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Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Modern Records of Atmospheric Nitrous Oxide (N2O) and a 2000-year Ice-core  

NLE Websites -- All DOE Office Websites (Extended Search)

Modern Records of Atmospheric Nitrous Oxide (N2O) and a 2000-year Ice-core Modern Records of Atmospheric Nitrous Oxide (N2O) and a 2000-year Ice-core Record from Law Dome, Antarctica Introduction This page provides an introduction and links to records of atmospheric nitrous oxide (N2O) over the last 2000 years, emphasizing large data bases each representing currently active stations. Records in recent decades (time period depending on location) have been obtained from samples of ambient-air at remote locations, which represent changing global atmospheric conditions rather than influences of local sources. The longer (2000-year) record is from the Law Dome ice core in Antarctica. The ice-core record has been merged with modern annual data from Cape Grim, Tasmania to provide a 2000-year time series of annual values. A spline function has been fit to the data to provide a continuous time series of

2

A kinetics study of the atmospheric pressure CVD reaction of silane and nitrous oxide  

SciTech Connect

A mechanistic study of oxide deposition from silane and nitrous oxide between 495{sup 0}C and 690{sup 0}C was performed in a laminar flow, cool wall reactor. Results indicate the existence of two distinct chemical pathways. At high nitrous oxide concentrations, the deposition reaction is dominated by radical chain chemistry initiated by the decomposition of N/sub 2/O. At lower N/sub 2/O concentrations, the decomposition of silane to form silylene (SiH/sub 2/) initiates the deposition. Studies of the reaction of disilane and nitrous oxide confirmed the role of SiH/sub 2/ in the deposition. Reactions involving SiH/sub 2/ are used to explain the observed growth of sub-stoichiometric oxides under low N/sub 2/O conditions.

Chapple-Sokol, J.D.; Giunta, C.J.; Gordon, R.G. (Harvard Univ., Cambridge, MA (USA). Dept. of Chemistry)

1989-10-01T23:59:59.000Z

3

Role of Nitrous Oxide in Ambulatory Anaesthesia  

Science Journals Connector (OSTI)

As the oldest anaesthetic still in routine use, the continued role of nitrous oxide is frequently questioned. There are a few well-defined situations in which nitrous oxide is contraindicated or undesirable; i...

Sarah Billingham; Ian Smith

2014-12-01T23:59:59.000Z

4

Rapid thermal oxidation of silicon in mixtures of oxygen and nitrous oxide  

SciTech Connect

Oxidation in nitrous oxide by conventional hot wall furnace processing and by rapid thermal oxidation (RTO) has been a subject of much interest in recent years. RTO is a fundamentally different process than furnace oxidation, however, and the full effects of this type of processing on the oxidation kinetics are not well understood. Oxidation of silicon by RTO at a variety of pressures, temperatures, and oxidation gas mixtures has been studied. Although at lower temperatures (< 850 C) the atmospheric pressure oxidation rate in nitrous oxide is very close to that in oxygen, at higher temperatures the oxidation rate in nitrous oxide is much lower than that in oxygen. At lower pressures in a RTO process, the oxidation rate in nitrous oxide is higher than that in oxygen. The effect of the nitrogen incorporated in the oxide acting as a diffusion barrier has been proposed as the mechanism of temperature dependence for atmospheric pressure oxidation in nitrous oxide. This does not explain the effects seen at lower pressure,s however, The authors propose that some of the intermediate species produced in the decomposition of nitrous oxide into molecular nitrogen, molecular oxygen, and nitric oxide play a role in the initial stages of oxidation by RTO in nitrous oxide.

Grant, J.M.; Karim, Z. [Sharp Microelectronics Technology, Inc., Camas, WA (United States)

1996-12-01T23:59:59.000Z

5

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

6

Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, ...

Harris, Eliza

7

Development of a New Chemiluminescence Detector for Sub-ppm Level Nitrous Oxide  

Science Journals Connector (OSTI)

......atmosphere (15) and sea water (7), sometimes...sub-ppm level atmospheric N2O without any...through a standard gas generator (Model SGGU-72...Lodger, Jr. Atmospheric ni- trious oxide...Measurement of atmospheric nitrous oxide using...oxide in air and water using a 5A molecular......

Shun Araki; Shigetaka Suzuki; Masaaki Yamada; Hiroshi Suzuki; Toshiyuki Hobo

1978-06-01T23:59:59.000Z

8

MODELING THE EMISSIONS OF NITROUS OXIDE (N20) AND METHANE (CH 4) FROM THE  

E-Print Network (OSTI)

MODELING THE EMISSIONS OF NITROUS OXIDE (N20) AND METHANE (CH 4) FROM THE TERRESTRIAL BIOSPHERE;2 #12;MODELING THE EMISSIONS OF NITROUS OXIDE (N 20) AND METHANE (CH 4) FROM THE TERRESTRIAL BIOSPHERE cli- mate has on natural emissions of N2 0 and CH4 from the terrestrial biosphere to the atmosphere

9

Process Modeling of Global Soil Nitrous Oxide Emissions  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and is a major ozone-depleting substance. To understand and

Saikawa, E.

2011-09-01T23:59:59.000Z

10

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India  

E-Print Network (OSTI)

High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

Chatterjee, A.

11

Nitrous Oxide Emissions from a Municipal Landfill  

Science Journals Connector (OSTI)

Nitrous Oxide Emissions from a Municipal Landfill ... Due to the small area of landfills as compared to other land-use classes, the total N2O emissions from landfills are estimated to be of minor importance for the total emissions from Finland. ...

Janne Rinne; Mari Pihlatie; Annalea Lohila; Tea Thum; Mika Aurela; Juha-Pekka Tuovinen; Tuomas Laurila; Timo Vesala

2005-09-21T23:59:59.000Z

12

Nitrous oxide emissions from wastewater treatment processes  

Science Journals Connector (OSTI)

...specific ammonia oxidation rate. Symbols represent...Research Council (ARC) for funding this...correlated to its ammonia oxidation rate. 51 Arp, D...1146/annurev.micro.61.080706.093449...1146/annurev.micro.61.080706.093449...2004 Anaerobic oxidation of inorganic nitrogen...

2012-01-01T23:59:59.000Z

13

E-Print Network 3.0 - anesthetic nitrous oxide Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

such concentrations of anesthetics are safe... ), hypoxemia (eg, nitrogen and carbon monoxide), addiction (eg, nitrous oxide), or health effects resulting... from chronic exposure...

14

Laboratory flammability studies of mixtures of hydrogen, nitrous oxide, and air  

SciTech Connect

At the request of the Department of Energy and the Westinghouse Hanford Company, the Bureau of Mines has investigated the flammability of mixtures of hydrogen, nitrous oxide, and air. This work is relevant to the possible hazards of flammable gas generation from nuclear waste tanks at Hanford, WA. The tests were performed in a 120-L spherical chamber under both quiescent and turbulent conditions using both electric spark and pyrotechnic ignition sources. The data reported here for binary mixtures of hydrogen in air generally confirm the data of previous investigators, but they are more comprehensive than those reported previously. The results clarify to a greater extent the complications associated with buoyancy, turbulence, and selective diffusion. The data reported here for ternary mixtures of hydrogen and nitrous oxide in air indicate that small additions of nitrous oxide (relative to the amount of air) have little effect, but that higher concentrations of nitrous oxide (relative to air) significantly increase the explosion hazard.

Cashdollar, K L; Hertzberg, M; Zlochower, I A; Lucci, C E; Green, G M; Thomas, R A [Bureau of Mines, Pittsburgh, PA (United States). Pittsburgh Research Center

1992-06-26T23:59:59.000Z

15

Nitrous Oxide Fluxes from the Gulf of Mexico "Dead Zone" Primary Investigator: Craig Stow -NOAA GLERL  

E-Print Network (OSTI)

forecasts require accurate estimates of greenhouse gas emission rates. Currently, there are few measurements Management Research Laboratory Overview Nitrous oxide is a potent greenhouse gas with a global warming oxide is a potent greenhouse gas with a global warming potential ~300 times that of carbon dioxide

16

CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING  

E-Print Network (OSTI)

CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING in strategies for climate protection. 1. Introduction Carbon sequestration has been highlighted recently concentration of carbon dioxide (CO2) in the atmo- sphere include sequestering carbon (C) in soils

17

EMISSIONS OF NITROUS OXIDE AND METHANE FROM CONVENTIONAL AND ALTERNATIVE FUEL MOTOR VEHICLES  

E-Print Network (OSTI)

-produced electricity for battery electric vehicles. Already, vehicles powered by compressed natural gas, propane. LIPMAN AND MARK A. DELUCCHI example, promising strategies for powering motor vehicles with reduced GHGEMISSIONS OF NITROUS OXIDE AND METHANE FROM CONVENTIONAL AND ALTERNATIVE FUEL MOTOR VEHICLES

Kammen, Daniel M.

18

Sensitive detection of methane and nitrous oxide isotopomers using a continuous wave quantum cascade laser  

Science Journals Connector (OSTI)

A continuous wave quantum cascade laser (QCL), operating near 8.1 ?m...4) and nitrous oxide (N2O) stable isotopes. Several rotational transitions of 14N2 16O, 15N14N16O, 14N2 18O,

G. Gagliardi; F. Tamassia; P. De Natale…

2002-06-01T23:59:59.000Z

19

Estimation of nitrous oxide emissions (GHG) from wastewater treatment plants using closed-loop mass balance and data reconciliation  

Science Journals Connector (OSTI)

The amount of greenhouse gases (GHG), especially, nitrous oxide (N2O) emitted from wastewater treatment plants (WWTP) using data reconciliation and closed-loop mass balance was estimated. This study is based on a...

JungJin Lim; Boddupalli Sankarrao; TaeSeok Oh…

2012-09-01T23:59:59.000Z

20

Nitrous oxide (N?O) isotopic composition in the troposphere : instrumentation, observations at Mace Head, Ireland, and regional modeling  

E-Print Network (OSTI)

Nitrous oxide (N?O) is a significant greenhouse gas and main contributor to stratospheric ozone destruction. Surface measurements of N?O mole fractions have been used to attribute source and sink strengths, but large ...

Potter, Katherine Ellison

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Emissions of carbon dioxide, methane and nitrous oxide from soil receiving urban wastewater for maize (Zea mays L.) cultivation  

Science Journals Connector (OSTI)

We investigated how amending maize with wastewater at 120 kg N ha?1 affected crop growth, soil characteristics and emissions of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) compared to plants ferti...

Fabián Fernández-Luqueño; Verónica Reyes-Varela…

2010-06-01T23:59:59.000Z

22

Nitrous Oxide as a Scavenger for Electrons in the Radiolysis of Propane  

Science Journals Connector (OSTI)

... (~400 ml.) using a cobalt-60 ¡-ray source. The dose-rate in propane was 5 ´ 1014 eV ml,?1 min?1 (nitrous oxide dosimeter: assuming ... eV2 and using an experimentally determined value of 1.42 for the stopping power of propane relative to N2O). Total doses were 1016?1017 eV ml.?1. The results ...

G. R. A. JOHNSON; J. M. WARMAN

1964-07-04T23:59:59.000Z

23

Methane and nitrous oxide in the ice core record  

Science Journals Connector (OSTI)

...observed changes would lead to other feedbacks in atmospheric chemistry, which need to be included in future coupled Earth system models. The pre-industrial Holocene also shows interesting and significant changes, and a debate still exists about...

2007-01-01T23:59:59.000Z

24

AT A GLANCE Title: Hydrogen, Methane and Nitrous oxide: Trend  

E-Print Network (OSTI)

to increases in atmospheric molecular hydrogen (H2) and reductions of fossil fuel burning emissions burning emissions have been calculated with one of the models. MAIN RESULTS Improved methane emissions (from ruminants and waste) is larger. First robust estimates of the uptake of hydrogen by

Haak, Hein

25

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

26

Effect of Thermal Neutron Irradiation on Oxide Catalysts for the Decomposition of Nitrous Oxide  

Science Journals Connector (OSTI)

... alpha-particles which are produced by an (n, a) reaction with lithium-6 or boron-10 atoms. Nickel oxide contains excess oxygen ions as a £-type semiconductor and probably ...

YASUKAZU SAITO; YUKIO YONEDA; SHOJI MAKISHIMA

1959-02-07T23:59:59.000Z

27

Regional-Scale Assessment of Nitrous Oxide Emissions within the US Corn Belt: The Impact of Precipitation and Agricultural Drainage on Indirect Emissions  

E-Print Network (OSTI)

Regional-Scale Assessment of Nitrous Oxide Emissions within the US Corn Belt: The Impact of Precipitation and Agricultural Drainage on Indirect Emissions Tim Griffis1, Xuhui Lee2, John Baker3, Peter, but mitigation strategies have been limited by the large uncertainties in both direct and indirect emission

Minnesota, University of

28

Modeling Seasonal Variations in Carbon Dioxide and Nitrous Oxide in the Vadose Zone  

Science Journals Connector (OSTI)

...temperature, and soil atmosphere composition were being monitored was specifically...and CEL pools were predominant in the composition of the maize residue and were mainly...also taken into account. agriculture agrochemicals Avignon France Cambisols CANTIS carbon...

P. Cannavo; F. Lafolie; B. Nicolardot; P. Renault

29

Nitrous oxide emissions. Topical report, July 1, 1990--June 30, 1993  

SciTech Connect

Published N{sub 2}O emissions data for experimental studies examining large numbers of coals are generally scarce at the pilot-scale fluidized-bed combustion (FBC) level, although some data are available at the laboratory scale. The primary objective of this study was to determine the atmospheric contribution of N{sub 2}O derived from coal combustion. Additionally, the goal was to establish a comprehensive engineering model to assist in the prediction of N{sub 2}O emissions based upon operating and design considerations. To meet the overall objectives of determining the overall contribution of N{sub 2}O derived from FBC and developing an engineering model seven tasks were originally proposed. The objective of each task as originally proposed and finally executed is presented in this topical report. The seven tasks were: (1) literature survey; (2) equipment design and test plan development; (3) experimental techniques; (4) pilot-scale determination of the impacts of coal properties and operating conditions on N{sub 2}O emissions; (5) role of coal char on N{sub 2}O formation and destruction; (6) homogeneous versus heterogeneous reactions; and (7) modeling of N{sub 2}O emissions.

Collings, M.E.; Mann, M.D.

1993-12-01T23:59:59.000Z

30

Atmospheric Oxidation of Coal at Moderate Temperatures. Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals.  

Science Journals Connector (OSTI)

Atmospheric Oxidation of Coal at Moderate Temperatures. ... Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals. ...

L Schmidt; J Elder; J Davis

1940-01-01T23:59:59.000Z

31

The Oxidation of Ferritic Stainless Steels in Simulated Solid-Oxide Fuel-Cell Atmospheres  

Science Journals Connector (OSTI)

The cyclic oxidation of a variety of chromia-forming ferritic stainless steels has been studied in the temperature range 700–900°C in atmospheres relevant to solid-oxide fuel-cell operation. The most detriment...

J. E. Hammer; S. J. Laney; R. W. Jackson; K. Coyne; F. S. Pettit…

2007-02-01T23:59:59.000Z

32

Determinations of Carbon Dioxide and Methane by Dual Catalyst Flame Ionization Chromatography and Nitrous Oxide by Electron Capture Chromatography  

Science Journals Connector (OSTI)

......equilibrate with atmospheric pressure through...applications involving atmospheric analyses, the instrument...electrolytically from distilled water by a General Electric...Massachusetts) hydrogen generator. The gas is further...the analysis. The water formed by the palladium...737-1-B "clean air generator," a preparative......

Ray F. Weiss

1981-12-01T23:59:59.000Z

33

Nitrogen Oxides in the Nocturnal Boundary Layer: Chemistry of Nitrous Acid (HONO) and the Nitrate Radical (N03)  

SciTech Connect

Summary Chemical processes occurring at night in the lowest part of the urban atmosphere, the so called nocturnal boundary layer (NBL), can influence the composition of the atmosphere during the night as well as the following day. They may impact the budgets of some of the most important pollutants, such as ozone and nitrogen oxides, as well as influence size and composition of particular matter. Few studies have thus far concentrated on the nocturnal chemistry of the urban NBL, most likely due to the strong influence of vertical transport and mixing, which requires the measurement of trace gas profiles instead of simple point observations. Motivated by our lack of observations and understanding of nocturnal chemistry, the focus of this project was the study of the vertical distribution of trace gases and the altitude dependence of nocturnal chemistry under polluted conditions through field observations and modeling studies. The analysis of three field experiments (TEXAQS, Houston, 2000; Phoenix Sunrise Ozone Experiment, 2001; NAPOX, Boston, 2002), two of which were performed in this project, showed that ozone concentrations typically increase with height in the lowest 150m, while NO2 typically decreases. NO3, the dominant nocturnal radical species, showed much higher concentrations in the upper part of the NBL, and was often not present at the ground. With the help of a one-dimensional chemical transport model, developed in this project, we found that the interaction of ground emissions of NOx and hydrocarbons, together with their vertical transport, is responsible for the vertical profiles. The dominant chemical reactions influencing ozone, NO2 and NO3 are the reaction of ozone and NO3 with freshly emitted NO. Sensitivity studies with our model showed that the magnitude of the trace gas gradients depend both on the emission rates and the vertical stability of the NBL. Observations and model analysis clearly show that nocturnal chemistry in urban areas is altitude dependent. Measurements at one altitude, for example at the ground, where most air quality monitoring stations are located, are not representative for the rest of the NBL. Our model also revealed that radical chemistry is, in general, altitude dependent at night. We distinguish three regions: an unreactive, NO rich, ground layer; an upper, O3 and NO3 dominated layer, and a reactive mixing layer, where RO2 radicals are mixed from aloft with NO from the ground. In this reactive layer an active radical chemistry and elevated OH radical levels can be found. The downward transport of N2O5 and HO2NO2, followed by their thermal decay, was also identified as a radical source in this layer. Our observations also gave insight into the formation of HONO in the NBL. Based on our field experiments we were able to show that the NO2 to HONO conversion was relative humidity dependent. While this fact was well known, we found that it is most likely the uptake of HONO onto surfaces which is R.H. dependent, rather than the NO2 to HONO conversion. This finding led to the proposal of a new NO2 to HONO conversion mechanism, which is based on solid physical chemical principles. Noteworthy is also the observation of enhanced NO2 to HONO conversion during a dust storm event in Phoenix. The final activity in our project investigated the influence of the urban canopy, i.e. building walls and surfaces, on nocturnal chemistry. For the first time the surface area of a city was determined based on a Geographical Information System database of the city of Santa Monica. The surface to volume areas found in this study showed that, in the 2 lower part of the NBL, buildings provide a much larger surface area than the aerosol. In addition, buildings take up a considerable amount of the volume near the ground. The expansion of our model and sensitivity studies based on the Santa Monica data revealed that the surface area of buildings considerably influences HONO levels in urban areas. The volume reduction leads to a decrease of O3 and an increase of NO2 near the ground due to the stronger impact o

Jochen Stutz

2005-05-24T23:59:59.000Z

34

Treatment of nitrous off-gas from dissolution of sludges  

SciTech Connect

Several configurations have been reviewed for the NO{sub x} removal of dissolver off-gas. A predesign has been performed and operating conditions have been optimized. Simple absorption columns seems to be sufficient. NHC is in charge of the treatment of sludges containing mainly uranium dioxide and metallic uranium. The process is based on the following processing steps a dissolution step to oxidize the pyrophoric materials and to dissolve radionuclides (uranium, plutonium, americium and fission products), a solid/liquid separation to get rid of the insoluble solids (to be disposed at ERDF), an adjustment of the acid liquor with neutronic poisons, and neutralization of the acid liquor with caustic soda. The dissolution step generates a flow of nitrous fumes which was evaluated in a previous study. This NO{sub x} flow has to be treated. The purpose of this report is to study the treatment process of the nitrous vapors and to 0482 perform a preliminary design. Several treatment configurations are studied and the most effective process option with respect to the authorized level of discharge into atmosphere is discussed. As a conclusion, recommendations concerning the unit preliminary design are given.

Flament, T.A.

1998-08-25T23:59:59.000Z

35

E-Print Network 3.0 - atmospheric oxidation by-products Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

only a few electrode materials are known... exhibits some selectivity towards the reduction of nitric oxide in a net oxidising atmosphere. Several... and in the nitric oxide...

36

Halocarbon and Other Atmospheric Trace Species (HATS) | Data.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Halocarbon and Other Atmospheric Trace Species (HATS) Halocarbon and Other Atmospheric Trace Species (HATS) Agriculture Community Menu DATA APPS EVENTS DEVELOPER STATISTICS COLLABORATE ABOUT Agriculture You are here Data.gov » Communities » Agriculture » Data Halocarbon and Other Atmospheric Trace Species (HATS) Dataset Summary Description The general mission of the Halocarbons and other Atmospheric Trace Species group is to quantify the distributions and magnitudes of sources and sinks for atmospheric nitrous oxide (N2O) and halogen containing compounds. HATS utilizes numerous types of platforms, including ground-based stations, towers, ocean vessels, aircraft, and balloons, to accomplish its mission. For a detailed mission statement, consult our FAQ. Tags {"nitrous oxide","sulfur hexaflouride",CFC-11,CFC-12,CFC-113,CCl4,CH3CCl3,CH3Cl,halon-1211,HCFC-22,HCFC-142b,halocarbons,chromatograph,aircraft,balloons,vessels,ships,towers,"natural resources",environment,air,"GHG "}

37

Mechanistic, sensitivity, and uncertainty studies of the atmospheric oxidation of dimethylsulfide  

E-Print Network (OSTI)

The global-scale emissions and reactivity of dimethylsulfide (CH3SCH3, DMS) make it an integral component in the atmospheric sulfur cycle. DMS is rapidly oxidized in the atmosphere by a complex gas-phase mechanism involving ...

Lucas, Donald David, 1969-

2003-01-01T23:59:59.000Z

38

Plasma-Assisted Reduction of Graphene Oxide at Low Temperature and Atmospheric Pressure for Flexible Conductor Applications  

Science Journals Connector (OSTI)

Plasma-Assisted Reduction of Graphene Oxide at Low Temperature and Atmospheric Pressure for Flexible Conductor Applications ... The method allows rapid deoxygenation of bulk graphite oxide (GO) in an atmosphere of ... ...

Seung Whan Lee; Cecilia Mattevi; Manish Chhowalla; R. Mohan Sankaran

2012-02-22T23:59:59.000Z

39

Denitrifying Alphaproteobacteria from the Arabian Sea That Express nosZ, the Gene Encoding Nitrous Oxide Reductase, in Oxic and Suboxic Waters  

Science Journals Connector (OSTI)

...the present study a closely related (99% nucleotide identity...clone BATS14_163), a closely related denitrifier (Fig. 2), were...atmospheric carbon dioxide. Policy document 12/05. Royal Society...liberates the climate-changing gas dimethylsulfide in several marine...

Michael Wyman; Sylvia Hodgson; Clare Bird

2013-02-08T23:59:59.000Z

40

Modeling of UO{sub 2} oxidation in steam atmosphere  

SciTech Connect

Nuclear fuel oxidation is an important phenomenon affecting fission product behavior. As indicated by a number of studies, uranium dioxide shows a very wide range of nonstoichiometric states. In steam, fuel oxidation produces a hyperstoichiometric composition, changing the transport properties. Variation of stoichiometry changes diffusion coefficients for oxygen, noble gases, and fission products substantially, affecting the release of fission products.

Dobrov, B.V.; Likhanskii, V.V. [Triniti Research Center, Triniti, Moscow (Russian Federation); Ozrin, V.D. [Nuclear Safety Institute IBREA, Moscow (Russian Federation)] [and others

1997-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Highly efficient oxidation of silicon at low temperatures using atmospheric pressure plasma  

Science Journals Connector (OSTI)

Silicon oxide ( Si O 2 ) layers were formed with initial oxidation rates in the range of 6.2 – 14.1 nm ? min in the temperature range of 150 – 400 ° C by oxidizing Si(001) wafers. Such a high-rate and low-temperature oxidation was realized by using a stable glow He ? O 2 plasma excited at atmospheric pressure by a 150 MHz very high-frequency power. Increasing the temperature led to both the higher oxidation rate and the better quality of Si O 2 and Si O 2 ? Si interface. The oxidation at 400 ° C showed an interface trap density of 6.2 × 10 10 eV ? 1 cm ? 2 which is considerably lower than that in a radical oxidation process using low-pressure He ? O 2 plasma at the same temperature.

Hiroaki Kakiuchi; Hiromasa Ohmi; Makoto Harada; Heiji Watanabe; Kiyoshi Yasutake

2007-01-01T23:59:59.000Z

42

Highly efficient oxidation of silicon at low temperatures using atmospheric pressure plasma  

SciTech Connect

Silicon oxide (SiO{sub 2}) layers were formed with initial oxidation rates in the range of 6.2-14.1 nm/min in the temperature range of 150-400 deg. C by oxidizing Si(001) wafers. Such a high-rate and low-temperature oxidation was realized by using a stable glow He/O{sub 2} plasma excited at atmospheric pressure by a 150 MHz very high-frequency power. Increasing the temperature led to both the higher oxidation rate and the better quality of SiO{sub 2} and SiO{sub 2}/Si interface. The oxidation at 400 deg. C showed an interface trap density of 6.2x10{sup 10} eV{sup -1} cm{sup -2}, which is considerably lower than that in a radical oxidation process using low-pressure He/O{sub 2} plasma at the same temperature.

Kakiuchi, Hiroaki; Ohmi, Hiromasa; Harada, Makoto; Watanabe, Heiji; Yasutake, Kiyoshi [Department of Precision Science and Technology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan)

2007-02-26T23:59:59.000Z

43

Heterogeneous Oxidation of Carbonyl Sulfide on Atmospheric Particles and Alumina  

Science Journals Connector (OSTI)

The specifications of gases used in this experiment are as follows without further purification:? OCS (2%, OCS/N2, Scott Specialty Gases Inc.), O2 (99.99% purity, Beijing AP BEIFEN Gases Inc.), H2 (99.999% purity, GCD-300B high purity hydrogen generator, China Bchp Analytical Technology Co. Ltd.). ... To confirm our assignment about the surface SO42- species, 1.0 g of preoxidized Al2O3 sample after exposure to a flow of 500 ppm OCS + 95% O2 at 298 K for 2 h was analyzed by ion chromatography (DIONEX, CA); 2.43 mg/L SO42- can be detected (sample stirred with 100 mL deionized water, and then filtered through a 0.45-?m filter). ... Since the real atmospheric particle sample has relatively high surface area (4.8 m2/g), its influence on the conversion of OCS in atmosphere is not neglectable. ...

Hong He; Junfeng Liu; Yujing Mu; Yunbo Yu; Meixue Chen

2005-11-05T23:59:59.000Z

44

Composition of a thermal plasma formed from PTFE with copper in non-oxidant atmosphere.  

E-Print Network (OSTI)

1 Composition of a thermal plasma formed from PTFE with copper in non-oxidant atmosphere. Part I the minimization of given thermodynamic functions or mass action laws even with plasmas out of thermal equilibrium- . Key Words: circuit breakers, SF6, PTFE, carbon formation, copper, dielectric gas, plasma composition

Paris-Sud XI, Université de

45

Global oceanic production of nitrous oxide  

Science Journals Connector (OSTI)

...1sigma) based on gas-exchange parametrization...upper 500 m of the water column. -The...its effect on solubility. -Our estimates...emissions based on gas-exchange parametrization...load of organic nitrogen. This fertilization...also affect the solubility of N2O. Rising...created by warming water masses after their...

2012-01-01T23:59:59.000Z

46

3, 729764, 2006 Nitrous oxide in the  

E-Print Network (OSTI)

. At the time of our cruise, water renewal had proceeded to the eastern Gotland Basin, whereas the western Gotland Basin was still unaffected by the inflow. The deep water renewal was detectable concentrations: Shallow stations in the10 Kiel Bight and Pomeranian Bight were well-ventilated with uniform N2O

Paris-Sud XI, Université de

47

Nitrous oxide emissions from wastewater treatment processes  

Science Journals Connector (OSTI)

...samples followed by GC analysis has been used in both laboratory scale reactors and full-scale plants...two laboratory scale reactors. Foley et al. [23...measurements. Combining the analyses of both the microsensor...significantly increases the reliability of data. Similar to...

2012-01-01T23:59:59.000Z

48

Fabrication of superconducting metal-oxide textiles by heating impregnated polymeric material in a weakly oxidizing atmosphere  

SciTech Connect

A process is described for producing crystalline fibers, textiles or shapes comprised of YBa[sub 2]Cu[sub 3]O[sub 7[minus]x] where x varies from about 0 to about 0.4, said process comprising: (a) impregnating a preformed organic polymeric material with three metal compounds to provide metal elements in said material in substantially the atomic ratio occurring in said YBa[sub 2]Cu[sub 3]O[sub 7[minus]x]; (b) heating said impregnated material in a weakly oxidizing atmosphere containing from about 0.05% to about 2% oxygen by volume to a temperature sufficiently high to at least partially pyrolize and oxidize said organic material and at least partially oxidize said metal compounds substantially without ignition of said organic material and without formation of a molten phase or reaching a decomposition temperature of said YBa[sub 2]Cu[sub 3]O[sub 7[minus]x]; and (c) cooling the resulting material in at least a moderately oxidizing atmosphere to room temperature so as to obtain said fibers, textiles or shapes.

Van den Sype, J.S.

1993-07-13T23:59:59.000Z

49

Optimization of a compact photoacoustic quantum cascade laser spectrometer for atmospheric flux measurements: application to the detection of methane and nitrous oxide  

Science Journals Connector (OSTI)

Room temperature (RT) quantum cascade lasers (QCL) are now available even in ... in the 8 ?m range. The first laser had already been used to calibrate the...4...with a 1s integration time per point was demonstrat...

A. Grossel; V. Zéninari; B. Parvitte; L. Joly; D. Courtois

2007-08-01T23:59:59.000Z

50

Effects of an oxidizing atmosphere in a spent fuel packaging facility  

SciTech Connect

Sufficient oxidation of spent fuel can cause a cladding breach to propagate, resulting in dispersion of fuel particulates and gaseous radionuclides. The literature for spent fuel oxidation in storage and disposal programs was reviewed to evaluate the effect of an oxidizing atmosphere in a preclosure packaging facility on (1) physical condition of the fuel and (2) operations in the facility. Effects such as cladding breach propagation, cladding oxidation, rod dilation, fuel dispersal, {sup 14}C and {sup 85}Kr release, and crud release were evaluated. The impact of these effects, due to oxidation, upon a spent fuel handling facility is generally predicted to be less than the impact of similar effects due to fuel rod breached during handling in an inert-atmosphere facility. Preliminary temperature limits of 240{degree}C and 227{degree}C for a 2-week or 4-week handling period and 175{degree}C for 2-year lag storage would prevent breach propagation and fuel dispersal. Additional data that are needed to support the assumptions in this analysis or complete the database were identified.

Einziger, R.E.

1991-09-01T23:59:59.000Z

51

Importance of atmospheric inputs and Fe-oxides in controlling soil uranium budgets and behavior along a Hawaiian chronosequence  

E-Print Network (OSTI)

Importance of atmospheric inputs and Fe-oxides in controlling soil uranium budgets and behavior: D. Rickard Abstract A long-term budget of uranium calculated for a chronosequence of Hawaiian soils extractions on the same soils shows a strong association between Fe-oxides and uranium, especially

Derry, Louis A.

52

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2: Implications for inversion analyses  

E-Print Network (OSTI)

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2 carbon emissions. We used TransCom3 annual mean simulations from three transport models to evaluate carbon emission and oxidation processes in deriving inversion estimates of CO2 surface fluxes. Citation

Krakauer, Nir Y.

53

On-line coating of glass with tin oxide by atmospheric pressure chemical vapor deposition.  

SciTech Connect

Atmospheric pressure chemical vapor deposition (APCVD) of tin oxide is a very important manufacturing technique used in the production of low-emissivity glass. It is also the primary method used to provide wear-resistant coatings on glass containers. The complexity of these systems, which involve chemical reactions in both the gas phase and on the deposition surface, as well as complex fluid dynamics, makes process optimization and design of new coating reactors a very difficult task. In 2001 the U.S. Dept. of Energy Industrial Technologies Program Glass Industry of the Future Team funded a project to address the need for more accurate data concerning the tin oxide APCVD process. This report presents a case study of on-line APCVD using organometallic precursors, which are the primary reactants used in industrial coating processes. Research staff at Sandia National Laboratories in Livermore, CA, and the PPG Industries Glass Technology Center in Pittsburgh, PA collaborated to produce this work. In this report, we describe a detailed investigation of the factors controlling the growth of tin oxide films. The report begins with a discussion of the basic elements of the deposition chemistry, including gas-phase thermochemistry of tin species and mechanisms of chemical reactions involved in the decomposition of tin precursors. These results provide the basis for experimental investigations in which tin oxide growth rates were measured as a function of all major process variables. The experiments focused on growth from monobutyltintrichloride (MBTC) since this is one of the two primary precursors used industrially. There are almost no reliable growth-rate data available for this precursor. Robust models describing the growth rate as a function of these variables are derived from modeling of these data. Finally, the results are used to conduct computational fluid dynamic simulations of both pilot- and full-scale coating reactors. As a result, general conclusions are reached concerning the factors affecting the growth rate in on-line APCVD reactors. In addition, a substantial body of data was generated that can be used to model many different industrial tin oxide coating processes. These data include the most extensive compilation of thermochemistry for gas-phase tin-containing species as well as kinetic expressions describing tin oxide growth rates over a wide range of temperatures, pressures, and reactant concentrations.

Allendorf, Mark D.; Sopko, J.F. (PPF Industries, Pittsburgh, PA); Houf, William G.; Chae, Yong Kee; McDaniel, Anthony H.; Li, M. (PPF Industries, Pittsburgh, PA); McCamy, J.W. (PPF Industries, Pittsburgh, PA)

2006-11-01T23:59:59.000Z

54

High-temperature corrosion of metallic alloys in an oxidizing atmosphere containing NaCl  

SciTech Connect

A particular heat-exchanger application involved metallic alloys exposed to flue gases of an aluminum remelt furnace. Because the flue gases might contain NaCl and other halides, the corrosion behavior of the alloys was to be investigated. Planned direct exposure of candidate alloys to the flue gases, however, was not conducted because of premature termination of the project. Complementary laboratory testing was conducted on seven commercially available alloys and two nickel aluminides. These materials were exposed to an oxidizing atmosphere containing 0.06 wt % NaCl for 1100 h at 1000/degree/C. Most of the alloy exhibited grain-boundary attack, which resulted in complete oxidation of enveloped grains. The alloys Incoloy MA-956, Incoloy 800, Inconel 625, Inconel 601, Hastelloy X, Haynes 188, and nickel aluminide IC-50 were substantially more corroded than Alloy 214 and nickel aluminide IC-221. The latter two alloys, therefore, would probably be superior to the others in application involving flue gases containing NaCl. Strength fabricability, and weldability, which are briefly discussed, would also affect selection of materials. 8 refs., 12 figs., 5 tabs.

Federer, J.I.

1989-02-01T23:59:59.000Z

55

Spatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic composition of atmospheric nitrate  

E-Print Network (OSTI)

exchange between gas-phase precursors and variability in reactive nitrogen sources. These findings product of NOx in the atmosphere. Due to its exceptionally high solubility in water, nitrate is rapidly deSpatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic

56

Low-temperature formation of Si O 2 layers using a two-step atmospheric pressure plasma-enhanced deposition-oxidation process  

Science Journals Connector (OSTI)

Silicon oxide ( Si O 2 ) layers were fabricated at low temperatures ( ? 400 ° C ) by combining the deposition of hydrogenated amorphous Si ( a - Si : H ) with its oxidation using atmospheric pressure plasmas excited by a 150 MHz very high-frequency (VHF) power. The surface excitation by the atmospheric pressure VHF plasma was capable of reducing the temperature for the hydrogen effusion from a - Si : H . As a result a porous a - Si : H film containing a large amount of hydrogen could be transformed into a stoichiometric Si O 2 with an approximately 24% increase in oxidation rate compared with the oxidation of Si(001) at a temperature of 400 ° C .

Hiroaki Kakiuchi; Hiromasa Ohmi; Makoto Harada; Heiji Watanabe; Kiyoshi Yasutake

2007-01-01T23:59:59.000Z

57

Availability of Nitrous Nitrogen to Plants.  

E-Print Network (OSTI)

V, .=DL ULL LI~C a~ailability 01 ILILKLL~: IIILIU~~I~ LU curn, l~aa, 8011 31LY3 1 27.3 .53 .I447 1 I 1 5: 1250 .I349 ic nitrogen ( 37.P' 1 -59 1 .2195 ru.. nv / 36.6 .57 1 .2086 I -2141 1 .O7b/ I 1. gm. nitrous nitrogen 30.2 1 .64 1 .I933 1... .12 -.01 ' .09 V1 -- I w 01 ---- I ------ el M - 1 --O6 X * ---- ------ U1 $ !z - --- i d $ --- - I -20 2 Y * F - I M 4 M .34 I --- .20 M .14 5 nitrogen --- --- -.02 .14 -.48 -.01 -12 .18 .OS...

Fraps, G. S. (George Stronach); Sterges, A. J.

1935-01-01T23:59:59.000Z

58

Low refractive index silicon oxide coatings at room temperature using atmospheric-pressure very high-frequency plasma  

Science Journals Connector (OSTI)

Low refractive index silicon oxide films were deposited using atmospheric-pressure He/SiH4/CO2 plasma excited by a 150-MHz very high-frequency power. Significant increase in deposition rate at room temperature could prevent the formation of dense SiO2 network, decreasing refractive index of the resulting film effectively. As a result, a silicon oxide film with the lowest refractive index, n = 1.24 at 632.8 nm, was obtained with a very high deposition rate of 235 nm/s. The reflectance and transmittance spectra showed that the low refractive index film functioned as a quarter-wave anti-reflection coating of a glass substrate.

H. Kakiuchi; H. Ohmi; Y. Yamaguchi; K. Nakamura; K. Yasutake

2010-01-01T23:59:59.000Z

59

Chemistry of carbonaceous aerosols : studies of atmospheric processing and OH-initiated oxidation  

E-Print Network (OSTI)

Carbonaceous aerosols are among the most prevalent yet least understood constituents of the atmosphere, particularly in urban environments. We have performed analyses of field samples and laboratory studies to probe the ...

Johnson, Kirsten S. (Kirsten Sue)

2008-01-01T23:59:59.000Z

60

Eddy-covariance observations of the atmosphere-biosphere exchange of nitrogen oxides  

E-Print Network (OSTI)

and Kesselmeier, J. : Nitrogen dioxide (NO 2 ) uptake byM. : Leaf uptake of nitrogen dioxide (NO 2 ) in a tropicalMorikawa, H. : Atmospheric nitrogen dioxide gas is a plant

Min, Kyung-Eun

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Development of metallic substrate supported planar solid oxide fuel cells fabricated by atmospheric plasma spraying  

Science Journals Connector (OSTI)

A planar solid oxide fuel cell (SOFC) consisting of a cell supported with a porous metallic substrate and a metallic separator has been developed. In the fabrication of the cell, anodes and electrolytes were form...

Shunji Takenoiri; Naruaki Kadokawa; Kazuo Koseki

2000-09-01T23:59:59.000Z

62

Nanostructured europium oxide thin films deposited by pulsed laser ablation of a metallic target in a He buffer atmosphere  

SciTech Connect

Nanostrucured europium oxide and hydroxide films were obtained by pulsed Nd:YAG (532 nm) laser ablation of a europium metallic target, in the presence of a 1 mbar helium buffer atmosphere. Both the produced film and the ambient plasma were characterized. The plasma was monitored by an electrostatic probe, for plume expansion in vacuum or in the presence of the buffer atmosphere. The time evolution of the ion saturation current was obtained for several probe to substrate distances. The results show the splitting of the plume into two velocity groups, being the lower velocity profile associated with metal cluster formation within the plume. The films were obtained in the presence of helium atmosphere, for several target-to-substrate distances. They were analyzed by Rutherford backscattering spectrometry, x-ray diffraction, and atomic force microscopy, for as-deposited and 600 deg. C treated-in-air samples. The results show that the as-deposited samples are amorphous and have chemical composition compatible with europium hydroxide. The thermally treated samples show x-ray diffraction peaks of Eu{sub 2}O{sub 3}, with chemical composition showing excess oxygen. Film nanostructuring was shown to be strongly correlated with cluster formation, as shown by velocity splitting in probe current versus time plots.

Luna, H.; Franceschini, D. F.; Prioli, R.; Guimaraes, R. B.; Sanchez, C. M.; Canal, G. P.; Barbosa, M. D. L.; Galvao, R. M. O. [Instituto de Fisica, Universidade Federal do Rio de Janeiro, Cx. Postal 68528, Rio de Janeiro, RJ 21941-972 (Brazil); Instituto de Fisica, Universidade Federal Fluminense, Niteroi, RJ 24210-346 (Brazil); Departamento de Fisica, Pontificia Universidade Catolica do Rio de Janeiro, Rua Marques de Sao Vicente 225, 22453-970, Rio de Janeiro, RJ (Brazil); Instituto de Fisica, Universidade Federal Fluminense, Niteroi, RJ 24210-346 (Brazil); Centro Brasileiro de Pesquisas Fisicas, Laboratorio de Plasmas Aplicados, Rua Xavier Sigaud 150, 22290-180, Rio de Janeiro, RJ (Brazil); Instituto de Fisica, Departamento de Fisica Nuclear, Universidade de Sao Paulo, Caixa Postal 66328, 05315-970, Sao Paulo, SP (Brazil); Centro Brasileiro de Pesquisas Fisicas, Laboratorio de Plasmas Aplicados, Rua Xavier Sigaud 150, 22290-180, Rio de Janeiro, RJ (Brazil)

2010-09-15T23:59:59.000Z

63

Nitrous Oxide Production in the Gulf of Mexico Hypoxic Zone  

E-Print Network (OSTI)

% of the annual freshwater discharge, 98.5% of the annual nitrogen load, and 98% of the annual phosphorus load into the zone most likely to influence hypoxia (Rabalais et al. 2007). Ecosystem responses to hypoxia include diminished biodiversity and altered...

Visser, Lindsey A.

2010-10-12T23:59:59.000Z

64

Nitrous oxide emission from denitrification in stream and river networks  

Science Journals Connector (OSTI)

...82071; e Environmental Sciences Division, Oak Ridge National Laboratory , Oak Ridge, TN 37831; f Department of Ecology and Evolutionary Biology...experiments on their lands. We also acknowledge the many workers who helped with the Lotic Intersite Nitrogen experiments...

Jake J. Beaulieu; Jennifer L. Tank; Stephen K. Hamilton; Wilfred M. Wollheim; Robert O. Hall; Jr.; Patrick J. Mulholland; Bruce J. Peterson; Linda R. Ashkenas; Lee W. Cooper; Clifford N. Dahm; Walter K. Dodds; Nancy B. Grimm; Sherri L. Johnson; William H. McDowell; Geoffrey C. Poole; H. Maurice Valett; Clay P. Arango; Melody J. Bernot; Amy J. Burgin; Chelsea L. Crenshaw; Ashley M. Helton; Laura T. Johnson; Jonathan M. O'Brien; Jody D. Potter; Richard W. Sheibley; Daniel J. Sobota; Suzanne M. Thomas

2011-01-01T23:59:59.000Z

65

Decomposition of nitrous oxide on AlFe-PILC catalyst  

Science Journals Connector (OSTI)

Two AlFe-PILC catalysts were prepared with different OH/metal...2O) decomposition reactions. The 100% conversion of N2O with NH3into N2and H2O was achieved below 500oC with both applied catalysts. However, the ac...

Ern? E. Kiss; Tatjana J Vuli?…

2005-11-01T23:59:59.000Z

66

UK emissions of the greenhouse gas nitrous oxide  

Science Journals Connector (OSTI)

...other land use, (v) waste, and (vi) other sources...forestry (LULUCF) and waste are similarly proportioned...8 per cent and manure storage systems for 6 per cent...is reported here from long-term monitoring of greenhouse...are still not enough long-term datasets to provide the...

2012-01-01T23:59:59.000Z

67

UK emissions of the greenhouse gas nitrous oxide  

Science Journals Connector (OSTI)

...ranges from 33 to 170 per cent for fuel combustion processes and 195 per cent for other combustion processes (annex 7 of MacCarthy et al. [11...manure storage and N fertilizers. Combustion processes are the main source of NO x and microbial...

2012-01-01T23:59:59.000Z

68

Low-temperature formation of SiO{sub 2} layers using a two-step atmospheric pressure plasma-enhanced deposition-oxidation process  

SciTech Connect

Silicon oxide (SiO{sub 2}) layers were fabricated at low temperatures ({<=}400 deg. C) by combining the deposition of hydrogenated amorphous Si (a-Si:H) with its oxidation using atmospheric pressure plasmas excited by a 150 MHz very high-frequency (VHF) power. The surface excitation by the atmospheric pressure VHF plasma was capable of reducing the temperature for the hydrogen effusion from a-Si:H. As a result, a porous a-Si:H film containing a large amount of hydrogen could be transformed into a stoichiometric SiO{sub 2} with an approximately 24% increase in oxidation rate compared with the oxidation of Si(001) at a temperature of 400 deg. C.

Kakiuchi, Hiroaki; Ohmi, Hiromasa; Harada, Makoto; Watanabe, Heiji; Yasutake, Kiyoshi [Department of Precision Science and Technology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan)

2007-10-15T23:59:59.000Z

69

Transition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget  

E-Print Network (OSTI)

of the oxygen-17 excess (D17 O) of sulfate in the Arctic to quantify the sulfate source from aqueous SO2 (S concentrations, respectively. The solubility and oxidation state of these metals is determined by cloud liquid discrepancies with surface SO2 and sulfate observations in Europe. Oxygen isotope measurements of sulfate

Alexander, Becky

70

Surface reactivity and oxygen migration in amorphous indium-gallium-zinc oxide films annealed in humid atmosphere  

SciTech Connect

An isotope tracer study, i.e., {sup 18}O/{sup 16}O exchange using {sup 18}O{sub 2} and H{sub 2}{sup 18}O, was performed to determine how post-deposition annealing (PDA) affected surface reactivity and oxygen diffusivity of amorphous indium–gallium–zinc oxide (a-IGZO) films. The oxygen tracer diffusivity was very high in the bulk even at low temperatures, e.g., 200?°C, regardless of PDA and exchange conditions. In contrast, the isotope exchange rate, dominated by surface reactivity, was much lower for {sup 18}O{sub 2} than for H{sub 2}{sup 18}O. PDA in a humid atmosphere at 400?°C further suppressed the reactivity of O{sub 2} at the a-IGZO film surface, which is attributable to –OH-terminated surface formation.

Watanabe, Ken, E-mail: Watanabe.Ken@nims.go.jp [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan)] [International Center for Young Scientists (ICYS-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan); Lee, Dong-Hee [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Sakaguchi, Isao; Haneda, Hajime [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan)] [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Nomura, Kenji [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)] [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Kamiya, Toshio [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Hosono, Hideo [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan) [Materials and Structures Laboratory (MSL), Tokyo Institute of Technology, Mailbox R3-4, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan); Ohashi, Naoki, E-mail: Ohashi.Naoki@nims.go.jp [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan) [Optical and Electronic Materials Unit, NIMS, 1-1 Namiki, Tsukuba 305-0044 (Japan); Materials Research Center for Element Strategy (MCES), Mailbox S2-13, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-0026 (Japan)

2013-11-11T23:59:59.000Z

71

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO 2 : Implications for inversion analyses  

E-Print Network (OSTI)

Influence of reduced carbon emissions and oxidation on thedescription of reduced carbon emission and oxidationInfluence of reduced carbon emissions and oxidation on the

Suntharalingam, Parvadha; Randerson, James T; Krakauer, Nir; Logan, Jennifer A; Jacob, Daniel J

2005-01-01T23:59:59.000Z

72

5, 60416076, 2005 Atmospheric  

E-Print Network (OSTI)

opportunity to examine atmospheric oxidation in a megacity that has more pollution than typical USACPD 5, 6041­6076, 2005 Atmospheric oxidation in the Mexico City Metropolitan Area T. R. Shirley et.atmos-chem-phys.org/acpd/5/6041/ SRef-ID: 1680-7375/acpd/2005-5-6041 European Geosciences Union Atmospheric Chemistry

Boyer, Edmond

73

The effect of Mn on the oxidation behavior and electrical conductivity of Fe–17Cr alloys in solid oxide fuel cell cathode atmosphere  

Science Journals Connector (OSTI)

Four Fe–17Cr alloys with various Mn contents between 0.0 and 3.0 wt.% are prepared for investigation of the effect of Mn content on the oxidation behavior and electrical conductivity of the Fe–Cr alloys for the application of metallic interconnects in solid oxide fuel cells (SOFCs). During the initial oxidation stage (within 1 min) at 750 °C in air, Cr is preferentially oxidized to form a layer of Cr2O3 type oxide in all the alloys, regardless the Mn content, with similar oxidation rate and oxide morphology. The subsequent oxidation of the Mn containing alloys is accelerated caused by the fast outward diffusion of Mn ions across the Cr2O3 type oxide layer to form Mn-rich (Mn, Cr)3O4 and Mn2O3 oxides on the top. After 700 h oxidation a multi-layered oxide scale is observed in the Mn containing alloys, which corresponds to a multi-stage oxidation kinetics in the alloys containing 0.5 and 1.0 wt.% of Mn. The oxidation rate and ASR of the oxide scale increase with the Mn content in the alloy changes from 0.0 to 3.0 wt.%. For the application of metallic interconnects in SOFCs, Mn-free Fe–17Cr alloy with conducting Cr free spinel coatings is preferred.

Bin Hua; Yonghong Kong; Wenying Zhang; Jian Pu; Bo Chi; Li Jian

2011-01-01T23:59:59.000Z

74

Atmospheric Pollution Research 1 (2010) 220228 Atmospheric Pollution Research  

E-Print Network (OSTI)

Atmospheric Pollution Research 1 (2010) 220228 Atmospheric Pollution Research www in modeling of the associated multiphase processes. Iron redox species are important pollutants. The oxidative capacity of the atmospheric cloud water decreases when dissolution is included

Boyer, Edmond

75

Atmos. Chem. Phys., 10, 61376149, 2010 www.atmos-chem-phys.net/10/6137/2010/  

E-Print Network (OSTI)

sections of nitrous oxide (N2O) and carbon tetrachloride (CCl4) between 210 and 350 K and the atmospheric of nitrous oxide (N2O) and carbon tetrachloride (CCl4) are reported at five atomic UV lines (184.95, 202 The long-lived atmospheric species nitrous oxide (N2O) and carbon tetrachloride (CCl4) are ozone depleting

Meskhidze, Nicholas

76

Atmospheric Pollutant Removal by Non?Thermal Plasmas: Basic Data Needs for Understanding and Optimization of the Process  

Science Journals Connector (OSTI)

Since fifteen years an increasing interest has been devoted to removal of atmospheric pollutant by non?thermal plasmas achieved using e?beams or pulsed discharges for the nitrous oxides the so?called de?NOx process or for Volatils Organic Compounds the so?called de?VOC process. However the physical and chemical mechanisms involved are not easy to understand: molecules or gas mixtures are quite complex and the transient plasma created by the type of discharge often used dielectric barrier or corona ones is non homogeneous in space. In this paper is discussed some data needs for understanding of the NO?removal process and the destruction of some selected VOC molecules TCE and TCA by pulsed discharge plasmas. Some experimental studies performed to get insight into the discharge plasma kinetic involved in the pollutant removal are presented in particular about the hydroxyl radical OH which play an important role in this kinetic.

S. Pasquiers; M. Cormier; O. Motret

2002-01-01T23:59:59.000Z

77

Investigation of the Atmospheric Ozone Impacts of Methyl Iodide  

E-Print Network (OSTI)

J. R. Holmes (1977): “Nitrogen Dioxide Photolysis in the LosO3 Ozone NO Nitric Oxide NO2 Nitrogen Dioxide NO3 NitrateNitrogen Pentoxide HONO Nitrous Acid HNO3 Nitric Acid HNO4 Peroxynitric Acid HO2H Hydrogen Peroxide CO Carbon Monoxide SO2 Sulfur Dioxide

Carter, W P L

2007-01-01T23:59:59.000Z

78

Characterization of YSZ solid oxide fuel cells electrolyte deposited by atmospheric plasma spraying and low pressure plasma spraying  

Science Journals Connector (OSTI)

Yttria doped zirconia has been widely used as electrolyte materials for solid oxide fuel cells (SOFC). Plasma spraying is a cost-effective process to...2O3 stabilized ZrO2...(YSZ) layer was deposited by low press...

C. Zhang; H. L. Liao; W. Y. Li; G. Zhang; C. Coddet…

2006-12-01T23:59:59.000Z

79

Atmospheric fate of OH initiated oxidation of terpenes. Reaction mechanism of ?-pinene degradation and secondary organic aerosol formation  

Science Journals Connector (OSTI)

This paper studies the reaction products of ?-pinene, ?-pinene, sabinene, 3-carene and limonene with OH radicals and of ?-pinene with ozone using FT-IR spectroscopy for measuring gas phase products and HPLC-MS-MS to measure products in the aerosol phase. These techniques were used to investigate the secondary organic aerosol (SOA) formation from the terpenes. The gas phase reaction products were all quantified using reference compounds. At low terpene concentrations (0.9–2.1 ppm), the molar yields of gas phase reaction products were: HCHO 16–92%, HCOOH 10–54% (OH source: H2O2, 6–25 ppm); HCHO 127–148%, HCOOH 4–6% (OH source: CH3ONO, 5–8 ppm). At high terpene concentrations (4.1–13.2 ppm) the results were: HCHO 9–27%, HCOOH 15–23%, CH3(CO)CH3 0–14%, CH3COOH 0–5%, nopinone 24% (only from ?-pinene oxidation), limona ketone 61% (only from limonene oxidation), pinonaldehyde was identified during ?-pinene degradation (OH source H2O2, 23–30 ppm); HCHO 76–183%, HCOOH 12–15%, CH3(CO)CH3 0–12%, nopinone 17% (from ?-pinene oxidation), limona ketone 48% (from limonene oxidation), pinonaldehyde was identified during ?-pinene degradation (OH source CH3ONO, 14–16 ppm). Pinic acid, pinonic acid, limonic acid, limoninic acid, 3-caric acid, 3-caronic acid and sabinic acid were identified in the aerosol phase. On the basis of these results, we propose a formation mechanism for pinonic and pinic acid in the aerosol phase explaining how degradation products could influence SOA formation and growth in the troposphere.

Vito Librando; Giuseppe Tringali

2005-01-01T23:59:59.000Z

80

Detecting industrial pollution in the atmospheres of earth-like exoplanets  

E-Print Network (OSTI)

Detecting biomarkers, such as molecular oxygen, in the atmospheres of transiting exoplanets has been a major focus in the search for alien life. We point out that in addition to these generic indicators, anthropogenic pollution could be used as a novel biomarker for intelligent life. To this end, we identify pollutants in the Earth's atmosphere that have significant absorption features in the spectral range covered by the James Webb Space Telescope (JWST). We estimate that for an Earth-mass planet in the habitable zone of a white dwarf, methane (CH4) and nitrous oxide (N2O) can be detected at earth-like concentrations with an integration time of ~1.5 hrs and 12 hrs respectively. Detecting pollutants that are produced nearly exclusively by anthropogenic activities will be significantly more challenging. Of these pollutants, we focus on tetrafluoromethane (CF4) and trichlorofluoromethane (CCl3F), which will be the easiest to detect. We estimate that ~1.5 days (~3 days) of total integration time will be sufficie...

Lin, Henry W; Loeb, Abraham

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Applicability of Anaerobic Nitrate-Dependent Fe(II) Oxidation to Microbial Enhanced Oil Recovery (MEOR)  

Science Journals Connector (OSTI)

Furthermore, both of the substrates of the NDFO organisms [Fe(II) and nitrate] and the various end products of the metabolism [Fe(III), nitrite, nitric oxide, and nitrous oxide] all have known anti-souring and sulfide-scouring activities. ... A glass wool pad was placed on the bottom of the bead beds to prevent beads from falling into the inlet tubing. ...

Hongbo Zhu; Han K. Carlson; John D. Coates

2013-06-25T23:59:59.000Z

82

Atmospheric pressure gas plasma-induced colorectal cancer cell death is mediated by Nox2–ASK1 apoptosis pathways and oxidative stress is mitigated by Srx–Nrf2 anti-oxidant system  

Science Journals Connector (OSTI)

Abstract Atmospheric pressure gas plasma (AGP) generates reactive oxygen species (ROS) that induce apoptosis in cultured cancer cells. The majority of cancer cells develop a ROS-scavenging anti-oxidant system regulated by Nrf2, which confers resistance to ROS-mediated cancer cell death. Generation of ROS is involved in the AGP-induced cancer cell death of several colorectal cancer cells (Caco2, HCT116 and SW480) by activation of ASK1-mediated apoptosis signaling pathway without affecting control cells (human colonic sub-epithelial myofibroblasts; CO18, human fetal lung fibroblast; MRC5 and fetal human colon; FHC). However, the identity of an oxidase participating in AGP-induced cancer cell death is unknown. Here, we report that AGP up-regulates the expression of Nox2 (NADPH oxidase) to produce ROS. RNA interference designed to target Nox2 effectively inhibits the AGP-induced ROS production and cancer cell death. In some cases both colorectal cancer HT29 and control cells showed resistance to AGP treatment. Compared to AGP-sensitive Caco2 cells, HT29 cells show a higher basal level of the anti-oxidant system transcriptional regulator Nrf2 and its target protein sulfiredoxin (Srx) which are involved in cellular redox homeostasis. Silencing of both Nrf2 and Srx sensitized HT29 cells, leads to ROS overproduction and decreased cell viability. This indicates that in HT29 cells, Nrf2/Srx axis is a protective factor against AGP-induced oxidative stress. The inhibition of Nrf2/Srx signaling should be considered as a central target in drug-resistant colorectal cancer treatments.

Musarat Ishaq; Margaret D.M. Evans; Kostya (Ken) Ostrikov

2014-01-01T23:59:59.000Z

83

An Intercomparison of Ground-Based Solar FTIR Measurements of Atmospheric Gases at Eureka, Canada  

Science Journals Connector (OSTI)

The authors report the results of an intercomparison of vertical column amounts of hydrogen chloride (HCl), hydrogen fluoride (HF), nitrous oxide (N2O), nitric acid (HNO3), methane (CH4), ozone (O3), carbon dioxide (CO2), and nitrogen (N2) ...

C. Paton-Walsh; R. L. Mittermeier; W. Bell; H. Fast; N. B. Jones; A. Meier

2008-11-01T23:59:59.000Z

84

Atmospheric Chemistry  

NLE Websites -- All DOE Office Websites (Extended Search)

competencies Atmospheric Chemistry Atmospheric Chemistry is the study of the composition of the atmosphere, the sources and fates of gases and particles in air, and changes induced...

85

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network (OSTI)

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% ...

Grenfell, J L; Patzer, B; Rauer, H; Segura, A; Stadelmann, A; Stracke, B; Titz, R; Von Paris, P; Grenfell, John Lee; Griessmeier, Jean-Mathias; Patzer, Beate; Rauer, Heike; Segura, Antigona; Stadelmann, Anja; Stracke, Barbara; Titz, Ruth; Paris, Philip von

2007-01-01T23:59:59.000Z

86

Oxidant for Trapping Atmospheric Radiokrypton  

Science Journals Connector (OSTI)

... Stein earlier showed4,5 that C1F2+, BrF2+ and IF43+ salts react with radon to produce RnF+ salts. These ... to produce RnF+ salts. These radon salts may be formed by electron transfer from the ...

JOEL F. LIEBMAN

1973-07-13T23:59:59.000Z

87

Atmospheric chemistry impacts and feedbacks on the global carbon cycle  

E-Print Network (OSTI)

prediction. Issues to be addressed include the quantification of the impact of the atmospheric oxidation and the oxidative state of the atmosphere. The end goal is to create a model that can quantitatively predict is required to: Predict 3-D atmospheric CO2 production as a function of the CCSM3 atmospheric chemistry module

88

Atmospheric chemistry of tetrachloroethene (Cl{sub 2}C{double{underscore}bond}CCl{sub 2}): Products of chlorine atom initiated oxidation  

SciTech Connect

The products following Cl atom initiated oxidation of C{sub 2}Cl{sub 4} at 700--760 Torr of air and 230--299 K in the presence and absence of NO{sub x} were investigated using three different FTIR smog chamber techniques. There was no measurable effect of temperature on the product yields. CCl{sub 3}C(O)Cl and COCl{sub 2} were formed with molar yields of 68 {+-} 6% and 77 {+-} 12% in the presence of NO{sub x} and 0.84 and 0.16 in the absence of NO{sub x}. Contrary to a recent report by Hasson and Smith, variation of the initial C{sub 2}Cl{sub 4} by a factor of 300 over the range (0.016--5.6) x 10{sup 14} molecule cm{sup {minus}3} had no discernible effect ({lt}10%) on the product distributions. The different product distribution observed in the presence of NO{sub x} may reflect the formation and subsequent decomposition of chemically activated C{sub 2}Cl{sub 5}O radicals, formed in the exothermic reaction of C{sub 2}Cl{sub 5}O{sub 2} with NO. The kinetics of the reaction of Cl atoms with C{sub 2}Cl{sub 4} were measured in 2.0--700 Torr of air at 296 K. The results are in good agreement with the previous study by Nicovich et al. The combined data can be described using F{sub c} = 0.6, k{sub o}= (1.8 {+-} 0.3) x 10{sup {minus}28} cm{sup 6} molecule{sup {minus}2}s{sup {minus}1} and k{sub {infinity}} = (4.0 {sup {minus}} 0.4) x 10{sup {minus}11} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}. Results are discussed with respect to the atmospheric chemistry of C{sub 2}Cl{sub 4}.

Thuener, L.P.; Barnes, I.; Becker, K.H.; Wallington, T.J.; Christensen, L.K.; Orlando, J.J.; Ramacher, B.

1999-10-28T23:59:59.000Z

89

Unexpected nondenitrifier nitrous oxide reductase gene diversity and abundance in soils  

Science Journals Connector (OSTI)

...with a Dionex DX-500 ion chromatograph with an EG40 eluent (methane-sulfonic acid) generator and a CS12A column (13). 7 References...BURPS1106A_2115 YP_001066380 Burkholderia pseudomallei 1106a-HHV NC_009076 BURPS1710b_2255 YP_333650 Burkholderia pseudomallei...

Robert A. Sanford; Darlene D. Wagner; Qingzhong Wu; Joanne C. Chee-Sanford; Sara H. Thomas; Claribel Cruz-García; Gina Rodríguez; Arturo Massol-Deyá; Kishore K. Krishnani; Kirsti M. Ritalahti; Silke Nissen; Konstantinos T. Konstantinidis; Frank E. Löffler

2012-01-01T23:59:59.000Z

90

The potential of mean force of nitrous oxide in a 1,2-dimyristoylphosphatidylcholine lipid bilayer  

E-Print Network (OSTI)

specific binding sites. The penetration bar- rier correlates strongly with the action rate penetration and partitioning between lipid and water is an important step toward elucidating the function of N2O as a general anesthetic. After all, N2O has to penetrate through mem- branes before it reaches

91

Activation of Pd-Ag Catalyst for Selective Hydrogenation of Acetylene via Nitrous Oxide Addition  

Science Journals Connector (OSTI)

Hydrogenation of acetylene in the presence of a large excess of ethylene has been investigated on the Pd-Ag catalyst under 60°C and a space velocity...?1.... It was found that an enhancement in the performance of...

Piyasan Praserthdam; Suphot Phatanasri…

2000-05-01T23:59:59.000Z

92

Quantification of and Controls on Dinitrogen and Nitrous Oxide Fluxes from Terrestrial Ecosystems  

E-Print Network (OSTI)

and lowest in a mixed conifer forest soil from the Blodgettin a northern hardwood-conifer forest. Soil Science Societyfir Yellow pine forest Mixed conifer and hardwood Oak

Yang, Wendy Hui-I

2010-01-01T23:59:59.000Z

93

Biological sources and sinks of nitrous oxide and strategies to mitigate emissions  

Science Journals Connector (OSTI)

...of organic nitrogen (eutrophication...m of the water column...affect the solubility of N2O...with other gases CO2, CH4...to yield nitrogen gas, e.g...laughing gas. Water Atmos. 15...2005 Global nitrogen enrichment...

2012-01-01T23:59:59.000Z

94

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Resonance and Low Pressure Sampling A first set of results has found that LASAR and VLPS data in the laboratory closely correlate with real-time, in-use measurement of NH3 and NO...

95

Unexpected nondenitrifier nitrous oxide reductase gene diversity and abundance in soils  

Science Journals Connector (OSTI)

...contributors to N2O consumption. Apparently, a large...contributions to N2O consumption will advance understanding...flux models. Fossil fuel combustion, agricultural practices...electron donor, and the vessels were inoculated with...contributing to N 2 O consumption in soils...

Robert A. Sanford; Darlene D. Wagner; Qingzhong Wu; Joanne C. Chee-Sanford; Sara H. Thomas; Claribel Cruz-García; Gina Rodríguez; Arturo Massol-Deyá; Kishore K. Krishnani; Kirsti M. Ritalahti; Silke Nissen; Konstantinos T. Konstantinidis; Frank E. Löffler

2012-01-01T23:59:59.000Z

96

Photolysis of Nitrous Oxide Isotopomers Studied by Time-Dependent Hermite Propagation  

Science Journals Connector (OSTI)

The model agrees with available experimental enrichment factors and stratospheric balloon infrared remote sensing data to within the estimated error. ...

Matthew S. Johnson; Gert Due Billing; Alytis Gruodis; Maurice H. M. Janssen

2001-09-05T23:59:59.000Z

97

Biological sources and sinks of nitrous oxide and strategies to mitigate emissions  

Science Journals Connector (OSTI)

...used to produce biodiesel and bioethanol...replacement of the fossil fuel by biofuel. It...cereals include engineering bacteria to recognize...considered was the introduction of the nitrogenase...It provides an introduction and background...microbiology, (ii) engineering crop plants to...

2012-01-01T23:59:59.000Z

98

The Resolution of Mixtures of Carbon Dioxide and Nitrous Oxide by Gas Solid Chromatography  

Science Journals Connector (OSTI)

......1106. R. P. DeGrazio The Dow Chemical Company, Rocky Flats Division, Golden, Colorado The Resolution of Mixtures...Chromatography* by R. P. DeGrazio, The Dow Chemical Company, Rocky Flats Division, Golden, Colorado A simple and unique chromato......

R. P. DeGrazio

1965-06-01T23:59:59.000Z

99

Nitrous oxide and carbon dioxide emissions from pelletized and nonpelletized poultry litter incorporated into soil  

Science Journals Connector (OSTI)

While several studies have shown that the addition of animal manures to soil can increase N2O and CO2 emissions, limited information is available on the effect that manure physical characteristics can have on the...

M. L. Cabrera; S. C. Chiang; W. C. Merka; O. C. Pancorbo; S. A. Thompson

100

Nitrous oxide emissions from soils: how well do we understand the processes and their controls?  

Science Journals Connector (OSTI)

...1365-2486.2010.02351.x ) 56 Birch, HF , Friend, MT. 1956 Humus decomposition...covariance measurements using quantum cascade laser spectrometery over a Swiss forest. Biogeosciences...review of applications of model-data fusion to studies of terrestrial carbon fluxes...

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Relationship Between Particle and Plasma Properties and Coating Characteristics of Samaria-Doped Ceria Prepared by Atmospheric Plasma Spraying for Use in Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Samaria-doped ceria (SDC) has become a promising material for the fabrication of high-performance, intermediate-temperature solid oxide fuel cells (SOFCs). In this study, the in-flight characteristics, such as pa...

Mark Cuglietta; Olivera Kesler

2012-06-01T23:59:59.000Z

102

Single crystal flow reactor for studying reactivities on metal oxide model catalysts at atmospheric pressure to bridge the pressure gap to the adsorption properties determined under UHV conditions  

Science Journals Connector (OSTI)

A flow reactor for the investigation of heterogeneous catalytic reactions on single crystalline metal oxide model catalysts has been designed. It is located in a high pressure cell attached to an UHV analysis cha...

C. Kuhrs; M. Swoboda; W. Weiss

2001-01-01T23:59:59.000Z

103

Musical Atmospherics  

Science Journals Connector (OSTI)

... THE characteristics of audio musical atmospherics which are obtained when an ... musical atmospherics which are obtained when an audio amplifier is placed in a long line or aerial have been discussed from time to ...

T. L. ECKERSLEY

1935-01-19T23:59:59.000Z

104

How and why electrostatic charge of combustible nanoparticles can radically change the mechanism and rate of their oxidation in humid atmosphere  

E-Print Network (OSTI)

Electrostatically charged aerosol nanoparticles strongly attract surrounding polar gas molecules due to a charge-dipole interaction. In humid air, the substantial electrostatic attraction and acceleration of surrounding water vapour molecules towards charged combustible nanoparticles cause intense electrostatic hydration and preferential oxidation of these nanoparticles by accelerated water vapor molecules rather than non-polar oxygen molecules. In particular, electrostatic acceleration, acquired by surrounding water vapour molecules at a distance of their mean free path from the minimally charged iron metal nanoparticle can increase an oxidative activity of these polar molecules with respect to the nanoparticle by a factor of one million. Intense electrostatic hydration of charged metal nanoparticles converts the nanoparticle's oxide based shells into the hydroxide based electrolyte shells, transforming these nanoparticles into metal/air core-shell nanobatteries, periodically short-circuited by intra-particl...

Meshcheryakov, Oleg

2010-01-01T23:59:59.000Z

105

Assessing methane oxidation under landfill covers and its contribution to the above atmospheric CO2 levels: The added value of the isotope  

E-Print Network (OSTI)

biogas fluxes, which was expected in clay covers presenting fissures, through which CH4 is rapidly transported. At shallow depth, more immobile biogas pockets show a higher level of CH4 oxidation., 1998). The main com- ponents of biogas are CH4 (50­60%) and carbon dioxide (CO2; 40­50%). A major

106

Highly oxidized superconductors  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

Morris, D.E.

1994-09-20T23:59:59.000Z

107

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network (OSTI)

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% lower CH4 fluxes compared to those studies. Unlike on the Earth, relatively modest changes in these fluxes can lead to larger changes in the concentrations of biomarker and related species on the M-star world. We calculate a CH4 greenhouse heating effect of up to 4K. O3 photochemistry in terms of the smog mechanism and the catalytic loss cycles on the M-star world differs considerably compared with the Earth.

John Lee Grenfell; Jean-Mathias Griessmeier; Beate Patzer; Heike Rauer; Antigona Segura; Anja Stadelmann; Barbara Stracke; Ruth Titz; Philip von Paris

2007-02-23T23:59:59.000Z

108

Atmospheric Neutrinos  

E-Print Network (OSTI)

This paper is a brief overview of the theory and experimental data of atmospheric neutrino production at the fiftieth anniversary of the experimental discovery of neutrinos.

Thomas K. Gaisser

2006-12-11T23:59:59.000Z

109

Ethylene Oxide Explosions  

Science Journals Connector (OSTI)

... THE occasional occurrence of ethylene oxide explosions during the fumigation of dried fruit has led us to undertake a detailed ... yielded results somewhat like those for acetaldehyde1,2.. Cool flames can be initiated in ethylene oxide – air mixtures in the neighbourhood of 330° C. at atmospheric pressure. ...

J. H. BURGOYNE; F. A. BURDEN

1948-07-31T23:59:59.000Z

110

Intrasphere and extrasphere effects of the influence of ammine complexes of transition metals on their catalytic activity in reactions of oxidation of manganese sulfate to the dioxide by atmospheric oxygen  

SciTech Connect

Manganese(II) sulfate is a waste product from the large-tonnage redox process for production of anthraquinone from aniline. Recovery of the original manganese dioxide and removal of manganese(II) sulfate from the wastewaters are economically and ecologically necessary. Liquid-phase low-temperature conversion of manganese(II) sulfate by the action of atmospheric oxygen blown through an aqueous solution of the salt containing ammine complexes of transition metals was studied earlier. It was shown that it does not depend only on intrasphere cations or extrasphere anions; it may be influenced by the effects of their interactions. The purpose of the present work was to study this influence in a complete factorial experiment of the CFE-3T type. It was found that homogeneous catalysis of oxidation of manganese(II) sulfate by atmospheric oxygen in presence of transition-metal ammines is determined to a considerable extent by the effects of pair interactions between complex-forming cations and extrasphere anions.

Eremeev, A.P.; Veselovskii, P.F.

1986-12-10T23:59:59.000Z

111

Composition and Reactions of Atmospheric Aerosol Particles  

NLE Websites -- All DOE Office Websites (Extended Search)

Composition and Reactions of Composition and Reactions of Atmospheric Aerosol Particles Composition and Reactions of Atmospheric Aerosol Particles Print Wednesday, 29 June 2005 00:00 Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth while changing organic composition by 13 to 24% per day, an oxidation rate significantly slower than is currently used in atmospheric models. Since oxidation has a strong effect on particle lifetime in the atmosphere, these results will help climate scientists refine the computer models used to predict climate change.

112

Composition and Reactions of Atmospheric Aerosol Particles  

NLE Websites -- All DOE Office Websites (Extended Search)

Composition and Reactions of Atmospheric Aerosol Particles Print Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth while changing organic composition by 13 to 24% per day, an oxidation rate significantly slower than is currently used in atmospheric models. Since oxidation has a strong effect on particle lifetime in the atmosphere, these results will help climate scientists refine the computer models used to predict climate change.

113

Composition and Reactions of Atmospheric Aerosol Particles  

NLE Websites -- All DOE Office Websites (Extended Search)

Composition and Reactions of Atmospheric Aerosol Particles Print Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth while changing organic composition by 13 to 24% per day, an oxidation rate significantly slower than is currently used in atmospheric models. Since oxidation has a strong effect on particle lifetime in the atmosphere, these results will help climate scientists refine the computer models used to predict climate change.

114

Chapter 10: Biological Impacts of ClimateChange 1.Nature of Climate Change  

E-Print Network (OSTI)

enters the atmosphere through the burning of fossil fuels (oil, natural gas, and coal), solid waste and by the decay of organic waste in municipal solid waste landfills. · Nitrous Oxide (N2O): Nitrous oxide and solid waste. · Fluorinated Gases: Hydrofluorocarbons, perfluorocarbons, and sulfur hexafluoride

Gottgens, Hans

115

NETL: Solid Oxide Fuel Cells Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Solid Oxide Fuel Cells Publications Operating Principles AEC Development Atmospheric Pressure Systems Pressurized Systems Program Plan Project Portfolio Project Information Systems...

116

Atmospheric tritium  

SciTech Connect

Research progress for the year 1979 to 1980 are reported. Concentrations of tritiated water vapor, tritium gas and tritiated hydrocarbons in the atmosphere at selected sampling points are presented. (ACR)

Oestlund, H.G.; Mason, A.S.

1980-01-01T23:59:59.000Z

117

Controlled atmosphere for fabrication of cermet electrodes  

DOE Patents (OSTI)

A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA)

1998-01-01T23:59:59.000Z

118

Global metaanalysis of the nonlinear response of soil nitrous oxide (N2O) emissions to fertilizer nitrogen  

Science Journals Connector (OSTI)

...programs, the US Department of Energy Office of Science (Grant DE-FCO2-07ER64494) and Office of Energy Efficiency and Renewable Energy (Grant DE-ACO5-76RL01830...Tsukuba 36°02 N 140°12 E 12 Brazil Capivari, San Paolo 22°93...

Iurii Shcherbak; Neville Millar; G. Philip Robertson

2014-01-01T23:59:59.000Z

119

Global metaanalysis of the nonlinear response of soil nitrous oxide (N2O) emissions to fertilizer nitrogen  

Science Journals Connector (OSTI)

...selected field studies from the literature where in situ measurements of...and in studies identified in reviews by Bouwman (8), Jungkunst...Dataset S1) when available: literature reference; location...fertilizer. Glob Change Biol Bioenergy 16(1):156 ZZQQhy170...

Iurii Shcherbak; Neville Millar; G. Philip Robertson

2014-01-01T23:59:59.000Z

120

Determinations of Carbon Dioxide and Methane by Dual Catalyst Flame Ionization Chromatography and Nitrous Oxide by Electron Capture Chromatography  

Science Journals Connector (OSTI)

......reduced by introducing additional fuel hydrogen before the palladium...smaller sample size is that the consumption of standards in long-term...1979 aboard the Research Vessel Wecoma during Leg 9 of the...because of its low rate of consumption of standard gases, but also......

Ray F. Weiss

1981-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Association of Earthworm-Denitrifier Interactions with Increased Emission of Nitrous Oxide from Soil Mesocosms Amended with Crop Residue  

Science Journals Connector (OSTI)

...mug C kg1, and total mineral N content (extraction...respectively. We used a soda-lime filter during N2O measurements...within 48 h of sampling. Mineral N was extracted using...were also ball milled. Mineral N and MBN was converted...Netherlands) with a SYBR green detection system. Each...

Lucas D. Nebert; Jaap Bloem; Ingrid M. Lubbers; Jan Willem van Groenigen

2011-04-22T23:59:59.000Z

122

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation .  

E-Print Network (OSTI)

??The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test… (more)

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

123

A post-Kyoto partner: Considering the stratospheric ozone regime as a tool to manage nitrous oxide  

Science Journals Connector (OSTI)

...There is a balance between ozone production...because the mass of N 2 O...such as wastewater, are developing...such as wastewater treatment and aquaculture...coal power plants) emit N...how to balance funding...nitric acid plants in the United...

David Kanter; Denise L. Mauzerall; A. R. Ravishankara; John S. Daniel; Robert W. Portmann; Peter M. Grabiel; William R. Moomaw; James N. Galloway

2013-01-01T23:59:59.000Z

124

Determinations of Carbon Dioxide and Methane by Dual Catalyst Flame Ionization Chromatography and Nitrous Oxide by Electron Capture Chromatography  

Science Journals Connector (OSTI)

......thermistor has a low thermal mass and the circuit...and have longer thermal exchange times will...detectors such as the thermal conductivity detector...equatorial Pacific Ocean during a 24 day...Department of Energy. References Journal...Methanizer" catalytic converter. 5. W.E. Wentworth......

Ray F. Weiss

1981-12-01T23:59:59.000Z

125

Biodegradation of monoaromatic hydrocarbons by aquifer microorganisms using oxygen, nitrate, or nitrous oxide as the terminal electron acceptor.  

Science Journals Connector (OSTI)

...I. Mayfield. 1986. Remediation of gasoline-contaminated...Aerobic denitrification as an innovative method for in-situ biological remediation of contaminated sub- surface...underground storage tanks: remediation with emphasis on in situ...

S R Hutchins

1991-08-01T23:59:59.000Z

126

Effect of encapsulated calcium carbide on dinitrogen, nitrous oxide, methane, and carbon dioxide emissions from flooded rice  

Science Journals Connector (OSTI)

The efficiency of N use in flooded rice is usually low, chiefly due to gaseous losses. Emission of CH4, a gas implicated in global warming, can also be substantial in flooded rice. In a greenhouse study, the nitr...

K. F. Bronson; A. R. Mosier

1991-05-01T23:59:59.000Z

127

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation  

E-Print Network (OSTI)

The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

128

tall tower facility and instrumentation New coNstraiNts oN the Nitrous oxide budget of agricultural ecosystems  

E-Print Network (OSTI)

thick. The FAO classification is Chernozem. The field site has been under cultivation for the past 125. The tall tower source footprint is dominated by agricultural land use. The domi- nant crop types include measured at 100 m using a three dimensional sonic anemometer- thermometer for computation of energy, water

Minnesota, University of

129

Apparatus and Method for Oxidation and Stabilization of Polymeric...  

NLE Websites -- All DOE Office Websites (Extended Search)

is based on the use of reactive oxidative species (ROS), such as monatomic oxygen, and atmospheric plasma to increase the rate of oxygen diffusion to nonoxidized polymeric...

130

E-Print Network 3.0 - atmospheric iron corrosion Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

atmosphere and an oxidizing... -2 Chromium additions seemed to help improve the corrosion resistance of the ... Source: DuPont, John N. - Department of Materials Science and...

131

Formation of atmospheric particles from organic acids produced by forests  

Science Journals Connector (OSTI)

... Ljungstrom, E. Atmospheric fate of carbonyl oxidation products originating from ?-pinene and ?3-carene: Determination of rate of reaction with OH and NO3radicals, UV absorption cross sections, ...

Ilias G. Kavouras; Nikolaos Mihalopoulos; Euripides G. Stephanou

1998-10-15T23:59:59.000Z

132

Winter and summer nitrous oxide and nitrogen oxides fluxes from a seasonally snow-covered subalpine meadow at Niwot Ridge, Colorado  

E-Print Network (OSTI)

of Geography, University of Colorado, Boulder, CO, USA M. W.Alpine Research, University of Colorado, Boulder, CO, USA D.Sciences, University of Colorado, Boulder, CO, USA B. Hall

2009-01-01T23:59:59.000Z

133

Communication: CO oxidation by silver and gold cluster cations: Identification of different active oxygen species  

SciTech Connect

The oxidation of carbon monoxide with nitrous oxide on mass-selected Au{sub 3}{sup +} and Ag{sub 3}{sup +} clusters has been investigated under multicollision conditions in an octopole ion trap experiment. The comparative study reveals that for both gold and silver cations carbon dioxide is formed on the clusters. However, whereas in the case of Au{sub 3}{sup +} the cluster itself acts as reactive species that facilitates the formation of CO{sub 2} from N{sub 2}O and CO, for silver the oxidized clusters Ag{sub 3}O{sub x}{sup +} (n= 1-3) are identified as active in the CO oxidation reaction. Thus, in the case of the silver cluster cations N{sub 2}O is dissociated and one oxygen atom is suggested to directly react with CO, whereas a second kind of oxygen strongly bound to silver is acting as a substrate for the reaction.

Popolan, Denisia M.; Bernhardt, Thorsten M. [Institute of Surface Chemistry and Catalysis, University of Ulm, Albert-Einstein-Allee 47, 89069 Ulm (Germany)

2011-03-07T23:59:59.000Z

134

Formation of submicron oxide widths on aluminum in the presence of keV electron beams and CO/sub 2/ or N/sub 2/O  

SciTech Connect

The purpose of this paper is to report the size of oxide islands or line widths that can be grown as smaller diameter electron beams are used for the oxidation. The implications of the potential lateral resolution available between oxide lines for electronic materials are discussed. The localize dioxide growth on thin Al films occurs in the presence of .5 to 10 keV electron beams and high vacuum level pressures of carbon dioxide or nitrous oxide. Auger electron spectroscopy shows saturation of the O (KLL) signal and depletion of the Al (LMM) signal after an exposure of 5000 l carbon dioxide with a 2 keV beam of 7 A/sq. cm. The oxide is spatially restricted to the beam impact region and is stable for long periods of time in vacuum. The most plausible mechanism for this oxide growth is dissociation of the carbon dioxide or the nitrous oxide by the electron beam in the region of impingement on or near the surface. Oxygen atoms thus formed can then react with the Al, and carbon monoxide or nitrogen desorbs.

Pitts, J.R.; Massopust, T.P.; Czanderna, A.W.; Kazmerski, L.L.

1986-03-01T23:59:59.000Z

135

High surface area, electrically conductive nanocarbon-supported metal oxide  

DOE Patents (OSTI)

A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.

Worsley, Marcus A; Han, Thomas Yong-Jin; Kuntz, Joshua D; Cervanted, Octavio; Gash, Alexander E; Baumann, Theodore F; Satcher, Jr., Joe H

2014-03-04T23:59:59.000Z

136

Microstreamer dynamics during plasma remediation of NO using atmospheric pressure dielectric barrier discharges  

E-Print Network (OSTI)

Microstreamer dynamics during plasma remediation of NO using atmospheric pressure dielectric- ate toxins from atmospheric pressure gas streams. Plasma remediation is one technique which has been methods for the removal of oxides of nitrogen NxOy from atmospheric gas streams and among those techniques

Kushner, Mark

137

A white paper on Effects of Anthropogenic Pollution on the Atmospheric  

E-Print Network (OSTI)

1 A white paper on Effects of Anthropogenic Pollution on the Atmospheric Chemistry of the Tropical Brazilian Partner Organizations National Institute for Amazonian Research (INPA)1 The Large-Scale Biosphere-Atmosphere by the atmospheric oxidation of trace gases to low volatility compounds (Chen et al. 2009). These products can

138

Atmospheric Transport of Radionuclides  

SciTech Connect

The purpose of atmospheric transport and diffusion calculations is to provide estimates of concentration and surface deposition from routine and accidental releases of pollutants to the atmosphere. This paper discusses this topic.

Crawford, T.V.

2003-03-03T23:59:59.000Z

139

The Boulder Atmospheric Observatory  

Science Journals Connector (OSTI)

The Boulder Atmospheric Observatory (BAO) is a unique research facility for studying the planetary boundary layer and for testing and calibrating atmospheric sensors. The facility includes a 300 m tower instrumented with fast- and slow-response ...

J. C. Kaimal; J. E. Gaynor

1983-05-01T23:59:59.000Z

140

8, 10691088, 2008 Atmospheric  

E-Print Network (OSTI)

into the atmosphere (Molina et al., 1974; Farman et al., 1985) has led to an interna- tional effort to replace

Boyer, Edmond

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

The Upper Atmosphere Observatory  

Science Journals Connector (OSTI)

...with *the plasma frethe progress...explorcreated an even larger number of...the upper atmosphere and ionosphere...the upper atmosphere. For this...ionospheric plasma motion simul-taneously...field is large, the horizontal...resolved. The atmospheric gravity waves...simul-taneously at a large number of...two regions plasma drifts separated...

J. V. Evans

1972-05-05T23:59:59.000Z

142

The Upper Atmosphere Observatory  

Science Journals Connector (OSTI)

...DATA, JOURNAL OF ATMOSPHERIC AND TERRESTRIAL...IN NEAR-EARTH PLASMA, SPACE SCIENCE...INVESTIGATION OF WHISTLING ATMOSPHERICS, PHILOSOPHICAL...TRANSPOLAR EXOSPHERIC PLASMA .1. PLASMASPHERE...dynamics of the upper atmosphere. For this purpose...the ionospheric plasma motion simul-taneously...

J. V. Evans

1972-05-05T23:59:59.000Z

143

Instrument Development and Measurements of the Atmospheric Pollutants Sulfur Dioxide, Nitrate Radical, and Nitrous Acid by Cavity Ring-down Spectroscopy and Cavity Enhanced Absorption Spectroscopy  

E-Print Network (OSTI)

A. , A method of nitrogen dioxide and sulphur dioxidedetermination of nitrogen dioxide and sulfur dioxide in theDOAS) have measured nitrogen dioxide (NO 2 ), nitrate

Medina, David Salvador

2011-01-01T23:59:59.000Z

144

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

145

DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES  

SciTech Connect

This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

Kyser, E

2009-01-12T23:59:59.000Z

146

AtmosphericAtmospheric Composition Introduction The division investigates the atmospheric  

E-Print Network (OSTI)

development on observation side was the installation of an ozone observation station in Surinam in close co-operation with the Surinam Meteorological Service. Processes in the tropical regions are important for the global climate and the global atmospheric composition. The participation in Indoex (Indian Ocean Experiment) and this Surinam

Haak, Hein

147

Increased Cytotoxicity of Oxidized Flame Soot  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

148

Atmospheric Radiation Measurement Program  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 ARM 2003 Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement WARNING! WARNING! Today is April 1 But that has NO bearing on this message Today is April 1 But that has NO bearing on this message ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Two Topics Two Topics * Status of ARM (quick overview) * Science plan - ARM in the next 5 years * Status of ARM (quick overview) * Science plan - ARM in the next 5 years ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement ARM Status - Science ARM Status - Science * Steadily increasing productivity - Poster session - over 220 posters (may need to do something about submissions next year) - Peer-reviewed articles: 2.5 to 3 per year per

149

Atmospheric Neutrino Fluxes  

E-Print Network (OSTI)

Starting with an historical review, I summarize the status of calculations of the flux of atmospheric neutrinos and how they compare to measurements.

Thomas K. Gaisser

2005-02-18T23:59:59.000Z

150

ARM - Atmospheric Heat Budget  

NLE Websites -- All DOE Office Websites (Extended Search)

ListAtmospheric Heat Budget Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About...

151

High-efficiency solar cells fabricated from direct-current magnetron sputtered n-indium tin oxide onto p-InP grown by atmospheric pressure metalorganic vapor phase epitaxy  

SciTech Connect

Solar cells based on dc magnetron sputtered indium tin oxide onto epitaxially grown films of p-InP have been fabricated and analyzed. The best cells had a global efficiency of 18.4% and an air mass zero (AMO) efficiency of 16.0%. The principal fabrication variable considered was the constituency of the sputtering gas and both argon/hydrogen and argon/oxygen mixtures have been used. The former cells have the higher efficiencies, are apparently stable, and exhibit almost ideal junction characteristics. The latter cells are relatively unstable and exhibit much higher ideality factors and reverse saturation current densities. The temperature dependence of the reverse saturation current indicates totally different charge transfer mechanisms in the two cases.

Li, X.; Wanlass, M.W.; Gessert, T.A.; Emery, K.A.; Coutts, T.J.

1989-05-01T23:59:59.000Z

152

Conference on Atmospheric Pollution  

Science Journals Connector (OSTI)

... THE half-yearly Conference of representatives of local authorities and other organisations co-operating with the Department of Scientific ... of atmospheric pollution was held in the offices of the Department on May 25. The Conference received from Dr. G. M. B. Dobson, chairman of the Atmospheric Pollution ...

1936-05-30T23:59:59.000Z

153

Deposition of TiO2 thin films by atmospheric plasma post-discharge assisted injection MOCVD  

E-Print Network (OSTI)

Deposition of TiO2 thin films by atmospheric plasma post-discharge assisted injection MOCVD C Keywords : Injection MOCVD, Atmospheric Plasma, titanium oxide, anatase, PECVD Abstract TiO2 thin films combines remote Atmospheric Pressure (AP) Plasma with Pulsed Injection Metallorganic Chemical Vapour

Boyer, Edmond

154

Why Sequence a Methane-Oxidizing Archaean?  

NLE Websites -- All DOE Office Websites (Extended Search)

a Methane-Oxidizing Archaeon? a Methane-Oxidizing Archaeon? Methane is a potent greenhouse gas whose atmospheric concentration has increased significantly because of anthropogenic activities and fluctuated naturally over glacial and interglacial cycles. While the importance of methane in Earth's climate dynamics has been well established, the global processes regulating its oceanic cycling remain poorly understood. Although there are high rates of methane production in many marine sedimentary environments (including a number that have been targeted as petroleum reserves), net methane sources from the ocean to the atmosphere appear to be small. This is due in large part to a biogeochemical process known as the anaerobic oxidation of methane (AOM). Microbially mediated AOM reduces methane flux from ocean to atmosphere, stimulates subsurface microbial

155

Atmospheric Physics and Earth Observations  

Science Journals Connector (OSTI)

...has been used by atmospheric modelers as a vertical...Ackerman, in Atmospheric Physics from Spacelab...shut-tle allows recovery of the film, we...dry nitrogen at atmospheric pressure. To avoid water condensation on the optical...

M. HERSÉ

1984-07-13T23:59:59.000Z

156

Decomposition Mechanism of Fluorinated Compounds in Water Plasmas Generated Under Atmospheric Pressure  

Science Journals Connector (OSTI)

We developed a DC water plasma torch which with a cathode of...16...]. The hafnium used as cathode material can overcome the erosion problems and achieve a long operating time in oxidation atmospheric. The torch ...

Narengerile; Hironori Saito; Takayuki Watanabe

2010-12-01T23:59:59.000Z

157

Nature: Earth's Atmosphere and Beyond  

Science Journals Connector (OSTI)

Nature: Earth's Atmosphere and Beyond ... The column summarizes research articles from Nature that report on anthropogenic activities and natural phenomena that influence the chemical composition of Earth's atmosphere. ...

Sabine Heinhorst; Gordon Cannon

2003-10-01T23:59:59.000Z

158

The atmosphere of Venus  

Science Journals Connector (OSTI)

The investigations of Venus take a special position in planetary researches. It was just the atmosphere of Venus where first measurements in situ were carried out by means of the equipment delivered by a space pr...

V. I. Moroz

1981-01-01T23:59:59.000Z

159

Atmospheric Dynamics of Exoplanets  

E-Print Network (OSTI)

The characterization of exoplanetary atmospheres has come of age in the last decade, as astronomical techniques now allow for albedos, chemical abundances, temperature profiles and maps, rotation periods and even wind speeds to be measured. Atmospheric dynamics sets the background state of density, temperature and velocity that determines or influences the spectral and temporal appearance of an exoplanetary atmosphere. Hot exoplanets are most amenable to these characterization techniques; in the present review, we focus on highly-irradiated, large exoplanets (the "hot Jupiters"), as astronomical data begin to confront theoretical questions. We summarize the basic atmospheric quantities inferred from the astronomical observations. We review the state of the art by addressing a series of current questions and look towards the future by considering a separate set of exploratory questions. Attaining the next level of understanding will require a concerted effort of constructing multi-faceted, multi-wavelength dat...

Heng, Kevin

2014-01-01T23:59:59.000Z

160

Steam Oxidation of Advanced Steam Turbine Alloys  

SciTech Connect

Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650°C to 800°C) to steam at 34.5 MPa (650°C to 760°C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

Holcomb, Gordon R.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Ethylene Oxide Gaseous Sterilization: II. Influence of Method of Humidification  

Science Journals Connector (OSTI)

...materials tend to remove water vapor from a gas mixture...that the penetration of water vapor into adsorbent...room atmosphere. The atmospheric relative humidity remained...prior to exposure to water vapor and ethylene oxide. The medium employed for recovery of viable cells after...

Robert R. Ernst; James J. Shull

1962-07-01T23:59:59.000Z

162

*Corresponding author. Atmospheric Environment 34 (2000) 1921}1957  

E-Print Network (OSTI)

of O , O -precursors (including the odd-hydrogen free radicals), the oxidation products*Corresponding author. Atmospheric Environment 34 (2000) 1921}1957 Methods for gas concludes with a brief discussion of calibration methods and standards and tests that should be routinely

Sillman, Sanford

163

Regional Modeling of the Atmospheric Fate and Transport of Benzene and Diesel Particles  

Science Journals Connector (OSTI)

It is oxidized in the atmosphere slowly by hydroxyl (OH) radicals; its atmospheric lifetime is on the order of 1 week. ... The surrogates used in this study include agriculture, airports, housing, major highways, ports, population, railroads, water, and land area. ... PM2.5 emissions from the 1996 EPA National Emission Trends (NET) were used to generate diesel particle emissions. ...

Christian Seigneur; Betty Pun; Kristen Lohman; Shiang-Yuh Wu

2003-10-17T23:59:59.000Z

164

Carbon Monoxide Oxidation by Bacteria Associated with the Roots of Freshwater Macrophytes  

Science Journals Connector (OSTI)

...consumption and production of atmospheric carbon monoxide by...the consumption of atmospheric carbon monoxide by...rapid oxidation of atmospheric CO to CO2 by soils...D. Influence of water table on carbon dioxide...rice fields and biogas generators: CH4, N2O, CO...

Jeremy J. Rich; G. M. King

1998-12-01T23:59:59.000Z

165

The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain  

E-Print Network (OSTI)

This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

Xu, Xin, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

166

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling  

Energy.gov (U.S. Department of Energy (DOE))

A first set of results has found that LASAR and VLPS data in the laboratory closely correlate with real-time, in-use measurement of NH3 and NO under various driving conditions.

167

Denitrifying Alphaproteobacteria from the Arabian Sea That Express nosZ, the Gene Encoding Nitrous Oxide Reductase, in Oxic and Suboxic Waters  

Science Journals Connector (OSTI)

...United Kingdom under the Marine and Freshwater Microbial...Keith Avery, and the ship's company of RRS Charles...Woodward of Plymouth Marine Laboratory, United Kingdom...gene-specific PCR primers for detection of denitrifiers and three nosZ genes from marine sediments. FEMS Microbiol...

Michael Wyman; Sylvia Hodgson; Clare Bird

2013-02-08T23:59:59.000Z

168

Graphite Oxidation Thermodynamics/Reactions  

SciTech Connect

The vulnerability of graphite-matrix spent nuclear fuel to oxidation by the ambient atmosphere if the fuel canister is breached was evaluated. Thermochemical and kinetic data over the anticipated range of storage temperatures (200 to 400 C) were used to calculate the times required for a total carbon mass loss of 1 mgcm-2 from a fuel specimen. At 200 C, the time required to produce even this small loss is large, 900,000 yr. However, at 400 C the time required is only 1.9 yr. The rate of oxidation at 200 C is negligible, and the rate even at 400 C is so small as to be of no practical consequence. Therefore, oxidation of the spent nuclear fuel upon a loss of canister integrity is not anticipated to be a concern based upon the results of this study.

Propp, W.A.

1998-09-01T23:59:59.000Z

169

Atmos. Chem. Phys., 11, 88098823, 2011 www.atmos-chem-phys.net/11/8809/2011/  

E-Print Network (OSTI)

of the particulate matter were carbonaceous materials, such as humic acid, water sol- uble organics, and less soluble in public concern regarding the emission of atmospheric pollutants, including gas phase and particulate from livestock include methane (CH4), ammonia (NH3), nitrogen oxides (NOx), and nitrous oxide (N2O

Meskhidze, Nicholas

170

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually.  

E-Print Network (OSTI)

Fertilizer and Nitrogen 1 billion tons of artificial nitrogen fertilizer used annually. Emissions. (fertilizers that use nitric acid or ammonium bicarbonate result in emissions of nitrogen oxides, nitrous oxide, ammonia and carbon dioxide into the atmosphere.) ~Indirect: Phosphorus in excess causes eutrophication

Toohey, Darin W.

171

Stochastic Six-Degree-of-Freedom Flight Simulator for Passively Controlled High-Power Rockets  

E-Print Network (OSTI)

are alternatively powered by hybrid motors using a liquid oxidizer, e.g., nitrous Oxide N2O and a solid fuel, e historical atmospheric data. The core simulation algorithm is a numerical integration of the rocket's equations of motion using the Runge-Kutta-Fehlberg method. The position of the rocket's center of mass

Bishop, Christopher M.

172

Article Atmospheric Science  

NLE Websites -- All DOE Office Websites (Extended Search)

© The Author(s) 2012. This article is published with open access at Springerlink.com csb.scichina.com www.springer.com/scp © The Author(s) 2012. This article is published with open access at Springerlink.com csb.scichina.com www.springer.com/scp *Corresponding author (email: luchunsong110@gmail.com) Article Atmospheric Science February 2013 Vol.58 No.4-5: 545  551 doi: 10.1007/s11434-012-5556-6 A method for distinguishing and linking turbulent entrainment mixing and collision-coalescence in stratocumulus clouds LU ChunSong 1,2* , LIU YanGang 2 & NIU ShengJie 1 1 Key Laboratory for Atmospheric Physics and Environment of China Meteorological Administration, Key Laboratory of Meteorological Disaster of Ministry of Education, Nanjing University of Information Science and Technology, Nanjing 210044, China; 2 Atmospheric Sciences Division, Brookhaven National Laboratory, New York 11973, USA

173

ARM - Measurement - Atmospheric moisture  

NLE Websites -- All DOE Office Websites (Extended Search)

moisture moisture ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric moisture The moisture content of the air as indicated by several measurements including relative humidity, specific humidity, dewpoint, vapor pressure, water vapor mixing ratio, and water vapor density; note that precipitable water is a separate type. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments AERI : Atmospheric Emitted Radiance Interferometer

174

BNL | Atmospheric Systems Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric System Research is a DOE observation-based research program Atmospheric System Research is a DOE observation-based research program created to advance process-level understanding of the key interactions among aerosols, clouds, precipitation, radiation, dynamics, and thermodynamics, with the ultimate goal of reducing the uncertainty in global and regional climate simulations and projections. General areas of research at BNL under this program include studies of aerosol and cloud lifecycles, and cloud-aerosol-precipitation interactions. Contact Robert McGraw, 631.344.3086 aerosols Aerosol Life Cycle The strategic focus of the Aerosol Life Cycle research is observation-based process science-examining the properties and evolution of atmospheric aerosols. Observations come from both long-term studies conducted by the

175

ARM - Measurement - Atmospheric pressure  

NLE Websites -- All DOE Office Websites (Extended Search)

pressure pressure ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric pressure The pressure exerted by the atmosphere as a consequence of gravitational attraction exerted upon the "column" of air lying directly above the point in question. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments SONDE : Balloon-Borne Sounding System CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

176

ARM - Measurement - Atmospheric temperature  

NLE Websites -- All DOE Office Websites (Extended Search)

temperature temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric temperature The temperature indicated by a thermometer exposed to the air in a place sheltered from direct solar radiation. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments AERI : Atmospheric Emitted Radiance Interferometer SONDE : Balloon-Borne Sounding System CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

177

Atmospheres of Brown Dwarfs  

E-Print Network (OSTI)

Brown Dwarfs are the coolest class of stellar objects known to date. Our present perception is that Brown Dwarfs follow the principles of star formation, and that Brown Dwarfs share many characteristics with planets. Being the darkest and lowest mass stars known makes Brown Dwarfs also the coolest stars known. This has profound implication for their spectral fingerprints. Brown Dwarfs cover a range of effective temperatures which cause brown dwarfs atmospheres to be a sequence that gradually changes from a M-dwarf-like spectrum into a planet-like spectrum. This further implies that below an effective temperature of atmospheres of objects marking the boundary between M-Dwarfs and brown dwarfs. Recent developments have sparked the interest in plasma processes in such very cool atmospheres: sporadic and quiescent radio emission has been observed in combination with decaying Xray-activity indicators across the fully convective boundary.

Helling, Christiane

2014-01-01T23:59:59.000Z

178

Sub-Doppler Spectra of Infrared Hyperfine Transitions of Nitric Oxide Using a Pulse Modulated Quantum Cascade Laser: Rapid Passage, Free Induction Decay and the AC Stark Effect  

SciTech Connect

Using a low power, rapid (nsec) pulse-modulated quantum cascade (QC) laser, collective coherent effects in the 5 {micro}m spectrum of nitric oxide have been demonstrated by the observation of sub-Doppler hyperfine splitting and also Autler-Townes splitting of Doppler broadened lines. For nitrous oxide, experiments and model calculations have demonstrated that two main effects occur with ulsemodulated (chirped) quantum cascade lasers: free induction decay signals, and signals induced by rapid passage during the laser chirp. In the open shell molecule, NO, in which both {Lambda}-doubling splitting and hyperfine structure occur, laser field-induced coupling between the hyperfine levels of the two {Lambda}-doublet components can induce a large AC Stark effect. This may be observed as sub-Doppler structure, field-induced splittings, or Autler-Townes splitting of a Doppler broadened line. These represent an extension of the types of behaviour observed in the closed shell molecule nitrous oxide, using the same apparatus, when probed with an 8 {micro}m QC laser.

Duxbury, Geoffrey; Kelly, James F.; Blake, Thomas A.; Langford, Nigel

2012-05-07T23:59:59.000Z

179

Dynamics of Planetary Atmospheres  

E-Print Network (OSTI)

pressure (bars) N2 82%; Ar 12%; CH4 6%CO2 96.5%; N2 3.5%Atmospheric composition 26177Orbital inclination (1992) orbiter ­ Winds from cloud-tracking and probe drifts ­ IR temperatures, solar-fixed tides, polar-Huygens mission (from 2005) ­ Doppler wind descent profile ­ IR temperature and composition maps ­ Visible, IR

Read, Peter L.

180

Characterization of vanadate-dependent NADH oxidation stimulated by Saccharomyces cerevisiae plasma membranes.  

Science Journals Connector (OSTI)

...oxidation activity of yeast plasma membranes for molecular DH...vanadate-dependent nonenzymatic and plasma mem- DH. Each point is brane-stimulated...aFor nonenzymatic nitrogen atmosphere, but NADH oxidation resumed...consumption of oxygen during Plasma membrane- the oxidation of...

L A Minasi; G R Willsky

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement  

NLE Websites -- All DOE Office Websites (Extended Search)

An Integrated Column Description An Integrated Column Description of the Atmosphere An Integrated Column Description of the Atmosphere Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Pacific Northwest National Laboratory Pacific Northwest National Laboratory The "other" Washington ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Credits to Credits to * Ric Cederwall * Xiquan Dong * Chuck Long * Jay Mace * Mark Miller * Robin Perez * Dave Turner and the rest of the ARM science team * Ric Cederwall * Xiquan Dong * Chuck Long * Jay Mace * Mark Miller * Robin Perez * Dave Turner and the rest of the ARM science team ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Outline Outline * A little philosophy

182

ATMOSPHERIC ELSEVIER AtmosphericResearch40 (1996) 223-259  

E-Print Network (OSTI)

of atmospheric aerosol particles and cloud hydrometeors (water drops, ice particles, and, particularlyATMOSPHERIC RESEARCH ELSEVIER AtmosphericResearch40 (1996) 223-259 Simulations of drop fall turbulence. The model permits us to generate different realizations of the random velocity field component

Mark, Pinsky

183

Quantitative infrared absorption cross sections of isoprene for atmospheric measurements  

SciTech Connect

The OH- and O3- initiated oxidations of isoprene, which is one of the primary volatile organic compounds produced by vegetation, are a major source of atmospheric formaldehyde and other oxygenated organics, yet little quantitative IR data exists for isoprene. We thus report absorption coefficients and integrated band intensities for isoprene in the 600 - 6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in a 19.96 cm path length cell at 0.112 cm-1 resolution, using a Bruker 66V FTIR. Composite spectra are derived from a minimum of seven pressures at each temperature.

Brauer, Carolyn S.; Blake, Thomas A.; Guenther, Alex B.; Sharpe, Steven W.; Sams, Robert L.; Johnson, Timothy J.

2014-11-19T23:59:59.000Z

184

ARM - Measurement - Atmospheric turbulence  

NLE Websites -- All DOE Office Websites (Extended Search)

turbulence turbulence ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric turbulence High frequency velocity fluctuations that lead to turbulent transport of momentum, heat, mositure, and passive scalars, and often expressed in terms of variances and covariances. Categories Atmospheric State, Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

185

Differential atmospheric tritium sampler  

DOE Patents (OSTI)

An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The moisture then passes through a combustion chamber where hydrogen gas in the form of H/sub 2/ or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

Griesbach, O.A.; Stencel, J.R.

1987-10-02T23:59:59.000Z

186

Differential atmospheric tritium sampler  

DOE Patents (OSTI)

An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The mixture then passes through a combustion chamber where hydrogen gas in the form of H.sub.2 or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

Griesbach, Otto A. (Langhorne, PA); Stencel, Joseph R. (Skillman, NJ)

1990-01-01T23:59:59.000Z

187

Oxidation of Propane by Doped Nickel Oxides  

Science Journals Connector (OSTI)

... present study, however, indicate that in the absence of excess oxygen, direct oxidation of propane by the oxide lattice can occur.

D. W. McKEE

1964-04-11T23:59:59.000Z

188

The changing atmosphere  

SciTech Connect

The chemistry of the atmosphere is changing, in large measure because of gases emitted by such human activities as farming, manufacturing, and the combustion of fossil fuels. The deleterious effects are increasingly evident; they may well become worse in the years ahead. This paper discusses the pollutants and the environmental perturbations with which they are associated. The authors believe the solution to the earth's environmental problems lies in a truly global effort.

Graedel, T.E.; Crutzen, P.J.

1989-09-01T23:59:59.000Z

189

Nitrogen oxides emission trends in Monthly emission estimates of nitrogen oxides from space provide  

E-Print Network (OSTI)

Chapter 5 Nitrogen oxides emission trends in East Asia Abstract Monthly emission estimates present first results of a new emission estimation algorithm, specifically designed to use daily satellite observations of column concentrations for fast updates of emission estimates of short-lived atmospheric

Haak, Hein

190

ORISE: Climate and Atmospheric Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Climate and Atmospheric Research Climate and Atmospheric Research Capabilities Overview U.S. Climate Reference Network U.S. Historical Climate Network Contact Us Oak Ridge Institute for Science Education Climate and Atmospheric Research The Oak Ridge Institute for Science and Education (ORISE) partners with the National Oceanic and Atmospheric Administration's Atmospheric Turbulence and Diffusion Division (ATDD) to conduct climate research focused on issues of national and global importance. Research is performed with personnel support from ORISE's Independent Environmental Assessment and Verification (IEAV) programs, as well as in collaboration with scientists and engineers from Oak Ridge National Laboratory (ORNL), and numerous other organizations, government agencies, universities and private research institutions.

191

Atmospheric Pressure Deposition for Electrochromic Windows |...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Atmospheric Pressure Deposition for Electrochromic Windows Atmospheric Pressure Deposition for Electrochromic Windows Emerging Technologies Project for the 2013 Building...

192

Summary Much attention is focused today on predicting how plants will respond to anticipated changes in atmospheric  

E-Print Network (OSTI)

, such as methane, became oxidized to form an early CO2-rich atmosphere. Over time, the concentration of carbon the atmosphere. Burial and lithification of carbonates and organic matter to limestone, coal or keragen the detailed history of CO2 is not well known for the whole of earth's history, some periods are reasonably

Ehleringer, Jim

193

Atmospheric Chemistry of Dichlorvos  

Science Journals Connector (OSTI)

Atmospheric Chemistry of Dichlorvos ... In the positive ion mode, protonated water hydrates (H3O+(H2O)n) generated by the corona discharge in the chamber diluent air were responsible for the protonation of analytes, and the ions that were mass analyzed were mainly protonated molecules ([M + H]+) and their protonated homo- and heterodimers. ... Methyl nitrite, 2-propyl nitrite and N2O5 were prepared and stored as described previously,(8, 10) and O3 in O2 diluent was generated using a Welsbach T-408 ozone generator. ...

Sara M. Aschmann; Ernesto C. Tuazon; William D. Long; Roger Atkinson

2011-03-15T23:59:59.000Z

194

Atmospheric chemistry of automotive fuel additives: Diisopropyl ether  

SciTech Connect

To quantify the atmospheric reactivity of diisopropyl ether (DIPE), we have conducted a study of the kinetics and mechanism of reaction 1: OH + DIPE {r_arrow} products. Kinetic measurements of reaction 1 were made using both relative (at 295 K) and absolute techniques (over the temperature range 240-440 K). Rate data from both techniques can be represented by the following: k{sub 1} = (2.2{sub -0.8}{sup +14}) x 10{sup -12} exp[(445 {plus_minus} 145)/T] cm{sup 3} molecule{sup -1}s{sup -1}. At 298 K, k{sub 1} = 9.8 x 10{sup -12} cm{sup 3} molecule{sup -1}s{sup -1}. The products of the simulated atmospheric oxidation of DIPE were identified using FT-IR spectroscopy; isopropyl acetate and HCHO were the main products. The atmospheric oxidation of DIPE can be represented by i-C{sub 3}H{sub 7}O-i-C{sub 3}H{sub 7} + OH + 2NO {r_arrow} HCHO + i-C{sub 3}H{sub 7}OC(O)CH{sub 3} + HO{sub 2} + 2NO{sub 2}. Our kinetic and mechanistic data were incorporated into a 1-day simulation of atmospheric chemistry to quantify the relative incremental reactivity of DIPE. Results are compared with other oxygenated fuel additives. 30 refs., 9 figs.

Wallington, T.J.; Andino, J.M.; Potts, A.R. [Ford Motor Company, Dearborn, MI (United States)] [and others

1993-01-01T23:59:59.000Z

195

Atmospheric propagation of THz radiation.  

SciTech Connect

In this investigation, we conduct a literature study of the best experimental and theoretical data available for thin and thick atmospheres on THz radiation propagation from 0.1 to 10 THz. We determined that for thick atmospheres no data exists beyond 450 GHz. For thin atmospheres data exists from 0.35 to 1.2 THz. We were successful in using FASE code with the HITRAN database to simulate the THz transmission spectrum for Mauna Kea from 0.1 to 2 THz. Lastly, we successfully measured the THz transmission spectra of laboratory atmospheres at relative humidities of 18 and 27%. In general, we found that an increase in the water content of the atmosphere led to a decrease in the THz transmission. We identified two potential windows in an Albuquerque atmosphere for THz propagation which were the regions from 1.2 to 1.4 THz and 1.4 to 1.6 THz.

Wanke, Michael Clement; Mangan, Michael A.; Foltynowicz, Robert J.

2005-11-01T23:59:59.000Z

196

Fabrication of ZnO/Cu2O heterojunctions in atmospheric conditions: improved interface quality and solar cell performance  

E-Print Network (OSTI)

Zn_1-xMg_xO/Cu_2O heterojunctions were successfully fabricated in open-air at low temperatures via atmospheric atomic layer deposition of Zn_1-xMg_xO on thermally oxidized cuprous oxide. Solar cells employing these heterojunctions demonstrated a...

Ievskaya, Y.; Hoye, R. L. Z.; Sadhanala, A.; Musselman, K.; MacManus-Driscoll, J. L.

2014-01-01T23:59:59.000Z

197

EMSL: Science: Atmospheric Aerosol Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Aerosol Systems Atmospheric Aerosol Systems atmospheric logo Nighttime enhancement of nitrogen-containing organic compounds, or NOC Observed nighttime enhancement of nitrogen-containing organic compounds, or NOC, showed evidence of being formed by reactions that transform carbonyls into imines. The Atmospheric Aerosol Systems Science Theme focuses on understanding the chemistry, physics and molecular-scale dynamics of aerosols for model parameterization to improve the accuracy of climate model simulations and develop a predictive understanding of climate. By elucidating the role of natural and anthropogenic regional and global climate forcing mechanisms, EMSL can provide DOE and others with the ability to develop cost-effective strategies to monitor, control and mitigate them.

198

ARM - Evolution of the Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

provides clues as to the composition of the early atmosphere. Volcanic emissions include nitrogen, sulfur dioxide, carbon dioxide, and trace gases such as argon. Although oxygen,...

199

Direct Non-oxidative Methane Conversion by Non-thermal Plasma: Experimental Study  

Science Journals Connector (OSTI)

The direct non-oxidative conversion of methane to higher hydrocarbons in non-thermal plasma, namely dielectric barrier discharge and corona discharge, has been investigated experimentally at atmospheric pressure....

Yun Yang

2003-06-01T23:59:59.000Z

200

Direct Non-oxidative Methane Conversion by Non-thermal Plasma: Modeling Study  

Science Journals Connector (OSTI)

The direct non-oxidative conversion of methane to higher hydrocarbons ... dielectric barrier discharges has been investigated theoretically at atmospheric pressure. Preliminary modeling of the results is...2...hy...

Yun Yang

2003-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Oxidation of No to No2 in Flue Gas Plumes of Power Stations  

Science Journals Connector (OSTI)

The oxidation of NO to NO2 in flue gas plumes takes place after release in the ... function of the turbulent mixing rate of flue gas plume and atmospheric air. The effects of ... are illustrated with the measurin...

A. J. Elshout; Dr. S. Beilke

1984-01-01T23:59:59.000Z

202

Calculation of the emission of nitrogen oxides in electric resistance heating furnaces  

Science Journals Connector (OSTI)

The present paper is devoted to the least studied topic in the field of use of modern electric heating equipment, namely, pollution of the atmosphere by nitrogen oxides and reduction of the intensity of this e...

A. V. Aksenov; V. A. Belyakov; Z. G. Sadykova

1998-02-01T23:59:59.000Z

203

GISS ICP at Columbia University SSttuuddyyiinngg GGlloobbaall CChhaannggee aanndd tthhee EEnnvviirroonnmmeenntt  

E-Print Network (OSTI)

large quantities of fossil fuels such as petroleum, coal and natural gas. Burning fossil fuels release additional greenhouse gases, such as nitrous oxide, methane and carbon dioxide into the atmosphere storage in the trees. We can study this forest carbon as well, with land-use variations (fire) as we began

204

Isotopes Environ. Health Stud., 2003, Vol. 39(1), pp. 4152 TREE SPECIES OF THE CENTRAL AMAZON AND  

E-Print Network (OSTI)

AND SOIL MOISTURE ALTER STABLE ISOTOPE COMPOSITION OF NITROGEN AND OXYGEN IN NITROUS OXIDE EVOLVED FROM SB RAS, Krasnoyarsk, Russia; b Department of Biological Sciences and Merriam-Powell Center; Oxygen 18; Tree species; Tropical soils INTRODUCTION The increase in the atmospheric concentration

Lehmann, Johannes

205

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

Jin, Xin

2012-07-16T23:59:59.000Z

206

DOE research on atmospheric aerosols  

SciTech Connect

Atmospheric aerosols are the subject of a significant component of research within DOE`s environmental research activities, mainly under two programs within the Department`s Environmental Sciences Division, the Atmospheric Radiation Measurement (ARM) Program and the Atmospheric Chemistry Program (ACP). Research activities conducted under these programs include laboratory experiments, field measurements, and theoretical and modeling studies. The objectives and scope of these programs are briefly summarized. The ARM Program is the Department`s major research activity focusing on atmospheric processes pertinent to understanding global climate and developing the capability of predicting global climate change in response to energy related activities. The ARM approach consists mainly of testing and improving models using long-term measurements of atmospheric radiation and controlling variables at highly instrumented sites in north central Oklahoma, in the Tropical Western Pacific, and on the North Slope of Alaska. Atmospheric chemistry research within DOE addresses primarily the issue of atmospheric response to emissions from energy-generation sources. As such this program deals with the broad topic known commonly as the atmospheric source-receptor sequence. This sequence consists of all aspects of energy-related pollutants from the time they are emitted from their sources to the time they are redeposited at the Earth`s surface.

Schwartz, S.E.

1995-11-01T23:59:59.000Z

207

Space Science : Atmosphere Greenhouse Effect  

E-Print Network (OSTI)

Space Science : Atmosphere Greenhouse Effect Part-5a Solar + Earth Spectrum IR Absorbers Grey Atmosphere Greenhouse Effect #12;Radiation: Solar and Earth Surface B"(T) Planck Ideal Emission Integrate at the carbon cycle #12;However, #12;Greenhouse Effect is Complex #12;PLANETARY ENERGY BALANCE G+W fig 3-5

Johnson, Robert E.

208

Transition metal oxides deposited on rhodium and platinum: Surface chemistry and catalysis  

SciTech Connect

The surface chemistry and catalytic reactivity of transition metal oxides deposited on Rh and Pt substrates has been examined in order to establish the role of oxide-metal interactions in influencing catalytic activity. The oxides investigated included titanium oxide (TiOx), vanadium oxide (VOx), iron oxide (FeOx), zirconium oxide (ZrOx), niobium oxide (NbOx), tantalum oxide (TaOx), and tungsten oxide (WOx). The techniques used to characterize the sample included AES, XPS, LEED, TPD, ISS, and STM. After characterization of the surface in UHV, the sample was enclosed in an atmospheric reaction cell to measure the influence of the oxide deposits on the catalytic activity of the pure metal for CO and CO{sub 2} hydrogenation. The oxide deposits were found to strongly enhance the reactivity of the Rh foil. The rates of methane formation were promoted by up to 15 fold with the maximum in rate enhancement occurring at oxide coverages of approximately 0.5 ML. TiOx TaOx, and NbOx were the most effective promoters and were stable in the highest oxidation states during both reactions (compared to VOx, WOx, and FeOx). The trend in promoter effectiveness was attributed to the direct relationship between oxidation state and Lewis acidity. Bonding at the metal oxide/metal interface between the oxygen end of adsorbed CO and the Lewis acidic oxide was postulated to facilitate C-O bond dissociation and subsequent hydrogenation. 192 refs.

Boffa, A.B. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Materials Sciences Div.

1994-07-01T23:59:59.000Z

209

Method of producing highly oxidized superconductors containing barium, copper, and a third metal  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

Morris, D.E.

1996-02-20T23:59:59.000Z

210

Author's personal copy Highly active surfaces for CO oxidation on Rh, Pd, and Pt  

E-Print Network (OSTI)

to that found at ultrahigh vacuum (UHV) condi- tions [4]. In contrast, for Ru the reaction mechanism is dra- matically different for CO oxidation at UHV conditions and at atmospheric conditions [14,25]. In UHV, Ru that measured in UHV. The signif- icantly higher activity near one atmosphere at stoichiome- tric reaction

Goodman, Wayne

211

Atmospheric Radiation Measurement (ARM) Climate Research Facility and Atmospheric  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Radiation Measurement (ARM) Atmospheric Radiation Measurement (ARM) Climate Research Facility and Atmospheric System Research (ASR) Science and Infrastructure Steering Committee CHARTER June 2012 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not

212

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.  

E-Print Network (OSTI)

complexes between nitrogen dioxide, nitric acid, nitrous1992) Indoor ozone and nitrogen dioxide: A potential pathwaybed of SiO 2 pellets. Nitrogen dioxide is introduced from a

2009-01-01T23:59:59.000Z

213

Method for fluorination of uranium oxide  

DOE Patents (OSTI)

Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

Petit, George S. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

214

Interfacial oxide re-growth in thin film metal oxide III-V semiconductor systems  

SciTech Connect

The Al{sub 2}O{sub 3}/GaAs and HfO{sub 2}/GaAs interfaces after atomic layer deposition are studied using in situ monochromatic x-ray photoelectron spectroscopy. Samples are deliberately exposed to atmospheric conditions and interfacial oxide re-growth is observed. The extent of this re-growth is found to depend on the dielectric material and the exposure temperature. Comparisons with previous studies show that ex situ characterization can result in misleading conclusions about the interface reactions occurring during the metal oxide deposition process.

McDonnell, S.; Dong, H.; Hawkins, J. M.; Brennan, B.; Milojevic, M.; Aguirre-Tostado, F. S.; Zhernokletov, D. M.; Hinkle, C. L.; Kim, J.; Wallace, R. M.

2012-04-02T23:59:59.000Z

215

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors  

Science Journals Connector (OSTI)

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors ... For safety and environmental protection reasons (to avoid syngas release into the atmosphere), after the analysis section, the reacted gas stream was completely oxidized by forced air in a catalytic honeycomb burner (Figure 2). ...

S. Specchia; L. D. Vella; B. Lorenzut; T. Montini; V. Specchia; P. Fornasiero

2009-07-22T23:59:59.000Z

216

Iron(III) Oxides from Thermal ProcessesSynthesis, Structural and Magnetic Properties, Mössbauer Spectroscopy Characterization, and Applications  

Science Journals Connector (OSTI)

Structural and magnetic properties, methods of synthesis, and applications of seven iron(III) oxide polymorphs, including rare beta, epsilon, amorphous, and high-pressure forms, are reviewed. ... Their discoveries as well as the majority of formation processes are connected with thermal transformations of iron-bearing materials in an oxidizing atmosphere. ... Iron(III) oxide in all its forms is one of the most used metal oxides with various applications in many scientific and industrial fields. ...

Radek Zboril; Miroslav Mashlan; Dimitris Petridis

2002-02-28T23:59:59.000Z

217

Observing chemistry of atmospheric particles | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Observing chemistry of atmospheric particles Observing chemistry of atmospheric particles Review article reached the International Reviews in Physical Chemistry most read list NULL...

218

Radon Content of the Atmosphere  

Science Journals Connector (OSTI)

... preliminary work. The absence of levels of a higher order suggests that the contribution of radon from this source does not represent a significant addition to the total atmospheric level. ... Domestic 0.70

W. ANDERSON; R. C. TURNER

1956-07-28T23:59:59.000Z

219

The Scientific Basis of Tobacco Product Regulation  

E-Print Network (OSTI)

contains nitric oxide, nitrogen dioxide and nitrous oxide,nitric oxide, while nitrogen dioxide is rapidly formedreadily oxidized to nitrogen dioxide, a pulmonary irritant.

World Health Organization

2008-01-01T23:59:59.000Z

220

Laser Atmospheric Studies with VERITAS  

E-Print Network (OSTI)

As a calibrated laser pulse propagates through the atmosphere, the amount of Rayleigh-scattered light arriving at the VERITAS telescopes can be calculated precisely. This technique was originally developed for the absolute calibration of ultra-high-energy cosmic-ray fluorescence telescopes but is also applicable to imaging atmospheric Cherenkov telescopes (IACTs). In this paper, we present two nights of laser data taken with the laser at various distances away from the VERITAS telescopes and compare it to Rayleigh scattering simulations.

C. M. Hui; for the VERITAS collaboration

2007-09-25T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Doubling of atmospheric methane supported  

SciTech Connect

Atmospheric methane over the past 27,000 years was measured by analyzing air trapped in glacial ice in Greenland and Antarctica. Atmospheric concentrations were stable over that period until about 200 years b.p. In the last 200 years they have more than doubled. This change in concentration is correlated with the increase in human population; the implications for climate modification are discussed. 1 figure, 3 references.

Kerr, R.A.

1984-11-23T23:59:59.000Z

222

Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz  

E-Print Network (OSTI)

potential than emissions in the United States to perturb the global oxidizing power of the atmosphere. #12% of NOx concentrations in the lower and middle troposphere throughout the extratropical northern of the ocean. Sources in the United States are found to contribute about half of the fossil fuel NOx over

Jacob, Daniel J.

223

Modeling atmospheric effects of the September 1859 solar flare B. C. Thomas,1  

E-Print Network (OSTI)

the production of odd hydrogen- and nitrogen-oxides. Production of HOx (e.g., H, OH, HO2) and NOy (e.g., N, NO showing production of odd nitrogen compounds and their impact on ozone. We also compute rainout of nitrate. Methods [4] Our modeling was performed using the Goddard Space Flight Center two-dimensional atmospheric

Jackman, Charles H.

224

Variability in morphology, hygroscopicity, and optical properties of soot aerosols during atmospheric processing  

Science Journals Connector (OSTI)

...12), or engine combustion (16...mass, we draw fundamental conclusions of atmospheric...particles from diesel combustion by using combined...Properties of jet engine combustion particles...of carbon and diesel soot particles...vehicle with a diesel oxidation catalyst . J...Boubel RW ( 1994 ) Fundamentals of Air Pollution...

Renyi Zhang; Alexei F. Khalizov; Joakim Pagels; Dan Zhang; Huaxin Xue; Peter H. McMurry

2008-01-01T23:59:59.000Z

225

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents (OSTI)

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

Rashid Khan, M.

1988-05-05T23:59:59.000Z

226

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents (OSTI)

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

Khan, M. Rashid (Morgantown, WV)

1989-01-01T23:59:59.000Z

227

Oxidation of propylene over copper oxide catalysts  

E-Print Network (OSTI)

to the study of propylene oxidation. Dunlop (17) reported that small quantities of iron compounds substantially enhanced the catalytic activity of chromia-alumina catalysts with respect to propylene oxidation, Woodharn (72) has suggested that under... between 360 C and 430oC the rate of propane oxidation decreases as the teznperature is increased, and the rate of conversion to olefins, especially propylene, becomes progressively greater. Above 430 C the proportion of propane converted to ethylene in...

Billingsley, David Stuart

2012-06-07T23:59:59.000Z

228

Prediction of Chinese coal ash fusion temperatures in Ar and H{sub 2} atmospheres  

SciTech Connect

The ash fusion temperatures (AFTs) of 21 typical Chinese coal ash samples and 60 synthetic ash samples were measured in Ar and H{sub 2} atmospheres. The computer software package FactSage was used to calculate the temperatures corresponding to different proportions of the liquid phase and predict the phase equilibria of synthetic ash samples. Empirical liquidus models were derived to correlate the AFTs under both Ar and H{sub 2} atmospheres of 60 synthetic ash samples, with their liquidus temperatures calculated by FactSage. These models were used to predict the AFTs of 21 Chinese coal ash samples in Ar and H{sub 2} atmospheres, and then the AFT differences between the atmospheres were analyzed. The results show that, for both atmospheres, there was an apparently linear correlation and good agreement between the AFTs of synthetic ash samples and the liquidus temperatures calculated by FactSage (R > 0.89, and {sigma} < 30{sup o}C). These models predict the AFTs of coal ash samples with a high level of accuracy (SE < 30{sup o}C). Because the iron oxides in coal ash samples fused under a H{sub 2} atmosphere are reduced to metallic iron and lead to changes of mineral species and micromorphology, the AFTs in a H{sub 2} atmosphere are always higher than those with an Ar atmosphere. 34 refs., 9 figs., 7 tabs.

Wen J. Song; Li H. Tang; Xue D. Zhu; Yong Q. Wu; Zi B. Zhu; Shuntarou Koyama [East China University of Science and Technology, Shanghai (China)

2009-04-15T23:59:59.000Z

229

Phase-field modeling of corrosion kinetics under dual-oxidants This article has been downloaded from IOPscience. Please scroll down to see the full text article.  

E-Print Network (OSTI)

Phase-field modeling of corrosion kinetics under dual-oxidants This article has been downloaded-field modeling of corrosion kinetics under dual-oxidants You-Hai Wen1 , Long-Qing Chen2 and Jeffrey A Hawk1 1 is proposed to simulate corrosion kinetics under a dual- oxidant atmosphere. It will be demonstrated

Chen, Long-Qing

230

Atmospheric Chemistry, Modeling, and Biogeochemistry of Mercury  

E-Print Network (OSTI)

activities that release mercury to the atmosphere include coal burning, industrial processes, waste incine

231

Nonthermal Dielectric-Barrier Discharge Plasma-Induced Inactivation Involves Oxidative DNA Damage and Membrane Lipid Peroxidation in Escherichia coli  

Science Journals Connector (OSTI)

...we decided to study plasmas mechanism of interaction...E. coli cells. As plasma created in normal atmospheric room air generates various...we hypothesized that plasma-induced oxidative...inactivation is an emerging area of interest (7, 25...

Suresh G. Joshi; Moogega Cooper; Adam Yost; Michelle Paff; Utku K. Ercan; Gregory Fridman; Gary Friedman; Alexander Fridman; Ari D. Brooks

2011-01-03T23:59:59.000Z

232

Atmospheric chemistry of diethyl ether and ethyl tert-butyl ether  

SciTech Connect

The mechanisms for the Cl-initiated and OH-initiated atmospheric oxidation of diethyl ether and ethyl tert-butyl ether (ETBE) have been determined. For diethyl ether the products are ethyl formate and formaldehyde and its atmospheric oxidation can be represented by C{sub 2}H{sub 5}OC{sub 2}H{sub 5} + OH + 2NO {yields} C{sub 2}H{sub 5}OC(O)H + HCHO + 2NO{sub 2} + HO{sub 2}. The mechanism for the atmospheric oxidation of ETBE is more complex, with 80% of the reaction being accounted for in terms of tert-butyl formate and formaldehyde. The remaining 20% the authors ascribe to 2-ethoxy-2-methylpropanal. The atmospheric oxidation of ETBE can be represented by ETBE + OH + 1.8NO {yields} 0.8HCOOC(CH{sub 3}){sub 3} + 0.2C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + HO{sub 2} + 0.8HCHO + 1.8NO{sub 2}. THe subsequent atmospheric chemistry of 2-ethoxy-2-methylpropanal the authors estimate to be represented by C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + OH + 3NO {yields} CO{sub 2} + H{sub 2}CO + C{sub 2}H{sub 5}OC(O)CH{sub 3} + HO{sub 2} + 3NO{sub 2}. These results are discussed in terms of the reactivity of these compounds in urban atmospheres.

Wallington, T.J.; Japar, S.M. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

233

Inhibition of Oxidation in Nuclear Graphite  

SciTech Connect

Graphite is a fundamental material of high temperature gas cooled nuclear reactors, providing both structure and neutron moderation. Its high thermal conductivity, chemical inertness, thermal heat capacity, and high thermal structural stability under normal and off normal conditions contribute to the inherent safety of these reactor designs. One of the primary safety issues for a high temperature graphite reactor core is the possibility of rapid oxidation of the carbon structure during an off normal design basis event where an oxidizing atmosphere (air ingress) can be introduced to the hot core. Although the current Generation IV high temperature reactor designs attempt to mitigate any damage caused by a postualed air ingress event, the use of graphite components that inhibit oxidation is a logical step to increase the safety of these reactors. Recent experimental studies of graphite containing between 5.5 and 7 wt% boron carbide (B4C) indicate that oxidation is dramatically reduced even at prolonged exposures at temperatures up to 900°C. The proposed addition of B4C to graphite components in the nuclear core would necessarily be enriched in B-11 isotope in order to minimize B-10 neutron absorption and graphite swelling. The enriched boron can be added to the graphite during billet fabrication. Experimental oxidation rate results and potential applications for borated graphite in nuclear reactor components will be discussed.

Phil Winston; James W. Sterbentz; William E. Windes

2013-10-01T23:59:59.000Z

234

Gamma-ray bursts and terrestrial planetary atmospheres  

E-Print Network (OSTI)

We describe results of modeling the effects of gamma-ray bursts (GRBs) within a few kiloparsecs of an Earth-like planet. A primary effect is generation of nitrogen oxide compounds which deplete ozone. Ozone depletion leads to an increase in solar UVB radiation at the surface, enhancing DNA damage, particularly in marine microorganisms such as phytoplankton. In addition, we expect increased atmospheric opacity due to buildup of nitrogen dioxide produced by the burst and enhanced precipitation of nitric acid. We review here previous work on this subject and discuss recent developments.

Thomas, B C; Thomas, Brian C.; Melott, Adrian L.

2006-01-01T23:59:59.000Z

235

Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

A Solid Oxide Fuel Cell (SOFC) is typically composed of two porous electrodes, interposed between an electrolyte made of a particular solid oxide ceramic material. The system originates from the work of Nernst...

Nigel M. Sammes; Roberto Bove; Jakub Pusz

2006-01-01T23:59:59.000Z

236

CDIAC Atmospheric Pressure Data Sets  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Pressure Atmospheric Pressure CDIAC Climate Holdings Containing Atmospheric Pressure Data Global Data Sets Data Set Name Investigators Data Type/Format Period of Record Global Historical Climatology Network (GHCN); Vs. 1 (CDIAC NDP-041) R.S. Vose et al. Surface stations; monthly mean sea-level pressure Varies by station; through 1990 Extended Edited Synoptic Cloud Reports from Ships and Land Stations Over the Globe, 1952-2009 (CDIAC NDP-026C) C.J. Hahn, S.G. Warren, and R. Eastman Six-hourly synoptic observations of sea-level pressure Land 1971-2009; Ocean 1952-2008 Global Historical Climatology Network (GHCN); Vs. 2 (Note: the above link takes you to NOAA's National Climatic Data Center website.) R.S. Vose et al. Surface stations; monthly mean sea-level pressure Varies by station; some through most recent month

237

National Atmospheric Release Advisory Center  

NLE Websites -- All DOE Office Websites (Extended Search)

NARAC TOC NARAC TOC The National Atmospheric Release Advisory Center, NARAC, provides tools and services to the Federal Government, that map the probable spread of hazardous material accidentally or intentionally released into the atmosphere. NARAC provides atmospheric plume predictions in time for an emergency manager to decide if taking protective action is necessary to protect the health and safety of people in affected areas. Located at the Lawrence Livermore National Laboratory, NARAC is a national support and resource center for planning, real-time assessment, emergency response, and detailed studies of incidents involving a wide variety of hazards, including nuclear, radiological, chemical, biological, and natural emissions. In an emergency situation (if lives are at risk), event-specific NARAC

238

CDIAC Atmospheric Moisture Data Sets  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Moisture Atmospheric Moisture CDIAC Climate Holdings Containing Atmospheric Moisture Data Global Data Sets Data Set Name Investigators Data Type/Format Period of Record Extended Edited Synoptic Cloud Reports from Ships and Land Stations Over the Globe, 1952-2009 (CDIAC NDP-026C) C.J. Hahn, S.G. Warren, and R. Eastman Six-hourly synoptic observations of dew point depression (combined with air temperature) Land 1971-2009; Ocean 1952-2008 Regional Data Sets Data Set Name Investigators Data Type/Format Period of Record Six- and Three-Hourly Meteorological Observations from 223 Former U.S.S.R. Stations (CDIAC NDP-048) V. Razuvaev et al. Surface stations; 6- and 3-hourly observations of relative humidity, vapor pressure, humidity deficit, and dew point temperature Varies by station; through 2000

239

Chemical modeling of exoplanet atmospheres  

E-Print Network (OSTI)

The past twenty years have revealed the diversity of planets that exist in the Universe. It turned out that most of exoplanets are different from the planets of our Solar System and thus, everything about them needs to be explored. Thanks to current observational technologies, we are able to determine some information about the atmospheric composition, the thermal structure and the dynamics of these exoplanets, but many questions remain still unanswered. To improve our knowledge about exoplanetary systems, more accurate observations are needed and that is why the Exoplanet Characterisation Observatory (EChO) is an essential space mission. Thanks to its large spectral coverage and high spectral resolution, EChO will provide exoplanetary spectra with an unprecedented accuracy, allowing to improve our understanding of exoplanets. In this work, we review what has been done to date concerning the chemical modeling of exoplanet atmospheres and what are the main characteristics of warm exoplanet atmospheres, which a...

Venot, Olivia

2014-01-01T23:59:59.000Z

240

atmospheric pressure | OpenEI  

Open Energy Info (EERE)

pressure pressure Dataset Summary Description (Abstract):Atmospheric Pressure (kPa)NASA Surface meteorology and Solar Energy (SSE) Release 6.0 Data Set (Nov 2007)22-year Monthly & Annual Average (July 1983 - June 2005)Parameter: Atmospheric Pressure (kPa)Internet: http://eosweb.larc.nasa.gov/sse/Note 1: SSE Methodology & Accuracy sections onlineNote 2: Lat/Lon values indicate the lower left corner of a 1x1 degree region. Negative values are south and west; positive values are north and east. Boundaries of the -90/-180 region Source U.S. National Aeronautics and Space Administration (NASA), Surface meteorology and Solar Energy (SSE) Date Released March 31st, 2009 (5 years ago) Date Updated Unknown Keywords atmospheric pressure climate NASA SWERA UNEP Data text/csv icon Download Data (csv, 46 MiB)

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics  

E-Print Network (OSTI)

. Radiant Energy. Radiative Transfer. Transport.) 10-Oct W 3 More Transfer Processes 15-Oct M 4 4 Gas. Equation of State. Hydrostatic Equilibrium.) 3-Oct W 2 2.11 First and Second Laws and Characteristics. Precipitation Processes. Radiative Transfer in a Cloudy Atmosphere. Fogs, Stratus

Russell, Lynn

242

Linked Environments for Atmospheric Discovery Linked Environments for Atmospheric  

E-Print Network (OSTI)

Unidata Program Center #12;Linked Environments for Atmospheric Discovery The Team: 9 institutions and 105 MethodologyTraditional NWP Methodology STATIC OBSERVATIONS Radar Data Mobile Mesonets Surface Observations Satellites The Process is Entirely Prescheduled and Serial; It Does NOT Respond to the Weather! The Process

243

Atmospheric Environment 40 (2006) 17431758 Impact of urban heat island on regional atmospheric pollution  

E-Print Network (OSTI)

and spatial distribution of atmospheric pollutants over the Paris region. One anticyclonic episode from Elsevier Ltd. All rights reserved. Keywords: Regional atmospheric pollution; Urban area micrometeorology are large sources of atmospheric pollutants. Their spatial distribution and their temporal evolution can

Ribes, Aurélien

244

Atmosphere-Surface Exchange Measurements  

Science Journals Connector (OSTI)

...HICKS, B.B., A SIMULATION OF THE EDDY ACCUMULATION...CLOSURES IN 2ND-ORDER MODELING, JOURNAL OF THE ATMOSPHERIC...Their advantag-es are rapid response, linear output...the measurement and modeling of surface fluxes are...the appli-cation of automated conditional sampling...

W. F. Dabberdt; D. H. Lenschow; T. W. Horst; P. R. Zimmerman; S. P. Oncley; A. C. Delany

1993-06-04T23:59:59.000Z

245

ATMOSPHERIC SCIENCES 2014-2015  

E-Print Network (OSTI)

ATMOSPHERIC SCIENCES 2014-2015 Graduate Student Handbook followed a Code of Honor, which is stated in this very simple verse: An Aggie does not lie, cheat, or steal that knowledge for the benefit of society. Our most fundamental mission is to help students at all levels, from

246

Pulsed atmospheric fluidized bed combustion  

SciTech Connect

The general specifications for a Pulsed Atmospheric Fluidized Bed Combustor Design Report (PAFBC) plant are presented. The design tasks for the PAFBC are described in the following areas: Coal/Limestone preparation and feed system; pulse combustor; fluidized bed; boiler parts; and ash handling system.

Not Available

1992-08-01T23:59:59.000Z

247

13, 90179049, 2013 Stable atmospheric  

E-Print Network (OSTI)

ACPD 13, 9017­9049, 2013 Stable atmospheric methane in the 2000s I. Pison et al. Title Page Utrecht, Utrecht University, Utrecht, the Netherlands 3 SRON Netherlands Institute for Space Research, Utrecht, the Netherlands 4 Vrije Universiteit, Department of Systems Ecology, Amsterdam, the Netherlands 5

Paris-Sud XI, Université de

248

Stress dependent oxidation of sputtered niobium and effects on superconductivity  

SciTech Connect

We report on the suppression of room temperature oxidation of DC sputtered niobium films and the effects upon the superconductive transition temperature, T{sub c}. Niobium was sputter-deposited on silicon dioxide coated 150?mm wafers and permitted to oxidize at room temperature and pressure for up to two years. Resistivity and stress measurements indicate that tensile films greater than 400?MPa resist bulk oxidation with measurements using transmission electron microscope, electron dispersive X-ray spectroscopy, x-ray photoelectric spectroscopy, and secondary ion mass spectrometry confirming this result. Although a surface oxide, Nb{sub 2}O{sub 5}, consumed the top 6–10?nm, we measure less than 1 at. % oxygen and nitrogen in the bulk of the films after the oxidation period. T{sub c} measurements using a SQUID magnetometer indicate that the tensile films maintained a T{sub c} approaching the dirty superconductive limit of 8.4?K after two years of oxidation while maintaining room temperature sheet resistance. This work demonstrates that control over niobium film stress during deposition can prevent bulk oxidation by limiting the vertical grain boundaries ability to oxidize, prolonging the superconductive properties of sputtered niobium when exposed to atmosphere.

David Henry, M., E-mail: mdhenry@sandia.gov; Wolfley, Steve; Monson, Todd; Clark, Blythe G.; Shaner, Eric; Jarecki, Robert [Sandia National Labs, MESA Fabrication Facility PO Box 5800 MS 1084, Albuquerque, New Mexico 87185-1084 (United States)

2014-02-28T23:59:59.000Z

249

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide  

E-Print Network (OSTI)

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

Kim, Sehun

250

KINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ  

E-Print Network (OSTI)

, reagent gas solubilities, mass trans- fer, stoichiometry, and reaction rate were not systematicallyKINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ for the oxidation of these compounds and their incorpo- ration into atmospheric liquid water are not fully

Schwartz, Stephen E.

251

Oxidation Resistant Graphite Studies  

SciTech Connect

The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

W. Windes; R. Smith

2014-07-01T23:59:59.000Z

252

Land and Atmospheric Science GRAD STUDENT HANDBOOK  

E-Print Network (OSTI)

1 Land and Atmospheric Science GRAD STUDENT HANDBOOK 2011-2012 WELCOME Welcome to the Graduate on the fundamentals of Earth system processes related to land and atmosphere and their coupled interactions. Students

Minnesota, University of

253

Land and Atmospheric Science GRAD STUDENT HANDBOOK  

E-Print Network (OSTI)

1 Land and Atmospheric Science GRAD STUDENT HANDBOOK 2012-2013 WELCOME Welcome to the Graduate on the fundamentals of Earth system processes related to land and atmosphere and their coupled interactions. Students

Minnesota, University of

254

Sulfuryl fluoride in the global atmosphere  

E-Print Network (OSTI)

The first calibrated high-frequency, high-precision, in situ atmospheric and archived air measurements of the fumigant sulfuryl fluoride (SO[subscript 2]F[subscript 2]) have been made as part of the Advanced Global Atmospheric ...

Muhle, J.

255

Lifetimes and time scales in atmospheric chemistry  

Science Journals Connector (OSTI)

...such as for years with extensive forest fires. Moving beyond atmospheric chemistry, extension of this approach to Earth system models could yield surprises. The coupling across different components of the chemistry-climate system, such as atmospheric...

2007-01-01T23:59:59.000Z

256

The Future of Precipitation: Global and Regional Isidoro Orlanski  

E-Print Network (OSTI)

destruction of ozone by chlorine; (1985) Farman et al: ozone hole Carbon dioxide methane Nitrous oxide CFCs

257

Surface Modification by Atmospheric Pressure Plasma for Improved Bonding  

E-Print Network (OSTI)

composites using atmospheric plasma treatment. J. Appl.of polymer surfaces: atmospheric plasma versus vacuum plasmaA. Morgan, The effect of atmospheric plasma treatment on the

Williams, Thomas Scott

2013-01-01T23:59:59.000Z

258

1997 Atmospheric Chemistry Colloquium for Emerging Senior Scientists  

SciTech Connect

DOE's Atmospheric Chemistry Program is providing partial funding for the Atmospheric Chemistry Colloquium for Emerging Senior Scientists (ACCESS) and FY 1997 Gordon Research Conference in Atmospheric Chemistry

Paul H. Wine

1998-11-23T23:59:59.000Z

259

Model Atmospheres for Low Field Neutron Stars  

E-Print Network (OSTI)

We compute model atmospheres and emergent spectra for low field (Bsolar abundance and iron atmospheres. We compare our results to high field magnetic atmospheres, available only for hydrogen. An application to apparently thermal flux from the low field millisecond pulsar PSR J0437--4715 shows that H atmospheres fit substantially better than Fe models. We comment on extension to high fields and the implication of these results for neutron star luminosities and radii.

Mohan Rajagopal; Roger Romani

1995-10-19T23:59:59.000Z

260

On the energy content of the atmosphere  

Science Journals Connector (OSTI)

Vertical profiles of the content of sensible heat, potential energy, and latent heat in the atmosphere between...

Stefan L. Hastenrath

1969-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Radar range measurements in the atmosphere.  

SciTech Connect

The earth's atmosphere affects the velocity of propagation of microwave signals. This imparts a range error to radar range measurements that assume the typical simplistic model for propagation velocity. This range error is a function of atmospheric constituents, such as water vapor, as well as the geometry of the radar data collection, notably altitude and range. Models are presented for calculating atmospheric effects on radar range measurements, and compared against more elaborate atmospheric models.

Doerry, Armin Walter

2013-02-01T23:59:59.000Z

262

Quantitative determination of atmospheric hydroperoxyl radical  

DOE Patents (OSTI)

A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.

Springston, Stephen R. (Upton, NY); Lloyd, Judith (Westbury, NY); Zheng, Jun (Stony Brook, NY)

2007-10-23T23:59:59.000Z

263

Radar Measurement of the Upper Atmosphere  

Science Journals Connector (OSTI)

...of the Upper Atmosphere James C. G...two decades large radars have...of the upper atmosphere. These radars...ionospheric plasma, all as functions...ionospheric plasma by detection...is wasted. Atmospheric radar scientists...305 m and an area of 73,000...frequency of 430 MHz. The radar...

James C. G. Walker

1979-10-12T23:59:59.000Z

264

Climate Impact of Increasing Atmospheric Carbon Dioxide  

Science Journals Connector (OSTI)

...RADIATIVE-TRANSFER DUE TO ATMOSPHERIC WATER-VAPOR - GLOBAL...giving rise to atmospheric mo-tions that...heat release by condensation as moist air...and because the atmospheric motions that...to thE1tfrof water in a leaky bucket...

J. Hansen; D. Johnson; A. Lacis; S. Lebedeff; P. Lee; D. Rind; G. Russell

1981-08-28T23:59:59.000Z

265

Instrumental Requirements for Global Atmospheric Chemistry  

Science Journals Connector (OSTI)

...SIMULTANEOUS MEASUREMENT OF ATMOSPHERIC CH2O, O3, AND NO2...AIRBORNE MEASUREMENTS OF ATMOSPHERIC OH, JOURNAL OF GEOPHYSICAL...HYDROGEN-CHLORIDE AND WATER AT ANTARCTIC STRATOSPHERIC...TOON, O.B., CONDENSATION OF HNO3 AND HCL IN...requirements for global atmospheric chemistry. | The field...

D. L. Albritton; F. C. Fehsenfeld; A. F. Tuck

1990-10-05T23:59:59.000Z

266

Space plasma influences on the Earth's atmosphere  

Science Journals Connector (OSTI)

...Lond. A (2003) Space plasma and the Earth's atmosphere 129 0.2 0.6 1.0...Lond. A (2003) Space plasma and the Earth's atmosphere 131 the size and the...satellites probing the space-plasma and atmospheric environments, they provide...

2003-01-01T23:59:59.000Z

267

Predicting Future Atmospheric Carbon Dioxide Levels  

Science Journals Connector (OSTI)

...Predicting future atmospheric carbon dioxide levels...1978012175 air atmosphere biosphere carbon...Predicting future atmospheric carbon dioxide levels...re-quired 5-Mhz bandwidth, which...synchronization rate of 16 khz and the picture...the interstellar plasma. For UHF frequencies...

U. Siegenthaler; H. Oeschger

1978-01-27T23:59:59.000Z

268

Impacts of Atmospheric Anthropogenic Nitrogen on the  

E-Print Network (OSTI)

anthropogenic carbon dioxide may result from this atmospheric nitrogen fertilization, leading to a decreaseImpacts of Atmospheric Anthropogenic Nitrogen on the Open Ocean R. A. Duce,1 * J. LaRoche,2 K quantities of atmospheric anthropogenic fixed nitrogen entering the open ocean could account for up to about

Ward, Bess

269

Ch4. Atmosphere and Surface Energy Balances  

E-Print Network (OSTI)

than red light. #12;The Electromagnetic Spectrum 8% 47% 45% 100% solar radiation #12;Blue Sky, Red;Energy Pathways #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Atmosphere or performing any work. #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Transmission

Pan, Feifei

270

Proof of the Atmospheric Greenhouse Effect  

E-Print Network (OSTI)

A recently advanced argument against the atmospheric greenhouse effect is refuted. A planet without an infrared absorbing atmosphere is mathematically constrained to have an average temperature less than or equal to the effective radiating temperature. Observed parameters for Earth prove that without infrared absorption by the atmosphere, the average temperature of Earth's surface would be at least 33 K lower than what is observed.

Smith, Arthur P

2008-01-01T23:59:59.000Z

271

ATS621, Fall 2013 Atmospheric Chemistry  

E-Print Network (OSTI)

ATS621, Fall 2013 Atmospheric Chemistry Tuesdays and Thursdays, 10 ­ 10:50, 212B ACRC) 491-8587 Teaching Assistant: Lauren Potter Atmospheric Chemistry Bldg., Room 11 Lepotter, transport, chemistry and deposition impact atmospheric chemical composition; 2) Explain the chemical

272

ATS621, Fall 2014 Atmospheric Chemistry  

E-Print Network (OSTI)

ATS621, Fall 2014 Atmospheric Chemistry Monday and Wednesday, 9 ­ 9:50, 212B ACRC Instructor: Prof) Understand quantitatively how emissions, transport, chemistry and deposition impact atmospheric chemical to Atmospheric Chemistry, D.J. Jacob Princeton University Press, 1999 PDF versions of the chapters can

Collett Jr., Jeffrey L.

273

Evaluation of Health Risks of Atmospheric Pollutants  

E-Print Network (OSTI)

4 5- (DRAFT) Evaluation of Health Risks of Atmospheric Pollutants Guy Landrieu INERIS Institut, Stuttgart : Germany (1995)" #12;INERIS: Evaluation of health risks of atmospheric pollutants (DRAFT may 1995) Evaluation of health risks of atmospheric pollutants Summary 1 Introduction 2 Background 3 Harmfulness

Paris-Sud XI, Université de

274

Light extinction in the atmosphere  

SciTech Connect

Atmospheric aerosol particles originating from natural sources, such as volcanos and sulfur-bearing gas emissions from the oceans, and from human sources, such as sulfur emissions from fossil fuel combustion and biomass burning, strongly affect visual air quality and are suspected to significantly affect radiative climate forcing of the planet. During the daytime, aerosols obscure scenic vistas, while at night they diminish our ability to observe stellar objects. Scattering of light is the main means by which aerosols attenuate and redistribute light in the atmosphere and by which aerosols can alter and reduce visibility and potentially modify the energy balance of the planet. Trends and seasonal variability of atmospheric aerosol loading, such as column-integrated light extinction or optical depth, and how they may affect potential climate change have been difficult to quantify because there have been few observations made of important aerosol optical parameters, such as optical depth, over the globe and over time and often these are of uneven quality. To address questions related to possible climate change, there is a pressing need to acquire more high-quality aerosol optical depth data. Extensive deployment of improved solar radiometers over the next few years will provide higher-quality extinction data over a wider variety of locations worldwide. An often overlooked source of turbidity data, however, is available from astronomical observations, particularly stellar photoelectric photometry observations. With the exception of the Project ASTRA articles published almost 20 years ago, few of these data ever appear in the published literature. This paper will review the current status of atmospheric extinction observations, as highlighted by the ASTRA work and augmented by more recent solar radiometry measurements.

Laulainen, N.

1992-06-01T23:59:59.000Z

275

METAL OXIDE NANOPARTICLES  

SciTech Connect

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

276

Atmospheric Sciences Program Department of Marine, Earth and Atmospheric Sciences (MEAS)  

E-Print Network (OSTI)

atmospheric chemistry/air quality, boundary layer and air pollution meteorology, regional/global climatology MODELING OF MULTIPLE AIR POLLUTANTS AT URBAN AND REGIONAL SCALES Our atmosphere is a complex systemAtmospheric Sciences Program Department of Marine, Earth and Atmospheric Sciences (MEAS) (http

Parker, Matthew D. Brown

277

Thermal oxidation of single crystal aluminum antimonide and materials having the same  

DOE Patents (OSTI)

In one embodiment, a method for forming a non-conductive crystalline oxide layer on an AlSb crystal includes heat treating an AlSb crystal in a partial vacuum atmosphere at a temperature conducive for air adsorbed molecules to desorb, surface molecule groups to decompose, and elemental Sb to evaporate from a surface of the AlSb crystal and exposing the AlSb crystal to an atmosphere comprising oxygen to form a crystalline oxide layer on the surface of the AlSb crystal. In another embodiment, a method for forming a non-conductive crystalline oxide layer on an AlSb crystal includes heat treating an AlSb crystal in a non-oxidizing atmosphere at a temperature conducive for decomposition of an amorphous oxidized surface layer and evaporation of elemental Sb from the AlSb crystal surface and forming stable oxides of Al and Sb from residual surface oxygen to form a crystalline oxide layer on the surface of the AlSb crystal.

Sherohman, John William; Yee, Jick Hong; Coombs, III, Arthur William; Wu, Kuang Jen J.

2012-12-25T23:59:59.000Z

278

Photochemical doping of graphene oxide with nitrogen for photoluminescence enhancement  

SciTech Connect

Nitrogen-doped graphene oxide (NGO) was synthesized by irradiation of graphene oxide (GO) in NH{sub 3} atmosphere. NGO obtained by irradiation of GO for 10 min has high N content of 13.62 at. %. The photoluminescence (PL) properties of NGO were investigated. The results showed that compared with GO, NGO exhibits significant PL enhancement with a high enhancement ratio of approximately 1501.57%. It may attribute to the high content of amino-like N, which can effectively enhance PL of GO because of the amino conjugation effect.

Liu, Fuchi [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China) [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); College of Physics and Technology, Guangxi Normal University, Guilin 541004 (China); Tang, Nujiang; Tang, Tao; Liu, Yuan; Feng, Qian; Zhong, Wei; Du, Youwei [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)] [Physics Department and Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China)

2013-09-16T23:59:59.000Z

279

Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions  

DOE Patents (OSTI)

A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

2008-11-25T23:59:59.000Z

280

Nickel Ferrite Aerogels with Monodisperse Nanoscale Building Blocks—The Importance of Processing Temperature and Atmosphere  

Science Journals Connector (OSTI)

Nickel Ferrite Aerogels with Monodisperse Nanoscale Building Blocks—The Importance of Processing Temperature and Atmosphere ... Using two-step (air/argon) thermal processing, sol?gel-derived nickel?iron oxide aerogels are transformed into monodisperse, networked nanocrystalline magnetic oxides of NiFe2O4 with particle diameters that can be ripened with increasing temperature under argon to 4.6, 6.4, and 8.8 nm. ... nickel ferrites; magnetic nanomaterials; nanoarchitectures; aerogels; sol?gel chemistry; single magnetic domains; thermal processing ...

Katherine A. Pettigrew; Jeffrey W. Long; Everett E. Carpenter; Colin C. Baker; Justin C. Lytle; Christopher N. Chervin; Michael S. Logan; Rhonda M. Stroud; Debra R. Rolison

2008-04-22T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

ATMOSPHERIC DENSITY ESTIMATION USING SATELLITE PRECISION ORBIT EPHEMERIDES  

E-Print Network (OSTI)

The current atmospheric density models are not capable enough to accurately model the atmospheric density, which varies continuously in the upper atmosphere mainly due to the changes in solar and geomagnetic activity. Inaccurate atmospheric modeling...

Arudra, Anoop Kumar

2011-04-22T23:59:59.000Z

282

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

1988-01-01T23:59:59.000Z

283

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Nyaiesh, A.R.; Garwin, E.L.

1986-08-04T23:59:59.000Z

284

Oxidative Degradation of Monoethanolamine  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

285

Oxygen Release and Exchange in Niobium Oxide MEHPPV Hybrid Solar Cells  

Science Journals Connector (OSTI)

Oxygen Release and Exchange in Niobium Oxide MEHPPV Hybrid Solar Cells ... This deliberate choice was made in order to distinguish the function of the transparent conducting oxide (TCO) and metal electrode as compared to traditional polymer photovoltaics where the TCO is the hole collector and the metal is the electron collector. ... The horizontal dashed black line in the graph (E) corresponds to the theoretical ratio (0.2%) for atmospheric oxygen. ...

Monica Lira-Cantu; Kion Norrman; Jens W. Andreasen; Frederik C. Krebs

2006-10-25T23:59:59.000Z

286

Phase-Transfer-Catalyzed Oxidations  

Science Journals Connector (OSTI)

Phase-transfer catalysis (PTC) offers many excellent opportunities for conducting oxidation reactions using inexpensive primary oxidants such as oxygen, sodium hypochlorite, hydrogen peroxide, electrooxidation...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

287

Atmospheric-pressure plasma jet  

SciTech Connect

A {gamma}-mode, resonant-cavity plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250 C at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two concentric cylindrical electrodes are employed to generate a plasma in the annular region there between. A jet of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly shaping the rf-powered electrode. Because of the atmospheric pressure operation, no ions survive for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike low-pressure plasma sources and conventional plasma processing methods.

Selwyn, G.S.

1999-10-05T23:59:59.000Z

288

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

289

Time dependences of atmospheric Carbon dioxide fluxes  

E-Print Network (OSTI)

Understanding the lifetime of CO2 in the atmosphere is critical for predictions regarding future climate changes. A simple mass conservation analysis presented here generates tight estimations for the atmosphere's retention time constant. The analysis uses a leaky integrator model that combines the observed deficit (only less than 40% of CO2 produced from combustion of fossil fuels is actually retained in the atmosphere, while more than 60% is continuously shed) with the exponential growth of fossil fuel burning. It reveals a maximum characteristic time of less than 23 year for the transfer of atmospheric CO2 to a segregation sink. This time constant is further constrained by the rapid disappearance of 14C after the ban of atmospheric atomic bomb tests, which provides a lower limit of 18 years for this transfer. The study also generates evaluations of other CO2 fluxes, exchange time constants and volumes exchanged. Analysis of large harmonic oscillations of atmospheric CO2 concentration, often neglected in th...

DeSalvo, Riccardo

2014-01-01T23:59:59.000Z

290

Absolute calibration of imaging atmospheric Cherenkov telescopes  

E-Print Network (OSTI)

A calibrated laser pulse propagating through the atmosphere produces a flash of Rayleigh scattered light with an intensity that can be calculated very accurately when atmospheric conditions are good. This is used in a technique developed for the absolute calibration of ultra high energy cosmic ray fluorescence telescopes, and it can also be applied to imaging atmospheric Cherenkov telescopes (IACTs). In this paper we present the absolute calibration system being constructed and tested for the VERITAS project.

N. Shepherd; J. H. Buckley; O. Celik; J. Holder; S. LeBohec; H. Manseri; F. Pizlo; M. Roberts

2005-07-04T23:59:59.000Z

291

What we can learn from atmospheric neutrinos  

E-Print Network (OSTI)

Physics potential of future measurements of atmospheric neutrinos is explored. Observation of $\\Delta m^2_{21}$ driven sub-dominant effects and $\\theta_{13}$ driven large matter effects in atmospheric neutrinos can be used to study the deviation of $\\theta_{23}$ from maximality and its octant. Neutrino mass hierarchy can be determined extremely well due to the large matter effects. New physics can be constrained both in standard atmospheric neutrino experiments as well as in future neutrino telescopes.

Sandhya Choubey

2006-09-19T23:59:59.000Z

292

Small Interannual Variability of Global Atmospheric Hydroxyl  

Science Journals Connector (OSTI)

...Nicosia 1645, Cyprus. The oxidizing capacity...air pollution and natural influences. We show...methane and other trace gases oxidized primarily...observations of additional gases oxidized primarily...from a variety of natural and anthropogenic...changes in trace-gas emissions with smoothed...

S. A. Montzka; M. Krol; E. Dlugokencky; B. Hall; P. Jöckel; J. Lelieveld

2011-01-07T23:59:59.000Z

293

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL  

E-Print Network (OSTI)

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach · Parallel planes: PSOFC · Other: combustor, reformer Solid Oxide Fuel Cell Electrochemistry Cell Reactions · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

Mease, Kenneth D.

294

NREL: Process Development and Integration Laboratory - Atmospheric  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Processing Platform Capabilities Atmospheric Processing Platform Capabilities The Atmospheric Processing platform in the Process Development and Integration Laboratory offers powerful capabilities with integrated tools for depositing, processing, and characterizing photovoltaic materials and devices. In particular, this platform focuses on different methods to deposit ("write") materials onto a variety of substrates and then further process into optoelectronic materials using rapid thermal processing. You can read more on the rationale for developing this platform and its capabilities. Contact Maikel van Hest for more details on these capabilities. The Atmospheric Processing platform will allow deposition in any sequence and is applicable to activities in all Technology Roadmaps, which include

295

Earth and Atmospheric Sciences | More Science | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Nuclear Forensics Climate & Environment Sensors and Measurements Chemical & Engineering Materials Computational Earth Science Systems Modeling Geographic Information Science and Technology Materials Science and Engineering Mathematics Physics More Science Home | Science & Discovery | More Science | Earth and Atmospheric Sciences SHARE Earth and Atmospheric Sciences At ORNL, we combine our capabilities in atmospheric science, computational science, and biological and environmental systems science to focus in the cross-disciplinary field of climate change science. We use computer models to improve climate change predications and to measure the impact of global warming on the cycling of chemicals in earth systems. Our Climate Change Science Institute uses models to explore connections among atmosphere,

296

Atmospheric Pressure Discharges: Traveling Wave Plasma Sources  

Science Journals Connector (OSTI)

Microwave sustained, atmospheric pressure plasmas are finding an increasing number of applications ... interest in the developing and investigating of appropriate plasma sources [1, 2].

Z. Zakrzewski; M. Moisan

1999-01-01T23:59:59.000Z

297

12.815 Atmospheric Radiation, Fall 2005  

E-Print Network (OSTI)

Introduction to the physics of atmospheric radiation and remote sensing including use of computer codes. Radiative transfer equation including emission and scattering, spectroscopy, Mie theory, and numerical solutions. ...

Prinn, Ronald G.

298

Mesoscale Coupled Ocean-Atmosphere Interaction  

E-Print Network (OSTI)

heat flux, and wind power input to the ocean. Geophys. Res.Powers and Stoelinga (2000). They developed a comprehensive atmosphere-ocean-

Seo, Hyodae

2007-01-01T23:59:59.000Z

299

Mesoscale coupled ocean-atmosphere interaction  

E-Print Network (OSTI)

heat flux, and wind power input to the ocean. Geophys. Res.Powers and Stoelinga (2000). They developed a comprehensive atmosphere-ocean-

Seo, Hyodae

2007-01-01T23:59:59.000Z

300

Atmosphere to Electrons Program Overview Presentation  

Energy.gov (U.S. Department of Energy (DOE))

This presentation provides an introduction to the Atmosphere to Electrons (A2e) initiative, including objectives, program areas, and a general timeline of activities.

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Tantalum etching with a nonthermal atmospheric-pressure plasma  

Science Journals Connector (OSTI)

Tantalum was etched in a downstream atmospheric-pressure plasma. In this process etching occurred without significant ion bombardment. An etching rate of 6.0±0.5 ?m/min was achieved using 14.8 Torr oxygen 22.4 Torr carbon tetrafluoride 720±5 Torr helium 685 W radio frequency power at 13.56 MHz and a film temperature of 300?°C. The etching rate increased with the applied power carbon tetrafluoride pressure oxygen pressure and residence time of the gas between the electrodes indicating that the surface reaction depends on the density of reactive fluorine species generated in the plasma.X-ray photoemission spectroscopy revealed that the etched surface was covered with tantalum fluoride and to a lesser extent tantalum oxide. Based on these observations a mechanism for tantalumetching is proposed which involves the reaction between fluorine atoms and the adsorbed tantalum fluoride.

V. J. Tu; J. Y. Jeong; A. Schütze; S. E. Babayan; G. Ding; G. S. Selwyn; R. F. Hicks

2000-01-01T23:59:59.000Z

302

Gamma-ray bursts and terrestrial planetary atmospheres  

E-Print Network (OSTI)

We describe results of modeling the effects on Earth-like planets of long-duration gamma-ray bursts (GRBs) within a few kiloparsecs. A primary effect is generation of nitrogen oxide compounds which deplete ozone. Ozone depletion leads to an increase in solar UVB radiation at the surface, enhancing DNA damage, particularly in marine microorganisms such as phytoplankton. In addition, we expect increased atmospheric opacity due to buildup of nitrogen dioxide produced by the burst and enhanced precipitation of nitric acid. We review here previous work on this subject and discuss recent developments, including further discussion of our estimates of the rates of impacting GRBs and the possible role of short-duration bursts.

Brian C. Thomas; Adrian L. Melott

2006-05-04T23:59:59.000Z

303

Syngas Oxidation Mechanism  

Science Journals Connector (OSTI)

A comprehensive analysis of synthesis gas (syngas) oxidation kinetics in wide ranges of temperature ... on the basis of the reaction mechanism of syngas ignition and combustion in air. A vast set of experimental ...

A. M. Starik; N. S. Titova; A. S. Sharipov…

2010-09-01T23:59:59.000Z

304

Catalytic production of metal carbonyls from metal oxides  

DOE Patents (OSTI)

This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

1984-01-06T23:59:59.000Z

305

Response of global soil consumption of atmospheric methane to changes in atmospheric climate and nitrogen deposition  

E-Print Network (OSTI)

Soil consumption of atmospheric methane plays an important secondary role in regulating the atmospheric CH4 budget, next to the dominant loss mechanism involving reaction with the hydroxyl radical (OH). Here we used a ...

Zhuang, Qianlai

306

Controlled CO preferential oxidation  

DOE Patents (OSTI)

Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

Meltser, M.A.; Hoch, M.M.

1997-06-10T23:59:59.000Z

307

Infrared spectroscopic studies of carbon monoxide adsorbed on a series of silica-supported copper catalysts in different oxidation states  

SciTech Connect

Infrared spectroscopy has been used to study the adsorption of carbon monoxide (358-493 K, 0.1-20 kPa) on four copper-on-silica (2-10 wt% Cu) catalysts prepared by the ion-exchange technique. The measurements are made for each sample in three different states: unreduced (predominantly Cu{sup 2+}), and reduced (Cu{sup 0}), and partially reoxidized in nitrous oxide (Cu{sup +}). On unreduced samples, a major absorption band between 2127 and 2132 cm{sup {minus}1} due to CO adsorbed on small CuO particles and a weak band at 2199 cm{sup {minus}1} due to CO on isolated Cu{sup 2+} ions incorporated in the silica surface have been identified. The former adsorption obeys a Langmuir isotherm with a heat of adsorption of 29 kJ/mol independent of CuO particle size and surface coverage. After catalyst reduction, the major absorption band lies between 2090 and 2113 cm{sup {minus}1} and arises from CO linearly bound to very small (1- to 5-nm) copper metal clusters. The observed frequency shifts indicate the presence of steps and terraces similar to low index Cu planes in very small particles (1- to 2-nm), and the presence of similar higher index Cu planes on larger clusters (2- to 5-nm). The absorption is described by a Freundlich isotherm with the heat of CO adsorption decreasing with coverage from 50 to 22 kJ/mol on bigger particles but more constant (27 to 22 kJ/mol) on small particles. A surface copper/CO atomic ratio increasing from 5 to 12 is established at equilibrium saturation between 358 and 493 K using extinction coefficients determined in this study. In the reduced catalysts, a weakly adsorbed ({Delta}H{sub a} = {minus}20 kJ/mol) species assigned to CO bound to isolated Cu{sup +} ions is also found and absorbs at 2175 cm{sup {minus}1}. The frequency of this band does not vary with catalyst loading and is not affected by reoxidation of the catalyst in nitrous oxide.

Kohler, M.A.; Wainwright, M.S.; Trimm, D.L.; Cant, N.W. (Macquarie Univ., New South Wales (Australia) Univ. of South Wales (Australia))

1989-05-01T23:59:59.000Z

308

Surface modification of polymeric materials by cold atmospheric plasma jet  

Science Journals Connector (OSTI)

Abstract In this work we report the surface modification of different engineering polymers, such as, polyethylene terephthalate (PET), polyethylene (PE) and polypropylene (PP) by an atmospheric pressure plasma jet (APPJ). It was operated with Ar gas using 10 kV, 37 kHz, sine wave as an excitation source. The aim of this study is to determine the optimal treatment conditions and also to compare the polymer surface modification induced by plasma jet with the one obtained by another atmospheric pressure plasma source – the dielectric barrier discharge (DBD). The samples were exposed to the plasma jet effluent using a scanning procedure, which allowed achieving a uniform surface modification. The wettability assessments of all polymers reveal that the treatment leads to reduction of more than 40° in the water contact angle (WCA). Changes in surface composition and chemical bonding were analyzed by x-ray photoelectron spectroscopy (XPS) and Fourier-Transformed Infrared spectroscopy (FTIR) that both detected incorporation of oxygen-related functional groups. Surface morphology of polymer samples was investigated by Atomic Force Microscopy (AFM) and an increase of polymer roughness after the APPJ treatment was found. The plasma-treated polymers exhibited hydrophobic recovery expressed in reduction of the O-content of the surface upon rinsing with water. This process was caused by the dissolution of low molecular weight oxidized materials (LMWOMs) formed on the surface as a result of the plasma exposure.

K.G. Kostov; T.M.C. Nishime; A.H.R. Castro; A. Toth; L.R.O. Hein

2014-01-01T23:59:59.000Z

309

The global change research center atmospheric chemistry model  

SciTech Connect

This work outlines the development of a new model of the chemistry of the natural atmosphere. The model is 2.5-dimensional, having spatial coordinates height, latitude, and, the half-dimension, land and ocean. The model spans both the troposphere and stratosphere, although the troposphere is emphasized and the stratosphere is simple and incomplete. The chemistry in the model includes the O{sub x}, HO{sub x}, NO{sub x}, and methane cycles in a highly modular fashion which allows model users great flexibility in selecting simulation parameters. A detailed modeled sensitivity analysis is also presented. A key aspect of the model is its inclusion of clouds. The model uses current understanding of the distribution and optical thickness of clouds to determine the true radiation distribution in the atmosphere. As a result, detailed studies of the radiative effects of clouds on the distribution of both oxidant concentrations and trace gas removal are possible. This work presents a beginning of this study with model results and discussion of cloud effects on the hydroxyl radical.

Moraes, F.P. Jr.

1995-01-01T23:59:59.000Z

310

Response of global soil consumption of atmospheric methane to changes in atmospheric climate and nitrogen deposition  

E-Print Network (OSTI)

Response of global soil consumption of atmospheric methane to changes in atmospheric climate June 2013. [1] Soil consumption of atmospheric methane plays an important secondary role in regulating). Here we used a process-based biogeochemistry model to quantify soil consumption during the 20th and 21

311

Atmospheric Science The Earth's atmosphere, a layered sphere of gas extending  

E-Print Network (OSTI)

division study the composition, structure, chemical, and physical processes of the Earth's atmosphere. The division's four interrelated groups focus on satellite, airborne, and ground-based observations processes such as atmospheric dynamics, chemistry, and radiation on Earth and other planets. Our atmospheric

Mojzsis, Stephen J.

312

Modeling of Diesel Oxidation Catalyst  

Science Journals Connector (OSTI)

Modeling of Diesel Oxidation Catalyst ... Optimization of hydrocarbon (HC) oxidation over a diesel oxidation catalyst (DOC) requires consideration of (i) HC gas diffusion into the catalyst layer, (ii) HC gas adsorption and desorption from catalyst sites, and (iii) kinetics of the oxidation reaction. ... Mutagenicity of Diesel Engine Exhaust Is Eliminated in the Gas Phase by an Oxidation Catalyst but Only Slightly Reduced in the Particle Phase ...

Yasushi Tanaka; Takashi Hihara; Makoto Nagata; Naoto Azuma; Akifumi Ueno

2005-09-30T23:59:59.000Z

313

Performance Engineering in the Community Atmosphere Model  

SciTech Connect

The Community Atmosphere Model (CAM) is the atmospheric component of the Community Climate System Model (CCSM) and is the primary consumer of computer resources in typical CCSM simulations. Performance engineering has been an important aspect of CAM development throughout its existence. This paper briefly summarizes these efforts and their impacts over the past five years.

Worley, P; Mirin, A; Drake, J; Sawyer, W

2006-05-30T23:59:59.000Z

314

Radio Frequency Signals in Jupiter's Atmosphere  

Science Journals Connector (OSTI)

...IMAGE OF A LARGE UPWARD ELECTRICAL-DISCHARGE...RINNERT K , HDB ATMOSPHERIC ELEC 27 ( 1995...MEASUREMENTS OF THE RF CHARACTERISTICS...JUPITER PLASMA-WAVE OBSERVATIONS...OBSERVATIONS OF UPPER ATMOSPHERIC OPTICAL FLASHES...Solar and thermal radiation...relatively large at the beginning...and about non-radiative...sensitive area of 6...

L. J. Lanzerotti; K. Rinnert; G. Dehmel; F. O. Gliem; E. P. Krider; M. A. Uman; J. Bach

1996-05-10T23:59:59.000Z

315

Predicting Future Atmospheric Carbon Dioxide Levels  

Science Journals Connector (OSTI)

...re-quired 5-Mhz bandwidth...interstellar plasma. For UHF frequencies of 500 Mhz, this amounts...chang-ing the atmospheric carbon dioxide...in the polar areas. Although...The shaded area indicates the...per-missible atmospheric CO2 level might...emission rates are largest between 2000...

U. Siegenthaler; H. Oeschger

1978-01-27T23:59:59.000Z

316

Some challenges of middle atmosphere data assimilation  

E-Print Network (OSTI)

Some challenges of middle atmosphere data assimilation 1234567 89A64BC7DEF72B4 8629EEC7C72DEEE5.1256/qj.05.87 Some challenges of middle atmosphere data assimilation By S. POLAVARAPU1,2, T. G. SHEPHERD2 Data assimilation is employed at operational weather forecast centres to combine measurements and model

Wirosoetisno, Djoko

317

Atmospheric muon background in the ANTARES detector  

E-Print Network (OSTI)

An evaluation of the background due to atmospheric muons in the ANTARES high energy neutrino telescope is presented. Two different codes for atmospheric shower simulation have been used. Results from comparisons between these codes at sea level and detector level are presented. The first results on the capability of ANTARES to reject this class of background are given.

S. Cecchini; E. Korolkova; A. Margiotta; L. Thompson

2005-10-28T23:59:59.000Z

318

The Radon Content of the Atmosphere  

Science Journals Connector (OSTI)

... MEASUREMENTS of the radon content of the atmosphere were made so long ago as 1905 by Eve1-2 in ... whole seemed to support the original suggestion of Elster and Geitel6 in 1903 that the radon in the atmosphere arises mainly from the soil. These workers noted that the highest ...

W. ANDERSON; W. V. MAYNEORD; R. C. TURNER

1954-09-04T23:59:59.000Z

319

United States Department Atmospheric and Biospheric Interactions  

E-Print Network (OSTI)

United States Department Atmospheric and Biospheric Interactions of Agriculture Forest Service coordinator. 1997. Atmospheric and biospheric interactions of gases and energy in the Pacific region century have caused a dramatic increase in global air pollution. This process has accelerated in the past

Standiford, Richard B.

320

Extremes and Atmospheric Data Eric Gilleland  

E-Print Network (OSTI)

Extremes and Atmospheric Data Eric Gilleland Research Applications Laboratory National Center for Atmospheric Research 2007-08 Program on Risk Analysis, Extreme Events and Decision Theory, opening workshop 16-19 September, North Carolina #12;Extremes · Interest in making inferences about large, rare, extreme phenomena

Gilleland, Eric

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

An experimental and detailed chemical kinetic modelling study of 2methyl furan oxidation  

E-Print Network (OSTI)

platform chemical 5hydroxymethylfurfural now a possibility [4], [5], [6] and [7]. 25DMF offers significantAn experimental and detailed chemical kinetic modelling study of 2methyl furan oxidation.55­1.65, initial temperatures of 298­398 K and atmospheric pressure. A detailed chemical kinetic mechanism

Paris-Sud XI, Université de

322

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux and  

E-Print Network (OSTI)

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux significant sink that regulates methane flux from sediments into the oceans and atmosphere. Here we examine mesophilic to thermophilic AOM in hydro- thermal sediments recovered from the Middle Valley vent field

Girguis, Peter R.

323

Methane oxidation by an extremely acidophilic bacterium of the phylum Verrucomicrobia  

Science Journals Connector (OSTI)

... primarily through the microbial degradation of organic matter, but abiogenic methane emitted from seeps and geothermal areas is also a major contribution to the atmospheric budget, estimated at 45–75? ... at 45–75?Tg annually. Hell’s Gate (Tikitere), New Zealand, is a geothermal area rich in abiogenic methane. We studied methane oxidation in an area of woody ...

Peter F. Dunfield; Anton Yuryev; Pavel Senin; Angela V. Smirnova; Matthew B. Stott; Shaobin Hou; Binh Ly; Jimmy H. Saw; Zhemin Zhou; Yan Ren; Jianmei Wang; Bruce W. Mountain; Michelle A. Crowe; Tina M. Weatherby; Paul L. E. Bodelier; Werner Liesack; Lu Feng; Lei Wang; Maqsudul Alam

2007-11-14T23:59:59.000Z

324

A SEARCH FOR MAGNESIUM IN EUROPA'S ATMOSPHERE  

SciTech Connect

Europa's tenuous atmosphere results from sputtering of the surface. The trace element composition of its atmosphere is therefore related to the composition of Europa's surface. Magnesium salts are often invoked to explain Galileo Near Infrared Mapping Spectrometer spectra of Europa's surface, thus magnesium may be present in Europa's atmosphere. We have searched for magnesium emission in the Hubble Space Telescope Faint Object Spectrograph archival spectra of Europa's atmosphere. Magnesium was not detected and we calculate an upper limit on the magnesium column abundance. This upper limit indicates that either Europa's surface is depleted in magnesium relative to sodium and potassium, or magnesium is not sputtered as efficiently resulting in a relative depletion in its atmosphere.

Hoerst, S. M. [Cooperative Institute for Research in Environmental Sciences, University of Colorado-Boulder, Boulder, CO (United States); Brown, M. E., E-mail: sarah.horst@colorado.edu [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA (United States)

2013-02-20T23:59:59.000Z

325

Atmospheric Chemistry of Ethyl Propionate  

Science Journals Connector (OSTI)

Atomic chlorine was produced by photolysis of Cl gas (reaction 9) with UV-A light, and OH was generated by photolysis of ozone with UV-C light followed by reaction with water vapor (reactions 10 and 11). ... (9)(10)(11)O3 was generated from O2 with an ozone generator from O3 Technology (model AC-20), and condensed on silica gel that was cooled with ethanol and dry ice to approximately ?70 °C. ... However, we show here a new surface-mediated coupling of nitrogen oxide and halogen activation cycles in which uptake of gaseous NO(2) or N(2)O(5) on solid substrates generates adsorbed intermediates that react with HCl to generate gaseous nitrosyl chloride (ClNO) and nitryl chloride (ClNO(2)), respectively. ...

Vibeke F. Andersen; Kristian B. Ørnsø; Solvejg Jørgensen; Ole John Nielsen; Matthew S. Johnson

2012-04-23T23:59:59.000Z

326

THE EARTH SYSTEM SCIENCE It is the science that studies the whole  

E-Print Network (OSTI)

by coal, continuing deforestation, and limited or no control of methane, nitrous oxide, and carbon of the twenty-first century, a phaseout of CFC emissions, and limitations on agricultural methane and nitrous

Gilbes, Fernando

327

Thermally Oxidized Silicon  

NLE Websites -- All DOE Office Websites (Extended Search)

Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Illustration of the silicon positions near the Si-SiO2 interface for a 4° miscut projected onto the ( ) plane. The silicon atoms in the substrate are blue and those in the oxide are red. The small black spots represent the translated silicon positions in the absence of static disorder. The silicon atoms in the oxide have been randomly assigned a magnitude and direction based on the static disorder value at that position in the lattice. The outline of four silicon unit cells is shown in black, whereas the outline of four expanded lattice cells in the oxide is shown in blue One of the most studied devices of modern technology is the field-effect transistor, which is the basis for most integrated circuits. At its heart

328

Oxidative Tritium Decontamination System  

SciTech Connect

The Princeton Plasma Physics Laboratory, Tritium Systems Group has developed and fabricated an Oxidative Tritium Decontamination System (OTDS), which is designed to reduce tritium surface contamination on various components and items. The system is configured to introduce gaseous ozone into a reaction chamber containing tritiated items that require a reduction in tritium surface contamination. Tritium surface contamination (on components and items in the reaction chamber) is removed by chemically reacting elemental tritium to tritium oxide via oxidation, while purging the reaction chamber effluent to a gas holding tank or negative pressure HVAC system. Implementing specific concentrations of ozone along with catalytic parameters, the system is able to significantly reduce surface tritium contamination on an assortment of expendable and non-expendable items. This paper will present the results of various experimentation involving employment of this system.

Charles A. Gentile; John J. Parker; Gregory L. Guttadora; Lloyd P. Ciebiera

2002-02-11T23:59:59.000Z

329

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

330

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

331

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

332

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

333

Electrical conductivity of plasmas of DB white dwarf atmospheres  

Science Journals Connector (OSTI)

......Electrical conductivity of plasmas of DB white dwarf atmospheres V. A. Sreckovic 1 Lj...applicable for the helium plasmas of DB white dwarf atmospheres described in Koester...study of DB white dwarf atmosphere plasma properties, helium plasmas......

V. A. Sreckovic; Lj. M. Ignjatovic; A. A. Mihajlov; M. S. Dimitrijevic

2010-07-21T23:59:59.000Z

334

Atomic Force and Scanning Electron Microscopy of Atmospheric Particles  

E-Print Network (OSTI)

conducted so as to characterize atmospheric aerosols from anthropogenic (pollution) and natural (sea saltAtomic Force and Scanning Electron Microscopy of Atmospheric Particles ZAHAVA BARKAY,1 * AMIT 69978, Israel KEY WORDS atmospheric aerosols; atomic force microscopy; scanning electron microscopy

Shapira, Yoram

335

Adjoint modeling for atmospheric pollution process sensitivity at regional scale  

E-Print Network (OSTI)

Adjoint modeling for atmospheric pollution process sensitivity at regional scale Laurent Menut; 0345 Atmospheric Composition and Structure: Pollution--urban and regional (0305); 3210 Mathematical: atmospheric pollution, tropospheric ozone, urban pollution peaks, adjoint modeling, sensitivity Citation

Menut, Laurent

336

Tetraalklylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

1998-10-06T23:59:59.000Z

337

Tetraalykylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

1998-01-01T23:59:59.000Z

338

Method for production of ceramic oxide and carbide bodies by polymer inclusion and decomposition  

DOE Patents (OSTI)

A method for the preparation of thin, free-standing metal oxide films which are useful as nuclear accelerator target materials. Cations of any metal except those of Group IA and precious metals, such as, U, Zr, Nd, Ce, Th, pr or Cr, are absorbed on a thin film of polymeric material, such as, carboxymethylcellulose, viscose rayon or cellophane. The cation impregnated polymeric material is dried. Then the impregnated film is heated in an inert atmosphere to form a carbonized membrane. The carbonized membrane is oxidized to yield a thin, self-supporting, metal oxide membrane. Or, the membrane can be heated in an inert atmosphere to yield a thin, self-supporting, metal carbide-containing membrane.

Quinby, Thomas C. (Kingston, TN)

1985-01-01T23:59:59.000Z

339

Radon in atmospheric studies: a review  

SciTech Connect

The distribution of the isotopes of radon in space and time, their physical characteristics, and their behavior in the dynamics of the atmosphere have presented challenges for many decades. /sup 220/Rn, /sup 222/Rn and their daughters furnish a unique set of tracers for the study of transport and mixing processes in the atmosphere. Appropriate applications of turbulent diffusion theory yield general agreement with measured profiles. Diurnal and seasonal variations follow patterns set by consideration of atmospheric stability. /sup 222/Rn has been used successfully in recent studies of nocturnal drainage winds and cumulus convection. Good results have been obtained using /sup 222/Rn and its long-lived /sup 210/Pb daughter as tracers in the study of continent-to-ocean and ocean-to-continent air mass trajectories, /sup 220/Rn (thoron) because of its short half-life of only 55 seconds has been used to measure turbulent diffusion within the first few meters of the earth's surface and to study the influence of meteorological variables on the rate of exhalation from the ground. Radon daughters attach readily to atmospheric particulate matter which makes it possible to study these aerosols with respect to size spectra, attachment characteristics, removal by gravitation and precipitation, and residence times in the troposphere. The importance of ionization by radon and its daughters in the lower atmosphere and its effect on atmospheric electrical parameters is well known. Knowledge of the mobility and other characteristics of radon daughter ions has led to applications in the study of atmospheric electrical environments under fair weather and thunderstorm conditions and in the formation of condensation nuclei. The availability of increasingly sophisticated analytical tools and atmospheric measurement systems can be expected to add much to our understanding of radon and its daughters as trace components of the atmospheric environment in the years ahead.

Wilkening, M.

1981-01-01T23:59:59.000Z

340

Atmospheric Mercury Model Intercomparisons Presentation at  

E-Print Network (OSTI)

...NERI G. Petersen, R. Ebinghaus .................. Germany...GKSS J. Pacyna and Oxidants Model, GKSS Research Center, GermanyADOM MSC-E heavy metal regional model, EMEP MSC

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst  

NLE Websites -- All DOE Office Websites (Extended Search)

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst Authors: Sherman, B. D., Pillai, S., Kodis, G., Bergkamp, J., Mallouk, T. E., Gust, D., Moore, T. A., and Moore, A. L....

342

Downhole steam generator having a downhole oxidant compressor  

DOE Patents (OSTI)

Apparatus and method for generation of steam in a borehole for penetration into an earth formation wherein a downhole oxidant compressor is used to compress relatively low pressure (atmospheric) oxidant, such as air, to a relatively high pressure prior to mixing with fuel for combustion. The multi-stage compressor receives motive power through a shaft driven by a gas turbine powered by the hot expanding combustion gases. The main flow of compressed oxidant passes through a velocity increasing nozzle formed by a reduced central section of the compressor housing. An oxidant bypass feedpipe leading to peripheral oxidant injection nozzles of the combustion chamber are also provided. The downhole compressor allows effective steam generation in deep wells without need for high pressure surface compressors. Feedback preheater means are provided for preheating fuel in a preheat chamber. Preheating of the water occurs in both a water feed line running from aboveground and in a countercurrent water flow channel surrounding the combustor assembly. The countercurrent water flow channels advantageously serve to cool the combustion chamber wall. The water is injected through slotted inlets along the combustion chamber wall to provide an unstable boundary layer and stripping of the water from the wall for efficient steam generation. Pressure responsive doors are provided at the steam outlet for closing and sealing the combustion chamber from entry of reservoir fluids in the event of a flameout.

Fox, Ronald L. (Albuquerque, NM)

1983-01-01T23:59:59.000Z

343

Nitric-phosphoric acid oxidation of organic waste materials  

SciTech Connect

A wet chemical oxidation technology has been developed to address issues facing defense-related facilities, private industry, and small-volume generators such as university and medical laboratories. Initially tested to destroy and decontaminate a heterogenous mixture of radioactive-contaminated solid waste, the technology can also remediate other hazardous waste forms. The process, unique to Savannah River, offers a valuable alternative to incineration and other high-temperature or high-pressure oxidation processes. The process uses nitric acid in phosphoric acid; phosphoric acid allows nitric acid to be retained in solution well above its normal boiling point. The reaction converts organics to carbon dioxide and water, and generates NO{sub x} vapors which can be recycled using air and water. Oxidation is complete in one to three hours. In previous studies, many organic compounds were completely oxidized, within experimental error, at atmospheric pressure below 180{degrees}C; more stable compounds were decomposed at 200{degrees}C and 170 kPa. Recent studies have evaluated processing parameters and potential throughputs for three primary compounds: EDTA, polyethylene, and cellulose. The study of polyvinylchloride oxidation is incomplete at this time.

Pierce, R.A.; Smith, J.R.

1995-11-01T23:59:59.000Z

344

MOISTURE AND SURFACE AREA MEASUREMENTS OF PLUTONIUM-BEARING OXIDES  

SciTech Connect

To ensure safe storage, plutonium-bearing oxides are stabilized at 950 C for at least two hours in an oxidizing atmosphere. Stabilization conditions are expected to decompose organic impurities, convert metals to oxides, and result in moisture content below 0.5 wt%. During stabilization, the specific surface area is reduced, which minimizes readsorption of water onto the oxide surface. Plutonium oxides stabilized according to these criteria were sampled and analyzed to determine moisture content and surface area. In addition, samples were leached in water to identify water-soluble chloride impurity content. Results of these analyses for seven samples showed that the stabilization process produced low moisture materials (< 0.2 wt %) with low surface area ({le} 1 m{sup 2}/g). For relatively pure materials, the amount of water per unit surface area corresponded to 1.5 to 3.5 molecular layers of water. For materials with chloride content > 360 ppm, the calculated amount of water per unit surface area increased with chloride content, indicating hydration of hygroscopic salts present in the impure PuO{sub 2}-containing materials. The low moisture, low surface area materials in this study did not generate detectable hydrogen during storage of four or more years.

Crowder, M.; Duffey, J.; Livingston, R.; Scogin, J.; Kessinger, G.; Almond, P.

2009-09-28T23:59:59.000Z

345

Visualizing Storms from NCAR's Atmosphere Model at NERSC  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmosphere Model Visualizing Storms from NCAR's Atmosphere Model CCSM-sprabhat.png Global warming will likely change the statistics of tropical cyclones and hurricanes. In this...

346

Comparative Analysis of Urban Atmospheric Aerosol by Particle...  

NLE Websites -- All DOE Office Websites (Extended Search)

Analysis of Urban Atmospheric Aerosol by Particle-Induced X-ray Emission (PIXE), Proton Elastic Scattering Analysis Comparative Analysis of Urban Atmospheric Aerosol by...

347

Intense and Highly Energetic Atmospheric Pressure Plasma Jet Arrays.  

E-Print Network (OSTI)

??This thesis documents the efforts taken to produce highly ionized and concentrated atmospheric pressure plasma using an arrayed atmospheric pressure plasma jet (APPJ) system. The… (more)

Furmanski, John

2012-01-01T23:59:59.000Z

348

Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951...  

Office of Environmental Management (EM)

Atmospheric Nuclear Weapons Testing, 1951-1963. Battlefield of the Cold War: The Nevada Test Site, Volume I Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951-1963....

349

An Infrared Spectral Library for Atmospheric Environmental Monitoring...  

NLE Websites -- All DOE Office Websites (Extended Search)

Library for Atmospheric Environmental Monitoring. An Infrared Spectral Library for Atmospheric Environmental Monitoring. Abstract: Infrared (IR) spectroscopy is one of several...

350

MEMORANDUM OF UNDERSTANDING THE NATIONAL OCEANIC AND ATMOSPHERIC ADMINISTRATION OF  

E-Print Network (OSTI)

national economies; Recognizing that significant interrelated, atmospheric, oceanic and terrestrial global, terrestrial and atmospheric ecosystem studies should focus on the structure and processes of the environment

351

Oxygen detected in atmosphere of Saturn's moon Dione  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

352

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide  

E-Print Network (OSTI)

as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel for use in solid oxide fuel cells. This cutting edge area of research continues to be important as energy prove useful for solid oxide fuel cells. METHODS Commercial molybdenum dioxide was used for all tests

Collins, Gary S.

353

Apparatus for solubilizing and oxidizing of peat  

SciTech Connect

Methane is produced from peat by solubilizing the phenolic polymers therein, and oxidizing the solute to produce short chain molecules. The short chain molecules are fermented to produce a gas that this scrubbed to remove CO/sub 2/ to produce methane. Solubilizing takes place in a vertically oriented pressurized vessel that is circular in cross-section and divided into a number of regular vertically elongated compartments, each comprising a circular sector in cross-section, and extending the majority the height of the vessel. Slurried peat is fed into the top of one compartment while another compartment is being emptied from the bottom, the compartment being filled or emptied being progressively changed in response to rotation of a central shaft in the vessel. Oxidation of solubilized peat takes place in a structure that transports the solubilized peat in a substantially vertical wave path from an inlet to an outlet with oxygen being introduced at the bottoms of segments of the wave path, and co2 being withdrawn from the tops of segments of the wave path while the solubilized peat is maintained at a pressure above atmospheric. Coolant is circulated around the wave path to remove the exothermic heat of reaction, and the coolant is flashed into steam used elsewhere in the process.

Elmore, C.L.; Funk, E.D.; Poulin, T.M.

1982-12-28T23:59:59.000Z

354

Fluxes of methane between landfills and the atmosphere: Natural and engineered controls  

SciTech Connect

Field measurement of landfill methane emissions indicates natural variability spanning more than 2 seven orders of magnitude, from approximately 0.0004 to more than 4000 g m{sub -2} day{sup -1}. This wide range reflects net emissions resulting from production (methanogenesis), consumption (methanotrophic oxidation), and gaseous transport processes. The determination of an {open_quotes}average{close_quotes} emission rate for a given field site requires sampling designs and statistical techniques which consider spatial and temporal variability. Moreover, particularly at sites with pumped gas recovery systems, it is possible for methanotrophic microorganisms in aerated cover soils to oxidize all of the methane from landfill sources below and, additionally, to oxidize methane diffusing into cover soils from atmospheric sources above. In such cases, a reversed soil gas concentration gradient is observed in shallow cover soils, indicating bidirectional diffusional transport to the depth of optimum methane oxidation. Rates of landfill methane oxidation from field and laboratory incubation studies range up to 166 g m{sup -2} day{sup -1} among the highest for any natural setting, providing an effective natural control on net emissions. Estimates of worldwide landfill methane emissions to the atmosphere have ranged from 9 to 70 Tg yr{sup -1}, differing mainly in assumed methane yields from estimated quantities of landfilled refuse. At highly controlled landfill sites in developed countries, landfill methane is often collected via vertical wells or horizontal collectors. Recovery of landfill methane through engineered systems can provide both environmental and energy benefits by mitigating subsurface migration, reducing surface emissions, and providing an alternative energy resource for industrial boiler use, on-site electrical generation, or upgrading to a substitute natural gas.

Bogner, J. [Argonne National Lab., IL (United States); Meadows, M. [ETSU, Harwell, Oxfordshire (United Kingdom); Czepiel, P. [Harvard Univ., Cambridge, MA (United States)

1997-08-01T23:59:59.000Z

355

Staged membrane oxidation reactor system  

DOE Patents (OSTI)

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2012-09-11T23:59:59.000Z

356

Staged membrane oxidation reactor system  

DOE Patents (OSTI)

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2014-05-20T23:59:59.000Z

357

Staged membrane oxidation reactor system  

DOE Patents (OSTI)

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2013-04-16T23:59:59.000Z

358

Shortwave Transport in the Cloudy Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

Shortwave Transport in the Cloudy Atmosphere Shortwave Transport in the Cloudy Atmosphere by Anomalous/Lévy Diffusion: New Diagnostics Using FORTÉ Lightning Data A. B. Davis Los Alamos National Laboratory Space & Remote Sensing Sciences Group Los Alamos, New Mexico D. M. Suszcynsky Los Alamos National Laboratory Space & Atmospheric Sciences Group Los Alamos, New Mexico A. Marshak National Aeronautics and Space Administration Goddard Space Flight Center Greenbelt, Maryland Introduction Anomalous photon diffusion can be described as an ad hoc modification of the popular 2-stream approximation, specifically the δ-Eddington/diffusion version, for monochromatic radiative transfer in a scattering plane-parallel atmosphere. In the physical picture that describes the standard diffusion (hence

359

Airborne Particles in Outdoor Air: Atmospheric Dust  

Science Journals Connector (OSTI)

For industrial products, in addition to the harmful effect like usual particles, the particular harmful effect of atmospheric dust especially metal particles is very large. For example, the light metal element...

Zhonglin Xu

2014-01-01T23:59:59.000Z

360

The Mars Atmospheric Constellation Observatory (MACO) Concept  

Science Journals Connector (OSTI)

The Mars Atmospheric Constellation Observatory (MACO) represents an innovative approach...2, and dust cycles together with the energy and momentum budgets. The mission concept is based on a constellation of satel...

E. R. Kursinski; W. Folkner; C. Zuffada…

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Uraninite and Fullerene in Atmospheric Particulates  

E-Print Network (OSTI)

incineration, uranium mining, and atmospheric testing of nuclearweapons-burning power plants typically contain very small amounts of uranium ( concentrations, the form of the uranium has been unknown. Using a variety of advanced electron microscopy

Utsunomiya, Satoshi

362

Atmospheric Plasma Effect on Cotton Nonwovens  

Science Journals Connector (OSTI)

Atmospheric Plasma Effect on Cotton Nonwovens ... (22) Plasma II is more effective than Plasma I with the ability to develop homogeneous plasmas and eliminate boundary-layer air effects. ...

Sudheer Jinka; Uday Turaga; Vinitkumar Singh; Rachel L. Behrens; Cenk Gumeci; Carol Korzeniewski; Todd Anderson; Rory Wolf; Seshadri Ramkumar

2014-07-22T23:59:59.000Z

363

Adaptive control for Mars atmospheric flight  

E-Print Network (OSTI)

landing accuracy requirements for a manned space vehicle make it necessary to ?y a controlled entry trajectory rather than a more robust ballistic entry trajectory used for some robotic missions. The large variations in Mars atmospheric properties make a...

Restrepo, Carolina Isabel

2009-05-15T23:59:59.000Z

364

Effects of Atmospheric Turbulence on Ballistic Testing  

Science Journals Connector (OSTI)

The effects of atmospheric turbulence on munition target scatter are determined from numerical simulations of ballistic trajectories through many realizations of realistic simulated turbulent wind fields. A technique is evaluated for correcting ...

Rod Frehlich; Robert Sharman; Charles Clough; Michael Padovani; Kelly Fling; Ward Boughers; W. Scott Walton

2008-05-01T23:59:59.000Z

365

Reducing the atmospheric impact of wet slaking  

SciTech Connect

Means of reducing the atmospheric emissions due to the wet slaking of coke are considered. One option, investigated here, is to remove residual active silt and organic compounds from the biologically purified wastewater sent for slaking, by coagulation and flocculation.

B.D. Zubitskii; G.V. Ushakov; B.G. Tryasunov; A.G.Ushakov [Kuznetsk Basin State Technical University, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

366

HYPERsensarium : an archive of atmospheric conditions  

E-Print Network (OSTI)

HYPERsensarium proposes a tangible interface of atmospheres for public experience through an archive of historical and projected weathers. While architecture's purpose has long been to act as the technical boundary between ...

Shaw, Kelly E. (Kelly Evelyn)

2013-01-01T23:59:59.000Z

367

Balanced Atmospheric Response to Squall Lines  

Science Journals Connector (OSTI)

When a Squall line propagates through the atmosphere, it not only excite transient gravity–inertia wave motion but also produces more permanent modifications to the large-scale balanced flow. Here we calculate this balanced response using the is ...

Wayne H. Schubert; Scott R. Fulton; Rolf F. A. Herttenstein

1989-08-01T23:59:59.000Z

368

Azores Global Atmosphere Monitoring Complex 1. INTRODUCTION  

E-Print Network (OSTI)

to the accuracy of European weather forecasts. Today, they provide a unique base for studies of atmospheric levels. Measurements in the free troposphere (FT) are particularly useful, because trace gas and particle

Honrath, Richard E.

369

Synopsis of Atmospheric Research under MAGS  

Science Journals Connector (OSTI)

Cold regions present a challenge to atmospheric and hydrologic research. Their low temperatures test the endurance of field workers and their instruments; their distance from large urban centers raises the cos...

Ming-ko Woo

2008-01-01T23:59:59.000Z

370

Atmospheric State, Cloud Microphysics and Radiative Flux  

DOE Data Explorer (OSTI)

Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

Mace, Gerald

371

Air Activation Following an Atmospheric Explosion  

SciTech Connect

In addition to thermal radiation and fission products, nuclear explosions result in a very high flux of unfissioned neutrons. Within an atmospheric nuclear explosion, these neutrons can activate the various elemental components of natural air, potentially adding to the radioactive signature of the event as a whole. The goal of this work is to make an order-of-magnitude estimate of the total amount of air activation products that can result from an atmospheric nuclear explosion.

Lowrey, Justin D.; McIntyre, Justin I.; Prichard, Andrew W.; Gesh, Christopher J.

2013-03-13T23:59:59.000Z

372

Trace analysis of atmospheric organic bases  

E-Print Network (OSTI)

analysis of atmospheric organic bases were investigated; the study included (1) the analysis of submarine charcoal filter bed samples for nitrogen bases and (2) the use of metallic tetraphenylporphines (TPP) as specific adsorbents for atmospheric... gas chromatography (GC) and GC-mass spectrometry (GC-MS). The isolation procedure provided acceptable reproducibi lity in the determination of trace amounts of nitrogen bases in the submarine environment. Several metallic TPP adsorbents were...

Clark, Dwayne C.

2012-06-07T23:59:59.000Z

373

SiC performance of coated fuel particles under high-temperature atmosphere of air  

Science Journals Connector (OSTI)

Abstract To better understand whether the SiC layer can withstand the corrosion given by the chemical reaction between SiC and O2, our experiments focused mainly on the effect of oxygen on SiC-coated fuel particles at high temperature. Tests were conducted on non-irradiated coated fuel particles in an atmosphere of air over a range of temperatures between 800 and 1600 °C. This paper summarizes the failure fractions, surface morphology and microstructure of the SiC coating, etc. The morphology of SiC-coated particles surfaces, optical and scanning electron micrographs and the oxygen distribution of polished SiC layers at 800, 1000 and 1200 °C for 200 h under air atmosphere showed that the features of SiC layers did not change in these cases. In contrast with the aforementioned cases, the behavior of SiC layers was deteriorated when the oxidation temperature was beyond 1400 °C. More serious the deterioration, higher the oxidation temperature is. The thickness of SiO2 layer from outside to inside SiC layers reached 6 ?8 ?m, and a large number of SiC-coated particles were broken into fragment at 1600 °C. The experiment results show that the oxidation of the SiC layer proceeds slowly at temperatures around 1400 °C and more rapidly as the temperature approaches 1600 °C.

Chunhe Tang; Bing Liu; Ziqiang Li; Ying Quan; Hongsheng Zhao; Youlin Shao

2014-01-01T23:59:59.000Z

374

The Birth and Life of Our Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

Birth and Life of Our Atmosphere Birth and Life of Our Atmosphere Nature Bulletin No. 554-A February 15, 1975 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation THE BIRTH AND LIFE OF OUR ATMOSPHERE In Bulletin No. 542-A we described the atmosphere that surrounds the earth, held there by the pull of gravity, including the canopy of air immediately above us. That canopy is responsible for our weather and climates, shields us from the killing rays of the sun, and furnishes substances necessary for all life: oxygen, nitrogen, carbon dioxide, and water vapor. Astronomers believe that none of the other planets -- excepting Mars, perhaps -- has an atmosphere anything like ours. The principal elements, free nitrogen (78 percent) and free oxygen (21 percent), apparently are rare in the universe. On the other hand, the earth's atmosphere contains only traces of free hydrogen and helium -- the two lightest gases -- whereas they are by far the most common elements elsewhere in the universe.

375

Ultrafast Graphene Oxide Humidity Sensors  

Science Journals Connector (OSTI)

Ultrafast Graphene Oxide Humidity Sensors ... Graphene oxide can be exploited in humidity and temperature sensors with a number of convenient features such as flexibility, transparency and suitability for large-scale manufacturing. ... Here we show that the two-dimensional nature of graphene oxide and its superpermeability to water combine to enable humidity sensors with unprecedented response speed (?30 ms response and recovery times). ...

Stefano Borini; Richard White; Di Wei; Michael Astley; Samiul Haque; Elisabetta Spigone; Nadine Harris; Jani Kivioja; Tapani Ryhänen

2013-11-09T23:59:59.000Z

376

Doped palladium containing oxidation catalysts  

DOE Patents (OSTI)

A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

Mohajeri, Nahid

2014-02-18T23:59:59.000Z

377

Chemical-looping combustion of coal-derived synthesis gas over copper oxide oxygen carriers  

SciTech Connect

CuO/bentonite and CuO-BHA nanocomposites were studied as oxygen carriers in chemical-looping combustion (CLC) of simulated synthesis gas. Global reaction rates of reduction and oxidation, as the function of reaction conversion, were calculated from 10-cycle oxidation/reduction tests utilizing thermogravimetric analysis at atmospheric pressure between 700 and 900 °C. It was found that the reduction reactions are always faster than oxidation reactions; reaction temperature and particle size do not significantly affect the reaction performance of CuO/bentonite. Multicycle CLC tests conducted in a high-pressure flow reactor showed stable reactivity for production of CO2 from fuel gas at 800 and 900 °C and full consumption of hydrogen during the reaction. Results of the tapered element oscillating microbalance showed a negative effect of pressure on the global rates of reduction-oxidation reactions at higher fractional conversions. X-ray diffraction patterns confirmed the presence of CuO in the bulk phase of the oxidized sample. Electron microanalysis showed significant morphology changes of reacted CuO/bentonite samples after the 10 oxidation-reduction cycles above 700 °C in an atmospheric thermogravimetric analyzer. The nanostructured CuO-BHA carrier also showed excellent stability and, in comparison to the CuO/bentonite system, slightly accelerated redox kinetics albeit at the expense of significantly increased complexity of manufacturing. Overall, both types of CuO carriers exhibited excellent reaction performance and thermal stability for the CLC process at 700-900 °C.

Tian, H.; Chaudhari, K.; Simonyi, T.; Poston, J.; Liu, T.; Sanders, T.; Veser, G.; Siriwardane, R.

2008-01-01T23:59:59.000Z

378

Chemical-looping combustion of coal-derived synthesis gas over copper oxide oxygen carriers  

SciTech Connect

CuO/bentonite and CuO?BHA nanocomposites were studied as oxygen carriers in chemical-looping combustion (CLC) of simulated synthesis gas. Global reaction rates of reduction and oxidation, as the function of reaction conversion, were calculated from 10-cycle oxidation/reduction tests utilizing thermogravimetric analysis at atmospheric pressure between 700 and 900 °C. It was found that the reduction reactions are always faster than oxidation reactions; reaction temperature and particle size do not significantly affect the reaction performance of CuO/bentonite. Multicycle CLC tests conducted in a high-pressure flow reactor showed stable reactivity for production of CO2 from fuel gas at 800 and 900 °C and full consumption of hydrogen during the reaction. Results of the tapered element oscillating microbalance showed a negative effect of pressure on the global rates of reduction?oxidation reactions at higher fractional conversions. X-ray diffraction patterns confirmed the presence of CuO in the bulk phase of the oxidized sample. Electron microanalysis showed significant morphology changes of reacted CuO/bentonite samples after the 10 oxidation?reduction cycles above 700 °C in an atmospheric thermogravimetric analyzer. The nanostructured CuO?BHA carrier also showed excellent stability and, in comparison to the CuO/bentonite system, slightly accelerated redox kinetics albeit at the expense of significantly increased complexity of manufacturing. Overall, both types of CuO carriers exhibited excellent reaction performance and thermal stability for the CLC process at 700?900 °C.

Tian, Hanjing; Chaudhari, K.P.; Simonyi, Thomas; Poston, J.A.; Liu, Tengfei; Sanders, Tom; Veser, Goetz; Siriwardane, R.V.

2008-11-01T23:59:59.000Z

379

Fluorine Gas Management Guidelines Fluorine is a highly toxic, pale yellow gas about 1.3 times as heavy as air at atmospheric  

E-Print Network (OSTI)

Fluorine Gas Management Guidelines Overview Fluorine is a highly toxic, pale yellow gas about 1.3 times as heavy as air at atmospheric temperature and pressure. Fluorine gas is the most powerful oxidizing agent known, reacting with practically all organic and inorganic substances. Fluorine gas

de Lijser, Peter

380

Graphene and Graphene Oxide: Biofunctionalization and Applications...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Graphene and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Abstract: Graphene...

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Radiocarbon Measurements of Atmospheric Volatile Organic Compounds:? Quantifying the Biogenic Contribution  

Science Journals Connector (OSTI)

The ability to obtain quality (interpretable) [14C]VOC measurements however relies on additional factors:? (1) transferring individual VOCs to the measurement system in a manner that preserves their original relative concentrations in the atmosphere (recovery), (2) quantifying limitations in the VOC isolation process (bias), and 3) quantifying chemical and isotopic contamination (blanks). ... The fM results for the VOC fractions from calibration mixtures and ambient samples are corrected for CO2 contamination using eq 2, where ?BLK in this case is defined as in which mCO2 is the carbon mass of residual atmospheric CO2 following LiOH treatment plus the carbon mass of CO2 contamination from the O2 used for VOC oxidation, and mREC is the total recovered carbon (Table 3). ... During pressurized sampling of humid air, water will be condensed in the canisters. ...

George A. Klouda; Charles W. Lewis; Reinhold A. Rasmussen; George C. Rhoderick; Robert L. Sams; Robert K. Stevens; Lloyd A. Currie; Douglas J. Donahue; A. J. Timothy Jull; Robert L. Seila

1996-03-26T23:59:59.000Z

382

Laboratory studies of atmospheric sulfur chemistry using tunable diode laser probes  

SciTech Connect

Tunable lead-salt diode laser absorption spectroscopy (TDLAS) provides a sensitive and versatile probe for the study of the kinetics and mechanisms of atmospheric reactions. In the laboratory, the combination of laser flash photolysis with TDLAS detection of reactant and/or product species has proven useful in several studies of the gas phase oxidation of the atmospheric sulfur compound dimethylsulfide (DMS), a process which may play an important role in global climate modification/regulation. Typically a radical species is produced by UV laser photolysis of a stable precursor in a slowly flowing mixture of reactant and buffer gases. The concentration of this radical or a selected reaction product is then followed by TDLAS on a time scale of microseconds to milliseconds. This method allows direct determination of reaction rates and product branching ratios over a range of temperature, pressure and reactant concentrations in complete isolation from reactor surfaces.

Stickel, R.E.; Urbanski, S.P.; Zhao, Z.; Wine, P.H. [Georgia Inst. of Tech., Atlanta, GA (United States)

1996-12-31T23:59:59.000Z

383

Development of Antimicrobial Coatings by Atmospheric Pressure Plasma Using a Guanidine-Based Precursor  

Science Journals Connector (OSTI)

Atmospheric pressure plasmas have been utilized in the engineering of antimicrobial materials, where their applications ranged from surface pretreatment of substrates for enhanced bonding of silver nanoparticles or antimicrobial agents in imparting antimicrobial behavior on surfaces spanning from pretreatments of substrate materials(13, 14) and very recently, deposition and/or plasma polymerization of antimicrobial polymers using monomer precursors. ... (20) Similar results of oxidized polar groups such as hydroxyls, carbonyls, and carboxyl groups on the surfaces of UHMWPE films from water vapor plasma treatments have been reported by Rodriguez-Santiago et al.(21) Also, reactive species such as ozone, O2, and O generated from plasma interactions with air from open atmosphere are also an underlying source of oxygen-bearing groups. ...

Jacqueline H. Yim; Michelle S. Fleischman; Victor Rodriguez-Santiago; Lars T. Piehler; André A. Williams; Julia L. Leadore; Daphne D. Pappas

2013-10-29T23:59:59.000Z

384

Observations of Secondary Organic Aerosol Production and Soot Aging under Atmospheric Conditions Using a Novel Environmental Aerosol Chamber  

E-Print Network (OSTI)

, heterogeneous surface reactions, cloud processing, and gas-to-particle partitioning through the formation of secondary organic aerosol (SOA) by organic gases (Pankow 1994). Moreover, SOA has been linked to adverse health effects as they typically contain... 1985; Ng et al. 2006; Presto et al. 2005; Saathoff et al. 2003). Such classes include cycloalkenes, aromatic hydrocarbons, and terpenes, most of which are cyclic compounds. When these compounds undergo atmospheric oxidation, 3 they produce first-generation...

Glen, Crystal

2012-02-14T23:59:59.000Z

385

MET 600: Advanced Atmospheric Dynamics Air-sea interface  

E-Print Network (OSTI)

the atmosphere-ocean-land system is driven? #12;Upper-Ocean Currents How the atmosphere-ocean-land system/Salinity/Mass/Momentum Conservations #12; How the atmosphere-ocean-land system is driven? It is the sun that sustains all living beings on earth #12;Energy Conservation: Global Radiation Balance How the atmosphere-ocean-land system is driven

Fu, Joshua Xiouhua

386

Apparatus and method for stabilization or oxidation of polymeric materials  

DOE Patents (OSTI)

An apparatus for treating polymeric materials comprises a treatment chamber adapted to maintain a selected atmosphere at a selected temperature; a means for supporting the polymeric material within the chamber; and, a source of ozone-containing gas, which decomposes at the selected temperature yielding at least one reactive oxidative species whereby the polymer is stabilized and cross linked through exposure to the oxidative species in the chamber at the selected temperature. The ozone may be generated by a plasma discharge or by various chemical processes. The apparatus may be configured for either batch-type or continuous-type processing. The apparatus and method are especially useful for preparing polymer fibers, particularly PAN fibers, for later carbonization treatments as well as to make flame-retardant fabrics.

Paulauskas, Felix L. (Knoxville, TN) [Knoxville, TN; Sherman, Daniel M. (Knoxville, TN) [Knoxville, TN

2010-01-19T23:59:59.000Z

387

Apparatus and method for oxidation and stabilization of polymeric materials  

DOE Patents (OSTI)

An apparatus for treating polymeric materials comprises a treatment chamber adapted to maintain a selected atmosphere; a means for supporting the polymeric material within the chamber; and, a source of plasma-derived gas containing at least one reactive oxidative species whereby the polymer is stabilized and cross linked through exposure to the oxidative species in the chamber at a selected temperature. The polymer may be directly exposed to the plasma, or alternatively, the plasma may be established in a separate volume from which the reactive species may be extracted and introduced into the vicinity of the polymer. The apparatus may be configured for either batch-type or continuous-type processing. The apparatus and method are especially useful for preparing polymer fibers, particularly PAN fibers, for later carbonization treatments.

Paulauskas, Felix L. (Knoxville, TN) [Knoxville, TN; White, Terry L. (Knoxville, TN) [Knoxville, TN; Sherman, Daniel M. (Knoxville, TN) [Knoxville, TN

2009-05-19T23:59:59.000Z

388

Apparatus and method for oxidation and stabilization of polymeric materials  

DOE Patents (OSTI)

An apparatus for treating polymeric materials comprises a treatment chamber adapted to maintain a selected atmosphere; a means for supporting the polymeric material within the chamber; and, a source of plasma-derived gas containing at least one reactive oxidative species whereby the polymer is stabilized and cross linked through exposure to the oxidative species in the chamber at a selected temperature. The polymer may be directly exposed to the plasma, or alternatively, the plasma may be established in a separate volume from which the reactive species may be extracted and introduced into the vicinity of the polymer. The apparatus may be configured for either batch-type or continuous-type processing. The apparatus and method are especially useful for preparing polymer fibers, particularly PAN fibers, for later carbonization treatments.

Paulauskas, Felix L. (Knoxville, TN) [Knoxville, TN; White, Terry L. (Knoxville, TN) [Knoxville, TN; Sherman, Daniel M. (Knoxville, TN) [Knoxville, TN

2010-08-31T23:59:59.000Z

389

Physics of Atmospheres and Oceans: Class Question Sheets COMPARATIVE PLANETARY ATMOSPHERES  

E-Print Network (OSTI)

is the mass of Jupiter and R its radius. Assuming this is all converted to thermal energy, give a crudePhysics of Atmospheres and Oceans: Class Question Sheets COMPARATIVE PLANETARY ATMOSPHERES PLA.1 for discounting the less popular of these? Show that the energy liberated during the collapse of a sphere of mass

Read, Peter L.

390

Chemical filters by non-thermal atmospheric pressure plasmas for reactive fields  

Science Journals Connector (OSTI)

Non-thermal plasmas in electrode configurations are designed in this study and investigated at atmospheric pressure for generation of reactive fields. A combination of insulated wire electrodes and bare metal wire electrodes makes it possible to obtain a filter-like assembly of microplasmas, even in ambient air or in aqueous solutions. Oxidation and reduction fields are obtained by controlling the gas supply of hydrogen, oxygen, and water vapor, and these fields benefit various functional processes such as recycling CO2, decomposing organic molecules, and increasing the work function on metal surfaces.

Osamu Sakai; Tadasuke Morita; Yoshihiko Ueda; Noriaki Sano; Kunihide Tachibana

2011-01-01T23:59:59.000Z

391

A new interpretation of the corrosion loss processes for weathering steels in marine atmospheres  

Science Journals Connector (OSTI)

Most available data sets for the long-term corrosion loss of various grades of weathering steel exposed to marine atmospheric environments are demonstrated to be consistent with the multi-phase corrosion model previously proposed for steels exposed to marine environments. This means that the early corrosion of weathering steels by oxidation is gradually inhibited by the build-up of corrosion products. These produce anoxic and sub-oxic conditions that may permit microbiological activity to govern the longer-term corrosion loss process. This new interpretation for the long-term corrosion of weathering steels may have implications for the design of such steels.

R.E. Melchers

2008-01-01T23:59:59.000Z

392

Atmospheric reactivity of gaseous dimethyl sulfate  

SciTech Connect

The atmospheric reactivity of dimethyl sulfate (DMS) with a series of atmospheric species has been investigated. Upper limits to the rate constants for the homogeneous gas-phase reactions of DMS with O{sub 3}, NH{sub 3}, and H{sub 2}O have been determined by using FTIR spectroscopy and are <1.4 {times} 10{sup {minus}21}, <1.5 {times} 10{sup {minus}21}, and <1.1 {times} 10{sup {minus}23} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. The reactivity of DMS toward ON radicals and Cl atoms has been determined by using relative rate techniques, and the rate constants for those reactions are <5 {times} 10{sup {minus}13} and (4.2 {plus minus} 0.5) {times} 10{sup {minus}13} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. These rate constants correspond to atmospheric lifetimes ranging from >23 days with respect to reaction with OH radicals to >33 years with respect to reaction with ozone. With the possible exception of its reaction with water, for which the calculated lifetime of DMS is >2 days, these results indicate that the atmospheric fate of DMS is not determined by its homogeneous gas-phase reactions with any of the atmosphere species studied.

Japar, S.M.; Wallington, T.J.; Andino, J.M.; Ball, J.C. (Ford Motor Co., Dearborn, MI (USA))

1990-03-01T23:59:59.000Z

393

Atmospheric and Climate Science | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric and Climate Science Atmospheric and Climate Science Argonne research in aerosols, micro-meteorology, remote sensing, and atmospheric chemistry combined with our scalable, portable, high-performance climate and weather applications offer a unique look at the complexities of a dynamic planet. Changes in climate can affect biodiversity, the cost of food, our health, and even whole economies. Argonne is developing computational models and tools designed to shed light on complex biological processes and their economic, social, and health effects. Research spans the molecular level to whole organisms and their interaction with climate, the ecosystem, and human activities. The goal is to improve our understanding of the world around us while increasing the accuracy of regional climate models to

394

Atmospheric Delta 14C Record from Wellington  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Isotopes » Carbon Isotopes » δ14C from Wellington Atmospheric δ14C Record from Wellington graphics Graphics data Data Investigators M.R. Manning, W.H. Melhuish National Institute of Water and Atmospheric Research, Ltd., Climate Division, Gracefield Road, Gracefield, P.O. Box 31-311, Lower Hutt, New Zealand Period of Record 1954-93 Methods Trays containing ~2 L of 5 normal NaOH carbonate-free solution are typically exposed for intervals of 1-2 weeks, and the atmospheric CO2 absorbed during that time is recovered by acid evolution. Considerable fractionation occurs during absorption into the NaOH solution, and the standard fractionation correction (Stuiver and Polach 1977) is used to determine a δ 14C value corrected to δ 13C = -25 per mil. Some samples reported here were taken using BaOH solution or with extended

395

atmospheric water vapor | OpenEI  

Open Energy Info (EERE)

atmospheric water vapor atmospheric water vapor Dataset Summary Description (Abstract): Monthly Average Solar Resource for 2-axis tracking concentrating collectors for Mexico, Central America, and the Caribbean Islands. (Purpose): Provide information on the solar resource potential for the data domain. The insolation values represent the average solar energy available to a concentrating collector, such as a dish collector, which tracks the sun continuously. Source NREL Date Released July 31st, 2006 (8 years ago) Date Updated October 30th, 2007 (7 years ago) Keywords atmospheric water vapor Carribean Islands Central America DNI GIS Mexico NREL GEF solar SWERA UNEP Data application/zip icon Download Shapefile (zip, 247.8 KiB) text/csv icon Download Data (csv, 370.6 KiB) Quality Metrics Level of Review Some Review

396

Our Dusty Atmosphere | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dusty Atmosphere Dusty Atmosphere Our Dusty Atmosphere September 6, 2011 - 4:26pm Addthis A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL Charles Rousseaux Charles Rousseaux Senior Writer, Office of Science What are the key facts? Researchers are developing a better understanding of the effects of

397

Our Dusty Atmosphere | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Our Dusty Atmosphere Our Dusty Atmosphere Our Dusty Atmosphere September 6, 2011 - 4:26pm Addthis A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL Charles Rousseaux Charles Rousseaux Senior Writer, Office of Science What are the key facts? Researchers are developing a better understanding of the effects of

398

Atmospheric Radiation Measurement Climate Research Facility | Argonne  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Radiation Measurement Climate Research Facility Atmospheric Radiation Measurement Climate Research Facility Argonne scientists study climate change 1 of 22 Argonne scientists study climate change The U.S. Department of Energy's Office of Science provided $60 million in ARRA funding for climate research to the Atmospheric Radiation Measurement (ARM) Climate Research Facility, a DOE national user facility that has been operating climate observing sites around the world for nearly two decades. These sites help scientists study clouds and their influence on the sun's radiant energy, which heats our planet. Above is one of the purchases: the Vaisala Present Weather Detector. It optically measures visibility, present weather, precipitation intensity, and precipitation type. It provides a measure of current weather conditions by combining measurements from three

399

Detection of an Extrasolar Planet Atmosphere  

E-Print Network (OSTI)

We report high precision spectrophotometric observations of four planetary transits of HD 209458, in the region of the sodium resonance doublet at 589.3 nm. We find that the photometric dimming during transit in a bandpass centered on the sodium feature is deeper by (2.32 +/- 0.57) x 10^{-4} relative to simultaneous observations of the transit in adjacent bands. We interpret this additional dimming as absorption from sodium in the planetary atmosphere, as recently predicted from several theoretical modeling efforts. Our model for a cloudless planetary atmosphere with a solar abundance of sodium in atomic form predicts more sodium absorption than we observe. There are several possibilities that may account for this reduced amplitude, including reaction of atomic sodium into molecular gases and/or condensates, photoionization of sodium by the stellar flux, a low primordial abundance of sodium, or the presence of clouds high in the atmosphere.

David Charbonneau; Timothy M. Brown; Robert W. Noyes; Ronald L. Gilliland

2001-11-28T23:59:59.000Z

400

A Community Atmosphere Model with Superparameterized Clouds  

SciTech Connect

In 1999, National Center for Atmospheric Research (NCAR) scientists Wojciech Grabowski and Piotr Smolarkiewicz created a "multiscale" atmospheric model in which the physical processes associated with clouds were represented by running a simple high-resolution model within each grid column of a lowresolution global model. In idealized experiments, they found that the multiscale model produced promising simulations of organized tropical convection, which other models had struggled to produce. Inspired by their results, Colorado State University (CSU) scientists Marat Khairoutdinov and David Randall created a multiscale version of the Community Atmosphere Model (CAM). They removed the cloud parameterizations of the CAM, and replaced them with Khairoutdinov's high-resolution cloud model. They dubbed the embedded cloud model a "super-parameterization," and the modified CAM is now called the "SP-CAM." Over the next several years, many scientists, from many institutions, have explored the ability of the SP-CAM to simulate tropical weather systems, the day-night changes of precipitation, the Asian and African monsoons, and a number of other climate processes. Cristiana Stan of the Center for Ocean-Land-Atmosphere Interactions found that the SP-CAM gives improved results when coupled to an ocean model, and follow-on studies have explored the SP-CAM's utility when used as the atmospheric component of the Community Earth System Model. Much of this research has been performed under the auspices of the Center for Multiscale Modeling of Atmospheric Processes, a National Science Foundation (NSF) Science and Technology Center for which the lead institution is CSU.

Randall, David; Branson, Mark; Wang, Minghuai; Ghan, Steven J.; Craig, Cheryl; Gettelman, A.; Edwards, Jim

2013-06-18T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Oxidation resistant alloys, method for producing oxidation resistant alloys  

DOE Patents (OSTI)

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

Dunning, John S. (Corvallis, OR); Alman, David E. (Salem, OR)

2002-11-05T23:59:59.000Z

402

Oxidation resistant alloys, method for producing oxidation resistant alloys  

DOE Patents (OSTI)

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

Dunning, John S.; Alman, David E.

2002-11-05T23:59:59.000Z

403

Atmospheric Pressure Deposition for Electrochromic Windows  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Pressure Deposition Atmospheric Pressure Deposition for Electrochromic Windows TDM - Karma Sawyer Robert C. Tenent National Renewable Energy Laboratory robert.tenent@nrel.gov 303-384-6775 4/4/2013 Insulating Glass Unit (IGU) Glass Transparent Conductor (TC) Active Electrode Counter Electrode Ion Conductor 2 | Building Technologies Office eere.energy.gov Purpose and Objectives * Expense - Current market price of $50-$100/ft 2 - Projections indicate under $20/ft 2 needed - A new production paradigm is required * Aesthetics - Architects hesitant to adopt "smurf glass"

404

Atmospheric Pressure Deposition for Electrochromic Windows  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Atmospheric Pressure Deposition Atmospheric Pressure Deposition for Electrochromic Windows TDM - Karma Sawyer Robert C. Tenent National Renewable Energy Laboratory robert.tenent@nrel.gov 303-384-6775 4/4/2013 Insulating Glass Unit (IGU) Glass Transparent Conductor (TC) Active Electrode Counter Electrode Ion Conductor 2 | Building Technologies Office eere.energy.gov Purpose and Objectives * Expense - Current market price of $50-$100/ft 2 - Projections indicate under $20/ft 2 needed - A new production paradigm is required * Aesthetics - Architects hesitant to adopt "smurf glass"

405

A sun glint heliostat for atmospheric spectroscopy  

Science Journals Connector (OSTI)

A simple arrangement based upon sun glint the brilliant image of the sun behind a convex reflecting surface is used to produce a nearly stationary image of the sun. Using a telescopemirror this image is directed into a spectrometer and is spectrally analyzed for the purpose of remote sensing of trace species in our atmosphere. Typical data using a reflecting sphere are reported and discussed qualitatively in relation to the atmospheric absorbers between the sun and detector. The over?all uses of the system are described and some cautions concerning its limitations are discussed. Alternate geometries and possible variations of the system are described.

A. E. S. Green; R. A. Sutherland; G. Ganguli

1974-01-01T23:59:59.000Z

406

Eddy-covariance observations of the atmosphere-biosphere exchange of nitrogen oxides  

E-Print Network (OSTI)

from the mean of vertical wind speed and concentration.observed between vertical wind speed and temperature sincethe cospectral density of vertical wind speed and NO X as

Min, Kyung-Eun

2012-01-01T23:59:59.000Z

407

Ball lightning from atmospheric discharges via metal nanosphere oxidation: from soils, wood or metals  

Science Journals Connector (OSTI)

...capacitor bank soil insulators sampling filter to pump earth AC Figure 2. Experimental...nozzle and across a fine silica fibre filter (Gelman A/E, glass), on the front...turn-off. Subsequently, the deposit on the filter was examined by scanning electron microscopy...

2002-01-01T23:59:59.000Z

408

Numerical study of the partial oxidation of a coal particle in steam and dry air atmospheres  

Science Journals Connector (OSTI)

......and oxygen on particle combustion rate are approximately...modelling of particle combustion, studies on the in...coupled with a simple chemistry) on the influences...and velocity of the coal char particle, and...establishment of the combustion or gasification regimes......

M. Kestel; P. Nikrityuk; O. Hennig; C. Hasse

2012-02-01T23:59:59.000Z

409

Evaluation of Hydrogen Isotope Oxidation Process in an Atmospheric Pressure Plasma  

Science Journals Connector (OSTI)

Detritiation and Isotope Separation / Proceedings of the Ninth International Conference on Tritium Science and Technology (Part 2)

K. Akahane; N. Ezumi; Y. Uesugi; Y. Tanaka; M. Tanaka; K. Nishimura

410

Uncertainties in estimates of the oxidative capacity of the urban atmosphere : a modeling and measurement approach  

E-Print Network (OSTI)

Mobile emissions represent a significant fraction of the total anthropogenic emissions burden in megacities and have a deleterious effect on air quality at local and regional scales. Due to the significant sources of ...

Zavala-Pérez, Miguel Angel

2007-01-01T23:59:59.000Z

411

Enhanced Thermal Conductivity Oxide Fuels  

SciTech Connect

the purpose of this project was to investigate the feasibility of increasing the thermal conductivity of oxide fuels by adding small fractions of a high conductivity solid phase.

Alvin Solomon; Shripad Revankar; J. Kevin McCoy

2006-01-17T23:59:59.000Z

412

Anodic oxidation of zircaloy-2  

Science Journals Connector (OSTI)

The anodic polarization of zircaloy-2 in different electrolytic baths has been investigated in order to obtain thick oxide films with properties suitable for wear applications.

A. Conte; A. Borello; A. Cabrini

1976-07-01T23:59:59.000Z

413

Cooperative Institute for Research in the Atmosphere  

E-Print Network (OSTI)

#12;2 Cooperative Institute for Research in the Atmosphere Contents 3 Heavy Snowfall regulations designed to elimi- nate human-caused haze in Big Bend and 155 other National Parks), and the Electric Power Research Institute (EPRI), among others. In support of BRAVO, NPS and CIRA scientists

Collett Jr., Jeffrey L.

414

Kinetics of Non-Thermal Atmospheric Pressure  

E-Print Network (OSTI)

Kinetics of Non-Thermal Atmospheric Pressure Plasmas Alexander Fridman · Microdischarge Interaction and Structuring in Dielectric Barrier Discharges · Kinetics of Blood Coagulation in Plasma · Surface Wound wire Area of DBD plasma region: ~104cm2 #12;7 Microdischarge Patterning (2D) R22 R23 R24 R26 R27 R28

Kaganovich, Igor

415

Sputtering and heating of Titan's upper atmosphere  

Science Journals Connector (OSTI)

...Although, the plasma energy deposition...viable, but the plasma heating is inadequate...be true: another non-thermal process must be active...composition of the ambient plasma near Titan's orbit...used to test the atmospheric loss rate. Prior...

2009-01-01T23:59:59.000Z

416

THE LOWER SOLAR ATMOSPHERE ROBERT J. RUTTEN  

E-Print Network (OSTI)

of solar composition studies. The first column labeled "radial" describes the overall structure of the workTHE LOWER SOLAR ATMOSPHERE ROBERT J. RUTTEN Sterrekundig Instituut, Postbus 80 000, NL­3508 TA, Utrecht, The Netherlands Abstract. This "rapporteur" report discusses the solar photosphere and low

Rutten, Rob

417

Atmospheric chemistry of gaseous diethyl sulfate  

SciTech Connect

The atmospheric reactivity of diethyl sulfate (DES) has been investigated. Upper limits to the rate constants (in cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}) for the homogeneous gas-phase reactions of DES with O{sub 3}, NH{sub 3}, and H{sub 2}O have been determined by FTIR spectroscopy and are <3.4 {times} 10{sup {minus}21}, <1.4 {times} 10{sup {minus}21}, and {le}2.3 {times} 10{sup {minus}23}, respectively. The reactivity of DES toward OH radicals and Cl atoms has been determined by using relative rate techniques. These rate constants correspond to atmospheric lifetimes ranging from {ge}1 day with respect to reaction with water to >12 years with respect to ozone. With the possible exception of its reaction with water, these results indicate that the atmospheric fate of DES within an urban air parcel is not determined by its homogeneous gas-phase reactions with any of the atmospheric species studied. No evidence has been found for the formation of DES or related compounds during the ozonolysis of olefins in the presence of SO{sub 2} and ethanol.

Japar, S.M.; Wallington, T.J.; Andino, J.M.; Ball, J.C. (Ford Motor Co., Dearborn, MI (USA))

1990-06-01T23:59:59.000Z

418

METEOROLOGICAL Journal of Atmospheric and Oceanic Technology  

E-Print Network (OSTI)

that there is no10 isotopic fractionation between the liquid phase and the generated moist "air". The water11., A microdrop generator for the calibration of.... 1. Introduction1 2 Water vapor is a key element in the globalAMERICAN METEOROLOGICAL SOCIETY Journal of Atmospheric and Oceanic Technology EARLY ONLINE RELEASE

Paris-Sud XI, Université de

419

Wind Structure in the Atmospheric Boundary Layer  

Science Journals Connector (OSTI)

13 May 1971 research-article Wind Structure in the Atmospheric Boundary Layer...semi-empirical laws for the variation of mean wind speed with height and for the statistical...provide some useful ordering of the mean wind profile characteristics in relation to...

1971-01-01T23:59:59.000Z

420

TETTERSTO NATURE Pre-industrial atmospheric  

E-Print Network (OSTI)

, starting with the Greek and Roman cultures3'4.The cumulative deposition from anthropogenicsourcesin preTETTERSTO NATURE Pre-industrial atmospheric lead contamination detected in Swedish lake sediments for pre-industrial atmospherictrace-metalcontaminationt''it is commonlyassumed that air pollution

Short, Daniel

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Doctoral Programs Atmospheric, Oceanic & Space Sciences  

E-Print Network (OSTI)

Professor; Recipient, Teaching Innovation Prize; Michigan Distinguished Professor of the Year Allison Mission to Comet 67P / Churyumov- Gerasimenko · Solar and Heliospheric Physics Group · STEREO Mission,OceanicandSpaceSciences Atmospheric, Oceanic & Space Sciences University of Michigan Space Research Building 2455 Hayward Street Ann

Eustice, Ryan

422

Doctoral Programs Atmospheric, Oceanic & Space Sciences  

E-Print Network (OSTI)

University of Michigan Space Research Building 2455 Hayward Street Ann Arbor, MI 48109-2143 aoss Katherine E. White, Ann Arbor ©The Regents of the University of Michigan Research areas Atmospheric Science/Thermosphere Physics Planetary Magnetospheres Solar & Heliospheric Physics Space Weather Aeronomy For Faculty involved

Eustice, Ryan

423

1 - Solubility of Atmospheric Gases in Freshwater  

Science Journals Connector (OSTI)

This chapter presents tabular information on the standard air saturation concentration (moist air at 1 atm) for oxygen, nitrogen, argon, and carbon dioxide gas in terms of ?mol/kg, mg/L, and mL/L; and in terms of Bunsen coefficients L real gas/(L atm); mg real gas/(L mmHg); and mg real gas/(L kPa) for 0–40°C and freshwater conditions. Because the mole fraction of carbon dioxide in the atmosphere is changing, solubility information is provided for 2010 (390 ?atm) and for 2030 (440 ?atm) based on projected atmospheric values. Tabular information is also provided to allow computation of standard air saturation concentrations of carbon dioxide gas directly as a function of atmospheric mole fraction. Conversion factors are presented to convert these concentrations to other commonly used units. Equations and tabular information are provided to compute air saturation concentration for moist air at local barometric pressure for the four atmospheric gases. Because of the importance of dissolved oxygen in biological processes, the air solubility concentration is also presented as a function of elevation for both metric and English elevations. Equations and tabular information are provided to allow conversion of concentrations in mg/L to partial pressures in mmHg. Sample problems are included for representative examples. Keywords gas solubility, freshwater, oxygen, nitrogen, argon, carbon dioxide, standard air solubility, air solubility, Bunsen coefficients, partial pressures

John Colt

2012-01-01T23:59:59.000Z

424

Introducing Research College of Oceanic & Atmospheric Sciences  

E-Print Network (OSTI)

.coas.oregonstate.edu WECOMA WECOMA Coll ege of Oceanic & Atmospheric Scie nces OREGON STATE UNIVERSITY in the O cean currents, to the south in summer and generally to the north in winter, create ocean currents. The strong summertime and the topography of the ocean floor influence the east-west cross-shelf currents. Understanding and being able

Pierce, Stephen

425

Introducing Research College of Oceanic & Atmospheric Sciences  

E-Print Network (OSTI)

WECOMA Coll ege of Oceanic & Atmospheric Scie nces OREGON STATE UNIVERSITY in the O cean currents introduced by man (e.g., pollutants). Knowledge of upper-ocean currents is important for navigation and for search and rescue. The ocean currents off Oregon vary seasonally and can also vary from year to year

Barth, Jack

426

Nonlinear waves in the solar atmosphere  

Science Journals Connector (OSTI)

...the intended application to solar physics deserves great effort...waves and oscillations in the solar plasma. Figure 1 A typical...distance from the base of the solar atmosphere. The quantity is...The (a), (b) and (c) panels correspond to z=0, z=z...

2006-01-01T23:59:59.000Z

427

White Dwarf Spectra and Atmosphere Models  

E-Print Network (OSTI)

We describe the spectral classification of white dwarfs and some of the physical processes important for their understanding. In the major part of this paper we discuss the input physics and computational methods for one of the most widely used stellar atmosphere codes for white dwarfs.

Detlev Koester

2008-12-02T23:59:59.000Z

428

Ch.6 Atmospheric and Oceanic Circulations  

E-Print Network (OSTI)

difference in air pressure. #12;Measure Air Pressure-- Mercury Barometer ·Seal the glass tube at one end of latitude. Meridional flows Zonal flows #12;Learning Objective Two: Air Pressure #12;Air Pressure Atmospheric pressure is the force per unit area exerted against a surface by the weight of air above

Pan, Feifei

429

Stereographic displays of atmospheric model data  

Science Journals Connector (OSTI)

A system has been developed to display color stereographic time-lapsed sequences of outputs of three-dimensional atmospheric models. Contour lines and wind vectors derived from a model can be overlaid on a geostationary satellite image or displayed with ... Keywords: Computer graphics, Meteorology, Modeling display, Stereography

Mary desJardins; A. Frederick Hasler

1980-07-01T23:59:59.000Z

430

The Magnetic Field in the Solar Atmosphere  

E-Print Network (OSTI)

This publication provides an overview of magnetic fields in the solar atmosphere with the focus lying on the corona. The solar magnetic field couples the solar interior with the visible surface of the Sun and with its atmosphere. It is also responsible for all solar activity in its numerous manifestations. Thus, dynamic phenomena such as coronal mass ejections and flares are magnetically driven. In addition, the field also plays a crucial role in heating the solar chromosphere and corona as well as in accelerating the solar wind. Our main emphasis is the magnetic field in the upper solar atmosphere so that photospheric and chromospheric magnetic structures are mainly discussed where relevant for higher solar layers. Also, the discussion of the solar atmosphere and activity is limited to those topics of direct relevance to the magnetic field. After giving a brief overview about the solar magnetic field in general and its global structure, we discuss in more detail the magnetic field in active regions, the quie...

Wiegelmann, Thomas; Solanki, Sami K

2014-01-01T23:59:59.000Z

431

Operation of staged membrane oxidation reactor systems  

SciTech Connect

A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

Repasky, John Michael

2012-10-16T23:59:59.000Z

432

Effect of oxidizing environment on the strength and oxidation kinetics of HTGR graphites. Part I. Reactivity and strength loss of H451, PGX and IG-11 graphites  

SciTech Connect

The effects of oxidizing atmosphere and temperature on the reactivities and strengths of PGX, H451, and IG-11 were examined. Preliminary measurements of the oxidation kinetics of these graphites in H/sub 2/O-, CO/sub 2/- and O/sub 2/-containing atmospheres indicated that the reactivities of H451 graphite toward O/sub 2/ and H/sub 2/O are quite similar to those of IG-11 graphite. The apparent activation energy for oxidation of these in O/sub 2/ were estimated to be approx. 175 kJ/mol while that in H/sub 2/O is probably approx. 200 kJ/mol. The apparent activation energy of IG-11 graphite oxidized in CO/sub 2/ is 255 +- 18 kJ/mol. PGX graphite was found to be quite variable in its reactivity toward H/sub 2/O. A linear dependence with (Fe) was determined, but other intrinsic properties were found to affect its absolute reactivity by as much as a factor of X50.

Eto, M.; Growcock, F.B.

1981-09-01T23:59:59.000Z

433

Catalytic wet oxidation of phenolic wastes  

E-Print Network (OSTI)

Possible catalyst deactivation problems High capital, low operating Supercritical water oxidation (SCWO) Feasible only at high organic concentra- tions High Fast reaction, complete oxidation Severe reaction conditions, canosion problems... of milder reaction conditions and is much less energy intensive. Thus, catalytic wet oxidation would be an alternative to solvent extraction, supercritical water oxidation, homogeneous oxidation, and incineration. It should also be feasible at low...

Thomas, Brook James

1995-01-01T23:59:59.000Z

434

Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications  

E-Print Network (OSTI)

Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.solidoxide.html, Tubular Solid Oxide Fuel Cell Technology,Oxide Films for Solid Oxide Fuel Cell Applications by Jason

Nicholas, Jason.D.

2007-01-01T23:59:59.000Z

435

Plasmonic transparent conducting metal oxide nanoparticles and films for optical sensing applications  

DOE Patents (OSTI)

The disclosure relates to a method of detecting a change in a chemical composition by contacting a doped oxide material with a monitored stream, illuminating the doped oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The doped metal oxide has a carrier concentration of at least 10.sup.18/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.1 S/cm, where parameters are specified at a temperature of 25.degree. C. The optical response of the doped oxide materials results from the high carrier concentration of the doped metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration. These changes in effective carrier densities of conducting metal oxide nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary doped metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

Ohodnicki, Jr., Paul R; Wang, Congjun; Andio, Mark A

2014-01-28T23:59:59.000Z

436

Electronically conducting metal oxide nanoparticles and films for optical sensing applications  

DOE Patents (OSTI)

The disclosure relates to a method of detecting a change in a chemical composition by contacting a conducting oxide material with a monitored stream, illuminating the conducting oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The conducting metal oxide has a carrier concentration of at least 10.sup.17/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.-1 S/cm, where parameters are specified at the gas stream temperature. The optical response of the conducting oxide materials is proposed to result from the high carrier concentration and electronic conductivity of the conducting metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration and electronic conductivity. These changes in effective carrier densities and electronic conductivity of conducting metal oxide films and nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary conducting metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

Ohodnicki, Jr., Paul R.; Wang, Congjun; Andio, Mark A

2014-09-16T23:59:59.000Z

437

Indoor atmospheric corrosion of conventional weathering steels in the tropical atmosphere of Panama  

Science Journals Connector (OSTI)

One year indoor atmospheric corrosion examinations have been carried out on two conventional weathering steels for a year, at two test sites, Tocumen and Sherman Breakwater in Panama. They are environmentally cla...

Juan A. Jaén; Josefina Iglesias; Olga Adames

2014-01-01T23:59:59.000Z

438

Representing El Niño in Coupled Ocean–Atmosphere GCMs: The Dominant Role of the Atmospheric Component  

Science Journals Connector (OSTI)

A systematic modular approach to investigate the respective roles of the ocean and atmosphere in setting El Niño characteristics in coupled general circulation models is presented. Several state-of-the-art coupled models sharing either the same ...

E. Guilyardi; S. Gualdi; J. Slingo; A. Navarra; P. Delecluse; J. Cole; G. Madec; M. Roberts; M. Latif; L. Terray

2004-12-01T23:59:59.000Z

439

Corrosion evaluation of weldments exposed in TVA and Rocketdyne AFB (Atmospheric Fluid-Bed) Combustors  

SciTech Connect

A number of experimental iron-, nickel-, and cobalt-based weldment materials were exposed in TVA 20MW and Rocketdyne Atmospheric Fluid-bed Combustors at 849{degree}C for 1261 h and 871{degree}C for 1000 h, respectively. The post-exposure analyses were conducted in Argonne National Laboratory. All specimens experienced different degrees of internal oxidation/sulfidation. Among eight filler materials, Marathon 25/35R and Haynes 188 showed the least corrosion attack, which was less than 0.5 mmpy. The high nickel content in the weldment turned out to be unfavorable for the corrosion resistance in AFBC environment. The differences in the coal/bed chemistry induced different corrosion behavior in materials exposed in TVA and Rocketdyne systems. Calcium sulfate deposit on the specimens showed significant effects on the internal oxidation/sulfidation of the alloys. The results of this study would supplement the material database, in particular weldment performance, and aid in materials selection for atmospheric fluidized bed combustor applications. 10 refs., 13 figs., 4 tabs.

Wang, D.Y.; Natesan, K.

1989-09-01T23:59:59.000Z

440

Fractal and Multifractal Analysis of the Rise of Oxygen in Earth's Early Atmosphere  

E-Print Network (OSTI)

The rise of oxygen in Earth's atmosphere that occurred 2.4 to 2.2 billion years ago is known as the Earth's Great Oxidation, and its impact on the development of life on Earth has been profound. Thereafter, the increase in Earth's oxygen level persisted, though at a more gradual pace. The proposed underlying mathematical models for these processes are based on physical parameters whose values are currently not well-established owing to uncertainties in geological and biological data. In this paper, a previously developed model of Earth's atmosphere is modified by adding different strengths of noise to account for the parameters' uncertainties. The effects of the noise on the time variations of oxygen, carbon and methane for the early Earth are investigated by using fractal and multifractal analysis. We show that the time variations following the Great Oxidation cannot properly be described by a single fractal dimension because they exhibit multifractal characteristics. The obtained results demonstrate that the time series as obtained exhibit multifractality caused by long-range time correlations.

Satish Kumar; Manfred Cuntz; Zdzislaw E. Musielak

2014-12-16T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Influence of a Cerium surface treatment on the oxidation behavior of type 347 stainless steel  

SciTech Connect

A surface treatment was applied to the surface of Type 347 stainless steel to enhance oxidation resistance. The treatment consisted of dip coating coupons in a CeO2 and halide activator slurry, followed by a thermal treatment at 900C in an inert atmosphere for 12 hours. Cyclical oxidation tests were conducted at 800C in either dry air or air+3%H2O. In dry air, the treatment reduced the oxidation rate (reduced the magnitude of weight gain) of the alloy by a factor of three. Protective chromium based oxide and spinel ((Mn,Cr)3O4 and (Cr,Fe)2O3) phases formed on the surface of the untreated and treated alloy. More significantly, the treatment suppressed the oxide scale spallation that occurred upon cyclical exposure of this alloy to moist air. In moist air, less protective chromite (FeCr2O4), magnetite (Fe+2Fe2+3O4), and hematite (Fe2O3) formed as oxide products on the surface of the base alloy. The treated alloy did not spall during exposure to moist air, and interestingly, the treated alloy possessed similar oxidation rates (magnitude of weight gain) in both moist and dry air. The same protective chromium based oxide and spinel ((Mn,Cr)3O4 and (Cr,Fe)2O3) phases formed on the surface of the treated alloy exposed to both moist and dry air. In the aggressive moist environment, the Ce surface treatment suppressed the formation of less protective iron-oxides, and concomitant oxide scale spallation during thermal cycling.

Alman, D.E.; Jablonski, P.D.

2007-04-01T23:59:59.000Z

442

Metal oxide films on metal  

DOE Patents (OSTI)

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

443

Ethylene Oxide for Soil Sterilization  

Science Journals Connector (OSTI)

... , this method may be time-consuming, and in view of the physical properties of ethylene oxide (solubility in water and boiling point 12-5 C.) it was considered ... consists of making up an aqueous solution to supply 2 or 4 c.c. of ethylene oxide in a given amount of water, using pre-chilled glassware and water. The ...

R. E. ROSE; R. W. BAILEY

1952-04-26T23:59:59.000Z

444

Ultra Supercritical Steamside Oxidation  

SciTech Connect

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

2005-01-01T23:59:59.000Z

445

Stability of Ruddlesden–Popper-structured oxides in humid conditions  

SciTech Connect

Some of layered transition-metal oxides are known to react with atmospheric humidity to form through topotactic intercalation reactions new water-containing layered structures. Here we investigate the influence of oxygen content (7??) of the Ruddlesden–Popper-structured Sr{sub 3}FeMO{sub 7??} (M=Ni, Mn, Ti) oxides on the water-intercalation reaction. It is found that their oxygen contents influence greatly the reactivity of the phases with water. Other factors possibly affecting the reactivity are discussed on the basis of the present data in combination with a comprehensive review of previous works on Ruddlesden–Popper and related layered oxide phases. - Graphical abstract: Many of the Ruddlesden–Popper-structured A{sub 3}B{sub 2}O{sub 7??} oxides readily react with water via intercalation reactions. Three possible factors affecting the water intercalation are identified: oxygen content of the phase, ionic radius of cation A and valence state of cation B. The resultant layered water-derivative phases can be categorised into two groups, depending on the crystal symmetry of the phase. Highlights: • Ruddlesden–Popper oxides A{sub 3}B{sub 2}O{sub 7??} often accommodate water via intercalation reaction. • The lower the oxygen content 7?? is the more readily the intercalation reaction occurs. • The second factor promoting the reaction is the large size of cation A. • The third possible factor is the high valence state of cation B. • Resultant water-derivatives can be categorised into two groups depending on symmetry.

Lehtimäki, M.; Yamauchi, H.; Karppinen, M., E-mail: maarit.karppinen@aalto.fi

2013-08-15T23:59:59.000Z

446

ARM - Field Campaign - Tropical Ocean Global Atmosphere Coupled  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsTropical Ocean Global Atmosphere Coupled Ocean-Atmosphere govCampaignsTropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Exp Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Exp 1992.07.11 - 1993.02.28 Lead Scientist : Chuck Long Data Availability Final data available. For data sets, see below. Summary IOP completed. Description The Tropical Ocean Global Atmosphere Coupled Ocean-Atmosphere Response Experiment (TOGA-COARE) was conducted to better understand the structure of the coupled system of the warm pool of the western Pacific Ocean. Hundreds of participants from dozens of countries took part in this experiment from November 1, 1992 through February 28, 1993. Campaign Data Sets

447

BIOSIGNATURE GASES IN H?-DOMINATED ATMOSPHERES ON ROCKY EXOPLANETS  

E-Print Network (OSTI)

Super-Earth exoplanets are being discovered with increasing frequency and some will be able to retain stable H2-dominated atmospheres. We study biosignature gases on exoplanets with thin H2 atmospheres and habitable surface ...

Seager, Sara

448

Faculty-Led Study Abroad in Atmospheric Science Education  

Science Journals Connector (OSTI)

For several years the University of Wisconsin–Milwaukee's Atmospheric Science group has offered the faculty-led study abroad program Mexico: Air Pollution and Ancient Cultures. In this course, open to both atmospheric science majors and nonmajors as well ...

Jonathan D. W. Kahl; Julia G. Cerón

2014-02-01T23:59:59.000Z

449

Trends and inferred emissions of atmospheric high molecular weight perfluorocarbons  

E-Print Network (OSTI)

Atmospheric observations and atmospheric observation-based global emission estimates are presented for the five high molecular weight perfluorocarbons (PFCs): decafluorobutane (C 4 F 1 0 ), dodecafluoropentane (C5 F1 2 ), ...

Ivy, Diane Jean

2012-01-01T23:59:59.000Z

450

Muon diagnostics of the Earth’s atmosphere and magnetosphere  

Science Journals Connector (OSTI)

A method of distant monitoring of the Earth’s magnetosphere and atmosphere is described, which is based on the close correlation between the modulations in the flux of atmospheric muons detected at the Earth’s su...

N. S. Barbashina; V. V. Borog…

2007-07-01T23:59:59.000Z

451

COLLOQUIUM: The Alfvénic Motions of the Sun's Outer Atmosphere...  

NLE Websites -- All DOE Office Websites (Extended Search)

8, 2013, 4:15pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: The Alfvnic Motions of the Sun's Outer Atmosphere Scott McIntosh National Center for Atmospheric Research (NCAR)...

452

Land-atmosphere interaction and radiative-convective equilibrium  

E-Print Network (OSTI)

I present work on several topics related to land-atmosphere interaction and radiative-convective equilibrium: the first two research chapters invoke ideas related to land-atmosphere interaction to better understand ...

Cronin, Timothy (Timothy Wallace)

2014-01-01T23:59:59.000Z

453

Hadley Cell Dynamics in a Virtually Dry Snowball Earth Atmosphere  

Science Journals Connector (OSTI)

The Hadley cell of a virtually dry snowball Earth atmosphere under equinox insolation is studied in a comprehensive atmospheric general circulation model. In contrast to the Hadley cell of modern Earth, momentum transport by dry convection, which ...

Aiko Voigt; Isaac M. Held; Jochem Marotzke

2012-01-01T23:59:59.000Z

454

Atmospheric Crude Oil Distillation Operable Capacity  

Gasoline and Diesel Fuel Update (EIA)

(Barrels per Calendar Day) (Barrels per Calendar Day) Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge Capacity (B/SD) Thermal Cracking Downstream Charge Capacity (B/SD) Thermal Cracking Total Coking Downstream Charge Capacity (B/SD) Thermal Cracking Delayed Coking Downstream Charge Capacity (B/SD Thermal Cracking Fluid Coking Downstream Charge Capacity (B/SD) Thermal Cracking Visbreaking Downstream Charge Capacity (B/SD) Thermal Cracking Other/Gas Oil Charge Capacity (B/SD) Catalytic Cracking Fresh Feed Charge Capacity (B/SD) Catalytic Cracking Recycle Charge Capacity (B/SD) Catalytic Hydro-Cracking Charge Capacity (B/SD) Catalytic Hydro-Cracking Distillate Charge Capacity (B/SD) Catalytic Hydro-Cracking Gas Oil Charge Capacity (B/SD) Catalytic Hydro-Cracking Residual Charge Capacity (B/SD) Catalytic Reforming Charge Capacity (B/SD) Catalytic Reforming Low Pressure Charge Capacity (B/SD) Catalytic Reforming High Pressure Charge Capacity (B/SD) Catalytic Hydrotreating/Desulfurization Charge Capacity (B/SD) Catalytic Hydrotreating Naphtha/Reformer Feed Charge Cap (B/SD) Catalytic Hydrotreating Gasoline Charge Capacity (B/SD) Catalytic Hydrotreating Heavy Gas Oil Charge Capacity (B/SD) Catalytic Hydrotreating Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Kerosene/Jet Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Diesel Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Other Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Residual/Other Charge Capacity (B/SD) Catalytic Hydrotreating Residual Charge Capacity (B/SD) Catalytic Hydrotreating Other Oils Charge Capacity (B/SD) Fuels Solvent Deasphalting Charge Capacity (B/SD) Catalytic Reforming Downstream Charge Capacity (B/CD) Total Coking Downstream Charge Capacity (B/CD) Catalytic Cracking Fresh Feed Downstream Charge Capacity (B/CD) Catalytic Hydro-Cracking Downstream Charge Capacity (B/CD) Period:

455

Nanostructured Solid Oxide Fuel Cell Electrodes  

E-Print Network (OSTI)

post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and V. I. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C.Nanostructured Solid Oxide Fuel Cell Electrodes By Tal Zvi

Sholklapper, Tal Zvi

2007-01-01T23:59:59.000Z

456

Detection of oxidation in human serum lipoproteins  

E-Print Network (OSTI)

A method for the oxidation of lipoproteins in vitro was developed using the free radical initiator, 2,2?-azobis-(2-amidinopropane) dihydrochloride (AAPH). Following in vitro oxidation, the susceptibility to oxidation of the serum samples...

Myers, Christine Lee

2006-04-12T23:59:59.000Z

457

Coal Fly Ash as a Source of Iron in Atmospheric Dust  

SciTech Connect

Anthropogenic coal fly ash aerosols may represent a significant source of bioavailable iron in the open ocean. Few measurements have been made to compare the solubility of atmospheric iron from anthropogenic aerosols and other sources. We report an investigation of the iron dissolution of three fly ash samples in acidic aqueous solutions and compare the solubilities with that of Arizona test dust, a reference material of mineral dust. The effects of pH, cloud processing, and solar irradiation on Fe solubility were explored. Similar to previously reported results on mineral dust, iron in aluminosilicate phases provide predominant dissolved iron compared with iron in oxides. Iron solubility of fly ash is higher than Arizona test dust, especially at the higher pH conditions investigated. Simulated atmospheric processing elevates iron solubility due to significant changes in the morphology aluminosilicate glass, a dominantly material in fly ash particle. Iron continuously releases into the aqueous solution as fly ash particles break up into smaller fragments. The assessment of dissolved atmospheric iron deposition fluxes, and their effect on the biogeochemistry at ocean surface should be constrained by taking into account the source, environment pH, Fe speciation, and solar radiation.

Chen, Haihan; Laskin, Alexander; Baltrusaitis, Jonas; Gorski, Christopher A.; Scherer, Michelle; Grassian, Vicki H.

2012-01-18T23:59:59.000Z

458

Surface Nanostructuring of Polysulfone Membranes by Atmospheric Pressure Plasma-Induced Graft Polymerization (APPIGP)  

E-Print Network (OSTI)

large substrates. Various atmospheric plasma sources arePolymerization The atmospheric plasma source used in thisby Remote Atmospheric- Pressure Plasma. Ieee Transactions on

Kim, Soo Min

2013-01-01T23:59:59.000Z

459

Sensitive multi-photon nonlinear laser spectroscopic methods for isotope analysis in atmospheric and environmental applications  

E-Print Network (OSTI)

measurements in atmospheric pressure plasma. However, nonean atmospheric radio-frequency inductively coupled plasma (atmospheric atomizer. Also, the inductively coupled plasma

Lyons, Wendy Jean

2009-01-01T23:59:59.000Z

460

E-Print Network 3.0 - atmospheric physics Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

for: atmospheric physics Page: << < 1 2 3 4 5 > >> 1 Cloud Physics and Atmospheric Chemistry http:cpac.pku.edu.cn Summary: Cloud Physics and Atmospheric Chemistry http:...

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

E-Print Network 3.0 - atmospheric aerosol size Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

for about ten percent of all aerosols in the atmosphere. We... , can actually absorb solar energy and warm the atmosphere. Atmospheric aerosols are very important... by...

462

Dispersion relation for magnetosonic waves within the upper atmospheric plasma  

Science Journals Connector (OSTI)

The dispersion relation for magnetosonic waves within the upper atmospheric plasma has been derived. The result can be...

S. S. De; Bithika Ghosh; Manasi Mal; B. Ghosh

1990-01-01T23:59:59.000Z

463

FUEL CELLS – SOLID OXIDE FUEL CELLS | Systems  

Science Journals Connector (OSTI)

In this article, some basic arrangements of solid oxide fuel cell (SOFC) systems are described, starting with atmospheric systems using a catalytic burner or a thermal burner and anode gas recycling. For illustrating the potential electrical efficiency of SOFC systems, their combination with a gas turbine and also with a steam turbine (ST) are described. To be able to evaluate the potential of the different systems, first the essential efficiencies relevant to fuel cell systems are defined and then the basics of calculating energy balance are illustrated. Equations are given to describe, for example, the effect of fuel recycling on system fuel utilization and of internal reforming on the necessary air flow for cooling the stack. It is obvious that electrical efficiency depends strongly on cell voltage and fuel utilization. In the case of cells that operate with a high fuel utilization at cell voltages of 800 mV, a net electrical efficiency above 55% can be achieved. The combination in a pressurized system with a gas turbine enables efficiencies of up to 70% and combining this system with an additional ST allows efficiencies of up to 75%. However, an investigation into the size of these \\{STs\\} shows that such combined systems make sense only above a gas input of 10 MW.

L. Blum; E. Riensche

2009-01-01T23:59:59.000Z

464

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network (OSTI)

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from a global 3D land.S. National Science Foundation Atmospheric Chemistry Program #12;FROM ATMOSPHERE TO FISH: MERCURY RISING Ice core from Wyoming [Schuster et al., ES&T 2002] Mercury deposition has increased by 300% since

Selin, Noelle Eckley

465

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network (OSTI)

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from global modeling Noelle Atmospheric Chemistry Program #12;FROM ATMOSPHERE TO FISH: MERCURY RISING Ice core from Wyoming [Schuster et al., ES&T 2002] Mercury deposition has increased by 300% since industrialization Major anthropogenic

Selin, Noelle Eckley

466

The nature of moss and lower atmospheric seismology  

Science Journals Connector (OSTI)

...TR (i.e. thermal interface between...perform lower atmospheric seismology...chromospheric plasma upwards at...despite the atmospheric seeing deformations...EUV-emitting plasma in its vicinity...tunnel some non-propagating...examples of lower atmospheric seismology...in the solar plasma. Figure 1...

2006-01-01T23:59:59.000Z

467

Nonequilibrium atmospheric secondary organic aerosol formation and growth  

Science Journals Connector (OSTI)

...Mexico City area are shown...inorganic atmospheric aerosols...2005 ) A large organic aerosol source...photochemical and thermal studies of...Characteristic Group Frequencies—Tables and...particle thermal speed...phase-equilibrium in the atmospheric system: Aerosol...Support, Non-U.S...Determination by plasma-based...implications for atmospheric chemistry...2002) A thermal disso-ciation...

Véronique Perraud; Emily A. Bruns; Michael J. Ezell; Stanley N. Johnson; Yong Yu; M. Lizabeth Alexander; Alla Zelenyuk; Dan Imre; Wayne L. Chang; Donald Dabdub; James F. Pankow; Barbara J. Finlayson-Pitts

2012-01-01T23:59:59.000Z

468

New consideration of atmospheric refraction in laser ranging data  

Science Journals Connector (OSTI)

......atmosphere near the Earth. Atmospheric refraction increases...function based on the generator function method proposed...incorporated with the generator function theory and...which P is the total atmospheric pressure in millibars...partial pressure of water vapour in millibars......

Haojian Yan; Guangli Wang

1999-08-11T23:59:59.000Z

469

Refined correlations between atmospheric and rapid polar motion excitations  

Science Journals Connector (OSTI)

......experiments, the atmospheric or geodetic excitation...a random number generator, and is regenerated...1990. Global water storage and polar...C.R., 1993. Atmospheric excitation computations...polar motion by atmospheric angular momentum...Global surface water-induced Rosen......

T. C. Stieglitz; S. R. Dickman

1999-10-01T23:59:59.000Z

470

Integrated Water, Atmosphere, Ecosystems, Education and Research Program  

E-Print Network (OSTI)

I-WATER Integrated Water, Atmosphere, Ecosystems, Education and Research Program #12;I-WATER management decisions? II--WATERWATER Integrated Water, Atmosphere,Integrated Water, Atmosphere, Ecosystems resource issues. #12;I-WATER: Vision and Goals ¤ I-WATER will provide a new generation of Ph.D. students

471

Short-term production and synoptic influences on atmospheric 7  

E-Print Network (OSTI)

Short-term production and synoptic influences on atmospheric 7 Be concentrations Ilya G. Usoskin,1; published 21 March 2009. [1] Variations of the cosmogenic radionuclide 7 Be in the global atmosphere the variations in the 7 Be concentration in the atmosphere for the period from 1 January to 28 February 2005

472

Numerical Analysis of Flow Characteristics of An Atmospheric Plasma Torch  

E-Print Network (OSTI)

Numerical Analysis of Flow Characteristics of An Atmospheric Plasma Torch You-Jae Kim, J.-G. HanCheon-dong, Suwon 440-746, KOREA Abstract The atmospheric plasma is regarded as an effective method for surface mathematical models used for simulating plasma characteristics inside an atmospheric plasma torch is carried

Paris-Sud XI, Université de

473

College of Earth, Ocean, and Atmospheric Sciences Oregon State University  

E-Print Network (OSTI)

College of Earth, Ocean, and Atmospheric Sciences Oregon State University 104 CEOAS Admin Bldg Announcement College of Earth, Ocean, and Atmospheric Sciences Posting 0012926 ASSISTANT PROFESSOR, Earth Systems History The College of Earth, Ocean, and Atmospheric Sciences (CEOAS) at Oregon State University

474

Radon-222 Daughter Concentrations in Uranium Mine Atmospheres  

Science Journals Connector (OSTI)

... undertaken to measure the concentrations of 210Pb and 210Po in uranium mine atmospheres at various radon daughter concentration levels, and to determine the amount of 210Pb in the mine atmosphere ... atmosphere relative to that which would be produced from the decay of the short-lived radon daughters deposited in the lungs. Radium-226 was also measured in air so as ...

RICHARD L. BLANCHARD

1969-07-19T23:59:59.000Z

475

Falsification Of The Atmospheric CO2 Greenhouse Effects  

E-Print Network (OSTI)

Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3 Contents Abstract 2 1 Introduction 6 1.1 Problem background

Learned, John

476

Singular Vector Analysis for Atmospheric Chemical Transport Models  

E-Print Network (OSTI)

are presented for a simulation of atmospheric pollution in East Asia in March 2001. The singular valuesSingular Vector Analysis for Atmospheric Chemical Transport Models Wenyuan Liao and Adrian Sandu for atmospheric chemical transport models. The distinguishing feature of these models is the presence of stiff

Sandu, Adrian

477

AT631, Spring 2011 Introduction to Atmospheric Aerosols  

E-Print Network (OSTI)

. Pandis, Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, Wiley-Interscience, 2006AT631, Spring 2011 Introduction to Atmospheric Aerosols Tuesdays 9-9:50 AM, 212B ACRC Wednesdays, Lab, 1-4 PM, ACB 10 Instructor: Prof. Sonia Kreidenweis Atmospheric Chemistry Bldg., Room 19 491

478

Targeted Observations for Atmospheric Chemistry and Transport Models  

E-Print Network (OSTI)

for a simulation of atmospheric pollution in East Asia in March 2001 show that the optimal location of observations, targeted observations. 1 Introduction Our ability to anticipate and manage changes in atmospheric pollutantTargeted Observations for Atmospheric Chemistry and Transport Models Adrian Sandu Department

Sandu, Adrian

479

High-resolution terahertz atmospheric water vapor continuum measurements  

E-Print Network (OSTI)

High-resolution terahertz atmospheric water vapor continuum measurements David M. Slocum,* Thomas M such as pollution monitoring and the detection of energetic chemicals using remote sensing over long path lengths through the atmosphere. Although there has been much attention to atmospheric effects over narrow

Massachusetts at Lowell, University of

480

European Atmospheric Pollution Imported by Cooler Air Masses to  

E-Print Network (OSTI)

European Atmospheric Pollution Imported by Cooler Air Masses to the Eastern Mediterranean during of European pollution are observed in the atmosphere (74 ( 13%). On the other hand, when the Persian Trough). This study demonstrates that atmospheric pollution over the East Mediterranean region during the summer

Einat, Aharonov

Note: This page contains sample records for the topic "atmospheric nitrous oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Science DMZ National Oceanic and Atmospheric Administration  

NLE Websites -- All DOE Office Websites (Extended Search)

NOAA NOAA About ESnet Overview ESnet Staff Governance Our Network Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ CU Science DMZ Penn State & VTTI Science DMZ NOAA Science DMZ NERSC Science DMZ ALS Multi-facility Workflow LCLS ESnet Strategic Plan ESnet Organizational Chart ESnet History Science Requirements Careers Contact Us Technical Assistance: 1 800-33-ESnet (Inside the US) 1 800-333-7638 (Inside the US) 1 510-486-7600 (Globally) 1 510-486-7607 (Globally) Report Network Problems: trouble@es.net Provide Web Site Feedback: info@es.net Science DMZ National Oceanic and Atmospheric Administration The National Oceanic and Atmospheric Administration (NOAA) in Boulder houses the Earth System Research Lab, which supports a "reforecasting" project. The initiative involves running several decades of historical

482

Atmospheric Measurements of Climate-Relevant Species  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Measurements of Climate-Relevant Species Atmospheric Measurements of Climate-Relevant Species CDIAC's data collection includes measurements of the following climate-relevant chemical species. A summary of recent greenhouse gas concentrations is also available. To determine how compounds are named, see the CDIAC "Name that compound" page. Butane (C4H10) Carbon Dioxide (CO2) Carbon Isotopes Carbon Monoxide (CO) Carbon Tetrachloride (CCl4) Chlorofluorocarbons Chloroform (CHCl3) Deuterium (2H) Ethane (C2H6) Ethyl Nitrate (C2H5ONO2) Ethyne (C2H2) Fluoroform (CHF3) Halogenated Compounds (modern records) Halons (fluorocarbons) Hydrogen (H2) Hydrochlorofluorocarbons (HCFCs) Hydrofluorocarbons (HFCs) i-Propyl Nitrate (C3H7ONO2) Methane (CH4) Methyl Bromide (CH3Br) Methyl Chloride (CH3Cl) Methyl Chloroform (CH3CCl3)

483

ORISE: Capabilities in Climate and Atmospheric Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Capabilities Capabilities ORISE partners with NOAA to operate climate monitoring network U.S. Climate Reference Network (CRN) station in Hawaii The U.S. Climate Reference Network (CRN) consists of 121 stations throughout the continental U.S., Alaska, Hawaii and Canada. The stations use highly accurate and reliable sensors and gauges to measure temperature, wind speed and precipitation. The network allows scientists to study the climate of an area over sustained periods, from 50 to 100 years. Pictured here is a CRN station at the Mauna Loa Slope Observatory in Hawaii. The Oak Ridge Institute for Science and Education (ORISE) works closely with the National Oceanic and Atmospheric Administration's (NOAA) Atmospheric Turbulence and Diffusion Division (ATDD) to perform lower

484

Atmospheric Dispersion Modeling in Safety Analyses; GENII  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Workshop to Discuss Issues Regarding Deposition Workshop to Discuss Issues Regarding Deposition Velocity June 5-6, 2012 Jeremy Rishel Bruce Napier Atmospheric Dispersion Modeling in Safety Analyses: GENII Today's Presentation.... Will provide a high-level overview of the GENII codes. Will cover basic aspects of GENII's acute atmospheric transport model. Will review the GENII deposition model that is used to estimate the deposition velocity used in plume depletion. 2 GENII Development History 1988 - GENII V1 released ICRP-26/30/48 dosimetry 1990 - GENII V1.485 stabilized Current DOE Toolbox Version 1992 - GENII-S stochastic version 2004 - GENII V2 ICRP-72 age-dependent dosimetry Federal Guidance Report 13 risk factors

485

Parallel computing in atmospheric chemistry models  

SciTech Connect

Studies of atmospheric chemistry are of high scientific interest, involve computations that are complex and intense, and require enormous amounts of I/O. Current supercomputer computational capabilities are limiting the studies of stratospheric and tropospheric chemistry and will certainly not be able to handle the upcoming coupled chemistry/climate models. To enable such calculations, the authors have developed a computing framework that allows computations on a wide range of computational platforms, including massively parallel machines. Because of the fast paced changes in this field, the modeling framework and scientific modules have been developed to be highly portable and efficient. Here, the authors present the important features of the framework and focus on the atmospheric chemistry module, named IMPACT, and its capabilities. Applications of IMPACT to aircraft studies will be presented.

Rotman, D. [Lawrence Livermore National Lab., CA (United States). Atmospheric Sciences Div.

1996-02-01T23:59:59.000Z

486

Atmospheres and radiating surfaces of neutron stars  

E-Print Network (OSTI)

The beginning of the 21st century was marked by a breakthrough in the studies of thermal radiation of neutron stars. Observations with modern space telescopes have provided a wealth of valuable information. Being correctly interpreted, this information can elucidate physics of superdense matter in the interiors of these stars. The theory of formation of thermal spectra of neutron stars is based on the physics of plasmas and radiative processes in stellar photospheres. It provides the framework for interpretation of observational data and for extracting neutron-star parameters from these data. This paper presents a review of the current state of the theory of surface layers of neutron stars and radiative processes in these layers, with the main focus on the neutron stars that possess strong magnetic fields. In addition to the conventional deep (semi-infinite) atmospheres, radiative condensed surfaces of neutron stars and "thin" (finite) atmospheres are also considered.

Potekhin, A Y

2014-01-01T23:59:59.000Z

487

Coastal Atmospheric Circulation around an Idealized Cape during Wind-Driven Upwelling Studied from a Coupled Ocean–Atmosphere Model  

Science Journals Connector (OSTI)

The study analyzes atmospheric circulation around an idealized coastal cape during summertime upwelling-favorable wind conditions simulated by a mesoscale coupled ocean–atmosphere model. The domain resembles an eastern ocean boundary with a ...

Natalie Perlin; Eric D. Skyllingstad; Roger M. Samelson

2011-03-01T23:59:59.000Z

488

Response of a Coupled Ocean–Atmosphere Model to Increasing Atmospheric Carbon Dioxide: Sensitivity to the Rate of Increase  

Science Journals Connector (OSTI)

The influence of differing rates of increase of the atmospheric CO2 concentration on the climatic response is investigated using a coupled ocean–atmosphere model. Five transient integrations are performed each using a different constant ...

Ronald J. Stouffer; Syukuro Manabe

1999-08-01T23:59:59.000Z

489

New manganese catalyst for light alkane oxidation  

DOE Patents (OSTI)

Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.

Durante, Vincent A. (West Chester, PA); Lyons, James E. (Wallingford, PA); Walker, Darrell W. (Visalia, CA); Marcus, Bonita K. (Radnor, PA)

1994-01-01T23:59:59.000Z

490

Pulsed atmospheric fluidized bed combustor apparatus  

DOE Patents (OSTI)

A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

Mansour, Momtaz N. (Columbia, MD)

1993-10-26T23:59:59.000Z

491

Atmosphere to Electrons Initiative Takes Shape  

Energy.gov (U.S. Department of Energy (DOE))

Since DOE launched its Atmosphere to Electrons (A2e) Initiative last July, the A2e executive committee has been developing a comprehensive approach for working with multiple stakeholders (industry, national laboratories, international experts, and universities) over the next 5- to 7 years. In February, they held an external merit review to lay the groundwork for an A2e multi-year strategic research plan.

492

Thomson scattering measurements in atmospheric plasma jets  

Science Journals Connector (OSTI)

Electron temperature and electron density in a dc plasma jet at atmospheric pressure have been obtained using Thomson laser scattering. Measurements performed at various scattering angles have revealed effects that are not accounted for by the standard scattering theory. Differences between the predicted and experimental results suggest that higher order corrections to the theory may be required, and that corrections to the form of the spectral density function may play an important role.

G. Gregori; J. Schein; P. Schwendinger; U. Kortshagen; J. Heberlein; E. Pfender

1999-02-01T23:59:59.000Z

493

Introduction satellite observations of atmospheric constitents have  

E-Print Network (OSTI)

%. sulphur dioxide reacts on the surface of a variety of airborne solid particles, is soluble in water and support to aviation control. Nitrogen oxides (NOx, the collective name for NO and NO2) play an important, an important greenhouse gas. The most important source of NOx is the combustion of fossil fuels, mainly

Haak, Hein

494

Atmospheric Mercury Concentrations Near Salmon Falls Creek Reservoir - Phase 1  

SciTech Connect

Elemental and reactive gaseous mercury (EGM/RGM) were measured in ambient air concentrations over a two-week period in July/August 2005 near Salmon Falls Creek Reservoir, a popular fishery located 50 km southwest of Twin Falls, Idaho. A fish consumption advisory for mercury was posted at the reservoir in 2002 by the Idaho Department of Health and Welfare. The air measurements were part of a multi-media (water, sediment, precipitation, air) study initiated by the Idaho Department of Environmental Quality and the U.S. Environmental Protection Agency (EPA) Region 10 to identify potential sources of mercury contamination to the reservoir. The sampling site is located about 150 km northeast of large gold mining operations in Nevada, which are known to emit large amounts of mercury to the atmosphere (est. 2,200 kg/y from EPA 2003 Toxic Release Inventory). The work was co-funded by the Idaho National Laboratory’s Community Assistance Program and has a secondary objective to better understand mercury inputs to the environment near the INL, which lies approximately 230 km to the northeast. Sampling results showed that both EGM and RGM concentrations were significantly elevated (~ 30 – 70%, P<0.05) compared to known regional background concentrations. Elevated short-term RGM concentrations (the primary form that deposits) were likely due to atmospheric oxidation of high EGM concentrations, which suggests that EGM loading from upwind sources could increase Hg deposition in the area. Back-trajectory analyses indicated that elevated EGM and RGM occurred when air parcels came out of north-central and northeastern Nevada. One EGM peak occurred when the air parcels came out of northwestern Utah. Background concentrations occurred when the air was from upwind locations in Idaho (both northwest and northeast). Based on 2003 EPA Toxic Release Inventory data, it is likely that most of the observed peaks were from Nevada gold mine sources. Emissions from known large natural mercury sources in that area cannot account for the observed EGM peaks due to their diffuse source geometry and the large (170 km) transport distance involved. The EGM peak originating from northwestern Utah air may be from three known mercury sources west of Salt Lake City (Kennecott, US Magnesium, Clean Harbors Aragonite) and/or the 1600 MW coal-fired Intermountain Power plant near Delta. However, the relative importance of these short-term peaks for long-term watershed mercury loading (critical factor affecting fish concentrations) is not known, and there is a need to better quantify the annual frequency and magnitude of these different inputs over a longer period of time.

M. L. Abbott

2005-10-01T23:59:59.000Z

495

Free Floating Atmospheric Pressure Ball Plasmas  

NLE Websites -- All DOE Office Websites (Extended Search)

Free-Floating Atmospheric Pressure Ball Plasmas Free-Floating Atmospheric Pressure Ball Plasmas G. A. Wurden, Z. Wang, C. Ticos Los Alamos National Laboratory L Al NM 87545 USA Los Alamos, NM 87545 USA C. J. v. Wurden Los Alamos High School L Al NM 87544 Los Alamos, NM 87544 Presented at the PPPL Colloquium Sept. 17, 2008 U N C L A S S I F I E D Operated by the Los Alamos National Security, LLC for the DOE/NNSA LA-UR-08-06284 Outline of this talk *A discussion of ball lightning reports in nature *How can ball plasmas be made in the laboratory? *Detailed experiments on long lived free floating *Detailed experiments on long-lived free-floating atmospheric pressure ball plasmas C i f l b b ll l i h "b ll *Comparison of laboratory ball plasmas with "ball lightning" *Summary U N C L A S S I F I E D Operated by the Los Alamos National Security, LLC for the DOE/NNSA

496

Atmospheric and combustion chemistry of dimethyl ether  

SciTech Connect

It has been demonstrated that dimethyl ether (DME) is an ideal diesel fuel alternative. DME, CH{sub 3}OCH{sub 3}, combines good fuel properties with low exhaust emissions and low combustion noise. Large scale production of this fuel can take place using a single step catalytic process converting CH{sub 4} to DME. The fate of DME in the atmosphere has previously been studied. The atmospheric degradation is initiated by the reaction with hydroxyl radicals, which is also a common feature of combustion processes. Spectrokinetic investigations and product analysis were used to demonstrate that the intermediate oxy radical, CH{sub 3}OCH{sub 2}O, exhibits a novel reaction pathway of hydrogen atom ejection. The application of tandem mass spectrometry to chemi-ions based on supersonic molecular beam sampling has recently been demonstrated. The highly reactive ionic intermediates are sampled directly from the flame and identified by collision activation mass spectrometry and ion-molecule reactions. The mass spectrum reflects the distribution of the intermediates in the flame. The atmospheric degradation of DME as well as the unique fuel properties of a oxygen containing compound will be discussed.

Nielsen, O.J.; Egsgaard, H.; Larsen, E.; Sehested, J. [Risoe National Lab., Roskilde (Denmark); Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States)

1997-12-31T23:59:59.000Z

497

The atmospheric reactivity of. alpha. -methyltetrahydrofuran  

SciTech Connect

Biomass-derived {alpha}-methyltetrahydrofuran (MTHF) has been proposed as an automotive fuel additive. Since MTHF is a volatile organic compound, the environmental impact of evaporation to the atmosphere needs to be considered. The major loss process of MTHF in the atmosphere is expected to occur via reaction with hydroxyl radical; hence we have conducted a study of the kinetics of the reaction OH + MTHF {yields} products using both absolute (flash photolysis resonance fluorescence) and relative rate techniques. The absolute rate experiments were performed over the temperature range 240-400 K at total pressures of 35 Torr (4.7 kPa) argon; the relative rate experiments were conducted at 295 K in 740 Torr (99 kPa) synthetic air. The results from both techniques were in good agreement and yield k{sub 1} = (2.52 {plus minus} 0.74) {times} 10{sup {minus}12} exp-((650 {plus minus} 80)/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, with k{sub 1} (298 K) = 2.2 {times} 10{sup {minus}11} cm{sup 3} molecule{sup {minus}1}. The implications of these results for the atmospheric chemistry of MTHF are discussed.

Wallington, T.J.; Siegl, W.O. (Ford Motor Company, Dearborn, MI (USA)); Liu, Renzhang; Zhang, Zhengyu; Huie, R.E.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1990-10-01T23:59:59.000Z

498

Extraction of Freshwater and Energy from Atmosphere  

E-Print Network (OSTI)

Author offers and researches a new, cheap method for the extraction of freshwater from the Earth atmosphere. The suggected method is fundamentally dictinct from all existing methods that extract freshwater from air. All other industrial methods extract water from a saline water source (in most cases from seawater). This new method may be used at any point in the Earth except Polar Zones. It does not require long-distance freshwater transportation. If seawater is not utilized for increasing its productivity, this inexpensive new method is very environment-friendly. The author method has two working versions: (1) the first variant the warm (hot) atmospheric air is lifted by the inflatable tube in a high altitude and atmospheric steam is condenced into freswater: (2) in the second version, the warm air is pumped 20-30 meters under the sea-surface. In the first version, wind and solar heating of air are used for causing air flow. In version (2) wind and propeller are used for causing air movment. The first method...

Bolonkin, Alexander

2007-01-01T23:59:59.000Z

499

Lightning, atmospheric electricity and climate change  

SciTech Connect

Temperature records indicate that a global warming of 0.5{minus}0.7{degrees}C has occurred over the past century (Hansen and Lebedeff, 1987). Whether this trend is a result of increased trace gas concentrations in the atmosphere, or simply a result of natural variability; is still not known. These temperature trends are derived from thousands of observations worldwide. However, these observations are concentrated largely over continental areas, and then mainly in the northern hemisphere`s populated regions. This northern hemisphere continental bias results in large uncertainties in estimates of global temperature trends. Due to the increasing evidence that the present buildup of greenhouse gases in the atmosphere may result in an additional global warming of 1-5{degrees}C by the year 2050 (IPCC, 1990), it is increasingly important to find afternative methods to monitor fluctuations in global surface temperatures. As shown by two recent studies (Williams, 1992; Price, 1993), the global atmospheric electric circuit may provide a promising afternative for monitoring future climate change.

Price, C.

1993-10-01T23:59:59.000Z

500

IONIZATION OF EXTRASOLAR GIANT PLANET ATMOSPHERES  

SciTech Connect

Many extrasolar planets orbit close in and are subject to intense ionizing radiation from their host stars. Therefore, we expect them to have strong, and extended, ionospheres. Ionospheres are important because they modulate escape in the upper atmosphere and can modify circulation, as well as leave their signatures, in the lower atmosphere. In this paper, we evaluate the vertical location Z{sub I} and extent D{sub I} of the EUV ionization peak layer. We find that Z{sub I{approx}}1-10 nbar-for a wide range of orbital distances (a = 0.047-1 AU) from the host star-and D{sub I}/H{sub p{approx}}>15, where H{sub p} is the pressure scale height. At Z{sub I}, the plasma frequency is {approx}80-450 MHz, depending on a. We also study global ion transport, and its dependence on a, using a three-dimensional thermosphere-ionosphere model. On tidally synchronized planets with weak intrinsic magnetic fields, our model shows only a small, but discernible, difference in electron density from the dayside to the nightside ({approx}9 x 10{sup 13} m{sup -3} to {approx}2 x 10{sup 12} m{sup -3}, respectively) at Z{sub I}. On asynchronous planets, the distribution is essentially uniform. These results have consequences for hydrodynamic modeling of the atmospheres of close-in extrasolar giant planets.

Koskinen, Tommi T. [Lunar and Planetary Laboratory, University of Arizona, 1629 E. University Blvd., Tucson, AZ (United States); Cho, James Y-K. [Astronomy Unit, School of Mathematical Sciences, Queen Mary, University of London, Mile End Road, London E1 4NS (United Kingdom); Achilleos, Nicholas; Aylward, Alan D., E-mail: tommi@lpl.arizona.ed [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

2010-10-10T23:59:59.000Z