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Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

800,000-year Ice-Core Records of Atmospheric Methane (CH4)  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane (CH4) » Ice Cores Methane (CH4) » Ice Cores 800,000-year Ice-Core Records of Atmospheric Methane (CH4) This page introduces ice-core records of methane (CH4) extending back 800,000 years at Dome C, Antarctica and over 400,000 years at the Vostok site. Links are also provided to shorter records from other Antarctic locations. The 2000-year record from Law Dome, Antarctica, has been merged with modern records to create a long-term record to the present. These records are maintained by the World Data Center for Paleoclimatology, National Oceanic and Atmospheric Administration (NOAA), and have graciously been made freely available for access and distribution. The original investigators made the effort to obtain the data and assure their quality. To assure proper credit is given, please follow the citation instructions

2

Modern Records of Atmospheric Methane (CH4) and a 2000-year Ice-core Record  

NLE Websites -- All DOE Office Websites (Extended Search)

(CH4) » Ice Cores (CH4) » Ice Cores Modern Records of Atmospheric Methane (CH4) and a 2000-year Ice-core Record from Law Dome, Antarctica Introduction This page provides an introduction and links to records of atmospheric methane (CH4) over the last 2000 years, emphasizing large data bases each representing currently active stations. Records in recent decades (time period depending on location) have been obtained from samples of ambient-air at remote locations, which represent global atmospheric conditions rather than influences of local sources. The longer (2000-year) record is from the Law Dome ice core in Antarctica. The ice-core record has been merged with modern annual data from Cape Grim, Tasmania to provide a 2000-year record ending with the most recent data. A spline function has

3

MODELING THE EMISSIONS OF NITROUS OXIDE (N20) AND METHANE (CH 4) FROM THE  

E-Print Network (OSTI)

MODELING THE EMISSIONS OF NITROUS OXIDE (N20) AND METHANE (CH 4) FROM THE TERRESTRIAL BIOSPHERE;2 #12;MODELING THE EMISSIONS OF NITROUS OXIDE (N 20) AND METHANE (CH 4) FROM THE TERRESTRIAL BIOSPHERE cli- mate has on natural emissions of N2 0 and CH4 from the terrestrial biosphere to the atmosphere

4

Constraints on Asian and European sources of methane from CH4 -C2H6-CO correlations in Asian outflow  

E-Print Network (OSTI)

of emissions from coal mining and landfills. 2 #12;1. Introduction Atmospheric methane (CH4) is an importantConstraints on Asian and European sources of methane from CH4 - C2H6-CO correlations in Asian and European methane sources Submitted to J. Geophys. Res.: 22 December 2003 Revised: 9 April 2004 1 #12

Jacob, Daniel J.

5

Ch4. Atmosphere and Surface Energy Balances  

E-Print Network (OSTI)

than red light. #12;The Electromagnetic Spectrum 8% 47% 45% 100% solar radiation #12;Blue Sky, Red;Energy Pathways #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Atmosphere or performing any work. #12;Solar radiation transfer in the atmosphere Solar radiation Reflection Transmission

Pan, Feifei

6

Kinetics of the Reduction of CuO/Bentonite by Methane (CH4) during Chemical Looping Combustion  

Science Journals Connector (OSTI)

Kinetics of the Reduction of CuO/Bentonite by Methane (CH4) during Chemical Looping Combustion ... The Journal of Physical Chemistry C2014 118 (37), 21532-21540 ...

Esmail R. Monazam; Ranjani Siriwardane; Ronald W. Breault; Hanjing Tian; Lawrence J. Shadle; George Richards; Stephen Carpenter

2012-03-08T23:59:59.000Z

7

Response of global soil consumption of atmospheric methane to changes in atmospheric climate and nitrogen deposition  

E-Print Network (OSTI)

Soil consumption of atmospheric methane plays an important secondary role in regulating the atmospheric CH4 budget, next to the dominant loss mechanism involving reaction with the hydroxyl radical (OH). Here we used a ...

Zhuang, Qianlai

8

Formation and characterization of hydrophobic glass surface treated by atmospheric pressure He/CH4 plasma  

Science Journals Connector (OSTI)

Atmospheric pressure helium plasmas generated in the open air by 13.56?MHz rf power were applied for the glass surface wettability modification. The plasma gas temperature measured by the spectroscopic method was under 400?K which is low enough to treat the samples without thermal damages. The hydrophobicity of the samples determined by the water droplet contact angle method was dependent on the methane gas content and the plasma exposure time. Adding the methane gas by a small amount of 0.25% the contact angle was remarkably increased from 10 to 83 after the 10 s plasma treatment. From the analysis of the treated surface and the plasma it was shown that the deposition of alkane functional groups such as C-H stretch CH2 bend and CH3 bend was one of the contributing factors for the hydrophobicity development. In addition the hydrophobic properties lasted over 2 months even after the single treatment. From the results the atmospheric pressure plasma treatment promises the fast and low-cost method for the thermally-weak surface modification.

2014-01-01T23:59:59.000Z

9

Atmospheric Methane at Cape Meares, Oregon, U.S.A.: A High-Resolution Data  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » Methane » Atmospheric Trace Gases » Methane » Atmospheric Methane, Cape Meares Atmospheric Methane at Cape Meares, Oregon, U.S.A.: A High-Resolution Data Base for the Period 1979-1992 DOI: 10.3334/CDIAC/atg.db1007 data Data (DB1007) Investigators M. A. K. Khalil and R. A. Rasmussen Description This data base presents continuous automated atmospheric methane (CH4) measurements taken at the atmospheric monitoring facility in Cape Meares, Oregon, by the Oregon Graduate Institute of Science and Technology. The Cape Meares data represent some 119,000 individual atmospheric methane measurements carried out during 1979-1992. Analysis of ambient air (collected 12 to 72 times daily) was carried out by means of an automated sampling and measurement system, using the method of gas chromatography and

10

Application of non-thermal atmospheric pressure ac plasmas to the carbon dioxide reforming of methane  

Science Journals Connector (OSTI)

Methane conversions of 11.9%, yields of hydrogen as high as 23.3% and energy yields of 1.0 mol H2/kWh have been achieved from CO2 reforming of CH4 in non-thermal, atmospheric pressure plasma reactors with Pt coat...

Stephanie L. Brock; Tomoko Shimojo; Steven L. Suib

11

Doubling of atmospheric methane supported  

SciTech Connect

Atmospheric methane over the past 27,000 years was measured by analyzing air trapped in glacial ice in Greenland and Antarctica. Atmospheric concentrations were stable over that period until about 200 years b.p. In the last 200 years they have more than doubled. This change in concentration is correlated with the increase in human population; the implications for climate modification are discussed. 1 figure, 3 references.

Kerr, R.A.

1984-11-23T23:59:59.000Z

12

Seasonal variation of CH4 emissions from central California  

NLE Websites -- All DOE Office Websites (Extended Search)

Seasonal variation of CH4 emissions from central California Seasonal variation of CH4 emissions from central California Title Seasonal variation of CH4 emissions from central California Publication Type Journal Article Year of Publication 2012 Authors Jeong, Seongeun, Chuanfeng Zhao, Arlyn E. Andrews, Laura Bianco, James M. Wilczak, and Marc L. Fischer Journal Journal of Geophysical Research - Atmospheres Volume 117 Issue D11 Keywords atmospheric transport, emission inventory, greenhouse gas, inverse model, methane Abstract We estimate seasonal variations in methane (CH4) emissions from central California from December 2007 through November 2008 by comparing CH4 mixing ratios measured at a tall tower with transport model predictions based on a global 1° a priori CH4emissions map (EDGAR32) and a 10 km seasonally varying California-specific map, calibrated to statewide by CH4emission totals. Atmospheric particle trajectories and surface footprints are computed using the Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport models. Uncertainties due to wind velocity and boundary layer mixing depth are evaluated using measurements from radar wind profilers. CH4signals calculated using the EDGAR32 emission model are larger than those based on the California-specific model and in better agreement with measurements. However, Bayesian inverse analyses using the California-specific and EDGAR32 maps yield comparable annually averaged posterior CH4emissions totaling 1.55 ± 0.24 times and 1.84 ± 0.27 times larger than the California-specific prior emissions, respectively, for a region of central California within approximately 150 km of the tower. If these results are applicable across California, state total CH4 emissions would account for approximately 9% of state total greenhouse gas emissions. Spatial resolution of emissions within the region near the tower reveal seasonality expected from several biogenic sources, but correlations in the posterior errors on emissions from both prior models indicate that the tower footprints do not resolve spatial structure of emissions. This suggests that including additional towers in a measurement network will improve the regional specificity of the posterior estimates.

13

Methanation  

Science Journals Connector (OSTI)

Methanation describes the heterogeneous, gas-catalytic or biological synthesis of CH4 from H2 and CO/CO2...or in case of the biological path, alternatively from other carbon sources. It is the second substantial,...

Markus Lehner; Robert Tichler

2014-01-01T23:59:59.000Z

14

Reduced methane emissions from large-scale changes in water management of China's rice paddies during 19802000  

E-Print Network (OSTI)

Reduced methane emissions from large-scale changes in water management of China's rice paddies contributed to the decline in the rate of increase of global atmospheric methane (CH4) concentration over mid-season drainage to generate estimates of total methane flux for 1980­2000. CH4 emissions from

15

A Process-based Analysis of Methane Exchanges Between Alaskan Terrestrial Ecosystems and the Atmosphere  

E-Print Network (OSTI)

We developed and used a new version of the Terrestrial Ecosystem Model (TEM) to study how rates of methane (CH4) emissions and consumption in Alaskan soils have changed over the past century in response to observed changes ...

Zhuang, Qianlai.

16

E-Print Network 3.0 - atmospheric methane extracted Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

search results for: atmospheric methane extracted Page: << < 1 2 3 4 5 > >> 1 Oceanic sediment methane, including methane clathrate hydrates (hydrates), is the Earth's largest...

17

TRENDS: METHANE EMISSIONS - INTRODUCTION  

NLE Websites -- All DOE Office Websites (Extended Search)

Of the total direct radiative forcing of long-lived greenhouse gases (2.45 Of the total direct radiative forcing of long-lived greenhouse gases (2.45 Wm-2), almost 20% is attributable to methane (CH4), according to the 1995 report of the Intergovernmental Panel on Climate Change (IPCC 1995). Since the mid-1700s, the atmospheric concentration of methane has increased by about 145% (IPCC 1995). Thus, an understanding of the various sources of methane is important. Atmospheric methane is produced both from natural sources (e.g., wetlands) and from human activities (see global methane cycle, from Professor W.S. Reeburgh at the University of California Irvine). Total sources of methane to the atmosphere for the period 1980-1990 were about 535 (range of 410-660) Tg (1 Teragram = 1 million metric tons) CH4 per year, of which 160 (110-210) Tg CH4/yr were from natural sources and 375 (300-450) Tg CH4/yr

18

Planetary and Space Science 54 (2006) 11771187 Titan's methane cycle  

E-Print Network (OSTI)

Abstract Methane is key to sustaining Titan's thick nitrogen atmosphere. However, methane is destroyed and the pressure induced opacity in the infrared, particularly by CH4­N2 and H2­N2 collisions in the troposphere), whose reaction with carbon grains or carbon dioxide in the crustal pores produces methane gas

Atreya, Sushil

19

Response of global soil consumption of atmospheric methane to changes in atmospheric climate and nitrogen deposition  

E-Print Network (OSTI)

Response of global soil consumption of atmospheric methane to changes in atmospheric climate June 2013. [1] Soil consumption of atmospheric methane plays an important secondary role in regulating). Here we used a process-based biogeochemistry model to quantify soil consumption during the 20th and 21

20

Biological sources and sinks of methane in tropical habitats and tropical atmospheric chemistry. Doctoral thesis  

SciTech Connect

The contents of this study include: two methods for measuring methane emission from a tropical lake; methane emission by bubbling from Gatun Lake, Panama; methane emission from wetlands in central Panama; consumption of atmospheric methane in soils of central Panama: effects of agricultural development; a seasonal study of soil-atmosphere methane, carbon dioxide, and 222Rn flux in a tropical moist forest; and the effects of tropical deforestation on global and regional atmospheric chemistry.

Keller, M.M.

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Photofragment imaging of methane Albert J. R. Heck  

E-Print Network (OSTI)

on CH4. © 1996 American Institute of Physics. S0021-9606 96 03810-3 INTRODUCTION Knowledge about the photo dissociation pathways of the methane molecule is of fundamental importance as it is of central, the photochemistry of methane in the atmosphere is mostly driven by intense solar atomic emission lines

Zare, Richard N.

22

Global atmospheric methane: budget, changes and dangers  

Science Journals Connector (OSTI)

...contribute emissions to an air...larger. Reducing emissions from many...emissions related to economic...climate|greenhouse gas mitigation...Prospects for reducing emissions Methane is...reductions in greenhouse warming...agriculture, energy sectors...oil and gas) and landfills...

2011-01-01T23:59:59.000Z

23

Remote Sensing and Sea-Truth Measurements of Methane Flux to the Atmosphere (HYFLUX project)  

SciTech Connect

A multi-disciplinary investigation of distribution and magnitude of methane fluxes from seafloor gas hydrate deposits in the Gulf of Mexico was conducted based on results obtained from satellite synthetic aperture radar (SAR) remote sensing and from sampling conducted during a research expedition to three sites where gas hydrate occurs (MC118, GC600, and GC185). Samples of sediments, water, and air were collected from the ship and from an ROV submersible using sediments cores, niskin bottles attached to the ROV and to a rosette, and an automated sea-air interface collector. The SAR images were used to quantify the magnitude and distribution of natural oil and gas seeps that produced perennial oil slicks on the ocean surface. A total of 176 SAR images were processed using a texture classifying neural network algorithm, which segmented the ocean surface into oil-free and oil-covered water. Geostatistical analysis indicates that there are a total of 1081 seep formations distributed over the entire Gulf of Mexico basin. Oil-covered water comprised an average of 780.0 sq. km (sd 86.03) distributed with an area of 147,370 sq. km. Persistent oil and gas seeps were also detected with SAR sampling on other ocean margins located in the Black Sea, western coast of Africa, and offshore Pakistan. Analysis of sediment cores from all three sites show profiles of sulfate, sulfide, calcium and alkalinity that indicated anaerobic oxidation of methane with precipitation of authigenic carbonates. Difference among the three sampling sites may reflect the relative magnitude of methane flux. Methane concentrations in water column samples collected by ROV and rosette deployments from MC118 ranged from {approx}33,000 nM at the seafloor to {approx}12 nM in the mixed layer with isolated peaks up to {approx}13,670 nM coincident with the top of the gas hydrate stability field. Average plume methane, ethane, and propane concentrations in the mixed layer are 7, 630, and 9,540 times saturation, respectively. Based on the contemporaneous wind speeds at this site, contemporary estimates of the diffusive fluxes from the mixed layer to the atmosphere for methane, ethane, and propane are 26.5, 2.10, and 2.78 {micro}mol/m{sup 2}d, respectively. Continuous measurements of air and sea surface concentrations of methane were made to obtain high spatial and temporal resolution of the diffusive net sea-to-air fluxes. The atmospheric methane fluctuated between 1.70 ppm and 2.40 ppm during the entire cruise except for high concentrations (up to 4.01 ppm) sampled during the end of the occupation of GC600 and the transit between GC600 and GC185. Results from interpolations within the survey areas show the daily methane fluxes to the atmosphere at the three sites range from 0.744 to 300 mol d-1. Considering that the majority of seeps in the GOM are deep (>500 m), elevated CH{sub 4} concentrations in near-surface waters resulting from bubble-mediated CH4 transport in the water column are expected to be widespread in the Gulf of Mexico.

Ian MacDonald

2011-05-31T23:59:59.000Z

24

Passive landfill gas emission Influence of atmospheric pressure and implications for the operation of methane-oxidising biofilters  

Science Journals Connector (OSTI)

A passively vented landfill site in Northern Germany was monitored for gas emission dynamics through high resolution measurements of landfill gas pressure, flow rate and composition as well as atmospheric pressure and temperature. Landfill gas emission could be directly related to atmospheric pressure changes on all scales as induced by the autooscillation of air, diurnal variations and the passage of pressure highs and lows. Gas flux reversed every 20h on average, with 50% of emission phases lasting only 10h or less. During gas emission phases, methane loads fed to a connected methane oxidising biofiltration unit varied between near zero and 247g CH4 h?1m?3 filter material. Emission dynamics not only influenced the amount of methane fed to the biofilter but also the establishment of gas composition profiles within the biofilter, thus being of high relevance for biofilter operation. The duration of the gas emission phase emerged as most significant variable for the distribution of landfill gas components within the biofilter.

Julia Gebert; Alexander Groengroeft

2006-01-01T23:59:59.000Z

25

Joint CO2 and CH4 accountability for global warming Kirk R. Smitha,1,2  

E-Print Network (OSTI)

debt index incorporating both methane (CH4) and carbon dioxide (CO2) emissions. We develop national for global perspectives. We include CO2 emissions from fossil sources [CO2(f)], as well as, in a separate by decreasing CH4 emissions by 46% as stopping CO2 emissions entirely, but with substantial differences among

Silver, Whendee

26

Internal tar/CH4 reforming in a biomass dual fluidised bed gasifier  

Science Journals Connector (OSTI)

An internal reformer is developed for in situ catalytic reforming of tar and methane (CH4) in allothermal gasifiers. The study has been performed in the ... 150kW dual fluidised bed (DFB) biomass gasifier at Mid...

Kristina Gransson; Ulf Sderlind; Till Henschel

2014-10-01T23:59:59.000Z

27

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network (OSTI)

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% lower CH4 fluxes compared to those studies. Unlike on the Earth, relatively modest changes in these fluxes can lead to larger changes in the concentrations of biomarker and related species on the M-star world. We calculate a CH4 greenhouse heating effect of up to 4K. O3 photochemistry in terms of the smog mechanism and the catalytic loss cycles on the M-star world differs considerably compared with the Earth.

John Lee Grenfell; Jean-Mathias Griessmeier; Beate Patzer; Heike Rauer; Antigona Segura; Anja Stadelmann; Barbara Stracke; Ruth Titz; Philip von Paris

2007-02-23T23:59:59.000Z

28

Methane Fluxes Between Terrestrial Ecosystems and the Atmosphere at Northern High Latitudes During the Past Century: A retrospective analysis with a process-based biogeochemistry model  

E-Print Network (OSTI)

We develop and use a new version of the Terrestrial Ecosystem Model (TEM) to study how rates of methane (CH4) emissions and consumption in high-latitude soils of the Northern Hemisphere have changed over the past century ...

Zhuang, Qianlai.

29

Der atmosphrische Kreislauf von Methan  

Science Journals Connector (OSTI)

Present methane concentrations in the northern troposphere average 1.65 ppm. Most CH4 is of recent biogenic origin. 14C analyses indicate that no more than 10% is released by fossil sources. The various CH4-produ...

D. H. Ehhalt

1979-06-01T23:59:59.000Z

30

Discovery of New Materials to Capture Methane | U.S. DOE Office...  

Office of Science (SC) Website

Science Computer simulations reveal new zeolites (porous crystalline adsorbents used by oil industries) with sufficient methane (CH4) adsorption capacity and better CH4carbon...

31

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network (OSTI)

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% ...

Grenfell, J L; Patzer, B; Rauer, H; Segura, A; Stadelmann, A; Stracke, B; Titz, R; Von Paris, P; Grenfell, John Lee; Griessmeier, Jean-Mathias; Patzer, Beate; Rauer, Heike; Segura, Antigona; Stadelmann, Anja; Stracke, Barbara; Titz, Ruth; Paris, Philip von

2007-01-01T23:59:59.000Z

32

Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere  

E-Print Network (OSTI)

dioxide Water vapor #12;Atmospheric composition (parts per million by volume) · Nitrogen (N2) 780Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere Bill Satzer 3M Company #12;Outline,840 · Oxygen (O2) 209,460 · Argon (Ar) 9340 · Carbon dioxide (CO2) 394 · Methane (CH4) 1.79 · Ozone (O3) 0

Olver, Peter

33

The Chemistry of Methane Remediation by a Non?thermal Atmospheric Pressure Plasma  

Science Journals Connector (OSTI)

The destruction of methane by a non?thermal plasma in atmospheric pressure gas streams of nitrogen with variable ... determined by on?line FTIR spectroscopy and the plasma chemistry is interpreted using kinetic m...

Kirsty J. Pringle; J. Christopher Whitehead

2004-09-01T23:59:59.000Z

34

Atmospheric Inverse Estimates of Methane Emissions from Central California  

SciTech Connect

Methane mixing ratios measured at a tall-tower are compared to model predictions to estimate surface emissions of CH{sub 4} in Central California for October-December 2007 using an inverse technique. Predicted CH{sub 4} mixing ratios are calculated based on spatially resolved a priori CH{sub 4} emissions and simulated atmospheric trajectories. The atmospheric trajectories, along with surface footprints, are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. An uncertainty analysis is performed to provide quantitative uncertainties in estimated CH{sub 4} emissions. Three inverse model estimates of CH{sub 4} emissions are reported. First, linear regressions of modeled and measured CH{sub 4} mixing ratios obtain slopes of 0.73 {+-} 0.11 and 1.09 {+-} 0.14 using California specific and Edgar 3.2 emission maps respectively, suggesting that actual CH{sub 4} emissions were about 37 {+-} 21% higher than California specific inventory estimates. Second, a Bayesian 'source' analysis suggests that livestock emissions are 63 {+-} 22% higher than the a priori estimates. Third, a Bayesian 'region' analysis is carried out for CH{sub 4} emissions from 13 sub-regions, which shows that inventory CH{sub 4} emissions from the Central Valley are underestimated and uncertainties in CH{sub 4} emissions are reduced for sub-regions near the tower site, yielding best estimates of flux from those regions consistent with 'source' analysis results. The uncertainty reductions for regions near the tower indicate that a regional network of measurements will be necessary to provide accurate estimates of surface CH{sub 4} emissions for multiple regions.

Zhao, Chuanfeng; Andrews, Arlyn E.; Bianco, Laura; Eluszkiewicz, Janusz; Hirsch, Adam; MacDonald, Clinton; Nehrkorn, Thomas; Fischer, Marc L.

2008-11-21T23:59:59.000Z

35

Storms, polar deposits and the methane cycle in Titan's atmosphere  

Science Journals Connector (OSTI)

...2004GL021415 . Lorenz, R.D , 2006The sand seas on Titan: Cassini RADAR...Stevenson1985Thermodynamics of clathrate hydrate at low and high pressures with...constituent, methane, exists as a gas, liquid and solid, and cycles...constituent, methane, exists as a gas, liquid and solid, and cycles...

2009-01-01T23:59:59.000Z

36

Assessment of kinetic modeling for lean H2/CH4/O2/diluent flames at high pressures  

E-Print Network (OSTI)

) and HO2 + H with the main branching reactions. Methane addition is shown to influence the pressure: Hydrogen; Methane; Syngas; Flame speed; Chemical mechanism 1. Introduction The H2/O2 reaction system CO, CO2, H2O, CH4 and other small hydrocarbons (synthetic gas or "syngas") from coal or biomass

Ju, Yiguang

37

Selection of coals of different maturities for CO2 Storage by modelling of CH4 and CO2 adsorption isotherms  

E-Print Network (OSTI)

of this study is to compare and model pure gas sorption isotherms (CO2 and CH4) for well-characterised coals of different maturities to determine the most suitable coal for CO2 storage. Carbon dioxide and methane; Coals; Methane and carbon dioxide adsorption; Modelling isotherms 1. Introduction CO2 is a greenhouse

Paris-Sud XI, Université de

38

Sulfur pollution suppression of the wetland methane source in the 20th and 21st centuries  

E-Print Network (OSTI)

. Emission of this powerful greenhouse gas from wet- lands is known to depend on climate, with increasing are likely due to factors other than the global warming of wetlands. Atmospheric methane (CH4) is a powerful greenhouse gas (GHG) that is responsible for an estimated 22% of the present anthropogenically enhanced

39

COST 526 Project CH4 Final Report  

E-Print Network (OSTI)

1 COST 526 ­ Project CH4 Final Report Modelling, Simulating and Analysing EQ-Casting and Quenching. Remark: Due to the delay of the funding of the proposed investment casting project we change the focus of the project. The development of an Open Source optimization tool (see collaboration) was a relevant

40

Upper bound of polymeric membranes for mixed-gas CO2/CH4 separations  

Science Journals Connector (OSTI)

Abstract Membrane polymers with high permeability and high selectivity are preferred for gas separations. However, there exists a trade-off or upper bound, i.e., polymers with higher permeability often exhibit lower selectivity, and vice versa. The upper bound for separation of various gas pairs has been empirically drawn and theoretically rationalized using pure-gas data. However, for CO2/CH4 separation, the high pressure CO2 and non-methane hydrocarbons can plasticize polymers, increasing mixed-gas CO2 permeability and decreasing mixed-gas CO2/CH4 selectivity. This study aims to apply a modified free volume theory to interpret CO2/CH4 separation performance in polymeric membranes. The model satisfactorily describes the pure-gas upper bounds for various gas pairs including CO2/CH4, the effect of high pressure CO2 on mixed-gas CO2/CH4 separation properties, and the practical mixed-gas upper bound for CO2/CH4 separations. The CO2 is found to have an estimated glass transition temperature of 108K. The assumptions of this model are discussed, and future work to improve this model is proposed.

Haiqing Lin; Milad Yavari

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Large methane emission upon spring thaw from natural wetlands in the northern permafrost region  

SciTech Connect

The permafrost carbon climate feedback is one of the major mechanisms in controlling the climate ecosystem interactions in northern high latitudes. Of this feedback, methane (CH4) emission from natural wetlands is critically important due to its high warming potential. The freeze thaw transition has been confirmed to play an important role in annual CH4 budget, yet the magnitude of this effect is uncertain. An intensive field campaign was carried out in the Sanjiang Plain, Northeast China to estimate the CH4 emission in the spring freeze thaw transition period. The observation concluded that a large CH4 source was caused by spring thaw; the maximum hourly emission rate was 48.6 g C m 2 h 1, more than three orders of the regularly observed CH4 emission rate in the growing season. In some sporadically observed 'hot spots', the spring thawing effect contributed to a large CH4 source of 31.3 10.1 g C m 2, which is approximately 80% of the previously calculated annual CH4 emission in the same study area. If our results are typical for natural wetlands in the Northern Hemisphere permafrost region, we estimate a global CH4 source strength of 0.5 1.0 Tg C (1 Tg =1012 g) caused by spring thaw in the Northern Hemisphere permafrost region in the year 2011. Combining with available satellite and flask data, a regional extrapolation reaches a temporal pattern of CH4 emission during 2003 2009 which is consistent with recently observed changes in atmospheric CH4 concentration in the high latitudes. This suggests that the CH4 emission upon spring thaw in the high latitudes might be enhanced by the projected climate warming. These findings indicate that the spring thawing effect is an important mechanism in the permafrost carbon climate feedback and needs to be incorporated in Earth system models.

Song, Changchun [Chinese Academy of Sciences; Xu, Xiaofeng [ORNL; Sun, Xiaoxin [Chinese Academy of Sciences; Tian, Hanqin [Auburn University, Auburn, Alabama; Sun, Li [Chinese Academy of Sciences; Miao, Yuqing [Chinese Academy of Sciences; Wang, Xianwei [Chinese Academy of Sciences; Guo, Yuedong [Chinese Academy of Sciences

2012-01-01T23:59:59.000Z

42

Atmosphrisches Methan als Treibhausgas  

Science Journals Connector (OSTI)

Methan (CH4) gehrt neben Wasser(dampf), Kohlendioxid (CO2), Distickstoffmonoxid (Lachgas, N2O), Ozon (O3) und den Fluorchlorkohlenwasserstoffen (FCKW) zu den sog.Treibhausgasen, von denen man mit groer Sicherhe...

W. Klpffer

1990-09-01T23:59:59.000Z

43

Fluxes of methane between landfills and the atmosphere: Natural and engineered controls  

SciTech Connect

Field measurement of landfill methane emissions indicates natural variability spanning more than 2 seven orders of magnitude, from approximately 0.0004 to more than 4000 g m{sub -2} day{sup -1}. This wide range reflects net emissions resulting from production (methanogenesis), consumption (methanotrophic oxidation), and gaseous transport processes. The determination of an {open_quotes}average{close_quotes} emission rate for a given field site requires sampling designs and statistical techniques which consider spatial and temporal variability. Moreover, particularly at sites with pumped gas recovery systems, it is possible for methanotrophic microorganisms in aerated cover soils to oxidize all of the methane from landfill sources below and, additionally, to oxidize methane diffusing into cover soils from atmospheric sources above. In such cases, a reversed soil gas concentration gradient is observed in shallow cover soils, indicating bidirectional diffusional transport to the depth of optimum methane oxidation. Rates of landfill methane oxidation from field and laboratory incubation studies range up to 166 g m{sup -2} day{sup -1} among the highest for any natural setting, providing an effective natural control on net emissions. Estimates of worldwide landfill methane emissions to the atmosphere have ranged from 9 to 70 Tg yr{sup -1}, differing mainly in assumed methane yields from estimated quantities of landfilled refuse. At highly controlled landfill sites in developed countries, landfill methane is often collected via vertical wells or horizontal collectors. Recovery of landfill methane through engineered systems can provide both environmental and energy benefits by mitigating subsurface migration, reducing surface emissions, and providing an alternative energy resource for industrial boiler use, on-site electrical generation, or upgrading to a substitute natural gas.

Bogner, J. [Argonne National Lab., IL (United States); Meadows, M. [ETSU, Harwell, Oxfordshire (United Kingdom); Czepiel, P. [Harvard Univ., Cambridge, MA (United States)

1997-08-01T23:59:59.000Z

44

Storms, polar deposits and the methane cycle in Titan's atmosphere  

Science Journals Connector (OSTI)

...systems indicate the production of virga, with...daily averaged solar insolation (Brown...mid-troposphere convection cell evident from the...Sun lowers the solar heating two orders...methane and the production of haze causes...2008Titan's inventory of organic surface materials...application to the outer solar system. Astrophys...

2009-01-01T23:59:59.000Z

45

The Formation of Nitriles in Hydrocarbon-Rich Atmospheres  

E-Print Network (OSTI)

of the light elements hydrogen and helium;2 polyatomic molecules methane (CH4), ammonia (NH3), water (H2O at an early stage. As a consequence, the study of the chemistry of Titan's atmosphere offers the unique, Technical University Chemnitz, 09107 Chemnitz, Germany, and Department of Chemistry, University of York

Kaiser, Ralf I.

46

CO2 Conversion to CH4  

Science Journals Connector (OSTI)

A power-to-gas technology that converts renewable energy to methane...16]. Conversion of renewable energy, that is, solar or wind, into fuel is an easy way to store solar energy, characterized by low energy densi...

V. Barbarossa; C. Bassano; P. Deiana; G. Vanga

2013-01-01T23:59:59.000Z

47

U.S. Natural Gas System Methane Emissions: State of Knowledge from LCAs, Inventories, and Atmospheric Measurements (Presentation)  

SciTech Connect

Natural gas (NG) is a potential "bridge fuel" during transition to a decarbonized energy system: It emits less carbon dioxide during combustion than other fossil fuels and can be used in many industries. However, because of the high global warming potential of methane (CH4, the major component of NG), climate benefits from NG use depend on system leakage rates. Some recent estimates of leakage have challenged the benefits of switching from coal to NG, a large near-term greenhouse gas (GHG) reduction opportunity. During this presentation, Garvin will review evidence from multiple perspectives - life cycle assessments (LCAs), inventories and measurements - about NG leakage in the US. Particular attention will be paid to a recent article in Science magazine which reviewed over 20 years of published measurements to better understand what we know about total methane emissions and those from the oil and gas sectors. Scientific and policy implications of the state of knowledge will be discussed.

Heath, G.

2014-04-01T23:59:59.000Z

48

Catalytic deactivation on methane steam reforming catalysts. 2. Kinetic study  

SciTech Connect

The kinetics of methane steam reforming reaction over an alumina-supported nickel catalyst was investigated at a temperature range of 640-740/sup 0/C in a flow reactor at atmospheric pressure. The experiments were performed varying the inlet concentration of methane, hydrogen, and water. A kinetic scheme of the Houghen-Watson type was satisfactorily proposed assuming the dissociative adsorption of CH/sub 4/ as the rate-limiting step, but this kinetic scheme can be easily replaced by a first-order kinetics (r/sub CH/4/sub / = kapparho/sub CH/4/sub /) for engineering purposes. Catalyst activation with H/sub 2/ and N/sub 2/ mixtures or with the reactant mixture results in the same extent of reaction.

Agnelli, M.E.; Ponzi, E.N.; Yeramian, A.A.

1987-08-01T23:59:59.000Z

49

Warum Methan in der Atmosphre ansteigt Die Rolle von Archaebakterien  

Science Journals Connector (OSTI)

Methan ist ein brennbares Gas, das nach seiner Herkunft auch als Erdgas, Grubengas oder Sumpfgas bezeichnet wird. Es ist der einfachste Kohlenwasserstoff. Seine Summenformel ist CH4.

Rudolf K. Thauer

1992-01-01T23:59:59.000Z

50

CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1  

DOE Data Explorer (OSTI)

This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

Margaret Torn

51

Evidence for large methane releases to the atmosphere from deep-sea gas-hydrate dissociation during the last glacial episode  

Science Journals Connector (OSTI)

...inductively coupled plasma optical emission...waters induced by the thermal dissociation of gas...large increases in atmospheric concentration...episode. | Past atmospheric methane-concentration...Research Support, Non-U.S. Gov't...2006036403 Past atmospheric methane-concentration...

Thibault de Garidel-Thoron; Luc Beaufort; Franck Bassinot; Pierre Henry

2004-01-01T23:59:59.000Z

52

ARM - Methane Background Information  

NLE Websites -- All DOE Office Websites (Extended Search)

our atmosphere's methane levels have more than doubled in the last 200 years. These methane levels contribute to the greenhouse effect, which contributes to overall climate change....

53

Rapid communication Mapping urban pipeline leaks: Methane leaks across Boston  

E-Print Network (OSTI)

Rapid communication Mapping urban pipeline leaks: Methane leaks across Boston Nathan G. Phillips a of methane (CH4) in the United States. To assess pipeline emissions across a major city, we mapped CH4 leaks signatures w20& lighter (m ¼ ?57.8&, ?1.6& s.e., n ¼ 8). Repairing leaky natural gas distribution systems

Jackson, Robert B.

54

A Mercury-Catalyzed, High-Yield System for the Oxidation of Methane to Methanol  

Science Journals Connector (OSTI)

...con-version of methane to methanol with...for commercial economics. See N. D. Parkyns...How-ever, most methane (CH4) is in locations...desirable to convert methane into liquid products...process termed steam reforming (l): CH4 + H2O-C...

Roy A. Periana; Douglas J. Taube; Eric R. Evitt; Daniel G. Lffler; Paul R. Wentrcek; George Voss; Toshihiko Masuda

1993-01-15T23:59:59.000Z

55

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed DE-NT0006553 Goal The goal of this project is to define, plan, conduct and evaluate the results of a field trial of a methane hydrate production methodology whereby carbon dioxide (CO2) molecules are exchanged in situ for methane (CH4) molecules within a hydrate structure, releasing the methane for production. The objective is to evaluate the viability of this hydrate production technique and to understand the implications of the process at a field scale. image showing Conceptual rendering of proposed CO2 - CH4 exchange methodology for the production of natural gas from hydrates Conceptual rendering of proposed CO2 - CH4 exchange methodology for the

56

E-Print Network 3.0 - atmospheric methane consumption Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidation of Methane with Air in AC Electric Gas Discharge Summary: , and specific energy consumption. Methane and oxygen conversions increased with input power but...

57

Unusual reaction paths of SN2 nucleophile substitution reactions CH4+H-  

E-Print Network (OSTI)

Unusual reaction paths of SN2 nucleophile substitution reactions CH4+H- CH4+H- and CH4+F- CH3F for the SN2 nucleophile substitution reactions CH4+H- CH4+H- and CH4+F- CH3F+H- . The calculated gradient of the PES, which is observed for almost all the studied gas phase SN2 reactions [1-18]. However, when

Quapp, Wolfgang

58

Infrared experimental proof of the orientation of CH4 adsorbed in NaA zeolite by means of the degeneracy splitting of the 03BD3 band,  

E-Print Network (OSTI)

L-255 Infrared experimental proof of the orientation of CH4 adsorbed in NaA zeolite by means (C3v) en face d'un cation Na+. Abstract 2014 The infrared spectrum ofmethane adsorbed in NaA zeolite lattice and connected by windows of 4 A diameter [1]. The methane molecule adsorbed in these cavities

Paris-Sud XI, Université de

59

Performance Characteristics of Fluidized Bed Syngas Methanation over Ni-Mg/Al2O3 Catalyst  

Science Journals Connector (OSTI)

Abstract The performance characteristics of isothermal fluidized bed syngas methanation for substitute natural gas is investigated over a self-made Ni-Mg/Al2O3 catalyst. Via atmospheric methanation in a laboratory fluidized bed reactor it was clarified that the CO conversion varied in 5% when changing the space velocity in 40-120Lg-1h-1 but the conversion increased obviously by raising the superficial gas velocity from 4 to 12.4cms-1. The temperature 823K is suitable for syngas methanation while obvious deposition of uneasy-oxidizing C? occurs on the catalyst at temperatures around 873K. From kinetic aspect, the lowest reaction temperature is suggested to be 750K when the space velocity is 60Lg-1h-1. Raising the H2/CO ratio of the syngas increased proportionally the CO conversion and CH4 selectivity, showing that at enough high H2/CO ratios the active sites on the catalyst are sufficient for CO adsorption and in turn the reaction with H2 for forming CH4. Introducing CO2 into the syngas feed increased H2 consumption but suppressed water gas shift and Boudouard reactions. The ratio of CO2/CO in syngas should be better below 0.52 because varying the ratio from 0.52 to 0.92 resulted in negligible increases in the H2 conversion and CH4 selectivity but decreased the CH4 yield. Introducing steam into the feed gas affected little the CO conversion but decreased the selectivity to CH4. The tested Ni-Mg/Al2O3 catalyst manifested good stability in structure and activity even in syngas containing water vapor.

Jiao Liu; Dianmiao Cui; Jian Yu; Fabing Su; Guangwen Xu

2014-01-01T23:59:59.000Z

60

Influence of propane on CO2/CH4 and N2/CH4 separations in CHA zeolite membranes  

Science Journals Connector (OSTI)

Abstract Two types of CHA zeolite membranes (SAPO-34, SSZ-13) were used for CO2/CH4, N2/CH4, and CO2/i-butane separations at both low (270 and 350kPa) and high (1.73MPa) pressures. The SSZ-13 membranes were more selective, with CO2/CH4 separation selectivities as high as 280 and N2/CH4 separation selectivities of 12 at 270kPa feed pressure. For both types of membranes, selectivities and permeances decreased as the feed pressure increased. The CO2/i-butane separation selectivities were greater than 500,000 for SAPO-34 membranes, indicating extremely low densities of defects because i-butane is too large to enter the CHA pores. The CO2/i-butane selectivities were smaller for SSZ-13 membranes (2,80020,000), in part because the SSZ-13 layer was on the outside of the porous mullite tubes and sealing the membrane on the zeolite surface was more difficult than for the SAPO-34 membranes that were grown on the inside of glazed alumina tubes. Propane, in feed concentrations from 1 to 9%, significantly influenced separations by decreasing permeances in most cases. The effect was larger for N2/CH4 than for CO2/CH4 mixtures, apparently because the more strongly-adsorbing CO2 competes better than N2 with propane for adsorption sites. Although propane caused permeances to decrease significantly over time, selectivities decreased much less. Propane decreased permeances more for SAPO-34 membranes than for SSZ-13 membranes at 350kPa, and at high pressure propane even increased CO2 permeances and decreased CH4 permeances in SSZ-13 membranes, thus significantly increasing CO2/CH4 selectivities. Propane permeances reached steady state relatively quickly because its permeation was mostly through defects, but CO2, N2, and CH4 permeances did not stabilize in the presence of propane, even after seven days. The effects of propane were reversible when it was removed from the feed and the membranes were heated.

Ting Wu; Merritt C. Diaz; Yihong Zheng; Rongfei Zhou; Hans H. Funke; John L. Falconer; Richard D. Noble

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Micrometeorological Measurements of Methane and Carbon Dioxide Fluxes at a Municipal Landfill  

Science Journals Connector (OSTI)

Micrometeorological Measurements of Methane and Carbon Dioxide Fluxes at a Municipal Landfill ... Of the global anthropogenic CH4 emissions, more than 10% originates from landfills (1). ... Landfills are the largest source of anthropogenic CH4 emissions to the atm. in the US; however, few measurements of whole landfill CH4 emissions have been reported. ...

Annalea Lohila; Tuomas Laurila; Juha-Pekka Tuovinen; Mika Aurela; Juha Hatakka; Tea Thum; Mari Pihlatie; Janne Rinne; Timo Vesala

2007-03-15T23:59:59.000Z

62

Combustion Characteristics of Coal Gangue under an Atmosphere of Coal Mine Methane  

Science Journals Connector (OSTI)

(2) CH4 is the third most important greenhouse gas (GHG) after H2O vapor and CO2, and has a global warming potential that is 21 times that of CO2. ... Wang, C. a.; Liu, Y.; Zhang, X.; Che, D.A Study on Coal Properties and Combustion Characteristics of Blended Coals in Northwestern China Energy Fuels 2011, 25, 3634 3645 ...

Jun Ren; Chuanjin Xie; Xuan Guo; Zhifeng Qin; Jian-Ying Lin; Zhong Li

2014-05-16T23:59:59.000Z

63

Adsorption Kinetics of CO2, CH4, and their Equimolar Mixture on Coal from the Black Warrior Basin, West-Central Alabama  

SciTech Connect

Laboratory experiments were conducted to investigate the adsorption kinetic behavior of pure and mixed gases (CO2, CH4, approximately equimolar CO2 + CH4 mixtures, and He) on a coal sample obtained from the Black Warrior Basin at the Littleton Mine (Twin Pine Coal Company), Jefferson County, west-central Alabama. The sample was from the Mary Lee coal zone of the Pottsville Formation (Lower Pennsylvanian). Experiments with three size fractions (45-150 m, 1-2 mm, and 5-10 mm) of crushed coal were performed at 40 C and 35 C over a pressure range of 1.4 6.9 MPa to simulate coalbed methane reservoir conditions in the Black Warrior Basin and provide data relevant for enhanced coalbed methane recovery operations. The following key observations were made: (1) CO2 adsorption on both dry and water-saturated coal is much more rapid than CH4 adsorption; (2) water saturation decreases the rates of CO2 and CH4 adsorption on coal surfaces, but it appears to have minimal effects on the final magnitude of CO2 or CH4 adsorption if the coal is not previously exposed to CO2; (3) retention of adsorbed CO2 on coal surfaces is significant even with extreme pressure cycling; and (4) adsorption is significantly faster for the 45-150 m size fraction compared to the two coarser fractions.

Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Naney, Michael {Mike} T [ORNL; Blencoe, James {Jim} G [ORNL; Cole, David R [ORNL; Pashin, Jack C. [Geological Survey of Alabama; Carroll, Richard E. [Geological Survey of Alabama

2009-01-01T23:59:59.000Z

64

CO2 + CH4 Chemistry over Pd: Results of Kinetic Simulations Relevant to  

E-Print Network (OSTI)

-component feed gas consisted of CO2 and CH4 with total pressure of 1 bar. The CO2 ­ CH4 partial pressures reactions in certain situations. Even in the gas-phase for example the reaction between CO2 and CH4 yielding reactor employing CO2 and CH4 as the two-component feed gas. We discuss the pred

Spiteri, Raymond J.

65

CO2 and CH4 Fluxes across Polygon Geomorphic Types, Barrow, Alaska, 2006-2010  

DOE Data Explorer (OSTI)

Carbon flux data are reported as Net Ecosystem Exchange (NEE), Gross Ecosystem Exchange (GEE), Ecosystem Respiration (ER), and Methane (CH4) flux. Measurements were made at 82 plots across various polygon geomorphic classes at research sites on the Barrow Environmental Observatory (BEO), the Biocomplexity Experiment site on the BEO, and the International Biological Program (IBP) site a little west of the BEO. This product is a compilation of data from 27 plots as presented in Lara et al. (2012), data from six plots presented in Olivas et al. (2010); and from 49 plots described in (Lara et al. 2014). Measurements were made during the peak of the growing seasons during 2006 to 2010. At each of the measurement plots (except Olivas et al., 2010) four different thicknesses of shade cloth were used to generate CO2 light response curves. Light response curves were used to normalize photosynthetically active radiation that is diurnally variable to a peak growing season average ~400 umolm-2sec-1. At the Olivas et al. (2010) plots, diurnal patterns were characterized by repeated sampling. CO2 measurements were made using a closed-chamber photosynthesis system and CH4 measurements were made using a photo-acoustic multi-gas analyzer. In addition, plot-level measurements for thaw depth (TD), water table depth (WTD), leaf area index (LAI), and normalized difference vegetation index (NDVI) are summarized by geomorphic polygon type.

Tweedie, Craig; Lara, Mark

66

Modeling ruminant methane emissions from the U.S. beef cattle industry  

E-Print Network (OSTI)

Computer models were constructed to estimate methane emissions from cow/calf, replacement heifers, burs, stockers and feedlot sectors of the U.S. beef cattle industry. Methane (CH4) yields were calculated based on net energy values and forage...

Turk, Danny Carroll

2012-06-07T23:59:59.000Z

67

Pan-Arctic landatmospheric fluxes of methane and carbon dioxide in response to climate change over the 21st century  

E-Print Network (OSTI)

Future changes of pan-Arctic landatmospheric methane (CH[subscript 4]) and carbon dioxide (CO[subscript 2]) depend on how terrestrial ecosystems respond to warming climate. Here, we used a coupled hydrologybiogeochemistry ...

Zhu, Xudong

68

Engineering Methane is a major component of shale gas. Recent  

E-Print Network (OSTI)

-added chemicals, (ii) efficient electricity generation through fuel cells, and (iii) methane storage for vehicles), and electrochemical oxidation of CH4 in the solid oxide fuel cell (SOFC). In situ IR studies revealed that adsorbed-based catalysts involved decomposition of CH4 to surface carbon/coke and adsorbed hydrogen, followed

69

Chemiluminescence-based multivariate sensing of local equivalence ratios in premixed atmospheric methane-air flames  

SciTech Connect

Chemiluminescence emissions from OH*, CH*, C2, and CO2 formed within the reaction zone of premixed flames depend upon the fuel-air equivalence ratio in the burning mixture. In the present paper, a new partial least square regression (PLS-R) based multivariate sensing methodology is investigated and compared with an OH*/CH* intensity ratio-based calibration model for sensing equivalence ratio in atmospheric methane-air premixed flames. Five replications of spectral data at nine different equivalence ratios ranging from 0.73 to 1.48 were used in the calibration of both models. During model development, the PLS-R model was initially validated with the calibration data set using the leave-one-out cross validation technique. Since the PLS-R model used the entire raw spectral intensities, it did not need the nonlinear background subtraction of CO2 emission that is required for typical OH*/CH* intensity ratio calibrations. An unbiased spectral data set (not used in the PLS-R model development), for 28 different equivalence ratio conditions ranging from 0.71 to 1.67, was used to predict equivalence ratios using the PLS-R and the intensity ratio calibration models. It was found that the equivalence ratios predicted with the PLS-R based multivariate calibration model matched the experimentally measured equivalence ratios within 7%; whereas, the OH*/CH* intensity ratio calibration grossly underpredicted equivalence ratios in comparison to measured equivalence ratios, especially under rich conditions ( > 1.2). The practical implications of the chemiluminescence-based multivariate equivalence ratio sensing methodology are also discussed.

Tripathi, Markandey M.; Krishnan, Sundar R.; Srinivasan, Kalyan K.; Yueh, Fang-Yu; Singh, Jagdish P.

2012-03-01T23:59:59.000Z

70

E-Print Network 3.0 - atmospheric methane removal Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

from the U-trap, remove carbon and hydrogen impurities, oxidize the purified methane to CO2 and H2... . The helium gas was recycled through the U-trap (1) to remove and purify...

71

Interactions between wetlands CH4 emissions and climate at global scale  

E-Print Network (OSTI)

emissions? Observations Introduction Tool Wetlands emissions [CH4 ]atmo Feedback Conclusion #12;[CO2 ]atmo e.g.: Climate (T) CO2 anthropogenic emissions wetlands CH4 emissions Under future climate change, Shindell et al. (2004) => +78% under climate change generated by 2xCO2 Introduction Tool Wetlands emissions [CH4

Canet, Léonie

72

J. Am. Chem. SOC.1994,116, 7815-7826 7815 Conversion of CH4 to CH3OH: Reactions of COO+with CH4  

E-Print Network (OSTI)

J. Am. Chem. SOC.1994,116, 7815-7826 7815 Conversion of CH4 to CH3OH: Reactions of COO+with CH4 a half century because of its great economic and scientific importance.' Although this oxidation reaction of providing fundamental information regarding this process is to study a prototypical gas-phase reaction MO

Clemmer, David E.

73

Unusual reaction paths of SN2 nucleophile substitution reactions CH4+H??CH4+H? and CH4+F??CH3F+H?: Quantum chemical calculations  

Science Journals Connector (OSTI)

Abstract Quantum chemical (CCSD(full)/6-311++G(3df,3pd), CCSD(T)(full)/6-311++G(3df,3pd)) and density function theory (B3LYP/6-311++G(3df,3pd)) calculations were performed for the SN2 nucleophile substitution reactions CH4+H??CH4+H? and CH4+F??CH3F+H?. The calculated gradient reaction pathways for both reactions have an unusual behavior. An unusual stationary point of index 2 lies on the gradient reaction path. Using Newton trajectories for the reaction path, we can detect VRI point at which the reaction path branches.

Ruslan M. Minyaev; Wolfgang Quapp; Benjamin Schmidt; Ilya V. Getmanskii; Vitaliy V. Koval

2013-01-01T23:59:59.000Z

74

The Role of the Ocean in the Atmospheric Budgets of Methyl Bromide, Methyl Chloride and Methane  

E-Print Network (OSTI)

of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved by: Chair of Committee, Shari A. Yvon-Lewis Committee Members, John D. Kessler Robert Rhew Gunnar W. Schade... to work with her. I would like to thank my committee members, Drs. John D. Kessler, Robert Rhew and Gunnar W. Schade. I went to two cruises with John and coauthored several papers with him. He gave me a lot of help and inspiration for methane study. He...

Hu, Lei

2012-10-19T23:59:59.000Z

75

Structure of Neutral Nanosized Clusters Produced by Coexpansion of CF4 and CH4  

Science Journals Connector (OSTI)

experimentTn (K)p0 (bar)bCF4CH4CF4CH4CF4CH4ACH4/ACF4e ... Carbon 1s photoelectron spectroscopy of CF4 and CO: Search for chemical effects on the carbon 1s hole-state lifetime ... C 1s photoelectron spectra for CF4 and CO were measured at several photon energies near the C 1s threshold. ...

M. Winkler; J. Harnes; K. J. Brve

2011-09-21T23:59:59.000Z

76

Assessing methane oxidation under landfill covers and its contribution to the above atmospheric CO2 levels: The added value of the isotope  

E-Print Network (OSTI)

biogas fluxes, which was expected in clay covers presenting fissures, through which CH4 is rapidly transported. At shallow depth, more immobile biogas pockets show a higher level of CH4 oxidation., 1998). The main com- ponents of biogas are CH4 (50­60%) and carbon dioxide (CO2; 40­50%). A major

77

Stoichiometry of CH4 and CO2 flux in a California Rice Paddy  

E-Print Network (OSTI)

Measurements of carbon sequestration by long-term eddyemission versus carbon sequestration, Tellus, Ser. B,which to estimate carbon sequestration from F CH4 data since

McMillan, Andrew M. S.; Goulden, Michael L.; Tyler, Stanley C.

2007-01-01T23:59:59.000Z

78

Methane Hydrate and Free Gas on the Blake Ridge from Vertical Seismic Profiling  

Science Journals Connector (OSTI)

...expression: The phase boundary between methane hydrate and methane plus...and methane hydrate, CH4-5.75H20...a structure I hydrate construct-ed...documented anomalous behavior in the formation...325 Fig. 1. Phase diagram for the...

W. Steven Holbrook; Hartley Hoskins; Warren T. Wood; Ralph A. Stephen; Daniel Lizarralde

1996-09-27T23:59:59.000Z

79

Constraining past global tropospheric methane budgets with carbon and hydrogen isotope ratios in ice  

Science Journals Connector (OSTI)

...turn, shift the global delta13CH4 and deltaD-CH4...for natural gas (coal, thermogenic or...Ledru2001Correlations of char coal records of fires...Ward1993Methane production from global biomass burning...Wuebbles2000Radiative forcings and global warming potentials of 39...

2007-01-01T23:59:59.000Z

80

Inverse modeling of European CH4 emissions 20012006 P. Bergamaschi,1  

E-Print Network (OSTI)

Inverse modeling of European CH4 emissions 2001­2006 P. Bergamaschi,1 M. Krol,2,3,4 J. F. Meirink,5] European CH4 emissions are estimated for the period 2001­2006 using a four dimensional variational (4DVAR/ESRL network. The available observations mainly provide information on the emissions from northwest Europe (NWE

Haak, Hein

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Methane and carbon dioxide emissions and nitrogen turnover during liquid manure storage  

Science Journals Connector (OSTI)

Anthropogenic emissions of the greenhouse gas (GHG) methane...4) have increased significantly during the twentieth century (IPCC 2001). Compared to carbon dioxide (CO2), the amounts of CH4 are low in the atmosphe...

Sven G. Sommer; Sren O. Petersen; Peter Srensen

2007-05-01T23:59:59.000Z

82

Development of correction factors for landfill gas emission model suiting Indian condition to predict methane emission from landfills  

Science Journals Connector (OSTI)

Abstract Methane emission from landfill gas emission (LandGEM) model was validated through the results of laboratory scale biochemical methane potential assay. Results showed that LandGEM model over estimates methane (CH4) emissions; and the true CH4 potential of waste depends on the level of segregation. Based on these findings, correction factors were developed to estimate CH4 emission using LandGEM model especially where the level of segregation is negligible or does not exist. The correction factors obtained from the study were 0.94, 0.13 and 0.74 for food waste, mixed un-segregated municipal solid waste (MSW) and vegetable wastes, respectively.

Avick Sil; Sunil Kumar; Jonathan W.C. Wong

2014-01-01T23:59:59.000Z

83

Steam Reforming of Methane over Ni Catalysts Prepared from Hydrotalcite-Type Precursors: Catalytic Activity and Reaction Kinetics  

Science Journals Connector (OSTI)

Abstract Ni/Mg-Al catalysts derived from hydrotalcite-type precursors were prepared by a co-precipitation technique and applied to steam reforming of methane. By comparison with Ni/?-Al2O3 and Ni/?-Al2O3 catalysts prepared by incipient wetness impregnation, the Ni/Mg-Al catalyst presented much higher activity as a result of higher specific surface area and better Ni dispersion. The Ni/Mg-Al catalyst with a Ni/Mg/Al molar ratio of 0.5:2.5:1 exhibited the highest activity for steam methane reforming and was selected for kinetic investigation. With external and internal diffusion limitations eliminated, kinetic experiments were carried out at atmospheric pressure and over a temperature range of 823?973K. The results demonstrated that the overall conversion of CH4 and the conversion of CH4 to CO2 were strongly influenced by reaction temperature, residence time of reactants as well as molar ratio of steam to methane. A classical Langmuir-Hinshelwood kinetic model proposed by Xu and Froment (1989) fitted the experimental data with excellent agreement. The estimated adsorption parameters were consistent thermodynamically.

Yang Qi; Zhenmin Cheng; Zhiming Zhou

2014-01-01T23:59:59.000Z

84

Constraints on the microwave opacity of gaseous methane and water vapor in the Jovian atmosphere  

SciTech Connect

Gaseous NH/sub 3/'s microwave absorption in the Jovian atmosphere appears too great to be due to a solar abundance of this gas. The additional capacity of microwave absorption is presently sought in measurements of the microwave absorption of CH/sub 4/ and H/sub 2/O under simulated Jovian conditions at 2.25 GHz, 8.5 GHz, 21.7 GHz; due to large error bars, measurements represent upper limits on the microwave opacity generated by H/sub 2/O and CH/sub 4/. The results obtained are consistent with theoretical expressions for microwave opacity in a Jovian atmosphere at the specified frequencies. The presence of an NH/sub 3/ abundance exceeding the solar level by a factor of 1.5 is indicated by test results. 16 references.

Jenkins, J.M.; Steffes, P.G.

1988-11-01T23:59:59.000Z

85

The influence of air inflow on CH4 composition ratio in landfill gas  

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When landfill gas is collected, air inflow into the landfill...4 productivity. The decline of CH4 content in landfill gas (LFG) negatively affects energy projects. We...2 was an effective indicator of air inflow ...

Seung-Kyu Chun

2014-02-01T23:59:59.000Z

86

Experimental investigations on combustion characteristics of syngas composed of CH4, CO, and H2  

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The residual gas and remained raw gas in dual gas resources polygeneration system are quite complex in components (mainly CH4, CO, and H2...), and these results to the distinguished differences in combustion reac...

Qingwei Fan; Shien Hui; Qulan Zhou

2010-12-01T23:59:59.000Z

87

X-ray diffraction studies and equation of state of methane at 202 GPa Liling Sun a,*, Wei Yi a  

E-Print Network (OSTI)

X-ray diffraction studies and equation of state of methane at 202 GPa Liling Sun a,*, Wei Yi that at room temperature compressed CH4 remains an insulator with cubic structure to 202 GPa. ? 2009 Elsevier B of planetary interiors and the origin of their magnetic field distribution. CH4 has a very rich phase diagram

Shen, Guoyin

88

Dopant low-n Rydberg states in CF4 and CH4 near the critical point  

E-Print Network (OSTI)

Dopant low-n Rydberg states in CF4 and CH4 near the critical point Luxi Li a,b , Xianbo Shi a,b , G States Abstract Dopant low-n Rydberg states perturbed by dense CF4 and CH4 were investigated using vacuum. Evans). 2 #12;ular fluids. We present absorption spectra of the xenon 6s Rydberg state perturbed by CF4

Findley, Gary L.

89

Atmospheric Measurements of Climate-Relevant Species  

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Atmospheric Measurements of Climate-Relevant Species Atmospheric Measurements of Climate-Relevant Species CDIAC's data collection includes measurements of the following climate-relevant chemical species. A summary of recent greenhouse gas concentrations is also available. To determine how compounds are named, see the CDIAC "Name that compound" page. Butane (C4H10) Carbon Dioxide (CO2) Carbon Isotopes Carbon Monoxide (CO) Carbon Tetrachloride (CCl4) Chlorofluorocarbons Chloroform (CHCl3) Deuterium (2H) Ethane (C2H6) Ethyl Nitrate (C2H5ONO2) Ethyne (C2H2) Fluoroform (CHF3) Halogenated Compounds (modern records) Halons (fluorocarbons) Hydrogen (H2) Hydrochlorofluorocarbons (HCFCs) Hydrofluorocarbons (HFCs) i-Propyl Nitrate (C3H7ONO2) Methane (CH4) Methyl Bromide (CH3Br) Methyl Chloride (CH3Cl) Methyl Chloroform (CH3CCl3)

90

Emissions of carbon dioxide, methane and nitrous oxide from soil receiving urban wastewater for maize (Zea mays L.) cultivation  

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We investigated how amending maize with wastewater at 120kg N ha?1 affected crop growth, soil characteristics and emissions of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) compared to plants ferti...

Fabin Fernndez-Luqueo; Vernica Reyes-Varela

2010-06-01T23:59:59.000Z

91

Four Corners methane hotspot points to coal-related sources  

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methane hotspot points to coal-related sources Methane is very efficient at trapping heat in the atmosphere and, like carbon dioxide, it contributes to global warming. October...

92

Methane Main  

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the the Methane Hydrate Advisory Committee on Methane Hydrate Issues and Opportunities Including Assessment of Uncertainty of the Impact of Methane Hydrate on Global Climate Change December 2002 Report of the Methane Hydrate Advisory Committee on Methane Hydrate Issues and Opportunities Including Assessment of Uncertainty of the Impact of Methane Hydrate on Global Climate Change December 2002 i CONTENTS What is Methane Hydrate? ............................................................................................. 1 Why Methane Hydrate Matters for the United States? ..................................................... 4 Resource Potential of Methane Hydrate .......................................................................... 5 Implications of Methane Hydrate on Safety and Seafloor Stability

93

Global Atmospheric Change and Animal Populations  

E-Print Network (OSTI)

, which are increasing in frequency, also produce large amounts of greenhouse gases (e.g., CO2; methane to increase dramatically (Withgott & Brennan, 2009; Figure 2). Burning of fossil fuels, such as coal, gasoline by 2100 (IPCC 2007). (Approximate contribution to global warming: 33%; Hansen & Sato 2001). Methane (CH4

94

Strategic use of the underground in an energy mix plan: Synergies among CO2, CH4 geological storage and geothermal energy. Latium Region case study (Central Italy)  

Science Journals Connector (OSTI)

Abstract In recent decades, the worldwide demand for energy has been increasing, with an associated rise in CO2 emissions being observed. In such conditions, the development of low carbon energy technologies and strategic energy-mix plans is necessary, and an evaluation of the underground energy potential may be a useful step in developing these plans. This evaluation involves the synergic development of such technologies as: coal combustion in combination with CO2 geological storage (CCS), natural gas geological storage (CH4-GS) and geothermal energy (GE), especially in densely populated countries, such as Italy. Currently, 13.7% of Italian energy demand is met by foreign providers. Most of the Italian regions have energy deficits, and the Latium Region (in Central Italy) represents one of those in the worst conditions. This work proposes a methodology to develop energy-mix scenarios, starting in Latium, to identify areas that are potentially suitable for CCS, CH4-GS and GE. Six geothermal systems and one CO2/CH4 storage potential area were identified. Three main scenarios are proposed: (A) a combination of CH4-GS with methane as cushion gas and GE; (B) a combination of CH4-GS with CO2 as cushion gas and GE; (C) a combination of CCS and GE. Scenario A results in a reduction of the regional energy deficit that ranges from 21.8% to 45.6%. In Scenario B, the regional energy deficit reduction ranges from 30.8% to 80.7% and the CO2 emissions reduction ranges from 1.4% to 5.6%, supposing an injection of 20years. Scenario C shows a decrease in the regional energy deficit that ranges from 15.9% to 22.1%, while the CO2 emissions reduction ranges from 7.1% to 31.3%, over the same time period. The proposed scenarios may be useful not only for the scientific community but also for policymakers as they identify the most reliable energetic strategies. Thus, this case study could be extended to the entire Italian territory with the ultimate goal of reaching energy autonomy in each region.

M. Procesi; B. Cantucci; M. Buttinelli; G. Armezzani; F. Quattrocchi; E. Boschi

2013-01-01T23:59:59.000Z

95

Effects of CH4, H2 and CO2 Mixtures on SI Gas Engine  

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Abstract Performance of a four-stroke spark ignition gas engine operated on mixtures of CH4, H2 and CO2 was studied. Experiments were carried out at a constant engine speed of 2,000rpm and throttle opening of 14% with various equivalence ratios. The results showed that the highest brake power output of 12.5kW and 35% thermal efficiency were achieved when operated with the mixture of 69.70% CH4, 9.95% H2 and 20.45% CO2 and the equivalence ratios between 1.0 and 0.82.

S. Chuayboon; S. Prasertsan; T. Theppaya; K. Maliwan; P. Prasertsan

2014-01-01T23:59:59.000Z

96

Laboratory Investigations of a Low-swirl Injector withH2 and CH4 at Gas  

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Investigations of a Low-swirl Injector withH2 and CH4 at Gas Investigations of a Low-swirl Injector withH2 and CH4 at Gas Turbine Conditions Title Laboratory Investigations of a Low-swirl Injector withH2 and CH4 at Gas Turbine Conditions Publication Type Journal Article Year of Publication 2009 Authors Cheng, Robert K., David Littlejohn, P. A. Strakey, and T. Sidwell Journal Science Direct Abstract Laboratory experiments were conducted at gas turbine and atmospheric conditions (0.101 < P0 < 0.810 MPa, 298 < T0 < 580K, 18 < U0 < 60 m/s) to characterize the overall behaviors and emissions of the turbulent premixed flames produced by a low-swirl injector (LSI) for gas turbines. The objective was to investigate the effects of hydrogen on the combustion processes for the adaptation to gas turbines in an IGCC power plant. The experiments at high pressures and temperatures showed that the LSI can operate with 100% H2 at up to f = 0.5 and has a slightly higher flashback tolerance than an idealized high-swirl design. With increasing H2 fuel concentration, the lifted LSI flame begins to shift closer to the exit and eventually attaches to the nozzle rim and assumes a different shape at 100% H2. The STP experiments show the same phenomena. The analysis of velocity data from PIV shows that the stabilization mechanism of the LSI remains unchanged up to 60% H2. The change in the flame position with increasing H2 concentration is attributed to the increase in the turbulent flame speed. The NOx emissions show a log linear dependency on the adiabatic flame temperature and the concentrations are similar to those obtained previously in a LSI prototype developed for natural gas. These results show that the LSI exhibits the same overall behaviors at STP and at gas turbine conditions. Such insight will be useful for scaling the LSI to operate at IGCC conditions.

97

ch_4  

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47 47 DOE/EIS-0287 Idaho HLW & FD EIS 4.8.2 SUBSURFACE WATER Subsurface water at INEEL occurs in the under- lying Snake River Plain Aquifer and the vadose zone (area of unsaturated soil and material above the aquifer). This section describes the regional and local hydrogeology, vadose zone hydrology, perched water, and subsurface water quality. 4.8.2.1 Regional Hydrogeology INEEL overlies the Snake River Plain Aquifer as shown in Figure 4-12. This aquifer is the major source of drinking water for southeast- ern Idaho and has been desig- nated a Sole Source Aquifer by EPA. The aquifer flows to the south and southwest and covers an area of 9,611 square miles. Water storage in the aquifer is estimated at 2 billion acre-feet, and irrigation wells can yield 7,000 gallons per minute (DOE 1995). Depth to the

98

ch_4  

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1998, INEEL 1998, INEEL contracts paid $1.4 million to the State of Idaho in Idaho sales taxes and an additional $0.9 million in Idaho franchise tax. 4.4 Cultural Resources 4.4.1 CULTURAL RESOURCE MANAGEMENT AND CONSULTATION AT INEEL Cultural resources at INEEL include archaeolog- ical and historic resources, such as prehistoric camp sites and historic buildings and trails, as well as the plants, animals, physical locations, and other features of INEEL environment impor- tant to the culture of the Shoshone-Bannock Tribes and to national, regional and local history. Several Federal laws, which are described in Chapter 6, govern the protection of archaeologi- cal and historic resources on lands managed by Federal agencies. These and other laws also require consultations among Federal agencies,

99

ch_4  

NLE Websites -- All DOE Office Websites (Extended Search)

71 71 DOE/EIS-0287 Idaho HLW & FD EIS university research programs and private con- tractors. Ongoing studies by the Centers for Disease Control and Prevention, an agency of the U.S. Department of Health and Human Services, also carefully tracks possible health effects from past activities at INEEL. 4.11.1.1 Radiological Health Risk Very low doses of radiation are not known to cause health effects in humans; however, extrapolation of the dose-response relationship from high doses indicates that statistical effects might be observed in large populations. The doses reported in this EIS from INEEL opera- tions are in this very low category. This EIS reports two values: col- lective dose (in person- rem) and the hypothetical number of latent cancer fatalities. For effects on

100

ch_4  

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20 20 Affected Environment 4.6 Geology and Soils This section describes the geological, mineral resources, seismic, and volcanic characteristics of INEEL, INTEC, and surrounding areas. A more detailed description of geology at INEEL can be reviewed in the SNF & INEL EIS, Volume 2, Part A, Section 4.6 (DOE 1995). 4.6.1 GENERAL GEOLOGY INEEL occupies a relatively flat area on the northwestern edge of the Eastern Snake River Plain. Figure 4-4 shows important geological features of the INEEL area. The area consists of a broad plain that has been built up from the eruptions of multi- ple flows of basaltic lava, which is shown on Figure 4-5. The flows at the surface range in age from 1.2 million to 2,100 years. The Plain is bounded on the north and south by the north-to-north-

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

ch_4  

NLE Websites -- All DOE Office Websites (Extended Search)

40 40 Affected Environment playas 15 to 20 miles northeast of INTEC, where the water infiltrates. The water in Birch Creek and the Little Lost River is diverted in summer months for irriga- tion prior to reaching INEEL. During periods of unusually high precipitation or rapid snow melt, water from Birch Creek and the Little Lost River may enter INEEL from the northwest and infil- trate the ground, recharging the underlying aquifer. 4.8.1.2 Local Drainage INTEC is located on an alluvial plain approxi- mately 200 feet from the Big Lost River channel near the channel intersection with Lincoln Boulevard on INEEL. INTEC is surrounded by a stormwater drainage ditch system (DOE 1998). Stormwater runoff from most areas of INTEC flows through the ditches to an abandoned gravel

102

ch_4  

NLE Websites -- All DOE Office Websites (Extended Search)

Antelope Buttes are visible to the northeast. Smaller volcanic buttes dot the natural landscape of INEEL, providing a striking contrast to the relatively flat ground surface. The...

103

ch_4  

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Moon National Monument and Wilderness Area, Hell's Half Acre Wilderness Study Area, Black Canyon Wilderness Study Area, Camas National Wildlife Refuge, Market Lake Wildlife...

104

ch_4  

NLE Websites -- All DOE Office Websites (Extended Search)

58 58 Affected Environment 4.9.1 PLANT COMMUNITIES AND ASSOCIATIONS INEEL lies within a cool desert ecosystem dom- inated by shrub-steppe vegetation. The area is relatively undisturbed, providing important habi- tat for species native to the region. Vegetation and habitat on INEEL can be grouped into six types: shrub-steppe, juniper woodlands, native grasslands, modified ephemeral playas, lava, and wetland-like areas. Figure 4-16 shows these areas. More than 90 percent of INEEL falls within the shrub-steppe vegetation type. The shrub-steppe vegetation type is dominated by sagebrush (Artemisia spp.), saltbush (Atriplex spp.), and rabbitbrush (Chrysothamnus spp.). Grasses found on INEEL include cheatgrass (Bromus tectorum), Indian ricegrass (Oryzopsis hymenoides), wheatgrass (Agropyron spp.), and

105

JASPERSE CHEM 350 TEST 2 VERSION 3 Ch. 4 The Study of Chemical Reactions  

E-Print Network (OSTI)

toward SN2 reactions (from most reactive 1 to least reactive 4). Br Br Br I 4. Rank the bond strengthJASPERSE CHEM 350 TEST 2 VERSION 3 Ch. 4 The Study of Chemical Reactions Ch. 5 Sterochemistry Ch. 6 the following alkyl halides in order of decreasing reactivity toward SN1/E1 reactions (from most reactive 1

Jasperse, Craig P.

106

JASPERSE CHEM 350 TEST 2 VERSION 2 Ch. 4 The Study of Chemical Reactions  

E-Print Network (OSTI)

;9. Show an alkyl bromide and some nucleophile that you could use to make the following by SN2. (3 pointsJASPERSE CHEM 350 TEST 2 VERSION 2 Ch. 4 The Study of Chemical Reactions Ch. 5 Sterochemistry Ch. 6 that is needed in each case) for each of the following reactions. (Minor products or inorganic side products need

Jasperse, Craig P.

107

CH4 and N2O emissions from Spartina alterniflora and Phragmites australis in experimental mesocosms  

E-Print Network (OSTI)

Author's personal copy CH4 and N2O emissions from Spartina alterniflora and Phragmites australis emissions from S. alterniflora with those from a native C3 plant, Phragmites australis, by establishing Elsevier Ltd. All rights reserved. Keywords: Common reed (Phragmites australis); Brackish marsh mesocosms

Chen, Jiquan

108

MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE  

E-Print Network (OSTI)

Municipal Solid Waste-Sewage Sludge. b 4.15 SCF CH 4 / cu ftUP I j methane 31.5 scf sludge 18.61b water 161b Btu/scfsewer 65.3 lb ( 7.9 gal) sludge ash 1.74 lb stack emissions

Haven, Kendall F.

2011-01-01T23:59:59.000Z

109

CSIRO GASLAB Network: Individual Flask Measurements of Atmospheric Trace  

NLE Websites -- All DOE Office Websites (Extended Search)

GASLAB Network GASLAB Network CSIRO GASLAB Network: Individual Flask Measurements of Atmospheric Trace Gases (April 2003) data Data Investigators L.P. Steele, P.R. Krummel, and R.L. Langenfelds Commonwealth Scientific and Industrial Research Organisation (CSIRO) DOI 10.3334/CDIAC/atg.db1021 Data are available for four atmospheric trace gases at nine stationary sites and one moving platform (aircraft over Cape Grim, Tasmania, and Bass Strait, between the Australian continent and Tasmania). The trace gases are carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), and hydrogen (H2). Measurements of δ13C from CO2 are also included in this database. The nine stationary sites are, from north to south: Alert, Canada; Shetland Islands, Scotland; Estevan Point, Canada; Mauna Loa, Hawaii; Cape Ferguson,

110

Deep-Sea Field Test of the CH4 Hydrate to CO2 Hydrate Spontaneous Conversion Hypothesis  

Science Journals Connector (OSTI)

We have carried out a small-scale deep-sea field test of the hypothesis that CH4 gas can be spontaneously produced from CH4 hydrate by injection of a CO2/N2 gas mixture, thereby inducing release of the encaged molecules with sequestration of the injected ...

Peter G. Brewer; Edward T. Peltzer; Peter M. Walz; Elizabeth K. Coward; Laura A. Stern; Stephen H. Kirby; John Pinkston

2014-10-06T23:59:59.000Z

111

Why Sequence a Methane-Oxidizing Archaean?  

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a Methane-Oxidizing Archaeon? a Methane-Oxidizing Archaeon? Methane is a potent greenhouse gas whose atmospheric concentration has increased significantly because of anthropogenic activities and fluctuated naturally over glacial and interglacial cycles. While the importance of methane in Earth's climate dynamics has been well established, the global processes regulating its oceanic cycling remain poorly understood. Although there are high rates of methane production in many marine sedimentary environments (including a number that have been targeted as petroleum reserves), net methane sources from the ocean to the atmosphere appear to be small. This is due in large part to a biogeochemical process known as the anaerobic oxidation of methane (AOM). Microbially mediated AOM reduces methane flux from ocean to atmosphere, stimulates subsurface microbial

112

Consumption of Methane and CO2 by Methanotrophic Microbial Mats from Gas Seeps of the Anoxic Black Sea  

Science Journals Connector (OSTI)

...Consumption of Methane and CO2 by Methanotrophic Microbial Mats from Gas Seeps of the Anoxic...Black Sea has numerous gas seeps, which are...patterns of CH4 and CO2 assimilation in relation...Consumption of methane and CO2 by methanotrophic microbial mats from gas seeps of the anoxic...

Tina Treude; Victoria Orphan; Katrin Knittel; Armin Gieseke; Christopher H. House; Antje Boetius

2007-02-02T23:59:59.000Z

113

The thermal decomposition of methane in a tubular reactor  

SciTech Connect

The reaction rate of methane decomposition using a tubular reactor having a 1 inch inside diameter with an 8 foot long heated zone was investigated in the temperature range of 700 to 900 C with pressures ranging from 28.2 to 56.1 atm. Representing the rate by a conventional model, {minus}dC{sub CH4}/dt= k1 C{sub CH4} {minus}k2 C{sub H2}{sup 2}, the rate constant k1 for methane decomposition was determined. The activation energy, 31.3 kcal/mol, calculated by an Arrhenius Plot was lower than for previously published results for methane decomposition. This result indicates that submicron particles found in the reactor adhere to the inside of the reactor and these submicron high surface area carbon particles tend to catalyze the methane decomposition. The rate constant has been found to be approximately constant at 900 C with pressure range cited above. The rate of methane decomposition increases with methane partial pressure in first-order. The rate of the methane decomposition is favored by higher temperatures and pressures while the thermochemical equilibrium of methane decomposition is favored by lower pressures. 8 refs., 7 figs., 2 tabs.

Kobayashi, Atsushi; Steinberg, M.

1992-01-01T23:59:59.000Z

114

Biogeochemistry 71: 141162, 2004. # 2004 Kluwer Academic Publishers. Printed in the Netherlands.  

E-Print Network (OSTI)

Introduction Atmospheric methane (CH4) is a powerful greenhouse gas that has contributed 50% as much enhanced

Gauci, Vincent

115

50&100YEARSAGO EXTRASOLAR PLANETS  

E-Print Network (OSTI)

of the powerful greenhouse gas methane (CH4) in planetary atmospheres. In Earth'satmosphere,thedominant sources

Royer, Dana

116

A comparative study of CH4 and CF4 rf discharges using a consistent plasma physics and chemistry simulator  

Science Journals Connector (OSTI)

A self-consistent, one-dimensional simulator for the physics and chemistry of radio frequency (rf) plasmas was developed and applied for CH4 and CF4. The simulator consists of a fluid model for the discharge phys...

Nikolaos V. Mantzaris; Evangelos Gogolides

1996-09-01T23:59:59.000Z

117

The role of CO2 in CH4 exsolution from deep brine: Implications for geologic carbon sequestration  

E-Print Network (OSTI)

spreading under the shale where gas saturation is higher duecomposition of the gas above the shale is mainly CH 4 , andeffect of the shale remains as higher gas saturations are

Oldenburg, C.M.

2014-01-01T23:59:59.000Z

118

Preparation and Adsorption Performance of GrO@Cu-BTC for Separation of CO2/CH4  

Science Journals Connector (OSTI)

Biomethane production from municipal wastes through anaerobic digestion technology is growing worldwide. ... CO2 is the main undesirable compound present in landfill gas, so CO2/CH4 separation is critical for the production of biomethane from landfill gas. ...

Wenyu Huang; Xin Zhou; Qibin Xia; Junjie Peng; Haihui Wang; Zhong Li

2014-06-08T23:59:59.000Z

119

Kinetics of the Selective Reduction of NO with CH4 Over an In-Fe2O3/HZSM-5 Catalyst  

Science Journals Connector (OSTI)

A kinetic model presented for the selective reduction of NO with CH4 over an In-Fe2O3/HZSM-5 catalyst by considering the process as a combination...2+CH4 (reaction 1) and O2+CH4 (reaction 2). Linear regression ca...

Xiaodong Wang; Weicheng Liu; Tao Zhang

2000-03-01T23:59:59.000Z

120

Negative ion motion in the mixtures of SF6 with CF4 and CH4-Ar  

Science Journals Connector (OSTI)

This paper deals with the measurement of the mobility of negative ions in the mixtures of SF6 with CF4 and the CH4-Ar (50:50) binary mixture with SF6 contents up to 50%. The pulsed Townsend technique was used to observe the integrated ionic avalanches over a range of the density-reduced electric field E/N for which ionization is either negligible or absent, and attachment processes are significant, leading to the formation of mostly SF6-. The E/N range of measurement was from 1 to 70 Td (1 Td=10-17 V cm2), over which the measured mobilities were found to be almost constant. The mobility of the negative ions was also measured for trace amounts of SF6 in CH4 and Ar and 1% CF4, thereby providing a good value of the mobility of SF6- in these pure gases, in order to test the measured mobilities with Blancs law. We have found good agreement, within quoted experimental uncertainties, between calculated and measured values.

J. de Urquijo and F. B. Yousif

2003-10-28T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water  

SciTech Connect

The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (??Methane in the Arctic Shelf? or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (??metagenomes?). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in anaerobic methane oxidation.

David Kirchman

2011-12-31T23:59:59.000Z

122

Experimental study of combustion of hydrogensyngas/methane fuel mixtures in a porous burner  

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Lean premixed combustion of hydrogensyngas/methane fuel mixtures was investigated experimentally to demonstrate fuel flexibility of a two-section porous burner. The un-insulated burner was operated at atmospheric pressure. Combustion was stabilized at the interface of silicon-carbide coated carbon foam of 26 pores per centimeter (ppcm) and 4ppcm. Methane (CH4) content in the fuel was decreased from 100% to 0% (by volume), with the remaining amount split equally between carbon monoxide (CO) and hydrogen (H2), the two reactive components of the syngas. Experiments for different fuel mixtures were conducted at a fixed air flow rate, while the fuel flow rate was varied to obtain a range of adiabatic flame temperatures. The CO and nitric oxide ( NO x ) emissions were measured downstream of the porous burner, in the axial direction to identify the post-combustion zone and in the transverse direction to quantify combustion uniformity. For a given adiabatic flame temperature, increasing H2/CO content in the fuel mixture decreased both the CO and NO x emissions. Presence of H2/CO in the fuel mixture also decreased temperature near the lean blow-off limit, especially for higher percentages of CO and H2 in the fuel.

S.K. Alavandi; A.K. Agrawal

2008-01-01T23:59:59.000Z

123

Methane Hydrates and Climate Change | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrates and Climate Change Hydrates and Climate Change Methane Hydrates and Climate Change Methane hydrates store huge volumes of methane formed by the bacterial decay of organic matter or leaked from underlying oil and natural gas deposits. The active formation of methane hydrates in the shallow crust prevents methane, a greenhouse gas, from entering the atmosphere. On the other hand, warming of arctic sediments or ocean waters has the potential to cause methane hydrate to dissociate, releasing methane into the deepwater sediments, the ocean or atmosphere. DOE is conducting research to understand the mechanisms and volumes involved in these little-studied processes. DOE environmental and climate change research projects related to Arctic methane hydrate deposits include: Characterization of Methane Degradation and Methane-Degrading

124

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 DE-NT0005667 Goal The goal of this project is to assess the efficacy of aerobic methanotrophy in preventing the escape of methane from marine, hydrate-bearing reservoirs to the atmosphere and ultimately to better define the role of aerobic methanotrophy in the global carbon cycle. Graph overlayed on photo - Methane seeps with the resulting methane plume Methane seeps with the resulting methane plume, Geophysical Research Letters, November 2007 Performers University of California – Santa Barbara, Santa Barbara (UCSB), CA 93106 Background The global methane reservoir in the form of gas hydrate is estimated at 500–10,000 Gt (KVENVOLDEN, 1995; MILKOV, 2004). This pool of carbon

125

Numerical modeling of methane venting from lake sediments  

E-Print Network (OSTI)

The dynamics of methane transport in lake sediments control the release of methane into the water column above, and the portion that reaches the atmosphere may contribute significantly to the greenhouse effect. The observed ...

Scandella, Benjamin P. (Benjamin Paul)

2010-01-01T23:59:59.000Z

126

Airborne observations of methane emissions from rice cultivation in the Sacramento Valley of California  

E-Print Network (OSTI)

, the California Air Resources Board (CARB) greenhouse gas inventory emission rate of 2.7 ? 1010 g CH4/yr is not accounted for in the CARB inventory. Citation: Peischl, J., et al. (2012), Airborne observations of methane California, which include livestock, landfills, wastewater treatment, oil and gas drilling and distribution

Cohen, Ronald C.

127

1 In situ Ramanbased measurements of high dissolved methane 2 concentrations in hydraterich ocean sediments  

E-Print Network (OSTI)

sediments 3 Xin Zhang,1,2 Keith C. Hester,1,3 William Ussler,1 Peter M. Walz,1 Edward T. Peltzer,1 4 XX Month 2011. 6 [1] Ocean sediment dissolved CH4 concentrations are of 7 interest for possible dissolved 28 methane concentrations in hydraterich ocean sediments, Geophys. 29 Res. Lett., 38, LXXXXX, doi

Tian, Weidong

128

Electrolysed palladium has the potential to increase methane production by a mixed rumen population in vitro  

E-Print Network (OSTI)

Electrolysed palladium has the potential to increase methane production by a mixed rumen population the proportion of protozoa with attached methanogens decreased, however no estimate of CH4 production under were re-filled with H2:CO2, sealed with butyl rubber stoppers and incubated at 39�C with shaking

Paris-Sud XI, Université de

129

Dynamics of Planetary Atmospheres  

E-Print Network (OSTI)

pressure (bars) N2 82%; Ar 12%; CH4 6%CO2 96.5%; N2 3.5%Atmospheric composition 26177Orbital inclination (1992) orbiter ­ Winds from cloud-tracking and probe drifts ­ IR temperatures, solar-fixed tides, polar-Huygens mission (from 2005) ­ Doppler wind descent profile ­ IR temperature and composition maps ­ Visible, IR

Read, Peter L.

130

Das Methan  

Science Journals Connector (OSTI)

Bei Einwirkung von Salzsure auf Aluminiumkarbid entwickelt sich ein farbloses Gas, welches, angezndet, mit schwach leuchtender Flamme brennt: Es ist Methan.

A. Lipp

1928-01-01T23:59:59.000Z

131

Adsorption of CH4?CF4 Mixtures in Silicalite:? Simulation, Experiment, and Theory  

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total loading, the diffusivities of both components decrease as the fraction of the larger, less-mobile CF4 in the system is increased. ... The simulations predict preferential adsorption of CF4 in the straight channels and methane in the zigzag channels. ... Diffusion of tetrafluoromethane (CF4) in single-walled aluminosilicate nanotubes was studied by means of pulsed field gradient (PFG) NMR and molecular dynamics (MD) simulations. ...

Matthias Heuchel; Randall Q. Snurr; Eckhard Buss

1997-12-10T23:59:59.000Z

132

Transport Diffusivities of CH4, CF4, He, Ne, Ar, Xe, and SF6 in Silicalite from Atomistic Simulations  

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We have used atomistic simulations to examine the adsorption isotherms, self diffusivity, and transport diffusivity of seven light gases, CH4, CF4, He, Ne, Ar, Xe, and SF6, adsorbed as single-components in silicalite at room temperature. By using ...

Anastasios I. Skoulidas; David S. Sholl

2002-04-23T23:59:59.000Z

133

The Effect of the Electric Pulse Polarity on CO2 Reforming of CH4 Using Dielectric Barrier Discharge  

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For the CO2 reformation of CH4 using a plasma process to produce synthesis gas, various kinds of electric sources were used such as ac and dc corona discharges,1-4?glow discharge,5-7?or dielectric-barrier discharge. ... Its charge limits the voltage applied to the gas avoiding the transition to arc. ...

Hwaung Lee; Chung-Hun Lee; Jae-Wook Choi; Hyung Keun Song

2006-11-08T23:59:59.000Z

134

O2, CH4 and CO2 gas retentions by acid smectites before and after thermal treatment  

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Acid smectites in natural condition and after thermal treatment up to 900 C were studied for their O2, CH4 and CO2 gas retentions at 25 C and 1 kg/cm2. Two smectites, one dioctahedral and one trioctahedral, wer...

C. Volzone; J. Ortiga

135

cwebch3 ICON cweb_ch3.ico cwebch4 ICON cweb_ch4.ico cwebs3 ...  

E-Print Network (OSTI)

cwebch3 ICON cweb_ch3.ico cwebch4 ICON cweb_ch4.ico cwebs3 ICON cweb_s3.ico cwebs4 ICON cweb_s4.ico dvi3 ICON dvi3.ico dvi4 ICON dvi4.ico gf3...

136

Single-QCL-based absorption sensor for simultaneous trace-gas detection of CH4 and N2O  

E-Print Network (OSTI)

compact multipass gas cell (MGC). This sensor uses a thermoelectrically cooled, continuous wave­8]. A compact mid-infrared absorption spectrometer for N2O and CH4 was developed using thermoelectrically cooled.04 cm-1 ) and N2O (1274.61 cm-1 ) lines at a 1 Hz repetition rate. Wavelength modulation spec- troscopy

137

Separation of CO2 from CH4 Using Mixed-Ligand Metal-Organic Youn-Sang Bae,  

E-Print Network (OSTI)

and landfill gas, where methane is the major component. The presence of CO2 reduces the energy content

138

Synthesis, characterization and properties of anti-sintering nickel incorporated MCM-41 methanation catalysts  

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Abstract Several nickel incorporated MCM-41 catalysts with a nickel molar content from 1% to 10% were prepared by a hydrothermal synthesis method, and investigated for their catalytic performances for the production of substitute natural gas (SNG) from syngas methanation in a continuous flow fixed-bed reactor. The catalysts were characterized by FTIR, ICP, XRD, H2-TPR, TGDTA and TEM, and the results showed that the mesoporous structure of MCM-41 still maintained well when the incorporated Ni molar content was up to 10%. The NiM catalyst prepared by the hydrothermal synthesis method with a nickel molar content of 10% showed the best catalytic activity with a high CO conversion of almost 100%, and a CH4 yield of 95.7% at 350C with 3:1 molar ratio of H2 to CO under 1.0MPa and 12000ml/h/g. Compared with the 10%Ni/M catalyst prepared by the impregnation method, the 10%NiM catalyst showed a higher resistance to sintering and no decrease in catalytic activity after calcination at 700C for 2h. In the 100h stability test under atmospheric pressure, the CO conversion rate and the CH4 yield obtained on 10%NiM catalyst maintained at about 100% and 82%, respectively, suggesting an excellent catalytic stability of this catalyst. The results of XRD, H2-TPR and TGDTA showed that there was a strong interaction between the Ni species and the support, which inhibited the catalyst sintering. And the amount of coke formed on the spent 10%NiM catalyst in the stability test was 3.0wt%. The coke formation was relatively easily to remove by calcination because the deposited carbon had a small particle size and uniform dispersion on the catalyst.

Jiaying Zhang; Zhong Xin; Xin Meng; Miao Tao

2013-01-01T23:59:59.000Z

139

NETL: Methane Hydrates - DOE/NETL Projects - Properties of Hydrate-Bearing  

NLE Websites -- All DOE Office Websites (Extended Search)

Properties of Hydrate-Bearing Sediments Subjected to Changing Gas Compositions Last Reviewed 12/11/2013 Properties of Hydrate-Bearing Sediments Subjected to Changing Gas Compositions Last Reviewed 12/11/2013 ESD12-011 Goal The objective of this research is to measure physical, chemical, mechanical, and hydrologic property changes in methane hydrate-bearing sediments subjected to injection of carbon dioxide and nitrogen. Performer Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA 94720 Background A number of studies have investigated the impact of injecting carbon dioxide (CO2) and CO2-nitrogen (N2) mixtures into methane hydrate for the purpose of sequestering CO2 and releasing methane (CH4), and review articles have been published summarizing the literature. Most of these studies have investigated the fundamental physical/chemical nature of the exchange of CO2 and/or N2 with CH4 in the clathrate. These studies have

140

Production of Syngas by Direct Catalytic Oxidation of Methane  

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...DESORPTION AT HIGH-TEMPERATURES...of abundant natural gas into liquid...a 50-mI high-pressure Autoclave...atmospheric pressure, and the...with very high CH4 yields...Contact times of gases within the...catalytic combustors and reactors...

D. A. Hickman; L. D. Schmidt

1993-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Current status and development of membranes for CO2/CH4 separation: A review  

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Carbon dioxide (CO2) is a greenhouse gas found primarily as a main combustion product of fossil fuel as well as a component in natural gas, biogas and landfill gas. The interest to remove CO2 from those gas streams to obtain fuel with enhanced energy content and prevent corrosion problems in the gas transportation system, in addition to CO2 implications to the climate change, has driven the development of CO2 separation process technology. One type of technology which has experienced substantial growth, breakthroughs and advances during past decades is membrane-based technology. The attractive features offered by this technology include high energy efficiency, simplicity in design and construction of membrane modules and environmental compatibility. The objective of this review is to overview the different types of membranes available for use including their working principles, current status and development which form the primary determinants of separation performance and efficiency. The emphasis is toward CO2/CH4 separation, considering its substantial and direct relevance to the gas industry. To this end, discussion is made to cover polymeric gas permeation membranes; CO2-selective facilitated transport membranes, hollow fiber gasliquid membrane contactors, inorganic membranes and mixed matrix membranes. The market for CO2 separation is currently dominated by polymeric membranes due to their relatively low manufacturing cost and processing ability into flat sheet and hollow fiber configurations as well as well-documented research studies. While there have been immensely successful membrane preparation and development techniques with consequential remarkable performance for each type of membrane. Each type of membrane brings associated advantages and drawbacks related to the characteristic transport mechanism for specific application conditions. Inorganic membranes, for example, are very suitable for high temperature CO2 separation in excess of 400C while all other membranes can be applied at lower temperatures. The recent emergence of mixed matrix membranes has allowed the innovative approach to combine the advantages offered by inorganic and polymeric materials.

Yuan Zhang; Jaka Sunarso; Shaomin Liu; Rong Wang

2013-01-01T23:59:59.000Z

142

Highly stable Ni catalyst supported on CeZrO2 for oxy-steam reforming of methane  

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A novel catalyst, Ni/CeZrO2..., exhibits very high catalytic activity and stability even in the stoichiometric steam reforming of methane (H2O/CH4...= 1). Furthermore, when it was employed in oxy-steam reforming

Hyun-Seog Roh; Ki-Won Jun; Wen-Sheng Dong; Sang-Eon Park

2001-06-01T23:59:59.000Z

143

Formation of methane on Mars by fluid-rock interaction in the crust James R. Lyons,1  

E-Print Network (OSTI)

alteration of basaltic crust by carbon-bearing hydrothermal fluid can produce the required CH4 flux of 1 ? km intruded during the past 104 years is capable of driving the alteration, if all carbon is supplied and hydrothermal alteration on Mars. Citation: Lyons, J. R., C. Manning, and F. Nimmo (2005), Formation of methane

Nimmo, Francis

144

Applied reaction dynamics: Efficient synthesis gas production via single collision partial oxidation of methane to CO on Rh,,111...  

E-Print Network (OSTI)

of the incident beam's translational energy, and approaches unity for energies greater than 1.3 eV. Comparison for methanol synthesis. One method is the direct partial oxidation of methane, CH4 + 1/2 O2 CO + 2H2. 1 This process has been extensively studied using high surface area supported Rh catalysts in flow reactors

Sibener, Steven

145

Na2WO4/CoMn/SiO2 Catalyst for the Simultaneous Production of Ethylene and Syngas from CH4  

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Na2WO4/CoMn/SiO2...catalyst was prepared and used for the simultaneous production of ethylene and syngas from CH4. A CH4 conversion of 38% and a yield of 21% for (C2H4+CO), with a C2H4/CO/H2 ratio of 1/0.7/0.7...

Jingjing Wu; Song Qin; Changwei Hu

2007-10-01T23:59:59.000Z

146

The Photo-Chemistry of Some Minor Constituents of the Earth's Atmosphere (CO2, CO, CH4, N2O)  

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......Monthly Notices The Photo-Chemistry of Some Minor Constituents...the various forms of combustion taking place on the Earth...date from oil wells and coal mines appears to be less...Monthly Notices THE PHOTO-CHEMISTRY OF SOME MINOR CONSTITUENTS...date from oil wells and coal mines appears to be less......

D. R. Bates; Agnes E. Witherspoon

1952-05-01T23:59:59.000Z

147

The Photo-Chemistry of Some Minor Constituents of the Earth's Atmosphere (CO2, CO, CH4, N2O)  

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......research-article Articles The Photo-Chemistry of Some Minor Constituents of the Earth's...is estimated that the various forms of combustion taking place on the Earth would provide...The yield to date from oil wells and coal mines appears to be less than the amount......

D. R. Bates; Agnes E. Witherspoon

1952-02-01T23:59:59.000Z

148

JASPERSE CHEM 350 TEST 2 VERSION 1 Ch. 4 The Study of Chemical Reactions; Ch. 5 Stereochemistry  

E-Print Network (OSTI)

nucleophile that you could use to make the following by SN2. (3 points) OCH2CH3 3. For the structure shown, (3JASPERSE CHEM 350 TEST 2 VERSION 1 Ch. 4 The Study of Chemical Reactions; Ch. 5 Stereochemistry Ch of the following is true regarding an SN1 reaction? a. It would be faster at 25° than 50° b. It would be faster

Jasperse, Craig P.

149

Capture and Use of Coal Mine Ventilation-Air Methane  

NLE Websites -- All DOE Office Websites (Extended Search)

Capture and use of Coal Mine Capture and use of Coal Mine Ventilation - air Methane Background Methane emissions from coal mines represent about 10 percent of the U.S. anthropogenic methane released to the atmosphere. Methane-the second most important non-water greenhouse gas-is 21 times as powerful as carbon dioxide (CO 2 ) in its global warming potential. Ventilation-air methane (VAM)-the exhaust air from underground coal mines-is the largest source of coal mine methane, accounting for about half of the methane emitted from coal mines in the United States. Unfortunately, because of the low methane concentration (0.3-1.5 percent) in ventilation air, its beneficial use is difficult. However, oxidizing the methane to CO 2 and water reduces its global warming potential by 87 percent. A thermal

150

Photon production from collisions of 100350-keV positive ions with CO, CF4, and CH4  

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Various photon emissions from collisions of H+, H2+, and He+ in the 100350-keV energy range with targets of CO, CF4, and CH4 were studied. The wavelength range of the investigation ran from 2000 to 7000 . Photon-emission cross sections were measured for all significant features. The cross-section data were compared to the Bethe-Born theory through the use of Fano plots. The results show that the theory could be applicable in the case of the CO target, but is probably not applicable to the tetrahedral molecular targets as the emissions are from dissociated atoms.

Eric J. Freeman; Elisabeth L. Bryan; Michael N. Monce

1992-07-01T23:59:59.000Z

151

Wetland (peat) Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Wetland (peat) Carbon Cycle Methane (CH4) is an important greenhouse gas, twenty times more potent than CO2, but atmospheric concentrations of CH4 under future climate change are...

152

E-Print Network 3.0 - atmospheric gas annual Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

reactive trace gas with a current lifetime in the atmosphere of w... gas'. The greenhouse effect of one molecule of CH4 ... Source: USGS Western Region Coastal and Marine...

153

RETRACTED ARTICLE: Effect of Gd2O3 over Ni/SiO2 on syngas production via methane autothermal reforming  

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Gd2O3-promoted Ni/SiO2 catalysts exhibited higher activity and selectivity than Ni/SiO2 in methane autothermal reforming. The results of the temperature-programmed surface reaction of CH4 indicated that Gd2O3 mig...

Jian-Zhong Guo; Zhao-Yin Hou

2010-10-01T23:59:59.000Z

154

CF4 Glow Discharge Modification of CH4 Plasma Polymer Layers Deposited onto Asymmetric Polysulfone Gas Separation Membranes  

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Post CF4 glow discharge modification of methane plasma polymer layers deposited onto asymmetric polysulfone membranes has been investigated by XPS, FTIR, AFM, and gas permeability measurements. Oxygen and nitrogen gas permeability and permselectivity ...

J. Hopkins; J. P. S. Badyal

1996-08-21T23:59:59.000Z

155

CH4 reforming with CO2 for syngas production over nickel catalysts supported on mesoporous nanostructured ?-Al2O3  

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Nanostructured ?-Al2O3 with high surface area and mesoporous structure was synthesized by sol-gel method and employed as catalyst support for nickel catalysts in methane reforming with carbon dioxide. The prepare...

Nasrollah Majidian; Narges Habibi; Mehran Rezaei

2014-07-01T23:59:59.000Z

156

Observation of CH4 and other Non-CO2 Green House Gas Emissions from California  

SciTech Connect

In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

2009-01-09T23:59:59.000Z

157

Techno-Economic Analysis of Bioconversion of Methane into Biofuel and Biochemical (Poster)  

SciTech Connect

In light of the relatively low price of natural gas and increasing demands of liquid transportation fuels and high-value chemicals, attention has begun to turn to novel biocatalyst for conversion of methane (CH4) into biofuels and biochemicals [1]. A techno-economic analysis (TEA) was performed for an integrated biorefinery process using biological conversion of methane, such as carbon yield, process efficiency, productivity (both lipid and acid), natural gas and other raw material prices, etc. This analysis is aimed to identify research challenges as well provide guidance for technology development.

Fei, Q.; Tao, L.; Pienkos, P .T.; Guarnieri, M.; Palou-Rivera, I.

2014-10-01T23:59:59.000Z

158

Matrix Shrinkage and Swelling Effects on Economics of Enhanced Coalbed Methane Production and CO2 Sequestration in Coal  

SciTech Connect

Increases in CO2 levels in the atmosphere and their contributions to global climate change have been a major concern. It has been shown that CO2 injection can enhance the methane recovery from coal. Accordingly, sequestration costs can be partially offset by the value added product. Indeed, coal seam sequestration may be profitable, particularly with the introduction of incentives for CO2 sequestration. Hence, carbon dioxide sequestration in unmineable coals is a very attractive option, not only for environmental reasons, but also for possible economic benefits. Darcy flow through cleats is an important transport mechanism in coal. Cleat compression and permeability changes due to gas sorption desorption, changes of effective stress, and matrix swelling and shrinkage introduce a high level of complexity into the feasibility of a coal sequestration project. The economic effects of carbon dioxide-induced swelling on permeabilities and injectivities has received little (if any) detailed attention. Carbon dioxide and methane have different swelling effects on coal. In this work, the Palmer-Mansoori model for coal shrinkage and permeability increases during primary methane production was re-written to also account for coal swelling caused by carbon dioxide sorption. The generalized model was added to PSU-COALCOMP, a dual porosity reservoir simulator for primary and enhanced coalbed methane production. A standard five-spot of vertical wells and representative coal properties for Appalachian coals were used.[1] Simulations and sensitivity analyses were performed with the modified simulator for nine different parameters, including coal seam and operational parameters and economic criteria. The coal properties and operating parameters that were varied included Youngs modulus, Poissons ratio, the cleat porosity, and the injection pressure. The economic variables included CH4 price, CO2 cost, CO2 credit, water disposal cost, and interest rate. Net present value analyses of the simulation results included profits due to methane production, and potential incentives for CO2 sequestered. This work shows that for some coal-property values, the compressibility and cleat porosity of coal may be more important than more purely economic criteria.

Gorucu, F.B.; Jikich, S.A.; Bromhal, G.S.; Sams, W.N.; Ertekin, T.; Smith, D.H.

2005-09-01T23:59:59.000Z

159

Mixing Ratios of CO, CO2, CH4, and Isotope Ratios of Associated 13C, 18O,  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Samples, Niwot Ridge, Colorado Air Samples, Niwot Ridge, Colorado Mixing Ratios of CO, CO2, CH4, and Isotope Ratios of Associated 13C, 18O, and 2H in Air Samples from Niwot Ridge, Colorado, and Montaña de Oro, California, USA (January 2004) image Abstract graphics Graphics data Data Investigator Stanley C. Tyler Department of Earth System Science University of California Irvine, CA DOI: 10.3334/CDIAC/atg.db1022 Description and Methods Air samples from Niwot Ridge, Colorado (41°N, 105°W) and Montaña de Oro, CA (35°N, 121°W) have been collected at approximately semi-monthly to monthly intervals since the mid 1990s. The beginning dates for each gas and isotope analyzed are as follows: GASLAB Flask Sampling Network Data Available (April 2003) Gas or isotope Niwot Ridge Montaña de Oro

160

An Intercomparison of Ground-Based Solar FTIR Measurements of Atmospheric Gases at Eureka, Canada  

Science Journals Connector (OSTI)

The authors report the results of an intercomparison of vertical column amounts of hydrogen chloride (HCl), hydrogen fluoride (HF), nitrous oxide (N2O), nitric acid (HNO3), methane (CH4), ozone (O3), carbon dioxide (CO2), and nitrogen (N2) ...

C. Paton-Walsh; R. L. Mittermeier; W. Bell; H. Fast; N. B. Jones; A. Meier

2008-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Measurements and analysis of CO and O2 emissions in CH4/CO2/O2 flames  

E-Print Network (OSTI)

or deep saline aquifiers, or used for enhanced oil recovery (EOR) or enhanced coal bed methane recovery the key tradeoffs associated with optimizing these systems, as well as the dependence of emissions concepts (e.g., Graz [4] or Matiant [5] cycles) and integra- tion with gasification processes for coal

Lieuwen, Timothy C.

162

Methane oxidation by an extremely acidophilic bacterium of the phylum Verrucomicrobia  

Science Journals Connector (OSTI)

... primarily through the microbial degradation of organic matter, but abiogenic methane emitted from seeps and geothermal areas is also a major contribution to the atmospheric budget, estimated at 4575? ... at 4575?Tg annually. Hells Gate (Tikitere), New Zealand, is a geothermal area rich in abiogenic methane. We studied methane oxidation in an area of woody ...

Peter F. Dunfield; Anton Yuryev; Pavel Senin; Angela V. Smirnova; Matthew B. Stott; Shaobin Hou; Binh Ly; Jimmy H. Saw; Zhemin Zhou; Yan Ren; Jianmei Wang; Bruce W. Mountain; Michelle A. Crowe; Tina M. Weatherby; Paul L. E. Bodelier; Werner Liesack; Lu Feng; Lei Wang; Maqsudul Alam

2007-11-14T23:59:59.000Z

163

Physical properties of selected block Argonne Premium bituminous coal related to CO2, CH4, and N2 adsorption  

Science Journals Connector (OSTI)

CO2, CH4, and N2 adsorption and gas-induced swelling were quantified for block Blind Canyon, Pittsburgh #8 and Pocahontas Argonne Premium coals that were dried and structurally relaxed at 75C in vacuum. Strain measurements were made perpendicular and parallel to the bedding plane on ~7נ7נ7mm3 coal blocks and gravimetric sorption measurements were obtained simultaneously on companion coal blocks exposed to the same gaseous environment. The adsorption amount and strain were determined after equilibration at P?1.8MPa. There is a strong non-linear correlation between strain and the quantity of gas adsorbed and the results for all gases and coals studied follow a common pattern. The dependence of the coal matrix shrinkage/swelling coefficient (Cgc) on the type and quantity of gas adsorbed is seen by plotting the ratio between the strain and the adsorbate concentration against the adsorbate concentration. In general, Cgc increases with increasing adsorbate concentration over the range of ~0.1 to 1.4mmol/g. Results from the dried block coals are compared to CO2 experiments using native coals with an inherent level of moisture as received. The amount of CO2 adsorbed using native coals (assuming no displacement of H2O by CO2) is significantly less than the dried coals. The gas-induced strain (S) and adsorption amount (M) were measured as a function of time following step changes in CO2, CH4, and N2 pressure from vacuum to 1.8MPa. An empirical diffusion equation was applied to the kinetic data to obtain the exponent (n) for time dependence for each experiment. The data for all coals were pooled and the exponent (n) evaluated using an ANOVA statistical analysis method. Values for (n) near 0.5 were found to be independent on the coal, the gas or type of measurement (e.g., parallel strain, perpendicular strain, and gas uptake). These data support the use of a Fickian diffusion model framework for kinetic analysis. The kinetic constant k was determined using a unipore diffusion model for each experiment and the data were pooled for ANOVA analysis. For dry coal, statistically significant differences for k were found for the gases (CO2>N2>CH4) and coals (Pocahontas>Blind Canyon>Pittsburgh #8) but not for the method of the kinetic measurement (e.g., strain or gas uptake). For Blind Canyon and Pittsburgh #8 coal, the rate of CO2 adsorption and gas-induced strain for dry coal was significantly greater than that of the corresponding native coal. For Pocahontas coal the rates of CO2 adsorption and gas-induced strain for dry and native coal were indistinguishable and may be related to its low native moisture and minimal amount of created porosity upon drying.

S.R. Kelemen; L.M. Kwiatek

2009-01-01T23:59:59.000Z

164

Selectivity of the steam reforming of methane over metallic catalysts  

Science Journals Connector (OSTI)

The activity and selectivity of the methane-steam reaction has been studied in a gradientless reactor at atmospheric pressure and 700850 C. Differences were found in the course of the reaction on Pd relative...

T. Borowiecki; J. Barcicki

1979-01-01T23:59:59.000Z

165

Chapter 14 - Coal bed methane  

Science Journals Connector (OSTI)

Publisher Summary Methane adsorbed to the surface of coal is a very old issue with some new commercial ramifications. This explosive gas has made underground coal mines dangerous both from the risk of explosion and the possibility of an oxygen-poor atmosphere that wouldn't support life. The miner's main concern with coal bed methane (CBM) has been how to get rid of it. Techniques to deal with CBM in mines have ranged from the classic canary in a cage to detect an oxygen-poor atmosphere to huge ventilation fans to force the replacement of a methane-rich environment with outside air, to drilling CBM wells in front of the coal face to try to degas the coal prior to exposing the mine to the CBM. All these techniques have met with some amount of success. None of the techniques to prevent CBM from fouling the air in an underground mine has been totally successful. With the CBM's unique method of gas storage, the preponderance of the gas is available only to very low coalface pressures. The coalface pressure is set by a combination of flowing wellhead pressure and the hydrostatic head exerted by standing liquid within the well bore. Effective compression strategies can lower the wellhead pressure to very low values. Effective deliquification techniques can reduce or remove the backpressure caused by accumulated liquid. CBM's economic impact is briefly explained in this chapter.

James F. Lea; Henry V. Nickens; Mike R. Wells

2008-01-01T23:59:59.000Z

166

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Interrelation of Global Climate and the Response of Oceanic Hydrate Accumulations Last Reviewed 8/21/2013 Interrelation of Global Climate and the Response of Oceanic Hydrate Accumulations Last Reviewed 8/21/2013 Field Work Proposals: ESD07-014 (LBNL) and 08FE-003 (LANL) Project Goal The primary objectives of this project are to: 1) investigate the effect of rising water temperatures on the stability of oceanic hydrate accumulations, 2) estimate the global quantity of hydrate-originating carbon that could reach the upper atmosphere as CH4 or CO2 thus affecting global climate, 3) quantify the interrelationship between global climate and the amount of hydrate-derived carbon reaching the upper atmosphere focusing on the potential link between hydrate dissociation and cascading global warming and 4) test the discharge phase of the Clathrate Gun Hypothesis which stipulates large-scale hydrate dissociation and gas

167

Cobalt recovery with simultaneous methane and acetate production in biocathode microbial electrolysis cells  

Science Journals Connector (OSTI)

Abstract Cobalt was successfully recovered with simultaneous methane and acetate production in biocathode microbial electrolysis cells (MECs). At an applied voltage of 0.2V, 88.1% of Co(II) was reduced with concomitantly achieving yields of 0.2660.001mol Co/mol COD, 0.1130.000mol CH4/mol COD, and 0.1030.003mol acetate/mol COD. Energy efficiencies relative to the electrical input were 21.20.05% (Co), 100.93.2% (CH4), and 1.00.01% (acetate), and overall energy efficiencies relative to both electrical input and energy of anodic substrate averaged 3.70.05% (Co), 17.51.4% (CH4) and 0.50.001% (acetate). Applied voltage, initial Co(II) concentration, and temperature affected system performance. The apparent activation energy (Ea) obtained in \\{MECs\\} was 26.7kJ/mol compared to 40.5kJ/mol in the abiotic controls, highlighting the importance of cathodic microbial catalysis to Co(II) reduction. Dominant microorganisms most similar to Geobacter psychrophilus, Acidovorax ebreus, Diaphorobacter oryzae, Pedobacter duraquae, and Prolixibacter bellariivorans were observed on the biocathodes. This study provides a new process for cobalt recovery and recycle of spent lithium ion batteries with simultaneous methane and acetate production in the biocathode MECs.

Liping Huang; Linjie Jiang; Qiang Wang; Xie Quan; Jinhui Yang; Lijie Chen

2014-01-01T23:59:59.000Z

168

Correlation Effects in Diffusion of CH4/CF4 Mixtures in MFI Zeolite. A Study Linking MD Simulations with the Maxwell?Stefan Formulation  

Science Journals Connector (OSTI)

Correlation effects in diffusion of CH4 and CF4 in MFI zeolite have been investigated with the help of molecular dynamics (MD) simulations and the Maxwell?Stefan (M?S) formulation. For single-component diffusion, the correlations are captured by the self-...

Anastasios I. Skoulidas; David S. Sholl; Rajamani Krishna

2003-08-08T23:59:59.000Z

169

ProClim-Flash | No 57, June 201318 Figure 1: Swiss CH4 fluxes from (a) anthropogenic (agriculture, energy, waste) and (b) natural contributors (wetlands, lakes and  

E-Print Network (OSTI)

April 2013 under the United Nations Framework Convention on Climate Change and under the Kyoto Protocol layers representing CH4 emissions from wastewater treatment and natural sources and sinks (Figure 1b by the CCES projects ENHANCE, www.cces.ethz.ch/ projects/sulu/ENHANCE, and BioChange, www.cces.ethz.ch/projects/clench/BioChange

170

Methane-steam reforming  

SciTech Connect

A discussion covers steam reforming developments to the 1950's; the kinetics of methane-steam reforming, of the water-gas shift during methane-steam reforming, and of the carbon formation during methane-steam reforming, as approached by Akers and Camp.

Van Hook, J.P.

1980-01-01T23:59:59.000Z

171

NETL: Methane Hydrates - Methane Hydrate Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Reference Shelf Reference Shelf The Methane Hydrate Reference Shelf was created to provide a repository for information collected from projects funded as part of the National Methane Hydrate R&D Program. As output from the projects is received, it will be reviewed and then placed onto the reference shelf to be available to other methane hydrate researchers. Projects: DOE/NETL Projects : These pages contain detailed information on methane hydrate projects funded through the National Energy Technology Laboratory. Publications: Newsletter | Bibliography | Software | Reports | Program Publications | Photo Gallery Newsletter: Fire in the Ice: A publication highlighting the National Methane Hydrate R&D Program Bibliography: "Project Reports Bibliography"[PDF]: The bibliography lists publications resulting from DOE/NETL-sponsored

172

Detecting industrial pollution in the atmospheres of earth-like exoplanets  

E-Print Network (OSTI)

Detecting biomarkers, such as molecular oxygen, in the atmospheres of transiting exoplanets has been a major focus in the search for alien life. We point out that in addition to these generic indicators, anthropogenic pollution could be used as a novel biomarker for intelligent life. To this end, we identify pollutants in the Earth's atmosphere that have significant absorption features in the spectral range covered by the James Webb Space Telescope (JWST). We estimate that for an Earth-mass planet in the habitable zone of a white dwarf, methane (CH4) and nitrous oxide (N2O) can be detected at earth-like concentrations with an integration time of ~1.5 hrs and 12 hrs respectively. Detecting pollutants that are produced nearly exclusively by anthropogenic activities will be significantly more challenging. Of these pollutants, we focus on tetrafluoromethane (CF4) and trichlorofluoromethane (CCl3F), which will be the easiest to detect. We estimate that ~1.5 days (~3 days) of total integration time will be sufficie...

Lin, Henry W; Loeb, Abraham

2014-01-01T23:59:59.000Z

173

Water production in enhanced coalbed methane operations  

Science Journals Connector (OSTI)

Coalbed methane (CBM) formations provides a considerable amount of the US natural gas production and have the potential of storing significant amounts of carbon dioxide (CO2) through enhanced gas recovery operations. Enhanced coalbed methane (ECBM) recovery by injection of CO2 or a mixture of CO2 and nitrogen (N2) has been proven to recover additional natural gas resources. However, since coalbeds are normally saturated with water and can be in communication with an aquifer, a large amount of water is often co-produced during the natural gas extraction. The conventional approach for CBM production relies on the reduction of the gas partial pressure in the coal seam. This can be accomplished by either pumping the formation water to the surface and/or by injecting gases such as N2 and CO2. Disposal of the produced water is an environmental challenge as harmful impurities must be removed by appropriate purification techniques. Consequently, a reduction of water production in CBM operations is desirable. In this paper we present a numerical investigation of the potential reduction in water production during ECBM operations that are commonly used to increase methane (CH4) recovery. We use a three-dimensional coalbed model with an aquifer located at the bottom to investigate the amounts of gas and water produced in ECBM operations per volume of coal seam as a function of aquifer strength and sorption characteristics including sorption induced strain. The amount of gas/water that is produced varies significantly depending on the aquifer strength and injection gas composition. We demonstrate that injection of CO2 and/or N2 in some settings reduces the water handling problem substantially. CBM is an important worldwide energy source with a large number of formations being excellent candidates for ECBM recovery processes. Our analysis of the interplay between coal characteristics, aquifer support and the resultant behavior in terms of gas/water production provides valuable input for optimization of future planning and operations.

M. Jamshidi; K. Jessen

2012-01-01T23:59:59.000Z

174

E-Print Network 3.0 - atmospheric source observations Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Wien Collection: Geosciences 2 PLANETARY ATMOSPHERES Winter 2003 (ATMS 555ASTR 555, ESS 581) Summary: in planetary atmospheres (Earth, Venus; Mars as a case study). Methane on...

175

Enhancement of sludge reduction and methane production by removing extracellular polymeric substances from waste activated sludge  

Science Journals Connector (OSTI)

Abstract The management of waste activated sludge (WAS) recycling is a concern that affects the development of the future low-carbon society, particularly sludge reduction and biomass utilization. In this study, we investigated the effect of removing extracellular polymeric substances (EPS), which play important roles in the adhesion and flocculation of WAS, on increased sludge disintegration, thereby enhancing sludge reduction and methane production by anaerobic digestion. EPS removal from WAS by ethylenediaminetetraacetic acid (EDTA) significantly enhanced sludge reduction, i.e., 495% compared with 271% of the control at the end the digestion process. Methane production was also improved in WAS without EPS by 8881109 CH4?molg?1 dry-weight of sludge. Microbial activity was determined by denaturing gradient gel electrophoresis and real-time polymerase chain reaction, which showed that the hydrolysis and acetogenesis stages were enhanced by pretreatment with 2% EDTA, with a larger methanogenic community and better methane production.

Minh Tuan Nguyen; Nazlina Haiza Mohd Yasin; Toshiki Miyazaki; Toshinari Maeda

2014-01-01T23:59:59.000Z

176

Biogeochemical modelling of anaerobic vs. aerobic methane oxidation in a meromictic crater lake (Lake Pavin, France)  

E-Print Network (OSTI)

be considered both as an energy resource and as an atmospheric contaminant contributing to the greenhouse effect Géosciences, 1A rue de la Férolerie, 45071 Orléans Cedex 2, France Abstract Methane is a powerful greenhouse gas and its concentration in the atmosphere has increased over the past decades. Methane produced

Boyer, Edmond

177

Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report  

SciTech Connect

Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

2007-09-01T23:59:59.000Z

178

Ab Initio/RRKM Study of the Potential Energy Surface of Triplet Ethylene and Product Branching Ratios of the C(3P) + CH4 Reaction  

E-Print Network (OSTI)

Ab Initio/RRKM Study of the Potential Energy Surface of Triplet Ethylene and Product Branching originating from the collision energy (12.2 kcal/mol), the sole reaction products are C2H3 + H, where 90 potential energy surface for the C(3P) + CH4 reaction have been performed using the CCSD(T)/6-311+G(3df,2p

Nguyen, Minh Tho

179

Methane Hydrate Field Program  

SciTech Connect

This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. Historical Methane Hydrate Project Review Report Methane Hydrate Workshop Report Topical Report: Marine Methane Hydrate Field Research Plan Final Scientific/Technical Report

None

2013-12-31T23:59:59.000Z

180

LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL  

SciTech Connect

''Conventional'' waste landfills emit methane, a potent greenhouse gas, in quantities such that landfill methane is a major factor in global climate change. Controlled landfilling is a novel approach to manage landfills for rapid completion of total gas generation, maximizing gas capture and minimizing emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated and brought to much earlier completion by improving conditions for biological processes (principally moisture levels) in the landfill. Gas recovery efficiency approaches 100% through use of surface membrane cover over porous gas recovery layers operated at slight vacuum. A field demonstration project's results at the Yolo County Central Landfill near Davis, California are, to date, highly encouraging. Two major controlled landfilling benefits would be the reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role in reduction of US greenhouse gas emissions.

Don Augenstein

1999-01-11T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Coalbed Methane Production  

U.S. Energy Information Administration (EIA) Indexed Site

NA Not Available; W Withheld to avoid disclosure of individual company data. Notes: Coalbed Methane production data collected in conjunction with proved reserves data on Form...

182

Coalbed Methane | Department of Energy  

Energy Savers (EERE)

Coalbed Methane Coalbed Methane Coalbed methane is natural gas found in coal deposits. It was once considered a nuisance and mine safety hazard, but today has become a valuable...

183

Estimating the Carbon Sequestration Capacity of Shale Formations Using Methane Production Rates  

Science Journals Connector (OSTI)

Estimating the Carbon Sequestration Capacity of Shale Formations Using Methane Production Rates ... Even though both of these strategies have some potential to sequester CO2, the magnitude is much smaller than current or projected CO2 emissions. ... This distribution is combined with stochastic estimates for (4) the ratio of CH4 volume to CO2 volume that can sorb to the fracture surface and (5) the ratio of the gas diffusivities at the fracture surface to estimate the volume of CO2 that could be sequestered in these wells. ...

Zhiyuan Tao; Andres Clarens

2013-08-29T23:59:59.000Z

184

EOS7C Version 1.0: TOUGH2 Module for Carbon Dioxide or Nitrogen inNatural Gas (Methane) Reservoirs  

SciTech Connect

EOS7C is a TOUGH2 module for multicomponent gas mixtures in the systems methane carbon dioxide (CH4-CO2) or methane-nitrogen (CH4-N2) with or without an aqueous phase and H2O vapor. EOS7C uses a cubic equation of state and an accurate solubility formulation along with a multiphase Darcy s Law to model flow and transport of gas and aqueous phase mixtures over a wide range of pressures and temperatures appropriate to subsurface geologic carbon sequestration sites and natural gas reservoirs. EOS7C models supercritical CO2 and subcritical CO2 as a non-condensible gas, hence EOS7C does not model the transition to liquid or solid CO2 conditions. The components modeled in EOS7C are water, brine, non-condensible gas, gas tracer, methane, and optional heat. The non-condensible gas (NCG) can be selected by the user to be CO2 or N2. The real gas properties module has options for Peng-Robinson, Redlich-Kwong, or Soave-Redlich-Kwong equations of state to calculate gas mixture density, enthalpy departure, and viscosity. Partitioning of the NCG and CH4 between the aqueous and gas phases is calculated using a very accurate chemical equilibrium approach. Transport of the gaseous and dissolved components is by advection and Fickian molecular diffusion. We present instructions for use and example problems to demonstrate the accuracy and practical application of EOS7C.

Oldenburg, Curtis M.; Moridis,George J.; Spycher, Nicholas; Pruess, Karsten

2004-06-29T23:59:59.000Z

185

Geochemical assessment of gaseous hydrocarbons: mixing of bacterial and thermogenic methane in the deep subsurface petroleum system, Gulf of Mexico continental slope  

E-Print Network (OSTI)

Page 12 Modelled maturity variations in g10013C of methane through butane, relative to g10013C of total source kerogen .......................................................... 29 13 Diagrams showing various processes and resulting compositional... gas contains methane (CH4) as a major constituent (70-100%), ethane (C2H6) (1-10%), lower percentages of higher hydrocarbons ?propane (C3H8), butane (C4H10), pentane (C5H12)? through hexanes (C6H14), and traces up through nonanes (C9H20) (Tissot...

Ozgul, Ercin

2004-09-30T23:59:59.000Z

186

Syngas methanation for substitute natural gas over NiMg/Al2O3 catalyst in fixed and fluidized bed reactors  

Science Journals Connector (OSTI)

Abstract A comparative study was conducted for laboratory syngas methanation over a self-made NiMg/Al2O3 catalyst to demonstrate the technical advantages of fluidized bed over fixed bed reactor. At different reaction temperatures, gas velocities and pressures, the CO conversion and selectivity to CH4 in fluidized bed were shown to be higher than in fixed bed, and much closer to the thermodynamic equilibriums. The spent catalysts from fluidized bed methanation had distinctively low and easy-oxidizing deposited carbon in comparison with that from fixed bed. The results were attributed to the bigger effective catalytic surface, better heat and mass transfer in fluidized bed reactor.

Jiao Liu; Wenlong Shen; Dianmiao Cui; Jian Yu; Fabing Su; Guangwen Xu

2013-01-01T23:59:59.000Z

187

Coalbed methane gains viability  

SciTech Connect

In recent government studies, the Department of Energy (DOE) states that coal bed methane can be produced economically by using recovery systems that maximize return on investment rather than a system to produce a single coal seam just prior to mining. DOE suggests that the cost of recovering coal bed methane can be substantially reduced by increasing well spacing and employing multizone production if possible. Created as a by-product during the formation of coal, methane frequently is trapped in coal beds and associated strata. Estimates of total US methane contained in coal beds range from 260 to 860 TCF. The Pittsburgh seam in the N. Appalachia basin has estimates of 0.6 to 4 TCF alone. With current technology, DOE thinks that approximately 300 TCF of coal bed methane can be extracted from coal beds.

Not Available

1981-08-01T23:59:59.000Z

188

Comparison of propane and methane performance and emissions in a turbocharged direct injection dual fuel engine  

SciTech Connect

With increasingly restrictive NO x and particulate matter emissions standards, the recent discovery of new natural gas reserves, and the possibility of producing propane efficiently from biomass sources, dual fueling strategies have become more attractive. This paper presents experimental results from dual fuel operation of a four-cylinder turbocharged direct injection (DI) diesel engine with propane or methane (a natural gas surrogate) as the primary fuel and diesel as the ignition source. Experiments were performed with the stock engine control unit at a constant speed of 1800 rpm, and a wide range of brake mean effective pressures (BMEPs) (2.7-11.6 bars) and percent energy substitutions (PESs) of C 3 H 8 and CH 4. Brake thermal efficiencies (BTEs) and emissions (NO x, smoke, total hydrocarbons (THCs), CO, and CO 2) were measured. Maximum PES levels of about 80-95% with CH 4 and 40-92% with C 3 H 8 were achieved. Maximum PES was limited by poor combustion efficiencies and engine misfire at low loads for both C 3 H 8 and CH 4, and the onset of knock above 9 bar BMEP for C 3 H 8. While dual fuel BTEs were lower than straight diesel BTEs at low loads, they approached diesel BTE values at high loads. For dual fuel operation, NO x and smoke reductions (from diesel values) were as high as 66-68% and 97%, respectively, but CO and THC emissions were significantly higher with increasing PES at all engine loads

Gibson, C. M.; Polk, A. C.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

2011-04-20T23:59:59.000Z

189

Global atmospheric methane: budget, changes and dangers  

Science Journals Connector (OSTI)

...In particular, wider use of heating and air-conditioning in rapidly...sectors (underground coal mines, oil and gas) and landfills by capturing...to reduce emissions from the oil and gas industry come from upgrading...the late-2009 US wellhead price of US$3 per 1000ft3), cost...

2011-01-01T23:59:59.000Z

190

The European land and inland water CO2, CO, CH4 and N2O balance between 2001 and 2005  

SciTech Connect

Globally, terrestrial ecosystems have absorbed about 30% of anthropogenic greenhouse gas emissions over the period 2000-2007 and inter-hemispheric gradients indicate that a significant fraction of terrestrial carbon sequestration must be north of the Equator. We present a compilation of the CO{sub 2}, CO, CH{sub 4} and N{sub 2}O balances of Europe following a dual constraint approach in which (1) a land-based balance derived mainly from ecosystem carbon inventories and (2) a land-based balance derived from flux measurements are compared to (3) the atmospheric data-based balance derived from inversions constrained by measurements of atmospheric GHG (greenhouse gas) concentrations. Good agreement between the GHG balances based on fluxes (1294 {+-} 545 Tg C in CO{sub 2}-eq yr{sup -1}), inventories (1299 {+-} 200 Tg C in CO{sub 2}-eq yr{sup -1}) and inversions (1210 {+-} 405 Tg C in CO{sub 2}-eq yr{sup -1}) increases our confidence that the processes underlying the European GHG budget are well understood and reasonably sampled. However, the uncertainty remains large and largely lacks formal estimates. Given that European net land to atmosphere exchanges are determined by a few dominant fluxes, the uncertainty of these key components needs to be formally estimated before efforts could be made to reduce the overall uncertainty. The net land-to-atmosphere flux is a net source for CO{sub 2}, CO, CH{sub 4} and N{sub 2}O, because the anthropogenic emissions by far exceed the biogenic sink strength. The dual-constraint approach confirmed that the European biogenic sink removes as much as 205 {+-} 72 Tg C yr{sup -1} from fossil fuel burning from the atmosphere. However, This C is being sequestered in both terrestrial and inland aquatic ecosystems. If the C-cost for ecosystem management is taken into account, the net uptake of ecosystems is estimated to decrease by 45% but still indicates substantial C-sequestration. However, when the balance is extended from CO{sub 2} towards the main GHGs, C-uptake by terrestrial and aquatic ecosystems is offset by emissions of non-CO{sub 2} GHGs. As such, the European ecosystems are unlikely to contribute to mitigating the effects of climate change.

Luyassaert, S [CEA-CNRS-UVSQ, LSCE; Abril, G [Laboratoire EPOC, CNRS; Andres, Robert Joseph [ORNL; Bastviken, D [Linkoping University; Bellassen, V [CEA-CNRS-UVSQ, LSCE; Bergamaschi, P [European Commission Joint Research Centre; Bousquet, P [CEA-CNRS-UVSQ, LSCE; Chevallier, F [CEA-CNRS-UVSQ, LSCE; Ciais, P. [LSCE/CEA, Gif-sur-Yvette, France; Corazza, M [European Commission Joint Research Centre; Dechow, R [Johann Heinrich von Thnen Institute; Erb, K-H [Alpen-Adria Universitaet Klagenfurt-Vienna-Graz; Etiope, G [Istituto Nazionale di Geofisica e Vulcanologia; Fortems-Cheiney, A [CEA-CNRS-UVSQ, LSCE; Grassi, G [European Commission Joint Research Centre; Hartmann, J [University of Hamburg; Jung, M. [Max Planck Institute for Biogeochemistry; Lathiere, J [CEA-CNRS-UVSQ, LSCE; Lohila, A [Finnish Meteorological institute; Mayorga, E [University of Washington; Moosdorf, N [University of Hamburg; Njakou, D [University of Antwerp; Otto, J [CEA-CNRS-UVSQ, LSCE; Papale, D. [University of Tuscia; Peters, W [Wageningen University and Research Centre, The Netherlands; Peylin, P [CEA-CNRS-UVSQ, LSCE; Raymond, Peter A [Yale School of Forestry and Environmental Studies; Rodenbeck, C [Max Planck Institute for Biogeochemistry; Saarnio, S [University of Eastern Finland; Schulze, E.-D. [Max Planck Institute for Biogeochemistry; Szopa, S [CEA-CNRS-UVSQ, LSCE; Thompson, R [CEA-CNRS-UVSQ, LSCE; Verkerk, P [European Forest Institute; Vuichard, N [CEA-CNRS-UVSQ, LSCE; Wang, R [Peking University; Wattenbach, M [Helmholtz Centre Potsdam GFZ German Research Centre For Geosciences; Zaehle, S [Max Planck Institute for Biogeochemistry

2012-01-01T23:59:59.000Z

191

Methane Hydrates - Methane Hydrate Graduate Fellowship  

NLE Websites -- All DOE Office Websites (Extended Search)

Future Supply and Emerging Resources Future Supply and Emerging Resources The National Methane Hydrates R&D Program - Graduate Fellowship Program Methane Hydrate Graduate Fellowship Program Jeffrey James Marlow, a graduate student in Geobiology at the California Institute of Technology, was recently selected as the 2012 recipient of the NETL-National Academy of Sciences (NAS) Methane Hydrate Research Fellowship. Please see page 15 of the March 2013 issue (Vol. 13, Issue 1) of Fire in the Ice for more information on the recipient. The Department of Energy has a long history of building synergistic relationships with research universities. Funding academic research is a "win-win-win" situation. The U.S. government is able to tap into some of the best minds available for solving national energy problems, the universities get the support they need to maintain cutting edge faculty and laboratories, and the students involved are provided with opportunities that help them along their chosen path of study, strengthening the national pool of scientists and engineers. According to Samuel Bodman, speaking about graduate research in methane hydrates, "Students are the foundation of our energy future, bringing new ideas and fresh perspectives to the energy industry. What better way to assure technology innovation than to encourage students working on the development of a resource that has the potential to tip our energy balance toward clean-burning, domestic fuels."

192

A Flux-Gradient System for Simultaneous Measurement of the CH4, CO2, and H2O Fluxes at a LakeAir Interface  

Science Journals Connector (OSTI)

This study aims to test the performance of a flux-gradient system for simultaneous measurement of the fluxes of water vapor, CO2, and CH4 at a lakeair interface. ... The K parametrization(32) has been successfully deployed for flux observations in terrestrial ecosystems,(33) but to the best of the authors knowledge, extensive testing of this method for lake systems has not yet been reported in the published literature. ... This correction procedure has been thoroughly tested by the manufacturer up to a water vapor concentration of 1 %v. ...

Wei Xiao; Shoudong Liu; Hanchao Li; Qitao Xiao; Wei Wang; Zhenghua Hu; Cheng Hu; Yunqiu Gao; Jing Shen; Xiaoyan Zhao; Mi Zhang; Xuhui Lee

2014-11-07T23:59:59.000Z

193

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3and SO2  

E-Print Network (OSTI)

3. Continued. SO 2 NO Ethene Propane n- Butane n- Heptanebetween CH 4 , ethane and propane suggest low levels ofa n/a n/a Alkanes Ethane Propane i-Butane n-Butane i-Pentane

2010-01-01T23:59:59.000Z

194

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production Southern Research Institute (SRI) Project Number: FE0012054 Project Description The focus of the project will be to develop, test, and optimize steam-reforming catalysts for converting tars, C2+ hydrocarbons, NH3, and CH4 in high-temperature and sulfur environments, increasing the ratio of hydrogen in syngas, as part of a modified, advanced gasification platform for the conversion of low-rank coals to syngas for coal-to-liquid and integrated gasification combined cycle applications. Project Details Program Background and Project Benefits Project Scope and Technology Readiness Level Accomplishments Contacts, Duration, and Cost Project Images Abstract Performer website: Southern Research Institute

195

Discussion of the Influence of CO and CH4 in CO2 Transport, Injection, and Storage for CCS Technology  

Science Journals Connector (OSTI)

The goal of CCS is to avoid the release to the atmosphere of anthropogenic CO2 generated by industrial and energy-related sources. ... (26, 28) The experiments were performed at T and P relevant to those in CO2 pipelines and in geologic storage sites (geothermic gradient = 25 K/km; hydrostatic pressure gradient = 10 MPa/km). ... assessment, which showed an energetic improvement of 0.7?-points for the CASPER model solvent system in comparison to the baseline 30wt? MEA case. ...

Sofa T. Blanco; Clara Rivas; Ramn Bravo; Javier Fernndez; Manuela Artal; Inmaculada Velasco

2014-08-20T23:59:59.000Z

196

H2O CO2 CH4-BEARING FLUID INCLUSIONS IN QUARTZ: INSIGHTS INTO THE ORIGIN AND EVOLUTION OF TWO DIFFERENT HYDROTHERMAL AU DEPOSITS FROM THE EGYPTIAN EASTERN DESERT  

E-Print Network (OSTI)

DIFFERENT HYDROTHERMAL AU DEPOSITS FROM THE EGYPTIAN EASTERN DESERT ZOHEIR, B.A.1, EL-SHAZLY, Aley K.2 and laser micro-Raman spectroscopy: (i) three phase aqueous - carbonic (H2O-CO2±CH4), (ii) two-phase carbonic (CO2±CH4±N2), and (iii) two phase, CO2-bearing, aqueous inclusions. Homogenization temperatures

El-Shazly, Aley

197

Atmos. Chem. Phys., 3, 14951508, 2003 www.atmos-chem-phys.org/acp/3/1495/ Atmospheric  

E-Print Network (OSTI)

and Physics Trace gas measurements from infrared satellite for chemistry and climate applications C. Clerbaux1 that impact on the chemical composi- tion of the atmosphere and on the climate forcing: H2O, CO2, N2O, CH4, CFCs, O3, and CO. The atmospheric abundances obtained from the analysis of IMG/ADEOS measurements

198

Methane Hydrate Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FY 2011 FY 2011 Methane Hydrate Program Report to Congress July 2012 United States Department of Energy Washington, DC 20585 Department of Energy | July 2012 FY 2011 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled U.S. Department of Energy FY 2011 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of research. Pursuant to statutory requirements, this report is being provided to the following

199

Ionisierungsspannung von Methan  

Science Journals Connector (OSTI)

In einer nher skizzierten Versuchsanordnung wird die Ionisierungsspannung von Methan zu 14,580,05 Volt, die...4?Molekel erforderliche Energie zu 15,400,05 Volt in guter bereinstimmung mit der fr den homogene...

Erich Pietsch; Gertrud Wilcke

1927-01-01T23:59:59.000Z

200

Methane Hydrate Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fiscal Year 2012 Fiscal Year 2012 Methane Hydrate Program Report to Congress August 2013 United States Department of Energy Washington, DC 20585 Department of Energy | August 2013 Fiscal Year 2012 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the actions taken to carry out methane hydrate research. I am pleased to submit the enclosed report, entitled U.S. Department of Energy Fiscal Year 2012 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Electrochemical methane sensor  

DOE Patents (OSTI)

A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

Zaromb, S.; Otagawa, T.; Stetter, J.R.

1984-08-27T23:59:59.000Z

202

Effect of bituminous coal properties on carbon dioxide and methane high pressure sorption  

Science Journals Connector (OSTI)

Abstract High pressure sorption experiments with carbon dioxide and methane were carried out at a temperature of 45C and at pressures up to 15MPa with three samples of methane-bearing, medium-rank coals in a moisture-equilibrated state using a manometric method. The samples were taken from selected positions of drill cores from exploration boreholes in the Bohemian part of the Upper Silesian Basin, and were characterized by a narrow range of degree of coalification and markedly different petrographic compositions, including a different mineral matter content. The total porosity of the coal samples was between 9% and 10%. A positive correlation was found between the equilibrium moisture in the coal samples and the total abundance of oxygen functional groups determined by FTIR. The excess sorption capacities ranged from 0.78 to 0.91mmolg?1 for CO2 and from 0.45 to 0.52mmolg?1 for CH4, and after recalculation to coal organic matter, the excess sorption capacities increased by up to 14% in the coal with the highest mineral fraction. The highest CO2/CH4 ratio was found in the sample that had the highest inertinite and liptinite content. The experimental isotherm data was fitted by modified Langmuir and DubininRadushkevich sorption isotherms. The parameters obtained by these two methods were in good agreement for carbon dioxide. It was found that the sorption capacity of the organic matter in a coal sample with prevalence of inertinite (63.0vol.%) was lower only by 14% for CO2 and by 18% for CH4 than the sorption capacity of the organic matter in a coal sample with prevalence of vitrinite (65.3vol.%). This provided confirmation that the petrographic composition of a coal has an ambiguous effect.

Zuzana Weishauptov; Old?ich P?ibyl; Ivana Skorov; Vladimr Machovi?

2015-01-01T23:59:59.000Z

203

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux and  

E-Print Network (OSTI)

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux significant sink that regulates methane flux from sediments into the oceans and atmosphere. Here we examine mesophilic to thermophilic AOM in hydro- thermal sediments recovered from the Middle Valley vent field

Girguis, Peter R.

204

Mars long has been considered a cold, dead planet.However,recent reports of methane  

E-Print Network (OSTI)

currently is being produced,since its calculated atmo- spheric lifetime of 400 years or less [Nair et al of the processes producing Martian atmospheric methane, and the places on Mars from which it arises, will have wide to form methane and water, and by the fermentation of a variety of organic substrates,including methanol

Manning, Craig

205

Aging tests of the proportional wire chambers using Ar/CF4/CH4 (74:20:6), Ar/CF4/CH4 (67:30:3), Ar/CF4/CO2 (65:30:5) mixtures for the HERA-B Muon Detector  

E-Print Network (OSTI)

The Muon Detector of the HERA-B experiment at DESY is a gaseous detector that provides muon identification in a high-rate hadronic environment. We present our studies on the properties of several fast gases, Ar/CF4/CH4 (74:20:6), Ar/CF4/CH4 (67:30:3) and Ar/CF4/CO2 (65:30:5), which have been found to fulfill muon detection requirements. The severe radiation environment of the HERA-B experiment leads to the maximum charge deposit on a wire, within the muon detector, of 200 mC/cm per year. For operation in such an environment, the main criteria for the choice of gas turned out to be stability against aging. An overview of aging results from laboratory setups and experimental detectors for binary and ternary mixtures of Ar, CH4, CF4 and CO2 is presented and the relevance of the various aging results is discussed. Since it is not clear how to extrapolate aging results from small to large areas of irradiation, the lifetime of aluminum proportional chambers was studied under various conditions. In this paper we provide evidence that aging results depend not only upon the total collected charge. It was found that the aging rate for irradiation with $Fe^{55}$ X-rays and 100 MeV $\\alpha$-particles may differ by more than two orders of magnitude.

M. Danilov; L. Laptin; I. Tichomirov; M. Titov; Yu. Zaitsev

2001-07-28T23:59:59.000Z

206

Methane Hydrate | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Methane Hydrate Methane Hydrate Types of Methane Hydrate Deposits Types of Methane Hydrate Deposits Methane hydrate is a cage-like lattice of ice inside of which are trapped molecules of methane, the chief constituent of natural gas. If methane hydrate is either warmed or depressurized, it will revert back to water and natural gas. When brought to the earth's surface, one cubic meter of gas hydrate releases 164 cubic meters of natural gas. Hydrate deposits may be several hundred meters thick and generally occur in two types of settings: under Arctic permafrost, and beneath the ocean floor. Methane that forms hydrate can be both biogenic, created by biological activity in sediments, and thermogenic, created by geological processes deeper within the earth.

207

Effect of carbon dioxide and nitrogen on the diffusivity of methane confined in nano-porous carbon aerogel  

SciTech Connect

The microscopic diffusivity of methane (CH{sub 4}) confined in nano-porous carbon aerogel was investigated as a function of added carbon dioxide (CO{sub 2}) and nitrogen (N{sub 2}) pressure using quasi-elastic neutron scattering (QENS). In the range of the external pressure of 1-2.5 MPa, the self-diffusivity of methane was found to increase with CO{sub 2} pressure and remain practically unchanged in the N{sub 2} environment. Increasing mobility of methane with CO{sub 2} pressure suggests that the adsorbed CH4 molecules become gradually replaced by CO{sub 2} on the surface of carbon aerogel pores, whereas the presence of N{sub 2} does not induce the replacement. The molecular mobility of the methane, with or without added carbon dioxide and nitrogen, is described by the unrestricted diffusion model, which is characteristic of methane compressed in small pores. On the other hand, both nitrogen and carbon dioxide molecules in carbon aerogel, when studied alone, with no methane present, follow a jump diffusion process, characteristic of the molecular mobility in the densified adsorbed layers on the surface of the aerogel pores.

Mavila Chathoth, Suresh [ORNL; He, Lilin [ORNL; Mamontov, Eugene [ORNL; Melnichenko, Yuri B [ORNL

2012-01-01T23:59:59.000Z

208

Syngas production via dry reforming of CH4 over Co- and Cu-promoted Ni/Al2O3ZrO2 nanocatalysts synthesized via sequential impregnation and solgel methods  

Science Journals Connector (OSTI)

Abstract In this study, the effect of synthesis method (impregnation and so-gel) as well as Co and Cu addition on the catalytic and physicochemical properties of Ni/Al2O3ZrO2 nanocatalyst was evaluated in dry reforming of methane. The XRD, FESEM, PSD, BET and FTIR analysis were used to characterize the nanocatalysts. Highly dispersed Ni and Zr species and no spinel production in the solgel synthesized samples were confirmed by XRD results. The FESEM images showed small and uniform nanoparticles in the solgel synthesized catalyst. Also, after Cu added to Ni/Al2O3ZrO2, the particles were more compact than others. Moreover, the promoters addition especially Co to Ni/Al2O3ZrO2 nanocatalyst improved the particles size uniformity. Particle size distribution of solgel synthesized NiCo/Al2O3ZrO2 nanocatalyst represented that the majority of the particles (nearly 95%) lies between 10 and 40nm with an average size of 27.4nm. BET analysis showed higher surface area in the solgel samples, especially when it was coupled with Co and Cu addition. The results indicated the remarkable synergetic effect of solgel method and Co addition on the surface morphology and elemental dispersion. Activity of nanocatalysts were evaluated as a function of temperature from 550 to 850C at GHSV=24l/gh, P=1atm and CH4/CO2=1. The solgel synthesized nanocatalyst showed better catalytic performance. Moreover, it was observed that, Cu and Co addition improved feed conversion, products yield and better syngas ratio. The comparison between promoters revealed that activity of Co was better than Cu. During the 1440min time on stream test at 850C, the solgel synthesized NiCo/Al2O3ZrO2 nanocatalyst exhibited the best activity compared to the other samples and produced syngas with approximately stoichiometry ratio.

Mahdi Sharifi; Mohammad Haghighi; Farhad Rahmani; Samira Karimipour

2014-01-01T23:59:59.000Z

209

Methane emission by bubbling from Gatun Lake, Panama  

SciTech Connect

We studied methane emission by bubbling from Gatun Lake, Panama, at water depths of less than 1 m to about 10 m. Gas bubbles were collected in floating traps deployed during 12- to 60-hour observation periods. Comparison of floating traps and floating chambers showed that about 98% of methane emission occurred by bubbling and only 2% occurred by diffusion. Average methane concentration of bubbles at our sites varied from 67% to 77%. Methane emission by bubbling occurred episodically, with greatest rates primarily between the hours of 0800 and 1400 LT. Events appear to be triggered by wind. The flux of methane associated with bubbling was strongly anticorrelated with water depth. Seasonal changes in water depth caused seasonal variation of methane emission. Bubble methane fluxes through the lake surface into the atmosphere measured during 24-hour intervals were least (10-200 mg m{sup -2} d{sup -1}) at deeper sites (>7 m) and greatest (300-2000 mg m{sup -2} d{sup -1}) at shallow sites (<2 m). 37 refs., 11 figs., 5 tabs.

Keller, M. [National Center for Atmospheric Research, Boulder, CO (United States)] [National Center for Atmospheric Research, Boulder, CO (United States); Stallard, R.F. [Geological Survey, Denver, CO (United States)] [Geological Survey, Denver, CO (United States)

1994-04-20T23:59:59.000Z

210

Direct Non-oxidative Methane Conversion by Non-thermal Plasma: Experimental Study  

Science Journals Connector (OSTI)

The direct non-oxidative conversion of methane to higher hydrocarbons in non-thermal plasma, namely dielectric barrier discharge and corona discharge, has been investigated experimentally at atmospheric pressure....

Yun Yang

2003-06-01T23:59:59.000Z

211

Direct Non-oxidative Methane Conversion by Non-thermal Plasma: Modeling Study  

Science Journals Connector (OSTI)

The direct non-oxidative conversion of methane to higher hydrocarbons ... dielectric barrier discharges has been investigated theoretically at atmospheric pressure. Preliminary modeling of the results is...2...hy...

Yun Yang

2003-06-01T23:59:59.000Z

212

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India  

E-Print Network (OSTI)

High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

Chatterjee, A.

213

Changing concentrations of CO, CH4, C5H8, CH3Br, CH3I, and dimethyl sulfide during the Southern Ocean Iron Enrichment Experiments  

Science Journals Connector (OSTI)

...important sink for atmospheric CH 3 Br, a result...half of the atmospheric organobromine burden...delay the recovery of stratospheric...from ocean waters is a major source of cloud condensation nuclei...above the atmospheric boundary layer...

Oliver W. Wingenter; Karl B. Haase; Peter Strutton; Gernot Friederich; Simone Meinardi; Donald R. Blake; F. Sherwood Rowland

2004-01-01T23:59:59.000Z

214

NETL: Methane Hydrates - DOE/NETL Projects - Controls On Methane Expulsion  

NLE Websites -- All DOE Office Websites (Extended Search)

Controls On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 12/24/2013 Controls On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 12/24/2013 DE-FE0010406 Goal The project goal is to predict, given characteristic climate-induced temperature change, the conditions under which gas will be expelled from existing accumulations of gas hydrate into the shallow ocean or directly to the atmosphere. When those conditions are met, the fraction of the gas accumulation that escapes and the rate of escape shall be quantified. The predictions shall be applicable in Arctic regions and in gas hydrate systems at the updip limit of the stability zone on continental margins. The behavior shall be explored in response to both longer term changes in sea level (e.g., twenty-thousand years) and shorter term due to atmospheric

215

The basics of coalbed methane  

SciTech Connect

The report is an overview of coalbed methane (CBM), also known as coal seam gas. It provides an overview of what coalbed methane is and the current status of global coalbed methane exploration and production. Topics covered in the report include: An analysis of the natural gas industry, including current and future production, consumption, and reserves; A detailed description of coalbed methane, its characteristics, and future potential; An analysis of the key business factors that are driving the increased interest in coalbed methane; An analysis of the barriers that are hindering the development of coalbed methane; An overview of the technologies used for coalbed methane production and water treatment; and Profiles of key coalbed methane producing countries. 25 figs., 5 tabs., 1 app.

NONE

2006-12-15T23:59:59.000Z

216

Electron-induced dry reforming of methane in a temperature-controlled dielectric barrier discharge reactor  

Science Journals Connector (OSTI)

Dry reforming of methane has the potential to reduce the greenhouse gases methane and carbon dioxide and to generate hydrogen-rich syngas. In reforming methane, plasma-assisted reforming processes may have advantages over catalytic processes because they are free from coking and their response time for mobile applications is quick. Although plasma-assisted reforming techniques have seen recent developments, systematic studies that clarify the roles that electron-induced chemistry and thermo-chemistry play are needed for a full understanding of the mechanisms of plasma-assisted reformation. Here, we developed a temperature-controlled coaxial dielectric barrier discharge (DBD) apparatus to investigate the relative importance of electron-induced chemistry and thermo-chemistry in dry reforming of methane. In the tested background temperature range 297773K, electron-induced chemistry, as characterized by the physical properties of micro-discharges, was found to govern the conversions of CH4 and CO2, while thermo-chemistry influenced the product selectivities because they were found to depend on the background temperature. Comparisons with results from arc-jet reformation indicated that thermo-chemistry is an efficient conversion method. Our findings may improve designs of plasma-assisted reformers by using relatively hotter plasma sources. However, detailed chemical kinetic studies are needed.

Xuming Zhang; Min Suk Cha

2013-01-01T23:59:59.000Z

217

Enhanced coalbed methane recovery  

SciTech Connect

The recovery of coalbed methane can be enhanced by injecting CO{sub 2} in the coal seam at supercritical conditions. Through an in situ adsorption/desorption process the displaced methane is produced and the adsorbed CO{sub 2} is permanently stored. This is called enhanced coalbed methane recovery (ECBM) and it is a technique under investigation as a possible approach to the geological storage of CO{sub 2} in a carbon dioxide capture and storage system. This work reviews the state of the art on fundamental and practical aspects of the technology and summarizes the results of ECBM field tests. These prove the feasibility of ECBM recovery and highlight substantial opportunities for interdisciplinary research at the interface between earth sciences and chemical engineering.

Mazzotti, M.; Pini, R.; Storti, G. [ETH, Zurich (Switzerland). Inst. of Process Engineering

2009-01-15T23:59:59.000Z

218

Studies of Reaction Kinetics of Methane Hydrate Dissocation in Porous Media  

E-Print Network (OSTI)

sand cores partially satu- rated with water, hydrate and CH 4 gas,the formation of hydrates. For the sand/water/gas/CH 4 -

Moridis, George J.; Seol, Yongkoo; Kneafsey, Timothy J.

2005-01-01T23:59:59.000Z

219

AT A GLANCE Title: Hydrogen, Methane and Nitrous oxide: Trend  

E-Print Network (OSTI)

to increases in atmospheric molecular hydrogen (H2) and reductions of fossil fuel burning emissions burning emissions have been calculated with one of the models. MAIN RESULTS Improved methane emissions (from ruminants and waste) is larger. First robust estimates of the uptake of hydrogen by

Haak, Hein

220

Metal foam-supported PdRh catalyst for steam methane reforming and its application to SOFC fuel processing  

Science Journals Connector (OSTI)

Abstract PdRh/metal foam catalyst was studied for steam methane reforming and application to SOFC fuel processing. Performance of 0.068wt% PdRh/metal foam catalyst was compared with 13wt% Ni/Al2O3 and 8wt% Ru/Al2O3 catalysts in a tubular reactor. At 1023K with GHSV 2000h?1 and S/C ratio 2.5, CH4 conversion and H2 yield were 96.7% and 3.16molper mole of CH4 input for PdRh/metal foam, better than the alumina-supported catalysts. In 200h stability test, PdRh/metal foam catalyst exhibited steady activity. PdRh/metal foam catalyst performed efficiently in a heat exchanger platform reactor to be used as prototype SOFC fuel processor: at 983K with GHSV 1200h?1 and S/C ratio 2.5, CH4 conversion was nearly the same as that in the tubular reactor, except for more H2 and CO2 yields. Used PdRh/metal foam catalyst was characterized by SEM, TEM, BET and CO chemisorption measurements, which provided evidence for thermal stability of the catalyst.

Partho Sarothi Roy; No-Kuk Park; Kiseok Kim

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Direct Aromaization of Methane  

SciTech Connect

The thermal decomposition of methane offers significant potential as a means of producing higher unsaturated and aromatic hydrocarbons when the extent of reaction is limited. Work in the literature previous to this project had shown that cooling the product and reacting gases as the reaction proceeds would significantly reduce or eliminate the formation of solid carbon or heavier (Clo+) materials. This project studied the effect and optimization of the quenching process as a means of increasing the amount of value added products during the pyrolysis of methane. A reactor was designed to rapidly quench the free-radical combustion reaction so as to maximize the yield of aromatics. The use of free-radical generators and catalysts were studied as a means of lowering the reaction temperature. A lower reaction temperature would have the benefits of more rapid quenching as well as a more feasible commercial process due to savings realized in energy and material of construction costs. It was the goal of the project to identify promising routes from methane to higher hydrocarbons based on the pyrolysis of methane.

George Marcelin

1997-01-15T23:59:59.000Z

222

Can Algae utilize Methane?  

Science Journals Connector (OSTI)

... in connexion with oil prospecting, corrosion problems and formation of a microbial sludge in jet fuel tanks?. The scope of hydrocarbon microbiology has expanded rapidly in the meantime and currently ... the growth of photosynthetic sulphur bacteria in different gaseous environments Dr Enebo isolated the green alga Chlorella from highly reducing enrichment media in which carbonate and methane provided the carbon sources ...

Our Correspondent in Microbiology

1967-07-01T23:59:59.000Z

223

Methane from Anaerobic Fermentation  

Science Journals Connector (OSTI)

...removal rate; and recycling. Many studies have...di-gestion is utilized for wastewater stabili-zation...processes are used in some wastewater treatment plants...sludge is separated for recycling from the digester effluent...percent meth-ane. Many wastewater treatment plants in...

Donald L. Klass

1984-03-09T23:59:59.000Z

224

Methane and Coal  

Science Journals Connector (OSTI)

... stored source of the energy supplies of the world ; every twenty years the world burns a volume of coal equivalent to the volume of Snowdon (a cone of base ... hole method being most in favour. This method is being applied in about twelve British pits. The amount of methane drawn off appears to depend on the movement of the ...

ALFRED EGERTON

1952-07-19T23:59:59.000Z

225

Conversion of CH4 into H2 at 300 C using Pd/MnO2 catalyst made with an effect of water oxidation  

SciTech Connect

A novel electricity-free deposition of palladium on the surface of manganese dioxide, which has a crystal structure of ramsdellite, was studied. Using the Pd deposition, a nano-particle of Pd/MnO2 was prepared, and it was used for a catalytic performance for reforming methane into hydrogen at 300 C.

Koyanaka, Hideki [Forward Science Laboratory Ltd, Oita, Japan] [Forward Science Laboratory Ltd, Oita, Japan; Takeuchi, K [Tokyo University of Science, Oshamanbe Hokkaido, Japan] [Tokyo University of Science, Oshamanbe Hokkaido, Japan; Kolesnikov, Alexander I [ORNL] [ORNL

2014-01-01T23:59:59.000Z

226

Carbon Dioxide Reforming of Methane to Syngas by Thermal Plasma  

Science Journals Connector (OSTI)

Experiments were conducted on syngas preparation from dry reforming of methane by carbon dioxide with a DC arc plasma at atmospheric pressure. In all experiments, nitrogen gas was used as the working gas for thermal plasma to generate a high-temperature jet into a horizontal tube reactor. A mixture of methane and carbon dioxide was fed vertically into the jet. In order to obtain a higher conversion rate of methane and carbon dioxide, chemical energy efficiency and fuel production efficiency, parametric screening studies were conducted, in which the volume ratio of carbon dioxide to methane in fed gases and the total flux of fed gases were taken into account. Results showed that carbon dioxide reforming of methane to syngas by thermal plasma exhibited a larger processing capacity, higher conversion of methane and carbon dioxide and higher chemical energy efficiency and fuel production efficiency. In addition, thermodynamic simulation for the reforming process was conducted. Experimental data agreed well with the thermodynamic results, indicating that high thermal efficiency can be achieved with the thermal plasma reforming process.

Sun Yanpeng (???); Nie Yong (??); Wu Angshan (???); Ji Dengxiang (???); Yu Fengwen (???); Ji Jianbing (???)

2012-01-01T23:59:59.000Z

227

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station DE-FC26-02NT41328 Goal Determine the potential impacts of gas hydrate instability in terms of the release of methane into seafloor sediments, the ocean and the atmosphere. Performers University of California, San Diego (Scripps Institution of Oceanography) - manage geochemical, hydrological and sedimentological investigations Texas A&M University - manage field monitoring program Location La Jolla, California 92093 Background This project will monitor, characterize, and quantify the rates of formation and dissociation of methane gas hydrates at and near the seafloor in the northern Gulf of Mexico, and determine linkages between formation/dissociation and physical/chemical parameters of the deposits over the course of a year. The stability and response of shallow gas hydrates to temperature and chemical perturbations will be monitored in situ, and localized seafloor and water column environmental impacts of hydrate formation and dissociation characterized. The following will be determined: 1) The equilibrium/steady state conditions for structure II methane gas hydrates at the field site,2) whether the system is in dynamic equilibrium and the local hydrology is characterized by steady state episodic fluid flow, and 3) how fluid fluxes and fluid composition work together to dynamically influence gas hydrate stability.

228

Supplemental material CH4 analyses  

E-Print Network (OSTI)

vacuum glass vessel and the air was stripped from the molten sample with He carrier gas. Water is removed from the carrier gas stream by a cooled Nafion membrane and easily condensable gases (e.g. CO2, N2O and trap extraction coupled to a gas chromatography - isotope ratio mass spectrometer (GC-IRMS)1 . Using

Fischer, Hubertus

229

Coal Bed Methane Primer  

SciTech Connect

During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

Dan Arthur; Bruce Langhus; Jon Seekins

2005-05-25T23:59:59.000Z

230

Methane-steam reforming  

SciTech Connect

The literature relating to the kinetics of methane-steam reforming involving integral and differential reactor data, porous nickel catalysts and nickel foil, and data over large ranges of temperature (500 to 1700/sup 0/F), pressure (0.01 to 50 atm), and intrinsic catalyst activities (200,000-fold) was reviewed. A simple reversible first-order kinetic expression for the steam-methane reaction appears to be applicable throughout the operable region of steam-to-carbon ratios. Internal pore diffusion limitation on the conversion rate, due to catalyst size and/or intrinsic catalyst activity and total operating pressure was underlined. S-shaped Arrhenium plots (changing activation energy) are obtained when steam reforming is conducted over a temperature range sufficient to produce intrinsic kinetics (low temperature, inactive catalyst, or small catalyst size), pore diffusional limitations, and reaction on the outside surface. Homogeneous gas-phase kinetics appear to contribute only at relatively high temperature (1400/sup 0/F). In steam reforming, the water-gas shift reaction departs from its equilibrium position, especially at low methane conversion level. A general correlation of approach to water-gas shift equilibration as a function of conversion level only was indicated. (DP) 18 figures, 6 tables.

Van Hook, J.P.

1980-01-01T23:59:59.000Z

231

13, 90179049, 2013 Stable atmospheric  

E-Print Network (OSTI)

ACPD 13, 9017­9049, 2013 Stable atmospheric methane in the 2000s I. Pison et al. Title Page Utrecht, Utrecht University, Utrecht, the Netherlands 3 SRON Netherlands Institute for Space Research, Utrecht, the Netherlands 4 Vrije Universiteit, Department of Systems Ecology, Amsterdam, the Netherlands 5

Paris-Sud XI, Université de

232

Solubility of CCl2F2, CClF3, CF4, and CH4 in Water and Seawater at 288.15-303.15 K and 101.325 kPa  

Science Journals Connector (OSTI)

Solubility of CCl2F2, CClF3, CF4, and CH4 in Water and Seawater at 288.15-303.15 ... A quasi-chemical theory implemented on the basis of molecular simulation is derived and tested for the hydrophobic hydration of CF4(aq). ...

Pirketta Scharlin; Rubin Battino

1995-01-01T23:59:59.000Z

233

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

234

Methane/nitrogen separation process  

DOE Patents (OSTI)

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

235

Bioconversion of biomass to methane  

SciTech Connect

The conversion of biomass to methane is described. The biomethane potentials of various biomass feedstocks from our laboratory and literature is summarized.

Hashimoto, A.G. [Oregon State Univ., Corvallis, OR (United States)

1995-12-01T23:59:59.000Z

236

NREL: News - NREL to Help Convert Methane to Liquid Diesel  

NLE Websites -- All DOE Office Websites (Extended Search)

113 113 NREL to Help Convert Methane to Liquid Diesel Advanced research project could lead to lower greenhouse emissions, new life for spent gas and oil wells January 3, 2013 The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) will help develop microbes that convert methane found in natural gas into liquid diesel fuel, a novel approach that if successful could reduce greenhouse gas emissions and lower dependence on foreign oil. The amount of natural gas simply flared or vented from oil wells globally is enormous - equal to one-third of the amount of petroleum used in the United States each year. And every molecule of methane vented to the atmosphere in that process has the global-warming capacity of 12 molecules of carbon dioxide.

237

Timelines for mitigating methane emissions from energy technologies  

E-Print Network (OSTI)

Energy technologies emitting differing proportions of methane and carbon dioxide vary in their relative climate impacts over time, due to the different atmospheric lifetimes of the two gases. Standard technology comparisons using the global warming potential (GWP) emissions equivalency metric do not reveal these dynamic impacts, and may not provide the information needed to assess technologies and emissions mitigation opportunities in the context of broader climate policy goals. Here we formulate a portfolio optimization model that incorporates changes in technology impacts as a radiative forcing (RF) stabilization target is approached. An optimal portfolio, maximizing allowed energy consumption while meeting the RF target, is obtained by year-wise minimization of the marginal RF impact in an intended stabilization year. The optimal portfolio calls for using certain higher methane-emitting technologies prior to an optimal switching year, followed by methane-light technologies as the stabilization year approac...

Roy, Mandira; Trancik, Jessika E

2015-01-01T23:59:59.000Z

238

Integrated process for coalbed brine and methane disposal  

SciTech Connect

This paper describes a technology and project to demonstrate and commercialize a brine disposal process for converting the brine stream of a coalbed gas producing site into clean water for agricultural use and dry solids that can be recycled for industrial consumption. The process also utilizes coalbed methane (CBM) released from coal mining for the combustion process thereby substantially reducing the potential for methane emissions to the atmosphere. The technology is ideally suited for the treatment and disposal of produced brines generated from the development of coal mines and coalbed methane resources worldwide. Over the next 10 to 15 years, market potential for brine elimination equipment and services is estimated to be in the range of $1 billion.

Byam, J.W. Jr.; Tait, J.H.; Brandt, H.

1996-12-31T23:59:59.000Z

239

Federal Offshore California Coalbed Methane Proved Reserves ...  

Gasoline and Diesel Fuel Update (EIA)

12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Federal Offshore, Pacific (California) Coalbed Methane Proved Reserves, Reserves Changes, and...

240

methane hydrate science plan-final.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

2013 Principal Authors: Consor um for Ocean Leadership and the Methane Hydrate Project Science Team December 2013 DOE Award Number: DE-FE0010195 Project Title: Methane Hydrate...

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Ohio Coalbed Methane Production (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production Ohio Coalbed Methane Proved Reserves, Reserves...

242

Florida Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production Florida Coalbed Methane Proved Reserves, Reserves...

243

Michigan Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production Michigan Coalbed Methane Proved Reserves, Reserves...

244

Enhanced Renewable Methane Production System | Argonne National...  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhanced Renewable Methane Production System Technology available for licensing: Enhanced renewable methane production system provides a low-cost process that accelerates...

245

A 25kWe low concentration methane catalytic combustion gas turbine prototype unit  

Science Journals Connector (OSTI)

Abstract Low concentration methane, emitted from various industries e.g. coal mines and landfills into atmosphere, is not only an important greenhouse gas, but also a wasted energy resource if not utilized. In the past decade, we have been developing a novel VAMCAT (ventilation air methane catalytic combustion gas turbine) technology. This turbine technology can be used to mitigate methane emissions for greenhouse gas reduction, and also to utilize the low concentration methane as an energy source. This paper presents our latest research results on the development and demonstration of a 25kWe lean burn catalytic combustion gas turbine prototype unit. Recent experimental results show that the unit can be operated with 0.8 vol% of methane in air, producing about 1921kWe of electricity output.

Shi Su; Xinxiang Yu

2014-01-01T23:59:59.000Z

246

Questions and Answers - In the chemical equation for methane gas why is  

NLE Websites -- All DOE Office Websites (Extended Search)

carbon found in all organicand inorganic matter? carbon found in all organic<br>and inorganic matter? Previous Question (Is carbon found in all organic and inorganic matter?) Questions and Answers Main Index Next Question (How do you separate tungsten from its ore?) How do you separatetungsten from its ore? In the chemical equation CH4 for methane gas why is there more hydrogen than carbon? This is a very good question, and the answer is at the heart of modern atomic physics. The nucleus is at the center of the atom, like the sun is at the center of the solar system. Electrons move around in orbits around the nucleus, like the planets around the sun. But there is an important difference: electrons can only have very special energies, which correspond to specific orbits. The orbits in the atoms are called shells, and each shell can only hold so

247

Methyl Chloride from Direct Methane Partial Oxidation: A High-Temperature Shilov-Like Catalytic System  

SciTech Connect

The intention of this study is to demonstrate and evaluate the scientific and economic feasibility of using special solvents to improve the thermal stability of Pt-catalyst in the Shilov system, such that a high reaction temperature could be achieved. The higher conversion rate (near 100%) of methyl chloride from partial oxidation of methane under the high temperature ({approx} 200 C) without significant Pt0 precipitation has been achieved. High concentration of the Cl- ion has been identified as the key for the stabilization of the Pt-catalysts. H/D exchange measurements indicated that the over oxidation will occur at the elevated temperature, developments of the effective product separation processes will be necessary in order to rationalize the industry-visible CH4 to CH3Cl conversion.

Yongchun Tang; John (Qisheng) Ma

2012-03-23T23:59:59.000Z

248

Understanding the Synergistic Catalytic Effect between La2O3 and CaO for the CH4 Lean De-NOx Reaction:? Kinetic and Mechanistic Studies  

Science Journals Connector (OSTI)

Department of Chemistry, Heterogeneous Catalysis Laboratory, University of Cyprus, P.O. ... 3-5 Methane is of particular interest as a reductant hydrocarbon species because of the large availability of natural gas, the use of the latter at gas-fired power plants (main stationary NOx polluting source), and the potential to be considered as an alternative to NH3 reductant used in industrial practice (NH3?SCR technology), which faces various problems. ... However, the likelihood for the presence of inactive but exchangeable NOx species with gaseous 15NO cannot be excluded. ...

T. Anastasiadou; L. A. Loukatzikou; C. N. Costa; A. M. Efstathiou

2005-06-28T23:59:59.000Z

249

Integrated Underground Gas Storage of CO2 and CH4 to Decarbonise the Power-to-gas-to-gas-to-power Technology  

Science Journals Connector (OSTI)

Abstract Excess energy produced from renewables can be stored and reused via the power-to-gas-to-power (PGP) technology. We present an innovative idea which represents a decarbonised extension of PGP based on a closed carbon cycle. Our show case for the cities Potsdam and Brandenburg/Havel (Germany) outlines an overall efficiency for the entire process chain of 28% with total costs of electricity of 20 eurocents/kWh. If existing locations in Europe, where natural gas storage in porous formations is performed, were to be extended by CO2 storage sites, a significant quantity of wind and solar energy could be stored economically as methane.

Michael Khn; Martin Streibel; Natalie Nakaten; Thomas Kempka

2014-01-01T23:59:59.000Z

250

CO2 conversion for syngas production in methane catalytic partial oxidation  

Science Journals Connector (OSTI)

Abstract The catalytic partial oxidation of methane (CPOM) involves the interaction among methane combustion (MC), steam reforming (SR), and dry reforming (DR), and CO2 generated from MC is utilized for syngas production in DR. To evaluate the potential of CO2 utilization in CPOM for syngas production, a numerical study is carried out where CO2 is added into the feed gas and CPOM is triggered in a rhodium-based catalyst bed. Two important parameters of CO2/O2 ratio and O2/CH4 ratio (or O/C ratio) in the feed gas are taken into account. The predictions suggest that CO2 addition plays no part in MC, but it retards SR and intensifies DR. The CO2 consumption increases with CO2/O2 ratio; however, the CO2 conversion goes down. As a whole, increasing CO2 addition enhances CO formation but reduces H2 formation. The maximum syngas production is exhibited at CO2/O2=0.2 when the O/C ratio is 1. At a fixed CO2/O2 ratio, the maximum H2 yield and CO2 consumption are located at O/C=1.8 and 1.0, respectively. However, the CO2 conversion monotonically decreases with increasing O/C ratio. Within the investigated range of CO2/O2 and O/C ratios, the H2 yield and CO2 conversion in CPOM are in the ranges of approximately 0.421.34mol(molCH4)?1 and 1041%, respectively.

Wei-Hsin Chen

2014-01-01T23:59:59.000Z

251

Coal mine methane global review  

SciTech Connect

This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

NONE

2008-07-01T23:59:59.000Z

252

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

253

Thermodynamic analysis of hydrogen production via chemical looping steam methane reforming coupled with in situ CO2 capture  

Science Journals Connector (OSTI)

Abstract In this study, a detailed thermodynamic analysis of the sorption enhanced chemical looping reforming of methane (SE-CL-SMR), using CaO and NiO as CO2 sorbent and oxygen transfer material respectively, was conducted. The effect of different parameters, such as reactor temperature, pressure, H2O/CH4 ratio, CaO/CH4 ratio and CaO/NiO ratio was investigated. Moreover, the use of different sweep gases and oxidants for the re-oxidation/calcination cycle, like pure oxygen, air, steam and CO2, was specifically addressed. Conventional steam reforming (SMR) and sorption enhanced steam reforming (SE-SMR) were also investigated for comparison reasons. The results of thermodynamic analysis show that there are significant advantages of both sorption enhanced processes compared to conventional steam reforming. Presence of CaO sorbent in the reformer leads to higher methane conversion, hydrogen purity and yield at low temperatures (?650C). Addition of the oxygen carrier, in the chemical looping reforming concept, minimizes thermal requirements of the process, and results in superior performance compared to SE-SMR and SMR processes. A negative effect from NiO addition is reduction in hydrogen production (due to the reaction of part of methane with NiO to form CO/CO2). Hydrogen yield is up to 11% lower compared to SE-SMR for a NiO/CaO ratio of 0.7. It was found that only pure O2 can be used for re-oxidation/regeneration in order to reduce the energy requirements of the SE-CL-SMR process up to 26% compared to SE-SMR and up to 55% compared to conventional SMR.

A. Antzara; E. Heracleous; D.B. Bukur; A.A. Lemonidou

2015-01-01T23:59:59.000Z

254

7.4 Landfill Methane Utilization  

Energy.gov (U.S. Department of Energy (DOE))

A chapter on Landfill Methane Utilization from the Clean Energy Strategies for Local Governments publication.

255

Chapter 8 - Methane Hydrates  

Science Journals Connector (OSTI)

Gas hydrate is a solid, naturally occurring substance consisting predominantly of methane gas and water. Recent scientific drilling programs in Japan, Canada, the United States, Korea and India have demonstrated that gas hydrate occurs broadly and in a variety of forms in shallow sediments of the outer continental shelves and in Arctic regions. Field, laboratory and numerical modelling studies conducted to date indicate that gas can be extracted from gas hydrates with existing production technologies, particularly for those deposits in which the gas hydrate exists as pore-filling grains at high saturation in sand-rich reservoirs. A series of regional resource assessments indicate that substantial volumes of gas hydrate likely exist in sand-rich deposits. Recent field programs in Japan, Canada and in the United States have demonstrated the technical viability of methane extraction from gas-hydrate-bearing sand reservoirs and have investigated a range of potential production scenarios. At present, basic reservoir depressurisation shows the greatest promise and can be conducted using primarily standard industry equipment and procedures. Depressurisation is expected to be the foundation of future production systems; additional processes, such as thermal stimulation, mechanical stimulation and chemical injection, will likely also be integrated as dictated by local geological and other conditions. An innovative carbon dioxide and methane swapping technology is also being studied as a method to produce gas from select gas hydrate deposits. In addition, substantial additional volumes of gas hydrate have been found in dense arrays of grain-displacing veins and nodules in fine-grained, clay-dominated sediments; however, to date, no field tests, and very limited numerical modelling, have been conducted with regard to the production potential of such accumulations. Work remains to further refine: (1) the marine resource volumes within potential accumulations that can be produced through exploratory drilling programs; (2) the tools for gas hydrate detection and characterisation from remote sensing data; (3) the details of gas hydrate reservoir production behaviour through additional, well-monitored and longer duration field tests and (4) the understanding of the potential environmental impacts of gas hydrate resource development. The results of future production tests, in the context of varying market and energy supply conditions around the globe, will be the key to determine the ultimate timing and scale of the commercial production of natural gas from gas hydrates.

Ray Boswell; Koji Yamamoto; Sung-Rock Lee; Timothy Collett; Pushpendra Kumar; Scott Dallimore

2014-01-01T23:59:59.000Z

256

Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture  

SciTech Connect

Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700C) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

2014-01-01T23:59:59.000Z

257

Method of coalbed methane production  

SciTech Connect

This patent describes a method for producing coalbed methane from a coal seam containing coalbed methane and penetrated by at least one injection well and at least one producing well. It comprises: injecting an inert gas through the injection well and into the coal seam. The inert gas being a gas that does not react with the coal under conditions of use and that does not significantly adsorb to the coal; and producing a gas from the production well which consists essentially of the inert gas, coalbed methane, or mixtures thereof.

Puri, R.; Stein, M.H.

1989-11-28T23:59:59.000Z

258

Texas--State Offshore Coalbed Methane Production (Billion Cubic...  

Annual Energy Outlook 2012 (EIA)

Date: 12312015 Referring Pages: Coalbed Methane Estimated Production Texas State Offshore Coalbed Methane Proved Reserves, Reserves Changes, and Production Coalbed Methane...

259

Louisiana--State Offshore Coalbed Methane Production (Billion...  

Annual Energy Outlook 2012 (EIA)

Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production LA, State Offshore Coalbed Methane Proved Reserves, Reserves Changes, and Production Coalbed Methane...

260

Methane Credit | Open Energy Information  

Open Energy Info (EERE)

Methane Credit Methane Credit Jump to: navigation, search Name Methane Credit Place Charlotte, North Carolina Zip 28273 Product Specialises in utilising methane produced on municipal landfill sites. Coordinates 35.2225°, -80.837539° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.2225,"lon":-80.837539,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

NETL: Methane Hydrates - Hydrate Newsletter  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate R&D Program Newsletter Methane Hydrate R&D Program Newsletter An image of a hydrate burning overlayed with the Newsletter Title: Fire in the Ice The methane hydrate newsletter, Fire in the Ice, is a bi-annual publication highlighting the latest developments in international gas hydrates R&D. Fire in the Ice promotes the exchange of information amoung those involved in gas hydrates research and development, and also recognizes the efforts of a hydrate researcher in each issue. The newsletter now reaches nearly 1300 scientists and other interested individuals in sixteen countries. To subscribe electronically to Fire in the Ice please send an email to karl.lang@contr.netl.doe.gov Please click on the links below to access issues of "Fire in the Ice". More on Methane Hydrates

262

ISSUE PAPER METHANE AVOIDANCE FROM  

E-Print Network (OSTI)

.........................................................................................1 1.2. GHG Emissions from Organic Waste...........................................................................................................39 6.2. Standard Methods for Quantifying Methane from Organic Waste in Landfills...40 6.3. GHG.2. Compost GHG Potential

Brown, Sally

263

Emission of methane from plants  

Science Journals Connector (OSTI)

...basis for the efforts to ameliorate fluxes of this potent greenhouse gas, which may contribute significantly to global warming...was emitting significant quantities of methane under ambient lighting in laboratory-controlled conditions. We also examined other...

2009-01-01T23:59:59.000Z

264

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Heat flow and gas hydrates on the continental margin of India Last Reviewed 12/15/2011 Heat flow and gas hydrates on the continental margin of India Last Reviewed 12/15/2011 DE-NT0005669 Goal The goals of this project are to construct maps of apparent and residual heat flow through the western continental margin of India and to investigate the relationship of residual heat flow anomalies to fluid flow and gas hydrate distribution in the subsurface. Performer Oregon State University, College of Oceanic and Atmospheric Science, Corvallis, OR 97331 Map of the four regions sampled during NGHP Expedition 01 Map of the four regions sampled during NGHP Expedition 01 Background Gas hydrate distribution in sediments depends on methane supply, which in turn depends on fluid flow. When drilling data are available to calibrate seismic observations of the base of the gas hydrate stability zone (GHSZ),

265

Atmospheric Chemistry  

NLE Websites -- All DOE Office Websites (Extended Search)

competencies Atmospheric Chemistry Atmospheric Chemistry is the study of the composition of the atmosphere, the sources and fates of gases and particles in air, and changes induced...

266

Combustion analysis of an equimolar mixture of methane and syngas in a surface-stabilized combustion burner for household appliances  

Science Journals Connector (OSTI)

Abstract The primary objective of this work is to study the combustion of an equimolar mixture of methane and syngas (CH4SG) in a ceramic surface-stabilized combustion burner. We examine the effects of the fuel composition, the air-to-fuel ratio and the thermal input on the flame stability, the radiation efficiency and the pollutant emissions (CO and NOx). In this study, we evaluate a syngas with a high hydrogen content that is similar to those obtained by coal gasification (5060% H2) using Sasol/Lurgi gasification technology and biomass gasification, for example. To determine the effect of the air-to-fuel ratio (?), the burner performance is analyzed at ?=1.4 and ?=1.1. Some studies have reported optimal operating conditions for ?=1.4, whereas for hydrocarbons, the proximity to stoichiometric conditions at the ?=1.1 air-to-fuel ratio produces the highest possible laminar burning velocity and flame temperature. The thermal inputs evaluated in this study correspond to three values (1.0, 1.8, and 2.5kW) found in household appliances and for cooking appliances in particular. The results for this experimental burner design indicate that the macroscopic flame shape for an equimolar CH4SG mixture is approximately the same as that for CH4. Moreover, the pollutant concentrations in the flue gas are generally below 85ppm for CO and 15ppm for NOx. However, the thermal input and the air-to-fuel ratio significantly affect the flame structure, the radiation efficiency and the pollutant emissions.

Carlos E. Arrieta; Andrs A. Amell

2014-01-01T23:59:59.000Z

267

Coalbed Methane Proved Reserves  

Gasoline and Diesel Fuel Update (EIA)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2003 2004 2005 2006 2007 2008 View History U.S. 18,743 18,390 19,892 19,620 21,874 20,798 1989-2008 Alabama 1,665 1,900 1,773 2,068 2,126 1,727 1989-2008 Alaska 0 0 2007-2008 Arkansas 31 31 2007-2008 California 0 0 2007-2008 Colorado 6,473 5,787 6,772 6,344 7,869 8,238 1989-2008 Florida 0 0 2007-2008 Kansas 340 301 2007-2008 Kentucky 0 0 2007-2008 Louisiana 7 9 2007-2008 North 7 9 2007-2008 South Onshore 0 0 2007-2008 South Offshore 0 0 2007-2008 Michigan 0 0 2007-2008 Mississippi 0 0 2007-2008 Montana 66 75 2007-2008 New Mexico 4,396 5,166 5,249 4,894 4,169 3,991 1989-2008

268

SO2-induced stability of Ag-alumina catalysts in the SCR of NO with methane  

SciTech Connect

We report on a stabilization effect on the structure and activity of Ag/Al2O3 for the selective catalytic reduction (SCR) of NOx with CH4 imparted by the presence of SO2 in the exhaust gasmixture. The reaction is carried out at temperature above 600 8C to keep the surface partially free of sulfates. In SO2-free gases, catalyst deactivation is fast and measurable at these temperatures. Time-resolved TEM analyses of used samples have determined that deactivation is due to sintering of silver from well-dispersed clusters to nanoparticles to micrometer-size particles with time-on-stream at 625 8C. However, sintering of silver was dramatically suppressed by the presence of SO2 in the reaction gas mixture. The structural stabilization by SO2 was accompanied by stable catalyst activity for the NO reduction to N2. The direct oxidation of methane was suppressed, thus the methane selectivity was improved in SO2-laden gas mixtures. In tests with high-content silver alumina with some of the silver present in metallic form, an increase in the SCR activity was found in SO2-containing gas mixtures. This is attributed to redispersion of the silver particles by SO2, an unexpected finding. The catalyst performance was reversible over many cycles of operation at 625 8C with the SO2 switched on and off in the gas mixture.

She, Xiaoyan; Flytzani-Stephanopoulos, Maria; Wang, Chong M.; Wang, Yong; Peden, Charles HF

2009-04-29T23:59:59.000Z

269

The methane-acetylene cycle Aerospace Plane - A promising candidate for earth to orbit transportation  

SciTech Connect

The methane-acetylene cycle Aerosapce Plane (MACASP) concept is proposed and its theoretical feasibility is shown. In this concept, methane fuel stored on-board the aircraft is run out within the wing leading edge in pipes at temperatures up to 1400 K. In the presence of catalyst, the heat provided by wing drag is used to drive the highly endothermic chemical reaction 2CH4 yields 3H2 + C2H2. The products of this reaction, hydrogen and acetylene, are then fed into a combustion chamber and burned in air. On the NASP, terminal acceleration to orbit beyond the critical Mach number of the scramjet can be enabled by rocket operation using a small on-board supply of LOx. The advantages of this concept are that the two highly energetic but difficult-to-store fuels can be used without on-board storage. It is shown that the MACASP concept offers significant promise for economical earth-to-orbit transportation. 5 refs.

Zubrin, R.M. (Martin Marietta Astronautics Group, Denver, CO (United States))

1992-01-01T23:59:59.000Z

270

Ethanol and Methane Production from Oil Palm Frond by Two Stage SSF  

Science Journals Connector (OSTI)

Abstract A two step, included process producing ethanol from oil palm fronts (OPF) by two-stage simultaneous saccharification and Saccharomyces cerevisiae fermentation followed by anaerobic digestion of its effluent to produce methane was investigated. OPF was soaked in dilute sulfuric acid, hydrogen peroxide and water consequently pretreated by microwave for preparing of cellulose and followed by simultaneous saccharification and fermentation. The result indicated OPF soaking in water gave a maximal ethanol yield was 0.32 g-ethanol/g-glucose which was 62.75% of the ethanol theoretical yield (0.51g-ethanol/g-glucose). The effluent from the ethanol production process was used to produce methane with the yield of 514 ml CH4/g VS added. Therefore, soaking in water and microwave co-pretreatment could helpful due to its low toxicity and low corrosion compare to sulfuric acid and hydrogen peroxide which improves the efficiency of enzymatic hydrolysis. The maximum energy output of the process (745 kWh/ ton of OPF) was about 72% of the energy contributed by cellulose fraction, contained in the oil palm frond.

Tussanee Srimachai; Veerasak Thonglimp; Sompong O-Thong

2014-01-01T23:59:59.000Z

271

Photochemistry in Terrestrial Exoplanet Atmospheres III: Photochemistry and Thermochemistry in Thick Atmospheres on Super Earths and Mini Neptunes  

E-Print Network (OSTI)

Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H2-dominated atmospheres and non-H2-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to be in the form of CO2 rather than CH4 or CO in a H2-depleted water-dominated thick atmosphere, and that the preferred loss of light elements from an oxygen-poor carbon-rich atmosphere leads to formation of unsaturated hydrocarbons (C2H2 and C2H4). We apply our self-consistent atmosphere models to compute spectra and diagnostic features for known transiting low-mass exoplanets GJ 1214 b, HD 97658 b, and 55 Cnc e. For GJ 1...

Hu, Renyu

2014-01-01T23:59:59.000Z

272

Effects of anode microstructures on durability of microtubular solid oxide fuel cells during internal steam reforming of methane  

Science Journals Connector (OSTI)

Abstract When hydrocarbons are used as a fuel in solid oxide fuel cells (SOFCs), internal steam reforming increases the energy conversion efficiency and simplifies the system, including the balance-of-plant. However, conventional nickelyttria stabilized zirconia (NiYSZ) anodes are prone to deterioration at high temperatures and high humidity. This paper focuses on effects in anode microstructure on performance and durability of microtubular SOFCs. The evaluations were conducted under high steam content and internal methane reforming conditions using NiYSZ anodes using acrylic resin and graphite pore formers. The initial cell performance was almost identical to that of \\{SOFCs\\} with anodes using acrylic resin and graphite pore formers in 40% H23% H2O at 700C. However, the anode using acrylic resin deteriorated rapidly in 40% H230% H2O over a period of 28h. Furthermore, it generated almost no electric power by internal steam reforming of methane. The local oxidation of nickel particles was observed at the interface between the electrolyte and the deteriorated anodes. The anode using graphite pore former provided stable power generation in 40% H230% H2O, and was able to generate power in 10% CH430% H2O. The pore formers strongly affect fuel diffusivity in the SOFC anodes, which is an important factor in stable internal steam reforming of methane.

Hirofumi Sumi; Toshiaki Yamaguchi; Toshio Suzuki; Hiroyuki Shimada; Koichi Hamamoto; Yoshinobu Fujishiro

2014-01-01T23:59:59.000Z

273

Methane oxidation rates in the anaerobic sediments of Saanich Inlet  

Science Journals Connector (OSTI)

water methane concentration were avail- able. ... water solute concentrations and methane oxidation rates ..... Diffusion of light paraffin hydrocarbons in water.

2000-02-09T23:59:59.000Z

274

NETL: Methane Hydrates - Global Assessment of Methane Gas Hydrates  

NLE Websites -- All DOE Office Websites (Extended Search)

Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 DE-FE0003060 Goal The goal of this project is to develop a global assessment of methane gas hydrates that will facilitate informed decision-making regarding the potential development of gas hydrate resources between the scientific community and other stakeholders/decision makers. The Assessment will provide science-based information on the role of gas hydrates in natural climate change and the carbon cycle, their sensitivity to climate change, and the potential environmental and socio-economic impacts of hydrate production. Performers Stiftelsen GRID-Arendal, Arendal, Norway Funding Institutions United Nations Environment Programme (UNEP) Statoil Schlumberger United States Department of Energy (USDOE)

275

Chapter 18 - Worldwide Coal Mine Methane and Coalbed Methane Activities  

Science Journals Connector (OSTI)

Abstract The chapter provides an overview of coal bed methane production in all countries (except USA; covered in Chapter 17) around the world where there is a viable coal deposit. Coal deposits are shown in a map and coal bed methane reserves are estimated. All countries can follow the lead provided by USA in CBM production where 10% of total gas consumption (2 TCF/year) comes from coal seams. Exploitation of thick and deep coal seams using the latest technology can create a vast source of domestic energy for many countries around the world.

Charlee Boger; James S. Marshall; Raymond C. Pilcher

2014-01-01T23:59:59.000Z

276

Miscellaneous States Coalbed Methane Proved Reserves (Billion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

277

Carbon Dioxide and Methane Emissions from Estuaries  

Science Journals Connector (OSTI)

Carbon dioxide and methane emissions from estuaries are reviewed in relation with biogeochemical processes and carbon cycling. In estuaries, carbon dioxide and methane emissions show a large spatial and temporal ...

Gwenal Abril; Alberto Vieira Borges

2005-01-01T23:59:59.000Z

278

Optical constants of liquid and solid methane  

Science Journals Connector (OSTI)

The optical constants nr + ini of liquid methane and phase I solid methane were determined over the entire spectral range by the use of various data sources published in the...

Martonchik, John V; Orton, Glenn S

1994-01-01T23:59:59.000Z

279

Implementation of SAFT + Cubic, PC-SAFT, and SoaveBenedictWebbRubin Equations of State for Comprehensive Description of Thermodynamic Properties in Binary and Ternary Mixtures of CH4, CO2, and n-C16H34  

Science Journals Connector (OSTI)

Implementation of SAFT + Cubic, PC-SAFT, and SoaveBenedictWebbRubin Equations of State for Comprehensive Description of Thermodynamic Properties in Binary and Ternary Mixtures of CH4, CO2, and n-C16H34 ... The recently proposed SAFT + Cubic EoS passes this test relatively successfully (AAD% for the single phase properties less than 6%), proving its robustness as a predictive tool. ... PC-SAFT appears to be the less reliable estimator of the data, whose AAD% might exceed 22%. ...

Ilya Polishuk

2011-11-09T23:59:59.000Z

280

coalbed methane | OpenEI  

Open Energy Info (EERE)

coalbed methane coalbed methane Dataset Summary Description (Abstract): Each TMY is a data set of hourly values of solar radiation and meteorological elements for a 1-year period. Solar radiation is modeled using the NREL METSTAT model, with surface observed cloud cover being the principal model input. The container file contains one TMY file for each selected station in the region, plus documentation files and a TMY data reader file for use with Microsoft Excel. (Purpose): Simulations Source NREL Date Released April 30th, 2005 (9 years ago) Date Updated November 07th, 2007 (7 years ago) Keywords coalbed methane GEF Kenya NREL SWERA TMY UNEP Data application/zip icon Download Data (zip, 5.4 MiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Method for the photocatalytic conversion of methane  

DOE Patents (OSTI)

A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

1998-02-24T23:59:59.000Z

282

Methane bubbling from northern lakes: present and future contributions to the  

E-Print Network (OSTI)

in permafrost. A carbon mass balance calculation of CH4 release from thermokarst lakes on the Siberian yedoma

Smith, Laurence C.

283

Effects of oxygen concentration on radiative loss from normal-gravity and microgravity methane diffusion flames  

SciTech Connect

Laminar diffusion flames of methane, burning in quiescent oxidizing environments at atmospheric pressure, have been studied under both normal-gravity and microgravity conditions. Radiation from these flames is measured using a wide-view-angle, thermopile detector radiometer. The oxidizer was 18, 21, and 30 percent oxygen in nitrogen. 17 refs.

Bahadori, M.Y.; Edelman, R.B.; Stocker, D.P.; Sotos, R.G.; Vaughan, D.F. (Science Applications International Corp., Torrance, CA (United States) Rockwell International Corp., Rocketdyne Div., Canoga Park, CA (United States) NASA, Lewis Research Center, Cleveland, OH (United States))

1992-01-01T23:59:59.000Z

284

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy  

E-Print Network (OSTI)

, and carbon dioxide. Introduction Carbon dioxide emissions resulting from the burning of fossil fuels 20 metric tons of carbon dioxide per capita are released annually into the atmosphere.1a,b CarbonStorage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks

Yaghi, Omar M.

285

Modeling of fixed bed methanation reactor for syngas production: Operating window and performance characteristics  

Science Journals Connector (OSTI)

Abstract The present work focuses on the development of phenomenological model for the bio-syngas to methane conversion process. One dimensional heterogeneous and pseudo-homogeneous model were simulated for a typical pilot plant scale fixed bed methanator processing 55mol/h of CO (total molar flow rate of 310mol/h) with inlet composition of H2/CO=3, CO2/CO=1, CH4/CO=0.5 at 550K and 1atm. Performance of the fixed bed reactor at different operating conditions like CO2/CO ratio, H2/CO ratio, effect of H2O in the feed was studied. It was found that for feeds that were not pre-enriched with hydrogen, presence of water and water gas shift activity was found to decrease the catalyst inventory substantially. CO2 in the inlet feed stream would help to decrease the temperature due to dilution effect and more importantly, can be chosen to maximize methane yield per mole of CO converted. Further, the model was simulated to predict the performance characteristics of reactor with a mixture containing two types of catalyst, one of them being specifically added to increase H2/CO ratio in feed through water gas shift reaction. The work also laid the importance of incorporating pore diffusion and external mass transfer locally in the computation of actual catalyst inventory and reactor volume. The work was useful in selection of operating window and assessing the various viable options for an industrial reactor. The model developed will serve in selection of operability window for commercialization of substitute natural gas synthesis (SNG) process.

Naren Rajan Parlikkad; Stphane Chambrey; Pascal Fongarland; Nouria Fatah; Andrei Khodakov; Sandra Capela; Olivier Guerrini

2013-01-01T23:59:59.000Z

286

Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily  

SciTech Connect

Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but prone to rapid desiccation. Bacterial adsorption onto foam padding, natural sponge, and geotextile was successful. The most important factor for success appeared to be water holding capacity. Prototype biotarps made with geotextiles plus adsorbed methane oxidizing bacteria were tested for their responses to temperature, intermittent starvation, and washing (to simulate rainfall). The prototypes were mesophilic, and methane oxidation activity remained strong after one cycle of starvation but then declined with repeated cycles. Many of the cells detached with vigorous washing, but at least 30% appeared resistant to sloughing. While laboratory landfill simulations showed that four-layer composite biotarps made with two different types of geotextile could remove up to 50% of influent methane introduced at a flux rate of 22 g m{sup -2} d{sup -1}, field experiments did not yield high activity levels. Tests revealed that there were high hour-to-hour flux variations in the field, which, together with frequent rainfall events, confounded the field testing. Overall, the findings suggest that a methanotroph embedded biotarp appears to be a feasible strategy to mitigate methane emission from landfill cells, although the performance of field-tested biotarps was not robust here. Tarps will likely be best suited for spring and summer use, although the methane oxidizer population may be able to shift and adapt to lower temperatures. The starvation cycling of the tarp may require the capacity for intermittent reinoculation of the cells, although it is also possible that a subpopulation will adapt to the cycling and become dominant. Rainfall is not expected to be a major factor, because a baseline biofilm will be present to repopulate the tarp. If strong performance can be achieved and documented, the biotarp concept could be extended to include interception of other compounds beyond methane, such as volatile aromatic hydrocarbons and chlorinated solvents.

Helene Hilger; James Oliver; Jean Bogner; David Jones

2009-03-31T23:59:59.000Z

287

Reaktionshemmender Einflu von Schwefel auf die Aufkohlung von Nickel in Methan-Wasserstoff-Gemischen  

Science Journals Connector (OSTI)

The carburization of nickel in CH4-H2 and CH4-H2S-H2 gas mixtures was studied in a flow apparatus at 10601280 K applying the resistance-relaxation technique. The reaction of nickel with CH4 is found to be therma...

R. Kikowatz; G. Hrz

1987-01-01T23:59:59.000Z

288

The catalytic activity of Ru and Ir supported on Eu2O3 for the reaction, CO2 + CH4 ? 2 H2 + 2 CO: a viable solar-thermal energy system  

Science Journals Connector (OSTI)

Methane and carbon dioxide which often co-exist in nature, constitute valuable potential resources both for the storage of solar (thermal) energy and the convenient production of synthesis gas....2O3 are effectiv...

J. S. H. Q. Perera; J. W. Couves; G. Sankar; J. M. Thomas

1991-01-01T23:59:59.000Z

289

Accurate equations of state for CF4, CF4Ar, and CF4CH4 fluids using two-body and three-body intermolecular potentials from molecular dynamics simulation  

Science Journals Connector (OSTI)

Abstract Molecular dynamics simulations have been performed to obtain pressures and equations of state of CF4, CF4Ar, and CF4CH4 fluids using different inversion and ab initio pair-potentials. To take many-body forces into account, the three-body potentials of Hauschild and Prausnitz, Mol. Simul. 11 (1993) 177185, Wang and Sadus, J. Chem. Phys. 125 (2006) 144509144513, and Guzman et al., Mol. Phys. 109 (2011) 955967 have been used with the pair-potentials. The significance of this work is that the many-body potential of Hauschild and Prausnitz is extended as a function of density, temperature, and molar fraction and is used with the HFD-like pair-potentials of CF4, CF4Ar, and CF4CH4 systems to improve the prediction of the pressure values without requiring an expensive three-body calculation. We have also simulated the self-diffusion coefficient of CF4 in good agreement with experimental data.

Mohsen Abbaspour; Maryam Sheykh

2014-01-01T23:59:59.000Z

290

Electron Transport in Methane Gas  

Science Journals Connector (OSTI)

We propose a kinetic theory for electron-drift-velocity maxima in polyatomic gases. The case of methane is considered in detail, and good agreement with experiment is obtained with use of model cross sections. The Boltzmann equation is solved directly by applying an iterative numerical technique, which converges well when inelastic scattering effects are important.

Peter Kleban and H. Ted Davis

1977-08-22T23:59:59.000Z

291

Methane production by attached film  

DOE Patents (OSTI)

A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

Jewell, William J. (202 Eastwood Ave., Ithaca, NY 14850)

1981-01-01T23:59:59.000Z

292

Methane generation from waste materials  

DOE Patents (OSTI)

An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

Samani, Zohrab A. (Las Cruces, NM); Hanson, Adrian T. (Las Cruces, NM); Macias-Corral, Maritza (Las Cruces, NM)

2010-03-23T23:59:59.000Z

293

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network (OSTI)

Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THE2011] METHANE DIGESTERS AND BIOGAS RECOVERY methane, and 64%

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

294

Methane Hydrate Advisory Committee | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Advisory Methane Hydrate Advisory Committee Methane Hydrate Advisory Committee The Methane Hydrate Advisory Committee was created in response to provisions of the Methane Hydrate Research and Development Act of 2000 and reauthorized by the Energy Policy Act of 2005. The Committee is to advise the Secretary of Energy on potential applications of methane hydrate; assist in developing recommendations and priorities for the methane hydrate research and development program; and submit to Congress one or more reports on an assessment of the research program and an assessment of the DOE 5-year research plan. The Committee's charter stipulates that up to 15 members can be appointed by the Secretary of Energy, representing institutions of higher education, industrial enterprises and oceanographic institutions and state agencies.

295

Methane Hydrate Production Feasibility | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Production Feasibility Production Feasibility Methane Hydrate Production Feasibility The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. Methane, the predominant component of natural gas, forms hydrate in the presence of water, low temperatures and high pressures. Alternatively, when the temperature is increased or the pressure decreased so that hydrates are outside their stability field, they dissociate into methane and water.

296

Recovery economics of coalbed methane and cost implications of pipeline hookup  

SciTech Connect

For Appalachian coal mines, the totaled methane emission rates exceed 180 MMCF/D, with active mines pushing deeper into virgin seams having higher relative gas contents. While most of this gas currently is vented into the atmosphere to prevent gas-related explosions, the technology exists to develop this valuable gas resource either in conjunction with mining or independently. In 1977, the U.S. Department of Energy (DOE) began the Methane Recovery from Coalbeds Project (MRCP) to characterize and help encourage utilization of this resource. Since the project inception, TRW has been involved in the collection and analysis of data, and is in the process of forming a coherent picture of the coalbed methane resource potential for the entire Appalachian region. Preliminary analysis indicates an estimated in-place coalbed methane resource in the Appalachian Basin of up to 150 TCF. Eastern coal operators are beginning to better understand the production potential of coalbed methane. In Buchanan County, Virginia, the Island Creek Coal Company produced up to 434 MCF/d from 12 horizontal boreholes drilled into the mine face. In Alabama, U.S. Steel's mines recently began commercial production and sold 25 MMCF of pipeline quality gas in December of 1981. This study examines the recovery economics of coalbed methane, and specifically addresses the cost implications of pipeline hook-up. An analysis which addresses the size of a project, pipeline construction costs, and anticipated contract gas price helps determine an economical project-topipeline hook-up distance.

Dickehuth, D.A.; Adams, M.A.; Hayoz, F.P.

1982-11-01T23:59:59.000Z

297

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

SciTech Connect

Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

2011-06-01T23:59:59.000Z

298

Increase of Atmospheric Methane Recorded in Antarctic Ice Core  

Science Journals Connector (OSTI)

...obtained by Rasmussen and Khalil with ice samples from Camp Century (77011'N, 61009'W), Crete (71 07'N, 37 19'W...however, this difference is 130 years for ice from Camp Century, 200 years for Crete, and 240 years for Byrd Station...

B. STAUFFER; G. FISCHER; A. NEFTEL; H. OESCHGER

1985-09-27T23:59:59.000Z

299

Nickel crystallite thermometry during methanation  

SciTech Connect

A magnetic method to measure the average temperature of superparamagnetic nickel crystallites has been applied during CO methanation. The method takes advantage of the temperature dependence of the low field magnetization of such catalysts; however, the adsorption of carbon monoxide and the formation of surface carbon species complicate the interpretation of results. Calibrations to account for temperature change and the adsorption of reactants are described. The calibration for the effects of CO is based on the assumption that the interaction of CO with nickel is the same for methanation and disproportionation. Interphase heat transfer calculations based on the thermometric data compare favorably with previous results from ethane hyrogenolysis, and give no indication of microscopic temperature differences between the nickel crystallites and support.

Ludlow, D.K.; Cale, T.S.

1986-01-01T23:59:59.000Z

300

Planetary and Space Science ] (  

E-Print Network (OSTI)

to sustaining Titan's thick nitrogen atmosphere. However, methane is destroyed and converted to heavier the warming provided by CH4- generated hydrocarbon hazes in the stratosphere and the pressure induced opacity), whose reaction with carbon grains or carbon dioxide in the crustal pores produces methane gas

Atreya, Sushil

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

PRINT ONLY: OUTER SOLAR SYSTEM Mousis O. Lunine J. I. Pasek M. Cordier D. Waite J. H. Jr. Mandt K. E. Lewis W. S. Nguyen M.-J.  

E-Print Network (OSTI)

with hydrothermal reactions that may produce CH4 in the satellite's interior. If methane derives from such reactions that hydrothermal reac- tions in the interior of Titan could lead to the formation of H2-rich fluids which may combine with ambient carbon dioxide to produce the observed atmospheric methane [4][5]. On the other hand

Rathbun, Julie A.

302

A study on the solubility of heavy hydrocarbons in liquid methane and methane containing mixtures.  

E-Print Network (OSTI)

??The solubilities of the hydrocarbons n-butane, n-pentane, n-hexane, n-octane, and n-nonane in liquid methane and of n-hexane in the mixed solvents of methane and ethane (more)

Brew, T. C. L.

2009-01-01T23:59:59.000Z

303

Plasma catalytic reforming of methane  

Science Journals Connector (OSTI)

Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This article describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius), and a high degree of dissociation and a substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (40% H2, 17% CO2 and 33% N2, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (23 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H2 with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content (?1.5%) with power densities of ?30 kW (H2 HHV)/l of reactor, or ?10m3/h H2 per liter of reactor. Power density should further increase with increased power and improved design.

L Bromberg; D.R Cohn; A Rabinovich; N Alexeev

1999-01-01T23:59:59.000Z

304

Energieverteilung von in flssigem Methan gestreuten kalten Neutronen  

Science Journals Connector (OSTI)

The interaction between CH4 molecules shall be studied by neutron spectroscopic measurements for different phases of the substance. In a first investigation the molecular rotations are found to be completely free...

H. Stiller; S. Hautecler

1962-01-01T23:59:59.000Z

305

Rapid Methane Oxidation in a Landfill Cover Soil  

Science Journals Connector (OSTI)

...fluor (1) as 14CO2 after combustion; radiocarbon recovery...core was assayed by dry combustion of freeze-dried, homogenized...Label recovered by dry combustion represents 14CH4 assimilated into microbial biomass and inorganic matter...

S. C. Whalen; W. S. Reeburgh; K. A. Sandbeck

1990-11-01T23:59:59.000Z

306

HIGH-PRESSURE SOLVENT EXTRACTION OF METHANE FROM GEOPRESSURED...  

Office of Scientific and Technical Information (OSTI)

to be about 100 based on CH4 solubility in brine at 50-125C from O'Sullivan and Smith (11), tnd low pressure CH solubility in hexadecane at 25-2002 from Cukor and Prausni...

307

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 EST-380-NEDA Goal The purpose of this study is to establish sediment lithology and quantification of methane in hydrates hosted in fine-grained sediments from the Gulf of Mexico (GoM), a marine site of methane hydrate occurrence. The results will help establish a correlation between laboratory data and hydrate accumulation field data on dispersed hydrates in the natural environment. Performer Brookhaven National Laboratory (BNL), Upton, New York 11973 Background Gas hydrates are located in permafrost and marine environments and show potential as a vast methane source worldwide. However, methane is about 17 times more potent a greenhouse gas than CO2 and the inherent instability of

308

Microbial Sequestration of Carbon Dioxide and Subsequent Conversion to Methane  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration of Carbon Dioxide and Subsequent Sequestration of Carbon Dioxide and Subsequent conversion to Methane By Nirupam Pal Associate Professor California Polytechnic State University San Luis Obispo, CA 93401 Email : npal@calpoly.edu Phone : (805) 756-1355 INTRODUCTION The rising level of carbon dioxide in the atmosphere has been of growing concern in recent years. The increasing levels of carbon dioxide, the most dominant component of greenhouse gases, contribute to global warming and changing global weather patterns which could potentially lead to catastrophic events that could threaten life in every form on this planet. The level of carbon dioxide in the worlds atmosphere has increased from about 280 ppm in 1850 to the current level of approximately 350 ppm. There are several natural sources and sinks of

309

Methane Hydrates R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program Gas hydrates are a naturally-occurring combination of methane gas and water that form under specific conditions of low temperature and high pressure. Once thought to be rare in nature, gas hydrates are now known to occur in great abundance in association with arctic permafrost and in the shallow sediments of the deep-water continental shelves. The most recent estimates of gas hydrate abundance suggest that they contain

310

,"Federal Offshore California Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Federal Offshore California Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2013...

311

Miscellaneous States Coalbed Methane Proved Reserves Revision...  

U.S. Energy Information Administration (EIA) Indexed Site

Revision Decreases (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

312

,"Colorado Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

313

,"Arkansas Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

314

,"Wyoming Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Wyoming Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

315

,"Miscellaneous States Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

316

A guide to coalbed methane operations  

SciTech Connect

A guide to coalbed methane production is presented. The guide provides practical information on siting, drilling, completing, and producing coalbed methane wells. Information is presented for experienced coalbed methane producers and coalbed methane operations. The information will assist in making informed decisions about producing this resource. The information is presented in nine chapters on selecting and preparing of field site, drilling and casing the wellbore, wireline logging, completing the well, fracturing coal seams, selecting production equipment and facilities, operating wells and production equipment, treating and disposing of produced water, and testing the well.

Hollub, V.A.; Schafer, P.S.

1992-01-01T23:59:59.000Z

317

,"Montana Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Montana Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

318

,"Oklahoma Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Oklahoma Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

319

,"Pennsylvania Coalbed Methane Proved Reserves (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

320

,"Virginia Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Virginia Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

CO2 Sequestration Enhances Coalbed Methane Production.  

E-Print Network (OSTI)

??Since 1980s, petroleum engineers and geologists have conducted researches on Enhanced Coalbed Methane Recovery (ECBM). During this period, many methods are introduced to enhance the (more)

Pang, Yu

2013-01-01T23:59:59.000Z

322

,"Pennsylvania Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

323

,"Miscellaneous Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

324

,"Alabama Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

325

,"California - Coastal Region Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

326

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS  

E-Print Network (OSTI)

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS by Elliott Paul Barnhart ..................................................................................14 Ability of the Consortium to Produce Methane from Coal and Metabolites ................16.............................................................................................21 Coal and Methane Production

Maxwell, Bruce D.

327

Methane for Power Generation in Muaro Jambi: A Green Prosperity Model Project  

SciTech Connect

NREL conducted eight model projects for Millennium Challenge Corporation's (MCC) Compact with Indonesia. Green Prosperity, the largest project of the Compact, seeks to address critical constraints to economic growth while supporting the Government of Indonesia's commitment to a more sustainable, less carbon-intensive future. This study evaluates electricity generation from the organic content of wastewater at a palm oil mill in Muaro Jambi, Sumatra. Palm mills use vast amounts of water in the production process resulting in problematic waste water called palm oil mill effluent (POME). The POME releases methane to the atmosphere in open ponds which could be covered to capture the methane to produce renewable electricity for rural villages. The study uses average Indonesia data to determine the economic viability of methane capture at a palm oil mill and also evaluates technology as well as social and environmental impacts of the project.

Moriarty, K.; Elchinger, M.; Hill, G.; Katz, J.; Barnett, J.

2014-07-01T23:59:59.000Z

328

A highly active and stable Co4N/?-Al2O3 catalyst for CO and CO2 methanation to produce synthetic natural gas (SNG)  

Science Journals Connector (OSTI)

Abstract Co4N/?-Al2O3 and Co/?-Al2O3 catalysts with different metal loadings were prepared by NH3 and H2-temperature programmed reaction method for the co-methanation of carbon oxides (CO and CO2). The catalysts were characterized by N2 adsorptiondesorption, XRD, XPS, TEM-SAED, H2, CO, and CO2-TPD techniques. Results showed that the Co4N catalysts had higher activity than Co metal-supported catalysts due to their enhanced adsorption capacity, uniform metal dispersion, and superior metal-support interaction. Among the catalysts studied, 20Co4N/?-Al2O3 catalyst with 20wt% metal loading showed the best performance. This catalyst achieved higher activity for CH4 formation between 200 and 300C and maintained high product selectivity (?98%). A 250h stability test for 20Co4N/?-Al2O3 was also conducted at 350C and increased gas hourly space velocity (GHSV; 10,000h?1). The spent catalyst was further characterized using XRD, TEM, and TGA analysis. Results revealed that the catalyst was highly resistant to metal sintering and carbon deposition, whereas high CO and CO2 conversion and CH4 selectivity were maintained even at a higher GHSV.

Rauf Razzaq; Chunshan Li; Muhammad Usman; Kenzi Suzuki; Suojiang Zhang

2015-01-01T23:59:59.000Z

329

Scientists detect methane levels three times larger than expected...  

NLE Websites -- All DOE Office Websites (Extended Search)

methane that actually preceded recent concerns about potential emissions from fracking," Dubey said. Scientists detect methane levels three times larger than expected over...

330

Three-dimensional model synthesis of the global methane cycle  

E-Print Network (OSTI)

39, Ehhalt, D. H. , The atmoheric cycle of methane, Tellugworld-wide increase in theric methane, 1978-1987, Science,

1991-01-01T23:59:59.000Z

331

Texas--State Offshore Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Texas State Offshore Coalbed Methane Proved Reserves, Reserves Changes, and...

332

Louisiana--State Offshore Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 LA, State Offshore Coalbed Methane Proved Reserves, Reserves Changes, and...

333

Federal Offshore--Texas Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Federal Offshore Texas Coalbed Methane Proved Reserves, Reserves Changes, and Production...

334

California--State Offshore Coalbed Methane Proved Reserves (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 CA, State Offshore Coalbed Methane Proved Reserves, Reserves Changes, and Production...

335

Texas--RRC District 9 Coalbed Methane Production (Billion Cubic...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 9 Coalbed Methane Proved Reserves,...

336

North Dakota Coalbed Methane Proved Reserves (Billion Cubic Feet...  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 North Dakota Coalbed Methane Proved...

337

Texas--RRC District 6 Coalbed Methane Production (Billion Cubic...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 6 Coalbed Methane Proved Reserves,...

338

California (with State off) Coalbed Methane Proved Reserves ...  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 California Coalbed Methane Proved Reserves,...

339

Alaska (with Total Offshore) Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production Alaska Coalbed Methane Proved Reserves, Reserves...

340

Texas--RRC District 1 Coalbed Methane Production (Billion Cubic...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 1 Coalbed Methane Proved Reserves,...

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Alaska (with Total Offshore) Coalbed Methane Proved Reserves...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Alaska Coalbed Methane Proved Reserves,...

342

Michigan Coalbed Methane Proved Reserves (Billion Cubic Feet...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Michigan Coalbed Methane Proved Reserves,...

343

Other States Natural Gas Coalbed Methane, Reserves Based Production...  

Gasoline and Diesel Fuel Update (EIA)

Other States Natural Gas Coalbed Methane, Reserves Based Production (Billion Cubic Feet) Other States Natural Gas Coalbed Methane, Reserves Based Production (Billion Cubic Feet)...

344

California (with State off) Coalbed Methane Production (Billion...  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production California Coalbed Methane Proved Reserves, Reserves...

345

Texas (with State Offshore) Coalbed Methane Proved Reserves ...  

NLE Websites -- All DOE Office Websites (Extended Search)

Texas (with State Offshore) Coalbed Methane Proved Reserves (Billion Cubic Feet) Texas (with State Offshore) Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0...

346

Prediction of coalbed methane reservoir performance with type curves.  

E-Print Network (OSTI)

??Coalbed methane is an unconventional gas resource that consists of methane production from the coal seams. CBM reservoirs are dual-porosity systems that are characterized by (more)

Bhavsar, Amol Bhaskar.

2005-01-01T23:59:59.000Z

347

Louisiana--South Onshore Coalbed Methane Proved Reserves (Billion...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 LA, South Onshore Coalbed Methane Proved...

348

New York Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production New York Coalbed Methane Proved Reserves, Reserves...

349

Texas--RRC District 5 Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 5 Coalbed Methane Proved...

350

Texas--RRC District 1 Coalbed Methane Proved Reserves (Billion...  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, RRC District 1 Coalbed Methane Proved...

351

North Dakota Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production North Dakota Coalbed Methane Proved Reserves,...

352

Mississippi (with State off) Coalbed Methane Production (Billion...  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production Mississippi Coalbed Methane Proved Reserves, Reserves...

353

The Optimization of Well Spacing in a Coalbed Methane Reservoir.  

E-Print Network (OSTI)

??Numerical reservoir simulation has been used to describe mechanism of methane gas desorption process, diffusion process, and fluid flow in a coalbed methane reservoir. The (more)

Sinurat, Pahala Dominicus

2012-01-01T23:59:59.000Z

354

Louisiana--South Onshore Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production LA, South Onshore Coalbed Methane Proved Reserves,...

355

Lower 48 Federal Offshore Coalbed Methane Production (Billion...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production Federal Offshore U.S. Coalbed Methane Proved...

356

Mississippi (with State off) Coalbed Methane Proved Reserves...  

Annual Energy Outlook 2012 (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Mississippi Coalbed Methane Proved Reserves,...

357

Texas--RRC District 8 Coalbed Methane Production (Billion Cubic...  

Gasoline and Diesel Fuel Update (EIA)

company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Estimated Production TX, RRC District 8 Coalbed Methane Proved Reserves,...

358

Diffusion Characterization of Coal for Enhanced Coalbed Methane Production.  

E-Print Network (OSTI)

??This thesis explores the concept of displacement of sorbed methane and enhancement of methane recovery by injection of CO2 into coal, while sequestering CO2. The (more)

Chhajed, Pawan

2011-01-01T23:59:59.000Z

359

Development of gas production type curves for coalbed methane reservoirs.  

E-Print Network (OSTI)

??Coalbed methane is an unconventional gas resource that consists on methane production from the coal seams. The unique coal characteristic results in a dual-porosity system. (more)

Garcia Arenas, Anangela.

2004-01-01T23:59:59.000Z

360

Pure- and mixed-gas permeation of CO2 and CH4 in thermally rearranged polymers based on 3,3?-dihydroxy-4,4?-diamino-biphenyl (HAB) and 2,2?-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA)  

Science Journals Connector (OSTI)

Abstract Permeability coefficients for pure CO2, pure CH4, and CO2/CH4 mixtures containing 50% CO2 are reported for a polyimide synthesized from 3,3?-dihydroxy-4,4?-diamino-biphenyl (HAB) and 2,2?-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) and for three thermally-rearranged (TR) derivatives thereof. Permeability measurements were made at 35C for fugacities ranging from 4 to 25atm. The permeability of CO2 and CH4 increased as the degree of TR conversion increased. For example, CO2 permeability at 10atm increased by a factor of 30 between the unconverted polyimide and its TR analog converted at 450C. In pure-gas experiments, CO2 was observed to plasticize the unconverted polyimide, but it did not appear to plasticize the TR polymers. In mixed-gas experiments, dual-mode competitive sorption caused a depression in CH4 permeability, with very little change in CO2 permeability. In addition, plasticization by CO2 was evident in the CH4 mixed-gas permeability trends, but its impact was small in contrast with dual-mode competitive effects. Consequently, CO2/CH4 mixed-gas permeability selectivity was higher than the ideal selectivity, calculated as the ratio of pure gas permeability coefficients. The dual-mode sorption and permeation model was fit to the experimental data. Dual-mode model parameters and model predictions are reported, along with their confidence intervals. By comparing the dual-mode model predictions with the experimental mixed-gas data, the degree of CO2-induced plasticization was observed to decrease as the degree of TR conversion increased and was completely absent (within experimental uncertainty) for the TR polymer converted at 450C.

Kristofer L. Gleason; Zachary P. Smith; Qiang Liu; Donald R. Paul; Benny D. Freeman

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Musical Atmospherics  

Science Journals Connector (OSTI)

... THE characteristics of audio musical atmospherics which are obtained when an ... musical atmospherics which are obtained when an audio amplifier is placed in a long line or aerial have been discussed from time to ...

T. L. ECKERSLEY

1935-01-19T23:59:59.000Z

362

Plasma catalytic reforming of methane  

SciTech Connect

Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This paper describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius) and high degree of dissociation and substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (50% H{sub 2}, 17% CO and 33% N{sub 2}, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2--3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H{sub 2} with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content ({approximately} 1.5%) with power densities of {approximately} 30 kW (H{sub 2} HHV)/liter of reactor, or {approximately} 10 m{sup 3}/hr H{sub 2} per liter of reactor. Power density should further increase with increased power and improved design.

Bromberg, L.; Cohn, D.R.; Rabinovich, A. [Massachusetts Inst. of Technology, Cambridge, MA (United States). Plasma Science and Fusion Center; Alexeev, N. [Russian Academy of Sciences, Moscow (Russian Federation). Baikov Inst. of Metallurgy

1998-08-01T23:59:59.000Z

363

Direct catalytic conversion of methane and light hydrocarbon gases. Final report, October 1, 1986--July 31, 1989  

SciTech Connect

This project explored conversion of methane to useful products by two techniques that do not involve oxidative coupling. The first approach was direct catalytic dehydrocoupling of methane to give hydrocarbons and hydrogen. The second approach was oxidation of methane to methanol by using heterogenized versions of catalysts that were developed as homogeneous models of cytochrome-P450, an enzyme that actively hydroxylates hydrocarbons by using molecular oxygen. Two possibilities exist for dehydrocoupling of methane to higher hydrocarbons: The first, oxidative coupling to ethane/ethylene and water, is the subject of intense current interest. Nonoxidative coupling to higher hydrocarbons and hydrogen is endothermic, but in the absence of coke formation the theoretical thermodynamic equilibrium yield of hydrocarbons varies from 25% at 827{degrees}C to 65% at 1100{degrees}C (at atmospheric pressure). In this project we synthesized novel, highly dispersed metal catalysts by attaching metal clusters to inorganic supports. The second approach mimics microbial metabolism of methane to produce methanol. The methane mono-oxygenase enzyme responsible for the oxidation of methane to methanol in biological systems has exceptional selectivity and very good rates. Enzyme mimics are systems that function as the enzymes do but overcome the problems of slow rates and poor stability. Most of that effort has focused on mimics of cytochrome P-450, which is a very active selective oxidation enzyme and has a metalloporphyrin at the active site. The interest in nonporphyrin mimics coincides with the interest in methane mono-oxygenase, whose active site has been identified as a {mu}-oxo dinuclear iron complex.We employed mimics of cytochrome P-450, heterogenized to provide additional stability. The oxidation of methane with molecular oxygen was investigated in a fixed-bed, down-flow reactor with various anchored metal phthalocyanines (PC) and porphyrins (TPP) as the catalysts.

Wilson, R.B. Jr.; Posin, B.M.; Chan, Yee-Wai

1995-06-01T23:59:59.000Z

364

The 1991 coalbed methane symposium proceedings  

SciTech Connect

The proceedings of the 1991 coalbed methane symposium are presented. The proceedings contains 50 papers on environmental aspects of recovering methane from coal seams, reservoir characterization and testing mine safety and productivity, coalbed stimulation, geology and resource assessment, well completion and production technologies, reservoir modeling and case histories, and resources and technology.

Not Available

1991-01-01T23:59:59.000Z

365

Technical Note Methane gas migration through geomembranes  

E-Print Network (OSTI)

and Fick's law. This chart can be used by landfill designers to evaluate the methane gas transmission rate for a selected geomembrane type and thickness and expected methane gas pressure in the landfill. KEYWORDS landfill usually consists, from bottom to top, of: graded landfill surface; a gas-venting layer; a low

366

Arctic Methane, Hydrates, and Global Climate  

NLE Websites -- All DOE Office Websites (Extended Search)

Arctic Methane, Hydrates, and Global Climate Arctic Methane, Hydrates, and Global Climate Speaker(s): Matthew T. Reagan Date: March 17, 2010 - 12:00pm Location: 90-3122 Paleooceanographic evidence has been used to postulate that methane may have had a significant role in regulating past climate. However, the behavior of contemporary permafrost deposits and oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. A recent expedition to the west coast of Spitsbergen discovered substantial methane gas plumes exiting the seafloor at depths that correspond to the upper limit of the receding gas hydrate stability zone. It has been suggested that these plumes may be the

367

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 DE-FC26-06NT42963 Goal The goal of this project is to develop observational and experimental data that can provide a better understanding of the basic mechanisms at work in a methane hydrate reservoir that is under production. To this end, a thorough physical understanding of underlying phenomena associated with methane hydrate production will be acquired through unique, multi-scale experiments and associated analyses. In addition, one or more mathematical models that account for the observed phenomena and provide insights that may help to optimize methane hydrate production methods will be developed. Performers Georgia Tech Research Corporation, Atlanta, Georgia 30332 Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee 37831

368

Development of Al-stabilized CaOnickel hybrid sorbentcatalyst for sorption-enhanced steam methane reforming  

Science Journals Connector (OSTI)

Abstract In this work, Al-stabilized CaONi hybrid sorbentcatalysts integrated in a single particle with various nickel loadings (12, 18 and 25wt% NiO) were developed and tested in cyclic hydrogen production by sorption-enhanced steam methane reforming (SESMR) process. A simple wet-mixing technique based on limestone acidification and two-step calcination was employed to produce hybrid materials with different nickel loadings. All developed materials were characterized by BET, XRD, SEM and TEM and studied during 25 CO2 sorption/regeneration cycles as well as for 10 SESMR cycles. Based on both CO2 sorption and SESMR results, it was concluded that the proposed hybrid sorbentcatalyst with NiO loading of 25wt% led to the best performances: (i) CaO molar conversion is 41.2% at the end of the 25th sorption cycle and (ii) average CH4 conversion and H2 production efficiency during 10 SESMR cycles are remarkable (99.1% and 96.1%, respectively). For the most efficient hybrid sorbentcatalyst (25wt% NiO), the influence of CH4 flow rate and steam to carbon ratio (S/C) was also investigated, as well as its behavior during long-term cyclic operation of SESMR (30 cycles), where the H2 production time was just limited to pre-breakthrough period. The very efficient performance (average of H2 yield 97.3%) of the proposed hybrid sorbentcatalyst material in long-term operation confirmed its high potential for use in SESMR process.

Hamid R. Radfarnia; Maria C. Iliuta

2014-01-01T23:59:59.000Z

369

Reaction Pathways and Site Requirements for the Activation and Chemical Conversion of Methane on Ru-Based Catalysts  

E-Print Network (OSTI)

-reactant activation steps. These conclusions suggest that water-gas shift reactions are also equilibrated at Berkeley, Berkeley, California 94720 ReceiVed: June 24, 2003; In Final Form: September 29, 2003 Kinetic mechanistic picture and a unifying kinetic treatment for CH4/CO2 and CH4/H2O reforming reactions and CH4

Iglesia, Enrique

370

Stable isotope and water quality analysis of coal bed methane production waters and gases from the Bowen Basin, Australia  

Science Journals Connector (OSTI)

Coal bed methane (CBM) is a significant growing industry in Queensland's energy sector. It is, however, a relatively new industry with little local water quality data and stable isotope compositions of production waters and gases available in the public domain. This study aims to determine whether water quality and stable isotope data can be correlated with gas and groundwater production and flow pathways, and identify zones of recharge and water mixing. Stable isotope analysis and accessory water quality tests were conducted on CBM production gas and water samples collected from two CBM producing bituminous coal seams within a single field in the Bowen Basin. In the production field, the reservoir seams are gently folded with eastwardly dipping fold axes, and compartmentalised by an ENE normal fault on the flank of a broad central anticline that contains minor faults. For one seam, splitting and a change in coal quality parallels the fault and fold axes. Although virgin reservoir conditions were similar, differing production performance north and south of the main fault suggests it acts as a barrier to water and gas flow along strike. The stable isotope analysis on the production water showed that waters with more positive ?D and ?18O compositions were associated with areas of higher water production and shallower depths, whereas more negative ?D and ?18O compositions were associated with lower water production and high gas production. The gas isotope analysis showed that production gases had both biogenic and thermogenic origins and that secondary biogenic gas generated through CO2 reduction comprises a significant portion of the CBM produced from this field. More negative CH4 ?13C values characterize the zones of meteoric recharge in shallow, up-dip areas. Gas production data and CO2 ?13C values suggest that this may result from 13CH4 stripping by the recharge waters and/or increased biogenic activity in this area. Smaller CO2CH4 carbon isotopic fractionation values characterized zones of meteoric recharge, whereas higher isotopic fractionation values characterized the high gas production domain.

E.C.P. Kinnon; S.D. Golding; C.J. Boreham; K.A. Baublys; J.S. Esterle

2010-01-01T23:59:59.000Z

371

Department of Energy Advance Methane Hydrates Science and Technology Projects  

Energy.gov (U.S. Department of Energy (DOE))

Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

372

New Methane Hydrate Research: Investing in Our Energy Future | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Research: Investing in Our Energy Future Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Jenny Hakun What Are Methane Hydrates? Methane hydrates are 3D ice-lattice structures with natural gas locked inside. The substance looks remarkably like white ice, but it does not behave like ice. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas.

373

Diffusive Accumulation of Methane Bubbles in Seabed  

E-Print Network (OSTI)

We consider seabed bearing methane bubbles. In the absence of fractures the bubbles are immovably trapped in a porous matrix by surface tension forces; therefore the dominant mechanism of transfer of gas mass becomes the diffusion of gas molecules through the liquid. The adequate description of this process requires accounting "other-than-normal" (non-Fickian) diffusion effects, thermodiffusion and gravity action. We evaluate the diffusive flux of aqueous methane and predict the possibility of existence of bubble mass accumulation zones (which can appear independently from the presence/absence of hydrate stability zone) and effect of non-Fickian drift on the capacity of shallow and deep methane-hydrate deposits.

Goldobin, D S; Levesley, J; Lovell, M A; Rochelle, C A; Jackson, P; Haywood, A; Hunter, S; Rees, J

2010-01-01T23:59:59.000Z

374

Atmospheric Neutrinos  

E-Print Network (OSTI)

This paper is a brief overview of the theory and experimental data of atmospheric neutrino production at the fiftieth anniversary of the experimental discovery of neutrinos.

Thomas K. Gaisser

2006-12-11T23:59:59.000Z

375

Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane  

E-Print Network (OSTI)

Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

Green, Michael A.

2005-01-01T23:59:59.000Z

376

Development of water production type curves for horizontal wells in coalbed methane reservoirs.  

E-Print Network (OSTI)

??Coalbed methane is an unconventional gas resource that consists of methane production from the coal seams. The key parameters for the evaluation of coalbed methane (more)

Burka Narayana, Praveen Kumar.

2007-01-01T23:59:59.000Z

377

Tool to predict the production performance of vertical wells in a coalbed methane reservoir.  

E-Print Network (OSTI)

??Coalbed Methane (CBM) is an unconventional gas resource that consists of methane production from coal seams. Coalbed Methane gas production is controlled be interactions of (more)

Enoh, Michael E.

2007-01-01T23:59:59.000Z

378

Atmos. Chem. Phys., 6, 51735182, 2006 www.atmos-chem-phys.net/6/5173/2006/  

E-Print Network (OSTI)

1Laboratory of Atmospheric Pollution and Pollution Control Engineering of Atmospheric Pollutants Abstract. Methane in air and seawater was measured in the Eastern Black Sea during the 10­18 December 1999 fluxes across the air-sea interface. CH4 mixing ratios in air were generally in the 1.8­2.0 ppmv range

Boyer, Edmond

379

Methane Digester Loan Program | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Digester Loan Program Methane Digester Loan Program Methane Digester Loan Program < Back Eligibility Agricultural Savings Category Bioenergy Maximum Rebate RFA can provide up to $250,000 of loan principal Program Info Funding Source Minnesota Rural Finance Authority (RFA) State Minnesota Program Type State Loan Program Rebate Amount RFA participation limited to 45% of loan principal Provider Minnesota Department of Agriculture Established in 1998, the Minnesota Dept. of Agriculture Methane Digester Loan Program helps livestock producers install on-farm anaerobic digesters used for the production of electricity by providing zero-interest loans to eligible borrowers. The loan program is part of the Rural Finance Authority (RFA) revolving loan fund, through which farmers can receive financial aid

380

Methane Hydrate Program Annual Report to Congress  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FY 2010 FY 2010 Methane Hydrate Program Annual Report to Congress September 2011 U.S. Department of ENERGY United States Department of Energy Washington, DC 20585 Department of Energy | September 2011 FY 2010 Methane Hydrate Program Annual Report to Congress | Page 2 Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled, U.S. Department of Energy FY 2010 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 ESD05-048 Goal The project is bringing new laboratory measurements and evaluation techniques to bear on the difficult problems of characterization and gas recovery from methane hydrate deposits. Performer Lawrence Berkeley National Laboratory, Berkeley, CA 94720 Background LBNL is performing laboratory tests to provide data to support the characterization and development of methane hydrate deposits. Major areas of research underway include hydrologic measurements, combined geomechanical/geophysical measurements, and synthetic hydrate formation studies. Hydrologic Measurements Relatively little research has been done to experimentally determine

382

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection and Microbiological Analysis of Gas Hydrate Cores Collection and Microbiological Analysis of Gas Hydrate Cores FWP-4340-60 and FWP-42C1-01 Goal Determine the presence and activity of methanogens in methane hydrate-bearing sediments. Background The project was set up to determine a fundamental modeling parameter - the amount of methane generated in deep sediments by methanogenic microorganisms. This would allow methane distribution models of gas hydrate reservoirs to accurately reflect an unknown volume and the distribution of biogenic methane within in a reservoir. The personnel at INEL have experience in similar biologic research and are considered to be experts by their global peers. Performer Idaho National Engineering and Environmental Laboratory (INEEL) - sample collection and analysis Location

383

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Seismic-Scale Rock Physics of Methane Hydrate Seismic-Scale Rock Physics of Methane Hydrate DE-FC26-05NT42663 Goal The goal of this project was to establish rock physics models for use in generating synthetic seismic signatures of methane hydrate reservoirs. Ultimately, the intent was to improve seismic detection and quantification of offshore and onshore methane hydrate accumulations. Performer Stanford University, Stanford, CA 94305 Background Gas hydrate reservoir characterization is, in principle, no different from traditional hydrocarbon reservoir characterization. The seismic response of the subsurface is determined by the spatial distribution of the elastic properties (properties of the subsurface that deform as seismic waves pass through it) and attenuation. By mapping changes in the elastic properties, scientists can identify geologic features, including hydrocarbon reservoirs.

384

methane_hydrates | netl.doe.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

hydrate and its potential as a fuel source, please read the 2011 Methane Hydrates Primer. Information on other elements of the program can be found under the links below. Fire...

385

Hydraulic fracturing accelerates coalbed methane recovery  

SciTech Connect

Methane production from deep coal seams that never will be mined requires hydraulic fracturing for faster, optimal recovery. Since this can be a complex process, proper formation evaluation beforehand is essential, according to this paper.

Holditch, S.A. (Texas A and M Univ. (US)); Ely, J.W.; Semmelbeck, M.E.; Carter, R.H. (S.A. Holditch and Associates (US)); Hinkel, J.J.; Jeffrey, R.G. Jr. (Dowell Schlumberger (US))

1990-11-01T23:59:59.000Z

386

Mikrobiologie und kophysiologie des Methan-Kreislaufs  

Science Journals Connector (OSTI)

Methan ist ein Spurengas in der Atmosphre (1,8 ppmv), dessen Konzentration aufgrund von anthropogenen Aktivitten jhrlich mit etwa 0,51% zunimmt. Es wird zusammen mit CO2, N2O (Lachgas), O3 (Ozon) und Fluorchl...

Professor em. Dr. sc. agr. habil. Johannes C. G. Ottow

2011-01-01T23:59:59.000Z

387

Virginia Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

388

Oklahoma Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

389

Montana Coalbed Methane Production (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

Production (Billion Cubic Feet) Montana Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 12 12 13...

390

Virginia Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Virginia Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 56 81...

391

Pennsylvania Coalbed Methane Proved Reserves Revision Decreases...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

392

Colorado Coalbed Methane Production (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

Production (Billion Cubic Feet) Colorado Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 12...

393

Alabama Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Production (Billion Cubic Feet) Alabama Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 23...

394

Wyoming Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Wyoming Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 133 278...

395

Virginia Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

396

Arkansas Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

397

Kansas Coalbed Methane Production (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

Production (Billion Cubic Feet) Kansas Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 17 25 38...

398

Colorado Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

399

Oklahoma Coalbed Methane Production (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

Production (Billion Cubic Feet) Oklahoma Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 58 68...

400

Arkansas Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Production (Billion Cubic Feet) Arkansas Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 2 3 3 3...

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Pennsylvania Coalbed Methane Proved Reserves Revision Increases...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

402

Virginia Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

403

Colorado Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

404

Oklahoma Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

405

Montana Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Montana Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

406

Wyoming Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

407

Utah Coalbed Methane Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Production (Billion Cubic Feet) Utah Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 74 83 103...

408

Wyoming Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

409

Arkansas Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

410

Oklahoma Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

411

Miscellaneous States Coalbed Methane Proved Reserves Adjustments...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

412

Pennsylvania Coalbed Methane Production (Billion Cubic Feet)  

Annual Energy Outlook 2012 (EIA)

Production (Billion Cubic Feet) Pennsylvania Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 3 5...

413

Oklahoma Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

414

Pennsylvania Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

415

Colorado Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

416

Arkansas Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

417

Colorado Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

418

Oklahoma Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

419

Colorado Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

420

Arkansas Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Virginia Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

422

Pennsylvania Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

423

Processes for Methane Production from Gas Hydrates  

Science Journals Connector (OSTI)

The main cost here is only that of the pipeline used to transport the gas to the production platform. For subsea systems that do not ... group of wells. Transporting methane from the production site to the shore ...

2010-01-01T23:59:59.000Z

424

Methane Hydrates R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

abundance suggest that they contain perhaps more organic carbon that all the world's oil, gas, and coal combined. The primary mission of the Methane Hydrates R&D Program is to...

425

The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification  

E-Print Network (OSTI)

steam methane reforming .H 2 O ? CO 2 + H 2 Steam methane reforming reaction: CH 4 +by the SMR (Steam Methane Reforming) step and a final step

Luo, Qian

2012-01-01T23:59:59.000Z

426

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network (OSTI)

+ H 2 -41 MJ/kmol Steam methane reforming reaction CH 4 + Htechnologies such as steam methane reforming, gas shiftingand preparation, steam methane reforming and FT synthesis,

Lu, Xiaoming

2012-01-01T23:59:59.000Z

427

Marine methane cycle simulations for the period of early global warming  

SciTech Connect

Geochemical environments, fates, and effects are modeled for methane released into seawater by the decomposition of climate-sensitive clathrates. A contemporary global background cycle is first constructed, within the framework of the Parallel Ocean Program. Input from organics in the upper thermocline is related to oxygen levels, and microbial consumption is parameterized from available rate measurements. Seepage into bottom layers is then superimposed, representing typical seabed fluid flow. The resulting CH{sub 4} distribution is validated against surface saturation ratios, vertical sections, and slope plume studies. Injections of clathrate-derived methane are explored by distributing a small number of point sources around the Arctic continental shelf, where stocks are extensive and susceptible to instability during the first few decades of global warming. Isolated bottom cells are assigned dissolved gas fluxes from porous-media simulation. Given the present bulk removal pattern, methane does not penetrate far from emission sites. Accumulated effects, however, spread to the regional scale following the modeled current system. Both hypoxification and acidification are documented. Sensitivity studies illustrate a potential for material restrictions to broaden the perturbations, since methanotrophic consumers require nutrients and trace metals. When such factors are considered, methane buildup within the Arctic basin is enhanced. However, freshened polar surface waters act as a barrier to atmospheric transfer, diverting products into the deep return flow. Uncertainties in the logic and calculations are enumerated including those inherent in high-latitude clathrate abundance, buoyant effluent rise through the column, representation of the general circulation, and bacterial growth kinetics.

Elliott, S.; Maltrud, M.; Reagan, M.T.; Moridis, G.J.; Cameron-Smith, P.J.

2011-01-02T23:59:59.000Z

428

Atmospheric tritium  

SciTech Connect

Research progress for the year 1979 to 1980 are reported. Concentrations of tritiated water vapor, tritium gas and tritiated hydrocarbons in the atmosphere at selected sampling points are presented. (ACR)

Oestlund, H.G.; Mason, A.S.

1980-01-01T23:59:59.000Z

429

Quantifying sources of methane using light alkanes in the Los Angeles basin, California  

E-Print Network (OSTI)

Air Resources Board (CARB) was tasked with compiling and verifying an inventory of GHG emissions of CH4 emissions in the region coming from fugitive losses from natural gas in pipelines and urban recent works have estimated CH4 emissions to the South Coast Air Basin (SoCAB; Figure 1a), which

Cohen, Ronald C.

430

The ebullition of hydrogen, carbon monoxide, methane, carbon dioxide and total gaseous mercury  

E-Print Network (OSTI)

of gaseous species depends of their solubility in the water. Since CH4 is relatively insoluble, ebullition-product of the respiration and is highly soluble in the water, leading ofte h- 1 . Measurements of H2, CO, CH4 and CO2 trapped gas concentrations and fluxes were used

O'Driscoll, Nelson

431

Methane Power Inc | Open Energy Information  

Open Energy Info (EERE)

Methane Power Inc Methane Power Inc Jump to: navigation, search Logo: Methane Power Inc. Name Methane Power Inc. Address 121 Edinburgh South Drive Place Cary, NC Zip 27511 Sector Renewable Energy Product Methane Power is a renewable energy project developer that focuses on landfill gas-to-energy projects. Currently, they are a supplier of landfill gas generated energy to Duke Energy in North Carolina. Phone number 919-297-7206 Website http://www.methanepower.net Coordinates 35.7395875°, -78.8029226° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.7395875,"lon":-78.8029226,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

432

Carbon deposition in steam reforming and methanation  

SciTech Connect

The purpose of this review is to survey recent studies of carbon deposition on metals used as catalysts in steam reforming and methanation, emphasizing research where significant progress has been made. Where possible, an attempt is made to treat the fundamental nature of carbon formation and deactivation by carbon and the relationships between these two phenomena. Steam reforming and methanation are emphasized in this review because (1) deactivation of catalysts by carbon deposits is a serious concern in both processes, (2) much of the previous research with carbon formation on metals involved one or the other of these two reactions, and (3) there are interesting differences and similarities between these two reactions; for example, methanation is typically carried out at moderate reaction temperatures (200-450/sup 0/C) while steam reforming is typically carried out at significantly higher reaction temperatures (600-900/sup 0/C). Yet the two reactions are very closely related, since methane steam reforming is the reverse of methanation of CO. Moreover, there is evidence that some of the carbons formed in these two different processes are similar in their morphology.

Bartholomew, C.H.

1982-01-01T23:59:59.000Z

433

Natural Gas Infrastructure R&D and Methane Emissions Mitigation...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12, 2014 11:00AM EST to...

434

Ohio Coalbed Methane Proved Reserves (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Ohio Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

435

U.S. Coalbed Methane Proved Reserves (Billion Cubic Feet)  

NLE Websites -- All DOE Office Websites (Extended Search)

Coalbed Methane Proved Reserves (Billion Cubic Feet) U.S. Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

436

Louisiana--North Coalbed Methane Proved Reserves (Billion Cubic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Louisiana--North Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

437

Texas--RRC District 4 Onshore Coalbed Methane Proved Reserves...  

Gasoline and Diesel Fuel Update (EIA)

4 Onshore Coalbed Methane Proved Reserves (Billion Cubic Feet) Texas--RRC District 4 Onshore Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

438

Louisiana (with State Offshore) Coalbed Methane Proved Reserves...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Louisiana (with State Offshore) Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

439

Texas--RRC District 2 Onshore Coalbed Methane Proved Reserves...  

Annual Energy Outlook 2012 (EIA)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Texas--RRC District 2 Onshore Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

440

Eastern States Coalbed Methane Production (Billion Cubic Feet...  

Gasoline and Diesel Fuel Update (EIA)

Coalbed Methane Production (Billion Cubic Feet) Eastern States Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Western States Coalbed Methane Production (Billion Cubic Feet...  

Gasoline and Diesel Fuel Update (EIA)

Western States Coalbed Methane Production (Billion Cubic Feet) Western States Coalbed Methane Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

442

Texas--RRC District 10 Coalbed Methane Proved Reserves (Billion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Texas--RRC District 10 Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

443

Alabama Coalbed Methane Proved Reserves (Billion Cubic Feet)  

NLE Websites -- All DOE Office Websites (Extended Search)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Alabama Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

444

Colorado Coalbed Methane Proved Reserves (Billion Cubic Feet...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coalbed Methane Proved Reserves (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

445

Methane Adsorption and Dissociation and Oxygen Adsorption and...  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

446

Spatial Heterogeneity of Methane Ebullition in a Large Tropical Reservoir  

Science Journals Connector (OSTI)

Data was postprocessed using Sonar 5 Pro (Lindem Acquisition, Norway). ... Surface water CH4 concentrations were highly variable within individual bays and tended to decrease in the offshore direction. ... Mungwena, W.The distribution and potential utilizablity of Zimbabwes wind energy resource Renewable Energy 2002, 26, 363 377 ...

Tonya DelSontro; Manuel J. Kunz; Tim Kempter; Alfred West; Bernhard Wehrli; David B. Senn

2011-10-10T23:59:59.000Z

447

NETL: Methane Hydrates - Gas Hydrate Research in Deep Sea Sediments - New  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrate Research in Deep Sea Sediments - Chatham Rise, New Zealand Task Last Reviewed 12/30/2013 Hydrate Research in Deep Sea Sediments - Chatham Rise, New Zealand Task Last Reviewed 12/30/2013 DE-AI26-06NT42878 Goal The goal of the Interagency Agreement between the National Energy Technology Laboratory and the Naval Research Laboratory is to conduct research to enhance understanding of the extent and dynamics of gas hydrate deposits and their relation to areas of focused fluid flux at and beneath the seafloor. Performer Marine Biogeochemistry Section, Naval Research Laboratory, Washington, DC 20375 Background Methane is a potent greenhouse gas necessitating a better understanding of the mechanisms controlling its contribution to the atmospheric carbon cycle. Active methane fluxes (from deep sediment hydrates and seeps) contribute to shallow sediment biogeochemical carbon cycles, which in turn

448

Hydrogen production from methane dry reforming over nickel-based nanocatalysts using surfactant-assisted or polyol method  

Science Journals Connector (OSTI)

Abstract In this study, two series of Ni-based nanocatalysts were synthesized successfully by the polyol and surfactant-assisted methods and subsequently tested for hydrogen production from CO2CH4 reforming. Surfactant-assisted catalysts were prepared by using cetyl trimethyl ammonium bromide (CTAB) as a surfactant, whereas polyol catalysts were prepared in ethylene glycol (EG) medium with polyvinylpyrrolidone (PVP) as a nucleation-protective agent. The catalytic performance of each catalyst, in terms of H2 yield and selectivity, was evaluated at different temperatures (500800C). In order to clarify and explain the differences in catalytic activities of catalysts, the prepared samples were characterized by various techniques, such as BET, H2-TPR, CO2-TPD, XRD, TGA, SEM, HRTEM and CO pulse chemisorption. The results demonstrated that the method of preparation had a significant effect on the catalytic performance of tested catalysts. Overall, polyol catalysts showed high activity and selectivity for hydrogen production, while surfactant-assisted catalysts exhibited a fairly high resistance towards carbon deposition under similar reaction conditions of dry reforming of methane. Moreover, due to the reverse water gas shift reaction (RWGS), surfactant-assisted catalysts always produced smaller values of H2/CO product ratio than their corresponding polyol catalysts.

Muhammad Awais Naeem; Ahmed Sadeq Al-Fatesh; Anis Hamza Fakeeha; Ahmed Elhag Abasaeed

2014-01-01T23:59:59.000Z

449

Direct use of methane in coal liquefaction  

DOE Patents (OSTI)

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20-120 minutes at a temperature of 250.degree.-750.degree. C., preferably 350.degree.-450.degree. C., pressurized up to 6000 psi, and preferably in the 1000-2500 psi range, preferably directly utilizing methane 50-100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0-100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems.

Sundaram, Muthu S. (Shoreham, NY); Steinberg, Meyer (Melville, NY)

1987-01-01T23:59:59.000Z

450

Direct use of methane in coal liquefaction  

DOE Patents (OSTI)

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20 to 120 minutes at a temperature of 250 to 750/sup 0/C, preferably 350 to 450/sup 0/C, pressurized up to 6000 psi, and preferably in the 1000 to 2500 psi range, preferably directly utilizing methane 50 to 100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0 to 100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems. 1 fig.

Sundaram, M.S.; Steinberg, M.

1985-06-19T23:59:59.000Z

451

MethaneHydrateRD_FC.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

gas is an important energy gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy (FE) has played a major role in developing technologies to help tap new, unconventional sources of natural gas. FOSSIL ENERGY RESEARCH BENEFITS Methane Hydrate R&D "The (DOE) Program has supported and managed a high-quality research portf olio that has enabled signifi cant progress toward the (DOE) Program's long-term goals." The Nati onal Academies 2010 One of these is methane hydrate - molecules of natural gas trapped in ice crystals. Containing vast amounts of natural gas, methane hydrate occurs in a variety of forms in sediments within and below thick permafrost in Arctic regions, and in the

452

Numerical analysis of an internal methane reforming solid oxide fuel cell with fuel recycling  

Science Journals Connector (OSTI)

The development of solid oxide fuel cell (SOFC) systems capable of direct internal reforming (DIR) of methane is being actively pursued. However, a major challenge with current state-of-the-art nickel-based anodes is their propensity to form deteriorous carbon deposits in DIR, unless excess steam is introduced in the fuel. Reduced fuel humidification levels are desirable from the viewpoints of cell performance, reliability and plant economics. This study explores the use of partial recycling of the anode exhaust as a mitigation strategy against carbon deposits at fuel steam-to-carbon ratios less than unity. Using a detailed computational fluid dynamics (CFD) model which couples momentum, heat, mass and charge transport with electrochemical and chemical reactions, the spatial extent of carbon deposition within a SOFC anode is analyzed by accounting for both the cracking and Boudouard reactions, for several fuel humidification and recycling conditions. At temperatures of approximately 1173K and for inlet fuel molar H2O/CH4 ratios between 0.5 and 1, 50% (mass%) fuel recycling is found to be an effective strategy against carbon deposition. For lower recycling levels at the same fuel compositions, or lower fuel humidification levels (regardless of the recycling level), fuel recycling reduces the risk of coking, but does not eliminate it. The analyses presented suggest that recycling of the anodic fuel stream could help extend the operational range of DIR-SOFCs to lower fuel humidification levels than typically considered, with reduced risks of carbon deposits, while reducing system cost and complexity in terms of steam production. For dry or weakly humidified fuels, additional mitigation strategies would be required.

Valrie Eveloy

2012-01-01T23:59:59.000Z

453

Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer (OSTI)

CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

454

Summary Much attention is focused today on predicting how plants will respond to anticipated changes in atmospheric  

E-Print Network (OSTI)

, such as methane, became oxidized to form an early CO2-rich atmosphere. Over time, the concentration of carbon the atmosphere. Burial and lithification of carbonates and organic matter to limestone, coal or keragen the detailed history of CO2 is not well known for the whole of earth's history, some periods are reasonably

Ehleringer, Jim

455

Measurements of Methane Emissions at Natural Gas Production Sites  

E-Print Network (OSTI)

Measurements of Methane Emissions at Natural Gas Production Sites in the United States #12;Why = 21 #12;Need for Study · Estimates of methane emissions from natural gas production , from academic in assumptions in estimating emissions · Measured data for some sources of methane emissions during natural gas

Lightsey, Glenn

456

Gravimetric study of adsorbed intermediates in methanation of carbon monoxide  

SciTech Connect

The purpose of this study is to more fully elucidate the adsorbed intermediates and mechanism involved in catalytic methanation of CO on a typical nickel methanation catalyst. Rates of adsorption and desorption of surface species and of gasification of carbon were measured gravimetrically to determine their kinetics and possible roles in methanation. 19 refs.

Gardner, D.C.; Bartholomew, C.H.

1981-08-01T23:59:59.000Z

457

METHANE IN SUBSURFACE: MATHEMATICAL MODELING AND COMPUTATIONAL CHALLENGES  

E-Print Network (OSTI)

advanced models of adsorption occuring in coalbed methane recovery processes, and discuss the underlying methods, hysteresis, coalbed methane, mean-field equi- librium models AMS(MOS) subject classifications. 76 applications important for global climate and energy studies, namely Enhanced Coalbed Methane (ECBM) recovery

Peszynska, Malgorzata

458

Methane in lakes and wetlands Microbiological production, ecosystem  

E-Print Network (OSTI)

Methane in lakes and wetlands Microbiological production, ecosystem uptake, climatological significance LAKES AND WETLANDS ­ A RELEVANT METHANE SOURCE Lakes and other wetlands are an important source methane from wetlands will respond to future climatic change. Dr. Paul Bodelier (Netherlands Institute

Mühlemann, Oliver

459

Detection and Production of Methane Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

July-September 2007 July-September 2007 Detection and Production of Methane Hydrate Submitted by: Rice University University of Houston George J. Hirasaki Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; FAX: 713-348-5478; Email: gjh@rice.edu Prepared for: United States Department of Energy National Energy Technology Laboratory December, 2007 Office of Fossil Energy Table of Contents DOE Methane Hydrate Program Peer Review.................................................. 3 Task 5: Carbon Inputs and Outputs to Gas Hydrate Systems ........................... 3 Task 6: Numerical Models for Quantification of Hydrate and Free Gas Accumulations....................................................................................................

460

E-Print Network 3.0 - anaerobic carbon metabolism Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

1 Two-Phase Production of H2CH4 Mixtures An anaerobic digestion process to produce hydrogen and methane (CH4) in Summary: Two-Phase Production of H2CH4 Mixtures An anaerobic...

Note: This page contains sample records for the topic "atmospheric methane ch4" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Unconventional gas resources. [Eastern Gas Shales, Western Gas Sands, Coalbed Methane, Methane from Geopressured Systems  

SciTech Connect

This document describes the program goals, research activities, and the role of the Federal Government in a strategic plan to reduce the uncertainties surrounding the reserve potential of the unconventional gas resources, namely, the Eastern Gas Shales, the Western Gas Sands, Coalbed Methane, and methane from Geopressured Aquifers. The intent is to provide a concise overview of the program and to identify the technical activities that must be completed in the successful achievement of the objectives.

Komar, C.A. (ed.)

1980-01-01T23:59:59.000Z

462

File:Methane.pdf | Open Energy Information  

Open Energy Info (EERE)

Methane.pdf Methane.pdf Jump to: navigation, search File File history File usage File:Methane.pdf Size of this preview: 448 × 600 pixels. Go to page 1 2 3 4 5 Go! next page → next page → Full resolution ‎(1,218 × 1,630 pixels, file size: 929 KB, MIME type: application/pdf, 5 pages) File history Click on a date/time to view the file as it appeared at that time. Date/Time Thumbnail Dimensions User Comment current 15:51, 9 February 2012 Thumbnail for version as of 15:51, 9 February 2012 1,218 × 1,630, 5 pages (929 KB) Graham7781 (Talk | contribs) You cannot overwrite this file. Edit this file using an external application (See the setup instructions for more information) File usage The following page links to this file: Hydraulic Fracturing Retrieved from "http://en.openei.org/w/index.php?title=File:Methane.pdf&oldid=404017"

463

Hydroelectric Reservoirs -the Carbon Dioxide and Methane  

E-Print Network (OSTI)

Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

Fischlin, Andreas

464

High Temperature Solar Splitting of Methane  

E-Print Network (OSTI)

-term commercialization opportunities #12;Why Use Solar Energy?Why Use Solar Energy? · High concentrations possible (>1000High Temperature Solar Splitting of Methane to Hydrogen and Carbon High Temperature Solar Splitting and worldwide) ­ Sufficient to power the world (if we choose to) · Advantages tradeoff against collection area

465

California - Coastal Region Coalbed Methane Proved Reserves ...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 0 0 0 0 2010's 0 0 0 0 - No Data...

466

Generating power with drained coal mine methane  

SciTech Connect

The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

NONE

2005-09-01T23:59:59.000Z

467

Formation and retention of methane in coal  

SciTech Connect

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

468

Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water  

SciTech Connect

Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

Song Jin

2007-05-31T23:59:59.000Z

469

Coal Bed Methane Protection Act (Montana) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coal Bed Methane Protection Act (Montana) Coal Bed Methane Protection Act (Montana) Coal Bed Methane Protection Act (Montana) < Back Eligibility Utility Fed. Government Commercial Agricultural Investor-Owned Utility State/Provincial Govt Industrial Construction Municipal/Public Utility Local Government Rural Electric Cooperative Tribal Government Institutional Fuel Distributor Program Info State Montana Program Type Environmental Regulations Provider Montana Department of Natural Resources and Conservation The Coal Bed Methane Protection Act establishes a long-term coal bed methane protection account and a coal bed methane protection program for the purpose of compensating private landowners and water right holders for damage to land and to water quality and availability that is attributable to the development of coal bed methane wells. The Act aims to provide for

470

Methane Hydrates - The National R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program The National Methane Hydrates R&D Program Welcome to the information portal for the National Methane Hydrate R&D Program. Over the past eight years, research carried out under this program has resulted in significant advances in our understanding of methane hydrates, their role in nature, and their potential as a future energy resource. This success is largely due to an unprecedented level of cooperation between federal agencies, industry, national laboratories, and academic institutions. For a quick introduction to methane hydrate and its potential as a fuel source, please read the 2011 Methane Hydrates Primer. Information on other elements of the program can be found under the remaining Key Links. Read More.

471

Regulation of methane genes and genome expression  

SciTech Connect

At the start of this project, it was known that methanogens were Archaeabacteria (now Archaea) and were therefore predicted to have gene expression and regulatory systems different from Bacteria, but few of the molecular biology details were established. The goals were then to establish the structures and organizations of genes in methanogens, and to develop the genetic technologies needed to investigate and dissect methanogen gene expression and regulation in vivo. By cloning and sequencing, we established the gene and operon structures of all of the methane genes that encode the enzymes that catalyze methane biosynthesis from carbon dioxide and hydrogen. This work identified unique sequences in the methane gene that we designated mcrA, that encodes the largest subunit of methyl-coenzyme M reductase, that could be used to identify methanogen DNA and establish methanogen phylogenetic relationships. McrA sequences are now the accepted standard and used extensively as hybridization probes to identify and quantify methanogens in environmental research. With the methane genes in hand, we used northern blot and then later whole-genome microarray hybridization analyses to establish how growth phase and substrate availability regulated methane gene expression in Methanobacterium thermautotrophicus ?H (now Methanothermobacter thermautotrophicus). Isoenzymes or pairs of functionally equivalent enzymes catalyze several steps in the hydrogen-dependent reduction of carbon dioxide to methane. We established that hydrogen availability determine which of these pairs of methane genes is expressed and therefore which of the alternative enzymes is employed to catalyze methane biosynthesis under different environmental conditions. As were unable to establish a reliable genetic system for M. thermautotrophicus, we developed in vitro transcription as an alternative system to investigate methanogen gene expression and regulation. This led to the discovery that an archaeal protein, designated TFE, that had sequences in common with the eukaryotic general transcription factor TFIIE, stimulated archaeal transcription initiation and that the archaeal TATA-box binding protein (TBP) remained attached to the promoter region whereas the transcription factor TFB dissociated from the template DNA following initiation. DNA sequences that directed the localized assembly of archaeal histones into archaeal nucleosomes were identified, and we established that transcription by an archaeal RNA polymerase was slowed but not blocked by archaeal nucleosomes. We developed a new protocol to purify archaeal RNA polymerases and with this enzyme and additional improvements to the in vitro transcription system, we established the template requirements for archaeal transcription termination, investigated the activities of proteins predicted to be methane gene regulators, and established how TrpY, a novel archaeal regulator of expression of the tryptophan biosynthetic operon functions in M. thermautotrophicus. This also resulted in the discovery that almost all M. thermautotrophicus mutants isolated as spontaneously resistant to 5-methyl tryptophan (5MTR) had mutations in trpY and were therefore 5MTR through de-repressed trp operon expression. This established a very simple, practical procedure to determine and quantify the DNA sequence changes that result from exposure of this Archaeon to any experimental mutagenesis protocol. Following the discovery that the Thermococcus kodakaraensis was amenable to genetic manipulation, we established this technology at OSU and subsequently added plasmid expression, a reporter system and additional genetic selections to the T. kodakaraensis genetic toolbox. We established that transcription and translation are coupled in this Archaeon, and by combining in vitro transcription and in vivo genetics, we documented that both TFB1 and TFB2 support transcription initiation in T. kodakaraensis. We quantified the roles of ribosome binding sequences and alternative initiation codons in translation initiation, established that polarity e

John N. Reeve

2009-09-09T23:59:59.000Z

472

Atmos. Chem. Phys., 11, 88098823, 2011 www.atmos-chem-phys.net/11/8809/2011/  

E-Print Network (OSTI)

of the particulate matter were carbonaceous materials, such as humic acid, water sol- uble organics, and less soluble in public concern regarding the emission of atmospheric pollutants, including gas phase and particulate from livestock include methane (CH4), ammonia (NH3), nitrogen oxides (NOx), and nitrous oxide (N2O

Meskhidze, Nicholas

473

Calculations for methane scattering from LiF(001)  

Science Journals Connector (OSTI)

Calculations are presented for the scattering of CH4 molecules from a LiF(001) surface. The theory utilized is a mixed classical-quantum model that includes energy and momentum transfers between the surface and projectile for translational and rotational motions as well as internal mode excitation of the projectile molecule. The translation and rotation motions, including multiphonon excitations with the surface, are treated with classical dynamics. Internal vibrational mode excitation of the molecules is treated quantum mechanically with extension to arbitrary numbers of modes and arbitrary excitation quantum numbers. The results of calculations are compared with recent high-precision measurements of the scattering of CH4 molecules from clean, ordered LiF(001). The calculated results for energy-resolved spectra and for the angular distributions are in good agreement with experiment.

Iryna Moroz and J. R. Manson

2004-05-19T23:59:59.000Z

474

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 DE-FC26-01NT41329 photo of a man showing the pressure core sampler on the deck of JOIDES Resolution Pressure core sampler on deck courtesy Texas A&M University Goal The goal of the project was to characterize hydrate accumulation at Hydrate Ridge (offshore Oregon) and improve the ability to use geophysical and subsurface logging to identify hydrates. A follow-on goal was to characterize hydrate accumulation at offshore Vancouver Island, BC, Canada. Background This project focused on physically verifying the existence of hydrates at Hydrate Ridge through the collection of pressurized and non-pressurized core samples and logging data. This study developed and tested tools to

475

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 DE-FC26-06NT42960 Goal The goal of this project is to improve the understanding of regional and local differences in gas hydrate systems from three perspectives: as an energy resource, as a geohazard, and as a long-term influence on global climate. Performers Rice University, Houston, TX University of Texas, Austin, TX Oklahoma State University, Stillwater, OK Background Heterogeneity in the distribution of gas hydrate accumulations impacts all aspects of research into gas hydrate natural systems. The challenge is to delineate, understand, and appreciate these differences at the regional and local scales, where differences in in situ concentrations are relevant to the importance of gas hydrate as a resource, a geohazard, and a factor in

476

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

- Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 - Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 Project Goals The primary goals of the DOE/NETL Natural Gas Hydrate Field Studies (NGHFS) project are: Conduct field-based studies that advance the ability to predict, detect, characterize, and understand distribution of and controls on natural gas hydrate occurrences. Analyze geologic, geochemical, and microbiologic data for indications of past and current changes to the stability of natural gas hydrate in marine settings. Develop links between the U.S. Gas Hydrate Program and international R&D efforts through direct participation in international field programs and workshops. Evaluate the potential role natural gas hydrates may play in the global carbon cycle through analysis of modern and paleo-natural gas

477

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

– Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 – Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 Project Objective Observe hydrate formation and dissociation phenomena in various porous media and characterize hydrate-bearing sediments by estimating physical properties (kinetic parameters for hydrate formation and dissociation, thermal conductivity, permeability, relative permeability, and mechanical strength) to enhance fundamental understanding on hydrate formation and accumulation and to support numerical simulations and potential gas hydrate production Project Performers Yongkoo Seol – NETL Office of Research & Development Jeong Choi – Oak Ridge Institute for Science and Education Jongho Cha-Virginia Polytech Institute Project Location National Energy Technology Laboratory - Morgantown, West Virginia

478

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields DE-FC26-06NT42962 Goal The goal of this project is to characterize and quantify the postulated gas hydrate resource associated with the Barrow Gas Fields – three producing fields located in a permafrost region near Barrow, the North Slope's biggest population center and economic hub. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Performers North Slope Borough, Barrow, Alaska (North Slope Borough) 99723

479

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 DE-FC26-01NT41331 photo of new Anadarko drilling rig in place at Hot Ice No.1 on Alaska's North Slope Hot Ice No. 1 Drilling Platform courtesy Anadarko Petroleum Corp. Goal The goal of the project was to develop technologies for drilling and recovering hydrates in arctic areas. The specific objectives were to drill, core, and test a well through the hydrate stability zone in northern Alaska Performers Maurer Technology, Inc.* - Project coordination with DOE Anadarko Petroleum Corporation - Overall project management for the design, construction, and operation of the Arctic Drilling Platform and mobile core lab, and field coring operations Noble Engineering and Development* - Real time data collection and

480

Detection and Production of Methane Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

Oil & Natural Gas Technology Oil & Natural Gas Technology DOE Award No.: DE-FC26-06NT42960 Quarterly Progress Report Reporting Period: April-June 2007 Detection and Production of Methane Hydrate Submitted by: Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Prepared for: United States Department of Energy National Energy Technology Laboratory August, 2007 Office of Fossil Energy Detection and Production of Methane Hydrate Quarterly Progress Report Reporting Period: April-June 2007 Prepared by: George Hirasaki Rice University August 2007 CONTRACT NO. DE-FC26-06NT42960 Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; Fax: 713-348-5478; Email: gjh@rice.edu

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481

Methane Hydrate Field Studies | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Field Studies Field Studies Methane Hydrate Field Studies Arctic/Alaska North Slope Field Studies Since 2001, DOE has conducted field trials of exploration and production technology in the Alaska North Slope. Although Alaska methane hydrate resources are smaller than marine deposits and currently lack outlets to commercial markets, Alaska provides an excellent laboratory to study E&P technology. The research also has implications for various Alaska resources, including potential gas hydrate resources for local communities, conventional "stranded" gas, as well as Alaska's large unconventional oil resources. The hydrate deposits have been delineated in the process of developing underlying oil fields, and drilling costs are much lower than offshore. DOE-BP Project

482

Enhanced carbon monoxide utilization in methanation process  

DOE Patents (OSTI)

Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

Elek, Louis F. (Peekskill, NY); Frost, Albert C. (Congers, NY)

1984-01-01T23:59:59.000Z

483

Alternative technologies to steam-methane reforming  

SciTech Connect

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

484

Carbon dioxide adsorption and methanation on ruthenium  

SciTech Connect

The adsorption and methanation of carbon dioxide on a ruthenium-silica catalyst were studied using temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR). Carbon dioxide adsorption was found to be activated; CO/sub 2/ adsorption increased significantly as the temperature increased from 298 to 435 K. During adsorption, some of the CO/sub 2/ dissociated to carbon monoxide and oxygen; upon hydrogen exposure at room temperature, the oxygen reacted to water. Methanation of adsorbed CO and of adsorbed CO/sub 2/, using TPR in flowing hydrogen, yielded a CH/sub 4/ peak with a peak temperature of 459 K for both adsorbates, indicating that both reactions follow the same mechanism after adsorption. This peak temperature did not change with initial surface coverage of CO, indicating that methanation is first order in CO coverage. The desorption and reaction spectra for Ru/SiO/sub 2/ were similar to those previously obtained for Ni/SiO/sub 2/, but both CO/sub 2/ formation and CH/sub 4/ formation proceeded faster on Ru. Also, the details of CO desorption and the changes in CO/sub 2/ and CO desorptions with initial coverage were different on the two metals. 5 figures, 3 tables.

Zagli, E.; Falconer, J.L.

1981-05-01T23:59:59.000Z

485

Radiative forcing due to changes in ozone and methane caused by the transport sector  

E-Print Network (OSTI)

and indirect aerosol effect from SHIP (Balkanski et al. ,effect of O 3 and CH 4 amounting to 42 mW m 2 for ROAD, 11 mW m 2 for SHIP and

2011-01-01T23:59:59.000Z

486

Hollow fiber membrane process for the pretreatment of methane hydrate from landfill gas  

Science Journals Connector (OSTI)

Abstract Landfill gas is major source of green house effect because it is mainly composed of CH4 and CO2. Especially, the separation of CH4 from landfill gas was studied actively due to its high heating value which can be used for energy resource. In this study, polymeric hollow fiber membrane was produced by drywet phase inversion method to separate CH4 from the landfill gas. The morphology of the membranes was examined by scanning electron microscopy (SEM) to understand and correlate the morphology with the performance of the membrane. Firstly, single gas permeation and mixed gas separation were performed in lab-scale. After then, a pilot scale membrane process was designed using a simulation program. The manufactured process settled in Gyeong-ju landfill site and operated at various conditions. As a result, CH4 was concentrated to 88vol.% and also CO2 removal efficiency increases up to 86.7%.

KeeHong Kim; WonKil Choi; HangDae Jo; JongHak Kim; Hyung Keun Lee

2014-01-01T23:59:59.000Z

487

International Cooperation in Methane Hydrates | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oil & Gas » Methane Hydrate » Oil & Gas » Methane Hydrate » International Cooperation in Methane Hydrates International Cooperation in Methane Hydrates In 1982 the multi-national Deep Sea Drilling Program (DSDP) recovered the first subsea substantial methane hydrate deposits, which spurred methane hydrate research in the US and other countries. The successor programs, the Ocean Drilling Program (ODP) and the Integrated Ocean Drilling Program (IODP) sampled hydrate deposits off Oregon (ODP 204, 2002) and in the Cascadia Margin off Vancouver Island, Canada (ODP 146, 1992 and IODP 311, 2005). In the Atlantic Ocean off the US, ODP Leg 146 sampled hydrate deposits on the Blake Ridge and Carolina Rise in 1995. International cooperation helps scientists in the US and other countries

488

METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

METHANE HYDRATE ADVISORY COMMITTEE METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy Advisory Committee Charter - - - - ---- ---- ------~ 1. Committee's Official Designation. Methane Hydrate Advisory Committee (MHAC) 2. Authority:. This charter establishes the Methane Hydrate Advisory Committee (Committee) pursuant to Title IX, Subtitle F, Section 968, Methane Hydrate Research of the Energy Policy Act of 2005 (EPACT), Public Law 109-58. This charter establishes the MHAC under the authority of the Department of Energy (DOE). The MHAC is being renewed in accordance with the provisions of the Federal Advisory Committee Act (FACA), as amended, 5 U.S.C., App.2. 3. Objectives and Scope of Activities. The Committee provides advice to the Secretary of Energy by developing recommendations and broad programmatic priorities for the methane

489

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents (OSTI)

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

490

Production of methane-rich syngas from hydrocarbon fuels using multi-functional catalyst/capture agent  

DOE Patents (OSTI)

The disclosure provides a gasification process for the production of a methane-rich syngas at temperatures exceeding 700.degree. C. through the use of an alkali hydroxide MOH, using a gasification mixture comprised of at least 0.25 moles and less than 2 moles of water for each mole of carbon, and at least 0.15 moles and less than 2 moles of alkali hydroxide MOH for each mole of carbon. These relative amounts allow the production of a methane-rich syngas at temperatures exceeding 700.degree. C. by enabling a series of reactions which generate H.sub.2 and CH.sub.4, and mitigate the reforming of methane. The process provides a methane-rich syngas comprised of roughly 20% (dry molar percentage) CH.sub.4 at temperatures above 700.degree. C., and may effectively operate within an IGFC cycle at reactor temperatures between 700-900.degree. C. and pressures in excess of 10 atmospheres.

Siefert, Nicholas S; Shekhawat, Dushyant; Berry, David A; Surdoval, Wayne A

2014-12-30T23:59:59.000Z

491

Hydrogen production in Multi-Channel Membrane Reactor via Steam Methane Reforming and Methane Catalytic Combustion  

Science Journals Connector (OSTI)

Abstract A novel Multi-Channel Membrane Reactor (MCMR) was designed and built for the small-scale production of hydrogen via Steam Methane Reforming (SMR). The prototype alternates an SMR gas channel to produce hydrogen catalytically, with a Methane Catalytic Combustion (MCC) gas channel to provide the heat of reaction needed by the endothermic reforming. A palladiumsilver membrane inside the reforming gas channel shifts the reaction equilibrium, allowing lower operating temperatures, and producing pure hydrogen in a single vessel. Using an innovative air-spray coating technique, channels were coated with RuMgOLa2O3/?-Al2O3 and Pd/?-Al2O3 catalyst particles for the SMR and MCC reactions, respectively. Results for the proof-of-concept MCMR showed that methane conversion in the reformer of 91% and a hydrogen purity in excess of 99.99% were possible with the reformer operating at 570C and 15bar.

Alexandre Vigneault; John R. Grace

2014-01-01T23:59:59.000Z

492

,"New Mexico Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2012,"6...

493

Spektroskopische Vorgnge in Explosionszonen von Methan und anderen Kohlenwasserstoffen  

Science Journals Connector (OSTI)

Zur Untersuchung gelangen stehende Explosionen von Methan-Sauerstoff und vergleichsweise die von Acetylen- bzw. Benzoldampf-Sauerstoff. Die einzelnen Zonen bei der Verbrennung werden spektrographisch festgehal...

F. J. Lauer

1933-01-01T23:59:59.000Z

494

,"New York Coalbed Methane Proved Reserves (Billion Cubic Feet...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

495

Biomass Gasification and Methane Digester Property Tax Exemption  

Energy.gov (U.S. Department of Energy (DOE))

Michigan exempts certain energy production related farm facilities from real and personal property taxes. Among exempted property are certain methane digesters, biomass gasification equipment,...

496

Oxidation of methane by a biological dicopper centre  

Science Journals Connector (OSTI)

... Cu(I) ions and their implications. J. Am. Chem. Soc. 118, 1276612776 (1996) Chan, S. I. et al. Redox potentiometry studies of particulate methane ...

Ramakrishnan Balasubramanian; Stephen M. Smith; Swati Rawat; Liliya A. Yatsunyk; Timothy L. Stemmler; Amy C. Rosenzweig

2010-04-21T23:59:59.000Z

497

,"California--State Offshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","California--State Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

498

,"Texas (with State Offshore) Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Texas (with State Offshore) Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

499

,"Louisiana--State Offshore Coalbed Methane Proved Reserves ...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana--State Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

500

,"Lower 48 Federal Offshore Coalbed Methane Proved Reserves ...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Lower 48 Federal Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet)",1,"Annual",2013 ,"Release...