National Library of Energy BETA

Sample records for atmospheric moisture rh

  1. ARM - Measurement - Atmospheric moisture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    moisture ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric moisture The moisture content of the air as indicated by several measurements including relative humidity, specific humidity, dewpoint, vapor pressure, water vapor mixing ratio, and water vapor density; note that precipitable water is a separate type. Categories Atmospheric State Instruments The above measurement is considered

  2. The role of moisture transport between ground and atmosphere in global change

    SciTech Connect (OSTI)

    Rind, D.; Rosenzweig, C.; Stieglitz, M.

    1997-12-31

    Projections of the effect of climate change on future water availability are examined by reviewing the formulations used to calculate moisture transport between the ground and the atmosphere. General circulation models and climate change impact models have substantially different formulations for evapotranspiration, so their projections of future water availability often disagree, even though they use the same temperature and precipitation forecasts. General circulation models forecast little change in tropical and subtropical water availability, while impact models show severe water and agricultural shortages. A comparison of observations and modeling techniques shows that the parameterizations in general circulation models likely lead to an underestimate of the impacts of global warming on soil moisture and vegetation. Such errors would crucially affect the temperature and precipitation forecasts used in impact models. Some impact model evaporation formulations are probably more appropriate than those in general circulation models, but important questions remain. More observations are needed, especially in the vicinity of forests, to determine appropriate parameterizations.

  3. Response of the regional water cycle to an increase of atmosphere moisture related to global warming

    SciTech Connect (OSTI)

    Frei, C.; Widmann, M.; Luethi, D.

    1997-11-01

    This study examines the sensitivity of the mid-latitude regional hydrological cycle to an imposed warming. Mesoscale limited-area climate simulations over Europe are performed. The modelling study is complemented with a detailed analysis of the observed precipitation and circulation trends in the same region. It is demonstrated that an increase of the moisture content leads to an enhancement of the model`s water cycle during the synoptically active seasons. The simulations suggest that this mechanism may contribute towards an increase in mean precipitation and more frequency occurrence of heavy precipitation events. Observational analysis results illustrate that the relationship between precipitation and atmospheric moisture seen in the climate simulations constitutes a possible physical mechanism relevant for the interpretation of the observed trends. A key feature of the model results is the pronounced increase in the frequency of strong precipitation events associated with the intensification of the water cycle. This large sensitivity highlights the vulnerability of the precipitation climate with respect to global climate change. 19 refs., 2 figs., 1 tab.

  4. International H2O Project (IHOP) 2002: Datasets Related to Atmospheric Moisture and Rainfall Prediction

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schanot, Allen [IHOP 2002 PI; Friesen, Dick [IHOP 2002 PI

    IHOP 2002 was a field experiment that took place over the Southern Great Plains of the United States from 13 May to 25 June 2002. The chief aim of IHOP_2002 was improved characterization of the four-dimensional (4-D) distribution of water vapor and its application to improving the understanding and prediction of convection. The region was an optimal location due to existing experimental and operational facilities, strong variability in moisture, and active convection [copied from http://www.eol.ucar.edu/projects/ihop/]. The project's master list of data identifies 146 publicly accessible datasets.

  5. Radiosondes Corrected for Inaccuracy in RH Measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miloshevich, Larry

    2008-01-15

    Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and therefore the correction magnitude, is a function of atmospheric conditions, mainly T, RH, and dRH/dt (humidity gradient). The corrections are also very sensitive to the RH sensor type, and there are 3 Vaisala sensor types represented in this dataset (RS80-H, RS90, and RS92). Depending on the sensor type and the radiosonde production date, one or more of the following three corrections were applied to the RH data: Temperature-Dependence correction (TD), Contamination-Dry Bias correction (C), Time Lag correction (TL). The estimated absolute accuracy of NIGHTTIME corrected and uncorrected Vaisala RH measurements, as determined by comparison to simultaneous reference-quality measurements from Holger Voemel's (CU/CIRES) cryogenic frostpoint hygrometer (CFH), is given by Miloshevich et al. (2006).

  6. RH TRU Waste Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remote-Handled Transuranic Waste Program After seven years and more than 5,000 safe shipments of contact-handled (CH) transuranic (TRU) waste, the Waste Isolation Pilot Plant is now also receiving remote-handled (RH) TRU waste. In October 2006, the New Mexico Environment Department (NMED) approved the U.S. Department of Energy's plans for disposal of RH-TRU waste at WIPP. The Environmental Protection Agency (EPA) gave its approval in 2004. Located in the remote desert of southeastern New Mexico,

  7. 15.11.21 RH Methanol - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Highlights 2.01.16 RH Plasmonics 06.01.16 BVO 15.12.04 RH Motifs 15.12.04 RH Screening 15.12.03 RH Assembly 15.11.21 RH Methanol 15.10.5 RH ECS Atwater 15.09.28 RH Bandgap Tunability 15.08.28 RH Novel Photoanodes 15.08.07 RH Si Microwire Photoanode 15.07.15 RH Interface Engineering 15.07.10 RH P-type Transparent 15.05.29 RH Operando X-ray 15.03.03 RH Fe Elecrolyte 15.01.16 RH Perovskite Solar Cells 15.02.10 RH Transparent Catalytic 14.05.14 RH Synchrotron X-ray 15.01.05 RH High OER

  8. 15.12.04 RH Screening - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Highlights 2.01.16 RH Plasmonics 06.01.16 BVO 15.12.04 RH Motifs 15.12.04 RH Screening 15.12.03 RH Assembly 15.11.21 RH Methanol 15.10.5 RH ECS Atwater 15.09.28 RH Bandgap Tunability 15.08.28 RH Novel Photoanodes 15.08.07 RH Si Microwire Photoanode 15.07.15 RH Interface Engineering 15.07.10 RH P-type Transparent 15.05.29 RH Operando X-ray 15.03.03 RH Fe Elecrolyte 15.01.16 RH Perovskite Solar Cells 15.02.10 RH Transparent Catalytic 14.05.14 RH Synchrotron X-ray 15.01.05 RH High OER

  9. 2.01.16 RH Plasmonics - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Highlights 2.01.16 RH Plasmonics 06.01.16 BVO 15.12.04 RH Motifs 15.12.04 RH Screening 15.12.03 RH Assembly 15.11.21 RH Methanol 15.10.5 RH ECS Atwater 15.09.28 RH Bandgap Tunability 15.08.28 RH Novel Photoanodes 15.08.07 RH Si Microwire Photoanode 15.07.15 RH Interface Engineering 15.07.10 RH P-type Transparent 15.05.29 RH Operando X-ray 15.03.03 RH Fe Elecrolyte 15.01.16 RH Perovskite Solar Cells 15.02.10 RH Transparent Catalytic 14.05.14 RH Synchrotron X-ray 15.01.05 RH High OER

  10. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2008-01-12

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package (also known as the "RH-TRU 72-B cask") and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) 71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  11. RH-TRU Waste Content Codes (RH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-08-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is 3. The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  12. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-11-07

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 Code of Federal Regulations (CFR) 71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  13. RH-TRU Waste Content Codes (RH TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-05-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is 3. The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code.

  14. Analysis of Joint Masonry Moisture Content Monitoring

    SciTech Connect (OSTI)

    Ueno, Kohta

    2015-10-01

    Adding insulation to the interior side of walls of masonry buildings in cold (and wet) climates may cause performance and durability problems. Some concerns, such as condensation and freeze-thaw, have known solutions, but wood members embedded in the masonry structure will be colder (and potentially wetter) after an interior insulation retrofit. Moisture content & relative humidity were monitored at joist ends in historic mass brick masonry walls retrofitted with interior insulation in a cold climate (Zone 5A); data were collected from 2012-2015. Eleven joist ends were monitored in all four orientations. One limitation of these results is that the renovation is still ongoing, with limited wintertime construction heating and no permanent occupancy to date. Measurements show that many joists ends remain at high moisture contents, especially at north- and east-facing orientations, with constant 100% RH conditions at the worst cases. These high moisture levels are not conducive for wood durability, but no evidence for actual structural damage has been observed. Insulated versus non-insulated joist pockets do not show large differences. South facing joists have safe (10-15%) moisture contents. Given the uncertainty pointed out by research, definitive guidance on the vulnerability of embedded wood members is difficult to formulate. In high-risk situations, or when a very conservative approach is warranted, the embedded wood member condition can be eliminated entirely, supporting the joist ends outside of the masonry pocket.

  15. ARM - Measurement - Soil moisture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    moisture ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil moisture The moisture of the soil measured near the surface. This includes soil wetness and soil water potential. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  16. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Not Available

    1982-04-29

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the reusltant hydrogen.

  17. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Harrah, Larry A. (Albuquerque, NM); Mead, Keith E. (Peralta, NM); Smith, Henry M. (Overland Park, KS)

    1983-01-01

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  18. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Harrah, L.A.; Mead, K.E.; Smith, H.M.

    1983-09-20

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (1) a solid acetylenic compound and (2) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  19. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  20. Moisture Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weatherize » Moisture Control Moisture Control Controlling moisture can make your home more energy-efficient, less costly to heat and cool, more comfortable, and prevent mold growth. Controlling moisture can make your home more energy-efficient, less costly to heat and cool, more comfortable, and prevent mold growth. Properly controlling moisture in your home will improve the effectiveness of your air sealing and insulation efforts, and these efforts in turn will help control moisture. The best

  1. Moisture Control | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    of your air sealing and insulation efforts, and these efforts in turn will help control moisture. The best strategies for controlling moisture in your home depend on your...

  2. RH-TRU Waste Content Codes

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-07-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is 3. The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  3. Fiber optic moisture sensor

    DOE Patents [OSTI]

    Kirkham, R.R.

    1984-08-03

    A method and apparatus for sensing moisture changes by utilizing optical fiber technology. One embodiment uses a reflective target at the end of an optical fiber. The reflectance of the target varies with its moisture content and can be detected by a remote unit at the opposite end of the fiber. A second embodiment utilizes changes in light loss along the fiber length. This can be attributed to changes in reflectance of cladding material as a function of its moisture content. It can also be affected by holes or inserts interposed in the cladding material and/or fiber. Changing light levels can also be coupled from one fiber to another in an assembly of fibers as a function of varying moisture content in their overlapping lengths of cladding material.

  4. Practical Considerations of Moisture in Baled Biomass Feedstocks

    SciTech Connect (OSTI)

    William A. Smith; Ian J. Bonner; Kevin L. Kenney; Lynn M. Wendt

    2013-01-01

    Agricultural residues make up a large portion of the immediately available biomass feedstock for renewable energy markets. Current collection and storage methods rely on existing feed and forage practices designed to preserve nutrients and properties of digestibility. Low-cost collection and storage practices that preserve carbohydrates across a range of inbound moisture contents are needed to assure the economic and technical success of the emerging biomass industry. This study examines the movement of moisture in storage and identifies patterns of migration resulting from several on-farm storage systems and their impacts on moisture measurement and dry matter recovery. Baled corn stover and energy sorghum were stored outdoors in uncovered, tarp-covered, or wrapped stacks and sampled periodically to measure moisture and dry matter losses. Interpolation between discrete sampling locations in the stack improved bulk moisture content estimates and showed clear patterns of accumulation and re-deposition. Atmospheric exposure, orientation, and contact with barriers (i.e., soil, tarp, and wrap surfaces) were found to cause the greatest amount of moisture heterogeneity within stacks. Although the bulk moisture content of many stacks remained in the range suitable for aerobic stability, regions of high moisture were sufficient to support microbial activity, thus support dry matter loss. Stack configuration, orientation, and coverage methods are discussed relative to impact on moisture management and dry matter preservation. Additionally, sample collection and data analysis are discussed relative to assessment at the biorefinery as it pertains to stability in storage, queuing, and moisture carried into processing.

  5. Check for chirality in {sup 102}Rh

    SciTech Connect (OSTI)

    Tonev, D.; Goutev, N.; Yavahchova, M. S.; Petkov, P.; Angelis, G. de; Bhowmik, R. K.; Singh, R. P.; Muralithar, S.; Madhavan, N.; Kumar, R.; Raju, M. Kumar; Kaur, J.; Mahanto, G.; Singh, A.; Kaur, N.; Garg, R.; Sukla, A.; Marinov, Ts. K.; Brant, S.

    2012-10-20

    Excited states in {sup 102}Rh, populated by the fusion-evaporation reaction {sup 94}Zr({sup 11}B,3n){sup 102}Rh at a beam energy of 36 MeV, were studied using the INGA spectrometer at IUAC, New Delhi. The angular correlations and the electromagnetic character of some of the gamma-ray transitions observed were investigated in details. A new chiral candidate sister band was found in the level-scheme of {sup 102}Rh. Lifetimes of exited states in {sup 102}Rh were measured by means of the Doppler-shift attenuation technique. The experimental results do not support the presence of static chirality in {sup 102}Rh.

  6. Analysis of Joist Masonry Moisture Content Monitoring

    SciTech Connect (OSTI)

    Ueno, Kohta

    2015-10-08

    There are many existing buildings with load-bearing mass masonry walls, whose energy performance could be improved with the retrofit of insulation. However, adding insulation to the interior side of walls of such masonry buildings in cold (and wet) climates may cause performance and durability problems. Some concerns, such as condensation and freeze-thaw have known solutions. But wood members embedded in the masonry structure will be colder (and potentially wetter) after an interior insulation retrofit. Moisture content & relative humidity were monitored at joist ends in historic mass brick masonry walls retrofitted with interior insulation in a cold climate (Zone 5A); data were collected from 2012-2015. Eleven joist ends were monitored in all four orientations. One limitation of these results is that the renovation is still ongoing, with limited wintertime construction heating and no permanent occupancy to date. Measurements show that many joists ends remain at high moisture contents, especially at north- and east-facing orientations, with constant 100% RH conditions at the worst cases. These high moisture levels are not conducive for wood durability, but no evidence for actual structural damage has been observed. Insulated vs. non-insulated joist pockets do not show large differences. South facing joists have safe (10-15%) moisture contents. Given the uncertainty pointed out by research, definitive guidance on the vulnerability of embedded wood members is difficult to formulate. In high-risk situations, or when a very conservative approach is warranted, the embedded wood member condition can be eliminated entirely, supporting the joist ends outside of the masonry pocket.

  7. Multilayer moisture barrier

    DOE Patents [OSTI]

    Pankow, Joel W; Jorgensen, Gary J; Terwilliger, Kent M; Glick, Stephen H; Isomaki, Nora; Harkonen, Kari; Turkulainen, Tommy

    2015-04-21

    A moisture barrier, device or product having a moisture barrier or a method of fabricating a moisture barrier having at least a polymer layer, and interfacial layer, and a barrier layer. The polymer layer may be fabricated from any suitable polymer including, but not limited to, fluoropolymers such as polyethylene terephthalate (PET) or polyethylene naphthalate (PEN), or ethylene-tetrafluoroethylene (ETFE). The interfacial layer may be formed by atomic layer deposition (ALD). In embodiments featuring an ALD interfacial layer, the deposited interfacial substance may be, but is not limited to, Al.sub.2O.sub.3, AlSiO.sub.x, TiO.sub.2, and an Al.sub.2O.sub.3/TiO.sub.2 laminate. The barrier layer associated with the interfacial layer may be deposited by plasma enhanced chemical vapor deposition (PECVD). The barrier layer may be a SiO.sub.xN.sub.y film.

  8. Moisture Barrier - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search Moisture Barrier National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Moisture barriers serve as a robust packaging solution to enclose moisture sensitive encapsulated materials. They enable a device, product, substrate, or apparatus which in use will be exposed to moisture, water vapor, freeze thaw cycles or other environmental elements

  9. ARM - Measurement - Soil moisture flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    moisture flux ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil moisture flux A quantity measured according to the formula B = {lambda}(dq/dz), where {lambda} is the conductivity of the soil that the moisture is moving through. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file

  10. Soil Density/Moisture Gauge

    Broader source: Energy.gov [DOE]

    This scenario provides the planning instructions, guidance, and evaluation forms necessary to conduct an exercise involving a highway shipment of a soil moisture/density gauge (Class 7 -...

  11. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, O.A.; Stencel, J.R.

    1987-10-02

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The moisture then passes through a combustion chamber where hydrogen gas in the form of H/sub 2/ or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  12. Fiber optic moisture sensor with moisture-absorbing reflective target

    DOE Patents [OSTI]

    Kirkham, Randy R. (Richland, WA)

    1987-01-01

    A method and apparatus for sensing moisture changes by utilizing optical fiber technology. One embodiment uses a reflective target at the end of an optical fiber. The reflectance of the target varies with its moisture content and can be detected by a remote unit at the opposite end of the fiber. A second embodiment utilizes changes in light loss along the fiber length. This can be attributed to changes in reflectance of cladding material as a function of its moisture content. It can also be affected by holes or inserts interposed in the cladding material and/or fiber. Changing light levels can also be coupled from one fiber to another in an assembly of fibers as a function of varying moisture content in their overlapping lengths of cladding material.

  13. Hybridized Nature of Pseudogap in Kondo Insulators CeRhSb and CeRhAs

    SciTech Connect (OSTI)

    Kumigashira, H.; Takahashi, T.; Yoshii, S.; Kasaya, M.

    2001-08-06

    We studied the electronic structure of Kondo insulators CeRhSb and CeRhAs using high-resolution photoemission spectroscopy. We found that the 4f -derived density of states shows a depletion (pseudogap) at E{sub F} in contrast to metallic Kondo materials. It was found that the size of the f pseudogap is smaller than that of conduction electrons (c pseudogap) while both scale well with the Kondo temperature. The present results indicate that the hybridization between 4f and conduction electrons near E{sub F} is essential for the Kondo gap in the Ce-based compounds.

  14. ARM - PI Product - Radiosondes Corrected for Inaccuracy in RH Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsRadiosondes Corrected for Inaccuracy in RH Measurements ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Radiosondes Corrected for Inaccuracy in RH Measurements Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and

  15. Chemical and Morphological Evolution of Nanoporous Pd/Rh Alloy...

    Office of Scientific and Technical Information (OSTI)

    Conference: Chemical and Morphological Evolution of Nanoporous PdRh Alloy Particles for ... Country of Publication: United States Language: English Word Cloud More Like This Full ...

  16. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, Otto A. (Langhorne, PA); Stencel, Joseph R. (Skillman, NJ)

    1990-01-01

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The mixture then passes through a combustion chamber where hydrogen gas in the form of H.sub.2 or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  17. Wet buildings: A moisture primer

    SciTech Connect (OSTI)

    Lotz, W.A.

    1998-01-01

    This article will attempt to clarify the various issues that must be solved when investigating the cause of a building moisture problem. Several classic errors that result in mechanical engineers and contractors defending themselves in lawsuits will be reviewed. Moisture from internal and external sources is the most frequent cause of building problems and subsequent legal action. Many reported roof leaks are, in reality, condensation problems that have nothing to do with the roofing contractor. Mechanical design engineers need to work closely with the building owner, architect, and contractors to insure a dry, durable building. The first issue to examine is if the moisture is coming from the outside--i.e. rain. Other leaks discussed are ice dams, groundwater leaks, and roof leaks. Also discussed are vapor barriers, continuity of insulation, humidification chilled water, warehouses, trash plants, indoor pools, and hot or humid climates.

  18. Moisture Research - Optimizing Wall Assemblies

    SciTech Connect (OSTI)

    Arena, L.; Mantha, P.

    2013-05-01

    The Consortium for Advanced Residential Buildings (CARB) evaluated several different configurations of wall assemblies to determine the accuracy of moisture modeling and make recommendations to ensure durable, efficient assemblies. WUFI and THERM were used to model the hygrothermal and heat transfer characteristics of these walls.

  19. Investigation of SGP Atmospheric Moisture Budget for CLASIC ?...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Budget for CLASIC - Recycling Study Contributors Peter Lamb, Diane Portis, Daniel Hartsock Background * Motivation: to provide larger-scale background for the interpretation of...

  20. Atmospheric Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    competencies Atmospheric Chemistry Atmospheric Chemistry is the study of the composition of the atmosphere, the sources and fates of gases and particles in air, and changes induced...

  1. Ethanol Oxidation on the Ternary PtRhSnO2/C Electrocatalysts with Varied Pt:Rh:Sn ratios

    SciTech Connect (OSTI)

    Adzic, R.R.; Li, M.; Kowal, A.; Sasaki, K.; Marinkovic, N.; Su, D.; Korach, E.; Liu, P.

    2010-05-30

    Ternary Pt-Rh-SnO{sub 2}/C electrocatalysts with the atomic ratio Pt:Rh:Sn = 3:1:x, where x varies from 2 to 6, were synthesized using the modified polyol method followed by thermal treatment. Several techniques used to characterize these electrocatalysts showed they were composed of homogeneous PtRh alloy and SnO{sub 2}, having all three constituents coexisting in single nanoparticles with the average particle size around 1.4 nm and a narrow size distribution. While all the electrocatalysts investigated exhibited high catalytic activity for ethanol oxidation, the most active one had the composition with the Pt:Rh:Sn = 3:1:4 atomic ratio. These ternary-electrocatalysts effectively split the C-C bond in ethanol at room temperature in acidic solutions, which is verified using the in situ IRRAS technique.

  2. Moisture Research - Optimizing Wall Assemblies

    SciTech Connect (OSTI)

    Arena, Lois; Mantha, Pallavi

    2013-05-01

    In this project, the Consortium for Advanced Residential Buildings (CARB) team evaluated several different configurations of wall assemblies to determine the accuracy of moisture modeling and make recommendations to ensure durable, efficient assemblies. WUFI and THERM were used to model the hygrothermal and heat transfer characteristics of these walls. Wall assemblies evaluated included code minimum walls using spray foam insulation and fiberglass batts, high R-value walls at least 12 in. thick (R-40 and R-60 assemblies), and brick walls with interior insulation.

  3. The Nature of the First Order Isostructural Transition in GdRhSn...

    Office of Scientific and Technical Information (OSTI)

    The Nature of the First Order Isostructural Transition in GdRhSn Citation Details In-Document Search Title: The Nature of the First Order Isostructural Transition in GdRhSn...

  4. Position Paper for High Moisture Content Waste

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for High Moisture Content Waste Revision 0, November 3, 1998 Prepared by: Nevada Test Site Generator Work Group High Moisture Content Waste Subgroup EXECUTIVE SUMMARY During the 1995 Annual Waste Generator Workshop, discussions were held regarding several areas of concern to waste generators currently shipping Low Level Waste to the Nevada Test Site. A goal to resolving these areas of concern was the establishment of an NVO-325 Work Group. In January of 1996 the NVO-325 Work Group was formalized

  5. Superconductivity versus structural phase transition in the closely related Bi2Rh3.5S2 and Bi2Rh3S2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Xie, Weiwei; Lin, Qisheng; Taufour, Valentin; Bud'ko, Sergey L.; Miller, Gordon J.; Canfield, Paul C.

    2015-05-19

    Single crystals of Bi2Rh3S2 and Bi2Rh3.5S2 were synthesized by solution growth, and the crystal structures and thermodynamic and transport properties of both compounds were studied. In the case of Bi2Rh3S2, a structural first-order transition at around 165 K is identified by single-crystal diffraction experiments, with clear signatures visible in resistivity, magnetization, and specific heat data. No superconducting transition for Bi2Rh3S2 was observed down to 0.5 K. In contrast, no structural phase transition at high temperature was observed for Bi2Rh3.5S2; however, bulk superconductivity with a critical temperature, Tc ≈ 1.7 K, was observed. The Sommerfeld coefficient γ and the Debye temperaturemore » (ΘD) were found to be 9.41 mJ mol–1K–2 and 209 K, respectively, for Bi2Rh3S2, and 22 mJ mol–1K–2 and 196 K, respectively, for Bi2Rh3.5S2. As a result, the study of the specific heat in the superconducting state of Bi2Rh3.5S2 suggests that Bi2Rh3.5S2 is a weakly coupled, BCS superconductor.« less

  6. Rh(I)-Catalyzed Direct Arylation of Pyridines and Quinolines

    SciTech Connect (OSTI)

    Berman, Ashley; Lewis, Jared; Bergman, Robert; Ellman, Jonathan

    2008-07-29

    The pyridine and quinoline nuclei are privileged scaffolds that occupy a central role in many medicinally relevant compounds. Consequently, methods for their expeditious functionalization are of immediate interest. However, despite the immense importance of transition-metal catalyzed cross-coupling for the functionalization of aromatic scaffolds, general solutions for coupling 2-pyridyl organometallics with aryl halides have only recently been presented. Direct arylation at the ortho position of pyridine would constitute an even more efficient approach because it eliminates the need for the stoichiometric preparation and isolation of 2-pyridyl organometallics. Progress towards this goal has been achieved by activation of the pyridine nucleus for arylation via conversion to the corresponding pyridine N-oxide or N-iminopyridinium ylide. However, this approach necessitates two additional steps: activation of the pyridine or quinoline starting material, and then unmasking the arylated product. The use of pyridines directly would clearly represent the ideal situation both in terms of cost and simplicity. We now wish to document our efforts in this vein, culminating in an operationally simple Rh(I)-catalyzed direct arylation of pyridines and quinolines. We recently developed an electron-rich Rh(I) system for catalytic alkylation at the ortho position of pyridines and quinolines with alkenes. Therefore, we initially focused our attention on the use of similarly electron-rich Rh(I) catalysts for the proposed direct arylation. After screening an array of electron-rich phosphine ligands and Rh(I) salts, only marginal yields (<20%) of the desired product were obtained. Much more efficient was an electron-poor Rh(I) system with [RhCl(CO){sub 2}]{sub 2} as precatalyst (Table 1). For the direct arylation of picoline with 3,5-dimethyl-bromobenzene, addition of P(OiPr){sub 3} afforded a promising 40% yield of the cross coupled product 1a (entry 1). The exclusion of phosphite additive proved even more effective, with the yield of 1a improving to 61% (entry 2). Further enhancement in yield was not observed upon the inclusion of other additives such as MgO (entry 3), various organic bases (entries 4, 5), or a protic acid source (entry 6). Absolute concentration proved very important, with the best results being obtained at relatively high concentrations of the aryl bromide (compare entries 7 and 8). A marginal improvement was observed upon running the reaction with 6 equivalents of 2-methyl pyridine (entry 9). The reaction temperature could also be increased to 175 or 190 C while maintaining reaction yield, to enable the reaction time to be reduced to 24 h (entries 10 and 11). In summary, we have developed a Rh(I)-catalyzed strategy for the direct arylation of pyridines and quinolines. The heterocycle is used without the need for prefunctionalization, and all reaction components are inexpensive and readily available. The strategy represents an expeditious route to an important class of bis(hetero)aryls and should be of broad utility.

  7. Moisture Flux Convergence in Regional and Global Climate Models: Implications for Droughts in the Southwestern United States Under Climate Change

    SciTech Connect (OSTI)

    Gao, Yanhong; Leung, Lai-Yung R.; Salathe, E.; Dominguez, Francina; Nijssen, Bart; Lettenmaier, D. P.

    2012-05-10

    The water cycle of the southwestern United States (SW) is dominated by winter storms that maintain a positive annual net precipitation. Analysis of the control and future climate from four pairs of regional and global climate models (RCMs and GCMs) shows that the RCMs simulate a higher fraction of transient eddy moisture fluxes because the hydrodynamic instabilities associated with flow over complex terrain are better resolved. Under global warming, this enables the RCMs to capture the response of transient eddies to increased atmospheric stability that allows more moisture to converge on the windward side of the mountains by blocking. As a result, RCMs simulate enhanced transient eddy moisture convergence in the SW compared to GCMs, although both robustly simulate drying due to enhanced moisture divergence by the divergent mean flow in a warmer climate. This enhanced convergence leads to reduced susceptibility to hydrological change in the RCMs compared to GCMs.

  8. Precipitation and soil impacts on partitioning of subsurface moisture in Avena barbata: Observations from a greenhouse experiment

    SciTech Connect (OSTI)

    Salve, R.; Torn, M.S.

    2011-03-01

    The primary objective of this study was to assess the impact of two grassland soils and precipitation regimes on soil-moisture dynamics. We set up an experiment in a greenhouse, and monitored soil moisture dynamics in mesocosms planted with Avena barbata, an annual species found in California grasslands. By repeating the precipitation input at regular intervals, we were able to observe plant manipulation of soil moisture during well-defined periods during the growing season. We found that the amount of water partitioned to evapotranspiration, seepage, and soil storage varied among different growth stages. Further, both soil type and precipitation regimes had a significant impact on redistributing soil moisture. Whereas in the low-precipitation treatments most water was released to the atmosphere as evapotranspiration, major losses from the high-precipitation treatment occurred as gravity drainage. Observations from this study emphasize the importance of understanding intra-seasonal relationships between vegetation, soil, and water.

  9. Distributed fiber optic moisture intrusion sensing system

    DOE Patents [OSTI]

    Weiss, Jonathan D. (Albuquerque, NM)

    2003-06-24

    Method and system for monitoring and identifying moisture intrusion in soil such as is contained in landfills housing radioactive and/or hazardous waste. The invention utilizes the principle that moist or wet soil has a higher thermal conductance than dry soil. The invention employs optical time delay reflectometry in connection with a distributed temperature sensing system together with heating means in order to identify discrete areas within a volume of soil wherein temperature is lower. According to the invention an optical element and, optionally, a heating element may be included in a cable or other similar structure and arranged in a serpentine fashion within a volume of soil to achieve efficient temperature detection across a large area or three dimensional volume of soil. Remediation, moisture countermeasures, or other responsive action may then be coordinated based on the assumption that cooler regions within a soil volume may signal moisture intrusion where those regions are located.

  10. Investigations of Possible Low-Level Temperature and Moisture Anomalies During the AMIE Field Campaign on Manus Island

    SciTech Connect (OSTI)

    Long, CN; Holdridge, DJ

    2012-11-19

    This document discusses results stemming from the investigation of near-surface temperature and moisture “oddities” that were brought to light as part of the Atmospheric Radiation Measurement (ARM) Madden-Julian Oscillation (MJO) Investigation Experiment (AMIE), Dynamics of the Madden-Julian Oscillation (DYNAMO), and Cooperative Indian Ocean experiment on intraseasonal variability in the Year 2011 (CINDY2011) campaigns.

  11. Assessment of NGNP Moisture Ingress Events

    SciTech Connect (OSTI)

    Bill Landman

    2011-04-01

    An assessment of modular HTGR moisture ingress events, making use of a phenomena identification and ranking process, was conducted by a panel of experts in the related areas for the U.S. next generation nuclear plant (NGNP) design. Consideration was given mainly to the prismatic core gas-cooled reactor configurations incorporating a steam generator within the primary circuit.

  12. Quantitative EDS Analysis of Nanometer-Scale Core/Shell Pd/Rh...

    Office of Scientific and Technical Information (OSTI)

    of Nanometer-Scale CoreShell PdRh Structures. Authors: Sugar, Joshua Daniel ; Kotula, Paul Gabriel 1 ; Robinson, David ; Cappillino, Patrick + Show Author Affiliations (Sandia...

  13. Electronic structure and magnetism of the Rh[l brace]001[r brace] surface

    SciTech Connect (OSTI)

    Wu, S.C. Physics Department, Peking University, Beijing 100871 ); Garrison, K. ); Begley, A.M.; Jona, F. ); Johnson, P.D. )

    1994-05-15

    Spin-polarized-photoemission experiments on clean Rh[l brace]001[r brace] show that the surface resonance at the [ital [bar M

  14. Microwave Synthesis of Au?Rh Core?Shell Nanoparticles and Implications...

    Office of Scientific and Technical Information (OSTI)

    Microwave Synthesis of Au?Rh Core?Shell Nanoparticles and Implications of the Shell Thickness in Hydrogenation Catalysis Citation Details In-Document Search Title: Microwave ...

  15. How do elevated [CO2], warming, and reduced precipitation interact to affect soil moisture and LAI in an old field ecosystem?

    SciTech Connect (OSTI)

    Dermody, Orla [University of Tennessee, Knoxville (UTK); Weltzin, Jake [University of Tennessee, Knoxville (UTK); Engel, Elizabeth C. [University of Tennessee, Knoxville (UTK); Allen, Phillip [University of Tennessee, Knoxville (UTK); Norby, Richard J [ORNL

    2007-01-01

    Soil moisture content and leaf area index (LAI) are properties that will be particularly important in mediating whole system responses to the combined effects of elevated atmospheric [CO2], warming and altered precipitation. Warming and drying will likely reduce soil moisture, and this effect may be exacerbated when these factors are combined. However, elevated [CO2] may increase soil moisture contents and when combined with warming and drying may partially compensate for their effects. The response of LAI to elevated [CO2] and warming will be closely tied to soil moisture status and may mitigate or exacerbate the effects of global change on soil moisture. Using open-top chambers (4-m diameter), the interactive effects of elevated [CO2], warming, and differential irrigation on soil moisture availability were examined in the OCCAM (Old-Field Community Climate and Atmospheric Manipulation) experiment at Oak Ridge National Laboratory in eastern Tennessee. Warming consistently reduced soil moisture contents and this effect was exacerbated by reduced irrigation. However, elevated [CO2] partially compensated for the effects of warming and drying on soil moisture. Changes in LAI were closely linked to soil moisture status. LAI was determined using an AccuPAR ceptometer and both the leaf area duration (LAD) and canopy size were increased by irrigation and elevated [CO2]. The climate of the southeastern United States is predicted to be warmer and drier in the future. This research suggests that although elevated [CO2] will partially ameliorate the effects of warming and drying, losses of soil moisture will increase from old field ecosystems in the future.

  16. Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings J. Woods, J. Winkler, and D. Christensen National Renewable Energy Laboratory Technical Report NREL/TP-5500-57441 January 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401

  17. Measurement of Moisture Outgassing of the Plastic-Bonded TATB...

    Office of Scientific and Technical Information (OSTI)

    Measurement of Moisture Outgassing of the Plastic-Bonded TATB Explosive LX-17 Citation Details In-Document Search Title: Measurement of Moisture Outgassing of the Plastic-Bonded...

  18. Building America Technology Solutions for New and Existing Homes: Moisture

    Energy Savers [EERE]

    Management of High-R Walls | Department of Energy Management of High-R Walls Building America Technology Solutions for New and Existing Homes: Moisture Management of High-R Walls This project by Building Science Corporation focuses on how eight high-R walls handle the three main sources of moisture-construction moisture, air leakage condensation, and bulk water leaks. PDF icon Moisture Management of High-R Walls More Documents & Publications Building America Technology Solutions for New

  19. Conquering Moisture and Humidity in Your Home | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conquering Moisture and Humidity in Your Home Conquering Moisture and Humidity in Your Home September 5, 2014 - 10:54am Addthis Moisture barriers can help reduce humidity in your home. | Photo courtesy of Dennis Schroder, National Renewable Energy Laboratory Moisture barriers can help reduce humidity in your home. | Photo courtesy of Dennis Schroder, National Renewable Energy Laboratory Paige Terlip Paige Terlip Former Communicator, National Renewable Energy Laboratory What does this mean for

  20. Technology Solutions Case Study: Moisture Management of High-Walls

    SciTech Connect (OSTI)

    2013-12-01

    Moisture management of high-R walls is important to ensure optimal performance. This case study, developed by Building America team Building Science Corporation, focuses on how eight high-R walls handle the three main sources of moistureconstruction moisture, air leakage condensation, and bulk water leaks.

  1. Modeling studies of gas movement and moisture migration at Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Tsang, Y.W.; Pruess, K. [Lawrence Berkeley Lab., CA (United States)

    1991-06-01

    Modeling studies on moisture redistribution processes that are mediated by gas phase flow and diffusion have been carried out. The problem addressed is the effect of a lowered humidity of the soil gas at the land surface on moisture removal from Yucca Mountain, the potential site for a high-level nuclear waste repository. At the land surface, humid formation gas contacts much drier atmospheric air. Near this contact, the humidity of the soil gas may be considerably lower than at greater depth, where the authors expect equilibrium with the liquid phase and close to 100% humidity. The lower relative humidity of the soil gas may be modeled by imposing, at the land surface, an additional negative capillary suction corresponding to vapor pressure lowering according to Kelvin`s Equation, thus providing a driving force for the upward movement of moisture in both the vapor and liquid phases. Sensitivity studies show that moisture removal from Yucca Mountain arising from the lowered-relative-humidity boundary condition is controlled by vapor diffusion. There is much experimental evidence in the soil literature that diffusion of vapor is enhanced due to pore-level phase change effects by a few orders of magnitude. Modeling results presented here will account for this enhancement in vapor diffusion.

  2. Process for treating moisture laden coal fines

    DOE Patents [OSTI]

    Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  3. Building-Integrated Heat & Moisture Exchange

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building-Integrated Heat & Moisture Exchange 2014 Building Technologies Office Peer Review John E. Breshears jbreshears@architecturalapplications.com Architectural Applications Project Summary Timeline: Start date: October, 2012 Planned end date: August, 2014 Key Milestones Mid- & Full-scale Lab Tests; June, 2013 Full-scale Demo; January, 2014 System Documentation; July, 2014 Budget: Total DOE $ to date: $1,037,812 Total future DOE $: $0 (committed to date) Target Market/Audience:

  4. Final Design Report for the RH LLW Disposal Facility (RDF) Project

    SciTech Connect (OSTI)

    Austad, S. L.

    2015-05-01

    The RH LLW Disposal Facility (RDF) Project was designed by AREVA Federal Services (AFS) and the design process was managed by Battelle Energy Alliance (BEA) for the Department of Energy (DOE). The final design report for the RH LLW Disposal Facility Project is a compilation of the documents and deliverables included in the facility final design.

  5. Final Design Report for the RH LLW Disposal Facility (RDF) Project

    SciTech Connect (OSTI)

    Austad, Stephanie Lee

    2015-09-01

    The RH LLW Disposal Facility (RDF) Project was designed by AREVA Federal Services (AFS) and the design process was managed by Battelle Energy Alliance (BEA) for the Department of Energy (DOE). The final design report for the RH LLW Disposal Facility Project is a compilation of the documents and deliverables included in the facility final design.

  6. Surface moisture measurement system electromagnetic induction probe calibration technique

    SciTech Connect (OSTI)

    Crowe, R.D., Westinghouse Hanford

    1996-07-08

    The Surface Moisture Measurement System (SMMS) is designed to measure the moisture concentration near the surfaces of the wastes located in the Hanford Site tank farms. This document describes a calibration methodology to demonstrate that the Electromagnetic Induction (EMI) moisture probe meets relevant requirements in the `Design Requirements Document (DRD) for the Surface Moisture Measurement System.` The primary purpose of the experimental tests described in this methodology is to make possible interpretation of EMI in-tank surface probe data to estimate the surface moisture.

  7. Towards tailoring the magnetocaloric response in FeRh-based ternary compounds

    SciTech Connect (OSTI)

    Barua, Radhika Jiménez-Villacorta, Félix; Lewis, L. H.

    2014-05-07

    In this work, we demonstrate that the magnetocaloric response of FeRh-based compounds may be tailored for potential magnetic refrigeration applications by chemical modification of the FeRh lattice. Alloys of composition Fe(Rh{sub 1−x}A{sub x}) or (Fe{sub 1−x}B{sub x})Rh (A = Cu, Pd; B = Ni; 0 < x < 0.06) were synthesized via arc-melting and subsequent annealing in vacuum at 1000 °C for 48 h. The magnetocaloric properties of the FeRh-based systems were determined using isothermal M(H) curves measured in the vicinity of the magnetostructural temperature (T{sub t}). It is found that the FeRh working temperature range (δT{sub FWHM}) may be chemically tuned over a wide temperature range, 100 K ≤ T ≤ 400 K. While elemental substitution consistently decreases the magnetic entropy change (ΔS{sub mag}) of the FeRh-based ternary alloys from that of the parent FeRh compound (ΔS{sub mag},{sub FeRh} ∼ 17 J/kg K; ΔS{sub mag,FeRh-ternary =} 7–14 J/kg K at H{sub app} = 2 T), the net refrigeration capacity (RC), defined as the amount of heat that can be transferred during one magnetic refrigeration cycle, of the modified systems is significantly higher (RC{sub FeRh} ∼ 150 J/kg; RC{sub FeRh-ternary =} 170–210 J/kg at H{sub app} = 2 T). These results are attributed to stoichiometry-induced changes in the FeRh electronic band structure and beneficial broadening of the magnetostructural transition due to local chemical disorder.

  8. Reducing the moisture content of clean coals

    SciTech Connect (OSTI)

    Kehoe, D. )

    1992-12-01

    Coal moisture content can profoundly effect the cost of burning coal in utility boilers. Because of the large effect of coal moisture, the Empire State Electric Energy Research Corporation (ESEERCO) contracted with the Electric Power Research Institute to investigate advanced coal dewatering methods at its Coal Quality Development Center. This report contains the test result on the high-G solid-bowl centrifuge, the second of four devices to be tested. The high-G solid-bowl centrifuge removes water for coal by spinning the coal/water mixture rapidly in a rotating bowl. This causes the coal to cling to the sides of the bowl where it can be removed, leaving the water behind. Testing was performed at the CQDC to evaluate the effect of four operating variables (G-ratio, feed solids concentration, dry solids feed rate, and differential RPM) on the performance of the high-G solid-bowl centrifuge. Two centrifuges of different bowl diameter were tested to establish the effect of scale-up of centrifuge performance. Testing of the two centrifuges occurred from 1985 through 1987. CQDC engineers performed 32 tests on the smaller of the two centrifuges, and 47 tests on the larger. Equations that predict the performance of the two centrifuges for solids recovery, moisture content of the produced coal, and motor torque were obtained. The equations predict the observed data well. Traditional techniques of establishing the performance of centrifuge of different scale did not work well with the two centrifuges, probably because of the large range of G-ratios used in the testing. Cost of operating a commercial size bank of centrifuges is approximately $1.72 per ton of clean coal. This compares well with thermal drying, which costs $1.82 per ton of clean coal.

  9. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to producemore » carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.« less

  10. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore »by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  11. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    SciTech Connect (OSTI)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to produce carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.

  12. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore » by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  13. Moisture Control Handbook: New, low-rise, residential construction

    SciTech Connect (OSTI)

    Lstiburek, J.; Carmody, J.

    1991-10-01

    Moisture problems are prevalent all over North America, almost independent of climate. They are viewed as one of the single largest factors limiting the useful service life of a building. Elevated levels of moisture in buildings also can lead to serious health effects for occupants. Until recently, very little consensus on moisture control existed in the building community. The information available was typically incomplete, contradictory, usually limited to specific regions, and in many cases misleading. A need to develop a document which presented the issues relating to moisture from a building science or ``systems`` approach existed. This handbook attempts to fill that need and illustrates that energy-efficient, tight envelope design is clearly part of the solution to healthy buildings when interior relative humidity, temperature, and pressure are controlled simultaneously. The first three chapters of the handbook present the basic principles of moisture problems and solutions in buildings. Chapter 1 -- Mold, Mildew, and Condensation, examines surface moisture problems. Chapter 2 -- Moisture Movement, examines how building assemblies get wet from both the exterior and interior. Chapter 3 -- Wetting and Drying of Building Assemblies, introduces the concepts of acceptable performance, moisture balance, and the redistribution of moisture within building assemblies. Chapters 4 through 6 apply the concepts outlined in the previous chapters and present specific moisture control practices for three basic US climate zones. The advantages and disadvantages of several wall, foundation, and roof assemblies are discussed for each climate zone.

  14. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn?

    SciTech Connect (OSTI)

    Das, Pinaki [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Lin, S. -Z. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ghimire, N.? J. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Huang, K. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of California, San Diego, La Jolla, CA (United States); Ronning, F. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Bauer, E.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Thompson, J.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Batista, C.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ehlers, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Janoschek, M. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2014-12-01

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J??J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3)??meV. Our results pave the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  15. Moisture Management for High R-Value Walls

    SciTech Connect (OSTI)

    Lepage, R.; Schumacher, C.; Lukachko, A.

    2013-11-01

    This report explains the moisture-related concerns for high R-value wall assemblies and discusses past Building America research work that informs this study. In this project, hygrothermal simulations were prepared for several common approaches to High R-value wall construction in six cities (Houston, Atlanta, Seattle, St. Louis, Chicago, and International Falls) representing a range of climate zones. The modeling program assessed the moisture durability of the wall assemblies based on three primary sources of moisture: construction moisture, air leakage condensation, and bulk water leakage; the report presents results of the study.

  16. Moisture and Ventilation Solutions in Hot, Humid Climates: Florida...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    One manufacturer reported zero moisture-related issues in 35,000 homes built after ... Standard Work Specifications for Single-Family Home Energy Upgrades Building America ...

  17. W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS;...

    Office of Scientific and Technical Information (OSTI)

    thorium fuel reprocessing experience Brooksbank, R.E.; McDuffee, W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; NUCLEAR MATERIALS DIVERSION; SAFEGUARDS; SPENT FUELS;...

  18. Electronic band structure and Kondo coupling in YbRh2Si2

    SciTech Connect (OSTI)

    Wigger, G.A.

    2010-04-15

    The electronic band structure of YbRh2Si2 is calculated in a relativistic framework including correlation corrections and magnetization of the Yb ion and compared to detailed angle-resolved photoemission spectra. The photoemission spectra for LuRh2Si2 are used as reference to identify electronic bands with no f symmetry. The calculated band structure manifests a 4f13 spin-polarized configuration leaving the unoccupied state at 1.4eV above the Fermi energy. At the band theory level, the 4f bands are located far below the Fermi level and the anisotropic Coulomb interaction within the 4f shell spreads the multilevel into broader 4f complexes below -2.5eV . The photoemission spectra obtained on YbRh2Si2 show a clear f -multilevel splitting into j=7/2 and 5/2 excitations. The interaction of the 4f7/2 levels close to the Fermi energy with two conduction bands shows visible hybridization gaps of 45 and 80meV, respectively. We discuss the origin of these excitations and provide an analysis according to Anderson's single-impurity model with parameters suggested by the band-structure calculation and the photoemission spectra. Both experiment and theory indicate nearly identical Fermi surfaces for LuRh2Si2 and YbRh2Si2 . The valency of Yb in YbRh2Si2 is estimated to be close to +3.

  19. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  20. ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Pacific Northwest National Laboratory Pacific ...

  1. Moisture Management of High-R Walls (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-12-01

    The following report explains the moisture-related concerns for High R-value wall assemblies and discusses past Building America research work that informs this study. Hygrothermal simulations were prepared for several common approaches to High R-value wall construction in six cities (Houston, Atlanta, Seattle, St. Louis, Chicago, and International Falls) representing a range of climate zones (2, 3, 4C, 4, 5A, and 7, respectively). The simulations are informed by experience gained from past research in this area and validated by field measurement and forensic experience. The modeling program was developed to assess the moisture durability of the wall assemblies based on three primary sources of moisture: construction moisture, air leakage condensation, and bulk water leakage. The peak annual moisture content of the wood based exterior sheathing was used to comparatively analyze the response to the moisture loads for each of the walls in each given city. Walls which experienced sheathing moisture contents between 20% and 28% were identified as risky, whereas those exceeding 28% were identified as very high risk. All of the wall assemblies perform well under idealized conditions. However, only the walls with exterior insulation, or cavity insulation which provides a hygrothermal function similar to exterior insulation, perform adequately when exposed to moisture loads. Walls with only cavity insulation are particularly susceptible to air leakage condensation. None of the walls performed well when a precipitation based bulk water leak was introduced to the backside of the sheathing, emphasizing the importance of proper flashing details.

  2. Moisture Management for High R-Value Walls

    SciTech Connect (OSTI)

    Lepage, R.; Schumacher, C.; Lukachko, A.

    2013-11-01

    The following report explains the moisture-related concerns for High R-value wall assemblies and discusses past Building America research work that informs this study. Hygrothermal simulations were prepared for several common approaches to High R-value wall construction in six cities (Houston, Atlanta, Seattle, St. Louis, Chicago, and International Falls) representing a range of climate zones (2, 3, 4C, 4, 5A, and 7, respectively). The simulations are informed by experience gained from past research in this area and validated by field measurement and forensic experience. The modeling program was developed to assess the moisture durability of the wall assemblies based on three primary sources of moisture: construction moisture, air leakage condensation, and bulk water leakage. The peak annual moisture content of the wood based exterior sheathing was used to comparatively analyze the response to the moisture loads for each of the walls in each given city. Walls which experienced sheathing moisture contents between 20% and 28% were identified as risky, whereas those exceeding 28% were identified as very high risk. All of the wall assemblies perform well under idealized conditions. However, only the walls with exterior insulation, or cavity insulation which provides a hygrothermal function similar to exterior insulation, perform adequately when exposed to moisture loads. Walls with only cavity insulation are particularly susceptible to air leakage condensation. None of the walls performed well when a precipitation based bulk water leak was introduced to the backside of the sheathing, emphasizing the importance of proper flashing details.

  3. High-R Walls for Remodeling. Wall Cavity Moisture Monitoring

    SciTech Connect (OSTI)

    Wiehagen, J.; Kochkin, V.

    2012-12-01

    The focus of the study is on the performance of wall systems, and in particular, the moisture characteristics inside the wall cavity and in the wood sheathing. Furthermore, while this research will initially address new home construction, the goal is to address potential moisture issues in wall cavities of existing homes when insulation and air sealing improvements are made.

  4. High-R Walls for Remodeling: Wall Cavity Moisture Monitoring

    SciTech Connect (OSTI)

    Wiehagen, J.; Kochkin, V.

    2012-12-01

    The focus of the study is on the performance of wall systems, and in particular, the moisture characteristics inside the wall cavity and in the wood sheathing. Furthermore, while this research will initially address new home construction, the goal is to address potential moisture issues in wall cavities of existing homes when insulation and air sealing improvements are made.

  5. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect (OSTI)

    Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

    2013-06-01

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energys Office of Biomass Programs. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  6. Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings

    SciTech Connect (OSTI)

    Woods, J.; Winkler, J.; Christensen, D.

    2013-01-01

    This study examines the effective moisture penetration depth (EMPD) model, and its suitability for building simulations. The EMPD model is a compromise between the simple, inaccurate effective capacitance approach and the complex, yet accurate, finite-difference approach. Two formulations of the EMPD model were examined, including the model used in the EnergyPlus building simulation software. An error in the EMPD model we uncovered was fixed with the release of EnergyPlus version 7.2, and the EMPD model in earlier versions of EnergyPlus should not be used.

  7. Origin of the smaller conductances of Rh, Pb, and Co atomic junctions in hydrogen environment

    SciTech Connect (OSTI)

    Li, Xue; Chen, Mingyan; Ye, Xiang; Xie, Yi-qun; Ke, San-huang

    2015-02-14

    We study theoretically the structural and electronic origins of the smaller conductances (one conductance quantum, G{sub 0}, and smaller) of Rh, Pb, and Co metal atomic junctions (MAJs) in a hydrogen environment, as were measured in recent experiments. For the Rh MAJs, the 1G{sub 0} conductance is attributed to a stable contact bridged by a single hydrogen molecule whose antibonding state provides a single transport channel. For the Pb and Co MAJs the 1G{sub 0} conductance is, however, ascribed to a linear atomic chain adsorbing two dissociated H atoms, which largely reduces the density of states at the Fermi energy with respect to the pure ones. On the other hand, the small conductances of 0.3G{sub 0} (Rh) and 0.2G{sub 0} (Co) are due to H-decorated atomic chains connected to electrodes by a H atom.

  8. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H.

    1996-12-31

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  9. Electronic Band Structure And Kondo Coupling in YbRh(2)Si(2)

    SciTech Connect (OSTI)

    Wigger, G.A.; Baumberger, F.; Shen, Z.X.; Yin, Z.P.; Pickett, W.E.; Maquilon, S.; Fisk, Z.; /UC, Davis

    2007-09-26

    The electronic band structure of YbRh{sub 2}Si{sub 2} is calculated in a relativistic framework including correlation corrections and magnetization of the Yb ion and compared to detailed angle-resolved photoemission spectra. The photoemission spectra for LuRh{sub 2}Si{sub 2} are used as reference to identify electronic bands with no f symmetry. The calculated band structure manifests a 4f{sup 13} spin-polarized configuration leaving the unoccupied state at 1.4 eV above the Fermi energy. At the band theory level, the 4f bands are located far below the Fermi level and the anisotropic Coulomb interaction within the 4f shell spreads the multilevel into broader 4f complexes below -2.5 eV. The photoemission spectra obtained on YbRh2Si2 show a clear f-multilevel splitting into j=7/2 and 5/2 excitations. The interaction of the 4f{sub 7/2} levels close to the Fermi energy with two conduction bands shows visible hybridization gaps of 45 and 80 meV, respectively. We discuss the origin of these excitations and provide an analysis according to Anderson's single-impurity model with parameters suggested by the band-structure calculation and the photoemission spectra. Both experiment and theory indicate nearly identical Fermi surfaces for LuRh{sub 2}Si{sub 2} and YbRh{sub 2}Si{sub 2}. The valency of Yb in YbRh{sub 2}Si{sub 2} is estimated to be close to +3.

  10. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Rh/Ba

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Traps for Design and Optimization | Department of Energy Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Rh/Ba NOx Traps for Design and Optimization Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Rh/Ba NOx Traps for Design and Optimization 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_27_harold.pdf More Documents & Publications

  11. Moisture Risk in Unvented Attics Due to Air Leakage Paths

    SciTech Connect (OSTI)

    Prahl, D.; Shaffer, M.

    2014-11-01

    IBACOS completed an initial analysis of moisture damage potential in an unvented attic insulated with closed-cell spray polyurethane foam. To complete this analysis, the research team collected field data, used computational fluid dynamics to quantify the airflow rates through individual airflow (crack) paths, simulated hourly flow rates through the leakage paths with CONTAM software, correlated the CONTAM flow rates with indoor humidity ratios from Building Energy Optimization software, and used Warme und Feuchte instationar Pro two-dimensional modeling to determine the moisture content of the building materials surrounding the cracks. Given the number of simplifying assumptions and numerical models associated with this analysis, the results indicate that localized damage due to high moisture content of the roof sheathing is possible under very low airflow rates. Reducing the number of assumptions and approximations through field studies and laboratory experiments would be valuable to understand the real-world moisture damage potential in unvented attics.

  12. Moisture Risk in Unvented Attics Due to Air Leakage Paths

    SciTech Connect (OSTI)

    Prahl, D.; Shaffer, M.

    2014-11-01

    IBACOS completed an initial analysis of moisture damage potential in an unvented attic insulated with closed-cell spray polyurethane foam. To complete this analysis, the research team collected field data, used computational fluid dynamics to quantify the airflow rates through individual airflow (crack) paths, simulated hourly flow rates through the leakage paths with CONTAM software, correlated the CONTAM flow rates with indoor humidity ratios from Building Energy Optimization software, and used Wrme und Feuchte instationr Pro two-dimensional modeling to determine the moisture content of the building materials surrounding the cracks. Given the number of simplifying assumptions and numerical models associated with this analysis, the results indicate that localized damage due to high moisture content of the roof sheathing is possible under very low airflow rates. Reducing the number of assumptions and approximations through field studies and laboratory experiments would be valuable to understand the real-world moisture damage potential in unvented attics.

  13. Innovative Drying Technology Extracts More Energy from High Moisture Coal

    Broader source: Energy.gov [DOE]

    An innovative coal-drying technology that will extract more energy from high moisture coal at less cost and simultaneously reduce potentially harmful emissions is ready for commercial use after successful testing at a Minnesota electric utility.

  14. Measurement of Moisture Content in Sand, Slag, and Crucible Materials

    SciTech Connect (OSTI)

    Gray, J.H.

    1999-09-20

    The deinventory process at Rocky Flats (RFETS) has included moisture content measurements of sand, slag, and crucible (SSC) materials by performing weight loss measurements at 210 degrees - 220 degrees Celsius on representative samples prior to packaging for shipment. Shipping requirements include knowledge of the moisture content. Work at the Savannah River Technology Center (SRTC) showed that the measurement at 210 degrees - 220 degrees Celsius did not account for all of the moisture. The objective of the work in this report was to determine if the measurement at 210 degrees - 220 degrees Celsius at RFETS could be used to set upper bounds on moisture content and therefore, eliminate the need for RFETS to unpack, reanalyze and repack the material.

  15. Building Integrated Heat and Moisture Exchange | Department of...

    Energy Savers [EERE]

    and moisture exchanger, the AirFlow(tm) Panel, installed for evaluation at Lawrence Berkeley National Lab. Image: Architectural Applications 2 of 2 A schematic of the AirFlow(tm)...

  16. Monitoring of Double Stud Wall Moisture Conditions in the Northeast

    SciTech Connect (OSTI)

    Ueno, K.

    2015-03-01

    Double-stud walls insulated with cellulose or low-density spray foam can have R-values of 40 or higher. However, double stud walls have a higher risk of interior-sourced condensation moisture damage, when compared with high-R approaches using exterior insulating sheathing.; Moisture conditions in double stud walls were monitored in Zone 5A (Massachusetts); three double stud assemblies were compared.

  17. Moisture desorption rates from TATB-formulations: experiments and kinetic

    Office of Scientific and Technical Information (OSTI)

    models (Journal Article) | SciTech Connect Moisture desorption rates from TATB-formulations: experiments and kinetic models Citation Details In-Document Search Title: Moisture desorption rates from TATB-formulations: experiments and kinetic models Authors: Glascoe, E A ; Dinh, L N ; Small, W ; Overturf, G E Publication Date: 2012-01-19 OSTI Identifier: 1093909 Report Number(s): LLNL-JRNL-528991 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal Article Resource Relation: Journal Name:

  18. Moisture and Ventilation Solutions in Hot, Humid Climates: Florida

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufactured Housing - Building America Top Innovation | Department of Energy Moisture and Ventilation Solutions in Hot, Humid Climates: Florida Manufactured Housing - Building America Top Innovation Moisture and Ventilation Solutions in Hot, Humid Climates: Florida Manufactured Housing - Building America Top Innovation Photo of workers on the roof of a home. This Top Innovation profile describes research by Building America Partnership for Improved Residential Construction team to diagnose

  19. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  20. Atmospheric Radiation Measurement Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement WARNING WARNING Today is April 1 But that ...

  1. Antiferromagnetic ordering in the doped Kondo insulator CeRhSb

    SciTech Connect (OSTI)

    Menon, L.; Malik, S.K.

    1997-06-01

    CeRhSb, the so-called {open_quotes}Kondo insulator,{close_quotes} is a mixed-valent compound showing a gap formation in the electronic density of states. On the other hand, CePdSb is ferromagnetically ordered with a Curie temperature of {approximately}17 K. We have carried out magnetic susceptibility and electrical resistivity measurements on CeRh{sub 1{minus}x}Pd{sub x}Sb (0{le}x{le}1.0), to study the ground-state properties of this system. For small Pd doping in CeRhSb, up to 20{percent}, the gap continually diminishes and no magnetic ordering is observed down to 2 K. In the region 0.3{le}x{le}0.4, as soon as the gap is suppressed, an antiferromagnetic ground state is observed. In the region 0.5{le}x{lt}0.7, the compounds are not single phase. At the CePdSb end, in the region 0.7{le}x{le}1, the ground state is ferromagnetic. The observation of an antiferromagnetic phase in the phase diagram of CeRh{sub 1{minus}x}Pd{sub x}Sb, where neither end is antiferromagnetic, is interesting and is discussed in the light of some recent theoretical models. {copyright} {ital 1997} {ital The American Physical Society}

  2. Thermodynamics and superconductivity of Th7(Fe, Ru, Os, Co, Rh, Ir)3 system

    SciTech Connect (OSTI)

    Smith, James L; Lashley, Jason C; Volz, Heather M; Fisher, Robert A

    2008-01-01

    Expanding the temperature range of previous specific-heat measurements on the Th7(Fe, Ru, Os, Co, Rh, Ir)3 system, we measure the effect of transition-metal substitution on total entropy (S{sub 298 k}), electronic specific heat ({gamma}), and Debye temperature ({Theta}D). In addition we measure the pressure dependence, up to 10 kbar, of the superconducting transition.

  3. Impact of Materials Processing on Microstructural Evolution and Hydrogen Isotope Storage Properties of Pd-Rh Alloy Powders.

    SciTech Connect (OSTI)

    Yee, Joshua K

    2015-02-01

    Cryomilled Pd - 10Rh was investiga ted as potential solid - state storage material of hydrogen. Pd - 10Rh was first atomized, and then subsequently cryomilled. The cryomilled Pd - 10Rh was then examined using microstructural characterization techniques including op tical microscopy, electron microscopy, and X - ray diffraction. Pd - 10Rh particles were significantly flattened, increasing the apparent surface area. Microstructural refinement was observed in the cryomilled Pd - 10Rh, generating grains at the nanom etric scale through dislocation - based activity. Hydrogen sorption properties were also characterized, generating both capacity as well as kinetics measurements. It was found that the microstructural refinement due to cryomilling did not play a significant role on hyd rogen sorption properties until the smallest grain size (on the order of %7E25 nm) was achieved. Additionally, the increased surface area and other changes in particle morphology were associated with cryomilling changed the kinetics of hydrogen absorption.

  4. Waste Isolation Pilot Plant simulated RH TRU waste experiments: Data and interpretation pilot

    SciTech Connect (OSTI)

    Molecke, M.A.; Argueello, G.J.; Beraun, R.

    1993-04-01

    The simulated, i.e., nonradioactive remote-handled transuranic waste (RH TRU) experiments being conducted underground in the Waste Isolation Pilot Plant (WIPP) were emplaced in mid-1986 and have been in heated test operation since 9/23/86. These experiments involve the in situ, waste package performance testing of eight full-size, reference RH TRU containers emplaced in horizontal, unlined test holes in the rock salt ribs (walls) of WIPP Room T. All of the test containers have internal electrical heaters; four of the test emplacements were filled with bentonite and silica sand backfill materials. We designed test conditions to be ``near-reference`` with respect to anticipated thermal outputs of RH TRU canisters and their geometrical spacing or layout in WIPP repository rooms, with RH TRU waste reference conditions current as of the start date of this test program. We also conducted some thermal overtest evaluations. This paper provides a: detailed test overview; comprehensive data update for the first 5 years of test operations; summary of experiment observations; initial data interpretations; and, several status; experimental objectives -- how these tests support WIPP TRU waste acceptance, performance assessment studies, underground operations, and the overall WIPP mission; and, in situ performance evaluations of RH TRU waste package materials plus design details and options. We provide instrument data and results for in situ waste container and borehole temperatures, pressures exerted on test containers through the backfill materials, and vertical and horizontal borehole-closure measurements and rates. The effects of heat on borehole closure, fracturing, and near-field materials (metals, backfills, rock salt, and intruding brine) interactions were closely monitored and are summarized, as are assorted test observations. Predictive 3-dimensional thermal and structural modeling studies of borehole and room closures and temperature fields were also performed.

  5. Modifications to WRFs dynamical core to improve the treatment of moisture for large-eddy simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiao, Heng; Endo, Satoshi; Wong, May; Skamarock, William C.; Klemp, Joseph B.; Fast, Jerome D.; Gustafson, Jr., William I.; Vogelmann, Andrew; Wang, Hailong; Liu, Yangang; et al

    2015-10-29

    Yamaguchi and Feingold (2012) note that the cloud fields in their large-eddy simulations (LESs) of marine stratocumulus using the Weather Research and Forecasting (WRF) model exhibit a strong sensitivity to time stepping choices. In this study, we reproduce and analyze this sensitivity issue using two stratocumulus cases, one marine and one continental. Results show that (1) the sensitivity is associated with spurious motions near the moisture jump between the boundary layer and the free atmosphere, and (2) these spurious motions appear to arise from neglecting small variations in water vapor mixing ratio (qv) in the pressure gradient calculation in themore » acoustic sub-stepping portion of the integration procedure. We show that this issue is remedied in the WRF dynamical core by replacing the prognostic equation for the potential temperature θ with one for the moist potential temperature θm=θ(1+1.61qv), which allows consistent treatment of moisture in the calculation of pressure during the acoustic sub-steps. With this modification, the spurious motions and the sensitivity to the time stepping settings (i.e., the dynamic time step length and number of acoustic sub-steps) are eliminated in both of the example stratocumulus cases. In conclusion, this modification improves the applicability of WRF for LES applications, and possibly other models using similar dynamical core formulations, and also permits the use of longer time steps than in the original code.« less

  6. Modifications to WRFs dynamical core to improve the treatment of moisture for large-eddy simulations

    SciTech Connect (OSTI)

    Xiao, Heng; Endo, Satoshi; Wong, May; Skamarock, William C.; Klemp, Joseph B.; Fast, Jerome D.; Gustafson, Jr., William I.; Vogelmann, Andrew; Wang, Hailong; Liu, Yangang; Lin, Wuyin

    2015-10-29

    Yamaguchi and Feingold (2012) note that the cloud fields in their large-eddy simulations (LESs) of marine stratocumulus using the Weather Research and Forecasting (WRF) model exhibit a strong sensitivity to time stepping choices. In this study, we reproduce and analyze this sensitivity issue using two stratocumulus cases, one marine and one continental. Results show that (1) the sensitivity is associated with spurious motions near the moisture jump between the boundary layer and the free atmosphere, and (2) these spurious motions appear to arise from neglecting small variations in water vapor mixing ratio (qv) in the pressure gradient calculation in the acoustic sub-stepping portion of the integration procedure. We show that this issue is remedied in the WRF dynamical core by replacing the prognostic equation for the potential temperature θ with one for the moist potential temperature θm=θ(1+1.61qv), which allows consistent treatment of moisture in the calculation of pressure during the acoustic sub-steps. With this modification, the spurious motions and the sensitivity to the time stepping settings (i.e., the dynamic time step length and number of acoustic sub-steps) are eliminated in both of the example stratocumulus cases. In conclusion, this modification improves the applicability of WRF for LES applications, and possibly other models using similar dynamical core formulations, and also permits the use of longer time steps than in the original code.

  7. CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Margaret Torn

    2015-01-14

    This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

  8. CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Margaret Torn

    This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

  9. Atmospheric Radiation Measurement Radiative Atmospheric Divergence...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    campaign is sponsored by the Atmospheric Radiation Measurement (ARM) Program, the largest global change research program within the U.S. Department of Energy's Office of Science. ...

  10. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental interest in that they add to a growing body of evidence indicating that certain, appropriately ligated, coordinatively unsaturated, subnanometer M4 transition-metal clusters can be relatively robust catalysts. Also demonstrated herein is that Rh4 clusters are poisoned by Hg(0), demonstrating for the first time that the classic Hg(0) poisoning test of 'homogeneous' vs 'heterogeneous'catalysts cannot distinguish Rh4-based subnanometer catalysts from Rh(0)n nanoparticle catalysts, at least for the present examples of these two specific, Rh-based catalysts.

  11. Moisture Durability with Vapor-Permeable Insulating Sheathing

    SciTech Connect (OSTI)

    Lepage, R.; Lstiburek, J.

    2013-09-01

    Exterior sheathing insulation is an effective strategy in increasing the overall R-value of wall assemblies; other benefits include decreasing the effects of thermal bridging and increasing the moisture durability of the built assembly. Vapor-permeable exterior insulation, such as mineral board or expanded polystyrene foam, are one such product that may be used to achieve these benefits. However, uncertainty exists on the effects of inward driven moisture and the interaction of increased sheathing temperatures on the moisture durability of the edifice. To address these concerns, Building Science Corporation (BSC) conducted a series of hygrothermal models for cities representing a range of different climate zones. This report describes the research project, key research questions, and the procedures utilized to analyse the problems.

  12. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    SciTech Connect (OSTI)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of FeRh alloys for catalyst with 17 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidenced by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of FeRh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.

  13. Synthesis of few-walled carbon nanotube-Rh nanoparticles by arc discharge: Effect of selective oxidation

    SciTech Connect (OSTI)

    Zhang Yanfeng

    2012-06-15

    Highly crystalline rhodium (Rh) nanoparticles supported on carbon nanotubes were prepared by selective oxidation method. Carbon nanotubes and FeRh nanoparticles were simultaneously generated in hydrogen arc plasma. The as-grown nanomaterials can be purified by heat treatment in open air and by soaking in HCl. X-ray diffraction and selected area electron diffraction results reveal that as-grown FeRh nanoparticles have a typical chemical CsCl-type structure which can be transformed into a face-centered cubic structure by thermal annealing in the purification process. The purification process is selective toward the removal of the amorphous carbon coating the nanoparticles, and transforms Fe to Fe{sub 2}O{sub 3}. Fe{sub 2}O{sub 3} can be easily dissolved in hydrochloric acid, leaving carbon nanotubes-Rh nanoparticles. Rh nanoparticles with diameters of 2-60 nm are deposited uniformly on the surface of the carbon nanotube bundles. This simple and selective chemistry offers a new process for synthesizing and controlling Fe content in carbon nanotube-FeRh nanoparticles. Highlights: Black-Right-Pointing-Pointer High-crystallinity CNTs and FeRh nanoparticles were simultaneously generated in arc plasma. Black-Right-Pointing-Pointer The diameter distribution of CNTs depends on different gases. Black-Right-Pointing-Pointer Heat treatment in open air and soaking in HCl can convert CNTs-FeRh to CNTs-Rh. Black-Right-Pointing-Pointer The selective oxidation mechanisms of metal nanoparticles and carbon materials differ.

  14. System design description for surface moisture measurement system (SMMS)

    SciTech Connect (OSTI)

    Vargo, G.F.

    1996-09-23

    The SMMS has been developed to measure moisture in the top few centimeters of tank waste. The SMMS development was initiated by the preliminary findings of SAR-033, and does not necessarily fulfill any established DQO. After the SAR-033 is released, if no significant changes are made, moisture measurements in the organic waste tanks will rapidly become a DQO. The SMMS was designed to be installed in any 4 inch or larger riser, and to allow maximum adjustability for riser lengths, and is used to deploy a sensor package on the waste surface within a 6 foot radius about the azimuth. The first sensor package will be a neutron probe.

  15. ARM - Field Campaign - Scintillometry and Soil Moisture Remote Sensing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsScintillometry and Soil Moisture Remote Sensing Related Campaigns Enhanced Soundings for Local Coupling Studies 2015.06.15, Ferguson, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Scintillometry and Soil Moisture Remote Sensing 2015.06.01 - 2015.10.31 Lead Scientist : Jan Hendrickx Abstract The technical goal was to support the campaign "Enhanced soundings for local coupling studies" of Dr. Craig Ferguson by

  16. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn₅. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J₁-J₂ model that also naturally explains the magnetic spin-spiral ground state of CeRhIn₅ and yields a dominant in-plane nearest-neighbor magnetic exchange constant J₀=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn₅ (T = Co, Rh, Ir) class of heavy-fermion materials.

  17. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    SciTech Connect (OSTI)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J?-J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  18. Magnetism and superconductivity in U2PtxRh1?xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. Themorereduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.less

  19. Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C-H Bond Activation

    SciTech Connect (OSTI)

    Lewis, Jared; Bergman, Robert; Ellman, Jonathan

    2008-02-04

    Nitrogen heterocycles are present in many compounds of enormous practical importance, ranging from pharmaceutical agents and biological probes to electroactive materials. Direct funtionalization of nitrogen heterocycles through C-H bond activation constitutes a powerful means of regioselectively introducing a variety of substituents with diverse functional groups onto the heterocycle scaffold. Working together, our two groups have developed a family of Rh-catalyzed heterocycle alkylation and arylation reactions that are notable for their high level of functional-group compatibility. This Account describes their work in this area, emphasizing the relevant mechanistic insights that enabled synthetic advances and distinguished the resulting transformations from other methods. They initially discovered an intramolecular Rh-catalyzed C-2-alkylation of azoles by alkenyl groups. That reaction provided access to a number of di-, tri-, and tetracyclic azole derivatives. They then developed conditions that exploited microwave heating to expedite these reactions. While investigating the mechanism of this transformation, they discovered that a novel substrate-derived Rh-N-heterocyclic carbene (NHC) complex was involved as an intermediate. They then synthesized analogous Rh-NHC complexes directly by treating precursors to the intermediate [RhCl(PCy{sub 3}){sub 2}] with N-methylbenzimidazole, 3-methyl-3,4-dihydroquinazolein, and 1-methyl-1,4-benzodiazepine-2-one. Extensive kinetic analysis and DFT calculations supported a mechanism for carbene formation in which the catalytically active RhCl(PCy{sub 3}){sub 2} fragment coordinates to the heterocycle before intramolecular activation of the C-H bond occurs. The resulting Rh-H intermediate ultimately tautomerizes to the observed carbene complex. With this mechanistic information and the discovery that acid co-catalysts accelerate the alkylation, they developed conditions that efficiently and intermolecularly alkylate a variety of heterocycles, including azoles, azolines, dihydroquinazolines, pyridines, and quinolines, with a wide range of functionalized olefins. They demonstrated the utility of this methodology in the synthesis of natural products, drug candidates, and other biologically active molecules. In addition, they developed conditions to directly arylate these heterocycles with aryl halides. The initial conditions that used PCy{sub 3} as a ligand were successful only for aryl iodides. However, efforts designed to avoid catalyst decomposition led to the development of ligands based on 9-phosphabicyclo[4.2.1]nonane (Phoban) that also facilitated the coupling of aryl bromides. They then replicated the unique coordination environment, stability, and catalytic activity of this complex using the much simpler tetrahydrophosphepine ligands and developed conditions that coupled aryl bromides bearing diverse functional groups without the use of a glovebox or purified reagents. With further mechanistic inquiry, they anticipate that researchers will better understand the details of the aforementioned Rh-catalyzed C-H bond functionalization reactions, resulting in the design of more efficient and robust catalysts, expanded substrate scope, and new transformations.

  20. Magnetism and superconductivity in U?PtxRh(1x)C?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x.moreThe reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.less

  1. Electronic structure of U2PtC2 and U2RhC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronning, F.; Zhu, J. -X.

    2015-03-18

    In this study, we present density functional theory calculations within the generalized gradient approximation of U2RhC2 and U2PtC2. We find the calculated density of states are significantly less than that measured by specific heat indicating the need for electronic correlations. The mass enhancement found for U2PtC2 is m*/mband ≈ 4.

  2. Retrieval and Repackaging of RH-TRU Waste - General Presentation Modular Hot Cell Technology

    Office of Environmental Management (EM)

    Paul Murray Oak Ridge, TN July 29, 2009 Retrieval and Repackaging of RH-TRU Waste- GENERAL PRESENTATION MODULAR HOT CELL TECHNOLOGY AREVA FEDERAL SERVICES - OAK RIDGE, TN - GENERAL PRESENTATION OF MODULAR HOT CELL TECHNOLOGY - July 29, 2009 ADAPTING AREVA'S TECHNOLOGY AREVA Worldwide Nuclear Lifecycle Transmission & Distribution Renewable Energy AREVA US Nuclear Fuel Services Nuclear Engineering Services AREVA Federal Services, LLC. (AFS) Federal Services Major Projects * MOX-MFFF * Yucca

  3. Hydrogen sorption characteristics of nanostructured Pd10Rh processed by cryomilling

    SciTech Connect (OSTI)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less than 100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the ?-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.

  4. Hydrogen sorption characteristics of nanostructured Pd–10Rh processed by cryomilling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less thanmore » 100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the α-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.« less

  5. Moisture Distribution and Flow During Drying of Wood and Fiber

    SciTech Connect (OSTI)

    Zink-Sharp, Audrey; Hanna, Robert B.

    2001-12-28

    New understanding, theories, and techniques for moisture flow and distribution were developed in this research on wood and wood fiber. Improved understanding of the mechanisms of flake drying has been provided. Observations of flake drying and drying rate curves revealed that rate of moisture loss consisted of two falling rate periods and no constant rate drying period was observed. Convective heat transfer controls the first period, and bound water diffusion controls the second period. Influence of lower drying temperatures on bending properties of wood flakes was investigated. Drying temperature was found to have a significant influence on bending stiffness and strength. A worksheet for calculation of the energy required to dry a single strandboard flake was developed but has not been tested in an industrial setting yet. A more complete understanding of anisotropic transverse shrinkage of wood is proposed based on test results and statistical analysis. A simplified mod el of a wood cell's cross-section was drawn for calculating differential transverse shrinkage. The model utilizes cell wall thickness and microfibrillar packing density and orientation. In spite of some phenomena of cell wall structure not yet understood completely, the results might explain anisotropic transverse shrinkage to a major extent. Boundary layer theory was found useful for evaluating external moisture resistance during drying. Simulated moisture gradients were quire comparable to the actual gradients in dried wood. A mathematical procedure for determining diffusion and surface emission coefficients was also developed. Thermal conductivity models of wood derived from its anatomical structure were created and tested against experimental values. Model estimations provide insights into changes in heat transfer parameters during drying. Two new techniques for measuring moisture gradients created in wood during drying were developed. A new technique that utilizes optical properties of cobalt chloride was developed for nondestructive determination of surface moisture content. Fundamental new understanding of drying characteristics in wood and fiber has been provided that can be used by researchers to improve drying of wood and fiber. The three techniques for measuring moisture content and gradients provided in this study are efficient, practical, and economical - easy to apply by industry and researchers. An energy consumption worksheet is provided as a first step toward reducing energy consumed during drying of lumber and strandboard flakes. However, it will need additional verification and testing.

  6. The valence band structure of Ag{sub x}Rh{sub 1–x} alloy nanoparticles

    SciTech Connect (OSTI)

    Yang, Anli; Sakata, Osami; Kusada, Kohei; Kobayashi, Hirokazu; Yayama, Tomoe; Ishimoto, Takayoshi; Yoshikawa, Hideki; Koyama, Michihisa; and others

    2014-10-13

    The valence band (VB) structures of face-centered-cubic Ag-Rh alloy nanoparticles (NPs), which are known to have excellent hydrogen-storage properties, were investigated using bulk-sensitive hard x-ray photoelectron spectroscopy. The observed VB spectra profiles of the Ag-Rh alloy NPs do not resemble simple linear combinations of the VB spectra of Ag and Rh NPs. The observed VB hybridization was qualitatively reproduced via a first-principles calculation. The electronic structure of the Ag{sub 0.5}Rh{sub 0.5} alloy NPs near the Fermi edge was strikingly similar to that of Pd NPs, whose superior hydrogen-storage properties are well known.

  7. Fundamental Bulk/Surface Structure Photoactivity Relationships of Supported (Rh2-yCryO3)/GaN Photocatalysts

    SciTech Connect (OSTI)

    Phivilay, Somphonh; Roberts, Charles; Puretzky, Alexander A; Domen, Kazunari Domen; Wachs, Israel

    2013-01-01

    ABSTRACT. The supported (Rh2-yCryO3)/GaN photocatalyst was examined as a model nitride photocatalyst system to assist in the development of fundamental structure photoactivity relationships for UV activated water splitting. Surface characterization of the outermost surface layers by High Sensitivity-LEIS and High Resolution-XPS revealed for the first time that the GaN support consists of a GaOx outermost surface layer and a thin film of GaOxNy in the surface region. HR-XPS also demonstrates that the supported (Rh2-yCryO3) mixed oxide nanoparticles (NPs) exclusively consist of Cr+3 and Rh+3 cations and are surface enriched for the supported (Rh2-yCryO3)/GaN photocatalyst. Bulk analysis by Raman and UV-vis spectroscopy show that the bulk molecular and electronic structures, respectively, of the GaN support are not perturbed by the deposition of the (Rh2-yCryO3) mixed oxide NPs. The function of the GaN bulk lattice is to generate photoexcited electrons/holes, with the electrons harnessed by the surface Rh+3 sites for evolution of H2 and the holes trapped at the Ga oxide/oxynitride surface sites for splitting of water and evolving O2. These new structure-photoactivity relationships for supported (Rh2-yCryO3)/GaN also extend to the best performing visible light activated supported (Rh2-yCryO3)/(Ga1-xZnx)(N1-xOx) photocatalyst.

  8. Microsoft Word - 06-1532dsm ltr to Zappe INL-CCP RH A-07-16 Report.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 2006 Mr. Steve Zappe, Project Leader Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Bldg. 1 Santa Fe, New Mexico 87505-6303 Subject: Audit Report A-07-16 for INL/CCP RH Waste Characterization Activities Dear Mr. Zappe: This letter transmits the Idaho National Laboratory /Central Characterization Project (INL/CCP) - Remote Handled (RH) Waste Characterization (Acceptable Knowledge and Visual Examination) Activities Audit A-07-16. The report contains the

  9. The Measurement of the Moisture Concentration of Selected Test Model Ore

    Energy Savers [EERE]

    Zones (April 1977) | Department of Energy The Measurement of the Moisture Concentration of Selected Test Model Ore Zones (April 1977) The Measurement of the Moisture Concentration of Selected Test Model Ore Zones (April 1977) The Measurement of the Moisture Concentration of Selected Test Model Ore Zones (April 1977) PDF icon The Measurement of the Moisture Concentration of Selected Test Model Ore Zones (April 1977) More Documents & Publications Field Calibration Facilities for

  10. Moisture and Structural Analysis for High Performance Hybrid Wall Assemblies

    SciTech Connect (OSTI)

    Grin, A.; Lstiburek, J.

    2012-09-01

    Based on past experience in the Building America program, BSC has found that combinations of materials and approachesin other words, systemsusually provide optimum performance. Integration is necessary, as described in this research project. The hybrid walls analyzed utilize a combination of exterior insulation, diagonal metal strapping, and spray polyurethane foam and leave room for cavity-fill insulation. These systems can provide effective thermal, air, moisture, and water barrier systems in one assembly and provide structure.

  11. Moisture Monitoring Results in an R-40 Wall

    Energy Savers [EERE]

    INSERT TITLE HERE Moisture Monitoring Results in an R-40 Wall Building America Webinar 2014 High Performance Enclosure Strategies © Steven Winter Associates, Inc. 2013 NEW YORK, NY | WASHINGTON, DC | NORWALK, CT © Steven Winter Associates, Inc. 2014 Overview of Presentation * Reasons for Research * Research Overview * Results * Recommendations * Future Work NEW YORK, NY | WASHINGTON, DC | NORWALK, CT © Steven Winter Associates, Inc. 2014 Reasons for Research * Changes in construction due to:

  12. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore » been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3μB/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

  13. Community Atmosphere Model

    Energy Science and Technology Software Center (OSTI)

    2004-10-18

    The Community Atmosphere Model (CAM) is an atmospheric general circulation model that solves equations for atmospheric dynamics and physics. CAM is an outgrowth of the Community Climate Model at the National Center for Atmospheric Research (NCAR) and was developed as a joint collaborative effort between NCAR and several DOE laboratories, including LLNL. CAM contains several alternative approaches for advancing the atmospheric dynamics. One of these approaches uses a finite-volume method originally developed by personnel atmore » NASNGSFC, We have developed a scalable version of the finite-volume solver for massively parallel computing systems. FV-CAM is meant to be used in conjunction with the Community Atmosphere Model. It is not stand-alone.« less

  14. ARM - Measurement - Atmospheric pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressure ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric pressure The pressure exerted by the atmosphere as a consequence of gravitational attraction exerted upon the "column" of air lying directly above the point in question. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream

  15. ARM - Atmospheric Pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ListAtmospheric Pressure Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Atmospheric Pressure Humans are subjected to the pressure produced by the weight of the gases of the atmosphere above us. The force exerted on a unit area of surface by the weight of the air above the surface is named

  16. The influence of nano-architectured CeOx supports in RhPd/CeO? for the catalytic ethanol steam reforming reaction

    SciTech Connect (OSTI)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO? cubes and CeO? rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO?-cubes > RhPd/CeO? -rods > RhPd/CeO?- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO?-cubes and RhPd/CeO? -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic - oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria

  17. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more » oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  18. The Low-Level Jet over the Southern Great Plains Determined from Observations and Reanalyses and Its Impact on Moisture Transport

    SciTech Connect (OSTI)

    Berg, Larry K.; Riihimaki, Laura D.; Qian, Yun; Yan, Huiping; Huang, Maoyi

    2015-09-01

    This study utilizes five commonly used reanalysis products, including the NCEP-DOE Reanalysis 2 (NCEP2), ECMWF Re-Analysis (ERA)-Interim, Japanese 25-year Reanalysis (JRA-25), Modern-Era Retrospective Analysis for Research and Applications (MERRA), and North American Regional Reanalysis (NARR) to evaluate features of the Southern Great Plains Low Level Jet (LLJ) above the Atmospheric Radiation Measurement (ARM) Climate Research Facility (ACRF) Southern Great Plains site. Two sets of radiosonde data are utilized: the six-week Midlatitude Continental Convective Clouds Experiment (MC3E), and a ten-year period spanning 2001-2010. All five reanalysis are compared to MC3E data, while only the NARR and MERRA are compared to the ten-year data. Each reanalysis is able to represent most aspects of the composite LLJ profile, although there is a tendency for each reanalysis to overestimate the wind speed between the nose of the LLJ and 700 mb. There are large discrepancies in the number of LLJ observed and derived from the reanalysis, particularly for strong LLJs that leads to an underestimate of the water vapor transport associated with LLJs. When the ten-year period is considered, the NARR overestimates and MERRA underestimates the total moisture transport, but both underestimate the transport associated with strong LLJs by factors of 2.0 and 2.7 for the NARR and MERR, respectively. During MC3E there were differences in the patterns of moisture convergence and divergence, with the MERRA having an area of moisture divergence over Oklahoma, while the NARR has moisture convergence. The patterns of moisture convergence and divergence are more consistent during the ten-year period.

  19. Synthesis, structure and chemical bonding of CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2) and SrCo{sub 2}Si{sub 2}

    SciTech Connect (OSTI)

    Hlukhyy, Viktor Hoffmann, Andrea V.; Fssler, Thomas F.

    2013-07-15

    The finding of superconductivity in Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} put the attention on the investigation of compounds that crystallize with ThCr{sub 2}Si{sub 2} structure type such as AT{sub 2}X{sub 2} (A=alkali/alkaline earth/rare earth element; T=transition metal and X=element of the 1315th group). In this context the silicides CaFe{sub 2}Si{sub 2}, CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}, CaRh{sub 2}Si{sub 2} and SrCo{sub 2}Si{sub 2} have been synthesized by reaction of the elements under an argon atmosphere. Single crystals were obtained by special heat treatment in welded niobium/tantalum ampoules. The compounds were investigated by means of powder and single crystal X-ray diffraction. All compounds crystallize in the ThCr{sub 2}Si{sub 2}-type structure with space group I4/mmm (No. 139): a=3.939(1) , c=10.185(1) , R{sub 1}=0.045, 85 F{sup 2} values, 8 variable parameters for CaFe{sub 2}Si{sub 2}; a=4.0590(2) , c=9.9390(8) , R{sub 1}=0.030, 90 F{sup 2} values, 10 variable parameters for CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}; a=4.0695(1) , c=9.9841(3) , R{sub 1}=0.031, 114 F{sup 2} values, 9 variable parameters for CaRh{sub 2}Si{sub 2}; and a=3.974(1) , c=10.395(1) , R{sub 1}=0.036, 95 F{sup 2} values, 8 variable parameters for SrCo{sub 2}Si{sub 2}. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} 2D-layers in the ab-plane whereas in CaFe{sub 2?x}Rh{sub x}Si{sub 2} the [T{sub 2}Si{sub 2}] layers (T=Fe and Rh) are interconnected along the c-axis via Si3Si bonds resulting in a three-dimentional (3D) [T{sub 2}Si{sub 2}]{sup 2?} polyanions and therefore belong to the so-called collapsed form of the ThCr{sub 2}Si{sub 2}-type structure. The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 ironpnictide superconductors AeFe{sub 2}As{sub 2} (Ae=alkaline earth elements), whereas CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of CaFe{sub 2}As{sub 2}. The crystal chemistry and chemical bonding in the title compounds are discussed in terms of LMTO band structure calculations and a topological analysis using the Electron Localization Function (ELF). - Graphical abstract: The SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x==0, 1.32, and 2) crystallize in the ThCr{sub 2}Si{sub 2}-type. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} layers in the ab-plane, whereas the [T{sub 2}Si{sub 2}] layers in CaFe{sub 2?x}Rh{sub x}Si{sub 2} are interconnected along the c-axis via Si3Si bonds resulting in a [T{sub 2}Si{sub 2}]{sup 2?} network. - Highlights: Synthesis and structure of ternary silicides SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2). The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 ironpnictide superconductors AeFe{sub 2}As{sub 2}. CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of superconductor CaFe{sub 2}As{sub 2}. The title compounds demonstrate the tunable Si3Si distances.

  20. The structure and reactivity of adsorbates on stepped Rh and Pt surfaces investigated by LEED, HREELS, TPD, XPS and STM

    SciTech Connect (OSTI)

    Batteas, J.D. |

    1995-06-01

    Defects on surfaces such as steps play an important role in surface chemistry. In order to obtain an understanding of the influence of steps in surface chemical reactions, the structure and reactivity of small molecules (O{sub 2}, CO, H{sub 2}S, and C{sub 2}H{sub 4}) on atomically stepped surfaces of RH and Pt have been investigated. The detailed structures of CO and oxygen bonded to the Rh(110) surface were determined. The CO molecules bond near the short bridge sites with the CO molecular axis tilted approximately 24{degree} from the surface normal. Oxygen atoms are bound asymmetrically in the 3-fold fcc hollow-sites to the (111) facets of the steps. The interactions of CO and oxygen on the Rh(311) surface were examined. The reaction of CO with the ordered phases of O shows two distinct reaction channels, a low temperature reaction limited channel (200 K) and a high temperature diffusion limited channel (350 K). Models of the reaction geometry and dynamics are proposed. The thermal decomposition of ethylene was examined on the Rh(311) surface. The stable decomposition species (C{sub 2}H, CH and C{sub 2}) are formed near 300 K, approximately 100 K lower on the stepped Rh(311) than on the flatter Rh(111) surface. The formation of these species at lower temperatures is attributed to the stepped nature of the surface. Finally, in situ STM was used to examine surface structural changes of a stepped Pt(111) crystal under coadsorption of sulfur and CO. This is the first direct evidence for a new mechanism by which a surface covered with an unreactive, strongly chemisorbed overlayer can form new sites, for bonding and reactions to occur, by massive surface restructuring at the step edges. This new surface phenomenon answers some of the puzzles of metal surface catalysis and its implications are described. 278 refs.

  1. Moisture Durability Assessment of Selected Well-insulated Wall Assemblies

    SciTech Connect (OSTI)

    Pallin, Simon B.; Boudreaux, Philip R.; Kehrer, Manfred; Hun, Diana E.; Jackson, Roderick K.; Desjarlais, Andre Omer

    2015-12-01

    This report presents the results from studying the hygrothermal performance of two well-insulated wall assemblies, both complying with and exceeding international building codes (IECC 2015 2014, IRC 2015). The hygrothermal performance of walls is affected by a large number of influential parameters (e.g., outdoor and indoor climates, workmanship, material properties). This study was based on a probabilistic risk assessment in which a number of these influential parameters were simulated with their natural variability. The purpose of this approach was to generate simulation results based on laboratory chamber measurements that represent a variety of performances and thus better mimic realistic conditions. In total, laboratory measurements and 6,000 simulations were completed for five different US climate zones. A mold growth indicator (MGI) was used to estimate the risk of mold which potentially can cause moisture durability problems in the selected wall assemblies. Analyzing the possible impact on the indoor climate due to mold was not part of this study. The following conclusions can be reached from analyzing the simulation results. In a hot-humid climate, a higher R-value increases the importance of the airtightness because interior wall materials are at lower temperatures. In a cold climate, indoor humidity levels increase with increased airtightness. Air leakage must be considered in a hygrothermal risk assessment, since air efficiently brings moisture into buildings from either the interior or exterior environment. The sensitivity analysis of this study identifies mitigation strategies. Again, it is important to remark that MGI is an indicator of mold, not an indicator of indoor air quality and that mold is the most conservative indicator for moisture durability issues.

  2. Moisture absorption results for vertical calciner plutonium dioxide product

    SciTech Connect (OSTI)

    Compton, J.A., Westinghouse Hanford

    1996-07-03

    A sample of calcined plutonium dioxide was exposed to room air for one week. The sample was weighed daily to determine if the material absorbed moisture from the room air. A random variation of weight was observed after the first day; however, the sample returned to its original weight at the end of the week. The loss on ignition for the material increased from 0.439 to 0.544 weight percent during this time. This change is considered inconsequential as the material will normally be packaged for storage within hours of its production.

  3. Summary of EXAFS results on Cd-doped PuRhIn5 (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Summary of EXAFS results on Cd-doped PuRhIn5 Citation Details In-Document Search Title: Summary of EXAFS results on Cd-doped PuRhIn5 Authors: Booth, C H ; Bauer, E D ; Tobin, J G Publication Date: 2014-06-12 OSTI Identifier: 1149554 Report Number(s): LLNL-TR-657137 DOE Contract Number: DE-AC52-07NA27344 Resource Type: Technical Report Research Org: Lawrence Livermore National Laboratory (LLNL), Livermore, CA Sponsoring Org: USDOE Country of Publication: United States Language:

  4. Ensemble Atmospheric Dispersion Modeling

    SciTech Connect (OSTI)

    Addis, R.P.

    2002-06-24

    Prognostic atmospheric dispersion models are used to generate consequence assessments, which assist decision-makers in the event of a release from a nuclear facility. Differences in the forecast wind fields generated by various meteorological agencies, differences in the transport and diffusion models, as well as differences in the way these models treat the release source term, result in differences in the resulting plumes. Even dispersion models using the same wind fields may produce substantially different plumes. This talk will address how ensemble techniques may be used to enable atmospheric modelers to provide decision-makers with a more realistic understanding of how both the atmosphere and the models behave.

  5. Temperature and moisture dependence of dielectric constant for silica aerogels

    SciTech Connect (OSTI)

    Hrubesh, L.H., LLNL

    1997-03-01

    The dielectric constants of silica aerogels are among the lowest measured for any solid material. The silica aerogels also exhibit low thermal expansion and are thermally stable to temperatures exceeding 500{degrees}C. However, due to the open porosity and large surface areas for aerogels, their dielectric constants are strongly affected by moisture and temperature. This paper presents data for the dielectric constants of silica aerogels as a function of moisture content at 25{degrees}C, and as a function of temperature, for temperatures in the range from 25{degrees}C to 450{degrees}C. Dielectric constant data are also given for silica aerogels that are heat treated in dry nitrogen at 500{degrees}C, then cooled to 25{degrees}C for measurements in dry air. All measurements are made on bulk aerogel spheres at 22GHz microwave frequency, using a cavity perturbation method. The results of the dependence found here for bulk materials can be inferred to apply also to thin films of silica aerogels having similar nano-structures and densities.

  6. Magnetism and superconductivity in U2PtxRh1-xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U₂PtxRh(1–x)C₂, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U₂Rh₂C₂ of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ≥ 0.9, with Tc increasing with increasing x. Themore » reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  7. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  8. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in amore » heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.« less

  9. ?ot8rh QI ahnloal Corporation In Hart IUnover, Ma86rohusett8,

    Office of Legacy Management (LM)

    GE 1 ;" qr)-1 s?llq ' p raspy.. c" ifa K. mris I talked with Hr. Wllllm cIF(Iy, Metrllurgist, Wnlon CarbId@ Nuclear cOrp8ny, 08k B&t&$@, Tenne66ee, on April 26, 1961. He informed me th&t the #rtioMl Northern birislon, Ame~ic6.n ?ot8rh QI ahnloal Corporation In Hart IUnover, Ma86rohusett8, la pePfopn1~ lo8lve forming studier for the. ilnion olo)w Wuolem Conpmy "p l7?JHa). The work at National Northern l#rirc.- alon ir under the 6upenl6lon of Ehsll Phillpohuc4~, v of

  10. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

    1988-01-01

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

  11. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, R.L.; Cannon, T.W.

    1988-10-25

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

  12. ARM - Measurement - Atmospheric temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric temperature The temperature indicated by a thermometer exposed to the air in a place sheltered from direct solar radiation. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list

  13. ARM - Measurement - Atmospheric turbulence

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    turbulence ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric turbulence High frequency velocity fluctuations that lead to turbulent transport of momentum, heat, mositure, and passive scalars, and often expressed in terms of variances and covariances. Categories Atmospheric State, Surface Properties Instruments The above measurement is considered scientifically relevant for the following

  14. ARM - Atmospheric Heat Budget

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ListAtmospheric Heat Budget Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Atmospheric Heat Budget The average temperature of the earth has remained approximately constant at about 15 degrees Celsius during the past century. It is therefore in a state of radiative balance, emitting the same

  15. Results of experimental tests and calibrations of the surface neutron moisture measurement probe

    SciTech Connect (OSTI)

    Watson, W.T.; Bussell, J.H., Westinghouse Hanford

    1996-08-13

    The surface neutron moisture probe has been tested both to demonstrate that is is able to operate in the expected in-tank temperature and gamma-ray fields and to provide detector responses to known moisture concentration materials. The probe will properly function in a simultaneous high temperature (80 degrees C) and high gamma radiation field (210 rad/hr)environment. Comparisons between computer model predicted and experimentally measured detector responses to changes in moisture provide a basis for the probe calibration to in-tank moisture concentrations.

  16. Method and apparatus for fuel gas moisturization and heating

    DOE Patents [OSTI]

    Ranasinghe, Jatila (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01

    Fuel gas is saturated with water heated with a heat recovery steam generator heat source. The heat source is preferably a water heating section downstream of the lower pressure evaporator to provide better temperature matching between the hot and cold heat exchange streams in that portion of the heat recovery steam generator. The increased gas mass flow due to the addition of moisture results in increased power output from the gas and steam turbines. Fuel gas saturation is followed by superheating the fuel, preferably with bottom cycle heat sources, resulting in a larger thermal efficiency gain compared to current fuel heating methods. There is a gain in power output compared to no fuel heating, even when heating the fuel to above the LP steam temperature.

  17. Building America Top Innovations 2012: Moisture and Ventilation Solutions in Hot, Humid Climates: Florida Manufactured Housing

    SciTech Connect (OSTI)

    none,

    2013-01-01

    This Building America Top Innovations profile describes work by Building America researchers who visited 24 manufactured home factories between 1996 and 2003 to investigate moisture problems while improving energy efficiency and identified insufficient air sealing and poor HVAC installation as the biggest culprits. One manufacturer reported zero moisture-related issues in 35,000 homes built after implementing Building America recommendations.

  18. NEC Hazardous classification and compliance regarding the surface moisture monitor measurement system

    SciTech Connect (OSTI)

    Bussell, J.H., WHC

    1996-06-12

    The National Electrical Code, NFPA 70, and National Fire Protection Association requirements for use of Surface Moisture Monitor Systems in classified locations are discussed. The design and configuration of the surface moisture monitor are analyzed with respect to how they comply with requirements of the National Electrical Code requirements, articles 500-504.

  19. Moisture and Ventilation Solutions in Hot, Humid Climates: Florida Manufactured Housing- Building America Top Innovation

    Broader source: Energy.gov [DOE]

    This Building America Innovations profile describes work by Building America researchers who visited 24 manufactured home factories between 1996 and 2003 to investigate moisture problems while improving energy efficiency and identified insufficient air sealing and poor HVAC installation as the biggest culprits. One manufacturer reported zero moisture-related issues in 35,000 homes built after implementing Building America recommendations.

  20. Mechanistic aspects of [Rh(nbd)CI][sub 2]initiated oligomerization of new acetylenic monomers

    SciTech Connect (OSTI)

    Densmore, C.G. (Crystal G); Rasmussen, P.G. (Paul G.)

    2004-01-01

    Although a number of papers report the use of rhodium-based initiators, very little has been said about the mechanism of acetylene polymerizations. Kishimoto and coworkers recently proposed an insertion mechanism for the rhodium-initiated polymerization of phenylacetylenes. The initiator consisted of the tetracoordinate rhodium complex, Rh(C{triple_bond}CC{sub 6}H{sub 5})(nbd)(PPh{sub 3}) with 4-(dimethylamino)-pyidine. The product was found to be stereoregular poly(phenylacety1ene) with a cis-transoidal backbone microstructure. Gorman and coworkers found palladium and nickel-based catalysts to be successful in the polymerization of cyanoacetylene. Zhan and Yang addressed the polymerization mechanism of acetylenes using palladium and nickel acetylide catalysts. They propose that the initial activation step, and also the rate-determining step, involve coordination of a nickel or palladium acetylide catalyst with an acetylene. Based on NMR and elemental analysis, we propose a more complete mechanistic picture of acetylene polymerizations, especially those with electron-withdrawing substituents.

  1. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Kowal, A.; Li, M; Shao, M; Sasaki, K; Vukmirovic, M; Zhang, J; Marinkovic, N; Liu, P; Frenkel, A; Adzic, R

    2009-01-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts1, 2. We synthesized a ternary PtRhSnO2/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO2, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  2. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Adzic, R.R.; Kowal, A.; Li, M.; Shao, M.; Sasaki, K.; Vukmirovic, M.B.; Zhang, J.; Marinkovic, N.S. Liu, P.; Frenkel, A.I.

    2009-04-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts. We synthesized a ternary PtRhSnO{sub 2}/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO{sub 2}, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  3. Magnetism and superconductivity in U?PtxRh(1x)C?

    SciTech Connect (OSTI)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.

  4. Safety evaluation for packaging (onsite) for the concrete-shielded RH TRU drum for the 327 Postirradiation Testing Laboratory

    SciTech Connect (OSTI)

    Smith, R.J.

    1998-03-31

    This safety evaluation for packaging authorizes onsite transport of Type B quantities of radioactive material in the Concrete Shielded Remote-Handled Transuranic Waste (RH TRU) Drum per HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments. The drum will be used for transport of 327 Building legacy waste from the 300 Area to a solid waste storage facility on the Hanford Site.

  5. Excited states in {sup 115}Pd populated in the {beta}{sup -} decay of {sup 115}Rh

    SciTech Connect (OSTI)

    Kurpeta, J.; Plochocki, A. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Urban, W. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Institut Laue-Langevin, 6 rue J. Horowitz, F-38042 Grenoble (France); Rissanen, J.; Eronen, T.; Hakala, J.; Jokinen, A.; Kankainen, A.; Karvonen, P.; Moore, I. D.; Penttilae, H.; Saastamoinen, A.; Weber, C.; Aeystoe, J. [Department of Physics, University of Jyvaeskylae, P.O. Box 35, FIN-40351, Jyvaeskylae (Finland); Elomaa, V.-V. [Turku PET Centre, Accelerator Laboratory, Abo Akademi University, FIN-20500 Turku (Finland); Rahaman, S. [Physics Division, P-23, Mail Stop H803, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Sonoda, T. [Nishina Center for Accelerator Based Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Szerypo, J. [Fakultaet fuer Physik, Ludwig-Maximilians-Universitaet Muenchen, Am Coulombwall 1, D-85748 Garching (Germany)

    2010-08-15

    Excited states in {sup 115}Pd, populated following the {beta}{sup -} decay of {sup 115}Rh have been studied by means of {gamma} spectroscopy after the Penning-trap station at the IGISOL facility, University of Jyvaeskylae. The 1/2{sup +} spin and parity assignment of the ground state of {sup 115}Pd, confirmed in this work, may indicate a transition to an oblate shape in Pd isotopes at high neutron number.

  6. Synthesis and crystal structure of two new cerium rhodium oxides: Ce{sub 2/3-x}Rh{sup 3+}{sub 2}O{sub 4} (x{approx}0.12) with Ce mixed valency and Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Mizoguchi, Hiroshi; Zakharov, L.N.; Bhuvanesh, N.S.P.; Sleight, A.W.; Subramanian, M.A.

    2011-06-15

    The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared. Their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Based on the structural analysis and physical properties, oxidation states for CeRh{sub 2}O{sub 5} can be assigned as Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}. A small variation in x was detected for Ce{sub 2/3-x}Rh{sub 2}O{sub 4} indicating a formula ranging from Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}. - Graphical abstract: The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared and their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Highlights: > The new compounds CeRh{sub 2}O{sub 5} and Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) have been prepared. > Their structures were determined from single crystal X-ray diffraction data. > Valence picture is Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5} and Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}.

  7. Agriculture intensifies soil moisture decline in Northern China

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Yaling; Pan, Zhihua; Zhuang, Qianlai; Miralles, Diego; Teuling, Adriann; Zhang, Tonglin; An, Pingli; Dong, Zhiqiang; Zhang, Jingting; He, Di; et al

    2015-07-09

    Northern China is one of the most densely populated regions in the world. Agricultural activities have intensified since the 1980s to provide food security to the country. However, this intensification has likely contributed to an increasing scarcity in water resources, which may in turn be endangering food security. Based on in-situ measurements of soil moisture collected in agricultural plots during 1983–2012, we find that topsoil (0–50 cm) volumetric water content during the growing season has declined significantly (p<0.01), with a trend of -0.011 to -0.015 m3 m-3 per decade. Observed discharge declines for the three large river basins are consistentmore » with the effects of agricultural intensification, although other factors (e.g. dam constructions) likely have contributed to these trends. Practices like fertilizer application have favoured biomass growth and increased transpiration rates, thus reducing available soil water. In addition, the rapid proliferation of water-expensive crops (e.g., maize) and the expansion of the area dedicated to food production have also contributed to soil drying. Adoption of alternative agricultural practices that can meet the immediate food demand without compromising future water resources seem critical for the sustainability of the food production system.« less

  8. Agriculture intensifies soil moisture decline in Northern China

    SciTech Connect (OSTI)

    Liu, Yaling; Pan, Zhihua; Zhuang, Qianlai; Miralles, Diego; Teuling, Adriann; Zhang, Tonglin; An, Pingli; Dong, Zhiqiang; Zhang, Jingting; He, Di; Wang, Liwei; Pan, Xuebiao; Bai, Wei; Niyogi, Dev

    2015-07-09

    Northern China is one of the most densely populated regions in the world. Agricultural activities have intensified since the 1980s to provide food security to the country. However, this intensification has likely contributed to an increasing scarcity in water resources, which may in turn be endangering food security. Based on in-situ measurements of soil moisture collected in agricultural plots during 1983–2012, we find that topsoil (0–50 cm) volumetric water content during the growing season has declined significantly (p<0.01), with a trend of -0.011 to -0.015 m3 m-3 per decade. Observed discharge declines for the three large river basins are consistent with the effects of agricultural intensification, although other factors (e.g. dam constructions) likely have contributed to these trends. Practices like fertilizer application have favoured biomass growth and increased transpiration rates, thus reducing available soil water. In addition, the rapid proliferation of water-expensive crops (e.g., maize) and the expansion of the area dedicated to food production have also contributed to soil drying. Adoption of alternative agricultural practices that can meet the immediate food demand without compromising future water resources seem critical for the sustainability of the food production system.

  9. Features of conduction mechanisms in n-HfNiSn semiconductor heavily doped with a Rh acceptor impurity

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Stadnyk, Yu. V.; Romaka, V. V.; Hlil, E. K.; Krajovskii, V. Ya.; Horyn, A. M.

    2013-09-15

    The crystal structure and electron-density distribution, as well as the energy, kinetic, and magnetic characteristics of n-HfNiSn intermetallic semiconductor heavily doped with a Rh acceptor impurity in the temperature range T = 80-400 K, in the acceptor-concentration range N{sub A}{sup Rh} Almost-Equal-To 9.5 Multiplication-Sign 10{sup 19}-1.9 Multiplication-Sign 10{sup 21} cm{sup -3} (x = 0.005-0.10), and in magnetic fields H {<=} 10 kG are investigated. It is established that doping is accompanied by a simultaneous decrease in concentration, the elimination of donor-type structural defects (to x Almost-Equal-To 0.02), and an increase in the concentration of acceptor-type structural defects (0 < x {<=} 0.10). The dependence of the degree of semiconductor compensation on temperature is revealed. A model of the spatial arrangement of atoms in HfNi{sub 1-x}Rh{sub x}Sn is proposed, and the results of calculating the electron structure based on this model agree with the results of investigations of the kinetic and magnetic characteristics of the semiconductor. The results are discussed within the context of the Shklovskii-Efros model for a heavily doped and compensated semiconductor.

  10. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 Kmore » with an ordered moment of μsat = 0.8 μB for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.« less

  11. Development of the prototype Munitions Case Moisture Meter, Model ORNL-1

    SciTech Connect (OSTI)

    Agouridis, D.C.; Gayle, T.M.; Griest, W.H.

    1993-02-24

    There is a great need for a rapid and simple means of determining the moisture content in combustible cartridge case (ccc) munitions. Previous studies have demonstrated that accumulation of moisture in ccc rounds, such as the M829, leads to softening of the case wall and weakening of the adhesive joint. Moisture in the ccc can lead to incomplete combustion of the case upon firing the round. Currently, there are no facile methods for measuring the moisture content. A prototype portable meter for non-destructive and rapid estimation of moisture in ccc has been developed. The Munitions Case Moisture Meter Model ORNL-1 demonstrates the feasibility of developing an instrument based on the moisture dependence of dielectric properties, to measure moisture in ccc munitions in storage and in the field. These instruments are simple, inexpensive, lightweight, portable, low-power battery operated, and intrinsically safe. They provide nondestructive, noninvasive, and rapid measurements. Calibration data for the prototype are not available at this time. Therefore, calibration of the meter and the development of a scale reading directly moisture content in munitions rounds could not be completed. These data will be supplied by the US Army from its tests of the meter with actual munitions. However, experimental results on empty cccs in laboratory conditions demonstrate satisfactory performance of the instrument. Additional work is needed to bring the prototype to its optimum usefulness and accuracy for field measurements. This includes: Calibration of the meter scale with full-up munitions; Data and evaluation procedures to adjust the performance of the meter for different environmental conditions such as temperature and humidity; and Studies of the dielectric properties of moist ccc materials, as a function of frequency and temperature, are needed for adjustment of the meter for optimal performance.

  12. Development of the prototype Munitions Case Moisture Meter, Model ORNL-1. Final report

    SciTech Connect (OSTI)

    Agouridis, D.C.; Gayle, T.M.; Griest, W.H.

    1993-02-24

    There is a great need for a rapid and simple means of determining the moisture content in combustible cartridge case (ccc) munitions. Previous studies have demonstrated that accumulation of moisture in ccc rounds, such as the M829, leads to softening of the case wall and weakening of the adhesive joint. Moisture in the ccc can lead to incomplete combustion of the case upon firing the round. Currently, there are no facile methods for measuring the moisture content. A prototype portable meter for non-destructive and rapid estimation of moisture in ccc has been developed. The Munitions Case Moisture Meter Model ORNL-1 demonstrates the feasibility of developing an instrument based on the moisture dependence of dielectric properties, to measure moisture in ccc munitions in storage and in the field. These instruments are simple, inexpensive, lightweight, portable, low-power battery operated, and intrinsically safe. They provide nondestructive, noninvasive, and rapid measurements. Calibration data for the prototype are not available at this time. Therefore, calibration of the meter and the development of a scale reading directly moisture content in munitions rounds could not be completed. These data will be supplied by the US Army from its tests of the meter with actual munitions. However, experimental results on empty cccs in laboratory conditions demonstrate satisfactory performance of the instrument. Additional work is needed to bring the prototype to its optimum usefulness and accuracy for field measurements. This includes: Calibration of the meter scale with full-up munitions; Data and evaluation procedures to adjust the performance of the meter for different environmental conditions such as temperature and humidity; and Studies of the dielectric properties of moist ccc materials, as a function of frequency and temperature, are needed for adjustment of the meter for optimal performance.

  13. Reactivity of liquid and semisolid secondary organic carbon with chloride and nitrate in atmospheric aerosols

    SciTech Connect (OSTI)

    Wang, Bingbing; O'Brien, Rachel E.; Kelly, Stephen T.; Shilling, John E.; Moffet, Ryan C.; Gilles, Mary K.; Laskin, Alexander

    2015-05-14

    Constituents of secondary organic carbon (SOC) in atmospheric aerosols are often mixed with inorganic components and compose a significant mass fraction of fine particulate matter in the atmosphere. Interactions between SOC and other condensed-phase species are not well understood. Here, we investigate the reactions of liquid-like and semi-solid SOC from ozonolysis of limonene (LSOC) and ?-pinene (PSOC) with NaCl using a set of complementary micro-spectroscopic analyses. These reactions result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions attributed to acid displacement by SOC acidic components are driven by the high volatility of HCl. Similar reactions can take place in SOC/NaNO? particles. The results show that an increase in SOC mass fraction in the internally mixed SOC/NaCl particles leads to higher chloride depletion. Glass transition temperatures and viscosity of PSOC were estimated for atmospherically relevant conditions. Data show that the reaction extent depends on SOC composition, particle phase state and viscosity, mixing state, temperature, relative humidity (RH), and reaction time. LSOC shows slightly higher potential to deplete chloride than PSOC. Higher particle viscosity at low temperatures and RH can hinder these acid displacement reactions. Formation of organic salts from these overlooked reactions can alter particle physiochemical properties and may affect their reactivity and ability to act as cloud condensation and ice nuclei. The release and potential recycling of HCl and HNO? from reacted aerosol particles may have important implications for atmospheric chemistry.

  14. ARM - Evolution of the Atmosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ListEvolution of the Atmosphere Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Evolution of the Atmosphere The earth's atmosphere plays a crucial role in shaping the weather, climate, and life-supporting systems. However, the ocean and atmosphere are the earth's fluid outer layers and are

  15. ARM - Composition of the Atmosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ListComposition of the Atmosphere Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Composition of the Atmosphere The atmosphere is 1000 kilometers above mean sea level. In fact, only about 1 percent of the total mass of the atmosphere is above an altitude of approximately 30 kilometers above

  16. Spin-orbit tuned metal-insulator transitions in single-crystal Sr?Ir1xRhxO? (0?x?1)

    SciTech Connect (OSTI)

    Qi, T. F.; Korneta, O. B.; Li, L.; Butrouna, K.; Cao, V. S.; Wan, Xiangang; Schlottmann, P.; Kaul, R. K.; Cao, G.

    2012-09-06

    Sr?IrO? is a magnetic insulator driven by spin-orbit interaction (SOI) whereas the isoelectronic and isostructural Sr?RhO? is a paramagnetic metal. The contrasting ground states have been shown to result from the critical role of the strong SOI in the iridate. Our investigation of structural, transport, magnetic, and thermal properties reveals that substituting 4d Rh?? (4d?) ions for 5d Ir?? (5d?) ions in Sr?IrO? directly reduces the SOI and rebalances the competing energies so profoundly that it generates a rich phase diagram for Sr?Ir1xRhxO? featuring two major effects: (1) Light Rh doping (0 ? x ? 0.16) prompts a simultaneous and precipitous drop in both the electrical resistivity and the magnetic ordering temperature TC, which is suppressed to zero at x = 0.16 from 240 K at x = 0. (2) However, with heavier Rh doping [0.24 < x < 0.85 (0.05)] disorder scattering leads to localized states and a return to an insulating state with spin frustration and exotic magnetic behavior that only disappears near x = 1. The intricacy of Sr?Ir1xRhxO? is further highlighted by comparison with Sr?Ir1xRuxO? where Ru?? (4d?) drives a direct crossover from the insulating to metallic states.

  17. Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers

    SciTech Connect (OSTI)

    Oostrom, Martinus; Smoot, Katherine V.; Wietsma, Thomas W.; Truex, Michael J.; Benecke, Mark W.; Chronister, Glen B.

    2012-11-19

    Super-absorbent polymers (SAPs) have the potential to remove water and associated contaminants from unsaturated sediments in the field. Column and flow cell experiment were conducted to test the ability of four types of SAPs to remove water from unsaturated porous media. Column experiments, with emplacement of a layer of polymer on top of unsaturated porous media, showed the ability of the SAPs to extract up to 80% of the initially emplaced water against gravity into the sorbent over periods up to four weeks. In column experiments where the sorbent was emplaced between layers of unsaturated porous media, gel formation was observed at both the sorbent-porous medium interfaces. The extraction percentages over four weeks of contact time were similar for both column configurations and no obvious differences were observed for the four tested SAPs. Two different flow cells were used to test the wicking behavior of SAPs in two dimensions using three configurations. The largest removal percentages occurred for the horizontal sorbent layer configuration which has the largest sorbent-porous medium interfacial area. In a larger flow cell, a woven nylon sock was packed with sorbent and subsequently placed between perforated metal plates, mimicking a well configuration. After one week of contact time the sock was removed and replaced by a fresh sock. The results of this experiment showed that the sorbent was able to continuously extract water from the porous media, although the rate decreased over time. The declining yield during both periods is associated with the sharp reduction in water saturation and relative permeability near the sorbent. It was also observed that the capillary pressure continued to increase over the total contact time of 14 days, indicating that the sorbent remained active over that period. This work has demonstrated the potential of soil moisture wicking using SAPs at the proof-of-principle level.

  18. Moisture sensor based on evanescent wave light scattering by porous sol-gel silica coating

    DOE Patents [OSTI]

    Tao, Shiquan; Singh, Jagdish P.; Winstead, Christopher B.

    2006-05-02

    An optical fiber moisture sensor that can be used to sense moisture present in gas phase in a wide range of concentrations is provided, as well techniques for making the same. The present invention includes a method that utilizes the light scattering phenomenon which occurs in a porous sol-gel silica by coating an optical fiber core with such silica. Thus, a porous sol-gel silica polymer coated on an optical fiber core forms the transducer of an optical fiber moisture sensor according to an embodiment. The resulting optical fiber sensor of the present invention can be used in various applications, including to sense moisture content in indoor/outdoor air, soil, concrete, and low/high temperature gas streams.

  19. BTO Awards Small Business Grants for Lighting, Building-Integrated Heat and Moisture Exchange Technology

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy Office of Science has awarded four Small Business Innovation Research (SBIR) grants targeting advances in solid-state lighting (SSL) and building-integrated heat and moisture exchange technology.

  20. Moisture exposure to different layers in organic light-emitting diodes and the effect on electroluminescence characteristics

    SciTech Connect (OSTI)

    Liao, L. S.; Tang, C. W.

    2008-08-15

    Moisture effect on electroluminescence characteristics, including current density versus voltage, luminance versus voltage, luminous efficiency versus current density, dark spot formation, and operational stability of organic light-emitting diodes, has been systematically investigated by exposing each layer of the devices to moisture at room temperature. Moisture has a different effect on each of the interfaces or surfaces, and the influence increases as exposure time increases. There is a slight effect on the electroluminescence characteristics after the anode surface has been exposed to moisture. However, severe luminance decrease, dark spot formation, and operational stability degradation take place after the light-emitting layer or the electron-transporting layer is exposed to moisture. It is also demonstrated that the effect of moisture can be substantially reduced if the exposure to moisture is in a dark environment.

  1. Monitoring of Double-Stud Wall Moisture Conditions in the Northeast

    SciTech Connect (OSTI)

    Ueno, K.

    2015-03-01

    Double-stud walls insulated with cellulose or low-density spray foam can have R-values of 40 or higher. However, double-stud walls have a higher risk of interior-sourced condensation moisture damage when compared with high-R approaches using exterior insulating sheathing. Moisture conditions in double-stud walls were monitored in Zone 5A (Massachusetts); three double-stud assemblies were compared.

  2. Modifications to WRFs dynamical core to improve the treatment of moisture

    Office of Scientific and Technical Information (OSTI)

    for large-eddy simulations (Journal Article) | SciTech Connect Journal Article: Modifications to WRFs dynamical core to improve the treatment of moisture for large-eddy simulations Citation Details In-Document Search Title: Modifications to WRFs dynamical core to improve the treatment of moisture for large-eddy simulations Yamaguchi and Feingold (2012) note that the cloud fields in their large-eddy simulations (LESs) of marine stratocumulus using the Weather Research and Forecasting (WRF)

  3. Measurements of structural and chemical order in Zr80Pt20 and Zr77Rh23 liquids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, M. L.; Blodgett, M. E.; Lokshin, K. A.; Mauro, N. A.; Neuefeind, J.; Pueblo, C.; Quirinale, D. G.; Vogt, A. J.; Egami, T.; Goldman, A. I.; et al

    2016-02-03

    In this study, the short-range order (SRO) and medium-range order of electrostatically levitated Zr80Pt20 and Zr77Rh23 liquids are presented founded on a combination of high-energy x-ray diffraction and time-of-flight neutron diffraction studies. The atomic structures of the Zr80Pt20 liquids were determined as a function of temperature from constrained reverse Monte Carlo simulations using x-ray and elastic neutron scattering measurements and two partial pair-distribution functions obtained from molecular dynamics (MD) simulations.

  4. Atmospheric Radiation Measurement Climate Research Facility ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Radiation Measurement Climate Research Facility Argonne scientists study ... for climate research to the Atmospheric Radiation Measurement (ARM) Climate Research ...

  5. Atmospheric Radiation Measurement Climate Research Facility ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Radiation Measurement Climate Research Facility (ARM) Biological and ... BER Home About Research Facilities User Facilities Atmospheric Radiation Measurement ...

  6. FINAL REPORT FOR MOISTURE EFFECTS ON COMPACTION OF FIBERBOARD IN A 9975 SHIPPING PACKAGE

    SciTech Connect (OSTI)

    Stefek, T.; Daugherty, W.; Estochen, E.

    2013-09-17

    Compaction of lower layers in the fiberboard assembly has been observed in 9975 packages that contain elevated moisture. Lab testing has resulted in a better understanding of the relationship between the fiberboard moisture level and compaction of the lower fiberboard assembly, and the behavior of the fiberboard during transport. In laboratory tests of cane fiberboard, higher moisture content has been shown to correspond to higher total compaction, greater rate of compaction, and continued compaction over a longer period of time. In addition, laboratory tests have shown that the application of a dynamic load results in higher fiberboard compaction compared to a static load. The test conditions and sample geometric/loading configurations were chosen to simulate the regulatory requirements for 9975 package input dynamic loading. Dynamic testing was conducted to acquire immediate and cumulative changes in geometric data for various moisture levels. Two sample sets have undergone a complete dynamic test regimen, one set for 27 weeks, and the second set for 47 weeks. The dynamic input, data acquisition, test effects on sample dynamic parameters, and results from this test program are summarized and compared to regulatory specifications for dynamic loading. Compaction of the bottom fiberboard layers due to the accumulation of moisture is one possible cause of an increase in the axial gap at the top of the package. The net compaction of the bottom layers will directly add to the axial gap. The moisture which caused this compaction migrated from the middle region of the fiberboard assembly (which is typically the hottest). This will cause the middle region to shrink axially, which will also contribute directly to the axial gap. Measurement of the axial gap provides a screening tool for identifying significant change in the fiberboard condition. The data in this report provide a basis to evaluate the impact of moisture and fiberboard compaction on 9975 package performance during storage at the Savannah River Site (SRS).

  7. Using Whole-House Field Tests to Empirically Derive Moisture Buffering Model Inputs

    SciTech Connect (OSTI)

    Woods, J.; Winkler, J.; Christensen, D.; Hancock, E.

    2014-08-01

    Building energy simulations can be used to predict a building's interior conditions, along with the energy use associated with keeping these conditions comfortable. These models simulate the loads on the building (e.g., internal gains, envelope heat transfer), determine the operation of the space conditioning equipment, and then calculate the building's temperature and humidity throughout the year. The indoor temperature and humidity are affected not only by the loads and the space conditioning equipment, but also by the capacitance of the building materials, which buffer changes in temperature and humidity. This research developed an empirical method to extract whole-house model inputs for use with a more accurate moisture capacitance model (the effective moisture penetration depth model). The experimental approach was to subject the materials in the house to a square-wave relative humidity profile, measure all of the moisture transfer terms (e.g., infiltration, air conditioner condensate) and calculate the only unmeasured term: the moisture absorption into the materials. After validating the method with laboratory measurements, we performed the tests in a field house. A least-squares fit of an analytical solution to the measured moisture absorption curves was used to determine the three independent model parameters representing the moisture buffering potential of this house and its furnishings. Follow on tests with realistic latent and sensible loads showed good agreement with the derived parameters, especially compared to the commonly-used effective capacitance approach. These results show that the EMPD model, once the inputs are known, is an accurate moisture buffering model.

  8. ARM - Sources of Atmospheric Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sources of Atmospheric Carbon Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Sources of Atmospheric Carbon Atmospheric carbon represented a steady state system, where influx equaled outflow, before the Industrial Revolution. Currently, it is no longer a steady state system because the

  9. NETL SOFC: Atmospheric Pressure Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Pressure Systems ATMOSPHERIC PRESSURE SYSTEMS (INDUSTRY TEAMS)-This key technology focuses on the design, scaleup, and integration of the SOFC technology, ultimately resulting in atmospheric-pressure modules suitable to serve as the building blocks for distributed-generation, commercial, and utility-scale power systems. Activities include fabrication, testing, post-test analysis of cells; integrating cells into stacks; and the development and validation testing of progressively

  10. ARM - Destination of Atmospheric Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Destination of Atmospheric Carbon Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Destination of Atmospheric Carbon Oceans: 92 gigatonnes [(Gt) 1 gigatonne = 1x1012 kilograms] are recycled annually from the atmosphere to the oceans. This carbon is used for biosynthesis or remains dissolved

  11. Perovskite LaRhO{sub 3} as a p-type active layer in oxide photovoltaics

    SciTech Connect (OSTI)

    Nakamura, Masao Krockenberger, Yoshiharu; Fujioka, Jun; Kawasaki, Masashi; Tokura, Yoshinori

    2015-02-16

    Perovskite-type transition-metal oxides have a wide variety of physical properties and triggered intensive research on functional devices in the form of heteroepitaxial junctions. However, there is a missing component that is a p-type conventional band semiconductor. LaRhO{sub 3} (LRO) is one of very few promising candidates having its bandgap between filled t{sub 2g} and empty e{sub g} of Rh in low-spin state, but there has been no report on the synthesis of large-size single crystals or thin films. Here, we report on the junction properties of single-crystalline thin films of LRO grown on (110) oriented Nb-doped SrTiO{sub 3} substrates. The external quantum efficiency of the photo-electron conversion exceeds 1% in the visible-light region due to the wide depletion layer and long diffusion length of minority carriers in LRO. Clear indication of p-type band semiconducting character in a perovskite oxide of LRO will pave a way to explore oxide electronics of perovskite heterostructures.

  12. Effect of residential air-to-air heat and moisture exchangers on indoor humidity

    SciTech Connect (OSTI)

    Barringer, C.G.; McGugan, C.A. )

    1989-01-01

    A project was undertaken to develop guidelines for the selection of residential heat and moisture recovery ventilation systems (HRVs) in order to maintain an acceptable indoor humidity for various climatic conditions. These guidelines were developed from reviews on ventilation requirements, HRV performance specifications, and from computer modeling. Space conditions within three house/occupancy models for several types of HRV were simulated for three climatic conditions (Lake Charles, LA; Seattle, WA; and Winnipeg, MB) in order to determine the impact of the HRVs on indoor relative humidity and space-conditioning loads. Results show that when reduction of cooling cost is the main consideration, exchangers with moisture recovery are preferable to sensible HRVs. For reduction of heating costs, moisture recovery should be done for ventilation rates greater than about 15 L/s and average winter temperatures less than about (minus) 10{degrees}C if internal moisture generation rates are low. For houses with higher ventilation rates and colder average winter temperatures, exchangers with moisture recovery should be used.

  13. Polyport atmospheric gas sampler

    DOE Patents [OSTI]

    Guggenheim, S. Frederic (Teaneck, NJ)

    1995-01-01

    An atmospheric gas sampler with a multi-port valve which allows for multi, sequential sampling of air through a plurality of gas sampling tubes mounted in corresponding gas inlet ports. The gas sampler comprises a flow-through housing which defines a sampling chamber and includes a gas outlet port to accommodate a flow of gases through the housing. An apertured sample support plate defining the inlet ports extends across and encloses the sampling chamber and supports gas sampling tubes which depend into the sampling chamber and are secured across each of the inlet ports of the sample support plate in a flow-through relation to the flow of gases through the housing during sampling operations. A normally closed stopper means mounted on the sample support plate and operatively associated with each of the inlet ports blocks the flow of gases through the respective gas sampling tubes. A camming mechanism mounted on the sample support plate is adapted to rotate under and selectively lift open the stopper spring to accommodate a predetermined flow of gas through the respective gas sampling tubes when air is drawn from the housing through the outlet port.

  14. Low-temperature conversion of high-moisture biomass: Topical report, January 1984--January 1988

    SciTech Connect (OSTI)

    Sealock, L.J. Jr.; Elliott, D.C.; Butner, R.S.; Neuenschwander, G.G.

    1988-10-01

    Pacific Northwest Laboratory (PNL) is developing a low-temperature, catalytic process that converts high-moisture biomass feedstocks and other wet organic substances to useful gaseous and liquid fuels. The advantage of this process is that it works without the need for drying or dewatering the feedstock. Conventional thermal gasification processes, which require temperatures above 750/degree/C and air or oxygen for combustion to supply reaction heat, generally cannot utilize feedstocks with moisture contents above 50 wt %, as the conversion efficiency is greatly reduced as a result of the drying step. For this reason, anaerobic digestion or other bioconversion processes traditionally have been used for gasification of high-moisture feedstocks. However, these processes suffer from slow reaction rates and incomplete carbon conversion. 50 refs., 21 figs., 22 tabs.

  15. ANALYSIS OF THE AXIAL GAP VS FIBERBOARD MOISTURE CONTENT IN A 9975 SHIPPING PACKAGE

    SciTech Connect (OSTI)

    Daugherty, W.

    2013-09-30

    The fiberboard assembly within a 9975 shipping package contains a modest amount of moisture, which can migrate to the cooler regions of the package when an internal heat load is present. Typically, this leads to increased moisture levels in the bottom fiberboard layers, along with elevated chloride levels which can leach from the fiberboard. Concerns have been raised that this condition could lead to corrosion of the stainless steel drum. It has been postulated that checking the axial gap at the top of the package against the current 1 inch maximum criterion provides a sufficient indication regarding the integrity of the fiberboard and drum. This report estimates the increase in axial gap that might be expected for a given moisture increase in the bottom fiberboard layers, and the likelihood that the increase will create a nonconforming condition that will lead to identification of the moisture increase. Using data relating the fiberboard moisture content with the degree of compaction under load, the present analysis indicates that the axial gap will increase by 0.282 inch as the bottom fiberboard layers approach the saturation point. This increase will cause approximately 58% of packages with otherwise nominal package component dimensions to fail the axial gap criterion, based on a survey of axial gap values recorded in K-Area surveillance activities. As the moisture content increases above saturation, the predicted increase in axial gap jumps to 0.405 inch, which would result in 92% or more of all packages failing the axial gap criterion. The data and analysis described in this report are specific to cane fiberboard. While it is expected that softwood fiberboard will behave similarly, such behavior has not yet been demonstrated.

  16. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    SciTech Connect (OSTI)

    Masud, Jahangir; Nguyena, Trung V.; Singh, Nirala; McFarland, Eric; Ikenberry, Myles; Hohn, Keith; Pan, Chun-Jern; Hwang, Bing-Joe

    2015-01-01

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600C to 850C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchange current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.

  17. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study

    SciTech Connect (OSTI)

    Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

    2014-07-01

    In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850C. Turnover rate at 850C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

  18. Measurement of Moisture Outgassing of the Plastic-Bonded TATB Explosive

    Office of Scientific and Technical Information (OSTI)

    LX-17 (Journal Article) | SciTech Connect Measurement of Moisture Outgassing of the Plastic-Bonded TATB Explosive LX-17 Citation Details In-Document Search Title: Measurement of Moisture Outgassing of the Plastic-Bonded TATB Explosive LX-17 Authors: Small, W ; Glascoe, E A ; Overturf, G E Publication Date: 2012-02-15 OSTI Identifier: 1093404 Report Number(s): LLNL-JRNL-530535 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal Article Resource Relation: Journal Name: Thermochimica

  19. Characterization of extreme precipitation within atmospheric river events over California

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeon, S.; Prabhat,; Byna, S.; Gu, J.; Collins, W. D.; Wehner, M. F.

    2015-11-17

    Atmospheric rivers (ARs) are large, spatially coherent weather systems with high concentrations of elevated water vapor. These systems often cause severe downpours and flooding over the western coastal United States – and with the availability of more atmospheric moisture in the future under global warming we expect ARs to play an important role as potential causes of extreme precipitation changes. Therefore, we aim to investigate changes in extreme precipitation properties correlated with AR events in a warmer climate, which are large-scale meteorological patterns affecting the weather and climate of California. We have recently developed the TECA (Toolkit for Extreme Climatemore » Analysis) software for automatically identifying and tracking features in climate data sets. Specifically, we can now identify ARs that make landfall on the western coast of North America. Based on this detection procedure, we can investigate the impact of ARs by exploring the spatial extent of AR precipitation using climate model (CMIP5) simulations and characterize spatial patterns of dependence for future projections between AR precipitation extremes under climate change within the statistical framework. Our results show that AR events in the future RCP (Representative Concentration Pathway)8.5 scenario (2076–2100) tend to produce heavier rainfall with higher frequency and longer days than events from the historical run (1981–2005). We also find that the dependence between extreme precipitation events has a shorter spatial range, within localized areas in California, under the high future emissions scenario than under the historical run.« less

  20. Effect of magnetic fields on the Kondo insulator CeRhSb: Magnetoresistance and high-field heat capacity measurements

    SciTech Connect (OSTI)

    Malik, S.K.; Menon, L.; Pecharsky, V.K.; Gschneidner, K.A. Jr.

    1997-05-01

    The compound CeRhSb is a mixed valent Ce-based compound which shows a gap in the electronic density of states at low temperatures. The gap manifests by a rise in electrical resistivity{emdash}below about 8 K from which the gap energy is estimated to be about 4 K. We have carried out heat capacity measurements on this compound in various applied fields up to 9.85 T. The magnetic contribution to the heat capacity, {Delta}C, is found to have a maximum in {Delta}C/T vs T at 10 K, below which {Delta}C/T is linear with T. This is attributed to the fact that below this temperature, in the gapped state, the electronic density of states decreases linearly with decreasing temperature. On application of a magnetic field, the electronic specific heat coefficient {gamma} in the gapped state increases by {approximately}4mJ/molK{sup 2}. The maximum in {Delta}C/T vs T is observed in all fields, which shifts to lower temperatures {approximately}1K at 5.32 T and raises again at 9.85 T to about the same values as at H=0T. This suggests that the gap exists for all fields up to 9.85 T. Above 10 K, in the mixed-valent state, {Delta}C/T vs T decreases with increasing temperature in zero field. There is hardly any effect of application of field in the mixed-valent state. We have also carried out magnetoresistance measurements on CeRhSb up to fields of 5.5 T at 2, 4.5, 10, 20, and 30 K. The magnetoresistance in CeRhSb is positive at temperatures of 4.5 K and above, in applied fields up to 5.5 T. At 5.5 T, the magnetoresistance is maximum at 4.5 K (6{percent}) and decreases with increasing temperature. The observation of the maximum is consistent with the observation of a maximum in {Delta}C/T vs T and is due to a change in the density of states. At a temperature of 2 K, a negative magnetoresistance is observed for magnetic fields greater than {approximately}3.5T which suggests reduction in the gap. {copyright} {ital 1997} {ital The American Physical Society}

  1. Terrain-Responsive Atmospheric Code

    Energy Science and Technology Software Center (OSTI)

    1991-11-20

    The Terrain-Responsive Atmospheric Code (TRAC) is a real-time emergency response modeling capability designed to advise Emergency Managers of the path, timing, and projected impacts from an atmospheric release. TRAC evaluates the effects of both radiological and non-radiological hazardous substances, gases and particulates. Using available surface and upper air meteorological information, TRAC realistically treats complex sources and atmospheric conditions, such as those found in mountainous terrain. TRAC calculates atmospheric concentration, deposition, and dose for more thanmore »25,000 receptor locations within 80 km of the release point. Human-engineered output products support critical decisions on the type, location, and timing of protective actions for workers and the public during an emergency.« less

  2. Atmospheric science and power production

    SciTech Connect (OSTI)

    Randerson, D.

    1984-07-01

    This is the third in a series of scientific publications sponsored by the US Atomic Energy Commission and the two later organizations, the US Energy Research and Development Adminstration, and the US Department of Energy. The first book, Meteorology and Atomic Energy, was published in 1955; the second, in 1968. The present volume is designed to update and to expand upon many of the important concepts presented previously. However, the present edition draws heavily on recent contributions made by atmospheric science to the analysis of air quality and on results originating from research conducted and completed in the 1970s. Special emphasis is placed on how atmospheric science can contribute to solving problems relating to the fate of combustion products released into the atmosphere. The framework of this book is built around the concept of air-quality modeling. Fundamentals are addressed first to equip the reader with basic background information and to focus on available meteorological instrumentation and to emphasize the importance of data management procedures. Atmospheric physics and field experiments are described in detail to provide an overview of atmospheric boundary layer processes, of how air flows around obstacles, and of the mechanism of plume rise. Atmospheric chemistry and removal processes are also detailed to provide fundamental knowledge on how gases and particulate matter can be transformed while in the atmosphere and how they can be removed from the atmosphere. The book closes with a review of how air-quality models are being applied to solve a wide variety of problems. Separate analytics have been prepared for each chapter.

  3. Investigation of transient, two-dimensional coupled heat and moisture flow in soils

    SciTech Connect (OSTI)

    Shen, L.S.W.

    1986-01-01

    A two-dimensional finite difference numerical model has been developed to study coupled heat and moisture flow in the soil surrounding an earth-sheltered construction. The model is based on a mechanistic approach formulated by Milly and developed from the work of Philip and deVries. Using soil temperatures and matric potentials as the dependent variables, the model is capable of simulating unsaturated/saturated flow conditions in heterogeneous soil domains. The model is a fully implicit, integrated finite difference approach based on the Patankar Spalding method. The numerical modeling of the governing heat and moisture equations was validated against a number of analytical and quasi-analytical solutions. An axisymmetric, two-dimensional experiment was then defined to which the numerical model could be compared. The experimental apparatus was composed of a cylinder filled with a dredged Mississippi River sand. A series of one and two dimensional heat and moisture flow experiments were run, using boundary conditions consistent with those that occur in the soil surrounding a building. Soil properties used in the model were either calculated from theoretical models or measured experimentally. Agreement between the model and experiments were good, with an error of 10-15% obtained for the two-dimensional coupled heat and moisture flow experiment.

  4. Feasibility study of prompt gamma neutron activation for NDT measurement of moisture in stone and brick

    SciTech Connect (OSTI)

    Livingston, R. A.; Al-Sheikhly, M.; Grissom, C.; Aloiz, E.; Paul, R.

    2014-02-18

    The conservation of stone and brick architecture or sculpture often involves damage caused by moisture. The feasibility of a NDT method based on prompt gamma neutron activation (PGNA) for measuring the element hydrogen as an indication of water is being evaluated. This includes systematic characterization of the lithology and physical properties of seven building stones and one brick type used in the buildings of the Smithsonian Institution in Washington, D.C. To determine the required dynamic range of the NDT method, moisture-related properties were measured by standard methods. Cold neutron PGNA was also used to determine chemically bound water (CBW) content. The CBW does not damage porous masonry, but creates an H background that defines the minimum level of detection of damaging moisture. The CBW was on the order of 0.5% for all the stones. This rules out the measurement of hygric processes in all of the stones and hydric processed for the stones with fine scale pore-size distributions The upper bound of moisture content, set by porosity through water immersion, was on the order of 5%. The dynamic range is about 1020. The H count rates were roughly 13 cps. Taking into account differences in neutron energies and fluxes and sample volume between cold PGNA and a portable PGNA instrument, it appears that it is feasible to apply PGNA in the field.

  5. Systematics of the temperature-dependent interplane resistivity in Ba(Fe1-xMx)?As? (M=Co, Rh, Ni, and Pd)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tanatar, M. A.; Ni, N.; Thaler, A.; Budko, S. L.; Canfield, P. C.; Prozorov, R.

    2011-07-27

    Temperature-dependent interplane resistivity ?c(T) was measured systematically as a function of transition-metal substitution in the iron-arsenide superconductors Ba(Fe1-xMx)?As?, M=Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe1-xCox)?As?, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature T* from nonmetallic to metallic temperature dependence on cooling. Suppression of T* proceeds very similarly in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent ?c emerges for high dopings,morewhen superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni- and Pd-doped compositions than in Co- and Rh-doped compounds.less

  6. Tuning the Curie temperature of L1{sub 0} ordered FePt thin films through site-specific substitution of Rh

    SciTech Connect (OSTI)

    Xu, Dongbin; Sun, Cheng-Jun E-mail: msecgm@nus.edu.sg; Heald, Steve M.; Chen, Jing-Sheng; Chow, Gan Moog E-mail: msecgm@nus.edu.sg; Zhou, Tie-Jun; Bergman, Anders; Sanyal, Biplab

    2014-10-14

    In structurally ordered magnetic thin films, the Curie temperature (T{sub C}) of ferromagnetic films depends on the exchange integral of the short range ordered neighboring atoms. The exchange integral may be adjusted by controlling the elemental substitutional concentration at the lattice site of interest. We show how to control the T{sub C} in high anisotropy L1{sub 0} Fe{sub 50}Pt{sub 50} magnetic thin films by substituting Rh into the Pt site. Rh substitution in L1{sub 0} FePt modified the local atomic environment and the corresponding electronic properties, while retaining the ordered L1{sub 0} phase. The analysis of extended x-ray Absorption Fine Structure spectra shows that Rh uniformly substitutes for Pt in L1{sub 0} FePt. A model of antiferromagnetic defects caused by controlled Rh substitution of the Pt site, reducing the T{sub C,} is proposed to interpret this phenomenon and its validity is further examined by ab initio density functional calculations.

  7. Dynamical and thermodynamical modulations of future changes in landfalling atmospheric rivers over North America

    SciTech Connect (OSTI)

    Gao, Yang; Lu, Jian; Leung, Lai-Yung R.; Yang, Qing; Hagos, Samson M.; Qian, Yun

    2015-09-12

    This study examines the changes of landfalling atmospheric rivers (ARs) over the west coast of North America in response to future warming using model outputs from the Coupled Model Intercomparison Project phase 5 (CMIP5). The result reveals a strikingly large magnitude of increase of AR days by the end of the 21st century in the RCP8.5 climate change scenario, with fractional increases ranging between ~50% and 600%, depending on the seasons and the landfall locations. These increases are predominantly controlled by the super-Clausius-Clapeyron rate of increase of atmospheric water vapor with warming, while changes of winds that transport moisture in the ARs, or dynamical effect, mostly counter the thermodynamical effect of increasing water vapor, limiting the increase of AR events in the future. The consistent negative effect of wind changes on AR days during spring and fall can be further linked to the robust poleward shift of the subtropical jet in the North Pacific basin.

  8. Plant Response and Environmental Data from the Oldfield Community Climate and Atmospheric Manipulation (OCCAM) Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Oldfield Community Climate and Atmospheric Manipulation (OCCAM) project is a joint effort of ORNL and the University of Tennessee to investigate community and ecosystem response to global change, specifically looking at the interactive effects of atmospheric carbon dioxide, surface temperatures, and soil moisture. The plants studied for their response to warming temperatures, elevated carbon dioxide, and altered water availability include C3 and C4 grasses, forbs, and legumes. These plants are typical of an old-field ecosystem that establishes itself on unused agricultural land. The results of the research focus on species abundance, production, phenology, and what is going on chemically below ground. Data are currently available from 2003 through July, 2008.

  9. Atmospheric Crude Oil Distillation Operable Capacity

    Gasoline and Diesel Fuel Update (EIA)

    (Barrels per Calendar Day) Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum

  10. CRADA with the Belhaven group and Pacific Northwest National Laboratory (PNL-081): Automated soil moisture measuring systems. Final project report

    SciTech Connect (OSTI)

    Ramesh, K.S.

    1996-08-01

    The objectives of this project were to (1) develop an improved, full- scale, inexpensive, soil moisture sensor, using innovative porous ceramic materials as the moisture wicking component and (2) demonstrate the performance of the sensor in the laboratory and in field to determine its reliability and accuracy. The opportunity for this project arose as a result of an inquiry from Belhaven to whom the soil moisture sensor developed at PNNL by John Cary was licensed. The existing Cary sensor needed research and development effort in order to create the type of soil moisture sensor envisioned by the Belhaven for use in an integrated soil moisture systems in the field. PNNL was identified as being uniquely qualified to participate in this Collaborative project.

  11. Working with SRNL - Our Facilities - Atmospheric Technologies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The SRNL Atmospheric Technologies Center has extensive capabilities for world-wide meteorological forecasts and real-time atmospheric transport modeling and assessment. ...

  12. National Oceanic and Atmospheric Administration (NOAA) | Open...

    Open Energy Info (EERE)

    National Oceanic and Atmospheric Administration (NOAA) Jump to: navigation, search Logo: National Oceanic and Atmospheric Administration (NOAA) Name: National Oceanic and...

  13. Correcting radar range measurements for atmospheric propagation...

    Office of Scientific and Technical Information (OSTI)

    Correcting radar range measurements for atmospheric propagation effects. Citation Details In-Document Search Title: Correcting radar range measurements for atmospheric propagation...

  14. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion...

  15. Atmospheric Radiation Measurement Climate Research Facility Operations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6-001 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly ... DOESC-ARM-16-001 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  16. Atmospheric Radiation Measurement Program Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-12-001 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  17. Atmospheric Radiation Measurement Program Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 Atmospheric Radiation Measurement Program Climate Research Facility Operations Quarterly ... DOESC-ARM-11-008 Atmospheric Radiation Measurement Program Climate Research Facility ...

  18. Atmospheric Radiation Measurement Program Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Atmospheric Radiation Measurement Program Climate Research Facility Operations Quarterly ... DOESC-ARM-10-029 Atmospheric Radiation Measurement Program Climate Research Facility ...

  19. Atmospheric Radiation Measurement (ARM) Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Radiation Measurement (ARM) Climate Research Facility and Atmospheric System Research (ASR) Science and Infrastructure Steering Committee CHARTER June 2012 DISCLAIMER ...

  20. Atmospheric Radiation Measurement Climate Research Facility ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... of Energy (DOE) established the Atmospheric Radiation Measurement (ARM) Program. ... Fiscal Year 2004 Budget Summary and User Statistics Atmospheric Radiation Measurement ...

  1. Atmospheric Radiation Measurement Program Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Atmospheric Radiation Measurement Program Climate Research Facility Operations Quarterly ... DOESC-ARM-11-002 Atmospheric Radiation Measurement Program Climate Research Facility ...

  2. Atmospheric Radiation Measurement Climate Research Facility Operations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-15-069 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  3. Atmospheric Radiation Measurement Program Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-11-022 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  4. Atmospheric Radiation Measurement Program Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Atmospheric Radiation Measurement Program Climate Research Facility Operations Quarterly ... DOESC-ARM-11-019 Atmospheric Radiation Measurement Program Climate Research Facility ...

  5. Atmospheric Radiation Measurement Program Climate Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-12-007 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  6. A moist aquaplanet variant of the HeldSuarez test for atmospheric model dynamical cores

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thatcher, D. R.; Jablonowski, C.

    2015-09-29

    A moist idealized test case (MITC) for atmospheric model dynamical cores is presented. The MITC is based on the HeldSuarez (HS) test that was developed for dry simulations on a flat Earth and replaces the full physical parameterization package with a Newtonian temperature relaxation and Rayleigh damping of the low-level winds. This new variant of the HS test includes moisture and thereby sheds light on the non-linear dynamics-physics moisture feedbacks without the complexity of full physics parameterization packages. In particular, it adds simplified moist processes to the HS forcing to model large-scale condensation, boundary layer mixing, and the exchange ofmorelatent and sensible heat between the atmospheric surface and an ocean-covered planet. Using a variety of dynamical cores of NCAR's Community Atmosphere Model (CAM), this paper demonstrates that the inclusion of the moist idealized physics package leads to climatic states that closely resemble aquaplanet simulations with complex physical parameterizations. This establishes that the MITC approach generates reasonable atmospheric circulations and can be used for a broad range of scientific investigations. This paper provides examples of two application areas. First, the test case reveals the characteristics of the physics-dynamics coupling technique and reproduces coupling issues seen in full-physics simulations. In particular, it is shown that sudden adjustments of the prognostic fields due to moist physics tendencies can trigger undesirable large-scale gravity waves, which can be remedied by a more gradual application of the physical forcing. Second, the moist idealized test case can be used to intercompare dynamical cores. These examples demonstrate the versatility of the MITC approach and suggestions are made for further application areas. The new moist variant of the HS test can be considered a test case of intermediate complexity.less

  7. Moisture Management of High-R Walls (Fact Sheet), Building America Case Study: Technology Solutions for New and Existing Homes, Building Technologies Office (BTO)

    Energy Savers [EERE]

    Management of High-R Walls PROJECT APPLICATION Construction: Existing homes with vapor open wall assemblies Type: Residential Climate Zones: All TECHNICAL PARAMETERS Moisture Sources: Water vapor is moisture that flows from areas of high vapor pressure to low vapor pressure. It can accumulate behind vapor impermeable materials. Construction moisture is moisture that is stored in materials when exposed to the environment during construction. Rain is the primary source. This was simulated with a

  8. Effect of process variables on the density and durability of the pellets made from high moisture corn stover

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru

    2014-03-01

    A flat die pellet mill was used to understand the effect of high levels of feedstock moisture content in the range of 2838% (w.b.), with die rotational speeds of 4060 Hz, and preheating temperatures of 30110 C on the pelleting characteristics of 4.8 mm screen size ground corn stover using an 8 mm pellet die. The physical properties of the pelletised biomass studied are: (a) pellet moisture content, (b) unit, bulk and tapped density, and (c) durability. Pelletisation experiments were conducted based on central composite design. Analysis of variance (ANOVA) indicated that feedstock moisture content influenced all of the physical properties at P < 0.001. Pellet moisture content decreased with increase in preheating temperature to about 110 C and decreasing the feedstock moisture content to about 28% (w.b.). Response surface models developed for quality attributes with respect to process variables has adequately described the process with coefficient of determination (R2) values of >0.88. The other pellet quality attributes such as unit, bulk, tapped density, were maximised at feedstock moisture content of 3033% (w.b.), die speeds of >50 Hz and preheating temperature of >90 C. In case of durability a medium moisture content of 3334% (w.b.) and preheating temperatures of >70 C and higher die speeds >50 Hz resulted in high durable pellets. It can be concluded from the present study that feedstock moisture content, followed by preheating, and die rotational speed are the interacting process variables influencing pellet moisture content, unit, bulk and tapped density and durability.

  9. Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures

    DOE Patents [OSTI]

    Plancher, Henry (Laramie, WY); Petersen, Joseph C. (Laramie, WY)

    1982-01-01

    Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

  10. Influence of Airflow on Laboratory Storage of High Moisture Corn Stover

    SciTech Connect (OSTI)

    Lynn M. Wendt; Ian J. Bonner; Amber N. Hoover; Rachel M. Emerson; William A. Smith

    2014-04-01

    Storing high moisture biomass for bioenergy use is a reality in many areas of the country where wet harvest conditions and environmental factors prevent dry storage from being feasible. Aerobic storage of high moisture biomass leads to microbial degradation and self-heating, but oxygen limitation can aid in material preservation. To understand the influence of oxygen presence on high moisture biomass (50 %, wet basis), three airflow rates were tested on corn stover stored in laboratory reactors. Temperature, carbon dioxide production, dry matter loss, chemical composition, fungal abundance, pH, and organic acids were used to monitor the effects of airflow on storage conditions. The results of this work indicate that oxygen availability impacts both the duration of self-heating and the severity of dry matter loss. High airflow systems experienced the greatest initial rates of loss but a shortened microbially active period that limited total dry matter loss (19 %). Intermediate airflow had improved preservation in short-term storage compared to high airflow systems but accumulated the greatest dry matter loss over time (up to 27 %) as a result of an extended microbially active period. Low airflow systems displayed the best performance with the lowest rates of loss and total loss (10 %) in storage at 50 days. Total structural sugar levels of the stored material were preserved, although glucan enrichment and xylan loss were documented in the high and intermediate flow conditions. By understanding the role of oxygen availability on biomass storage performance, the requirements for high moisture storage solutions may begin to be experimentally defined.

  11. Moisture performance of sealed attics in the mixed-humid climate

    SciTech Connect (OSTI)

    Boudreaux, Philip R; Pallin, Simon B; Jackson, Roderick K

    2013-12-01

    Oak Ridge National Laboratory studied 8 homes in the mixed-humid climate, 4 with vented attics and 4 with sealed attics. ORNL wanted to understand the moisture performance of the sealed attic and how it affected the interior environment. We found that the attic and interior of sealed attic homes were more humid than the attic and interior observed in vented attic homes. This is due to the lack of ventilation in the sealed attic. Historically attics have been vented to dehumidify the attic and interior of the home. A sealed attic design greatly reduces the venting potential and thus this drying pathway and can cause elevated interior moisture over a vented attic home. Despite the elevated attic and interior moisture in the sealed attic homes, so far no mold or material degradation has been found. The roof sheathing moisture content has stayed below 20%, indicating low potential for material degradation. Also the relative humidity at the roof sheathing has stayed within the ASHRAE 160 design criteria except for a short time during the 2011/2012 winter. This was due to a combination of the sealed attic design (minimal venting to the outside) and the duct work not being operated in the attic which usually provides a dehumidification pathway. It was also found that when the humidity was controlled using the HVAC system, it resulted in 7% more cooling energy consumption. In the mixed-humid climate this reduces the cost effectiveness of the sealed attic design as a solution for bringing ducts into a semi-conditioned space. Because of this we are recommending the other alternatives be used to bringing ducts into the conditioned space in both new construction and retrofit work in the mixed-humid climate.

  12. Size reduction of high- and low-moisture corn stalks by linear knife grid system

    SciTech Connect (OSTI)

    Womac, A.R. [University of Tennessee; Igathinathane, C. [Mississippi State University (MSU); Sokhansanj, Shahabaddine [ORNL; Narayan, S. [First American Scientific Co.

    2009-04-01

    High- and low-moisture corn stalks were tested using a linear knife grid size reduction device developed for first-stage size reduction. The device was used in conjunction with a universal test machine that quantified shearing stress and energy characteristics for forcing a bed of corn stalks through a grid of sharp knives. No published engineering performance data for corn stover with similar devices are available to optimize performance; however, commercial knife grid systems exist for forage size reduction. From the force displacement data, mean and maximum ultimate shear stresses, cumulative and peak mass-based cutting energies for corn stalks, and mean new surface area-based cutting energies were determined from 4 5 refill runs at two moisture contents (78.8% and 11.3% wet basis), three knife grid spacings (25.4, 50.8, and 101.6 mm), and three bed depths (50.8, 101.6, and 152.4 mm). In general, the results indicated that peak failure load, ultimate shear stress, and cutting energy values varied directly with bed depth and inversely with knife grid spacing. Mean separation analysis established that high- and low-moisture conditions and bed depths 101.6 mm did not differ significantly (P < 0.05) for ultimate stress and cutting energy values, but knife grid spacing were significantly different. Linear knife grid cutting energy requirements for both moisture conditions of corn stalks were much smaller than reported cutting energy requirements. Ultimate shear stress and cutting energy results of this research should aid the engineering design of commercial scale linear knife gird size reduction equipment for various biomass feedstocks.

  13. Development of Optical Technologies for Monitoring Moisture and Particulate in Geothermal Steam

    SciTech Connect (OSTI)

    J. K. Partin

    2006-08-01

    The results of an investigation directed at evaluating the feasibility of using optical measurements for the real-time monitoring moisture and particulate in geothermal steam is described. The measurements exploit new technologies that have been developed for the telecommunications industry and includes new solid state laser devices, large-bandwidth, high-sensitivity detectors and low loss optical fiber compo-nents. In particular, the design, fabrication, and in-plant testing of an optical steam monitor for the detection of moisture is presented. The measurement principle is based upon the selective absorption of infrared energy in response to the presence of moisture. Typically, two wavelengths are used in the measurements: a wavelength that is strongly absorbed by water and a reference wavelength that is minimally influenced by water and steam which serves as a reference to correct for particulate or droplet scattering. The two wavelengths are chosen to be as close as possible in order to more effectively correct for scattering effects. The basic instrumentation platform developed for the in-situ monitoring of steam moisture can be modified and used to perform other measurements of interest to plant operators. An upgrade that will allow the instrument to be used for the sensitive detection of particulate in process streams has been investigated. The new monitor design involves the use of laser diodes that are much less sensitive to water and water vapor and more sensitive to scattering phenomena, as well as new processing techniques to recover these signals. The design reduces the averaging time and sampling volume, while increasing the laser probe power, enhancing particulate detection sensitivity. The design concept and initial laboratory experiments with this system are also reported.

  14. An analysis of moisture accumulation in the roof cavities of manufactured housing

    SciTech Connect (OSTI)

    Burch, D.

    1995-09-01

    A detailed computer analysis is conducted to investigate whether moisture problems occur in the roof cavity of manufactured homes constructed in compliance with the current Department of Housing and Urban Development (HUD) Standards for manufactured housing. The current HUD Standards require a ceiling vapor retarder, but do not require outdoor ventilation of the roof cavity. In cold climates, the analysis revealed that moisture accumulates at lower roof surface and poses a risk of material degradation. The analysis found the following combination of passive measures to be effective in preventing detrimental winter moisture accumulation at lower surface of the roof: (1) providing a ceiling vapor retarder; (2) sealing penetrations and openings in the ceiling construction, and (3) providing natural ventilation openings in the roof cavity. In addition, the performance of a roof cavity exposed to a hot and humid climate is investigated. The analysis revealed that outdoor ventilation of the roof cavity causes the monthly mean relative humidity at the upper surface of the vapor retarder to exceed 80%. This condition is conducive to mold and mildew growth.

  15. Effects of Compressive Force, Particle Size and Moisture Content on Mechanical Properties of Biomass Grinds

    SciTech Connect (OSTI)

    Mani, Sudhagar; Tabil, Lope Jr.; Sokhansanj, Shahabaddine

    2006-03-01

    Chemical composition, moisture content, bulk and particle densities, and geometric mean particle size were determined to characterize grinds from wheat and barley straws, corn stover and switchgrass. The biomass grinds were compressed for five levels of compressive forces (1000, 2000, 3000, 4000, 4400 N) and three levels of particle sizes (3.2, 1.6 and 0.8 mm) at two levels of moisture contents (12% and 15% (wb) to establish the compression and relaxation data. Corn stover grind produced the highest compact density at low pressure during compression. Compressive force, particle size and moisture content of grinds significantly affected the compact density of barley straw, corn stover and switchgrass grinds. However, different particle sizes of wheat straw grind did not produce any significant difference on compact density. Barley straw grind had the highest asymptotic modulus among all other biomass grinds indicating that compact from barley straw grind were more rigid than those of other compacts. Asymptotic modulus increased with an increase in maximum compressive pressure. The trend of increase in asymptotic modulus (EA) with the maximum compressive pressure ( 0) was fitted to a second order polynomial equation. Keywords: Biomass grinds, chemical composition, compact density and asymptotic modulus

  16. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Ba/Rh NOx Traps for Design and Optimization

    SciTech Connect (OSTI)

    Michael Harold; Vemuri Balakotaiah

    2010-05-31

    In this project a combined experimental and theoretical approach was taken to advance our understanding of lean NOx trap (LNT) technology. Fundamental kinetics studies were carried out of model LNT catalysts containing variable loadings of precious metals (Pt, Rh), and storage components (BaO, CeO{sub 2}). The Temporal Analysis of Products (TAP) reactor provided transient data under well-characterized conditions for both powder and monolith catalysts, enabling the identification of key reaction pathways and estimation of the corresponding kinetic parameters. The performance of model NOx storage and reduction (NSR) monolith catalysts were evaluated in a bench scale NOx trap using synthetic exhaust, with attention placed on the effect of the pulse timing and composition on the instantaneous and cycle-averaged product distributions. From these experiments we formulated a global model that predicts the main spatio-temporal features of the LNT and a mechanistic-based microkinetic models that incorporates a detailed understanding of the chemistry and predicts more detailed selectivity features of the LNT. The NOx trap models were used to determine its ability to simulate bench-scale data and ultimately to evaluate alternative LNT designs and operating strategies. The four-year project led to the training of several doctoral students and the dissemination of the findings as 47 presentations in conferences, catalysis societies, and academic departments as well 23 manuscripts in peer-reviewed journals. A condensed review of NOx storage and reduction was published in an encyclopedia of technology.

  17. Asymmetric “melting” and “freezing” kinetics of the magnetostructural phase transition in B2-ordered FeRh epilayers

    SciTech Connect (OSTI)

    Vries, M. A. de; Loving, M.; Lewis, L. H.; McLaren, M.; Brydson, R. M. D.; Liu, X.; Langridge, S.; Marrows, C. H.

    2014-06-09

    Synchrotron X-ray diffraction was used to study the phase transformation processes during the magnetostructural transition in a B2-ordered FeRh (001)-oriented epilayer grown on MgO by sputtering. Out-of-plane lattice constant measurements within the hysteretic regime of the transition reveal a microstructure consistent with the coexistence of lattice-expanded and contracted phases in spatially distinct regions. It was found that the phase separation is more pronounced during cooling than heating. Furthermore, whilst lattice-expanded domains that span the height of the film can be undercooled by several kelvins, there is no equivalent superheating. This asymmetry between the cooling and heating processes in FeRh is consistent with the difference in the kinetics of generic freezing and melting transitions.

  18. Magnetic structure of the antiferromagnetic Kondo lattice compounds CeRhAl4Si2 and CeIrAl4Si2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Calder, S.; Janoschek, M.; Bauer, E. D.

    2015-06-01

    In this article, we have investigated the magnetic ground state of the antiferromagnetic Kondo-lattice compounds CeMAl4Si2(M = Rh, Ir) using neutron powder diffraction. Although both of these compounds show two magnetic transitions TN1 and TN2 in the bulk properties measurements, evidence for magnetic long-range order was only found below the lower transition TN2. Analysis of the diffraction profiles reveals a commensurate antiferromagnetic structure with a propagation vector k = (0, 0, 1/2). The magnetic moment in the ordered state of CeRhAl4Si2 and CeIrAl4Si2 were determined to be 1.14(2) and 1.41(3) μB/Ce, respectively, and are parallel to the crystallographic c-axis inmore » agreement with magnetic susceptibility measurements.« less

  19. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    SciTech Connect (OSTI)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 K with an ordered moment of ?sat = 0.8 ?B for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.

  20. Dendrimer Templated Synthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole Hydrogenation.

    SciTech Connect (OSTI)

    Huang, Wenyu; Kuhn, John N.; Tsung, Chia-Kuang; Zhang, Yawen; Habas, Susan E.; Yang, Peidong; Somorjai, Gabor A.

    2008-05-09

    Monodisperse rhodium (Rh) and platinum (Pt) nanoparticles as small as {approx}1 nm were synthesized within a fourth generation polyaminoamide (PAMAM) dendrimer, a hyperbranched polymer, in aqueous solution and immobilized by depositing onto a high-surface-area SBA-15 mesoporous support. X-ray photoelectron spectroscopy indicated that the as-synthesized Rh and Pt nanoparticles were mostly oxidized. Catalytic activity of the SBA-15 supported Rh and Pt nanoparticles was studied with ethylene hydrogenation at 273 and 293 K in 10 torr of ethylene and 100 torr of H{sub 2} after reduction (76 torr of H{sub 2} mixed with 690 torr of He) at different temperatures. Catalysts were active without removing the dendrimer capping but reached their highest activity after hydrogen reduction at a moderate temperature (423 K). When treated at a higher temperature (473, 573, and 673 K) in hydrogen, catalytic activity decreased. By using the same treatment that led to maximum ethylene hydrogenation activity, catalytic activity was also evaluated for pyrrole hydrogenation.

  1. Wiedemann-Franz law and nonvanishing temperature scale across the field-tuned quantum critical point of YbRh2Si2

    SciTech Connect (OSTI)

    Reid, J.-Ph.; Tanatar, Makariy; Daou, R.; Hu, Rongwei; Petrovic, C.; Taillefer, Louis

    2014-01-23

    The in-plane thermal conductivity kappa and electrical resistivity rho of the heavy-fermion metal YbRh2Si2 were measured down to 50 mK for magnetic fields H parallel and perpendicular to the tetragonal c axis, through the field-tuned quantum critical point H-c, at which antiferromagnetic order ends. The thermal and electrical resistivities, w L0T/kappa and rho, show a linear temperature dependence below 1 K, typical of the non-Fermi-liquid behavior found near antiferromagnetic quantum critical points, but this dependence does not persist down to T = 0. Below a characteristic temperature T-star similar or equal to 0.35 K, which depends weakly on H, w(T) and rho(T) both deviate downward and converge as T -> 0. We propose that T-star marks the onset of short-range magnetic correlations, persisting beyond H-c. By comparing samples of different purity, we conclude that the Wiedemann-Franz law holds in YbRh2Si2, even at H-c, implying that no fundamental breakdown of quasiparticle behavior occurs in this material. The overall phenomenology of heat and charge transport in YbRh2Si2 is similar to that observed in the heavy-fermion metal CeCoIn5, near its own field-tuned quantum critical point.

  2. Atmospheric Chemistry and Air Pollution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemore » and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.« less

  3. Atmosphere to Electrons Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Atmosphere to Electrons (A2e) Initiative Overview DOE Wind and Water Power Technologies Office January 2014 2 * Motivation for a new R&D framework * A2e initiative overview - Strategic planning framework - Management construct - Executive Management Committee (EMC) - National Laboratory Leadership * Strategic thrust area planning introduction * Program objectives * Open discussion of approach Overview Agenda 3 Wind energy today ..... * Multi-Billion dollar industry with involvement of

  4. Atmospheric-pressure plasma jet

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1999-01-01

    Atmospheric-pressure plasma jet. A .gamma.-mode, resonant-cavity plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two concentric cylindrical electrodes are employed to generate a plasma in the annular region therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly shaping the rf-powered electrode. Because of the atmospheric pressure operation, no ions survive for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike low-pressure plasma sources and conventional plasma processing methods.

  5. DEFRA Global Atmosphere Dept | Open Energy Information

    Open Energy Info (EERE)

    Kingdom Zip: SW1E 6DE Product: Atmosphere research department of the UK Department of Food and Rural Affairs. References: DEFRA - Global Atmosphere Dept.1 This article is a...

  6. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused

  7. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused

  8. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused

  9. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Composition and Reactions of Atmospheric Aerosol Particles Print Wednesday, 29 June 2005 00:00 Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the

  10. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused

  11. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion emissions released from around the world. How long these tiny particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused

  12. Quantitative determination of atmospheric hydroperoxyl radical

    DOE Patents [OSTI]

    Springston, Stephen R. (Upton, NY); Lloyd, Judith (Westbury, NY); Zheng, Jun (Stony Brook, NY)

    2007-10-23

    A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.

  13. Atmosphere to Electrons | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research & Development » Atmosphere to Electrons Atmosphere to Electrons Atmosphere to Electrons Atmosphere to Electrons (A2e) is a multi-year U.S. Department of Energy (DOE) research initiative targeting significant reductions in the cost of wind energy through an improved understanding of the complex physics governing wind flow into and through wind farms. Better insight into the flow physics has the potential to reduce wind farm energy losses by up to 20%, to reduce annual operational

  14. Flexible Ultra Moisture Barrier Film for Thin-Film Photovoltaic Applications

    SciTech Connect (OSTI)

    David M. Dean

    2012-10-30

    Flexible Thin-film photovoltaic (TFPV) is a low cost alternative to incumbent c-Si PV products as it requires less volume of costly semiconductor materials and it can potentially reduce installation cost. Among the TFPV options, copper indium gallium diselenide (CIGS) has the highest efficiency and is believed to be one of the most attractive candidates to achieve PV cost reduction. However, CIGS cells are very moisture sensitive and require module water vapor transmission rate (WVTR) of less than 1x10-4 gram of water per square meter per day (g-H2O/m2/day). Successful development and commercialization of flexible transparent ultra moisture barrier film is the key to enable flexible CIGS TFPV products, and thus enable ultimate PV cost reduction. At DuPont, we have demonstrated at lab scale that we can successfully make polymer-based flexible transparent ultra moisture barrier film by depositing alumina on polymer films using atomic layer deposition (ALD) technology. The layer by layer ALD approach results in uniform and amorphous structure which effectively reduces pinhole density of the inorganic coating on the polymer, and thus allow the fabrication of flexible barrier film with WVTR of 10-5 g-H2O/m2/day. Currently ALD is a time-consuming process suitable only for high-value, relatively small substrates. To successfully commercialize the ALD-on-plastic technology for the PV industry, there is the need to scale up this technology and improve throughput. The goal of this contract work was to build a prototype demonstrating that the ALD technology could be scaled-up for commercial use. Unfortunately, the prototype failed to produce an ultra-barrier film by the close of the project.

  15. Soil temperature, soil moisture and thaw depth, Barrow, Alaska, Ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sloan, V.L.; J.A. Liebig; M.S. Hahn; J.B. Curtis; J.D. Brooks; A. Rogers; C.M. Iversen; R.J. Norby

    2014-01-10

    This dataset consists of field measurements of soil properties made during 2012 and 2013 in areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) weekly measurements of thaw depth, soil moisture, presence and depth of standing water, and soil temperature made during the 2012 and 2013 growing seasons (June - September) and ii) half-hourly measurements of soil temperature logged continuously during the period June 2012 to September 2013.

  16. Cavitation controlled acoustic probe for fabric spot cleaning and moisture monitoring

    DOE Patents [OSTI]

    Sheen, Shuh-Haw (Naperville, IL); Chien, Hual-Te (Naperville, IL); Raptis, Apostolos C. (Downers Grove, IL)

    1997-01-01

    A method and apparatus are provided for monitoring a fabric. An acoustic probe generates acoustic waves relative to the fabric. An acoustic sensor, such as an accelerometer is coupled to the acoustic probe for generating a signal representative of cavitation activity in the fabric. The generated cavitation activity representative signal is processed to indicate moisture content of the fabric. A feature of the invention is a feedback control signal is generated responsive to the generated cavitation activity representative signal. The feedback control signal can be used to control the energy level of the generated acoustic waves and to control the application of a cleaning solution to the fabric.

  17. Soil temperature, soil moisture and thaw depth, Barrow, Alaska, Ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sloan, V.L.; J.A. Liebig; M.S. Hahn; J.B. Curtis; J.D. Brooks; A. Rogers; C.M. Iversen; R.J. Norby

    This dataset consists of field measurements of soil properties made during 2012 and 2013 in areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) weekly measurements of thaw depth, soil moisture, presence and depth of standing water, and soil temperature made during the 2012 and 2013 growing seasons (June - September) and ii) half-hourly measurements of soil temperature logged continuously during the period June 2012 to September 2013.

  18. RH_SRS_Shipment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WIPP Trucks Delivering First Remote-Handled Transuranic Waste from the Savannah River Site CARLSBAD, N.M., June 11, 2012- Photo caption: On June 7, 2012, Waste Isolation Pilot Plant (WIPP) trucks approach the WIPP facility near Carlsbad, New Mexico, with the first shipment of defense- related remote-handled transuranic (TRU) waste from Savannah River Site (SRS), near Aiken, South Carolina. TRU waste consists of materials contaminated with radioactive elements that have atomic numbers greater

  19. Temperature and RH Targets

    Broader source: Energy.gov [DOE]

    Presented by Vishal O Mittal of the Florida Solar Energy Center at the High Temperature Membrane Working Group Meeting, San Francisco, September 14, 2006.

  20. Microsoft Word - ORNL RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NEWS MEDIA CONTACT: March 2, 2009 Roger Nelson, Carlsbad Field Office (575) 234-7213 Walter Perry, Oak Ridge Office (865) 576-0885 FIRST OAK RIDGE REMOTE-HANDLED TRANSURANIC WASTE...

  1. Microsoft Word - SRS RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FOR IMMEDIATE RELEASE Roger Nelson, (575) 234-7213 April 24, 2009 For Immediate Release REMOTE-HANDLED TRU WASTE SHIPMENTS FROM SAVANNAH RIVER SITE ARRIVE SAFELY AT WIPP CARLSBAD,...

  2. Method and apparatus for simulating atmospheric absorption of solar energy due to water vapor and CO{sub 2}

    DOE Patents [OSTI]

    Sopori, B.L.

    1995-06-20

    A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth`s surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO{sub 2} and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO{sub 2} and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO{sub 2} and moisture. 8 figs.

  3. Al{sub 2}O{sub 3} multi-density layer structure as a moisture permeation barrier deposited by radio frequency remote plasma atomic layer deposition

    SciTech Connect (OSTI)

    Jung, Hyunsoo [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Samsung Display Co. Ltd., Tangjeong, Chungcheongnam-Do 336-741 (Korea, Republic of); Jeon, Heeyoung [Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Choi, Hagyoung; Ham, Giyul; Shin, Seokyoon [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Jeon, Hyeongtag, E-mail: hjeon@hanyang.ac.kr [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)

    2014-02-21

    Al{sub 2}O{sub 3} films deposited by remote plasma atomic layer deposition have been used for thin film encapsulation of organic light emitting diode. In this study, a multi-density layer structure consisting of two Al{sub 2}O{sub 3} layers with different densities are deposited with different deposition conditions of O{sub 2} plasma reactant time. This structure improves moisture permeation barrier characteristics, as confirmed by a water vapor transmission rate (WVTR) test. The lowest WVTR of the multi-density layer structure was 4.7 10{sup ?5} gm{sup ?2} day{sup ?1}, which is one order of magnitude less than WVTR for the reference single-density Al{sub 2}O{sub 3} layer. This improvement is attributed to the location mismatch of paths for atmospheric gases, such as O{sub 2} and H{sub 2}O, in the film due to different densities in the layers. This mechanism is analyzed by high resolution transmission electron microscopy, elastic recoil detection, and angle resolved X-ray photoelectron spectroscopy. These results confirmed that the multi-density layer structure exhibits very good characteristics as an encapsulation layer via location mismatch of paths for H{sub 2}O and O{sub 2} between the two layers.

  4. Radar range measurements in the atmosphere. (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Radar range measurements in the atmosphere. Citation Details In-Document Search Title: Radar range measurements in the atmosphere. The earth's atmosphere affects the velocity of...

  5. Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets

    SciTech Connect (OSTI)

    Davis, K.J.; Richardson, S.J.; Miles, N.L.

    2007-03-07

    Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2?3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute are captured. Influence functions, derived using a Lagrangian Particle Dispersion model driven by the CSU Regional Atmospheric Modeling System and nudged to NCEP reanalysis meteorological fields, are used to determine source regions for the towers. The influence functions are combined with satellite vegetation observations to interpret the observed trends in CO2 concentration. Full inversions will combine these elements in a more formal analytic framework.

  6. Spokane Wall Insulation Project: a field study of moisture damage in walls insulated without a vapor barrier

    SciTech Connect (OSTI)

    Tsongas, G.

    1985-09-01

    Considerable uncertainty has existed over whether or not the addition of wall insulation without a vapor barrier might increase the risk of moisture damage to the structure. Although it was concluded from a 1979 field study that there is no such risk in mild climates like that of Portland, Oregon (4792 degree-days), it was not clear if a problem might exist in colder climates. Thus, a second major field study was undertaken in Spokane, Washington (6835 degree-days) aimed at finding out if such a moisture problem really exists. This report describes that study and its results and conclusions. During the study the exterior walls of 103 homes were opened, of which 79 had retrofitted cellulose, rock wool, or fiberglass, and 24 were uninsulated as a control group. Field and laboratory test results are presented which, contrary to diffusion theory predictions, show the absence of moisture accumulation and consequent moisture damage caused by the addition of retrofitted wall insulation. Infrared thermography results giving the percentage of wall insulation void area for 30 of the test homes are also presented. The study strongly concludes that the addition of wall insulation without a vapor barrier does not cause moisture problems in existing homes in climates similar to that of Spokane. Future research needs are described, and the overall advisability of future retrofitting of wall insulation is discussed. 23 refs., 7 figs., 16 tabs.

  7. Bioorganometallic chemistry: biocatalytic oxidation reactions with biomimetic nad+/nadh co-factors and [cp*rh(bpy)h]+ for selective organic synthesis

    SciTech Connect (OSTI)

    Lutz, Jochen; Hollman, Frank; Ho, The Vinh; Schnyder, Adrian; Fish, Richard H.; Schmid, Andreas

    2004-03-09

    The biocatalytic, regioselective hydroxylation of 2-hydroxybiphenyl to the corresponding catechol was accomplished utilizing the monooxygenase 2-hydroxybiphenyl 3-monooxygenase (HbpA). The necessary natural nicotinamide adenine dinucleotide (NAD{sup +}) co-factor for this biocatalytic process was replaced by a biomimetic co-factor, N-benzylnicotinamide bromide, 1a. The interaction between the flavin (FAD) containing HbpA enzyme and the corresponding biomimetic NADH compound, N-benzyl-1,4-dihdronicotinamide, 1b, for hydride transfers, was shown to readily occur. The in situ recycling of the reduced NADH biomimic 1b from 1a was accomplished with [Cp*Rh(bpy)H](Cl); however, productive coupling of this regeneration reaction to the enzymatic hydroxylation reaction was not totally successful, due to a deactivation process concerning the HbpA enzyme peripheral groups; i.e., -SH or -NH{sub 2} possibly reacting with the precatalyst, [Cp*Rh(bpy)(H{sub 2}O)](Cl){sub 2}, and thus inhibiting the co-factor regeneration process. The deactivation mechanism was studied, and a promising strategy of derivatizing these peripheral -SH or -NH{sub 2} groups with a polymer containing epoxide was successful in circumventing the undesired interaction between HbpA and the precatalyst. This latter strategy allowed tandem co-factor regeneration using 1a or 2a, [Cp*Rh(bpy)(H2O)](Cl){sub 2}, and formate ion, in conjunction with the polymer bound, FAD containing HbpA enzyme to provide the catechol product.

  8. Building America Webinar: High Performance Enclosure Strategies: Part II, New Construction- August 13, 2014- Moisture Monitoring Results in an R-40 Wall

    Broader source: Energy.gov [DOE]

    This presentation, Moisture Monitoring Results in an R-40 Wall, was presented at the Building America webinar, High Performance Enclosure Strategies, Part II, on August 13, 2014.

  9. Field study of moisture damage in walls insulated without a vapor barrier. Final report for the Oregon Department of Energy

    SciTech Connect (OSTI)

    Tsongas, G.A.

    1980-05-01

    Considerable uncertainty has existed over whether or not wall insulation installed without a vapor barrier causes an increased risk of moisture damage (wood decay) within walls. This report describes the results of one of the first major studies in the country aimed at finding out if such a moisture problem really exists. The exterior walls of a total of 96 homes in Portland, Oregon were opened, of which 70 had retrofitted insulation and 26 were uninsulated and were a control group. The types of insulation included urea-formaldehyde foam (44), mineral wool (16), and cellulose (10). In each opened wall cavity the moisture content of wood was measured and insulation and wood samples were taken for laboratory analysis of moisture content and for the determination of the presence of absence of decay fungi. Foam shrinkage was also measured. To evaluate the possible influence of the relative air tightness of the homes, fan depressurization tests were run using a door blower unit. The field and laboratory test results indicating the lack of a moisture damage problem in existing homes with wood siding in climates similar to that of western Oregon are described along with results of a statistical analysis of the data. Related problems of interest to homeowners and insulation installers are noted. The standard operating procedures used throughout the study are discussed, including the home selection process, quantitative and qualitative techniques used to identify wall locations with the highest moisture content, wall opening and data/sample collection methodology, laboratory analysis of samples, data processing and analysis, and applicability of the results. Recommendations for furutre tests are made. Finally, the potential and desirability for future retrofitting of wall insulation is explored.

  10. Researching Complex Heat, Air and Moisture Interactions for a Wide-Range of Building Envelope Systems and Environmental Loads

    SciTech Connect (OSTI)

    Karagiozis, A.N.

    2007-05-15

    This document serves as the final report documenting work completed by Oak Ridge National Laboratory (ORNL) and the Fraunhofer Institute in Building Physics (Holzkirchen, Germany) under an international CRADA No. 0575 with Fraunhofer Institute of Bauphysics of the Federal Republic of Germany for Researching Complex Heat, Air and Moisture Interactions for a Wide Range of Building Envelope Systems and Environmental Loads. This CRADA required a multi-faceted approach to building envelope research that included a moisture engineering approach by blending extensive material property analysis, laboratory system and sub-system thermal and moisture testing, and advanced moisture analysis prediction performance. The Participant's Institute for Building physics (IBP) and the Contractor's Buildings Technology Center (BTC) identified potential research projects and activities capable of accelerating and advancing the development of innovative, low energy and durable building envelope systems in diverse climates. This allowed a major leverage of the limited resources available to ORNL to execute the required Department of Energy (DOE) directives in the area of moisture engineering. A joint working group (ORNL and Fraunhofer IBP) was assembled and a research plan was executed from May 2000 to May 2005. A number of key deliverables were produced such as adoption of North American loading into the WUFI-software. in addition the ORNL Weather File Analyzer was created and this has been used to address environmental loading for a variety of US climates. At least 4 papers have been co-written with the CRADA partners, and a chapter in the ASTM Manual 40 on Moisture Analysis and Condensation Control. All deliverables and goals were met and exceeded making this collaboration a success to all parties involves.

  11. Broadband Outdoor Radiometer Callibration Process for the Atmospheric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Broadband Outdoor Radiometer Calibration Process for the Atmospheric Radiation Measurement ... Broadband Outdoor Radiometer Calibration Process for the Atmospheric Radiation Measurement ...

  12. Flexible Residential Test Facility: Impact of Infiltration and Ventilation on Measured Cooling Season Energy and Moisture Levels

    SciTech Connect (OSTI)

    Parker, D.; Kono, J.; Vieira, R.; Fairey, P.; Sherwin, J.; Withers, C.; Hoak, D.; Beal, D.

    2014-05-01

    Air infiltration and ventilation in residential buildings is a very large part of the heating loads, but empirical data regarding the impact on space cooling has been lacking. Moreover, there has been little data on how building tightness might relate to building interior moisture levels in homes in a hot and humid climate. To address this need, BA-PIRC has conducted research to assess the moisture and cooling load impacts of airtightness and mechanical ventilation in two identical laboratory homes in the hot-humid climate over the cooling season.

  13. National Oceanic and Atmospheric Administration, Honolulu, Hawaii |

    Office of Environmental Management (EM)

    Department of Energy Oceanic and Atmospheric Administration, Honolulu, Hawaii National Oceanic and Atmospheric Administration, Honolulu, Hawaii Photo of a Staff Residence at the Pacific Tsunami Warning Center in Hawaii The staff residences at the Pacific Tsunami Warning Center in Hawaii now have solar water heating systems funded by the Federal Energy Management Program (FEMP). The Center is part of the Department of Commerce's National Oceanic and Atmospheric Administration (DOC-NOAA). New

  14. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth while...

  15. Precision Determination of Atmospheric Extinction at Optical...

    Office of Scientific and Technical Information (OSTI)

    a technique to implement a new strategy to directly measure variations of atmospheric transmittance at optical wavelengths and application of these measurements to calibration...

  16. Atmospheric Dispersion Modeling in Safety Analyses; GENII

    Office of Environmental Management (EM)

    part of GENII) 5 GENII Acute Atmospheric Transport Straight-line (centerline) Gaussian plume for individuals For short duration releases (2 hours) Single source...

  17. Atmosphere to Electrons Program Overview Presentation

    Broader source: Energy.gov [DOE]

    This presentation provides an introduction to the Atmosphere to Electrons (A2e) initiative, including objectives, program areas, and a general timeline of activities.

  18. Precision Determination of Atmospheric Extinction at Optical...

    Office of Scientific and Technical Information (OSTI)

    spectra by their characteristic dependences on wavelength and airmass. State-of-the-art models of atmospheric radiation transport and modern codes are used to accurately...

  19. An Instrumentation Complex for Atmospheric Radiation Measurements...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Instrumentation Complex for Atmospheric Radiation Measurements in Siberia S. M. Sakerin, F. V. Dorofeev, D. M. Kabanov, V. S. Kozlov, M. V. Panchenko, Yu. A. Pkhalagov, V. V. ...

  20. Session Papers Atmospheric Radiation Measurement Program- Unmanned...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Session Papers Atmospheric Radiation Measurement Program- Unmanned Aerospace Vehicle: The Follow-On Phase J. Vitko, Jr. ARM-UAV Technical Director Sandia National Laboratories ...

  1. Atmospheric Radiation Measurement Tropical Warm Pool International...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Tropical Warm Pool - International Cloud Experiment (TWP-ICE) was a collaborative effort led by the U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) Program ...

  2. Atmospheric Radiation Measurement Convective and Orographically...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Convective and Orographically Induced Precipitation Study The U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) Climate Research Facility is providing the ARM ...

  3. Sidewall tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Sisson, James B. (Idaho Falls, ID)

    2001-01-01

    A sidewall tensiometer to in situ determine below-grade soil moisture potential of earthen soil includes, a) a body adapted for insertion into an opening in earthen soil below grade, the body having lateral sidewalls; b) a laterally oriented porous material provided relative to the body lateral sidewalls, the laterally oriented porous material at least in part defining a fluid chamber within the body; c) a pressure a sensor in fluid communication with the fluid chamber; and d) sidewall engaging means for engaging a portion of a sidewall of an earth opening to laterally urge the porous material into hydraulic communication with earthen soil of another portion of the opening sidewall. Methods of taking tensiometric measurements are also disclosed.

  4. Acoustic wave (AW) based moisture sensor for use with corrosive gases

    DOE Patents [OSTI]

    Pfeifer, K.B.; Frye, G.C.; Schneider, T.W.

    1996-11-05

    Moisture corrosive gas stream is measured as a function of the difference in resonant frequencies between two acoustic wave (AW) devices, each with a film which accepts at least one of the components of the gas stream. One AW is located in the gas stream while the other is located outside the gas stream but in the same thermal environment. In one embodiment, the film is a hydrophilic material such as SiO{sub 2}. In another embodiment, the SiO{sub 2} is covered with another film which is impermeable to the corrosive gas, such that the AW device in the gas stream measures only the water vapor. In yet another embodiment, the film comprises polyethylene oxide which is hydrophobic and measures only the partial pressure of the corrosive gas. Other embodiments allow for compensation of drift in the system. 8 figs.

  5. Acoustic wave (AW) based moisture sensor for use with corrosive gases

    DOE Patents [OSTI]

    Pfeifer, Kent B. (Los Lunas, NM); Frye, Gregory C. (Cedar Crest, NM); Schneider, Thomas W. (Albuquerque, NM)

    1996-01-01

    Moisture corrosive gas stream is measured as a function of the difference in resonant frequencies between two acoustic wave (AW) devices, each with a film which accepts at least one of the components of the gas stream. One AW is located in the gas stream while the other is located outside the gas stream but in the same thermal environment. In one embodiment, the film is a hydrophilic material such as SiO.sub.2. In another embodiment, the SiO.sub.2 is covered with another film which is impermeable to the corrosive gas, such that the AW device in the gas stream measures only the water vapor. In yet another embodiment, the film comprises polyethylene oxide which is hydrophobic and measures only the partial pressure of the corrosive gas. Other embodiments allow for compensation of drift in the system.

  6. Hygric Redistribution in Insulated Assemblies. Retrofitting Residential Envelopes Without Creating Moisture Issues

    SciTech Connect (OSTI)

    Smegal, J.; Lstiburek, J.

    2013-01-01

    The Building America program has recognized that most of the current housing stock is in need of energy related retrofits. One of the best ways of reducing the space conditioning energy consumption is to improve the thermal performance of the enclosure by adding exterior board foam insulation. This report quantifies the amount of water that can become trapped in the drainage cavity of typical wall systems, and measures the effect of water trapped in the drainage cavity on the moisture content of the sheathing. This study also attempts to explain the discrepancy between hygrothermal simulations and field performance of low permeance, low R-value exterior insulation (e.g. -in. foil faced polyisocyanurate) in cold climates.

  7. Test Plan to Evaluate the Relationship Among IAQ, Comfort, Moisture, and Ventilation in Humid Climates

    SciTech Connect (OSTI)

    Widder, Sarah H.; Martin, Eric

    2013-03-15

    This experimental plan describes research being conducted by Pacific Northwest National Laboratory (PNNL), in coordinatation with Florida Solar Energy Center (FSEC), Florida HERO, and Lawrence Berkeley National Laboratory (LBNL) to evaluate the impact of ventilation rate on interior moisture levels, temperature distributions, and indoor air contaminant concentrations. Specifically, the research team will measure concentrations of indoor air contaminants, ventilation system flow rates, energy consumption, and temperature and relative humidity in ten homes in Gainesville, FL to characterize indoor pollutant levels and energy consumption associated with the observed ventilation rates. PNNL and FSEC have collaboratively prepared this experimental test plan, which describes background and context for the proposed study; the experimental design; specific monitoring points, including monitoring equipment, and sampling frequency; key research questions and the associated data analysis approach; experimental logistics, including schedule, milestones, and team member contact information; and clearly identifies the roles and responsibilities of each team in support of project objectives.

  8. Variation in soil moisture and N availability modulates carbon and water exchange in a California grassland experiment

    SciTech Connect (OSTI)

    St. Clair, S.B.; Sudderth, E.; Fischer, M.L.; Torn, M.S.; Stuart, S.; Salve, R.; Eggett, D.; Ackerly, D.

    2009-03-15

    Variability in the magnitude and timing of precipitation is predicted to change under future climate scenarios. The primary objective of this study was to understand how variation in precipitation patterns consisting of soil moisture pulses mixed with intermittent dry down events influence ecosystem gas fluxes. We characterized the effects of precipitation amount and timing, N availability, and plant community composition on whole ecosystem and leaf gas exchange in a California annual grassland mesocosm study system that allowed precise control of soil moisture conditions. Ecosystem CO2 and fluxes increased significantly with greater precipitation and were positively correlated with soil moisture. A repeated 10 day dry down period following 11 days of variable precipitation inputs strongly depressed net ecosystem CO2 exchange (NEE) across a range of season precipitation totals, and plant community types. Ecosystem respiration (Re), evapotranspiration (ET) and leaf level photosynthesis (Amax) showed greatest sensitivity to dry down periods in low precipitation plots. Nitrogen additions significantly increased NEE, Re and Amax, particularly as water availability was increased. These results demonstrate that N availability and intermittent periods of soil moisture deficit (across a wide range of cumulative season precipitation totals) strongly modulate ecosystem gas exchange.

  9. SULI Intern: Atmospheric Science | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Science Share Hear how Argonne intern Jane Pan helped scientists accurately represent atmospheric conditions in computer models and forecasts. Browse By - Any - Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Diesel ---Electric drive technology ---Hybrid & electric vehicles ---Hydrogen & fuel cells ---Internal combustion ---Powertrain research --Building design ---Construction --Manufacturing -Energy sources --Renewable energy

  10. NREL: Process Development and Integration Laboratory - Atmospheric

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processing Platform Capabilities Atmospheric Processing Platform Capabilities The Atmospheric Processing platform in the Process Development and Integration Laboratory offers powerful capabilities with integrated tools for depositing, processing, and characterizing photovoltaic materials and devices. In particular, this platform focuses on different methods to deposit ("write") materials onto a variety of substrates and then further process into optoelectronic materials using rapid

  11. Indoor climate and moisture durability performances of houses with unvented attic roof constructions in a mixed-humid climate.

    SciTech Connect (OSTI)

    Pallin, Simon B.; Boudreaux, Philip R.; Jackson, Roderick K.

    2014-10-01

    A sealed or unvented attic is an energy-efficient envelope component that can reduce the amount of energy a house consumes for space conditioning if the air handler and/or ducts are located in the attic. The attic is typically sealed by using spray foam on the underside of the roof deck and covering the soffit, ridge and gable vents to minimize air leakage from the attic to the outside. This approach can save up to 10% in space-conditioning energy when ducts are located in the attic (DOE 2013). Past research done by ORNL and Florida Solar Energy Center suggests that in more hot, humid climates, an unvented attic could potentially create a more humid, uncomfortable living environment than a vented attic (Colon 2011, Boudreaux, Pallin et al. 2013). Research showed that controlling the higher indoor humidity could reduce the energy savings from the sealed, unvented attic, which in turn would decrease the energy savings payback. Research also showed that the roof assembly (5.5 inches of open-cell foam, 1inch of closed-cell foam, OSB, felt paper, and asphalt shingles) stored moisture, thus acting as a moisture buffer. During the fall and winter, the roof assembly stored moisture and during the spring and summer it released moisture. This phenomenon is not seen in a vented attic, in which the air exchange rate to the outside is greater and, in the winter, helps to dehumidify the attic air. It was also seen that in a vented attic, the direction of water vapor diffusion is on average from the attic to the interior of the house. Air leakage from the attic to the interior also occurs during more of the year in a house with an unvented attic than in one with a vented attic. These discoveries show that the moisture dynamics in a house with an unvented attic are much different from those in a house with a vented attic. This study reports on a series of computer model investigations completed to determine the key variables impacting indoor comfort and the durability of roof assemblies against moisture. The key variables investigated were the leakage area from the attic to the outside, leakage area from the attic to the interior, leakage area from the interior to the outside, supply duct leakage in the attic, and interior moisture generation. These investigations are described in this report.

  12. Atmospheric sampling glow discharge ionization source

    DOE Patents [OSTI]

    McLuckey, S.A.; Glish, G.L.

    1989-07-18

    An atmospheric sampling glow discharge ionization source that can be used in combination with an analytical instrument which operates at high vacuum, such as a mass spectrometer. The atmospheric sampling glow discharge ionization source comprises a chamber with at least one pair of electrodes disposed therein, an inlet for a gaseous sample to be analyzed and an outlet communicating with an analyzer which operates at subatmospheric pressure. The ionization chamber is maintained at a pressure below atmospheric pressure, and a voltage difference is applied across the electrodes to induce a glow discharge between the electrodes, so that molecules passing through the inlet are ionized by the glow discharge and directed into the analyzer. The ionization source accepts the sample under atmospheric pressure conditions and processes it directly into the high vacuum instrument, bridging the pressure gap and drawing off unwanted atmospheric gases. The invention also includes a method for analyzing a gaseous sample using the glow discharge ionization source described above. 3 figs.

  13. Atmospheric sampling glow discharge ionization source

    DOE Patents [OSTI]

    McLuckey, Scott A. (Oak Ridge, TN); Glish, Gary L. (Oak Ridge, TN)

    1989-01-01

    An atmospheric sampling glow discharge ionization source that can be used in combination with an analytical instrument which operates at high vacuum, such as a mass spectrometer. The atmospheric sampling glow discharge ionization source comprises a chamber with at least one pair of electrodes disposed therein, an inlet for a gaseous sample to be analyzed and an outlet communicating with an analyzer which operates at subatmospheric pressure. The ionization chamber is maintained at a pressure below atmospheric pressure, and a voltage difference is applied across the electrodes to induce a glow discharge between the electrodes, so that molecules passing through the inlet are ionized by the glow discharge and directed into the analyzer. The ionization source accepts the sample under atmospheric pressure conditions and processes it directly into the high vacuum instrument, bridging the pressure gap and drawing off unwanted atmospheric gases. The invention also includes a method for analyzing a gaseous sample using the glow discharge ionization source described above.

  14. Non-OH chemistry in oxidation flow reactors for the study of atmospheric chemistry systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Ortega, A. M.; Palm, B. B.; Hu, W. W.; Stark, H.; Li, R.; Tsigaridis, K.; Brune, W. H.; Jimenez, J. L.

    2015-09-01

    Oxidation flow reactors (OFRs) using low-pressure Hg lamp emission at 185 and 254 nm produce OH radicals efficiently and are widely used in atmospheric chemistry and other fields. However, knowledge of detailed OFR chemistry is limited, allowing speculation in the literature about whether some non-OH reactants, including several not relevant for tropospheric chemistry, may play an important role in these OFRs. These non-OH reactants are UV radiation, O(1D), O(3P), and O3. In this study, we investigate the relative importance of other reactants to OH for the fate of reactant species in OFR under a wide range of conditions via boxmoremodeling. The relative importance of non-OH species is less sensitive to UV light intensity than to relative humidity (RH) and external OH reactivity (OHRext), as both non-OH reactants and OH scale roughly proportional to UV intensity. We show that for field studies in forested regions and also the urban area of Los Angeles, reactants of atmospheric interest are predominantly consumed by OH. We find that O(1D), O(3P), and O3 have relative contributions to VOC consumption that are similar or lower than in the troposphere. The impact of O atoms can be neglected under most conditions in both OFR and troposphere. Under "pathological OFR conditions" of low RH and/or high OHRext, the importance of non-OH reactants is enhanced because OH is suppressed. Some biogenics can have substantial destructions by O3, and photolysis at non-tropospheric wavelengths (185 and 254 nm) may also play a significant role in the degradation of some aromatics under pathological conditions. Working under low O2 with the OFR185 mode allows OH to completely dominate over O3 reactions even for the biogenic species most reactive with O3. Non-tropospheric VOC photolysis may have been a problem in some laboratory and source studies, but can be avoided or lessened in future studies by diluting source emissions and working at lower precursor concentrations in lab studies, and by humidification. SOA photolysis is shown to be insignificant for most functional groups, except for nitrates and especially aromatics, which may be photolyzed at high UV flux settings. Our work further establishes the OFR's usefulness as a tool to study atmospheric chemistry and enables better experiment design and interpretation, as well as improved future reactor design.less

  15. SWiFT site atmospheric characterization

    SciTech Connect (OSTI)

    Kelley, Christopher Lee; Ennis, Brandon Lee

    2016-01-01

    Historical meteorological tall tower data are analyzed from the Texas Tech University 200 m tower to characterize the atmospheric trends of the Scaled Wind Farm Technologies (SWiFT) site. In this report the data are analyzed to reveal bulk atmospheric trends, temporal trends and correlations of atmospheric variables. Through this analysis for the SWiFT turbines the site International Electrotechnical Commission (IEC) classification is determined to be class III-C. Averages and distributions of atmospheric variables are shown, revealing large fluctuations and the importance of understanding the actual site trends as opposed to simply using averages. The site is significantly directional with the average wind speed from the south, and particularly so in summer and fall. Site temporal trends are analyzed from both seasonal (time of the year) to daily (hour of the day) perspectives. Atmospheric stability is seen to vary most with time of day and less with time of year. Turbulence intensity is highly correlated with stability, and typical daytime unstable conditions see double the level of turbulence intensity versus that experienced during the average stable night. Shear, veer and atmospheric stability correlations are shown, where shear and veer are both highest for stable atmospheric conditions. An analysis of the Texas Tech University tower anemometer measurements is performed which reveals the extent of the tower shadow effects and sonic tilt misalignment.

  16. Electronic structure of Ce?RhIn?: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Petrovic, C.; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimoresheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.less

  17. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Sisson, James B. (Idaho Falls, ID)

    1997-01-01

    A portable tensiometer to in situ determine below-grade soil moisture potential of earthen soil includes, a) a body having opposing first and second ends and being adapted for complete insertion into earthen soil below grade; b) a porous material provided at the first body end, the porous material at least in part defining a fluid chamber within the body at the first body end, the fluid chamber being fluidically sealed within the body but for the porous material; c) a degassed liquid received within the fluid chamber; d) a pressure transducer mounted in fluid communication with the fluid chamber; e) the body, pressure transducer and degassed liquid having a combined mass; f) a flexible suspension line connected to the body adjacent the second body end, the flexible line being of sufficient strength to gravitationally freely self suspend the combined mass; and c) the combined mass being sufficient to effectively impart hydraulic communication between below-grade earthen soil contacted by the porous material under the weight of the combined mass. Tensiometers configured to engage the sidewalls of an earthen opening are also disclosed. Methods of taking tensiometric measurements are also disclosed.

  18. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, J.M.; Sisson, J.B.

    1997-07-08

    A portable tensiometer to in-situ determine below-grade soil moisture potential of earthen soil includes, (a) a body having opposing first and second ends and being adapted for complete insertion into earthen soil below grade; (b) a porous material provided at the first body end, the porous material at least in part defining a fluid chamber within the body at the first body end, the fluid chamber being fluidically sealed within the body but for the porous material; (c) a degassed liquid received within the fluid chamber; (d) a pressure transducer mounted in fluid communication with the fluid chamber; (e) the body, pressure transducer and degassed liquid having a combined mass; (f) a flexible suspension line connected to the body adjacent the second body end, the flexible line being of sufficient strength to gravitationally freely self suspend the combined mass; and (g) the combined mass being sufficient to effectively impart hydraulic communication between below-grade earthen soil contacted by the porous material under the weight of the combined mass. Tensiometers configured to engage the sidewalls of an earthen opening are also disclosed. Methods of taking tensiometric measurements are also disclosed. 12 figs.

  19. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Mattson, Earl D. (Albuquerque, NM); Sisson, James B. (Idaho Falls, ID)

    1998-01-01

    A tensiometer to in situ determine below-grade soil moisture, potential of earthen soil includes, a) an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and, comprising; b) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; c) a first fluid conduit extending outwardly of the first fluid chamber; d) a first controllable isolation valve provided within the first fluid conduit, the first controllable isolation valve defining a second fluid chamber in fluid communication with the first fluid chamber through the first fluid conduit and the isolation valve, the first controllable isolation valve being received within the below-grade portion; and e) a pressure transducer in fluid communication with the first fluid chamber, the pressure transducer being received within the below-grade portion. An alternate embodiment includes an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and including: i) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; and ii) a pressure sensing apparatus in fluid communication with the first fluid chamber, the pressure sensing apparatus being entirely received within the below-grade portion. A method is also disclosed using the above and other apparatus.

  20. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, J.M.; Mattson, E.D.; Sisson, J.B.

    1998-06-02

    A tensiometer to in-situ determine below-grade soil moisture, potential of earthen soil includes, (a) an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and, comprising; (b) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; (c) a first fluid conduit extending outwardly of the first fluid chamber; (d) a first controllable isolation valve provided within the first fluid conduit, the first controllable isolation valve defining a second fluid chamber in fluid communication with the first fluid chamber through the first fluid conduit and the isolation valve, the first controllable isolation valve being received within the below-grade portion; and (e) a pressure transducer in fluid communication with the first fluid chamber, the pressure transducer being received within the below-grade portion. An alternate embodiment includes an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and including: (1) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; and (2) a pressure sensing apparatus in fluid communication with the first fluid chamber, the pressure sensing apparatus being entirely received within the below-grade portion. A method is also disclosed using the above and other apparatus. 6 figs.

  1. Effect of moisture on the traction-separation behavior of cellulose nanocrystal interfaces

    SciTech Connect (OSTI)

    Sinko, Robert; Keten, Sinan

    2014-12-15

    Interfaces and stress transfer between cellulose nanocrystals (CNCs) dictate the mechanical properties of hierarchical cellulose materials such as neat films and nanocomposites. An interesting question that remains is how the behavior of these interfaces changes due to environmental stimuli, most notably moisture. We present analyses on the traction-separation behavior between I? CNC elementary fibrils, providing insight into how the presence of a single atomic layer of water at these interfaces can drastically change the mechanical behavior. We find that molecular water at the interface between hydrophilic CNC surfaces has a negligible effect on the tensile separation adhesion energy. However, when water cannot hydrogen bond easily to the surface (i.e., hydrophobic surface), it tends to maintain hydrogen bonds with other water molecules across the interface and form a capillary bridge that serves to increase the energy required to separate the crystals. Under shear loading, water lowers the energy barriers to sliding by reducing the atomic friction and consequently the interlayer shear modulus between crystals. Our simulations indicate that these nanoscale interfaces and physical phenomena such as interfacial adhesion, interlayer shear properties, and stick-slip friction behavior can be drastically altered by the presence of water.

  2. Pavlos Kollias Associate Professor Department of Atmospheric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pavlos Kollias Associate Professor Department of Atmospheric and Oceanic Sciences, McGill University Room 817, Burnside Hall, 805 Sherbrooke Street West, Montreal, Quebec, H3A 0B9...

  3. Operating Experience Level 3, Atmospheric Dispersion Parameter...

    Broader source: Energy.gov (indexed) [DOE]

    5 OE-3 2015-02: Atmospheric Dispersion Parameter (xQ) for Calculation of Co-located Worker Dose This Operating Experience Level 3 (OE-3) document informs the complex of the...

  4. Free Floating Atmospheric Pressure Ball Plasmas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Free-Floating Atmospheric Pressure Ball Plasmas G. A. Wurden, Z. Wang, C. Ticos Los Alamos National Laboratory L Al NM 87545 USA Los Alamos, NM 87545 USA C. J. v. Wurden Los Alamos...

  5. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    2008-01-15

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  6. Air Activation Following an Atmospheric Explosion

    SciTech Connect (OSTI)

    Lowrey, Justin D.; McIntyre, Justin I.; Prichard, Andrew W.; Gesh, Christopher J.

    2013-03-13

    In addition to thermal radiation and fission products, nuclear explosions result in a very high flux of unfissioned neutrons. Within an atmospheric nuclear explosion, these neutrons can activate the various elemental components of natural air, potentially adding to the radioactive signature of the event as a whole. The goal of this work is to make an order-of-magnitude estimate of the total amount of air activation products that can result from an atmospheric nuclear explosion.

  7. Atmospheric and Climate Science | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric and Climate Science Argonne research in aerosols, micro-meteorology, remote sensing, and atmospheric chemistry combined with our scalable, portable, high-performance climate and weather applications offer a unique look at the complexities of a dynamic planet. Changes in climate can affect biodiversity, the cost of food, our health, and even whole economies. Argonne is developing computational models and tools designed to shed light on complex biological processes and their economic,

  8. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  9. Atmospheric Neutrinos in the MINOS Far Detector

    SciTech Connect (OSTI)

    Howcroft, Caius L.F.

    2004-12-01

    The phenomenon of flavour oscillations of neutrinos created in the atmosphere was first reported by the Super-Kamiokande collaboration in 1998 and since then has been confirmed by Soudan 2 and MACRO. The MINOS Far Detector is the first magnetized neutrino detector able to study atmospheric neutrino oscillations. Although it was designed to detect neutrinos from the NuMI beam, it provides a unique opportunity to measure the oscillation parameters for neutrinos and anti-neutrinos independently. The MINOS Far Detector was completed in August 2003 and since then has collected 2.52 kton-years of atmospheric data. Atmospheric neutrino interactions contained within the volume of the detector are separated from the dominant background from cosmic ray muons. Thirty seven events are selected with an estimated background contamination of less than 10%. Using the detector's magnetic field, 17 neutrino events and 6 anti-neutrino events are identified, 14 events have ambiguous charge. The neutrino oscillation parameters for {nu}{sub {mu}} and {bar {nu}}{sub {mu}} are studied using a maximum likelihood analysis. The measurement does not place constraining limits on the neutrino oscillation parameters due to the limited statistics of the data set analysed. However, this thesis represents the first observation of charge separated atmospheric neutrino interactions. It also details the techniques developed to perform atmospheric neutrino analyses in the MINOS Far Detector.

  10. Correlation between ERMI values and other Moisture and Mold Assessments of Homes in the American Healthy Home Survey

    SciTech Connect (OSTI)

    Vesper, Sephen J.; McKinstry, Craig A.; Cox, David J.; DeWalt, Gary

    2009-11-30

    Objective: The objective of this study was to determine the correlation between ERMI values in the HUD American Healthy Home Survey (AHHS) homes and either inspector reports or occupant assessments of mold and moisture. Methods: In the AHHS, moisture and mold were assessed by a pair of inspectors and with an occupant questionnaire. These results were compared to the results of the Environmental Relative Moldiness Index (ERMI) values for each home. Results: Homes in the highest ERMI quartile were most often in agreement with visual inspection and/or occupant assessment. However, in 52% of the fourth quartile ERMI homes, the inspector and occupant assessment did not indicate water or mold problems. Yet the concentrations of each ERMI panel mold species detected in all fourth quartile homes were statistically indistinguishable. Conclusions: About 50% of water-damaged, moldy homes were not detected by inspection or questioning of the occupant about water and mold.

  11. Flexible Residential Test Facility: Impact of Infiltration and Ventilation on Measured Heating Season Energy and Moisture Levels

    SciTech Connect (OSTI)

    Vieira, R.; Parker, D.; Fairey, P.; Sherwin, J.; Withers, C.; Hoak, D.

    2013-09-01

    Two identical laboratory homes designed to model existing Florida building stock were sealed and tested to 2.5 ACH50. Then, one was made leaky with 70% leakage through the attic and 30% through windows, to a tested value of 9 ACH50. Reduced energy use was measured in the tighter home (2.5 ACH50) in the range of 15% to 16.5% relative to the leaky (9 ACH50) home. Internal moisture loads resulted in higher dew points inside the tight home than the leaky home. Window condensation and mold growth occurred inside the tight home. Even cutting internal moisture gains in half to 6.05 lbs/day, the dew point of the tight home was more than 15 degrees F higher than the outside dry bulb temperature. The homes have single pane glass representative of older Central Florida homes.

  12. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final...

    Office of Scientific and Technical Information (OSTI)

    Title: Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary ... estimates of regional land-atmosphere carbon exchange (i.e., estimates based on ...

  13. Global Atmospheric Pollution Forum Air Pollutant Emission Inventory...

    Open Energy Info (EERE)

    Atmospheric Pollution Forum Air Pollutant Emission Inventory Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Global Atmospheric Pollution (GAP) Forum Air Pollutant...

  14. Radar range measurements in the atmosphere. (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Radar range measurements in the atmosphere. Citation Details In-Document Search Title: Radar range measurements in the atmosphere. You are accessing a document from the...

  15. Simulation and Theory of Ions at Atmospherically Relevant Aqueous...

    Office of Scientific and Technical Information (OSTI)

    Simulation and Theory of Ions at Atmospherically Relevant Aqueous Liquid-Air Interfaces Citation Details In-Document Search Title: Simulation and Theory of Ions at Atmospherically...

  16. A marine biogenic source of atmospheric ice-nucleating particles...

    Office of Scientific and Technical Information (OSTI)

    A marine biogenic source of atmospheric ice-nucleating particles Citation Details In-Document Search Title: A marine biogenic source of atmospheric ice-nucleating particles The ...

  17. Model-Observation "Data Cubes" for the DOE Atmospheric Radiation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model-Observation "Data Cubes" for the DOE Atmospheric Radiation Measurement Facility's ... Program through its Atmospheric Radiation Measurement Facility. 2. Data Cube ...

  18. Posters Single-Column Model for Atmospheric Radiation Measurement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Posters Single-Column Model for AtmosphericRadiation Measurement Sites: Model Development ... Using observational data obtained from the Oklahoma Atmospheric Radiation Measurement ...

  19. A U. S. Department of Energy User Facility Atmospheric Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    S. Department of Energy User Facility AtmosphericRadiationMeasurement Climate Research Facility U.S. Department of Energy Atmospheric Radiation Measurement Program DOESC-ARM...

  20. Session Papers Quality Measurement Experiments Within the Atmospheric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quality Measurement Experiments Within the Atmospheric Radiation Measurement Program N. E. ... Introduction The general goal of the Atmospheric RadiationMeasurement (ARM) Program is to ...

  1. Modeling Workflow for the DOE Atmospheric Radiation Measurement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workflow for the DOE Atmospheric Radiation Measurement Facility's LES ARM Symbiotic ... and Environmental Research Program through its Atmospheric Radiation Measurement Facility. ...

  2. ARMlUnmanned Air VehiclelSatelites The Atmospheric Radiation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARMlUnmanned Air VehiclelSatelites The Atmospheric Radiation Measurement Unmanned ... This program has its origins in the Atmospheric RadiationMeasurement (ARM) Program's long ...

  3. DOE/SC-ARM-020 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    20 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-020 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  4. Posters Objective Analysis Schemes to Monitor Atmospheric Radiation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Objective Analysis Schemes to Monitor AtmosphericRadiation Measurement Data in Near ... large networks of instruments such as the AtmosphericRadiation Measurement (ARM) Program. ...

  5. Style Guide Atmospheric Radiation Measurement (ARM) Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Style Guide Atmospheric Radiation Measurement (ARM) Climate Research Facility March 2013 Style Guide Atmospheric Radiation Measurement Climate Research Facility March 2013 Work ...

  6. A Decade of Atmospheric Research in the Tropical Western Pacific...

    Office of Science (SC) Website

    The Atmospheric Radiation Measurement (ARM) Climate Research Facility has three user ... The Science The Department of Energy's Atmospheric Radiation Measurement (ARM) Climate ...

  7. Influence of moisture content, particle size and forming temperature on productivity and quality of rice straw pellets

    SciTech Connect (OSTI)

    Ishii, Kazuei Furuichi, Toru

    2014-12-15

    Highlights: • Optimized conditions were determined for the production of rice straw pellets. • The moisture content and forming temperature are key factors. • High quality rice pellets in the lower heating value and durability were produced. - Abstract: A large amount of rice straw is generated and left as much in paddy fields, which causes greenhouse gas emissions as methane. Rice straw can be used as bioenergy. Rice straw pellets are a promising technology because pelletization of rice straw is a form of mass and energy densification, which leads to a product that is easy to handle, transport, store and utilize because of the increase in the bulk density. The operational conditions required to produce high quality rice straw pellets have not been determined. This study determined the optimal moisture content range required to produce rice straw pellets with high yield ratio and high heating value, and also determined the influence of particle size and the forming temperature on the yield ratio and durability of rice straw pellets. The optimal moisture content range was between 13% and 20% under a forming temperature of 60 or 80 °C. The optimal particle size was between 10 and 20 mm, considering the time and energy required for shredding, although the particle size did not significantly affect the yield ratio and durability of the pellets. The optimized conditions provided high quality rice straw pellets with nearly 90% yield ratio, ⩾12 MJ/kg for the lower heating value, and >95% durability.

  8. Calibration of a Neutron Hydroprobe for Moisture Measurements in Small-Diameter Steel-Cased Boreholes

    SciTech Connect (OSTI)

    Ward, Anderson L.; Wittman, Richard S.

    2009-08-01

    Computation of soil moisture content from thermalized neutron counts for the T-Farm Interim cover requires a calibration relationship but none exists for 2-in tubes. A number of calibration options are available for the neutron probe, including vendor calibration, field calibration, but none of these methods were deemed appropriate for the configuration of interest. The objective of this work was to develop a calibration relation for converting neutron counts measured in 2-in access tubes to soil water content. The calibration method chosen for this study was a computational approach using the Monte Carlo N-Particle Transport Code (MCNP). Model calibration was performed using field measurements in the Hanford calibration models with 6-in access tubes, in air and in the probe shield. The bet-fit model relating known water content to measured neutron counts was an exponential model that was essentially equivalent to that currently being used for 6-in steel cased wells. The MCNP simulations successfully predicted the neutron count rate for the neutron shield and the three calibration models for which data were collected in the field. However, predictions for air were about 65% lower than the measured counts . This discrepancy can be attributed to uncertainties in the configuration used for the air measurements. MCNP-simulated counts for the physical models were essentially equal to the measured counts with values. Accurate prediction of the response in 6-in casings in the three calibration models was motivation to predict the response in 2-in access tubes. Simulations were performed for six of the seven calibration models as well as 4 virtual models with the entire set covering a moisture range of 0 to 40%. Predicted counts for the calibration models with 2-in access tubes were 40 to 50% higher than in the 6-inch tubes. Predicted counts for water were about 60% higher in the 2-in tube than in the 6-in tube. The discrepancy between the 2-in and 6-in tube can be attributed to the smaller air gap between the probe and the 2-in access tube. The best-fit model relating volumetric water content to count ratio (CR) is of the form e^A x CR^B with A=0.3596 0.0216 and B=0.4629 0.0629 and r^2= 0.9998. It is recommended that the calibration function based on the count ratio, rather than raw counts, be used to avoid the effects of electronic noise in the probe that may arise due to the conditions at the time of measurement. These results suggest that the MCNP code can be used to extend calibrations for the neutron probe to different conditions including access tube size as well as composition without the need to construct additional physical models.

  9. Multi-scale Atmospheric Modeling of Green House Gas Dispersion in Complex Terrain. Atmospheric Methane at Four Corners

    SciTech Connect (OSTI)

    Costigan, Keeley Rochelle; Dubey, Manvendra Krishna

    2015-07-10

    Atmospheric models are compared in collaboration with LANL and the University of Michigan to understand emissions and the condition of the atmosphere from a model perspective.

  10. Field-scale investigation of enhanced petroleum hydrocarbon biodegradation in the vadose zone combining soil venting as an oxygen source with moisture and nutrient addition. Appendices. Doctoral thesis

    SciTech Connect (OSTI)

    Miller, R.N.

    1990-01-01

    This document contains appendices regarding a reprint on a field scale investigation of enhanced petroleum hydrocarbon biodegradation in the vadose zone combining soil venting as a oxygen source with moisture and nutrient addition.

  11. High moisture corn stover pelleting in a flat die pellet mill fitted with a 6 mm die: physical properties and specific energy consumption

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluru, Jaya Shankar

    2015-06-15

    The quality and specific energy consumption (SEC) of the biomass pellets produced depend upon pelleting process conditions. The present study includes understanding the effect of feedstock moisture in the range of 28–38% (wet basis [w.b.]) and preheating in the range of 30–110°C at two die speeds of 40 and 60 Hz on the physical properties and SEC. A flat die pellet mill fitted with a 6 mm die was used in the present study. The physical properties of pellets such as moisture content, unit, bulk and tapped density, durability, and expansion ratio and SEC of the pelleting process are measured.more » The results indicate that the pellets produced have durability values in the range of 87–98%, and unit bulk and tapped density in the range of 670–1100, 375–575, and 420–620 kg/m³. Increasing the feedstock moisture content from 33% to 38% (w.b) decreased the unit, bulk and tapped density by about 30–40%. Increasing feedstock moisture content increased the expansion ratio and decreased the density values. A higher feedstock moisture content of 38% (w.b.) and higher preheating temperature of 110°C resulted in lower density and a higher expansion ratio, which can be attributed to flash off of moisture as the material extrudes out of the die. The SEC was in the range of 75–275 kWh/ton. Higher feedstock moisture content of 38% (w.b.) and a lower die speed of 40 Hz increased the SEC, whereas lower to medium preheating temperature (30–70°C), medium feedstock moisture content of 33% (w.b.), and a higher die speed of 60 Hz minimized the SEC to <100 kWh/ton.« less

  12. Atmospheric Pressure Plasma Process And Applications

    SciTech Connect (OSTI)

    Peter C. Kong; Myrtle

    2006-09-01

    This paper provides a general discussion of atmospheric-pressure plasma generation, processes, and applications. There are two distinct categories of atmospheric-pressure plasmas: thermal and nonthermal. Thermal atmospheric-pressure plasmas include those produced in high intensity arcs, plasma torches, or in high intensity, high frequency discharges. Although nonthermal plasmas are at room temperatures, they are extremely effective in producing activated species, e.g., free radicals and excited state atoms. Thus, both thermal and nonthermal atmosphericpressure plasmas are finding applications in a wide variety of industrial processes, e.g. waste destruction, material recovery, extractive metallurgy, powder synthesis, and energy conversion. A brief discussion of recent plasma technology research and development activities at the Idaho National Laboratory is included.

  13. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA)

    1998-01-01

    A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

  14. Our Dusty Atmosphere | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dusty Atmosphere Our Dusty Atmosphere September 6, 2011 - 4:26pm Addthis A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest National Laboratory show the importance of including the small-scale effects of aerosols in climate modeling. | Image courtesy of PNNL A heavy layer of air pollution, a mix of aerosol particles and vapors, obscures the view over Mexico City. Two studies by the Pacific Northwest

  15. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, S.P.; Woods, R.W.

    1998-08-11

    A process is disclosed for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750 C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5--3000 ppm in order to obtain a desired composition in the resulting composite. 2 figs.

  16. Electronic structure of Ce2RhIn8: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Petrovic, C.; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce₂RhIn₈. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) π/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore » sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. As a result, our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  17. Connectivity To Atmospheric Release Advisory Capability

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-02-26

    To establish DOE and NNSA connectivity to Atmospheric Release Advisory Capability (ARAC) for sites and facilities that have the potential for releasing hazardous materials sufficient to generate certain emergency declarations and to promote efficient use of resources for consequence assessment activities at DOE sites, facilities, operations, and activities in planning for and responding to emergency events. No cancellations.

  18. Application of lidar to current atmospheric topics

    SciTech Connect (OSTI)

    Sedlacek, A.J. III

    1996-12-31

    The goal of the conference was to address the various applications of lidar to topics of interest in the atmospheric community. Specifically, with the development of frequency-agile, all solid state laser systems, high-quantum-efficiency detectors, increased computational power along with new and more powerful algorithms, and novel detection schemes, the application of lidar to both old and new problems has expanded. This expansion is evidenced by the contributions to the proceedings, which demonstrate the progress made on a variety of atmospheric remote sensing problems, both theoretically and experimentally. The first session focused on aerosol, ozone, and temperature profile measurements from ground-based units. The second session, Chemical Detection, provided applications of lidar to the detection of atmospheric pollutants. Papers in the third session, Wind and Turbulence Measurements, described the Multi-center Airborne Coherent Atmospheric Wind Sensor (MACAWS) experiments, Doppler techniques for ground-based wind profiling and mesopause radial wind and temperature measurements utilizing a frequency-agile lidar system. The papers in the last two sessions, Recent Advanced in Lidar Technology and Techniques and Advanced Operational Lidars, provided insights into novel approaches, materials, and techniques that would be of value to the lidar community. Papers have been processed separately for inclusion on the data base.

  19. Atmospheric Science: Solving Challenges of Climate Change

    SciTech Connect (OSTI)

    Geffen, Charlette

    2015-08-05

    PNNLs atmospheric science research provides data required to make decisions about challenges presented by climate change: Where to site power plants, how to manage water resources, how to prepare for severe weather events and more. Our expertise in fundamental observations and modeling is recognized among the national labs and the world.

  20. CHARACTERIZATION OF CLOUDS IN TITAN'S TROPICAL ATMOSPHERE

    SciTech Connect (OSTI)

    Griffith, Caitlin A.; Penteado, Paulo; Rodriguez, Sebastien; Baines, Kevin H.; Buratti, Bonnie; Sotin, Christophe; Clark, Roger; Nicholson, Phil; Jaumann, Ralf

    2009-09-10

    Images of Titan's clouds, possible over the past 10 years, indicate primarily discrete convective methane clouds near the south and north poles and an immense stratiform cloud, likely composed of ethane, around the north pole. Here we present spectral images from Cassini's Visual Mapping Infrared Spectrometer that reveal the increasing presence of clouds in Titan's tropical atmosphere. Radiative transfer analyses indicate similarities between summer polar and tropical methane clouds. Like their southern counterparts, tropical clouds consist of particles exceeding 5 {mu}m. They display discrete structures suggestive of convective cumuli. They prevail at a specific latitude band between 8 deg. - 20 deg. S, indicative of a circulation origin and the beginning of a circulation turnover. Yet, unlike the high latitude clouds that often reach 45 km altitude, these discrete tropical clouds, so far, remain capped to altitudes below 26 km. Such low convective clouds are consistent with the highly stable atmospheric conditions measured at the Huygens landing site. Their characteristics suggest that Titan's tropical atmosphere has a dry climate unlike the south polar atmosphere, and despite the numerous washes that carve the tropical landscape.

  1. Impact of Sequential Ammonia Fiber Expansion (AFEX) Pretreatment and Pelletization on the Moisture Sorption Properties of Corn Stover

    SciTech Connect (OSTI)

    Bonner, Ian J.; Thompson, David N.; Teymouri, Farzaneh; Campbell, Timothy; Bals, Bryan; Tumuluru, Jaya Shankar

    2015-05-01

    Combining ammonia fiber expansion (AFEX) pretreatment with a depot processing facility is a promising option for delivering high-value densified biomass to the emerging bioenergy industry. However, because the pretreatment process results in a high moisture material unsuitable for pelleting or storage (40% wet basis), the biomass must be immediately dried. If AFEX pretreatment results in a material that is difficult to dry, the economics of this already costly operation would be at risk. This work tests the nature of moisture sorption isotherms and thin-layer drying behavior of corn (Zea mays L.) stover at 20C to 60C before and after sequential AFEX pretreatment and pelletization to determine whether any negative impacts to material drying or storage may result from the AFEX process. The equilibrium moisture content to equilibrium relative humidity relationship for each of the materials was determined using dynamic vapor sorption isotherms and modeled with modified Chung-Pfost, modified Halsey, and modified Henderson temperature-dependent models as well as the Double Log Polynomial (DLP), Peleg, and Guggenheim Anderson de Boer (GAB) temperature-independent models. Drying kinetics were quantified under thin-layer laboratory testing and modeled using the Modified Page's equation. Water activity isotherms for non-pelleted biomass were best modeled with the Peleg temperature-independent equation while isotherms for the pelleted biomass were best modeled with the Double Log Polynomial equation. Thin-layer drying results were accurately modeled with the Modified Page's equation. The results of this work indicate that AFEX pretreatment results in drying properties more favorable than or equal to that of raw corn stover, and pellets of superior physical stability in storage.

  2. Reducing the moisture content of clean coals. Volume 2, High-G solid-bowl centrifuge: Final report

    SciTech Connect (OSTI)

    Kehoe, D.

    1992-12-01

    Coal moisture content can profoundly effect the cost of burning coal in utility boilers. Because of the large effect of coal moisture, the Empire State Electric Energy Research Corporation (ESEERCO) contracted with the Electric Power Research Institute to investigate advanced coal dewatering methods at its Coal Quality Development Center. This report contains the test result on the high-G solid-bowl centrifuge, the second of four devices to be tested. The high-G solid-bowl centrifuge removes water for coal by spinning the coal/water mixture rapidly in a rotating bowl. This causes the coal to cling to the sides of the bowl where it can be removed, leaving the water behind. Testing was performed at the CQDC to evaluate the effect of four operating variables (G-ratio, feed solids concentration, dry solids feed rate, and differential RPM) on the performance of the high-G solid-bowl centrifuge. Two centrifuges of different bowl diameter were tested to establish the effect of scale-up of centrifuge performance. Testing of the two centrifuges occurred from 1985 through 1987. CQDC engineers performed 32 tests on the smaller of the two centrifuges, and 47 tests on the larger. Equations that predict the performance of the two centrifuges for solids recovery, moisture content of the produced coal, and motor torque were obtained. The equations predict the observed data well. Traditional techniques of establishing the performance of centrifuge of different scale did not work well with the two centrifuges, probably because of the large range of G-ratios used in the testing. Cost of operating a commercial size bank of centrifuges is approximately $1.72 per ton of clean coal. This compares well with thermal drying, which costs $1.82 per ton of clean coal.

  3. Intermediate valence in single crystals of (Lu{sub 1?x}Y b{sub x}){sub 3}Rh{sub 4}Ge{sub 13} (0 ? x ? 1)

    SciTech Connect (OSTI)

    Rai, Binod K.; Morosan, E.

    2015-04-01

    Single crystals of (Lu{sub 1?x}Y b{sub x}){sub 3}Rh{sub 4}Ge{sub 13} were characterized by magnetization, specific heat, and electrical resistivity measurements. Doping Yb into the non-magnetic Lu{sub 3}Rh{sub 4}Ge{sub 13} compound tunes this cubic systems properties from a superconductor with disordered metal normal state (x < 0.05) to a Kondo for 0.05 ? x ?0.2 and intermediate valence at the highest Yb concentrations. The evidence for intermediate Yb valence comes from a broad maximum in the magnetic susceptibility and X-ray photoelectron spectroscopy. Furthermore, the resistivity displays a local maximum at finite temperatures at intermediate compositions x, followed by apparent metallic behavior closest to the Yb end compound in the series.

  4. Flexible Residential Test Facility: Impact of Infiltration and Ventilation on Measured Heating Season Energy and Moisture Levels

    SciTech Connect (OSTI)

    2013-09-01

    Two identical laboratory homes designed to model existing Florida building stock were sealed and tested to 2.5 ACH50. Then, one was made leaky with 70% leakage through the attic and 30% through windows, to a tested value of 9 ACH50. Reduced energy use was measured in the tighter home (2.5 ACH50) in the range of 15% to 16.5% relative to the leaky (9 ACH50) home. Internal moisture loads resulted in higher dew points inside the tight home than the leaky home. Window condensation and mold growth occurred inside the tight home.

  5. Change in magnetic and structural properties of FeRh thin films by gold cluster ion beam irradiation with the energy of 1.67?MeV/atom

    SciTech Connect (OSTI)

    Koide, T.; Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Sakamaki, M.; Amemiya, K. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801 (Japan); Matsui, T., E-mail: t-matsui@21c.osakafu-u.ac.jp [Research Organization for the 21st Century, Osaka Prefecture University Sakai, Osaka 599-8531 (Japan)

    2014-05-07

    The effect of energetic cluster ion beam irradiation on magnetic and structural properties of FeRh thin films have been investigated. The cluster ions used in the present studies consist of a few gold atoms with the energy of 1.67?MeV/gold atom. Saturation magnetization of the sample irradiated with Au3 cluster ion beam (280?emu/cc) is larger than that for the irradiated sample with Au1 ion beam (240?emu/cc) for the same irradiation ion fluence. These results can also be confirmed by the X-ray magnetic circular dichroism (XMCD) measurement; the XMCD signal for Au3 cluster ion irradiation is larger than that for Au1 ion irradiation. Since the ion beam irradiation induced magnetization of FeRh is significantly correlated with the amount of the lattice defects in the samples, cluster ion beam irradiation can be considered to effectively introduce the lattice defects in B2-type FeRh rather than the single ion beam. Consequently, cluster ion irradiation is better than single ion irradiation for the viewpoint of saturation magnetization, even if the same irradiation energy is deposited in the samples.

  6. ANALYTICAL MODELS OF EXOPLANETARY ATMOSPHERES. I. ATMOSPHERIC DYNAMICS VIA THE SHALLOW WATER SYSTEM

    SciTech Connect (OSTI)

    Heng, Kevin; Workman, Jared E-mail: jworkman@coloradomesa.edu

    2014-08-01

    Within the context of exoplanetary atmospheres, we present a comprehensive linear analysis of forced, damped, magnetized shallow water systems, exploring the effects of dimensionality, geometry (Cartesian, pseudo-spherical, and spherical), rotation, magnetic tension, and hydrodynamic and magnetic sources of friction. Across a broad range of conditions, we find that the key governing equation for atmospheres and quantum harmonic oscillators are identical, even when forcing (stellar irradiation), sources of friction (molecular viscosity, Rayleigh drag, and magnetic drag), and magnetic tension are included. The global atmospheric structure is largely controlled by a single key parameter that involves the Rossby and Prandtl numbers. This near-universality breaks down when either molecular viscosity or magnetic drag acts non-uniformly across latitude or a poloidal magnetic field is present, suggesting that these effects will introduce qualitative changes to the familiar chevron-shaped feature witnessed in simulations of atmospheric circulation. We also find that hydrodynamic and magnetic sources of friction have dissimilar phase signatures and affect the flow in fundamentally different ways, implying that using Rayleigh drag to mimic magnetic drag is inaccurate. We exhaustively lay down the theoretical formalism (dispersion relations, governing equations, and time-dependent wave solutions) for a broad suite of models. In all situations, we derive the steady state of an atmosphere, which is relevant to interpreting infrared phase and eclipse maps of exoplanetary atmospheres. We elucidate a pinching effect that confines the atmospheric structure to be near the equator. Our suite of analytical models may be used to develop decisively physical intuition and as a reference point for three-dimensional magnetohydrodynamic simulations of atmospheric circulation.

  7. Perspective: Water cluster mediated atmospheric chemistry

    SciTech Connect (OSTI)

    Vaida, Veronica

    2011-07-14

    The importance of water in atmospheric and environmental chemistry initiated recent studies with results documenting catalysis, suppression and anti-catalysis of thermal and photochemical reactions due to hydrogen bonding of reagents with water. Water, even one water molecule in binary complexes, has been shown by quantum chemistry to stabilize the transition state and lower its energy. However, new results underscore the need to evaluate the relative competing rates between reaction and dissipation to elucidate the role of water in chemistry. Water clusters have been used successfully as models for reactions in gas-phase, in aqueous condensed phases and at aqueous surfaces. Opportunities for experimental and theoretical chemical physics to make fundamental new discoveries abound. Work in this field is timely given the importance of water in atmospheric and environmental chemistry.

  8. Pulsed atmospheric fluidized bed combustor apparatus

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1993-10-26

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

  9. Atmosphere to Electrons Initiative Takes Shape

    Broader source: Energy.gov [DOE]

    Since DOE launched its Atmosphere to Electrons (A2e) Initiative last July, the A2e executive committee has been developing a comprehensive approach for working with multiple stakeholders (industry, national laboratories, international experts, and universities) over the next 5- to 7 years. In February, they held an external merit review to lay the groundwork for an A2e multi-year strategic research plan.

  10. Emerging Technology for Measuring Atmospheric Aerosol Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology for Measuring Atmospheric Aerosol Properties Bruce Gandrud Greg Kok Droplet Measurement Technologies Darrel Baumgardner Centro de Ciencias de la Atmósfera Universidad Nacional Autónoma de México Acknowledgements * The DMT staff * Bob Bluth and Haflidi Jonsson * Pat Arnott * Greg Roberts and Thanos Nenes * Dave Fahey, Shuka Schwarz and Ru-Shan Gao * NSF, NASA, ONR, NOAA and DOE Introducing Droplet Measurement Technologies * Founded in 1987 * Specializing in aerosol and cloud

  11. High Hydrogen Concentrations Detected In The Underground Vaults For RH-TRU Waste At INEEL Compared With Calculated Values Using The INEEL-Developed Computer Code

    SciTech Connect (OSTI)

    Rajiv Bhatt; Soli Khericha

    2005-02-01

    About 700 remote-handled transuranic (RH-TRU) waste drums are stored in about 144 underground vaults at the Intermediate-Level Transuranic Storage Facility at the Idaho National Environmental and Engineering Laboratorys (INEELs) Radioactive Waste Management Complex (RWMC). These drums were shipped to the INEEL from 1976 through 1996. During recent monitoring, concentrations of hydrogen were found to be in excess of lower explosive limits. The hydrogen concentration in one vault was detected to be as high as 18% (by volume). This condition required evaluation of the safety basis for the facility. The INEEL has developed a computer program to estimate the hydrogen gas generation as a function of time and diffusion through a series of layers (volumes), with a maximum five layers plus a sink/environment. The program solves the first-order diffusion equations as a function of time. The current version of the code is more flexible in terms of user input. The program allows the user to estimate hydrogen concentrations in the different layers of a configuration and then change the configuration after a given time; e.g.; installation of a filter on an unvented drum or placed in a vault or in a shipping cask. The code has been used to predict vault concentrations and to identify potential problems during retrieval and aboveground storage. The code has generally predicted higher hydrogen concentrations than the measured values, particularly for the drums older than 20 year, which could be due to uncertainty and conservative assumptions in drum age, heat generation rate, hydrogen generation rate, Geff, and diffusion rates through the layers.

  12. Large area atmospheric-pressure plasma jet

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM); Henins, Ivars (Los Alamos, NM); Babayan, Steve E. (Huntington Beach, CA); Hicks, Robert F. (Los Angeles, CA)

    2001-01-01

    Large area atmospheric-pressure plasma jet. A plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two planar, parallel electrodes are employed to generate a plasma in the volume therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly spacing the rf-powered electrode. Because of the atmospheric pressure operation, there is a negligible density of ions surviving for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike the situation for low-pressure plasma sources and conventional plasma processing methods.

  13. Atmospheric and combustion chemistry of dimethyl ether

    SciTech Connect (OSTI)

    Nielsen, O.J.; Egsgaard, H.; Larsen, E.; Sehested, J.; Wallington, T.J.

    1997-12-31

    It has been demonstrated that dimethyl ether (DME) is an ideal diesel fuel alternative. DME, CH{sub 3}OCH{sub 3}, combines good fuel properties with low exhaust emissions and low combustion noise. Large scale production of this fuel can take place using a single step catalytic process converting CH{sub 4} to DME. The fate of DME in the atmosphere has previously been studied. The atmospheric degradation is initiated by the reaction with hydroxyl radicals, which is also a common feature of combustion processes. Spectrokinetic investigations and product analysis were used to demonstrate that the intermediate oxy radical, CH{sub 3}OCH{sub 2}O, exhibits a novel reaction pathway of hydrogen atom ejection. The application of tandem mass spectrometry to chemi-ions based on supersonic molecular beam sampling has recently been demonstrated. The highly reactive ionic intermediates are sampled directly from the flame and identified by collision activation mass spectrometry and ion-molecule reactions. The mass spectrum reflects the distribution of the intermediates in the flame. The atmospheric degradation of DME as well as the unique fuel properties of a oxygen containing compound will be discussed.

  14. Atmospheric Radiation Measurement Program Science Plan

    SciTech Connect (OSTI)

    Ackerman, T

    2004-10-31

    The Atmospheric Radiation Measurement (ARM) Program has matured into one of the key programs in the U.S. Climate Change Science Program. The ARM Program has achieved considerable scientific success in a broad range of activities, including site and instrument development, atmospheric radiative transfer, aerosol science, determination of cloud properties, cloud modeling, and cloud parameterization testing and development. The focus of ARM science has naturally shifted during the last few years to an increasing emphasis on modeling and parameterization studies to take advantage of the long time series of data now available. During the next 5 years, the principal focus of the ARM science program will be to: Maintain the data record at the fixed ARM sites for at least the next five years. Improve significantly our understanding of and ability to parameterize the 3-D cloud-radiation problem at scales from the local atmospheric column to the global climate model (GCM) grid square. Continue developing techniques to retrieve the properties of all clouds, with a special focus on ice clouds and mixed-phase clouds. Develop a focused research effort on the indirect aerosol problem that spans observations, physical models, and climate model parameterizations. Implement and evaluate an operational methodology to calculate broad-band heating rates in the atmospheric columns at the ARM sites. Develop and implement methodologies to use ARM data more effectively to test atmospheric models, both at the cloud-resolving model scale and the GCM scale. Use these methodologies to diagnose cloud parameterization performance and then refine these parameterizations to improve the accuracy of climate model simulations. In addition, the ARM Program is actively developing a new ARM Mobile Facility (AMF) that will be available for short deployments (several months to a year or more) in climatically important regions. The AMF will have much of the same instrumentation as the remote facilities at ARM's Tropical Western Pacific and the North Slope of Alaska sites. Over time, this new facility will extend ARM science to a much broader range of conditions for model testing.

  15. Atmosphere to Electrons: Enabling the Wind Plant of Tomorrow

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Atmosphere to Electrons Enabling the Wind Plant of Tomorrow 2 Atmosphere to Electrons Enabling the Wind Plant of Tomorrow The U.S. Department of Energy's (DOE's) Atmosphere to Electrons (A2e) research initiative is focused on improving the performance and reliability of wind plants by establishing an unprecedented under- standing of how the Earth's atmosphere interacts with the wind plants and developing innovative technologies to maximize energy extraction from the wind. The A2e initiative

  16. DOE - NNSA/NFO -- Photo Library Atmospheric Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric NNSA/NFO Language Options U.S. DOE/NNSA - Nevada Field Office Photo Library - Atmospheric Testing A total of 100 atmospheric tests were conducted at the Nevada Test Site. These tests were conducted to provide information on weapons effects, effects of the height of burst on overpressure, and information on nuclear phenomena to improve the design of nuclear weapons. Atmospheric testing ceased for good in 1963, after which nuclear testing moved underground. Instructions: Click the

  17. Atmosphere to Electrons: Enabling the Wind Plant of Tomorrow | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Atmosphere to Electrons: Enabling the Wind Plant of Tomorrow Atmosphere to Electrons: Enabling the Wind Plant of Tomorrow a2e-fact-sheet-cover-thumbnail.jpg The U.S. Department of Energy's (DOE's) Atmosphere to Electrons (A2e) research initiative is focused on improving the performance and reliability of wind plants by establishing an unprecedented understanding of how the Earth's atmosphere interacts with the wind plants and developing innovative technologies to maximize energy

  18. On the connection between continental-scale land surface processes and the tropical climate in a coupled ocean-atmosphere-land system

    SciTech Connect (OSTI)

    Ma, Hsi-Yen; Mechoso, C. R.; Xue, Yongkang; Xiao, Heng; Neelin, David; Ji, Xuan

    2013-11-15

    The impact of global tropical climate to perturbations in land surface processes (LSP) are evaluated using perturbations given by different LSP representations of continental-scale in a global climate model that includes atmosphere-ocean interactions. One representation is a simple land scheme, which specifies climatological albedos and soil moisture availability. The other representation is the more comprehensive Simplified Simple Biosphere Model, which allows for interactive soil moisture and vegetation biophysical processes. The results demonstrate that LSP processes such as interactive soil moisture and vegetation biophysical processes have strong impacts on the seasonal mean states and seasonal cycles of global precipitation, clouds, and surface air temperature. The impact is especially significant over the tropical Pacific. To explore the mechanisms for such impact, different LSP representations are confined to selected continental-scale regions where strong interactions of climate-vegetation biophysical processes are present. We find that the largest impact is mainly from LSP perturbations over the tropical African continent. The impact is through anomalous convective heating in tropical Africa due to changes in the surface heat fluxes, which in turn affect basinwide teleconnections in the Pacific through equatorial wave dynamics. The modifications in the equatorial Pacific climate are further enhanced by strong air-sea coupling between surface wind stress and upwelling, as well as effect of ocean memory. Our results further suggest that correct representations of land surface processes, land use change and the associated changes in the deep convection over tropical Africa are crucial to reducing the uncertainty when performing future climate projections under different climate change scenarios.

  19. Impact of Infiltration and Ventilation on Measured Space Conditioning Energy and Moisture Levels in the Hot-Humid Climate, Cocoa, Florida (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-04-01

    Air infiltration and ventilation in residential buildings is a very large part of the heating loads, but empirical data regarding the impact on space cooling has been lacking. Moreover, there has been little data on how building tightness might relate to building interior moisture levels in homes in a hot and humid climate. To address this need, BA-PIRC has conducted research to assess the moisture and cooling load impacts of airtightness and mechanical ventilation in two identical laboratory homes in the hot-humid climate over the cooling season. ​

  20. Technology Solutions Case Study: Impact of Infiltration and Ventilation on Measured Space Conditioning Energy and Moisture Levels in the Hot-Humid Climate

    SciTech Connect (OSTI)

    2014-04-01

    Air infiltration and ventilation in residential buildings is a very large part of the heating loads, but empirical data regarding the impact on space cooling has been lacking. Moreover, there has been little data on how building tightness might relate to building interior moisture levels in homes in a hot and humid climate. To address this need, BA-PIRC conducted research to assess the moisture and cooling load impacts of airtightness and mechanical ventilation in two identical laboratory homes in the hot-humid climate over the cooling season.

  1. Nonlinear symmetric stability of planetary atmospheres

    SciTech Connect (OSTI)

    Bowman, J.C.; Shepherd, T.G.

    1994-11-01

    The energy-Casimir method is applied to the problem of symmetric stability in the context of a compressible, hydrostatic planetary atmosphere with a general equation of state. Linear stability criteria for symmetric disturbances to a zonally symmetric baroclinic flow are obtained. In the special case of a perfect gas the results of Stevens (1983) are recovered. Nonlinear stability conditions are also obtained that, in addition to implying linear stability, provide an upper bound on a certain positive-definite measure of disturbance amplitude.

  2. Relations between rainfall amount, soil moisture and landslides in Hamilton County, Ohio, measured by strain survey and tensiometers

    SciTech Connect (OSTI)

    Bechtel, B.; Mayer, L. . Dept. of Geology)

    1993-03-01

    The movement of water through fill material and natural colluvium in a cut slope is being monitored at two sites with past landslide activity adjacent to I-275 in Hamilton County, Ohio. Quadrilaterals and an array of wooden stakes were placed immediately adjacent to the slide area to monitor movement of the slope at Site 1. To correlate any movement with soil moisture levels, rain gauges were installed. Changes in line-length measurements over a 3-month period are < 14 mm, and most differences average about 4 mm. Since measurement errors of up to 5--6 mm can be expected using a steel tape, more measurements over time will be needed to determine if significant displacement is occurring. Tensiometers were placed at 12 and 36 inches depth in the soil from mid-September through early November 1992, in order to measure matric suction. The 36 inch tensiometer indicated that the soil remained saturated at that depth. The 12 inch tensiometer measured 8 centibars, which occurred following a week of rain-free weather. Gravimetric measurements of soil samples show that surface soil moisture ranges from 14--39% immediately following a storm to 7--29% following at least 10 days of dry weather. At Site 2, quadrilaterals were set up in mid-August 1992; resurveys of the quadrilaterals shows very little, if any, movement. Movement of 38 mm occurred in one quadrilateral; movement in other quadrilaterals averaged close to 5 mm. The slide is not steadily moving, and may be following a pattern, where slides in Hamilton County were more likely to move in late winter or early spring.

  3. Effect of moisture on leaf litter decomposition and its contribution to soil respiration in a temperate forest

    SciTech Connect (OSTI)

    Cisneros-Dozal, Luz Maria; Trumbore, Susan E.; Hanson, Paul J

    2007-01-01

    The degree to which increased soil respiration rates following wetting is caused by plant (autotrophic) versus microbial (heterotrophic) processes, is still largely uninvestigated. Incubation studies suggest microbial processes play a role but it remains unclear whether there is a stimulation of the microbial population as a whole or an increase in the importance of specific substrates that become available with wetting of the soil. We took advantage of an ongoing manipulation of leaf litter 14C contents at the Oak Ridge Reservation, Oak Ridge, Tennessee, to (1) determine the degree to which an increase in soil respiration rates that accompanied wetting of litter and soil, following a short period of drought, could be explained by heterotrophic contributions; and (2) investigate the potential causes of increased heterotrophic respiration in incubated litter and 0-5 cm mineral soil. The contribution of leaf litter decomposition increased from 6 3 mg C m 2 hr 1 during a transient drought, to 63 18 mg C m 2 hr 1 immediately after water addition, corresponding to an increase in the contribution to soil respiration from 5 2% to 37 8%. The increased relative contribution was sufficient to explain all of the observed increase in soil respiration for this one wetting event in the late growing season. Temperature (13 C versus 25 C) and moisture (dry versus field capacity) conditions did not change the relative contributions of different decomposition substrates in incubations, suggesting that more slowly cycling C has at least the same sensitivity to decomposition as faster cycling organic C at the temperature and moisture conditions studied.

  4. Explosive Release Atmospheric Dispersal 3.2

    Energy Science and Technology Software Center (OSTI)

    2001-06-26

    ERAD (Explosive Release Atmospheric Dispersal) is a 3D numerical transport and diffusion model, used to model the consequences associated with the buoyant (or nonbuoyant) dispersal of radioactive material It incorporates an integral plume rise model to simulate the buoyant rise of heated gases following an explosive detonation. treating buoyancy effects from time zero onward, eliminating the need for the stabilized doud assumption, and enabling the penetration of inversions. Modeling of the atmospheric boundary layer usesmore » contemporary parameterization based on scaling theories derived from observational, laboratory and numerical studies. A Monte Carlo stochastic process simulates particle dispersion. Results were validated for both dose and deposition against measurements taken during Operation Roller Coaster (a joint US-UK test performed at NTS). Meteorology is defined using a single vertical sounding containing wind speed and direction and temperature as a function of height. Post processing applies 50-year CEDE DCFs (either ICRP 26 or 60) to determine the contribution of the relevant dose pathways (inhalation, submersion, and ground shine) as well as the total dose received. Dose and deposition contours are overlaid on a fully integrated worldwide GIS and tabulates hearth effects (fatalities and casualties) to resident population. The software runs on a laptop and takes less than 2 minutes to process. The Municipal version of ERAD does not include the ability to model the mitigation effects of aqueous foam.« less

  5. Cold atmospheric plasma in cancer therapy

    SciTech Connect (OSTI)

    Keidar, Michael; Shashurin, Alex; Volotskova, Olga; Ann Stepp, Mary; Srinivasan, Priya; Sandler, Anthony; Trink, Barry

    2013-05-15

    Recent progress in atmospheric plasmas has led to the creation of cold plasmas with ion temperature close to room temperature. This paper outlines recent progress in understanding of cold plasma physics as well as application of cold atmospheric plasma (CAP) in cancer therapy. Varieties of novel plasma diagnostic techniques were developed recently in a quest to understand physics of CAP. It was established that the streamer head charge is about 10{sup 8} electrons, the electrical field in the head vicinity is about 10{sup 7} V/m, and the electron density of the streamer column is about 10{sup 19} m{sup ?3}. Both in-vitro and in-vivo studies of CAP action on cancer were performed. It was shown that the cold plasma application selectively eradicates cancer cells in-vitro without damaging normal cells and significantly reduces tumor size in-vivo. Studies indicate that the mechanism of action of cold plasma on cancer cells is related to generation of reactive oxygen species with possible induction of the apoptosis pathway. It is also shown that the cancer cells are more susceptible to the effects of CAP because a greater percentage of cells are in the S phase of the cell cycle.

  6. Aeras: A next generation global atmosphere model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Spotz, William F.; Smith, Thomas M.; Demeshko, Irina P.; Fike, Jeffrey A.

    2015-06-01

    Sandia National Laboratories is developing a new global atmosphere model named Aeras that is performance portable and supports the quantification of uncertainties. These next-generation capabilities are enabled by building Aeras on top of Albany, a code base that supports the rapid development of scientific application codes while leveraging Sandia's foundational mathematics and computer science packages in Trilinos and Dakota. Embedded uncertainty quantification (UQ) is an original design capability of Albany, and performance portability is a recent upgrade. Other required features, such as shell-type elements, spectral elements, efficient explicit and semi-implicit time-stepping, transient sensitivity analysis, and concurrent ensembles, were not componentsmore » of Albany as the project began, and have been (or are being) added by the Aeras team. We present early UQ and performance portability results for the shallow water equations.« less

  7. Aeras: A next generation global atmosphere model

    SciTech Connect (OSTI)

    Spotz, William F.; Smith, Thomas M.; Demeshko, Irina P.; Fike, Jeffrey A.

    2015-06-01

    Sandia National Laboratories is developing a new global atmosphere model named Aeras that is performance portable and supports the quantification of uncertainties. These next-generation capabilities are enabled by building Aeras on top of Albany, a code base that supports the rapid development of scientific application codes while leveraging Sandia's foundational mathematics and computer science packages in Trilinos and Dakota. Embedded uncertainty quantification (UQ) is an original design capability of Albany, and performance portability is a recent upgrade. Other required features, such as shell-type elements, spectral elements, efficient explicit and semi-implicit time-stepping, transient sensitivity analysis, and concurrent ensembles, were not components of Albany as the project began, and have been (or are being) added by the Aeras team. We present early UQ and performance portability results for the shallow water equations.

  8. Emulation to simulate low resolution atmospheric data

    SciTech Connect (OSTI)

    Hebbur Venkata Subba Rao, Vishwas [ORNL; Archibald, Richard K [ORNL; Evans, Katherine J [ORNL

    2012-08-01

    Climate simulations require significant compute power, they are complex and therefore it is time consuming to simulate them. We have developed an emulator to simulate unknown climate datasets. The emulator uses stochastic collocation and multi-dimensional in- terpolation to simulate the datasets. We have used the emulator to determine various physical quantities such as temperature, short and long wave cloud forcing, zonal winds etc. The emulation gives results which are very close to those obtained by simulations. The emulator was tested on 2 degree atmospheric datasets. The work evaluates the pros and cons of evaluating the mean first and inter- polating and vice versa. To determine the physical quantities, we have assumed them to be a function of time, longitude, latitude and a random parameter. We have looked at parameters that govern high stable clouds, low stable clouds, timescale for convection etc. The emulator is especially useful as it requires negligible compute times when compared to the simulation itself.

  9. Atmospheric transmittance model for photosynthetically active radiation

    SciTech Connect (OSTI)

    Paulescu, Marius; Stefu, Nicoleta; Gravila, Paul; Paulescu, Eugenia; Boata, Remus; Pacurar, Angel; Mares, Oana; Pop, Nicolina; Calinoiu, Delia

    2013-11-13

    A parametric model of the atmospheric transmittance in the PAR band is presented. The model can be straightforwardly applied for calculating the beam, diffuse and global components of the PAR solar irradiance. The required inputs are: air pressure, ozone, water vapor and nitrogen dioxide column content, ngstrm's turbidity coefficient and single scattering albedo. Comparison with other models and ground measured data shows a reasonable level of accuracy for this model, making it suitable for practical applications. From the computational point of view the calculus is condensed into simple algebra which is a noticeable advantage. For users interested in speed-intensive computation of the effective PAR solar irradiance, a PC program based on the parametric equations along with a user guide are available online at http://solar.physics.uvt.ro/srms.

  10. Atmospheric Dispersion Effects in Weak Lensing Measurements

    SciTech Connect (OSTI)

    Plazas, Andrs Alejandro; Bernstein, Gary

    2012-10-01

    The wavelength dependence of atmospheric refraction causes elongation of finite-bandwidth images along the elevation vector, which produces spurious signals in weak gravitational lensing shear measurements unless this atmospheric dispersion is calibrated and removed to high precision. Because astrometric solutions and PSF characteristics are typically calibrated from stellar images, differences between the reference stars' spectra and the galaxies' spectra will leave residual errors in both the astrometric positions (dr) and in the second moment (width) of the wavelength-averaged PSF (dv) for galaxies.We estimate the level of dv that will induce spurious weak lensing signals in PSF-corrected galaxy shapes that exceed the statistical errors of the DES and the LSST cosmic-shear experiments. We also estimate the dr signals that will produce unacceptable spurious distortions after stacking of exposures taken at different airmasses and hour angles. We also calculate the errors in the griz bands, and find that dispersion systematics, uncorrected, are up to 6 and 2 times larger in g and r bands,respectively, than the requirements for the DES error budget, but can be safely ignored in i and z bands. For the LSST requirements, the factors are about 30, 10, and 3 in g, r, and i bands,respectively. We find that a simple correction linear in galaxy color is accurate enough to reduce dispersion shear systematics to insignificant levels in the r band for DES and i band for LSST,but still as much as 5 times than the requirements for LSST r-band observations. More complex corrections will likely be able to reduce the systematic cosmic-shear errors below statistical errors for LSST r band. But g-band effects remain large enough that it seems likely that induced systematics will dominate the statistical errors of both surveys, and cosmic-shear measurements should rely on the redder bands.

  11. Atmospheric Dispersion Effects in Weak Lensing Measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plazas, Andrés Alejandro; Bernstein, Gary

    2012-10-01

    The wavelength dependence of atmospheric refraction causes elongation of finite-bandwidth images along the elevation vector, which produces spurious signals in weak gravitational lensing shear measurements unless this atmospheric dispersion is calibrated and removed to high precision. Because astrometric solutions and PSF characteristics are typically calibrated from stellar images, differences between the reference stars' spectra and the galaxies' spectra will leave residual errors in both the astrometric positions (dr) and in the second moment (width) of the wavelength-averaged PSF (dv) for galaxies.We estimate the level of dv that will induce spurious weak lensing signals in PSF-corrected galaxy shapes that exceed themore »statistical errors of the DES and the LSST cosmic-shear experiments. We also estimate the dr signals that will produce unacceptable spurious distortions after stacking of exposures taken at different airmasses and hour angles. We also calculate the errors in the griz bands, and find that dispersion systematics, uncorrected, are up to 6 and 2 times larger in g and r bands,respectively, than the requirements for the DES error budget, but can be safely ignored in i and z bands. For the LSST requirements, the factors are about 30, 10, and 3 in g, r, and i bands,respectively. We find that a simple correction linear in galaxy color is accurate enough to reduce dispersion shear systematics to insignificant levels in the r band for DES and i band for LSST,but still as much as 5 times than the requirements for LSST r-band observations. More complex corrections will likely be able to reduce the systematic cosmic-shear errors below statistical errors for LSST r band. But g-band effects remain large enough that it seems likely that induced systematics will dominate the statistical errors of both surveys, and cosmic-shear measurements should rely on the redder bands.« less

  12. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of molecular oxygen ions in the upper-most atmosphere of Dione. March 3, 2012 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics

  13. Clear Skies S. A. Clough Atmospheric and Environmental Research, Inc.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    S. A. Clough Atmospheric and Environmental Research, Inc. Cambridge, MA 02139 The objective of this research effort is to develop radiative transfer models that are consistent with Atmospheric Radiation Measurement (ARM) Program spectral radiance measurements for clear and cloudy atmospheres. Our approach is to develop the model physics and related databases with a line-by-line model in the context of available spectral radiance measurements. The line-by- line mode! then functions as an

  14. ARM - PI Product - Atmospheric State, Cloud Microphysics & Radiative Flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsAtmospheric State, Cloud Microphysics & Radiative Flux ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Atmospheric State, Cloud Microphysics & Radiative Flux [ ARM Principal Investigator (PI) Data Product ] Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the

  15. ARM - Amount of Greenhouse Gases in the Global Atmosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PlansAmount of Greenhouse Gases in the Global Atmosphere Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Amount of Greenhouse Gases in the Global Atmosphere Objective The objective is to feel the changes of the amounts of greenhouse gases in the global atmosphere. Materials Each group of

  16. Magnetic structure of the antiferromagnetic Kondo lattice compounds CeRhAl4Si2 and CeIrAl4Si2

    SciTech Connect (OSTI)

    Ghimire, N. J.; Calder, S.; Janoschek, M.; Bauer, E. D.

    2015-06-01

    In this article, we have investigated the magnetic ground state of the antiferromagnetic Kondo-lattice compounds CeMAl4Si2(M = Rh, Ir) using neutron powder diffraction. Although both of these compounds show two magnetic transitions TN1 and TN2 in the bulk properties measurements, evidence for magnetic long-range order was only found below the lower transition TN2. Analysis of the diffraction profiles reveals a commensurate antiferromagnetic structure with a propagation vector k = (0, 0, 1/2). The magnetic moment in the ordered state of CeRhAl4Si2 and CeIrAl4Si2 were determined to be 1.14(2) and 1.41(3) ?B/Ce, respectively, and are parallel to the crystallographic c-axis in agreement with magnetic susceptibility measurements.

  17. Pyrrole Hydrogenation over Rh(111) and Pt(111) Single-Crystal Surfaces and Hydrogenation Promotion Mediated by 1-Methylpyrrole: A Kinetic and Sum-Frequency Generation Vibrational Spectroscopy Study

    SciTech Connect (OSTI)

    Kliewer, Christopher J.; Bieri, Marco; Somorjai, Gabor A.

    2008-03-04

    Sum-frequency generation (SFG) surface vibrational spectroscopy and kinetic measurements using gas chromatography have been used to study the adsorption and hydrogenation of pyrrole over both Pt(111) and Rh(111) single-crystal surfaces at Torr pressures (3 Torr pyrrole, 30 Torr H{sub 2}) to form pyrrolidine and the minor product butylamine. Over Pt(111) at 298 K it was found that pyrrole adsorbs in an upright geometry cleaving the N-H bond to bind through the nitrogen evidenced by SFG data. Over Rh(111) at 298 K pyrrole adsorbs in a tilted geometry relative to the surface through the p-aromatic system. A pyrroline surface reaction intermediate, which was not detected in the gas phase, was seen by SFG during the hydrogenation over both surfaces. Significant enhancement of the reaction rate was achieved over both metal surfaces by adsorbing 1-methylpyrrole before reaction. SFG vibrational spectroscopic results indicate that reaction promotion is achieved by weakening the bonding between the N-containing products and the metal surface because of lateral interactions on the surface between 1-methylpyrrole and the reaction species, reducing the desorption energy of the products. It was found that the ring-opening product butylamine was a reaction poison over both surfaces, but this effect can be minimized by treating the catalyst surfaces with 1-methylpyrrole before reaction. The reaction rate was not enhanced with elevated temperatures, and SFG suggests desorption of pyrrole at elevated temperatures.

  18. Good Is Not Enough: Improving Measurements of Atmospheric Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scatter sunlight, with other particle properties. These properties include particle size, chemical composition, and ability to soak up atmospheric water. By linking these...

  19. Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tmospheric R R esearch esearch 4STAR: 4STAR: Spectrometer Spectrometer for for Sky Sky - - Scanning Scanning , , Sun Sun - - Tracking Tracking Atmospheric Research...

  20. Simulation of atmospheric temperature effects on cosmic ray muon flux

    SciTech Connect (OSTI)

    Tognini, Stefano Castro; Gomes, Ricardo Avelino

    2015-05-15

    The collision between a cosmic ray and an atmosphere nucleus produces a set of secondary particles, which will decay or interact with other atmosphere elements. This set of events produced a primary particle is known as an extensive air shower (EAS) and is composed by a muonic, a hadronic and an electromagnetic component. The muonic flux, produced mainly by pions and kaons decays, has a dependency with the atmospheres effective temperature: an increase in the effective temperature results in a lower density profile, which decreases the probability of pions and kaons to interact with the atmosphere and, consequently, resulting in a major number of meson decays. Such correlation between the muon flux and the atmospheres effective temperature was measured by a set of experiments, such as AMANDA, Borexino, MACRO and MINOS. This phenomena can be investigated by simulating the final muon flux produced by two different parameterizations of the isothermal atmospheric model in CORSIKA, where each parameterization is described by a depth function which can be related to the muon flux in the same way that the muon flux is related to the temperature. This research checks the agreement among different high energy hadronic interactions models and the physical expected behavior of the atmosphere temperature effect by analyzing a set of variables, such as the height of the primary interaction and the difference in the muon flux.

  1. An ensemble constrained variational analysis of atmospheric forcing...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: An ensemble constrained variational analysis of atmospheric forcing data and its application to evaluate clouds in CAM5: Ensemble 3DCVA and Its Application ...

  2. Posters Scanning Raman Lidar Measurements of Atmospheric Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program (ARM) is to develop a better understanding of the atmospheric radiative balance in order to improve the parameterization of radiative processes in general...

  3. Atmospheric Dispersion Parameter (x/Q) for Calculation of Co...

    Energy Savers [EERE]

    Nuclear facilities that are potentially affected by the situation described above should review their atmospheric dispersion assumptions and NSRD- 2015-TD01. Attachment E of...

  4. Estimating atmospheric parameters and reducing noise for multispectral imaging

    DOE Patents [OSTI]

    Conger, James Lynn

    2014-02-25

    A method and system for estimating atmospheric radiance and transmittance. An atmospheric estimation system is divided into a first phase and a second phase. The first phase inputs an observed multispectral image and an initial estimate of the atmospheric radiance and transmittance for each spectral band and calculates the atmospheric radiance and transmittance for each spectral band, which can be used to generate a "corrected" multispectral image that is an estimate of the surface multispectral image. The second phase inputs the observed multispectral image and the surface multispectral image that was generated by the first phase and removes noise from the surface multispectral image by smoothing out change in average deviations of temperatures.

  5. Atmospheric Correction of Satellite Signal in Solar Domain: ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Correction of Satellite Signal in Solar Domain: Impact of Improved Molecular Spectroscopy A. P. Trishchenko Canada Centre for Remote Sensing Ottawa, Ontario, Canada B....

  6. Technical Sessions M. C. MacCracken Atmospheric amj Geophysical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... system, including treatment of the deep ocean and horizontal transport by ocean currents 4 Separate, uncoupled, and limited treatment of atmospheric composition, chemical ...

  7. NSRD-2015-TD01, Technical Report for Calculations of Atmospheric...

    Broader source: Energy.gov (indexed) [DOE]

    an evaluation of the technical bases for the default value for the atmospheric dispersion parameter Q. This parameter appears in the calculation of radiological dose at...

  8. ARM - Field Campaign - Evaluation of Routine Atmospheric Sounding...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Routine Atmospheric Sounding Measurements using Unmanned Systems (ERASMUS) Campaign Links ERASMUS Backgrounder News & Press Images Comments? We would love to hear from...

  9. A Framework for Integrated Modeling of Perturbations in Atmospheres...

    Office of Scientific and Technical Information (OSTI)

    Conjunction Tracking (IMPACT) Citation Details In-Document Search Title: A Framework for Integrated Modeling of Perturbations in Atmospheres for Conjunction Tracking (IMPACT) ...

  10. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final...

    Office of Scientific and Technical Information (OSTI)

    Publisher: DOE ARM Climate Research Facility, Pacific Northwest National Laboratory; Richland, Washington. Research Org: DOE Office of Science Atmospheric Radiation Measurement ...

  11. Duplex Rules June 2010 Atmospheric Radiation Measurement Climate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Duplex Rules June 2010 Atmospheric Radiation Measurement Climate Research Facility North Slope of AlaskaAdjacent Arctic Ocean (ACRFNSAAAO) Duplex Rules Who can stay in the ...

  12. Changes in Moisture Flux over the Tibetan Plateau during 1979-2011: Insights from a High Resolution Simulation

    SciTech Connect (OSTI)

    Gao, Yanhong; Leung, Lai-Yung R.; Zhang, Yongxin; Cuo, Lan

    2015-05-15

    Net precipitation (precipitation minus evapotranspiration, P-E) changes between 1979 and 2011 from a high resolution regional climate simulation and its reanalysis forcing are analyzed over the Tibet Plateau (TP) and compared to the global land data assimilation system (GLDAS) product. The high resolution simulation better resolves precipitation changes than its coarse resolution forcing, which contributes dominantly to the improved P-E change in the regional simulation compared to the global reanalysis. Hence, the former may provide better insights about the drivers of P-E changes. The mechanism behind the P-E changes is explored by decomposing the column integrated moisture flux convergence into thermodynamic, dynamic, and transient eddy components. High-resolution climate simulation improves the spatial pattern of P-E changes over the best available global reanalysis. High-resolution climate simulation also facilitates new and substantial findings regarding the role of thermodynamics and transient eddies in P-E changes reflected in observed changes in major river basins fed by runoff from the TP. The analysis revealed the contrasting convergence/divergence changes between the northwestern and southeastern TP and feedback through latent heat release as an important mechanism leading to the mean P-E changes in the TP.

  13. Changes in Moisture Flux Over the Tibetan Plateau During 1979-2011: Insights from a High Resolution Simulation

    SciTech Connect (OSTI)

    Gao, Yanhong; Leung, Lai-Yung R.; Zhang, Yongxin; Cuo, Lan

    2015-05-01

    Net precipitation (precipitation minus evapotranspiration, P-E) changes from a high resolution regional climate simulation and its reanalysis forcing are analyzed over the Tibet Plateau (TP) and compared to the global land data assimilation system (GLDAS) product. The mechanism behind the P-E changes is explored by decomposing the column integrated moisture flux convergence into thermodynamic, dynamic, and transient eddy components. High-resolution climate simulation improves the spatial pattern of P-E changes over the best available global reanalysis. Improvement in simulating precipitation changes at high elevations contributes dominantly to the improved P-E changes. High-resolution climate simulation also facilitates new and substantial findings regarding the role of thermodynamics and transient eddies in P-E changes reflected in observed changes in major river basins fed by runoff from the TP. The analysis revealed the contrasting convergence/divergence changes between the northwestern and southeastern TP and feedback through latent heat release as an important mechanism leading to the mean P-E changes in the TP.

  14. A Field Study Comparison of the Energy and Moisture Performance Characteristics of Ventilated Versus Sealed Crawl Spaces in the South

    SciTech Connect (OSTI)

    Bruce Davis; Cyrus Dastur; William E. Warren; Shawn Fitzpatrick; Christine Maurer; Rob Stevens; Terry Brennan; William Rose

    2005-06-22

    This study compared the performance of closed crawl spaces, which had sealed foundation wall vents, a sealed polyethylene film liner and various insulation and drying strategies, to traditional wall-vented crawl spaces with perimeter wall vents and polyethylene film covering 100% of the ground surface. The study was conducted at 12 owner-occupied, all electric, single-family detached houses with the same floor plan located on one cul-de-sac in the southeastern United States. Using the matched pairs approach, the houses were divided into three study groups of four houses each. Comparative data was recorded for each house to evaluate sub-metered heat pump energy consumption, relative humidity, wood moisture content, duct infiltration, house infiltration, temperature, radon, and bioaerosol levels. Findings indicated that in the humid conditions of the southeastern United States, a properly closed crawl space is a robust construction measure that produces a substantially drier crawl space and significantly reduces occupied space conditioning energy use on an annual basis.

  15. Treating of solid earthen material and a method for measuring moisture content and resistivity of solid earthen material

    DOE Patents [OSTI]

    Heath, William (Richland, WA); Richardson, Richard (Richland, WA); Goheen, Steven (Richland, WA)

    1994-01-01

    The present invention includes a method of treating solid earthen material having volatile, semi-volatile and non-volatile contaminants. Six electrodes are inserted into a region of earthen material to be treated in a substantially equilateral hexagonal arrangement. Six phases of voltages are applied to corresponding electrodes. The voltages are adjusted within a first range of voltages to create multiple current paths between pairs of the electrodes. The current paths are evenly distributed throughout the region defined by the electrodes and therefore uniformly heat the region. The region of earthen material is heated to a temperature sufficient to substantially remove volatile and semi-volatile contaminants. This temperature is less than a melting temperature of the earthen material. The voltages are then increased to a second range of voltages effective to create dry regions around the electrodes. The dry regions have a perimeter which define a boundary between the dry regions and the earthen material exterior to the dry regions. Corona discharge occurs at the boundaries of the dry regions. As voltages are increased further, the dry regions move radially outward from the electrodes through the entire region. The corona boundaries decompose the non-volatilized contaminants remaining in the region. The hexagonal arrangement of electrodes is also preferable for measuring resistivity and moisture content of the earthen material. The electric field created between the electrodes is readily discernable and therefore facilitates accurate measurements.

  16. Using electromagnetic sensors (magnetometers and dielectrometers) to detect corrosion beneath and moisture within paint coatings on aircraft

    SciTech Connect (OSTI)

    Goldfine, N.; Greig, N.A.

    1994-12-31

    Current nondestructive inspection (NDI) techniques, such as visual inspection, ultrasonic testing, and eddy current testing, do not adequately detect the early stages of hidden corrosion under paint in critical structures such as airframes. This paper proposes a sensor system that uses meandering winding magnetometers (MWMs) and interdigital electrode dielectrometers (IDEDs) to detect hidden corrosion under paint and to measure the depth of moisture within barrier paint coatings. The MWM uses magnetic fields and inductive coupling to measure profiles of the properties of conducting media (such as the reduced conductivity near a metal surface caused by an oxygen diffusion layer resulting from early-stage corrosion). The IDED uses electric fields and capacitive coupling to measure the properties of multiple-layered insulating media, such as paint or the metal oxides formed during corrosion. MWM and IDED sensor designs permit Cartesian coordinate modal continuum modeling, which takes advantage of sensor geometries to provide more precise response predictions than are generally possible with conventional eddy current probes. Data are presented to describe the limitations of current NDI techniques, address the need for a new type of corrosion-detection system and discuss the underlying theory and potential of using MWMs and IDEDs to detect corrosion.

  17. Photochemistry in terrestrial exoplanet atmospheres. III. Photochemistry and thermochemistry in thick atmospheres on super Earths and mini Neptunes

    SciTech Connect (OSTI)

    Hu, Renyu; Seager, Sara

    2014-03-20

    Some super Earths and mini Neptunes will likely have thick atmospheres that are not H{sub 2}-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H{sub 2}-dominated atmospheres and non-H{sub 2}-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to be in the form of CO{sub 2} rather than CH{sub 4} or CO in a H{sub 2}-depleted water-dominated thick atmosphere and that the preferred loss of light elements from an oxygen-poor carbon-rich atmosphere leads to the formation of unsaturated hydrocarbons (C{sub 2}H{sub 2} and C{sub 2}H{sub 4}). We apply our self-consistent atmosphere models to compute spectra and diagnostic features for known transiting low-mass exoplanets GJ 1214 b, HD 97658 b, and 55 Cnc e. For GJ 1214 b, we find that (1) C{sub 2}H{sub 2} features at 1.0 and 1.5 ?m in transmission and C{sub 2}H{sub 2} and C{sub 2}H{sub 4} features at 9-14 ?m in thermal emission are diagnostic for hydrocarbon-rich atmospheres; (2) a detection of water-vapor features and a confirmation of the nonexistence of methane features would provide sufficient evidence for a water-dominated atmosphere. In general, our simulations show that chemical stability has to be taken into account when interpreting the spectrum of a super Earth/mini Neptune. Water-dominated atmospheres only exist for carbon to oxygen ratios much lower than the solar ratio, suggesting that this kind of atmospheres could be rare.

  18. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Doyle, Edward F. (Dedham, MA); DiBella, Francis A. (Roslindale, MA)

    1994-01-01

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculated through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried The dryer comprises a vessel which enables the feedstock and steam to enter recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard.

  19. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, F.E.; Smolensky, L.A.; Doyle, E.F.; DiBella, F.A.

    1994-03-08

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculates through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried. The dryer comprises a vessel which enables the feedstock and steam to enter and recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard. 17 figures.

  20. Antineutrino Oscillations in the Atmospheric Sector

    SciTech Connect (OSTI)

    Himmel, Alexander I.; /Caltech

    2011-05-01

    This thesis presents measurements of the oscillations of muon antineutrinos in the atmospheric sector, where world knowledge of antineutrino oscillations lags well behind the knowledge of neutrinos, as well as a search for {nu}{sub {mu}} {yields} {bar {nu}}{sub {mu}} transitions. Differences between neutrino and antineutrino oscillations could be a sign of physics beyond the Standard Model, including non-standard matter interactions or the violation of CPT symmetry. These measurements leverage the sign-selecting capabilities of the magnetized steel-scintillator MINOS detectors to analyze antineutrinos from the NuMI beam, both when it is in neutrino-mode and when it is in antineutrino-mode. Antineutrino oscillations are observed at |{Delta}{bar m}{sub atm}{sup 2}| = (3.36{sub -0.40}{sup +0.46}(stat) {+-} 0.06(syst)) x 10{sup -3} eV{sup 2} and sin{sup 2}(2{bar {theta}}{sub 23}) = 0.860{sub -0.12}{sup +0.11}(stat) {+-} 0.01(syst). The oscillation parameters measured for antineutrinos and those measured by MINOS for neutrinos differ by a large enough margin that the chance of obtaining two values as discrepant as those observed is only 2%, assuming the two measurements arise from the same underlying mechanism, with the same parameter values. No evidence is seen for neutrino-to-antineutrino transitions.

  1. Development of a Bulk-Format System to Harvest, Handle, Store, and Deliver High-Tonnage Low-Moisture SwitchgrassFeedstock

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Genera Energy Inc. ● 167 Tellico Port Road ● Vonore, TN 37885 Development of a Bulk-Format System to Harvest, Handle, Store, and Deliver High-Tonnage Low-Moisture Switchgrass Feedstock DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review March 25, 2015 Feedstock Supply & Logistics Presenter: Sam Jackson, Genera Energy Inc. Technical Lead: Al Womac, University of Tennessee Lead Organization: TennEra LLC (formerly Genera Energy LLC) Goal Statement  Develop and test

  2. Atmospheric process evaluation of mobile source emissions

    SciTech Connect (OSTI)

    1995-07-01

    During the past two decades there has been a considerable effort in the US to develop and introduce an alternative to the use of gasoline and conventional diesel fuel for transportation. The primary motives for this effort have been twofold: energy security and improvement in air quality, most notably ozone, or smog. The anticipated improvement in air quality is associated with a decrease in the atmospheric reactivity, and sometimes a decrease in the mass emission rate, of the organic gas and NO{sub x} emissions from alternative fuels when compared to conventional transportation fuels. Quantification of these air quality impacts is a prerequisite to decisions on adopting alternative fuels. The purpose of this report is to present a critical review of the procedures and data base used to assess the impact on ambient air quality of mobile source emissions from alternative and conventional transportation fuels and to make recommendations as to how this process can be improved. Alternative transportation fuels are defined as methanol, ethanol, CNG, LPG, and reformulated gasoline. Most of the discussion centers on light-duty AFVs operating on these fuels. Other advanced transportation technologies and fuels such as hydrogen, electric vehicles, and fuel cells, will not be discussed. However, the issues raised herein can also be applied to these technologies and other classes of vehicles, such as heavy-duty diesels (HDDs). An evaluation of the overall impact of AFVs on society requires consideration of a number of complex issues. It involves the development of new vehicle technology associated with engines, fuel systems, and emission control technology; the implementation of the necessary fuel infrastructure; and an appropriate understanding of the economic, health, safety, and environmental impacts associated with the use of these fuels. This report addresses the steps necessary to properly evaluate the impact of AFVs on ozone air quality.

  3. Effects of moisture on the life of power plant cables: Part 1, Medium-voltage cables; Part 2, Low-voltage cables. Final report

    SciTech Connect (OSTI)

    Toman, G.J.; Morris, G.W.; Holzman, P.

    1994-08-01

    Motivated by the concern that in-service moisture may decrease the useful life of medium and low-voltage electrical cables in power plants, EPRI investigators surveyed plant operators, examined cable failure experience, and assessed the need to develop unproved life prediction techniques. The survey revealed that only 34 medium-voltage cable failures have occurred in the more than 1000 plant-years of experience represented. In addition, moisture effects such as voltage-induced water-freeing have not been the primary cause of the failures but are one contributor among several, including manufacturing defects, installation damage, and inadvertent damage to cable by field equipment the study concludes that medium-voltage cables are rehable and there is insufficient interest on the part of surveyed utilities to warrant further R&D on cable condition evaluation techniques at this time. In addition, moisture-related degradation is not a significant concern for low-voltage cables. This two-part report discusses,the limitations of existing cable field testing techniques and highlights measures for maximizing the useful life of medium- and low-voltage power plant cables.

  4. Strategic Environmental Research and Development Program: Atmospheric Remote Sensing and Assessment Program -- Final Report. Part 1: The lower atmosphere

    SciTech Connect (OSTI)

    Tooman, T.P.

    1997-01-01

    This report documents work done between FY91 and FY95 for the lower atmospheric portion of the joint Department of Defense (DoD) and Department of Energy (DOE) Atmospheric Remote Sensing and Assessment Program (ARSAP) within the Strategic Environmental Research and Development Program (SERDP). The work focused on (1) developing new measurement capabilities and (2) measuring atmospheric heating in a well-defined layer and then relating it to cloud properties an water vapor content. Seven new instruments were develop3ed for use with Unmanned Aerospace Vehicles (UAVs) as the host platform for flux, radiance, cloud, and water vapor measurements. Four major field campaigns were undertaken to use these new as well as existing instruments to make critically needed atmospheric measurements. Scientific results include the profiling of clear sky fluxes from near surface to 14 km and the strong indication of cloudy atmosphere absorption of solar radiation considerably greater than predicted by extant models.

  5. Test Plan for Evaluating Hammer and Fixed Cutter Grinders Using Multiple Varieties and Moistures of Biomass Feedstock

    SciTech Connect (OSTI)

    Not listed

    2007-07-01

    Biomass preprocessing is a critical operation in the preparation of feedstock for the front-end of a cellulosic ethanol biorefinery. Its purpose is to chop, grind, or otherwise format the biomass material into a suitable feedstock for optimum conversion to ethanol and other bioproducts. Without this operation, the natural size, bulk density, and flowability characteristics of harvested biomass would decrease the capacities and efficiencies of feedstock assembly unit operations and biorefinery conversion processes to the degree that programmatic cost targets could not be met. The preprocessing unit operation produces a bulk flowable material that 1) improves handling and conveying efficiencies throughout the feedstock assembly system and biorefinery 2) increases biomass surface areas for improved pretreatment efficiencies, 3) reduces particle sizes for improved feedstock uniformity and density, and 4) fractionates structural components for improved compositional quality. The Idaho National Laboratory (INL) is tasked with defining the overall efficiency/effectiveness of current commercial hammer and fixed cutter grinding systems and other connecting systems such as harvest and collection, storage, transportation, and handling for a wide variety of feedstock types used in bioethanol or syngas production. This test plan details tasks and activities for two separate full-scale grinding tests: Material Characterization Test and Machine Characterization Test. For the Material Characterization Test, a small amount (~5-7 tons each) of several feedstock varieties will be ground. This test will define the fractionation characteristics of the grinder that affect the bulk density, particle size distribution, and quality of the size reduced biomass resulting from different separation screen sizes. A specific screen size will be selected based on the characteristics of the ground material. The Machine Characterization Test will then use this selected screen to grind several 30-ton batches of different feedstock varieties and moistures. This test will focus on identifying the performance parameters of the grinding system specific to the feed, fractionation, and screen separation components and their affect on machine capacity and efficiency.

  6. First-principles studies of structural stabilities and enthalpies of formation of refractory intermetallics: TM and TM3 (T = Ti, Zr, Hf; M = Ru, Rh, Pd, Os, Ir, Pt)

    SciTech Connect (OSTI)

    Xing, Weiwei; Chen, X.; Li, Dianzhong; Li, Y. Y.; Fu, Chong Long; Meschel, S.

    2012-01-01

    Using first-principles local density functional approach, we have calculated the ground-state structural phase stabilities and enthalpies of formation of thirty-six binary transition-metal refractory TM and TM3 compounds formed by Group IV elements T (T = Ti, Zr, Hf) and platinum group elements M (M = Ru, Rh, Pd, Os, Ir, Pt) . We compared our results with the available experimental data and found good agreement between theory and experiment in both the trends of structural stabilities and the magnitudes of formation enthalpies. Moreover, based on our calculated results, an empirical relationship between cohesive energies ( E) and melting temperatures (Tm) was derived as Tm = 0.0292 E/kB (where kB is the Boltzmann constant) for both TM and TM3 compounds.

  7. Role of the reaction intermediates in determining PHIP (parahydrogen induced polarization) effect in the hydrogenation of acetylene dicarboxylic acid with the complex [Rh (dppb)]{sup +} (dppb: 1,4-bis(diphenylphosphino)butane)

    SciTech Connect (OSTI)

    Reineri, F.; Aime, S.; Gobetto, R.; Nervi, C.

    2014-03-07

    This study deals with the parahydrogenation of the symmetric substrate acetylene dicarboxylic acid catalyzed by a Rh(I) complex bearing the chelating diphosphine dppb (1,4-bis(diphenylphosphino)butane). The two magnetically equivalent protons of the product yield a hyperpolarized emission signal in the {sup 1}H-NMR spectrum. Their polarization intensity varies upon changing the reaction solvent from methanol to acetone. A detailed analysis of the hydrogenation pathway is carried out by means of density functional theory calculations to assess the structure of hydrogenation intermediates and their stability in the two solvents. The observed polarization effects have been accounted on the basis of the obtained structures. Insights into the lifetime of a short-lived reaction intermediate are also obtained.

  8. ARM - Field Campaign - 2013 Lower Atmospheric Boundary Layer Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaigns2013 Lower Atmospheric Boundary Layer Experiment ARM Data Discovery Browse Data Related Campaigns Lower Atmospheric Boundary Layer Experiment 2012.09.17, Turner, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : 2013 Lower Atmospheric Boundary Layer Experiment 2013.05.28 - 2013.07.01 Lead Scientist : David Turner For data sets, see below. Abstract Instruments were deployed at the SGP Central Facility to investigate how

  9. ARM - Field Campaign - Lower Atmospheric Boundary Layer Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsLower Atmospheric Boundary Layer Experiment Campaign Links LABLE Website Field Campaign Report ARM Data Discovery Browse Data Related Campaigns 2013 Lower Atmospheric Boundary Layer Experiment 2013.05.28, Turner, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Lower Atmospheric Boundary Layer Experiment 2012.09.17 - 2012.11.13 Lead Scientist : David Turner For data sets, see below. Abstract Boundary layer turbulence is

  10. ARM - Field Campaign - Radon Measurements of Atmospheric Mixing (RAMIX

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008) govCampaignsRadon Measurements of Atmospheric Mixing (RAMIX 2008) ARM Data Discovery Browse Data Related Campaigns Radon Measurements of Atmospheric Mixing (RAMIX) 2006.11.01, Fischer, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Radon Measurements of Atmospheric Mixing (RAMIX 2008) 2008.04.01 - 2009.03.31 Lead Scientist : Marc Fischer For data sets, see below. Abstract At present, uncertainty in vertical mixing

  11. JGR-Atmospheres Papers from the RADAGAST Research Team

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    JGR-Atmospheres Papers from the RADAGAST Research Team Bharmal, N.A., A. Slingo, G.J. Robinson, and J.J. Settle, 2009: Simulation of surface and top of atmosphere thermal fluxes and radiances from the RADAGAST experiment. Journal of Geophysical Research-Atmospheres, 114, doi:10.1029/2008JD010504, in press. Kollias, P., M.A. Miller, K.L. Johnson, M.P. Jensen, and D.T. Troyan, 2009: Cloud, thermodynamic, and precipitation observations in West Africa during 2006. Journal of Geophysical Research-

  12. Airborne Instrumentation Needs for Climate and Atmospheric Research

    SciTech Connect (OSTI)

    McFarquhar, Greg; Schmid, Beat; Korolev, Alexei; Ogren, John A.; Russell, P. B.; Tomlinson, Jason M.; Turner, David D.; Wiscombe, Warren J.

    2011-10-06

    Observational data are of fundamental importance for advances in climate and atmospheric research. Advances in atmospheric science are being made not only through the use of ground-based and space-based observations, but also through the use of in-situ and remote sensing observations acquired on instrumented aircraft. In order for us to enhance our knowledge of atmospheric processes, it is imperative that efforts be made to improve our understanding of the operating characteristics of current instrumentation and of the caveats and uncertainties in data acquired by current probes, as well as to develop improved observing methodologies for acquisition of airborne data.

  13. Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951-1963.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battlefield of the Cold War: The Nevada Test Site, Volume I | Department of Energy Atmospheric Nuclear Weapons Testing, 1951-1963. Battlefield of the Cold War: The Nevada Test Site, Volume I Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951-1963. Battlefield of the Cold War: The Nevada Test Site, Volume I Terrence R. Fehner and F.G. Gosling. Atmospheric Nuclear Weapons Testing, 1951-1963. Battlefield of the Cold War: The Nevada Test Site, Volume I (pdf). DOE/MA-0003. Washington,

  14. S-H bond activation in H{sub 2}S and thiols by [RhMn(CO){sub 4}(Ph{sub 2}PCH{sub 2}PPh{sub 2}){sub 2}]. Compounds containing terminal or bridging sulfhydryl and thiolato groups

    SciTech Connect (OSTI)

    Li-Sheng Wang; McDonald, R.; Cowie, M. [Univ. of Alberta, Edmonton (Canada)

    1994-08-17

    A rhodium-magnesium carbonyl-phosphines reacted with thiols to yield the products of S-H addition. Further reactions result in bridging sulfide can be alkylated or protonated at the sulfur. The compound, [RhMn(CO){sub 4}({mu}-S)(dppm){sub 2}], was structurally characterized by X-ray crystallography.

  15. Computer support to run models of the atmosphere. Final report

    SciTech Connect (OSTI)

    Fung, I.

    1996-08-30

    This research is focused on a better quantification of the variations in CO{sub 2} exchanges between the atmosphere and biosphere and the factors responsible for these exchangers. The principal approach is to infer the variations in the exchanges from variations in the atmospheric CO{sub 2} distribution. The principal tool involves using a global three-dimensional tracer transport model to advect and convect CO{sub 2} in the atmosphere. The tracer model the authors used was developed at the Goddard institute for Space Studies (GISS) and is derived from the GISS atmospheric general circulation model. A special run of the GCM is made to save high-frequency winds and mixing statistics for the tracer model.

  16. PNNL: Atmospheric Sciences & Global Change Search for Staff

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Science & Global Change Search for Staff Search for an ASGC staff member (Last, First) Search Search for staff member by Group View Alphabetical List of all ASGC Staff...

  17. Integrated Study of MFRSR-derived Parameters of Atmospheric Aerosols...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program CART site, in Remote Sensing of Clouds and the Atmosphere VI, K. Schafer, O. Lado- Bordowsky, A. Comeron, M. R. Carleer, J. S. Fender, Editors, Proc. SPIE Vol. 4539,...

  18. North America's net terrestrial CO2 exchange with the atmosphere...

    Office of Scientific and Technical Information (OSTI)

    a synthesis of net land-atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990-2009. Only CO2 is considered, not methane or...

  19. ARM - Field Campaign - Cross-Scale Land-Atmosphere Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Cross-Scale Land-Atmosphere Experiment 2016.09.01 - 2019.05.31 Lead Scientist :...

  20. The Atmosphere as a Laboratory: Aerosols, Air Quality, and Climate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to 11:00am Science On Saturday MBG Auditorium The Atmosphere as a Laboratory: Aerosols, Air Quality, and Climate Peter DeCarlo, Assistant Professor of Environmental Engineering...

  1. Free Floating Atmospheric Pressure Ball Plasmas | Princeton Plasma...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7, 2008, 4:15pm to 5:30pm Colloquia MBG Auditorium Free Floating Atmospheric Pressure Ball Plasmas Dr. Glen Wurden Los Alamos National Laboratory Presentation: PDF icon Free...

  2. Atmospheric Pressure Deposition for Electrochromic Windows | Department of

    Office of Environmental Management (EM)

    Energy Atmospheric Pressure Deposition for Electrochromic Windows Atmospheric Pressure Deposition for Electrochromic Windows Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech22_tenent_040413.pdf More Documents & Publications NREL senior scientist, Robert Tenent, Ph.D., with equipment for low cost processing (deposition) of window coatings materials. Dynamic Windows Low-Cost Solutions for Dynamic Window Material CX-003799:

  3. Atmospheric Radiation Measurement Program Facilities Newsletter - September 1999

    SciTech Connect (OSTI)

    Holdridge, D. J., ed

    1999-09-27

    The Atmospheric Radiation Measurement Program September 1999 Facilities Newsletter discusses the several Intensive Observation Periods (IOPs) that the ARM SGP CART site will host in the near future. Two projects of note are the International Pyrgeometer Intercomparison and the Fall Single Column Model (SCM)/Nocturnal Boundary Layer (NBL) IOP. Both projects will bring many US and international scientists to the SGP CART site to participate in atmospheric research.

  4. Technical Sessions B. E. Manner National Oceanic and Atmospheric Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B. E. Manner National Oceanic and Atmospheric Administration Wave Propagation Laboratory 130ulder, CO 80303 The Atmospheric Radiation Measurement (ARM) pirog ram goals are ambitious, and its schedule is demanding. Many of the instruments, proposed for operations at the first Cloud and Radiation Testbed (CART) site as early alS 1992 represent emerging technology and exist only as :special research prototypes. Therefore, an important preparatory step for ARM was an intensive field project in

  5. ARM - Field Campaign - ASSIST: Atmospheric Sounder Spectrometer for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Spectral Technology govCampaignsASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : ASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology 2008.07.08 - 2008.07.18 Lead Scientist : Michael Howard For data sets, see below. Abstract Goals of assist were to intercompare radiance spectra and profile retrievals

  6. PRECISION DETERMINATION OF ATMOSPHERIC EXTINCTION AT OPTICAL AND

    Office of Scientific and Technical Information (OSTI)

    NEAR-INFRARED WAVELENGTHS (Journal Article) | SciTech Connect PRECISION DETERMINATION OF ATMOSPHERIC EXTINCTION AT OPTICAL AND NEAR-INFRARED WAVELENGTHS Citation Details In-Document Search Title: PRECISION DETERMINATION OF ATMOSPHERIC EXTINCTION AT OPTICAL AND NEAR-INFRARED WAVELENGTHS The science goals for future ground-based all-sky surveys, such as the Dark Energy Survey, PanSTARRS, and the Large Synoptic Survey Telescope, require calibration of broadband photometry that is stable in time

  7. A Framework for Integrated Modeling of Perturbations in Atmospheres for

    Office of Scientific and Technical Information (OSTI)

    Conjunction Tracking (IMPACT) (Conference) | SciTech Connect Framework for Integrated Modeling of Perturbations in Atmospheres for Conjunction Tracking (IMPACT) Citation Details In-Document Search Title: A Framework for Integrated Modeling of Perturbations in Atmospheres for Conjunction Tracking (IMPACT) Authors: Linares, Richard [1] ; Klimenko, Alexei V. [1] ; Brennan, Sean M. [1] ; Godinez Vazquez, Humberto C. [1] ; Higdon, David M. [1] ; Koller, Josef [1] ; Lawrence, Earl C. [1] ; Palmer,

  8. A comparison between characteristics of atmospheric-pressure plasma jets

    Office of Scientific and Technical Information (OSTI)

    sustained by nanosecond- and microsecond-pulse generators in helium (Journal Article) | SciTech Connect A comparison between characteristics of atmospheric-pressure plasma jets sustained by nanosecond- and microsecond-pulse generators in helium Citation Details In-Document Search Title: A comparison between characteristics of atmospheric-pressure plasma jets sustained by nanosecond- and microsecond-pulse generators in helium Power source is an important parameter that can affect the

  9. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  10. DOE/ER-0441 Atmospheric Radiation Measurement Plan - February 1990

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Atmospheric Radiation Measurement Program Plan ARM Program Plan Forward In 1978 the Department of Energy initiated the Carbon Dioxide Research Program to address climate change from the increasing concentration of carbon dioxide in the atmosphere. Over the years the Program has studied the many facets of the issue, from the carbon cycle, the climate diagnostics, the vegetative effects, to the societal impacts. The Program is presently the Department's principal entry in the U.S. Global Change

  11. Diesel and Gasoline Engine Emissions: Characterization of Atmosphere

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Composition and Health Responses to Inhaled Emissions | Department of Energy and Gasoline Engine Emissions: Characterization of Atmosphere Composition and Health Responses to Inhaled Emissions Diesel and Gasoline Engine Emissions: Characterization of Atmosphere Composition and Health Responses to Inhaled Emissions 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_mcdonald.pdf More Documents & Publications The Effect of Changes in Diesel

  12. INFERENCE OF INHOMOGENEOUS CLOUDS IN AN EXOPLANET ATMOSPHERE

    SciTech Connect (OSTI)

    Demory, Brice-Olivier; De Wit, Julien; Lewis, Nikole; Zsom, Andras; Seager, Sara; Fortney, Jonathan; Knutson, Heather; Desert, Jean-Michel; Heng, Kevin; Madhusudhan, Nikku; Gillon, Michael; Barclay, Thomas; Cowan, Nicolas B.

    2013-10-20

    We present new visible and infrared observations of the hot Jupiter Kepler-7b to determine its atmospheric properties. Our analysis allows us to (1) refine Kepler-7b's relatively large geometric albedo of Ag = 0.35 0.02, (2) place upper limits on Kepler-7b thermal emission that remains undetected in both Spitzer bandpasses and (3) report a westward shift in the Kepler optical phase curve. We argue that Kepler-7b's visible flux cannot be due to thermal emission or Rayleigh scattering from H{sub 2} molecules. We therefore conclude that high altitude, optically reflective clouds located west from the substellar point are present in its atmosphere. We find that a silicate-based cloud composition is a possible candidate. Kepler-7b exhibits several properties that may make it particularly amenable to cloud formation in its upper atmosphere. These include a hot deep atmosphere that avoids a cloud cold trap, very low surface gravity to suppress cloud sedimentation, and a planetary equilibrium temperature in a range that allows for silicate clouds to potentially form in the visible atmosphere probed by Kepler. Our analysis does not only present evidence of optically thick clouds on Kepler-7b but also yields the first map of clouds in an exoplanet atmosphere.

  13. mu-Scale Variations Of Elemental Composition In Individual Atmospheric Particles By Means Of Synchrotron Radiation Based mu-XRF Analysis

    SciTech Connect (OSTI)

    Schleicher, N.; Kramar, U.; Norra, S.; Dietze, V.; Kaminski, U.; Cen, K.; Yu, Y.

    2010-04-06

    Atmospheric pollution poses a huge challenge especially for densely populated urban areas. Although a tremendous knowledge already exists on atmospheric particulate pollution, only very limited knowledge is available on mineral and chemical composition of single atmospheric particles because most studies on air pollution focus on total mass concentrations or bulk elemental analysis. However, it is of particular importance to investigate the properties of single particles since according to their individually composition they differ in their specific impact on climate change, negative environment and health effects, as well as accelerating the weathering of stone buildings in urban areas. Particles with sulfate and nitrate coatings together with sufficient moisture increase metal solubility and possibly catalyze further surface reactions on stone facades of buildings. From the viewpoint of health effects of aerosols it is important to consider agglomerations processes of fine anthropogenic and highly toxic particles with coarse geogenic and less toxic particles. With respect to fundamental research in mineralogy, processes forming composed coarse particles consisting of geogenic and anthropogenic substances are valuable to study since a new type of particle is produced. In this context, the important and still in detail unknown role of geogenic particles as catchers for anthropogenic aerosols can be investigated more closely. Coarse particles can provide a possible sink for fine particles. Moreover, the intermixture of particles from geogenic and anthropogenic sources and the spatial and temporal variations of contributions from different sources, which plays a decisive role in the study area of Beijing, can be clarified with this approach. For this study, particles were collected with the passive sampling device Sigma-2 and analyzed for particles from 3 to 96 {mu}m. The analyzed particles showed a very inhomogeneous distribution in their elemental composition. For this study, synchrotron radiation based mu-X-ray fluorescence analysis (mu-SXRF) proved to be an excellent tool to investigate mu-scalic distributions of main and trace element concentrations within individual airborne particles.

  14. DOE/SC-ARM-13-013 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-13-013 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  15. DOE/SC-ARM-14-025 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-14-025 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  16. DOE/SC-ARM-15-037 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-15-037 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  17. DOE/SC-ARM-12-021 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-12-021 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  18. DOE/SC-ARM-14-007 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-14-007 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  19. DOE/SC-ARM-15-018 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-15-018 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  20. FACT SHEET U.S. Department of Energy Atmospheric Radiation Measurement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Radiation Measurement Climate Research Facility The Atmospheric Radiation Measurement (ARM) Climate Research Facility is a key component of the U.S. Department of ...

  1. DOE/SC-ARM-14-019 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-14-019 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  2. DOE/SC-ARM-15-001 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-15-001 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  3. DOE/SC-ARM-14-001 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-14-001 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  4. DOE/SC-ARM-13-007 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-13-007 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  5. DOE/SC-ARM-12-015 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-12-015 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  6. DOE/SC-ARM-13-001 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-13-001 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  7. DOE/SC-ARM-13-020 Atmospheric Radiation Measurement Climate Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Atmospheric Radiation Measurement Climate Research Facility Operations Quarterly Report ... DOESC-ARM-13-020 Atmospheric Radiation Measurement Climate Research Facility Operations ...

  8. Investigation on coal pyrolysis in CO{sub 2} atmosphere

    SciTech Connect (OSTI)

    Lunbo Duan; Changsui Zhao; Wu Zhou; Chengrui Qu; Xiaoping Chen [Institute for Thermal Power Engineering of Southeast University, Nanjing (China)

    2009-07-15

    Considerable studies have been reported on the coal pyrolysis process and the formation of SO{sub 2} and NOx processors such as H{sub 2}S, COS, SO{sub 2}, HCN, and NH{sub 3} in inert atmospheres. Similar studies in CO{sub 2} atmosphere also need to be accomplished for better understanding of the combustion characteristics and the SO{sub 2}/NOx formation mechanism of oxy-fuel combustion, which is one of the most important technologies for CO{sub 2} capture. In this study, thermogravimetry coupled with Fourier Transform Infrared (TG-FTIR) analysis was employed to measure the volatile yield and gas evolution features during coal pyrolysis process in CO{sub 2} atmosphere. Results show that replacing N{sub 2} with CO{sub 2} does not influence the starting temperature of volatile release but seems to enhance the volatile releasing rate even at 480{sup o}C. At about 760{sup o}C, CO{sub 2} prevents the calcite from decomposing. In CO{sub 2} atmosphere, the volatile yield increases as the temperature increases and decreases as the heating rate increases. COS is monitored during coal pyrolysis in CO{sub 2} atmosphere while there are only H{sub 2}S and SO{sub 2} formed in N{sub 2} atmosphere. The COS is most likely formed by the reaction between CO{sub 2} and H{sub 2}S. No NH{sub 3} was monitored in this study. In CO{sub 2} atmosphere, the gasification of char elevates the conversion of char-N to HCN. The HCN yield increases as the temperature increases and decreases as the heating rate increases. 20 refs., 13 figs., 3 tabs.

  9. Atmospheric sensing for the H.E.S.S. array

    SciTech Connect (OSTI)

    Aye, K.-M.; Brown, A.M.; Chadwick, P.M.; Hadjichristidis, C.; Latham, I.J.; Le Gallou, R.; McComb, T.J.L.; Nolan, S.J.; Noutsos, A.; Orford, K.J.; Osborne, J.L.; Rayner, S.M.

    2005-02-21

    Several atmospheric monitoring instruments have been installed at the H.E.S.S. gamma-ray observatory in Namibia. Firstly, Heitronics KT19 infrared radiometers, aligned paraxially with the H.E.S.S. telescopes, measure the infrared radiation of the water molecules. These allow us to detect clouds crossing the telescopes' field of view and to estimate the humidity present in the atmosphere. For a general estimate of the atmosphere's transmittance, i.e. the detection of any light-attenuating aerosols, a ceilometer, which is a LIDAR with built-in atmospheric data reduction code, is being used. It will be complemented soon by an instrument which will measure the transmissivity of the atmosphere at different wavelengths up to 500m above the ground. The overall status of the weather is monitored by a fully automated weatherstation. This paper describes the setup, the data analysis and how this will be used in order to improve the knowledge of the telescopes' effective collection area.

  10. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Misztal, P. K.; Hewitt, C. N.; Wildt, J.; Blande, J. D.; Eller, A. S.D.; Fares, S.; Gentner, D. R.; Gilman, J. B.; Graus, M.; Greenberg, J.; et al

    2015-07-13

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functionsmore » of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y-1), pointing to the importance of these natural emissions in atmospheric physics and chemistry.« less

  11. Atmospheric dispersion modeling: Challenges of the Fukushima Daiichi response

    SciTech Connect (OSTI)

    Sugiyama, Gayle; Nasstrom, John; Pobanz, Brenda; Foster, Kevin; Simpson, Matthew; Vogt, Phil; Aluzzi, Fernando; Homann, Steve

    2012-05-01

    In this research, the U.S. Department of Energy’s (DOE) National Atmospheric Release Advisory Center (NARAC) provided a wide range of predictions and analyses as part of the response to the Fukushima Daiichi Nuclear Power Plant accident including: daily Japanese weather forecasts and atmospheric transport predictions to inform planning for field monitoring operations and to provide U.S. government agencies with ongoing situational awareness of meteorological conditions; estimates of possible dose in Japan based on hypothetical U.S. Nuclear Regulatory Commission scenarios of potential radionuclide releases to support protective action planning for U.S. citizens; predictions of possible plume arrival times and dose levels at U.S. locations; and source estimation and plume model refinement based on atmospheric dispersion modeling and available monitoring data.

  12. An active atmospheric methane sink in high Arctic mineral cryosols

    SciTech Connect (OSTI)

    Lau, Maggie C.Y.; Stackhouse, B.; Layton, Alice C.; Chauhan, Archana; Vishnivetskaya, T. A.; Chourey, Karuna; Mykytczuk, N. C.S.; Bennett, Phil C.; Lamarche-Gagnon, G.; Burton, N.; Renholm, J.; Hettich, R. L.; Pollard, W. H.; Omelon, C. R.; Medvigy, David M.; Pffifner, Susan M.; Whyte, L. G.; Onstott, T. C.

    2015-04-14

    The transition of Arctic carbon-rich cryosols into methane (CH?)-emitting wetlands due to global warming is a rising concern. However, the spatially predominant mineral cryosols and their CH? emission potential are poorly understood. Fluxes measured in situ and estimated under laboratory conditions coupled with -omics analysis indicate (1) mineral cryosols in the Canadian high Arctic contain atmospheric CH?-oxidizing bacteria; (2) the atmospheric CH? uptake flux increases with ground temperature; and, as a result, (3) the atmospheric CH? sink strength will increase by a factor of 5-30 as the Arctic warms by 5-15 C over a century. We demonstrated that acidic mineral cryosols have previously unrecognized potential of negative CH? feedback.

  13. An active atmospheric methane sink in high Arctic mineral cryosols

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lau, Maggie C.Y.; Stackhouse, B.; Layton, Alice C.; Chauhan, Archana; Vishnivetskaya, T. A.; Chourey, Karuna; Mykytczuk, N. C.S.; Bennett, Phil C.; Lamarche-Gagnon, G.; Burton, N.; et al

    2015-04-14

    The transition of Arctic carbon-rich cryosols into methane (CH₄)-emitting wetlands due to global warming is a rising concern. However, the spatially predominant mineral cryosols and their CH₄ emission potential are poorly understood. Fluxes measured in situ and estimated under laboratory conditions coupled with -omics analysis indicate (1) mineral cryosols in the Canadian high Arctic contain atmospheric CH₄-oxidizing bacteria; (2) the atmospheric CH⁺ uptake flux increases with ground temperature; and, as a result, (3) the atmospheric CH₄ sink strength will increase by a factor of 5-30 as the Arctic warms by 5-15 °C over a century. We demonstrated that acidic mineralmore » cryosols have previously unrecognized potential of negative CH₄ feedback.« less

  14. Atmospheric-pressure guided streamers for liposomal membrane disruption

    SciTech Connect (OSTI)

    Svarnas, P.; Aleiferis, Sp.; Matrali, S. H.; Gazeli, K.; Clement, F.; Antimisiaris, S. G.

    2012-12-24

    The potential to use liposomes (LIPs) as a cellular model in order to study interactions of cold atmospheric-pressure plasma with cells is herein investigated. Cold atmospheric-pressure plasma is formed by a dielectric-barrier discharge reactor. Large multilamellar vesicle liposomes, consisted of phosphatidylcholine and cholesterol, are prepared by the thin film hydration technique, to encapsulate a small hydrophilic dye, i.e., calcein. The plasma-induced release of calcein from liposomes is then used as a measure of liposome membrane integrity and, consequently, interaction between the cold atmospheric plasma and lipid bilayers. Physical mechanisms leading to membrane disruption are suggested, based on the plasma characterization including gas temperature calculation.

  15. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    SciTech Connect (OSTI)

    Misztal, P. K.; Hewitt, C. N.; Wildt, J.; Blande, J. D.; Eller, A. S.D.; Fares, S.; Gentner, D. R.; Gilman, J. B.; Graus, M.; Greenberg, J.; Guenther, A. B.; Hansel, A.; Harley, P.; Huang, M.; Jardine, K.; Karl, T.; Kaser, L.; Keutsch, F. N.; Kiendler-Scharr, A.; Kleist, E.; Lerner, B. M.; Li, T.; Mak, J.; Nlscher, A. C.; Schnitzhofer, R.; Sinha, V.; Thornton, B.; Warneke, C.; Wegener, F.; Werner, C.; Williams, J.; Worton, D. R.; Yassaa, N.; Goldstein, A. H.

    2015-07-13

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functions of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y-1), pointing to the importance of these natural emissions in atmospheric physics and chemistry.

  16. Atmospheric pressure plasma analysis by modulated molecular beam mass spectrometry

    SciTech Connect (OSTI)

    Aranda Gonzalvo, Y.; Whitmore, T.D.; Rees, J.A.; Seymour, D.L.; Stoffels, E.

    2006-05-15

    Fractional number density measurements for a rf plasma 'needle' operating at atmospheric pressure have been obtained using a molecular beam mass spectrometer (MBMS) system designed for diagnostics of atmospheric plasmas. The MBMS system comprises three differentially pumped stages and a mass/energy analyzer and includes an automated beam-to-background measurement facility in the form of a software-controlled chopper mechanism. The automation of the beam modulation allows the neutral components in the plasma to be rapidly and accurately measured using the mass spectrometer by threshold ionization techniques. Data are reported for plasma generated by a needle plasma source operated using a helium/air mixture. In particular, data for the conversion of atmospheric oxygen and nitrogen into nitric oxide are discussed with reference to its significance for medical applications such as disinfecting wounds and dental cavities and for microsurgery.

  17. ChEAS Data: The Chequamegon Ecosystem Atmosphere Study

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Davis, Kenneth J. [Penn State

    The Chequamegon Ecosystem-Atmosphere Study (ChEAS) is a multi-organizational research effort studying biosphere/atmosphere interactions within a northern mixed forest in Northern Wisconsin. A primary goal is to understand the processes controlling forest-atmosphere exchange of carbon dioxide and the response of these processes to climate change. Another primary goal is to bridge the gap between canopy-scale flux measurements and the global CO2 flask sampling network. The ChEAS flux towers participate in AmeriFlux, and the region is an EOS-validation site. The WLEF tower is a NOAA-CMDL CO2 sampling site. ChEAS sites are primarily located within or near the Chequamegon-Nicolet National Forest in northern Wisconsin, with one site in the Ottawa National Forest in the upper peninsula of Michigan. Current studies observe forest/atmosphere exchange of carbon dioxide at canopy and regional scales, forest floor respiration, photosynthesis and transpiration at the leaf level and use models to scale to canopy and regional levels. EOS-validation studies quantitatively assess the land cover of the area using remote sensing and conduct extensive ground truthing of new remote sensing data (i.e. ASTER and MODIS). Atmospheric remote sensing work is aimed at understanding atmospheric boundary layer dynamics, the role of entrainment in regulating the carbon dioxide mixing ratio profiles through the lower troposphere, and feedback between boundary layer dynamics and vegetation (especially via the hydrologic cycle). Airborne studies have included include balloon, kite and aircraft observations of the CO2 profile in the troposphere.

  18. ARESE (ARM Enhanced Shortwave Experiment) Science Plan [Atmospheric Radiation Program

    SciTech Connect (OSTI)

    Valero, F.P.J.; Schwartz, S.E.; Cess, R.D.; Ramanathan, V.; Collins, W.D.; Minnis, P.; Ackerman, T.P.; Vitko, J.; Tooman, T.P.

    1995-09-27

    Several recent studies have indicated that cloudy atmospheres may absorb significantly more solar radiation than currently predicted by models. The magnitude of this excess atmospheric absorption, is about 50% more than currently predicted and would have major impact on our understanding of atmospheric heating. Incorporation of this excess heating into existing general circulation models also appears to ameliorate some significant shortcomings of these models, most notably a tendency to overpredict the amount of radiant energy going into the oceans and to underpredict the tropopause temperature. However, some earlier studies do not show this excess absorption and an underlying physical mechanism that would give rise to such absorption has yet to be defined. Given the importance of this issue, the Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) program is sponsoring the ARM Enhanced Shortwave Experiment (ARESE) to study the absorption of solar radiation by clear and cloudy atmospheres. The experimental results will be compared with model calculations. Measurements will be conducted using three aircraft platforms (ARM-UAV Egrett, NASA ER-2, and an instrumented Twin Otter), as well as satellites and the ARM central and extended facilities in North Central Oklahoma. The project will occur over a four week period beginning in late September, 1995. Spectral broadband, partial bandpass, and narrow bandpass (10nm) solar radiative fluxes will be measured at different altitudes and at the surface with the objective to determine directly the magnitude and spectral characteristics of the absorption of shortwave radiation by the atmosphere (clear and cloudy). Narrow spectral channels selected to coincide with absorption by liquid water and ice will help in identifying the process of absorption of radiation. Additionally, information such as water vapor profiles, aerosol optical depths, cloud structure and ozone profiles, needed to use as input in radiative transfer calculations, will be acquired using the aircraft and surface facilities available to ARESE. This document outlines the scientific approach and measurement requirements of the project.

  19. ATMOSPHERIC CIRCULATION OF BROWN DWARFS: JETS, VORTICES, AND TIME VARIABILITY

    SciTech Connect (OSTI)

    Zhang, Xi; Showman, Adam P.

    2014-06-10

    A variety of observational evidence demonstrates that brown dwarfs exhibit active atmospheric circulations. In this study we use a shallow-water model to investigate the global atmospheric dynamics in the stratified layer overlying the convective zone on these rapidly rotating objects. We show that the existence and properties of the atmospheric circulation crucially depend on key parameters including the energy injection rate and radiative timescale. Under conditions of strong internal heat flux and weak radiative dissipation, a banded flow pattern comprised of east-west jet streams spontaneously emerges from the interaction of atmospheric turbulence with the planetary rotation. In contrast, when the internal heat flux is weak and/or radiative dissipation is strong, turbulence injected into the atmosphere damps before it can self-organize into jets, leading to a flow dominated by transient eddies and isotropic turbulence instead. The simulation results are not very sensitive to the form of the forcing. Based on the location of the transition between jet-dominated and eddy-dominated regimes, we suggest that many brown dwarfs may exhibit atmospheric circulations dominated by eddies and turbulence (rather than jets) due to the strong radiative damping on these worlds, but a jet structure is also possible under some realistic conditions. Our simulated light curves capture important features from observed infrared light curves of brown dwarfs, including amplitude variations of a few percent and shapes that fluctuate between single-peak and multi-peak structures. More broadly, our work shows that the shallow-water system provides a useful tool to illuminate fundamental aspects of the dynamics on these worlds.

  20. Impact of atmospheric refraction: how deeply can we probe exo-earth's atmospheres during primary eclipse observations?

    SciTech Connect (OSTI)

    Btrmieux, Yan; Kaltenegger, Lisa

    2014-08-10

    Most models used to predict or fit exoplanet transmission spectra do not include all the effects of atmospheric refraction. Namely, the angular size of the star with respect to the planet can limit the lowest altitude, or highest density and pressure, probed during primary eclipses as no rays passing below this critical altitude can reach the observer. We discuss this geometrical effect of refraction for all exoplanets and tabulate the critical altitude, density, and pressure for an exoplanet identical to Earth with a 1 bar N{sub 2}/O{sub 2} atmosphere as a function of both the incident stellar flux (Venus, Earth, and Mars-like) at the top of the atmosphere and the spectral type (O5-M9) of the host star. We show that such a habitable exo-Earth can be probed to a surface pressure of 1 bar only around the coolest stars. We present 0.4-5.0 ?m model transmission spectra of Earth's atmosphere viewed as a transiting exoplanet, and show how atmospheric refraction modifies the transmission spectrum depending on the spectral type of the host star. We demonstrate that refraction is another phenomenon that can potentially explain flat transmission spectra over some spectral regions.

  1. 2010 Atmospheric System Research (ASR) Science Team Meeting Summary

    SciTech Connect (OSTI)

    Dupont, DL

    2011-05-04

    This document contains the summaries of papers presented in poster format at the March 2010 Atmospheric System Research Science Team Meeting held in Bethesda, Maryland. More than 260 posters were presented during the Science Team Meeting. Posters were sorted into the following subject areas: aerosol-cloud-radiation interactions, aerosol properties, atmospheric state and surface, cloud properties, field campaigns, infrastructure and outreach, instruments, modeling, and radiation. To put these posters in context, the status of ASR at the time of the meeting is provided here.

  2. ARM - Field Campaign - The MOSAiC Atmosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsThe MOSAiC Atmosphere Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : The MOSAiC Atmosphere 2019.09.01 - 2020.10.31 Lead Scientist : Matthew Shupe Abstract Arctic climate change is amplified relative to global change and is embodied by a dramatic decline in the perennial sea-ice pack. These cryospheric transitions carry significant implications for regional resource development, geopolitics, and global climate patterns.

  3. Lower Atmospheric Boundary Layer Experiment (LABLE) Final Campaign Report

    SciTech Connect (OSTI)

    Klein, P; Bonin, TA; Newman, JF; Turner, DD; Chilson, P; Blumberg, WG; Mishra, S; Wainwright, CE; Carney, M; Jacobsen, EP; Wharton, S

    2015-11-01

    The Lower Atmospheric Boundary Layer Experiment (LABLE) included two measurement campaigns conducted at the Atmospheric Radiation Measurement (ARM) Southern Great Plains site in Oklahoma during 2012 and 2013. LABLE was designed as a multi-phase, low-cost collaboration among the University of Oklahoma, the National Severe Storms Laboratory, Lawrence Livermore National Laboratory, and the ARM program. A unique aspect was the role of graduate students in LABLE. They served as principal investigators and took the lead in designing and conducting experiments using different sampling strategies to best resolve boundary-layer phenomena.

  4. Assignment of the luminescing states of [Au{sup 1}Rh{sup 1}({sup t}BuNC){sub 2}({mu}-dppm){sub 2}][PF{sub 6}]{sub 2}

    SciTech Connect (OSTI)

    Striplin, D.R.; Crosby, G.A.

    1995-07-13

    Fluorescence, phosphorescence, and excitation spectra were measured on the title compound. These results were augmented with polarization ratios obtained at 77 K and detailed studies of the temperature dependence of the phosphorescence in the 77-4 K range. The phosphorescence decay rate at K was also recorded as a function of an applied magnetic field. All the results are consistent with a 4d{sub z}Rh{sup 1} {yields} 6p{sub 2}Au{sup 1} orbital promotion leading to emitting {sup 1}A, {sup 3}A{sub 1} terms in pseudo-C{sub 2v} symmetry. The {sup 3}A{sub 1} term is split by spin-orbit coupling into a forbidden A{sub 2} state lying lowest followed by a quasi-degenerate pair, [B{sub 1}(x), B{sub 2}(y)] lying approximately 16 cm{sup -1} higher that decays >500 times faster than the lowest one. 28 refs., 6 figs.

  5. Dimethyl sulfide substituted mixed-metal clusters: Synthesis, structure, and characterization of HRuCo sub 3 (CO) sub 11 (SMe sub 2 ) and (HRuRh sub 3 (CO) sub 9 ) sub 2 (SMe sub 2 ) sub 3

    SciTech Connect (OSTI)

    Rossi, S.; Pursianinen, J.; Ahlgren, M.; Pakkanen, T.A. (Univ. of Joensuu (Finland))

    1990-02-01

    Ligand substitution reactions of dimethyl sulfide with mixed-metal clusters are described. The clusters HRuCo{sub 3}(CO){sub 11}(SMe{sub 2}) (1) and (HRuRh{sub 3}(CO){sub 9}){sub 2}(SMe{sub 2}){sub 3} (2) have been prepared by reactions of SMe{sub 2} with the neutral parent clusters. Their crystal structures have been established: 1, monoclinic, space group P2{sub 1}/n, a = 11.459 (5) {angstrom}, b = 12.484 (4) {angstrom}, c = 14.384 (4) {angstrom}, {beta} = 96.40 (3){degree}, Z = 4; 2, trigonal, space group R3c, a = 13.181 (7) {angstrom}, {alpha} = 75.54 (5){degree}, Z = 2. Dimethyl sulfide coordinates terminally as a two-electron donor on basal cobalt in 1 and as a bridging four-electron donor causing unusual dimerization of clusters in 2. The carbonyl arrangement of the parent clusters was not changed during the ligand substitution, and hydride ligands bridge the three basal metals in both compounds.

  6. PHOTOCHEMISTRY IN TERRESTRIAL EXOPLANET ATMOSPHERES. II. H{sub 2}S AND SO{sub 2} PHOTOCHEMISTRY IN ANOXIC ATMOSPHERES

    SciTech Connect (OSTI)

    Hu Renyu; Seager, Sara; Bains, William

    2013-05-20

    Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial exoplanets with sulfur compounds (i.e., H{sub 2}S and SO{sub 2}) emitted from their surfaces. We use a comprehensive one-dimensional photochemistry model and radiative transfer model to investigate the sulfur chemistry in atmospheres ranging from reducing to oxidizing. The most important finding is that both H{sub 2}S and SO{sub 2} are chemically short-lived in virtually all types of atmospheres on terrestrial exoplanets, based on models of H{sub 2}, N{sub 2}, and CO{sub 2} atmospheres. This implies that direct detection of surface sulfur emission is unlikely, as their surface emission rates need to be extremely high (>1000 times Earth's volcanic sulfur emission) for these gases to build up to a detectable level. We also find that sulfur compounds emitted from the surface lead to photochemical formation of elemental sulfur and sulfuric acid in the atmosphere, which would condense to form aerosols if saturated. For terrestrial exoplanets in the habitable zone of Sun-like stars or M stars, Earth-like sulfur emission rates result in optically thick haze composed of elemental sulfur in reducing H{sub 2}-dominated atmospheres for a wide range of particle diameters (0.1-1 {mu}m), which is assumed as a free parameter in our simulations. In oxidized atmospheres composed of N{sub 2} and CO{sub 2}, optically thick haze, composed of elemental sulfur aerosols (S{sub 8}) or sulfuric acid aerosols (H{sub 2}SO{sub 4}), will form if the surface sulfur emission is two orders of magnitude more than the volcanic sulfur emission of Earth. Although direct detection of H{sub 2}S and SO{sub 2} by their spectral features is unlikely, their emission might be inferred by observing aerosol-related features in reflected light with future generation space telescopes.

  7. Excitation of electron Langmuir frequency harmonics in the solar atmosphere

    SciTech Connect (OSTI)

    Fomichev, V. V.; Fainshtein, S. M.; Chernov, G. P.

    2013-05-15

    An alternative mechanism for the excitation of electron Langmuir frequency harmonics as a result of the development of explosive instability in a weakly relativistic beam-plasma system in the solar atmosphere is proposed. The efficiency of the new mechanism as compared to the previously discussed ones is analyzed.

  8. Atmospheric pressure helium afterglow discharge detector for gas chromatography

    DOE Patents [OSTI]

    Rice, G.; D'Silva, A.P.; Fassel, V.A.

    1985-04-05

    An apparatus for providing a simple, low-frequency, electrodeless discharge system for atmospheric pressure afterglow generation. A single quartz tube through which a gas mixture is passed is extended beyond a concentric electrode positioned thereabout. A grounding rod is placed directly above the tube outlet to permit optical viewing of the discharge between the electrodes.

  9. Connectivity to National Atmospheric Release Advisory Center (NARAC)

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2003-08-11

    To establish requirements for connectivity with the National Atmospheric Release Advisory Center (NARAC) at Lawrence Livermore National Laboratory for all DOE and NNSA sites and facilities with potential for hazardous materials releases at levels that require emergency response. The requirements of this Notice have been incorporated into DOE O 151.1C, Comprehensive Emergency Management System, dated 11-2-05. No cancellations.

  10. LARGE ABUNDANCES OF POLYCYCLIC AROMATIC HYDROCARBONS IN TITAN'S UPPER ATMOSPHERE

    SciTech Connect (OSTI)

    Lopez-Puertas, M.; Funke, B.; Garcia-Comas, M.; Dinelli, B. M.; Adriani, A.; D'Aversa, E.; Moriconi, M. L.; Boersma, C.; Allamandola, L. J.

    2013-06-20

    In this paper, we analyze the strong unidentified emission near 3.28 {mu}m in Titan's upper daytime atmosphere recently discovered by Dinelli et al. We have studied it by using the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbons (PAHs), after absorbing UV solar radiation, are able to emit strongly near 3.3 {mu}m. By using current models for the redistribution of the absorbed UV energy, we have explained the observed spectral feature and have derived the vertical distribution of PAH abundances in Titan's upper atmosphere. PAHs have been found to be present in large concentrations, about (2-3) Multiplication-Sign 10{sup 4} particles cm{sup -3}. The identified PAHs have 9-96 carbons, with a concentration-weighted average of 34 carbons. The mean mass is {approx}430 u; the mean area is about 0.53 nm{sup 2}; they are formed by 10-11 rings on average, and about one-third of them contain nitrogen atoms. Recently, benzene together with light aromatic species as well as small concentrations of heavy positive and negative ions have been detected in Titan's upper atmosphere. We suggest that the large concentrations of PAHs found here are the neutral counterpart of those positive and negative ions, which hence supports the theory that the origin of Titan main haze layer is located in the upper atmosphere.

  11. Atmospheric Radiation Measurement Climate Research Facility (ACRF) Annual Report 2008

    SciTech Connect (OSTI)

    LR Roeder

    2008-12-01

    The Importance of Clouds and Radiation for Climate Change: The Earths surface temperature is determined by the balance between incoming solar radiation and thermal (or infrared) radiation emitted by the Earth back to space. Changes in atmospheric composition, including greenhouse gases, clouds, and aerosols, can alter this balance and produce significant climate change. Global climate models (GCMs) are the primary tool for quantifying future climate change; however, there remain significant uncertainties in the GCM treatment of clouds, aerosol, and their effects on the Earths energy balance. In 1989, the U.S. Department of Energy (DOE) Office of Science created the Atmospheric Radiation Measurement (ARM) Program to address scientific uncertainties related to global climate change, with a specific focus on the crucial role of clouds and their influence on the transfer of radiation in the atmosphere. To reduce these scientific uncertainties, the ARM Program uses a unique twopronged approach: The ARM Climate Research Facility, a scientific user facility for obtaining long-term measurements of radiative fluxes, cloud and aerosol properties, and related atmospheric characteristics in diverse climate regimes; and The ARM Science Program, focused on the analysis of ACRF and other data to address climate science issues associated with clouds, aerosols, and radiation, and to improve GCMs. This report provides an overview of each of these components and a sample of achievements for each in fiscal year (FY) 2008.

  12. Program Abstracts: Formation and Growth of Atmospheric Aerosols

    SciTech Connect (OSTI)

    Peter H. McMurry; Markku Kulmala

    2006-09-07

    DOE provided $11,000 to sponsor the Workshop on New Particle Formation in the Atmosphere, which was held at The Riverwood Inn and Conference Center near Minneapolis, MN from September 7 to 9, 2006. Recent work has shown that new particle formation is an important atmospheric process that must be better understood due to its impact on cloud cover and the Earth's radiation balance. The conference was an informal gathering of atmospheric and basic scientists with expertise pertinent to this topic. The workshop included discussions of: atmospheric modeling; computational chemistry pertinent to clustering; ions and ion induced nucleation; basic laboratory and theoretical studies of nucleation; studies on neutral molecular clusters; interactions of organic compounds and sulfuric acid; composition of freshly nucleated particles. Fifty six scientists attended the conference. They included 27 senior scientists, 9 younger independent scientists (assistant professor or young associate professor level), 7 postdocs, 13 graduate students, 10 women, 35 North Americans (34 from the U.S.), 1 Asian, and 20 Europeans. This was an excellent informal workshop on an important topic. An effort was made to include individuals from communities that do not regularly interact. A number of participants have provided informal feedback indicating that the workshop led to research ideas and possible future collaborations.

  13. Atmospheric pressure helium afterglow discharge detector for gas chromatography

    DOE Patents [OSTI]

    Rice, Gary (Gloucester, VA); D'Silva, Arthur P. (Ames, IA); Fassel, Velmer A. (Ames, IA)

    1986-05-06

    An apparatus for providing a simple, low-frequency electrodeless discharge system for atmospheric pressure afterglow generation. A single quartz tube through which a gas mixture is passed is extended beyond a concentric electrode positioned thereabout. A grounding rod is placed directly above the tube outlet to permit optical viewing of the discharge between the electrodes.

  14. National Atmospheric Release Advisory Center | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration Atmospheric Release Advisory Center | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply

  15. THE LOS ALAMOS NATIONAL LABORATORY ATMOSPHERIC TRANSPORT AND DIFFUSION MODELS

    SciTech Connect (OSTI)

    M. WILLIAMS

    1999-08-01

    The LANL atmospheric transport and diffusion models are composed of two state-of-the-art computer codes. The first is an atmospheric wind model called HOThlAC, Higher Order Turbulence Model for Atmospheric circulations. HOTMAC generates wind and turbulence fields by solving a set of atmospheric dynamic equations. The second is an atmospheric diffusion model called RAPTAD, Random Particle Transport And Diffusion. RAPTAD uses the wind and turbulence output from HOTMAC to compute particle trajectories and concentration at any location downwind from a source. Both of these models, originally developed as research codes on supercomputers, have been modified to run on microcomputers. Because the capability of microcomputers is advancing so rapidly, the expectation is that they will eventually become as good as today's supercomputers. Now both models are run on desktop or deskside computers, such as an IBM PC/AT with an Opus Pm 350-32 bit coprocessor board and a SUN workstation. Codes have also been modified so that high level graphics, NCAR Graphics, of the output from both models are displayed on the desktop computer monitors and plotted on a laser printer. Two programs, HOTPLT and RAPLOT, produce wind vector plots of the output from HOTMAC and particle trajectory plots of the output from RAPTAD, respectively. A third CONPLT provides concentration contour plots. Section II describes step-by-step operational procedures, specifically for a SUN-4 desk side computer, on how to run main programs HOTMAC and RAPTAD, and graphics programs to display the results. Governing equations, boundary conditions and initial values of HOTMAC and RAPTAD are discussed in Section III. Finite-difference representations of the governing equations, numerical solution procedures, and a grid system are given in Section IV.

  16. Development of a Bulk-Format System to Harvest, Handle, Store, and Deliver High-Tonnage Low-Moisture Switchgrass Feedstock

    SciTech Connect (OSTI)

    Womac, Alvin; Groothuis, Mitch; Westover, Tyler; Phanphanich, Manunya; Webb, Erin; Sokhansanj, Shahab; Turhollow, Anthony

    2013-09-24

    This project evaluates and compares comprehensive feedstock logistics systems (FLS), where a FLS is defined to comprehensively span from biomass material standing in a field to conveyance of a uniform, industrial-milled product into the throat of a biomass conversion facility (BCF). Elements of the bulk-format FLS evaluated in this project include: field-standing switchgrass dry chopped into bulk format on the farm, hauled (either loose or bulk compacted) to storage, stored with confining overburden in a protective facility, reclaimed and conveyed to bulk-format discharge, bulk compacted into an ejector trailer, and conveyed as bulk flow into the BCF. In this FLS evaluation, bulk storage bins served as a controlled and sensored proxy for large commercial stacks protected from moisture with a membrane cover.

  17. Atmospheric Radiation Measurement Program facilities newsletter, April 2000

    SciTech Connect (OSTI)

    Sisterson, D. L.

    2000-05-05

    This issue of the Atmospheric Radiation Measurement Program (ARM Program) monthly newsletter is about the ARM Program goal to improve scientific understanding of the interactions of sunlight (solar radiation) with the atmosphere, then incorporate this understanding into computer models of climate change. To model climate accurately all around the globe, a variety of data must be collected from many locations on Earth. For its Cloud and Radiation Testbed (CART) sites, ARM chose locations in the US Southern Great Plains, the North Slope of Alaska, and the Tropical Western Pacific Ocean to represent different climate types around the world. In this newsletter they consider the North Slope of Alaska site, with locations at Barrow and Atqasuk, Alaska.

  18. The Atmospheric Muon Charge Ratio at the MINOS Near Detector

    SciTech Connect (OSTI)

    de Jong, J.K.; /IIT, Chicago /Oxford U.

    2011-11-01

    The magnetized MINOS near detector can accurately determine the charge sign of atmospheric muons, this facilitates a measurement of the atmospheric muon charge ratio. To reduce the systematic error associated with geometric bias and acceptance we have combined equal periods of data obtained with opposite magnetic field polarities. We report a charge ratio of 1.2666 {+-} 0.0015(stat.){sub -0.0088}{sup +0.0096}(syst.) at a mean E{sub {mu},0{sup cos}}({theta}) = 63 GeV. This measurement is consistent with the world average but significantly lower than the earlier observation at the MINOS far detector. This increase is shown to be consistent with the hypothesis that a greater fraction of the observed muons arise from kaon decay within the cosmic ray shower.

  19. Dynamic characteristic of intense short microwave propagation in an atmosphere

    SciTech Connect (OSTI)

    Yee, J.H.; Alvarez, R.A.; Mayhall, D.J.; Madsen, N.K.; Cabayan, H.S.

    1983-07-01

    The dynamic behavior of an intense microwave pulse which propagates through the atmosphere will be presented. Our theoretical results are obtained by solving Maxwell's equations, together with the electron fluid equations. Our calculations show that although large portions of the initial energy are absorbed by the electrons that are created through the avalanche process, a significant amount of energy is still able to reach the earth's surface. The amount of energy that reaches the earth's surface as a function of initial energy and wave shape after having propagated through 100 km in the atmosphere are investigated. Results for the air breakdown threshold intensity as a function of the pressure for different pulse widths and different frequencies will also be presented. In addition, we will present a comparison between the theoretical and the experimental results for the pulse shape of a short microwave pulse after it has traveled through a rectangular wave guide which contains a section of air. 23 references, 9 figures.

  20. National Atmospheric Release Advisory Center (NARAC) Capabilities for Homeland Security

    SciTech Connect (OSTI)

    Sugiyama, G; Nasstrom, J; Baskett, R; Simpson, M

    2010-03-08

    The Department of Energy's National Atmospheric Release Advisory Center (NARAC) provides critical information during hazardous airborne releases as part of an integrated national preparedness and response strategy. Located at Lawrence Livermore National Laboratory, NARAC provides 24/7 tools and expert services to map the spread of hazardous material accidentally or intentionally released into the atmosphere. NARAC graphical products show affected areas and populations, potential casualties, and health effect or protective action guideline levels. LLNL experts produce quality-assured analyses based on field data to assist decision makers and responders. NARAC staff and collaborators conduct research and development into new science, tools, capabilities, and technologies in strategically important areas related to airborne transport and fate modeling and emergency response. This paper provides a brief overview of some of NARAC's activities, capabilities, and research and development.

  1. Cellular membrane collapse by atmospheric-pressure plasma jet

    SciTech Connect (OSTI)

    Kim, Kangil; Sik Yang, Sang E-mail: ssyang@ajou.ac.kr; Jun Ahn, Hak; Lee, Jong-Soo E-mail: ssyang@ajou.ac.kr; Lee, Jae-Hyeok; Kim, Jae-Ho

    2014-01-06

    Cellular membrane dysfunction caused by air plasma in cancer cells has been studied to exploit atmospheric-pressure plasma jets for cancer therapy. Here, we report that plasma jet treatment of cervical cancer HeLa cells increased electrical conductivity across the cellular lipid membrane and caused simultaneous lipid oxidation and cellular membrane collapse. We made this finding by employing a self-manufactured microelectrode chip. Furthermore, increased roughness of the cellular lipid membrane and sequential collapse of the membrane were observed by atomic force microscopy following plasma jet treatment. These results suggest that the cellular membrane catastrophe occurs via coincident altered electrical conductivity, lipid oxidation, and membrane roughening caused by an atmospheric-pressure plasma jet, possibly resulting in cellular vulnerability to reactive species generated from the plasma as well as cytotoxicity to cancer cells.

  2. Atmospheric Science Program. Summaries of research in FY 1994

    SciTech Connect (OSTI)

    1995-06-01

    This report provides descriptions for all projects funded by ESD under annual contracts in FY 1994. Each description contains the project`s title; three-year funding history (in thousands of dollars); the contract period over which the funding applies; the name(s) of the principal investigator(s); the institution(s) conducting the projects; and the project`s objectives, products, approach, and results to date (for most projects older than one year). Project descriptions are categorized within the report according to program areas: atmospheric chemistry, atmospheric dynamics, and support operations. Within these categories, the descriptions are ordered alphabetically by principal investigator. Each program area is preceded by a brief text that defines the program area, states it goals and objectives, lists principal research questions, and identifies program managers. Appendixes provide the addresses and telephone numbers of the principal investigators and define the acronyms used.

  3. Unintended consequences of atmospheric injection of sulphate aerosols.

    SciTech Connect (OSTI)

    Brady, Patrick Vane; Kobos, Peter Holmes; Goldstein, Barry

    2010-10-01

    Most climate scientists believe that climate geoengineering is best considered as a potential complement to the mitigation of CO{sub 2} emissions, rather than as an alternative to it. Strong mitigation could achieve the equivalent of up to -4Wm{sup -2} radiative forcing on the century timescale, relative to a worst case scenario for rising CO{sub 2}. However, to tackle the remaining 3Wm{sup -2}, which are likely even in a best case scenario of strongly mitigated CO{sub 2} releases, a number of geoengineering options show promise. Injecting stratospheric aerosols is one of the least expensive and, potentially, most effective approaches and for that reason an examination of the possible unintended consequences of the implementation of atmospheric injections of sulphate aerosols was made. Chief among these are: reductions in rainfall, slowing of atmospheric ozone rebound, and differential changes in weather patterns. At the same time, there will be an increase in plant productivity. Lastly, because atmospheric sulphate injection would not mitigate ocean acidification, another side effect of fossil fuel burning, it would provide only a partial solution. Future research should aim at ameliorating the possible negative unintended consequences of atmospheric injections of sulphate injection. This might include modeling the optimum rate and particle type and size of aerosol injection, as well as the latitudinal, longitudinal and altitude of injection sites, to balance radiative forcing to decrease negative regional impacts. Similarly, future research might include modeling the optimum rate of decrease and location of injection sites to be closed to reduce or slow rapid warming upon aerosol injection cessation. A fruitful area for future research might be system modeling to enhance the possible positive increases in agricultural productivity. All such modeling must be supported by data collection and laboratory and field testing to enable iterative modeling to increase the accuracy and precision of the models, while reducing epistemic uncertainties.

  4. T AMS ARAC (Atmospheric Release Advisory Capability) NEST RAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T AMS ARAC (Atmospheric Release Advisory Capability) NEST RAP . . INTRODUCTION ARAC ARAC he Department of Energy's (DOE) National Nuclear Security Administration (NNSA) has the world's leading scientists, engineers and technicians from over 50 years of managing the nation's nuclear weapons program. When the need arises, DOE is prepared to respond immediately to any type of radiological accident or incident anywhere in the world with the following seven radiological emergency response assets.

  5. ARM - Publications: Science Team Meeting Documents: Atmospheric Modes of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Drizzling Stratus at the ARM SGP Site Atmospheric Modes of Drizzling Stratus at the ARM SGP Site Kollias, Pavlos RSMAS/University of Miami Albrecht, Bruce University of Miami The representation of boundary layer clouds in GCMs remains a source of uncertainty in climate simulations. The cloud amount in the boundary layer is sensitive to the boundary layer scheme. Furthermore, little is known on the climatology of drizzling or precipitating boundary layer clouds, their seasonal variability and

  6. Hierardlicsl Diagnosis V. V. Zuev Institute of Atmospheric Optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hierardlicsl Diagnosis V. V. Zuev Institute of Atmospheric Optics Siberian Branch of the Russian Academy of Sciences Tomsk, Russia Systematic observations of the earth's ozone layer over the last ten years indicate a steady decrease of ozone content in the stratospheric maximum and, on the contrary, a increase of ozone concentrations in the troposphere. This trend is illustrated clearly by the results of 20 years' observations of high-altitude ozone concentration distribution in the troposphere

  7. MONTE CARLO SIMULATION OF METASTABLE OXYGEN PHOTOCHEMISTRY IN COMETARY ATMOSPHERES

    SciTech Connect (OSTI)

    Bisikalo, D. V.; Shematovich, V. I. [Institute of Astronomy of the Russian Academy of Sciences, Moscow (Russian Federation); Grard, J.-C.; Hubert, B. [Laboratory for Planetary and Atmospheric Physics (LPAP), University of Lige, Lige (Belgium); Jehin, E.; Decock, A. [Origines Cosmologiques et Astrophysiques (ORCA), University of Lige (Belgium); Hutsemkers, D. [Extragalactic Astrophysics and Space Observations (EASO), University of Lige (Belgium); Manfroid, J., E-mail: B.Hubert@ulg.ac.be [High Energy Astrophysics Group (GAPHE), University of Lige (Belgium)

    2015-01-01

    Cometary atmospheres are produced by the outgassing of material, mainly H{sub 2}O, CO, and CO{sub 2} from the nucleus of the comet under the energy input from the Sun. Subsequent photochemical processes lead to the production of other species generally absent from the nucleus, such as OH. Although all comets are different, they all have a highly rarefied atmosphere, which is an ideal environment for nonthermal photochemical processes to take place and influence the detailed state of the atmosphere. We develop a Monte Carlo model of the coma photochemistry. We compute the energy distribution functions (EDF) of the metastable O({sup 1}D) and O({sup 1}S) species and obtain the red (630nm) and green (557.7nm) spectral line shapes of the full coma, consistent with the computed EDFs and the expansion velocity. We show that both species have a severely non-Maxwellian EDF, that results in broad spectral lines and the suprathermal broadening dominates due to the expansion motion. We apply our model to the atmosphere of comet C/1996 B2 (Hyakutake) and 103P/Hartley 2. The computed width of the green line, expressed in terms of speed, is lower than that of the red line. This result is comparable to previous theoretical analyses, but in disagreement with observations. We explain that the spectral line shape does not only depend on the exothermicity of the photochemical production mechanisms, but also on thermalization, due to elastic collisions, reducing the width of the emission line coming from the O({sup 1}D) level, which has a longer lifetime.

  8. Evaluation of Routine Atmospheric Sounding Measurements Using Unmanned Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Routine Atmospheric Sounding Measurements Using Unmanned Systems but also to understand the different processes involved in a cloud's life cycle by providing measurements complimentary to those concurrently obtained by instruments stationed at the third ARM Mobile Facility (AMF3) at Oliktok Point. ERASMUS will supply data to address the following science questions: * How does temperature and humidity evolve during transitions between clear and cloudy skies? * How do aerosol properties vary with

  9. Interactive Uses of the NSDL: .Atmospheric Visualization Collection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interactive Uses of the NSDL: Atmospheric Visualization Collection C. M. Klaus, E. N. Vernon, T. McCollum, T. R. Gobble, H. M. Anthony, and D. Johnson Argonne National Laboratory Argonne, Illinois K. Andrew Eastern Illinois University Charleston, Illinois G. G. Mace University of Utah Salt Lake City, Utah C. P. Bahrmann University of Oklahoma Norman, Oklahoma User Interfaces The National Science Digital Library (NSDL) has three user interfaces for accessing data images. 1. The Geophysical Focus

  10. Pulsed atmospheric fluidized bed combustor apparatus and process

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1992-01-01

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g. organic and medical waste, drying, calcining and the like.

  11. Atmospheric Sciences Program summaries of research in FY 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    This document describes the activities and products of the Atmospheric Science Program of the Environmental Sciences Division, Office of Health and Environmental Research, Office of Energy Research, in FY 1993. Each description contains the project`s title; three-year funding history; the contract period over which the funding applies; the name(s) of the principal investigator(s); the institution(s) conducting the projects; and the project`s objectives, products, approach, and results to date. Project descriptions are categorized within the report according to program areas: atmospheric chemistry, atmospheric dynamics, and support operations. Within these categories, the descriptions are ordered alphabetically by principal investigator. Each program area is preceded by a brief text that defines the program area, states its goals and objectives, lists principal research questions, and identifies program managers. Appendixes provide the addresses and telephone numbers of the principal investigators and define the acronyms used. This document has been indexed to aid the reader in locating research topics, participants, and research institutions in the text and the project descriptions. Comprehensive subject, principal investigator, and institution indexes are provided at the end of the text for this purpose. The comprehensive subject index includes keywords from the introduction and chapter texts in addition to those from the project descriptions.

  12. Stable microwave coaxial cavity plasma system at atmospheric pressure

    SciTech Connect (OSTI)

    Song, H. [Department of Electrical and Computer Engineering, University of Colorado, Colorado Springs, Colorado 80918 (United States); Hong, J. M.; Lee, K. H. [Plasma Systems and Materials (PSM) Inc., Sungnam-Si, Gyonggi-Do 190-1 (Korea, Republic of); Choi, J. J. [Department of Radio Science and Engineering, Kwangwoon University, Nowon-Gu, Seoul 447-1 (Korea, Republic of)

    2008-05-15

    We present a systematic study of the development of a novel atmospheric microwave plasma system for material processing in the pressure range up to 760 torr and the microwave input power up to 6 kW. Atmospheric microwave plasma was reliably produced and sustained by using a cylindrical resonator with the TM{sub 011} cavity mode. The applicator and the microwave cavity, which is a cylindrical resonator, are carefully designed and optimized with the time dependent finite element Maxwell equation solver. The azimuthal apertures are placed at the maximum magnetic field positions between the cavity and the applicator to maximize the coupling efficiency into the microwave plasma at a resonant frequency of 2.45 GHz. The system consists of a magnetron power supply, a circulator, a directional coupler, a three-stub tuner, a dummy load, a coaxial cavity, and a central cavity. Design and construction of the resonant structures and diagnostics of atmospheric plasma using optical experiments are discussed in various ranges of pressure and microwave input power for different types of gases.

  13. Critical review of studies on atmospheric dispersion in coastal regions

    SciTech Connect (OSTI)

    Shearer, D.L.; Kaleel, R.J.

    1982-09-01

    This study effort was required as a preliminary step prior to initiation of field measurements of atmospheric dispersion in coastal regions. The Nuclear Regulatory Commission (NRC) is in the process of planning an extensive field measurement program to generate data which will serve as improved data bases for licensing decisions, confirmation of regulations, standards, and guides, and for site characterizations. The study being reported here is an effort directed to obtaining as much information as is possible from existing studies that is relevant toward NRC's objectives. For this study, reports covering research and meteorological measurements conducted for industrial purposes, utility needs, military objectives, and academic studies were obtained and critically reviewed in light of NRC's current data needs. This report provides an interpretation of the extent of existing usable information, an indication of the potential for tailoring existing research toward current NRC information needs, and recommendations for several follow-on studies which could provide valuable additional information through reanalysis of the data. Recommendations are also offered regarding new measurement programs. Emphasis is placed on the identification and acquisition of data from atmospheric tracer studies conducted in coastal regions. A total of 225 references were identified which deal with the coastal atmosphere, including meteorological and tracer measurement programs, theoretical descriptions of the relevant processes, and dispersion models.

  14. Retention of elemental mercury in fly ashes in different atmospheres

    SciTech Connect (OSTI)

    M.A. Lopez-Anton; M. Diaz-Somoano; M.R. Martinez-Tarazona

    2007-01-15

    Mercury is an extremely volatile element, which is emitted from coal combustion to the environment mostly in the vapor phase. To avoid the environmental problems that the toxic species of this element may cause, control technologies for the removal of mercury are necessary. Recent research has shown that certain fly ash materials have an affinity for mercury. Moreover, it has been observed that fly ashes may catalyze the oxidation of elemental mercury and facilitate its capture. However, the exact nature of Hg-fly ash interactions is still unknown, and mercury oxidation through fly ash needs to be investigated more thoroughly. In this work, the influence of a gas atmosphere on the retention of elemental mercury on fly ashes of different characteristics was evaluated. The retention capacity was estimated comparatively in inert and two gas atmospheres containing species present in coal gasification and coal combustion. Fly ashes produced in two pulverized coal combustion (PCC) plants, produced from coals of different rank (CTA and CTSR), and a fly ash (CTP) produced in a fluidized bed combustion (FBC) plant were used as raw materials. The mercury retention capacity of these fly ashes was compared to the retention obtained in different activated carbons. Although the capture of mercury is very similar in the gasification atmosphere and N{sub 2}, it is much more efficient in a coal combustion retention, being greater in fly ashes from PCC than those from FBC plants. 22 refs., 6 figs., 3 tabs.

  15. VOCALS: The VAMOS Ocean-Cloud-Atmosphere-Land Study

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wood, Robert [VOCALS-REx PI, University of Washington; Bretherton, Christopher [GEWEX/GCSS Representative, University of Washington; Huebert, Barry [SOLAS Representative, University of Hawaii; Mechoso, Roberto C. [VOCALS Science Working Group Chair, UCLA; Weller, Robert [Woods Hole Oceanographic Institution

    VOCALS (VAMOS* Ocean-Cloud-Atmosphere-Land Study) is an international CLIVAR program the major goal of which is to develop and promote scientific activities leading to improved understanding of the Southeast Pacific (SEP) coupled ocean-atmosphere-land system on diurnal to inter-annual timescales. The principal program objectives are: 1) the improved understanding and regional/global model representation of aerosol indirect effects over the SEP; 2) the elimination of systematic errors in the region of coupled atmospheric-ocean general circulation models, and improved model simulations and predictions of the coupled climate in the SEP and global impacts of the system variability. VOCALS is organized into two tightly coordinated components: 1) a Regional Experiment (VOCALSREx), and 2) a Modeling Program (VOCALS-Mod). Extended observations (e.g. IMET buoy, satellites, EPIC/PACS cruises) will provide important additional contextual datasets that help to link the field and the modeling components. The coordination through VOCALS of observational and modeling efforts (Fig. 3) will accelerate the rate at which field data can be used to improve simulations and predictions of the tropical climate variability [Copied from the Vocals Program Summary of June 2007, available as a link from the VOCALS web at http://www.eol.ucar.edu/projects/vocals/]. The CLIVAR sponsored program to under which VOCALS falls is VAMOS, which stands for Variability of the American Monsoon Systems.

  16. Atmosphere contamination following repainting of a human hyperbaric chamber complex

    SciTech Connect (OSTI)

    Lillo, R.S.; Morris, J.W.; Caldwell, J.M.; Balk, D.M.; Flynn, E.T. )

    1990-09-01

    The Naval Medical Research Institute currently conducts hyperbaric research in a Man-Rated Chamber Complex (MRCC) originally installed in 1977. Significant engineering alterations to the MRCC and rusting of some of its interior sections necessitated repainting, which was completed in 1988. Great care was taken in selecting an appropriate paint (polyamide epoxy) and in ensuring correct application and curing procedures. Only very low levels of hydrocarbons were found in the MRCC atmosphere before initial pressurization after painting and curing. After pressurization, however, significant chemical contamination was found. The primary contaminants were aromatic hydrocarbons: xylenes (which were a major component of both the primer and topcoat paint) and ethyl benzene. The role that pressure played in stimulating off-gassing from the paint is not clear; the off-gassing rate was observed to be similar over a large range in chamber pressures from 1.6 to 31.0 atm abs. Scrubbing the chamber atmosphere with the chemical absorbent Purafil was effective in removing the contaminants. Contamination has been observed to slowly decline with chamber use and is expected to continue to improve with time. However, this contamination experience emphasizes the need for a high precision gas analysis program at any diving facility to ensure the safety of the breathing gas and chamber atmosphere.

  17. Atmospheric Rivers Coming to a Cloud Near You (Other) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Other: Atmospheric Rivers Coming to a Cloud Near You Citation Details In-Document Search Title: Atmospheric Rivers Coming to a Cloud Near You You are accessing a document from...

  18. About EffectiveŽ Height of the Aerosol Atmosphere in Visible and IR Wavelength Range

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Effective" Height of the Aerosol Atmosphere in Visible and IR Wavelength Range V. N. Uzhegov, D. M. Kabanov, M. V. Panchenko, Yu. A. Pkhalagov, and S. M. Sakerin Institute of Atmospheric Optics Tomsk, Russia Introduction Aerosol component of the atmosphere is one of the important factors affecting the radiation budget of the space - atmosphere - underlying surface system in visible and infrared (IR) wavelength ranges. It is extremely important to take into account the contribution of

  19. The mean climate of the Community Atmosphere Model (CAM4) in forced SST and

    Office of Scientific and Technical Information (OSTI)

    fully coupled experiments (Journal Article) | SciTech Connect Journal Article: The mean climate of the Community Atmosphere Model (CAM4) in forced SST and fully coupled experiments Citation Details In-Document Search Title: The mean climate of the Community Atmosphere Model (CAM4) in forced SST and fully coupled experiments The Community Atmosphere Model, version 4 (CAM4) was released as the atmosphere component of the Community Climate System Model, version 4 (CCSM4) and is described. The

  20. Improvement of Moist and Radiative Processes in Highly Parallel Atmospheric General Circulation Models: Validation and Development

    SciTech Connect (OSTI)

    Frank, William M.; Hack, James J.; Kiehl, Jeffrey T.

    1997-02-24

    Research on designing an integrated moist process parameterization package was carried. This work began with a study that coupled an ensemble of cloud models to a boundary layer model to examine the feasibility of such a methodology for linking boundary layer and cumulus parameterization schemes. The approach proved feasible, prompting research to design and evaluate a coupled parameterization package for GCMS. This research contributed to the development of an Integrated Cumulus Ensemble-Turbulence (ICET) parameterization package. This package incorporates a higher-order turbulence boundary layer that feeds information concerning updraft properties and the variances of temperature and water vapor to the cloud parameterizations. The cumulus ensemble model has been developed, and initial sensitivity tests have been performed in the single column model (SCM) version of CCM2. It is currently being coupled to a convective wake/gust front model. The major function of the convective wake/gust front model is to simulate the partitioning of the boundary layer into disturbed and undisturbed regions. A second function of this model is to predict the nonlinear enhancement of surface to air sensible heat and moisture fluxes that occur in convective regimes due to correlations between winds and anomalously cold, dry air from downdrafts in the gust front region. The third function of the convective wake/gust front model is to predict the amount of undisturbed boundary layer air lifted by the leading edge of the wake and the height to which this air is lifted. The development of the wake/gust front model has been completed, and it has done well in initial testing as a stand-alone component. The current task, to be completed by the end of the funding period, is to tie the wake model to a cumulus ensemble model and to install both components into the single column model version of CCM3 for evaluation. Another area of parametrization research has been focused on the representation of cloud radiative properties. An examination of the CCM2 simulation characteristics indicated that many surface temperature and warm land precipitation problems were linked to deficiencies in the specification of cloud optical properties, which allowed too much shortwave radiation to reach the surface. In-cloud liquid water path was statically specified in the CCM2 using a "prescribed, meridionally and height varying, but time independent, cloud liquid water density profile, which was analytically determined from a meridionally specified liquid water scale height. Single-column model integrations were conducted to explore alternative formulations for the cloud liquid water path diagnostic, converging on an approach that employs a similar, but state-dependent technique for determining in-cloud liquid water concentration. The new formulation, results in significant improvements to both the top-of- atmosphere and surface energy budgets. In particular, when this scheme is incorporated in the three-dimensional GCM, simulated July surface temperature biases are substantially reduced, where summer precipitation over the northern hemisphere continents, as well as precipitation rates over most all warm land areas, is more consistent with observations". This improved parameterization has been incorporated in the CCM3.