National Library of Energy BETA

Sample records for atmospheric gases experiment

  1. Detectability of biosignature gases in the atmospheres of terrestrial exoplanets

    E-Print Network [OSTI]

    Messenger, Stephen Joseph

    2013-01-01

    Biosignature gases in the atmosphere of an exoplanet provide a means by which we can deduce the possible existence of life on that planet. As the list of possible biosignature gases is ever growing, the need to determine ...

  2. BIOSIGNATURE GASES IN H?-DOMINATED ATMOSPHERES ON ROCKY EXOPLANETS

    E-Print Network [OSTI]

    Seager, Sara

    Super-Earth exoplanets are being discovered with increasing frequency and some will be able to retain stable H2-dominated atmospheres. We study biosignature gases on exoplanets with thin H2 atmospheres and habitable surface ...

  3. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  4. Experiments with interacting Bose and Fermi gases

    E-Print Network [OSTI]

    Stan, Claudiu Andrei

    2005-01-01

    In the past few years, the study of trapped fermionic atoms evolved from the first cooling experiments which produced quantum degenerate samples to becoming one of the most exciting branches of current atomic physics ...

  5. Earth is warm because of "greenhouse gases" in atmosphere

    E-Print Network [OSTI]

    Callender, Craig

    " properties of carbon dioxide, water. #12;Early 20th century, scientists realized that if CO2 content changed "Calculation shows that doubling or tripling the amount of the carbon dioxide in the atmosphere increases

  6. Results from the Phoenix Atmospheric Structure Experiment

    E-Print Network [OSTI]

    Withers, Paul

    Results from the Phoenix Atmospheric Structure Experiment Paul Withers1 and David Catling2 (1 and atmospheric structure reconstruction for Phoenix · Highlight selected aspects of Phoenix reconstruction reconstruction for Phoenix · Highlight selected aspects of Phoenix reconstruction that offer lessons for future

  7. A comprehensive study of different gases in inductively coupled plasma torch operating at one atmosphere

    SciTech Connect (OSTI)

    Punjabi, Sangeeta B.; Joshi, N. K.; Mangalvedekar, H. A.; Lande, B. K.; Das, A. K.; Kothari, D. C.

    2012-01-15

    A numerical study is done to understand the possible operating regimes of RF-ICP torch (3 MHz, 50 kW) using different gases for plasma formation at atmospheric pressure. A two dimensional numerical simulation of RF-ICP torch using argon, nitrogen, oxygen, and air as plasma gas has been investigated using computational fluid dynamic (CFD) software fluent{sup (c)}. The operating parameters varied here are central gas flow, sheath gas flow, RF-power dissipated in plasma, and plasma gas. The temperature contours, flow field, axial, and radial velocity profiles were investigated under different operating conditions. The plasma resistance, inductance of the torch, and the heat distribution for various plasma gases have also been investigated. The plasma impedance of ICP torch varies with different operating parameters and plays an important role for RF oscillator design and power coupling. These studies will be useful to decide the design criteria for ICP torches required for different material processing applications.

  8. Production of stable, non-thermal atmospheric pressure rf capacitive plasmas using gases other than helium or neon

    DOE Patents [OSTI]

    Park, Jaeyoung; Henins, Ivars

    2005-06-21

    The present invention enables the production of stable, steady state, non-thermal atmospheric pressure rf capacitive .alpha.-mode plasmas using gases other than helium and neon. In particular, the current invention generates and maintains stable, steady-state, non-thermal atmospheric pressure rf .alpha.-mode plasmas using pure argon or argon with reactive gas mixtures, pure oxygen or air. By replacing rare and expensive helium with more readily available gases, this invention makes it more economical to use atmospheric pressure rf .alpha.-mode plasmas for various materials processing applications.

  9. Investigation of light emission from a parallel-plate avalanche chamber filled with noble gases and with TEA, TMAE, and $H_{2}O$ vapours at atmospheric pressure

    E-Print Network [OSTI]

    Peskov, Vladimir; Dominik, Wojciech; Sauli, Fabio

    1989-01-01

    Investigation of light emission from a parallel-plate avalanche chamber filled with noble gases and with TEA, TMAE, and $H_{2}O$ vapours at atmospheric pressure

  10. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R. (Littleton, CO); Weimer, Carl S. (Littleton, CO); Nelson, Loren D. (Evergreen, CO); O'Brien, Martin J. (Pine, CO)

    2003-01-01

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  11. Carbon dioxide Information Analysis Center and World Data Center: A for Atmospheric trace gases. Annual progress report, FY 1994

    SciTech Connect (OSTI)

    Burtis, M.D. [comp.] [Tennessee Univ., Knoxville, TN (United States). Energy, Environment and Resources Center; Cushman, R.M.; Boden, T.A.; Jones, S.B.; Nelson, T.R.; Stoss, F.W. [Oak Ridge National Lab., TN (United States)

    1995-03-01

    This report summarizes the activities and accomplishments made by the Carbon Dioxide Information Analysis Center and World Data Center-A for Atmospheric Trace Gases during the fiscal year 1994. Topics discussed in this report include; organization and staff, user services, systems, communications, Collaborative efforts with China, networking, ocean data and activities of the World Data Center-A.

  12. Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases Fiscal Year 2000 Annual Report

    SciTech Connect (OSTI)

    Cushman, R.M.

    2001-11-15

    The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global change data and information analysis center of the U.S. Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has, since its inception in 1982, enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including concentrations of carbon dioxide (CO{sub 2}) and other radiatively active gases in the atmosphere; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; emissions of CO{sub 2} and other trace gases to the atmosphere; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea levels.

  13. Atom chip apparatus for experiments with ultracold rubidium and potassium gases

    SciTech Connect (OSTI)

    Ivory, M. K.; Ziltz, A. R.; Fancher, C. T.; Pyle, A. J.; Sensharma, A.; Chase, B.; Field, J. P.; Garcia, A.; Aubin, S.; Jervis, D.

    2014-04-15

    We present a dual chamber atom chip apparatus for generating ultracold {sup 87}Rb and {sup 39}K atomic gases. The apparatus produces quasi-pure Bose-Einstein condensates of 10{sup 4} {sup 87}Rb atoms in an atom chip trap that features a dimple and good optical access. We have also demonstrated production of ultracold {sup 39}K and subsequent loading into the chip trap. We describe the details of the dual chamber vacuum system, the cooling lasers, the magnetic trap, the multicoil magnetic transport system, the atom chip, and two optical dipole traps. Due in part to the use of light-induced atom desorption, the laser cooling chamber features a sufficiently good vacuum to also support optical dipole trap-based experiments. The apparatus is well suited for studies of atom-surface forces, quantum pumping and transport experiments, atom interferometry, novel chip-based traps, and studies of one-dimensional many-body systems.

  14. Atmospheric photochemistry, surface features, and potential biosignature gases of terrestrial exoplanets

    E-Print Network [OSTI]

    Hu, Renyu, Ph. D. Massachusetts Institute of Technology

    2013-01-01

    The endeavor to characterize terrestrial exoplanets warrants the study of chemistry in their atmospheres. Here I present a comprehensive one-dimensional photochemistry-thermochemistry model developed from the ground up for ...

  15. The Global Anthropogenic Lead Experiment Earth, Atmospheric and Planetary Sciences

    E-Print Network [OSTI]

    Einat, Aharonov

    The Global Anthropogenic Lead Experiment Ed Boyle Earth, Atmospheric and Planetary Sciences Reuer Rick Kayser Boyle Lab, arriving in Rio at the end of EN 367 #12;The Global Anthropogenic Lead Experiment Lead is a volatile element and it is emitted by high temperature industrial activities (smelting

  16. Carbon Dioxide Information Analysis Center and World Data Center-A for atmospheric trace gases: FY 1993 activities

    SciTech Connect (OSTI)

    Cushman, R.M.; Stoss, F.W. |

    1994-01-01

    During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specialty publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIAC`s staff also provide technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC (including World Data Center-A for Atmospheric Trace Gases) during the period October 1, 1992, to September 30, 1993. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. An analysis and description of the preparation and distribution of NDPS, CMPS, technical reports, newsletters, fact sheets, specialty publications, and reprints are provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also presented.

  17. Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases Fiscal Year 2001 Annual Report

    SciTech Connect (OSTI)

    Cushman, R.M.

    2002-10-15

    The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global change data and information analysis center of the U.S. Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has, since its inception in 1982, enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including concentrations of carbon dioxide (CO{sub 2}) and other radiatively active gases in the atmosphere; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; emissions of CO{sub 2} and other trace gases to the atmosphere; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea levels. CDIAC is located within the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee. CDIAC is co-located with ESD researchers investigating global-change topics, such as the global carbon cycle and the effects of carbon dioxide on climate and vegetation. CDIAC staff are also connected with current ORNL research on related topics, such as renewable energy and supercomputing technologies. CDIAC is supported by the Environmental Sciences Division (Jerry Elwood, Director) of DOE's Office of Biological and Environmental Research. CDIAC represents DOE in the multi-agency Global Change Data and Information System (GCDIS). Wanda Ferrell is DOE's Program Manager with overall responsibility for CDIAC. Roger Dahlman is responsible for CDIAC's AmeriFlux tasks, and Anna Palmisano for CDIAC's Ocean Data tasks. CDIAC is made up of three groups: Data Systems, Information Services, and Computer Systems, with nineteen full-time or part-time staff. The following section provides details on CDIAC's staff and organization. The Data Systems Group identifies and obtains databases important to global-change research; analyzes data; compiles needed databases; provides data management and support to specific programs [e.g., NARSTO, Free-Air CO{sub 2} Enrichment (FACE), AmeriFlux, Oceans]; and prepares documentation to ensure the long-term utility of CDIAC's data holdings. The Information Services Group responds to data and information requests; maintains records of all request activities; analyzes user statistics; assists in Web development and maintenance; and produces CDIAC's newsletter (CDIAC Communications), the fiscal year annual reports, and various information materials. The Computer Systems Group provides computer system support for all CDIAC and WDC activities; designs and maintains CDIAC's computing system network; ensures compliance with ORNL/DOE computing security regulations; ensures long-term preservation of CDIAC data holdings through systematic backups; evaluates, develops, and implements software; ensures standards compliance; generates user statistics; provides Web design, development, and oversight; and provides systems analysis and programming assistance for scientific data projects.

  18. Evidence for multiple magma ocean outgassing and atmospheric loss episodes from mantle noble gases

    E-Print Network [OSTI]

    Tucker, Jonathan M

    2014-01-01

    The energy associated with giant impacts is large enough to generate global magma oceans during Earth's accretion. However, geochemical evidence requiring a terrestrial magma ocean is scarce. Here we present evidence for at least two separate magma ocean outgassing episodes on Earth based on the ratio of primordial 3He to 22Ne in the present-day mantle. We demonstrate that the depleted mantle 3He/22Ne ratio is at least 10 while a more primitive mantle reservoir has a 3He/22Ne ratio of 2.3 to 3. The 3He/22Ne ratios of the mantle reservoirs are higher than possible sources of terrestrial volatiles, including the solar nebula ratio of 1.5. Therefore, a planetary process must have raised the mantle's 3He/22Ne ratio. We show that long-term plate tectonic cycling is incapable of raising the mantle 3He/22Ne ratio and may even lower it. However, ingassing of a gravitationally accreted nebular atmosphere into a magma ocean on the proto-Earth explains the 3He/22Ne and 20Ne/22Ne ratios of the primitive mantle reservoir....

  19. ARESE (ARM Enhanced Shortwave Experiment) Science Plan [Atmospheric Radiation Program

    SciTech Connect (OSTI)

    Valero, F.P.J.; Schwartz, S.E.; Cess, R.D.; Ramanathan, V.; Collins, W.D.; Minnis, P.; Ackerman, T.P.; Vitko, J.; Tooman, T.P.

    1995-09-27

    Several recent studies have indicated that cloudy atmospheres may absorb significantly more solar radiation than currently predicted by models. The magnitude of this excess atmospheric absorption, is about 50% more than currently predicted and would have major impact on our understanding of atmospheric heating. Incorporation of this excess heating into existing general circulation models also appears to ameliorate some significant shortcomings of these models, most notably a tendency to overpredict the amount of radiant energy going into the oceans and to underpredict the tropopause temperature. However, some earlier studies do not show this excess absorption and an underlying physical mechanism that would give rise to such absorption has yet to be defined. Given the importance of this issue, the Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) program is sponsoring the ARM Enhanced Shortwave Experiment (ARESE) to study the absorption of solar radiation by clear and cloudy atmospheres. The experimental results will be compared with model calculations. Measurements will be conducted using three aircraft platforms (ARM-UAV Egrett, NASA ER-2, and an instrumented Twin Otter), as well as satellites and the ARM central and extended facilities in North Central Oklahoma. The project will occur over a four week period beginning in late September, 1995. Spectral broadband, partial bandpass, and narrow bandpass (10nm) solar radiative fluxes will be measured at different altitudes and at the surface with the objective to determine directly the magnitude and spectral characteristics of the absorption of shortwave radiation by the atmosphere (clear and cloudy). Narrow spectral channels selected to coincide with absorption by liquid water and ice will help in identifying the process of absorption of radiation. Additionally, information such as water vapor profiles, aerosol optical depths, cloud structure and ozone profiles, needed to use as input in radiative transfer calculations, will be acquired using the aircraft and surface facilities available to ARESE. This document outlines the scientific approach and measurement requirements of the project.

  20. On the global distribution of neutral gases in Titan's upper atmosphere and its effect on the thermal structure

    E-Print Network [OSTI]

    Mueller-Wodarg, Ingo

    distribution of neutral gases by winds and diffusion. Our calculations suggest that solar driven dynamics at equinox near 1400 km reaching up to 50%. The reverse happens on the dayside, where lighter gases and vertical winds, and thereby adiabatic heating and cooling. On the dayside, changes in solar EUV absorption

  1. O_3-N_2O correlations from the Atmospheric Chemistry Experiment

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    O_3-N_2O correlations from the Atmospheric Chemistry Experiment: revisiting a diagnostic. (2007) O_3-N_2O correlations from the Atmospheric Chemistry Experiment: revisiting a diagnostic outputs online #12;O3-N2O correlations from the Atmospheric Chemistry Experiment: Revisiting a diagnostic

  2. Experiments on the reduction of nitric oxide from exhaust gases by selective non-catalytic reactions

    E-Print Network [OSTI]

    Narney, John Kenneth

    1993-01-01

    The use of ammonia in a selective non-catalytic process for the removal of nitric oxide (NO) from exhaust gases was studied. A quartz lined flow reactor system was constructed in order to examine the behavior of the process with 15% oxygen...

  3. Contamination of Dark Matter Experiments from Atmospheric Magnetic Dipoles

    E-Print Network [OSTI]

    A. Bueno; M. Masip; P. Snchez-Lucas; N. Setzer

    2013-10-14

    Dark matter collisions with heavy nuclei (Xe, Ge, Si, Na) may produce recoils observable at direct-search experiments. Given that some of these experiments are yielding conflicting information, however, it is worth asking if physics other than dark matter may produce similar nuclear recoils. We examine under what conditions an atmospherically-produced neutral particle with a relatively large magnetic dipole moment could fake a dark matter signal. We argue that a very definite flux could explain the signals seen at DAMA/LIBRA, CDMS/Si and CoGeNT consistently with the bounds from XENON100 and CDMS/Ge. To explore the plausibility of this scenario, we discuss a concrete model with 10-50 MeV sterile neutrinos that was recently proposed to explain the LSND and MiniBooNE anomalies.

  4. Global and regional emissions of HFC-125 (CHF[subscript 2]CF[subscript 3]) from in situ and air archive atmospheric observations at AGAGE and SOGE observatories

    E-Print Network [OSTI]

    O'Doherty, S.

    High-frequency, in situ observations from the Advanced Global Atmospheric Gases Experiment (AGAGE) and System for Observation of halogenated Greenhouse gases in Europe (SOGE) networks for the period 1998 to 2008, combined ...

  5. Upper ocean model of dissolved atmospheric gases. Final report for the period 1 August 1991--31 May 1995

    SciTech Connect (OSTI)

    Schudlich, R.; Emerson, S.

    1996-05-01

    This report summarizes results from three years of funding for a modelling study of processes controlling the distribution of metabolic chemical tracers in surface waters. We determined concentrations of the gases O{sub 2}, Ar, N{sub 2}, and the stable isotope ratio ({sup 18}O/{sup 16}O) of molecular oxygen in surface waters at Station ALOHA in conjunction with the Global Ocean Flux Study (GOFS) Hawaiian Ocean Time-series project during the years 1989- 90 and 1992-93. Under this contract we have incorporated chemical tracers into an existing ocean mixed-layer model to simulate the physical processes controlling the distribution and seasonal cycle of dissolved gases in the upper ocean. The broad background of concurrent chemical, physical, and biological measurements at Station ALOHA provides enough redundancy of ``ground truth`` to assess the model`s accuracy. Biological oxygen production estimated from modelled chemical tracers agrees with estimates based on measurement of carbon fluxes into the deep ocean and nitrate fluxes into the upper ocean during 1989-90 and 1992-93, verifying for the first time the utility of chemical tracers for determining biological fluxes in the ocean. Our results suggest that in the euphotic zone (the upper 100 m of the ocean), the net biological O{sub 2} production is 1.0-2. 0 moles m{sup -2}yr{sup - 1}. Inert gas (Ar, N{sub 2}) supersaturation levels show that air and bubble injection are important modes of air-sea gas transfer in the Station ALOHA region.

  6. Fiscal Year 1998 Annual Report, Carbon Dioxide Information Analysis Center, World Data Center -- A for Atmospheric Trace Gases

    SciTech Connect (OSTI)

    Cushman, R.M.; Boden, T.A.; Hook, L.A.; Jones, S.B.; Kaiser, D.P.; Nelson, T.R.

    1999-03-01

    Once again, the most recent fiscal year was a productive one for the Carbon Dioxide Information Analysis Center (CDIAC) at Oak Ridge National Laboratory (ORNL), as well as a year for change. The FY 1998 in Review section in this report summarizes quite a few new and updated data and information products, and the ''What's Coming in FY 1999'' section describes our plans for this new fiscal year. During FY 1998, CDIAC began a data-management system for AmeriFlux, a long-term study of carbon fluxes between the terrestrial biosphere of the Western Hemisphere and the atmosphere. The specific objectives of AmeriFlux are to establish an infrastructure for guiding, collecting, synthesizing, and disseminating long-term measurements of CO{sub 2}, water, and energy exchange from a variety of ecosystems; collect critical new information to help define the current global CO{sub 2} budget; enable improved predictions of future concentrations of atmospheric CO{sub 2}; and enhance understanding of carbon fluxes. Net Ecosystem Production (NEP), and carbon sequestration in the terrestrial biosphere. The data-management system, available from CDIAC'S AmeriFlux home page (http://cdiac.esd.ornl.gov/programs/ameriflux/ ) is intended to provide consistent, quality-assured, and documented data across all AmeriFlux sites in the US, Canada, Costa Rica, and Brazil. It is being developed by Antoinette Brenkert and Tom Boden, with assistance from Susan Holladay (who joined CDIAC specifically to support the AmeriFlux data-management effort).

  7. Global atmospheric chemistry: Integrating over fractional cloud cover

    E-Print Network [OSTI]

    Neu, Jessica L; Prather, Michael J; Penner, Joyce E

    2007-01-01

    trace gases and atmospheric chemistry, in Climate Change2007 Global atmospheric chemistry: Integrating over2007), Global atmospheric chemistry: Integrating over

  8. ARM - Field Campaign - Lower Atmospheric Boundary Layer Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01)govCampaignsFIRE-Arctic-govCampaignsLower Atmospheric Boundary

  9. THE PHOENIX ATMOSPHERIC STRUCTURE EXPERIMENT (ASE): DATA PROCESSING AND SCIENTIFIC RESULTS

    E-Print Network [OSTI]

    Withers, Paul

    THE PHOENIX ATMOSPHERIC STRUCTURE EXPERIMENT (ASE): DATA PROCESSING AND SCIENTIFIC RESULTS Paul (ASE) of the Phoenix Mars lander. This experiment presented some unique challenges because its hardware was essentially designed and built to fulfill engineering requirements be- fore the Phoenix mission began, meaning

  10. The 2003 North American electrical blackout: An accidental experiment in atmospheric chemistry

    E-Print Network [OSTI]

    Stehr, Jeffrey

    The 2003 North American electrical blackout: An accidental experiment in atmospheric chemistry 2004; published 15 July 2004. [1] The August 2003 North American electrical blackout provided a unique observations over central Pennsylvania on August 15, 2003, $24 h into the blackout, revealed large reductions

  11. Lifetimes and eigenstates in atmospheric chemistry

    E-Print Network [OSTI]

    Prather, Michael J

    1994-01-01

    Perturbation dynamics in atmospheric chemistry. J. Geophys.isotopic variations in atmospheric chemistry. Geophys. Res.M. et al. 2001 Atmospheric chemistry and greenhouse gases (

  12. Probing photo-ionization: experiments on positive streamers in pure gases and mixtures This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Ebert, Ute

    Probing photo-ionization: experiments on positive streamers in pure gases and mixtures This article. Phys. 43 (2010) 145204 (16pp) doi:10.1088/0022-3727/43/14/145204 Probing photo-ionization: experiments/145204 Abstract Positive streamers are thought to propagate by photo-ionization; the parameters of photo

  13. Airborne measurements of total sulfur gases during NASA global tropospheric experiment/chemical instrumentation test and evaluation 3

    SciTech Connect (OSTI)

    Farwell, S.O.; MacTaggart, D.L.; Chatham, W.H.

    1995-04-20

    A metal foil collection/flash desorption/flame photometric detection (MFC/FD/FPD) technique was used by investigators from the University of Idaho (UI) to measure ambient total sulfur gas concentrations from an aircraft platform during the NASA Global Tropospheric Experiment/Chemical Instrumentation Test and Evaluation 3 (GTE/CITE 3) program. The MFC/FD/FPD technique allowed rapid quantitation of tropospheric background air masses using sample integration times of 1-3 min with little or no gap between measurements. The rapid and continual sampling nature of this technique yielded data covering approximately 75% of the entire CITE 3 program`s air track. Ambient air measurement data obtained during northern hemisphere (NH) flights often exhibited relatively high total sulfur gas values (up to 19 ppb) and an extremely high degree of sample heterogeneity, especially in coastal locations. Data from southern hemisphere (SH) flights typically exhibited relatively low total sulfur gas concentrations and a low degree of sample heterogeneity. A bimodal interhemispheric total sulfur gas gradient was observed using data obtained during transit flights between the two CITE 3 program ground bases. Comparisons were made of UI total sulfur gas measurements with composite sulfur gas values generated using speciated sulfur gas measurements from other CITE 3 participants. Only a relatively small number of overlap periods for comparison were obtained from all the available CITE 3 data because of large differences in measurement integration times and lack of synchronization of sample start/stop times for the various investigators. These effects were compounded with extreme sample heterogeneity in the NH and the speed at which the aircraft traversed the air masses being sampled. Comparison of NH UI total with composite sulfur gas values showed excellent correlation and linear curve fit, indicating substantial qualitative agreement. 20 refs., 10 figs., 7 tabs.

  14. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G.; Gerritsen, W.; Stewart, A.; Robinson, K.

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock & Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  15. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G. ); Gerritsen, W.; Stewart, A.; Robinson, K. )

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  16. The extreme nonlinear optics of gases and femtosecond optical filamentation

    SciTech Connect (OSTI)

    Milchberg, H. M.; Chen, Y.-H.; Cheng, Y.-H.; Jhajj, N.; Palastro, J. P.; Rosenthal, E. W.; Varma, S.; Wahlstrand, J. K.; Zahedpour, S. [Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

    2014-10-15

    Under certain conditions, powerful ultrashort laser pulses can form greatly extended, propagating filaments of concentrated high intensity in gases, leaving behind a very long trail of plasma. Such filaments can be much longer than the longitudinal scale over which a laser beam typically diverges by diffraction, with possible applications ranging from laser-guided electrical discharges to high power laser propagation in the atmosphere. Understanding in detail the microscopic processes leading to filamentation requires ultrafast measurements of the strong field nonlinear response of gas phase atoms and molecules, including absolute measurements of nonlinear laser-induced polarization and high field ionization. Such measurements enable the assessment of filamentation models and make possible the design of experiments pursuing applications. In this paper, we review filamentation in gases and some applications, and discuss results from diagnostics developed at Maryland for ultrafast measurements of laser-gas interactions.

  17. Reactive greenhouse gas scenarios: Systematic exploration of uncertainties and the role of atmospheric chemistry

    E-Print Network [OSTI]

    Prather, Michael J; Holmes, Christopher D; Hsu, Juno

    2012-01-01

    and time scales in atmospheric chemistry, Philos. Trans. R.PRATHER ET AL. : ATMOSPHERIC CHEMISTRY AND GREENHOUSE GASESet al. (2001), Atmospheric chemistry and greenhouse gases,

  18. Time scales in atmospheric chemistry: Theory, GWPs for CH 4 and CO, and runaway growth

    E-Print Network [OSTI]

    Prather, Michael J

    1996-01-01

    Program and NSF's Atmospheric Chemistry Program for supporteigenstates in atmospheric chemistry, (2) Exponential decaytracer gases and atmospheric chemistry, in steady-state

  19. Time scales in atmospheric chemistry: Theory, GWPs for CH4 and CO, and runaway growth

    E-Print Network [OSTI]

    Prather, MJ; Prather, MJ

    1996-01-01

    Program and NSF's Atmospheric Chemistry Program for supporteigenstates in atmospheric chemistry, (2) Exponential decaytracer gases and atmospheric chemistry, in steady-state

  20. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  1. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

    1986-01-01

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  2. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL)

    1986-01-01

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  3. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  4. The HIPPO (HIAPER Pole-to-Pole Observations) study of the carbon cycle and greenhouse gases measured meteorology, atmospheric chemistry, and aerosol constituents along transects from approximately pole-to-pole

    E-Print Network [OSTI]

    .) Ancillary flight information, field catalogs, data quality reports, software, and documentation Pole products and user documentation. Files are in ASCII text format. Products include: A comprehensive merged structure data: 1) greenhouse gases and carbon cycle gases, 2) ozone and water vapor, 3) black carbon

  5. Detailed discussion of a linear electric field frequency shift (important for next generation) electric dipole moment searches) induced in confined gases by a magnetic field gradient: Implications for electric dipole moment experiments (II)

    E-Print Network [OSTI]

    A. L. Barabanov; R. Golub; S. K. Lamoreaux

    2005-12-20

    The search for particle electric dipole moments represents a most promising way to search for physics beyond the standard model. A number of groups are planning a new generation of experiments using stored gases of various kinds. In order to achieve the target sensitivities it will be necessary to deal with the systematic error resulting from the interaction of the well-known E x v field with magnetic field gradients (often referred to as the geometric phase effect [9,10]). This interaction produces a frequency shift linear in the electric field, mimicking an edm. In this work we introduce an analytic model for the correlation function which determines the behavior of the frequency shift [11], and show in detail how it depends on the operating conditions of the experiment. We also propose a method to directly measure ths correlation function under the exact conditions of a given experiment.

  6. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  7. Observations of the Pulsar PSR B1951+32 with the Solar Tower Atmospheric Cherenkov Effect Experiment

    E-Print Network [OSTI]

    J. Kildea; J. Zweerink; J. Ball; J. E. Carson; C. E. Covault; D. D. Driscoll; P. Fortin; D. M. Gingrich; D. S. Hanna; A. Jarvis; T. Lindner; C. Mueller; R. Mukherjee; R. A. Ong; K. Ragan; D. A. Williams

    2007-10-25

    We present the analysis and results of 12.5 hours of high-energy gamma-ray observations of the EGRET-detected pulsar PSR B1951+32 using the Solar Tower Atmospheric Cherenkov Effect Experiment (STACEE). STACEE is an atmospheric Cherenkov detector, in Albuquerque, New Mexico, that detects cosmic gamma rays using the shower-front-sampling technique. STACEE's sensitivity to astrophysical sources at energies around 100 GeV allows it to investigate emission from gamma-ray pulsars with expected pulsed emission cutoffs below 100 GeV. We discuss the observations and analysis of STACEE's PSR 1951+32 data, accumulated during the 2005 and 2006 observing seasons.

  8. Impacts of greenhouse gases and aerosol direct and indirect effects on clouds and

    E-Print Network [OSTI]

    Dufresne, Jean-Louis

    Impacts of greenhouse gases and aerosol direct and indirect effects on clouds and radiation/C.N.R.S., Villeneuve d'Ascq, France Among anthropogenic perturbations of the Earth's atmosphere, greenhouse gases the radiative impacts of five species of greenhouse gases (CO2, CH4, N2O, CFC-11 and CFC-12) and sulfate

  9. D) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases

    E-Print Network [OSTI]

    Jackman, Charles H.

    O(1 D) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases Munkhbayar Baasandorj) and greenhouse gases (GHGs) is reaction with the O(1 D) atom. In this study, rate coefficients, k, for the O(1 D) and greenhouse gases (GHGs). Quantifying the atmospheric loss processes of ODSs and GHGs is essential

  10. Eddy covariance flux measurements of pollutant gases in urban Mexico City

    E-Print Network [OSTI]

    Velasco, Erik

    Eddy covariance (EC) flux measurements of the atmosphere/surface exchange of gases over an urban area are a direct way to improve and evaluate emissions inventories, and, in turn, to better understand urban atmospheric ...

  11. Atmospheric Radiation Measurment (ARM) Data from the Ganges Valley, India for the Ganges Valley Aerosol Experiment (GVAX)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    In 2011 and 2012, the Ganges Valley Aerosol Experiment (GVAX) began in the Ganges Valley region of India. The objective was to obtain measurements of clouds, precipitation, and complex aerosols to study their impact on cloud formation and monsoon activity in the region. During the Indian Ocean Experiment (INDOEX) field studies, aerosols from the Ganges Valley region were shown to affect cloud formation and monsoon activity over the Indian Ocean. The complex field study used the ARM Mobile Facility (AMF) to measure radiative, cloud, convection, and aerosol characteristics over the mainland. The resulting data set captured pre-monsoon to post-monsoon conditions to establish a comprehensive baseline for advancements in the study of the effects of atmospheric conditions of the Ganges Valley.

  12. High Energy Gamma-Ray Observations of the Crab Nebula and Pulsar with the Solar Tower Atmospheric Cherenkov Effect Experiment

    E-Print Network [OSTI]

    Oser, S; Boone, L M; Chantell, M C; Conner, Z; Covault, C E; Dragovan, M; Fortin, P; Gregorich, D T; Hanna, D S; Mukherjee, R; Ong, R A; Ragan, K; Scalzo, R A; Schuette, D R; Theoret, C G; Tumer, T O; Williams, D A; Zweerink, J A

    2015-01-01

    The Solar Tower Atmospheric Cherenkov Effect Experiment (STACEE) is a new ground-based atmospheric Cherenkov telescope for gamma-ray astronomy. STACEE uses the large mirror area of a solar heliostat facility to achieve a low energy threshold. A prototype experiment which uses 32 heliostat mirrors with a total mirror area of ~ 1200\\unit{m^2} has been constructed. This prototype, called STACEE-32, was used to search for high energy gamma-ray emission from the Crab Nebula and Pulsar. Observations taken between November 1998 and February 1999 yield a strong statistical excess of gamma-like events from the Crab, with a significance of $+6.75\\sigma$ in 43 hours of on-source observing time. No evidence for pulsed emission from the Crab Pulsar was found, and the upper limit on the pulsed fraction of the observed excess was E_{th}) = (2.2 \\pm 0.6 \\pm 0.2) \\times 10^{-10}\\unit{photons cm^{-2} s^{-1}}. The observed flux is in agreement with a continuation to lower energies of the power law spectrum seen at TeV energies...

  13. Where do California's greenhouse gases come from?

    SciTech Connect (OSTI)

    Fischer, Marc

    2009-01-01

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  14. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  15. Simulation of Containment Atmosphere Mixing and Stratification Experiment in the ThAI Facility with a CFD Code

    SciTech Connect (OSTI)

    Babic, Miroslav; Kljenak, Ivo; Mavko, Borut [Reactor Engineering Division, Jozef Stefan Institute, Jamova 39, Ljubljana (Slovenia)

    2006-07-01

    The CFD code CFX4.4 was used to simulate an experiment in the ThAI facility, which was designed for investigation of thermal-hydraulic processes during a severe accident inside a Light Water Reactor containment. In the considered experiment, air was initially present in the vessel, and helium and steam were injected during different phases of the experiment at various mass flow rates and at different locations. The main purpose of the proposed work was to assess the capabilities of the CFD code to reproduce the atmosphere structure with a three-dimensional model, coupled with condensation models proposed by the authors. A three-dimensional model of the ThAI vessel for the CFX4.4 code was developed. The flow in the simulation domain was modeled as single-phase. Steam condensation on vessel walls was modeled as a sink of mass and energy using a correlation that was originally developed for an integral approach. A simple model of bulk phase change was also included. Calculated time-dependent variables together with temperature and volume fraction distributions at the end of different experiment phases are compared to experimental results. (authors)

  16. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Control of pollutants in flue gases and fuel gases Ron Zevenhoven Helsinki University of Technology Programme Solid Fuel Committee s, Norway Helsinki University of Technology Espoo, Finland #12;limited . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3 Chapter 2 Flue gases and fuel gases 2.1 Introduction

  17. Atmospheric science and power production

    SciTech Connect (OSTI)

    Randerson, D.

    1984-07-01

    This is the third in a series of scientific publications sponsored by the US Atomic Energy Commission and the two later organizations, the US Energy Research and Development Adminstration, and the US Department of Energy. The first book, Meteorology and Atomic Energy, was published in 1955; the second, in 1968. The present volume is designed to update and to expand upon many of the important concepts presented previously. However, the present edition draws heavily on recent contributions made by atmospheric science to the analysis of air quality and on results originating from research conducted and completed in the 1970s. Special emphasis is placed on how atmospheric science can contribute to solving problems relating to the fate of combustion products released into the atmosphere. The framework of this book is built around the concept of air-quality modeling. Fundamentals are addressed first to equip the reader with basic background information and to focus on available meteorological instrumentation and to emphasize the importance of data management procedures. Atmospheric physics and field experiments are described in detail to provide an overview of atmospheric boundary layer processes, of how air flows around obstacles, and of the mechanism of plume rise. Atmospheric chemistry and removal processes are also detailed to provide fundamental knowledge on how gases and particulate matter can be transformed while in the atmosphere and how they can be removed from the atmosphere. The book closes with a review of how air-quality models are being applied to solve a wide variety of problems. Separate analytics have been prepared for each chapter.

  18. The VAMOS Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx): Goals, platforms, and field operations

    SciTech Connect (OSTI)

    Wood, R.; Springston, S.; Mechoso, C. R.; Bretherton, C. S.; A.Weller, R.; Huebert, B.; Straneo, F.; Albrecht, B. A.; Coe, H.; Allen, G.; Vaughan, G.; Daum, P.; Fairall, C.; Chand, D.; Klenner, L. G.; Garreaud, R.; Grados, C.; Covert, D. S.; Bates, T. S.; Krejci, R.; Russell, L. M.; Szoeke, S. d.; Brewer, A.; Yuter, S. E.; Chaigneau, A.; Toniazzo, T.; Minnis, P.; Palikonda, R.; Abel, S. J.; Brown, W. O. J.; Williams, S.; Fochesatto, J.; Brioude, J.; Bower, K. N

    2011-01-21

    The VAMOS Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) was an international field program designed to make observations of poorly understood but critical components of the coupled climate system of the southeast Pacific. This region is characterized by strong coastal upwelling, the coolest SSTs in the tropical belt, and is home to the largest subtropical stratocumulus deck on Earth. The field intensive phase of VOCALS-REx took place during October and November 2008 and constitutes a critical part of a broader CLIVAR program (VOCALS) designed to develop and promote scientific activities leading to improved understanding, model simulations, and predictions of the southeastern Pacific (SEP) coupled ocean-atmosphere-land system, on diurnal to interannual timescales. The other major components of VOCALS are a modeling program with a model hierarchy ranging from the local to global scales, and a suite of extended observations from regular research cruises, instrumented moorings, and satellites. The two central themes of VOCALS-REx focus upon (a) links between aerosols, clouds and precipitation and their impacts on marine stratocumulus radiative properties, and (b) physical and chemical couplings between the upper ocean and the lower atmosphere, including the role that mesoscale ocean eddies play. A set of hypotheses designed to be tested with the combined field, monitoring and modeling work in VOCALS is presented here. A further goal of VOCALS-REx is to provide datasets for the evaluation and improvement of large-scale numerical models. VOCALS-REx involved five research aircraft, two ships and two surface sites in northern Chile. We describe the instrument payloads and key mission strategies for these platforms and give a summary of the missions conducted.

  19. Reply to comment by D. A. Hansen et al. on ``The 2003 North American electrical blackout: An accidental experiment in atmospheric

    E-Print Network [OSTI]

    Stehr, Jeffrey

    Reply to comment by D. A. Hansen et al. on ``The 2003 North American electrical blackout), Reply to comment by D. A. Hansen et al. on ``The 2003 North American electrical blackout: An accidental blackout: An accidental experiment in atmospheric chemistry'' and ap- preciate the opportunity to expand

  20. Guidance Document CompressedGases

    E-Print Network [OSTI]

    gases are toxic, flammable, pyrophoric, or corrosive. Liquefied compressed gases (cryogenic liquids of exposure may be delayed. Cold "Burns": Rapidly escaping gas from a cylinder can cause destruction freezing

  1. Chemistry of atmospheres formed during accretion of the Earth and other terrestrial planets

    E-Print Network [OSTI]

    Schaefer, L

    2009-01-01

    We used chemical equilibrium and chemical kinetic calculations to model chemistry of the volatiles released by heating different types of carbonaceous, ordinary and enstatite chondritic material as a function of temperature and pressure. Our results predict the composition of atmospheres formed by outgassing during accretion of the Earth and other terrestrial planets. Outgassing of CI and CM carbonaceous chondritic material produces H2O-rich (steam) atmospheres in agreement with the results of impact experiments. However, outgassing of other types of chondritic material produces atmospheres dominated by other gases. Outgassing of ordinary (H, L, LL) and high iron enstatite (EH) chondritic material yields H2-rich atmospheres with CO and H2O being the second and third most abundant gases. Outgassing of low iron enstatite (EL) chondritic material gives a CO-rich atmosphere with H2, CO2, and H2O being the next most abundant gases. Outgassing of CV carbonaceous chondritic material gives a CO2-rich atmosphere with ...

  2. ATMOSPHERIC CHEMISTRY AND PHYSICS

    E-Print Network [OSTI]

    Brandenburg, Axel

    of electronic formats. Some content that appears in print may not be available in electronic formats. For more information about Wiley products, visit our web site at www.wiley.com. Library of Congress Cataloging components of the atmosphere, nitrogen, oxygen, water, carbon dioxide, and the noble gases. In the late

  3. Radio-frequency spectroscopy of ultracold atomic Fermi gases

    E-Print Network [OSTI]

    Schirotzek, Andre

    2010-01-01

    This thesis presents experiments investigating the phase diagram of ultracold atomic Fermi gases using radio-frequency spectroscopy. The tunability of many experimental parameters including the temperature, the interparticle ...

  4. Detailed Discussion of a linear electric field frequency shift induced in confined gases by a magnetic field gradient: Implications for neutron electric dipole moment experiments

    E-Print Network [OSTI]

    S. K. Lamoreaux; R. Golub

    2005-01-25

    The search for particle electric dipole moments (edm) is one of the best places to look for physics beyond the standard model because the size of time reversal violation predicted by the standard model is incompatible with present ideas concerning the creation of the Baryon-Antibaryon asymmetry. As the sensitivity of these edm searches increases more subtle systematic effects become important. We develop a general analytical approach to describe a systematic effect recently observed in an electric dipole moment experiment using stored particles \\cite{JMP}. Our approach is based on the relationship between the systematic frequency shift and the velocity autocorrelation function of the resonating particles. Our results, when applied to well-known limiting forms of the correlation function, are in good agreement with both the limiting cases studied in recent work that employed a numerical/heuristic analysis. Our general approach explains some of the surprising results observed in that work and displays the rich behavior of the shift for intermediate frequencies, which has not been previously studied.

  5. Greenhouse Gases CHAPTER 4 Why some gases are greenhouse gases, but

    E-Print Network [OSTI]

    Greenhouse Gases CHAPTER 4 Why some gases are greenhouse gases, but most aren't, and some. It has the essential ingre- dient of the greenhouse effect, but it is missing numerous things, the mixing ratio is currently about 390 ppm, and its pCO2 is about 390 atm. 29 #12;30 CHAPTER 4 Greenhouse

  6. Thermodynamics of sustaining gases in the roughness of submerged superhydrophobic surfaces

    E-Print Network [OSTI]

    Neelesh A. Patankar

    2015-05-22

    Rough surfaces submerged in a liquid can remain almost dry if the liquid does not fully wet the roughness and gases are sustained in roughness grooves. Such partially dry surfaces can help reduce drag or enhance boiling. Gases sustained in roughness grooves would be composed of air and the vapor phase of the liquid itself. The thermodynamics of sustaining vapor was considered in a prior work [Patankar, Soft Matter, 2010, 6:1613]. Here, the thermodynamics of sustaining gases (e.g. air) is considered. Governing equations are presented along with a solution methodology to determine a critical condition to sustain gases. The critical roughness scale to sustain gases is estimated for different degrees of saturation of gases dissolved in the liquid. It is shown that roughness spacings of less than a micron are essential to sustain gases on surfaces submerged in water at atmospheric pressure. This is consistent with prior empirical data.

  7. Chapter 22 Greenhouse Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (EPA 2010b). The GHGs present in the earth's atmosphere include water vapor (H 2 O), ozone (O 3 ), CO 2 , methane (CH 4 ), nitrous oxide (N 2 O), and trace amounts of...

  8. Traffic Congestion and Greenhouse Gases

    E-Print Network [OSTI]

    Barth, Matthew; Boriboonsomsin, Kanok

    2009-01-01

    TATES IS A source of greenhouse gas emissions, and thereforeis increased emissions of greenhouse gases. Althoughthat driving contributes to greenhouse gas emis- sions, the

  9. Investigating and Using Biomass Gases

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigating and Using Biomass Gases Grades: 9-12 Topic: Biomass Authors: Eric Benson and Melissa Highfill Owner: National Renewable Energy Laboratory This educational material is...

  10. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  11. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  12. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  13. Regional respiratory tract absorption of inhaled reactive gases

    SciTech Connect (OSTI)

    Miller, F.J.; Overton, J.H.; Kimbell, J.S.; Russell, M.L.

    1992-06-29

    Highly reactive gases present unique problems due to the number of factors which must be taken into account to determine regional respiratory tract uptake. The authors reviewed some of the physical, chemical, and biological factors that affect dose and that must be understood to interpret toxicological data, to evaluate experimental dosimetry studies, and to develop dosimetry models. Selected dosimetry experiments involving laboratory animals and humans were discussed, showing the variability and uptake according to animal species and respiratory tract region for various reactive gases. New experimental dosimetry approaches, such as those involving isotope ratio mass spectroscopy and cyclotron generation reactive gases, were discussed that offer great promise for improving the ability to study regional respiratory tract absorption of reactive gases. Various dosimetry modeling applications were discussed which demonstrate: the importance of airflow patterns for site-specific dosimetry in the upper respiratory tract, the influence of the anatomical model used to make inter- and intraspecies dosimetric comparisons, the influence of tracheobronchial path length on predicted dose curves, and the implications of ventilatory unit structure and volume on dosimetry and response. Collectively, these examples illustrate important aspects of regional respiratory tract absorption of inhaled reactive gases. Given the complex nature of extent and pattern of injury in the respiratory tract from exposure to reactive gases, understanding interspecies differences in the absorption of reactive gases will continue to be an important area for study.

  14. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  15. Reactive greenhouse gas scenarios: Systematic exploration of uncertainties and the role of atmospheric chemistry

    E-Print Network [OSTI]

    Prather, Michael J; Holmes, Christopher D; Hsu, Juno

    2012-01-01

    et al. (2011b), The RCP greenhouse gas concentrations andResearch Council (2010), Greenhouse Gas Emissions: MethodsATMOSPHERIC CHEMISTRY AND GREENHOUSE GASES Prather, M. , and

  16. Atmospheric Test Models and Numerical Experiments for the Simulation of the Global Distributions of Weather Data Transponders III. Horizontal Distributions

    SciTech Connect (OSTI)

    Molenkamp, C.R.; Grossman, A.

    1999-12-20

    A network of small balloon-borne transponders which gather very high resolution wind and temperature data for use by modern numerical weather predication models has been proposed to improve the reliability of long-range weather forecasts. The global distribution of an array of such transponders is simulated using LLNL's atmospheric parcel transport model (GRANTOUR) with winds supplied by two different general circulation models. An initial study used winds from CCM3 with a horizontal resolution of about 3 degrees in latitude and longitude, and a second study used winds from NOGAPS with a 0.75 degree horizontal resolution. Results from both simulations show that reasonable global coverage can be attained by releasing balloons from an appropriate set of launch sites.

  17. An analytical inversion method for determining regional and global emissions of greenhouse gases: Sensitivity studies and application to halocarbons

    E-Print Network [OSTI]

    Stohl, A.

    A new analytical inversion method has been developed to determine the regional and global emissions of long-lived atmospheric trace gases. It exploits in situ measurement data from three global networks and builds on ...

  18. On detecting biospheres from thermodynamic disequilibrium in planetary atmospheres

    E-Print Network [OSTI]

    Krissansen-Totton, Joshua; Catling, David C

    2015-01-01

    Atmospheric chemical disequilibrium has been proposed as a method for detecting extraterrestrial biospheres from exoplanet observations. Chemical disequilibrium is potentially a generalized biosignature since it makes no assumptions about particular biogenic gases or metabolisms. Here, we present the first rigorous calculations of the thermodynamic chemical disequilibrium in the atmospheres of Solar System planets, in which we quantify the difference in Gibbs free energy of an observed atmosphere compared to that of all the atmospheric gases reacted to equilibrium. The purely gas phase disequilibrium in Earth's atmosphere, as measured by this available Gibbs free energy, is not unusual by Solar System standards and smaller than that of Mars. However, Earth's atmosphere is in contact with a surface ocean, which means that gases can react with water, and so a multiphase calculation that includes aqueous species is required. We find that the disequilibrium in Earth's atmosphere-ocean system (in joules per mole o...

  19. The mean climate of the Community Atmosphere Model (CAM4) in forced SST and fully coupled experiments

    SciTech Connect (OSTI)

    Neale, Richard; Richter, Jadwiga; Park, Sungsu; Lauritzen, P. H.; Vavrus, Steven J.; Rasch, Philip J.; Zhang, Minghua

    2013-07-15

    The Community Atmosphere Model, version 4 (CAM4) was released as the atmosphere component of the Community Climate System Model, version 4 (CCSM4) and is described. The finite volume dynamical core available in CAM3 is now the default due to its superior transport and conservation properties. Deep convection parameterization changes include a dilute plume calculation of convective available potential energy (CAPE) and the introduction of a formulation for Convective Momentum Transport (CMT). For the cloud fraction an additional calculation is performed following macrophysical state updates that provides improved thermodynamic condistancy. A freeze-drying modification is further made to the cloud fraction calculation in very dry environments, such as arctic Winter, where cloud fractionand cloud water estimates were often inconsistant in CAM3. In CAM4 the finite volume dynamical core leads to a degradation in the excessive trade-wind simulation, but with an accompanying reduction in zonal stresses at higher latitudes. Plume dilution leads to a moister deep tropics alleviating much of the mid-tropospheric dry biases and reduces the persistant precipitation biases over the Arabian peninsular and the southern Indian ocean during the Indian Monsoon. CMT reduces much of the excessive trade-wind biases in eastern ocean basins. The freeze drying modification alleviates much of the high latitude, winter-time excessive cloud bias and improves the associated surface cloud-related energy budget, but the updated cloud macrophysical calculation generally leads to reduced cloud fraction and cloud forcing away from high latitudes. Although there are marginal improvements in time-averaged, large-scale hydrology there are signficant improvements in regional climate features such as the generation of tropical and propagation of stationary waves from the Pacific into mid-latitudes and in the seasonal frequency of Northern Hemisphere blocking events. A 1? versus 2? horizontal resolution of the finite volume 24 dynamical core exhibits signficiant improvements in model climate. Improvements in the fully coupled mean climate between CAM3 and CAM4 are also much more signficant than in forced Sea Surface Temperature (SST) simulations. Furthermore, improvements in the transient characteristics ofthe model climate, documented elsewhere, are substantial.

  20. Atmospheric Environment ] (

    E-Print Network [OSTI]

    Raman, Sethu

    that the influence of the urban region on wind patterns and atmospheric stability could be studied. HeightAtmospheric Environment ] (

  1. NEW ATLAS9 AND MARCS MODEL ATMOSPHERE GRIDS FOR THE APACHE POINT OBSERVATORY GALACTIC EVOLUTION EXPERIMENT (APOGEE)

    SciTech Connect (OSTI)

    Meszaros, Sz.; Allende Prieto, C.; De Vicente, A.; Edvardsson, B.; Gustafsson, B.; Castelli, F.; Garcia Perez, A. E.; Majewski, S. R.; Plez, B.; Schiavon, R.; Shetrone, M.

    2012-10-01

    We present a new grid of model photospheres for the SDSS-III/APOGEE survey of stellar populations of the Galaxy, calculated using the ATLAS9 and MARCS codes. New opacity distribution functions were generated to calculate ATLAS9 model photospheres. MARCS models were calculated based on opacity sampling techniques. The metallicity ([M/H]) spans from -5 to 1.5 for ATLAS and -2.5 to 0.5 for MARCS models. There are three main differences with respect to previous ATLAS9 model grids: a new corrected H{sub 2}O line list, a wide range of carbon ([C/M]) and {alpha} element [{alpha}/M] variations, and solar reference abundances from Asplund et al. The added range of varying carbon and {alpha}-element abundances also extends the previously calculated MARCS model grids. Altogether, 1980 chemical compositions were used for the ATLAS9 grid and 175 for the MARCS grid. Over 808,000 ATLAS9 models were computed spanning temperatures from 3500 K to 30,000 K and log g from 0 to 5, where larger temperatures only have high gravities. The MARCS models span from 3500 K to 5500 K, and log g from 0 to 5. All model atmospheres are publicly available online.

  2. Atmospheric test models and numerical experiments for the simulation of the global distribution of weather data transponders

    SciTech Connect (OSTI)

    Grossman, A; Molenkamp, C R

    1999-08-25

    A proposal has been made to establish a high density global network of atmospheric micro transponders to record time, temperature, and wind data with time resolution of {le} 1 minute, temperature accuracy of {+-} 1 K, spatial resolution no poorer than {approx}3km horizontally and {approx}0.1km vertically, and 2-D speed accuracy of {le} 1m/s. This data will be used in conjunction with advanced numerical weather prediction models to provide increases in the reliability of long range weather forecasts. Major advances in data collection technology will be required to provide the proposed high-resolution data collection network. Systems studies must be undertaken to determine insertion requirements, spacing, and evolution of the transponder ensemble, which will be used to collect the data. Numerical models which provide realistic global weather pattern simulations must be utilized in order to perform these studies. A global circulation model with a 3{sup o} horizontal resolution has been used for initial simulations of the generation and evolution of transponder distributions. These studies indicate that reasonable global coverage of transponders can be achieved by a launch scenario consisting of the sequential launch of transponders at specified heights from a globally distributed set of launch sites.

  3. ARM - Field Campaign - Aerosol and Cloud Experiments in the Eastern...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    horizontal variabilities of aerosol, trace gases, cloud, drizzle, and atmospheric thermodynamics are critically needed for understanding and quantifying the budget of MBL aerosol,...

  4. Atmospheric Radiation Measurement (ARM) Data from Steamboat Springs, Colorado, for the Storm Peak Laboratory Cloud Property Validation Experiment (STORMVEX)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    In October 2010, the initial deployment of the second ARM Mobile Facility (AMF2) took place at Steamboat Springs, Colorado, for the Storm Peak Laboratory Cloud Property Validation Experiment (STORMVEX). The objective of this field campaign was to obtain data about liquid and mixed-phase clouds using AMF2 instruments in conjunction with Storm Peak Laboratory (located at an elevation of 3220 meters on Mt. Werner), a cloud and aerosol research facility operated by the Desert Research Institute. STORMVEX datasets are freely available for viewing and download. Users are asked to register with the ARM Archive; the user's email address is used from that time forward as the login name.

  5. ARM - Amount of Greenhouse Gases in the Global Atmosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers'OrganizationgovAboutAcronyms

  6. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  7. Castaing Instability and Precessing Domains in Confined Alkali Gases

    E-Print Network [OSTI]

    A. Kuklov; A. E. Meyerovich

    2002-02-05

    We explore analogy between two-component quantum alkali gases and spin-polarized helium systems. Recent experiments in trapped gases are put into the frame of the existing theory for Castaing instability in transverse channel and formation of homogeneous precessing domains in spin-polarized systems. Analogous effects have already been observed in spin-polarized $% ^{3}He$ and $^{3}He- ^{4}He$ mixtures systems. The threshold effect of the confining potential on the instability is analyzed. New experimental possibilities for observation of transverse instability in a trap are discussed.

  8. Predicted Abundances of Carbon Compounds in Volcanic Gases on Io

    E-Print Network [OSTI]

    Laura Schaefer; Bruce Fegley Jr

    2004-09-17

    We use chemical equilibrium calculations to model the speciation of carbon in volcanic gases on Io. The calculations cover wide temperature (500-2000 K), pressure (10^-8 to 10^+2 bars), and composition ranges (bulk O/S atomic ratios \\~0 to 3), which overlap the nominal conditions at Pele (1760 K, 0.01 bar, O/S ~ 1.5). Bulk C/S atomic ratios ranging from 10^-6 to 10^-1 in volcanic gases are used with a nominal value of 10^-3 based upon upper limits from Voyager for carbon in the Loki plume on Io. Carbon monoxide and CO2 are the two major carbon gases under all conditions studied. Carbonyl sulfide and CS2 are orders of magnitude less abundant. Consideration of different loss processes (photolysis, condensation, kinetic reactions in the plume) indicates that photolysis is probably the major loss process for all gases. Both CO and CO2 should be observable in volcanic plumes and in Io's atmosphere at abundances of several hundred parts per million by volume for a bulk C/S ratio of 10^-3.

  9. Hard probes of strongly-interacting atomic gases

    SciTech Connect (OSTI)

    Nishida, Yusuke

    2012-06-18

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  10. A Biomass-based Model to Estimate the Plausibility of Exoplanet Biosignature Gases

    E-Print Network [OSTI]

    Seager, S; Hu, R

    2013-01-01

    Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H2S, CH4, CH3Cl, and DMS. We have applied the models to propose NH3 as a biosignature gas on a "cold Haber World," a planet with a N2-H2 atmosphere, and to demonstrate why gases such as CH3Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such...

  11. Role of metastable atoms in the propagation of atmospheric pressure dielectric barrier discharge jets

    SciTech Connect (OSTI)

    Li Qing; Zhu Ximing; Li Jiangtao; Pu Yikang [Department of Engineering Physics, Tsinghua University, Beijing 100084 (China)

    2010-02-15

    In the experiment of plasma jets generated in a tube dielectric barrier discharge configuration, three distinguishable modes, namely, laminar, transition, and turbulent jet modes, have been identified. Flows of helium, neon, and argon gases shared the hydrodynamic law when their plasma jets spraying into ambient air of atmospheric pressure and room temperature. Aiming to reveal the basic processes, we propose that plasma jet length is mainly determined by reactions involving metastable atoms. These processes are responsible for the variation in plasma jet length versus gas flow rate and working gas species. To investigate this proposal in detail, we have obtained three significant experimental results, i.e., (1) the plasma jet lengths of helium, neon, and argon are different; (2) the plasma jet length of krypton slightly changes with gas flow rate, with three modes indistinguishable; and (3) there are large differences between optical emission spectra of helium, neon, argon, and krypton flow gases. These observations are in good agreement with our proposal.

  12. CLIMATICALLY-ACTIVE GASES IN THE EASTERN BOUNDARY UPWELLING AND OXYGEN MINIMUM ZONE (OMZ) SYSTEMS

    E-Print Network [OSTI]

    Garbe, Christoph S.

    . In this contribution we introduce Index Terms-- Air-Sea Interactions, Fluxes, Green House Gases, Satellite Retrieval) contribute very significantly to the gas exchange between the ocean and the atmosphere, notably with respect (Oxygen Minimum Zone) contribute very significantly to the gas exchange between the ocean

  13. The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions

    E-Print Network [OSTI]

    Guenther, A. B.

    The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1) is a modeling framework for estimating fluxes of biogenic compounds between terrestrial ecosystems and the atmosphere using simple mechanistic ...

  14. Greenhouse gases mitigation options and strategies for Tanzania

    SciTech Connect (OSTI)

    Mwandosya, M.J.; Meena, H.E.

    1996-12-31

    Tanzania became a party to the United Nations Framework on Climate Change (UN FCCC) when she ratified the Convention in March, 1996. Now that Tanzania and other developing countries are Parties to the UN FCCC, compliance with its provisions is mandatory. The legal requirements therefore provide a basis for their participation in climate change studies and policy formulation. All parties to the Convention are required by Article 4.1 of the United Nations Convention on Climate Change (UN FCCC) to develop, periodically update, publish, and make available national inventories of anthropogenic emissions and removal of greenhouse gases that are not controlled by the Montreal Protocol. This study on possible options for the mitigation of greenhouse gases in Tanzania is a preliminary effort towards the fulfilment of the obligation. In order to fulfil their obligations under the UN FCCC and have a meaningful mitigation assessment, identification and quantification of anthropogenic sources of atmospheric emissions of greenhouse gases in the country was undertaken. In this respect, the study of anthropogenic emissions by source and removals by sink of GHGs in Tanzania was done with the main objective of increasing the quantity and quality of base-line data available in order to further scientific understanding of the relationship of greenhouse gas emissions to climate change. Furthermore, the study facilitated identification of national policy and technological options that could reduce the level of emissions in the country.

  15. Observations of atmospheric tides on Mars at the season and latitude of the Phoenix atmospheric entry

    E-Print Network [OSTI]

    Withers, Paul

    Observations of atmospheric tides on Mars at the season and latitude of the Phoenix atmospheric atmospheric entry of NASA's Phoenix Mars probe using Phoenix Atmospheric Structure Experiment (ASE) data atmospheric entry, Geophys. Res. Lett., 37, L24204, doi:10.1029/2010GL045382. 1. Introduction [2] Phoenix

  16. Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3]) have the poten-

    E-Print Network [OSTI]

    Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3 gases (greenhouse gases) altered by human activities (IPCC 2007), only carbon dioxide (CO2 vegeta- tion properties affect local and regional climate, as well as how atmospheric forcing

  17. Development of the first nonhydrostatic nested-grid grid-point global atmospheric modeling system on parallel machines

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Langley, D.L.; Reisner, J.M.; Smith, W.S.

    1998-11-01

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Evaluating the importance of global and regional climate response to increasing atmospheric concentrations of greenhouse gases requires a comprehensive global atmospheric modeling system (GAMS) capable of simulations over a wide range of atmospheric circulations, from complex terrain to continental scales, on high-performance computers. Unfortunately, all of the existing global circulation models (GCMs) do not meet this requirements, because they suffer from one or more of the following three shortcomings: (1) use of the hydrostatic approximation, which makes the models potentially ill-posed; (2) lack of a nested-grid (or multi-grid) capability, which makes it difficult to consistently evaluate the regional climate response to the global warming, and (3) spherical spectral (opposed to grid-point finite-difference) representation of model variables, which hinders model performance for parallel machine applications. The end product of the research is a highly modularized, multi-gridded, self-calibratable (for further parameterization development) global modeling system with state-of-the-science physics and chemistry. This system will be suitable for a suite of atmospheric problems: from local circulations to climate, from thunderstorms to global cloud radiative forcing, from urban pollution to global greenhouse trace gases, and from the guiding of field experiments to coupling with ocean models. It will also provide a unique testbed for high-performance computing architecture.

  18. Emissions of greenhouse gases in the United States, 1985--1990

    SciTech Connect (OSTI)

    Not Available

    1993-11-10

    The Earth`s capacity to support life depends on the moderating influences of gases that envelop the planet and warm its surface and protect it from harmful radiation. These gases are referred to as ``greenhouse gases.`` Their warming capacity, called ``the greenhouse effect,`` is essential to maintaining a climate hospitable to all plant, animal, and human life. In recent years, however, there has been increasing concern that human activity may be affecting the intricate balance between the Earth`s absorption of heat from the sun and its capacity to reradiate excess heat back into space. Emissions of greenhouse gases from human activities may be an important mechanism that affects global climate. Thus, research is intensifying to improve our understanding of the role human activities might play in influencing atmospheric concentrations of greenhouse gases. On the basis of scientific findings of the past few decades, the US Government and the international community at large are now taking steps toward stabilizing greenhouse gas emissions. This report contributes to that process. Mandated by Congress this report provides estimates of US emissions of the principal greenhouse gases--carbon dioxide, methane, nitrous oxide, chlorofluorcarbons, carbon monoxide, nitrogen oxides, and nonmethane volatile organic compounds. Estimates are for the period 1985 to 1990. Preliminary estimates for 1991 have also been included, whenever data were available.

  19. Method of concurrently filtering particles and collecting gases

    DOE Patents [OSTI]

    Mitchell, Mark A; Meike, Annemarie; Anderson, Brian L

    2015-04-28

    A system for concurrently filtering particles and collecting gases. Materials are be added (e.g., via coating the ceramic substrate, use of loose powder(s), or other means) to a HEPA filter (ceramic, metal, or otherwise) to collect gases (e.g., radioactive gases such as iodine). The gases could be radioactive, hazardous, or valuable gases.

  20. Thermalization of Gases: A First Principles Approach

    E-Print Network [OSTI]

    Clifford Chafin

    2015-06-20

    Previous approaches of emergent thermalization for condensed matter based on typical wavefunctions are extended to generate an intrinsically quantum theory of gases. Gases are fundamentally quantum objects at all temperatures, by virtue of rapid delocalization of their constituents. When there is a sufficiently broad spread in the energy of eigenstates, a well-defined temperature is shown to arise by photon production when the samples are optically thick. This produces a highly accurate approximation to the Planck distribution so that thermalization arises from the initial data as a consequence of purely quantum and unitary dynamics. These results are used as a foil for some common hydrodynamic theory of ultracold gases. It is suggested here that strong history dependence typically remains in these gases and so limits the validity of thermodynamics in their description. These problems are even more profound in the extension of hydrodynamics to such gases when they are optically thin, even when their internal energy is not low. We investigate rotation of elliptically trapped gases and consistency problems with deriving a local hydrodynamic approach. The presence of vorticity that is "hidden" from order parameter approaches is discussed along with some buoyancy intrinsically associated with vorticity that gives essential quantum corrections to gases in the regimes where standard perturbation approaches to the Boltzmann equations are known to fail to converge. These results suggest that studying of trapped gases in the far from ultracold regions may yield interesting results not described by classical hydrodynamics.

  1. Stable microwave coaxial cavity plasma system at atmospheric pressure

    SciTech Connect (OSTI)

    Song, H. [Department of Electrical and Computer Engineering, University of Colorado, Colorado Springs, Colorado 80918 (United States); Hong, J. M.; Lee, K. H. [Plasma Systems and Materials (PSM) Inc., Sungnam-Si, Gyonggi-Do 190-1 (Korea, Republic of); Choi, J. J. [Department of Radio Science and Engineering, Kwangwoon University, Nowon-Gu, Seoul 447-1 (Korea, Republic of)

    2008-05-15

    We present a systematic study of the development of a novel atmospheric microwave plasma system for material processing in the pressure range up to 760 torr and the microwave input power up to 6 kW. Atmospheric microwave plasma was reliably produced and sustained by using a cylindrical resonator with the TM{sub 011} cavity mode. The applicator and the microwave cavity, which is a cylindrical resonator, are carefully designed and optimized with the time dependent finite element Maxwell equation solver. The azimuthal apertures are placed at the maximum magnetic field positions between the cavity and the applicator to maximize the coupling efficiency into the microwave plasma at a resonant frequency of 2.45 GHz. The system consists of a magnetron power supply, a circulator, a directional coupler, a three-stub tuner, a dummy load, a coaxial cavity, and a central cavity. Design and construction of the resonant structures and diagnostics of atmospheric plasma using optical experiments are discussed in various ranges of pressure and microwave input power for different types of gases.

  2. Measuring non-condensable gases in steam

    SciTech Connect (OSTI)

    Doornmalen, J. P. C. M. van; Kopinga, K., E-mail: k.kopinga@tue.nl [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2013-11-15

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1%) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M{sup TM} Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

  3. Scientific Achievement Networks of highly photoresponsive crystalline GaSe

    E-Print Network [OSTI]

    Geohegan, David B.

    Scientific Achievement Networks of highly photoresponsive crystalline GaSe nanosheets a crystalline GaSe target was adjusted to directly grow networks of interconnected triangular GaSe crystalline nanosheets of ~ 200 nm size (inset shows atomic

  4. Atmospheric Neutrinos

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2006-12-11

    This paper is a brief overview of the theory and experimental data of atmospheric neutrino production at the fiftieth anniversary of the experimental discovery of neutrinos.

  5. Atmospheric Test Models and Numerical Experiments for the Simulation of the Global Distribution of Weather Data Transponders II. Vertical Transponder Motion Considerations

    SciTech Connect (OSTI)

    Grossman, A.; Errico, R.M.

    1999-11-29

    The vertical motion of constant density atmospheric balloons has been considered via an equation of motion for the vertical displacement of a balloon, due to vertical air motion, which can be numerically solved for balloon positions. Initial calculations are made for a constant density atmosphere. Various vertical wind models with relatively large amplitudes are applied to the model to determine how tightly the balloons are coupled to the reference level and the time scale for the balloons to change to the wind driven reference altitude. A surface launch of a balloon to a 6 km reference altitude is modeled using a detailed atmospheric pressure-density-temperature profile in the equation of motion. The results show the balloons to be relatively tightly coupled ({approx} 50-100 m) to the reference altitude.

  6. Welcome to Greenhouse Gases: Science and Technology: Editorial

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2013-01-01

    Welcome to Greenhouse Gases: Science and Technology510) 486-7419 Welcome to Greenhouse Gases: Science andand interviews on greenhouse gas emissions science and

  7. The Greenhouse Gases, Regulated Emissions, and Energy Use in...

    Open Energy Info (EERE)

    The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation Model (GREET) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Greenhouse Gases, Regulated...

  8. Energy Efficiency and Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as deemed appropriate for LM operations...

  9. Remote Sensing and In-Situ Observations of Arctic Mixed-Phase and Cirrus Clouds Acquired During Mixed-Phase Arctic Cloud Experiment: Atmospheric Radiation Measurement Uninhabited Aerospace Vehicle Participation

    SciTech Connect (OSTI)

    McFarquhar, G.M.; Freer, M.; Um, J.; McCoy, R.; Bolton, W.

    2005-03-18

    The Atmospheric Radiation Monitor (ARM) uninhabited aerospace vehicle (UAV) program aims to develop measurement techniques and instruments suitable for a new class of high altitude, long endurance UAVs while supporting the climate community with valuable data sets. Using the Scaled Composites Proteus aircraft, ARM UAV participated in Mixed-Phase Arctic Cloud Experiment (M-PACE), obtaining unique data to help understand the interaction of clouds with solar and infrared radiation. Many measurements obtained using the Proteus were coincident with in-situ observations made by the UND Citation. Data from M-PACE are needed to understand interactions between clouds, the atmosphere and ocean in the Arctic, critical interactions given large-scale models suggest enhanced warming compared to lower latitudes is occurring.

  10. Denitrification of combustion gases. [Patent application

    DOE Patents [OSTI]

    Yang, R.T.

    1980-10-09

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  11. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect (OSTI)

    1996-07-01

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  12. Interpretation of observed atmospheric variations of CO2 and CH4.

    E-Print Network [OSTI]

    Barlow, James Mathew

    2015-06-30

    The overarching theme of my thesis is understanding observed variations of northern hemisphere atmospheric carbon dioxide (CO2) and methane (CH4) concentrations. I focus my analysis on high-latitude observations of these gases, as there are large...

  13. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2002-01-22

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  14. Atmospheric sampling glow discharge ionization source

    DOE Patents [OSTI]

    McLuckey, S.A.; Glish, G.L.

    1989-07-18

    An atmospheric sampling glow discharge ionization source that can be used in combination with an analytical instrument which operates at high vacuum, such as a mass spectrometer. The atmospheric sampling glow discharge ionization source comprises a chamber with at least one pair of electrodes disposed therein, an inlet for a gaseous sample to be analyzed and an outlet communicating with an analyzer which operates at subatmospheric pressure. The ionization chamber is maintained at a pressure below atmospheric pressure, and a voltage difference is applied across the electrodes to induce a glow discharge between the electrodes, so that molecules passing through the inlet are ionized by the glow discharge and directed into the analyzer. The ionization source accepts the sample under atmospheric pressure conditions and processes it directly into the high vacuum instrument, bridging the pressure gap and drawing off unwanted atmospheric gases. The invention also includes a method for analyzing a gaseous sample using the glow discharge ionization source described above. 3 figs.

  15. Alkali and Halogen Chemistry in Volcanic Gases on Io

    E-Print Network [OSTI]

    Laura Schaefer; Bruce Fegley Jr

    2004-09-20

    We use chemical equilibrium calculations to model the speciation of alkalis and halogens in volcanic gases emitted on Io. The calculations cover wide temperature (500-2000 K) and pressure (10^-6 to 10^+1 bars) ranges, which overlap the nominal conditions at Pele (T = 1760 K, P = 0.01 bars). About 230 compounds of 11 elements (O, S, Li, Na, K, Rb, Cs, F, Cl, Br, I) are considered. We predict the major alkali and halogen species in a Pele-like volcanic gas and the major alklai and halogen condensates. We also model disequilibrium chemistry of the alkalis and halogens in the volcanic plume. Based on this work and our prior modeling for Na, K, and Cl in a volcanic plume, we predict the major loss processes for the alkali halide gases are photolysis and/or condensation onto grains. On the basis of elemental abundances and photochemical lifetimes, we recommend searching for gaseous KCl, NaF, LiF, LiCl, RbF, RbCl, CsF, and CsCl around volcanic vents during eruptions. Based on abundance considerations and observations of brown dwarfs, we also recommend a search of Io's extended atmosphere and the Io plasma torus for neutral and ionized Li, Cs, Rb, and F.

  16. Atmospheric Chemistry and Air Pollution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemoreand peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.less

  17. Elliptic flow and nearly perfect fluidity in dilute Fermi gases

    E-Print Network [OSTI]

    Thomas Schaefer

    2010-12-16

    In this contribution we summarize recent progress in understanding the shear viscosity of strongly correlated dilute Fermi gases. We discuss predictions from kinetic theory, and show how these predictions can be tested using recent experimental data on elliptic flow. We find agreement between theory and experiments in the high temperature regime $T\\gg T_F$, where $T_F$ is the the temperature where quantum degeneracy effects become important. In the low temperature regime, $T\\sim T_F$, the strongest constraints on the shear viscosity come from experimental studies of the damping of collective modes. These experiments indicate that $\\eta/s\\lsim 0.5\\hbar/k_B$, where $\\eta$ is the shear viscosity and $s$ is the entropy density.

  18. Cmo simular flujo de gases reactivos con

    E-Print Network [OSTI]

    Politcnica de Catalunya, Universitat

    Cmo simular flujo de gases reactivos con RetrasoCodeBright? Maarten W. Saaltink #12;Procesos Difusin de especies gaseosas Flujo de gas reactivo Se forma/consume especies gaseosas por reacciones dispersin #12;Tipos de fenmenos Descomposicin de materia orgnica CH2O + O2(g) CO2(g) + H2O CH2O + 0.8NO3

  19. Lesson Summary Students will use models of Earth's atmosphere

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    to Do Scientific Inquiry Physical Science Transfer of Energy Earth and Space Science Structure the greenhouse from the captured solar energy. Certain gases in Earth's atmosphere especially water vapor by storing and releasing energy from the sun. Materials: Large pickle jars, smaller jelly jar, laboratory

  20. Unstructured Adaptive Mesh MOL Solvers for Atmospheric Reacting

    E-Print Network [OSTI]

    Utah, University of

    . Achieving high resolution in air pollution models is a difficult challenge because of the large number for the next generation of air pollution models in order to "capture important smaller scale atmospheric in understanding the complex processes which lead to the formation of pollutants such as greenhouse gases, acid

  1. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  2. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, C.E.

    1997-06-10

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  3. Scale-invariant nonlinear optics in gases

    E-Print Network [OSTI]

    Heyl, C M; Miranda, M; Louisy, M; Kovacs, K; Tosa, V; Balogh, E; Varj, K; L'Huillier, A; Couairon, A; Arnold, C L

    2015-01-01

    Nonlinear optical methods are becoming ubiquitous in many areas of modern photonics. They are, however, often limited to a certain range of input parameters, such as pulse energy and average power, since restrictions arise from, for example, parasitic nonlinear effects, damage problems and geometrical considerations. Here, we show that many nonlinear optics phenomena in gaseous media are scale-invariant if spatial coordinates, gas density and laser pulse energy are scaled appropriately. We develop a general scaling model for (3+1)-dimensional wave equations, demonstrating the invariant scaling of nonlinear pulse propagation in gases. Our model is numerically applied to high-order harmonic generation and filamentation as well as experimentally verified using the example of pulse post-compression via filamentation. Our results provide a simple recipe for up-or downscaling of nonlinear processes in gases with numerous applications in many areas of science.

  4. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  5. Physics Potential of Future Atmospheric Neutrino Searches

    E-Print Network [OSTI]

    Thomas Schwetz

    2008-12-12

    The potential of future high statistics atmospheric neutrino experiments is considered, having in mind currently discussed huge detectors of various technologies (water Cerekov, magnetized iron, liquid Argon). I focus on the possibility to use atmospheric data to determine the octant of $\\theta_{23}$ and the neutrino mass hierarchy. The sensitivity to the $\\theta_{23}$-octant of atmospheric neutrinos is competitive (or even superior) to long-baseline experiments. I discuss the ideal properties of a fictitious atmospheric neutrino detector to determine the neutrino mass hierarchy.

  6. RESULTS FROM THE PHOENIX ATMOSPHERIC STRUCTURE PAUL WITHERS*,a

    E-Print Network [OSTI]

    Withers, Paul

    RESULTS FROM THE PHOENIX ATMOSPHERIC STRUCTURE EXPERIMENT PAUL WITHERS*,a AND DAVID C. CATLINGb through the atmosphere of Mars, Phoenix recorded acceleration and angular velocity data using the Experimental Data Records (EDRs) of the Phoenix Atmospheric Structure Experiment (ASE), are available from

  7. Device for accurately measuring mass flow of gases

    DOE Patents [OSTI]

    Hylton, J.O.; Remenyik, C.J.

    1994-08-09

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure is disclosed. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel. 5 figs.

  8. Device for accurately measuring mass flow of gases

    DOE Patents [OSTI]

    Hylton, James O. (Clinton, TN); Remenyik, Carl J. (Knoxville, TN)

    1994-01-01

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel.

  9. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  10. The greenhouse gases HFCs, PFCs Danish consumption and emissions, 2007

    E-Print Network [OSTI]

    The greenhouse gases HFCs, PFCs and SF6 Danish consumption and emissions, 2007 Tomas Sander Poulsen AND EMISSION OF F-GASES 7 1.1.1 Consumption 7 1.1.2 Emission 7 1.1.3 Trends in total GWP contribution from F 21 4 EMISSION OF F-GASES 23 4.1.1 Emissions of HFCs from refrigerants 23 4.1.2 Emissions of HFCs from

  11. HYPERsensarium : an archive of atmospheric conditions

    E-Print Network [OSTI]

    Shaw, Kelly E. (Kelly Evelyn)

    2013-01-01

    HYPERsensarium proposes a tangible interface of atmospheres for public experience through an archive of historical and projected weathers. While architecture's purpose has long been to act as the technical boundary between ...

  12. Deviation from the Knudsen law on quantum gases

    SciTech Connect (OSTI)

    Babac, Gulru

    2014-12-09

    Gas flow in micro/nano scale systems has been generally studied for the Maxwell gases. In the limits of very low temperature and very confined domains, the Maxwellian approximation can break down and the quantum character of the gases becomes important. In these cases, Knudsen law, which is one of the important equations to analyze rarefied gas flows is invalid and should be reanalyzed for quantum gases. In this work, the availability of quantum gas conditions in the high Knudsen number cases is discussed and Knudsen law is analyzed for quantum gases.

  13. Test Results For Physical Separation Of Tritium From Noble Gases...

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Test Results For Physical Separation...

  14. Finalize Historic National Program to Reduce Greenhouse Gases...

    Open Energy Info (EERE)

    Finalize Historic National Program to Reduce Greenhouse Gases and Improve Fuel Economy for Cars and Trucks Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Finalize...

  15. Noble gases on metal surfaces: Insights on adsorption site preference

    SciTech Connect (OSTI)

    Chen, De-Li; Al-Saidi, W. A.; Johnson, J. Karl

    2011-12-19

    We use a nonlocal van der Waals density functional (vdW-DF) approach to reexamine the problem of why noble gases are experimentally observed to adsorb on low-coordination atop sites rather than on high-coordination hollow sites for several different metal surfaces. Previous calculations using density functional theory (DFT) within the local density approximation (LDA) ascribed the site preference to reduced Pauli repulsion at atop sites, largely due to reduced exchange repulsion within LDA-DFT. In contrast, our vdW-DF calculations show that site preference is not due to differences in the exchange repulsion at all, but rather the result of a delicate balance between the electrostatic and kinetic energies; surprisingly, exchange-correlation energies play a negligible role in determining site preference. In contrast to previous calculations, we find that experimental results cannot be explained in terms of binding energy differences between atop and hollow sites. Instead, we show that the hollow sites are transition states rather than minima on the two-dimensional potential energy surface, and therefore not likely to be observed in experiments. This phenomenon is quite general, holding for close-packed and non-close-packed metal surfaces. We show that inclusion of nonlocal vdW interactions is crucial for obtaining results in quantitative agreement with experiments for adsorption energies, equilibrium distances, and vibrational energies.

  16. On flame kernel formation and propagation in premixed gases

    SciTech Connect (OSTI)

    Eisazadeh-Far, Kian; Metghalchi, Hameed [Northeastern University, Mechanical and Industrial Engineering Department, Boston, MA 02115 (United States); Parsinejad, Farzan [Chevron Oronite Company LLC, Richmond, CA 94801 (United States); Keck, James C. [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

    2010-12-15

    Flame kernel formation and propagation in premixed gases have been studied experimentally and theoretically. The experiments have been carried out at constant pressure and temperature in a constant volume vessel located in a high speed shadowgraph system. The formation and propagation of the hot plasma kernel has been simulated for inert gas mixtures using a thermodynamic model. The effects of various parameters including the discharge energy, radiation losses, initial temperature and initial volume of the plasma have been studied in detail. The experiments have been extended to flame kernel formation and propagation of methane/air mixtures. The effect of energy terms including spark energy, chemical energy and energy losses on flame kernel formation and propagation have been investigated. The inputs for this model are the initial conditions of the mixture and experimental data for flame radii. It is concluded that these are the most important parameters effecting plasma kernel growth. The results of laminar burning speeds have been compared with previously published results and are in good agreement. (author)

  17. A 350-year atmospheric history for carbonyl sulfide inferred from Antarctic firn air and air trapped in ice

    E-Print Network [OSTI]

    Saltzman, Eric

    A 350-year atmospheric history for carbonyl sulfide inferred from Antarctic firn air and air August 2004; published 17 November 2004. [1] Carbonyl sulfide (COS) and other trace gases were measured: atmosphere composition, carbonyl sulfide, stratosphere sulfate aerosol Citation: Montzka, S. A., M. Aydin, M

  18. The stability of the thermohaline circulation in global warming experiments

    SciTech Connect (OSTI)

    Schmittner, A.; Stocker, T.F.

    1999-04-01

    A simplified climate model of the coupled ocean-atmosphere system is used to perform extensive sensitivity studies concerning possible future climate change induced by anthropogenic greenhouse gas emissions. Supplemented with an active atmospheric hydrological cycle, experiments with different rates of CO{sub 2} increase and different climate sensitivities are performed. The model exhibits a threshold value of atmospheric CO{sub 2} concentration beyond which the North Atlantic Deep Water formation stops and never recovers. For a climate sensitivity that leads to an equilibrium warming of 3.6 C for a doubling of CO{sub 2} and a rate of CO{sub 2} increase of 1% yr{sup {minus}1}, the threshold lies between 650 and 700 ppmv. Moreover, it is shown that the stability of the thermohaline circulation depends on the rate of increase of greenhouse gases. For a slower increase of atmospheric pCO{sub 2} the final amount that can be reached without a shutdown of the circulation is considerably higher. This rate-sensitive response is due to the uptake of heat and excess freshwater from the uppermost layers to the deep ocean. The increased equator-to-pole freshwater transport in a warmer atmosphere is mainly responsible for the cessation of deep water formation in the North Atlantic. Another consequence of the enhanced latent heat transport is a stronger warming at high latitudes. A model version with fixed water vapor transport exhibits uniform warming at all latitudes. The inclusion of a simple parameterization of the ice-albedo feedback increases the model sensitivity and further decreases the pole-to-equator temperature difference in a greenhouse climate. The possible range of CO{sub 2} threshold concentrations and its dependency on the rate of CO{sub 2} increase, on the climate sensitivity, and on other model parameters are discussed.

  19. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    NONE

    1999-05-01

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  20. Removal of mercury from waste gases

    SciTech Connect (OSTI)

    Muster, U.; Marr, R.; Pichler, G.; Kremshofer, S.; Wilferl, R.; Draxler, J.

    1996-12-31

    Waste and process gases from thermal power, incineration and metallurgical plants or those from cement and alkali chloride industries contain metallic, inorganic and organic mercury. Widespread processes to remove the major amount of mercury are absorption and adsorption. Caused by the lowering of the emission limit from 200 to 50 {mu}g/m{sup 3} [STP] by national and European legislators, considerable efforts were made to enhance the efficiency of the main separation units of flue gas cleaning plants. Specially impregnated ceramic carriers can be used for the selective separation of metallic, inorganic and organic mercury. Using the ceramic reactor removal rates lower than 5 {mu}g/m{sup 3} [STP] of gaseous mercury and its compounds can be achieved. The ceramic reactor is active, regenerable and stable for a long term operation. 4 refs., 7 figs.

  1. AMIII Termodinamica dos Gases Ideais 17 de Janeiro de 2002

    E-Print Network [OSTI]

    Natário, José

    AMIII ­ Termodin??amica dos Gases Ideais 17 de Janeiro de 2002 N moles de um g??as ideal em equil dos gases ideais). A Primeira Lei da Termodin??amica afirma que existe uma fun?c?ao E : M # R, dita pela Segunda Lei da Termodin??amica. 2 #12;

  2. Climate change and trace gases BY JAMES HANSEN

    E-Print Network [OSTI]

    Ford, Andrew

    Climate change and trace gases BY JAMES HANSEN 1,*, MAKIKO SATO 1 , PUSHKER KHARECHA 1 , GARY climate change that could run out of our control, with great dangers for humans and other creatures and the global environment. Keywords: climate change; trace gases; climate feedbacks; black carbon; sea level

  3. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  4. The role of van der Waals interactions in the adsorption of noble gases on metal surfaces

    SciTech Connect (OSTI)

    Chen, De-Li; Al-Saidi, W. A.; Johnson, J. Karl

    2012-10-24

    Adsorption of noble gases on metal surfaces is determined by weak interactions. We applied two versions of the nonlocal van der Waals density functional (vdW-DF) to compute adsorption energies of Ar, Kr, and Xe on Pt(111), Pd(111), Cu(111), and Cu(110) metal surfaces. We have compared our results with data obtained using other density functional approaches, including the semiempirical vdW corrected DFT-D2. The vdW-DF results show considerable improvements in the description of adsorption energies and equilibrium distances over other DFTbased methods, giving good agreement with experiments. We have also calculated perpendicular vibrational energies for noble gases on the metal surfaces using vdWDF data and found excellent agreement with available experimental results. Our vdW-DF calculations show that adsorption of noble gases on low-coordination sites is energetically favored over high-coordination sites, but only by a few meV. Analysis of the 2-dimensional potential energy surface shows that the high-coordination sites are local maxima on the 2-dimensional potential energy surface and therefore unlikely to be observed in experiments, which provides an explanation of the experimental observations. The DFT-D2 approach with the standard parameterization was found to overestimate the dispersion interactions, and to give the wrong adsorption site preference for four of the nine systems we studied.

  5. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect (OSTI)

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  6. Atmospheric Chemistry in Giant Planets, Brown Dwarfs, and Low-Mass Dwarf Stars II. Sulfur and Phosphorus

    E-Print Network [OSTI]

    Channon Visscher; Katharina Lodders; Bruce Fegley Jr

    2006-06-06

    Thermochemical equilibrium and kinetic calculations are used to model sulfur and phosphorus chemistry in giant planets, brown dwarfs, and extrasolar giant planets (EGPs). The chemical behavior of individual S- and P-bearing gases and condensates is determined as a function of pressure, temperature, and metallicity. The results are independent of particular model atmospheres and, in principle, the equilibrium composition along the pressure-temperature profile of any object can be determined. Hydrogen sulfide (H2S) is the dominant S-bearing gas throughout substellar atmospheres and approximately represents the atmospheric sulfur inventory. Silicon sulfide (SiS) is a potential tracer of weather in substellar atmospheres. Disequilibrium abundances of phosphine (PH3) approximately representative of the total atmospheric phosphorus inventory are expected to be mixed upward into the observable atmospheres of giant planets and T dwarfs. In hotter objects, several P-bearing gases (e.g., P2, PH3, PH2, PH, HCP) become increasingly important at high temperatures.

  7. Methane activation using noble gases in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-08-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gasesHe, Ne, and Aras additives. The empirical results obtained clearly indicate that methane activation is considerably affected by thy type of noble gas used. Through 0-D calculations, the discharge parameters inside the reactor, i.e., electron temperature and electron density, are estimated using experiment results. A comparison of the discharge characteristics and experimental results shows that the electron temperature is an important factor in achieving high methane activation and the mixture with Ar gas shows the highest methane conversion. These results are constructed using the mechanisms of energy and charge transfer from excited and ionized noble gas atoms to methane molecules, considering the number density of active atoms of noble gases. Finally, electron temperatures obtained for gas mixtures having different reactant compositions and concentrations are analyzed to estimate methane activation.

  8. GAS-GENERATION EXPERIMENTS FOR LONG-TERM STORAGE OF TRU WASTES AT WIPP

    SciTech Connect (OSTI)

    Felicione, F.S.; Carney, K.P.; Dwight, C.C.; Cummings, D.G.; Foulkrod, L.E.

    2003-02-27

    An experimental investigation was conducted for gas generation in contact-handled transuranic (CH-TRU) wastes subjected for several years to conditions similar to those expected to occur at the Waste Isolation Pilot Plant (WIPP) should the repository eventually become inundated with brine. Various types of actual CH-TRU wastes were placed into 12 corrosion-resistant vessels. The vessels were loosely filled with the wastes, which were submerged in synthetic brine having the same chemical composition as that in the WIPP vicinity. The vessels were also inoculated with microbes found in the Salado Formation at WIPP. The vessels were sealed, purged, and the approximately 750-ml headspace was pressurized with nitrogen gas to approximately 146 atmospheres to create anoxic conditions at the lithostatic pressure expected in the repository were it inundated. The temperature was maintained at the expected 30 C. The test program objective was to measure the quantities and species of gases generate d by metal corrosion, radiolysis, and microbial activity. These data will assist in the specification of the rates at which gases are produced under inundated repository conditions for use in the WIPP Performance Assessment computer models. These experiments were very carefully designed, constructed, instrumented, and performed. Approximately 6-1/2 years of continuous, undisturbed testing were accumulated. Several of the vessels showed significantly elevated levels of generated gases, virtually all of which was hydrogen. One vessel measured over 4.2% hydrogen, by volume. Two other vessels generated well over 1% hydrogen, and another was at nearly 1%. Only small quantities of other gases, principally carbon dioxide, were detected. Gas generation was found to depend strongly on the waste composition. The maximum hydrogen generation occurred in tests containing carbon steel. Average corrosion penetration rates in carbon-steel of up to 2.3 microns per year were deduced. Conversion of carbon to carbon dioxide was calculated to be up to 4.7 {micro}g-mol/yr/g-carbon.

  9. Latitudinal survey of middle atmospheric water vapor revealed by shipboard microwave spectroscopy. Master's thesis

    SciTech Connect (OSTI)

    Schrader, M.L.

    1994-05-01

    Water vapor is one of the most important greenhouse gases and is an important tracer of atmospheric motions in the middle atmosphere. It also plays an important role in the chemistry of the middle atmosphere and through its photodissociation by solar radiation, it is the major source of hydrogen escaping to space. Ground-based microwave measurements conducted in the 1980s have provided a fair understanding of the seasonal variation of mesospheric water vapor in the northern hemisphere mid-latitudes, but the global distribution of water vapor in the middle atmosphere is only beginning to be revealed by space-based measurements.

  10. Atmospheric Environment 38 (2004) 49414956 Ground-based and aircraft measurements of trace gases in

    E-Print Network [OSTI]

    2004-01-01

    /Physics Department, State University of New York, Old Westbury, NY 11568, USA c Arizona Department of Environmental of 1998, an extensive measurement campaign was fielded in the city of Phoenix and its environs 1) (Maricopa Ozone Emissions Inventory, 1999). In fact, there are no coal-fired power plants

  11. The second virial coefficient of the major atmospheric gases at low temperatures

    E-Print Network [OSTI]

    Claitor, Lilburn Carroll

    1948-01-01

    that encounters between molecules are rare, the only forces acting on the molecules are those of the retaining vessel. The behavior of a gas under such conditions 's expressed oy the ideal gas law, PV = RT where P is pressure, V is volume, R is the universal..., and, so long as encounters between three or more molecules are rare, the behavior of the gas can be expressed by PV = RT (I + Bj)) where') is the molal density and B is the second viriai coefficient. Th1s equation can also be written, approxi...

  12. Unconventional states and geometric effects in mesoscopic systems of ultra-cold atomic Fermi gases

    SciTech Connect (OSTI)

    Bolech, C. J.

    2014-10-15

    During the last decade, experiments all over the world started to test the superconducting state of matter using a newly developed mesoscopic tunable system: trapped ultra-cold atomic gases. Theorists and experimentalists hand-in-hand are now able to advance our understanding of the superconducting state by asking new questions that probe further into the physical mechanisms underlying the phenomenon and the door is open to the exploration of exotic unconventional superconducting states. In particular, a series of experiments on systems of trapped cold atomic gases were aimed at studying the effects of polarization on superconducting pairing. Two different experimental groups encountered surprising qualitative and quantitative discrepancies which seemed to be a function of the confining geometry and the cooling protocol. Our numerical studies demonstrate a tendency towards metastability and suggest an explanation for the observed discrepancy. From our calculations, the most likely solution which is consistent with the experiments supports a state strikingly similar to the so called FFLO state (after Ferrell, Fulde, Larkin and Ovchinnikov), which had been theorized long ago but eluded detection so far. Moreover, the three-dimensional scenario described above is reminiscent of predictions for one-dimensional systems of dilute polarized attractive gases and another set of ultra-cold-atom experiments incorporates optical lattices to study this reduced-dimensionality setting. The measurements are in quantitative agreement with theoretical calculations (using a wide array of numerical and analytic techniques) in which a partially polarized phase is found to be the one-dimensional analogue of the FFLO state. Moreover, exploring the dimensional-crossover regime, our latest findings indicate that the mesoscopic nature of these quasi-one-dimensional systems favors the appearance of a new type of Mott phase transition involving an emergent pair-superfluid of equal-spin fermions.

  13. Rethinking Downstream Regulation: California's Opportunity to Engage Households in Reducing Greenhouse Gases

    E-Print Network [OSTI]

    2008-01-01

    households in reducing greenhouse gases. Energy Policy (Tradable Permits for Greenhouse Gas Emissions: a Primer WithEIA, 2006a. Emissions of Greenhouse Gases in the United

  14. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  15. Spin noise spectroscopy to probe quantum states of ultracold fermionic atomic gases

    E-Print Network [OSTI]

    Bogdan Mihaila; Scott A. Crooker; Krastan B. Blagoev; Dwight G. Rickel; Peter B. Littlewood; Darryl L. Smith

    2006-01-01

    Ultracold alkali atoms provide experimentally accessible model systems for probing quantum states that manifest themselves at the macroscopic scale. Recent experimental realizations of superfluidity in dilute gases of ultracold fermionic (half-integer spin) atoms offer exciting opportunities to directly test theoretical models of related many-body fermion systems that are inaccessible to experimental manipulation, such as neutron stars and quark-gluon plasmas. However, the microscopic interactions between fermions are potentially quite complex, and experiments in ultracold gases to date cannot clearly distinguish between the qualitatively different microscopic models that have been proposed. Here, we theoretically demonstrate that optical measurements of electron spin noise -- the intrinsic, random fluctuations of spin -- can probe the entangled quantum states of ultracold fermionic atomic gases and unambiguously reveal the detailed nature of the interatomic interactions. We show that different models predict different sets of resonances in the noise spectrum, and once the correct effective interatomic interaction model is identified, the line-shapes of the spin noise can be used to constrain this model. Further, experimental measurements of spin noise in classical (Boltzmann) alkali vapors are used to estimate the expected signal magnitudes for spin noise measurements in ultracold atom systems and to show that these measurements are feasible.

  16. A Study of Atmospheric Deposition of Air Toxics to the Waters of Puget Sound

    E-Print Network [OSTI]

    Aguirre, Danielle

    2009-06-09

    Air pollutants can be deposited in many forms such as rain, snow, and gases. Urban centers are major sources of combustion-derived particulate matter, black carbon, and volatile organic carbon to the atmosphere. Expansion of urban centers in the 20...

  17. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

    1988-01-01

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  18. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  19. Modeling shows that alternative soil management can decrease greenhouse gases

    E-Print Network [OSTI]

    De Gryze, Steven; Albarracin, Maria Victoria; Catala-Luque, Rosa; Howitt, Richard E; Six, Johan

    2009-01-01

    warmer temperatures. Reducing greenhouse gases A (SacramentoMan. Yes Agricultural greenhouse-gas emis- sions can beWhether the decrease in greenhouse-gas emissions comes from

  20. Measuring the Isotopic Composition of Solar Wind Noble Gases

    E-Print Network [OSTI]

    Floss, Christine

    in meteorites are depleted by many orders of magnitude compared with the solar nebula and, although lunar soils the various components, these gases were extracted using stepped pyrolysis and analyzed in sensitive mass

  1. Low-Value Waste Gases as an Energy Source

    E-Print Network [OSTI]

    Waibel, R. T.

    1996-01-01

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  2. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

    1989-01-01

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  3. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999) Jump to: navigation, search OpenEI Reference LibraryAdd to library Report:...

  4. Viscosities of natural gases at high pressures and high temperatures

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  5. Studying coherence in ultra-cold atomic gases

    E-Print Network [OSTI]

    Miller, Daniel E. (Daniel Edward)

    2007-01-01

    This thesis will discuss the study of coherence properties of ultra-cold atomic gases. The atomic systems investigated include a thermal cloud of atoms, a Bose-Einstein condensate and a fermion pair condensate. In each ...

  6. Atmospheric Transport of Radionuclides

    SciTech Connect (OSTI)

    Crawford, T.V.

    2003-03-03

    The purpose of atmospheric transport and diffusion calculations is to provide estimates of concentration and surface deposition from routine and accidental releases of pollutants to the atmosphere. This paper discusses this topic.

  7. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.; Liu, D.K.

    1992-11-17

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  8. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  9. Non-hydrodynamic transport in trapped unitary Fermi gases

    E-Print Network [OSTI]

    Jasmine Brewer; Paul Romatschke

    2015-08-05

    Many strongly coupled fluids are known to share similar hydrodynamic transport properties. In this work we argue that this similarity could extend beyond hydrodynamics to transient dynamics through the presence of non-hydrodynamic modes. We review non-hydrodynamic modes in kinetic theory and gauge/gravity duality and discuss their signatures in trapped Fermi gases close to unitarity. Reanalyzing previously published experimental data, we find hints of non-hydrodynamic modes in cold Fermi gases in two and three dimensions.

  10. Non-hydrodynamic transport in trapped unitary Fermi gases

    E-Print Network [OSTI]

    Brewer, Jasmine

    2015-01-01

    Many strongly coupled fluids are known to share similar hydrodynamic transport properties. In this work we argue that this similarity could extend beyond hydrodynamics to transient dynamics through the presence of non-hydrodynamic modes. We review non-hydrodynamic modes in kinetic theory and gauge/gravity duality and discuss their signatures in trapped Fermi gases close to unitarity. Reanalyzing previously published experimental data, we find hints of non-hydrodynamic modes in cold Fermi gases in two and three dimensions.

  11. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2000-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  12. Atmospheric chemistry and global change

    E-Print Network [OSTI]

    Prather, MJ

    1999-01-01

    and particles. Thus Atmospheric Chemistry and Global Changethe future of atmospheric chemistry. BROWSINGS Tornadothe complexity of atmospheric chemistry well, but trips a

  13. Molecular dynamics of gases and vapors in nanoporous solids. Final LDRD project report

    SciTech Connect (OSTI)

    Pohl, P.I.

    1996-08-01

    This report provides a study of gases in microporous solids using molecular modeling. The theory of gas transport in porous materials as well as the molecular modeling literature is briefly reviewed. Work complete is described and analyzed with retard to the prevailing theory. The work covers two simple subjects, construction of porous solid models and diffusion of He, H{sub 2}, Ar and CH{sub 4} down a pressure gradient across the material models as in typical membrane permeation experiments. The broader objective is to enhance our capability to efficiently and accurately develop, produce and apply microporous materials.

  14. Fractionation of soil gases by diffusion of water vapor, gravitational settling, and thermal diffusion

    SciTech Connect (OSTI)

    Severinghaus, J.P.; Bender, M.L. [Univ. of Rhode Island, RI (United States)] [Univ. of Rhode Island, RI (United States); Keeling, R.F. [Scripps Institution of Oceanography, LaJolla, CA (United States)] [Scripps Institution of Oceanography, LaJolla, CA (United States); Broecker, W.S. [Lamont-Doherty Earth Observatory, Palisades, NY (United States)] [Lamont-Doherty Earth Observatory, Palisades, NY (United States)

    1996-03-01

    Air sampled from the moist unsaturated zone in a sand dune exhibits depletion in the heavy isotopes of N{sub 2} and O{sub 2}. We propose that the depletion is caused by a diffusive flux of water vapor out of the dune, which sweeps out the other gases, forcing them to diffuse back into the dune. The heavy isotopes of N{sub 2} and O{sub 2} diffuse back more slowly, resulting in a steady-state depletion of the heavy isotopesin the dune interior. We predict the effect`s magnitude with molecular diffusion theory and reproduce it in a laboratory simulation, finding good agreement between field, theory, and lab. The magnitude of the effect is governed by the ratio of the binary diffusivities against water vapor of a pair of gases, and increases {approximately} linearly with the difference between the water vapor mole fraction of the site and the advectively mixed reservoir with which it is in diffusive contact (in most cases the atmosphere). 32 refs., 1 fig., 3 tabs.

  15. Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

    E-Print Network [OSTI]

    Dennis, J A

    1971-01-01

    Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

  16. PHOTOCHEMISTRY IN TERRESTRIAL EXOPLANET ATMOSPHERES. I. PHOTOCHEMISTRY MODEL AND BENCHMARK CASES

    SciTech Connect (OSTI)

    Hu Renyu; Seager, Sara; Bains, William

    2012-12-20

    We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial planet atmospheres, ranging from oxidizing through reducing, which makes the code suitable for applications for the wide range of anticipated terrestrial exoplanet compositions. The one-dimensional chemical transport model treats up to 800 chemical reactions, photochemical processes, dry and wet deposition, surface emission, and thermal escape of O, H, C, N, and S bearing species, as well as formation and deposition of elemental sulfur and sulfuric acid aerosols. We validate the model by computing the atmospheric composition of current Earth and Mars and find agreement with observations of major trace gases in Earth's and Mars' atmospheres. We simulate several plausible atmospheric scenarios of terrestrial exoplanets and choose three benchmark cases for atmospheres from reducing to oxidizing. The most interesting finding is that atomic hydrogen is always a more abundant reactive radical than the hydroxyl radical in anoxic atmospheres. Whether atomic hydrogen is the most important removal path for a molecule of interest also depends on the relevant reaction rates. We also find that volcanic carbon compounds (i.e., CH{sub 4} and CO{sub 2}) are chemically long-lived and tend to be well mixed in both reducing and oxidizing atmospheres, and their dry deposition velocities to the surface control the atmospheric oxidation states. Furthermore, we revisit whether photochemically produced oxygen can cause false positives for detecting oxygenic photosynthesis, and find that in 1 bar CO{sub 2}-rich atmospheres oxygen and ozone may build up to levels that have conventionally been accepted as signatures of life, if there is no surface emission of reducing gases. The atmospheric scenarios presented in this paper can serve as the benchmark atmospheres for quickly assessing the lifetime of trace gases in reducing, weakly oxidizing, and highly oxidizing atmospheres on terrestrial exoplanets for the exploration of possible biosignature gases.

  17. Impact of rising greenhouse gases on mid-latitude storm tracks and associated hydroclimate variability and change

    SciTech Connect (OSTI)

    Seager, Richard

    2014-12-08

    Project Summary This project aimed to advance physical understanding of how and why the mid-latitude jet streams and storm tracks shift in intensity and latitude in response to changes in radiative forcing with an especial focus on rising greenhouse gases. The motivation, and much of the work, stemmed from the importance that these mean and transient atmospheric circulation systems have for hydroclimate. In particular drying and expansion of the subtropical dry zones has been related to a poleward shift of the mid-latitude jets and storm tracks. The work involved integrated assessment of observation and model projections as well as targeted model simulations.

  18. Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases

    SciTech Connect (OSTI)

    Beavon, D.K.; Mackles, M.

    1980-11-11

    Liquified hydrocarbon gases containing at least carbonyl sulfide as an impurity are purified by intimately mixing the liquified hydrocarbon gas with an aqueous absorbent for hydrogen sulfide in a hydrolysis zone maintained at a temperature and a pressure sufficient to maintain the liquified hydrocarbon gas in the liquid state and hydrolyze the carbonyl sulfide to hydrogen sulfide and carbon dioxide. The liquified hydrocarbon gas containing at least a portion of the formed carbonyl sulfide and carbon dioxide is separated from the liquid absorbent and passed to an absorption zone where it is contacted with a liquid hydrogen sulfide absorbent where at least the formed hydrogen sulfide is separated from the liquified petroleum gas. A stage of absorption of at least hydrogen sulfide may proceed mixing of the liquified hydrocarbon gas with the absorbent in the hydrolysis reaction zone. The absorbent employed does not combine irreversibly with carbonyl sulfide, hydrogen sulfide, and carbon dioxide, and preferably is an aqueous solution of diethanolamine.

  19. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  20. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Markun, Francis (Joliet, IL); Zawadzki, Mary T. (South Bend, IN)

    1998-01-01

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  1. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  2. June 1998 GPS WORLD 33 Global warming and greenhouse gases are

    E-Print Network [OSTI]

    Businger, Steven

    by an interna- tional sense of urgency to comprehend the effect of human activity on the earth's cli- mate and solar and terrestrial radiation. The availability of affordable GPS receivers has enabled us to develop balloon (see Figure 1) in atmospheric chemistry field experiments at different sites around the globe

  3. A comparison of hydrocarbon gases from springs and seeps of varied geologic provinces of the northwestern US

    SciTech Connect (OSTI)

    Lorenson, T.D.; Kvenvolden, K.A. (Geological Survey, Menlo Park, CA (United States))

    1993-04-01

    The northwestern US hosts a remarkable quantity and variety of thermal springs and seeps. Although many studies have dealt with the liquids and non-hydrocarbon gases emanating from these sources, few have focused on hydrocarbon gases. methane in particular is now recognized as an important reactive trace gas in the earth's atmosphere. To understand better the magnitude and occurrence of natural sources of hydrocarbons to the atmosphere, the authors have begun a survey of these gases throughout the northwestern US. This area encompasses a number of different tectonic regimes: the Yellowstone Hot Spot, the northern Basin and Range province, the Cascade volcanic arc, and the Cascadia subduction complex. Methane is present in each area at concentration levels ranging from about 2 ppmv (parts per million by volume) to 99.9% (by volume). Hydrothermal activity in the Yellowstone area produces spring gases containing less than 4% methane, with CO[sub 2] as the balance gas. The Teton area has a wide variety of gas compositions with either methane, carbon dioxide, or nitrogen as the primary gas component. In the northern Great Basin, thermal springs and seeps typically occur along fault zones at the base of mountain ranges. Methane concentrations range from 0.2 to 47%, with HMW HC concentrations from 0 to 3,100 ppmv. Areas covered by the Cenozoic Columbia River basalts and the basalts of the Snake River Plain continue to have high heat flow and produce thermal springs and seeps, usually along fault zones. Gases from the southern Cascade volcanic arc (Mt. Shasta and Mt. Lassen) are composed typically of carbon dioxide, with minor amounts of methane (less than 0.2%); however some fumaroles at Mt. Lassen have minor quantities of HMW HC. Along the Pacific coast, melanges of the Cascadia subduction complex host many seeps and springs. In some seeps the gas consists almost exclusively of methane (94.3 to 99.9%) with amounts of HMW HC ranging from about 5 ppmv to 3.5%.

  4. Atmospheric Neutrino Fluxes

    E-Print Network [OSTI]

    Thomas K. Gaisser

    2005-02-18

    Starting with an historical review, I summarize the status of calculations of the flux of atmospheric neutrinos and how they compare to measurements.

  5. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    1998-10-01

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  6. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

    2012-04-17

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  7. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  8. Conserving Energy by Recovering Heat from Hot Waste Gases

    E-Print Network [OSTI]

    Magnuson, E. E.

    1979-01-01

    ;::;,. """"= ;e - -e-- - ~ ------- ., ~ A~ PULL THRU - WITH SUPPLEMENTARY BURNER t t - ~"~ ~ - t77 7'0.. Fig. No. B ;i' ~ A+-, j + ~ ~s:- i.I A..-J PUSH THRU OR PULL THRU - W ITII SUPPI F'MF'NTARY ALJRNER years later a steel company discharging... BY RECOVERING HEAT FROM HOT WASTE GASES E. E. Magnuson Consultant and Training Director Eclipse Lookout Co. - Division of Eclipse, Inc. Chattanooga, Tennessee Intent of this paper is to show how recovery of heat in hot waste gases reduces nation...

  9. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  10. Oceanography and Atmospheric Sciences

    E-Print Network [OSTI]

    Kurapov, Alexander

    Oceanography and Atmospheric Sciences 19592009 WayneBurt. #12;Oceanography and Atmospheric in Oceanography (TENOC). Wayne Burt immediately responds with proposal to President Strand of Oregon State College to start a graduate Department of Oceanography. 1959 Oregon State Board of Higher Education approves

  11. Can we learn something more on oscillations from atmospheric neutrinos?

    E-Print Network [OSTI]

    Thomas Schwetz

    2006-10-04

    We show that for long-baseline experiments using a Mt water Cerenkov detector atmospheric neutrino data provide a powerful method to resolve parameter degeneracies. In particular, the combination of long-baseline and atmospheric data increases significantly the sensitivity to the neutrino mass hierarchy and the octant of $\\theta_{23}$. Furthermore, we discuss the possibility to use $\\mu$-like atmospheric neutrino data from a big magnetized iron calorimeter to determine the neutrino mass hierarchy.

  12. Hydrothermal venting of greenhouse gases triggering Early Jurassic global warming

    E-Print Network [OSTI]

    Svensen, Henrik

    Hydrothermal venting of greenhouse gases triggering Early Jurassic global warming Henrik Svensen a carbon cycle. The event lasted for approximately 200,000 years and was manifested by a global warming, and the Toarcian global warming. 2007 Elsevier B.V. All rights reserved. Keywords: climate change; Toarcian

  13. Use of low temperature blowers for recirculation of hot gases

    DOE Patents [OSTI]

    Maru, H.C.; Forooque, M.

    1982-08-19

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  14. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  15. Lieb-Thirring Bounds for Interacting Bose Gases

    E-Print Network [OSTI]

    Douglas Lundholm; Fabian Portmann; Jan Philip Solovej

    2015-02-02

    We study interacting Bose gases and prove lower bounds for the kinetic plus interaction energy of a many-body wave function in terms of its particle density. These general estimates are then applied to various types of interactions, including hard sphere (in 3D) and hard disk (in 2D) as well as a general class of homogeneous potentials.

  16. Thermodynamic and hydrodynamic behaviour of interacting Fermi gases

    E-Print Network [OSTI]

    Goulko, Olga

    2012-01-10

    Fermionic matter is ubiquitous in nature, from the electrons in metals and semiconductors or the neutrons in the inner crust of neutron stars, to gases of fermionic atoms, like 40K or 6Li that can be created and studied under laboratory conditions...

  17. OPTIONS FOR ABATING GREENHOUSE GASES FROM EXHAUST STREAMS.

    SciTech Connect (OSTI)

    FTHENAKIS,V.

    2001-12-01

    This report examines different alternatives for replacing, treating, and recycling greenhouse gases. It is concluded that treatment (abatement) is the only viable short-term option. Three options for abatement that were tested for use in semiconductor facilities are reviewed, and their performance and costs compared. This study shows that effective abatement options are available to the photovoltaic (PV) industry, at reasonable cost.

  18. HTheorems in some kinetic models of chemically reacting dense gases

    E-Print Network [OSTI]

    Polewczak, Jacek

    gases: -- search for the RET (Revised Enskog Theory) analog's of the reacting hardsphere system -- H as perturbations to the nonreactive terms. This was confirmed in a series of papers by B.Shizgal and M.Karplus (J by an equilibrium computations, where solvent e#ects enter through the free energy at the transition state. (for

  19. Ensemble Atmospheric Dispersion Modeling

    SciTech Connect (OSTI)

    Addis, R.P.

    2002-06-24

    Prognostic atmospheric dispersion models are used to generate consequence assessments, which assist decision-makers in the event of a release from a nuclear facility. Differences in the forecast wind fields generated by various meteorological agencies, differences in the transport and diffusion models, as well as differences in the way these models treat the release source term, result in differences in the resulting plumes. Even dispersion models using the same wind fields may produce substantially different plumes. This talk will address how ensemble techniques may be used to enable atmospheric modelers to provide decision-makers with a more realistic understanding of how both the atmosphere and the models behave.

  20. Fluctuations of the number of particles within a given volume in cold quantum gases

    SciTech Connect (OSTI)

    Astrakharchik, G. E.; Combescot, R.; Pitaevskii, L. P.

    2007-12-15

    In ultracold gases many experiments use atom imaging as a basic observable. The resulting image is averaged over a number of realizations and mostly only this average is used. Only recently the noise has been measured to extract physical information. In the present paper we investigate the quantum noise arising in these gases at zero temperature. We restrict ourselves to the homogeneous situation and study the fluctuations in particle number found within a given volume in the gas, and more specifically inside a sphere of radius R. We show that zero-temperature fluctuations are not extensive and the leading term scales with sphere radius R as R{sup 2} ln R (or ln R) in three- (or one-) dimensional systems. We calculate systematically the next term beyond this leading order. We consider first the generic case of a compressible superfluid. Then we investigate the whole Bose-Einstein-condensation (BEC) -BCS crossover, and in particular the limiting cases of the weakly interacting Bose gas and of the free Fermi gas.

  1. Polaronic atom-trimer continuity in three-component Fermi gases

    E-Print Network [OSTI]

    Nishida, Yusuke

    2014-01-01

    Recently it has been proposed that three-component Fermi gases may exhibit a new type of crossover physics in which an unpaired Fermi sea of atoms smoothly evolves into that of trimers in addition to the ordinary BCS-BEC crossover of condensed pairs. Here we study its corresponding polaron problem in which a single impurity atom of one component interacts with condensed pairs of the other two components with equal populations. By developing a variational approach in the vicinity of a narrow Feshbach resonance, we show that the impurity atom smoothly changes its character from atom to trimer with increasing the attraction and eventually there is a sharp transition to dimer. The emergent polaronic atom-trimer continuity can be probed in ultracold atoms experiments with the inverse radio-frequency spectroscopy. Our novel crossover wave function properly incorporating the polaronic atom-trimer continuity will provide a useful basis to further investigate the phase diagram of three-component Fermi gases in more ge...

  2. Toxicity of atmospheric aerosols on marine phytoplankton

    E-Print Network [OSTI]

    2009-01-01

    address: Center for Atmospheric Chemistry Study, Departmenttween phytoplankton, atmospheric chemistry, and climate areno. 12 ? 4601 4605 CHEMISTRY Atmospheric aerosol deposition

  3. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

    1988-01-01

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

  4. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, R.L.; Cannon, T.W.

    1988-10-25

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

  5. Autumn 2014 Atmospheric Circulation

    E-Print Network [OSTI]

    Doty, Sharon Lafferty

    to perform atmospheric chemistry measurements in this remote region of ubiquitous oil and gas drilling 30 days they raised $12,000, enough to support Maria's travel to Utah and to cover the costs

  6. Uniqueness of chemical equilibria in ideal mixtures of ideal gases Joseph M. Powersa

    E-Print Network [OSTI]

    forces between mol- ecules of the same type. Ideal mixtures, which include gases which obey Dalton's law

  7. System for trapping and storing gases for subsequent chemical reduction to solids

    DOE Patents [OSTI]

    Vogel, John S. (San Jose, CA); Ognibene, Ted J. (Oakland, CA); Bench, Graham S. (Livermore, CA); Peaslee, Graham F. (Holland, MI)

    2009-11-03

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  8. Institute for Climate & Atmospheric Science Department of Earth & Atmospheric Sciences

    E-Print Network [OSTI]

    Azevedo, Ricardo

    platforms to study numerous trace gases including carbon dioxide. We operate a suite of remote sensing is elucidating the carbon cycle through the satellite data (e.g., AIRS, TES, GOSAT, and OCO2

  9. Analise Matematica III Turma Especial Ficha Extra 3 Termodinamica dos Gases Ideais

    E-Print Network [OSTI]

    Natário, José

    An??alise Matem??atica III ­ Turma Especial Ficha Extra 3 ­ Termodin??amica dos Gases Ideais N estado dos gases ideais: PV = NRT (onde R ??e a constante dos gases ideais). A Primeira Lei da Termodin??amica pela Segunda Lei da Termodin??amica. 2 #12;

  10. New model more accurately tracks gases for underground nuclear...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    knowledge about atmospheric conditions (e.g., the barometric pressure that creates a vacuum) and seasonal variabilities in different regions. This team's research investigated...

  11. Advanced Gas Reactor (AGR)-5/6/7 Fuel Irradiation Experiments in the Advanced Test Reactor

    SciTech Connect (OSTI)

    A. Joseph Palmer; David A. Petti; S. Blaine Grover

    2014-04-01

    The United States Department of Energys Very High Temperature Reactor (VHTR) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which each consist of at least five separate capsules, are being irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gases also have on-line fission product monitoring the effluent from each capsule to track performance of the fuel during irradiation. The first two experiments (designated AGR-1 and AGR-2), have been completed. The third and fourth experiments have been combined into a single experiment designated AGR-3/4, which started its irradiation in December 2011 and is currently scheduled to be completed in April 2014. The design of the fuel qualification experiment, designated AGR-5/6/7, is well underway and incorporates lessons learned from the three previous experiments. Various design issues will be discussed with particular details related to selection of thermometry.

  12. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, Michael (Los Alamos, NM)

    1995-01-01

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  13. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, M.

    1995-02-07

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  14. Frequency-dependent fluctuation-dissipation relations in granular gases

    E-Print Network [OSTI]

    Guy Bunin; Yair Shokef; Dov Levine

    2008-05-19

    The Green-Kubo relation for two models of granular gases is discussed. In the Maxwell model in any dimension, the effective temperature obtained from the Green-Kubo relation is shown to be frequency independent, and equal to the average kinetic energy, known as the granular temperature. In the second model analyzed, a mean-field granular gas, the collision rate of a particle is taken to be proportional to its velocity. The Green-Kubo relation in the high frequency limit is calculated for this model, and the effective temperature in this limit is shown to be equal to the granular temperature. This result, taken together with previous results, showing a difference between the effective temperature at zero frequency (the Einstein relation) and the granular temperature, shows that the Green-Kubo relation for granular gases is violated.

  15. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

    1997-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  16. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  17. Wave Speed in the Macroscopic Extended Model for Ultrarelativistic Gases

    E-Print Network [OSTI]

    F. Borghero; F. Demontis; S. Pennisi

    2010-12-07

    An exact macroscopic extended model for ultrarelativistic gases, with an arbitrary number of moments, is present in the literature. Here we exploit equations determining wave speeds for that model. We find interesting results; for example, the whole system for their determination can be divided into independent subsystems and some, but not all, wave speeds are expressed by rational numbers. Moreover, the extraordinary property that these wave speeds for the macroscopic model are the same of those in the kinetic model, is proved.

  18. Low-dimensional weakly interacting Bose gases: Nonuniversal equations of state

    SciTech Connect (OSTI)

    Astrakharchik, G. E.; Boronat, J.; Mazzanti, F.; Kurbakov, I. L.; Lozovik, Yu. E.

    2010-01-15

    The zero-temperature equation of state is analyzed in low-dimensional bosonic systems. We propose to use the concept of energy-dependent s-wave scattering length for obtaining estimations of nonuniversal terms in the energy expansion. We test this approach by making a comparison to exactly solvable one-dimensional problems and find that the generated terms have the correct structure. The applicability to two-dimensional systems is analyzed by comparing with results of Monte Carlo simulations. The prediction for the nonuniversal behavior is qualitatively correct and the densities, at which the deviations from the universal equation of state become visible, are estimated properly. Finally, the possibility of observing the nonuniversal terms in experiments with trapped gases is also discussed.

  19. Optical Signatures from Magnetic 2-D Electron Gases in High Magnetic Fields to 60 Tesla

    SciTech Connect (OSTI)

    Crooker, S.A.; Kikkawa, J.M.; Awschalom, D.D.; Smorchikova, I.P.; Samarth, N.

    1998-11-08

    We present experiments in the 60 Tesla Long-Pulse magnet at the Los Alamos National High Magnetic Field Lab (NHMFL) focusing on the high-field, low temperature photoluminescence (PL) from modulation-doped ZnSe/Zn(Cd,Mn)Se single quantum wells. High-speed charge-coupled array detectors and the long (2 second) duration of the magnet pulse permit continuous acquisition of optical spectra throughout a single magnet shot. High-field PL studies of the magnetic 2D electron gases at temperatures down to 350mK reveal clear intensity oscillations corresponding to integer quantum Hall filling factors, from which we determine the density of the electron gas. At very high magnetic fields, steps in the PL energy are observed which correspond to the partial unlocking of antiferromagnetically bound pairs of Mn2+ spins.

  20. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  1. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    1997-10-01

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  2. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  3. 13, 1479714822, 2013 Atmospheric waves

    E-Print Network [OSTI]

    Lovejoy, Shaun

    .5194/acpd-13-14797-2013 Author(s) 2013. CC Attribution 3.0 License. Sciences ss Atmospheric Chemistry and Physics OpenAccess Atmospheric Chemistry and Physics OpenAccess Discussions Atmospheric Measurement s Discussions This discussion paper is/has been under review for the journal Atmospheric Chemistry and Physics

  4. The middle Martian atmosphere

    SciTech Connect (OSTI)

    Jaquin, R.F.

    1989-01-01

    Profiles of scattered light above the planetary limb from 116 Viking Orbiter images are used to constrain the temporal and spatial behavior of aerosols suspended in the Martian atmosphere. The data cover a wide range of seasons, locations, and viewing geometry, providing information about the aerosol optical properties and vertical distribution. The typical atmospheric column contains one or more discrete, optically thin, ice-like haze layers between 30 and 90 km elevation whose composition is inferred to be water ice. Below the detached hazes, a continuous haze, interpreted to have a large dust component, extends from as much as 50 km to the surface. The haze distribution exhibits an annual variation that reflects a seasonally driven circulation in the middle atmosphere. The potential role of stationary gravity waves in modifying the middle atmosphere circulation is explored using a linear theory applied to a realistic Martian environment. Martian topography derived from radar observations is decomposed into Fourier harmonics and used to linearly superpose gravity waves arising from each component. The larger amplitude topography on Mars combined with the absence of extended regions of smooth topography like oceans generates larger wave amplitudes than on the Earth. The circulation of the middle atmosphere is examined using a two-dimensional, linearized, axisymmetric model successfully employed in the study of the terrestrial mesosphere. Illustrations of temperature and wind speeds are presented for the southern summer solstice and southern spring equinox.

  5. Atmospheric-pressure plasma decontamination/sterilization chamber

    DOE Patents [OSTI]

    Herrmann, Hans W. (Los Alamos, NM); Selwyn, Gary S. (Los Alamos, NM)

    2001-01-01

    An atmospheric-pressure plasma decontamination/sterilization chamber is described. The apparatus is useful for decontaminating sensitive equipment and materials, such as electronics, optics and national treasures, which have been contaminated with chemical and/or biological warfare agents, such as anthrax, mustard blistering agent, VX nerve gas, and the like. There is currently no acceptable procedure for decontaminating such equipment. The apparatus may also be used for sterilization in the medical and food industries. Items to be decontaminated or sterilized are supported inside the chamber. Reactive gases containing atomic and metastable oxygen species are generated by an atmospheric-pressure plasma discharge in a He/O.sub.2 mixture and directed into the region of these items resulting in chemical reaction between the reactive species and organic substances. This reaction typically kills and/or neutralizes the contamination without damaging most equipment and materials. The plasma gases are recirculated through a closed-loop system to minimize the loss of helium and the possibility of escape of aerosolized harmful substances.

  6. Etching process of silicon dioxide with nonequilibrium atmospheric pressure plasma

    SciTech Connect (OSTI)

    Yamakawa, Koji; Hori, Masaru; Goto, Toshio; Den, Shoji; Katagiri, Toshirou; Kano, Hiroyuki [Department of Quantum Engineering, Nagoya University, Furo-Cho, Chikusa-ku, Nagoya 464-8603 (Japan); Department of Electrical Engineering and Computer Science, Nagoya University, Furo-Cho, Chikusa-ku, Nagoya 464-8603 (Japan); Department of Quantum Engineering, Nagoya University, Furo-Cho, Chikusa-ku, Nagoya 464-8603 (Japan); Department of Engineering, Katagiri Engineering Co., Ltd., Minamikase Saiwai-ku, Kawasaki 661-8661 (Japan); NU-EcoEngineering Co., Ltd., Ooaza, Kurozasa Aza, Umazutsumi, Miyoshi-cho, Nishikamo-gun, Aichi 470-0201 (Japan)

    2005-07-01

    An ultrahigh etch rate (14 {mu}m/min) of SiO{sub 2} and a high selectivity of SiO{sub 2}/Si over 200 were achieved using a microwave-excited nonequilibrium atmospheric pressure plasma source employing He, NF{sub 3}, and H{sub 2}O gases, which have been developed for application to microelectromechanical systems and other bionanotechnology fields. In order to clarify the etching mechanism, two diagnostic methods have been performed: (1) imaging of plasma emission with an intensified charge-coupled device camera, and (2) absorption measurements using Fourier transform infrared spectroscopy. The etching characteristics are discussed in relation to the spatial distributions of the species involved. The etch rate depended considerably on the distance between the plasma and the substrate. Some radicals generated from the feed gases reached the substrate directly, while other radicals recombined into different species, which reached the substrate. An abundance of HF molecules were produced through a reaction between radicals generated by the atmospheric pressure discharge of NF{sub 3} and H{sub 2}O. From these measurements, it has been found that the HF molecules generated played a role in producing the high etch rate of SiO{sub 2} and high etch selectivity of SiO{sub 2}/Si.

  7. Observations of Exoplanet Atmospheres

    E-Print Network [OSTI]

    Crossfield, Ian J M

    2015-01-01

    Detailed characterization of an extrasolar planet's atmosphere provides the best hope for distinguishing the makeup of its outer layers, and the only hope for understanding the interplay between initial composition, chemistry, dynamics & circulation, and disequilibrium processes. In recent years, some areas have seen rapid progress while developments in others have come more slowly and/or have been hotly contested. This article gives an observer's perspective on the current understanding of extrasolar planet atmospheres prior to the considerable advances expected from the next generation of observing facilities. Atmospheric processes of both transiting and directly-imaged planets are discussed, including molecular and atomic abundances, cloud properties, thermal structure, and planetary energy budgets. In the future we can expect a continuing and accelerating stream of new discoveries, which will fuel the ongoing exoplanet revolution for many years to come.

  8. Overview of the United States Department of Energy's ARM (Atmospheric Radiation Measurement) Program

    SciTech Connect (OSTI)

    Stokes, G.M. ); Tichler, J.L. )

    1990-06-01

    The Department of Energy (DOE) is initiating a major atmospheric research effort, the Atmospheric Radiation Measurement Program (ARM). The program is a key component of DOE's research strategy to address global climate change and is a direct continuation of DOE's decade-long effort to improve the ability of General Circulation Models (GCMs) to provide reliable simulations of regional, and long-term climate change in response to increasing greenhouse gases. The effort is multi-disciplinary and multi-agency, involving universities, private research organizations and more than a dozen government laboratories. The objective of the ARM Research is to provide an experimental testbed for the study of important atmospheric effects, particularly cloud and radiative processes, and to test parameterizations of these processes for use in atmospheric models. This effort will support the continued and rapid improvement of GCM predictive capability. 2 refs.

  9. Thermodynamic analysis and experimental study of the effect of atmospheric pressure on the ice point

    SciTech Connect (OSTI)

    Harvey, A. H. [Thermophysical Properties Division National Institute of Standards and Technology, Boulder, Colorado (United States)] [Thermophysical Properties Division National Institute of Standards and Technology, Boulder, Colorado (United States); McLinden, M. O. [Thermophysical Properties Division, National Institute of Standards and Technology, Boulder, Colorado (United States)] [Thermophysical Properties Division, National Institute of Standards and Technology, Boulder, Colorado (United States); Tew, W. L. [Sensor Science Division National Institute of Standards and Technology, Gaithersburg, Maryland (United States)] [Sensor Science Division National Institute of Standards and Technology, Gaithersburg, Maryland (United States)

    2013-09-11

    We present a detailed thermodynamic analysis of the temperature of the ice point as a function of atmospheric pressure. This analysis makes use of accurate international standards for the properties of water and ice, and of available high-accuracy data for the Henry's constants of atmospheric gases in liquid water. The result is an ice point of 273.150 019(5) K at standard atmospheric pressure, with higher ice-point temperatures (varying nearly linearly with pressure) at lower pressures. The effect of varying ambient CO{sub 2} concentration is analyzed and found to be significant in comparison to other uncertainties in the model. The thermodynamic analysis is compared with experimental measurements of the temperature difference between the ice point and the triple point of water performed at elevations ranging from 145 m to 4302 m, with atmospheric pressures from 101 kPa to 60 kPa.

  10. Atmospheric Neutrino Oscillations for Earth Tomography

    E-Print Network [OSTI]

    Winter, Walter

    2015-01-01

    Modern proposed atmospheric neutrino oscillation experiments, such as PINGU in the Antarctic ice or or ORCA in Mediterranean sea water, aim for precision measurements of the oscillation parameters including the ordering of the neutrino masses. They can, however, go far beyond that: Since neutrino oscillations are affected by the coherent forward scattering with matter, neutrinos can provide a new view on the interior of the earth. We show that the proposed atmospheric oscillation experiments can robustly measure the lower mantle density of the earth with a precision at the level of 4-5 percent, including the uncertainties of the oscillation parameters and correlations among different density layers. While the earth's core is, in principle, accessible by the angular resolution, new technology would be required to extract degeneracy-free information.

  11. Atmospheric Radiation Measurement Climate Research Facility (ACRF) Annual Report 2008

    SciTech Connect (OSTI)

    LR Roeder

    2008-12-01

    The Importance of Clouds and Radiation for Climate Change: The Earths surface temperature is determined by the balance between incoming solar radiation and thermal (or infrared) radiation emitted by the Earth back to space. Changes in atmospheric composition, including greenhouse gases, clouds, and aerosols, can alter this balance and produce significant climate change. Global climate models (GCMs) are the primary tool for quantifying future climate change; however, there remain significant uncertainties in the GCM treatment of clouds, aerosol, and their effects on the Earths energy balance. In 1989, the U.S. Department of Energy (DOE) Office of Science created the Atmospheric Radiation Measurement (ARM) Program to address scientific uncertainties related to global climate change, with a specific focus on the crucial role of clouds and their influence on the transfer of radiation in the atmosphere. To reduce these scientific uncertainties, the ARM Program uses a unique twopronged approach: The ARM Climate Research Facility, a scientific user facility for obtaining long-term measurements of radiative fluxes, cloud and aerosol properties, and related atmospheric characteristics in diverse climate regimes; and The ARM Science Program, focused on the analysis of ACRF and other data to address climate science issues associated with clouds, aerosols, and radiation, and to improve GCMs. This report provides an overview of each of these components and a sample of achievements for each in fiscal year (FY) 2008.

  12. Autumn 2012 Atmospheric Circulation

    E-Print Network [OSTI]

    Doty, Sharon Lafferty

    wind, and accumulated precipitation at a designated city. Forecasts are made over a two-week period Department 1 The UW Atmospheric Sciences spring forecast contest has been an annual tradition there will be a marine push or a convergence zone wrecking their forecast for maximum temperature and precipitation

  13. Laboratory for Atmospheric and

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    Laboratory for Atmospheric and Space Physics Activity Report 2013 University of Colorado at Boulder from the Naval Research Center and the Air Force Cambridge Research Laboratory (now the Phillips Laboratory), the University of Colorado formed a research group called the Upper Air Laboratory (UAL

  14. Laboratory for Atmospheric and

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    Laboratory for Atmospheric and Space Physics Activity Report 2012 University of Colorado at Boulder from the Naval Research Center and the Air Force Cambridge Research Laboratory (now the Phillips Laboratory), the University of Colorado formed a research group called the Upper Air Laboratory (UAL

  15. Laboratory for Atmospheric and

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    Laboratory for Atmospheric and Space Physics Activity Report 2008 University of Colorado at Boulder, Jet Propulsion Laboratory) LASP: A Brief History In 1946-47, a handful of American universities joined Laboratory (now the Phillips Laboratory), the University of Colorado formed a research group called the Upper

  16. Laboratory for Atmospheric and

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    1 Laboratory for Atmospheric and Space Physics Activity Report 2010 University of Colorado from the Na- val Research Center and the Air Force Cambridge Research Laboratory (now the Phillips Laboratory), the University of Colorado formed a research group called the Upper Air Laboratory (UAL

  17. On the Sensitivity of L/E Analysis of Super-Kamiokande Atmospheric Neutrino Data to Neutrino Oscillation Part~2 --- Four Possible L/E Analyses for the Maximum Oscillation by the Numerical Computer Experiment ---

    E-Print Network [OSTI]

    E. Konishi; Y. Minorikawa; V. I. Galkin; M. Ishiwata; I. Nakamura; N. Takahashi; M. Kato; A. Misaki

    2010-07-28

    In the previous paper (Part~1), we have verified that the SK assumption on the direction does not hold in the analysis of neutrino events occurred inside the SK detector. We have made four possible L/E analyses, L_nu/E_nu, L_nu/E_mu, L_mu/E_nu and L_mu/E_mu. Among four kinds of L/E analyses, we have shown that only L_nu/E_nu analysis can give the signature of maximum oscillations clearly, while the L_mu/E_mu analysis which are really done by Super-Kamiokande Collaboration cannot give the maximum oscillation at all. It is thus concluded that Super-Kamiokande type experiment cannot find the maximum oscillation from L/E analysis. Therefore, we would suggest Super-Kamiokande Collaboration to re-analyze the zenith angle distribution of the neutrino events which occur inside the detector carefully.

  18. Nonperturbative Predictions for Cold Atom Bose Gases with Tunable Interactions

    SciTech Connect (OSTI)

    Cooper, Fred; Chien, Chih-Chun; Mihaila, Bogdan; Timmermans, Eddy; Dawson, John F.

    2010-12-10

    We derive a theoretical description for dilute Bose gases as a loop expansion in terms of composite-field propagators by rewriting the Lagrangian in terms of auxiliary fields related to the normal and anomalous densities. We demonstrate that already in leading order this nonperturbative approach describes a large interval of coupling-constant values, satisfies Goldstone's theorem, yields a Bose-Einstein transition that is second order, and is consistent with the critical temperature predicted in the weak-coupling limit by the next-to-leading-order large-N expansion.

  19. An Effective Method of Accelerating Bose Gases Using Magnetic Coils

    E-Print Network [OSTI]

    Lu, Haichang; Zhai, Yueyang; Pan, Ruizhi; Yang, Shifeng

    2014-07-23

    are settled around an ultra-vacuum glass container on a cop- per supporter that can be cooled by water. To prevent the eddy current in the copper frame when being ener- gized, some crucial parts in the holder are fabricated with gaps. The potential energy... the relationship of different current supply and delay time versus the ultimate velocity of the atom,we theoretically predict the method of accelerating the gases to an expected velocity. This method is of great convenience and significance for the applications...

  20. Liquefaction and storage of thermal treatment off-gases

    SciTech Connect (OSTI)

    Stull, D.M. . Rocky Flats Plant); Golden, J.O. )

    1992-09-08

    A fluidized bed catalytic oxidation unit is being developed for use in the destruction of mixed waste at the Rocky Flats Plant. Cyclones, filters, in situ neutralization of acid gases, and a catalytic converter are used to meet emission standards. Because there is concern by the public that these measures may not be adequate, two off-gas capture systems were evaluated. Both systems involve liquefaction of carbon dioxide produced in the oxidation process. The carbon dioxide would be released only after analysis proved that all appropriate emission standards are met.

  1. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, Raymond J. (Mt. Prospect, IL); Kurek, Paul R. (Schaumburg, IL)

    1988-01-01

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  2. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  3. Two-phase compressibility factors for retrograde gases

    E-Print Network [OSTI]

    Rayes, Daniel George

    1989-01-01

    . K. , M Cain, W. D. , Jr. and Jennings, J. W. : "An Improved Method for the Determination of the Reservoir Specific Gravity for Retrograde Gases, " JPT (July 1989) 747-752. 7. Craft, B. C. and Hawkins, M. F. : A li P 1 m R rv ir En ine rin...). Variable Mean Standard Deviation Minimum Maximum H2S CO2 N2 CI C2 C3 IC4 NC4 IC5 NC5 C6 C7+ M. W. C7+ S. G. C7+ 1, 01840 0. 00997 0. 02545 0. 01840 0. 73233 0. 07584 0. 03948 0. 00859 0. 01482 0. 00611 0. 00637 0. 00857 0. 05404...

  4. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  5. Hazardous Gases VASILIS M. FTHENAKIS Department of Applied Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-DoseOptions for Accidental Releases of Hazardous Gases

  6. EIA-Voluntary Reporting of Greenhouse Gases Program

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural GasNatural GasEIA lowers forecastof Greenhouse Gases Program

  7. JOURNAL OF GEOPHYSICAL RESEARCH: ATMOSPHERES, VOL. 118, 112, doi:10.1002/jgrd.50505, 2013 SO2 as a possible proxy for volcanic ash in aviation hazard avoidance

    E-Print Network [OSTI]

    Oxford, University of

    gases such as water vapor, carbon dioxide, and sulphur dioxide into the atmosphere [Robock, 2000 accurately using satellite data, while sulphur dioxide is much easier to detect accurately, but is much less]. These eruptions can occur in remote locations which are not the focus of regular measurements, and the first

  8. A Community Atmosphere Model with Superparameterized Clouds

    SciTech Connect (OSTI)

    Randall, David; Branson, Mark; Wang, Minghuai; Ghan, Steven J.; Craig, Cheryl; Gettelman, A.; Edwards, Jim

    2013-06-18

    In 1999, National Center for Atmospheric Research (NCAR) scientists Wojciech Grabowski and Piotr Smolarkiewicz created a "multiscale" atmospheric model in which the physical processes associated with clouds were represented by running a simple high-resolution model within each grid column of a lowresolution global model. In idealized experiments, they found that the multiscale model produced promising simulations of organized tropical convection, which other models had struggled to produce. Inspired by their results, Colorado State University (CSU) scientists Marat Khairoutdinov and David Randall created a multiscale version of the Community Atmosphere Model (CAM). They removed the cloud parameterizations of the CAM, and replaced them with Khairoutdinov's high-resolution cloud model. They dubbed the embedded cloud model a "super-parameterization," and the modified CAM is now called the "SP-CAM." Over the next several years, many scientists, from many institutions, have explored the ability of the SP-CAM to simulate tropical weather systems, the day-night changes of precipitation, the Asian and African monsoons, and a number of other climate processes. Cristiana Stan of the Center for Ocean-Land-Atmosphere Interactions found that the SP-CAM gives improved results when coupled to an ocean model, and follow-on studies have explored the SP-CAM's utility when used as the atmospheric component of the Community Earth System Model. Much of this research has been performed under the auspices of the Center for Multiscale Modeling of Atmospheric Processes, a National Science Foundation (NSF) Science and Technology Center for which the lead institution is CSU.

  9. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J. (Berkeley, CA); Berman, Samuel M. (San Francisco, CA)

    1988-01-01

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  10. Differential atmospheric tritium sampler

    DOE Patents [OSTI]

    Griesbach, O.A.; Stencel, J.R.

    1987-10-02

    An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The moisture then passes through a combustion chamber where hydrogen gas in the form of H/sub 2/ or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

  11. Atmospheric contamination for CMB ground-based observations

    E-Print Network [OSTI]

    Errard, J; Akiba, Y; Arnold, K; Atlas, M; Baccigalupi, C; Barron, D; Boettger, D; Borrill, J; Chapman, S; Chinone, Y; Cukierman, A; Delabrouille, J; Dobbs, M; Ducout, A; Elleflot, T; Fabbian, G; Feng, C; Feeney, S; Gilbert, A; Goeckner-Wald, N; Halverson, N W; Hasegawa, M; Hattori, K; Hazumi, M; Hill, C; Holzapfel, W L; Hori, Y; Inoue, Y; Jaehnig, G C; Jaffe, A H; Jeong, O; Katayama, N; Kaufman, J; Keating, B; Kermish, Z; Keskitalo, R; Kisner, T; Jeune, M Le; Lee, A T; Leitch, E M; Leon, D; Linder, E; Matsuda, F; Matsumura, T; Miller, N J; Myers, M J; Navaroli, M; Nishino, H; Okamura, T; Paar, H; Peloton, J; Poletti, D; Puglisi, G; Rebeiz, G; Reichardt, C L; Richards, P L; Ross, C; Rotermund, K M; Schenck, D E; Sherwin, B D; Siritanasak, P; Smecher, G; Stebor, N; Steinbach, B; Stompor, R; Suzuki, A; Tajima, O; Takakura, S; Tikhomirov, A; Tomaru, T; Whitehorn, N; Wilson, B; Yadav, A; Zahn, O

    2015-01-01

    Atmosphere is one of the most important noise sources for ground-based Cosmic Microwave Background (CMB) experiments. By increasing optical loading on the detectors, it amplifies their effective noise, while its fluctuations introduce spatial and temporal correlations between detected signals. We present a physically motivated 3d-model of the atmosphere total intensity emission in the millimeter and sub-millimeter wavelengths. We derive an analytical estimate for the correlation between detectors time-ordered data as a function of the instrument and survey design, as well as several atmospheric parameters such as wind, relative humidity, temperature and turbulence characteristics. Using numerical computation, we examine the effect of each physical parameter on the correlations in the time series of a given experiment. We then use a parametric-likelihood approach to validate the modeling and estimate atmosphere parameters from the POLARBEAR-I project first season data set. We compare our results to previous st...

  12. Electron Stimulated Desorption of Condensed Gases on Cryogenic Surfaces

    E-Print Network [OSTI]

    Tratnik, H; Hilleret, Nol

    2005-01-01

    In ultra-high vacuum systems outgassing from vacuum chamber walls and desorption from surface adsorbates are usually the factors which in°uence pressure and residual gas composition. In particular in beam vacuum systems of accelerators like the LHC, where surfaces are exposed to intense synchro- tron radiation and bombardment by energetic ions and electrons, properties like the molecular desorption yield or secondary electron yield can strongly in°uence the performance of the accelerator. In high-energy particle accelerators operating at liquid helium temperature, cold surfaces are exposed to the bombardment of energetic photons, electrons and ions. The gases released by the subsequent desorption are re-condensed on the cold surfaces and can be re-desorbed by the impinging electrons and ions. The equilibrium coverage reached on the surfaces exposed to the impact of energetic particles depends on the desorption yield of the condensed gases and can a®ect the operation of the accelerator by modifying th...

  13. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    1996-10-01

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  14. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  15. Dark resonances for ground state transfer of molecular quantum gases

    E-Print Network [OSTI]

    Manfred J. Mark; Johann G. Danzl; Elmar Haller; Mattias Gustavsson; Nadia Bouloufa; Olivier Dulieu; Houssam Salami; Tom Bergeman; Helmut Ritsch; Russell Hart; Hanns-Christoph Ngerl

    2008-11-05

    One possible way to produce ultracold, high-phase-space-density quantum gases of molecules in the rovibronic ground state is given by molecule association from quantum-degenerate atomic gases on a Feshbach resonance and subsequent coherent optical multi-photon transfer into the rovibronic ground state. In ultracold samples of Cs_2 molecules, we observe two-photon dark resonances that connect the intermediate rovibrational level |v=73,J=2> with the rovibrational ground state |v=0,J=0> of the singlet $X^1\\Sigma_g^+$ ground state potential. For precise dark resonance spectroscopy we exploit the fact that it is possible to efficiently populate the level |v=73,J=2> by two-photon transfer from the dissociation threshold with the stimulated Raman adiabatic passage (STIRAP) technique. We find that at least one of the two-photon resonances is sufficiently strong to allow future implementation of coherent STIRAP transfer of a molecular quantum gas to the rovibrational ground state |v=0,J=0>.

  16. Atmospheric Chemistry Theodore S. Dibble

    E-Print Network [OSTI]

    Dibble, Theodore

    SYLLABUS FOR Atmospheric Chemistry FCH 511 Fall 2014 Theodore S. Dibble Professor of Chemistry 421 in Required Text Seinfeld, J. H. and Pandis, S. N. Atmospheric Chemistry and Physics: From Air Pollution nineteenth year at ESF, and my seventeenth year teaching FCH 511 (Atmospheric Chemistry). I have done a lot

  17. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  18. Atmospheric chemistry of an Antarctic volcanic plume

    E-Print Network [OSTI]

    2010-01-01

    L. , et al. (2010), Atmospheric chemistry results from theI. , et al. (2006), Atmospheric chemistry of a 33 34 hourvolcanic eruptions on atmospheric chemistry, Chem. Geol. ,

  19. Experience with Palladium Diffusers in Tritium Processing

    SciTech Connect (OSTI)

    Motyka, T.; Clark, E.A.; Dauchess, D.A.; Heung, L.K.; Rabum, R.L.

    1995-01-27

    Hydrogen isotopes are separated from other gases by permeation through palladium and palladium-silver alloy diffusers in the Tritium Facilities at the US Department of Energy Savannah River Site (SRS). Diffusers have provided effective service for almost forty years. This paper is an overview of the operational experience with the various diffuser types that have been employed at SRS. Alternative technologies being developed at SRS for purifying hydrogen isotopes are also discussed.

  20. Direct containment heating and aerosol generation during high-pressure-melt expulsion experiments

    SciTech Connect (OSTI)

    Tarbell, W.W.; Brockmann, J.E.; Washington, K.E.; Pilch, M.; Marx, K.D.

    1988-01-01

    Severe nuclear plant accidents can involve the degradation of the reactor core while the primary coolant system remains pressurized. Molten fuel reaching the lower head of the reactor pressure vessel (RPV) may attack and fail the instrument guide tube penetrations, allowing the tube to be expelled from the vessel. The resulting aperture allows the molten fuel to be ejected into the cavity, followed by the blowdown of the contents of the primary system (high-pressure-melt ejection). Entrainment of the core debris in the cavity by the blowdown gases may cause high-temperature fuel particles to be carried into the containment building. Energy exchange between the particles and the atmosphere may cause heating and pressurizing of the containment (direct containment heating (DCH)). The complex phenomena associated with direct containment heating accident sequences are not well understood. This work describes a series of four experiments that have been performed to study and quantify the processes involved. The data from the experiments are used to guide the development of computer models to describe the response of containments under accident conditions.

  1. Oceanic Trace Gases Numeric Data Packages from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Most data sets or packages, many with numerous data files, are free to download from CDIAC's ftp area. CDIAC lists the following numeric data packages under the broad heading of Oceanic Trace Gases: Carbon Dioxide, Hydrographic, and Chemical Data Obtained during the R/V Ronald H. Brown Repeat Hydrography Cruise in the Atlantic Ocean: CLIVAR CO2 Section A16S_2005 ( 01/11/05 - 022405) Determination of Carbon Dioxide, Hydrographic, and Chemical Parameters during the R/V Nathaniel B. Palmer Cruise in the Southern Indian Ocean (WOCE Section S04I, 050396 - 070496) Inorganic Carbon, Nutrient, and Oxygen Data from the R/V Ronald H. Brown Repeat Hydrography Cruise in the Atlantic Ocean: CLIVAR CO2 Section A16N_2003a (060403 081103) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Maurice Ewing Cruise in the Atlantic Ocean (WOCE Section A17, 010494 - 032194) Global Ocean Data Analysis Project GLODAP: Results and Data Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Knorr Cruises in the North Atlantic Ocean on WOCE Sections AR24 (1102 120596) and A24, A20, and A22 (053097 090397) Carbon Dioxide, Hydrographic and Chemical Data Obtained During the Nine R/V Knorr Cruises Comprising the Indian Ocean CO2 Survey (WOCE Sections I8SI9S, I9N, I8NI5E, I3, I5WI4, I7N, I1, I10, and I2; 120 194 012296) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Meteor Cruise 28/1 in the South Atlantic Ocean (WOCE Section A8, 032994 - 051294) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Knorr Cruise 138-3, -4, and -5 in the South Pacific Ocean (WOCE Sections P6E, P6C, and P6W, 050292 - 073092) Global Distribution of Total Inorganic Carbon and Total Alkalinity below the deepest winter mixed layer depths Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V John V. Vickers Cruise in the Pacific Ocean (WOCE Section P13, NOAA CGC92 Cruise, 080492 102192) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Hesperides Cruise in the Atlantic Ocean (WOCE Section A5, 071492 - 081592) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas G. Thompson Cruise in the Pacific Ocean (WOCE Section P10, 100593 111093) The International Intercomparison Exercise of Underway fCO2 Systems during the R/V Meteor Cruise 36/1 in the North Atlantic Ocean Carbon Dioxide, Hydrographic, and Chemical Data Obtained during the R/V Meteor Cruise 22/5 in the South Atlantic Ocean (WOCE Section A10, Dec. 1992-Jan, 1993) Carbon Dioxide, Hydrographic, and Chemical Data Obtained in the South Pacific Ocean (WOCE Sections P16A/P17A, P17E/P19S, and P19C, R/V Knorr , Oct. 1992-April 1993) Surface Water and Atmospheric Underway Carbon Data Obtained During the World Ocean Circulation Experiment Indian Ocean Survey Cruises (R/V Knorr, Dec. 1994 Jan, 1996) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Akademik Ioffe Cruise in the South Pacific Ocean (WOCE Section S4P, Feb.-April 1992) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas Washington Cruise TUNES-1 in the Equatorial Pacific Ocean (WOCE section P17C) Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas Washington Cruise TUNES-3 in the Equatorial Pacific Ocean (WOCE section P16C) Carbon-14 Measurements in Surface Water CO2 from the Atlantic, Indian and Pacific Oceans, 1965-1994 Carbon Dioxide, Hydrographic, and Chemical Data Obtained During R/V Meteor Cruise 18/1 in the North Atlantic Ocean (WOCE Section A1E) Carbon Dioxide, Hydrographic, and Chemical Data Obtained in the Central South Pacific Ocean (WOCE Sections P17S and P16S) during the TUNES-2 Expedition of the R/V Th

  2. TAPAS, a web-based service of atmospheric transmission computation for astronomy

    E-Print Network [OSTI]

    Bertaux, J L; Ferron, S; Boone, C; Bodichon, R

    2013-01-01

    Spectra of astronomical targets acquired from ground-based instruments are affected by the atmospheric transmission. The authors and their institutes are developing a web-based service, TAPAS (Transmissions of the AtmosPhere for AStromomical data). This service, freely available, is developed and maintained within the atmospheric ETHER data center. TAPAS computes the atmospheric transmission in the line-of-sight to the target indicated by the user. The user files a request indicating the time, ground location, and either the equatorial coordinates of the target or the Zenith Angle of the line-of sight (LOS). The actual atmospheric profile (temperature, pressure, humidity, ozone content) at that time and place is retrieved from the ETHER atmospheric data base (from a combination of ECMWF meteorological field and other informations), and the atmospheric transmission is computed from LBLRTM software and HITRAN data base for a number of gases: O2, H2O, O3, CO2, and Rayleigh extinction. The first purpose of TAPAS ...

  3. ARM Carbon Cycle Gases Flasks at SGP Site

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Biraud, Sebastien

    2013-03-26

    Data from flasks are sampled at the Atmospheric Radiation Measurement Program ARM, Southern Great Plains Site and analyzed by the National Oceanic and Atmospheric Administration NOAA, Earth System Research Laboratory ESRL. The SGP site is included in the NOAA Cooperative Global Air Sampling Network. The surface samples are collected from a 60 m tower at the ARM SGP Central Facility, usually once per week in the afternoon. The aircraft samples are collected approximately weekly from a chartered aircraft, and the collection flight path is centered over the tower where the surface samples are collected. The samples are collected by the ARM and LBNL Carbon Project.

  4. ARM Carbon Cycle Gases Flasks at SGP Site

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Biraud, Sebastien

    Data from flasks are sampled at the Atmospheric Radiation Measurement Program ARM, Southern Great Plains Site and analyzed by the National Oceanic and Atmospheric Administration NOAA, Earth System Research Laboratory ESRL. The SGP site is included in the NOAA Cooperative Global Air Sampling Network. The surface samples are collected from a 60 m tower at the ARM SGP Central Facility, usually once per week in the afternoon. The aircraft samples are collected approximately weekly from a chartered aircraft, and the collection flight path is centered over the tower where the surface samples are collected. The samples are collected by the ARM and LBNL Carbon Project.

  5. Impacts of aerosols on the chemistry of atmospheric trace gases: a case study of peroxides and HO2 radicals

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    - + H2O2 + H+ SO4 2- + H2O + 2H+ 6.9107 4000 R44 HSO3- + O3 HSO4 - + O2 3.7105 5530 R45 SO3 2- + O3+ + SO4 2- Cu(SO4) 2.3102 E6 HSO4 - SO4 2- + H+ 1.0210-2 -2700 E7 HSO3 - SO3 2- + H+ 6.2210-8 -1960

  6. Integrated Study of MFRSR-derived Parameters of Atmospheric Aerosols and Trace Gases Over the ARM CART Site Extended Facili...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLANIs gravity aOverviewISM Integrated Safety

  7. Final report on activities and findings under DOE grant Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases

    SciTech Connect (OSTI)

    Prather, Michael J.

    2014-11-07

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  8. ARM - Atmospheric Heat Budget

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016Study (CHAPS)Archive CampaignListAtmospheric Heat

  9. ARM - Atmospheric Pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016Study (CHAPS)Archive CampaignListAtmospheric

  10. Atmospheric PSF Interpolation

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby a contractor ofvarDOE PAGES11 PPPL-Atmospheric PSF

  11. Finite-size energy of non-interacting Fermi gases

    E-Print Network [OSTI]

    Martin Gebert

    2014-06-14

    We prove the asymptotics of the difference of the ground-state energies of two non-interacting $N$-particle Fermi gases on the half line of length $L$ in the thermodynamic limit up to order $1/L$. We are particularly interested in subdominant terms proportional to $1/L$, called finite-size energy. In the nineties Affleck and co-authors [Aff97, ZA97, AL94] claimed that the finite-size energy equals the decay exponent occuring in Anderson's orthogonality catastrophe. It turns out that the finite-size energy depends on the details of the thermodynamic limit and typically also includes a linear term in the scattering phase shift.

  12. Wave speeds in the macroscopic extended model for ultrarelativistic gases

    SciTech Connect (OSTI)

    Borghero, F.; Demontis, F.; Pennisi, S.

    2013-11-15

    Equations determining wave speeds for a model of ultrarelativistic gases are investigated. This model is already present in literature; it deals with an arbitrary number of moments and it was proposed in the context of exact macroscopic approaches in Extended Thermodynamics. We find these results: the whole system for the determination of the wave speeds can be divided into independent subsystems which are expressed by linear combinations, through scalar coefficients, of tensors all of the same order; some wave speeds, but not all of them, are expressed by square roots of rational numbers; finally, we prove that these wave speeds for the macroscopic model are the same of those furnished by the kinetic model.

  13. The exponent in the orthogonality catastrophe for Fermi gases

    E-Print Network [OSTI]

    Martin Gebert; Heinrich Kttler; Peter Mller; Peter Otte

    2015-06-15

    We quantify the asymptotic vanishing of the ground-state overlap of two non-interacting Fermi gases in $d$-dimensional Euclidean space in the thermodynamic limit. Given two one-particle Schr\\"odinger operators in finite-volume which differ by a compactly supported bounded potential, we prove a power-law upper bound on the ground-state overlap of the corresponding non-interacting $N$-particle systems. We interpret the decay exponent $\\gamma$ in terms of scattering theory and find $\\gamma = \\pi^{-2}{\\lVert\\arcsin{\\lvert T_E/2\\rvert}\\rVert}_{\\mathrm{HS}}^2$, where $T_E$ is the transition matrix at the Fermi energy $E$. This exponent reduces to the one predicted by Anderson [Phys. Rev. 164, 352-359 (1967)] for the exact asymptotics in the special case of a repulsive point-like perturbation.

  14. Nuclear magnetic resonance imaging with hyper-polarized noble gases

    SciTech Connect (OSTI)

    Schmidt, D.M.; George, J.S.; Penttila, S.I.; Caprihan, A.

    1997-10-01

    This is the final report of a six-month, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The nuclei of noble gases can be hyper polarized through a laser-driven spin exchange to a degree many orders of magnitude larger than that attainable by thermal polarization without requiring a strong magnetic field. The increased polarization from the laser pumping enables a good nuclear magnetic resonance (NMR) signal from a gas. The main goal of this project was to demonstrate diffusion-weighted imaging of such hyper-polarized noble gas with magnetic resonance imaging (MRI). Possible applications include characterizing porosity of materials and dynamically imaging pressure distributions in biological or acoustical systems.

  15. Noble gases and cosmogenic radionuclides in the Eltanin Pacific meteorite

    SciTech Connect (OSTI)

    Bogard, D D; Garrison, D H; Caffee, M W; Kyte, F; Nishiizumi, K

    2000-01-14

    A 1.5 cm long, 1.2 g specimen of the Eltanin meteorite was found at 10.97 m depth in Polarstern piston core PS2704-1. The early studies indicated that the small fragments of the Eltanin meteorite was debris from a km-sized asteroid which impacted into the deep-ocean basin. In this study, the authors measured {sup 39}Ar-{sup 40}Ar age, noble gases, and cosmogenic radionuclides in splits of specimen as a part of consortium studies of Eltanin meteorite. They concluded that the specimen was about 3 m deep from the asteroid surface. The exposure age of the Eltanin asteroid was about 20 Myr.

  16. Free Energies of Dilute Bose gases: upper bound

    E-Print Network [OSTI]

    Jun Yin

    2010-12-19

    We derive a upper bound on the free energy of a Bose gas system at density $\\rho$ and temperature $T$. In combination with the lower bound derived previously by Seiringer \\cite{RS1}, our result proves that in the low density limit, i.e., when $a^3\\rho\\ll 1$, where $a$ denotes the scattering length of the pair-interaction potential, the leading term of $\\Delta f$ the free energy difference per volume between interacting and ideal Bose gases is equal to $4\\pi a (2\\rho^2-[\\rho-\\rhoc]^2_+)$. Here, $\\rhoc(T)$ denotes the critical density for Bose-Einstein condensation (for the ideal gas), and $[\\cdot ]_+$ $=$ $\\max\\{\\cdot, 0\\}$ denotes the positive part.

  17. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect (OSTI)

    Lelas, K.; Seva, T.; Buljan, H.

    2011-12-15

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  18. Performance of the STACEE Atmospheric Cherenkov Telescope

    E-Print Network [OSTI]

    STACEE Collaboration; D. A. Williams; D. Bhattacharya; L. M. Boone; M. C. Chantell; Z. Conner; C. E. Covault; M. Dragovan; P. Fortin; D. Gingrich; D. T. Gregorich; D. S. Hanna; G. Mohanty; R. Mukherjee; R. A. Ong; S. Oser; K. Ragan; R. A. Scalzo; D. R. Schuette; C. G. Theoret; T. O. Tumer; F. Vincent; J. A. Zweerink

    2000-10-17

    The Solar Tower Atmospheric Cherenkov Effect Experiment (STACEE) is located at the National Solar Thermal Test Facility of Sandia National Laboratories in Albuquerque, New Mexico, USA. The field of solar tracking mirrors (heliostats) around a central receiver tower is used to direct Cherenkov light from atmospheric showers onto secondary mirrors on the tower, which in turn image the light onto cameras of photomultiplier tubes. The STACEE Collaboration has previously reported a detection of the Crab Nebula with approximately 7 standard deviation significance, using 32 heliostats (STACEE-32). This result demonstrates both the viability of the technique and the suitability of the site. We are in the process of completing an upgrade to 48 heliostats (STACEE-48) en route to an eventual configuration using 64 heliostats (STACEE-64) in early 2001. In this paper, we summarize the results obtained on the sensitivity of STACEE-32 and our expectations for STACEE-48 and STACEE-64.

  19. Catalytic process for removing toxic gases from gas streams

    SciTech Connect (OSTI)

    Baglio, J.A.; Gaudet, G.G.; Palilla, F.C.

    1983-02-22

    A multi-stage process for reducing the content of sulfurcontaining gases-notably hydrogen sulfide, sulfur dioxide, carbonyl sulfide and carbon disulfide-in waste gas streams is provided. In the first stage, the gas stream is passed through a reaction zone at a temperature between about 150 and 350/sup 0/C in the presence of a pretreated novel catalyst of the formula xLn/sub 2/O/sub 3/ in which Ln is yttrium or a rare earth element and T is cobalt, iron or nickel, and each of x and y is independently a number from 0 to 3, said catalyst being substantially non-crystalline and having a surface area of from about 10 m/sup 2//g to about 40 m/sup 2//g. The preferred catalyst is one in which Ln is lanthanum, T is cobalt, and x and y range from 1 to 3, including non-integers. The first stage yields a product stream having a reduced content of sulfur-containing gases, including specifically, substantial reduction of carbonyl sulfide and virtual elimination of carbon disulfide. An intermediate stage is a claus reaction, which may take place in one or more reaction zones, at temperatures less than about 130/sup 0/ C, in the presence of known catalysts such as bauxite, alumina or cobalt molybdates. The final stage is the air oxidation of hydrogen sulfide at a temperature between about 150 and 300/sup 0/ C in the presence of a catalyst usable in first stage.

  20. Atmospheric Research at BNL

    ScienceCinema (OSTI)

    Peter Daum

    2010-01-08

    Brookhaven researcher Peter Daum discusses an international field experiment designed to make observations of critical components of the climate system of the southeastern Pacific. Because elements of this system are poorly understood and poorly represent

  1. A field study on the trace metal behavior in atmospheric circulating fluidized-bed coal combustion

    SciTech Connect (OSTI)

    Lind, T.; Kauppinen, E.I.; Jokiniemi, J.K.; Maenhaut, W.

    1994-12-31

    Trace element behavior in atmospheric circulating fluidized-bed combustion (CFBC) of Venezuelan bituminous coal was studied by determining particle size distributions in the CFBC flue gas. The size distributions of calcium, iron, aluminium, and 21 trace elements, Sc, V, Cr, Mn, Co, Ni, Zn, Ga, As, Se, Sr, Cd, Sb, Cs, Ba, La, Ce, Sm, Lu, Pb, and Th, in the size range 0.01--70{micro}m, were determined by collecting aerosols with a low-pressure impactor-cyclone sampling train from the flue gases of an 80-MW(th) CFBC boiler upstream of the electrostatic precipitator. The collected samples were analyzed gravimetrically and with instrumental neutron activation analysis (INAA), particle-induced X-ray emission analysis (PIXE), and inductively coupled plasma mass spectrometry (ICP-MS). The number size distributions of the aerosols were determined with a differential electrical mobility method in the size range 0.01--0.8 {micro}m. In the ultrafine particle mode, i.e., D{sub p} < 0.1 {micro}m, the CFBC number concentrations varied strongly during the experiments, being one to two orders of magnitude lower than those observed in pulverized coal combustion. For all of the elements studied, 75% or more were found in particles larger than 5{micro}m. None of the studied elements showed significant vaporization and subsequent chemical surface reaction or condensation in the CFBC. The Sr, Se, V, Zn, Ga, Cs, Ba, La, Sm, Lu, and Th size distributions resembled those of aluminium, suggesting their occurrence in aluminosilicate-rich particles in the fly ash. The association of the trace elements with aluminium in the fly ash particles may result from reactions of the trace elements with the aluminosilicate mineral particles inside the burning coal particles, or their initial occurrence in association with these minerals.

  2. Abstract--Airborne pollution and explosive gases threaten human health and occupational safety, therefore generating high

    E-Print Network [OSTI]

    Mason, Andrew

    Abstract--Airborne pollution and explosive gases threaten human health and occupational safety and a thumb-drive sized prototype system. I. INTRODUCTION xposure to air pollution consistently ranks among to occupational safety as energy demands rise. Airborne pollutants and explosive gases vary in both time and space

  3. IUPAC-NIST Solubility Data Series 70. Solubility of Gases in Glassy Polymers

    E-Print Network [OSTI]

    Magee, Joseph W.

    IUPAC-NIST Solubility Data Series 70. Solubility of Gases in Glassy Polymers Volume Editors Russell Synthesis, Moscow, Russia Received December 11, 1998 Solubility of gases in polymers is an important in polymers is a fun- damental concern in such areas as food packaging, beverage storage, and polymer pro

  4. Fluctuations and State Preparation in Quantum Degenerate Gases of Sodium and Lithium

    E-Print Network [OSTI]

    Fluctuations and State Preparation in Quantum Degenerate Gases of Sodium and Lithium by Edward Su and State Preparation in Quantum Degenerate Gases of Sodium and Lithium by Edward Su Submitted- periments with sodium and lithium in optical lattices. We describe progress towards the implementation

  5. Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES gas focusing, is observed. For even higher powers, the laser pulse is partially trapped by the plasma laser pulses in tenuous gases is studied. The dynamics of these pulses will be affected by nonlinear

  6. Gas release during salt-well pumping: Model predictions and laboratory validation studies for soluble and insoluble gases

    SciTech Connect (OSTI)

    Peurrung, L.M.; Caley, S.M.; Gauglitz, P.A.

    1997-08-01

    The Hanford Site has 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. Of these, 67 are known or suspected to have leaked liquid from the tanks into the surrounding soil. Salt-well pumping, or interim stabilization, is a well-established operation for removing drainable interstitial liquid from SSTs. The overall objective of this ongoing study is to develop a quantitative understanding of the release rates and cumulative releases of flammable gases from SSTs as a result of salt-well pumping. The current study is an extension of the previous work reported by Peurrung et al. (1996). The first objective of this current study was to conduct laboratory experiments to quantify the release of soluble and insoluble gases. The second was to determine experimentally the role of characteristic waste heterogeneities on the gas release rates. The third objective was to evaluate and validate the computer model STOMP (Subsurface Transport over Multiple Phases) used by Peurrung et al. (1996) to predict the release of both soluble (typically ammonia) and insoluble gases (typically hydrogen) during and after salt-well pumping. The fourth and final objective of the current study was to predict the gas release behavior for a range of typical tank conditions and actual tank geometry. In these models, the authors seek to include all the pertinent salt-well pumping operational parameters and a realistic range of physical properties of the SST wastes. For predicting actual tank behavior, two-dimensional (2-D) simulations were performed with a representative 2-D tank geometry.

  7. Bromocarbons in the tropical coastal and open ocean atmosphere during the 2009 Prime Expedition Scientific Cruise (PESC-09)

    E-Print Network [OSTI]

    Mohd Nadzir, M. S.; Phang, S. M.; Abas, M. R.; Abdul Rahman, N.; Abu Samah, A.; Sturges, W. T.; Oram, D. E.; Mills, G. P.; Leedham, E. C.; Pyle, J. A.; Harris, N. R. P.; Robinson, A. D.; Ashfold, M. J.; Mead, M. I.; Latif, M. T.; Khan, M. F.; Amiruddin, A. M.; Banan, N.; Hanafiah, M. M.

    2014-08-14

    Cl). Biogenic emissions from the oceans have been identified as one of the main natu- ral sources where organisms such as macroalgae (seaweeds) and microalgae (phytoplankton) can release large quanti- ties of halocarbon gases into the atmosphere (Sturges et al... seaweed biomass, with cultivated Kappaphycus and Eucheuma at Semporna, and Sargassum and other brown algae at Kunak. Samples 17 and 21 had slightly elevated levels of C2Cl4, suggesting a possible influence from local anthropogenic sources. Pyle et al...

  8. Atmospheric Radiation Measurement Tropical Warm Pool International Cloud Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O DBiomass and BiofuelsPhysicist47July 1999

  9. ARM - Field Campaign - 2013 Lower Atmospheric Boundary Layer Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See22, 2012 [DataJulyMarch 27,5 Southern2

  10. ARM - Field Campaign - Cross-Scale Land-Atmosphere Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments? WeDatastreamstps DocumentationAtlanticENA ContactsProductsSACR26, 2015govCampaignsCross-Scale

  11. Mobility of singly-charged lanthanide cations in rare gases: Theoretical assessment of the state specificity

    SciTech Connect (OSTI)

    Buchachenko, Alexei A.; Viehland, Larry A.

    2014-03-21

    High quality, ab initio calculations are reported for the potential energy curves governing the interactions of four singly-charged lanthanide ions (Yb{sup +}, Eu{sup +}, Lu{sup +}, and Gd{sup +}) with the rare gases (RG = HeXe). Scalar-relativistic coupled cluster calculations are used for the first three S-state ions, but for Gd{sup +}({sup 10}D) it is necessary to take the interaction anisotropy into account with the help of the multi-reference technique. The potential energy curves are used to determine the ion mobility and other transport properties describing the motion of the ions through the dilute RG, both as functions of the temperature, T, in the low-field limit, and at fixed T as functions of the ratio of the electrostatic field strength to the gas number density, E/N. The calculated mobilities are in good agreement with the very limited experimental data that have become available recently. The calculations show a pronounced dependence of the transport properties on the electronic configuration of the ion, as well as a significant effect of the spin-orbit coupling on the transport properties of the Gd{sup +} ion, and predict that state-specific mobilities could be detectable in Gd{sup +}RG experiments.

  12. Are Greenhouse Gases Changing ENSO Precursors in the Western North Pacific?

    SciTech Connect (OSTI)

    Wang, S-Y (Simon); Heureux, Michelle L.; Yoon, Jin-Ho

    2013-09-01

    Using multiple observational and modeling datasets, we document a strengthening relationship between boreal winter sea surface temperature anomalies (SSTA) in the western North Pacific (WNP) and the development of the El Nino-Southern Oscillation (ENSO) one year later. The increased WNP-ENSO association emerged in the mid 20th century and has grown through the present, reaching correlation coefficients as high as ~0.70 in recent decades. Fully coupled climate experiments with the Community Earth System Model (CESM) replicate the WNP-ENSO association and indicate that greenhouse gases (GHG) are largely responsible for the observed increase. We speculate that shifts in the location and amplitudes of positive SST trends in the subtropical-tropical western Pacific impacts the low-level circulation so that WNP variability is increasingly influencing the development of ENSO one year later. A strengthened GHG-driven relationship between the WNP and ENSO provides an example of how anthropogenic climate change can potentially improve the skill of intraseasonal-to-interannual climate prediction.

  13. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Misztal, P. K.; Hewitt, C. N.; Wildt, J.; Blande, J. D.; Eller, A. S.D.; Fares, S.; Gentner, D. R.; Gilman, J. B.; Graus, M.; Greenberg, J.; et al

    2015-07-13

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functionsmoreof these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y-1), pointing to the importance of these natural emissions in atmospheric physics and chemistry.less

  14. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Molina, Luisa T.; Molina, Mario J.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavaka, Miguel; Velasco, Erik

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on-road vehicles: the MCMA motor vehicles produce abundant amounts of primary PM, elemental carbon, particle-bound polycyclic aromatic hydrocarbons, carbon monoxide and a wide range of air toxics; the feasibility of using eddy covariance techniques to measure fluxes of volatile organic compounds in an urban core and a valuable tool for validating local emissions inventory; a much better understanding of the sources and atmospheric loadings of volatile organic compounds; the first spectroscopic detection of glyoxal in the atmosphere; a unique analysis of the high fraction of ambient formaldehyde from primary emission sources; characterization of ozone formation and its sensitivity to VOCs and NOx; a much more extensive knowledge of the composition, size distribution and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models; evaluations of significant errors that can arise from standard air quality monitors for O3 and NO2; and the implementation of an innovative Markov Chain Monte Carlo method for inorganic aerosol modeling as a powerful tool to analyze aerosol data and predict gas phase concentrations where these are unavailable. During the MILAGRO Campaign the collaborative team utilized a combination of central fixed sites and a mobile laboratory deployed throughout the MCMA to representative urban and boundary sites to measure trace gases and fine particles. Analysis of the extensive 2006 data sets has confirmed the key findings from MCMA-2002/2003; additionally MCMA-2006 provided more detailed gas and aerosol chemistry and wider regional scale coverage. Key results include an updated 2006 emissions inventory; extension of the flux system to measure fluxes of fine particles; better understanding of the sources and apportionment of aerosols, including contribution from biomass burning and industrial sources; a comprehensive evaluation of metal containing particles in a com

  15. Space Science : Atmosphere Greenhouse Effect

    E-Print Network [OSTI]

    Johnson, Robert E.

    Space Science : Atmosphere Greenhouse Effect Part-5a Solar + Earth Spectrum IR Absorbers Grey Atmosphere Greenhouse Effect #12;Radiation: Solar and Earth Surface B"(T) Planck Ideal Emission Integrate and it emits Note: heat balance Fvis( = Fout = Te 4 z #12;(simple Greenhouse cont.) 0 1 2 3 4 Ground Space Top

  16. Glass surface deactivants for sulfur-containing gases

    SciTech Connect (OSTI)

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  17. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  18. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  19. Atmospheric science encompasses meteorology and climatology, as well as fields such as atmospheric chemistry and remote sensing.Atmospheric

    E-Print Network [OSTI]

    chemistry and remote sensing.Atmospheric scientists apply physics, mathematics, and chemistry to understandAtmospheric science encompasses meteorology and climatology, as well as fields such as atmospheric the atmosphere and its interactions with land and sea. One of the goals of atmospheric science is to understand

  20. Digestion Experiments.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1908-01-01

    STATION. ppp DIGESTION EXPERIMENTS G. S. FRAPS, PH. D., CHEMIST. POSTOFFICE COLLEGE SL'ATION, HRAZOS COUNTY, TEXAS. AUSTIN, TEXAS: \\'ON BOECKMANN-JONES CO., PRLNTEHP. 1908 TEXAS AGRICULTURAL EXPERIMENT 8TArFIONS. OFFICERS. GOVERNING BOARD... OF CONTENTS . 1 . Digestibility of 1Caffir Corn. Milo Maize. and Molasses ....... G .................................... Ilcfinition of Terms 7 .................................. Method of Experiment 7 ............ Digestibility of Basal Ration of Meal...

  1. DIVISION OF MARINE AND ATMOSPHERIC CHEMISTRY

    E-Print Network [OSTI]

    Shyu, Mei-Ling

    DIVISION OF MARINE AND ATMOSPHERIC CHEMISTRY The missions of the Division of Marine and Atmospheric Chemistry (MAC) are to carry out broadly based research on the chemistry of the atmosphere and marine and stratosphere. Atmospheric Chemistry Research activities in atmospheric chemistry and modeling are diverse

  2. The effect of diluent gases on ignition delay times in the shock tube and in the rapid compression machine

    SciTech Connect (OSTI)

    Wuermel, J.; Silke, E.J.; Curran, H.J.; O Conaire, M.S.; Simmie, J.M.

    2007-10-15

    The diluent gas used in the preparation of test fuel/oxygen mixtures is inert and does not take part in the chemical reaction. However, it does have an effect on the measured ignition delay time both in rapid compression machines and in shock tubes - argon decelerates ignition in the RCM, but accelerates it in the shock tube under some conditions. This opposite effect is due to the times scales involved in these experimental devices. Typical ignition delay times in the RCM are in the region of 1-200 ms, while those in the shock tube are much shorter (10-1000 {mu}s). Comparative RCM experiments and simulations for helium, argon, xenon, and nitrogen have shown extreme heat loss in the postcompression period, particularly for helium. Autoignition measurements of 2,3-dimethylpentane have highlighted a direct dependency of ignition delay time on the type of diluent used, where longer ignition delay time were recorded with argon. This increased ignition delay time is due to the extreme cooling of argon in the postcompression period. This observation was strengthened by comparative experiments with helium and argon, where the diluent effect was even stronger for helium, caused by its higher thermal conductivity. In the shock tube, the diluent effect is opposite to that in the RCM. For dilute mixtures of isooctane, calculations have predicted that mixtures with argon will ignite faster than those with nitrogen, based on the relative heat capacities of the two diluent gases. Overall, we conclude that the choice of diluent gases in experimental devices must be made with care, as ignition delay times can depend strongly on the type of diluent gas used. (author)

  3. Pairing and superfluidity in strongly interacting Fermi gases

    E-Print Network [OSTI]

    Schunck, Christian H. (Christian Heinrich)

    2008-01-01

    This thesis describes experiments with superfluid spin mixtures of ultracold fermionic 6Li atoms. The properties of the strongly interacting gas are studied in the crossover regime between Bose-Einstein condensation (BEC) ...

  4. Nonperturbative Effects on the Ferromagnetic Transition in Repulsive Fermi Gases

    E-Print Network [OSTI]

    Lianyi He; Xu-Guang Huang

    2012-04-26

    It is generally believed that a dilute spin-1/2 Fermi gas with repulsive interactions can undergo a ferromagnetic phase transition to a spin-polarized state at a critical gas parameter $(k_{\\rm F}a)_c$. Previous theoretical predictions of the ferromagnetic phase transition have been based on the perturbation theory, which treats the gas parameter as a small number. On the other hand, Belitz, Kirkpatrick, and Vojta (BKV) have argued that the phase transition in clean itinerant ferromagnets is generically of first order at low temperatures, due to the correlation effects that lead to a nonanalytic term in the free energy. The second-order perturbation theory predicts a first-order phase transition at $(k_{\\rm F}a)_c=1.054$, consistent with the BKV argument. However, since the critical gas parameter is expected to be of order O(1), perturbative predictions may be unreliable. In this paper we study the nonperturbative effects on the ferromagnetic phase transition by summing the particle-particle ladder diagrams to all orders in the gas parameter. We consider a universal repulsive Fermi gas where the effective range effects can be neglected, which can be realized in a two-component Fermi gas of $^6$Li atoms by using a nonadiabatic field switch to the upper branch of a Feshbach resonance with a positive s-wave scattering length. Our theory predicts a second-order phase transition, which indicates that ferromagnetic transition in dilute Fermi gases is possibly a counterexample to the BKV argument. The predicted critical gas parameter $(k_{\\rm F}a)_c=0.858$ is in good agreement with the recent quantum Monte Carlo result $(k_{\\rm F}a)_c=0.86$ for a nearly zero-range potential [S. Pilati, \\emph{et al}., Phys. Rev. Lett. {\\bf 105}, 030405 (2010)]. We also compare the spin susceptibility with the quantum Monte Carlo result and find good agreement.

  5. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard (Lafayette, CO); Schwartz, Michael (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  6. Localization of Deep Water Formation: Role of Atmospheric Moisture Transport and Geometrical Constraints on Ocean Circulation

    E-Print Network [OSTI]

    Marshall, John C.

    A series of coupled atmosphereoceanice aquaplanet experiments is described in which topological constraints on ocean circulation are introduced to study the role of ocean circulation on the mean climate of the coupled ...

  7. Carbon Dynamics in Aquatic Ecosystems in Response to Elevated Atmospheric CO2 and Altered Nutrients Availability

    E-Print Network [OSTI]

    Song, Chao

    2011-04-26

    Aquatic ecosystems will experience altered inorganic carbon, nitrogen and phosphorous availability in the future due to elevated atmospheric CO2, stronger stratification and anthropogenic activities. Despite its importance in modulating global...

  8. Rethinking Downstream Regulation: California's Opportunity to Engage Households in Reducing Greenhouse Gases

    E-Print Network [OSTI]

    2008-01-01

    greenhouse gases. Energy Policy (2008), doi:10.1016/j.rebound effecta survey. Energy Policy 28 (6-7), 389401.and climate policy. Energy Policy 32 (4), 481491. Leiby,

  9. Kinetic modeling of nitric oxide removal from exhaust gases by Selective Non-Catalytic Reduction

    E-Print Network [OSTI]

    Chenanda, Cariappa Mudappa

    1993-01-01

    Selective Non-Catalytic Reduction is one of the most promising techniques for the removal of oxides of nitrogen from combustion exhaust gases. These techniques are based on the injection of certain compounds, such as cyanuric acid and ammonia...

  10. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOE Patents [OSTI]

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  11. Metal-organic frameworks with high capacity and selectivity for harmful gases

    E-Print Network [OSTI]

    Yaghi, Omar M.

    , MOF-199, and IRMOF-62, as selective adsorbents for eight harmful gases: sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethyl- ene oxide, and carbon monoxide. Kinetic breakthrough measure- ments are used to determine the calculated dynamic adsorption capacity of each

  12. Quantifying emissions of greenhouse gases from South Asia through a targeted measurement campaign

    E-Print Network [OSTI]

    Ganesan, Anita Lakshmi

    2013-01-01

    Methane (CH 4 ), nitrous oxide (N20) and sulfur hexafluoride (SF6) are powerful greenhouse gases with global budgets that are well-known but regional distributions that are not adequately constrained for the purposes of ...

  13. Quantum coherence and magnetism in bosonic and fermionic gases of ultracold atoms

    E-Print Network [OSTI]

    Jo, Gyu-Boong

    2010-01-01

    In this thesis, two sets of experimental studies in bosonic and fermionic gases are described. In the first part of the thesis, itinerant ferromagnetism was studied in a strongly interacting Fermi gas of ultracold atoms. ...

  14. Biological sweetening of energy gases mimics in biotrickling filters Marc Fortuny a,c

    E-Print Network [OSTI]

    : Hydrogen sulfide; Gas sweetening; Biotrickling filter; Desulfurization; Fuel gas; Biogas 1. Introduction in energy-rich gases such as biogas from anaerobic digesters which may contain H2S concentrations exceeding

  15. ATMOSPHERIC CHEMISTRY - RESPONSE TO HUMAN INFLUENCE

    E-Print Network [OSTI]

    LOGAN, J; PRATHER, M; WOFSY, S; MCELROY, M

    1978-01-01

    Trans. II 70, 253. ATMOSPHERIC CHEMISTRY Clyne, M. A. A. &data for modelling atmospheric chemistry. NBS Technical NoteChem. 80, 2711. ATMOSPHERIC CHEMISTRY Sanadze, G. A. 1963 On

  16. IMPROVED QUASISTEADYSTATEAPPROXIMATION METHODS FOR ATMOSPHERIC CHEMISTRY INTEGRATION #

    E-Print Network [OSTI]

    Jay, Laurent O.

    IMPROVED QUASISTEADYSTATEAPPROXIMATION METHODS FOR ATMOSPHERIC CHEMISTRY INTEGRATION # L. O. JAY QSSA are presented. Key words. atmospheric chemistry, sti# ordinary di#erential equations, quasi PII. S1064827595283033 1. Introduction. As our scientific understanding of atmospheric chemistry

  17. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  18. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  19. Scale-free Universal Spectrum for Atmospheric Aerosol Size Distribution for Davos, Mauna Loa and Izana

    E-Print Network [OSTI]

    A. M. Selvam

    2014-08-14

    Atmospheric flows exhibit fractal fluctuations and inverse power law form for power spectra indicating an eddy continuum structure for the selfsimilar fluctuations. A general systems theory for fractal fluctuations developed by the author is based on the simple visualisation that large eddies form by space-time integration of enclosed turbulent eddies, a concept analogous to Kinetic Theory of Gases in Classical Statistical Physics. The ordered growth of atmospheric eddy continuum is in dynamical equilibrium and is associated with Maximum Entropy Production. The model predicts universal (scale-free) inverse power law form for fractal fluctuations expressed in terms of the golden mean. Atmospheric particulates are held in suspension in the fractal fluctuations of vertical wind velocity. The mass or radius (size) distribution for homogeneous suspended atmospheric particulates is expressed as a universal scale-independent function of the golden mean, the total number concentration and the mean volume radius. Model predicted spectrum is in agreement (within two standard deviations on either side of the mean) with total averaged radius size spectra for the AERONET (aerosol inversions) stations Davos and Mauna Loa for the year 2010 and Izana for the year 2009 daily averages. The general systems theory model for aerosol size distribution is scale free and is derived directly from atmospheric eddy dynamical concepts. At present empirical models such as the log normal distribution with arbitrary constants for the size distribution of atmospheric suspended particulates are used for quantitative estimation of earth-atmosphere radiation budget related to climate warming/cooling trends. The universal aerosol size spectrum will have applications in computations of radiation balance of earth-atmosphere system in climate models.

  20. Experiment Profile:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    their shapes, how galaxies cluster and the brightness of exploding stars called supernovae. WHY IS THIS EXPERIMENT NEEDED NOW? Research during the last decade using different...

  1. Infrared Observations of Exoplanet Atmospheres

    E-Print Network [OSTI]

    Crossfield, Ian James Mills

    2012-01-01

    However, atmospheres of cool planets can still be studiedvia outgassing as the planet cools (Rogers & Seager 2010).at low resolution) and the cool, low-mass planet GJ 1214b (

  2. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion...

  3. Laser Atmospheric Studies with VERITAS

    E-Print Network [OSTI]

    C. M. Hui; for the VERITAS collaboration

    2007-09-25

    As a calibrated laser pulse propagates through the atmosphere, the amount of Rayleigh-scattered light arriving at the VERITAS telescopes can be calculated precisely. This technique was originally developed for the absolute calibration of ultra-high-energy cosmic-ray fluorescence telescopes but is also applicable to imaging atmospheric Cherenkov telescopes (IACTs). In this paper, we present two nights of laser data taken with the laser at various distances away from the VERITAS telescopes and compare it to Rayleigh scattering simulations.

  4. Report of the Solar and Atmospheric Neutrino Working Group

    SciTech Connect (OSTI)

    Back, H.; Bahcall, J.N.; Bernabeu, J.; Boulay, M.G.; Bowles, T.; Calaprice, F.; Champagne, A.; Freedman, S.; Gai, M.; Galbiati, C.; Gallagher, H.; Gonzalez-Garcia, C.; Hahn, R.L.; Heeger, K.M.; Hime, A.; Jung, C.K.; Klein, J.R.; Koike, M.; Lanou, R.; Learned, J.G.; Lesko, K.T.; Losecco, J.; Maltoni, M.; Mann, A.; McKinsey, D.; Palomares-Ruiz, S.; Pena-Garay, C.; Petcov, S.T.; Piepke, A.; Pitt, M.; Raghavan, R.; Robertson, R.G.H.; Scholberg, K.; Sobel, H.W.; Takeuchi, T.; Vogelaar, R.; Wolfenstein, L.

    2004-10-22

    The highest priority of the Solar and Atmospheric Neutrino Experiment Working Group is the development of a real-time, precision experiment that measures the pp solar neutrino flux. A measurement of the pp solar neutrino flux, in comparison with the existing precision measurements of the high energy {sup 8}B neutrino flux, will demonstrate the transition between vacuum and matter-dominated oscillations, thereby quantitatively testing a fundamental prediction of the standard scenario of neutrino flavor transformation. The initial solar neutrino beam is pure {nu}{sub e}, which also permits sensitive tests for sterile neutrinos. The pp experiment will also permit a significantly improved determination of {theta}{sub 12} and, together with other solar neutrino measurements, either a measurement of {theta}{sub 13} or a constraint a factor of two lower than existing bounds. In combination with the essential pre-requisite experiments that will measure the {sup 7}Be solar neutrino flux with a precision of 5%, a measurement of the pp solar neutrino flux will constitute a sensitive test for non-standard energy generation mechanisms within the Sun. The Standard Solar Model predicts that the pp and {sup 7}Be neutrinos together constitute more than 98% of the solar neutrino flux. The comparison of the solar luminosity measured via neutrinos to that measured via photons will test for any unknown energy generation mechanisms within the nearest star. A precise measurement of the pp neutrino flux (predicted to be 92% of the total flux) will also test stringently the theory of stellar evolution since the Standard Solar Model predicts the pp flux with a theoretical uncertainty of 1%. We also find that an atmospheric neutrino experiment capable of resolving the mass hierarchy is a high priority. Atmospheric neutrino experiments may be the only alternative to very long baseline accelerator experiments as a way of resolving this fundamental question. Such an experiment could be a very large scale water Cerenkov detector, or a magnetized detector with flavor and antiflavor sensitivity. Additional priorities are nuclear physics measurements which will reduce the uncertainties in the predictions of the Standard Solar Model, and similar supporting measurements for atmospheric neutrinos (cosmic ray fluxes, magnetic fields, etc.). We note as well that the detectors for both solar and atmospheric neutrino measurements can serve as multipurpose detectors, with capabilities of discovering dark matter, relic supernova neutrinos, proton decay, or as targets for long baseline accelerator neutrino experiments.

  5. Zevenhoven & Kilpinen Greenhouse Gases, Ozone-Depleting Gases 19.6.2001 9-1 Figure 9.1 Increasing world population

    E-Print Network [OSTI]

    Zevenhoven, Ron

    ), methane (CH4) and nitrous oxide (N2O) trap the outgoing solar radiation that is reflected by the earth by blocking "hard" ultraviolet solar radiation. #12;Zevenhoven & Kilpinen Greenhouse Gases, Ozone by using experimental data from e.g. air trapped in polar ice. CO2 concentrations started to rise in ~1800

  6. Transformative Experiences

    E-Print Network [OSTI]

    Gering, Jon C.

    Transformative Experiences Internships & Field Schools Honors & Research Faculty Notables Alumni have at least one poten- tially transformative experi- ence - an opportunity to de- sign and carry out to be transformational are study abroad, internships, service learning, research, student-led learning, and lead- ership

  7. Abiotic ozone and oxygen in atmospheres similar to prebiotic Earth

    SciTech Connect (OSTI)

    Domagal-Goldman, Shawn D.; Segura, Antgona; Claire, Mark W.; Robinson, Tyler D.; Meadows, Victoria S.

    2014-09-10

    The search for life on planets outside our solar system will use spectroscopic identification of atmospheric biosignatures. The most robust remotely detectable potential biosignature is considered to be the detection of oxygen (O{sub 2}) or ozone (O{sub 3}) simultaneous to methane (CH{sub 4}) at levels indicating fluxes from the planetary surface in excess of those that could be produced abiotically. Here we use an altitude-dependent photochemical model with the enhanced lower boundary conditions necessary to carefully explore abiotic O{sub 2} and O{sub 3} production on lifeless planets with a wide variety of volcanic gas fluxes and stellar energy distributions. On some of these worlds, we predict limited O{sub 2} and O{sub 3} buildup, caused by fast chemical production of these gases. This results in detectable abiotic O{sub 3} and CH{sub 4} features in the UV-visible, but no detectable abiotic O{sub 2} features. Thus, simultaneous detection of O{sub 3} and CH{sub 4} by a UV-visible mission is not a strong biosignature without proper contextual information. Discrimination between biological and abiotic sources of O{sub 2} and O{sub 3} is possible through analysis of the stellar and atmospheric contextparticularly redox state and O atom inventoryof the planet in question. Specifically, understanding the spectral characteristics of the star and obtaining a broad wavelength range for planetary spectra should allow more robust identification of false positives for life. This highlights the importance of wide spectral coverage for future exoplanet characterization missions. Specifically, discrimination between true and false positives may require spectral observations that extend into infrared wavelengths and provide contextual information on the planet's atmospheric chemistry.

  8. Modulational instability, wave breaking and formation of large scale dipoles in the atmosphere

    E-Print Network [OSTI]

    A. Iafrati; A. Babanin; M. Onorato

    2012-08-27

    In the present Letter we use the Direct Numerical Simulation (DNS) of the Navier-Stokes equation for a two-phase flow (water and air) to study the dynamics of the modulational instability of free surface waves and its contribution to the interaction between ocean and atmosphere. If the steepness of the initial wave is large enough, we observe a wave breaking and the formation of large scale dipole structures in the air. Because of the multiple steepening and breaking of the waves under unstable wave packets, a train of dipoles is released and propagate in the atmosphere at a height comparable with the wave length. The amount of energy dissipated by the breaker in water and air is considered and, contrary to expectations, we observe that the energy dissipation in air is larger than the one in the water. Possible consequences on the wave modelling and on the exchange of aerosols and gases between air and water are discussed.

  9. Soft x-ray generation in gases with an ultrashort pulse laser

    SciTech Connect (OSTI)

    Ditmire, T.R.

    1996-01-08

    An experimental investigation of soft x-ray production resulting from the interaction of intense near infra-red laser radiation with gases is presented in this thesis. Specifically, soft x-ray generation through high order harmonic generation or exploiting intense inverse bremsstrahlung heating is examined. Most of these studies are conducted with femtosecond, terawatt class Cr:LiSrAlF{sub 6} (LiSAF) laser, though results derived from studies with other laser systems are presented as well. The majority of this work is devoted to experimental investigations, however, theoretical and computational models are developed to interpret the data. These studies are motivated by the possibility of utilizing the physics of intense laser/matter interactions as a potential compact source of bright x-rays. Consequently, the thrust of many of the experiments conducted is aimed at characterizing the x-rays produced for possible use in applications. In general, the studies of this manuscript fall into three categories. First, a unique 130 fs, 8 TW laser that is based on chirped pulse amplification, is described, and its performance is evaluated. The generation of x-rays through high order harmonics is then discussed with emphasis on characterizing and optimizing harmonic generation. Finally, the generation of strong, incoherent x-ray radiation by the intense irradiation of large (>1,000 atom) clusters in gas jets, is explored. The physics of laser energy absorption by clusters illuminated with intensities of 10{sup 15} to 10{sup 17} W/cm{sup 2} is considered in detail. X-ray spectroscopy of the hot plasmas that result from the irradiation of the clusters is conducted, and energy transport and kinetics issues in these plasmas are discussed.

  10. Theoretical investigation of the impact of grain boundaries and fission gases on UO2 thermal conductivity

    SciTech Connect (OSTI)

    Du, Shiyu; Andersson, Anders D.; Germann, Timothy C.; Stanek, Christopher R.

    2012-05-02

    Thermal conductivity is one of the most important metrics of nuclear fuel performance. Therefore, it is crucial to understand the impact of microstructure features on thermal conductivity, especially since the microstructure evolves with burn-up or time in the reactor. For example, UO{sub 2} fuels are polycrystalline and for high-burnup fuels the outer parts of the pellet experience grain sub-division leading to a very fine grain structure. This is known to impact important physical properties such as thermal conductivity as fission gas release. In a previous study, we calculated the effect of different types of {Sigma}5 grain boundaries on UO{sub 2} thermal conductivity and predicted the corresponding Kapitza resistances, i.e. the resistance of the grain boundary in relation to the bulk thermal resistance. There have been reports of pseudoanisotropic effects for the thermal conductivity in cubic polycrystalline materials, as obtained from molecular dynamics simulations, which means that the conductivity appears to be a function of the crystallographic direction of the temperature gradient. However, materials with cubic symmetry should have isotropic thermal conductivity. For this reason it is necessary to determine the cause of this apparent anisotropy and in this report we investigate this effect in context of our earlier simulations of UO{sub 2} Kapitza resistances. Another source of thermal resistance comes from fission products and fission gases. Xe is the main fission gas and when generated in sufficient quantity it dissolves from the lattice and forms gas bubbles inside the crystalline structure. We have performed studies of how Xe atoms dissolved in the UO{sub 2} matrix or precipitated as bubbles impact thermal conductivity, both in bulk UO{sub 2} and in the presence of grain boundaries.

  11. Development and application of an analysis methodology for interpreting ambiguous historical pressure data in the WIPP gas-generation experiments.

    SciTech Connect (OSTI)

    Felicione, F. S.

    2006-01-23

    The potential for generation of gases in transuranic (TRU) waste by microbial activity, chemical interactions, corrosion, and radiolysis was addressed in the Argonne National Laboratory-West (ANL-West) Gas-Generation Experiments (GGE). Data was collected over several years by simulating the conditions in the Waste Isolation Pilot Plant (WIPP) after the eventual intrusion of brine into the repository. Fourteen test containers with various actual TRU waste immersed in representative brine were inoculated with WIPP-relevant microbes, pressurized with inert gases, and kept in an inert-atmosphere environment for several years to provide estimates of the gas-generation rates that will be used in computer models for future WIPP Performance Assessments. Modest temperature variations occurred during the long-term ANL-West experiments. Although the experiment temperatures always remained well within the experiment specifications, the small temperature variation was observed to affect the test container pressure far more than had been anticipated. In fact, the pressure variations were so large, and seemingly erratic, that it was impossible to discern whether the data was even valid and whether the long-term pressure trend was increasing, decreasing, or constant. The result was that no useful estimates of gas-generation rates could be deduced from the pressure data. Several initial attempts were made to quantify the pressure fluctuations by relating these to the measured temperature variation, but none was successful. The work reported here carefully analyzed the pressure measurements to determine if these were valid or erroneous data. It was found that a thorough consideration of the physical phenomena that were occurring can, in conjunction with suitable gas laws, account quite accurately for the pressure changes that were observed. Failure of the earlier attempts to validate the data was traced to the omission of several phenomena, the most important being the variation in the headspace volume caused by thermal expansion and contraction within the brine and waste. A further effort was directed at recovering useful results from the voluminous archived pressure data. An analytic methodology to do this was developed. This methodology was applied to each archived pressure measurement to nullify temperature and other effects to yield an adjusted pressure, from which gas-generation rates could be calculated. A review of the adjusted-pressure data indicated that generated-gas concentrations among these containers after approximately 3.25 years of test operation ranged from zero to over 17,000 ppm by volume. Four test containers experienced significant gas generation. All test containers that showed evidence of significant gas generation contained carbon-steel in the waste, indicating that corrosion was the predominant source of gas generation.

  12. Waste Heat Recovery from High Temperature Off-Gases from Electric Arc Furnace

    SciTech Connect (OSTI)

    Nimbalkar, Sachin U [ORNL; Thekdi, Arvind [E3M Inc; Keiser, James R [ORNL; Storey, John Morse [ORNL

    2014-01-01

    This article presents a study and review of available waste heat in high temperature Electric Arc Furnace (EAF) off gases and heat recovery techniques/methods from these gases. It gives details of the quality and quantity of the sensible and chemical waste heat in typical EAF off gases, energy savings potential by recovering part of this heat, a comprehensive review of currently used waste heat recovery methods and potential for use of advanced designs to achieve a much higher level of heat recovery including scrap preheating, steam production and electric power generation. Based on our preliminary analysis, currently, for all electric arc furnaces used in the US steel industry, the energy savings potential is equivalent to approximately 31 trillion Btu per year or 32.7 peta Joules per year (approximately $182 million US dollars/year). This article describes the EAF off-gas enthalpy model developed at Oak Ridge National Laboratory (ORNL) to calculate available and recoverable heat energy for a given stream of exhaust gases coming out of one or multiple EAF furnaces. This Excel based model calculates sensible and chemical enthalpy of the EAF off-gases during tap to tap time accounting for variation in quantity and quality of off gases. The model can be used to estimate energy saved through scrap preheating and other possible uses such as steam generation and electric power generation using off gas waste heat. This article includes a review of the historical development of existing waste heat recovery methods, their operations, and advantages/limitations of these methods. This paper also describes a program to develop and test advanced concepts for scrap preheating, steam production and electricity generation through use of waste heat recovery from the chemical and sensible heat contained in the EAF off gases with addition of minimum amount of dilution or cooling air upstream of pollution control equipment such as bag houses.

  13. Chemistry of Atmospheric Brown Carbon Alexander Laskin,*,

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Chemistry of Atmospheric Brown Carbon Alexander Laskin,*, Julia Laskin,*, and Sergey A. Nizkorodov fraction of atmospheric aerosol and has profound effects on air quality, atmospheric chemistry, and climate of radiation through Earth's atmosphere. The cloud albedo effect, Special Issue: 2015 Chemistry in Climate

  14. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  15. Cumulant expansions for atmospheric flows

    E-Print Network [OSTI]

    Ait-Chaalal, Farid; Meyer, Bettina; Marston, J B

    2015-01-01

    The equations governing atmospheric flows are nonlinear, and consequently the hierarchy of cumulant equations is not closed. But because atmospheric flows are inhomogeneous and anisotropic, the nonlinearity may manifests itself only weakly through interactions of mean fields with disturbances such as thermals or eddies. In such situations, truncations of the hierarchy of cumulant equations hold promise as a closure strategy. We review how truncations at second order can be used to model and elucidate the dynamics of turbulent atmospheric flows. Two examples are considered. First, we study the growth of a dry convective boundary layer, which is heated from below, leading to turbulent upward energy transport and growth of the boundary layer. We demonstrate that a quasilinear truncation of the equations of motion, in which interactions of disturbances among each other are neglected but interactions with mean fields are taken into account, can successfully capture the growth of the convective boundary layer. Seco...

  16. Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases

    E-Print Network [OSTI]

    Neimark, Alexander V.

    Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases into our harbors. Meeting our society's surging demand for commodities

  17. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J. (Bethel Park, PA)

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  18. The Spectral Backbone of Excitation Transport in Ultra-Cold Rydberg Gases

    E-Print Network [OSTI]

    Scholak, Torsten; Buchleitner, Andreas

    2014-01-01

    The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly distributed, highly polarizable atoms that interact via strong dipolar forces. Dynamics in such a system is fundamentally different from cases in which the interactions are of short range, and is ultimately determined by the spectral and eigenvector structure. In the energy levels' spacing statistics, we find evidence for a critical energy that separates delocalized eigenstates from states that are localized at pairs or clusters of atoms separated by less than the typical nearest-neighbor distance. We argue that the dipole blockade effect in Rydberg gases can be leveraged to manipulate this transition across a wide range: As the blockade radius increases, the relative weight of localized states is reduced. At the same time, the spectral statistics -- in particular, the den...

  19. Simulation of condensation systems in the presence of noncondensable gases

    E-Print Network [OSTI]

    Raja, Laxminarayan Lakshmana

    1992-01-01

    , and turbine trip. The MOD3 version of RELAP5 has been developed jointly by the NRC and a consortium consisting of several of the countries and organizations in the U. S. that are members of the International Code Assessment and Applications Program (ICAP... of the loss of residual heat removal (RHR) system during midloop operations is also per- formed. The RELAP5(MOD3 thermal hydraulic code is utilized for the same. Two separate effects experiments were chosen for this study considering their relevance...

  20. Effect of Noble Gases on Sonoluminescence Temperatures during Multibubble

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) | SciTech ConnectExperimentsGAMMA-RAY

  1. Emission of biogenic sulfur gases from Chinese paddy soil and rice plant

    SciTech Connect (OSTI)

    Zhen Yang [Nanjing Univ. of Science and Technology (China); Li Kong [Nanjing Agricultural Univ. (China)

    1996-12-31

    Biogenic sulfur gases emitted from terrestrial ecosystem may play in important role in global sulfur cycle and have a profound influence on global climate change. But very little is known concerning emissions from paddy soil and rice plant, which are abundant in many parts of the world. As a big agricultural country, this is about 33 million hectare rice planted in China. With laboratory incubation and closed chamber method in the field, the biogenic sulfur gases emitted from Chinese paddy soil and rice plant were detected in both conditions: hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), methyl mercaptan (MSH), carbon disulfide (CS{sub 2}), dimethyl sulfide (DMS) and dimethyl disulfide (DMDS). Among which, DMS was predominant part of sulfur emission. Emission of sulfur gases from different paddy field exhibit high spatial and temporal variability. The application of fertilizer and organic manure, total sulfur content in wetland, air temperature were positively correlated to the emission of volatile sulfur gases from paddy soil. Diurnal and seasonal variation of total volatile sulfur gases and DMS indicate that their emissions were greatly influenced by the activity of the rice plant. The annual emission of total volatile sulfur gases, from Nanjing paddy field is ranged from 4.0 to 9.5 mg S m{sup -2}yr{sup -1}, that of DMS is ranged from 3.1 to 6.5 mg S m{sup -2}yr{sup -1}. Rice plant could absorb COS gas, that may be one of the sinks of COS.

  2. A BIOMASS-BASED MODEL TO ESTIMATE THE PLAUSIBILITY OF EXOPLANET BIOSIGNATURE GASES

    E-Print Network [OSTI]

    Seager, Sara

    Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry ...

  3. Data quality monitoring in the presence of aerosols and other adverse atmospheric conditions with H.E.S.S

    E-Print Network [OSTI]

    Hahn, J; Bernlhr, K; Krger, P; Lo, Y T E; Chadwick, P M; Daniel, M K; Deil, C; Gast, H; Kosack, K; Marandon, V

    2015-01-01

    Cherenkov telescope experiments, such as H.E.S.S., have been very successful in astronomical observations in the very-high-energy (VHE; E $>$ 100 GeV) regime. As an integral part of the detector, such experiments use Earth's atmosphere as a calorimeter. For the calibration and energy determination, a standard model atmosphere is assumed. Deviations of the real atmosphere from the model may therefore lead to an energy misreconstruction of primary gamma rays. To guarantee satisfactory data quality with respect to difficult atmospheric conditions, several atmospheric data quality criteria are implemented in the H.E.S.S. software. These quantities are sensitive to clouds and aerosols. Here, the Cherenkov transparency coefficient will be presented. It is a new monitoring quantity that is able to measure long-term changes in the atmospheric transparency. The Cherenkov transparency coefficient derives exclusively from Cherenkov data and is quite hardware-independent. Furthermore, its positive correlation with indepe...

  4. Atmospheric sciences division. Annual report, fiscal year 1981

    SciTech Connect (OSTI)

    Raynor, G.S. (ed.) [ed.

    1981-12-01

    The research activities of the Atmospheric Sciences Division of the Department of Energy and Environment for FY 1981 are presented. Facilities and major items of equipment are described. Research programs are summarized in three categories, modeling, field and laboratory experiments and data management and analysis. Each program is also described individually with title, principal investigator, sponsor and funding levels for FY 1981 and FY 1982. Future plans are summarized. Publications for FY 1981 are listed with abstracts. A list of personnel is included.

  5. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The general specifications for a Pulsed Atmospheric Fluidized Bed Combustor Design Report (PAFBC) plant are presented. The design tasks for the PAFBC are described in the following areas: Coal/Limestone preparation and feed system; pulse combustor; fluidized bed; boiler parts; and ash handling system.

  6. Critical phenomena in atmospheric precipitation

    E-Print Network [OSTI]

    Loss, Daniel

    LETTERS Critical phenomena in atmospheric precipitation OLE PETERS1,2,3 * AND J. DAVID NEELIN3 1 convection and precipitation (the order parameter)--with correlated regions on scales of tens to hundreds the climatological mean by an order of magnitude or more. Moist convection and the accompanying precipitation have

  7. Sorption of organic gases in residential bedrooms andbathrooms

    SciTech Connect (OSTI)

    Singer, B.C.; Hodgson, A.T.; Hotchi, T.; Ming, K.Y.; Sextro,R.G.; Wood, E.E.; Brown, N.J.

    2005-01-05

    Experiments were conducted to characterize organic gas sorption in residential bedrooms (n=4), bathrooms (n=2), and a furnished test chamber. Rooms were studied ''as-is'' with material surfaces and furnishings unaltered. Surface materials were characterized and areas quantified. Experiments included rapid volatilization of a volatile organic compound (VOC) mixture with the room closed and sealed for a 5-h Adsorb phase, followed by 30-min Flush and 2-h closed-room Desorb phases. The mixture included n-alkanes, aromatics, glycol ethers, 2-ethyl-1-hexanol, dichlorobenzene, and organophosphorus compounds. Measured gas-phase concentrations were fit to three variations of a mathematical model that considers sorption occurring at one surface sink and one potential embedded sink. The 2-parameter sink model tracked measurements for most compounds, but improved fits were obtained for some VOCs with a 3-parameter sink-diffusion or a 4-parameter two-sink model. Sorptive partitioning and initial adsorption rates increased with decreasing vapor pressure within each chemical class.

  8. Comparison of heavy ion-induced K? x-ray satellite spectra from gases and solids

    E-Print Network [OSTI]

    Demarest, John Allen

    1977-01-01

    COMPARISON OF HEAVY ION-INDUCED IQX X-RAY SATELLITE SPECTRA FROM GASES AND SOLIDS A Thesis by JOHN ALLEN DEMAREST Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1977 Ma)or Subject: Chemistry COMPARISON OF HEAVY ION-INDUCED Ks X-RAY SATELLITE SPECTRA FROM GASES AND SOLIDS A Thesis by JOHN ALLEN DEMAREST Approved as to style and content by (Chairman of Committee) 7&F~. ~MA (Head...

  9. Energies and damping rates of elementary excitations in spin-1 Bose-Einstein condensed gases

    E-Print Network [OSTI]

    Gergely Szirmai; Peter Szepfalusy; Krisztian Kis-Szabo

    2003-05-15

    Finite temperature Green's function technique is used to calculate the energies and damping rates of elementary excitations of the homogeneous, dilute, spin-1 Bose gases below the Bose-Einstein condensation temperature both in the density and spin channels. For this purpose the self-consistent dynamical Hartree-Fock model is formulated, which takes into account the direct and exchange processes on equal footing by summing up certain classes of Feynman diagrams. The model is shown to fulfil the Goldstone theorem and to exhibit the hybridization of one-particle and collective excitations correctly. The results are applied to the gases of ^{23}Na and ^{87}Rb atoms.

  10. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  11. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  12. Multiple solutions in the theory of direct current glow discharges: Effect of plasma chemistry and nonlocality, different plasma-producing gases, and 3D modelling

    SciTech Connect (OSTI)

    Almeida, P. G. C.; Benilov, M. S.

    2013-10-15

    The work is aimed at advancing the multiple steady-state solutions that have been found recently in the theory of direct current (DC) glow discharges. It is shown that an account of detailed plasma chemistry and non-locality of electron transport and kinetic coefficients results in an increase of the number of multiple solutions but does not change their pattern. Multiple solutions are shown to exist for discharges in argon and helium provided that discharge pressure is high enough. This result indicates that self-organization in DC glow microdischarges can be observed not only in xenon, which has been the case until recently, but also in other plasma-producing gases; a conclusion that has been confirmed by recent experiments. Existence of secondary bifurcations can explain why patterns of spots grouped in concentric rings, observed in the experiment, possess in many cases higher number of spots in outer rings than in inner ones.

  13. IRRADIATION EXPERIMENTS &

    E-Print Network [OSTI]

    McDonald, Kirk

    IRRADIATION EXPERIMENTS & FACILITIES AT BNL: BLIP & NSLS II Peter Wanderer Superconducting MagnetV). Simultaneous irradiation and isotope production by increasing beam energy, placing irradiation target ahead of isotope production target 117 Mev 140, 160, 180, 202 MeV Irradiation at room temperature Alternative

  14. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  15. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  16. Detailed Investigations of Interactions between Ionizing Radiation and Neutral Gases

    SciTech Connect (OSTI)

    Landers, Allen L

    2014-03-31

    We are investigating phenomena that stem from the many body dynamics associated with ionization of an atom or molecule by photon or charged particle. Our program is funded through the Department of Energy EPSCoR Laboratory Partnership Award in collaboration with Lawrence Berkeley National Laboratory. We are using variations on the well established COLTRIMS technique to measure ions and electrons ejected during these interactions. Photoionization measurements take place at the Advanced Light Source at LBNL as part of the ALS-COLTRIMS collaboration with the groups of Reinhard Drner at Frankfurt and Ali Belkacem at LBNL. Additional experiments on charged particle impact are conducted locally at Auburn University where we are studying the dissociative molecular dynamics following interactions with either ions or electrons over a velocity range of 1 to 12 atomic units.

  17. Proceedings of the International Workshop on Sustainable ForestManagement: Monitoring and Verification of Greenhouse Gases

    SciTech Connect (OSTI)

    Sathaye (Ed.), Jayant; Makundi (Ed.), Willy; Goldberg (Ed.),Beth; Andrasko (Ed.), Ken; Sanchez (Ed.), Arturo

    1997-07-01

    The International Workshop on Sustainable Forest Management: Monitoring and Verification of Greenhouse Gases was held in San Jose, Costa Rica, July 29-31, 1996. The main objectives of the workshop were to: (1) assemble key practitioners of forestry greenhouse gas (GHG) or carbon offset projects, remote sensing of land cover change, guidelines development, and the forest products certification movement, to offer presentations and small group discussions on findings relevant to the crucial need for the development of guidelines for monitoring and verifying offset projects, and (2) disseminate the findings to interested carbon offset project developers and forestry and climate change policy makers, who need guidance and consistency of methods to reduce project transaction costs and increase probable reliability of carbon benefits, at appropriate venues. The workshop brought together about 45 participants from developed, developing, and transition countries. The participants included researchers, government officials, project developers, and staff from regional and international agencies. Each shared his or her perspectives based on experience in the development and use of methods for monitoring and verifying carbon flows from forest areas and projects. A shared sense among the participants was that methods for monitoring forestry projects are well established, and the techniques are known and used extensively, particularly in production forestry. Introducing climate change with its long-term perspective is often in conflict with the shorter-term perspective of most forestry projects and standard accounting principles. The resolution of these conflicts may require national and international agreements among the affected parties. The establishment of guidelines and protocols for better methods that are sensitive to regional issues will be an important first step to increase the credibility of forestry projects as viable mitigation options. The workshop deliberations led to three primary outputs: (1) a Workshop Statement in the JI Quarterly, September, 1996; (2) the publication of a series of selected peer-reviewed technical papers from the workshop in a report of the Lawrence Berkeley National Laboratory (LBNL. 40501); and (3) a special issue of the journal ''Mitigation and Adaptation Strategies for Global Change'', Kluwer Academic Publishers. The outputs will be distributed to practitioners in this field and to negotiators attending the Framework Convention on Climate Change (FCCC) deliberations leading up to the Third conference of Parties in Kyoto, in December 1997.

  18. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOE Patents [OSTI]

    Judkins, R.R.; Burchell, T.D.

    1999-07-20

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known pressure swing adsorption'' technique utilizing the same sorption material. 1 fig.

  19. Revised and Updated Thermochemical Properties of the Gases Mercapto ,,HS..., Disulfur Monoxide ,,S2O..., Thiazyl ,,NS...,

    E-Print Network [OSTI]

    Fegley Jr., Bruce

    in the 4th edition of the NIST-JANAF Thermochemical Tables. Updated enthalpies of formation were includedRevised and Updated Thermochemical Properties of the Gases Mercapto ,,HS..., Disulfur Monoxide ,,S2 to compute the thermochemical tables for four ideal gases: mercapto HS , disulfur monox- ide (S2O), thiazyl

  20. Adsorption and Separation of Light Gases on an Amino-Functionalized MetalOrganic Framework: An Adsorption and In Situ XRD Study

    SciTech Connect (OSTI)

    Couck S.; Stavitski E.; Gobehiya, E.; Kirschhock, C.E.A.; Serra-Crespo, P.; Juan-Alcaniz, J.; Martinez Joaristi, A.; Gascon, J.; Kapteijn, F.; Baron, G. V.; Denayer J.F.M.

    2012-02-29

    The NH{sub 2}-MIL-53(Al) metal-organic framework was studied for its use in the separation of CO{sub 2} from CH{sub 4}, H{sub 2}, N{sub 2} C{sub 2}H{sub 6} and C{sub 3}H{sub 8} mixtures. Isotherms of methane, ethane, propane, hydrogen, nitrogen, and CO{sub 2} were measured. The atypical shape of these isotherms is attributed to the breathing properties of the material, in which a transition from a very narrow pore form to a narrow pore form and from a narrow pore form to a large pore form occurs, depending on the total pressure and the nature of the adsorbate, as demonstrated by in-situ XRD patterns measured during adsorption. Apart from CO{sub 2}, all tested gases interacted weakly with the adsorbent. As a result, they are excluded from adsorption in the narrow pore form of the material at low pressure. CO{sub 2} interacted much more strongly and was adsorbed in significant amounts at low pressure. This gives the material excellent properties to separate CO{sub 2} from other gases. The separation of CO{sub 2} from methane, nitrogen, hydrogen, or a combination of these gases has been demonstrated by breakthrough experiments using pellets of NH{sub 2}-MIL-53(Al). The effect of total pressure (1-30 bar), gas composition, temperature (303-403 K) and contact time has been examined. In all cases, CO{sub 2} was selectively adsorbed, whereas methane, nitrogen, and hydrogen nearly did not adsorb at all. Regeneration of the adsorbent by thermal treatment, inert purge gas stripping, and pressure swing has been demonstrated. The NH{sub 2}-MIL-53(Al) pellets retained their selectivity and capacity for more than two years.

  1. BoseEinstein condensation of atomic gases Frederic Chevy and Jean Dalibard

    E-Print Network [OSTI]

    Dalibard, Jean

    BoseEinstein condensation of atomic gases Frederic Chevy and Jean Dalibard Laboratoire Kastler The discovery of the superfluid transition of liquid helium [1, 2] marked the first achievement of BoseEinstein, gaseous BoseEinstein condensates (BECs) discovered in 1995 after the development of laser cooling

  2. Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases

    E-Print Network [OSTI]

    Kolstad, Charles

    Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases to avoid damage from climate change and regulations limiting greenhouse gas emissions at the country level to the Socioeconomic Drivers of Greenhouse Gas Emissions. As the issue was framed (Leifman and Heil, 2005

  3. ANTHROPOGENIC AND NATURAL SOURCES AND SINKS OF GREENHOUSE GASES FOR THE UK

    E-Print Network [OSTI]

    Bateman, Ian J.

    ANTHROPOGENIC AND NATURAL SOURCES AND SINKS OF GREENHOUSE GASES FOR THE UK by W. Neil Adger Katrina are listed at the back of this publication. #12;ANTHROPOGENIC AND NATURAL SOURCES AND SINKS OF GREENHOUSE The Climate Change Framework Convention will require countries to calculate inventories of greenhouse gas

  4. Spin noise spectroscopy to probe quantum states of ultracold fermionic atom gases Bogdan Mihaila,1

    E-Print Network [OSTI]

    Mihaila, Bogdan

    Spin noise spectroscopy to probe quantum states of ultracold fermionic atom gases Bogdan Mihaila,1 2006 We theoretically demonstrate that optical measurements of electron spin noise can interactions predict entirely new sets of resonances in the spin noise spectrum. Once the correct effective

  5. Integrated Model for Production-Distribution Coordination in an Industrial Gases Supply-chain

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    and their demand/consumption profiles Max/Min inventory at production sites and customer locations Max and Respective Production limits Daily Electricity Prices (off-peak and peak) Customers and their demand/consumptionIntegrated Model for Production-Distribution Coordination in an Industrial Gases Supply-chain Pablo

  6. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  7. Heavy noble gases in solar wind delivered by Genesis mission Alex Meshik a,

    E-Print Network [OSTI]

    knowledge of the isotopic composition of the heavy noble gases in solar wind and, by inference, the Sun measured in the Genesis solar wind collectors generally agree with the less precise values obtained from), captured by Genesis Mission collectors (http://genesismis- sion.jpl.nasa.gov/; Burnett et al., 2003

  8. Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases in Soils

    E-Print Network [OSTI]

    Vallino, Joseph J.

    Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases Emissions--Carbon Dioxide Emissions--Sequestration and Storage--Biochar--Basalt--Organic Fertilizers, this investigation focuses on the range of potential of different soil additives to enhance sequestration and storage

  9. AMIII -Termodin^amica dos Gases Ideais 17 de Janeiro de 2002

    E-Print Network [OSTI]

    Ferreira dos Santos, Pedro

    AMIII - Termodin^amica dos Gases Ideais 17 de Janeiro de 2002 N moles de um g´as ideal em equil ideais). A Primeira Lei da Termodin^amica afirma que existe uma fun¸c~ao E : M R, dita a energia interna pela Segunda Lei da Termodin^amica. 2 #12;

  10. AMIII -Termodin^amica dos Gases Ideais 10 de Julho de 2002

    E-Print Network [OSTI]

    Granja, Gustavo

    AMIII - Termodin^amica dos Gases Ideais 10 de Julho de 2002 N moles de um g´as ideal em equil ideais). A Primeira Lei da Termodin^amica afirma que existe uma fun¸c~ao E : M R, dita a energia interna pela Segunda Lei da Termodin^amica. 2 #12;

  11. Analise Matematica III -Turma Especial Ficha Extra 2 -Termodin^amica dos Gases Ideais

    E-Print Network [OSTI]

    Natário, José

    An´alise Matem´atica III - Turma Especial Ficha Extra 2 - Termodin^amica dos Gases Ideais N Termodin^amica afirma que existe uma fun¸c~ao E : M R, dita a energia interna do g´as, cuja derivada garantida em sistemas termodin^amicos gerais pela Segunda Lei da Termodin^amica. 2 #12;

  12. Isotopic studies of rare gases in terrestrial samples and natural nucleosynthesis

    SciTech Connect (OSTI)

    Not Available

    1990-07-01

    This project is concerned with research in rare gas mass spectrometry. We read the natural record that isotopes of the rare gases provide. We study fluids using a system (RARGA) that is sometimes deployed in the field. In 1990 there was a strong effort to reduce the backlog of RARGA samples on hand, so that it was a year of intensive data gathering. Samples from five different areas in the western United States and samples from Guatemala and Australia were analyzed. In a collaborative study we also began analyzing noble gases from rocks associated with the fluids. An important objective, continuing in 1991, is to understand better the reasons for somewhat elevated {sup 3}He/{sup 4}He ratios in regions where there is no contemporary volcanism which could produce the effect by addition of mantle helium. Our helium data have given us and our collaborators some insights, which are to be followed up, into gold mineralization in geothermal regions. Our DOE work in calibrating a sensitive laser microprobe mass spectrometer for noble gases in fluid inclusions continues. Having completed a series of papers on noble gases in diamonds, we next will attempt to make precise isotopic measurements on xenon from mantle sources, in search of evidence for terrestrially elusive {sup 244}Pu decay.

  13. Steam Production from Waste Stack Gases in a Carbon Black Plant

    E-Print Network [OSTI]

    Istre, R. I.

    1981-01-01

    Waste stack gases from carbon black plant bag filters are used as fuel to produce superheated steam - G25 PSIG and 7500F. This steam is out into a steam header that serves Conoco plants in the Lake Charles, Louisiana area. Combustion of the waste...

  14. Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs

    E-Print Network [OSTI]

    George, Steven C.

    Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs PETER CONDORELLI, is produced within the tissue of the airways of the lungs.16 As an intercellular messenger, NO is involved is available regarding the basic gas exchange dynamics of NO in the lungs. Ingested ethanol EtOH is transported

  15. Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network infrastructures are

    E-Print Network [OSTI]

    Politcnica de Catalunya, Universitat

    Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network on the overall power consumption and on the GHG emissions with just 25% of green energy sources. I. INTRODUCTION]. In the zero carbon approach, renewable (green) energy sources (e.g. sun, wind, tide) are employed and no GHGs

  16. The origins and concentrations of water, carbon, nitrogen and noble gases on Earth

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    1 The origins and concentrations of water, carbon, nitrogen and noble gases on Earth Bernard Marty (PSN) are still present in the mantle, presumably signing the sequestration of PSN gas at an early), and up to ~500 ppm C, both largely sequestrated in the solid Earth. This volatile content is equivalent

  17. Influence of Induced Interactions on the Superfluid Transition in Dilute Fermi Gases

    E-Print Network [OSTI]

    H. Heiselberg; C. J. Pethick; H. Smith; L. Viverit

    2000-04-20

    We calculate the effects of induced interactions on the transition temperature to the BCS state in dilute Fermi gases. For a pure Fermi system with 2 species having equal densities, the transition temperature is suppressed by a factor $(4e)^{1/3}\\approx 2.2$, and for $\

  18. Future climate change in the Southern Hemisphere: Competing effects of ozone and greenhouse gases

    E-Print Network [OSTI]

    Arblaster, Julie

    Future climate change in the Southern Hemisphere: Competing effects of ozone and greenhouse gases J 2010; accepted 19 October 2010; published 19 January 2011. [1] Future anthropogenic climate change simulations. Citation: Arblaster, J. M., G. A. Meehl, and D. J. Karoly (2011), Future climate change

  19. LETTER doi:10.1038/nature10176 Increased soil emissions of potent greenhouse gases

    E-Print Network [OSTI]

    Osenberg, Craig W.

    , such as microbial activity and water content1,2 . In turn, these changes might be expected to alter the production and consumption of the important greenhouse gases nitrous oxide (N2O) and methane (CH4) (refs 2, 3). However, these emissions are expected to negate at least 16.6 per cent of the climate change miti- gation potential

  20. Electronic structure of the Si(111):GaSe van der Waals-like surface termination

    E-Print Network [OSTI]

    Olmstead, Marjorie

    Electronic structure of the Si(111):GaSe van der Waals-like surface termination Reiner Rudolph-like surface termination has been determined by angle-resolved photoelectron spectroscopy using photons. This explains both the absence of a surface core-level shift in Si 2p photoelectron spectra of the terminated

  1. Documentation for Emissions of Greenhouse Gases in the United States 2008

    Reports and Publications (EIA)

    2011-01-01

    The Energy Policy Act of 1992 required the U.S. Energy Information Administration (EIA) to prepare an inventory of aggregate U.S. national emissions of greenhouse gases for the period 1987-1990, with annual updates thereafter. This report documents the methodology for the seventeenth annual inventory, covering national emissions over the period 1990-2008.

  2. Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials

    E-Print Network [OSTI]

    Stillinger, Frank

    Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials of wave vectors; and iii "equi-luminous" materials, which scatter radiation equally intensely of many-particle systems--the zero-temperature particle ar- rangement that minimizes potential energy per

  3. Predictive Modeling of Mercury Speciation in Combustion Flue Gases Using GMDH-Based Abductive Networks

    E-Print Network [OSTI]

    Abdel-Aal, Radwan E.

    and boiler operating conditions. Prediction performance compares favourably with neural network models for future work to further improve performance. Index Terms: Mercury speciation, Flue gases, Boiler emissions activities are coal-fired electric utility boilers, where speciation depends on the operating conditions

  4. Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells

    E-Print Network [OSTI]

    Stockie, John

    Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells M.J. Kermani1 J and N2, through the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically) an energy equation, written in a form that has enthalpy as the dependent variable. Keywords: PEM fuel cells

  5. The sulfur content of volcanic gases on Mars Fabrice Gaillard, a

    E-Print Network [OSTI]

    Boyer, Edmond

    The sulfur content of volcanic gases on Mars Fabrice Gaillard, a and Bruno Scaillet1, a a CNRS sulfur contents of the martian regolith and lack of detection of extensive carbonate deposits suggest that the latest geological events that shaped the landscapes of Mars were dominated by acidic waters possibly

  6. Plasmon mass and Drude weight in strongly spin-orbit-coupled two-dimensional electron gases

    E-Print Network [OSTI]

    Agarwal, Amit; Chesi, Stefano; Jungwirth, T.; Sinova, Jairo; Vignale, G.; Polini, Marco.

    2011-01-01

    -coupled 2D electron and hole gases, which are promising candidates for semiconductor spintronics,1 (ii) graphene2 (a monolayer of carbon atoms arranged in a 2D honeycomb lattice), which has attracted a great deal of interest because of the massless...

  7. Survey and assessment of the effects of nonconventional gases on gas distribution equipment

    SciTech Connect (OSTI)

    Jasionowski, W.J.; Scott, M.I.; Gracey, W.C.

    1982-10-01

    A literature search and a survey of the gas industry were conducted to assess potential problems in the distribution of nonconventional gases. Available literature did not uncover data that would describe potential problems or substantiate the presence of harmful trace elements in final gas compositions produced from various SNG processes. Information from the survey indicates that some companies have encountered problems with nonconventional gases and extraneous additives such as landfill gas, refinery off-gases, oil gas, carbureted water gas, coke-oven gas, propane-air, and compressor lubricant oils. These nonconventional gases and compressor oils may 1) cause pipeline corrosion, 2) degrade some elastomeric materials and greases and affect the integrity of seals, gaskets, O-rings, and meter and regulator diaphragms, and 3) cause operational and safety problems. The survey indicated that 62% of the responding companies plan to use supplemental gas, with most planning on more than one type. Distribution companies intend to significantly increase their use of polyethylene piping from 11.6% in 1980 to 22.4% in 2000 for gas mains and from 33.4% to 50.3% in 2000 for gas service lines.

  8. Noble gases identify the mechanisms of fugitive gas contamination in drinking-water wells overlying the

    E-Print Network [OSTI]

    Jackson, Robert B.

    Noble gases identify the mechanisms of fugitive gas contamination in drinking-water wells overlying 12, 2014 (received for review November 27, 2013) Horizontal drilling and hydraulic fracturing have and economic sustainability of shale-gas extraction. We analyzed 113 and 20 samples from drinking-water wells

  9. H-Theorems in some kinetic models of chemically reacting dense gases

    E-Print Network [OSTI]

    Polewczak, Jacek

    gases: search for the RET (Revised Enskog Theory) analog's of the reacting hard-sphere system H as perturbations to the non-reactive terms. This was confirmed in a series of papers by B.Shizgal and M.Karplus (J by an equilibrium computations, where solvent effects enter through the free energy at the transition state. (for

  10. Space Science: Atmospheres Evolution of planets

    E-Print Network [OSTI]

    Johnson, Robert E.

    ;Atmospheres / Evolution Heat Sources Compressional Energy Trapped Radioactive Material Tidal InteractionsSpace Science: Atmospheres Part- 7a Evolution of planets Out-Gassing/ Volcanoes Evolution Initial Species Solar abundance Solar wind composition? Carbonaceous chondrites? Variables Early sun

  11. ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2012)

    E-Print Network [OSTI]

    Gerber, Edwin

    2012-01-01

    ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2012) Published online in Wiley Online Library using National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP) concentrations and sea- surface temperatures (SSTs). These integrations enable the relative role of ozone

  12. Equilibration of an atmosphere by geostrophic turbulence

    E-Print Network [OSTI]

    Jansen, Malte F. (Malte Friedrich)

    2013-01-01

    A major question for climate studies is to quantify the role of turbulent eddy fluxes in maintaining the observed atmospheric mean state. It has been argued that eddy fluxes keep the mid-latitude atmosphere in a state that ...

  13. Land and Atmospheric Science GRAD STUDENT HANDBOOK

    E-Print Network [OSTI]

    Minnesota, University of

    Land and Atmospheric Science GRAD STUDENT HANDBOOK 20142015 WELCOME Welcome to the Graduate Program in Land and Atmospheric Science at the University of Minnesota. It is a sciencebased interdisciplinary program focused on the fundamentals of Earth system processes related

  14. On the Cool Side: Modeling the Atmospheres of Brown Dwarfs and Giant Planets

    E-Print Network [OSTI]

    Marley, Mark S

    2014-01-01

    The atmosphere of a brown dwarf or extrasolar giant planet controls the spectrum of radiation emitted by the object and regulates its cooling over time. While the study of these atmospheres has been informed by decades of experience modeling stellar and planetary atmospheres, the distinctive characteristics of these objects present unique challenges to forward modeling. In particular, complex chemistry arising from molecule-rich atmospheres, molecular opacity line lists (sometimes running to 10 billion absorption lines or more) multiple cloud-forming condensates, and disequilibrium chemical processes all combine to create a challenging task for any modeling effort. This review describes the process of incorporating these complexities into one-dimensional radiative-convective equilibrium models of sub-stellar objects. We discuss the underlying mathematics as well as the techniques used to model the physics, chemistry, radiative transfer, and other processes relevant to understanding these atmospheres. The revi...

  15. Radar range measurements in the atmosphere.

    SciTech Connect (OSTI)

    Doerry, Armin Walter

    2013-02-01

    The earth's atmosphere affects the velocity of propagation of microwave signals. This imparts a range error to radar range measurements that assume the typical simplistic model for propagation velocity. This range error is a function of atmospheric constituents, such as water vapor, as well as the geometry of the radar data collection, notably altitude and range. Models are presented for calculating atmospheric effects on radar range measurements, and compared against more elaborate atmospheric models.

  16. Earth and Atmospheric Sciences | More Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth and Atmospheric Sciences Nuclear Forensics Climate & Environment Sensors and Measurements Chemical & Engineering Materials Computational Earth Science Systems Modeling...

  17. Atmospheric-pressure plasma jet

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1999-01-01

    Atmospheric-pressure plasma jet. A .gamma.-mode, resonant-cavity plasma discharge that can be operated at atmospheric pressure and near room temperature using 13.56 MHz rf power is described. Unlike plasma torches, the discharge produces a gas-phase effluent no hotter than 250.degree. C. at an applied power of about 300 W, and shows distinct non-thermal characteristics. In the simplest design, two concentric cylindrical electrodes are employed to generate a plasma in the annular region therebetween. A "jet" of long-lived metastable and reactive species that are capable of rapidly cleaning or etching metals and other materials is generated which extends up to 8 in. beyond the open end of the electrodes. Films and coatings may also be removed by these species. Arcing is prevented in the apparatus by using gas mixtures containing He, which limits ionization, by using high flow velocities, and by properly shaping the rf-powered electrode. Because of the atmospheric pressure operation, no ions survive for a sufficiently long distance beyond the active plasma discharge to bombard a workpiece, unlike low-pressure plasma sources and conventional plasma processing methods.

  18. Atmospheric Dispersion Effects in Weak Lensing Measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plazas, Andrs Alejandro; Bernstein, Gary

    2012-10-01

    The wavelength dependence of atmospheric refraction causes elongation of finite-bandwidth images along the elevation vector, which produces spurious signals in weak gravitational lensing shear measurements unless this atmospheric dispersion is calibrated and removed to high precision. Because astrometric solutions and PSF characteristics are typically calibrated from stellar images, differences between the reference stars' spectra and the galaxies' spectra will leave residual errors in both the astrometric positions (dr) and in the second moment (width) of the wavelength-averaged PSF (dv) for galaxies.We estimate the level of dv that will induce spurious weak lensing signals in PSF-corrected galaxy shapes that exceed themorestatistical errors of the DES and the LSST cosmic-shear experiments. We also estimate the dr signals that will produce unacceptable spurious distortions after stacking of exposures taken at different airmasses and hour angles. We also calculate the errors in the griz bands, and find that dispersion systematics, uncorrected, are up to 6 and 2 times larger in g and r bands,respectively, than the requirements for the DES error budget, but can be safely ignored in i and z bands. For the LSST requirements, the factors are about 30, 10, and 3 in g, r, and i bands,respectively. We find that a simple correction linear in galaxy color is accurate enough to reduce dispersion shear systematics to insignificant levels in the r band for DES and i band for LSST,but still as much as 5 times than the requirements for LSST r-band observations. More complex corrections will likely be able to reduce the systematic cosmic-shear errors below statistical errors for LSST r band. But g-band effects remain large enough that it seems likely that induced systematics will dominate the statistical errors of both surveys, and cosmic-shear measurements should rely on the redder bands.less

  19. Atmospheric Dispersion Effects in Weak Lensing Measurements

    SciTech Connect (OSTI)

    Plazas, Andrs Alejandro; Bernstein, Gary

    2012-10-01

    The wavelength dependence of atmospheric refraction causes elongation of finite-bandwidth images along the elevation vector, which produces spurious signals in weak gravitational lensing shear measurements unless this atmospheric dispersion is calibrated and removed to high precision. Because astrometric solutions and PSF characteristics are typically calibrated from stellar images, differences between the reference stars' spectra and the galaxies' spectra will leave residual errors in both the astrometric positions (dr) and in the second moment (width) of the wavelength-averaged PSF (dv) for galaxies.We estimate the level of dv that will induce spurious weak lensing signals in PSF-corrected galaxy shapes that exceed the statistical errors of the DES and the LSST cosmic-shear experiments. We also estimate the dr signals that will produce unacceptable spurious distortions after stacking of exposures taken at different airmasses and hour angles. We also calculate the errors in the griz bands, and find that dispersion systematics, uncorrected, are up to 6 and 2 times larger in g and r bands,respectively, than the requirements for the DES error budget, but can be safely ignored in i and z bands. For the LSST requirements, the factors are about 30, 10, and 3 in g, r, and i bands,respectively. We find that a simple correction linear in galaxy color is accurate enough to reduce dispersion shear systematics to insignificant levels in the r band for DES and i band for LSST,but still as much as 5 times than the requirements for LSST r-band observations. More complex corrections will likely be able to reduce the systematic cosmic-shear errors below statistical errors for LSST r band. But g-band effects remain large enough that it seems likely that induced systematics will dominate the statistical errors of both surveys, and cosmic-shear measurements should rely on the redder bands.

  20. Comment on "Radiative forcings for 28 potential Archean greenhouse gases" by Byrne and Goldblatt (2014)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kochanov, R. V.; Gordon, I. E.; Rothman, L. S.; Sharpe, S. W.; Johnson, T. J.; Sams, R. L.

    2015-08-25

    In the recent article by Byrne and Goldblatt, "Radiative forcing for 28 potential Archean greenhouse gases", Clim. Past. 10, 17791801 (2014), the authors employ the HITRAN2012 spectroscopic database to evaluate the radiative forcing of 28 Archean gases. As part of the evaluation of the status of the spectroscopy of these gases in the selected spectral region (501800 cm-1), the cross sections generated from the HITRAN line-by-line parameters were compared with those of the PNNL database of experimental cross sections recorded at moderate resolution. The authors claimed that for NO2, HNO3, H2CO, H2O2, HCOOH, C2H4, CH3OH and CH3Br there exist largemoreor sometimes severe disagreements between the databases. In this work we show that for only three of these eight gases a modest discrepancy does exist between the two databases and we explain the origin of the differences. For the other five gases, the disagreements are not nearly at the scale suggested by the authors, while we explain some of the differences that do exist. In summary, the agreement between the HITRAN and PNNL databases is very good, although not perfect. Typically differences do not exceed 10 %, provided that HITRAN data exist for the bands/wavelengths of interest. It appears that a molecule-dependent combination of errors has affected the conclusions of the authors. In at least one case it appears that they did not take the correct file from PNNL (N2O4 (dimer)+ NO2 was used in place of the monomer). Finally, cross sections of HO2 from HITRAN (which do not have a PNNL counterpart) were not calculated correctly in BG, while in the case of HF misleading discussion was presented there based on the confusion by foreign or noise features in the experimental PNNL spectra.less

  1. A Recognized Leader in Marine & Atmospheric

    E-Print Network [OSTI]

    Miami, University of

    D/Masters Applied Marine Physics Marine & Atmospheric Chemistry Marine Affairs & Policy (Masters Only) MarineA Recognized Leader in Marine & Atmospheric Studies Our graduate program has over 250 students University of MiaMi rosenstiel school of Marine & atMospheric science #12;Miami Ranks #5: fDi Magazine's Top

  2. Atmospheric evolution on Venus Bruce Fegley, Jr.

    E-Print Network [OSTI]

    1 Atmospheric evolution on Venus Bruce Fegley, Jr. Planetary Chemistry Laboratory Department by Hunten et al. (1983), of Magellan results by Bougher et al. (1997), and atmospheric chemistry on Venus and Ancient Environments Edited by Vivien Gornitz January 2004 #12;2 ATMOSPHERIC EVOLUTION ON VENUS Overview

  3. Atmospheric Lifetime of Fossil Fuel Carbon Dioxide

    E-Print Network [OSTI]

    Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

  4. Proof of the Atmospheric Greenhouse Effect

    E-Print Network [OSTI]

    Smith, Arthur P

    2008-01-01

    A recently advanced argument against the atmospheric greenhouse effect is refuted. A planet without an infrared absorbing atmosphere is mathematically constrained to have an average temperature less than or equal to the effective radiating temperature. Observed parameters for Earth prove that without infrared absorption by the atmosphere, the average temperature of Earth's surface would be at least 33 K lower than what is observed.

  5. Atmospheric composition change - global and regional air quality

    E-Print Network [OSTI]

    2009-01-01

    in urban air. Atmospheric Chemistry and Physics 5, 2881deep convective system. Atmospheric Chemistry and Physics 4,processes in atmospheric chemistry. Chemical Society Review

  6. Coupling of nitrous oxide and methane by global atmospheric chemistry

    E-Print Network [OSTI]

    Prather, MJ; Hsu, J

    2010-01-01

    supported by NSFs Atmospheric Chemistry program (grant ATM-Methane by Global Atmospheric Chemistry Michael J. Prathergas, through atmospheric chemistry that en- hances the

  7. Formation mechanisms and quantification of organic nitrates in atmospheric aerosol

    E-Print Network [OSTI]

    Rollins, Andrew Waite

    2010-01-01

    and J. Viidanoja, Atmospheric chemistry of c 3 -c 6organic nitrates, Atmospheric Chemistry and Physics, 9 (4),organic aerosol yields, Atmospheric Chemistry and Physics

  8. 1997 Atmospheric Chemistry Colloquium for Emerging Senior Scientists

    SciTech Connect (OSTI)

    Paul H. Wine

    1998-11-23

    DOE's Atmospheric Chemistry Program is providing partial funding for the Atmospheric Chemistry Colloquium for Emerging Senior Scientists (ACCESS) and FY 1997 Gordon Research Conference in Atmospheric Chemistry

  9. Operating experience review of an INL gas monitoring system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cadwallader, Lee C.; DeWall, K. G.; Herring, J. S.

    2015-03-01

    This article describes the operations of several types of gas monitors in use at the Idaho National Laboratory (INL) High Temperature Electrolysis Experiment (HTE) laboratory. The gases monitored in the lab room are hydrogen, carbon monoxide, carbon dioxide, and oxygen. The operating time, calibration, and both actual and unwanted alarms are described. The calibration session time durations are described. Some simple calculations are given to estimate the reliability of these monitors and the results are compared to operating experiences of other types of monitors.

  10. Development of Atmospheric Monitoring System at Akeno Observatory for the Telescope Array Project

    E-Print Network [OSTI]

    T. Yamamoto; M. Teshima; M. Chikawa; N. Hayashida; S. Kawakami; N. Minagawa; Y. Morizane; M. Sasano; K. Yasui

    2002-08-09

    We have developed an atmospheric monitoring system for the Telescope Array experiment at Akeno Observatory. It consists of a Nd:YAG laser with an alt-azimuth shooting system and a small light receiver. This system is installed inside an air conditioned weather-proof dome. All parts, including the dome, laser, shooter, receiver, and optical devices are fully controlled by a personal computer utilizing the Linux operating system. It is now operated as a back-scattering LIDAR System. For the Telescope Array experiment, to estimate energy reliably and to obtain the correct shower development profile, the light transmittance in the atmosphere needs to be calibrated with high accuracy. Based on observational results using this monitoring system, we consider this LIDAR to be a very powerful technique for Telescope Array experiments. The details of this system and its atmospheric monitoring technique will be discussed.

  11. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Design and Engineering of most components in the Pulsed Atmospheric Fluidized Bed System was completed prior to September 1992. The components remaining to be designed at that time were: Aerovalves for the Pulse Combustor; Gas and coal injectors for the Pulse Combustor; Lines for PC tailpipes; Air plenum and inlet silencer; Refractory lined hot gas duct connecting outlet hot cyclone to boiler; Structure and platforms, and ladders around PAFBC vessel access and major equipment. Design work is currently in progress on all of the above components. Items 1, 2, 3 and 4 are 50% completed, and items 5 6 are 75% complete.

  12. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  13. Natalie Marie Mahowald Department of Earth and Atmospheric Sciences

    E-Print Network [OSTI]

    Mahowald, Natalie

    in the Community Atmosphere Model: development of framework and impact on radiative forcing, Atmospheric Chemistry, Atmospheric Chemistry and 1 1 Natalie Marie Mahowald Department of Earth and Atmospheric Sciences Professor Director

  14. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3and SO2

    E-Print Network [OSTI]

    2010-01-01

    gases measured over Alberta oil sands mining operationsand Lee, P. : Does the Alberta tar sands industry pollute?gases measured over Alberta oil sands mining operations: 76

  15. Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets

    SciTech Connect (OSTI)

    Davis, K.J.; Richardson, S.J.; Miles, N.L.

    2007-03-07

    Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2?3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute are captured. Influence functions, derived using a Lagrangian Particle Dispersion model driven by the CSU Regional Atmospheric Modeling System and nudged to NCEP reanalysis meteorological fields, are used to determine source regions for the towers. The influence functions are combined with satellite vegetation observations to interpret the observed trends in CO2 concentration. Full inversions will combine these elements in a more formal analytic framework.

  16. Effect of global warming and increases in atmospheric [CO{sub 2}] on water stress in soybeans during critical reproductive stages: A regional study of Iowa

    SciTech Connect (OSTI)

    Haskett, J.D.; Pachepsky, Y.A.; Acock, B.

    1997-12-31

    The anthropogenic increase in radiatively active gases in the atmosphere has been well documented. Recently the impact of this increase on the earth`s climate has been confirmed. Agriculture is vulnerable to climatic change, and estimating the likely response to such changes is critical. Many studies of these responses have included soybeans both because they are an important commodity and because they are sensitive to changes in atmospheric CO, concentration. Such studies have generally focused on yield response. While this is critical it does not provide information on the underlying causal link between climate and atmospheric change and changes in soybean yield. The current work examines the impact of climatic change on water stress during the critical periods of soybean reproductive development.

  17. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

    1998-01-01

    Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

  18. Travelling waves in a mixture of gases with bimolecular reversible reactions

    E-Print Network [OSTI]

    A. Rossani; A. M. Scarfone

    2003-12-01

    Starting from the kinetic approach for a mixture of reacting gases whose particles interact through elastic scattering and a bimolecular reversible chemical reaction, the equations that govern the dynamics of the system are obtained by means of the relevant Boltzmann-like equation. Conservation laws are considered. Fluid dynamic approximations are used at the Euler level to obtain a close set of PDEs for six unknown macroscopic fields. The dispersion relation of the mixture of reacting gases is explicitly derived in the homogeneous equilibrium state. A set of ODE that governs the propagation of a plane travelling wave is obtained using the Galilei invariance. After numerical integration some solutions, including the well-known Maxwellian and the hard spheres cases, are found for various meaningful interaction laws. The main macroscopic observables for the gas mixture such as the drift velocity, temperature, total density, pressure and its chemical composition are shown.

  19. Free cooling and high-energy tails of granular gases with variable restitution coefficient

    E-Print Network [OSTI]

    Ricardo J. Alonso; Bertrand Lods

    2010-05-31

    We prove the so-called generalized Haff's law yielding the optimal algebraic cooling rate of the temperature of a granular gas described by the homogeneous Boltzmann equation for inelastic interactions with non constant restitution coefficient. Our analysis is carried through a careful study of the infinite system of moments of the solution to the Boltzmann equation for granular gases and precise Lp estimates in the selfsimilar variables. In the process, we generalize several results on the Boltzmann collision operator obtained recently for homogeneous granular gases with constant restitution coefficient to a broader class of physical restitution coefficients that depend on the collision impact velocity. This generalization leads to the so-called L1-exponential tails theorem. for this model.

  20. Non-equilibrium electron transport in gases: Influence of magnetic fields on temporal and spatial relaxation

    SciTech Connect (OSTI)

    White, R. D.; Dujko, S.; Ness, K. F. [School of Mathematics, Physics and IT, James Cook University, Townsville, QLD (Australia); Li, B. [School of Physics, University of Sydney, NSW 2006 (Australia); Robson, R. E. [Research School of Physical Sciences, Australian National University, ACT 2600 (Australia); School of Mathematics, Physics and IT, James Cook University, Townsville, QLD (Australia)

    2006-12-01

    The ability to control the temporal and spatial relaxation of electron swarms in gases through application of an orthogonal magnetic field is examined via solutions of Boltzmann's equation. Multi-term solutions of Boltzmann's equation are presented for two specific applications: temporal relaxation in the time-dependent hydrodynamic regime, and spatial relaxation in the steady state non-hydrodynamic regime. We highlight the commonality of methods and techniques for handling the velocity dependence of the phase-space distribution function as well as their point of departure for treating the spatial dependence. We present results for model and real gases highlighting the explicit influence of the magnetic field on spatial and temporal relaxation characteristics, including the existence of transiently negative diffusion coefficients.

  1. Membranes, methods of making membranes, and methods of separating gases using membranes

    DOE Patents [OSTI]

    Ho, W. S. Winston

    2012-10-02

    Membranes, methods of making membranes, and methods of separating gases using membranes are provided. The membranes can include at least one hydrophilic polymer, at least one cross-linking agent, at least one base, and at least one amino compound. The methods of separating gases using membranes can include contacting a gas stream containing at least one of CO.sub.2, H.sub.2S, and HCl with one side of a nonporous and at least one of CO.sub.2, H.sub.2S, and HCl selectively permeable membrane such that at least one of CO.sub.2, H.sub.2S, and HCl is selectively transported through the membrane.

  2. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

    1998-01-13

    Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor. 2 figs.

  3. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

    1985-01-01

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  4. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C.J.; Mackenzie, P.D.

    1982-09-03

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  5. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, J.L.

    1998-09-15

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

  6. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    1998-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  7. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01

    budget of atmospheric carbonyl sulfide: Temporal and spatialyear atmospheric history for carbonyl sulfide inferred fromterm measurement record of carbonyl sulfide (COS) in two

  8. Paint coatings: Controlled field and chamber experiments

    SciTech Connect (OSTI)

    Edney, E.O.

    1989-04-01

    To determine the impact of pollution levels on the weathering rates of coatings, laboratory chamber experiments and controlled field exposures at North Carolina and Ohio sites were conducted in such a manner to separate the contributions due to dry deposition, wet deposition, precipitation pH, etc. The results of these studies confirm that acidic gases such as SO/sub 2/ and HNO/sub 3/, as well as acids within rain, promote the dissolution of alkaline components including CaCO/sub 3/, ZnO, and Al flake from paint films. It is unclear from these studies whether the removal of these components reduces the service life or protective properties of the paint film. Other researchers within the Coatings Effects Program are conducting subsequent analyses to determine micro-damage of these paints. The uptake of acidic gases to painted surfaces is a complex process that depends on several factors. The deposition rate of SO/sub 2/ to a wet, painted surface may be controlled by the level of oxidants such as H/sub 2/O/sub 2/.

  9. Temperature jump in degenerate quantum gases in the presence of a Bose - Einstein condensate

    E-Print Network [OSTI]

    A. V. Latyshev; A. A. Yushkanov

    2010-01-04

    We construct a kinetic equation modeling the behavior of degenerate quantum Bose gases whose collision rate depends on the momentum of elementary excitations. We consider the case where the phonon component is the decisive factor in the elementary excitations. We analytically solve the half-space boundary value problem of the temperature jump at the boundary of the degenerate Bose gas in the presence of a Bose -- Einstein condensate.

  10. MRI of the lung gas-space at very low-field using hyperpolarized noble gases

    E-Print Network [OSTI]

    MRI of the lung gas-space at very low-field using hyperpolarized noble gases Arvind K. Venkatesha such as in the lungs. In HP gas MRI the signal-to-noise ratio (SNR) depends only weakly on the static magnetic field (B of the lungs in humans and in rats, obtained at a field of only 15 millitesla (150 Gauss). 2003 Elsevier Inc

  11. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  12. One-dimensional ultracold atomic gases: impact of the effective range on integrability

    E-Print Network [OSTI]

    Tom Kristensen; Ludovic Pricoupenko

    2015-06-12

    The one-dimensional one-component Bose and Fermi gases are considered in a regime of large effective range. We focus our study on the three-body problem, which is at the heart of the integra-bility issue. For fermions, the vicinity of the integrability is characterized by large deviations with respect to the predictions of the Bethe ansatz. For the consistency of the contact model, it appears essential to take into account the contact of three particles.

  13. Greenhouse Gases, Regulated Emissions, and Energy use in Transportation (GREET) Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits the Bill Financing Tool Fits27,Network Newsletter Green PowerGreenhouse Gases,

  14. Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause-Based Climatology and Optimal Estimation Approach

    E-Print Network [OSTI]

    Pan, Laura

    Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause for retrieving atmospheric ozone profile information from advanced satellite infrared sounders, this study investigates various methods to optimize ozone retrievals. A set of retrieval experiments has been performed

  15. Apparatus and method for atmospheric pressure reactive atom plasma processing for shaping of damage free surfaces

    DOE Patents [OSTI]

    Carr; Jeffrey W. (Livermore, CA)

    2009-03-31

    Fabrication apparatus and methods are disclosed for shaping and finishing difficult materials with no subsurface damage. The apparatus and methods use an atmospheric pressure mixed gas plasma discharge as a sub-aperture polisher of, for example, fused silica and single crystal silicon, silicon carbide and other materials. In one example, workpiece material is removed at the atomic level through reaction with fluorine atoms. In this example, these reactive species are produced by a noble gas plasma from trace constituent fluorocarbons or other fluorine containing gases added to the host argon matrix. The products of the reaction are gas phase compounds that flow from the surface of the workpiece, exposing fresh material to the etchant without condensation and redeposition on the newly created surface. The discharge provides a stable and predictable distribution of reactive species permitting the generation of a predetermined surface by translating the plasma across the workpiece along a calculated path.

  16. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect (OSTI)

    1995-09-25

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  17. The Spectral Backbone of Excitation Transport in Ultra-Cold Rydberg Gases

    E-Print Network [OSTI]

    Torsten Scholak; Thomas Wellens; Andreas Buchleitner

    2014-11-26

    The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly distributed, highly polarizable atoms that interact via strong dipolar forces. Dynamics in such a system is fundamentally different from cases in which the interactions are of short range, and is ultimately determined by the spectral and eigenvector structure. In the energy levels' spacing statistics, we find evidence for a critical energy that separates delocalized eigenstates from states that are localized at pairs or clusters of atoms separated by less than the typical nearest-neighbor distance. We argue that the dipole blockade effect in Rydberg gases can be leveraged to manipulate this transition across a wide range: As the blockade radius increases, the relative weight of localized states is reduced. At the same time, the spectral statistics -- in particular, the density of states and the nearest neighbor level spacing statistics -- exhibits a transition from approximately a 1-stable L\\'evy to a Gaussian orthogonal ensemble. Deviations from random matrix statistics are shown to stem from correlations between interatomic interaction strengths that lead to an asymmetry of the spectral density and profoundly affect localization properties. We discuss approximations to the self-consistent Matsubara-Toyozawa locator expansion that incorporate these effects.

  18. High-Pressure Phase Equilibria of Ionic Liquids and Compressed Gases for Applications in Reactions and Absorption Refrigeration

    E-Print Network [OSTI]

    Ren, Wei

    2009-12-29

    properties, especially their lack of volatility. However, using ionic liquids over common organic solvents has several challenges, i.e., higher viscosity (lower diffusivity) than common organic solvents; lower solubility of reaction gases and large number...

  19. Accuracy of truncated Leiden and Berlin virial expansions for pure gases and sealing joints between silicon carbide and stainless steel

    E-Print Network [OSTI]

    Santana Rodriguez, Gabriel Enrique

    2003-01-01

    Pure gases such as methane, carbon dioxide and steam were used to make comparisons between Leiden and Berlin virial expansions for the calculation of the compressibility factor, fugacity coefficient and enthalpy residual. ...

  20. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    The design of the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) as described in the Quarterly Report for the period April--June, 1992 was reviewed and minor modifications were included. The most important change made was in the coal/limestone preparation and feed system. Instead of procuring pre-sized coal for testing of the PAFBC, it was decided that the installation of a milling system would permit greater flexibility in the testing with respect to size distributions and combustion characteristics in the pulse combustor and the fluid bed. Particle size separation for pulse combustor and fluid bed will be performed by an air classifier. The modified process flow diagram for the coal/limestone handling system is presented in Figure 1. The modified process flow diagrams of the fluidized bed/steam cycle and ash handling systems are presented in Figures 2 and 3, respectively.

  1. Mesoscale coupled ocean-atmosphere interaction

    E-Print Network [OSTI]

    Seo, Hyodae

    2007-01-01

    mesoscale oceanic features are current coarse resolutionmesoscale r current variability associated with oceanic ringthe TIW- currents. These mesoscale oceanic and atmospheric

  2. Mesoscale Coupled Ocean-Atmosphere Interaction

    E-Print Network [OSTI]

    Seo, Hyodae

    2007-01-01

    mesoscale oceanic features are current coarse resolutionmesoscale r current variability associated with oceanic ringthe TIW- currents. These mesoscale oceanic and atmospheric

  3. 4, 497545, 2011 atmosphere-wildland

    E-Print Network [OSTI]

    Mandel, Jan

    by the coupling of a mesoscale weather 498 #12;GMDD 4, 497545, 2011 Coupled atmosphere-wildland model WRF-Fire 3

  4. Impacts of Atmospheric Anthropogenic Nitrogen on the

    E-Print Network [OSTI]

    Ward, Bess

    discharges from wastewater treatment, atmospheric deposition, and so forth, resulting in increasing), including oxidized and reduced inorganic and organic forms. The availability of Nr limits primary pro

  5. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth...

  6. Atmospheric chemistry of an Antarctic volcanic plume

    E-Print Network [OSTI]

    2010-01-01

    ET AL. : EREBUS PLUME CHEMISTRY Horrocks, L. A. , C.et al. (2010), Atmospheric chemistry results from the ANTCI2007), Reactive halogen chemistry in volca- nic plumes, J.

  7. Ranking low cost sorbents for mercury capture from simulated flue gases

    SciTech Connect (OSTI)

    H. Revata Seneviratne; Cedric Charpenteau; Anthe George; Marcos Millan; Denis R. Dugwell; Rafael Kandiyoti

    2007-12-15

    Coal fired utility boilers are the largest anthropogenic source of mercury release to the atmosphere, and mercury abatement legislation is already in place in the USA. The present study aimed to rank low cost mercury sorbents (char and activated carbon from the pyrolysis of scrap tire rubber and two coal fly ashes from UK power plants) against Norit Darco HgTM for mercury retention by using a novel bench-scale reactor. In this scheme, a fixed sorbent bed was tested for mercury capture efficiency from a simulated flue gas stream. Experiments with a gas stream of only mercury and nitrogen showed that while the coal ashes were the most effective in mercury capture, char from the pyrolysis of scrap tire rubber was as effective as the commercial sorbent Norit Darco HgTM. Tests conducted at 150{sup o}C, with a simulated flue gas mix that included N{sub 2}, NO, NO{sub 2}, CO{sub 2}, O{sub 2}, SO{sub 2} and HCl, showed that all the sorbents captured approximately 100% of the mercury in the gas stream. The introduction of NO and NO{sub 2} was found to significantly improve the mercury capture, possibly by reactions between NOx and the mercury. Since the sorbents' efficiency decreased with increasing test temperature, physical sorption could be the initial step in the mercury capture process. As the sorbents were only exposed to 64 ng of mercury in the gas stream, the mercury loadings on the samples were significantly less than their equilibrium capacities. The larger capacities of the activated carbons due to their more microporous structure were therefore not utilized. Although the sorbents have been characterized by BET surface area analysis and XRD analysis, further analysis is needed in order to obtain a more conclusive correlation of how the characteristics of the different sorbents correlate with the observed variations in mercury capture ability. 34 refs., 8 figs., 6 tabs.

  8. Motion characteristics of long ac arcs in atmospheric air

    SciTech Connect (OSTI)

    Gu Shanqiang; He Jinliang; Zeng Rong; Zhang Bo; Xu Guozheng; Chen Weijiang

    2007-01-29

    Experiments on the motion of long alternating current arcs in atmospheric air show that the anode and cathode arc roots have different motion characteristics because of different formation mechanisms. During a half cycle of the arc current, the anode arc root moves towards the direction of magnetic force and occasionally has a jumping motion, while the cathode arc root moves sufficiently slow to consider it stationary and hardly has any jump. The arc column has a complex shape and moves under the drive of the magnetic force and is also quickened by the lower arc root.

  9. Response of global soil consumption of atmospheric methane to changes in atmospheric climate and nitrogen deposition

    E-Print Network [OSTI]

    Zhuang, Qianlai

    Soil consumption of atmospheric methane plays an important secondary role in regulating the atmospheric CH4 budget, next to the dominant loss mechanism involving reaction with the hydroxyl radical (OH). Here we used a ...

  10. The impact of atmospheric aerosols on trace metal chemistry in open ocean surface seawater 3. Lead

    SciTech Connect (OSTI)

    Maring, H.B.; Duce, R.A. )

    1990-04-15

    Atmospheric aerosols collected at Enewetak Atoll in the tropical North Pacific were exposed to seawater in laboratory experiments to assess the impact of atmospheric aerosols on lead chemistry in surface seawater. The net atmospheric flux of soluble lead to the ocean is between 16 and 32 pmol cm{sup {minus}2}/yr at Enewetak. The stable lead isotopic composition of soluble aerosol lead indicates that it is of anthropogenic origin. Anthropogenic aerosol lead from Central and North America appears to be less soluble and/or to dissolve less rapidly than that from Asia. Dissolved organic matter and possibly lower pH appear to increase the nonaluminosilicate aerosol lead solubility and/or dissolution rate. The isotopic composition of lead in air, seawater and dry deposition suggests that after deposition in the ocean, nonaluminosilicate particulate lead can be reinjected into the atmosphere during sea salt aerosol production.

  11. Experience Report for WOPR

    SciTech Connect (OSTI)

    Pope, G

    2010-04-06

    One of the purposes of the SQA effort at LLNL is to attempt to determine the 'goodness' of the research codes used for various scientific applications. Typically these are two and three dimensional multi-physics simulation and modeling codes. These legacy research codes are used for applciations such as atmospheric dispersion modeling and analysis and prediction of the performance of engineered systems. These codes are continually subjected to automated regression test suites consisting of verified and validated expected results. Code is managed in repositories. Experience level of developers is high in the knowledge domain, platforms, and languages used. Code size of the multi-physics code used in this study was 578,242 lines excluding comment and blank lines or 5538.7 function points. Languages were 70% C++, 20% C, and 10% Fortran. The code has 130 users and a development team of 14 and an embedded SQE. The code has achieved 100% prime feature test coverage, 73.6% functional test coverage, and 71.5% statement test coverage. The average cyclomatic complexity of the code was 6.25. The codes have evolved over 10 years. Research codes are challenging because there is a desire to balance agility with discipline as well as compliance with DOE standards. Agility is important to allow experimentation with new algorithms and addition of the latest physics features. Discipline is important to increase the quality of the codes. Automation of processes and defect prevention/detection are deployed throughout the software development process. Since resarch codes are a small segment of the software industry, not much information exists in terms of reliability studies on these types of codes. This paper describes attempts to determine the goodness of these research codes. Goodness defined as both correctness of the codes and their fault densities. Correctness is determined by user interviews, peer review; feature based automated testing, and coverage measurement. This paper focuses on the fault density aspect of goodness and reliability of the codes in particular. The approach taken was to use multiple fault density prediction methods and compare results to actual experimentation and other industry studies on fault density. As a result of the predictions and experiments our confidence in the prediction methods was increased and our confidence in the goodness of the code from a fault density perspective was given more context. A large unintended benefit of these experiments was to find defects hidden for years in the codes when using the Monte Carlo reliability testing results to develop heuristic based bug driven tests.

  12. Cell model of in-cloud scavenging of highly soluble gases Alexander Baklanov a,b,n

    E-Print Network [OSTI]

    Elperin, Tov

    of fully online integrated atmospheric chemistry and meteorology models and Earth system models requires

  13. Experiment to Characterize Tropical Cloud Systems

    SciTech Connect (OSTI)

    May, Peter T.; Mather, Jim H.; Jakob, Christian

    2005-08-02

    A major experiment to study tropical convective cloud systems and their impacts will take place around Darwin, Northern Australia in early 2006. The Tropical Warm Pool International Cloud Experiment (TWP-ICE) is a collaboration including the DOE ARM (Atmospheric Radiation Measurement) and ARM-UAV programs, NASA centers, the Australian Bureau of Meteorology, CSIRO, and universities in the USA, Australia, Japan, the UK, and Canada. TWP-ICE will be preceded in November/December 2004 by a collaborating European aircraft campaign involving the EU SCOUT-O3 and UK NERC ACTIVE projects. Detailed atmospheric measurements will be made in the Darwin area through the whole Austral summer, giving unprecedented coverage through the pre-monsoon and monsoon periods.

  14. VOCALS: The VAMOS Ocean-Cloud-Atmosphere-Land Study

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wood, Robert [VOCALS-REx PI, University of Washington; Bretherton, Christopher [GEWEX/GCSS Representative, University of Washington; Huebert, Barry [SOLAS Representative, University of Hawaii; Mechoso, Roberto C. [VOCALS Science Working Group Chair, UCLA; Weller, Robert [Woods Hole Oceanographic Institution

    VOCALS (VAMOS* Ocean-Cloud-Atmosphere-Land Study) is an international CLIVAR program the major goal of which is to develop and promote scientific activities leading to improved understanding of the Southeast Pacific (SEP) coupled ocean-atmosphere-land system on diurnal to inter-annual timescales. The principal program objectives are: 1) the improved understanding and regional/global model representation of aerosol indirect effects over the SEP; 2) the elimination of systematic errors in the region of coupled atmospheric-ocean general circulation models, and improved model simulations and predictions of the coupled climate in the SEP and global impacts of the system variability. VOCALS is organized into two tightly coordinated components: 1) a Regional Experiment (VOCALSREx), and 2) a Modeling Program (VOCALS-Mod). Extended observations (e.g. IMET buoy, satellites, EPIC/PACS cruises) will provide important additional contextual datasets that help to link the field and the modeling components. The coordination through VOCALS of observational and modeling efforts (Fig. 3) will accelerate the rate at which field data can be used to improve simulations and predictions of the tropical climate variability [Copied from the Vocals Program Summary of June 2007, available as a link from the VOCALS web at http://www.eol.ucar.edu/projects/vocals/]. The CLIVAR sponsored program to under which VOCALS falls is VAMOS, which stands for Variability of the American Monsoon Systems.

  15. Atmosphere contamination following repainting of a human hyperbaric chamber complex

    SciTech Connect (OSTI)

    Lillo, R.S.; Morris, J.W.; Caldwell, J.M.; Balk, D.M.; Flynn, E.T. )

    1990-09-01

    The Naval Medical Research Institute currently conducts hyperbaric research in a Man-Rated Chamber Complex (MRCC) originally installed in 1977. Significant engineering alterations to the MRCC and rusting of some of its interior sections necessitated repainting, which was completed in 1988. Great care was taken in selecting an appropriate paint (polyamide epoxy) and in ensuring correct application and curing procedures. Only very low levels of hydrocarbons were found in the MRCC atmosphere before initial pressurization after painting and curing. After pressurization, however, significant chemical contamination was found. The primary contaminants were aromatic hydrocarbons: xylenes (which were a major component of both the primer and topcoat paint) and ethyl benzene. The role that pressure played in stimulating off-gassing from the paint is not clear; the off-gassing rate was observed to be similar over a large range in chamber pressures from 1.6 to 31.0 atm abs. Scrubbing the chamber atmosphere with the chemical absorbent Purafil was effective in removing the contaminants. Contamination has been observed to slowly decline with chamber use and is expected to continue to improve with time. However, this contamination experience emphasizes the need for a high precision gas analysis program at any diving facility to ensure the safety of the breathing gas and chamber atmosphere.

  16. EDDY RESOLVING NUTRIENT ECODYNAMICS IN THE GLOBAL PARALLEL OCEAN PROGRAM AND CONNECTIONS WITH TRACE GASES IN THE SULFUR, HALOGEN AND NMHC CYCLES

    SciTech Connect (OSTI)

    S. CHU; S. ELLIOTT

    2000-08-01

    Ecodynamics and the sea-air transfer of climate relevant trace gases are intimately coupled in the oceanic mixed layer. Ventilation of species such as dimethyl sulfide and methyl bromide constitutes a key linkage within the earth system. We are creating a research tool for the study of marine trace gas distributions by implementing coupled ecology-gas chemistry in the high resolution Parallel Ocean Program (POP). The fundamental circulation model is eddy resolving, with cell sizes averaging 0.15 degree (lat/long). Here we describe ecochemistry integration. Density dependent mortality and iron geochemistry have enhanced agreement with chlorophyll measurements. Indications are that dimethyl sulfide production rates must be adjusted for latitude dependence to match recent compilations. This may reflect the need for phytoplankton to conserve nitrogen by favoring sulfurous osmolytes. Global simulations are also available for carbonyl sulfide, the methyl halides and for nonmethane hydrocarbons. We discuss future applications including interaction with atmospheric chemistry models, high resolution biogeochemical snapshots and the study of open ocean fertilization.

  17. Study of dust particle charging in weakly ionized inert gases taking into account the nonlocality of the electron energy distribution function

    SciTech Connect (OSTI)

    Filippov, A. V. Dyatko, N. A.; Kostenko, A. S.

    2014-11-15

    The charging of dust particles in weakly ionized inert gases at atmospheric pressure has been investigated. The conditions under which the gas is ionized by an external source, a beam of fast electrons, are considered. The electron energy distribution function in argon, krypton, and xenon has been calculated for three rates of gas ionization by fast electrons: 10{sup 13}, 10{sup 14}, and 10{sup 15} cm{sup ?1}. A model of dust particle charging with allowance for the nonlocal formation of the electron energy distribution function in the region of strong plasma quasi-neutrality violation around the dust particle is described. The nonlocality is taken into account in an approximation where the distribution function is a function of only the total electron energy. Comparative calculations of the dust particle charge with and without allowance for the nonlocality of the electron energy distribution function have been performed. Allowance for the nonlocality is shown to lead to a noticeable increase in the dust particle charge due to the influence of the group of hot electrons from the tail of the distribution function. It has been established that the screening constant virtually coincides with the smallest screening constant determined according to the asymptotic theory of screening with the electron transport and recombination coefficients in an unperturbed plasma.

  18. ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2013)

    E-Print Network [OSTI]

    Lee, Sukyoung

    2013-01-01

    ATMOSPHERIC SCIENCE LETTERS Atmos. Sci. Let. (2013) Published online in Wiley Online Library Sciences, Seoul National University, Seoul, South Korea *Correspondence to: C. Yoo, Center for Atmosphere). A number of studies have shown that the MJO plays an important role in modulating the extratropical cir

  19. Stellar Atmospheres, Ht 2007 Problem Set 1

    E-Print Network [OSTI]

    Korn, Andreas

    Stellar Atmospheres, Ht 2007 Problem Set 1 Due date: Monday, 24 September 2007 at 10.15 1. LTE of how temperature is defined. (b) Where in the solar atmosphere would you expect the strongest for the photosphere? (c) How does the relation between matter and radiation differ between LTE and NLTE? What must

  20. Geochemistry of Surface-Atmosphere Interactions on

    E-Print Network [OSTI]

    Withers, Paul

    , T, and atmospheric composition ...Kinetics What are the major minerals? What is the oxidation of terrestrial alkaline igneous rocks #12;Oxidation State of the Surface 2CO + O2 = 2CO2 controls O2 Lack. S in lower atmosphere is kinetically controlled CaCO3 + SO2 = CaSO4 + CO removes SO2 , deposits CaSO4 Fe

  1. Global surface cooling: the atmospheric fast feedback response to a collapse of the thermohaline circulation

    E-Print Network [OSTI]

    Drijfhout, Sybren

    Global surface cooling: the atmospheric fast feedback response to a collapse of the thermohaline thermohaline circulation results in a global surface cooling of 0.72 K. The mechanisms that are responsible for this cooling are investigated. Additional experiments were performed with a one-dimensional radiative

  2. The contributions of atmosphere and ocean to North Atlantic Subtropical Mode Water volume anomalies

    E-Print Network [OSTI]

    The formation of Subtropical Mode Water (STMW) in the western North Atlantic has been attributed to both are the subject of a study, the CLIvar MOde Water Dynamics Experiment (CLIMODE), which includes a large fieldThe contributions of atmosphere and ocean to North Atlantic Subtropical Mode Water volume anomalies

  3. The solvation radius of silicate melts based on the solubility of noble gases and scaled particle theory

    SciTech Connect (OSTI)

    Ottonello, Giulio; Richet, Pascal

    2014-01-28

    The existing solubility data on noble gases in high-temperature silicate melts have been analyzed in terms of Scaling Particle Theory coupled with an ab initio assessment of the electronic, dispersive, and repulsive energy terms based on the Polarized Continuum Model (PCM). After a preliminary analysis of the role of the contracted Gaussian basis sets and theory level in reproducing appropriate static dipole polarizabilities in a vacuum, we have shown that the procedure returns Henry's law constants consistent with the values experimentally observed in water and benzene at T = 25?C and P = 1 bar for the first four elements of the series. The static dielectric constant (?) of the investigated silicate melts and its optical counterpart (?{sup ?}) were then resolved through the application of a modified form of the Clausius-Mossotti relation. Argon has been adopted as a probe to depict its high-T solubility in melts through an appropriate choice of the solvent diameter ?{sub s}, along the guidelines already used in the past for simple media such as water or benzene. The ?{sub s} obtained was consistent with a simple functional form based on the molecular volume of the solvent. The solubility calculations were then extended to He, Ne, and Kr, whose dispersive and repulsive coefficients are available from theory and we have shown that their ab initio Henry's constants at high T reproduce the observed increase with the static polarizability of the series element with reasonable accuracy. At room temperature (T = 25?C) the calculated Henry's constants of He, Ne, Ar, and Kr in the various silicate media predict higher solubilities than simple extrapolations (i.e., Arrhenius plots) based on high-T experiments and give rise to smooth trends not appreciably affected by the static polarizabilities of the solutes. The present investigation opens new perspectives on a wider application of PCM theory which can be extended to materials of great industrial interest at the core of metallurgical processes, ceramurgy, and the glass industry.

  4. Removal potential of toxic 2378-substituted PCDD/F from incinerator flue gases by waste-derived activated carbons

    SciTech Connect (OSTI)

    Hajizadeh, Yaghoub; Onwudili, Jude A.; Williams, Paul T.

    2011-06-15

    The application of activated carbons has become a commonly used emission control protocol for the removal or adsorption of persistent organic pollutants from the flue gas streams of waste incinerators. In this study, the 2378-substituted PCDD/F removal efficiency of three types of activated carbons derived from the pyrolysis of refuse derived fuel, textile waste and scrap tyre was investigated and compared with that of a commercial carbon. Experiments were carried out in a laboratory scale fixed-bed reactor under a simulated flue gas at 275 deg. C with a reaction period of four days. The PCDD/F in the solid matrices and exhaust gas, were analyzed using gas chromatography coupled with a triple quadrupole mass spectrometer. In the absence of activated carbon adsorbent, there was a significant increase in the concentration of toxic PCDD/F produced in the reacted flyash, reaching up to 6.6 times higher than in the raw flyash. In addition, there was a substantial release of PCDD/F into the gas phase, which was found in the flue gas trapping system. By application of the different commercial, refuse derived fuel, textile and tyre activated carbons the total PCDD/F toxic equivalent removal efficiencies in the exhaust gas stream were 58%, 57%, 64% and 52%, respectively. In general, the removal of the PCDDs was much higher with an average of 85% compared to PCDFs at 41%. Analysis of the reacted activated carbons showed that there was some formation of PCDD/F, for instance, a total of 60.6 {mu}g I-TEQ kg{sup -1} toxic PCDD/F was formed in the refuse derived fuel activated carbon compared to 34 {mu}g I-TEQ kg{sup -1} in the commercial activated carbon. The activated carbons derived from the pyrolysis of waste, therefore, showed good potential as a control material for PCDD/F emissions in waste incinerator flue gases.

  5. High resolution transmission spectroscopy as a diagnostic for Jovian exoplanet atmospheres: constraints from theoretical models

    SciTech Connect (OSTI)

    Kempton, Eliza M.-R.; Perna, Rosalba; Heng, Kevin

    2014-11-01

    We present high resolution transmission spectra of giant planet atmospheres from a coupled three-dimensional (3D) atmospheric dynamics and transmission spectrum model that includes Doppler shifts which arise from winds and planetary motion. We model Jovian planets covering more than two orders of magnitude in incident flux, corresponding to planets with 0.9-55 day orbital periods around solar-type stars. The results of our 3D dynamical models reveal certain aspects of high resolution transmission spectra that are not present in simple one-dimensional (1D) models. We find that the hottest planets experience strong substellar to anti-stellar (SSAS) winds, resulting in transmission spectra with net blueshifts of up to 3 km s{sup 1}, whereas less irradiated planets show almost no net Doppler shifts. We find only minor differences between transmission spectra for atmospheres with temperature inversions and those without. Compared to 1D models, peak line strengths are significantly reduced for the hottest atmospheres owing to Doppler broadening from a combination of rotation (which is faster for close-in planets under the assumption of tidal locking) and atmospheric winds. Finally, high resolution transmission spectra may be useful in studying the atmospheres of exoplanets with optically thick clouds since line cores for very strong transitions should remain optically thick to very high altitude. High resolution transmission spectra are an excellent observational test for the validity of 3D atmospheric dynamics models, because they provide a direct probe of wind structures and heat circulation. Ground-based exoplanet spectroscopy is currently on the verge of being able to verify some of our modeling predictions, most notably the dependence of SSAS winds on insolation. We caution that interpretation of high resolution transmission spectra based on 1D atmospheric models may be inadequate, as 3D atmospheric motions can produce a noticeable effect on the absorption signatures.

  6. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    SciTech Connect (OSTI)

    Moskovitz, Yevgeny [Middle Tennessee State Univ., Murfreesboro, TN (United States). Dept. of Chemistry; Univ. of Capetown (South Africa). Dept. of Chemistry, Scientific Computing Research Unit; Yang, Hui [Middle Tennessee State Univ., Murfreesboro, TN (United States). Dept. of Chemistry

    2015-01-01

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the critical volume hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

  7. The Marginal Damage Costs of Different Greenhouse Gases: An Application of FUND

    SciTech Connect (OSTI)

    Waldhoff, Stephanie T.; Anthoff, David; Rose, Steven K.; Tol, Richard

    2014-01-01

    We use FUND 3.8 to estimate the social cost of four greenhouse gases: carbon dioxide, methane, nitrous oxide, and sulphur hexafluoride emissions. The damage potential for each gasthe ratio of the social cost of the non-carbon dioxide greenhouse gas to the social cost of carbon dioxideis also estimated. The damage potentials are compared to several metrics, focusing in particular on the global warming potentials, which are frequently used to measure the trade-off between gases in the form of carbon dioxide equivalents. We find that damage potentials could be significantly higher than global warming potentials. This finding implies that previous papers have underestimated the relative importance of reducing non-carbon dioxide greenhouse gas emissions from an economic damage perspective. We show results for a range of sensitivity analyses: carbon dioxide fertilization on agriculture productivity, terrestrial feedbacks, climate sensitivity, discounting, equity weighting, and socioeconomic and emissions scenarios. The sensitivity of the results to carbon dioxide fertilization is a primary focus as it is an important element of climate change that has not been considered in much of the previous literature. We estimate that carbon dioxide fertilization has a large positive impact that reduces the social cost of carbon dioxide with a much smaller effect on the other greenhouse gases. As a result, our estimates of the damage potentials of methane and nitrous oxide are much higher compared to estimates that ignore carbon dioxide fertilization. As a result, our base estimates of the damage potential for methane and nitrous oxide that include carbon dioxide fertilization are twice their respective global warming potentials. Our base estimate of the damage potential of sulphur hexafluoride is similar to the one previous estimate, both almost three times the global warming potential.

  8. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-08

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distributionmorefunctions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the critical volume hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.less

  9. Raman Scattering Sensor for On-Line Monitoring of Amines and Acid Gases

    SciTech Connect (OSTI)

    Uibel, Rory; Smith, Lee

    2010-05-20

    Sulfur and CO2 removal from hydrocarbon streams and power plant effluents are a major problem. The sulfur is normally in the form of H2S. These two acid gases are scrubbed using aqueous amine solutions that are difficult to control with conventional technology. Process Instruments Inc. developed Raman scattering technology for on-line, real-time monitoring of amine streams to improve their efficiency in scrubbing H2S and CO2 from hydrocarbon streams and power plant effluents. Improved control of amine and acid gas concentrations will allow refineries, natural gas processes and power plants to more efficiently scrub Sulfur and CO2, saving energy, time and financial resources.

  10. Separation of rare gases and chiral molecules by selective binding in porous organic cages

    SciTech Connect (OSTI)

    Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.; Holden, Daniel; Jelfs, Kim E.; Hasell, Tom; Little, Marc A.; Kewley, Adam; Briggs, Michael E.; Stephenson, Andrew; Thomas, K. M.; Armstrong, Jayne A.; Bell, Jon; Busto, Jose; Noel, Raymond; Liu, Jian; Strachan, Denis M.; Thallapally, Praveen K.; Cooper, Andrew I.

    2014-10-31

    Abstract: The rare gases krypton, xenon, and radon pose both an economic opportunity and a potential environmental hazard. Xenon is used in commercial lighting, medical imaging, and anesthesia, and can sell for $5,000 per kilogram. Radon, by contrast, Is naturally radioactive and the second largest cause of lung cancer, and radioactive xenon, 133Xe, was a major pollutant released In the Fukushima Daiichi Nuclear Power Plant disaster. We describe an organic cage molecule that can capture xenon and radon with unprecedented selectivity, suggesting new technologies for environmental monitoring, removal of pollutants, or the recovery of rare, valuable elements from air.

  11. Sampling and analysis of hydrocarbons in combustion gases. Annual report, October 1979-September 1980

    SciTech Connect (OSTI)

    Johnson, I.; Myles, K.M.; Siczek, A.A.

    1981-04-01

    The purpose of these studies is to develop a method for the chemical analysis of ultratrace levels of polycyclic organic compounds in the flue gases from fluidized-bed combustors. Methods which have the potential for real time analysis have been studied. Two methods, double mass spectrometry and laser ionization mass spectrometry, appear to be promising. A brief review of current analytical methods has been made. A brief examination of fly ash from fluidized-bed combustion revealed no carcinogenic species although samples collected during fluidized-bed combustor startup were found to be mutagenic.

  12. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  13. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  14. Enhancement of NMR and MRI in the presence of hyperpolarized noble gases

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2004-11-16

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  15. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect (OSTI)

    LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

    2000-07-21

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

  16. EIA-Voluntary Reporting of Greenhouse Gases Program - What are Greenhouse

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets 9, 3:00MarketsProgramGases?

  17. Studying atmosphere-dominated hot Jupiter Kepler phase curves: Evidence that inhomogeneous atmospheric reflection is common

    E-Print Network [OSTI]

    Shporer, Avi

    2015-01-01

    We identify 3 Kepler transiting planet systems, Kepler-7, Kepler-12, and Kepler-41, whose orbital phase-folded light curves are dominated by planetary atmospheric processes including thermal emission and reflected light, while the impact of non-atmospheric (i.e. gravitational) processes, including beaming (Doppler boosting) and tidal ellipsoidal distortion, is negligible. Therefore, those systems allow a direct view of their atmospheres without being hampered by the approximations used in the inclusion of both atmospheric and non-atmospheric processes when modeling the phase curve shape. Here we analyze Kepler-12b and Kepler-41b atmosphere based on their Kepler phase curve, while the analysis of Kepler-7b was presented elsewhere. The model we used efficiently computes reflection and thermal emission contributions to the phase curve, including inhomogeneous atmospheric reflection due to longitudinally varying cloud coverage. We confirm Kepler-12b and Kepler-41b show a westward phase shift between the brightest...

  18. Range gated imaging experiments using gated intensifiers

    SciTech Connect (OSTI)

    McDonald, T.E. Jr.; Yates, G.J.; Cverna, F.H.; Gallegos, R.A.; Jaramillo, S.A.; Numkena, D.M.; Payton, J.; Pena-Abeyta, C.R.

    1999-03-01

    A variety of range gated imaging experiments using high-speed gated/shuttered proximity focused microchannel plate image intensifiers (MCPII) are reported. Range gated imaging experiments were conducted in water for detection of submerged mines in controlled turbidity tank test and in sea water for the Naval Coastal Sea Command/US Marine Corps. Field experiments have been conducted consisting of kilometer range imaging of resolution targets and military vehicles in atmosphere at Eglin Air Force Base for the US Air Force, and similar imaging experiments, but in smoke environment, at Redstone Arsenal for the US Army Aviation and Missile Command (AMCOM). Wavelength of the illuminating laser was 532 nm with pulse width ranging from 6 to 12 ns and comparable gate widths. These tests have shown depth resolution in the tens of centimeters range from time phasing reflected LADAR images with MCPII shutter opening.

  19. THREE-DIMENSIONAL CLOUD STRUCTURE OBSERVED DURING DOE ARM'S 2009 CLOUD TOMOGRAPHY FIELD EXPERIMENT

    E-Print Network [OSTI]

    THREE-DIMENSIONAL CLOUD STRUCTURE OBSERVED DURING DOE ARM'S 2009 CLOUD TOMOGRAPHY FIELD EXPERIMENT on Cloud Physics, Portland, OR June 28-July 2, 2010 Environmental Sciences Department/Atmospheric Sciences Atmospheric Radiation Measurement (ARM)'s cloud tomography Intensive Observation Period (IOP

  20. North America's net terrestrial CO2 exchange with the atmosphere 19902009

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    King, Anthony W.; Andres, Robert; Davis, Kenneth J.; Hafer, M.; Hayes, Daniel J.; Huntzinger, Deborah N.; de Jong, Bernardus; Kurz, Werner; McGuire, A. David; Vargas, Rodrigo; et al

    2015-01-21

    Scientific understanding of the global carbon cycle is required for developing national and international policy to mitigate fossil fuel CO2 emissions by managing terrestrial carbon uptake. Toward that understanding and as a contribution to the REgional Carbon Cycle Assessment and Processes (RECCAP) project, this paper provides a synthesis of net landatmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 19902009. Only CO2 is considered, not methane or other greenhouse gases. This synthesis is based on results from three different methods: atmospheric inversion, inventory-based methods and terrestrial biosphere modeling. All methods indicate that the North Americanmoreland surface was a sink for atmospheric CO2, with a net transfer from atmosphere to land. Estimates ranged from -890 to -280 Tg C yr-1, where the mean of atmospheric inversion estimates forms the lower bound of that range (a larger land sink) and the inventory-based estimate using the production approach the upper (a smaller land sink). This relatively large range is due in part to differences in how the approaches represent trade, fire and other disturbances and which ecosystems they include. Integrating across estimates, \\"best\\" estimates (i.e., measures of central tendency) are -472 281 Tg C yr-1 based on the mean and standard deviation of the distribution and -360 Tg C yr-1 (with an interquartile range of -496 to -337) based on the median. Considering both the fossil fuel emissions source and the land sink, our analysis shows that North America was, however, a net contributor to the growth of CO2 in the atmosphere in the late 20th and early 21st century. With North America's mean annual fossil fuel CO2 emissions for the period 19902009 equal to 1720 Tg C yr-1 and assuming the estimate of -472 Tg C yr-1 as an approximation of the true terrestrial CO2 sink, the continent's source : sink ratio for this time period was 1720:472, or nearly 4:1.less

  1. Ultrahigh-speed etching of organic films using microwave-excited nonequilibrium atmospheric-pressure plasma

    SciTech Connect (OSTI)

    Yamakawa, Koji; Hori, Masaru; Goto, Toshio; Den, Shoji; Katagiri, Toshirou; Kano, Hiroyuki [Department of Quantum Engineering, Nagoya University, Furo-Cho, Chikusa-ku, Nagoya 464-8603 (Japan); Depertment of Electrical Engineering and Computer Science, Nagoya University, Furo-Cho, Chikusa-ku, Nagoya 464-8603 (Japan); Department of Quantum Engineering, Nagoya University, Furo-Cho, Chikusa-ku, Nagoya 464-8603 (Japan); Department of Engineering, Katagiri Engineering Co., Ltd., 3-5-34 Shitte Tsurumu-Ku, Yokohama, Kanagawa 230-0003 (Japan); NU-EcoEngineering Co., Ltd., Ooaza Kurozasa Aza Umazutsumi Miyoshi-cho Nishikamo-gun Aichi 470-0201 (Japan)

    2005-08-15

    An ultrahigh etch rate (24 {mu}m/min at 155 deg. C and 0.3 mm/min at 325 deg. C) of an organic film was successfully achieved using a microwave-excited nonequilibrium atmospheric-pressure plasma source employing He and O{sub 2} gases. This has the potential to be applied to various kinds of fabrication of structures for microelectromechanical systems and bionanotechnology. A stable glow discharge was realized between the narrow gap (200 {mu}m) electrodes covered with a dielectric film in atmospheric pressure. The etching characteristics were investigated by changing the O{sub 2} flow rate and the distance of the substrate from the electrode. In order to clarify the ultrahigh etching mechanism, in situ diagnostic methods, including two-dimensional imaging of optical emissions in the plasma with an intensified charge-coupled device camera, electron-density evaluation using the Stark-broadened profile of the hydrogen Balmer beta line in optical emission spectroscopy, and two dimensional spatial distribution of ozone density measured with ultraviolet absorption spectroscopy, have been performed. It was found that O atoms were the dominant etching species for ultrahigh-speed etching of the organic film, and the effect of ozone on the etching process was negligible.

  2. The Effect of Diluent Gases In The Shock Tube and Rapid Compression Machine

    SciTech Connect (OSTI)

    Silke, E; W?rmel, J; O?Conaire, M; Simmie, J; Curran, H

    2007-02-09

    Studying the details of hydrocarbon chemistry in an internal combustion engine is not straightforward. A number of factors, including varying conditions of temperature and pressure, complex fluid motions, as well as variation in the composition of gasoline, render a meaningful characterization of the combusting system difficult. Some simplified experimental laboratory devices offer an alternative to complex engine environments: they remove some of the complexities that exist in real engines but retain the ability to work under engine-relevant conditions. The choice of simplified experimental devices is limited by the range of temperature and pressure at which they can operate; only the shock tube and rapid compression machine (RCM) can reach engine-relevant temperatures and pressures quickly enough and yet withstand the high pressures that occur after the ignition event. Both devices, however, suffer a common drawback: the use of inert diluent gases has been shown to affect the measured ignition delay time under some experimental conditions. Interestingly, this effect appears to be opposite in the shock tube and RCM: in the comparative study of the carrier gases argon and nitrogen, argon decreases the ignition delay time in the shock tube, but increases it in the RCM. This observation is investigated in more detail in this study.

  3. Quantum fluctuations in the BCS-BEC crossover of two-dimensional Fermi gases

    E-Print Network [OSTI]

    He, Lianyi; Cao, Gaoqing; Hu, Hui; Liu, Xia-Ji

    2015-01-01

    We present a theoretical study of the ground state of the BCS-BEC crossover in dilute two-dimensional Fermi gases. While the mean-field theory provides a simple and analytical equation of state, the pressure is equal to that of a noninteracting Fermi gas in the entire BCS-BEC crossover, which is not consistent with the features of the weakly interacting Bose condensate in the BEC limit and the weakly interacting Fermi liquid in the BCS limit. The inadequacy of the 2D mean-field theory indicates that the quantum fluctuations are much more pronounced than those in 3D. In this work, we show that the inclusion of the Gaussian quantum fluctuations naturally recovers the above features in both the BEC and BCS limits. In the BEC limit, the missing logarithmic dependence on the boson chemical potential is recovered by the quantum fluctuations. Near the quantum phase transition from the vacuum to the BEC phase, we compare our equation of state with the known grand canonical equation of state of 2D Bose gases and deter...

  4. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-09-30

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

  5. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    particles remain in the atmosphere can have a huge impact on the global climate. Measurements based on high-resolution scanning transmission x-ray images obtained at the ALS...

  6. Transport impacts on atmosphere and climate: Aviation

    E-Print Network [OSTI]

    2010-01-01

    Environment 44 (2010) 46784734 Brunner, D. , Staehelin,Environment 44 (2010) 46784734 Vedantham, A. , Wuebbles,Environment 44 (2010) 46784734 global atmosphere. In:

  7. Optical Intensity Interferometry through Atmospheric Turbulence

    E-Print Network [OSTI]

    Peng Kian Tan; Aik Hui Chan; Christian Kurtsiefer

    2015-12-29

    Conventional ground-based astronomical observations suffer from image distortion due to atmospheric turbulence. This can be minimized by choosing suitable geographic locations or adaptive optical techniques, and avoided altogether by using orbital platforms outside the atmosphere. One of the promises of optical intensity interferometry is its independence from atmospherically induced phase fluctuations. By performing narrowband spectral filtering on sunlight and conducting temporal intensity interferometry using actively quenched avalanche photon detectors (APDs), the Solar $g^{(2)}(\\tau)$ signature was directly measured. We observe an averaged photon bunching signal of $g^{(2)}(\\tau) = 1.693 \\pm 0.003$ from the Sun, consistently throughout the day despite fluctuating weather conditions, cloud cover and elevation angle. This demonstrates the robustness of the intensity interferometry technique against atmospheric turbulence and opto-mechanical instabilities, and the feasibility to implement measurement schemes with both large baselines and long integration times.

  8. Uraninite and Fullerene in Atmospheric Particulates

    E-Print Network [OSTI]

    Utsunomiya, Satoshi

    incineration, uranium mining, and atmospheric testing of nuclearweapons-burning power plants typically contain very small amounts of uranium ( concentrations, the form of the uranium has been unknown. Using a variety of advanced electron microscopy

  9. Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951...

    Energy Savers [EERE]

    Atmospheric Nuclear Weapons Testing, 1951-1963. Battlefield of the Cold War: The Nevada Test Site, Volume I Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951-1963....

  10. The faculty and students in the Atmospheric Sciences Department use physics, chemistry, and mathematics to better understand the atmosphere

    E-Print Network [OSTI]

    Doty, Sharon Lafferty

    The faculty and students in the Atmospheric Sciences Department use physics, chemistry chemistry Atmospheric fluid dynamics Biosphere interactions Climate variability Clouds & storms Radiative, and mathematics to better understand the atmosphere and improve the prediction of its future state, both over

  11. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    2008-01-15

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  12. Air Activation Following an Atmospheric Explosion

    SciTech Connect (OSTI)

    Lowrey, Justin D.; McIntyre, Justin I.; Prichard, Andrew W.; Gesh, Christopher J.

    2013-03-13

    In addition to thermal radiation and fission products, nuclear explosions result in a very high flux of unfissioned neutrons. Within an atmospheric nuclear explosion, these neutrons can activate the various elemental components of natural air, potentially adding to the radioactive signature of the event as a whole. The goal of this work is to make an order-of-magnitude estimate of the total amount of air activation products that can result from an atmospheric nuclear explosion.

  13. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  14. Basalt-Atmosphere Interactions on Venus -

    E-Print Network [OSTI]

    Treiman, Allan H.

    Atmosphere? · CaAl2Si2O8 + SO3 CaSO4 + Al2SiO5 + SiO2 ­ Anhydrite + andalusite + quartz !!! · Does this reaction proceed? ­ Venus atmosphere est'd 0.2 - 0.3 ppt SO3. #12;Reaction Position · From this, very possible that SO3 is buffered! · But ... SO3 value is not known very well - who knows what is really going

  15. Linear electric field frequency shift (important for next generation electric dipole moment searches) induced in confined gases by a magnetic field gradient

    E-Print Network [OSTI]

    Authors A. L. Barabanov; R. Golub; S. K. Lamoreaux

    2006-07-17

    The search for particle electric dipole moments (edm) represents a most promising way to search for physics beyond the standard model. A number of groups are planning a new generation of experiments using stored gases of various kinds. In order to achieve the target sensitivities it will be necessary to deal with the systematic error resulting from the interaction of the well-known $\\overrightarrow{v}\\times \\overrightarrow{E}$ field with magnetic field gradients (often referred to as the geometric phase effect (Commins, ED; Am. J. Phys. \\QTR{bf}{59}, 1077 (1991), Pendlebury, JM \\QTR{em}{et al;} Phys. Rev. \\QTR{bf}{A70}, 032102 (2004)). This interaction produces a frequency shift linear in the electric field, mimicking an edm. In this work we introduce an analytic form for the velocity auto-correlation function which determines the velocity-position correlation function which in turn determines the behavior of the frequency shift (Lamoreaux, SK and Golub, R; Phys. Rev \\QTR{bf}{A71}, 032104 (2005)) and show how it depends on the operating conditions of the experiment. We also discuss some additional issues.

  16. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2006-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

  17. Lookup tables to compute high energy cosmic ray induced atmospheric ionization and changes in atmospheric chemistry

    E-Print Network [OSTI]

    Dimitra Atri; Adrian L. Melott; Brian C. Thomas

    2010-05-03

    A variety of events such as gamma-ray bursts and supernovae may expose the Earth to an increased flux of high-energy cosmic rays, with potentially important effects on the biosphere. Existing atmospheric chemistry software does not have the capability of incorporating the effects of substantial cosmic ray flux above 10 GeV . An atmospheric code, the NASA-Goddard Space Flight Center two-dimensional (latitude, altitude) time-dependent atmospheric model (NGSFC), is used to study atmospheric chemistry changes. Using CORSIKA, we have created tables that can be used to compute high energy cosmic ray (10 GeV - 1 PeV) induced atmospheric ionization and also, with the use of the NGSFC code, can be used to simulate the resulting atmospheric chemistry changes. We discuss the tables, their uses, weaknesses, and strengths.

  18. Simulation of Aerosol Behavior in a Saturated Atmosphere With the CONTAIN Code

    SciTech Connect (OSTI)

    Kljenak, Ivo; Mavko, Borut [Jozef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia)

    2002-07-01

    Experiments on aerosol behavior in an atmosphere containing saturated vapor, which were performed in the KAEVER experimental facility and proposed for the OECD International Standard Problem No. 44, were simulated with the CONTAIN thermal-hydraulic computer code. The purpose of the work was to assess the capability of the CONTAIN code to model aerosol condensation and deposition in a containment of a light-water-reactor nuclear power plant at severe accident conditions. Results of dry and wet aerosol concentrations in the test vessel atmosphere are presented and analyzed. (authors)

  19. Sintering atmosphere effects on the ductility of W-Ni-Fe heavy metals

    SciTech Connect (OSTI)

    German, R.M.; Churn, K.S.

    1984-04-01

    Residual porosity has a strong negative effect on the ductility of tungsten-nickel-iron heavy metals. This investigation examined the sintering atmosphere role in stabilizing detrimental residual pore structures. Experiments are reported on alloys containing 93, 95, or 97 wt pct W with Ni:Fe ratios of 7:3. The negative effect of prolonged sintering is attributed to pore coarsening involving trapped gas. Calculated pore growth rates for hydrogen filled pores suggest that pore coarsening involves both ripening and coalescence driven by tungsten grain growth. A change in sintering atmosphere from hydrogen to argon midway through the sintering cycle can aid pore degassing and increase ductility and strength.

  20. Atmospheric Neutrinos in the MINOS Far Detector

    SciTech Connect (OSTI)

    Howcroft, Caius L.F.

    2004-12-01

    The phenomenon of flavour oscillations of neutrinos created in the atmosphere was first reported by the Super-Kamiokande collaboration in 1998 and since then has been confirmed by Soudan 2 and MACRO. The MINOS Far Detector is the first magnetized neutrino detector able to study atmospheric neutrino oscillations. Although it was designed to detect neutrinos from the NuMI beam, it provides a unique opportunity to measure the oscillation parameters for neutrinos and anti-neutrinos independently. The MINOS Far Detector was completed in August 2003 and since then has collected 2.52 kton-years of atmospheric data. Atmospheric neutrino interactions contained within the volume of the detector are separated from the dominant background from cosmic ray muons. Thirty seven events are selected with an estimated background contamination of less than 10%. Using the detector's magnetic field, 17 neutrino events and 6 anti-neutrino events are identified, 14 events have ambiguous charge. The neutrino oscillation parameters for {nu}{sub {mu}} and {bar {nu}}{sub {mu}} are studied using a maximum likelihood analysis. The measurement does not place constraining limits on the neutrino oscillation parameters due to the limited statistics of the data set analysed. However, this thesis represents the first observation of charge separated atmospheric neutrino interactions. It also details the techniques developed to perform atmospheric neutrino analyses in the MINOS Far Detector.