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Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Discovery of carbon monoxide in the upper atmosphere of Pluto  

E-Print Network (OSTI)

Pluto's icy surface has changed colour and its atmosphere has swelled since its last closest approach to the Sun in 1989. The thin atmosphere is produced by evaporating ices, and so can also change rapidly, and in particular carbon monoxide should be present as an active thermostat. Here we report the discovery of gaseous CO via the 1.3mm wavelength J=2-1 rotational transition, and find that the line-centre signal is more than twice as bright as a tentative result obtained by Bockelee-Morvan et al. in 2000. Greater surface-ice evaporation over the last decade could explain this, or increased pressure could have caused the atmosphere to expand. The gas must be cold, with a narrow line-width consistent with temperatures around 50 K, as predicted for the very high atmosphere, and the line brightness implies that CO molecules extend up to approximately 3 Pluto radii above the surface. The upper atmosphere must have changed markedly over only a decade since the prior search, and more alterations could occur by the...

Greaves, J S; Friberg, P

2011-01-01T23:59:59.000Z

2

Photochemistry and Transport of Carbon Monoxide in the Middle Atmosphere  

Science Conference Proceedings (OSTI)

Two-dimensional model calculations of the photochemistry and transport of carbon monoxide in the stratosphere, mesosphere, and lower thermosphere are presented. Results are compared to available observations at midlatitudes, where both ...

S. Solomon; R. R. Garcia; J. J. Olivero; R. M. Bevilacqua; P. R. Schwartz; R. T. Clancy; D. O. Muhleman

1985-05-01T23:59:59.000Z

3

Compressed Air Sample Technology for Isotopic Analysis of Atmospheric Carbon Monoxide  

Science Conference Proceedings (OSTI)

A methodology for the collection of large (1000 L) air samples for isotopic analysis of atmospheric carbon monoxide is presented. A low-background, high-pressure, high-flow sampling system with a residual background of less than 2 ppbv CO has ...

John E. Mak; Carl A. M. Brenninkmeijer

1994-04-01T23:59:59.000Z

4

Impact of emissions, chemistry, and climate on atmospheric carbon monoxide : 100-year predictions from a global chemistry-climate model  

E-Print Network (OSTI)

The possible trends for atmospheric carbon monoxide in the next 100 yr have been illustrated using a coupled atmospheric chemistry and climate model driven by emissions predicted by a global economic development model. ...

Wang, Chien.; Prinn, Ronald G.

5

Carbon Monoxide Safety Tips  

E-Print Network (OSTI)

Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist.

Shaw, Bryan W.; Garcia, Monica L.

1999-07-26T23:59:59.000Z

6

Method of removing carbon monoxide from gases  

DOE Patents (OSTI)

A process and catalyst are disclosed for purifying an atmosphere containing carbon monoxide by passing the atmosphere through a bed of a catalyst of TbO.sub.x, where x = 1.8 to 1.5, which oxidizes the carbon monoxide to carbon dioxide.

Gerstein, Bernard C. (Ames, IA); Macaulay, David B. (Arlington Heights, IL)

1976-06-01T23:59:59.000Z

7

Role of carboxydobacteria in consumption of atmospheric carbon monoxide by soil  

Science Conference Proceedings (OSTI)

The carbon monoxide consumption rates of the carboxydobacteria Pseudomonas (Seliberia) carboxydohydrogena, P. carboxydovorans, and P. carboxydoflava were measured at high (50%) and low (0.5 ..mu..l liter/sup -1/) mixing ratios of CO in air. CO was only consumed when the bacteria had been grown under CO-autotrophic conditions. At low cell densities the CO comsumption rates measured at low CO mixing ratios were similar in cell suspensions and in mixtures of bacteria in soil. CO consumption observed in natural soil (loess, eolian sand, chernozem) as well as in suspensions or soil mixtures of carboxydobacteria showed Michaelis-Menten kinetics. Considering the difference of the K/sub m/, values and the observed V/sub max/ values, carboxydobacteria cannot contribute significantly to the consumption of atmospheric CO.

Conrad, R. (Max-Planck-Institut fuer Chemie, Mainz, Germany); Meyer, O.; Seiler, W.

1981-08-01T23:59:59.000Z

8

Carbon Monoxide Tolerant Electrocatalyst with Low Platinum ...  

Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading and a Process for its Preparation Brookhaven National Laboratory. Contact BNL About ...

9

Why sequence carbon monoxide oxidizing thermophiles?  

NLE Websites -- All DOE Office Websites (Extended Search)

carbon monoxide oxidizing thermophiles? carbon monoxide oxidizing thermophiles? Many microbes that use carbon monoxide as an energy source are found in high temperature environments such as geothermal areas. Researchers think that these carboxydotrophs may be involved in reducing potentially toxic carbon monoxide hotspots by combine with water to form hydrogen, carbon dioxide and acetate, which are in turn used for thermophilic energy conservation and carbon sequestration mechanisms. The project focuses on sequencing two closely related microbes, one of which is Carboxydothermus hydrogenformans. A strain of C. hydrogenformans has been grown in hydrogen-enriched synthesis gas (syngas), which contains a mix of hydrogen and carbon monoxide. Researchers are interested in sequencing both microbial strains to track the genome's evolution and

10

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission...

11

Device for staged carbon monoxide oxidation  

DOE Patents (OSTI)

A method and apparatus for selectively oxidizing carbon monoxide in a hydrogen rich feed stream. The method comprises mixing a feed stream consisting essentially of hydrogen, carbon dioxide, water and carbon monoxide with a first predetermined quantity of oxygen (air). The temperature of the mixed feed/oxygen stream is adjusted in a first the heat exchanger assembly (20) to a first temperature. The mixed feed/oxygen stream is sent to reaction chambers (30,32) having an oxidation catalyst contained therein. The carbon monoxide of the feed stream preferentially absorbs on the catalyst at the first temperature to react with the oxygen in the chambers (30,32) with minimal simultaneous reaction of the hydrogen to form an intermediate hydrogen rich process stream having a lower carbon monoxide content than the feed stream. The elevated outlet temperature of the process stream is carefully controlled in a second heat exchanger assembly (42) to a second temperature above the first temperature. The process stream is then mixed with a second predetermined quantity of oxygen (air). The carbon monoxide of the process stream preferentially reacts with the second quantity of oxygen in a second stage reaction chamber (56) with minimal simultaneous reaction of the hydrogen in the process stream. The reaction produces a hydrogen rich product stream having a lower carbon monoxide content than the process stream. The product stream is then cooled in a third heat exchanger assembly (72) to a third predetermined temperature. Three or more stages may be desirable, each with metered oxygen injection.

Vanderborgh, Nicholas E. (Los Alamos, NM); Nguyen, Trung V. (College Station, TX); Guante, Jr., Joseph (Denver, CO)

1993-01-01T23:59:59.000Z

12

Terpolymerization of ethylene, sulfur dioxide and carbon monoxide  

DOE Patents (OSTI)

This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

1981-01-01T23:59:59.000Z

13

Enhanced carbon monoxide utilization in methanation process  

DOE Green Energy (OSTI)

Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

Elek, Louis F. (Peekskill, NY); Frost, Albert C. (Congers, NY)

1984-01-01T23:59:59.000Z

14

Method and apparatus for selective removal of carbon monoxide  

DOE Patents (OSTI)

There is provided a method and apparatus for treatment of a hydrogen-rich gas to reduce the carbon monoxide content thereof by reacting the carbon monoxide in the gas with an amount of oxygen sufficient to oxidize at least a portion of the carbon monoxide in the presence of a catalyst in a desired temperature range without substantial reaction of hydrogen. The catalyst is an iridium-based catalyst dispersed on, and supported on, a carrier. In the presence of the catalyst, carbon monoxide in a hydrogen-rich feed gas is selectively oxidized such that a product stream is produced with a very low carbon monoxide content.

Borup, Rodney L. (East Rochester, NY); Skala, Glenn W. (Churchville, NY); Brundage, Mark A. (Pittsford, NY); LaBarge, William J. (Bay City, MI)

2000-01-01T23:59:59.000Z

15

Carbon Monoxide in type II supernovae  

E-Print Network (OSTI)

Infrared spectra of two type II supernovae 6 months after explosion are presented. The spectra exhibit a strong similarity to the observations of SN 1987A and other type II SNe at comparable epochs. The continuum can be fitted with a cool black body and the hydrogen lines have emissivities that are approximately those of a Case B recombination spectrum. The data extend far enough into the thermal region to detect emission by the first overtone of carbon monoxide. The molecular emission is modeled and compared with that in the spectra of SN 1987A. It is found that the flux in the CO first overtone is comparable to that found in SN 1987A. We argue that Carbon Monoxide forms in the ejecta of all type II SNe during the first year after explosion.

J. Spyromilio; B. Leibundgut; R. Gilmozzi

2001-07-16T23:59:59.000Z

16

Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts  

E-Print Network (OSTI)

for reduction of carbon dioxide. IR-SpectroelectrochemicalElectrocatalytic reduction of carbon dioxide mediated by Re(Reduction of Carbon Dioxide to Carbon Monoxide Mediated by (

Smieja, Jonathan Mark

2012-01-01T23:59:59.000Z

17

CO (Carbon Monoxide Mixing Ratio System) Handbook  

Science Conference Proceedings (OSTI)

The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

Biraud, S

2011-02-23T23:59:59.000Z

18

Search of medical literature for indoor carbon monoxide exposure  

SciTech Connect

This report documents a literature search on carbon monoxide. The search was limited to the medical and toxicological databases at the National Library of Medicine (MEDLARS). The databases searched were Medline, Toxline and TOXNET. Searches were performed using a variety of strategies. Combinations of the following keywords were used: carbon, monoxide, accidental, residential, occult, diagnosis, misdiagnosis, heating, furnace, and indoor. The literature was searched from 1966 to the present. Over 1000 references were identified and summarized using the following abbreviations: The major findings of the search are: (1) Acute and subacute carbon monoxide exposures result in a large number of symptoms affecting the brain, kidneys, respiratory system, retina, and motor functions. (2) Acute and subacute carbon monoxide (CO) poisonings have been misdiagnosed on many occasions. (3) Very few systematic investigations have been made into the frequency and consequences of carbon monoxide poisonings.

Brennan, T.; Ivanovich, M.

1995-12-01T23:59:59.000Z

19

Reduction of Carbon Monoxide. Past Research Summary  

DOE R&D Accomplishments (OSTI)

Research programs for the year on the preparation, characterization, and reactions of binuclear tantalum complexes are described. All evidence to date suggest the following of these dimeric molecules: (1) the dimer does not break into monomers under mild conditions; (2) intermolecular hydride exchange is not negligible, but it is slow; (3) intermolecular non-ionic halide exchange is fast; (4) the ends of the dimers can rotate partially with respect to one another. The binuclear tantalum hydride complexes were found to react with carbon monoxide to give a molecule which is the only example of reduction of CO by a transition metal hydride to give a complex containing a CHO ligand. Isonitrides also reacted in a similar manner with dimeric tantalum hydride. (ATT)

Schrock, R. R.

1982-00-00T23:59:59.000Z

20

Carbon Monoxide Poisoning Avoided Through Weatherization | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Monoxide Poisoning Avoided Through Weatherization Carbon Monoxide Poisoning Avoided Through Weatherization Carbon Monoxide Poisoning Avoided Through Weatherization October 5, 2010 - 10:56am Addthis Joshua DeLung What does this mean for me? Getting your heating pipes fixed can not only save you money, but also improve your health. "If we'd had a couple cold nights where I would've had to use my heat more than usual, it probably would've put me to sleep and left me there -- it was just too much carbon monoxide coming out in the house," says Mark Pickartz, of Van Buren, Ark. Pickartz's home was weatherized in February by his local community action agency, Crawford-Sebastian Community Development Council (C-SCDC). When energy auditors arrived to his house, they found that his home's heater was severely leaking the poisonous gas. C-SCDC, based in Fort Smith, Ark.,

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Inhibition of Premixed Carbon Monoxide-Hydrogen-Oxygen ...  

Science Conference Proceedings (OSTI)

... The fuel gas is carbon monoxide (Mathe- son UHP, 99.9% CO, with the sum of ... filters) gener- ates the schlieren image of the flame for capture by a ...

2012-09-07T23:59:59.000Z

22

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

23

A Smart Sensor System for Carbon Monoxide Detection  

Science Conference Proceedings (OSTI)

This paper illustrates a smart sensor system for carbon monoxide detection. An innovative technological approach has been pursued to fabricate gas sensors on silicon substrate, compatible with IC fabrication. A mixed analog-digital electronic interface processes ... Keywords: sensor interfaces, sensors, sigma-delta converters

G. C. Cardinali; L. Dori; M. Fiorini; I. Sayago; G. Faglia; C. Perego; G. Sberveglieri; V. Liberali; F. Maloberti; D. Tonietto

1997-11-01T23:59:59.000Z

24

Carbon monoxide study - Seattle, Washington, October 6-November 2, 1977. Part 1. Executive summary report  

SciTech Connect

This report is a summary of EPA 910/9-78-054b, a study of the carbon monoxide problem in downtown Seattle.

Wilson, C.B.; Schweiss, J.W.

1978-12-01T23:59:59.000Z

25

An experimental investigation of the ignition properties of hydrogen and carbon monoxide  

E-Print Network (OSTI)

for syngas turbine applications S.M. Walton *, X. He, B.T. Zigler, M.S. Wooldridge Department of Mechanical of simulated syngas mixtures of hydrogen (H2), carbon monoxide (CO), oxygen (O2), nitrogen (N2), and carbon. Keywords: Carbon monoxide; Hydrogen; Syngas; Ignition; Rapid compression facility 1. Introduction Syngas

Wooldridge, Margaret S.

26

Transient PrOx carbon monoxide measurement, control, and optimization  

DOE Green Energy (OSTI)

Fuel processing systems for low temperature polymer electrolyte membrane (PEM) fuel cell systems require control of the carbon monoxide concentration to less than 100 ppm to 10 ppm in the anode feed. Conventional hydrocarbon fuel processors use a water-gas shift (WGS) reactor to react CO with water to form H2 and reduce the CO concentration. The CO conversion is limited by equilibrium at the outlet temperature of the WGS reactor. The WGS outlet CO concentration can range from over 1% to 2000 ppm depending on the system and its operating parameters. At these concentrations, CO poisons low temperature PEM fuel cells and the concentrations needs to be reduced further.

Inbody, M. A. (Michael A.); Borup, R. L. (Rodney L.); Tafoya, J. (Jose I.)

2002-01-01T23:59:59.000Z

27

Methanation of gas streams containing carbon monoxide and hydrogen  

DOE Patents (OSTI)

Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

Frost, Albert C. (Congers, NY)

1983-01-01T23:59:59.000Z

28

Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon...  

NLE Websites -- All DOE Office Websites (Extended Search)

Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and Carbon-13 in Methane Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and...

29

Interaction of carbon monoxide and hydrogen with the (1010) face of ruthenium  

DOE Green Energy (OSTI)

The interaction was studied at 23.5, 200, and -135/sup 0/C with low energy electron diffraction (LEED) and Auger electron spectroscopy. (AES). Carbon monoxide adsorbs associatively at 23.5/sup 0/C, but is apparently dissociated by the LEED beam and hydrogen adsorbed from the ambient after a few minutes for less than 10 Langmuirs of carbon monoxide. For large doses of carbon monoxide at 23.5/sup 0/C, 10 Langmuirs or more, the LEED beam does not disociate carbon monoxide, but carbon monoxide and hydrogen adsorbed from the ambient do appear to be removed from the surface by the LEED beam. Carbon monoxide and hydrogen on the surface together will react and form surface complexes with distinctive LEED patterns at 23.5/sup 0/C though some of the interactions appear to be LEED beam induced. If sufficient hydrogen is present, some of these complexes are lost from the surface probably as methane and water. Carbon monoxide will react with itself and hydrogen at 23.5/sup 0/C with carbon being lost from the surface probably as carbon dioxide. At 200/sup 0/C, neither carbon monoxide nor hydrogen will absorb on Ru (1010) in significant amounts at the low dose pressures used. However, if the Ru(1010) crystal is allowed to cool below 70/sup 0/C, ambient carbon monoxide and hydrogen will adsorb on Ru (1010) and form LEED patterns like those formed at 23.5/sup 0/C. At -135/sup 0/C, carbon monoxide will react with itself and hydrogen readily most of the time producing surface complexes with distinctive LEED paterns. If a moderate amount of hydrogen is present, some of these complexes are lost from the surface, probably as methane. If a large amount of hydrogen is present, some of these complexes are lost from the surface probably as carbon dioxdie. 17 figures, 8 tables.

Tomcsik, T.L.

1979-01-01T23:59:59.000Z

30

717 Notices to Readers Carbon Monoxide Poisoning Deaths  

E-Print Network (OSTI)

Carbon Monoxide monoxide Poisoning (CO) is an odorless, — Continued colorless, nonirritating gas produced by the incomplete combustion of carbon-based fuels. CO exposure is responsible for more fatal unintentional poisonings in the United States than any other agent, with the highest incidence occurring during the cold-weather months (1). Although most of these deaths occur in residences or motor vehicles (2), two incidents among campers in Georgia illustrate the danger of CO in outdoor settings. This report describes the two incidents, which resulted in six deaths, and provides recommendations for avoiding CO poisoning in outdoor settings. Cases 1–4. On the afternoon of March 14, 1999, a 51-year-old man, his 10-year-old son, a 9-year-old boy, and a 7-year-old girl were found dead inside a zipped-up, 10-foot by 14-foot, two-room tent at their campsite in southeast Georgia (a pet dog also died). A propane gas stove, still burning, was found inside the tent; the stove apparently had been brought inside to provide warmth. The occupants had died during the night. Postmortem carboxyhemoglobin (COHb) levels measured 50%, 63%, 69%, and 63%, respectively, in the four decedents (in the general U.S. population, COHb concentrations

Basidiobolomycosis Arizona; North Carolinia

1999-01-01T23:59:59.000Z

31

Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation  

Science Conference Proceedings (OSTI)

Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

2010-04-04T23:59:59.000Z

32

Biomass burning sources of nitrogen oxides, carbon monoxide, and non-methane hydrocarbons  

SciTech Connect

Biomass burning is an important source of many key tropospheric species, including aerosols, carbon dioxide (CO{sub 2}), nitrogen oxides (NO{sub {times}}=NO+NO{sub 2}), carbon monoxide (CO), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), methyl bromide (CH{sub 3}Br), ammonia (NH{sub 3}), non-methane hydrocarbons (NMHCs) and other species. These emissions and their subsequent products act as pollutants and affect greenhouse warming of the atmosphere. One important by-product of biomass burning is tropospheric ozone, which is a pollutant that also absorbs infrared radiation. Ozone is formed when CO, CH{sub 4}, and NMHCs react in the presence of NO{sub {times}} and sunlight. Ozone concentrations in tropical regions (where the bulk of biomass burning occurs) may increase due to biomass burning. Additionally, biomass burning can increase the concentration of nitric acid (HNO{sub 3}), a key component of acid rain.

Atherton, C.S.

1995-11-01T23:59:59.000Z

33

Cyclic process for producing methane from carbon monoxide with heat removal  

DOE Patents (OSTI)

Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

1982-01-01T23:59:59.000Z

34

Modeling Ambient Carbon Monoxide Trends to Evaluate Mobile Source Emissions Reductions  

Science Conference Proceedings (OSTI)

Regression models have been used with poor success to detect the effect of emission control programs in ambient concentration measurements of carbon monoxide. An advanced CO regression model is developed whose form is based on an understanding of ...

Robin L. Dennis; Mary W. Downton

1987-10-01T23:59:59.000Z

35

Production of carbon monoxide-free hydrogen and helium from a high-purity source  

DOE Patents (OSTI)

The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

Golden, Timothy Christopher (Allentown, PA); Farris, Thomas Stephen (Bethlehem, PA)

2008-11-18T23:59:59.000Z

36

Basin-Scale Carbon Monoxide Distributions in the Parallel Ocean Program  

Science Conference Proceedings (OSTI)

As a primary photochemical constituent in upper-ocean and tropospheric geocycling, carbon monoxide is of interest to a variety of global change research communities. Dynamic three-dimensional simulations of its marine concentration patterns, ...

Shaoping Chu; Scott Elliott; David Erickson

2007-12-01T23:59:59.000Z

37

Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin  

DOE Patents (OSTI)

The compound, [Pd(Me-DUPHOS)(MeCN){sub 2}](BF{sub 4}){sub 2}, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic {alpha}-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone).

Sen, A.; Jiang, Z.

1996-05-28T23:59:59.000Z

38

Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin  

DOE Patents (OSTI)

The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)

Sen, Ayusman (State College, PA); Jiang, Zhaozhong (State College, PA)

1996-01-01T23:59:59.000Z

39

A Micro-Computer-Based Fuel Optimization System Utilizing In-Situ Measurement of Carbon Monoxide  

E-Print Network (OSTI)

A microcomputer-based control system utilizing a distributed intelligence architecture has been developed to control combustion in hydrocarbon fuel-fired boilers and heaters to significantly reduce fuel usage. The system incorporates a unique flue gas analyzer that mounts directly in the flue or stack to continuously measure carbon monoxide, unburned hydrocarbons, opacity and temperature. The control console interfaces directly with the boiler's existing analog control system to provide precise air fuel ratio control based on carbon monoxide measurements. Significant decreases in excess air result in reduced fuel usage while meeting steam demand. Actual performance on industrial boilers shows increases in efficiency of from 1% to 3% with substantial fuel savings.

DeVivo, D. G.

1980-01-01T23:59:59.000Z

40

Process for producing methane from gas streams containing carbon monoxide and hydrogen  

DOE Patents (OSTI)

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Frost, Albert C. (Congers, NY)

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Gold Nanoparticles Supported on Carbon Nitride: Influence of Surface Hydroxyls on Low Temperature Carbon Monoxide Oxidation  

SciTech Connect

This paper reports the synthesis of 2.5 nm gold clusters on the oxygen free and chemically labile support carbon nitride (C3N4). Despite having small particle sizes and high enough water partial pressure these Au/C3N4 catalysts are inactive for the gas phase and liquid phase oxidation of carbon monoxide. The reason for the lack of activity is attributed to the lack of surface OH groups on the C3N4. These OH groups are argued to be responsible for the activation of CO in the oxidation of CO. The importance of basic OH groups explains the well document dependence of support isoelectric point versus catalytic activity.

Singh, Joseph A [ORNL; Dudney, Nancy J [ORNL; Li, Meijun [ORNL; Overbury, Steven {Steve} H [ORNL; Veith, Gabriel M [ORNL

2012-01-01T23:59:59.000Z

42

Indonesia Forest Fires Exacerbate Carbon Monoxide Pollution over Peninsular Malaysia during July to September 2005  

Science Conference Proceedings (OSTI)

Wind carried the smoke further afield from forest fires in Sumatra caused worse air pollution in Malaysia reached extremely hazardous levels and forced schools and an airport to close. There were 3,258 'hot spots' recorded by NOAA satellites in the province ... Keywords: AIRS, Carbon monoxide, Peninsular

Jasim M. Rajab; M. Z. MatJafri; H. S. Lim; K. Abdullah

2009-08-01T23:59:59.000Z

43

Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor  

Science Conference Proceedings (OSTI)

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

2012-11-13T23:59:59.000Z

44

One-dimensional turbulence model simulations of autoignition of hydrogen/carbon monoxide fuel mixtures in a turbulent jet  

Science Conference Proceedings (OSTI)

The autoignition of hydrogen/carbon monoxide in a turbulent jet with preheated co-flow air is studied using the one-dimensional turbulence (ODT) model. The simulations are performed at atmospheric pressure based on varying the jet Reynolds number and the oxidizer preheat temperature for two compositions corresponding to varying the ratios of H{sub 2} and CO in the fuel stream. Moreover, simulations for homogeneous autoignition are implemented for similar mixture conditions for comparison with the turbulent jet results. The results identify the key effects of differential diffusion and turbulence on the onset and eventual progress of autoignition in the turbulent jets. The differential diffusion of hydrogen fuels results in a reduction of the ignition delay relative to similar conditions of homogeneous autoignition. Turbulence may play an important role in delaying ignition at high-turbulence conditions, a process countered by the differential diffusion of hydrogen relative to carbon monoxide; however, when ignition is established, turbulence enhances the overall rates of combustion of the non-premixed flame downstream of the ignition point. (author)

Gupta, Kamlesh G.; Echekki, Tarek [Department of Mechanical and Aerospace Engineering, North Carolina State University, NC (United States)

2011-02-15T23:59:59.000Z

45

In situ gasification process for producing product gas enriched in carbon monoxide and hydrogen  

SciTech Connect

The present invention is directed to an in situ coal gasification process wherein the combustion zone within the underground coal bed is fed with air at increasing pressure to increase pressure and temperature in the combustion zone for forcing product gases and water naturally present in the coal bed into the coal bed surrounding the combustion zone. No outflow of combustion products occurs during the build-up of pressure and temperature in the combustion zone. After the coal bed reaches a temperature of about 2000.degree. F and a pressure in the range of about 100-200 psi above pore pressure the airflow is terminated and the outflow of the combustion products from the combustion zone is initiated. The CO.sub.2 containing gaseous products and the water bleed back into the combustion zone to react endothermically with the hot carbon of the combustion zone to produce a burnable gas with a relatively high hydrogen and carbon monoxide content. About 11 to 29 percent of the gas recovered from the combustion zone is carbon monoxide which is considerably better than the 4 to 10 percent carbon monoxide obtained by employing previously known coal gasification techniques.

Capp, John P. (Morgantown, WV); Bissett, Larry A. (Morgantown, WV)

1978-01-01T23:59:59.000Z

46

A survey of carbon monoxide and nitrogen dioxide in indoor ice arenas in Vermont  

Science Conference Proceedings (OSTI)

Because of the history of health problems traceable to the exhaust of ice resurfacing machines, state sanitarians used detector tubes to measure carbon monoxide (CO) and nitrogen dioxide (NO[sub 2]) levels in enclosed ice arenas in Vermont during high school hockey games. Five of eight arenas had average game CO measurements of 30 ppm carbon monoxide or more. Two of the three periods of play had average CO readings in excess of 100 ppm in one arena. Only six arenas had the complete series of nitrogen dioxide measurements. One had an average game NO[sub 2] level of 1.2 ppm. Two had one or more periods of play that averaged in excess of 0.5 ppm. Despite the ample documentation of the hazards of operating combustion-powered resurfacing machines inside enclosed ice arenas, a significant portion of the arenas had undesirable levels of carbon monoxide or nitrogen dioxide. Ice arenas should be routinely monitored for air contaminants. Considerations should be given to the purchase of electric ice resurfacing machines for new arenas and arenas that have air contamination that cannot be resolved with ventilation.

Paulozzi, L.J. (Vermont Health Dept., Burlington, VT (United States)); Spengler, R.F.; Vogt, R.L.; Carney, J.K.

1993-12-01T23:59:59.000Z

47

Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides  

SciTech Connect

The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

Haas, P.A.; Lee, D.D.; Mailen, J.C.

1991-11-01T23:59:59.000Z

48

Atmospheric carbon dioxide and the greenhouse effect  

SciTech Connect

This document contains a non-technical review of the problems associated with atmospheric carbon dioxide and the resulting greenhouse effect. (TEM)

Firestine, M.W. (ed.)

1989-05-01T23:59:59.000Z

49

Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases  

DOE Patents (OSTI)

Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2001-01-01T23:59:59.000Z

50

Interaction and reactivity of nitric oxide and carbon monoxide on ruthenium surfaces  

DOE Green Energy (OSTI)

A multifaceted investigation of the reduction of nitric oxide by carbon monoxide using a ruthenium (102) single crystal catalyst in the pressure range 10/sup -3/ to 10 Torr and temperature range of 300 to 475/sup 0/C has been undertaken. Kinetic and isotopic results indicate that the reaction products CO/sub 2/ and N/sub 2/ were produced via two reaction mechanisms. Using a reducing gas mixture (low P/sub NO//P/sub CO/ ratio) a two site mechanism was operative involving NO dissociation. The carbon monoxide kinetic order varied from +1 to -3 and the nitric oxide order varied from +1 to 0. The catalyst under these conditions was determined to be metallic ruthenium with oxygen bonded within the first surface layer. The oxygen was unreactive and formed a (1 x 3)-0 LEED pattern. Under oxidizing conditions (high P/sub NO//P/sub CO/ ratio) the catalyst was ruthenium dioxide and the functional mechanism under these reaction conditions yielded a nitric oxide order of +2 to -4. Inclusion of a site poisoning mechanism under reducing conditions and an RuO/sub 2/ growth mechanism involving ruthenium cation transfer under oxidizing conditions into the kinetic rate laws led to an overall rate law which could be fit to the carbon monoxide and nitric oxide order plots. Using isotopically oxygen labelled reactants, it was observed that the three possible isotopes of carbon dioxide were produced. A ..gamma..-CO surface species is postulated as an intermediate in the exchange process. The reaction was observed to be initially surface structure insensitive and the reaction kinetics were derived using a Langmuir-Hinshelwood formalism.

Quick, E.E.

1980-03-01T23:59:59.000Z

51

EXAFS of carbon monoxide oxidation on supported Pt fuel cell electrocatalysts  

Science Conference Proceedings (OSTI)

The potential dependence of the extended X-ray absorption fine structure (EXAFS) obtained at the Pt L{sub III} absorption edge for a carbon supported Pt electrocatalyst exposed to carbon monoxide is presented. The data have been analyzed using the difference file method to separate the dominant contributions of the Pt neighbors from contributions to the EXAFS from the adsorbed species. The presence of adsorbed CO is clearly observed with a Pt-C distance of 1.85 {angstrom} at potentials less than 0.5 V vs. RHE. Increasing the potential above 0.5 V resulted first in the removal of the adsorbed CO and at more positive potentials, e.g., 1.05 V, in the formation of an oxide layer, as evidenced by the presence of a Pt-O coordination shell at 2.00 {angstrom}. These results demonstrate that in situ EXAFS of supported Pt electrocatalysts may be used to probe adsorbate structures.

Maniguet, S.; Mathew, R.J.; Russell, A.E.

2000-03-09T23:59:59.000Z

52

Carbon Dioxide Variability and Atmospheric Circulation  

Science Conference Proceedings (OSTI)

Hourly values of the concentration of atmospheric carbon dioxide at Mauna Loa Observatory (MLO) formed the basis for an investigation of concentration fluctuations on daily to monthly time scales. In agreement with earlier studies we found no ...

James C. Sadler; Colin S. Ramage; Arnold M. Hori

1982-06-01T23:59:59.000Z

53

Retrieval of Tropospheric Carbon Monoxide Profiles from High-Resolution Interferometer Observations: A New Digital Gas Correlation (DGC)Method and Applications  

Science Conference Proceedings (OSTI)

Global tropospheric carbon monoxide (CO) distributions can be retrieved from observations by spaceborne gas correlation radiometers and high-resolution interferometers. The Measurement of Pollution in the Troposphere (MOPITT) is a gas correlation ...

Jinxue Wang; John C. Gille; Paul L. Bailey; Liwen Pan; David Edwards; James R. Drummond

1999-01-01T23:59:59.000Z

54

Carbon monoxide oxidation over three different states of copper: Development of a model metal oxide catalyst  

SciTech Connect

Carbon monoxide oxidation was performed over the three different oxidation states of copper -- metallic (Cu), copper (I) oxide (Cu{sub 2}O), and copper (II) oxide (CuO) as a test case for developing a model metal oxide catalyst amenable to study by the methods of modern surface science and catalysis. Copper was deposited and oxidized on oxidized supports of aluminum, silicon, molybdenum, tantalum, stainless steel, and iron as well as on graphite. The catalytic activity was found to decrease with increasing oxidation state (Cu > Cu{sub 2}O > CuO) and the activation energy increased with increasing oxidation state (Cu, 9 kcal/mol < Cu{sub 2}O, 14 kcal/mol < CuO, 17 kcal/mol). Reaction mechanisms were determined for the different oxidation states. Lastly, NO reduction by CO was studied. A Cu and CuO catalyst were exposed to an equal mixture of CO and NO at 300--350 C to observe the production of N{sub 2} and CO{sub 2}. At the end of each reaction, the catalyst was found to be Cu{sub 2}O. There is a need to study the kinetics of this reaction over the different oxidation states of copper.

Jernigan, G.G. [California Univ., Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States). Materials and Chemical Sciences Div.

1994-10-01T23:59:59.000Z

55

Carbon monoxide in indoor ice skating rinks: Evaluation of absorption by adult hockey players  

Science Conference Proceedings (OSTI)

We evaluated alveolar carbon monoxide (CO) levels of 122 male, adult hockey players active in recreational leagues of the Quebec City region (Canada), before and after 10 weekly 90-minute games in 10 different rinks. We also determined exposure by quantifying the average CO level in the rink during the games. Other variables documented included age, pulmonary function, aerobic capacity, and smoking status. Environmental concentrations varied from 1.6 to 131.5 parts per million (ppm). We examined the absorption/exposure relationship using a simple linear regression model. In low CO exposure levels, physical exercise lowered the alveolar CO concentration. However, we noted that for each 10 ppm of CO in the ambient air, the players had adsorbed enough CO to raise their carboxyhemoglobin (COHb) levels by 1 percent. This relationship was true both for smokers and non-smokers. We suggest that an average environmental concentration of 20 ppm of CO for the duration of a hockey game (90 minutes) should be reference limit not to be exceeded in indoor skating rinks.

Levesque, B.; Dewailly, E.; Lavoie, R.; Prud'Homme, D.; Allaire, S. (Centre hospitalier de l'Universite Laval, Quebec City (Canada))

1990-05-01T23:59:59.000Z

56

Review Article A Review on Preferential Oxidation of Carbon Monoxide in Hydrogen Rich Gases  

E-Print Network (OSTI)

In this review, recent works on the preferential oxidation of carbon monoxide in hydrogen rich gases for fuel cell applications are summarized. H2 is used as a fuel for polymer-electrolyte membrane fuel cell (PEMFC). It is produced by reforming of natural gas or liquid fuels followed by water gas shift reaction. The produced gas consists of H2, CO, and CO2. In which CO content is around 1%, which is highly poisonous for the Pt anode of the PEMFC so that further removal of CO is needed. Catalytic preferential oxidation of CO (CO-PROX) is one of the most suitable methods of purification of H2 because of high CO conversion rate at low temperature range, which is preferable for PEMFC operating conditions. Catalysts used for CO-PROX are mainly noble metal based; gold based and base metal oxide catalysts among them Copper-Ceria based catalysts are the most appropriate due to its low cost, easy availability and result obtained by these catalysts are comparable with the conventional noble metal catalysts. Copyright © 2011 by BCREC UN-

A. Mishra; R. Prasad

2010-01-01T23:59:59.000Z

57

Highly ordered magnetic mesoporous silicas for effective elimination of carbon monoxide  

Science Conference Proceedings (OSTI)

Catalysts based on crystalline nanoparticles of Fe metal supported on mesoporous silica have been developed. The synthetic process involves hydrogen reduction processing for high abundant Fe metal nanoparticles within the mesopores, in which impregnated Fe salt in the inner nanopores of mesoporous silica is thermally treated under hydrogen at 500 Degree-Sign C. Detailed characterization was achieved by XRD, XPS, BET, and HR-TEM techniques. The catalytic efficiency was demonstrated as a function of the used amounts and reaction time. The results show that more than 90% of the carbon monoxide was eliminated at room temperature during a period 80 min with 0.5 g of catalyst. - Graphical abstract: Strategy for the preparation of highly abundant Fe nanoparticle embedded MS catalyst by hydrogen reduction process and HR-TEM images of cross-sectional and top view. Highlights: Black-Right-Pointing-Pointer MS based heterogeneous catalyst with Fe nanoparticles were demonstrated for CO elimination. Black-Right-Pointing-Pointer Highly Fe nanoparticle embedded MS catalyst prepared by hydrogen reduction process. Black-Right-Pointing-Pointer Systematic characterization was achieved by XRD, XPS, BET, and HR-TEM analyses. Black-Right-Pointing-Pointer More than 90% of the CO was eliminated at RT during 80 min with 0.5 g of catalyst.

Lee, Jiho [Korea Institute of Ceramic Engineering and Technology, Seoul 153-801 (Korea, Republic of); Department of Chemistry, Inha University, Incheon 402-751 (Korea, Republic of); Ho Chang, Jeong, E-mail: jhchang@kicet.re.kr [Korea Institute of Ceramic Engineering and Technology, Seoul 153-801 (Korea, Republic of)

2012-04-15T23:59:59.000Z

58

Thermodynamic investigation into steam-methane reforming and the synthesis of methane from carbon monoxide and hydrogen  

SciTech Connect

In this study the stream-methane equilibrium reaction was investigated by considering both methane synthesis from hydrogen and carbon monoxide and by considering steam-methane reforming from methane and steam. A FORTRAN computer program was written to carry out all the calculations over a wide range of temperatures, pressures, and initial compositions. The products of each process as a function of pressure, temperature, and starting ratio of reactant gases were calculated, as well as the heats involved. In both processes the minimum ratios above which no carbon precipitates were determined as a function of temperature and pressure were given.

Wu, L.H.; Lietzke, M.H.

1976-11-01T23:59:59.000Z

59

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

DOE Green Energy (OSTI)

Several different catalytic reactions must be carried out in order to convert hydrocarbons (or alcohols) into hydrogen for use as a fuel for polyelectrolyte membrane (PEM) fuel cells. Each reaction in the fuel-processing sequence has a different set of characteristics, which influences the type of catalyst support that should be used for that particular reaction. A wide range of supports are being evaluated for the various reactions in the fuel-processing scheme, including porous and non-porous particles, ceramic and metal straight-channel monoliths, and ceramic and metal monolithic foams. These different types of support have distinctly different transport characteristics. The best choice of support for a given reaction will depend on the design constraints for the system, e.g., allowable pressure drop, and on the characteristics of the reaction for which the catalyst is being designed. Three of the most important reaction characteristics are the intrinsic reaction rate, the exothermicity/endothermicity of the reaction, and the nature of the reaction network, e.g., whether more than one reaction takes place and, in the case of multiple reactions, the configuration of the network. Isotopic transient kinetic analysis was used to study the surface intermediates. The preferential oxidation of low concentrations of carbon monoxide in the presence of high concentrations of hydrogen (PROX) is an important final step in most fuel processor designs. Data on the behavior of straight-channel monoliths and foam monolith supports will be presented to illustrate some of the factors involved in choosing a support for this reaction.

Mr. Paul Chin; Dr. Xiaolei Sun; Professor George W. Roberts; Professor James J. Spivey; Mr. Amornmart Sirijarhuphan; Dr. James G. Goodwin, Jr.; Dr. Richard W. Rice

2002-12-31T23:59:59.000Z

60

SOFT X-RAY IRRADIATION OF PURE CARBON MONOXIDE INTERSTELLAR ICE ANALOGUES  

SciTech Connect

There is an increasing evidence for the existence of large organic molecules in the interstellar and circumstellar medium. Very few among such species are readily formed in conventional gas-phase chemistry under typical conditions of interstellar clouds. Attention has therefore focused on interstellar ices as a potential source of these relatively complex species. Laboratory experiments show that irradiation of interstellar ice analogues by fast particles or ultraviolet radiation can induce significant chemical complexity. However, stars are sources of intense X-rays at almost every stage of their formation and evolution. Such radiation may thus provide chemical changes in regions where ultraviolet radiation is severely inhibited. After H{sub 2}O, CO is often the most abundant component of icy grain mantles in dense interstellar clouds and circumstellar disks. In this work we present irradiation of a pure carbon monoxide ice using a soft X-ray spectrum peaked at 0.3 keV. Analysis of irradiated samples shows formation of CO{sub 2}, C{sub 2}O, C{sub 3}O{sub 2}, C{sub 3}, C{sub 4}O, and CO{sub 3}/C{sub 5}. Comparison of X-rays and ultraviolet irradiation experiments, of the same energy dose, shows that X-rays are more efficient than ultraviolet radiation in producing new species. With the exception of CO{sub 2}, X-ray photolysis induces formation of a larger number of products with higher abundances, e.g., C{sub 3}O{sub 2} column density is about one order of magnitude higher in the X-ray experiment. To our knowledge this is the first report on X-ray photolysis of CO ices. The present results show that X-ray irradiation represents an efficient photo-chemical way to convert simple ices to more complex species.

Ciaravella, A.; Candia, R.; Collura, A. [INAF-Osservatorio Astronomico di Palermo, P.za Parlamento 1, 90134 Palermo (Italy); Jimenez-Escobar, A.; Munoz Caro, G. M. [Centro de Astrobiologia (CSIC-INTA), Carretera de Ajalvir, km 4, Torrejon de Ardoz, 28850 Madrid (Spain); Cecchi-Pestellini, C. [INAF-Osservatorio Astronomico di Cagliari, Strada n.54, Loc. Poggio dei Pini, I-09012 Capoterra (Italy); Giarrusso, S. [INAF-Istituto di Astrofisica Spaziale e Fisica Cosmica, Via U. La Malfa 153, I-90146 Palermo (Italy); Barbera, M., E-mail: aciaravella@astropa.unipa.it [Dipartimento di Scienze Fisiche and Astronomiche, Universita di Palermo, Sezione di Astronomia, Piazza del Parlamento 1, I-90134 Palermo (Italy)

2012-02-10T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Atmospheric Carbon Dioxide Record from Mauna Loa  

NLE Websites -- All DOE Office Websites (Extended Search)

SIO Air Sampling Network » Mauna Loa SIO Air Sampling Network » Mauna Loa Atmospheric Carbon Dioxide Record from Mauna Loa DOI: 10.3334/CDIAC/atg.035 graphics Graphics data Data Investigators R.F. Keeling, S.C. Piper, A.F. Bollenbacher and J.S. Walker Carbon Dioxide Research Group Scripps Institution of Oceanography University of California La Jolla, California 92093-0444, U.S.A. Period of Record 1958-2008 Methods Air samples at Mauna Loa are collected continuously from air intakes at the top of four 7-m towers and one 27-m tower. Four air samples are collected each hour for the purpose of determining the CO2 concentration. Determinations of CO2 are made by using a Siemens Ultramat 3 nondispersive infrared gas analyzer with a water vapor freeze trap. This analyzer registers the concentration of CO2 in a stream of air flowing at ~0.5

62

Atmospheric Trace Gases, Carbon Isotopes, Radionuclides, and Aerosols: Atmospheric Carbon Dioxide Data from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer (OSTI)

CDIAC products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication titled Trends Online: A Compendium of Global Change Data. Most datasets, many with numerous data files, are free to download from CDIAC's ftp area. Information related to atmospheric carbon dioxide data includes: Atmospheric Carbon Dioxide and Carbon Isotopes • Atmospheric carbon dioxide records from Mauna Loa, Hawaii • Monthly atmospheric CO2 mixing ratios and other data from the NOAA/CMDL continuous monitoring network • Data from the CSIRO GASLAB Flask Sampling Network • Atmospheric CO2 records from continuous measurements at Jubany Station, Antarctica and from 10 sites in the SIO air sampling network • Historical data from the extended Vostok ice core (2003) and the Siple Station ice core (1997) • Historical records from the Law Dome DE08, DE08-2, and DSS ice cores (1998) • AmeriFlux Carbon Dioxide, Water Vapor, and Energy Balance Measurements • Data from the Canadian Background Air Pollution Monitoring Network • Flask Samples from at U.S.S.R.-Operated Sites (1991) • The CISIRO (Australia) Monitoring Program from Aircraft for 1972-1981 • CO2 Concentrations in Surface Water and the Atmosphere during 1986-1989 NOAA/PMEL Cruises in the Pacific and Indian Oceans • Surface Water and Atmospheric CO2 and Nitrous Oxide Observations by Shipboard Automated Gas Chromatography: Results from Expeditions Between 1977 and 1990 (1992) • IPCC Working Group 1, 1994: Modeling Results Relating Future Atmospheric CO2 Concentrations to Industrial Emissions (1995). New datasets are added when available to the category of atmospheric carbon dioxide.

63

Dissociation of carbon dioxide in atmospheric pressure microchannel plasma devices.  

E-Print Network (OSTI)

??Plasma discharge of carbon dioxide at atmospheric pressure was successfully demonstrated in microchannel plasma devices at breakdown voltages lower than 1 kVRMS. Optical emissions of… (more)

Oh, Taegon

2013-01-01T23:59:59.000Z

64

Atmospheric Carbon Dioxide Record from Flask Measurements at...  

NLE Websites -- All DOE Office Websites (Extended Search)

Island Atmospheric Carbon Dioxide Record from Flask Measurements at Lampedusa Island graphics Graphics data Data Investigators Paolo Chamard, Luigi Ciattaglia, Alcide di Sarra,...

65

Transient Response of a Global Ocean-Atmosphere Model to a Doubling of Atmospheric Carbon Dioxide  

Science Conference Proceedings (OSTI)

The transient response of climate to an instantaneous increase in the atmospheric concentration of carbon dioxide has been investigated by a general circulation model of the coupled ocean-atmosphere-land system with global geography and annual ...

Syukuro Manabe; Kirk Bryan; Michael J. Spelman

1990-05-01T23:59:59.000Z

66

DETERMINATION OF CARBON IN ATMOSPHERIC AEROSOLS BY DEUTERON-INDUCED NUCLEAR REACTIONS  

E-Print Network (OSTI)

deuteron irradiation of an atmospheric aerosol sample.CARBON IN ATMOSPHERIC AEROSOLS BY DEUTERON-INDUCED NUCLEARCARBON IN ATMOSPHERIC AEROSOLS BY DEUTERON-INDUCED NUCLEAR

Clemenson, Mark

2013-01-01T23:59:59.000Z

67

Carbon Monoxide Urban Emission Monitoring: A Ground-Based FTIR Case Study  

Science Conference Proceedings (OSTI)

The characterization and the precise measurements of atmospheric pollutant’s concentration are essential to improve the understanding and modeling of urban air pollution processes. The QualAir platform at the Université Pierre et Marie Curie (UPMC)...

Y. Té; E. Dieudonné; P. Jeseck; F. Hase; J. Hadji-Lazaro; C. Clerbaux; F. Ravetta; S. Payan; I. Pépin; D. Hurtmans; J. Pelon; C. Camy-Peyret

2012-07-01T23:59:59.000Z

68

Atmospheric Circulation Response to an Instantaneous Doubling of Carbon Dioxide. Part II: Atmospheric Transient Adjustment and Its Dynamics  

Science Conference Proceedings (OSTI)

The dynamical mechanisms underlying the transient circulation adjustment in the extratropical atmosphere after the instantaneous doubling of carbon dioxide are investigated using the National Center for Atmospheric Research Community Atmosphere ...

Yutian Wu; Richard Seager; Tiffany A. Shaw; Mingfang Ting; Naomi Naik

2013-02-01T23:59:59.000Z

69

Dynamics and Disequilibrium Carbon Chemistry in Hot Jupiter Atmospheres, With Application to HD 209458b  

E-Print Network (OSTI)

Chemical equilibrium considerations suggest that, assuming solar elemental abundances, carbon on HD 209458b is sequestered primarily as carbon monoxide (CO) and methane (CH4). The relative mole fractions of CO(g) and CH4(g) in chemical equilibrium are expected to vary greatly according to variations in local temperature and pressure. We show, however, that in the p = 1--1000 mbar range, chemical equilibrium does not hold. To explore disequilibrium effects, we couple the chemical kinetics of CO and CH4 to a three-dimensional numerical model of HD 209458b's atmospheric circulation. These simulations show that vigorous dynamics caused by uneven heating of this tidally locked planet homogenize the CO and CH4 concentrations at p < 1 bar, even in the presence of lateral temperature variations of ~500--1000 K. In the 1--1000 mbar pressure range, we find that over 98% of the carbon is in CO. This is true even in cool regions where CH4 is much more stable thermodynamically. Our work shows furthermore that planets 300--500 K cooler than HD 209458b can also have abundant CO in their upper layers due to disequilibrium effects. We demonstrate several interesting observational consequences of these results.

Curtis S. Cooper; Adam P. Showman

2006-02-22T23:59:59.000Z

70

Carbon monoxide sensor for PEM fuel cell systems Christopher T. Holta,*  

E-Print Network (OSTI)

environment; Copper-halide 1. Introduction The use of hydrocarbon fuels for generating power for cars for both transportation and residential power systems. PEM fuel cells operate on hydro- gen. However, the infrastructure for hydrogen that will support large markets is decades away. The use of hydro- carbon fuels (e

Dutta, Prabir K.

71

Syngas formation in methane flames and carbon monoxide release during quenching  

SciTech Connect

Following a recent investigation into chemi-ionization and chemiluminescence during gradual aeration of small, laminar methane flames, we proposed that partial oxidation products, or syngas constituents, formed in the pre-flame zone well below the luminous region, were responsible for the observed effects. We therefore map temperature, CO, and H{sub 2} for geometries and conditions relevant to burners in domestic boiler systems, to assess the potential hazard of CO release into the ambient atmosphere, should any partial quenching occur. CO concentrations peaks of 5.5 volume % are recorded in the core surrounding the axis. Appreciable CO concentrations are also found in the absence of added air. Experiments on various burner port geometries and temperatures suggest that this is not due to air entrainment at the flame base but to diffusion from zones closer to the flame. Next, quenching surfaces such as grids, perforated plates and flame trap matrices of different metals are progressively lowered into the flame. To avoid flow line distortion, suction aspirates the quenched products. The highest emission rate occurs with the quenching plane some 4 mm above the burner; further lowering of the quenching surface causes flame extinction. The maximum CO release is close to converting 10% of the CH{sub 4} feed, with some variation with quenching material. Expressing this potential release in terms of, e.g. boiler power, predicts a potentially serious hazard. Results of numerical simulations adequately parallel the experimental sampling profiles and provide insights into local concentrations, as well as the spatially resolved CO flux, which is calculated for a parabolic inlet flow profile. Integration across the stream implies, on the basis of the simulation, a possible tripling of the experimental CO release, were quenching simply to release the local gas composition into the atmosphere. Comparison with experiment suggests some chemical interaction with the quenching surface. (author)

Weinberg, Felix; Carleton, Fred; Houdmont, Raphael [Department of Chemical Engineering, Imperial College, London (United Kingdom); Dunn-Rankin, Derek; Karnani, Sunny [Department of Mechanical and Aerospace Engineering, University of California, Irvine (United States)

2011-02-15T23:59:59.000Z

72

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents (OSTI)

A method of converting low H.sub.2 /CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200.degree. to 350.degree. C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n+1).gtoreq.x.gtoreq.O and for olefinic hydrocarbons: 2n.gtoreq.x.gtoreq.O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); Goldberg, Robert I. (Selden, NY)

1987-01-01T23:59:59.000Z

73

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents (OSTI)

A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

1985-11-06T23:59:59.000Z

74

Roles of Surface Step on Pt Nanoparticles in Electro-oxidation of Carbon Monoxide and Methanol  

DOE Green Energy (OSTI)

Design of highly active nanoscale catalysts for electro-oxidation of small organic molecules is of great importance to the development of efficient fuel cells. Increasing steps on single-crystal Pt surfaces is shown to enhance the activity of CO and methanol electro-oxidation up to several orders of magnitude. However, little is known about the surface atomic structure of nanoparticles with sizes of practical relevance, which limits the application of fundamental understanding in the reaction mechanisms established on single-crystal surfaces to the development of active, nanoscale catalysts. In this study, we reveal the surface atomic structure of Pt nanoparticles supported on multiwall carbon nanotubes, from which the amount of high-index surface facets on Pt nanoparticles is quantified. Correlating the surface steps on Pt nanoparticles with the electrochemical activity and stability clearly shows the significant role of surface steps in enhancing intrinsic activity for CO and methanol electro-oxidation. Here, we show that increasing surface steps on Pt nanoparticles of {approx}2 nm can lead to enhanced intrinsic activity up to {approx}200% (current normalized to Pt surface area) for electro-oxidation of methanol.

Lee, S.W.; Vescovo, E.; Chen, S.; Sheng, W.; Yabuuchi, N.; Kim, Y.T.; Mitani, T.; Shao-Horn, Y.

2009-10-13T23:59:59.000Z

75

Phase relation between global temperature and atmospheric carbon dioxide  

E-Print Network (OSTI)

The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause for temperature variations. In this paper we discuss this assumption and analyze it on basis of bi-centenary measurements and using a relaxation model which causes phase shifts and delays.

Stallinga, Peter

2013-01-01T23:59:59.000Z

76

Atmospheric Radon Measurements in the Arctic; Fronts, Seasonal Observations, and Transport of Continental Air to Polar Regions  

Science Conference Proceedings (OSTI)

Radon was determined in the atmosphere over the Arctic Ocean in flights of a United States Naval Research Laboratory aircraft in April and May 1974. Simultaneously collected air samples were analyzed for carbon monoxide, methane, ...

P. E. Wilkniss; R. E. Larson

1984-08-01T23:59:59.000Z

77

Observations of Middle Atmosphere CO from the UARS ISAMS during the Early Northern Winter 1991/92  

Science Conference Proceedings (OSTI)

Structure and kinematics of carbon monoxide in the upper stratosphere and lower mesosphere (10–0.03 hPa) are studied for the early northern winter 1991/92 using the Upper Atmosphere Research Satellite Improved Stratospheric and Mesospheric ...

D. R. Allen; J. L. Stanford; M. A. López-Valverde; N. Nakamura; D. J. Lary; A. R. Douglass; M. C. Cerniglia; J. J. Remedios; F. W. Taylor

1999-02-01T23:59:59.000Z

78

Multiple-Century Response of a Coupled Ocean-Atmosphere Model to an Increase of Atmospheric Carbon Dioxide  

Science Conference Proceedings (OSTI)

To speculate on the future change of climate over several centuries, three 500-year integrations of a coupled ocean-atmosphere model were performed. In addition to the standard integration in which the atmospheric concentration of carbon dioxide ...

Syukuro Manabe; Ronald J. Stouffer

1994-01-01T23:59:59.000Z

79

Atmospheric Plasma Deposition of Diamond-like Carbon Coatings  

DOE Green Energy (OSTI)

DLC coatings in a low-pressure environment. For example, ion beam processes are widely utilized since the ion bombardment is thought to promote denser sp3-bonded carbon networks. Other processes, such as sputtering, are better suited for coating large parts [29,30,44]. However, the deposition of DLC in a vacuum system has several disadvantages, including high equipment cost and restrictions on the size and shape of material that may be treated. The deposition of DLC at atmospheric pressure has been demonstrated by several researchers. Izake, et al [53] and Novikov and Dymont [54] have demonstrated an electrochemical process that is carried out with organic compounds such as methanol and acetylene dissolved in ammonia. This process requires that the substrates be immersed in the liquid [53-54]. The atmospheric pressure deposition of DLC was also demonstrated by Kulik, et al. utilizing a plasma torch. However, this process requires operating temperatures in excess of 800 oC [55]. In this report, we investigate the deposition of diamond-like carbon films using a low temperature, atmospheric pressure plasma-enhanced chemical vapor deposition (PECVD) process. The films were characterized by solid-state carbon-13 nuclear magnetic resonance (13C NMR) and found to have a ratio of sp2 to sp3 carbon of 43 to 57%. The films were also tested for adhesion, coefficient of friction, and dielectric strength.

Ladwig, Angela

2008-01-23T23:59:59.000Z

80

HIGH-TEMPERATURE REACTIONS OF TYPE 304 STAINLESS STEEL IN LOW CONCENTRATIONS OF CARBON DIOXIDE AND CARBON MONOXIDE  

SciTech Connect

Compatibility studies of type 304 stainless steel in helium containing low concentrations of CO and CO/sub 2/ were conducted. The oxidation rates were insensitive to impurity concentrations between 0.0006--0.3 vol% in the temperature range 400--1000 deg C when P/sub co2/P/sub co/ was less than 0.66. Ratios above this value resulted initially in a slow oxidation rate, but was followed by an accelerated attack. The incubation period for the break-away varied with the P/sub co2//P/sub co/ ratio and the pressure of the two gases. The oxidation reactions proceeded through a selective depletion of chromium from the alloy which increased the carbon solubility and depletion of nickel which led to the transformation of austenite to ferrite. Parabolic reaction rates were observed for the formation of the protective oxides. Arrhenius plots of rate constants versus 1/T indicated the presence of several oxides which was confirmed by other methods. Carburization or decarburization reactions occurred coincidentally with oxidation and depended upon temperature and (P/sub CO/)/sup 2/ /P/sub CO2/ and the P/sub co2//P /sub CO/. Neither was detected below 600 deg C. Between 600--900 deg C, only carburization occurred and appeared to be mainly dependent on the temperature. Above 900 deg C, both carburization and decarburization occurred depending upon the (P/sub co/)/sup 2//P/sub co2/ and the P/sub co2//P/sub co/. The interactions of the oxidizing and carburization reactions resulted in carbon maxima at a (P/sub co/)/sup 2//P/sub co2/ ratio of 0.227. The results indicate that it may be impractical or unnecessary to reduce impurity gases to levels which do not cause surface reactions. It is concluded that undesirable oxidation and carburization reactions can be eliminated by controlling the ratios of the impurity gases. (auth)

Inouye, H.

1962-08-29T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The effects of atmospheric pressure plasma on the synthesis of carbon nanotubes  

Science Conference Proceedings (OSTI)

In this study, we investigated the effects of atmospheric plasma on the synthesis of carbon nanotubes (CNTs) forests. Tall and high CNTs forests have been successfully grown on a large scale using a newly developed system called atmospheric pressure ... Keywords: Atmospheric pressure, Carbon nanotubes, Mass production, Plasma effects, Plasma enhanced chemical vapor deposition

Seok Seung Shin; Bum Ho Choi; Young Mi Kim; Jong Ho Lee; Dong Chan Shin

2009-04-01T23:59:59.000Z

82

Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615  

SciTech Connect

Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

Wayland, B.B.

2009-08-31T23:59:59.000Z

83

Large-Scale Changes of Soil Wetness Induced by an Increase in Atmospheric Carbon Dioxide  

Science Conference Proceedings (OSTI)

The change in soil wetness in response to an increase of atmospheric concentration of carbon dioxide is investigated by two versions of a climate model which consists of a general circulation model of the atmosphere and a static mixed layer ...

S. Manabe; R. T. Wetherald

1987-04-01T23:59:59.000Z

84

Atmospheric Carbon Dioxide and the Global Carbon Cycle: The Key Uncertainties  

DOE R&D Accomplishments (OSTI)

The biogeochemical cycling of carbon between its sources and sinks determines the rate of increase in atmospheric CO{sub 2} concentrations. The observed increase in atmospheric CO{sub 2} content is less than the estimated release from fossil fuel consumption and deforestation. This discrepancy can be explained by interactions between the atmosphere and other global carbon reservoirs such as the oceans, and the terrestrial biosphere including soils. Undoubtedly, the oceans have been the most important sinks for CO{sub 2} produced by man. But, the physical, chemical, and biological processes of oceans are complex and, therefore, credible estimates of CO{sub 2} uptake can probably only come from mathematical models. Unfortunately, one- and two-dimensional ocean models do not allow for enough CO{sub 2} uptake to accurately account for known releases. Thus, they produce higher concentrations of atmospheric CO{sub 2} than was historically the case. More complex three-dimensional models, while currently being developed, may make better use of existing tracer data than do one- and two-dimensional models and will also incorporate climate feedback effects to provide a more realistic view of ocean dynamics and CO{sub 2} fluxes. The instability of current models to estimate accurately oceanic uptake of CO{sub 2} creates one of the key uncertainties in predictions of atmospheric CO{sub 2} increases and climate responses over the next 100 to 200 years.

Peng, T. H.; Post, W. M.; DeAngelis, D. L.; Dale, V. H.; Farrell, M. P.

1987-12-00T23:59:59.000Z

85

Carbon nanostructures production by AC arc discharge plasma process at atmospheric pressure  

Science Conference Proceedings (OSTI)

Carbon nanostructures have received much attention for a wide range of applications. In this paper, we produced carbon nanostructures by decomposition of benzene using AC arc discharge plasma process at atmospheric pressure. Discharge was carried out ...

Shenqiang Zhao; Ruoyu Hong; Zhi Luo; Haifeng Lu; Biao Yan

2011-01-01T23:59:59.000Z

86

Remote sounding of the mixing ratio of carbon dioxide in the atmosphere from a satellite  

SciTech Connect

Carbon dioxide is the most important atmospheric constituent contributing to the greenhouse effect in the earth-atmosphere system. Here, a method is presented for the remote sounding of the mixing ratio of carbon dioxide in the atmosphere from a satellite, including the inversion method and preliminary calculation results. The results indicate that the measurement accuracy of the mixing ratio of carbon dioxide in 0.25 ppm, calculated according to volume, in ground field of view of 1,127 x 1,162 km[sup 2] for an instrument such as the HIRS-2 on the US National Oceanographic and Atmospheric Administration meteorological satellite.

Zhaoxian Zhang (Shangai Inst. of Technical Physics (China))

1993-03-01T23:59:59.000Z

87

Climate Impacts of Atmospheric Sulfate and Black Carbon Aerosols  

SciTech Connect

Although the global average surface temperature has increased by about 0.6°C during the last century (IPCC, 2001), some regions such as East Asia, Eastern North America, and Western Europe have cooled rather than warmed during the past decades (Jones, 1988; Qian and Giorgi, 2000). Coherent changes at the regional scale may reflect responses to different climate forcings that need to be understood in order to predict the future net climate response at the global and regional scales under different emission scenarios. Atmospheric aerosols play an important role in global climate change (IPCC 2001). They perturb the earth’s radiative budget directly by scattering and absorbing solar and long wave radiation, and indirectly by changing cloud reflectivity, lifetime, and precipitation efficiency via their role as cloud condensation nuclei. Because aerosols have much shorter lifetime (days to weeks) compared to most greenhouse gases, they tend to concentrate near their emission sources and distribute very unevenly both in time and space. This non-uniform distribution of aerosols, in conjunction with the greenhouse effect, may lead to differential net heating in some areas and net cooling in others (Penner et al. 1994). Sulfate aerosols come mainly from the oxidation of sulfur dioxide (SO2) emitted from fossil fuel burning. Black carbon aerosols are directly emitted during incomplete combustion of biomass, coal, and diesel derived sources. Due to the different optical properties, sulfate and black carbon affect climate in different ways. Because of the massive emissions of sulfur and black carbon that accompany the rapid economic expansions in East Asia, understanding the effects of aerosols on climate is particularly important scientifically and politically in order to develop adaptation and mitigation strategies.

Qian, Yun; Song, Qingyuan; Menon, Surabi; Yu, Shaocai; Liu, Shaw C.; Shi, Guangyu; Leung, Lai R.; Luo, Yunfeng

2008-09-19T23:59:59.000Z

88

Integrated Removal of NOx with Carbon Monoxide as Reductant, and Capture of Mercury in a Low Temperature Selective Catalytic and Adsorptive Reactor  

SciTech Connect

Coal will likely continue to be a dominant component of power generation in the foreseeable future. This project addresses the issue of environmental compliance for two important pollutants: NO{sub x} and mercury. Integration of emission control units is in principle possible through a Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR) in which NO{sub x} removal is achieved in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The capture of mercury is integrated into the same process unit. Such an arrangement would reduce mercury removal costs significantly, and provide improved control for the ultimate disposal of mercury. The work completed in this project demonstrates that the use of CO as a reductant in LTSCR is technically feasible using supported manganese oxide catalysts, that the simultaneous warm-gas capture of elemental and oxidized mercury is technically feasible using both nanostructured chelating adsorbents and ceria-titania-based materials, and that integrated removal of mercury and NO{sub x} is technically feasible using ceria-titania-based materials.

Neville Pinto; Panagiotis Smirniotis; Stephen Thiel

2010-08-31T23:59:59.000Z

89

Elevated atmospheric carbon dioxide in agroecosystems affects groundwater quality  

Science Conference Proceedings (OSTI)

Increasing atmospheric carbon dioxide (CO{sub 2}) concentration has led to concerns about global changes to the environment. One area of global change that has not been addressed is the effect of elevated atmospheric CO{sub 2} on groundwater quality below agroecosystems. Elevated CO{sub 2} concentration alterations of plant growth and C/N ratios may modify C and N cycling in soil and affect nitrate (NO{sub 3}{sup {minus}}) leaching to groundwater. This study was conducted to examine the effects of a legume (soybean [Glycine max (L.) Merr.]) and a nonlegume (grain sorghum [Sorghum bicolor (L.) Moench]) CO{sub 2}-enriched agroecosystems on NO{sub 3}{sup {minus}} movement below the root zone in a Blanton loamy sand (loamy siliceous, thermic, Grossarenic Paleudults). The study was a split-plot design replicated three times with plant species (soybean and grain sorghum) as the main plots and CO{sub 2} concentration ({approximately}360 and {approximately}720 {mu}L L{sup {minus}1} CO{sub 2}) as subplots using open-top field chambers. Fertilizer application was made with {sup 15}N-depleted NH{sub 4}NO{sub 3} to act as a fertilizer tracer. Soil solution samples were collected weekly at 90-cm depth for a 2-yr period and monitored for NO{sub 3}{sup {minus}}-N concentrations. Isotope analysis of soil solution indicated that the decomposition of organic matter was the primary source of No{sub 3}{sup {minus}}-N in soil solution below the root zone through most of the monitoring period. Significant differences were observed for NO{sub 3}{sup {minus}}-N concentrations between soybean and grain sorghum, with soybean having the higher NO{sub 3}{sup {minus}}-N concentration. Elevated CO{sub 2} increased total dry weight, total N content, and C/N ratio of residue returned to soil in both years. Elevated CO{sub 2} significantly decreased NO{sub 3}{sup {minus}}-N concentrations below the root zone in both soybean and grain sorghum. 37 refs., 2 figs., 2 tabs.

Torbert, H.A. [Blackland, Soil and Water Research Lab., Temple, TX (United States); Prior, S.A.; Rogers, H.H. [National Soil Dynamics Lab., Auburn, AL (United States); Schlesinger, W.H. [Duke Univ., Durham, NC (United States); Mullins, G.L.; Runion, G.B. [Auburn Univ., AL (United States)

1996-07-01T23:59:59.000Z

90

Might Carbon-Atmosphere White Dwarfs Harbour a New Type of Pulsating Star?  

E-Print Network (OSTI)

In the light of the recent and unexpected discovery of a brand new type of white dwarfs, those with carbon-dominated atmospheres, we examine the asteroseismological potential of such stars. The motivation behind this is based on the observation that past models of carbon-atmosphere white dwarfs have partially ionized outer layers that bear strong resemblance with those responsible for mode excitation in models of pulsating DB (helium-atmosphere) and pulsating DA (hydrogen-atmosphere) white dwarfs. Our exciting main result is that, given the right location in parameter space, some carbon-atmosphere white dwarfs are predicted to show pulsational instability against gravity modes. We are eagerly waiting the results of observational searches for luminosity variations in these stars.

G. Fontaine; P. Brassard; P. Dufour

2008-03-14T23:59:59.000Z

91

TRENDS Online - Carbon Flux to the Atmosphere from Land-Use Change  

NLE Websites -- All DOE Office Websites (Extended Search)

Trends graphic Carbon Flux to the Atmosphere from Land-Use Changes 1850-2005 Richard A. Houghton The Woods Hole Research Center, 149 Woods Hole Road, Falmouth, Massachusetts 02540,...

92

Development of an Implementation Plan for Atmospheric Carbon Monitoring in California  

E-Print Network (OSTI)

carbon dioxide on very tall towers: results of the NOAA/CMDLDioxide on a Very Tall Tower. Tellus Series B-Chemical &vapor measurements from a tall tower. JGR-Atmospheres 109:

Fischer, Marc L.; Riley, William J.; Tonse, Shaheen

2004-01-01T23:59:59.000Z

93

Responses of primary production and total carbon storage to changes in climate and atmospheric CO? concentration  

E-Print Network (OSTI)

The authors used the terrestrial ecosystem model (TEM, version 4.0) to estimate global responses of annual net primary production (NPP) and total carbon storage to changes in climate and atmospheric CO2, driven by the ...

Xiao, Xiangming.; Kicklighter, David W.; Melillo, Jerry M.; McGuire, A. David.; Stone, Peter H.; Sokolov, Andrei P.

94

Contrasting Regional Responses to Increasing Leaf-Level Atmospheric Carbon Dioxide over Australia  

Science Conference Proceedings (OSTI)

Using a coupled atmosphere–land surface model, simulations were conducted to characterize the regional climate changes that result from the response of stomates to increases in leaf-level carbon dioxide (CO2) under differing conditions of ...

Faye T. Cruz; Andrew J. Pitman; John L. McGregor; Jason P. Evans

2010-04-01T23:59:59.000Z

95

Modern Records of Atmospheric Carbon Dioxide (CO2) and a 2000-year Ice-core  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Dioxide (CO2) » Ice Cores Carbon Dioxide (CO2) » Ice Cores Modern Records of Atmospheric Carbon Dioxide (CO2) and a 2000-year Ice-core Record from Law Dome, Antarctica Introduction This page provides an introduction and links to records of atmospheric carbon dioxide (CO2) concentrations over the last 2000 years, emphasizing large data bases each representing many currently active stations. Records since about 1960 (depending on location) have been obtained from samples of ambient-air at remote stations, which represent changing global atmospheric concentrations rather than influences of local sources. The longer (2000-year) record is from the Law Dome ice core in Antarctica. The ice-core record has been merged with modern annual data from Cape Grim, Tasmania to provide a 2000-year record ending with the most recent data. A

96

Short-range atmospheric dispersion of carbon dioxide  

E-Print Network (OSTI)

important. We model dense gas dispersion using the steady-eld data to analyze dense gas dispersion mod- eling issues.element modeling of gas dispersion in the atmosphere. In:

Cortis, A.

2010-01-01T23:59:59.000Z

97

Evaluating the Carbon Cycle of a Coupled Atmosphere-Biosphere Model  

SciTech Connect

We investigate how well a coupled biosphere-atmosphere model, CCM3-IBIS, can simulate the functioning of the terrestrial biosphere and the carbon cycling through it. The simulated climate is compared to observations, while the vegetation cover and the carbon cycle are compared to an offline version of the biosphere model IBIS forced with observed climatic variables. The simulated climate presents some local biases that strongly affect the vegetation (e.g., a misrepresentation of the African monsoon). Compared to the offline model, the coupled model simulates well the globally averaged carbon fluxes and vegetation pools. The zonal mean carbon fluxes and the zonal mean seasonal cycle are also well represented except between 0{sup o} and 20{sup o}N due to the misrepresentation of the African monsoon. These results suggest that, despite regional biases in climate and ecosystem simulations, this coupled atmosphere-biosphere model can be used to explore geographic and temporal variations in the global carbon cycle.

Delire, C; Foley, J A; Thompson, S

2002-08-21T23:59:59.000Z

98

Method for producing carbon nanotubes  

DOE Patents (OSTI)

Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

Phillips, Jonathan (Santa Fe, NM); Perry, William L. (Jemez Springs, NM); Chen, Chun-Ku (Albuquerque, NM)

2006-02-14T23:59:59.000Z

99

Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef*  

E-Print Network (OSTI)

1 Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef* and J. M applications (1, 2) . Synthesis gas or syngas (mixture of hydrogen and carbon monoxide) are used as a major. The conventional reformers allowing syngas production are based on steam reforming of hydrocarbons (3) following

Paris-Sud XI, Université de

100

Bayesian Modelling Volatility of Growth Rate in Atmospheric Carbon Dioxide Concentrations  

Science Conference Proceedings (OSTI)

Atmospheric gases, such as carbon dioxide, ozone, methane, nitrous oxide, and etc., create a natural greenhouse effect and cause climate change. Therefore, modelling behavior of these gases could help policy makers to control greenhouse effects. In a ... Keywords: Stochastic volatility, Smooth transition autoregressive, Markov chain Monte Carlo, methods, Bayesian, ARCH, GARCH

Esmail Amiri

2009-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Carbon Flux to the Atmosphere From Land-use Changes: 1850 to 1990  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Flux to the Atmosphere From Land-use Changes: 1850 to 1990 Carbon Flux to the Atmosphere From Land-use Changes: 1850 to 1990 (NDP-050/R1) DOI: 10.3334/CDIAC/lue.ndp050 data Data PDF PDF The PDF of NDP-050/R1 (body of report, plus appendices A through E) and tellus51b.pdf (Appendix F, reprint of Houghton paper in Tellus, Vol. 51B; copyright 1999 Blackwell Publishing Ltd and reprinted with kind permission from the publisher) Contributors Richard A. Houghton Joseph L. Hackler The Woods Hole Research Center Woods Hole, Massachusetts Please Note: Revised data through the year 2000 are available in CDIAC's Trends Online. Prepared by Robert M. Cushman Carbon Dioxide Information Analysis Center Environmental Sciences Division Publication No. 5054 Date Published: February 2001 Prepared for the Environmental Sciences Division Office of Biological and Environmental Research

102

Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol  

SciTech Connect

A detailed understanding of the sources, transformations, and fates of organic species in the environment is crucial because of the central roles that organics play in human health, biogeochemical cycles, and Earth's climate. However, such an understanding is hindered by the immense chemical complexity of environmental mixtures of organics; for example, atmospheric organic aerosol consists of at least thousands of individual compounds, all of which likely evolve chemically over their atmospheric lifetimes. Here we demonstrate the utility of describing organic aerosol (and other complex organic mixtures) in terms of average carbon oxidation state (OSC), a quantity that always increases with oxidation, and is readily measured using state-of-the-art analytical techniques. Field and laboratory measurements of OSC , using several such techniques, constrain the chemical properties of the organics and demonstrate that the formation and evolution of organic aerosol involves simultaneous changes to both carbon oxidation state and carbon number (nC).

Massachusetts Institute of Technology; Kroll, Jesse H.; Donahue, Neil M.; Jimenez, Jose L.; Kessler, Sean H.; Canagaratna, Manjula R.; Wilson, Kevin R.; Altieri, Katye E.; Mazzoleni, Lynn R.; Wozniak, Andrew S.; Bluhm, Hendrik; Mysak, Erin R.; Smith, Jared D.; Kolb, Charles E.; Worsnop, Douglas R.

2010-11-05T23:59:59.000Z

103

Influence of temperature, moisture, and organic carbon on the flux of H/sub 2/ and CO between soil and atmosphere: field studies in subtropical regions  

Science Conference Proceedings (OSTI)

Production and deposition rates of atmospheric hydrogen and carbon monoxide were studied during field measurements in subtropical regions, i.e., Transvaal (South Africa), Andalusia (Spain), and the Karoo (South Africa). Measurements were carried out by applying static and equilibrium box techniques. The equilibrium technique has been introduced as a novel method to measure production and destruction rates simultaneously even when soil conditions (e.g., temperature) change during the course of the measurements. Deposition velocities of H/sub 2/ and CO were virtually independent of the soil temperature measured in 3- to 10-mm depths and agreed with those measured in the temperate regions. The deposition velocities were inhibited or stimulated by irrigation water depending on the conditions of the individual field sites. H/sub 2/ production by soil was not observed. By contrast, CO was produced by soil in a dark chemical reaction. Production rates increased exponentially with soil temperatures, giving activation energies of 57-110 kJ mol/sup -1/ and increased linearly with soil organic carbon content. CO production rates followed a diel rhythm parallel to soil surface temperatures. Production generally exceeded CO deposition during the hot hours of the day, so that arid subtropical soils act as a net source of atmospheric CO during this time. On a global basis, CO production by soil may reach source strengths of 30 Tg yr/sup -1/, which is considerably less than the global deposition of CO estimated to be 190-580 Tg yr/sup -1/. Global H/sub 2/ deposition rates were estimated to 70-110 Tg yr/sup -1/.

Conrad, R.; Seiler, W.

1985-06-20T23:59:59.000Z

104

Atmospheric Measurements of Climate-Relevant Species  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Measurements of Climate-Relevant Species Atmospheric Measurements of Climate-Relevant Species CDIAC's data collection includes measurements of the following climate-relevant chemical species. A summary of recent greenhouse gas concentrations is also available. To determine how compounds are named, see the CDIAC "Name that compound" page. Butane (C4H10) Carbon Dioxide (CO2) Carbon Isotopes Carbon Monoxide (CO) Carbon Tetrachloride (CCl4) Chlorofluorocarbons Chloroform (CHCl3) Deuterium (2H) Ethane (C2H6) Ethyl Nitrate (C2H5ONO2) Ethyne (C2H2) Fluoroform (CHF3) Halogenated Compounds (modern records) Halons (fluorocarbons) Hydrogen (H2) Hydrochlorofluorocarbons (HCFCs) Hydrofluorocarbons (HFCs) i-Propyl Nitrate (C3H7ONO2) Methane (CH4) Methyl Bromide (CH3Br) Methyl Chloride (CH3Cl) Methyl Chloroform (CH3CCl3)

105

Low Cost Open-Path Instrument for Monitoring Atmospheric Carbon Dioxide at Sequestration Sites  

NLE Websites -- All DOE Office Websites (Extended Search)

Low Cost open-path Instrument for Low Cost open-path Instrument for monItorIng atmospherIC Carbon DIoxIDe at sequestratIon sItes Background Growing concern over the effect on global climate of the buildup of greenhouse gases (GHG), particularly carbon dioxide (CO 2 ), in the atmosphere may lead to the curtailment of CO 2 emissions. One potential course of action by industry to reduce GHG emissions is the subsurface disposal of CO 2 . An important requirement of such disposal is verification that the injected gases remain in place and do not leak to the surface. Perhaps the most direct evidence of a successful sequestration project is the lack of a detectable CO 2 concentration above the background level in the air near the ground. Although measurement of CO 2 concentration can be performed, it is

106

Atmospheric Carbon Dioxide Record from In Situ Measurements at Baring Head  

NLE Websites -- All DOE Office Websites (Extended Search)

Baring Head Baring Head Atmospheric Carbon Dioxide Record from In Situ Measurements at Baring Head graphics Graphics data Data Investigators M.R. Manning, A.J. Gomez, K.P. Pohl National Institute of Water and Atmospheric Research, Ltd., Climate Division, Gracefield Road, Gracefield, P.O. Box 31-311, Lower Hutt, New Zealand Period of Record 1970-93 Methods Determinations of atmospheric CO2 mixing ratios are made using a Siemens Ultramat-3 nondispersive infrared (NDIR) gas analyzer. The NDIR CO2 analyzer is connected via a gas manifold consisting of stainless steel tubing and computer-controlled solenoid switches to 12 gas cylinders and 2 sample air lines. The NDIR analyzer compares ambient air CO2 mixing ratios relative to known CO2 mixing ratios in tanks of compressed reference gases.

107

In situ Carbon 13 and Oxygen 18 Ratios of Atmospheric CO2 from Cape Grim,  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxygen Isotopes and Ratios » 13C and 18O Oxygen Isotopes and Ratios » 13C and 18O Ratios, Atmospheric CO2, Cape Grim In situ Carbon 13 and Oxygen 18 Ratios of Atmospheric CO2 from Cape Grim, Tasmania, Australia: 1982-1993 DOI: 10.3334/CDIAC/atg.db1014 data Data Investigators Francey R. J. and C. E. Allison Description Since 1982, a continuous program of sampling atmospheric CO2 to determine stable isotope ratios has been maintained at the Australian Baseline Air Pollution Station, Cape Grim, Tasmania (40°, 40'56"S, 144°, 41'18"E). The process of in situ extraction of CO2 from air, the preponderance of samples collected in conditions of strong wind from the marine boundary layer of the Southern Ocean, and the determination of all isotope ratios relative to a common high purity CO2 reference gas with isotopic δ13C close to

108

Carbon Flux to the Atmosphere from Land-Use Changes: 1850 to 1990  

DOE Green Energy (OSTI)

The database documented in this numeric data package, a revision to a database originally published by the Carbon Dioxide Information Analysis Center (CDIAC) in 1995, consists of annual estimates, from 1850 through 1990, of the net flux of carbon between terrestrial ecosystems and the atmosphere resulting from deliberate changes in land cover and land use, especially forest clearing for agriculture and the harvest of wood for wood products or energy. The data are provided on a year-by-year basis for nine regions (North America, South and Central America, Europe, North Africa and the Middle East, Tropical Africa, the Former Soviet Union, China, South and Southeast Asia, and the Pacific Developed Region) and the globe. Some data begin earlier than 1850 (e.g., for six regions, areas of different ecosystems are provided for the year 1700) or extend beyond 1990 (e.g., fuelwood harvest in South and Southeast Asia, by forest type, is provided through 1995). The global net flux during the period 1850 to 1990 was 124 Pg of carbon (1 petagram = 10{sup 15} grams). During this period, the greatest regional flux was from South and Southeast Asia (39 Pg of carbon), while the smallest regional flux was from North Africa and the Middle East (3 Pg of carbon). For the year 1990, the global total net flux was estimated to be 2.1 Pg of carbon.

Houghton, R.A.

2001-02-22T23:59:59.000Z

109

The Atmospheric Chemistry of Iodine Monoxide  

Science Conference Proceedings (OSTI)

... of I, and C1, or by reaction of 0 with a mixture of IC1 and CIO,. ... Stein, SE; Rukkers, JM; Brown, RM NIST Structures & Properties Database; ver. ...

2011-10-18T23:59:59.000Z

110

Atmospheric Carbon Dioxide Record from In Situ Measurements at Mt. Cimone  

NLE Websites -- All DOE Office Websites (Extended Search)

Mt. Cimone Mt. Cimone Atmospheric Carbon Dioxide Record from In Situ Measurements at Mt. Cimone graphics Graphics data Data Investigators Tiziano Colombo and Riccardo Santaguida Italian Meteorological Service, Via delle Ville, 100-41029 Sestola (MO), Italy Period of Record 1979-1997 Methods Continuous atmospheric CO2 measurements have been carried out at Mt. Cimone since 1979. Since December 1988, air samples have also been collected approximately once per week in a pair of 2-L, electropolished, stainless steel cylindrical flasks. From 1979 until December 1988, a Hartmann and Braun URAS-2T NDIR gas analyzer was used for CO2 determinations. Currently, CO2 determinations are made through the use of a Siemens Ultramat-5E NDIR gas analyzer. Water vapor is eliminated by passing the air through a U-tube

111

Composition and decomposition of soybean and sorghum tissues grown under elevated atmospheric carbon dioxide  

Science Conference Proceedings (OSTI)

It has been hypothesized that changes in both quantity and quality of plant residue inputs to soils as atmospheric carbon dioxide (CO{sub 2}) concentration increases may alter carbon (C) and nitrogen (N) turnover rates and pool sizes. We determined the effect of elevated atmospheric CO{sub 2} on plant tissue quality, and how modifications in tissue quality affect C and N mineralization. Soybean and sorghum were grown under elevated (704.96 {plus_minus} 0.33 {mu}mol CO{sub 2} mol{sup {minus}1}) and ambient (357.44 {plus_minus} 0.12 {mu}mol CO{sub 2} mol{sup {minus}1}) atmospheric CO{sub 2} in open-top chambers. Leaf and stem tissues were separated form harvested plants and analyzed for C,N, lignin, and cellulose. Tissues were applied to Norfolk loamy sand (fine-loamy, siliceous, thermic Typic Kandiudult) and aerobically incubated for 70-d to determine C and N mineralization, C turnover, relative N mineralization, and C/N mineralized. Elevated CO{sub 2} had no effect on plant residue C concentration, but N concentration of soybean leaves and stems and sorghum stems was reduced; however, CO{sub 2} enrichment increased C/N ratio and lignin concentration for only sorghum stems and soybean leaves, respectively. Source of plant residue (i.e., produced under either elevated or ambient CO{sub 2}) had no impact on soil C turnover, relative N mineralization, cumulative C and N mineralization, and C/N mineralized. These data suggest that increasing atmospheric CO{sub 2} will have little effect on composition or decomposition of field crop residues. Thus, since CO{sub 2} enrichment results in increased photosynthetic C fixation, the possibility exists for increased soil C storage under field crops in an elevated CO{sub 2} world. 29 refs., 4 figs., 4 tabs.

Henning, F.P. [Cooperative Ext. Serv., Dunwoody, GA (United States); Wood, C.W. [Auburn Univ., AL (United States); Rogers, H.H.; Runion, G.B.; Prior, S.A. [National Soil Dynamics Lab., Auburn, AL (United States)

1996-07-01T23:59:59.000Z

112

Plasmachemical Synthesis of Carbon Suboxide  

E-Print Network (OSTI)

A nonthermal carbon monoxide plasma is known to produce a solid deposition which is thought to be a polymer of carbon suboxide (C3O2); however there are very few investigations of this deposition in the literature. This thesis contains an analysis of the theoretical thermodynamics and kinetics of carbon suboxide formation as well as experimental results. The theoretical analysis suggests that carbon suboxide may be an equilibrium product even at ambient conditions but favors lower temperatures; furthermore if solid carbon is considered to be kinetically limited, and therefore not a product, then carbon suboxide is more likely to be a product under these pseudo-equilibrium conditions. Experimentally, solid films were produced in a dielectric barrier discharge (DBD) containing pure carbon monoxide. Optical emission spectroscopy was used to analyze the plasma and models of the emission spectra were created to determine the plasma temperatures. Deposition rates were determined to be on the order of 0.2 mg/min at a power of about 10W; it is expected however that these conditions are not optimized. The overall kinetics of carbon suboxide was analyzed and optimal conditions for operation can be estimated. Characterization of the solid depositions were carried out using Solid State Nuclear Magnetic Resonance (NMR), Fourier Transform Infrared Spectroscopy (FTIR), Electrospray Ionization Mass Spectroscopy (ESI-MS), and Matrix-assisted Laser Desorption Ionization Mass Spectroscopy (MALDI-MS). The characteristics of the film are very comparable to hydrolyzed carbon suboxide polymer suggesting that carbon suboxide polymer were in fact created in the carbon monoxide plasma at atmospheric conditions.

Geiger, Robert

2013-05-01T23:59:59.000Z

113

Response of a Coupled Ocean–Atmosphere Model to Increasing Atmospheric Carbon Dioxide: Sensitivity to the Rate of Increase  

Science Conference Proceedings (OSTI)

The influence of differing rates of increase of the atmospheric CO2 concentration on the climatic response is investigated using a coupled ocean–atmosphere model. Five transient integrations are performed each using a different constant ...

Ronald J. Stouffer; Syukuro Manabe

1999-08-01T23:59:59.000Z

114

CARBON FLUX TO THE ATMOSPHERE FROM LAND-USE CHANGES: 1850 TO 1990 (APPENDIX  

NLE Websites -- All DOE Office Websites (Extended Search)

E: FULL LISTING OF COMPARE.DAT (FILE 4) E: FULL LISTING OF COMPARE.DAT (FILE 4) The following is a full listing of ascii file compare.dat (File 4), which is also provided, in binary spreadsheet format, as file compare.wk1 (File 5). This file compares the estimated global total net flux of carbon to the atmosphere from land-use change, from 1850 to 1990, by year, for this database (Houghton 1999) and three earlier publications (Houghton et al. 1983, Houghton and Skole 1990, and Houghton and Hackler 1995). Note that the data for the period 1850 through 1859 attributed below to Houghton et al. (1983) were not actually presented in that publication but are present in the data used in that publication. Units = Pg of carbon (1 petagram = 1015 grams); -9.999 denotes missing value Year Houghton Houghton Houghton Houghton

115

CARBON FLUX TO THE ATMOSPHERE FROM LAND-USE CHANGES: 1850 TO 1990 (APPENDIX  

NLE Websites -- All DOE Office Websites (Extended Search)

D: FULL LISTING OF NDP050.DAT (FILE 2) D: FULL LISTING OF NDP050.DAT (FILE 2) The following is a full listing of ascii file ndp050.dat (File 2), which is also provided, in binary spreadsheet format, as file ndp050.wk1 (File 3). This file lists the estimated net flux of carbon, in units of 1000 Gg of carbon (1 gigagram = 109 g), to the atmosphere from land-use change, from 1850 through 1990, by year and by region, along with the global totals. The values in this listing replace the values in files netflux.* in Houghton and Hackler (1995), the previous version of this database. Year North South and Europe North Tropical Former China South and Pacific TOTAL America Central Africa and Africa Soviet Southeast Developed FLUX America Middle East Union Asia Region

116

Transient Response of the Hadley Centre Coupled Ocean-Atmosphere Model to Increasing Carbon Dioxide. Part III: Analysis of Global-Mean Response Using Simple Models  

Science Conference Proceedings (OSTI)

The roles of surface, atmospheric, and oceanic feedbacks in controlling the global-mean transient response of a coupled ocean-atmosphere general circulation model to increasing carbon dioxide are investigated. The analysis employs a four-box ...

J. M. Murphy

1995-03-01T23:59:59.000Z

117

Atmospheric Trace Gases, Carbon Isotopes, Radionuclides, and Aerosols: Isotopes in Greenhouse Gases Data from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer (OSTI)

(Scroll down to find Isotopes in Greenhouse Gases, a subheading under the broader heading of Atmospheric Trace Gases, etc.) CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Information related to isotopes in greenhouse gases includes: • Monthly atmospheric 13C/12C isotopic ratios for 10 SIO stations, (2005) (Trends Online) • Mixing ratios of CO, CO2, CH4, and isotope ratios of associated 13C, 18O, and 2H in air samples from Niwot Ridge, Colorado, and Monta±a de Oro, California, USA (2004) • Estimates of Monthly CO2 Emissions and Associated 13C/12C Values from Fossil-Fuel Consumption in the U.S.A., (2004) (Trends Online) ?13C in CO2 from the CSIRO GASLAB Flask Sampling Network (Trends Online) • In Situ 13CO2 from Cape Grim, Tasmania, Australia: 1982-1993 (2001) (Trends Online) • In situ Carbon 13 and Oxygen 18 Ratios of Atmospheric CO2 from Cape Grim, Tasmania, Australia: 1982-1993 (1995) • Carbon-13 Isotopic Abundance and concentration of Atmospheric Methane for Background Air in the Southern and Northern Hemispheres from 1978 to 1989 (1995) • Measurements of Atmospheric Methane and 13C/12C of Atmospheric Methane from Flask Air Samples (1999) • 14CO 2 Observations from Schauinsland, Germany (1997) (Trends Online) • Carbon-14 Measurements in Atmospheric CO 2 from Northern and Southern Hemisphere Sites, 1962-1992 (1996) • Carbon-14 Measurements in Surface Water CO2 from the Atlantic, Indian and Pacific Oceans, 1965-1994 (1998) (Specialized Interface)

118

Carbon Dioxide Information Analysis Center and World Data Center-A for Atmospheric Trace Gases catalog of databases and reports  

SciTech Connect

Data products and reports made available by the US Department of Energy's (DOE) Environmental Sciences Division, Office of Biological and Environmental Research (OBER), and the Carbon Dioxide Information Analysis Center (CDIAC) provide coverage in a number of areas relevant to the greenhouse effect and global climate change. Such areas include records of the concentration of carbon dioxide and other radiatively active gases in the atmosphere; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; emissions of carbon dioxide to the atmosphere; long-term climate trends; the effects of elevated carbon dioxide on vegetation; and the vulnerability of coastal areas to rising sea level. Currently, in its eighth revision, this catalog provides information about the data products and reports available through CDIAC.

Burtis, M.D. [comp.

1998-05-01T23:59:59.000Z

119

Application of an all-solid-state diode-laser-based sensor for carbon monoxide detection by optical absorption in the 4.4 ? 4.8 µm spectral region  

E-Print Network (OSTI)

An all-solid-state continuous-wave (cw) laser system for mid-infrared absorption measurements of the carbon monoxide (CO) molecule has been developed and demonstrated. The single-mode, tunable output of an external-cavity diode laser (ECDL) is difference-frequency mixed (DFM) with the output of a 550-mW diode-pumped cw Nd:YAG laser in a periodically-poled lithium niobate (PPLN) crystal to produce tunable cw radiation in the mid-infrared. The wavelength of the 860-nm ECDL can be coarse tuned between 860.78 to 872.82 nm allowing the sensor to be operated in the 4.4 ? 4.8 µm region. Results from single-pass mid-IR direct absorption experiments for CO concentration measurements are discussed. CO measurements were performed in CO/CO2/N2 mixtures in a room temperature gas cell that allowed the evaluation of the sensor operation and data reduction procedures. Field testing was performed at two locations: in the exhaust of a well-stirred reactor (WSR) at Wright-Patterson Air Force Base and the exhaust of a gas turbine at Honeywell Engines and Systems. Field tests demonstrated the feasibility of the sensor for operation in harsh combustion environments but much improvement in the sensor design and operation was required. Experiments in near-adiabatic hydrogen/air CO2-doped flames were performed featuring two-line thermometry in the 4.8 µm spectral region. The sensor concentration measurement uncertainty was estimated at 2% for gas cell testing. CO concentration measurements agreed within 15% of conventional extractive sampling at WSR, and for the flame experiments the repeatability of the peak absorption gives a system uncertainty of 10%. The noise equivalent CO detection limit for these experiments was estimated at 2 ppm per meter, for combustion gas at 1000 K assuming a SNR ratio of 1.

Rodolfo, Barron Jimenez

2004-12-01T23:59:59.000Z

120

A Study of the Abundance and 13C/12C Ratio of Atmospheric Carbon Dioxide to Advance the Scientific Understanding of Terrestrial Processes Regulating the Global Carbon Cycle  

Science Conference Proceedings (OSTI)

The primary goal of our research program, consistent with the goals of the U.S. Climate Change Science Program and funded by the terrestrial carbon processes (TCP) program of DOE, has been to improve understanding of changes in the distribution and cycling of carbon among the active land, ocean and atmosphere reservoirs, with particular emphasis on terrestrial ecosystems. Our approach is to systematically measure atmospheric CO2 to produce time series data essential to reveal temporal and spatial patterns. Additional measurements of the 13C/12C isotopic ratio of CO2 provide a basis for distinguishing organic and inorganic processes. To pursue the significance of these patterns further, our research also involved interpretations of the observations by models, measurements of inorganic carbon in sea water, and of CO2 in air near growing land plants.

Stephen C. Piper

2005-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Climatic changes from increased atmospheric carbon dioxide (citations from the NTIS data base). Report for 1970-Jan 1980  

SciTech Connect

The cited reports of Federally-funded research examine the relationship between climatic changes and an increase in atmospheric carbon dioxide. Topics considered include the Greenhouse effect, global climatic models, and climatic effects from increased combustion of fossil fuels. (Contains 39 abstracts)

Reimherr, G.W.

1980-02-01T23:59:59.000Z

122

Carbon dioxide Information Analysis Center and World Data Center: A for Atmospheric trace gases. Annual progress report, FY 1994  

SciTech Connect

This report summarizes the activities and accomplishments made by the Carbon Dioxide Information Analysis Center and World Data Center-A for Atmospheric Trace Gases during the fiscal year 1994. Topics discussed in this report include; organization and staff, user services, systems, communications, Collaborative efforts with China, networking, ocean data and activities of the World Data Center-A.

Burtis, M.D. [comp.] [Tennessee Univ., Knoxville, TN (United States). Energy, Environment and Resources Center; Cushman, R.M.; Boden, T.A.; Jones, S.B.; Nelson, T.R.; Stoss, F.W. [Oak Ridge National Lab., TN (United States)

1995-03-01T23:59:59.000Z

123

Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases, Fiscal Year 2002 Annual Report  

SciTech Connect

The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global change data and information analysis center of the U.S. Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has, since its inception in 1982, enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including atmospheric concentrations and atmospheric emissions of carbon dioxide (CO{sub 2}) and other radiatively active gases; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea levels.

Cushman, R.M.

2003-08-28T23:59:59.000Z

124

Whitings as a Potential Mechanism for Controlling Atmospheric Carbon Dioxide Concentrations – Final Project Report  

SciTech Connect

Species of cyanobacteria in the genera Synechococcus and Synechocystis are known to be the catalysts of a phenomenon called "whitings", which is the formation and precipitation of fine-grained CaCO3 particles. Whitings occur when the cyanobacteria fix atmospheric CO2 through the formation of CaCO3 on their cell surfaces which leads to precipitation to the ocean floor and subsequent entombment in mud. Whitings represent one potential mechanism for CO2 sequestration. Research was performed to determine the ability of various strains of Synechocystis and Synechococcus to calcify when grown in microcosms amended with 2.5 mM HCO3- and 3.4 mM Ca2+. Results indicated that while all strains tested have the ability to calcify, only two, Synechococcus species, strains PCC 8806 and PCC 8807, were able to calcify to the extent that CaCO3 was precipitated. Enumeration of the cyanobacterial cultures during testing indicated that cell density did not appear to have an effect on calcification. Factors that had the greatest effect on calcification were CO2 removal and subsequent generation of alkaline pH. As CO2 was removed, growth medium pH increased and soluble Ca2+ was removed from solution. The largest increases in growth medium pH occurred when CO2 levels dropped below 400 ppmv. Precipitation of CaCO3 catalyzed by the growth and physiology of cyanobacteria in the Genus Synechococcus represents a potential mechanism for sequestration of atmospheric CO2 produced during the burning of coal for power generation. Synechococcus sp. strain PCC 8806 and Synechococcus sp. strain PCC 8807 were tested in microcosm experiments for their ability to calcify when exposed to a fixed calcium concentration of 3.4 mM and dissolved inorganic carbon concentrations of 0.5, 1.25 and 2.5 mM. Synechococcus sp. strain PCC 8806 removed calcium continuously over the duration of the experiment producing approximately 18.6 mg of solid-phase calcium. Calcium removal occurred over a two-day time period when Synechococcus sp. strain PCC 8807 was tested and only 8.9 mg of solid phase calcium was produced. The ability of the cyanobacteria to create an alkaline growth environment appeared to be the primary factor responsible for CaCO3 precipitation in these experiments. These research results demonstrate the potential of using cyanobacterial catalyzed “whitings” as a method to sequester CO2 from the atmosphere.

Brady D. Lee; William A. Apel; Michelle R. Walton

2006-03-01T23:59:59.000Z

125

Atmospheric measurements of carbonyl sulfide, dimethyl sulfide, and carbon disulfide using the electron capture sulfur detector  

SciTech Connect

Measurements of atmospheric dimethyl sulfide (DMS), carbonyl sulfide (COS), and carbon disulfide (CS2) were conducted over the Atlantic Ocean on board the NASA Electra aircraft during the Chemical Instrumentation Test and Evaluation (CITE 3) project using the electron capture sulfur detector (ECD-S). The system employed cryogenic preconcentration of air samples, gas chromatographic separation, catalytic fluorination, and electron capture detection. Samples collected for DMS analysis were scrubbed of oxidants with NaOH impregnated glass fiber filters to preconcentration. The detection limits (DL) of the system for COS, DMS, and CS2 were 5, 5, and 2 ppt, respectively. COS concentrations ranged from 404 to 603 ppt with a mean of 489 ppt for measurements over the North Atlantic Ocean (31 deg N to 41 deg N), and from 395 to 437 ppt with a mean of 419 ppt for measurements over the Tropical Atlantic Ocean (11 deg S to 2 deg N). DMS concentrations in the lower marine boundary layer, below 600-m altitude, ranged from below DL to 150 ppt from flights over the North Atlantic, and from 9 to 104 ppt over the Tropical Atlantic. CS2 concentrations ranged from below DL to 29 ppt over the North Atlantic. Almost all CS2 measurements over the Tropical Atlantic were below DL.

Johnson, J.E.; Bates, T.S. [NOAA, Seattle, WA (United States)

1993-12-01T23:59:59.000Z

126

Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol  

E-Print Network (OSTI)

for measuring ecosystem carbon oxidation state and oxidativemean oxidation number of carbon (MOC) - A useful concept forJ.F. & Barsanti, K.C. The Carbon Number-Polarity Grid: A

Kroll, Jesse H.

2011-01-01T23:59:59.000Z

127

CARBON FLUX TO THE ATMOSPHERE FROM LAND-USE CHANGES: 1850 TO...  

NLE Websites -- All DOE Office Websites (Extended Search)

C: REGIONAL CARBON-CHANGE COEFFICIENTS The following listing provides the regional values and coefficients associated with oxidation and recovery of carbon in vegetation, soils,...

128

Chemical Bonding and Structural Information of Black Carbon Reference Materials and Individual Carbonaceous Atmospheric Aerosols  

E-Print Network (OSTI)

HULIS) in biomass-burning aerosols, Atmospheric Chemistrymicroscopical and aerosol dynamical characterizationof soot aerosols, Journal of Aerosol Science , 34 , 1347-

Hopkins, Rebecca J.; Tivanski, Alexei V.; Marten, Bryan D.; Gilles, Mary K.

2007-01-01T23:59:59.000Z

129

Production Test IP-358-AC: Replacement of carbon dioxide with nitrogen as a constituent of the K reactor atmosphere  

SciTech Connect

Compensation for the positive long-term reactivity transient associated with Hanford reactor may be accomplished in two ways: The addition of a poisonous material (rods, splines, etc.) to the reactor, or cooling the moderator by changing the gas composition. The objective of this study is to investigate the reactivity and temperature effects and the associated operating problems if any, resulting from the use of nitrogen instead of carbon dioxide as a constituent of the reactor atmosphere.

Bailey, G.F.; Benoliel, R.W.

1960-10-03T23:59:59.000Z

130

Carbon Monoxide Sensor - Energy Innovation Portal  

Electricity Transmission; Energy Analysis; ... the sensor ensures reproducibility and reduces the need for calibration of every sensor coming off the ...

131

Predicting Smoke and Carbon Monoxide Detector Response ...  

Science Conference Proceedings (OSTI)

... room with floor dimensions of 3.15 m by 3.02 m. A sand burner was ... The detector was isolated from the CO environment by placing a tight fitting can ...

2003-08-28T23:59:59.000Z

132

Standard Reference Materials Carbon Monoxide Absorption ...  

Science Conference Proceedings (OSTI)

... Use With a Broadband Source: A broadband source in the 1560 nm to 1595 nm region such as a light emitting diode, white light, or amplified ...

2011-08-04T23:59:59.000Z

133

Prototype Generators Emit Much Less Carbon Monoxide ...  

Science Conference Proceedings (OSTI)

... Portable electric generators retrofitted with off-the-shelf hardware by ... Technology (NIST) for the US Consumer Product Safety Commission (CPSC). ...

2013-04-17T23:59:59.000Z

134

Atmospheric Carbon Dioxide Variability in the Community Earth System Model: Evaluation and Transient Dynamics during the Twentieth and Twenty-First Centuries  

Science Conference Proceedings (OSTI)

Changes in atmospheric CO2 variability during the twenty-first century may provide insight about ecosystem responses to climate change and have implications for the design of carbon monitoring programs. This paper describes changes in the three-...

Gretchen Keppel-Aleks; James T. Randerson; Keith Lindsay; Britton B. Stephens; J. Keith Moore; Scott C. Doney; Peter E. Thornton; Natalie M. Mahowald; Forrest M. Hoffman; Colm Sweeney; Pieter P. Tans; Paul O. Wennberg; Steven C. Wofsy

2013-07-01T23:59:59.000Z

135

Damage of Land Biosphere due to Intense Warming by 1000-Fold Rapid Increase in Atmospheric Methane: Estimation with a Climate–Carbon Cycle Model  

Science Conference Proceedings (OSTI)

Decadal-time-scale responses of climate and the global carbon cycle to warming associated with rapid increases in atmospheric methane from a massive methane release from marine sedimentary methane hydrates are investigated with a coupled climate–...

Atsushi Obata; Kiyotaka Shibata

2012-12-01T23:59:59.000Z

136

Atmospheric Circulation Response to an Instantaneous Doubling of Carbon Dioxide. Part I: Model Experiments and Transient Thermal Response in the Troposphere  

Science Conference Proceedings (OSTI)

This study aims to understand the dynamical mechanisms driving the changes in the general circulation of the atmosphere due to increased carbon dioxide (CO2) by looking into the transient step-by-step adjustment of the circulation. The transient ...

Yutian Wu; Richard Seager; Mingfang Ting; Naomi Naik; Tiffany A. Shaw

2012-04-01T23:59:59.000Z

137

Ecosystem-Atmosphere Exchange of Carbon, Water and Energy over a Mixed Deciduous Forest in the Midwest  

Science Conference Proceedings (OSTI)

During the project period we continued to conduct long-term (multi-year) measurements, analysis, and modeling of energy and mass exchange in and over a deciduous forest in the Midwestern United States, to enhance the understanding of soil-vegetation-atmosphere exchange of carbon. At the time when this report was prepared, results from nine years of measurements (1998 - 2006) of above canopy CO2 and energy fluxes at the AmeriFlux site in the Morgan-Monroe State Forest, Indiana, USA (see Table 1), were available on the Fluxnet database, and the hourly CO2 fluxes for 2007 are presented here (see Figure 1). The annual sequestration of atmospheric carbon by the forest is determined to be between 240 and 420 g C m-2 a-1 for the first ten years. These estimates are based on eddy covariance measurements above the forest, with a gap-filling scheme based on soil temperature and photosynthetically active radiation. Data gaps result from missing data or measurements that were rejected in qua)lity control (e.g., during calm nights). Complementary measurements of ecological variables (i.e. inventory method), provided an alternative method to quantify net carbon uptake by the forest, partition carbon allocation in each ecosystem components, and reduce uncertainty on annual net ecosystem productivity (NEP). Biometric datasets are available on the Fluxnext database since 1998 (with the exclusion of 2006). Analysis for year 2007 is under completion.

Danilo Dragoni; Hans Peter Schmid; C.S.B. Grimmond; J.C. Randolph; J.R. White

2012-12-17T23:59:59.000Z

138

Long-Term, Autonomous Measurement of Atmospheric Carbon Dioxide Using an Ormosil Nanocomposite-Based Optical Sensor  

Science Conference Proceedings (OSTI)

The goal of this project is to construct a prototype carbon dioxide sensor that can be commercialized to offer a low-cost, autonomous instrument for long-term, unattended measurements. Currently, a cost-effective CO2 sensor system is not available that can perform cross-platform measurements (ground-based or airborne platforms such as balloon and unmanned aerial vehicle (UAV)) for understanding the carbon sequestration phenomenon. The CO2 sensor would support the research objectives of DOE-sponsored programs such as AmeriFlux and the North American Carbon Program (NACP). Global energy consumption is projected to rise 60% over the next 20 years and use of oil is projected to increase by approximately 40%. The combustion of coal, oil, and natural gas has increased carbon emissions globally from 1.6 billion tons in 1950 to 6.3 billion tons in 2000. This figure is expected to reach 10 billon tons by 2020. It is important to understand the fate of this excess CO2 in the global carbon cycle. The overall goal of the project is to develop an accurate and reliable optical sensor for monitoring carbon dioxide autonomously at least for one year at a point remote from the actual CO2 release site. In Phase I of this project, InnoSense LLC (ISL) demonstrated the feasibility of an ormosil-monolith based Autonomous Sensor for Atmospheric CO2 (ASAC) device. All of the Phase I objectives were successfully met.

Kisholoy Goswami

2005-10-11T23:59:59.000Z

139

CSIRO GASLAB Network: Individual Flask Measurements of Atmospheric Trace  

NLE Websites -- All DOE Office Websites (Extended Search)

GASLAB Network GASLAB Network CSIRO GASLAB Network: Individual Flask Measurements of Atmospheric Trace Gases (April 2003) data Data Investigators L.P. Steele, P.R. Krummel, and R.L. Langenfelds Commonwealth Scientific and Industrial Research Organisation (CSIRO) DOI 10.3334/CDIAC/atg.db1021 Data are available for four atmospheric trace gases at nine stationary sites and one moving platform (aircraft over Cape Grim, Tasmania, and Bass Strait, between the Australian continent and Tasmania). The trace gases are carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), and hydrogen (H2). Measurements of δ13C from CO2 are also included in this database. The nine stationary sites are, from north to south: Alert, Canada; Shetland Islands, Scotland; Estevan Point, Canada; Mauna Loa, Hawaii; Cape Ferguson,

140

Transient Response of the Hadley Centre Coupled Ocean-Atmosphere Model to Increasing Carbon Dioxide. Part II: Spatial and Temporal Structure of Response  

Science Conference Proceedings (OSTI)

A high-resolution (2.75° lat × ° 3.75° long) coupled ocean-atmosphere model has been used to simulate the transient response of climate to a gradual increase in atmospheric carbon dioxide concentrations. Although the radiative forcing increases ...

J. M. Murphy; J. F. B. Mitchell

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

800,000-year Ice-Core Records of Atmospheric Carbon Dioxide ...  

NLE Websites -- All DOE Office Websites (Extended Search)

time series extending to the present These records are maintained by the World Data Center for Paleoclimatology, National Oceanic and Atmospheric Administration (NOAA), and...

142

Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases Fiscal Year 2000 Annual Report  

SciTech Connect

The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global change data and information analysis center of the U.S. Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has, since its inception in 1982, enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including concentrations of carbon dioxide (CO{sub 2}) and other radiatively active gases in the atmosphere; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; emissions of CO{sub 2} and other trace gases to the atmosphere; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea levels.

Cushman, R.M.

2001-11-15T23:59:59.000Z

143

Atmospheric carbon diooxide mixing ratios from the NOAA Climate Monitoring and Diagnostics Laboratory cooperative flask sampling network, 1967-1993  

Science Conference Proceedings (OSTI)

This data report documents monthly atmospheric CO{sub 2} mixing ratios and measurements obtained by analyzing individual flask air samples for the NOAA/CMDL global cooperative flask sampling network. Measurements include land-based sampling sites and shipboard measurements covering 14 latitude bands in the Pacific Ocean and South China Sea. Analysis of the NOAA/CMDL flask CO{sub 2} database shows a long-term increase in atmospheric CO{sub 2} mixing ratios since the late 1960s. This report describes how the samples are collected and analyzed and how the data are processed, defines limitations, and restrictions of the data, describes the contents and format of the data files, and provides tabular listings of the monthly carbon dioxide records.

Conway, T.J.; Tans, P.P. [National Oceanic and Atmospheric Administration, Boulder, CO (United States); BBoden, T.A. [Oak Ridge National Lab., TN (United States)

1996-02-01T23:59:59.000Z

144

Glossary: Energy-Related Carbon Emissions  

U.S. Energy Information Administration (EIA)

Carbon Sequestration: The fixation of atmospheric carbon dioxide in a carbon sink through biological or physical processes. Carbon Sink: ...

145

A Lightweight Observation System for Atmospheric Carbon Dioxide Concentration Using a Small Unmanned Aerial Vehicle  

Science Conference Proceedings (OSTI)

To make the investigation of the temporal and spatial variations of atmospheric CO2 in and above the planetary boundary layer more flexible and economical, a lightweight observation system using a small unmanned aerial vehicle has been developed ...

T. Watai; T. Machida; N. Ishizaki; G. Inoue

2006-05-01T23:59:59.000Z

146

Regional Estimates of Net Ecosystem-Atmosphere Exchange of Carbon Dioxide over a Heterogeneous Ecosystem.  

E-Print Network (OSTI)

??The net ecosystem-atmosphere exchange of CO2 (NEE) is estimated over a mixed forest ecosystem in the 40×40km2 region centered at the WLEF tall tower in… (more)

Wang, Weiguo

2005-01-01T23:59:59.000Z

147

Carbon-14 Measurements in Atmospheric CO2 from Northern and Southern...  

NLE Websites -- All DOE Office Websites (Extended Search)

ray neutrons and the nitrogen atoms of the air (Libby 1952). Solar (heliomagnetic), geomagnetic, and ocean forcing all play a role in atmospheric 14CO2 (Stuiver and Braziunas...

148

Modeling the effects of topography and wind on atmospheric dispersion of CO2 surface leakage at geologic carbon sequestration sites  

Science Conference Proceedings (OSTI)

Understanding the potential impacts of unexpected surface releases of CO{sub 2} is an essential part of risk assessment for geologic carbon sequestration sites. We have extended a mesoscale atmospheric model to model dense gas dispersion of CO{sub 2} leakage. The hazard from CO{sub 2} leakage is greatest in regions with topographic depressions where the dense gas can pool. Simulation of dispersion in idealized topographies shows that CO{sub 2} can persist even under high winds. Simulation of a variety of topographies, winds, and release conditions allows the generation of a catalog of simulation results that can be queried to estimate potential impacts at actual geologic carbon sequestration sites.

Chow, Fotini K.; Granvold, Patrick W.; Oldenburg, Curtis M.

2008-11-01T23:59:59.000Z

149

Carbon Dioxide and Hydrogen Sulfide Emission Factors Applicable to Wastewater Wet Wells.  

E-Print Network (OSTI)

??Transport of wastewater in sewer networks causes potential problems associated with gases which include ammonia, carbon dioxide, carbon monoxide, hydrogen sulfide and methane, in regard… (more)

Mudragaddam, Madhuri

2010-01-01T23:59:59.000Z

150

Functionalization of Hydrogen-free Diamond-like Carbon Films using Open-air Dielectric Barrier Discharge Atmospheric Plasma Treatments  

SciTech Connect

A dielectric barrier discharge (DBD) technique has been employed to produce uniform atmospheric plasmas of He and N2 gas mixtures in open air in order to functionalize the surface of filtered-arc deposited hydrogen-free diamond-like carbon (DLC) films. XPS measurements were carried out on both untreated and He/N2 DBD plasma treated DLC surfaces. Chemical states of the C 1s and N 1s peaks were collected and used to characterize the surface bonds. Contact angle measurements were also used to record the short- and long-term variations in wettability of treated and untreated DLC. In addition, cell viability tests were performed to determine the influence of various He/N2 atmospheric plasma treatments on the attachment of osteoblast MC3T3 cells. Current evidence shows the feasibility of atmospheric plasmas in producing long-lasting variations in the surface bonding and surface energy of hydrogen-free DLC and consequently the potential for this technique in the functionalization of DLC coated devices.

Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA; Instituto de Materiales de Madrid, C.S.I.C., Cantoblanco, 28049 Madrid, Spain; Instituto de Quimica-Fisica" Rocasolano" C.S.I.C., 28006 Madrid, Spain; Mahasarakham University, Mahasarakham 44150, Thailand; CASTI, CNR-INFM Regional Laboratory, L' Aquila 67100, Italy; SUNY Upstate Medical University, Syracuse, NY 13210, USA; Endrino, Jose; Endrino, J. L.; Marco, J. F.; Poolcharuansin, P.; Phani, A.R.; Allen, M.; Albella, J. M.; Anders, A.

2007-12-28T23:59:59.000Z

151

Review of recent reports dealing with the greenhouse effect of atmospheric carbon dioxide  

SciTech Connect

Prior to the Industrial Revolution, the concentration of CO/sub 2/ in the Earth's atmosphere is estimated to have been between 260 to 270 ppm by volume. Direct measurements begun during the International Geophysical year of 1957-1958 indicate a change in global concentration to 315 ppm; current measurements indicate levels of just over 350 ppm. The author states that theoretical climate models may not reflect demonstrable biological realities; that increased atmospheric CO/sub 2/ levels may lead to increased vegetation, with grasslands spreading out over deserts and forests encroaching on grasslands.

Idso, S.B.

1984-05-01T23:59:59.000Z

152

The tropical cyclone-induced flux of carbon between the ocean and the atmosphere  

E-Print Network (OSTI)

Tropical cyclones are known to cause phytoplankton blooms in regions of the ocean that would otherwise support very little life; it is also known that these storms entrain carbon-rich deep water, which can cause ...

Zimmerman, Neil L

2012-01-01T23:59:59.000Z

153

EXTRACTION OF CARBON DIOXIDE FROM THE ATMOSPHERE THROUGH ENGINEERED CHEMICAL SINKAGE.  

DOE Green Energy (OSTI)

We present the case for C02 extraction from air as a means of sustaining fossil energy use by avoiding climate change. Our concept harnesses atmospheric circulation to transport C02 to sites where the C02 is extracted by binding it to an adsorbent. As a proof of concept, we show that an aqueous Ca(OH)2 solution efficiently converts C02 to a CaC03 solid that can be heated to obtain pure C02 and recover the CaO. Even with recycling costs, C02 extraction from air blown by wind through a 1 m2 aperture could eliminate the greenhouse gas impact of 100 kW gasoline engine, making it more favorable than renewable sources as solar, wind, or bio-mass. In addition it collects C02 from dispersed sources, preserves the energy infrastructure, can yield negative emissions, and provide free C02 transport to sequestration sites. We report economic and scaling arguments, atmospheric simulations and experiments that support pursuing air-extraction as an advanced C02 capture technology. This method could process today's world output of C02 with many collection units with a net area of 103-104 km2 at costs of -5/liter of gasoline, a manageable scale for this massive undertaking.

Dubey, M. K. (Manvendra K.); Ziock, H. J. (Hans-Joachim); Rueff, G. (Gordon); Elliott, S. M. (Scott M.); Smith, W. S. (William S.); Lackner, K. S. (Klaus S.); Johnston, N. A.

2001-01-01T23:59:59.000Z

154

EXTRACTION OF CARBON DIOXIDE FROM THE ATMOSPHERE THROUGH ENGINEERED CHEMICAL SINKAGE  

DOE Green Energy (OSTI)

We present the case for CO{sub 2} extraction from air as a means of sustaining fossil energy use by avoiding climate change. Our concept harnesses atmospheric circulation to transport CO{sub 2} to sites where the CO{sub 2} is extracted by binding it to an adsorbent. As a proof of concept, we show that an aqueous Ca(OH){sub 2} solution efficiently converts CO{sub 2} to a CaCO{sub 3} solid that can be heated to obtain pure CO{sub 2} and recover the CaO. Even with recycling costs, CO{sub 2} extraction from air blown by wind through a 1 m{sup 2} aperture could eliminate the greenhouse gas impact of 100 kW gasoline engine, making it more favorable than renewable sources as solar, wind, or bio-mass. In addition it collects CO{sub 2} from dispersed sources, preserves the energy infrastructure, can yield negative emissions, and provide free CO{sub 2} transport to sequestration sites. We report economic and scaling arguments, atmospheric simulations and experiments that support pursuing air-extraction as an advanced CO{sub 2} capture technology. This method could process today's world output of CO{sub 2} with many collection units with a net area of 10{sup 3}-10{sup 4} km{sup 2} at costs of {approx} 5{cents}/liter of gasoline, a manageable scale for this massive undertaking.

M. K. DUBEY; H. ZIOCK; ET AL

2001-11-01T23:59:59.000Z

155

Climatic changes from increased atmospheric carbon dioxide. 1970-February 1981 (citations from the NTIS Data Base). Report for 1970-Feb 81  

SciTech Connect

The cited reports of Federally-funded research examine the relationship between climatic changes and an increase in atmospheric carbon dioxide. Topics considered include the Greenhouse effect, global climatic models, and climatic effects from increased combustion of fossil fuels. (This updated bibliography contains 59 citations, 20 of which are new entries to the previous edition.)

1981-03-01T23:59:59.000Z

156

Soil–Atmosphere Exchange of Nitrous Oxide, Nitric Oxide, Methane, and Carbon Dioxide in Logged and Undisturbed Forest in the Tapajos National Forest, Brazil  

Science Conference Proceedings (OSTI)

Selective logging is an extensive land use in the Brazilian Amazon region. The soil–atmosphere fluxes of nitrous oxide (N2O), nitric oxide (NO), methane (CH4), and carbon dioxide (CO2) are studied on two soil types (clay Oxisol and sandy loam ...

Michael Keller; Ruth Varner; Jadson D. Dias; Hudson Silva; Patrick Crill; Raimundo Cosme de Oliveira Jr.; Gregory P. Asner

2005-11-01T23:59:59.000Z

157

Carbon Dioxide Information Analysis Center and World Data Center-A for atmospheric trace gases: FY 1993 activities  

SciTech Connect

During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specialty publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIAC`s staff also provide technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC (including World Data Center-A for Atmospheric Trace Gases) during the period October 1, 1992, to September 30, 1993. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. An analysis and description of the preparation and distribution of NDPS, CMPS, technical reports, newsletters, fact sheets, specialty publications, and reprints are provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also presented.

Cushman, R.M. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center; Stoss, F.W. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center]|[Univ. of Tennessee, Knoxville, TN (United States). Energy, Environment, and Resources Center

1994-01-01T23:59:59.000Z

158

Modeling the effects of topography and wind on atmospheric dispersion of CO2 surface leakage at geologic carbon sequestration sites  

E-Print Network (OSTI)

CO 2 from geologic carbon sequestration sites, Vadose Zoneleakage at geologic carbon sequestration sites Fotini K.assessment for geologic carbon sequestration sites. We have

Chow, Fotini K.

2009-01-01T23:59:59.000Z

159

Coupled Vadose Zone and Atmospheric Surface-Layer Transport of CO2 from Geologic Carbon Sequestration Sites  

E-Print Network (OSTI)

1999. Reichle, D. et al. , Carbon sequestration research andfrom geologic carbon sequestration sites: unsaturated zoneCO 2 from a geologic carbon sequestration site showing the

Oldenburg, Curtis M.; Unger, Andre J.A.

2004-01-01T23:59:59.000Z

160

Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases Fiscal Year 2001 Annual Report  

SciTech Connect

The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global change data and information analysis center of the U.S. Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has, since its inception in 1982, enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including concentrations of carbon dioxide (CO{sub 2}) and other radiatively active gases in the atmosphere; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; emissions of CO{sub 2} and other trace gases to the atmosphere; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea levels. CDIAC is located within the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee. CDIAC is co-located with ESD researchers investigating global-change topics, such as the global carbon cycle and the effects of carbon dioxide on climate and vegetation. CDIAC staff are also connected with current ORNL research on related topics, such as renewable energy and supercomputing technologies. CDIAC is supported by the Environmental Sciences Division (Jerry Elwood, Director) of DOE's Office of Biological and Environmental Research. CDIAC represents DOE in the multi-agency Global Change Data and Information System (GCDIS). Wanda Ferrell is DOE's Program Manager with overall responsibility for CDIAC. Roger Dahlman is responsible for CDIAC's AmeriFlux tasks, and Anna Palmisano for CDIAC's Ocean Data tasks. CDIAC is made up of three groups: Data Systems, Information Services, and Computer Systems, with nineteen full-time or part-time staff. The following section provides details on CDIAC's staff and organization. The Data Systems Group identifies and obtains databases important to global-change research; analyzes data; compiles needed databases; provides data management and support to specific programs [e.g., NARSTO, Free-Air CO{sub 2} Enrichment (FACE), AmeriFlux, Oceans]; and prepares documentation to ensure the long-term utility of CDIAC's data holdings. The Information Services Group responds to data and information requests; maintains records of all request activities; analyzes user statistics; assists in Web development and maintenance; and produces CDIAC's newsletter (CDIAC Communications), the fiscal year annual reports, and various information materials. The Computer Systems Group provides computer system support for all CDIAC and WDC activities; designs and maintains CDIAC's computing system network; ensures compliance with ORNL/DOE computing security regulations; ensures long-term preservation of CDIAC data holdings through systematic backups; evaluates, develops, and implements software; ensures standards compliance; generates user statistics; provides Web design, development, and oversight; and provides systems analysis and programming assistance for scientific data projects.

Cushman, R.M.

2002-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases Fiscal Year 1999 Annual Report  

SciTech Connect

The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global-change data and information analysis center of the Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has--since its inception in 1982--enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including concentrations of carbon dioxide (CO{sub 2}) and other radiatively active gases in the atmosphere; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; emissions of CO{sub 2} and other trace gases to the atmosphere; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea level. CDIAC is located within the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee. CDIAC is co-located with ESD researchers investigating global-change topics, such as the global carbon cycle and the effects of carbon dioxide on vegetation. CDIAC staff are also connected with current ORNL research on related topics, such as renewable energy and supercomputing technologies. CDIAC is supported by the Environmental Sciences Division (Jerry Elwood, Acting Director) of DOE's Office of Biological and Environmental Research. CDIAC's FY 1999 budget was 2.2M dollars. CDIAC represents the DOE in the multi-agency Global Change Data and Information System. Bobbi Parra, and Wanda Ferrell on an interim basis, is DOE's Program Manager with responsibility for CDIAC. CDIAC comprises three groups, Global Change Data, Computer Systems, and Information Services, with seventeen full-time and part-time staff. The Global Change Data group is responsible for identifying and obtaining databases important to global-change research, analyzing data, compiling needed databases, providing data management support to specific programs (e.g., NARSTO), and preparing documentation to ensure the long-term utility of CDIAC's data holdings. The Computer Systems group provides computer system support for all CDIAC and WDC activities, including designing and maintaining CDIAC's computing system network; ensuring compliance with ORNL/DOE computing security regulations; ensuring long-term preservation of CDIAC data holdings through systematic backups; evaluating, developing, and implementing software; ensuring standards compliance; generating user statistics; providing Web design, development, and oversight; and providing systems analysis and programming assistance for scientific data projects. The Information Services group responds to data and information requests; maintains records of all request activities; assists in Web development and maintenance; and produces CDIAC's newsletter, CDIAC Communications, catalog, glossary, and educational materials. The following section provides further details on CDIAC's organization.

Cushman, R.M.

2000-03-31T23:59:59.000Z

162

Structure of Isoprene Synthase Illuminates the Chemical Mechanism of Teragram Atmospheric Carbon Emission  

SciTech Connect

The X-ray crystal structure of recombinant PcISPS (isoprene synthase from gray poplar hybrid Populus x canescens) has been determined at 2.7 {angstrom} resolution, and the structure of its complex with three Mg{sup 2+} and the unreactive substrate analogue dimethylallyl-S-thiolodiphosphate has been determined at 2.8 {angstrom} resolution. Analysis of these structures suggests that the generation of isoprene from substrate dimethylallyl diphosphate occurs via a syn-periplanar elimination mechanism in which the diphosphate-leaving group serves as a general base. This chemical mechanism is responsible for the annual atmospheric emission of 100 Tg of isoprene by terrestrial plant life. Importantly, the PcISPS structure promises to guide future protein engineering studies, potentially leading to hydrocarbon fuels and products that do not rely on traditional petrochemical sources.

Koksal, M.; Zimmer, I; Schnitzler, J; Christianson, D

2010-01-01T23:59:59.000Z

163

Black carbon enrichment in atmospheric ice particle residuals observed in lower tropospheric mixed phase clouds  

SciTech Connect

The enrichment of black carbon (BC) in residuals of small ice crystals was investigated during intensive experiments in winter 2004 and 2005 at the high alpine research station Jungfraujoch (3580 m asl, Switzerland). Two inlets were used to sample the bulk aerosol (residuals of cloud droplets and ice crystals as well as non-activated aerosol particles) and the residual particles of small ice crystals (diameter 5 - 20 ?m). An enrichment of the BC mass fraction in the ice particle residuals was observed by investigating the measured BC mass concentration as a fraction of the bulk (submicrometer) aerosol mass concentration sampled by the two inlets. On average, the BC mass fraction was 5% for the bulk aerosol and 27% for the ice particle residuals. The observed enrichment of BC in ice particle residuals suggests that BC containing particles preferentially act as ice nuclei, with important implications for the indirect aerosol effect via glaciation of clouds.

Cozic, J.; Mertes, S.; Verheggen, B.; Cziczo, Daniel J.; Gallavardin, S. J.; Walter, S.; Baltensperger, Urs; Weingartner, E.

2008-08-15T23:59:59.000Z

164

Black carbon enrichment in atmospheric ice particle residuals observed in lower trophospheric mixed phase clouds  

SciTech Connect

The enrichment of black carbon (BC) in residuals of small ice particles was investigated during intensive experiments in winter 2004 and 2005 at the high alpine research station Jungfraujoch (3580 m asl, Switzerland). Two inlets were used to sample the bulk aerosol (residuals of cloud droplets and ice crystals as well as non-activated aerosol particles) and the residual particles of small ice crystals (diameter 5 - 20 m). An enrichment of the BC mass fraction in the ice particle residuals was observed by investigating the measured BC mass concentration as a fraction of the bulk (submicrometer) aerosol mass concentration sampled by the two inlets. On average, the BC mass fraction was 5% for the bulk aerosol and 14% for the ice particle residuals. The observed enrichment of BC in ice particle residuals suggests that BC may act as ice nuclei, with important implications for the indirect aerosol effect via glaciation of clouds.

Cozic, J.; Mertes, S.; Verheggen, B.; Cziczo, Dan; Gallavardin, S. J.; Walter, S.; Baltensperger, Urs; Weingartner, E.

2008-08-15T23:59:59.000Z

165

On the coupled evolution of inflation, wealth and atmospheric concentrations of carbon dioxide  

E-Print Network (OSTI)

In a prior study (Garrett, 2009), a thermodynamically-based economic growth model was introduced that was based on the finding that the rate of consumption of energy by civilization has been related to its historical accumulation of inflation-adjusted Gross World Product (GWP), or its ``wealth'', through a constant value {\\lambda} of 9.7 {\\pm} 0.3 milliwatts per 1990 US dollar. Here, this simple model is extended to describe, first, a thermodynamically-based theory for economic inflation and, second, a prognostic model for the coupled multi-decadal evolution of CO2 concentrations and GWP. Multi-decadal hindcasts of GWP and CO2 concentrations made with this model are shown to be accurate. Applied to coming decades, the model implies that, like a long-term natural disaster, future greenhouse warming will accelerate economic inflation. Such inflation will slow growth of not just inflation-adjusted economic wealth, but also CO2 emission rates because the two are coupled through {\\lambda}. Maintaining atmospheric ...

Garrett, Timothy J

2010-01-01T23:59:59.000Z

166

Response of a tundra ecosystem to elevated atmospheric carbon dioxide and CO{sub 2}-induced climate change. Annual technical report  

Science Conference Proceedings (OSTI)

Northern ecosystems contain up to 455 Gt of C in the soil active layer and upper permafrost. The soil carbon in these layers is equivalent to approximately 60% of the carbon currently in the atmosphere as CO{sub 2}. Much of this carbon is stored in the soil as dead organic matter. Its fate is subject to the net effects of global change on the plant and soil systems of northern ecosystems. The arctic alone contains about 60 Gt C, 90% of which is present in the soil active layer and upper permafrost. The arctic is assumed to have been a sink for CO{sub 2} during the historic and recent geologic past. The arctic has the potential to be a very large, long-term source or sink of CO{sub 2} with respect to the atmosphere. In situ experimental manipulations of atmospheric CO{sub 2}, indicated that there is little effect of elevated atmospheric CO{sub 2} on leaf level photosynthesis or whole-ecosystem CO{sub 2} flux over the course of weeks to years, respectively. However, there may be longer- term ecosystem responses to elevated CO{sub 2} that could ultimately affect ecosystem CO{sub 2} balance. In addition to atmospheric CO{sub 2}, climate may affect net ecosystem carbon balance. Recent results indicate that the arctic has become a source of CO{sub 2} to the atmosphere. This change coincides with recent climatic variation in the arctic, and suggests a positive feedback of arctic ecosystems on atmospheric CO{sub 2} and global change. The research proposed in this application has four principal aspects: (A) Long-term response of arctic plants and ecosystems to elevated atmospheric CO{sub 2}; (B) Circumpolar patterns of net ecosystem CO{sub 2} flux; (C) In situ controls by temperature and moisture on net ecosystem CO{sub 2} flux; (D) Scaling of CO{sub 2} flux from plot, to landscape, to regional scales (In conjunction with research proposed for NSF support).

Oechel, W.C.

1992-04-01T23:59:59.000Z

167

Classification of Multiple Types of Organic Carbon Composition in Atmospheric Particles by Scanning Transmission X-Ray Microscopy Analysis  

Science Conference Proceedings (OSTI)

A scanning transmission X-ray microscope at the Lawrence Berkeley National Laboratory is used to measure organic functional group abundance and morphology of atmospheric aerosols. We present a summary of spectra, sizes, and shapes observed in 595 particles that were collected and analyzed between 2000 and 2006. These particles ranged between 0.1 and 12 mm and represent aerosols found in a large range of geographical areas, altitudes, and times. They include samples from seven different field campaigns: PELTI, ACE-ASIA, DYCOMS II, Princeton, MILAGRO (urban), MILAGRO (C-130), and INTEX-B. At least 14 different classes of organic particles show different types of spectroscopic signatures. Different particle types are found within the same region while the same particle types are also found in different geographical domains. Particles chemically resembling black carbon, humic-like aerosols, pine ultisol, and secondary or processed aerosol have been identified from functional group abundance and comparison of spectra with those published in the literature.

Kilcoyne, Arthur L; Takahama, S.; Gilardoni, S.; Russell, L.M.; Kilcoyne, A.L.D.

2007-05-16T23:59:59.000Z

168

Modeling global atmospheric CO2 with improved emission inventories and CO2 production from the oxidation of other carbon species  

Science Conference Proceedings (OSTI)

The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of CO2 chemical production on monthly-averaged loss rates of CO (a key precursor and intermediate in the oxidation of organic carbon) and apply an associated surface correction for inventories that have counted emissions of CO2 precursors as CO2. We also explore the benefit of assimilating satellite observations of CO into GEOS-Chem to obtain an observation-based estimate of the CO2 chemical source. The CO assimilation corrects for an underestimate of atmospheric CO abundances in the model, resulting in increases of as much as 24% in the chemical source during May June 2006, and increasing the global annual estimate of CO2 chemical production from 1.05 to 1.18 Pg C. Comparisons of model CO2 with measurements are carried out in order to investigate the spatial and temporal distributions that result when these new sources are added. Inclusion of CO2 emissions from shipping and aviation are shown to increase the global CO2 latitudinal gradient by just over 0.10 ppm (3%), while the inclusion of CO2 chemical production (and the surface correction) is shown to decrease the latitudinal gradient by about 0.40 ppm (10%) with a complex spatial structure generally resulting in decreased CO2 over land and increased CO2 over the oceans. Since these CO2 emissions are omitted or misrepresented in most inverse modeling work to date, their implementation in forward simulations should lead to improved inverse modeling estimates of terrestrial biospheric fluxes.

Nassar, Ray [University of Toronto; Jones, DBA [University of Toronto; Suntharalingam, P [University of East Anglia, Norwich, United Kingdom; Chen, j. [University of Toronto; Andres, Robert Joseph [ORNL; Wecht, K. J. [Harvard University; Yantosca, R. M. [Harvard University; Kulawik, SS [Jet Propulsion Laboratory, Pasadena, CA; Bowman, K [Jet Propulsion Laboratory, Pasadena, CA; Worden, JR [Jet Propulsion Laboratory, Pasadena, CA; Machida, T [National Institute for Environmental Studies, Japan; Matsueda, H [Meteorological Research Institute, Japan

2010-01-01T23:59:59.000Z

169

The effects of snowlines on C/O in planetary atmospheres  

E-Print Network (OSTI)

The C/O ratio is predicted to regulate the atmospheric chemistry in hot Jupiters. Recent observations suggest that some exo-planets, e.g. Wasp 12- b, have atmospheric C/O ratios substantially different from the solar value of 0.54. In this paper we present a mechanism that can produce such atmospheric deviations from the stellar C/O ratio. In protoplanetary disks, different snowlines of oxygen- and carbon-rich ices, especially water and carbon monoxide, will result in systematic variations in the C/O ratio both in the gas and in the condensed phase. In particular, between the H2O and CO snowlines most oxygen is present in icy grains - the building blocks of planetary cores in the core accretion model - while most carbon remains in the gas-phase. This region is coincidental with the giant-planet forming zone for a range of observed protoplanetary disks. Based on standard core accretion models of planet formation, gas giants that sweep up most of their atmospheres from disk gas outside of the water snowline wil...

Oberg, Karin I; Bergin, Edwin A

2011-01-01T23:59:59.000Z

170

Study of the Role of Terrestrial Processes in the Carbon Cycle Based on Measurements of the Abundance and Isotopic Composition of Atmospheric CO2  

Science Conference Proceedings (OSTI)

The main objective of this project was to continue research to develop carbon cycle relationships related to the land biosphere based on remote measurements of atmospheric CO2 concentration and its isotopic ratios 13C/12C, 18O/16O, and 14C/12C. The project continued time-series observations of atmospheric carbon dioxide and isotopic composition begun by Charles D. Keeling at remote sites, including Mauna Loa, the South Pole, and eight other sites. Using models of varying complexity, the concentration and isotopic measurements were used to study long-term change in the interhemispheric gradients in CO2 and 13C/12C to assess the magnitude and evolution of the northern terrestrial carbon sink, to study the increase in amplitude of the seasonal cycle of CO2, to use isotopic data to refine constraints on large scale changes in isotopic fractionation which may be related to changes in stomatal conductance, and to motivate improvements in terrestrial carbon cycle models. The original proposal called for a continuation of the new time series of 14C measurements but subsequent descoping to meet budgetary constraints required termination of measurements in 2007.

Stephen C. Piper; Ralph F. Keeling

2012-01-03T23:59:59.000Z

171

Surface water and atmospheric underway carbon data obtained during the World Ocean Circulation Experiment Indian Ocean survey cruises (R/V Knorr, December 1998--January 1996)  

SciTech Connect

This data documentation presents the results of the surface water and atmospheric underway measurements of mole fraction of carbon dioxide (xCO{sub 2}), sea surface salinity, and sea surface temperature, obtained during the World Ocean Circulation Experiment (WOCE) Indian Ocean survey cruises (December 1994--January 1996). Discrete and underway carbon measurements were made by members of the CO{sub 2} survey team. The survey team is a part of the Joint Global Ocean Flux Study supported by the US Department of Energy to make carbon-related measurements on the WOCE global survey cruises. Approximately 200,000 surface seawater and 50,000 marine air xCO{sub 2} measurements were recorded.

Kozyr, A. [Univ. of Tennessee, Knoxville, TN (United States). Energy, Environment, and Resources Center; Allison, L. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center

1997-11-01T23:59:59.000Z

172

Production of SNG from shale oil by catalytic gasification in a steam-hydrogen atmosphere  

DOE Green Energy (OSTI)

This report presents the results from experiments performed at the Laramie Energy Technology Center (LETC) of the Department of Energy (DOE) to produce a substitute natural gas (SNG) from shale oil via catalytic gasification in a steam-hydrogen atmosphere. Also contained is a comparison of the yields of SNG obtained with those from previous experiments performed at LETC in which shale oil was catalytically gasified in a pure hydrogen atmosphere. The maximum yield of gas obtained in the Stream-hydrogen experiments corresponded to 75 wt % of the feed carbon being recovered as gas. This maximum yield was obtained at the highest temperature (1300/sup 0/F (978/sup 0/K)) and hydrogen partial pressure (900 psig (6205 kPa)) tested, while the gas yield for gasification in a pure hydrogen atmosphere was 86 wt % of feed carbon at similar operating conditions. The reduced yield was attributed to poisoning of the cobalt-molybdate catalyst employed by carbon monoxide generated in small amounts from the reaction of steam with carbon and/or hydrocarons in the gasification reactor.

Stagner, M.J.; Barker, L.K.

1979-12-01T23:59:59.000Z

173

Mitigation of atmospheric carbon emissions through increased energy efficiency versus increased non-carbon energy sources: A trade study using a simplified {open_quotes}market-free{close_quotes} exogenously driven model  

SciTech Connect

A simplified model of global, long-term energy use is described and used to make a `top-level` comparison of two generic approaches for mitigating atmospheric carbon emissions: (a) those based on increased energy efficiency; and (b) those based on increased use of reduced- or non-carbon fuels. As approximate as is the model, first-order estimates of and trade offs between increasing non-carbon generation capacities (e.g., supply-side solutions) versus energy-use efficiency (e.g., demand-side solutions) to stem atmospheric carbon accumulations can be useful in guiding more elaborate models. At the level of this analysis, both the costs of abatement and the costs of damage can be large, with the formation of benefit-to-cost ratios as a means of assessment being limited by uncertainties associated with relating given climatic responses to greenhouse warming to aggregate damage cost, as well as uncertainties associated with procedures used for multi-generation discounting of both abatement and damage costs. In view of uncertainties associated with both supply-side and demand-side approaches, as well as the estimation of greenhouse-warming responses per se, a combination of solutions seems prudent. Key findings are: (a) the relative insensitivity of the benefit-to-cost ratio adopted in this study to supply-side versus demand-side approaches to abating atmospheric carbon-dioxide emissions; (b) the extreme sensitivity of damage costs, abatement costs, and the related benefit-to-cost ratios to the combination of discounting procedure and the (time) concavity of the function used to relate global temperature rise to damage costs; and (c) no matter the discounting procedure and/or functional relationship between average temperature rise and a damage cost, a goal of increased per-capita gross world product at minimum damage suggests action now rather than delay.

Krakowski, R.A.

1997-08-24T23:59:59.000Z

174

Computational fluid dynamics simulations of oxy-coal combustion for carbon capture at atmospheric and elevated pressures  

E-Print Network (OSTI)

Oxy-fuel combustion of solid fuels, often performed in a mixture of oxygen and wet or dry recycled carbon dioxide, has gained significant interest in the last two decades as one of the leading carbon capture technologies ...

Chen, Lei, Ph. D. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

175

Infrared spectra of the photosorption products of hydrogen and carbon monoxide on Al/sub 2/O/sub 3/ and SiO/sub 2/ containing transition-metal ions  

Science Conference Proceedings (OSTI)

It has been demonstrated by IR spectroscopy that the irradiation of samples of V/sup 5 +//SiO/sub 2/, V/sup 5 +//Al/sub 2/O/sub 3/, and Ni/sup 2 +//Al/sub 2/O/sub 3/ in an atmosphere of D/sub 2/ causes the isotope replacement of hydrogen atoms of the hydroxyl groups on the surface of the support and results in the formation of OD groups on photoinduced V/sup 4 +/O/sup -/ sites. Molecules of CO are photosorbed both on reduced ions of transition metals in the form of M-CVertical BarO surface carbonyls and on O/sup -/ ions. In the latter case, CO/sub 2/, which is easily desorbed from V/sup 5 +//SiO/sub 2/, but is tightly bound to V/sup 5 +//Al/sub 2/O/sub 3/ owing to the chemisorption on the surface of the support, is formed on the samples containing vanadium.

Gerasimov, S.F.; Filimonov, V.N.

1981-10-01T23:59:59.000Z

176

Regional Impacts of Climate Change and Atmospheric CO2 on Future Ocean Carbon Uptake: A Multimodel Linear Feedback Analysis  

Science Conference Proceedings (OSTI)

The increase in atmospheric CO2 over this century depends on the evolution of the oceanic air–sea CO2 uptake, which will be driven by the combined response to rising atmospheric CO2 itself and climate change. Here, the future oceanic CO2 uptake is ...

Tilla Roy; Laurent Bopp; Marion Gehlen; Birgit Schneider; Patricia Cadule; Thomas L. Frölicher; Joachim Segschneider; Jerry Tjiputra; Christoph Heinze; Fortunat Joos

2011-05-01T23:59:59.000Z

177

News Briefs  

Science Conference Proceedings (OSTI)

... regional carbon in atmospheric methane, carbon monoxide ... An SFG spectrum thus provides information ... improve immunity to vibration, and create ...

1997-04-03T23:59:59.000Z

178

Response of a tundra ecosystem to elevated atmospheric carbon dioxide and CO{sub 2}-induced climate change. Annual technical report  

Science Conference Proceedings (OSTI)

Northern ecosystems contain up to 455 Gt of C in the soil active layer and upper permafrost, which is equivalent to approximately 60% of the carbon currently in the atmosphere as CO{sub 2}. Much of this carbon is stored in the soil as dead organic matter. Its fate is subject to the net effects of global change on the plant and soil systems of northern ecosystems. The arctic alone contains about 60 Gt C, 90% of which is present in the soil active layer and upper permafrost, and is assumed to have been a sink for CO{sub 2} during the historic and recent geologic past. Depending on the nature, rate, and magnitude of global environmental change, the arctic may have a positive or negative feedback on global change. Results from the DOE- funded research efforts of 1990 and 1991 indicate that the arctic has become a source of CO{sub 2} to the atmosphere. Measurements made in the Barrow, Alaska region during 1992 support these results. This change coincides with recent climatic variation in the arctic, and suggests a positive feedback of arctic ecosystems on atmospheric CO{sub 2} and global change. There are obvious potential errors in scaling plot level measurements to landscape, mesoscale, and global spatial scales. In light of the results from the recent DOE-funded research, and the remaining uncertainties regarding the change in arctic ecosystem function due to high latitude warming, a revised set of research goals is proposed for the 1993--94 year. The research proposed in this application has four principal aspects: (A) Long- term response of arctic plants and ecosystems to elevated atmospheric CO{sub 2}. (B) Circumpolar patterns of net ecosystem CO{sub 2} flux. (C) In situ controls by temperature and moisture on net ecosystem CO{sub 2} flux. (D) Scaling of CO{sub 2} flux from plot, to landscape, to regional scales.

Oechel, W.C.

1993-02-01T23:59:59.000Z

179

A Concept for a Gas-Filter Correlation Radiometer to Remotely Sense the Atmospheric Carbon Dioxide Column from Space  

Science Conference Proceedings (OSTI)

Concern about the climatic effects of anthropogenic emissions of CO2 has resulted in a growing need, both scientifically and politically, to monitor atmospheric CO2. The development of a satellite instrument that could measure the global ...

Boyd T. Tolton

2004-05-01T23:59:59.000Z

180

Black Carbon’s Properties and Role in the Environment: A Comprehensive Review  

E-Print Network (OSTI)

Keywords: soil carbon sequestration; carbon budget;of an energy efficient carbon sequestration mechanism, asin the later section on carbon sequestration. In atmospheric

Shrestha, Gyami

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Performance of carbon-based hot frit substrates. 2, Coating performance studies in hydrogen at atmospheric pressure  

DOE Green Energy (OSTI)

Erosion tests were conducted on coated graphite and 2D, 3D carbon- carbons in 1 atm hydrogen at high temperatures. Refractory NbC, TaC coatings were used. It was found that the most effective combination of coating and substrate was TaC deposited by chemical vapor reaction method on AXF-5QI graphite.

Barletta, R.; Vanier, P.; Adams, J.; Svandrlik, J.; Powell, J.R.

1993-07-01T23:59:59.000Z

182

Reconciling estimates of the contemporary North American carbon balance among terrestrial biosphere models, atmospheric inversions and a new approach for estimating net ecosystem exchange from inventory-based data  

Science Conference Proceedings (OSTI)

While fossil fuel emissions are calculated with relatively high precision, understanding the fate of those emissions with respect to sequestration in terrestrial ecosystems requires data and methods that can reduce uncertainties in the diagnosis of land-based CO2 sinks. The wide range in the land surface flux estimates is related to a number of factors, but most generally because of the different methodologies used to develop estimates of carbon stocks and flux, and the uncertainties inherent in each approach. The alternative approaches to estimating continental scale carbon fluxes that we explored here can be broadly classified as applying a top-down or bottom-up perspective. Top-down approaches calculate land-atmosphere carbon fluxes based on atmospheric budgets and inverse modeling. Bottom-up approaches rely primarily on measurements of carbon stock changes (the inventory approach) or on spatially distributed simulations of carbon stocks and/or fluxes using process-based modeling (the forward modelapproach).

Hayes, D. J.; Turner, D. P.; Stinson, Graham; McGuire, A. David; Wei, Yaxing; West, Tristram O.; Heath, L.; deJong, B.; McConkey, Brian; Birdsey, Richard A.; Kurz, Werner; Jacobson, Andy; Huntzinger, Deborah N.; Pan, Y.; Post, W. M.; Cook, R. B.

2012-04-02T23:59:59.000Z

183

Estimation of methane and carbon dioxide surface fluxes using a 3-D global atmospheric chemical transport model  

E-Print Network (OSTI)

Methane (CH?) and carbon dioxide (CO?) are the two most radiatively important greenhouse gases attributable to human activity. Large uncertainties in their source and sink magnitudes currently exist. We estimate global ...

Chen, Yu-Han, 1973-

2004-01-01T23:59:59.000Z

184

Analysis of the carbon dioxide concentration in the lowest atmospheric layers and the factors affecting China based on satellite observations  

Science Conference Proceedings (OSTI)

Carbon dioxide CO2 is the most important anthropogenic greenhouse gas contributing to global climate change. SCIAMACHY on board ENVISAT launched in 2002 is the first satellite instrument to monitor the changes in CO2 concentration ...

Yanfang Hou; Shixin Wang; Yi Zhou; Fuli Yan; Jinfeng Zhu

2013-03-01T23:59:59.000Z

185

On the Influence of Pacific Ocean Temperatures on Atmospheric Carbon Dioxide Concentration at Ocean Weather Station P  

Science Conference Proceedings (OSTI)

The study presents an analysis of atmospheric CO2 measurements at Ocean Weather Station P (50°N, 145°W) and sea surface temperatures over the North Pacific for the period 1974–78. The results show that during 1976 and 1977 sea surface ...

Kirby J. Hanson; James T. Peterson; Jerome Namias; Robert Born; C. S. Wong

1981-07-01T23:59:59.000Z

186

BSA 01-07: Carbon Monoxide Tolerant Fuel Cell Electrocatalyst  

This fuel cell anode includes an electrocatalyst that has a conductive support material, ... Brookhaven National Laboratory conducts research in the ...

187

Premixed Carbon Monoxide–Nitrous Oxide–Hydrogen Flames ...  

Science Conference Proceedings (OSTI)

... the combustion emission charac- teristics of stationary and mobile power plants. ... present data are in good agreement with the low-hydro- gen data ...

2012-12-06T23:59:59.000Z

188

Stimulation of aortic and carotid chemoreceptors during carbon monoxide inhalation  

SciTech Connect

The decrease in local tissue PO/sub 2/ that occurs with carboxyhemoglobinemia was thought to be responsible for the 2 to 5 times greater chemoreceptor impulse frequency in cats with 18 to 40% COHb.

Mills, E.; Edwards, M.W. Jr.

1968-01-01T23:59:59.000Z

189

Carbon Monoxide Formation in Fires by High-Temperature ...  

Science Conference Proceedings (OSTI)

... experiments. Page 7. FORMATION BY ANAEROBIC WOOD PYROLYSIS 1461 . ... 1990. Milne, T,, in Biomass Gasification. ...

1996-08-14T23:59:59.000Z

190

Carbon Isotopes  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » Carbon Isotopes Atmospheric Trace Gases » Carbon Isotopes Carbon Isotopes Gateway Pages to Isotopes Data Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and Carbon-13 in Methane 800,000 Deuterium Record and Shorter Records of Various Isotopic Species from Ice Cores Carbon-13 13C in CO Measurements from Niwot Ridge, Colorado and Montana de Oro, California (Tyler) 13C in CO2 NOAA/CMDL Flask Network (White and Vaughn) CSIRO GASLAB Flask Network (Allison, Francey, and Krummel) CSIRO in situ measurements at Cape Grim, Tasmania (Francey and Allison) Scripps Institution of Oceanography (Keeling et al.) 13C in CH4 NOAA/CMDL Flask Network (Miller and White) Northern & Southern Hemisphere Sites (Quay and Stutsman) Northern & Southern Hemisphere Sites (Stevens)

191

Environmental control technology for atmospheric carbon dioxide. Quarterly progress report No. 1, June 20, 1977--September 30, 1977  

DOE Green Energy (OSTI)

The primary objective of the subject program is to assess the potential options for controlling atmospheric CO/sub 2/. Accordingly, CO/sub 2/ control scenarios based on conventional technology and applied to the larger industrial emitters will be prepared. The studies will include preliminary cost estimates of selected processes, to identify fruitful areas for environmental control technology (ECT) programmatic development as related to CO/sub 2/ release control. BNL's prior experience in this area includes the development and evaluation of a number of processes for removing CO/sub 2/ from the atmosphere for the purpose of producing synthetic carbonaceous fuels including methanol, gasoline, and methane. Background information from other DOE programs will be used to determine the limitations for the control studies. This progress report presents background information on: (1) the concentration levels of CO/sub 2/ in the atmosphere during the last one hundred years; (2) the possible effects of rising CO/sub 2/ levels; (3) the impact of fossil fuel use in the United States on overall worldwide CO/sub 2/ emissions; (4) the impact of increased coal utilization on CO/sub 2/ emissions; and (5) process considerations for controlling CO/sub 2/.

Steinberg, M.; Albanese, A.S.; Dang, V.D.

1977-10-01T23:59:59.000Z

192

Carbon Dioxide Information Analysis Center and World Data Center-A for atmospheric trace gases: Fiscal year 1995 annual report  

SciTech Connect

Fiscal year 1995 was both a very productive year for the Carbon Dioxide Information Analysis Center and a year of significant change. This document presents information about the most notable accomplishments made during the year. Topics include: high-lights; statistics; future plans; publications, presentations, and awards; and change in organization and staff.

Burtis, M.D. [comp.; Cushman, R.M.; Boden, T.A.; Jones, S.B.; Nelson, T.; Stoss, F.W.

1996-01-01T23:59:59.000Z

193

Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter  

E-Print Network (OSTI)

hydrocarbons (toluene), alkanes (butane, methane, heptane),tube/GC (NIOSH 1 5 0 0 ) a Butane 300ppm Charcoal tube/GC (O toluene toluene + C O butane butane + C O methane methane

Apte, Michael G.

2010-01-01T23:59:59.000Z

194

Control of carbon balance in a silicon smelting furnace  

DOE Patents (OSTI)

The present invention is a process for the carbothermic reduction of silicon dioxide to form elemental silicon. Carbon balance of the process is assessed by measuring the amount of carbon monoxide evolved in offgas exiting the furnace. A ratio of the amount of carbon monoxide evolved and the amount of silicon dioxide added to the furnace is determined. Based on this ratio, the carbon balance of the furnace can be determined and carbon feed can be adjusted to maintain the furnace in carbon balance.

Dosaj, V.D.; Haines, C.M.; May, J.B.; Oleson, J.D.

1992-12-29T23:59:59.000Z

195

Atmospheric Aerosols  

NLE Websites -- All DOE Office Websites (Extended Search)

measuring equipment Atmospheric Aerosols Atmospheric aerosol research at Berkeley Lab seeks to understand the air quality and climate impacts of particles in the atmosphere. On...

196

ON CALCULATING THE TRANSFER OF CARBON-13 IN RESERVOIR MODELS OF THE CARBON CYCLE  

E-Print Network (OSTI)

7. Keeling. C. D. 1973. The carbon dioxide cycle: reservoirexchange of atmospheric carbon dioxide with the oceans andmodel to study the carbon dioxide exchange in nature. Tellus

Tans, Pieter P.

2013-01-01T23:59:59.000Z

197

Enhanced research program on the long-range climatic effects of increased atmospheric carbon dioxide and sulfate aerosols. Final report  

SciTech Connect

Consistent with the objectives to extract as much as possible from existing models on the role of the oceans in the greenhouse effect and to improve various aspects of the coupled system, the authors made significant progress in three areas. (1) In a series of manuscripts, they documented how the El Nino-Southern Oscillation operates in the model and how it is enhanced with increased carbon dioxide. (2) In studies with collaborators Branstator, Karoly, and Karl, they explored the possible carbon dioxide ``fingerprint`` in zonal mean temperatures, the effects of changes in extratropical teleconnections, and the regional effects of low-frequency variability and climate change. (3) They experimented with an advanced version of the NCAR community climate model (CCM0) that also includes the Ramanathan and Collins cirrus albedo feedback mechanism. This model was run with a mixed layer and was tested with the 1{degree} 20-level Semtner and Chervin ocean model. The latter includes the Arctic Ocean and dynamic sea ice, both showing realistic results. The authors completed the coupling of the advanced models. The dynamic ocean model was a 1{degree}x1{degree} version of the Semtner-Chervin 1/2{degree}x1/2{degree} ocean model with 20 vertical levels. The 1{degree}x1{degree} version of the Semtner-Chervin model used in this research explicitly resolved some aspects of the mesoscale eddies as did the parent model. The new coupled model system for greenhouse gas simulations on climate change was tested on multidecadal runs.

Washington, W.M.; Meehl, G.A.

1997-04-01T23:59:59.000Z

198

Alcohol fuel use: Implications for atmospheric levels of aldehydes, organic nitrates, pans, and peroxides: Separating sources using carbon isotopes  

DOE Green Energy (OSTI)

We have developed DiNitroPhenylHydrazone (DNPH) derivatization--high performance liquid chromatographic methods for measuring aldehydes in ambient samples with detection limits of approximately 1ppbV. These methods can be used for air or precipitation studies, and have been used for indoor measurements at much higher levels using shorter integration times. We are using gas chromatographs with electron capture detection (GCECD) to measure ambient levels of peroxyacyl nitrates and organic nitrates. Diffusion tubes with synthetically produced organic nitrates in n-tridecane solution are used to calibrate these systems. These compounds are important means of transporting NO/sub x/ over large scales due to their reduced tropospheric reactivity, low water solubilities, photolytic, and thermal stability. Their chemistries are coupled to aldehyde chemistry and are important greenhouse gases as well as phytotoxins. We have completed preliminary studies in Rio de Janeiro examining the atmospheric chemistry consequences of ethanol fuel usage. The urban air mass has been effected by the direct uncontrolled usage of ethanolgasoline and ethanoldiesel mixtures. We are exploring the use of luminol chemiluminescent detection of peroxides using gas chromatography to separate the various organic and inorganic peroxides. These compounds are coupled to the aldehyde chemistry, particularly in remote chemistries down-wind of urban sources. 13 refs.

Gaffney, J.S.; Tanner, R.L.

1988-01-01T23:59:59.000Z

199

Transient response of the Hadley Centre coupled ocean-atmosphere model to increasing carbon dioxide. Part 3: Analysis of global-mean response using simple models  

Science Conference Proceedings (OSTI)

The roles of surface, atmospheric, and oceanic feedbacks in controlling the global-mean transient response of a coupled ocean-atmosphere general circulation model (AOGCM) to increasing carbon dioxide are investigated. The analysis employs a four-box energy balance model (EBM) and an oceanic box-diffusion model (BDM) both tuned to the simulated general circulation model response. The land-sea contrast in the surface warming is explained almost entirely by the shortwave radiative feedbacks associated with changes in cloud and surface albedo. The oceanic thermal inertia delays the response; however, the initial delay is enhanced by increases in Anarctic sea-ice cover, which substantially reduce the effective climate sensitivity of the model in the first half of the 75-year experiment. When driven by the observed anthropogenic greenhouse forcing from the pre-industrial period to present day, the energy balance model overestimates the warming observed over land. However, inclusion of the direct forcing due to anthropogenic tropospheric sulphate aerosol eliminates the land/sea contrast in the response at 1990, leaving the simulated warming over land slightly below the observed value, although the rapid warming observed during the 1980s is well reproduced. The vertical penetration of the oceanic response is small below 1000 m. Within the top 1000 m the effective diffusivities are substantially enhanced by reduced convection and thermohaline overturning, driven by increased precipitation minus evaporation at high latitudes. These changes in ocean heat transport become significant after year 30, whereupon the effective oceanic heat capacity increases substantially, although this increase is partially offset by the effect of changes in the sea-ice margin.

Murphy, J.M. [Meteorological Office, Bracknell, Berkshire (United Kingdom)

1995-03-01T23:59:59.000Z

200

The Effect of Building Shadows on the Vertical Temperature Structure of the Lower Atmosphere in Downtown Denver  

Science Conference Proceedings (OSTI)

Denver's Continuous Air Monitoring Program (CAMP) site, typically recording the highest carbon monoxide levels in the metropolitan area; lies within a large region of downtown Denver shadowed by tall buildings. Two studies conducted during the ...

Dominique Ruffieux; Daniel E. Wolfe; Catherine Russell

1990-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Atmospheric Aerosols  

NLE Websites -- All DOE Office Websites (Extended Search)

Tom Kirchstetter with aerosol measurement instrument Atmospheric Aerosols Atmospheric aerosol research at LBNL seeks to understand the air quality and climate impacts of particles...

202

Nonlinearity of Carbon Cycle Feedbacks  

Science Conference Proceedings (OSTI)

Coupled climate–carbon models have shown the potential for large feedbacks between climate change, atmospheric CO2 concentrations, and global carbon sinks. Standard metrics of this feedback assume that the response of land and ocean carbon uptake ...

Kirsten Zickfeld; Michael Eby; H. Damon Matthews; Andreas Schmittner; Andrew J. Weaver

2011-08-01T23:59:59.000Z

203

INDOOR AIR QUALITY AND ENERGY EFFICIENT VENTILATION RATES AT A NEW YORK CITY ELEMENTARY SCHOOL  

E-Print Network (OSTI)

inorganic pollutants: carbon dioxide, carbon monoxide,odor perception, carbon dioxide, carbon monoxide, sulfurkeywords; pollution, carbon dioxide, carbon monoxide, energy

Young, Rodger A.

2013-01-01T23:59:59.000Z

204

Quantifying Carbon Cycle Feedbacks  

Science Conference Proceedings (OSTI)

Perturbations to the carbon cycle could constitute large feedbacks on future changes in atmospheric CO2 concentration and climate. This paper demonstrates how carbon cycle feedback can be expressed in formally similar ways to climate feedback, ...

J. M. Gregory; C. D. Jones; P. Cadule; P. Friedlingstein

2009-10-01T23:59:59.000Z

205

Reconciling carbon-cycle concepts, terminology, and methods  

E-Print Network (OSTI)

factors that determine whether particularly a or net source is sink of ecosystem atmospheric carbon dioxide (

2006-01-01T23:59:59.000Z

206

The Role of Circulation Features on Black Carbon Transport into the Arctic in the Community Atmosphere Model Version 5 (CAM5)  

SciTech Connect

Current climate models generally under-predict the surface concentration of black carbon (BC) in the Arctic due to the uncertainties associated with emissions, transport, and removal. This bias is also present in the Community Atmosphere Model Version 5.1 (CAM5). In this study, we investigate the uncertainty of Arctic BC due to transport processes simulated by CAM5 by configuring the model to run in an “offline mode” in which the large-scale circulations are prescribed. We compare the simulated BC transport when the offline model is driven by the meteorology predicted by the standard free-running CAM5 with simulations where the meteorology is constrained to agree with reanalysis products. Some circulation biases are apparent: the free-running CAM5 produces about 50% less transient eddy transport of BC than the reanalysis-driven simulations, which may be attributed to the coarse model resolution insufficient to represent eddies. Our analysis shows that the free-running CAM5 reasonably captures the essence of the Arctic Oscillation (AO), but some discernable differences in the spatial pattern of the AO between the free-running CAM5 and the reanalysis-driven simulations result in significantly different AO modulation of BC transport over Northeast Asia and Eastern Europe. Nevertheless, we find that the overall climatological circulation patterns simulated by the free-running CAM5 generally resembles those from the reanalysis products, and BC transport is very similar in both simulation sets. Therefore, the simulated circulation features regulating the long-range BC transport is unlikely the most important cause of the large under-prediction of surface BC concentration in the Arctic.

Ma, Po-Lun; Rasch, Philip J.; Wang, Hailong; Zhang, Kai; Easter, Richard C.; Tilmes, S.; Fast, Jerome D.; Liu, Xiaohong; Yoon, Jin-Ho; Lamarque, Jean-Francois

2013-05-28T23:59:59.000Z

207

Ultraviolet photoelectron spectroscopy of molybdenum and molybdenum monoxide anions  

E-Print Network (OSTI)

of Utah, Salt Lake City, Utah 84112 Received 30 May 1995; accepted 23 October 1995 The 351 nm photoelectron spectra of Mo and MoO have been measured. The electron affinity of atomic molybdenum is 0.748 2 e- denum monoxide illustrates these difficulties especially well, since the molybdenum atomic ground state

Lineberger, W. Carl

208

The Woodland Carbon Code  

E-Print Network (OSTI)

The Woodland Carbon Code While society must continue to make every effort to reduce greenhouse gas a role by removing carbon dioxide from the atmosphere. The potential of woodlands to soak up carbon to help compensate for their carbon emissions. But before investing in such projects, people want to know

209

Carbon Dioxide Information Analysis Center (CDIAC)  

NLE Websites -- All DOE Office Websites (Extended Search)

available free of charge - include estimates of carbon dioxide emissions from fossil-fuel consumption and land-use changes; records of atmospheric concentrations of carbon...

210

Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein  

DOE Patents (OSTI)

A thermochemical cyclic process for producing hydrogen from water comprises reacting ceric oxide with monobasic or dibasic alkali metal phosphate to yield a solid reaction product, oxygen and water. The solid reaction product, alkali metal carbonate or bicarbonate, and water, are reacted to yield hydrogen, ceric oxide, carbon dioxide and trialkali metal phosphate. Ceric oxide is recycled. Trialkali metal phosphate, carbon dioxide and water are reacted to yield monobasic or dibasic alkali metal phosphate and alkali metal bicarbonate, which are recycled. The cylic process can be modified for producing carbon monoxide from carbon dioxide by reacting the alkali metal cerous phosphate and alkali metal carbonate or bicarbonate in the absence of water to produce carbon monoxide, ceric oxide, carbon dioxide and trialkali metal phosphate. Carbon monoxide can be converted to hydrogen by the water gas shift reaction.

Bamberger, Carlos E. (Oak Ridge, TN); Robinson, Paul R. (Knoxville, TN)

1980-01-01T23:59:59.000Z

211

Carbon abundances of early B-type stars in the solar vicinity. Non-LTE line-formation for C II/III/IV and self-consistent atmospheric parameters  

E-Print Network (OSTI)

Precise determinations of the chemical composition in early B-type stars consitute fundamental observational constraints on stellar and galactochemical evolution. Carbon is one of the most abundant metals in the Universe but analyses in early-type stars show inconclusive results, like large discrepancies between analyses of different lines in C II, a failure to establish the C II/III ionization balance and the derivation of systematically lower abundances than from other objects. We present a comprehensive and robust C II/III/IV model for non-LTE line-formation calculations based on carefully selected atomic data. The model is calibrated with high-S/N spectra of six apparently slow-rotating early B-type dwarfs and giants, which cover a wide parameter range and are randomly distributed in the solar neighbourhood. A self-consistent quantitative spectrum analysis is performed using an extensive iteration scheme to determine stellar atmospheric parameters and to select the appropriate atomic data used for the derivation of chemical abundances. We establish the carbon ionization balance for all sample stars based on a unique set of input atomic data, achieving consistency for all modelled lines. Highly accurate atmospheric parameters and a homogeneous carbon abundance with reduced systematic errors are derived. This results in a present-day stellar carbon abundance in the solar neighbourhood, which is in good agreement with recent determinations of the solar value and with the gas-phase abundance of the Orion H II region. The homogeneous present-day carbon abundance also conforms with predictions of chemical-evolution models for the Galaxy. The present approach allows us to constrain the effects of systematic errors on fundamental parameters and abundances. (abridged)

M. F. Nieva; N. Przybilla

2007-11-23T23:59:59.000Z

212

Generation and Solid Oxide Fuel Cell Carbon Sequestration in Northwest Indiana  

DOE Green Energy (OSTI)

The objective of the project is to develop the technology capable of capturing all carbon monoxide and carbon dioxide from natural gas fueled Solid Oxide Fuel Cell (SOFC) system. In addition, the technology to electrochemically oxidize any remaining carbon monoxide to carbon dioxide will be developed. Success of this R&D program would allow for the generation of electrical power and thermal power from a fossil fuel driven SOFC system without the carbon emissions resulting from any other fossil fueled power generationg system.

Kevin Peavey; Norm Bessette

2007-09-30T23:59:59.000Z

213

Reconciling estimates of the contemporary North American carbon balance among terrestrial biosphere models, atmospheric inversions and a new approach for estimating net ecosystem exchange from inventory-based data  

Science Conference Proceedings (OSTI)

We develop an approach for estimating net ecosystem exchange (NEE) using inventory-based information over North America (NA) for a recent 7-year period (ca. 2000 2006). The approach notably retains information on the spatial distribution of NEE, or the vertical exchange between land and atmosphere of all non-fossil fuel sources and sinks of CO2, while accounting for lateral transfers of forest and crop products as well as their eventual emissions. The total NEE estimate of a 327 252 TgC yr1 sink for NA was driven primarily by CO2 uptake in the Forest Lands sector (248 TgC yr1), largely in the Northwest and Southeast regions of the US, and in the Crop Lands sector (297 TgC yr1), predominantly in the Midwest US states. These sinks are counteracted by the carbon source estimated for the Other Lands sector (+218 TgC yr1), where much of the forest and crop products are assumed to be returned to the atmosphere (through livestock and human consumption). The ecosystems of Mexico are estimated tobe a small net source (+18 TgC yr1) due to land use change between 1993 and 2002. We compare these inventorybased estimates with results from a suite of terrestrial biosphere and atmospheric inversion models, where the mean continental-scale NEE estimate for each ensemble is 511 TgC yr1 and 931 TgC yr1, respectively. In the modeling approaches, all sectors, including Other Lands, were generally estimated to be a carbon sink, driven in part by assumed CO2 fertilization and/or lack of consideration of carbon sources from disturbances and product emissions. Additional fluxes not measured by the inventories, although highly uncertain, could add an additional 239 TgC yr1 to the inventory-based NA sink estimate, thus suggesting some convergence with the modeling approaches.

Hayes, Daniel J [ORNL; Turner, David P [Oregon State University, Corvallis; Stinson, Graham [Pacific Forestry Centre, Canadian Forest Service; Mcguire, David [University of Alaska; Wei, Yaxing [ORNL; West, Tristram O. [Joint Global Change Research Institute, PNNL; Heath, Linda S. [USDA Forest Service; De Jong, Bernardus [ECOSUR; McConkey, Brian G. [Agriculture and Agri-Food Canada; Birdsey, Richard A. [U.S. Department of Agriculture Forest Service; Kurz, Werner [Canadian Forest Service; Jacobson, Andrew [NOAA ESRL and CIRES; Huntzinger, Deborah [University of Michigan; Pan, Yude [U.S. Department of Agriculture Forest Service; Post, Wilfred M [ORNL; Cook, Robert B [ORNL

2012-01-01T23:59:59.000Z

214

Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide  

DOE Patents (OSTI)

A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

Rathke, Jerome W. (Lockport, IL); Klingler, Robert J. (Westmount, IL)

1993-01-01T23:59:59.000Z

215

Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide  

DOE Patents (OSTI)

A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

Rathke, J.W.; Klingler, R.J.

1992-12-31T23:59:59.000Z

216

Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide  

DOE Patents (OSTI)

A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

Rathke, J.W.; Klingler, R.J.

1993-03-30T23:59:59.000Z

217

Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts  

E-Print Network (OSTI)

are on the decline of the peak oil production curve, and thedue to the impending peak in oil production and the threatoil production curves for those countries that have passed peak

Smieja, Jonathan Mark

2012-01-01T23:59:59.000Z

218

Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts  

E-Print Network (OSTI)

fuels but also shows that total energy usage has increasedfuels, but also shows that total energy usage has increased

Smieja, Jonathan Mark

2012-01-01T23:59:59.000Z

219

Hydroxyl, water, ammonia, carbon monoxide and neutral carbon towards the Sgr A complex  

E-Print Network (OSTI)

We observed OH, H$_2$O, HN$_3$, C$^{18}$O, and C$_I$ towards the +50 km/s cloud (M-0.02-0.07), the CND and the +20 km/s (M-0.13-0.08) cloud in the Sgr A complex with the VLA, Odin and SEST. Strong OH absorption, H$_2$O emission and absorption lines were seen at all three positions. Strong C$^{18}$O emissions were seen towards the +50 and +20 km/s clouds. The CND is rich in H$_2$O and OH, and these abundances are considerably higher than in the surrounding clouds, indicating that shocks, star formation and clump collisions prevail in those objects. A comparison with the literature reveals that it is likely that PDR chemistry including grain surface reactions, and perhaps also the influences of shocks has led to the observed abundances of the observed molecular species studied here. In the redward high-velocity line wings of both the +50 and +20 km/s clouds and the CND, the very high H$_2$O abundances are suggested to be caused by the combined action of shock desorption from icy grain mantles and high-temperatu...

Karlsson, Roland; Hjalmarson, Ĺke; Winnberg, Anders; Fathi, Kambiz; Frisk, Urban; Olberg, Michael

2013-01-01T23:59:59.000Z

220

Atmospheric Chemistry and Physics  

E-Print Network (OSTI)

Abstract. A 3-D chemistry-transport model has been applied to the Mexico City metropolitan area to investigate the origin of elevated levels of non-fossil (NF) carbonaceous aerosols observed in this highly urbanized region. High time resolution measurements of the fine aerosol concentration and composition, and 12 or 24 h integrated 14 C measurements of aerosol modern carbon have been performed in and near Mexico City during the March 2006 MILAGRO field experiment. The non-fossil carbon fraction (fNF), which is lower than the measured modern fraction (fM) due to the elevated 14 C in the atmosphere caused by nuclear bomb testing, is estimated from the measured fM and the source-dependent information on modern carbon enrichment. The fNF contained in PM1 total carbon analyzed by a US team (f TC

unknown authors

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Air and steam coal partial gasification in an atmospheric fluidized bed  

Science Conference Proceedings (OSTI)

Using the mixture of air and steam as gasification medium, three different rank coal partial gasification studies were carried out in a bench-scale atmospheric fluidized bed with the various operating parameters. The effects of air/coal (Fa/Fc) ratio, steam/coal (Fs/Fc) ratio, bed temperature, and coal rank on the fuel gas compositions and the high heating value (HHV) were reported in this paper. The results show that there is an optimal Fa/Fc ratio and Fs/Fc ratio for coal partial gasification. A rise of bed temperature favors the semigasification reaction of coal, but the concentrations of carbon monoxide and methane and the HHV decrease with the rise of bed temperature, except hydrogen. In addition, the gas HHVs are between 2.2 and 3.4 MJ/Nm{sup 3}. The gas yield and carbon conversion increase with Fa/Fc ratio, Fs/Fc ratio, and bed temperature, while they decrease with the rise of the rank of coal. 7 refs., 9 figs., 2 tabs.

Hongcang Zhou; Baosheng Jing; Zhaoping Zhong; Yaji Huang; Rui Xiao [Nanjing University of Information Science & Technology, Nanjing (China). Department of Environmental Science & Engineering

2005-08-01T23:59:59.000Z

222

Global Warming and Greenhouse Gases  

Science Conference Proceedings (OSTI)

... NIST is producing new suites of primary gas standards for carbon dioxide, methane, carbon monoxide, and nitrous oxide in air at atmospheric levels ...

2013-09-20T23:59:59.000Z

223

ARM - Measurement - Atmospheric pressure  

NLE Websites -- All DOE Office Websites (Extended Search)

pressure pressure ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric pressure The pressure exerted by the atmosphere as a consequence of gravitational attraction exerted upon the "column" of air lying directly above the point in question. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments SONDE : Balloon-Borne Sounding System CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

224

ARM - Measurement - Atmospheric temperature  

NLE Websites -- All DOE Office Websites (Extended Search)

temperature temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric temperature The temperature indicated by a thermometer exposed to the air in a place sheltered from direct solar radiation. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments AERI : Atmospheric Emitted Radiance Interferometer SONDE : Balloon-Borne Sounding System CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

225

Carbon dioxide capture process with regenerable sorbents  

DOE Patents (OSTI)

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

226

Development of an Atmospheric Carbon Dioxide Standard Gas Saving System and Its Application to a Measurement at a Site in the West Siberian Forest  

Science Conference Proceedings (OSTI)

Observations of the atmospheric CO2 concentration from a 90-m tower in Berezorechka, western Siberia, that have taken place since October 2001 were used to characterize CO2 variations over a vast boreal forest area. A new CO2 standard gas saving ...

T. Watai; T. Machida; K. Shimoyama; O. Krasnov; M. Yamamoto; G. Inoue

2010-05-01T23:59:59.000Z

227

The Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Carbon Cycle The Carbon Cycle The global carbon cycle involves the carbon in and exchanging between the earth's atmosphere, fossil fuels, the oceans, and the vegetation and soils of the earth's terrestrial ecosystems. image Each year, the world's terrestrial ecosystems withdraw carbon from the atmosphere through photosynthesis and add it again through respiration and decay. A more detailed look at the global carbon cycle for the 1990s is shown below. The main annual fluxes in GtC yr-1 are: pre-industrial "natural" fluxes in black and "anthropogenic" fluxes in red (modified from Sarmiento and Gruber, 2006, with changes in pool sizes from Sabine et al., 2004a). The net terrestrial loss of -39 GtC is inferred from cumulative fossil fuel emissions minus atmospheric increase minus ocean storage. The loss of

228

Atmospheric deposition of polycyclic aromatic hydrocarbons in an urban and a suburban area of Korea from 2002 to 2004  

SciTech Connect

Atmospheric bulk samples (wet and dry) were collected monthly during 2002 to 2004 from an urban and a suburban area in Korea for assessment of depositional flux and seasonal variations in the concentrations of polycyclic aromatic hydrocarbons (PAHs). PAH depositional flux ranged from 64.1 to 610 {mu} g/m{sup 2}/y for the urban area and from 65 to 460 {mu} g/m{sup 2}/y for the suburban area. The fluxes of PAHs measured in this study were comparable with those reported for urban and suburban areas in other countries. The fluxes of particulates and PAHs were higher in winter than in summer, consistent with the greater per capita consumption of fossil fuel in winter than in summer. Ambient temperature played a major role in the seasonal variability in PAH fluxes. Photochemical degradation of PAHs appears to occur during the summer months. The relationship of PAH depositional fluxes with major air pollutants, such as ozone, sulfur dioxide, carbon monoxide, nitrogen dioxide, and presence of particulate matter up to 10 {mu} m in size (PM10), was also investigated. Dominant PAH compounds in both the urban and the suburban locations were benzo(g,h,i)perylene, pyrene, and indeno(1,2,3-c,d)pyrene. Based on the PAH diagnostic ratios and a factor analysis, the major sources of PAHs in the urban and the suburban regions were found to be similar. Diesel exhaust, coal combustion, and gasoline emissions contributed predominantly to atmospheric PAH contamination.

Moon, H.B.; Kannan, K.; Lee, S.J.; Ok, G. [National Fisheries Research & Development Institute, Pusan (Republic of Korea)

2006-11-15T23:59:59.000Z

229

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents (OSTI)

The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

Liu, D. Kwok-Keung; Chang, Shih-Ger

1987-08-25T23:59:59.000Z

230

A tight-binding potential for atomistic simulations of carbon interacting with transition metals: Application to the Ni-C system  

E-Print Network (OSTI)

, such as steam reforming of methane and methanation of carbon monoxide.2 Another more recent example catalytic reactions in relation with the air pollution problem. Sur- face reactions of methane on nickel

Paris-Sud XI, Université de

231

Graphics: Atmospheric Trace Gases in Whole-Air Samples  

NLE Websites -- All DOE Office Websites (Extended Search)

Graphics graphics Graphics: Atmospheric Trace Gases in Whole-Air Samples The following links are for methane, nonmethane hydrocarbons, alkyl nitrates, and chlorinated carbon...

232

Atmospheric CO2 Record from Continuous Measurements at Jubany...  

NLE Websites -- All DOE Office Websites (Extended Search)

PNRA (National Research Program in Antarctica) began continuous atmospheric carbon dioxide measurements at Jubany in 1994. The laboratory at Jubany Station is operated...

233

Atmospheric Aerosol Chemistry, Climate Change, and Air Quality  

NLE Websites -- All DOE Office Websites (Extended Search)

spectrometry capabilities to analyze the molecular composition of atmospheric organic aerosols, or OA, containing nitrogen- containing organic compounds (NOC) and only carbon,...

234

Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model  

SciTech Connect

Characterizing flow patterns and mixing of fossil fuel-derived CO{sub 2} is important for effectively using atmospheric measurements to constrain emissions inventories. Here we used measurements and a model of atmospheric radiocarbon ({sup 14}C) to investigate the distribution and fluxes of atmospheric fossil fuel CO{sub 2} across the state of California. We sampled {sup 14}C in annual C{sub 3} grasses at 128 sites and used these measurements to test a regional model that simulated anthropogenic and ecosystem CO{sub 2} fluxes, transport in the atmosphere, and the resulting {sup 14}C of annual grasses ({Delta}{sub g}). Average measured {Delta}{sub g} in Los Angeles, San Francisco, the Central Valley, and the North Coast were 27.7 {+-} 20.0, 44.0 {+-} 10.9, 48.7 {+-} 1.9, and 59.9 {+-} 2.5{per_thousand}, respectively, during the 2004-2005 growing season. Model predictions reproduced regional patterns reasonably well, with estimates of 27.6 {+-} 2.4, 39.4 {+-} 3.9, 46.8 {+-} 3.0, and 59.3 {+-} 0.2{per_thousand} for these same regions and corresponding to fossil fuel CO{sub 2} mixing ratios (Cf) of 13.7, 6.1, 4.8, and 0.3 ppm. {Delta}{sub g} spatial heterogeneity in Los Angeles and San Francisco was higher in the measurements than in the predictions, probably from insufficient spatial resolution in the fossil fuel inventories (e.g., freeways are not explicitly included) and transport (e.g., within valleys). We used the model to predict monthly and annual transport patterns of fossil fuel-derived CO{sub 2} within and out of California. Fossil fuel CO{sub 2} emitted in Los Angeles and San Francisco was predicted to move into the Central Valley, raising Cf above that expected from local emissions alone. Annually, about 21, 39, 35, and 5% of fossil fuel emissions leave the California airspace to the north, east, south, and west, respectively, with large seasonal variations in the proportions. Positive correlations between westward fluxes and Santa Ana wind conditions were observed. The southward fluxes over the Pacific Ocean were maintained in a relatively coherent flow within the marine boundary layer, while the eastward fluxes were more vertically dispersed. Our results indicate that state and continental scale atmospheric inversions need to consider areas where concentration measurements are sparse (e.g., over the ocean to the south and west of California), transport within and across the marine boundary layer, and terrestrial boundary layer dynamics. Measurements of {Delta}{sub g} can be very useful in constraining these estimates.

Riley, W.J.; Hsueh, D.Y.; Randerson, J.T.; Fischer, M.L.; Hatch, J.G.; Pataki, D.E.; Wang, W.; Goulden, M.L.

2008-05-01T23:59:59.000Z

235

ARM - Measurement - Atmospheric turbulence  

NLE Websites -- All DOE Office Websites (Extended Search)

turbulence turbulence ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric turbulence High frequency velocity fluctuations that lead to turbulent transport of momentum, heat, mositure, and passive scalars, and often expressed in terms of variances and covariances. Categories Atmospheric State, Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments CO2FLX : Carbon Dioxide Flux Measurement Systems ECOR : Eddy Correlation Flux Measurement System

236

Human effects on the global atmosphere  

SciTech Connect

This review considers whether human activities can significantly change important functions of the global atmosphere by altering the amount or distribution of certain trace species. It deals with three specific topics: stratopheric ozone, the role of species other than carbon dioxide on the greenhouse effect, and certain recently recognized atmospheric consequences of a large scale nuclear war. 64 references, 10 figures, 2 tables.

Johnston, H.S.

1984-01-01T23:59:59.000Z

237

The responses of net primary production (NPP) and total carbon storage for the continental United States to changes in atmospheric CO{sub 2}, climate, and vegetation  

Science Conference Proceedings (OSTI)

We extrapolated 3 biogeochemistry models (BIOME-BGC, CENTURY, and TEM) across the continental US with the vegetation distributions of 3 biogeography models (BIOME2, DOLY, and MAPSS) for contemporary climate at 355 ppmv CO{sub 2} and each of 3 GCM climate scenarios at 710 ppmv. For contemporary conditions, continental NPP ranges from 3132 to 3854 TgC/yr and total carbon storage ranges from 109 to 125 PgC. The responses of NPP range from no response (BIOME-BGC with DOLY or MAPSS vegetations for UKMO climate) to increases of 53% and 56% (TEM with BIOME2 vegetations for GFDL and OSU climates). The responses of total carbon storage vary from a decrease of 39% (BIOME-BGC with MAPSS vegetation for UKMO climate) to increases of 52% and 56% (TEM with BIOME2 vegetations for OSU and GFDL climates). The UKMO responses of BIOME-BGC with MAPSS vegetation are caused by both decreased forest area (from 44% to 38%) and photosynthetic water stress. The OSU and GFDL responses of TEM with BIOME2 vegetations are caused by forest expansion (from 46% to 67% for OSU and to 75% for GFDL) and increased nitrogen cycling.

McGuire, D.A. [Marine Biological Lab., Woods Hole, MA (United States)

1995-06-01T23:59:59.000Z

238

(Chemistry of the global atmosphere)  

SciTech Connect

The traveler attended the conference The Chemistry of the Global Atmosphere,'' and presented a paper on the anthropogenic emission of carbon dioxide (CO{sub 2}) to the atmosphere. The conference included meetings of the International Global Atmospheric Chemistry (IGAC) programme, a core project of the International Geosphere/Biosphere Programme (IGBP) and the traveler participated in meetings on the IGAC project Development of Global Emissions Inventories'' and agreed to coordinate the working group on CO{sub 2}. Papers presented at the conference focused on the latest developments in analytical methods, modeling and understanding of atmospheric CO{sub 2}, CO, CH{sub 4}, N{sub 2}O, SO{sub 2}, NO{sub x}, NMHCs, CFCs, and aerosols.

Marland, G.

1990-09-27T23:59:59.000Z

239

Formation of Carbon Dwarfs  

E-Print Network (OSTI)

We consider the formation of dwarf carbon stars via accretion from a carbon AGB companion in light of the new 107 object sample of Downes et al. (2004). This sample is now large enough to allow good mass determination via comparison of a composite spectrum to theoretical atmospheric models. Carbon dwarfs of spectral type M are indeed main sequence M dwarfs with enhanced metallicity and carbon abundance. We also calculate the predicted abundance of both M and of F/G carbon dwarfs, and show that the latter should be falsifiable in the near future.

Charles L. Steinhardt; Dimitar D. Sasselov

2005-02-08T23:59:59.000Z

240

NETL: Carbon Dioxide 101 FAQs  

NLE Websites -- All DOE Office Websites (Extended Search)

is carbon dioxide? is carbon dioxide? CO2 Dipole Carbon Dioxide Carbon dioxide (chemical name CO2) is a clear gas composed of one atom of carbon (C) and two atoms of oxygen (O). Carbon dioxide is one of many chemical forms of carbon on the Earth. It does not burn, and in standard temperature and pressure conditions it is stable, inert, and non-toxic. Carbon dioxide occurs naturally in small amounts (about 0.04%) in the Earth's atmosphere. The volume of CO2 in the atmosphere is equivalent to one individual in a crowd of 2,500. Carbon dioxide is produced naturally by processes deep within the Earth. This CO2 can be released at the surface by volcanoes or might be trapped in natural underground geologic CO2 deposits, similar to underground deposits of oil and natural gas. As a major greenhouse gas, CO2 helps create and

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Large Scale Atmospheric Chemistry Simulations for 2001: An Analysis of Ozone and Other Species in Central Arizona  

DOE Green Energy (OSTI)

A key atmospheric gas is ozone. Ozone in the stratosphere is beneficial to the biosphere because it absorbs a significant fraction of the sun's shorter wavelength ultraviolet radiation. Ozone in the troposphere is a pollutant (respiratory irritant in humans and acts to damage crops, vegetation, and many materials). It affects the Earths energy balance by absorbing both incoming solar radiation and outgoing long wave radiation. An important part of the oxidizing capacity of the atmosphere involves ozone, through a photolysis pathway that leads to the hydroxyl radical (OH). Since reaction with OH is a major sink of many atmospheric species, its concentration controls the distributions of many radiatively important species. Ozone in the troposphere arises from both in-situ photochemical production and transport from the stratosphere. Within the troposphere, ozone is formed in-situ when carbon monoxide (CO), methane (CH4), and non-methane hydrocarbons (NMHCs) react in the presence of nitrogen oxides (NO, = NO + NO2) and sunlight. The photochemistry of the stratosphere differs significantly from that in the troposphere. Within the stratosphere, ozone formation is initiated by the photolysis of 02. Stratospheric ozone may be destroyed via catalytic reactions with NO, H (hydrogen), OH, CI (chlorine) and Br (bromine), or photolysis. In the past, attempts to simulate the observed distributions of ozone (and other important gases) have focused on either the stratosphere or the troposphere. Stratospheric models either employed simplified parameterizations to represent tropospheric chemical and physical processes, or assumed the troposphere behaved as a boundary condition. Likewise, tropospheric models used simplified stratospheric chemistry and transport.

Atherton, C; Bergmann, D; Cameron-Smith, P; Connell, P; Molenkamp, C; Rotman, D; Tannahil, J

2002-10-08T23:59:59.000Z

242

Gas turbine combustion modeling for a Parametric Emissions Monitoring System.  

E-Print Network (OSTI)

??Oxides of nitrogen (NOx), carbon monoxide (CO) and other combustion by-products of gas turbines have long been identified as harmful atmospheric pollutants to the environment… (more)

Honegger, Ueli

2007-01-01T23:59:59.000Z

243

Hard carbon nitride and method for preparing same  

DOE Patents (OSTI)

Novel crystalline .alpha. (silicon nitride-like)-carbon nitride and .beta. (silicon nitride-like)-carbon nitride are formed by sputtering carbon in the presence of a nitrogen atmosphere onto a single crystal germanium or silicon, respectively, substrate.

Haller, Eugene E. (Berkeley, CA); Cohen, Marvin L. (Berkeley, CA); Hansen, William L. (Walnut Creek, CA)

1992-01-01T23:59:59.000Z

244

NETL: News Release - DOE Reports on State of the Science of Carbon...  

NLE Websites -- All DOE Office Websites (Extended Search)

atmosphere. Carbon dioxide is one of the primary gases that contribute to the "greenhouse effect" - the phenomena where certain trace gases in the atmosphere trap earth's...

245

A nanochemomechanical investigation of carbonated cement paste  

E-Print Network (OSTI)

Concrete, and in particular its principal component, cement paste, has an interesting relation with carbon dioxide. Concrete is a carbon dioxide generator-- it is estimated that 5-10% of atmospheric CO? comes from this ...

Vanzo, James (James F.)

2009-01-01T23:59:59.000Z

246

METHANE IN THE ATMOSPHERE OF THE TRANSITING HOT NEPTUNE GJ436B?  

SciTech Connect

We present an analysis of seven primary transit observations of the hot Neptune GJ436b at 3.6, 4.5, and 8 {mu}m obtained with the Infrared Array Camera on the Spitzer Space Telescope. After correcting for systematic effects, we fitted the light curves using the Markov Chain Monte Carlo technique. Combining these new data with the EPOXI, Hubble Space Telescope, and ground-based V, I, H, and K{sub s} published observations, the range 0.5-10 {mu}m can be covered. Due to the low level of activity of GJ436, the effect of starspots on the combination of transits at different epochs is negligible at the accuracy of the data set. Representative climate models were calculated by using a three-dimensional, pseudospectral general circulation model with idealized thermal forcing. Simulated transit spectra of GJ436b were generated using line-by-line radiative transfer models including the opacities of the molecular species expected to be present in such a planetary atmosphere. A new, ab-initio-calculated, line list for hot ammonia has been used for the first time. The photometric data observed at multiple wavelengths can be interpreted with methane being the dominant absorption after molecular hydrogen, possibly with minor contributions from ammonia, water, and other molecules. No clear evidence of carbon monoxide and carbon dioxide is found from transit photometry. We discuss this result in the light of a recent paper where photochemical disequilibrium is hypothesized to interpret secondary transit photometric data. We show that the emission photometric data are not incompatible with the presence of abundant methane, but further spectroscopic data are desirable to confirm this scenario.

Beaulieu, J.-P.; Batista, V. [Institut d'Astrophysique de Paris, UMR7095, CNRS, Universite Paris VI, 98bis Boulevard Arago, 75014 Paris (France); Tinetti, G.; Kipping, D. M.; Barber, R. J.; Tennyson, J.; Waldmann, I.; Miller, S.; Fossey, S. J.; Aylward, A. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Ribas, I. [Institut de Ciencies de l'Espai (CSIC-IEEC), Campus UAB, 08193 Bellaterra (Spain); Cho, J. Y.-K.; Polichtchouk, I. [Astronomy Unit, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom); Yurchenko, S. N. [Institut fur Physikalische Chemie und Elektrochemie, Technische Universitat Dresden, D-01062 Dresden (Germany); Griffith, C. A. [Lunar and Planetary Laboratory, University of Arizona, Tucson, AZ (United States); Carey, S. [IPAC-Spitzer Science Center, California Institute of Technology, Pasadena, CA 91125 (United States); Mousis, O., E-mail: beaulieu@iap.fr [Universite de Franche-Comte, Institut UTINAM, CNRS/INSU, UMR 6213, 25030 Besancon Cedex (France)

2011-04-10T23:59:59.000Z

247

Consequences of Considering Carbon/Nitrogen Interactions on the Feedbacks between Climate and the Terrestrial Carbon Cycle  

E-Print Network (OSTI)

A number of observational studies indicate that carbon sequestration by terrestrial ecosystems in a world with an atmosphere richer in carbon dioxide and a warmer climate depends on the interactions between the carbon and ...

Sokolov, Andrei P.

248

Carbon Jungle | Open Energy Information  

Open Energy Info (EERE)

Jungle Jungle Jump to: navigation, search Name Carbon Jungle Place El Segundo, California Zip 90246 Sector Carbon Product Carbon Jungle's mission is to decrease CO2 in the atmosphere by planting and managing tree plantations, increasing awareness of the facts behind increased CO2 in the atmosphere, and giving companies a means to participate in carbon credit trading. References Carbon Jungle[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Carbon Jungle is a company located in El Segundo, California . References ↑ "Carbon Jungle" Retrieved from "http://en.openei.org/w/index.php?title=Carbon_Jungle&oldid=343237" Categories: Clean Energy Organizations

249

Mixed uranium dicarbide and uranium dioxide microspheres and process of making same  

DOE Patents (OSTI)

Nuclear fuel microspheres are made by sintering microspheres containing uranium dioxide and uncombined carbon in a 1 mole percent carbon monoxide/99 mole percent argon atmosphere at 1550.degree. C. and then sintering the microspheres in a 3 mole percent carbon monoxide/97 mole percent argon atmosphere at the same temperature.

Stinton, David P. (Knoxville, TN)

1983-01-01T23:59:59.000Z

250

Microbially induced magnesium carbonation reactions as a strategy for carbon sequestration in ultramafic mine tailings.  

E-Print Network (OSTI)

??The atmospheric carbon dioxide (CO2) concentration has increased due to anthropogenic fossil fuel combustion, causing higher global temperatures and other negative environmental effects. CO2 sequestration… (more)

McCutcheon, Jenine

2013-01-01T23:59:59.000Z

251

A LAND-USE-BASED COUNTY-LEVEL CARBON BUDGET FOR CHITTENDEN COUNTY, VERMONT.  

E-Print Network (OSTI)

??As interest grows in mitigating atmospheric carbon dioxide (CO2) concentrations, there is an increasing need to understand the factors that determine fluxes of carbon (C)… (more)

Quigley, Erin

252

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network (OSTI)

requirements are a low heat capacity sample and a smallwith hundreds of times the heat capacity of the nickel filmsOnly very thin,low heat capacity samples can be used. A tiny

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

253

Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering  

SciTech Connect

Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov [AO Mittal Steel Temirtau, Temirtau (Kazakhstan)

2007-07-01T23:59:59.000Z

254

Detection of carbon monoxide (CO) as a furnace byproduct using a rotating mask spectrometer.  

Science Conference Proceedings (OSTI)

Sandia National Laboratories, in partnership with the Consumer Product Safety Commission (CPSC), has developed an optical-based sensor for the detection of CO in appliances such as residential furnaces. The device is correlation radiometer based on detection of the difference signal between the transmission spectrum of the sample multiplied by two alternating synthetic spectra (called Eigen spectra). These Eigen spectra are derived from a priori knowledge of the interferents present in the exhaust stream. They may be determined empirically for simple spectra, or using a singular value decomposition algorithm for more complex spectra. Data is presented on the details of the design of the instrument and Eigen spectra along with results from detection of CO in background N{sub 2}, and CO in N{sub 2} with large quantities of interferent CO{sub 2}. Results indicate that using the Eigen spectra technique, CO can be measured at levels well below acceptable limits in the presence of strongly interfering species. In addition, a conceptual design is presented for reducing the complexity and cost of the instrument to a level compatible with consumer products.

Sinclair, Michael B.; Flemming, Jeb Hunter; Blair, Raymond (Honeywell Federal Manufacturing & Technologies, Albuqueruque, NM); Pfeifer, Kent Bryant

2006-02-01T23:59:59.000Z

255

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

DOE Green Energy (OSTI)

Uses for structured catalytic supports, such as ceramic straight-channel monoliths and ceramic foams, have been established for a long time. One of the most prominent examples is the washcoated ceramic monolith as a three-way catalytic converter for gasoline-powered automobiles. A distinct alternative to the ceramic monolith is the metal foam, with potential use in fuel cell-powered automobiles. The metal foams are characterized by their pores per inch (ppi) and density ({rho}). In previous research, using 5 wt% platinum (Pt) and 0.5 wt% iron (Fe) catalysts, washcoated metal foams, 5.08 cm in length and 2.54 cm in diameter, of both varying and similar ppi and {rho} were tested for their activity (X{sub CO}) and selectivity (S{sub CO}) on a CO preferential oxidation (PROX) reaction in the presence of a H{sub 2}-rich gas stream. The variances in these metal foams' activity and selectivity were much larger than expected. Other structured supports with 5 wt% Pt, 0-1 wt% Fe weight loading were also examined. A theory for this phenomenon states that even though these structured supports have a similar nominal catalyst weight loading, only a certain percentage of the Pt/Fe catalyst is exposed on the surface as an active site for CO adsorption. We will use two techniques, pulse chemisorption and temperature programmed desorption (TPD), to characterize our structured supports. Active metal count, metal dispersion, and other calculations will help clarify the causes for the activity and selectivity variations between the supports. Results on ceramic monoliths show that a higher Fe loading yields a lower dispersion, potentially because of Fe inhibition of the Pt surface for CO adsorption. This theory is used to explain the reason for activity and selectivity differences for varying ppi and {rho} metal foams; less active and selective metal foams have a lower Fe loading, which justifies their higher metal dispersion. Data on the CO desorption temperature and average metal crystallite size for TPD are also collected.

Paul Chin; George W. Roberts; James J. Spivey

2003-12-31T23:59:59.000Z

256

Validation Study of the MOPITT Retrieval Algorithm: Carbon Monoxide Retrieval from IMG Observations during WINCE  

Science Conference Proceedings (OSTI)

The Measurement of Pollution in the Troposphere (MOPITT) instrument is an eight-channel gas correlation radiometer selected for the Earth Observing System (EOS) Terra spacecraft launched in December 1999. Algorithms for the retrieval of ...

Jinxue Wang; John C. Gille; Henry E. Revercomb; Von P. Walden

2000-10-01T23:59:59.000Z

257

Synthesis of higher alcohols from carbon monoxide and hydrogen in a slurry reactor  

DOE Green Energy (OSTI)

Higher, i.e. C{sub 2{sup +}}, alcohols are desired as gasoline additives, feedstocks for producing ethers and as alternative fuels for automobiles. In all cases, the backbone branching of an alcohol improves octane rating, which is essential for good engine performance. These types of branched, higher alcohols are the desired products for a process converting synthesis gas, a CO and H{sub 2} mixture, often generated from coal gasification. Based on this premise, promoted ZnCr oxide catalysts appear to be as one of the best avenues for further investigation. Once this investigation is complete, a natural extension is to replace the Cr in the ZnCr oxide catalyst with Mo and W, both in the same elemental triad with Cr. Mo has already been shown as an active HAS catalyst, both on a SiO{sub 2} support and in the MoS{sub 2} form. The three catalyst combinations, ZnMo, ZnW, and MnCr oxides will be tested in the stirred autoclave system. However, if none of the three indicate any comparable activity and/or selectivity toward higher alcohols as compared with other HAS catalysts, then an investigation of the effects of Cs promotion on the ZnCr oxide methanol catalysts will be executed.

McCutchen, M.S.

1992-08-28T23:59:59.000Z

258

Nitric oxide and carbon monoxide in cigarette smoke in the development of cardiorespiratory disease in smokers  

E-Print Network (OSTI)

in General and Geriatric Medicine, West Suffolk Hospital . 1985 - 1986 . 3) Consultant Physician in General and Geriatric Medicine, Huntingdon District Health Au~hority. 1986. Acknowledgements I am most grateful to the East Anglian Regional Health... was starting in Virginia. Growing was also started at that time in other parts of the world where the climate was suitable e.g. Turkey (Akehurst 1981). During the 18th century snuff became the most popular way of taking tobacco but the habit rapidly...

Borland, Colin David Ross

1988-10-18T23:59:59.000Z

259

Hazardous Off-Gassing of Carbon Monoxide and Oxygen Depletion during Ocean Transportation of  

E-Print Network (OSTI)

which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited. doi:10.1093/annhyg/men013

Wood Pellets; Urban Svedberg; Jerker Samuelsson; Staffan Melin

2008-01-01T23:59:59.000Z

260

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

DOE Green Energy (OSTI)

Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

2005-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Continuous Measurement of Carbon Monoxide Improves Combustion Efficiency of CO Boilers  

E-Print Network (OSTI)

The paper describes the application of in-situ flue gas CO measurement in the operation of CO Boilers and details the steps needed to optimize combustion efficiency.

Gilmour, W. A.; Pregler, D. N.; Branham, R. L.; Prichard, J. J.

1981-01-01T23:59:59.000Z

262

Technology development for iron Fischer-Tropsch catalysis. [Pretreatment of catalyst in carbon monoxide  

DOE Green Energy (OSTI)

The present study shows that activation of a high surface area Fe{sub 2}O{sub 3} catalyst in CO in a (CSTR), continuously stirred tank reactor using tetralin as solvent results in an activated that is three times of material that is activated in H{sub 2} or directly in the syngas.

Not Available

1991-01-01T23:59:59.000Z

263

Atmospheric Delta 14C Record from Wellington  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Isotopes » Carbon Isotopes » δ14C from Wellington Atmospheric δ14C Record from Wellington graphics Graphics data Data Investigators M.R. Manning, W.H. Melhuish National Institute of Water and Atmospheric Research, Ltd., Climate Division, Gracefield Road, Gracefield, P.O. Box 31-311, Lower Hutt, New Zealand Period of Record 1954-93 Methods Trays containing ~2 L of 5 normal NaOH carbonate-free solution are typically exposed for intervals of 1-2 weeks, and the atmospheric CO2 absorbed during that time is recovered by acid evolution. Considerable fractionation occurs during absorption into the NaOH solution, and the standard fractionation correction (Stuiver and Polach 1977) is used to determine a δ 14C value corrected to δ 13C = -25 per mil. Some samples reported here were taken using BaOH solution or with extended

264

Interactions between Vegetation and Climate: Radiative and Physiological Effects of Doubled Atmospheric CO2  

Science Conference Proceedings (OSTI)

The radiative and physiological effects of doubled atmospheric carbon dioxide (CO2) on climate are investigated using a coupled biosphere–atmosphere model. Five 30-yr climate simulations, designed to assess the radiative and physiological effects ...

L. Bounoua; G. J. Collatz; P. J. Sellers; D. A. Randall; D. A. Dazlich; S. O. Los; J. A. Berry; I. Fung; C. J. Tucker; C. B. Field; T. G. Jensen

1999-02-01T23:59:59.000Z

265

THE EFFECTS OF ENERGY-EFFICIENT VENTILATION RATES ON INDOOR AIR QUALITY AT AN OHIO ELEMENTARY SCHOOL  

E-Print Network (OSTI)

inorganic pollutants: carbon dioxides carbon monoxides ozonetotal aldehydes, carbon dioxide, carbon monoxide, sulfurquality standards. Carbon dioxide concentrations increased

Berk, J.V.

2013-01-01T23:59:59.000Z

266

Carbon Dioxide Hydrate Process for Gas Separation from a Shifted Synthesis Gas Stream  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration and Sequestration and Gasification Technologies Carbon DioxiDe HyDrate ProCess for Gas seParation from a sHifteD syntHesis Gas stream Background One approach to de-carbonizing coal is to gasify it to form fuel gas consisting predominately of carbon monoxide and hydrogen. This fuel gas is sent to a shift conversion reactor where carbon monoxide reacts with steam to produce carbon dioxide (CO 2 ) and hydrogen. After scrubbing the CO 2 from the fuel, a stream of almost pure hydrogen stream remains, which can be burned in a gas turbine or used to power a fuel cell with essentially zero emissions. However, for this approach to be practical, it will require an economical means of separating CO 2 from mixed gas streams. Since viable options for sequestration or reuse of CO

267

Earth's early atmosphere  

SciTech Connect

Ideas about atmospheric composition and climate on the early Earth have evolved considerably over the last 30 years, but many uncertainties still remain. It is generally agreed that the atmosphere contained little or no free oxygen initially and that oxygen concentrations increased markely near 2.0 billion years ago, but the precise timing of and reasons for its rise remain unexplained. Likewise, it is usually conceded that the atmospheric greenhouse effect must have been higher in the past to offset reduced solar luminosity, but the levels of atmospheric carbon cioxide and other greenhouse gases required remain speculative. A better understanding of past atmospheric evolution is important to understanding the evolution of life and to predicting whether Earth-like planets might exist elsewhere in the galaxy.

Kasting, J.F. (Pennsylvania State Univ., University Park (United States))

1993-02-12T23:59:59.000Z

268

PAGES 85–96 Estimating Carbon Budgets  

E-Print Network (OSTI)

On a global basis, plants and soils may hold more than twice the amount of carbon present in the atmosphere [ Geider et al., 2001]. Under increasing atmospheric carbon dioxide (CO 2) concentrations and subsequently warming temperatures, these large biogenic pools may change in size [ Cox et al., 2000]. Due to a lack of long-term field studies, there is uncertainty as to whether vegetation and soils will act as a net sink or a source of atmospheric

For U. S. Ecosystems; B Y C. P Otter; S. Klooster; R. Nemani; V. G Enovese; S. Hiatt; M. Fladeland; P. G Ross

2006-01-01T23:59:59.000Z

269

Emissions of CO/sub 2/ to the atmosphere due to U. S. A. fossil fuel consumption  

SciTech Connect

Analysis and projection of carbon dioxide emitted to the atmosphere are estimated based on the Brookhaven reference energy system. Some new results are given on carbon dioxide contribution to the atmosphere from US fossil fuel consumption by different sectors including residential, commercial, industrial and transportation. The total weight of carbon as carbon dioxide emitted to the atmosphere and the additional CO/sub 2/ concentration over background by different subsectors in the years 1977, 1980, 1985, 1990, 2000 and 2020 are presented.

Dang, V.D.; Steinberg, M.

1980-06-01T23:59:59.000Z

270

Atmospheric carbon dioxide and the climate record  

SciTech Connect

This paper is an attempt to provide a summary review of conclusions from previous studies on this subject. Subject headings include: conceptualization of the greenhouse effect, the climatic effect of doubled CO/sub 2/, interpretation of the climatic record, diagnosis of apparent and possible model deficiencies, and the palaeoclimatic record.

Ellsaesser, H.W.

1989-04-01T23:59:59.000Z

271

Environmental control technology for atmospheric carbon dioxide  

Science Conference Proceedings (OSTI)

The impact of fossil fuel use in the United States on worldwide CO/sub 2/ emissions and the impact of increased coal utilization on CO/sub 2/ emission rates are assessed. The aspects of CO/sub 2/ control are discussed as well as the available CO/sub 2/ control points (CO/sub 2/ removal sites). Two control scenarios are evaluated, one based on the absorption of CO/sub 2/ contained in power plant flue gas by seawater; the other, based on absorption of CO/sub 2/ by MEA (Mono Ethanol Amine). Captured CO/sub 2/ is injected into the deep ocean in both cases. The analyses indicate that capture and disposal by seawater is energetically not feasible, whereas capture and disposal using MEA is a possibility. However, the economic penalities of CO/sub 2/ control are significant. The use of non-fossil energy sources, such as hydroelectric, nuclear or solar energy is considered as an alternative for limiting and controlling CO/sub 2/ emissions resulting from fossil energy usage.

Steinberg, M.; Albanese, A.S.

1980-01-01T23:59:59.000Z

272

NETL: Carbon Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Storage Technologies Carbon Storage (formerly referred to as the "Carbon Sequestration Program") Program Overview For quick navigation of NETL's Carbon Storage Program website, please click on the image. NETL's Carbon Storage Program Fossil fuels are considered the most dependable, cost-effective energy source in the world. The availability of these fuels to provide clean, affordable energy is essential for domestic and global prosperity and security well into the 21st century. However, a balance is needed between energy security and concerns over the impacts of concentrations of greenhouse gases (GHGs) in the atmosphere - particularly carbon dioxide (CO2). NETL's Carbon Storage Program is developing a technology portfolio of safe, cost-effective, commercial-scale CO2 capture, storage, and mitigation

273

Analysis of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions and photochemistry  

E-Print Network (OSTI)

, the inventories use year-2000 energy forecasts (off a 1995 base) from the RAINS-Asia (regional air pollution running under optimal conditions; in- use engines operating in developing countries may eject more OC; published 4 September 2002. [1] Air from South Asia carries heavy loadings of organic and light

Dickerson, Russell R.

274

Carbon-14 Bomb-Pulse Dating  

Science Conference Proceedings (OSTI)

Atmospheric testing of nuclear weapons during the 1950s and early 1960s doubled the concentration of carbon-14 atmosphere and created a pulse that labeled everything alive in the past 50 years as carbon moved up the food chain. The variation in carbon-14 concentration in time is well-documented and can be used to chronologically date all biological materials since the mid-1950s.

Buchholz, B A

2007-12-16T23:59:59.000Z

275

A Cable-Borne Tram for Atmospheric Measurements along Transects  

Science Conference Proceedings (OSTI)

A system to make atmospheric measurements from a moving trolley suspended by a stretched cable has been developed. At present, these measurements consist of wind velocity, temperature, humidity, and carbon dioxide concentration, though other ...

S. P. Oncley; K. Schwenz; S. P. Burns; J. Sun; R. K. Monson

2009-03-01T23:59:59.000Z

276

Agricultural Carbon Mitigation in Europe  

NLE Websites -- All DOE Office Websites (Extended Search)

Agricultural Carbon Mitigation in Europe Agricultural Carbon Mitigation in Europe Agricultural Carbon Mitigation in Europe Smith P, Powlson DS, Smith JU, Falloon P, and Coleman K. 2000. Meeting Europe's climate change commitments: Quantitative estimates of the potential for carbon mitigation by agriculture. Global Climate Change 6:525-539. Abstract Under the Kyoto Protocol, the European Union is committed to a reduction in CO2 emissions to 92% of baseline (1990) levels during the first commitment period (2008-2012). The Kyoto Protocol allows carbon emissions to be offset by demonstrable removal of carbon from the atmosphere. Thus, land-use / land-management change and forestry activities that are shown to reduce atmospheric CO2 levels can be included in the Kyoto targets. These activities include afforestation, reforestation and deforestation (article

277

Ranges of Atmospheric Mass and Composition of Super Earth Exoplanets  

E-Print Network (OSTI)

Terrestrial-like exoplanets may obtain atmospheres from three primary sources: Capture of nebular gases, degassing during accretion, and degassing from subsequent tectonic activity. Here we model degassing during accretion to estimate the range of atmospheric mass and composition on exoplanets ranging from 1 to 30 Earth masses. We use bulk compositions drawn from primitive and differentiated meteorite compositions. Degassing alone can create a wide range of masses of planetary atmospheres, ranging from less than a percent of the planet's total mass up to ~6 mass% of hydrogen, ~20 mass% of water, and/or ~5 mass% of carbon compounds. Hydrogen-rich atmospheres can be outgassed as a result of oxidizing metallic iron with water, and excess water and carbon can produce atmospheres through simple degassing. As a byproduct of our atmospheric outgassing models we find that modest initial water contents (10 mass% of the planet and above) create planets with deep surface liquid water oceans soon after accretion is complete.

L. Elkins-Tanton; S. Seager

2008-08-13T23:59:59.000Z

278

Carbon dynamics following landscape fire: influence of burn severity, climate, and stand history in the Metolius Watershed, Oregon.  

E-Print Network (OSTI)

??Fire is a fundamental disturbance that drives terrestrial and atmospheric carbon dynamics. Previous studies have quantified fire effects on carbon cycling from local to global… (more)

[No author

2009-01-01T23:59:59.000Z

279

8, 98839929, 2008 Black carbon at  

E-Print Network (OSTI)

ACPD 8, 9883­9929, 2008 Black carbon at Syowa station, Antarctica K. Hara et al. Title Page.0 License. Atmospheric Chemistry and Physics Discussions Measurement of black carbon at Syowa station on behalf of the European Geosciences Union. 9883 #12;ACPD 8, 9883­9929, 2008 Black carbon at Syowa station

Paris-Sud XI, Université de

280

Carbon Dioxide Carbonates in the Earth;s Mantle: Implications to the Deep Carbon Cycle  

SciTech Connect

An increase in the ionic character in C-O bonds at high pressures and temperatures is shown by the chemical/phase transformation diagram of CO{sub 2}. The presence of carbonate carbon dioxide (i-CO{sub 2}) near the Earth's core-mantle boundary condition provides insights into both the deep carbon cycle and the transport of atmospheric CO{sub 2} to anhydrous silicates in the mantle and iron core.

Yoo, Choong-Shik; Sengupta, Amartya; Kim, Minseob (Princeton); (WSU)

2012-05-22T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Evaluation of Carbon Dioxide Capture/Utilization/Disposal Options  

NLE Websites -- All DOE Office Websites (Extended Search)

for the existing fleet of coal-fired power plants in the event of carbon constraints. Concerns over possible global climate changes due to increasing atmospheric con- centrations...

282

Carbon Dioxide, Hydrographic, and Chemical Data Obtained During...  

NLE Websites -- All DOE Office Websites (Extended Search)

Marine Environmental Laboratory National Oceanic and Atmospheric Administration Seattle, Washington, U.S.A. Prepared by Alexander Kozyr1 Carbon Dioxide Information Analysis...

283

NETL: News Release - Worldwide Carbon Capture and Storage Projects...  

NLE Websites -- All DOE Office Websites (Extended Search)

of slagging gasifiers, where a carbon-based feedstock (such as coal, petroleum, coke, andor biomass) is converted at high temperatures in an oxygen short atmosphere into...

284

Carbon Cycle Uncertainty Increases Climate Change Risks and Mitigation Challenges  

Science Conference Proceedings (OSTI)

Projections of greenhouse gas concentrations over the twenty-first century generally rely on two optimistic, but questionable, assumptions about the carbon cycle: 1) that elevated atmospheric CO2 concentrations will enhance terrestrial carbon ...

Paul A. T. Higgins; John Harte

2012-11-01T23:59:59.000Z

285

Interhemispheric Asymmetry in the Transient Response of a Coupled Ocean–Atmosphere Model to a CO2 Forcing  

Science Conference Proceedings (OSTI)

Numerical experiments are carried out using a general circulation model of a coupled ocean-atmosphere system with idealized geography, exploring the transient response of climate to a rapid increase of atmospheric carbon dioxide. The ...

K. Bryan; S. Manabe; M. J. Spelman

1988-06-01T23:59:59.000Z

286

The Boulder Atmospheric Observatory  

Science Conference Proceedings (OSTI)

The Boulder Atmospheric Observatory (BAO) is a unique research facility for studying the planetary boundary layer and for testing and calibrating atmospheric sensors. The facility includes a 300 m tower instrumented with fast- and slow-response ...

J. C. Kaimal; J. E. Gaynor

1983-05-01T23:59:59.000Z

287

Atmospheric Radiation Measurement Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Observatory (UAO) Pilot Experiment at NYC" - Michael Reynolds, BNL 17:30 "EML Pilot Studies for the Urban Atmospheric Observatory" - Hsi-Na (Sam) Lee, EML 17:40 "A...

288

Carbon sequestration research and development  

SciTech Connect

Predictions of global energy use in the next century suggest a continued increase in carbon emissions and rising concentrations of carbon dioxide (CO{sub 2}) in the atmosphere unless major changes are made in the way we produce and use energy--in particular, how we manage carbon. For example, the Intergovernmental Panel on Climate Change (IPCC) predicts in its 1995 ''business as usual'' energy scenario that future global emissions of CO{sub 2} to the atmosphere will increase from 7.4 billion tonnes of carbon (GtC) per year in 1997 to approximately 26 GtC/year by 2100. IPCC also projects a doubling of atmospheric CO{sub 2} concentration by the middle of next century and growing rates of increase beyond. Although the effects of increased CO{sub 2} levels on global climate are uncertain, many scientists agree that a doubling of atmospheric CO{sub 2} concentrations could have a variety of serious environmental consequences. The goal of this report is to identify key areas for research and development (R&D) that could lead to an understanding of the potential for future use of carbon sequestration as a major tool for managing carbon emissions. Under the leadership of DOE, researchers from universities, industry, other government agencies, and DOE national laboratories were brought together to develop the technical basis for conceiving a science and technology road map. That effort has resulted in this report, which develops much of the information needed for the road map.

Reichle, Dave; Houghton, John; Kane, Bob; Ekmann, Jim; and others

1999-12-31T23:59:59.000Z

289

Regional carbon dynamics in monsoon Asia and its implications for the global carbon cycle  

E-Print Network (OSTI)

Regional carbon dynamics in monsoon Asia and its implications for the global carbon cycle Hanqin on the exchange of CO2 between the atmosphere and monsoon Asian ecosystems. During 1860­1990, modeled results suggest that monsoon Asia as a whole released 29.0 Pg C, which represents 50% of the global carbon release

290

Carbon dioxide and climate: a bibliography  

SciTech Connect

This bibliography with abstracts presents 394 citations retrieved from the Energy Data Base of the Department of Energy Technical Information Center, Oak Ridge, Tennessee. The citations cover all aspects of the climatic effects of carbon dioxide emissions to the atmosphere. These include carbon cycling, temperature effects, carbon dioxide control technologies, paleoclimatology, carbon dioxide sources and sinks, mathematical models, energy policies, greenhouse effect, and the role of the oceans and terrestrial forests.

Ringe, A.C. (ed.)

1980-10-01T23:59:59.000Z

291

Equilibrium Response of an Atmosphere–Mixed Layer Ocean Model to Different Radiative Forcing Agents: Global and Zonal Mean Response  

Science Conference Proceedings (OSTI)

The equilibrium response to various forcing agents, including CO2, solar irradiance, tropospheric ozone, black carbon, organic carbon, sulfate, and volcanic aerosols, is investigated using an atmospheric general circulation model coupled to a ...

Masakazu Yoshimori; Anthony J. Broccoli

2008-09-01T23:59:59.000Z

292

Carbon Dioxide Information Analysis Center (CDIAC)  

NLE Websites -- All DOE Office Websites (Extended Search)

find data of interest. Ocean investigators may submit data to CDIAC here: image Fossil-Fuel CO2 Emissions Trace Gas Emissions Atmospheric Trace Gases Oceanic Trace Gases Carbon...

293

Quantification of Black Carbon and Other Pollutant Emissions from a  

NLE Websites -- All DOE Office Websites (Extended Search)

Quantification of Black Carbon and Other Pollutant Emissions from a Quantification of Black Carbon and Other Pollutant Emissions from a Traditional and an Improved Cookstove Title Quantification of Black Carbon and Other Pollutant Emissions from a Traditional and an Improved Cookstove Publication Type Report LBNL Report Number LBNL-6062E Year of Publication 2010 Authors Kirchstetter, Thomas W., Chelsea Preble, Odelle L. Hadley, and Ashok J. Gadgil Keywords aethalometer, Berkeley Darfur Stove, black carbon, carbon monoxide, climate change, DustTrak, global warming, improved cookstoves, indoor air quality, LBNL Stove Testing Facility, particulate matter, photoacoustic absorption spectrometer, pollutant emission factor, three-stone fire Abstract Traditional methods of cooking in developing regions of the world emit pollutants that

294

The Birth and Life of Our Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

Birth and Life of Our Atmosphere Birth and Life of Our Atmosphere Nature Bulletin No. 554-A February 15, 1975 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation THE BIRTH AND LIFE OF OUR ATMOSPHERE In Bulletin No. 542-A we described the atmosphere that surrounds the earth, held there by the pull of gravity, including the canopy of air immediately above us. That canopy is responsible for our weather and climates, shields us from the killing rays of the sun, and furnishes substances necessary for all life: oxygen, nitrogen, carbon dioxide, and water vapor. Astronomers believe that none of the other planets -- excepting Mars, perhaps -- has an atmosphere anything like ours. The principal elements, free nitrogen (78 percent) and free oxygen (21 percent), apparently are rare in the universe. On the other hand, the earth's atmosphere contains only traces of free hydrogen and helium -- the two lightest gases -- whereas they are by far the most common elements elsewhere in the universe.

295

Carbon Dioxide Information Analysis Center (CDIAC)  

NLE Websites -- All DOE Office Websites (Extended Search)

Latest Estimates Latest Estimates Atmos CO2 Level 397.31 ppm Fossil CO2 Emissions 9,167 MMT Carbon Global Temp Anomaly +0.56°C / +1.01°F Global Sea Level Rise +2.9 ± 0.4 mm/y Carbon Dioxide Information Analysis Center The Carbon Dioxide Information Analysis Center (CDIAC) is the primary climate-change data and information analysis center of the U.S. Department of Energy (DOE). CDIAC is located at DOE's Oak Ridge National Laboratory (ORNL) and includes the World Data Center for Atmospheric Trace Gases. CDIAC's data holdings include estimates of carbon dioxide emissions from fossil-fuel consumption and land-use changes; records of atmospheric concentrations of carbon dioxide and other radiatively active trace gases; carbon cycle and terrestrial carbon management datasets and analyses; and

296

Atmospheric Concentrations of CO2 from Mauna Loa, Hawaii  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Concentrations of CO2 from Mauna Loa, Hawaii Atmospheric Concentrations of CO2 from Mauna Loa, Hawaii The graphs on this page are generated from data taken from "Trends in Carbon Dioxide" page on the Department of Commerce/National Oceanic and Atmospheric Administration (NOAA) website. The NOAA website presents monthly and weekly atmospheric CO2 concentrations measured at the Mauna Loa Observatory in Hawaii. It offers weekly and monthly data, additional graphs, analysis, descriptions of how the data are collected, and an animation of historical changes in atmospheric CO2. Mauna Loa constitutes the longest record of direct measurements of CO2 in the atmosphere. The measurents were started by C. David Keeling of the Scripps Institution of Oceanography in March of 1958. Recent Monthly Average CO2

297

Method for making carbon films  

DOE Patents (OSTI)

A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area ([approx equal]1000 m[sup 2] /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160 C for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750 C in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750--850 C for between 1--6 hours. 2 figs.

Tan, M.X.

1999-07-29T23:59:59.000Z

298

Method for making carbon films  

DOE Patents (OSTI)

A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

Tan, Ming X. (Livermore, CA)

1999-01-01T23:59:59.000Z

299

Atmospheric Radiation Measurement Program  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 ARM 2003 Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement WARNING! WARNING! Today is April 1 But that has NO bearing on this message Today is April 1 But that has NO bearing on this message ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Two Topics Two Topics * Status of ARM (quick overview) * Science plan - ARM in the next 5 years * Status of ARM (quick overview) * Science plan - ARM in the next 5 years ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement ARM Status - Science ARM Status - Science * Steadily increasing productivity - Poster session - over 220 posters (may need to do something about submissions next year) - Peer-reviewed articles: 2.5 to 3 per year per

300

Total atmospheric emissivities for a tropical climate  

SciTech Connect

The total atmospheric flux emissivities as a function of water vapor optical depth are reported for meteorological condtions in Thailand. The water vapor optical depth was first calculated as a function of height up to 12 km from the annual average upper air pressures, temperature, and dew points at Bangkok. The flux emissivity was then computed using tabulated data for the flux emissivities of water vapor, carbon dioxide, and ozone at 20/sup 0/C. (SPH)

Exell, R.H.B.

1978-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Environmental and societal consequences of a possible CO/sub 2/-induced climate change. Volume II, Part 8. Impacts of rising atmospheric carbon dioxide levels on agricultural growing seasons and crop water use efficiencies  

Science Conference Proceedings (OSTI)

The researchable areas addressed relate to the possible impacts of climate change on agricultural growing seasons and crop adaptation responses on a global basis. The research activities proposed are divided into the following two main areas of investigation: anticipated climate change impacts on the physical environmental characteristics of the agricultural growing seasons and, the most probable food crop responses to the possible changes in atmospheric CO/sub 2/ levels in plant environments. The main physical environmental impacts considered are the changes in temperature, or more directly, thermal energy levels and the growing season evapotranspiration-precipitation balances. The resulting food crop, commercial forest and rangeland species response impacts addressed relate to potential geographical shifts in agricultural growing seasons as determined by the length in days of the frost free period, thermal energy changes and water balance changes. In addition, the interaction of possible changes in plant water use efficiencies during the growing season in relationship to changing atmospheric CO/sub 2/ concentrations, is also considered under the scenario of global warming due to increases in atmospheric CO/sub 2/ concentration. These proposed research investigations are followed by adaptive response evaluations.

Newman, J. E.

1982-09-01T23:59:59.000Z

302

Carbon Cycle Uncertainty Increases Climate Change Risks and Mitigation Challenges PAUL A. T. HIGGINS  

E-Print Network (OSTI)

Carbon Cycle Uncertainty Increases Climate Change Risks and Mitigation Challenges PAUL A. T about the carbon cycle: 1) that elevated atmospheric CO2 concentrations will enhance terrestrial carbon that carbon cycle uncertainty is considerably larger than currently recognized and that plausible carbon cycle

Kammen, Daniel M.

303

Topic T4 Claudia Hildenbrand #274 EDLC electrodes from cellulose-based carbon aerogels: influence of  

E-Print Network (OSTI)

Topic T4 Claudia Hildenbrand #274 EDLC electrodes from cellulose-based carbon aerogels: influence performance if used as EDLC electrode material. Carbon aerogels were synthesized by crosslinking cellulose atmosphere (1000°C, nitrogen atmosphere). Subsequently, the surface chemistry of the carbon aerogels

Paris-Sud XI, Université de

304

Old-field Community, Climate and Atmospheric Manipulation  

SciTech Connect

We are in the process of finishing a number of laboratory, growth chamber and greenhouse projects, analyzing data, and writing papers. The projects reported addressed these subjects: How do climate and atmospheric changes alter aboveground plant biomass and community structure; Effects of multiple climate changes factors on plant community composition and diversity: what did we learn from a 5-year open-top chamber experiment using constructed old-field communities; Do atmospheric and climatic change factors interact to alter woody seedling emergence, establishment and productivity; Soil moisture surpasses elevated CO{sub 2} and temperature in importance as a control on soil carbon dynamics; How do climate and atmospheric changes alter belowground root and fungal biomass; How do climate and atmospheric changes alter soil microarthropod and microbial communities; How do climate and atmospheric changes alter belowground microbial function; Linking root litter diversity and microbial functioning at a micro scale under current and projected CO{sub 2} concentrations; Multifactor climate change effects on soil ecosystem functioning depend on concurrent changes in plant community composition; How do climate and atmospheric changes alter aboveground insect populations; How do climate and atmospheric changes alter festuca endophyte infection; How do climate and atmospheric changes soil carbon stabilization.

Aimee Classen

2009-11-01T23:59:59.000Z

305

Carbon fiber manufacturing via plasma technology  

DOE Patents (OSTI)

The disclosed invention introduces a novel method of manufacturing carbon and/or graphite fibers that avoids the high costs associated with conventional carbonization processes. The method of the present invention avoids these costs by utilizing plasma technology in connection with electromagnetic radiation to produce carbon and/or graphite fibers from fully or partially stabilized carbon fiber precursors. In general, the stabilized or partially stabilized carbon fiber precursors are placed under slight tension, in an oxygen-free atmosphere, and carbonized using a plasma and electromagnetic radiation having a power input which is increased as the fibers become more carbonized and progress towards a final carbon or graphite product. In an additional step, the final carbon or graphite product may be surface treated with an oxygen-plasma treatment to enhance adhesion to matrix materials.

Paulauskas, Felix L. (Knoxville, TN); Yarborough, Kenneth D. (Oak Ridge, TN); Meek, Thomas T. (Knoxville, TN)

2002-01-01T23:59:59.000Z

306

The Carbon Cycle Response to ENSO: A Coupled Climate–Carbon Cycle Model Study  

Science Conference Proceedings (OSTI)

There is significant interannual variability in the atmospheric concentration of carbon dioxide (CO2) even when the effect of anthropogenic sources has been accounted for. This variability is well correlated with the El Nińo–Southern Oscillation (...

Chris D. Jones; Matthew Collins; Peter M. Cox; Steven A. Spall

2001-11-01T23:59:59.000Z

307

Process for removing carbon from uranium  

DOE Patents (OSTI)

Carbon contamination is removed from uranium and uranium alloys by heating in inert atmosphere to 700.degree.-1900.degree.C in effective contact with yttrium to cause carbon in the uranium to react with the yttrium. The yttrium is either in direct contact with the contaminated uranium or in indirect contact by means of an intermediate transport medium.

Powell, George L. (Oak Ridge, TN); Holcombe, Jr., Cressie E. (Knoxville, TN)

1976-01-01T23:59:59.000Z

308

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite  

E-Print Network (OSTI)

strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine-C composite containing continuous PAN T300 fibers · SWB: Chopped Fiber Composite containing SWB fibers Crush

Rollins, Andrew M.

309

Estimating the Seasonal Carbon Source-Sink Geography of a Natural, Steady-State Terrestrial Biosphere  

Science Conference Proceedings (OSTI)

The seasonal dynamics of biospheric-carbon sources and sinks represents a needed input to global atmospheric CO2 studies and models. For the terrestrial biosphere, initial monthly estimates of overall metabolism and net biosphere-atmosphere ...

Elgene O. Box

1988-10-01T23:59:59.000Z

310

BNL | Carbon Cycle Science  

NLE Websites -- All DOE Office Websites (Extended Search)

The Carbon Cycle Science & Technology Group aims to increase understanding The Carbon Cycle Science & Technology Group aims to increase understanding of the impacts of global change on managed and unmanaged ecosystems and improve knowledge of possible global change mitigation approaches. The group has three main focus areas. FACE Climate Change Experimental Facility Design and Management The CCS&T group is an internationally recognized leader in the development of Free Air CO2 Enrichment (FACE) research facilities. We are interested in the design and management of manipulative experiments that examine the effects of carbon dioxide, ozone, other atmospheric pollutants, temperature and precipitation on natural and managed ecosystems. FACE Plant Physiology and High Throughput Biochemical Phenotyping At FACE facilities we have studied the mechanisms that underlie the

311

Pre-Combustion Carbon Capture Research | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-combustion capture refers to removing CO2 from fossil fuels before combustion is completed. For example, in gasification processes a feedstock (such as coal) is partially oxidized in steam and oxygen/air under high temperature and pressure to form synthesis gas. This synthesis gas, or syngas, is a mixture of hydrogen, carbon monoxide, CO2, and smaller amounts of other gaseous components, such as methane. The syngas can then undergo the water-gas shift reaction to convert CO and water (H2O) to H2 and CO2, producing a H2 and CO2-rich gas mixture. The concentration of CO2 in this mixture can range from 15-50%. The CO2 can then be captured and separated, transported, and ultimately sequestered, and the H2-rich fuel combusted.

312

Mathematical Analysis of High-Temperature Co-electrolysis of CO2 and O2 Production in a Closed-Loop Atmosphere Revitalization System  

DOE Green Energy (OSTI)

NASA has been evaluating two closed-loop atmosphere revitalization architectures based on Sabatier and Bosch carbon dioxide, CO2, reduction technologies. The CO2 and steam, H2O, co-electrolysis process is another option that NASA has investigated. Utilizing recent advances in the fuel cell technology sector, the Idaho National Laboratory, INL, has developed a CO2 and H2O co-electrolysis process to produce oxygen and syngas (carbon monoxide, CO and hydrogen, H2 mixture) for terrestrial (energy production) application. The technology is a combined process that involves steam electrolysis, CO2 electrolysis, and the reverse water gas shift (RWGS) reaction. A number of process models have been developed and analyzed to determine the theoretical power required to recover oxygen, O2, in each case. These models include the current Sabatier and Bosch technologies and combinations of those processes with high-temperature co-electrolysis. The cases of constant CO2 supply and constant O2 production were evaluated. In addition, a process model of the hydrogenation process with co-electrolysis was developed and compared. Sabatier processes require the least amount of energy input per kg of oxygen produced. If co-electrolysis replaces solid polymer electrolyte (SPE) electrolysis within the Sabatier architecture, the power requirement is reduced by over 10%, but only if heat recuperation is used. Sabatier processes, however, require external water to achieve the lower power results. Under conditions of constant incoming carbon dioxide flow, the Sabatier architectures require more power than the other architectures. The Bosch, Boudouard with co-electrolysis, and the hydrogenation with co-electrolysis processes require little or no external water. The Bosch and hydrogenation processes produce water within their reactors, which aids in reducing the power requirement for electrolysis. The Boudouard with co-electrolysis process has a higher electrolysis power requirement because carbon dioxide is split instead of water, which has a lower heat of formation. Hydrogenation with co-electrolysis offers the best overall power performance for two reasons: it requires no external water, and it produces its own water, which reduces the power requirement for co-electrolysis.

Michael G. McKellar; Manohar S. Sohal; Lila Mulloth; Bernadette Luna; Morgan B. Abney

2010-03-01T23:59:59.000Z

313

Method for making carbon super capacitor electrode materials  

DOE Patents (OSTI)

A method for making near-net-shape, monolithic carbon electrodes for energy storage devices. The method includes the controlled pyrolysis and activation of a pressed shape of methyl cellulose powder with pyrolysis being carried out in two stages; pre-oxidation, preferably in air at a temperature between 200.degree.-250.degree. C., followed by carbonization under an inert atmosphere. An activation step to adjust the surface area of the carbon shape to a value desirable for the application being considered, including heating the carbon shape in an oxidizing atmosphere to a temperature of at least 300.degree. C., follows carbonization.

Firsich, David W. (Dayton, OH); Ingersoll, David (Albuquerque, NM); Delnick, Frank M. (Dexter, MI)

1998-01-01T23:59:59.000Z

314

Method for making carbon super capacitor electrode materials  

DOE Patents (OSTI)

A method is described for making near-net-shape, monolithic carbon electrodes for energy storage devices. The method includes the controlled pyrolysis and activation of a pressed shape of methyl cellulose powder with pyrolysis being carried out in two stages; pre-oxidation, preferably in air at a temperature between 200--250 C, followed by carbonization under an inert atmosphere. An activation step to adjust the surface area of the carbon shape to a value desirable for the application being considered, including heating the carbon shape in an oxidizing atmosphere to a temperature of at least 300 C, follows carbonization. 1 fig.

Firsich, D.W.; Ingersoll, D.; Delnick, F.M.

1998-07-07T23:59:59.000Z

315

Soil organic carbon – A Western Australian perspective Soil organic carbon A Western Australian perspective  

E-Print Network (OSTI)

Sequestering carbon in soils is being investigated worldwide as a way to remove carbon dioxide from the atmosphere and provide land managers with extra income from the sale of carbon offsets or credits. In theory, the opportunity exists for farmers and other land managers to be paid via voluntary trades or carbon trading schemes to implement land management changes that sequester soil carbon, with additional benefits gained in improving the biological, chemical and physical health of their soils. The concept of increasing soil organic carbon is very attractive because it seemingly provides a ‘win-win’ situation in which farmers earn extra income for removing greenhouse gas emissions from the atmosphere while simultaneously lifting the productivity of arable soils. But how realistic is this concept and what opportunities and risks does it present to farmers? Soil organic carbon is part of the global carbon cycle The soil can either represent an enormous ‘source’ or ‘sink ’ of carbon – with more carbon contained in the soil than in the world’s vegetation and atmosphere combined. Soil organic carbon represents a critical component

Janet Paterson; Dr. Fran Hoyle; Department Of Agriculture

2011-01-01T23:59:59.000Z

316

Economic Impacts of Carbon Taxes: Detailed Results  

Science Conference Proceedings (OSTI)

Due to the possibility that rising concentrations of atmospheric greenhouse gases might cause undesirable climate change, policies to restrict emissions of carbon dioxide, a greenhouse gas, have been proposed. Such proposals frequently take the form of carbon taxes. This report presents the detailed results of an examination of the economic costs of carbon taxes, including where and how the U.S. economy would be impacted.

1995-01-04T23:59:59.000Z

317

Economic Impacts of Carbon Taxes: Overview  

Science Conference Proceedings (OSTI)

Due to the possibility that rising concentrations of atmospheric greenhouse gases might cause undesirable climate change, policies to restrict emissions of carbon dioxide, a greenhouse gas, have been proposed. Such proposals frequently take the form of carbon taxes. This report presents an overview of the results of a detailed examination of the economic costs of carbon taxes, including where and how the U.S. economy would be impacted.

1995-01-04T23:59:59.000Z

318

Carbon Emitted, Carbon Saved  

E-Print Network (OSTI)

The concentration of greenhouse gases in the atmosphere continues to grow, and there is increasing interest in trying to minimize emissions. Countries and corporations are conducting inventories of their emissions and investigating how changes in some practices might lead to reduced emissions. If ratified, the Kyoto Protocol would permit countries to trade emissions permits. In conducting the inventories and related analyses, analysts and policymakers need to clearly understand system boundaries and their significance.

Gregg Marl; Tristram O. West; John C. Fenderson; Karen Gibson

2001-01-01T23:59:59.000Z

319

BIOMINERALIZATION FOR CARBON SEQUESTRATION T. J. Phelps and Y. Roh  

E-Print Network (OSTI)

of the controlling factors, rate and extent of carbonate mineral precipitation will significantly advance our while carbon dioxide is liberated to the atmosphere. While previous strategies dealt the sulfur in the coal) and/or reject kiln dust. Carbon dioxide from the plant could be bubbled through

320

Synthesis and reactivity of pyridinediimine iron complexes : for the breakdown of carbon dioxide.  

E-Print Network (OSTI)

??The increase of greenhouse gases in our atmosphere, particularly carbon dioxide (CO2), has been recognized by the scientific, industrial, and political communities. The increase in… (more)

Thammavongsy, Zachary

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Carbonation of Calcium Silicates for Long-Term CO2 Sequestration  

Carbonation of Calcium Silicates for Long-Term CO2 Sequestration ... technology for reducing industrial CO2 emissions into the Earth’s atmosphere. Inventor PALMER, ...

322

S&TR | May 2005: Locked in Rock: Sequestering Carbon Dioxide...  

NLE Websites -- All DOE Office Websites (Extended Search)

abundant greenhouse gas is carbon dioxide (CO2). Many climate research studies focus on developing technologies to greatly reduce the atmospheric levels of CO2. One approach...

323

Dynamic molecular structure of plant biomass-derived black carbon (biochar)  

E-Print Network (OSTI)

and the atmosphere from biomass burning.  Climatic Change Introduction to pyrolysis of biomass.  J.  Anal.  Appl.  Molecular Structure of Plant Biomass-derived Black Carbon (

Keiluweit, M.

2010-01-01T23:59:59.000Z

324

CARBON TETRACHLORIDE  

E-Print Network (OSTI)

This fact sheet answers the most frequently asked health questions (FAQs) about carbon tetrachloride.

unknown authors

2005-01-01T23:59:59.000Z

325

Simulation of Atmospheric Variability  

Science Conference Proceedings (OSTI)

A spectral atmospheric circulation model is time-integrated for approximately 18 years. The model has a global computational domain and realistic geography and topography. The model undergoes an annual cycle as daily values of seasonally varying ...

Syukuro Manabe; Douglas G. Hahn

1981-11-01T23:59:59.000Z

326

Atmospheric Laser Communication  

Science Conference Proceedings (OSTI)

Atmospheric laser communication, often referred to as free-space optics (FSO) or free-space laser (FSL) communication, is similar to fiber optic cable in terms of carrier wavelength and bandwidth capability, but data are transmitted directly ...

Kenneth W. Fischer*Michael R. Witiw; Jeffrey A. Baars+; T. R. Oke

2004-05-01T23:59:59.000Z

327

Atmospheric Available Energy  

Science Conference Proceedings (OSTI)

The total potential energy of the atmosphere is the sum of its internal and gravitational energies. The portion of this total energy available to be converted into kinetic energy is determined relative to an isothermal, hydrostatic, equilibrium ...

Peter R. Bannon

2012-12-01T23:59:59.000Z

328

Atmospheric optical calibration system  

DOE Patents (OSTI)

An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

1988-01-01T23:59:59.000Z

329

Atmospheric optical calibration system  

DOE Patents (OSTI)

An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

Hulstrom, R.L.; Cannon, T.W.

1988-10-25T23:59:59.000Z

330

NETL: Carbon Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Sequestration Partnerships Regional Carbon Sequestration Partnership (RCSP) Programmatic Points of Contact Carbon Storage Program Infrastructure Coordinator Carbon Storage...

331

INCCA: Integrated Climate and Carbon  

SciTech Connect

The INCCA (Integrated Climate and Carbon) initiative will develop and apply the ability to simulate the fate and climate impact of fossil fuel-derived carbon dioxide (CO{sub 2}) and aerosols on a global scale. Coupled climate and carbon cycle modeling like that proposed for INCCA is required to understand and predict the future environmental impacts of fossil fuel burning. At present, atmospheric CO{sub 2} concentrations are prescribed, not simulated, in large climate models. Credible simulations of the entire climate system, however, need to predict time-evolving atmospheric greenhouse forcing using anthropogenic emissions as the fundamental input. Predicting atmospheric COS concentrations represents a substantial scientific advance because there are large natural sources and sinks of carbon that are likely to change as a result of climate change. Both terrestrial (e.g., vegetation on land) and oceanic components of the carbon cycle are known to be sensitive to climate change. Estimates of the amount of man-made CO{sub 2} that will accumulate in the atmosphere depend on understanding the carbon cycle. For this reason, models that use CO{sub 2} emissions, not prescribed atmospheric concentrations, as fundamental inputs are required to directly address greenhouse-related questions of interest to policymakers. INCCA is uniquely positioned to make rapid progress in this high-priority area of global change modeling and prediction because we can leverage previous and ongoing LLNL developments, and use existing component models that are well-developed and published. The need for a vastly improved carbon dioxide prediction capability is appreciated by the DOE. As the US Accelerated Climate Prediction Initiative (ACPI) progresses, we expect the DOE will emphasize the carbon cycle as the next major department-level earth science focus. INCCA will position LLNL for substantial additional funding as this new focus is realized. In the limited time since our LDRD funding was first received (1 November 2000) we have made good progress in acquisition and testing of component models, applications of the terrestrial biosphere model, enhancements to the ocean carbon cycle model and development of the fossil fuel aerosol model.

Thompson, S L

2001-03-13T23:59:59.000Z

332

Carbon dioxide and climate  

SciTech Connect

Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

1990-10-01T23:59:59.000Z

333

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents (OSTI)

A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

1995-01-01T23:59:59.000Z

334

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents (OSTI)

A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

Steinberg, M.; Grohse, E.W.

1995-06-27T23:59:59.000Z

335

Incorporation of CO2 Exchange Processes into a Multilayer Atmosphere–Soil–Vegetation Model  

Science Conference Proceedings (OSTI)

Carbon dioxide (CO2) exchange processes were incorporated into a multilayer atmosphere–soil–vegetation model known as SOLVEG, and its performance was examined using measurements obtained from a grassland site. It was also applied for the CO2 ...

Haruyasu Nagai

2005-10-01T23:59:59.000Z

336

If anthropogenic CO2 emissions cease, will atmospheric CO2 concentration continue to increase?  

Science Conference Proceedings (OSTI)

If anthropogenic CO2 emissions were to suddenly cease, the evolution of the atmospheric CO2 concentration would depend on the magnitude and sign of natural carbon sources and sinks. Experiments using Earth system models indicate that overall ...

Andrew H. MacDougall; Michael Eby; Andrew J. Weaver

337

Worldwide Measurements of Atmospheric CO2 and Other Trace Gas Species Using Commercial Airlines  

Science Conference Proceedings (OSTI)

New automated observation systems for use in passenger aircraft to measure atmospheric carbon dioxide (CO2) and other trace species have been developed and are described in this paper. The Continuous CO2 Measuring Equipment (CME) is composed ...

T. Machida; H. Matsueda; Y. Sawa; Y. Nakagawa; K. Hirotani; N. Kondo; K. Goto; T. Nakazawa; K. Ishikawa; T. Ogawa

2008-10-01T23:59:59.000Z

338

Carbon Capture and Storage  

Science Conference Proceedings (OSTI)

Carbon capture and sequestration (CCS) is the long-term isolation of carbon dioxide from the atmosphere through physical, chemical, biological, or engineered processes. This includes a range of approaches including soil carbon sequestration (e.g., through no-till farming), terrestrial biomass sequestration (e.g., through planting forests), direct ocean injection of CO{sub 2} either onto the deep seafloor or into the intermediate depths, injection into deep geological formations, or even direct conversion of CO{sub 2} to carbonate minerals. Some of these approaches are considered geoengineering (see the appropriate chapter herein). All are considered in the 2005 special report by the Intergovernmental Panel on Climate Change (IPCC 2005). Of the range of options available, geological carbon sequestration (GCS) appears to be the most actionable and economic option for major greenhouse gas reduction in the next 10-30 years. The basis for this interest includes several factors: (1) The potential capacities are large based on initial estimates. Formal estimates for global storage potential vary substantially, but are likely to be between 800 and 3300 Gt of C (3000 and 10,000 Gt of CO{sub 2}), with significant capacity located reasonably near large point sources of the CO{sub 2}. (2) GCS can begin operations with demonstrated technology. Carbon dioxide has been separated from large point sources for nearly 100 years, and has been injected underground for over 30 years (below). (3) Testing of GCS at intermediate scale is feasible. In the US, Canada, and many industrial countries, large CO{sub 2} sources like power plants and refineries lie near prospective storage sites. These plants could be retrofit today and injection begun (while bearing in mind scientific uncertainties and unknowns). Indeed, some have, and three projects described here provide a great deal of information on the operational needs and field implementation of CCS. Part of this interest comes from several key documents written in the last three years that provide information on the status, economics, technology, and impact of CCS. These are cited throughout this text and identified as key references at the end of this manuscript. When coupled with improvements in energy efficiency, renewable energy supplies, and nuclear power, CCS help dramatically reduce current and future emissions (US CCTP 2005, MIT 2007). If CCS is not available as a carbon management option, it will be much more difficult and much more expensive to stabilize atmospheric CO{sub 2} emissions. Recent estimates put the cost of carbon abatement without CCS to be 30-80% higher that if CCS were to be available (Edmonds et al. 2004).

Friedmann, S

2007-10-03T23:59:59.000Z

339

REDUCTION OF NITRIC OXIDE BY CARBON MONOXIDE OVER A SILICA SUPPORTED PLATINUM CATALYST: INFRARED AND KINETIC STUDIES  

E-Print Network (OSTI)

System. • B. Procedures. Catalyst Preparation Infrared DiskPreparation. Catalyst Characterization. PreliminaryReduction by CO Over a Pt Catalyst," M.S. thesis, Department

Lorimer, D.H.

2011-01-01T23:59:59.000Z

340

SYNTHESIS OF OXYGENATED PRODUCTS FROM CARBON MONOXIDE AND HYDROGEN OVER SILICA- AND ALUMINA-SUPPORTED RUTHENIUM CATALYSTS  

E-Print Network (OSTI)

Formation Over a 1.01; Ru/A1 o Catalyst at 498K H/CO P (atm)a silica-supported Ru catalyst Fig. 2 Effect of feed flowan alumina-supported Ru catalyst Fig. 3 Effect of reaction

Kellner, C.Stephen

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Seasonal variation of carbon monoxide in northern Japan: Fourier transform IR measurements and source-labeled model calculations  

E-Print Network (OSTI)

the Siberian high and Aleutian low dominated over northernthe Siberian high and Aleutian low resulted in higher

2006-01-01T23:59:59.000Z

342

The effect of carbon monoxide on the colour stability and quality of yellowfin tuna (Thunnus Albacares) muscle.  

E-Print Network (OSTI)

??ENGLISH ABSTRACT: Processors face the problem of extending the shelf-life of yellowfin tuna, while still maintaining the desirable bright red colour. Methods which have commonly… (more)

Neethling, Nikki E.

2013-01-01T23:59:59.000Z

343

Program on Technology Innovation: Monitoring Carbon Monoxide and Nitric Oxide in Combustion Gases with Laser Absorption Sensors  

Science Conference Proceedings (OSTI)

Two important considerations for monitoring CO/O2 and NO/NH3 in the flue gas of coal-fired boilers include (1) optimization of the air/fuel distribution to individual burners, thereby enabling lower excess oxygen operation, reduced NOx emissions, and improved unit heat rate, and (2) optimization of NH3/NOx distribution at the inlet of a selective catalytic reduction (SCR) reactor, thereby enabling increased NOx reduction performance while maintaining ammonia slip targets. Lower NOx emissions can be achie...

2011-04-12T23:59:59.000Z

344

SYNTHESIS OF OXYGENATED PRODUCTS FROM CARBON MONOXIDE AND HYDROGEN OVER SILICA- AND ALUMINA-SUPPORTED RUTHENIUM CATALYSTS  

E-Print Network (OSTI)

R. B. , "The Fischer-Tropsch and Related Syntheses", Wiley,with hydrocarbons during Fischer-Tropsch synthesis over iron

Kellner, C.Stephen

2013-01-01T23:59:59.000Z

345

Seasonal variation of carbon monoxide in northern Japan: Fourier transform IR measurements and source-labeled model calculations  

E-Print Network (OSTI)

emissions in this study. Fossil fuel and biofuel emissionsdirect emissions by 20% (fossil fuel) and 10% (biofuel andNMVOC) emissions from fossil fuels [Piccot et al. , 1992

2006-01-01T23:59:59.000Z

346

SYNTHESIS OF OXYGENATED PRODUCTS FROM CARBON MONOXIDE AND HYDROGEN OVER SILICA- AND ALUMINA-SUPPORTED RUTHENIUM CATALYSTS  

E-Print Network (OSTI)

is consistent with the projection discussed above. Theis consistent with the projection given recently by Wilson (

Kellner, C.Stephen

2013-01-01T23:59:59.000Z

347

Glossary: Energy-Related Carbon Emissions  

U.S. Energy Information Administration (EIA) Indexed Site

Glossary: Energy-Related Carbon Emissions Glossary: Energy-Related Carbon Emissions Glossary: Energy-Related Carbon Emissions For additional terms, refer to: the Glossary of Emissions of Greenhouse Gases in the United States 1998 for additional greenhouse gas related terms, the Glossary of Manufacturing Consumption of Energy 1994 for additional manufacturing terms, and Appendix F of Manufacturing Consumption of Energy 1994 for descriptions of the major industry groups. British Thermal Unit: The amount of heat required to raise the temperature of 1 pound of water by 1 degree Fahrenheit. One quadrillion Btu is 1015 Btu, or 1.055 exajoules. Btu: See British Thermal Unit. Carbon Dioxide: A colorless, odorless, non-poisonous gas that is a normal part of Earth's atmosphere. Carbon dioxide is a product of fossil-fuel combustion as well as other processes. It is considered a greenhouse gas as it traps heat radiated into the atmosphere and thereby contributes to the potential for global warming.

348

Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets  

Science Conference Proceedings (OSTI)

Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within ± 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than ± 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than ± 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2?3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute are captured. Influence functions, derived using a Lagrangian Particle Dispersion model driven by the CSU Regional Atmospheric Modeling System and nudged to NCEP reanalysis meteorological fields, are used to determine source regions for the towers. The influence functions are combined with satellite vegetation observations to interpret the observed trends in CO2 concentration. Full inversions will combine these elements in a more formal analytic framework.

Davis, K.J.; Richardson, S.J.; Miles, N.L.

2007-03-07T23:59:59.000Z

349

Challenges for improving estimates of soil organic carbon stored in  

NLE Websites -- All DOE Office Websites (Extended Search)

Challenges for improving estimates of soil organic carbon stored in Challenges for improving estimates of soil organic carbon stored in permafrost regions September 30, 2013 Tweet EmailPrint One of the greatest environmental challenges of the 21st century lies in predicting the impacts of anthropogenic activities on Earth's carbon cycle. Soil is a significant component of the carbon cycle, because it contains at least two-thirds of the world's terrestrial carbon and more than twice as much carbon as the atmosphere. Although soil organic carbon (SOC) stocks were built over millennial time scales, they are susceptible to a far more rapid release back to the atmosphere due to climatic and land use change. If environmental perturbations negatively impact the processes regulating the storage of SOC, significant amounts of this carbon could be decomposed

350

THERMALLY DRIVEN ATMOSPHERIC ESCAPE  

Science Conference Proceedings (OSTI)

Accurately determining the escape rate from a planet's atmosphere is critical for determining its evolution. A large amount of Cassini data is now available for Titan's upper atmosphere and a wealth of data is expected within the next decade on escape from Pluto, Mars, and extra-solar planets. Escape can be driven by upward thermal conduction of energy deposited well below the exobase, as well as by nonthermal processes produced by energy deposited in the exobase region. Recent applications of a model for escape driven by upward thermal conduction, called the slow hydrodynamic escape model, have resulted in surprisingly large loss rates for the atmosphere of Titan, Saturn's largest moon. Based on a molecular kinetic simulation of the exobase region, these rates appear to be orders of magnitude too large. Therefore, the slow hydrodynamic model is evaluated here. It is shown that such a model cannot give a reliable description of the atmospheric temperature profile unless it is coupled to a molecular kinetic description of the exobase region. Therefore, the present escape rates for Titan and Pluto must be re-evaluated using the atmospheric model described here.

Johnson, Robert E., E-mail: rej@virginia.ed [Engineering Physics, Thornton Hall B102, University of Virginia, Charlottesville, VA 22902 (United States); Physics Department, New York University, New York, NY 10003 (United States)

2010-06-20T23:59:59.000Z

351

Implications of "peak oil" for atmospheric CO2 and climate  

E-Print Network (OSTI)

Peaking of global oil production may have a large effect on future atmospheric CO2 amount and climate change, depending upon choices made for subsequent energy sources. We suggest that, if estimates of oil and gas reserves by the Energy Information Administration are realistic, it is feasible to keep atmospheric CO2 from exceeding approximately 450 ppm, provided that future exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration, must be phased out before mid-century to achieve this limit on atmospheric CO2. We also suggest that it is important to "stretch" oil reserves via energy efficiency, thus avoiding the need to extract liquid fuels from coal or unconventional fossil fuels. We argue that a rising price on carbon emissions is probably needed to keep CO2 beneath the 450 ppm ceiling.

Kharecha, P A

2007-01-01T23:59:59.000Z

352

Article Atmospheric Science  

NLE Websites -- All DOE Office Websites (Extended Search)

© The Author(s) 2012. This article is published with open access at Springerlink.com csb.scichina.com www.springer.com/scp © The Author(s) 2012. This article is published with open access at Springerlink.com csb.scichina.com www.springer.com/scp *Corresponding author (email: luchunsong110@gmail.com) Article Atmospheric Science February 2013 Vol.58 No.4-5: 545  551 doi: 10.1007/s11434-012-5556-6 A method for distinguishing and linking turbulent entrainment mixing and collision-coalescence in stratocumulus clouds LU ChunSong 1,2* , LIU YanGang 2 & NIU ShengJie 1 1 Key Laboratory for Atmospheric Physics and Environment of China Meteorological Administration, Key Laboratory of Meteorological Disaster of Ministry of Education, Nanjing University of Information Science and Technology, Nanjing 210044, China; 2 Atmospheric Sciences Division, Brookhaven National Laboratory, New York 11973, USA

353

ARM - Measurement - Atmospheric moisture  

NLE Websites -- All DOE Office Websites (Extended Search)

moisture moisture ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Atmospheric moisture The moisture content of the air as indicated by several measurements including relative humidity, specific humidity, dewpoint, vapor pressure, water vapor mixing ratio, and water vapor density; note that precipitable water is a separate type. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments AERI : Atmospheric Emitted Radiance Interferometer

354

BNL | Atmospheric Systems Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric System Research is a DOE observation-based research program Atmospheric System Research is a DOE observation-based research program created to advance process-level understanding of the key interactions among aerosols, clouds, precipitation, radiation, dynamics, and thermodynamics, with the ultimate goal of reducing the uncertainty in global and regional climate simulations and projections. General areas of research at BNL under this program include studies of aerosol and cloud lifecycles, and cloud-aerosol-precipitation interactions. Contact Robert McGraw, 631.344.3086 aerosols Aerosol Life Cycle The strategic focus of the Aerosol Life Cycle research is observation-based process science-examining the properties and evolution of atmospheric aerosols. Observations come from both long-term studies conducted by the

355

A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells  

SciTech Connect

The cathode CL of a polymer electrolyte membrane fuel cell (PEMFC) was exposed to high potentials, 1.0 to 1.4 V versus a reversible hydrogen electrode (RHE), that are typically encountered during start up/shut down operation. While both platinum dissolution and carbon corrosion occurred, the carbon corrosion effects were isolated and modeled. The presented model separates the carbon corrosion process into two reaction steps; (1) oxidation of the carbon surface to carbon-oxygen groups, and (2) further corrosion of the oxidized surface to carbon dioxide/monoxide. To oxidize and corrode the cathode catalyst carbon support, the CL was subjected to an accelerated stress test cycled the potential from 0.6 VRHE to an upper potential limit (UPL) ranging from 0.9 to 1.4 VRHE at varying dwell times. The reaction rate constants and specific capacitances of carbon and platinum were fitted by evaluating the double layer capacitance (Cdl) trends. Carbon surface oxidation increased the Cdl due to increased specific capacitance for carbon surfaces with carbon-oxygen groups, while the second corrosion reaction decreased the Cdl due to loss of the overall carbon surface area. The first oxidation step differed between carbon types, while both reaction rate constants were found to have a dependency on UPL, temperature, and gas relative humidity.

Young, Alan; Colbow, Vesna; Harvey, David; Rogers, Erin; Wessel, Silvia

2013-01-01T23:59:59.000Z

356

Biofuels Science and Facilities (Carbon Cycle 2.0)  

DOE Green Energy (OSTI)

Jay D. Keasling speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 2, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

Keasling, Jay D.

2010-02-04T23:59:59.000Z

357

Modeling and Scaling Coupled Energy, Water, and Carbon Fluxes Based on Remote Sensing: An Application to Canada’s Landmass  

Science Conference Proceedings (OSTI)

Land surface models (LSMs) need to be coupled with atmospheric general circulation models (GCMs) to adequately simulate the exchanges of energy, water, and carbon between the atmosphere and terrestrial surfaces. The heterogeneity of the land ...

Baozhang Chen; Jing M. Chen; Gang Mo; Chiu-Wai Yuen; Hank Margolis; Kaz Higuchi; Douglas Chan

2007-04-01T23:59:59.000Z

358

Workshop on Carbon Sequestration Science - Ocean Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Ocean Carbon Ocean Carbon Sequestration Howard Herzog MIT Energy Laboratory May 24, 2001 Ocean Carbon Sequestration Options * The direct injection of a relatively pure CO 2 stream that has been generated, for example, at a power plant or from an industrial process * The enhancement of the net oceanic uptake from the atmosphere, for example, through iron fertilization The DOE Center for Research on Ocean Carbon Sequestration (DOCS) * Established July 1999 * Centered at LBNL and LLNL * Participants S Eric Adams MIT S Jim Barry MBARI S Jim Bishop DOCS Scientific Co-director LBNL S Ken Caldeira DOCS Scientific Co-director LLNL S Sallie Chisholm MIT S Kenneth Coale Moss Landing Marine Laboratory S Russ Davis Scripps Institution of Oceanography S Paul Falkowski Rutgers S Howard Herzog MIT S Gerard Nihous Pacific International Center for High Technology Research

359

Tropical forestry practices for carbon sequestration  

E-Print Network (OSTI)

Carbon sequestration through forestry has the potential to play a significant role in ameliorating global environmental problems such as atmospheric accumulation of GHG's and climate change. This chapter provides an overview of various aspects related to carbon sequestration through forestry. It describes the main concepts of carbon fixation; the trends in global environmental policy are discussed; different forestry practices are listed; examples of existing projects are given; and finally, a case study of a carbon sequestration project in Malaysia is described. The paper also discusses issues related to the quantification of carbon sequestration potential of different forestry options. This section was included with the intention of specifically highlighting some problems related to commercial transactions for carbon sequestration. Key words: carbon sequestration, CO2 offset, tropical forestry, dipterocarps.

Pedro Moura-costa; Innoprise-face Foundation

1996-01-01T23:59:59.000Z

360

Carbon film electrodes for super capacitor applications  

DOE Patents (OSTI)

A microporous carbon film for use as electrodes in energy strorage devices is disclosed, which is made by the process comprising the steps of: (1) heating a polymer film material consisting essentially of a copolymer of polyvinylidene chloride and polyvinyl chloride in an inert atmosphere to form a carbon film; and (2) activating said carbon film to form said microporous carbon film having a density between about 0.7 g/cm.sup.2 and 1 g/cm.sup.2 and a gravimetric capacitance of about between 120 F/g and 315 F/g.

Tan, Ming X. (Livermore, CA)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

CO.sub.2 Pretreatment prevents calcium carbonate formation  

DOE Patents (OSTI)

Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by pretreatment with carbon dioxide. The carbon dioxide pretreatment is believed to convert the scale-forming components to the corresponding carbonate prior to liquefaction. The pretreatment is accomplished at a total pressure within the range from about 14 to about 68 atmospheres and a carbon dioxide partial pressure within the range from about 14 to about 34 atmospheres. Temperature during pretreatment will generally be within the range from about 100.degree. to about 200.degree. C.

Neavel, Richard C. (Baytown, TX); Brunson, Roy J. (Buffalo Grove, IL); Chaback, Joseph J. (Worthington, OH)

1980-01-01T23:59:59.000Z

362

DOE/ER-0441 Atmospheric Radiation Measurement Plan - February 1990  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 Atmospheric Radiation Measurement Program Plan ARM Program Plan Forward In 1978 the Department of Energy initiated the Carbon Dioxide Research Program to address climate change from the increasing concentration of carbon dioxide in the atmosphere. Over the years the Program has studied the many facets of the issue, from the carbon cycle, the climate diagnostics, the vegetative effects, to the societal impacts. The Program is presently the Department's principal entry in the U.S. Global Change Research Program coordinated by the Committee on Earth Sciences (CES) of the Office of Science and Technology Policy (OSTP). The recent heightened concern about global warming from an enhanced greenhouse effect has prompted the Department to accelerate the research to improve predictions of climate change. The emphasis is on

363

Precomputed atmospheric scattering  

Science Conference Proceedings (OSTI)

We present a new and accurate method to render the atmosphere in real time from any viewpoint from ground level to outer space, while taking Rayleigh and Mie multiple scattering into account. Our method reproduces many effects of the scattering of light, ...

Eric Bruneton; Fabrice Neyret

2008-06-01T23:59:59.000Z

364

Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters...  

Open Energy Info (EERE)

waters contain magmatic helium with 3He4He ratios as high as 4.5 times the atmospheric ratio, and a magmatic component in the dissolved inorganic carbon (DIC) can be identified in...

365

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

E-Print Network (OSTI)

factors for carbon monoxide, nitrogen oxides,  nitrogen dioxide, factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, 

Singer, Brett C.

2010-01-01T23:59:59.000Z

366

ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement  

NLE Websites -- All DOE Office Websites (Extended Search)

An Integrated Column Description An Integrated Column Description of the Atmosphere An Integrated Column Description of the Atmosphere Tom Ackerman Chief Scientist Tom Ackerman Chief Scientist ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Pacific Northwest National Laboratory Pacific Northwest National Laboratory The "other" Washington ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Credits to Credits to * Ric Cederwall * Xiquan Dong * Chuck Long * Jay Mace * Mark Miller * Robin Perez * Dave Turner and the rest of the ARM science team * Ric Cederwall * Xiquan Dong * Chuck Long * Jay Mace * Mark Miller * Robin Perez * Dave Turner and the rest of the ARM science team ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement Outline Outline * A little philosophy

367

Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Cycle Carbon Cycle Latest Global Carbon Budget Estimates Including CDIAC Estimates Terrestrial Carbon Management Data Sets and Analyses Carbon Dioxide Emissions from Fossil-Fuel Consumption and Cement Manufacture, (2011) Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Monthly Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature (2012) Monthly Fossil-Fuel CO2 Emissions: Isomass (δ 13C) of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) AmeriFlux - Terrestrial Carbon Dioxide, Water Vapor, and Energy Balance Measurements Estimates of Monthly CO2 Emissions and Associated 13C/12C Values

368

Modification of a Commercial Gas Filter Correlation CO Detector for Enhanced Sensitivity  

Science Conference Proceedings (OSTI)

Carbon monoxide is important in tropospheric chemsitry and useful in studies of cloud dynamics, yet measurements of this gas, especially from aircraft, are too few to characterize fully the atmospheric sources, sinks and distribution of CO. This ...

Russell R. Dickerson; Anthony C. Delany

1988-06-01T23:59:59.000Z

369

Radiative Measurements of Pressure Modulator Operation  

Science Conference Proceedings (OSTI)

The pressure modulator is extensively used in atmospheric measurements but is not well characterized in terms of its spectroscopic operation. A series of measurements on a carbon monoxide radiometer is described and comparisons are made with ...

J. R. Drummond; A. Ashton

1990-02-01T23:59:59.000Z

370

A conceptual framework for the evaluation of cost-effectiveness of projects to reduce GHG emissions and sequester carbon  

SciTech Connect

This paper proposes a conceptual framework for evaluating the cost of projects to reduce atmospheric greenhouse gases (GHGs). The evaluation of cost-effectiveness should account for both the timing of carbon emissions and the damage caused by the atmospheric stock of carbon. We develop a conceptual basis to estimate the cost-effectiveness of projects in terms of the cost of reducing atmospheric carbon (CRAC) and other GHGs. CRAC accounts for the economic discount rate, alternative functional forms of the shadow price, the residence period of carbon in the atmosphere, and the multiple monetary benefits of projects. The last item is of particular importance to the developing countries.

Sathaye, J.; Norgaard, R.; Makundi, W.

1993-07-01T23:59:59.000Z

371

Review of Bioenergy with Carbon Capture and Storage (BECCS) and Possibilities of Introducing a Small-Scale Unit.  

E-Print Network (OSTI)

?? With the ever-increasing level of carbon dioxide in the atmosphere, there is an enormous need to find new ways to minimize CO2 emissions. One… (more)

Edström, Elin

2013-01-01T23:59:59.000Z

372

The Effect of the Water Vapor and Carbon Dioxide on the Radiation Absorption and Temperature Profile in Troposphere.  

E-Print Network (OSTI)

??The work on this paper focus on the effect of the water vapor and carbon dioxide on the absorption of atmospheric radiation and the temperature… (more)

Li, Chieh

2013-01-01T23:59:59.000Z

373

Catalytic Transformation of Waste Carbon Dioxide into Valuable Products  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Transformation of Waste Catalytic Transformation of Waste Carbon Dioxide into Valuable Products Background Many industrial processes contribute large amounts of carbon dioxide (CO 2 ) to the earth's atmosphere. In an effort to reduce the amount of CO 2 released to the atmosphere, the U.S. Department of Energy (DOE) is funding efforts to develop CO 2 capture and storage technologies. In addition to permanent storage of CO 2 in underground reservoirs, some

374

Hydrostatic Adjustment in Nonisothermal Atmospheres  

Science Conference Proceedings (OSTI)

The author examines hydrostatic adjustment due to heating in two nonisothermal atmospheres. In the first case both the temperature and lapse rate decrease with height; in the second case the atmosphere consists of a troposphere with constant ...

Dean G. Duffy

2003-01-01T23:59:59.000Z

375

Efficient rendering of atmospheric phenomena  

Science Conference Proceedings (OSTI)

Rendering of atmospheric bodies involves modeling the complex interaction of light throughout the highly scattering medium of water and air particles. Scattering by these particles creates many well-known atmospheric optical phenomena including rainbows, ...

Kirk Riley; David S. Ebert; Martin Kraus; Jerry Tessendorf; Charles Hansen

2004-06-01T23:59:59.000Z

376

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation's carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. (Energy Research Corp., Danbury, CT (United States)); Meyers, S.J. (Fluor Daniel, Inc., Irvine, CA (United States)); Hauserman, W.B. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

1992-01-01T23:59:59.000Z

377

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation`s carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. [Energy Research Corp., Danbury, CT (United States); Meyers, S.J. [Fluor Daniel, Inc., Irvine, CA (United States); Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

1992-12-01T23:59:59.000Z

378

THE FACILITY 350 HELIUM-ATMOSPHERE SYSTEM. Final Report, Metallurgy Division Program 1.5.5  

SciTech Connect

The He atmosphere system in Argonne's Facility 350 is described in detail. The system is straightforward, employing drying and carbon towers for the removal of moisture, oxygen, and other impurities. The bulk of the 15,000 ft/ sup 3/ of He atmosphere is continuously recirculated at nearly atmospheric pressure. Purification is accomplished at 140 psig on a portion of the gas that is passed through the drying tower at room temperature and the carbon towers at -- 46 deg C (--50 deg F). The operation is continuous, requiring a minimum of maintenance and operational manpower. The He atmosphere is supplied to the glove- boxes with impurity levels below 3,000 ppm nitrogen, 1,000 ppm oxygen, and 50 ppm moisture. Such purity levels prevent oxidation and combustion of the Pu materials being processed. Experimental data concerning the adsorption of oxygen from He by activated carbon over a range of temperature and pressure conditions are reported. (auth)

Mayfield, R.M.; Tope, W.G.; Shuck, A.B.

1962-12-01T23:59:59.000Z

379

Corona method and apparatus for altering carbon containing compounds  

DOE Patents (OSTI)

The present invention is a method and apparatus for altering a carbon containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

Sharma, Amit K. (Richland, WA); Camaioni, Donald M. (Richland, WA); Josephson, Gary B. (Richland, WA)

1999-01-01T23:59:59.000Z

380

Corona Method And Apparatus For Altering Carbon Containing Compounds  

DOE Patents (OSTI)

The present invention is a method and apparatus for altering a carbon-containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon-containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

Sharma, Amit K. (Plainsboro, NJ); Camaioni, Donald M. (Richland, WA); Josephson; Gary B. (Richland, WA)

2004-05-04T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Analysis and optimization of the Graz cycle : a coal fired power generation scheme with near-zero carbon dioxide emissions  

E-Print Network (OSTI)

Humans are releasing record amounts of carbon dioxide into the atmosphere through the combustion of fossil fuels in power generation plants. With mounting evidence that this carbon dioxide is a leading cause of global ...

Alexander, Brentan R

2007-01-01T23:59:59.000Z

382

Carbon Film Electrodes For Super Capacitor Applications  

DOE Patents (OSTI)

A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

Tan, Ming X. (Livermore, CA)

1999-07-20T23:59:59.000Z

383

Differential atmospheric tritium sampler  

DOE Patents (OSTI)

An atmospheric tritium sampler is provided which uses a carrier gas comprised of hydrogen gas and a diluting gas, mixed in a nonexplosive concentration. Sample air and carrier gas are drawn into and mixed in a manifold. A regulator meters the carrier gas flow to the manifold. The air sample/carrier gas mixture is pulled through a first moisture trap which adsorbs water from the air sample. The mixture then passes through a combustion chamber where hydrogen gas in the form of H.sub.2 or HT is combusted into water. The manufactured water is transported by the air stream to a second moisture trap where it is adsorbed. The air is then discharged back into the atmosphere by means of a pump.

Griesbach, Otto A. (Langhorne, PA); Stencel, Joseph R. (Skillman, NJ)

1990-01-01T23:59:59.000Z

384

Atmospheric Release Advisory Capability  

SciTech Connect

The Atmospheric Release Advisory Capability (ARAC) project is a Department of Energy (DOE) sponsored real-time emergency response service available for use by both federal and state agencies in case of a potential or actual atmospheric release of nuclear material. The project, initiated in 1972, is currently evolving from the research and development phase to full operation. Plans are underway to expand the existing capability to continuous operation by 1984 and to establish a National ARAC Center (NARAC) by 1988. This report describes the ARAC system, its utilization during the past two years, and plans for its expansion during the next five to six years. An integral part of this expansion is due to a very important and crucial effort sponsored by the Defense Nuclear Agency to extend the ARAC service to approximately 45 Department of Defense (DOD) sites throughout the continental US over the next three years.

Dickerson, M.H.; Gudiksen, P.H.; Sullivan, T.J.

1983-02-01T23:59:59.000Z

385

Atmospheric Mercury Research Update  

Science Conference Proceedings (OSTI)

This report is a summary and analysis of research findings on utility and environmental mercury from 1997 to 2003. The update categorizes and describes recent work on mercury in utility-burned coal and its route through power plants, the measures for its control, and its fate in the environment following emissions from utility stacks. This fate includes atmospheric chemistry and transport, deposition to land and water surfaces, aquatic cycling, the dynamics of mercury in freshwater fish food webs, and th...

2004-03-30T23:59:59.000Z

386

Impact of biomass burning on the atmosphere  

DOE Green Energy (OSTI)

Fire has played an important part in biogeochemical cycling throughout most of the history of our planet. Ice core studies have been very beneficial in paleoclimate studies and constraining the budgets of biogeochemical cycles through the past 160,000 years of the Vostok ice core. Although to date there has been no way of determining cause and effect, concentration of greenhouse gases directly correlates with temperature in ice core analyses. Recent ice core studies on Greenland have shown that significant climate change can be very rapid on the order of a decade. This chapter addresses the coupled evolution of our planet`s atmospheric composition and biomass burning. Special attention is paid to the chemical and climatic impacts of biomass burning on the atmosphere throughout the last century, specifically looking at the cycles of carbon, nitrogen, and sulfur. Information from ice core measurements may be useful in understanding the history of fire and its historic affect on the composition of the atmosphere and climate.

Dignon, J.

1993-03-01T23:59:59.000Z

387

and Implications for the Global Carbon Cycle Executive Summary  

E-Print Network (OSTI)

North America is currently a net source of carbon dioxide to the atmosphere, contributing to the global buildup of greenhouse gases in the atmosphere and associated changes in the earth’s climate. In 2003, North America emitted nearly two billion metric tons of carbon to the atmosphere as carbon dioxide. North America’s fossil fuel emissions in 2003 (1856 million metric tons of carbon ±10 % with 95 % certainty) were 27 % of global emissions. Approximately 85 % of those emissions were from the United States, 9 % from Canada and 6 % from Mexico. The conversion of fossil fuels to energy (primarily electricity) is the single largest contributor, accounting for approximately 42 % of North American fossil emissions in 2003. Transportation is the second largest, accounting for 31 % of total emissions. There are also globally important carbon sinks in North America. In 2003, growing vegetation in North America removed approximately 530 million tons of carbon per year ( ± 50%) from the atmosphere and stored it as plant material and soil organic matter. This land sink is equivalent to approximately 30 % of the fossil fuel emissions from North America. The imbalance between the fossil fuel source and the sink on land is a net release to the atmosphere of 1335 million metric tons of carbon per year ( ± 25%). Approximately 50 % of North America’s terrestrial sink is due to the regrowth of forests in the United

Lisa Dilling (co-lead; David M. Fairman; Richard A. Houghton; Gregg H. Marl; Adam Z. Rose; Thomas J. Wilbanks

2007-01-01T23:59:59.000Z

388

Carbon dioxide disposal in solid form  

SciTech Connect

Coal reserves can provide for the world`s energy needs for centuries. However, coal`s long term use may be severely curtailed if the emission of carbon dioxide into the atmosphere is not eliminated. We present a safe and permanent method of carbon dioxide disposal that is based on combining carbon dioxide chemically with abundant raw materials to form stable carbonate minerals. We discuss the availability of raw materials and potential process designs. We consider our initial rough cost estimate of about 3{cents}/kWh encouraging. The availability of a carbon dioxide fixation technology would serve as insurance in case global warming, or the perception of global warming, causes severe restrictions on carbon dioxide emissions. If the increased energy demand of a growing world population is to be satisfied from coal, the implementation of such a technology would quite likely be unavoidable.

Lackner, K.S.; Butt, D.P.; Sharp, D.H. [Los Alamos National Lab., NM (United States); Wendt, C.H. [Auxon Corp., (United States)

1995-12-31T23:59:59.000Z

389

Carbon Nanotubes  

Science Conference Proceedings (OSTI)

Carbon Nanotubes. Sponsored by: TMS Electronic, Magnetic and Photonic Materials Division Date and Time: Sunday, February 13, 2005 ~ 8:30 am-5:00 pm

390

Carbon Nanomaterials  

Science Conference Proceedings (OSTI)

Mar 12, 2012 ... The graphene film was spin-coated using carbon nanotubes to form the cathode of the field emission device. A phosphor coated graphene-PET ...

391

ORISE: Climate and Atmospheric Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Climate and Atmospheric Research Climate and Atmospheric Research Capabilities Overview U.S. Climate Reference Network U.S. Historical Climate Network Contact Us Oak Ridge Institute for Science Education Climate and Atmospheric Research The Oak Ridge Institute for Science and Education (ORISE) partners with the National Oceanic and Atmospheric Administration's Atmospheric Turbulence and Diffusion Division (ATDD) to conduct climate research focused on issues of national and global importance. Research is performed with personnel support from ORISE's Independent Environmental Assessment and Verification (IEAV) programs, as well as in collaboration with scientists and engineers from Oak Ridge National Laboratory (ORNL), and numerous other organizations, government agencies, universities and private research institutions.

392

Atmospheric attenuation of solar radiation  

DOE Green Energy (OSTI)

The attenuation of solar radiation by the atmosphere between the heliostat and receiver of a Central Receiver solar energy system has been computed for a number of atmospheric conditions and tower-heliostat distances. The most important atmospheric variable is found to be the atmospheric aerosol content. No dependence of atmospheric water vapor is found and only a weak dependence on solar zenith angle. For a 500 m heliostat-tower distance two to four percent reductions are expected under typical desert conditions (50 to 120 km visibility). The reduction is approximately linear with heliostat-tower distance. A representative value of the attenuation coefficient is 0.051 km/sup -1/.

Randall, C.M.

1977-05-18T23:59:59.000Z

393

NETL: Gasifipedia - Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal: SNG from Coal: Process & Commercialization: Carbon Sequestration Coal: SNG from Coal: Process & Commercialization: Carbon Sequestration Carbon sequestration, also termed carbon storage, is the permanent storage of CO2, usually in deep geologic formations. Industrially-generated CO2 -- resulting from fossil fuel combustion, gasification, and other industrial processes -- is injected as a supercritical fluid into geologic reservoirs, where it is held in place by natural traps and seals. Carbon storage is one approach to minimizing atmospheric emissions of man-made CO2. As discussed above, the main purpose of CO2 EOR such as the Weyburn Project is tertiary recovery of crude oil, but in effect substantial CO2 remains sequestered/stored as a result. Current Status of CO2 Storage CO2 storage is currently underway in the United States and around the world. Large, commercial-scale projects, like the Sleipner CO2 Storage Site in Norway and the Weyburn-Midale CO2 Project in Canada, have been injecting CO2 into geologic storage formations more than a decade. Each of these projects stores more than 1 million tons of CO2 per year. Large-scale efforts are currently underway in Africa, China, Australia, and Europe, as well. These commercial-scale projects are demonstrating that large volumes of CO2 can be safely and permanently stored. In addition, a number of smaller pilot projects are underway in different parts of the world to determine suitable locations and technologies for future long-term CO2 storage. To date, more than 200 small-scale CO2 storage projects have been carried out worldwide. A demonstration project that captures CO2 from a pulverized coal power plant and pipes it to a geologic formation for storage recently came online in Alabama.

394

NETL: Carbon Storage - Carbon Sequestration Leadership Forum  

NLE Websites -- All DOE Office Websites (Extended Search)

CSLF Carbon Storage Carbon Sequestration Leadership Forum CSLF Logo The Carbon Sequestration Leadership Forum (CSLF) is a voluntary climate initiative of industrially developed and...

395

PNNL: FCSD: Atmospheric Sciences & Global Change: Programs &...  

NLE Websites -- All DOE Office Websites (Extended Search)

Programs & Facilities Atmospheric Measurements Laboratory Atmospheric Radiation Measurement (ARM) Program and ARM Climate Research Facility ARM Aerial Facility Environmental...

396

A Multiscale and Multidisciplinary Investigation Of Ecosystem–Atmosphere CO2 Exchange Over the Rocky Mountains of Colorado  

Science Conference Proceedings (OSTI)

A significant fraction of Earth consists of mountainous terrain. However, the question of how to monitor the surface–atmosphere carbon exchange over complex terrain has not been fully explored. This article reports on studies by a team of ...

Jielun Sun; Steven P. Oncley; Sean P. Burns; Britton B. Stephens; Donald H. Lenschow; Teresa Campos; Andrew S. Watt; Russell K. Monson; David J. P. Moore; Jia Hu; Mark Tschudi; David S. Schimel; Steven Aulenbach; William J. Sacks; Stephan F. J. De Wekker; Chun-Ta Lai; Brian Lamb; Eugene Allwine; Teresa Coons; Dennis Ojima; Patrick Z. Ellsworth; Leonel S. L. Sternberg; Sharon Zhong; Craig Clements; Dean E. Anderson

2010-02-01T23:59:59.000Z

397

Carbon dioxide emission during forest fires ignited by lightning  

E-Print Network (OSTI)

In this paper we developed the model for the carbon dioxide emission from forest fire. The master equation for the spreading of the carbon dioxide to atmosphere is the hyperbolic diffusion equation. In the paper we study forest fire ignited by lightning. In that case the fores fire has the well defined front which propagates with finite velocity.

Magdalena Pelc; Radoslaw Osuch

2009-03-31T23:59:59.000Z

398

SPATIAL AND SEASONAL DISTRIBUTION OF CARBON DIOXIDE EMISSIONS FROM FOSSIL-FUEL COMBUSTION; GLOBAL, REGIONAL, AND NATIONAL POTENTIAL FOR SUSTAINABLE BIOENERGY FROM RESIDUE BIOMASS AND MUNICIPAL SOLID WASTE.  

E-Print Network (OSTI)

??Combustion of fossil fuels releases carbon dioxide (CO2) into the atmosphere, and has led to an increase in the atmospheric concentration of CO2. CO2 is… (more)

Gregg, Jay Sterling

2009-01-01T23:59:59.000Z

399

Capturing Carbon Dioxide From Air  

NLE Websites -- All DOE Office Websites (Extended Search)

Capturing Carbon Dioxide From Air Capturing Carbon Dioxide From Air Klaus S. Lackner (kl2010@columbia.edu; 212-854-0304) Columbia University 500 West 120th Street New York, NY 10027 Patrick Grimes (pgrimes@worldnet.att.net; 908-232-1134) Grimes Associates Scotch Plains, NJ 07076 Hans-J. Ziock (ziock@lanl.gov; 505-667-7265) Los Alamos National Laboratory P.O.Box 1663 Los Alamos, NM 87544 Abstract The goal of carbon sequestration is to take CO 2 that would otherwise accumulate in the atmosphere and put it in safe and permanent storage. Most proposed methods would capture CO 2 from concentrated sources like power plants. Indeed, on-site capture is the most sensible approach for large sources and initially offers the most cost-effective avenue to sequestration. For distributed, mobile sources like cars, on-board capture at affordable cost would not be

400

Open Ocean Iron Fertilization for Scientific Study and Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Ocean Iron Fertilization for Scientific Study and Carbon Sequestration Ocean Iron Fertilization for Scientific Study and Carbon Sequestration K. Coale coale@mlml.calstate.edu (831) 632-4400 Moss Landing Marine Laboratories 8272 Moss Landing Road Moss Landing, California 95039 USA Abstract The trace element iron has been recently shown to play a critical role in nutrient utilization, phytoplankton growth and therefore the uptake of carbon dioxide from the surface waters of the global ocean. Carbon fixation in the surface waters, via phytoplankton growth, shifts the ocean/atmosphere exchange equilibrium for carbon dioxide. As a result, levels of atmospheric carbon dioxide (a greenhouse gas) and iron flux to the oceans have been linked to climate change (glacial to interglacial transitions). These recent findings have led some to suggest that large scale

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Synthetic fuels, carbon dioxide and climate  

Science Conference Proceedings (OSTI)

The observed increase in atmospheric carbon dioxide (CO2) has been attributed to the use of fossil fuels. There is concern that the generation and use of synthetic fuels derived from oil shale and coal will accelerate the increase of CO2.

Alex R. Sapre; John R. Hummel; Ruth A. Reck

1982-01-01T23:59:59.000Z

402

Laplace transform analysis of the carbon cycle  

Science Conference Proceedings (OSTI)

A Laplace transform representation is used to describe the changes in atmospheric CO"2 in response to emissions. The formalism gives an explicit representation of generic relations that are less clear when model results are presented as numerical integrations ... Keywords: Carbon cycle, Geosequestration, Laplace transforms, Response functions

I. G. Enting

2007-10-01T23:59:59.000Z

403

Small hydrocarbon molecules in cloud-forming Brown Dwarf and giant gas planet atmospheres  

E-Print Network (OSTI)

We study the abundances of complex carbon-bearing molecules in the oxygen-rich dust- forming atmospheres of Brown Dwarfs and giant gas planets. The inner atmospheric re- gions that form the inner boundary for thermochemical gas-phase models are investigated. Results from Drift-phoenix atmosphere simulations, which include the feedback of phase- non-equilibrium dust cloud formation on the atmospheric structure and the gas-phase abun- dances, are utilised. The resulting element depletion leads to a shift in the carbon-to-oxygen ratio such that several hydrocarbon molecules and cyanopolycyanopolyynene molecules can be present. An increase in surface gravity and/or a decrease in metallicity support the increase in the partial pressures of these species. CO, CO2, CH4, and HCN contain the largest fraction of carbon. In the upper atmosphere of low-metallicity objects, more carbon is contained in C4H than in CO, and also CH3 and C2H2 play an increasingly important role as carbon-sink. We determine chemical relaxation...

Bilger, Camille; Helling, Christiane

2013-01-01T23:59:59.000Z

404

Combustion of biomass as a global carbon sink  

E-Print Network (OSTI)

This note is intended to highlight the important role of black carbon produced from biomass burning in the global carbon cycle, and encourage further research in this area. Consideration of the fundamental physical chemistry of cellulose thermal decomposition suggests that suppression of biomass burning or biasing burning practices to produce soot-free flames must inevitably transfer more carbon to the atmosphere. A simple order-of-magnitude quantitative analysis indicates that black carbon may be a significant carbon reservoir that persists over geological time scales.

Ball, Rowena

2008-01-01T23:59:59.000Z

405

On carbon footprints and growing energy use  

SciTech Connect

Could fractional reductions in the carbon footprint of a growing organization lead to a corresponding real reduction in atmospheric CO{sub 2} emissions in the next ten years? Curtis M. Oldenburg, head of the Geologic Carbon Sequestration Program of LBNL’s Earth Sciences Division, considers his own organization's carbon footprint and answers this critical question? In addressing the problem of energy-related greenhouse gas (GHG) emissions and climate change, it is essential that we understand which activities are producing GHGs and the scale of emission for each activity, so that reduction efforts can be efficiently targeted. The GHG emissions to the atmosphere of an individual or group are referred to as the ‘carbon footprint’. This terminology is entirely appropriate, because 85% of the global marketed energy supply comes from carbon-rich fossil fuel sources whose combustion produces CO{sub 2}, the main GHG causing global climate change. Furthermore, the direct relation between CO2 emissions and fossil fuels as they are used today makes energy consumption a useful proxy for carbon footprint. It would seem to be a simple matter to reduce energy consumption across the board, both individually and collectively, to help reduce our carbon footprints and therefore solve the energyclimate crisis. But just how much can we reduce carbon footprints when broader forces, such as growth in energy use, cause the total footprint to simultaneously expand? In this feature, I present a calculation of the carbon footprint of the Earth Sciences Division (ESD), the division in which I work at Lawrence Berkeley National Laboratory (LBNL), and discuss the potential for reducing this carbon footprint. It will be apparent that in terms of potential future carbon footprint reductions under projections of expected growth, ESD may be thought of as a microcosm of the situation of the world as a whole, in which alternatives to the business-as-usual use of fossil fuels are needed if absolute GHG emission reductions are to be achieved.

Oldenburg, C.M.

2011-06-01T23:59:59.000Z

406

Capturing and sequestering carbon by enhancing the natural carbon cycle: Prelimary identification of basic science needs and opportunities  

SciTech Connect

This document summarizes proceedings and conclusions of a US DOE workshop. The purpose of the workshop was to identify the underlying research needed to answer the following questions: (1) Can the natural carbon cycle be used to aid in stabilizing or decreasing atmospheric CO{sub 2} and CH{sub 4} by: (a) Increasing carbon capture; (b) Preventing carbon from returning to the atmosphere through intermediate (<100 years) to long-term sequestration (> 100 years)?; and (2) What kind of ecosystem management practices could be used to achieve this? Three working groups were formed to discuss the terrestrial biosphere, oceans, and methane. Basic research needs identified included fundamental understanding of carbon cycling and storage in soils, influence of climate change and anthropogenic emissions on the carbon cycle, and carbon capture and sequestration in oceans. 2 figs., 4 tabs.

Benson, S.M.

1997-07-01T23:59:59.000Z

407

Integrated Estimates of Global Terrestrial Carbon Sequestration  

SciTech Connect

Assessing the contribution of terrestrial carbon sequestration to international climate change mitigation requires integration across scientific and disciplinary boundaries. As part of a scenario analysis for the US Climate Change Technology Program, measurements and geographic data were used to develop terrestrial carbon sequestration estimates for agricultural soil carbon, reforestation and pasture management. These estimates were then applied in the MiniCAM integrated assessment model to evaluate mitigation strategies within policy and technology scenarios aimed at achieving atmospheric CO2 stabilization by 2100. Adoption of terrestrial sequestration practices is based on competition for land and economic markets for carbon. Terrestrial sequestration reach a peak combined rate of 0.5 to 0.7 Gt carbon yr-1 in mid-century with contributions from agricultural soil (0.21 Gt carbon yr-1), reforestation (0.31 Gt carbon yr-1) and pasture (0.15 Gt carbon yr-1). Sequestration rates vary over time period and with different technology and policy scenarios. The combined contribution of terrestrial sequestration over the next century ranges from 31 to 41 GtC. The contribution of terrestrial sequestration to mitigation is highest early in the century, reaching up to 20% of total carbon mitigation. This analysis provides insight into the behavior of terrestrial carbon mitigation options in the presence and absence of climate change mitigation policies.

Thomson, Allison M.; Izaurralde, R Cesar; Smith, Steven J.; Clarke, Leon E.

2008-02-01T23:59:59.000Z

408

Atmospheric Radiation Measurement Program facilities newsletter, July 2001.  

Science Conference Proceedings (OSTI)

Global Warming and Methane--Global warming, an increase in Earth's near-surface temperature, is believed to result from the buildup of what scientists refer to as ''greenhouse gases.'' These gases include water vapor, carbon dioxide, methane, nitrous oxide, ozone, perfluorocarbons, hydrofluoro-carbons, and sulfur hexafluoride. Greenhouse gases can absorb outgoing infrared (heat) radiation and re-emit it back to Earth, warming the surface. Thus, these gases act like the glass of a greenhouse enclosure, trapping infrared radiation inside and warming the space. One of the more important greenhouse gases is the naturally occurring hydrocarbon methane. Methane, a primary component of natural gas, is the second most important contributor to the greenhouse effect (after carbon dioxide). Natural sources of methane include wetlands, fossil sources, termites, oceans, fresh-waters, and non-wetland soils. Methane is also produced by human-related (or anthropogenic) activities such as fossil fuel production, coal mining, rice cultivation, biomass burning, water treatment facilities, waste management operations and landfills, and domesticated livestock operations (Figure 1). These anthropogenic activities account for approximately 70% of the methane emissions to the atmosphere. Methane is removed naturally from the atmosphere in three ways. These methods, commonly referred to as sinks, are oxidation by chemical reaction with tropospheric hydroxyl ion, oxidation within the stratosphere, and microbial uptake by soils. In spite of their important role in removing excess methane from the atmosphere, the sinks cannot keep up with global methane production. Methane concentrations in the atmosphere have increased by 145% since 1800. Increases in atmospheric methane roughly parallel world population growth, pointing to anthropogenic sources as the cause (Figure 2). Increases in the methane concentration reduce Earth's natural cooling efficiency by trapping more of the outgoing terrestrial infrared radiation, increasing the near-surface temperature.

Holdridge, D. J.

2001-07-23T23:59:59.000Z

409

Global Distribution of Total Inorganic Carbon and Total Alkalinity below the Deepest Winter Mixed Layer Depths  

SciTech Connect

Modeling the global ocean-atmosphere carbon dioxide system is becoming increasingly important to greenhouse gas policy. These models require initialization with realistic three-dimensional (3-D) oceanic carbon fields. This report presents an approach to establishing these initial conditions from an extensive global database of ocean carbon dioxide (CO{sub 2}) system measurements and well-developed interpolation methods.

Goyet, C.; Healy, R.; Ryan, J.; Kozyr, A.

2000-05-01T23:59:59.000Z

410

Carbon capture and storage in geologic formations has been proposed as a global warming mitigation strategy  

E-Print Network (OSTI)

Abstract Carbon capture and storage in geologic formations has been proposed as a global warming mitigation strategy that can contribute to stabilize the atmospheric concentration of carbon dioxide to maintain adsorbed methane in the coalbed formation. But now carbon dioxide will replace the methane

Mohaghegh, Shahab

411

The Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Cycle Print E-mail U.S. Carbon Cycle Science Program U.S. Carbon Cycle Science Program The U.S. Carbon Cycle Science Program, in consultation with the Carbon Cycle...

412

EMSL: Science: Atmospheric Aerosol Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Aerosol Systems Atmospheric Aerosol Systems atmospheric logo Nighttime enhancement of nitrogen-containing organic compounds, or NOC Observed nighttime enhancement of nitrogen-containing organic compounds, or NOC, showed evidence of being formed by reactions that transform carbonyls into imines. The Atmospheric Aerosol Systems Science Theme focuses on understanding the chemistry, physics and molecular-scale dynamics of aerosols for model parameterization to improve the accuracy of climate model simulations and develop a predictive understanding of climate. By elucidating the role of natural and anthropogenic regional and global climate forcing mechanisms, EMSL can provide DOE and others with the ability to develop cost-effective strategies to monitor, control and mitigate them.

413

Carbon-13 Isotopic Abundance and Concentration of Atmospheric...  

NLE Websites -- All DOE Office Websites (Extended Search)

and 35 from the Southern Hemisphere. The air samples were collected mostly in rural or marine locations remote from large sources of CH4 and are considered representative...

414

Short-Range Atmospheric Dispersion of Carbon Dioxide  

E-Print Network (OSTI)

layer model for heavy gas dispersion from natural sources:data to analyze dense gas dispersion modeling issues. Atmosforum (perf) dense gas dispersion modeling project. Atmos

Cortis, Andrea; Oldenburg, Curtis M.

2009-01-01T23:59:59.000Z

415

Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

David a. Lang David a. Lang Project Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-4881 david.lang@netl.doe.gov andrew chizmeshya Arizona State University Center for Solid State Science Tempe, AZ 85287-1704 480-965-6072 chizmesh@asu.edu A Novel ApproAch to MiNerAl cArboNAtioN: eNhANciNg cArboNAtioN While AvoidiNg MiNerAl pretreAtMeNt process cost Background Carbonation of the widely occurring minerals of the olivine group, such as forsterite (Mg 2 SiO 4 ), is a potential large-scale sequestration process that converts CO 2 into the environmentally benign mineral magnesite (MgCO 3 ). Because the process is exothermic, it inherently offers low-cost potential. Enhancing carbonation reactivity is the key to economic viability. Previous

416

Soiling by atmospheric aerosols in an urban industrial area  

Science Conference Proceedings (OSTI)

The gradual and progressive soiling of structures exposed to the atmosphere is commonplace. Material soiling results from the deposition of atmospheric aerosols. Both wet and dry deposition occurs. The particle size and the orientation, exposure and roughness of the surface determine the dominant deposition mechanisms. Wet deposition is not an important cause of surface soiling, but precipitation removes particles from a surface. Aged atmospheric particles are characterized by a bimodal size distribution of coarse and fine particles. Coarse particles tend to be inactive chemically and are removed by washout and runoff. A primary cause of building soiling in urban areas has been attributed to the fine-particle mode. When fine particles contain carbon they tend to be black, and adhere more tenaciously to surface than do course particles. Elemental carbon is usually 10-20 percent of the urban fine aerosol mass, and vehicular emissions, particularly diesel emissions, are the major source of urban black smoke. The soiling of buildings occurs over the years from fine particle deposition and is associated with low atmospheric concentrations. This paper describes the influences of particle size and rainfall on the deposition, and on the soiling of surfaces with different surface glosses, orientations and exposures.

Creighton, P.J. (Rutgers: The State Univ., New Brunswick, NJ (USA)); Lioy, P.J. (Environmental and Occupational Health Sciences Inst., Piscataway, NJ (USA)); Haynie, F.H.; Lemmons, T.J.; Miller, J.L.; Gerhart, J. (Environmental Protection Agency, Research Triangle Park, NC (USA))

1990-08-01T23:59:59.000Z

417

Dynamics of nitrogen and greenhouse gas emission under elevated carbon dioxide in semi-arid cropping systems in Australia and China.  

E-Print Network (OSTI)

??Within less than 50 years, atmospheric carbon dioxide concentration [CO2] will likely be double that observed in 1950. In this higher [CO2] world the sustainability… (more)

Lam, Shu Kee

2012-01-01T23:59:59.000Z

418

Canada, carbon dioxide and the greenhouse effect  

SciTech Connect

One of the major contributors to the greenhouse effect is carbon dioxide from the combustion of fossil fuels such as coal, oil, and natural gas. Even with its low population density, Canada, on a per capita basis, has the dubious distinction of being the world's fourth largest producer of carbon from carbon dioxide. This paper considers the impact of Canadian carbon dioxide emissions on the greenhouse effect in light of the 1988 Conference on the Changing Atmosphere's recommendations. A computer model has been developed that, when using anticipated Canadian fossil fuel demands, shows that unless steps are taken immediately, Canada will not be able to meet the conference's proposed carbon dioxide reduction of 20 percent of 1988 levels by the year 2005, let alone meet any more substantial cuts that may be required in the future.

Hughes, L.; Scott, S. (Dept. of Mathematics and Computing Science, Saint Mary' s Univ., Halifax, Nova Scotia B3H 3C3 (CA))

1991-01-01T23:59:59.000Z

419

ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC  

E-Print Network (OSTI)

ELSEVIER AtmosphericResearch 38 (1995) 207-235 ATMOSPHERIC RESEARCH On the parameterization of ice and water substance mixing ratio fields were only strongly altered by turning off the ice phase of these schemes includes ice processes. But in mid- latitudes and also in tropics the ice phase is an important

Moelders, Nicole

420

Atmospheric Corrosion Test Sites  

Science Conference Proceedings (OSTI)

Table 27   Some marine-atmospheric corrosion test sites around the world...Zealand Phia Marine 0.2 0.12 15.8 2.4 � � � � Greece Rafina Marine 0.2 0.12 13.6 1.0 � � � � Rhodes Marine 0.2 0.12 14.3 1.5 � � � � Netherlands Schagen Marine 2.4 1.5 17.0 2.0 � � � � Spain Almeria � 0.035 0.022 22.4 1.6 � � � � Cartagena � 0.050 0.031 5.2 1.9 � � � � La Coruña � 0.160 0.1 26.2 1.4...

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

CDIAC::Carbon Emission::Introduction  

NLE Websites -- All DOE Office Websites (Extended Search)

Introduction Introduction Each year the Carbon Dioxide Information Analysis Center (CDIAC) generates estimates of carbon releases from fossil-fuel consumption and cement production. Emissions from fossil-fuel burning represent the largest anthropogenic source of carbon to the atmosphere and are an important contributor to elevated atmospheric CO2 levels. CDIAC produces annual fossil-fuel CO2 emission time series at global and national scales and these time series serve as building blocks for other data products including gridded (1 x 1) emission time series. Details regarding the methods used to produce these time series and data products may be found on the CDIAC website. This new interface allows users to query, visualize, and download the latest CDIAC fossil-fuel CO2 emission estimates. In the future, additional

422

Traffic-related air pollution exposures and changes in heart rate variability in Mexico City: A panel study  

E-Print Network (OSTI)

related pollutants including PM 2.5 , carbon dioxide (COparticles; CO 2 : Carbon dioxide; CO: Carbon monoxide; HF:2 ), carbon monoxide (CO), nitrogen dioxide (NO 2 ),

2013-01-01T23:59:59.000Z

423

Internal energy and parameters of the order-disorder phase transition in titanium monoxide TiO{sub y}  

Science Conference Proceedings (OSTI)

Quantum-mechanical ab initio calculations are used to simulate the free energy functions for titanium monoxide TiO{sub y}. The effect of the long-range order of the Ti{sub 5}O{sub 5} type superstructure on the internal energy of the compound is studied by the supercell method. The dependences of the configuration entropy and free energy on the long-range order parameter are determined. It is found that the order-disorder phase transition in titanium monoxide must occur in accordance with the mechanism of the first-order phase transition with a critical value of the long-range order parameter of 0.971. The calculated parameters of the phase transition are compared with the experimental data and the results obtained using the model of point charges and by calculating the Madelung energy. It is concluded that the short-range order and the phonon entropy must be taken into account in calculating the equilibrium phase diagrams for strongly nonstoichiometric compounds.

Kostenko, M. G.; Rempel, A. A., E-mail: rempel@ihim.uran.ru [Russian Academy of Sciences, Institute of Solid-State Chemistry, Ural Branch (Russian Federation); Lukoyanov, A. V. [Ural Federal University (Russian Federation)

2013-06-15T23:59:59.000Z

424

Carbon Dioxide: Threat or Opportunity?  

E-Print Network (OSTI)

Over the past century, fossil fuel consumption has added carbon dioxide to the atmosphere at rapidly increasing rates. The prospect of further acceleration of this rate by turning from petroleum to coal has alarmed climatologists because of possible catastrophic long term effects on world climate. An alternative to discharging carbon dioxide into the atmosphere is to find new uses. One possible use is in 'Biofactories'. Biofactories may be achieved by exploiting two new developing technologies: Solar (Photosynthesis) energy, and genetic engineering. Some exciting new developments in genetic engineering will be touched on together with established bio-engineering-aquaculture, hydroponics, yeast, pharmaceutical production, fermentation, single cell protein, etc. A 'bio-factory' will be described, with a feed stream of carbon dioxide, water, nutrients containing sulfur, nitrogen, phosphorus and trace elements, and living culture interacting with light under controlled conditions to yield food and raw materials. Candidate products will be suggested and a few of the problems anticipated. Engineering and logistic requirements will be outlined and the economic impact assessed.

McKinney, A. R.

1982-01-01T23:59:59.000Z

425

Atmospheric Radiation Measurement (ARM) Climate Research Facility and Atmospheric  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Radiation Measurement (ARM) Atmospheric Radiation Measurement (ARM) Climate Research Facility and Atmospheric System Research (ASR) Science and Infrastructure Steering Committee CHARTER June 2012 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not

426

Estimated Annual Net Change in Soil Carbon per US County  

NLE Websites -- All DOE Office Websites (Extended Search)

Estimated Annual Net Change in Soil Carbon per US County These data represent the estimated net change (Megagram per year) in soil carbon due to changes in the crop type and tillage intensity. Estimated accumulation of soil carbon under Conservation Reserve Program (CRP)lands is included in these estimates. Negative values represent a net flux from the atmosphere to the soil; positive values represent a net flux from the soil to the atmosphere. As such, soil carbon sequestration is represented here as a negative value. The method of analysis is based on empirical relationshipsbetween land management and soil carbon. The method for modeling land management and estimating soil carbonchange, used to generate these data, is described in the following publication:

427

Microbial Sequestration of Carbon Dioxide and Subsequent Conversion to Methane  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration of Carbon Dioxide and Subsequent Sequestration of Carbon Dioxide and Subsequent conversion to Methane By Nirupam Pal Associate Professor California Polytechnic State University San Luis Obispo, CA 93401 Email : npal@calpoly.edu Phone : (805) 756-1355 INTRODUCTION The rising level of carbon dioxide in the atmosphere has been of growing concern in recent years. The increasing levels of carbon dioxide, the most dominant component of greenhouse gases, contribute to global warming and changing global weather patterns which could potentially lead to catastrophic events that could threaten life in every form on this planet. The level of carbon dioxide in the worlds atmosphere has increased from about 280 ppm in 1850 to the current level of approximately 350 ppm. There are several natural sources and sinks of

428

Modelling interactions of carbon dioxide, forests, and climate  

SciTech Connect

Atmospheric carbon dioxide is rising and forests and climate is changing! This combination of fact and premise may be evaluated at a range of temporal and spatial scales with the aid of computer simulators describing the interrelationships between forest vegetation, litter and soil characteristics, and appropriate meteorological variables. Some insights on the effects of climate on the transfers of carbon and the converse effect of carbon transfer on climate are discussed as a basis for assessing the significance of feedbacks between vegetation and climate under conditions of rising atmospheric carbon dioxide. Three main classes of forest models are reviewed. These are physiologically-based models, forest succession simulators based on the JABOWA model, and ecosystem-carbon budget models that use compartment transfer rates with empirically estimated coefficients. Some regression modeling approaches are also outlined. Energy budget models applied to forests and grasslands are also reviewed. This review presents examples of forest models; a comprehensive discussion of all available models is not undertaken.

Luxmoore, R.J. [Oak Ridge National Lab., TN (United States); Baldocchi, D.D. [National Oceanic and Atmospheric Administration, Oak Ridge, TN (United States)

1994-09-01T23:59:59.000Z

429

Carbon dioxide effects research and assessment program  

Science Conference Proceedings (OSTI)

Information about the past and present concentrations of CO/sub 2/ in the atmosphere and variations in climate can be obtained from measurements of stable isotopes in tree rings; specifically carbon-13, oxygen-18 and deuterium. The analysis of these stable isotopes in tree rings is a relatively new and rapidly developing field. This proceedings volume contains most of the papers presented at the meeting. The first paper gives an overview of the status of carbon-13 research. Papers relating to carbon-13 are in section I and grouped separately from the contributions on carbon-14. Although the meeting was primarily concerned with stable isotopes, all carbon isotopic analysis may be helpful in understanding the carbon-13 record in tree rings. The papers on hydrogen and oxygen isotope studies are in sections II and III respectively. The remaining sections contain papers that consider more than one isotope at a time, general topics related to isotopes, atmospheric changes and tree growth, and methods of isotopic analysis.

Jacoby, G. (ed.)

1980-12-01T23:59:59.000Z

430

Carbon supercapacitors  

SciTech Connect

Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

Delnick, F.M.

1993-11-01T23:59:59.000Z

431

Carbon particles  

DOE Patents (OSTI)

A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

Hunt, Arlon J. (Oakland, CA)

1984-01-01T23:59:59.000Z

432

carbon sequestration via direct injection  

NLE Websites -- All DOE Office Websites (Extended Search)

SEQUESTRATION VIA DIRECT INJECTION SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams INTRODUCTION The build-up of carbon dioxide (CO 2 ) and other greenhouse gases in the Earth's atmosphere has caused concern about possible global climate change. As a result, international negotiations have produced the Framework Convention on Climate Change (FCCC), completed during the 1992 Earth Summit in Rio de Janeiro. The treaty, which the United States has ratified, calls for the "stabilization of greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system." The primary greenhouse gas is CO 2 , which is estimated to contribute to over two-thirds of any climate change. The primary source of CO

433

NETL: Carbon Dioxide 101 FAQs  

NLE Websites -- All DOE Office Websites (Extended Search)

is the greenhouse effect? is the greenhouse effect? Greenhouse Effect Greenhouse Effect The greenhouse effect is used to describe the phenomenon whereby the Earth's atmosphere traps solar radiation, caused by the presence of gases, such as carbon dioxide (CO2), methane (CH4), and water vapor (H2O), in the atmosphere that allow incoming sunlight to pass through but absorb heat radiated back from the Earth's surface, resulting in higher temperatures. The greenhouse effect gets its name from what actually happens in a greenhouse. In a greenhouse, short wavelength visible sunlight shines through the glass panes and warms the air and the plants inside. The radiation emitted from the heated objects is of longer wavelength and is unable to pass through the glass barrier, maintaining a warm temperature

434

Carbon microtubes  

DOE Patents (OSTI)

A carbon microtube comprising a hollow, substantially tubular structure having a porous wall, wherein the microtube has a diameter of from about 10 .mu.m to about 150 .mu.m, and a density of less than 20 mg/cm.sup.3. Also described is a carbon microtube, having a diameter of at least 10 .mu.m and comprising a hollow, substantially tubular structure having a porous wall, wherein the porous wall comprises a plurality of voids, said voids substantially parallel to the length of the microtube, and defined by an inner surface, an outer surface, and a shared surface separating two adjacent voids.

Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

2011-06-14T23:59:59.000Z

435

Mountain Forces and the Atmospheric Energy Budget  

Science Conference Proceedings (OSTI)

Although mountains are generally thought to exert forces on the atmosphere, the related transfers of energy between earth and atmosphere are not represented in standard energy equations of the atmosphere. It is shown that the axial rotation of the ...

Joseph Egger

2011-11-01T23:59:59.000Z

436

Baiu rainband termination in atmospheric and atmosphere-ocean models  

Science Conference Proceedings (OSTI)

Baiu rainband is a summer rainband stretching from eastern China through Japan towards the Northwest Pacific. The climatological termination of the Baiu rainband is investigated using Japanese 25-year ReAnalysis (JRA25), a stand-alone atmospheric ...

Akira Kuwano-Yoshida; Bunmei Taguchi; Shang-Ping Xie

437

Atmospheric System Research (ASR) Program | U.S. DOE Office of Science (SC)  

NLE Websites -- All DOE Office Websites (Extended Search)

» Atmospheric System Research (ASR) » Atmospheric System Research (ASR) Program Biological and Environmental Research (BER) BER Home About Research Research Abstracts Searchable Archive of BER Highlights External link Biological Systems Science Division (BSSD) Climate and Environmental Sciences Division (CESD) ARM Climate Research Facility Atmospheric System Research (ASR) Program Data Management Earth System Modeling (ESM) Program William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) Integrated Assessment of Global Climate Change Regional & Global Climate Modeling (RGCM) Program Subsurface Biogeochemical Research Terrestrial Carbon Sequestration External link Terrestrial Ecosystem Science Facilities Science Highlights Benefits of BER Funding Opportunities Biological & Environmental Research Advisory Committee (BERAC)

438

Krypton-85 in the atmosphere  

E-Print Network (OSTI)

Measurement results are presented on 85Kr content in the atmosphere over the European part of Russia in 1971-1995 based on the analysis of the commercial krypton, which is separated from air by industrial plants. Our results are by 15 per cent lower then 85Kr activites observed over West Europe. According our prediction by 2030 85Kr content in the atmosphere over Europe will amount to 1,5-3 Bq in m3 air. Average 85Kr release to the atmosphere from regeneration of spent nuclear fuel (SNF) is estimated, some 180 TBq per a ton SNF. It is advisable to recommence monitoring of 85Kr content within Russia.

A. T. Korsakov; E. G. Tertyshnik

2013-07-09T23:59:59.000Z

439

Krypton-85 in the atmosphere  

E-Print Network (OSTI)

Measurement results are presented on 85Kr content in the atmosphere over the European part of Russia in 1971-1995 based on the analysis of the commercial krypton, which is separated from air by industrial plants. Our results are by 15 per cent lower then 85Kr activites observed over West Europe. According our prediction by 2030 85Kr content in the atmosphere over Europe will amount to 1,5-3 Bq in m3 air. Average 85Kr release to the atmosphere from regeneration of spent nuclear fuel (SNF) is estimated, some 180 TBq per a ton SNF. It is advisable to recommence monitoring of 85Kr content within Russia.

Korsakov, A T

2013-01-01T23:59:59.000Z

440

Stability and phase evolution of mullite in reducing atmosphere  

Science Conference Proceedings (OSTI)

The aim of this study is to investigate the stability of mullite and its phase evolution when heated at 1600-1650 deg. C in reducing atmosphere created by a carbon bed. The stoichiometric mullite (3Al{sub 2}O{sub 3}.2SiO{sub 2}) was synthesized by reacting the proper precursors at 1400 deg. C in air atmosphere. Samples containing the primary mullite and graphite or carbon were prepared by pressing the mix and heated at 1600-1650 deg. C. Products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that the stoichiometric mullite could decompose to corundum and alumina-rich mullite. During firing under reducing atmosphere, the stoichiometric mullite became richer in Al{sup 3+} cations. The gaseous SiO compound was found to be released from the sample and reacting with C to form SiC phase. Comparison of general mullite solid solution (Al{sub 4+2x}Si{sub 2-2x}O{sub 10-x}) with alumina-rich mullite obtained from decomposition revealed that x would take different values depending on temperature and atmosphere. The ultimate decomposition product was found to be corundum. - Research Highlights: {yields} This method is a new route for investigation of thermochemical stability of stoichimetric mullite under reducing condition which have done by the authors. {yields} This research has got very good results for stability of mullite at different conditions. {yields} This work has also studied the mechanism of stability of mullite under reducing atmosphere.

Naghizadeh, R., E-mail: rnaghizadeh@iust.ac.ir; Golestani-fard, F.; Rezaie, H.R.

2011-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "atmospheric carbon monoxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

One strategy for estimating the potential soil carbon storage due to CO{sub 2} fertilization  

SciTech Connect

Soil radiocarbon measurements can be used to estimate soil carbon turnover rates and inventories. A labile component of soil carbon has the potential to respond to perturbations such as CO{sub 2} fertilization, changing climate, and changing land use. Soil carbon has influenced past and present atmospheric CO{sub 2} levels and will influence future levels. A model is used to calculate the amount of additional carbon stored in soil because of CO{sub 2} fertilization.

Harrison, K.G. [Oak Ridge National Lab., TN (United States); Bonani, G. [Eidgenoessische Technische Hochschule, Zurich (Switzerland). Inst. fuer Mittelenergiephysik

1994-06-01T23:59:59.000Z

442

Energy Storage: Breakthrough in Battery Technologies (Carbon Cycle 2.0)  

DOE Green Energy (OSTI)

Nitash Balsara speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 2, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

Balsara, Nitash

2010-02-04T23:59:59.000Z

443

Glossary Term - Composition of the Earth's Atmosphere  

NLE Websites -- All DOE Office Websites (Extended Search)

the Earth's Atmosphere Source: Definition of the U.S. Standard Atmosphere (1976) CRC Handbook of Chemistry and Physics, 77th Edition Gas Formula Abundance percent by volume...

444

A Computational Thermodynamic Analysis of Atmospheric ...  

Science Conference Proceedings (OSTI)

Feb 1, 2001 ... The vacuum atmosphere is typically 0.1 atm. However, the vacuum atmosphere creates two major problems: air leakage and batch operation to ...

445

Low Cost Solar Energy Conversion (Carbon Cycle 2.0)  

DOE Green Energy (OSTI)

Ramamoorthy Ramesh from LBNL's Materials Science Division speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 2, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

Ramesh, Ramamoorthy

2010-02-04T23:59:59.000Z

446

Reductive Sequestration of Carbon Dioxide  

NLE Websites -- All DOE Office Websites (Extended Search)

Reductive Sequestration of Carbon Dioxide Reductive Sequestration of Carbon Dioxide T. Mill (ted.mill@sri.com; 650-859-3605) SRI, PS273 333 Ravenswood Menlo Park, CA 94025 D. Ross (dsross3@yahoo.com; 650-327-3842) U.S. Geological Survey, Bldg 15 MS 999 345 Middlefield Rd. Menlo Park, CA 94025 Introduction The United States currently meets 80% of its energy needs by burning fossil fuels to form CO 2 . The combustion-based production of CO 2 has evolved into a major environmental challenge that extends beyond national borders and the issue has become as politically charged as it is technologically demanding. Whereas CO 2 levels in the atmosphere had remained stable over the 10,000 years preceeding the industrial revolution, that event initiated rapid growth in CO 2 levels over the past 150 years (Stevens, 2000). The resulting accelerating accumulation of

447

IEP - Carbon Dioxide: Regulatory Drivers  

NLE Websites -- All DOE Office Websites (Extended Search)

IEP - Carbon Dioxide (CO2) Regulatory Drivers In July 7, 2009 testimony before the U.S. Senate Committee on Environment and Public Works, Secretary of Energy Steven Chu made the following statements:1 "...Overwhelming scientific evidence shows that carbon dioxide from human activity has increased the atmospheric level of CO2 by roughly 40 percent, a level one- third higher than any time in the last 800,000 years. There is also a consensus that CO2 and other greenhouse gas emissions have caused our planet to change. Already, we have seen the loss of about half of the summer arctic polar ice cap since the 1950s, a dramatically accelerating rise in sea level, and the loss of over two thousand cubic miles of glacial ice, not on geological time scales but over a mere hundred years.

448

The Workshop in Atmospheric Predictability  

Science Conference Proceedings (OSTI)

A workshop on the subject of atmospheric predictability was held during 23-25 April 2001 at the Naval Postgraduate School in Monterey, California. Of primary concern was the nature of forecast uncertainty due to initial conditionuncertainty of ...

Ronald M. Errico; Rolf Langland; David P. Baumhefner

2002-09-01T23:59:59.000Z

449

Precursors to atmospheric blocking events  

E-Print Network (OSTI)

Atmospheric blocking events disturb synoptic-scale features from their normal eastward progression, causing anomalous weather conditions for the duration of the blocking event. The essence of blocking can be captured by ...

Marino, Garrett P

2009-01-01T23:59:59.000Z

450

Automated Measurements of Atmospheric Visibility  

Science Conference Proceedings (OSTI)

The concept of using a solid-state, linear-array imaging device coupled with computerized scene analysis and display to measure daytime atmospheric visibility is described. Computer software is implemented for routine conversion of observed ...

W. Viezee; W. E. Evans

1983-08-01T23:59:59.000Z

451

The Navy's Operational Atmospheric Analysis  

Science Conference Proceedings (OSTI)

In January of 1988, significant upgrades were made to the Navy Operational Global Atmospheric Prediction System (NOGAPS). Among these improvements was the implementation of a multivariate optimum interpolation analysis scheme. Since that time, ...

James S. Goerss; Patricia A. Phoebus

1992-06-01T23:59:59.000Z

452

Stochastic Simulation of Atmospheric Trajectories  

Science Conference Proceedings (OSTI)

Methods are presented for generating an ensemble of synthetic atmospheric trajectories. These include methods for a set of independent trajectories, and methods for a correlated set of sequential trajectories. The models incorporate first-order ...

Mitchell J. Small; Perry J. Samson

1983-02-01T23:59:59.000Z

453

Atmospheric Water Vapor over China  

Science Conference Proceedings (OSTI)

Chinese radiosonde data from 1970 to 1990 are relatively homogeneous in time and are used to examine the climatology, trends, and variability of China’s atmospheric water vapor content. The climatological distribution of precipitable water (PW) ...

Panmao Zhai; Robert E. Eskridge

1997-10-01T23:59:59.000Z

454

Carbon | Open Energy Information  

Open Energy Info (EERE)

Carbon Sector Retrieved from "http:en.openei.orgwindex.php?titleCarbon&oldid271960" Categories: Articles with outstanding TODO tasks...

455

Chemical sensing and imaging in microfluidic pore network structures relevant to natural carbon cycling and industrial carbon sequestration  

SciTech Connect

Energy and climate change represent significant factors in global security. Atmospheric carbon dioxide levels, while global in scope, are influenced by pore-scale phenomena in the subsurface. We are developing tools to visualize and investigate processes in pore network microfluidic structures with transparent covers as representations of normally-opaque porous media. In situ fluorescent oxygen sensing methods and fluorescent cellulosic materials are being used to investigate processes related to terrestrial carbon cycling involving cellulytic respiring microorganisms. These structures also enable visualization of water displacement from pore spaces by hydrophobic fluids, including carbon dioxide, in studies related to carbon sequestration.

Grate, Jay W.; Zhang, Changyong; Wilkins, Michael J.; Warner, Marvin G.; Anheier, Norman C.; Suter, Jonathan D.; Kelly, Ryan T.; Oostrom, Martinus

2013-06-11T23:59:59.000Z

456

North America carbon dioxide sources and sinks: magnitude, attribution, and uncertainty  

SciTech Connect

North America is both a source and sink of atmospheric CO2. Sources, predominately fossil-fuel combustion in the United States along with contributions from deforestation in Mexico, add CO2 to the atmosphere. Most North America ecosystems, particularly regrowing forests in the United States, are sinks for atmospheric CO2. CO2 is removed from the atmosphere in photosynthesis, converted into biomass and stored as carbon in vegetation, soil and wood products. Fossil-fuel emissions dominate the North American source-sink balance. North America is a net source of atmospheric CO2 with ecosystem sinks balancing approximately 35% of fossil-fuel CO2 emissions from North America.

King, Anthony W.; Hayes, Daniel J.; Huntzinger, Deborah N.; West, Tristram O.; Post, W. M.

2012-12-01T23:59:59.000Z

457

ChEAS Data: The Chequamegon Ecosystem Atmosphere Study  

DOE Data Explorer (OSTI)

The ChEAS flux towers participate in AmeriFlux, and the region is an EOS-validation site. The WLEF tower is a NOAA-CMDL CO2 sampling site. ChEAS sites are primarily located within or near the Chequamegon-Nicolet National Forest in northern Wisconsin, with one site in the Ottawa National Forest in the upper peninsula of Michigan. Current studies observe forest/atmosphere exchange of carbon dioxide at canopy and regional scales, forest floor respiration, photosynthesis and transpiration at the leaf level and use models to scale to canopy and regional levels. EOS-validation studies quantitatively assess the land cover of the area using remote sensing and conduct extensive ground truthing of new remote sensing data (i.e. ASTER and MODIS). Atmospheric remote sensing work is aimed at understanding atmospheric boundary layer dynamics, the role of entrainment in regulating the carbon dioxide mixing ratio profiles through the lower troposphere, and feedback between boundary layer dynamics and vegetation (especially via the hydrologic cycle). Airborne studies have included include balloon, kite and aircraft observations of the CO2 profile in the troposphere.

Davis, Kenneth J. [Penn State

458

Carbon Additionality: Discussion Paper  

E-Print Network (OSTI)

Carbon Additionality: A review Discussion Paper Gregory Valatin November 2009 Forest Research. Voluntary Carbon Standards American Carbon Registry Forest Carbon Project Standard (ACRFCPS) 27 CarbonFix Standard (CFS) 28 Climate, Community and Biodiversity Standard (CCBS) 28 Forest Carbon Standard (FCS) 28

459

The Predictive Uncertainty of Land Surface Fluxes in Response to Increasing Ambient Carbon Dioxide  

Science Conference Proceedings (OSTI)

The exchange of water vapor and carbon dioxide (CO2) between the land surface and the atmosphere plays an important role in numerical weather forecasting and climate change prediction using general circulation models. In this study, a typical ...

Karsten Schulz; Andrew Jarvis; Keith Beven; Henrik Soegaard

2001-06-01T23:59:59.000Z

460

Uncertainties in CMIP5 climate projections due to carbon cycle feedbacks  

Science Conference Proceedings (OSTI)

In the context of Coupled Model Intercomparison Project phase 5, most climate simulations use prescribed atmospheric CO2 concentration and therefore do not interactively include the effect of carbon cycle feedbacks. However, the RCP8.5 scenario ...

Pierre Friedlingstein; Malte Meinshausen; Vivek K. Arora; Chris D. Jones; Alessandro Anav; Spencer K. Liddicoat; Reto Knutti

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to obtain the most current and comprehensive results.


461

Carbonate clumped isotope compositions of modern marine mollusk and brachiopod shells  

E-Print Network (OSTI)

, leaving the oxygen isotope paleother- mometer underdetermined in most geologic applicationsCarbonate clumped isotope compositions of modern marine mollusk and brachiopod shells Gregory A, Baltimore, MD 21218, USA b Department of Geological & Atmospheric Sciences, Iowa State University, Ames, IA

Grossman, Ethan L.

462

Feedbacks in Emission-Driven and Concentration-Driven Global Carbon Budgets  

Science Conference Proceedings (OSTI)

Emissions of CO2 into the atmosphere affect the carbon budgets of the land and ocean as biogeochemical processes react to increased CO2 concentrations. Biogeochemical processes also react to changes in temperature and other climate parameters. ...

G. J. Boer; V. K. Arora

2013-05-01T23:59:59.000Z

463

IA-SDSS: A GIS-based land use decision support system with consideration of carbon sequestration  

Science Conference Proceedings (OSTI)

Land use, land use change and forestry (LULUCF) can play a positive role in mitigating global warming by sequestering carbon from the atmosphere into vegetation and soils. Local entities (e.g. local government, community, stockholders) have been making ... Keywords: Carbon models, Carbon sequestration, GIS, Integrated assessment, Land-use planning, RS, SDSS

Jun Wang; Jingming Chen; Weimin Ju; Manchun Li

2010-04-01T23:59:59.000Z

464

Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Technology Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 412-386-4966 jose.figueroa@netl.doe.gov Kevin o'Brien Principal Investigator SRI International Materials Research Laboratory 333 Ravenswood Avenue Menlo Park, AK 94025 650-859-3528 kevin.obrien@sri.com Fabrication and Scale-Up oF polybenzimidazole - baSed membrane SyStem For pre - combUStion captUre oF carbon dioxide Background In order to effectively sequester carbon dioxide (CO 2 ) from a gasification plant, there must be an economically viable method for removing the CO 2 from other gases. While CO 2 separation technologies currently exist, their effectiveness is limited. Amine-based separation technologies work only at low temperatures, while pressure-swing absorption and cryogenic distillation consume significantly

465

Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

andrea Mcnemar andrea Mcnemar National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 304-285-2024 andrea.mcnemar@netl.doe.gov Gregory J. Elbring Principal Investigator Sandia National Laboratory P.O. Box 5800 Albuquerque, NM 87185 505-844-4904 gjelbri@sandia.gov GeoloGic SequeStration of carbon DioxiDe in a DepleteD oil reServoir: a comprehenSive moDelinG anD Site monitorinG project Background The use of carbon dioxide (CO 2 ) to enhance oil recovery (EOR) is a familiar and frequently used technique in the United States. The oil and gas industry has significant experience with well drilling and injecting CO 2 into oil-bearing formations to enhance production. While using similar techniques as in oil production, this sequestration field

466

Continuous, Non-Invasive, In-Field Soil Carbon Scanning System  

NLE Websites -- All DOE Office Websites (Extended Search)

Continuous, non-invasive, in-Field soil Continuous, non-invasive, in-Field soil Carbon sCanning system Background Vegetation and soils serve as carbon storage sinks for the approximately 2 billion tons of carbon absorbed annually by the global biosphere. While global warming is promoted by anthropogenic carbon dioxide (CO 2 ) emissions into the atmosphere, it is partially mitigated by carbon sequestration in the terrestrial ecosystem. However, a better understanding and monitoring of the underground carbon processes is necessary for evaluating various strategies for terrestrial carbon sequestration and quantification of the carbon stores for carbon credits. Description Brookhaven National Laboratory (BNL) has developed a multi-elemental scanning instrument for determining carbon analysis in soil. The method is based on inelastic

467

Carbon-14 Dose Calculation Methods at Nuclear Power Plants  

Science Conference Proceedings (OSTI)

Carbon-14 (C-14) is a naturally occurring isotope of carbon produced by cosmic radiation interactions in the upper atmosphere. Nuclear weapons testing in the 1950s and 1960s significantly increased the amount of C-14 in the atmosphere. C-14 is also produced in commercial nuclear reactors, but the amounts produced are much less than those produced naturally or from weapons testing. C-14 is released through permitted effluent pathways of a nuclear power plant. This report provides the current industry best...

2012-04-26T23:59:59.000Z

468

FORMATION OF ORGANIC MOLECULES AND WATER IN WARM DISK ATMOSPHERES  

Science Conference Proceedings (OSTI)

Observations from Spitzer and ground-based infrared spectroscopy reveal significant diversity in the molecular emission from the inner few AU of T Tauri disks. We explore theoretically the possible origin of this diversity by expanding on our earlier thermal-chemical model of disk atmospheres. We consider how variations in grain settling, X-ray irradiation, accretion-related mechanical heating, and the oxygen-to-carbon ratio can affect the thermal and chemical properties of the atmosphere at 0.25-40 AU. We find that these model parameters can account for many properties of the detected molecular emission. The column density of the warm (200-2000 K) molecular atmosphere is sensitive to grain settling and the efficiency of accretion-related heating, which may account, at least in part, for the large range in molecular emission fluxes that have been observed. The dependence of the atmospheric properties on the model parameters may also help to explain trends that have been reported in the literature between molecular emission strength and mid-infrared color, stellar accretion rate, and disk mass. We discuss whether some of the differences between our model results and the observations (e.g., for water) indicate a role for vertical transport and freezeout in the disk midplane. We also discuss how planetesimal formation in the outer disk (beyond the snowline) may imprint a chemical signature on the inner few AU of the disk and speculate on possible observational tracers of this process.

Najita, Joan R. [National Optical Astronomy Observatory, 950 N. Cherry Avenue, Tucson, AZ 85719 (United States); Adamkovics, Mate; Glassgold, Alfred E. [Astronomy Department, University of California, Berkeley, CA 94720 (United States)

2011-12-20T23:59:59.000Z

469

Gasification behavior of carbon residue in bed solids of black liquor gasifier  

SciTech Connect

Steam gasification of carbon residue in bed solids of a low-temperature black liquor gasifier was studied using a thermogravimetric system at 3 bar. Complete gasification of the carbon residue, which remained unreactive at 600 C, was achieved in about 10 min as the temperature increased to 800 C. The rate of gasification and its temperature dependence were evaluated from the non-isothermal experiment results. Effects of particle size and adding H{sub 2} and CO to the gasification agent were also studied. The rate of steam gasification could be taken as zero order in carbon until 80% of carbon was gasified, and for the rest of the gasification process the rate appeared to be first order in carbon. The maximum rate of carbon conversion was around 0.003/s and the activation energy was estimated to be in the range of 230-300 kJ/mol. The particle size did not show significant effect on the rate of gasification. Hydrogen and carbon monoxide appeared to retard the onset of the gasification process. (author)

Preto, Fernando; Zhang, Xiaojie (Frank); Wang, Jinsheng [CANMET Energy Technology Centre, Natural Resources (Canada)

2008-07-15T23:59:59.000Z

470

Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions  

DOE Patents (OSTI)

A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

Huffman, Gerald P

2012-09-18T23:59:59.000Z

471

The Large Scale Biosphere-Atmosphere Experiment in Amazonia (LBA)  

NLE Websites -- All DOE Office Websites (Extended Search)

LBA (Amazon) LBA (Amazon) The Large Scale Biosphere-Atmosphere Experiment in Amazonia (LBA) Overview [LBA Logo] The Large-Scale Biosphere-Atmosphere Experiment in Amazonia (LBA) is an international research initiative conducted from 1995-2005 and led by Brazil. The LBA Project encompasses several scientific disciplines, or components. The LBA-ECO component focuses on the question: "How do tropical forest conversion, regrowth, and selective logging influence carbon storage, nutrient dynamics, trace gas fluxes, and the prospect for sustainable land use in Amazonia?" The Amazon rain forest or Amazonia, is the largest remaining expanse of tropical rain forest on Earth, harboring approximately one-third of all Earth's species. Although the rain forest's area is so large that it

472

Potential multiple steady-states in the long-term carbon cycle  

E-Print Network (OSTI)

Modelers of the long term carbon cycle in Earth history have previously assumed there is only one stable climatic steady state. Here we investigate the possibility of multiple steady states. We find them in Abiotic World, lacking any biotic influence, resulting from possible variations in planetary albedo in different temperature, atmospheric carbon dioxide level regimes, with the same weathering forcing balancing a volcanic source to the atmosphere, ocean pool. In Plant World modeling relevant to the Phanerozoic, we include the additional effects of biotic enhancement of weathering on land, organic carbon burial, oxidation of reduced organic carbon in terrestrial sediments and the variation of biotic productivity with temperature, finding a second stable steady state appearing between twenty and fifty degrees C. The very warm early Triassic climate may be the prime candidate for an upper temperature steady state. Given our results, the anthropogenic driven rise of atmospheric carbon dioxide could potentially...

Tennenbaum, Stephen; Schwartzman, David

2013-01-01T23:59:59.000Z

473

EFRC Carbon Capture and Sequestration Activities at NERSC  

NLE Websites -- All DOE Office Websites (Extended Search)

EFRC Carbon Capture and EFRC Carbon Capture and Sequestration Activities at NERSC EFRC Carbon Capture and Sequestration Activities at NERSC Why it Matters: Carbon dioxide (CO2) gas is considered to be present in only trace proportions in our atmosphere but it has a leading role in the cast of greenhouse gases, with a thermal radiative effect nearly three times as large as the next biggest contributor. Energy related processes are the biggest sources of atmospheric CO2, espec