixing in the troposphere from1 Lagrangian trace gas reconstructions during2

    E-Print Network [OSTI]

    Legras, Bernard

    of Physics and Atmospheric Science, Dalhousie University, Halifax, Canada 7 Institut f¨ur Physik der Atmosph for Mathematical Sciences University of Cambridge (i.pisso@damtp.cam.ac.uk) 1 Department of Applied Mathematics

  5. Simultaneous gas-chromatographic determination of four toxic gases generally present in combustion atmospheres. Final report

    SciTech Connect (OSTI)

    Endecott, B.R.; Sanders, D.C.; Chaturvedi, A.K.

    1994-09-01T23:59:59.000Z

    Measurement of combustion gases produced by burning aircraft cabin materials poses a continuing limitation for smoke toxicity research. Since toxic effects of gases depend on both their concentrations and duration of exposures, frequent atmosphere sampling is necessary to define the concentration-time curve. A gas chromatographic method was developed for the simultaneous analyses of carbon monoxide (CO), hydrogen sulfide (H2S), sulfur dioxide (SO2), and hydrogen cyanide (HCN). The method utilized an MTI M200 dual-column gas chromatograph (GC) equipped with 4-m molecular sieve-5A and 8-m PoraPlot-U capillary columns and two low-volume, high-sensitivity thermal conductivity detectors. Detectability (ppm)/retention times (seconds) for the gases were: CO (100/28); H2S (50/26); SO2 (125/76); HCN (60/108). The method was effective for determining these gases in mixtures and in the combustion atmospheres generated by burning wool (CO, HCN, and H2S) and modacrylic (CO and HCN) fabrics. Common atmospheric gaseous or combustion products (oxygen, carbon dioxide, nitrogen, water vapor, and other volatiles) did not interfere with the analyses. However, filtration of the combustion atmospheres was necessary to prevent restriction of the GC sampling inlet by smoke particulates. The speed, sensitivity, and selectivity of this method make it suitable for smoke toxicity research and for evaluating performance of passenger protective breathing equipment.

  6. Temporally, spatially, and spectrally resolved barrier discharge produced in trapped helium gas at atmospheric pressure

    SciTech Connect (OSTI)

    Chiper, Alina Silvia; Popa, Gheorghe [Faculty of Physics, Alexandru Ioan Cuza University, 700506 Iasi (Romania)] [Faculty of Physics, Alexandru Ioan Cuza University, 700506 Iasi (Romania)

    2013-06-07T23:59:59.000Z

    Experimental study was made on induced effects by trapped helium gas in the pulsed positive dielectric barrier discharge (DBD) operating in symmetrical electrode configuration at atmospheric pressure. Using fast photography technique and electrical measurements, the differences in the discharge regimes between the stationary and the flowing helium are investigated. It was shown experimentally that the trapped gas atmosphere (TGA) has notable impact on the barrier discharge regime compared with the influence of the flowing gas atmosphere. According to our experimental results, the DBD discharge produced in trapped helium gas can be categorized as a multi-glow (pseudo-glow) discharge, each discharge working in the sub-normal glow regime. This conclusion is made by considering the duration of current pulse (few {mu}s), their maximum values (tens of mA), the presence of negative slope on the voltage-current characteristic, and the spatio-temporal evolution of the most representative excited species in the discharge gap. The paper focuses on the space-time distribution of the active species with a view to better understand the pseudo-glow discharge mechanism. The physical basis for these effects was suggested. A transition to filamentary discharge is suppressed in TGA mode due to the formation of supplementary source of seed electrons by surface processes (by desorption of electrons due to vibrationally excited nitrogen molecules, originated from barriers surfaces) rather than volume processes (by enhanced Penning ionisation). Finally, we show that the pseudo-glow discharge can be generated by working gas trapping only; maintaining unchanged all the electrical and constructive parameters.

  7. Quantifying Climate Feedbacks from Abrupt Changes in High-Latitude Trace-Gas Emissions

    SciTech Connect (OSTI)

    Qianlai Zhuang

    2012-11-16T23:59:59.000Z

    During the three-year project period, Purdue University has specifically accomplished the following: revised the existing Methane Dynamics Model (MDM) to consider the effects of changes of atmospheric pressure; applied the methane dynamics model (MDM) to Siberian region to demonstrate that ebullition estimates could increase previous estimates of regional terrestrial CH{sub 4} emissions 3- to 7-fold in Siberia; Conducted an analysis of the carbon balance of the Arctic Basin from 1997 to 2006 to show that terrestrial areas of the Arctic were a net source of 41.5 Tg CH{sub 4} yr{sup â??1} that increased by 0.6 Tg CH{sub 4} yr{sup â??1} during the decade of analysis, a magnitude that is comparable with an atmospheric inversion of CH{sub 4}; improved the quantification of CH{sub 4} fluxes in the Arctic with inversion methods; evaluated AIRS CH4 retrieval data with a transport and inversion model and surface flux and aircraft data; to better quantify methane emissions from wetlands, we extended the MDM within a biogeochemistry model, the Terrestrial Ecosystem Model (TEM), to include a large-scale hydrology model, the variable infiltration capacity (VIC) model; more recently, we developed a single box atmospheric chemistry model involving atmospheric methane (CH{sub 4}), carbon monoxide (CO) and radical hydroxyl (OH) to analyze atmospheric CH{sub 4} concentrations from 1984 to 2008.

  8. Investigation of trace amounts of gas on microvave water-cut measurement

    E-Print Network [OSTI]

    Liu, Jin

    2006-08-16T23:59:59.000Z

    In recent years, the upstream oil and gas industry has dealt with some of the most challenging metering applications. One of these is the measurement of water percentage at the point of allocation. It is an essential requirement when test separators...

  9. Pulsed microwave discharge in a capillary filled with atmospheric-pressure gas

    SciTech Connect (OSTI)

    Gritsinin, S. I., E-mail: gritsinins@mail.ru [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation); Gushchin, P. A. [Gubkin Russian State University of Oil and Gas (Russian Federation)] [Gubkin Russian State University of Oil and Gas (Russian Federation); Davydov, A. M. [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)] [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation); Ivanov, E. V. [Gubkin Russian State University of Oil and Gas (Russian Federation)] [Gubkin Russian State University of Oil and Gas (Russian Federation); Kossyi, I. A. [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)] [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)

    2013-08-15T23:59:59.000Z

    A pulsed microwave coaxial capillary plasma source generating a thin plasma filament along the capillary axis in an atmospheric-pressure argon flow is described. The dynamics of filament formation is studied, and the parameters of the gas and plasma in the contraction region are determined. A physical model of discharge formation and propagation is proposed. The model is based on the assumption that, under the conditions in which the electric fields is substantially below the threshold value, the discharge operates in a specific form known as a self-sustained-non-self-sustained (SNS) microwave discharge.

  10. Control of Gas Tungsten Arc welding pool shape by trace element addition to the weld pool

    DOE Patents [OSTI]

    Heiple, C.R.; Burgardt, P.

    1984-03-13T23:59:59.000Z

    An improved process for Gas Tungsten Arc welding maximizes the depth/width ratio of the weld pool by adding a sufficient amount of a surface active element to insure inward fluid flow, resulting in deep, narrow welds. The process is especially useful to eliminate variable weld penetration and shape in GTA welding of steels and stainless steels, particularly by using a sulfur-doped weld wire in a cold wire feed technique.

  11. Quantifying Climate Feedbacks from Abrupt Changes in High-Latitude Trace-Gas Emissions

    SciTech Connect (OSTI)

    Schlosser, Courtney Adam [MIT; Walter-Anthony, Katey [University of Alaska; Zhuang, Qianlai [Purdue University; Melillo, Jerry [Marine Biological Laboratory

    2013-04-26T23:59:59.000Z

    Our overall goal was to quantify the potential for threshold changes in natural emission rates of trace gases, particularly methane and carbon dioxide, from pan-arctic terrestrial systems under the spectrum of anthropogenically forced climate warming, and the extent to which these emissions provide a strong feedback mechanism to global climate warming. This goal is motivated under the premise that polar amplification of global climate warming will induce widespread thaw and degradation of the permafrost, and would thus cause substantial changes in the extent of wetlands and lakes, especially thermokarst (thaw) lakes, over the Arctic. Through a coordinated effort of field measurements, model development, and numerical experimentation with an integrated assessment model framework, we have investigated the following hypothesis: There exists a climate-warming threshold beyond which permafrost degradation becomes widespread and thus instigates strong and/or sharp increases in methane emissions (via thermokarst lakes and wetland expansion). These would outweigh any increased uptake of carbon (e.g. from peatlands) and would result in a strong, positive feedback to global climate warming.

  12. Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J. [U.S. DOE; Stanko, Dennis C. [U.S. DOE

    2013-01-01T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150–540 °C) to hot (>540 °C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 °C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  13. Tunable photonic cavities for in-situ spectroscopic trace gas detection

    DOE Patents [OSTI]

    Bond, Tiziana; Cole, Garrett; Goddard, Lynford

    2012-11-13T23:59:59.000Z

    Compact tunable optical cavities are provided for in-situ NIR spectroscopy. MEMS-tunable VCSEL platforms represents a solid foundation for a new class of compact, sensitive and fiber compatible sensors for fieldable, real-time, multiplexed gas detection systems. Detection limits for gases with NIR cross-sections such as O.sub.2, CH.sub.4, CO.sub.x and NO.sub.x have been predicted to approximately span from 10.sup.ths to 10s of parts per million. Exemplary oxygen detection design and a process for 760 nm continuously tunable VCSELS is provided. This technology enables in-situ self-calibrating platforms with adaptive monitoring by exploiting Photonic FPGAs.

  14. Commercial demonstration of atmospheric medium BTU fuel gas production from biomass without oxygen the Burlington, Vermont Project

    SciTech Connect (OSTI)

    Rohrer, J.W. [Zurn/NEPCO, South Portland, MA (United States); Paisley, M. [Battelle Laboratories, Columbus, OH (United States)

    1995-12-31T23:59:59.000Z

    The first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification of biomass occurred at Battelle Columbus Labs (BCL) during 1994 using their high throughput indirect medium Btu gasification Process Research Unit (PRU). Zurn/NEPCO was retained to build a commercial scale gas plant utilizing this technology. This plant will have a throughput rating of 8 to 12 dry tons per hour. During a subsequent phase of the Burlington project, this fuel gas will be utilized in a commercial scale gas turbine. It is felt that this process holds unique promise for economically converting a wide variety of biomass feedstocks efficiently into both a medium Btu (500 Btu/scf) gas turbine and IC engine quality fuel gas that can be burned in engines without modification, derating or efficiency loss. Others are currently demonstrating sub-commercial scale thermal biomass gasification processes for turbine gas, utilizing both atmospheric and pressurized air and oxygen-blown fluid bed processes. While some of these approaches hold merit for coal, there is significant question as to whether they will prove economically viable in biomass facilities which are typically scale limited by fuel availability and transportation logistics below 60 MW. Atmospheric air-blown technologies suffer from large sensible heat loss, high gas volume and cleaning cost, huge gas compressor power consumption and engine deratings. Pressurized units and/or oxygen-blown gas plants are extremely expensive for plant scales below 250 MW. The FERCO/BCL process shows great promise for overcoming the above limitations by utilizing an extremely high throughout circulation fluid bed (CFB) gasifier, in which biomass is fully devolitalized with hot sand from a CFB char combustor. The fuel gas can be cooled and cleaned by a conventional scrubbing system. Fuel gas compressor power consumption is reduced 3 to 4 fold verses low Btu biomass gas.

  15. Fiscal Year 1998 Annual Report, Carbon Dioxide Information Analysis Center, World Data Center -- A for Atmospheric Trace Gases

    SciTech Connect (OSTI)

    Cushman, R.M.; Boden, T.A.; Hook, L.A.; Jones, S.B.; Kaiser, D.P.; Nelson, T.R.

    1999-03-01T23:59:59.000Z

    Once again, the most recent fiscal year was a productive one for the Carbon Dioxide Information Analysis Center (CDIAC) at Oak Ridge National Laboratory (ORNL), as well as a year for change. The FY 1998 in Review section in this report summarizes quite a few new and updated data and information products, and the ''What's Coming in FY 1999'' section describes our plans for this new fiscal year. During FY 1998, CDIAC began a data-management system for AmeriFlux, a long-term study of carbon fluxes between the terrestrial biosphere of the Western Hemisphere and the atmosphere. The specific objectives of AmeriFlux are to establish an infrastructure for guiding, collecting, synthesizing, and disseminating long-term measurements of CO{sub 2}, water, and energy exchange from a variety of ecosystems; collect critical new information to help define the current global CO{sub 2} budget; enable improved predictions of future concentrations of atmospheric CO{sub 2}; and enhance understanding of carbon fluxes. Net Ecosystem Production (NEP), and carbon sequestration in the terrestrial biosphere. The data-management system, available from CDIAC'S AmeriFlux home page (http://cdiac.esd.ornl.gov/programs/ameriflux/ ) is intended to provide consistent, quality-assured, and documented data across all AmeriFlux sites in the US, Canada, Costa Rica, and Brazil. It is being developed by Antoinette Brenkert and Tom Boden, with assistance from Susan Holladay (who joined CDIAC specifically to support the AmeriFlux data-management effort).

  16. Final Report on Testing of Off-Gas Treatment Technologies for Abatement of Atmospheric Emissions of Chlorinated Volatile Organic Compounds

    SciTech Connect (OSTI)

    Jarosch, T.R.; Haselow, J.S.; Rossabi, J.; Burdick, S.A.; Raymond, R.; Young, J.E.; Lombard, K.H.

    1995-01-23T23:59:59.000Z

    The purpose of this report is to summarize the results of the program for off-gas treatment of atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program was funded through the Department of Energy Office of Technology Development`s VOC`s in Non-Arid Soils Integrated Demonstration (VNID). The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed (Looney et al., 1991). That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the United States to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate cost effective evaluation of the emerging technologies. Another motivation for the program is that many CVOCs will be regulated under the Clean Air Act Amendments of 1990 and are already regulated by many state regulatory programs. Additionally, compounds such as TCE and PCE are pervasive subsurface environmental contaminants, and, as a result, a small improvement in terms of abatement efficiency or cost will significantly reduce CVOC discharges to the environment as well as costs to United States government and industry.

  17. Nitrous Oxide Nitrous oxide (chemical formula N2O), is a trace gas in Earth's atmosphere, with a

    E-Print Network [OSTI]

    fuel, biomass and biofuel, and industrial processes. Nitrous oxide emissions related to biofuel, the Global Warming Potential (GWP) is a more useful quantity. The GWP of N2O is the time- integrated radiative forcing following a 1 kg pulse emission of N2O, relative to the same quantity following a 1 kg

  18. Greenhouse Gas Basics

    Broader source: Energy.gov [DOE]

    Greenhouse gases are trace gases in the lower atmosphere that trap heat through a natural process called the "greenhouse effect."

  19. Formation of gas-phase peroxides in a rural atmosphere: An interpretation of the recent SOS/SERON field results

    SciTech Connect (OSTI)

    Lee, J.H.; Tang, I.N. [Brookhaven National Lab., Upton, NY (United States); Weinstein-Lloyd, J.B. [State Univ. of New York, Old Westbury, NY (United States). Chemistry/Physics Dept.

    1993-09-01T23:59:59.000Z

    Hydrogen perioxide (H{sub 2}O{sub 2}) and certain organic peroxides such as hydroxymethyl-hydroperoxide (HMHP), are gas-phase oxidants present in the atmosphere at ppbv concentration levels. These oxidants play an important role in atmospheric chemistry. In addition, precipitation containing H{sub 2}O{sub 2} is toxic to trees, and it has also been suggested that organic peroxides formed presumably by ozone reactions with biogenic alkenes are responsible for leaf disorders. Recently, we have developed a nonenzymatic method or aqueous-phase H{sub 2}O{sub 2} measurement, using Fenton reagent and fluorescent hydroxy- benzoic acid. The new method, in conjunction with the well-known method of p-hydroxyphenylacetic acid and horseradish peroxidase for total peroxides, and together with an improved gas scrubber to mitigate sampling line problems, has been successfully deployed in recent SOS/SERON field measurements in rural Georgia. For the first time, continuously measured and speciated gas-phase peroxide data have become available, making it possible to examine some aspects of the ozone chemistry leading to the formation of these oxidants. It is observed that daily H{sub 2}O{sub 2} maximum frequently occurs at a different time than does HMHP, and that H{sub 2}O{sub 2} concentration, but not HMHP, tends to correlate with solar fluxes measured at the same location. These findings seem to indicate that the formation mechanisms for H{sub 2}O{sub 2} and organic peroxides are basically different. It is likely that H{sub 2}O{sub 2} is formed from radical-radical recombination, while HMHP is formed by ozone-alkene reactions. Since the gas-phase ozone-alkene reactions are usually too slow to account for the diurnal concentration variations observed for HMHP, heterogeneous processes involving ozone and alkenes are also a possibility.

  20. Investigation of mercury transformation by HBr addition in a slipstream facility with real flue gas atmospheres of bituminous coal and Powder River Basin Coal

    SciTech Connect (OSTI)

    Yan Cao; Quanhai Wang; Chien-wei Chen; Bobby Chen; Martin Cohron; Yi-chuan Tseng; Cheng-chung Chiu; Paul Chu; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

    2007-09-15T23:59:59.000Z

    An investigation of speciated mercury transformation with the addition of hydrogen bromide (HBr) at elevated temperatures was conducted in a slipstream reactor with real flue gas atmospheres. Test results indicated that adding HBr into the flue gas at several parts per million strongly impacted the mercury oxidation and adsorption, which were dependent upon temperature ranges. Higher temperatures (in the range of 300-350 C) promoted mercury oxidation by HBr addition but did not promote mercury adsorption. Lower temperatures (in a range of 150-200 C) enhanced mercury adsorption on the fly ash by adding HBr. Test results also verified effects of flue gas atmospheres on the mercury oxidation by the addition of HBr, which included concentrations of chlorine and sulfur in the flue gas. Chlorine species seemed to be involved in the competition with bromine species in the mercury oxidation process. With the addition of HBr at 3 ppm at a temperature of about 330 C, the additional mercury oxidation could be reached by about 55% in a flue gas atmosphere by burning PRB coal in the flue gas and by about 20% in a flue gas by burning bituminous coal. These are both greater than the maximum gaseous HgBr2 percentage in the flue gas (35% for PRB coal and 5% for bituminous coal) by thermodynamic equilibrium analysis predictions under the same conditions. This disagreement may indicate a greater complexity of mercury oxidation mechanisms by the addition of HBr. It is possible that bromine species promote activated chlorine species generation in the flue gas, where the kinetics of elemental mercury oxidation were enhanced. However, SO{sub 2} in the flue gas may involve the consumption of the available activated chlorine species. Thus, the higher mercury oxidation rate by adding bromine under the flue gas by burning PRB coal may be associated with its lower SO{sub 2} concentration in the flue gas. 39 refs., 8 figs., 4 tabs.

  1. Trace element emissions. Semi-annual report, October 1994--February 1995

    SciTech Connect (OSTI)

    Pigeaud, A.; Maru, H.; Wilemski, G.; Helble, J.

    1995-02-01T23:59:59.000Z

    Many trace elements can exist in raw coal gas either in the form of metallic vapors or gaseous compounds which, besides their action on potentially ``very clean`` advanced power generating systems such as fuel cells and gas turbines, can also be detrimental to plant and animal life when released into the atmosphere. Therefore, volatile trace contaminants from coal which can also be toxic must be removed before they become detrimental to both power plant performance/endurance and the environment. Five trace elements were selected in this project based on: abundance in solid coal, volatility during gasification, effects on downstream systems and toxicity to plant and animal life. An understanding was sought in this investigation of the interactions of these five trace elements (and their high temperature species) with the different components in integrated cleanup and power generating systems, as well as the ultimate effects with respect to atmospheric emissions. Utilizing thermodynamic calculations and various experimental techniques, it was determined that a number of trace contaminants that exist in coal may be substantially removed by flyash, and after that by different sorbent systems. High temperature cleanup of contaminants by sorbents such as zinc titanate, primarily to remove sulfur, can also absorb some metallic contaminants such as cadmium and antimony. Further polishing will be required, however, to eliminate trace contaminant species incorporating the elements arsenic, selemium, lead, and mercury.

  2. Analytical and experimental investigations of gas turbine model combustor acoustics operated at atmospheric pressure

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Analytical and experimental investigations of gas turbine model combustor acoustics operated the eigenmodes of the combustor results from the resonant coupling between pressure disturbances in the flame distribution within the combustor, except when these frequencies match. When the frequencies are close to each

  3. Benchmark experiments with global climate models applicable to extra-solar gas giant planets in the shallow atmosphere approximation

    E-Print Network [OSTI]

    Bending, V L; Kolb, U

    2012-01-01T23:59:59.000Z

    The growing field of exoplanetary atmospheric modelling has seen little work on standardised benchmark tests for its models, limiting understanding of the dependence of results on specific models and conditions. With spatially resolved observations as yet difficult to obtain, such a test is invaluable. Although an intercomparison test for models of tidally locked gas giant planets has previously been suggested and carried out, the data provided were limited in terms of comparability. Here, the shallow PUMA model is subjected to such a test, and detailed statistics produced to facilitate comparison, with both time means and the associated standard deviations displayed, removing the time dependence and providing a measure of the variability. Model runs have been analysed to determine the variability between resolutions, and the effect of resolution on the energy spectra studied. Superrotation is a robust and reproducible feature at all resolutions.

  4. On the potential of the EChO mission to characterise gas giant atmospheres

    E-Print Network [OSTI]

    Barstow, Joanna K; Irwin, Patrick G J; Bowles, Neil; Fletcher, Leigh N; Lee, Jae-Min

    2012-01-01T23:59:59.000Z

    Space telescopes such as EChO (Exoplanet Characterisation Observatory) and JWST (James Webb Space Telescope) will be important for the future study of extrasolar planet atmospheres. Both of these missions are capable of performing high sensitivity spectroscopic measurements at moderate resolutions in the visible and infrared, which will allow the characterisation of atmospheric properties using primary and secondary transit spectroscopy. We use the NEMESIS radiative transfer and retrieval tool (Irwin et al. 2008, Lee et al. 2012) to explore the potential of the proposed EChO mission to solve the retrieval problem for a range of H2-He planets orbiting different stars. We find that EChO should be capable of retrieving temperature structure to ~200 K precision and detecting H2O, CO2 and CH4 from a single eclipse measurement for a hot Jupiter orbiting a Sun-like star and a hot Neptune orbiting an M star, also providing upper limits on CO and NH3. We provide a table of retrieval precisions for these quantities in ...

  5. WRF/Chem Simulations Over Fairbanks, AK Atmospheric Stability and Energy Correlation

    E-Print Network [OSTI]

    Moelders, Nicole

    1 WRF/Chem Simulations Over Fairbanks, AK Atmospheric Stability and Energy Correlation Analysis deposition. #12;3 The interactions and cycles of energy, water and trace gas components are also simulated, Alaska, that is characteristic of the Tanana valley; Specifically, Turbulent Kinetic Energy (TKE

  6. Fate of trace elements in UK coals during gasification processes

    SciTech Connect (OSTI)

    Bushell, A.J.; Williamson, J. [Imperial College of Science, Technology and Medicine, London (United Kingdom)

    1996-12-31T23:59:59.000Z

    Five UK coals were selected to cover the range of mineral matter and ash contents typically encountered in UK bituminous coals. Trace element analysis was performed on both the whole coals and size separated fractions using ICP analysis for 21 trace elements, including Be, Cr, Co, Ni, As, Cd, Sb, Hg, and Pb, elements deemed to be the most environmentally hazardous. Small quantities of each coal were gasified in a laboratory gasifier in an atmosphere of N{sub 2} containing 15% O{sub 2}. Samples of bed ash, cyclone ash, and a fine gas-filtered ash were collected and analyzed to determine the partition of the trace elements between the gasification products. Mass balance calculations showed that the recovery of the trace elements varied from 20 to 97%; the low recovery of some trace elements highlighting the difficulties of collecting representative samples from a laboratory system. A parallel study on samples taken from a pilot plant gasifier showed significantly higher recovery rates, indicating the value of larger scale trials.

  7. Effect of O3 on the atmospheric temperature structure of early Mars

    E-Print Network [OSTI]

    von Paris, P; Godolt, M; Grenfell, J L; Stracke, B; Rauer, H

    2015-01-01T23:59:59.000Z

    Ozone is an important radiative trace gas in the Earth's atmosphere. The presence of ozone can significantly influence the thermal structure of an atmosphere, and by this e.g. cloud formation. Photochemical studies suggest that ozone can form in carbon dioxide-rich atmospheres. We investigate the effect of ozone on the temperature structure of simulated early Martian atmospheres. With a 1D radiative-convective model, we calculate temperature-pressure profiles for a 1 bar carbon dioxide atmosphere. Ozone profiles are fixed, parameterized profiles. We vary the location of the ozone layer maximum and the concentration at this maximum. The maximum is placed at different pressure levels in the upper and middle atmosphere (1-10 mbar). Results suggest that the impact of ozone on surface temperatures is relatively small. However, the planetary albedo significantly decreases at large ozone concentrations. Throughout the middle and upper atmospheres, temperatures increase upon introducing ozone due to strong UV absorpt...

  8. ARM - Measurement - Trace gas concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat flux ARM Data Discovery

  9. Tin oxide thick film by doping rare earth for detecting traces of CO{sub 2}: Operating in oxygen-free atmosphere

    SciTech Connect (OSTI)

    Xiong, Ya; Zhang, Guozhu; Zhang, Shunping; Zeng, Dawen; Xie, Changsheng, E-mail: csxie@mail.hust.edu.cn

    2014-04-01T23:59:59.000Z

    Highlights: • La, Gd, and Lu doped SnO{sub 2} with their sensing properties toward CO{sub 2} were compared. • The microstructures of SnO{sub 2}-based nanoparticles were elaborately characterized. • La-SnO{sub 2} thick film shows superior response toward trace ppm CO{sub 2}. • Our sensing material can be recommended to employ in oxygen-free environment. - Abstract: SnO{sub 2} thick films doped with atomic ratios ranging from 0 up to 8 at.% La, 8 at.% Gd, 8 at.% Lu were fabricated, respectively, via hydrothermal and impregnation methods. The crystal phase, morphology, and chemical composition of the SnO{sub 2}-based nanoparticles were characterized by XRD, FE-SEM, EDX, HRTEM and XPS. Sensing properties of La-SnO{sub 2}, Gd-SnO{sub 2}, Lu-SnO{sub 2} films, as well as the pure SnO{sub 2} film, were analyzed toward CO{sub 2} in the absence of O{sub 2}. It was found that the optimal doping element was La and the best doping ratio was 4 at.%. The maximum response appeared at an operating temperature of 250 °C, on which condition the 4 at.% La-SnO{sub 2} exhibited a remarkable improvement of response from 5.12 to 29.8 when increasing CO{sub 2} concentration from 50 to 500 ppm. Furthermore, the working mechanism underlying such enhancement in CO{sub 2}-sensing functions by La additive in the absence of O{sub 2} was proposed and discussed.

  10. Atmospheric composition, radiative forcing, and climate change as a consequence of a massive methane release from gas hydrates

    E-Print Network [OSTI]

    methane release from gas hydrates Gavin A. Schmidt and Drew T. Shindell National Aeronautics and Space of methane gas (CH4) from hydrate deposits on the continental slope. We investigate whether reported PETM, and climate change as a consequence of a massive methane release from gas hydrates, Paleoceanography, 18

  11. Gas-phase synthesis of nitrogen-doped TiO{sub 2} nanorods by microwave plasma torch at atmospheric pressure

    SciTech Connect (OSTI)

    Hong, Yong Cheol; Kim, Jong Hun; Bang, Chan Uk; Uhm, Han Sup [Department of Molecular Science and Technology, Ajou University, San 5, Wonchon-Dong, Youngtong-Gu, Suwon 443-749 (Korea, Republic of)

    2005-11-15T23:59:59.000Z

    Nitrogen (N)-doped titanium dioxide (TiO{sub 2}) nanorods were directly synthesized via decomposition of gas-phase titanium tetrachloride (TiCl{sub 4}) by an atmospheric microwave plasma torch. X-ray diffraction, field-emission scanning electron microscope, field-emission transmission electron microscope, and electron-energy-loss spectroscopy (EELS) have been employed to investigate fraction of the anatase and rutile phases, diameter and length, and chemical composition of the nanorods, respectively. The diameters of the nanorods are approximately 30-80 nm and the length is several micrometers. EELS data show that incorporation of N into the O site of TiO{sub 2} nanorods was enhanced in N{sub 2} gas by the microwave plasma torch. Also, a growth model of the rods was proposed on the basis of vapor-liquid-solid mechanism.

  12. The Proton Transfer Reaction-Mass Spectrometer for Atmospheric Chemistry Tracers of Diesel Exhaust Emissions and Measurements of Trace gas and Aerosol properties.

    E-Print Network [OSTI]

    Collins, Gary S.

    , for it was dependent upon their polarity and the required heat supply for sufficient signals. The pipeline required

  13. U.S. Natural Gas System Methane Emissions: State of Knowledge from LCAs, Inventories, and Atmospheric Measurements (Presentation)

    SciTech Connect (OSTI)

    Heath, G.

    2014-04-01T23:59:59.000Z

    Natural gas (NG) is a potential "bridge fuel" during transition to a decarbonized energy system: It emits less carbon dioxide during combustion than other fossil fuels and can be used in many industries. However, because of the high global warming potential of methane (CH4, the major component of NG), climate benefits from NG use depend on system leakage rates. Some recent estimates of leakage have challenged the benefits of switching from coal to NG, a large near-term greenhouse gas (GHG) reduction opportunity. During this presentation, Garvin will review evidence from multiple perspectives - life cycle assessments (LCAs), inventories and measurements - about NG leakage in the US. Particular attention will be paid to a recent article in Science magazine which reviewed over 20 years of published measurements to better understand what we know about total methane emissions and those from the oil and gas sectors. Scientific and policy implications of the state of knowledge will be discussed.

  14. Modeling Atmospheric Aerosols V. Rao Kotamarthi

    E-Print Network [OSTI]

    Modeling Atmospheric Aerosols V. Rao Kotamarthi and Yan Feng Climate Research Section Environmental Science Division Argonne National Laboratory #12;Outline Atmospheric Aerosols and gas phase heterogeneous reactions Regional Scales and Atmospheric Aerosols Regional Scale Aerosols: Ganges Valley Aerosol

  15. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions into the atmosphere2

    E-Print Network [OSTI]

    Boyer, Edmond

    dioxide sequestration process. The overall carbonation reaction includes the following steps: (1)23 CaCarbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions change.20 This study investigates experimentally the aqueous carbonation mechanisms of an alkaline paper

  16. Sandia National Laboratories: atmospheric chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and atmospheric chemistry that is expected to benefit auto and engine manufacturers, oil and gas utilities, and other industries that employ combustion models. A paper...

  17. Trace elements in coal by glow discharge mass spectrometry

    SciTech Connect (OSTI)

    Jacobs, M.L.; Wilson, C.R.; Pestovich, J. Jr. [WAL Inc., Wheat Ridge, CO (United States)] [and others

    1995-08-01T23:59:59.000Z

    A need and a demand exist for determining trace elements in coal and coal related by-products, especially those elements which may potentially be a health hazard. The provisions of the 1990 clean air act require that the EPA evaluate the emissions of electric utilities for trace elements and other potentially hazardous organic compounds. The coal fired electric utility industry supplies roughly 60% of the total generating capacity of 2,882,525 million kilowatt hours (nearly 3 trillion kilowatt hours) generated in the U.S. This is accomplished by 414 power plants scattered across the country that burned 813,508,000 short tons of coal in 1993. The relative volatility of some inorganic constituents in coal makes them more prone to be emitted to the atmosphere following combustion. The production of analytical data for trace elements is known to be a difficult task in coal and by-products of coal combustion (fly ash, bottom ash, gas streams, etc.), in terms of both sample collection and analytical determinations. There are several common analytical methods available to the analyst to determine trace elements in coal and coal by-products. In general analytical germs, the material to be analyzed can be totally solubilized (or extracted), or the elements analytes can be determined in the material as a solid. A relatively new elemental technique, Glow Discharge Mass Spectrometry (GDMS) can be used with solids as well. This new analytical technique had never before been applied directly to coal. The radio frequency-glow discharge quadropole mass spectrometer was used to analyze coal directly for the first time ever by rf-GDMS. The rf-GDMS technique is described.

  18. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, O.A.; Stencel, J.R.

    1987-10-02T23:59:59.000Z

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The moisture then passes through a combustion chamber where hydrogen gas in the form of H/sub 2/ or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  19. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, Otto A. (Langhorne, PA); Stencel, Joseph R. (Skillman, NJ)

    1990-01-01T23:59:59.000Z

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The mixture then passes through a combustion chamber where hydrogen gas in the form of H.sub.2 or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  20. atmospheric physics: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effects Within The Frame Of Physics CERN Preprints Summary: The atmospheric greenhouse effect, an idea that authors trace back to the traditional works of Fourier 1824,...

  1. angstrom noble gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (AMS) and Atom Trap Trace Analysis (ATTA). Collon, P; Lu, Z T 2004-01-01 5 Tracing Noble Gas Radionuclides in the Environment Nuclear Experiment (arXiv) Summary: Trace analysis of...

  2. Sensitive Multi-Species Emissions Monitoring: Infrared Laser-Based Detection of Trace-Level Contaminants.

    SciTech Connect (OSTI)

    Steill, Jeffrey D

    2015-01-01T23:59:59.000Z

    This report summarizes our development of spectroscopic chemical analysis techniques and spectral modeling for trace-gas measurements of highly-regulated low-concentration species present in flue gas emissions from utility coal boilers such as HCl under conditions of high humidity. Detailed spectral modeling of the spectroscopy of HCl and other important combustion and atmospheric species such as H 2 O, CO 2 , N 2 O, NO 2 , SO 2 , and CH 4 demonstrates that IR-laser spectroscopy is a sensitive multi-component analysis strategy. Experimental measurements from techniques based on IR laser spectroscopy are presented that demonstrate sub-ppm sensitivity levels to these species. Photoacoustic infrared spectroscopy is used to detect and quantify HCl at ppm levels with extremely high signal-to-noise even under conditions of high relative humidity. Additionally, cavity ring-down IR spectroscopy is used to achieve an extremely high sensitivity to combustion trace gases in this spectral region; ppm level CH 4 is one demonstrated example. The importance of spectral resolution in the sensitivity of a trace-gas measurement is examined by spectral modeling in the mid- and near-IR, and efforts to improve measurement resolution through novel instrument development are described. While previous project reports focused on benefits and complexities of the dual-etalon cavity ring-down infrared spectrometer, here details on steps taken to implement this unique and potentially revolutionary instrument are described. This report also illustrates and critiques the general strategy of IR- laser photodetection of trace gases leading to the conclusion that mid-IR laser spectroscopy techniques provide a promising basis for further instrument development and implementation that will enable cost-effective sensitive detection of multiple key contaminant species simultaneously.

  3. Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas, desorbtion, tracing, migration Overview The discovery of shale gas in UK Shales demonstrates how important and no doubt will vary from shale to shale. An improved understanding of the controls on gas production from

  4. TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID...

    Open Energy Info (EERE)

    FLUID-INCLUSION GAS CHEMISTRY Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING...

  5. Human effects on the global atmosphere

    SciTech Connect (OSTI)

    Johnston, H.S.

    1984-01-01T23:59:59.000Z

    This review considers whether human activities can significantly change important functions of the global atmosphere by altering the amount or distribution of certain trace species. It deals with three specific topics: stratopheric ozone, the role of species other than carbon dioxide on the greenhouse effect, and certain recently recognized atmospheric consequences of a large scale nuclear war. 64 references, 10 figures, 2 tables.

  6. Historical Doses from Tritiated Water and Tritiated Hydrogen Gas Released to the Atmosphere from Lawrence Livermore National Laboratory (LLNL). Part 6. Summary

    SciTech Connect (OSTI)

    Peterson, S

    2007-09-05T23:59:59.000Z

    Throughout fifty-three years of operations, an estimated 792,000 Ci (29,300 TBq) of tritium have been released to the atmosphere at the Livermore site of Lawrence Livermore National Laboratory (LLNL); about 75% was tritium gas (HT) primarily from the accidental releases of 1965 and 1970. Routine emissions contributed slightly more than 100,000 Ci (3,700 TBq) HT and about 75,000 Ci (2,800 TBq) tritiated water vapor (HTO) to the total. A Tritium Dose Reconstruction was undertaken to estimate both the annual doses to the public for each year of LLNL operations and the doses from the few accidental releases. Some of the dose calculations were new, and the others could be compared with those calculated by LLNL. Annual doses (means and 95% confidence intervals) to the potentially most exposed member of the public were calculated for all years using the same model and the same assumptions. Predicted tritium concentrations in air were compared with observed mean annual concentrations at one location from 1973 onwards. Doses predicted from annual emissions were compared with those reported in the past by LLNL. The highest annual mean dose predicted from routine emissions was 34 {micro}Sv (3.4 mrem) in 1957; its upper confidence limit, based on very conservative assumptions about the speciation of the release, was 370 {micro}Sv (37 mrem). The upper confidence limits for most annual doses were well below the current regulatory limit of 100 {micro}Sv (10 mrem) for dose to the public from release to the atmosphere; the few doses that exceeded this were well below the regulatory limits of the time. Lacking the hourly meteorological data needed to calculate doses from historical accidental releases, ingestion/inhalation dose ratios were derived from a time-dependent accident consequence model that accounts for the complex behavior of tritium in the environment. Ratios were modified to account for only those foods growing at the time of the releases. The highest dose from an accidental release was calculated for a release of about 1,500 Ci HTO that occurred in October 1954. The likely dose for this release was probably less than 360 {micro}Sv (36 mrem), but, because of many unknowns (e.g., release-specific meteorological and accidental conditions) and conservative assumptions, the uncertainty was very high. As a result, the upper confidence limit on the predictions, considered a dose that could not have been exceeded, was estimated to be 2 mSv (200 mrem). The next highest dose, from the 1970 accidental release of about 290,000 Ci (10,700 TBq) HT when wind speed and wind direction were known, was one-third as great. Doses from LLNL accidental releases were well below regulatory reporting limits. All doses, from both routine and accidental releases, were far below the level (3.6 mSv [360 mrem] per year) at which adverse health effects have been documented in the literature.

  7. Apparatus and method for atmospheric pressure reactive atom plasma processing for shaping of damage free surfaces

    DOE Patents [OSTI]

    Carr; Jeffrey W. (Livermore, CA)

    2009-03-31T23:59:59.000Z

    Fabrication apparatus and methods are disclosed for shaping and finishing difficult materials with no subsurface damage. The apparatus and methods use an atmospheric pressure mixed gas plasma discharge as a sub-aperture polisher of, for example, fused silica and single crystal silicon, silicon carbide and other materials. In one example, workpiece material is removed at the atomic level through reaction with fluorine atoms. In this example, these reactive species are produced by a noble gas plasma from trace constituent fluorocarbons or other fluorine containing gases added to the host argon matrix. The products of the reaction are gas phase compounds that flow from the surface of the workpiece, exposing fresh material to the etchant without condensation and redeposition on the newly created surface. The discharge provides a stable and predictable distribution of reactive species permitting the generation of a predetermined surface by translating the plasma across the workpiece along a calculated path.

  8. Prediction of rainwater acidity using trace element concentrations

    SciTech Connect (OSTI)

    Vong, R.J.; Peterson, R.E. (Univ. of Washington, Seattle (USA))

    1988-09-01T23:59:59.000Z

    It is of interest to be able to estimate the contribution of an anthropogenic emission source to downwind rainwater chemistry. The authors here consider the closure of a large copper smelter which operated in a region where background and other emission sources should contribute smaller amounts of atmospheric sulfur than the smelter. An additional simplification existed in that meteorology associated with rain was relatively well known and consistent. A field experiment was conducted in the winters of 1985 and 1986 to collect rainwater at sites upwind and downwind of the Tacoma, Washington smelter. The smelters SO{sub 2} emissions, their conversion to SO{sub 4}= via three oxidants (O{sub 3}, H{sub 2}O{sub 2}, and O{sub 2} - Fe catalyzed reactions), diffusion, transport, and aerosol/gas scavenging previously have been estimated while adjusting model parameters until the predictions fit the rainwater data. To take advantage of the unique experimental design afforded by the closure of the smelter, statistical analysis was performed on NO{sub 3}-, SO{sub 4}(xs)= (excess of seasalt), and pH data; analysis of variance (ANOVA) confirmed that the smelter had a significant (p < .01) influence on rainwater pH and SO{sub 4}(xs). The analysis presented here extends the ANOVA by applying a multivariate regression technique to new data for trace element concentrations for the same rain samples. To predict rainwater acidity, they derive fingerprints from trace element data, identify a source or process related to that fingerprint, and compare the predicted contributions for pre- and post- closure samples.

  9. Investigation into the effects of trace coal syn gas species on the performance of solid oxide fuel cell anodes, PhD. thesis, Russ College of Engineering and Technology of Ohio University

    SciTech Connect (OSTI)

    Trembly, J.P.

    2007-06-01T23:59:59.000Z

    Coal is the United States’ most widely used fossil fuel for the production of electric power. Coal’s availability and cost dictates that it will be used for many years to come in the United States for power production. As a result of the environmental impact of burning coal for power production more efficient and environmentally benign power production processes using coal are sought. Solid oxide fuel cells (SOFCs) combined with gasification technologies represent a potential methodology to produce electric power using coal in a much more efficient and cleaner manner. It has been shown in the past that trace species contained in coal, such as sulfur, severely degrade the performance of solid oxide fuel cells rendering them useless. Coal derived syngas cleanup technologies have been developed that efficiently remove sulfur to levels that do not cause any performance losses in solid oxide fuel cells. The ability of these systems to clean other trace species contained in syngas is not known nor is the effect of these trace species on the performance of solid oxide fuel cells. This works presents the thermodynamic and diffusion transport simulations that were combined with experimental testing to evaluate the effects of the trace species on the performance of solid oxide fuel cells. The results show that some trace species contained in coal will interact with the SOFC anode. In addition to the transport and thermodynamic simulations that were completed experimental tests were completed investigating the effect of HCl and AsH3 on the performance of SOFCs.

  10. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); Summers, Cathy A. (Albany, OR); Gerdemann, Steve (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul (Independence, OR); Patrick, Brian R. (Chicago, IL)

    2011-10-18T23:59:59.000Z

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  11. Statistical analysis of aerosol species, trace gasses, and meteorology in Chicago

    E-Print Network [OSTI]

    O'Brien, Timothy E.

    in uncovering linear relationships between meteorology and air pollutants in Chicago and aided in determining possible pollutant sources. Keywords Atmospheric aerosols . Canonical correlation analysis . Chicago air pollution . Multivariate statistics . Principal component analysis . Trace gasses Introduction Many air

  12. Influence of Atmospheric Pressure and Water Table Fluctuations on Gas Phase Flow and Transport of Volatile Organic Compounds (VOCs) in Unsaturated Zones

    E-Print Network [OSTI]

    You, Kehua

    2013-04-19T23:59:59.000Z

    Understanding the gas phase flow and transport of volatile organic compounds (VOCs) in unsaturated zones is indispensable to develop effective environmental remediation strategies, to create precautions for fresh water protection, and to provide...

  13. Quantifying the Digital Traces of Hurricane Sandy on Flickr

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Quantifying the Digital Traces of Hurricane Sandy on Flickr Tobias Preis1 *, Helen Susannah Moat1 social science. To investigate user attention to the Hurricane Sandy disaster in 2012, we analyze data to Hurricane Sandy bears a striking correlation to the atmospheric pressure in the US state New Jersey during

  14. Deriving emissions time series from sparse atmospheric mole fractions

    E-Print Network [OSTI]

    Rigby, Matthew

    A growth-based Bayesian inverse method is presented for deriving emissions of atmospheric trace species from temporally sparse measurements of their mole fractions. This work is motivated by many recent studies that have ...

  15. Atmospheric Neutrinos

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2006-12-11T23:59:59.000Z

    This paper is a brief overview of the theory and experimental data of atmospheric neutrino production at the fiftieth anniversary of the experimental discovery of neutrinos.

  16. Molecular gas and AGN fueling

    E-Print Network [OSTI]

    F. Combes

    2003-08-01T23:59:59.000Z

    CO emission, tracing the molecular content and distribution in galaxies, is a privileged tool to trace gas towards the nucleus, since the HI tracer is in general depleted there. A review is done of recent CO line observations, with sufficient spatial resolution to indicate the morphology and kinematics of the gas near the nucleus. The puzzling result that nuclei presently observed in an active phase have little sign of fueling, is discussed.

  17. Atom trap trace analysis of krypton isotopes

    SciTech Connect (OSTI)

    Bailey, K.; Chen, C. Y.; Du, X.; Li, Y. M.; Lu, Z.-T.; O'Connor, T. P.; Young, L.

    1999-11-17T23:59:59.000Z

    A new method of ultrasensitive isotope trace analysis has been developed. This method, based on the technique of laser manipulation of neutral atoms, has been used to count individual {sup 85}Kr and {sup 81}Kr atoms present in a natural krypton gas sample with isotopic abundances in the range of 10{sup {minus}11} and 10{sup {minus}13}, respectively. This method is free of contamination from other isotopes and elements and can be applied to several different isotope tracers for a wide range of applications. The demonstrated detection efficiency is 1 x 10{sup {minus}7}. System improvements could increase the efficiency by many orders of magnitude.

  18. Using Hierarchical Simplicial Meshes to Render Atmospheric Effects

    E-Print Network [OSTI]

    Atalay, F. Betül

    Using Hierarchical Simplicial Meshes to Render Atmospheric Effects F. Betul Atalay David M. Mount natural phenomena. An important problem in this area is that of rendering scenes containing atmospheric and smoke. Generating photorealistic renderings through ray-tracing is computationally very demanding

  19. atmospheric emissions control: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H? in a forest environment : from canopy to soil MIT - DSpace Summary: Atmospheric hydrogen (H? ), an indirect greenhouse gas, plays a notable role in the chemistry of the...

  20. Mid-Infrared Laser based Gas Sensor Technologies for Environmental Monitoring,

    E-Print Network [OSTI]

    , quantification and monitoring of trace gas species and their applications in environmental and industrial process performing sensitive trace gas measurements in gas samples of a few mm3 in volume. QEPAS employs readilyChapter XX Mid-Infrared Laser based Gas Sensor Technologies for Environmental Monitoring, Medical

  1. BNL-65897-AB NEW DETECTABILITY IN ATMOSPHERIC PERFLUOROCARBON TRACING

    E-Print Network [OSTI]

    J. Rappolt Tracer Environmental Sciences & Technologies, Inc. San Marcos, CA 92069. Presented.S. Department of Energy under Contract No. DE-AC02-98CH10886. #12;

  2. atmospheric trace element: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concern, and provides an incentive to study metals in food webs of other (Katsuwonus pelamis) and Common Dolfinfish (Coryphaena hippurus), which are at the top of marine food...

  3. atmospheric trace metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concern, and provides an incentive to study metals in food webs of other (Katsuwonus pelamis) and Common Dolfinfish (Coryphaena hippurus), which are at the top of marine food...

  4. Interactive Visualization of Modeled Atmospheric Trace Constituents Carmen M. Benkovitz

    E-Print Network [OSTI]

    directly as particles, for example from industrial activities, biomass burning, mineral dust sources biogenic ocean and land processes, SO from volcanoes (degassing 2and erupting), SO from biomass burning emissions in Europe and Asia are prominent on this date. The softwar

  5. atmospheric trace gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    it back down to the Earth. This phenomenon, called the greenhouse. Without the greenhouse effect, the Earth's average surface temperature would be about 60 Fahrenheit 29...

  6. Historical Doses from Tritiated Water and Tritiated Hydrogen Gas Released to the Atmosphere from Lawrence Livermore National Laboratory (LLNL). Part 5. Accidental Releases

    SciTech Connect (OSTI)

    Peterson, S

    2007-08-15T23:59:59.000Z

    Over the course of fifty-three years, LLNL had six acute releases of tritiated hydrogen gas (HT) and one acute release of tritiated water vapor (HTO) that were too large relative to the annual releases to be included as part of the annual releases from normal operations detailed in Parts 3 and 4 of the Tritium Dose Reconstruction (TDR). Sandia National Laboratories/California (SNL/CA) had one such release of HT and one of HTO. Doses to the maximally exposed individual (MEI) for these accidents have been modeled using an equation derived from the time-dependent tritium model, UFOTRI, and parameter values based on expert judgment. All of these acute releases are described in this report. Doses that could not have been exceeded from the large HT releases of 1965 and 1970 were calculated to be 43 {micro}Sv (4.3 mrem) and 120 {micro}Sv (12 mrem) to an adult, respectively. Two published sets of dose predictions for the accidental HT release in 1970 are compared with the dose predictions of this TDR. The highest predicted dose was for an acute release of HTO in 1954. For this release, the dose that could not have been exceeded was estimated to have been 2 mSv (200 mrem), although, because of the high uncertainty about the predictions, the likely dose may have been as low as 360 {micro}Sv (36 mrem) or less. The estimated maximum exposures from the accidental releases were such that no adverse health effects would be expected. Appendix A lists all accidents and large routine puff releases that have occurred at LLNL and SNL/CA between 1953 and 2005. Appendix B describes the processes unique to tritium that must be modeled after an acute release, some of the time-dependent tritium models being used today, and the results of tests of these models.

  7. Atmospheric Aerosols Workshop | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Aerosols Workshop Atmospheric Aerosols Workshop EMSL Science Theme Advisory Panel Workshop - Atmospheric Aerosol Chemistry, Climate Change, and Air Quality. Baer DR, BJ...

  8. Heat-Traced Fluid Transfer Lines

    E-Print Network [OSTI]

    Schilling, R. E.

    1984-01-01T23:59:59.000Z

    HEAT-TRACED FLUID TRANSFER LINES Robert E. Schilling, P.E. Eaton Corporation Aurora, Ohio This paper discusses basic considerations in designing a heat tracing system using either steam or electrical tracing. Four basic reasons to heat...

  9. Tracing Geothermal Fluids

    SciTech Connect (OSTI)

    Michael C. Adams; Greg Nash

    2004-03-01T23:59:59.000Z

    Geothermal water must be injected back into the reservoir after it has been used for power production. Injection is critical in maximizing the power production and lifetime of the reservoir. To use injectate effectively the direction and velocity of the injected water must be known or inferred. This information can be obtained by using chemical tracers to track the subsurface flow paths of the injected fluid. Tracers are chemical compounds that are added to the water as it is injected back into the reservoir. The hot production water is monitored for the presence of this tracer using the most sensitive analytic methods that are economically feasible. The amount and concentration pattern of the tracer revealed by this monitoring can be used to evaluate how effective the injection strategy is. However, the tracers must have properties that suite the environment that they will be used in. This requires careful consideration and testing of the tracer properties. In previous and parallel investigations we have developed tracers that are suitable from tracing liquid water. In this investigation, we developed tracers that can be used for steam and mixed water/steam environments. This work will improve the efficiency of injection management in geothermal fields, lowering the cost of energy production and increasing the power output of these systems.

  10. Epidemic Contact Tracing via Communication Traces Katayoun Farrahi1

    E-Print Network [OSTI]

    interactions, where contagious outbreaks propagate. However, due to privacy constraints and noisy data traces may be a viable option to arrest contagious outbreaks. Citation: Farrahi K, Emonet R, Cebrian M

  11. Adsorptive Stripping Voltammetric Measurements of Trace Uranium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adsorptive Stripping Voltammetric Measurements of Trace Uranium at the Bismuth Film Electrode. Adsorptive Stripping Voltammetric Measurements of Trace Uranium at the Bismuth Film...

  12. Enhanced membrane gas separations

    SciTech Connect (OSTI)

    Prasad, R.

    1993-07-13T23:59:59.000Z

    An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

  13. Atmospheric Aerosol Systems | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Themes Atmospheric Aerosol Systems Overview Atmospheric Aerosol Systems Biosystem Dynamics & Design Energy Materials & Processes Terrestrial & Subsurface Ecosystems...

  14. Trace tritium and the H-mode density limit G.F. Matthews a,*, K.-D. Zastrow a

    E-Print Network [OSTI]

    Basse, Nils Plesner

    Trace tritium and the H-mode density limit G.F. Matthews a,*, K.-D. Zastrow a , P. Andrew a , B University, Princeton, NJ 08543, USA Abstract Trace amounts of tritium gas have been injected in short pus then saturation of the separatrix density implies clamping of the core density. Short pus of tritium were used

  15. INTRODUCTIONTOTHE SOLAR ATMOSPHERE

    E-Print Network [OSTI]

    ? #12;WHAT ISTHE SOLAR ATMOSPHERE? #12;#12;1-D MODEL ATMOSPHERE · Averaged over space and time · GoodINTRODUCTIONTOTHE SOLAR ATMOSPHERE D. Shaun Bloomfield Trinity College Dublin #12;OUTLINE · What is the solar atmosphere? · How is the solar atmosphere observed? · What structures exist and how do they evolve

  16. Mechanistic, sensitivity, and uncertainty studies of the atmospheric oxidation of dimethylsulfide

    E-Print Network [OSTI]

    Lucas, Donald David, 1969-

    2003-01-01T23:59:59.000Z

    The global-scale emissions and reactivity of dimethylsulfide (CH3SCH3, DMS) make it an integral component in the atmospheric sulfur cycle. DMS is rapidly oxidized in the atmosphere by a complex gas-phase mechanism involving ...

  17. The aging of organic aerosol in the atmosphere : chemical transformations by heterogeneous oxidation

    E-Print Network [OSTI]

    Kessler, Sean Herbert

    2013-01-01T23:59:59.000Z

    The immense chemical complexity of atmospheric organic particulate matter ("aerosol") has left the general field of condensed-phase atmospheric organic chemistry relatively under-developed when compared with either gas-phase ...

  18. Field measurement of the fate of atmospheric H? in a forest environment : from canopy to soil

    E-Print Network [OSTI]

    Meredith, Laura Kelsey, 1982-

    2013-01-01T23:59:59.000Z

    Atmospheric hydrogen (H? ), an indirect greenhouse gas, plays a notable role in the chemistry of the atmosphere and ozone layer. Current anthropogenic emissions of H? are substantial and may increase with its widespread ...

  19. The Cosmological Context of Extraplanar Gas

    E-Print Network [OSTI]

    James Binney

    2004-09-27T23:59:59.000Z

    I review evidence that galaxies form from gas that falls into potential wells cold, rather than from virialized gas, and that formation stops once an atmosphere of trapped virialized gas has accumulated. Disk galaxies do not have such atmospheres, so their formation is ongoing. During galaxy formation feedback is an efficient process, and the nuclear regions of disk galaxies blow winds. The cold infalling gas that drives continued star formation has a significant component of angular momentum perpendicular to that of the disk. Extraplanar gas has to be understood in the context set by nuclear outflows and cold skew-rotating cosmic infall.

  20. Distributed trace using central performance counter memory

    DOE Patents [OSTI]

    Satterfield, David L; Sexton, James C

    2013-10-22T23:59:59.000Z

    A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

  1. Distributed trace using central performance counter memory

    DOE Patents [OSTI]

    Satterfield, David L.; Sexton, James C.

    2013-01-22T23:59:59.000Z

    A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

  2. LEARNING FROM BULLYING TRACES IN SOCIAL MEDIA

    E-Print Network [OSTI]

    Zhu, Xiaojin "Jerry"

    of bullying traces collected Lady Gaga Movie: Bully #12;Questions NLP Can Help with 8 Is the post a bullying

  3. Cosmic-ray strangelets in the Earth's atmosphere

    E-Print Network [OSTI]

    B. Monreal

    2006-11-03T23:59:59.000Z

    If strange quark matter is stable in small lumps, we expect to find such lumps, called ``strangelets'', on Earth due to a steady flux in cosmic rays. Following recent astrophysical models, we predict the strangelet flux at the top of the atmosphere, and trace the strangelets' behavior in atmospheric chemistry and circulation. We show that several strangelet species may have large abundances in the atmosphere; that they should respond favorably to laboratory-scale preconcentration techniques; and that they present promising targets for mass spectroscopy experiments.

  4. Atmospheric-pressure plasma jet

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1999-01-01T23:59:59.000Z

    Atmospheric-pressure plasma jet. A .gamma.-mode, resonant-cavity plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two concentric cylindrical electrodes are employed to generate a plasma in the annular region therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly shaping the rf-powered electrode. Because of the atmospheric pressure operation, no ions survive for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike low-pressure plasma sources and conventional plasma processing methods.

  5. Multi-Gas Assessment of the Kyoto Protocol John Reilly,*

    E-Print Network [OSTI]

    Multi-Gas Assessment of the Kyoto Protocol John Reilly,* Ronald G. Prinn,* Jochen Harnisch,* Jean in the protocol appear to be an adequate representation of trace gas climatic effects. The principal reason for the success of this simplified GWP approach in our calculations is that the mix of gas emissions resulting

  6. Casimir Effect and Trace formula Andreas Wirzba

    E-Print Network [OSTI]

    Wirzba, Andreas - Helmholtz-Institut für Strahlen- und Kernphysik (HISKP)

    1 Casimir Effect and Trace formula Andreas Wirzba Institut f¨ur Kernphysik Forschungszentrum J¨ulich · · Andreas Wirzba Casimir effect and trace formula Copenhagen, 17 May 2006 #12;1 Casimir Effect and Trace formula Andreas Wirzba Institut f¨ur Kernphysik Forschungszentrum J¨ulich 1. Introduction to the Casimir

  7. Measurements and Analyses of Urban Metabolism and Trace Gas Respiration

    E-Print Network [OSTI]

    McManus, J.B.

    2002-05-30T23:59:59.000Z

    Human society has well defined metabolic processes that can be characterized and quantified in the same way that an ecosystem’s metabolism can be defined and understood [Fischer-Kowalski, 1998.] The study of “industrial ...

  8. Estimation of atmospheric deposition in coastal Jalisco, western Mexico, using an epiphytic plant (Tillandsia recurvata L. Bromeliaceae)

    E-Print Network [OSTI]

    Sahagun Godinez, Eduardo

    1998-01-01T23:59:59.000Z

    Ttllandsia recurvata was used as a biomonitor to ographics. estimate the trace element atmospheric deposition in a tropical dry forest of the Pacific coast of Jalisco, in western Mexico. The plant samples were initially collected gem a population...

  9. Estimation of atmospheric deposition in coastal Jalisco, western Mexico, using an epiphytic plant (Tillandsia recurvata L. Bromeliaceae) 

    E-Print Network [OSTI]

    Sahagun Godinez, Eduardo

    1998-01-01T23:59:59.000Z

    Ttllandsia recurvata was used as a biomonitor to ographics. estimate the trace element atmospheric deposition in a tropical dry forest of the Pacific coast of Jalisco, in western Mexico. The plant samples were initially ...

  10. Trace Explosive Detection Using Nanosensors

    SciTech Connect (OSTI)

    Senesac, Larry R [ORNL; Thundat, Thomas George [ORNL

    2008-01-01T23:59:59.000Z

    Selective and sensitive detection of explosives is very important in countering terrorist threats. Detecting trace explosives has become a very complex and expensive endeavor because of a number of factors, such as the wide variety of materials that can be used as explosives, the lack of easily detectable signatures, the vast number of avenues by which these weapons can be deployed, and the lack of inexpensive sensors with high sensitivity and selectivity. High sensitivity and selectivity, combined with the ability to lower the deployment cost of sensors using mass production, is essential in winning the war on explosives-based terrorism. Nanosensors have the potential to satisfy all the requirements for an effective platform for the trace detection of explosives.

  11. Improved helium exchange gas cryostat and sample tube designs for automated gas sampling and cryopumping

    E-Print Network [OSTI]

    Severinghaus, Jeffrey P.

    Improved helium exchange gas cryostat and sample tube designs for automated gas sampling, California 92093-0244, USA [1] In order to eliminate the use of liquid helium for the extraction of atmospheric gases from polar ice cores, two units of a redesigned top load helium exchange gas cryostat were

  12. Apparatus and method for monitoring of gas having stable isotopes

    DOE Patents [OSTI]

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05T23:59:59.000Z

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  13. The Natural Aerodynamic Sampling of Trace Explosives from the Human Body

    E-Print Network [OSTI]

    Settles, Gary S.

    The Natural Aerodynamic Sampling of Trace Explosives from the Human Body Gary S. Settles, Huban A. Gowadia, Sean B. Strine, and Timothy E. Johnson Gas Dynamics Lab, Mechanical Engineering Dept., 301D Reber developed for this purpose, their widespread use may be too slow for airport security use and may

  14. Trace Holdings | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlin Baxin Hydropower StationTown ofTown ofTown ofTrace Holdings Jump to:

  15. Reactive trace metals in the stratified central North Pacific

    SciTech Connect (OSTI)

    Bruland, K.W. (Univ. of California, Santa Cruz, CA (United States)); Orians, K.J. (Univ. of British Columbia, Vancouver (Canada)); Cowen, J.P. (Univ. of Hawaii, Manoa, HI (United States))

    1994-08-01T23:59:59.000Z

    Vertical concentration profiles of the dissolved and suspended particulate phases were determined for a suite of reactive trace metals, Al, Fe, Mn, Zn, and Cd, during summertime at a station in the center of the North Pacific gyre. During summer the euphotic zone becomes stratified, forming a shallow (0-25 m), oligotrophic, mixed layer overlying a subsurface (25-140 m), strongly-stratified region. The physical, biological, and chemical structure within the euphotic zone during this period enhanced the effect of atmospheric inputs of Al, Fe, and Mn on mixed layer concentrations. For example, the concentration of dissolved Fe in the surface mixed layer was eighteen times that observed at a depth of 100 m. The observed aeolian signature of these metals matched that predicted from estimates of atmospheric input during the period between the onset of stratification and sampling. The distributions of suspended particulate Al, Fe, and Mn all exhibited minima in the euphotic zone and increased with depth into the main thermocline. Particulate Al and Fe were then uniform with depth below 1000 m before increasing in the near bottom nepheloid layer. Average particulate phase concentrations in intermediate and deep waters of the central North Pacific were 1.0, 0.31, and 0.055 nmol[center dot]kg[sup [minus]1] for Al, Fe, and Mn, respectively. The distribution of particulate Cd exhibited a maximum within the subsurface euphotic zone. Particulate zinc also exhibited a surface maximum, albeit a smaller one. Concentrations of particulate Zn and Cd in intermediate and deep waters were 17 and 0.2 pmol[center dot]kg[sup [minus]1]. Substantial interbasin differences in particulate trace metals occur. Concentrations of suspended particulate Al, Fe, and Mn were three to four times lower in the central North Pacific than recently reported for the central North Atlantic gyre, consistent with differences in atmospheric input to these two regions.

  16. On detecting biospheres from thermodynamic disequilibrium in planetary atmospheres

    E-Print Network [OSTI]

    Krissansen-Totton, Joshua; Catling, David C

    2015-01-01T23:59:59.000Z

    Atmospheric chemical disequilibrium has been proposed as a method for detecting extraterrestrial biospheres from exoplanet observations. Chemical disequilibrium is potentially a generalized biosignature since it makes no assumptions about particular biogenic gases or metabolisms. Here, we present the first rigorous calculations of the thermodynamic chemical disequilibrium in the atmospheres of Solar System planets, in which we quantify the difference in Gibbs free energy of an observed atmosphere compared to that of all the atmospheric gases reacted to equilibrium. The purely gas phase disequilibrium in Earth's atmosphere, as measured by this available Gibbs free energy, is not unusual by Solar System standards and smaller than that of Mars. However, Earth's atmosphere is in contact with a surface ocean, which means that gases can react with water, and so a multiphase calculation that includes aqueous species is required. We find that the disequilibrium in Earth's atmosphere-ocean system (in joules per mole o...

  17. Estimating the benefits of greenhouse gas emission reduction from agricultural policy reform

    SciTech Connect (OSTI)

    Adger, W.N. (Univ. of East Anglia, Norwich (United Kingdom). Centre for Social and Economic Research on the Global Environment); Moran, D.C. (Univ. College, London (United Kingdom). Centre for Social and Economic Research on the Global Environment)

    1993-09-01T23:59:59.000Z

    Land use and agricultural activities contribute directly to the increased concentrations of atmospheric greenhouse gases. Economic support in industrialized countries generally increases agriculture's contribution to global greenhouse gas concentrations through fluxes associated with land use change and other sources. Changes in economic support offers opportunities to reduce net emissions, through this so far has gone unaccounted. Estimates are presented here of emissions of methane from livestock in the UK and show that, in monetary terms, when compared to the costs of reducing support, greenhouse gases are a significant factor. As signatory parties to the Climate Change Convection are required to stabilize emissions of all greenhouse gases, options for reduction of emissions of methane and other trace gases from the agricultural sector should form part of these strategies.

  18. The Upper Atmosphere of HD17156b

    E-Print Network [OSTI]

    T. T. Koskinen; A. D. Aylward; S. Miller

    2008-11-28T23:59:59.000Z

    HD17156b is a newly-found transiting extrasolar giant planet (EGP) that orbits its G-type host star in a highly eccentric orbit (e~0.67) with an orbital semi-major axis of 0.16 AU. Its period, 21.2 Earth days, is the longest among the known transiting planets. The atmosphere of the planet undergoes a 27-fold variation in stellar irradiation during each orbit, making it an interesting subject for atmospheric modelling. We have used a three-dimensional model of the upper atmosphere and ionosphere for extrasolar gas giants in order to simulate the progress of HD17156b along its eccentric orbit. Here we present the results of these simulations and discuss the stability, circulation, and composition in its upper atmosphere. Contrary to the well-known transiting planet HD209458b, we find that the atmosphere of HD17156b is unlikely to escape hydrodynamically at any point along the orbit, even if the upper atmosphere is almost entirely composed of atomic hydrogen and H+, and infrared cooling by H3+ ions is negligible. The nature of the upper atmosphere is sensitive to to the composition of the thermosphere, and in particular to the mixing ratio of H2, as the availability of H2 regulates radiative cooling. In light of different simulations we make specific predictions about the thermosphere-ionosphere system of HD17156b that can potentially be verified by observations.

  19. Atmospheric Transport of Radionuclides

    SciTech Connect (OSTI)

    Crawford, T.V.

    2003-03-03T23:59:59.000Z

    The purpose of atmospheric transport and diffusion calculations is to provide estimates of concentration and surface deposition from routine and accidental releases of pollutants to the atmosphere. This paper discusses this topic.

  20. How atmospheric ice forms | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atmospheric ice forms How atmospheric ice forms Released: September 08, 2014 New insights into atmospheric ice formation could improve climate models This study advances our...

  1. Atmospheric Pressure Reactor System | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Pressure Reactor System Atmospheric Pressure Reactor System The atmospheric pressure reactor system is designed for testing the efficiency of various catalysts for the...

  2. Traces on Module Categories over Fusion Categories

    E-Print Network [OSTI]

    Gregor Schaumann

    2015-01-27T23:59:59.000Z

    We consider traces on module categories over pivotal fusion categories which are compatible with the module structure. It is shown that such module traces characterise the Morita classes of special haploid symmetric Frobenius algebras. Moreover, they are unique up to a scale factor and they equip the dual category with a pivotal structure. This implies that for each pivotal structure on a fusion category over the complex numbers there exists a conjugate pivotal structure defined by the canonical module trace.

  3. Climate Sciences: Atmospheric Thermodynamics

    E-Print Network [OSTI]

    Russell, Lynn

    1 Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http://aerosol.ucsd.edu/courses.html Text: Curry & Webster Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 Energy Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http

  4. Radar remote sensing of the lower atmosphere

    E-Print Network [OSTI]

    Karimian, Ali

    2012-01-01T23:59:59.000Z

    from ray tracing (solid). (d) Clutter power from maximum rayby ray tracing (solid). (d) Clutter power calculated bysolid) and maximum of ray traces (dashed). (d) Clutter power

  5. Coal beneficiation by gas agglomeration

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14T23:59:59.000Z

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  6. Coal Beneficiation by Gas Agglomeration

    SciTech Connect (OSTI)

    Thomas D. Wheelock; Meiyu Shen

    2000-03-15T23:59:59.000Z

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  7. Geothermal: Sponsored by OSTI -- Trace metal characterization...

    Office of Scientific and Technical Information (OSTI)

    Trace metal characterization and speciation in geothermal effluent by multiple scanning anodic stripping voltammetry and atomic absorpotion analysis. Annual progress report...

  8. Global budget of methanol: Constraints from atmospheric observations Daniel J. Jacob,1

    E-Print Network [OSTI]

    Li, Qinbin

    Global budget of methanol: Constraints from atmospheric observations Daniel J. Jacob,1 Brendan D of atmospheric methanol to examine the consistency between observed atmospheric concentrations and current of methanol in the model is 7 days; gas-phase oxidation by OH accounts for 63% of the global sink, dry

  9. Black holes, cuspy atmospheres, and galaxy formation

    E-Print Network [OSTI]

    James Binney

    2004-07-12T23:59:59.000Z

    In cuspy atmospheres, jets driven by supermassive black holes (BHs) offset radiative cooling. The jets fire episodically, but often enough that the cuspy atmosphere does not move very far towards a cooling catastrophe in the intervals of jet inactivity. The ability of energy released on the sub-parsec scale of the BH to balance cooling on scales of several tens of kiloparsecs arises through a combination of the temperature sensitivity of the accretion rate and the way in which the radius of jet disruption varies with ambient density. Accretion of hot gas does not significantly increase BH masses, which are determined by periods of rapid BH growth and star formation when cold gas is briefly abundant at the galactic centre. Hot gas does not accumulate in shallow potential wells. As the Universe ages, deeper wells form, and eventually hot gas accumulates. This gas soon prevents the formation of further stars, since jets powered by the BH prevent it from cooling, and it mops up most cold infalling gas before many stars can form. Thus BHs set the upper limit to the masses of galaxies. The formation of low-mass galaxies is inhibited by a combination of photo-heating and supernova-driven galactic winds. Working in tandem these mechanisms can probably explain the profound difference between the galaxy luminosity function and the mass function of dark halos expected in the cold dark matter cosmology.

  10. Terrestrial Planet Atmospheres. The Moon's Sodium Atmosphere

    E-Print Network [OSTI]

    Walter, Frederick M.

    ;Origins of Atmospheres · Outgassing ­ Volcanoes expel water, CO2, N2, H2S, SO2 removed by the Fme convecFon reaches deserts #12;Water and Ice Clouds #12;H2SO4

  11. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    National Lab Directors, . .

    2001-04-05T23:59:59.000Z

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions. These technology pathways (which are described in greater detail in Appendix B, Technology Pathways) address three areas: energy efficiency, clean energy, and carbon sequestration (removing carbon from emissions and enhancing carbon storage). Based on an assessment of each of these technology pathways over a 30-year planning horizon, the directors of the Department of Energy's (DOE's) national laboratories conclude that success will require pursuit of multiple technology pathways to provide choices and flexibility for reducing greenhouse gas emissions. Advances in science and technology are necessary to reduce greenhouse gas emissions from the United States while sustaining economic growth and providing collateral benefits to the nation.

  12. Combustion-gas recirculation system

    DOE Patents [OSTI]

    Baldwin, Darryl Dean (Lacon, IL)

    2007-10-09T23:59:59.000Z

    A combustion-gas recirculation system has a mixing chamber with a mixing-chamber inlet and a mixing-chamber outlet. The combustion-gas recirculation system may further include a duct connected to the mixing-chamber inlet. Additionally, the combustion-gas recirculation system may include an open inlet channel with a solid outer wall. The open inlet channel may extend into the mixing chamber such that an end of the open inlet channel is disposed between the mixing-chamber inlet and the mixing-chamber outlet. Furthermore, air within the open inlet channel may be at a pressure near or below atmospheric pressure.

  13. Coupling field and laboratory measurements to estimate the emission factors of identified and unidentified trace gases for prescribed fires

    SciTech Connect (OSTI)

    Yokelson, Robert J.; Burling, Ian R.; Gilman, Jessica; Warneke, Carsten; Stockwell, Chelsea E.; de Gouw, Joost A.; Akagi, Sheryl; Urbanski, Shawn; Veres, Patrick; Roberts, James M.; Kuster, W. C.; Reardon, James; Griffith, David WT; Johnson, Timothy J.; Hosseini, SeyedEhsan; Miller, J. Wayne; Cocker, David R.; Jung, H.; Weise, David

    2013-01-07T23:59:59.000Z

    Vegetative fuels commonly consumed in prescribed fires were collected from five locations in the southeastern and southwestern U.S. and burned in a series of 77 fires at the U.S. Forest Service Fire Sciences Laboratory in Missoula, Montana. The particulate matter (PM2.5) emissions were measured by gravimetric filter sampling with subsequent analysis for elemental carbon (EC), organic carbon (OC), and 38 elements. The trace gas emissions were measured with a large suite of state-of-the-art instrumentation including an open-path Fourier transform infrared (OP FTIR) spectrometer, proton-transfer-reaction mass spectrometry (PTR-MS), proton-transfer ion-trap mass spectrometry (PIT-MS), negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS), and gas chromatography with MS detection (GC-MS). 204 trace gas species (mostly non-methane organic compounds (NMOC)) were identified and quantified with the above instruments. An additional 152 significant peaks in the unit mass resolution mass spectra were quantified, but either could not be identified or most of the signal at that molecular mass was unaccounted for by identifiable species. As phase II of this study, we conducted airborne and ground-based sampling of the emissions from real prescribed fires mostly in the same land management units where the fuels for the lab fires were collected. A broad variety, but smaller number of species (21 trace gas species and PM2.5) was measured on 14 fires in chaparral and oak savanna in the southwestern US, as well as pine forest understory in the southeastern US and Sierra Nevada mountains of California. These extensive field measurements of emission factors (EF) for temperate biomass burning are useful both for modeling and to examine the representativeness of our lab fire EF. The lab/field EF ratio for the pine understory fuels was not statistically different from one, on average. However, our lab EF for “smoldering compounds” emitted by burning the semi-arid SW fuels should likely be increased by about a factor of 2.7 to better represent field fires. Based on the lab/field comparison, we present a table with emission factors for 365 pyrogenic species (including unidentified species) for 4 broad fuel types: pine understory, semi-arid shrublands, evergreen canopy, and duff. To our knowledge this is the most complete measurement of biomass burning emissions to date and it should enable improved representation of smoke in atmospheric models. The results provide important insights into the nature of smoke. For example, ~35% (range from 16-71%) of the mass of gas-phase NMOC species was attributed to the species that we could not identify. These unidentified species are likely not represented in most models, but some provision should be made for the fact that they will react in the atmosphere. In addition, the total mass of gas-phase NMOC divided by the mass of co-emitted PM2.5 averaged ~2.6 for the main fire types with a range from ~1.8-8.8. About 36-63% of the NMOC were likely semivolatile or of intermediate volatility. Thus, the gas-phase NMOC represent a large reservoir of potential precursors for secondary formation of organic aerosol. For the one fire in organic soil (Alaskan duff) about 28% of the emitted carbon was present as gas-phase NMOC in contrast to the other fuels for which NMOC accounted for only ~1-3% of emitted carbon. 71% of the mass of NMOC emitted by the smoldering duff was un-identified. The duff results highlight the need to learn more about the emissions from smoldering organic soils. The ?NMOC/“NOx-as-NO” ratio was consistently about ten for the main fire types when accounting for all NMOC, indicating strongly NOx-limited O3 production conditions. Finally, the fuel consumption per unit area was measured on 6 of the 14 prescribed fires and averaged 7.08 ± 2.09 (1?) Mg ha-1.

  14. High concentrations of trace metals in oysters from the Patuxent River, Maryland

    SciTech Connect (OSTI)

    Riedel, G.; Sanders, J.; Abbe, G. [Academy of Natural Sciences, St. Leonard, MD (United States). Benedict Estuarine Research Center

    1995-12-31T23:59:59.000Z

    Oyster (Crassostrea virginica) populations from the Patuxent River have been analyzed for trace metals by a number of organizations over at least the past 19 years. During that period, high concentrations of Cu (200--500 {micro}g/g dry weight), Cd (3--7 {micro}g/g) and Ag (2--8 /{micro}g/g) have been found in oysters from the oyster bars furthest up river. In particular, Cd values in oysters from this region have had concentrations approaching or exceeding current FDA warning levels throughout the period. In previous studies it was suggested that a coal-burning power plant located in that region, Chalk Point Steam Electric Station, was responsible for the copper enrichment due to the corrosion of Cu/Ni alloy condenser tubes. However, a monthly survey of trace elements in the nearby oyster populations from 1986 to the present showed only a small decline in copper concentrations after the plant switched from Cu/Ni to Ti alloy condenser tubes in 1987. Other potential sources for trace metals in the region include municipal and industrial discharges, atmospheric deposition, and biocides (anti-fouling paint in particular). The very rapid rise in trace element concentrations in oysters with position up river, and the lack of such a response by another local bivalve, the hooked mussel (Ischadium recurvum), suggests that a physiological effect of low salinity stress on oysters may be in part responsible for the high concentrations of trace metals in oysters in this region.

  15. EMSL - Atmospheric Aerosol Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scienceatmospheric The Atmospheric Aerosol Systems Science Theme focuses on understanding the chemistry, physics and molecular-scale dynamics of aerosols for model...

  16. Atmospheric Neutrino Fluxes

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2005-02-18T23:59:59.000Z

    Starting with an historical review, I summarize the status of calculations of the flux of atmospheric neutrinos and how they compare to measurements.

  17. Pulsed atmospheric fluidized bed combustor apparatus

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1993-10-26T23:59:59.000Z

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

  18. Method for remote detection of trace contaminants

    DOE Patents [OSTI]

    Simonson, Robert J.; Hance, Bradley G.

    2003-09-09T23:59:59.000Z

    A method for remote detection of trace contaminants in a target area comprises applying sensor particles that preconcentrate the trace contaminant to the target area and detecting the contaminant-sensitive fluorescence from the sensor particles. The sensor particles can have contaminant-sensitive and contaminant-insensitive fluorescent compounds to enable the determination of the amount of trace contaminant present in the target are by relative comparison of the emission of the fluorescent compounds by a local or remote fluorescence detector. The method can be used to remotely detect buried minefields.

  19. Infrared near-field spectroscopy of trace explosives using an...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spectroscopy of trace explosives using an external cavity quantum cascade laser. Infrared near-field spectroscopy of trace explosives using an external cavity quantum cascade...

  20. Workshop on L-functions and Trace Formula

    E-Print Network [OSTI]

    Ali Altug, Columbia University: Trace formula beyond endoscopy and analytic number theory. I will talk about trace formula and analytic number theory, and how ...

  1. Feasibility of the detection of trace elements in particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of trace elements in particulate matter using online High-Resolution Aerosol Mass Spectrometry. Feasibility of the detection of trace elements in particulate matter using online...

  2. atom trap trace: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 An atom trap trace analysis system for measuring krypton contamination in xenon dark matter detectors Physics Websites Summary: An atom trap trace analysis system for measuring...

  3. Methodology for flammable gas evaluations

    SciTech Connect (OSTI)

    Hopkins, J.D., Westinghouse Hanford

    1996-06-12T23:59:59.000Z

    There are 177 radioactive waste storage tanks at the Hanford Site. The waste generates flammable gases. The waste releases gas continuously, but in some tanks the waste has shown a tendency to trap these flammable gases. When enough gas is trapped in a tank`s waste matrix, it may be released in a way that renders part or all of the tank atmosphere flammable for a period of time. Tanks must be evaluated against previously defined criteria to determine whether they can present a flammable gas hazard. This document presents the methodology for evaluating tanks in two areas of concern in the tank headspace:steady-state flammable-gas concentration resulting from continuous release, and concentration resulting from an episodic gas release.

  4. Additivity of detector responses of a portable direct-reading 10. 2 eV photoionization detector and a flame ionization gas chromatograph for atmospheres of multicomponent organics: use of PID/FID ratios

    SciTech Connect (OSTI)

    Lee, I.N.; Hee, S.S.Q.; Clark, C.S.

    1987-05-01T23:59:59.000Z

    The H-Nu PI-101 with a photoionization detector (PID) of 10.2 eV and Century OVA-128 equipped with a flame ionization detector (FID) were evaluated for the additivity of their responses to a defined mixtures of dissimilar organic vapors at a 0 and 90% relative humidity (RH). The responses of both instruments were additive as long as the effect of RH was accounted for the PID. The PI-101 was not as precise as the Century OVA-128 for 90% RH atmospheres. PID/FID ratios did not change in the presence of 90% RH as long as the effect of RH also was accounted for in the PID reading. The compounds investigated included: toluene, benzaldehyde; 1,2,4-trichlorobenzene, methyl chloroform, methylene dichloride, methyl ethyl ketone, ethanol and acetonitrile.

  5. High resolution atmospheric monitoring of urban carbon dioxide D. E. Pataki,1

    E-Print Network [OSTI]

    Ehleringer, Jim

    the contribution of gasoline versus natural gas combustion to atmospheric CO2 in Salt Lake City. The results showed a pronounced diurnal pattern: the proportional contribution of natural gas combustion varied from 30 period of several days, the proportional contribution of natural gas combustion decreased with air

  6. Atmospheric Dynamics II Instructor

    E-Print Network [OSTI]

    AT602 Atmospheric Dynamics II 2 credits Instructor: David W. J. Thompson davet: An Introduction to Dynamic Meteorology, 5th Edition, Academic Press (recommended) · Marshall, J., and Plumb, R. A., 2008: Atmosphere, Ocean, and Climate Dynamics: An Introductory Text, Academic Press. · Vallis, G. K

  7. Atmospheric Thermodynamics Composition

    E-Print Network [OSTI]

    Russell, Lynn

    1 Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 EnergyBalance Ch4 Water Ch Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http #12;2 Review from Ch. 1 · Thermodynamic quantities · Composition · Pressure · Density · Temperature

  8. Thermophoretic separation of aerosol particles from a sampled gas stream

    SciTech Connect (OSTI)

    Poztman, A.K.

    1986-02-25T23:59:59.000Z

    A method is described for separating aerosol particles from a gas sample being withdrawn from a contained atmosphere, comprising the following steps: placing within the contained atmosphere a covering gas impermeable enclosure have an interior chamber partly defined by a bottom metal plate that is permeable to gas; fixing the position of the enclosure with the plate facing downwardly and directly exposed to the contained atmosphere; heating the metal plate to a temperature greater than that of the contained atmosphere, whereby aerosol particles are repelled to the resulting thermophoretic forces applied to them by the temperature gradient produced in the atmosphere immediately under the plate; and sampling gas within the interior chamber of the enclosure.

  9. Privacy Vulnerability of Published Anonymous Mobility Traces

    E-Print Network [OSTI]

    2010-07-07T23:59:59.000Z

    Sep 20, 2010 ... locations of real users leading to the public availabilities of many such traces through .... infer the private information. ... are open to observations in public spaces. Hence, the ..... value is called the entropy rate of the process X.

  10. RESTRICTED-TRACE APPROXIMATION FOR NUCLEAR ANTIFERROMAGNETISM

    E-Print Network [OSTI]

    Boyer, Edmond

    1353 RESTRICTED-TRACE APPROXIMATION FOR NUCLEAR ANTIFERROMAGNETISM M. GOLDMAN and G. SARMA Service to predict several properties of nuclear antiferromagnetic structures : sublattice magnetization of nuclear dipolar magnetic ordering, either antiferromagnetic or ferromagnetic, has been reported

  11. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

    1984-01-01T23:59:59.000Z

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  12. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15T23:59:59.000Z

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  13. Trace element analysis of Texas lignite

    E-Print Network [OSTI]

    Mahar, Sean

    1982-01-01T23:59:59.000Z

    or in the planning stages, Near surface lignite re- sources are estimated to be 21 billion metric tons in Texas, while deep basin reserves are estimated at 31 billion metric tons. Near (3] surface reserves alone could fulfill Texas' electrical needs for 100 years... for environmental and health concerns trace element characterization of lignites is important. A needed avenue of research is charact- erization of trace element pathways in lignite fired power plants. :hat is to say what percentage of a certain element...

  14. Novel Sorbent-Based Process for High Temperature Trace Metal Removal

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2008-09-30T23:59:59.000Z

    The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

  15. Transitions between corona, glow, and spark regimes of nanosecond repetitively pulsed discharges in air at atmospheric pressure

    E-Print Network [OSTI]

    Boyer, Edmond

    of large volume, low power, high chemical reactivity, and low gas temperature. At atmospheric pressure in air at atmospheric pressure David Z. Pai,a Deanna A. Lacoste, and Christophe O. Laux Laboratoire EM2C January 2010; published online 6 May 2010 In atmospheric pressure air preheated from 300 to 1000 K

  16. The trace formula The Langevin process in R

    E-Print Network [OSTI]

    Herrmann, Samuel

    The trace formula The Langevin process in R Symmetric spaces and the Malliavin calculus and the trace formula Jean-Michel Bismut Universit´e Paris-Sud, Orsay `A la m´emoire de Paul Malliavin Jean-Michel Bismut The Malliavin calculus and the trace formula #12;The trace formula The Langevin process in R

  17. ON THE STABILITY OF SUPER-EARTH ATMOSPHERES

    SciTech Connect (OSTI)

    Heng, Kevin [ETH Zuerich, Institute for Astronomy, Wolfgang-Pauli-Strasse 27, CH-8093, Zuerich (Switzerland); Kopparla, Pushkar [ETH Zuerich, Institute for Atmospheric and Climate Science, Universitaetstrasse 16, CH-8092, Zuerich (Switzerland)

    2012-07-20T23:59:59.000Z

    We investigate the stability of super-Earth atmospheres around M stars using a seven-parameter, analytical framework. We construct stability diagrams in the parameter space of exoplanetary radius versus semimajor axis and elucidate the regions in which the atmospheres are stable against the condensation of their major constituents, out of the gas phase, on their permanent nightside hemispheres. We find that super-Earth atmospheres that are nitrogen-dominated (Earth-like) occupy a smaller region of allowed parameter space, compared to hydrogen-dominated atmospheres, because of the dual effects of diminished advection and enhanced radiative cooling. Furthermore, some super-Earths which reside within the habitable zones of M stars may not possess stable atmospheres, depending on the mean molecular weight and infrared photospheric pressure of their atmospheres. We apply our stability diagrams to GJ 436b and GJ 1214b, and demonstrate that atmospheric compositions with high mean molecular weights are disfavored if these exoplanets possess solid surfaces and shallow atmospheres. Finally, we construct stability diagrams tailored to the Kepler data set, for G and K stars, and predict that about half of the exoplanet candidates are expected to harbor stable atmospheres if Earth-like conditions are assumed. We include 55 Cancri e and CoRoT-7b in our stability diagram for G stars.

  18. Characterization of trace element emissions from a pilot-scale coal combustion unit

    SciTech Connect (OSTI)

    Hargis, R.A.; Pennline, H.W. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center

    1996-12-31T23:59:59.000Z

    The flue gas cleanup projects in the in-house research program at the Pittsburgh Energy Technology Center range from laboratory-scale work to testing with the combustion products of coal at a scale equivalent to about 0.75 MW of electric power generation. The largest unit is a 500-pound-per-hour coal combustor, complete with ductwork, spray dryer, baghouse, and ancillary equipment. Over the past year, tests to investigate the distribution and fate of trace elements have been conducted with this pilot unit. These investigations are an integral component of the Air Toxics and Fine Particulate Control subprogrammatic area of the AR and ET Power Systems Program. The overall effort of this area focuses on the improvement of existing technologies and the development of new technologies for the control of hazardous air pollutants and fine particulates associated with coal combustion. A major endeavor within the subprogram is the characterization of trace elements in flue gas from coal combustion, including a special emphasis on mercury speciation. The study described in this paper examined the results from an investigation on the pilot unit; the distribution of trace elements in the ash streams and flue gas stream, material recoveries for the system, baghouse removal efficiencies, and enrichment of ash particulate. Also, a preliminary comparison between the results from the pilot unit and a full-scale utility that burned coal from the same coal batch is provided.

  19. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

    1988-01-01T23:59:59.000Z

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

  20. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, R.L.; Cannon, T.W.

    1988-10-25T23:59:59.000Z

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

  1. Atmospheric Science: An introductory survey 1. Introduction to the atmosphere

    E-Print Network [OSTI]

    Folkins, Ian

    Sound Convergence Zone #12;Terrain effects #12;Von Karman vortex streets #12;Atmosphere in Earth system

  2. Greenhouse Gas Reductions: SF6

    ScienceCinema (OSTI)

    Anderson, Diana

    2013-04-19T23:59:59.000Z

    Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas ? one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6 emissions. Argonne saves over 16,000 tons of SF6 from being emitted into the atmosphere each year, and by recycling the gas rather than purchasing it new, we save taxpayers over $208,000 each year.

  3. Greenhouse Gas Reductions: SF6

    SciTech Connect (OSTI)

    Anderson, Diana

    2012-01-01T23:59:59.000Z

    Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas — one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6 emissions. Argonne saves over 16,000 tons of SF6 from being emitted into the atmosphere each year, and by recycling the gas rather than purchasing it new, we save taxpayers over $208,000 each year.

  4. Large area atmospheric-pressure plasma jet

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM); Henins, Ivars (Los Alamos, NM); Babayan, Steve E. (Huntington Beach, CA); Hicks, Robert F. (Los Angeles, CA)

    2001-01-01T23:59:59.000Z

    Large area atmospheric-pressure plasma jet. A plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two planar, parallel electrodes are employed to generate a plasma in the volume therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly spacing the rf-powered electrode. Because of the atmospheric pressure operation, there is a negligible density of ions surviving for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike the situation for low-pressure plasma sources and conventional plasma processing methods.

  5. System and method for cooling a combustion gas charge

    DOE Patents [OSTI]

    Massey, Mary Cecelia; Boberg, Thomas Earl

    2010-05-25T23:59:59.000Z

    The present invention relates to a system and method for cooling a combustion gas charge prior. The combustion gas charge may include compressed intake air, exhaust gas, or a mixture thereof. An evaporator is provided that may then receive a relatively high temperature combustion gas charge and discharge at a relatively lower temperature. The evaporator may be configured to operate with refrigeration cycle components and/or to receive a fluid below atmospheric pressure as the phase-change cooling medium.

  6. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. (Los Alamos National Lab., NM (United States)); Tie, X. (Scripps Institution of Oceanography, San Diego, CA (United States))

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth's radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  7. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. [Los Alamos National Lab., NM (United States); Tie, X. [Scripps Institution of Oceanography, San Diego, CA (United States)

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth`s radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  8. HARMONIZATION OF PRACTICES FOR ATMOSPHERIC DISPERSION MODELLING WITHIN THE FRAMEWORK OF RISK ASSESSMENT

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to compute hazardous consequences of dangerous phenomena such as fire, explosion or atmospheric gas in France On September 21, 2001, a huge explosion occurred in Toulouse (at the AZF factory) causing 31

  9. Trace fossil assemblages in selected shelf sandstones

    E-Print Network [OSTI]

    Locke, Kathleen Ann

    1983-01-01T23:59:59.000Z

    and decreasing marine 1nfluence. Individual trace fossil types are more abundant and show a greater d1versity 1n the delta-margin facies; several large, vert1cal crab(?) burrows are P ascot a d th bi g is do 1 t d by ~Ohio o h In the shelf sequences, mostly... ~Zoo h os, f d ly i th iddl -to. outer and outer shelf sequences. Continued study of trace fossils should provide more specific information than the general shelf locations described above. ACKNOWLEDGEMENTS The completion of this thesis marks...

  10. Trace element analysis of Texas lignite 

    E-Print Network [OSTI]

    Mahar, Sean

    1982-01-01T23:59:59.000Z

    . Gluskoter, and N. F. Shimp: Occurence and Distribution of Potentiall Volatile Trace Elements in Coal. Illinois State Geological Survey. Urbana, IL. (July, 1974). 39 [26] Andren, A. W. , D. H. Klein, and Y. Talmi: Selenium in Coal- Fired Plant Emissions.... Envir. Sci. and Tech. , 9:856, (Sept. , 1975). [27] Gluskoter, H. J. , R. R. Ruch, W. G. Miller, R. A. Cahill, G. B. Breher and J, K. Kuhn: Trace Elements in Coal: Occur- rence and Distribution. Illinois State Geological Sur- vey. Urbane, Illinois...

  11. Gas power, its promises and problems

    SciTech Connect (OSTI)

    Seay, J.G.

    1980-02-01T23:59:59.000Z

    In spite of the recent decline in natural gas supply, it is still the dominant domestic source of energy supply and the most widely used fuel in the industrial, commercial, and household sectors. The basic problem of the gas industry is that of finding new supplies cost-competitive with other fuels in order to maintain the delivery of adequate gaseous energy to its customers, utilizing the existing and literally irreplaceable underground transmission and distribution system. The decline in gas supplies is traced to regulation of the field price of natural gas at a level too low to insure continuing additions to reserves at a rate sufficient to balance production. As a result, the US is drawing down its inventory of gas supply. The higher prices for gas in the field established by the Natural Gas Policy Act of 1978 provides additional economic incentives for exploration and development of new natural gas, and it is hoped that the higher prices will elicit new supplies. The US has available a large resource base of gas yet to be discovered, natural gas in unconventional sources, and the potential of additional incremental supplies from gasification of coal, the largest remaining fossil fuel resource.

  12. Assessment of hot gas contaminant control

    SciTech Connect (OSTI)

    Rutkowski, M.D.; Klett, M.G.; Zaharchuk, R.

    1996-12-31T23:59:59.000Z

    The objective of this work is to gather data and information to assist DOE in responding to the NRC recommendation on hot gas cleanup by performing a comprehensive assessment of hot gas cleanup systems for advanced coal-based Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) including the status of development of the components of the hot gas cleanup systems, and the probable cost and performance impacts. The scope and time frame of information gathering is generally responsive to the boundaries set by the National Research council (NRC), but includes a broad range of interests and programs which cover hot gas cleanup through the year 2010. As the status of hot gas cleanup is continually changing, additional current data and information are being obtained for this effort from this 1996 METC Contractors` Review Meeting as well as from the 1996 Pittsburgh Coal Conference, and the University of Karlsruhe Symposium. The technical approach to completing this work consists of: (1) Determination of the status of hot gas cleanup technologies-- particulate collection systems, hot gas desulfurization systems, and trace contaminant removal systems; (2) Determination of hot gas cleanup systems cost and performance sensitivities. Analysis of conceptual IGCC and PFBC plant designs with hot gas cleanup have been performed. The impact of variations in hot gas cleanup technologies on cost and performance was evaluated using parametric analysis of the baseline plant designs and performance sensitivity.

  13. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect (OSTI)

    Michael L. Swanson; Grant E. Dunham; Mark A. Musich

    2007-02-01T23:59:59.000Z

    Three potential additives for controlling mercury emissions from syngas at temperatures ranging from 350 to 500 F (177 to 260 C) were developed. Current efforts are being directed at increasing the effective working temperature for these sorbents and also being able to either eliminate any potential mercury desorption or trying to engineer a trace metal removal system that can utilize the observed desorption process to repeatedly regenerate the same sorbent monolith for extended use. Project results also indicate that one of these same sorbents can also successfully be utilized for arsenic removal. Capture of the hydrogen selenide in the passivated tubing at elevated temperatures has resulted in limited results on the effective control of hydrogen selenide with these current sorbents, although lower-temperature results are promising. Preliminary economic analysis suggests that these Corning monoliths potentially could be more cost-effective than the conventional cold-gas (presulfided activated carbon beds) technology currently being utilized. Recent Hg-loading results might suggest that the annualized costs might be as high as 2.5 times the cost of the conventional technology. However, this annualized cost does not take into account the significantly improved thermal efficiency of any plant utilizing the warm-gas monolith technology currently being developed.

  14. Improving UK greenhouse gas emission estimates using tall tower observations 

    E-Print Network [OSTI]

    Howie, James Edward

    2014-06-30T23:59:59.000Z

    Greenhouse gases in the Earth’s atmosphere play an important role in regulating surface temperatures. The UK is signatory to international agreements that legally commit the UK to reduce its greenhouse gas emissions, and ...

  15. Influence of dissociative recombination on the LTE of argon high-frequency plasmas at atmospheric pressure

    E-Print Network [OSTI]

    Boyer, Edmond

    at atmospheric pressure A. Sáinz1 , J. Margot2 , M. C. García1 , M. D. Calzada1 1 Grupo de Espectroscopía de influencing its analytical performances are the electron density (ne) and temperature (Te), as well as the gas+ ) are also expected to play an important role in the discharge kinetics. At atmospheric pressure

  16. Trace metals in sediments of coastal Siberia 

    E-Print Network [OSTI]

    Esnough, Teresa Elizabeth

    1996-01-01T23:59:59.000Z

    For the work described in this thesis, a total of 218 samples from 104 cores from the East Siberian, Laptev, Kara, and Pechora Seas and the Ob and Yenisei Rivers were analyzed for the trace metals Ag, As, Ba, Cd, Cr, Cu, Fe, Hg, Ni, Pb, Sb, and Zn...

  17. Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs) in snow and ice sampled at Colle designed, built and tested. Melt water from inner part of ice core section was pumped to an ICP-SFMS and ICP-OES. Melt water from outer section was on-line extracted by solid-phase cartridges for semi

  18. Background Concentrations of Trace Metals in

    E-Print Network [OSTI]

    Ma, Lena

    of Florida State University System of Florida FLORIDA CENTER FOR SOLID AND HAZARDOUS WASTE MANAGEMENT 2207 NW for evaluating land application of non-hazardous waste materials and monitoring the mobility of trace metals from 8,000 archived samples. l To validate the sampling protocol used by the Florida Cooperative Soil

  19. Trace metals in sediments of coastal Siberia

    E-Print Network [OSTI]

    Esnough, Teresa Elizabeth

    1996-01-01T23:59:59.000Z

    For the work described in this thesis, a total of 218 samples from 104 cores from the East Siberian, Laptev, Kara, and Pechora Seas and the Ob and Yenisei Rivers were analyzed for the trace metals Ag, As, Ba, Cd, Cr, Cu, Fe, Hg, Ni, Pb, Sb, and Zn...

  20. Dynamics of Atmospheres

    E-Print Network [OSTI]

    Read, Peter L.

    transfer ­ Solar heating of surface, and atmosphere via dust absorption ­ Infrared CO2 band cooling (especially around 667 cm-1) ­ nonLTE near-infrared heating of CO2 and nonLTE cooling effects above ~60-80 km. Baroclinic waves, scales, heat and momentum transport, seasonal occurrence. Qualitative treatment

  1. Laboratory for Atmospheric and

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    . Along with this growth came a new building on campus and a new name: the Laboratory for Atmospheric of the Sun to the outermost fringes of the solar system. With LASP's continuing operations role in the planet traditional and stable approach based on federal agency funding of research grant

  2. Are the TRACE-P measurements representative of the western Pacific during March 2001?

    E-Print Network [OSTI]

    2004-01-01T23:59:59.000Z

    TRACE-P measurements representative of the western PacificTHE TRACE- P MEASUREMENTS REPRESENTATIVE? Pierce, R. B. , etTRACE-P measurements representative of the western Pacific

  3. 12.479 Trace-Element Geochemistry, Fall 2006

    E-Print Network [OSTI]

    Frey, Frederick August

    Focuses on element distribution in rocks and minerals using data obtained from natural and experimental systems. Emphasizes models describing trace-element partitioning and applications of trace-element geochemistry to ...

  4. 12.479 Trace-Element Geochemistry, Spring 2009

    E-Print Network [OSTI]

    Frey, Frederick

    The emphasis of this course is to use Trace Element Geochemistry to understand the origin and evolution of igneous rocks. The approach is to discuss the parameters that control partitioning of trace elements between phases ...

  5. A graphics architecture for ray tracing and photon mapping 

    E-Print Network [OSTI]

    Ling, Junyi

    2005-11-01T23:59:59.000Z

    and spatial locality, as well as eliminating unnecessary random memory accesses. A high level abstraction of the combined ray tracing and photon mapping streaming pipeline is introduced. Based on this abstraction, an e?cient ray tracing and photon...

  6. Steam Tracing...New Technologies for the 21st Century

    E-Print Network [OSTI]

    Pitzer, R. K.; Barth, R. E.; Bonorden, C.

    For decades, steam tracing has been an accepted practice in the heating of piping, vessels, and equipment. This paper presents recent product innovations such as "burn-safe" and "energy efficient" steam tracing products. For the many applications...

  7. Ambient methods and apparatus for rapid laser trace constituent analysis

    DOE Patents [OSTI]

    Snyder, Stuart C. (Idaho Falls, ID); Partin, Judy K. (Idaho Falls, ID); Grandy, Jon D. (Idaho Falls, ID); Jeffery, Charles L. (Blackfoot, ID)

    2002-01-01T23:59:59.000Z

    A method and apparatus are disclosed for measuring trace amounts of constituents in samples by using laser induced breakdown spectroscopy and laser induced fluorescence under ambient conditions. The laser induced fluorescence is performed at a selected wavelength corresponding to an absorption state of a selected trace constituent. The intensity value of the emission decay signal which is generated by the trace constituent is compared to calibrated emission intensity decay values to determine the amount of trace constituent present.

  8. Active Moss Biomonitoring of Atmospheric Trace Element Deposition in Belgrade Urban Area using ENAA and AAS

    SciTech Connect (OSTI)

    Anicic, M.; Tasic, M.; Tomasevic, M.; Rajsic, S. [Institute of Physics, Pregrevica 118, 11080 Belgrade (Serbia and Montenegro); Frontasyeva, M. V.; Strelkova, L. P. [Joint Institute for Nuclear Research, Joliot Curie 6, 141980 Dubna (Russian Federation); Steinnes, E. [Department of Chemistry, Norwegian University of Science and Technology, NO-7491 Trondheim (Norway)

    2007-11-26T23:59:59.000Z

    Active biomonitoring of air quality in Belgrade, Serbia, was performed using the moss Sphagnum girgensohnii. Moss bags were exposed in parallel with and without irrigation respectively for four consecutive 3-month periods at three urban sites. Twenty-nine elements were determined in the exposed moss samples by ENAA and three (Cu, Cd, and Pb) by AAS. The relative accumulation factor (RAF) was greater than 1 for the majority of elements. Elements such as Cl, K, Rb and Cs, however, leached from the moss tissue during the exposure time. For all exposure periods, higher uptake in the irrigated moss bags was evident for Al, Cr, Fe, Cu, Zn, Sr, Pb, and Cd.

  9. Sources and fluxes of atmospheric trace elements to the Gulf of Aqaba, Ying Chen,1

    E-Print Network [OSTI]

    Paytan, Adina

    of these elements [Bruland, 1983; Patterson and Settle, 1987]. Several elements that show surface depletion also-like uptake in the upper ocean thus the surface enrichment is not marked [e.g., Fe and Cd, Bruland, 1983 al., 1990] and Zn [Bruland, 1989] are also considered elements that may limit primary productivity

  10. SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics

    E-Print Network [OSTI]

    Russell, Lynn

    SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics Course Syllabus and Lecture Schedule Instructor: Lynn Russell, 343 NH, 534-4852, lmrussell@ucsd.edu Text: Thermodynamics of Atmospheres of Thermodynamics (Work, Heat, First Law, Second Law, Heat Capacity, Adiabatic Processes) 5-Oct F Hurricane Example

  11. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R.K.; Im, K.H.

    1996-04-02T23:59:59.000Z

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

  12. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R. K. (6440 Hillcrest Dr., Burr Ridge, IL 60521); Im, K. H. (925 Lehigh Cir., Naperville, IL 60565)

    1996-01-01T23:59:59.000Z

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

  13. High precision measurements of atmospheric concentrations and plant exchange rates of carbonyl

    E-Print Network [OSTI]

    Yakir, Dan

    High precision measurements of atmospheric concentrations and plant exchange rates of carbonyl K I R * *Environmental Sciences and Energy Research, The Weizmann Institute of Science, Rehovot. The results were consistent with those of nononline gas chromatography­mass spectrometry for COS and IR gas

  14. Methods developed for detecting hazardous elements in produced gas

    SciTech Connect (OSTI)

    Chao, S.; Attari, A. (Inst. of Gas Technology, Des Plaines, IL (United States))

    1995-01-16T23:59:59.000Z

    The Institute of Gas Technology, Des Plaines, Ill. has been developing sampling and analytical methods to detect in natural gas various trace constituents that may pose health, safety, or operational risks. The constituents of interest include paraffinic and aromatic hydrocarbons, H[sub 2]S, organic sulfur compounds, arsenic, mercury, radon, and others. Better sampling and analytical techniques for produced natural gas, similar to those developed by IGT for processed gas, will enhance producers and processors' abilities to monitor undesirable constituents in raw gas streams and improve their clean-up processes. The methods developed at IGT were modifications of air sampling and analytical methods that are commonly used for air toxic substances. These monitoring methods, when applied to natural gas, present special challenges because gas has a much more complex matrix than the air. Methods for the analysis of the following are discussed: arsenic, mercury, radon, sulfur compounds, hydrocarbons, and aromatics including BTEX and PAHs.

  15. Long term performance of boilers using landfill gas

    SciTech Connect (OSTI)

    Gulledge, J.; Cosulich, J.; Ahmed, S.L.

    1996-11-01T23:59:59.000Z

    The US EPA estimates that approximately 600 to 700 landfills produce sufficient gas for profitable energy production in the United States. The gas from these landfills could provide enough electricity for about 3 million homes. Yet, there are only about 120 operating landfill gas to energy facilities. A lack of information on successful projects may cause part of this shortfall. This paper provides information on 4 successful projects using landfill gas fired boilers, some of which have operated over a decade. Natural gas fired boilers can be easily converted to bum landfill gas. Several modifications to Districts` boilers, described in this paper, have resulted in many years of safe and corrosion free operation. Most of the modifications are minor. Conversion can be accomplished for under $100,000 in many cases. Information on the reliability and longevity of landfill gas supplies is also provided. Gas from a given landfill is generally available over 99.5% of the time with about 5 brief flow interruptions annually. Actual data from 3 landfills document the high availability of landfill gas. To show the longevity of landfill gas flows, data from the Palos Verdes Landfill are provided. The Palos Verdes Landfill closed in 1980. The Palos Verdes. Landfill Gas to Energy Facility is currently producing over 8 megawatts. Landfill gas pretreatment is not required for boilers. In cases where the landfill gas is being piped offsite, it is usually cost effective to dehydrate the landfill gas. Landfill gas bums cleaner than natural gas. NO{sub x} emissions from landfill gas fired boilers are lower because of the carbon dioxide in the landfill gas. Trace organic destruction efficiency is usually over 99% in landfill gas fired boilers. In addition, flare emissions are eliminated when landfill gas is used to displace fossil fuels in boilers.

  16. Pluto's Atmosphere Does Not Collapse

    E-Print Network [OSTI]

    Olkin, C B; Borncamp, D; Pickles, A; Sicardy, B; Assafin, M; Bianco, F B; Buie, M W; de Oliveira, A Dias; Gillon, M; French, R G; Gomes, A Ramos; Jehin, E; Morales, N; Opitom, C; Ortiz, J L; Maury, A; Norbury, M; Ribas, F B; Smith, R; Wasserman, L H; Young, E F; Zacharias, M; Zacharias, N

    2013-01-01T23:59:59.000Z

    Combining stellar occultation observations probing Pluto's atmosphere from 1988 to 2013 and models of energy balance between Pluto's surface and atmosphere, we conclude that Pluto's atmosphere does not collapse at any point in its 248-year orbit. The occultation results show an increasing atmospheric pressure with time in the current epoch, a trend present only in models with a high thermal inertia and a permanent N2 ice cap at Pluto's north rotational pole.

  17. THE EFFECTS OF SNOWLINES ON C/O IN PLANETARY ATMOSPHERES

    SciTech Connect (OSTI)

    Oeberg, Karin I.; Murray-Clay, Ruth [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Bergin, Edwin A., E-mail: koberg@cfa.harvard.edu [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States)

    2011-12-10T23:59:59.000Z

    The C/O ratio is predicted to regulate the atmospheric chemistry in hot Jupiters. Recent observations suggest that some exoplanets, e.g., Wasp 12-b, have atmospheric C/O ratios substantially different from the solar value of 0.54. In this Letter, we present a mechanism that can produce such atmospheric deviations from the stellar C/O ratio. In protoplanetary disks, different snowlines of oxygen- and carbon-rich ices, especially water and carbon monoxide, will result in systematic variations in the C/O ratio both in the gas and in the condensed phases. In particular, between the H{sub 2}O and CO snowlines most oxygen is present in icy grains-the building blocks of planetary cores in the core accretion model-while most carbon remains in the gas phase. This region is coincidental with the giant-planet-forming zone for a range of observed protoplanetary disks. Based on standard core accretion models of planet formation, gas giants that sweep up most of their atmospheres from disk gas outside of the water snowline will have a C/O {approx} 1, while atmospheres significantly contaminated by evaporating planetesimals will have a stellar or substellar C/O when formed at the same disk radius. The overall metallicity will also depend on the atmosphere formation mechanism, and exoplanetary atmospheric compositions may therefore provide constraints on where and how a specific planet formed.

  18. Trace anomaly of the conformal gauge field

    E-Print Network [OSTI]

    Sladkowski, J

    1993-01-01T23:59:59.000Z

    The proposed by Bastianelli and van Nieuwenhuizen new method of calculations of trace anomalies is applied in the conformal gauge field case. The result is then reproduced by the heat equation method. An error in previous calculation is corrected. It is pointed out that the introducing gauge symmetries into a given system by a field-enlarging transformation can result in unexpected quantum effects even for trivial configurations.

  19. Substrate-Free Gas-Phase Synthesis of Graphene Sheets

    E-Print Network [OSTI]

    Frenklach, Michael

    Substrate-Free Gas-Phase Synthesis of Graphene Sheets Albert Dato,*, Velimir Radmilovic, Zonghoon graphene sheets in the gas phase using a substrate-free, atmospheric-pressure microwave plasma reactor. Graphene sheets were synthesized by passing liquid ethanol droplets into an argon plasma. The graphene

  20. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Trace elements and alkaliTrace elements and alkali

    E-Print Network [OSTI]

    Zevenhoven, Ron

    elements in fossil - and waste-derived fuelsTrace elements in fossil - and waste-derived fuels Coal Peat Heavy fuel oil Pet coke MSW RDF Wood Waste wood Waste paper Scrap tyres Sew. sludge Hg 0.02-3 ~0.07 .153 Behaviour of trace elements in coalBehaviour of trace elements in coal combustion flue gasescombustion flue

  1. The electrodeless discharge at atmospheric pressure

    SciTech Connect (OSTI)

    Laroussi, M.

    1999-07-01T23:59:59.000Z

    Recently the generation and applications of atmospheric pressure plasmas received increased interest in the plasma research community. Applications such as the surface modification of materials, and the decontamination of matter have been under investigation. In this context, the authors introduce a new means of generating an atmospheric pressure discharge, which is suitable for use in the above-mentioned applications, and in the treatment of undesirable or polluting gases, such as VOC's. This device is a capacitively coupled discharge. It is basically made of a non-conducting tube with two independent loops of wire wrapped around it, and separated by a distance d. A stable discharge is generated inside the tube when an AC voltage of few hundred volts to few kilovolts, at a frequency of few kilohertz, is applied between the loops. One end of the tube is completely open to the outside air, and a seed gas (generally a noble gas such as Helium) is introduced in the tube. The plasma generated with this method is weakly ionized, cold, and is maintained by a relatively low input power (few tens of watts, depending on the size of the tube). In this paper, the discharge electrical characteristics, its radiation emission characteristics, and the measurement of relevant plasma parameters will be presented.

  2. Trace element distribution and mercury speciation in a pilot-scale coal combustor burning Blacksville coal

    SciTech Connect (OSTI)

    Hargis, R.A.; Pennline, H.W. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technical Center

    1997-12-31T23:59:59.000Z

    A series of tests have been conducted on a nominal 500-pound-per-hour, pilot-scale combustion unit to characterize trace element emissions and mercury speciation. The coal fired during the testing was a Blacksville {number_sign}2, medium-sulfur coal, similar to that used by other researchers investigating mercury speciation. A description of the pilot unit operating conditions during the testing is provided. A summary of the gas/solid distribution of trace elements at various locations within the system, material balances, and baghouse removal efficiencies is also supplied. EPA Method 29 was used to determine trace element and speciated mercury concentrations before and after the baghouse. A comparison of these results with past trace element results from this unit and with the findings of other researchers who have used Blacksville coal is also presented. The pilot-scale combustion unit has been characterized in terms of trace element distribution during two tests while burning a medium-sulfur bituminous Blacksville coal. EPA sampling methodology at the inlet to the baghouse and at the stack was used. Results indicate that most of the elements are removed across the baghouse with the exception of mercury and selenium. Both of these elements were found predominantly in the vapor phase. The average mercury speciation revealed that the vapor-phase mercury was primarily in the oxidized form, which is consistent with the findings of other research with Blacksville coal. Material recoveries for most of the elements were very good. The average recovery for mercury further validates that this pilot unit will be a viable system for mercury sampling and control methods.

  3. Trace Analytical Techniques for Nuclear Forensics

    SciTech Connect (OSTI)

    Halverson, J.E.

    1999-04-28T23:59:59.000Z

    Over the history of the Savannah River Site, the Savannah River Technology Center (SRTC) has developed high sensitivity analytical capabilities in support of the Site's Environmental Monitoring Program and nuclear material protection process. Many of these techniques are applicable to the developing need for nuclear forensic analysis capabilities. Radiological and critically control procedures are in place at the SRTC, as well as clean room practices, to minimize the potential for a radiological evidentiary sample to contaminate personnel and the facility, as well as to minimize contaminating the sample thus rendering it useless by law enforcement agencies. Some of the trace analytical techniques available at the SRTC include ultra-low-level gamma and alpha spectrometry, high-sensitivity thermal ionization mass spectrometry, time-of-flight secondary ion mass spectrometry and trace organic analyses. These techniques have been tested during a planned domestic smuggling exercise and in the analysis of an unknown sample.In the event of an interdiction involving the illegal use or movement of radioactive material by U.S. law enforcement agencies (local, state or federal) forensic analyses will be used in developing and building a legal case against the perpetrators. The Savannah River Technology Center (SRTC) at the U.S. Department of Energy's Savannah River Site, a former nuclear production site currently conducting nuclear material stabilization missions, located in Aiken South Carolina, has a long history of performing trace analytical analyses for environmental monitoring. Many of these techniques are also applicable to nuclear forensic analyses. A summary of the trace analytical techniques used at the SRTC, which are applicable to Nuclear Forensics, is presented in this paper.Contamination control, of facilities and personnel involved in the analytical analyses, as well as preventing contamination of the sample, is a unique challenge for nuclear forensic analyses. A discussion of sample handling and contamination control procedures is included in this paper. Some of the applicable analytical techniques available at the SRTC for nuclear forensic analyses include: ultra-low-level gamma and alpha spectroscopy, high-sensitivity thermal-ionization mass spectrometry (TIMS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and trace organic analyses. Results from analyses of special nuclear material (SNM) standards, materials from nuclear smuggling exercises, and materials of unknown origin will be presented.

  4. Ionization in atmospheres of Brown Dwarfs and extrasolar planets IV. The Effect of Cosmic Rays

    E-Print Network [OSTI]

    Rimmer, Paul

    2013-01-01T23:59:59.000Z

    Cosmic rays provide an important source for free electrons in the Earth's atmosphere and also in dense interstellar regions where they produce a prevailing background ionization. We utilize a Monte Carlo cosmic ray transport model for particle energies of 1 MeV model for particle energies of 1 GeV model atmospheres of an example brown dwarf with effective temperature Teff = 1500 K, and two example giant gas planets (Teff = 1000 K, 1500 K). For the model brown dwarf atmosphere, the electron fraction is enhanced significantly by cosmic rays when the pressure pgas model atmosphere of the examp...

  5. (Astro)Physics 343 Lecture # 8: Green Bank trip + gas dynamics

    E-Print Network [OSTI]

    Baker, Andrew J.

    matter (i.e., dark matter). #12; A heretical alternative? A few bold souls have pointed out that once/T. #12; Gas dynamics: a Keplerian example From Herrnstein et al. (1999): water masers tracing orbital, based on the central concentration of luminous matter (stars and gas): #12; Rotation curves

  6. (Astro)Physics 343 Lecture # 8: Green Bank trip; gas dynamics

    E-Print Network [OSTI]

    Baker, Andrew J.

    matter (i.e., dark matter). #12; A heretical alternative? A few bold souls have pointed out that once/T. #12; Gas dynamics: a Keplerian example From Herrnstein et al. (1999): water masers tracing orbital, based on the central concentration of luminous matter (stars and gas): #12; Rotation curves

  7. ScalaTrace: Tracing, Analysis and Modeling of HPC Codes at Scale

    SciTech Connect (OSTI)

    Mueller, F; Wu, X; Schulz, M; de Supinski, B; Gamblin, T

    2010-03-31T23:59:59.000Z

    Characterizing the communication behavior of large-scale applications is a difficult and costly task due to code/system complexity and their long execution times. An alternative to running actual codes is to gather their communication traces and then replay them, which facilitates application tuning and future procurements. While past approaches lacked lossless scalable trace collection, we contribute an approach that provides orders of magnitude smaller, if not near constant-size, communication traces regardless of the number of nodes while preserving structural information. We introduce intra- and inter-node compression techniques of MPI events, we develop a scheme to preserve time and causality of communication events, and we present results of our implementation for BlueGene/L. Given this novel capability, we discuss its impact on communication tuning and on trace extrapolation. To the best of our knowledge, such a concise representation of MPI traces in a scalable manner combined with time-preserving deterministic MPI call replay are without any precedence.

  8. Trace water vapor determination in nitrogen and corrosive gases using infrared spectroscopy

    SciTech Connect (OSTI)

    Espinoza, L.H.; Niemczyk, T.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry; Stallard, B.R.; Garcia, M.J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-06-01T23:59:59.000Z

    The generation of particles in gas handling systems as a result of corrosion is a major concern in the microelectronics industry. The corrosion can be caused by the presence of trace quantities of water in corrosive gases such as HCl or HBr. FTIR spectroscopy has been shown to be a method that can be made compatible with corrosive gases and is capable of detecting low ppb levels of water vapor. In this report, the application of FTIR spectroscopy combined with classical least squares multivariate calibration to detect trace H{sub 2}O in N{sub 2}, HCl and HBr is discussed. Chapter 2 discusses the gas handling system and instrumentation required to handle corrosive gases. A method of generating a background spectrum useful to the measurements discussed in this report, as well as in other application areas such as gas phase environmental monitoring, is discussed in Chapter 3. Experimental results obtained with the first system are presented in Chapter 4. Those results made it possible to optimize the design options for the construction of a dedicate system for low ppb water vapor determination. These designs options are discussed in Chapter 5. An FTIR prototype accessory was built. In addition, a commercially available evacuable FTIR system was obtained for evaluation. Test results obtained with both systems are discussed in Chapter 6. Experiments dealing with the interaction between H{sub 2}O-HCl and potential improvements to the detection system are discussed in Chapter 7.

  9. Processing materials inside an atmospheric-pressure radiofrequency nonthermal plasma discharge

    DOE Patents [OSTI]

    Selwyn, Gary S.; Henins, Ivars; Park, Jaeyoung; Herrmann, Hans W.

    2006-04-11T23:59:59.000Z

    Apparatus for the processing of materials involving placing a material either placed between an radio-frequency electrode and a ground electrode, or which is itself one of the electrodes. This is done in atmospheric pressure conditions. The apparatus effectively etches or cleans substrates, such as silicon wafers, or provides cleaning of spools and drums, and uses a gas containing an inert gas and a chemically reactive gas.

  10. Thermophoretic separation of aerosol particles from a sampled gas stream

    SciTech Connect (OSTI)

    Postma, Arlin K. (Halfway, OR)

    1986-01-01T23:59:59.000Z

    A method for separating gaseous samples from a contained atmosphere that includes aerosol particles uses the step of repelling particles from a gas permeable surface or membrane by heating the surface to a temperature greater than that of the surrounding atmosphere. The resulting thermophoretic forces maintain the gas permeable surface clear of aerosol particles. The disclosed apparatus utilizes a downwardly facing heated plate of gas permeable material to combine thermophoretic repulsion and gravity forces to prevent particles of any size from contacting the separating plate surfaces.

  11. Clathrate hydrates as a sink of noble gases in Titan's atmosphere

    E-Print Network [OSTI]

    Thomas, C; Ballenegger, V; Picaud, Sylvain

    2007-01-01T23:59:59.000Z

    We use a statistical thermodynamic approach to determine the composition of clathrate hydrates which may form from a multiple compound gas whose composition is similar to that of Titan's atmosphere. Assuming that noble gases are initially present in this gas phase, we calculate the ratios of xenon, krypton and argon to species trapped in clathrate hydrates. We find that these ratios calculated for xenon and krypton are several orders of magnitude higher than in the coexisting gas at temperature and pressure conditions close to those of Titan's present atmosphere at ground level. Furthermore we show that, by contrast, argon is poorly trapped in these ices. This trapping mechanism implies that the gas-phase is progressively depleted in xenon and krypton when the coexisting clathrate hydrates form whereas the initial abundance of argon remains almost constant. Our results are thus compatible with the deficiency of Titan's atmosphere in xenon and krypton measured by the {\\it Huygens} probe during its descent on J...

  12. MFR PAPER 1191 Effect of Atmospheric Gas Supersaturation

    E-Print Network [OSTI]

    of Columbia River fish are affected by the huge dams built for hydroelectric power, CANADA I --·---------j

  13. atmospheric pressure gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    position and dimensions of flaws that produce AE. Time of Flight Diffraction (TOFD), ultrasonic examination is also commonly used for flaw sizing. 1.5 The values stated...

  14. The investigation of atmospheric humidity control by hot gas reheat

    E-Print Network [OSTI]

    Whitlock, Paul Leroy

    1963-01-01T23:59:59.000Z

    Number 1, 2, and 3 24 10 Psychrometric Chart with the Processes of Runs Number 1, 2, and 3 Superimposed Upon One Another 25 Nossle Performance Curvos 31 vi LIST OF SM30LS ~Sbol OF ~tit Cubic feet per minute Constant pressure specific heat... tempera- ture L2/T2 in. Hg in, H2O MV PD psig sp gr tdb Inches of mercury Inches of water Pounds mass Pounds mass dry air Pounds mass water vapor Millivolt s Pressure diff'erential (in. Hg) Gage pressure Heat added or re...

  15. TCgen 2.0: A Tool to Automatically Generate Lossless Trace Compressors Martin Burtscher

    E-Print Network [OSTI]

    Burtscher, Martin

    TCgen 2.0: A Tool to Automatically Generate Lossless Trace Compressors Martin Burtscher Computer of TCgen, a tool for generating portable lossless trace compressors based on user-provided trace format for translating user-provided trace descriptions into fast and effective trace compressors. A typical trace

  16. Universal Quantification for Self-Organized Criticality in Atmospheric Flows

    E-Print Network [OSTI]

    A. Mary Selvam

    1997-10-09T23:59:59.000Z

    Atmospheric flows exhibit selfsimilar fluctuations on all scales(space-time) ranging from climate(kilometers/years) to turbulence(millimeters/seconds) manifested as fractal geometry to the global cloud cover pattern concomitant with inverse power law form for power spectra of temporal fluctuations. Selfsimilar fluctuations implying long-range correlations are ubiquitous to dynamical systems in nature and are identified as signatures of self-organized criticality in atmospheric flows. Also, mathematical models for simulation and prediction of atmospheric flows are nonlinear and computer realizations give unrealistic solutions because of deterministic chaos, a direct consequence of finite precision round-off error doubling for each iteration of iterative computations incorporated in long-term numerical integration schemes used for model solutions An alternative non-deterministic cell dynamical system model predicts, (a): the observed self organized criticality as a consequence of quantumlike mechanics governing flow dynamics,.(b):atmospheric flows trace an overall logarithmic spiral trajectory with the quasiperiodic Penrose tiling pattern for the internal structure,(c): eddy circulation structure follows Kepler's third law of planetary motion and results in inverse square law form for centripetal acceleration. The inertial masses representing the eddy circulation therefore follow laws analogous to the Newton's inverse square law for gravitation. The model is similar to a superstring model for subatomic dynamics which unifies quantum mechanical and classical concept and incorporates gravitational forces along with nuclear and electromagnetic forces.

  17. Screening the Hanford tanks for trapped gas

    SciTech Connect (OSTI)

    Whitney, P.

    1995-10-01T23:59:59.000Z

    The Hanford Site is home to 177 large, underground nuclear waste storage tanks. Hydrogen gas is generated within the waste in these tanks. This document presents the results of a screening of Hanford`s nuclear waste storage tanks for the presence of gas trapped in the waste. The method used for the screening is to look for an inverse correlation between waste level measurements and ambient atmospheric pressure. If the waste level in a tank decreases with an increase in ambient atmospheric pressure, then the compressibility may be attributed to gas trapped within the waste. In this report, this methodology is not used to estimate the volume of gas trapped in the waste. The waste level measurements used in this study were made primarily to monitor the tanks for leaks and intrusions. Four measurement devices are widely used in these tanks. Three of these measure the level of the waste surface. The remaining device measures from within a well embedded in the waste, thereby monitoring the liquid level even if the liquid level is below a dry waste crust. In the past, a steady rise in waste level has been taken as an indicator of trapped gas. This indicator is not part of the screening calculation described in this report; however, a possible explanation for the rise is given by the mathematical relation between atmospheric pressure and waste level used to support the screening calculation. The screening was applied to data from each measurement device in each tank. If any of these data for a single tank indicated trapped gas, that tank was flagged by this screening process. A total of 58 of the 177 Hanford tanks were flagged as containing trapped gas, including 21 of the 25 tanks currently on the flammable gas watch list.

  18. 1. Introduction to the relative trace formula Give an idea of the relative trace formula along any of the sources [CPS90,

    E-Print Network [OSTI]

    Ould Ahmedou, Mohameden

    1. Introduction to the relative trace formula Give an idea of the relative trace formula along any (91h:11042) [Jac05] Herv´e Jacquet, A guide to the relative trace formula, Automorphic representations2192826 (2006g:11100) [Lap10] Erez M. Lapid, Some applications of the trace formula and the relative trace

  19. Dual liquid and gas chromatograph system

    DOE Patents [OSTI]

    Gay, Don D. (Aiken, SC)

    1985-01-01T23:59:59.000Z

    A chromatographic system that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a non-transparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extremely low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  20. Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics

    E-Print Network [OSTI]

    Gerlich, Gerhard

    2007-01-01T23:59:59.000Z

    The atmospheric greenhouse effect, an idea that authors trace back to the traditional works of Fourier 1824, Tyndall 1861 and Arrhenius 1896 and is still supported in global climatology essentially describes a fictitious mechanism in which a planetary atmosphere acts as a heat pump driven by an environment that is radiatively interacting with but radiatively equilibrated to the atmospheric system. According to the second law of thermodynamics such a planetary machine can never exist. Nevertheless, in almost all texts of global climatology and in a widespread secondary literature it is taken for granted that such mechanism is real and stands on a firm scientific foundation. In this paper the popular conjecture is analyzed and the underlying physical principles are clarified. By showing that (a) there are no common physical laws between the warming phenomenon in glass houses and the fictitious atmospheric greenhouse effects, (b) there are no calculations to determine an average surface temperature of a planet, ...

  1. Effects of atmospheric deposition of energy-related pollutants on water quality: a review and assessment

    SciTech Connect (OSTI)

    Davis, M.J.

    1981-05-01T23:59:59.000Z

    The effects on surface-water quality of atmospheric pollutants that are generated during energy production are reviewed and evaluated. Atmospheric inputs from such sources to the aquatic environment may include trace elements, organic compounds, radionuclides, and acids. Combustion is the largest energy-related source of trace-element emissions to the atmosphere. This report reviews the nature of these emissions from coal-fired power plants and discusses their terrestrial and aquatic effects following deposition. Several simple models for lakes and streams are developed and are applied to assess the potential for adverse effects on surface-water quality of trace-element emissions from coal combustion. The probability of acute impacts on the aquatic environment appears to be low; however, more subtle, chronic effects are possible. The character of acid precipitation is reviewed, with emphasis on aquatic effects, and the nature of existing or potential effects on water quality, aquatic biota, and water supply is considered. The response of the aquatic environment to acid precipitation depends on the type of soils and bedrock in a watershed and the chemical characteristics of the water bodies in question. Methods for identifying regions sensitive to acid inputs are reviewed. The observed impact of acid precipitation ranges from no effects to elimination of fish populations. Coal-fired power plants and various stages of the nuclear fuel cycle release radionuclides to the atmosphere. Radioactive releases to the atmosphere from these sources and the possible aquatic effects of such releases are examined. For the nuclear fuel cycle, the major releases are from reactors and reprocessing. Although aquatic effects of atmospheric releases have not been fully quantified, there seems little reason for concern for man or aquatic biota.

  2. ARM - Atmospheric Heat Budget

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OFMaterialsAnnual Reports27,ListAtmospheric Heat

  3. ARM - Atmospheric Pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OFMaterialsAnnual Reports27,ListAtmospheric

  4. Atmospheric PSF Interpolation

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR SEPARATION BYAbrasion andArticle)Atmospheric

  5. Optical emission spectroscopy of atmospheric pressure microwave plasmas

    SciTech Connect (OSTI)

    Jia Haijun; Fujiwara, Hiroyuki; Kondo, Michio [Research Center for Photovoltaics (RCPVs), National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan); Kuraseko, Hiroshi [Furukawa Electric Co., Ltd., Production Technology Development Center, 6 Yawata-Kaigandori, Chiba 290-8555 (Japan)

    2008-09-01T23:59:59.000Z

    The optical emission behaviors of Ar, He, and Ar+He plasmas generated in air using an atmospheric pressure microwave plasma source have been studied employing optical emission spectroscopy (OES). Emissions from various source gas species and air were observed. The variations in the intensities and intensity ratios of specific emissions as functions of the microwave power and gas flow rate were analyzed to investigate the relationship between the emission behavior and the plasma properties. We find that dependence of the emission behavior on the input microwave power is mainly determined by variations in electron density and electron temperature in the plasmas. On the other hand, under different gas flow rate conditions, changes in the density of the source gas atoms also significantly affect the emissions. Interestingly, when plasma is generated using an Ar+He mixture, emissions from excited He atoms disappear while a strong H{sub {alpha}} signal appears. The physics behind these behaviors is discussed in detail.

  6. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09T23:59:59.000Z

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  7. Pacific Northwest Laboratory annual report for 1980 to the DOE Assistant Secretary for Environment. Part 3. Atmospheric sciences.

    SciTech Connect (OSTI)

    Elderkin, C.E.

    1981-02-01T23:59:59.000Z

    Separate absracts were prepared for the 15 sections of this progress report which is a description of atmospheric research at PNL organized in terms of the following energy technologies: coal, gas and oil; fission and fusion; and oil shale. (KRM)

  8. Noble gas temperature control of metal clusters: A molecular dynamics study

    E-Print Network [OSTI]

    Noble gas temperature control of metal clusters: A molecular dynamics study Jan Westergren a noble gas atmosphere. The simulations are performed using a many-body interaction scheme for the intra-cluster potential, while a pairwise Lennard-Jones potential is used to model the interaction between the noble gas

  9. atmospheres thin atmospheres: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  10. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  11. Images reveal that atmospheric particles can undergo liquid-liquid phase separations

    SciTech Connect (OSTI)

    You, Yuan; Renbaum-Wolff, Lindsay; Carreras-Sospedra, Marc; Hanna, Sarah; Hiranuma, Naruki; Kamal, Saeid; Smith, Mackenzie L.; Zhang, Xiaolu; Weber, Rodney; Shilling, John E.; Dabdub, Donald; Martin, Scot T.; Bertram, Allan K.

    2012-07-30T23:59:59.000Z

    A large fraction of submicron atmospheric particles contains both organic material and inorganic salts. As the relative humidity cycles in the atmosphere, these mixed particles can undergo a range of phase transitions, possibly including liquid-liquid phase separation. If liquid-liquid phase separation occurs, the gas-particle partitioning of atmospheric semi-volatile organic compounds, the scattering and absorption of solar radiation, and the uptake of reactive gas species on atmospheric particles will be affected, with important implications for climate predictions. The actual occurrence of these types of phase transitions within individual atmospheric particles has been considered uncertain, in large part because of the absence of observations for real-world samples. Here, using optical and fluorescence microscopy, we observe the coexistence of two non-crystalline phases in particles generated from real-world samples collected on multiple days in Atlanta, Georgia, and in particles generated in the laboratory using atmospheric conditions. These results reveal that atmospheric particles can undergo liquid-liquid phase separations. Using a box model, we show that liquid-liquid phase separation can result in increased concentrations of gas-phase NO3 and N2O5 in the Atlanta region, due to decreased particle uptake of N2O5.

  12. Atmospheric heat redistribution and collapse on tidally locked rocky planets

    E-Print Network [OSTI]

    Wordsworth, Robin

    2014-01-01T23:59:59.000Z

    Atmospheric collapse is likely to be of fundamental importance to tidally locked rocky exoplanets but remains understudied. Here, general results on the heat transport and stability of tidally locked terrestrial-type atmospheres are reported. First, the problem is modeled with an idealized 3D general circulation model (GCM) with gray gas radiative transfer. It is shown that over a wide range of parameters the atmospheric boundary layer, rather than the large-scale circulation, is the key to understanding the planetary energy balance. Through a scaling analysis of the interhemispheric energy transfer, theoretical expressions for the day-night temperature difference and surface wind speed are created that reproduce the GCM results without tuning. Next, the GCM is used with correlated-k radiative transfer to study heat transport for two real gases (CO2 and CO). For CO2, empirical formulae for the collapse pressure as a function of planetary mass and stellar flux are produced, and critical pressures for atmospher...

  13. Implications of "peak oil" for atmospheric CO2 and climate

    E-Print Network [OSTI]

    Kharecha, P A

    2007-01-01T23:59:59.000Z

    Peaking of global oil production may have a large effect on future atmospheric CO2 amount and climate change, depending upon choices made for subsequent energy sources. We suggest that, if estimates of oil and gas reserves by the Energy Information Administration are realistic, it is feasible to keep atmospheric CO2 from exceeding approximately 450 ppm, provided that future exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration, must be phased out before mid-century to achieve this limit on atmospheric CO2. We also suggest that it is important to "stretch" oil reserves via energy efficiency, thus avoiding the need to extract liquid fuels from coal or unconventional fossil fuels. We argue that a rising price on carbon emissions is probably needed to keep CO2 beneath the 450 ppm ceiling.

  14. Atmospheric-pressure guided streamers for liposomal membrane disruption

    SciTech Connect (OSTI)

    Svarnas, P.; Aleiferis, Sp. [High Voltage Laboratory, Department of Electrical and Computer Engineering, University of Patras, Rion 26504 (Greece); Matrali, S. H. [Pharmaceutical Technology Laboratory, Department of Pharmacy, University of Patras, Rion 26504 (Greece); Gazeli, K. [High Voltage Laboratory, Department of Electrical and Computer Engineering, University of Patras, Rion 26504 (Greece); IPREM-LCABIE, Plasmas et Applications, UPPA, 64000 Pau (France); Clement, F. [IPREM-LCABIE, Plasmas et Applications, UPPA, 64000 Pau (France); Antimisiaris, S. G. [Pharmaceutical Technology Laboratory, Department of Pharmacy, University of Patras, Rion 26504 (Greece); Institute of Chemical Engineering Sciences (ICES)-FORTH, Rion 26504 (Greece)

    2012-12-24T23:59:59.000Z

    The potential to use liposomes (LIPs) as a cellular model in order to study interactions of cold atmospheric-pressure plasma with cells is herein investigated. Cold atmospheric-pressure plasma is formed by a dielectric-barrier discharge reactor. Large multilamellar vesicle liposomes, consisted of phosphatidylcholine and cholesterol, are prepared by the thin film hydration technique, to encapsulate a small hydrophilic dye, i.e., calcein. The plasma-induced release of calcein from liposomes is then used as a measure of liposome membrane integrity and, consequently, interaction between the cold atmospheric plasma and lipid bilayers. Physical mechanisms leading to membrane disruption are suggested, based on the plasma characterization including gas temperature calculation.

  15. ADVANCED HOT GAS FILTER DEVELOPMENT

    SciTech Connect (OSTI)

    Matthew R. June; John L. Hurley; Mark W. Johnson

    1999-04-01T23:59:59.000Z

    Iron aluminide hot gas filters have been developed using powder metallurgy techniques to form seamless cylinders. Three alloys were short-term corrosion tested in simulated IGCC atmospheres with temperatures between 925 F and 1200 F with hydrogen sulfide concentrations ranging from 783 ppm{sub v} to 78,300 ppm{sub v}. Long-term testing was conducted for 1500 hours at 925 F with 78,300 ppm{sub v}. The FAS and FAL alloys were found to be corrosion resistant in the simulated environments. The FAS alloy has been commercialized.

  16. Pulsed atmospheric fluidized bed combustor apparatus and process

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1992-01-01T23:59:59.000Z

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g. organic and medical waste, drying, calcining and the like.

  17. ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC

    E-Print Network [OSTI]

    Moelders, Nicole

    ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC RESEARCH On the parameterization of ice and water substance mixing ratio fields were only strongly altered by turning off the ice phase of these schemes includes ice processes. But in mid- latitudes and also in tropics the ice phase is an important

  18. ATMOSPHERIC ELSEVIER AtmosphericResearch 44 (1997) 231-241

    E-Print Network [OSTI]

    Reading, University of

    ATMOSPHERIC RESEARCH ELSEVIER AtmosphericResearch 44 (1997) 231-241 Error analysis of backscatter;accepted 14 February 1997 Abstract Ice sphere backscatter has been calculated using both Mie theory as a reasonable approximation for rv 1997 Elsevier Science B.V. 1. Introduction Cirrus clouds play

  19. Trace Element Geochemical Zoning in the Roosevelt Hot Springs...

    Open Energy Info (EERE)

    Capuano. 1980. Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah. In: Transactions. GRC Annual Meeting; 09091980; Salt Lake City, UT. Salt...

  20. Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters...

    Open Energy Info (EERE)

    Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters- Lessons Learned From Mammoth Mountain, USA Jump to: navigation, search OpenEI Reference LibraryAdd to...

  1. Monitoring Trace Radionuclides by ICP Mass Spectrometry with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    extensive monitoring programs for trace radionuclides relevant to the observation of illicit nuclear activities. FUNDING SOURCE: United States Department of Energy NA22 FOR MORE...

  2. The Effects of Trace Contaminants on Catalytic Processing of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processing of Biomass-Derived Feedstocks . Abstract: Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to...

  3. Georgia Tech Dangerous Gas

    E-Print Network [OSTI]

    Sherrill, David

    1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

  4. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18T23:59:59.000Z

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  5. Space Science : Atmosphere Greenhouse Effect

    E-Print Network [OSTI]

    Johnson, Robert E.

    Space Science : Atmosphere Greenhouse Effect Part-5a Solar + Earth Spectrum IR Absorbers Grey Atmosphere Greenhouse Effect #12;Radiation: Solar and Earth Surface B"(T) Planck Ideal Emission Integrate at the carbon cycle #12;However, #12;Greenhouse Effect is Complex #12;PLANETARY ENERGY BALANCE G+W fig 3-5

  6. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01T23:59:59.000Z

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR�¢����s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument�¢����s robustness in a real-world situation.

  7. Can the trace formula describe weak localisation?

    E-Print Network [OSTI]

    Robert S. Whitney; Igor V. Lerner; Robert A. Smith

    1999-02-24T23:59:59.000Z

    We attempt to systematically derive perturbative quantum corrections to the Berry diagonal approximation of the two-level correlation function (TLCF) for chaotic systems. To this end, we develop a ``weak diagonal approximation'' based on a recent description of the first weak localisation correction to conductance in terms of the Gutzwiller trace formula. This semiclassical method is tested by using it to derive the weak localisation corrections to the TLCF for a semiclassically disordered system. Unfortunately the method is unable to correctly reproduce the ``Hikami boxes'' (the relatively small regions where classical paths are glued together by quantum processes). This results in the method failing to reproduce the well known weak localisation expansion. It so happens that for the first order correction it merely produces the wrong prefactor. However for the second order correction, it is unable to reproduce certain contributions, and leads to a result which is of a different form to the standard one.

  8. Ch4. Atmosphere and Surface Energy Balances

    E-Print Network [OSTI]

    Pan, Feifei

    ;Energy Pathways #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Atmosphere or performing any work. #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Transmission or water. #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Transmission Atmosphere

  9. GAS INJECTION/WELL STIMULATION PROJECT

    SciTech Connect (OSTI)

    John K. Godwin

    2005-12-01T23:59:59.000Z

    Driver Production proposes to conduct a gas repressurization/well stimulation project on a six well, 80-acre portion of the Dutcher Sand of the East Edna Field, Okmulgee County, Oklahoma. The site has been location of previous successful flue gas injection demonstration but due to changing economic and sales conditions, finds new opportunities to use associated natural gas that is currently being vented to the atmosphere to repressurize the reservoir to produce additional oil. The established infrastructure and known geological conditions should allow quick startup and much lower operating costs than flue gas. Lessons learned from the previous project, the lessons learned form cyclical oil prices and from other operators in the area will be applied. Technology transfer of the lessons learned from both projects could be applied by other small independent operators.

  10. Why Condensing Steam Turbines are More Efficient than Gas Turbines 

    E-Print Network [OSTI]

    Nelson, K. E.

    1988-01-01T23:59:59.000Z

    with gas in a combustion chamber. The gas burns and the hot combustion gases are expanded through a turbine. generating electricity. The gases exit at about 1000oF. slightly above atmospheric pressure. They enter a heat recovery unit. which is a series... statement. however, is relevant to value. GAS TURBINE CYCLE Figure :> shows the enthalpy analysis for a gas turbine cycle employing a heat recovery unit for steam generation. Air enters the compressor where it's boosted to about 190 psi and mixed...

  11. Fixed Space of Positive Trace-Preserving Super-Operators

    E-Print Network [OSTI]

    Ansis Rosmanis

    2011-09-15T23:59:59.000Z

    We examine the fixed space of positive trace-preserving super-operators. We describe a specific structure that this space must have and what the projection onto it must look like. We show how these results, in turn, lead to an alternative proof of the complete characterization of the fixed space of completely positive trace-preserving super-operators.

  12. Accuracy of Memory Reference Traces of Parallel Computations

    E-Print Network [OSTI]

    Holliday, Mark A.

    , the trace-driven simulator uses the intrinsic traces and the sequence of loads and stores before the current cy- cle, to determine the next address. The mapping between load and store sequences and next addresses to issue, sometimes, requires partial program reexecution. Programs that do not require partial

  13. Initial conditions for paraxial ray tracing in inhomogeneous anisotropic media

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    , theoretical seismology, seismic anisotropy, wave propagation 1 Introduction By standard kinematic ray tracing and in numerical modelling and interpretation of high-frequency seismic wave #12;elds propagating in inhomogeneous to such important quantities as geometrical spreading and ray amplitudes. The limitations of kinematic ray tracing

  14. Evaluating impacts of CO2 gas intrusion into a confined sandstone aquifer: Experimental results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31T23:59:59.000Z

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  15. Nitrogen gas emissions from stormwater retention basins during wet weather events in the Phoenix Metropolitan area: an additional ecosystem service?

    E-Print Network [OSTI]

    Hall, Sharon J.

    . We pretreated the basin with a heavy N isotope (15N in NO3 ­ ) to trace the fate of the N added from any process by basin design. Data calculated from gas fluxes in chambers after water, but potentially producing considerable amounts of N2O, a greenhouse gas Incoming data will allow complete

  16. Seasonal cycle of carbon dioxide and its isotopic composition in an urban atmosphere: Anthropogenic and biogenic effects

    E-Print Network [OSTI]

    Ehleringer, Jim

    and summer. The effects of gasoline combustion, natural gas combustion, and biogenic respiration of plants isotopic tracers. The calculations showed large contributions of natural gas combustion in the winter burning, and fossil fuel combustion impart carbon and oxygen isotope signals to the atmosphere that can

  17. Atmos. Chem. Phys., 3, 607621, 2003 www.atmos-chem-phys.org/acp/3/607/ Atmospheric

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    , is formed in the gas-phase reaction OH + NO2 HNO3. (3) Condensable compounds may also be formed and Physics Nonlinear relationships between atmospheric aerosol and its gaseous precursors: Analysis of long (PM) is formation of sulfuric acid by a gas-phase chain mechanism which can be represented

  18. Controlled Microdroplet Transport in an Atmospheric Pressure Microplasma

    E-Print Network [OSTI]

    Maguire, P D; Kelsey, C P; Bingham, A; Montgomery, E P; Bennet, E D; Potts, H E; Rutherford, D; McDowell, D A; Diver, D A; Mariotti, D

    2015-01-01T23:59:59.000Z

    We report the controlled injection of near-isolated micron-sized liquid droplets into a low temperature He-Ne steady-state rf plasma at atmospheric pressure. The H2O droplet stream is constrained within a 2 mm diameter quartz tube. Imaging at the tube exit indicates a log-normal droplet size distribution with an initial count mean diameter of 15 micrometers falling to 13 micrometers with plasma exposure. The radial velocity profile is approximately parabolic indicating near laminar flow conditions with the majority of droplets travelling at >75% of the local gas speed and having a plasma transit time of < 100 microseconds. The maximum gas temperature, determined from nitrogen spectral lines, was below 400 K and the observed droplet size reduction implies additional factors beyond standard evaporation, including charge and surface chemistry effects. The successful demonstration of controlled microdroplet streams opens up possibilities for gas-phase microreactors and remote delivery of active species for pla...

  19. Dynamics of the solar chromosphere. V. High-frequency modulation in ultraviolet image sequences from TRACE

    E-Print Network [OSTI]

    A. G. de Wijn; R. J. Rutten; T. D. Tarbell

    2007-06-13T23:59:59.000Z

    We search for signatures of high-frequency oscillations in the upper solar photosphere and low chromosphere in the context of acoustic heating of outer stellar atmospheres. We use ultraviolet image sequences of a quiet center-disk area from the Transition Region and Coronal Explorer (TRACE) mission which were taken with strict cadence regularity. The latter permits more reliable high-frequency diagnosis than in earlier work. Spatial Fourier power maps, spatially averaged coherence and phase-difference spectra, and spatio-temporal k-f decompositions all contain high-frequency features that at first sight seem of considerable intrinsic interest but actually are more likely to represent artifacts of different nature. Spatially averaged phase difference measurement provides the most sensitive diagnostic and indicates the presence of acoustic modulation up to f=20 mHz (periods down to 50 seconds) in internetwork areas.

  20. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01T23:59:59.000Z

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  1. Experimental study on the emission spectra of microwave plasma at atmospheric pressure

    SciTech Connect (OSTI)

    Zhang, Boya; Wang, Qiang; Zhang, Guixin, E-mail: guixin@mail.tsinghua.edu.cn [Department of Electrical Engineering, Tsinghua University, Beijing 100084 (China); Liao, Shanshan [Department of Electrical Engineering, Tsinghua University, Beijing 100084 (China); Shenzhen Power Supply Co. Ltd., Shenzhen 518000, Guangdong (China)

    2014-01-28T23:59:59.000Z

    An experimental study on microwave plasma at atmospheric pressure was conducted by employing optical emission spectroscopy. Based on a microwave plasma generation device developed for nanoparticle synthesis, we studied the influence of input microwave power and gas flow rate on the optical emission behaviors and electron temperature of plasma using Ar, He, and N{sub 2} as working gas, respectively. The physics behind these behaviors was discussed. The results are useful in characterizing microwave plasma at atmospheric pressure and can be used for improving nanoparticle synthesis system for commercial use in the future.

  2. Gas hydrate research in the Gulf of Mexico: Final report

    SciTech Connect (OSTI)

    Bennet, R.

    1988-05-01T23:59:59.000Z

    The high energy seismic sections on the continental slope showed no evidence of a Bottom Simulating Reflector (BSR), which would indicate the presence of gas hydrates. There was no indication of metastable hydrates in continental shelf or slope sediments outside of the conventionally accepted temperature and pressure environment. Tracing the path of migrating gas from the source is much more straight forward than intercepting gas being transported and tracing it back to the source. Our study of low and medium energy seismic methods has shown that they could identify migrating gas. We feel strongly that there are hydrate zones in the Gulf of Mexico that are decomposing; they build up pressure and periodically release the trapped hydrocarbon gases. The released gases migrate vertically and/or laterally to mix with other types of gas or to form discrete pockets. Some of this gas may be emitted from underwater seeps into the overlying water column where it could be identified by a geochemical survey. The ratio of isobutane to normal butane determined by the geochemical survey can be used to assess the probability of the hydrocarbons emanating from a hydrate source. (The more the ratio exceeds 1.0 the greater the probability that the gas could be from a hydrate source.) As no indications of a hydrate zone (e.g., a BSR) were located, we were not able to establish a geophysical signature for gas hydrates; but the records indicate there are large volumes of gas migrating up the continental slope, some of which may have originated from a decomposing hydrate zone or from gas trapped below the hydrate cap. 20 refs., 13 figs., 1 tab.

  3. Atmos. Chem. Phys., 3, 563579, 2003 www.atmos-chem-phys.org/acp/3/563/ Atmospheric

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Stockholm, Sweden Received: 5 October 2002 ­ Published in Atmos. Chem. Phys. Discuss.: 6 December 2002. Additional measurements were made of gas phase SO2 from one of the vessels in 1999. All samples col- lected properties are needed to trace the nature, loca- tion and strength of the sources as well as to understand

  4. Fragmentation Energetics of Clusters Relevant to Atmospheric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Clusters Relevant to Atmospheric New Particle Formation. Fragmentation Energetics of Clusters Relevant to Atmospheric New Particle Formation. Abstract: The exact mechanisms by...

  5. Pacific Northwest Laboratory annual report for 1984 to the DOE Office of Energy Research. Part 3. Atmospheric sciences

    SciTech Connect (OSTI)

    Elderkin, C.E.

    1985-02-01T23:59:59.000Z

    The goals of atmospheric research at Pacific Northwest Laboratory (PNL) are to assess, describe, and predict the nature and fate of atmospheric contaminants and to study the impacts of contaminants on local, regional, and global climates. The contaminants being investigated are those resulting from the development and use of conventional resources (coal, gas, oil, and nuclear power) as well as alternative energy sources. The description of the research is organized into 3 sections: (1) Atmospheric Studies in Complex Terrain (ASCOT); (2) Boundary Layer Meteorology; and (3) Dispersion, Deposition, and Resuspension of Atmospheric Contaminants. Separate analytics have been done for each of the sections and are indexed and contained in the EDB. (MDF)

  6. Transport impacts on atmosphere and climate: Aviation

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    positive ions in aircraft gas-turbine engine exhaust. Atmos.aerosol precursors from gas turbine engines on the volatilelarge ions in aircraft gas turbine engine combustor exhaust:

  7. Environmental Chemistry II (Atmospheric Chemistry)

    E-Print Network [OSTI]

    Dibble, Theodore

    SYLLABUS FOR Environmental Chemistry II (Atmospheric Chemistry) FCH 511 Fall 2013 Theodore S/explaining the trends in J as a function of altitude and solar zenith angle. The second involves analyzing real

  8. THE MARTIAN ATMOSPHERIC BOUNDARY LAYER

    E-Print Network [OSTI]

    Spiga, Aymeric

    THE MARTIAN ATMOSPHERIC BOUNDARY LAYER A. Petrosyan,1 B. Galperin,2 S. E. Larsen,3 S. R. Lewis,4 A [Haberle et al., 1993a; Larsen et al., 2002; Hinson et al., 2008]. At night, convection is inhibited

  9. Trace Assessment for BWR ATWS Analysis

    SciTech Connect (OSTI)

    Cheng, L.Y.; Diamond, D.; Arantxa Cuadra, Gilad Raitses, Arnold Aronson

    2010-04-22T23:59:59.000Z

    A TRACE/PARCS input model has been developed in order to be able to analyze anticipated transients without scram (ATWS) in a boiling water reactor. The model is based on one developed previously for the Browns Ferry reactor for doing loss-of-coolant accident analysis. This model was updated by adding the control systems needed for ATWS and a core model using PARCS. The control systems were based on models previously developed for the TRAC-B code. The PARCS model is based on information (e.g., exposure and moderator density (void) history distributions) obtained from General Electric Hitachi and cross sections for GE14 fuel obtained from an independent source. The model is able to calculate an ATWS, initiated by the closure of main steam isolation valves, with recirculation pump trip, water level control, injection of borated water from the standby liquid control system and actuation of the automatic depres-surization system. The model is not considered complete and recommendations are made on how it should be improved.

  10. Atmospheric science and power production

    SciTech Connect (OSTI)

    Randerson, D. (ed.)

    1984-07-01T23:59:59.000Z

    This is the third in a series of scientific publications sponsored by the US Atomic Energy Commission and the two later organizations, the US Energy Research and Development Adminstration, and the US Department of Energy. The first book, Meteorology and Atomic Energy, was published in 1955; the second, in 1968. The present volume is designed to update and to expand upon many of the important concepts presented previously. However, the present edition draws heavily on recent contributions made by atmospheric science to the analysis of air quality and on results originating from research conducted and completed in the 1970s. Special emphasis is placed on how atmospheric science can contribute to solving problems relating to the fate of combustion products released into the atmosphere. The framework of this book is built around the concept of air-quality modeling. Fundamentals are addressed first to equip the reader with basic background information and to focus on available meteorological instrumentation and to emphasize the importance of data management procedures. Atmospheric physics and field experiments are described in detail to provide an overview of atmospheric boundary layer processes, of how air flows around obstacles, and of the mechanism of plume rise. Atmospheric chemistry and removal processes are also detailed to provide fundamental knowledge on how gases and particulate matter can be transformed while in the atmosphere and how they can be removed from the atmosphere. The book closes with a review of how air-quality models are being applied to solve a wide variety of problems. Separate analytics have been prepared for each chapter.

  11. Laser Atmospheric Studies with VERITAS

    E-Print Network [OSTI]

    C. M. Hui; for the VERITAS collaboration

    2007-09-25T23:59:59.000Z

    As a calibrated laser pulse propagates through the atmosphere, the amount of Rayleigh-scattered light arriving at the VERITAS telescopes can be calculated precisely. This technique was originally developed for the absolute calibration of ultra-high-energy cosmic-ray fluorescence telescopes but is also applicable to imaging atmospheric Cherenkov telescopes (IACTs). In this paper, we present two nights of laser data taken with the laser at various distances away from the VERITAS telescopes and compare it to Rayleigh scattering simulations.

  12. Trace elements in oil shale. Progress report, 1979-1980

    SciTech Connect (OSTI)

    Chappell, W R

    1980-01-01T23:59:59.000Z

    The purpose of this research program is to understand the potential impact of an oil shale industry on environmental levels of trace contaminants in the region. The program involves a comprehensive study of the sources, release mechanisms, transport, fate, and effects of toxic trace chemicals, principally the trace elements, in an oil shale industry. The overall objective of the program is to evaluate the environmental and health consequences of the release of toxic trace elements by shale and oil production and use. The baseline geochemical survey shows that stable trace elements maps can be constructed for numerous elements and that the trends observed are related to geologic and climatic factors. Shale retorted by above-ground processes tends to be very homogeneous (both in space and in time) in trace element content. Leachate studies show that significant amounts of B, F, and Mo are released from retorted shales and while B and Mo are rapidly flushed out, F is not. On the other hand, As, Se, and most other trace elements are not present in significant quantities. Significant amounts of F and B are also found in leachates of raw shales. Very large concentrations of reduced sulfur species are found in leachates of processed shale. Very high levels of B and Mo are taken up in some plants growing on processed shale with and without soil cover. There is a tendency for some trace elements to associate with specific organic fractions, indicating that organic chelation or complexation may play an important role. Many of the so-called standard methods for analyzing trace elements in oil shale-related materials are inadequate. A sampling manual is being written for the environmental scientist and practicing engineer. A new combination of methods is developed for separating the minerals in oil shale into different density fractions. Microbial investigations have tentatively identified the existence of thiobacilli in oil shale materials such as leachates. (DC)

  13. Redistribution of trace chemical species by a small convective cloud

    SciTech Connect (OSTI)

    Stith, J.L.; Alkezweeny, A.J.; Pleim, J.E.; Ching, J.K.S.

    1993-01-01T23:59:59.000Z

    The paper describes a new experiment with a SF6 tracer to determine the mixing history of a small region of cloud-base air. In situ measurements of the SF6 are made to follow the region and simultaneous measurements of natural trace gases are used to determine the dilution of the tagged region as it is affected by the cloud. After describing the experimental method, the results from an experiment with a small cumulus, which was ideally suited for the experiment, are explained. The goal of the paper is to better understand how convective clouds redistribute trace constituents (e.g. moisture, trace gases) in the vertical.

  14. Algorithms and analysis for underwater vehicle plume tracing.

    SciTech Connect (OSTI)

    Byrne, Raymond Harry; Savage, Elizabeth L. (Texas A& M University, College Station, TX); Hurtado, John Edward (Texas A& M University, College Station, TX); Eskridge, Steven E.

    2003-07-01T23:59:59.000Z

    The goal of this research was to develop and demonstrate cooperative 3-D plume tracing algorithms for miniature autonomous underwater vehicles. Applications for this technology include Lost Asset and Survivor Location Systems (L-SALS) and Ship-in-Port Patrol and Protection (SP3). This research was a joint effort that included Nekton Research, LLC, Sandia National Laboratories, and Texas A&M University. Nekton Research developed the miniature autonomous underwater vehicles while Sandia and Texas A&M developed the 3-D plume tracing algorithms. This report describes the plume tracing algorithm and presents test results from successful underwater testing with pseudo-plume sources.

  15. Gas Storage Act (Illinois)

    Broader source: Energy.gov [DOE]

    Any corporation which is engaged in or desires to engage in, the distribution, transportation or storage of natural gas or manufactured gas, which gas, in whole or in part, is intended for ultimate...

  16. Gas Companies Program (Tennessee)

    Broader source: Energy.gov [DOE]

    The Gas Companies program is a set of rules that encourage the development of the natural gas industry in Tennessee. They empower gas companies to lay piped and extend conductors through the...

  17. Gas Utilities (Maine)

    Broader source: Energy.gov [DOE]

    Rules regarding the production, sale, and transfer of manufactured gas will also apply to natural gas. This section regulates natural gas utilities that serve ten or more customers, more than one...

  18. Gas Utilities (New York)

    Broader source: Energy.gov [DOE]

    This chapter regulates natural gas utilities in the State of New York, and describes standards and procedures for gas meters and accessories, gas quality, line and main extensions, transmission and...

  19. Future of Natural Gas

    Office of Environmental Management (EM)

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts *...

  20. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  1. Supervisory Natural Gas Analyst

    Broader source: Energy.gov [DOE]

    The Department of Energys Office of Fossil Energy, Office of Oil and Natural Gas, Office of Oil and Gas Global Security and Supply (FE) is responsible for regulating natural gas imports and exports...

  2. Tracing spiral density waves in M81

    E-Print Network [OSTI]

    S. Kendall; R. C. Kennicutt; C. Clarke; M. D. Thornley

    2008-04-15T23:59:59.000Z

    We use SPITZER IRAC 3.6 and 4.5micron near infrared data from the Spitzer Infrared Nearby Galaxies Survey (SINGS), optical B, V and I and 2MASS Ks band data to produce mass surface density maps of M81. The IRAC 3.6 and 4.5micron data, whilst dominated by emission from old stellar populations, is corrected for small-scale contamination by young stars and PAH emission. The I band data are used to produce a mass surface density map by a B-V colour-correction, following the method of Bell and de Jong. We fit a bulge and exponential disc to each mass map, and subtract these components to reveal the non-axisymmetric mass surface density. From the residual mass maps we are able to extract the amplitude and phase of the density wave, using azimuthal profiles. The response of the gas is observed via dust emission in the 8micron IRAC band, allowing a comparison between the phase of the stellar density wave and gas shock. The relationship between this angular offset and radius suggests that the spiral structure is reasonably long lived and allows the position of corotation to be determined.

  3. Natural Gas Monthly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    other liquids including biofuels and natural gas liquids. Natural Gas Exploration and reserves, storage, imports and exports, production, prices, sales. Electricity Sales, revenue...

  4. Gas Production Tax (Texas)

    Broader source: Energy.gov [DOE]

    A tax of 7.5 percent of the market value of natural gas produced in the state of Texas is imposed on every producer of gas.

  5. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  6. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07T23:59:59.000Z

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  7. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  8. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  9. Sodium storage facility trace heat system design description

    SciTech Connect (OSTI)

    Jones, D.D.

    1997-06-12T23:59:59.000Z

    This document describes the SSF PLC Ladder Logic, Cross references, and the software that was used to control the amount of power applied to the SSF Trace Heated components.

  10. L-?Functions and Trace Formula Workshop Schedule

    E-Print Network [OSTI]

    2015-05-11T23:59:59.000Z

    L-?Functions and Trace Formula Workshop Schedule. May 11 – May 13, 2015 at Purdue University. Monday, May 11. 9:15 am – 9:30 am: Casselman/Shahidi:.

  11. Inhibition of trace element release during Fe(II)-activatedrecrystall...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    impurities (e.g., Al) which are known to affect the chemical properties of such minerals. Here we explore the effect of Al(III), Cr(III), and Sn(IV) substitution on trace...

  12. TRACES Centre Thermo GFS35 Graphite Furnace Spectrometer

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    TRACES Centre Thermo GFS35 Graphite Furnace Spectrometer Standard Operating Procedure 1. Turn. Click on the lamp icon a. ID the lamp of choice and click the `Off' button to `On' b. Non-Thermo lamps

  13. TRACES Centre Thermo iCE 3500 Flame AA Spectrometer

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    TRACES Centre Thermo iCE 3500 Flame AA Spectrometer Standard Operating Procedure 1. Turn on the lamp icon a. ID the lamp of choice and click the `Off' button to `On' b. Non-Thermo lamps MUST

  14. Application of Reinforcement Learning to Requirements Engineering: Requirements Tracing

    E-Print Network [OSTI]

    Hayes, Jane E.

    of the Software Development Life Cycle (SDLC) can be appreciated by the customers who request and expect delivery the phases of the SDLC, a number of steps can be taken. Requirements tracing ensures that requirements

  15. A Virtuous Cycle: Tracing Democratic Quality through Equality 

    E-Print Network [OSTI]

    Ross, Ashley Dyan

    2011-10-21T23:59:59.000Z

    This dissertation asks the question: How do democracies improve in quality? Building on previous scholarship, the author offers a theoretical framework that traces democratic quality through equality of outcomes. The ...

  16. Ichnotaxonomic assessment of Mazon Creek area trace fossils, Illinois, USA

    E-Print Network [OSTI]

    LoBue, David J.

    2010-08-12T23:59:59.000Z

    The Francis Creek Shale Member (FCSM) of the Mid-Pennsylvanian Carbondale Formation along Mazon Creek in northern Illinois is known for soft-bodied organisms preserved within siderite concretions. Trace fossils, though ...

  17. active trace gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D13, PAGES 16,417-16,421,NOVEMBER 20, 1989 Greenhouse Effect of Chlorofluorocarbons and Other Trace Gases Environmental Sciences and Ecology...

  18. Affine braids, Markov traces and the category O Rosa Orellana

    E-Print Network [OSTI]

    Ram, Arun

    , affine BMW algebras, cyclotomic BMW algebras, Markov traces, Jacobi-Trudi type identities, dual pairs [Ze of affine braid groups of type A, (d) We define the affine BMW algebra (Birman-Murakami-Wenzl) and show

  19. Trace determination of lead by helium-4 activation analysis 

    E-Print Network [OSTI]

    Vargas Bernal, Maria E.

    1984-01-01T23:59:59.000Z

    TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1984 Major Subject: Chemistry TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Approved as to style and format by: Emile A. Schweikert (Chairman of Committee) Marvin W. Rowe (Member) Gerald A. Sc...

  20. Trace determination of lead by helium-4 activation analysis

    E-Print Network [OSTI]

    Vargas Bernal, Maria E.

    1984-01-01T23:59:59.000Z

    TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1984 Major Subject: Chemistry TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Approved as to style and format by: Emile A. Schweikert (Chairman of Committee) Marvin W. Rowe (Member) Gerald A. Sc...

  1. The Fidelity and Trace Norm Distances for Quantifying Coherence

    E-Print Network [OSTI]

    Lian-He Shao; Zhengjun Xi; Heng Fan; Yongming Li

    2014-10-30T23:59:59.000Z

    We investigate the coherence measures induced by fidelity and trace norm, based on the recent proposed coherence quantification in [Phys. Rev. Lett. 113, 140401, 2014]. We show that the fidelity of coherence does not in general satisfy the monotonicity requirement as a measure of coherence under the subselection of measurements condition. We find that the trace norm of coherence can act as a measure of coherence for qubit case and some special class of qutrits.

  2. Investigation of trace amounts of gas on microvave water-cut measurement 

    E-Print Network [OSTI]

    Liu, Jin

    2006-08-16T23:59:59.000Z

    sampling probe or a sampling port on the pipeline. Then, the oil and water are separated using a centrifuge. Finally, the volume of the separated water is measured and the water-cut of the sample is calculated based on the total volume of the liquid... pipeline; 2. The oil/water monitor generates the current or electrical signal transmit to a zero-&- span adjuster; 3. From the zero-&-span adjuster, the data is transmitted from analog to digital at converter and calculator and to a comparator. 4...

  3. Studies with a laboratory atmospheric fluidized bed combustor system

    SciTech Connect (OSTI)

    Orndorff, W.W.; Su, Shi; Napier, J. [Western Kentucky Univ., Bowling Green, KY (United States)] [and others

    1996-12-31T23:59:59.000Z

    Growing public concerns over acid rain and municipal solid waste problems have created interest in the development of atmospheric fluidized bed combustion systems. A computer controlled 12-inch laboratory atmospheric fluidized bed combustor (AFBC) system has been developed at Western Kentucky University. On-line analysis by gas chromatography, Fourier-transform infrared (FTIR) spectrometry, and mass spectrometry (MS) allows extensive analysis of the flux gases. Laboratory experiments with a thermogravimetric analyzer (TGA) interfaced with FTIR and MS systems are used to screen fuel blends for runs in the AFBC system. Current experiments being conducted include co-firing blends of refuse derived fuels with coal and extended burns with coals containing different levels of chlorine.

  4. Effect of furnace atmosphere on E-glass foaming

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Dutton, Bryan C.; Hrma, Pavel R.; Pilon, Laurent

    2006-12-01T23:59:59.000Z

    The effect of furnace atmosphere on E-glass foaming generated in crucible has been studied with a specific goal to understand the impact of increased water content on foaming in oxy-fired furnaces. E-glass foams were generated in a fused-quartz crucible located in a quartz window furnace equipped with video recording. The present study showed that humidity in the furnace atmosphere destabilizes foam, while other gases have little effect on foam stability. This study suggests that the higher foaming in oxy-fired furnace compared to air-fired is caused by the effect of water on early sulfate decomposition, promoting more efficient refining gas generation from sulfate (known as “dilution effect”).

  5. Natural marine seepage blowout: Contribution to atmospheric Ira Leifer,1,2

    E-Print Network [OSTI]

    Luyendyk, Bruce

    . Simulations suggest a 1.1% gas loss to dissolution compared to $10% loss for a typical low-flux bubble plume than carbon dioxide, CO2 [Khalil and Rasmussen, 1995]. Its atmospheric mixing ratio has more than constrained. [4] Seepage emission estimates are mostly based on observations of gentle bubble emanations [e

  6. Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef* and J. M applications (1, 2) . Synthesis gas or syngas (mixture of hydrogen and carbon monoxide) are used as a major. The conventional reformers allowing syngas production are based on steam reforming of hydrocarbons (3) following

  7. Oscillations of solar atmosphere neutrinos

    E-Print Network [OSTI]

    G. L. Fogli; E. Lisi; A. Mirizzi; D. Montanino; P. D. Serpico

    2006-11-10T23:59:59.000Z

    The Sun is a source of high energy neutrinos (E > 10 GeV) produced by cosmic ray interactions in the solar atmosphere. We study the impact of three-flavor oscillations (in vacuum and in matter) on solar atmosphere neutrinos, and calculate their observable fluxes at Earth, as well as their event rates in a kilometer-scale detector in water or ice. We find that peculiar three-flavor oscillation effects in matter, which can occur in the energy range probed by solar atmosphere neutrinos, are significantly suppressed by averaging over the production region and over the neutrino and antineutrino components. In particular, we find that the relation between the neutrino fluxes at the Sun and at the Earth can be approximately expressed in terms of phase-averaged ``vacuum'' oscillations, dominated by a single mixing parameter (the angle theta_23).

  8. Cumulant expansions for atmospheric flows

    E-Print Network [OSTI]

    Ait-Chaalal, Farid; Meyer, Bettina; Marston, J B

    2015-01-01T23:59:59.000Z

    The equations governing atmospheric flows are nonlinear, and consequently the hierarchy of cumulant equations is not closed. But because atmospheric flows are inhomogeneous and anisotropic, the nonlinearity may manifests itself only weakly through interactions of mean fields with disturbances such as thermals or eddies. In such situations, truncations of the hierarchy of cumulant equations hold promise as a closure strategy. We review how truncations at second order can be used to model and elucidate the dynamics of turbulent atmospheric flows. Two examples are considered. First, we study the growth of a dry convective boundary layer, which is heated from below, leading to turbulent upward energy transport and growth of the boundary layer. We demonstrate that a quasilinear truncation of the equations of motion, in which interactions of disturbances among each other are neglected but interactions with mean fields are taken into account, can successfully capture the growth of the convective boundary layer. Seco...

  9. COMPOSITIONAL DIVERSITY IN THE ATMOSPHERES OF HOT NEPTUNES, WITH APPLICATION TO GJ 436b

    SciTech Connect (OSTI)

    Moses, J. I. [Space Science Institute, 4750 Walnut Street, Suite 205, Boulder, CO 80301 (United States); Line, M. R. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States); Visscher, C. [Southwest Research Institute, Boulder, CO 80302 (United States); Richardson, M. R. [Rice University, Houston, TX 77005-1892 (United States); Nettelmann, N.; Fortney, J. J. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Barman, T. S. [Lowell Observatory, Flagstaff, AZ 86001 (United States); Stevenson, K. B. [Department of Astronomy and Astrophysics, University of Chicago, Chicago, IL 60637 (United States); Madhusudhan, N., E-mail: jmoses@spacescience.org [Department of Physics and Department of Astronomy, Yale University, New Haven, CT 06520-8101 (United States)

    2013-11-01T23:59:59.000Z

    Neptune-sized extrasolar planets that orbit relatively close to their host stars—often called {sup h}ot Neptunes{sup —}are common within the known population of exoplanets and planetary candidates. Similar to our own Uranus and Neptune, inefficient accretion of nebular gas is expected produce hot Neptunes whose masses are dominated by elements heavier than hydrogen and helium. At high atmospheric metallicities of 10-10,000 times solar, hot Neptunes will exhibit an interesting continuum of atmospheric compositions, ranging from more Neptune-like, H{sub 2}-dominated atmospheres to more Venus-like, CO{sub 2}-dominated atmospheres. We explore the predicted equilibrium and disequilibrium chemistry of generic hot Neptunes and find that the atmospheric composition varies strongly as a function of temperature and bulk atmospheric properties such as metallicity and the C/O ratio. Relatively exotic H{sub 2}O, CO, CO{sub 2}, and even O{sub 2}-dominated atmospheres are possible for hot Neptunes. We apply our models to the case of GJ 436b, where we find that a CO-rich, CH{sub 4}-poor atmosphere can be a natural consequence of a very high atmospheric metallicity. From comparisons of our results with Spitzer eclipse data for GJ 436b, we conclude that although the spectral fit from the high-metallicity forward models is not quite as good as the best fit obtained from pure retrieval methods, the atmospheric composition predicted by these forward models is more physically and chemically plausible in terms of the relative abundance of major constituents. High-metallicity atmospheres (orders of magnitude in excess of solar) should therefore be considered as a possibility for GJ 436b and other hot Neptunes.

  10. COMPACT QEPAS SENSOR FOR TRACE METHANE AND AMMONIA DETECTION IN IMPURE HYDROGEN

    SciTech Connect (OSTI)

    Wright, J; Ferguson, B; Peters, B; Mcwhorter, S

    2011-11-02T23:59:59.000Z

    A compact two-gas sensor based on quartz enhanced photoacoustic spectroscopy (QEPAS) was developed for trace methane and ammonia quantification in impure hydrogen. The sensor is equipped with a micro-resonator to confine the sound wave and enhance QEPAS signal. The normalized noise-equivalent absorption coefficients (1{sigma}) of 2.45 x 10{sup -8} cm{sup -1}W/{radical}Hz and 9.1 x 10{sup -9} cm{sup -1}W/{radical}Hz for CH{sub 4} detection at 200 Torr and NH{sub 3} detection at 50 Torr were demonstrated with the QEPAS sensor configuration, respectively. The influence of water vapor on the CH{sub 4} channel was also investigated.

  11. Rampant Negativity No Reason to be so Glum Predictably, as scientific evidence clarifies that the dangerous level of atmospheric CO2 is at

    E-Print Network [OSTI]

    Hansen, James E.

    that the dangerous level of atmospheric CO2 is at hand, there are cries that it is impractical to avoid climate that if emissions from coal are phased out linearly between 2020 and 2050 atmospheric CO2 will not exceed ~450 ppm, with the exact peak CO2 depending on the true amount of oil and gas reserves, about which there is some dispute

  12. Naturally fractured tight gas reservoir detection optimization. Quarterly report, January 1, 1997--March 31, 1997

    SciTech Connect (OSTI)

    NONE

    1998-04-01T23:59:59.000Z

    This document contains the quarterly report dated January 1-March 31, 1997 for the Naturally Fractured Tight Gas Reservoir Detection Optimization project. Topics covered in this report include AVOA modeling using paraxial ray tracing, AVOA modeling for gas- and water-filled fractures, 3-D and 3-C processing, and technology transfer material. Several presentations from a Geophysical Applications Workshop workbook, workshop schedule, and list of workshop attendees are also included.

  13. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    fuels (eg diesel, compressed natural gas). Electricity (infossil fuels, such as compressed natural gas and liquefied

  14. High explosives vapor detection by atmospheric sampling glow discharge ionization/tandem mass spectrometry

    SciTech Connect (OSTI)

    McLuckey, S.A.; Goeringer, D.E.; Asano, K.G. [Oak Ridge National Lab., TN (United States). Chemical and Analytical Sciences Div.

    1996-02-01T23:59:59.000Z

    The combination of atmospheric sampling glow discharge ionization with tandem mass spectrometry for the detection of traces of high explosives is described. Particular emphasis is placed on use of the quadrupole ion trap as the type of tandem mass spectrometer. Atmospheric sampling glow discharge provides a simple, rugged, and efficient means for anion formation while the quadrupole ion trap provides for efficient tandem mass spectrometry. Mass selective ion accumulation and non-specific ion activation methods can be used to overcome deleterious effects arising from ion/ion interactions. Such interactions constitute the major potential technical barrier to the use of the ion trap for real-time monitoring of targeted compounds in uncontrolled and highly variable matrices. Tailored waveforms can be used to effect both mass selective ion accumulation and ion activation. Concatenated tailored waveforms allow for both functions in a single experiment thereby providing the capability for monitoring several targeted species simultaneously. The combination of atmospheric sampling glow discharge ionization with a state-of-the-art analytical quadrupole ion trap is a highly sensitive and specific detector for traces of high explosives. The combination is also small and inexpensive relative to virtually any other form of tandem mass spectrometry. The science and technology underlying the glow discharge/ion trap combination is sufficiently mature to form the basis for an engineering effort to make the detector portable. 85 refs.

  15. Heat and Metal Transfer in Gas Metal Arc Welding Using Argon and Helium

    E-Print Network [OSTI]

    Eagar, Thomas W.

    Heat and Metal Transfer in Gas Metal Arc Welding Using Argon and Helium P.G. JONSSON, T.W. EAGAR transfer in gas metal arc welding (GMAW) of mild steel using argon and helium shielding gases. Major dif properties. Various findings from the study include that an arc cannot be stru~k in a pure helium atmosphere

  16. Table A1 Molar mass, gas constant, and critical-point properties

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    of carbon dioxide, CO2 Table A­21 Ideal-gas properties of carbon monoxide, CO Table A­22 Ideal Properties of the atmosphere at high altitude Table A­17 Ideal-gas properties of air Table A­18 Ideal-point properties Molar mass, constant, Temperature, Pressure, Volume, Substance Formula M kg/kmol R kJ/kg·K* K MPa

  17. Compressed gas manifold

    DOE Patents [OSTI]

    Hildebrand, Richard J. (Edgemere, MD); Wozniak, John J. (Columbia, MD)

    2001-01-01T23:59:59.000Z

    A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.

  18. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15T23:59:59.000Z

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  19. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Mottram, Nigel

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  20. The influence of atmospheric pressure on landfill methane emissions

    SciTech Connect (OSTI)

    Czepiel, P.M.; Shorter, J.H.; Mosher, B.; Allwine, E.; McManus, J.B.; Harriss, R.C.; Kolb, C.E.; Lamb, B.K

    2003-07-01T23:59:59.000Z

    Landfills are the largest source of anthropogenic methane (CH{sub 4}) emissions to the atmosphere in the United States. However, few measurements of whole landfill CH{sub 4} emissions have been reported. Here, we present the results of a multi-season study of whole landfill CH{sub 4} emissions using atmospheric tracer methods at the Nashua, New Hampshire Municipal landfill in the northeastern United States. The measurement data include 12 individual emission tests, each test consisting of 5-8 plume measurements. Measured emissions were negatively correlated with surface atmospheric pressure and ranged from 7.3 to 26.5 m{sup 3} CH{sub 4} min{sup -1}. A simple regression model of our results was used to calculate an annual emission rate of 8.4x10{sup 6} m{sup 3} CH{sub 4} year{sup -1}. These data, along with CH{sub 4} oxidation estimates based on emitted landfill gas isotopic characteristics and gas collection data, were used to estimate annual CH{sub 4} generation at this landfill. A reported gas collection rate of 7.1x10{sup 6} m{sup 3} CH{sub 4} year{sup -1} and an estimated annual rate of CH{sub 4} oxidation by cover soils of 1.2x10{sup 6} m{sup 3} CH{sub 4} year{sup -1} resulted in a calculated annual CH{sub 4} generation rate of 16.7x10{sup 6} m{sup 3} CH{sub 4} year{sup -1}. These results underscore the necessity of understanding a landfill's dynamic environment before assessing long-term emissions potential.

  1. Arthur-Selberg trace formula CRM, June 30-July 3, 2009

    E-Print Network [OSTI]

    Lapid, Erez

    #12;#12;Arthur-Selberg trace formula Erez Lapid CRM, June 30-July 3, 2009 #12;Contents Applications of the Selberg Trace Formula 1. Weyl's law #12;Contents Applications of the Selberg Trace Formula 1. Weyl's law 2. Prime Geodesic Theorem #12;Contents Applications of the Selberg Trace Formula 1. Weyl's law 2. Prime

  2. Effect of Sawtooth Activity on Tritium and Beam Deuterium Evolution in Trace Tritium Experiments on JET

    E-Print Network [OSTI]

    Effect of Sawtooth Activity on Tritium and Beam Deuterium Evolution in Trace Tritium Experiments on JET

  3. New Safety and Technical Challenges and Operational Experience on the JET First Trace Tritium Experiment

    E-Print Network [OSTI]

    New Safety and Technical Challenges and Operational Experience on the JET First Trace Tritium Experiment

  4. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect (OSTI)

    Musich, Mark; Swanson, Michael; Dunham, Grant; Stanislowski, Joshua

    2010-10-05T23:59:59.000Z

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-?g/m{sup 3} (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-?g/m{sup 3} (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine and hydrogen selenide sorbents. The noncarbon sorbent was able to reduce the concentration to 0 ppb from a starting concentration of 120 ppb. This compares to the target value of 5 ppb (~17?g/m{sup 3}). The EERC-prepared metal-based pellet and coprecipitate sorbents exhibited arsine reductions of 90% or greater, being below 10 ppb. Corning SR Liquid monoliths exhibited brief periods (<1 hour) of attaining 90% arsine reduction but were able to achieve greater than 80% reduction for several hours. With respect to hydrogen selenide, all Group IB and IIB metal-based sorbents tested exhibited 100% reduction from an inlet concentration of approximately 400 ppb. Corning SR Liquid monoliths exhibited an 82% reduction when two monoliths were tested simultaneously in series.

  5. ADVANCED GASIFICATION MERCURY/TRACE METAL CONTROL WITH MONOLITH TRAPS

    SciTech Connect (OSTI)

    Mark A. Musich; Michael L. Swanson; Grant E. Dunham; Joshua J. Stanislowski

    2010-07-31T23:59:59.000Z

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-?g/m3 (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-?g/m3 (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine and hydrogen selenide sorbents. The noncarbon sorbent was able to reduce the concentration to 0 ppb from a starting concentration of 120 ppb. This compares to the target value of 5 ppb (~17?g/m3). The EERC-prepared metal-based pellet and coprecipitate sorbents exhibited arsine reductions of 90% or greater, being below 10 ppb. Corning SR Liquid monoliths exhibited brief periods (<1 hour) of attaining 90% arsine reduction but were able to achieve greater than 80% reduction for several hours. With respect to hydrogen selenide, all Group IB and IIB metal-based sorbents tested exhibited 100% reduction from an inlet concentration of approximately 400 ppb. Corning SR Liquid monoliths exhibited an 82% reduction when two monoliths were tested simultaneously in series.

  6. No loss fueling station for liquid natural gas vehicles

    SciTech Connect (OSTI)

    Cieslukowski, R.E.

    1992-06-16T23:59:59.000Z

    This patent describes a no loss fueling station for delivery of liquid natural gas (LNG) to a use device such as a motor vehicle. It comprises: a pressure building tank holding a quantity of LNG and gas head; means for delivering LNG to the pressure building tank; means for selectively building the pressure in the pressure building tank; means for selectively reducing the pressure in the pressure building tank; means for controlling the pressure building and pressure reducing means to maintain a desired pressure in the pressure building tank without venting natural gas to the atmosphere; and means for delivering the LNG from the pressure building tank to the use device.

  7. Numerical study on microwave-sustained argon discharge under atmospheric pressure

    SciTech Connect (OSTI)

    Yang, Y.; Hua, W., E-mail: huaw@scu.edu.cn; Guo, S. Y. [School of Electronics and Information Engineering, Sichuan University, Chengdu 610065 (China)] [School of Electronics and Information Engineering, Sichuan University, Chengdu 610065 (China)

    2014-04-15T23:59:59.000Z

    A numerical study on microwave sustained argon discharge under atmospheric pressure is reported in this paper. The purpose of this study is to investigate both the process and effects of the conditions of microwave-excited gas discharge under atmospheric pressure, thereby aiding improvements in the design of the discharge system, setting the appropriate working time, and controlling the operating conditions. A 3D model is presented, which includes the physical processes of electromagnetic wave propagation, electron transport, heavy species transport, gas flow, and heat transfer. The results can be obtained by means of the fluid approximation. The maxima of the electron density and gas temperature are 4.96?×?10{sup 18} m{sup ?3} and 2514.8?K, respectively, and the gas pressure remains almost unchanged for typical operating conditions with a gas flow rate of 20 l/min, microwave power of 1000 W, and initial temperature of 473?K. In addition, the conditions (microwave power, gas flow rate, and initial temperature) of discharge are varied to obtain deeper information about the electron density and gas temperature. The results of our numerical study are valid and clearly describe both the physical process and effects of the conditions of microwave-excited argon discharge.

  8. Natural gas monthly

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the Natural Gas Monthly features articles designed to assist readers in using and interpreting natural gas information.

  9. Thermodynamic analysis of interactions between Ni-based solid oxide fuel cells (SOFC) anodes and trace species in a survey of coal syngas

    SciTech Connect (OSTI)

    Andrew Martinez; Kirk Gerdes; Randall Gemmen; James Postona

    2010-03-20T23:59:59.000Z

    A thermodynamic analysis was conducted to characterize the effects of trace contaminants in syngas derived from coal gasification on solid oxide fuel cell (SOFC) anode material. The effluents from 15 different gasification facilities were considered to assess the impact of fuel composition on anode susceptibility to contamination. For each syngas case, the study considers the magnitude of contaminant exposure resulting from operation of a warm gas cleanup unit at two different temperatures and operation of a nickel-based SOFC at three different temperatures. Contaminant elements arsenic (As), phosphorous (P), and antimony (Sb) are predicted to be present in warm gas cleanup effluent and will interact with the nickel (Ni) components of a SOFC anode. Phosphorous is the trace element found in the largest concentration of the three contaminants and is potentially the most detrimental. Poisoning was found to depend on the composition of the syngas as well as system operating conditions. Results for all trace elements tended to show invariance with cleanup operating temperature, but results were sensitive to syngas bulk composition. Synthesis gas with high steam content tended to resist poisoning.

  10. Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis

    E-Print Network [OSTI]

    Romalis, Mike

    Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis; published 7 December 2010) Optical pumping of an optically thick atomic vapor typically requires a quenching the atoms. We show that optical pumping of a trace contamination of Rb present in K metal results in a 4

  11. Evaluation of high-efficiency gas-liquid contactors for natural gas processing. Semi-annual report, April--September 1995

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    The objective of this proposed program is to ensure reliable supply of high-quality natural gas by reducing the cost of treating subquality natural gas containing H{sub 2}O, CO{sub 2}, H{sub 2}S and/or trace quantities of other gaseous impurities by applying high-efficiency rotating and structured packing gas liquid contactors. Work accomplished during this reporting period are discussed for the following tasks: Task 2, field experimental site seletion; Task 3, field experimental skid unit design and preliminary economic evaluations; and Task 6, fluid dynamic studies.

  12. HEATING THE ATMOSPHERE ABOVE SUNSPOTS

    E-Print Network [OSTI]

    Rucklidge, Alastair

    become fragmented and twisted, and where they generate the necessary energy to heat the solar coronaHEATING THE ATMOSPHERE ABOVE SUNSPOTS David Alexander and Neal E. Hurlburt Lockheed Martin Solar, University of Cambridge, Cambridge, CB3 9EW, UK Abstract We present our results of a hybrid model of sunspots

  13. Space Science: Atmosphere Thermal Structure

    E-Print Network [OSTI]

    Johnson, Robert E.

    Space Science: Atmosphere Part -2 Thermal Structure Review tropospheres Absorption of Radiation Adiabatic Lapse Rate ~ 9 K/km Slightly smaller than our estimate Pressure ~3000ft under ocean surface thickness (positive up) is the solar zenith angle Fs is the solar energy flux at frequency (when

  14. Sulfur capture in an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Baars, D.M.; Hunter, C.A.; Keitelman, E.N.

    1981-06-01T23:59:59.000Z

    Sulfur capture in an atmospheric fluidized-bed combustor (AFBC) both with and without recycle of fines elutriated from the bed was studied. Two empirical correlations, one by Babcock and Wilcox and the other by Westinghouse, correlate sulfur capture as a function of the calcium-to-sulfur mole ratio and gas residence time. Both correlations fit the experimental no-recycle results quite well. Of the limestones tested with no recycle, Vulcan Materials exhibits the best sulfur-capture performance. Data collected with Reed limestone indicates that recycle improves sulfur-capture compared with once-through performance. However, there is a decreasing effect on sulfur capture as the recycle rate is increased to large values. At 90% sulfur capture, the fractional reduction of fresh limestone feed attributable to recycle is 24 to 35% over a gas-residence time range of 0.7 to 0.4 s.

  15. Exhaust gas treatment in testing nuclear rocket engines

    SciTech Connect (OSTI)

    Zweig, H.R.; Fischler, S.; Wagner, W.R. (Rocketdyne Division, Rockwell International Corporation, 6633 Canoga Avenue, P.O. Box 7922, Canoga Park, California 91309-7922 (United States))

    1993-01-15T23:59:59.000Z

    With the exception of the last test series of the Rover program, Nuclear Furnace 1, test-reactor and rocket engine hydrogen gas exhaust generated during the Rover/NERVA program was released directly to the atmosphere, without removal of the associated fission products and other radioactive debris. Current rules for nuclear facilities (DOE Order 5480.6) are far more protective of the general environment; even with the remoteness of the Nevada Test Site, introduction of potentially hazardous quantities of radioactive waste into the atmosphere must be scrupulously avoided. The Rocketdyne treatment concept features a diffuser to provide altitude simulation and pressure recovery, a series of heat exchangers to gradually cool the exhaust gas stream to 100 K, and an activated charcoal bed for adsorption of inert gases. A hydrogen-gas fed ejector provides auxiliary pumping for startup and shutdown of the engine. Supplemental filtration to remove particulates and condensed phases may be added at appropriate locations in the system. The clean hydrogen may be exhausted to the atmosphere and flared, or the gas may be condensed and stored for reuse in testing. The latter approach totally isolates the working gas from the environment.

  16. Description of the Science Plan for the April 1995 CoOP Experiment, `Gas Transfer in Coastal Waters',

    E-Print Network [OSTI]

    Jaehne, Bernd

    of air-sea gas-transfer rates are essential for understand- ing the global cycles of carbon dioxide that intended to measure both atmospheric and ocean-mixed layer properties. 1 Introduction Accurate estimates

  17. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27T23:59:59.000Z

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  18. Compositional diversity in the atmospheres of hot Neptunes, with application to GJ 436b

    E-Print Network [OSTI]

    Moses, Julianne I; Visscher, Channon; Richardson, Molly R; Nettelmann, Nadine; Fortney, Jonathan J; Stevenson, Kevin B; Madhusudhan, Nikku

    2013-01-01T23:59:59.000Z

    Neptune-sized extrasolar planets that orbit relatively close to their host stars -- often called "hot Neptunes" -- are common within the known population of exoplanets and planetary candidates. Similar to our own Uranus and Neptune, inefficient accretion of nebular gas is expected produce hot Neptunes whose masses are dominated by elements heavier than hydrogen and helium. At high atmospheric metallicities of 10-10,000x solar, hot Neptunes will exhibit an interesting continuum of atmospheric compositions, ranging from more Neptune-like, H2-dominated atmospheres to more Venus-like, CO2-dominated atmospheres. We explore the predicted equilibrium and disequilibrium chemistry of generic hot Neptunes and find that the atmospheric composition varies strongly as a function of temperature and bulk atmospheric properties such as metallicity and the C/O ratio. Relatively exotic H2O, CO, CO2, and even O2-dominated atmospheres are possible for hot Neptunes. We apply our models to the case of GJ 436b, where we find that a...

  19. AN OVERVIEW OF TOOL FOR RESPONSE ACTION COST ESTIMATING (TRACE)

    SciTech Connect (OSTI)

    FERRIES SR; KLINK KL; OSTAPKOWICZ B

    2012-01-30T23:59:59.000Z

    Tools and techniques that provide improved performance and reduced costs are important to government programs, particularly in current times. An opportunity for improvement was identified for preparation of cost estimates used to support the evaluation of response action alternatives. As a result, CH2M HILL Plateau Remediation Company has developed Tool for Response Action Cost Estimating (TRACE). TRACE is a multi-page Microsoft Excel{reg_sign} workbook developed to introduce efficiencies into the timely and consistent production of cost estimates for response action alternatives. This tool combines costs derived from extensive site-specific runs of commercially available remediation cost models with site-specific and estimator-researched and derived costs, providing the best estimating sources available. TRACE also provides for common quantity and key parameter links across multiple alternatives, maximizing ease of updating estimates and performing sensitivity analyses, and ensuring consistency.

  20. Sulfuryl fluoride in the global atmosphere

    E-Print Network [OSTI]

    Muhle, J.

    The first calibrated high-frequency, high-precision, in situ atmospheric and archived air measurements of the fumigant sulfuryl fluoride (SO[subscript 2]F[subscript 2]) have been made as part of the Advanced Global Atmospheric ...

  1. ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2012)

    E-Print Network [OSTI]

    Gerber, Edwin

    2012-01-01T23:59:59.000Z

    ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2012) Published online in Wiley Online Library using National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP) concentrations and sea- surface temperatures (SSTs). These integrations enable the relative role of ozone

  2. Cost of Gas Adjustment for Gas Utilities (Maine)

    Broader source: Energy.gov [DOE]

    This rule, applicable to gas utilities, establishes rules for calculation of gas cost adjustments, procedures to be followed in establishing gas cost adjustments and refunds, and describes reports...

  3. 1997 Atmospheric Chemistry Colloquium for Emerging Senior Scientists

    SciTech Connect (OSTI)

    Paul H. Wine

    1998-11-23T23:59:59.000Z

    DOE's Atmospheric Chemistry Program is providing partial funding for the Atmospheric Chemistry Colloquium for Emerging Senior Scientists (ACCESS) and FY 1997 Gordon Research Conference in Atmospheric Chemistry

  4. atmospheric nitrogen fluorescence: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Greenhouse Effect and Atmospheric Warming Atmosphere absorbs heat energy A real greenhouse traps heatCh4. Atmosphere and Surface Energy Balances...

  5. atmospheric energy redistribution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 Ch4. Atmosphere and Surface Energy Balances Geosciences Websites Summary: Greenhouse Effect and Atmospheric Warming Atmosphere absorbs heat energy A real greenhouse traps...

  6. atmospheric pressure surface: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    K. 27 Ch4. Atmosphere and Surface Energy Balances Geosciences Websites Summary: Greenhouse Effect and Atmospheric Warming Atmosphere absorbs heat energy A real greenhouse traps...

  7. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2009-08-11T23:59:59.000Z

    Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  8. Radar range measurements in the atmosphere.

    SciTech Connect (OSTI)

    Doerry, Armin Walter

    2013-02-01T23:59:59.000Z

    The earth's atmosphere affects the velocity of propagation of microwave signals. This imparts a range error to radar range measurements that assume the typical simplistic model for propagation velocity. This range error is a function of atmospheric constituents, such as water vapor, as well as the geometry of the radar data collection, notably altitude and range. Models are presented for calculating atmospheric effects on radar range measurements, and compared against more elaborate atmospheric models.

  9. Trace metal mapping by laser-induced breakdown spectroscopy

    SciTech Connect (OSTI)

    Kaiser, Jozef [ORNL; Novotny, Dr. Karel [Masaryk University; Hrdlicka, A [Brno University of Technology, Czech Republic; Malina, R [Brno University of Technology, Czech Republic; Hartl, M [Brno University of Technology, Czech Republic; Kizek, R [Mendel University of Brno; Adam, V [Mendel University of Brno

    2012-01-01T23:59:59.000Z

    Abstract: Laser-Induced Breakdown Spectroscopy (LIBS) is a sensitive optical technique capable of fast multi-elemental analysis of solid, gaseous and liquid samples. The potential applications of lasers for spectrochemical analysis were developed shortly after its invention; however the massive development of LIBS is connected with the availability of powerful pulsed laser sources. Since the late 80s of 20th century LIBS dominated the analytical atomic spectroscopy scene and its application are developed continuously. Here we review the utilization of LIBS for trace elements mapping in different matrices. The main emphasis is on trace metal mapping in biological samples.

  10. Proof of the Atmospheric Greenhouse Effect

    E-Print Network [OSTI]

    Smith, Arthur P

    2008-01-01T23:59:59.000Z

    A recently advanced argument against the atmospheric greenhouse effect is refuted. A planet without an infrared absorbing atmosphere is mathematically constrained to have an average temperature less than or equal to the effective radiating temperature. Observed parameters for Earth prove that without infrared absorption by the atmosphere, the average temperature of Earth's surface would be at least 33 K lower than what is observed.

  11. Atmospheric Lifetime of Fossil Fuel Carbon Dioxide

    E-Print Network [OSTI]

    Scherer, Norbert F.

    Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

  12. Homogeneous and Heterogeneous Reaction and Transformation of Hg and Trace Metals in Combustion Systems

    SciTech Connect (OSTI)

    J. Helble; Clara Smith; David Miller

    2009-08-31T23:59:59.000Z

    The overall goal of this project was to produce a working dynamic model to predict the transformation and partitioning of trace metals resulting from combustion of a broad range of fuels. The information provided from this model will be instrumental in efforts to identify fuels and conditions that can be varied to reduce metal emissions. Through the course of this project, it was determined that mercury (Hg) and arsenic (As) would be the focus of the experimental investigation. Experiments were therefore conducted to examine homogeneous and heterogeneous mercury oxidation pathways, and to assess potential interactions between arsenic and calcium. As described in this report, results indicated that the role of SO{sub 2} on Hg oxidation was complex and depended upon overall gas phase chemistry, that iron oxide (hematite) particles contributed directly to heterogeneous Hg oxidation, and that As-Ca interactions occurred through both gas-solid and within-char reaction pathways. Modeling based on this study indicated that, depending upon coal type and fly ash particle size, vaporization-condensation, vaporization-surface reaction, and As-CaO in-char reaction all play a role in arsenic transformations under combustion conditions.

  13. Changes in the ocean mixed layer following extraordinary atmospheric forcing. Master's thesis

    SciTech Connect (OSTI)

    Mettlach, T.R.

    1985-12-01T23:59:59.000Z

    A one-dimensional ocean planetary boundary-layer model is used to predict the evolution of the thermal structure of the ocean mixed layer at six locations in the ocean following the hypothetical effects on the atmosphere of a major nuclear war. The inputs to the ocean model are the heat and momentum fluxes computed from a 3D climate model designed to simulate nuclear winter effects in the atmosphere. The experiment gives evidence that the summertime mixed layer can cool 5 C within 30 days and that the effect of increased wind along coastal regions due to sudden ocean-land temperture differences will deepen the mixed layer 20 to 30 meters. The scientific literature on the subject of nuclear winter is reviewed and interpreted to trace the evolution of the nuclear winter hypothesis and to assess the quality of the results of the mixed layer experiment.

  14. COMPUTATIONAL OPTIMIZATION OF GAS COMPRESSOR ...

    E-Print Network [OSTI]

    2015-02-26T23:59:59.000Z

    Feb 26, 2015 ... When considering cost-optimal operation of gas transport net- works ..... The four most frequently used drive types are gas turbines, gas driven.

  15. Purchased Gas Adjustment Rules (Tennessee)

    Broader source: Energy.gov [DOE]

    The Purchased Gas Adjustment Rules are implemented by the Tennessee Regulatory Authority (Authority). Purchased Gas Adjustment (PGA) Rules are intended to permit the company/LDC (local gas...

  16. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    natural gas and liquefied petroleum gas have continued to make small contributions to transportation,transportation actions include electric power sector actions, eg coal to natural gas

  17. Natural gas annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-09-01T23:59:59.000Z

    This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

  18. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, J.F.

    1992-02-25T23:59:59.000Z

    A positive displacement, recirculating Roots-type rotary gas compressor is described which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits which return compressed discharge gas to the compressor housing, where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor. 12 figs.

  19. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, John F. (601 Oakwood Loop, NE., Albuquerque, NM 87123)

    1992-01-01T23:59:59.000Z

    A positive displacement, recirculating Roots-type rotary gas compressor which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits (24 and 26) which return compressed discharge gas to the compressor housing (14), where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers (10 and 12) and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor.

  20. Gas and Oil (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment has the authority to enact regulations pertaining to oil and gas production, but it cannot prorate or limit the output of any gas or oil well. A permit from the...

  1. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, Conrad M. (Antioch, CA)

    1996-01-01T23:59:59.000Z

    A microminiature gas chromatograph (.mu.GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode.

  2. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, C.M.

    1996-12-10T23:59:59.000Z

    A microminiature gas chromatograph ({mu}GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode. 7 figs.

  3. Production of stable, non-thermal atmospheric pressure rf capacitive plasmas using gases other than helium or neon

    DOE Patents [OSTI]

    Park, Jaeyoung; Henins, Ivars

    2005-06-21T23:59:59.000Z

    The present invention enables the production of stable, steady state, non-thermal atmospheric pressure rf capacitive .alpha.-mode plasmas using gases other than helium and neon. In particular, the current invention generates and maintains stable, steady-state, non-thermal atmospheric pressure rf .alpha.-mode plasmas using pure argon or argon with reactive gas mixtures, pure oxygen or air. By replacing rare and expensive helium with more readily available gases, this invention makes it more economical to use atmospheric pressure rf .alpha.-mode plasmas for various materials processing applications.

  4. Residual gas analysis device

    DOE Patents [OSTI]

    Thornberg, Steven M. (Peralta, NM)

    2012-07-31T23:59:59.000Z

    A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

  5. Natural gas annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

  6. Natural gas annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-11-17T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1994 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1990 to 1994 for each Census Division and each State. Annual historical data are shown at the national level.

  7. Gas separations using ceramic membranes. Final report, September 1988--February 1993

    SciTech Connect (OSTI)

    Lin, C.L.; Wu, J.C.S.; Gallaher, G.R.; Smith, G.W.; Flowers, D.L.; Gerdes, T.E.; Liu, P.K.T.

    1993-02-01T23:59:59.000Z

    This study covers a comprehensive evaluation of existing ceramic membranes for high temperature gas separations. Methodology has been established for microporous characterization stability and gas separation efficiency. A mathematical model was developed to predict gas separations with existing membranes. Silica and zeolitic modifications of existing membranes were pursued to enhance its separation efficiency. Some of which demonstrate unique separations properties. Use of the dense-silica membranes for hydrogen enrichment was identified as a promising candidate for future development. In addition, the decomposition of trace ammonia contaminant via a catalytic membrane reactor appears feasible. A further economic analysis is required to assess its commercial viability.

  8. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, C.A.; Rurbage, C.H.

    1982-03-17T23:59:59.000Z

    The invention is pneumatically operated valve assembly for simulatenously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two on the lines so closed. The value assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  9. Gas Cylinders: Proper Management

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    Compressed Gas Cylinders: Proper Management And Use Published by the Office of Environment, Health;1 Introduction University of California, Berkeley (UC Berkeley) departments that use compressed gas cylinders (MSDS) and your department's Job Safety Analyses (JSAs). Talk to your gas supplier about hands

  10. Static gas expansion cooler

    DOE Patents [OSTI]

    Guzek, J.C.; Lujan, R.A.

    1984-01-01T23:59:59.000Z

    Disclosed is a cooler for television cameras and other temperature sensitive equipment. The cooler uses compressed gas ehich is accelerated to a high velocity by passing it through flow passageways having nozzle portions which expand the gas. This acceleration and expansion causes the gas to undergo a decrease in temperature thereby cooling the cooler body and adjacent temperature sensitive equipment.

  11. Natural Gas Exploration

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    . Exploration and extraction of natural gas from the Marcellus shale is a potentially valuable economic stimulus for landowners. You might be wondering how the nation's economic situation is affecting the market for naturalNatural Gas Exploration: A Landowners Guide to Financial Management Natural Gas Exploration

  12. Spatial Heterogeneity of Trace Species Distributions in the Atmosphere and their effects on Climate Change

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary Moniz9MorganYouofSolvingexplore2 SpaceFacilities »of

  13. Integrated Study of MFRSR-derived Parameters of Atmospheric Aerosols and Trace Gases Over the ARM CART Site Extended Facili...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn Other NewsSpin andInterim Data

  14. Clathrate hydrates as a sink of noble gases in Titan's atmosphere

    E-Print Network [OSTI]

    C. Thomas; O. Mousis; V. Ballenegger; S. Picaud

    2007-08-16T23:59:59.000Z

    We use a statistical thermodynamic approach to determine the composition of clathrate hydrates which may form from a multiple compound gas whose composition is similar to that of Titan's atmosphere. Assuming that noble gases are initially present in this gas phase, we calculate the ratios of xenon, krypton and argon to species trapped in clathrate hydrates. We find that these ratios calculated for xenon and krypton are several orders of magnitude higher than in the coexisting gas at temperature and pressure conditions close to those of Titan's present atmosphere at ground level. Furthermore we show that, by contrast, argon is poorly trapped in these ices. This trapping mechanism implies that the gas-phase is progressively depleted in xenon and krypton when the coexisting clathrate hydrates form whereas the initial abundance of argon remains almost constant. Our results are thus compatible with the deficiency of Titan's atmosphere in xenon and krypton measured by the {\\it Huygens} probe during its descent on January 14, 2005. However, in order to interpret the subsolar abundance of primordial Ar also revealed by {\\it Huygens}, other processes that occurred either during the formation of Titan or during its evolution must be also invoked.

  15. Interactive Distributed Ray Tracing of Highly Complex Models

    E-Print Network [OSTI]

    Wald, Ingo

    projects dealing with entire cars, ships, buildings, and processing plants. The complexity of such modelsInteractive Distributed Ray Tracing of Highly Complex Models Ingo Wald, Philipp Slusallek, Carsten- ulation of huge and complex 3D environments. Examples include large structural and mechanical engineering

  16. Trace Elements Greg Mullins, Extension Nutrient Management Specialist, Virginia Tech

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    the plants. Manganese (Mn) Manganese deficiency has been found on soybeans and peanuts grown in VirginiaTrace Elements Greg Mullins, Extension Nutrient Management Specialist, Virginia Tech Steve Heckendorn, Soil Test Laboratory Manager, Virginia Tech Soil Test Note #4 Introduction Your Soil Test Report

  17. Traces of Human Migrations in Helicobacter pylori Populations

    E-Print Network [OSTI]

    Wirth, Thierry

    Traces of Human Migrations in Helicobacter pylori Populations Daniel Falush,1 Thierry Wirth,1 Bodo Reichard,1 Elena Katzowitsch,8 Xiaoyan Wang,1 Mark Achtman,1 * Sebastian Suerbaum8 Helicobacter pylori tuberculosis (2), Haemophilus influenzae (3), and Helicobac- ter pylori (4­8). H. pylori, a Gram

  18. From transformation traces to transformation rules: Assisting Model Driven Engineering

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    From transformation traces to transformation rules: Assisting Model Driven Engineering approach. In this paper we are interested in semi-automatically gen- erating labelled graph (model) transformations conform to a particu- lar syntax (meta-model). Those transformations are basic operations in model driven

  19. Boron isotope application for tracing sources of contamination in groundwater.

    E-Print Network [OSTI]

    Kasher, Roni

    Boron isotope application for tracing sources of contamination in groundwater. Abstract: Boron isotope composition and concentration of sewage effluent and pristine and contaminated groundwater from sodium perborate as a bleaching agent in detergents, leads to an enrichment of boron in wastewaters

  20. ANIMAL TRACING: BENEFITS IN CATTLE INDUSTRY AND PRIVATE INCENTIVES

    E-Print Network [OSTI]

    McCarl, Bruce A.

    AND PRIVATE INCENTIVES The economic implications of foreign animal diseases and their mitigation options haveANIMAL TRACING: BENEFITS IN CATTLE INDUSTRY AND PRIVATE INCENTIVES LEVAN ELBAKIDZE Assistant Research Professor Department of Agricultural Economics Texas A&M University College Station, TX, 77843

  1. Execution Trace-Driven Automated Attack Signature Generation Susanta Nanda

    E-Print Network [OSTI]

    Chiueh, Tzi-cker

    Execution Trace-Driven Automated Attack Signature Generation Susanta Nanda Symantec Research Labs In its most general form, an attack signature is a program that can correctly determine if an input network packet se- quence can successfully attack a protected network appli- cation. Filter rules used

  2. A Feasibility Study: Mining Daily Traces for Home Heating Control

    E-Print Network [OSTI]

    Whitehouse, Kamin

    , prediction 1. INTRODUCTION Heating, ventilation and cooling (HVAC) contributes most to a home's energy billsA Feasibility Study: Mining Daily Traces for Home Heating Control Dezhi Hong and Kamin Whitehouse and make predictions of arrival times. Our approach requires the minimum ef- forts for heating controls

  3. Auto-Generation of Communication Benchmark Traces Vivek Deshpande

    E-Print Network [OSTI]

    Mueller, Frank

    Auto-Generation of Communication Benchmark Traces Vivek Deshpande North Carolina State University.edu Frank Mueller North Carolina State University Raleigh, NC, USA mueller@cs.ncsu.edu ABSTRACT Benchmarks creation is a tedious manual process. As a result, benchmarks tend to lag behind the development of complex

  4. RESEARCH ARTICLE Particles for tracing turbulent liquid helium

    E-Print Network [OSTI]

    Lathrop, Daniel P.

    RESEARCH ARTICLE Particles for tracing turbulent liquid helium Gregory P. Bewley Æ K. R of local flow velocities in turbulent liquid helium, using tracer particles. We survey and evaluate, we note that cryogenic helium is attractive for experimental studies because its kinematic viscosity

  5. PALEOZOIC TRACE FOSSILS FROM THE KUFRA BASIN, LIBYA

    E-Print Network [OSTI]

    Benton, Michael

    PALEOZOIC TRACE FOSSILS FROM THE KUFRA BASIN, LIBYA BRIAN R. TURNER AND MICHAEL J. BENTONPaleozoicsuccessionin the southeastern part ofthe Kufra Basin, Libya, comprises a sequence of sedimentary facies up to 250 m thick THEK u m BASINin southeast Libya (Figure 1)occupiesan area of about 400,000km2and is filled

  6. Developing Performance Models from Non-intrusive Monitoring Traces

    E-Print Network [OSTI]

    Murphy, John

    Developing Performance Models from Non- intrusive Monitoring Traces Daniela Mania, John Murphy transactions within the system at run-time using non-intrusive monitoring. Our belief is this methodology obtained by non-intrusive monitoring of an EJB-based e-commerce application. Moreover, the methodology

  7. Parallel Seismic Ray Tracing in a Global Earth Model

    E-Print Network [OSTI]

    Genaud, Stéphane

    1 Parallel Seismic Ray Tracing in a Global Earth Model Marc Grunberg * , Stéphane Genaud of the Earth interior, and seismic tomogra- phy is a means to improve knowledge in this #28;eld. In order present in this paper the de- sign of a software program implement- ing a fast seismic ray

  8. Balancing Privacy and Fidelity in Packet Traces for Security Evaluation

    E-Print Network [OSTI]

    Fahmy, Sonia

    for a certain network. Previous attempts at developing security benchmarks include the 1998 and 1999 evaluation1 Balancing Privacy and Fidelity in Packet Traces for Security Evaluation Sonia Fahmy and Christine.com Abstract Security mechanisms, such as firewalls and intrusion detection systems, protect networks

  9. Welcome FUPWG- Natural Gas Overview

    Broader source: Energy.gov [DOE]

    Presentation—given at the Federal Utility Partnership Working Group (FUPWG) Fall 2008 meeting—provides an overview of natural gas, including emissions, compressed natural gas (CNG) vehicles, and landfill gas supplement for natural gas system.

  10. An Infrared Spectral Library for Atmospheric Environmental Monitoring...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An Infrared Spectral Library for Atmospheric Environmental Monitoring. An Infrared Spectral Library for Atmospheric Environmental Monitoring. Abstract: Infrared (IR) spectroscopy...

  11. atmospheric research community: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University Corporation for Atmospheric Research Geosciences Websites Summary: University Corporation for Atmospheric Research CIGNA DENTAL PREFERRED PROVIDER INSURANCE EFFECTIVE...

  12. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios; Torres, Sharon G.; Hakala, Jacqueline A.; Shao, Hongbo; Cantrell, Kirk J.; Carroll, Susan A.

    2013-01-01T23:59:59.000Z

    ABSTRACT: Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising; however, possible CO2 or CO2-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define to provide a range of concentrations that can be used as the trace element source term for reservoirs and leakage pathways in risk simulations. Storage source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from cements and sandstones, shales, carbonates, evaporites, and basalts from the Frio, In Salah, Illinois Basin, Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands, and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution was tracked by measuring solution concentrations over time under conditions (e.g., pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for maximum contaminant levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments because of the presence of CO2. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rocks exceed the MCLs byan order of magnitude, while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the trace element source term for reservoirs and leakage pathways in risk simulations to further evaluate the impact of leakage on groundwater quality.

  13. Natural gas leak mapper

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2008-05-20T23:59:59.000Z

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  14. Gas Hydrate Storage of Natural Gas

    SciTech Connect (OSTI)

    Rudy Rogers; John Etheridge

    2006-03-31T23:59:59.000Z

    Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

  15. Zevenhoven & Kilpinen TRACE ELEMENTS, ALKALI METALS 19.6.2001 8-1 Chapter 8 Trace elements,

    E-Print Network [OSTI]

    Zevenhoven, Ron

    air pollutants), "known or suspected of causing cancer or other serious health effects" (see also, in part stemming from anthropogenic sources, i.e. pollution. In wastes and waste-derived fuels the "trace to fouling of turbine blades (mainly Ca)or pollute or poison catalysts (mainly As) or sorbents downstream

  16. Monitoring hydrocarbons and trace metals in Beaufort Sea sediments and organisms. Final report

    SciTech Connect (OSTI)

    Boehm, P.; LeBlanc, L.; Trefry, J.; Marajh-Whittemore, P.; Brown, J.

    1990-10-01T23:59:59.000Z

    As part of the Minerals Management Service's environmental studies of oil and gas exploration and production activities in the Alaskan Beaufort Sea, a study was conducted in 1989 to monitor the marine environment for inputs of chemicals related to drilling and exploration. The 1989 Beaufort Sea Monitoring Program (BSMP) was designed to monitor sediments and selected benthic organisms for trace metals and hydrocarbons so as to infer any changes that might have resulted from drilling and production activities. A series of 49 stations were sampled during the program. The study area extended from Cape Halkett on the western end of Harrison Bay to Griffin Point, east of Barter Island. The sampling design combined an area-wide approach in which stations were treated as replicates of 8 specific geographic regions, with an activity-specific approach, which focused on the potential establishment of metal or hydrocarbon concentration gradients with distance from the Endicott Production Field in Prudhoe Bay. The analytical program focused on the analysis of the fine-fraction of the sediment for a series of trace metals and elements and the analysis of a suite of saturated and aromatic hydrocarbons in the bulk sediment. The total organic carbon (TOB) content and the grain size distribution in the sediments were determined as well. Benthic bivalve molluscs, representative of several feeding types were collected from those stations for which data previously existed from the 1984-1986 BSMP, and were analyzed for metals and saturated and aromatic hydrocarbons. The benthic amphipods were collected, pooled by station or region, and analyzed as well.

  17. Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters...

    Open Energy Info (EERE)

    the groundwater system was essentially complete. Some of the waters contain magmatic helium with 3He4He ratios as high as 4.5 times the atmospheric ratio, and a magmatic...

  18. Pulse atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. During this reporting period, a total of eight shakedown and debugging coal combustion tests were performed in the AFBC. A start-up procedure was established, system improvements implemented, and preliminary material and heat balances made based on these tests. The pulse combustor for the AFBC system was fabricated and installed and a series of tests was conducted on the system. 17 figs., 5 tabs.

  19. NETL SOFC: Atmospheric Pressure Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Saleshttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gif Directorate -AdvancedMIRTBD525AdaptingWaterTerryAtmospheric

  20. Trace metal uptake and accumulation pathways in Kemp's ridley sea turtles (Lepidochelys kempii)

    E-Print Network [OSTI]

    Wang, Hui-Chen

    2005-08-29T23:59:59.000Z

    Little is known of trace metal concentrations and their possible role in the mortality of critically endangered Kemp??s ridley sea turtles (Lepidochelys kempii). Research described herein characterized concentrations of seven trace metals ?? Ag, Cd...

  1. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  2. Atmospheric fluidized-bed combustion performance guidelines

    SciTech Connect (OSTI)

    Sotelo, E. (Sotelo (Ernest), Berkeley, CA (USA))

    1991-03-01T23:59:59.000Z

    Performance specifications for conventional coal-fired boilers typically call for tests to be conducted in accordance with the ASME Performance Test Code for Steam Generating Units, PTC 4.1. The Code establishes procedures for conducting performance tests primarily to determine efficiency and capacity. The current edition of the PTC 4.1 is not entirely applicable to atmospheric fluidized-bed combustion boilers, however. AFBC boilers typically are equipped with integral sulfur capture through the addition of a sorbent material along with the fuel feed to the combustor, and this new technology introduces heat losses and credits that are not described in PTC 4.1. These heat losses and credits include combustion heat loss due to the calcination of the sorbent, heat credit due to sulfation, and the effects of calcination and sulfation on the dry flue gas flow, all of which significantly affect boiler efficiency calculations. The limitations of the current issue of the PTC 4.1 is recognized and the Code is now being reviewed to include heat losses and credits common to AFBC boilers. While this work will take some time, there is an immediate need for procedures for performance testing of AFBC boilers. These Guidelines are prepared to meet that need in the interim. The Guidelines detail procedures for boiler efficiency tests. They introduce technical and economic issues that may influence the test level of detail and accuracy. Methods of identifying required measurements, selection of measurement schemes, and assessment of measured versus estimated values are presented. A case study is used to illustrate the procedures and indicate which are the major credits and losses in the efficiency of a typical AFBC boiler. 6 figs., 8 tabs.

  3. Atmospheric process evaluation of mobile source emissions

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    During the past two decades there has been a considerable effort in the US to develop and introduce an alternative to the use of gasoline and conventional diesel fuel for transportation. The primary motives for this effort have been twofold: energy security and improvement in air quality, most notably ozone, or smog. The anticipated improvement in air quality is associated with a decrease in the atmospheric reactivity, and sometimes a decrease in the mass emission rate, of the organic gas and NO{sub x} emissions from alternative fuels when compared to conventional transportation fuels. Quantification of these air quality impacts is a prerequisite to decisions on adopting alternative fuels. The purpose of this report is to present a critical review of the procedures and data base used to assess the impact on ambient air quality of mobile source emissions from alternative and conventional transportation fuels and to make recommendations as to how this process can be improved. Alternative transportation fuels are defined as methanol, ethanol, CNG, LPG, and reformulated gasoline. Most of the discussion centers on light-duty AFVs operating on these fuels. Other advanced transportation technologies and fuels such as hydrogen, electric vehicles, and fuel cells, will not be discussed. However, the issues raised herein can also be applied to these technologies and other classes of vehicles, such as heavy-duty diesels (HDDs). An evaluation of the overall impact of AFVs on society requires consideration of a number of complex issues. It involves the development of new vehicle technology associated with engines, fuel systems, and emission control technology; the implementation of the necessary fuel infrastructure; and an appropriate understanding of the economic, health, safety, and environmental impacts associated with the use of these fuels. This report addresses the steps necessary to properly evaluate the impact of AFVs on ozone air quality.

  4. THE INFLUENCE OF BENZENE AS A TRACE REACTANT IN TITAN AEROSOL ANALOGS

    SciTech Connect (OSTI)

    Trainer, Melissa G. [Planetary Environments Laboratory, Code 699, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Sebree, Joshua A. [NASA Postdoctoral Program Fellow, Code 699, Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Heidi Yoon, Y.; Tolbert, Margaret A., E-mail: melissa.trainer@nasa.gov [Cooperative Institute for Research in Environmental Sciences, University of Colorado at Boulder, Box 216 UCB, Boulder, CO 80309 (United States)

    2013-03-20T23:59:59.000Z

    Benzene has been detected in Titan's atmosphere by Cassini instruments, with concentrations ranging from sub-ppb in the stratosphere to ppm in the ionosphere. Sustained levels of benzene in the haze formation region could signify that it is an important reactant in the formation of Titan's organic aerosol. To date, there have not been laboratory investigations to assess the influence of benzene on aerosol properties. We report a laboratory study on the chemical composition of organic aerosol formed from C{sub 6}H{sub 6}/CH{sub 4}/N{sub 2} via far ultraviolet irradiation (120-200 nm). The compositional results are compared to those from aerosol generated by a more ''traditional Titan'' mixture of CH{sub 4}/N{sub 2}. Our results show that even a trace amount of C{sub 6}H{sub 6} (10 ppm) has significant impact on the chemical composition and production rates of organic aerosol. There are several pathways by which photolyzed benzene may react to form larger molecules, both with and without the presence of CH{sub 4}, but many of these reaction mechanisms are only beginning to be explored for the conditions at Titan. Continued work investigating the influence of benzene in aerosol growth will advance understanding of this previously unstudied reaction system.

  5. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01T23:59:59.000Z

    gas reservoirs for carbon sequestration and enhanced gasproduction and carbon sequestration, Society of Petroleumfeasibiilty of carbon sequestration with enhanced gas

  6. Matrix Optimization for the MALDI-TOF-MS Analysis of Trace Biodiesel Components (Poster)

    SciTech Connect (OSTI)

    McAlpin, C. R.; Voorhees, K. J.; Alleman, T. L.; McCormick, R. L.

    2009-01-01T23:59:59.000Z

    Trace biodiesel components that could reduce the fuel's operability in cold weather are analyzed using MALDI-TOF mass spectrometry.

  7. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01T23:59:59.000Z

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  8. A Thesis for the Degree of Master Design of Fair Tracing E-cash

    E-Print Network [OSTI]

    Kim, Kwangjo

    A Thesis for the Degree of Master Design of Fair Tracing E-cash System based on Blind Signature Tracing E-cash System based on Blind Signature #12;Design of Fair Tracing E-cash System based on Blind and Communications University A thesis submitted to the faculty of Information and Com- munications University

  9. TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE

    E-Print Network [OSTI]

    Laughlin, Robert B.

    TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE WAVELENGTH Grand Forks, ND 58202-9018 Keywords: scanning electron microscopy, trace metals, coal analysis ABSTRACT Scanningelectron microscopy with wavelength-dispersive spectrometry has been used to measure trace metals in coal

  10. Trace Formula in Noncommutative Geometry and the Zeros of the Riemann Zeta Function

    E-Print Network [OSTI]

    Connes, Alain

    Trace Formula in Noncommutative Geometry and the Zeros of the Riemann Zeta Function Alain CONNES interpretation of the explicit formulas of number theory as a trace formula on the noncommutative space of Adele classes. This reduces the Riemann hypothesis to the validity of the trace formula and eliminates

  11. A RELATIVE TRACE FORMULA FOR A COMPACT RIEMANN KIMBALL MARTIN, MARK MCKEE, AND ERIC WAMBACH

    E-Print Network [OSTI]

    Martin, Kimball

    A RELATIVE TRACE FORMULA FOR A COMPACT RIEMANN SURFACE KIMBALL MARTIN, MARK MCKEE, AND ERIC WAMBACH Abstract. We study a relative trace formula for a compact Riemann surface with respect to a closed geodesic estimates on the lengths of geodesic segments which start and end orthogonally on C. Variant trace formulas

  12. IEEE TRANSACTIONS ON MULTIMEDIA, VOL. 9, NO. 4, JUNE 2007 677 Digital Image Tracing by Sequential

    E-Print Network [OSTI]

    Fontanari, Claudio

    IEEE TRANSACTIONS ON MULTIMEDIA, VOL. 9, NO. 4, JUNE 2007 677 Digital Image Tracing by Sequential many interesting applications such as multimedia document tracing, data usage monitoring, mul- tiple--Asymmetric watermarking, image tracing, linear algebra, multiple watermarking. I. INTRODUCTION SECURITY of multimedia

  13. The effects of shifting modality between study and test: a fuzzy-trace theory analysis

    E-Print Network [OSTI]

    Gerkens, David Preston

    2001-01-01T23:59:59.000Z

    The present research was designed to test properties of the fuzzy-trace theory memory model. Fuzzy-trace theory is a global memory model that posits that multiple memory traces are formed for every experience. According to the theory there are two...

  14. RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL.

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL. PART 1: SEISMOGRAMS V â?? ACLAV BUCHA­waves in the smoothed acoustic SEG/EAGE Salt Model are computed. The shot­receiver configuration is derived from that the smoothed SEG/EAGE Salt Model is suitable for two­point ray tracing. KEY WORDS Velocity model, ray tracing

  15. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1984-06-05T23:59:59.000Z

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  16. Atmospheric neutrino flux at INO site

    SciTech Connect (OSTI)

    Honda, Morihiro [Institute for Cosmic Ray Research, University of Tokyo, 5-1-5 Kashiwa-no-ha, Kashiwa, Chiba 277-8582 (Japan)

    2011-11-23T23:59:59.000Z

    To illustrate the calculation of the atmospheric neutrino flux, we briefly explain our calculation scheme and important components, such as primary cosmic ray spectra, interaction model, and geomagnetic model. Then, we calculate the atmospheric neutrino flux at INO site in our calculation scheme. We compare the calculated atmospheric neutrino fluxes predicted at INO with those at other major neutrino detector sites, especially that at SK site.

  17. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, Charles A. (Oak Ridge, TN); Burbage, Charles H. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    The invention is a pneumatically operated valve assembly for simultaneously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two of the lines so closed. The valve assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  18. Thermodynamics of Chaplygin gas

    E-Print Network [OSTI]

    Yun Soo Myung

    2011-05-11T23:59:59.000Z

    We clarify thermodynamics of the Chaplygin gas by introducing the integrability condition. All thermal quantities are derived as functions of either volume or temperature. Importantly, we find a new general equation of state, describing the Chaplygin gas completely. We confirm that the Chaplygin gas could show a unified picture of dark matter and energy which cools down through the universe expansion without any critical point (phase transition).

  19. Ray tracing a three dimensional scene using a grid

    SciTech Connect (OSTI)

    Wald, Ingo; Ize, Santiago; Parker, Steven G; Knoll, Aaron

    2013-02-26T23:59:59.000Z

    Ray tracing a three-dimensional scene using a grid. One example embodiment is a method for ray tracing a three-dimensional scene using a grid. In this example method, the three-dimensional scene is made up of objects that are spatially partitioned into a plurality of cells that make up the grid. The method includes a first act of computing a bounding frustum of a packet of rays, and a second act of traversing the grid slice by slice along a major traversal axis. Each slice traversal includes a first act of determining one or more cells in the slice that are overlapped by the frustum and a second act of testing the rays in the packet for intersection with any objects at least partially bounded by the one or more cells overlapped by the frustum.

  20. Toxicity of atmospheric aerosols on marine phytoplankton

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    metals added from these aerosols to the bioassay incubationsreleased to seawater from the aerosol filters after Author4605 CHEMISTRY Atmospheric aerosol deposition CHEMISTRY

  1. Urban Atmospheres captures a unique, synergistic moment

    E-Print Network [OSTI]

    Paulos, Eric

    Urban Atmospheres captures a unique, synergistic moment ­ expanding urban populations, rapid EDITORS Eric Paulos Intel Research eric@paulos.net Tom Jenkins Royal College of Art thomas

  2. Characterizing orbit uncertainty due to atmospheric uncertainty

    E-Print Network [OSTI]

    Wilkins, Matthew Paul

    2000-01-01T23:59:59.000Z

    is implemented to model errors in the atmospheric density model. This study shows that the Kalman filter computes a believable and more realistic covariance....

  3. Atmospheric Radiation Measurement Climate Research Facility ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    improving our understanding of how clouds and atmospheric moisture interact with solar radiation and the effects of these interactions on climate. Photo courtesy Argonne National...

  4. Physics Potential of Future Atmospheric Neutrino Searches

    E-Print Network [OSTI]

    Thomas Schwetz

    2008-12-12T23:59:59.000Z

    The potential of future high statistics atmospheric neutrino experiments is considered, having in mind currently discussed huge detectors of various technologies (water Cerekov, magnetized iron, liquid Argon). I focus on the possibility to use atmospheric data to determine the octant of $\\theta_{23}$ and the neutrino mass hierarchy. The sensitivity to the $\\theta_{23}$-octant of atmospheric neutrinos is competitive (or even superior) to long-baseline experiments. I discuss the ideal properties of a fictitious atmospheric neutrino detector to determine the neutrino mass hierarchy.

  5. Super-Kamiokande atmospheric neutrino results

    E-Print Network [OSTI]

    Toshiyuki Toshito; the Super-Kamiokande collaboration

    2001-05-14T23:59:59.000Z

    We present atmospheric neutrino results from a 79 kiloton year (1289 days) exposure of the Super-Kamiokande detector. Our data are well explained by $\

  6. atmospheres: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  7. atmosphere: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  8. atmospherics: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to optical depth perturbations. In Earth-type atmospheres sustained planetary greenhouse effect with a stable ground surface temperature can only exist at a particular...

  9. Izvestiya, Atmospheric and Oceanic Physics, Vol. 40, No. 3, 2004, pp. 313322. Translated from Izvestiya AN. Fizika Atmosfery i Okeana, Vol. 40, No. 3, 2004, pp. 355365. Original Russian Text Copyright 2004 by Makarova, Poberovskii, Timofeev.

    E-Print Network [OSTI]

    information about them is used in global atmospheric models for the prediction of climate change. The annual major factors that cause the observed changes in gas contents over northwestern Russia. Temporal /Interperiodica" (Russia). 1. INTRODUCTION Anthropogenic impacts on the atmospheric compo- sition have enhanced

  10. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios K.; Torres, Sharon G.; Hakala, J. Alexandra; Shao, Hongbo; Cantrell, Kirk J.; Carroll, Susan

    2013-01-01T23:59:59.000Z

    Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising, however, possible CO{sub 2} or CO{sub 2}-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define trace metal source terms from the reaction of supercritical CO{sub 2}, storage reservoir brines, reservoir and cap rocks. Storage reservoir source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from sandstones, shales, carbonates, evaporites, basalts and cements from the Frio, In Salah, Illinois Basin – Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution is tracked by measuring solution concentrations over time under conditions (e.g. pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for Maximum Contaminant Levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments due to the presence of CO{sub 2}. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rock exceed the MCLs by an order of magnitude while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the reservoir and caprock source term to further evaluate the impact of leakage on groundwater quality.

  11. Solar limb darkening and ray trace evaluation of solar concentrators

    SciTech Connect (OSTI)

    Negi, B.S.; Bhowmik, N.C.; Mathur, S.S.; Kandpal, T.C.

    1985-01-15T23:59:59.000Z

    A comparison of different correlations commonly used to describe the limb darkening effect is made. A somewhat new correlation is proposed which predicts the values to within +- 1.5% of the experimental values. Using a conventional ray trace technique and assigning proper weight factors to each ray, the distribution of the local concentration ratio over a flat absorber placed in the focal plane of a cylindrical parabolic trough is also determined.

  12. Lyapunov exponents for 2D ray tracing without interfaces

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    Lyapunov exponents for 2­D ray tracing without interfaces LudŸek KlimeŸs Department of Geophysics@seis.karlov.mff.cuni.cz Summary The Lyapunov exponents asymptotically quantify the exponential divergence of rays. The ``Lyapunov exponent'' for a finite 2­D ray and the average ``Lyapunov exponents'' for a set of finite 2­D rays

  13. Home Safety: Radon Gas 

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12T23:59:59.000Z

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  14. String Gas Baryogenesis

    E-Print Network [OSTI]

    G. L. Alberghi

    2010-02-19T23:59:59.000Z

    We describe a possible realization of the spontaneous baryogenesis mechanism in the context of extra-dimensional string cosmology and specifically in the string gas scenario.

  15. Natural gas annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-10-01T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1997 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1993 to 1997 for each Census Division and each State. Annual historical data are shown at the national level. 27 figs., 109 tabs.

  16. Home Safety: Radon Gas

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12T23:59:59.000Z

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  17. Liquefied Natural Gas (Iowa)

    Broader source: Energy.gov [DOE]

    This document adopts the standards promulgated by the National Fire Protection Association as rules for the transportation, storage, handling, and use of liquefied natural gas. The NFPA standards...

  18. Oil and Gas Outlook

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas Outlook For Independent Petroleum Association of America November 13, 2014 | Palm Beach, FL By Adam Sieminski, Administrator U.S. Energy Information Administration Recent...

  19. Oil and Gas (Indiana)

    Broader source: Energy.gov [DOE]

    This division of the Indiana Department of Natural Resources provides information on the regulation of oil and gas exploration, wells and well spacings, drilling, plugging and abandonment, and...

  20. NETL: Oil & Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that address the unique nature and challenging locations of many of our remaining oil and natural gas accumulations. The National Energy Technology Laboratory's (NETL)...

  1. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31T23:59:59.000Z

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  2. Natural Gas Rules (Louisiana)

    Broader source: Energy.gov [DOE]

    The Louisiana Department of Natural Resources administers the rules that govern natural gas exploration and extraction in the state. DNR works with the Louisiana Department of Environmental...

  3. Gas venting system

    DOE Patents [OSTI]

    Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

    2010-06-29T23:59:59.000Z

    A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

  4. Line formation in AGB atmospheres including velocity effects. Molecular line profile variations of long period variables

    E-Print Network [OSTI]

    Nowotny, W; Aringer, B

    2010-01-01T23:59:59.000Z

    The atmospheres of evolved red giants are considerably influenced by pulsations of the stellar interiors and developing stellar winds. The resulting complex velocity fields severely affect molecular line profiles observable in NIR spectra. With the help of model calculations the complex line formation process in AGB atmospheres was explored with the focus on velocity effects. Furthermore, we aimed for atmospheric models which are able to quantitatively reproduce line profile variations found in observed spectra of pulsating late-type giants. Models describing pulsation-enhanced dust-driven winds were used to compute synthetic spectra under the assumptions of chemical equilibrium and LTE and by solving the radiative transfer in spherical geometry including velocity effects. Radial velocities derived from Doppler-shifted synthetic line profiles provide information on the gas velocities in the line-forming region of the spectral features. On the basis of dynamic models we investigated in detail the finding that ...

  5. Control of Trace Metal Emissions During Coal Combustion

    SciTech Connect (OSTI)

    Thomas C. Ho

    1996-10-01T23:59:59.000Z

    Emissions of toxic trace metals in the form of metal fumes or submicron particulate from a coal-fired combustion source have received greater environmental and regulatory concern over the past years. Current practice of controlling these emissions is to collect them at the cold-end of the process by air-pollution control devices (APCDS) such as electrostatic precipitators and baghouses. However, trace metal fumes may not always be effectively collected by these devices because the formed fumes are extremely small. The proposed research is to explore the opportunities for improved control of toxic trace metal emissions, alternatively, at the hot-end of the coal combustion process, i.e., in the combustion chamber. The technology proposed is to prevent the metal fumes from forming during the process, which would effectively eliminate the metal emission problems. Specifically, the technology is to employ suitable sorbents to (1) reduce the amount of metal volatilization during combustion and (2) capture volatilized metal vapors. The objectives of the project are to demonstrate the technology and to characterize the metal capture process during coal combustion in a fluidized bed combustor.

  6. Landfill gas cleanup for carbonate fuel cell power generation. Final report

    SciTech Connect (OSTI)

    Steinfield, G.; Sanderson, R.

    1998-02-01T23:59:59.000Z

    Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

  7. Response of global soil consumption of atmospheric methane to changes in atmospheric climate and nitrogen deposition

    E-Print Network [OSTI]

    Zhuang, Qianlai

    Soil consumption of atmospheric methane plays an important secondary role in regulating the atmospheric CH4 budget, next to the dominant loss mechanism involving reaction with the hydroxyl radical (OH). Here we used a ...

  8. 47 Natural Gas Market Trends NATURAL GAS MARKET TRENDS

    E-Print Network [OSTI]

    47 Natural Gas Market Trends Chapter 5 NATURAL GAS MARKET TRENDS INTRODUCTION Natural gas discusses current natural gas market conditions in California and the rest of North America, followed on the outlook for demand, supply, and price of natural gas for the forecasted 20-year horizon. It also addresses

  9. Parallization of Stellar Atmosphere Codes

    E-Print Network [OSTI]

    P. Hoeflich

    2002-09-19T23:59:59.000Z

    Parallel computing has turned out to be the enabling technology to solve complex physical systems. However, the transition from shared memory, vector computers to massively parallel, distributed memory systems and, recently, to hybrid systems poses new challenges to the scientist. We want to present a cook-book (with a very strong, personal bias) based on our experience with parallization of our existing codes. Some of the general tools and communication libraries are discussed. Our approach includes a mixture of algorithm, domain and physical module based parallization. The advantages, scalability and limitations of each are discussed at some examples. We want show that it becomes easier to write parallel code with increasing complexity of the physical problem making stellar atmosphere codes beyond the classical assumptions very suitable.

  10. Shale gas is natural gas trapped inside

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretary of EnergyFocus Group HSS/UnionGlossary Shale GasShale gas

  11. Bulk Viscosity of a Gas of Massless Pions

    E-Print Network [OSTI]

    Jiunn-Wei Chen; Juven Wang

    2009-03-31T23:59:59.000Z

    In the hadronic phase, the dominant configuration of QCD with two flavors of massless quarks is a gas of massless pions. We calculate the bulk viscosity (zeta) using the Boltzmann equation with the kinetic theory generalized to incorporate the trace anomaly. We find that the dimensionless ratio zeta/s, s being the entropy density, is monotonic increasing below T=120 MeV, where chiral perturbation theory is applicable. This, combined with previous results, shows that zeta/s reaches its maximum near the phase transition temperature Tc, while eta/s, eta being the shear viscosity, reaches its minimum near Tc in QCD with massless quarks.

  12. Limits to the lunar atmosphere

    SciTech Connect (OSTI)

    Morgan, T.H. (National Aeronautics and Space Administration, Washington, D.C. (USA)); Shemansky, D.E. (Univ. of Arizona, Tucson (USA))

    1991-02-01T23:59:59.000Z

    The presence of sodium and potassium on the Moon implies that other more abundant species should be present. Volatile molecules like H{sub 2}O are significantly more abundant than sodium in any of the proposed external atmospheric sources. Source mechanisms which derive atoms from the surface should favor abundant elements in the regolith. It is therefore puzzling that the Apollo ultraviolet spectrometer experiment set limits on the density of oxygen of N{sub O} < 5 {times} 10{sup 2} cm{sup {minus}3}, and that the Apollo Lunar Atmospheric Composition Experiment data imply N{sub O} < 50 cm{sup {minus}3} above the subsolar point. These limits are surprisingly small relative to the measured value for sodium. A simple consideration of sources and sinks predicts significantly greater densities of oxygen. It is possible but doubtful that the Apollo measurements occur ed during an epoch in which source rates were small. A preferential loss process for oxygen on the darkside of the Moon is considered in which ionization by electron capture in surface collisions leads to escape through acceleration in the local electric field. Cold trapping in permanently shadowed regions as a net sink is considered and discounted, but the episodic nature of cometary insertion may allow formation of ice layers which act as a stablized source of OH. On the basis of an assumed meteoroid impact source, the authors predict a possible emission brightness of {approximately} 50 R in the OH(A {minus} X)(0,0) band above the lunar bright limb. A very uncertain small comet source of H{sub 2}O could raise this value by more than two orders of magnitude.

  13. Turbine Drive Gas Generator for Zero Emission Power Plants

    SciTech Connect (OSTI)

    Doyle, Stephen E.; Anderson, Roger E.

    2001-11-06T23:59:59.000Z

    The Vision 21 Program seeks technology development that can reduce energy costs, reduce or eliminate atmospheric pollutants from power plants, provide choices of alternative fuels, and increase the efficiency of generating systems. Clean Energy Systems is developing a gas generator to replace the traditional boiler in steam driven power systems. The gas generator offers the prospects of lower electrical costs, pollution free plant operations, choices of alternative fuels, and eventual net plant efficiencies in excess of 60% with sequestration of carbon dioxide. The technology underlying the gas generator has been developed in the aerospace industry over the past 30 years and is mature in aerospace applications, but it is as yet unused in the power industry. This project modifies and repackages aerospace gas generator technology for power generation applications. The purposes of this project are: (1) design a 10 MW gas generator and ancillary hardware, (2) fabricate the gas generator and supporting equipment, (3) test the gas generator using methane as fuel, (4) submit a final report describing the project and test results. The principal test objectives are: (1) define start-up, shut down and post shutdown control sequences for safe, efficient operation; (2) demonstrate the production of turbine drive gas comprising steam and carbon dioxide in the temperature range 1500 F to 3000 F, at a nominal pressure of 1500 psia; (3) measure and verify the constituents of the drive gas; and (4) examine the critical hardware components for indications of life limitations. The 21 month program is in its 13th month. Design work is completed and fabrication is in process. The gas generator igniter is a torch igniter with sparkplug, which is currently under-going hot fire testing. Fabrication of the injector and body of the gas generator is expected to be completed by year-end, and testing of the full gas generator will begin in early 2002. Several months of testing are anticipated. When demonstrated, this gas generator will be the prototype for use in demonstration power plants planned to be built in Antioch, California and in southern California during 2002. In these plants the gas generator will demonstrate durability and its operational RAM characteristics. In 2003, it is expected that the gas generator will be employed in new operating plants primarily in clean air non-attainment areas, and in possible locations to provide large quantities of high quality carbon dioxide for use in enhanced oil recovery or coal bed methane recovery. Coupled with an emission free coal gasification system, the CES gas generator would enable the operation of high efficiency, non-polluting coal-fueled power plants.

  14. On the application of computational fluid dynamics codes for liquefied natural gas dispersion.

    SciTech Connect (OSTI)

    Luketa-Hanlin, Anay Josephine; Koopman, Ronald P. (Lawrence Livermore National Laboratory, Livermore, CA); Ermak, Donald (Lawrence Livermore National Laboratory, Livermore, CA)

    2006-02-01T23:59:59.000Z

    Computational fluid dynamics (CFD) codes are increasingly being used in the liquefied natural gas (LNG) industry to predict natural gas dispersion distances. This paper addresses several issues regarding the use of CFD for LNG dispersion such as specification of the domain, grid, boundary and initial conditions. A description of the k-{var_epsilon} model is presented, along with modifications required for atmospheric flows. Validation issues pertaining to the experimental data from the Burro, Coyote, and Falcon series of LNG dispersion experiments are also discussed. A description of the atmosphere is provided as well as discussion on the inclusion of the Coriolis force to model very large LNG spills.

  15. Inorganic hazardous air pollutants before and after a limestone flue gas desulfurization system as a function of <10 micrometer particle sizes and unit load

    SciTech Connect (OSTI)

    Maxwell, D.P.; Williams, W.A.; Flora, H.B. II [Radian Corp., Austin, TX (United States)

    1995-12-31T23:59:59.000Z

    Radian Corporation collected size-fractionated particulate samples from stack gas at a unit burning high sulfur coal with a venturi scrubber FGD system. Independent sample fractions were collected under high-load and low-load operating conditions and subjected to various techniques designed to measure the total composition and surface-extractable concentrations of selected trace elements. The relationships between unit load, particle-size distribution, total composition, and surface-extractable inorganic species are reported and compared to show the availability of trace elements relevant to potential health risks from flue gas particulate emissions.

  16. Research on Greenhouse-Gas-Induced Climate Change

    SciTech Connect (OSTI)

    Schlesinger, M. E.

    2001-07-15T23:59:59.000Z

    During the 5 years of NSF grant ATM 95-22681 (Research on Greenhouse-Gas-Induced Climate Change, $1,605,000, 9/15/1995 to 8/31/2000) we have performed work which we are described in this report under three topics: (1) Development and Application of Atmosphere, Ocean, Photochemical-Transport, and Coupled Models; (2) Analysis Methods and Estimation; and (3) Climate-Change Scenarios, Impacts and Policy.

  17. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01T23:59:59.000Z

    of Gas Price ($/Mscf) for Offshore Gas Hydrate StudyEvaluation of deepwater gas-hydrate systems. The Leadingfor Gas Production from Gas Hydrates Reservoirs. J. Canadian

  18. Controls on Gas Hydrate Formation and Dissociation

    SciTech Connect (OSTI)

    Miriam Kastner; Ian MacDonald

    2006-03-03T23:59:59.000Z

    The main objectives of the project were to monitor, characterize, and quantify in situ the rates of formation and dissociation of methane hydrates at and near the seafloor in the northern Gulf of Mexico, with a focus on the Bush Hill seafloor hydrate mound; to record the linkages between physical and chemical parameters of the deposits over the course of one year, by emphasizing the response of the hydrate mound to temperature and chemical perturbations; and to document the seafloor and water column environmental impacts of hydrate formation and dissociation. For these, monitoring the dynamics of gas hydrate formation and dissociation was required. The objectives were achieved by an integrated field and laboratory scientific study, particularly by monitoring in situ formation and dissociation of the outcropping gas hydrate mound and of the associated gas-rich sediments. In addition to monitoring with the MOSQUITOs, fluid flow rates and temperature, continuously sampling in situ pore fluids for the chemistry, and imaging the hydrate mound, pore fluids from cores, peepers and gas hydrate samples from the mound were as well sampled and analyzed for chemical and isotopic compositions. In order to determine the impact of gas hydrate dissociation and/or methane venting across the seafloor on the ocean and atmosphere, the overlying seawater was sampled and thoroughly analyzed chemically and for methane C isotope ratios. At Bush hill the pore fluid chemistry varies significantly over short distances as well as within some of the specific sites monitored for 440 days, and gas venting is primarily focused. The pore fluid chemistry in the tub-warm and mussel shell fields clearly documented active gas hydrate and authigenic carbonate formation during the monitoring period. The advecting fluid is depleted in sulfate, Ca Mg, and Sr and is rich in methane; at the main vent sites the fluid is methane supersaturated, thus bubble plumes form. The subsurface hydrology exhibits both up-flow and down-flow of fluid at rates that range between 0.5 to 214 cm/yr and 2-162 cm/yr, respectively. The fluid flow system at the mound and background sites are coupled having opposite polarities that oscillate episodically between 14 days to {approx}4 months. Stability calculations suggest that despite bottom water temperature fluctuations, of up to {approx}3 C, the Bush Hill gas hydrate mound is presently stable, as also corroborated by the time-lapse video camera images that did not detect change in the gas hydrate mound. As long as methane (and other hydrocarbon) continues advecting at the observed rates the mound would remain stable. The {_}{sup 13}C-DIC data suggest that crude oil instead of methane serves as the primary electron-donor and metabolic substrate for anaerobic sulfate reduction. The oil-dominated environment at Bush Hill shields some of the methane bubbles from being oxidized both anaerobically in the sediment and aerobically in the water column. Consequently, the methane flux across the seafloor is higher at Bush hill than at non-oil rich seafloor gas hydrate regions, such as at Hydrate Ridge, Cascadia. The methane flux across the ocean/atmosphere interface is as well higher. Modeling the methane flux across this interface at three bubble plumes provides values that range from 180-2000 {_}mol/m{sup 2} day; extrapolating it over the Gulf of Mexico basin utilizing satellite data is in progress.

  19. Oil and Gas Exploration

    E-Print Network [OSTI]

    Tingley, Joseph V.

    , oil and gas, and geothermal activities and accomplishments in Nevada: production statistics Products 23. Sloan dolomite quarry 24. Weiser gypsum quarry Oil Fields 1. Blackburn field 2. North WillowMetals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada

  20. Illinois Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals NA NA NA NA NA NA 1991-2014 From Gas Wells NA NA NA NA NA NA 1991-2014 From Oil Wells NA NA NA NA NA NA 1991-2014 From Shale Gas Wells NA NA NA NA NA NA 2007-2014...

  1. Montana Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals NA NA NA NA NA NA 1991-2014 From Gas Wells NA NA NA NA NA NA 1991-2014 From Oil Wells NA NA NA NA NA NA 1991-2014 From Shale Gas Wells NA NA NA NA NA NA 2007-2014...

  2. Gas Kick Mechanistic Model

    E-Print Network [OSTI]

    Zubairy, Raheel

    2014-04-18T23:59:59.000Z

    -gain and temperature profile in the annulus. This research focuses on these changes in these parameters to be able to detect the occurrence of gas kick and the circulation of the gas kick out from the well. In this thesis, we have developed a model that incorporates...

  3. Fission gas detection system

    DOE Patents [OSTI]

    Colburn, Richard P. (Pasco, WA)

    1985-01-01T23:59:59.000Z

    A device for collecting fission gas released by a failed fuel rod which device uses a filter to pass coolant but which filter blocks fission gas bubbles which cannot pass through the filter due to the surface tension of the bubble.

  4. Western Europe's future gas supplies

    SciTech Connect (OSTI)

    Kardaun, G.

    1983-05-01T23:59:59.000Z

    Decline in indigenous natural gas production by 2000 will be compensated by imported natural gas and LNG and gas from unconventional sources. Coal gas will furnish about 10 percent of the demand, more natural gas imports will come from North Africa and the USSR and additional LNG will come from West Africa, the Middle East and the Western Hemisphere.

  5. Short-range atmospheric dispersion of carbon dioxide

    SciTech Connect (OSTI)

    Cortis, A.; Oldenburg, C.M.

    2009-11-01T23:59:59.000Z

    We present a numerical study aimed at quantifying the effects of concentration-dependent density on the spread of a seeping plume of CO{sub 2} into the atmosphere such as could arise from a leaking geologic carbon sequestration site. Results of numerical models can be used to supplement field monitoring estimates of CO{sub 2} seepage flux by modelling transport and dispersion between the source emission and concentration-measurement points. We focus on modelling CO{sub 2} seepage dispersion over relatively short distances where density effects are likely to be important. We model dense gas dispersion using the steady-state Reynolds-averaged Navier-Stokes equations with density dependence in the gravity term. Results for a two-dimensional system show that a density dependence emerges at higher fluxes than prior estimates. A universal scaling relation is derived that allows estimation of the flux from concentrations measured downwind and vice versa.

  6. Phenomena of oscillations in atmospheric pressure direct current glow discharges

    SciTech Connect (OSTI)

    Liu, Fu-cheng [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)] [College of Physics Science and Technology, Hebei University, Baoding 071002 (China); Yan, Wen; Wang, De-zhen [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-12-15T23:59:59.000Z

    Self-sustained oscillations in a dc glow discharge with a semiconductor layer at atmospheric pressure were investigated by means of a one-dimensional fluid model. It is found that the dc glow discharge initially becomes unstable in the subnormal glow region and gives rise to oscillations of plasma parameters. A variety of oscillations with one or more frequencies have been observed under different conditions. The discharge oscillates between the glow discharge mode and the Townsend discharge mode in the oscillations with large amplitude while operates in the subnormal glow discharge mode all the while in the oscillations with small amplitude. Fourier Transform spectra of oscillations reveal the transition mechanism between different oscillations. The effects of semiconductor conductivity on the oscillation frequency of the dominant mode, gas voltage, as well as the discharge current have also been analyzed.

  7. Gas pump with movable gas pumping panels

    DOE Patents [OSTI]

    Osher, John E. (Alamo, CA)

    1984-01-01T23:59:59.000Z

    Apparatus for pumping gas continuously a plurality of articulated panels of getter material, each of which absorbs gases on one side while another of its sides is simultaneously reactivated in a zone isolated by the panels themselves from a working space being pumped.

  8. Doctoral Programs Atmospheric, Oceanic & Space Sciences

    E-Print Network [OSTI]

    Eustice, Ryan

    University of Michigan Space Research Building 2455 Hayward Street Ann Arbor, MI 48109-2143 aoss Katherine E. White, Ann Arbor ©The Regents of the University of Michigan Research areas Atmospheric Science Atmospheric Dynamics Climate, Climate Modeling & Climate Change Clouds & Precipitation Paleoclimate, Ice

  9. ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2013)

    E-Print Network [OSTI]

    Lee, Sukyoung

    2013-01-01T23:59:59.000Z

    ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2013) Published online in Wiley Online Library Sciences, Seoul National University, Seoul, South Korea *Correspondence to: C. Yoo, Center for Atmosphere). A number of studies have shown that the MJO plays an important role in modulating the extratropical cir

  10. ATOMIC IONIZATION AND OPACITIES IN PULSAR ATMOSPHERES

    E-Print Network [OSTI]

    ATOMIC IONIZATION AND OPACITIES IN PULSAR ATMOSPHERES Hydrogen Atmospheres J. VENTURA Physics.g. Pavlov et al., 1995; Zavlin et al., 1995, 1996; #12; 2 J. VENTURA ET AL. Rajagopal and Romani, 1996 the past three years. As is well known (Canuto and Ventura, 1977; Ruder et al., 1994), the external strong

  11. Shale gas production: potential versus actual greenhouse gas emissions

    E-Print Network [OSTI]

    O’Sullivan, Francis Martin

    Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

  12. Intermountain Gas Company (IGC)- Gas Heating Rebate Program

    Broader source: Energy.gov [DOE]

    The Intermountain Gas Company's (IGC) Gas Heating Rebate Program offers customers a $200 per unit rebate when they convert to a high efficiency natural gas furnace that replaces a heating system...

  13. Peoples Gas and North Shore Gas- Bonus Rebate Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Peoples Gas and North Shore Gas Natural Gas Savings Programs are offering the following bonus rebates (in addition to the joint utilities bonus rebate). For both offers below, installation must...

  14. Underground Storage of Natural Gas and Liquefied Petroleum Gas (Nebraska)

    Broader source: Energy.gov [DOE]

    This statute declares underground storage of natural gas and liquefied petroleum gas to be in the public interest if it promotes the conservation of natural gas and permits the accumulation of...

  15. EIA - Natural Gas Pipeline Network - Natural Gas Supply Basins...

    U.S. Energy Information Administration (EIA) Indexed Site

    Corridors About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates U.S. Natural Gas Supply Basins Relative to Major Natural...

  16. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P. (Bellevue, WA); Novaresi, Mark A. (San Diego, CA); Cornelius, Charles C. (Kirkland, WA)

    2007-11-13T23:59:59.000Z

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  17. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

    2012-04-03T23:59:59.000Z

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  18. Atmospheric neutrino flux calculation using the NRLMSISE00 atmospheric model

    E-Print Network [OSTI]

    Honda, M; Kajita, T; Kasahara, K; Midorikawa, S

    2015-01-01T23:59:59.000Z

    In this paper, we extend the calculation of the atmospheric neutrino flux~\\cite{hkkm2004,hkkms2006,hkkm2011} to the sites in polar and tropical regions. In our earliest full 3D-calculation~\\cite{hkkm2004}, we used DPMJET-III~\\cite{dpm} for the hadronic interaction model above 5~GeV, and NUCRIN~\\cite{nucrin} below 5~GeV. We modified DPMJET-III as in Ref.~\\cite{hkkms2006} to reproduce the experimental muon spectra better, mainly using the data observed by BESS group~\\cite{BESSTeVpHemu}. In a recent work~\\cite{hkkm2011}, we introduced JAM interaction model for the low energy hadronic interactions. JAM is a nuclear interaction model developed with PHITS (Particle and Heavy-Ion Transport code System)~\\cite{phits}. In Ref.~\\cite{hkkm2011}, we could reproduce the observed muon flux at the low energies at balloon altitude with DPMJET-III above 32 GeV and JAM below that better than the combination of DPMJET-III above 5~GeV and NUCRIN below that. Besides the interaction model, we have also improved the calculation sche...

  19. Evolution of gas processing industry in Saudi Arabia

    SciTech Connect (OSTI)

    Showail, A.

    1983-01-01T23:59:59.000Z

    The beginning of the natural gas processing industry in Saudi Arabia is traced back to 1959 when Aramco embarked on a program to recover natural gas liquids (NGL) for export from low pressure gases such as stabilizer overhead, spheroid, tank farm, and refinery off-gases. The processing scheme involves compression and refrigeration to extract C3+ raw NGL, a raw NGL gathering system, and a fractionation plant to separate propane, butane, and natural gasoline. NGL extracted in Abqaiq and Ras Tanura is moved to Ras Tanura for fractionation, storage, and export. The system, built in several increments, has total design capacity of 500 MMscfd of feed gases to produce 320,000 bpd of NGL composed of 40% propane, 30% butane, and 30% natural gasoline. Phase II of the Saudi gas program envisages collection and processing of associated gas produced with Arabian medium and heavy crude oils largely in the northern onshore and offshore fields. Further domestic development may focus on more diversification in gas product utilization and on upgrading to higher value products.

  20. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel Morrison

    2005-09-14T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1, 2005 through June 30, 2005. During this time period efforts were directed toward (1) GSTC administration changes, (2) participating in the American Gas Association Operations Conference and Biennial Exhibition, (3) issuing a Request for Proposals (RFP) for proposal solicitation for funding, and (4) organizing the proposal selection meeting.