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Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Modern Records of Atmospheric Nitrous Oxide (N2O) and a 2000-year Ice-core  

NLE Websites -- All DOE Office Websites (Extended Search)

Modern Records of Atmospheric Nitrous Oxide (N2O) and a 2000-year Ice-core Modern Records of Atmospheric Nitrous Oxide (N2O) and a 2000-year Ice-core Record from Law Dome, Antarctica Introduction This page provides an introduction and links to records of atmospheric nitrous oxide (N2O) over the last 2000 years, emphasizing large data bases each representing currently active stations. Records in recent decades (time period depending on location) have been obtained from samples of ambient-air at remote locations, which represent changing global atmospheric conditions rather than influences of local sources. The longer (2000-year) record is from the Law Dome ice core in Antarctica. The ice-core record has been merged with modern annual data from Cape Grim, Tasmania to provide a 2000-year time series of annual values. A spline function has been fit to the data to provide a continuous time series of

2

A kinetics study of the atmospheric pressure CVD reaction of silane and nitrous oxide  

SciTech Connect

A mechanistic study of oxide deposition from silane and nitrous oxide between 495{sup 0}C and 690{sup 0}C was performed in a laminar flow, cool wall reactor. Results indicate the existence of two distinct chemical pathways. At high nitrous oxide concentrations, the deposition reaction is dominated by radical chain chemistry initiated by the decomposition of N/sub 2/O. At lower N/sub 2/O concentrations, the decomposition of silane to form silylene (SiH/sub 2/) initiates the deposition. Studies of the reaction of disilane and nitrous oxide confirmed the role of SiH/sub 2/ in the deposition. Reactions involving SiH/sub 2/ are used to explain the observed growth of sub-stoichiometric oxides under low N/sub 2/O conditions.

Chapple-Sokol, J.D.; Giunta, C.J.; Gordon, R.G. (Harvard Univ., Cambridge, MA (USA). Dept. of Chemistry)

1989-10-01T23:59:59.000Z

3

Soil–Atmosphere Exchange of Nitrous Oxide, Nitric Oxide, Methane, and Carbon Dioxide in Logged and Undisturbed Forest in the Tapajos National Forest, Brazil  

Science Conference Proceedings (OSTI)

Selective logging is an extensive land use in the Brazilian Amazon region. The soil–atmosphere fluxes of nitrous oxide (N2O), nitric oxide (NO), methane (CH4), and carbon dioxide (CO2) are studied on two soil types (clay Oxisol and sandy loam ...

Michael Keller; Ruth Varner; Jadson D. Dias; Hudson Silva; Patrick Crill; Raimundo Cosme de Oliveira Jr.; Gregory P. Asner

2005-11-01T23:59:59.000Z

4

The biogeochemistry of marine nitrous oxide  

E-Print Network (OSTI)

Atmospheric nitrous oxide N?O concentrations have been rising steadily for the past century as a result of human activities. In particular, human perturbation of the nitrogen cycle has increased the N?O production rates ...

Frame, Caitlin H

2011-01-01T23:59:59.000Z

5

800,000 Year Ice-Core Records of Atmospheric Nitrous Oxide (N2O...  

NLE Websites -- All DOE Office Websites (Extended Search)

create a long-term record to the present. These records are maintained by the World Data Center for Paleoclimatology, National Oceanic and Atmospheric Administration (NOAA), and...

6

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Annual Energy Outlook 2012 (EIA)

nitrous oxide emisssions from industrial sources, 1990, 2005, 2008, and 2009 4.5. Waste management sources In 2009, treatment of residential and commercial wastewater produced 92...

7

Nitrous oxide emissions  

SciTech Connect

The purpose of this paper is to report the effect of key operating parameters, the relative importance of coal type, and the potentially significant coal properties for producing N{sub 2}O emissions in an atmospheric circulating fluidized-bed combustor (CFBC) and pressurized bubbling fluidized-bed combustor (PFBC). The generation of N{sub 2}O emissions is quantified in an empirical model based on the experimental data.

Mann, M.D.; Collings, M.E.; Young, B.C.

1992-12-01T23:59:59.000Z

8

Nitrous oxide emissions  

SciTech Connect

The purpose of this paper is to report the effect of key operating parameters, the relative importance of coal type, and the potentially significant coal properties for producing N[sub 2]O emissions in an atmospheric circulating fluidized-bed combustor (CFBC) and pressurized bubbling fluidized-bed combustor (PFBC). The generation of N[sub 2]O emissions is quantified in an empirical model based on the experimental data.

Mann, M.D.; Collings, M.E.; Young, B.C.

1992-01-01T23:59:59.000Z

9

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

10

Low temperature plasma enhanced chemical vapor deposition of silicon oxide films using disilane and nitrous oxide  

Science Conference Proceedings (OSTI)

Keywords: disilane, low temperature, nitrous oxide, plasma enhanced chemical vapor deposition, silicon oxide

Juho Song; G. S. Lee; P. K. Ajmera

1995-10-01T23:59:59.000Z

11

Process Modeling of Global Soil Nitrous Oxide Emissions  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and is a major ozone-depleting substance. To understand and

Saikawa, E.

2011-09-01T23:59:59.000Z

12

Spatiotemporal modelling in estimation of nitrous oxide emissions from soil.  

E-Print Network (OSTI)

??Nitrous oxide is a major greenhouse gas emission. The aim of this research was to develop and apply statistical models to characterize the complex spatial… (more)

Huang, Xiaodong

2013-01-01T23:59:59.000Z

13

Methane and Nitrous Oxide: Their Effects on the Terrestrial Climate  

Science Conference Proceedings (OSTI)

Simplified band models are developed for methane (CH4) and nitrous oxide (N2O) bands in the longwave radiation spectrum. The band models are then employed in a radiation model to calculate the seasonally and latitudinally varying contributions of ...

L. Donner; V. Ramanathan

1980-01-01T23:59:59.000Z

14

On-farm Assessment of Nitrogen Fertilizer application to corn on Nitrous Oxide Emissions  

E-Print Network (OSTI)

mitigation of greenhouse gas emissions by agriculture. Nutr.1998. Nitrous oxide emission in three years as affected by2008. Soil-surface gas emissions. p.851-861. In: M.R. Carter

2009-01-01T23:59:59.000Z

15

Final Report for DOE grant no. DE-FG02-04ER63883: Can soil genomics predict the impact of precipitation on nitrous oxide flux from soil  

SciTech Connect

Nitrous oxide is a potent greenhouse gas that is released by microorganisms in soil. However, the production of nitrous oxide in soil is highly variable and difficult to predict. Future climate change may have large impacts on nitrous oxide release through alteration of precipitation patterns. We analyzed DNA extracted from soil in order to uncover relationships between microbial processes, abundance of particular DNA sequences and net nitrous oxide fluxes from soil. Denitrification, a microbial process in which nitrate is used as an electron acceptor, correlated with nitrous oxide flux from soil. The abundance of ammonia oxidizing archaea correlated positively, but weakly, with nitrous oxide production in soil. The abundance of bacterial genes in soil was negatively correlated with gross nitrogen mineralization rates and nitrous oxide release from soil. We suggest that the most important control over nitrous oxide production in soil is the growth and death of microorganisms. When organisms are growing nitrogen is incorporated into their biomass and nitrous oxide flux is low. In contrast, when microorganisms die, due to predation or infection by viruses, inorganic nitrogen is released into the soil resulting in nitrous oxide release. Higher rates of precipitation increase access to microorganisms by predators or viruses through filling large soil pores with water and therefore can lead to large releases of nitrous oxide from soil. We developed a new technique, stable isotope probing with 18O-water, to study growth and mortality of microorganisms in soil.

Egbert Schwartz

2008-12-15T23:59:59.000Z

16

EMISSIONS OF NITROUS OXIDE AND METHANE FROM CONVENTIONAL AND ALTERNATIVE FUEL MOTOR VEHICLES  

E-Print Network (OSTI)

EMISSIONS OF NITROUS OXIDE AND METHANE FROM CONVENTIONAL AND ALTERNATIVE FUEL MOTOR VEHICLES from motor vehicles because unlike emissions of CO2, which are relatively easy to estimate, emissions-related emissions. In the U.S., for example, emissions of carbon dioxide (CO2) from the production and use of motor

Kammen, Daniel M.

17

Nitrous oxide (N?O) isotopic composition in the troposphere : instrumentation, observations at Mace Head, Ireland, and regional modeling  

E-Print Network (OSTI)

Nitrous oxide (N?O) is a significant greenhouse gas and main contributor to stratospheric ozone destruction. Surface measurements of N?O mole fractions have been used to attribute source and sink strengths, but large ...

Potter, Katherine Ellison

2011-01-01T23:59:59.000Z

18

Vibrational Infrared Lifetime of the Anesthetic nitrous oxide gas in solution  

E-Print Network (OSTI)

The lifetime of the asymmetric fundamental stretching 2218 cm$^{-1}$ vibration of the anesthetic gas nitrous oxide (N$_2$O) dissolved in octanol and olive oil is reported. These solvents are model systems commonly used to assess anesthetic potency. Picosecond time-scale molecular dynamics simulations have suggested that protein dynamics or membrane dynamics play a role in the molecular mechanism of anesthetic action. Ultrafast infrared spectroscopy with 100 fs time resolution is an ideal tool to probe dynamics of anesthetic molecules on such timescales. Pump-probe studies at the peak of the vibrational band yield a lifetime of $55 \\pm 1$ ps in olive oil and $52 \\pm 1 ps$ in octanol. The similarity of lifetimes suggests that energy relaxation of the anesthetic is determined primarily by the hydrophobic nature of the environment, consistent with models of anesthetic action. The results show that nitrous oxide is a good model system for probing anesthetic-solvent interactions using nonlinear infrared spectroscop...

Chieffo, Logan; Shattuck, Jeffrey; Hong, Mi K; Ziegler, Lawrence; Erramilli, Shyamsunder

2006-01-01T23:59:59.000Z

19

Nitrous oxide production from radiolysis of simulted high-level nuclear waste solutions  

DOE Green Energy (OSTI)

Nitrous oxide gas (N{sub 2}O) is produced by the radiolysis of aqueous nitrate or nitrite solutions in the presence of organic compounds. When ethylenediaminetetraacetic acid (EDTA) or N- (2-hydroxyethyl)-ethylenediaminetriacetic acid (HEDTA) is present, the G-value for hydrogen increases and N{sub 2}O become the major gaseous product (G=0.54). A survey of organic compounds indicates the amount of N{sub 2}O formed depends on the structure of the organic. With highly oxidized organics (carbonate, formate, acetate and oxalate), little or no N{sub 2}O is formed. Aromatic and aliphatic organics (sodium tetraphenylborate, benzene, phenol, n-paraffin, and tributylphosphate) produce small amounts of N{sub 2}O. Water soluble, easily oxidized organics (methanol, ethanol, isopropanol, n-butanol, acetone, and ethylene glycol) produce large amounts of N{sub 2}O relative to the previous two categories. Nitrous oxide production is not greatly affected by pH between neutral and pH=13, but increases significantly in acid solution. The G-value for N{sub 2}O production in 10 wt% potassium tetraphenylborate slurries has been measured under process conditions important at the Savannah River Site.

Walker, D.D.; Hobbs, D.T.; Tiffany, J.B.; Bibler, N.E. [Westinghouse Savannah River Co., Aiken, SC (United States); Meisel, D. [Argonne National Lab., IL (United States)

1992-07-01T23:59:59.000Z

20

Nitrous oxide production from radiolysis of simulted high-level nuclear waste solutions  

DOE Green Energy (OSTI)

Nitrous oxide gas (N{sub 2}O) is produced by the radiolysis of aqueous nitrate or nitrite solutions in the presence of organic compounds. When ethylenediaminetetraacetic acid (EDTA) or N- (2-hydroxyethyl)-ethylenediaminetriacetic acid (HEDTA) is present, the G-value for hydrogen increases and N{sub 2}O become the major gaseous product (G=0.54). A survey of organic compounds indicates the amount of N{sub 2}O formed depends on the structure of the organic. With highly oxidized organics (carbonate, formate, acetate and oxalate), little or no N{sub 2}O is formed. Aromatic and aliphatic organics (sodium tetraphenylborate, benzene, phenol, n-paraffin, and tributylphosphate) produce small amounts of N{sub 2}O. Water soluble, easily oxidized organics (methanol, ethanol, isopropanol, n-butanol, acetone, and ethylene glycol) produce large amounts of N{sub 2}O relative to the previous two categories. Nitrous oxide production is not greatly affected by pH between neutral and pH=13, but increases significantly in acid solution. The G-value for N{sub 2}O production in 10 wt% potassium tetraphenylborate slurries has been measured under process conditions important at the Savannah River Site.

Walker, D.D.; Hobbs, D.T.; Tiffany, J.B.; Bibler, N.E. (Westinghouse Savannah River Co., Aiken, SC (United States)); Meisel, D. (Argonne National Lab., IL (United States))

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions in Agricultural Crop Production  

Science Conference Proceedings (OSTI)

This final project report describes a three-year long EPRI supplemental project entitled "Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions." This EPRI-sponsored project investigated an innovative approach to developing large-scale, cost-effective greenhouse gas (GHG) emissions offsets that potentially can be implemented across broad geographic areas of the United States and internationally.

2009-12-17T23:59:59.000Z

22

Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions in Agricultural Crop Production  

Science Conference Proceedings (OSTI)

This Technical Update covers the first year of a three-year-long EPRI research project entitled Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions in Agricultural Crop Production. The report provides a project overview and explains the preliminary results yielded from the first year of on-farm research.

2007-10-30T23:59:59.000Z

23

Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions in Agricultural Crop Production  

Science Conference Proceedings (OSTI)

This report covers the first two years of a three-year long project entitled "Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions." This EPRI-sponsored project is investigating an innovative approach to developing large-scale and potentially cost-effective greenhouse gas (GHG) emissions offsets that could be implemented across broad geographic areas of the U.S. and internationally. The tools and information developed in this project will broaden the GHG emissions offset ...

2008-11-11T23:59:59.000Z

24

Regional Sources of Nitrous Oxide over the United States: Seasonal Variation and Spatial Distribution  

SciTech Connect

This paper presents top-down constraints on the magnitude, spatial distribution, and seasonality of nitrous oxide (N{sub 2}O) emissions over the central United States. We analyze data from tall towers in 2004 and 2008 using a high resolution Lagrangian particle dispersion model paired with both geostatistical and Bayesian inversions. Our results indicate peak N{sub 2}O emissions in June with a strong seasonal cycle. The spatial distribution of sources closely mirrors data on fertilizer application with particularly large N{sub 2}O sources over the US Cornbelt. Existing inventories for N{sub 2}O predict emissions that differ substantially from the inverse model results in both seasonal cycle and magnitude. We estimate a total annual N{sub 2}O budget over the central US of 0.9-1.2 TgN/yr and an extrapolated budget for the entire US and Canada of 2.1-2.6 TgN/yr. By this estimate, the US and Canada account for 12-15% of the total global N{sub 2}O source or 32-39% of the global anthropogenic source as reported by the Intergovernmental Panel on Climate Change in 2007.

Miller, S. M.; Kort, E. A.; Hirsch, A. I.; Dlugokencky, E. J.; Andrews, A. E.; Xu, X.; Tian, H.; Nehrkorn, T.; Eluszkiewicz, J.; Michalak, A. M.; Wofsy, S. C.

2012-01-01T23:59:59.000Z

25

Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Reduction Proto col for US Midwest Agriculture  

Science Conference Proceedings (OSTI)

Status: Published Citation: Millar, N; Robertson, GP; Grace, PR; Gehl, RJ; and Hoben, JP. 2010. Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Reduction Protocol for US Midwest Agriculture. In Journal of Mitigation and Adaptation Strategies for Global Change,Volume 15, Number 2, 2010, pp. 185-204. Link to Journal Publication: See Journal of Mitigation and Adaptation Strategies for Global Change.

2010-09-03T23:59:59.000Z

26

Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Redu ction Protocol for U.S. Midwest Agriculture  

Science Conference Proceedings (OSTI)

Status: Published Citation: Millar, N; Robertson, GP; Grace, PR; Gehl, RJ; and Hoben; JP. 2010. Nitrogen Fertilizer Management for Nitrous Oxide (N2O) Mitigation in Intensive Corn (Maize) Production: An Emissions Reduction Protocol for U.S. Midwest Agriculture. In Mitigation and Adaptation Strategies for Global Change, Volume 15, Number 2, 2010, pp. 185-204. A peer-reviewed journal article that identifies, describes and analyzes socio-economic factors that may encourage or inhibit farmers from participat...

2009-12-17T23:59:59.000Z

27

Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions in Agricultural Crop Production: Experience Validating a New GHG Offset Protocol  

Science Conference Proceedings (OSTI)

This project report describes in part the second phase (years four through six, 2010–2012) of a two-phase, six-year long EPRI-sponsored research project entitled “Developing Greenhouse Gas Emissions Offsets by Reducing Nitrous Oxide (N2O) Emissions.” This project investigated an innovative approach to developing large-scale, cost-effective greenhouse gas (GHG) emissions offsets that potentially can be implemented across broad geographic areas of the ...

2013-05-28T23:59:59.000Z

28

Effect of fresh green waste and green waste compost on mineral nitrogen, nitrous oxide and carbon dioxide from a Vertisol  

Science Conference Proceedings (OSTI)

Incorporation of organic waste amendments to a horticultural soil, prior to expected risk periods, could immobilise mineral N, ultimately reducing nitrogen (N) losses as nitrous oxide (N{sub 2}O) and leaching. Two organic waste amendments were selected, a fresh green waste (FGW) and green waste compost (GWC) as they had suitable biochemical attributes to initiate N immobilisation into the microbial biomass and organic N forms. These characteristics include a high C:N ratio (FGW 44:1, GWC 35:1), low total N (14%). Both products were applied at 3 t C/ha to a high N (plus N fertiliser) or low N (no fertiliser addition) Vertisol soil in PVC columns. Cumulative N{sub 2}O production over the 28 day incubation from the control soil was 1.5 mg/N{sub 2}O/m{sup 2}, and 11 mg/N{sub 2}O/m{sup 2} from the control + N. The N{sub 2}O emission decreased with GWC addition (P < 0.05) for the high N soil, reducing cumulative N{sub 2}O emissions by 38% by the conclusion of the incubation. Analysis of mineral N concentrations at 7, 14 and 28 days identified that both FGW and GWC induced microbial immobilisation of N in the first 7 days of incubation regardless of whether the soil environment was initially high or low in N; with the FGW immobilising up to 30% of available N. It is likely that the reduced mineral N due to N immobilisation led to a reduced substrate for N{sub 2}O production during the first week of the trial, when soil N{sub 2}O emissions peaked. An additional finding was that FGW + N did not decrease cumulative N{sub 2}O emissions compared to the control + N, potentially due to the fact that it stimulated microbial respiration resulting in anaerobic micro sites in the soil and ultimately N{sub 2}O production via denitrification. Therefore, both materials could be used as post harvest amendments in horticulture to minimise N loss through nitrate-N leaching in the risk periods between crop rotations. The mature GWC has potential to reduce N{sub 2}O, an important greenhouse gas.

Vaughan, Sarah M., E-mail: s.vaughan@uq.edu.au [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia); Dalal, Ram C. [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia); Department of Environment and Resource Management, 80 Meiers Rd., Indooroopilly, QLD 4068 (Australia); Harper, Stephen M. [Department of Employment, Economic Development and Innovation, Warrego Highway, Gatton, QLD 4343 (Australia); Menzies, Neal W. [School of Land, Crop and Food Sciences, University of Queensland, St. Lucia, QLD 4072 (Australia)

2011-08-15T23:59:59.000Z

29

Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, nitrogen, and ammonia in contact with tank 241-SY-101 simulated waste  

DOE Green Energy (OSTI)

Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. Described in this report are the results of tests to evaluate the rates of thermal and combined thermal and radiolytic reactions involving flammable gases in the presence of Tank 241-SY-101 simulated waste. Flammable gases generated by the radiolysis of water and by the thermal and radiolytic decomposition of organic waste constituents may themselves participate in further reactions. Examples include the decomposition of nitrous oxide to yield nitrogen and oxygen, the reaction of nitrous oxide and hydrogen to produce nitrogen and water, and the reaction of nitrogen and hydrogen to produce ammonia. The composition of the gases trapped in bubbles in the wastes might therefore change continuously as a function of the time that the gas bubbles are retained.

Bryan, S.A.; Pederson, L.R.

1996-02-01T23:59:59.000Z

30

Halocarbon and Other Atmospheric Trace Species (HATS) | Data.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Halocarbon and Other Atmospheric Trace Species (HATS) Halocarbon and Other Atmospheric Trace Species (HATS) Agriculture Community Menu DATA APPS EVENTS DEVELOPER STATISTICS COLLABORATE ABOUT Agriculture You are here Data.gov » Communities » Agriculture » Data Halocarbon and Other Atmospheric Trace Species (HATS) Dataset Summary Description The general mission of the Halocarbons and other Atmospheric Trace Species group is to quantify the distributions and magnitudes of sources and sinks for atmospheric nitrous oxide (N2O) and halogen containing compounds. HATS utilizes numerous types of platforms, including ground-based stations, towers, ocean vessels, aircraft, and balloons, to accomplish its mission. For a detailed mission statement, consult our FAQ. Tags {"nitrous oxide","sulfur hexaflouride",CFC-11,CFC-12,CFC-113,CCl4,CH3CCl3,CH3Cl,halon-1211,HCFC-22,HCFC-142b,halocarbons,chromatograph,aircraft,balloons,vessels,ships,towers,"natural resources",environment,air,"GHG "}

31

Mechanistic, sensitivity, and uncertainty studies of the atmospheric oxidation of dimethylsulfide  

E-Print Network (OSTI)

The global-scale emissions and reactivity of dimethylsulfide (CH3SCH3, DMS) make it an integral component in the atmospheric sulfur cycle. DMS is rapidly oxidized in the atmosphere by a complex gas-phase mechanism involving ...

Lucas, Donald David, 1969-

2003-01-01T23:59:59.000Z

32

Bayesian Modelling Volatility of Growth Rate in Atmospheric Carbon Dioxide Concentrations  

Science Conference Proceedings (OSTI)

Atmospheric gases, such as carbon dioxide, ozone, methane, nitrous oxide, and etc., create a natural greenhouse effect and cause climate change. Therefore, modelling behavior of these gases could help policy makers to control greenhouse effects. In a ... Keywords: Stochastic volatility, Smooth transition autoregressive, Markov chain Monte Carlo, methods, Bayesian, ARCH, GARCH

Esmail Amiri

2009-12-01T23:59:59.000Z

33

Pathways for the Oxidation of Sarin in Urban Atmospheres  

Science Conference Proceedings (OSTI)

Terrorists have threatened and carried out chemicalhiological agent attacks on targets in major cities. The nerve agent sarin figured prominently in one well-publicized incident. Vapors disseminating from open containers in a Tokyo subway caused thousands of casualties. High-resolution tracer transport modeling of agent dispersion is at hand and will be enhanced by data on reactions with components of the urban atmosphere. As a sample of the level of complexity currently attainable, we elaborate the mechanisms by which sarin can decompose in polluted air. A release scenario is outlined involving the passage of a gas-phase agent through a city locale in the daytime. The atmospheric chemistry database on related organophosphorus pesticides is mined for rate and product information. The hydroxyl,radical and fine-mode particles are identified as major reactants. A review of urban air chernistry/rnicrophysics generates concentration tables for major oxidant and aerosol types in both clean and dirty environments. Organic structure-reactivity relationships yield an upper limit of 10-1' cm3 molecule-' S-* for hydrogen abstraction by hydroxyl. The associated midday loss time scale could be as little as one hour. Product distributions are difficult to define but may include nontoxic organic oxygenates, inorganic phosphorus acids, sarin-like aldehydes, and nitrates preserving cholinergic capabilities. Agent molecules will contact aerosol surfaces in on the order of minutes, with hydrolysis and side-chain oxidation as likely reaction channels.

Gerald E. Streit; James E. Bossert; Jeffrey S. Gaffney; Jon Reisner; Laurie A. McNair; Michael Brown; Scott Elliott

1998-11-01T23:59:59.000Z

34

Nitrous Oxide and Molecular Nitrogen Isotopic Compositions and Aerosol Optical Properties: Experiments and Observations Relevant to Planetary Atmospheres  

E-Print Network (OSTI)

D6), doi:10.1029/1096JD03382. Volk, C. M. , et al. (1996),CIRS, Icarus , 191 , 712-721. Volk, C. M. , et al. (1996),Mass Spectrom. , 22, 603-312. Volk, C. M. , et al. (1996),

Croteau, Philip Louis

2010-01-01T23:59:59.000Z

35

Nitrous Oxide and Molecular Nitrogen Isotopic Compositions and Aerosol Optical Properties: Experiments and Observations Relevant to Planetary Atmospheres  

E-Print Network (OSTI)

through biomass and fossil fuel combustion, which show thatof industrial combustion or biomass burning processes butbiomass burning, based on recent measurements of a combustion

Croteau, Philip Louis

2010-01-01T23:59:59.000Z

36

Nitrous Oxide and Molecular Nitrogen Isotopic Compositions and Aerosol Optical Properties: Experiments and Observations Relevant to Planetary Atmospheres  

E-Print Network (OSTI)

not included here). The solar spectrum at 625 km in Earth’ssee if structure in the solar spectrum changes the ratio ofnot included here). The solar spectrum at 625 km in Earth’s

Croteau, Philip Louis

2010-01-01T23:59:59.000Z

37

Ignition and Combustion of Fuel Pockets Moving in an Oxidizing Atmosphere  

E-Print Network (OSTI)

Ignition and Combustion of Fuel Pockets Moving in an Oxidizing Atmosphere JOEL DAOU Dpto, Spain. E-mail: daou@tupi.dmt.upm.es Ignition and combustion of an initially spherical pocket of fuel, the results provide a good appreciation of the dynamics of the combustion process. For example, it is found

Heil, Matthias

38

Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol  

SciTech Connect

A detailed understanding of the sources, transformations, and fates of organic species in the environment is crucial because of the central roles that organics play in human health, biogeochemical cycles, and Earth's climate. However, such an understanding is hindered by the immense chemical complexity of environmental mixtures of organics; for example, atmospheric organic aerosol consists of at least thousands of individual compounds, all of which likely evolve chemically over their atmospheric lifetimes. Here we demonstrate the utility of describing organic aerosol (and other complex organic mixtures) in terms of average carbon oxidation state (OSC), a quantity that always increases with oxidation, and is readily measured using state-of-the-art analytical techniques. Field and laboratory measurements of OSC , using several such techniques, constrain the chemical properties of the organics and demonstrate that the formation and evolution of organic aerosol involves simultaneous changes to both carbon oxidation state and carbon number (nC).

Massachusetts Institute of Technology; Kroll, Jesse H.; Donahue, Neil M.; Jimenez, Jose L.; Kessler, Sean H.; Canagaratna, Manjula R.; Wilson, Kevin R.; Altieri, Katye E.; Mazzoleni, Lynn R.; Wozniak, Andrew S.; Bluhm, Hendrik; Mysak, Erin R.; Smith, Jared D.; Kolb, Charles E.; Worsnop, Douglas R.

2010-11-05T23:59:59.000Z

39

Adaptation to space applications of a 2000 c furnace with oxidizing atmosphere  

SciTech Connect

The possibility of using a low weight low power consumption furnace with oxidizing atmosphere at 2000 C for space applications is discussed. The main heating element is made of zirconium oxide with a platinum preheating system. The structure and stabilization of zirconium oxide are detailed together with its application to the space situation. The static and dynamic regimes are discussed with regard to measurement of the resistivity as a function of temperature and dynamic model. The temperature distribution in the furnace and in a main heating element were studied in relation to thermal insulation and weight budget. A model is proposed for optimal control and thermostat using analog simulation. The final concept requires 350 W for an isothermal furnace of 20 mm diameter weighing 3 kg. The cases of temperature gradient furnaces and of universal furnaces are reviewed. (GRA)

1975-01-01T23:59:59.000Z

40

CO oxidation over ruthenium: identification of the catalytically active phases at near-atmospheric pressures  

SciTech Connect

CO oxidation was carried out over Ru(0001) and RuO2(110) thin film grown on Ru(0001) at various O2/CO ratios near atmospheric pressures. Reaction kinetics, coupled with in situ polarization modulation infrared reflection absorption spectroscopy (PM-IRAS) and post-reaction Auger electron spectroscopy (AES) measurements were used to identify the catalytically relevant phases at different reaction conditions. Under stoichiometric and reducing conditions at all reaction temperatures, as well as net-oxidizing reaction conditions below {approx}475 K, a reduced metallic phase with chemisorbed oxygen is the thermodynamically stable and catalytically active phase. On this surface CO oxidation occurs at surface defect sites, for example step edges. Only at net-oxidizing reaction conditions and above {approx}475 K is the RuO2 thin film grown on metallic Ru stable and active. However, RuO2 is not active itself without the existence of the metal substrate, suggesting the importance of a strong metal-substrate interaction (SMSI).

Gao, Feng; Goodman, Wayne D.

2012-05-21T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Some observations of retorting phenomena in shale blocks. [Large blocks in oxidizing and nonoxidizing atmospheres  

DOE Green Energy (OSTI)

A small retort (nominal capacity, one-half-ton oil shale) with glass viewing ports was designed and operated to provide additional information on the retorting characteristics of large blocks of oil shale in oxidizing and nonoxidizing atmospheres. Shale blocks selected for retorting ranged in weight from 240 to 680 pounds and represented shale grades of 14 to 36 gallons of oil per ton. In all tests, temperature profiles show a lag in heating rate of the inside of these blocks compared to the heating rate for the shale rubble surrounding them. Analytical data on the vent gases and gas samples taken from inside the blocks are included along with physical observations to expand the technology on retorting large blocks of oil shale.

Minster, R.A.; Martel, R.A.; Harak, A.E.

1976-10-01T23:59:59.000Z

42

On-line coating of glass with tin oxide by atmospheric pressure chemical vapor deposition.  

SciTech Connect

Atmospheric pressure chemical vapor deposition (APCVD) of tin oxide is a very important manufacturing technique used in the production of low-emissivity glass. It is also the primary method used to provide wear-resistant coatings on glass containers. The complexity of these systems, which involve chemical reactions in both the gas phase and on the deposition surface, as well as complex fluid dynamics, makes process optimization and design of new coating reactors a very difficult task. In 2001 the U.S. Dept. of Energy Industrial Technologies Program Glass Industry of the Future Team funded a project to address the need for more accurate data concerning the tin oxide APCVD process. This report presents a case study of on-line APCVD using organometallic precursors, which are the primary reactants used in industrial coating processes. Research staff at Sandia National Laboratories in Livermore, CA, and the PPG Industries Glass Technology Center in Pittsburgh, PA collaborated to produce this work. In this report, we describe a detailed investigation of the factors controlling the growth of tin oxide films. The report begins with a discussion of the basic elements of the deposition chemistry, including gas-phase thermochemistry of tin species and mechanisms of chemical reactions involved in the decomposition of tin precursors. These results provide the basis for experimental investigations in which tin oxide growth rates were measured as a function of all major process variables. The experiments focused on growth from monobutyltintrichloride (MBTC) since this is one of the two primary precursors used industrially. There are almost no reliable growth-rate data available for this precursor. Robust models describing the growth rate as a function of these variables are derived from modeling of these data. Finally, the results are used to conduct computational fluid dynamic simulations of both pilot- and full-scale coating reactors. As a result, general conclusions are reached concerning the factors affecting the growth rate in on-line APCVD reactors. In addition, a substantial body of data was generated that can be used to model many different industrial tin oxide coating processes. These data include the most extensive compilation of thermochemistry for gas-phase tin-containing species as well as kinetic expressions describing tin oxide growth rates over a wide range of temperatures, pressures, and reactant concentrations.

Allendorf, Mark D.; Sopko, J.F. (PPF Industries, Pittsburgh, PA); Houf, William G.; Chae, Yong Kee; McDaniel, Anthony H.; Li, M. (PPF Industries, Pittsburgh, PA); McCamy, J.W. (PPF Industries, Pittsburgh, PA)

2006-11-01T23:59:59.000Z

43

The aging of organic aerosol in the atmosphere : chemical transformations by heterogeneous oxidation  

E-Print Network (OSTI)

The immense chemical complexity of atmospheric organic particulate matter ("aerosol") has left the general field of condensed-phase atmospheric organic chemistry relatively under-developed when compared with either gas-phase ...

Kessler, Sean Herbert

2013-01-01T23:59:59.000Z

44

A Modeling Study of Atmospheric Transport and Photochemistry in the Mixed Layer during Anticyclonic Episodes in Europe. Part II. Calculations of Photo-Oxidant Levels along Air Trajectories  

Science Conference Proceedings (OSTI)

A computer model for photochemical oxidant formation in the atmospheric boundary layer has been used to calculate trends in ozone formation in air masses traveling across Europe. Ozone calculations were made for some actual summertime ...

K. Selby

1987-10-01T23:59:59.000Z

45

Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol  

E-Print Network (OSTI)

for measuring ecosystem carbon oxidation state and oxidativemean oxidation number of carbon (MOC) - A useful concept forJ.F. & Barsanti, K.C. The Carbon Number-Polarity Grid: A

Kroll, Jesse H.

2011-01-01T23:59:59.000Z

46

Chemistry of carbonaceous aerosols : studies of atmospheric processing and OH-initiated oxidation  

E-Print Network (OSTI)

Carbonaceous aerosols are among the most prevalent yet least understood constituents of the atmosphere, particularly in urban environments. We have performed analyses of field samples and laboratory studies to probe the ...

Johnson, Kirsten S. (Kirsten Sue)

2008-01-01T23:59:59.000Z

47

Atmospheric Trace Gases, Carbon Isotopes, Radionuclides, and Aerosols: Atmospheric Carbon Dioxide Data from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer (OSTI)

CDIAC products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication titled Trends Online: A Compendium of Global Change Data. Most datasets, many with numerous data files, are free to download from CDIAC's ftp area. Information related to atmospheric carbon dioxide data includes: Atmospheric Carbon Dioxide and Carbon Isotopes • Atmospheric carbon dioxide records from Mauna Loa, Hawaii • Monthly atmospheric CO2 mixing ratios and other data from the NOAA/CMDL continuous monitoring network • Data from the CSIRO GASLAB Flask Sampling Network • Atmospheric CO2 records from continuous measurements at Jubany Station, Antarctica and from 10 sites in the SIO air sampling network • Historical data from the extended Vostok ice core (2003) and the Siple Station ice core (1997) • Historical records from the Law Dome DE08, DE08-2, and DSS ice cores (1998) • AmeriFlux Carbon Dioxide, Water Vapor, and Energy Balance Measurements • Data from the Canadian Background Air Pollution Monitoring Network • Flask Samples from at U.S.S.R.-Operated Sites (1991) • The CISIRO (Australia) Monitoring Program from Aircraft for 1972-1981 • CO2 Concentrations in Surface Water and the Atmosphere during 1986-1989 NOAA/PMEL Cruises in the Pacific and Indian Oceans • Surface Water and Atmospheric CO2 and Nitrous Oxide Observations by Shipboard Automated Gas Chromatography: Results from Expeditions Between 1977 and 1990 (1992) • IPCC Working Group 1, 1994: Modeling Results Relating Future Atmospheric CO2 Concentrations to Industrial Emissions (1995). New datasets are added when available to the category of atmospheric carbon dioxide.

48

USING POLYMERIC HYDROGEN GETTERS TO PREVENT COMBUSTIBLE ATMOSPHERES DURING INTERIM SAFE STORAGE OF PLUTONIUM OXIDE  

DOE Green Energy (OSTI)

Nuclear Materials Management (NMM) of WSRC has recently installed the capability to perform both non-destructive and destructive examination of 3013 containers of Pu oxide in accordance with DOE-STD-3013. The containers will be opened and the oxide will be sampled for analysis. The remaining bulk oxide must then be safely stored in a non-3013-compliant configuration. Available processing equipment and controls cannot prevent the oxide from adsorbing moisture during this process. Subsequent radiolysis of moisture during storage may generate combustible quantities of gases while waiting final processing, and satisfying DOE Interim Safe Storage Criteria (ISSC) would require that storage containers be vented at impractical frequencies. With support from an independent National Laboratory, WSRC/NMM has demonstrated that a commercial hydrogen getter material will effectively prevent the accumulation of combustible gas concentrations. A project overview, including storage requirements and strategies, as well as getter technology, current test results, and anticipated future developments will be addressed.

Woodsmall, T

2007-05-24T23:59:59.000Z

49

Atmospheric Radiation Measurement Program facilities newsletter, July 2001.  

Science Conference Proceedings (OSTI)

Global Warming and Methane--Global warming, an increase in Earth's near-surface temperature, is believed to result from the buildup of what scientists refer to as ''greenhouse gases.'' These gases include water vapor, carbon dioxide, methane, nitrous oxide, ozone, perfluorocarbons, hydrofluoro-carbons, and sulfur hexafluoride. Greenhouse gases can absorb outgoing infrared (heat) radiation and re-emit it back to Earth, warming the surface. Thus, these gases act like the glass of a greenhouse enclosure, trapping infrared radiation inside and warming the space. One of the more important greenhouse gases is the naturally occurring hydrocarbon methane. Methane, a primary component of natural gas, is the second most important contributor to the greenhouse effect (after carbon dioxide). Natural sources of methane include wetlands, fossil sources, termites, oceans, fresh-waters, and non-wetland soils. Methane is also produced by human-related (or anthropogenic) activities such as fossil fuel production, coal mining, rice cultivation, biomass burning, water treatment facilities, waste management operations and landfills, and domesticated livestock operations (Figure 1). These anthropogenic activities account for approximately 70% of the methane emissions to the atmosphere. Methane is removed naturally from the atmosphere in three ways. These methods, commonly referred to as sinks, are oxidation by chemical reaction with tropospheric hydroxyl ion, oxidation within the stratosphere, and microbial uptake by soils. In spite of their important role in removing excess methane from the atmosphere, the sinks cannot keep up with global methane production. Methane concentrations in the atmosphere have increased by 145% since 1800. Increases in atmospheric methane roughly parallel world population growth, pointing to anthropogenic sources as the cause (Figure 2). Increases in the methane concentration reduce Earth's natural cooling efficiency by trapping more of the outgoing terrestrial infrared radiation, increasing the near-surface temperature.

Holdridge, D. J.

2001-07-23T23:59:59.000Z

50

Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants/Hygroscopicity and CCN Activity of Secondary & Processed Primary Organic Aerosols  

Science Conference Proceedings (OSTI)

The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was to carry out reactions of representative anthropogenic and biogenic VOCs and organic particles with ozone (O3), and hydroxyl (OH), nitrate (NO3), and chlorine (Cl) radicals, which are the major atmospheric oxidants, under simulated atmospheric conditions in large-volume environmental chambers. A combination of on-line and off-line analytical techniques were used to monitor the chemical and physical properties of the particles including their hygroscopicity and CCN activity. The results of the studies were used to (1) improve scientific understanding of the relationships between the chemical composition of organic particles and their hygroscopicity and CCN activity, (2) develop an improved molecular level theoretical framework for describing these relationships, and (3) establish a large database that is being used to develop parameterizations relating organic aerosol chemical properties and SOA sources to particle hygroscopicity and CCN activity for use in regional and global atmospheric air quality and climate models.

Ziemann, P.J.; Arey, J.; Atkinson, R.; Kreidenweis, S.M.; Petters, M.D.

2012-06-13T23:59:59.000Z

51

Kinetics, FTIR and controlled atmosphere EXAFS study of the effect of chlorine on Pt supported catalysts during oxidation reactions.  

SciTech Connect

The poisoning effect of Cl on the activity of Pt-supported catalysts for CO, methane, and ethane oxidation has been investigated by kinetic studies and in situ IR and controlled atmosphere EXAFS spectroscopies. Catalysts containing 1.5% Pt/Al{sub 2}O{sub 3} were prepared by incipient wetness from H{sub 2}PtCl{sub 6} and Pt(NH{sub 3}){sub 4}(NO{sub 3}){sub 2} precursors. The reduced catalysts have similar dispersion (0.8) as estimated by H{sub 2} chemisorption. The Cl-free catalyst was 10 times more active than the Cl-containing catalyst during CO and ethane oxidation. Addition of HCl to the Cl-free catalyst rendered its activity identical to the catalyst prepared from Cl-containing precursors. The presence of Cl also affects the activity of 2% Pt/SiO{sub 2} catalysts, but to a lower extent. On the Cl-free oxidation catalyst, Pt-Pt and Pt-O bonds were detected using EXAFS, suggesting that the reduced metal particles are not fully oxidized under the reaction conditions. Additionally, chemisorption of CO by the oxidized catalyst indicates that a portion of the reduced Pt atoms is exposed to the reactants. On the Cl-containing catalyst, there are also Pt-Cl as well as Pt-Pt and Pt-O bonds. The later catalyst, however, does not chemisorb CO, indicating that there are no reduced surface Pt atoms. The effect of Cl poisoning on the oxidation activity of Pt supported on silica is similar to that on alumina. IR results show that chlorine significantly reduces the amount of CO adsorbed on metallic Pt sites. At low temperature there is little CO adsorbed on the Cl-containing Pt/silica catalyst, while at higher temperature the amount of adsorbed CO increases, likely due to reduction of the oxidized surface. The catalyst activities correlate well with the amount of reduced surface sites, and a model is proposed to explain the mechanism of chloride poisoning, which is shown to occur mainly by site blocking.

Gracia, F. J.; Wolf, E. E.; Miller, J. T.; Kropf, A. J.; Chemical Engineering; Univ. of Notre Dame; BP Research Center

2002-07-25T23:59:59.000Z

52

An evaluation of anti-oxidative protection for cells against atmospheric pressure cold plasma treatment  

Science Conference Proceedings (OSTI)

With the development of plasma medicine, safety issues are emerging as a serious concern. In this study, both intracellular (genetic engineering) and extracellular (scavengers) measures were tested in an effort to determine the best protection for cells against plasma-induced oxidative stress. All results of immediate reactive species detection, short term survival and long term proliferation, suggest that intracellular pathways are superior in reducing oxidative stress and cell death. This work provides a potential mechanism to enhance safety and identifies precautionary measures that should be taken in future clinical applications of plasmas.

Ma Ruonan; Zhang Qian [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); Feng Hongqing; Liang Yongdong [College of Engineering, Peking University, Beijing 100871 (China); Li Fangting [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); College of Physics, Peking University, Beijing 100871 (China); Zhu Weidong [Department of Applied Science and Technology, Saint Peter's College, Jersey City, New Jersey 07306 (United States); Zhang Jue; Fang Jing [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); College of Engineering, Peking University, Beijing 100871 (China); Becker, Kurt H. [Department of Applied Physics, Polytechnic Institute of New York University, Brooklyn, New York 11201 (United States)

2012-03-19T23:59:59.000Z

53

Multiple sample characterization of coals and other substances by controlled-atmosphere programmed temperature oxidation  

DOE Patents (OSTI)

A furnace with two hot zones holds multiple analysis tubes. Each tube has a separable sample-packing section positioned in the first hot zone and a catalyst-packing section positioned in the second hot zone. A mass flow controller is connected to an inlet of each sample tube, and gas is supplied to the mass flow controller. Oxygen is supplied through a mass flow controller to each tube to either or both of an inlet of the first tube and an intermediate portion between the tube sections to intermingle with and oxidize the entrained gases evolved from the sample. Oxidation of those gases is completed in the catalyst in each second tube section. A thermocouple within a sample reduces furnace temperature when an exothermic condition is sensed within the sample. Oxidized gases flow from outlets of the tubes to individual gas cells. The cells are sequentially aligned with an infrared detector, which senses the composition and quantities of the gas components. Each elongated cell is tapered inward toward the center from cell windows at the ends. Volume is reduced from a conventional cell, while permitting maximum interaction of gas with the light beam. Reduced volume and angulation of the cell inlets provide rapid purgings of the cell, providing shorter cycles between detections. For coal and other high molecular weight samples, from 50% to 100% oxygen is introduced to the tubes.

LaCount, Robert B. (403 Arbor Ct., Waynesburg, PA 15370)

1993-01-01T23:59:59.000Z

54

Characteristics of indium oxide plasma filters deposited by atmospheric pressure CVD  

DOE Green Energy (OSTI)

Thin films of undoped and tin-doped In{sub 2}O{sub 3} are being investigated for use as plasma filters in spectral control applications for thermal photovoltaic cells. These films are required to exhibit high reflectance at wavelengths longer than the plasma wavelength {lambda}{sub p}, high transmittance at wavelengths shorter than {lambda}{sub p} and low absorption throughout the spectrum. Both types of films were grown via atmospheric pressure chemical vapor deposition (APCVD) on Si (100) and fused silica substrates using trimethylindium (TMI), tetraethyltin (TET), and oxygen as the precursors. Fourier Transform InfraRed (FTIR) spectroscopy was used to measure the filter transmittance and reflectance between 1.8--20 {micro}m. Nominal conditions used during the growth of undoped In{sub 2}O{sub 3} were a substrate temperature of 450 C and partial pressures of 1.4 {times} 10{sup {minus}4} atm. and 1 {times} 10{sup {minus}3} atm. for TMI and O{sub 2} respectively. The O{sub 2}/TMI partial pressure ratio and substrate temperature were systematically varied to control the filter characteristics. The plasma wavelength {lambda}{sub p} was found to be a sensitive function of these parameters. Post-growth annealing of the films was done in inert as well as air ambient at elevated temperatures, but was found to have no beneficial effect. Tin-doped In{sub 2}O{sub 3} was grown under similar conditions as above, with a typical TET partial pressure of 4 {times} 10{sup {minus}6} atm. Here also, the material properties and consequently the optical response were found to be strongly dependent on growth conditions such as O{sub 2} and TET partial pressures. Both undoped and tin-doped In{sub 2}O{sub 3} grown on fused silica exhibited enhanced transmittance due to the close matching of refractive indices of In{sub 2}O{sub 3} and silica. X-ray diffractometer measurements indicated that all these films were polycrystalline and highly textured towards the (111) direction. The best undoped and tin-doped In{sub 2}O{sub 3} films had a {lambda}{sub p} around 2.7 {micro}m, peak reflectance greater than 75% and residual absorption below 20%. These results indicate the promise of undoped and tin-doped In{sub 2}O{sub 3} as a material for plasma filters.

Langlois, E.; Murthy, S.D.; Bhat, I.; Gutmann, R. [Rensselaer Polytechnic Inst., Troy, NY (United States); Brown, E.; Dziendziel, R.; Freeman, M.; Choudhury, N. [Lockheed Martin Corp., Schenectady, NY (United States)

1995-07-01T23:59:59.000Z

55

Premixed Carbon Monoxide–Nitrous Oxide–Hydrogen Flames ...  

Science Conference Proceedings (OSTI)

... the combustion emission charac- teristics of stationary and mobile power plants. ... present data are in good agreement with the low-hydro- gen data ...

2012-12-06T23:59:59.000Z

56

Modeling global atmospheric CO2 with improved emission inventories and CO2 production from the oxidation of other carbon species  

Science Conference Proceedings (OSTI)

The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of CO2 chemical production on monthly-averaged loss rates of CO (a key precursor and intermediate in the oxidation of organic carbon) and apply an associated surface correction for inventories that have counted emissions of CO2 precursors as CO2. We also explore the benefit of assimilating satellite observations of CO into GEOS-Chem to obtain an observation-based estimate of the CO2 chemical source. The CO assimilation corrects for an underestimate of atmospheric CO abundances in the model, resulting in increases of as much as 24% in the chemical source during May June 2006, and increasing the global annual estimate of CO2 chemical production from 1.05 to 1.18 Pg C. Comparisons of model CO2 with measurements are carried out in order to investigate the spatial and temporal distributions that result when these new sources are added. Inclusion of CO2 emissions from shipping and aviation are shown to increase the global CO2 latitudinal gradient by just over 0.10 ppm (3%), while the inclusion of CO2 chemical production (and the surface correction) is shown to decrease the latitudinal gradient by about 0.40 ppm (10%) with a complex spatial structure generally resulting in decreased CO2 over land and increased CO2 over the oceans. Since these CO2 emissions are omitted or misrepresented in most inverse modeling work to date, their implementation in forward simulations should lead to improved inverse modeling estimates of terrestrial biospheric fluxes.

Nassar, Ray [University of Toronto; Jones, DBA [University of Toronto; Suntharalingam, P [University of East Anglia, Norwich, United Kingdom; Chen, j. [University of Toronto; Andres, Robert Joseph [ORNL; Wecht, K. J. [Harvard University; Yantosca, R. M. [Harvard University; Kulawik, SS [Jet Propulsion Laboratory, Pasadena, CA; Bowman, K [Jet Propulsion Laboratory, Pasadena, CA; Worden, JR [Jet Propulsion Laboratory, Pasadena, CA; Machida, T [National Institute for Environmental Studies, Japan; Matsueda, H [Meteorological Research Institute, Japan

2010-01-01T23:59:59.000Z

57

Biomass burning sources of nitrogen oxides, carbon monoxide, and non-methane hydrocarbons  

SciTech Connect

Biomass burning is an important source of many key tropospheric species, including aerosols, carbon dioxide (CO{sub 2}), nitrogen oxides (NO{sub {times}}=NO+NO{sub 2}), carbon monoxide (CO), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), methyl bromide (CH{sub 3}Br), ammonia (NH{sub 3}), non-methane hydrocarbons (NMHCs) and other species. These emissions and their subsequent products act as pollutants and affect greenhouse warming of the atmosphere. One important by-product of biomass burning is tropospheric ozone, which is a pollutant that also absorbs infrared radiation. Ozone is formed when CO, CH{sub 4}, and NMHCs react in the presence of NO{sub {times}} and sunlight. Ozone concentrations in tropical regions (where the bulk of biomass burning occurs) may increase due to biomass burning. Additionally, biomass burning can increase the concentration of nitric acid (HNO{sub 3}), a key component of acid rain.

Atherton, C.S.

1995-11-01T23:59:59.000Z

58

Effect of Uranium Oxidation State and Sintering Atmosphere on Phase Formation of the Ceramic Wasteform for Plutonium  

SciTech Connect

'This paper discusses the effects of various sources of uranium oxide on the mineralogy and density of the baseline composition (AO) targeted for plutonium immobilization.'

Pareizs, J.M.

1999-07-22T23:59:59.000Z

59

A Ruggedized Ultrasensitive Field Air Sampler for Differentially Determining Tritium Oxide and Gas in Ambient Air Atmosphere  

SciTech Connect

The instrument described is an operational, practical, ruggedized, ultrasensitive, tritium field air sampler assembled for the simultaneous, differential sampling of the environmental air for tritium oxide and elemental tritium. The system uses hardware assembled and packaged in such manner as to facilitate use in the field as well as in the laboratory. The sampling system occupies relatively small space and is simple to operate. The detection sensitivity approaches tritium background levels and is achieved by high volume sampling, efficient removal of tritium oxide and elemental tritium ("tritium gas"), and counting the recovered fractions by liquid scintillation spectrometry.

Brown, R.; Meyer, H. E.; Robinson, B.; Sheehan, W. E.

1971-12-21T23:59:59.000Z

60

Atmospheric Aerosols  

NLE Websites -- All DOE Office Websites (Extended Search)

measuring equipment Atmospheric Aerosols Atmospheric aerosol research at Berkeley Lab seeks to understand the air quality and climate impacts of particles in the atmosphere. On...

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Atmospheric Aerosols  

NLE Websites -- All DOE Office Websites (Extended Search)

Tom Kirchstetter with aerosol measurement instrument Atmospheric Aerosols Atmospheric aerosol research at LBNL seeks to understand the air quality and climate impacts of particles...

62

An Intercomparison of Ground-Based Solar FTIR Measurements of Atmospheric Gases at Eureka, Canada  

Science Conference Proceedings (OSTI)

The authors report the results of an intercomparison of vertical column amounts of hydrogen chloride (HCl), hydrogen fluoride (HF), nitrous oxide (N2O), nitric acid (HNO3), methane (CH4), ozone (O3), carbon dioxide (CO2), and nitrogen (N2) ...

C. Paton-Walsh; R. L. Mittermeier; W. Bell; H. Fast; N. B. Jones; A. Meier

2008-11-01T23:59:59.000Z

63

Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review  

Science Conference Proceedings (OSTI)

Nonmethane hydrocarbons are ubiquitous trace atmospheric constituents yet they control the oxidation capacity of the atmosphere. Both anthropogenic and biogenic processes contribute to the release of hydrocarbons to the atmosphere. In this ...

J. D. Fuentes; L. Gu; M. Lerdau; R. Atkinson; D. Baldocchi; J. W. Bottenheim; P. Ciccioli; B. Lamb; C. Geron; A. Guenther; T. D. Sharkey; W. Stockwell

2000-07-01T23:59:59.000Z

64

Katharine Gebbie GHG Emissions Speech ? June 2, 2010 ...  

Science Conference Proceedings (OSTI)

... 2. We are also releasing other gases – methane, nitrous oxide, sulfur hexafluoride – into the atmosphere that trap heat more effectively than CO ...

2012-05-10T23:59:59.000Z

65

Global Warming and Greenhouse Gases  

Science Conference Proceedings (OSTI)

... NIST is producing new suites of primary gas standards for carbon dioxide, methane, carbon monoxide, and nitrous oxide in air at atmospheric levels ...

2013-09-20T23:59:59.000Z

66

NIST Kevin Douglass  

Science Conference Proceedings (OSTI)

... 1.6 micron atmospheric window region where three critical greenhouse gases, carbon dioxide (CO 2 ), nitrous oxide (N 2 O), and methane (CH 4 ...

2013-04-01T23:59:59.000Z

67

Atmospheric radiation measurement program facilities newsletter, September 2001.  

SciTech Connect

Our Changing Climate--Is our climate really changing? How do we measure climate change? How can we predict what Earth's climate will be like for generations to come? One focus of the Atmospheric Radiation Measurement (ARM) Program is to improve scientific climate models enough to achieve reliable regional prediction of future climate. According to the Environmental Protection Agency (EPA), the global mean surface temperature has increased by 0.5-1.0 F since the late 19th century. The 20th century's 10 warmest years all occurred in the last 15 years of the century, with 1998 being the warmest year of record. The global mean surface temperature is measured by a network of temperature-sensing instruments distributed around the world, including ships, ocean buoys, and weather stations on land. The data from this network are retrieved and analyzed by various organizations, including the National Aeronautics and Space Administration, the National Oceanic and Atmospheric Administration, and the World Meteorological Organization. Worldwide temperature records date back to 1860. To reconstruct Earth's temperature history before 1860, scientists use limited temperature records, along with proxy indicators such as tree rings, pollen records, and analysis of air frozen in ancient ice. The solar energy received from the sun drives Earth's weather and climate. Some of this energy is reflected and filtered by the atmosphere, but most is absorbed by Earth's surface. The absorbed solar radiation warms the surface and is re-radiated as heat energy into the atmosphere. Some atmospheric gases, called greenhouse gases, trap some of the re-emitted heat, keeping the surface temperature regulated and suitable for sustaining life. Although the greenhouse effect is natural, some evidence indicates that human activities are producing increased levels of some greenhouse gases such as carbon dioxide, methane, and nitrous oxide. Scientists believe that the combustion of fossil fuels is responsible for the increased levels of carbon dioxide in the atmosphere. According to the EPA, the burning of fossil fuels for cars and trucks, the heating of homes and businesses, and the operation of power plants account for approximately 98% of U.S. carbon dioxide emissions. The increase of greenhouse gases will, theoretically, enhance the greenhouse effect by trapping more of the heat energy emitted by Earth's surface, thus increasing the surface temperatures on a global scale. Scientists expect that the global average surface temperature could rise 1-4.5 F in the next 50 years and as much as 10 F in the next century. Global warming could potentially have harmful effects on human health, water resources, forests, agriculture, wildlife, and coastal areas. A few degrees of warming might lead to more frequent and severe heat waves, worsened air pollution with adverse effects on human respiratory health, and wider spread of tropical disease such as malaria. The world's hydrologic cycle might be affected by an increase in evaporation and, thus, in precipitation. An increase in evaporation will increase atmospheric water vapor, a significant natural greenhouse gas. The increase in water vapor might further enhance the global warming caused by the greenhouse effect. This is known as a positive feedback. The increase in water vapor could also change the amount of clouds present in the atmosphere, which could reduce temperatures in a negative feedback. Many interrelated factors affect the global climate and are responsible for climate change. Predicting the outcome of the interactions among the many factors is not easy, but it must be addressed. The ARM Program is taking a lead in this effort by collecting vast amounts of data whose analysis will improve our forecasting models for both daily weather and long-term climate. For more information on the ARM Program, please visit our web site at www.arm.gov.

Holdridge, D. J.

2001-10-10T23:59:59.000Z

68

Atmospheric radiation measurement program facilities newsletter, September 2001.  

DOE Green Energy (OSTI)

Our Changing Climate--Is our climate really changing? How do we measure climate change? How can we predict what Earth's climate will be like for generations to come? One focus of the Atmospheric Radiation Measurement (ARM) Program is to improve scientific climate models enough to achieve reliable regional prediction of future climate. According to the Environmental Protection Agency (EPA), the global mean surface temperature has increased by 0.5-1.0 F since the late 19th century. The 20th century's 10 warmest years all occurred in the last 15 years of the century, with 1998 being the warmest year of record. The global mean surface temperature is measured by a network of temperature-sensing instruments distributed around the world, including ships, ocean buoys, and weather stations on land. The data from this network are retrieved and analyzed by various organizations, including the National Aeronautics and Space Administration, the National Oceanic and Atmospheric Administration, and the World Meteorological Organization. Worldwide temperature records date back to 1860. To reconstruct Earth's temperature history before 1860, scientists use limited temperature records, along with proxy indicators such as tree rings, pollen records, and analysis of air frozen in ancient ice. The solar energy received from the sun drives Earth's weather and climate. Some of this energy is reflected and filtered by the atmosphere, but most is absorbed by Earth's surface. The absorbed solar radiation warms the surface and is re-radiated as heat energy into the atmosphere. Some atmospheric gases, called greenhouse gases, trap some of the re-emitted heat, keeping the surface temperature regulated and suitable for sustaining life. Although the greenhouse effect is natural, some evidence indicates that human activities are producing increased levels of some greenhouse gases such as carbon dioxide, methane, and nitrous oxide. Scientists believe that the combustion of fossil fuels is responsible for the increased levels of carbon dioxide in the atmosphere. According to the EPA, the burning of fossil fuels for cars and trucks, the heating of homes and businesses, and the operation of power plants account for approximately 98% of U.S. carbon dioxide emissions. The increase of greenhouse gases will, theoretically, enhance the greenhouse effect by trapping more of the heat energy emitted by Earth's surface, thus increasing the surface temperatures on a global scale. Scientists expect that the global average surface temperature could rise 1-4.5 F in the next 50 years and as much as 10 F in the next century. Global warming could potentially have harmful effects on human health, water resources, forests, agriculture, wildlife, and coastal areas. A few degrees of warming might lead to more frequent and severe heat waves, worsened air pollution with adverse effects on human respiratory health, and wider spread of tropical disease such as malaria. The world's hydrologic cycle might be affected by an increase in evaporation and, thus, in precipitation. An increase in evaporation will increase atmospheric water vapor, a significant natural greenhouse gas. The increase in water vapor might further enhance the global warming caused by the greenhouse effect. This is known as a positive feedback. The increase in water vapor could also change the amount of clouds present in the atmosphere, which could reduce temperatures in a negative feedback. Many interrelated factors affect the global climate and are responsible for climate change. Predicting the outcome of the interactions among the many factors is not easy, but it must be addressed. The ARM Program is taking a lead in this effort by collecting vast amounts of data whose analysis will improve our forecasting models for both daily weather and long-term climate. For more information on the ARM Program, please visit our web site at www.arm.gov.

Holdridge, D. J.

2001-10-10T23:59:59.000Z

69

Composition and Reactions of Atmospheric Aerosol Particles  

NLE Websites -- All DOE Office Websites (Extended Search)

Composition and Reactions of Atmospheric Aerosol Particles Print Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth while changing organic composition by 13 to 24% per day, an oxidation rate significantly slower than is currently used in atmospheric models. Since oxidation has a strong effect on particle lifetime in the atmosphere, these results will help climate scientists refine the computer models used to predict climate change.

70

Composition and Reactions of Atmospheric Aerosol Particles  

NLE Websites -- All DOE Office Websites (Extended Search)

Composition and Reactions of Composition and Reactions of Atmospheric Aerosol Particles Composition and Reactions of Atmospheric Aerosol Particles Print Wednesday, 29 June 2005 00:00 Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth while changing organic composition by 13 to 24% per day, an oxidation rate significantly slower than is currently used in atmospheric models. Since oxidation has a strong effect on particle lifetime in the atmosphere, these results will help climate scientists refine the computer models used to predict climate change.

71

Composition and Reactions of Atmospheric Aerosol Particles  

NLE Websites -- All DOE Office Websites (Extended Search)

Composition and Reactions of Atmospheric Aerosol Particles Print Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth while changing organic composition by 13 to 24% per day, an oxidation rate significantly slower than is currently used in atmospheric models. Since oxidation has a strong effect on particle lifetime in the atmosphere, these results will help climate scientists refine the computer models used to predict climate change.

72

APPENDIX F: EMISSIONS OF NITROUS OXIDE AND METHANE FROM ALTERNATIVE FUELS FOR MOTOR  

E-Print Network (OSTI)

for Improving Efficiency and Versatility of Dye-Sensitized Solar Cells ... PM 307 (Convention Center ) Pisist The operation and efficiency of dye-sensitized solar cells (DSSCs) ... Macromolecular Crowding Effects by Supported Wox/SiO2 Catalysts ... Center ) Israel E. Wachs1, Soe Lwin1, Wu Zhou2, Chris K. Kiely3, Nikolaos

Delucchi, Mark

73

Quantification of and Controls on Dinitrogen and Nitrous Oxide Fluxes from Terrestrial Ecosystems  

E-Print Network (OSTI)

and then 100 g was weighed into each sample jar (490 mL).The jars were sealed on viton gaskets with aluminum lidssepta for gas sampling. The jars were flushed with N 2 for

Yang, Wendy Hui-I

2010-01-01T23:59:59.000Z

74

Table 11.4 Nitrous Oxide Emissions, 1980-2009 (Thousand Metric ...  

U.S. Energy Information Administration (EIA)

States 2009 (March 2011), Table 22; and EIA estimates based on the Intergovernmental Panel on Climate Change's Guidelines for National Greenhouse Gas Inventories ...

75

On-farm Assessment of Nitrogen Fertilizer application to corn on Nitrous Oxide Emissions  

E-Print Network (OSTI)

in soils cropped to corn with varying N fertilization. Can.as affected by tillage, corn-soybean-alfalfa rotations, andsoil nitrogen mineralization for corn production in eastern

2009-01-01T23:59:59.000Z

76

Table 11.4 Nitrous Oxide Emissions, 1980-2009 (Thousand Metric ...  

U.S. Energy Information Administration (EIA)

Short-Term Energy Outlook › Annual Energy Outlook › Energy Disruptions › International Energy Outlook ... 1984: 86: 45: 132: 1: 11: 11: 355: 2: 74: 431: 87: 661:

77

Controlled Atmospheres  

Science Conference Proceedings (OSTI)

...for the removal of oxides, coatings, grease, oil, dirt, or other foreign materials from the parts to be brazed. All parts for brazing must be subjected to

78

Ontario Power Generation's 250 kWe Class Atmospheric Solid Oxide Fuel Cell (SOFC): Combined Heat and Power (CHP) Power Plant  

Science Conference Proceedings (OSTI)

This case study documents the demonstration experiences and lessons learned from a 250 kW solid oxide fuel cell system in a combined heat and power demonstration operating on natural gas. The project was a collaboration initiative between Siemens Westinghouse Power Corporation (SWPC) and Ontario Power Generation (OPG) to install and test a first-of-a-kind SOFC system at OPG site in Toronto, Canada. This test and evaluation case study is one of several distributed generation project case studies under res...

2005-01-26T23:59:59.000Z

79

Highly oxidized superconductors  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

Morris, D.E.

1994-09-20T23:59:59.000Z

80

Highly oxidized superconductors  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed.

Morris, Donald E. (Kensington, CA)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Selective methane oxidation over promoted oxide catalysts. Quarterly report, September 1 - November 30, 1995  

DOE Green Energy (OSTI)

The objective of this research is the selective oxidation of methane to C{sub 2}H{sub 4} hydrocarbons and to oxygenates, in particular formaldehyde and methanol. Air, oxygen, or carbon dioxide rather than nitrous oxide, are utilized as the oxidizing gas at high gas hourly space velocity but mild reaction conditions (500-700{degrees}C, 1 atm total pressure). All the investigated processes are catalytic, aiming at minimizing gas phase reactions that are difficult to control. During this quarter, solid state {sup 51}V NMR and double catalyst bed experiments were conducted to demonstrate the unfavorable effect of the presence of bulk crystalline V{sub 2}O{sub 5} in V{sub 2}O{sub 5}-SiO{sub 2} xerogel catalysts on selective oxidation of methane to methanol and formaldehyde. Results are discussed.

Klier, Kamil; Herman, R.G.; Wang, C.B. [USDOE Morgantown Energy Technology Center, WV (United States)

1995-12-31T23:59:59.000Z

82

Assessing methane oxidation under landfill covers and its contribution to the above atmospheric CO{sub 2} levels: The added value of the isotope ({delta}{sup 13}C and {delta}{sup 18}O CO{sub 2}; {delta}{sup 13}C and {delta}D CH{sub 4}) approach  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Comparison of the isotope and mass balance approaches to evaluate the level of methane oxidation within a landfill. Black-Right-Pointing-Pointer The level of methane oxidation is not homogenous under the landfill cover and is strongly correlated to the methane flux. Black-Right-Pointing-Pointer Isotope tracking of the contribution of the methane oxidation to the CO{sub 2} concentrations in the ambient air. - Abstract: We are presenting here a multi-isotope approach ({delta}{sup 13}C and {delta}{sup 18}O of CO{sub 2}; {delta}{sup 13}C and {delta}D of CH{sub 4}) to assess (i) the level(s) of methane oxidation during waste biodegradation and its migration through a landfill cover in Sonzay (France), and (ii) its contribution to the atmospheric CO{sub 2} levels above the surface. The isotope approach is compared to the more conventional mass balance approach. Results from the two techniques are comparable and show that the CH{sub 4} oxidation under the landfill cover is heterogenous, with low oxidation percentages in samples showing high biogas fluxes, which was expected in clay covers presenting fissures, through which CH{sub 4} is rapidly transported. At shallow depth, more immobile biogas pockets show a higher level of CH{sub 4} oxidation by the methanotrophic bacteria. {delta}{sup 13}C of CO{sub 2} samples taken at different heights (from below the cover up to 8 m above the ground level) were also used to identify and assess the relative contributions of its main sources both under the landfill cover and in the surrounding atmosphere.

Widory, D., E-mail: d.widory@brgm.fr [BRGM, 3 ave Claude Guillemin, 45000 Orleans (France); Proust, E.; Bellenfant, G. [BRGM, 3 ave Claude Guillemin, 45000 Orleans (France); Bour, O. [INERIS, Parc Technologique ALATA, 60550 Verneuil-en-Halatte (France)

2012-09-15T23:59:59.000Z

83

--No Title--  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

The PlasmaPen is being researched as an alternative method of tritium surface decontamination. In the course of generating plasma in the atmosphere, ozone and nitrous oxide are...

84

The Boulder Atmospheric Observatory  

Science Conference Proceedings (OSTI)

The Boulder Atmospheric Observatory (BAO) is a unique research facility for studying the planetary boundary layer and for testing and calibrating atmospheric sensors. The facility includes a 300 m tower instrumented with fast- and slow-response ...

J. C. Kaimal; J. E. Gaynor

1983-05-01T23:59:59.000Z

85

Atmospheric Radiation Measurement Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Observatory (UAO) Pilot Experiment at NYC" - Michael Reynolds, BNL 17:30 "EML Pilot Studies for the Urban Atmospheric Observatory" - Hsi-Na (Sam) Lee, EML 17:40 "A...

86

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation  

E-Print Network (OSTI)

The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

87

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation.  

E-Print Network (OSTI)

??The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test… (more)

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

88

Ultrathin high-temperature oxidation-resistant coatings of hexagonal...  

NLE Websites -- All DOE Office Websites (Extended Search)

coatings for nickel up to 1,100 C in oxidizing atmospheres. Furthermore, graphene layers coated with a few hexagonal boron nitride layers are also protected at...

89

Flame Synthesized Metal Oxide Nanowires as Effective Photoanodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Stanford, CA 94305, USA I will discuss an atmospheric, cost-effective and scalable flame synthesis method for the growth and doping of metal oxide nanowires and these...

90

Atmospheric Radiation Measurement Program  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 ARM 2003 Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement WARNING! WARNING! Today is April 1 But that has NO bearing on this message Today is April 1 But that has NO bearing on this message ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Two Topics Two Topics * Status of ARM (quick overview) * Science plan - ARM in the next 5 years * Status of ARM (quick overview) * Science plan - ARM in the next 5 years ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement ARM Status - Science ARM Status - Science * Steadily increasing productivity - Poster session - over 220 posters (may need to do something about submissions next year) - Peer-reviewed articles: 2.5 to 3 per year per

91

Ranges of Atmospheric Mass and Composition of Super Earth Exoplanets  

E-Print Network (OSTI)

Terrestrial-like exoplanets may obtain atmospheres from three primary sources: Capture of nebular gases, degassing during accretion, and degassing from subsequent tectonic activity. Here we model degassing during accretion to estimate the range of atmospheric mass and composition on exoplanets ranging from 1 to 30 Earth masses. We use bulk compositions drawn from primitive and differentiated meteorite compositions. Degassing alone can create a wide range of masses of planetary atmospheres, ranging from less than a percent of the planet's total mass up to ~6 mass% of hydrogen, ~20 mass% of water, and/or ~5 mass% of carbon compounds. Hydrogen-rich atmospheres can be outgassed as a result of oxidizing metallic iron with water, and excess water and carbon can produce atmospheres through simple degassing. As a byproduct of our atmospheric outgassing models we find that modest initial water contents (10 mass% of the planet and above) create planets with deep surface liquid water oceans soon after accretion is complete.

L. Elkins-Tanton; S. Seager

2008-08-13T23:59:59.000Z

92

Evolution of Organic Aerosols in the Atmosphere.  

SciTech Connect

Organic aerosol (OA) particles affect climate forcing and human health, but their sources and evolution remain poorly characterized. We present a unifying model framework that describes the atmospheric evolution of OA and is constrained and motivated by new, high time resolution, experimental characterizations of their composition, volatility, and oxidation state. OA and OA-precursor gases evolve by becoming increasingly oxidized, less volatile, and more hygroscopic, leading to the formation of large amounts of oxygenated organic aerosol (OOA) mass that has comparable concentrations to sulfate aerosol over the Northern Hemisphere. Our new model framework captures the dynamic aging behavior observed in the atmosphere and the laboratory and can serve as a basis for improving parameterizations in regional and global models.

Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M.; Prevot, A. S. H.; Zhang, Qi; Kroll, Jesse H.; DeCarlo, Peter F.; Allan, James D.; Coe, H.; Ng, N. L.; Aiken, Allison; Docherty, Kenneth S.; Ulbrich, Ingrid M.; Grieshop, A. P.; Robinson, A. L.; Duplissy, J.; Smith, J. D.; Wilson, K. R.; Lanz, V. A.; Hueglin, C.; Sun, Y. L.; Tian, J.; Laaksonen, A.; Raatikainen, T.; Rautiainen, J.; Vaattovaara, P.; Ehn, M.; Kulmala, M.; Tomlinson, Jason M.; Collins, Donald R.; Cubison, Michael J.; Dunlea, E. J.; Huffman, John A.; Onasch, Timothy B.; Alfarra, M. R.; Williams, Paul I.; Bower, K.; Kondo, Yutaka; Schneider, J.; Drewnick, F.; Borrmann, S.; Weimer, S.; Demerjian, K.; Salcedo, D.; Cottrell, L.; Griffin, Robert; Takami, A.; Miyoshi, T.; Hatakeyama, S.; Shimono, A.; Sun, J. Y.; Zhang, Y. M.; Dzepina, K.; Kimmel, Joel; Sueper, D.; Jayne, J. T.; Herndon, Scott C.; Trimborn, Achim; Williams, L. R.; Wood, Ezra C.; Middlebrook, A. M.; Kolb, C. E.; Baltensperger, Urs; Worsnop, Douglas R.

2009-12-11T23:59:59.000Z

93

Adsorption of Atmospheric Gases on Pu Surfaces  

Science Conference Proceedings (OSTI)

Surface adsorption represents a competition between collision and scattering processes that depend on surface energy, surface structure and temperature. The surface reactivity of the actinides can add additional complexity due to radiological dissociation of the gas and electronic structure. Here we elucidate the chemical bonding of gas molecules adsorbed on Pu metal and oxide surfaces. Atmospheric gas reactions were studied at 190 and 300 K using x-ray photoelectron spectroscopy. Evolution of the Pu 4f and O 1s core-level states were studied as a function of gas dose rates to generate a set of Langmuir isotherms. Results show that the initial gas dose forms Pu{sub 2}O{sub 3} on the Pu metal surface followed by the formation of PuO{sub 2} resulting in a layered oxide structure. This work represents the first steps in determining the activation energy for adsorption of various atmospheric gases on Pu.

Nelson, A J; Holliday, K S; Stanford, J A; Grant, W K; Erler, R G; Allen, P G; McLean, W; Roussel, P

2012-03-29T23:59:59.000Z

94

Oxidative Tritium Decontamination System  

DOE Patents (OSTI)

The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

2006-02-07T23:59:59.000Z

95

Selective methane oxidation over promoted oxide catalysts. Quarterly report, March--May 1995  

DOE Green Energy (OSTI)

The objective of this research is the selective oxidative coupling of methane to C{sub 2}H{sub 4} hydrocarbons and oxygenates, in particular formaldehyde and methanol. Air, oxygen or carbon dioxide, rather than nitrous oxide will be utilized as the oxidizing gas at high gas hourly space velocity, but mild reaction conditions (500-700 {degrees}C, 1 atm total pressure). All the investigated processes are catalytic, aiming at minimizing gas phase reactions that are difficult to control. The research is divided into the following three tasks: (1) maximizing selective methane oxidation to C{sub 2}H{sub 4} products over promoted Sr/La{sub 2}O{sub 3}; (2) selective methane oxidation to oxygenates; and (3) catalyst characterization and optimization. Task 1 dealt with the preparation, testing, and optimization of acidic promoted lanthana-based catalysts for the synthesis of C{sub 2}H{sub 4} hydrocarbons and is essentially completed. Task 2 aims at the formation and optimization of promoted catalysts for the synthesis of oxygenates, in particular formaldehyde and methanol. Task 3 involves characterization of the most promising catalysts so that optimization can be achieved under Task 2. Accomplishments for this period are presented.

Klier, K.; Herman, R.G.; Wang, Chaun-Bao; Shi, Chunlei; Sun, Qun

1995-08-01T23:59:59.000Z

96

Simulation of Atmospheric Variability  

Science Conference Proceedings (OSTI)

A spectral atmospheric circulation model is time-integrated for approximately 18 years. The model has a global computational domain and realistic geography and topography. The model undergoes an annual cycle as daily values of seasonally varying ...

Syukuro Manabe; Douglas G. Hahn

1981-11-01T23:59:59.000Z

97

Atmospheric Laser Communication  

Science Conference Proceedings (OSTI)

Atmospheric laser communication, often referred to as free-space optics (FSO) or free-space laser (FSL) communication, is similar to fiber optic cable in terms of carrier wavelength and bandwidth capability, but data are transmitted directly ...

Kenneth W. Fischer*Michael R. Witiw; Jeffrey A. Baars+; T. R. Oke

2004-05-01T23:59:59.000Z

98

Atmospheric Available Energy  

Science Conference Proceedings (OSTI)

The total potential energy of the atmosphere is the sum of its internal and gravitational energies. The portion of this total energy available to be converted into kinetic energy is determined relative to an isothermal, hydrostatic, equilibrium ...

Peter R. Bannon

2012-12-01T23:59:59.000Z

99

Atmospheric optical calibration system  

DOE Patents (OSTI)

An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

1988-01-01T23:59:59.000Z

100

Atmospheric optical calibration system  

DOE Patents (OSTI)

An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

Hulstrom, R.L.; Cannon, T.W.

1988-10-25T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Winter and summer nitrous oxide and nitrogen oxides fluxes from a seasonally snow-covered subalpine meadow at Niwot Ridge, Colorado  

E-Print Network (OSTI)

of Geography, University of Colorado, Boulder, CO, USA M. W.Alpine Research, University of Colorado, Boulder, CO, USA D.Sciences, University of Colorado, Boulder, CO, USA B. Hall

2009-01-01T23:59:59.000Z

102

Destruction of organic wastes with molten oxidizers  

DOE Patents (OSTI)

A process for destruction of biologically hazardous organic chemical wastes by using liquefied strongly oxidizing inorganic salts, such as the alkali metal nitrates, at high temperatures and atmospheric pressure, to yield inorganic salts, carbon dioxide, and water. The oxidizing salts are regenerated and recycled.

Bradshaw, R.W.; Holmes, J.T.; Tyner, C.E.

1990-12-31T23:59:59.000Z

103

Destruction of organic wastes with molten oxidizers  

DOE Patents (OSTI)

A process for destruction of biologically hazardous organic chemical wastes by using liquefied strongly oxidizing inorganic salts, such as the alkali metal nitrates, at high temperatures and atmospheric pressure, to yield inorganic salts, carbon dioxide, and water. The oxidizing salts are regenerated and recycled.

Bradshaw, R.W.; Holmes, J.T.; Tyner, C.E.

1990-01-01T23:59:59.000Z

104

THERMALLY DRIVEN ATMOSPHERIC ESCAPE  

Science Conference Proceedings (OSTI)

Accurately determining the escape rate from a planet's atmosphere is critical for determining its evolution. A large amount of Cassini data is now available for Titan's upper atmosphere and a wealth of data is expected within the next decade on escape from Pluto, Mars, and extra-solar planets. Escape can be driven by upward thermal conduction of energy deposited well below the exobase, as well as by nonthermal processes produced by energy deposited in the exobase region. Recent applications of a model for escape driven by upward thermal conduction, called the slow hydrodynamic escape model, have resulted in surprisingly large loss rates for the atmosphere of Titan, Saturn's largest moon. Based on a molecular kinetic simulation of the exobase region, these rates appear to be orders of magnitude too large. Therefore, the slow hydrodynamic model is evaluated here. It is shown that such a model cannot give a reliable description of the atmospheric temperature profile unless it is coupled to a molecular kinetic description of the exobase region. Therefore, the present escape rates for Titan and Pluto must be re-evaluated using the atmospheric model described here.

Johnson, Robert E., E-mail: rej@virginia.ed [Engineering Physics, Thornton Hall B102, University of Virginia, Charlottesville, VA 22902 (United States); Physics Department, New York University, New York, NY 10003 (United States)

2010-06-20T23:59:59.000Z

105

ARM - Measurement - Atmospheric pressure  

NLE Websites -- All DOE Office Websites (Extended Search)

pressure pressure ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric pressure The pressure exerted by the atmosphere as a consequence of gravitational attraction exerted upon the "column" of air lying directly above the point in question. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments SONDE : Balloon-Borne Sounding System CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

106

ARM - Measurement - Atmospheric temperature  

NLE Websites -- All DOE Office Websites (Extended Search)

temperature temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric temperature The temperature indicated by a thermometer exposed to the air in a place sheltered from direct solar radiation. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments AERI : Atmospheric Emitted Radiance Interferometer SONDE : Balloon-Borne Sounding System CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

107

Article Atmospheric Science  

NLE Websites -- All DOE Office Websites (Extended Search)

© The Author(s) 2012. This article is published with open access at Springerlink.com csb.scichina.com www.springer.com/scp © The Author(s) 2012. This article is published with open access at Springerlink.com csb.scichina.com www.springer.com/scp *Corresponding author (email: luchunsong110@gmail.com) Article Atmospheric Science February 2013 Vol.58 No.4-5: 545  551 doi: 10.1007/s11434-012-5556-6 A method for distinguishing and linking turbulent entrainment mixing and collision-coalescence in stratocumulus clouds LU ChunSong 1,2* , LIU YanGang 2 & NIU ShengJie 1 1 Key Laboratory for Atmospheric Physics and Environment of China Meteorological Administration, Key Laboratory of Meteorological Disaster of Ministry of Education, Nanjing University of Information Science and Technology, Nanjing 210044, China; 2 Atmospheric Sciences Division, Brookhaven National Laboratory, New York 11973, USA

108

ARM - Measurement - Atmospheric moisture  

NLE Websites -- All DOE Office Websites (Extended Search)

moisture moisture ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric moisture The moisture content of the air as indicated by several measurements including relative humidity, specific humidity, dewpoint, vapor pressure, water vapor mixing ratio, and water vapor density; note that precipitable water is a separate type. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments AERI : Atmospheric Emitted Radiance Interferometer

109

BNL | Atmospheric Systems Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric System Research is a DOE observation-based research program Atmospheric System Research is a DOE observation-based research program created to advance process-level understanding of the key interactions among aerosols, clouds, precipitation, radiation, dynamics, and thermodynamics, with the ultimate goal of reducing the uncertainty in global and regional climate simulations and projections. General areas of research at BNL under this program include studies of aerosol and cloud lifecycles, and cloud-aerosol-precipitation interactions. Contact Robert McGraw, 631.344.3086 aerosols Aerosol Life Cycle The strategic focus of the Aerosol Life Cycle research is observation-based process science-examining the properties and evolution of atmospheric aerosols. Observations come from both long-term studies conducted by the

110

Future Changes in Biogenic Isoprene Emissions: How Might They Affect Regional and Global Atmospheric Chemistry?  

Science Conference Proceedings (OSTI)

Isoprene is emitted from vegetation to the atmosphere in significant quantities, and it plays an important role in the reactions that control tropospheric oxidant concentrations. As future climatic and land-cover changes occur, the spatial and ...

Christine Wiedinmyer; Xuexi Tie; Alex Guenther; Ron Neilson; Claire Granier

2006-01-01T23:59:59.000Z

111

Atmospheric Mercury Deposition during the Last 270 Years: A  

E-Print Network (OSTI)

that were placed in an oven at 50 °C overnight to ensure complete oxidation of all mercury species. Analysis requiring pollutant scrubbers that also likely remove a fraction of the Hg in flue gases. If so, the resultsAtmospheric Mercury Deposition during the Last 270 Years: A Glacial Ice Core Record of Natural

112

Precomputed atmospheric scattering  

Science Conference Proceedings (OSTI)

We present a new and accurate method to render the atmosphere in real time from any viewpoint from ground level to outer space, while taking Rayleigh and Mie multiple scattering into account. Our method reproduces many effects of the scattering of light, ...

Eric Bruneton; Fabrice Neyret

2008-06-01T23:59:59.000Z

113

ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement  

NLE Websites -- All DOE Office Websites (Extended Search)

An Integrated Column Description An Integrated Column Description of the Atmosphere An Integrated Column Description of the Atmosphere Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Pacific Northwest National Laboratory Pacific Northwest National Laboratory The "other" Washington ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Credits to Credits to * Ric Cederwall * Xiquan Dong * Chuck Long * Jay Mace * Mark Miller * Robin Perez * Dave Turner and the rest of the ARM science team * Ric Cederwall * Xiquan Dong * Chuck Long * Jay Mace * Mark Miller * Robin Perez * Dave Turner and the rest of the ARM science team ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Outline Outline * A little philosophy

114

Hydrostatic Adjustment in Nonisothermal Atmospheres  

Science Conference Proceedings (OSTI)

The author examines hydrostatic adjustment due to heating in two nonisothermal atmospheres. In the first case both the temperature and lapse rate decrease with height; in the second case the atmosphere consists of a troposphere with constant ...

Dean G. Duffy

2003-01-01T23:59:59.000Z

115

Efficient rendering of atmospheric phenomena  

Science Conference Proceedings (OSTI)

Rendering of atmospheric bodies involves modeling the complex interaction of light throughout the highly scattering medium of water and air particles. Scattering by these particles creates many well-known atmospheric optical phenomena including rainbows, ...

Kirk Riley; David S. Ebert; Martin Kraus; Jerry Tessendorf; Charles Hansen

2004-06-01T23:59:59.000Z

116

ARM - Measurement - Atmospheric turbulence  

NLE Websites -- All DOE Office Websites (Extended Search)

turbulence turbulence ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric turbulence High frequency velocity fluctuations that lead to turbulent transport of momentum, heat, mositure, and passive scalars, and often expressed in terms of variances and covariances. Categories Atmospheric State, Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

117

Differential atmospheric tritium sampler  

DOE Patents (OSTI)

An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The mixture then passes through a combustion chamber where hydrogen gas in the form of H.sub.2 or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

Griesbach, Otto A. (Langhorne, PA); Stencel, Joseph R. (Skillman, NJ)

1990-01-01T23:59:59.000Z

118

Atmospheric Release Advisory Capability  

SciTech Connect

The Atmospheric Release Advisory Capability (ARAC) project is a Department of Energy (DOE) sponsored real-time emergency response service available for use by both federal and state agencies in case of a potential or actual atmospheric release of nuclear material. The project, initiated in 1972, is currently evolving from the research and development phase to full operation. Plans are underway to expand the existing capability to continuous operation by 1984 and to establish a National ARAC Center (NARAC) by 1988. This report describes the ARAC system, its utilization during the past two years, and plans for its expansion during the next five to six years. An integral part of this expansion is due to a very important and crucial effort sponsored by the Defense Nuclear Agency to extend the ARAC service to approximately 45 Department of Defense (DOD) sites throughout the continental US over the next three years.

Dickerson, M.H.; Gudiksen, P.H.; Sullivan, T.J.

1983-02-01T23:59:59.000Z

119

Atmospheric Mercury Research Update  

Science Conference Proceedings (OSTI)

This report is a summary and analysis of research findings on utility and environmental mercury from 1997 to 2003. The update categorizes and describes recent work on mercury in utility-burned coal and its route through power plants, the measures for its control, and its fate in the environment following emissions from utility stacks. This fate includes atmospheric chemistry and transport, deposition to land and water surfaces, aquatic cycling, the dynamics of mercury in freshwater fish food webs, and th...

2004-03-30T23:59:59.000Z

120

Program on Technology Innovation: Coastal Halogen Atmospheric Research on Mercury Deposition (CHARMeD)  

Science Conference Proceedings (OSTI)

Determining mercury’s atmospheric transformation reactions is essential for atmospheric deposition models that are used for regulatory purposes. It is the oxidation of inorganic elemental Hg (Hg0) to its water-soluble ionic form (Hg2+) that determines the rate of Hg deposited in waterways. Substantial research has been done in the past on atmospheric Hg transformation reactions with ozone (O3) and the hydroxyl radical (OH), but O3 and OH may not be capable of fully causing mercury’s observed oxidation an...

2009-08-11T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Increased Cytotoxicity of Oxidized Flame Soot  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

122

ORISE: Climate and Atmospheric Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Climate and Atmospheric Research Climate and Atmospheric Research Capabilities Overview U.S. Climate Reference Network U.S. Historical Climate Network Contact Us Oak Ridge Institute for Science Education Climate and Atmospheric Research The Oak Ridge Institute for Science and Education (ORISE) partners with the National Oceanic and Atmospheric Administration's Atmospheric Turbulence and Diffusion Division (ATDD) to conduct climate research focused on issues of national and global importance. Research is performed with personnel support from ORISE's Independent Environmental Assessment and Verification (IEAV) programs, as well as in collaboration with scientists and engineers from Oak Ridge National Laboratory (ORNL), and numerous other organizations, government agencies, universities and private research institutions.

123

Atmospheric attenuation of solar radiation  

DOE Green Energy (OSTI)

The attenuation of solar radiation by the atmosphere between the heliostat and receiver of a Central Receiver solar energy system has been computed for a number of atmospheric conditions and tower-heliostat distances. The most important atmospheric variable is found to be the atmospheric aerosol content. No dependence of atmospheric water vapor is found and only a weak dependence on solar zenith angle. For a 500 m heliostat-tower distance two to four percent reductions are expected under typical desert conditions (50 to 120 km visibility). The reduction is approximately linear with heliostat-tower distance. A representative value of the attenuation coefficient is 0.051 km/sup -1/.

Randall, C.M.

1977-05-18T23:59:59.000Z

124

DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES  

Science Conference Proceedings (OSTI)

This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

Kyser, E

2009-01-12T23:59:59.000Z

125

PNNL: FCSD: Atmospheric Sciences & Global Change: Programs &...  

NLE Websites -- All DOE Office Websites (Extended Search)

Programs & Facilities Atmospheric Measurements Laboratory Atmospheric Radiation Measurement (ARM) Program and ARM Climate Research Facility ARM Aerial Facility Environmental...

126

Why Sequence a Methane-Oxidizing Archaean?  

NLE Websites -- All DOE Office Websites (Extended Search)

a Methane-Oxidizing Archaeon? a Methane-Oxidizing Archaeon? Methane is a potent greenhouse gas whose atmospheric concentration has increased significantly because of anthropogenic activities and fluctuated naturally over glacial and interglacial cycles. While the importance of methane in Earth's climate dynamics has been well established, the global processes regulating its oceanic cycling remain poorly understood. Although there are high rates of methane production in many marine sedimentary environments (including a number that have been targeted as petroleum reserves), net methane sources from the ocean to the atmosphere appear to be small. This is due in large part to a biogeochemical process known as the anaerobic oxidation of methane (AOM). Microbially mediated AOM reduces methane flux from ocean to atmosphere, stimulates subsurface microbial

127

Evolution of Nitrogen Oxide Chemistry in the Nocturnal Boundary Layer  

Science Conference Proceedings (OSTI)

The nocturnal cycle of nitrogen oxides in the atmospheric boundary layer is studied by means of a one-dimensional model. The model solves the conservation equations of momentum, entropy, total water content, and of five chemical species. The ...

S. Galmarini; P. G. Duynkerke; J. Vilà-Guerau de Arellano

1997-07-01T23:59:59.000Z

128

OH-Initiated Heterogeneous Aging of Highly Oxidized Organic Aerosol  

E-Print Network (OSTI)

The oxidative evolution (“aging”) of organic species in the atmosphere is thought to have a major influence on the composition and properties of organic particulate matter but remains poorly understood, particularly for ...

Kessler, Sean Herbert

129

Multifunctional Oxides  

Science Conference Proceedings (OSTI)

3) Electric, ferroelectric, magnetic and photonic properties of oxides 4) Theoretical modeling of epitaxial growth, interfaces and microstructures 5) Composition ...

130

www.defra.gov.uk SMALL BUSINESS USER GUIDE  

E-Print Network (OSTI)

is caused by the release of greenhouse gases into the atmosphere. What are greenhouse gas emissions? The key greenhouse gas emissions are carbon dioxide, methane and nitrous oxide hydrofluorocarbons, perfluorocarbons gas emissions? Human activities release greenhouse gas emissions into the atmosphere ­ using

131

EMSL: Science: Atmospheric Aerosol Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Aerosol Systems Atmospheric Aerosol Systems atmospheric logo Nighttime enhancement of nitrogen-containing organic compounds, or NOC Observed nighttime enhancement of nitrogen-containing organic compounds, or NOC, showed evidence of being formed by reactions that transform carbonyls into imines. The Atmospheric Aerosol Systems Science Theme focuses on understanding the chemistry, physics and molecular-scale dynamics of aerosols for model parameterization to improve the accuracy of climate model simulations and develop a predictive understanding of climate. By elucidating the role of natural and anthropogenic regional and global climate forcing mechanisms, EMSL can provide DOE and others with the ability to develop cost-effective strategies to monitor, control and mitigate them.

132

ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC  

E-Print Network (OSTI)

ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC RESEARCH On the parameterization of ice and water substance mixing ratio fields were only strongly altered by turning off the ice phase of these schemes includes ice processes. But in mid- latitudes and also in tropics the ice phase is an important

Moelders, Nicole

133

Atmospheric Chemistry and Physics  

E-Print Network (OSTI)

Abstract. A 3-D chemistry-transport model has been applied to the Mexico City metropolitan area to investigate the origin of elevated levels of non-fossil (NF) carbonaceous aerosols observed in this highly urbanized region. High time resolution measurements of the fine aerosol concentration and composition, and 12 or 24 h integrated 14 C measurements of aerosol modern carbon have been performed in and near Mexico City during the March 2006 MILAGRO field experiment. The non-fossil carbon fraction (fNF), which is lower than the measured modern fraction (fM) due to the elevated 14 C in the atmosphere caused by nuclear bomb testing, is estimated from the measured fM and the source-dependent information on modern carbon enrichment. The fNF contained in PM1 total carbon analyzed by a US team (f TC

unknown authors

2010-01-01T23:59:59.000Z

134

Atmospheric Corrosion Test Sites  

Science Conference Proceedings (OSTI)

Table 27   Some marine-atmospheric corrosion test sites around the world...Zealand Phia Marine 0.2 0.12 15.8 2.4 � � � � Greece Rafina Marine 0.2 0.12 13.6 1.0 � � � � Rhodes Marine 0.2 0.12 14.3 1.5 � � � � Netherlands Schagen Marine 2.4 1.5 17.0 2.0 � � � � Spain Almeria � 0.035 0.022 22.4 1.6 � � � � Cartagena � 0.050 0.031 5.2 1.9 � � � � La Coruña � 0.160 0.1 26.2 1.4...

135

Simultaneous removal of nitrogen oxides and sulfur oxides from combustion gases  

DOE Patents (OSTI)

A process for the simultaneous removal of sulfur oxides and nitrogen oxides from power plant stack gases comprising contacting the stack gases with a supported iron oxide catalyst/absorbent in the presence of sufficient reducing agent selected from the group consisting of carbon monoxide, hydrogen, and mixtures thereof, to provide a net reducing atmosphere in the SO.sub.x /NO.sub.x removal zone. The sulfur oxides are removed by absorption substantially as iron sulfide, and nitrogen oxides are removed by catalytic reduction to nitrogen and ammonia. The spent iron oxide catalyst/absorbent is regenerated by oxidation and is recycled to the contacting zone. Sulfur dioxide is also produced during regeneration and can be utilized in the production of sulfuric acid and/or sulfur.

Clay, David T. (Longview, WA); Lynn, Scott (Walnut Creek, CA)

1976-10-19T23:59:59.000Z

136

OH-initiated heterogeneous aging of highly oxidized organic aerosol  

Science Conference Proceedings (OSTI)

The oxidative evolution (“aging”) of organic species in the atmosphere is thought to have a major influence on the composition and properties of organic particulate matter, but remains poorly understood, particularly for the most oxidized fraction of the aerosol. Here we measure the kinetics and products of the heterogeneous oxidation of highly oxidized organic aerosol, with an aim of better constraining such atmospheric aging processes. Submicron particles composed of model oxidized organics—1,2,3,4-butanetetracarboxylic acid (C{sub 8}H{sub 10}O{sub 8}), citric acid (C{sub 6}H{sub 8}O{sub 7}), tartaric acid (C{sub 4}H{sub 6}O{sub 6}), and Suwannee River fulvic acid—were oxidized by gas-phase OH in a flow reactor, and the masses and elemental composition of the particles were monitored as a function of OH exposure. In contrast to our previous studies of less-oxidized model systems (squalane, erythritol, and levoglucosan), particle mass did not decrease significantly with heterogeneous oxidation. Carbon content of the aerosol always decreased somewhat, but this mass loss was approximately balanced by an increase in oxygen content. The estimated reactive uptake coefficients of the reactions range from 0.37 to 0.51 and indicate that such transformations occur at rates corresponding to 1-2 weeks in the atmosphere, suggesting their importance in the atmospheric lifecycle of organic particulate matter.

Kessler, Sean H.; Nah, Theodora; Daumit, Kelly E.; Smith, Jared D.; Leone, Stephen R.; Kolb, Charles E.; Worsnop, Douglas R.; Wilson, Kevin R.; Kroll, Jesse H.

2011-12-05T23:59:59.000Z

137

Atmospheric Radiation Measurement (ARM) Climate Research Facility and Atmospheric  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Radiation Measurement (ARM) Atmospheric Radiation Measurement (ARM) Climate Research Facility and Atmospheric System Research (ASR) Science and Infrastructure Steering Committee CHARTER June 2012 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not

138

Graphite Oxidation Thermodynamics/Reactions  

Science Conference Proceedings (OSTI)

The vulnerability of graphite-matrix spent nuclear fuel to oxidation by the ambient atmosphere if the fuel canister is breached was evaluated. Thermochemical and kinetic data over the anticipated range of storage temperatures (200 to 400 C) were used to calculate the times required for a total carbon mass loss of 1 mgcm-2 from a fuel specimen. At 200 C, the time required to produce even this small loss is large, 900,000 yr. However, at 400 C the time required is only 1.9 yr. The rate of oxidation at 200 C is negligible, and the rate even at 400 C is so small as to be of no practical consequence. Therefore, oxidation of the spent nuclear fuel upon a loss of canister integrity is not anticipated to be a concern based upon the results of this study.

Propp, W.A.

1998-09-01T23:59:59.000Z

139

Mountain Forces and the Atmospheric Energy Budget  

Science Conference Proceedings (OSTI)

Although mountains are generally thought to exert forces on the atmosphere, the related transfers of energy between earth and atmosphere are not represented in standard energy equations of the atmosphere. It is shown that the axial rotation of the ...

Joseph Egger

2011-11-01T23:59:59.000Z

140

Baiu rainband termination in atmospheric and atmosphere-ocean models  

Science Conference Proceedings (OSTI)

Baiu rainband is a summer rainband stretching from eastern China through Japan towards the Northwest Pacific. The climatological termination of the Baiu rainband is investigated using Japanese 25-year ReAnalysis (JRA25), a stand-alone atmospheric ...

Akira Kuwano-Yoshida; Bunmei Taguchi; Shang-Ping Xie

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain  

E-Print Network (OSTI)

This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

Xu, Xin, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

142

Oxidation pretreatment to reduce corrosion of 20%Cr-25%Ni-Nb stainless steel. II. Surface morphology and oxide characterization  

SciTech Connect

Improved corrosion behavior of 20%Cr-25%Ni-Nb steel resulting from a low pressure oxidation pretreatment in CO/sub 2/ has been related to changes in elemental composition and distribution in the oxide scale. Auger electron spectroscopy, secondary ion mass spectroscopy, electron microprobe, and X-ray diffraction techniques have been used to investigate the properties of the oxide scale formed on both untreated and pretreated specimens when oxidized at 823 K and 923 K in a CO/sub 2/-1%CO atmosphere. A sputter ion plating technique has been used to separate the oxide from the metal and the incorporation of chromium and silicon at the metal-oxide interface has been investigated at grain centers and grain boundaries by depth profiling. The improvement in oxide adhesion and oxidation rates, using data from Parts I and II of this study, is assessed in terms of oxide formation by solid-state displacement reactions.

Tempest, P.A.; Wild, R.K.

1988-10-01T23:59:59.000Z

143

Krypton-85 in the atmosphere  

E-Print Network (OSTI)

Measurement results are presented on 85Kr content in the atmosphere over the European part of Russia in 1971-1995 based on the analysis of the commercial krypton, which is separated from air by industrial plants. Our results are by 15 per cent lower then 85Kr activites observed over West Europe. According our prediction by 2030 85Kr content in the atmosphere over Europe will amount to 1,5-3 Bq in m3 air. Average 85Kr release to the atmosphere from regeneration of spent nuclear fuel (SNF) is estimated, some 180 TBq per a ton SNF. It is advisable to recommence monitoring of 85Kr content within Russia.

A. T. Korsakov; E. G. Tertyshnik

2013-07-09T23:59:59.000Z

144

Krypton-85 in the atmosphere  

E-Print Network (OSTI)

Measurement results are presented on 85Kr content in the atmosphere over the European part of Russia in 1971-1995 based on the analysis of the commercial krypton, which is separated from air by industrial plants. Our results are by 15 per cent lower then 85Kr activites observed over West Europe. According our prediction by 2030 85Kr content in the atmosphere over Europe will amount to 1,5-3 Bq in m3 air. Average 85Kr release to the atmosphere from regeneration of spent nuclear fuel (SNF) is estimated, some 180 TBq per a ton SNF. It is advisable to recommence monitoring of 85Kr content within Russia.

Korsakov, A T

2013-01-01T23:59:59.000Z

145

Glossary Term - Composition of the Earth's Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

the Earth's Atmosphere Source: Definition of the U.S. Standard Atmosphere (1976) CRC Handbook of Chemistry and Physics, 77th Edition Gas Formula Abundance percent by volume...

146

A Computational Thermodynamic Analysis of Atmospheric ...  

Science Conference Proceedings (OSTI)

Feb 1, 2001 ... The vacuum atmosphere is typically 0.1 atm. However, the vacuum atmosphere creates two major problems: air leakage and batch operation to ...

147

The Workshop in Atmospheric Predictability  

Science Conference Proceedings (OSTI)

A workshop on the subject of atmospheric predictability was held during 23-25 April 2001 at the Naval Postgraduate School in Monterey, California. Of primary concern was the nature of forecast uncertainty due to initial conditionuncertainty of ...

Ronald M. Errico; Rolf Langland; David P. Baumhefner

2002-09-01T23:59:59.000Z

148

(Chemistry of the global atmosphere)  

SciTech Connect

The traveler attended the conference The Chemistry of the Global Atmosphere,'' and presented a paper on the anthropogenic emission of carbon dioxide (CO{sub 2}) to the atmosphere. The conference included meetings of the International Global Atmospheric Chemistry (IGAC) programme, a core project of the International Geosphere/Biosphere Programme (IGBP) and the traveler participated in meetings on the IGAC project Development of Global Emissions Inventories'' and agreed to coordinate the working group on CO{sub 2}. Papers presented at the conference focused on the latest developments in analytical methods, modeling and understanding of atmospheric CO{sub 2}, CO, CH{sub 4}, N{sub 2}O, SO{sub 2}, NO{sub x}, NMHCs, CFCs, and aerosols.

Marland, G.

1990-09-27T23:59:59.000Z

149

Precursors to atmospheric blocking events  

E-Print Network (OSTI)

Atmospheric blocking events disturb synoptic-scale features from their normal eastward progression, causing anomalous weather conditions for the duration of the blocking event. The essence of blocking can be captured by ...

Marino, Garrett P

2009-01-01T23:59:59.000Z

150

Automated Measurements of Atmospheric Visibility  

Science Conference Proceedings (OSTI)

The concept of using a solid-state, linear-array imaging device coupled with computerized scene analysis and display to measure daytime atmospheric visibility is described. Computer software is implemented for routine conversion of observed ...

W. Viezee; W. E. Evans

1983-08-01T23:59:59.000Z

151

The Navy's Operational Atmospheric Analysis  

Science Conference Proceedings (OSTI)

In January of 1988, significant upgrades were made to the Navy Operational Global Atmospheric Prediction System (NOGAPS). Among these improvements was the implementation of a multivariate optimum interpolation analysis scheme. Since that time, ...

James S. Goerss; Patricia A. Phoebus

1992-06-01T23:59:59.000Z

152

Stochastic Simulation of Atmospheric Trajectories  

Science Conference Proceedings (OSTI)

Methods are presented for generating an ensemble of synthetic atmospheric trajectories. These include methods for a set of independent trajectories, and methods for a correlated set of sequential trajectories. The models incorporate first-order ...

Mitchell J. Small; Perry J. Samson

1983-02-01T23:59:59.000Z

153

Atmospheric Water Vapor over China  

Science Conference Proceedings (OSTI)

Chinese radiosonde data from 1970 to 1990 are relatively homogeneous in time and are used to examine the climatology, trends, and variability of China’s atmospheric water vapor content. The climatological distribution of precipitable water (PW) ...

Panmao Zhai; Robert E. Eskridge

1997-10-01T23:59:59.000Z

154

Recuperated atmosphere SOFC/gas turbine hybrid cycle  

Science Conference Proceedings (OSTI)

A method of operating an atmospheric-pressure solid oxide fuel cell generator (6) in combination with a gas turbine comprising a compressor (1) and expander (2) where an inlet oxidant (20) is passed through the compressor (1) and exits as a first stream (60) and a second stream (62) the first stream passing through a flow control valve (56) to control flow and then through a heat exchanger (54) followed by mixing with the second stream (62) where the mixed streams are passed through a combustor (8) and expander (2) and the first heat exchanger for temperature control before entry into the solid oxide fuel cell generator (6), which generator (6) is also supplied with fuel (40).

Lundberg, Wayne (Pittsburgh, PA)

2010-08-24T23:59:59.000Z

155

THE NITROGEN OXIDES CONTROVERSY  

E-Print Network (OSTI)

2 ) by far ultraviolet solar radiation (hv) 02 + hv (A solar radiation above the atmosphere.by Chapman concerning solar radiation above the atmosphere

Johnston, Harold S.

2012-01-01T23:59:59.000Z

156

CDIAC Atmospheric Moisture Data Sets  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Moisture Atmospheric Moisture CDIAC Climate Holdings Containing Atmospheric Moisture Data Global Data Sets Data Set Name Investigators Data Type/Format Period of Record Extended Edited Synoptic Cloud Reports from Ships and Land Stations Over the Globe, 1952-2009 (CDIAC NDP-026C) C.J. Hahn, S.G. Warren, and R. Eastman Six-hourly synoptic observations of dew point depression (combined with air temperature) Land 1971-2009; Ocean 1952-2008 Regional Data Sets Data Set Name Investigators Data Type/Format Period of Record Six- and Three-Hourly Meteorological Observations from 223 Former U.S.S.R. Stations (CDIAC NDP-048) V. Razuvaev et al. Surface stations; 6- and 3-hourly observations of relative humidity, vapor pressure, humidity deficit, and dew point temperature Varies by station; through 2000

157

atmospheric pressure | OpenEI  

Open Energy Info (EERE)

pressure pressure Dataset Summary Description (Abstract):Atmospheric Pressure (kPa)NASA Surface meteorology and Solar Energy (SSE) Release 6.0 Data Set (Nov 2007)22-year Monthly & Annual Average (July 1983 - June 2005)Parameter: Atmospheric Pressure (kPa)Internet: http://eosweb.larc.nasa.gov/sse/Note 1: SSE Methodology & Accuracy sections onlineNote 2: Lat/Lon values indicate the lower left corner of a 1x1 degree region. Negative values are south and west; positive values are north and east. Boundaries of the -90/-180 region Source U.S. National Aeronautics and Space Administration (NASA), Surface meteorology and Solar Energy (SSE) Date Released March 31st, 2009 (5 years ago) Date Updated Unknown Keywords atmospheric pressure climate NASA SWERA UNEP Data text/csv icon Download Data (csv, 46 MiB)

158

CDIAC Atmospheric Pressure Data Sets  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Pressure Atmospheric Pressure CDIAC Climate Holdings Containing Atmospheric Pressure Data Global Data Sets Data Set Name Investigators Data Type/Format Period of Record Global Historical Climatology Network (GHCN); Vs. 1 (CDIAC NDP-041) R.S. Vose et al. Surface stations; monthly mean sea-level pressure Varies by station; through 1990 Extended Edited Synoptic Cloud Reports from Ships and Land Stations Over the Globe, 1952-2009 (CDIAC NDP-026C) C.J. Hahn, S.G. Warren, and R. Eastman Six-hourly synoptic observations of sea-level pressure Land 1971-2009; Ocean 1952-2008 Global Historical Climatology Network (GHCN); Vs. 2 (Note: the above link takes you to NOAA's National Climatic Data Center website.) R.S. Vose et al. Surface stations; monthly mean sea-level pressure Varies by station; some through most recent month

159

National Atmospheric Release Advisory Center  

NLE Websites -- All DOE Office Websites (Extended Search)

NARAC TOC NARAC TOC The National Atmospheric Release Advisory Center, NARAC, provides tools and services to the Federal Government, that map the probable spread of hazardous material accidentally or intentionally released into the atmosphere. NARAC provides atmospheric plume predictions in time for an emergency manager to decide if taking protective action is necessary to protect the health and safety of people in affected areas. Located at the Lawrence Livermore National Laboratory, NARAC is a national support and resource center for planning, real-time assessment, emergency response, and detailed studies of incidents involving a wide variety of hazards, including nuclear, radiological, chemical, biological, and natural emissions. In an emergency situation (if lives are at risk), event-specific NARAC

160

Oxidation catalyst  

DOE Patents (OSTI)

The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

2010-11-09T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Trace gases could double climate warming  

SciTech Connect

The atmospheric concentrations of several trace gases capable of changing the climate are increasing. Researchers are concerned about the trace gases despite their miniscule concentrations because they are such efficient absorbers of far-infrared radiation. The trace gases that concern climatologists are methane, nitrous oxide, and the chlorofluorocarbons or CFC's. The increase in atmospheric concentrations of these gases are discussed and atmospheric models predicting their greenhouse effect are described.

Kerr, R.A.

1983-06-24T23:59:59.000Z

162

METAL SPRAYER FOR USE IN VACUUM OR INERT ATMOSPHERE  

DOE Patents (OSTI)

A metal sprayer is described for use in a vacuum or inert atmosphere with a straight line wire feed and variable electrode contact angle. This apparatus comprises two wires which are fed through straight tubes of two mechanisms positioned on opposite sides of a central tube to which an inert gas is fed. The two mechanisms and the wires being fed constitute electrodes to which electrical current is supplied so that the wires are melted by the electric are formed at their contacting region and sprayed by the gas supplied by the central tube. This apparatus is designed specifically to apply a zirconium coating to uranium in an inert atmosphere and without the use of an oxidizing flame.

Monroe, R.E.

1958-10-14T23:59:59.000Z

163

A Fast Line-by-Line Method for Atmospheric Absorption Computations: The Automatized Atmospheric Absorption Atlas  

Science Conference Proceedings (OSTI)

A computationally fast line-by-line method for the determination of atmospheric absorption is described. This method is based on the creation of an Automatized Atmospheric Absorption Atlas (4A) covering all possible plausible atmospheric ...

N. A. Scott; A. Chedin

1981-07-01T23:59:59.000Z

164

Embracing Complexity: Deciphering Origins and Transformations of Atmospheric Organics through Speciated Measurements  

E-Print Network (OSTI)

oxidation processes. Organic compounds are emitted to the atmosphere from a variety of natural and man temporal resolution are necessary to adequately observe variations in chemical composition caused analytical tools. Current gas and particle-phase instrumentation has focused on measuring organic compounds

Silver, Whendee

165

Quality Assurance in Atmospheric Modeling  

Science Conference Proceedings (OSTI)

This paper summarizes a number of best practices associated with the use of numerical models of the atmosphere and is motivated by the rapid growth in the number of model users, who have a range of scientific and technical preparations. An underlying ...

Thomas T. Warner

2011-12-01T23:59:59.000Z

166

Geomagnetic Effects on Atmospheric Neutrinos  

E-Print Network (OSTI)

Geomagnetic effects distort the zenith angle distribution of sub--GeV and few--GeV atmospheric neutrinos, breaking the up--down symmetry that would be present in the absence of neutrino oscillations and without a geomagnetic field. The geomagnetic effects also produce a characteristic azimuthal dependence of the $\

Paolo Lipari; T. K. Gaisser; Todor Stanev

1998-03-09T23:59:59.000Z

167

High-energy atmospheric neutrinos  

E-Print Network (OSTI)

High-energy neutrinos, arising from decays of mesons that were produced through the cosmic rays collisions with air nuclei, form unavoidable background noise in the astrophysical neutrino detection problem. The atmospheric neutrino flux above 1 PeV should be supposedly dominated by the contribution of charmed particle decays. These (prompt) neutrinos originated from decays of massive and shortlived particles, $D^\\pm$, $D^0$, $\\bar{D}{}^0$, $D_s^\\pm$, $\\Lambda^+_c$, form the most uncertain fraction of the high-energy atmospheric neutrino flux because of poor explored processes of the charm production. Besides, an ambiguity in high-energy behavior of pion and especially kaon production cross sections for nucleon-nucleus collisions may affect essentially the calculated neutrino flux. There is the energy region where above flux uncertainties superimpose. A new calculation presented here reveals sizable differences, up to the factor of 1.8 above 1 TeV, in muon neutrino flux predictions obtained with usage of known hadronic models, SIBYLL 2.1 and QGSJET-II. The atmospheric neutrino flux in the energy range $10-10^7$ GeV was computed within the 1D approach to solve nuclear cascade equations in the atmosphere, which takes into account non-scaling behavior of the inclusive cross-sections for the particle production, the rise of total inelastic hadron-nucleus cross-sections and nonpower-law character of the primary cosmic ray spectrum. This approach was recently tested in the atmospheric muon flux calculations [1]. The results of the neutrino flux calculations are compared with the Frejus, AMANDA-II and IceCube measurement data.

S. I. Sinegovsky; A. A. Kochanov; T. S. Sinegovskaya

2010-10-12T23:59:59.000Z

168

THE FACILITY 350 HELIUM-ATMOSPHERE SYSTEM. Final Report, Metallurgy Division Program 1.5.5  

SciTech Connect

The He atmosphere system in Argonne's Facility 350 is described in detail. The system is straightforward, employing drying and carbon towers for the removal of moisture, oxygen, and other impurities. The bulk of the 15,000 ft/ sup 3/ of He atmosphere is continuously recirculated at nearly atmospheric pressure. Purification is accomplished at 140 psig on a portion of the gas that is passed through the drying tower at room temperature and the carbon towers at -- 46 deg C (--50 deg F). The operation is continuous, requiring a minimum of maintenance and operational manpower. The He atmosphere is supplied to the glove- boxes with impurity levels below 3,000 ppm nitrogen, 1,000 ppm oxygen, and 50 ppm moisture. Such purity levels prevent oxidation and combustion of the Pu materials being processed. Experimental data concerning the adsorption of oxygen from He by activated carbon over a range of temperature and pressure conditions are reported. (auth)

Mayfield, R.M.; Tope, W.G.; Shuck, A.B.

1962-12-01T23:59:59.000Z

169

Method of producing highly oxidized superconductors containing barium, copper, and a third metal  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed.

Morris, Donald E. (Kensington, CA)

1996-01-01T23:59:59.000Z

170

Method of producing highly oxidized superconductors containing barium, copper, and a third metal  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

Morris, D.E.

1996-02-20T23:59:59.000Z

171

Generation of Turbulence by Atmospheric Gravity Waves  

Science Conference Proceedings (OSTI)

The standard current criterion for the generation of turbulence by atmospheric gravity waves and for the associated limitation on wave growth is based upon the standard criterion for static instability of the unperturbed atmosphere, namely, that ...

Colin O. Hines

1988-04-01T23:59:59.000Z

172

AMIP: The Atmospheric Model Intercomparison Project  

Science Conference Proceedings (OSTI)

The Atmospheric Model Intercomparison Project (AMIP) is an international effort to determine the systematic climate errors of atmospheric models under realistic conditions, and calls for the simulation of the climate of the decade 1979–1988 using ...

W. Lawrence Gates

1992-12-01T23:59:59.000Z

173

Retrieval of atmospheric properties of extrasolar planets  

E-Print Network (OSTI)

We present a new method to retrieve molecular abundances and temperature profiles from exoplanet atmosphere photometry and spectroscopy. Our method allows us to run millions of 1-D atmosphere models in order to cover the ...

Nikku, Madhusudhan, 1980-

2009-01-01T23:59:59.000Z

174

Interannual Variation of Global Atmospheric Angular Momentum  

Science Conference Proceedings (OSTI)

The relative atmospheric angular momentum (RAM) integrated over the globe is an explicit variable representing the state of the atmospheric general circulation. After removing the annual, semiannual, and higher-frequency components, the filtered ...

Tsing-Chang Chen; Joseph J. Tribbia; Ming-Cheng Yen

1996-10-01T23:59:59.000Z

175

Statistics Education in the Atmospheric Sciences  

Science Conference Proceedings (OSTI)

Analyses of atmospheric sciences data and models are heavily dependent upon statistical and probabilistic reasoning. Statistical methods have played an important role in establishing physical relationships of atmosphere-ocean-land interactions ...

Timothy J. Brown; L. Mark Berliner; Daniel S. Wilks; Michael B. Richman; Christopher K. Wilke

1999-10-01T23:59:59.000Z

176

Atmospheric Control on the Thermohaline Circulation  

Science Conference Proceedings (OSTI)

In an attempt to elucidate the role of atmospheric and oceanic processes in setting a vigorous ocean overturning circulation in the North Atlantic but not in the North Pacific, a comparison of the observed atmospheric circulation and net surface ...

Arnaud Czaja

2009-01-01T23:59:59.000Z

177

The Promise of GPS in Atmospheric Monitoring  

Science Conference Proceedings (OSTI)

This paper provides an overview of applications of the Global Positioning System (GPS) for active measurement of the Earth's atmosphere. Microwave radio signals transmitted by GPS satellites are delayed (refracted) by the atmosphere as they ...

Steven Businger; Steven R. Chiswell; Michael Bevis; Jingping Duan; Richard A. Anthes; Christian Rocken; Randolph H. Ware; Michael Exner; T. VanHove; Fredrick S. Solheim

1996-01-01T23:59:59.000Z

178

Testing and Evaluating Atmospheric Climate Models  

Science Conference Proceedings (OSTI)

Model validation is a crucial process that underpins model development and gives confidence to the results from running models. This article discusses a range of techniques for validating atmosphere models given that the atmosphere is chaotic and incompletely ...

Vicky Pope; Terry Davies

2002-09-01T23:59:59.000Z

179

Sulfuryl fluoride in the global atmosphere  

E-Print Network (OSTI)

The first calibrated high-frequency, high-precision, in situ atmospheric and archived air measurements of the fumigant sulfuryl fluoride (SO[subscript 2]F[subscript 2]) have been made as part of the Advanced Global Atmospheric ...

Muhle, J.

180

Dynamical Processes of Equatorial Atmospheric Angular Momentum  

Science Conference Proceedings (OSTI)

The dynamical processes that drive intraseasonal equatorial atmospheric angular momentum (EAAM) fluctuations are examined with the National Centers for Environmental Prediction–National Center for Atmospheric Research (NCEP–NCAR) reanalysis data. ...

Steven B. Feldstein

2006-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

VALDRIFT—A Valley Atmospheric Dispersion Model  

Science Conference Proceedings (OSTI)

VALDRIFT (valley drift) is a valley atmospheric transport, diffusion, and deposition model. The model is phenomenological—that is, the dominant meteorological processes governing the behavior of the valley atmosphere are formulated explicitly in ...

K. Jerry Allwine; Xindi Bian; C. David Whiteman; Harold W. Thistle

1997-08-01T23:59:59.000Z

182

A Spontaneously Generated Tropical Atmospheric General Circulation  

Science Conference Proceedings (OSTI)

A series of idealized atmospheric general circulation model (AGCM) experiments are presented. These experiments examine whether and how atmospheric deep moist convection, in the absence of meridional gradients in external forcing, interacts with ...

Ben P. Kirtman; Edwin K. Schneider

2000-07-01T23:59:59.000Z

183

Atmospheric Turbidity in the Polar Regions  

Science Conference Proceedings (OSTI)

Analysis is presented of 800 measurements of atmospheric monochromatic aerosol optical depth made poleward of 65° latitude. The atmosphere of the southern polar region appears to be uncontaminated but is charged with a background aerosol having ...

Glenn E. Shaw

1982-08-01T23:59:59.000Z

184

Advanced Atmospheric Modeling for Emergency Response  

Science Conference Proceedings (OSTI)

Atmospheric transport and diffusion models are an important part of emergency response systems for industrial facilities that have the potential to release significant quantities of toxic or radioactive material into the atmosphere. An advanced ...

Jerome D. Fast; B. Lance O'steen; Robert P. Addis

1995-03-01T23:59:59.000Z

185

Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

Solid oxide fuel cell (SOFC) technology, which offers many advantages over traditional energy conversion systems including low emission and high efficiency, has become increasingly attractive to the utility, automotive, and defense industries (as shown in Figure 1). As an all solid-state energy conversion device, the SOFC operates at high temperatures (700-1,000 C) and produces electricity by electrochemically combining the fuel and oxidant gases across an ionically conducting oxide membrane. To build up a useful voltage, a number of cells or PENs (Positive cathode-Electrolyte-Negative anode) are electrically connected in series in a stack through bi-polar plates, also known as interconnects. Shown in Figure 2 (a) is a schematic of the repeat unit for a planar stack, which is expected to be a mechanically robust, high power-density and cost-effective design. In the stack (refer to Figure 2 (b)), the interconnect is simultaneously exposed to both an oxidizing (air) environment on the cathode side and a reducing (fuels such as hydrogen or natural gas) environment on the anode side for thousands of hours at elevated temperatures (700-1,000 C). Other challenges include the fact that water vapor is likely to be present in both of these environments, and the fuel is likely to contain sulfide impurities. Also, the interconnect must be stable towards any sealing materials with which it is in contact, under numerous thermal cycles. Furthermore, the interconnect must also be stable towards electrical contact materials that are employed to minimize interfacial contact resistance, and/or the electrode materials. Considering these service environments, the interconnect materials should possess the following properties: (1) Good surface stability (resistance to oxidation and corrosion) in both cathodic (oxidizing) and anodic (reducing) atmospheres. (2) Thermal expansion matching to the ceramic PEN and other adjacent components, all of which typically have a coefficient of thermal expansion (CTE) in the range of 10.5-12.0 x 10{sup -6} K{sup -1}. (3) High electrical conductivity through both the bulk material and in-situ formed oxide scales. (4) Satisfactory bulk and interfacial mechanical/thermomechanical reliability and durability at the SOFC operating temperatures. (5) Good compatibility with other materials in contact with interconnects such as seals and electrical contact materials. Until recently, the leading candidate material for the interconnect was doped lanthanum chromite (LaCrO3), which is a ceramic material which can easily withstand the traditional 1000 C operating temperature. However, the high cost of raw materials and fabrication, difficulties in obtaining high-density chromite parts at reasonable sintering temperatures, and the tendency of the chromite interconnect to partially reduce at the fuel gas/interconnect interface, causing the component to warp and the peripheral seal to break, have plagued the commercialization of planar SOFCs for years. The recent trend in developing lower temperature, more cost-effective cells which utilize anode-supported, several micron-thin electrolytes and/or new electrolytes with improved conductivity make it feasible for lanthanum chromite to be supplanted by metals or alloys as the interconnect materials. Compared to doped lanthanum chromite, metals or alloys offer significantly lower raw material and fabrication costs.

Yang, Z Gary; Stevenson, Jeffry W.; Singh, Prabhakar

2003-06-15T23:59:59.000Z

186

Quantitative determination of atmospheric hydroperoxyl radical  

SciTech Connect

A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.

Springston, Stephen R. (Upton, NY); Lloyd, Judith (Westbury, NY); Zheng, Jun (Stony Brook, NY)

2007-10-23T23:59:59.000Z

187

INHIBITION OF METHANE ATMOSPHERIC FLAMES BY ...  

Science Conference Proceedings (OSTI)

... atmospheric pressure was studied. The burner temperature was maintained at 65 “C by using a thermostat. The volumetric velocity ...

2011-10-20T23:59:59.000Z

188

North Carolina Refinery Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

North Carolina Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

189

Method for making monolithic metal oxide aerogels  

DOE Patents (OSTI)

Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The containment vessel is enclosed within an aqueous atmosphere that is above the supercritical temperature and pressure of the solvent of the metal alkoxide solution.

Coronado, Paul R. (Livermore, CA)

1999-01-01T23:59:59.000Z

190

Detecting atmospheric rivers in large climate datasets  

Science Conference Proceedings (OSTI)

Extreme precipitation events on the western coast of North America are often traced to an unusual weather phenomenon known as atmospheric rivers. Although these storms may provide a significant fraction of the total water to the highly managed western ... Keywords: atmospheric rivers, automatic detection of atmospheric rivers, connected component labeling, extreme climate events

Surendra Byna; Prabhat; Michael F. Wehner; Kesheng John Wu

2011-11-01T23:59:59.000Z

191

Acoustic Waves in the Turbulent Atmosphere: A Review  

Science Conference Proceedings (OSTI)

The subject of atmospheric acoustics and its role in atmospheric research and in development of modern methods of ground-based remote sensing of the atmosphere are outlined. A historical overview of investigations of the effect of atmospheric ...

M. A. Kallistratova

2002-08-01T23:59:59.000Z

192

Microwave plasma source operating with atmospheric pressure air-water mixtures  

Science Conference Proceedings (OSTI)

The overall performance of a surface wave driven air-water plasma source operating at atmospheric pressure and 2.45 GHz has been analyzed. A 1D model previously developed has been improved in order to describe in detail the creation and loss processes of active species of interest. This model provides a complete characterization of the axial structure of the source, including the discharge and the afterglow zones. The main electron creation channel was found to be the associative ionization process N + O {yields} NO{sup +}+ e. The NO(X) relative density in the afterglow plasma jet ranges from 1.2% to 1.6% depending on power and water percentage, according to the model predictions and the measurements. Other types of species such as NO{sub 2} and nitrous acid HNO{sub 2} have also been detected by mass and Fourier Transform Infrared spectroscopy. The relative population density of O({sup 3}P) ground state atoms increases from 8% to 10% in the discharge zone when the input microwave power increases from 200 to 400 W and the water percentage from 1% to 10%. Furthermore, high densities of O{sub 2}(a{sup 1}{Delta}{sub g}) singlet delta oxygen molecules and OH radicals (1% and 5%, respectively) can be achieved in the discharge zone. In the late afterglow the O{sub 2}(a{sup 1}{Delta}{sub g}) density is about 0.1% of the total density. This plasma source has a flexible operation and potential for channeling the energy in ways that maximize the density of active species of interest.

Tatarova, E.; Henriques, J. P.; Felizardo, E.; Lino da Silva, M.; Ferreira, C. M. [Institute of Plasmas and Nuclear Fusion, Instituto Superior Tecnico, Technical University of Lisbon, 1049-001 Lisbon (Portugal); Gordiets, B. [Lebedev Physical Institute of the Russian Academy of Sciences, 119991 Moscow (Russian Federation)

2012-11-01T23:59:59.000Z

193

Atmospheric Nitrogen Fixation by Lightning  

Science Conference Proceedings (OSTI)

The production Of nitrogen oxides (NO and NO2) by lightning flashes has been computed from a model of gaseous molecular reactions occurring as heated lightning-channel air cools by mixing with surrounding ambient air. The effect of ozone (O3) on ...

R. D. Hill; R. G. Rinker; H. Dale Wilson

1980-01-01T23:59:59.000Z

194

Transition metal oxides deposited on rhodium and platinum: Surface chemistry and catalysis  

DOE Green Energy (OSTI)

The surface chemistry and catalytic reactivity of transition metal oxides deposited on Rh and Pt substrates has been examined in order to establish the role of oxide-metal interactions in influencing catalytic activity. The oxides investigated included titanium oxide (TiOx), vanadium oxide (VOx), iron oxide (FeOx), zirconium oxide (ZrOx), niobium oxide (NbOx), tantalum oxide (TaOx), and tungsten oxide (WOx). The techniques used to characterize the sample included AES, XPS, LEED, TPD, ISS, and STM. After characterization of the surface in UHV, the sample was enclosed in an atmospheric reaction cell to measure the influence of the oxide deposits on the catalytic activity of the pure metal for CO and CO{sub 2} hydrogenation. The oxide deposits were found to strongly enhance the reactivity of the Rh foil. The rates of methane formation were promoted by up to 15 fold with the maximum in rate enhancement occurring at oxide coverages of approximately 0.5 ML. TiOx TaOx, and NbOx were the most effective promoters and were stable in the highest oxidation states during both reactions (compared to VOx, WOx, and FeOx). The trend in promoter effectiveness was attributed to the direct relationship between oxidation state and Lewis acidity. Bonding at the metal oxide/metal interface between the oxygen end of adsorbed CO and the Lewis acidic oxide was postulated to facilitate C-O bond dissociation and subsequent hydrogenation. 192 refs.

Boffa, A.B. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States). Materials Sciences Div.

1994-07-01T23:59:59.000Z

195

MODELING CHAR OXIDATION AS A FUNCTION OF PRESSURE USING AN INTRINSIC LANGMUIR RATE EQUATION  

E-Print Network (OSTI)

, is essential in boiler design and operation. Technologies have been under development to burn coal more of Engineering and Technology #12;ABSTRACT MODELING CHAR OXIDATION AT ATMOSPHERIC AND ELEVATED PRESSURES USING was to develop a model that can be used to explain and unify char oxidation rates over wide ranges

Fletcher, Thomas H.

196

Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets  

Science Conference Proceedings (OSTI)

Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within ± 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than ± 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than ± 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2?3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute are captured. Influence functions, derived using a Lagrangian Particle Dispersion model driven by the CSU Regional Atmospheric Modeling System and nudged to NCEP reanalysis meteorological fields, are used to determine source regions for the towers. The influence functions are combined with satellite vegetation observations to interpret the observed trends in CO2 concentration. Full inversions will combine these elements in a more formal analytic framework.

Davis, K.J.; Richardson, S.J.; Miles, N.L.

2007-03-07T23:59:59.000Z

197

Method for fluorination of uranium oxide  

SciTech Connect

Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

Petit, George S. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

198

High-energy atmospheric neutrinos  

E-Print Network (OSTI)

High-energy neutrinos, arising from decays of mesons that were produced through the cosmic rays collisions with air nuclei, form unavoidable background noise in the astrophysical neutrino detection problem. The atmospheric neutrino flux above 1 PeV should be supposedly dominated by the contribution of charmed particle decays. These (prompt) neutrinos originated from decays of massive and shortlived particles, $D^\\pm$, $D^0$, $\\bar{D}{}^0$, $D_s^\\pm$, $\\Lambda^+_c$, form the most uncertain fraction of the high-energy atmospheric neutrino flux because of poor explored processes of the charm production. Besides, an ambiguity in high-energy behavior of pion and especially kaon production cross sections for nucleon-nucleus collisions may affect essentially the calculated neutrino flux. There is the energy region where above flux uncertainties superimpose. A new calculation presented here reveals sizable differences, up to the factor of 1.8 above 1 TeV, in muon neutrino flux predictions obtained with usage of known...

Sinegovsky, S I; Sinegovskaya, T S

2010-01-01T23:59:59.000Z

199

Lipid Oxidation Pathways  

Science Conference Proceedings (OSTI)

This book reviews state-of-the-art developments in the understanding of the oxidation of lipids and its connection with the oxidation of other biological molecules such as proteins and starch. Lipid Oxidation Pathways Hardback Books Health - Nutrition -

200

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents (OSTI)

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

Khan, M. Rashid (Morgantown, WV)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents (OSTI)

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

Rashid Khan, M.

1988-05-05T23:59:59.000Z

202

Formation of metal oxides by cathodic arc deposition  

DOE Green Energy (OSTI)

Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

1995-03-01T23:59:59.000Z

203

Selective methane oxidation over promoted oxide catalysts  

DOE Green Energy (OSTI)

Objective was to selectively oxidize methane to C{sub 2} hydrocarbons and to oxygenates, in particular formaldehyde and methanol, in high space time yields under relatively mild reaction conditions. Results in this document are reported under the headings: methane oxidation over silica, methane oxidation over Sr/La{sub 2}O{sub 3} catalysts, and oxidative coupling of methane over sulfate-doped Sr/La{sub 2}O{sub 3} catalysts. 24 refs, 10 figs, 4 tabs.

Klier, K.; Herman, R.G.

1993-12-31T23:59:59.000Z

204

Atmospheric neutrino flux at INO site  

Science Conference Proceedings (OSTI)

To illustrate the calculation of the atmospheric neutrino flux, we briefly explain our calculation scheme and important components, such as primary cosmic ray spectra, interaction model, and geomagnetic model. Then, we calculate the atmospheric neutrino flux at INO site in our calculation scheme. We compare the calculated atmospheric neutrino fluxes predicted at INO with those at other major neutrino detector sites, especially that at SK site.

Honda, Morihiro [Institute for Cosmic Ray Research, University of Tokyo, 5-1-5 Kashiwa-no-ha, Kashiwa, Chiba 277-8582 (Japan)

2011-11-23T23:59:59.000Z

205

Earth and Atmospheric Sciences | More Science | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Nuclear Forensics Climate & Environment Sensors and Measurements Chemical & Engineering Materials Computational Earth Science Systems Modeling Geographic Information Science and Technology Materials Science and Engineering Mathematics Physics More Science Home | Science & Discovery | More Science | Earth and Atmospheric Sciences SHARE Earth and Atmospheric Sciences At ORNL, we combine our capabilities in atmospheric science, computational science, and biological and environmental systems science to focus in the cross-disciplinary field of climate change science. We use computer models to improve climate change predications and to measure the impact of global warming on the cycling of chemicals in earth systems. Our Climate Change Science Institute uses models to explore connections among atmosphere,

206

Atmospheric carbon dioxide and the greenhouse effect  

SciTech Connect

This document contains a non-technical review of the problems associated with atmospheric carbon dioxide and the resulting greenhouse effect. (TEM)

Firestine, M.W. (ed.)

1989-05-01T23:59:59.000Z

207

NREL: Process Development and Integration Laboratory - Atmospheric  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Processing Platform Capabilities Atmospheric Processing Platform Capabilities The Atmospheric Processing platform in the Process Development and Integration Laboratory offers powerful capabilities with integrated tools for depositing, processing, and characterizing photovoltaic materials and devices. In particular, this platform focuses on different methods to deposit ("write") materials onto a variety of substrates and then further process into optoelectronic materials using rapid thermal processing. You can read more on the rationale for developing this platform and its capabilities. Contact Maikel van Hest for more details on these capabilities. The Atmospheric Processing platform will allow deposition in any sequence and is applicable to activities in all Technology Roadmaps, which include

208

Mesoscale Coupled Ocean-Atmosphere Interaction  

E-Print Network (OSTI)

small-scale features in ocean winds. Science, 303, Chelton,of the regional coupled ocean-atmosphere model RCAO. Borealstress dependence on ocean surface velocity: implications

Seo, Hyodae

2007-01-01T23:59:59.000Z

209

Mesoscale coupled ocean-atmosphere interaction  

E-Print Network (OSTI)

small-scale features in ocean winds. Science, 303, Chelton,of the regional coupled ocean-atmosphere model RCAO. Borealstress dependence on ocean surface velocity: implications

Seo, Hyodae

2007-01-01T23:59:59.000Z

210

FOAM:The Fast Ocean Atmosphere Model  

NLE Websites -- All DOE Office Websites (Extended Search)

Models Performance User Resources Publications History Developer's Page FOAM The Fast Ocean Atmosphere Model cup2.jpeg (48474 bytes) Image made by Johan Kellum with Vis5D...

211

12.815 Atmospheric Radiation, Fall 2005  

E-Print Network (OSTI)

Introduction to the physics of atmospheric radiation and remote sensing including use of computer codes. Radiative transfer equation including emission and scattering, spectroscopy, Mie theory, and numerical solutions. ...

Prinn, Ronald G.

212

Atmospheric Radiation Measurement Convective and Orographically...  

NLE Websites -- All DOE Office Websites (Extended Search)

Induced Precipitation Study The U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) Climate Research Facility is providing the ARM Mobile Facility...

213

Atmospheric Radiation Measurement Program Climate Research Facility...  

NLE Websites -- All DOE Office Websites (Extended Search)

2 Atmospheric Radiation Measurement Program Climate Research Facility Operations Quarterly Report October 1-December 31, 2010 DISCLAIMER This report was prepared as an account of...

214

Atmospheric Radiation Measurement Program Climate Research Facility...  

NLE Websites -- All DOE Office Websites (Extended Search)

9 Atmospheric Radiation Measurement Program Climate Research Facility Operations Quarterly Report April 1-June 30, 2011 DISCLAIMER This report was prepared as an account of work...

215

Jefferson Lab Science Series - Investigating Earth's Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

Byron Meadows - NASALangley Research Center May 14, 1991 Demonstrations of weather forecasting tools and techniques for experiments in the atmosphere and of lasers used to...

216

Total Atmospheric Crude Oil Distillation Capacity Former ...  

U.S. Energy Information Administration (EIA)

Former Corporation/Refiner Total Atmospheric Crude Oil Distillation Capacity (bbl/cd)a New Corporation/Refiner Date of Sale Table 14. Refinery Sales During 2005

217

Internal Versus SST-Forced Atmospheric Variability as Simulated by an Atmospheric General Circulation Model  

Science Conference Proceedings (OSTI)

The variability of atmospheric flow is analyzed by separating it into an internal part due to atmospheric dynamics only and an external (or forced) part due to the variability of sea surface temperature forcing. The two modes of variability are ...

Ali Harzallah; Robert Sadourny

1995-03-01T23:59:59.000Z

218

Transient Response of a Global Ocean-Atmosphere Model to a Doubling of Atmospheric Carbon Dioxide  

Science Conference Proceedings (OSTI)

The transient response of climate to an instantaneous increase in the atmospheric concentration of carbon dioxide has been investigated by a general circulation model of the coupled ocean-atmosphere-land system with global geography and annual ...

Syukuro Manabe; Kirk Bryan; Michael J. Spelman

1990-05-01T23:59:59.000Z

219

Measurements of Atmospheric Methane and 13C/12C of Atmospheric...  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane and 13C12C, Flask Air Samples Measurements of Atmospheric Methane and 13C12C of Atmospheric Methane from Flask Air Samples (1999) data Data Investigators Paul Quay and...

220

Response of the Middle Atmosphere to CO2 Doubling: Results from the Canadian Middle Atmosphere Model  

Science Conference Proceedings (OSTI)

The Canadian Middle Atmosphere Model (CMAM) has been used to examine the middle atmosphere response to CO2 doubling. The radiative-photochemical response induced by doubling CO2 alone and the response produced by changes in prescribed SSTs are ...

V. I. Fomichev; A. I. Jonsson; J. de Grandpré; S. R. Beagley; C. McLandress; K. Semeniuk; T. G. Shepherd

2007-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

AN INVESTIGATION OF URANIUM CORROSION IN 100 C WATER AND 200 C STEAM AT ATMOSPHERIC PRESSURE  

DOE Green Energy (OSTI)

Material balance in atmospheric-pressure water and steam corrosion of uranium have been studied by examination of the phase composition and valence state of the corrosion product and by hydrogen-evolution measurements. The corrosion rates in atmospheric-pressure steam above 100 deg C are lower than those obtained in tests carried out in water with a hydrogen overpressure. The atmospheric-pressure-water corrosion product was found to be two phase: an oxygen- rich oxide, UO/sub 2.2/, and uncorroded metal particles. No hydride phase was detected, in contrast to previously reported evidence for hydride in uranium corrosion. The differences are explained on the basis of hydrogen pressure in the reaction vessel. (auth)

Stewart, O.M.; Berry, W.E.; Miller, P.D.; Vaughan, D.A.; Schroeder, J.B.; Fink, F.W.; Schwartz, C.M.

1958-06-19T23:59:59.000Z

222

Scanning Transmission X-ray Microscopy: Applications in Atmospheric Aerosol Research  

Science Conference Proceedings (OSTI)

Scanning transmission x-ray microscopy (STXM) combines x-ray microscopy and near edge x-ray absorption fine structure spectroscopy (NEXAFS). This combination provides spatially resolved bonding and oxidation state information. While there are reviews relevant to STXM/NEXAFS applications in other environmental fields (and magnetic materials) this chapter focuses on atmospheric aerosols. It provides an introduction to this technique in a manner approachable to non-experts. It begins with relevant background information on synchrotron radiation sources and a description of NEXAFS spectroscopy. The bulk of the chapter provides a survey of STXM/NEXAFS aerosol studies and is organized according to the type of aerosol investigated. The purpose is to illustrate the current range and recent growth of scientific investigations employing STXM-NEXAFS to probe atmospheric aerosol morphology, surface coatings, mixing states, and atmospheric processing.

Moffet, Ryan C.; Tivanski, Alexei V.; Gilles, Mary K.

2011-01-20T23:59:59.000Z

223

Review of literature on catalytic recombination of hydrogen--oxygen. [Removal of hydrogen from containment atmosphere following LWR blowdown  

DOE Green Energy (OSTI)

The results are reported of a literature search for information concerning the heterogeneous, gas phase, catalytic hydrogen-oxygen recombination. Laboratory scale experiments to test the performance of specific metal oxide catalysts under conditions simulating the atmosphere within a nuclear reactor containment vessel following a loss-of-coolant blowdown accident are suggested.

Homsy, R.V.; Glatron, C.A.

1968-05-03T23:59:59.000Z

224

Atmospheric emissions of one pulp and paper mill. contribution to the air quality of Viana do Castelo  

Science Conference Proceedings (OSTI)

One of the most sensitive environmental impact of the pulp and paper mills is associated with the atmospheric pollution namely with sulphur compounds, particulate matter and nitrogen oxides. The study undertaken aimed to evaluate the influence of one ... Keywords: air pollution modelling, kraft pulp and paper mill, urban air pollution

Lígia T. Silva; José F. G. Mendes

2009-10-01T23:59:59.000Z

225

Measuring Mercury Isotopes in the Atmosphere and Rainfall near a Coal-Fired Power Plant  

Science Conference Proceedings (OSTI)

Recent work has shown that the seven naturally occurring stable isotopes of mercury (Hg) undergo mass-dependent fractionation (MDF) and mass-independent fractionation (MIF) during transformation processes, especially during chemical oxidation and reduction (redox) reactions that can occur in the atmosphere. The isotopic patterns resulting from fractionation can be used to help trace the sources of Hg in the environment and to help clarify the mechanisms of Hg cycling. This project was designed with ...

2013-11-19T23:59:59.000Z

226

Human effects on the global atmosphere  

SciTech Connect

This review considers whether human activities can significantly change important functions of the global atmosphere by altering the amount or distribution of certain trace species. It deals with three specific topics: stratopheric ozone, the role of species other than carbon dioxide on the greenhouse effect, and certain recently recognized atmospheric consequences of a large scale nuclear war. 64 references, 10 figures, 2 tables.

Johnston, H.S.

1984-01-01T23:59:59.000Z

227

Overwater Atmospheric Diffusion: Measurements and Parameterization  

Science Conference Proceedings (OSTI)

A series of ten atmospheric tracer experiments provided 62 hours of overwater atmospheric dispersion data. Sulfur hexafluoride (SF6) was released as the tracer gas at a height of 13 m from a ship positioned about 7 km off the central California ...

Walter F. Dabberdt

1986-08-01T23:59:59.000Z

228

Measurements of Atmospheric Nanoparticles (1875–1980)  

Science Conference Proceedings (OSTI)

The atmosphere contains a large variety of particles, ranging in size from near molecular (~1 nm) to larger than 10,000 nm. The total number concentration N of particles is dominated by nanoparticles ? 100 nm in diameter. Discovery of atmospheric ...

Volker Mohnen; George M. Hidy

2010-11-01T23:59:59.000Z

229

Earth's early atmosphere  

SciTech Connect

Ideas about atmospheric composition and climate on the early Earth have evolved considerably over the last 30 years, but many uncertainties still remain. It is generally agreed that the atmosphere contained little or no free oxygen initially and that oxygen concentrations increased markely near 2.0 billion years ago, but the precise timing of and reasons for its rise remain unexplained. Likewise, it is usually conceded that the atmospheric greenhouse effect must have been higher in the past to offset reduced solar luminosity, but the levels of atmospheric carbon cioxide and other greenhouse gases required remain speculative. A better understanding of past atmospheric evolution is important to understanding the evolution of life and to predicting whether Earth-like planets might exist elsewhere in the galaxy.

Kasting, J.F. (Pennsylvania State Univ., University Park (United States))

1993-02-12T23:59:59.000Z

230

CO oxidation on substituted copper chromite spinel oxide catalysts  

Science Conference Proceedings (OSTI)

Oxidation of carbon monoxide was studied on Mg- and Al-substituted CuCr[sub 2]O[sub 4] spinel catalyst at atmospheric pressure and temperatures between 373 and 723 K. The activity of CuCr[sub 2]O[sub 4] decreased even for small replacements of either Cu by Mg or Cr by Al and none of the substituted oxides was as active as CuCr[sub 2]O[sub 4]. In Cu[sub 1[minus]x]Mg[sub x]Cr[sub 2]O[sub 4] catalysts, the activity systematically decreased with increasing x, except for 0.4 < x < 0.6. The decrease in activity is due to a decrease in the active Cu[sup 2+] ions of the catalyst. The increase in activity on increasing x from 0.4 to 0.6 is attributed to the crystallographic phase change, i.e., tetragonal to cubic, in the catalyst. This was also found in the CuCr[sub 2[minus]x]Al[sub x]O[sub 4] catalysts. The decrease in the catalytic activity on substitution of Cr by Al, even when the total copper content is not altered, is due to the reduction of some of the active Cu[sup 2+] ions to Cu[sup 1+] ions. 10 refs., 9 figs., 2 tabs.

Murthy, K.S.R.C. (Indian Telephone Industries, Ltd., Banglore (India)); Ghose, J. (Indian Institute of Technology, Kharagpur (India))

1994-05-01T23:59:59.000Z

231

Photo-oxidation catalysts  

DOE Patents (OSTI)

Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

2009-07-14T23:59:59.000Z

232

NUCLEAR POWERED CO2 CAPTURE FROM THE ATMOSPHERE  

DOE Green Energy (OSTI)

A process for capturing CO{sub 2} from the atmosphere was recently proposed. This process uses a closed cycle of sodium and calcium hydroxide, carbonate, and oxide transformations to capture dilute CO{sub 2} from the atmosphere and to generate a concentrated stream of CO{sub 2} that is amenable to sequestration or subsequent chemical transformations. In one of the process steps, a fossil-fueled lime kiln is needed, which reduces the net CO{sub 2} capture of the process. It is proposed to replace the fossil-fueled lime kiln with a modified kiln heated by a high-temperature nuclear reactor. This will have the effect of eliminating the use of fossil fuels for the process and increasing the net CO{sub 2} capture. Although the process is suitable to support sequestration, the use of a nuclear power source for the process provides additional capabilities, and the captured CO{sub 2} may be combined with nuclear-produced hydrogen to produce liquid fuels via Fischer-Tropsch synthesis or other technologies. Conceivably, such plants would be carbon-neutral, and could be placed virtually anywhere without being tied to fossil fuel sources or geological sequestration sites.

Sherman, S

2008-09-22T23:59:59.000Z

233

The Upper Atmosphere of HD17156b  

E-Print Network (OSTI)

HD17156b is a newly-found transiting extrasolar giant planet (EGP) that orbits its G-type host star in a highly eccentric orbit (e~0.67) with an orbital semi-major axis of 0.16 AU. Its period, 21.2 Earth days, is the longest among the known transiting planets. The atmosphere of the planet undergoes a 27-fold variation in stellar irradiation during each orbit, making it an interesting subject for atmospheric modelling. We have used a three-dimensional model of the upper atmosphere and ionosphere for extrasolar gas giants in order to simulate the progress of HD17156b along its eccentric orbit. Here we present the results of these simulations and discuss the stability, circulation, and composition in its upper atmosphere. Contrary to the well-known transiting planet HD209458b, we find that the atmosphere of HD17156b is unlikely to escape hydrodynamically at any point along the orbit, even if the upper atmosphere is almost entirely composed of atomic hydrogen and H+, and infrared cooling by H3+ ions is negligible. The nature of the upper atmosphere is sensitive to to the composition of the thermosphere, and in particular to the mixing ratio of H2, as the availability of H2 regulates radiative cooling. In light of different simulations we make specific predictions about the thermosphere-ionosphere system of HD17156b that can potentially be verified by observations.

T. T. Koskinen; A. D. Aylward; S. Miller

2008-11-28T23:59:59.000Z

234

Multifunctional Oxides: Multifunctional Oxides: Synthesis and ...  

Science Conference Proceedings (OSTI)

Using Ultrafast Optical Spectroscopy to Explore Magneoelectric Coupling in Multiferroic Oxide Heterostructures: Y-M Sheu1; S. Trugman1; L Yan1; C-P Chuu 1; ...

235

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement performance has not been considered adequately in pavement design. Part of the reason is that the process of asphalt oxidation in pavement is not well understood. This work focused on understanding the asphalt oxidation kinetics and on developing pavement oxidation model that predicts asphalt oxidation and hardening in pavement under environmental conditions. A number of asphalts were studied in laboratory condition. Based on kinetics data, a fast-rate ? constant-rate asphalt oxidation kinetics model was developed to describe the early nonlinear fast-rate aging period and the later constant-rate period of asphalt oxidation. Furthermore, reaction kinetics parameters for the fast-rate and constant-rate reactions were empirically correlated, leading to a simplified model. And the experimental effort and time to obtain these kinetics parameters were significantly reduced. Furthermore, to investigate the mechanism of asphalt oxidation, two antioxidants were studied on their effectiveness. Asphalt oxidation was not significantly affected. It was found that evaluation of antioxidant effectiveness based on viscosity only is not reliable. The asphalt oxidation kinetics model was incorporated into the pavement oxidation model that predicts asphalt oxidation in pavement. The pavement oxidation model mimics the oxidation process of asphalt in real mixture at pavement temperatures. A new parameter, diffusion depth, defined the oxygen diffusion region in the mastic. A field calibration factor accounted for the factors not considered in the model such as the effect of small aggregate particles on oxygen diffusion. Carbonyl area and viscosity of binders recovered from field cores of three pavements in Texas were measured and were used for model calibration and validation. Results demonstrated that the proposed model estimates carbonyl growth over time in pavement, layer-by-layer, quite well. Finally, this work can be useful for incorporating asphalt oxidation into a pavement design method that can predict pavement performance with time and for making strategic decisions such as optimal time for maintenance treatments.

Jin, Xin

2012-05-01T23:59:59.000Z

236

Use of oxides in thermochemical water-splitting cycles for solar heat sources. Copper oxides  

DOE Green Energy (OSTI)

Several oxides can be decomposed to oxygen and a lower oxide at temperatures that might be feasible with a solar heat source. Heat might be directly transmitted to the solid through an air window, rather than quartz, with release of oxygen to the atmosphere. The cycle utilizing CuO, I/sub 2/, and Mg (OH)/sub 2/ is similar to the previous Co/sub 3/O/sub 4/ - CoO cycle. We are concentrating on the reformation of CuO. At 448 K the rate is favorable; for example, the yield rises about linearly with time to 92% at 1.17 h and more slowly thereafter. The only difficulty is the formation of CuI as a metastable intermediate. The oxidation of CuI is thermodynamically very favorable, but its rate limits completion. Excess Mg(OH)/sub 2/ appears to increase the rate but not to the point where IO/sub 3//sup -/ oxidation of CuI competes with oxidation of Cu/sub 2/O. Nevertheless, the batch runs suggest that about 98% of the maximum possible MgI/sub 2/ could be formed. Cuprous iodide complexes formed in the concentrated MgI/sub 2/ may give the necessary improvement by providing a solution path for their oxidation by iodate. Work of others pertaining to the cycle is briefly discussed.

Jones, W.M.; Bowman, M.G.

1984-01-01T23:59:59.000Z

237

Synoptic Reorganization of Atmospheric Flow during the Last Glacial Maximum  

Science Conference Proceedings (OSTI)

A coupled global atmosphere–ocean model of intermediate complexity is used to study the influence of glacial boundary conditions on the atmospheric circulation during the Last Glacial Maximum in a systematical manner. A web of atmospheric ...

Flávio Justino; Axel Timmermann; Ute Merkel; Enio P. Souza

2005-08-01T23:59:59.000Z

238

The NCAR Atmosphere-Surface Turbulent Exchange Research (ASTER) Facility  

Science Conference Proceedings (OSTI)

The Atmosphere-Surface Turbulent Exchange Research (ASTER) facility developed at the National Center for Atmospheric Research (NCAR) will support observational research on the structure of the atmospheric surface layer. ASTER will provide state-...

J. A. Businger; W. F. Dabberdt; A. C. Delany; T. W. Horst; C. L. Martin; S. P. Oncley; S. R. Semmer

1990-07-01T23:59:59.000Z

239

Estimating the Meridional Energy Transports in the Atmosphere and Ocean  

Science Conference Proceedings (OSTI)

The poleward energy transports in the atmosphere–ocean system are estimated for the annual mean and the four seasons based on satellite measurements of the net radiation balance at the top of the atmosphere, atmospheric transports of energy at ...

B. C. Carissimo; A. H. Oort; T. H. Vonder Haar

1985-01-01T23:59:59.000Z

240

Vacillations in a Coupled Ocean–Atmosphere Model  

Science Conference Proceedings (OSTI)

Results are presented from a 35-year integration of a coupled ocean-atmosphere model. Both ocean and atmosphere are two-level, nonlinear primitive equations models. The global atmospheric model is forced by a steady, zonally symmetric Newtonian ...

Paul S. Schopf; Max J. Suarez

1988-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Rainfall and Radiative Heating Rates from TOGA COARE Atmospheric Budgets  

Science Conference Proceedings (OSTI)

Atmospheric heat and moisture budgets are used to determine rainfall and radiative heating rates over the western Pacific warm pool during the Tropical Ocean Global Atmosphere Coupled Ocean–Atmosphere Response Experiment (TOGA COARE). Results are ...

Richard H. Johnson; Paul E. Ciesielski

2000-05-01T23:59:59.000Z

242

Including Atmospheric Layers in Vegetation and Urban Offline Surface Schemes  

Science Conference Proceedings (OSTI)

A formulation to include prognostic atmospheric layers in offline surface schemes is derived from atmospheric equations. Whereas multilayer schemes developed previously need a complex coupling between atmospheric-model levels and surface-scheme ...

Valéry Masson; Yann Seity

2009-07-01T23:59:59.000Z

243

Homoclinic Dynamics: A Scenario for Atmospheric Ultralow-Frequency Variability  

Science Conference Proceedings (OSTI)

In this paper, a link will be established between atmospheric ultralow-frequency variability (ULFV) and the occurrence of homoclinic dynamics in models of large-scale atmospheric flow. It is known that uncoupled atmosphere models possess ...

Daan T. Crommelin

2002-05-01T23:59:59.000Z

244

Atmospheric Circulation Response to an Instantaneous Doubling of Carbon Dioxide. Part II: Atmospheric Transient Adjustment and Its Dynamics  

Science Conference Proceedings (OSTI)

The dynamical mechanisms underlying the transient circulation adjustment in the extratropical atmosphere after the instantaneous doubling of carbon dioxide are investigated using the National Center for Atmospheric Research Community Atmosphere ...

Yutian Wu; Richard Seager; Tiffany A. Shaw; Mingfang Ting; Naomi Naik

2013-02-01T23:59:59.000Z

245

Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon...  

NLE Websites -- All DOE Office Websites (Extended Search)

Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and Carbon-13 in Methane Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and...

246

A U. S. Department of Energy User Facility Atmospheric Radiation  

NLE Websites -- All DOE Office Websites (Extended Search)

S. Department of Energy User Facility Atmospheric Radiation Measurement Climate Research Facility U.S. Department of Energy Atmospheric Radiation Measurement Program DOESC-ARM...

247

ATMOSPHERIC AEROSOL RESEARCH ANNUAL REPORT 1975-76  

E-Print Network (OSTI)

this room ATMOSPHERIC AEROSOL RESEARCH -RECEIVED •I.AWSSKCEDIVISION ATMOSPHERIC AEROSOL RESEARCH ANNUAL REPORTMass and Composition of Aerosol as a Function of Time,

Novakov, T.

2010-01-01T23:59:59.000Z

248

ATMOSPHERIC AEROSOL RESEARCH, ANNUAL REPORT 1976-77  

E-Print Network (OSTI)

DIVISION ATMOSPHERIC AEROSOL RESEARCH ANNUAL REPORTLow-Z Elements in Atmospheric Aerosol Particles by Nuclearof sulfur dioxide by aerosols of manganese sulfate," Ind.

Novakov, T.

2010-01-01T23:59:59.000Z

249

Observations of the atmospheric sulfur cycle on SAGA 3  

SciTech Connect

During the Soviet/American Gases and Aerosols (SAGA) 3 program in February and March 1991 the authors measured a wide variety of sulfur compounds simultaneously in the equatorial Pacific marine boundary layer. They made measurements of atmospheric dimethyl sulfide (DMS), sulfur dioxide (SO{sub 2}), and size-resolved aerosol non-sea-salt sulfate (NSS), and methane sulfonate (MSA). Some of the observed ratios contradict commonly held views of the marine sulfur cycle: the large DMS/NSS ratio implies that NSS may not be the primary product of DMS oxidation under some conditions. The authors also found much more DMS than SO{sub 2}, which may suggest that SO{sub 2} is not always an intermediate in DMS oxidation. The small SO{sub 2}/NSS ratio also supports the idea that most NSS was not formed from SO{sub 2}. Although the measured ratios of MSA/NSS were similar to previous observations in this region, much of the MSA was contained on supermicron particles, in contrast to both the NSS and the earlier MSA observations at higher latitudes. This implies that MSA/NSS ratios in ice cores may not accurately reflect the MSA/NSS ratios in their source areas. 51 refs., 4 figs., 3 tabs.

Huebert, B.J.; Howell, S.; Laj, P. [Univ. of Rhode Island, Narragansett, RI (United States); Johnson, J.E.; Bates, T.S.; Quinn, P.K. [NOAA/Pacific Marine Environmental Lab., Seattle, WA (United States); Yegorov, V. [State Committee for Hydrometeorology, Moscow (Russian Federation); Clarke, A.D.; Porter, J.N. [Univ. of Hawaii, Honolulu, HI (United States)

1993-09-20T23:59:59.000Z

250

Shortwave Transport in the Cloudy Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

Shortwave Transport in the Cloudy Atmosphere Shortwave Transport in the Cloudy Atmosphere by Anomalous/Lévy Diffusion: New Diagnostics Using FORTÉ Lightning Data A. B. Davis Los Alamos National Laboratory Space & Remote Sensing Sciences Group Los Alamos, New Mexico D. M. Suszcynsky Los Alamos National Laboratory Space & Atmospheric Sciences Group Los Alamos, New Mexico A. Marshak National Aeronautics and Space Administration Goddard Space Flight Center Greenbelt, Maryland Introduction Anomalous photon diffusion can be described as an ad hoc modification of the popular 2-stream approximation, specifically the δ-Eddington/diffusion version, for monochromatic radiative transfer in a scattering plane-parallel atmosphere. In the physical picture that describes the standard diffusion (hence

251

Atmospheric considerations for central receiver power plants  

DOE Green Energy (OSTI)

This report documents the results of a study of the effects of atmospheric attenuation, turbulent scattering, and the use of cooling towers on the performance of solar thermal central receiver power plants.

Henderson, R.G.; Pitter, R.L.

1979-06-01T23:59:59.000Z

252

Spectral Preconditioners for Nonhydrostatic Atmospheric Models  

Science Conference Proceedings (OSTI)

The elliptic problems in semi-implicit nonhydrostatic atmospheric models are difficult. Typically, they are poorly conditioned, nonseparable, contain cross-derivative terms, and are often nonsymmetric. Here, the resulting linear system is solved ...

Stephen J. Thomas; Joshua P. Hacker; Piotr K. Smolarkiewicz; Roland B. Stull

2003-10-01T23:59:59.000Z

253

Toward a Fully Lagrangian Atmospheric Modeling System  

Science Conference Proceedings (OSTI)

An improved treatment of advection is essential for atmospheric transport and chemistry models. Eulerian treatments are generally plagued with instabilities, unrealistic negative constituent values, diffusion, and dispersion errors. A higher-...

Jahrul M. Alam; John C. Lin

2008-12-01T23:59:59.000Z

254

Filtering of Gravity Modes in Atmospheric Models  

Science Conference Proceedings (OSTI)

The impact of gravity modes in atmospheric model predictions is assessed quantitatively by comparing integrations with a normal mode initialized primitive equation model and its corresponding pseudogeostrophic form to document some generally ...

F. Baer; J. J. Tribbia

1984-05-01T23:59:59.000Z

255

Stochastic Dynamics of the Midlatitude Atmospheric Jet  

Science Conference Proceedings (OSTI)

The innate tendency of the background straining field of the midlatitude atmospheric jet to preferentially amplify a subset of disturbances produces a characteristic response to stochastic perturbation whether the perturbations are internally ...

Brian F. Farrell; Peteros J. Ioannou

1995-05-01T23:59:59.000Z

256

Removal of Atmospheric Effects prom AVHRR Albedos  

Science Conference Proceedings (OSTI)

Based on numerical simulations, coefficients are determined to be used in a linear relationship between clear-sky planetary albedo and surface albedo. Thew coefficients are given as functions of solar zenith angle and atmospheric parameters for ...

Peter Koepke

1989-12-01T23:59:59.000Z

257

HYPERsensarium : an archive of atmospheric conditions  

E-Print Network (OSTI)

HYPERsensarium proposes a tangible interface of atmospheres for public experience through an archive of historical and projected weathers. While architecture's purpose has long been to act as the technical boundary between ...

Shaw, Kelly E. (Kelly Evelyn)

2013-01-01T23:59:59.000Z

258

Exploring Atmospheric Aerosols by Twilight Photometry  

Science Conference Proceedings (OSTI)

The instrument twilight photometer was designed, developed, and installed at the Indian Institute of Tropical Meteorology (IITM), Pune, India (18°43?N, 73°51?E), to monitor the vertical distribution of atmospheric aerosols. The instrument, based ...

B. Padma Kumari; S. H. Kulkarni; D. B. Jadhav; A. L. Londhe; H. K. Trimbake

2008-09-01T23:59:59.000Z

259

Carbon Dioxide Variability and Atmospheric Circulation  

Science Conference Proceedings (OSTI)

Hourly values of the concentration of atmospheric carbon dioxide at Mauna Loa Observatory (MLO) formed the basis for an investigation of concentration fluctuations on daily to monthly time scales. In agreement with earlier studies we found no ...

James C. Sadler; Colin S. Ramage; Arnold M. Hori

1982-06-01T23:59:59.000Z

260

Potential Vorticity in a Moist Atmosphere  

Science Conference Proceedings (OSTI)

The potential vorticity principle for a nonhydrostatic, moist, precipitating atmosphere is derived. An appropriate generalization of the well-known (dry) Ertel potential vorticity is found to be P = ??1(2? + × u)?·???, where ? is the total ...

Wayne H. Schubert; Scott A. Hausman; Matthew Garcia; Katsuyuki V. Ooyama; Hung-Chi Kuo

2001-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Nonlinear Atmospheric Adjustment to Thermal Forcing  

Science Conference Proceedings (OSTI)

A nonlinear, numerical model of a compressible atmosphere is used to simulate the hydrostatic and geostrophic adjustment to a localized prescribed heating applied over five minutes with a size characteristic of an isolated, deep, cumulus cloud. ...

Paul F. Fanelli; Peter R. Bannon

2005-12-01T23:59:59.000Z

262

Effect of Nonlinearity on Atmospheric Gravity Waves  

Science Conference Proceedings (OSTI)

The weakly nonlinear limit of two-dimensional gravity waves in an incompressible, inviscid and stably stratified atmosphere is studied. The three-wave resonant interaction theory indicates an energy cascade from a vertically propagating wave (...

Mostafa M. Ibrahim

1987-02-01T23:59:59.000Z

263

Shear Excitation of Atmospheric Gravity Waves  

Science Conference Proceedings (OSTI)

Unstable Velocity shears are a Common source of vertically propagating gravity waves in the atmosphere. However, the growth rates of unstable modes predicted by linear theory cannot always amount for their observed importance.

David C. Fritts

1982-09-01T23:59:59.000Z

264

Dynamic Stabilization of Atmospheric Single Column Models  

Science Conference Proceedings (OSTI)

Single column models (SCMs) provide an economical framework for assessing the sensitivity of atmospheric temperature and humidity to natural and imposed perturbations, and also for developing improved representations of diabatic processes in ...

John W. Bergman; Prashant D. Sardeshmukh

2004-03-01T23:59:59.000Z

265

Intraseasonal Variability in a Dry Atmospheric Model  

Science Conference Proceedings (OSTI)

A long integration of a primitive equation dry atmospheric model with time-independent forcing under boreal winter conditions is analyzed. A variety of techniques such as time filtering, space–time spectral analysis, and lag regressions are used ...

Hai Lin; Gilbert Brunet; Jacques Derome

2007-07-01T23:59:59.000Z

266

The Atmospheric Mesoscale Dispersion Modeling System  

Science Conference Proceedings (OSTI)

The mesoscale dispersion modeling system (MDMS) described herein is under development as a simulation tool to investigate atmospheric flow and pollution dispersion over complex terrain for domains up to several hundred kilometers. The system ...

Marek Uliasz

1993-01-01T23:59:59.000Z

267

Atmospheric Entropy. Part I: Climate Dissipation Structure  

Science Conference Proceedings (OSTI)

Atmospheric entropy and its association with climate dissipation are investigated. The balance equation for entropy is derived through the mean and transient thermal and moisture equations. The entropy production contains the internal and external ...

Jiangnan Li; Petr Chylek

2012-05-01T23:59:59.000Z

268

Atmospheric Turbidity over Central North Carolina  

Science Conference Proceedings (OSTI)

Some 8500 observations of atmospheric turbidity, taken at Raleigh, North Carolina from July 1969 to July 1975 are analyzed for within-day and day-to-day variations and their dependence on meteorological parameters. The annual average turbidity of ...

James T. Peterson; Edwin C. Flowers; Guillermo J. Berri; Cheryl L. Reynolds; John H. Rudisill

1981-03-01T23:59:59.000Z

269

Meteorological Tracer Techniques for Parameterizing Atmospheric Dispersion  

Science Conference Proceedings (OSTI)

Although tracer materials have been used in atmospheric dispersion studies for decades, basic information about meteorological tracer techniques is scattered among a number of different sources. This paper attempts to pull together this ...

Warren B. Johnson

1983-05-01T23:59:59.000Z

270

Linear Baroclinic Instability in the Martian Atmosphere  

Science Conference Proceedings (OSTI)

The linear baroclinic instability of zonal-mean flows like those in the wintertime Martian atmosphere under both relatively nondusty and highly dusty conditions is examined using a spherical quasi-geostrophic model. The basic states are idealized,...

Jeffrey R. Barnes

1984-05-01T23:59:59.000Z

271

State-Space Modeling for Atmospheric Pollution  

Science Conference Proceedings (OSTI)

Two different aspect concerning the state-space modeling for atmospheric pollution are dealt with separately in this paper: (i) the treatment of the advection-diffusion equation and (ii) the use of time series analysis.

E. Hernández; F. Martín; F. Valero

1991-06-01T23:59:59.000Z

272

Resonant Planetary Waves in a Spherical Atmosphere  

Science Conference Proceedings (OSTI)

A global model of planetary wave propagation in a spherical atmosphere is used to examine the spectrum of free or resonant planetary waves of the solstitial stratosphere. These free modes are located by forcing the model with a weak periodic ...

Mark R. Schoeberl; John H. E. Clark

1980-01-01T23:59:59.000Z

273

The Flywheel Effect in the Middle Atmosphere  

Science Conference Proceedings (OSTI)

Because of the requirement of geostrophic balance, mechanical inertia can affect the thermal response of the atmosphere to transient heating. We examine some very simple linear models of this “flywheel effect,” and discuss their possible ...

Roelof K. Snieder; Stephen B. Fels

1988-12-01T23:59:59.000Z

274

Atmosphere–Ocean Modeling Exploiting Fluid Isomorphisms  

Science Conference Proceedings (OSTI)

Mathematical isomorphisms between the hydrostatic equations that govern the evolution of a compressible atmosphere and an incompressible ocean are described and exploited to guide the design of a hydrodynamical kernel for simulation of either ...

John Marshall; Alistair Adcroft; Jean-Michel Campin; Chris Hill; Andy White

2004-12-01T23:59:59.000Z

275

Basic Meteorological Observations for Schools: Atmospheric Pressure  

Science Conference Proceedings (OSTI)

This article addresses measurement of atmospheric surface pressure using economical instruments. It is intended to provide members of the Society with a ready reference to respond to inquiries from earth and physical science teachers at the ...

John T. Snow; Michelle E. Akridge; Shawn B. Harley

1992-06-01T23:59:59.000Z

276

A Comprehensive Ocean-Atmosphere Data Set  

Science Conference Proceedings (OSTI)

Development is described of a Comprehensive Ocean-Atmosphere Data Set (COADS)—the result of a cooperative project to collect global weather observations taken near the ocean's surface since 1854, primarily from merchant ships, into a compact and ...

Scott D. Woodruff; Ralph J. Slutz; Roy L. Jenne; Peter M. Steurer

1987-10-01T23:59:59.000Z

277

Effects of Atmospheric Turbulence on Ballistic Testing  

Science Conference Proceedings (OSTI)

The effects of atmospheric turbulence on munition target scatter are determined from numerical simulations of ballistic trajectories through many realizations of realistic simulated turbulent wind fields. A technique is evaluated for correcting ...

Rod Frehlich; Robert Sharman; Charles Clough; Michael Padovani; Kelly Fling; Ward Boughers; W. Scott Walton

2008-05-01T23:59:59.000Z

278

Mars Atmosphere Pressure Periodicities from Viking Observations  

Science Conference Proceedings (OSTI)

The first martian year of pressure data taken by the Viking landers on Mars is subjected to power spectrum analysis. The analysis suggests that strong periodicities are present in the martian atmosphere, especially at the high-latitude (48°N) ...

R. D. Sharman; J. A. Ryan

1980-09-01T23:59:59.000Z

279

Pierre Auger Atmosphere-Monitoring Lidar System  

E-Print Network (OSTI)

The fluorescence-detection techniques of cosmic-ray air-shower experiments require precise knowledge of atmospheric properties to reconstruct air-shower energies. Up to now, the atmosphere in desert-like areas was assumed to be stable enough so that occasional calibration of atmospheric attenuation would suffice to reconstruct shower profiles. However, serious difficulties have been reported in recent fluorescence-detector experiments causing systematic errors in cosmic ray spectra at extreme energies. Therefore, a scanning backscatter lidar system has been constructed for the Pierre Auger Observatory in Malargue, Argentina, where on-line atmospheric monitoring will be performed. One lidar system is already deployed at the Los Leones fluorescence detector site and the second one is currently (April 2003) under construction at the Coihueco site. Next to the established ones, a novel analysis method with assumption on horizontal invariance, using multi-angle measurements is shown to unambiguously measure optical depth, as well as absorption and backscatter coefficient.

A. Filipcic; M. Horvat; D. Veberic; D. Zavrtanik; M. Zavrtanik; M. Chiosso; R. Mussa; G. Sequeiros; M. A. Mostafa; M. D. Roberts

2003-05-21T23:59:59.000Z

280

Profiling atmospheric aerosols | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

a number of instruments that use low power lasers (the instrument is called Micropulse Lidar, MPL) to measure the turbidity of the atmosphere above the ground. For the first time,...

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Reducing the atmospheric impact of wet slaking  

SciTech Connect

Means of reducing the atmospheric emissions due to the wet slaking of coke are considered. One option, investigated here, is to remove residual active silt and organic compounds from the biologically purified wastewater sent for slaking, by coagulation and flocculation.

B.D. Zubitskii; G.V. Ushakov; B.G. Tryasunov; A.G.Ushakov [Kuznetsk Basin State Technical University, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

282

Lookup tables to compute high energy cosmic ray induced atmospheric ionization and changes in atmospheric chemistry  

E-Print Network (OSTI)

A variety of events such as gamma-ray bursts and supernovae may expose the Earth to an increased flux of high-energy cosmic rays, with potentially important effects on the biosphere. Existing atmospheric chemistry software does not have the capability of incorporating the effects of substantial cosmic ray flux above 10 GeV . An atmospheric code, the NASA-Goddard Space Flight Center two-dimensional (latitude, altitude) time-dependent atmospheric model (NGSFC), is used to study atmospheric chemistry changes. Using CORSIKA, we have created tables that can be used to compute high energy cosmic ray (10 GeV - 1 PeV) induced atmospheric ionization and also, with the use of the NGSFC code, can be used to simulate the resulting atmospheric chemistry changes. We discuss the tables, their uses, weaknesses, and strengths.

Dimitra Atri; Adrian L. Melott; Brian C. Thomas

2008-04-20T23:59:59.000Z

283

Quantum light in the turbulent atmosphere  

E-Print Network (OSTI)

Nonclassical properties of light propagating through the turbulent atmosphere are studied. We demonstrate by numerical simulation that the probability distribution of the transmission coefficient, which characterizes the effects of the atmosphere on the quantum state of light, can be reconstructed by homodyne detection. Nonclassical photon-statistics and, more generally, nonclassical Glauber-Sudarshan functions appear to be more robust against turbulence for weak light fields rather than for bright ones.

A. A. Semenov; W. Vogel

2009-02-24T23:59:59.000Z

284

Atmospheric Neutrinos in the MINOS Far Detector  

Science Conference Proceedings (OSTI)

The phenomenon of flavour oscillations of neutrinos created in the atmosphere was first reported by the Super-Kamiokande collaboration in 1998 and since then has been confirmed by Soudan 2 and MACRO. The MINOS Far Detector is the first magnetized neutrino detector able to study atmospheric neutrino oscillations. Although it was designed to detect neutrinos from the NuMI beam, it provides a unique opportunity to measure the oscillation parameters for neutrinos and anti-neutrinos independently. The MINOS Far Detector was completed in August 2003 and since then has collected 2.52 kton-years of atmospheric data. Atmospheric neutrino interactions contained within the volume of the detector are separated from the dominant background from cosmic ray muons. Thirty seven events are selected with an estimated background contamination of less than 10%. Using the detector's magnetic field, 17 neutrino events and 6 anti-neutrino events are identified, 14 events have ambiguous charge. The neutrino oscillation parameters for {nu}{sub {mu}} and {bar {nu}}{sub {mu}} are studied using a maximum likelihood analysis. The measurement does not place constraining limits on the neutrino oscillation parameters due to the limited statistics of the data set analysed. However, this thesis represents the first observation of charge separated atmospheric neutrino interactions. It also details the techniques developed to perform atmospheric neutrino analyses in the MINOS Far Detector.

Howcroft, Caius L.F.; /Cambridge U.

2004-12-01T23:59:59.000Z

285

The Birth and Life of Our Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

Birth and Life of Our Atmosphere Birth and Life of Our Atmosphere Nature Bulletin No. 554-A February 15, 1975 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation THE BIRTH AND LIFE OF OUR ATMOSPHERE In Bulletin No. 542-A we described the atmosphere that surrounds the earth, held there by the pull of gravity, including the canopy of air immediately above us. That canopy is responsible for our weather and climates, shields us from the killing rays of the sun, and furnishes substances necessary for all life: oxygen, nitrogen, carbon dioxide, and water vapor. Astronomers believe that none of the other planets -- excepting Mars, perhaps -- has an atmosphere anything like ours. The principal elements, free nitrogen (78 percent) and free oxygen (21 percent), apparently are rare in the universe. On the other hand, the earth's atmosphere contains only traces of free hydrogen and helium -- the two lightest gases -- whereas they are by far the most common elements elsewhere in the universe.

286

A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States  

E-Print Network (OSTI)

Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

Sun, Lin, S.M. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

287

Technology Innovation Program Transforming America's ...  

Science Conference Proceedings (OSTI)

... Reducing US dependence on foreign oil. # Reducing carbon dioxide, nitrous oxide, and other ... Separation, sequestration, and utilization of CO2 ...

2011-02-02T23:59:59.000Z

288

Method for converting uranium oxides to uranium metal  

DOE Green Energy (OSTI)

A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixture is then cooled to a temperature less than -100.degree. C. in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

Duerksen, Walter K. (Norris, TN)

1988-01-01T23:59:59.000Z

289

Method for converting uranium oxides to uranium metal  

DOE Patents (OSTI)

A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixtures is then cooled to a temperature less than -100/sup 0/C in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

Duerksen, W.K.

1987-01-01T23:59:59.000Z

290

Pacific Northwest Laboratory annual report for 1993 to the DOE Office of Energy Research. Part 3: Atmospheric and climate research  

Science Conference Proceedings (OSTI)

The US Department of Energy`s (DOE`s) Office of Health and Environmental Research (OHER) atmospheric sciences and carbon dioxide research programs provide the DOE with scientifically defensible information on the local, regional, and global distributions of energy-related pollutants and their effects on climate. PNL has had a long history of technical leadership in the atmospheric sciences research programs within OHER. Within the Environmental Sciences Division of OHER, the Atmospheric Chemistry Program continues DOE`s long-term commitment to understanding the local, regional, and global effects of energy-related air pollutants. Research through direct measurement, numerical modeling, and analytical studies in the Atmospheric Chemistry Program emphasizes the long-range transport, chemical transformation, and removal of emitted pollutants, photochemically produced oxidant species, nitrogen-reservoir species, and aerosols. The atmospheric studies in Complex Terrain Program applies basic research on atmospheric boundary layer structure and evolution over inhomogeneous terrain to DOE`s site-specific and generic mission needs in site safety, air quality, and climate change. Research at PNL provides basic scientific underpinnings to DOE`s program of global climate research. Research projects within the core carbon dioxide and ocean research programs are now integrated with those in the Atmospheric Radiation Measurements, the Computer Hardware, Advanced Mathematics and Model Physics, and Quantitative Links program to form DOE`s contribution to the US Global Change Research Program. The description of ongoing atmospheric and climate research at PNL is organized in two broad research areas: atmospheric research; and climate research. This report describes the progress in fiscal year 1993 in each of these areas. Individual papers have been processed separately for inclusion in the appropriate data bases.

Not Available

1994-05-01T23:59:59.000Z

291

3D atmospheric modeling based on MODTRAN4  

Science Conference Proceedings (OSTI)

All the factors of atmospheric environment that influence the transmission of infrared radiation were analyzed in detail in the paper. Taking horizontally varying atmospheric property into consideration, a 3D model of atmospheric transmission of infrared ... Keywords: MODTRAN4, infrared radiation, model, path radiation, ratio of atmospheric transmission, simulation, single scatter solar radiation

Ge Li; Zhifeng Lu; Gang Guo; Kedi Huang

2008-06-01T23:59:59.000Z

292

East Coast (PADD 1) Gross Inputs to Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

East Coast (PADD 1) Gross Inputs to Atmospheric Crude Oil Distillation Units (Thousand Barrels per Day)

293

Guam Refinery Operable Atmospheric Crude Oil Distillation Capacity ...  

U.S. Energy Information Administration (EIA)

Guam Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

294

Refining District New Mexico Gross Inputs to Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

Refining District New Mexico Gross Inputs to Atmospheric Crude Oil Distillation Units (Thousand Barrels per Day)

295

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Green Energy (OSTI)

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

296

Partial oxidation catalyst  

DOE Patents (OSTI)

A two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion. The dehydrogenation portion is a group VIII metal and the oxide-ion conducting portion is selected from a ceramic oxide crystallizing in the fluorite or perovskite structure. There is also disclosed a method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

2000-01-01T23:59:59.000Z

297

Atmospheric and Climate Science | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric and Climate Science Atmospheric and Climate Science Argonne research in aerosols, micro-meteorology, remote sensing, and atmospheric chemistry combined with our scalable, portable, high-performance climate and weather applications offer a unique look at the complexities of a dynamic planet. Changes in climate can affect biodiversity, the cost of food, our health, and even whole economies. Argonne is developing computational models and tools designed to shed light on complex biological processes and their economic, social, and health effects. Research spans the molecular level to whole organisms and their interaction with climate, the ecosystem, and human activities. The goal is to improve our understanding of the world around us while increasing the accuracy of regional climate models to

298

Atmospheric Delta 14C Record from Wellington  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Isotopes » Carbon Isotopes » δ14C from Wellington Atmospheric δ14C Record from Wellington graphics Graphics data Data Investigators M.R. Manning, W.H. Melhuish National Institute of Water and Atmospheric Research, Ltd., Climate Division, Gracefield Road, Gracefield, P.O. Box 31-311, Lower Hutt, New Zealand Period of Record 1954-93 Methods Trays containing ~2 L of 5 normal NaOH carbonate-free solution are typically exposed for intervals of 1-2 weeks, and the atmospheric CO2 absorbed during that time is recovered by acid evolution. Considerable fractionation occurs during absorption into the NaOH solution, and the standard fractionation correction (Stuiver and Polach 1977) is used to determine a δ 14C value corrected to δ 13C = -25 per mil. Some samples reported here were taken using BaOH solution or with extended

299

atmospheric water vapor | OpenEI  

Open Energy Info (EERE)

atmospheric water vapor atmospheric water vapor Dataset Summary Description (Abstract): Monthly Average Solar Resource for 2-axis tracking concentrating collectors for Mexico, Central America, and the Caribbean Islands. (Purpose): Provide information on the solar resource potential for the data domain. The insolation values represent the average solar energy available to a concentrating collector, such as a dish collector, which tracks the sun continuously. Source NREL Date Released July 31st, 2006 (8 years ago) Date Updated October 30th, 2007 (7 years ago) Keywords atmospheric water vapor Carribean Islands Central America DNI GIS Mexico NREL GEF solar SWERA UNEP Data application/zip icon Download Shapefile (zip, 247.8 KiB) text/csv icon Download Data (csv, 370.6 KiB) Quality Metrics Level of Review Some Review

300

Our Dusty Atmosphere | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dusty Atmosphere Dusty Atmosphere Our Dusty Atmosphere September 6, 2011 - 4:26pm Addthis A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL Charles Rousseaux Charles Rousseaux Senior Writer, Office of Science What are the key facts? Researchers are developing a better understanding of the effects of

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Our Dusty Atmosphere | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Our Dusty Atmosphere Our Dusty Atmosphere Our Dusty Atmosphere September 6, 2011 - 4:26pm Addthis A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL Charles Rousseaux Charles Rousseaux Senior Writer, Office of Science What are the key facts? Researchers are developing a better understanding of the effects of

302

Atmospheric Radiation Measurement Climate Research Facility | Argonne  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Radiation Measurement Climate Research Facility Atmospheric Radiation Measurement Climate Research Facility Argonne scientists study climate change 1 of 22 Argonne scientists study climate change The U.S. Department of Energy's Office of Science provided $60 million in ARRA funding for climate research to the Atmospheric Radiation Measurement (ARM) Climate Research Facility, a DOE national user facility that has been operating climate observing sites around the world for nearly two decades. These sites help scientists study clouds and their influence on the sun's radiant energy, which heats our planet. Above is one of the purchases: the Vaisala Present Weather Detector. It optically measures visibility, present weather, precipitation intensity, and precipitation type. It provides a measure of current weather conditions by combining measurements from three

303

Atmospheric Pressure Plasma Process And Applications  

SciTech Connect

This paper provides a general discussion of atmospheric-pressure plasma generation, processes, and applications. There are two distinct categories of atmospheric-pressure plasmas: thermal and nonthermal. Thermal atmospheric-pressure plasmas include those produced in high intensity arcs, plasma torches, or in high intensity, high frequency discharges. Although nonthermal plasmas are at room temperatures, they are extremely effective in producing activated species, e.g., free radicals and excited state atoms. Thus, both thermal and nonthermal atmosphericpressure plasmas are finding applications in a wide variety of industrial processes, e.g. waste destruction, material recovery, extractive metallurgy, powder synthesis, and energy conversion. A brief discussion of recent plasma technology research and development activities at the Idaho National Laboratory is included.

Peter C. Kong; Myrtle

2006-09-01T23:59:59.000Z

304

A Community Atmosphere Model with Superparameterized Clouds  

SciTech Connect

In 1999, National Center for Atmospheric Research (NCAR) scientists Wojciech Grabowski and Piotr Smolarkiewicz created a "multiscale" atmospheric model in which the physical processes associated with clouds were represented by running a simple high-resolution model within each grid column of a lowresolution global model. In idealized experiments, they found that the multiscale model produced promising simulations of organized tropical convection, which other models had struggled to produce. Inspired by their results, Colorado State University (CSU) scientists Marat Khairoutdinov and David Randall created a multiscale version of the Community Atmosphere Model (CAM). They removed the cloud parameterizations of the CAM, and replaced them with Khairoutdinov's high-resolution cloud model. They dubbed the embedded cloud model a "super-parameterization," and the modified CAM is now called the "SP-CAM." Over the next several years, many scientists, from many institutions, have explored the ability of the SP-CAM to simulate tropical weather systems, the day-night changes of precipitation, the Asian and African monsoons, and a number of other climate processes. Cristiana Stan of the Center for Ocean-Land-Atmosphere Interactions found that the SP-CAM gives improved results when coupled to an ocean model, and follow-on studies have explored the SP-CAM's utility when used as the atmospheric component of the Community Earth System Model. Much of this research has been performed under the auspices of the Center for Multiscale Modeling of Atmospheric Processes, a National Science Foundation (NSF) Science and Technology Center for which the lead institution is CSU.

Randall, David; Branson, Mark; Wang, Minghuai; Ghan, Steven J.; Craig, Cheryl; Gettelman, A.; Edwards, Jim

2013-06-18T23:59:59.000Z

305

Atmospheric Correction Algorithm for Hyperspectral Imagery  

SciTech Connect

In December 1997, the US Department of Energy (DOE) established a Center of Excellence (Hyperspectral-Multispectral Algorithm Research Center, HyMARC) for promoting the research and development of algorithms to exploit spectral imagery. This center is located at the DOE Remote Sensing Laboratory in Las Vegas, Nevada, and is operated for the DOE by Bechtel Nevada. This paper presents the results to date of a research project begun at the center during 1998 to investigate the correction of hyperspectral data for atmospheric aerosols. Results of a project conducted by the Rochester Institute of Technology to define, implement, and test procedures for absolute calibration and correction of hyperspectral data to absolute units of high spectral resolution imagery will be presented. Hybrid techniques for atmospheric correction using image or spectral scene data coupled through radiative propagation models will be specifically addressed. Results of this effort to analyze HYDICE sensor data will be included. Preliminary results based on studying the performance of standard routines, such as Atmospheric Pre-corrected Differential Absorption and Nonlinear Least Squares Spectral Fit, in retrieving reflectance spectra show overall reflectance retrieval errors of approximately one to two reflectance units in the 0.4- to 2.5-micron-wavelength region (outside of the absorption features). These results are based on HYDICE sensor data collected from the Southern Great Plains Atmospheric Radiation Measurement site during overflights conducted in July of 1997. Results of an upgrade made in the model-based atmospheric correction techniques, which take advantage of updates made to the moderate resolution atmospheric transmittance model (MODTRAN 4.0) software, will also be presented. Data will be shown to demonstrate how the reflectance retrieval in the shorter wavelengths of the blue-green region will be improved because of enhanced modeling of multiple scattering effects.

R. J. Pollina

1999-09-01T23:59:59.000Z

306

Fluxes of methane between landfills and the atmosphere: Natural and engineered controls  

SciTech Connect

Field measurement of landfill methane emissions indicates natural variability spanning more than 2 seven orders of magnitude, from approximately 0.0004 to more than 4000 g m{sub -2} day{sup -1}. This wide range reflects net emissions resulting from production (methanogenesis), consumption (methanotrophic oxidation), and gaseous transport processes. The determination of an {open_quotes}average{close_quotes} emission rate for a given field site requires sampling designs and statistical techniques which consider spatial and temporal variability. Moreover, particularly at sites with pumped gas recovery systems, it is possible for methanotrophic microorganisms in aerated cover soils to oxidize all of the methane from landfill sources below and, additionally, to oxidize methane diffusing into cover soils from atmospheric sources above. In such cases, a reversed soil gas concentration gradient is observed in shallow cover soils, indicating bidirectional diffusional transport to the depth of optimum methane oxidation. Rates of landfill methane oxidation from field and laboratory incubation studies range up to 166 g m{sup -2} day{sup -1} among the highest for any natural setting, providing an effective natural control on net emissions. Estimates of worldwide landfill methane emissions to the atmosphere have ranged from 9 to 70 Tg yr{sup -1}, differing mainly in assumed methane yields from estimated quantities of landfilled refuse. At highly controlled landfill sites in developed countries, landfill methane is often collected via vertical wells or horizontal collectors. Recovery of landfill methane through engineered systems can provide both environmental and energy benefits by mitigating subsurface migration, reducing surface emissions, and providing an alternative energy resource for industrial boiler use, on-site electrical generation, or upgrading to a substitute natural gas.

Bogner, J. [Argonne National Lab., IL (United States); Meadows, M. [ETSU, Harwell, Oxfordshire (United Kingdom); Czepiel, P. [Harvard Univ., Cambridge, MA (United States)

1997-08-01T23:59:59.000Z

307

Dual atmosphere tolerance of Ag-CuO based air braze  

DOE Green Energy (OSTI)

Recently, a new braze filler metal based on the silver-copper oxide system was developed for use in sealing high-temperature, solid-state electrochemical devices such as solid oxide fuel cells. One of the concerns regarding the viability of this joining technique is the long-term stability of silver-based alloys under a high-temperature, dual oxidizing/reducing gas environment. This paper reports on an initial series of exposure experiments that were conducted to characterize the effects of (1) filler metal composition, (2) brazing temperature, and (3) exposure time on the microstructural stability of Ag-CuO brazed Al2O3/Al2O3 joints under a prototypic operating environment for an intermediate temperature solid oxide fuel cell stack. In general joints exposed simultaneously to air on one side and hydrogen on the other for short periods of time at 800°C (100 hrs) showed no signs of degradation with respect to hermeticity or joint microstructure. Samples exposed for longer periods of time (1000 hrs) displayed some internal porosity, which extends approximately halfway across the joint and is not interconnected. Little effect of the filler metal’s composition on its tolerance to dual atmosphere exposure was observed. However brazing temperature was found to have a measurable effect. Higher brazing temperature leads to a more extensive formation of an interfacial reaction phase, copper aluminate, which tends to tie up some of the free CuO in the filler metal and minimize the formation of porosity in the air brazed joints during long-term, dual-atmosphere exposure. The effect is due to the greater chemical stability of the copper aluminate relative to copper oxide.

Kim, Jin Yong Y.; Hardy, John S.; Weil, K. Scott

2007-11-01T23:59:59.000Z

308

Atmospheric Pressure Deposition for Electrochromic Windows  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Pressure Deposition Atmospheric Pressure Deposition for Electrochromic Windows TDM - Karma Sawyer Robert C. Tenent National Renewable Energy Laboratory robert.tenent@nrel.gov 303-384-6775 4/4/2013 Insulating Glass Unit (IGU) Glass Transparent Conductor (TC) Active Electrode Counter Electrode Ion Conductor 2 | Building Technologies Office eere.energy.gov Purpose and Objectives * Expense - Current market price of $50-$100/ft 2 - Projections indicate under $20/ft 2 needed - A new production paradigm is required * Aesthetics - Architects hesitant to adopt "smurf glass"

309

Atmospheric Pressure Deposition for Electrochromic Windows  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Atmospheric Pressure Deposition Atmospheric Pressure Deposition for Electrochromic Windows TDM - Karma Sawyer Robert C. Tenent National Renewable Energy Laboratory robert.tenent@nrel.gov 303-384-6775 4/4/2013 Insulating Glass Unit (IGU) Glass Transparent Conductor (TC) Active Electrode Counter Electrode Ion Conductor 2 | Building Technologies Office eere.energy.gov Purpose and Objectives * Expense - Current market price of $50-$100/ft 2 - Projections indicate under $20/ft 2 needed - A new production paradigm is required * Aesthetics - Architects hesitant to adopt "smurf glass"

310

Barium oxide, calcium oxide, magnesia, and alkali oxide free glass  

DOE Patents (OSTI)

A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

2013-09-24T23:59:59.000Z

311

Multifunctional Oxide Heterostructures  

Science Conference Proceedings (OSTI)

This book is devoted to the rapidly developing field of oxide thin-films and heterostructures. Oxide materials combined with atomic-scale precision in a heterostructure exhibit an abundance of macroscopic physical properties involving the strong coupling between the electronic, spin, and structural degrees of freedom, and the interplay between magnetism, ferroelectricity, and conductivity. Recent advances in thin-film deposition and characterization techniques made possible the experimental realization of such oxide heterostructures, promising novel functionalities and device concepts.

Tsymbal, E Y [University of Nebraska, Lincoln; Dagotto, Elbio R [ORNL; Eom, Professor Chang-Beom [University of Wisconsin, Madison; Ramesh, Ramamoorthy [University of California, Berkeley

2012-01-01T23:59:59.000Z

312

METAL OXIDE NANOPARTICLES  

SciTech Connect

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

313

Defect Structure of Oxides  

Science Conference Proceedings (OSTI)

Table 1   Classification of electrical conductors: oxides, sulfides, and nitrides...2 O 4 , NiAl 2 O 4 , (Tl 2 O),

314

Oxidation of gallium arsenide  

DOE Patents (OSTI)

This invention relates to gallium arsenide semiconductors and, more particularly, to the oxidation of surface layers of gallium arsenide semiconductors for semiconductor device fabrication.

Hoffbauer, M.A.; Cross, J.B.

1991-11-16T23:59:59.000Z

315

Oxidation/Coatings  

Science Conference Proceedings (OSTI)

Oct 28, 2009 ... International Symposium on Ceramic Matrix Composites: Oxidation/ ... on combustor liners of a Solar Turbines' industrial gas turbine engine, ...

316

Atmospheric Gravity Waves and Aircraft Turbulence Encounters  

Science Conference Proceedings (OSTI)

We describe aircraft turbulence-atmospheric gravity wave events which occurred during a 2-day period over the Continental Divide. The waves are observed by two microbarograph networks an each side of the divide and last for several hours at a ...

A. J. Bedard Jr.; F. Canavero; F. Einaudi

1986-12-01T23:59:59.000Z

317

Heat Budget of Tropical Ocean and Atmosphere  

Science Conference Proceedings (OSTI)

Heat budget estimates for the global tropics are derived from recent calculations of the oceanic heat budget and satellite measurements of net radiation at the top of the atmosphere. Annual mean heat export from the zone 30°N–30°S amounts to 101 ...

Stefan Hastenrath

1980-02-01T23:59:59.000Z

318

Temperature stratification of the atmosphere of Arcturus  

E-Print Network (OSTI)

A brief overview of the results of the investigations of the red giant star Arcturus is given. One-dimensional LTE modeling of the atmospheres of Arcturus and the Sun as a star is carried out on the basis of synthesis of the extended wings of the H and K Ca II lines. It is found that the local continuum in this spectral region is underestimated by an average of 12% in the atlases of Arcturus. The average deficit in UV absorption amounts to 43% for Arcturus whereas it is 9% for the Sun. For Arcturus the correction factor to the continuum opacity at the wavelengths of 390.0, 392.5, 395.0, 398.0, and 400.0 nm equals 2.20, 1.90, 1.70, 1.55, and 1.45. The model atmosphere of Arcturus obtained from the best-fit of the wings of the H and K Ca II lines corresponds to the model atmosphere with the fundamental parameters T_eff = 4286 K, log g = 1.66, and [Fe/H]=-0.52 derived by Ramirez and Allende Prieto (2011). The temperature stratification of Arcturus' atmosphere is presented in tabular form. To obtain more accurate...

Sheminova, V A

2013-01-01T23:59:59.000Z

319

Atmospheric Heat Engines on Earth and Mars  

Science Conference Proceedings (OSTI)

The character of the Earth's atmospheric heat engine depends, inter alia, on the relatively tight linkage between surface fluxes of energy and of H20. On Mars, on the other hand, H2O-based latent heat fluxes are only a trivial fraction of total ...

J. R. Philip

1987-06-01T23:59:59.000Z

320

Analysis methods for Atmospheric Cerenkov Telescopes  

E-Print Network (OSTI)

Three different analysis techniques for Atmospheric Imaging System are presented. The classical Hillas parameters based technique is shown to be robust and efficient, but more elaborate techniques can improve the sensitivity of the analysis. A comparison of the different analysis techniques shows that they use different information for gamma-hadron separation, and that it is possible to combine their qualities.

Mathieu de Naurois

2006-07-12T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Profiling Atmospheric Water Vapor by Microwave Radiometry  

Science Conference Proceedings (OSTI)

High-altitude microwave radiometric observations at frequencies near 92 and 183.3 GHz were used to study the potential of retrieving atmospheric water vapor profiles over both land and water. An algorithm based on an extended Kaiman-Bucy filter ...

J. R. Wang; J. L. King; T. T. Wilheit; G. Szejwach; L. H. Gesell; R. A. Nieman; D. S. Niver; B. M. Krupp; J. A. Gagliano

1983-05-01T23:59:59.000Z

322

Baroclinic Modons as Prototypes for Atmospheric Blocking  

Science Conference Proceedings (OSTI)

A two-layer quasi-geostrophic channel model on a ?-plane is used to investigate the properties of dipole eddies which may be relevant models for atmospheric blocking. It is shown that quasi-stationary equivalent barotropic dipole eddies, similar ...

K. Haines

1989-10-01T23:59:59.000Z

323

Accuracy of Atmospheric Energy Budgets from Analyses  

Science Conference Proceedings (OSTI)

Issues relevant to achieving an accuracy of better than 10 W m?2 on 250-km scales for monthly means in the atmospheric energy balance are explored from the standpoint of the formulation and computational procedures using the National Centers for ...

Kevin E. Trenberth; David P. Stepaniak; Julie M. Caron

2002-12-01T23:59:59.000Z

324

The Mathematics of Atmospheric Dispersion Modeling  

Science Conference Proceedings (OSTI)

The Gaussian plume model is a standard approach for studying the transport of airborne contaminants due to turbulent diffusion and advection by the wind. This paper reviews the assumptions underlying the model, its derivation from the advection-diffusion ... Keywords: Gaussian plume solution, advection-diffusion equation, atmospheric dispersion, contaminant transport, inverse problem, linear least squares

John M. Stockie

2011-05-01T23:59:59.000Z

325

Atmosphere Feedbacks during ENSO in a Coupled GCM with a Modified Atmospheric Convection Scheme  

Science Conference Proceedings (OSTI)

The too diverse representation of ENSO in a coupled GCM limits one’s ability to describe future change of its properties. Several studies pointed to the key role of atmosphere feedbacks in contributing to this diversity. These feedbacks are ...

Eric Guilyardi; Pascale Braconnot; Fei-Fei Jin; Seon Tae Kim; Michel Kolasinski; Tim Li; Ionela Musat

2009-11-01T23:59:59.000Z

326

Atmospheric Energetics in the Wavelet Domain. Part II: Time-Averaged Observed Atmospheric Blocking  

Science Conference Proceedings (OSTI)

Wavelet energetics (WE) is a useful generalization of traditional wavenumber energetics, for analyzing atmospheric dynamics. WE is doubly indexed by wavenumber band j and location k. The interpretation is that 2 to the jth power is proportional ...

Aimé Fournier

2003-01-01T23:59:59.000Z

327

Characteristics of Atmospheric Transport Using Three Numerical Formulations for Atmospheric Dynamics in a Single GCM Framework  

Science Conference Proceedings (OSTI)

This study examines the sensitivity of a number of important archetypical tracer problems to the numerical method used to solve the equations of tracer transport and atmospheric dynamics. The tracers' scenarios were constructed to exercise the ...

Philip J. Rasch; Danielle B. Coleman; Natalie Mahowald; David L. Williamson; Shian-Jiann Lin; Byron A. Boville; Peter Hess

2006-06-01T23:59:59.000Z

328

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

1988-01-01T23:59:59.000Z

329

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Nyaiesh, A.R.; Garwin, E.L.

1986-08-04T23:59:59.000Z

330

Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, and nitrogen in the gas phase; comparison of gas generation rates in supernate and solid fractions of Tank 241-SY-101 simulated waste  

DOE Green Energy (OSTI)

This report summarizes progress made in evaluating me by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using simulated waste mixtures. Work described in this report. was conducted at Pacific Northwest Laboratory (PNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT), under subcontract to PNL, using simulated wastes, and to studies being performed at VMC using actual wastes.

Bryan, S.A.; Pederson, L.R.

1995-03-01T23:59:59.000Z

331

Oxidative Degradation of Monoethanolamine  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

332

Land–Atmosphere Coupling Strength in the Global Forecast System  

Science Conference Proceedings (OSTI)

The operational coupled land–atmosphere forecast model from the National Centers for Environmental Prediction (NCEP) is evaluated for the strength and characteristics of its coupling in the water cycle between land and atmosphere. Following the ...

Li Zhang; Paul A. Dirmeyer; Jiangfeng Wei; Zhichang Guo; Cheng-Hsuan Lu

2011-02-01T23:59:59.000Z

333

Atmospheric Response to the Gulf Stream: Seasonal Variations  

Science Conference Proceedings (OSTI)

The atmospheric response to the Gulf Stream front in sea surface temperature is investigated using high-resolution data from satellite observations and operational analysis and forecast. Two types of atmospheric response are observed with ...

Shoshiro Minobe; Masato Miyashita; Akira Kuwano-Yoshida; Hiroki Tokinaga; Shang-Ping Xie

2010-07-01T23:59:59.000Z

334

Adaptive Multilevel Modeling of Land-Atmosphere Interactions  

Science Conference Proceedings (OSTI)

Adaptive multilevel methods allow full coupling of atmospheric and land surface hydrological models by preserving consistency between the large-scale (atmospheric) and the regional (land) components. The methodology was investigated for three ...

Ana Paula Barros

1995-09-01T23:59:59.000Z

335

ARM - Field Campaign - Tropical Ocean Global Atmosphere Coupled  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsTropical Ocean Global Atmosphere Coupled Ocean-Atmosphere govCampaignsTropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Exp Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Exp 1992.07.11 - 1993.02.28 Lead Scientist : Chuck Long Data Availability Final data available. For data sets, see below. Summary IOP completed. Description The Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA-COARE) was conducted to better understand the structure of the coupled system of the warm pool of the western Pacific Ocean. Hundreds of participants from dozens of countries took part in this experiment from November 1, 1992 through February 28, 1993. Campaign Data Sets

336

A Simulated Climatology of Spectrally Decomposed Atmospheric Infrared Radiation  

Science Conference Proceedings (OSTI)

A simulation experiment is conducted to inquire into the mean climate state and likely trends in atmospheric infrared radiation spectra. Upwelling and downwelling spectra at five vertical levels from the surface to the top of the atmosphere (TOA) ...

Yi Huang

2013-03-01T23:59:59.000Z

337

Hadley Cell Dynamics in a Virtually Dry Snowball Earth Atmosphere  

Science Conference Proceedings (OSTI)

The Hadley cell of a virtually dry snowball Earth atmosphere under equinox insolation is studied in a comprehensive atmospheric general circulation model. In contrast to the Hadley cell of modern Earth, momentum transport by dry convection, which ...

Aiko Voigt; Isaac M. Held; Jochem Marotzke

2012-01-01T23:59:59.000Z

338

Evolution Dynamics of Tropical Ocean-Atmosphere Annual Cycle Variability  

Science Conference Proceedings (OSTI)

The structure of ocean-atmosphere annual cycle variability is extracted from the revised Comprehensive Ocean-Atmosphere Data Set SSTs, surface winds, and the latent heat (LH) and net shortwave (SW) surface fluxes using the covariance-based ...

Sumant Nigam; Yi Chao

1996-12-01T23:59:59.000Z

339

A Thermodynamic Foundation for Modeling the Moist Atmosphere  

Science Conference Proceedings (OSTI)

With advances in numerical modeling of the atmosphere, we have experienced that the return to the first principles of physics often enables a model to cope more easily with the complexities of the real atmosphere. The return to the primitive ...

Katsuyuki V. Ooyama

1990-11-01T23:59:59.000Z

340

Systematic Metastable Atmospheric Regime Identification in an AGCM  

Science Conference Proceedings (OSTI)

In this study the authors apply a recently developed clustering method for the systematic identification of metastable atmospheric regimes in high-dimensional datasets generated by atmospheric models. The novelty of this approach is that it ...

Christian Franzke; Illia Horenko; Andrew J. Majda; Rupert Klein

2009-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Time–Space Distribution of Long-Range Atmospheric Predictability  

Science Conference Proceedings (OSTI)

The global three-dimensional structure of long-range (one month to one season) atmospheric predictability was investigated with a general circulation model. The main focus was to ascertain the role of atmospheric initial conditions for such ...

Thomas Reichler; John O. Roads

2004-02-01T23:59:59.000Z

342

On the Sources of Methane to the Los Angeles Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

On the Sources of Methane to the Los Angeles Atmosphere Title On the Sources of Methane to the Los Angeles Atmosphere Publication Type Journal Article Year of Publication 2012...

343

The Dry-Entropy Budget of a Moist Atmosphere  

Science Conference Proceedings (OSTI)

The entropy budget has been a popular starting point for theories of the work, or dissipation, performed by moist atmospheres. For a dry atmosphere, the entropy budget provides a theory for the dissipation in terms of the imposed diabatic heat ...

David M. Romps

2008-12-01T23:59:59.000Z

344

TOGA COARE: The Coupled Ocean—Atmosphere Response Experiment  

Science Conference Proceedings (OSTI)

Despite significant progress in the Tropical Ocean—Global Atmosphere (TOGA) program, a number of major hurdles remain before the primary objective, prediction of the variability of the coupled ocean—atmosphere system on time scales of months to ...

Peter J. Webster; Roger Lukas

1992-09-01T23:59:59.000Z

345

Predictability Associated with Nonlinear Regimes in an Atmospheric Model  

Science Conference Proceedings (OSTI)

Atmospheric regimes are midlatitude flow patterns that persist for periods of time exceeding a few days. Here, the authors analyzed the output of an idealized atmospheric model (QG3) to examine the relationship between regimes and predictability.

John M. Peters; Sergey Kravtsov; Nicholas T. Schwartz

2012-03-01T23:59:59.000Z

346

Acoustic Tomographic Monitoring of the Atmospheric Surface Layer  

Science Conference Proceedings (OSTI)

Acoustic tomography is proposed as a method for monitoring near-surface atmospheric temperature and wind velocity fields. Basic issues relating to the feasibility and implementation of atmospheric tomography are discussed. Among these issues are ...

D. Keith Wilson; Dennis W. Thomson

1994-06-01T23:59:59.000Z

347

Destabilization of the Thermohaline Circulation by Atmospheric Eddy Transports  

Science Conference Proceedings (OSTI)

Simple proem models have been developed to investigate the role of atmosphere-ocean feedbacks in the stability of the current mode of the thermohaline circulation in the North Atlantic. A positive feedback between the meridional atmospheric ...

Mototaka Nakamura; Peter H. Stone; Jochem Marotzke

1994-12-01T23:59:59.000Z

348

Estimates of Meridional Atmosphere and Ocean Heat Transports  

Science Conference Proceedings (OSTI)

New estimates of the poleward energy transport based on atmospheric reanalyses from the National Centers for Environmental Prediction–National Center for Atmospheric Research (NCEP–NCAR) and the European Centre for Medium-Range Weather Forecasts ...

Kevin E. Trenberth; Julie M. Caron

2001-08-01T23:59:59.000Z

349

Structure of the Atmosphere in Radiative–Convective Equilibrium  

Science Conference Proceedings (OSTI)

To investigate water vapor transport in an atmosphere in radiative–convective equilibrium, a simplified dynamical convection model (DCM) was constructed that explicitly models moist convection and longwave radiation in a gray atmosphere. In the ...

Yoshiharu Iwasa; Yutaka Abe; Hiroshi Tanaka

2002-07-01T23:59:59.000Z

350

Interannual Variability of Land-Atmosphere Coupling Strength  

Science Conference Proceedings (OSTI)

Recent studies in the Global Land-Atmosphere Coupling Experiment (GLACE) established a framework to estimate the extent to which anomalies in the land surface state (e.g., soil moisture) can affect rainfall generation and other atmospheric ...

Zhichang Guo; Paul A. Dirmeyer

351

Atmospheric Solar Heating Rate in the Water Vapor Bands  

Science Conference Proceedings (OSTI)

The total absorption of solar radiation by water vapor in clear atmosphere is parameterized as a simple function of the scaled water vapor amount. For applications to cloudy and hazy atmospheres, the flux-weighted k-distribution functions are ...

Ming-Dah Chou

1986-11-01T23:59:59.000Z

352

Atmospheric Icing Climatologies of Two New England Mountains  

Science Conference Proceedings (OSTI)

The atmospheric icing climatologies of two New England mountaintops with different elevations are compared: Mount Mansfield in northern Vermont and Mount Washington in New Hampshire. Atmospheric icing, as measured with Rosemount ice detectors, is ...

Charles C. Ryerson

1988-11-01T23:59:59.000Z

353

Estimating Intensity of Atmospheric Ice Accretion on Stationary Structures  

Science Conference Proceedings (OSTI)

The role of various atmospheric parameters in determining atmospheric ice accretion intensity on structures near the ground is examined theoretically, with an emphasis on glaze formation. Methods are presented for calculating the icing rate on ...

Lasse Makkonen

1981-05-01T23:59:59.000Z

354

Direct Atmospheric Forcing of Geostrophic Eddies. Part II: Coherence Maps  

Science Conference Proceedings (OSTI)

The theory of stochastic atmospheric forcing of quasigeostrophic eddies is applied to calculate coherence maps, that is, the coherence between the oceanic response at one location and the atmospheric forcing at another location as a function of ...

Angelika Lippert; Peter Müller

1995-01-01T23:59:59.000Z

355

Variational Objective Analysis for Atmospheric Field Programs: A Model Assessment  

Science Conference Proceedings (OSTI)

The objective of this study is to examine the effectiveness of the variational objective analysis (VOA) for producing realistic diagnoses of atmospheric field program data. Simulations from the Naval Research Laboratory's Coupled Ocean/Atmosphere ...

D. E. Waliser; J. A. Ridout; S. Xie; M. Zhang

2002-12-01T23:59:59.000Z

356

Coupled Atmosphere–Biophysics–Hydrology Models for Environmental Modeling  

Science Conference Proceedings (OSTI)

The formulation and implementation of LEAF-2, the Land Ecosystem–Atmosphere Feedback model, which comprises the representation of land–surface processes in the Regional Atmospheric Modeling System (RAMS), is described. LEAF-2 is a prognostic ...

Robert L. Walko; Larry E. Band; Jill Baron; Timothy G. F. Kittel; Richard Lammers; Tsengdar J. Lee; Dennis Ojima; Roger A. Pielke Sr.; Chris Taylor; Christina Tague; Craig J. Tremback; Pier Luigi Vidale

2000-06-01T23:59:59.000Z

357

Implications of the Hydrostatic Assumption on Atmospheric Gravity Waves  

Science Conference Proceedings (OSTI)

The validity of the hydrostatic approximation is examined for use in predicting the dynamics of topographically generated atmospheric gravity waves (lee waves) propagating in an atmosphere with realistic wind shear. To isolate nonhydrostatic ...

Teddie L. Keller

1994-07-01T23:59:59.000Z

358

Atmospheric Emitted Radiance Interferometer. Part I: Instrument Design  

Science Conference Proceedings (OSTI)

A ground-based Fourier transform spectrometer has been developed to measure the atmospheric downwelling infrared radiance spectrum at the earth's surface with high absolute accuracy. The Atmospheric Emitted Radiance Interferometer (AERI) ...

R. O. Knuteson; H. E. Revercomb; F. A. Best; N. C. Ciganovich; R. G. Dedecker; T. P. Dirkx; S. C. Ellington; W. F. Feltz; R. K. Garcia; H. B. Howell; W. L. Smith; J. F. Short; D. C. Tobin

2004-12-01T23:59:59.000Z

359

COLLOQUIUM: The Alfvénic Motions of the Sun's Outer Atmosphere...  

NLE Websites -- All DOE Office Websites (Extended Search)

8, 2013, 4:15pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: The Alfvnic Motions of the Sun's Outer Atmosphere Scott McIntosh National Center for Atmospheric Research (NCAR)...

360

Accuracy of Atmospheric Angular Momentum Estimates from Operational Analyses  

Science Conference Proceedings (OSTI)

Modern, high resolution atmospheric and geodetic data are finding increasing use in geophysical studies of the angular momentum balance of the earth-atmosphere system. Such studies require knowledge of the level of uncertainty associated with ...

Richard D. Rosen; Dayid A. Salstein; Alvin J. Miller; Klaus Arpe

1987-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Multiscale Low-Frequency Circulation Modes in the Global Atmosphere  

Science Conference Proceedings (OSTI)

In this paper, fundamental multiscale circulation modes in the global atmosphere are identified with the objective of providing better understanding of atmospheric low-frequency variabilities over a wide range of spatial and temporal scales. With ...

K-M. Lau; P-J. Sheu; I-S. Kang

1994-05-01T23:59:59.000Z

362

Global Thermohaline Circulation. Part II: Sensitivity with Interactive Atmospheric Transports  

Science Conference Proceedings (OSTI)

A hybrid coupled ocean–atmosphere model is used to investigate the stability of the thermohaline circulation (THC) to an increase in the surface freshwater forcing in the presence of interactive meridional transports in the atmosphere. The ocean ...

Xiaoli Wang; Peter H. Stone; Jochem Marotzke

1999-01-01T23:59:59.000Z

363

Atmospheric Crude Oil Distillation Operable Capacity  

Gasoline and Diesel Fuel Update (EIA)

(Barrels per Calendar Day) (Barrels per Calendar Day) Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge Capacity (B/SD) Thermal Cracking Downstream Charge Capacity (B/SD) Thermal Cracking Total Coking Downstream Charge Capacity (B/SD) Thermal Cracking Delayed Coking Downstream Charge Capacity (B/SD Thermal Cracking Fluid Coking Downstream Charge Capacity (B/SD) Thermal Cracking Visbreaking Downstream Charge Capacity (B/SD) Thermal Cracking Other/Gas Oil Charge Capacity (B/SD) Catalytic Cracking Fresh Feed Charge Capacity (B/SD) Catalytic Cracking Recycle Charge Capacity (B/SD) Catalytic Hydro-Cracking Charge Capacity (B/SD) Catalytic Hydro-Cracking Distillate Charge Capacity (B/SD) Catalytic Hydro-Cracking Gas Oil Charge Capacity (B/SD) Catalytic Hydro-Cracking Residual Charge Capacity (B/SD) Catalytic Reforming Charge Capacity (B/SD) Catalytic Reforming Low Pressure Charge Capacity (B/SD) Catalytic Reforming High Pressure Charge Capacity (B/SD) Catalytic Hydrotreating/Desulfurization Charge Capacity (B/SD) Catalytic Hydrotreating Naphtha/Reformer Feed Charge Cap (B/SD) Catalytic Hydrotreating Gasoline Charge Capacity (B/SD) Catalytic Hydrotreating Heavy Gas Oil Charge Capacity (B/SD) Catalytic Hydrotreating Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Kerosene/Jet Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Diesel Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Other Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Residual/Other Charge Capacity (B/SD) Catalytic Hydrotreating Residual Charge Capacity (B/SD) Catalytic Hydrotreating Other Oils Charge Capacity (B/SD) Fuels Solvent Deasphalting Charge Capacity (B/SD) Catalytic Reforming Downstream Charge Capacity (B/CD) Total Coking Downstream Charge Capacity (B/CD) Catalytic Cracking Fresh Feed Downstream Charge Capacity (B/CD) Catalytic Hydro-Cracking Downstream Charge Capacity (B/CD) Period:

364

Chemistry of atmospheric aerosol particles and their resulting warm cloud-nucleation properties  

E-Print Network (OSTI)

CCN activation, Atmospheric Chemistry and Physics, 10, 5241-precipitation, Atmospheric Chemistry and Physics, 9, 3223-particles. Atmospheric Chemistry and Physics, 2009, 9, A. P.

Moore, Meagan Julia Kerry

2011-01-01T23:59:59.000Z

365

DETERMINATION OF CARBON IN ATMOSPHERIC AEROSOLS BY DEUTERON-INDUCED NUCLEAR REACTIONS  

E-Print Network (OSTI)

deuteron irradiation of an atmospheric aerosol sample.CARBON IN ATMOSPHERIC AEROSOLS BY DEUTERON-INDUCED NUCLEARCARBON IN ATMOSPHERIC AEROSOLS BY DEUTERON-INDUCED NUCLEAR

Clemenson, Mark

2013-01-01T23:59:59.000Z

366

ATMOSPHERIC AEROSOL RESEARCH FY-1979, CHAPTER IN THE ENERGY AND ENVIRONMENT ANNUAL REPORT, 1979  

E-Print Network (OSTI)

California atmospheric aerosols," Environ. Sci. Technol. ll•suspensions," in Atmospheric Aerosol Research Annual Report,formation," in Atmospheric Aerosol Research Annual Report,

Authors, Various

2013-01-01T23:59:59.000Z

367

Transient phenomena in the solar atmosphere and solar wind  

SciTech Connect

Observations of transient disturbances in the solar atmosphere are reviewed with emphasis on coronal mass ejection events. (JFP)

Gosling, J.T.

1976-01-01T23:59:59.000Z

368

Table 5. Refiners' Total Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

CORPORATION / Refiner / Location Table 5. Refiners' Total Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 2011 Calendar Day

369

Table 5. Refiners' Total Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

CORPORATION / Refiner / Location Table 5. Refiners' Total Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 2009 Calendar Day

370

Year/PAD District Distillation Crude Oil Atmospheric Distillation  

U.S. Energy Information Administration (EIA) Indexed Site

Distillation Crude Oil Atmospheric Distillation Vacuum Cracking Thermal Catalytic Cracking Fresh Recycled Catalytic Hydro- Cracking Catalytic Reforming Desulfurization...

371

Formation of Hydrogen Cottrell Atmosphere in Palladium: Theory ...  

Science Conference Proceedings (OSTI)

Symposium, Hydrogen Storage in Materials: Theory and Experiment. Presentation Title, Formation of Hydrogen Cottrell Atmosphere in Palladium: Theory and ...

372

Formation mechanisms and quantification of organic nitrates in atmospheric aerosol  

E-Print Network (OSTI)

Atmospheric submicron aerosol . . . . . . . 2.3 Partitioningon SOA organic aerosol formation alkyl nitrate and secondaryPeroxy radical fate . . . . . . Aerosol . . . . . . . .

Rollins, Andrew Waite

2010-01-01T23:59:59.000Z

373

East Coast (PADD 1) Refinery Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

East Coast (PADD 1) Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

374

West Coast (PADD 5) Refinery Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

West Coast (PADD 5) Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

375

Puerto Rico Refinery Operable Atmospheric Crude Oil Distillation ...  

U.S. Energy Information Administration (EIA)

Puerto Rico Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

376

Rocky Mountain (PADD 4) Refinery Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

Rocky Mountain (PADD 4) Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

377

Gulf Coast (PADD 3) Refinery Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

Gulf Coast (PADD 3) Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

378

U.S. Refinery Operating Atmospheric Crude Oil Distillation ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Operating Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

379

U.S. Refinery Operable Atmospheric Crude Oil Distillation Capacity ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Calendar Day)

380

U.S. Refinery Operable Atmospheric Crude Oil Distillation Capacity ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Operable Atmospheric Crude Oil Distillation Capacity as of January 1 (Barrels per Stream Day)

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

The Seasonal Cycle of Atmospheric Heating and Temperature  

Science Conference Proceedings (OSTI)

The seasonal cycle of the heating of the atmosphere is divided into a component due to direct solar absorption in the atmosphere and a component due to the flux of energy from the surface to the atmosphere via latent, sensible, and radiative heat ...

Aaron Donohoe; David S. Battisti

2013-07-01T23:59:59.000Z

382

Improving the performance scalability of the community atmosphere model  

Science Conference Proceedings (OSTI)

The Community Atmosphere Model (CAM), which serves as the atmosphere component of the Community Climate System Model (CCSM), is the most computationally expensive CCSM component in typical configurations. On current and next-generation leadership class ... Keywords: CAM, atmospheric modeling, massively parallel computing, performance, scalability

Arthur A. Mirin; Patrick H. Worley

2012-02-01T23:59:59.000Z

383

Development of a 3D atmospheric radiative transfer model  

Science Conference Proceedings (OSTI)

The 3D atmospheric radiative transfer model is established based on MODTRAN4. Moreover, the methods of calculating the ratio of atmospheric transmission, path radiation and single scattering solar radiation are presented. This 3D model is running by ... Keywords: MODTRAN4, atmospheric radiative transfer model, infrared radiation

Zhifeng Lu; Ge Li; Gang Guo; Kedi Huang

2008-05-01T23:59:59.000Z

384

Foliar lead uptake by lettuce exposed to atmospheric fallouts  

E-Print Network (OSTI)

1 Foliar lead uptake by lettuce exposed to atmospheric fallouts Gaëlle Uzu, Sophie Sobanska of foliar uptake of lead by lettuce (lactuca sativa) exposed to the atmospheric fallouts of a lead Pb-rich fallouts are studied. INTRODUCTION Particles emitted in the atmosphere present a large

Paris-Sud XI, Université de

385

Foliar Lead Uptake by Lettuce Exposed to Atmospheric Fallouts  

E-Print Network (OSTI)

Foliar Lead Uptake by Lettuce Exposed to Atmospheric Fallouts G A ¨E L L E U Z U , S O P H I E S O) exposed to the atmospheric fallouts of a lead-recycling plant were studied. After43daysofexposure area, they can strongly impact the biosphere (7, 8). At the global scale, fallouts of atmospheric PM

Mailhes, Corinne

386

ORISE: Capabilities in Climate and Atmospheric Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Capabilities Capabilities ORISE partners with NOAA to operate climate monitoring network U.S. Climate Reference Network (CRN) station in Hawaii The U.S. Climate Reference Network (CRN) consists of 121 stations throughout the continental U.S., Alaska, Hawaii and Canada. The stations use highly accurate and reliable sensors and gauges to measure temperature, wind speed and precipitation. The network allows scientists to study the climate of an area over sustained periods, from 50 to 100 years. Pictured here is a CRN station at the Mauna Loa Slope Observatory in Hawaii. The Oak Ridge Institute for Science and Education (ORISE) works closely with the National Oceanic and Atmospheric Administration's (NOAA) Atmospheric Turbulence and Diffusion Division (ATDD) to perform lower

387

Atmospheric Dispersion Modeling in Safety Analyses; GENII  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Workshop to Discuss Issues Regarding Deposition Workshop to Discuss Issues Regarding Deposition Velocity June 5-6, 2012 Jeremy Rishel Bruce Napier Atmospheric Dispersion Modeling in Safety Analyses: GENII Today's Presentation.... Will provide a high-level overview of the GENII codes. Will cover basic aspects of GENII's acute atmospheric transport model. Will review the GENII deposition model that is used to estimate the deposition velocity used in plume depletion. 2 GENII Development History 1988 - GENII V1 released ICRP-26/30/48 dosimetry 1990 - GENII V1.485 stabilized Current DOE Toolbox Version 1992 - GENII-S stochastic version 2004 - GENII V2 ICRP-72 age-dependent dosimetry Federal Guidance Report 13 risk factors

388

Science DMZ National Oceanic and Atmospheric Administration  

NLE Websites -- All DOE Office Websites (Extended Search)

NOAA NOAA About ESnet Overview ESnet Staff Governance Our Network Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ CU Science DMZ Penn State & VTTI Science DMZ NOAA Science DMZ NERSC Science DMZ ALS Multi-facility Workflow LCLS ESnet Strategic Plan ESnet Organizational Chart ESnet History Science Requirements Careers Contact Us Technical Assistance: 1 800-33-ESnet (Inside the US) 1 800-333-7638 (Inside the US) 1 510-486-7600 (Globally) 1 510-486-7607 (Globally) Report Network Problems: trouble@es.net Provide Web Site Feedback: info@es.net Science DMZ National Oceanic and Atmospheric Administration The National Oceanic and Atmospheric Administration (NOAA) in Boulder houses the Earth System Research Lab, which supports a "reforecasting" project. The initiative involves running several decades of historical

389

Atmospheric Measurements of Climate-Relevant Species  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Measurements of Climate-Relevant Species Atmospheric Measurements of Climate-Relevant Species CDIAC's data collection includes measurements of the following climate-relevant chemical species. A summary of recent greenhouse gas concentrations is also available. To determine how compounds are named, see the CDIAC "Name that compound" page. Butane (C4H10) Carbon Dioxide (CO2) Carbon Isotopes Carbon Monoxide (CO) Carbon Tetrachloride (CCl4) Chlorofluorocarbons Chloroform (CHCl3) Deuterium (2H) Ethane (C2H6) Ethyl Nitrate (C2H5ONO2) Ethyne (C2H2) Fluoroform (CHF3) Halogenated Compounds (modern records) Halons (fluorocarbons) Hydrogen (H2) Hydrochlorofluorocarbons (HCFCs) Hydrofluorocarbons (HFCs) i-Propyl Nitrate (C3H7ONO2) Methane (CH4) Methyl Bromide (CH3Br) Methyl Chloride (CH3Cl) Methyl Chloroform (CH3CCl3)

390

Performance of the STACEE Atmospheric Cherenkov Telescope  

E-Print Network (OSTI)

The Solar Tower Atmospheric Cherenkov Effect Experiment (STACEE) is located at the National Solar Thermal Test Facility of Sandia National Laboratories in Albuquerque, New Mexico, USA. The field of solar tracking mirrors (heliostats) around a central receiver tower is used to direct Cherenkov light from atmospheric showers onto secondary mirrors on the tower, which in turn image the light onto cameras of photomultiplier tubes. The STACEE Collaboration has previously reported a detection of the Crab Nebula with approximately 7 standard deviation significance, using 32 heliostats (STACEE-32). This result demonstrates both the viability of the technique and the suitability of the site. We are in the process of completing an upgrade to 48 heliostats (STACEE-48) en route to an eventual configuration using 64 heliostats (STACEE-64) in early 2001. In this paper, we summarize the results obtained on the sensitivity of STACEE-32 and our expectations for STACEE-48 and STACEE-64.

STACEE Collaboration; D. A. Williams; D. Bhattacharya; L. M. Boone; M. C. Chantell; Z. Conner; C. E. Covault; M. Dragovan; P. Fortin; D. Gingrich; D. T. Gregorich; D. S. Hanna; G. Mohanty; R. Mukherjee; R. A. Ong; S. Oser; K. Ragan; R. A. Scalzo; D. R. Schuette; C. G. Theoret; T. O. Tumer; F. Vincent; J. A. Zweerink

2000-10-17T23:59:59.000Z

391

Pacific Northwest Laboratory annual report for 1992 to the DOE Office of Energy Research. Part 3, Atmospheric and climate research  

Science Conference Proceedings (OSTI)

Within the US Department of Energy`s (DOE`s) Office of Health and Environmental Research (OHER), the atmospheric sciences and carbon dioxide research programs are part of the Environmental Sciences Division (ESD). One of the central missions of the division is to provide the DOE with scientifically defensible information on the local, regional, and global distributions of energy-related pollutants and their effects on climate. This information is vital to the definition and implementation of a sound national energy strategy. This volume reports on the progress and status of all OHER atmospheric science and climate research projects at the Pacific Northwest Laboratory (PNL). PNL has had a long history of technical leadership in the atmospheric sciences research programs within OHER. Within the ESD, the Atmospheric Chemistry Program (ACP) continues DOE`s long-term commitment to study the continental and oceanic fates of energy-related air pollutants. Research through direct measurement, numerical modeling, and laboratory studies in the ACP emphasizes the long-range transport, chemical transformation, and removal of emitted pollutants, oxidant species, nitrogen-reservoir species, and aerosols. The Atmospheric Studies in Complex Terrain (ASCOT) program continues to apply basic research on density-driven circulations and on turbulent mixing and dispersion in the atmospheric boundary layer to the micro- to mesoscale meteorological processes that affect air-surface exchange and to emergency preparedness at DOE and other facilities. Research at PNL provides basic scientific underpinnings to DOE`s program of global climate research. Research projects within the core carbon dioxide and ocean research programs are now integrated with those in the Atmospheric Radiation Measurements (ARM), the Computer Hardware, Advanced Mathematics and Model Physics (CHAMMP), and Quantitative Links programs to form DOE`s contribution to the US Global Change Research Program.

Schrempf, R.E. [ed.

1993-04-01T23:59:59.000Z

392

Coastal Atmospheric Circulation around an Idealized Cape during Wind-Driven Upwelling Studied from a Coupled Ocean–Atmosphere Model  

Science Conference Proceedings (OSTI)

The study analyzes atmospheric circulation around an idealized coastal cape during summertime upwelling-favorable wind conditions simulated by a mesoscale coupled ocean–atmosphere model. The domain resembles an eastern ocean boundary with a ...

Natalie Perlin; Eric D. Skyllingstad; Roger M. Samelson

2011-03-01T23:59:59.000Z

393

Response of a Coupled Ocean–Atmosphere Model to Increasing Atmospheric Carbon Dioxide: Sensitivity to the Rate of Increase  

Science Conference Proceedings (OSTI)

The influence of differing rates of increase of the atmospheric CO2 concentration on the climatic response is investigated using a coupled ocean–atmosphere model. Five transient integrations are performed each using a different constant ...

Ronald J. Stouffer; Syukuro Manabe

1999-08-01T23:59:59.000Z

394

Multiple-Century Response of a Coupled Ocean-Atmosphere Model to an Increase of Atmospheric Carbon Dioxide  

Science Conference Proceedings (OSTI)

To speculate on the future change of climate over several centuries, three 500-year integrations of a coupled ocean-atmosphere model were performed. In addition to the standard integration in which the atmospheric concentration of carbon dioxide ...

Syukuro Manabe; Ronald J. Stouffer

1994-01-01T23:59:59.000Z

395

Near-Continuous Profiling of Temperature, Moisture, and Atmospheric Stability Using the Atmospheric Emitted Radiance Interferometer (AERI)  

Science Conference Proceedings (OSTI)

The Department of Energy Atmospheric Radiation Measurement Program (ARM) has funded the development and installation of five ground-based atmospheric emitted radiance interferometer (AERI) systems at the Southern Great Plains (SGP) site. The ...

W. F. Feltz; W. L. Smith; H. B. Howell; R. O. Knuteson; H. Woolf; H. E. Revercomb

2003-05-01T23:59:59.000Z

396

High-Resolution Atmospheric Sensing of Multiple Atmospheric Variables Using the DataHawk Small Airborne Measurement System  

Science Conference Proceedings (OSTI)

The DataHawk small airborne measurement system provides in situ atmospheric measurement capabilities for documenting scales as small as 1 m and can access reasonably large volumes in and above the atmospheric boundary layer at low cost. The design ...

Dale A. Lawrence; Ben B. Balsley

2013-10-01T23:59:59.000Z

397

Central U.S. Atmospheric Water and Energy Budgets Adjusted for Diurnal Sampling Biases Using Top-of-Atmosphere Radiation  

Science Conference Proceedings (OSTI)

The water and energy budgets of the atmospheric column over the Mississippi River basin are estimated using 18 yr (1976–93) of twice-daily radiosonde observations, top-of-atmosphere net radiation estimates from the Earth Radiation Budget ...

Hideki Kanamaru; Guido D. Salvucci; Dara Entekhabi

2004-06-01T23:59:59.000Z

398

Nucleation and Growth of Atmospheric Particles  

SciTech Connect

New particle formation (NPF) in the atmospheric is a two-step process: Nucleation leads to the birth of stable nuclei that subsequently grow to sizes that can be detected and affect the atmosphere’s radiative properties. Our group is studying both of these processes. Our nucleation research is largely supported by NSF and involves measurements of neutral molecular clusters formed by nucleation with a new custom-designed mass spectrometer (the Cluster-CIMS) and measurements of nanoparticle size distributions as small as 1 nm with a new aerosol spectrometer (the DEG SMPS). These measurements are providing new insights into aspects of cluster behavior that affect nucleation rates. The U.S. DOE supports our research on nanoparticle growth rates. This research couples physical and chemical measurements of aerosol properties and behavior. The TDCIMS, which enables real-time measurements of composition for freshly nucleated particles as small as 8 nm and was developed with support from DOE, is the most important tool in this work. Our most important discoveries about processes that affect growth rates are summarized in a recent PNAS article (doi:10.1073/pnas.0912127107). In short, this work has shown that alkylammonium-carboxylate salts, formed, for example, by reactions between amines and carboxylic acids, account for 20–50% of the mass of freshly nucleated particles in locations that include Atlanta, Mexico City, Boulder, and Hyytiälä, while sulfates account for only about 10%. These newly discovered compounds help to explain the high growth rates of freshly nucleated particles that have been observed around the globe and help to explain why nucleation is an important atmospheric process, not just a scientific curiosity. Our poster will provide an overview of this work.

McMurry, P.; Kuang, C.; Barsanti, K.; Eisele, F.; Friedli, H.; Scheckman, J.; Titcombe, M.; Williams, B.; Zhao, J.; Smith, J.

2010-03-15T23:59:59.000Z

399

Extraction of Freshwater and Energy from Atmosphere  

E-Print Network (OSTI)

Author offers and researches a new, cheap method for the extraction of freshwater from the Earth atmosphere. The suggected method is fundamentally dictinct from all existing methods that extract freshwater from air. All other industrial methods extract water from a saline water source (in most cases from seawater). This new method may be used at any point in the Earth except Polar Zones. It does not require long-distance freshwater transportation. If seawater is not utilized for increasing its productivity, this inexpensive new method is very environment-friendly. The author method has two working versions: (1) the first variant the warm (hot) atmospheric air is lifted by the inflatable tube in a high altitude and atmospheric steam is condenced into freswater: (2) in the second version, the warm air is pumped 20-30 meters under the sea-surface. In the first version, wind and solar heating of air are used for causing air flow. In version (2) wind and propeller are used for causing air movment. The first method does not need energy, the second needs a small amount. Moreover, in variant (1) the freshwater has a high pressure (>30 or more atm.) and can be used for production of energy such as electricity and in that way the freshwater cost is lower. For increasing the productivity the seawater is injected into air and solar air heater may be used. The solar air heater produces a huge amount of electricity as a very powerful electricity generation plant. The offered electricity installation in 100 - 200 times cheaper than any common electric plant of equivalent output. Key words: Extraction freshwater, method of getting freshwater, receiving energy from atmosphere, powerful renewal electric plant.

Alexander Bolonkin

2007-04-19T23:59:59.000Z

400

Pulsed atmospheric fluidized bed combustor apparatus  

DOE Patents (OSTI)

A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

Mansour, Momtaz N. (Columbia, MD)

1993-10-26T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

INO as atmospheric and magic baseline detector  

Science Conference Proceedings (OSTI)

We present a status report on the proposed India?based Neutrino Observatory (INO). We focus on the physics studies possible with an iron calorimeter detector (ICAL) at INO. Such a detector would make precision measurements of neutrino oscillation parameters with atmospheric neutrinos in the first phase with the possibility of acting as a far?end detector of a future neutrino factory or beta beam. This talk was given at the 12th International Workshop on Neutrino Factories

D. Indumathi; The INO Collaboration

2011-01-01T23:59:59.000Z

402

Total atmospheric emissivities for a tropical climate  

SciTech Connect

The total atmospheric flux emissivities as a function of water vapor optical depth are reported for meteorological condtions in Thailand. The water vapor optical depth was first calculated as a function of height up to 12 km from the annual average upper air pressures, temperature, and dew points at Bangkok. The flux emissivity was then computed using tabulated data for the flux emissivities of water vapor, carbon dioxide, and ozone at 20/sup 0/C. (SPH)

Exell, R.H.B.

1978-01-01T23:59:59.000Z

403

Natural Aerosols in the Global Atmosphere  

E-Print Network (OSTI)

1 N?ar det kjem til stykket ?Ar ut og ?ar inn har du site bøygd yver bøkene, du har samla deg meir kunnskap enn du treng til ni liv. N?ar det kjem til stykket, er det so lite som skal til, og det vesle har hjarta alltid visst. I Egypt hadde guden for lærdom hovud som ei ape. Olav H. HaugeNatural aerosols in the global atmosphere

Alf Grini; Alf Grini

2004-01-01T23:59:59.000Z

404

Free Floating Atmospheric Pressure Ball Plasmas  

NLE Websites -- All DOE Office Websites (Extended Search)

Free-Floating Atmospheric Pressure Ball Plasmas Free-Floating Atmospheric Pressure Ball Plasmas G. A. Wurden, Z. Wang, C. Ticos Los Alamos National Laboratory L Al NM 87545 USA Los Alamos, NM 87545 USA C. J. v. Wurden Los Alamos High School L Al NM 87544 Los Alamos, NM 87544 Presented at the PPPL Colloquium Sept. 17, 2008 U N C L A S S I F I E D Operated by the Los Alamos National Security, LLC for the DOE/NNSA LA-UR-08-06284 Outline of this talk *A discussion of ball lightning reports in nature *How can ball plasmas be made in the laboratory? *Detailed experiments on long lived free floating *Detailed experiments on long-lived free-floating atmospheric pressure ball plasmas C i f l b b ll l i h "b ll *Comparison of laboratory ball plasmas with "ball lightning" *Summary U N C L A S S I F I E D Operated by the Los Alamos National Security, LLC for the DOE/NNSA

405

Lightning, atmospheric electricity and climate change  

SciTech Connect

Temperature records indicate that a global warming of 0.5{minus}0.7{degrees}C has occurred over the past century (Hansen and Lebedeff, 1987). Whether this trend is a result of increased trace gas concentrations in the atmosphere, or simply a result of natural variability; is still not known. These temperature trends are derived from thousands of observations worldwide. However, these observations are concentrated largely over continental areas, and then mainly in the northern hemisphere`s populated regions. This northern hemisphere continental bias results in large uncertainties in estimates of global temperature trends. Due to the increasing evidence that the present buildup of greenhouse gases in the atmosphere may result in an additional global warming of 1-5{degrees}C by the year 2050 (IPCC, 1990), it is increasingly important to find afternative methods to monitor fluctuations in global surface temperatures. As shown by two recent studies (Williams, 1992; Price, 1993), the global atmospheric electric circuit may provide a promising afternative for monitoring future climate change.

Price, C.

1993-10-01T23:59:59.000Z

406

Extraction of Freshwater and Energy from Atmosphere  

E-Print Network (OSTI)

Author offers and researches a new, cheap method for the extraction of freshwater from the Earth atmosphere. The suggected method is fundamentally dictinct from all existing methods that extract freshwater from air. All other industrial methods extract water from a saline water source (in most cases from seawater). This new method may be used at any point in the Earth except Polar Zones. It does not require long-distance freshwater transportation. If seawater is not utilized for increasing its productivity, this inexpensive new method is very environment-friendly. The author method has two working versions: (1) the first variant the warm (hot) atmospheric air is lifted by the inflatable tube in a high altitude and atmospheric steam is condenced into freswater: (2) in the second version, the warm air is pumped 20-30 meters under the sea-surface. In the first version, wind and solar heating of air are used for causing air flow. In version (2) wind and propeller are used for causing air movment. The first method...

Bolonkin, Alexander

2007-01-01T23:59:59.000Z

407

Program Operations Plan. Atmospheric Chemistry Program  

SciTech Connect

The Department of Energy`s Atmospheric Chemistry Program (ACP) was initiated in 1991 to coordinate DOE`s university and federal-laboratory atmospheric-chemistry research, and to focus these efforts on national and international information requirements in the atmospheric-chemistry field. This Program Operations Plan describes the structure and vision of the effort designed to fulfill these needs, and is divided into two major components. The first of these is a Strategic Plan, which outlines the ACP`s rationale, objectives, and vision, and describes its products that are anticipated over a future ten-year period. Although based on realistic appraisals of goals that are attainable given the financial, material, and intellectual resources of the ACP community, this Strategic Plan does not describe these resources themselves. The second component of the Program Operations Plan, the Implementation Plan, deals directly with these resource considerations. As such it focuses on practical implementation of Strategic-Plan elements at the individual research institutions, the anticipated scientific contributions of these groups, and their coordination within the ACP. In contrast to the Strategic Plan, this Implementation Plan extends only five years into the future.

1993-04-01T23:59:59.000Z

408

Impact of biomass burning on the atmosphere  

DOE Green Energy (OSTI)

Fire has played an important part in biogeochemical cycling throughout most of the history of our planet. Ice core studies have been very beneficial in paleoclimate studies and constraining the budgets of biogeochemical cycles through the past 160,000 years of the Vostok ice core. Although to date there has been no way of determining cause and effect, concentration of greenhouse gases directly correlates with temperature in ice core analyses. Recent ice core studies on Greenland have shown that significant climate change can be very rapid on the order of a decade. This chapter addresses the coupled evolution of our planet`s atmospheric composition and biomass burning. Special attention is paid to the chemical and climatic impacts of biomass burning on the atmosphere throughout the last century, specifically looking at the cycles of carbon, nitrogen, and sulfur. Information from ice core measurements may be useful in understanding the history of fire and its historic affect on the composition of the atmosphere and climate.

Dignon, J.

1993-03-01T23:59:59.000Z

409

Clustering of Aerosols in Atmospheric Turbulent Flow  

E-Print Network (OSTI)

A mechanism of formation of small-scale inhomogeneities in spatial distributions of aerosols and droplets associated with clustering instability in the atmospheric turbulent flow is discussed. The particle clustering is a consequence of a spontaneous breakdown of their homogeneous space distribution due to the clustering instability, and is caused by a combined effect of the particle inertia and a finite correlation time of the turbulent velocity field. In this paper a theoretical approach proposed in Phys. Rev. E 66, 036302 (2002) is further developed and applied to investigate the mechanisms of formation of small-scale aerosol inhomogeneities in the atmospheric turbulent flow. The theory of the particle clustering instability is extended to the case when the particle Stokes time is larger than the Kolmogorov time scale, but is much smaller than the correlation time at the integral scale of turbulence. We determined the criterion of the clustering instability for the Stokes number larger than 1. We discussed applications of the analyzed effects to the dynamics of aerosols and droplets in the atmospheric turbulent flow.

T. Elperin; N. Kleeorin; M. A. Liberman; V. L'vov; I. Rogachevskii

2007-02-15T23:59:59.000Z

410

Measurement of fragmentation and functionalization pathways in the multistep heterogeneous oxidation of organic aerosol  

DOE Green Energy (OSTI)

The competition between the addition of polar, oxygen-containing functional groups (functionalization) and the cleavage of C-C bonds (fragmentation) has a governing influence on the change in volatility of organic species upon atmospheric oxidation, and hence on the loading of tropospheric organic aerosol. However the branching between these two channels is generally poorly constrained for oxidized organics. Here we determine functionalization/fragmentation branching ratios for organics spanning a range of oxidation levels, using the heterogeneous oxidation of squalane (C30H62) as a model system. Squalane particles are exposed to high concentrations of OH in a flow reactor, and measurements of particle mass and elemental ratios enable the determination of absolute elemental composition (number of oxygen, carbon, and hydrogen atoms) of the oxidized particles. At low OH exposures, the oxygen content of the organics increases, indicating that functionalization dominates, whereas at higher exposures the amount of carbon in the particles decreases, indicating the increasing importance of fragmentation processes. Once the organics are moderately oxidized (O/C~;;0.4), fragmentation completely dominates, and the increase in O/C ratio upon further oxidation is due to the loss of carbon rather than the addition of oxygen. These results suggest that fragmentation reactions may be key steps in the atmospheric formation and evolution of oxygenated organic aerosol (OOA).

Kroll, Jesse H.; Smith, Jared D.; Che, Dung L.; Kessler, Sean H.; Worsnop, Douglas R.; Wilson, Kevin R.

2009-03-10T23:59:59.000Z

411

Test plan for long-term, low-temperature oxidation of BWR spent fuel  

Science Conference Proceedings (OSTI)

Preliminary studies indicated the need for more spent fuel oxidation data in order to determine the probable behavior of spent fuel in a tuff repository. Long-term, low-temperature testing was recommended in a comprehensive technical approach to (1) confirm the findings of the short-term thermogravimetric analysis tests; (2) evaluate the effects of variables such as burnup, atmospheric moisture,and fuel type on the oxidation rate; and (3) extend the oxidation data base to representative repository temperatures and better define the temperature dependence of the operative oxidation mechanisms. This document presents the test plan to study the effects of atmospheric moisture and temperature on oxidation rate and phase formation using a large number of boiling-water reactor fuel samples. Tests will run for up to two years, use characterized fragmented and pulverized fuel samples, cover a temperature range of 110{degree}C to 175{degree}C, and be conducted with an atmospheric moisture content ranging from <{minus}55{degree}C to {approximately}80{degree}C dew point. After testing, the samples will be examined and made available for leaching testing. 15 refs., 2 figs., 2 tabs.

Einziger, R.E.

1988-12-01T23:59:59.000Z

412

Multiple hearth furnace for reducing iron oxide  

SciTech Connect

A multiple moving hearth furnace (10) having a furnace housing (11) with at least two moving hearths (20) positioned laterally within the furnace housing, the hearths moving in opposite directions and each moving hearth (20) capable of being charged with at least one layer of iron oxide and carbon bearing material at one end, and being capable of discharging reduced material at the other end. A heat insulating partition (92) is positioned between adjacent moving hearths of at least portions of the conversion zones (13), and is capable of communicating gases between the atmospheres of the conversion zones of adjacent moving hearths. A drying/preheat zone (12), a conversion zone (13), and optionally a cooling zone (15) are sequentially positioned along each moving hearth (30) in the furnace housing (11).

Brandon, Mark M. (Charlotte, NC); True, Bradford G. (Charlotte, NC)

2012-03-13T23:59:59.000Z

413

Method for producing metal oxide aerogels  

DOE Patents (OSTI)

A two-step hydrolysis-condensation method was developed to form metal oxide aerogels of any density, including densities of less than 0.003g/cm{sup 3} and greater than 0.27g/cm{sup 3}. High purity metal alkoxide is reacted with water, alcohol solvent, and an additive to form a partially condensed metal intermediate. All solvent and reaction-generated alcohol is removed, and the intermediate is diluted with a nonalcoholic solvent. The intermediate can be stored for future use to make aerogels of any density. The aerogels are formed by reacting the intermediate with water, nonalcoholic solvent, and a catalyst, and extracting the nonalcoholic solvent directly. The resulting monolithic aerogels are hydrophobic and stable under atmospheric conditions, and exhibit good optical transparency, high clarity, and homogeneity. The aerogels have high thermal insulation capacity, high porosity, mechanical strength and stability, and require shorter gelation times than aerogels formed by conventional methods. 8 figs.

Tillotson, T.M.; Poco, J.F.; Hrubesh, L.W.; Thomas, I.M.

1995-04-25T23:59:59.000Z

414

Method for producing metal oxide aerogels  

SciTech Connect

A two-step hydrolysis-condensation method was developed to form metal oxide aerogels of any density, including densities of less than 0.003g/cm.sup.3 and greater than 0.27g/cm.sup.3. High purity metal alkoxide is reacted with water, alcohol solvent, and an additive to form a partially condensed metal intermediate. All solvent and reaction-generated alcohol is removed, and the intermediate is diluted with a nonalcoholic solvent. The intermediate can be stored for future use to make aerogels of any density. The aerogels are formed by reacting the intermediate with water, nonalcoholic solvent, and a catalyst, and extracting the nonalcoholic solvent directly. The resulting monolithic aerogels are hydrophobic and stable under atmospheric conditions, and exhibit good optical transparency, high clarity, and homogeneity. The aerogels have high thermal insulation capacity, high porosity, mechanical strength and stability, and require shorter gelation times than aerogels formed by conventional methods.

Tillotson, Thomas M. (Tracy, CA); Poco, John F. (Livermore, CA); Hrubesh, Lawrence W. (Pleasanton, CA); Thomas, Ian M. (Livermore, CA)

1995-01-01T23:59:59.000Z

415

Atmospheric Hydrology of the Anomalous 2002 Indian Summer Monsoon Program in Atmospheric and Oceanic Sciences, University of Colorado, Boulder, Colorado  

E-Print Network (OSTI)

Atmospheric Hydrology of the Anomalous 2002 Indian Summer Monsoon J. FASULLO Program in Atmospheric, in final form 7 April 2005) ABSTRACT The 2002 Indian summer monsoon season is unique because of its in which ENSO events fail to be associated with significant monsoon anomalies. In this study, atmospheric

Fasullo, John

416

ATMO 642 Remote Sensing of the Atmosphere Jan. 17, 2012 ATMO 642: Remote Sensing of the Atmosphere  

E-Print Network (OSTI)

ATMO 642 Remote Sensing of the Atmosphere Jan. 17, 2012 ATMO 642: Remote Sensing of the Atmosphere. 15 % Exam 1 15 % Exam 2 15 % Exam 3 30 % Homework/In class exercises 25 % Project #12;ATMO 642 Remote Sensing of the Atmosphere Jan. 17, 2012 Project: We are going to have a semester long research project

Peterson, Blake R.

417

Atmospheric Radiation Measurement Program Science Plan  

SciTech Connect

The Atmospheric Radiation Measurement (ARM) Program has matured into one of the key programs in the U.S. Climate Change Science Program. The ARM Program has achieved considerable scientific success in a broad range of activities, including site and instrument development, atmospheric radiative transfer, aerosol science, determination of cloud properties, cloud modeling, and cloud parameterization testing and development. The focus of ARM science has naturally shifted during the last few years to an increasing emphasis on modeling and parameterization studies to take advantage of the long time series of data now available. During the next 5 years, the principal focus of the ARM science program will be to: Maintain the data record at the fixed ARM sites for at least the next five years. Improve significantly our understanding of and ability to parameterize the 3-D cloud-radiation problem at scales from the local atmospheric column to the global climate model (GCM) grid square. Continue developing techniques to retrieve the properties of all clouds, with a special focus on ice clouds and mixed-phase clouds. Develop a focused research effort on the indirect aerosol problem that spans observations, physical models, and climate model parameterizations. Implement and evaluate an operational methodology to calculate broad-band heating rates in the atmospheric columns at the ARM sites. Develop and implement methodologies to use ARM data more effectively to test atmospheric models, both at the cloud-resolving model scale and the GCM scale. Use these methodologies to diagnose cloud parameterization performance and then refine these parameterizations to improve the accuracy of climate model simulations. In addition, the ARM Program is actively developing a new ARM Mobile Facility (AMF) that will be available for short deployments (several months to a year or more) in climatically important regions. The AMF will have much of the same instrumentation as the remote facilities at ARM's Tropical Western Pacific and the North Slope of Alaska sites. Over time, this new facility will extend ARM science to a much broader range of conditions for model testing.

Ackerman, T

2004-10-31T23:59:59.000Z

418

ATMOSPHERIC RETRIEVAL FOR SUPER-EARTHS: UNIQUELY CONSTRAINING THE ATMOSPHERIC COMPOSITION WITH TRANSMISSION SPECTROSCOPY  

SciTech Connect

We present a retrieval method based on Bayesian analysis to infer the atmospheric compositions and surface or cloud-top pressures from transmission spectra of exoplanets with general compositions. In this study, we identify what can unambiguously be determined about the atmospheres of exoplanets from their transmission spectra by applying the retrieval method to synthetic observations of the super-Earth GJ 1214b. Our approach to inferring constraints on atmospheric parameters is to compute their joint and marginal posterior probability distributions using the Markov Chain Monte Carlo technique in a parallel tempering scheme. A new atmospheric parameterization is introduced that is applicable to general atmospheres in which the main constituent is not known a priori and clouds may be present. Our main finding is that a unique constraint of the mixing ratios of the absorbers and two spectrally inactive gases (such as N{sub 2} and primordial H{sub 2}+ He) is possible if the observations are sufficient to quantify both (1) the broadband transit depths in at least one absorption feature for each absorber and (2) the slope and strength of the molecular Rayleigh scattering signature. A second finding is that the surface pressure or cloud-top pressure can be quantified if a surface or cloud deck is present at low optical depth. A third finding is that the mean molecular mass can be constrained by measuring either the Rayleigh scattering slope or the shapes of the absorption features, thus enabling one to distinguish between cloudy hydrogen-rich atmospheres and high mean molecular mass atmospheres. We conclude, however, that without the signature of molecular Rayleigh scattering-even with robustly detected infrared absorption features (>10{sigma})-there is no reliable way to tell from the transmission spectrum whether the absorber is a main constituent of the atmosphere or just a minor species with a mixing ratio of X{sub abs} < 0.1%. The retrieval method leads us to a conceptual picture of which details in transmission spectra are essential for unique characterizations of well-mixed exoplanet atmospheres.

Benneke, Bjoern; Seager, Sara, E-mail: bbenneke@mit.edu [Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

2012-07-10T23:59:59.000Z

419

Analysis of Lipid Oxidation  

Science Conference Proceedings (OSTI)

Analysis of Lipid Oxidation is essential for further developments in analytical methodology and hyphenated techniques, with which more understanding of the reaction kinetics, mechanism, and implications will take place. ...

420

Cathodoluminescence of uranium oxides  

SciTech Connect

The cathodoluminescence of uranium oxide surfaces prepared in-situ from clean uranium exposed to dry oxygen was studied. The broad asymmetric peak observed at 470 nm is attributed to F-center excitation.

Winer, K.; Colmenares, C.; Wooten, F.

1984-08-09T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

HIGH TEMPERATURE OXIDATION/CORROSION BEHAVIOR OF METALS AND ALLOYS UNDER A HYDROGEN GRADIENT  

Science Conference Proceedings (OSTI)

Metallic interconnects in SOFC stacks, perform in challenging environment, as they are simultaneously exposed to a reducing environment (e.g. hydrogen, reformate) on one side and an oxidizing environment (e.g. air) on the other side at elevated temperatures. To understand the oxidation/corrosion behavior of metals and alloys under the dual exposures and assess their suitability, selected metals and alloys, including nickel, Fe-Cr and Ni-Cr base chromia forming alloys, alumina forming Fecralloy®, were investigated. It was found that the oxidation/corrosion behavior of metals and alloys in the presence of dual environment can be significantly different in terms of scale structure and/or chemistry from their exposure in a single oxidizing or reducing atmosphere. The anomalous oxidization/corrosion is attributed to the presence of hydrogen diffusion flux from the fuel side to the air side under the influence of a hydrogen gradient across the metallic substrates.

Yang, Z Gary; Xia, Gordon; Walker, Matthew S.; Wang, Chong M.; Stevenson, Jeffry W.; Singh, Prabhakar

2007-11-01T23:59:59.000Z

422

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

423

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

424

Controlled CO preferential oxidation  

DOE Patents (OSTI)

Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

Meltser, M.A.; Hoch, M.M.

1997-06-10T23:59:59.000Z

425

ADVANCED OXIDATION PROCESS  

DOE Green Energy (OSTI)

The removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from automotive fuels is an integral component in the development of cleaner burning and more efficient automobile engines. Oxidative desulfurization (ODS) wherein the dibenzothiophene derivative is converted to its corresponding sulfoxide and sulfone is an attractive approach to sulfur removal because the oxidized species are easily extracted or precipitated and filtered from the hydrocarbon phase. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) catalytically convert dibenzothiophene and its derivatives rapidly and effectively at moderate temperatures (50-60 C) and ambient pressure to the corresponding sulfoxides and sulfones. The oxidation process can be performed in both aqueous systems containing alcohols such as methanol, ethanol, or t-butanol, and in a two-phase hydrocarbon/aqueous system containing tert-butanol or acetonitrile. In the biphasic system, essentially complete conversion of the DBT to its oxidized products can be achieved using slightly longer reaction times than in homogeneous solution. Among the key features of the technology are the mild reaction conditions, the very high selectivity where no over oxidation of the sulfur compounds occurs, the near stoichiometric use of hydrogen peroxide, the apparent lack of degradation of sensitive fuel components, and the ease of separation of oxidized products.

Dr. Colin P. Horwitz; Dr. Terrence J. Collins

2003-11-04T23:59:59.000Z

426

JEM Table of Contents: October 1995  

Science Conference Proceedings (OSTI)

Low Temperature Plasma Enhanced Chemical Vapor Deposition of Silicon Oxide Films Using Disilane and Nitrous Oxide [pp. 1507-1510] Juho Song, G.S. Lee, ...

427

ATMOSPHERIC POLLUTANTS IN AND AROUND MANCHESTER,  

E-Print Network (OSTI)

no nitrogen oxides whatsoever the ozone could not be created, and in some cases a reduction in NOx emissions in NOx emissions can actually lead to an increase in ozone concentrations due to the reduction in ozone achieved through the reduction of VOC emissions. Local areas have been characterised as being either NOx

428

Atmospheric CO2 Records fFrom Sites Operated by the Fraunhofer...  

NLE Websites -- All DOE Office Websites (Extended Search)

the Fraunhofer Institute for Atmospheric Environment Research Garmisch-Partenkirchen, Germany Wank Peak, Germany Zugspitze, Germany Fraunhofer Institute for Atmospheric...

429

Evaluation of Hydrogen Isotope Oxidation Process in an Atmospheric Pressure Plasma  

Science Conference Proceedings (OSTI)

Detritiation and Isotope Separation / Proceedings of the Ninth International Conference on Tritium Science and Technology (Part 2)

K. Akahane; N. Ezumi; Y. Uesugi; Y. Tanaka; M. Tanaka; K. Nishimura

430

Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol  

E-Print Network (OSTI)

Sun, Y. et al. Size-resolved aerosol chemistry on Whistlerwith a high-resolution aerosol mass spectrometer duringBasis Set: 1. Organic-Aerosol Mixing Thermodynamics. Atmos.

Kroll, Jesse H.

2011-01-01T23:59:59.000Z

431

Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol  

E-Print Network (OSTI)

A detailed understanding of the sources, transformations and fates of organic species in the environment is crucial because of the central roles that they play in human health, biogeochemical cycles and the Earth's climate. ...

Kroll, Jesse

432

Uncertainties in estimates of the oxidative capacity of the urban atmosphere : a modeling and measurement approach  

E-Print Network (OSTI)

Mobile emissions represent a significant fraction of the total anthropogenic emissions burden in megacities and have a deleterious effect on air quality at local and regional scales. Due to the significant sources of ...

Zavala-Pérez, Miguel Angel

2007-01-01T23:59:59.000Z

433

Geomagnetic effects on atmospheric Cerenkov images  

E-Print Network (OSTI)

Atmospheric Cerenkov telescopes are used to detect electromagnetic showers from primary gamma rays of energy ~300 GeV - ~10 TeV and to discriminate these from cascades due to hadrons using the Cerenkov images. The geomagnetic field affects the development of showers and is shown to diffuse and distort the images. When the component of the field normal to the shower axis is sufficiently large (> 0.4 G) the performance of gamma ray telescopes may be affected, although corrections should be possible.

P. M. Chadwick; K. Lyons; T. J. L. McComb; K. J. Orford; J. L. Osborne; S. M. Rayner; I. D. Roberts; S. E. Shaw; K. E. Turver

1999-04-07T23:59:59.000Z

434

Atmospheric pressure scanning transmission electron microscopy  

SciTech Connect

Scanning transmission electron microscope (STEM) images of gold nanoparticles (2.1 nm average diameter) at atmospheric pressure have been recorded through a 0.36 mm thick mixture of CO, O2 and He. This was accomplished using a reaction cell consisting of two electron-transparent silicon nitride membranes mounted on a specially designed specimen rod. Gas flow occurred through plastic tubing from the outside of the microscope to the specimen region and back. Gold nanoparticles of a full width half maximum diameter of 1.0 nm were visible above the background noise and the achieved resolution was 0.5 nm in accordance with calculations of the beam broadening.

De Jonge, Niels [ORNL; Veith, Gabriel M [ORNL; Bigelow, Wilbur C [ORNL

2010-01-01T23:59:59.000Z

435

Atmospheric neutrinos: phenomenological summary and outlook  

E-Print Network (OSTI)

The predictions of the atmospheric nu event rates are affected by significant uncertainties, however the evidence for the `disappearance' of nu_mu's and nubar_mu's obtained by SK (and other underground detectors) is robust and cannot be accounted in the framework of the minimum standard model without assuming very large ad hoc experimental systematic effects. The existence of `new physics' beyond the standard model is therefore close to be established; neutrino oscillations provide a very good fit to all data. The theoretical uncertainties do have an important role in the detailed interpretation of the data, and in the estimate of oscillation parameters.

Paolo Lipari

1999-04-23T23:59:59.000Z

436

Downhole steam generator having a downhole oxidant compressor  

SciTech Connect

Apparatus and method for generation of steam in a borehole for penetration into an earth formation wherein a downhole oxidant compressor is used to compress relatively low pressure (atmospheric) oxidant, such as air, to a relatively high pressure prior to mixing with fuel for combustion. The multi-stage compressor receives motive power through a shaft driven by a gas turbine powered by the hot expanding combustion gases. The main flow of compressed oxidant passes through a velocity increasing nozzle formed by a reduced central section of the compressor housing. An oxidant bypass feedpipe leading to peripheral oxidant injection nozzles of the combustion chamber are also provided. The downhole compressor allows effective steam generation in deep wells without need for high pressure surface compressors. Feedback preheater means are provided for preheating fuel in a preheat chamber. Preheating of the water occurs in both a water feed line running from aboveground and in a countercurrent water flow channel surrounding the combustor assembly. The countercurrent water flow channels advantageously serve to cool the combustion chamber wall. The water is injected through slotted inlets along the combustion chamber wall to provide an unstable boundary layer and stripping of the water from the wall for efficient steam generation. Pressure responsive doors are provided at the steam outlet for closing and sealing the combustion chamber from entry of reservoir fluids in the event of a flameout.

Fox, Ronald L. (Albuquerque, NM)

1983-01-01T23:59:59.000Z

437

MOISTURE AND SURFACE AREA MEASUREMENTS OF PLUTONIUM-BEARING OXIDES  

DOE Green Energy (OSTI)

To ensure safe storage, plutonium-bearing oxides are stabilized at 950 C for at least two hours in an oxidizing atmosphere. Stabilization conditions are expected to decompose organic impurities, convert metals to oxides, and result in moisture content below 0.5 wt%. During stabilization, the specific surface area is reduced, which minimizes readsorption of water onto the oxide surface. Plutonium oxides stabilized according to these criteria were sampled and analyzed to determine moisture content and surface area. In addition, samples were leached in water to identify water-soluble chloride impurity content. Results of these analyses for seven samples showed that the stabilization process produced low moisture materials (< 0.2 wt %) with low surface area ({le} 1 m{sup 2}/g). For relatively pure materials, the amount of water per unit surface area corresponded to 1.5 to 3.5 molecular layers of water. For materials with chloride content > 360 ppm, the calculated amount of water per unit surface area increased with chloride content, indicating hydration of hygroscopic salts present in the impure PuO{sub 2}-containing materials. The low moisture, low surface area materials in this study did not generate detectable hydrogen during storage of four or more years.

Crowder, M.; Duffey, J.; Livingston, R.; Scogin, J.; Kessinger, G.; Almond, P.

2009-09-28T23:59:59.000Z

438

Climate Impacts of Atmospheric Sulfate and Black Carbon Aerosols  

SciTech Connect

Although the global average surface temperature has increased by about 0.6°C during the last century (IPCC, 2001), some regions such as East Asia, Eastern North America, and Western Europe have cooled rather than warmed during the past decades (Jones, 1988; Qian and Giorgi, 2000). Coherent changes at the regional scale may reflect responses to different climate forcings that need to be understood in order to predict the future net climate response at the global and regional scales under different emission scenarios. Atmospheric aerosols play an important role in global climate change (IPCC 2001). They perturb the earth’s radiative budget directly by scattering and absorbing solar and long wave radiation, and indirectly by changing cloud reflectivity, lifetime, and precipitation efficiency via their role as cloud condensation nuclei. Because aerosols have much shorter lifetime (days to weeks) compared to most greenhouse gases, they tend to concentrate near their emission sources and distribute very unevenly both in time and space. This non-uniform distribution of aerosols, in conjunction with the greenhouse effect, may lead to differential net heating in some areas and net cooling in others (Penner et al. 1994). Sulfate aerosols come mainly from the oxidation of sulfur dioxide (SO2) emitted from fossil fuel burning. Black carbon aerosols are directly emitted during incomplete combustion of biomass, coal, and diesel derived sources. Due to the different optical properties, sulfate and black carbon affect climate in different ways. Because of the massive emissions of sulfur and black carbon that accompany the rapid economic expansions in East Asia, understanding the effects of aerosols on climate is particularly important scientifically and politically in order to develop adaptation and mitigation strategies.

Qian, Yun; Song, Qingyuan; Menon, Surabi; Yu, Shaocai; Liu, Shaw C.; Shi, Guangyu; Leung, Lai R.; Luo, Yunfeng

2008-09-19T23:59:59.000Z

439

Synoptic Variability of Ocean–Atmosphere Turbulent Fluxes Associated with Atmospheric Cyclones  

Science Conference Proceedings (OSTI)

Synoptic-scale variability in the air–sea turbulent fluxes in the areas of midlatitudinal western boundary currents is analyzed. In the Gulf Stream area, ocean–atmosphere fluxes on synoptic time- and space scales are clearly coordinated with the ...

Olga Zolina; Sergey K. Gulev

2003-08-01T23:59:59.000Z

440

Propagation of B mesons in the atmosphere  

E-Print Network (OSTI)

Collisions of cosmic rays in the atmosphere may produce heavy hadrons of very high energy. The decay length of a $B$ meson of energy above $10^7$ GeV is larger than 1 km, implying that such a particle tends to interact in the air before it decays. We show that the fraction of energy deposited in these interactions is much smaller than in proton and pion collisions. We parameterize their elasticity and determine the average number of interactions and the atmospheric depth at the decay point for different initial energies. We find that the profile of a $3\\times 10^9$ GeV bottom shower may be very different from the profile of a proton shower of the same energy, defining either a very deep maximum, or two maxima, or other features that cannot be parameterized with a single Gaisser-Hillas function. Finally, we discuss under what conditions a bottom hadron inside the parent air shower may provide observable effects.

A. Bueno; A. Gascon; J. I. Illana; M. Masip

2011-09-20T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Vapor scavenging by atmospheric aerosol particles  

Science Conference Proceedings (OSTI)

Particle growth due to vapor scavenging was studied using both experimental and computational techniques. Vapor scavenging by particles is an important physical process in the atmosphere because it can result in changes to particle properties (e.g., size, shape, composition, and activity) and, thus, influence atmospheric phenomena in which particles play a role, such as cloud formation and long range transport. The influence of organic vapor on the evolution of a particle mass size distribution was investigated using a modified version of MAEROS (a multicomponent aerosol dynamics code). The modeling study attempted to identify the sources of organic aerosol observed by Novakov and Penner (1993) in a field study in Puerto Rico. Experimentally, vapor scavenging and particle growth were investigated using two techniques. The influence of the presence of organic vapor on the particle`s hydroscopicity was investigated using an electrodynamic balance. The charge on a particle was investigated theoretically and experimentally. A prototype apparatus--the refractive index thermal diffusion chamber (RITDC)--was developed to study multiple particles in the same environment at the same time.

Andrews, E.

1996-05-01T23:59:59.000Z

442

Thermally Oxidized Silicon  

NLE Websites -- All DOE Office Websites (Extended Search)

Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Illustration of the silicon positions near the Si-SiO2 interface for a 4° miscut projected onto the ( ) plane. The silicon atoms in the substrate are blue and those in the oxide are red. The small black spots represent the translated silicon positions in the absence of static disorder. The silicon atoms in the oxide have been randomly assigned a magnitude and direction based on the static disorder value at that position in the lattice. The outline of four silicon unit cells is shown in black, whereas the outline of four expanded lattice cells in the oxide is shown in blue One of the most studied devices of modern technology is the field-effect transistor, which is the basis for most integrated circuits. At its heart

443

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

444

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

445

Combustion characteristics and influential factors of isooctane active-thermal atmosphere combustion assisted by two-stage reaction of n-heptane  

Science Conference Proceedings (OSTI)

This paper presents an experimental study on the isooctane active-thermal atmosphere combustion (ATAC) which is assisted by two-stage reaction of n-heptane. The active-thermal atmosphere is created by low- and high-temperature reactions of n-heptane which is injected at intake port, and isooctane is directly injected into combustion chamber near the top dead center. The effects of isooctane injection timing, active-thermal atmosphere intensity, overall equivalence ratio, and premixed ratio on combustion characteristics and emissions are investigated. The experimental results reveal that, the isooctane ignition and combustion can be classified to thermal atmosphere combustion, active atmosphere combustion, and active-thermal atmosphere combustion respectively according to the extent of n-heptane oxidation as well as effects of isooctane quenching and charge cooling. n-Heptane equivalence ratio, isooctane equivalence ratio and isooctane delivery advance angle are major control parameters. In one combustion cycle, the isooctane ignited and burned after those of n-heptane, and then this combustion phenomenon can also be named as dual-fuel sequential combustion (DFSC). The ignition timing of the overall combustion event is mainly determined by n-heptane equivalence ratio and can be controlled in flexibility by simultaneously adjusting isooctane equivalence ratio. The isooctane ignition regime, overall thermal efficiency, and NO{sub x} emissions show strong sensitivity to the fuel delivery advance angle between 20 CA BTDC and 25 CA BTDC. (author)

Lu, Xingcai; Ji, Libin; Ma, Junjun; Zhou, Xiaoxin; Huang, Zhen [Key Lab. for Power Machinery and Engineering of MOE, Shanghai Jiao Tong University, 200240 Shanghai (China)

2011-02-15T23:59:59.000Z

446

A General Systems Theory for Atmospheric Flows and Atmospheric Aerosol Size Distribution  

E-Print Network (OSTI)

Atmospheric flows exhibit selfsimilar fractal spacetime fluctuations manifested as the fractal geometry to global cloud cover pattern and inverse power law form for power spectra of meteorological parameters such as windspeed, temperature, rainfall etc. Inverse power law form for power spectra indicate long-range spacetime correlations or non-local connections and is a signature of selforganised criticality generic to dynamical systems in nature such as river flows, population dynamics, heart beat patterns etc. The author has developed a general systems theory which predicts the observed selforganised criticality as a signature of quantumlike chaos in dynamical systems. The model predictions are (i) The fractal fluctuations can be resolved into an overall logarithmic spiral trajectory with the quasiperiodic Penrose tiling pattern for the internal structure. (ii) The probability distribution represents the power (variance) spectrum for fractal fluctuations and follows universal inverse power law form incorporating the golden mean. Such a result that the additive amplitudes of eddies when squared represent probability distribution is observed in the subatomic dynamics of quantum systems such as the electron or photon. Therefore the irregular or unpredictable fractal fluctuations exhibit quantumlike chaos. (iii) Atmospheric aerosols are held in suspension by the vertical velocity distribution (spectrum). The atmospheric aerosol size spectrum is derived in terms of the universal inverse power law characterizing atmospheric eddy energy spectrum. Model predicted spectrum is in agreement with the following two experimentally determined atmospheric aerosol data sets, (i) SAFARI 2000 CV-580 Aerosol Data, Dry Season 2000 (CARG) (ii) World Data Centre Aerosols data sets for the three stations Ny {\\AA}lesund, Pallas and Hohenpeissenberg.

A. M. Selvam

2009-08-17T23:59:59.000Z

447

JGR-Atmospheres Papers from the RADAGAST Research Team  

NLE Websites -- All DOE Office Websites (Extended Search)

JGR-Atmospheres Papers from the RADAGAST Research Team JGR-Atmospheres Papers from the RADAGAST Research Team Bharmal, N.A., A. Slingo, G.J. Robinson, and J.J. Settle, 2009: Simulation of surface and top of atmosphere thermal fluxes and radiances from the RADAGAST experiment. Journal of Geophysical Research-Atmospheres, 114, doi:10.1029/2008JD010504, in press. Kollias, P., M.A. Miller, K.L. Johnson, M.P. Jensen, and D.T. Troyan, 2009: Cloud, thermodynamic, and precipitation observations in West Africa during 2006. Journal of Geophysical Research- Atmospheres, 114, doi: 10.1029/2008JD010641, in press. McFarlane, S.A., E.I. Kassianov, J. Barnard, C. Flynn, and T. Ackerman, 2009: Surface shortwave aerosol forcing during the ARM Mobile Facility deployment in Niamey, Niger. Journal of Geophysical Research-Atmospheres, 114, doi: 10.1029/2008JD010491, 17 pages.

448

Atmospheric Concentrations of CO2 from Mauna Loa, Hawaii  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Concentrations of CO2 from Mauna Loa, Hawaii Atmospheric Concentrations of CO2 from Mauna Loa, Hawaii The graphs on this page are generated from data taken from "Trends in Carbon Dioxide" page on the Department of Commerce/National Oceanic and Atmospheric Administration (NOAA) website. The NOAA website presents monthly and weekly atmospheric CO2 concentrations measured at the Mauna Loa Observatory in Hawaii. It offers weekly and monthly data, additional graphs, analysis, descriptions of how the data are collected, and an animation of historical changes in atmospheric CO2. Mauna Loa constitutes the longest record of direct measurements of CO2 in the atmosphere. The measurents were started by C. David Keeling of the Scripps Institution of Oceanography in March of 1958. Recent Monthly Average CO2

449

ARM - Field Campaign - Lower Atmospheric Boundary Layer Experiment  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsLower Atmospheric Boundary Layer Experiment govCampaignsLower Atmospheric Boundary Layer Experiment Campaign Links LABLE Website Related Campaigns 2013 Lower Atmospheric Boundary Layer Experiment 2013.05.28, Turner, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Lower Atmospheric Boundary Layer Experiment 2012.09.17 - 2012.11.13 Lead Scientist : David Turner Description Boundary layer turbulence is an important process that is parameterized in most atmospheric numerical models. Turbulence redistributes energy and mass within the boundary layer. Many different characteristics can impact the character of turbulence in the boundary layer, including different surface types, horizontal wind speed and direction, and the vertical temperature structure of the atmosphere. However, there have been few studies that have

450

A Volcanologist'S Review Of Atmospheric Hazards Of Volcanic Activity- Fuego  

Open Energy Info (EERE)

Volcanologist'S Review Of Atmospheric Hazards Of Volcanic Activity- Fuego Volcanologist'S Review Of Atmospheric Hazards Of Volcanic Activity- Fuego And Mount St Helens Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Volcanologist'S Review Of Atmospheric Hazards Of Volcanic Activity- Fuego And Mount St Helens Details Activities (0) Areas (0) Regions (0) Abstract: The large amount of scientific data collected on the Mount St. Helens eruption has resulted in significant changes in thinking about the atmospheric hazards caused by explosive volcanic activity. The hazard posed by fine silicate ash with long residence time in the atmosphere is probably much less serious than previously thought. The Mount St. Helens eruption released much fine ash in the upper atmosphere. These silicates were removed very rapidly due to a process of particle aggregation (Sorem, 1982;

451

Energy Spectra, Altitude Profiles and Charge Ratios of Atmospheric Muons  

E-Print Network (OSTI)

We present a new measurement of air shower muons made during atmospheric ascent of the High Energy Antimatter Telescope balloon experiment. The muon charge ratio mu+ / mu- is presented as a function of atmospheric depth in the momentum interval 0.3-0.9 GeV/c. The differential mu- momentum spectra are presented between 0.3 and about 50 GeV/c at atmospheric depths between 13 and 960 g/cm^2. We compare our measurements with other recent data and with Monte Carlo calculations of the same type as those used in predicting atmospheric neutrino fluxes. We find that our measured mu- fluxes are smaller than the predictions by as much as 70% at shallow atmospheric depths, by about 20% at the depth of shower maximum, and are in good agreement with the predictions at greater depths. We explore the consequences of this on the question of atmospheric neutrino production.

S. Coutu; J. J. Beatty; M. A. DuVernois; S. W. Barwick; E. Schneider; A. Bhattacharyya; C. R. Bower; J. A. Musser; A. Labrador; D. Muller; S. P. Swordy; E. Torbet; C. Chaput; S. McKee; G. Tarle; A. D. Tomasch; S. L. Nutter; G. A. deNolfo

2000-04-07T23:59:59.000Z

452

CHEMISTRY OF SILICATE ATMOSPHERES OF EVAPORATING SUPER-EARTHS  

SciTech Connect

We model the formation of silicate atmospheres on hot volatile-free super-Earths. Our calculations assume that all volatile elements such as H, C, N, S, and Cl have been lost from the planet. We find that the atmospheres are composed primarily of Na, O{sub 2}, O, and SiO gas, in order of decreasing abundance. The atmospheric composition may be altered by fractional vaporization, cloud condensation, photoionization, and reaction with any residual volatile elements remaining in the atmosphere. Cloud condensation reduces the abundance of all elements in the atmosphere except Na and K. We speculate that large Na and K clouds such as those observed around Mercury and Io may surround hot super-Earths. These clouds would occult much larger fractions of the parent star than a closely bound atmosphere, and may be observable through currently available methods.

Schaefer, Laura; Fegley, Bruce, E-mail: laura_s@levee.wustl.ed, E-mail: bfegley@levee.wustl.ed [Planetary Chemistry Laboratory, McDonnell Center for the Space Sciences, Department of Earth and Planetary Sciences, Washington University in St. Louis, Saint Louis, MO 63130-4899 (United States)

2009-10-01T23:59:59.000Z

453

Molecular water oxidation catalyst  

DOE Patents (OSTI)

A dimeric composition of the formula: ##STR1## wherein L', L", L'", and L"" are each a bidentate ligand having at least one functional substituent, the ligand selected from bipyridine, phenanthroline, 2-phenylpyridine, bipyrimidine, and bipyrazyl and the functional substituent selected from carboxylic acid, ester, amide, halogenide, anhydride, acyl ketone, alkyl ketone, acid chloride, sulfonic acid, phosphonic acid, and nitro and nitroso groups. An electrochemical oxidation process for the production of the above functionally substituted bidentate ligand diaqua oxo-bridged ruthenium dimers and their use as water oxidation catalysts is described.

Gratzel, Michael (St. Sulpice, CH); Munavalli, Shekhar (Bel Air, MD); Pern, Fu-Jann (Lakewood, CO); Frank, Arthur J. (Lakewood, CO)

1993-01-01T23:59:59.000Z

454

Tetraalykylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

1998-01-01T23:59:59.000Z

455

Tetraalklylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

1998-10-06T23:59:59.000Z

456

Atmospheric neutrino flux at INO, South Pole and Pyhäsalmi  

E-Print Network (OSTI)

We present the calculation of the atmospheric neutrino fluxes for the neutrino experiments proposed at INO, South Pole and Pyh\\"asalmi. Neutrino fluxes have been obtained using ATMNC, a simulation code for cosmic ray in the atmosphere. Even using the same primary flux model and the interaction model, the calculated atmospheric neutrino fluxes are different for the different sites due to the geomagnetic field. The prediction of these fluxes in the present paper would be quite useful in the experimental analysis.

M. Sajjad Athar; M. Honda; T. Kajita; K. Kasahara; S. Midorikawa

2012-10-18T23:59:59.000Z

457

Biological Properties of Zinc Oxide-Coated Anodized Aluminum Oxide  

Science Conference Proceedings (OSTI)

We used agar diffusion assays to evaluate the activity of zinc oxide-coated ... Zirconia Stabilisation Nano-Confined by Using Electroless Nickel Cladding .... Metal Oxide Nanofibers Produced by a ForceSpinning Method for Battery Electrodes.

458

Global Atmospheric Pollution Forum Air Pollutant Emission Inventory | Open  

Open Energy Info (EERE)

Global Atmospheric Pollution Forum Air Pollutant Emission Inventory Global Atmospheric Pollution Forum Air Pollutant Emission Inventory Jump to: navigation, search Tool Summary Name: Global Atmospheric Pollution (GAP) Forum Air Pollutant Emission Inventory Agency/Company /Organization: BOC foundation, U.S. Environment Protection Agency (EPA) and Swedish International Development Cooperation Agency (SIDA) Complexity/Ease of Use: Moderate Website: sei-international.org/rapidc/gapforum/html/emissions-manual.php Cost: Free Related Tools Global Atmospheric Pollution Forum Air Pollutant Emission Inventory World Induced Technical Change Hybrid (WITCH) Energy Development Index (EDI) ... further results Find Another Tool FIND DEVELOPMENT IMPACTS ASSESSMENT TOOLS A manual that provides formulation of methods and assessment of good

459

ON THE STABILITY OF SUPER-EARTH ATMOSPHERES  

SciTech Connect

We investigate the stability of super-Earth atmospheres around M stars using a seven-parameter, analytical framework. We construct stability diagrams in the parameter space of exoplanetary radius versus semimajor axis and elucidate the regions in which the atmospheres are stable against the condensation of their major constituents, out of the gas phase, on their permanent nightside hemispheres. We find that super-Earth atmospheres that are nitrogen-dominated (Earth-like) occupy a smaller region of allowed parameter space, compared to hydrogen-dominated atmospheres, because of the dual effects of diminished advection and enhanced radiative cooling. Furthermore, some super-Earths which reside within the habitable zones of M stars may not possess stable atmospheres, depending on the mean molecular weight and infrared photospheric pressure of their atmospheres. We apply our stability diagrams to GJ 436b and GJ 1214b, and demonstrate that atmospheric compositions with high mean molecular weights are disfavored if these exoplanets possess solid surfaces and shallow atmospheres. Finally, we construct stability diagrams tailored to the Kepler data set, for G and K stars, and predict that about half of the exoplanet candidates are expected to harbor stable atmospheres if Earth-like conditions are assumed. We include 55 Cancri e and CoRoT-7b in our stability diagram for G stars.

Heng, Kevin [ETH Zuerich, Institute for Astronomy, Wolfgang-Pauli-Strasse 27, CH-8093, Zuerich (Switzerland); Kopparla, Pushkar [ETH Zuerich, Institute for Atmospheric and Climate Science, Universitaetstrasse 16, CH-8092, Zuerich (Switzerland)

2012-07-20T23:59:59.000Z

460

National Atmospheric Release Advisory Center | National Nuclear Security  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Release Advisory Center | National Nuclear Security Atmospheric Release Advisory Center | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog National Atmospheric Release Advisory Center Home > About Us > Our Programs > Emergency Response > Responding to Emergencies > Consequence Management > National Atmospheric Release Advisory Center

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

The Limitations of CFD Modeling for Furnace Atmosphere ... - TMS  

Science Conference Proceedings (OSTI)

Feb 1, 2002 ... The Limitations of CFD Modeling for Furnace Atmosphere Troubleshooting by P.F. Stratton, N. Saxena and M. Huggahalli ...

462

Visualizing Storms from NCAR's Atmosphere Model at NERSC  

NLE Websites -- All DOE Office Websites (Extended Search)

Community Atmosphere Model, we are studying how well the model can reproduced observed tropical cyclone statistics. The simulated storms seen in this animation are generated...

463

Dissociation of carbon dioxide in atmospheric pressure microchannel plasma devices.  

E-Print Network (OSTI)

??Plasma discharge of carbon dioxide at atmospheric pressure was successfully demonstrated in microchannel plasma devices at breakdown voltages lower than 1 kVRMS. Optical emissions of… (more)

Oh, Taegon

2013-01-01T23:59:59.000Z

464

A Volcanologist'S Review Of Atmospheric Hazards Of Volcanic Activity...  

Open Energy Info (EERE)

1982). Evidence based on measurements of S and Cl in erupted rocks, glass inclusions, gas samples, and atmospheric samples collected for both Mount St. Helens and Fuego...

465

Gravity wave coupling of the lower and middle atmosphere.  

E-Print Network (OSTI)

??A method of inferring tropospheric gravity wave source characteristics from middle atmosphere observations has been adapted from previous studies for use with MF radar observations… (more)

Love, Peter Thomas

2009-01-01T23:59:59.000Z

466

Advanced Understanding of the Atmospheric Corrosion of Materials  

Science Conference Proceedings (OSTI)

On the Mechanism of Castastropic Atmospheric Sulfidation of Electronic Components in Data Centers · Real Time Measure of Corrosion under Differing Relative ...

467

On the Mechanism of Castastropic Atmospheric Sulfidation of ...  

Science Conference Proceedings (OSTI)

Presentation Title, On the Mechanism of Castastropic Atmospheric Sulfidation of Electronic Components in Data Centers. Author(s), Linn W. Hobbs. On-Site ...

468

The Climatology of Relative Humidity in the Atmosphere  

Science Conference Proceedings (OSTI)

The present paper deals with the analysis of the time-average relative humidity fields in the atmosphere. Twice-daily estimates of relative humidity are used.

JoséP. Peixoto; Abraham H. Oort

1996-12-01T23:59:59.000Z

469

Validation of the ARchived CERES Surface and Atmosphere Radiation...  

NLE Websites -- All DOE Office Websites (Extended Search)

Rutledge, T. P. Charlock, N. G. Loeb, and S. Kato, 2001: Atmospheric corrections using MODTRAN for TOA and surface BRDF characteristics from high resolution spectroradiometeric...

470

The Effect of Hydrogen as Sintering Atmosphere on Densification ...  

Science Conference Proceedings (OSTI)

Presentation Title, The Effect of Hydrogen as Sintering Atmosphere on Densification and Microstructural Features of Powder Metallurgy Titanium. Author (s), Pei ...

471

TIP Project Brief100019 Atmospheric Spray Freeze Dried ...  

Science Conference Proceedings (OSTI)

Page 1. TIP Project Brief – 100019/11H003 Manufacturing Atmospheric Spray Freeze Dried Powder Process Advancement and Scale-Up ...

2011-11-07T23:59:59.000Z

472

Atmospheric Carbon Dioxide Record from Flask Measurements at...  

NLE Websites -- All DOE Office Websites (Extended Search)

Island Atmospheric Carbon Dioxide Record from Flask Measurements at Lampedusa Island graphics Graphics data Data Investigators Paolo Chamard, Luigi Ciattaglia, Alcide di Sarra,...

473

Graphics: Atmospheric Trace Gases in Whole-Air Samples  

NLE Websites -- All DOE Office Websites (Extended Search)

Graphics graphics Graphics: Atmospheric Trace Gases in Whole-Air Samples The following links are for methane, nonmethane hydrocarbons, alkyl nitrates, and chlorinated carbon...

474

Atmospheric CO2 Record from Continuous Measurements at Jubany...  

NLE Websites -- All DOE Office Websites (Extended Search)

PNRA (National Research Program in Antarctica) began continuous atmospheric carbon dioxide measurements at Jubany in 1994. The laboratory at Jubany Station is operated...

475

Atmospheric Aerosol Chemistry, Climate Change, and Air Quality  

NLE Websites -- All DOE Office Websites (Extended Search)

spectrometry capabilities to analyze the molecular composition of atmospheric organic aerosols, or OA, containing nitrogen- containing organic compounds (NOC) and only carbon,...

476

Table 40. Refiners' Total Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

Table 40. Refiners' Total Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 2005 Companies with Capacity Over 100,000 bbl/cd

477

Table 5. Refiners' Total Operable Atmospheric Crude Oil ...  

U.S. Energy Information Administration (EIA)

Table 5. Refiners' Total Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 2006 Companies with Capacity Over 100,000 bbl/cd

478

Table 40. Refiners’ Operable Atmospheric Crude Oil Distillation ...  

U.S. Energy Information Administration (EIA)

Table 40. Refiners’ Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 1997 Refiner Barrels per Calendar Day Refiner Barrels per

479

Studies of urban atmospheric aerosols using lidar and sky radiometer.  

E-Print Network (OSTI)

???This thesis discusses the remote sensing of atmospheric aerosols, the corresponding instrumental technology and inversion algorithm. The urban aerosol optical properties in Hong Kong have… (more)

Yang, Xun (??)

2008-01-01T23:59:59.000Z

480

Reference Alloy Waste Form Fabrication and Initiation of Reducing Atmosphere and Reductive Additives Study on Alloy Waste Form Fabrication  

Science Conference Proceedings (OSTI)

This report describes the fabrication of two reference alloy waste forms, RAW-1(Re) and RAW-(Tc) using an optimized loading and heating method. The composition of the alloy materials was based on a generalized formulation to process various proposed feed streams resulting from the processing of used fuel. Waste elements are introduced into molten steel during alloy fabrication and, upon solidification, become incorporated into durable iron-based intermetallic phases of the alloy waste form. The first alloy ingot contained surrogate (non-radioactive), transition-metal fission products with rhenium acting as a surrogate for technetium. The second alloy ingot contained the same components as the first ingot, but included radioactive Tc-99 instead of rhenium. Understanding technetium behavior in the waste form is of particular importance due the longevity of Tc-99 and its mobility in the biosphere in the oxide form. RAW-1(Re) and RAW-1(Tc) are currently being used as test specimens in the comprehensive testing program investigating the corrosion and radionuclide release mechanisms of the representative alloy waste form. Also described in this report is the experimental plan to study the effects of reducing atmospheres and reducing additives to the alloy material during fabrication in an attempt to maximize the oxide content of waste streams that can be accommodated in the alloy waste form. Activities described in the experimental plan will be performed in FY12. The first aspect of the experimental plan is to study oxide formation on the alloy by introducing O2 impurities in the melt cover gas or from added oxide impurities in the feed materials. Reducing atmospheres will then be introduced to the melt cover gas in an attempt to minimize oxide formation during alloy fabrication. The second phase of the experimental plan is to investigate melting parameters associated with alloy fabrication to allow the separation of slag and alloy components of the melt.

S.M. Frank; T.P. O'Holleran; P.A. Hahn

2011-09-01T23:59:59.000Z

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481

SECHIBA, a New Set of Parameterizations of the Hydrologic Exchanges at the Land-Atmosphere Interface within the LMD Atmospheric General Circulation Model  

Science Conference Proceedings (OSTI)

A simple parameterization of the hydrologic exchanges between the soil-vegetation system and the atmosphere (SECHIBA) has been developed for use within atmospheric general circulation models (AGCM).

Nathale I. Ducoudré; Katia Laval; Alain Perrier

1993-02-01T23:59:59.000Z

482

Hydrous oxide activated charcoal  

SciTech Connect

This patent describes a process for preparing of an ion exchanger, comprising: treating an ionically inert activated charcoal porous support with an aqueous solution of metal oxychloride selected from the group consisting of zirconium and titanium oxychlorides so as to impregnate the pores of the support with the solution; separating the treated support from excess metal oxychloride solution; converting the metal oxychloride to a hydrous metal oxide precipitate in the pores of the support at a pH above 8 and above the pH whereat the hydrous metal oxide and activated charcoal support have opposite zeta potentials and sufficient to hydrolyze the metal oxychloride. It also describes a process for preparing an ion exchanger comprising: treating granulated activated charcoal with a concentrated solution of a metal oxychloride from the group consisting of zirconium and titanium oxychlorides, degassing the mixture; and treating the resultant mixture with a base selected from the group consisting of ammonium hydroxide and alkali metal hydroxides so as to precipitate the oxychloride within the pores of the activated carbon granules as hydrous metal oxide at a pH above 8 and above the pH whereat the hydrous metal oxide and activated charcoal have opposite zeta potentials.

Weller, J.P.

1987-09-08T23:59:59.000Z

483

Doped zinc oxide microspheres  

DOE Patents (OSTI)

A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

1993-12-14T23:59:59.000Z

484

Iron aluminide alloy container for solid oxide fuel cells  

DOE Patents (OSTI)

A container for fuel cells is made from an iron aluminide alloy. The container alloy preferably includes from about 13 to about 22 weight percent Al, from about 2 to about 8 weight percent Cr, from about 0.1 to about 4 weight percent M selected from Zr and Hf, from about 0.005 to about 0.5 weight percent B or from about 0.001 to about 1 weight percent C, and the balance Fe and incidental impurities. The iron aluminide container alloy is extremely resistant to corrosion and metal loss when exposed to dual reducing and oxidizing atmospheres at elevated temperatures. The alloy is particularly useful for containment vessels for solid oxide fuel cells, as a replacement for stainless steel alloys which are currently used.

Judkins, Roddie Reagan (Knoxville, TN); Singh, Prabhakar (Export, PA); Sikka, Vinod Kumar (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

485

Apparatus and method for stabilization or oxidation of polymeric materials  

DOE Patents (OSTI)

An apparatus for treating polymeric materials comprises a treatment chamber adapted to maintain a selected atmosphere at a selected temperature; a means for supporting the polymeric material within the chamber; and, a source of ozone-containing gas, which decomposes at the selected temperature yielding at least one reactive oxidative species whereby the polymer is stabilized and cross linked through exposure to the oxidative species in the chamber at the selected temperature. The ozone may be generated by a plasma discharge or by various chemical processes. The apparatus may be configured for either batch-type or continuous-type processing. The apparatus and method are especially useful for preparing polymer fibers, particularly PAN fibers, for later carbonization treatments as well as to make flame-retardant fabrics.

Paulauskas, Felix L. (Knoxville, TN); Sherman, Daniel M. (Knoxville, TN)

2010-01-19T23:59:59.000Z

486

Atmospheric Carbon Dioxide Record from Mauna Loa  

NLE Websites -- All DOE Office Websites (Extended Search)

SIO Air Sampling Network » Mauna Loa SIO Air Sampling Network » Mauna Loa Atmospheric Carbon Dioxide Record from Mauna Loa DOI: 10.3334/CDIAC/atg.035 graphics Graphics data Data Investigators R.F. Keeling, S.C. Piper, A.F. Bollenbacher and J.S. Walker Carbon Dioxide Research Group Scripps Institution of Oceanography University of California La Jolla, California 92093-0444, U.S.A. Period of Record 1958-2008 Methods Air samples at Mauna Loa are collected continuously from air intakes at the top of four 7-m towers and one 27-m tower. Four air samples are collected each hour for the purpose of determining the CO2 concentration. Determinations of CO2 are made by using a Siemens Ultramat 3 nondispersive infrared gas analyzer with a water vapor freeze trap. This analyzer registers the concentration of CO2 in a stream of air flowing at ~0.5

487

Nucla circulating atmospheric fluidized bed demonstration project  

Science Conference Proceedings (OSTI)

Colorado-Ute Electric Association began a study to evaluate options for upgrading and extending the life of its Nucla power station in 1982. Located in southwestern Colorado near the town of Nucla, this station was commissioned in 1959 with a local bituminous coal as its design fuel for three identical stoker-fired units, each rated at 12.6 MW(e). Poor station efficiency, high fuel costs, and spiraling boiler maintenance costs forced the Nucla Station into low priority in the CUEA dispatch order as early as 1981. Among the options CUEA considered was to serve as a host utility to demonstrate Atmospheric Fluidized Bed Combustion (AFBC) technology. The anticipated environmental benefits and apparent attractive economics of a circulating AFBC led to Colorado-Ute's decision to proceed with the design and construction of a demonstration project in 1984 at the Nucla facility.

Not Available

1991-10-01T23:59:59.000Z

488

The Atmospheric and Terrestrial Mobile Laboratory (ATML).  

Science Conference Proceedings (OSTI)

The ionospheric disturbance dynamo signature in geomagnetic variations is investigated using the National Center for Atmospheric Research Thermosphere-Ionosphere-Electrodynamics General Circulation Model. The model results are tested against reference magnetically quiet time observations on 21 June 1993, and disturbance effects were observed on 11 June 1993. The model qualitatively reproduces the observed diurnal and latitude variations of the geomagnetic horizontal intensity and declination for the reference quiet day in midlatitude and low-latitude regions but underestimates their amplitudes. The patterns of the disturbance dynamo signature and its source 'anti-Sq' current system are well reproduced in the Northern Hemisphere. However, the model significantly underestimates the amplitude of disturbance dynamo effects when compared with observations. Furthermore, the largest simulated disturbances occur at different local times than the observations. The discrepancies suggest that the assumed high-latitude storm time energy inputs in the model were not quantitatively accurate for this storm.

Zak, Bernard Daniel; Rahn, Thom (Los Alamos National Laboratory); Nitschke, Kim (Los Alamos National Laboratory); Ivey, Mark D.; Mora, Claudia (Los Alamos National Laboratory); McDowell, Nate (Los Alamos National Laboratory); Love, Steve (Los Alamos National Laboratory); Dubey, M. (Los Alamos National Laboratory); Michelsen, Hope A.; Guilderson, Tom (Lawrence Livermore National Laboratory); Schubert, William Kent; Costigan, Keeley (Los Alamos National Laboratory); Chylek, Petr (Los Alamos National Laboratory); Bambha, Ray P.; Roskovensky, John K.

2010-04-01T23:59:59.000Z

489

Atmospheric Dispersion Analysis using MACCS2  

Science Conference Proceedings (OSTI)

The Nuclear Regulatory Commission (NRC) Regulatory Guide 1.145 requires an evaluation of the offsite atmospheric dispersion coefficient, {Chi}/Q, as a part of the acceptance criteria in the accident analysis. In it, it requires in sequence computations of (1) the overall site 95th percentile {Chi}/Q, (2) the maximum of the sixteen sector 99.5th percentile {Chi}/Q, and (3) comparison and selection of the worst of the two values for reporting in the safety analysis report (SAR). In all cases, the site-specific meteorology and sector-specific site boundary distances are employed in the evaluation. There are sixteen 22.5-sectors, the nearest site boundary of which is determined within the 45-arc centered on each of the sixteen compass directions.

Glaser, R; Yang, J M

2004-02-02T23:59:59.000Z

490

Thermodynamics of atmospheric circulation on hot Jupiters  

E-Print Network (OSTI)

Atmospheric circulation on tidally-locked exoplanets is driven by the absorption and reradiation of heat from the host star. They are natural heat engines, converting heat into mechanical energy. A steady state is possible only if there is a mechanism to dissipate mechanical energy, or if the redistribution of heat is so effective that the Carnot efficiency is driven to zero. Simulations based on primitive, equivalent-barotropic, or shallow-water equations without explicit provision for dissipation of kinetic energy and for recovery of that energy as heat, violate energy conservation. More seriously perhaps, neglect of physical sources of drag may overestimate wind speeds and rates of advection of heat from the day to the night side.

J. Goodman

2008-10-07T23:59:59.000Z

491

Lipid Oxidation Pathways, Volume 2  

Science Conference Proceedings (OSTI)

This book complements Lipid Oxidation Pathways, Volume 1. Lipid Oxidation Pathways, Volume 2 Health acid analysis aocs april articles chloropropanediol contaminants detergents dietary fats division divisions esters fats fatty food foods glycidol Health h

492

Cholesterol and Phytosterol Oxidation Products  

Science Conference Proceedings (OSTI)

This book comprehensively reviews several aspects of cholesterol oxidation products: cholesterol oxidation mechanisms, analytical determination, origin and content of these compounds in foods and biological samples, and their biological effects, with an em

493

Oxygen sensitive, refractory oxide composition  

DOE Patents (OSTI)

Oxide compositions containing niobium pentoxide and an oxide selected from the group consisting of hafnia, titania, and zirconia have electrical conductivity characteristics which vary greatly depending on the oxygen content.

Holcombe, Jr., Cressie E. (Oak Ridge, TN); Smith, Douglas D. (Knoxville, TN)

1976-01-01T23:59:59.000Z

494

ADVANCED OXIDATION PROCESS  

DOE Green Energy (OSTI)

The design of new, high efficiency and cleaner burning engines is strongly coupled with the removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from fuels. Oxidative desulfurization (ODS) wherein these dibenzothiophene derivatives are oxidized to their corresponding sulfoxides and sulfones is an approach that has gained significant attention. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) convert in a catalytic process dibenzothiophene and its derivatives to the corresponding sulfoxides and sulfones rapidly at moderate temperatures (60 C) and ambient pressure. The reaction can be performed in both an aqueous system containing an alcohol (methanol, ethanol, or t-butanol) to solubilize the DBT and in a two-phase hydrocarbon/aqueous system where the alcohol is present in both phases and facilitates the oxidation. Under a consistent set of conditions using the FeBF{sub 2} TAML activator, the degree of conversion was found to be t-butanol > methanol > ethanol. In the cases of methanol and ethanol, both the sulfoxide and sulfone were observed while for t-butanol only the sulfone was detected. In the two-phase system, the alcohol may function as an inverse phase transfer agent. The oxidation was carried out using two different TAML activators. In homogeneous solution, approximately 90% oxidation of the DBT could be achieved using the prototype TAML activator, FeB*, by sonicating the solution at near room temperature. In bi-phasic systems conversions as high as 50% were achieved using the FeB* TAML activator and hydrogen peroxide at 100 C. The sonication method yielded only {approx}6% conversion but this may have been due to mixing.

Colin P. Horwitz; Terrence J. Collins

2003-10-22T23:59:59.000Z

495

METAL INTERCONNECTS FOR SOLID OXIDE FUEL CELL POWER SYSTEMS  

DOE Green Energy (OSTI)

Interconnect development is identified by the U.S. Department of Energy as a key technical area requiring focused research to meet the performance and cost goals under the Solid State Energy Conversion Alliance initiative. In the Phase I SECA Core Technology Program, Ceramatec investigated a commercial ferritic stainless steel composition for oxidation resistance properties by measuring the weight gain when exposed to air at the fuel cell operating temperature. A pre-treatment process that results in a dense, adherent scale was found to reduce the oxide scale growth rate significantly. A process for coating the surface of the alloy in order to reduce the in-plane resistance and potentially inhibit chromium oxide evaporation was also identified. The combination of treatments provided a very low resistance through the scale. The resistance measured was as low as 10 milliohm-cm{sup 2} at 750 C in air. The oxide scale was found to be stable in humidified air at 750 C. The resistance value was stable over several thermal cycles. A similar treatment and coating for the fuel side of the interconnect also showed an exceptionally low resistance of one milliohm-cm{sup 2} in humidified hydrogen at 750 C, and was stable through multiple thermal cycles. Analysis of the scale after exposure to various atmospheres showed the presence of a stable composition. When exposed to a dual (air and hydrogen) atmosphere however, the scale composition contains a mixture of phases. Based on results to-date, the alloy selection and the treatment processes appear to be well suited for SOFC interconnect application.

S. Elangovan; S. Balagopal; M. Timper; I. Bay; D. Larsen; J. Hartvigsen

2003-10-01T23:59:59.000Z

496

REVIEW OF PLUTONIUM OXIDATION LITERATURE  

Science Conference Proceedings (OSTI)

A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles ( 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

Korinko, P.

2009-11-12T23:59:59.000Z

497

REVIEW OF PLUTONIUM OXIDATION LITERATURE  

SciTech Connect

A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

Korinko, P.

2009-11-12T23:59:59.000Z

498

Multifunctional Oxide - Programmaster.org  

Science Conference Proceedings (OSTI)

Toshihiko Tani, Toyota Motor Engineering and Manufacturing North America, Inc. Scope, Multifunctional oxide ceramics and thin films exhibit fascinating ...

499

Preparation and Characterization of Uranium Oxides in Support of the K Basin Sludge Treatment Project  

Science Conference Proceedings (OSTI)

Uraninite (UO2) and metaschoepite (UO3·2H2O) are the uranium phases most frequently observed in K Basin sludge. Uraninite arises from the oxidation of uranium metal by anoxic water and metaschoepite arises from oxidation of uraninite by atmospheric or radiolytic oxygen. Studies of the oxidation of uraninite by oxygen to form metaschoepite were performed at 21°C and 50°C. A uranium oxide oxidation state characterization method based on spectrophotometry of the solution formed by dissolving aqueous slurries in phosphoric acid was developed to follow the extent of reaction. This method may be applied to determine uranium oxide oxidation state distribution in K Basin sludge. The uraninite produced by anoxic corrosion of uranium metal has exceedingly fine particle size (6 nm diameter), forms agglomerates, and has the formula UO2.004±0.007; i.e., is practically stoichiometric UO2. The metaschoepite particles are flatter and wider when prepared at 21°C than the particles prepared at 50°C. These particles are much smaller than the metaschoepite observed in prolonged exposure of actual K Basin sludge to warm moist oxidizing conditions. The uraninite produced by anoxic uranium metal corrosion and the metaschoepite produced by reaction of uraninite aqueous slurries with oxygen may be used in engineering and process development testing. A rapid alternative method to determine uranium metal concentrations in sludge also was identified.

Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

2008-07-08T23:59:59.000Z

500

Impacts of humidity and temperature on the performance of transparent conducting zinc oxide.  

Science Conference Proceedings (OSTI)

The impact of humidity and temperature on a zinc oxide based transparent conducting oxide (TCO) was assessed under accelerated aging conditions. An in situ electroanalytical method was used to monitor the electrical properties for a conducting zinc oxide under controlled atmospheric (humidity, temperature and irradiation) conditions. A review of thin film photovoltaic (PV) literature has shown one major failure mode of cells/modules is associated with the ingress of water into modules in the field. Water contamination has been shown to degrade the performance of the TCO in addition to corroding interconnects and other conductive metals/materials associated with the module. Water ingress is particularly problematic in flexible thin film PV modules since traditional encapsulates such as poly(ethyl vinyl acetate) (EVA) have high water vapor transmission rates. The accelerated aging studies of the zinc oxide based TCOs will allow acceleration factors and kinetic parameters to be determined for reliability purposes.

Granata, Jennifer E.; Yaklin, Melissa A.; Schneider, Duane Allen; Staiger, Chad Lynn; Norman, Kirsten

2010-06-01T23:59:59.000Z