Sample records for atmospheric oxygen o2

  1. CO oxidation over Ru(0001) at near-atmospheric pressures: From chemisorbed oxygen to RuO2

    E-Print Network [OSTI]

    Goodman, Wayne

    modulation Infrared reflection absorption spectroscopy Reaction kinetics a b s t r a c t RuO2(110) was formed polarization modulation infrared reflection absorption spectroscopy (PM-IRAS) and post-reaction Auger electronCO oxidation over Ru(0001) at near-atmospheric pressures: From chemisorbed oxygen to RuO2 Feng Gao

  2. Atmospheric Oxygen Binding and Hole Doping in Deformed Graphene on a SiO2 Substrate

    E-Print Network [OSTI]

    Sunmin Ryu; Li Liu; Stephane Berciaud; Young-Jun Yu; Haitao Liu; Philip Kim; George W. Flynn; Louis E. Brus

    2010-11-13T23:59:59.000Z

    Using micro-Raman spectroscopy and scanning tunneling microscopy, we study the relationship between structural distortion and electrical hole doping of graphene on a silicon dioxide substrate. The observed upshift of the Raman G band represents charge doping and not compressive strain. Two independent factors control the doping: (1) the degree of graphene coupling to the substrate, and (2) exposure to oxygen and moisture. Thermal annealing induces a pronounced structural distortion due to close coupling to SiO2 and activates the ability of diatomic oxygen to accept charge from graphene. Gas flow experiments show that dry oxygen reversibly dopes graphene; doping becomes stronger and more irreversible in the presence of moisture and over long periods of time. We propose that oxygen molecular anions are stabilized by water solvation and electrostatic binding to the silicon dioxide surface.

  3. Enhanced oxygen evolution activity of IrO2 and RuO2 (100) surfaces

    SciTech Connect (OSTI)

    Stoerzinger, Kelsey [Massachusetts Institute of Technology (MIT)] [Massachusetts Institute of Technology (MIT); Qiao, Liang [ORNL] [ORNL; Biegalski, Michael D [ORNL] [ORNL; Christen, Hans M [ORNL] [ORNL; Shao-Horn, Yang [Massachusetts Institute of Technology (MIT)] [Massachusetts Institute of Technology (MIT)

    2014-01-01T23:59:59.000Z

    The activities of the oxygen evolution reaction (OER) on IrO2 and RuO2 catalysts are among the highest known to date. However, the intrinsic OER activities of surfaces with defined crystallographic orientations are not well established experimentally. Here we report that the (100) surface of IrO2 and RuO2 is more active than the (110) surface that has been traditionally explored by density functional theory studies. The relation between the OER activity and density of coordinatively undersaturated metal sites exposed on each rutile crystallographic facet is discussed. The surface-orientation dependent activities can guide the design of high-surface-area catalysts with increased activity for electrolyzers, metal-air batteries, and photoelectrochemical water splitting applications.

  4. atmospheric oxygen concentration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: can be combined into a tracer known as atmospheric potential oxygen (APO % O2N2 + CO2) that is conservative with respect to terrestrial biological activity....

  5. Acetone-Assisted Oxygen Vacancy Diffusion on TiO2(110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acetone-Assisted Oxygen Vacancy Diffusion on TiO2(110). Acetone-Assisted Oxygen Vacancy Diffusion on TiO2(110). Abstract: We have studied the dynamic relationship between acetone...

  6. Stability and Migration of Charged Oxygen Interstitials in ThO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen interstitial mobility in ThO2 than in CeO2. Citation: Xiao HY, Y Zhang, and WJ Weber.2013."Stability and Migration of Charged Oxygen Interstitials in ThO2 and CeO2."Acta...

  7. Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 with Oxygen Adatoms on Rutile TiO2(110). Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). Abstract: The interactions of CO2 with oxygen adatoms (Oa’s) on...

  8. Using the Oxygen Plasma Machine 1. Turn on the O2 (g) valve on the wall.

    E-Print Network [OSTI]

    Using the Oxygen Plasma Machine 1. Turn on the O2 (g) valve on the wall. 2. Turn on the O2 inlet valve on the front of the machine just a tiny-bit ­ O2 should now be leaking through the black, chamber-right of the machine), just the Red Power Switch. 6. Turn off the O2 valve on the chamber door. At the same time, turn

  9. Transient Mobility of Oxygen Adatoms upon O2 Dissociation on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    only at the bridging oxygen vacancies, with one O atom healing a vacancy and other O atom bonding at the neighboring Ti site as an adatom. Majority (81%) of O adatoms are found...

  10. 6.11 Atmospheric CO2 and O2 During the Phanerozoic: Tools, Patterns, and Impacts

    E-Print Network [OSTI]

    Royer, Dana

    6.11 Atmospheric CO2 and O2 During the Phanerozoic: Tools, Patterns, and Impacts DL Royer, Wesleyan.11.2 Models for Atmospheric CO2 and O2 Estimation 251 6.11.2.1 Key Principles 251 6.11.2.2 GEOCARB Models 252.11.2.2.5 Estimates of CO2 and O2 from the GEOCARB model 254 6.11.2.3 Other Models for CO2 and O2 Reconstruction 254 6

  11. A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed on MCM-48

    E-Print Network [OSTI]

    Bell, Alexis

    A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed.932), suggesting the formation of oxygen vacancies. The fraction of Ti that could be reduced increased with TiO2 the TiO2 overlayer as the size of the titania patches increases. The amount of oxygen removed during

  12. Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 catalyst Formation, stability and CO

    E-Print Network [OSTI]

    Pfeifer, Holger

    1 Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 are the activation of molecular oxygen, the active site for this reaction step, and the nature of the catalytically active oxygen species present under working conditions.[3;9-15] Stiehl et al. had shown that molecularly

  13. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

  14. Atmospheric O2//N2 changes, 19932002: Implications for the partitioning of fossil fuel CO2 sequestration

    E-Print Network [OSTI]

    Ho, David

    Atmospheric O2//N2 changes, 1993­­2002: Implications for the partitioning of fossil fuel CO2. Cassar (2005), Atmospheric O2/N2 changes, 1993­2002: Implications for the partitioning of fossil fuel CO2. The O2/N2 ratio of air is falling because combustion of fossil fuel and biomass both con- sume O2

  15. atmospheric oxygenation recorded: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cores may contain high quality records of atmospheric deposition. The qualitative Short, Daniel 3 Bistability of atmospheric oxygen and the Great Oxidation Geosciences Websites...

  16. Molecular Beam Scattering of Aligned Oxygen Molecules. The Nature of the Bond in the O2-O2 Dimer

    E-Print Network [OSTI]

    Pirani, Fernando

    . These results indicate that most of the bonding in the dimer comes from van der Waals forces, but chemical (spin that it is not paramagnetic." He also gave a value of 5.60 meV for the heat of dissociation of the O2-O2 dimer. Actually from different spin coupling of the monomers in the ground electronic state. Spin coupling leads

  17. Atmospheric Pressure Chemical Vapor Deposition of High Silica SiO2-TiO2 Antireflective Thin Films for Glass Based Solar Panels

    SciTech Connect (OSTI)

    Klobukowski, Erik R [ORNL; Tenhaeff, Wyatt E [ORNL; McCamy, James [PPG; Harris, Caroline [PPG; Narula, Chaitanya Kumar [ORNL

    2013-01-01T23:59:59.000Z

    The atmospheric pressure chemical vapor deposition (APCVD) of SiO2-TiO2 thin films employing [[(tBuO)3Si]2O-Ti(OiPr)2], which can be prepared from commercially available materials, results in antireflective thin films on float glass under industrially relevant manufacturing conditions. It was found that while the deposition temperature had an effect on the SiO2:TiO2 ratio, the thickness was dependent on the time of deposition. This study shows that it is possible to use APCVD employing a single source precursor containing titanium and silicon to produce thin films on float glass with high SiO2:TiO2 ratios.

  18. Measurements of Atmospheric O2 Variations at the WLEF Tall-tower Site Figure 4. Comparison to

    E-Print Network [OSTI]

    Stephens, Britton B.

    adapted a commercially available fuel-cell detector to make the first atmospheric O2 measurements from. The fuel-cell instrument has successfully measured O2 concentrations at the WLEF tall-tower research site in Environmental Sciences, CU, Boulder, Colorado, 2 NOAA Climate Monitoring and Diagnostics Laboratory, Boulder

  19. Time Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2.5 Brownmillerite Structure: Comparison with the Homologous SrCoO2.5 System

    E-Print Network [OSTI]

    Frenkel, Anatoly

    temperature oxygen ionic conductors are key materials for the development of the next generation solid oxideTime Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2 to reversibly intercalate oxygen in an electrochemical reaction at room temperature to reach SrMO3 stoichiometry

  20. A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature

    E-Print Network [OSTI]

    Cao, Wenwu

    ­18 have been focused on the synthesis of hybrid TiO2/graphene nanocomposites, where high stability and others lack high sensitivity but a high-cost.12 Recently, hybrid of TiO2 with nanoscale carbon materials -bonded carbon atoms,19 has been extensively researched in photovoltaic and photocatalysis hybrid mate

  1. Oxygen vacancies in N doped anatese TiO2: Experiment and first principles calculations

    SciTech Connect (OSTI)

    Rumaiz, A.; Woicik, J.C.; Cockayne, E.; Lin, H.Y.; Hassnain, J.; Shah, S.I.

    2009-12-31T23:59:59.000Z

    We have determined the electronic and atomic structure of N doped TiO{sub 2} using a combination of hard x-ray photoelectron spectroscopy and first-principles density functional theory calculations. Our results reveal that N doping of TiO{sub 2} leads to the formation of oxygen vacancies and the combination of both N impurity and oxygen vacancies accounts for the observed visible light catalytic behavior of N doped TiO{sub 2}.

  2. E-Print Network 3.0 - atmospheric pressure helium-oxygen Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copyright permission to reproduce figures andor text from this article 12;Remote Atmospheric-Pressure... ) were treated with an atmospheric-pressure oxygen and...

  3. Surface core-level shifts at an oxygen-rich Ru surface: O/Ru(0 0 0 1) vs. RuO2(1 1 0)

    E-Print Network [OSTI]

    , morphology, roughness, and topography; Ruthenium; Oxygen; Single crystal surfaces 1. Introduction In additionSurface core-level shifts at an oxygen-rich Ru surface: O/Ru(0 0 0 1) vs. RuO2(1 1 0) Karsten density-functional theory calculations of Ru 3d and O 1s surface core-level shifts (SCLSs) at an oxygen

  4. Atmospheric Pressure Deposition of Fluorinedoped SnO2 Thin Films from Organotin Fluorocarboxylate Precursors. 

    E-Print Network [OSTI]

    Mahon, Mary F; Molloy, Kieran C; Stanley, Joanne E; Rankin, David W H; Robertson, Heather E; Johnston, Blair F

    2005-01-01T23:59:59.000Z

    Nine organotin fluorocarboxylates RnSnO2CRf (n = 3, R = Bu, Rf = CF3, C2F5, C3F7, C7F15; R = Et, Rf = CF3, C2F5; R = Me, Rf = C2F5; n = 2, R =Me, Rf = CF3) have been synthesised; key examples have been used to deposit ...

  5. Plants, Weathering, and the Evolution of Atmospheric Carbon Dioxide and Oxygen

    SciTech Connect (OSTI)

    Berner, Robert A

    2008-02-05T23:59:59.000Z

    Over the past six years we have published 24 papers that can be divided into three sections: (1) Study of plants and weathering, (2) modeling the evolution of atmospheric CO2 over Phanerozoic time (past 550 million years). (3) Modeling of atmospheric O2 over Phanerozoic time. References to papers published acknowledging this grant can be found at the end of this report and almost all are supplied in pdf form. (1) In the temperate forests of the Cascade Mountains, USA, calcium and magnesium meet vastly different fates beneath angiosperms vs gymnosperms. Calcium is leached beneath both groves of trees, but leached 20-40% more beneath the angiosperms. Magnesium is retained in the forest system beneath the angiosperms and leached from beneath the gymnosperms. (2) We have shown that climate and CO2, based on both carbon cycle modeling and hundreds of independent proxies for paleo-CO2, correlate very well over the past 550 million year. In a recent paper we use this correlation to deduce the sensitivity of global mean temperature to a doubling of atmospheric CO2, and results are in excellent agreement with the results of climatologists based on the historical record and on theoretical climate models (GCM’s).(3) We have shown that concentrations of atmospheric oxygen, calculated by a combined carbon-sulfur cycle model, over the past 550 million years have varied with and influenced biological evolution.

  6. Avian embryonic development in a helium-oxygen atmosphere

    E-Print Network [OSTI]

    Miller, David Harrison

    1968-01-01T23:59:59.000Z

    -through of the helium-oxygen mixture or com- pressed breathing air, (Figure 1, 2, and 3). Although the chambers were tightly sealed and a slight pressure inside the chamber showed no leaks when tested with a soapy solution, the interior atmosphere (He-02), became... seal without the use of tape. A slight positive pressure wss maintained inside each chamber and a soapy solution or ~gnoo (manufactured by Nuclear Products Co. , Cleveland, Ohio) was used to test for leaks. The chamber with He-02 was flushed...

  7. Mathematical Analysis of High-Temperature Co-electrolysis of CO2 and O2 Production in a Closed-Loop Atmosphere Revitalization System

    SciTech Connect (OSTI)

    Michael G. McKellar; Manohar S. Sohal; Lila Mulloth; Bernadette Luna; Morgan B. Abney

    2010-03-01T23:59:59.000Z

    NASA has been evaluating two closed-loop atmosphere revitalization architectures based on Sabatier and Bosch carbon dioxide, CO2, reduction technologies. The CO2 and steam, H2O, co-electrolysis process is another option that NASA has investigated. Utilizing recent advances in the fuel cell technology sector, the Idaho National Laboratory, INL, has developed a CO2 and H2O co-electrolysis process to produce oxygen and syngas (carbon monoxide, CO and hydrogen, H2 mixture) for terrestrial (energy production) application. The technology is a combined process that involves steam electrolysis, CO2 electrolysis, and the reverse water gas shift (RWGS) reaction. A number of process models have been developed and analyzed to determine the theoretical power required to recover oxygen, O2, in each case. These models include the current Sabatier and Bosch technologies and combinations of those processes with high-temperature co-electrolysis. The cases of constant CO2 supply and constant O2 production were evaluated. In addition, a process model of the hydrogenation process with co-electrolysis was developed and compared. Sabatier processes require the least amount of energy input per kg of oxygen produced. If co-electrolysis replaces solid polymer electrolyte (SPE) electrolysis within the Sabatier architecture, the power requirement is reduced by over 10%, but only if heat recuperation is used. Sabatier processes, however, require external water to achieve the lower power results. Under conditions of constant incoming carbon dioxide flow, the Sabatier architectures require more power than the other architectures. The Bosch, Boudouard with co-electrolysis, and the hydrogenation with co-electrolysis processes require little or no external water. The Bosch and hydrogenation processes produce water within their reactors, which aids in reducing the power requirement for electrolysis. The Boudouard with co-electrolysis process has a higher electrolysis power requirement because carbon dioxide is split instead of water, which has a lower heat of formation. Hydrogenation with co-electrolysis offers the best overall power performance for two reasons: it requires no external water, and it produces its own water, which reduces the power requirement for co-electrolysis.

  8. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx/CeO2

    SciTech Connect (OSTI)

    Kwak, Ja Hun; Szanyi, Janos

    2014-12-23T23:59:59.000Z

    Pulsing 15N18O onto an annealed 1% Mn16Ox/Ce16O2 catalyst resulted in very fast oxygen isotope exchange and 15N2 formation at 295 K. In the 1st 15N18O pulse, due to the presence of large number of surface oxygen defects, extensive 15N218O and 15N2 formations were observed. In subsequent pulses oxygen isotope exchange dominated as a result of highly labile oxygen in the oxide. We gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy/Vehicle Technologies Program for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

  9. Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps

    E-Print Network [OSTI]

    Bennett, Albert F.

    4111 Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps (Weibel et al., 1981). In mammals, maximal rate of oxygen consumption (VOmax) is not limited by any one step of the oxygen cascade; rather limitations to VOmax are distributed across all steps

  10. JOURNAL OF MATERIALS SCIENCE LETTERS 17 (1998) 20832086 Effect of oxygen plasma treatment on SiO2 aerogel lms

    E-Print Network [OSTI]

    Jo, Moon-Ho

    aerogel ®lms H.-H. PARK, M.-H. JO, H.-R. KIM, S.-H. HYUN Department of Ceramic Engineering, Yonsei with a lower dielectric constant material as an intermetal dielectric (IMD). SiO2 aerogel is a promising aerogel ®lm with 70% porosity exhibited the static dielectric constant of 2 at 1 MHz, and a leakage

  11. The effect of bed temperature on oxygen partial pressures in an atmospheric fluidized bed combustor

    SciTech Connect (OSTI)

    Malik, S.R. [PCSIR, Karachi (Pakistan). Fuel Research Centre; Gibbs, B.M. [Univ. of Leeds (United Kingdom). Dept. of Fuel and Energy

    1996-12-31T23:59:59.000Z

    One of the factors which cause corrosion of in-bed material is the existence of low oxygen levels. Therefore, oxygen`s partial pressure measurements are important for corrosion studies in atmospheric fluidized bed combustor (AFBC). The effect of bed temperature on oxygen levels has been discussed in this paper. The experiments were conducted on a 0.3 meters square combustor. In-bed oxygen partial pressures were measured using zirconia oxygen probes and recorded on a computerized data logging system. Detail statistical analysis of the data has been presented. The probability density function (PDF) was the most important statistical parameter which reveals not only how long environment is exposed to oxidizing reducing conditions but also the probability whether corrosion could occur.

  12. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeeding access toTest andOptimize carbonOtherdefault Sign InOverviewOxygen

  13. Atmospheric pressure intercalation of oxygen via wrinkles between graphene and a metal

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Atmospheric pressure intercalation of oxygen via wrinkles between graphene and a metal Amina with graphene, an atomically thin sheet of carbon atoms in a honeycomb lattice. These prospects are urging, has reached such maturity that graphene now appears as an alternative to indium tin oxide

  14. Deposition of TiO2 thin films by atmospheric plasma post-discharge assisted injection MOCVD

    E-Print Network [OSTI]

    Boyer, Edmond

    -discharge is sent away from electrodes confinement [3]. In this work, we have combined these two systems working combines remote Atmospheric Pressure (AP) Plasma with Pulsed Injection Metallorganic Chemical Vapour developed Pulsed Injection MOCVD [1] method, based on a liquid delivery system controlled by a high speed

  15. The effect of a helium-oxygen atmosphere on chick embryo development and subsequent chick performance

    E-Print Network [OSTI]

    Valera, Juan

    1969-01-01T23:59:59.000Z

    !ie hc I ium-oxygen groups r ere stroller t!ian embryos from the air group after 12 and 16 darys of development. The util is- tion of yolt& and al!'umen by the helium-oxygen etibryos during incu!ration r;as less than for the air grou... and reorod. ctive performance of chicks hatched in a helium- omycen atmosphere showed es -entially no differences when compared with c!sicks of the same ape hatched in the a ir chambers. physiolosical seasure. cnts, body weights, heso, lobin, hemntocr its...

  16. Fractal and Multifractal Analysis of the Rise of Oxygen in Earth's Early Atmosphere

    E-Print Network [OSTI]

    Satish Kumar; Manfred Cuntz; Zdzislaw E. Musielak

    2014-12-16T23:59:59.000Z

    The rise of oxygen in Earth's atmosphere that occurred 2.4 to 2.2 billion years ago is known as the Earth's Great Oxidation, and its impact on the development of life on Earth has been profound. Thereafter, the increase in Earth's oxygen level persisted, though at a more gradual pace. The proposed underlying mathematical models for these processes are based on physical parameters whose values are currently not well-established owing to uncertainties in geological and biological data. In this paper, a previously developed model of Earth's atmosphere is modified by adding different strengths of noise to account for the parameters' uncertainties. The effects of the noise on the time variations of oxygen, carbon and methane for the early Earth are investigated by using fractal and multifractal analysis. We show that the time variations following the Great Oxidation cannot properly be described by a single fractal dimension because they exhibit multifractal characteristics. The obtained results demonstrate that the time series as obtained exhibit multifractality caused by long-range time correlations.

  17. Fractal and Multifractal Analysis of the Rise of Oxygen in Earth's Early Atmosphere

    E-Print Network [OSTI]

    Satish Kumar; Manfred Cuntz; Zdzislaw E. Musielak

    2015-06-09T23:59:59.000Z

    The rise of oxygen in Earth's atmosphere that occurred 2.4 to 2.2 billion years ago is known as the Earth's Great Oxidation, and its impact on the development of life on Earth has been profound. Thereafter, the increase in Earth's oxygen level persisted, though at a more gradual pace. The proposed underlying mathematical models for these processes are based on physical parameters whose values are currently not well-established owing to uncertainties in geological and biological data. In this paper, a previously developed model of Earth's atmosphere is modified by adding different strengths of noise to account for the parameters' uncertainties. The effects of the noise on the time variations of oxygen, carbon and methane for the early Earth are investigated by using fractal and multifractal analysis. We show that the time variations following the Great Oxidation cannot properly be described by a single fractal dimension because they exhibit multifractal characteristics. The obtained results demonstrate that the time series as obtained exhibit multifractality caused by long-range time correlations.

  18. Standard Test Method for Determination of Uranium, Oxygen to Uranium (O/U), and Oxygen to Metal (O/M) in Sintered Uranium Dioxide and Gadolinia-Uranium Dioxide Pellets by Atmospheric Equilibration

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2007-01-01T23:59:59.000Z

    Standard Test Method for Determination of Uranium, Oxygen to Uranium (O/U), and Oxygen to Metal (O/M) in Sintered Uranium Dioxide and Gadolinia-Uranium Dioxide Pellets by Atmospheric Equilibration

  19. Soot formation in laminar premixed methane/oxygen flames at atmospheric pressure

    SciTech Connect (OSTI)

    Xu, F.; Lin, K.C.; Faeth, G.M. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Aerospace Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Aerospace Engineering

    1998-10-01T23:59:59.000Z

    Flame structure and soot formation were studied within soot-containing laminar premixed methane/oxygen flames at atmospheric pressure. The following measurements were made: soot volume fractions by laser extinction, soot temperatures by multiline emission, gas temperatures (where soot was absent) by corrected fine-wire thermocouples, soot structure by thermophoretic sampling and transmission electron microscope (TEM), major gas species concentrations by sampling and gas chromatography, and gas velocities by laser velocimetry. Present measurements of gas species concentrations were in reasonably good agreement with earlier measurements due to Ramer et al. as well as predictions based on the detailed mechanisms of Frenklach and co-workers and Leung and Lindstedt; the predictions also suggest that H atom concentrations are in local thermodynamic equilibrium throughout the soot formation region. Using this information, it was found that measured soot surface growth rates could be correlated successfully by predictions based on the hydrogen-abstraction/carbon-addition (HACA) mechanisms of both Frenklach and co-workers and Colket and Hall, extending an earlier assessment of these mechanisms for premixed ethylene/air flames to conditions having larger H/C ratios and acetylene concentrations. Measured primary soot particle nucleation rates were somewhat lower than the earlier observations for laminar premixed ethylene/air flames and were significantly lower than corresponding rates in laminar diffusion flames, for reasons that still must be explained.

  20. A dominant role of oxygen additive on cold atmospheric-pressure He + O{sub 2} plasmas

    SciTech Connect (OSTI)

    Yang, Aijun; Liu, Dingxin, E-mail: liudingxin@gmail.com, E-mail: xhw@mail.xjtu.edu.cn; Rong, Mingzhe; Wang, Xiaohua, E-mail: liudingxin@gmail.com, E-mail: xhw@mail.xjtu.edu.cn [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049 (China); Kong, Michael G. [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049 (China); Frank Reidy Research Center for Bioelectrics, Old Dominion University, Norfolk, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2014-08-15T23:59:59.000Z

    We present in this paper how oxygen additive impacts on the cold atmospheric-pressure helium plasmas by means of a one-dimensional fluid model. For the oxygen concentration [O{sub 2}]?>??0.1%, the influence of oxygen on the electron characteristics and the power dissipation becomes important, e.g., the electron density, the electron temperature in sheath, the electron-coupling power, and the sheath width decreasing by 1.6 to 16 folds with a two-log increase in [O{sub 2}] from 0.1% to 10%. Also the discharge mode evolves from the ? mode to the ? mode. The reactive oxygen species are found to peak in the narrow range of [O{sub 2}]?=?0.4%–0.9% in the plasmas, similar to their power-coupling values. This applies to their wall fluxes except for those of O* and O{sub 2}{sup ?}. These two species have very short lifetimes, thus only when generated in boundary layers within several micrometers next to the electrode can contribute to the fluxes. The dominant reactive oxygen species and the corresponding main reactions are schematically presented, and their relations are quantified for selected applications.

  1. Separation of VUV/UV photons and reactive particles in the effluent of a He/O2 atmospheric pressure plasma jet

    E-Print Network [OSTI]

    Schneider, S; Narberhaus, F; Bandow, J E; Denis, B; Benedikt, J

    2011-01-01T23:59:59.000Z

    Cold atmospheric pressure plasmas can be used for treatment of living tissues or for inactivation of bacteria or biological macromolecules. The treatment is usually characterized by a combined effect of UV and VUV radiation, reactive species, and ions. This combination is usually beneficial for the effectiveness of the treatment but it makes the study of fundamental interaction mechanisms very difficult. Here we report on an effective separation of VUV/UV photons and heavy reactive species in the effluent of a micro scale atmospheric pressure plasma jet ($\\mu$-APPJ). The separation is realized by an additional flow of helium gas under well-defined flow conditions, which deflects heavy particles in the effluent without affecting the VUV and UV photons. Both components of the effluent, the photons and the reactive species, can be used separately or in combination for sample treatment. The results of treatment of a model plasma polymer film and vegetative Bacillus subtilis and Escherichia coli cells are shown an...

  2. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking....

  3. Electron- and hole-mediated reactions in UV -irradiated O2 adsorbed...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O2 adsorbed on reduced rutile TiO2(110). Abstract: The photon-stimulated reactions in oxygen adsorbed on reduced TiO2(110) at low temperatures (< 100 K) are studied. The amount...

  4. Failure analysis of an {alpha}-SiC tube subjected to thermal cycling in an oxygen-steam atmosphere

    SciTech Connect (OSTI)

    Breder, K.; Keiser, J.R.

    1995-12-31T23:59:59.000Z

    Failure analysis of a 0.965 m long closed end {alpha}-SiC tube which failed during thermal cycling in an oxygen-steam atmosphere was conducted. The tube failed during heating after having survived several cycles. The shattered tube was re-assembled and the fracture origin was determined to be a flaw in the lower part of the tube on the outer surface. The flaw was likely an oxidation pit produced during the previous cycles. The stresses in the tube at the time of failure were a combination of stresses from the internal pressure and from thermal gradients.

  5. Analysis of the atmospheric distribution, sources, and sinks of oxygenated volatile organic chemicals based on

    E-Print Network [OSTI]

    Jacob, Daniel J.

    chemicals based on measurements over the Pacific during TRACE-P H. B. Singh,1 L. J. Salas,1 R. B. Chatfield measurements of a large number of oxygenated volatile organic chemicals (OVOC) were carried out in the Pacific of OVOC is comparable to that of methane and far exceeds that of NMHC. A comparison of these data

  6. oxygen-plasma | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen-plasma oxygen-plasma Leads No leads are available at this time. Conversion of 1,2-Propylene Glycol on Rutile TiO2(110). Abstract: We have studied the reactions of...

  7. Commercial demonstration of atmospheric medium BTU fuel gas production from biomass without oxygen the Burlington, Vermont Project

    SciTech Connect (OSTI)

    Rohrer, J.W. [Zurn/NEPCO, South Portland, MA (United States); Paisley, M. [Battelle Laboratories, Columbus, OH (United States)

    1995-12-31T23:59:59.000Z

    The first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification of biomass occurred at Battelle Columbus Labs (BCL) during 1994 using their high throughput indirect medium Btu gasification Process Research Unit (PRU). Zurn/NEPCO was retained to build a commercial scale gas plant utilizing this technology. This plant will have a throughput rating of 8 to 12 dry tons per hour. During a subsequent phase of the Burlington project, this fuel gas will be utilized in a commercial scale gas turbine. It is felt that this process holds unique promise for economically converting a wide variety of biomass feedstocks efficiently into both a medium Btu (500 Btu/scf) gas turbine and IC engine quality fuel gas that can be burned in engines without modification, derating or efficiency loss. Others are currently demonstrating sub-commercial scale thermal biomass gasification processes for turbine gas, utilizing both atmospheric and pressurized air and oxygen-blown fluid bed processes. While some of these approaches hold merit for coal, there is significant question as to whether they will prove economically viable in biomass facilities which are typically scale limited by fuel availability and transportation logistics below 60 MW. Atmospheric air-blown technologies suffer from large sensible heat loss, high gas volume and cleaning cost, huge gas compressor power consumption and engine deratings. Pressurized units and/or oxygen-blown gas plants are extremely expensive for plant scales below 250 MW. The FERCO/BCL process shows great promise for overcoming the above limitations by utilizing an extremely high throughout circulation fluid bed (CFB) gasifier, in which biomass is fully devolitalized with hot sand from a CFB char combustor. The fuel gas can be cooled and cleaned by a conventional scrubbing system. Fuel gas compressor power consumption is reduced 3 to 4 fold verses low Btu biomass gas.

  8. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte

    SciTech Connect (OSTI)

    Xiao, Jie; Hu, Jian Z.; Wang, Deyu; Hu, Dehong; Xu, Wu; Graff, Gordon L.; Nie, Zimin; Liu, Jun; Zhang, Jiguang

    2011-07-01T23:59:59.000Z

    In order to understand the nature of the limited cycle life and poor energy efficiency associated with the secondary Li-O¬2 batteries the discharge products of primary Li-O2 cells at different depth of discharge (DOD) are systematically analyzed in this work. It is revealed that if discharged to 2.0 V a small amount of Li2O2 coexist with Li2CO3 and RO-(C=O)-OLi) in alkyl carbonate-based electrolyte. Further discharging the air electrodes to below 2.0 V the amount of Li2CO3 and LiRCO3 increases significantly due to the severe electrolyte decomposition. There is no Li2O detected in this alkyl carbonate electrolyte regardless of DOD. It is also found that the alkyl carbonate based electrolyte begins to decompose at 4.0 V during charging under the combined influences from the high surface area carbon, the nickel metal current collector and the oxygen atmosphere. Accordingly the impedance of the Li-O2 cell continues to increase after each discharge and recharge process indicating a repeated plating of insoluble lithium salts on the carbon surface. Therefore the whole carbon electrode becomes completely insulated only after a few cycles and loses the function of providing active tri-phase regions for the Li-oxygen batteries.

  9. Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

  10. Measurement of positive gain on the 1315 nm transition of atomic iodine pumped by O2,,a1

    E-Print Network [OSTI]

    Carroll, David L.

    state I 2 P3/2 . Conventionally, the O2 1 is produced by a liquid chemistry singlet oxygen generator of gain. © 2004 American Institute of Physics. [DOI: 10.1063/1.1784519] The classic chemical oxygen the metastable excited singlet oxygen molecule, O2 a1 [de- noted O2 1 hereafter], and the iodine atom ground

  11. Investigation of the Production of O2(a1 ) in Rectangular

    E-Print Network [OSTI]

    Carroll, David L.

    is not simply a flow consisting primarily of O2(a) and O2(X) (as in classic COIL singlet-oxygen generation Oxygen- Iodine Laser (ElectricOIL) system. This continuous wave (cw) laser operating on the 1315 nm-section and multi-circular tube discharges. I. Introduction The electrically driven oxygen-iodine laser (Electric

  12. Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on bridge-bonded oxygen vacancies of TiO2(110) (1×1) surface...

  13. Chemical Reactivity of Reduced TiO2(110): The dominant role of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

  14. Dynamic light scattering in sooting premixed atmospheric-pressure methane-, propane-, ethene-, and propene-oxygen flames

    SciTech Connect (OSTI)

    Lamprecht, A.; Eimer, W.; Kohse-Hoeinghaus, K. [Univ. Bielefeld (Germany)] [Univ. Bielefeld (Germany)

    1999-07-01T23:59:59.000Z

    In a systematic investigation under well-defined flame conditions, dynamic light scattering (DLS) was applied to the determination of soot particle radii with the aim of examining the suitability of this technique for accurate soot particle sizing. In particular, flat premixed methane-, propane-, ethene-, and propene-oxygen flames at atmospheric pressure were investigated, and particle sizes were obtained as a function of stoichiometry and height above the burner surface. In combination with absorption measurements, soot volume fraction and particle number density were determined; also, the temperature was measured at each flame condition. In comparison to absorption techniques, attractive features of DLS are its independence of the particle refractive index and its insensitivity to fluorescence interference; also, it offers spatial resolution. In principle, additional information on the particle size distribution as well as on the global shape of the particles may be obtained from DLS experiments. This study is therefore an evaluation of the potential of DLS as a complement to other soot diagnostic techniques.

  15. Preparation and electrochemical/thermal properties of LiNi0.74Co0.26O2 cathode material

    E-Print Network [OSTI]

    Park, Byungwoo

    oxygen as a result of decomposition into MxOy (MCo or Mn) and O2. The LiNiO2 phase also shows a lower

  16. Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4

    E-Print Network [OSTI]

    Bazant, Martin Z.

    Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4 Betar continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory

  17. Optical emission spectroscopic diagnostics of a non-thermal atmospheric pressure helium-oxygen plasma jet for biomedical applications

    SciTech Connect (OSTI)

    Thiyagarajan, Magesh; Sarani, Abdollah; Nicula, Cosmina [Plasma Engineering Research Laboratory (PERL), College of Science and Engineering, Texas A and M University-Corpus Christi, Texas 78412 (United States)] [Plasma Engineering Research Laboratory (PERL), College of Science and Engineering, Texas A and M University-Corpus Christi, Texas 78412 (United States)

    2013-06-21T23:59:59.000Z

    In this work, we have applied optical emission spectroscopy diagnostics to investigate the characteristics of a non-thermal atmospheric pressure helium plasma jet. The discharge characteristics in the active and afterglow region of the plasma jet, that are critical for biomedical applications, have been investigated. The voltage-current characteristics of the plasma discharge were analyzed and the average plasma power was measured to be around 18 W. The effect of addition of small fractions of oxygen at 0.1%-0.5% on the plasma jet characteristics was studied. The addition of oxygen resulted in a decrease in plasma plume length due to the electronegativity property of oxygen. Atomic and molecular lines of selected reactive plasma species that are considered to be useful to induce biochemical reactions such as OH transitions A{sup 2}{Sigma}{sup +}({nu}=0,1){yields}X{sup 2}{Pi}({Delta}{nu}=0) at 308 nm and A{sup 2}{Sigma}{sup +}({nu}=0,1){yields}X{sup 2}{Pi}({Delta}{nu}=1) at 287 nm, O I transitions 3p{sup 5}P{yields}3s{sup 5}S{sup 0} at 777.41 nm, and 3p{sup 3}P{yields}3s{sup 3}S{sup 0} at 844.6 nm, N{sub 2}(C-B) second positive system with electronic transition C{sup 3}{Pi}{sub u}{sup {yields}}B{sup 3}{Pi}{sub g}'' in the range of 300-450 nm and N{sub 2}{sup +}(B-X) first negative system with electronic transition B{sup 2}{Sigma}{sub u}{sup +}{yields}X{sup 2}{Sigma}{sub g}{sup +}({Delta}{nu}=0) at 391.4 nm have been studied. The atomic emission lines of helium were identified, including the He I transitions 3p{sup 3}P{sup 0}{yields}2s{sup 3}S at 388.8 nm, 3p{sup 1}P{sup 0}{yields} 2s{sup 1}S at 501.6 nm, 3d{sup 3}D{yields}2p{sup 3}P{sup 0} at 587.6 nm, 3d{sup 1}D{yields}2p{sup 1}P{sup 0} at 667.8 nm, 3s{sup 3}S{sup 1}{yields}2p{sup 3}P{sup 0} at 706.5 nm, 3s{sup 1}S{sup 0}{yields}2p{sup 1}P{sup 0} at 728.1 nm, and H{sub {alpha}} transition 2p-3d at 656.3 nm. Using a spectral fitting method, the OH radicals at 306-312 nm, the rotational and vibrational temperatures equivalent to gas temperatures of the discharge was measured and the effective non-equilibrium nature of the plasma jet was demonstrated. Our results show that, in the entire active plasma region, the gas temperature remains at 310 {+-} 25 K and 340 {+-} 25 K and it increases to 320 {+-} 25 K and 360 {+-} 25 K in the afterglow region of the plasma jet for pure helium and helium/oxygen (0.1%) mixture, respectively. Additionally, the vibrational temperatures range from 2200 {+-} 100 K and 2500 {+-} 100 K for pure helium and helium/oxygen (0.1%) mixture, respectively. The plasma jet was tested on heat sensitive polymer films used in biomedical applications such as polyethylene terephthalate and poly-L-lactide samples continuously for several minutes without causing any physical or thermal damage to the films. The plasma jet produces significant reactive species of interest while the gas temperatures remain very low demonstrating its potential for a range of biomedical applications.

  18. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30T23:59:59.000Z

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  19. EMSL - oxygen-plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen-plasma en Conversion of 1,2-Propylene Glycol on Rutile TiO2(110). http:www.emsl.pnl.govemslwebpublicationsconversion-12-propylene-glycol-rutile-tio2110

  20. Atmospheric Pressure Humid Argon DBD Plasma for the Application of Sterilization -Measurement and Simulation of Hydrogen, Oxygen, and Hydrogen

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and Simulation of Hydrogen, Oxygen, and Hydrogen Peroxide Formation M.J. Kirkpatrick, B. Dodet, E. Odic Département Energie - Supélec, F-91192 Gif-sur-Yvette cedex, France AbstractHydrogen, oxygen, and hydrogen. The yield of the three species was studied as a function of the discharge power and gas flow rate. Hydrogen

  1. Three-dimensional hydrodynamical CO5BOLD model atmospheres of red giant stars. IV. Oxygen diagnostics in extremely metal-poor red giants with infrared OH lines

    E-Print Network [OSTI]

    Dobrovolskas, V; Bonifacio, P; Caffau, E; Ludwig, H -G; Steffen, M; Spite, M

    2015-01-01T23:59:59.000Z

    Context. Although oxygen is an important tracer of Galactic chemical evolution, measurements of its abundance in the atmospheres of the oldest Galactic stars are still scarce and rather imprecise. At the lowest end of the metallicity scale, oxygen can only be measured in giant stars and in most of cases such measurements rely on a single forbidden [O I] 630 nm line that is very weak and frequently blended with telluric lines. Although molecular OH lines located in the ultraviolet and infrared could also be used for the diagnostics, oxygen abundances obtained from the OH lines and the [O I] 630 nm line are usually discrepant to a level of ~0.3-0.4 dex. Aims. We study the influence of convection on the formation of the infrared (IR) OH lines and the forbidden [O I] 630 nm line in the atmospheres of extremely metal-poor (EMP) red giant stars. Methods. We used high-resolution and high signal-to-noise ratio spectra of four EMP red giant stars obtained with the VLT CRIRES spectrograph. For each EMP star, 4-14 IR OH...

  2. Rate-dependent morphology of Li2O2 growth in Li-O2 batteries

    E-Print Network [OSTI]

    Horstmann, B; Mitchell, R; Bessler, W G; Shao-Horn, Y; Bazant, M Z

    2013-01-01T23:59:59.000Z

    Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter we develop a nanoscale continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes, based on a theory of electrochemical non-equilibrium thermodynamics originally applied to Li-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory predicts a transition from complex to uniform morphologies of Li2O2 with increasing current. Discrete particle growth at low discharge rates becomes suppressed at high rates, resulting in a film of electronically insulating Li2O2 that limits cell performance. We predict that the transition between these surface growth modes occurs at current densities close to the exchange current density of the cathode reaction, consistent with experimental observations.

  3. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

  4. Inhibitive Influence of Oxygen Vacancies for Photoactivity on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Abstract: Scanning tunneling...

  5. Absolute atomic oxygen and nitrogen densities in radio-frequency driven atmospheric pressure cold plasmas: Synchrotron vacuum ultra-violet high-resolution Fourier-transform absorption measurements

    SciTech Connect (OSTI)

    Niemi, K.; O'Connell, D.; Gans, T. [York Plasma Institute, Department of Physics, University of York, York YO10 5DD (United Kingdom); Oliveira, N. de; Joyeux, D.; Nahon, L. [Synchrotron Soleil, l'Orme des Merisiers, St. Aubin BP 48, 91192 Gif sur Yvette Cedex (France); Booth, J. P. [Laboratoire de Physique des Plasmas-CNRS, Ecole Polytechnique, 91128 Palaiseau (France)

    2013-07-15T23:59:59.000Z

    Reactive atomic species play a key role in emerging cold atmospheric pressure plasma applications, in particular, in plasma medicine. Absolute densities of atomic oxygen and atomic nitrogen were measured in a radio-frequency driven non-equilibrium plasma operated at atmospheric pressure using vacuum ultra-violet (VUV) absorption spectroscopy. The experiment was conducted on the DESIRS synchrotron beamline using a unique VUV Fourier-transform spectrometer. Measurements were carried out in plasmas operated in helium with air-like N{sub 2}/O{sub 2} (4:1) admixtures. A maximum in the O-atom concentration of (9.1 {+-} 0.7) Multiplication-Sign 10{sup 20} m{sup -3} was found at admixtures of 0.35 vol. %, while the N-atom concentration exhibits a maximum of (5.7 {+-} 0.4) Multiplication-Sign 10{sup 19} m{sup -3} at 0.1 vol. %.

  6. Imaging Oxygen Molecules Up Close | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging Oxygen Molecules Up Close Imaging Oxygen Molecules Up Close Released: March 20, 2011 ARRA-enabled upgrades enhance research capabilities STM images of the same TiO2(110)...

  7. Solid-to-solid phase transformations of nanostructured selenium-tin thin films induced by thermal annealing in oxygen atmosphere

    SciTech Connect (OSTI)

    Serra, A. [Physics Applied to Material Science interdepartmental Laboratory (PAMS-Lab) - Dipartimento di Beni Culturali - Università del Salento - Lecce (Italy); Rossi, M. [Dipartimento Scienze di Base ed Applicate all'Ingegneria, and CNIS - Sapienza Università di Roma, Roma (Italy); Buccolieri, A.; Manno, D. [Physics Applied to Material Science interdepartmental Laboratory (PAMS-Lab) - Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali - Università del Salento - Lecce (Italy)

    2014-06-19T23:59:59.000Z

    The structural and morphological evolution of nanostructured thin films obtained from thermal evaporation of polycrystalline Sn-Se starting charge as a function of the subsequent annealing temperature in an oxygen flow has been analysed. High-resolution transmission electron microscopy, small area electron diffraction, digital image processing, x-ray diffraction and Raman spectroscopy have been employed in order to investigate the structure and the morphology of the obtained films. The results evidenced, in the temperature range from RT to 500°C, the transition of the material from a homogeneous mixture of SnSe and SnSe{sub 2} nanocrystals, towards a homogeneous mixture of SnO{sub 2} and SeO{sub 2} nanocrystals, with an intermediate stage in which only SnSe{sub 2} nanocrystals are present.

  8. Rhodium Catalysts in the Oxidation of CO by O2 and NO: Shape, Composition, and Hot Electron Generation

    E-Print Network [OSTI]

    Renzas, James R.

    2010-01-01T23:59:59.000Z

    the manifold was filled with 40 Torr CO (Praxair, UHP), 100Torr O 2 (Praxair, UHP), and abalance of He (Praxair, UHP) initially at atmospheric

  9. Formation of O Adatom Pairs and Charge Transfer upon O-2 Dissociation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    details of O2 dissociation leading to the formation of oxygen adatom (Oa) pairs at terminal Ti sites. An intermediate, metastable Oa-Oa configuration with two nearest-neighbor O...

  10. Reactive Ballistic Deposition of Porous TiO2 Films: Growth and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    high-surface area films of TiO2 are synthesized by reactive ballistic deposition of titanium metal in an oxygen ambient. Auger electron spectroscopy (AES) is used to investigate...

  11. Adsorption of water on O(2x2)/Ru(0001): thermal stability and inhibition of dissociation by H2O-O bonding

    E-Print Network [OSTI]

    Mugarza, Aitor

    2009-01-01T23:59:59.000Z

    Adsorption of water on O(2x2)/Ru(0001): thermal stabilitySaitama 351-0198, Japan. Adsorption of water on O(2x2)/Ru(oxygen on the subsequent adsorption and reactions of water

  12. Effects of CeO2 Support Facets on VOx/CeO2 Catalysts in Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Gao, Feng; Kovarik, Libor; Peden, Charles HF; Wang, Yong

    2014-05-13T23:59:59.000Z

    CeO2 supports with dominating facets, i.e., low index (100), (110) and (111) facets, are prepared. The facet effects on the structure and catalytic performance of supported vanadium oxide catalysts are investigated using oxidative dehydrogenation of methanol as a model reaction. In the presence of mixed facets, Infrared and Raman characterizations demonstrate that surface vanadia species preferentially deposit on CeO2 (100) facets, presumably because of its higher surface energy. At the same surface vanadium densities, VOx species on (100) facets show better dispersion, followed by (110) and (111) facets. The VOx species on CeO2 nanorods with (110) and (100) facets display higher activity and lower apparent activation energies compared to that on CeO2 nanopolyhedras with dominating (111) facets and CeO2 nanocubes with dominating (100) facets. The higher activity for VOx/CeO2(110) might be related to the more abundant oxygen vacancies present on the (110) facets, evidenced from Raman spectroscopic measurements.

  13. Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$

    E-Print Network [OSTI]

    Santilli, R M

    2000-01-01T23:59:59.000Z

    We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capaciti...

  14. Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter

    SciTech Connect (OSTI)

    Davidson, Stephen; Sun, Junming; Wang, Yong

    2013-12-02T23:59:59.000Z

    A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

  15. Continuous-wave laser oscillation on the 1315 nm transition of atomic iodine pumped by O2,,a1

    E-Print Network [OSTI]

    Carroll, David L.

    oxygen generator. There are many system issues having to do with weight, safety, and the ability.1063/1.1883317 The classic chemical oxygen-iodine laser COIL system1 operates on the I 2 P1/2 I 2 P3/2 electronic transi transfer between the metastable excited singlet oxygen molecule, O2 a1 de- noted as O2 1 hereafter

  16. CO Oxidation at the Interface of Au Nanoclusters and the Stepped-CeO2(111) Surface

    SciTech Connect (OSTI)

    Kim H. Y.; Henkelman, G.

    2013-01-14T23:59:59.000Z

    To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters NCs)/Nanoparticles, we design a Au12 supported on a stepped-CeO2 model (Au/CeO2-step) and study various kinds of CO oxidation mechanisms at the interface of the Au/CeO2-step: oxygen spillover from the CeO2 to the Au NCs;2 CO oxidation by the O2 bound to the Au-Ce3+ interface;3 and CO oxidation by the Mars-van Krevelen (M-vK) mechanism.4 DFT+U calculations show that lattice oxygen at the CeO2 step edge oxidizes CO bound to Au NCs by the M-vK mechanism. CO2 desorption determines the rate of CO oxidation and the vacancy formation energy (Evac) is a reactivity descriptor for CO oxidation. The maximum Evac that insures spontaneous CO2 production is higher for the Au/CeO2-step than the Au/CeO2-surface suggesting that the CeO2-step is a better supporting material than the CeO2-surface for CO oxidation by the Au/CeO2. Our results also suggest that for CO oxidation by Au NCs supported on nano- or meso-structured CeO2, which is the case of industrial catalysts, the M-vK mechanism accounts for a large portion of the total activity.

  17. Density functional theory study of first-layer adsorption of ZrO2 and HfO2 on Ge(100)

    E-Print Network [OSTI]

    Kummel, Andrew C.

    Density functional theory study of first-layer adsorption of ZrO2 and HfO2 on Ge(100) T.J. Grassman on the Ge(100)-4 Â 2 surface. Surface binding geometries of metal-down (O­M­Ge) and oxygen-down (M­ O­Ge) were considered, including both adsorbate and displacement geometries of M­O­Ge. Calculated enthalpies

  18. Imaging Consecutive Steps of O2 Reaction with Hydroxylated TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Steps of O2 Reaction with Hydroxylated TiO2(110): Identification of HO2 and Terminal OH Intermediates. Imaging Consecutive Steps of O2 Reaction with Hydroxylated...

  19. Non-linear response of carbon dioxide and methane emissions to oxygen availability in a drained histosol

    E-Print Network [OSTI]

    McNicol, Gavin; Silver, Whendee L

    2015-01-01T23:59:59.000Z

    emissions to oxygen availability in a drained HistosolIncreased O 2 availability from wetland drainage and climateunder greater O 2 availability. We varied gas-phase O 2

  20. In vivo blood oxygenation level measurements using photoacoustic microscopy

    E-Print Network [OSTI]

    Sivaramakrishnan, Mathangi

    2007-09-17T23:59:59.000Z

    in absorption spectra of oxygenated (HbO 2 ) and deoxygenated hemoglobin (Hb) is exploited to yield oxygenation level information. This method consists of using Light Emitting Diodes (LEDs) as light sources to deliver light of known intensity and wavelength...

  1. Variation of corrosion behaviour of candidate heat exchanger alloys with local oxygen partial pressure in a 0. 6 meter diameter AFBC. [Atmospheric fluidized bed combustor

    SciTech Connect (OSTI)

    Rocazella, M.A.; Wright, I.G.

    1983-08-01T23:59:59.000Z

    The investigation reported in this article was aimed at characterising the types of corrosive environments encountered in AFBC by monitoring oxygen partial pressure at exposure locations, and correlating the corrosion behaviour of exposed alloys with the local oxygen partial pressure measurements.

  2. MODELING THE GENERATION AND DISSOCIATION OF THE BORON-OXYGEN COMPLEX IN B-DOPED CZ-SI

    E-Print Network [OSTI]

    MODELING THE GENERATION AND DISSOCIATION OF THE BORON-OXYGEN COMPLEX IN B-DOPED CZ-SI Bianca Lim Emmerthal, Germany ABSTRACT We demonstrate that the boron-oxygen (BsO2i) re- combination center responsible of this complex with the oxygen dimer O2i into XO2i, thereby reducing the concen- tration of unbound O2i

  3. trans-K3[TcO2(CN)4

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Edwards, Matthew K.; Twamley, Brendan; Krause, Jeanette A.; Bryan, Samuel A.

    2010-07-14T23:59:59.000Z

    The dioxotetracyanotechnetate anion, [TcO2(CN)4]3-, of the title complex has octahedral symmetry. The technetium is located on a center of inversion and is bound by two oxygen atoms and four cyano ligands. The Tc?O bond distance of 1.7721 (12) Å is consistent with double bond character. The potassium cations [located on special (1/2,0,1) and general positions] reside in octahedral or tetrahedral environments; interionic K···O and K···N interactions occur in the 2.7877 (19)-2.8598 (15) Å range.

  4. Deposition of TiO2 thin films using RF magnetron sputtering method and study of their surface characteristics

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    , Sungkyunkwan University, Suwon 440-746, South Korea Available online 27 October 2004 Abstract Titanium dioxide Titanium dioxide (TiO2) has many excellent physical pro- perties such as a high dielectric constant films such as TiO2 and TiN. Generally, high flows of the reactive gases such as oxygen and nitrogen

  5. Sandia National Laboratories: TiO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News & Events, Photovoltaic, Research & Capabilities, Solar, Solid-State Lighting Titanium-dioxide (TiO2) nanoparticles show great promise as fillers to tune the refractive...

  6. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

    2014-09-01T23:59:59.000Z

    The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

  7. Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*,

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*, Lee D. Bryant,, Andreas Matzinger obtained from 11 eutrophic lakes and suggests a model describing the consumption of dissolved oxygen (O2) in the hypolimnia of eutrophic lakes as a result of only two fundamental processes: O2 is consumed (i) by settled

  8. Unexpected Nondissociative Binding of N2O on Oxygen Vacancies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 . Unexpected Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 ....

  9. ICPIG, July 15-20, 2007, Prague, Czech Republic C9 Heavy particle impact excitation of atomic oxygen in front of the powered

    E-Print Network [OSTI]

    Fehske, Holger

    was assumed. Collision between O2 + and the background gas O2 generate electronically excited atomic oxygen oxygen in front of the powered electrode of oxygen rf plasmas ­ Experiment and PIC-Simulation K. Dittmann) resolved plasma induced optical emission of the atomic oxygen in an asymmetrical oxygen rf plasma (CCP

  10. Effects of CeO2 Support Facets on VOx/CeO2 Catalysts in Oxidative...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CeO2 Support Facets on VOxCeO2 Catalysts in Oxidative Dehydrogenation of Methanol. Effects of CeO2 Support Facets on VOxCeO2 Catalysts in Oxidative Dehydrogenation of Methanol....

  11. Investigation on the Charging Process of Li2O2-Based Air Electrodes in Li-O2 Batteries with Organic Carbonate Electrolytes

    SciTech Connect (OSTI)

    Xu, Wu; Viswanathan, Vilayanur V.; Wang, Deyu; Towne, Silas A.; Xiao, Jie; Nie, Zimin; Hu, Dehong; Zhang, Jiguang

    2011-04-15T23:59:59.000Z

    The charge processes of Li-O2 batteries were investigated by analyzing the gas evolution by in situ gas chromatography-mass spectroscopy (GC/MS) technique. The mixture of Li2O2/Fe3O4/Super P carbon/polyvinylidene fluoride (PVDF) was used as the starting air electrode material and 1M LiTFSI in carbonate-based solvents was used as electrolyte. It was found that Li2O2 is reactive to 1-methyl-2-pyrrolidinone and PVDF binder used in the electrode preparation. During the 1st charge (up to 4.6 V), O2 was the main component in the gases released. The amount of O2 measured by GC/MS was consistent with the amount of Li2O2 decomposed in the electrochemical process as measured by the charge capacity, indicative of the good chargeability of Li2O2. However, after the cell was discharged to 2.0 V in O2 atmosphere and re-charged to ~ 4.6 V in the second cycle, CO2 was dominant in the released gases. Further analysis of the discharged air electrode by X-ray diffraction and Fourier transform infrared spectroscopy indicated that lithium-containing carbonate species (lithium alkyl carbonate and/or Li2CO3) were the main reaction products. Therefore, compatible electrolyte and electrodes as well as the electrode preparation procedures need to be developed for long term operation of rechargeable Li-O2 or Li-air batteries.

  12. Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$

    E-Print Network [OSTI]

    R. M. Santilli

    2000-09-04T23:59:59.000Z

    We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capacities of quantum chemistry. In fact, magnegas contains up to 50% hydrogen, while having combustion exhaust with: 1) a positive oxygen balance (releasing more oxygen in the exhaust than that used in the combustion); 2) no appreciable carcinogenic or toxic substances; 3) considerably reduced carbon dioxide as compared to fossil fuels; 4) considerably reduced nitrogen oxides; and 5) general reduction of pollutants in the exhaust up to 96% of current EPA standards.

  13. atmospheric chemistry simulations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  14. atmospheric chemistry project: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  15. atmospheric chemistry programme: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  16. atmospheric chemistry experiment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  17. atmospheric chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: , nitrogen and oxygen The Greenhouse Effect Atmospheric Aerosols Atmospheric chemical kinetics including and oral reports to...

  18. 8, 22252248, 2008 Detection of oxygen

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

  19. Oxygen Reduction DOI: 10.1002/anie.201403264

    E-Print Network [OSTI]

    Goddard III, William A.

    Oxygen Reduction DOI: 10.1002/anie.201403264 Dramatic Increase in the Oxygen Reduction Reaction solvation) is used to predict how the energies and barriers for the mechanistic steps of the oxygen. In these electro- chemical devices, H2 (generated e.g. from solar energy conversion) reacts with O2 to produce

  20. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H. (Danville, CA)

    1986-01-01T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  1. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao-Qing; Lee, Hung-Sui; Qu, Deyang

    2015-08-01T23:59:59.000Z

    Oxygen reduction and oxygen evolution reactions were studied on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently andmore »a new strategy of developing the catalyst for oxygen evolution reaction.« less

  2. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong [Univ. of Wisconsin, Milwaukee, WI (United States). Collece of Engineering and Applied Science; Zhang, Xuran [Wuhan Univ. of Technology, Wuhan (China). School of Science; Qu, Deyu [Wuhan Univ. of Technology, Wuhan (China). School of Science; Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Wisconsin, Milwaukee, WI (United States). Collece of Engineering and Applied Science

    2015-08-01T23:59:59.000Z

    Oxygen reduction and oxygen evolution reactions were studied on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  3. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  4. High Density n-Si/n-TiO2 Core/Shell Nanowire Arrays with Enhanced Photoactivity

    SciTech Connect (OSTI)

    Hwang, Yun Jeong; Boukai, Akram; Yang, Peidong

    2008-11-15T23:59:59.000Z

    There are currently great needs to develop low-cost inorganic materials that can efficiently perform solar water splitting as photoelectrolysis of water into hydrogen and oxygen has significant potential to provide clean energy. We investigate the Si/TiO2 nanowire heterostructures to determine their potential for the photooxidation of water. We observed that highly dense Si/TiO2 core/shell nanowire arrays enhanced the photocurrent by 2.5 times compared to planar Si/TiO2 structure due to their low reflectance and high surface area. We also showed that n-Si/n-TiO2 nanowire arrays exhibited a larger photocurrent and open circuit voltage than p-Si/n-TiO2 nanowires due to a barrier at the heterojunction.

  5. Phosphorescent semiconductor nanocrystals and proteins for biological oxygen sensing

    E-Print Network [OSTI]

    McLaurin, Emily J. (Emily Jane)

    2011-01-01T23:59:59.000Z

    Oxygen is required for cellular respiration by all complex life making it a key metabolic profiling factor in biological systems. Tumors are defined by hypoxia (low pO2), which has been shown to influence response to ...

  6. Tin oxide thick film by doping rare earth for detecting traces of CO{sub 2}: Operating in oxygen-free atmosphere

    SciTech Connect (OSTI)

    Xiong, Ya; Zhang, Guozhu; Zhang, Shunping; Zeng, Dawen; Xie, Changsheng, E-mail: csxie@mail.hust.edu.cn

    2014-04-01T23:59:59.000Z

    Highlights: • La, Gd, and Lu doped SnO{sub 2} with their sensing properties toward CO{sub 2} were compared. • The microstructures of SnO{sub 2}-based nanoparticles were elaborately characterized. • La-SnO{sub 2} thick film shows superior response toward trace ppm CO{sub 2}. • Our sensing material can be recommended to employ in oxygen-free environment. - Abstract: SnO{sub 2} thick films doped with atomic ratios ranging from 0 up to 8 at.% La, 8 at.% Gd, 8 at.% Lu were fabricated, respectively, via hydrothermal and impregnation methods. The crystal phase, morphology, and chemical composition of the SnO{sub 2}-based nanoparticles were characterized by XRD, FE-SEM, EDX, HRTEM and XPS. Sensing properties of La-SnO{sub 2}, Gd-SnO{sub 2}, Lu-SnO{sub 2} films, as well as the pure SnO{sub 2} film, were analyzed toward CO{sub 2} in the absence of O{sub 2}. It was found that the optimal doping element was La and the best doping ratio was 4 at.%. The maximum response appeared at an operating temperature of 250 °C, on which condition the 4 at.% La-SnO{sub 2} exhibited a remarkable improvement of response from 5.12 to 29.8 when increasing CO{sub 2} concentration from 50 to 500 ppm. Furthermore, the working mechanism underlying such enhancement in CO{sub 2}-sensing functions by La additive in the absence of O{sub 2} was proposed and discussed.

  7. Oxygen Loss from Venus and the Influence of Extreme Solar Wind Conditions

    E-Print Network [OSTI]

    McEnulty, Tess

    2012-01-01T23:59:59.000Z

    and I. Sillanpää (2009), Oxygen ion escape from Venus in aobservations of atmospheric oxygen escape during the passageI. F. Stewart (1981), Hot oxygen BIBLIOGRAPHY atoms in the

  8. Triple Oxygen Isotope Measurement of Nitrate to Analyze Impact of Aircraft Emissions

    E-Print Network [OSTI]

    Chan, Sharleen

    P. ; Craig, H. Atmospheric oxygen: isotopic composition andM.H. 1986. A non-mass-dependent oxygen isotope effect in theof ozone from molecular oxygen: the role of symmetry in

  9. Effects of oxygen on embryonic stem proliferation, energetics, and differentiation into cardiomyocytes

    E-Print Network [OSTI]

    Powers, Daryl E

    2007-01-01T23:59:59.000Z

    Most embryonic stem (ES) cell research has been performed using a gas-phase oxygen partial pressure (pO2gas) of 142 mmHg, whereas embryonic cells in early development are exposed to cellular pO2 (pO2cell) values of about ...

  10. A calorimetric analysis of a polymer electrolyte fuel cell and the production of H2O2 at the cathode

    E-Print Network [OSTI]

    Kjelstrup, Signe

    31.08.2009 1 A calorimetric analysis of a polymer electrolyte fuel cell and the production of H2O2 fuel cell that is operated on hydrogen and oxygen at 50 °C and 1 bar. The cell had a SolviCore Catalyst 1. INTRODUCTION The energy that is dissipated as heat in fuel cells is interesting for several

  11. E-Print Network 3.0 - atmospheric plasma-treated 3d Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF MATERIALS SCIENCE LETTERS 17 (1998) 20832086 Effect of oxygen plasma treatment on SiO2 aerogel lms Summary: , microstructure, and electrical proper- ties of the oxygen plasma...

  12. Electron-Stimulated Reactions and O-2 Production in Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and O-2 Production in Methanol-Covered Amorphous Solid Water Films. Electron-Stimulated Reactions and O-2 Production in Methanol-Covered Amorphous Solid Water Films. Abstract: The...

  13. Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age

    E-Print Network [OSTI]

    Macalady, Jenn

    Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age D. T photosynthesis to overall primary production would have influ- enced oceanic redox and the Proterozoic O2 budget time in Earth's history, complete dominance of oxygenic photosynthesis in the oceans. This paved

  14. Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear, and medical applications. In these en- vironments the advantages of fiber-optic chemical sensors are that they

  15. Photochemical Escape of Oxygen from Early Mars

    E-Print Network [OSTI]

    Zhao, Jinjin

    2015-01-01T23:59:59.000Z

    Photochemical escape is an important process for oxygen escape from present Mars. In this work, a 1-D Monte-Carlo Model is developed to calculate escape rates of energetic oxygen atoms produced from O2+ dissociative recombination reactions (DR) under 1, 3, 10, and 20 times present solar XUV fluxes. We found that although the overall DR rates increase with solar XUV flux almost linearly, oxygen escape rate increases from 1 to 10 times present solar XUV conditions but decreases when increasing solar XUV flux further. Analysis shows that atomic species in the upper thermosphere of early Mars increases more rapidly than O2+ when increasing XUV fluxes. While the latter is the source of energetic O atoms, the former increases the collision probability and thus decreases the escape probability of energetic O. Our results suggest that photochemical escape be a less important escape mechanism than previously thought for the loss of water and/or CO2 from early Mars.

  16. Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(111)

    SciTech Connect (OSTI)

    Calaza, Florencia [Max Planck Society, Fritz Haber Institute; Chen, Tsung-Liang [ORNL; Mullins, David R [ORNL; Xu, Ye [Louisiana State University; Overbury, Steven {Steve} H [ORNL

    2015-01-01T23:59:59.000Z

    Adsorption and reaction of acetic acid on a CeO2(1 1 1) surface was studied by a combination of ultra-highvacuum based methods including temperature desorption spectroscopy (TPD), soft X-ray photoelectronspectroscopy (sXPS), near edge X-ray absorption spectroscopy (NEXAFS) and reflection absorption IRspectroscopy (RAIRS), together with density functional theory (DFT) calculations. TPD shows that thedesorption products are strongly dependent upon the initial oxidation state of the CeO2surface, includingselectivity between acetone and acetaldehyde products. The combination of sXPS and NEXAFS demon-strate that acetate forms upon adsorption at low temperature and is stable to above 500 K, above whichpoint ketene, acetone and acetic acid desorb. DFT and RAIRS show that below 500 K, bridge bondedacetate coexists with a moiety formed by adsorption of an acetate at an oxygen vacancy, formed bywater desorption.

  17. Oxygen production and carbon sequestration in an upwelling coastal Burke Hales,1

    E-Print Network [OSTI]

    Pierce, Stephen

    Oxygen production and carbon sequestration in an upwelling coastal margin Burke Hales,1 Lee Karp), Oxygen production and carbon sequestration in an upwelling coastal margin, Global Biogeochem. Cycles, 20 of particulate organic carbon (POC) and dissolved O2 during the upwelling season off the Oregon coast. Oxygen

  18. Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of

    E-Print Network [OSTI]

    Roth, Justine P.

    Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of Activated O2, Maryland 21218 RECEIVED ON JULY 26, 2008 C O N S P E C T U S Competitively determined oxygen (18 O) isotope effects can be power- ful probes of chemical and biological transformations involving molec- ular oxygen

  19. Layered Li1+x(Ni0.425Mn0.425Co0.15)1xO2 Positive Electrode Materials for Lithium-Ion Batteries

    E-Print Network [OSTI]

    Boyer, Edmond

    and Dahn to be due to an irreversible oxygen loss.14 Ever since LiNi1/3Mn1/3Co1/3O2 material was shown

  20. Importance of Diffusion in Methanol Photochemistry on TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Acharya, Danda P.; Dohnalek, Zdenek; Henderson, Michael A.

    2012-12-06T23:59:59.000Z

    The photoactivity of methanol on the rutile TiO2(110) surface is shown to depend on the ability of methanol to diffuse on the surface and find sites active for its thermal dissociation to methoxy. Temperature programmed desorption (TPD) results show that the extent of methanol photodecomposition to formaldehyde is negligible on the clean TiO2(110) surface at 100 K due to a scarcity of sites that can convert (photoinactive) methanol to (photoactive) methoxy. The extent of photoactivity at 100 K significantly increases when methanol is coadsorbed with oxygen, however only those molecules able to adsorb near (next to) a coadsorbed oxygen species are active. Preannealing coadsorbed methanol and oxygen to above 200 K prior to UV irradiation results in a significant increase in photoactivity. Scanning tunneling microscopy (STM) images clearly show that the advent of increased photoactivity in TPD correlates with the onset of methanol diffusion along the surface’s Ti4+ rows at ~200 K. These results demonstrate that optimizing thermal processes (such as diffusion or proton transfer reactions) can be critical to maximizing photocatalytic reactivity on TiO2 surfaces. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle under contract DEAC05-76RL01830. The research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  1. Nucleation and Stoichiometry Dependence of rutile-TiO2(001)/GaN(0001) Thin Films Grown by Plasma-Assisted Molecular Beam Epitaxy

    E-Print Network [OSTI]

    Feenstra, Randall

    the initial nucleation and the stoichiometry of rutile- TiO2(001) grown on wurtzite GaN(0001) by radio explore the growth of rutile-TiO2(001) on wurtzite GaN(0001) by oxygen plasma-assisted molecular beam) was maintained constant at 400 W. The substrates were commercially available wurtzite Ga-polar GaN(0001) grown

  2. Modeling of durability of polyelectrolyte membrane of O2/H2 fuel cell

    E-Print Network [OSTI]

    Atrazhev, Vadim V

    2014-01-01T23:59:59.000Z

    In this paper, we discuss critical aspects of the mechanisms and features of polymer proton exchange membrane (PEM) degradation in low-temperature H2/O2 fuel cell. In this paper, we focused on chemical mechanism of OH radical generation and their distribution in operational fuel cell. According to the current concept, free radicals are generated from hydrogen and oxygen crossover gases at the surface of Pt particles that precipitated in the membrane. We explicitly calculate Pt precipitation rate and electrochemical potential distribution in the membrane that controls it. Based on radical generation rate and Pt distribution we calculate degradation rate of the membrane taking advantage of simple kinetics equations.

  3. Maintaining Low Oxygen (O2) in Coal Fueled Utility Boilers Using CO Instrumentation

    E-Print Network [OSTI]

    Hopkins, D.; Downing, T.

    and the annual fuel savings possible from this 02 reduction. Unit til 1.8 a pulverized coal fired, 565 MW, CE boiler system placed in service July 27, 1982. Complete and safe combustion in this boiler is maintained by continuously monitoring 02 and CO...Il at Muleshoe, Texas. This is a 565 :Megawatt unit utilizing a Combustion Engineering boiler firing sub-bituminous Wyoming coal thrQugh six elevations of tilting tangential nozzles. The boiler is balanced draft with two air preheaters. Environmental...

  4. Two Pathways for Water Interaction with Oxygen Adatoms on TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    or adjacent Ti4+ rows, Oa facilitates H2O dissociation and proton transfer to form a terminal hydroxyl pair, positioned along- or across-Ti row, respectively. The latter process...

  5. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

  6. Experimental: Sample Preparation TiO2 compact (TiO2comp) anatase films (0.1

    E-Print Network [OSTI]

    state device based on the wealth of knowledge housed in the field of Dye Sensitized Solar Cells (20 min, 110 °C). Cell geometries : (1) ITO/TiO2comp/PbS/Pedot/Au (2) ITO/TiO2comp/TiO2nps and Development of Extremely Thin Absorber Solid State Solar Cells Matteo Biancardo*, Frederik Krebs The Danish

  7. atmospheres pressure mixed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  8. atmospheric pressure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  9. atmospheric pressure hf: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  10. atmospheric pressure photoionization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  11. atmospheric pressure argon: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  12. atmospheric pressure nitrogen: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  13. atmospheric pressure direct: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  14. atmospheric pressure cvd: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  15. atmospheric pressure glow: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  16. atmospheric pressure photoionisation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  17. atmospheric pressure microdischarge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  18. atmospheric pressure cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  19. atmospheric pressure maldi: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  20. An Organometallic Synthesis of TiO2 Nanoparticles

    E-Print Network [OSTI]

    such as pigments, catalysts, catalyst supports, ceramics, energy storage, magnetic data storage, sensors Siegrist,# Louis E. Brus,, and Michael L. Steigerwald*,, Department of Chemistry, Department of Applied-sensitized TiO2 solar cells are inexpensive and have high photon to electron conversion efficiency.2 TiO2

  1. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  2. Hot-electron-driven charge transfer processes on O2 Pt,,111... surface probed by ultrafast extreme-ultraviolet pulses

    E-Print Network [OSTI]

    Bauer, Michael

    it with an ultrafast laser pulse, charge transfer induced changes in the platinum-oxygen bond were observedHot-electron-driven charge transfer processes on O2 Ã?Pt,,111... surface probed by ultrafast extreme-ultraviolet pulses C. Lei,1, * M. Bauer,2 K. Read,1 R. Tobey,1 Y. Liu,3 T. Popmintchev,1 M. M. Murnane,1 and H. C

  3. High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study of their optical and interfacial characteristics

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study with unbalanced magnetrons, we deposited advanced inorganic functional thin films such as TiO2, TiN, and TiO2/Ti sputtering. The TiO2 101 and TiN 100 thin films were stoichiometric and polycrystalline but highly oriented

  4. SnO2 atomic layer deposition on ZrO2 and Al nanoparticles: Pathway to enhanced thermite materials

    E-Print Network [OSTI]

    George, Steven M.

    SnO2 atomic layer deposition on ZrO2 and Al nanoparticles: Pathway to enhanced thermite materials J of Colorado, Boulder, CO 80309-0414, United States Available online 1 June 2005 Abstract Thermite mixtures with traditional thermite mixtures. One technique to create thermite mixtures with improved contact is to deposit

  5. Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated Production of H-2 and O-2 in Amorphous Solid Water Films on TiO2 Nonthermal Water Splitting on Rutile TiO2:...

  6. Evaluation of Advanced PSA and Oxygen Combustion System for Industrial Furnace Applications

    E-Print Network [OSTI]

    Delano, M. A.; Lagree, D.; Kwan, Y.

    M. A. Delano Union Carbide Corp. Tarrytown, NY ABSTRACT EVALUATION OF ADVANCED PSA AND OXYGEN COMBUSTION SYSTEM FOR INDUSTRIAL FURNACE APPLICATIONS D. Lagree Union Carbide Corp. Tonawanda, NY The performance of a pilot scale advanced PSA... oxygen generation system and a low NO x oxygen burner was evaluated for industrial furnace applications. The PSA system employs a two-bed vacuum cycle design with a capacity of 1.3 TPD at 90% O 2 purity. The oxygen generated from the PSA system...

  7. Geochemistry of Surface-Atmosphere Interactions on

    E-Print Network [OSTI]

    Withers, Paul

    state of the surface? #12;Carbonates on Venus ¥ CaCO3+SiO2 = CaSiO3+CO2(g) ¥ Psurface = Pbuffer. ¥ S in lower atmosphere is kinetically controlled ¥ CaCO3 + SO2 = CaSO4 + CO removes SO2 , deposits CaSO4 ¥ Fe rates ¥ Need more data, new spacecraft instruments #12;Handy Minerals ¥ SiO2 Quartz ¥ CaCO3 Calcite ¥ Ca

  8. Role of Water in Methanol Photochemistry on Rutile TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Henderson, Michael A.

    2012-08-07T23:59:59.000Z

    Photochemistry of the molecularly and dissociatively adsorbed forms of methanol on the vacuum-annealed rutile TiO2(110) surface was explored using temperature programmed desorption (TPD), both with and without coadsorbed water. Methoxy, and not methanol, was confirmed as the photochemically active form of adsorbed methanol on this surface. UV irradiation of methoxy-covered TiO2(110) lead to depletion of the methoxy coverage and formation of formaldehyde and a surface OH group. Coadsorbed water did not promote either molecular methanol photochemistry or thermal decomposition of methanol to methoxy. However, terminal OH groups (OHt), prepared by coadsorption of water and oxygen atoms, thermally converted molecularly adsorbed methanol to methoxy at 120 K, thus enabling photoactivity. While chemisorbed water molecules had no influence on methoxy photochemistry, water molecules hydrogen-bonded in the second layer to bridging oxygen (Obr) sites inhibited the methoxy photodecomposition to formaldehyde. From this we conclude that Obr sites accept protons from the hole-mediated conversion of methoxy to formaldehyde. These results provide new fundamental understanding of the hole-scavenging role of methanol in photochemical processes on TiO2-based materials and how water influences this photochemistry. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle under contract DEAC05-76RL01830. The research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  9. Oxygen Transport Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay

    2008-08-30T23:59:59.000Z

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

  10. atmospheric precipitations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Mars;MEX ASPERA (Energetic particles) Escape fluxes of O+, O2 +, CO2 + Three example energy spectra Withers, Paul 131 High Impact Atmospheric Research to Advance Scientific...

  11. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

  12. O$_2$ Emission Toward Orion H$_2$ Peak 1 and the Role of FUV-Illuminated C-Shocks

    E-Print Network [OSTI]

    Melnick, Gary J

    2015-01-01T23:59:59.000Z

    Molecular oxygen, O_2, has been the target of ground-based and space-borne searches for decades. Of the thousands of lines of sight surveyed, only those toward Rho Oph and Orion H_2 Peak 1 have yielded detections of any statistical significance. The detection of the O_2 N_J =3_3 -1_2 and 5_4 - 3_4 lines at 487.249 GHz and 773.840 GHz, respectively, toward Rho Ophiuchus has been attributed to a short-lived peak in the time-dependent, cold-cloud O_2 abundance, while the detection of the O_2 N_J =3_3 - 1_2, 5_4 - 3_4 lines, plus the 7_6 - 5_6 line at 1120.715 GHz, toward Orion has been ascribed to time-dependent preshock physical and chemical evolution and low-velocity (12 km/s) non-dissociative C-type shocks, both of which are fully shielded from far-ultraviolet (FUV) radiation, plus a postshock region that is exposed to a FUV field. We report a re-interpretation of the Orion O_2 detection based on new C-type shock models that fully incorporate the significant effects the presence of even a weak FUV field can h...

  13. Electron-Stimulated Reactions and O-2 Production in Methanol-Covered Amorphous Solid Water Films

    SciTech Connect (OSTI)

    Akin, Minta C.; Petrik, Nikolay G.; Kimmel, Gregory A.

    2009-03-14T23:59:59.000Z

    The low-energy, electron-stimulated desorption (ESD) of molecular products from amorphous solid water (ASW) films capped with methanol is investigated versus methanol coverage (0 - 4 x 1015 cm-2) at 50 K using 100 eV incident electrons. The major ESD products from a monolayer of methanol on ASW are quite similar to the ESD products from bulk methanol film: H2, CH4, H2O, C2H6, CO, CH2O, and CH3OH. For 40 ML ASW films, the molecular oxygen, hydrogen, and water ESD yields from the ASW are suppressed with increasing methanol coverage, while the CH3OH ESD yield increases proportionally to the methanol coverage. The suppression of the water ESD products by methanol is consistent with the non-thermal reactions occurring preferentially at or near the ASW/vacuum interface and not in the interior of the film. The water and molecular hydrogen ESD yields from the water layer decrease exponentially with the methanol cap coverage with 1/e constants of ~ 0.6 x 1015 cm-2 and 1.6 x 1015 cm-2, respectively. In contrast, the O2 ESD from the water layer is very efficiently quenched by small amounts of methanol (1/e ~ 6.5 x 1013 cm-2). The rapid suppression of O2 production by small amounts of methanol is due to reactions between CH3OH and the precursors for the O2 - mainly OH radicals. A kinetic model for the O2 ESD which semi-quantitatively accounts for the observations is presented.

  14. Nonresonant ionization of oxygen molecules by femtosecond pulses: Plasma dynamics studied by time-resolved terahertz spectroscopy

    E-Print Network [OSTI]

    Apkarian, V. Ara

    contribution to laser plasmas generated in air,26 ionized oxygen O2 + plays an important role in the upperNonresonant ionization of oxygen molecules by femtosecond pulses: Plasma dynamics studied by time for exploring laser-induced ionization and plasma formation in gases. Plasma was produced in gaseous oxygen

  15. Photocatalytic reduction of methylene blue by TiO2 nanotube arrays: effects of TiO2 crystalline phase

    E-Print Network [OSTI]

    Kang, Xiongwu; Chen, Shaowei

    2010-01-01T23:59:59.000Z

    reduction of methylene blue by TiO 2 nanotube arrays:the reduction of methylene blue in water as an illustratingpro?les of methylene blue exhibited apparent diminishment.

  16. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham

    2006-12-31T23:59:59.000Z

    Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

  17. Low-Temperature, Strong SiO2-SiO2 Covalent Wafer Bonding for IIIV Compound Semiconductors-to-Silicon Photonic

    E-Print Network [OSTI]

    Bowers, John

    required temperature for strong covalent bond for- mation and greater diffusion efficiency of gasLow-Temperature, Strong SiO2-SiO2 Covalent Wafer Bonding for III­V Compound Semiconductors-temperature process for covalent bonding of thermal SiO2 to plasma-enhanced chemical vapor deposited (PECVD) SiO2

  18. Regulation of Singlet Oxygen Generation Using Single-Walled Carbon Zhiwen Tang,

    E-Print Network [OSTI]

    Tan, Weihong

    Regulation of Singlet Oxygen Generation Using Single-Walled Carbon Nanotubes Zhi Zhu, Zhiwen Tang of Chemistry and Chemical Engineering, Hunan UniVersity, Changsha 410082, P. R. China Received April 20, 2008DNA aptamer, and single-walled carbon nanotubes (SWNTs) for controllable singlet oxygen (1 O2) generation. 1 O

  19. 15N2 formation and fast oxygen isotope exchange during pulsed...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOxCeO2. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx...

  20. On the Origin and Implications of Li$_2$O$_2$ Toroid Formation in Nonaqueous Li-O$_2$ Batteries

    E-Print Network [OSTI]

    Aetukuri, Nagaphani B; García, Jeannette M; Krupp, Leslie E; Viswanathan, Venkatasubramanian; Luntz, Alan C

    2014-01-01T23:59:59.000Z

    The lithium-air (Li-O$_2$) battery has received enormous attention as a possible alternative to current state-of-the-art rechargeable Li-ion batteries given their high theoretical specific energy. However, the maximum discharge capacity in nonaqueous Li-O$_2$ batteries is limited to a small fraction of its theoretical value due to the insulating nature of lithium peroxide, Li$_2$O$_2$, the battery$'$s primary discharge product. In this work, we show that the inclusion of trace amounts of electrolyte additives, such as H$_2$O, significantly improve the capacity of the Li-O$_2$ battery. These additives trigger a solution-based growth mechanism due to their solvating properties, thereby circumventing the Li$_2$O$_2$ conductivity limitation. Experimental observations and a growth model imply that this solution mechanism is responsible for Li$_2$ toroid formation. We present a general formalism describing an additive$'$s tendency to trigger the solution process, providing a rational design route for electrolytes t...

  1. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-11-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

  2. Oxygen-related dielectric relaxation and leakage characteristics of Pt,,Ba,Sr...TiO3 Pt thin-film capacitors

    E-Print Network [OSTI]

    Cao, Wenwu

    Oxygen-related dielectric relaxation and leakage characteristics of PtÕ,,Ba,Sr...TiO3 ÕPt thin to the postannealing temperature in oxygen and nitrogen atmosphere. High leakage currents and low-frequency dielectric and subsequently annealed in oxygen at 350 °C. Such results are related to the mobile oxygen ions and oxygen

  3. Measurements and analysis of CO and O2 emissions in CH4/CO2/O2 flames

    E-Print Network [OSTI]

    Lieuwen, Timothy C.

    accommodate carbon dioxide capture and sequestration. Oxy-fuel combustion, where the fuel is combusted in oxygen diluted with steam or CO2, is one promising approach for post-combustion carbon capture Inc. All rights reserved. Keywords: Oxy-fuel; Carbon dioxide; Carbon capture; Carbon monoxide; Oxygen

  4. Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Abstract: Understanding hydrogen formation on TiO2...

  5. Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Abstract: Rutile TiO2 nanorods were synthesized by...

  6. Water as a Catalyst: Imaging Reactions of O-2 with Partially...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging Reactions of O-2 with Partially and Fully Hydroxylated TiO2(110) Surfaces. Water as a Catalyst: Imaging Reactions of O-2 with Partially and Fully Hydroxylated...

  7. Electron-impact excitation of neutral oxygen

    E-Print Network [OSTI]

    P. S. Barklem

    2006-09-25T23:59:59.000Z

    Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

  8. Etching of porous and solid SiO2 in Ar/c-C4F8, O2/c-C4F8 and Ar/O2/c-C4F8 plasmas

    E-Print Network [OSTI]

    Kushner, Mark

    and porous SiO2 in fluorocarbon plasmas and for etching of organic polymers in O2 plasmas have been.1063/1.1834979] I. INTRODUCTION Fluorocarbon plasma etching of SiO2 and low-dielectric constant (low-k) porous SiO2 of pattern transfer by fluorocarbon plasmas is in large part a result of the excellent selectivity which can

  9. Atmospheric Neutrinos

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2006-12-11T23:59:59.000Z

    This paper is a brief overview of the theory and experimental data of atmospheric neutrino production at the fiftieth anniversary of the experimental discovery of neutrinos.

  10. Optical properties of bismuth-doped SiO2- or GeO2-based glass core optical fibers

    E-Print Network [OSTI]

    Firstova, Elena G

    2015-01-01T23:59:59.000Z

    A detailed study of optical properties of bismuth-doped fibers based on SiO2 and GeO2 glasses containing no other dopants has been carried out. To provide important information about spectroscopic properties of IR bismuth-related active centers (BAC) the excitation-emission fluorescence spectra for a spectral region of 220-2000 nm have been measured. The obtained three-dimensional spectra have been presented for different host glass compositions: silicate, germanate, aluminosilicate and phosphosilicate. Energy-level configuration and main radiative transitions associated with BACs in GeO2 and SiO2 glasses have been revealed. Fluorescence lifetime analysis of the basic radiative transitions of BAC have been carried out. It has been shown that the energy-level schemes of BAC-Si and BAC-Ge (BAC associated with silicon and germanium, respectively) are similar, corresponding BAC-Ge energy levels lying 10-16% lower than those of BAC-Si. It has been determined that BAC-Si, BAC-Ge and BAC-Si, BAC-P can exist simultan...

  11. Catalytic epoxidation of propene with H2O-O2 reactants on Au/TiO2

    E-Print Network [OSTI]

    Ojeda, Manuel

    2009-01-01T23:59:59.000Z

    rutile ~4). Propene (4 kPa, Praxair, UHP) epoxidation ratesmeasured using O 2 (4 kPa, Praxair, UHP) at 350 K in theof H 2 (4 kPa, 99.999%, Praxair) or H 2 O (0-12 kPa) using a

  12. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy...

  13. Chemical oxygen diffusion coefficient measurement by conductivity relaxation--correlation between tracer diffusion

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Chemical oxygen diffusion coefficient measurement by conductivity relaxation--correlation between J. P., Grenier J. C., Loup J. P. ABSTRACT Chemical oxygen diusion coecient ¯(D)was measured the oxygen partial pressure in the surrounding atmosphere of the sample. The consequent evolution

  14. Nitric Oxide Production from Surface Recombination of Oxygen and Nitrogen Atoms

    E-Print Network [OSTI]

    Martín, Pino

    of hypersonic reentry vehicles. In the Earth's atmosphere, oxygen and nitrogen atoms are generated in the shock1 Nitric Oxide Production from Surface Recombination of Oxygen and Nitrogen Atoms Dusan A. Pejakovi from the recombination of oxygen and nitrogen atoms on quartz. The experiments employ two-photon laser

  15. atmospheric pressure matrix-assisted: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Utilization Websites Summary: Aircraft Performance: Atmospheric Pressure FAA Handbook of Aeronautical Knowledge Chap 10 12 - 21% Oxygen - 1% other gases (argon,...

  16. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-10-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  17. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06T23:59:59.000Z

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  18. Site Competition During Coadsorption of Acetone with Methanol and Water on TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Henderson, Michael A.

    2011-08-02T23:59:59.000Z

    The competitive interaction between acetone and two solvent molecules (methanol and water) for surface sites on rutile TiO2(110) was studied using temperature programmed desorption (TPD). On a vacuum reduced TiO2(110) surface, which possessed ~5% oxygen vacancy sites, excess methanol displaced preadsorbed acetone molecules to weakly bound and physisorbed desorption states below 200 K, whereas acetone was stabilized to 250 K against displacement by methanol on an oxidized surface through formation of an acetone-diolate species. These behaviors of acetone differ from the competitive interactions between acetone and water in that acetone is less susceptible to displacement by water. Examination of acetone+methanol and acetone+water multilayer combinations shows that acetone is more compatible in water-ice films than in methanol-ice films, presumably because water has greater potential as a hydrogen-bond donor than does methanol. Acetone molecules displaced from the TiO2(110) surface by water are more likely to be retained in the near-surface region, having a greater opportunity to revisit the surface, than when methanol is used as a coadsorbate. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  19. Heat Transfer between Graphene and Amorphous SiO2

    E-Print Network [OSTI]

    B. N. J. Persson; H. Ueba

    2010-07-22T23:59:59.000Z

    We study the heat transfer between graphene and amorphous SiO2. We include both the heat transfer from the area of real contact, and between the surfaces in the non-contact region. We consider the radiative heat transfer associated with the evanescent electromagnetic waves which exist outside of all bodies, and the heat transfer by the gas in the non-contact region. We find that the dominant contribution to the heat transfer result from the area of real contact, and the calculated value of the heat transfer coefficient is in good agreement with the value deduced from experimental data.

  20. O2Diesel Corporation formerly Dynamic Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellence SeedNunn, Colorado:Cables | Open5-015 JumpO2Diesel

  1. The Molecular Oxygen Tetramer: Intermolecular Interactions and Implications for the $\\epsilon$ Solid Phase

    E-Print Network [OSTI]

    Bartolomei, Massimiliano; Hernández, Marta I; Pérez-Ríos, Jesús; Campos-Martínez, José; Hernández-Lamoneda, Ramón

    2011-01-01T23:59:59.000Z

    Recent data have determined that the structure of the high pressure $\\epsilon$ phase of solid oxygen consists of clusters composed of four O$_2$ molecules. This finding has opened the question about the nature of the intermolecular interactions within the molecular oxygen tetramer. We use multiconfigurational ab initio calculations to obtain an adequate characterization of the ground singlet state of (O$_2$)$_4$ which is compatible with the non magnetic character of the $\\epsilon$ phase. In contrast to previous suggestions implying chemical bonding, we show that (O$_2$)$_4$ is a van der Waals like cluster where exchange interactions preferentially stabilize the singlet state. However, as the cluster shrinks, there is an extra stabilization due to many-body interactions that yields a significant softening of the repulsive wall. We show that this short range behavior is a key issue for the understanding of the structure of $\\epsilon$-oxygen.

  2. Small, Inexpensive Combined NOx Sensor and O2 Sensor

    SciTech Connect (OSTI)

    W. N. Lawless; C. F. Clark, Jr.

    2008-09-08T23:59:59.000Z

    It has been successfully demonstrated in this program that a zirconia multilayer structure with rhodium-based porous electrodes performs well as an amperometric NOx sensor. The sensitivity of the sensor bodies operating at 650 to 700 C is large, with demonstrated current outputs of 14 mA at 500 ppm NOx from sensors with 30 layers. The sensor bodies are small (4.5 x 4.2 x 3.1 mm), rugged, and inexpensive. It is projected the sensor bodies will cost $5 - $10 in production. This program has built on another successful development program for an oxygen sensor based on the same principles and sponsored by DOE. This oxygen sensor is not sensitive to NOx. A significant technical hurdle has been identified and solved. It was found that the 100% Rh electrodes oxidize rapidly at the preferred operating temperatures of 650 - 700 C, and this oxidation is accompanied by a volume change which delaminates the sensors. The problem was solved by using alloys of Rh and Pt. It was found that a 10%/90% Rh/Pt alloy dropped the oxidation rate of the electrodes by orders of magnitude without degrading the NOx sensitivity of the sensors, allowing long-term stable operation at the preferred operating temperatures. Degradation in the sensor output caused by temperature cycling was identified as a change in resistance at the junction between the sensor body and the external leads attached to the sensor body. The degradation was eliminated by providing strong mechanical anchors for the wire and processing the junctions to obtain good electrical bonds. The NOx sensors also detect oxygen and therefore the fully-packaged sensor needs to be enclosed with an oxygen sensor in a small, heated zirconia chamber exposed to test gas through a diffusion plug which limits the flow of gas from the outside. Oxygen is pumped from the interior of the chamber to lower the oxygen content and the combination of measurements from the NOx and oxygen sensors yields the NOx content of the gas. Two types of electronic control units were designed and built. One control unit provides independent constant voltages to the NOx and oxygen sensors and reads the current from them (that is, detects the amount of test gas present). The second controller holds the fully-assembled sensor at the desired operating temperature and controllably pumps excess oxygen from the test chamber. While the development of the sensor body was a complete success, the development of the packaging was only partially successful. All of the basic principles were demonstrated, but the packaging was too complex to optimize the operation within the resources of the program. Thus, no fully-assembled sensors were sent to outside labs for testing of cross-sensitivities, response times, etc. Near the end of the program, Sensata Technologies of Attleboro, MA tested the sensor bodies and confirmed the CeramPhysics measurements as indicated in the following attached letter. Sensata was in the process of designing their own packaging for the sensor and performing cross-sensitivity tests when they stopped all sensor development work due to the automotive industry downturn. Recently Ceramatec Inc. of Salt Lake City has expressed an interest in testing the sensor, and other licensing opportunities are being pursued.

  3. Small, Inexpensive Combined NOx and O2 Sensor

    SciTech Connect (OSTI)

    W. Lawless; C. Clark

    2008-09-01T23:59:59.000Z

    It has been successfully demonstrated in this program that a zirconia multilayer structure with rhodium-based porous electrodes performs well as an amperometric NO{sub x} sensor. The sensitivity of the sensor bodies operating at 650 to 700 C is large, with demonstrated current outputs of 14 mA at 500 ppm NO{sub x} from sensors with 30 layers. The sensor bodies are small (4.5 x 4.2 x 3.1 mm), rugged, and inexpensive. It is projected the sensor bodies will cost $5-$10 in production. This program has built on another successful development program for an oxygen sensor based on the same principles and sponsored by DOE. This oxygen sensor is not sensitive to NO{sub x}. A significant technical hurdle has been identified and solved. It was found that the 100% Rh electrodes oxidize rapidly at the preferred operating temperatures of 650-700 C, and this oxidation is accompanied by a volume change which delaminates the sensors. The problem was solved by using alloys of Rh and Pt. It was found that a 10%/90% Rh/Pt alloy dropped the oxidation rate of the electrodes by orders of magnitude without degrading the NO{sub x} sensitivity of the sensors, allowing long-term stable operation at the preferred operating temperatures. Degradation in the sensor output caused by temperature cycling was identified as a change in resistance at the junction between the sensor body and the external leads attached to the sensor body. The degradation was eliminated by providing strong mechanical anchors for the wire and processing the junctions to obtain good electrical bonds. The NO{sub x} sensors also detect oxygen and therefore the fully-packaged sensor needs to be enclosed with an oxygen sensor in a small, heated zirconia chamber exposed to test gas through a diffusion plug which limits the flow of gas from the outside. Oxygen is pumped from the interior of the chamber to lower the oxygen content and the combination of measurements from the NO{sub x} and oxygen sensors yields the NO{sub x} content of the gas. Two types of electronic control units were designed and built. One control unit provides independent constant voltages to the NOx and oxygen sensors and reads the current from them (that is, detects the amount of test gas present). The second controller holds the fully-assembled sensor at the desired operating temperature and controllably pumps excess oxygen from the test chamber. While the development of the sensor body was a complete success, the development of the packaging was only partially successful. All of the basic principles were demonstrated, but the packaging was too complex to optimize the operation within the resources of the program. Thus, no fully-assembled sensors were sent to outside labs for testing of cross-sensitivities, response times, etc. Near the end of the program, Sensata Technologies of Attleboro, MA tested the sensor bodies and confirmed the CeramPhysics measurements as indicated in the following attached letter. Sensata was in the process of designing their own packaging for the sensor and performing cross-sensitivity tests when they stopped all sensor development work due to the automotive industry downturn. Recently Ceramatec Inc. of Salt Lake City has expressed an interest in testing the sensor, and other licensing opportunities are being pursued.

  4. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17T23:59:59.000Z

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  5. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  6. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  7. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  8. D0 Detector Collision Hall Oxygen Deficiancy Hazard Analysis

    SciTech Connect (OSTI)

    Wu, J.; /Fermilab

    1992-08-06T23:59:59.000Z

    EN-258, D0 Platform ODH Analysts. provided the oxygen deficiency hazard analysts for the D0 detector in the Assembly Hall. This note covers the same analysis. but revised for the Collision Hall. Liquid cryogens. released and warming to atmosphere conditions, expand to, on average, seven hundred times their liquid volume, and displace vital atmospheric oxygen. An oxygen deficiency hazard analysis assesses the increased risk to personnel in areas containing cryogenic systems. The D0 detector Collision Hall ODH analysis has been approached five different ways using established methods. If the low beta quad magnets are powered, and the exhaust rate is below 4220 scfm, the area is ODH class 1. In any other case, the analysis shows the area to be ODH class 0 as equipped (with ventilation fans) and requiring no special safety provisions. System designers have provided for a reduced oxygen level detection and warning system as well as emergency procedures to address fault conditions.

  9. Oxygen contamination in liquid Argon: combined effects on ionization electron charge and scintillation light

    E-Print Network [OSTI]

    R. Acciarri; M. Antonello; B. Baibussinov; M. Baldo-Ceolin; P. Benetti; F. Calaprice; E. Calligarich; M. Cambiaghi; N. Canci; F. Carbonara; F. Cavanna; S. Centro; A. G. Cocco; F. Di Pompeo; G. Fiorillo; C. Galbiati; V. Gallo; L. Grandi; G. Meng; I. Modena; C. Montanari; O. Palamara; L. Pandola; F. Pietropaolo; G. L. Raselli; M. Roncadelli; M. Rossella; C. Rubbia; E. Segreto; A. M. Szelc; F. Tortorici; S. Ventura; C. Vignoli

    2008-04-08T23:59:59.000Z

    A dedicated test of the effects of Oxygen contamination in liquid Argon has been performed at the INFN-Gran Sasso Laboratory (LNGS, Italy) within the WArP R&D program. Two detectors have been used: the WArP 2.3 lt prototype and a small (0.7 lt) dedicated detector, coupled with a system for the injection of controlled amounts of gaseous Oxygen. Purpose of the test with the 0.7 lt detector is to detect the reduction of the long-lived component lifetime of the Argon scintillation light emission at increasing O2 concentration. Data from the WArP prototype are used for determining the behavior of both the ionization electron lifetime and the scintillation long-lived component lifetime during the O2-purification process activated in closed loop during the acquisition run. The electron lifetime measurements allow to infer the O2 content of the Argon and correlate it with the long-lived scintillation lifetime data. The effect of Oxygen contamination on the scintillation light has been thus measured over a wide range of O2 concentration, spanning from about 10^-3 ppm up to about 10 ppm. The rate constant of the light quenching process induced by Oxygen in LAr has been found to be k'(O2)=0.54+-0.03 micros^-1 ppm^-1.

  10. An experimental investigation of the urea-water decomposition and selective catalytic reduction (SCR) of nitric oxides with urea using V2O5-WO3-TiO2 catalyst.

    E-Print Network [OSTI]

    Johar, Jasmeet Singh

    2005-11-01T23:59:59.000Z

    ) stream. The decomposition experiments were conducted with a number of oxygen (O2) compositions (0, 1, 10, and 15%) over the temperature range of 227oC to 477oC. The study showed ammonia (NH3), carbon-dioxide (CO2) and nitric oxide (NO) as the major...

  11. Improved thermal stability of LiCoO2 by nanoparticle AlPO4 coating with respect to spinel Li1:05Mn1:95O4

    E-Print Network [OSTI]

    Cho, Jaephil

    secondary batteries has rapidly expanded due to their applicability to mobile electron- ics batteries use LiCoO2 as a cathode material due to the higher volumetric energy density and excel- lent, resulting in oxygen generation [7]. In addition, the deposited lithium on the graphite anode increases

  12. Ultra-cold Neutron Production in Anti-ferromagnetic Oxygen Solid

    E-Print Network [OSTI]

    Liu, C Y

    2004-01-01T23:59:59.000Z

    Spin waves, or magnons, in the anti-ferromagnetic $\\alpha$ phase of solid oxygen provide a novel mechanism for ultra-cold neutron (UCN) production. Magnons dominate the energy exchange mechanisms for cold neutrons and UCN in solid $\\alpha$-oxygen, much in the same way as do phonons in solid deuterium superthermal UCN sources. We present calculations of UCN production and upscattering rates in S-O$_2$. The results indicate that S-O$_2$ is potentially a much more efficient UCN source material than solid deuterium.

  13. Ultra-cold Neutron Production in Anti-ferromagnetic Oxygen Solid

    E-Print Network [OSTI]

    C. -Y. Liu; A. R. Young

    2004-06-02T23:59:59.000Z

    Spin waves, or magnons, in the anti-ferromagnetic $\\alpha$ phase of solid oxygen provide a novel mechanism for ultra-cold neutron (UCN) production. Magnons dominate the energy exchange mechanisms for cold neutrons and UCN in solid $\\alpha$-oxygen, much in the same way as do phonons in solid deuterium superthermal UCN sources. We present calculations of UCN production and upscattering rates in S-O$_2$. The results indicate that S-O$_2$ is potentially a much more efficient UCN source material than solid deuterium.

  14. High-Quality Epitaxy of Ruthenium Dioxide, RuO2, on Rutile Titanium Dioxide, TiO2, by Pulsed Chemical Vapor Deposition

    E-Print Network [OSTI]

    of rutile TiO2, a material with a high dielectric constant. Therefore, capacitors with high capacitance per these capacitors have low leakage current. Due to its good redox properties, RuO2 has been made into electrodes films have been made by CVD, such as wide-gap semiconductors ZnO23,25 and SnO2,26,27 super- conducting

  15. Central metabolism in Mycobacterium smegmatis during the transition from O2-rich to O2-poor conditions as studied by isotopomer-assisted metabolite analysis

    E-Print Network [OSTI]

    Tang, Yinjie J.; Shui, Wenqing; Myers, Samuel; Feng, Xueyang; Bertozzi, Carolyn; Keasling, Jay D.

    2009-01-01T23:59:59.000Z

    environmental perturbations. glass bottle with a septum cap.of O 2 in a sealed glass bottle, and thus cell growth

  16. Spectral signatures of photosynthesis II: coevolution with other stars and the atmosphere on extrasolar worlds

    E-Print Network [OSTI]

    Nancy Y. Kiang; Antigona Segura; Giovanna Tinetti; Govindjee; Robert E. Blankenship; Martin Cohen; Janet Siefert; David Crisp; Victoria S. Meadows

    2007-01-12T23:59:59.000Z

    As photosynthesis on Earth produces the primary signatures of life that can be detected astronomically at the global scale, a strong focus of the search for extrasolar life will be photosynthesis, particularly photosynthesis that has evolved with a different parent star. We take planetary atmospheric compositions simulated by Segura, et al. (2003, 2005) for Earth-like planets around observed F2V and K2V stars, modeled M1V and M5V stars, and around the active M4.5V star AD Leo; our scenarios use Earth's atmospheric composition as well as very low O2 content in case anoxygenic photosynthesis dominates. We calculate the incident spectral photon flux densities at the surface of the planet and under water. We identify bands of available photosynthetically relevant radiation and find that photosynthetic pigments on planets around F2V stars may peak in absorbance in the blue, K2V in the red-orange, and M stars in the NIR, in bands at 0.93-1.1 microns, 1.1-1.4 microns, 1.5-1.8 microns, and 1.8-2.5 microns. In addition, we calculate wavelength restrictions for underwater organisms and depths of water at which they would be protected from UV flares in the early life of M stars. We estimate the potential productivity for both surface and underwater photosynthesis, for both oxygenic and anoxygenic photosynthesis, and for hypothetical photosynthesis in which longer wavelength, multi-photosystem series are used.

  17. Importance of Diffusion in Methanol Photochemistry on TiO2(110...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Importance of Diffusion in Methanol Photochemistry on TiO2(110). Importance of Diffusion in Methanol Photochemistry on TiO2(110). Abstract: The photoactivity of methanol on the...

  18. Intrinsic Diffusion of Hydrogen on Rutile TiO2(110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diffusion of Hydrogen on Rutile TiO2(110). Intrinsic Diffusion of Hydrogen on Rutile TiO2(110). Abstract: The combined experimental and theoretical study of intrinsic hydrogen...

  19. Adsorption States and Mobility of TMAA Molecules on Reduced TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    States and Mobility of TMAA Molecules on Reduced TiO2(110) Surface. Adsorption States and Mobility of TMAA Molecules on Reduced TiO2(110) Surface. Abstract: Combined scanning...

  20. Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared via Carboxylic Acid Adsorption and Photolysis. Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared...

  1. Adsorption geometry of CO versus coverage on TiO2(110) from s...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of CO versus coverage on TiO2(110) from s- and p-polarized infrared spectroscopy. Adsorption geometry of CO versus coverage on TiO2(110) from s- and p-polarized infrared...

  2. Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Dynamics of CO2 on Rutile TiO2(110)-1×1. Abstract: Adsorption, binding, and diffusion of CO2 molecules on rutile TiO2(110) model surfaces was...

  3. Stability of polymer binders in Li-O2 batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability of polymer binders in Li-O2 batteries. Stability of polymer binders in Li-O2 batteries. Abstract: A number of polymers with various chemical structures were studied as...

  4. Effects of electrolyte salts on the performance of Li-O2 batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrolyte salts on the performance of Li-O2 batteries. Effects of electrolyte salts on the performance of Li-O2 batteries. Abstract: It is well known that the stability of...

  5. A New Vision for High-Capacity Hybrid Li-ion/Li-O2 Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduces A New Vision for High-Capacity Hybrid Li-ionLi-O2 Batteries Diagram illustrating the CEES all-in-one vision for a high-capacity Li-ionLi-O2 cell. Illustration of CEES'...

  6. Investigation of the Rechargeability of Li-O2 Batteries in Non...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Abstract: In order to...

  7. Thermodynamic properties of CexTh1-xO2 solid solution from first...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    properties of the CexTh1xO2 solid solution. Citation: Xiao HY, Y Zhang, and WJ Weber.2012."Thermodynamic properties of CexTh1-xO2 solid solution from first-principles...

  8. Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Abstract: We used anionic...

  9. Methylene Bromide Chemistry and Photochemistry on Rutile TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such as CD2Br2 on TiO2 likely occurs via indirect processes (such as OH radical attack) as opposed to direct mechanisms involving charge carriers generated in TiO2 by...

  10. Fluorine doping in dilute magnetic semiconductor Sn1–xFexO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fluorine doping in dilute magnetic semiconductor Sn1–xFexO2. Fluorine doping in dilute magnetic semiconductor Sn1–xFexO2. Abstract: Recent studies have reported...

  11. The Synthesis of Ag-Doped Mesoporous TiO2 . | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2 . The Synthesis of Ag-Doped Mesoporous TiO2 . Abstract: Ag-doped mesoporous titanium oxide was prepared using non-ionic surfactants and easily handled titanium...

  12. The Synthesis of Cadmium Doped Mesoporous TiO2. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2. The Synthesis of Cadmium Doped Mesoporous TiO2. Abstract: Cd doped mesoporous titanium oxide was prepared using non-ionic surfactants and easily handled titanium...

  13. Water Interactions with Terminal Hydroxyls on TiO2 (110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interactions with Terminal Hydroxyls on TiO2 (110). Water Interactions with Terminal Hydroxyls on TiO2 (110). Abstract: A combination of scanning tunneling microscopy and density...

  14. Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Chemistry of 2-Propanol on TiO2(110): Low and High...

  15. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

  16. Development of high-temperature ferromagnetism in SnO2 and paramagneti...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    high-temperature ferromagnetism in SnO2 and paramagnetism in SnO by Fe doping. Development of high-temperature ferromagnetism in SnO2 and paramagnetism in SnO by Fe doping....

  17. Ethanol synthesis from syngas over Rh-based/SiO2 catalysts: A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    synthesis from syngas over Rh-basedSiO2 catalysts: A combined experimental and theoretical modeling study. Ethanol synthesis from syngas over Rh-basedSiO2 catalysts: A combined...

  18. Assessment of the O2Diesel Operational Safety Program: December 23, 2002 -- June 30, 2007

    SciTech Connect (OSTI)

    TIAX LLC

    2006-06-01T23:59:59.000Z

    This report assesses O2Diesel's operational safety program using its ethanol-diesel blended fuel product.

  19. CO Oxidation mechanism on CeO2-supported Au nanoclusters

    SciTech Connect (OSTI)

    Kim H. Y.; Henkelman, G.

    2013-09-08T23:59:59.000Z

    To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters(NCs)/Nanoparticles, we design Au13 and Au12 supported on a flat and a stepped-CeO2 model (Au/CeO2) and study various kinds of CO oxidation mechanisms at the Au-CeO2 interface and the Au NC as well.

  20. Evaluation of CuAl2O4 as an Oxygen Carrier in Chemical-Looping Mehdi Arjmand,*,

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    Al2O4) was assessed as a potential oxygen carrier using methane as fuel. The carrier particles were of the oxygen carrier is achieved. Thus, CuAl2O4 could be a potential oxygen carrier for chemical dioxide in the atmosphere. Among these, carbon capture and storage (CCS) is considered promising

  1. Oxygen exchange in hybrid solar cells Kion Norrman,a Monica Lira-Cantu,b Frederik C. Krebsa

    E-Print Network [OSTI]

    Oxygen exchange in hybrid solar cells Kion Norrman,a Monica Lira-Cantu,b Frederik C. Krebsa a.risoe.dk/solarcells, Tel (+45) 4677 4793, Fax (+45) 4677 4791, kion.norrman@risoe.dk Abstract: Exchange of oxygen-SIMS) made it possible to demonstrate that atmospheric oxygen is incorporated in the semiconductor oxide

  2. Independent Component Analysis Applied to Pulse Oximetry in the Estimation of the Arterial Oxygen Saturation (SpO2)

    E-Print Network [OSTI]

    pulse oximetry sensor integrated in an Electronic Patch. This system is intended for patients reflective pulse oxime- try based on a novel ring-shaped optical sensor [1], [2], [3]. The Electronic Patch Bakke 23, 2400 Copenhagen NV, Denmark 1 cm LEDs Photo detector Hard plastic capsule Adhesive Fig. 1

  3. Oxygen Isotope Effects on Electron Transfer to O2 Probed Using Chemically Modified Flavins Bound to Glucose Oxidase

    E-Print Network [OSTI]

    Roth, Justine P.

    -reaching consequences, possibly leading to improved biosensors1 and fuel cells2 and to the development of "green2 of ) 28 kcal mol-1 at optimal pH, which is similar to the value obtained earlier from temperature

  4. Investigation into Photoconductivity in Single CNF/TiO2-Dye Core–Shell Nanowire Devices

    E-Print Network [OSTI]

    Li, Zhuangzhi; Rochford, Caitlin; Baca, F. Javier

    2010-06-15T23:59:59.000Z

    A vertically aligned carbon nanofiber array coated with anatase TiO2 (CNF/TiO2) is an attractive possible replacement for the sintered TiO2 nanoparticle network in the original dye-sensitized solar cell (DSSC) design due to the potential...

  5. Leakage current and dielectric breakdown behavior in annealed SiO2 aerogel films

    E-Print Network [OSTI]

    Jo, Moon-Ho

    Leakage current and dielectric breakdown behavior in annealed SiO2 aerogel films Moon-Ho Jo behavior in annealed SiO2 aerogel films for intermetal dielectric applications was investigated in a metal­insulator­semiconductor structure. SiO2 aerogel films with porosities of 70% exhibited Poole­Frenkel conduction both before

  6. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24T23:59:59.000Z

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  7. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOE Patents [OSTI]

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24T23:59:59.000Z

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  8. Atmospheric Aerosols Workshop | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Aerosols Workshop Atmospheric Aerosols Workshop EMSL Science Theme Advisory Panel Workshop - Atmospheric Aerosol Chemistry, Climate Change, and Air Quality. Baer DR, BJ...

  9. Electrical conductivity in Li2O2 and its role in determining capacity limitations in non-aqueous Li-O2 batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    -O2 batteries V. Viswanathan, K. S. Thygesen, J. S. Hummelshøj, J. K. Nørskov, G. Girishkumar et al limitations in non-aqueous Li-O2 batteries V. Viswanathan,1 K. S. Thygesen,2 J. S. Hummelshøj,3 J. K. Nørskov energy density battery couple. Such cells, however, show sudden death at capacities far below

  10. On the optical properties of Ag+15 ion beam irradiated TiO2 and SnO2 thin films

    E-Print Network [OSTI]

    Thakur, Hardeep; Thakur, P; Sharma, K K; Singh, Abhinav Pratap; Kumar, Yogesh; Kumar, Ravi; Chae, Keun Hwa

    2011-01-01T23:59:59.000Z

    In this study, the effects of 200 MeV Ag+15 ion irradiation on the optical properties of TiO2 and SnO2 thin films prepared by RF magnetron sputtering technique were investigated. These films were characterized by the UV-vis spectroscopy and it was observed that with increase in irradiation fluence the transmittance for the TiO2 films systematically increases while that for SnO2 decreases. Absorption spectra of the irradiated samples showed a minor changes in indirect bandgap from 3.44 to 3.59 eV for TiO2 while that for SnO2 significant modifications in the direct bandgap from 3.92 to 3.6 eV were observed on increasing irradiation fluence. The observed modifications in the optical properties of both TiO2 and SnO2 systems with irradiation can be attributed to controlled structural disorder/defects in the system.

  11. A method of determining the dissolved oxygen in the moisture of a porous medium and some oxygen diffusion studies

    E-Print Network [OSTI]

    Runkles, Jack Ralph

    1952-01-01T23:59:59.000Z

    this dissolved oxygen The sample chamber apparatus gives ocnsplcte seal of the bottle from the atmosphere The ohsabor does not require a large ameunt Of nitrogen Sb remove all the oxygen from it, It is easily portable and light in weight The proposed method... METHOD QF DETRHRIUIHO THE DISSOLVED OXmEK IE THE MOISTURE OF A POROUS ERDD% @AD SMfE QXYOEB DKFFUSIOE STUDIES ' INTRO DUO fQRF, I Oxygen, bas been known to be important in plant growth fox maay years There has been a great deal of xesearoh...

  12. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15T23:59:59.000Z

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  13. Atmospheric Aerosol Systems | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Themes Atmospheric Aerosol Systems Overview Atmospheric Aerosol Systems Biosystem Dynamics & Design Energy Materials & Processes Terrestrial & Subsurface Ecosystems...

  14. Enhanced visible-light absorption of mesoporous TiO2 by co-doping with transition-metal/nitrogen ions

    SciTech Connect (OSTI)

    Mathis, John [Embry-Riddle Aeronautical University; Bi, Zhonghe [ORNL; Bridges, Craig A [ORNL; Kidder, Michelle [ORNL; Paranthaman, Mariappan Parans [ORNL

    2013-01-01T23:59:59.000Z

    Titanium (IV) oxide, TiO2, has been the object of intense scrutiny for energy applications. TiO2 is inexpensive, non-toxic, and has excellent corrosion resistance when exposed to electrolytes. A major drawback preventing the widespread use TiO2 for photolysis is its relatively large band gap of ~3eV. Only light with wavelengths shorter than 400 nm, which is in the ultraviolet portion of the spectrum, has sufficient energy to be absorbed. Less than 14 percent of the solar irradiation reaching the earth s surface has energy exceeding this band gap. Adding dopants such as transition metals has long been used to reduce the gap and increase photocatalytic activity by accessing the visible part of the solar spectrum. The degree to which the band gap is reduced using transition metals depends in part on the overlap of the d-orbitals of the transition metals with the oxygen p-orbitals. Therefore, doping with anions such as nitrogen to modify the cation-anion orbital overlap is another approach to reduce the gap. Recent studies suggest that using a combination of transition metals and nitrogen as dopants is more effective at introducing intermediate states within the band gap, effectively narrowing it. Here we report the synthesis of mesoporous TiO2 spheres, co-doped with transition metals and nitrogen that exhibit a nearly flat absorbance response across the visible spectrum extending into the near infrared.

  15. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Liu, Jue [Brookhaven National Lab. (BNL), Upton, NY (United States); Lee, Byungju [Seoul National Univ. (Korea, Republic of); Qiao, Ruimin [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source; Yang, Zhenzhong [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Xu, Shuyin [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States)] (ORCID:000000018513518X); Gu, Lin [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Hu, Yong-Sheng [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)] (ORCID:0000000284306474); Yang, Wanli [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source] (ORCID:0000000306668063); Kang, Kisuk [Seoul National Univ. (Korea, Republic of); Li, Hong [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)] (ORCID:000000028659086X); Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States); Chen, Liquan [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Huang, Xuejie [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)

    2015-03-25T23:59:59.000Z

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.

  16. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng; Liu, Jue; Lee, Byungju; Qiao, Ruimin; Yang, Zhenzhong; Xu, Shuyin; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Yang, Wanli; et al

    2015-03-25T23:59:59.000Z

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accuratelymore »identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.« less

  17. Transition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget

    E-Print Network [OSTI]

    Alexander, Becky

    processes, volca- noes) or produced within the atmosphere by oxidation of re- duced sulfur speciesTransition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur importance of sulfate production by Fe(III)- and Mn(II)-catalyzed oxidation of S(IV) by O2. We scale

  18. Experimental Evaluation of a Model for Oxygen Exchange in a Pulsating Intravascular Artificial Lung

    E-Print Network [OSTI]

    Federspiel, William J.

    Experimental Evaluation of a Model for Oxygen Exchange in a Pulsating Intravascular Artificial Lung an intravascular hollow fiber artificial lung that uses a pulsating balloon located within the fiber bundle in pulsating intravascular artificial lungs. In this study we evaluate the O2 exchange model with gas exchange

  19. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  20. A calcium oxygen secondary battery

    SciTech Connect (OSTI)

    Pujare, N.U.; Semkow, K.W.; Sammells, A.F.

    1988-01-01T23:59:59.000Z

    The authors report preliminary work performed in their laboratory on a high-temperature electrochemically reversible calcium-oxygen cell. Following an analogous strategy to that recently discussed for the lithium-oxygen secondary system, this calcium-oxygen cell utilizes stabilized zirconia oxygen vacancy conducting solid electrolytes to achieve effective separation between half-cell reactions.

  1. Surface Passivation of Nanoporous TiO2 via Atomic Layer Deposition of ZrO2 for Solid-State Dye-Sensitized Solar Cell Applications

    E-Print Network [OSTI]

    to the spiro-OMeTAD. Introduction Dye-sensitized solar cells (DSCs) based on mesoporous titania and liquidSurface Passivation of Nanoporous TiO2 via Atomic Layer Deposition of ZrO2 for Solid-State Dye-Sensitized Solar Cell Applications Tina C. Li, Ma´rcio S. Go´es,,§ Francisco Fabregat-Santiago,*, Juan Bisquert

  2. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dehydrogenation (ODH) of methanol. The effect of sodium on the surface structure, redox properties, and surface aciditybasicity of VOxCeO2 was investigated using hydrogen...

  3. INTRODUCTIONTOTHE SOLAR ATMOSPHERE

    E-Print Network [OSTI]

    ? #12;WHAT ISTHE SOLAR ATMOSPHERE? #12;#12;1-D MODEL ATMOSPHERE · Averaged over space and time · GoodINTRODUCTIONTOTHE SOLAR ATMOSPHERE D. Shaun Bloomfield Trinity College Dublin #12;OUTLINE · What is the solar atmosphere? · How is the solar atmosphere observed? · What structures exist and how do they evolve

  4. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2003-01-01T23:59:59.000Z

    In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

  5. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

  6. Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation of

    E-Print Network [OSTI]

    Brown, Eric

    Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation that an alizarin red S ~ARS! dye coating on TiO2 nanoparticles enables visible light activation coatings on TiO2 nanoparticles can serve to enhance imaging, by clearly showing that dye coatings on TiO2

  7. Ordered Array of Gold Semishells on TiO2 Spheres: An Ultrasensitive and Recyclable SERS Substrate

    E-Print Network [OSTI]

    Xiong, Qihua

    more semiconductor-noble metal nanocomposites were fabricated, such as TiO2/Ag, ZnO/Ag, ZnO/Au, TiO2/AuOrdered Array of Gold Semishells on TiO2 Spheres: An Ultrasensitive and Recyclable SERS Substrate, 639798, Singapore ABSTRACT: Ordered array of Au semishells on TiO2 spheres with controlled size

  8. Novel SiO2-based antioxidant compound with significantly extended life-time and activity

    E-Print Network [OSTI]

    Daraio, Chiara

    Nanoparticles Covalently Functionalized with Gallic Acid", ACS Applied Materials & Interfaces, Vol. 4,Issue 12 grafting on SiO2 nanoparticles Composition: SiO2 (FDA approved) ­ E551 Gallic acid (FDA approved) E310 15, 2013 Copyright ETH Zürich 3 Current antioxidants Phenols are potent antioxidants Gallic acid

  9. Conversion of 1,2-Propylene Glycol on Rutile TiO2(110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion of 1,2-Propylene Glycol on Rutile TiO2(110). Conversion of 1,2-Propylene Glycol on Rutile TiO2(110). Abstract: We have studied the reactions of 1,2-propylene glycol...

  10. Surface morphologies of SnO2(110) Matthias Batzill *, Khabibulakh Katsiev, Ulrike Diebold *

    E-Print Network [OSTI]

    Diebold, Ulrike

    ; Surface relaxation and reconstruction; Surface structure, morphology, roughness, and topography; TinSurface morphologies of SnO2(110) Matthias Batzill *, Khabibulakh Katsiev, Ulrike Diebold), and low energy electron diffraction (LEED) was used to investigate the surface morphology of SnO2(1 1 0

  11. Hard templating synthesis of mesoporous and nanowire SnO2 lithium battery anode materials

    E-Print Network [OSTI]

    Cho, Jaephil

    Hard templating synthesis of mesoporous and nanowire SnO2 lithium battery anode materials Hyesun materials for lithium batteries were prepared using KIT-6 and SBA-15 SiO2 templates as an anode material for lithium batteries due to its high capacity (>600 mAh gÀ1 ) compared with graphite

  12. MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE

    E-Print Network [OSTI]

    Foss, Bjarne A.

    MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland Dagfinn Snarheim and control of a semi-closed O2/CO2 gas turbine cycle for CO2 capture. In the first part the process predictive control, Gas turbines, CO2 capture 1. INTRODUCTION Gas turbines are widely used for power

  13. Supporting Materials Hierarchical TiO2/Si Nanowire Architecture with

    E-Print Network [OSTI]

    Wang, Xudong

    Supporting Materials Hierarchical TiO2/Si Nanowire Architecture with Photoelectrochemical Activity 1287) system was used for J-E measurement. Prior to potentiodynamic testing, back side of the sample surface was scratched by blade to remove semiconducting TiO2 and the other half surface was partially

  14. Morphological Dependence of Lithium Insertion in Nanocrystalline TiO2(B) Nanoparticles and Nanosheets

    E-Print Network [OSTI]

    Henkelman, Graeme

    Morphological Dependence of Lithium Insertion in Nanocrystalline TiO2(B) Nanoparticles ABSTRACT: The lithium insertion behavior of nanoparticle (3-D) and nanosheet (2- D) architectures of TiO2(B-axis that reduces Li+ -Li+ interactions between C and A2 sites. The calculated lithiation potentials and degree

  15. Capacity Fade Studies of LiCoO2 Based Li-ion Cells Cycled at

    E-Print Network [OSTI]

    Popov, Branko N.

    in capacity of commercially available Sony 18650 Cells cycled at different temperatures. Perform rate of a Sony 18650 Li-ion cell Cathode (positive electrode) - LiCoO2. Anode (negative electrode) - MCMB. Cell capacity ­ 1.8 Ah #12;Characteristics of a Sony 18650 Li-ion cell Characteristics Positive LiCoO2 Negative

  16. Densification and microstructure development in spark plasma sintered WC6 wt% ZrO2 nanocomposites

    E-Print Network [OSTI]

    Srivastava, Kumar Vaibhav

    Densification and microstructure development in spark plasma sintered WC­6 wt% ZrO2 nanocomposites nanocomposite, spark plasma sintered at 1300 °C, for varying times of up to 20 min. The primary aim of this work investigation indicated that ZrO2 in the spark plasma sintered nanocomposite adopted an orthorhombic crystal

  17. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For...

  18. Multiscale Modeling of TiO2 Nanoparticle Production in Flame Reactors: Effect of Chemical Mechanism

    E-Print Network [OSTI]

    Raman, Venkat

    , catalysis, energy, and semiconductors. Titanium dioxide (TiO2) nanoparticles are traditionally used and Engineering Mechanics, The UniVersity of Texas, Austin, Texas 78712 For titanium dioxide (TiO2) nanoparticles in the flame with detailed titanium oxidation chemistry, compared to one-step chemistry. Finally, a large

  19. Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite

    E-Print Network [OSTI]

    Iglic, Ales

    nanocomposite sensitized with a D35-cpdt dye was investigated. A dye-sensitized solar cell (DSSC) with a Zn discussed. Keywords ZnO/SnO2 Nanocomposite, Dye-sensitized Solar Cell, Nanostructured Surfaces 1O/SnO2 nanocomposite photoanode based on a cobalt electrolyte achieved a solar-to-electricity conversion

  20. Enhanced Energy Conversion Efficiency of the Sr2+-Modified Nanoporous TiO2 Electrode Sensitized

    E-Print Network [OSTI]

    Huang, Yanyi

    efficiency achieved with dye-sensitized solar cells may be attributed to the nanoporous TiO2 electrode.3 photon to current efficiency of a solar cell based on the dye Ru[LL(NCS)2] (L ) 2,2-bipyridine-4 cell based on dye-sensitized nanoporous TiO2 thin film electrode, and power conversion efficiency

  1. Solar Energy Materials & Solar Cells 71 (2002) 261271 Photoelectric behavior of nanocrystalline TiO2

    E-Print Network [OSTI]

    Huang, Yanyi

    . A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6:1 mA cmÃ?2; Nanocrystalline TiO2; Dye sensitized solar cell; Terpyridyl ruthenium dyes; Photoelectrochemical solar cells unmatched performance in dye staff studied as solar cell sensitizer before 1997. Only recently, a black dye

  2. Laser processing of nanocrystalline TiO2 films for dye-sensitized solar cells

    E-Print Network [OSTI]

    Arnold, Craig B.

    Laser processing of nanocrystalline TiO2 films for dye-sensitized solar cells H. Kim,a) G. P­20 m thick) layers incorporated in dye-sensitized solar cells. Laser direct-write is a laser techniques to produce porous nc- TiO2 films required for dye-sensitized solar cells. The dye solar cells

  3. Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells Kadiatou photoanodes for dye- sensitized solar cells (DSCs), based on nanocrystalline TiO2 with limited addition applied (i.e., soaking in TiCl4 to boost open circuit photovoltage). INTRODUCTION Dye-sensitized solar

  4. FischerTropsch synthesis on a model Co/SiO2 catalyst , Zhoujun Wang a

    E-Print Network [OSTI]

    Goodman, Wayne

    Fischer­Tropsch synthesis on a model Co/SiO2 catalyst Zhen Yan a , Zhoujun Wang a , Dragomir B Keywords: Model catalyst Cobalt catalyst Silica Fischer­Tropsch synthesis a b s t r a c t A model Co/SiO2 catalyst was prepared by depositing cobalt on silica films in ultrahigh vacuum condi- tions. Fischer­Tropsch

  5. Transformation plasticity and thermoelastic behavior in ZrO2-containing ceramics

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    565 Transformation plasticity and thermoelastic behavior in ZrO2-containing ceramics A. H. Heuer plasticity in Zr02-containing ceramics. The trans thermoélastique. Abstract.- Transformation plasticity in ZrO2, which is responsible for the high strength and high

  6. Application of SiO2 aerogel film with low dielectric constant to intermetal dielectrics

    E-Print Network [OSTI]

    Jo, Moon-Ho

    Application of SiO2 aerogel film with low dielectric constant to intermetal dielectrics Moon-Ho Jo aerogel film was characterized from its structural and chemical viewpoints. High porosity of material infrared spectroscopy (FT-IR) for their chemical states. The improved electrical properties of SiO2 aerogel

  7. Ultrafast optical nonlinearity in poly,,methylmethacrylate...-TiO2 nanocomposites

    E-Print Network [OSTI]

    Wei, Ji

    -quality, transparent films consisting of polymer-TiO2 hybrid nanocomposites, and on their linear optical properties.3Ultrafast optical nonlinearity in poly,,methylmethacrylate...-TiO2 nanocomposites H. I. Elim and W nanocomposites, which are synthesized by a simple technique of in-situ sol-gel/polymerization. The best figures

  8. Europium-Doped TiO2 Hollow Nanoshells: Two-Photon Imaging of Cell Binding

    E-Print Network [OSTI]

    Kummel, Andrew C.

    Europium-Doped TiO2 Hollow Nanoshells: Two-Photon Imaging of Cell Binding Sergio Sandoval,,,§ Jian method to fabricate luminescent monodisperse 200 nm europium-doped hollow TiO2 nanoshell (NS) particles-functionalized polystyrene beads were used as templates, and the porous walls of europium-doped titania nanoshells were

  9. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, S.P.; Woods, R.W.

    1998-08-11T23:59:59.000Z

    A process is disclosed for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750 C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5--3000 ppm in order to obtain a desired composition in the resulting composite. 2 figs.

  10. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA)

    1998-01-01T23:59:59.000Z

    A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

  11. Dimerization Induced Deprotonation of Water on RuO2(110)

    SciTech Connect (OSTI)

    Mu, Rentao; Cantu Cantu, David; Lin, Xiao; Glezakou, Vassiliki Alexandra; Wang, Zhitao; Lyubinetsky, Igor; Rousseau, Roger J.; Dohnalek, Zdenek

    2014-10-02T23:59:59.000Z

    RuO2 has proven to be indispensable as a co-catalyst in numerous systems designed for photocatalytic water splitting. In this study we have carried out a detailed mechanistic study of water behavior on the most stable RuO2 face, RuO2(110), by employing variable temperature scanning tunneling microscopy and density functional theory calculations. We show that water monomers adsorb molecularly on Ru sites, become mobile above 238 K, diffuse along the Ru rows and form water dimers. The onset for dimer diffusion is observed at ~277 K indicating significantly higher diffusion barrier than that for monomers. More importantly, we find that water dimers deprotonate readily to form Ru-bound H3O2 and bridging OH species. The observed behavior is compared and contrasted with that observed for water on isostructural rutile TiO2(110).

  12. Limits to the lunar atmosphere

    SciTech Connect (OSTI)

    Morgan, T.H. (National Aeronautics and Space Administration, Washington, D.C. (USA)); Shemansky, D.E. (Univ. of Arizona, Tucson (USA))

    1991-02-01T23:59:59.000Z

    The presence of sodium and potassium on the Moon implies that other more abundant species should be present. Volatile molecules like H{sub 2}O are significantly more abundant than sodium in any of the proposed external atmospheric sources. Source mechanisms which derive atoms from the surface should favor abundant elements in the regolith. It is therefore puzzling that the Apollo ultraviolet spectrometer experiment set limits on the density of oxygen of N{sub O} < 5 {times} 10{sup 2} cm{sup {minus}3}, and that the Apollo Lunar Atmospheric Composition Experiment data imply N{sub O} < 50 cm{sup {minus}3} above the subsolar point. These limits are surprisingly small relative to the measured value for sodium. A simple consideration of sources and sinks predicts significantly greater densities of oxygen. It is possible but doubtful that the Apollo measurements occur ed during an epoch in which source rates were small. A preferential loss process for oxygen on the darkside of the Moon is considered in which ionization by electron capture in surface collisions leads to escape through acceleration in the local electric field. Cold trapping in permanently shadowed regions as a net sink is considered and discounted, but the episodic nature of cometary insertion may allow formation of ice layers which act as a stablized source of OH. On the basis of an assumed meteoroid impact source, the authors predict a possible emission brightness of {approximately} 50 R in the OH(A {minus} X)(0,0) band above the lunar bright limb. A very uncertain small comet source of H{sub 2}O could raise this value by more than two orders of magnitude.

  13. Oxygen Concentration Microgradients for Cell Culture

    E-Print Network [OSTI]

    Park, Jaehyun

    2010-01-01T23:59:59.000Z

    The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

  14. Oxygen abundances in the most oxygen-rich spiral galaxies

    E-Print Network [OSTI]

    L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

    2006-01-06T23:59:59.000Z

    Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

  15. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1992-01-01T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  16. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  17. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-08-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

  18. Heterogeneous Reduction of PuO2 with Fe(II): Importance of the Fe(III) Reaction Product

    SciTech Connect (OSTI)

    Felmy, Andrew R.; Moore, Dean A.; Rosso, Kevin M.; Qafoku, Odeta; Rai, Dhanpat; Buck, Edgar C.; Ilton, Eugene S.

    2011-05-01T23:59:59.000Z

    Abstract Heterogeneous reduction of actinides in higher and more soluble oxidation states to lower more insoluble oxidation states by reductants such as Fe(II) has been the subject of intensive study for more than two decades. However, Fe(II)-induced reduction of sparingly soluble Pu(IV) to the more soluble lower oxidation state Pu(III) has been much less studied even though such reactions can potentially increase the mobility of Pu in the subsurface. Thermodynamic calculations are presented that show how differences in the free energy of various possible solid-phase Fe(III) reaction products can greatly influence aqueous Pu(III) concentrations resulting from reduction of PuO2(am) by Fe(II). We present the first experimental evidence that reduction of PuO2(am) to Pu(III) by Fe(II) was enhanced when the Fe(III) mineral goethite was spiked into the reaction. The effect of goethite on reduction of Pu(IV) was demonstrated by measuring the time-dependence of total aqueous Pu concentration, its oxidation state, and system pe/pH. We also re-evaluated established protocols for determining Pu(III) [(Pu(III) + Pu(IV)) - Pu(IV)] by using thenoyltrifluoroacetone (TTA) in toluene extractions; the study showed that it is important to eliminate dissolved oxygen from the TTA solutions for accurate determinations. More broadly, this study highlights the importance of the Fe(III) reaction product in actinide reduction rate and extent by Fe(II).

  19. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  20. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  1. Formation of Interfacial Layer and Long-Term Cylability of Li-O-2 Batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Mehdi, Beata L.; Thomsen, Edwin C.; Engelhard, Mark H.; Masse, Robert C.; Bhattacharya, Priyanka; Gu, Meng; Bennett, Wendy D.; Nie, Zimin; Wang, Chong M.; Browning, Nigel D.; Zhang, Jiguang

    2014-07-28T23:59:59.000Z

    Extended cycling of the Li-O2 battery under full discharge/charge conditions is achievable upon selection of appropriate electrode materials and cycling protocol. However, the decomposition of the side products also contribute to the observed good cycling behavior of high capacity Li-O2 batteries. Quantitative analyses of the discharge and charge products reveals a quick switch from the predominant formation of Li2O2 to the predominant formation of side products during the first a few cycles of the Li-O2 batteries. After the switch, cycling stabilizes with a repeatable formation of Li2O2/side products at ~1:2 ratio. CNTs/Ru composite electrodes exhibits lower charge voltage and deliver 50 full discharge-charge cycles without sharp capacity drop. Ru coated glass carbon electrode can lead to more than 500 cycles without change in its cycling profiles. The better understanding on Li-O2 reaction processes developed in this work may lead to the further improvement on the long term cycling behavior of high capacity Li-O2 batteries.

  2. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

  3. Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

  4. Microchannel Reactor System Design & Demonstration For On-Site H2O2 Production by Controlled H2/O2 Reaction

    SciTech Connect (OSTI)

    Adeniyi Lawal

    2008-12-09T23:59:59.000Z

    We successfully demonstrated an innovative hydrogen peroxide (H2O2) production concept which involved the development of flame- and explosion-resistant microchannel reactor system for energy efficient, cost-saving, on-site H2O2 production. We designed, fabricated, evaluated, and optimized a laboratory-scale microchannel reactor system for controlled direct combination of H2 and O2 in all proportions including explosive regime, at a low pressure and a low temperature to produce about 1.5 wt% H2O2 as proposed. In the second phase of the program, as a prelude to full-scale commercialization, we demonstrated our H2O2 production approach by ‘numbering up’ the channels in a multi-channel microreactor-based pilot plant to produce 1 kg/h of H2O2 at 1.5 wt% as demanded by end-users of the developed technology. To our knowledge, we are the first group to accomplish this significant milestone. We identified the reaction pathways that comprise the process, and implemented rigorous mechanistic kinetic studies to obtain the kinetics of the three main dominant reactions. We are not aware of any such comprehensive kinetic studies for the direct combination process, either in a microreactor or any other reactor system. We showed that the mass transfer parameter in our microreactor system is several orders of magnitude higher than what obtains in the macroreactor, attesting to the superior performance of microreactor. A one-dimensional reactor model incorporating the kinetics information enabled us to clarify certain important aspects of the chemistry of the direct combination process as detailed in section 5 of this report. Also, through mathematical modeling and simulation using sophisticated and robust commercial software packages, we were able to elucidate the hydrodynamics of the complex multiphase flows that take place in the microchannel. In conjunction with the kinetics information, we were able to validate the experimental data. If fully implemented across the whole industry as a result of our technology demonstration, our production concept is expected to save >5 trillion Btu/year of steam usage and >3 trillion Btu/year in electric power consumption. Our analysis also indicates >50 % reduction in waste disposal cost and ~10% reduction in feedstock energy. These savings translate to ~30% reduction in overall production and transportation costs for the $1B annual H2O2 market.

  5. Dust in brown dwarfs and extra-solar planets IV. Assessing TiO2 and SiO nucleation for cloud formation modeling

    E-Print Network [OSTI]

    Lee, G; Giles, H; Bromley, S T

    2014-01-01T23:59:59.000Z

    Clouds form in atmospheres of brown dwarfs and planets. The cloud particle formation processes are similar to the dust formation process studied in circumstellar shells of AGB stars and in Supernovae. Cloud formation modelling in substellar objects requires gravitational settling and element replenishment in addition to element depletion. All processes depend on the local conditions, and a simultaneous treatment is required. We apply new material data in order to assess our cloud formation model results regarding the treatment of the formation of condensation seeds. We re-address the question of the primary nucleation species in view of new (TiO2)_N-cluster data and new SiO vapour pressure data. We apply the density functional theory using the computational chemistry package Gaussian 09 to derive updated thermodynamical data for (TiO2)_N-clusters as input for our TiO2 seed formation model. We test different nucleation treatments and their effect on the overall cloud structure by solving a system of dust momen...

  6. Calculation of the degree of utilization of oxygen in the oxidation of bitumen under industrial conditions

    SciTech Connect (OSTI)

    Marakaeva, L.A.; Bereznikov, A.V.; Rozental', D.A.

    1988-09-10T23:59:59.000Z

    The degree of utilization of air oxygen plays an important role in bitumen production. This parameter depends firstly on the capacity of the compressor that could be reduced at a more complete utilization of oxygen; secondly, a high oxygen content of the waste gases can lead to explosions and coke formation. Besides this, the waste gases contain toxic substances at concentrations which are not permitted for discharge into the atmosphere. Thus, the possibility of calculating the oxygen content of waste gases on industrial installation was investigated. The authors have derived an equation which describes the oxygen content of the waste gases as a function of the temperature and depth of oxidation, the oxygen flow rate, and the height of the liquid phase, for a laboratory unit; it was taken as the basis for the transition to the industrial scale.

  7. Immobilizing Au Nanoparticles on SiO2 Surfaces Using Octadecylsiloxane Monolayers

    E-Print Network [OSTI]

    Southern California, University of

    of octadecylsiloxane (ODS) and also in SiO2 layers created by deposition and oxidation of ODS layers. The ODS of any layer. Depositing a second set of particles onto an ODS layer in contact with the substrate

  8. Excellent Sulfur Resistance of Pt/BaO/CeO2 Lean NOx Trap Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and CHF Peden.2008."Excellent Sulfur Resistance of PtBaOCeO2 Lean NOx Trap Catalysts."Applied Catalysis. B, Environmental 84(3-4):545-551. doi:10.1016j.apcatb.2008.05.009...

  9. Synthesis of TiO2 photocatalyst and study on their improvement technology of photocatalytic activity

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    was evaluated by the measurements of the UV/vis. irradiation, infrared spectroscopy, XPS, and contact angleO2) plays an important role in a variety of technological applications ranging from sensors

  10. Investigation of Local Environments in Nafion-SiO2 Composite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the analysis of the Nafion-SiO2 composite membrane used in a vanadium redox flow battery by nuclear magnetic resonance (NMR) spectroscopy, X-ray photoelectron spectroscopy...

  11. Hole-mediated Photodecomposition of Trimehtyl Acetate on a TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acetate on a TiO2(001) Anatase Epitaxial Thin Film Surface. Abstract: Surfaces of titanium dioxide in both rutile and anatase polymorphs have attracted significant attention in...

  12. Properties of Structurally Excellent N-doped TiO2 Rutile. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Citation: Chambers SA, SH Cheung, V Shutthanandan, S Thevuthasan, MK Bowman, and AG Joly.2007."Properties of Structurally Excellent N-doped TiO2 Rutile."Chemical Physics...

  13. trans-K3[TcO2(CN)4]. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    range. Citation: Chatterjee S, AS Del Negro, MK Edwards, B Twamley, JA Krause, and SA Bryan.2010."trans-K3TcO2(CN)4."Acta Crystallographica. Section E 66(8):i61 - i62....

  14. Invoking any Intel compiler with -g defaults to -O2 optimization...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Invoking any Intel compiler with a Cray wrapper with -g defaults to -O2 optimization contrary to the Intel compiler man pages Invoking any Intel compiler with a Cray wrapper with...

  15. Porous TiO2 microspheres with tunable properties for photocatalytic air purification Alberto Naldoni a,

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    2012 Keywords: TiO2 Nanostructured microsphere Silica Photocatalysis NOx a b s t r a c t The synthesis, photonic materials, batteries and membrane fuel cells, and photocatalysis [7­15]. Titanium dioxide

  16. Reproducible Automated Phosphopeptide Enrichment Using Magnetic TiO 2 and Ti-IMAC

    E-Print Network [OSTI]

    Tape, Christopher

    Reproducible, comprehensive phosphopeptide enrichment is essential for studying phosphorylation-regulated processes. Here, we describe the application of hyper-porous magnetic TiO2 and Ti-IMAC microspheres for uniform ...

  17. D0 Detector Assemble Hall Platform Oxygen Deficiency Hazard Analysis

    SciTech Connect (OSTI)

    Clark, D.; Michael, J.; /Fermilab

    1991-01-29T23:59:59.000Z

    Liquid cryogens, released and warming to atmosphere conditions, expand to, on average, seven hundred times their liquid volume, and displace vital atmospheric oxygen. An oxygen deficiency hazard analysis assesses the increased risk to personnel in areas containing cryogenic systems. The D0 detector platform area ODH analysis has been approached four different ways using established methods. In each case, the analysis shows the platform area to be ODH class 0 as equipped (with ventilation fans) and requiring no special safety provisions. System designers have provided for a reduced oxygen level detection and warning system as well as emergency procedures to address fault conditions. The Oxygen Deficiency Hazard of any particular area is defined by these parameters: the nature of the accidental supply of inert gas (probability of occurrence and quantity then released), the area's volume, the area's ventilation rate, and to a small degree the elevation of the area. Once this information is assembled, the ODH classification can be determined through standardized calculations. The platform area under the D0 detector contains much of the cryogenic and gas system piping necessary for the D0 experiment. Prior to moving the detector into the Collision Hall, the liquid argon calorimeters are cooled down and operated in the Assembly Hall. The first phase of this operation involved the cooldown of the Central Calorimeter, which was done in February 1991. This engineering note assesses the increased risk to personnel in the platform level to a reduced oxygen atmosphere during the cool down and subsequent operation of the calorimeters in the Assembly Hall. In addition, it outlines the steps taken to warn personnel of an emergency and to direct the subsequent evacuation. This note analyses only the Assembly Hall area. A similar engineering note, EN-332, covers the analysis of the Collision Hall area.

  18. Ultrafast Photooxidation of Mn(II)-Terpyridine Complexes Covalently Attached to TiO2 Nanoparticles

    E-Print Network [OSTI]

    -energy conversion by dye-sensitized solar cells,1,2 photocatalysis,3-6 and molecular electronics.7,8 Most previous-cost, high-efficiency solar cell based on Ru-dye sensitization of colloidal TiO2 films.1 Presently, the most studies have been focused on TiO2 nanoparticles sensitized with Ru dyes,9,10 although IET in other

  19. Fuel and Fuel Additive Registration Testing of Ethanol-Diesel Blend for O2Diesel, Inc.

    SciTech Connect (OSTI)

    Fanick, E. R.

    2004-02-01T23:59:59.000Z

    O2 Diesel Inc. (formerly AAE Technologies Inc.) tested a heavy duty engine with O2Diesel (diesel fuel with 7.7% ethanol and additives) for regulated emissions and speciation of vapor-phase and semi-volatile hydrocarbon compounds. This testing was performed in support of EPA requirements for registering designated fuels and fuel additives as stipulated by sections 211(b) and 211(e) of the Clean Air Act.

  20. Electrochemical Properties of Disordered-Carbon-Coated SnO2 Nanoparticles for Li Rechargeable Batteries

    E-Print Network [OSTI]

    Park, Byungwoo

    Batteries Taeho Moon, Chunjoong Kim, Sun-Tae Hwang, and Byungwoo Park*,z School of Materials Science batteries.1-5 It is rationalized that the reactions of SnO2 with lithium are SnO2 + 4Li Sn + 2Li2O and Sn is to distribute nanoparticles uniformly on a large matrix such as graphite, mesoporous carbon, etc.12,13 However

  1. Composite oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05T23:59:59.000Z

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  2. Results from ORNL characterization of ZrO2-500-AK2 - surrogate TRISO material

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Hunn, John D [ORNL

    2005-06-01T23:59:59.000Z

    This document is a compilation of the characterization data for the TRISO-coated surrogate particles designated ZrO2-500-AK2 that was produced at Oak Ridge National Laboratory (ORNL) as part of the Advanced Gas Reactor Fuel Development and Qualification (AGR) program. The ZrO2-500-AK2 material contains nominally 500 {micro}m kernels of yttria-stabilized zirconia (YSZ) coated with all TRISO layers (buffer, inner pyrocarbon, silicon carbide, and outer pyrocarbon). The ZrO2-500-AK2 material was created for: (1) irradiation testing in the High Flux Isotope Reactor (HFIR) and (2) limited dissemination to laboratories as deemed appropriate to the AGR program. This material was created midway into a TRISO fuel development program to accommodate a sudden opportunity to perform irradiation testing on surrogate material. While the layer deposition processes were chosen based on the best technical understanding at the time, technical progress at ORNL has led to an evolution in the perceived optimal deposition conditions since the creation of ZrO2-500-AK2. Thus, ZrO2-500-AK2 contains a reasonable TRISO microstructure, but does differ significantly from currently produced TRISO surrogates and fuel at ORNL. In this document, characterization data of the ZrO2-500-AK2 surrogate includes: size, shape, coating thickness, and density.

  3. Composite WO3/TiO2 nanostructures for high electrochromic activity.

    SciTech Connect (OSTI)

    Reyes, Karla Rosa; Stephens, Zachary Dan.; Robinson, David B.

    2013-05-01T23:59:59.000Z

    A composite material consisting of TiO2 nanotubes (NTs) with WO3 electrodeposited homogeneously on its surface has been fabricated, detached from its substrate, and attached to a fluorine-doped tin oxide film on glass for application to electrochromic (EC) reactions. A paste of TiO2 made from commercially available TiO2 nanoparticles creates an interface for the TiO2 NT film to attach to the FTO glass, which is conductive and does not cause solution-phase ions in an electrolyte to bind irreversibly with the material. The effect of NT length on the current density and the EC contrast of the material were studied. The EC redox reaction seen in this material is diffusion- limited, having relatively fast reaction rates at the electrode surface. The composite WO3/TiO2 nanostructures showed higher ion storage capacity, better stability, enhanced EC contrast and longer memory time compared with the pure WO3 and TiO2.

  4. Deep observations of O2 toward a low-mass protostar with Herschel-HIFI

    E-Print Network [OSTI]

    Y?ld?z, Umut A; Goldsmith, Paul F; van Dishoeck, Ewine F; Melnick, Gary; Snell, Ronald; Liseau, Rene; Chen, Jo-Hsin; Pagani, Laurent; Bergin, Edwin; Caselli, Paola; Herbst, Eric; Kristensen, Lars E; Visser, Ruud; Lis, Dariusz C; Gerin, Maryvonne

    2013-01-01T23:59:59.000Z

    According to traditional gas-phase chemical models, O2 should be abundant in molecular clouds, but until recently, attempts to detect interstellar O2 line emission with ground- and space-based observatories have failed. Following the multi-line detections of O2 with low abundances in the Orion and rho Oph A molecular clouds with Herschel, it is important to investigate other environments, and we here quantify the O2 abundance near a solar-mass protostar. Observations of O2, at 487 GHz toward a deeply embedded low-mass Class 0 protostar, NGC 1333-IRAS 4A, are presented, using the HIFI instrument on the Herschel Space Observatory. Complementary data of the chemically related NO and CO molecules are obtained as well. The high spectral resolution data are analysed using radiative transfer models to infer column densities and abundances, and are tested directly against full gas-grain chemical models. The deep HIFI spectrum fails to show O2 at the velocity of the dense protostellar envelope, implying one of the low...

  5. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas

    2005-09-30T23:59:59.000Z

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

  6. Efficiency of clay-TiO2 nanocomposites on the photocatalytic elimination of a model hydrophobic air pollutant

    E-Print Network [OSTI]

    Kibanova, Daria

    2010-01-01T23:59:59.000Z

    Paris - Chemistry 2000, 3, 405-411. Clay-TiO 2 nanocompositenanocomposites Appl. Clay Sci. 2006, (28) Ooka, C. ;of TiO 2 -pillared clay on adsorption and photocatalysis of

  7. Preparation of TiO2(110)-(1x1) Surface via UHV Cleavage: An scanning...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preparation of TiO2(110)-(1x1) Surface via UHV Cleavage: An scanning tunneling microscopy study. Preparation of TiO2(110)-(1x1) Surface via UHV Cleavage: An scanning tunneling...

  8. Mineralization of Basalts in the CO2-H2O-SO2-O2 System. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SO2-O2 System. Mineralization of Basalts in the CO2-H2O-SO2-O2 System. Abstract: Sequestering carbon dioxide (CO2) containing minor amounts of co-contaminants in geologic...

  9. DFT-MD approach to TiO2/liquid interface systems for photocatalysis and dye-sensitised solar cell

    E-Print Network [OSTI]

    Katsumoto, Shingo

    DFT-MD approach to TiO2/liquid interface systems for photocatalysis and dye-sensitised solar cell- namics (MD) analysis of TiO2/solution in- terfaces related to photocatalysis and dye- sensitized solar

  10. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

    2011-03-22T23:59:59.000Z

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  11. Electrochemical studies of quinone oxygen

    SciTech Connect (OSTI)

    Deanhardt, M.L. (Lander College, Greenwood, SC (US)); Mushrush, G.W.; Stalick, W.M. (Chemistry Dept., George mason Univ., Fairfax, VA (US)); Watkins, J.M. Jr. (Naval Research Lab., Fuels Section, Code 6180, Washington, DC (US))

    1990-02-01T23:59:59.000Z

    Asphaltenes are a chemically complex mixture of aromatic and heteroaromatic compounds. This material contains oxygen in various functional groups. The distribution includes esters, carboxylic acids, phenolic and most probably quinone type oxygen functionalities. The present work details the complete electrochemical behaviour of quinone type oxygen. The method is quinone specific. A condensed aromatic quinone, 9,10-anthraquinone, was selected as representative of complex quinones. By this method quinones can be determined in the presence of other oxygen functional groups, alcohols, carboxylic acids, ethers, and other carbonyls.

  12. Integrated feature scale modeling of plasma processing of porous and solid SiO2 . I. Fluorocarbon etching

    E-Print Network [OSTI]

    Kushner, Mark

    Integrated feature scale modeling of plasma processing of porous and solid SiO2 . I. Fluorocarbon these issues, reaction mechanisms for fluorocarbon plasma etching of SiO2 in C2F6 , CHF3 , and C4F8 chemistries typically involve SiO2 based materials which are etched in fluorocarbon plasmas.6,7 Porous SiO2 PS is one

  13. Photodissociation of Ozone from 321 to 329 nm: The Relative Yields P2) with O2(X 3

    E-Print Network [OSTI]

    Houston, Paul L.

    Photodissociation of Ozone from 321 to 329 nm: The Relative Yields of O(3 P2) with O2(X 3 g - ), O2 Supporting Information ABSTRACT: Product imaging of O(3 P2) following dissociation of ozone has been used to determine the relative yields of the product channels O(3 P2) + O2(X 3 g - ) of ozone. All three channels

  14. Increasing the Conversion Efficiency of Dye-Sensitized TiO2 Photoelectrochemical Cells by Coupling to Photonic Crystals

    E-Print Network [OSTI]

    The mechanism of enhancing the light harvesting efficiency of dye-sensitized TiO2 solar cells by coupling TiO2Increasing the Conversion Efficiency of Dye-Sensitized TiO2 Photoelectrochemical Cells by Coupling to conventional single-crystal solar cells. In this cell, an optically excited dye injects electrons

  15. DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural and Surface

    E-Print Network [OSTI]

    Lin, Zhiqun

    DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural employed to substitute TiO2 nanoparticles for use in dye-sensitized solar cells. To fur- ther improve the performance of dye-sensitized TiO2 nanotube solar cells, efforts have been directed toward the optimization

  16. Low-Temperature Desorption of N2O from NO on Rutile TiO2(110...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Desorption of N2O from NO on Rutile TiO2(110)-1x1. Low-Temperature Desorption of N2O from NO on Rutile TiO2(110)-1x1. Abstract: We find that NO dosed on rutile TiO2(110)-1×1...

  17. NOx/O2 Sensors for High-Temperature Applications | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a combustion chamber without the requirement of a reference air supply. Placement in combustion chamber provide accurate oxygen-sensing, extremely low drift 2-10% energy...

  18. Role of Water in Methanol Photochemistry on Rutile TiO2(110)...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methanol photochemistry or thermal decomposition of methanol to methoxy. However, terminal OH groups (OHt), prepared by coadsorption of water and oxygen atoms, thermally...

  19. Acetone Chemistry on Oxidized and Reduced TiO2(110). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy loss spectroscopy (HREELS). The reduced surface was prepared with about 7% oxygen vacancy sites by annealing in ultrahigh vacuum (UHV) at 850 K, and the oxidized...

  20. Effects of electrolyte salts on the performance of Li-O2 batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Burton, Sarah D.; Cosimbescu, Lelia; Gross, Mark E.; Zhang, Jiguang

    2013-02-05T23:59:59.000Z

    It is well known that the stability of nonaqueous electrolyte is critical for the rechargeable Li-O2 batteries. Although stability of many solvents used in the electrolytes has been investigated, considerably less attention has been paid to the stability of electrolyte salt which is the second major component. Herein, we report the systematic investigation of the stability of seven common lithium salts in tetraglyme used as electrolytes for Li-O2 batteries. The discharge products of Li-O2 reaction were analyzed by X-ray diffraction, X-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy. The performance of Li-O2 batteries was strongly affected by the salt used in the electrolyte. Lithium tetrafluoroborate (LiBF4) and lithium bis(oxalato)borate (LiBOB) decompose and form LiF and lithium borates, respectively during the discharge of Li-O2 batteries. Several other salts, including lithium bis(trifluoromethane)sulfonamide (LiTFSI), lithium trifluoromethanesulfonate (LiTf), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4) , and lithium bromide (LiBr) led to the discharge products which mainly consisted of Li2O2 and only minor signs of decomposition of LiTFSI, LiTf, LPF6 and LiClO4 were detected. LiBr showed the best stability during the discharge process. As for the cycling performance, LiTf and LiTFSI were the best among the studied salts. In addition to the instability of lithium salts, decomposition of tetraglyme solvent was a more significant factor contributing to the limited cycling stability. Thus a more stable nonaqueous electrolyte including organic solvent and lithium salt still need to be further developed to reach a fully reversible Li-O2 battery.

  1. Atmospheric Transport of Radionuclides

    SciTech Connect (OSTI)

    Crawford, T.V.

    2003-03-03T23:59:59.000Z

    The purpose of atmospheric transport and diffusion calculations is to provide estimates of concentration and surface deposition from routine and accidental releases of pollutants to the atmosphere. This paper discusses this topic.

  2. How atmospheric ice forms | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atmospheric ice forms How atmospheric ice forms Released: September 08, 2014 New insights into atmospheric ice formation could improve climate models This study advances our...

  3. Atmospheric Pressure Reactor System | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Pressure Reactor System Atmospheric Pressure Reactor System The atmospheric pressure reactor system is designed for testing the efficiency of various catalysts for the...

  4. Climate Sciences: Atmospheric Thermodynamics

    E-Print Network [OSTI]

    Russell, Lynn

    1 Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http://aerosol.ucsd.edu/courses.html Text: Curry & Webster Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 Energy Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http

  5. Controls on Soluble Pu Concentrations in PuO2/Magnetite Suspensions

    SciTech Connect (OSTI)

    Felmy, Andrew R.; Moore, Dean A.; Pearce, Carolyn I.; Conradson, Steven D.; Qafoku, Odeta; Buck, Edgar C.; Rosso, Kevin M.; Ilton, Eugene S.

    2012-11-06T23:59:59.000Z

    Time-dependent reduction of PuO2(am) was studied over a range of pH values in the presence of aqueous Fe(II) and magnetite (Fe3O4) nanoparticles. At early time frames (up to 56 days) very little aqueous Pu was mobilized from PuO2(am), even though measured pH and redox potentials, coupled to equilibrium thermodynamic modeling indicated the potential for significant reduction of PuO2(am) to relatively soluble Pu(III). Introduction of Eu(III) or Nd(III) to the suspensions as competitive cations to displace possible sorbed Pu(III) resulted in the release of significant concentrations of aqueous Pu. However, the similarity of aqueous Pu concentrations that resulted from the introduction of Eu(III)/Nd(III) to suspensions with and without magnetite indicated that the Pu was displaced from the PuO2(am), not from magnetite. The fact that soluble forms of Pu can be displaced from the surface of PuO2(am) represents a potential, but previously unidentified, source of Pu to aqueous solution or subsurface groundwaters.

  6. Oxygen detection using evanescent fields

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

    2007-08-28T23:59:59.000Z

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  7. A review of the environmental behavior and fate of fuel oxygenates

    SciTech Connect (OSTI)

    Squillace, P.J.

    1995-12-31T23:59:59.000Z

    The ways in which fuel oxygenate compounds behave in water, soil, and air are determined by how they partition among the different media. The behavior of a gasoline oxygenate in water is affected by the oxygenate`s (1) solubility in water from gasoline: (2) partitioning between water and soil materials; and (3) partitioning between air and water. Water in equilibrium with oxygenated gasoline can contain high concentrations of the oxygenate. For example, at room temperature water solubility of methyl tert-butyl ether (MTBE) will be about 5,000 mg/L for a gasoline that is 10% MTBE by weight. In contrast, the total hydrocarbon solubility in water is typically about 120 mg/L for nonoxygenated gasoline. Fuel oxygenates sorb only weakly to soil and aquifer materials. Therefore, sorption to these materials will not significantly retard their transport by ground water. Fuel oxygenates tend to partition into atmospheric water, including precipitation. For example, washout of gas-phase MTBE by precipitation would not, by itself, greatly alter the gas-phase concentration of the compound in the atmosphere. Nevertheless, the partitioning of MTBE to precipitation is strong enough to allow for submicrogram per liter to 3 pg/L or more inputs of MTBE to ground water and surface water. Occurrence data for MTBE in water and air supports partition theoretical calculations. MTBE and other alkyl ether oxygenates have half lives in the atmosphere that range from about 1 to 14 days. These compounds are generally considered recalcitrant in ground water; whereas ethanol and methanol will readily undergo microbial degradation except where present in concentrations toxic to microorganisms.

  8. Low Oxygen Environments in Chesapeake Bay

    E-Print Network [OSTI]

    Boynton, Walter R.

    Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

  9. Mixed oxygen ion/electron-conducting ceramics for oxygen separation

    SciTech Connect (OSTI)

    Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

    1995-05-01T23:59:59.000Z

    Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

  10. Influence of Atomic Layer Deposition Temperatures on TiO2/n-Si MOS Capacitor

    SciTech Connect (OSTI)

    Wei, Daming [Kansas State University; Hossain, T [Kansas State University; Garces, N. Y. [Naval Research Laboratory, Washington, D.C.; Nepal, N. [Naval Research Laboratory, Washington, D.C.; Meyer III, Harry M [ORNL; Kirkham, Melanie J [ORNL; Eddy, C.R., Jr. [Naval Research Laboratory, Washington, D.C.; Edgar, J H [Kansas State University

    2013-01-01T23:59:59.000Z

    This paper reports on the influence of temperature on the structure, composition, and electrical properties of TiO2 thin films deposited on n-type silicon (100) by atomic layer deposition (ALD). TiO2 layers around 20nm thick, deposited at temperatures ranging from 100 to 300 C, were studied. Samples deposited at 250 C and 200 C had the most uniform coverage as determined by atomic force microscopy. The average carbon concentration throughout the oxide layer and at the TiO2/Si interface was lowest at 200 C. Metal oxide semiconductor capacitors (MOSCAPs) were fabricated, and profiled by capacitance-voltage techniques. Negligible hysteresis was observed from a capacitance-voltage plot and the capacitance in the accumulation region was constant for the sample prepared at a 200 C ALD growth temperature. The interface trap density was on the order of 1013 eV-1cm-2 regardless of the deposition temperature.

  11. Dendrimer-Encapsulated Ruthenium Nanoparticles as Catalysts for Lithium-O2 Batteries

    SciTech Connect (OSTI)

    Bhattacharya, Priyanka; Nasybulin, Eduard N.; Engelhard, Mark H.; Kovarik, Libor; Bowden, Mark E.; Li, Shari; Gaspar, Daniel J.; Xu, Wu; Zhang, Jiguang

    2014-12-01T23:59:59.000Z

    Dendrimer-encapsulated ruthenium nanoparticles (DEN-Ru) have been used as catalysts in lithium-O2 batteries for the first time. Results obtained from UV-vis spectroscopy, electron microscopy and X-ray photoelectron spectroscopy show that the nanoparticles synthesized by the dendrimer template method are ruthenium oxide instead of metallic ruthenium reported earlier by other groups. The DEN-Ru significantly improve the cycling stability of lithium (Li)-O2 batteries with carbon black electrodes and decrease the charging potential even at low catalyst loading. The monodispersity, porosity and large number of surface functionalities of the dendrimer template prevent the aggregation of the ruthenium nanoparticles making their entire surface area available for catalysis. The potential of using DEN-Ru as stand-alone cathode materials for Li-O2 batteries is also explored.

  12. Terrestrial Planet Atmospheres. The Moon's Sodium Atmosphere

    E-Print Network [OSTI]

    Walter, Frederick M.

    ;Origins of Atmospheres · Outgassing ­ Volcanoes expel water, CO2, N2, H2S, SO2 removed by the Fme convecFon reaches deserts #12;Water and Ice Clouds #12;H2SO4

  13. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

  14. Economic Analysis for Conceptual Design of Supercritical O2-Based PC Boiler

    SciTech Connect (OSTI)

    Andrew Seltzer; Archie Robertson

    2006-09-01T23:59:59.000Z

    This report determines the capital and operating costs of two different oxygen-based, pulverized coal-fired (PC) power plants and compares their economics to that of a comparable, air-based PC plant. Rather than combust their coal with air, the oxygen-based plants use oxygen to facilitate capture/removal of the plant CO{sub 2} for transport by pipeline to a sequestering site. To provide a consistent comparison of technologies, all three plants analyzed herein operate with the same coal (Illinois No 6), the same site conditions, and the same supercritical pressure steam turbine (459 MWe). In the first oxygen-based plant, the pulverized coal-fired boiler operates with oxygen supplied by a conventional, cryogenic air separation unit, whereas, in the second oxygen-based plant, the oxygen is supplied by an oxygen ion transport membrane. In both oxygen-based plants a portion of the boiler exhaust gas, which is primarily CO{sub 2}, is recirculated back to the boiler to control the combustion temperature, and the balance of the flue gas undergoes drying and compression to pipeline pressure; for consistency, both plants operate with similar combustion temperatures and utilize the same CO{sub 2} processing technologies. The capital and operating costs of the pulverized coal-fired boilers required by the three different plants were estimated by Foster Wheeler and the balance of plant costs were budget priced using published data together with vendor supplied quotations. The cost of electricity produced by each of the plants was determined and oxygen-based plant CO{sub 2} mitigation costs were calculated and compared to each other as well as to values published for some alternative CO{sub 2} capture technologies.

  15. Site-Specific Imaging of Elemental Steps in Dehydration of Diols on TiO2(110)

    SciTech Connect (OSTI)

    Acharya, Danda P.; Yoon, Yeohoon; Li, Zhenjun; Zhang, Zhenrong; Lin, Xiao; Mu, Rentao; Chen, Long; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek

    2013-11-26T23:59:59.000Z

    The conversion of diols on partially reduced TiO2(110) at low coverage was studied using variable-temperature scanning tunneling microscopy, temperature programmed desorption and density functional theory calculations. We find, that below ~230 K, ethane-1,2-diol and propane-1,3-diol molecules adsorb predominantly on five-fold coordinated Ti5c atoms. The dynamic equilibrium between molecularly bound and dissociated species resulting from O-H bond scission and reformation is observed. As the diols start to diffuse on the Ti5c rows above ~230 K, they dissociate irreversibly upon encountering bridging oxygen (Ob) vacancy (VO’s) defects. Two dissociation pathways, one via O-H and the other via C-O bond scission leading to identical surface intermediates, hydroxyalkoxy, Ob-(CH2)n-OH (n = 2, 3) and bridging hydroxyl, HOb, are seen. For O-H bond scission, the Ob-(CH2)n-OH is found on the position of the original VO, while for C-O scission it is found on the adjacent Ob site. Theoretical calculations suggest that the observed mixture of C-O/O-H bond breaking processes are a result of the steric factors enforced upon the diols by the second OH group that is bound to a Ti5c site. At room temperature, rich dissociation/reformation dynamics of the second, Ti5c-bound O-H leads to the formation of dioxo, Ob-(CH2)n-OTi, species. Above ~400 K, both Ob-(CH2)n-OH and Ob-(CH2)n-OTi species convert into a new intermediate, that is centered on Ob row. Combined experimental and theoretical evidence shows that this intermediate is most likely a new dioxo, Ob-(CH2)2-Ob, species. Further annealing leads to sequential C-Ob bond cleavage and alkene desorption above ~ 500 K. Simulations find that the sequential C-O bond breaking process follows a homolytic diradical pathway with the first C-O bond breaking event accompanied by a non-adiabatic electron transfer within the TiO2(110) substrate.

  16. The Effects of Oxygen Partial Pressure on Liquidus Temperature of a High-Level Waste Glass with Spinel as the Primary Phase

    SciTech Connect (OSTI)

    Izak, Pavel; Hrma, Pavel R.; Wilson, Benjamin K.; Vienna, John D.

    2000-04-07T23:59:59.000Z

    The redox state of iron affects spinal crystallization in vitrified high-level waste (HLW) glass. Simulated HLW glass with spinel as the primary crystalline phase field was heat treated at constant temperatures within the interval from 850 C to 1300 C under varying atmospheres with oxygen partial pressure, Po2, ranging from 1x10-16 kPa (pure CO) to 101 kPa (pure O2). Liquidus temperature (TL) of glass increased with decreasing Po2 up to Po2 > 3 x 10-9 kPa. At Po2 < 3 x 10-9 kPa, Ni-Fe alloy precipitated from the glass, and TL decreased. Samples were analyzed with optical microscope and scanning electron microscope. The mass fraction of spinel in glass was determined using quantitative X-ray diffraction. Spinel composition was investigated with energy disperse spectroscopy. Ferrous-ferric equilibrium at TL was calculated in a HLW glass as a function of temperature and Po2, based on the previous studies by Schreiber. TL/FeO over the itnerval 0.0063 < gFeO < 0.051 (1x10-2 kPa < Po2 < 3x10-9 kPa) was estimated from calucated ferrous-ferric equilibrium at TL as 1835 C.

  17. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D.

    2009-10-01T23:59:59.000Z

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

  18. OXYGEN DIFFUSION IN UO2-x

    E-Print Network [OSTI]

    Kim, K.C.

    2013-01-01T23:59:59.000Z

    ~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

  19. Oxygen transfer in the implant environment

    E-Print Network [OSTI]

    Goor, Jared Braden

    2007-01-01T23:59:59.000Z

    Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

  20. Stabilization of CO2 Atmospheres on Exoplanets around M Dwarf Stars

    E-Print Network [OSTI]

    Gao, Peter; Robinson, Tyler D; Li, Cheng; Yung, Yuk L

    2015-01-01T23:59:59.000Z

    We investigate the chemical stability of CO2-dominated atmospheres of M dwarf terrestrial exoplanets using a 1-dimensional photochemical model. On planets orbiting Sun-like stars, the photolysis of CO2 by Far-UV (FUV) radiation is balanced by the reaction between CO and OH, the rate of which depends on H2O abundance. By comparison, planets orbiting M dwarf stars experience higher FUV radiation compared to planets orbiting Sun-like stars, and they are also likely to have low H2O abundance due to M dwarfs having a prolonged, high-luminosity pre-main sequence (Luger & Barnes 2015). We show that, for H2O-depleted planets around M dwarfs, a CO2-dominated atmosphere is stable to conversion to CO and O2 by relying on a catalytic cycle involving H2O2 photolysis. However, this cycle breaks down for planets with atmospheric hydrogen mixing ratios below ~1 ppm, resulting in ~40% of the atmospheric CO2 being converted to CO and O2 on a time scale of 1 Myr. The increased abundance of O2 also results in high O3 concent...

  1. MODELLING MODIFIED ATMOSPHERE PACKAGING FOR FRUITS AND VEGETABLES USING MEMBRANE SYSTEMS

    E-Print Network [OSTI]

    Hinze, Thomas

    of polymeric film in or- der to modify the O2 and CO2 concentrations inside the package, reducing metabolic are not fully under- stood. As examples we can refer to the little knowl- edge about the effect of CO2MODELLING MODIFIED ATMOSPHERE PACKAGING FOR FRUITS AND VEGETABLES USING MEMBRANE SYSTEMS Gabi

  2. PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux

    E-Print Network [OSTI]

    Mallin, Michael

    PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

  3. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07T23:59:59.000Z

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  4. Extracorporeal membrane oxygenation promotes long chain fatty...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

  5. Electrocatalytic Reactivity for Oxygen Reduction of Palladium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

  6. OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE

    E-Print Network [OSTI]

    Kim, Kee Chul

    2010-01-01T23:59:59.000Z

    Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

  7. Formation, characterization and reactivity of adsorbed oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

  8. Angling chromium to let oxygen through | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Angling chromium to let oxygen through Angling chromium to let oxygen through Released: September 10, 2014 New semiconducting material works at lower temperatures Scanning...

  9. Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

    E-Print Network [OSTI]

    VanVeller, Brett

    The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

  10. Antioxidant and Antiradical SiO2 Nanoparticles Covalently Functionalized with Gallic Acid

    E-Print Network [OSTI]

    Daraio, Chiara

    Antioxidant and Antiradical SiO2 Nanoparticles Covalently Functionalized with Gallic Acid Yiannis with no impairment of their RSC. KEYWORDS: nanoantioxidant, DPPH radical, gallic acid, grafting, nanoparticle Zurich, Switzerland *S Supporting Information ABSTRACT: Gallic acid (GA) and its derivatives are natural

  11. NOx-Mediated Homogeneous Pathways for the Synthesis of Formaldehyde from CH4-O2 Mixtures

    E-Print Network [OSTI]

    Iglesia, Enrique

    CH4 conversion, because weaker C-H bonds in HCHO and CH3OH relative to CH4 lead to their fast that the O2 distribution along a reactor will not improve HCHO yields but may prove useful to inhibit NOx losses to less reactive N-compounds. 1. Introduction The practical conversion of remote natural gas

  12. Adsorption of Nucleic Acid Components on Rutile (TiO2) Surfaces

    E-Print Network [OSTI]

    Sverjensky, Dimitri A.

    Adsorption of Nucleic Acid Components on Rutile (TiO2) Surfaces H. James Cleaves II,1 Caroline M and horizontal gene transfer. The adsorption of mono-, oligo-, and polynucleotides and their components obtained from studies of other minerals. In contrast with recent studies of nucleotide adsorption on Zn

  13. StatetoState Quantum Dynamics of O + O2 Isotope Exchange

    E-Print Network [OSTI]

    Maccabe, Barney

    StatetoState Quantum Dynamics of O + O2 Isotope Exchange Reactions Reveals Non body (M). An in depth understanding of the bimolecular isotope exchange reactions will shed light on the surprising and significant enrichment of heavy ozone isotopomers discovered in the stratosphere more than

  14. Short communication TiO2 nanoparticles-decorated carbon nanotubes for significantly improved

    E-Print Network [OSTI]

    Short communication TiO2 nanoparticles-decorated carbon nanotubes for significantly improved-Remediation and Pollution Control, Nanchang Hangkong University, Nanchang 330063, China h i g h l i g h t s g r a p h i c Carbon nanotube Microbial fuel cell a b s t r a c t A facile and reliable method has been developed

  15. SnO2 Filled Mesoporous Tin Phosphate High Capacity Negative Electrode for Lithium Secondary Battery

    E-Print Network [OSTI]

    Cho, Jaephil

    SnO2 Filled Mesoporous Tin Phosphate High Capacity Negative Electrode for Lithium Secondary Battery insulators, and optics.1-6 On the other hand, their applications to electrode materials in lithium secondary batteries have received little attention because of the very limited candidates.7,8 Recently

  16. Branched CNT@SnO2 nanorods@carbon hierarchical heterostructures for lithium ion

    E-Print Network [OSTI]

    Qi, Limin

    highly reversible lithium storage behavior and excellent rate capability. The reversible capacity diffusivity and electronic conductivity, which is unfavorable for its applications in high-power devices. Designing hybrid materials of SnO2 nanostructures with carbon-based materials with desirable structures

  17. Mechanism of O2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)PtII

    E-Print Network [OSTI]

    Goddard III, William A.

    Mechanism of O2 Activation and Methanol Production by (Di(2- pyridyl)methanesulfonate)PtII Me observed for the SN2 functionalization to form methanol by two isomeric (dpms)PtIV Me(OH)2 complexes, one conversion of methane to methanol at low temper- ature is crucial for transportation of shale gas produced

  18. Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications

    E-Print Network [OSTI]

    Cao, Guozhong

    by anodic oxidation of titanium foil followed with O2 and CO annealing were employed as matrices nanostructures by means of acidic anodization of titanium foils.14,15 The diameters and lengths of the TNT can bone­implant inter- actions. In addition, doping with nitrogen, carbon, and boron has been reported

  19. Scanning tunneling microscopic studies of SiO2 thin film supported metal nano-clusters

    E-Print Network [OSTI]

    Min, Byoung Koun

    2005-11-01T23:59:59.000Z

    synthesized on a Mo(112) single crystal. The electronic and geometric structure of the SiO2 thin film was investigated by STM combined with LEED, Auger electron spectroscopy (AES), and X-ray photoelectron spectroscopy (XPS). The relationship between defects...

  20. A MICROSTRUCTURED CATHODE FOR FUEL CELL WITH SELF-REGULATED O2 BUBBLE CREATION AND CONSUMPTION

    E-Print Network [OSTI]

    pumping mechanism [1]. In the bubble pumping mechanism, carbon dioxide generated inside the anodic channel forms bubbles that fill the channel and directionally grow away from the check valve. The carbon dioxideA MICROSTRUCTURED CATHODE FOR FUEL CELL WITH SELF-REGULATED O2 BUBBLE CREATION AND CONSUMPTION

  1. Effect of Niobium on the Defect Chemistry and Oxidation Kinetics of Tetragonal ZrO2

    E-Print Network [OSTI]

    Yildiz, Bilge

    Effect of Niobium on the Defect Chemistry and Oxidation Kinetics of Tetragonal ZrO2 Uuganbayar, Massachusetts 02139, United States ABSTRACT: Zirconium-niobium alloys are currently proposed for applications the effect of an extrinsic defect, niobium (Nb) dopant, on the defect equilibria and charge transfer

  2. Most of the world's titanium output is refined into titanium dioxide (TiO2

    E-Print Network [OSTI]

    Torgersen, Christian

    Most of the world's titanium output is refined into titanium dioxide (TiO2 ), which is used to give.S. Geological Survey (USGS) supports science to understand · How and where titanium resources form and concentrate in the Earth's crust · How titanium resources interact with the environment to affect human

  3. Deposition dynamics and chemical properties of size-selected Ir clusters on TiO2

    E-Print Network [OSTI]

    Anderson, Scott L.

    reserved. Keywords: Iridium; Clusters; Titanium oxide; X-ray photoelectron spectroscopy; Low energy ion report a study of Irn/TiO2 samples prepared by size and energy-selected deposition of Irþ n (n ¼ 1, 2, 5 in the zero oxidation state, and there are no significant shifts in Ir 4f binding energy with cluster size

  4. Dopant location identification in Nd3+ -doped TiO2 nanoparticles

    E-Print Network [OSTI]

    Frenkel, Anatoly

    Dopant location identification in Nd3+ -doped TiO2 nanoparticles W. Li Department of Materials. The identification of dopant position and its local environ- ment are essential to explore the effect of doping. X and Technology, Gaithersburg, Maryland 20899, USA C. Ni Department of Materials Science and Engineering

  5. Photoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2 nanocomposite

    E-Print Network [OSTI]

    coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resourcesPhotoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2

  6. Formation of Calcium Phosphate Whiskers in Hydrogen Peroxide (H2O2) Solutions at 901C

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    )2) powders were aged in unstirred 30% H2O2 solutions at 901C for 48 h in ordinary glass media bottlesH, Buchs, Switzerland) were placed in a 250 mL capacity Pyrex s glass media bottle (Catalog No: 215 into the bottle. The bottle was tight- ly capped and manually shaken for 1 min, followed by keeping the bottle

  7. Formation of CO precursors during char gasification with O2, CO2 and H2O

    E-Print Network [OSTI]

    Truong, Thanh N.

    Formation of CO precursors during char gasification with O2, CO2 and H2O Alejandro Montoya a are presented to get insight into an unified mechanism of uncatalyzed carbon gasification. D 2002 Elsevier Science B.V. All rights reserved. Keywords: Gasification; Chemisorption; Molecular simulation; Surface

  8. Enhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2 Nanotubes

    E-Print Network [OSTI]

    Cao, Guozhong

    -called third generation of solar cells including dye-sensitized solar cells, DSCs2,3 and organic phoEnhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2 nanotubes can be effectively controlled for the suitable use for a hybrid solar cell by varying the diameter

  9. Hierarchical TiO2Si nanowire architecture with photoelectrochemical activity under visible light illumination

    E-Print Network [OSTI]

    Wang, Xudong

    systems are currently less competitive than common solar panels, which to a great extent limits decoration approach opens a new window to tailoring electrical properties of TiO2 for wider spectrum solar energy harvesting and conversion. Owing to the abundance, cleanness, potentially low-cost

  10. Optical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry

    E-Print Network [OSTI]

    to the solar spectrum.3 A natural dielectric to consider is to encapsulate these metal clusters supported on TiOptical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry Fei WangV range, a much better match to the solar spectrum than the 3.8 eV Ag plasmon. AFM measurements indicate

  11. Inorganic-modified semiconductor TiO2 nanotube arrays for photocatalysis

    E-Print Network [OSTI]

    Lin, Zhiqun

    Inorganic-modified semiconductor TiO2 nanotube arrays for photocatalysis Mengye Wang,ab James Ioccozia,b Lan Sun,*a Changjian Lin*a and Zhiqun Lin*b Semiconductor photocatalysis is a promising resistance, and nontoxicity. This Review briefly introduces the key mechanisms of photocatalysis, highlights

  12. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01T23:59:59.000Z

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  13. Probing the Failure Mechanism of SnO2 Nanowires for Sodium-ion Batteries

    SciTech Connect (OSTI)

    Gu, Meng; Kushima, Akihiro; Shao, Yuyan; Zhang, Jiguang; Liu, Jun; Browning, Nigel D.; Li, Ju; Wang, Chong M.

    2013-09-30T23:59:59.000Z

    Non-lithium metals such as sodium have attracted wide attention as a potential charge carrying ion for rechargeable batteries, performing the same role as lithium in lithium- ion batteries. As sodium and lithium have the same +1 charge, it is assumed that what has been learnt about the operation of lithium ion batteries can be transferred directly to sodium batteries. Using in-situ TEM, in combination with DFT calculations, we probed the structural and chemical evolution of SnO2 nanowire anodes in Na-ion batteries and compared them quantitatively with results from Li-ion batteries [Science 330 (2010) 1515]. Upon Na insertion into SnO2, a displacement reaction occurs, leading to the formation of amorphous NaxSn nanoparticles covered by crystalline Na2O shell. With further Na insertion, the NaxSn core crystallized into Na15Sn4 (x=3.75). Upon extraction of Na (desodiation), the NaxSn core transforms to Sn nanoparticles. Associated with a volume shrinkage, nanopores appear and metallic Sn particles are confined in hollow shells of Na2O, mimicking a peapod structure. These pores greatly increase electrical impedance, therefore naturally accounting for the poor cyclability of SnO2. DFT calculations indicate that Na+ diffuses 30 times slower than Li+ in SnO2, in agreement with in-situ TEM measurement. Insertion of Na can chemo-mechanically soften the reaction product to greater extent than in lithiation. Therefore, in contrast to the lithiation of SnO2, no dislocation plasticity was seen ahead of the sodiation front. This direct comparison of the results from Na and Li highlights the critical role of ionic size and electronic structure of different ionic species on the charge/discharge rate and failure mechanisms in these batteries.

  14. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

    2003-11-01T23:59:59.000Z

    The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

  15. TiO2-rich reconstructions of SrTiO3(001): a theoretical study of structural patterns

    E-Print Network [OSTI]

    Marks, Laurence D.

    . In the present work we use density functional theory to generate a number of variations of this structural motif in the ability of oxygen atoms to relax vertically out of the overlayer plane to minimize non-bonded oxygen­oxygen repulsions. Out-of-plane relaxation of oxygen atoms in turn is modulated by the number and relative position

  16. EMSL - Atmospheric Aerosol Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scienceatmospheric The Atmospheric Aerosol Systems Science Theme focuses on understanding the chemistry, physics and molecular-scale dynamics of aerosols for model...

  17. Atmospheric Neutrino Fluxes

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2005-02-18T23:59:59.000Z

    Starting with an historical review, I summarize the status of calculations of the flux of atmospheric neutrinos and how they compare to measurements.

  18. Soot formation and temperature structure in small methane-oxygen diffusion flames at subcritical and supercritical pressures

    SciTech Connect (OSTI)

    Joo, Hyun I.; Guelder, Oemer L. [University of Toronto, Institute for Aerospace Studies, 4925 Dufferin Street, Toronto, Ont. (Canada)

    2010-06-15T23:59:59.000Z

    An experimental study was conducted to examine the characteristics of laminar methane-oxygen diffusion flames up to 100 atmospheres. The influence of pressure on soot formation and on the structure of the temperature field was investigated over the pressure range of 10-90 atmospheres in a high-pressure combustion chamber using a non-intrusive, line-of-sight spectral soot emission diagnostic technique. Two distinct zones characterized the appearance of a methane and pure oxygen diffusion flame: an inner luminous zone similar to the methane-air diffusion flames, and an outer diffusion flame zone which is mostly blue. The flame height, marked by the visible soot radiation emission, was reduced by over 50% over the pressure range of 10-100 atmospheres. Between 10 and 40 atmospheres, the soot levels increased with increasing pressure; however, above 40 atmospheres the soot concentrations decreased with increasing pressure. (author)

  19. Laser diagnostics of pulverized coal combustion in O_2/N_2 and O_2/CO_2 conditions: velocity and scalar field measurements

    E-Print Network [OSTI]

    Balusamy, Saravanan; Kamal, M. Mustafa; Lowe, Steven M.; Tian, Bo; Gao, Yi; Hochgreb, Simone

    2015-05-13T23:59:59.000Z

    (Metz et al. 2005; IEA 2012). Increasing demand for power, especially in developing countries, will lead to a further increase in CO2 emissions and other harmful pollutants. To address the problem, several carbon capture and storage (CCS... ) technologies have been under develop- ment. One of the keys to CCS is the ability to increase CO2 concentrations in the stream gas to make it economical for sequestration. Oxyfuel combustion, where oxygen diluted with exhaust CO2 is used as an oxidizer...

  20. Properties of Reactive Oxygen Species by Quantum Monte Carlo

    E-Print Network [OSTI]

    Andrea Zen; Bernhardt L. Trout; Leonardo Guidoni

    2014-06-16T23:59:59.000Z

    The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of Chemistry, Biology and Atmospheric Science. Nevertheless, the electronic structure of such species is a challenge for ab-initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as $N^3-N^4$, where $N$ is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

  1. Two-stage epitaxial growth of vertically-aligned SnO2 nano-rods on(001) ceria

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Solovyov, Vyacheslav F. [Brookhaven National Lab. (BNL), Upton, NY (United States); Wu, Li-jun [Brookhaven National Lab. (BNL), Upton, NY (United States); Rupich, Martin W. [American Superconductor, Devens, MA (United States); Sathyamurthy, Srivatsan [American Superconductor, Devens, MA (United States); Li, Xiaoping [American Superconductor, Devens, MA (United States); Li, Qiang [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-12-01T23:59:59.000Z

    Growth of high-aspect ratio oriented tin oxide, SnO2, nano-rods is complicated by a limited choice of matching substrates. We show that a (001) cerium oxide, CeO2, surface uniquely enables epitaxial growth of tin-oxide nano-rods via a two-stage process. First, (100) oriented nano-wires coat the ceria surface by lateral growth, forming a uniaxially-textured SnO2 deposit. Second, vertical SnO2nano-rods nucleate on the deposit by homoepitaxy. We demonstrate growth of vertically oriented 1-2 ?m long nano-rods with an average diameter of ?20 nm.

  2. Efficiency of clay-TiO2 nanocomposites on the photocatalytic elimination of a model hydrophobic air pollutant

    E-Print Network [OSTI]

    Kibanova, Daria

    2010-01-01T23:59:59.000Z

    of semiconductor photocatalysis Chem. Rev. 1995, 95, 69-effluents by TiO 2 photocatalysis Catalysis Today 2000, 63,clay on adsorption and photocatalysis of gaseous molecules

  3. Atomic oxygen patterning from a biomedical needle-plasma source

    SciTech Connect (OSTI)

    Kelly, Seán; Turner, Miles M. [School of Physical Science and National Centre for Plasma Science and Technology, Dublin City University, Dublin (Ireland)] [School of Physical Science and National Centre for Plasma Science and Technology, Dublin City University, Dublin (Ireland)

    2013-09-28T23:59:59.000Z

    A “plasma needle” is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  4. High-temperature potentiometric oxygen sensor with internal reference

    DOE Patents [OSTI]

    Routbort, Jules L. (Hinsdale, IL); Singh, Dileep (Naperville, IL); Dutta, Prabir K. (Worthington, OH); Ramasamy, Ramamoorthy (North Royalton, OH); Spirig, John V. (Columbus, OH); Akbar, Sheikh (Hilliard, OH)

    2011-11-15T23:59:59.000Z

    A compact oxygen sensor is provided, comprising a mixture of metal and metal oxide an enclosure containing said mixture, said enclosure capable of isolating said mixture from an environment external of said enclosure, and a first wire having a first end residing within the enclosure and having a second end exposed to the environment. Also provided is a method for the fabrication of an oxygen sensor, the method comprising confining a metal-metal oxide solid mixture to a container which consists of a single material permeable to oxygen ions, supplying an electrical conductor having a first end and a second end, whereby the first end resides inside the container as a reference (PO.sub.2).sup.ref, and the second end resides outside the container in the atmosphere where oxygen partial pressure (PO.sub.2).sup.ext is to be measured, and sealing the container with additional single material such that grain boundary sliding occurs between grains of the single material and grains of the additional single material.

  5. Atmospheric Dynamics II Instructor

    E-Print Network [OSTI]

    AT602 Atmospheric Dynamics II 2 credits Instructor: David W. J. Thompson davet: An Introduction to Dynamic Meteorology, 5th Edition, Academic Press (recommended) · Marshall, J., and Plumb, R. A., 2008: Atmosphere, Ocean, and Climate Dynamics: An Introductory Text, Academic Press. · Vallis, G. K

  6. Atmospheric Thermodynamics Composition

    E-Print Network [OSTI]

    Russell, Lynn

    1 Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 EnergyBalance Ch4 Water Ch Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http #12;2 Review from Ch. 1 · Thermodynamic quantities · Composition · Pressure · Density · Temperature

  7. Oxygen-assisted multipass cutting of carbon fiber reinforced plastics with ultra-short laser pulses

    SciTech Connect (OSTI)

    Kononenko, T. V.; Komlenok, M. S.; Konov, V. I. [Natural Sciences Center, General Physics Institute, Vavilov str. 38, 119991 Moscow (Russian Federation); National Research Nuclear University, “MEPhI,” Kashirskoye shosse 31, 115409 Moscow (Russian Federation); Freitag, C. [Universität Stuttgart, Institut für Strahlwerkzeuge (IFSW), Pfaffenwaldring 43, 70569 Stuttgart (Germany); GSaME Graduate School of Excellence Advanced Manufacturing Engineering, Nobelstrasse 12, 70569 Stuttgart (Germany); Onuseit, V.; Weber, R.; Graf, T. [Universität Stuttgart, Institut für Strahlwerkzeuge (IFSW), Pfaffenwaldring 43, 70569 Stuttgart (Germany)

    2014-03-14T23:59:59.000Z

    Deep multipass cutting of bidirectional and unidirectional carbon fiber reinforced plastics (CFRP) with picosecond laser pulses was investigated in different static atmospheres as well as with the assistance of an oxygen or nitrogen gas flow. The ablation rate was determined as a function of the kerf depth and the resulting heat affected zone was measured. An assisting oxygen gas flow is found to significantly increase the cutting productivity, but only in deep kerfs where the diminished evaporative ablation due to the reduced laser fluence reaching the bottom of the kerf does not dominate the contribution of reactive etching anymore. Oxygen-supported cutting was shown to also solve the problem that occurs when cutting the CFRP parallel to the fiber orientation where a strong deformation and widening of the kerf, which temporarily slows down the process speed, is revealed to be typical for processing in standard air atmospheres.

  8. OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES

    E-Print Network [OSTI]

    Truong, Thanh N.

    OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

  9. Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production

    DOE Patents [OSTI]

    Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

    1988-01-01T23:59:59.000Z

    A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

  10. Atmospheric pressure cold plasma as an antifungal therapy

    SciTech Connect (OSTI)

    Sun Peng; Wu Haiyan [College of Engineering, Peking University, Beijing 100871 (China); Sun Yi; Liu Wei; Li Ruoyu [Department of Dermatology and Venereology, Peking Univ. 1st Hospital and Research Center for Medical Mycology, Peking Univ., Beijing 100034 (China); Zhu Weidong; Lopez, Jose L. [Department of Applied Science and Technology and Center for Microplasma Science and Technology, Saint Peter's College, Jersey City, New Jersey 07306 (United States); Zhang Jue; Fang Jing [College of Engineering, Peking University, Beijing 100871 (China); Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China)

    2011-01-10T23:59:59.000Z

    A microhollow cathode based, direct-current, atmospheric pressure, He/O{sub 2} (2%) cold plasma microjet was used to inactive antifungal resistants Candida albicans, Candida krusei, and Candida glabrata in air and in water. Effective inactivation (>90%) was achieved in 10 min in air and 1 min in water. Antifungal susceptibility tests showed drastic reduction of the minimum inhibitory concentration after plasma treatment. The inactivation was attributed to the reactive oxygen species generated in plasma or in water. Hydroxyl and singlet molecular oxygen radicals were detected in plasma-water system by electron spin resonance spectroscopy. This approach proposed a promising clinical dermatology therapy.

  11. Simultaneous MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis Conditions on Cu/SiO2

    SciTech Connect (OSTI)

    Yang, Yong; Mims, Charles A.; Disselkamp, Robert S.; Peden, Charles HF; Campbell, C. T.

    2009-06-09T23:59:59.000Z

    The coverages and surface lifetimes of copper-bound formates on Cu/SiO2 catalysts, and the steady-state rates of reverse water-gas shift and methanol synthesis have been measured simultaneously by mass (MS) and infrared (IR) spectroscopies under a variety of elevated pressure conditions at temperatures between 140 and 160°C. DCOO lifetimes under steady state catalytic conditions in CO2:D2 atmospheres were measured by 12C – 13C isotope transients (SSITKA). The values range from 220s at 160°C to 660s at 140°C. The catalytic rates of both reverse water gas shift (RWGS) and methanol synthesis are ~100-fold slower than this formate removal rate back to CO2+1/2 H2, and thus they do not significantly influence the formate lifetime or coverage at steady state. The formate coverage is instead determined by formate’s rapid production / decomposition equilibrium with gas phase CO2+H2. The results are consistent with formate being an intermediate in methanol synthesis, but with the rate-controlling step being after formate production (for example, its further hydrogenation to methoxy). A 2-3 fold shorter life time (faster decomposition rate) was observed for formate under reactions conditions when both D2 and CO2 are present than in pure Ar or D2+Ar alone, attributed to effects of coadsorbates (produced in D2 and CO2) on adsorbed formate reaction pathways. The carbon which appears in the methanol product spends a longer time on the surface than the formate species, 1.8 times as long at 140°C. The additional delay on the surface is attributed in part to readsorption of methanol on the catalyst, thus obscuring the mechanistic link between formate and methanol.

  12. Carbon Clusters as Possible Defects in the SiC-SiO2 Interface

    SciTech Connect (OSTI)

    Dang, Hongli [ORNL; Ramkumar, Gudipati [unknown; Yang, Liu [unknown; Li, Ying [ORNL; Peterson, Heather [unknown; Chisholm, Matthew F [ORNL; Biggerstaff, Trinity Leigh [ORNL; Duscher, Gerd [University of Tennessee, Knoxville (UTK); Wang, Sanwu [ORNL

    2009-01-01T23:59:59.000Z

    High state densities in the band gap of the SiC-SiO2 interface significantly reduce the channel mobilities in SiC-based high-temperature/high-power microelectronics. Investigations of the nature of the interface defects are thus of great importance. While several possible defects including very small carbon clusters with up to four carbon atoms have been identified by first-principles theory, larger carbon clusters as possible defects have attracted less attention. Here, we report first-principles quantum-mechanical calculations for two larger carbon clusters, the C10 ring and the C20 fullerence, in the SiC-SiO2 interface. We find that both carbon clusters introduce significant states in the band gap. The states extend over the entire band gap with higher densities in the upper half of the gap, thus accounting for some of the interface trap densities observed experimentally

  13. Mesoporous TiO2-B Microspheres with Superior Rate Performance for Lithium Ion Batteries

    SciTech Connect (OSTI)

    Liu, Hansan [ORNL; Bi, Zhonghe [ORNL; Sun, Xiao-Guang [ORNL; Unocic, Raymond R [ORNL; Paranthaman, Mariappan Parans [ORNL; Dai, Sheng [ORNL; Brown, Gilbert M [ORNL

    2011-01-01T23:59:59.000Z

    Mesoporous TiO2-B microsperes with a favorable material architecture are designed and synthesized for high power lithium ion batteries. This material, combining the advantages of fast lithium transport with a pseudocapacitive mechanism, adequate electrode-electrolyte contact and compact particle packing in electrode layer, shows superior high-rate charge-discharge capability and long-time cyclability for lithium ion batteries.

  14. SnO2:F Coated Duplex Stainless Steel for PEM Fuel Cell Bipolar Plates

    SciTech Connect (OSTI)

    Wang, H.; Turner, J. A.

    2008-01-01T23:59:59.000Z

    Duplex 2205 stainless steel was deposited with 0.6 {micro}m thick SnO2:F coating; coated steel was characterized for PEMFC bipolar plate application. Compared with bare alloy, interfacial contact resistance (ICR) values of the coated 2205 steel are higher. SnO2:F coating adds its own resistance to the air-formed film on the steel. In a PEMFC anode environment, a current peak of ca. 25 {micro}A/cm2 registered at ca. 30 min for coated 2205 steel. It stabilized at ca. 2.0 {approx} -1.0 {micro}A/cm2. This peak is related to the complicated process of coating dissolution and oxide-layer formation. Anodic-cathodic current transfer occurred at ca. 200 min polarization. In a PEMFC cathode environment, current was stable immediately after polarization. The stable current was ca. 0.5 {approx} 2.0 {micro}A/cm2 during the entire polarization period. AES depth profiles with tested samples and ICP analysis with the tested solutions confirmed the excellent corrosion resistance of the SnO2:F coated 2205 alloy in simulated PEMFC environments.

  15. Atomistic Studies of Cation Transport in Tetragonal ZrO2 During Zirconium Corrosion

    SciTech Connect (OSTI)

    Xian-Ming Bai; Yongfeng Zhang; Michael R. Tonks

    2013-10-01T23:59:59.000Z

    Zirconium alloys are the major fuel cladding materials in current reactors. The water-side corrosion is one of the major degradation mechanisms of these alloys. During corrosion the transport of oxidizing species in zirconium dioxide (ZrO2) determines the corrosion kinetics. Previously it has been argued that the outward diffusion of cation ions is important for forming protective oxides. In this work, the migration of Zr defects in tetragonal ZrO2 is studied with temperature accelerated dynamics and molecular dynamics simulations. The results show that Zr interstitials have anisotropic diffusion and migrate preferentially along the [001] or c direction in tetragonal ZrO2. The compressive stresses can increase the Zr interstitial migration barrier significantly. The migration barriers of some defect clusters can be much lower than those of point defects. The migration of Zr interstitials at some special grain boundaries is much slower than in a bulk oxide. The implications of these atomistic simulation results in the Zr corrosion are discussed.

  16. Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

  17. Photocatalytic reactions of oxygenates on tropospheric oxide particles

    SciTech Connect (OSTI)

    Idriss, H.; Seebauer, E.G.; Miller, A. [Univ. of Illinois, Urbana, IL (United States)

    1996-10-01T23:59:59.000Z

    Oxygenates such as ethanol and tert-butyl methyl ether (MTBE) are finding increased use as additives to fuels. The relative merits of ethanol and MTBE have become the focus of intense debate with their ultimate fate as fugitive emissions representing one aspect of this controversy. Both species are known to react homogeneously with photogenerated OH radicals. Here we show that both can also photoreact on suspended solid particulates in the atmosphere with rates comparable to those of OH reactions. Heterogeneous reactions of ethanol yield acetaldehyde and those of MTBE give isobutene and formaldehyde (carcinogenic). Experiments by spectroscopic and kinetic techniques show that the active phases in fly ash are Fe and Ti oxides. In addition, the effects of humidity and alkali addition on the activity and selectivity of these reactions are also discussed. This work appears to be the first demonstration that volatile organic compounds can react as fast by a heterogeneous mechanism as by a homogeneous one in the atmosphere.

  18. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped Ti-substituted perovskites, La{sub 0.7}Sr{sub 0.3}Mn{sub 1-x}Ti{sub x}O{sub 3}, with 0 {le} x {le} 0.20, were investigated by neutron diffraction, magnetization, electric resistivity, and magnetoresistance (MR) measurements. All samples show a rhombohedral structure (space group R3C) from 10 K to room temperature. At room temperature, the cell parameters a, c and the unit cell volume increase with increasing Ti content. However, at 10 K, the cell parameter a has a maximum value for x = 0.10, and decreases for x > 0.10, while the unit cell volume remains nearly constant for x > 0.10. The average (Mn,Ti)-O bond length increases up to x = 0.15, and the (Mn,Ti)-O-(Mn,Ti) bond angle decreases with increasing Ti content to its minimum value at x = 0.15 at room temperature. Below the Curie temperature TC, the resistance exhibits metallic behavior for the x {le} 0.05 samples. A metal (semiconductor) to insulator transition is observed for the x {ge} 0.10 samples. A peak in resistivity appears below TC for all samples, and shifts to a lower temperature as x increases. The substitution of Mn by Ti decreases the 2p-3d hybridization between O and Mn ions, reduces the bandwidth W, and increases the electron-phonon coupling. Therefore, the TC shifts to a lower temperature and the resistivity increases with increasing Ti content. A field-induced shift of the resistivity maximum occurs at x {le} 0.10 compounds. The maximum MR effect is about 70% for La{sub 0.7}Sr{sub 0.3}Mn{sub 0.8}Ti{sub 0.2}O{sub 3}. The separation of TC and the resistivity maximum temperature T{sub {rho},max} enhances the MR effect in these compounds due to the weak coupling between the magnetic ordering and the resistivity as compared with La{sub 0.7}Sr{sub 0.3}MnO{sub 3}. The bulk densities of the membranes were determined using the Archimedes method. The bulk density was 5.029 and 5.57 g/cc for LSFT and dual phase membranes, respectively. The microstructure of the dual phase membrane was analyzed using SEM. It is evident from the micrograph that the microstructure is composed of dual phases. The dense circular regions are enclosed by the less dense, continuous phase which accommodates most of the pores. The pores are normally aggregated and found clustered along the dense regions where as the dense regions do not have pores. Upon closer observation of the micrograph it is revealed that the dense region has a clear circular cleavage or crack as their boundary. The circular cleavage clearly encompasses a dense region and which consists of no pore or any flaw that is visible. The size distribution of the dense, discontinuous regions is varying from 5 to 20 {micro}m with a D{sub 50} of 15 {micro}m. The grain size distribution was estimated from the micrographs using image analysis and a unimodal distribution of grains was observed with an average grain size of 1.99 {micro}m. The chemical compositions of the membranes were analyzed using EDS analysis and no other impurities were observed. The XRD analysis was carried out for the membranes and the phase purity was confirmed. The fracture toughness of LSFT membranes at room temperature has to be calculated using the Vickers indentation method. An electrochemical cell has been designed and built for measurements of the ionic conductivity by the use of blocking electrodes. Preliminary measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Modifications to the apparatus to improve the data quality have been completed. Electron microscopy studies of the origin of the slow kinetics on reduction of ferrites have been initiated. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradient

  19. Oxygen uptake of benthic systems

    E-Print Network [OSTI]

    Priebe, William Franklin

    1972-01-01T23:59:59.000Z

    mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

  20. Oxygen uptake of benthic systems 

    E-Print Network [OSTI]

    Priebe, William Franklin

    1972-01-01T23:59:59.000Z

    mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

  1. Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

    SciTech Connect (OSTI)

    Brauer, Carolyn S.; Blake, Thomas A.; Guenther, Alex B.; Sharpe, Steven W.; Sams, Robert L.; Johnson, Timothy J.

    2014-11-19T23:59:59.000Z

    The OH- and O3- initiated oxidations of isoprene, which is one of the primary volatile organic compounds produced by vegetation, are a major source of atmospheric formaldehyde and other oxygenated organics, yet little quantitative IR data exists for isoprene. We thus report absorption coefficients and integrated band intensities for isoprene in the 600 - 6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in a 19.96 cm path length cell at 0.112 cm-1 resolution, using a Bruker 66V FTIR. Composite spectra are derived from a minimum of seven pressures at each temperature.

  2. Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes Riccardo Ruffo a

    E-Print Network [OSTI]

    Cui, Yi

    Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes Riccardo Ruffo 2008 Available online xxxx Keywords: LiCoO2 Aqueous electrolyte LiNO3 Lithium-ion battery Cathode substrate using the procedures typical for the study of electrodes for lithium-ion batteries in organic

  3. Mossbauer spectroscopic and x-ray diffraction studies of FeSiO2 nanocomposite soft magnetic materials

    E-Print Network [OSTI]

    Yang, De-Ping

    Mo¨ssbauer spectroscopic and x-ray diffraction studies of FeÕSiO2 nanocomposite soft magnetic. The compositions of the precursor and the successive heat-treated samples have been investigated by 57 Fe Mo¨ssbauer a synthesis of Fe/SiO2 nanocomposites and a study of their magnetic and structural properties using Mo¨ssbauer

  4. Surface-initiated polymerization from TiO2 nanoparticle surfaces through a biomimetic initiator: A new route toward

    E-Print Network [OSTI]

    Surface-initiated polymerization from TiO2 nanoparticle surfaces through a biomimetic initiator radical polymerization (SI-ATRP) gave rise to PMMA polymer shell layers tethered to TiO2 nanoparticle functionalized metal oxide nanoparticles that may be useful for construction of functional polymer nanocomposites

  5. Thermal behavior of localized surface plasmon resonance of Au/TiO2 core/shell nanoparticle arrays

    E-Print Network [OSTI]

    Thermal behavior of localized surface plasmon resonance of Au/TiO2 core/shell nanoparticle arrays/shell nanoparticle arrays. Thermal annealing is carried out in three different routes, i.e., pre-TiO2 annealing, post various metallic nanostructures, core/shell nanoparticles exhibit high LSPR tunability and ap- plicability

  6. Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode Materials

    E-Print Network [OSTI]

    Cho, Jaephil

    Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode and annealing temperature are used for MPO4 nanoparticle coatings M = Al, Fe, Ce, and SrH on a LiCoO2 cathode, the extent of the coating coverage is influenced by the nanoparticle size or morphology. Nanoparticles AlPO4

  7. Combination of two catalytic sites in a novel nanocrystalline TiO2iron tetrasulfophthalocyanine material provides better

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ). This reveals that sulfonic acid groups are chemisorbed as sulfonates onto the TiO2 nanoparticles. XPS spectra-isophorone suggesting a cooperative effect between TiO2 and FePcS catalytic sites. Nano-sized functional hybrid and bromide ammonium salts as catalysts.1 This synthetic approach could allow to introduce acid

  8. Modeling of implantation and mixing damage during etching of SiO2 over Si in fluorocarbon plasmas

    E-Print Network [OSTI]

    Kushner, Mark

    Modeling of implantation and mixing damage during etching of SiO2 over Si in fluorocarbon plasmas- sions (CD).3 An example of this process is fluorocarbon plasma etching of trenches and vias in SiO2 and stopping on a crystalline Si layer. The fluorocarbon radicals produced in the plasma deposit a polymer

  9. Preparation and characterization of VOx/TiO2 catalytic coatings on stainless steel plates for structured catalytic reactors.

    E-Print Network [OSTI]

    Boyer, Edmond

    for structured catalytic reactors. Thierry Giornelli, Axel Löfberg* and Elisabeth Bordes-Richard Unité de.Lofberg@univ-lille1.fr Abstract The parameters to be controlled to coat metallic walls by VOx/TiO2 catalysts which) was chosen because of its large application in industrial catalytic reactors. TiO2 films on stainless steel

  10. Optimisation of Accurate Rutile TiO2 (110), (100), (101) and (001) Surface Models from Periodic DFT Calculations

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Title Optimisation of Accurate Rutile TiO2 (110), (100), (101) and (001) Surface Models from of this study was to optimise accurate rutile TiO2 surfaces models that will be used in further calculations(1)69156869 Fax: +0033(1)69157150 Abstract In this paper, geometric bulk parameters, bulk moduli, energy gaps

  11. Evidence for Strain-Induced Local Conductance Modulations in Single-Layer Graphene on SiO2

    E-Print Network [OSTI]

    Yeh, Nai-Chang

    Evidence for Strain-Induced Local Conductance Modulations in Single-Layer Graphene on SiO2 M. L, California Institute of Technology, Pasadena, CA 91125 (Dated: June 8, 2009) Graphene has emerged modulations in the local conductance of single- layer graphene on SiO2 substrates from scanning tunneling

  12. Influence of Nitrogen Doping on the Defect Formation and Surface Properties of TiO2 Rutile and Anatase

    E-Print Network [OSTI]

    Diebold, Ulrike

    Influence of Nitrogen Doping on the Defect Formation and Surface Properties of TiO2 Rutile, New Orleans, Louisiana 70118, USA (Received 25 July 2005; published 20 January 2006) Nitrogen doping numbers: 68.35.ÿp, 81.05.Je, 82.65.+r Titanium dioxide (TiO2) is a good photocatalyst for the remediation

  13. Performance study of commercial LiCoO2 and spinel-based Li-ion cells

    E-Print Network [OSTI]

    Popov, Branko N.

    -ion cells and Sony 18650 cells using non-stoichiometric spinel and LiCoO2, respectively, as positive at the cathode and loss of active material at both electrodes due to electrolyte oxidation. For the Sony cells Science B.V. All rights reserved. Keywords: Li-ion cells; LiCoO2; Cell-Batt1 ; Capacity fade; Sony 18650

  14. Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure

    E-Print Network [OSTI]

    Cao, Guozhong

    Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure Min Intercalation Electrochemistry Capacitance Lithium Ion batteries A B S T R A C T We demonstrate TiO2@graphitic on the electrode surface and enhanced lithium ion intercalation, leading to lower charge transfer resistance

  15. The electrochemical reactions of SnO2 with Li and Na: a study using thin films and mesoporous carbons

    SciTech Connect (OSTI)

    Gorka, Joanna [ORNL; Baggetto, Loic [ORNL; Keum, Jong Kahk [ORNL; Mahurin, Shannon Mark [ORNL; Mayes, Richard T [ORNL; Dai, Sheng [ORNL; Veith, Gabriel M [ORNL

    2015-01-01T23:59:59.000Z

    In this work we have determined the room temperature electrochemical reactivity of SnO2 thin films and mesoporous carbons filled with SnO2 anodes with Na, and compare the results with those obtained during the reaction with Li. We show that SnO2 can reversibly deliver up to 6.2 Li/SnO2 whereas the reaction with Na is significantly limited. The initial discharge capacity is equivalent to less than 4 Na/SnO2, which is expected to correspond to the formation of 2 Na2O and Sn. This limited discharge capacity suggests the negative role of the formed Na2O matrix upon the reversible reaction of Sn clusters. Moreover, the reversible cycling of less than 1 Na/SnO2, despite the utilization of 6-7 nm SnO2 particles, is indicative of sluggish reaction kinetics. The origin of this significant capacity reduction is likely due to the formation of a diffusion limiting interface. Furthermore, there is a larger apparent hysteresis compared to Li. These results point to the need to design composite structures of SnO2 nanoparticles with suitable morphological and conductivity components.

  16. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)

    E-Print Network [OSTI]

    174 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise-mining operations in Florida and Virginia. The value of titanium mineral concentrates consumed in the United States 94% of titanium mineral concentrates was consumed by domestic titanium dioxide (TiO2) pigment

  17. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)

    E-Print Network [OSTI]

    174 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise-mining operations in Florida and Virginia. The value of titanium mineral concentrates consumed in the United States 95% of titanium mineral concentrates was consumed by domestic titanium dioxide (TiO2) pigment

  18. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2, unless otherwise noted)

    E-Print Network [OSTI]

    176 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2, unless surface mining operations in Florida and Virginia. The value of titanium mineral concentrates consumed deposits was zircon. About 97% of titanium mineral concentrates was consumed by domestic TiO2 pigment

  19. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)

    E-Print Network [OSTI]

    172 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise-mining operations in Florida and Virginia. The value of titanium mineral concentrates consumed in the United States. About 95% of titanium mineral concentrates was consumed by domestic titanium dioxide (TiO2) pigment

  20. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2, unless otherwise noted)

    E-Print Network [OSTI]

    178 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2, unless surface mining operations in Florida and Virginia. The value of titanium mineral concentrates consumed deposits was zircon. About 97% of titanium mineral concentrates was consumed by domestic TiO2 pigment

  1. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)

    E-Print Network [OSTI]

    178 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise-mining operations in Florida and Virginia. The value of titanium mineral concentrates consumed in the United States 94% of titanium mineral concentrates was consumed by domestic titanium dioxide (TiO2) pigment

  2. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)

    E-Print Network [OSTI]

    178 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise mining operations in Florida, Georgia, and Virginia. The value of titanium mineral concentrates consumed deposits was zircon. About 97% of titanium mineral concentrates was consumed by domestic TiO2 pigment

  3. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)

    E-Print Network [OSTI]

    176 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise mining operations in Florida, Georgia, and Virginia. The value of titanium mineral concentrates consumed deposits was zircon. About 97% of titanium mineral concentrates was consumed by domestic TiO2 pigment

  4. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)

    E-Print Network [OSTI]

    172 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise-mining operations in Florida and Virginia. The value of titanium mineral concentrates consumed in the United States 94% of titanium mineral concentrates was consumed by domestic titanium dioxide (TiO2) pigment

  5. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of TiO2 content, unless otherwise noted)

    E-Print Network [OSTI]

    174 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of TiO2 content, unless otherwise-mineral sands operations in Florida and Virginia. The value of titanium mineral concentrates consumed deposits was zircon. About 95% of titanium mineral concentrates was consumed by TiO2 pigment producers

  6. TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2, unless otherwise noted)

    E-Print Network [OSTI]

    176 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2, unless-mineral sands operations in Florida and Virginia. The value of titanium mineral concentrates consumed deposits was zircon. About 95% of titanium mineral concentrates was consumed by TiO2 pigment producers

  7. Oriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Park, Byungwoo

    of highly-oriented anatase TiO2 nanocrystals, are adopted as photoelectrodes in dye-sensitized solar cells. [1­4]. In particular, lightweight and flexible dye-sensitized solar cells (DSSCs) have received muchOriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized

  8. First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang

    E-Print Network [OSTI]

    Ceder, Gerbrand

    First-principles study of magnetism in spinel MnO2 Dane Morgan and Billie Wang Department to calculate the ground state, transition tem- perature, and thermodynamic properties of magnetic excitations in spinel MnO2 . The magnetic interactions are mapped onto a Heisenberg model whose exchange interactions

  9. Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2

    E-Print Network [OSTI]

    , 2010; E-mail: jrlong@berkeley.edu The separation of O2 from air is carried out in industry using, as in postcombustion capture, O2 is separated from the N2 in air prior to combustion. Advantages of this scenario cryogenic distillation on a scale of 100 Mtons/year,1 as well as using zeolites in portable devices

  10. Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings

    E-Print Network [OSTI]

    Park, Byungwoo

    and Engineering and Research Center for Energy Conversion and Storage, Seoul National University, Seoul, Korea b Department of Applied Chemistry, Kumoh National Institute of Technology, Gumi, Korea ZrO2-coated LiCoO2 due to its high energy density and good cycling-life performance. However, even though the theoretical

  11. Chemically grown TiO2 on glass with superior photocatalytic properties G. Kenanakis a,b,

    E-Print Network [OSTI]

    : Titanium dioxide thin films Degussa P25 TiO2 Sol­gel technique Photocatalysis Stearic acid Methylene blue of photocatalysis for various applications such as water treatment, air purification and fuel cells [1­5]. TiO2

  12. Oxygen deficiency hazards associated with liquefied gas systems development of a program of controls

    SciTech Connect (OSTI)

    Miller, T.M.; Mazur, P.O.

    1983-01-01T23:59:59.000Z

    The use of liquefied gases in industry and research has become commonplace. Release into the atmosphere of these gases, whether intentional or not, will result in a displacement of air and a reduction in the oxygen concentration. Exposure to reduced levels of oxygen levels may cause reduced abilities, unconsciousness, or death. This paper describes the derivation of a novel program of controls for oxygen deficiency hazards. The key to this approach is a quantitative assessment of risk for each planned operation and the application of control measures to reduce that risk to an acceptable level. Five risk levels evolve which are based on the probability of fatality. Controls such as training, oxygen monitoring equipment, self-rescue respirators, and medical surveillance are required when the probability of fatality exceeds 10/sup -7/ per hour. The quantitative nature of this program ensures an appropriate level of control without undue burden or expense. 11 references, 5 figures, 3 tables.

  13. Inhibition of ERK Oscillations by Ionizing Radiation and Reactive Oxygen Species

    SciTech Connect (OSTI)

    Shankaran, Harish; Chrisler, William B.; Sontag, Ryan L.; Weber, Thomas J.

    2010-12-28T23:59:59.000Z

    The shuttling of activated protein kinases between the cytoplasm and nucleus is an essential feature of normal growth factor signaling cascades. Here we demonstrate that transforming growth factor alpha (TGF?) induces oscillations in extracellular signal regulated kinase (ERK) cytoplasmic-nuclear translocations in human keratinocytes. TGF?-dependent ERK oscillations mediated through the epidermal growth factor receptor (EGFR) are inhibited by low dose X-irradiation (10?cGy) and low concentrations of hydrogen peroxide (0.32–3.26?µM H2O2) used as a model reactive oxygen species (ROS). A fluorescent indicator dye (H2-DCFDA) was used to measure cellular ROS levels following X-irradiation, 12-O-tetradecanoyl phorbol-13-acetate (TPA) and H2O2. X-irradiation did not generate significant ROS production while 0.32?µM H2O2 and TPA induced significant increases in ROS levels with H2O2? >?TPA. TPA alone induced transactivation of the EGFR but did not induce ERK oscillations. TPA as a cotreatment did not inhibit TGF?-stimulated ERK oscillations but qualitatively altered TGF?-dependent ERK oscillation characteristics (amplitude, time-period). Collectively, these observations demonstrate that TGF?-induced ERK oscillations are inhibited by ionizing radiation/ROS and perturbed by epigenetic carcinogen in human keratinocytes. © 2010 Wiley-Liss, Inc.

  14. Mechanism of Methane Chemical Looping Combustion with Hematite Promoted with CeO2

    SciTech Connect (OSTI)

    Miller, Duane D.; Siriwardane, Ranjani

    2013-08-01T23:59:59.000Z

    Chemical looping combustion (CLC) is a promising technology for fossil fuel combustion that produces sequestration-ready CO{sub 2} stream, reducing the energy penalty of CO{sub 2} separation from flue gases. An effective oxygen carrier for CLC will readily react with the fuel gas and will be reoxidized upon contact with oxygen. This study investigated the development of a CeO{sub 2}-promoted Fe{sub 2}O{sub 3}?hematite oxygen carrier suitable for the methane CLC process. Composition of CeO{sub 2} is between 5 and 25 wt % and is lower than what is generally used for supports in Fe{sub 2}O{sub 3} carrier preparations. The incorporation of CeO{sub 2} to the natural ore hematite strongly modifies the reduction behavior in comparison to that of CeO{sub 2} and hematite alone. Temperature-programmed reaction studies revealed that the addition of even 5 wt % CeO{sub 2} enhances the reaction capacity of the Fe{sub 2}O{sub 3} oxygen carrier by promoting the decomposition and partial oxidation of methane. Fixed-bed reactor data showed that the 5 wt % cerium oxides with 95 wt % iron oxide produce 2 times as much carbon dioxide in comparison to the sum of carbon dioxide produced when the oxides were tested separately. This effect is likely due to the reaction of CeO{sub 2} with methane forming intermediates, which are reactive for extracting oxygen from Fe{sub 2}O{sub 3} at a considerably faster rate than the rate of the direct reaction of Fe{sub 2}O{sub 3} with methane. These studies reveal that 5 wt % CeO{sub 2}/Fe{sub 2}O{sub 3} gives stable conversions over 15 reduction/oxidation cycles. Lab-scale reactor studies (pulsed mode) suggest the methane reacts initially with CeO{sub 2} lattice oxygen to form partial oxidation products (CO + H{sub 2}), which continue to react with oxygen from neighboring Fe{sub 2}O{sub 3}, leading to its complete oxidation to form CO{sub 2}. The reduced cerium oxide promotes the methane decomposition reaction to form C + H{sub 2}, which continue to react with Fe{sub 2}O{sub 3}/Fe{sub 3}O{sub 4} to form CO/CO{sub 2} and H{sub 2}O. This mechanism is supported by the characterization studies, which also suggest that the formation of carbonaceous intermediates may affect the reaction rate and selectivity of the oxygen carrier.

  15. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

    1988-01-01T23:59:59.000Z

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

  16. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, R.L.; Cannon, T.W.

    1988-10-25T23:59:59.000Z

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

  17. An evaluation of atmospheric evaporation for treating wood preserving wastes

    E-Print Network [OSTI]

    Shack, Pete A

    1976-01-01T23:59:59.000Z

    i. hat a constant rate of total organi carbon and chemical oxygen demand removal occurred as the wastewai. r was evaporated. A procedure for designing atmospheric evaporation ponds was developed and applied to a hypothetical wood preserving plant.... From this example design estimates of equivalent hydrocarbon concentrations in the air downwind of the pond are made. Various other design con- siderations such as the input data, modifications to the design pro- cedure, solids accumulation...

  18. Atmospheric Science: An introductory survey 1. Introduction to the atmosphere

    E-Print Network [OSTI]

    Folkins, Ian

    Sound Convergence Zone #12;Terrain effects #12;Von Karman vortex streets #12;Atmosphere in Earth system

  19. Carbonate-H2O2 Leaching for Sequestering Uranium from Seawater

    SciTech Connect (OSTI)

    Pan, Horng-Bin [University of Idaho, Moscow] [University of Idaho, Moscow; Weisheng, Liao [University of Idaho, Moscow] [University of Idaho, Moscow; Wai, Chien [University of Idaho, Moscow] [University of Idaho, Moscow; Oyola, Yatsandra [ORNL] [ORNL; Janke, Christopher James [ORNL] [ORNL; Tian, Guoxin [Lawrence Berkeley National Laboratory (LBNL)] [Lawrence Berkeley National Laboratory (LBNL); Rao, Linfeng [Lawrence Berkeley National Laboratory (LBNL)] [Lawrence Berkeley National Laboratory (LBNL)

    2014-01-01T23:59:59.000Z

    Uranium adsorbed on amidoxime-based polyethylene fiber in simulated seawater can be quantitatively eluted at room temperature using 1M Na2CO3 containing 0.1 M H2O2. This efficient elution process is probably due to formation of an extremely stable uranyl-peroxo-carbonato complex in the carbonate solution. After washing with water, the sorbent can be reused with little loss of uranium loading capacity. Possible existence of this stable uranyl species in ocean water is also discussed.

  20. DFT+U Study of CeO2 and Its Native Defects

    E-Print Network [OSTI]

    Huang, Bolong; Gillen, Roland; Robertson, John

    2014-10-14T23:59:59.000Z

    in solid state fuel cells2, as a catalyst3-6, as a high-dielectric constant gate oxide7, and in resistance random access memories (ReRAM)8. Many properties of CeO2 are determined by its intrinsic defects9-23 and the unusual behavior of the semi-core Ce 4f... averaging scheme46 for spin- orbital coupling effect. The RRKJ method is chosen as optimization of pseudopotentials47. The PBE functional was chosen for PBE+U calculations with a kinetic cutoff energy of 750eV, which expands the valence electrons states...

  1. 2.0 COrE lOgO 2.01 overview

    E-Print Network [OSTI]

    Lotze, Heike K.

    2.0 COrE lOgO 2.01 overview 2.02 cLear space and minimum size 2.03 exampLes of pLacement on coLied to the core Logo 2.08 appLying the Logo properLy 2.09 LinKs to daLhousie authorized core Logo AuguST 2014 with real substance and stature, and seen as a vibrant, welcoming community. Our core logo is the visual

  2. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard (Lafayette, CO); Schwartz, Michael (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2000-01-01T23:59:59.000Z

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  3. The Role of Oxygen in Coal Gasification 

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    1986-01-01T23:59:59.000Z

    Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

  4. Oxygen reduction on platinum : an EIS study

    E-Print Network [OSTI]

    Golfinopoulos, Theodore

    2009-01-01T23:59:59.000Z

    The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

  5. Microbial oceanography of anoxic oxygen minimum zones

    E-Print Network [OSTI]

    Ulloa, Osvaldo

    Vast expanses of oxygen-deficient and nitrite-rich water define the major oxygen minimum zones (OMZs) of the global ocean. They support diverse microbial communities that influence the nitrogen economy of the oceans, ...

  6. Microchemical systems for singlet oxygen generation

    E-Print Network [OSTI]

    Hill, Tyrone F. (Tyrone Frank), 1980-

    2008-01-01T23:59:59.000Z

    Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

  7. Mitochondrial reactive oxygen species and cancer

    E-Print Network [OSTI]

    Chandel, Navdeep S

    Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

  8. The Mechanisms of Oxygen Reduction and Evolution Reactions in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

  9. Principles of water oxidation and O2-based hydrocarbon transformation by multinuclear catalytic sites

    SciTech Connect (OSTI)

    Musaev, Djamaladdin G [Chemistry, Emory University; Hill, Craig L [Chemistry, Emory University; Morokuma, Keiji [Chemistry, Emory University

    2014-10-28T23:59:59.000Z

    Abstract The central thrust of this integrated experimental and computational research program was to obtain an atomistic-level understanding of the structural and dynamic factors underlying the design of catalysts for water oxidation and selective reductant-free O2-based transformations. The focus was on oxidatively robust polyoxometalate (POM) complexes in which a catalytic active site interacts with proximal metal centers in a synergistic manner. Thirty five publications in high-impact journals arose from this grant. I. Developing an oxidatively and hydrolytically stable and fast water oxidation catalyst (WOC), a central need in the production of green fuels using water as a reductant, has proven particularly challenging. During this grant period we have designed and investigated several carbon-free, molecular (homogenous), oxidatively and hydrolytically stable WOCs, including the Rb8K2[{Ru4O4(OH)2(H2O)4}(?-SiW10O36)2]·25H2O (1) and [Co4(H2O)2(?-PW9O34)2]10- (2). Although complex 1 is fast, oxidatively and hydrolytically stable WOC, Ru is neither abundant nor inexpensive. Therefore, development of a stable and fast carbon-free homogenous WOC, based on earth-abundant elements became our highest priority. In 2010, we reported the first such catalyst, complex 2. This complex is substantially faster than 1 and stable under homogeneous conditions. Recently, we have extended our efforts and reported a V2-analog of the complex 2, i.e. [Co4(H2O)2(?-VW9O34)2]10- (3), which shows an even greater stability and reactivity. We succeeded in: (a) immobilizing catalysts 1 and 2 on the surface of various electrodes, and (b) elucidating the mechanism of O2 formation and release from complex 1, as well as the Mn4O4L6 “cubane” cluster. We have shown that the direct O-O bond formation is the most likely pathway for O2 formation during water oxidation catalyzed by 1. II. Oxo transfer catalysts that contain two proximal and synergistically interacting redox active metal centers in the active site form another part of considerable interest of our grant because species with such sites [including methane monooxygenase (MMO) and more] are some of the most effective oxygenase catalysts known. Our team conducted the following research on ?-M2-Keggin complexes: (a) investigated stability of the trimer [{Fe3(OH)3(H2O)2}3(?-SiW10O36)3]15-, 4, in water, and developed the chemistry and catalysis of the di-iron centered POM, [?(1,2)-SiW10{Fe(OH)}2O38]6-, 5, in organic solvents (Figure 2). We also study the thermodynamic and structural stability of ?-M2-Keggin in aqueous media for different M’s (d-electron metals). We have defined two structural classes of POMs with proximally bound d-electron metal centers. We refer to these structural isomers of the {?-M2SiW10} family of POMs as “in-pocket” and “out-of pocket”. We have elucidated the factors controlling the structure and stability of the V, Fe, Ru, Tc, Mo and Rh derivatives of [(SiO4)M2(OH)2W10O32]4- using a range of computational tools. We have: (a) demonstrated that heteroatom X in these polyanions may function as an “internal switch” for defining the ground electronic states and, consequently, the reactivity of the ?-M2-Keggin POM complexes; (b) elucidated reactivity of divacant lacunary species and polyperoxotungstates (PPTs), {Xn+O4[WO(O2)2]4}n-, which could be degradation products of ?-M2-Keggin complexes in aqueous media; (c) elucidated the role of the POM ligand in stabilization of {Ru2} and {(Ru-oxo)2} fragments in the reactant and product of the reaction of {?-[(Xn+O4)Ru2(OH)2W10O32]}(8-n)- (where X = Si4+, P5+ and S6+) with O2, and (d) the mechanisms of olefin epoxidation catalyzed by these di-d-transition metal substituted and divacant lacunary ?-M2-Keggin complexes. III. Complementing the efforts presented above was the development of less time-consuming but reasonably accurate computational methods allowing one to explore more deeply large catalytic systems. We developed Reactive Force Field (ReaxFF) to study interaction of the targeted POMs with water, pro

  10. Measurements of the Cerenkov light emitted by a TeO2 crystal

    E-Print Network [OSTI]

    F. Bellini; N. Casali; I. Dafinei; M. Marafini; S. Morganti; F. Orio; D. Pinci; M. Vignati; C. Voena

    2012-12-12T23:59:59.000Z

    Bolometers have proven to be good instruments to search for rare processes because of their excellent energy resolution and their extremely low intrinsic background. In this kind of detectors, the capability of discriminating alpha particles from electrons represents an important aspect for the background reduction. One possibility for obtaining such a discrimination is provided by the detection of the Cerenkov light which, at the low energies of the natural radioactivity, is only emitted by electrons. In this paper, the results of the analysis of the light emitted by a TeO2 crystal at room temperature when transversed by a cosmic ray are reported. Light is promptly emitted after the particle crossing and a clear evidence of its directionality is also found. These results represent a strong indication that Cerenkov light is the main, if not even the only, component of the light signal in a TeO2 crystal. They open the possibility to make large improvements in the performance of experiments based on this kind of materials

  11. On the consistency of QCBED structure factor measurements for TiO2 (Rutile)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Spence, J.C.H [Arizona State University; Friis, J. [Norwegian University of Science and Technology; Zuo, J.M [University of Illinois, Urbana, IL; Jiang, B.

    2003-10-01T23:59:59.000Z

    The same Bragg reflection in TiO2 from twelve different CBED patterns (from different crystals, orientations and thicknesses) are analysed quantitatively in order to evaluate the consistency of the QCBED method for bond-charge mapping. The standard deviation in the resulting distribution of derived X-ray structure factors is found to be an order of magnitude smaller than that in conventional X-ray work , and the standard error (0.026% for FX(110)) is slightly better than obtained by the X-ray Pendellosung method applied to silicon. This is sufficiently accuracy to distinguish between atomic, covalent and ionic models of bonding. We describe the importance of extracting experimental parameters from CCD camera characterization, and of surface oxidation and crystal shape. The current experiments show that the QCBED method is now a robust and powerful tool for low order structure factor measurement, which does not suffer from the large extinction (multiple scattering) errors which occur in inorganic X-ray crystallography, and may be applied to nanocrystals. Our results will be used to understand the role of d electrons in the chemical bonding of TiO2.

  12. On the Consistency of QCBED Structure Factor Measurements for TiO2 (Rutile)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Bin; Zuo, Jian-Min; Friis, Jesper; Spence, John C.H.

    2003-10-01T23:59:59.000Z

    The same Bragg reflection in TiO2 from twelve different CBED patterns (from different crystals, orientations and thicknesses) are analysed quantitatively in order to evaluate the consistency of the QCBED method for bond-charge mapping. The standard deviation in the resulting distribution of derived X-ray structure factors is found to be an order of magnitude smaller than that in conventional X-ray work, and the standard error (0.026% for FX(110)) is slightly better than obtained by the X-ray Pendellosung method applied to silicon. This is sufficiently accuracy to distinguish between atomic, covalent and ionic models of bonding. We describe the importance of extractingmore »experimental parameters from CCD camera characterization, and of surface oxidation and crystal shape. The current experiments show that the QCBED method is now a robust and powerful tool for low order structure factor measurement, which does not suffer from the large extinction (multiple scattering) errors which occur in inorganic X-ray crystallography, and may be applied to nanocrystals. Our results will be used to understand the role of d electrons in the chemical bonding of TiO2.« less

  13. New Insights into Reaction Mechanisms of Ethanol Steam Reforming on Co-ZrO2

    SciTech Connect (OSTI)

    Sun, Junming; Karim, Ayman M.; Mei, Donghai; Engelhard, Mark H.; Bao, Xinhe; Wang, Yong

    2015-01-01T23:59:59.000Z

    The reaction pathway of ethanol steam reforming on Co-ZrO2 has been identified and the active sites associated with each step are proposed. Ethanol is converted to acetaldehyde and then to acetone, followed by acetone steam reforming. More than 90% carbon was found to follow this reaction pathway. N2-Sorption, X-ray Diffraction (XRD), Temperature Programmed Reduction (TPR), in situ X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy, as well as theoretical Density Functional Theory (DFT) calculations have been employed to identify the structure and functionality of the catalysts, which was further used to correlate their performance in ESR. It was found that metallic cobalt is mainly responsible for the acetone steam reforming reactions; while, CoO and basic sites on the support play a key role in converting ethanol to acetone via dehydrogenation and condensation/ketonization reaction pathways. The current work provides fundamental understanding of the ethanol steam reforming reaction mechanisms on Co-ZrO2 catalysts and sheds light on the rational design of selective and durable ethanol steam reforming catalysts.

  14. Redox Active Layer-by-Layer Structures containing MnO2 Nanoparticles

    SciTech Connect (OSTI)

    Bazito, Fernanda; O'Brien, Robert; Buttry, Daniel A.

    2005-02-01T23:59:59.000Z

    Nanoscale materials provide unique properties that will enable new technologies and enhance older ones. One area of intense activity in which nanoscale materials are being used is in the development of new functional materials for battery applications. This effort promises superior materials with properties that circumvent many of the problems associated with traditional battery materials. Previously we have worked on several approaches for using nanoscale materials for application as cathode materials in rechargeable Li batteries. Our recent work has focused on synthesizing MnO2 nanoparticles and using these in layer-by-layer (LbL) structures to probe the redox properties of the nanoparticles. We show that the aqueous colloidal nanoparticles produced by butanol reduction of tetramethylammonium permanganate can be trapped in thin films using a layer-by-layer deposition approach, and that these films are both redox active and exhibit kinetically facile electrochemical responses. We show cyclic voltammetry of MnO2 colloidal nanoparticles entrapped in a LbL thin film at an ITO electrode surface using poly(diallyldimethylammonium chloride) (PDDA). CV experiments demonstrate that Li+ insertion accompanies Mn(IV) reduction in LiClO4 supporting electrolytes, and that reduction is hindered in supporting electrolytes containing only tetrabutylammonium cations. We also show that electron propagation through multilayer films is facile, suggesting that electrons percolate through the films via electron exchange between nanoparticles.

  15. Oxygen Deficient Metabolism in Organs: A Link to Combustion Science 

    E-Print Network [OSTI]

    Miller, Jason Mathew

    2014-12-10T23:59:59.000Z

    and profiles for O2. Diffusion limitation causes m''' to be proportional to local O2 concentration. Thus, the present work modifies COS engineering models for COA cases and considers only diffusion limited transport of O2 to metabolic cells from IF. O2 profiles...

  16. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

    2007-06-12T23:59:59.000Z

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  17. Catalyst containing oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04T23:59:59.000Z

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  18. Large-Eddy Simulation of Pulverized Coal Jet Flame -Effect of Oxygen Concentration on NOx formation

    E-Print Network [OSTI]

    Muto, Masaya; Watanabe, Hiroaki; Kurose, Ryoichi; Komori, Satoru; Balusamy, Saravanan; Hochgreb, Simone

    2015-01-01T23:59:59.000Z

    than those by using other fossil fuels [1]. It is therefore important to develop clean coal technology for pulverized coal fired power plants, in order to control such emissions and to reduce the environmental impact. Regarding the reduction... of environmental impact of CO2, carbon capture and sequestration (CCS) is expected as a key technology, and it is believed that oxy-fuel pulverized coal combus- tion, in which gas mixture of oxygen (O2) and CO2 are used instead of air as oxidizer, has advantages...

  19. Effects of oxygen on fracturing fluids

    SciTech Connect (OSTI)

    Walker, M.L.; Shuchart, C.E.; Yaritz, J.G.; Norman, L.R.

    1995-11-01T23:59:59.000Z

    The stability of polysaccharide gels at high temperature is limited by such factors as pH, mechanical degradation, and oxidants. Oxygen is unavoidably placed in fracturing fluids through dissolution of air. To prevent premature degradation of the fracturing fluid by this oxidant, oxygen scavengers are commonly used. In this paper, the effects of oxygen and various oxygen scavengers on gel stability will be presented. Mechanical removal of oxygen resulted in surprisingly stable fracturing gels at 275 F. However, chemical removal of oxygen gave mixed results. Test data from sodium thiosulfate, sodium sulfite, and sodium erythorbate used as oxygen scavengers/gel stabilizers showed that the efficiency of oxygen removal from gels did not directly coincide with the viscosity retention of the gel, and large excesses of additives were necessary to provide optimum gel stabilization. The inability of some oxygen scavengers to stabilize the gel was the result of products created from the interaction of oxygen with the oxygen scavenger, which in turn, produced species that degraded the gel. The ideal oxygen scavenger should provide superior gel stabilization without creating detrimental side reaction products. Of the materials tested, sodium thiosulfate appeared to be the most beneficial.

  20. Oxygen Detection via Nanoscale Optical Indicators

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

  1. Oxygen quenching in LAB based liquid scintillator and nitrogen bubbling model

    E-Print Network [OSTI]

    Xiao Hua-Lin

    2009-07-03T23:59:59.000Z

    The oxygen quenching effect in Linear Alkl Benzne (LAB) based liquid scintillator (LAB as the solvent, 3 g/L 2, 5 diphe-nyloxazole (PPO) as the fluor and 15 mg/L $p$-bis-($o$-methylstyryl)-benzene (bis-MSB) as the $\\lambda$-shifter) is studied by measuring the light yield as the function of the nitrogen bubbling time. It is shown that the light yield of the fully purged liquid scintillator is increased by 11% at the room temperature and the room atmosphere pressure. A simple nitrogen bubbling model is proposed to describe the relationship between the relative light yield (oxygen quenching factor) and the bubbling time.

  2. Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

  3. Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

  4. Lycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic

    E-Print Network [OSTI]

    Wurtzel, Eleanore

    , quenching singlet oxygen generated during the water-splitting process of photo- synthesis (10, 11). VariousLycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic photosynthetic cyclase. Instead, we show that CruP aids in preventing accumulation of reactive oxygen species (ROS

  5. Experimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine Laser

    E-Print Network [OSTI]

    Carroll, David L.

    state I. Conventionally, a two-phase (gas-liquid) chemistry singlet oxygen generator (SOG) producesExperimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine of the electric discharge iodine laser continues, the role of oxygen atoms downstream of the discharge region

  6. Water adsorption on O(2x2)/Ru(0001) from STM experiments and first-principles calculations

    E-Print Network [OSTI]

    Cabrera-Sanfelix, P.; Sanchez-Portal, D.; Mugarza, A.; Shimizu, T.K.; Salmeron, M.; Arnau, A.

    2007-01-01T23:59:59.000Z

    indicate top, hcp and fcc adsorption sites respectively. TheWater adsorption on O(2x2)/Ru(0001) from STM experiments andand experimental study of water adsorption on Ru(0001) pre-

  7. In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC Core-Shell Nanoparticles for High-Performance Lithium-Ion Storage. In Situ Generation of Few-Layer Graphene Coatings...

  8. Vehicle Technologies Office Merit Review 2015: Efficient Rechargeable Li/O2 Batteries Utilizing Stable Inorganic Molten Salt Electrolytes

    Broader source: Energy.gov [DOE]

    Presentation given by Liox at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about efficient rechargeable Li/O2 batteries...

  9. Tuning the oxide/organic interface: Benzene on SnO2,,101... Matthias Batzill,a)

    E-Print Network [OSTI]

    Diebold, Ulrike

    Tuning the oxide/organic interface: Benzene on SnO2,,101... Matthias Batzill,a) Khabibulakh Katsiev,16 As a model molecule for simulating an organic semiconductor film benzene was chosen as a simple -conjugated

  10. Applications of Low Dimensional Manifolds: 1. Resolved Viscous Detonations with Detailed H2/O2 Kinetics,

    E-Print Network [OSTI]

    , ­ Atmospheric chemistry, ­ Internal combustion engines, ­ Gas phase reactions in energetic solid combustion Kinetics, 2. Combustion of HMX or RDX Product Gases. by Joseph M. Powers Department of Aerospace and Mechanical Engineering University of Notre Dame presented at the 1999 Explosives Research Program Review Los

  11. Patterned Growth of TiO2 Nanowires on Titanium Substrates Jong-Yoon Ha1;2

    E-Print Network [OSTI]

    Lin, Liwei

    with the (001) and (110) side facets. This facile approach to TiO2 NW fabrication with fast induction heating for application in catalysis,1) optical devices,2) gas and humidity sensors,3,4) solar cells,5) Li-ion batteries,6-catalyst VLS method in an inductively heated reactor to synthesize TiO2 NWs on a Ti foil substrate patterned

  12. Adsorption of L-aspartate to rutile (a-TiO2): Experimental and theoretical surface complexation studies

    E-Print Network [OSTI]

    Sverjensky, Dimitri A.

    Adsorption of L-aspartate to rutile (a-TiO2): Experimental and theoretical surface complexation the adsorption of L-aspartate on the surface of rutile (a-TiO2, pHPPZC = 5.4) in NaCl(aq) over a wide range of pH, ligand-to-solid ratio and ionic strength, using potentiometric titrations and batch adsorption

  13. Antireflection and SiO2 Surface Passivation by Liquid-Phase Chemistry for Efficient Black Silicon Solar Cells: Preprint

    SciTech Connect (OSTI)

    Yuan, H. C.; Oh, J.; Zhang, Y.; Kuznetsov, O. A.; Flood, D. J.; Branz, H. M.

    2012-06-01T23:59:59.000Z

    We report solar cells with both black Si antireflection and SiO2 surface passivation provided by inexpensive liquid-phase chemistry, rather than by conventional vacuum-based techniques. Preliminary cell efficiency has reached 16.4%. Nanoporous black Si antireflection on crystalline Si by aqueous etching promises low surface reflection for high photon utilization, together with lower manufacturing cost compared to vacuum-based antireflection coating. Ag-nanoparticle-assisted black Si etching and post-etching chemical treatment recently developed at NREL enables excellent control over the pore diameter and pore separation. Performance of black Si solar cells, including open-circuit voltage, short-circuit current density, and blue response, has benefited from these improvements. Prior to this study, our black Si solar cells were all passivated by thermal SiO2 produced in tube furnaces. Although this passivation is effective, it is not yet ideal for ultra-low-cost manufacturing. In this study, we report, for the first time, the integration of black Si with a proprietary liquid-phase deposition (LPD) passivation from Natcore Technology. The Natcore LPD forms a layer of <10-nm SiO2 on top of the black Si surface in a relatively mild chemical bath at room temperature. We demonstrate black Si solar cells with LPD SiO2 with a spectrum-weighted average reflection lower than 5%, similar to the more costly thermally grown SiO2 approach. However, LPD SiO2 provides somewhat better surface-passivation quality according to the lifetime analysis by the photo-conductivity decay measurement. Moreover, black Si solar cells with LPD SiO2 passivation exhibit higher spectral response at short wavelength compared to those passivated by thermally grown SiO2. With further optimization, the combination of aqueous black Si etching and LPD could provide a pathway for low-cost, high-efficiency crystalline Si solar cells.

  14. Dynamics of Atmospheres

    E-Print Network [OSTI]

    Read, Peter L.

    transfer ­ Solar heating of surface, and atmosphere via dust absorption ­ Infrared CO2 band cooling (especially around 667 cm-1) ­ nonLTE near-infrared heating of CO2 and nonLTE cooling effects above ~60-80 km. Baroclinic waves, scales, heat and momentum transport, seasonal occurrence. Qualitative treatment

  15. Laboratory for Atmospheric and

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    . Along with this growth came a new building on campus and a new name: the Laboratory for Atmospheric of the Sun to the outermost fringes of the solar system. With LASP's continuing operations role in the planet traditional and stable approach based on federal agency funding of research grant

  16. Nucleation and Growth of Crystalline Grains in RF-Sputtered TiO2Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, J. C.; Ahrenkiel, S. P.; Dutta, P.; Bommisetty, V. R.

    2009-01-01T23:59:59.000Z

    AmorphousTiO2thin films were radio frequency sputtered onto siliconmonoxide and carbon support films on molybdenum transmission electron microscope (TEM) grids and observed during in situ annealing in a TEM heating stage at250?C. The evolution of crystallization is consistent with a classical model of homogeneous nucleation and isotropic grain growth. The two-dimensional grain morphology of the TEM foil allowed straightforward recognition of amorphous and crystallized regions of the films, for measurement of crystalline volume fraction and grain number density. By assuming that the kinetic parameters remain constant beyond the onset of crystallization, the final average grain size was computed, using an analyticalmore »extrapolation to the fully crystallized state. Electron diffraction reveals a predominance of the anatase crystallographic phase.« less

  17. Specific heat and energy for the three-dimensional O(2) model

    E-Print Network [OSTI]

    Holtmann, S; Schulze, T

    2002-01-01T23:59:59.000Z

    We investigate the three-dimensional O(2) model on lattices of size 8^3 to 160^3 close to the critical point at zero magnetic field. We confirm explicitly the value of the critical coupling J_c found by Ballesteros et al. and estimate there the universal values of g_r and xi/L. At the critical point we study the finite size dependencies of the energy density epsilon and the specific heat C. We find that the nonsingular part of the specific heat C_{ns} is linearly dependent on 1/alpha. From the critical behaviour of the specific heat for T not T_c on the largest lattices we determine the universal amplitude ratio A+/A-. The alpha- dependence of this ratio is close to the phenomenological relation A+/A- = 1-4alpha.

  18. OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

    E-Print Network [OSTI]

    Byrn, Marianne; Calvin, Melvin

    1965-01-01T23:59:59.000Z

    OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES TWO-eng-48 OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

  19. SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics

    E-Print Network [OSTI]

    Russell, Lynn

    SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics Course Syllabus and Lecture Schedule Instructor: Lynn Russell, 343 NH, 534-4852, lmrussell@ucsd.edu Text: Thermodynamics of Atmospheres of Thermodynamics (Work, Heat, First Law, Second Law, Heat Capacity, Adiabatic Processes) 5-Oct F Hurricane Example

  20. Developments in ITM oxygen technology for IGCC

    SciTech Connect (OSTI)

    Stein, V.E.E.; Richards, R.E.

    1999-07-01T23:59:59.000Z

    In partnership with the U.S. Department of Energy (DOE), an Air Products-led team (with Ceramatec, Eltron Research, McDermott Technology, NREC, Texaco, the Pennsylvania State University, and the University of Pennsylvania) is developing a new technology for air separation - Ion Transport Membrane Oxygen - based on the use of mixed-conducting ceramic membranes that have both electronic and oxygen ionic conductivity when operated at high temperature, typically 800 to 900 C. Under the influence of an oxygen partial-pressure driving force, the ITM Oxygen process achieves a high-purity, high-flux separation of oxygen from a compressed-air stream. By integrating the energy-rich, oxygen-depleted, non-permeate stream with a gas turbine system, the ITM Oxygen process becomes a co-producer of high-purity oxygen, power, and steam. Under a recent CRADA entitled ``Ion Transport Membranes (ITM) for Oxygen-Blown IGCC Systems and Indirect Coal Liquefaction,'' Air Products and DOE completed an initial quantification of the benefits of an ITM Oxygen-integrated IGCC facility. Compared to the cryogenic oxygen base case, the ITM Oxygen technology can potentially: reduce total installed costs by 7%; improve thermal efficiency for the integrated IGCC system by about 3%, leading to further decreases in carbon dioxide and sulfur emissions; and reduce the cost of generated electric power by more than 6%. The ITM Oxygen development project will proceed in three phases. Phase 1, which commenced under a DOE Cooperative Agreement in October 1998, is a 3-year effort focusing on construction of a technology development unit (TDU) for process concept validation tests at a capacity of 0.1 ton-per-day (TPD) oxygen. To accomplish this objective, the Air Products team will address relevant technical challenges in ITM Oxygen materials, engineering, membrane module development, and performance testing. During Phase 1 the team will also verify the economic prospects for integrating ITM Oxygen technology with IGCC and other advanced power generation systems. After at least one intermediate scaleup, Phase 2 and 3 activities will culminate with scaleup to a 25- to 50-TPD pre-commercial demonstration unit, fully integrated with a gas turbine. Meeting these challenges of developing cost-effective fabrication techniques for ITM Oxygen devices, and successfully integrating them with commercially available gas turbine engines, is key to bringing ITM Oxygen technology to the marketplace.

  1. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    SciTech Connect (OSTI)

    Gerlach, T.M. (Geological Survey, Vancouver, WA (United States))

    1993-02-01T23:59:59.000Z

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO[sub 2]. The CO[sub 2]-poor gases are typical of Type II volcanic gases (GERLACH and GRAEBER, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO[sub 2]-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032[degrees]C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the F[sub o[sub 2

  2. The 2 1 reconstruction of the rutile TiO2(011) surface: A combined density functional theory, X-ray diffraction, and scanning

    E-Print Network [OSTI]

    Diebold, Ulrike

    -terminated TiO2 rutile (011)-1 Â 1 surface shows an undulated surface topography with exposed two-fold O (O2cThe 2 Â 1 reconstruction of the rutile TiO2(011) surface: A combined density functional theory, X for publication 28 October 2008 Available online 5 November 2008 Keywords: Titanium dioxide Surface reconstruction

  3. Gas Transport and Exchange: Interaction Between O2 and CO2 CJ Brauner and JL Rummer, University of British Columbia, Vancouver, BC, Canada

    E-Print Network [OSTI]

    Wood, Spencer

    Gas Transport and Exchange: Interaction Between O2 and CO2 Exchange CJ Brauner and JL Rummer Nonlinear Bohr­Haldane Effect within the OEC Basis for the Interaction between O2 and CO2: Implications of Non-Steady-State Conditions for the Bohr­Haldane Effect Interaction between O2 and CO2 Exchange

  4. Coal Particle Flow Patterns for O2 Enriched, Low NOx Burners

    SciTech Connect (OSTI)

    Jennifer Sinclair Curtis

    2005-08-01T23:59:59.000Z

    This project involved a systematic investigation examining the effect of near-flame burner aerodynamics on standoff distance and stability of turbulent diffusion flames and the resultant NO{sub x} emissions from actual pulverized coal diffusion flames. Specifically, the scope of the project was to understand how changes in near-flame aerodynamics and transport air oxygen partial pressure can influence flame attachment and coal ignition, two properties essential to proper operation of low NO{sub x} burners. Results from this investigation utilized a new 2M tall, 0.5m in diameter combustor designed to evaluate near-flame combustion aerodynamics in terms of transport air oxygen partial pressure (Po{sub 2}), coal fines content, primary fuel and secondary air velocities, and furnace wall temperature furnish insight into fundamental processes that occur during combustion of pulverized coal in practical systems. Complementary cold flow studies were conducted in a geometrically similar chamber to analyze the detailed motion of the gas and particles using laser Doppler velocimetry. This final technical report summarizes the key findings from our investigation into coal particle flow patterns in burners. Specifically, we focused on the effects of oxygen enrichment, the effect of fines, and the effect of the nozzle velocity ratio on the resulting flow patterns. In the cold flow studies, detailed measurements using laser Doppler velocimetry (LDV) were made to determine the details of the flow. In the hot flow studies, observations of flame stability and measurements of NO{sub x} were made to determine the effects of the flow patterns on burner operation.

  5. THE GREAT OXIDATION OF EARTH'S ATMOSPHERE: CONTESTING THE YOYO MODEL VIA TRANSITION STABILITY ANALYSIS

    SciTech Connect (OSTI)

    Cuntz, M.; Roy, D.; Musielak, Z. E., E-mail: cuntz@uta.ed, E-mail: dipanjan.roy@etumel.univmed.f, E-mail: zmusielak@uta.ed [Department of Physics, University of Texas at Arlington, Arlington, TX 76019 (United States)

    2009-11-20T23:59:59.000Z

    A significant controversy regarding the climate history of the Earth and its relationship to the development of complex life forms concerns the rise of oxygen in the early Earth's atmosphere. Geological records show that this rise occurred about 2.4 Gyr ago, when the atmospheric oxygen increased from less than 10{sup -5} present atmospheric level (PAL) to more than 0.01 PAL and possibly above 0.1 PAL. However, there is a debate whether this rise happened relatively smoothly or with well-pronounced ups and downs (the Yoyo model). In our study, we explore a simplified atmospheric chemical system consisting of oxygen, methane, and carbon that is driven by the sudden decline of the net input of reductants to the surface as previously considered by Goldblatt et al. Based on the transition stability analysis for the system equations, constituting a set of non-autonomous and non-linear differential equations, as well as the inspection of the Lyapunov exponents, it is found that the equations do not exhibit chaotic behavior. In addition, the rise of oxygen occurs relative smoothly, possibly with minor bumps (within a factor of 1.2), but without major jumps. This result clearly argues against the Yoyo model in agreement with recent geological findings.

  6. Pluto's Atmosphere Does Not Collapse

    E-Print Network [OSTI]

    Olkin, C B; Borncamp, D; Pickles, A; Sicardy, B; Assafin, M; Bianco, F B; Buie, M W; de Oliveira, A Dias; Gillon, M; French, R G; Gomes, A Ramos; Jehin, E; Morales, N; Opitom, C; Ortiz, J L; Maury, A; Norbury, M; Ribas, F B; Smith, R; Wasserman, L H; Young, E F; Zacharias, M; Zacharias, N

    2013-01-01T23:59:59.000Z

    Combining stellar occultation observations probing Pluto's atmosphere from 1988 to 2013 and models of energy balance between Pluto's surface and atmosphere, we conclude that Pluto's atmosphere does not collapse at any point in its 248-year orbit. The occultation results show an increasing atmospheric pressure with time in the current epoch, a trend present only in models with a high thermal inertia and a permanent N2 ice cap at Pluto's north rotational pole.

  7. THE EFFECTS OF SNOWLINES ON C/O IN PLANETARY ATMOSPHERES

    SciTech Connect (OSTI)

    Oeberg, Karin I.; Murray-Clay, Ruth [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Bergin, Edwin A., E-mail: koberg@cfa.harvard.edu [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States)

    2011-12-10T23:59:59.000Z

    The C/O ratio is predicted to regulate the atmospheric chemistry in hot Jupiters. Recent observations suggest that some exoplanets, e.g., Wasp 12-b, have atmospheric C/O ratios substantially different from the solar value of 0.54. In this Letter, we present a mechanism that can produce such atmospheric deviations from the stellar C/O ratio. In protoplanetary disks, different snowlines of oxygen- and carbon-rich ices, especially water and carbon monoxide, will result in systematic variations in the C/O ratio both in the gas and in the condensed phases. In particular, between the H{sub 2}O and CO snowlines most oxygen is present in icy grains-the building blocks of planetary cores in the core accretion model-while most carbon remains in the gas phase. This region is coincidental with the giant-planet-forming zone for a range of observed protoplanetary disks. Based on standard core accretion models of planet formation, gas giants that sweep up most of their atmospheres from disk gas outside of the water snowline will have a C/O {approx} 1, while atmospheres significantly contaminated by evaporating planetesimals will have a stellar or substellar C/O when formed at the same disk radius. The overall metallicity will also depend on the atmosphere formation mechanism, and exoplanetary atmospheric compositions may therefore provide constraints on where and how a specific planet formed.

  8. The PMMA opal film was infiltrated with SiO2 using a homemade CVD setup operating at atmospheric pressure and room temperature

    E-Print Network [OSTI]

    by Shearing** By Dan E. Angelescu,* Judith H. Waller, Douglas H. Adamson, Paru Deshpande, Stephen Y. Chou, Richard A. Register, and Paul M. Chaikin Block copolymer thin films are currently of great interest

  9. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, O.A.; Stencel, J.R.

    1987-10-02T23:59:59.000Z

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The moisture then passes through a combustion chamber where hydrogen gas in the form of H/sub 2/ or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  10. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, Otto A. (Langhorne, PA); Stencel, Joseph R. (Skillman, NJ)

    1990-01-01T23:59:59.000Z

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The mixture then passes through a combustion chamber where hydrogen gas in the form of H.sub.2 or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  11. Electron-impact excitation of the Rydberg levels of the oxygen molecule

    SciTech Connect (OSTI)

    Chung, S.; Lin, C.C.; Lee, E.T.

    1990-10-01T23:59:59.000Z

    Electron-impact cross sections for exciting the oxygen molecule from the ground electronic level to the ns sigma sub g, np sigma sub u, nd sigma subg, nf sigma sub u, np pi sub u, nd pi sub g, and nf pi sub u. Rydberg levels associated with the O2+(B2 sigma(-)sub g) and O2(+)(b4 sigma(-) sub g) cores are presented. For each Rydberg series of a given l, m, and O2+ core state, the cross sections exhibit n dependence of the form 1/n to the alpha power with alpha varying from one series to another in the range of 1.47 to 4.60 in contrast to the more universal 1/n-cubed dependence for the hydrogen atom. The potential cusps at the two nuclear sites of the molecule make the Rydberg orbital density near the origin quite different from the hydrogen atom, thereby spoiling the simple 1/n-cubed dependence. (JHD)

  12. Cold atmospheric plasma in cancer therapy

    SciTech Connect (OSTI)

    Keidar, Michael; Shashurin, Alex; Volotskova, Olga [Mechanical and Aerospace Engineering, George Washington University, Washington DC 20052 (United States)] [Mechanical and Aerospace Engineering, George Washington University, Washington DC 20052 (United States); Ann Stepp, Mary [Medical School, George Washington University, Washington DC 20052 (United States)] [Medical School, George Washington University, Washington DC 20052 (United States); Srinivasan, Priya; Sandler, Anthony [Childrens National Medical Center, Washington DC 20010 (United States)] [Childrens National Medical Center, Washington DC 20010 (United States); Trink, Barry [Head and Neck Cancer Research Division, Department of Otolaryngology, School of Medicine, Johns Hopkins University, Baltimore, Maryland 21205 (United States)] [Head and Neck Cancer Research Division, Department of Otolaryngology, School of Medicine, Johns Hopkins University, Baltimore, Maryland 21205 (United States)

    2013-05-15T23:59:59.000Z

    Recent progress in atmospheric plasmas has led to the creation of cold plasmas with ion temperature close to room temperature. This paper outlines recent progress in understanding of cold plasma physics as well as application of cold atmospheric plasma (CAP) in cancer therapy. Varieties of novel plasma diagnostic techniques were developed recently in a quest to understand physics of CAP. It was established that the streamer head charge is about 10{sup 8} electrons, the electrical field in the head vicinity is about 10{sup 7} V/m, and the electron density of the streamer column is about 10{sup 19} m{sup ?3}. Both in-vitro and in-vivo studies of CAP action on cancer were performed. It was shown that the cold plasma application selectively eradicates cancer cells in-vitro without damaging normal cells and significantly reduces tumor size in-vivo. Studies indicate that the mechanism of action of cold plasma on cancer cells is related to generation of reactive oxygen species with possible induction of the apoptosis pathway. It is also shown that the cancer cells are more susceptible to the effects of CAP because a greater percentage of cells are in the S phase of the cell cycle.

  13. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Sun, Junming; Gao, Feng; Peden, Charles HF; Wang, Yong

    2013-03-21T23:59:59.000Z

    A series of VOx/CeO2 catalysts with various sodium loadings (Na/V ratio from 0 to 1) has been studied for oxidative dehydrogenation (ODH) of methanol. The effect of sodium on the surface structure, redox properties, and surface acidity/basicity of VOx/CeO2 was investigated using hydrogen temperature-programmed reduction (H2-TPR), Raman spectroscopy, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT). The experimental results indicate that the effect of sodium on VOx/CeO2 is highly dependent on the Na/V ratio. At a low Na/V ratio (Na/V<0.25), sodium addition only slightly decreases the redox properties of VOx/CeO2 and has little effect on its activity and selectivity to formaldehyde, even though the Brönsted acidity is almost completely eliminated at a Na/V ratio of 0.25. At a high Na/V ratio (Na/V>0.25), sodium addition greatly alters the nature of the active sites by V-O-Ce bond cleavage and V-O-Na bond formation, leading to significantly reduced activity of the VOx/CeO2 catalysts. At Na/V>0.25, the selectivity to formaldehyde also decreases with increasing Na/V ratio due to: (1) the suppressed reducibility of VOx, and (2) increased basicity leading to increased CO2.

  14. Myocardial Reloading after Extracorporeal Membrane Oxygenation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protein Synthesis. Abstract: Extracorporeal membrane oxygenation (ECMO) unloads the heart providing a bridge to recovery in children after myocardial stunning. Mortality after...

  15. The Role of Oxygen in Coal Gasification

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    in downst eam absorbs oxygen from air at low pressure by units. Selection of the optimum oxygen urHy contact with a circulating molten salt. High must be performed by optimizing the capit land purity (>99.5%) oxygen is regenerated from the operating... are evaluated, the use of oxygen is often preferred over air regardless of the pressure requirement. GOX GAN WASTE AIR FROM MOL SIEVE MAIN EXCHANGERS EXPANDER Figure 4 - Low Pressure Cryogenic Cycle Below about 95% purity, the specific power (k...

  16. Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li-O$_2$ battery capacity

    E-Print Network [OSTI]

    Burke, Colin M; Khetan, Abhishek; Viswanathan, Venkatasubramanian; McCloskey, Bryan D

    2015-01-01T23:59:59.000Z

    Among the 'beyond Li-ion' battery chemistries, nonaqueous Li-O$_2$ batteries have the highest theoretical specific energy and as a result have attracted significant research attention over the past decade. A critical scientific challenge facing nonaqueous Li-O$_2$ batteries is the electronically insulating nature of the primary discharge product, lithium peroxide, which passivates the battery cathode as it is formed, leading to low ultimate cell capacities. Recently, strategies to enhance solubility to circumvent this issue have been reported, but rely upon electrolyte formulations that further decrease the overall electrochemical stability of the system, thereby deleteriously affecting battery rechargeability. In this study, we report that a significant enhancement (greater than four-fold) in Li-O$_2$ cell capacity is possible by appropriately selecting the salt anion in the electrolyte solution. Using $^7$Li nuclear magnetic resonance and modeling, we confirm that this improvement is a result of enhanced Li...

  17. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO)

    1991-01-01T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

  18. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.

    1991-08-20T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  19. Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system

    E-Print Network [OSTI]

    Low, Clarke Alan

    2008-01-01T23:59:59.000Z

    Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

  20. Level Alignment of a Prototypical Photocatalytic System: Methanol on TiO2(110)

    SciTech Connect (OSTI)

    Migani, Annapaola; Mowbray, Duncan J.; Iacomino, Amilcare; Zhao, Jin; Petek, Hrvoje

    2013-08-07T23:59:59.000Z

    Photocatalytic activity depends on the optimal alignment of electronic levels at the molecule? semiconductor interface. Establishing the level alignment experimentally is complicated by the uncertain chemical identity of the surface species. We address the assignment of the occupied and empty electronic levels for the prototypical photocatalytic system consisting of methanol on a rutile TiO2(110) surface. Using many-body quasiparticle (QP) techniques, we show that the frontier levels measured in UV photoelectron and two-photon photoemission spectroscopy experiments can be assigned to molecularly chemisorbed methanol rather than its dissociated product, the methoxy species. We find that the highest occupied molecular orbital of the methoxy species is much closer to the valence band maximum, suggesting why it is more photocatalytically active than the methanol molecule. We develop a general semiquantitative model for predicting many-body QP energies based on the electronic screening within the bulk, molecular, or vacuum regions of the wave functions at molecule?semiconductor interfaces.