Sample records for asphalt paving mixture

  1. Recycled rubber, aggregate, and filler in asphalt paving mixtures. Transportation research record

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    ;Contents(Partial): Evaluation Systems for Crumb Rubber Modified Binders and Mixtures; Hot Mix Asphalt Rubber Applications in Virginia; Evaluation of Pyrolized Carbon Black from Scrap Tires as Additive in Hot Mix Asphalt; Use of Scrap Tire Chips in Asphaltic Membrane; Effects of Mineral Fillers on Properties of Stone Matrix Asphalt Mixtures; and Quantitative Analysis of Aggregate Based on Hough Transform.

  2. The potential use of tar sand bitumen as paving asphalt

    SciTech Connect (OSTI)

    Petersen, J.C.

    1988-01-01T23:59:59.000Z

    In this paper several research reports describing the preparation of potential paving asphalts from tar sand bitumen are reviewed and the results of the studies compared. The tar sand asphalts described in the studies were prepared from 1) hot water-recovered bitumen from deposits near San Luis Obispo, California (Edna deposits), and deposits near Vernal and Sunnyside, Utah; and 2) bitumen recovered from the Northwest Asphalt Ridge deposits near Vernal, Utah, by both in situ steamflood and in situ combustion recovery processes. Important properties of the tar sand asphalts compare favorably with those of specification petroleum asphalts. Laboratory data suggest that some tar sand asphalts may have superior aging characteristics and produce more water-resistant paving mixtures than typical petroleum asphalts.

  3. The potential use of tar sand bitumen as paving asphalt

    SciTech Connect (OSTI)

    Petersen, J.C.

    1987-01-01T23:59:59.000Z

    The properties of several tar sand asphalts prepared in past studies by several different investigators were compared with each other and with the properties of petroleum asphalts. These results were reviewed and discussed with regard to the potential use of tar sand bitumen in pavement applications. The data show that tar sand bitumen has good potential for use in highway pavements that meet today's performance specifications. No deficiencies in the tar sand asphalts were found that would be expected to seriously affect performance. On the other hand, the data indicate that some tar sand asphalts may have superior aging characteristics, being relatively resistant to oxidative age hardening compared with typical petroleum asphalts. Asphalt-aggregate mixtures prepared using two tar sand asphalts also showed acceptable strength properties and excellent resistance to moisture-induced damage.

  4. BBR Asphalt mixture creep test BBR Asphalt mixture creep size effect

    E-Print Network [OSTI]

    Minnesota, University of

    #12;Outline ØBBR Asphalt mixture creep test ØBBR Asphalt mixture creep size effect ØBBR Asphalt Point Bending Test Low temperature 3-point bending creep tests on specimens with three different sizes mixture strength test ØBBR Asphalt binder strength test #12;Asphalt Pavements ØRecent efforts under NCHRP

  5. INTRODUCTION The increase in energy costs has led to a significant rise in the cost of mixtures containing asphalt cement. This resulted

    E-Print Network [OSTI]

    Harms, Kyle E.

    containing asphalt cement. This resulted in a need to search for alternatives that reduce the cost of those mixed with low percentages (1 percent below standard HMA mixtures) of paving grade asphalt cement and lower percentages of asphalt cement binder and easier compaction efforts. Asphalt treated mixtures can

  6. State of the practice: Design and construction of asphalt paving materials with crumb-rubber modifier. Final report

    SciTech Connect (OSTI)

    Heitzman, M.A.

    1992-05-01T23:59:59.000Z

    The document is a comprehensive overview of the terminology, processes, products, and applications of crumb rubber modifier (CRM) technology. The technology includes any use of scrap tire rubber in asphalt paving materials. In general, CRM technology can be divided into two categories--the wet process and the dry process. When CRM is incorporated into an asphalt paving material, it will modify the properties of the binder (asphalt rubber) and/or act as a rubber aggregate (rubber modified hot mix asphalt). The five concepts for using CRM discussed in the report are McDonald, PlusRide, generic dry, chunk rubber asphalt concrete, and continuous blending asphalt rubber. There are two principal unresolved engineering issues related to the use of CRM in asphalt paving materials. On the national level, the ability to recycle asphalt paving mixes containing CRM has not been demonstrated. At the State and local levels, these modified asphalt mixes must be field evaluated to establish expected levels of performance. The appendices provide guidelines for material specifications, mix design, and construction specifications. An experimental work plan for monitoring performance and a stack emission testing program are also included.

  7. Mixture design and performance prediction of rubber-modified asphalt in Ohio. Final report

    SciTech Connect (OSTI)

    Liang, R.Y.

    1997-08-01T23:59:59.000Z

    Appropriate disposal of scrap tires has been a major environmental concern over the years, mainly due to potential fire and health hazards associated with uncontrolled stockpiling. Primarily driven by this environmental concern, the Intermodal Surface Transportation Efficiency Act (ISTEA) of 1991 has required each State to begin incorporating scrap tire rubber into its asphalt paving materials. Although in the revision of the original ISTEA, the mandate has been eliminated, there remains a language of encouraging the use of crumb rubbers in asphalt paving materials. Ohio Department of Transportation (ODOT) desires to develop the mix design procedure, construction practice, and performance specifications for crumb rubber modified asphalt paving materials. This research was conducted to develop the needed design and construction guidance for meeting the ODOT anticipated needs. Specifically, the objectives of this research encompass the following scope: (1) investigation of the rheological properties of asphalt-rubber binder to determine optimum content of crumb rubber, (2) development of optimum mix design for various applications, including both wet and dry mix processes, (3) characterization of mechanical properties of recommended paving mixtures, including resilient modulus, fatigue cracking behavior, low-temperature thermal cracking resistance, water sensitivity test, incremental creep test and loaded wheel track test, and (4) comparison of performance of selected paving mixes.

  8. Laboratory evaluation of crumb rubber asphalt concrete mixtures using the concepts of SMA mixtures 

    E-Print Network [OSTI]

    Rebala, Somasekhar Reddy

    1994-01-01T23:59:59.000Z

    Eight CRM asphalt concrete mixtures were evaluated using AAMAS characterization procedures: Four wet-process mixtures and four dry-process mixtures. These mixtures were compared to a conventional dense graded mixture. It was determined that CRM has...

  9. Characterization of Fatigue Cracking and Healing of Asphalt Mixtures

    E-Print Network [OSTI]

    Luo, Xue

    2012-07-16T23:59:59.000Z

    mixtures using an energy-based mechanistic approach. A controlled-strain repeated direct tension (RDT) test is selected to generate both fatigue cracking and permanent deformation in an asphalt mixture specimen. Fatigue cracking is separated from...

  10. Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement

    E-Print Network [OSTI]

    Tong, Yunwei

    2013-11-08T23:59:59.000Z

    aggregate contact due to dust particles on the aggregate surface. The rupture may occur because of the construction loads and operating traffic during construction, or could be environmentally induced by freeze-thaw cycling. Once a break in the film... design, environment and traffic, can be defined as progressive degradation of asphalt mixture material due to the presence of water. The occurrence of moisture damage in asphalt material is a rather complex phenomenon, which involves chemical, physical...

  11. A Coupled Micromechanical Model of Moisture-Induced Damage in Asphalt Mixtures: Formulation and Applications 

    E-Print Network [OSTI]

    Caro Spinel, Silvia

    2011-02-22T23:59:59.000Z

    The deleterious effect of moisture on the structural integrity of asphalt mixtures has been recognized as one of the main causes of early deterioration of asphalt pavements. This phenomenon, usually referred to as moisture damage, is defined...

  12. Evaluation of the filler effects on fatique cracking and permanent deformation of asphalt concrete mixtures 

    E-Print Network [OSTI]

    Izzo, Richard P

    1997-01-01T23:59:59.000Z

    The addition of hydrated lime to asphalt has shown to be beneficial with an improvement in the Theological properties of the binder, as well as resistance to permanent deformation (rutting) and fatigue cracking of asphalt concrete mixtures...

  13. Evaluation of the filler effects on fatique cracking and permanent deformation of asphalt concrete mixtures

    E-Print Network [OSTI]

    Izzo, Richard P

    1997-01-01T23:59:59.000Z

    The addition of hydrated lime to asphalt has shown to be beneficial with an improvement in the Theological properties of the binder, as well as resistance to permanent deformation (rutting) and fatigue cracking of asphalt concrete mixtures...

  14. Evaluation of methods of mixing lime in bituminous paving mixtures in batch and drum plants 

    E-Print Network [OSTI]

    Button, Joseph Wade

    1984-01-01T23:59:59.000Z

    ) Joseph Wade Button, B. S. , Texas ASM University Co-Chairmen of Advisory Committee: Mr. Bob M. Gallaway and Dr. Dallas N. Little A field test was conducted to evaluate the use of hydrated lime as an antistrip additive in hot mix asphalt concrete.... Lime was added in the pugmill of the batch plant, on the cold feed belt, and through the fines feeder of the drum mix plant. The asphalt and aggregates used were characterized in the laboratory. Asphalt concrete mixture tests included laboratory...

  15. An analysis of some properties of paving asphalts in Texas as they relate to pavement performance

    E-Print Network [OSTI]

    DuBose, Emmett Haygood

    1980-01-01T23:59:59.000Z

    51 73 93 115 115 DISTRESS AND CRACKING FACTORS THE PAVEMENT PERFORMANCE SYSTEM 5 CONCLUSIONS AND RECOMMENDATIONS CONCLUSIONS RECOMMENDATIONS REFERENCES . APPENDIX A: RAW DATA APPENDIX B: PAVEMENT PERFORMANCE VS. TIME CURVES APPENDIX C... harden1ng model. It had been shown in earlier research that excessive asphalt1c concrete binder hardening was a detrimental factor influencing certain types of pavement distress such as thermal cracking, raveling, fatigue cracking, and reflective crack...

  16. Evaluation of Rexene polymers in hot mixed asphalt concrete 

    E-Print Network [OSTI]

    Rodriguez, Mary Anne Reese

    1991-01-01T23:59:59.000Z

    Committee: Dr. Dallas N. Little The objective of this research was to provide a comprehensive characterization of asphalt binders and paving mixtures modified with four polymers produced by the Rexene Products Company (Odessa, Texas). The four polymers... LITERATURE REVIEW AND INTERPRETATION General Available Asphalt Additives Practical Application of Asphalt Additives Benefit-Costs for Additives Future Outlook for Additives MATERIALS AND TEST METHODS Polymers Asphalt Cements Aggregate Procedure...

  17. The use of sulfer modified bottom ash (SMBA) as an aggregate in asphaltic mixtures

    E-Print Network [OSTI]

    Chimakurthy, Harshavardhan

    1998-01-01T23:59:59.000Z

    , bottom ash is lighter in weight and generally much cheaper than conventional quality aggregates such as limestone, sand and gravel. This research was designed to up-grade the load-bearing charactcnstics of bottom ash and maximize its usc m asphaltic... and gravel. According to a study done by Hafizuddin Ahmad in 1974, sulfur was used extensively in sand-asphalt sulfur to upgrade marginal aggregates for use in asphaltic mixtures, was developed at Texas Transportation Institute (TT1) (JO). TTI's work...

  18. Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures

    E-Print Network [OSTI]

    Vasconcelos, Kamilla L.

    2011-08-08T23:59:59.000Z

    cost in highway maintenance and vehicle operations. One key mechanism of how moisture reaches the asphalt-aggregate interface is by its permeation or diffusion through the asphalt binder or mastic. Different techniques are available for diffusion...

  19. Damage analysis in asphalt concrete mixtures based on parameter relationships 

    E-Print Network [OSTI]

    Song, Injun

    2004-11-15T23:59:59.000Z

    Asphalt pavements experience damage due to traffic loading under various environmental conditions. Damage can be caused by viscopl microcracks, fracture due to fatigue cracking, or fracture due to thermal cracking. Asphalt ...

  20. Asphalt Oxidation Kinetics and Pavement Oxidation Modeling

    E-Print Network [OSTI]

    Jin, Xin

    2012-07-16T23:59:59.000Z

    Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

  1. Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures 

    E-Print Network [OSTI]

    Vasconcelos, Kamilla L.

    2011-08-08T23:59:59.000Z

    coefficient measurement of a wide variety of polymersolvent systems. For the asphalt-water system studied, the focus is on two techniques: (i) Fourier Transform Infrared (FTIR)-Attenuated Total Reflectance (ATR) spectrometry and (ii) Gravimetric Sorption...

  2. Recycled tire rubber and other waste materials in asphalt mixtures. Transportation research record

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The papers in this volume, dealing with various facets of recycled tire rubber and other waste materials in asphalt mixtures, should be of interest to state and local construction, design, materials, and research engineers as well as contractors and material producers. In the first papers, Rebala and Estakhri, Malpass and Khosla, and Baker and Connolly describe research related to crumb rubber modified mixtures that was done for the Texas, North Carolina, and New Jersey State Departments of Transportation. Ali et al. report on their research in Canada to determine the feasibility of sing reclaimed roofing materials in hot mix asphalt pavement. Emery discusses the evaluation of 11 Ontario rubber modified demonstration projects in terms of pavement performance, environmental impacts, and recyclability. In the last paper, Fwa and Aziz report on their work in Singapore related to the use of incinerator residue in asphalt mixtures.

  3. Mirzahosseini et. al. ANN-Based Prediction Model for Rutting Propensity of Asphalt Mixtures1

    E-Print Network [OSTI]

    Fernandez, Thomas

    in a repeated load permanent deformation test.21 Dynamic creep test is one of the best tools for assessing of load cycles is the most23 important output of the dynamic creep test. This curve includes primary based on volumetric proportioning of the asphalt mixture. This method does16 not include any direct test

  4. Recycled brake linings as partial aggregate substitute in asphalt paving. Construction and final report. Report for July 1992-August 1996

    SciTech Connect (OSTI)

    Miller, P.A.; Sukley, R.

    1996-09-01T23:59:59.000Z

    The purpose of this project was to evaluate the performance of asphalt containing various percentages of brake lining as an aggregate, and compare its performance to that of normal asphalt containing natural aggregate. This project is an effort to explore alternate ways to use waste product. Four test section of FB-2 Modified mix containing brake lining materials were placed in July 1992 along with one control section on SR 3022 in Mercer county. To date all sections are performing satisfactory, and Brake linings should be recommended as a viable partial replacement of aggregate in bituminous materials. This study only considered the performance of only off-spec brake linings, therefore, any performance data or enviromental effects of placement of used brake material should be addressed.

  5. The effects of asphalt binder oxidation on hot mix asphalt concrete mixture rheology and fatigue performance

    E-Print Network [OSTI]

    Jung, Sung Hoon

    2009-06-02T23:59:59.000Z

    .................................................. 108 Figure V-11. VE Function Map of Yoakum Mixtures .............................................. 108 Figure V-12. VE Function versus DSR Function ...................................................... 110 Figure V-13. Hirsch Model from Bryan PP2... Binder................................................. 112 xiv Page Figure V-14. Comparison between Bryan Mixture PP2 and Hirsch Model. ............. 113 Figure V-15. Comparison between Yoakum Mixture PP2 and Hirsch Model.......... 114 Figure...

  6. The application of triaxial compression tests to the design of sand-asphalt paving mixtures 

    E-Print Network [OSTI]

    Ritter, Leo J

    1940-01-01T23:59:59.000Z

    of Changes in Sand. Orading upon the JLngle of Internal Friction III. Effect of the Initial Void Ratio upon ths ' ingle of Internal friction (Pine Sand. ) . . . . . . . Page 31 35 IV. Xffect oi Dust on the Angle of Internal Jriction in Sand Nixes... after Failure . . , 24 S. Nffsct of Changes in Sand. Grading on the Angle of Internal Friction . . . . . . '. . . . . . . . . . . . . . . . . 32 Relation between ths Angle of Internal Friction ank Initial Yolk Ratio (Fine Sank...

  7. The application of triaxial compression tests to the design of sand-asphalt paving mixtures

    E-Print Network [OSTI]

    Ritter, Leo J

    1940-01-01T23:59:59.000Z

    ~ort Mk e) 31 ff 1 Straia es Stress o Corrected Area . Corrected irea; ~(1 S orp-PS Al iy I ~ ' ~ ~ . ~ I:I: I ' ~, 'I:I I, ~ I . . I Sik ~~~RIJ%~ %XKmIml~~~ ~~ ~~~~KHWRRK45GRR~~ ~~RW2%%~RR%H~% ~~~~~~~RER~~~~ BK~~~RKWRRXB~ ~~~S...

  8. Comparison of fatigue analysis approaches for predicting fatigue lives of hot-mix asphalt concrete (HMAC) mixtures

    E-Print Network [OSTI]

    Walubita, Lubinda F.

    2006-08-16T23:59:59.000Z

    Hot-mix asphalt concrete (HMAC) mixture fatigue characterization constitutes a fundamental component of HMAC pavement structural design and analysis to ensure adequate field fatigue performance. HMAC is a heterogeneous complex composite material...

  9. A unified method for the analysis of nonlinear viscoelasticity and fatigue cracking of asphalt mixtures using the dynamic mechanical analyzer

    E-Print Network [OSTI]

    Castelo Branco, Veronica Teixeira Franco

    2009-05-15T23:59:59.000Z

    A UNIFIED METHOD FOR THE ANALYSIS OF NONLINEAR VISCOELASTICITY AND FATIGUE CRACKING OF ASPHALT MIXTURES USING THE DYNAMIC MECHANICAL ANALYZER A Dissertation by VERONICA TEIXEIRA FRANCO CASTELO BRANCO Submitted to the Office... VISCOELASTICITY AND FATIGUE CRACKING OF ASPHALT MIXTURES USING THE DYNAMIC MECHANICAL ANALYZER A Dissertation by VERONICA TEIXEIRA FRANCO CASTELO BRANCO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  10. A study of the effects of limestone rock asphalt screenings on the structural properties of hot-mix asphaltic concrete made with siliceous materials

    E-Print Network [OSTI]

    Albritton, Oscar Willard

    1958-01-01T23:59:59.000Z

    Society for Testing Materials, Phila. , Pa. 15 PROCEDURE To limit the wide variations of aggregate grading, specifica- tions of the Texas Highway Department for a Type "D" Hot-Mix, Hot- Laid, Asphaltic Concrete were used as a guide in the design... Standards on Mineral Aggregates, Concrete, and Nonbituminous Highway Materials, American Society for Testing Materials, Phila, , Pa. Benson, Fred J, and Bh. Subbaraju, "Specific Gravity of Aggregates in Asphaltic Paving Mixtures, " Texas Engineering...

  11. Evaluation of methods of mixing lime in bituminous paving mixtures in batch and drum plants

    E-Print Network [OSTI]

    Button, Joseph Wade

    1984-01-01T23:59:59.000Z

    prepared mixtures, field mixtures obtained at the plant and pavement cores. Laboratory tests included Hveem and Marshall stability, resilient modulus and indirect tension. Mixture conditioning to evaluate resistance to moisture damage included vacuum... Mixed and Compacted Specimens Tensile Strength Ratio for Laboratory Mixed and Compacted Specimens 14 Marshall Stability Before and After 7-days Soaking in Water for Lab Mixed and Compacted Specimens 36 FIGURE Page 15 16 Hveem Stability Before...

  12. Laboratory evaluation of crumb rubber asphalt concrete mixtures using the concepts of SMA mixtures

    E-Print Network [OSTI]

    Rebala, Somasekhar Reddy

    1994-01-01T23:59:59.000Z

    , = 60 psi (414 kpa)) for Control and Crumb-Rubber Mixtures. . . . . . . . . 42 44 74 TABLE 5. 2 Compressive Strain at Failure for CRM and Dense Graded Mixtures 104'F 80 TABLE 5. 3 Number of Repetitions to Failure for Control and Crumb...

  13. Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures

    DOE Patents [OSTI]

    Plancher, Henry (Laramie, WY); Petersen, Joseph C. (Laramie, WY)

    1982-01-01T23:59:59.000Z

    Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

  14. Waste-tire and shingle scrap/bituminous paving test sections on the Willard Munger recreational trail gateway segment. Interim report, 1990-91

    SciTech Connect (OSTI)

    Turgeon, C.M.

    1991-02-01T23:59:59.000Z

    The need to reduce our states dependence on land fills resulted in a unique cooperative venture by three state agencies. A partnership was forged between the Minnesota Pollution Control Agency (MPCA), the Minnesota Department of Natural Resources (DNR) and the Minnesota Department of Transportation (Mn/DOT) to investigate the use of recycled tire rubber and processed asphalt shingle scrap. The result is a two mile section of the Willard Munger Recreational Trail in St. Paul constructed with asphalt paving mixtures which contain varying percentages of recycled tire rubber and shingle scrap. Conventional mixing and paving equipment was utilized for construction. The application appears to be a viable alternative to landfilling these materials. However, costs for the mixtures containing rubber increased from 35% to 50% over the cost of the conventional mixture. Since the use of shingle scrap was negotiated by the private companies involved, no comparable cost data is available.

  15. A Coupled Micromechanical Model of Moisture-Induced Damage in Asphalt Mixtures: Formulation and Applications

    E-Print Network [OSTI]

    Caro Spinel, Silvia

    2011-02-22T23:59:59.000Z

    the microstructure of the mixture at different intensities and rates. Although there have been important advancements in identifying and characterizing this phenomenon, there is still a lack of understanding of the damage mechanisms occurring at the microscopic level...

  16. An evaluation of permanent deformation properties of crumb rubber modified (CRM) asphalt concrete mixtures 

    E-Print Network [OSTI]

    Makunike, Danai Ellarin

    1995-01-01T23:59:59.000Z

    that are associated with permanent deformation. These include Hveem stability, air voids, permeability, creep response, and compressive strength. Three CRMAC mixtures were used, each containing different amounts of RAP. The study aimed at defining how these properties...

  17. Fatigue resistance of hot-mix asphalt concrete (HMAC) mixtures using the calibrated mechanistic with surface energy (CMSE) measurements approach

    E-Print Network [OSTI]

    Ofori-Abebresse, Edward Kwame

    2006-10-30T23:59:59.000Z

    Fatigue cracking is one of the fundamental distresses that occur in the life of a Hot Mix Asphalt Concrete (HMAC) pavement. This load induced distress leads to structural collapse of the entire pavement ultimately and can only be remedied...

  18. Fatigue resistance of hot-mix asphalt concrete (HMAC) mixtures using the calibrated mechanistic with surface energy (CMSE) measurements approach 

    E-Print Network [OSTI]

    Ofori-Abebresse, Edward Kwame

    2006-10-30T23:59:59.000Z

    Fatigue cracking is one of the fundamental distresses that occur in the life of a Hot Mix Asphalt Concrete (HMAC) pavement. This load induced distress leads to structural collapse of the entire pavement ultimately and can ...

  19. Characterization of aggregate resistance to degradation in stone matrix asphalt mixtures

    E-Print Network [OSTI]

    Gatchalian, Dennis

    2006-04-12T23:59:59.000Z

    breakdown, as can be seen on Figure 2.1 through comparing the gradation after compaction with that before compaction. Figure 2.1: Influence of Compaction on Change in Gradation (after Xie and Watson 2004). 14 The L.A. abrasion value and F... on Aggregate Breakdown (after Xie and Watson 2004). LA Abrasion value, % 15 Figure 2.3: Influence of F&E Content on Aggregate Breakdown (after Xie and Watson 2004). Methods for Characterization of Aggregates for SMA Mixtures An important...

  20. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Paul J. Tikalsky, Hussain U. Bahia, An Deng and Thomas Snyder

    2004-10-15T23:59:59.000Z

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: a statistically sound evaluation of the characterization of foundry sand, a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at Nini, Ndes, and Nmax. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  1. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Pauul J. Tikalsky

    2004-10-31T23:59:59.000Z

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: (1) a statistically sound evaluation of the characterization of foundry sand, (2) a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and (3) the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at N{sub ini}, N{sub des}, and N{sub max}. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  2. Aged asphalt

    E-Print Network [OSTI]

    Martin, Kenneth Lloyd

    1988-01-01T23:59:59.000Z

    Dorchester Asphalts Exxon Asphalts CONCLUSIONS RECOMMENDATIONS LITERATURE CITED APPENDIX 41 42 48 59 70 84 90 93 96 99 103 105 106 A. GEL PERMEATION CHROMATOGRAMS OF TEST ASPHALTS 108 B. FOURIER-TRANSFORM INFRARED SPECTRUMS OF TEST... Apparatus 5. Abson Method Apparatus 6. ASTM D 2171 Apparatus 7. Sample Pellet Die 8. Sample Pellet Holder 21 23 27 29 38 40 9. GPC of Lufkin Exxon AC-20 Extracted by Two Methods . . . . . . . . . . . . . . . . 46 10. GPC of Dickens Exxon AC-20 51...

  3. Asphalt and Asphaltic Concrete

    E-Print Network [OSTI]

    Young, A. R.

    1914-05-01T23:59:59.000Z

    , and combined curb and gutter furnished and set, the rate for resetting old curbing; the rate per cubic yard for extra concrete, if any is used; the price per cubic yard for broken stone or gravel; the rate per square yard for paving and for relaying old...- tified and given access to the same at least ten days be- fore it is required for use, and any work in which re- jected cement was used will be rejected altogether. 5. The cement shall be packed in strong bags having printed on the outside the brand...

  4. Disk-shaped Compact Tension Test for Asphalt Concrete Fracture

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Disk-shaped Compact Tension Test for Asphalt Concrete Fracture by M.P.Wagoner, W.G. Buttlar and G geometry is the ability to test cylindrical cores obtained from in-place asphalt concrete pavements finalizing the specimen geometry, a typical asphalt concrete surface mixture was tested at various

  5. asphalt technology test: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and evaluated its performance when used in split mastic asphalt (SMA) mixture using Marshall Characteristic and dynamic charateristics (resilient modulus). As many as 90...

  6. Evaluation of polyethylene-modified asphalt blends

    E-Print Network [OSTI]

    Consuegra Granger, Fernando

    1990-01-01T23:59:59.000Z

    aggregate and asphalt modified with LDPE (binder contents of 4. 8%%u and 5. 87'). 42 Table 9. Summary of statistical parameters derived from IDT testing on crushed granite mixtures bound with AC-20 + LDPE (4. 8%, and 5. 8/ binder). 46 Table 10. Summary... of creep to rupture data for crushed granite mixtures. 71 Table 11. Summary of the results of IDT repeated load fatigue testing of river gravel mixtures bound with Texaco asphalt: AC- 10, AC-10 + LDPE and AC-20. Table 12. K, ' and n, values of river...

  7. Effect of airblowing on the durability of asphalt paving cements

    E-Print Network [OSTI]

    Tolson, Ronald Geoffrey

    1962-01-01T23:59:59.000Z

    to become more pronounced as the environments harden the material. The problem is to decide at what rate of shear or shearing stress should the viscosity be calculated so that changes in consistency can be most satisfactorily determined and compared... in this investigation were calcu- lated by both methods. Generally, using both methods it was found that the same trends in comparative data exist; only the magnitude of the viscosities and relative viscosities change. For simplification and to avoid confusion -2...

  8. Toxic species emissions from controlled combustion of selected paving asphalts 

    E-Print Network [OSTI]

    Mendez, Carlos Luis

    1993-01-01T23:59:59.000Z

    Table XIII. Gas Analysis Results for Material ACT-2 Using Method 1 . . . 46 Table XIV. Approximate Yield (liter/kg) of NOx from Materials AC-10A, AC-10B, AC-10C, AR4%-B, AR10%-B and AR18%-B 48 Table XV. Approximate Yield (liter/kg) of SO2 from... 53 LIST OF TABLES (Continued) Table XIX. Smoke Mass Results for Material AC-5B . . . Table XX. Smoke Mass Results for Material AR10%-B . . Table XXI. Coefficient of Variation for Materials AC-10A, AC-10B, AC-10C, AC-5B and AR10%-B. Table XXII...

  9. Toxic species emissions from controlled combustion of selected paving asphalts

    E-Print Network [OSTI]

    Mendez, Carlos Luis

    1993-01-01T23:59:59.000Z

    . . . . . . . . . . . . . . . . . . . . . . List of Materials Analyzed . Size Ranges and Effective Cut Off Diameters of the Andersen 2000 Inc. Cascade Impactor. . . . , . . . , . . . . . . . . . . . . . . . . . . 35 Gas Analysis Results for Material AC-IOA Using Method 1. . 38 Table VI. Gas... Analysis Results for Material AC-10B Using Method I . . 39 Table VII. Gas Analysis Results for Material AC-10C Using Method I . . 40 Table VIII. Gas Analysis Results for Material AC-5B Using Method I . . . 41 Table IX. Gas Analysis Results for Material...

  10. Design and Proportioning of Concrete Paving Mixtures

    E-Print Network [OSTI]

    , IMCP guidance, MCO, Shilstone, COMPASS? Guidance ultimately incorporated in training efforts! #12;Don

  11. CONCRETE PAVING & TEXTURING FOR SUSTAINABILITY

    E-Print Network [OSTI]

    Minnesota, University of

    CONCRETE PAVING & TEXTURING FOR SUSTAINABILITY Bernard Igbafen Izevbekhai, Research Operations 2012 #12;OUTLINE #12;SUSTAINABILITY · Meeting the needs of the present generation without compromising Brundtland Commission in 1987: · Successful application of the principles of sustainable development lies

  12. What's the future for rubberized asphalt

    SciTech Connect (OSTI)

    Not Available

    1991-04-01T23:59:59.000Z

    This article describes the debate over the use of rubberized asphalt for highway surfacing. The Department of Transportation claims that the process is too costly; that it presents potential air pollution, safety and health problems. They also claim that there is a lack of understanding between rubber and asphalt cement and of the recyclability of the product. The Legislative Commission on Solid Waste Management claims that the mixture performs as well or better than conventional asphalt at reduced thicknesses. In addition, there could be savings of local funds currently expended for regulation of tire dumps, fire-fighting and clean-up, vector control and scrap tire disposal costs ranging from $.50 to $2.00 per tire.

  13. Fiber reinforcement of asphalt concrete using cow manure

    E-Print Network [OSTI]

    Bakar, Mohammed Abu

    1976-01-01T23:59:59.000Z

    . Specimens were made according to the Marshall Method of Mixture Design and tested for 1) Marshall Stability 2) Hveem Stability and 3) Hater Susceptibil- ity. Test results indicated that 4. 4 percent cow manure by volume of rhe total aggregate when used... Voids in Mineral Aggregate 11 LIST OF FIGURES Figures Page l. 2 l. 3 1. 4 1. 5 1. 6 Determination of Optimum Asphalt Content by the Marshall Method Determination of Optimum Asphalt Content by the Marshall Method Determination of Optimum...

  14. Controlling Thermal Properties of Asphalt Concrete and its Multifunctional Applications

    E-Print Network [OSTI]

    Shi, Xijun

    2014-08-10T23:59:59.000Z

    of the thermally modified asphalt mixtures on the surface temperature of pavements and bridges, a series of heat transfer analysis were conducted using the finite difference heat transfer model. In addition, a case study of a building using EPP modified cement...

  15. Evaluation of the effects of crumb rubber and SBR on rutting resistance of asphalt concrete

    SciTech Connect (OSTI)

    Shih, Chuang-Tsair; Tia, Mang; Ruth, B.E. [Univ. of Florida, Gainesville, FL (United States)

    1996-12-31T23:59:59.000Z

    This paper presents the results of a study to evaluate the effects of addition of crumb rubber (CR) and styrene-butadiene rubber (SBR) on the rutting resistance of asphalt concrete. These two additives were blended with an AC-20 and an AC-30 grade asphalt cements at different levels of concentrations. These modified and unmodified asphalt blends were tested at intermediate and high temperatures to evaluate their rutting resistance characteristics. They were also used to make Florida type S-I structural surface mixtures. These mixtures were made into Marshall-size specimens by using Gyratory Testing Machine (GTM) equipped with air-roller to compact and density to three compaction levels which simulate three different conditions in the pavement. The FDOT`s (Florida Department of Transportation) Loaded Wheel Tester was also used to evaluate the rutting resistance of these asphalt mixtures. The test results indicate that the modified asphalt mixtures show relatively better rutting resistance and shear resistance as compared with the unmodified asphalt mixtures.

  16. asphalt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt pavements containing asphalt binder and aggregates. The use of RAP can reduce the cost of construction materials, reduce the amount of waste... Thakur, Jitendra Kumar...

  17. asphalts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt pavements containing asphalt binder and aggregates. The use of RAP can reduce the cost of construction materials, reduce the amount of waste... Thakur, Jitendra Kumar...

  18. Anisotropic Characterization of Asphalt Mixtures in Compression 

    E-Print Network [OSTI]

    Zhang, Yuqing 1983-

    2012-10-08T23:59:59.000Z

    and physically related to anisotropic modulus ratio. The anisotropic viscoelasticity was represented by complex moduli and Poisson's ratios in separate orthogonal directions that were determined by an efficient testing protocol. Master curve models were proposed...

  19. Evaluation of oil shale bitumen as a pavement asphalt additive to reduce moisture damage susceptibility

    SciTech Connect (OSTI)

    Robertson, R.E.; Harnsberger, P.M.; Wolf, J.M.

    1991-01-01T23:59:59.000Z

    An unrefined shale bitumen was evaluated as an agent to reduce moisture damage susceptibility of asphalt aggregate mixtures. Some activity was observed but less than might have been expected based on the molecular weight and nitrogen content of the bitumen. The counter effects of free carboxylic acids, which are known to be variable in asphalt and which are also present in the unrefined bitumen, appear to diminish the activity of the bitumen to inhibit moisture damage. 5 refs., 1 tab.

  20. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded ­ II ­ Asphalt Pavements ­ Effect of Aging ­ Simulations ­ Concluding Remarks #12;3 Objectives Develop) Correspondence Principle based formulation Application: Asphalt concrete pavements (Part II) #12;4 Asphalt

  1. Low temperature fracture evaluation of plasticized sulfur paving mixtures

    E-Print Network [OSTI]

    Mahboub, Kamyar

    1985-01-01T23:59:59.000Z

    18 19 20 21 J1C, a measure of initial crack extension as defined by ASTM (40) General trends of regression lines Actual JR lines. J lC-K0 Correl ati on . J and tearing modulus, T, as defined in this study General form of da/dN versus J... E X C (2-6) A reasonably accurate assumption can be made that Then which means that, theoretically, fracture strength o numerically is c about I/3 of modulus of elasticity. The fracture work done per unit area of crack extension can...

  2. Evaluation of Rexene polymers in hot mixed asphalt concrete

    E-Print Network [OSTI]

    Rodriguez, Mary Anne Reese

    1991-01-01T23:59:59.000Z

    -- polyethylene, polypropylene, ethylene-vinyl acetate (EVA) and ethylene-propylene rubbers -- show increased stability and stiffness modulus, increased resistance to permanent deformation and lower temperature susceptibility. Carpenter and VanDam (14... five asphalt additives: block copolymer rubber, SBR latex, EVA, polyethylene and carbon black. Mixture stability, stiffness, tensile strength and resistance to fatigue, thermal cracking, permanent deformation and moisture damage were tested. Three...

  3. A novel method of bitumen extraction from asphalt pavement

    SciTech Connect (OSTI)

    Houser, T.J. (Western Michigan Univ., Kalamazoo (United States))

    1990-07-01T23:59:59.000Z

    A new method of extracting bitumen from asphalt pavement mixtures has been developed which does not require chlorinated or aromatic compounds for solvents. The preferred solvent is cyclohexane (although cyclopentane may be used) at high temperatures and pressures. The new method requires equipment that is less costly than the centrifuge method currently used and takes less time than extractions with Bioact but more time than when chlorocompounds are used.

  4. Evaluation of a biomass derived oil for use as additive in paving asphalt

    SciTech Connect (OSTI)

    Houde, J. Jr.; Clelland, I.; Sawatzky, H. [CANMET, Ottawa, Ontario (Canada)

    1995-12-31T23:59:59.000Z

    Treatment and disposal costs of sewage sludge can represent up to 50% of a municipality`s annual wastewater treatment budget. Sewage sludge (30% solids) accounts 5% of Canadian landfill by weight, and the ever increasing volume of sludge coupled with the decreasing options available for disposal creates a growing problem for major municipalities. Current disposal options are agricultural application, incineration and landfill. Concern about heavy metal migration and public pressure to find a local solution has severely curtailed the spreading of sludge on agricultural land. Incineration is the major option for larger centers but the relatively high cost for incineration, ranging from $350 to $1000/t dry sludge, has caused a great deal of interest in methods of improving the cost effectiveness of incineration or in new equivalent technologies. The high cost and more stringent environmental regulations for incinerating municipal sludges have led to developing more efficient sludge management technologies that are not agricultural based. This paper describes applications of oils from sludge processing.

  5. Did you pave the road to project completion with gold, asphalt, or mud?

    SciTech Connect (OSTI)

    Wilberg, M.; Simpson, W.

    1994-12-31T23:59:59.000Z

    The Simpson-Wilberg Technique for Expert Decision Tree Modeling (patent case number S-83,506) establishes and identifies the proper requirements governing effective business and operating practices through the use of knowledge-based engineering (KBE). The new application, Project Control Expert System (ProCon X) was created by the Simpson-Wilberg technique as a tool for project definition planning and control. ProCon X guides the project manager through an interview session asking project characteristic questions and establishes the proper project criteria. The criteria produced define the rigor applied to the project activities, i.e., level of work breakdown structure (WBS), type of scheduling, amount of cost estimating, etc. In this paper the use of the Simpson-Wilberg technique will be illustrated for solving the problems of identifying proper project criteria for project management. This technique has been used for other applications outside the project management field and can be used in any field with a need for consistent application of rules and procedures routinely used for business and operating practices.

  6. Prediction of Asphalt Mixture Compactability from Mixture, Asphalt, and Aggregate Properties

    E-Print Network [OSTI]

    Muras, Andrew J.

    2010-07-14T23:59:59.000Z

    . Predicted Plot of CV Neural Net of Entire Data Set for a ............................ 50 Figure 32. Predicted Plot of CV Neural Net of Entire Data Set for AV Nini ................... 51 Figure 33. a versus Predicted a... ................................................... 24 Table 5 HMA Mixing and Compaction Temperatures ............................................. 27 Table 6 Compaction Parameters a, c, and AV Nini ................................................... 38 Table 7 Compaction Parameters m1, m2...

  7. Life Cycle Assessment of Reclaimed Asphalt Pavement

    E-Print Network [OSTI]

    Minnesota, University of

    Life Cycle Assessment of Reclaimed Asphalt Pavement to Improve Asphalt Pavement Sustainability By Pavement (RAP) Courtesy of http://myconstructionphotos.smugmug.com/ RAP #12;Transport Back to the Plant-melt old binder on the RAP #12;Life Cycle Assessment (LCA) · #12;Asphalt Pavement Life Cycle Road

  8. FIELD PERFORMANCE AND LABORATORY EVALUATION OF WARM MIX ASPHALT PRODUCED WITH RUBBERIZED BITUMEN

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    FIELD PERFORMANCE AND LABORATORY EVALUATION OF WARM MIX ASPHALT PRODUCED WITH RUBBERIZED BITUMEN of rubberized bitumen has been spread out mainly due to environmental aspects, but high mixing and compaction temperatures are necessary due to the higher viscosity of this bitumen. A WMA mixture (using a surfactant

  9. High temperature performance of scrap tire rubber modified asphalt concrete

    SciTech Connect (OSTI)

    Coomarasamy, A. [Ministry of Transportation, Downsview, Ontario (Canada); Manolis, S.; Hesp, S. [Queen`s Univ., Kingston, Ontario (Canada)

    1996-12-31T23:59:59.000Z

    Wheel track rutting tests on mixes modified with 30 mesh, 80 mesh, and very fine colloidal crumb rubber particles show that a very significant improvement in performance occurs with a reduction in the rubber particle size. The SHRP binder test for rutting, which was originally developed for homogeneous systems only, does not predict the performance improvement for smaller rubber particles. If these new scrap rubber binder systems are to be used in pavements then rutting tests on the asphalt-aggregate mixture should be conducted in order to accurately predict high temperature performance.

  10. Development of asphalts and pavements using recycled tire rubber. Phase 1, Technical feasibility. Technical progress report, September 1, 1994--August 31, 1995

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J. [and others

    1996-06-01T23:59:59.000Z

    About 285 million tires are discarded every year; less than 100 million are currently being recycled, with the rest being placed in landfills and other waste sites. A solution to reduce the littering of the environment is to use ground tire rubber in road construction. Currently, about 27 million tons of asphalt are used each year in road construction and maintenance of the country`s 2 million miles of roads. If all of the waste tire rubber could be combined with asphalt in road construction, it would displace less than 6% of the total asphalt used each year, yet could save about 60 trillion Btus annually. Purpose of this project is to provide data needed to optimize the performance of rubber-asphalt concretes. The first phase is to develop asphalts and recycling agents tailored for compatibility with ground tire rubber. Chapter 2 presents results on Laboratory Testing and Evaluation: fractionate asphalt material, reblending for aromatic asphalts, verifying optimal curing parameters, aging of blends, and measuring ductilities of asphalt-rubber binders. Chapter 3 focuses on Evaluating Mixture Characteristics (modified binders). Chapter 4 covers Adhesion Test Development (water susceptibility is also covered). The final chapter focuses on the Performance/Economic Update and Commercialization Plan.

  11. Asphalt deposition in miscible floods

    E-Print Network [OSTI]

    Hasan, Syed Mir Ahmed

    1964-01-01T23:59:59.000Z

    : Petroleum Engineering ASPHALT DEPOSITION IN MISCIBLE FLOODS A Thesis By SYED MIR AHMED HASAN Approved as to style and content by: (Chairman of Committee) ommittee Member) Committee Member) Head of Department), (Co 'ttee Member) January, f964... Subject: Petroleum Engineering TABLE OF CONTENTS ABS TRAC T. Page 2. INTRODUCTION. 3 DESCRIPTION OF EQUIPMENT AND MATERIALS. . . . . , . 6 4. EXPERIMENTAL PROCEDURE 5. INTERPRETATION AND DISCUSSION OF RESULTS. . . . . . 13 6. CONCLUSIONS. 7...

  12. Winter Performance and Maintenance of Porous Asphalt Pavements

    E-Print Network [OSTI]

    Concrete (HSG-B)Porous Asphalt (HSG-C) #12;Cold Climate Performance Results #12;12 Porous Asphalt SurfaceWinter Performance and Maintenance of Porous Asphalt Pavements Robert M. Roseen, Ph.D., P.E., D impacts for new development and reverse impacts in areas with redevelopment. #12;Porous Asphalt Design

  13. Compatibilizer for crumb rubber modified asphalt

    SciTech Connect (OSTI)

    Labib, M.E. [New Jersey Institute of Technology, Newark, NJ (United States); Memon, G.M.; Chollar, B.H. [Federal Highway Administration, McLean, VA (United States)

    1996-12-31T23:59:59.000Z

    The United States of America discards more than 300 million tires each year, and out of that a large fraction of the tires is dumped into stock piles. This large quantity of tires creates an environmental problem. The use of scrap tires is limited. There is a usage potential in such fields as fuel for combustion and Crumb Rubber-Modified Asphalt binder (CRMA). The use of crumb rubber in modifying asphalt is not a new technique; it is been used since early 1960 by pavement engineers. Crumb rubber is a composite of different blends of natural and synthetic rubber (natural rubber, processing oils, polybutadiene, polystyrene butadiene, and filler). Prior research had concluded that the performance of crumb rubber modified asphalt is asphalt dependent. In some cases it improves the Theological properties and in some cases it degrades the properties of modified asphalt.

  14. Materials characterization of asphalt and polymer modified asphalt 

    E-Print Network [OSTI]

    Paramasivam, Mohan

    1992-01-01T23:59:59.000Z

    specimen mold made of aluminum ? ? ? ? ? ? ? ? ? ? - 28 5. Strain sweep of Santa Maria AC10/AR4000 at 100 rad/sec --- 33 6. Strain sweep of Conoco AC10 at 10 rad/sec ------------- 34 7. Stress relaxation modulus of AAM grade asphalt at 25'C --- 37 8.... The verification of Cox-Merz rule for Santa Maria AC6/AR2000 at 40'C- 9. The master curve of Santa Maria AC6/Muehlstein LDPE shifted to 25'C showing the errors 10. Master curve (G') of Santa Maria AC6 shifted to 25'C ? ? ? ? ? 43 11. Master curve of Santa...

  15. Materials characterization of asphalt and polymer modified asphalt

    E-Print Network [OSTI]

    Paramasivam, Mohan

    1992-01-01T23:59:59.000Z

    specimen mold made of aluminum ? ? ? ? ? ? ? ? ? ? - 28 5. Strain sweep of Santa Maria AC10/AR4000 at 100 rad/sec --- 33 6. Strain sweep of Conoco AC10 at 10 rad/sec ------------- 34 7. Stress relaxation modulus of AAM grade asphalt at 25'C --- 37 8.... The verification of Cox-Merz rule for Santa Maria AC6/AR2000 at 40'C- 9. The master curve of Santa Maria AC6/Muehlstein LDPE shifted to 25'C showing the errors 10. Master curve (G') of Santa Maria AC6 shifted to 25'C ? ? ? ? ? 43 11. Master curve of Santa...

  16. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12T23:59:59.000Z

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organicsmore »present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.« less

  17. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12T23:59:59.000Z

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organics present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.

  18. TECHNICAL POLLUTION PREVENTION GUIDE FOR ASPHALT PREPARATION OPERATIONS

    E-Print Network [OSTI]

    Delivery, Storage and Cold Feed . . . . . . . . . . . . . 12 2.3.2 Liquid Asphalt Delivery, Storage . . . . . . . . . . . . . . . . . . . . . . 4 2 INDUSTRY PROFILE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2.1 ASPHALT and Heating . . . . . . . . . . . . 12 2.3.3 Cold Feed Drying and Heating

  19. An investigation of the use of tire rubber in asphalt

    E-Print Network [OSTI]

    Koo, Heamo Lee

    1996-01-01T23:59:59.000Z

    -rubber binder. The selected variables chosen are curing time, curing temperature, rubber content (weight percent), rubber particle size, base asphalt type, and carbonyl area. Results confirmed that the addition of rubber increased the viscosity of the asphalt...

  20. asphalt composition aplicacao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Warm mix asphalt (WMA) is not a hot mix asphalt (HMA), it's just warm mix The WMA production temperature typically ranges from 100 to 140o C, whereas for HMA it ranges Das,...

  1. Controlling Thermal Properties of Asphalt Concrete and its Multifunctional Applications 

    E-Print Network [OSTI]

    Shi, Xijun

    2014-08-10T23:59:59.000Z

    ) by controlling thermal properties of the construction materials. To change thermal properties of asphalt concrete, expanded polypropylene (EPP) pellet and graphite were selected as the additives and mixed into asphalt concrete. Experimental tests are classified...

  2. Effect of viscosity of asphalt on stress strain and volume change characteristics of asphaltic mixtures

    E-Print Network [OSTI]

    Gandhi, Poduru Mohandas Karamchand

    1966-01-01T23:59:59.000Z

    Raages for Cannonading Vacuum Capillary Viscometers Viscosities at 140 F and 275 F Using Capillary V iscaaetar Rxpaasion of Triaxial Cell Mith Time At Various pressures 10 Typical Triaxial Test Data 11 Typical Triaxial Test Data 12 Typical... and the top loading cap was placed in position. 2. The circumferential surfaces of base plate and loading cap mre covered with high vacuum silicone grease. 3, The rubber membrane suitable for four inch diameter samples was placed over the speciamn using a...

  3. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded ­ Verification ­ Concluding Remarks Part ­ II (Companion presentation) ­ Asphalt Pavements ­ Effect of Aging: Asphalt concrete pavements (Part II) E1 E2 E3 Eh 1 2 3 h #12;Graded Finite Elements Graded Elements

  4. Effect of density on the stability of asphaltic concrete mixtures

    E-Print Network [OSTI]

    Subbaraju, Bhupatiraju

    1953-01-01T23:59:59.000Z

    Test, The Rarohall Stabi- lity Tost as8 The Califorsia Co beeiemtor Tost, fer Series I 8 as Chtai ass by 'Tbo Marshall Cosyae- tios Preoo8lro ~ ~ ~ s ~ ~ ~ ~ ~ ~ ~ ~ ~ Rela4ioaship boteeea Doss ity aas Sta- bility as RoaeereS by Tbs Rroea... Stability Tost, the Marshall Rishi lity Test as& Tho CaliforaLa Cshesie astor Test, for Series L 8 as Cbtaiaed by The Tease RLShoay Royartseat Cea- Ssotioa Pfiso8ere ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ Relatioaehiy beieses Qeasity as8 8ta- bLlity as Reassros...

  5. asphalt rubber mixtures: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jerry G. Murphy 2013-01-23 112 Material: Recycled Rubber from Tires, Industrial Scrap CiteSeer Summary: using the ambient desert heat (160-220F). The process was brought...

  6. Geocell-Reinforced Unpaved and Paved Roads with Recycled Asphalt Pavement (RAP) Bases: Experimental Study and Damage Model Development

    E-Print Network [OSTI]

    Thakur, Jitendra Kumar

    2013-08-31T23:59:59.000Z

    by increasing the percentage of resilient deformation and reducing the permanent deformations and the vertical stresses transferred to the subgrade. A thin (about 50 mm) HMA surface significantly improved the performance of RAP bases. The thicker geocell...

  7. Paving the Way to Nanoelectronics 16 nm and Smaller

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomassPPPO WebsitePalms Village95-1999)Paul J.Paving the WayPaving

  8. The effect of asphalt deposition on recovery of oil by a pentane slug

    E-Print Network [OSTI]

    Bhagia, Nanik S

    1965-01-01T23:59:59.000Z

    ":ty reduction increases, in general, with the increase in amount of, asphalt contained ir the oil. The increases in recovery at breakthrough due to asphalt deposition were noted for four asphaltic crude oils and were compared to those of asphalt-free refined... substantial range, the gain in recovery at breakthrough of asphaltic oils over refined oils of the same viscosity increases with increase in size of slug used. This is attributed to more favorable mobility ratios resulting from asphalt deposition during...

  9. Asphalt Pavement Aging and TemperatureAsphalt Pavement Aging and Temperature Dependent Properties using a FunctionallyDependent Properties using a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and TemperatureAsphalt Pavement Aging and Temperature Dependent Properties Analysis Time Integration Analysis Application Examples: Asphalt Pavement Summary and Conclusions #12) ­ Large fraction produced as hot-mix asphalt (HMA) ­ Most common form of pavement surfacing material (96

  10. Investigation of Noise and Durability Performance Trends for Asphaltic Pavement Surface Types: Three-Year Results

    E-Print Network [OSTI]

    Lu, Qing; Kohler, Erwin R.; Harvey, John T; Ongel, Aybike

    2009-01-01T23:59:59.000Z

    Trends for Asphalt Pavement Surface Types: First- andResults. University of California Pavement Research Center,Trends for Asphaltic Pavement Surface Types: First- and

  11. A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products

    E-Print Network [OSTI]

    Levinson, Ronnen

    2010-01-01T23:59:59.000Z

    for providing concrete tiles, and Lou Hahn of GAF-Elk forof cool colored concrete tile and asphalt shingle roofingsolar-reflective nonwhite concrete tile and asphalt shingle

  12. IMPROVING MIX DESIGN AND CONSTRUCTION OF PERMEABLE FRICTION COURSE MIXTURES

    E-Print Network [OSTI]

    Alvarez Lugo, Allex Eduardo

    2012-02-14T23:59:59.000Z

    and Transportation Officials ANOVA Analysis of Variance AR Asphalt Rubber AV Air Voids CEDEX Centro de Estudios y Experimentaci?n de Obras P?blicas COV Coefficient of Variation DEM Discrete Element Method DEM-IA Discrete Element Method and Image... of Theoretical Maximum Specific Gravity (Gmm) for (a) I-35-PG and (b) US-281-AR Mixtures.??????????.?........... 13 2-2 Variability of Theoretical Maximum Specific Gravity (Gmm) for (a) I-35-PG and (b) US-281-AR Mixtures?????????????.? 15 2...

  13. Predicting the fatigue life of asphalt concrete overlay systems

    E-Print Network [OSTI]

    Germann, Frederick P

    1979-01-01T23:59:59.000Z

    ON CRACK GROWTH IN VISCOELASTIC MATERIALS C'HAPTER V - STATE OF THE ART Effect of Mix Variables on Fatigue and Cracking Resistance in Asphalt Concrete Pavements . Field Performance of Asphalt Overlays with Fabric Summary CHAPTER VI ? MATERIALS... LIFE OF AN ASPHALT OVERLAY CHAPTER X - CONCLUSIONS AND RECOMMENDATIONS REFERENCES APPENDIX A. CRACK TIP STRESS ANALYSIS APPENDIX B. CONSTRUCTION OF THE MASTER RESILIENT MODULUS AND MASTER CREEP COMPLIANCE CURVES APPENDIX C. CRACK GROWTH RATES, da...

  14. Microstructural Characterization of Material Properties and Damage in Asphalt Composites

    E-Print Network [OSTI]

    Mohammad Khorasani, Sara

    2013-05-03T23:59:59.000Z

    MICROSTRUCTURAL CHARACTERIZATION OF MATERIAL PROPERTIES AND DAMAGE IN ASPHALT COMPOSITES A Thesis by SARA MOHAMMAD KHORASANI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... Engineering Copyright 2013 Sara Mohammad Khorasani ii ABSTRACT Asphalt composites are used to construct 90% of roads in the United States. These composites consist of asphalt binder, which is a product of the refinery process of oil, aggregates...

  15. anionic emulsified asphalt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 15 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization Websites...

  16. asphalt rock: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 17 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  17. asphaltic sand: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 19 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  18. asphalt concrete overlays: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    experimental results for concrete containing virgin limestone Paulino, Glaucio H. 71 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  19. asphalt overlay design: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    these overlay networks. Routing and search in these overlay ... Cheng, Bow-Nan 69 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  20. asphalt binder extraction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 43 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  1. Full-Depth Pavement Reclamation with Foamed Asphalt: Final Report

    E-Print Network [OSTI]

    Jones, David; Fu, P.; Harvey, John T; Halles, F.

    2008-01-01T23:59:59.000Z

    University of California Pavement Research Center. (WP-2005-8 th Conference on Asphalt Pavements for Southern Africa (International Journal of Pavement Engineering, Vol 8, No

  2. asphalt concrete bases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large amounts of PS wastes in civil engineering constructions. Key words: Asphalt surfaces Disposable dishes Polystyrene (PS) Wastes Environment A. Akbari Motlagh; A....

  3. asphalt concrete soil: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large amounts of PS wastes in civil engineering constructions. Key words: Asphalt surfaces Disposable dishes Polystyrene (PS) Wastes Environment A. Akbari Motlagh; A....

  4. Compositional evaluation of asphalt binder recycling agents

    E-Print Network [OSTI]

    Madrid, Richard Charles

    1997-01-01T23:59:59.000Z

    from: Exxon Research and Engineering Company, The National Consortium for Graduate Degrees for Minorities in Engineering and Science, Inc. Fellowship (GEM), and the DOW Technical Fellowship is greatly appreciated. I thank Sophie and Ignacio Madrid... for Recycled Blends . . . . . Asphaltic Materials. . 54 58 63 69 V-2 V-3 V-4 V-5 V-6 V-7 Fina DMO and Exxon Tank Compositions and Viscosities. . . . Blend Compositions and Viscosities...

  5. Properties of concrete paving blocks made with waste marble Osman Gencela,f,*, Cengiz Ozelb

    E-Print Network [OSTI]

    North Texas, University of

    Properties of concrete paving blocks made with waste marble Osman Gencela,f,*, Cengiz Ozelb , Fuat: Concrete paving blocks Recycled aggregate Marble waste Concrete wear a b s t r a c t Marble industry. Waste marble is well usable instead of the usual aggregate in the concrete paving block production. Ã?

  6. Rheological Investigation of the Influence of Acrylate Polymers on the Modification of Asphalt

    E-Print Network [OSTI]

    Hussein, Ibnelwaleed A.

    and superior ACM properties when blended with the high asphaltenes Arabian asphalt. © 2006 Wiley Periodicals

  7. Field Manual for Crack Sealing in Asphalt Pavements

    E-Print Network [OSTI]

    Texas at Austin, University of

    Field Manual for Crack Sealing in Asphalt Pavements Yetkin Yildirim, Ahmed Qatan, and Jorge Prozzi January 2006 3208RedRiver Austin,TX78705 #12;Dr. Yetkin Yildirim, P.E. Director Texas Pavement for Crack Sealing in Asphalt Pavements #12;Performing Organization: Center for Transportation Research

  8. Recycling asphalt overview of more than 25 years of use

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Recycling asphalt overview of more than 25 years of use in France Y. Brosseaud ­ LCPC hal with ring for recycling ­ Average rate with high proportion : 30 to 50% ­ Used of rejuvenators (soft oil,version1-20May2011 #12;4 Hot recycling asphalt on mixing plant Recycling in place in hot or cold

  9. Relationship Between Surface Free Energy and Total Work of Fracture of Asphalt Binder and Asphalt Binder-Aggregate Interfaces 

    E-Print Network [OSTI]

    Howson, Jonathan Embrey

    2012-10-19T23:59:59.000Z

    is the surface free energy of the asphalt binder and the aggregate. Surface free energy, which is a thermodynamic material property, is directly related to the adhesive bond energy between the asphalt binder and the aggregate as well as the cohesive bond energy...

  10. Relationship Between Surface Free Energy and Total Work of Fracture of Asphalt Binder and Asphalt Binder-Aggregate Interfaces

    E-Print Network [OSTI]

    Howson, Jonathan Embrey

    2012-10-19T23:59:59.000Z

    is the surface free energy of the asphalt binder and the aggregate. Surface free energy, which is a thermodynamic material property, is directly related to the adhesive bond energy between the asphalt binder and the aggregate as well as the cohesive bond energy...

  11. NERSC's Science Gateways Pave Way for 'Team Science'

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |IsLove Your1AllocationsNOVAPlayedNERSC's Science Gateways Pave Way

  12. Paving the Way to Nanoelectronics 16 nm and Smaller

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomassPPPO WebsitePalms Village95-1999)Paul J. Turinsky,PaulPaving

  13. Paving the Way to Nanoelectronics 16 nm and Smaller

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomassPPPO WebsitePalms Village95-1999)Paul J.Paving the Way to

  14. Paving the Way to Nanoelectronics 16 nm and Smaller

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomassPPPO WebsitePalms Village95-1999)Paul J.Paving the Way

  15. Paving the Way to Nanoelectronics 16 nm and Smaller

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeeding access toTestPhysicsParticipantsPartnersC. MessinaJ.RichPaving the

  16. Paving the Way to Nanoelectronics 16 nm and Smaller

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeeding access toTestPhysicsParticipantsPartnersC. MessinaJ.RichPaving

  17. Use of shredded tires in the subbase layer of asphalt pavements

    SciTech Connect (OSTI)

    Papp, W.J. Jr.; Maher, M.H. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Civil and Environmental Engineering; Baker, R.F. [New Jersey Dept. of Transportation, Trenton, NJ (United States)

    1997-12-31T23:59:59.000Z

    Research was conducted on the use of shredded scrap tires for use in the subbase layer of asphalt pavements. Mixtures of shredded scrap tires with virgin soil provide a means of recycling unwanted tires and conserving a finite supply of virgin soil. The mechanistic procedure for the design of pavement systems requires resilient modulus values. Plastic and elastic strains were measured using external LVDT`s and internal proximity sensors. Resilient modulus measurements were conducted on cohesionless soils mixed with various amounts of shredded tire chips. The performance f the shredded tire mixture is compared to that of the naturally occurring virgin soil used in subbase applications in New Jersey. A number of experimental issues are discussed such as: method of compaction, optimum ratio of shredded tire chips to soil, optimum size and gradation of shredded tire chips, and strength testing using California Bearing Ratio.

  18. Improvements to a Transport Model of Asphalt Binder Oxidation in Pavements: Pavement Temperature Modeling, Oxygen Diffusivity in Asphalt Binders and Mastics, and Pavement Air Void Characterization

    E-Print Network [OSTI]

    Han, Rongbin

    2012-07-16T23:59:59.000Z

    Although evidence is mounting that asphalt binder oxidizes in pavements, and that oxidation and subsequent hardening of asphalt binder has a profound effect on pavement durability, important implementation issues remain to be better understood...

  19. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded Viscoelastic Model, Part-II: Applications

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded simulation of functionally graded viscoelastic properties in asphalt concrete pavements. The techniques properties. A full-depth asphalt concrete pavement has been simulated to demonstrate the applicability

  20. Rutting Performance of Airport Hot-Mix Asphalt Characterized by Laboratory Performance Testing, Full-Scale Accelerated Pavement Testing, and Finite Element Modeling

    E-Print Network [OSTI]

    Rushing, John Ford

    2014-04-25T23:59:59.000Z

    California Bearing Ratio DoD Department of Defense DSR Dynamic Shear Rheometer ERDC U.S. Army Engineer Research and Development Center FAA Federal Aviation Administration FN flow number FT flow time HMA Hot Mix Asphalt HVS heavy vehicle simulator... aircraft continue to necessitate modifications in the procedures by which HMA mixtures are designed so that rutting does not become a prevalent distress on airport pavements. The Federal Aviation Administration (FAA) has predominantly required use...

  1. The curing of asphalt with rubber and its effect on the physical and chemical properties of asphalt-rubber binders

    E-Print Network [OSTI]

    Chun, Jay Sung

    1995-01-01T23:59:59.000Z

    10% TG-40 and 90% Exxon AC-5. 105 B-1 Molecular Size Distribution of Rubber in Asphalt 5% TG-40 and 95% Fina AC-10. . . 123 B-2 Molecular Size Distribution of Rubber in Asphalt 10% TG-40 and 90% Fina AC-10. . 124 xlv FIGURE B-3 Molecular Size.... 0 Frequency (rad/s) 10. 0 100. 0 Figure III-2: Effect of Frequency on Viscosity Measurements Fina AC-10 Tank Asphalt 2500 2000 0 a 1500 1000 o 0 0 0 0 o o 0 0 0 0 0 0 0 o 0 Fina AC-10 with 5% TG-40 mesh rubber Cured at 375 F and 500...

  2. asphalt emulsions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 21 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  3. Viscoelastic{Viscoplastic Damage Model for Asphalt Concrete

    E-Print Network [OSTI]

    Graham, Michael A.

    2010-10-12T23:59:59.000Z

    This thesis presents a continuum model for asphalt concrete incorporating non- linear viscoelasticity, viscoplasticity, mechanically-induced damage and moisture- induced damage. The Schapery single-integral viscoelastic model describes the nonlinear...

  4. A thermodynamic approach for compaction of asphaltic composites

    E-Print Network [OSTI]

    Koneru, Saradhi

    2009-05-15T23:59:59.000Z

    and Focus of Current Work . . . . . . . . . . . . . . 2 B. Outline of the Thesis . . . . . . . . . . . . . . . . . . . . . 3 C. Notations Used . . . . . . . . . . . . . . . . . . . . . . . . 4 II LITERATURE REVIEW... . . . . . . . . . . . . . . . . 8 b. Asphalt Binder . . . . . . . . . . . . . . . . . . . 8 C. Compaction Equipment . . . . . . . . . . . . . . . . . . . . 9 1. Field Compaction Equipment . . . . . . . . . . . . . . 9 a. Static Steel Wheel Rollers . . . . . . . . . . . . . 9 b...

  5. asphaltic pavements microsurfacing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  6. asphalt pavement cracking: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 16 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  7. asphalt concrete pavement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  8. asphalt pavement rap: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  9. asphaltic concrete pavement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  10. asphalt concrete pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  11. asphaltic concrete pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  12. asphalt pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  13. Measurements of moisture suction in hot mix asphalt mixes 

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    with different bond energies and exhibited different field performance in terms of resistance to moisture damage. The suction measurements in sand asphalt specimens were used to calculate the moisture diffusion coefficient. The results revealed that water...

  14. Imparting Electrical Conductivity into Asphalt Composites Using Graphite 

    E-Print Network [OSTI]

    Baranikumar, Aishwarya

    2013-07-09T23:59:59.000Z

    publications showed the potential of graphite in mitigating the sudden transition. The study presented herein investigates possibility of precisely controlling the electrical conductivity of asphalt concrete only by adding filler size graphite powder. Nine...

  15. asphalt concrete performance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robert L. 2014-01-01 23 Establishing material properties for thin asphalt concrete surfaces on granular bases Texas A&M University - TxSpace Summary: of MASTER OF SCIENCE...

  16. Study of properties of sand asphalt using a torsional rheometer 

    E-Print Network [OSTI]

    Kasula, Lavan Kumar Reddy

    2004-11-15T23:59:59.000Z

    The modeling of Sand Asphalt and experiments to measure their rheological properties are of vital concern to many industrial processes especially highway and roadway pavement construction industry. A variety of hot mix ...

  17. Use of VFDs on Asphalt Plant Induced Draft Fans

    E-Print Network [OSTI]

    Anderson, G. R.; Case, P. L.; Lowery, J.

    2005-01-01T23:59:59.000Z

    Studies of 10 asphalt plants in the Intermountain Region have identified average ID fan energy savings of 68% by controlling airflow using Variable Frequency Drives (VFDs) on the fan motors in place of damper control (inlet or outlet). Average...

  18. Characterization of road asphalt using Gel Permeation Chromatography

    E-Print Network [OSTI]

    Donaldson, Guy Randal

    1987-01-01T23:59:59.000Z

    inconsistent and inconsistent. Six were consistent, three were slightly inconsist nt, and three were inconsistent. To study the relationship between GPC and performance, samples from test pavements at three locations were obtained. Both original asphalts... Columns/Toluene/100 Nicroliters/ 7X 3 ' 2. Reproducibility of the Standard Asphalt in THF . ~ . . ~ . ~ . . . 500 and 50 Angstrom Columns/Toluene/100 Nicroliters/ 7X 19 3. 3. Differences in Refractive Index Detector Response. Exxon AC-10/Dumas Tank...

  19. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report, #930-of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferred to use a mix that would have good moisture resistance under laboratory testing

  20. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Harvey, John T; Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report no.of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferable to use a mix that would have good moisture resistance under laboratory testing

  1. Experimental Study on Geocell-Reinforced Recycled Asphalt Pavement (RAP) Bases under Static and Cyclic Loading

    E-Print Network [OSTI]

    Thakur, Jitendra Kumar

    2011-01-13T23:59:59.000Z

    Recycled Asphalt Pavement (RAP) is a removed and reprocessed pavement material containing asphalt and aggregates which can be used as a base course material for pavement applications. Geocells are a three-dimensional interconnected honeycomb type...

  2. Asphalt compositions containing spurted polyolefin fibers with improved dispersibility in hydrocarbons

    SciTech Connect (OSTI)

    Jabloner, H.

    1987-07-07T23:59:59.000Z

    A cutback asphalt composition is described comprising asphalt and a hydrocarbon solvent. The improvement composition comprises a water-dispersible spurted polyolefin pulp having precipitated a natural rubber or synthetic elastomer that is swellable in hydrocarbon solvents.

  3. E-Print Network 3.0 - asphalt mix design Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Environmental Engineering, Arizona State University Collection: Engineering 35 Bi Oil i A h ltBio-Oil in Asphalt ApplicationsApplications Summary: tons of hot mix asphalt...

  4. Development of asphalts and pavements using recycled tire rubber. Phase 1: technical feasibility. Final report

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J. [and others

    1998-01-01T23:59:59.000Z

    This report documents the technical progress made on the development of asphalts and pavements using recycled tire rubber.

  5. A study of the mixing viscosity of asphalt in hot-mix production

    E-Print Network [OSTI]

    Khan, Md. Musharraf Hossain

    1961-01-01T23:59:59.000Z

    Gravity and Absorption of Aggregates. 36 Sieve Analysis of Combined Aggregates 37 Centrifuge Kerosene Equivalent Test Data for Estimated Optimum Asphalt Content . 38 Test Data on Molded Specimens for Optimum Asphalt Content 39 XIII . Test Data... there is available to be filled with asphalt. The Centrifuge Kerosene Equivalent (CKE) Test was performed to 11 determine the estimated optimum asphalt content as a percentage of the 10 The American Association of State Highway Officials, "Standard...

  6. Asphalt Roofing Shingles Into Energy Project Summary Report

    SciTech Connect (OSTI)

    Jameson, Rex, PE

    2008-04-28T23:59:59.000Z

    Based on a widely cited September, 1999 report by the Vermont Agency of Natural Resources, nearly 11 million tons of asphalt roofing shingle wastes are produced in the United States each year. Recent data suggests that the total is made up of about 9.4 million tons from roofing tear-offs and about 1.6 million tons from manufacturing scrap. Developing beneficial uses for these materials would conserve natural resources, promote protection of the environment and strengthen the economy. This project explored the feasibility of using chipped asphalt shingle materials in cement manufacturing kilns and circulating fluidized bed (CFB) boilers. A method of enhancing the value of chipped shingle materials for use as fuel by removing certain fractions for use as substitute raw materials for the manufacture of new shingles was also explored. Procedures were developed to prevent asbestos containing materials from being processed at the chipping facilities, and the frequency of the occurrence of asbestos in residential roofing tear-off materials was evaluated. The economic feasibility of each potential use was evaluated based on experience gained during the project and on a review of the well established use of shingle materials in hot mix asphalt. This project demonstrated that chipped asphalt shingle materials can be suitable for use as fuel in circulating fluidized boilers and cement kilns. More experience would be necessary to determine the full benefits that could be derived and to discover long term effects, but no technical barriers to full scale commercial use of chipped asphalt shingle materials in these applications were discovered. While the technical feasibility of various options was demonstrated, only the use of asphalt shingle materials in hot mix asphalt applications is currently viable economically.

  7. Recycling of plastic and rubber tire waste in asphalt pavements

    SciTech Connect (OSTI)

    Morrison, G.R.; Lee, N.K.; Hesp, S.A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Chemistry

    1994-12-31T23:59:59.000Z

    This paper discusses some important issues related to the use of recycled thermoplastics and rubber tire waste in asphalt binders for hot-mix pavements. Both high temperature rheological and low temperature fracture studies are presented on recycled polyethylene, devulcanized and crumb rubber-modified asphalt binders. The results are compared to unmodified and commercially available modified binders. This research is especially timely in light of the US Intermodal Surface Transportation Efficiency Act of 1991, Section 1038 which, starting in 1995, will force state and local governments to use significant amounts of recycled rubber tire or plastic waste in federally funded highway projects. High temperature rheological measurements of the loss modulus, loss tangent and complex modulus show a significant improvement when only small quantities of crumb rubber, devulcanized crumb rubber or waste polyethylene are added to the asphalt binders. The low temperature fracture performance of the modified asphalts is greatly influenced by the interfacial strength between the dispersed and continuous phase. The fracture toughness increases dramatically, only when low molecular weight polymers are grafted in-situ onto the rubber and polymer dispersed phases in order to strength the interface. This points to a crack-pinning mechanism as being responsible for the dramatic increase in fracture toughness that is observed in this work. Single phase, devulcanized crumb rubber-asphalt systems perform quite poorly at low temperatures.

  8. Use of recycled chunk rubber asphalt concrete (CRAC) on low volume roads and use of recycled crumb rubber modifier in asphalt pavements. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Hossain, M.; Funk, L.P.; Sadeq, M.A.; Marucci, G.

    1995-06-01T23:59:59.000Z

    The major objective of this project was to formulate a Chunk Rubber Asphalt Concrete (CRAC) mix for use on low volume roads. CRAC is a rubber modified asphalt concrete product produced by the `dry process` where rubber chunks of 1/2 inch size are used as aggregate in a cold mix with a type C fly ash. The second objective of this project was to develop guidelines concerning the use of rubber modified asphalt concrete hot mix to include: (1) Design methods for use of asphalt-rubber mix for new construction and overlay, (2) Mix design method for asphalt-rubber, and (3) Test method for determining the amount of rubber in an asphalt-rubber concrete for quality control purposes.

  9. Effect of pyrolyzed carbon black on asphalt cement. Part 2. Asphalt binder. Final report, September 1993-May 1995

    SciTech Connect (OSTI)

    Zeng, Y.; Lovell, C.W.

    1996-02-20T23:59:59.000Z

    Scrap tires derived from automobiles have become a large environmental problem in the United States. In the study, research is carried out to investigate the potential use of tire-derived pyrolyzed carbon black from scrap tires as an asphalt cement modifier. The asphlat cements used in the research were AC10 and AC20. Penetration and softening point tests were performed to obtain the consistency of the asphalt cements. The pyrolyzed carbon black, as provided by Wolf Industries, was combined with the asphalt cement in the following percentages: 5%, 10%, 15% and 20%. Penetration, softening point and ductility tests were performed to determine the temperature susceptibility of the modified binder as altered by the pyrolyzed carbon black. In order that the results are comparable to previous testing, commercial carbon black purchased from CABOT Industry was also used as a modifier in the tests. The same test procedures were applied to the asphalt cements modified by commercial carbon black. The test results contained in the report illustrate the viability of the pyrolyzed carbon black as an asphalt modifier. Recommendations are provided to facilitate further research on this particular project. A preliminary assessment of a test road using the pyrolyzed carbon is appended.

  10. A study of the effects of limestone rock asphalt screenings on the structural properties of hot-mix asphaltic concrete made with siliceous materials 

    E-Print Network [OSTI]

    Albritton, Oscar Willard

    1958-01-01T23:59:59.000Z

    LiSRagy pptt8pp py IEXAa A STUDY OF THE EFFECTS OF LIMESTONE ROCK ASPHALT SCREENINGS ON THE STRUCTURAL PROPERTIES OF HOT-MIX ASPHALTIC CONCRETE MADE WITH SILICEOUS MATERIALS A Thesis By OSCAR WILLARD. AQBRITTON Submitted to the Graduate... ON THE STRUCTURAL PROPERTIES OF HOT-MIX ASPHALTIC CONCRETE MADE WITH SILICEOUS MATERIALS A Thesis By OSCAR WILLARD ALBRITTON Approved as to Style and Content by: Chairman of Committee ead of Departme t August 1958 ACKNOWLEDGMENTS Acknowledgment is due...

  11. Recycling asphaltic concrete with sulphur as a supplemental binder

    E-Print Network [OSTI]

    Barnett, Robert William

    1976-01-01T23:59:59.000Z

    in the United States, and the use of this secondary sulphur for construction purposes could provide not only a vast savings of natural resources and reusable materials but also aid industry in recovering the cost of environ- mental protection. The waste... industry [25, 26, 27, 28]. Research has been undertaken to investigate the use of sulphur in sand-asphalt- sulphur pavement mixes [11, 25, 29, 30]. The use of sulphur in sulphur-asphalt emulsions to serve as a binder has also been studied [26, 31, 32...

  12. Asphalt roofing industry Fourier transform infrared spectroscopy modified bitumen

    SciTech Connect (OSTI)

    NONE

    1999-07-01T23:59:59.000Z

    A Request for Emissions Testing at Four Asphalt Roofing and Processing Facilities was submitted by the US EPA Emission Standards Division (ESD), Minerals and Inorganic Chemicals Group (MICG) to the Emission Measurement Center (EMC). The Emission Measurement Center directed Midwest Research Institute (MRI) to conduct emissions testing at asphalt roofing plants. This report presents results of MRI`s FTIR and Method 25A testing conducted at US Intec in Port Arthur, Texas. The field measurements were performed in September 1997 under several test conditions for both controlled and uncontrolled emissions.

  13. Automated titration method for use on blended asphalts

    DOE Patents [OSTI]

    Pauli, Adam T. (Cheyenne, WY); Robertson, Raymond E. (Laramie, WY); Branthaver, Jan F. (Chatham, IL); Schabron, John F. (Laramie, WY)

    2012-08-07T23:59:59.000Z

    A system for determining parameters and compatibility of a substance such as an asphalt or other petroleum substance uses titration to highly accurately determine one or more flocculation occurrences and is especially applicable to the determination or use of Heithaus parameters and optimal mixing of various asphalt stocks. In a preferred embodiment, automated titration in an oxygen gas exclusive system and further using spectrophotometric analysis (2-8) of solution turbidity is presented. A reversible titration technique enabling in-situ titration measurement of various solution concentrations is also presented.

  14. A Methodology of Quantifying Precipitation Exposure for Wet-Weather Collisions and Evaluating Effectiveness of Open-Grade Asphalt Concrete as a Countermeasure

    E-Print Network [OSTI]

    Chan, Ching-Yao; Jin, Eui-Jae; Oh, Soon Mi; Ragland, David R

    2010-01-01T23:59:59.000Z

    Open-graded Asphaltic Concrete Friction Courses in Arizona.for Open-Graded Asphalt Concrete (OGAC) Wearing Courses.of Open-Grade Asphalt Concrete as a Countermeasure Ching-Yao

  15. asphalt technology development: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt technology development First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Development and...

  16. asphalt based materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt based materials First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Establishing material...

  17. Measurements of moisture suction in hot mix asphalt mixes

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    The presence of moisture in hot mix asphalt (HMA) causes loss of strength and durability of the mix, which is referred to as moisture damage. This study deals with the development of experimental methods for measuring total suction in HMA, which can...

  18. asphalt construction premature: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt construction premature First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Moisture Diffusion in...

  19. Summary of Construction Activities and Results from Six Initial Accelerated Pavement Tests Conducted on Asphalt Concrete Pavement Section for Modified-Binder Overlay

    E-Print Network [OSTI]

    Bejarano, Manuel O.; Morton, Bruce S.; Scheffy, Clark

    2005-01-01T23:59:59.000Z

    Testing on the Asphalt Concrete FWD testing was conducted onin asphalt concrete modulus after HVS testing for Sectionsconcrete pavements under accelerated pavement testing. This

  20. The use of HPGPC for determination of MWD of asphalt cement - A spectrophotometric vs. gravimetric finish

    SciTech Connect (OSTI)

    Bishara, S.W.; McReynolds, R.L. (Kansas Dept. of Transportation, Topeka (United States))

    1990-07-01T23:59:59.000Z

    A comparison between spectrophotometric and gravimetric methods to study MWD of asphalt is presented. Spectrophotometry suffers from not detecting saturated compounds, as well as from variation of molar absorptivity during analysis. To address these shortcoming, the whole asphalt sample is fractionated, and the relative molar absorptivity determined for each fraction. Using another sample weight of the whole asphalt, the saturates are separated, and injected to get their MWD using refractive index detection. This information, when used to mathematically treat the whole asphalt distribution data, can correct the latter to include saturates as well, but can only partially account for continuous variation of the molar absorptivity.

  1. The Laconia, New Hampshire bottom ash paving project: Volume 3, Physical Performance Testing Report

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    Bottom ash is the principal waste stream from the combustion of municipal solid waste (MSW). It is comprised of grate ash (97%), the slag material discharged at the end of the grate system, and grate sifting (3%), the material that melts or falls through the grate structure. This project was conducted to demonstrate the feasibility of using municipal solid waste grate ash as an aggregate substitute in the construction of a pavement binder course for a portion of Rt. 3 in Laconia, New Hampshire. The research was conducted over a two year period during 1993 and 1994. This study is the culmination of an earlier two year characterization study between 1990 and 1992 that documented the physical and environmental characteristics of the bottom ash as it was produced at the Concord, N.H. waste-to-energy (@) facility and used in an asphaltic binder course. Together, these two studies provide a complete evaluation of the potential for using grate ash or bottom ash in asphalt binder course or as recycled asphalt pavement (RAP) in base courses in pavements.

  2. Experimental Study on Geocell-Reinforced Flexible Pavements with Recycled Asphalt Pavement (RAP) Bases under Cyclic Loading

    E-Print Network [OSTI]

    Acharya, B. S.

    2011-12-31T23:59:59.000Z

    ABSTRACT The reprocessed old hot mix asphalt (HMA) concrete also called "Recycled Asphalt Pavement (RAP)", if used to build new roads or to maintain existing roads, would have several benefits, such as preservation of natural resources for future...

  3. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded Viscoelastic Model, Part-I: Development,

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded simulations, correspondence principle, finite-element method Abstract. Asphalt concrete pavements to climatic conditions are the major cause of such graded non-homogeneity. Current pavement analysis

  4. Microstructural Characterization of the Chemo-mechanical Behavior of Asphalt in Terms of Aging and Fatigue Performance Properties

    E-Print Network [OSTI]

    Allen, Robert Grover

    2013-03-27T23:59:59.000Z

    The study of asphalt chemo-mechanics requires a basic understanding of the physical properties and chemical composition of asphalt and how these properties are linked to changes in performance induced by chemical modifications. This work uniquely...

  5. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  6. Microstructural Characterization of Material Properties and Damage in Asphalt Composites 

    E-Print Network [OSTI]

    Mohammad Khorasani, Sara

    2013-05-03T23:59:59.000Z

    by NPRP grant # 08-310-2-110 from the Qatar National Research Fund (a member of Qatar Foundation). The statements made herein are solely the responsibility of the authors. vi TABLE OF CONTENTS Page ABSTRACT... ........................................................................................................................ 17 3D Experimental Investigation of the Microstructure of Cement Pastes Using Synchrotron X-Ray Microtomography (?CT) .......................................................... 18 Dynamic Modulus Simulation of the Asphalt Concrete Using the X...

  7. Effect of pavement temperature on the macrotexture of a semidense asphalt surface

    E-Print Network [OSTI]

    Boyer, Edmond

    Effect of pavement temperature on the macrotexture of a semidense asphalt surface J. Luong, M the pavement temperature could change the texture surface of the pavement. The aim of this work is to analyze the influence of the surface temperature on the macrotexture of a semidense asphalt pavement located in an urban

  8. Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1

    E-Print Network [OSTI]

    Aydilek, Ahmet

    Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1 and Ahmet H. Aydilek2 2007 133:7 406 CE Database subject headings: Moisture; Asphalt concrete; Dynamics; Hydraulic and Magdalena 2002 ; however, limited research has been conducted in modeling dynamic flow in porous geomedia

  9. RESEARCH REPORT 987-9 ASPHALT OVERLAY DESIGN METHODS FOR RIGID

    E-Print Network [OSTI]

    Texas at Austin, University of

    by using a fractional factorial design. An analysis of variance (ANOVA) was performed to identifyRESEARCH REPORT 987-9 ASPHALT OVERLAY DESIGN METHODS FOR RIGID PAVEMENTS CONSIDERING RUTTING's Catalog No. 5. Report Date October 1998 4. Title and Subtitle ASPHALT OVERLAY DESIGN METHODS FOR RIGID

  10. Characterization of asphalt cements modified with crumbed rubber from discarded tires. Final report

    SciTech Connect (OSTI)

    Daly, W.H.; Negulescu, I.I.

    1994-11-01T23:59:59.000Z

    The potential legislative requirement for incorporation of scrap rubber into asphalt blends mandated a thorough evaluation of the influence of scrap rubber additives on the physical properties and aging characteristics of rubber/asphalt blends. Blends with up to 20 percent ground vulcanized rubber (both crumb and 200 mesh powder particles) from recycled tires were prepared with asphalt cements of various grades (AC5 - AC30) and evaluated using DMA. Blends produced from powdered rubber particles exhibited Newtonian behavior at high temperatures; similar behavior was not observed with crumb rubber blends. The mechanical properties of asphalt-rubber blends depend upon the concentration of rubber additives, the particle dimensions, and the chemical composition of the asphalt.

  11. Analytical-Numerical Methodology to Measure Undamaged, Fracture and Healing Properties of Asphalt Mixtures

    E-Print Network [OSTI]

    Koohi, Yasser 1980-

    2012-08-29T23:59:59.000Z

    ....................................................................................................... 66? Methodology .................................................................................................... 67? Finite Element Duplication of the Test ........................................................ 68? Development of the Crack... the Crack .................................................................. 117? Results for the Fracture and Healing Properties ......................................... 118? Concluding Remarks...

  12. An evaluation of permanent deformation properties of crumb rubber modified (CRM) asphalt concrete mixtures

    E-Print Network [OSTI]

    Makunike, Danai Ellarin

    1995-01-01T23:59:59.000Z

    applications, while the remainder is dumped in stockpiles as scrap. Tire stockpiles pose an environmental threat as fire and health hazards. As a result, government agencies have taken action to mandate the recycling of waste tire rubber by state transportation...

  13. Evaluation of Moisture Susceptibility of Warm Mix Asphalt

    E-Print Network [OSTI]

    Garcia Cucalon, Maria Lorena

    2013-05-03T23:59:59.000Z

    . To evaluate WMA moisture susceptibility during this critical period, standard laboratory tests were used for three field projects each with an HMA control mixtures and multiple WMA mixtures. Different specimen types were also evaluated to capture differences...

  14. Evaluation of moisture damage within asphalt concrete mixes 

    E-Print Network [OSTI]

    Shah, Brij D.

    2004-09-30T23:59:59.000Z

    as bond energy in order to predict moisture damage. Mixtures with the two types of bitumen and each aggregate with and without hydrated lime were evaluated. The hydrated lime substantially improved the resistance of the mixture to moisture damage....

  15. 5th Eurasphalt & Eurobitume Congress, 13-15th June 2012, Istanbul THIXOTROPIC BEHAVIOUR OF PAVING GRADE BITUMENS UNDER DYNAMIC

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    OF PAVING GRADE BITUMENS UNDER DYNAMIC SHEAR Virginie Mouillet1 , Chantal De La Roche2 , Emmanuel Chailleux2 relevant results. Here we focus on bitumens known for quite a long time (Stinsky, 1975; Stefanczyk, 1993

  16. Influence of fundamental material properties and air void structure on moisture damage of asphalt mixes 

    E-Print Network [OSTI]

    Arambula Mercado, Edith

    2009-05-15T23:59:59.000Z

    parameters were obtained using mechanical tests and surface energy measurements. The microstructure of asphalt mixes prepared in the laboratory having different air void structures was captured using X-ray CT, and image analysis techniques were used...

  17. Evaluation of healing in asphalt binders using dynamic shear rheometer and molecular modeling techniques 

    E-Print Network [OSTI]

    Bommavaram, Ramamohan Reddy

    2009-05-15T23:59:59.000Z

    A self-healing material has the inherent ability to partially reverse damage such as crack formation that might have occurred during its service. Significant evidence exists in the literature to indicate that asphalt binder is a self...

  18. A Continuum Coupled Moisture-mechanical Constitutive Model for Asphalt Concrete

    E-Print Network [OSTI]

    Shakiba, Maryam

    2013-12-09T23:59:59.000Z

    procedure and give insight into the various damage inducing mechanisms in asphalt concrete. In this dissertation, thermo-hygro-mechanical constitutive relationships are developed based on the principle of virtual power and laws of thermodynamics in order...

  19. Chip Seals for Asphalt Concrete Pavements: A Proposed Emulsion Residue Specification and Existing Pavement Texture Evaluation

    E-Print Network [OSTI]

    Hoyt, Denise

    2012-07-16T23:59:59.000Z

    Chip seals are a pavement surface treatment used for maintaining asphalt concrete pavements. National Cooperative Highway Research Program (NCHRP) Project 14-17 was performed to produce a national Chip Seal Manual which would consolidate the best...

  20. Development of superior asphalt recycling agency: Phase 1, Technical feasibility. Technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Glover, C.J.; Davison, R.R.; Lin, Moon-Sun; Chaffin, J.; Liu, Meng; Eckhardt, C.

    1996-04-01T23:59:59.000Z

    About every 12 years, asphalt roads must be reworked, and this is usually done by placing thick layers (hot-mix overlays) of new material on top of failed material, resulting in considerable waste of material and use of new asphalt binder. A good recycling agent is needed, not only to reduce the viscosity of the aged material but also to restore compatibility. Objective is to establish the technical feasibility (Phase I) of determining the specifications and operating parameters for producing high quality recycling agents which will allow most/all the old asphalt-based road material to be recycled. It is expected that supercritical fractionation can be used. The advanced road aging simulation procedure will be used to study aging of blends of old asphalt and recycling agents.

  1. A program to design asphalt concrete overlays to mitigate reflection cracking

    E-Print Network [OSTI]

    Satyanarayana Rao, Sindhu

    2002-01-01T23:59:59.000Z

    of the research are to understand the occurrence and behavior of reflection cracking and for devising ways of mitigating them and to put together an effective and complete package of computer programs to design asphalt concrete overlays. Another primary objective...

  2. Evaluation of healing in asphalt binders using dynamic shear rheometer and molecular modeling techniques

    E-Print Network [OSTI]

    Bommavaram, Ramamohan Reddy

    2009-05-15T23:59:59.000Z

    the parameters of characteristic healing function of asphalt binders. In the second part of this study, Molecular Modeling (MM) techniques were used to determine the interrelationship between molecular structure, surface free energy, self diffusivity, and other...

  3. Automated Protocol for the Analysis of Dynamic Mechanical Analyzer Date from Fine Aggregate Asphalt Mixes 

    E-Print Network [OSTI]

    Cavalcanti De Sousa, Pedro

    2010-10-12T23:59:59.000Z

    Fatigue cracking and moisture damage are two important modes of distresses in asphalt pavements. Recently, the Dynamic Mechanical Analyzer (DMA) was used to characterize fatigue cracking and evaluate the effects of moisture ...

  4. The morphology of polymer modified asphalt and its relationship to rheology and durability

    E-Print Network [OSTI]

    Kraus, Zachary Rothman

    2008-10-10T23:59:59.000Z

    % % loglog * deg6010* deg6010 ?? , where d%A is the change in asphaltene in the asphalt (19). The other theory is that only the polar aromatics and napthene aromatics fluoresce when separated from the asphalt binder (16). Therefore as polar and napthene... aromatics change to asphaltenes with oxidative aging, the brightness would decrease. This brightness decrease would correspond to the increase in asphaltene with carbonyl area leading to a graph that looks like a chart for hardening susceptibility...

  5. An investigation of three problems concerning the analysis of airborne asphalt fumes

    E-Print Network [OSTI]

    Laird, Larry Teal

    1981-01-01T23:59:59.000Z

    AN INVESTIGATION OF THREE PROBLEMS CONCERNING THE ANALYSIS OF AIRBORNE ASPHALT FUMES A Thesis by LARRY TEAL LAIRD Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE May 1981 Major Subject: Industrial Hygiene AN INVESTIGATION OF THREE PROBLEMS CONCERNING THE ANALYSIS OF AIRBORNE ASPHALT FUMES A Thesis by LARRY T. LAIRD Approved as to style and content by: (Chairm of Committee) (Head of Department...

  6. Standards Pave the Way for Next Generation Workplace Charging Technology Opportunities/Decisions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretaryVideosSpring O&M UsersEnergy Standards Pave the Way

  7. Development of statistical wet weather model to evaluate frictional properties at the pavement-tire interface on hot mix asphalt concrete

    E-Print Network [OSTI]

    Bedi, Harpreet

    2001-01-01T23:59:59.000Z

    Skid resistance on wet pavements is influenced by friction at the tire-pavement interface as well as overall hot mix asphalt (HMA) performance. It is important to control aggregate, asphalt, and mix properties to achieve desirable frictional...

  8. Application of Metagenomics for Identification of Novel Petroleum Hydrocarbon Degrading Enzymes in Natural Asphalts from the Rancho La Brea Tar Pits

    E-Print Network [OSTI]

    Baquiran, Jean-Paul Mendoza

    2010-01-01T23:59:59.000Z

    and the origin of heavy oil. Nature, 426, 344-352. HEITKAMP,natural asphalts and heavy oil compounds. A major questionmainly of asphalts and heavy oils, which have saturated into

  9. Evaluation of moisture damage within asphalt concrete mixes

    E-Print Network [OSTI]

    Shah, Brij D.

    2004-09-30T23:59:59.000Z

    with load cycles. The analysis demonstrates the need to consider mixture compliance as well as bond energy in order to predict moisture damage. Mixtures with the two types of bitumen and each aggregate with and without hydrated lime were... evaluated. The hydrated lime substantially improved the resistance of the mixture to moisture damage. iv To my parents. v ACKNOWLEDGMENTS I would like to extend my sincere thanks to everyone who helped...

  10. Department of Energy and Mineral Engineering Spring Roller Design to Increase the Lifespan of Asphalt Compactor Wiper Blades

    E-Print Network [OSTI]

    Demirel, Melik C.

    the Lifespan of Asphalt Compactor Wiper Blades By: Thomas Krupa, Eric Resch, Phillip Yesenosky, John Marshall, Asset Kusmanov Overview Volvo CE's asphalt compactors have a polymer wiper blade that is used life. o The roller was tested five times as long as the wipers and never showed any change in diameter

  11. Development of superior asphalt recycling agents. Phase 1, Technical feasibility. Final technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J.; Chaffin, J.; Liu, M.; Madrid, R.

    1997-07-01T23:59:59.000Z

    After an introduction and a literature survey in Chap. 1, Chap. 2 describes the tasks, together with objectives and important results obtained for each task throughout the entire project. Chaps. 3 thru 7 detail work in developing a qualitative and quantitative knowledge of asphalt oxidation, composition dependence of asphalt properties, and guidelines for producing superior asphalt binders through composition control. They also detail the development of a kinetic model for asphalt oxidative aging and present an understanding of the composition dependence of asphalt oxidation as well as other performance-related properties. Chaps. 8 and 9 compare the aging performance of recycled blends produced using commercial recycling agents and industrial supercritical fractions as rejuvenating agents. Oxidative aging of the recycled blends were evaluated along with the performance of the recycled blends in terms of the strategic highway research program performance grading procedure. Chap. 10 summarizes the work completed in the areas of processing schemes development, projection updates, and scale-up and commercialization plans.

  12. Effects of carboxylic acids on the rheological properties of crumb rubber modified asphalt

    SciTech Connect (OSTI)

    Tauer, J.E.; Robertson, R.E. [Western Research Institute, Laramie, WY (United States)

    1996-12-31T23:59:59.000Z

    The Federal mandate of 1991-1995 on the use of scrap tires in Federal roadway construction sparked a major interest in gaining a fundamental understanding of the behavior of rubber in asphalt. This study is a systematic elucidation of what chemistry controls the final crumb rubber modified asphalt (CRMA) product quality. We discovered that the type and total acid content in the asphalt are the most influential chemical factors that determine the changes in the important roadway properties of shear modulus (G*) and loss angle ({delta}) of CRMA. Low acid (<0.005 m/L) asphalts were modified with three types of carboxylic acid and each made into CRMA using typical field mixing conditions of 1 hour at 175{degrees}C. Rheological measurements were then made at various storage times up to 192 hours following storage at both 156 and 200{degrees}C. We found the changes in CRMA theological properties correspond to the acid type spiked into the asphalt.

  13. Viscoroute 2.0: a tool for the simulation of moving load effects on asphalt pavement

    E-Print Network [OSTI]

    Chabot, Armelle; Deloffre, Lydie; Duhamel, Denis

    2010-01-01T23:59:59.000Z

    As shown by strains measured on full scale experimental aircraft structures, traffic of slow-moving multiple loads leads to asymmetric transverse strains that can be higher than longitudinal strains at the bottom of asphalt pavement layers. To analyze this effect, a model and a software called ViscoRoute have been developed. In these tools, the structure is represented by a multilayered half-space, the thermo-viscoelastic behaviour of asphalt layers is accounted by the Huet-Sayegh rheological law and loads are assumed to move at constant speed. First, the paper presents a comparison of results obtained with ViscoRoute to results stemming from the specialized literature. For thick asphalt pavement and several configurations of moving loads, other ViscoRoute simulations confirm that it is necessary to incorporate viscoelastic effects in the modelling to well predict the pavement behaviour and to anticipate possible damages in the structure.

  14. Asphalt emulsion radon barrier systems for uranium mill tailings: an overview of the technology

    SciTech Connect (OSTI)

    Baker, E.G.; Hartley, J.N.; Freeman, H.D.; Gates, T.E.; Nelson, D.A.; Dunning, R.L.

    1984-03-01T23:59:59.000Z

    Pacific Northwest Laboratory (PNL), under contract to the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) office, has developed an asphalt emulsion cover system to reduce the release of radon from uranium mill tailings. The system has been field tested at Grand Junction, Colorado. Results from laboratory and field tests indicate that this system is effective in reducing radon release to near-background levels (<2.5 pCi m/sup -2/s/sup -1/) and has the properties required for long-term effectiveness and stability. Engineering specifications have been developed, and analysis indicates that asphalt emulsion covers are cost-competitive with other cover systems. This report summarizes the technology for asphalt emulsion radon barrier systems. 59 references, 45 figures, 36 tables.

  15. Application of pyrolized carbon black from scrap tires in asphalt pavement design and construction

    SciTech Connect (OSTI)

    Park, T.; Coree, B.J. [Indiana Department of Transportation, West Lafayette, IN (United States). Division of Research; Lovell, C.W. [Purdue Univ., West Lafayette, IN (United States). School of Civil Engineering

    1995-12-31T23:59:59.000Z

    According to EPA reports (1991) of the over 242 million waste generated each year in the United State, 5% are exported, 6% recycled, 11% incinerated, and 78% are landfilled, stockpiled, or illegally dumped. A variety of uses for these tires are being studied. Among these is pyrolysis which produces 5 5% of oil, 25% of carbon black, 9% of steel, 5% of fiber and 6% of gas. Pyrolized carbon black contains 9 % of ash, 4% of sulfur, 12% of butadine copolymer and 75% of carbon black. The objective of this research is to investigate the viability of using PCB as an additive in hot mix asphalt. The use of PCB in asphalt pavement is expected not only to improve the performance of conventional asphalt, but also to provide a means for the mass disposal of waste fires.

  16. Evaluation of Laboratory Conditioning Protocols for Warm-Mix Asphalt

    E-Print Network [OSTI]

    Yin, Fan 1990-

    2012-10-26T23:59:59.000Z

    orientation of field cores and on-site PMLC specimens were evaluated using the Dynamic Shear Rheometer (DSR) (AASHTO T315) and image analysis techniques, respectively. In addition, mixture stiffness in a wet condition was evaluated using the Hamburg Wheel...

  17. Project Description In the search for superior batteries, the road to success is paved with advanced materials: better

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    Project Description In the search for superior batteries, the road to success is paved with advanced materials: better cathodes, better anodes, better electrolytes. The universe of candidates is so vast and the cost of selection and testing them is so great that conventional approaches to materials

  18. Gene therapy rescues photoreceptor blindness in dogs and paves the way for treating human X-linked

    E-Print Network [OSTI]

    Bushman, Frederic

    Gene therapy rescues photoreceptor blindness in dogs and paves the way for treating human X to treated areas. Both rod and cone photoreceptor function were greater in treated (three of four) than mislocalization in treated areas expressing human RPGR protein in rods and cones. Postreceptoral remodeling

  19. Queen's researchers play part in laser breakthrough A new approach that will pave the way for a range of

    E-Print Network [OSTI]

    Paxton, Anthony T.

    . By simply directing a high-power, ultra-short laser pulse onto a thin solid foil, it is now possibleQueen's researchers play part in laser breakthrough A new approach that will pave the way a revolutionary laser-driven acceleration technique has been developed by an international team of physicists

  20. Studies of asphalt air blowing and development of a new short-term aging technique

    E-Print Network [OSTI]

    Vassiliev, Nicolai

    2001-01-01T23:59:59.000Z

    , Table m-2. Low temperature hardening properi. ies of air blown asphalt fractions and blends. Table III-3. Parent asphalt HS, oxidation rate, and HR . Table IV-1. Estimated time required to achieve same degrcc of aging as RTFOT for Exxon AC-10 films... of varying I. hickness . 70 Table IV-2 Effect of air blowing conditions for Exxon AC- I 0, 325 'F, 70 min. 70 Table IV-3. Condensed volatiles and RTFOT mass change . 80 Table IV-4. Reproducibility analysis. LIST OF FIGURES P ige Figure I-l. Thin film...

  1. Influence of coarse aggregate size, shape and surface texture on rutting of hot mix asphalt concrete

    E-Print Network [OSTI]

    Yeggoni, Mohan

    1993-01-01T23:59:59.000Z

    increased Hveem Stability, Marshall Stability and resistance to creep of hot mix asphalt concrete. The resilient modulus of the specimens was also enhanced by the increase in the amount of crushed aggregate in the mix at high temperatures (115'F). Fractal...

  2. The State of the Practice and Common Pitfalls for Porous Asphalt for

    E-Print Network [OSTI]

    of stormwater treatment systems · To provide resources to stormwater communities currently involved in design)-131 Porous Asphalt Pavements (2008) NAPA IS-115 Open-Graded Friction Courses (2002) 3 #12;Overview 1. State of the Practice 2. Water Quality Performance 3. Hydraulic Performance 4. Cold Climate

  3. Project Information Form Project Title Evaluation of the Combined Effect of Recycled Asphalt Pavement (RAP),

    E-Print Network [OSTI]

    California at Davis, University of

    Pavement (RAP), Recycled Asphalt Shingles (RAS), and Different Virgin Binder Sources on Performance of Research Project As virgin material sources become increasingly scarce, and the volume of pavement material for pavement construction. The California Department of Transportation (Caltrans) has recently increased

  4. Creep Compliance Analysis Technique for the Flattened Indirect Tension Test of Asphalt Concrete

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Creep Compliance Analysis Technique for the Flattened Indirect Tension Test of Asphalt Concrete: ­ Cored Sample (Cylindrical) Indirect tensile testing (IDT) (Strength/Creep) ­ AASHTO T-322 Damage under and Flattened IDT · 1000-sec creep tests on three replicates · 0, -10, and -20 deg. C · Displacement

  5. A comparison of the fracture properties of conventional and polymer-modified two-layer asphalt concrete overlay systems 

    E-Print Network [OSTI]

    Reddy, Praveena Gutha

    1996-01-01T23:59:59.000Z

    The problem of reflection cracking through the conventional asphalt concrete overlays has increased the need to find new materials which could resist cracking or fracture more effectively. It is for this reason that polymers ...

  6. A study of substitution solvents in asphalt fume extraction and the effects of heating duration and temperature 

    E-Print Network [OSTI]

    Curry, Noel Thomas

    1981-01-01T23:59:59.000Z

    may be used as substitute solvents for the solvent extraction analytical method for asphalt furres proposed by NlnSH and currently in use by OSHA. Benzene is known to orovide IC0% effic- 1 iency in asphalt fume extraction. The results..., rather than the solvents' effic- iency loss, was responsible for the differences. The importance of the data lies in the fact that the other two test solvents exhibited a consiatency equal to that of benzene. 'Ahile the exact coefficient of any...

  7. A study of sand-asphalt mixtures: a constitutive model based on a thermomechanical framework and experimental corroboration 

    E-Print Network [OSTI]

    Ravindran, Parag

    2009-06-02T23:59:59.000Z

    . In proportion to the quantity of its usage and in acknowledgment of modeling complexity, the material has been interrogated by many researchers using a variety of mechanical tests, and a plethora of linear viscoelastic models have been developed. Most models...

  8. INTRODUCTION Asphalt is a mixture of a wide variety of chemical compounds that include aliphatic hydrocarbons and highly fused

    E-Print Network [OSTI]

    Harms, Kyle E.

    hydrocarbons and highly fused aromatic ring systems.They are classified as asphaltenes (medium molecular weight

  9. A study of sand-asphalt mixtures: a constitutive model based on a thermomechanical framework and experimental corroboration

    E-Print Network [OSTI]

    Ravindran, Parag

    2009-06-02T23:59:59.000Z

    TABLE OF CONTENTS CHAPTER Page I INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . 1 A. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . 1 B. Focus of Research . . . . . . . . . . . . . . . . . . . . . . . 2 C. Outline... of Dissertation . . . . . . . . . . . . . . . . . . . . 4 II CONTINUUM PRELIMINARIES . . . . . . . . . . . . . . . . . 6 A. Notation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 B. Kinematics . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 C...

  10. 1 INTRODUCTION Flexural fatigue is one of the main failure modes in asphalt mixtures and flexible pavement

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    pavement structures. This means good prediction of a pavement's fatigue life will help to develop and im- prove pavement design procedures. Fatigue resistance and stiffness are two required parameters for pavement design necessary to dimension the pavement structure (layer thickness). European standards (EN

  11. Thickness estimation of subsurface layers in asphalt pavement using monstatic ground penetrating radar

    E-Print Network [OSTI]

    Lau, Chun Lok

    1991-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE December 1991 Major Subject: Electrical Engineering THICKNESS ESTIMATION OF SUBSURFACE LAYERS IN ASPHALT PAVEMENT USING MONSTATIC GROUND PENETRATING RADAR A Thesis CHUN LOK LAU Approved as to style and content by... ACKNOWLEDGEMENTS. LIST OF FIGURES. . CHAPTER I INTRODUCTION. 1. 1 Importance of pavement profile data. 1. 2 Principle of Ground Penetrating Radar (GPR) . . . 1. 3 Subsurface layer thickness measurement method. . . . . . II GPR ANTENNA AND SYSTEM CALIBRATION...

  12. Oxidative reactions and their impact on the properties of asphalt as a pavement binder

    E-Print Network [OSTI]

    Lau, Chee Keung

    1991-01-01T23:59:59.000Z

    mechanical spectrometer was found to increase with aging time. Correlation was shown to exist between the limiting complex viscosity and the carbonyl area as determined by infrared analysis. The correlation was unique for each asphalt and was independent... of aging temperature. The carbonyl area growth rate was a strong function of the aging temperature and the temperature dependence of the rate constant followed the Arrhenius relation within the temperature range tested. The results led...

  13. Viscosity, relaxation time, and dynamics within a model asphalt of larger molecules

    SciTech Connect (OSTI)

    Li, Derek D.; Greenfield, Michael L., E-mail: greenfield@egr.uri.edu [Department of Chemical Engineering, University of Rhode Island, Kingston, Rhode Island 02881 (United States)

    2014-01-21T23:59:59.000Z

    The dynamics properties of a new “next generation” model asphalt system that represents SHRP AAA-1 asphalt using larger molecules than past models is studied using molecular simulation. The system contains 72 molecules distributed over 12 molecule types that range from nonpolar branched alkanes to polar resins and asphaltenes. Molecular weights range from 290 to 890 g/mol. All-atom molecular dynamics simulations conducted at six temperatures from 298.15 to 533.15 K provide a wealth of correlation data. The modified Kohlrausch-Williams-Watts equation was regressed to reorientation time correlation functions and extrapolated to calculate average rotational relaxation times for individual molecules. The rotational relaxation rate of molecules decreased significantly with increasing size and decreasing temperature. Translational self-diffusion coefficients followed an Arrhenius dependence. Similar activation energies of ?42 kJ/mol were found for all 12 molecules in the model system, while diffusion prefactors spanned an order of magnitude. Viscosities calculated directly at 533.15 K and estimated at lower temperatures using the Debye-Stokes-Einstein relationship were consistent with experimental data for asphalts. The product of diffusion coefficient and rotational relaxation time showed only small changes with temperature above 358.15 K, indicating rotation and translation that couple self-consistently with viscosity. At lower temperatures, rotation slowed more than diffusion.

  14. DEVELOPMENT OF A RAPID TEST TO DETERMINE MOISTURE SENSTIVITY OF HMA (SUPERPAVE) MIXTURES

    E-Print Network [OSTI]

    Shiwakoti, Harihar

    2007-12-14T23:59:59.000Z

    Exiting test methods to determine moisture sensitivity in hot mix asphalt are time consuming and inconsistent. This research focused on wheel tracking devices to develop a rapid test method to evaluate moisture sensitivity. The Asphalt Pavement...

  15. Experimental Study on Shear Fatigue Behavior and Stiffness Performance of Warm Mix Asphalt by adding Synthetic Wax

    E-Print Network [OSTI]

    Petit, Christophe; Canestrari, Francesco; Pannunzio, Valter; Virgili, Amadeo

    2012-01-01T23:59:59.000Z

    Synthetic waxes produced by standard and registered processes may be used to manufacture Warm Mix Asphalt (WMA), which is a modified asphalt concrete produced, applied and compacted at temperatures below those typically required. This feature leads to environmental benefits, such as reduced energy consumption, gas and fume emissions, as well as to economic/operational advantages, such as lower production costs and greater hauling distances for extended construction seasons with tighter schedules. The present article serves to compare the mechanical performance of a WMA produced by adding synthetic wax with a traditional Hot Mix Asphalt (HMA) specimen, in terms of shear fatigue response and both complex and stiffness moduli. The experimental results and related modeling work demonstrate that adding synthetic wax into the WMA composition does not hinder either the destructive or non-destructive performance of an HMA, and this finding is corroborated by respectively measuring fatigue life and stiffness.

  16. Experimental Study on Shear Fatigue Behavior and Stiffness Performance of Warm Mix Asphalt by adding Synthetic Wax

    E-Print Network [OSTI]

    Christophe Petit; Anne Millien; Francesco Canestrari; Valter Pannunzio; Amadeo Virgili

    2012-03-13T23:59:59.000Z

    Synthetic waxes produced by standard and registered processes may be used to manufacture Warm Mix Asphalt (WMA), which is a modified asphalt concrete produced, applied and compacted at temperatures below those typically required. This feature leads to environmental benefits, such as reduced energy consumption, gas and fume emissions, as well as to economic/operational advantages, such as lower production costs and greater hauling distances for extended construction seasons with tighter schedules. The present article serves to compare the mechanical performance of a WMA produced by adding synthetic wax with a traditional Hot Mix Asphalt (HMA) specimen, in terms of shear fatigue response and both complex and stiffness moduli. The experimental results and related modeling work demonstrate that adding synthetic wax into the WMA composition does not hinder either the destructive or non-destructive performance of an HMA, and this finding is corroborated by respectively measuring fatigue life and stiffness.

  17. Establishing material properties for thin asphalt concrete surfaces on granular bases

    E-Print Network [OSTI]

    Rosson, Barry Thomas

    1985-01-01T23:59:59.000Z

    cross-section of a Goodyear Hi -Miler 10. 00-20 14-ply bias truck tire carcass was obtained; the input data for the Tielking tire model was developed by measuring cord locations, angles, and plies on a section of the tire; and the tire pressure.... Since little work in the past has been done in the area of thin asphalt concrete surface analysis, re-evaluation of several assumptions concerning the tire load were necessary. The truck tire pressures on Texas highways have dramatically increased...

  18. The Effects of Using Alkali-Silica Reaction Affected Recycled Concrete Aggregate in Hot Mix Asphalt

    E-Print Network [OSTI]

    Geiger, Brian James

    2011-10-21T23:59:59.000Z

    mix asphalt (HMA) were investigated in this study. Dilatometer and modified beam tests were performed to determine the possibility of new ASR occurring in reactive aggregates within the HMA or re-expansion of existing gel. The Lottman test... (XRD) was used to check for the potential presence of gel in the filler fraction of the ASR-RCAs. Micro-deval and freeze-thaw tests were evaluated for their potential to indicate the presence of excess micro-cracks or ASR gel. Expansion testing...

  19. Whole House Thermal Performance of Asphalt Shingles Exploiting Special Infrared Reflective Pigments

    E-Print Network [OSTI]

    Hahn, L.; Miller, W.; Desjarlais, A.; Jacobs, J.; Youngquist, A.

    2006-01-01T23:59:59.000Z

    -04 using cycle 4 as described in Table X2.1, Common Exposure Conditions, of the G 154 standard (ASTM 2002b). A UVB-340 lamp was used for simulating direct solar UV radiation; this lamp has no UV output below 300 nm, which is the cutoff wavelength... for this behavior is unknown; overall, however, the data clearly show that the IRR shingles perform just as well when subjected to direct solar UV radiation as standard products accepted on the open market. The IRR asphalt shingles do not lose solar reflectance...

  20. Laboratory measured characteristics of hot-mix asphaltic concrete as related to field performance

    E-Print Network [OSTI]

    TenBrook, James Joseph

    1966-01-01T23:59:59.000Z

    Laboratory Army Corps of Engineers Study o THD 1';otorized Press Gyratory Testing 1'~machine ~'marshall Device California Ilachine 1G Field Test Sites Test Section Layout 12 Maco Section Layout 13 Paving A Test Section 14 Coring One Meek Samples 15... molded in their laboratories at the standard $0 blow compactive effort. These marshall specimens were used to provide density and stability data; and to provide a means of comparison between field and laboratory specimens. The significant conclusions...

  1. Porous Asphalt Pavement for Stormwater Management The UNH Stormwater Center Web: www.unh.edu/erg/cstev/

    E-Print Network [OSTI]

    Porous Asphalt Pavement for Stormwater Management The UNH Stormwater Center Web: www. Extended Pavement Life Due to Well Drained Base and Reduced Freeze-Thaw Disadvantages · Requires Routine. Standard Pavement Applications where Stormwater Infrastructure is Required · Materials Cost is ~20-25% More

  2. SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer

    E-Print Network [OSTI]

    California at Berkeley, University of

    SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer PAVEMENT TECHNOLOGY UPDATE This Technology Transfer Program publication is provided by the University of California Pavement Research Center. The University of California Pavement

  3. Recycling spent sandblasting grit and similar wastes as aggregate in asphaltic concrete. Technical data sheet

    SciTech Connect (OSTI)

    Heath, J.C.; Nelson, B.

    1998-12-01T23:59:59.000Z

    The Naval Facilities Engineering Service Center (NFESC), Port Hueneme, California, and Naval Facilities Engineering Command Engineering Field Activity, West, San Bruno, California, took overall leadership in identifying and testing methods to manage waste generated from a machine shop located at Hunters Point Annex, at Naval Station, Treasure Island, California. Ship cleaning and equipment maintenance resulted in the accumulation of 4,665 tons of spent sandblasting grit at the site. The spent grit, consisting of silica sand plus a small amount of slag-derived grit, had the physical characteristics of coarse-grained beach sand and also contained fragments of coatings. The spent grit had the potential for exhibiting hazardous characteristics since the coatings included lead-based primers, copper, and butyltin-containing antifouling topcoats. The most beneficial application of reusing the spent grit was to use it as a replacement for some of the fine aggregate in asphaltic concrete. A test program was established that included characterization, bench-scale testing, long-term pilot scale testing, and a full-scale demonstration. Full-scale asphalt production provided samples which proved both the chemical leaching resistance and physical performance characteristics were acceptable.

  4. Two- and Three-Dimensional Microstructural Modeling of Asphalt Particulate Composite Materials using a Unified Viscoelastic-Viscoplastic-Viscodamage Constitutive Model

    E-Print Network [OSTI]

    You, Taesun

    2013-08-13T23:59:59.000Z

    The main objective of this study is to develop and validate a framework for microstructural modeling of asphalt composite materials using a coupled thermo-viscoelastic, thermo-viscoplastic, and thermo-viscodamage constitutive model. In addition...

  5. The Self-Ignition Temperatures of Bitumen Mixtures Containing Transition Metal Nitrates

    SciTech Connect (OSTI)

    Okada, Ken; Nomura, Masao; Fujii, Yasuhiko [Tokyo Institute of Technology (Japan)

    2000-01-15T23:59:59.000Z

    Information is provided on the self-ignition temperature (SIT) of blown bitumen asphalt mixed with sodium nitrate and some chemicals that are added in the bituminization process to adjust pH and to immobilize the radioactive isotopes of Cs, Sr, and I. In each ignition temperature test, the prepared bitumen sample was heated at a constant rate of temperature increase, and the ignition point was measured. Among the tested chemicals added to the bitumen, Ni(NO{sub 3}){sub 2} shows a relatively large SIT decrease, and furthermore, the mixture of Ni(NO{sub 3}){sub 2} and AgNO{sub 3} has been shown to greatly lower the SIT of blown bitumen. It is suggested that, in general, segregation of these nitrates should be avoided in bituminization, and care should be taken in handling Ag in a Purex reprocessing plant from the viewpoint of waste treatment. Furthermore, the oxidation effects of Fe(NO{sub 3}){sub 3} were tested by measuring torque of the bitumen sample. It was confirmed that the addition of Fe(NO{sub 3}){sub 3} to bitumen rapidly oxidizes the bitumen and increases the viscosity of the bitumen mixture.

  6. Mixture Designs 1. Design and Analysis of Mixture Experiments

    E-Print Network [OSTI]

    Buyske, Steve

    the total amounts of the components. In product formulations, examples would be gasoline, soaps for a mixture model, the i 's will not be uniquely de- termined. We could choose to eliminate one of the xi 's

  7. Electrochemical assessment and service-life prediction of mechanically stabilized earth walls backfilled with crushed concrete and recycled asphalt pavement

    E-Print Network [OSTI]

    Esfeller, Michael Watts, Jr.

    2009-06-02T23:59:59.000Z

    Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 2006 Major Subject: Civil Engineering ELECTROCHEMICAL ASSESSMENT AND SERVICE-LIFE PREDICTION... OF MECHANICALLY STABILIZED EARTH WALLS BACKFILLED WITH CRUSHED CONCRETE AND RECYCLED ASPHALT PAVEMENT A Thesis by MICHAEL WATTS ESFELLER, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  8. Genotoxicity of complex chemical mixtures

    E-Print Network [OSTI]

    Phillips, Tracie Denise

    2009-05-15T23:59:59.000Z

    aromatic hydrocarbon (PAH) fraction. The genotoxicity of these mixtures were assessed via analytical quantification, in vitro (Salmonella microsome and E. coli prophage induction) and in vivo (32P-postlabeling) bioassays. The NF was further tested...

  9. Application of surface energy measurements to evaluate moisture susceptibility of asphalt and aggregates

    E-Print Network [OSTI]

    Zollinger, Corey James

    2005-08-29T23:59:59.000Z

    Conditions 64 17 DMA Linear Viscoelastic Phase Angle in Both Dry and Wet Conditions ......... 64 18 Mixture Rankings according to Average Fatigue Life in Both Dry and Wet Conditions.........................................................................................66 19 Mixture Rankings according to Reduction in Dynamic Modulus (G*/Go) at Fatigue Life in Both Dry and Wet Conditions.................................. 68 20 Average E1 and m Values...

  10. Value-added utilisation of recycled concrete in hot-mix asphalt

    SciTech Connect (OSTI)

    Wong, Yiik Diew [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Sun, Darren Delai [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)]. E-mail: ddsun@ntu.edu.sg; Lai, Dickson [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2007-07-01T23:59:59.000Z

    The feasibility of partial substitution of granite aggregate in hot-mix asphalt (HMA) with waste concrete aggregate was investigated. Three hybrid HMA mixes incorporating substitutions of granite fillers/fines with 6%, 45% untreated, and 45% heat-treated concrete were evaluated by the Marshall mix design method; the optimum binder contents were found to be 5.3%, 6.5% and 7.0% of grade Pen 60/70 bitumen, respectively. All three hybrid mixes satisfied the Marshall criteria of the Singapore Land Transport Authority (LTA) W3B wearing course specification. The hybrid mix with 6% concrete fillers gave comparable resilient modulus and creep resistance as the conventional W3B mix, while hybrid mixes with higher concrete substitutions achieved better performance. X-ray diffraction (XRD) showed the distinct presence of free lime in the heat-treated concrete, while the scanning electron microscope (SEM) provided an in-depth perspective of the concrete grains in the HMA matrix. The results suggest feasible use of waste concrete as partial aggregate substitution in HMA.

  11. Compaction Effects on Uniformity, Moisture Diffusion, and Mechanical Properties of Asphalt Pavements

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman Ahmed

    2011-08-08T23:59:59.000Z

    in gyratory specimens were related to the mixture mechanical properties measured using the Overlay and Hamburg tests. The second part of this study focused on studying the relationship between air void distribution and moisture diffusion. A laboratory test...

  12. A field demonstration project utilizing FBC/PCC residues for paving materials. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Ghafoori, N. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Civil Engineering and Mechanics

    1994-12-31T23:59:59.000Z

    Research has been undertaken into engineering properties of roller compacted concretes containing fluidized bed combustion/pulverized coal combustion (FBC/PCC) by-products as well as FBC/PCC-Portland Cement concrete mixtures prepared using conventional placement technique. This laboratory effort has resulted in identification of a number of potentially viable commercial applications for the FBC by-products residues derived from Illinois high-sulfur coal. One potential and promising application of the FBC/PCC solid waste residues, which also accounts for the large utilization of coal-based by-product materials, is in pavement construction. The proposal presented herein is intended to embark into a new endeavor in order to bring the commercialization aspect of the initial laboratory project a step closer to reality by conducting a field demonstration of the optimized mixtures identified during the two-year laboratory investigation. A total of twenty-three different pavement slabs will be constructed at an identified site located in the Illinois Coal Development Park, Carterville, Illinois, by two construction contractors who are part of the industrial participants of the initial project and have expressed interest in the construction of experimental slabs. Both conventional and roller compacted concrete placement techniques will be utilized. All sections will be subjected to an extensive engineering evaluation and will be monitored for nearly a year for both short and long-term performance. The field results will be compared to that of the equivalent laboratory-prepared mixes in order to ascertain the suitability, of the proposed mixes for field application. During this reporting period, the physico-chemical and preconditioning characteristics of the raw materials were evaluated. Construction of the experimental road consisting of twenty-three surface and base course slab sections was also completed.

  13. Poisson Mixtures Kenneth W. Church

    E-Print Network [OSTI]

    Church, Kenneth W.

    is a well­known special case where f is a G distribution.) Poisson mixtures fit the data better than Books 1632 Brown Corpus 1645 Wall Street Journal 5600 Associated Press 1994 8514 Associated Press 1987 9525 Associated Press 1991 9861 Associated Press 1990 10,040 Associated Press 1989 10,195 Associated

  14. A study of substitution solvents in asphalt fume extraction and the effects of heating duration and temperature

    E-Print Network [OSTI]

    Curry, Noel Thomas

    1981-01-01T23:59:59.000Z

    (denoted Dl). Duration two ( D2) ran from time 60 minutes to time 90 minutes, Dl and DZ were separated by a 30 minute period in wh i ch no sampling occurred. The total time of heati ng at this temperature range was 90 minutes, which was near the limit... of the filter to hold it in position, and the cassette cap was placed on top of this. 3oth ends were then plugged. (Figure 2) After a warming period of approximately 30 minutes, the temperature of the liquid asphalt was raised to 250 C. iihen it reached...

  15. A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products

    SciTech Connect (OSTI)

    Levinson, Ronnen; Akbari, Hashem; Berdahl, Paul; Wood, Kurt; Skilton, Wayne; Petersheim, Jerry

    2009-11-20T23:59:59.000Z

    The widespread use of solar-reflective roofing materials can save energy, mitigate urban heat islands and slow global warming by cooling the roughly 20% of the urban surface that is roofed. In this study we created prototype solar-reflective nonwhite concrete tile and asphalt shingle roofing materials using a two-layer spray coating process intended to maximize both solar reflectance and factory-line throughput. Each layer is a thin, quick-drying, pigmented latex paint based on either acrylic or a poly(vinylidene fluoride)/acrylic blend. The first layer is a titanium dioxide rutile white basecoat that increases the solar reflectance of a gray-cement concrete tile from 0.18 to 0.79, and that of a shingle surfaced with bare granules from 0.06 to 0.62. The second layer is a 'cool' color topcoat with weak near-infrared (NIR) absorption and/or strong NIR backscattering. Each layer dries within seconds, potentially allowing a factory line to pass first under the white spray, then under the color spray. We combined a white basecoat with monocolor topcoats in various shades of red, brown, green and blue to prepare 24 cool color prototype tiles and 24 cool color prototypes shingles. The solar reflectances of the tiles ranged from 0.26 (dark brown; CIELAB lightness value L* = 29) to 0.57 (light green; L* = 76); those of the shingles ranged from 0.18 (dark brown; L* = 26) to 0.34 (light green; L* = 68). Over half of the tiles had a solar reflectance of at least 0.40, and over half of the shingles had a solar reflectance of at least 0.25.

  16. Environmental toxicity of complex chemical mixtures

    E-Print Network [OSTI]

    Gillespie, Annika Margaret

    2009-05-15T23:59:59.000Z

    and inorganic constituents, as well as the pharmacokinetics and potential interactions of chemical mixtures. This research was conducted to investigate the potential genotoxic effects of complex chemical mixtures of polycyclic aromatic hydrocarbons (PAHs...

  17. Binary mixture flammability characteristics for hazard assessment 

    E-Print Network [OSTI]

    Vidal Vazquez, Migvia del C.

    2005-11-01T23:59:59.000Z

    can be estimated using a computational method and available information. The information needed for mixture flash point predictions are flashpoints, vapor pressures, and activity coefficients as functions of temperature for each mixture component...

  18. Asphaltenes and Asphalts, 2. Developments in Petroleum Science, 40 B edited by T.F. Yen and G.V. Chilingarian

    E-Print Network [OSTI]

    Ã?agin, Tahir

    Asphaltenes and Asphalts, 2. Developments in Petroleum Science, 40 B edited by T.F. Yen and G OF ASPHALTENES: A PREDICTIVE APPROACH BASED ON COMPUTER ASSISTED STRUCTURE ELUCIDATION AND ATOMISTIC SIMULATIONS, asphaltenes and resins [1­4]. Asphaltenes are operationally defined as the non-volatile and polar fraction

  19. Entanglement teleportation via Bell Mixture

    E-Print Network [OSTI]

    Sibasish Ghosh; Guruprasad Kar; Anirban Roy; Debasis Sarkar; Ujjwal Sen

    2001-07-10T23:59:59.000Z

    We investigate the teleportation of the bipartite entangled states through two equally noisy quantum channels, namely mixture of Bell states. There is a particular mixed state channel for which all pure entanglement in a known Schmidt basis remain entangled after teleportation and it happens till the channel state remains entangled. Werner state channel lacks both these features. The relation of these noisy channels with violation of Bell's inequality and 2-E inequality is studied.

  20. Application of Direct Tension Testing to Laboratory Samples to Investigate the Effects of Hot Mix Asphalt Aging

    E-Print Network [OSTI]

    Padigala, Meghana 1989-

    2012-12-07T23:59:59.000Z

    to design mixtures taking this phenomenon into account and achieving maximum durability is an important and complex issue. This study was aimed at characterizing the effects of oxidative aging on durability in terms of mixture fatigue resistance...

  1. Ultrasonic absorption in liquid mixtures 

    E-Print Network [OSTI]

    Davis, James Madison

    1954-01-01T23:59:59.000Z

    in mixtures~ Storey suggests that this is likely to be the cause and gives on argu. zont~ which he says has been considered in acne unpublished work by Bauer, in its fever ~rarey reveals that evidence for associati n of the ethanol snd water molecules may... slope at the concentration cor- respon'ing to Qmt of the compl~ Usin? the available data on the freezing points of ~ol and water~ Storey plots c curve which shows a discon~ity at a composition cf 29& alcohol . . ~ten '. ing his theoryx Storey...

  2. LEED Study Session Session #3: Buildings

    E-Print Network [OSTI]

    Zaferatos, Nicholas C.

    that allow water to penetrate and infiltrate the soil below. o Pervious (no fines) concrete o Porous Asphalt Sites Credit 6: Stormwater Management #12;Pervious Paving What is it? Newer, porous paving systems

  3. The effect of construction variables on the dynamic modulus of asphalt treated base courses 

    E-Print Network [OSTI]

    Moeller, William Ernest

    1970-01-01T23:59:59.000Z

    were taken the confining pressure was raised to 20 psi and the procedure repeated. The same sequence was repeated for a confining prossnre of 40 psi. 37 Unconfined Comcression Test The unconfined compression test has long been used in the testing... the recorder load versus time plot. No other instrumentation was utilized in this test. The Texas High?ay Department procedure for unconfined compression testing of bituminous mixtures specifies a specimen temperature of 140 F and a rate of loading...

  4. Utilize Cementitious High Carbon Fly Ash (CHCFA) to Stabilize Cold In-Place Recycled (CIR) Asphalt Pavement as Base Coarse

    SciTech Connect (OSTI)

    Wen, Haifang; Li, Xiaojun; Edil, Tuncer; O'Donnell, Jonathan; Danda, Swapna

    2011-02-05T23:59:59.000Z

    The purpose of this study was to evaluate the performance of cementitious high carbon fly ash (CHCFA) stabilized recycled asphalt pavement as a base course material in a real world setting. Three test road cells were built at MnROAD facility in Minnesota. These cells have the same asphalt surface layers, subbases, and subgrades, but three different base courses: conventional crushed aggregates, untreated recycled pavement materials (RPM), and CHCFA stabilized RPM materials. During and after the construction of the three cells, laboratory and field tests were carried out to characterize the material properties. The test results were used in the mechanistic-empirical pavement design guide (MEPDG) to predict the pavement performance. Based on the performance prediction, the life cycle analyses of cost, energy consumption, and greenhouse gasses were performed. The leaching impacts of these three types of base materials were compared. The laboratory and field tests showed that fly ash stabilized RPM had higher modulus than crushed aggregate and RPM did. Based on the MEPDG performance prediction, the service life of the Cell 79 containing fly ash stabilized RPM, is 23.5 years, which is about twice the service life (11 years) of the Cell 77 with RPM base, and about three times the service life (7.5 years) of the Cell 78 with crushed aggregate base. The life cycle analysis indicated that the usage of the fly ash stabilized RPM as the base of the flexible pavement can significantly reduce the life cycle cost, the energy consumption, the greenhouse gases emission. Concentrations of many trace elements, particularly those with relatively low water quality standards, diminish over time as water flows through the pavement profile. For many elements, concentrations below US water drinking water quality standards are attained at the bottom of the pavement profile within 2-4 pore volumes of flow.

  5. Microbes pave way for 'nanowires' -vnunet.com http://www.vnunet.com/vnunet/news/2139059/microbes-fire-nanowires 1 of 3 6/29/2005 5:24 PM

    E-Print Network [OSTI]

    Lovley, Derek

    over nanotech breakthrough Nanotech to turbocharge PC and mobile data More stories News centre News structures that are highly electrically conductive, paving the way for organically-based nanotechnology. "These could provide new approaches to using microbes to assist in the remediation of DOE waste sites

  6. Advanced Enzymes and Mixtures-final-sm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    enzymes in the mixture to maximize sugar yields. Leveraging Sandia's expertise in genomics, researchers are mining databases for genes encoded with enzymes from organisms that...

  7. Blind Identification of Over-complete MixturEs of sources (BIOME)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Blind Identification of Over-complete MixturEs of sources (BIOME) Laurent Albera(1,2) , Anne Ferr Abstract The problem of Blind Identification of linear mixtures of independent random pro- cesses is known words: Blind Source Separation, Independent Component Analysis, Tensor, High Order Statistics, Joint

  8. Variational inference for Dirichlet process mixtures

    E-Print Network [OSTI]

    Sekhon, Jasjeet S.

    Variational inference for Dirichlet process mixtures David M. Blei School of Computer Science Carnegie-Mellon University blei@cs.cmu.edu Michael I. Jordan Computer Science Division and Department, 2001; Blei et al., 2003). In this paper, we present a variational inference algo- rithm for DP mixtures

  9. Green Highways: American Concrete Paving

    E-Print Network [OSTI]

    ! So-called "global warming" is just a secret ploy by wacko tree-huggers to make America energy for only 1.5% of US CO2 emissions ­ the balance comes from... Electricity Production (40%) Other Industry

  10. Dynamic structure factors of a dense mixture

    E-Print Network [OSTI]

    Supurna Sinha

    2005-05-22T23:59:59.000Z

    We compute the dynamic structure factors of a dense binary liquid mixture. These describe dynamics on molecular length scales, where structural relaxation is important. We find that the presence of a few large particles in a dense fluid of small particles slows down the dynamics considerably. We also observe a deep narrowing of the spectrum for a disordered mixture composed of a nearly equal packing of the two species. In contrast, a few small particles diffuse easily in the background of a dense fluid of large particles. We expect our results to describe neutron scattering from a dense mixture.

  11. Ann. Occup. Hyg., Vol. 53, No. 6, pp. 551560, 2009 The Author 2009. Published by Oxford University Press

    E-Print Network [OSTI]

    California at Berkeley, University of

    not elevated among millers). Results from linear mixed-effects models of levels of U-Nap, U-Phe, OH-Phe, and OH; exposure; PAH; urine INTRODUCTION Asphalt (also referred to as bitumen) is a by-product of petroleum refining that is widely used to pave roads. Road-paving workers are exposed to emis- sions from hot asphalt

  12. Topic-based mixture language modelling. 

    E-Print Network [OSTI]

    Gotoh, Yoshihiko; Renals, Steve

    1999-01-01T23:59:59.000Z

    This paper describes an approach for constructing a mixture of language models based on simple statistical notions of semantics using probabilistic models developed for information retrieval. The approach encapsulates corpus-derived semantic...

  13. Toxicity Analysis of Polycyclic Aromatic Hydrocarbon Mixtures

    E-Print Network [OSTI]

    Naspinski, Christine S.

    2010-01-16T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are widely distributed in the environment and are generated by many sources. Though the potential of PAH-rich mixtures to cause health effects has been known for almost a century, there are still unanswered...

  14. Industrial Utilization of Coal-Oil Mixtures

    E-Print Network [OSTI]

    Dunn, J. E.; Hawkins, G. T.

    1982-01-01T23:59:59.000Z

    Coal-oil mixtures (COM) are receiving increasing interest as economical alternatives to residual fuel oil and natural gas used in heavy industrial and utility applications. Four basic approaches are currently employed in the manufacture of COM...

  15. PRP is a dedicated academic and research initiative incorporating research, education, and training activities in the fields of

    E-Print Network [OSTI]

    Neimark, Alexander V.

    , and reflective cracking · Tire/pavement interaction (acoustics) and modeling · Remaining service life evaluation · Conventional and polymer-modified asphalt · Innovative materials in hot mix asphalt · Recycled materials and runways. Examples include: · Northeast pooled fund study on high recycled asphalt pave- ment (RAP) mixes

  16. Mixed-mode diesel HCCI with External Mixture Formation: Preliminary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results Mixed-mode diesel HCCI with External Mixture Formation: Preliminary Results 2003 DEER Conference...

  17. Diffusion method of seperating gaseous mixtures

    DOE Patents [OSTI]

    Pontius, Rex B. (Rochester, NY)

    1976-01-01T23:59:59.000Z

    A method of effecting a relatively large change in the relative concentrations of the components of a gaseous mixture by diffusion which comprises separating the mixture into heavier and lighter portions according to major fraction mass recycle procedure, further separating the heavier portions into still heavier subportions according to a major fraction mass recycle procedure, and further separating the lighter portions into still lighter subportions according to a major fraction equilibrium recycle procedure.

  18. Mixture balance laws for fluid flows with phase transition

    E-Print Network [OSTI]

    Helluy, Philippe

    . Cavitation: Francis turbine, cavitation damage and old repairs with stainless steel welding Mixture balance

  19. Coal-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.

    1985-04-29T23:59:59.000Z

    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  20. Non-electrolyte viscous liquid mixtures

    E-Print Network [OSTI]

    Wakefield, Dawn Lee

    1982-01-01T23:59:59.000Z

    . Equations Proposed for the Dependence of Viscosity of Liquid Mixtures on Chemical Composition at Constant Temperature, 36 TABLE III. TABLE IV. Compar1son of Errors in Determining Mixture Viscosit1es Using the Congruence-Viscos1ty Equat1on 86... states theory simplif1ed the more complex initial equations into the reasonably simple eq 3 lg. For ideal systems there is no "interaction viscosity, ny2 and the equation reduces to 2 + 2 nM Xl"1 X2n2 or nM = ZX 0 2 o o o (3. 20) R1ce compared...

  1. Multiphase coexistence in polydisperse colloidal mixtures

    E-Print Network [OSTI]

    C. Grodon; R. Roth

    2006-12-08T23:59:59.000Z

    We study the phase behavior of mixtures of monodisperse colloidal spheres with a depletion agent which can have arbitrary shape and can possess a polydisperse size or shape distribution. In the low concentration limit, considered here, we can employ the free-volume theory and take the geometry of particles of the depletion agent into account within the framework of fundamental measure theory. We apply our approach to study the phase diagram of a mixture of (monodisperse) colloidal spheres and two polydisperse polymer components. By fine tuning the distribution of the polymer it is possible to construct a complex phase diagram which exhibits two stable critical points.

  2. Local composition models for lattice mixtures

    SciTech Connect (OSTI)

    Wu, D.W.; Cui, Y.; Donohue, M.D. [Johns Hopkins Univ., Baltimore, MD (United States). Dept. of Chemical Engineering] [Johns Hopkins Univ., Baltimore, MD (United States). Dept. of Chemical Engineering

    1998-08-01T23:59:59.000Z

    A detailed comparison is made of several local-composition lattice models. The models considered include several popular activity coefficient models: the Wilson equation, Guggenheim`s quasi-chemical theory (GQC), the nonrandom two-liquid theory (NRTL), and the universal quasi-chemical (UNIQUAC) theory. Also considered are three recently developed lattice models: the Born-Green-Yvon (BGY) model, the nonrandom surface fraction (NRSF) model, and the Aranovich-Donohue (AD) model. Similarities and differences in the assumptions regarding the local compositions are examined. Detailed comparisons are made for both symmetric and asymmetric monomer mixtures as well as for polymer/solvent mixtures with Monte Carlo simulations.

  3. SOLAR HEATING OF TANK BOTTOMS Application of Solar Heating to Asphaltic and Parrafinic Oils Reducing Fuel Costs and Greenhouse Gases Due to Use of Natural Gas and Propane

    SciTech Connect (OSTI)

    Eugene A. Fritzler

    2005-09-01T23:59:59.000Z

    The sale of crude oil requires that the crude meet product specifications for BS&W, temperature, pour point and API gravity. The physical characteristics of the crude such as pour point and viscosity effect the efficient loading, transport, and unloading of the crude oil. In many cases, the crude oil has either a very high paraffin content or asphalt content which will require either hot oiling or the addition of diluents to the crude oil to reduce the viscosity and the pour point of the oil allowing the crude oil to be readily loaded on to the transport. Marginal wells are significantly impacted by the cost of preheating the oil to an appropriate temperature to allow for ease of transport. Highly paraffinic and asphaltic oils exist throughout the D-J basin and generally require pretreatment during cold months prior to sales. The current study addresses the use of solar energy to heat tank bottoms and improves the overall efficiency and operational reliability of stripper wells.

  4. Methods and systems for deacidizing gaseous mixtures

    DOE Patents [OSTI]

    Hu, Liang

    2010-05-18T23:59:59.000Z

    An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

  5. Oxidative particle mixtures for groundwater treatment

    DOE Patents [OSTI]

    Siegrist, Robert L. (Boulder, CO); Murdoch, Lawrence C. (Clemson, SC)

    2000-01-01T23:59:59.000Z

    The invention is a method and a composition of a mixture for degradation and immobilization of contaminants in soil and groundwater. The oxidative particle mixture and method includes providing a material having a minimal volume of free water, mixing at least one inorganic oxidative chemical in a granular form with a carrier fluid containing a fine grained inorganic hydrophilic compound and injecting the resulting mixture into the subsurface. The granular form of the inorganic oxidative chemical dissolves within the areas of injection, and the oxidative ions move by diffusion and/or advection, therefore extending the treatment zone over a wider area than the injection area. The organic contaminants in the soil and groundwater are degraded by the oxidative ions, which form solid byproducts that can sorb significant amounts of inorganic contaminants, metals, and radionuclides for in situ treatment and immobilization of contaminants. The method and composition of the oxidative particle mixture for long-term treatment and immobilization of contaminants in soil and groundwater provides for a reduction in toxicity of contaminants in a subsurface area of contamination without the need for continued injection of treatment material, or for movement of the contaminants, or without the need for continuous pumping of groundwater through the treatment zone, or removal of groundwater from the subsurface area of contamination.

  6. PVT measurements for five natural gas mixtures

    E-Print Network [OSTI]

    Simon, Philip Parayil

    1991-01-01T23:59:59.000Z

    . Virial Coefficients for Natural Gas Mixtures Sample T B trc D N? (K) (cmc/mot) (cm'/mot) (cm /mct ) (cmc/mot ) (cmc/mot ) Amarillo 250 -73. 88 0. 03 275 -59. 45 0. 02 300 -47. 48 0. 19 325* -38. 69 0. 06 Gulf 250 -70. 76 0. 03 Coast 275 -56. 78 0...

  7. Ternary gas mixture for diffuse discharge switch

    DOE Patents [OSTI]

    Christophorou, Loucas G. (Oak Ridge, TN); Hunter, Scott R. (Oak Ridge, TN)

    1988-01-01T23:59:59.000Z

    A new diffuse discharge gas switch wherein a mixture of gases is used to take advantage of desirable properties of the respective gases. There is a conducting gas, an insulating gas, and a third gas that has low ionization energy resulting in a net increase in the number of electrons available to produce a current.

  8. Trajectory mixture density networks with multiple mixtures for acoustic-articulatory inversion 

    E-Print Network [OSTI]

    Richmond, Korin

    We have previously proposed a trajectory model which is based on a mixture density network (MDN) trained with target variables augmented with dynamic features together with an algorithm for estimating maximum likelihood trajectories which respects...

  9. air mixture glow: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1977- 2006-01-01 33 Inert Gas Dilution Effect on the Flammability Limits of Hydrocarbon Mixtures Texas A&M University - TxSpace Summary: limits of hydrocarbon mixtures in...

  10. Practical Identifiability of Finite Mixtures of Multivariate Bernoulli Distributions 

    E-Print Network [OSTI]

    Carreira-Perpinan, Miguel A; Renals, Steve

    The class of finite mixtures of multivariate Bernoulli distributions is known to be nonidentifiable; that is, different values of the mixture parameters can correspond to exactly the same probability distribution. In ...

  11. adaptive mixture modelling: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Randal Douc; Telecom Sudparis; Arnaud Guillin; Christian P. Robert 2007-01-01 24 Optimal Mixture Models in IR CiteSeer Summary: We explore the use of Optimal Mixture Models...

  12. Measurements of molecular and thermal diffusion coefficients in ternary mixtures

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    of a polymer and a colloid in a water-ethanol solvent, treating the ternary mixture as a pseudobinary; Gans et polymer in a water-ethanol solvent mixture. They reported a sign change in the Soret coefficient

  13. Characterization of Microexplosion Phenomena of Methanol-Glycerol Mixtures 

    E-Print Network [OSTI]

    Fan, Ge-Yi

    2014-07-17T23:59:59.000Z

    emissions even when combusting glycerol-based mixtures. In this research, microexplosion phenomena of methanol-in-glycerol mixtures have been studied using a high speed camera and an acoustic sensor system. A Fast Fourier Transform (FFT) algorithm has been...

  14. Shear viscosity of hadronic gas mixtures

    E-Print Network [OSTI]

    K. Itakura; O. Morimatsu; H. Otomo

    2008-05-12T23:59:59.000Z

    We investigate the effects of baryon chemical potential \\mu on the shear viscosity coefficient \\eta and the viscosity to entropy density ratio \\eta/s of a pion-nucleon gas mixture. We find that \\eta is an increasing function of T and \\mu, while the ratio \\eta/s turns to a decreasing function in a wide region of T-\\mu plane. In the kinematical region we studied, the smallest value of \\eta/s is about 0.3.

  15. Toxicity Analysis of Polycyclic Aromatic Hydrocarbon Mixtures 

    E-Print Network [OSTI]

    Naspinski, Christine S.

    2010-01-16T23:59:59.000Z

    TRANSFORMATION UV degradation Chemical reactions Biodegradation RECEPTOR Adults Children Ecological Fig. 1-1. Environmental exposure model. Once a mixture is released into the environment, it is acted upon by transformation and transport processes... chemical reactions with other compounds and may be degraded by UV light exposure or by biological organisms. Transport processes can be as simple as movement downstream of an industrial effluent released into a river, or complex, involving multiple...

  16. Liquid class predictor for liquid handling of complex mixtures

    DOE Patents [OSTI]

    Seglke, Brent W. (San Ramon, CA); Lekin, Timothy P. (Livermore, CA)

    2008-12-09T23:59:59.000Z

    A method of establishing liquid classes of complex mixtures for liquid handling equipment. The mixtures are composed of components and the equipment has equipment parameters. The first step comprises preparing a response curve for the components. The next step comprises using the response curve to prepare a response indicator for the mixtures. The next step comprises deriving a model that relates the components and the mixtures to establish the liquid classes.

  17. Dual-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, Thomas D. (Finleyville, PA); Reehl, Douglas P. (Pittsburgh, PA); Walbert, Gary F. (Library, PA)

    1986-08-05T23:59:59.000Z

    A coal-water mixture (CWM) burner includes a conically shaped rotating cup into which fuel comprised of coal particles suspended in a slurry is introduced via a first, elongated inner tube coupled to a narrow first end portion of the cup. A second, elongated outer tube is coaxially positioned about the first tube and delivers steam to the narrow first end of the cup. The fuel delivery end of the inner first tube is provided with a helical slot on its lateral surface for directing the CWM onto the inner surface of the rotating cup in the form of a uniform, thin sheet which, under the influence of the cup's centrifugal force, flows toward a second, open, expanded end portion of the rotating cup positioned immediately adjacent to a combustion chamber. The steam delivered to the rotating cup wets its inner surface and inhibits the coal within the CWM from adhering to the rotating cup. A primary air source directs a high velocity air flow coaxially about the expanded discharge end of the rotating cup for applying a shear force to the CWM in atomizing the fuel mixture for improved combustion. A secondary air source directs secondary air into the combustion chamber adjacent to the outlet of the rotating cup at a desired pitch angle relative to the fuel mixture/steam flow to promote recirculation of hot combustion gases within the ignition zone for increased flame stability.

  18. ccsd00004127, ON THE SURFACE TENSIONS OF BINARY MIXTURES

    E-Print Network [OSTI]

    ccsd­00004127, version 1 ­ 2 Feb 2005 ON THE SURFACE TENSIONS OF BINARY MIXTURES JEAN RUIZ Abstract tensions and the concentrations are brie y reviewed. Key Words: Surface tensions, binary mixtures the corresponding surface tension depends on the composition of the mixture. Some relationship is expected which

  19. Journal of Testing and Evaluation, Nov. 2005, Vol. 33, No. 6 Paper ID JTE12579

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    -Edge Notched Beam Test for Asphalt Concrete Mixtures ABSTRACT: This paper describes the development of a fracture test for determining the fracture energy of asphalt concrete. The test will be used in combination to be within a range typical for asphalt concrete fracture testing. KEYWORDS: asphalt concrete, fracture

  20. Multicomponent mixture analysis by multidimensional phosphorimetry

    SciTech Connect (OSTI)

    Ho, C.N.; Warner, I.M.

    1982-12-01T23:59:59.000Z

    A technique based on the rapid scanning capability of the video fluorometer to acquire an emission-excitation matrix (EEM) has been developed for phosphorimetry. This technique overcomes the problem of convolution of time decay with phosphorescence excitation and emission spectra by integrating the signal on target. This method also circumvents the need for very rapid acquisition of data for samples with phosphors of very short lifetimes. A phosphorescence emission-excitation matrix (PEEM) obtained in this manner permits time resolution. Sets of each time-PEEM allow a ratio deconvolution algorithm to successfully resolve mixtures of polynuclear aromatic compounds. 9 figures.

  1. Advanced Enzymes and Mixtures-final-sm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP7-0973 1BP-14 Power andAdvanced Componentsenzyme mixtures to

  2. Predicting viscosities of aqueous salt mixtures

    SciTech Connect (OSTI)

    Zaltash, A.; Ally, M.R.

    1992-01-01T23:59:59.000Z

    Viscosity plays an important role in quantifying heat and mass transfer rates as depicted in theoretical and semi-empirical correlations. In practical problems where extreme temperatures and solute concentrations are encountered, viscosity data is usually unavailable. At these conditions, no dependable correlation appears to exist in the literature. This paper uses the hole type model to predict the viscosity of aqueous electrolytes containing single and mixed salts up to the molten salt regime. This model needs two parameters which can be evaluated from sparse data. For LiBr/water and (Li, K, na) NO[sub 3]/water mixtures, it is shown that the agreement between predicted and experimental values is very good over wide temperature and concentration ranges. The deviation between these two values was found to be less than 9%.

  3. Predicting viscosities of aqueous salt mixtures

    SciTech Connect (OSTI)

    Zaltash, A.; Ally, M.R.

    1992-12-01T23:59:59.000Z

    Viscosity plays an important role in quantifying heat and mass transfer rates as depicted in theoretical and semi-empirical correlations. In practical problems where extreme temperatures and solute concentrations are encountered, viscosity data is usually unavailable. At these conditions, no dependable correlation appears to exist in the literature. This paper uses the hole type model to predict the viscosity of aqueous electrolytes containing single and mixed salts up to the molten salt regime. This model needs two parameters which can be evaluated from sparse data. For LiBr/water and (Li, K, na) NO{sub 3}/water mixtures, it is shown that the agreement between predicted and experimental values is very good over wide temperature and concentration ranges. The deviation between these two values was found to be less than 9%.

  4. Ternary liquid mixture viscosities and densities

    SciTech Connect (OSTI)

    Wei, I.C.; Rowley, R.L.

    1984-01-01T23:59:59.000Z

    Liquid mixture viscosities and densities have been measured at 298.15 K and ambient pressure for 20 ternary systems. Twelve ternary compositions, encompassing the entire composition range, have been chosen for each system in an effort to test a newly proposed predictive equation based on local compositions. Viscosities calculated by using the local composition model agreed with the experimental data within an average absolute deviation of 6.4%. No adjustable parameters were used and only binary interactions in the form of NRTL constants were input. The results of these studies indicate that the local composition model predictions are generally as good for multicomponent systems as they are for the corresponding binaries. 24 references, 3 tables.

  5. Phase equilibrium measurements on nine binary mixtures

    SciTech Connect (OSTI)

    Wilding, W.V. [Brigham Young Univ., Provo, UT (United States). Chemical Engineering Dept.] [Brigham Young Univ., Provo, UT (United States). Chemical Engineering Dept.; Giles, N.F.; Wilson, L.C. [Wiltec Research Co. Inc., Provo, UT (United States)] [Wiltec Research Co. Inc., Provo, UT (United States)

    1996-11-01T23:59:59.000Z

    Phase equilibrium measurements have been performed on nine binary mixtures. The PTx method was used to obtain vapor-liquid equilibrium data for the following systems at two temperatures each: (aminoethyl)piperazine + diethylenetriamine; 2-butoxyethyl acetate + 2-butoxyethanol; 2-methyl-2-propanol + 2-methylbutane; 2-methyl-2-propanol + 2-methyl-2-butene; methacrylonitrile + methanol; 1-chloro-1,1-difluoroethane + hydrogen chloride; 2-(hexyloxy)ethanol + ethylene glycol; butane + ammonia; propionaldehyde + butane. Equilibrium vapor and liquid phase compositions were derived form the PTx data using the Soave equation of state to represent the vapor phase and the Wilson or the NRTL activity coefficient model to represent the liquid phase. A large immiscibility region exists in the butane + ammonia system at 0 C. Therefore, separate vapor-liquid-liquid equilibrium measurements were performed on this system to more precisely determine the miscibility limits and the composition of the vapor phase in equilibrium with the two liquid phases.

  6. ar gas mixture: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cooling, spray painting or transport of bubbly liquids. Normally, we. Cavitation: Francis turbine, cavitation damage and old repairs with stainless steel welding Mixture balance -...

  7. ampholyte mixtures: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cooling, spray painting or transport of bubbly liquids. Normally, we. Cavitation: Francis turbine, cavitation damage and old repairs with stainless steel welding Mixture balance -...

  8. Variational Approach in Studying the Mixture of the Fluids: Transport ...

    E-Print Network [OSTI]

    Title: Variational Approach in Studying the Mixture of the Fluids: Transport and ... of the non-Newtonian complex fluids arise from the coupling and competing ...

  9. Chemical Analysis of Complex Organic Mixtures Using Reactive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    possessing these groups in complex mixtures. Citation: Laskin J, PA Eckert, PJ Roach, BS Heath, SA Nizkorodov, and A Laskin.2012."Chemical Analysis of Complex Organic...

  10. Adsorptive method for the separation of a gas mixture

    SciTech Connect (OSTI)

    Linde, G.

    1984-05-15T23:59:59.000Z

    A method of recovering at least two product fractions each highly enriched in a respective component of a gas mixture containing at least such components are recovered by separating a stream of the mixture into at least two partial streams and passing this stream separately through respective beds of respective adsorbents and selectively retaining at least one component from each mixture so that the respective product fractions emerge from the adsorbents highly enriched in respective components of this mixture, each adsorbent for a particular one of the fractions has a composition that retains at least one component in which the other fractions is enriched.

  11. Exotic superconducting phases of ultracold atom mixtures on triangular lattices

    E-Print Network [OSTI]

    Mathey, Ludwig; Tsai, Shan-Wen; Castro Neto, Antonio H.

    2007-01-01T23:59:59.000Z

    Exotic Superconducting Phases of Ultracold Atom Mixtures onlattice contain exotic superconducting phases. For spin-1/2competition between superconducting phases with di?erent

  12. Prediction of New Hydrogen Storage Compounds and Mixtures

    Broader source: Energy.gov (indexed) [DOE]

    8, 2006 DOE Theory Focus Session on Hydrogen Storage Materials Prediction of New Hydrogen Storage Compounds and Mixtures Vidvuds Ozoli UCLA Research supported by DOE grants No....

  13. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT ·How can we separate ternary mixtures in closed batch distillation-up period is required, followed by a heteroazeotropic distillation step (Figure 3) Modified: The separation

  14. MIXTURES OF FINE-GRAINED MINERALS KAOLINITE AND CARBONATE GRAINS

    E-Print Network [OSTI]

    Palomino, Angelica M.

    MIXTURES OF FINE-GRAINED MINERALS À KAOLINITE AND CARBONATE GRAINS ANGELICA M. PALOMINO 1, *, SUSAN, Georgia 30332-0355, USA Abstract--The behavior of mineral mixtures can be significantly different from properties of the individual minerals, and their ensuing effects on interparticle interactions and fabric

  15. DAMAGE AND ROCKVOLATILE MIXTURE EFFECTS ON IMPACT CRATER FORMATION

    E-Print Network [OSTI]

    Stewart, Sarah T.

    DAMAGE AND ROCK­VOLATILE MIXTURE EFFECTS ON IMPACT CRATER FORMATION JOHN D. O'KEEFE, SARAH T models for material damage, dilatancy, and inhomogeneous materials (mixtures). We found that a strength degradation (damage) model was necessary to produce faulting in homogeneous materials. Both normal and thrust

  16. VISCOSITY OF NEMATIC-CHIRAL MIXTURES AND THEIR ELECTROOPTICAL CHARACTERISTICS

    E-Print Network [OSTI]

    Boyer, Edmond

    VISCOSITY OF NEMATIC-CHIRAL MIXTURES AND THEIR ELECTROOPTICAL CHARACTERISTICS Z. M. ELASHVILI, M. D of Georgian SSR, Tbilisi 380086, S. Euli str. 5, USSR Abstract. -- We have measured the viscosity in mixtures that the increase of the viscosity at low additive concentration (Cm

  17. Quantification of Gas Mixtures with Active Recursive Estimation

    E-Print Network [OSTI]

    Gutierrez-Osuna, Ricardo

    the concentrations in a gas mixture using temperature modulation of metal-oxide (MOX) sensors. The approach is based temperature modulated responses of a MOX sensor exposed to a mixture of three analytes. The results presented the approach, we created a scenario with a simulated MOX sensor operating at 20 different temperatures. FIGURE

  18. Mixture Theories for Rock Properties James G. Berryman

    E-Print Network [OSTI]

    Mixture Theories for Rock Properties James G. Berryman Lawrence Livermore National Laboratory by Batchelor [3], Hale [41], Hashin [42], Torquato [95], and Willis [110] are also recommended. 1.1. Rocks Are Inhomogeneous Materials A rock is a naturally occurring mixture of minerals. Rocks are normally inhomogeneous

  19. Surface tension in a reactive binary mixture of incompressible fluids

    E-Print Network [OSTI]

    Struchtrup, Henning

    Surface tension in a reactive binary mixture of incompressible fluids Henning Struchtrup Institute with a distributed form of surface tension. The model describes chemistry, diffusion, viscosity and heat transfer tension at the front. Keywords: Binary mixtures, Surface tension, Irreversible thermodynamics, Hele

  20. 2500 University Drive N.W., Calgary, Alberta, Canada T2N 1N4 www.schulich.ucalgary.ca FOR IMMEDIATE RELEASE

    E-Print Network [OSTI]

    Calgary, University of

    Jadzinski (1st Prize) Paving Asphalt Modification with Tire Crumb Rubber with and without used lubricating oil Ameli Pereira (2nd Prize) Comparison of Direct Tension Test and the Ontario Ministry

  1. System for identifying known materials within a mixture of unknowns

    DOE Patents [OSTI]

    Wagner, J.S.

    1999-07-20T23:59:59.000Z

    One or both of two methods and systems are used to determine concentration of a known material in an unknown mixture on the basis of the measured interaction of electromagnetic waves upon the mixture. One technique is to utilize a multivariate analysis patch technique to develop a library of optimized patches of spectral signatures of known materials containing only those pixels most descriptive of the known materials by an evolutionary algorithm. Identity and concentration of the known materials within the unknown mixture is then determined by minimizing the residuals between the measurements from the library of optimized patches and the measurements from the same pixels from the unknown mixture. Another technique is to train a neural network by the genetic algorithm to determine the identity and concentration of known materials in the unknown mixture. The two techniques may be combined into an expert system providing cross checks for accuracy. 37 figs.

  2. Method of removing nitrogen oxides from exhaust gas mixtures

    SciTech Connect (OSTI)

    Batha, H.D.; Mason, J.H.; Thompson, S.R.

    1980-03-04T23:59:59.000Z

    A method of removing nitrogen oxides (NOX) from exhaust gas mixtures is described. The removal of NOX from exhaust gas mixtures is accomplished by exposing the exhaust gas mixture, in a manner that does not substantially impede the gas flow, to a ceramic material containing from about 75% to about 95% by weight silicon carbide and from about 0.3% to about 10.0% silica. A reduction of at least 85% of NOX from the mixture is to be expected and reductions up to 95 to 100% are attainable. Ceramic mixtures containing silicon nitride in amounts between about 10% and about 30% are found to reduce the amount of NOX in exhaust gases at temperatures as low as 200* C.

  3. Method for identifying known materials within a mixture of unknowns

    DOE Patents [OSTI]

    Wagner, John S. (Albuquerque, NM)

    2000-01-01T23:59:59.000Z

    One or both of two methods and systems are used to determine concentration of a known material in an unknown mixture on the basis of the measured interaction of electromagnetic waves upon the mixture. One technique is to utilize a multivariate analysis patch technique to develop a library of optimized patches of spectral signatures of known materials containing only those pixels most descriptive of the known materials by an evolutionary algorithm. Identity and concentration of the known materials within the unknown mixture is then determined by minimizing the residuals between the measurements from the library of optimized patches and the measurements from the same pixels from the unknown mixture. Another technique is to train a neural network by the genetic algorithm to determine the identity and concentration of known materials in the unknown mixture. The two techniques may be combined into an expert system providing cross checks for accuracy.

  4. System for identifying known materials within a mixture of unknowns

    DOE Patents [OSTI]

    Wagner, John S. (Albuquerque, NM)

    1999-01-01T23:59:59.000Z

    One or both of two methods and systems are used to determine concentration of a known material in an unknown mixture on the basis of the measured interaction of electromagnetic waves upon the mixture. One technique is to utilize a multivariate analysis patch technique to develop a library of optimized patches of spectral signatures of known materials containing only those pixels most descriptive of the known materials by an evolutionary algorithm. Identity and concentration of the known materials within the unknown mixture is then determined by minimizing the residuals between the measurements from the library of optimized patches and the measurements from the same pixels from the unknown mixture. Another technique is to train a neural network by the genetic algorithm to determine the identity and concentration of known materials in the unknown mixture. The two techniques may be combined into an expert system providing cross checks for accuracy.

  5. Phase equilibrium measurements on twelve binary mixtures

    SciTech Connect (OSTI)

    Giles, N.F. [Wiltec Research Co., Inc., Provo, UT (United States)] [Wiltec Research Co., Inc., Provo, UT (United States); Wilson, H.L.; Wilding, W.V. [Brigham Young Univ., Provo, UT (United States). Chemical Engineering Dept.] [Brigham Young Univ., Provo, UT (United States). Chemical Engineering Dept.

    1996-11-01T23:59:59.000Z

    Phase equilibrium measurements have been performed on twelve binary mixtures. The PTx method was used to obtain vapor-liquid equilibrium data for the following binary systems at two temperatures each: ethanethiol + propylene; nitrobenzene + methanol; pyridine + ethyl acetate; octane + tert-amyl methyl ether; diisopropyl ether + butane; 1,3-dichloro-2-propanol + epichlorohydrin; 2,3-dichloro-1-propanol + epichlorohydrin; 2,3-epoxy-1-propanol + epichlorohydrin; 3-chloro-1,2-propanediol + epichlorohydrin; methanol + hydrogen cyanide. For these systems, equilibrium vapor and liquid phase compositions were derived from the PTx data using the Soave equation of state to represent the vapor phase and the Wilson, NRTL, or Redlich-Kister activity coefficient model to represent the liquid phase. The infinite dilution activity coefficient of methylamine in N-methyl-2-pyrrolidone was determined at three temperatures by performing PTx measurements on the N-methyl-2-pyrrolidone was determined at three temperatures by performing PTx measurements on the N-methyl-2-pyrrolidone-rich half of the binary. Liquid-liquid equilibrium studies were made on the triethylene glycol + 1-pentene system at two temperatures by directly analyzing samples taken from each liquid phase.

  6. Responses in Milk Constituents to Intravascular Administration of Two Mixtures of Amino Acids to Dairy Cows

    E-Print Network [OSTI]

    Bequette, Brian J.

    to inves- tigate the effects of intravascular infusions of AA mixtures on milk constituents. Cows were infusion, followed by a 5-djugular infusion of a mixture of AA. Two mixtures of AA were used in a crossover (total AA); this mixture was infused at 400 g of M d . The other mixture represented the essential AA

  7. Low energy isomers of (H2O)25 from a hierarchical method based on Monte Carlo Temperature Basin Paving and Molecular Tailoring Approaches benchmarked by full MP2 calculations

    SciTech Connect (OSTI)

    Sahu, Nityananda; Gadre, Shridhar R.; Bandyopadhyay, Pradipta; Miliordos, Evangelos; Xantheas, Sotiris S.

    2014-10-28T23:59:59.000Z

    We report new global minimum candidate structures for the (H2O)25 cluster that are lower in energy than the ones reported previously and correspond to hydrogen bonded networks with 42 hydrogen bonds and an interior, fully coordinated water molecule. These were obtained as a result of a hierarchical approach based on initial Monte Carlo Temperature Basin Paving (MCTBP) sampling of the cluster’s Potential Energy Surface (PES) with the Effective Fragment Potential (EFP), subsequent geometry optimization using the Molecular Tailoring fragmentation Approach (MTA) and final refinement at the second order Møller Plesset perturbation (MP2) level of theory. The MTA geometry optimizations used between 14 and 18 main fragments with maximum sizes between 11 and 14 water molecules and average size of 10 water molecules, whose energies and gradients were computed at the MP2 level. The MTA-MP2 optimized geometries were found to be quite close (within < 0.5 kcal/mol) to the ones obtained from the MP2 optimization of the whole cluster. The grafting of the MTA-MP2 energies yields electronic energies that are within < 5×10-4 a.u. from the MP2 results for the whole cluster while preserving their energy order. The MTA-MP2 method was also found to reproduce the MP2 harmonic vibrational frequencies in both the HOH bending and the OH stretching regions.

  8. Low energy isomers of (H{sub 2}O){sub 25} from a hierarchical method based on Monte Carlo temperature basin paving and molecular tailoring approaches benchmarked by MP2 calculations

    SciTech Connect (OSTI)

    Sahu, Nityananda; Gadre, Shridhar R., E-mail: gadre@iitk.ac.in, E-mail: sotiris.xantheas@pnnl.gov [Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016 (India); Rakshit, Avijit; Bandyopadhyay, Pradipta [School of Computational and Integrative Sciences, Jawaharlal Nehru University, New Delhi 110067 (India); Miliordos, Evangelos; Xantheas, Sotiris S., E-mail: gadre@iitk.ac.in, E-mail: sotiris.xantheas@pnnl.gov [Physical Sciences Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, P.O. Box 999, MS K1-83, Richland, Washington 99352 (United States)

    2014-10-28T23:59:59.000Z

    We report new global minimum candidate structures for the (H{sub 2}O){sub 25} cluster that are lower in energy than the ones reported previously and correspond to hydrogen bonded networks with 42 hydrogen bonds and an interior, fully coordinated water molecule. These were obtained as a result of a hierarchical approach based on initial Monte Carlo Temperature Basin Paving sampling of the cluster's Potential Energy Surface with the Effective Fragment Potential, subsequent geometry optimization using the Molecular Tailoring Approach with the fragments treated at the second order Møller-Plesset (MP2) perturbation (MTA-MP2) and final refinement of the entire cluster at the MP2 level of theory. The MTA-MP2 optimized cluster geometries, constructed from the fragments, were found to be within <0.5 kcal/mol from the minimum geometries obtained from the MP2 optimization of the entire (H{sub 2}O){sub 25} cluster. In addition, the grafting of the MTA-MP2 energies yields electronic energies that are within <0.3 kcal/mol from the MP2 energies of the entire cluster while preserving their energy rank order. Finally, the MTA-MP2 approach was found to reproduce the MP2 harmonic vibrational frequencies, constructed from the fragments, quite accurately when compared to the MP2 ones of the entire cluster in both the HOH bending and the OH stretching regions of the spectra.

  9. Extension and replacement of aspalt cement with sulphur

    E-Print Network [OSTI]

    Pickett, Daniel Ernest

    1977-01-01T23:59:59.000Z

    supply of sulphur, it would be advantageous to reduce the dependence of the paving industry upon asphalt cement while utilizing effectively the readily available sulphur. An investigation was made of the use of elemental sulphur as a partial... purpose: an outlet would be pro- vided for the current oversupply of sulphur, and the dependence of the paving industry upon the use of asphalt cement would be reduced. Another potential benefit is the possibility of improved performance of pavements...

  10. Improved gas mixtures for gas-filled radiation detectors

    DOE Patents [OSTI]

    Christophorou, L.G.; McCorkle, D.L.; Maxey, D.V.; Carter, J.G.

    1980-03-28T23:59:59.000Z

    Improved binary and ternary gas mixtures for gas-filled radiation detectors are provided. The components are chosen on the basis of the principle that the first component is one molecular gas or mixture of two molecular gases having a large electron scattering cross section at energies of about 0.5 eV and higher, and the second component is a noble gas having a very small cross section at and below about 1.0 eV, whereby fast electrons in the gaseous mixture are slowed into the energy range of about 0.5 eV where the cross section for the mixture is small and hence the electron mean free path is large. The reduction in both the cross section and the electron energy results in an increase in the drift velocity of the electrons in the gas mixtures over that for the separate components for a range of E/P (pressure-reduced electric field) values. Several gas mixtures are provided that provide faster response in gas-filled detectors for convenient E/P ranges as compared with conventional gas mixtures.

  11. IGNITION IMPROVEMENT OF LEAN NATURAL GAS MIXTURES

    SciTech Connect (OSTI)

    Jason M. Keith

    2005-02-01T23:59:59.000Z

    This report describes work performed during a thirty month project which involves the production of dimethyl ether (DME) on-site for use as an ignition-improving additive in a compression-ignition natural gas engine. A single cylinder spark ignition engine was converted to compression ignition operation. The engine was then fully instrumented with a cylinder pressure transducer, crank shaft position sensor, airflow meter, natural gas mass flow sensor, and an exhaust temperature sensor. Finally, the engine was interfaced with a control system for pilot injection of DME. The engine testing is currently in progress. In addition, a one-pass process to form DME from natural gas was simulated with chemical processing software. Natural gas is reformed to synthesis gas (a mixture of hydrogen and carbon monoxide), converted into methanol, and finally to DME in three steps. Of additional benefit to the internal combustion engine, the offgas from the pilot process can be mixed with the main natural gas charge and is expected to improve engine performance. Furthermore, a one-pass pilot facility was constructed to produce 3.7 liters/hour (0.98 gallons/hour) DME from methanol in order to characterize the effluent DME solution and determine suitability for engine use. Successful production of DME led to an economic estimate of completing a full natural gas-to-DME pilot process. Additional experimental work in constructing a synthesis gas to methanol reactor is in progress. The overall recommendation from this work is that natural gas to DME is not a suitable pathway to improved natural gas engine performance. The major reasons are difficulties in handling DME for pilot injection and the large capital costs associated with DME production from natural gas.

  12. LETTER Community ecology theory predicts the effects of agrochemical mixtures on aquatic biodiversity and ecosystem

    E-Print Network [OSTI]

    Lajeunesse, Marc J.

    LETTER Community ecology theory predicts the effects of agrochemical mixtures on aquatic experiment to examine the effects of pairwise agrochemical mixtures [fertiliser, herbicide (atrazine. As postulated, the responses of biodiversity and ecosystem properties to agrochemicals alone and in mixtures

  13. Opening criteria for accelerated paving techniques 

    E-Print Network [OSTI]

    Johnson, Jason Leonard

    1993-01-01T23:59:59.000Z

    ?pih do?il t?r Dummy-groove contraction Dummy-groove, doweled contraction Dlrectioh of pour td I t d. th dotal ba Flee s?N th lob i pated Butt construction Expansion Filler tredeobe O/f I/Iced cf hooked ti b Q I/Z- $o/a Leyed longitudinal, tied...

  14. Opening criteria for accelerated paving techniques

    E-Print Network [OSTI]

    Johnson, Jason Leonard

    1993-01-01T23:59:59.000Z

    of field and lab research provides a synopsis of the experimentation used to develop design guidelines for opening criteria. This section includes crack surveys, coring tests, FWD testing, maturity testing, penetration testing and consistency testing...

  15. New Lasers Pave Way for Tabletop Accelerators

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center (NERSC). Traditional accelerators, like the Large Hadron Collider where the Higgs boson was recently discovered, rely on high-power radio-frequency waves to energize...

  16. New Lasers Pave Way for Tabletop Accelerators

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency VisitSilverNephelineNeuralNewIdeas Spring from|New

  17. Deconvolution in Random Effects Models via Normal Mixtures

    E-Print Network [OSTI]

    Litton, Nathaniel A.

    2010-10-12T23:59:59.000Z

    derivative of the deconvoluting kernel estimator and the bootstrap bandwidth selector outperform the cross validation method. 1.1.3 Distribution Function Estimation In line with the mixture approach of this dissertation, Cordy and Thomas (1997) discuss...

  18. Genetic Evidence for Recent Population Mixture in India

    E-Print Network [OSTI]

    Moorjani, Priya

    Most Indian groups descend from a mixture of two genetically divergent populations: Ancestral North Indians (ANI) related to Central Asians, Middle Easterners, Caucasians, and Europeans; and Ancestral South Indians (ASI) ...

  19. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01T23:59:59.000Z

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  20. EVALUATION OF DISTANCE MEASURES BETWEEN GAUSSIAN MIXTURE MODELS OF MFCCS

    E-Print Network [OSTI]

    Ellis, Dan

    of the parameters. For K > 1, the k-means algo- rithm and optionally the expectation-maximization algo- rithm Gaussian mixture models is frequently needed. We present a comparison of the Kullback-Leibler distance

  1. Supercritical extraction of organic mixtures from soil-water slurries

    E-Print Network [OSTI]

    Green, Lynda Ann

    1994-01-01T23:59:59.000Z

    Supercritical C02was used to extract orgamc rruxtures from soil-water slurries. The extent of extraction and the equilibrium distribution of the mixture and of the individual components were determined. A single stage batch vessel was used...

  2. Shock jump relations for multiphase mixtures with stiff mechanical relaxation

    E-Print Network [OSTI]

    characteristic velocity is the sound speed, while thermal relaxation is related with diffusive effects whose mixtures, shock propagation in solid alloys, solid and liquid propellants as well as condensed solid

  3. Fluctuating hydrodynamics of multispecies mixtures. I. Non-reacting Flows

    E-Print Network [OSTI]

    Balakrishnan, Kaushik; Donev, Aleksandar; Bell, John B

    2013-01-01T23:59:59.000Z

    In this paper we discuss the formulation of the fluctuating Navier-Stokes (FNS) equations for multi-species, non-reactive fluids. In particular, we establish a form suitable for numerical solution of the resulting stochastic partial differential equations. An accurate and efficient numerical scheme, based on our previous methods for single species and binary mixtures, is presented and tested at equilibrium as well as for a variety of non-equilibrium problems. These include the study of giant nonequilibrium concentration fluctuations in a ternary mixture in the presence of a diffusion barrier, the triggering of a Rayleigh-Taylor instability by diffusion in a four-species mixture, as well as reverse diffusion in a ternary mixture. Good agreement with theory and experiment demonstrates that the formulation is robust and can serve as a useful tool in the study of thermal fluctuations for multi- species fluids. The extension to include chemical reactions will be treated in a sequel paper.

  4. Light scattering and phase behavior of Lysozyme-PEG mixtures

    E-Print Network [OSTI]

    J. Bloustine; T. Virmani; G. M. Thurston; S. Fraden

    2005-12-14T23:59:59.000Z

    Measurements of liquid-liquid phase transition temperatures (cloud points) of mixtures of a protein (lysozyme) and a polymer, poly(ethylene glycol) (PEG) show that the addition of low molecular weight PEG stabilizes the mixture whereas high molecular weight PEG was destabilizing. We demonstrate that this behavior is inconsistent with an entropic depletion interaction between lysozyme and PEG and suggest that an energetic attraction between lysozyme and PEG is responsible. In order to independently characterize the lysozyme/PEG interactions, light scattering experiments on the same mixtures were performed to measure second and third virial coefficients. These measurements indicate that PEG induces repulsion between lysozyme molecules, contrary to the depletion prediction. Furthermore, it is shown that third virial terms must be included in the mixture's free energy in order to qualitatively capture our cloud point and light scattering data. The light scattering results were consistent with the cloud point measurements and indicate that attractions do exist between lysozyme and PEG.

  5. Bayesian variable selection in clustering via dirichlet process mixture models

    E-Print Network [OSTI]

    Kim, Sinae

    2007-09-17T23:59:59.000Z

    simultane- ously. I use Dirichlet process mixture models to define the cluster structure and to introduce in the model a latent binary vector to identify discriminating variables. I update the variable selection index using a Metropolis algorithm and obtain...

  6. Studies of Neurological Transmission Analysis Hierarchical Bayesian Mixture Models

    E-Print Network [OSTI]

    West, Mike

    Studies of Neurological Transmission Analysis using Hierarchical Bayesian Mixture Models MIKE WEST of individual neuro­ transmitter release sites at nerve junctions. Models attempt to capture scientific features, with result­ ing neurophysiological insights in some recently generated experimental contexts. Further

  7. A Flexible Extreme Value Mixture Model A. MacDonalda

    E-Print Network [OSTI]

    Scarrott, Carl

    A Flexible Extreme Value Mixture Model A. MacDonalda , C.J. Scarrotta, , D. Leea , B. Darlowb , M motivated models for unusual or rare events, e.g. the upper or lower tails of a distribution. A new flexible

  8. Stability of stainless-steel nanoparticle and water mixtures

    E-Print Network [OSTI]

    Song, You Young; Bhadeshia, H. K. D. H.; Suh, Dong-Woo

    2014-11-28T23:59:59.000Z

    of such mixtures, especially for heavy metallic particles. For 0.017 wt% stainless steel-distilled water nanoparticle-fluid, the thermal conductivity increases by 8.3 % at the optimal stability condition of pH 11. Keywords: Stainless steel, Nanofluid, Stability... of larger particle density related to metallic particles, metallic nanoparticle-fluids have been studied much less than oxides or nanotube dispersions. An important characteristic of a nanoparticle-fluid mixture or nanofluid is its stability with respect...

  9. Experimental Study on Transmission of an Overdriven Detonation Wave Across a Mixture

    E-Print Network [OSTI]

    Texas at Arlington, University of

    , ex- periments were performed wherein a propane/oxygen mixture was separated from a propane/air, main combustor filled with a gaseous or liquid hydrocarbon-air mixture. Nevertheless, Schultz examines the transmission of an overdriven detonation from a C3H8/O2 mixture to a C3H8/air mixture. #12;2 J

  10. Far-infrared spectra and associated dynamics in acetonitrilewater mixtures measured with femtosecond THz pulse spectroscopy

    E-Print Network [OSTI]

    Far-infrared spectra and associated dynamics in acetonitrile­water mixtures measured-infrared region of the spectrum for mixtures of acetonitrile and water. The mixtures do not behave ideally, and deviate from ideality most noticeably for mixtures that are between 25% and 65% acetonitrile by volume

  11. Sterilization of fermentation vessels by ethanol/water mixtures

    DOE Patents [OSTI]

    Wyman, C.E.

    1999-02-09T23:59:59.000Z

    A method is described for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process. 2 figs.

  12. Sterilization of fermentation vessels by ethanol/water mixtures

    DOE Patents [OSTI]

    Wyman, Charles E. (Lakewood, CO)

    1999-02-09T23:59:59.000Z

    A method for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process.

  13. Autoignition behavior of lean mixtures: Chemical and thermodynamics effects

    SciTech Connect (OSTI)

    Ronney, P.D.; Shoda, M.; Waida, S.T. [Princeton Univ., NJ (United States). Dept. of Mechanical and Aerospace Engineering; Westbrook, C.K.; Pitz, W.J. [Lawrence Livermore National Lab., CA (United States)

    1992-01-15T23:59:59.000Z

    Knock characteristics of natural gas (NG), 89 octane unleaded gasoline, 2,2-dimethyl butane (22DMB), and methyl tert-butyl ether (MTBE) in stoichiometric and lean fuel-air mixtures were studied in a production 4-cylinder automotive engine. The Intake Temperature at the Knock Limit (ITKL) was different for each fuel but always higher in lean mixtures. Gasoline and 22DMB exhibited much greater increases in ITKL than MTBE and NG at lean conditions. Surprisingly, for lean mixtures 22DMB exhibited higher ITKL than MTBE and was almost as high as NG. Comparison with detailed numerical modelling was very favorable. Computations show that both differences in chemistry and end-gas temperature and pressure histories are responsible for these trends. This behavior is interpreted in terms of the Negative Temperature Coefficient behavior of hydrocarbon oxidation. The implication of these results for the specification of optimal fuels for lean-burn engine is discussed.

  14. Salt-induced changes of colloidal interactions in critical mixtures

    E-Print Network [OSTI]

    Ursula Nellen; Julian Dietrich; Laurent Helden; Shirish Chodankar; Kim Nygard; J. Friso van der Veen; Clemens Bechinger

    2011-04-28T23:59:59.000Z

    We report on salt-dependent interaction potentials of a single charged particle suspended in a binary liquid mixture above a charged wall. For symmetric boundary conditions (BC) we observe attractive particle-wall interaction forces which are similar to critical Casimir forces previously observed in salt-free mixtures. However, in case of antisymmetric BC we find a temperature-dependent crossover from attractive to repulsive forces which is in strong contrast to salt-free conditions. Additionally performed small-angle x-ray scattering experiments demonstrate that the bulk critical fluctuations are not affected by the addition of salt. This suggests that the observed crossover can not be attributed alone to critical Casimir forces. Instead our experiments point towards a possible coupling between the ionic distributions and the concentration profiles in the binary mixture which then affects the interaction potentials in such systems.

  15. Multiphase carbon and its properties in complex mixtures

    SciTech Connect (OSTI)

    van Thiel, M.; Ree, F.H.

    1990-09-01T23:59:59.000Z

    We describe some key features of a carbon three-phase equation of state and a high-pressure high temperature mixture model in which it is used. Electronic terms in the carbon model have been investigated with INFERNO (atom in a cell model). The Lindeman criterion for melting is rederived for the anisotropic structure of the graphite lattice. The curvature of the graphite melting line is constrained by the evidence for the positive slope of the diamond melting line. The importance of carbon is apparent from various experiments on shock generated mixtures. The model allows us to estimate the energy of carbon clusters produced in a detonating mixture. A cluster model with specific surface structure is used to predict this energy. 41 refs., 7 figs., 4 tabs.

  16. Inferential determination of various properties of a gas mixture

    DOE Patents [OSTI]

    Morrow, Thomas B. (San Antonio, TX); Behring, II, Kendricks A. (Torrance, CA)

    2007-03-27T23:59:59.000Z

    Methods for inferentially determining various properties of a gas mixture, when the speed of sound in the gas is known at an arbitrary temperature and pressure. The method can be applied to natural gas mixtures, where the known parameters are the sound speed, temperature, pressure, and concentrations of any dilute components of the gas. The method uses a set of reference gases and their calculated density and speed of sound values to estimate the density of the subject gas. Additional calculations can be made to estimate the molecular weight of the subject gas, which can then be used as the basis for heating value calculations. The method may also be applied to inferentially determine density and molecular weight for gas mixtures other than natural gases.

  17. Binary and ternary gas mixtures for use in glow discharge closing switches

    DOE Patents [OSTI]

    Hunter, Scott R. (Oak Ridge, TN); Christophorou, Loucas G. (Oak Ridge, TN)

    1990-01-01T23:59:59.000Z

    Highly efficient binary and ternary gas mixtures for use in diffuse glow discharge closing switches are disclosed. The binary mixtures are combinations of helium or neon and selected perfluorides. The ternary mixtures are combinations of helium, neon, or argon, a selected perfluoride, and a small amount of gas that exhibits enhanced ionization characteristics. These mixtures are shown to be the optimum choices for use in diffuse glow discharge closing switches by virtue of the combined physio-electric properties of the mixture components.

  18. Absorption of sound in liquids and liquid mixtures

    E-Print Network [OSTI]

    Musa, Raiq S

    1955-01-01T23:59:59.000Z

    with Burton's results and are nearly twice the 1947 Pinkerton values. Bette tested Hall's theory on ethyl alcohol and arrived at a value of 6 a/f that was half the experimental value. 2 This does not necessarily discredit Hall 's work since his cal... been observed in water mixtures of acetone by Willard and of ethyl alcohol by. Willis and by. Burton. Burton 10 11 also found peaks in water mixtures of several alcohols and other organic compounds but failed to observe a peak in those of methyl...

  19. Eshan V. Dave,1 Andrew F. Braham,2

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    of a Flattened Indirect Tension Test for Asphalt Concrete ABSTRACT: The indirect tension test (IDT) is frequently is proposed for indirect tension testing of asphalt concrete. In place of the standard loading heads of three asphalt concrete mixtures in two flattened configurations. This integrated modeling and testing

  20. Competitive Mixture of Deformable Models for Pattern Classification \\Lambda

    E-Print Network [OSTI]

    Yeung, Dit-Yan

    Competitive Mixture of Deformable Models for Pattern Classification \\Lambda Kwok­Wai Cheung Dit to pattern classification. Recently, we have cast a deformable model under a Bayesian framework for classification, giving promising results. However, deformable model methods are computation­ ally expensive due

  1. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

  2. A mixture integer-valued GARCH model Mamadou Lamine DIOP

    E-Print Network [OSTI]

    Boyer, Edmond

    ´en´egal. Email: aliou.diop@ugb.edu.sn Abdou Ka DIONGUE LERSTAD, Universit´e Gaston Berger, Saint Louis, S´en´egal. Email: abdou.diongue@ugb.edu.sn Abstract. In this paper, we generalize the mixture integer-valued ARCH

  3. CO2-based mixtures as working fluids for geothermal turbines.

    SciTech Connect (OSTI)

    Wright, Steven Alan; Conboy, Thomas M.; Ames, David E.

    2012-01-01T23:59:59.000Z

    Sandia National Laboratories is investigating advanced Brayton cycles using supercritical working fluids for application to a variety of heat sources, including geothermal, solar, fossil, and nuclear power. This work is centered on the supercritical CO{sub 2} (S-CO{sub 2}) power conversion cycle, which has the potential for high efficiency in the temperature range of interest for these heat sources and is very compact-a feature likely to reduce capital costs. One promising approach is the use of CO{sub 2}-based supercritical fluid mixtures. The introduction of additives to CO{sub 2} alters the equation of state and the critical point of the resultant mixture. A series of tests was carried out using Sandia's supercritical fluid compression loop that confirmed the ability of different additives to increase or lower the critical point of CO{sub 2}. Testing also demonstrated that, above the modified critical point, these mixtures can be compressed in a turbocompressor as a single-phase homogenous mixture. Comparisons of experimental data to the National Institute of Standards and Technology (NIST) Reference Fluid Thermodynamic and Transport Properties (REFPROP) Standard Reference Database predictions varied depending on the fluid. Although the pressure, density, and temperature (p, {rho}, T) data for all tested fluids matched fairly well to REFPROP in most regions, the critical temperature was often inaccurate. In these cases, outside literature was found to provide further insight and to qualitatively confirm the validity of experimental findings for the present investigation.

  4. Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures using Elementary) diagrams like distillation lines and isotherms maps may be used in analysis of the closed (total reflux) multivessel batch distillation column. An indirect level control strategy is implemented that eliminates

  5. Wind speed PDF classification using Dirichlet mixtures Rudy CALIF1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Wind speed PDF classification using Dirichlet mixtures Rudy CALIF1 , Richard EMILION2 , Ted'Orléans), UMR CNRS 6628 Université d'Orléans, France. Abstract: Wind energy production is very sensitive to instantaneous wind speed fluctuations. Thus rapid variation of wind speed due to changes in the local

  6. Gas Distribution Modeling using Sparse Gaussian Process Mixture Models

    E-Print Network [OSTI]

    Stachniss, Cyrill

    Gas Distribution Modeling using Sparse Gaussian Process Mixture Models Cyrill Stachniss1 Christian-- In this paper, we consider the problem of learning a two dimensional spatial model of a gas distribution with a mobile robot. Building maps that can be used to accurately predict the gas concentration at query

  7. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, Robert N. (Allentown, PA)

    1986-01-01T23:59:59.000Z

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300.degree. C. before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil.

  8. VOCs, Pesticides, Nitrate, and Their Mixtures in Groundwater Used for

    E-Print Network [OSTI]

    areas. For each sample, as many as 60 volatile organic compounds (VOCs), 83 pesticides, and nitrate were of food and water, and dermal contact). Everyone has hundreds of measurable contami- nants in their bodies, especially volatile organic compounds (VOCs), are not known. Defining human exposure to mixtures

  9. Gettering of hydrogen and methane from a helium gas mixture

    SciTech Connect (OSTI)

    Cárdenas, Rosa Elia, E-mail: recarde1@uiwtx.edu [Department of Physics, The University of the Incarnate Word, 4301 Broadway, San Antonio, Texas 78209 (United States); Stewart, Kenneth D.; Cowgill, Donald F., E-mail: dfcowgi@sandia.gov [Sandia National Laboratories, Hydrogen and Metallurgical Sciences, 7011 East Avenue, Livermore, California 94550 (United States)

    2014-11-01T23:59:59.000Z

    In this study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H{sub 2} and CH{sub 4} can be removed simultaneously from the mixture using two SAES St 172{sup ®} getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. The optimum combination involved operating one getter at 650?°C to decompose the methane, and the second at 110?°C to remove the hydrogen. This approach eliminated the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements.

  10. A light scattering study of colloid-polymer mixtures 

    E-Print Network [OSTI]

    Pirie, Angus D

    A detailed light scattering study of non-equilibrium states found in a model colloid-polymer mixture is presented. Conventional light scattering is used to examine the average structure of the phase, over a wide range of wavevectors. For all non...

  11. Phase separation of acetonitrile-water mixture in protein purification

    E-Print Network [OSTI]

    Gu, Tingyue

    Phase separation of acetonitrile-water mixture in protein purification Tingyue Gu, Yesong Gu The removal of acetonitrile (ACN)from reversed-phase high performance liquid chromatography (RP- HPLC the majority of ACN after RP-HPLC. Keywords. purification; chromatography; acetonitrile; protein; human growth

  12. Methods for deacidizing gaseous mixtures by phase enhanced absorption

    DOE Patents [OSTI]

    Hu, Liang

    2012-11-27T23:59:59.000Z

    An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

  13. M. Bahrami ENSC 461 (S 11) Gas Vapor Mixtures and HVAC 1 Gas Vapor Mixtures and HVAC

    E-Print Network [OSTI]

    Bahrami, Majid

    = ha + hg Dry Bulb Temperature Tdb: the temperature measured by a thermometer placed in a mixture wet bulb temperature and the other dry bulb temperature. Tdb and Twb are sufficient to fix the state where 22 2 2 622.0 g g PP P since %1002 . Note that T2 is the wet-bulb temperature Twb. Wet Bulb

  14. aged material evaluations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and evaluated its performance when used in split mastic asphalt (SMA) mixture using Marshall Characteristic and dynamic charateristics (resilient modulus). As many as 90...

  15. Blind source separation of convolutive mixtures of non circular linearly modulated signals with unknown baud

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Blind source separation of convolutive mixtures of non circular linearly modulated signals addresses the problem of blind separation of convolutive mix- tures of BPSK and circular linearly modulated theoretical statements. Keywords: Blind source separation, Convolutive mixture, Constant Modulus Algorithm

  16. BLIND IDENTIFICATION OF UNDERDETERMINED MIXTURES BASED ON THE HEXACOVARIANCE AND HIGHER-ORDER CYCLOSTATIONARITY

    E-Print Network [OSTI]

    Boyer, Edmond

    BLIND IDENTIFICATION OF UNDERDETERMINED MIXTURES BASED ON THE HEXACOVARIANCE AND HIGHER consider the problem of blind identification of un- derdetermined mixtures in a cyclostationary context hexacovariance. Two blind identification algorithms based on the proposed estima- tor are considered

  17. Low velocity ion stopping in binary ionic mixtures

    SciTech Connect (OSTI)

    Tashev, Bekbolat; Baimbetov, Fazylkhan [Department of Physics, Kazakh National University, Tole Bi 96, Almaty 480012 (Kazakhstan); Deutsch, Claude [LPGP (UMR-CNRS 8578), Universite Paris XI, 91405 Orsay (France); Fromy, Patrice [Direction de l'Informatique, Universite Paris XI, 91405 Orsay (France)

    2008-10-15T23:59:59.000Z

    Attention is focused on the low ion velocity stopping mechanisms in multicomponent and dense target plasmas built of quasiclassical electron fluids neutralizing binary ionic mixtures, such as, deuterium-tritium of current fusion interest, proton-heliumlike iron in the solar interior or proton-helium ions considered in planetology, as well as other mixtures of fiducial concern in the heavy ion beam production of warm dense matter at Bragg peak conditions. The target plasma is taken in a multicomponent dielectric formulation a la Fried-Conte. The occurrence of projectile ion velocities (so-called critical) for which target electron slowing down equals that of given target ion components is also considered. The corresponding multiquadrature computations, albeit rather heavy, can be monitored analytical through a very compact code operating a PC cluster. Slowing down results are systematically scanned with respect to target temperature and electron density, as well as ion composition.

  18. Ionic liquids for separation of olefin-paraffin mixtures

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

    2013-09-17T23:59:59.000Z

    The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

  19. Ionic liquids for separation of olefin-paraffin mixtures

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

    2014-07-15T23:59:59.000Z

    The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

  20. Electrochemical separation and concentration of hydrogen sulfide from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (Atlanta, GA); Sather, Norman F. (Naperville, IL); Huang, Hann S. (Darian, IL)

    1984-10-30T23:59:59.000Z

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4 -- or, in the case of H.sub.2 S, to S--. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  1. Mixture Modeling and Outlier Detection in Microarray Data Analysis

    E-Print Network [OSTI]

    George, Nysia I.

    2010-01-16T23:59:59.000Z

    of replication in gene expression data (Nguyen et al., 2002). In order to assess the agreement between measurements from microarray data collected from the same subject we use the intraclass correlation coe?cient as a reliability index (Carrasco and Jover, 2002...-modeling in bioinformatic research is not new. Researchers have devoted much attention to methodology that can appropriately separate gene expressions into meaningful groups. Allison et al. (2002) and Ji et al. (2005) use beta-mixture modeling to describe distributional...

  2. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, R.N.

    1986-10-14T23:59:59.000Z

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

  3. Effects of mineral fillers in slurry seal mixtures

    E-Print Network [OSTI]

    Harper, William Joe

    1964-01-01T23:59:59.000Z

    rather than a desi~. The current practice among engineers and contractors is to prepare a mixture in ac- cordance with these specifications using local materials. In many cases a mineral filler, usually portland cement, is added to "improve... applied to portland cement concrete pavements to improve the skid resistance and riding qualities of tbe surface. A slurry seal cost does not increase or improve the strength of the pavement structure . The City of Las Vagas, New Mexico, used slurry...

  4. Variability of hot mix asphalt produced with reclaimed asphalt pavement

    E-Print Network [OSTI]

    Yang, Guiqin

    1999-01-01T23:59:59.000Z

    percent does not significantly influence the mix variability; it is desirable to use a large percentage of RAP in the Type S-I mix, i.e., more than 40% RAP; iii) On the average, the aggregate variability increases after transportation and stockpiling...

  5. Investigation of plasma-dust structures in He-Ar gas mixture

    SciTech Connect (OSTI)

    Maiorov, S. A. [A.M. Prokhorov General Physics Institute of Russian Academy of Sciences, Moscow (Russian Federation); Ramazanov, T. S.; Dzhumagulova, K. N.; Jumabekov, A. N.; Dosbolayev, M. K. [Al Farabi Kazakh National University, IETP, Tole bi 96a, Almaty, 050012 (Kazakhstan)

    2008-09-15T23:59:59.000Z

    The paper reports on the first experiments with plasma-dust formations in dc gas discharge plasma for a He-Ar mixture. It is shown that the choice of light and heavy gases for the mixture suppresses ion heating in electric field under the conventional conditions of experiments and results in a supersonic jet with high Mach numbers. Distribution functions for drifting ions in the gas mixture are calculated for various mixture concentrations, electric field strengths, and gas pressures.

  6. Depletion interactions in colloid-polymer mixtures X. Ye, T. Narayanan, and P. Tong*

    E-Print Network [OSTI]

    Tong, Penger

    are directly of interest to industries. Lubricating oils and paint are examples of the colloid-polymer mixtures

  7. Ultracold Heteronuclear Mixture of Ground and Excited State Atoms

    E-Print Network [OSTI]

    Khramov, Alexander; Dowd, William; Roy, Richard; Makrides, Constantinos; Petrov, Alexander; Kotochigova, Svetlana; Gupta, Subhadeep

    2014-01-01T23:59:59.000Z

    We report on the realization of an ultracold mixture of lithium atoms in the ground state and ytterbium atoms in the excited metastable 3P2 state. Such a mixture can support broad magnetic Feshbach resonances which may be utilized for the production of ultracold molecules with an electronic spin degree of freedom, as well as novel Efimov trimers. We investigate the interaction properties of the mixture in the presence of an external magnetic field and find an upper limit for the background interspecies two-body inelastic decay coefficient of K'2 < 3e-12 cm^3/s for the 3P2 m_J=-1 substate. We calculate the dynamic polarizabilities of the Yb 3P2 magnetic substates for a range of wavelengths, and find good agreement with our measurements at 1064nm. Our calculations also allow the identification of magic frequencies where Yb ground and metastable states are identically trapped and the determination of the interspecies van der Waals coefficients.

  8. USE OF MIXTURES AS WORKING FLUIDS IN OCEAN THERMAL ENERGY CONVERSION CYCLES

    E-Print Network [OSTI]

    Khan Zafar Iqbal; Kenneth E. Starling

    Mixtures offer potential advantages over pure compounds as working fluids in ocean thermal energy conversion cycles. Power plant capital costs per unit of energy output can be reduced using mixtures because of increased thermal efficiency and/or decreased heat exchanger size requirements. Mixtures

  9. The Importance of Identifying Different Components of a Mixture Distribution in the Prediction of Field Returns

    E-Print Network [OSTI]

    to a given date. The power transformer population consists of a mixture of two different designs, an oldThe Importance of Identifying Different Components of a Mixture Distribution in the Prediction, it is important to identify components of the mixture and do statistical inference based on the stratified data

  10. Process for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture

    SciTech Connect (OSTI)

    vanEijl, A.T.

    1986-06-24T23:59:59.000Z

    A process is described for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture characterized by: (a) distilling a hydrocarbon mixture containing the unsaturated hydrocarbon with an N-(aminoalkyl) piperazine; and (b) separating the amine/hydrocarbon mixture into at least two factions, one of which contains the amine and the unsaturated hydrocarbon.

  11. International Journal of Thermophysics, Vol. 19, No. 2, 1998 Prediction of Fluid Mixture Transport Properties by

    E-Print Network [OSTI]

    Dysthe, Dag Kristian

    dynamics simulations of mixtures of n-decane with methane, ethane, and carbon dioxide and of the mixture carbon dioxide-ethane were performed using the anisotropic united atoms model for n-decane and one: alkanes; carbon dioxide; diffusion; mixtures; molecular dynamics; thermal conductivity; viscosity. 1

  12. Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanol

    E-Print Network [OSTI]

    Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanol Dean S mixtures of water with acetone, acetonitrile, and methanol over their entire range of compositions have and acetonitrile mixtures. Spatial distribution functions are reported for the acetone/water system. © 2000

  13. Chemical characterization of beach asphalts

    E-Print Network [OSTI]

    May, Lloyd Alexander

    1973-01-01T23:59:59.000Z

    and flameless atomic absorption spectroscopy for vanadium, nickel, and iron. The neutron activation procedure was shown to be superior for vanadium, but no significant difference in methods was noted for nickel and iron. Other trace metals were done... by activation analysis. These include: mercury, gold, chromium, bromine, zinc, scandium, cobalt, and antimony. Use of the vanadium to nickel ratio, and of other trace element data, was discussed. As a key to understanding the nature of vanadium in crude...

  14. Binary and ternary gas mixtures for use in glow discharge closing switches

    DOE Patents [OSTI]

    Hunter, S.R.; Christophorou, L.G.

    1988-04-27T23:59:59.000Z

    Highly efficient binary and ternary gas mixtures for use in diffuse glow discharge closing switches are disclosed. The binary mixtures are combinations of helium or neon and selected perfluorides. The ternary mixtures are combinations of helium, neon, or argon, a selected perfluoride, and a small amount of gas that exhibits enhanced ionization characteristics. These mixtures are shown to be the optimum choices for use in diffuse glow discharge closing switches by virtue if the combines physio-electric properties of the mixture components. 9 figs.

  15. Plastic flow in polycrystal states in a binary mixture

    E-Print Network [OSTI]

    Toshiyuki Hamanaka; Akira Onuki

    2007-09-05T23:59:59.000Z

    Using molecular dynamics simulation we examine dynamics in sheared polycrystal states in a binary mixture containing 10% larger particles in two dimensions. We find large stress fluctuations arising from sliding motions of the particles at the grain boundaries, which occur cooperatively to release the elastic energy stored. These dynamic processes are visualized with the aid of a sixfold angle $\\alpha_j(t)$ representing the local crystal orientation and a disorder variable $D_j(t)$ representing a deviation from the hexagonal order for particle $j$.

  16. Efficient speaker verification using Gaussian mixture model component clustering.

    SciTech Connect (OSTI)

    De Leon, Phillip L. (New Mexico State University, Las Cruces, NM); McClanahan, Richard D.

    2012-04-01T23:59:59.000Z

    In speaker verification (SV) systems that employ a support vector machine (SVM) classifier to make decisions on a supervector derived from Gaussian mixture model (GMM) component mean vectors, a significant portion of the computational load is involved in the calculation of the a posteriori probability of the feature vectors of the speaker under test with respect to the individual component densities of the universal background model (UBM). Further, the calculation of the sufficient statistics for the weight, mean, and covariance parameters derived from these same feature vectors also contribute a substantial amount of processing load to the SV system. In this paper, we propose a method that utilizes clusters of GMM-UBM mixture component densities in order to reduce the computational load required. In the adaptation step we score the feature vectors against the clusters and calculate the a posteriori probabilities and update the statistics exclusively for mixture components belonging to appropriate clusters. Each cluster is a grouping of multivariate normal distributions and is modeled by a single multivariate distribution. As such, the set of multivariate normal distributions representing the different clusters also form a GMM. This GMM is referred to as a hash GMM which can be considered to a lower resolution representation of the GMM-UBM. The mapping that associates the components of the hash GMM with components of the original GMM-UBM is referred to as a shortlist. This research investigates various methods of clustering the components of the GMM-UBM and forming hash GMMs. Of five different methods that are presented one method, Gaussian mixture reduction as proposed by Runnall's, easily outperformed the other methods. This method of Gaussian reduction iteratively reduces the size of a GMM by successively merging pairs of component densities. Pairs are selected for merger by using a Kullback-Leibler based metric. Using Runnal's method of reduction, we were able to achieve a factor of 2.77 reduction in a posteriori probability calculations with no loss in accuracy when the original UBM consisted of 256 component densities. When clustering was implemented with a 1024 component UBM, we achieved a computation reduction of 5 with no loss in accuracy and a reduction by a factor of 10 with less than 2.4% relative loss in accuracy.

  17. Multifarious Assembly Mixtures: Systems Allowing Retrieval of Diverse Stored Structures

    E-Print Network [OSTI]

    Arvind Murugan; Zorana Zeravcic; Michael P. Brenner; Stanislas Leibler

    2014-08-29T23:59:59.000Z

    Self-assembly materials are traditionally designed so that molecular or meso-scale components form a single kind of large structure. Here, we propose a scheme to create "multifarious assembly mixtures", which self-assemble many different large structures from a set of shared components. We show that the number of multifarious structures stored in the solution of components increases rapidly with the number of different types of components. Yet, each stored structure can be retrieved by tuning only a few parameters, the number of which is only weakly dependent on the size of the assembled structure. Implications for artificial and biological self-assembly are discussed.

  18. Phase Transition in a Vlasov-Boltzmann Binary Mixture

    E-Print Network [OSTI]

    R. Esposito; Y. Guo; R. Marra

    2009-04-05T23:59:59.000Z

    There are not many kinetic models where it is possible to prove bifurcation phenomena for any value of the Knudsen number. Here we consider a binary mixture over a line with collisions and long range repulsive interaction between different species. It undergoes a segregation phase transition at sufficiently low temperature. The spatially homogeneous Maxwellian equilibrium corresponding to the mixed phase, minimizing the free energy at high temperature, changes into a maximizer when the temperature goes below a critical value, while non homogeneous minimizers, corresponding to coexisting segregated phases, arise. We prove that they are dynamically stable with respect to the Vlasov-Boltzmann evolution, while the homogeneous equilibrium becomes dynamically unstable.

  19. Nucleation and propagation of phase mixtures in a bistable chain

    E-Print Network [OSTI]

    Vainchtein, Anna; Van Vleck, Erik

    2009-04-29T23:59:59.000Z

    Nucleation and propagation of phase mixtures in a bistable chain Anna Vainchtein* Department of Mathematics, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA Erik S. Van Vleck† Department of Mathematics, University of Kansas, Lawrence...-to-nearest-neighbor interactions. w h wc a phase I phase II FIG. 2. The biquadratic NN interaction potential Eq. #1;3#2; . ANNA VAINCHTEIN AND ERIK S. VAN VLECK PHYSICAL REVIEW B 79, 144123 #1;2009#2; 144123-2 wn = un ? un?1 #7; , is below #1;phase I#2; or above #1;phase II#2...

  20. Minimally refined biomass fuel. [carbohydrate-water-alcohol mixture

    SciTech Connect (OSTI)

    Pearson, R.K.; Hirschfeld, T.B.

    1981-03-26T23:59:59.000Z

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water-solubilizes the carbohydrate; and the alcohol aids in the combustion of the carbohydrate and reduces the viscosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  1. A Simple Mixture Theory for ? Newtonian and Generalized Newtonian Constituents

    E-Print Network [OSTI]

    Powell, Michael Joseph

    2012-08-31T23:59:59.000Z

    ] based on the following notations L(?) = gradv?(x, t) D(?) = 1 2 ( L(?) + L T (?) ) q = ?? ?=1 q? Q = 1 ?m ?? ?=1 ??Q? ? = 1 ?m ?? ?=1 ????(x, t) pi = ?pi1 = pi2 (2.39) 13 In which q is heat flux, Q is heat supply, ? and ?? are entropy densities... of the mixture and the constituents. We begin with the entropy inequality ?m D? Dt + div (q ? ) ? ? Q ? ? 0 (2.40) We have assumed that entropy due to heat flux q? is q? ? where ? is the common temperature of the constituents and the entropy due to heat supply Q?...

  2. Finite-temperature study of Bose-Fermi superfluid mixtures

    SciTech Connect (OSTI)

    Ramachandhran, B.; Pu, H. [Department of Physics and Astronomy, and Rice Quantum Institute, Rice University, Houston, Texas 77005 (United States); Bhongale, S. G. [Department of Physics and Astronomy, and Rice Quantum Institute, Rice University, Houston, Texas 77005 (United States); Department of Physics and Astronomy, George Mason University, MS 3F3, Fairfax, Virginia 22030 (United States)

    2011-03-15T23:59:59.000Z

    Ultracold atom experiments offer the unique opportunity to study mixing of different types of superfluid states. Our interest is in superfluid mixtures comprising of particles with different statistics--Bose and Fermi. Such scenarios occur naturally, for example, in dense quantum chromodynamics (QCD) matter. Interestingly, cold atomic experiments are performed in traps with finite spatial extent, thus critically destabilizing the occurrence of various homogeneous phases. Critical to this analysis is the understanding that the trapped system can undergo phase separation, resulting in a unique situation where phase transition in either species (bosons or fermions) can overlap with the phase separation between possible phases. In the present work, we illustrate how this intriguing interplay manifests in an interacting two-species atomic mixture--one bosonic and another fermionic with two spin components--within a realistic trap configuration. We further show that such interplay of transitions can render the nature of the ground state to be highly sensitive to the experimental parameters and the dimensionality of the system.

  3. Effect of antagonistic salt on confined near-critical mixture

    E-Print Network [OSTI]

    Faezeh Pousaneh; Alina Ciach

    2014-06-13T23:59:59.000Z

    We consider a near-critical binary mixture with addition of antagonistic salt confined between weakly charged and selective surfaces. A mesoscopic functional for this system is developed from a microscopic description by a systematic coarse-graining procedure. The functional reduces to the Landau-Brazovskii functional for amphiphilic systems for sufficiently large ratio between the correlation length in the critical binary mixture and the screening length. Our theoretical result agrees with the experimental observation [Sadakane et.al. J. Chem. Phys. {\\bf 139}, 234905 (2013)] that the antagonistic salt and surfactant both lead to a similar mesoscopic structure. For very small salt concentration $\\rho_{ion}$ the Casimir potential is the same as in a presence of inorganic salt. For larger $\\rho_{ion}$ the Casimir potential takes a minimum followed by a maximum for separations of order of tens of nanometers, and exhibits an oscillatory decay very close to the critical point. For separations of tens of nanometers the potential between surfaces with a linear size of hundreds of nanometers can be of order of $k_BT$. We have verified that in the experimentally studied samples [Sadakane et.al. J. Chem. Phys. {\\bf 139}, 234905 (2013), Leys et.al. Soft Matter {\\bf 9}, 9326 (2013)] the decay length is too small compared to the period of oscillations of the Casimir potential, but the oscillatory force could be observed closer to the critical point.

  4. Finite Mixture of ARMA-GARCH Model for Stock Price Prediction Him Tang, Kai-Chun Chiu and Lei Xu

    E-Print Network [OSTI]

    Xu, Lei

    Finite Mixture of ARMA-GARCH Model for Stock Price Prediction Him Tang, Kai-Chun Chiu and Lei Xu mixture of autore- gressive generalized autoregressive conditional het- eroscedasticity (AR-GARCH) models to extend the mixture of AR-GARCH model (W.C. Wong, F. Yip and L. Xu, 1998) to the mixture of ARMA- GARCH

  5. Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

    DOE Patents [OSTI]

    Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

    1997-01-01T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

  6. Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1997-10-28T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

  7. Methods and compositions for removing carbon dioxide from a gaseous mixture

    DOE Patents [OSTI]

    Li, Jing; Wu, Haohan

    2014-06-24T23:59:59.000Z

    Provided is a method for adsorbing or separating carbon dioxide from a mixture of gases by passing the gas mixture through a porous three-dimensional polymeric coordination compound having a plurality of layers of two-dimensional arrays of repeating structural units, which results in a lower carbon dioxide content in the gas mixture. Thus, this invention provides useful compositions and methods for removal of greenhouse gases, in particular CO.sub.2, from industrial flue gases or from the atmosphere.

  8. Nonequilibrium Glass Transition in Mixtures of Active-Passive Particles

    E-Print Network [OSTI]

    Ding, Huai; Jiang, Huijun; Hou, Zhonghuai

    2015-01-01T23:59:59.000Z

    We develop a mode coupling theory(MCT) to study the nonequilibrium glass transition behavior of a mono-disperse mixture of active-passive hard-sphere particles. The MCT equations clearly demonstrate that the glass transition is shifted to higher values of total volume fraction when doping a passive system with active particles. Interestingly, we find that the glass transition point may show a non-monotonic dependence on the effective diffusivity of the active component, indicating a nontrivial type of activity induced reentrance behavior. Analysis based on the nonergodic parameters suggest that the glassy state at small activity is due to the caging effect, while that at high activity could result from activity induced dynamic clustering.

  9. Mixture of Quantum States: Thermal and Interaction Inducing Decoherence

    E-Print Network [OSTI]

    Kentaro Urasaki

    2011-05-09T23:59:59.000Z

    In this study, we show that the interaction energy plays an important role on the quantum decoherence: If we pay attention to the oscillation phase factor, $e^{-iE_{int}t/\\hbar},$ we see that the time average of the macro-system's density matrix becomes nearly diagonal, where the states giving extrema of interaction energy are privileged to describe the quantum decoherence. This approach is compatible with the von Neumann's old work, which has been recently studied with renewed interest: The thermal mixture of states can be reached by the time average of a density of matrix due to the oscillation phase factor, $e^{-i(E_i-E_j)t/\\hbar}.$ One of the direct results is the localization of macroscopic objects.

  10. Coprocessing of Highvale coal with Athabasca bitumen in syngas mixtures

    SciTech Connect (OSTI)

    Parker, R.J.; Clark, P.D.; Ignasiak, B.L.; Lee, T.; Ohuchi, T.

    1986-04-01T23:59:59.000Z

    Coprocessing of Alberta subbituminous coal with bitumen is currently under investigation at the Alberta Research Council. The high oxygen content of the coal results in high hydrogen consumption. The present study compares the effectiveness of syngas/water mixtures catalyzed by potassium carbonate for coprocessing Highvale coal with Athabasca bitumen. Single-stage (solubilization) experiments were performed with syngas (5.1 MPa) at 390/sup 0/C in a stirred autoclave. In simulated two-stage experiments, the second (upgrading) stage employed hydrogen (8.5 MPa) at 440/sup 0/C with a potassium molybdate/dimethyl disulphide catalyst. Coal conversion improved from 47 to 78% systematically when the carbon monoxide: hydrogen ratio was varied from 1:3 to 7:1. The additional yield was confined to pyridine extractable material. In simulated two-stage experiments similar coal conversions were observed when using carbon monoxide/water (91%) or hydrogen (88%) in the first stage.

  11. Two phase coexistence for the hydrogen-helium mixture

    E-Print Network [OSTI]

    Fantoni, Riccardo

    2015-01-01T23:59:59.000Z

    We use our newly constructed quantum Gibbs ensemble Monte Carlo algorithm to perform computer experiments for the two phase coexistence of a hydrogen-helium mixture. Our results are in quantitative agreement with the experimental results of C. M. Sneed, W. B. Streett, R. E. Sonntag, and G. J. Van Wylen. The difference between our results and the experimental ones is in all cases less than 15% relative to the experiment, reducing to less than 5% in the low helium concentration phase. At the gravitational inversion between the vapor and the liquid phase, at low temperatures and high pressures, the quantum effects become relevant. At extremely low temperature and pressure the first component to show superfluidity is the helium in the vapor phase.

  12. Unusual behavior of poly(ethylene-oxide) in aqueous mixtures.

    SciTech Connect (OSTI)

    Lal, J.; Hakem, I. F.; IPNS

    2004-10-01T23:59:59.000Z

    The model system of poly(ethylene-oxide) or PEO, where the changing hydrogen-bond connectivity of the water has large effect on the conformation of the polymer chain, in mixtures of water and acetonitrile, is experimentally studied. The results show the existence of a threshold water content in the system at which the 3d connectivity of the water network begins. Unusual expansion of the polymer chain, an effect larger than that observed in either of the pure solvents, is seen. Upon addition of small amounts of a monovalent salt, binding of ion to polymer takes place in pure acetonitrile solutions. Salt ions begin to co-ordinate with water molecules at the same solvent ratio as the threshold for water network formation. Ions now no longer complex to PEO; instead, hydrogen bonding of water to the polymer strongly dictates conformation in this regime.

  13. Robust mixtures in the presence of measurement errors

    E-Print Network [OSTI]

    Jianyong Sun; Ata Kaban; Somak Raychaudhury

    2007-09-06T23:59:59.000Z

    We develop a mixture-based approach to robust density modeling and outlier detection for experimental multivariate data that includes measurement error information. Our model is designed to infer atypical measurements that are not due to errors, aiming to retrieve potentially interesting peculiar objects. Since exact inference is not possible in this model, we develop a tree-structured variational EM solution. This compares favorably against a fully factorial approximation scheme, approaching the accuracy of a Markov-Chain-EM, while maintaining computational simplicity. We demonstrate the benefits of including measurement errors in the model, in terms of improved outlier detection rates in varying measurement uncertainty conditions. We then use this approach in detecting peculiar quasars from an astrophysical survey, given photometric measurements with errors.

  14. air-gas mixture khitinsoderzhashchie: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cooling, spray painting or transport of bubbly liquids. Normally, we. Cavitation: Francis turbine, cavitation damage and old repairs with stainless steel welding Mixture balance -...

  15. Thermal light cannot be represented as a statistical mixture of pulses

    E-Print Network [OSTI]

    Aurélia Chenu; Agata M. Bra?czyk; Gregory D. Scholes; J. E. Sipe

    2014-11-28T23:59:59.000Z

    We ask whether or not thermal light can be represented as a mixture of single broadband coherent pulses. We find that it cannot. Such a mixture of pulses is simply not rich enough to mimic thermal light; indeed, it cannot even reproduce the first-order correlation function. We show that it is possible to construct a modified mixture of single coherent pulses that does yield the correct first-order correlation function at equal space points. However, as we then demonstrate, such a mixture cannot reproduce the second-order correlation function.

  16. Differential effects of a complex organochlorine mixture on the proliferation of breast cancer cell lines

    SciTech Connect (OSTI)

    Aube, Michel, E-mail: 4aubem@videotron.ca [Axe de recherche en sante des populations et environnementale, Centre de recherche du Centre hospitalier universitaire de Quebec and Universite Laval, 2875 Boulevard Laurier, Edifice Delta 2, bureau 600, Quebec, QC, Canada G1V 2M2 (Canada)] [Axe de recherche en sante des populations et environnementale, Centre de recherche du Centre hospitalier universitaire de Quebec and Universite Laval, 2875 Boulevard Laurier, Edifice Delta 2, bureau 600, Quebec, QC, Canada G1V 2M2 (Canada); Larochelle, Christian, E-mail: christian.larochelle@inspq.qc.ca [Axe de recherche en sante des populations et environnementale, Centre de recherche du Centre hospitalier universitaire de Quebec and Universite Laval, 2875 Boulevard Laurier, Edifice Delta 2, bureau 600, Quebec, QC, Canada G1V 2M2 (Canada)] [Axe de recherche en sante des populations et environnementale, Centre de recherche du Centre hospitalier universitaire de Quebec and Universite Laval, 2875 Boulevard Laurier, Edifice Delta 2, bureau 600, Quebec, QC, Canada G1V 2M2 (Canada); Ayotte, Pierre, E-mail: pierre.ayotte@inspq.qc.ca [Axe de recherche en sante des populations et environnementale, Centre de recherche du Centre hospitalier universitaire de Quebec and Universite Laval, 2875 Boulevard Laurier, Edifice Delta 2, bureau 600, Quebec, QC, Canada G1V 2M2 (Canada) [Axe de recherche en sante des populations et environnementale, Centre de recherche du Centre hospitalier universitaire de Quebec and Universite Laval, 2875 Boulevard Laurier, Edifice Delta 2, bureau 600, Quebec, QC, Canada G1V 2M2 (Canada); Laboratoire de Toxicologie, Institut national de sante publique du Quebec, 945 avenue Wolfe, Quebec, QC, Canada G1V 5B3 (Canada)

    2011-04-15T23:59:59.000Z

    Organochlorine compounds (OCs) are a group of persistent chemicals that accumulate in fatty tissues with age. Although OCs has been tested individually for their capacity to induce breast cancer cell proliferation, few studies examined the effect of complex mixtures that comprise compounds frequently detected in the serum of women. We constituted such an OC mixture containing 15 different components in environmentally relevant proportions and assessed its proliferative effects in four breast cancer cell lines (MCF-7, T47D, CAMA-1, MDAMB231) and in non-cancerous CV-1 cells. We also determined the capacity of the mixture to modulate cell cycle stage of breast cancer cells and to induce estrogenic and antiandrogenic effects using gene reporter assays. We observed that low concentrations of the mixture (100x10{sup 3} and 50x10{sup 3} dilutions) stimulated the proliferation of MCF-7 cells while higher concentrations (10x10{sup 3} and 5x10{sup 3} dilutions) had the opposite effect. In contrast, the mixture inhibited the proliferation of non-hormone-dependent cell lines. The mixture significantly increased the number of MCF-7 cells entering the S phase, an effect that was blocked by the antiestrogen ICI 182,780. Low concentrations of the mixture also caused an increase in CAMA-1 cell proliferation but only in the presence estradiol and dihydrotestosterone (p<0.05 at the 50x10{sup 3} dilution). DDT analogs and polychlorinated biphenyls all had the capacity to stimulate the proliferation of CAMA-1 cells in the presence of sex steroids. Reporter gene assays further revealed that the mixture and several of its constituents (DDT analogs, aldrin, dieldrin, {beta}-hexachlorocyclohexane, toxaphene) induced estrogenic effects, whereas the mixture and several components (DDT analogs, aldrin, dieldrin and PCBs) inhibited the androgen signaling pathway. Our results indicate that the complex OC mixture increases the proliferation of MCF-7 cells due to its estrogenic potential. The proliferative effect of the mixture on CAMA-1 cells in the presence of sex steroids appears mostly due to the antiandrogenic properties of p,p'-DDE, a major constituent of the mixture. Other mixtures of contaminants that include emerging compounds of interest such as brominated flame retardants and perfluoroalkyl compounds should be tested for their capacity to induce breast cancer cell proliferation. - Research highlights: {yields} We studied effects of a complex organochlorine mixture on breast cancer cell growth. {yields} Weak xenoestrogens in the mixture stimulated the proliferation of MCF-7 cells. {yields} Antiandrogens increased the proliferation CAMA-1 cells grown with sex steroids. {yields} High concentrations of the mixture decreased the proliferation of all cell lines.

  17. Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.; Viani, Brian

    2013-01-29T23:59:59.000Z

    A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.

  18. Production and delivery of a fluid mixture to an annular volume of a wellbore

    SciTech Connect (OSTI)

    Hermes, Robert E. (Los Alamos, NM); Bland, Ronald Gene (Houston, TX); Foley, Ron Lee (Magnolia, TX); Bloys, James B. (Katy, TX); Gonzalez, Manuel E. (Kingwood, NM); Daniel, John M. (Germantown, TN); Robinson, Ian M. (Guisborough, GB); Carpenter, Robert B. (Tomball, TX)

    2012-01-24T23:59:59.000Z

    The methods described herein generally relate to preparing and delivering a fluid mixture to a confined volume, specifically an annular volume located between two concentrically oriented casing strings within a hydrocarbon fluid producing well. The fluid mixtures disclosed herein are useful in controlling pressure in localized volumes. The fluid mixtures comprise at least one polymerizable monomer and at least one inhibitor. The processes and methods disclosed herein allow the fluid mixture to be stored, shipped and/or injected into localized volumes, for example, an annular volume defined by concentric well casing strings.

  19. CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

    SciTech Connect (OSTI)

    Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

    2001-12-01T23:59:59.000Z

    The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

  20. Electrosorption selectivity of ions from mixtures of electrolytes inside nanopores

    SciTech Connect (OSTI)

    Hou, Chia-Hung [Georgia Institute of Technology; Taboada Serrano, Patricia L [ORNL; Yiacoumi, Sotira [Georgia Institute of Technology; Tsouris, Costas [ORNL

    2008-01-01T23:59:59.000Z

    Grand canonical Monte Carlo (GCMC) simulations are employed to study the selective electrosorption of ions from a mixture of symmetric and asymmetric electrolytes confined in pores and results are compared to experimental observations obtained via cyclic voltammetry and batch electrosorption equilibrium experiments. GCMC simulations have the advantage over other Monte Carlo methods to unambiguously quantify the total number of ions in the pore solution. The exclusion parameter and selectivity factor are used to evaluate the selective capacity of pores toward different ionic species under various conditions. The number of coions inside the pore solution is determined by the proportion of different counterions present in the double-layer region. Because of the competitive effects resulting from asymmetries in charge and size associated with different ions, the electrosorption selectivity of small monovalent over large divalent counterions first decreases with increasing surface charge, passes through a minimum, and then increases with further increase in surface charge. At low and moderate surface charge densities, the fact that large divalent counterions preferentially screen the surface charge has a strong effect on pore occupancy; whereas at a very high surface charge density, size-exclusion effects dominate and determine the accessibility of different ions into the pores. Therefore, electrosorption selectivity of ions from a mixture of electrolytes could, in principle, be achieved via tuning the electrical double-layer formation inside the pores through the regulation of surface charge tailored for different ion characteristics. The findings of this work provide important information relevant to ion selectivity during separation processes and energy storage in supercapacitors.

  1. Kalman filter mixture model for spike sorting of non-stationary Ana Calabrese and Liam Paninski

    E-Print Network [OSTI]

    Columbia University

    Kalman filter mixture model for spike sorting of non-stationary data Ana Calabrese and Liam. Our algorithm is based on a computationally efficient Kalman filter model; the recursive nature and real data. Keywords: Spike sorting; non-stationarity; Kalman filter; hidden Markov model; mixture model

  2. Adsorption of Charge-Bidisperse Mixtures of Colloidal Jeffrey J. Gray and Roger T. Bonnecaze*

    E-Print Network [OSTI]

    Gray, Jeffrey J.

    Adsorption of Charge-Bidisperse Mixtures of Colloidal Particles Jeffrey J. Gray and Roger T with the number of components in the system. Here, we perform simulations of the adsorption of binary mixtures%. In sequential adsorption, small amounts of the second component adsorb only for parameter combinations

  3. MOBILITIES OF POSITIVE IONS IN SOME GAS MIXTURES USED IN PROPORTIONAL AND DRIFT CHAMBERS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    67 MOBILITIES OF POSITIVE IONS IN SOME GAS MIXTURES USED IN PROPORTIONAL AND DRIFT CHAMBERS G proportional chambers or drift chambers with gas mixtures, using isobutane as a quencher. The positive ions, révisé le 11 juin 1976, accepté le 2 septembre 1976) Résumé. 2014 Le coefficient de mobilité des ions

  4. Maximum Likelihood Estimation of Mixture Densities for Binned and Truncated Multivariate

    E-Print Network [OSTI]

    Smyth, Padhraic

    Maximum Likelihood Estimation of Mixture Densities for Binned and Truncated Multivariate Data in data analysis and machine learning. This paper addresses the problem of fitting mixture densities to multivariate binned and truncated data. The EM approach proposed by McLachlan and Jones (1988

  5. Comment on "A Look at the Multiphase Mixture Model for PEM Fuel Cell Simulations"

    E-Print Network [OSTI]

    Comment on "A Look at the Multiphase Mixture Model for PEM Fuel Cell Simulations" [Electrochem received June 2, 2008. Published December 11, 2008. The article of Gurau et al.1 discusses the multiphase mixture M2 model developed by Wang and co-workers2-6 over the last 15 years for the modeling of multiphase

  6. In Search of Deterministic Methods for Initializing K-Means and Gaussian Mixture

    E-Print Network [OSTI]

    Dy, Jennifer G.

    In Search of Deterministic Methods for Initializing K-Means and Gaussian Mixture Clustering Ting Su of K-means and Gaussian mixture model (GMM) clustering depends on the initial guess of partitions) partitioning and Var-Part (Variance Partitioning). K-means clustering tries to minimize the sum-squared- error

  7. Low-Frequency Electrical Properties of Ice-Silicate Mixtures David E. Stillman,*,

    E-Print Network [OSTI]

    Stillman, David E.

    Low-Frequency Electrical Properties of Ice-Silicate Mixtures David E. Stillman,*, Robert E. Grimm The low-frequency electrical properties of mixtures of silicates and saline H2O were measured over broad are able to form in proximity to silicate surfaces. Five dielectric relaxations related to H2O were

  8. Electrical properties of saline ices and ice-silicate mixtures: geophysical and astrobiological consequences (Invited)

    E-Print Network [OSTI]

    Stillman, David E.

    MR22A-05 Electrical properties of saline ices and ice-silicate mixtures: geophysical) electrical-properties measurements of laboratory- produced saline ice, salt hydrates, and ice-silicate cutoff. In ice-silicate mixtures, brine channels are evident above the eutectic temperature only when

  9. Estimating a mixture of two product distributions Yoav Freund \\Lambda Yishay Mansour y

    E-Print Network [OSTI]

    Mansour, Yishay

    Estimating a mixture of two product distributions Yoav Freund \\Lambda Yishay Mansour y March 1, 1999 Abstract We describe an efficient algorithm for estimating a mixture of two product distributions meaningful structure in the data. One way to find a structure in the data is to approximate the distribution

  10. Nickel Sorption Mechanisms in a PyrophylliteMontmorillonite Mixture Evert J. Elzinga1

    E-Print Network [OSTI]

    Sparks, Donald L.

    Nickel Sorption Mechanisms in a Pyrophyllite­Montmorillonite Mixture Evert J. Elzinga1 and Donald L-mail: elzinga@udel.edu Received October 6, 1998; accepted February 17, 1999 Nickel sorption on pyrophyllite over the mixture components. Nickel uptake on singly reacted pyrophyllite was slightly higher than

  11. A phylogenetic mixture model for gene family loss in parasitic bacteria

    E-Print Network [OSTI]

    A phylogenetic mixture model for gene family loss in parasitic bacteria Submitted as a research words: gene families, mixture model, parasites, maximum likelihood,phylogenetics Running head: gene family gain and loss 1 #12;Abstract Gene families are frequently gained and lost from prokaryotic genomes

  12. AN EXPERIMENTAL INVESTIGATION ON FLOW BOILING OF ETHYLENE-GLYCOL/WATER MIXTURE

    E-Print Network [OSTI]

    Kandlikar, Satish

    are used in cooling the engines in automotive applications. To avoid the two-phase flow in the engine coefficient values over a small circular aluminum heater surface, 9.5-mm in diameter, placed at the bottom-glycol mixtures is in automotive engine cooling. Although this mixture has been used for over several decades

  13. Enhancing Hand Gesture Recognition using Fuzzy Clustering-based Mixture-of-Experts Model

    E-Print Network [OSTI]

    Cho, Sung-Bae

    Enhancing Hand Gesture Recognition using Fuzzy Clustering-based Mixture-of-Experts Model Jong cannot distinguish them accurately since they use only single model for recognition. For efficient hand gesture recognition with its enhanced performance, we propose the fuzzy c-means clustering based mixture

  14. Experimental investigation of burning velocities of ultra-wet methane-air-steam mixtures

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , steam, burning velocity, chemiluminescence, OH Introduction In ultra-wet gas turbines, the heatExperimental investigation of burning velocities of ultra-wet methane-air-steam mixtures Eric Abstract Global burning velocities of methane-air-steam mixtures are measured on prismatic laminar Bunsen

  15. SAFETY OF HYDROGEN/NATURAL GAS MIXTURES BY PIPELINES: ANR FRENCH PROJECT HYDROMEL

    E-Print Network [OSTI]

    Boyer, Edmond

    1 SAFETY OF HYDROGEN/NATURAL GAS MIXTURES BY PIPELINES: ANR FRENCH PROJECT HYDROMEL Hébrard, J.1 linked with Hydrogen/Natural gas mixtures transport by pipeline, the National Institute of Industrial scenario, i.e. how the addition of a quantity of hydrogen in natural gas can increase the potential

  16. Structure and dynamics of nonaqueous mixtures of dipolar liquids. II. Molecular dynamics simulations

    E-Print Network [OSTI]

    2000 Molecular dynamics simulations have been used to study mixtures of acetone/methanol, acetonitrile/ methanol, and acetone/acetonitrile over their entire composition range. Using the effective pair potentials in these two papers is on the nonaqueous dipolar liquid mixtures of acetone/methanol, acetonitrile

  17. Two-Phase Flow of Two HFC Refrigerant Mixtures Through Short Tube Orifices, Draft Final Report

    E-Print Network [OSTI]

    Payne, W. V.; O'Neal, D. L.

    1994-01-01T23:59:59.000Z

    The present study presents data for flow of two refrigerant mixtures through short tube orifices. The two mixtures were R3211251134a (23%/25%/52% on a mass percentage basis) and R321125 (50%/50%). The following presents results for the flow...

  18. Functions of Mg and Mg-CaO mixtures in hot metal desulphurization David Lindstrma

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Functions of Mg and Mg-CaO mixtures in hot metal desulphurization David Lindströma , Patrice of hot metal desulphurization using Mg and Mg-CaO mixtures were studied in a newly designed setup published online" DOI : 10.1002/srin.201300071 #12;Introduction Hot metal desulphurization is an important

  19. Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen in the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen and nitrogen gas separation is achieved through clathrate hydrate formation in the presence of cyclopentane the corresponding mole fraction in the gas mixture amounts to 0.507. When compared to the three phase hydrate

  20. Method and compositions for the degradation of tributyl phosphate in chemical waste mixtures

    DOE Patents [OSTI]

    Stoner, Daphne L. (Idaho Falls, ID); Tien, Albert J. (Zurich, CH)

    1995-01-01T23:59:59.000Z

    A method and process for the degradation of tributyl phosphate in an organic waste mixture and a biologically pure, novel bacteria culture for accomplishing the same. A newly-discovered bacteria (a strain of Acinetobacter sp. ATCC 55587) is provided which is combined in a reactor vessel with a liquid waste mixture containing tributyl phosphate and one or more organic waste compounds capable of functioning as growth substrates for the bacteria. The bacteria is thereafter allowed to incubate within the waste mixture. As a result, the tributyl phosphate and organic compounds within the waste mixture are metabolized (degraded) by the bacteria, thereby eliminating such materials which are environmentally hazardous. In addition, the bacteria is capable of degrading waste mixtures containing high quantities of tributyl phosphate (e.g. up to about 1.0% by weight tributyl phosphate).

  1. Method and compositions for the degradation of tributyl phosphate in chemical waste mixtures

    DOE Patents [OSTI]

    Stoner, D.L.; Tien, A.J.

    1995-09-26T23:59:59.000Z

    A method and process are disclosed for the degradation of tributyl phosphate in an organic waste mixture and a biologically pure, novel bacteria culture for accomplishing the same. A newly-discovered bacteria (a strain of Acinetobacter sp. ATCC 55587) is provided which is combined in a reactor vessel with a liquid waste mixture containing tributyl phosphate and one or more organic waste compounds capable of functioning as growth substrates for the bacteria. The bacteria is thereafter allowed to incubate within the waste mixture. As a result, the tributyl phosphate and organic compounds within the waste mixture are metabolized (degraded) by the bacteria, thereby eliminating such materials which are environmentally hazardous. In addition, the bacteria is capable of degrading waste mixtures containing high quantities of tributyl phosphate (e.g. up to about 1.0% by weight tributyl phosphate). 6 figs.

  2. Thermo-statistical description of gas mixtures from space partitions

    E-Print Network [OSTI]

    R. D. Rohrmann; J. Zorec

    2006-09-23T23:59:59.000Z

    The new mathematical framework based on the free energy of pure classical fluids presented in [R. D. Rohrmann, Physica A 347, 221 (2005)] is extended to multi-component systems to determine thermodynamic and structural properties of chemically complex fluids. Presently, the theory focuses on $D$-dimensional mixtures in the low-density limit (packing factor $\\eta < 0.01$). The formalism combines the free-energy minimization technique with space partitions that assign an available volume $v$ to each particle. $v$ is related to the closeness of the nearest neighbor and provides an useful tool to evaluate the perturbations experimented by particles in a fluid. The theory shows a close relationship between statistical geometry and statistical mechanics. New, unconventional thermodynamic variables and mathematical identities are derived as a result of the space division. Thermodynamic potentials $\\mu_{il}$, conjugate variable of the populations $N_{il}$ of particles class $i$ with the nearest neighbors of class $l$ are defined and their relationships with the usual chemical potentials $\\mu_i$ are established. Systems of hard spheres are treated as illustrative examples and their thermodynamics functions are derived analytically. The low-density expressions obtained agree nicely with those of scaled-particle theory and Percus-Yevick approximation. Several pair distribution functions are introduced and evaluated. Analytical expressions are also presented for hard spheres with attractive forces due to K\\^ac-tails and square-well potentials. Finally, we derive general chemical equilibrium conditions.

  3. Process for the synthesis of aliphatic alcohol-containing mixtures

    DOE Patents [OSTI]

    Greene, M.I.; Gelbein, A.P.

    1984-10-16T23:59:59.000Z

    A process for the synthesis of mixtures which include saturated aliphatic alcohols is disclosed. In the first step of the process, the first catalyst activation stage, a catalyst, which comprises the oxides of copper, zinc, aluminum, potassium and one or two additional metals selected from the group consisting of chromium, magnesium, cerium, cobalt, thorium and lanthanum, is partially activated. In this step, a reducing gas stream, which includes hydrogen and at least one inert gas, flows past the catalyst at a space velocity of up to 5,000 liters (STP) per hour, per kilogram of catalyst. The partially activated catalyst is then subjected to the second step of the process, second-stage catalyst activation. In this step, the catalyst is contacted by an activation gas stream comprising hydrogen and carbon monoxide present in a volume ratio of 0.5:1 and 4:1, respectively, at a temperature of 200 to 450 C and a pressure of between 35 and 200 atmospheres. The activation gas flows at a space velocity of from 1,000 to 20,000 liters (STP) per hour, per kilogram of catalyst. Second-stage activation continues until the catalyst is contacted with at least 500,000 liters (STP) of activation gas per kilogram of catalyst. The fully activated catalyst, in the third step of the process, contacts a synthesis gas stream comprising hydrogen and carbon monoxide.

  4. Process for the synthesis of aliphatic alcohol-containing mixtures

    DOE Patents [OSTI]

    Greene, Marvin I. (Oradell, NJ); Gelbein, Abraham P. (Morristown, NJ)

    1984-01-01T23:59:59.000Z

    A process for the synthesis of mixtures which include saturated aliphatic alcohols is disclosed. In the first step of the process, the first catalyst activation stage, a catalyst, which comprises the oxides of copper, zinc, aluminum, potassium and one or two additional metals selected from the group consisting of chromium, magnesium, cerium, cobalt, thorium and lanthanum, is partially activated. In this step, a reducing gas stream, which includes hydrogen and at least one inert gas, flows past the catalyst at a space velocity of up to 5,000 liters (STP) per hour, per kilogram of catalyst. The partially activated catalyst is then subjected to the second step of the process, second-stage catalyst activation. In this step, the catalyst is contacted by an activation gas stream comprising hydrogen and carbon monoxide present in a volume ratio of 0.5:1 and 4:1, respectively, at a temperature of 200.degree. to 450.degree. C. and a pressure of between 35 and 200 atmospheres. The activation gas flows at a space velocity of from 1,000 to 20,000 liters (STP) per hour, per kilogram of catalyst. Second-stage activation continues until the catalyst is contacted with at least 500,000 liters (STP) of activation gas per kilogram of catalyst. The fully activated catalyst, in the third step of the process, contacts a synthesis gas stream comprising hydrogen and carbon monoxide.

  5. Structural changes in block copolymer micelles induced by cosolvent mixtures

    SciTech Connect (OSTI)

    Kelley, Elizabeth G.; Smart, Thomas P.; Jackson, Andrew J.; Sullivan, Millicent O.; Epps, III, Thomas H. (Delaware)

    2012-11-26T23:59:59.000Z

    We investigated the influence of tetrahydrofuran (THF) addition on the structure of poly(1,2-butadiene-b-ethylene oxide) [PB-PEO] micelles in aqueous solution. Our studies showed that while the micelles remained starlike, the micelle core-corona interfacial tension and micelle size decreased upon THF addition. The detailed effects of the reduction in interfacial tension were probed using contrast variations in small angle neutron scattering (SANS) experiments. At low THF contents (high interfacial tensions), the SANS data were fit to a micelle form factor that incorporated a radial density distribution of corona chains to account for the starlike micelle profile. However, at higher THF contents (low interfacial tensions), the presence of free chains in solution affected the scattering at high q and required the implementation of a linear combination of micelle and Gaussian coil form factors. These SANS data fits indicated that the reduction in interfacial tension led to broadening of the core-corona interface, which increased the PB chain solvent accessibility at intermediate THF solvent fractions. We also noted that the micelle cores swelled with increasing THF addition, suggesting that previous assumptions of the micelle core solvent content in cosolvent mixtures may not be accurate. Control over the size, corona thickness, and extent of solvent accessible PB in these micelles can be a powerful tool in the development of targeting delivery vehicles.

  6. Polymer Crowding and Shape Distributions in Polymer-Nanoparticle Mixtures

    E-Print Network [OSTI]

    Wei Kang Lim; Alan R. Denton

    2014-10-24T23:59:59.000Z

    Macromolecular crowding can influence polymer shapes, which is important for understanding the thermodynamic stability of polymer solutions and the structure and function of biopolymers (proteins, RNA, DNA) under confinement. We explore the influence of nanoparticle crowding on polymer shapes via Monte Carlo simulations and free-volume theory of a coarse-grained model of polymer-nanoparticle mixtures. Exploiting the geometry of random walks, we model polymer coils as effective penetrable ellipsoids, whose shapes fluctuate according to the probability distributions of the eigenvalues of the gyration tensor. Accounting for the entropic cost of a nanoparticle penetrating a larger polymer coil, we compute the crowding-induced shift in the shape distributions, radius of gyration, and asphericity of ideal polymers in a theta solvent. With increased nanoparticle crowding, we find that polymers become more compact (smaller, more spherical), in agreement with predictions of free-volume theory. Our approach can be easily extended to nonideal polymers in good solvents and used to model conformations of biopolymers in crowded environments.

  7. Flammability of selected heat resistant alloys in oxygen gas mixtures

    SciTech Connect (OSTI)

    Zawierucha, R.; McIlroy, K.; Million, J.F. [Praxair, Inc., Tonawanda, NY (United States)

    1995-12-31T23:59:59.000Z

    Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

  8. Physical and mechanical properties of bituminous mixtures containing oil shales

    SciTech Connect (OSTI)

    Katamine, N.M.

    2000-04-01T23:59:59.000Z

    Rutting of bituminous surfaces on the Jordanian highways is a recurring problem. Highway authorities are exploring the use of extracted shale oil and oil shale fillers, which are abundant in Jordan. The main objectives of this research are to investigate the rheological properties of shale oil binders (conventional binder with various percentages of shale oil), in comparison with a conventional binder, and to investigate the ability of mixes to resist deformation. The latter is done by considering three wearing course mixes containing three different samples of oil shale fillers--which contained three different oil percentages--together with a standard mixture containing limestone filler. The Marshall design method and the immersion wheel tracking machine were adopted. It was concluded that the shale oil binders displayed inconsistent physical properties and therefore should be treated before being used. The oil shale fillers have provided mixes with higher ability to resist deformation than the standard mix, as measured by the Marshall quotients and the wheel tracking machine. The higher the percentages of oil in the oil shale fillers, the lower the ability of the mixes to resist deformation.

  9. Flammability Characteristics of Hydrogen and Its Mixtures with Light Hydrocarbons at Atmospheric and Sub-atmospheric Pressures 

    E-Print Network [OSTI]

    Le, Thuy Minh Hai

    2013-07-13T23:59:59.000Z

    /vapor. This research focuses on the flammability limits of hydrogen and its binary mixtures with light hydrocarbons (methane, ethane, n-butane, and ethylene) at sub-atmospheric pressures. The flammability limits of hydrogen, light hydrocarbons, and binary mixtures...

  10. Measurement of nitrogen content in a gas mixture by transforming the nitrogen into a substance detectable with nondispersive infrared detection

    DOE Patents [OSTI]

    Owen, Thomas E.; Miller, Michael A.

    2007-03-13T23:59:59.000Z

    A method of determining the amount of nitrogen in a gas mixture. The constituent gases of the mixture are dissociated and transformed to create a substance that may measured using nondispersive infrared adsorption techniques.

  11. Measurement of nitrogen content in a gas mixture by transforming the nitrogen into a substance detectable with nondispersive infrared detection

    DOE Patents [OSTI]

    Owen, Thomas E. (Helotes, TX); Miller, Michael A. (San Antonio, TX)

    2010-08-24T23:59:59.000Z

    A method of determining the amount of nitrogen in a gas mixture. The constituent gases of the mixture are dissociated and transformed to create a substance that may measured using nondispersive infrared adsorption techniques.

  12. Study of the aggregation behaviour of egg yolk lecithin/bile salt mixtures by increasing the ionic strength 

    E-Print Network [OSTI]

    Madenci, Dilek

    2009-11-25T23:59:59.000Z

    This thesis describes a study of the aggregational behaviour of egg yolk lecithin (EYL), a natural lecithin, and bile salt mixtures especially with respect to an increase of the ionic strength of the solvent. Mixtures ...

  13. Flammability Characteristics of Hydrogen and Its Mixtures with Light Hydrocarbons at Atmospheric and Sub-atmospheric Pressures

    E-Print Network [OSTI]

    Le, Thuy Minh Hai

    2013-07-13T23:59:59.000Z

    /vapor. This research focuses on the flammability limits of hydrogen and its binary mixtures with light hydrocarbons (methane, ethane, n-butane, and ethylene) at sub-atmospheric pressures. The flammability limits of hydrogen, light hydrocarbons, and binary mixtures...

  14. Irreversible Processes in a Universe modelled as a mixture of a Chaplygin gas and radiation

    E-Print Network [OSTI]

    G. M. Kremer

    2003-03-26T23:59:59.000Z

    The evolution of a Universe modelled as a mixture of a Chaplygin gas and radiation is determined by taking into account irreversible processes. This mixture could interpolate periods of a radiation dominated, a matter dominated and a cosmological constant dominated Universe. The results of a Universe modelled by this mixture are compared with the results of a mixture whose constituents are radiation and quintessence. Among other results it is shown that: (a) for both models there exists a period of a past deceleration with a present acceleration; (b) the slope of the acceleration of the Universe modelled as a mixture of a Chaplygin gas with radiation is more pronounced than that modelled as a mixture of quintessence and radiation; (c) the energy density of the Chaplygin gas tends to a constant value at earlier times than the energy density of quintessence does; (d) the energy density of radiation for both mixtures coincide and decay more rapidly than the energy densities of the Chaplygin gas and of quintessence.

  15. Method of separating short half-life radionuclides from a mixture of radionuclides

    DOE Patents [OSTI]

    Bray, Lane A. (Richland, WA); Ryan, Jack L. (West Richland, WA)

    1999-01-01T23:59:59.000Z

    The present invention is a method of removing an impurity of plutonium, lead or a combination thereof from a mixture of radionuclides that contains the impurity and at least one parent radionuclide. The method has the steps of (a) insuring that the mixture is a hydrochloric acid mixture; (b) oxidizing the acidic mixture and specifically oxidizing the impurity to its highest oxidation state; and (c) passing the oxidized mixture through a chloride form anion exchange column whereupon the oxidized impurity absorbs to the chloride form anion exchange column and the 22.sup.9 Th or 2.sup.27 Ac "cow" radionuclide passes through the chloride form anion exchange column. The plutonium is removed for the purpose of obtaining other alpha emitting radionuclides in a highly purified form suitable for medical therapy. In addition to plutonium; lead, iron, cobalt, copper, uranium, and other metallic cations that form chloride anionic complexes that may be present in the mixture; are removed from the mixture on the chloride form anion exchange column.

  16. Method of separating short half-life radionuclides from a mixture of radionuclides

    DOE Patents [OSTI]

    Bray, L.A.; Ryan, J.L.

    1999-03-23T23:59:59.000Z

    The present invention is a method of removing an impurity of plutonium, lead or a combination thereof from a mixture of radionuclides that contains the impurity and at least one parent radionuclide. The method has the steps of (a) insuring that the mixture is a hydrochloric acid mixture; (b) oxidizing the acidic mixture and specifically oxidizing the impurity to its highest oxidation state; and (c) passing the oxidized mixture through a chloride form anion exchange column whereupon the oxidized impurity absorbs to the chloride form anion exchange column and the {sup 229}Th or {sup 227}Ac ``cow`` radionuclide passes through the chloride form anion exchange column. The plutonium is removed for the purpose of obtaining other alpha emitting radionuclides in a highly purified form suitable for medical therapy. In addition to plutonium, lead, iron, cobalt, copper, uranium, and other metallic cations that form chloride anionic complexes that may be present in the mixture are removed from the mixture on the chloride form anion exchange column. 8 figs.

  17. Flame Propagation of Butanol Isomers/Air Mixtures

    SciTech Connect (OSTI)

    Veloo, Peter S.; Egolfopoulos, Fokion N.

    2011-01-01T23:59:59.000Z

    An experimental and computational study was conducted on the propagation of flames of saturated butanol isomers. The experiments were performed in the counterflow configuration under atmospheric pressure, unburned mixture temperature of 343 K, and for a wide range of equivalence ratios. The experiments were simulated using a recent kinetic model for the four isomers of butanol. Results indicate that n-butanol/air flames propagate somewhat faster than both sec-butanol/air and iso-butanol/air flames, and that tert-butanol/air flames propagate notably slower compared to the other three isomers. Reaction path analysis of tert-butanol/air flames revealed that iso-butene is a major intermediate, which subsequently reacts to form the resonantly stable iso-butenyl radical retarding thus the overall reactivity of tert-butanol/air flames relatively to the other three isomers. Through sensitivity analysis, it was determined that the mass burning rates of sec-butanol/air and iso-butanol/air flames are sensitive largely to hydrogen, carbon monoxide, and C{sub 1}–C{sub 2} hydrocarbon kinetics and not to fuel-specific reactions similarly to n-butanol/air flames. However, for tert-butanol/air flames notable sensitivity to fuel-specific reactions exists. While the numerical results predicted closely the experimental data for n-butanol/air and sec-butanol/air flames, they overpredicted and underpredicted the laminar flame speeds for iso-butanol/air and tert-butanol/air flames respectively. It was demonstrated further that the underprediction of the laminar flame speeds of tert-butanol/air flames by the model was most likely due to deficiencies of the C{sub 4}-alkene kinetics.

  18. Properties of concrete containing wood/coal fly ash mixtures

    SciTech Connect (OSTI)

    Boylan, D.M.; Larrimore, C.L.; Fouad, F.

    1999-07-01T23:59:59.000Z

    Utilities are increasingly interested in co-firing wood with coal in existing pulverized coal units. The co-firing technology is a means of developing a relatively low-cost renewable energy resource, as well as of supporting customers and community by making energy with biomass that might otherwise have been land-filled. However, recent changes in the ASTM C618 standard for fly ash as cement replacement restrict the definition of fly ash that includes non-coal sources. As a result, wood co-firing could affect the market for the fly ash, reducing ash sales revenue, increasing ash disposal costs, and overall substantially increasing the cost of the co-firing technology. In order to address concerns about the effect of wood ash/coal ash mixtures on concrete properties, a study was conducted by University of Alabama at Birmingham, Southern Company, EPRI, and the State of Alabama. This study compared the effects on properties of concrete made with fly ash from coal and made with fly ash from co-firing up to 30% wood with coal. Fly ashes from three plants were used, with two of the ashes from actual co-firing experience and the third an artificial blend of wood and coal ash. Concrete test cylinders were made of several cement/fly ash mixes, and enough were made to allow testing periodically over a one year time period. Test measurements included workability, setting time, air content, compressive and flexural strength, rapid chloride permeability and freeze thaw. It was concluded on the basis of these tests that the wood ash content had no detrimental effect on the plastic and hardened properties of the concrete.

  19. In vitro - in vivo correlations for endocrine activity of a mixture of currently used pesticides

    SciTech Connect (OSTI)

    Taxvig, Camilla, E-mail: camta@food.dtu.dk [Division of Toxicology and Risk Assessment, National Food Institute, Technical University of Denmark, Mørkhøj Bygade 19, DK-2860 Søborg (Denmark); Hadrup, Niels; Boberg, Julie; Axelstad, Marta [Division of Toxicology and Risk Assessment, National Food Institute, Technical University of Denmark, Mørkhøj Bygade 19, DK-2860 Søborg (Denmark); Bossi, Rossana [Department of Environmental Science, Aarhus University, DK-4000 Roskilde (Denmark); Bonefeld-Jørgensen, Eva Cecilie [Department of Public Health, University of Aarhus, DK-8000 Aarhus C (Denmark); Vinggaard, Anne Marie [Division of Toxicology and Risk Assessment, National Food Institute, Technical University of Denmark, Mørkhøj Bygade 19, DK-2860 Søborg (Denmark)

    2013-11-01T23:59:59.000Z

    Two pesticide mixtures were investigated for potential endocrine activity. Mix 3 consisted of bitertanol, propiconazole, and cypermethrin, and Mix 5 included malathion and terbuthylazine in addition to the three pesticides in Mix 3. All five single pesticides and the two mixtures were investigated for their ability to affect steroidogenesis in vitro in H295R cells. The pesticides alone and both mixtures affected steroidogenesis with both mixtures causing increase in progesterone and decrease in testosterone. For Mix 5 an increase in estradiol was seen as well, indicating increased aromatase activity. The two mixtures were also investigated in pregnant rats dosed from gestational day 7 to 21, followed by examination of dams and fetuses. Decreased estradiol and reduced placental testosterone were seen in dams exposed to Mix 5. Also a significant increase in aromatase mRNA-levels in female adrenal glands was found for Mix5. However, either of the two mixtures showed any effects on fetal hormone levels in plasma or testis, or on anogenital distance. Overall, potential aromatase induction was found for Mix 5 both in vitro and in vivo, but not for Mix 3, an effect likely owed to terbuthylazine in Mix 5. However, the hormonal responses in vitro were only partly reflected in vivo, probably due to some toxicokinetic issues, as the pesticide levels in the amniotic fluid also were found to be negatively affected by the number of compounds present in the mixtures. Nonetheless, the H295R assay gives hints on conceivable interference with steroidogenesis, thus generating hypotheses on in vivo effects. - Highlights: • The study examines the endocrine disrupting potential of mixtures of pesticides. • All single pesticides and both mixtures affected steroidogenesis in vitro. • Potential aromatase induction was found for Mix 5 both in vitro and in vivo. • The hormonal responses in vitro were only partly reflected in vivo.

  20. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

    1984-01-01T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  1. Physical properties of various soil mixtures used for golf green construction

    E-Print Network [OSTI]

    Johns, Don

    1976-01-01T23:59:59.000Z

    in bulk density than either concrete sand or brick sand. Root growth was greater in Brady sand than in brick sand or concrete sand. No significant differences were found between mixtures containing rice hulls and peat moss in their effects... green soil mix- tures. He concluded that mixtures containing 70 to 85% sand and 5 to 10% clay soil by volume with organic matter as the remaining fraction were ideal for golf greens. Howard (7) investigated the behavior of sand-soil-peat mixtures...

  2. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  3. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  4. Nuclear magnetic relaxation and diffusion in liquid CHCl?-CDCl? mixtures 

    E-Print Network [OSTI]

    Prevost, R. J

    1965-01-01T23:59:59.000Z

    of Slopes as Determined from Experimental Plots 35 Self-Diffusion Coefficient for H20 as a Function of Temperature 36 Measured Diffusion Coefficients for CHC13-CDC13 Mixtures 37 Measured Viscosity of CHC1 -CDCl Mixtures . 38 Calculated Diffusion... The diffusion coefficients for the liquid CHC1 -CDCl mixtures are determined experimentally at 0 C, 30 C, and 0 0 60 C for comparison to those calculated. These measurements 0 are made with the spin-echo method, with the apparatus tuned for proton resonance...

  5. Separation of a target substance from a fluid or mixture using encapsulated sorbents

    DOE Patents [OSTI]

    Aines, Roger D; Spadaccini, Christopher M; Stolaroff, Joshuah K; Bourcier, William L; Lewis, Jennifer A; Duoss, Eric B; Vericella, John J

    2014-09-16T23:59:59.000Z

    Method and apparatus for separating a target substance from a fluid or mixture. Capsules having a coating and stripping solvents encapsulated in the capsules are provided. The coating is permeable to the target substance. The capsules having a coating and stripping solvents encapsulated in the capsules are exposed to the fluid or mixture. The target substance migrates through the coating and is taken up by the stripping solvents. The target substance is separated from the fluid or mixture by driving off the target substance from the capsules.

  6. Electrical Properties of SandClay Mixtures Containing Trichloroethylene and Ethanol Jeffery J. Roberts and Dorthe Wildenschild*

    E-Print Network [OSTI]

    Wildenschild, Dorthe

    Electrical Properties of Sand­Clay Mixtures Containing Trichloroethylene and Ethanol Jeffery J, and as an ethanol­water mixture (80:20) was flowed through the sample. Resistivity increased by about a factor of 4 as the ethanol mixture replaced the water solution. Nondestructive x-ray imaging of the sample at various stages

  7. Clustering Dynamics in Water/Methanol Mixtures: A Nuclear Magnetic Resonance Study at 205 K < T < 295 K

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Clustering Dynamics in Water/Methanol Mixtures: A Nuclear Magnetic Resonance Study at 205 K functional groups in water/methanol mixtures at different methanol molar fractions (XMeOH ) 0, 0.04, 0.1, 0 in the mixtures, at all the methanol molar fractions, are faster than those of pure water and methanol because

  8. EXPERIMENTAL AND MODELING STUDY OF THE AUTOIGNITION OF 1-HEXENE / ISO-OCTANE MIXTURES AT LOW TEMPERATURE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    EXPERIMENTAL AND MODELING STUDY OF THE AUTOIGNITION OF 1-HEXENE / ISO-OCTANE MIXTURES AT LOW, France Full-length article Shortened running title : AUTOIGNITION OF 1-HEXENE / ISO-OCTANE MIXTURES * E compression from 630 to 840 K, pressures from 8 to 14 bar, = 1 and for a iso-octane/1-hexene mixture

  9. Gasification of Low Ash Partially Composted Dairy Biomass with Enriched Air Mixture

    E-Print Network [OSTI]

    Thanapal, Siva Sankar

    2012-02-14T23:59:59.000Z

    within the bed increases with increase in oxygen concentration in the gasification medium. Also carbon dioxide concentration in the mixture increases with corresponding decrease in carbon monoxide with increase in oxygen concentration of the incoming...

  10. LiNaK : multi-species apparatus for the study of ultracold quantum degenerate mixtures

    E-Print Network [OSTI]

    Santiago González, Ibon

    2012-01-01T23:59:59.000Z

    This thesis describes the construction of a versatile apparatus to study ultracold quantum mixtures capable of simultaneously cooling fermionic ?Li and ??K, as well as the bosonic ?¹K. The main features of the experimental ...

  11. Inert Gas Dilution Effect on the Flammability Limits of Hydrocarbon Mixtures

    E-Print Network [OSTI]

    Zhao, Fuman

    2012-02-14T23:59:59.000Z

    Flammability limit is a most significant property of substances to ensure safety of chemical processes and fuel application. Although there are numerous flammability literature data available for pure substances, for fuel mixtures...

  12. Gas adsorption and gas mixture separations using mixed-ligand MOF material

    DOE Patents [OSTI]

    Hupp, Joseph T. (Northfield, IL); Mulfort, Karen L. (Chicago, IL); Snurr, Randall Q. (Evanston, IL); Bae, Youn-Sang (Evanston, IL)

    2011-01-04T23:59:59.000Z

    A method of separating a mixture of carbon dioxiode and hydrocarbon gas using a mixed-ligand, metal-organic framework (MOF) material having metal ions coordinated to carboxylate ligands and pyridyl ligands.

  13. Gas adsorption and gas mixture separations using carborane-based MOF material

    DOE Patents [OSTI]

    Farha, Omar K.; Hupp, Joseph T.; Bae, Youn-Sang; Snurr, Randall Q.; Spokoyny, Alexander M.; Mirkin, Chad A.

    2010-06-29T23:59:59.000Z

    A method of separating a mixture of carbon dioxide and a hydrocarbon gas using a metal-organic framework (MOF) material having a three-dimensional carborane ligand structure.

  14. Physical Characteristics of the Dual Phase Region in Mixtures of Recycled Polystyrene/Curbside Tailings Materials

    E-Print Network [OSTI]

    electron microscopy, is interlocked and co-continuous, forming a three dimensional interpenetrating network and Lee University Introduction Virtually all studies of polymer mixtures made by the processing of virgin

  15. ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2006-07-10T23:59:59.000Z

    Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

  16. Meta-Analysis for Longitudinal Data Models using Multivariate Mixture Priors

    E-Print Network [OSTI]

    West, Mike

    of multivariate normals, accomodating population heterogeneity, out- liers and non-linearity in regression. First, the random e#11;ects model is a exible mixture of multivariate normals, accomodating population

  17. A new implementation of k-MLE for mixture modeling of Wishart distributions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    not to have empty clusters. To initialize k-MLE, we propose a careful and greedy strategy inspired by k-means-MLE with mixtures of Wishart (WMMs). Finally, we propose to use the Cauchy- Schwartz divergence as a comparison

  18. Scale-Based Gaussian Coverings: Combining Intra and Inter Mixture Models in Image Segmentation

    E-Print Network [OSTI]

    Murtagh, Fionn; Starck, Jean-Luc

    2009-01-01T23:59:59.000Z

    By a "covering" we mean a Gaussian mixture model fit to observed data. Approximations of the Bayes factor can be availed of to judge model fit to the data within a given Gaussian mixture model. Between families of Gaussian mixture models, we propose the R\\'enyi quadratic entropy as an excellent and tractable model comparison framework. We exemplify this using the segmentation of an MRI image volume, based (1) on a direct Gaussian mixture model applied to the marginal distribution function, and (2) Gaussian model fit through k-means applied to the 4D multivalued image volume furnished by the wavelet transform. Visual preference for one model over another is not immediate. The R\\'enyi quadratic entropy allows us to show clearly that one of these modelings is superior to the other.

  19. Adsorption and desorption of binary mixtures of volatile organic contaminants on soil

    E-Print Network [OSTI]

    Guo, Yang

    1995-01-01T23:59:59.000Z

    , the potential theory and the ideal adsorbed solution theory for mixture adsorption were also evaluated for prediction of the experimental results for binary adsorption. All models failed for prediction of the BET type III isotherms when methanol was present...

  20. A study of new mixture combining rules for prediction of vapor-liquid equilibria

    E-Print Network [OSTI]

    Shyu, Guor-Shiarn

    1993-01-01T23:59:59.000Z

    Wong and Sandler published two important articles in 1992 that established new mixture combining rules (MCR) for use with cubic equations of state (EOS) in the prediction and correlation of vapor-liquid equilibrium (VLE) over wide ranges of pressure...

  1. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOE Patents [OSTI]

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11T23:59:59.000Z

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  2. Bacterial mutagenicity of polycyclic aromatic hydrocarbons in reconstituted mixtures and crude coal tar extracts and fractions

    E-Print Network [OSTI]

    Onufrock, Amy Mildred

    1994-01-01T23:59:59.000Z

    , coal, and oil shale vary widely in the amount and nature of potentially carcinogenic polycyclic aromatic hydrocarbons. Thus, potential carcinogenicity varies widely between representative PAH fractions derived from complex mixtures. PAH fractions...

  3. Kinetic Modeling of Gasoline Surrogate Components and Mixtures under Engine Conditions

    SciTech Connect (OSTI)

    Mehl, M; Pitz, W J; Westbrook, C K; Curran, H J

    2010-01-11T23:59:59.000Z

    Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, an improved version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multicomponent gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines (3-50 atm, 650-1200K, stoichiometric fuel/air mixtures). Simulation results are discussed focusing attention on the mixing effects of the fuel components.

  4. Polymers Pushing Polymers: Polymer Mixtures in Thermodynamic Equilibrium with a Pore

    E-Print Network [OSTI]

    Podgornik, Rudolf

    Polymers Pushing Polymers: Polymer Mixtures in Thermodynamic Equilibrium with a Pore R. Podgornik, 1000 Ljubljana, Slovenia Polymer Science and Engineering Department, University of Massachusetts, Amherst, Massachusetts 01003, United States ABSTRACT: We investigate polymer partitioning from polymer

  5. Improved Resolution of Hydrocarbon Structures and Constitutional Isomers in Complex Mixtures Using Gas Chromatography-Vacuum

    E-Print Network [OSTI]

    Cohen, Ronald C.

    structural constraints. The capabilities of this analysis are explored using diesel fuel, in which is more important in diesel fuel than previously shown. The classification of unknown hydrocarbons hydrocarbon mixture. Chemical analyses of environmental contamination often rely on chemical speciation

  6. Characterization of zirconia- and niobia-silica mixture coatings produced by ion-beam sputtering

    SciTech Connect (OSTI)

    Melninkaitis, Andrius; Tolenis, Tomas; Mazule, Lina; Mirauskas, Julius; Sirutkaitis, Valdas; Mangote, Benoit; Fu Xinghai; Zerrad, Myriam; Gallais, Laurent; Commandre, Mireille; Kicas, Simonas; Drazdys, Ramutis

    2011-03-20T23:59:59.000Z

    ZrO{sub 2}-SiO{sub 2} and Nb{sub 2}O{sub 5}-SiO{sub 2} mixture coatings as well as those of pure zirconia (ZrO{sub 2}), niobia (Nb{sub 2}O{sub 5}), and silica (SiO{sub 2}) deposited by ion-beam sputtering were investigated. Refractive-index dispersions, bandgaps, and volumetric fractions of materials in mixed coatings were analyzed from spectrophotometric data. Optical scattering, surface roughness, nanostructure, and optical resistance were also studied. Zirconia-silica mixtures experience the transition from crystalline to amorphous phase by increasing the content of SiO{sub 2}. This also results in reduced surface roughness. All niobia and silica coatings and their mixtures were amorphous. The obtained laser-induced damage thresholds in the subpicosecond range also correlates with respect to the silica content in both zirconia- and niobia-silica mixtures.

  7. Structure and dynamics of nonaqueous mixtures of dipolar liquids. I. Infrared and far-infrared spectroscopy

    E-Print Network [OSTI]

    ; accepted 24 May 2000 Mixtures of acetone/methanol, acetonitrile/methanol, and acetone/acetonitrile over are acetone/methanol, acetonitrile/methanol, and acetone/acetonitrile. These three systems allow us to com

  8. Shock structure and temperature overshoot in macroscopic multi-temperature model of mixtures

    SciTech Connect (OSTI)

    Madjarevi?, Damir, E-mail: damirm@uns.ac.rs; Simi?, Srboljub, E-mail: ssimic@uns.ac.rs [Department of Mechanics, Faculty of Technical Sciences, University of Novi Sad, Trg Dositeja Obradovi?a 6, 21000 Novi Sad (Serbia); Ruggeri, Tommaso, E-mail: tommaso.ruggeri@unibo.it [Department of Mathematics and Research Center of Applied Mathematics, University of Bologna, Via Saragozza 8, 40123 Bologna (Italy)

    2014-10-15T23:59:59.000Z

    The paper discusses the shock structure in macroscopic multi-temperature model of gaseous mixtures, recently established within the framework of extended thermodynamics. The study is restricted to weak and moderate shocks in a binary mixture of ideal gases with negligible viscosity and heat conductivity. The model predicts the existence of temperature overshoot of heavier constituent, like more sophisticated approaches, but also puts in evidence its non-monotonic behavior not documented in other studies. This phenomenon is explained as a consequence of weak energy exchange between the constituents, either due to large mass difference, or large rarefaction of the mixture. In the range of small Mach number it is also shown that shock thickness (or equivalently, the inverse of Knudsen number) decreases with the increase of Mach number, as well as when the mixture tends to behave like a single-component gas (small mass difference and/or presence of one constituent in traces)

  9. A visualization study of mixture preparation mechanisms for port fuel injected spark ignition engines

    E-Print Network [OSTI]

    Costanzo, Vincent S. (Vincent Stanley), 1979-

    2004-01-01T23:59:59.000Z

    An experimental study was carried out that examined qualitatively the mixture preparation process in port fuel injected spark ignition engines. The primary variables in this study were intake valve lift, intake valve timing, ...

  10. one was tested, all reaction mixtures were supple-mented with an appropriate amount of ethanol

    E-Print Network [OSTI]

    Moorcroft, Paul R.

    one was tested, all reaction mixtures were supple- mented with an appropriate amount of ethanol (5% v/v), because the menadione was dissolved in ethanol as a stock solution. The reaction was ini

  11. Automatic isochoric apparatus for PVT and phase equilibrium studies of natural gas mixtures 

    E-Print Network [OSTI]

    Zhou, Jingjun

    2009-05-15T23:59:59.000Z

    We have developed a new automatic apparatus for the measurement of the phase equilibrium and pVT properties of natural gas mixtures in our laboratory. Based on the isochoric method, the apparatus can operate at temperature ...

  12. Isochoric measurements of an equimolar mixture of carbon dioxide and ethane

    E-Print Network [OSTI]

    Kidd, Michael William

    1992-01-01T23:59:59.000Z

    obtained from Burnett and pycnometer measurements to provide experimental information about PVT behavior, vapor pressures and the phase boundaries of the mixture. The PVT measurements are used to calculate residual energies and entropies at five... from a Reference State at 250 K and 25 bar. . 139 ix LIST OF FIGURES' Figure page Pressure-Temperature Diagram for a Mixture. Schematic of The Low Pressure Isochoric Apparatus. 13 Low Pressure Isochoric Measurement Cell. 15 Schematic...

  13. The effects of compaction of different golf green soil mixtures on plant growth

    E-Print Network [OSTI]

    Kunze, Raymond John

    1956-01-01T23:59:59.000Z

    growth, removed prior Co compaction treatments, from mixtures of different sand- clay soll-peat rstlosoeoooeoo ~ ~ aeoaoae ~ o oo ~ o ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 7e An average of 2 clipping yields of top growth, removed after Che compaction and during...-clay soil-peat rs'tlos ~ a ~ eaoaoaeooaeeaa ~ o ~ aeea e ~ o ~ eaeoao ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ a ~ aooo 28 9e Differential effects of the different sand-clay soll-peat ratios of 5 particle size mixtures on yields of 2 clip plugs following Che compaction...

  14. Chemical contaminants on DOE lands and selection of contaminant mixtures for subsurface science research

    SciTech Connect (OSTI)

    Riley, R.G.; Zachara, J.M. (Pacific Northwest Lab., Richland, WA (United States))

    1992-04-01T23:59:59.000Z

    This report identifies individual contaminants and contaminant mixtures that have been measured in the ground at 91 waste sites at 18 US Department of Energy (DOE) facilities within the weapons complex. The inventory of chemicals and mixtures was used to identify generic chemical mixtures to be used by DOE's Subsurface Science Program in basic research on the subsurface geochemical and microbiological behavior of mixed contaminants (DOE 1990a and b). The generic mixtures contain specific radionuclides, metals, organic ligands, organic solvents, fuel hydrocarbons, and polychlorinated biphenyls (PCBs) in various binary and ternary combinations. The mixtures are representative of in-ground contaminant associations at DOE facilities that are likely to exhibit complex geochemical behavior as a result of intercontaminant reactions and/or microbiologic activity stimulated by organic substances. Use of the generic mixtures will focus research on important mixed contaminants that are likely to be long-term problems at DOE sites and that will require cleanup or remediation. The report provides information on the frequency of associations among different chemicals and compound classes at DOE waste sites that require remediation.

  15. Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production

    DOE Patents [OSTI]

    Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

    1988-01-01T23:59:59.000Z

    A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

  16. Evaluation of the Nephrotoxicity of Complex Mixtures Containing Organics and Metals: Advantages and Disadvantages of the Use of Real-world Complex Mixtures

    E-Print Network [OSTI]

    Jane Ellen Simmons; Raymond S. H. Yang; Ezra Berman

    As part of a multidisciplinary health effects study, the nephrotoxicity of complex industrial waste mixtures was assessed. Adult, male Fischer 344 rats were gavaged with samples of complex industrial waste and nephrotoxicity evaluated 24 hr later. Of the 10 tested samples, 4 produced increased absolute or relative kidney weight, or both, coupled with a statistically significant alteration in at least one of the measured serum parameters (urea nitrogen (BUN), creatinine (CREAT), and BUN/CREAT ratio). Although the waste samples had been analyzed for a number of organic chemicals and 7 of the 10 samples were analyzed also for 12 elemental metals and metalloids, their nephrotoxicity was not readily predicted from the partial chemical characterization data. Because the chemical form or speciation of the metals was unknown, it was not possible to estimate their contribution to the observed biological response. Various experimental approaches, including use of real-world complex mixtures, chemically defined synthetic mixtures, and simple mixtures, will be necessary to adequately determine the potential human health risk from exposure to complex

  17. The Road to Farming Software is Paved with Good Intentions

    E-Print Network [OSTI]

    Easterbrook, Steve

    , the aggregation software, and GPS service contract (a cost starting at $12,000). Farmers must renew their service contract every five years, to have continued access to the GPS satellites. FarmMap was first released

  18. Department of Energy Paves Way for Additional Clean Energy Projects...

    Office of Environmental Management (EM)

    manufacturing sector, which is part of the Administration's long-term plan to create new green energy jobs. The solicitation will seek applications for projects that manufacture...

  19. NERSC's Science Gateways Pave Way for 'Team Science'

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as fallback supernovae, macronovae, Type Ia supernovae or the orphan afterglows of gamma-ray bursts. In fact, DeepSky was instrumental in the 2011 discovery of the closest...

  20. Tuesday May 22 2007 Company owners pave way to success

    E-Print Network [OSTI]

    Saskatchewan, University of

    companies Global Infobrokers and RSVP Event Design and the college of commerce at the University of Saskatchewan. Monica Kreuger, president of Global Infobrokers Inc. and a sessional entrepreneurship lecturer. Elyse and Halayna Franke won $10,000, invested by Global Infobrokers and RSVP Event Design

  1. DOE Signing Paves the Way for Funding, Construction of Innovative...

    Broader source: Energy.gov (indexed) [DOE]

    that will integrate a suite of technologies to slash emissions while producing both electricity and hydrogen from coal. Emissions from the plant will be reduced almost to zero,...

  2. Paving the path for next-generation nuclear energy | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    heat that could be used for industrial processes such as seawater desalination or plastics production. Today, China has begun construction of a prototype Generation-IV reactor,...

  3. New Technology Paves Way for Highly Sensitive Photodetectors with

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for Renewable Energy:Nanowire Solar541,9337, 2011R -Electrodes

  4. Paving the Way to Nanoelectronics 16 nm and Smaller

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomassPPPO WebsitePalms Village95-1999)Paul J.

  5. Pan African Vision for the Environment (PAVE) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |JilinLuOpenNorthOlympiaAnalysis) JumpPalcan s JV withPalmcoAlto,Pan

  6. Technological Advancements Paving the Way for Geothermal Growth |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreakingMayDepartment ofEnergyTeam CumberlandFebruary 2010RulemakingDepartment of

  7. Bound Neutrons Pave Way to Free Ones | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewindParticleBorn on anJefferson

  8. Bound Neutrons Pave Way to Free Ones | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewindParticleBorn on anJeffersonBound Neutrons

  9. Metal Oxide Semiconductor Nanoparticles Pave the Way for Medical Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighand Retrievals from aRod EggertMercuryAdvanced MaterialsPortal-

  10. HIV immunity study could pave way for vaccine development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm) Harmonic Engine GyroSolé(tm)HDFViewhighlights/HeavyHIV

  11. Construction of an embankment with a fly and bottom ash mixture: field performance study

    SciTech Connect (OSTI)

    Yoon, S.; Balunaini, U.; Yildirim, I.Z.; Prezzi, M.; Siddiki, N.Z. [Louisiana Transportation Research Center, Baton Rouge, LA (United States)

    2009-06-15T23:59:59.000Z

    Fly ash and bottom ash are coal combustion by-products (CCBPs) that are generated in large quantities throughout the world. It is often economical to dispose ash as mixtures rather than separately; that notwithstanding, only a few studies have been performed to investigate the behavior of fly and bottom ash mixtures, particularly those with high contents of fly ash. Also, there is very limited data available in the literature on the field performance of structures constructed using ash mixtures. This paper describes the construction and the instrumentation of a demonstration embankment built with an ash mixture (60:40 by weight of fly ash:bottom ash) on State Road 641, Terre Haute, Ind. Monitoring of the demonstration embankment was conducted for a period of 1 year from the start of construction of the embankment. The settlement of the embankment stabilized approximately 5 months after the end of its construction. According to horizontal inclinometer readings, the differential settlement at the top of the embankment is about 5 mm. Results from field quality control tests performed during construction of the demonstration embankment and monitoring data from vertical and horizontal inclinometers and settlement plates indicate that the ash mixture investigated can be considered an acceptable embankment construction material.

  12. Regulation of dispersion of carbon nanotubes in a mixture of good and bad solvents

    E-Print Network [OSTI]

    O. Deriabina; N. Lebovka; L. Bulavin; A. Goncharuk

    2013-04-21T23:59:59.000Z

    The microstructure and electrical conductivity of suspensions of multi-walled carbon nanotubes (MWCNTs) in binary liquid mixtures water-1-Cyclohexyl-2-pyrrolidone (CHP) were studied in the heating and cooling cycles. The concentration of MWCNTs was varied in the interval between 0-1 wt.% and the content of water in a binary mixture X = [water]/([CHP]+[water]) was varied within 0-1.0. The experimental data have shown that dispersing quality of MWCNTs in a mixture of good (CHP) and bad (water) solvents may be finely regulated by adjustment of composition of the CHP+ water mixtures. The aggregation ability of MWCNTs in dependence on X was discussed. The surface of MWCNT clusters was highly tortuous, its fractal dimension df increased with increase of X, approaching -> 1.9 at X->1. It was concluded that the surface tension is not suitable characteristic for prediction of dispersion ability in the mixture of good and bad solvents. The electrical conductivity data evidenced the presence of a fuzzy-type percolation with multiple thresholds in the systems under investigation. This behavior was explained by formation of different percolation networks in dependence of MWCNT concentration.

  13. Observation of crystallization slowdown in supercooled para-hydrogen and ortho-deuterium quantum liquid mixtures

    E-Print Network [OSTI]

    Matthias Kühnel; José M. Fernández; Filippo Tramonto; Guzmán Tejeda; Elena Moreno; Anton Kalinin; Marco Nava; Davide E. Galli; Salvador Montero; Robert E. Grisenti

    2014-10-10T23:59:59.000Z

    We report a quantitative experimental study of the crystallization kinetics of supercooled quantum liquid mixtures of para-hydrogen (pH$_2$) and ortho-deuterium (oD$_2$) by high spatial resolution Raman spectroscopy of liquid microjets. We show that in a wide range of compositions the crystallization rate of the isotopic mixtures is significantly reduced with respect to that of the pure substances. To clarify this behavior we have performed path-integral simulations of the non-equilibrium pH$_2$-oD$_2$ liquid mixtures, revealing that differences in quantum delocalization between the two isotopic species translate into different effective particle sizes. Our results provide first experimental evidence for crystallization slowdown of quantum origin, offering a benchmark for theoretical studies of quantum behavior in supercooled liquids.

  14. Geotechnical properties of fly and bottom ash mixtures for use in highway embankments

    SciTech Connect (OSTI)

    Kim, B.; Prezzi, M.; Salgado, R. [Korean Institute for Water & Environment, Taejon (Republic of Korea). Dam Safety Research Center

    2005-07-01T23:59:59.000Z

    Class F fly ash and bottom ash are the solid residue byproducts produced by coal-burning electric utilities. They are usually disposed of together as a waste in utility disposal sites with a typical disposal rate of 80% fly ash and 20% bottom ash. Direct use of these materials in construction projects consuming large volumes of materials, such as highway embankment construction, not only provides a promising solution to the disposal problem, but also an economic alternative to the use of traditional materials. Representative samples of class F fly and bottom ash were collected from two utility power plants in Indiana and tested for their mechanical properties (compaction, permeability, strength, stiffness, and compressibility). Three mixtures of fly and bottom ash with different mixture ratios (i.e., 50, 75, and 100% fly ash content by weight) were prepared for testing. Test results indicated that ash mixtures compare favorably with conventional granular materials.

  15. Investigation of the flame speeds of propane/methanol gas mixtures

    SciTech Connect (OSTI)

    Foote, K.L.; Villareal, J.

    1985-05-02T23:59:59.000Z

    A series of tests was conducted in an acoustically tuned flame tube in order to determine the laminar burning velocities in air of various propane/methanol gas mixtures. The experimental method is explained in detail, along with the tabular results. A 90% propane, 10% methanol mixture is shown to have a maximum burning velocity of 40.8 cm/s. A 65% propane, 35% methanol mixture has a maximum velocity of 41.8 cm/s. These maximum flame speeds are shown to be about the same as that of pure propane by the same method. Gulder has found evidence that the presence of methanol in some hydrocarbon fuels may actually inhibit combustion, but we see no apparent modifications in the combustion of propane when mixed with methanol.

  16. Crowding of Polymer Coils and Demixing in Nanoparticle-Polymer Mixtures

    E-Print Network [OSTI]

    Ben Lu; Alan R. Denton

    2011-06-24T23:59:59.000Z

    The Asakura-Oosawa-Vrij (AOV) model of colloid-polymer mixtures idealizes nonadsorbing polymers as effective spheres that are fixed in size and impenetrable to hard particles. Real polymer coils, however, are intrinsically polydisperse in size (radius of gyration) and may be penetrated by smaller particles. Crowding by nanoparticles can affect the size distribution of polymer coils, thereby modifying effective depletion interactions and thermodynamic stability. To analyse the influence of crowding on polymer conformations and demixing phase behaviour, we adapt the AOV model to mixtures of nanoparticles and ideal, penetrable polymer coils that can vary in size. We perform Gibbs ensemble Monte Carlo simulations, including trial nanoparticle-polymer overlaps and variations in radius of gyration. Results are compared with predictions of free-volume theory. Simulation and theory consistently predict that ideal polymers are compressed by nanoparticles and that compressibility and penetrability stabilise nanoparticle-polymer mixtures.

  17. A mixture theory formulation for hydraulic or pneumatic transport of solid particles

    SciTech Connect (OSTI)

    Massoudi, M.

    2010-01-01T23:59:59.000Z

    In this paper, we discuss the importance of constitutive modeling of the stress tensors in certain engineering issues, related to the pressure drop and skin friction, encountered in solids transport. To study this problem, we first give a brief account of the formulation of a two-component mixture based on the theory proposed by Massoudi, Rajagopal and co-workers. The mixture consists of a linearly viscous fluid infused with solid particles. The solids particles are modeled as a granular media and it is assumed that the mixture is dense enough so that we can use the theory of interacting continua. The subsequent boundary value problem, flow between two flat plates, is then solved numerically and results for various dimensionless numbers are presented for velocities and volume fraction profiles. The engineering quantities of interests discussed are related to the pressure drop and skin friction at the walls.

  18. Communication: Unusual structure and transport in ionic liquid-hexane mixtures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liang, Min [Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology; Khatun, Sufia [Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology; Castner, Edward W. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology

    2015-03-28T23:59:59.000Z

    Ionic liquids having a sufficiently amphiphilic cation can dissolve large volume fractions of alkanes, leading to mixtures with intriguing properties on molecular length scales. The trihexyl(tetradecyl)phosphonium cation paired with the bis(trifluoromethylsulfonyl)amide anion provides an ionic liquid that can dissolve large mole fractions of hexane. We present experimental results on mixtures of n-C6D14 with this ionic liquid. High- energy X-ray scattering studies reveal a persistence of the characteristic features of ionic liquid structure even for 80% dilution with n-C6D14. NMR self-diffusion results reveal decidedly non-hydrodynamic behavior where the self-diffusion of the neutral, non-polar n-C6D14 is on average a factor of 21 times faster than for the cation. Exploitation of the unique structural and transport properties of these mixtures may lead to new opportunities for designer solvents for enhanced chemical reactivity and interface science.

  19. Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

    DOE Patents [OSTI]

    Heffel, James W.; Scott, Paul B.

    2003-09-02T23:59:59.000Z

    An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

  20. Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

    DOE Patents [OSTI]

    Heffel, James W. (Lake Matthews, CA); Scott, Paul B. (Northridge, CA); Park, Chan Seung (Yorba Linda, CA)

    2011-11-01T23:59:59.000Z

    An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.