Sample records for asphalt ethane propane

  1. Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia

    E-Print Network [OSTI]

    Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-01-01T23:59:59.000Z

    catalysts: (a) ethane ODH, (b) propane ODH (663 K, 14 kPa CDehydrogenation of Ethane and Propane on Alumina-Supporteddehydrogenation of ethane and propane. UV-visible and Raman

  2. Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane

    E-Print Network [OSTI]

    Gülder, Ömer L.

    Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane the current study and the previous measurements in similar flames with methane, ethane, and propane flames

  3. Selective adsorption of ethylene over ethane and propylene over propane in the metalorganic

    E-Print Network [OSTI]

    Selective adsorption of ethylene over ethane and propylene over propane in the metal in the energy costs associated with the cryogenic separation of ethylene­ethane and propylene­propane mixtures adsorption data for ethylene, ethane, propylene, and propane at 45, 60, and 80 C for the entire series

  4. Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing

    E-Print Network [OSTI]

    Sessions, Alex L.

    Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section incubating sediment with 13 C-labeled methane, ethane, or propane, we5 confirmed the incorporation of 13 C

  5. Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a

    E-Print Network [OSTI]

    Iglesia, Enrique

    Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a , Georges and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane

  6. Molecular Properties of the "Ideal" Inhaled Anesthetic: Studies of Fluorinated Methanes, Ethanes, Propanes,

    E-Print Network [OSTI]

    Hudlicky, Tomas

    , Propanes, and Butanes E. 1Eger, 11, MD*, J. Liu, MD*, D. D. Koblin, PhD, MDt, M. J. Laster, DVM*, S. Taheri unfluorinated, partially fluorinated, and perfluorinated methanes, ethanes, propanes, and butanes to define fluorinated methanes, ethanes, propanes, and butanes, also obtaining limited data on longer- chained alkanes

  7. J. Am. Chem. SOC.1988, 110, 8305-8319 8305 Hydrogenolysis of Ethane, Propane, n-Butane, and Neopentane

    E-Print Network [OSTI]

    Goodman, Wayne

    J. Am. Chem. SOC.1988, 110, 8305-8319 8305 Hydrogenolysis of Ethane, Propane, n, Pasadena, California 91125. Received February I, 1988 Abstract: The hydrogenolysisof ethane, propane, n for ethane, propane, and neopentane involvesthe cleavage of a single carbon-carbon bond, resulting

  8. Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation

    SciTech Connect (OSTI)

    Sun, Pingping; Siddiqi, Georges; Vining, William C.; Chi, Miaofang; Bell, Alexis T. (UCB); (ORNL)

    2011-10-28T23:59:59.000Z

    Catalysts for the dehydrogenation of light alkanes were prepared by dispersing Pt on the surface of a calcined hydrotalcite-like support containing indium, Mg(In)(Al)O. Upon reduction in H{sub 2} at temperatures above 673 K, bimetallic particles of PtIn are observed by TEM, which have an average diameter of 1 nm. Analysis of Pt LIII-edge extended X-ray absorption fine structure (EXAFS) data shows that the In content of the bimetallic particles increases with increasing bulk In/Pt ratio and reduction temperature. Pt LIII-edge X-ray absorption near edge structure (XANES) indicates that an increasing donation of electronic charge from In to Pt occurs with increasing In content in the PtIn particles. The activity and selectivity of the Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants, maximum activity was achieved for a bulk In/Pt ratio of 0.48, and at this In/Pt ratio, the selectivity to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane dehydrogenation, and it was observed that the alloying of Pt with In greatly reduced the amount of coke deposited. Characterization of the deposit by Raman spectroscopy indicates that the coke is present as highly disordered graphite particles <30 nm in diameter. While the amount of coke deposited during ethane and propane dehydrogenation are comparable, the effects on activity are dependent on reactant composition. Coke deposition had no effect on ethane dehydrogenation activity, but caused a loss in propane dehydrogenation activity. This difference is attributed to the greater ease with which coke produced on the surface of PtIn nanoparticles migrates to the support during ethane dehydrogenation versus propane dehydrogenation.

  9. Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia

    SciTech Connect (OSTI)

    Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-09-11T23:59:59.000Z

    The catalytic properties of Al2O3-supported vanadia with a wide range of VOx surface density (1.4-34.2 V/nm2) and structure were examined for the oxidative dehydrogenation of ethane and propane. UV-visible and Raman spectra showed that vanadia is dispersed predominantly as isolated monovanadate species below {approx}2.3 V/nm2. As surface densities increase, two-dimensional polyvanadates appear (2.3-7.0 V/nm2) along with increasing amounts of V2O5 crystallites at surface densities above 7.0 V/nm2. The rate constant for oxidative dehydrogenation (k1) and its ratio with alkane and alkene combustion (k2/k1 and k3/k1, respectively) were compared for both alkane reactants as a function of vanadia surface density. Propene formation rates (per V-atom) are {approx}8 times higher than ethene formation rates at a given reaction temperature, but the apparent ODH activation energies (E1) are similar for the two reactants and relatively insensitive to vanadia surface density. Ethene and propene formation rates (per V-atom) are strongly influenced by vanadia surface density and reach a maximum value at intermediate surface densities ({approx}8 V/nm2). The ratio of k2/k1 depends weakly on reaction temperature, indicating that activation energies for alkane combustion and ODH reactions are similar. The ratio of k2/k1 is independent of surface density for ethane, but increase slightly with vanadia surface density for propane, suggesting that isolated structures prevalent at low surface densities are slightly more selective for alkane dehydrogenation reactions. The ratio of k3/k1 decreases markedly with increasing reaction temperature for both ethane and propane ODH. Thus, the apparent activation energy for alkene combustion (E3) is much lower than that for alkane dehydrogenation (E1) and the difference between these two activation energies decreases with increasing surface density. The lower alkene selectivities observed at high vanadia surface densities are attributed to an increase in alkene adsorption enthalpies with increasing vanadia surface density. The highest yield of alkene is obtained for catalysts containing predominantly isolated monovanadate species and operated at high temperatures that avoid homogeneous reactions (< {approx} 800 K).

  10. Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation

    SciTech Connect (OSTI)

    Yoon, S.S. [Corporate Research and Development Division, Hyundai-Kia Motors, Gyeonggi-do 445-706 (Korea); Anh, D.H. [Korea Electric Power Research Institute, Daejeon 305-380 (Korea); Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea)

    2008-08-15T23:59:59.000Z

    Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

  11. Experimental and kinetic study of autoignition in methane/ethane/air and methane/propane/air mixtures under engine-relevant conditions

    SciTech Connect (OSTI)

    Huang, J.; Bushe, W.K. [Department of Mechanical Engineering, University of British Columbia, 6950 Applied Science Lane, Vancouver, British Columbia (Canada V6T 1Z4)

    2006-01-01T23:59:59.000Z

    The ignition delay of homogeneous methane/air mixtures enriched with small fractions of ethane/propane was measured using the reflected-shock technique at temperatures from 900 to 1400 K and pressures from 16 to 40 bar. The results show complex effects of ethane/propane on the ignition of methane, but a common trend observed with both hydrocarbons is an increased promotion effect for temperatures below 1100 K. A detailed kinetic mechanism was used to investigate the interaction between ethane/propane and the ignition chemistry of methane under the above conditions. It was found that at relatively low temperatures, the reactions between ethane/propane and methylperoxy (CH{sub 3}O{sub 2}) lead to an enhanced rate of formation of OH radicals in the initiation phase of the ignition. By systematically applying the quasi-steady-state assumptions to the intermediate species involved in the main reaction path identified, we have achieved an analytical description of the ignition process in the transitional temperature regime. The analytical solutions agree reasonably well with the detailed kinetic model and the experimental results for both ignition delay and concentrations of major intermediate species.

  12. SOLAR HEATING OF TANK BOTTOMS Application of Solar Heating to Asphaltic and Parrafinic Oils Reducing Fuel Costs and Greenhouse Gases Due to Use of Natural Gas and Propane

    SciTech Connect (OSTI)

    Eugene A. Fritzler

    2005-09-01T23:59:59.000Z

    The sale of crude oil requires that the crude meet product specifications for BS&W, temperature, pour point and API gravity. The physical characteristics of the crude such as pour point and viscosity effect the efficient loading, transport, and unloading of the crude oil. In many cases, the crude oil has either a very high paraffin content or asphalt content which will require either hot oiling or the addition of diluents to the crude oil to reduce the viscosity and the pour point of the oil allowing the crude oil to be readily loaded on to the transport. Marginal wells are significantly impacted by the cost of preheating the oil to an appropriate temperature to allow for ease of transport. Highly paraffinic and asphaltic oils exist throughout the D-J basin and generally require pretreatment during cold months prior to sales. The current study addresses the use of solar energy to heat tank bottoms and improves the overall efficiency and operational reliability of stripper wells.

  13. Aged asphalt

    E-Print Network [OSTI]

    Martin, Kenneth Lloyd

    1988-01-01T23:59:59.000Z

    Dorchester Asphalts Exxon Asphalts CONCLUSIONS RECOMMENDATIONS LITERATURE CITED APPENDIX 41 42 48 59 70 84 90 93 96 99 103 105 106 A. GEL PERMEATION CHROMATOGRAMS OF TEST ASPHALTS 108 B. FOURIER-TRANSFORM INFRARED SPECTRUMS OF TEST... Apparatus 5. Abson Method Apparatus 6. ASTM D 2171 Apparatus 7. Sample Pellet Die 8. Sample Pellet Holder 21 23 27 29 38 40 9. GPC of Lufkin Exxon AC-20 Extracted by Two Methods . . . . . . . . . . . . . . . . 46 10. GPC of Dickens Exxon AC-20 51...

  14. 9118 J. Am. Chem. SOC.1992, 114, 9118-9122 Propane Buwe

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    9118 J. Am. Chem. SOC.1992, 114, 9118-9122 Scheme 111 Propane Buwe X =CHI and Y = H lossofH2 Z = H-82-8; ethane, 74- 84-0; propane, 74-98-6;butane, 106-97-8. (28) The heats of formation for C3H2are the scaled

  15. Selective dehydrogenation of propane over novel catalytic materials

    SciTech Connect (OSTI)

    Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

    1998-02-01T23:59:59.000Z

    The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

  16. Propane on Titan

    E-Print Network [OSTI]

    H. G. Roe; T. K. Greathouse; M. J. Richter; J. H. Lacy

    2003-09-23T23:59:59.000Z

    We present the first observations of propane (C$_3$H$_8$) on Titan that unambiguously resolve propane features from other numerous stratospheric emissions. This is accomplished using a $R=\\lambda/\\delta\\lambda\\approx10^5$ spectrometer (TEXES) to observe propane's $\

  17. Nationwide: Southeast Propane Autogas Development Program Brings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Southeast Propane Autogas Development Program Brings 1200 Propane Vehicles to the Road Nationwide: Southeast Propane Autogas Development Program Brings 1200 Propane Vehicles to the...

  18. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    propene, acetone, benzene, propane and ?-pinene (Table 1).cyanide Acetonitrile Ethane Propane i-Butane n-Butane i-= Ethane Ethane Ethane Ethane Propane Propane Propane ARCTAS

  19. Propane Vehicle Demonstration Grant Program

    SciTech Connect (OSTI)

    Jack Mallinger

    2004-08-27T23:59:59.000Z

    Project Description: Propane Vehicle Demonstration Grants The Propane Vehicle Demonstration Grants was established to demonstrate the benefits of new propane equipment. The US Department of Energy, the Propane Education & Research Council (PERC) and the Propane Vehicle Council (PVC) partnered in this program. The project impacted ten different states, 179 vehicles, and 15 new propane fueling facilities. Based on estimates provided, this project generated a minimum of 1,441,000 new gallons of propane sold for the vehicle market annually. Additionally, two new off-road engines were brought to the market. Projects originally funded under this project were the City of Portland, Colorado, Kansas City, Impco Technologies, Jasper Engines, Maricopa County, New Jersey State, Port of Houston, Salt Lake City Newspaper, Suburban Propane, Mutual Liquid Propane and Ted Johnson.

  20. Asphalt Oxidation Kinetics and Pavement Oxidation Modeling

    E-Print Network [OSTI]

    Jin, Xin

    2012-07-16T23:59:59.000Z

    Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

  1. The catalytic oxidation of propane 

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  2. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  3. Residential propane price increases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane

  4. Residential propane prices available

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices

  5. Residential propane prices decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices5, 2014

  6. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices5,

  7. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane

  8. 2013 Propane Market Outlook

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruary 2004AugustApril 20133 Audit2013 NUFOPlasma Propane

  9. asphalt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt pavements containing asphalt binder and aggregates. The use of RAP can reduce the cost of construction materials, reduce the amount of waste... Thakur, Jitendra Kumar...

  10. asphalts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt pavements containing asphalt binder and aggregates. The use of RAP can reduce the cost of construction materials, reduce the amount of waste... Thakur, Jitendra Kumar...

  11. BBR Asphalt mixture creep test BBR Asphalt mixture creep size effect

    E-Print Network [OSTI]

    Minnesota, University of

    #12;Outline ØBBR Asphalt mixture creep test ØBBR Asphalt mixture creep size effect ØBBR Asphalt Point Bending Test Low temperature 3-point bending creep tests on specimens with three different sizes mixture strength test ØBBR Asphalt binder strength test #12;Asphalt Pavements ØRecent efforts under NCHRP

  12. NREL: Energy Analysis - Ethan Warner

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Saleshttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gifNRELPower SystemsDebbie Brodt-Giles PhotoEllaEricEthan

  13. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded ­ II ­ Asphalt Pavements ­ Effect of Aging ­ Simulations ­ Concluding Remarks #12;3 Objectives Develop) Correspondence Principle based formulation Application: Asphalt concrete pavements (Part II) #12;4 Asphalt

  14. Liquid Propane Injection Technology Conductive to Today's North...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection...

  15. Propane - A Mid-Heating Season Assessment

    Reports and Publications (EIA)

    2001-01-01T23:59:59.000Z

    This report will analyze some of the factors leading up to the rapid increase in propane demand and subsequent deterioration in supply that propelled propane prices to record high levels during December and early January.

  16. Costs Associated With Propane Vehicle Fueling Infrastructure

    SciTech Connect (OSTI)

    Smith, M.; Gonzales, J.

    2014-08-01T23:59:59.000Z

    This document is designed to help fleets understand the cost factors associated with propane vehicle fueling infrastructure. It provides an overview of the equipment and processes necessary to develop a propane fueling station and offers estimated cost ranges.

  17. 1, 2341, 2001 OH + propane and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 1, 23­41, 2001 OH + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract Introduction Conclusions #12;ACPD 1, 23­41, 2001 OH + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract

  18. Fuels outlook for oil/propane

    SciTech Connect (OSTI)

    Weigand, P.

    1995-09-01T23:59:59.000Z

    The outlook for using oil and propane as fuels is outlined. The following topics are discussed: factors affecting price of the burner tip, supply and demand forecast, distribution costs and availability, alternate fuels economics, propane prices, No. 2 oil prices, natural gas vs. 1% residual HP prices, and future for industrial oil and propane consumers.

  19. Life Cycle Assessment of Reclaimed Asphalt Pavement

    E-Print Network [OSTI]

    Minnesota, University of

    Life Cycle Assessment of Reclaimed Asphalt Pavement to Improve Asphalt Pavement Sustainability By Pavement (RAP) Courtesy of http://myconstructionphotos.smugmug.com/ RAP #12;Transport Back to the Plant-melt old binder on the RAP #12;Life Cycle Assessment (LCA) · #12;Asphalt Pavement Life Cycle Road

  20. Selective adsorption of ethylene over ethane and propylene over propane in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > TheNuclearHomeland ScienceInnovationScienceMaterials Centerthe

  1. Propane Market Model documentation report

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    The purpose of this report is to define the objectives of the Propane Market Model (PMM), describe its basic approach, and to provide details on model functions. This report is intended as a reference document for model analysts, users, and the general public. Documentation of the model is in accordance with EIA`s legal obligation to provide adequate documentation in support of its models. The PMM performs a short-term (6- to 9-months) forecast of demand and price for consumer-grad propane in the national US market; it also calculates the end-of-month stock level during the term of the forecast. Another part of the model allows for short-term demand forecasts for certain individual Petroleum Administration for Defense (PAD) districts. The model is used to analyze market behavior assumptions or shocks and to determine the effect on market price, demand, and stock level.

  2. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, Richard W. (Livermore, CA); Skinner, Dewey F. (Livermore, CA); Thorsness, Charles B. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  3. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, R.W.; Skinner, D.F. Jr.; Thorsness, C.B.

    1983-05-26T23:59:59.000Z

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  4. Comparison of Hydrogen and Propane Fuels (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01T23:59:59.000Z

    Factsheet comparing the chemical, physical, and thermal properties of hydrogen and propane, designed to facilitate an understanding of the differences and similarites of the two fuels

  5. Comparison of Hydrogen and Propane Fuels (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2009-04-01T23:59:59.000Z

    Factsheet comparing the chemical, physical, and thermal properties of hydrogen and propane, designed to facilitate an understanding of the differences and similarites of the two fuels.

  6. Residential propane price decreases slightly

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane price

  7. Heating Oil and Propane Update - Energy Information Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Petroleum Reports Heating Oil and Propane Update Weekly heating oil and propane prices are only collected during the heating season, which extends from October through March....

  8. 29Counting Atoms in a Molecule The complex molecule Propanal

    E-Print Network [OSTI]

    29Counting Atoms in a Molecule The complex molecule Propanal was discovered in a dense interstellar is the ratio of carbon atoms to hydrogen atoms in propanal? Problem 4 - If the mass of a hydrogen atom of a propanal molecule in AMUs? Problem 5 - What is the complete chemical formula for propanal? C3 H __ O

  9. Alternative Fuel Tool Kit How to Implement: Propane

    E-Print Network [OSTI]

    1 08/2014 Alternative Fuel Tool Kit How to Implement: Propane Contents Introduction to Propane (LPG...........................................................................................................2 Benefits of Using Propane (LPG) for Transportation of Energy under Award Number DE-EE0006083. #12;2 08/2014 Introduction to Propane (LPG) for Transportation

  10. Evolutionary History of a Specialized P450 Propane Monooxygenase

    E-Print Network [OSTI]

    Arnold, Frances H.

    Evolutionary History of a Specialized P450 Propane Monooxygenase Rudi Fasan1 , Yergalem T-evolved P450 propane mono- oxygenase (P450PMO) having 20 heme domain substitutions compared to P450BM3 of propane activity. In contrast, refinement of the enzyme catalytic efficiency for propane oxidation (9000

  11. Propane vehicles : status, challenges, and opportunities.

    SciTech Connect (OSTI)

    Rood Werpy, M.; Burnham, A.; Bertram, K.; Energy Systems

    2010-06-17T23:59:59.000Z

    Propane as an auto fuel has a high octane value and has key properties required for spark-ignited internal combustion engines. To operate a vehicle on propane as either a dedicated fuel or bi-fuel (i.e., switching between gasoline and propane) vehicle, only a few modifications must be made to the engine. Until recently propane vehicles have commonly used a vapor pressure system that was somewhat similar to a carburetion system, wherein the propane would be vaporized and mixed with combustion air in the intake plenum of the engine. This leads to lower efficiency as more air, rather than fuel, is inducted into the cylinder for combustion (Myers 2009). A newer liquid injection system has become available that injects propane directly into the cylinder, resulting in no mixing penalty because air is not diluted with the gaseous fuel in the intake manifold. Use of a direct propane injection system will improve engine efficiency (Gupta 2009). Other systems include the sequential multi-port fuel injection system and a bi-fuel 'hybrid' sequential propane injection system. Carbureted systems remain in use but mostly for non-road applications. In the United States a closed-loop system is used in after-market conversions. This system incorporates an electronic sensor that provides constant feedback to the fuel controller to allow it to measure precisely the proper air/fuel ratio. A complete conversion system includes a fuel controller, pressure regulator valves, fuel injectors, electronics, fuel tank, and software. A slight power loss is expected in conversion to a vapor pressure system, but power can still be optimized with vehicle modifications of such items as the air/fuel mixture and compression ratios. Cold start issues are eliminated for vapor pressure systems since the air/fuel mixture is gaseous. In light-duty propane vehicles, the fuel tank is typically mounted in the trunk; for medium- and heavy-duty vans and trucks, the tank is located under the body of the vehicle. Propane tanks add weight to a vehicle and can slightly increase the consumption of fuel. On a gallon-to-gallon basis, the energy content of propane is 73% that of gasoline, thus requiring more propane fuel to travel an equivalent distance, even in an optimized engine (EERE 2009b).

  12. Asphalt deposition in miscible floods

    E-Print Network [OSTI]

    Hasan, Syed Mir Ahmed

    1964-01-01T23:59:59.000Z

    : Petroleum Engineering ASPHALT DEPOSITION IN MISCIBLE FLOODS A Thesis By SYED MIR AHMED HASAN Approved as to style and content by: (Chairman of Committee) ommittee Member) Committee Member) Head of Department), (Co 'ttee Member) January, f964... Subject: Petroleum Engineering TABLE OF CONTENTS ABS TRAC T. Page 2. INTRODUCTION. 3 DESCRIPTION OF EQUIPMENT AND MATERIALS. . . . . , . 6 4. EXPERIMENTAL PROCEDURE 5. INTERPRETATION AND DISCUSSION OF RESULTS. . . . . . 13 6. CONCLUSIONS. 7...

  13. Winter Performance and Maintenance of Porous Asphalt Pavements

    E-Print Network [OSTI]

    Concrete (HSG-B)Porous Asphalt (HSG-C) #12;Cold Climate Performance Results #12;12 Porous Asphalt SurfaceWinter Performance and Maintenance of Porous Asphalt Pavements Robert M. Roseen, Ph.D., P.E., D impacts for new development and reverse impacts in areas with redevelopment. #12;Porous Asphalt Design

  14. QER- Comment of National Propane Gas Association

    Broader source: Energy.gov [DOE]

    Ladies and Gentlemen: Please find attached the QER comments of the National Propane Gas Association. Please feel to contact us if we can provide further information. Thank you for your attention to our submission.

  15. Knoxville Area Transit: Propane Hybrid Electric Trolleys

    SciTech Connect (OSTI)

    Not Available

    2005-04-01T23:59:59.000Z

    A 2-page fact sheet summarizing the evaluation done by the U.S. Department of Energy's Advanced Vehicle Testing Activity on the Knoxville Area Transit's use of propane hybrid electric trolleys.

  16. QER- Comment of Propane Education & Research Council

    Broader source: Energy.gov [DOE]

    I plan to attend and ask a question of the Secretary regarding propane supply for the upcoming winter. Please do not hesitate to call or email if you have questions. Tucker Perkins

  17. Compatibilizer for crumb rubber modified asphalt

    SciTech Connect (OSTI)

    Labib, M.E. [New Jersey Institute of Technology, Newark, NJ (United States); Memon, G.M.; Chollar, B.H. [Federal Highway Administration, McLean, VA (United States)

    1996-12-31T23:59:59.000Z

    The United States of America discards more than 300 million tires each year, and out of that a large fraction of the tires is dumped into stock piles. This large quantity of tires creates an environmental problem. The use of scrap tires is limited. There is a usage potential in such fields as fuel for combustion and Crumb Rubber-Modified Asphalt binder (CRMA). The use of crumb rubber in modifying asphalt is not a new technique; it is been used since early 1960 by pavement engineers. Crumb rubber is a composite of different blends of natural and synthetic rubber (natural rubber, processing oils, polybutadiene, polystyrene butadiene, and filler). Prior research had concluded that the performance of crumb rubber modified asphalt is asphalt dependent. In some cases it improves the Theological properties and in some cases it degrades the properties of modified asphalt.

  18. Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane

    E-Print Network [OSTI]

    Green, Michael A.

    2005-01-01T23:59:59.000Z

    Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

  19. Materials characterization of asphalt and polymer modified asphalt 

    E-Print Network [OSTI]

    Paramasivam, Mohan

    1992-01-01T23:59:59.000Z

    specimen mold made of aluminum ? ? ? ? ? ? ? ? ? ? - 28 5. Strain sweep of Santa Maria AC10/AR4000 at 100 rad/sec --- 33 6. Strain sweep of Conoco AC10 at 10 rad/sec ------------- 34 7. Stress relaxation modulus of AAM grade asphalt at 25'C --- 37 8.... The verification of Cox-Merz rule for Santa Maria AC6/AR2000 at 40'C- 9. The master curve of Santa Maria AC6/Muehlstein LDPE shifted to 25'C showing the errors 10. Master curve (G') of Santa Maria AC6 shifted to 25'C ? ? ? ? ? 43 11. Master curve of Santa...

  20. Materials characterization of asphalt and polymer modified asphalt

    E-Print Network [OSTI]

    Paramasivam, Mohan

    1992-01-01T23:59:59.000Z

    specimen mold made of aluminum ? ? ? ? ? ? ? ? ? ? - 28 5. Strain sweep of Santa Maria AC10/AR4000 at 100 rad/sec --- 33 6. Strain sweep of Conoco AC10 at 10 rad/sec ------------- 34 7. Stress relaxation modulus of AAM grade asphalt at 25'C --- 37 8.... The verification of Cox-Merz rule for Santa Maria AC6/AR2000 at 40'C- 9. The master curve of Santa Maria AC6/Muehlstein LDPE shifted to 25'C showing the errors 10. Master curve (G') of Santa Maria AC6 shifted to 25'C ? ? ? ? ? 43 11. Master curve of Santa...

  1. Propane Vehicle and Infrastructure Codes and Standards Citations (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-07-01T23:59:59.000Z

    This document lists codes and standards typically used for U.S. propane vehicle and infrastructure projects.

  2. Correlation between homogeneous propane pyrolysis and pyrocarbon deposition

    E-Print Network [OSTI]

    Boyer, Edmond

    Correlation between homogeneous propane pyrolysis and pyrocarbon deposition C´edric Descamps, G propane pyrolysis is studied in a 1-D hot-wall CVD furnace. The gas-phase pyrolysis is modelled in previous reports [6]: total pressure equal to 2 kPa, temperature between 900 K and 1400 K, and pure propane

  3. Study of the Low Temperature Oxidation of Propane Maximilien Cord

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Study of the Low Temperature Oxidation of Propane Maximilien Cord , Benoit Husson , Juan of China, Hefei, Anhui 230029, P. R. China Abstract The lowtemperature oxidation of propane oxidation of propane in the gas phase has been the subject of very few experimental studies, mainly

  4. Evolutionary History of a Specialized P450 Propane Monooxygenase

    E-Print Network [OSTI]

    Arnold, Frances H.

    Evolutionary History of a Specialized P450 Propane Monooxygenase Rudi Fasan1 , Yergalem T hydroxylase (P450BM3) to a laboratory-evolved P450 propane mono- oxygenase (P450PMO) having 20 heme domain substrate range and the emergence of propane activity. In contrast, refinement of the enzyme catalytic

  5. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12T23:59:59.000Z

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organicsmore »present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.« less

  6. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12T23:59:59.000Z

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organics present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.

  7. Portland Public School Children Move with Propane

    SciTech Connect (OSTI)

    Not Available

    2004-04-01T23:59:59.000Z

    This 2-page Clean Cities fact sheet describes the use of propane as a fuel source for Portland Public Schools' fleet of buses. It includes information on the history of the program, along with contact information for the local Clean Cities Coordinator and Portland Public Schools.

  8. TECHNICAL POLLUTION PREVENTION GUIDE FOR ASPHALT PREPARATION OPERATIONS

    E-Print Network [OSTI]

    Delivery, Storage and Cold Feed . . . . . . . . . . . . . 12 2.3.2 Liquid Asphalt Delivery, Storage . . . . . . . . . . . . . . . . . . . . . . 4 2 INDUSTRY PROFILE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2.1 ASPHALT and Heating . . . . . . . . . . . . 12 2.3.3 Cold Feed Drying and Heating

  9. An investigation of the use of tire rubber in asphalt

    E-Print Network [OSTI]

    Koo, Heamo Lee

    1996-01-01T23:59:59.000Z

    -rubber binder. The selected variables chosen are curing time, curing temperature, rubber content (weight percent), rubber particle size, base asphalt type, and carbonyl area. Results confirmed that the addition of rubber increased the viscosity of the asphalt...

  10. asphalt composition aplicacao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Warm mix asphalt (WMA) is not a hot mix asphalt (HMA), it's just warm mix The WMA production temperature typically ranges from 100 to 140o C, whereas for HMA it ranges Das,...

  11. Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures

    E-Print Network [OSTI]

    Vasconcelos, Kamilla L.

    2011-08-08T23:59:59.000Z

    cost in highway maintenance and vehicle operations. One key mechanism of how moisture reaches the asphalt-aggregate interface is by its permeation or diffusion through the asphalt binder or mastic. Different techniques are available for diffusion...

  12. Controlling Thermal Properties of Asphalt Concrete and its Multifunctional Applications 

    E-Print Network [OSTI]

    Shi, Xijun

    2014-08-10T23:59:59.000Z

    ) by controlling thermal properties of the construction materials. To change thermal properties of asphalt concrete, expanded polypropylene (EPP) pellet and graphite were selected as the additives and mixed into asphalt concrete. Experimental tests are classified...

  13. Damage analysis in asphalt concrete mixtures based on parameter relationships 

    E-Print Network [OSTI]

    Song, Injun

    2004-11-15T23:59:59.000Z

    Asphalt pavements experience damage due to traffic loading under various environmental conditions. Damage can be caused by viscopl microcracks, fracture due to fatigue cracking, or fracture due to thermal cracking. Asphalt ...

  14. Evaluation of Rexene polymers in hot mixed asphalt concrete 

    E-Print Network [OSTI]

    Rodriguez, Mary Anne Reese

    1991-01-01T23:59:59.000Z

    Committee: Dr. Dallas N. Little The objective of this research was to provide a comprehensive characterization of asphalt binders and paving mixtures modified with four polymers produced by the Rexene Products Company (Odessa, Texas). The four polymers... LITERATURE REVIEW AND INTERPRETATION General Available Asphalt Additives Practical Application of Asphalt Additives Benefit-Costs for Additives Future Outlook for Additives MATERIALS AND TEST METHODS Polymers Asphalt Cements Aggregate Procedure...

  15. Disk-shaped Compact Tension Test for Asphalt Concrete Fracture

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Disk-shaped Compact Tension Test for Asphalt Concrete Fracture by M.P.Wagoner, W.G. Buttlar and G geometry is the ability to test cylindrical cores obtained from in-place asphalt concrete pavements finalizing the specimen geometry, a typical asphalt concrete surface mixture was tested at various

  16. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded ­ Verification ­ Concluding Remarks Part ­ II (Companion presentation) ­ Asphalt Pavements ­ Effect of Aging: Asphalt concrete pavements (Part II) E1 E2 E3 Eh 1 2 3 h #12;Graded Finite Elements Graded Elements

  17. What's the future for rubberized asphalt

    SciTech Connect (OSTI)

    Not Available

    1991-04-01T23:59:59.000Z

    This article describes the debate over the use of rubberized asphalt for highway surfacing. The Department of Transportation claims that the process is too costly; that it presents potential air pollution, safety and health problems. They also claim that there is a lack of understanding between rubber and asphalt cement and of the recyclability of the product. The Legislative Commission on Solid Waste Management claims that the mixture performs as well or better than conventional asphalt at reduced thicknesses. In addition, there could be savings of local funds currently expended for regulation of tire dumps, fire-fighting and clean-up, vector control and scrap tire disposal costs ranging from $.50 to $2.00 per tire.

  18. The potential use of tar sand bitumen as paving asphalt

    SciTech Connect (OSTI)

    Petersen, J.C.

    1988-01-01T23:59:59.000Z

    In this paper several research reports describing the preparation of potential paving asphalts from tar sand bitumen are reviewed and the results of the studies compared. The tar sand asphalts described in the studies were prepared from 1) hot water-recovered bitumen from deposits near San Luis Obispo, California (Edna deposits), and deposits near Vernal and Sunnyside, Utah; and 2) bitumen recovered from the Northwest Asphalt Ridge deposits near Vernal, Utah, by both in situ steamflood and in situ combustion recovery processes. Important properties of the tar sand asphalts compare favorably with those of specification petroleum asphalts. Laboratory data suggest that some tar sand asphalts may have superior aging characteristics and produce more water-resistant paving mixtures than typical petroleum asphalts.

  19. The potential use of tar sand bitumen as paving asphalt

    SciTech Connect (OSTI)

    Petersen, J.C.

    1987-01-01T23:59:59.000Z

    The properties of several tar sand asphalts prepared in past studies by several different investigators were compared with each other and with the properties of petroleum asphalts. These results were reviewed and discussed with regard to the potential use of tar sand bitumen in pavement applications. The data show that tar sand bitumen has good potential for use in highway pavements that meet today's performance specifications. No deficiencies in the tar sand asphalts were found that would be expected to seriously affect performance. On the other hand, the data indicate that some tar sand asphalts may have superior aging characteristics, being relatively resistant to oxidative age hardening compared with typical petroleum asphalts. Asphalt-aggregate mixtures prepared using two tar sand asphalts also showed acceptable strength properties and excellent resistance to moisture-induced damage.

  20. Titan's Prolific Propane: The Cassini CIRS Perspective

    E-Print Network [OSTI]

    Nixon, C A; Flaud, J -M; Bezard, B; Teanby, N A; Irwin, P G J; Ansty, T M; Coustenis, A; Vinatier, S; Flasar, F M; 10.1016/j.pss.2009.06.021

    2009-01-01T23:59:59.000Z

    In this paper we select large spectral averages of data from the Cassini Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low latitudes (30S--30N), greatly increasing the path length and hence signal-to-noise ratio for optically thin trace species such as propane. By modeling and subtracting the emissions of other gas species, we demonstrate that at least six infrared bands of propane are detected by CIRS, including two not previously identified in Titan spectra. Using a new line list for the range 1300-1400cm -1, along with an existing GEISA list, we retrieve propane abundances from two bands at 748 and 1376 cm-1. At 748 cm-1 we retrieve 4.2 +/- 0.5 x 10(-7) (1-sigma error) at 2 mbar, in good agreement with previous studies, although lack of hotbands in the present spectral atlas remains a problem. We also determine 5.7 +/- 0.8 x 10(-7) at 2 mbar from the 1376 cm-1 band - a value that is probably affected by systematic errors including continuum gradients due to haze and also an imperf...

  1. Electron attenuation in free, neutral ethane clusters

    SciTech Connect (OSTI)

    Winkler, M.; Harnes, J.; Børve, K. J., E-mail: Knut.Borve@kj.uib.no [Department of Chemistry, University of Bergen, NO-5007 Bergen (Norway); Myrseth, V. [Department of Physics and Technology, University of Bergen, NO-5007 Bergen (Norway)

    2014-10-28T23:59:59.000Z

    The electron effective attenuation length (EAL) in free, neutral ethane clusters has been determined at 40 eV kinetic energy by combining carbon 1s x-ray photoelectron spectroscopy and theoretical lineshape modeling. More specifically, theory is employed to form model spectra on a grid in cluster size (N) and EAL (?), allowing N and ? to be determined by optimizing the goodness-of-fit ?{sup 2}(N, ?) between model and observed spectra. Experimentally, the clusters were produced in an adiabatic-expansion setup using helium as the driving gas, spanning a range of 100–600 molecules in mean cluster size. The effective attenuation length was determined to be 8.4?±?1.9 Å, in good agreement with an independent estimate of 10 Å formed on the basis of molecular electron-scattering data and Monte Carlo simulations. The aggregation state of the clusters as well as the cluster temperature and its importance to the derived EAL value are discussed in some depth.

  2. Evaluation of polyethylene-modified asphalt blends

    E-Print Network [OSTI]

    Consuegra Granger, Fernando

    1990-01-01T23:59:59.000Z

    aggregate and asphalt modified with LDPE (binder contents of 4. 8%%u and 5. 87'). 42 Table 9. Summary of statistical parameters derived from IDT testing on crushed granite mixtures bound with AC-20 + LDPE (4. 8%, and 5. 8/ binder). 46 Table 10. Summary... of creep to rupture data for crushed granite mixtures. 71 Table 11. Summary of the results of IDT repeated load fatigue testing of river gravel mixtures bound with Texaco asphalt: AC- 10, AC-10 + LDPE and AC-20. Table 12. K, ' and n, values of river...

  3. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  4. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    See footnotes at end of table. 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State 386 Energy Information...

  5. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  6. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  7. Microsoft Word - Joe Rose - Providence remarks.propane.JUR -...

    Broader source: Energy.gov (indexed) [DOE]

    for propane consumers in acquiring adequate supply at affordable prices. Crop drying demand of 500% of last year's demand combined with heating demand of 20% above the...

  8. New insights into microbial responses to oil spills from the Deepwater Horizon incident

    E-Print Network [OSTI]

    Mason, O.U.

    2012-01-01T23:59:59.000Z

    C. J. Villanueva (2010). "Propane respiration jump-startsin samples that exhibited propane and ethane anomalies (loss of both ethane and propane relative to methane

  9. Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

  10. CONTRIBUTION A L'TUDE DES FLAMMES D'HYDROCARBURES. PROPANE ET ACTYLNE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CONTRIBUTION A L'ÉTUDE DES FLAMMES D'HYDROCARBURES. PROPANE ET ACÉTYLÈNE Par MM. JEAN VAN DER POLL du propane et de l'acétylène qui ont montré que, dans certains cas, les flammes oxy-propane et oxy

  11. The effect of asphalt deposition on recovery of oil by a pentane slug

    E-Print Network [OSTI]

    Bhagia, Nanik S

    1965-01-01T23:59:59.000Z

    ":ty reduction increases, in general, with the increase in amount of, asphalt contained ir the oil. The increases in recovery at breakthrough due to asphalt deposition were noted for four asphaltic crude oils and were compared to those of asphalt-free refined... substantial range, the gain in recovery at breakthrough of asphaltic oils over refined oils of the same viscosity increases with increase in size of slug used. This is attributed to more favorable mobility ratios resulting from asphalt deposition during...

  12. Asphalt Pavement Aging and TemperatureAsphalt Pavement Aging and Temperature Dependent Properties using a FunctionallyDependent Properties using a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and TemperatureAsphalt Pavement Aging and Temperature Dependent Properties Analysis Time Integration Analysis Application Examples: Asphalt Pavement Summary and Conclusions #12) ­ Large fraction produced as hot-mix asphalt (HMA) ­ Most common form of pavement surfacing material (96

  13. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    C-130 T0 T1 G1 Ethane Propane i-Butane n-Butane i-Pentane n-ppbv) Ethane Ethene Ethyne Propane Propene i-Butane n-Butanee.g. , ethane, ethene, propane, propane, methanol, ethanol,

  14. Finding the missing stratospheric Bry: a global modeling study of CHBr3 and CH2Br2

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    C-130 T0 T1 G1 Ethane Propane i-Butane n-Butane i-Pentane n-ppbv) Ethane Ethene Ethyne Propane Propene i-Butane n-Butanee.g. , ethane, ethene, propane, propane, methanol, ethanol,

  15. Liquid Propane Injection Applications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomy and EmissionsDepartment of EnergyLiquid propane

  16. Residential propane price decreases slightly decreases slightly

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane price7,

  17. Alternative Fuels Data Center: Propane Related Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version Share this

  18. Investigation of Noise and Durability Performance Trends for Asphaltic Pavement Surface Types: Three-Year Results

    E-Print Network [OSTI]

    Lu, Qing; Kohler, Erwin R.; Harvey, John T; Ongel, Aybike

    2009-01-01T23:59:59.000Z

    Trends for Asphalt Pavement Surface Types: First- andResults. University of California Pavement Research Center,Trends for Asphaltic Pavement Surface Types: First- and

  19. A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products

    E-Print Network [OSTI]

    Levinson, Ronnen

    2010-01-01T23:59:59.000Z

    for providing concrete tiles, and Lou Hahn of GAF-Elk forof cool colored concrete tile and asphalt shingle roofingsolar-reflective nonwhite concrete tile and asphalt shingle

  20. National propane safety week caps fifth anniversary of GAS Check

    SciTech Connect (OSTI)

    Prowler, S.

    1990-09-01T23:59:59.000Z

    This paper reports on National Propane Safety Week. The publicity encompassed everything from preventative maintenance to safe winter storage of cylinders. This campaign focused much of its attention on GAS (gas appliance system) Check, the propane industry's most well-known safety program.

  1. Predicting the fatigue life of asphalt concrete overlay systems

    E-Print Network [OSTI]

    Germann, Frederick P

    1979-01-01T23:59:59.000Z

    ON CRACK GROWTH IN VISCOELASTIC MATERIALS C'HAPTER V - STATE OF THE ART Effect of Mix Variables on Fatigue and Cracking Resistance in Asphalt Concrete Pavements . Field Performance of Asphalt Overlays with Fabric Summary CHAPTER VI ? MATERIALS... LIFE OF AN ASPHALT OVERLAY CHAPTER X - CONCLUSIONS AND RECOMMENDATIONS REFERENCES APPENDIX A. CRACK TIP STRESS ANALYSIS APPENDIX B. CONSTRUCTION OF THE MASTER RESILIENT MODULUS AND MASTER CREEP COMPLIANCE CURVES APPENDIX C. CRACK GROWTH RATES, da...

  2. Microstructural Characterization of Material Properties and Damage in Asphalt Composites

    E-Print Network [OSTI]

    Mohammad Khorasani, Sara

    2013-05-03T23:59:59.000Z

    MICROSTRUCTURAL CHARACTERIZATION OF MATERIAL PROPERTIES AND DAMAGE IN ASPHALT COMPOSITES A Thesis by SARA MOHAMMAD KHORASANI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... Engineering Copyright 2013 Sara Mohammad Khorasani ii ABSTRACT Asphalt composites are used to construct 90% of roads in the United States. These composites consist of asphalt binder, which is a product of the refinery process of oil, aggregates...

  3. Safety evaluation for packaging (onsite) nitrogen trailers propane tanks

    SciTech Connect (OSTI)

    Ferrell, P.C.

    1998-01-28T23:59:59.000Z

    The purpose of the Safety Evaluation for Packaging (SEP) is the evaluation and authorization of the onsite transport of propane tanks that are mounted on the Lockheed Martin Hanford Corporation Characterization Project`s nitrogen trailers. This SEP authorizes onsite transport of the nitrogen trailers, including the propane tanks, until May 31, 1998. The three nitrogen trailers (HO-64-4966, HO-64-4968, and HO-64-5170) are rated for 1,361 kg (30,000 lb) and are equipped with tandem axles and pintel hitches. Permanently mounted on each trailer is a 5,678 L (1,500 gal) cryogenic dewar that is filled with nitrogen, and a propane fired water bath vaporizer system, and a 454 L (1 20 gal) propane tank. The nitrogen trailer system is operated only when it is disconnected from the tow vehicle and is leveled and stabilized. When the trailers are transported, the propane tanks are isolated via closed supply valves.

  4. asphalt technology test: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and evaluated its performance when used in split mastic asphalt (SMA) mixture using Marshall Characteristic and dynamic charateristics (resilient modulus). As many as 90...

  5. anionic emulsified asphalt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 15 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization Websites...

  6. asphalt rock: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 17 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  7. asphaltic sand: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 19 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  8. asphalt concrete overlays: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    experimental results for concrete containing virgin limestone Paulino, Glaucio H. 71 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  9. asphalt overlay design: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    these overlay networks. Routing and search in these overlay ... Cheng, Bow-Nan 69 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  10. asphalt binder extraction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 43 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  11. Full-Depth Pavement Reclamation with Foamed Asphalt: Final Report

    E-Print Network [OSTI]

    Jones, David; Fu, P.; Harvey, John T; Halles, F.

    2008-01-01T23:59:59.000Z

    University of California Pavement Research Center. (WP-2005-8 th Conference on Asphalt Pavements for Southern Africa (International Journal of Pavement Engineering, Vol 8, No

  12. asphalt concrete bases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large amounts of PS wastes in civil engineering constructions. Key words: Asphalt surfaces Disposable dishes Polystyrene (PS) Wastes Environment A. Akbari Motlagh; A....

  13. asphalt concrete soil: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large amounts of PS wastes in civil engineering constructions. Key words: Asphalt surfaces Disposable dishes Polystyrene (PS) Wastes Environment A. Akbari Motlagh; A....

  14. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, Richard B. (Hurricane, WV); Warren, Barbara K. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  15. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, R.B.; Warren, B.K.

    1991-12-17T23:59:59.000Z

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using a catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  16. Why Study Mineralogy? Perspective from Prof. Ethan Baxter on

    E-Print Network [OSTI]

    Baxter, Ethan F.

    Why Study Mineralogy? Perspective from Prof. Ethan Baxter on CAS ES 222 "Mineralogy" offered IN GEOSCIENCES · Mineralogy is a foundational course for students with broad geosciences interests. · Mineralogy is a recommended prerequisite for ES301 (Structural Geology) and ES424 (Petrology). · Mineralogy

  17. Sequestration of ethane in the cryovolcanic subsurface of Titan

    E-Print Network [OSTI]

    Olivier Mousis; Bernard Schmitt

    2008-02-07T23:59:59.000Z

    Saturn's largest satellite, Titan, has a thick atmosphere dominated by nitrogen and methane. The dense orange-brown smog hiding the satellite's surface is produced by photochemical reactions of methane, nitrogen and their dissociation products with solar ultraviolet, which lead primarily to the formation of ethane and heavier hydrocarbons. In the years prior to the exploration of Titan's surface by the Cassini-Huygens spacecraft, the production and condensation of ethane was expected to have formed a satellite-wide ocean one kilometer in depth, assuming that it was generated over the Solar system's lifetime. However, Cassini-Huygens observations failed to find any evidence of such an ocean. Here we describe the main cause of the ethane deficiency on Titan: cryovolcanic lavas regularly cover its surface, leading to the percolation of the liquid hydrocarbons through this porous material and its accumulation in subsurface layers built up during successive methane outgassing events. The liquid stored in the pores may, combined with the ice layers, form a stable ethane-rich clathrate reservoir, potentially isolated from the surface. Even with a low open porosity of 10% for the subsurface layers, a cryovolcanic icy crust less than 2300 m thick is required to bury all the liquid hydrocarbons generated over the Solar system's lifetime.

  18. Compositional evaluation of asphalt binder recycling agents

    E-Print Network [OSTI]

    Madrid, Richard Charles

    1997-01-01T23:59:59.000Z

    from: Exxon Research and Engineering Company, The National Consortium for Graduate Degrees for Minorities in Engineering and Science, Inc. Fellowship (GEM), and the DOW Technical Fellowship is greatly appreciated. I thank Sophie and Ignacio Madrid... for Recycled Blends . . . . . Asphaltic Materials. . 54 58 63 69 V-2 V-3 V-4 V-5 V-6 V-7 Fina DMO and Exxon Tank Compositions and Viscosities. . . . Blend Compositions and Viscosities...

  19. Rheological Investigation of the Influence of Acrylate Polymers on the Modification of Asphalt

    E-Print Network [OSTI]

    Hussein, Ibnelwaleed A.

    and superior ACM properties when blended with the high asphaltenes Arabian asphalt. © 2006 Wiley Periodicals

  20. Recycled rubber, aggregate, and filler in asphalt paving mixtures. Transportation research record

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    ;Contents(Partial): Evaluation Systems for Crumb Rubber Modified Binders and Mixtures; Hot Mix Asphalt Rubber Applications in Virginia; Evaluation of Pyrolized Carbon Black from Scrap Tires as Additive in Hot Mix Asphalt; Use of Scrap Tire Chips in Asphaltic Membrane; Effects of Mineral Fillers on Properties of Stone Matrix Asphalt Mixtures; and Quantitative Analysis of Aggregate Based on Hough Transform.

  1. Field Manual for Crack Sealing in Asphalt Pavements

    E-Print Network [OSTI]

    Texas at Austin, University of

    Field Manual for Crack Sealing in Asphalt Pavements Yetkin Yildirim, Ahmed Qatan, and Jorge Prozzi January 2006 3208RedRiver Austin,TX78705 #12;Dr. Yetkin Yildirim, P.E. Director Texas Pavement for Crack Sealing in Asphalt Pavements #12;Performing Organization: Center for Transportation Research

  2. Recycling asphalt overview of more than 25 years of use

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Recycling asphalt overview of more than 25 years of use in France Y. Brosseaud ­ LCPC hal with ring for recycling ­ Average rate with high proportion : 30 to 50% ­ Used of rejuvenators (soft oil,version1-20May2011 #12;4 Hot recycling asphalt on mixing plant Recycling in place in hot or cold

  3. Relationship Between Surface Free Energy and Total Work of Fracture of Asphalt Binder and Asphalt Binder-Aggregate Interfaces 

    E-Print Network [OSTI]

    Howson, Jonathan Embrey

    2012-10-19T23:59:59.000Z

    is the surface free energy of the asphalt binder and the aggregate. Surface free energy, which is a thermodynamic material property, is directly related to the adhesive bond energy between the asphalt binder and the aggregate as well as the cohesive bond energy...

  4. Relationship Between Surface Free Energy and Total Work of Fracture of Asphalt Binder and Asphalt Binder-Aggregate Interfaces

    E-Print Network [OSTI]

    Howson, Jonathan Embrey

    2012-10-19T23:59:59.000Z

    is the surface free energy of the asphalt binder and the aggregate. Surface free energy, which is a thermodynamic material property, is directly related to the adhesive bond energy between the asphalt binder and the aggregate as well as the cohesive bond energy...

  5. Can propane school buses save money and provide other benefits...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Can propane school buses save money and provide other benefits? October 1, 2014 Tweet EmailPrint School districts across the country are looking for ways to save money and be more...

  6. VEE-0040- In the Matter of Western Star Propane, Inc.

    Broader source: Energy.gov [DOE]

    On February 18, 1997, Western Star Propane, Inc. (Western) filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE). In its application,...

  7. VEE-0060- In the Matter of Blakeman Propane, Inc.

    Broader source: Energy.gov [DOE]

    On May 11, 1999, Blakeman Propane, Inc. (Blakeman) of Moorcroft, Wyoming, filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE). In its...

  8. Residential home heating oil and propane survey, 1991--1992

    SciTech Connect (OSTI)

    Not Available

    1992-05-01T23:59:59.000Z

    This report contains pricing and consumption data on heating oils and propane for the Maine residential sector during the heating season 1991--1992. The information was gathered by survey. (VC)

  9. Dynamics of Propane in Silica Mesopores Formed upon Propylene Hydrogenation over Pt Nanoparticles by Time-Resolved FT-IR Spectroscopy

    E-Print Network [OSTI]

    Waslylenko, Walter; Frei, Heinz

    2008-01-01T23:59:59.000Z

    A steady state distribution of propane between gas andK). A steady state distribution of propane between gas phasesteady state distribution between propane inside and outside

  10. Improvements to a Transport Model of Asphalt Binder Oxidation in Pavements: Pavement Temperature Modeling, Oxygen Diffusivity in Asphalt Binders and Mastics, and Pavement Air Void Characterization

    E-Print Network [OSTI]

    Han, Rongbin

    2012-07-16T23:59:59.000Z

    Although evidence is mounting that asphalt binder oxidizes in pavements, and that oxidation and subsequent hardening of asphalt binder has a profound effect on pavement durability, important implementation issues remain to be better understood...

  11. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded Viscoelastic Model, Part-II: Applications

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded simulation of functionally graded viscoelastic properties in asphalt concrete pavements. The techniques properties. A full-depth asphalt concrete pavement has been simulated to demonstrate the applicability

  12. The curing of asphalt with rubber and its effect on the physical and chemical properties of asphalt-rubber binders

    E-Print Network [OSTI]

    Chun, Jay Sung

    1995-01-01T23:59:59.000Z

    10% TG-40 and 90% Exxon AC-5. 105 B-1 Molecular Size Distribution of Rubber in Asphalt 5% TG-40 and 95% Fina AC-10. . . 123 B-2 Molecular Size Distribution of Rubber in Asphalt 10% TG-40 and 90% Fina AC-10. . 124 xlv FIGURE B-3 Molecular Size.... 0 Frequency (rad/s) 10. 0 100. 0 Figure III-2: Effect of Frequency on Viscosity Measurements Fina AC-10 Tank Asphalt 2500 2000 0 a 1500 1000 o 0 0 0 0 o o 0 0 0 0 0 0 0 o 0 Fina AC-10 with 5% TG-40 mesh rubber Cured at 375 F and 500...

  13. asphalt emulsions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 21 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  14. Characterization of Fatigue Cracking and Healing of Asphalt Mixtures

    E-Print Network [OSTI]

    Luo, Xue

    2012-07-16T23:59:59.000Z

    mixtures using an energy-based mechanistic approach. A controlled-strain repeated direct tension (RDT) test is selected to generate both fatigue cracking and permanent deformation in an asphalt mixture specimen. Fatigue cracking is separated from...

  15. Viscoelastic{Viscoplastic Damage Model for Asphalt Concrete

    E-Print Network [OSTI]

    Graham, Michael A.

    2010-10-12T23:59:59.000Z

    This thesis presents a continuum model for asphalt concrete incorporating non- linear viscoelasticity, viscoplasticity, mechanically-induced damage and moisture- induced damage. The Schapery single-integral viscoelastic model describes the nonlinear...

  16. A thermodynamic approach for compaction of asphaltic composites

    E-Print Network [OSTI]

    Koneru, Saradhi

    2009-05-15T23:59:59.000Z

    and Focus of Current Work . . . . . . . . . . . . . . 2 B. Outline of the Thesis . . . . . . . . . . . . . . . . . . . . . 3 C. Notations Used . . . . . . . . . . . . . . . . . . . . . . . . 4 II LITERATURE REVIEW... . . . . . . . . . . . . . . . . 8 b. Asphalt Binder . . . . . . . . . . . . . . . . . . . 8 C. Compaction Equipment . . . . . . . . . . . . . . . . . . . . 9 1. Field Compaction Equipment . . . . . . . . . . . . . . 9 a. Static Steel Wheel Rollers . . . . . . . . . . . . . 9 b...

  17. asphaltic pavements microsurfacing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  18. asphalt pavement cracking: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 16 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  19. asphalt concrete pavement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  20. asphalt pavement rap: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  1. asphaltic concrete pavement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  2. asphalt concrete pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  3. asphaltic concrete pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  4. asphalt pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  5. Measurements of moisture suction in hot mix asphalt mixes 

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    with different bond energies and exhibited different field performance in terms of resistance to moisture damage. The suction measurements in sand asphalt specimens were used to calculate the moisture diffusion coefficient. The results revealed that water...

  6. Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures 

    E-Print Network [OSTI]

    Vasconcelos, Kamilla L.

    2011-08-08T23:59:59.000Z

    coefficient measurement of a wide variety of polymersolvent systems. For the asphalt-water system studied, the focus is on two techniques: (i) Fourier Transform Infrared (FTIR)-Attenuated Total Reflectance (ATR) spectrometry and (ii) Gravimetric Sorption...

  7. Imparting Electrical Conductivity into Asphalt Composites Using Graphite 

    E-Print Network [OSTI]

    Baranikumar, Aishwarya

    2013-07-09T23:59:59.000Z

    publications showed the potential of graphite in mitigating the sudden transition. The study presented herein investigates possibility of precisely controlling the electrical conductivity of asphalt concrete only by adding filler size graphite powder. Nine...

  8. asphalt concrete performance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robert L. 2014-01-01 23 Establishing material properties for thin asphalt concrete surfaces on granular bases Texas A&M University - TxSpace Summary: of MASTER OF SCIENCE...

  9. Study of properties of sand asphalt using a torsional rheometer 

    E-Print Network [OSTI]

    Kasula, Lavan Kumar Reddy

    2004-11-15T23:59:59.000Z

    The modeling of Sand Asphalt and experiments to measure their rheological properties are of vital concern to many industrial processes especially highway and roadway pavement construction industry. A variety of hot mix ...

  10. Use of VFDs on Asphalt Plant Induced Draft Fans

    E-Print Network [OSTI]

    Anderson, G. R.; Case, P. L.; Lowery, J.

    2005-01-01T23:59:59.000Z

    Studies of 10 asphalt plants in the Intermountain Region have identified average ID fan energy savings of 68% by controlling airflow using Variable Frequency Drives (VFDs) on the fan motors in place of damper control (inlet or outlet). Average...

  11. Fiber reinforcement of asphalt concrete using cow manure

    E-Print Network [OSTI]

    Bakar, Mohammed Abu

    1976-01-01T23:59:59.000Z

    . Specimens were made according to the Marshall Method of Mixture Design and tested for 1) Marshall Stability 2) Hveem Stability and 3) Hater Susceptibil- ity. Test results indicated that 4. 4 percent cow manure by volume of rhe total aggregate when used... Voids in Mineral Aggregate 11 LIST OF FIGURES Figures Page l. 2 l. 3 1. 4 1. 5 1. 6 Determination of Optimum Asphalt Content by the Marshall Method Determination of Optimum Asphalt Content by the Marshall Method Determination of Optimum...

  12. Characterization of road asphalt using Gel Permeation Chromatography

    E-Print Network [OSTI]

    Donaldson, Guy Randal

    1987-01-01T23:59:59.000Z

    inconsistent and inconsistent. Six were consistent, three were slightly inconsist nt, and three were inconsistent. To study the relationship between GPC and performance, samples from test pavements at three locations were obtained. Both original asphalts... Columns/Toluene/100 Nicroliters/ 7X 3 ' 2. Reproducibility of the Standard Asphalt in THF . ~ . . ~ . ~ . . . 500 and 50 Angstrom Columns/Toluene/100 Nicroliters/ 7X 19 3. 3. Differences in Refractive Index Detector Response. Exxon AC-10/Dumas Tank...

  13. Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement

    E-Print Network [OSTI]

    Tong, Yunwei

    2013-11-08T23:59:59.000Z

    aggregate contact due to dust particles on the aggregate surface. The rupture may occur because of the construction loads and operating traffic during construction, or could be environmentally induced by freeze-thaw cycling. Once a break in the film... design, environment and traffic, can be defined as progressive degradation of asphalt mixture material due to the presence of water. The occurrence of moisture damage in asphalt material is a rather complex phenomenon, which involves chemical, physical...

  14. MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER -METHANE AND WATER -ETHANE MIXTURES

    E-Print Network [OSTI]

    1 MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER - METHANE AND WATER - ETHANE MIXTURES Jeffrey were used to calculate water - methane and water - ethane phase equilibria over a wide range and petrochemical industry, natural and petroleum gas production, and environmental control. For many

  15. Experimental studies of steam-propane injection for the Duri intermediate crude oil 

    E-Print Network [OSTI]

    Hendroyono, Arief

    2003-01-01T23:59:59.000Z

    Laboratory experimental studies were carried out to better understand production mechanisms involved in steam-propane injection and to investigate effects of expected field pressure and temperature conditions on steam-propane injection...

  16. Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions tests of in-use heavy-duty vehicles...

  17. Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)

    E-Print Network [OSTI]

    Kushner, Mark

    Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia) Department exhausts with hydrocarbons propane (C3H8) and propene (C3H6) has been investigated. In general

  18. Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and David H. Olson,

    E-Print Network [OSTI]

    Li, Jing

    Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Kunhao Li, David H the first examples of MMOFs that are capable of kinetic separation of propane and propene (propylene), which

  19. Experimental studies of steam-propane injection for the Duri intermediate crude oil

    E-Print Network [OSTI]

    Hendroyono, Arief

    2003-01-01T23:59:59.000Z

    Laboratory experimental studies were carried out to better understand production mechanisms involved in steam-propane injection and to investigate effects of expected field pressure and temperature conditions on steam-propane injection...

  20. Alternative Fuels Data Center: Propane Powers Airport Shuttles in New

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropaneOrleans Propane

  1. Propane Vehicle and Infrastructure Codes and Standards Chart (Revised) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01T23:59:59.000Z

    This chart shows the SDOs responsible for leading the support and development of key codes and standards for propane.

  2. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report, #930-of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferred to use a mix that would have good moisture resistance under laboratory testing

  3. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Harvey, John T; Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report no.of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferable to use a mix that would have good moisture resistance under laboratory testing

  4. A Coupled Micromechanical Model of Moisture-Induced Damage in Asphalt Mixtures: Formulation and Applications 

    E-Print Network [OSTI]

    Caro Spinel, Silvia

    2011-02-22T23:59:59.000Z

    The deleterious effect of moisture on the structural integrity of asphalt mixtures has been recognized as one of the main causes of early deterioration of asphalt pavements. This phenomenon, usually referred to as moisture damage, is defined...

  5. Experimental Study on Geocell-Reinforced Recycled Asphalt Pavement (RAP) Bases under Static and Cyclic Loading

    E-Print Network [OSTI]

    Thakur, Jitendra Kumar

    2011-01-13T23:59:59.000Z

    Recycled Asphalt Pavement (RAP) is a removed and reprocessed pavement material containing asphalt and aggregates which can be used as a base course material for pavement applications. Geocells are a three-dimensional interconnected honeycomb type...

  6. Asphalt compositions containing spurted polyolefin fibers with improved dispersibility in hydrocarbons

    SciTech Connect (OSTI)

    Jabloner, H.

    1987-07-07T23:59:59.000Z

    A cutback asphalt composition is described comprising asphalt and a hydrocarbon solvent. The improvement composition comprises a water-dispersible spurted polyolefin pulp having precipitated a natural rubber or synthetic elastomer that is swellable in hydrocarbon solvents.

  7. E-Print Network 3.0 - asphalt mix design Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Environmental Engineering, Arizona State University Collection: Engineering 35 Bi Oil i A h ltBio-Oil in Asphalt ApplicationsApplications Summary: tons of hot mix asphalt...

  8. Evaluation of the filler effects on fatique cracking and permanent deformation of asphalt concrete mixtures 

    E-Print Network [OSTI]

    Izzo, Richard P

    1997-01-01T23:59:59.000Z

    The addition of hydrated lime to asphalt has shown to be beneficial with an improvement in the Theological properties of the binder, as well as resistance to permanent deformation (rutting) and fatigue cracking of asphalt concrete mixtures...

  9. Evaluation of the filler effects on fatique cracking and permanent deformation of asphalt concrete mixtures

    E-Print Network [OSTI]

    Izzo, Richard P

    1997-01-01T23:59:59.000Z

    The addition of hydrated lime to asphalt has shown to be beneficial with an improvement in the Theological properties of the binder, as well as resistance to permanent deformation (rutting) and fatigue cracking of asphalt concrete mixtures...

  10. A KINETIC STUDY OF AEROBIC PROPANE UPTAKE AND COMETABOLIC DEGRADATION OF CHLOROFORM,

    E-Print Network [OSTI]

    Semprini, Lewis

    A KINETIC STUDY OF AEROBIC PROPANE UPTAKE AND COMETABOLIC DEGRADATION OF CHLOROFORM, CIS the behavior of different consortiums of aerobic propane-utilizing microorganisms, with respect to both the lag time for growth after exposure to propane, and their ability to transform three chlorinated aliphatic

  11. Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

  12. Functional Characterization of Propane-Enhanced N-Nitrosodimethylamine Degradation by

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    ARTICLE Functional Characterization of Propane-Enhanced N-Nitrosodimethylamine Degradation by Two: Propane-induced cometabolic degradation of n-nitrosodimethylamine (NDMA) by two propanotrophs is characterized through kinetic, gene presence, and expression studies. After growth on propane, resting cells

  13. Ceramic microreactors for on-site hydrogen production from high temperature steam reforming of propane{

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    of propane{ Christian, Michael Mitchell and Paul J. A. Kenis* Received 31st May 2006, Accepted 10th August of propane into hydrogen at temperatures between 800 and 1000 uC. We characterized these microreactors. Kinetic analysis using a power law model showed reaction orders of 0.50 and 20.23 with respect to propane

  14. Fourier transform microwave spectrum of the propane-water complex: A prototypical water-hydrophobe system

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Fourier transform microwave spectrum of the propane-water complex: A prototypical water) The Fourier transform microwave spectrum of the propane-water complex (C3H,-H,O) has been observed and analyzed. This spectrum includes transitions assigned to propane complexed with both the ortho and para

  15. Improved Product-Per-Glucose Yields in P450-Dependent Propane Biotransformations

    E-Print Network [OSTI]

    Arnold, Frances H.

    ARTICLE Improved Product-Per-Glucose Yields in P450-Dependent Propane Biotransformations Using propane monooxygenase prepared by directed evolu- tion [P450PMOR2; Fasan et al. (2007); Angew Chem Int Ed of the energy source (glucose) in the propane biotransformation com- pared to the native E. coli strain. Using

  16. Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane

    E-Print Network [OSTI]

    Iglesia, Enrique

    Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane Kaidong The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo

  17. High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic

    E-Print Network [OSTI]

    High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic and propane isotherms measured at ambient temperatures and ideal adsorption solution theory (IAST) calculations revealed increasing propylene/propane selectivities with increasing pressures. The eld of highly

  18. Layering and orientational ordering of propane on graphite: An experimental and simulation study

    E-Print Network [OSTI]

    Borguet, Eric

    Layering and orientational ordering of propane on graphite: An experimental and simulation study 2002; accepted 30 July 2002 We report the results of an experimental and theoretical study of propane and experiments show that propane adsorbs in a layer-by-layer fashion and exhibits continuous growth beyond

  19. Experimental Study of Propane-Fueled Pulsed Detonation Rocket Frank K. Lu,* Jason M. Meyers,

    E-Print Network [OSTI]

    Texas at Arlington, University of

    1 Experimental Study of Propane-Fueled Pulsed Detonation Rocket Frank K. Lu,* Jason M. Meyers in comparison to cases without the spiral. Tests through a range of cycle frequencies up to 20 Hz in oxygen-propane spiral in a pulsed detonation engine operating with propane and oxygen. A high-energy igniter is used

  20. Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation

    E-Print Network [OSTI]

    Jones, William D.

    Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between] in interaction with propane. Two complexes have been found as minima coordinated through either a methyl the methylene complex of propane into a methyl complex of pro- pane. This latter reaction has a much lower

  1. Ionization Spectroscopy of Conformational Isomers of Propanal: The Origin of the Conformational Preference

    E-Print Network [OSTI]

    Kim, Sang Kyu

    Ionization Spectroscopy of Conformational Isomers of Propanal: The Origin of the Conformational conformational isomers of propanal, cis and gauche, are investigated by the vacuum-UV mass- analyzed thresholdV and 9.9516 ( 0.0006 eV, respectively. cis-Propanal, which is the more stable conformer in the neutral

  2. PROPANE -C3H8 MSDS (Document # 001045) PAGE 1 OF 8 MATERIAL SAFETY DATA SHEET

    E-Print Network [OSTI]

    Choi, Kyu Yong

    PROPANE - C3H8 MSDS (Document # 001045) PAGE 1 OF 8 MATERIAL SAFETY DATA SHEET Prepared to U in an emergency? 1. PRODUCT IDENTIFICATION CHEMICAL NAME; CLASS: PROPANE - C3H8 Document Number: 001045 PRODUCT IN AIR ACGIH OSHA TLV STEL PEL STEL IDLH OTHER ppm ppm ppm ppm ppm Propane 74-98-6 > 96.0 Simple

  3. Coleman Two Burner Stove The Coleman Matchlight 2-Burner Propane Stove is especially designed for outdoor

    E-Print Network [OSTI]

    Walker, Lawrence R.

    Coleman Two Burner Stove The Coleman Matchlight 2-Burner Propane Stove is especially designed-burner propane stove has a high-pressure regulator that ensures a constant flame regardless of weather propane stove has a removable nickel-chrome-plated grate that makes for easy cleaning. The aluminized

  4. Absorption du rayonnement 12 et 8 millimtres par les vapeurs de propane sous pression

    E-Print Network [OSTI]

    Boyer, Edmond

    Absorption du rayonnement 12 et 8 millimètres par les vapeurs de propane sous pression A. Battaglia des pertes diélectriques (03B5") présentées par le propane gazeux aux fréquences de 24 et 36 GHz, à la Birnbaum. Abstract. 2014 Experimental study of dielectric losses (03B5") presented by gaseous propane

  5. Dehydrogenation of Propane to Propylene over Supported Model NiAu Catalysts

    E-Print Network [OSTI]

    Goodman, Wayne

    Dehydrogenation of Propane to Propylene over Supported Model Ni­Au Catalysts Zhen Yan · Yunxi Yao 2012 Ó Springer Science+Business Media, LLC 2012 Abstract Hydrogenolysis and dehydrogenation of propane. For the conversionofpropane in the presence of hydrogen, the dehydrogenation of propane to propylene was observed onthe Ni

  6. Development of asphalts and pavements using recycled tire rubber. Phase 1: technical feasibility. Final report

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J. [and others

    1998-01-01T23:59:59.000Z

    This report documents the technical progress made on the development of asphalts and pavements using recycled tire rubber.

  7. A study of the mixing viscosity of asphalt in hot-mix production

    E-Print Network [OSTI]

    Khan, Md. Musharraf Hossain

    1961-01-01T23:59:59.000Z

    Gravity and Absorption of Aggregates. 36 Sieve Analysis of Combined Aggregates 37 Centrifuge Kerosene Equivalent Test Data for Estimated Optimum Asphalt Content . 38 Test Data on Molded Specimens for Optimum Asphalt Content 39 XIII . Test Data... there is available to be filled with asphalt. The Centrifuge Kerosene Equivalent (CKE) Test was performed to 11 determine the estimated optimum asphalt content as a percentage of the 10 The American Association of State Highway Officials, "Standard...

  8. Asphalt Roofing Shingles Into Energy Project Summary Report

    SciTech Connect (OSTI)

    Jameson, Rex, PE

    2008-04-28T23:59:59.000Z

    Based on a widely cited September, 1999 report by the Vermont Agency of Natural Resources, nearly 11 million tons of asphalt roofing shingle wastes are produced in the United States each year. Recent data suggests that the total is made up of about 9.4 million tons from roofing tear-offs and about 1.6 million tons from manufacturing scrap. Developing beneficial uses for these materials would conserve natural resources, promote protection of the environment and strengthen the economy. This project explored the feasibility of using chipped asphalt shingle materials in cement manufacturing kilns and circulating fluidized bed (CFB) boilers. A method of enhancing the value of chipped shingle materials for use as fuel by removing certain fractions for use as substitute raw materials for the manufacture of new shingles was also explored. Procedures were developed to prevent asbestos containing materials from being processed at the chipping facilities, and the frequency of the occurrence of asbestos in residential roofing tear-off materials was evaluated. The economic feasibility of each potential use was evaluated based on experience gained during the project and on a review of the well established use of shingle materials in hot mix asphalt. This project demonstrated that chipped asphalt shingle materials can be suitable for use as fuel in circulating fluidized boilers and cement kilns. More experience would be necessary to determine the full benefits that could be derived and to discover long term effects, but no technical barriers to full scale commercial use of chipped asphalt shingle materials in these applications were discovered. While the technical feasibility of various options was demonstrated, only the use of asphalt shingle materials in hot mix asphalt applications is currently viable economically.

  9. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01T23:59:59.000Z

    study of ethane and propane oxidation in the tropo- sphere,alkanes (ethane, C 2 H 6 ; propane, C 3 H 8 ; n-butane, n-Cfluid contamination. 4.1.2. Propane [ 24 ] Propane levels in

  10. Zeolitic imidazolate frameworks for kinetic separation of propane and propene

    SciTech Connect (OSTI)

    Li, Jing; Li, Kunhao; Olson, David H.

    2014-08-05T23:59:59.000Z

    Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.

  11. Recycling of plastic and rubber tire waste in asphalt pavements

    SciTech Connect (OSTI)

    Morrison, G.R.; Lee, N.K.; Hesp, S.A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Chemistry

    1994-12-31T23:59:59.000Z

    This paper discusses some important issues related to the use of recycled thermoplastics and rubber tire waste in asphalt binders for hot-mix pavements. Both high temperature rheological and low temperature fracture studies are presented on recycled polyethylene, devulcanized and crumb rubber-modified asphalt binders. The results are compared to unmodified and commercially available modified binders. This research is especially timely in light of the US Intermodal Surface Transportation Efficiency Act of 1991, Section 1038 which, starting in 1995, will force state and local governments to use significant amounts of recycled rubber tire or plastic waste in federally funded highway projects. High temperature rheological measurements of the loss modulus, loss tangent and complex modulus show a significant improvement when only small quantities of crumb rubber, devulcanized crumb rubber or waste polyethylene are added to the asphalt binders. The low temperature fracture performance of the modified asphalts is greatly influenced by the interfacial strength between the dispersed and continuous phase. The fracture toughness increases dramatically, only when low molecular weight polymers are grafted in-situ onto the rubber and polymer dispersed phases in order to strength the interface. This points to a crack-pinning mechanism as being responsible for the dramatic increase in fracture toughness that is observed in this work. Single phase, devulcanized crumb rubber-asphalt systems perform quite poorly at low temperatures.

  12. Experimental comparison of hot water/propane injection to steam/propane injection for recovery of heavy oil 

    E-Print Network [OSTI]

    Nesse, Thomas

    2005-02-17T23:59:59.000Z

    , attempts have been made to inject hot water instead of steam. The results have all been rather poor, the major problem being low sweep efficiency. The hot water just doesn?t enhance oil recovery enough. Adding propane to the steam injected in the reservoir...

  13. Experimental comparison of hot water/propane injection to steam/propane injection for recovery of heavy oil

    E-Print Network [OSTI]

    Nesse, Thomas

    2005-02-17T23:59:59.000Z

    , attempts have been made to inject hot water instead of steam. The results have all been rather poor, the major problem being low sweep efficiency. The hot water just doesn?t enhance oil recovery enough. Adding propane to the steam injected in the reservoir...

  14. Effect of a current polarisation on BIMEVOX membranes for oxidation of propane in a Catalytic Dense Membrane

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Effect of a current polarisation on BIMEVOX membranes for oxidation of propane in a Catalytic Dense of propane under OCV and under electrical bias. The propane conversion remained constantly equal to 12 by partial oxidation and oxidative dehydrogenation of propane, respectively. An anodic polarisation led

  15. Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique unlabeled products from mixtures of propene and propane-2-13C reactants. Aromatic products of propane-2-13C-Parmer) that allowed differential reactor operation (propane reactions were

  16. New thermodynamic diagrams developed for methane and ethane

    SciTech Connect (OSTI)

    Yaws, C.L.; Sheth, S.D.; Han, M. [Lamar Univ., Beaumont, TX (United States)

    1995-12-04T23:59:59.000Z

    Thermodynamic diagrams have been developed for methane and ethane. The diagrams determine volume and enthalpy as a function of pressure and temperature. The diagrams cover a wide range of conditions and are designed for ease of use. The enthalpy diagrams also contain constant-entropy lines, which allow engineers to solve second-law problems such as adiabatic expansion and fluid compression. Each diagram includes: a two-phase region for saturated liquid and vapor; a superheated gas region for gases at temperatures above the saturation temperature; a subcooled liquid region for liquids at temperatures below the saturation temperature; and a supercritical region for temperatures and pressures above the critical point. Representative engineering uses are illustrated in three examples.

  17. Use of recycled chunk rubber asphalt concrete (CRAC) on low volume roads and use of recycled crumb rubber modifier in asphalt pavements. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Hossain, M.; Funk, L.P.; Sadeq, M.A.; Marucci, G.

    1995-06-01T23:59:59.000Z

    The major objective of this project was to formulate a Chunk Rubber Asphalt Concrete (CRAC) mix for use on low volume roads. CRAC is a rubber modified asphalt concrete product produced by the `dry process` where rubber chunks of 1/2 inch size are used as aggregate in a cold mix with a type C fly ash. The second objective of this project was to develop guidelines concerning the use of rubber modified asphalt concrete hot mix to include: (1) Design methods for use of asphalt-rubber mix for new construction and overlay, (2) Mix design method for asphalt-rubber, and (3) Test method for determining the amount of rubber in an asphalt-rubber concrete for quality control purposes.

  18. Effect of pyrolyzed carbon black on asphalt cement. Part 2. Asphalt binder. Final report, September 1993-May 1995

    SciTech Connect (OSTI)

    Zeng, Y.; Lovell, C.W.

    1996-02-20T23:59:59.000Z

    Scrap tires derived from automobiles have become a large environmental problem in the United States. In the study, research is carried out to investigate the potential use of tire-derived pyrolyzed carbon black from scrap tires as an asphalt cement modifier. The asphlat cements used in the research were AC10 and AC20. Penetration and softening point tests were performed to obtain the consistency of the asphalt cements. The pyrolyzed carbon black, as provided by Wolf Industries, was combined with the asphalt cement in the following percentages: 5%, 10%, 15% and 20%. Penetration, softening point and ductility tests were performed to determine the temperature susceptibility of the modified binder as altered by the pyrolyzed carbon black. In order that the results are comparable to previous testing, commercial carbon black purchased from CABOT Industry was also used as a modifier in the tests. The same test procedures were applied to the asphalt cements modified by commercial carbon black. The test results contained in the report illustrate the viability of the pyrolyzed carbon black as an asphalt modifier. Recommendations are provided to facilitate further research on this particular project. A preliminary assessment of a test road using the pyrolyzed carbon is appended.

  19. A study of the effects of limestone rock asphalt screenings on the structural properties of hot-mix asphaltic concrete made with siliceous materials 

    E-Print Network [OSTI]

    Albritton, Oscar Willard

    1958-01-01T23:59:59.000Z

    LiSRagy pptt8pp py IEXAa A STUDY OF THE EFFECTS OF LIMESTONE ROCK ASPHALT SCREENINGS ON THE STRUCTURAL PROPERTIES OF HOT-MIX ASPHALTIC CONCRETE MADE WITH SILICEOUS MATERIALS A Thesis By OSCAR WILLARD. AQBRITTON Submitted to the Graduate... ON THE STRUCTURAL PROPERTIES OF HOT-MIX ASPHALTIC CONCRETE MADE WITH SILICEOUS MATERIALS A Thesis By OSCAR WILLARD ALBRITTON Approved as to Style and Content by: Chairman of Committee ead of Departme t August 1958 ACKNOWLEDGMENTS Acknowledgment is due...

  20. Recycling asphaltic concrete with sulphur as a supplemental binder

    E-Print Network [OSTI]

    Barnett, Robert William

    1976-01-01T23:59:59.000Z

    in the United States, and the use of this secondary sulphur for construction purposes could provide not only a vast savings of natural resources and reusable materials but also aid industry in recovering the cost of environ- mental protection. The waste... industry [25, 26, 27, 28]. Research has been undertaken to investigate the use of sulphur in sand-asphalt- sulphur pavement mixes [11, 25, 29, 30]. The use of sulphur in sulphur-asphalt emulsions to serve as a binder has also been studied [26, 31, 32...

  1. Asphalt roofing industry Fourier transform infrared spectroscopy modified bitumen

    SciTech Connect (OSTI)

    NONE

    1999-07-01T23:59:59.000Z

    A Request for Emissions Testing at Four Asphalt Roofing and Processing Facilities was submitted by the US EPA Emission Standards Division (ESD), Minerals and Inorganic Chemicals Group (MICG) to the Emission Measurement Center (EMC). The Emission Measurement Center directed Midwest Research Institute (MRI) to conduct emissions testing at asphalt roofing plants. This report presents results of MRI`s FTIR and Method 25A testing conducted at US Intec in Port Arthur, Texas. The field measurements were performed in September 1997 under several test conditions for both controlled and uncontrolled emissions.

  2. Automated titration method for use on blended asphalts

    DOE Patents [OSTI]

    Pauli, Adam T. (Cheyenne, WY); Robertson, Raymond E. (Laramie, WY); Branthaver, Jan F. (Chatham, IL); Schabron, John F. (Laramie, WY)

    2012-08-07T23:59:59.000Z

    A system for determining parameters and compatibility of a substance such as an asphalt or other petroleum substance uses titration to highly accurately determine one or more flocculation occurrences and is especially applicable to the determination or use of Heithaus parameters and optimal mixing of various asphalt stocks. In a preferred embodiment, automated titration in an oxygen gas exclusive system and further using spectrophotometric analysis (2-8) of solution turbidity is presented. A reversible titration technique enabling in-situ titration measurement of various solution concentrations is also presented.

  3. Dead poets' society New England, the 1950s. Todd Anderson (Ethan Hawke), a lonely and painfully

    E-Print Network [OSTI]

    Schenato, Luca

    Dead poets' society New England, the 1950s. Todd Anderson (Ethan Hawke), a lonely and painfully shy in it. After seeing that Mr. Keating listed "Dead Poets Society" as one of his activities at the school

  4. Evaluation of ethane as a power conversion system working fluid for fast reactors

    E-Print Network [OSTI]

    Perez, Jeffrey A

    2008-01-01T23:59:59.000Z

    A supercritical ethane working fluid Brayton power conversion system is evaluated as an alternative to carbon dioxide. The HSC® chemical kinetics code was used to study thermal dissociation and chemical interactions for ...

  5. Ethane enrichment and propane depletion in subsurface gases indicate gas hydrate occurrence in marine sediments at southern Hydrate Ridge offshore Oregon

    SciTech Connect (OSTI)

    Milkov, Alexei V.; Claypool, G E.; Lee, Young-Joo; Torres, Marta E.; Borowski, W S.; Tomaru, H; Sassen, Roger; Long, Philip E.

    2004-07-02T23:59:59.000Z

    The recognition of finely disseminated gas hydrate in deep marine sediments heavily depends on various indirect techniques because this mineral quickly decomposes upon recovery from in situ pressure and temperature conditions. Here, we discuss molecular properties of closely spaced gas voids (formed as a result of core recovery) and gas hydrates from an area of relatively low gas flux at the flanks of the southern Hydrate Ridge Offshore Oregon (ODP Sites 1244, 1245 and 1247).

  6. A Methodology of Quantifying Precipitation Exposure for Wet-Weather Collisions and Evaluating Effectiveness of Open-Grade Asphalt Concrete as a Countermeasure

    E-Print Network [OSTI]

    Chan, Ching-Yao; Jin, Eui-Jae; Oh, Soon Mi; Ragland, David R

    2010-01-01T23:59:59.000Z

    Open-graded Asphaltic Concrete Friction Courses in Arizona.for Open-Graded Asphalt Concrete (OGAC) Wearing Courses.of Open-Grade Asphalt Concrete as a Countermeasure Ching-Yao

  7. asphalt technology development: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt technology development First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Development and...

  8. asphalt based materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt based materials First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Establishing material...

  9. Controlling Thermal Properties of Asphalt Concrete and its Multifunctional Applications

    E-Print Network [OSTI]

    Shi, Xijun

    2014-08-10T23:59:59.000Z

    of the thermally modified asphalt mixtures on the surface temperature of pavements and bridges, a series of heat transfer analysis were conducted using the finite difference heat transfer model. In addition, a case study of a building using EPP modified cement...

  10. Measurements of moisture suction in hot mix asphalt mixes

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    The presence of moisture in hot mix asphalt (HMA) causes loss of strength and durability of the mix, which is referred to as moisture damage. This study deals with the development of experimental methods for measuring total suction in HMA, which can...

  11. asphalt construction premature: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt construction premature First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Moisture Diffusion in...

  12. Experimental study on transmission of an overdriven detonation wave from propane/oxygen to propane/air

    SciTech Connect (OSTI)

    Li, J.; Lai, W.H. [National Cheng Kung University, Institute of Aeronautics and Astronautics, Tainan (China); Chung, K. [National Cheng Kung University, Aerospace Science and Technology Research Center, Tainan (China); Lu, F.K. [University of Texas at Arlington, Mechanical and Aerospace Engineering Department, Aerodynamics Research Center, TX 76019 (United States)

    2008-08-15T23:59:59.000Z

    Two sets of experiments were performed to achieve a strong overdriven state in a weaker mixture by propagating an overdriven detonation wave via a deflagration-to-detonation transition (DDT) process. First, preliminary experiments with a propane/oxygen mixture were used to evaluate the attenuation of the overdriven detonation wave in the DDT process. Next, experiments were performed wherein a propane/oxygen mixture was separated from a propane/air mixture by a thin diaphragm to observe the transmission of an overdriven detonation wave. Based on the characteristic relations, a simple wave intersection model was used to calculate the state of the transmitted detonation wave. The results showed that a rarefaction effect must be included to ensure that there is no overestimate of the post-transmission wave properties when the incident detonation wave is overdriven. The strength of the incident overdriven detonation wave plays an important role in the wave transmission process. The experimental results showed that a transmitted overdriven detonation wave occurs instantaneously with a strong incident overdriven detonation wave. The near-CJ state of the incident wave leads to a transmitted shock wave, and then the transition to the overdriven detonation wave occurs downstream. The attenuation process for the overdriven detonation wave decaying to a near-CJ state occurs in all tests. After the attenuation process, an unstable detonation wave was observed in most tests. This may be attributed to the increase in the cell width in the attenuation process that exceeds the detonability cell width limit. (author)

  13. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 421 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  14. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 467 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  15. Table 14. U.S. Propane (Consumer Grade) Prices by Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    and EIA-782B, "Resellers'Retailers' Monthly Petroleum Product Sales Report." 14. U.S. Propane (Consumer Grade) Prices by Sales Type 28 Energy Information Administration ...

  16. Microsoft PowerPoint - Joe Rose.Providence.Propane Supply Infrastruct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from the Gulf Coast. * Growth in Canadian demand for diluent (Pentanes+) demand for the oil sands industry. American Shale Production In 2013, U.S. Propane Production Increased...

  17. Airborne measurement of OH reactivity during INTEX-B

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

  18. Summary of Construction Activities and Results from Six Initial Accelerated Pavement Tests Conducted on Asphalt Concrete Pavement Section for Modified-Binder Overlay

    E-Print Network [OSTI]

    Bejarano, Manuel O.; Morton, Bruce S.; Scheffy, Clark

    2005-01-01T23:59:59.000Z

    Testing on the Asphalt Concrete FWD testing was conducted onin asphalt concrete modulus after HVS testing for Sectionsconcrete pavements under accelerated pavement testing. This

  19. Dynamics of Propane in Silica Mesopores Formed upon Propylene Hydrogenation over Pt Nanoparticles by Time-Resolved FT-IR Spectroscopy

    E-Print Network [OSTI]

    Waslylenko, Walter; Frei, Heinz

    2008-01-01T23:59:59.000Z

    state distribution of propane between gas and mesopore phaseWavenumber (cm ) B Gas Phase Propane 2968 cm k 1 = 3.1 ± 0.4slices showing the gas phase propane component at 216, 648,

  20. The use of sulfer modified bottom ash (SMBA) as an aggregate in asphaltic mixtures

    E-Print Network [OSTI]

    Chimakurthy, Harshavardhan

    1998-01-01T23:59:59.000Z

    , bottom ash is lighter in weight and generally much cheaper than conventional quality aggregates such as limestone, sand and gravel. This research was designed to up-grade the load-bearing charactcnstics of bottom ash and maximize its usc m asphaltic... and gravel. According to a study done by Hafizuddin Ahmad in 1974, sulfur was used extensively in sand-asphalt sulfur to upgrade marginal aggregates for use in asphaltic mixtures, was developed at Texas Transportation Institute (TT1) (JO). TTI's work...

  1. Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures

    DOE Patents [OSTI]

    Plancher, Henry (Laramie, WY); Petersen, Joseph C. (Laramie, WY)

    1982-01-01T23:59:59.000Z

    Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

  2. The use of HPGPC for determination of MWD of asphalt cement - A spectrophotometric vs. gravimetric finish

    SciTech Connect (OSTI)

    Bishara, S.W.; McReynolds, R.L. (Kansas Dept. of Transportation, Topeka (United States))

    1990-07-01T23:59:59.000Z

    A comparison between spectrophotometric and gravimetric methods to study MWD of asphalt is presented. Spectrophotometry suffers from not detecting saturated compounds, as well as from variation of molar absorptivity during analysis. To address these shortcoming, the whole asphalt sample is fractionated, and the relative molar absorptivity determined for each fraction. Using another sample weight of the whole asphalt, the saturates are separated, and injected to get their MWD using refractive index detection. This information, when used to mathematically treat the whole asphalt distribution data, can correct the latter to include saturates as well, but can only partially account for continuous variation of the molar absorptivity.

  3. Propane cold neutron source: creation and operation experience

    SciTech Connect (OSTI)

    Zemlyanov, M. G.

    1997-09-01T23:59:59.000Z

    In most cold neutron sources, utilized until recently, liquid hydrogen, liquid deuterium and their mixtures were used as a moderating medium. The sources with the liquid hydrogen moderator offer the most specific effectiveness of cold neutron generation. But they are complicated in design, require special safety measures in the course of operation and are very expensive. In this connection, it is of undoubted interest to create a source which, although it yields the specific generation of cold neutrons comparable to the liquid hydrogen one, is safer in operation and simple in design. We assume such a source may be one which uses as a moderator liquid propane cooled to liquid nitrogen temperature.

  4. Alternative Fuels Data Center: Michigan Converts Vehicles to Propane,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduce OperatingPropane in OhioReducing

  5. Alternative Fuels Data Center: Propane Buses Shuttle Visitors in Maine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane Buses Shuttle

  6. Alternative Fuels Data Center: Propane Fueling Infrastructure Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane Buses

  7. Alternative Fuels Data Center: Propane Fueling Station Locations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane BusesStation

  8. Alternative Fuels Data Center: Propane Mowers Help National Park Cut

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane

  9. Alternative Fuels Data Center: Propane Powers Fleets Across the Nation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropaneOrleans

  10. Alternative Fuels Data Center: Propane School Buses Launched in Gloucester

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version Share

  11. Alternative Fuels Data Center: Propane Tank Overfill Safety Advisory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version

  12. Alternative Fuels Data Center: Propane Vans Keep Kansas City Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable VersionCompany

  13. Alternative Fuels Data Center: Renzenberger Inc Saves Money With Propane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane PrintableTools

  14. Final report of the Rhode Island State Energy Office on residential no. 2 heating oil and propane prices [SHOPP

    SciTech Connect (OSTI)

    McClanahan, Janice

    2001-04-01T23:59:59.000Z

    Summary report on residential No.2 heating oil and propane prepared under grant. Summarizes the monitoring and analysis of heating oil and propane prices from October 2000 through March 2001.

  15. Experimental Study on Geocell-Reinforced Flexible Pavements with Recycled Asphalt Pavement (RAP) Bases under Cyclic Loading

    E-Print Network [OSTI]

    Acharya, B. S.

    2011-12-31T23:59:59.000Z

    ABSTRACT The reprocessed old hot mix asphalt (HMA) concrete also called "Recycled Asphalt Pavement (RAP)", if used to build new roads or to maintain existing roads, would have several benefits, such as preservation of natural resources for future...

  16. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded Viscoelastic Model, Part-I: Development,

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded simulations, correspondence principle, finite-element method Abstract. Asphalt concrete pavements to climatic conditions are the major cause of such graded non-homogeneity. Current pavement analysis

  17. Microstructural Characterization of the Chemo-mechanical Behavior of Asphalt in Terms of Aging and Fatigue Performance Properties

    E-Print Network [OSTI]

    Allen, Robert Grover

    2013-03-27T23:59:59.000Z

    The study of asphalt chemo-mechanics requires a basic understanding of the physical properties and chemical composition of asphalt and how these properties are linked to changes in performance induced by chemical modifications. This work uniquely...

  18. Experimental studies of steam-propane and enriched gas injection for the Minas light crude oil 

    E-Print Network [OSTI]

    Yudishtira, Wan Dedi

    2003-01-01T23:59:59.000Z

    Experimental studies were carried out to compare the benefits of propane as an additive in steam injection and in lean gas injection to enhance production for the Minas light crude oil (34?API). The studies on steam-propane were specifically...

  19. Further experimental studies of steam-propane injection to enhance recovery of Morichal oil 

    E-Print Network [OSTI]

    Ferguson,Mark Anthony

    2000-01-01T23:59:59.000Z

    In 1998-1999, experimental research was conducted by Goite at Texas A&M University into steam-propane injection to enhance oil recovery from the Morichal field, Venezuela. Goite's results showed that, compared with steam injection alone, steam-propane...

  20. Experimental studies of steam-propane injection to enhance recovery of an intermediate crude oil 

    E-Print Network [OSTI]

    Tinss, Judicael Christopher

    2001-01-01T23:59:59.000Z

    In the past few years, research has been conducted at Texas A&M University on steam-propane injection to enhance oil recovery from the Morichal field, Venezuela, which contains 13.5 ?API gravity oil. Experimental results show that a 5:100 propane...

  1. Experimental studies of steam-propane injection to enhance recovery of an intermediate crude oil

    E-Print Network [OSTI]

    Tinss, Judicael Christopher

    2001-01-01T23:59:59.000Z

    In the past few years, research has been conducted at Texas A&M University on steam-propane injection to enhance oil recovery from the Morichal field, Venezuela, which contains 13.5 ?API gravity oil. Experimental results show that a 5:100 propane...

  2. Further experimental studies of steam-propane injection to enhance recovery of Morichal oil

    E-Print Network [OSTI]

    Ferguson,Mark Anthony

    2000-01-01T23:59:59.000Z

    In 1998-1999, experimental research was conducted by Goite at Texas A&M University into steam-propane injection to enhance oil recovery from the Morichal field, Venezuela. Goite's results showed that, compared with steam injection alone, steam-propane...

  3. Experimental studies of steam-propane and enriched gas injection for the Minas light crude oil

    E-Print Network [OSTI]

    Yudishtira, Wan Dedi

    2003-01-01T23:59:59.000Z

    Experimental studies were carried out to compare the benefits of propane as an additive in steam injection and in lean gas injection to enhance production for the Minas light crude oil (34?API). The studies on steam-propane were specifically...

  4. State heating oil and propane program, 1994--1995 heating season. Final technical report

    SciTech Connect (OSTI)

    NONE

    1995-05-09T23:59:59.000Z

    Propane prices and No. 2 fuel prices during the 1994-1995 heating season are tabulated for the state of Ohio. Nineteen companies were included in the telephone survey of propane prices, and twenty two companies for the fuel oil prices. A bar graph is also presented for average residential prices of No. 2 heating oil.

  5. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  6. Syngas Production from Propane Using Atmospheric Non-thermal Plasma

    E-Print Network [OSTI]

    Ouni, Fakhreddine; Cormier, Jean Marie; 10.1007/s11090-009-9166-2

    2009-01-01T23:59:59.000Z

    Propane steam reforming using a sliding discharge reactor was investigated under atmospheric pressure and low temperature (420 K). Non-thermal plasma steam reforming proceeded efficiently and hydrogen was formed as a main product (H2 concentration up to 50%). By-products (C2-hydrocarbons, methane, carbon dioxide) were measured with concentrations lower than 6%. The mean electrical power injected in the discharge is less than 2 kW. The process efficiency is described in terms of propane conversion rate, steam reforming and cracking selectivity, as well as by-products production. Chemical processes modelling based on classical thermodynamic equilibrium reactor is also proposed. Calculated data fit quiet well experimental results and indicate that the improvement of C3H8 conversion and then H2 production can be achieved by increasing the gas fraction through the discharge. By improving the reactor design, the non-thermal plasma has a potential for being an effective way for supplying hydrogen or synthesis gas.

  7. Microstructural Characterization of Material Properties and Damage in Asphalt Composites 

    E-Print Network [OSTI]

    Mohammad Khorasani, Sara

    2013-05-03T23:59:59.000Z

    by NPRP grant # 08-310-2-110 from the Qatar National Research Fund (a member of Qatar Foundation). The statements made herein are solely the responsibility of the authors. vi TABLE OF CONTENTS Page ABSTRACT... ........................................................................................................................ 17 3D Experimental Investigation of the Microstructure of Cement Pastes Using Synchrotron X-Ray Microtomography (?CT) .......................................................... 18 Dynamic Modulus Simulation of the Asphalt Concrete Using the X...

  8. Evaluation of Rexene polymers in hot mixed asphalt concrete

    E-Print Network [OSTI]

    Rodriguez, Mary Anne Reese

    1991-01-01T23:59:59.000Z

    -- polyethylene, polypropylene, ethylene-vinyl acetate (EVA) and ethylene-propylene rubbers -- show increased stability and stiffness modulus, increased resistance to permanent deformation and lower temperature susceptibility. Carpenter and VanDam (14... five asphalt additives: block copolymer rubber, SBR latex, EVA, polyethylene and carbon black. Mixture stability, stiffness, tensile strength and resistance to fatigue, thermal cracking, permanent deformation and moisture damage were tested. Three...

  9. A novel method of bitumen extraction from asphalt pavement

    SciTech Connect (OSTI)

    Houser, T.J. (Western Michigan Univ., Kalamazoo (United States))

    1990-07-01T23:59:59.000Z

    A new method of extracting bitumen from asphalt pavement mixtures has been developed which does not require chlorinated or aromatic compounds for solvents. The preferred solvent is cyclohexane (although cyclopentane may be used) at high temperatures and pressures. The new method requires equipment that is less costly than the centrifuge method currently used and takes less time than extractions with Bioact but more time than when chlorocompounds are used.

  10. Investigation of the flame speeds of propane/methanol gas mixtures

    SciTech Connect (OSTI)

    Foote, K.L.; Villareal, J.

    1985-05-02T23:59:59.000Z

    A series of tests was conducted in an acoustically tuned flame tube in order to determine the laminar burning velocities in air of various propane/methanol gas mixtures. The experimental method is explained in detail, along with the tabular results. A 90% propane, 10% methanol mixture is shown to have a maximum burning velocity of 40.8 cm/s. A 65% propane, 35% methanol mixture has a maximum velocity of 41.8 cm/s. These maximum flame speeds are shown to be about the same as that of pure propane by the same method. Gulder has found evidence that the presence of methanol in some hydrocarbon fuels may actually inhibit combustion, but we see no apparent modifications in the combustion of propane when mixed with methanol.

  11. Far-infrared laser vibration-rotation-tunneling spectroscopy of the propane-water compkx: Torsional dynamics of the hydrogen

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Far-infrared laser vibration-rotation-tunneling spectroscopy of the propane-water compkx: Torsional 1993) The far-infrared laservibration-rotation-tunneling (FIR-VRT) spectrumof the propane-water complex calculations. In the present paper and in its counterpart,13we present our results for the water-propane

  12. Non-oxidative reactions of propane on Zn/Na-ZSM5 Joseph A. Biscardi and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Non-oxidative reactions of propane on Zn/Na-ZSM5 Joseph A. Biscardi and Enrique Iglesia* Department rates during propane conversion at 773 K on Zn/Na-ZSM5 are about ten times higher than on Zn/H-ZSM5 catalysts with similar Zn content. The total rate of propane conversion is also higher on Zn/Na-ZSM5

  13. Modeling of the formation of short-chain acids in propane flames F. Battin-Leclerc , 1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Modeling of the formation of short-chain acids in propane flames F. Battin-Leclerc , 1 , A. Simulations of lean (equivalence ratios from 0.9 to 0.48) laminar premixed flames of propane stabilized in a combustion apparatus which can easily be modeled, a laminar premixed flame of propane at atmospheric pressure

  14. Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H-ZSM5

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H Co/H-ZSM5 catalyzes propane dehydrogenation and aromatization reactions. Initial product selectivities, product site-yields, and the 13C content and distribution in the products of 2-13C-propane show

  15. SURVEY OF THE LITERATURE ON THE CARBON-HYDROGEN SYSTEM

    E-Print Network [OSTI]

    Krakowski, R.A.

    2010-01-01T23:59:59.000Z

    one temperature and analyzed for propane for corr- osion-ratThe pyrolysis of ethane and propane at 2000 to 5000 0 K wasproduct was methane. Propane and The tempera- ethane

  16. INTRODUCTION The increase in energy costs has led to a significant rise in the cost of mixtures containing asphalt cement. This resulted

    E-Print Network [OSTI]

    Harms, Kyle E.

    containing asphalt cement. This resulted in a need to search for alternatives that reduce the cost of those mixed with low percentages (1 percent below standard HMA mixtures) of paving grade asphalt cement and lower percentages of asphalt cement binder and easier compaction efforts. Asphalt treated mixtures can

  17. Effect of pavement temperature on the macrotexture of a semidense asphalt surface

    E-Print Network [OSTI]

    Boyer, Edmond

    Effect of pavement temperature on the macrotexture of a semidense asphalt surface J. Luong, M the pavement temperature could change the texture surface of the pavement. The aim of this work is to analyze the influence of the surface temperature on the macrotexture of a semidense asphalt pavement located in an urban

  18. Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1

    E-Print Network [OSTI]

    Aydilek, Ahmet

    Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1 and Ahmet H. Aydilek2 2007 133:7 406 CE Database subject headings: Moisture; Asphalt concrete; Dynamics; Hydraulic and Magdalena 2002 ; however, limited research has been conducted in modeling dynamic flow in porous geomedia

  19. RESEARCH REPORT 987-9 ASPHALT OVERLAY DESIGN METHODS FOR RIGID

    E-Print Network [OSTI]

    Texas at Austin, University of

    by using a fractional factorial design. An analysis of variance (ANOVA) was performed to identifyRESEARCH REPORT 987-9 ASPHALT OVERLAY DESIGN METHODS FOR RIGID PAVEMENTS CONSIDERING RUTTING's Catalog No. 5. Report Date October 1998 4. Title and Subtitle ASPHALT OVERLAY DESIGN METHODS FOR RIGID

  20. Characterization of asphalt cements modified with crumbed rubber from discarded tires. Final report

    SciTech Connect (OSTI)

    Daly, W.H.; Negulescu, I.I.

    1994-11-01T23:59:59.000Z

    The potential legislative requirement for incorporation of scrap rubber into asphalt blends mandated a thorough evaluation of the influence of scrap rubber additives on the physical properties and aging characteristics of rubber/asphalt blends. Blends with up to 20 percent ground vulcanized rubber (both crumb and 200 mesh powder particles) from recycled tires were prepared with asphalt cements of various grades (AC5 - AC30) and evaluated using DMA. Blends produced from powdered rubber particles exhibited Newtonian behavior at high temperatures; similar behavior was not observed with crumb rubber blends. The mechanical properties of asphalt-rubber blends depend upon the concentration of rubber additives, the particle dimensions, and the chemical composition of the asphalt.

  1. Simulation of hydrogen and hydrogen-assisted propane ignition in Pt catalyzed microchannel

    SciTech Connect (OSTI)

    Seshadri, Vikram; Kaisare, Niket S. [Department of Chemical Engineering, Indian Institute of Technology - Madras, Chennai 600 036 (India)

    2010-11-15T23:59:59.000Z

    This paper deals with self-ignition of catalytic microburners from ambient cold-start conditions. First, reaction kinetics for hydrogen combustion is validated with experimental results from the literature, followed by validation of a simplified pseudo-2D microburner model. The model is then used to study the self-ignition behavior of lean hydrogen/air mixtures in a Platinum-catalyzed microburner. Hydrogen combustion on Pt is a very fast reaction. During cold start ignition, hydrogen conversion reaches 100% within the first few seconds and the reactor dynamics are governed by the ''thermal inertia'' of the microburner wall structure. The self-ignition property of hydrogen can be used to provide the energy required for propane ignition. Two different modes of hydrogen-assisted propane ignition are considered: co-feed mode, where the microburner inlet consists of premixed hydrogen/propane/air mixtures; and sequential feed mode, where the inlet feed is switched from hydrogen/air to propane/air mixtures after the microburner reaches propane ignition temperature. We show that hydrogen-assisted ignition is equivalent to selectively preheating the inlet section of the microburner. The time to reach steady state is lower at higher equivalence ratio, lower wall thermal conductivity, and higher inlet velocity for both the ignition modes. The ignition times and propane emissions are compared. Although the sequential feed mode requires slightly higher amount of hydrogen, the propane emissions are at least an order of magnitude lower than the other ignition modes. (author)

  2. An analysis of US propane markets, winter 1996-1997

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    In late summer 1996, in response to relatively low inventory levels and tight world oil markets, prices for crude oil, natural gas, and products derived from both began to increase rapidly ahead of the winter heating season. Various government and private sector forecasts indicated the potential for supply shortfalls and sharp price increases, especially in the event of unusually severe winter weather. Following a rapid runup in gasoline prices in the spring of 1996, public concerns were mounting about a possibly similar situation in heating fuels, with potentially more serious consequences. In response to these concerns, the Energy Information Administration (EIA) participated in numerous briefings and meetings with Executive Branch officials, Congressional committee members and staff, State Energy Offices, and consumers. EIA instituted a coordinated series of actions to closely monitor the situation and inform the public. This study constitutes one of those actions: an examination of propane supply, demand, and price developments and trends.

  3. Absorption Equilibrium and Kinetics for Ethylene-Ethane Separation with a Novel Solvent

    E-Print Network [OSTI]

    Eldridge, R. Bruce

    mixture of ethylene/ethane, distillation towers with an enormous number of trays are operated at high integration present in a modern ethylene unit, the energy expen- diture is enormous, making up 6.2% of the total yearly energy requirement of all distillation processes.2 Despite the high capital and energy

  4. Reactor simulation of benzene ethylation and ethane dehydrogenation catalyzed by ZSM-5: A multiscale approach

    E-Print Network [OSTI]

    Bell, Alexis

    Reactor simulation of benzene ethylation and ethane dehydrogenation catalyzed by ZSM-5 Dehydrogenation a b s t r a c t Rate expressions are vital for analysis, design and operation of chemical reactors used the extended continuum model in the design equation of a fixed bed reactor and simulated

  5. A study of the effects of limestone rock asphalt screenings on the structural properties of hot-mix asphaltic concrete made with siliceous materials

    E-Print Network [OSTI]

    Albritton, Oscar Willard

    1958-01-01T23:59:59.000Z

    Society for Testing Materials, Phila. , Pa. 15 PROCEDURE To limit the wide variations of aggregate grading, specifica- tions of the Texas Highway Department for a Type "D" Hot-Mix, Hot- Laid, Asphaltic Concrete were used as a guide in the design... Standards on Mineral Aggregates, Concrete, and Nonbituminous Highway Materials, American Society for Testing Materials, Phila, , Pa. Benson, Fred J, and Bh. Subbaraju, "Specific Gravity of Aggregates in Asphaltic Paving Mixtures, " Texas Engineering...

  6. Effect of temperature and pressure on the dynamics of nanoconfined propane

    SciTech Connect (OSTI)

    Gautam, Siddharth, E-mail: gautam.25@osu.edu; Liu, Tingting, E-mail: gautam.25@osu.edu; Welch, Susan; Cole, David [School of Earth Sciences, The Ohio State University, 275 Mendenhall Laboratory, 125 S Oval Mall, Columbus, OH 43210 (United States); Rother, Gernot [Geochemistry and Interfacial Science Group, Chemical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Jalarvo, Niina [Jülich Center for Neutron Sciences (JCNS-1), Forschungszentrum Jülich Outstation at Spallation Neutron Source(SNS), Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Mamontov, Eugene [Spallation Neutron Source (SNS), Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2014-04-24T23:59:59.000Z

    We report the effect of temperature and pressure on the dynamical properties of propane confined in nanoporous silica aerogel studied using quasielastic neutron scattering (QENS). Our results demonstrate that the effect of a change in the pressure dominates over the effect of temperature variation on the dynamics of propane nano-confined in silica aerogel. At low pressures, most of the propane molecules are strongly bound to the pore walls, only a small fraction is mobile. As the pressure is increased, the fraction of mobile molecules increases. A change in the mechanism of motion, from continuous diffusion at low pressures to jump diffusion at higher pressures has also been observed.

  7. High temperature performance of scrap tire rubber modified asphalt concrete

    SciTech Connect (OSTI)

    Coomarasamy, A. [Ministry of Transportation, Downsview, Ontario (Canada); Manolis, S.; Hesp, S. [Queen`s Univ., Kingston, Ontario (Canada)

    1996-12-31T23:59:59.000Z

    Wheel track rutting tests on mixes modified with 30 mesh, 80 mesh, and very fine colloidal crumb rubber particles show that a very significant improvement in performance occurs with a reduction in the rubber particle size. The SHRP binder test for rutting, which was originally developed for homogeneous systems only, does not predict the performance improvement for smaller rubber particles. If these new scrap rubber binder systems are to be used in pavements then rutting tests on the asphalt-aggregate mixture should be conducted in order to accurately predict high temperature performance.

  8. State heating oil and propane program: Final report. Survey of No.2 heating oil and propane prices at the retail level, October 1997 through March 1998

    SciTech Connect (OSTI)

    NONE

    1998-11-01T23:59:59.000Z

    The Energy Efficiency Division of the Vermont Department of Public Service (DPS) monitored the price and inventory of residential heating oil and propane during the 1997--98 heating season under a grant from the US Department of Energy`s Energy Information Administration (EIA). DPS staff collected data biweekly between October 5, 1997 and March 16, 1998 on the retail price of {number_sign}2 home heating oil and propane by telephone survey. Propane price quoted was based on the rate for a residential home heating customer using 1,000+ per year. The survey included a sample of fuel dealers selected by the EIA, plus additional dealers and fuels selected by the DPS. The EIA weighted, analyzed, and reported the data collected from their sample.

  9. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    Simulation study has shown oil production is accelerated when propane is used as an additive during steam injection. To better understand this phenomenon, distillation experiments were performed using San Ardo crude oil (12oAPI). For comparison...

  10. Experimental study of Morichal heavy oil recovery using combined steam and propane injection 

    E-Print Network [OSTI]

    Goite Marcano, Jose Gregorio

    1999-01-01T23:59:59.000Z

    with steam (for the purpose of increasing steam recovery efficiency) are being evaluated. An experimental study has been performed to investigate the effect of combined steam and propane injection on recovery of heavy oil from the Morichal field, Venezuela...

  11. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation 

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30T23:59:59.000Z

    Recent experimental and simulation studies -conducted at the Department of Petroleum Engineering at Texas A&M University - confirm oil production is accelerated when propane is used as an additive during steam injection. To better understand...

  12. Experimental study of Morichal heavy oil recovery using combined steam and propane injection

    E-Print Network [OSTI]

    Goite Marcano, Jose Gregorio

    1999-01-01T23:59:59.000Z

    with steam (for the purpose of increasing steam recovery efficiency) are being evaluated. An experimental study has been performed to investigate the effect of combined steam and propane injection on recovery of heavy oil from the Morichal field, Venezuela...

  13. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    U.S. Energy Information Administration (EIA) Indexed Site

    - W 73.5 See footnotes at end of table. A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present Energy Information Administration ...

  14. Analysis of tank deformation from fire induced ruptures and BLEVEs of 400 l propane tanks

    SciTech Connect (OSTI)

    Kielec, D.J.; Birk, A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Mechanical Engineering

    1996-12-01T23:59:59.000Z

    A series of fire tests were conducted to study the thermal rupture of propane tanks. The tests involved 400 liter ASME automotive propane tanks filled to 80% capacity with commercial propane. The tanks were brought to failure using torches and pool fires. the resulting thermal ruptures varied in severity from minor fissures, measuring a few centimeters in length, to catastrophic failures where the tank was flattened on the ground. The catastrophic failures would typically be called Boiling Liquid Expanding Vapour Explosions (BLEVE). The objective of this work was to develop a correlation between the failure severity and the tank condition at failure. The deformed propane tanks were measured in detail and the extent of deformation was quantified. The tank failure severity was found to be a complex function of a number of tank and lading properties at failure. this paper presents the measured data from the tanks and a step by step description of how the correlation was determined.

  15. Analysis of fire-induced ruptures of 400-L propane tanks

    SciTech Connect (OSTI)

    Kielec, D.J.; Birk, A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Mechanical Engineering

    1997-08-01T23:59:59.000Z

    A series of fire tests were conducted to study the thermal rupture of propane tanks. The tests involved 400-L ASME automotive propane tanks filled to 80% capacity with commercial propane. The tanks were brought to failure using torches and pool fires. The resulting thermal ruptures varied in severity from minor fissures, measuring a few centimeters in length, to catastrophic failures where the tank was flattened on the ground. The catastrophic failures would typically be called boiling liquid expanding vapor explosions (BLEVEs). The objective of this work was to develop a correlation between the failure severity and the tank condition at failure. The deformed propane tanks were measured in detail and the extent of deformation was quantified. The tank failure severity was found to be a complex function of a number of tank and lading properties at failure. This paper presents the measured data from the tanks and a step-by-step description of how the correlation was determined.

  16. Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty...

    Broader source: Energy.gov (indexed) [DOE]

    Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles 2011 Directions in Engine-Efficiency and Emissions Research (DEER) October 3-6, 2011 Presented By: Kent...

  17. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

  18. Etude cin\\'etique de CVD de pyrocarbone obtenu par pyrolyse de propane

    E-Print Network [OSTI]

    Ziegler-Devin, Isabelle; Marquaire, Paul-Marie

    2009-01-01T23:59:59.000Z

    High temeperature (900-1000\\degree C) low pressure (propane yields a pyrocarbon deposit, but also mainly hydrogen and hydrocarbons from methane to polyaromatics. 30 reaction products were exeperimentally quantified at different operating conditions. A detailed kinetic pyrolysis model (600 reactions) has been developed and validated based on the totality of experiments. This model includes a homogeneous model (describing the gas phase pyrolysis of propane) coupled with a heterogeneous model describing the pyrocarbon deposit.

  19. DOI: 10.1002/cbic.200500261 Direct Conversion of Ethane to

    E-Print Network [OSTI]

    Arnold, Frances H.

    by a variety of transition metal catalysts, but these sys- tems produce mixtures containing significant amounts dioxygen from the air as the oxidant, and produce little or no hazardous waste. Biological systems have as propane.[8­10] Communication between the heme and reduc- tase domains of BM-3 is substrate

  20. Heat transfer coefficients for propane (R-290), isobutane (R-600a), and 50/50 mixture of propane and isobutane

    SciTech Connect (OSTI)

    Mathur, G.D. [Zexel USA Corp., Decatur, IL (United States)

    1998-12-31T23:59:59.000Z

    Tube-side heat transfer coefficients for single-phase flow, evaporation, and condensation are presented for propane (R-290), isobutane (R-600a), and a 50/50 mixture (by weight) of propane and isobutane. Heat transfer coefficients have been presented for smooth tubes based on the standard correlations available in the literature for pure refrigerants. The correlations for evaporation and condensation have previously been verified for R-12 and other refrigerants. The correlations for evaporation and condensation have previously been verified for R-12 and other refrigerants. The mass flux of the refrigerant is varied over a wide range that is typically encountered in residential, commercial, and automotive applications. Evaporation temperatures of {minus}6.7 C (20 F) and 4.4 C (40 F) and condensation temperatures of 37.8 C (100 F) and 48.9 C (120 F) have been used for this investigation. The heat transfer coefficients for hydrocarbons (R-290, R-600a, R-290/R-600a) have been compared with R-12 and R-134a. The REFPROP computer program developed by the National Institute of Standards and Technology (NIST) has been used to determine the thermodynamic properties for R-290, R-600a, and R-290/R-600a. This study shows that the heat transfer coefficients for hydrocarbons are significantly higher than those for both R-12 and R-134a. For the range of refrigerant temperatures and mass flux studied, single-phase vapor heat transfer coefficients for hydrocarbons are greater by 234% to 259% in comparison to R-12 and are greater by 167% to 181% in comparison to R-134a. The single-phase liquid heat transfer coefficients for hydrocarbons are greater by 193% to 245% in comparison to R-12; and are greater by 155% to 198% in comparison to R-134a. Average evaporative heat transfer coefficients for hydrocarbons are greater by 194% to 238% in comparison to R-12 and are greater by 157% to 192% in comparison to R-134a. Finally, average condensing coefficients are greater by 220% to 233% in comparison to R-12 and are greater by 177% to 187% in comparison to R-134a. Tables 3 through 6 show a summary of the heat transfer coefficient enhancement of the hydrocarbons in comparison to both R-12 and R-134a.

  1. AIRBORNE, OPTICAL REMOTE SENSNG OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2005-04-15T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The scope of the work involved designing and developing an airborne, optical remote sensor capable of sensing methane and, if possible, ethane for the detection of natural gas pipeline leaks. Flight testing using a custom dual wavelength, high power fiber amplifier was initiated in February 2005. Ophir successfully demonstrated the airborne system, showing that it was capable of discerning small amounts of methane from a simulated pipeline leak. Leak rates as low as 150 standard cubic feet per hour (scf/h) were detected by the airborne sensor.

  2. Influence of fundamental material properties and air void structure on moisture damage of asphalt mixes 

    E-Print Network [OSTI]

    Arambula Mercado, Edith

    2009-05-15T23:59:59.000Z

    parameters were obtained using mechanical tests and surface energy measurements. The microstructure of asphalt mixes prepared in the laboratory having different air void structures was captured using X-ray CT, and image analysis techniques were used...

  3. Evaluation of healing in asphalt binders using dynamic shear rheometer and molecular modeling techniques 

    E-Print Network [OSTI]

    Bommavaram, Ramamohan Reddy

    2009-05-15T23:59:59.000Z

    A self-healing material has the inherent ability to partially reverse damage such as crack formation that might have occurred during its service. Significant evidence exists in the literature to indicate that asphalt binder is a self...

  4. A Continuum Coupled Moisture-mechanical Constitutive Model for Asphalt Concrete

    E-Print Network [OSTI]

    Shakiba, Maryam

    2013-12-09T23:59:59.000Z

    procedure and give insight into the various damage inducing mechanisms in asphalt concrete. In this dissertation, thermo-hygro-mechanical constitutive relationships are developed based on the principle of virtual power and laws of thermodynamics in order...

  5. Chip Seals for Asphalt Concrete Pavements: A Proposed Emulsion Residue Specification and Existing Pavement Texture Evaluation

    E-Print Network [OSTI]

    Hoyt, Denise

    2012-07-16T23:59:59.000Z

    Chip seals are a pavement surface treatment used for maintaining asphalt concrete pavements. National Cooperative Highway Research Program (NCHRP) Project 14-17 was performed to produce a national Chip Seal Manual which would consolidate the best...

  6. Development of superior asphalt recycling agency: Phase 1, Technical feasibility. Technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Glover, C.J.; Davison, R.R.; Lin, Moon-Sun; Chaffin, J.; Liu, Meng; Eckhardt, C.

    1996-04-01T23:59:59.000Z

    About every 12 years, asphalt roads must be reworked, and this is usually done by placing thick layers (hot-mix overlays) of new material on top of failed material, resulting in considerable waste of material and use of new asphalt binder. A good recycling agent is needed, not only to reduce the viscosity of the aged material but also to restore compatibility. Objective is to establish the technical feasibility (Phase I) of determining the specifications and operating parameters for producing high quality recycling agents which will allow most/all the old asphalt-based road material to be recycled. It is expected that supercritical fractionation can be used. The advanced road aging simulation procedure will be used to study aging of blends of old asphalt and recycling agents.

  7. A program to design asphalt concrete overlays to mitigate reflection cracking

    E-Print Network [OSTI]

    Satyanarayana Rao, Sindhu

    2002-01-01T23:59:59.000Z

    of the research are to understand the occurrence and behavior of reflection cracking and for devising ways of mitigating them and to put together an effective and complete package of computer programs to design asphalt concrete overlays. Another primary objective...

  8. Evaluation of healing in asphalt binders using dynamic shear rheometer and molecular modeling techniques

    E-Print Network [OSTI]

    Bommavaram, Ramamohan Reddy

    2009-05-15T23:59:59.000Z

    the parameters of characteristic healing function of asphalt binders. In the second part of this study, Molecular Modeling (MM) techniques were used to determine the interrelationship between molecular structure, surface free energy, self diffusivity, and other...

  9. Laboratory evaluation of crumb rubber asphalt concrete mixtures using the concepts of SMA mixtures 

    E-Print Network [OSTI]

    Rebala, Somasekhar Reddy

    1994-01-01T23:59:59.000Z

    Eight CRM asphalt concrete mixtures were evaluated using AAMAS characterization procedures: Four wet-process mixtures and four dry-process mixtures. These mixtures were compared to a conventional dense graded mixture. It was determined that CRM has...

  10. Automated Protocol for the Analysis of Dynamic Mechanical Analyzer Date from Fine Aggregate Asphalt Mixes 

    E-Print Network [OSTI]

    Cavalcanti De Sousa, Pedro

    2010-10-12T23:59:59.000Z

    Fatigue cracking and moisture damage are two important modes of distresses in asphalt pavements. Recently, the Dynamic Mechanical Analyzer (DMA) was used to characterize fatigue cracking and evaluate the effects of moisture ...

  11. Assessment of the risk of transporting propane by truck and train

    SciTech Connect (OSTI)

    Geffen, C.A.

    1980-03-01T23:59:59.000Z

    The risk of shipping propane is discussed and the risk assessment methodology is summarized. The risk assessment model has been constructed as a series of separate analysis steps to allow the risk to be readily reevaluated as additional data becomes available or as postulated system characteristics change. The transportation system and accident environment, the responses of the shipping system to forces in transportation accidents, and release sequences are evaluated to determine both the likelihood and possible consequences of a release. Supportive data and analyses are given in the appendices. The risk assessment results are related to the year 1985 to allow a comparison with other reports in this series. Based on the information presented, accidents involving tank truck shipments of propane will be expected to occur at a rate of 320 every year; accidents involving bobtails would be expected at a rate of 250 every year. Train accidents involving propane shipments would be expected to occur at a rate of about 60 every year. A release of any amount of material from propane trucks, under both normal transportation and transport accident conditions, is to be expected at a rate of about 110 per year. Releases from propane rail tank cars would occur about 40 times a year. However, only those releases that occur during a transportation accident or involve a major tank defect will include sufficient propane to present the potential for danger to the public. These significant releases can be expected at the lower rate of about fourteen events per year for truck transport and about one event every two years for rail tank car transport. The estimated number of public fatalities resulting from these significant releases in 1985 is fifteen. About eleven fatalities per year result from tank truck operation, and approximately half a death per year stems from the movement of propane in rail tank cars.

  12. The morphology of polymer modified asphalt and its relationship to rheology and durability

    E-Print Network [OSTI]

    Kraus, Zachary Rothman

    2008-10-10T23:59:59.000Z

    % % loglog * deg6010* deg6010 ?? , where d%A is the change in asphaltene in the asphalt (19). The other theory is that only the polar aromatics and napthene aromatics fluoresce when separated from the asphalt binder (16). Therefore as polar and napthene... aromatics change to asphaltenes with oxidative aging, the brightness would decrease. This brightness decrease would correspond to the increase in asphaltene with carbonyl area leading to a graph that looks like a chart for hardening susceptibility...

  13. An investigation of three problems concerning the analysis of airborne asphalt fumes

    E-Print Network [OSTI]

    Laird, Larry Teal

    1981-01-01T23:59:59.000Z

    AN INVESTIGATION OF THREE PROBLEMS CONCERNING THE ANALYSIS OF AIRBORNE ASPHALT FUMES A Thesis by LARRY TEAL LAIRD Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE May 1981 Major Subject: Industrial Hygiene AN INVESTIGATION OF THREE PROBLEMS CONCERNING THE ANALYSIS OF AIRBORNE ASPHALT FUMES A Thesis by LARRY T. LAIRD Approved as to style and content by: (Chairm of Committee) (Head of Department...

  14. Evaluation of oil shale bitumen as a pavement asphalt additive to reduce moisture damage susceptibility

    SciTech Connect (OSTI)

    Robertson, R.E.; Harnsberger, P.M.; Wolf, J.M.

    1991-01-01T23:59:59.000Z

    An unrefined shale bitumen was evaluated as an agent to reduce moisture damage susceptibility of asphalt aggregate mixtures. Some activity was observed but less than might have been expected based on the molecular weight and nitrogen content of the bitumen. The counter effects of free carboxylic acids, which are known to be variable in asphalt and which are also present in the unrefined bitumen, appear to diminish the activity of the bitumen to inhibit moisture damage. 5 refs., 1 tab.

  15. Evaluation of the effects of crumb rubber and SBR on rutting resistance of asphalt concrete

    SciTech Connect (OSTI)

    Shih, Chuang-Tsair; Tia, Mang; Ruth, B.E. [Univ. of Florida, Gainesville, FL (United States)

    1996-12-31T23:59:59.000Z

    This paper presents the results of a study to evaluate the effects of addition of crumb rubber (CR) and styrene-butadiene rubber (SBR) on the rutting resistance of asphalt concrete. These two additives were blended with an AC-20 and an AC-30 grade asphalt cements at different levels of concentrations. These modified and unmodified asphalt blends were tested at intermediate and high temperatures to evaluate their rutting resistance characteristics. They were also used to make Florida type S-I structural surface mixtures. These mixtures were made into Marshall-size specimens by using Gyratory Testing Machine (GTM) equipped with air-roller to compact and density to three compaction levels which simulate three different conditions in the pavement. The FDOT`s (Florida Department of Transportation) Loaded Wheel Tester was also used to evaluate the rutting resistance of these asphalt mixtures. The test results indicate that the modified asphalt mixtures show relatively better rutting resistance and shear resistance as compared with the unmodified asphalt mixtures.

  16. Lean and ultralean stretched propane-air counterflow flames

    SciTech Connect (OSTI)

    Cheng, Zhongxian; Pitz, Robert W. [Mechanical Engineering Department, Vanderbilt University, Box 1592, Station B, Nashville, TN 37235 (United States); Wehrmeyer, Joseph A. [Aerospace Testing Alliance, Building 1099, Avenue C, Arnold Air Force Base, TN 37389 (United States)

    2006-06-15T23:59:59.000Z

    Stretched laminar flame structures for a wide range of C{sub 3}H{sub 8}-air mixtures vs hot products are investigated by laser-based diagnostics and numerical simulation. The hot products are produced by a lean H{sub 2}-air premixed flame. The effect of stretch rate and equivalence ratio on four groups of C{sub 3}H{sub 8}-air flame structures is studied in detail by Raman scattering measurements and by numerical calculations of the major species concentration and temperature profiles. The equivalence ratio, f, is varied from a near-stoichiometric condition (f=0.86) to the sublean limit (f=0.44) and the stretch rate varies from 90 s{sup -1} to near extinction. For most of these C{sub 3}H{sub 8}-air lean mixtures, hot products are needed to maintain the flame. The significant feature of these flames is the relatively low flame temperatures (1200-1800 K). For this temperature range, the predicted C{sub 3}H{sub 8}-air flame structure is sensitive to the specific chemical kinetic mechanism. Two types of flame structures (a lean self-propagating flame and a lean diffusion-controlled flame) are obtained based on the combined effect of stretch and equivalence ratio. Three different mechanisms, the M5 mechanism, the Optimized mechanism, and the San Diego mechanism, are chosen for the numerical simulations. None of the propane chemical mechanisms give good agreement with the data over the entire range of flame conditions. (author)

  17. State of the practice: Design and construction of asphalt paving materials with crumb-rubber modifier. Final report

    SciTech Connect (OSTI)

    Heitzman, M.A.

    1992-05-01T23:59:59.000Z

    The document is a comprehensive overview of the terminology, processes, products, and applications of crumb rubber modifier (CRM) technology. The technology includes any use of scrap tire rubber in asphalt paving materials. In general, CRM technology can be divided into two categories--the wet process and the dry process. When CRM is incorporated into an asphalt paving material, it will modify the properties of the binder (asphalt rubber) and/or act as a rubber aggregate (rubber modified hot mix asphalt). The five concepts for using CRM discussed in the report are McDonald, PlusRide, generic dry, chunk rubber asphalt concrete, and continuous blending asphalt rubber. There are two principal unresolved engineering issues related to the use of CRM in asphalt paving materials. On the national level, the ability to recycle asphalt paving mixes containing CRM has not been demonstrated. At the State and local levels, these modified asphalt mixes must be field evaluated to establish expected levels of performance. The appendices provide guidelines for material specifications, mix design, and construction specifications. An experimental work plan for monitoring performance and a stack emission testing program are also included.

  18. No. 2 heating oil/propane program 1994--1995. Final report

    SciTech Connect (OSTI)

    McBrien, J.

    1995-05-01T23:59:59.000Z

    During the 1994--95 heating season, the Massachusetts Division of Energy Resources (DOER) participated in a joint data collection program between several state energy offices and the federal Department of Energy`s (DOE) Energy Information Administration (EIA). The purpose of the program was to collect and monitor retail and wholesale heating oil and propane prices and inventories from October 1994 through March 1995. This program augmented the existing Massachusetts data collection system and served several important functions. The information helped the federal and state governments respond to consumer, congressional and media inquiries regarding No. 2 oil and propane. The information also provided policy decision-makers with timely, accurate and consistent data to monitor current heating oil and propane markets and develop appropriate state responses when necessary. In addition, the communication network between states and the DOE was strengthened through this program. This final report begins with an overview of the unique events that had an impact on the petroleum markets prior to and during the reporting period. Next, the report summarizes the results from residential heating oil and propane price surveys conducted by DOER over the 1994--95 heating season. The report also incorporates the wholesale heating oil and propane prices and inventories collected by EIA and distributed to the states. Finally, the report outlines DOER`s use of the data.

  19. State Heating Oil & Propane Program. Final report 1997/98 heating season

    SciTech Connect (OSTI)

    Hunton, G.

    1998-06-01T23:59:59.000Z

    The following is a summary report of the New Hampshire Governor`s Office of Energy and Community Services (ECS) participation in the State Heating Oil and Propane Program (SHOPP) for the 1997/98 heating season. SHOPP is a cooperative effort, linking energy offices in East Coast and Midwest states, with the Department of Energy (DOE), Energy Information Administration (EIA) for the purpose of collecting retail price data for heating oil and propane. The program is funded by the participating state with a matching grant from DOE. SHOPP was initiated in response to congressional inquires into supply difficulties and price spikes of heating oil and propane associated with the winter of 1989/90. This is important to New Hampshire because heating oil controls over 55% of the residential heating market statewide. Propane controls 10% of the heating market statewide and is widely used for water heating and cooking in areas of the state where natural gas is not available. Lower installation cost, convenience, lower operating costs compared to electricity, and its perception as a clean heating fuel have all worked to increase the popularity of propane in New Hampshire and should continue to do so in the future. Any disruption in supply of these heating fuels to New Hampshire could cause prices to skyrocket and leave many residents in the cold.

  20. Development of statistical wet weather model to evaluate frictional properties at the pavement-tire interface on hot mix asphalt concrete

    E-Print Network [OSTI]

    Bedi, Harpreet

    2001-01-01T23:59:59.000Z

    Skid resistance on wet pavements is influenced by friction at the tire-pavement interface as well as overall hot mix asphalt (HMA) performance. It is important to control aggregate, asphalt, and mix properties to achieve desirable frictional...

  1. Application of Metagenomics for Identification of Novel Petroleum Hydrocarbon Degrading Enzymes in Natural Asphalts from the Rancho La Brea Tar Pits

    E-Print Network [OSTI]

    Baquiran, Jean-Paul Mendoza

    2010-01-01T23:59:59.000Z

    and the origin of heavy oil. Nature, 426, 344-352. HEITKAMP,natural asphalts and heavy oil compounds. A major questionmainly of asphalts and heavy oils, which have saturated into

  2. No. 2 heating oil/propane program. Final report, 1992/93

    SciTech Connect (OSTI)

    McBrien, J.

    1993-05-01T23:59:59.000Z

    During the 1992--93 heating season, the Massachusetts Division Energy Resources (DOER) participated in a joint data collection program between several state energy offices and the federal Department of Energy`s (DOE) Energy Information Administration (EIA). The purpose of the program was to collect and monitor retail and wholesale heating oil and propane prices and inventories from October, 1992 through March, 1993. This final report begins with an overview of the unique events which had an impact on the petroleum markets prior to and during the reporting period. Next, the report summarizes the results from residential heating oil and propane price surveys conducted by DOER over the 1992--93 heating season. The report also incorporates the wholesale heating oil and propane prices and inventories collected by the EIA and distributed to the states. Finally, the report outlines DOER`s use of the data.

  3. Clean Fuel Advanced Technology Public Education Campaign: Billboards According to the U.S. Department of Energy's July 2013 alternative fuel price report, the price of propane

    E-Print Network [OSTI]

    .S. Department of Energy's July 2013 alternative fuel price report, the price of propane (LPG) in North Carolina at least $1,000 in yearly fuel costs by driving on natural gas or propane. · According to the U

  4. Performance analysis of a series of hermetic reciprocating compressors working with R290 (propane) and R407C

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    Performance analysis of a series of hermetic reciprocating compressors working with R290 (propane Abstract In this paper, a series of compressors with different capacities and geometries working with propane as refrigerant are analyzed in terms of the compressor model developed by [E. Navarro, E. Granryd

  5. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Hodges, Don

    1952-01-01T23:59:59.000Z

    of thc Beg;voc cf kBSTBACT The propane-nitrogen system has been investigated in the gaseous phase at a temperature of 300 F. and at pressures up to 4/0 atmospheres. Compressibility curves for three mixtures of this system have been determined. A... the pressure corresponding to the "n " expansion ? th? the partial pressure of nitrogen the partial pressure oi' propane the total pressure of a gaseous system the universal gas constant (0. 08206 liter-atmosphere/ gram mole - oK) the absolute...

  6. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Dickson, Cecil Herman

    1955-01-01T23:59:59.000Z

    LIBRARY A A N O'iLLEOE OF 1EXAS THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEIN MIXTURES A Thesis Cecil Herman Dickson Submitted to the Graduate School of the Agricultural and Mechanical College of' Texas in partial... f'ulf'illment of the requirements for the de~ree of MASTER OF SCIENCE Ma]or GubjectI Chemistry May I&55 THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEN MIXTURES A Thesis Cecil Herman Dickson Approved as to style...

  7. The determination of compressibility factors of gaseous propane-nitrogen mixtures

    E-Print Network [OSTI]

    Dickson, Cecil Herman

    1955-01-01T23:59:59.000Z

    LIBRARY A A N O'iLLEOE OF 1EXAS THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEIN MIXTURES A Thesis Cecil Herman Dickson Submitted to the Graduate School of the Agricultural and Mechanical College of' Texas in partial... f'ulf'illment of the requirements for the de~ree of MASTER OF SCIENCE Ma]or GubjectI Chemistry May I&55 THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEN MIXTURES A Thesis Cecil Herman Dickson Approved as to style...

  8. The determination of compressibility factors of gaseous propane-nitrogen mixtures

    E-Print Network [OSTI]

    Hodges, Don

    1952-01-01T23:59:59.000Z

    of thc Beg;voc cf kBSTBACT The propane-nitrogen system has been investigated in the gaseous phase at a temperature of 300 F. and at pressures up to 4/0 atmospheres. Compressibility curves for three mixtures of this system have been determined. A... the pressure corresponding to the "n " expansion ? th? the partial pressure of nitrogen the partial pressure oi' propane the total pressure of a gaseous system the universal gas constant (0. 08206 liter-atmosphere/ gram mole - oK) the absolute...

  9. SUR LA POSSIBILIT D'UTILISATION D'UNE CHAMBRE A BULLES A PROPANE POUR L'TUDE DES RACTIONS NUCLAIRES

    E-Print Network [OSTI]

    Boyer, Edmond

    175 A. SUR LA POSSIBILITÉ D'UTILISATION D'UNE CHAMBRE A BULLES A PROPANE POUR L'ÉTUDE DES RÉACTIONS. - Mise au point et étude des caractéristiques du fonctionnement d'une chambre à bulles à propane de 6 135 MeV. Abstract. 2014 Adjustment and studies of some characteristics of a 6 litre propane bubble

  10. Single-Site Vanadyl Activation, Functionalization, and Reoxidation Reaction Mechanism for Propane Oxidative Dehydrogenation on the Cubic V4O10 Cluster

    E-Print Network [OSTI]

    Goddard III, William A.

    Single-Site Vanadyl Activation, Functionalization, and Reoxidation Reaction Mechanism for Propane of density functional theory) to examine the detailed mechanism for propane reacting with a V4O10 cluster to model the catalytic oxidative dehydrogenation (ODH) of propane on the V2O5(001) surface. We here report

  11. Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition

    E-Print Network [OSTI]

    Sklenak, Stepan

    Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative species Steamed Fe-zeolites Mössbauer spectroscopy UV­Vis FTIR H2-TPR N2O decomposition Propane oxidative of propane to propene with N2O. The evacuated non-steamed FeH-ZSM-5 contained high concentration of Brønsted

  12. Department of Energy and Mineral Engineering Spring Roller Design to Increase the Lifespan of Asphalt Compactor Wiper Blades

    E-Print Network [OSTI]

    Demirel, Melik C.

    the Lifespan of Asphalt Compactor Wiper Blades By: Thomas Krupa, Eric Resch, Phillip Yesenosky, John Marshall, Asset Kusmanov Overview Volvo CE's asphalt compactors have a polymer wiper blade that is used life. o The roller was tested five times as long as the wipers and never showed any change in diameter

  13. Development of superior asphalt recycling agents. Phase 1, Technical feasibility. Final technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J.; Chaffin, J.; Liu, M.; Madrid, R.

    1997-07-01T23:59:59.000Z

    After an introduction and a literature survey in Chap. 1, Chap. 2 describes the tasks, together with objectives and important results obtained for each task throughout the entire project. Chaps. 3 thru 7 detail work in developing a qualitative and quantitative knowledge of asphalt oxidation, composition dependence of asphalt properties, and guidelines for producing superior asphalt binders through composition control. They also detail the development of a kinetic model for asphalt oxidative aging and present an understanding of the composition dependence of asphalt oxidation as well as other performance-related properties. Chaps. 8 and 9 compare the aging performance of recycled blends produced using commercial recycling agents and industrial supercritical fractions as rejuvenating agents. Oxidative aging of the recycled blends were evaluated along with the performance of the recycled blends in terms of the strategic highway research program performance grading procedure. Chap. 10 summarizes the work completed in the areas of processing schemes development, projection updates, and scale-up and commercialization plans.

  14. Effects of carboxylic acids on the rheological properties of crumb rubber modified asphalt

    SciTech Connect (OSTI)

    Tauer, J.E.; Robertson, R.E. [Western Research Institute, Laramie, WY (United States)

    1996-12-31T23:59:59.000Z

    The Federal mandate of 1991-1995 on the use of scrap tires in Federal roadway construction sparked a major interest in gaining a fundamental understanding of the behavior of rubber in asphalt. This study is a systematic elucidation of what chemistry controls the final crumb rubber modified asphalt (CRMA) product quality. We discovered that the type and total acid content in the asphalt are the most influential chemical factors that determine the changes in the important roadway properties of shear modulus (G*) and loss angle ({delta}) of CRMA. Low acid (<0.005 m/L) asphalts were modified with three types of carboxylic acid and each made into CRMA using typical field mixing conditions of 1 hour at 175{degrees}C. Rheological measurements were then made at various storage times up to 192 hours following storage at both 156 and 200{degrees}C. We found the changes in CRMA theological properties correspond to the acid type spiked into the asphalt.

  15. Simulation studies of steam-propane injection for the Hamaca heavy oil field 

    E-Print Network [OSTI]

    Venturini, Gilberto Jose

    2002-01-01T23:59:59.000Z

    Simulation studies were performed to evaluate a novel technology, steam-propane injection, for the heavy Hamaca crude oil. The oil has a gravity of 9.3?API and a viscosity of 25,000 cp at 50?C. Two types of simulation studies were performed: a...

  16. Metallurgical failure analysis of a propane tank boiling liquid expanding vapor explosion (BLEVE).

    SciTech Connect (OSTI)

    Kilgo, Alice C.; Eckelmeyer, Kenneth Hall; Susan, Donald Francis

    2005-01-01T23:59:59.000Z

    A severe fire and explosion occurred at a propane storage yard in Truth or Consequences, N.M., when a truck ran into the pumping and plumbing system beneath a large propane tank. The storage tank emptied when the liquid-phase excess flow valve tore out of the tank. The ensuing fire engulfed several propane delivery trucks, causing one of them to explode. A series of elevated-temperature stress-rupture tears developed along the top of a 9800 L (2600 gal) truck-mounted tank as it was heated by the fire. Unstable fracture then occurred suddenly along the length of the tank and around both end caps, along the girth welds connecting the end caps to the center portion of the tank. The remaining contents of the tank were suddenly released, aerosolized, and combusted, creating a powerful boiling liquid expanding vapor explosion (BLEVE). Based on metallography of the tank pieces, the approximate tank temperature at the onset of the BLEVE was determined. Metallurgical analysis of the ruptured tank also permitted several hypotheses regarding BLEVE mechanisms to be evaluated. Suggestions are made for additional work that could provide improved predictive capabilities regarding BLEVEs and for methods to decrease the susceptibility of propane tanks to BLEVEs.

  17. Simulation studies of steam-propane injection for the Hamaca heavy oil field

    E-Print Network [OSTI]

    Venturini, Gilberto Jose

    2002-01-01T23:59:59.000Z

    Simulation studies were performed to evaluate a novel technology, steam-propane injection, for the heavy Hamaca crude oil. The oil has a gravity of 9.3?API and a viscosity of 25,000 cp at 50?C. Two types of simulation studies were performed: a...

  18. Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef* and J. M applications (1, 2) . Synthesis gas or syngas (mixture of hydrogen and carbon monoxide) are used as a major. The conventional reformers allowing syngas production are based on steam reforming of hydrocarbons (3) following

  19. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-11-12T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  20. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPLINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2004-05-12T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  1. Viscoroute 2.0: a tool for the simulation of moving load effects on asphalt pavement

    E-Print Network [OSTI]

    Chabot, Armelle; Deloffre, Lydie; Duhamel, Denis

    2010-01-01T23:59:59.000Z

    As shown by strains measured on full scale experimental aircraft structures, traffic of slow-moving multiple loads leads to asymmetric transverse strains that can be higher than longitudinal strains at the bottom of asphalt pavement layers. To analyze this effect, a model and a software called ViscoRoute have been developed. In these tools, the structure is represented by a multilayered half-space, the thermo-viscoelastic behaviour of asphalt layers is accounted by the Huet-Sayegh rheological law and loads are assumed to move at constant speed. First, the paper presents a comparison of results obtained with ViscoRoute to results stemming from the specialized literature. For thick asphalt pavement and several configurations of moving loads, other ViscoRoute simulations confirm that it is necessary to incorporate viscoelastic effects in the modelling to well predict the pavement behaviour and to anticipate possible damages in the structure.

  2. Asphalt emulsion radon barrier systems for uranium mill tailings: an overview of the technology

    SciTech Connect (OSTI)

    Baker, E.G.; Hartley, J.N.; Freeman, H.D.; Gates, T.E.; Nelson, D.A.; Dunning, R.L.

    1984-03-01T23:59:59.000Z

    Pacific Northwest Laboratory (PNL), under contract to the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) office, has developed an asphalt emulsion cover system to reduce the release of radon from uranium mill tailings. The system has been field tested at Grand Junction, Colorado. Results from laboratory and field tests indicate that this system is effective in reducing radon release to near-background levels (<2.5 pCi m/sup -2/s/sup -1/) and has the properties required for long-term effectiveness and stability. Engineering specifications have been developed, and analysis indicates that asphalt emulsion covers are cost-competitive with other cover systems. This report summarizes the technology for asphalt emulsion radon barrier systems. 59 references, 45 figures, 36 tables.

  3. Application of pyrolized carbon black from scrap tires in asphalt pavement design and construction

    SciTech Connect (OSTI)

    Park, T.; Coree, B.J. [Indiana Department of Transportation, West Lafayette, IN (United States). Division of Research; Lovell, C.W. [Purdue Univ., West Lafayette, IN (United States). School of Civil Engineering

    1995-12-31T23:59:59.000Z

    According to EPA reports (1991) of the over 242 million waste generated each year in the United State, 5% are exported, 6% recycled, 11% incinerated, and 78% are landfilled, stockpiled, or illegally dumped. A variety of uses for these tires are being studied. Among these is pyrolysis which produces 5 5% of oil, 25% of carbon black, 9% of steel, 5% of fiber and 6% of gas. Pyrolized carbon black contains 9 % of ash, 4% of sulfur, 12% of butadine copolymer and 75% of carbon black. The objective of this research is to investigate the viability of using PCB as an additive in hot mix asphalt. The use of PCB in asphalt pavement is expected not only to improve the performance of conventional asphalt, but also to provide a means for the mass disposal of waste fires.

  4. Recycled tire rubber and other waste materials in asphalt mixtures. Transportation research record

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The papers in this volume, dealing with various facets of recycled tire rubber and other waste materials in asphalt mixtures, should be of interest to state and local construction, design, materials, and research engineers as well as contractors and material producers. In the first papers, Rebala and Estakhri, Malpass and Khosla, and Baker and Connolly describe research related to crumb rubber modified mixtures that was done for the Texas, North Carolina, and New Jersey State Departments of Transportation. Ali et al. report on their research in Canada to determine the feasibility of sing reclaimed roofing materials in hot mix asphalt pavement. Emery discusses the evaluation of 11 Ontario rubber modified demonstration projects in terms of pavement performance, environmental impacts, and recyclability. In the last paper, Fwa and Aziz report on their work in Singapore related to the use of incinerator residue in asphalt mixtures.

  5. Studies of asphalt air blowing and development of a new short-term aging technique

    E-Print Network [OSTI]

    Vassiliev, Nicolai

    2001-01-01T23:59:59.000Z

    , Table m-2. Low temperature hardening properi. ies of air blown asphalt fractions and blends. Table III-3. Parent asphalt HS, oxidation rate, and HR . Table IV-1. Estimated time required to achieve same degrcc of aging as RTFOT for Exxon AC-10 films... of varying I. hickness . 70 Table IV-2 Effect of air blowing conditions for Exxon AC- I 0, 325 'F, 70 min. 70 Table IV-3. Condensed volatiles and RTFOT mass change . 80 Table IV-4. Reproducibility analysis. LIST OF FIGURES P ige Figure I-l. Thin film...

  6. A Minimum Free Energy Reaction Path for the E2 Reaction between Fluoro Ethane and a Fluoride Ion

    E-Print Network [OSTI]

    Nielsen, Steven O.

    A Minimum Free Energy Reaction Path for the E2 Reaction between Fluoro Ethane and a Fluoride Ion, such as the mechanism and the free-energy profile, remains an important challenge not only for enzyme catalysis1 of the reaction free-energy profile is very cumbersome with constrained molecular dynamics (MD) and umbrella

  7. Ethan Frome

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name: Email: Terminal2,7,7,of2014

  8. The oxidative dehydrogenation of ethane with nitrous oxide by molybdenum oxide supported on silica gel

    E-Print Network [OSTI]

    Yang, Tsong-Jen

    1979-01-01T23:59:59.000Z

    pmole/min/g Ho for the formation of ethylene corresponds to a conversion of 0. 6% based on ethane. The steady state rates were low at temperatures less than 350 C, wnereas tne selectivity to ethylene (defined as mole ethylene/mole ethylene + 1/2 mole.... The rates of formation for C284 ( ~ ) and CO& (& ) as a function of temperature. Flow rates of gases: C~H8, 8. 4 ml/min; N~Q, 48. 8 ml/min. 15 g 12 0 0) c g 0 E ~6 300 325 350 375 400 425 450 T ('~) TABLE 1 Reactions of C 2H6 with N20 at Different...

  9. Influence of coarse aggregate size, shape and surface texture on rutting of hot mix asphalt concrete

    E-Print Network [OSTI]

    Yeggoni, Mohan

    1993-01-01T23:59:59.000Z

    increased Hveem Stability, Marshall Stability and resistance to creep of hot mix asphalt concrete. The resilient modulus of the specimens was also enhanced by the increase in the amount of crushed aggregate in the mix at high temperatures (115'F). Fractal...

  10. The State of the Practice and Common Pitfalls for Porous Asphalt for

    E-Print Network [OSTI]

    of stormwater treatment systems · To provide resources to stormwater communities currently involved in design)-131 Porous Asphalt Pavements (2008) NAPA IS-115 Open-Graded Friction Courses (2002) 3 #12;Overview 1. State of the Practice 2. Water Quality Performance 3. Hydraulic Performance 4. Cold Climate

  11. Project Information Form Project Title Evaluation of the Combined Effect of Recycled Asphalt Pavement (RAP),

    E-Print Network [OSTI]

    California at Davis, University of

    Pavement (RAP), Recycled Asphalt Shingles (RAS), and Different Virgin Binder Sources on Performance of Research Project As virgin material sources become increasingly scarce, and the volume of pavement material for pavement construction. The California Department of Transportation (Caltrans) has recently increased

  12. Mixture design and performance prediction of rubber-modified asphalt in Ohio. Final report

    SciTech Connect (OSTI)

    Liang, R.Y.

    1997-08-01T23:59:59.000Z

    Appropriate disposal of scrap tires has been a major environmental concern over the years, mainly due to potential fire and health hazards associated with uncontrolled stockpiling. Primarily driven by this environmental concern, the Intermodal Surface Transportation Efficiency Act (ISTEA) of 1991 has required each State to begin incorporating scrap tire rubber into its asphalt paving materials. Although in the revision of the original ISTEA, the mandate has been eliminated, there remains a language of encouraging the use of crumb rubbers in asphalt paving materials. Ohio Department of Transportation (ODOT) desires to develop the mix design procedure, construction practice, and performance specifications for crumb rubber modified asphalt paving materials. This research was conducted to develop the needed design and construction guidance for meeting the ODOT anticipated needs. Specifically, the objectives of this research encompass the following scope: (1) investigation of the rheological properties of asphalt-rubber binder to determine optimum content of crumb rubber, (2) development of optimum mix design for various applications, including both wet and dry mix processes, (3) characterization of mechanical properties of recommended paving mixtures, including resilient modulus, fatigue cracking behavior, low-temperature thermal cracking resistance, water sensitivity test, incremental creep test and loaded wheel track test, and (4) comparison of performance of selected paving mixes.

  13. FIELD PERFORMANCE AND LABORATORY EVALUATION OF WARM MIX ASPHALT PRODUCED WITH RUBBERIZED BITUMEN

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    FIELD PERFORMANCE AND LABORATORY EVALUATION OF WARM MIX ASPHALT PRODUCED WITH RUBBERIZED BITUMEN of rubberized bitumen has been spread out mainly due to environmental aspects, but high mixing and compaction temperatures are necessary due to the higher viscosity of this bitumen. A WMA mixture (using a surfactant

  14. Creep Compliance Analysis Technique for the Flattened Indirect Tension Test of Asphalt Concrete

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Creep Compliance Analysis Technique for the Flattened Indirect Tension Test of Asphalt Concrete: ­ Cored Sample (Cylindrical) Indirect tensile testing (IDT) (Strength/Creep) ­ AASHTO T-322 Damage under and Flattened IDT · 1000-sec creep tests on three replicates · 0, -10, and -20 deg. C · Displacement

  15. Mirzahosseini et. al. ANN-Based Prediction Model for Rutting Propensity of Asphalt Mixtures1

    E-Print Network [OSTI]

    Fernandez, Thomas

    in a repeated load permanent deformation test.21 Dynamic creep test is one of the best tools for assessing of load cycles is the most23 important output of the dynamic creep test. This curve includes primary based on volumetric proportioning of the asphalt mixture. This method does16 not include any direct test

  16. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-05-13T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This six-month technical report summarizes the progress for each of the proposed tasks, discusses project concerns, and outlines near-term goals. Ophir has completed a data survey of two major natural gas pipeline companies on the design requirements for an airborne, optical remote sensor. The results of this survey are disclosed in this report. A substantial amount of time was spent on modeling the expected optical signal at the receiver at different absorption wavelengths, and determining the impact of noise sources such as solar background, signal shot noise, and electronic noise on methane and ethane gas detection. Based upon the signal to noise modeling and industry input, Ophir finalized the design requirements for the airborne sensor, and released the critical sensor light source design requirements to qualified vendors. Responses from the vendors indicated that the light source was not commercially available, and will require a research and development effort to produce. Three vendors have responded positively with proposed design solutions. Ophir has decided to conduct short path optical laboratory experiments to verify the existence of methane and absorption at the specified wavelength, prior to proceeding with the light source selection. Techniques to eliminate common mode noise were also evaluated during the laboratory tests. Finally, Ophir has included a summary of the potential concerns for project success and has established future goals.

  17. Thermophysical property predictions of propane, propylene and their mixtures by Benedict-Webb-Rubin type equations of state 

    E-Print Network [OSTI]

    Bengani, Pramod Kumar

    1990-01-01T23:59:59.000Z

    THERMOPHYSICAL PROPERTY PREDICTIONS OF PROPANE, PROPYLENE AND THEIR MIXTURES BY BENEDICT-WEBB-RUBIN TYPE EQUATIONS OF STATE A Thesis by PRAMOD KUMAR BENGANI Submitted to the Office of Graduate Studies of Texas A & M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1990 Major Subject: Chemical Engineering THERMOPHYSICAL PROPERTY PREDICTIONS OF PROPANE, PROPYLENE AND THEIR MIXTURES BY BENEDICT-WEBB-RUBIN TYPE EQUATIONS OF STATE A Thesis...

  18. SCADA system aids BGE`s Notch Cliff propane-air facility

    SciTech Connect (OSTI)

    Miller, B.A. [Baltimore Gas and Electric Co., MD (United States)

    1997-02-01T23:59:59.000Z

    SCADA systems in the natural gas industry are commonly associated with distribution networks and transmission pipelines. There is however, another application for SCADA technology that is increasingly being utilized in the industry. By implementing automation technology and process control concepts more typically associated with industrial and petrochemical process facilities, Baltimore Gas and Electric Co. (BGE) has significantly improved the efficiency, performance, and safety at its Notch Cliff Propane-Air peak shaving facility. These results have contributed to BGE`s ongoing efforts to effectively operate in the competitive energy marketplace. When the Notch Cliff plant was built in the early 1960s, it was a state-of-the-art facility. The plant blends propane vapor and compressed air to create a supplement to the natural gas supply during peak demand periods.

  19. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30T23:59:59.000Z

    from Instituto Mexicano del Petróleo (IMP), Dr. Fernando Rodriguez de la Garza, and Dr. Jose Luis Sanchez Bujanos from Petróleos Mexicanos (PEMEX), and Lawyer Rolando Rueda de Leon from Diario de Mexico, for their help and valuable advice. I would...-, and Steam with Propane-Distillation. (May 2004) Marco Antonio Ramírez-Garnica, B.S., Instituto Politécnico Nacional; M.S., Instituto Politécnico Nacional, México Chair of Advisory Committee: Dr. Daulat D. Mamora Recent experimental and simulation...

  20. Michigan residential heating oil and propane price survey: 1995--1996 heating season. Final report

    SciTech Connect (OSTI)

    Moriarty, C.

    1996-05-01T23:59:59.000Z

    This report summarizes the results of a survey of residential No. 2 distillate fuel (home heating oil) and liquefied petroleum gas (propane) prices over the 1995--1996 heating season in Michigan. The Michigan`s Public Service Commission (MPSC) conducted the survey under a cooperative agreement with the US Department of Energy`s (DOE) Energy Information Administration (EIA). This survey was funded in part by a grant from the DOE. From October 1995 through March 1996, the MPSC surveyed participating distributors by telephone for current residential retail home heating oil and propane prices. The MPSC transmitted the data via a computer modem to the EIA using the Petroleum Electronic Data Reporting Option (PEDRO). Survey results were published in aggregate on the MPSC World Wide Web site at http://ermisweb.state.mi.us/shopp. The page was updated with both residential and wholesale prices immediately following the transmission of the data to the EIA. The EIA constructed the survey using a sample of Michigan home heating oil and propane retailers. The sample accounts for different sales volumes, geographic location, and sources of primary supply.

  1. Asphalt and Asphaltic Concrete

    E-Print Network [OSTI]

    Young, A. R.

    1914-05-01T23:59:59.000Z

    , and combined curb and gutter furnished and set, the rate for resetting old curbing; the rate per cubic yard for extra concrete, if any is used; the price per cubic yard for broken stone or gravel; the rate per square yard for paving and for relaying old...- tified and given access to the same at least ten days be- fore it is required for use, and any work in which re- jected cement was used will be rejected altogether. 5. The cement shall be packed in strong bags having printed on the outside the brand...

  2. A comparison of the fracture properties of conventional and polymer-modified two-layer asphalt concrete overlay systems 

    E-Print Network [OSTI]

    Reddy, Praveena Gutha

    1996-01-01T23:59:59.000Z

    The problem of reflection cracking through the conventional asphalt concrete overlays has increased the need to find new materials which could resist cracking or fracture more effectively. It is for this reason that polymers ...

  3. Comparison of fatigue analysis approaches for predicting fatigue lives of hot-mix asphalt concrete (HMAC) mixtures

    E-Print Network [OSTI]

    Walubita, Lubinda F.

    2006-08-16T23:59:59.000Z

    Hot-mix asphalt concrete (HMAC) mixture fatigue characterization constitutes a fundamental component of HMAC pavement structural design and analysis to ensure adequate field fatigue performance. HMAC is a heterogeneous complex composite material...

  4. Fatigue resistance of hot-mix asphalt concrete (HMAC) mixtures using the calibrated mechanistic with surface energy (CMSE) measurements approach

    E-Print Network [OSTI]

    Ofori-Abebresse, Edward Kwame

    2006-10-30T23:59:59.000Z

    Fatigue cracking is one of the fundamental distresses that occur in the life of a Hot Mix Asphalt Concrete (HMAC) pavement. This load induced distress leads to structural collapse of the entire pavement ultimately and can only be remedied...

  5. Fatigue resistance of hot-mix asphalt concrete (HMAC) mixtures using the calibrated mechanistic with surface energy (CMSE) measurements approach 

    E-Print Network [OSTI]

    Ofori-Abebresse, Edward Kwame

    2006-10-30T23:59:59.000Z

    Fatigue cracking is one of the fundamental distresses that occur in the life of a Hot Mix Asphalt Concrete (HMAC) pavement. This load induced distress leads to structural collapse of the entire pavement ultimately and can ...

  6. A unified method for the analysis of nonlinear viscoelasticity and fatigue cracking of asphalt mixtures using the dynamic mechanical analyzer

    E-Print Network [OSTI]

    Castelo Branco, Veronica Teixeira Franco

    2009-05-15T23:59:59.000Z

    A UNIFIED METHOD FOR THE ANALYSIS OF NONLINEAR VISCOELASTICITY AND FATIGUE CRACKING OF ASPHALT MIXTURES USING THE DYNAMIC MECHANICAL ANALYZER A Dissertation by VERONICA TEIXEIRA FRANCO CASTELO BRANCO Submitted to the Office... VISCOELASTICITY AND FATIGUE CRACKING OF ASPHALT MIXTURES USING THE DYNAMIC MECHANICAL ANALYZER A Dissertation by VERONICA TEIXEIRA FRANCO CASTELO BRANCO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  7. A study of substitution solvents in asphalt fume extraction and the effects of heating duration and temperature 

    E-Print Network [OSTI]

    Curry, Noel Thomas

    1981-01-01T23:59:59.000Z

    may be used as substitute solvents for the solvent extraction analytical method for asphalt furres proposed by NlnSH and currently in use by OSHA. Benzene is known to orovide IC0% effic- 1 iency in asphalt fume extraction. The results..., rather than the solvents' effic- iency loss, was responsible for the differences. The importance of the data lies in the fact that the other two test solvents exhibited a consiatency equal to that of benzene. 'Ahile the exact coefficient of any...

  8. "Nanocrystal bilayer for tandem catalysis"

    E-Print Network [OSTI]

    Yamada, Yusuke

    2012-01-01T23:59:59.000Z

    Hydrogenolysis of Ethane, Propane, n-Butane and iso-Butanethe Hydroformylation of Propane over Silica-supported Groupproduct and small amount of propane, which is likely to be

  9. Detecting Volatile Organic Compounds from Orbit J. J. Harrison & P. F. Bernath

    E-Print Network [OSTI]

    ethane retrievals are currently being optimised by updating and improving the microwindow set. Propane cross sections have also been determined from spectra recorded at the MSF. Propane 215 K Propane Q

  10. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    of NO and N02 in a Turbulent Propane/Air Di fusion Flame,"Fuel Methanol Ethanol Ethane Propane i so Octane n - Cetanestage of the secondary Propane, at A spark air line contains

  11. An analysis of some properties of paving asphalts in Texas as they relate to pavement performance

    E-Print Network [OSTI]

    DuBose, Emmett Haygood

    1980-01-01T23:59:59.000Z

    51 73 93 115 115 DISTRESS AND CRACKING FACTORS THE PAVEMENT PERFORMANCE SYSTEM 5 CONCLUSIONS AND RECOMMENDATIONS CONCLUSIONS RECOMMENDATIONS REFERENCES . APPENDIX A: RAW DATA APPENDIX B: PAVEMENT PERFORMANCE VS. TIME CURVES APPENDIX C... harden1ng model. It had been shown in earlier research that excessive asphalt1c concrete binder hardening was a detrimental factor influencing certain types of pavement distress such as thermal cracking, raveling, fatigue cracking, and reflective crack...

  12. Thickness estimation of subsurface layers in asphalt pavement using monstatic ground penetrating radar

    E-Print Network [OSTI]

    Lau, Chun Lok

    1991-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE December 1991 Major Subject: Electrical Engineering THICKNESS ESTIMATION OF SUBSURFACE LAYERS IN ASPHALT PAVEMENT USING MONSTATIC GROUND PENETRATING RADAR A Thesis CHUN LOK LAU Approved as to style and content by... ACKNOWLEDGEMENTS. LIST OF FIGURES. . CHAPTER I INTRODUCTION. 1. 1 Importance of pavement profile data. 1. 2 Principle of Ground Penetrating Radar (GPR) . . . 1. 3 Subsurface layer thickness measurement method. . . . . . II GPR ANTENNA AND SYSTEM CALIBRATION...

  13. Oxidative reactions and their impact on the properties of asphalt as a pavement binder

    E-Print Network [OSTI]

    Lau, Chee Keung

    1991-01-01T23:59:59.000Z

    mechanical spectrometer was found to increase with aging time. Correlation was shown to exist between the limiting complex viscosity and the carbonyl area as determined by infrared analysis. The correlation was unique for each asphalt and was independent... of aging temperature. The carbonyl area growth rate was a strong function of the aging temperature and the temperature dependence of the rate constant followed the Arrhenius relation within the temperature range tested. The results led...

  14. Series 50 propane-fueled Nova bus: Engine development, installation, and field trials

    SciTech Connect (OSTI)

    Smith, B.

    1999-01-01T23:59:59.000Z

    The report describes a project to develop the Detroit Diesel series 50 liquefied propane gas (LPG) heavy-duty engine and to conduct demonstrations of LPG-fuelled buses at selected sites (Halifax Regional Municipality and three sites in the United States). The project included five main elements: Engine development and certification, chassis re-engineering and engine installation, field demonstration, LPG fuel testing, and LPG fuel variability testing. Lessons learned with regard to engine design and other issues are discussed, and recommendations are made for further development and testing.

  15. U.S. Natural Gas Supplemental Gas - Propane Air (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan Feb MarDecade Year-0 Year-1 Year-2 Year-3OtherPropane

  16. Alternative Fuels Data Center: Michigan School Buses Get Rolling on Propane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduce OperatingPropane inMichigan School

  17. Alternative Fuels Data Center: Propane Rolls on as Reliable Fleet Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulaseFuels andConversionsAssumptionsBenefitsPropane

  18. Viscosity, relaxation time, and dynamics within a model asphalt of larger molecules

    SciTech Connect (OSTI)

    Li, Derek D.; Greenfield, Michael L., E-mail: greenfield@egr.uri.edu [Department of Chemical Engineering, University of Rhode Island, Kingston, Rhode Island 02881 (United States)

    2014-01-21T23:59:59.000Z

    The dynamics properties of a new “next generation” model asphalt system that represents SHRP AAA-1 asphalt using larger molecules than past models is studied using molecular simulation. The system contains 72 molecules distributed over 12 molecule types that range from nonpolar branched alkanes to polar resins and asphaltenes. Molecular weights range from 290 to 890 g/mol. All-atom molecular dynamics simulations conducted at six temperatures from 298.15 to 533.15 K provide a wealth of correlation data. The modified Kohlrausch-Williams-Watts equation was regressed to reorientation time correlation functions and extrapolated to calculate average rotational relaxation times for individual molecules. The rotational relaxation rate of molecules decreased significantly with increasing size and decreasing temperature. Translational self-diffusion coefficients followed an Arrhenius dependence. Similar activation energies of ?42 kJ/mol were found for all 12 molecules in the model system, while diffusion prefactors spanned an order of magnitude. Viscosities calculated directly at 533.15 K and estimated at lower temperatures using the Debye-Stokes-Einstein relationship were consistent with experimental data for asphalts. The product of diffusion coefficient and rotational relaxation time showed only small changes with temperature above 358.15 K, indicating rotation and translation that couple self-consistently with viscosity. At lower temperatures, rotation slowed more than diffusion.

  19. Winter fuels report, week ending February 12, 1993. [Contains Glossary and feature article on Midwest Propane Markets

    SciTech Connect (OSTI)

    Not Available

    1993-02-18T23:59:59.000Z

    The Winter Fuels Report is intended to provide concise, timely information to the industry, the press, policymakers, consumers, analysts, and State and local governments on the following topics: Distillate fuel oil net production, imports and stocks on a US level and for all Petroleum Administration for Defense Districts (PADD) and product supplied on a US level; propane net production, imports and stocks on a US level and for PADD's 1, II, and III; natural gas supply and disposition and underground storage for the US and consumption for all PADD'S; as well as selected National average prices. Residential and wholesale pricing data for heating oil and propane for those States participating in the joint Energy Information Administration (EIA)/State Heating Oil and Propane Program; selected cities; and a 6--10 Day, 30-Day, and 90-Day outlook for temperature and precipitation and US total heating degree-days by city.

  20. Combustion: What is the Lower Heating Value (LHV) of Propane? Before we start: how reasonable is the use of the LHV? What is the dewpoint of the reaction products?

    E-Print Network [OSTI]

    Combustion: What is the Lower Heating Value (LHV) of Propane? Before we start: how reasonable temperature we can achieve with a propane-and-air blowtorch? We repeat this calculation for several different

  1. Analysis of ignition behavior in a turbocharged direct injection dual fuel engine using propane and methane as primary fuels

    SciTech Connect (OSTI)

    Polk, A. C.; Gibson, C. M.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-10-05T23:59:59.000Z

    This paper presents experimental analyses of the ignition delay (ID) behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant speed (1800 rev/min) using a 4-cylinder direct injection diesel engine with the stock ECU and a wastegated turbocharger. First, the effects of fuel-air equivalence ratios (���© pilot �¢���¼ 0.2-0.6 and ���© overall �¢���¼ 0.2-0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bar) on IDs were investigated. With constant ���© pilot (> 0.5), increasing ���© overall with propane initially decreased ID but eventually led to premature propane autoignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing ���© overall (at constant ���© pilot), more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear (initially increasing and later decreasing) trend at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID) was also shown to be a useful metric to understand the influence of ID on dual fuel combustion.

  2. The catalytic oxidation of propane and propylene with air: total aldehyde production and selectivity at low conversions. 

    E-Print Network [OSTI]

    Looney, Franklin Sittig

    1950-01-01T23:59:59.000Z

    ~ Ths writer is izntebteg to pr, P G~ ~och Tor his assistance azsi guidance in this work aC to Br~ J+ 9 Kinds Tor his aery. suggestions eel Succor~ a The oxidation cf propane~ propylene and prcya~cregyimm mbetccres ctver a ~ aiucdna ~st in a flew... formation of aldehyde fran pure grade propane The ~ce of Within the range of variables of this investigation and with propylene ~& aldehyde pr~cn was f'ennd to bs independent of" residence Qorrcgations relating aldehyde pressure to ~ and cncygsn pressure...

  3. Development of asphalts and pavements using recycled tire rubber. Phase 1, Technical feasibility. Technical progress report, September 1, 1994--August 31, 1995

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J. [and others

    1996-06-01T23:59:59.000Z

    About 285 million tires are discarded every year; less than 100 million are currently being recycled, with the rest being placed in landfills and other waste sites. A solution to reduce the littering of the environment is to use ground tire rubber in road construction. Currently, about 27 million tons of asphalt are used each year in road construction and maintenance of the country`s 2 million miles of roads. If all of the waste tire rubber could be combined with asphalt in road construction, it would displace less than 6% of the total asphalt used each year, yet could save about 60 trillion Btus annually. Purpose of this project is to provide data needed to optimize the performance of rubber-asphalt concretes. The first phase is to develop asphalts and recycling agents tailored for compatibility with ground tire rubber. Chapter 2 presents results on Laboratory Testing and Evaluation: fractionate asphalt material, reblending for aromatic asphalts, verifying optimal curing parameters, aging of blends, and measuring ductilities of asphalt-rubber binders. Chapter 3 focuses on Evaluating Mixture Characteristics (modified binders). Chapter 4 covers Adhesion Test Development (water susceptibility is also covered). The final chapter focuses on the Performance/Economic Update and Commercialization Plan.

  4. State Heating Oil and Propane Program, 1990--1991 heating season. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1991-06-06T23:59:59.000Z

    The following discussion summarizes the survey approach and results of the Department of Public Service`s survey of retail fuel oil and propane prices during the 1990--91 heating season. The semi-monthly phone surveys were conducted in cooperation with the US Department of Energy`s State Fuel Oil and Propane Program, which coordinated surveys of heating fuel prices by 25 eastern and midwest states. This federal/state program serves as a method for fast collection, analysis, and dissemination of information on current residential prices. No other information source meets needs for timely retail price information over the course of the heating season. For the 1990--91 heating season, the Minnesota Department of Public Service (MN/DPS) expanded the scope of its survey effort to include regional price data. Surveys were conducted with 160 retailers, including 59 respondents from the DOE samples, to provide a reasonable sample size for each region. Fuel oil retailers were also asked for updates on their secondary inventory levels.

  5. State Heating Oil and Propane Program, 1990--1991 heating season

    SciTech Connect (OSTI)

    Not Available

    1991-06-06T23:59:59.000Z

    The following discussion summarizes the survey approach and results of the Department of Public Service's survey of retail fuel oil and propane prices during the 1990--91 heating season. The semi-monthly phone surveys were conducted in cooperation with the US Department of Energy's State Fuel Oil and Propane Program, which coordinated surveys of heating fuel prices by 25 eastern and midwest states. This federal/state program serves as a method for fast collection, analysis, and dissemination of information on current residential prices. No other information source meets needs for timely retail price information over the course of the heating season. For the 1990--91 heating season, the Minnesota Department of Public Service (MN/DPS) expanded the scope of its survey effort to include regional price data. Surveys were conducted with 160 retailers, including 59 respondents from the DOE samples, to provide a reasonable sample size for each region. Fuel oil retailers were also asked for updates on their secondary inventory levels.

  6. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

    2007-03-01T23:59:59.000Z

    Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

  7. Comparison of propane and methane performance and emissions in a turbocharged direct injection dual fuel engine

    SciTech Connect (OSTI)

    Gibson, C. M.; Polk, A. C.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-04-20T23:59:59.000Z

    With increasingly restrictive NO x and particulate matter emissions standards, the recent discovery of new natural gas reserves, and the possibility of producing propane efficiently from biomass sources, dual fueling strategies have become more attractive. This paper presents experimental results from dual fuel operation of a four-cylinder turbocharged direct injection (DI) diesel engine with propane or methane (a natural gas surrogate) as the primary fuel and diesel as the ignition source. Experiments were performed with the stock engine control unit at a constant speed of 1800 rpm, and a wide range of brake mean effective pressures (BMEPs) (2.7-11.6 bars) and percent energy substitutions (PESs) of C 3 H 8 and CH 4. Brake thermal efficiencies (BTEs) and emissions (NO x, smoke, total hydrocarbons (THCs), CO, and CO 2) were measured. Maximum PES levels of about 80-95% with CH 4 and 40-92% with C 3 H 8 were achieved. Maximum PES was limited by poor combustion efficiencies and engine misfire at low loads for both C 3 H 8 and CH 4, and the onset of knock above 9 bar BMEP for C 3 H 8. While dual fuel BTEs were lower than straight diesel BTEs at low loads, they approached diesel BTE values at high loads. For dual fuel operation, NO x and smoke reductions (from diesel values) were as high as 66-68% and 97%, respectively, but CO and THC emissions were significantly higher with increasing PES at all engine loads

  8. Production of olefins by oxidative dehydrogenation of propane and butane over monoliths at short contact times

    SciTech Connect (OSTI)

    Huff, M.; Schmidt, L.D. [Univ. of Minnesota, Minneapolis, MN (United States)] [Univ. of Minnesota, Minneapolis, MN (United States)

    1994-09-01T23:59:59.000Z

    The autothermal production of olefins from propane or n-butane by oxidative dehydrogenation and cracking in air or oxygen at atmospheric pressure over noble metal coated ceramic foam monoliths at contact times of {approximately}5 milliseconds has been studied. On Pt, synthesis gas (CO and H{sub 2}) dominates near its stoichiometry, while olefin production dominates at higher fuel-to-oxygen ratios. No carbon buildup is observed, and catalysts exhibit no deactivation over at least several days. On Rh, primarily synthesis gas is produced under these conditions, while on Pd, carbon deposition rapidly deactivates the catalyst. The authors observed up to 65% selectivity to olefins at nearly 100% conversion of propane or n-butane with a catalyst contact time of 5 ms. Ethylene selectivity is maximized by increasing the reaction temperature, either by preheating the reactants or by using oxygen enriched air. Propylene selectivity is maximized by lower temperature and shorter catalyst contact time. Very small amounts alkanes and higher molecular weight species are obtained, suggesting that a homogeneous pyrolysis mechanism is not occurring. A very simple reaction mechanism appears to explain the observed product distribution. Reactions are initiated by oxidative dehydrogenation of the alkane by adsorbed oxygen to form a surface alkyl. On Pt, {beta}-hydrogen and {beta}-alkyl elimination reactions of adsorbed alkyl dominate which lead to olefin production rather than cracking to C{sub s} and H{sub s}. 24 refs., 14 figs., 4 tabs.

  9. Published in Journal de Physique IV, vol 11, pp. Pr3-101 ---Pr3-108 Kinetic modelling of gas-phase decomposition of propane : correlation with pyrocarbon deposition

    E-Print Network [OSTI]

    Boyer, Edmond

    -phase decomposition of propane : correlation with pyrocarbon deposition Cédric Descamps, Gerard L. Vignoles , Olivier : A chemical kinetic model for gas-phase pyrolysis of propane has been set up, partially reduced, and validated the notion of "maturation" from propane to lighter hydrocarbons, then to aromatic compounds and PAHs. The gas

  10. Experimental Study on Shear Fatigue Behavior and Stiffness Performance of Warm Mix Asphalt by adding Synthetic Wax

    E-Print Network [OSTI]

    Petit, Christophe; Canestrari, Francesco; Pannunzio, Valter; Virgili, Amadeo

    2012-01-01T23:59:59.000Z

    Synthetic waxes produced by standard and registered processes may be used to manufacture Warm Mix Asphalt (WMA), which is a modified asphalt concrete produced, applied and compacted at temperatures below those typically required. This feature leads to environmental benefits, such as reduced energy consumption, gas and fume emissions, as well as to economic/operational advantages, such as lower production costs and greater hauling distances for extended construction seasons with tighter schedules. The present article serves to compare the mechanical performance of a WMA produced by adding synthetic wax with a traditional Hot Mix Asphalt (HMA) specimen, in terms of shear fatigue response and both complex and stiffness moduli. The experimental results and related modeling work demonstrate that adding synthetic wax into the WMA composition does not hinder either the destructive or non-destructive performance of an HMA, and this finding is corroborated by respectively measuring fatigue life and stiffness.

  11. Experimental Study on Shear Fatigue Behavior and Stiffness Performance of Warm Mix Asphalt by adding Synthetic Wax

    E-Print Network [OSTI]

    Christophe Petit; Anne Millien; Francesco Canestrari; Valter Pannunzio; Amadeo Virgili

    2012-03-13T23:59:59.000Z

    Synthetic waxes produced by standard and registered processes may be used to manufacture Warm Mix Asphalt (WMA), which is a modified asphalt concrete produced, applied and compacted at temperatures below those typically required. This feature leads to environmental benefits, such as reduced energy consumption, gas and fume emissions, as well as to economic/operational advantages, such as lower production costs and greater hauling distances for extended construction seasons with tighter schedules. The present article serves to compare the mechanical performance of a WMA produced by adding synthetic wax with a traditional Hot Mix Asphalt (HMA) specimen, in terms of shear fatigue response and both complex and stiffness moduli. The experimental results and related modeling work demonstrate that adding synthetic wax into the WMA composition does not hinder either the destructive or non-destructive performance of an HMA, and this finding is corroborated by respectively measuring fatigue life and stiffness.

  12. A simulation study of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production 

    E-Print Network [OSTI]

    Sandoval Munoz, Jorge Eduardo

    2004-11-15T23:59:59.000Z

    A 3D 8-component thermal compositional simulation study has been performed to evaluate the merits of steam-propane injection and a novel vertical-smart horizontal well system for the Lombardi reservoir in the San Ardo field, California. The novel...

  13. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling

    SciTech Connect (OSTI)

    Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

    1991-01-01T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

  14. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling. Revision 1

    SciTech Connect (OSTI)

    Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

    1991-12-01T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

  15. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling

    SciTech Connect (OSTI)

    Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

    1991-12-31T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

  16. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling

    SciTech Connect (OSTI)

    Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

    1991-12-01T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

  17. Optimized design of a heat exchanger for an air-to-water reversible heat pump working with propane (R290)

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    Optimized design of a heat exchanger for an air-to-water reversible heat pump working with propane-to-water reversible heat pump unit was carried out using two different fin-and-tube heat exchanger ``coil'' designs concepts. The performance of the heat pump was evaluated for each coil design at different superheat

  18. Effect of propane-air on NGVs and vehicle fueling stations. Topical report, January 1-October 1, 1993

    SciTech Connect (OSTI)

    Liss, W.E.; Moulton, D.S.

    1994-06-01T23:59:59.000Z

    Propane-air (P/A) peakshaving is an important element of peak-load management for some U.S. gas utilities. P/A is used as a supplemental energy medium with natural gas and has been shown to operate satisfactorily in most natural gas applications. The propane levels injected are compatible with the pressures (under 200 psig) and temperatures (over 40 F) found in utility distribution networks. However, P/A can create problems for natural gas vehicles (NGVs) operating on compressed gas as well as NGV fueling stations. This report contains information on P/A peakshaving and its compatibility with NGVs by documenting condensation impacts at nine conditions--i.e., three propane levels and three temperatures. These data portray the depressurization of a vehicle tank, an area selected because it illustrates NGV operation and can discriminate between acceptable and potentially non-acceptable operating points. These analyses show, not surprisingly, a correlation exists between propane level, ambient temperature, and condensation.

  19. Studies of n-Propanol, iso-Propanol, and Propane Flames

    SciTech Connect (OSTI)

    Veloo, Peter S.; Egolfopoulos, Fokion N.

    2011-01-01T23:59:59.000Z

    The phenomena of propagation and extinction of flames of saturated C{sub 3} alcohols and propane were studied experimentally and numerically in order to assess the effects of the presence and location of the hydroxyl radical in the fuel molecular structure. The experiments were carried out in the counterflow configuration under atmospheric pressure and for unreacted fuel-carrying stream temperature of 343 K. The simulations included detailed descriptions of molecular transport and chemical kinetics using a recently developed kinetic model for C{sub 3} alcohols. The experimental results revealed that the laminar flame speeds and extinction strain rates of n-propanol/air and propane/air flames are close to each other whereas those of iso-propanol/air flames are consistently lower. Similar behavior was observed also for the extinction strain rates of non-premixed n-propanol and iso-propanol flames. It was shown through sensitivity and reaction path analyses that there are two major differences between the intermediates of n-propanol/air and iso-propanol/air flames. In iso-propanol/air flames there are notably higher concentrations of propene whose consumption pathway results in the relatively unreactive allyl radicals, retarding thus the overall reactivity. In n-propanol/air flames there are notably higher concentrations of formaldehyde that reacts readily to form formyl radicals whose subsequent reactions enhance the overall reactivity. The kinetic model used in this study was found to overpredict the experimental results for rich n-propanol/air and propane/air flames. Analysis revealed that those discrepancies are most likely caused by deficiencies in the C{sub 3} alkane kinetics. Through sensitivity analysis, it was determined also that the propagation and extinction of n-propanol/air and iso-propanol/air flames are sensitive largely to hydrogen, carbon monoxide, and C{sub 1}–C{sub 3} kinetics and not to fuel-specific reactions. Finally, the relative sooting propensities of flames of these three fuels were assessed computationally.

  20. Cross sections for electron scattering by propane in the low- and intermediate-energy ranges

    SciTech Connect (OSTI)

    Souza, G. L. C. de; Lee, M.-T.; Sanches, I. P.; Rawat, P.; Iga, I.; Santos, A. S. dos; Machado, L. E.; Sugohara, R. T.; Brescansin, L. M.; Homem, M. G. P.; Lucchese, R. R. [Departamento de Quimica, UFSCar, 13565-905 Sao Carlos, SP (Brazil); Departamento de Fisica, UFSCar, 13565-905 Sao Carlos, SP (Brazil); Instituto de Fisica 'Gleb Wataghin', UNICAMP, 13083-970 Campinas, SP (Brazil); Departamento de Fisica, UFSC, 88010-970 Florianopolis, SC (Brazil); Department of Chemistry, Texas A and M University, College Station, Texas 7784-3255 (United States)

    2010-07-15T23:59:59.000Z

    We present a joint theoretical-experimental study on electron scattering by propane (C{sub 3}H{sub 8}) in the low- and intermediate-energy ranges. Calculated elastic differential, integral, and momentum transfer as well as total (elastic + inelastic) and total absorption cross sections are reported for impact energies ranging from 2 to 500 eV. Also, experimental absolute elastic cross sections are reported in the 40- to 500-eV energy range. A complex optical potential is used to represent the electron-molecule interaction dynamics. A theoretical method based on the single-center-expansion close-coupling framework and corrected by the Pade approximant is used to solve the scattering equations. The experimental angular distributions of the scattered electrons are converted to absolute cross sections using the relative flow technique. The comparison of our calculated with our measured results, as well as with other experimental and theoretical data available in the literature, is encouraging.

  1. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13T23:59:59.000Z

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  2. Synthesis and Characterization of Gold Clusters Ligated with 1,3-Bis(dicyclohexylphosphino)propane

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2013-09-01T23:59:59.000Z

    In this multidisciplinary study we combine chemical reduction synthesis of novel gold clusters in solution with high-resolution analytical mass spectrometry (MS) to gain insight into the composition of the gold clusters and how their size, ionic charge state and ligand substitution influences their gas-phase fragmentation pathways. Ultra small cationic gold clusters ligated with 1,3-bis(dicyclohexylphosphino)propane (DCPP) were synthesized for the first time and introduced into the gas phase using electrospray ionization (ESI). Mass-selected cluster ions were fragmented employing collision induced dissociation (CID) and the product ions were analysed using MS. The solutions were found to contain the multiply charged cationic gold clusters Au9L43+, Au13L53+, Au6L32+, Au8L32+ and Au10L42+ (L = DCPP). The gas-phase fragmentation pathways of these cluster ions were examined systematically employing CID combined with MS. In addition, CID experiments were performed on related gold clusters of the same size and ionic charge state but capped with 1,3-bis(diphenylphosphino)propane (DPPP) ligands containing phenyl functional groups at the two phosphine centers instead of cyclohexane rings. It is shown that this relatively small change in the molecular substitution of the two phosphine centers in diphosphine ligands (C6H11 versus C6H5) exerts a pronounced influence on the size of the species that are preferentially formed in solution during reduction synthesis as well as the gas-phase fragmentation channels of otherwise identical gold cluster ions. The mass spectrometry results indicate that in addition to the length of the alkyl chain between the two phosphine centers, the substituents at the phosphine centers also play a crucial role in determining the composition, size and stability of diphosphine ligated gold clusters synthesized in solution.

  3. Establishing material properties for thin asphalt concrete surfaces on granular bases

    E-Print Network [OSTI]

    Rosson, Barry Thomas

    1985-01-01T23:59:59.000Z

    cross-section of a Goodyear Hi -Miler 10. 00-20 14-ply bias truck tire carcass was obtained; the input data for the Tielking tire model was developed by measuring cord locations, angles, and plies on a section of the tire; and the tire pressure.... Since little work in the past has been done in the area of thin asphalt concrete surface analysis, re-evaluation of several assumptions concerning the tire load were necessary. The truck tire pressures on Texas highways have dramatically increased...

  4. The Effects of Using Alkali-Silica Reaction Affected Recycled Concrete Aggregate in Hot Mix Asphalt

    E-Print Network [OSTI]

    Geiger, Brian James

    2011-10-21T23:59:59.000Z

    mix asphalt (HMA) were investigated in this study. Dilatometer and modified beam tests were performed to determine the possibility of new ASR occurring in reactive aggregates within the HMA or re-expansion of existing gel. The Lottman test... (XRD) was used to check for the potential presence of gel in the filler fraction of the ASR-RCAs. Micro-deval and freeze-thaw tests were evaluated for their potential to indicate the presence of excess micro-cracks or ASR gel. Expansion testing...

  5. Whole House Thermal Performance of Asphalt Shingles Exploiting Special Infrared Reflective Pigments

    E-Print Network [OSTI]

    Hahn, L.; Miller, W.; Desjarlais, A.; Jacobs, J.; Youngquist, A.

    2006-01-01T23:59:59.000Z

    -04 using cycle 4 as described in Table X2.1, Common Exposure Conditions, of the G 154 standard (ASTM 2002b). A UVB-340 lamp was used for simulating direct solar UV radiation; this lamp has no UV output below 300 nm, which is the cutoff wavelength... for this behavior is unknown; overall, however, the data clearly show that the IRR shingles perform just as well when subjected to direct solar UV radiation as standard products accepted on the open market. The IRR asphalt shingles do not lose solar reflectance...

  6. 4-70C Propane (molar mass = 44.1 kg/kmol) poses a greater fire danger than methane (molar mass = 16 kg/kmol) since propane is heavier than air (molar mass = 29 kg/kmol), and it will settle near the floor.

    E-Print Network [OSTI]

    Bahrami, Majid

    4-36 Ideal Gas 4-70C Propane (molar mass = 44.1 kg/kmol) poses a greater fire danger than methane (molar mass = 16 kg/kmol) since propane is heavier than air (molar mass = 29 kg/kmol), and it will settle MATERIAL. © 2008 The McGraw-Hill Companies, Inc. Limited distribution permitted only to teachers

  7. Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate

    E-Print Network [OSTI]

    Goddard III, William A.

    Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

  8. Porous Asphalt Pavement for Stormwater Management The UNH Stormwater Center Web: www.unh.edu/erg/cstev/

    E-Print Network [OSTI]

    Porous Asphalt Pavement for Stormwater Management The UNH Stormwater Center Web: www. Extended Pavement Life Due to Well Drained Base and Reduced Freeze-Thaw Disadvantages · Requires Routine. Standard Pavement Applications where Stormwater Infrastructure is Required · Materials Cost is ~20-25% More

  9. SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer

    E-Print Network [OSTI]

    California at Berkeley, University of

    SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer PAVEMENT TECHNOLOGY UPDATE This Technology Transfer Program publication is provided by the University of California Pavement Research Center. The University of California Pavement

  10. Recycling spent sandblasting grit and similar wastes as aggregate in asphaltic concrete. Technical data sheet

    SciTech Connect (OSTI)

    Heath, J.C.; Nelson, B.

    1998-12-01T23:59:59.000Z

    The Naval Facilities Engineering Service Center (NFESC), Port Hueneme, California, and Naval Facilities Engineering Command Engineering Field Activity, West, San Bruno, California, took overall leadership in identifying and testing methods to manage waste generated from a machine shop located at Hunters Point Annex, at Naval Station, Treasure Island, California. Ship cleaning and equipment maintenance resulted in the accumulation of 4,665 tons of spent sandblasting grit at the site. The spent grit, consisting of silica sand plus a small amount of slag-derived grit, had the physical characteristics of coarse-grained beach sand and also contained fragments of coatings. The spent grit had the potential for exhibiting hazardous characteristics since the coatings included lead-based primers, copper, and butyltin-containing antifouling topcoats. The most beneficial application of reusing the spent grit was to use it as a replacement for some of the fine aggregate in asphaltic concrete. A test program was established that included characterization, bench-scale testing, long-term pilot scale testing, and a full-scale demonstration. Full-scale asphalt production provided samples which proved both the chemical leaching resistance and physical performance characteristics were acceptable.

  11. Experimental study of enhancement of injectivity and in-situ oil upgrading by steam-propane injection for the Hamaca heavy oil field 

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2002-01-01T23:59:59.000Z

    Experiments were conducted to study the feasibility of using propane as a steam additive to accelerate oil production and improve steam injectivity in the Hamaca field, Venezuela. The experiments utilized a vertical injection cell into which a...

  12. Use of a thermodynamic cycle simulation to determine the difference between a propane-fuelled engine and an iso-octane-fuelled engine 

    E-Print Network [OSTI]

    Pathak, Dushyant

    2006-04-12T23:59:59.000Z

    the engine cycle simulation to determine the difference between a propane-fuelled and an iso-octane-fuelled engine for the same operating conditions and engine specifications. A comprehensive parametric investigation was conducted to examine the effects...

  13. Experimental study of enhancement of injectivity and in-situ oil upgrading by steam-propane injection for the Hamaca heavy oil field

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2002-01-01T23:59:59.000Z

    Experiments were conducted to study the feasibility of using propane as a steam additive to accelerate oil production and improve steam injectivity in the Hamaca field, Venezuela. The experiments utilized a vertical injection cell into which a...

  14. Use of a thermodynamic cycle simulation to determine the difference between a propane-fuelled engine and an iso-octane-fuelled engine

    E-Print Network [OSTI]

    Pathak, Dushyant

    2006-04-12T23:59:59.000Z

    the engine cycle simulation to determine the difference between a propane-fuelled and an iso-octane-fuelled engine for the same operating conditions and engine specifications. A comprehensive parametric investigation was conducted to examine the effects...

  15. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Paul J. Tikalsky, Hussain U. Bahia, An Deng and Thomas Snyder

    2004-10-15T23:59:59.000Z

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: a statistically sound evaluation of the characterization of foundry sand, a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at Nini, Ndes, and Nmax. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  16. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Pauul J. Tikalsky

    2004-10-31T23:59:59.000Z

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: (1) a statistically sound evaluation of the characterization of foundry sand, (2) a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and (3) the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at N{sub ini}, N{sub des}, and N{sub max}. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  17. Propane tank explosion (2 deaths, 7 injuries) at Herrig Brothers Feather Creek Farm, Albert City, Iowa, April 9, 1998. Investigation report

    SciTech Connect (OSTI)

    NONE

    1999-09-01T23:59:59.000Z

    This report explains the explosion/BLEVE that took place on April 9, 1998, at the Herrig Brothers Feather Creek Farm, located in Albert City, Iowa. Two volunteer fire fighters were killed and seven other emergency response personnel were injured. Safety issues covered in the report include protection of propane storage tanks and piping, state regulatory oversight of such installations, and fire fighter response to propane storage tank fires.

  18. Adsorption of propane, isopropyl, and hydrogen on cluster models of the M1 phase of Mo-V-Te-Nb-O mixed metal oxide catalyst

    SciTech Connect (OSTI)

    Govindasamy, Agalya [University of Cincinnati; Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

    2010-01-01T23:59:59.000Z

    The Mo-V-Te-Nb-O mixed metal oxide catalyst possessing the M1 phase structure is uniquely capable of directly converting propane into acrylonitrile. However, the mechanism of this complex eight-electron transformation, which includes a series of oxidative H-abstraction and N-insertion steps, remains poorly understood. We have conducted a density functional theory study of cluster models of the proposed active and selective site for propane ammoxidation, including the adsorption of propane, isopropyl (CH{sub 3}CHCH{sub 3}), and H which are involved in the first step of this transformation, that is, the methylene C-H bond scission in propane, on these active site models. Among the surface oxygen species, the telluryl oxo (Te=O) is found to be the most nucleophilic. Whereas the adsorption of propane is weak regardless of the MO{sub x} species involved, isopropyl and H adsorption exhibits strong preference in the order of Te=O > V=O > bridging oxygens > empty Mo apical site, suggesting the importance of TeO{sub x} species for H abstraction. The adsorption energies of isopropyl and H and consequently the reaction energy of the initial dehydrogenation of propane are strongly dependent on the number of ab planes included in the cluster, which points to the need to employ multilayer cluster models to correctly capture the energetics of surface chemistry on this mixed metal oxide catalyst.

  19. Two- and Three-Dimensional Microstructural Modeling of Asphalt Particulate Composite Materials using a Unified Viscoelastic-Viscoplastic-Viscodamage Constitutive Model

    E-Print Network [OSTI]

    You, Taesun

    2013-08-13T23:59:59.000Z

    The main objective of this study is to develop and validate a framework for microstructural modeling of asphalt composite materials using a coupled thermo-viscoelastic, thermo-viscoplastic, and thermo-viscodamage constitutive model. In addition...

  20. Michigan residential No. 2 fuel oil and propane price survey for the 1990/91 heating season. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    This report summarizes the results of a survey of home heating oil and propane prices over the 1990/1991 heating season in Michigan. The survey was conducted under a cooperative agreement between the State of Michigan, Michigan Public Service Commission and the US Department of Energy (DOE), Energy Information Administration (EIA), and was funded by a grant from EIA. From October 1990 through May 1991, participating dealers/distributions were called and asked for their current residential retail prices of No. 2 home heating oil and propane. This information was then transmitted to the EIA, bi-monthly using an electronic reporting system called Petroleum Data Reporting Option (PEDRO). The survey was conducted using a sample provided by EIA of home heating oil and propane retailers which supply Michigan households. These retailers were contacted the first and third Mondays of each month. The sample was designed to account for distributors with different sales volumes, geographic distributions and sources of primary supply. It should be noted that this simple is different from the sample used in prior year surveys.

  1. Michigan residential No. 2 fuel oil and propane price survey for the 1990/91 heating season

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    This report summarizes the results of a survey of home heating oil and propane prices over the 1990/1991 heating season in Michigan. The survey was conducted under a cooperative agreement between the State of Michigan, Michigan Public Service Commission and the US Department of Energy (DOE), Energy Information Administration (EIA), and was funded by a grant from EIA. From October 1990 through May 1991, participating dealers/distributions were called and asked for their current residential retail prices of No. 2 home heating oil and propane. This information was then transmitted to the EIA, bi-monthly using an electronic reporting system called Petroleum Data Reporting Option (PEDRO). The survey was conducted using a sample provided by EIA of home heating oil and propane retailers which supply Michigan households. These retailers were contacted the first and third Mondays of each month. The sample was designed to account for distributors with different sales volumes, geographic distributions and sources of primary supply. It should be noted that this simple is different from the sample used in prior year surveys.

  2. Super critical fluid extraction of a crude oil bitumen-derived liquid and bitumen by carbon dioxide and propane

    SciTech Connect (OSTI)

    Deo, M.D.; Hwang, J.; Hanson, F.V.

    1991-01-01T23:59:59.000Z

    Supercritical fluid extraction of complex hydrocarbon mixtures is important in separation processes, petroleum upgrading and enhanced oil recovery. In this study, a paraffinic crude oil, a bitumen- derived liquid and bitumen were extracted at several temperatures and pressures with carbon dioxide and propane to assess the effect of the size and type of compounds that makeup the feedstock on the extraction process. It was observed that the pure solvent density at the extraction conditions was not the sole variable governing extraction, and that the proximity of the extraction conditions to the pure solvent critical point affected the extraction yields and the compositions of the extracts. Heavier compounds reported to the extract phase as the extraction time increased at constant temperature and pressure and as the extraction pressure increased at constant temperature and extraction time for both the paraffin crude-propane and the bitumen-propane systems. This preferential extraction was not observed for the bitumen-derived liquid. The non-discriminatory extraction behavior of the bitumen-derived liquid was attributed to its thermal history and to the presence of the olefins and aromatics in the liquid. Phase behavior calculations using the Peng-Robinson equation of state and component lumping procedures provided reasonable agreement between calculated and experimental results for the crude oil and bitumen extractions, but failed in the prediction of the phase compositions for the bitumen-derived liquid extractions.

  3. Super critical fluid extraction of a crude oil bitumen-derived liquid and bitumen by carbon dioxide and propane

    SciTech Connect (OSTI)

    Deo, M.D.; Hwang, J.; Hanson, F.V.

    1991-12-31T23:59:59.000Z

    Supercritical fluid extraction of complex hydrocarbon mixtures is important in separation processes, petroleum upgrading and enhanced oil recovery. In this study, a paraffinic crude oil, a bitumen- derived liquid and bitumen were extracted at several temperatures and pressures with carbon dioxide and propane to assess the effect of the size and type of compounds that makeup the feedstock on the extraction process. It was observed that the pure solvent density at the extraction conditions was not the sole variable governing extraction, and that the proximity of the extraction conditions to the pure solvent critical point affected the extraction yields and the compositions of the extracts. Heavier compounds reported to the extract phase as the extraction time increased at constant temperature and pressure and as the extraction pressure increased at constant temperature and extraction time for both the paraffin crude-propane and the bitumen-propane systems. This preferential extraction was not observed for the bitumen-derived liquid. The non-discriminatory extraction behavior of the bitumen-derived liquid was attributed to its thermal history and to the presence of the olefins and aromatics in the liquid. Phase behavior calculations using the Peng-Robinson equation of state and component lumping procedures provided reasonable agreement between calculated and experimental results for the crude oil and bitumen extractions, but failed in the prediction of the phase compositions for the bitumen-derived liquid extractions.

  4. Modeling of the formation of short-chain acids in propane flames

    E-Print Network [OSTI]

    Battin-Leclerc, Frédérique; Jaffrezo, J L; Legrand, M

    2009-01-01T23:59:59.000Z

    In order to better understand their potential formation in combustion systems, a detailed kinetic mechanism for the formation of short-chain monocarboxylic acids, formic (HCOOH), acetic (CH3COOH), propionic (C2H5COOH) and propenic (C2H3COOH)) acids, has been developed. Simulations of lean (equivalence ratios from 0.9 to 0.48) laminar premixed flames of propane stabilized at atmospheric pressure with nitrogen as diluent have been performed. It was found that amounts up to 25 ppm of acetic acid, 15 ppm of formic acid and 1 ppm of C3 acid can be formed for some positions in the flames. Simulations showed that the more abundant C3 acid formed is propenic acid. A quite acceptable agreement has been obtained with the scarce results from the literature concerning oxygenated compounds, including aldehydes (CH2O, CH3CHO) and acids. A reaction pathways analysis demonstrated that each acid is mainly derived from the aldehyde of similar structure.

  5. Subnanometer platinum clusters highly active and selective catalysts for the oxidative dehydrogenation of propane.

    SciTech Connect (OSTI)

    Vajda, S; Pellin, M. J.; Greeley, J. P.; Marshall, C. L.; Curtiss, L. A.; Ballentine, G. A.; Elam, J. W.; Catillon-Mucherie, S.; Redfern, P. C.; Mehmood, F.; Zapol, P.; Yale Univ.

    2009-03-01T23:59:59.000Z

    Small clusters are known to possess reactivity not observed in their bulk analogues, which can make them attractive for catalysis. Their distinct catalytic properties are often hypothesized to result from the large fraction of under-coordinated surface atoms. Here, we show that size-preselected Pt{sub 8-10} clusters stabilized on high-surface-area supports are 40-100 times more active for the oxidative dehydrogenation of propane than previously studied platinum and vanadia catalysts, while at the same time maintaining high selectivity towards formation of propylene over by-products. Quantum chemical calculations indicate that under-coordination of the Pt atoms in the clusters is responsible for the surprisingly high reactivity compared with extended surfaces. We anticipate that these results will form the basis for development of a new class of catalysts by providing a route to bond-specific chemistry, ranging from energy-efficient and environmentally friendly synthesis strategies to the replacement of petrochemical feedstocks by abundant small alkanes.

  6. Autoignited laminar lifted flames of propane in coflow jets with tribrachial edge and mild combustion

    SciTech Connect (OSTI)

    Choi, B.C.; Kim, K.N.; Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-744 (Korea)

    2009-02-15T23:59:59.000Z

    Characteristics of laminar lifted flames have been investigated experimentally by varying the initial temperature of coflow air over 800 K in the non-premixed jets of propane diluted with nitrogen. The result showed that the lifted flame with the initial temperature below 860 K maintained the typical tribrachial structure at the leading edge, which was stabilized by the balance mechanism between the propagation speed of tribrachial flame and the local flow velocity. For the temperature above 860 K, the flame was autoignited without having any external ignition source. The autoignited lifted flames were categorized in two regimes. In the case with tribrachial edge structure, the liftoff height increased nonlinearly with jet velocity. Especially, for the critical condition near blowout, the lifted flame showed a repetitive behavior of extinction and reignition. In such a case, the autoignition was controlled by the non-adiabatic ignition delay time considering heat loss such that the autoignition height was correlated with the square of the adiabatic ignition delay time. In the case with mild combustion regime at excessively diluted conditions, the liftoff height increased linearly with jet velocity and was correlated well with the square of the adiabatic ignition delay time. (author)

  7. A rapid compression machine study of the oxidation of propane in the negative temperature coefficient regime

    SciTech Connect (OSTI)

    Gallagher, S.M.; Curran, H.J.; Metcalfe, W.K.; Healy, D.; Simmie, J.M. [Combustion Chemistry Centre, National University of Ireland, Galway (Ireland); Bourque, G. [Rolls-Royce Canada, Montreal (Canada)

    2008-04-15T23:59:59.000Z

    The oxidation of propane has been studied in the temperature range 680-970 K at compressed gas pressures of 21, 27, and 37 atm and at varying equivalence ratios of 0.5, 1.0, and 2.0. These data are consistent with other experiments presented in the literature for alkane fuels in that, when ignition delay times are plotted as a function of temperature, a characteristic negative coefficient behavior is observed. In addition, these data were simulated using a detailed chemical kinetic model. It was found that qualitatively the model correctly simulated the effect of change in equivalence ratio and pressure, predicting that fuel-rich, high-pressure mixtures ignite fastest, while fuel-lean, low-pressure mixtures ignite slowest. Moreover, reactivity as a function of temperature is well captured, with the model predicting negative temperature coefficient behavior similar to the experiments. Quantitatively the model is faster than experiment for all mixtures at the lowest temperatures (650-750 K) and is also faster than experiment throughout the entire temperature range for fuel-lean mixtures. (author)

  8. Soot formation and temperature field structure in laminar propane-air diffusion flames at elevated pressures

    SciTech Connect (OSTI)

    Bento, Decio S.; Guelder, OEmer L. [Institute for Aerospace Studies, University of Toronto, 4925 Dufferin Street, Toronto, ON M3H 5T6 (Canada); Thomson, Kevin A. [National Research Council, ICPET Combustion Technology, 1200 Montreal Road M-9, Ontario K1A 0R6 (Canada)

    2006-06-15T23:59:59.000Z

    The effect of pressure on soot formation and the structure of the temperature field was studied in coflow propane-air laminar diffusion flames over the pressure range of 0.1 to 0.73 MPa in a high-pressure combustion chamber. The fuel flow rate was selected so that the soot was completely oxidized within the visible flame and the flame was stable at all pressures. Spectral soot emission was used to measure radially resolved soot volume fraction and soot temperature as a function of pressure. Additional soot volume fraction measurements were made at selected heights using line-of-sight light attenuation. Soot concentration values from these two techniques agreed to within 30% and both methods exhibited similar trends in the spatial distribution of soot concentration. Maximum line-of-sight soot concentration along the flame centerline scaled with pressure; the pressure exponent was about 1.4 for pressures between 0.2 and 0.73 MPa. Peak carbon conversion to soot, defined as the percentage of fuel carbon content converted to soot, also followed a power-law dependence on pressure, where the pressure exponent was near to unity for pressures between 0.2 and 0.73 MPa. Soot temperature measurements indicated that the overall temperatures decreased with increasing pressure; however, the temperature gradients increased with increasing pressure. (author)

  9. Operation of a Four-Cylinder 1.9L Propane Fueled HCCI Engine

    SciTech Connect (OSTI)

    Flowers, D; Aceves, S M; Martinez-Frias, J; Smith, J R; Au, M; Girard, J; Dibble, R

    2001-03-15T23:59:59.000Z

    A four-cylinder 1.9 Volkswagen TDI Engine has been converted to run in Homogeneous Charge Compression Ignition (HCCI) mode. The stock configuration is a turbocharged direct injection Diesel engine. The combustion chamber has been modified by discarding the in-cylinder Diesel fuel injectors and replacing them with blank inserts (which contain pressure transducers). The stock pistons contain a reentrant bowl and have been retained for the tests reported here. The intake and exhaust manifolds have also been retained, but the turbocharger has been removed. A heater has been installed upstream of the intake manifold and fuel is added just downstream of this heater. The performance of this engine in naturally aspirated HCCI operation, subject to variable intake temperature and fuel flow rate, has been studied. The engine has been run with propane fuel at a constant speed of 1800 rpm. This work is intended to characterize the HCCI operation of the engine in this configuration that has been minimally modified from the base Diesel engine. The performance (BMEP, IMEP, efficiency, etc) and emissions (THC, CO, NOx) of the engine are presented, as are combustion process results based on heat release analysis of the pressure traces from each cylinder.

  10. Use of shredded tires in the subbase layer of asphalt pavements

    SciTech Connect (OSTI)

    Papp, W.J. Jr.; Maher, M.H. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Civil and Environmental Engineering; Baker, R.F. [New Jersey Dept. of Transportation, Trenton, NJ (United States)

    1997-12-31T23:59:59.000Z

    Research was conducted on the use of shredded scrap tires for use in the subbase layer of asphalt pavements. Mixtures of shredded scrap tires with virgin soil provide a means of recycling unwanted tires and conserving a finite supply of virgin soil. The mechanistic procedure for the design of pavement systems requires resilient modulus values. Plastic and elastic strains were measured using external LVDT`s and internal proximity sensors. Resilient modulus measurements were conducted on cohesionless soils mixed with various amounts of shredded tire chips. The performance f the shredded tire mixture is compared to that of the naturally occurring virgin soil used in subbase applications in New Jersey. A number of experimental issues are discussed such as: method of compaction, optimum ratio of shredded tire chips to soil, optimum size and gradation of shredded tire chips, and strength testing using California Bearing Ratio.

  11. Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural Characterization and Catalytic Function

    E-Print Network [OSTI]

    Bell, Alexis T.

    Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural of stoichiometric reduction in H2, and the oxidative dehydrogenation of propane. VOx domains on Al2O3 modified The oxidative dehydrogenation (ODH) of propane provides an attractive route for the synthesis of propene.1

  12. Hydrogen Storage -Overview George Thomas, Hydrogen Consultant to SNL*

    E-Print Network [OSTI]

    aspects of hydrogen utilization. production distribution utilization How do we achieve safe, efficient Forecourt storage (refueling stations) requirements being developed (IHIG) Distribution storage (delivery 75 100 125 hydrogen m ethane ethane propane butane pentane hexane heptane octane (gasoline) cetane

  13. Recycled brake linings as partial aggregate substitute in asphalt paving. Construction and final report. Report for July 1992-August 1996

    SciTech Connect (OSTI)

    Miller, P.A.; Sukley, R.

    1996-09-01T23:59:59.000Z

    The purpose of this project was to evaluate the performance of asphalt containing various percentages of brake lining as an aggregate, and compare its performance to that of normal asphalt containing natural aggregate. This project is an effort to explore alternate ways to use waste product. Four test section of FB-2 Modified mix containing brake lining materials were placed in July 1992 along with one control section on SR 3022 in Mercer county. To date all sections are performing satisfactory, and Brake linings should be recommended as a viable partial replacement of aggregate in bituminous materials. This study only considered the performance of only off-spec brake linings, therefore, any performance data or enviromental effects of placement of used brake material should be addressed.

  14. Hydronic Heating Coil Versus Propane Furnace, Rehoboth Beach, Delaware (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01T23:59:59.000Z

    Insight Homes constructed two houses in Rehoboth Beach, Delaware, with identical floor plans and thermal envelopes but different heating and domestic hot water (DHW) systems. Each house is 1,715-ft2 with a single story, three bedrooms, two bathrooms, and the heating, ventilation, and air conditioning (HVAC) systems and ductwork located in conditioned crawlspaces. The standard house, which the builder offers as its standard production house, uses an air source heat pump (ASHP) with supplemental propane furnace heating. The Building America test house uses the same ASHP unit with supplemental heat provided by the DHW heater (a combined DHW and hydronic heating system, where the hydronic heating element is in the air handler). Both houses were occupied during the test period. Results indicate that efficiency of the two heating systems was not significantly different. Three issues dominate these results; lower system design performance resulting from the indoor refrigerant coil selected for the standard house, an incorrectly functioning defrost cycle in the standard house, and the low resolution of the natural gas monitoring equipment. The thermal comfort of both houses fell outside the ASHRAE Standard 55 heating range but was within the ACCA room-to-room temperature range when compared to the thermostat temperature. The monitored DHW draw schedules were input into EnergyPlus to evaluate the efficiency of the tankless hot water heater model using the two monitored profiles and the Building America House Simulation Protocols. The results indicate that the simulation is not significantly impacted by the draw profiles.

  15. Electrochemical assessment and service-life prediction of mechanically stabilized earth walls backfilled with crushed concrete and recycled asphalt pavement

    E-Print Network [OSTI]

    Esfeller, Michael Watts, Jr.

    2009-06-02T23:59:59.000Z

    Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 2006 Major Subject: Civil Engineering ELECTROCHEMICAL ASSESSMENT AND SERVICE-LIFE PREDICTION... OF MECHANICALLY STABILIZED EARTH WALLS BACKFILLED WITH CRUSHED CONCRETE AND RECYCLED ASPHALT PAVEMENT A Thesis by MICHAEL WATTS ESFELLER, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  16. ED-XAS Data Reveal In-situ Time-Resolved Adsorbate Coverage on Supported Molybdenum Oxide Catalysts during Propane Dehydrogenation

    SciTech Connect (OSTI)

    Ramaker, David; Gatewood, Daniel [Department of Chemistry, George Washington University, Washington D.C. 20052 (United States); Beale, Andrew M.; Weckhuysen, Bert M. [Inorganic Chemistry and Catalysis, Dept. of Chem., Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht (Netherlands)

    2007-02-02T23:59:59.000Z

    Energy-Dispersive X-ray Absorption Spectroscopy (ED-XAS) data combined with UV/Vis, Raman, and mass spectrometry data on alumina- and silica-supported molybdenum oxide catalysts under propane dehydrogenation conditions have been previously reported. A novel {delta}{mu} adsorbate isolation technique was applied here to the time-resolved (0.1 min) Mo K-edge ED-XAS data by taking the difference of absorption, {mu}, at t>1 against the initial time, t=0. Further, full multiple scattering calculations using the FEFF 8.0 code are performed to interpret the {delta}{mu} signatures. The resulting difference spectra and interpretation provide real time propane coverage and O depletion at the MoOn surface. The propane coverage is seen to correlate with the propene and/or coke production, with the maximum coke formation occurring when the propane coverage is the largest. Combined, these data give unprecedented insight into the complicated dynamics for propane dehydrogenation.

  17. State heating oil & propane program. Final report for the Commonwealth of Pennsylvania 1994--1995 heating season

    SciTech Connect (OSTI)

    NONE

    1995-05-18T23:59:59.000Z

    This report has been prepared by the Pennsylvania Energy Office (PEO) to summarize its activities under the State Heating Oil and Propane Program (SHOPP) for the 1994-95 heating season. The PEO is under a cooperative agreement, Agreement DE-7C01-91E122784, Amendment No. 3, with the U.S. Department of Energy, Energy Information Administration (DOE/EIA) to conduct these activities. The objective of the SHOPP program was to collect Pennsylvania-specific price information for residential No. 2 heating oil and propane and transmit this information to DOE/EIA for compilation into its various reports and publications. Under the PEO`s cooperative agreement with DOE/EIA, prices were collected on the first and third Mondays of each month, starting on October 3, 1994, and extending through March 20, 1995. Prices were obtained via telephone calls made by PEO staff. For each heating oil distributor in the survey sample, the PEO collected charge prices for a standard delivery quantity of No. 2 heating oil. For propane, dealers were requested to provide the price for a customer using between one thousand and fifteen hundred gallons of fuel during the heating season. The PEO agreed to forward the survey results to the DOE/EIA within three days of the date of each survey. DOE/EIA`s responsibility was to compile the data from all states and distribute a bi-weekly report. In addition, DOE/EIA took responsibility for the collection of primary stock information for No. 2 heating oil.

  18. The catalytic oxidation of propane and propylene with air: total aldehyde production and selectivity at low conversions.

    E-Print Network [OSTI]

    Looney, Franklin Sittig

    1950-01-01T23:59:59.000Z

    ~ Ths writer is izntebteg to pr, P G~ ~och Tor his assistance azsi guidance in this work aC to Br~ J+ 9 Kinds Tor his aery. suggestions eel Succor~ a The oxidation cf propane~ propylene and prcya~cregyimm mbetccres ctver a ~ aiucdna ~st in a flew... vere developed for rms with Iow propylene pressers Froa ths recncits of this study it, appears that the reaction yieldiccg aldehyde occurs in the fere part af the reactec bed Increased oxidation br' about by tunreased residence tins causes eccidation...

  19. Working Draft

    Office of Environmental Management (EM)

    gases-including nitrogen, carbon dioxide, hydrogen sulfide, methane, ethane, and propane-and butanes and other volatile liquids) composition, and flash gas composition....

  20. NOAA Data Report ERL PMEL-2 LOW MOLECULAR WEIGHT HYDROCARBON CONCENTRATIONS (C1 -c4),

    E-Print Network [OSTI]

    or imply that the NOAA Environ- mental Research Laboratories approves, recommends, or endorses any pro) variations in the dissolved gaseous hydrocarbon fraction composed of methane, ethane, ethene, propane

  1. Quantum cascade laser investigations of CH4 and C2H2 interconversion in hydrocarbon/H2 gas mixtures during microwave plasma

    E-Print Network [OSTI]

    Bristol, University of

    described in Mankelevich et al. J. Appl. Phys. 104, 113304 2008 . The gas temperature distribution within source gases investigated methane, acetylene, ethane, propyne, propane, and butane are converted

  2. High-Pressure Micellar Solutions of Polystyrene-block-Polybutadiene and Polystyrene-block-Polyisoprene Solutions in Propane Exhibit Cloud-Pressure Reduction and Distinct Micellization End Points

    SciTech Connect (OSTI)

    Winoto, Winoto [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Tan, Sugata [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

    2009-01-01T23:59:59.000Z

    Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical non-micellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size and ratio, and on the polymer concentration. For a given pressure, the micellization end-point temperature corresponds to the "critical micelle temperature." The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

  3. Supplement of "Inversion of and emissions

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ¦&¡ ¤¢' ethane ¦&¡ ¤ ethylene ¦( ¤¢) propane ¦( ¤¢' propylene 0 ¨1 234¦&# ¤¢) $ isoprene 5 2 06£ 4¦ 768 ¤ 7 propylene ¦ ¤ %¦§ S © ¤ peracetic acid ¦( ¤©a © ¤ peroxide from propane 5 ¦!b!@ © ¤ 4¦ ¤ %¦§ S ¦ ¤ % ©¡ methylperoxy radical 2& ¢¡4¦( ¤¢' ¤ ¢¡%$ peroxy radical from propylene 5 ¦!b!@ ¢¡4¦ ¤ ¥¦§ S

  4. Photophysics and Luminescence Spectroelectrochemistry of [Tc(dmpe)3]+/2+ (dmpe = 1,2-bis(dimethylphosphino)ethane)

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Smith, Frances N.; Wang, Zheming; Hightower, Sean E.; Sullivan, Brian P.; Heineman, William R.; Seliskar, Carl J.; Bryan, Samuel A.

    2013-12-05T23:59:59.000Z

    The ligand-to-metal charge transfer (LMCT) excited state luminescence of [Tc(dmpe)3]2+ (dmpe is 1,2-bis-(dimethylphosphino)ethane) has been measured in solution at room temperature, and is compared to its Re analogue. Surprisingly, both [M(dmpe)3]2+* (M = Re, Tc) species have extremely large excited-state potentials (ESPs) as oxidants - the highest for any simple coordination complex of a transition metal. Furthermore, this potential is available using a photon of visible light (calculated for M = Re(Tc); E1/2* = +2.61(2.48) V versus SCE; ?max = 526(585) nm). Open shell TDDFT calculations support the assignment of the lowest energy transition in both the technetium and rhenium complexes to be a doublet-doublet process that involve predominantly LMCT (dmpe-to-metal) character and is in agreement with past assignments for the Re system. As expected for highly oxidizing excited state potentials, quenching is observed for the excited states by both the rhenium and technetium complexes. Stern-Volmer analysis resulted in quenching parameters for both the rhenium and technetium complexes under identical conditions, and are compared using Rehm-Weller analysis. Of particular interest is the fact that both benzene and toluene are oxidized by both the Re and Tc systems.

  5. A Sequential Fluid-mechanic Chemical-kinetic Model of Propane HCCI Combustion

    SciTech Connect (OSTI)

    Aceves, S M; Flowers, D L; Martinez-Frias, J; Smith, J R; Westbrook, C; Pitz, W; Dibble, R; Wright, J F; Akinyemi, W C; Hessel, R P

    2000-11-29T23:59:59.000Z

    We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. This methodology combines a detailed fluid mechanics code with a detailed chemical kinetics code. Instead of directly linking the two codes, which would require an extremely long computational time, the methodology consists of first running the fluid mechanics code to obtain temperature profiles as a function of time. These temperature profiles are then used as input to a multi-zone chemical kinetics code. The advantage of this procedure is that a small number of zones (10) is enough to obtain accurate results. This procedure achieves the benefits of linking the fluid mechanics and the chemical kinetics codes with a great reduction in the computational effort, to a level that can be handled with current computers. The success of this procedure is in large part a consequence of the fact that for much of the compression stroke the chemistry is inactive and thus has little influence on fluid mechanics and heat transfer. Then, when chemistry is active, combustion is rather sudden, leaving little time for interaction between chemistry and fluid mixing and heat transfer. This sequential methodology has been capable of explaining the main characteristics of HCCI combustion that have been observed in experiments. In this paper, we use our model to explore an HCCI engine running on propane. The paper compares experimental and numerical pressure traces, heat release rates, and hydrocarbon and carbon monoxide emissions. The results show an excellent agreement, even in parameters that are difficult to predict, such as chemical heat release rates. Carbon monoxide emissions are reasonably well predicted, even though it is intrinsically difficult to make good predictions of CO emissions in HCCI engines. The paper includes a sensitivity study on the effect of the heat transfer correlation on the results of the analysis. Importantly, the paper also shows a numerical study on how parameters such as swirl rate, crevices and ceramic walls could help in reducing HC and CO emissions from HCCI engines.

  6. United States Department of Energy New Jersey Department of Environmental Protection and Energy. 1991--1992 Heating Oil and Propane Price Monitoring Program

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    In cooperation with the United States Department of Energy (USDOE), Energy Information Administration (EIA) the New Jersey Department of Environmental Protection and Energy (DEPE), Office of Energy participated in a program to monitor retail prices of no. 2 heating oil and propane in New Jersey. According to program instructions, we conducted price surveys on a semi-monthly basis to obtain the necessary information from retail fuel merchants and propane dealers identified by the EIA. The period of the surveys was October 7, 1991 to March 16 1992. We submitted data collected as of specified reference dates to the EIA, within two working days of those dates.

  7. Value-added utilisation of recycled concrete in hot-mix asphalt

    SciTech Connect (OSTI)

    Wong, Yiik Diew [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Sun, Darren Delai [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)]. E-mail: ddsun@ntu.edu.sg; Lai, Dickson [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2007-07-01T23:59:59.000Z

    The feasibility of partial substitution of granite aggregate in hot-mix asphalt (HMA) with waste concrete aggregate was investigated. Three hybrid HMA mixes incorporating substitutions of granite fillers/fines with 6%, 45% untreated, and 45% heat-treated concrete were evaluated by the Marshall mix design method; the optimum binder contents were found to be 5.3%, 6.5% and 7.0% of grade Pen 60/70 bitumen, respectively. All three hybrid mixes satisfied the Marshall criteria of the Singapore Land Transport Authority (LTA) W3B wearing course specification. The hybrid mix with 6% concrete fillers gave comparable resilient modulus and creep resistance as the conventional W3B mix, while hybrid mixes with higher concrete substitutions achieved better performance. X-ray diffraction (XRD) showed the distinct presence of free lime in the heat-treated concrete, while the scanning electron microscope (SEM) provided an in-depth perspective of the concrete grains in the HMA matrix. The results suggest feasible use of waste concrete as partial aggregate substitution in HMA.

  8. Experimental studies of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production in the San Ardo field 

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2007-09-17T23:59:59.000Z

    is the use of propane as a steam additive with the purpose of increasing recovery and accelerating oil production. The second process involves the use of a novel production configuration that makes use of a vertical injector and a smart horizontal producer...

  9. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation 

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  10. An In-Situ XAS Study of the Structural Changes in a CuO-CeO2/Al2O3 Catalyst during Total Oxidation of Propane

    SciTech Connect (OSTI)

    Silversmith, Geert; Poelman, Hilde; Poelman, Dirk; Gryse, Roger de [Ghent University, Department of Solid State Sciences, Krijgslaan 281 S1, B-9000 Gent (Belgium); Olea, Maria; Balcaen, Veerle; Heynderickx, Philippe; Marin, Guy B. [Ghent University, Laboratorium voor Petrochemische Techniek, Krijgslaan 281 S5, B-9000 Gent (Belgium)

    2007-02-02T23:59:59.000Z

    A CuOx-CeOx/Al2O3 catalyst was studied with in-situ transmission Cu K XAS for the total oxidation of propane as model reaction for the catalytic elimination of volatile organic compounds. The local Cu structure was determined for the catalyst as such, after pre-oxidation and after reduction with propane. The catalyst as such has a local CuO structure. No structural effect was observed upon heating in He up to 600 deg. C or after pre-oxidation at 150 deg. C. A full reduction of the Cu2+ towards metallic Cu0 occurred, when propane was fed to the catalyst. The change in local Cu structure during propane reduction was followed with a time resolution of 1 min. The {chi}(k) scans appeared as linear combinations of start and end spectra, CuO and Cu structure, respectively. However, careful examination of the XANES edge spectra indicates the presence of a small amount of additional Cu1+ species.

  11. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  12. Influence of low and high temperature coking of H-GaMFI propane aromatization catalyst on its surface and catalytic properties

    SciTech Connect (OSTI)

    Choudhary, V.R.; Kinage, A.K.; Devadas, P. [National Chemical Lab., Pune (India)] [and others] [National Chemical Lab., Pune (India); and others

    1997-03-01T23:59:59.000Z

    H-Gallosilicate (MFI) (i.e., H-GaMFI) zeolite shows high activity/selectivity in the aromatization of lower alkanes, which is processes of treat practical importance. The high aromatization activity of this catalyst is attributed to its high dehydrogenation activity due to the presence of high dispersed nonframework Ga-oxide species (which are formed during hydrothermal synthesis and/or pretreatments to the zeolite) along with the zeolitic acid sites (or framework Ga), resulting in a bifunctional catalyst. However, this zeolite undergoes fast catalyst deactivation in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization at 500-550{degrees}C for a short time-on-stream (10 h). It is interesting to know the effect of catalyst deactivation due to coking in the propane aromatization for much longer periods both at low (at 400{degrees}C) and high (at 550{degrees}C) temperatures on the product selectivity and also on the surface (viz., sorption capacity, acidity/acid strength distribution) and catalytic properties of the zeolite. The present investigation was undertaken for this purpose. 16 refs., 1 fig., 3 tabs.

  13. A study of substitution solvents in asphalt fume extraction and the effects of heating duration and temperature

    E-Print Network [OSTI]

    Curry, Noel Thomas

    1981-01-01T23:59:59.000Z

    (denoted Dl). Duration two ( D2) ran from time 60 minutes to time 90 minutes, Dl and DZ were separated by a 30 minute period in wh i ch no sampling occurred. The total time of heati ng at this temperature range was 90 minutes, which was near the limit... of the filter to hold it in position, and the cassette cap was placed on top of this. 3oth ends were then plugged. (Figure 2) After a warming period of approximately 30 minutes, the temperature of the liquid asphalt was raised to 250 C. iihen it reached...

  14. Bench-Scale Synthetic Optimization of 1,2-bis(2-aminophenylthio)ethane (APO-Link) Used in the Production of APO-BMI Resin

    SciTech Connect (OSTI)

    Hilary Wheeler; Crystal Densmore

    2007-07-31T23:59:59.000Z

    The diamine reagent 1,2-bis(2-aminophenylthio)ethane is no longer commercially available but still required for the synthesis of the bismaleimide resin, APO-BMI, used in syntactic foams. In this work, we examined the hydrolysis of benzothiazole followed the by reaction with dichloroethane or dibromoethane. We also studied the deprotonation of 2-aminothiophenol followed by the reaction with dibromoethane. We optimized the latter for scale-up by scrutinizing all aspects of the reaction conditions, work-up and recrystallization. On bench-scale, our optimized procedure consistently produced a 75-80% overall yield of finely divided, high purity product (>95%).

  15. The preliminary result from spectra of $K^0_s ?^-$ in reaction p+propane at 10 GeV/c

    E-Print Network [OSTI]

    P. Zh. Aslanyan

    2006-05-04T23:59:59.000Z

    The experimental data from 2m propane bubble chamber have been analyzed to search for scalar meson $\\kappa(800)$ in a $K^0_s\\pi$ decay mode for the reaction p+$C_3H_8$ at 10 GeV/c. The $K^0_s\\pi^-$ invariant mass spectrum has shown resonant structures with $M_{K^0_s\\pi^-}$=730, 900 and $\\Gamma$=143, 48 MeV/$c^2$, respectively. The statistical significance are estimated to be of 14.2$\\sigma$ and 4.2$\\sigma$, respectively. The peak in M(900) is identified as reflection from the well known resonance with mass of 892 MeV/c$^2$.

  16. A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products

    SciTech Connect (OSTI)

    Levinson, Ronnen; Akbari, Hashem; Berdahl, Paul; Wood, Kurt; Skilton, Wayne; Petersheim, Jerry

    2009-11-20T23:59:59.000Z

    The widespread use of solar-reflective roofing materials can save energy, mitigate urban heat islands and slow global warming by cooling the roughly 20% of the urban surface that is roofed. In this study we created prototype solar-reflective nonwhite concrete tile and asphalt shingle roofing materials using a two-layer spray coating process intended to maximize both solar reflectance and factory-line throughput. Each layer is a thin, quick-drying, pigmented latex paint based on either acrylic or a poly(vinylidene fluoride)/acrylic blend. The first layer is a titanium dioxide rutile white basecoat that increases the solar reflectance of a gray-cement concrete tile from 0.18 to 0.79, and that of a shingle surfaced with bare granules from 0.06 to 0.62. The second layer is a 'cool' color topcoat with weak near-infrared (NIR) absorption and/or strong NIR backscattering. Each layer dries within seconds, potentially allowing a factory line to pass first under the white spray, then under the color spray. We combined a white basecoat with monocolor topcoats in various shades of red, brown, green and blue to prepare 24 cool color prototype tiles and 24 cool color prototypes shingles. The solar reflectances of the tiles ranged from 0.26 (dark brown; CIELAB lightness value L* = 29) to 0.57 (light green; L* = 76); those of the shingles ranged from 0.18 (dark brown; L* = 26) to 0.34 (light green; L* = 68). Over half of the tiles had a solar reflectance of at least 0.40, and over half of the shingles had a solar reflectance of at least 0.25.

  17. TIME-VARYING FLAME IONIZATION SENSING APPLIED TO NATURAL GAS AND PROPANE BLENDS IN A PRESSURIZED LEAN PREMIXED (LPM) COMBUSTOR

    SciTech Connect (OSTI)

    D. L. Straub; B. T. Chorpening; E. D. Huckaby; J. D. Thornton; W. L. Fincham

    2008-06-13T23:59:59.000Z

    In-situ monitoring of combustion phenomena is a critical need for optimal operation and control of advanced gas turbine combustion systems. The concept described in this paper is based on naturally occurring flame ionization processes that accompany the combustion of hydrocarbon fuels. Previous work has shown that flame ionization techniques may be applied to detect flashback, lean blowout, and some aspects of thermo-acoustic combustion instabilities. Previous work has focused on application of DC electric fields. By application of time-varying electric fields, significant improvements to sensor capabilities have been observed. These data have been collected in a lean premixed combustion test rig operating at 0.51-0.76 MPa (5-7.5 atm) with air preheated to 588 K (600°F). Five percent of the total fuel flow is injected through the centerbody tip as a diffusion pilot. The fuel composition is varied independently by blending approximately 5% (volume) propane with the pipeline natural gas. The reference velocity through the premixing annulus is kept constant for all conditions at a nominal value of 70 m/s. The fuel-air equivalence ratio is varied independently from 0.46 – 0.58. Relative to the DC field version, the time-varying combustion control and diagnostic sensor (TV-CCADS) shows a significant improvement in the correlation between the measured flame ionization current and local fuel-air equivalence ratio. In testing with different fuel compositions, the triangle wave data show the most distinct change in flame ionization current in response to an increase in propane content. Continued development of this sensor technology will improve the capability to control advanced gas turbine combustion systems, and help address issues associated with variations in fuel supplies.

  18. Compressible Solution Properties of Amorphous Polystyrene-block-Polybutadiene, Crystalline Polystyrene-block-Poly(Hydrogenated Polybutadiene) and Their Corresponding Homopolymers: Fluid-Fluid, Fluid-Solid and Fluid-Micelle Phase Transitions in Propane and Propylene

    SciTech Connect (OSTI)

    Hong, Kunlun [ORNL; Mays, Jimmy [ORNL; Winoto, Winoto [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie

    2009-01-01T23:59:59.000Z

    Abstract Polystyrene, polybutadiene, hydrogenated polybutadiene, and styrene diblock copolymers of these homopolymers can form homogenous solutions in compressible solvents, such as propane and propylene, which separate into two bulk phases upon reducing pressure. The cloud and micellization pressures for homopolymer and diblock copolymers are generally found to be higher in propane than in propylene, except for hydrogenated polybutadiene and polystyrene-block-(hydrogenated polybutadiene). Hydrogenated polybutadiene homopolymers and copolymers exhibit relatively pressure-independent crystallization and melting observed in both propane and propylene solutions.

  19. Asphaltenes and Asphalts, 2. Developments in Petroleum Science, 40 B edited by T.F. Yen and G.V. Chilingarian

    E-Print Network [OSTI]

    Ã?agin, Tahir

    Asphaltenes and Asphalts, 2. Developments in Petroleum Science, 40 B edited by T.F. Yen and G OF ASPHALTENES: A PREDICTIVE APPROACH BASED ON COMPUTER ASSISTED STRUCTURE ELUCIDATION AND ATOMISTIC SIMULATIONS, asphaltenes and resins [1­4]. Asphaltenes are operationally defined as the non-volatile and polar fraction

  20. Biodegradation of ddt (1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane) by the white rot fungus phanerochaete chrysosporium

    SciTech Connect (OSTI)

    Bumpus, J.A.; Aust, S.D.

    1987-01-01T23:59:59.000Z

    Extensive biodegradation of 1,1,1-trichloro-2,2bis(4-chlorophenyl)ethane (DDT) by the white rot fungus Phanerochaete chrysosporium was demonstrated by disappearance and mineralization of (14C) DDT in nutrient nitrogen-deficient cultures. Mass balance studies demonstrated the formation of polar and water-soluble metabolites during degradation. Hexane-extractable metabolites identified by gas chromatography-mass spectrometry included 1,1-dichloro-2,2-bis(4-chlorophenyl)ethane(DDD), 2,2,2-trichloro-1,1-bis(4-chlorophenyl)ethanol (dicofol), 2,2-dichloro-1,1-bis(4-chlorophenyl) ethanol (FW-152), and 4,4'-dichlorobenzophenone (DBP). DDD was the first metabolite observed; it appeared after 3 days of incubation and disappeared from culture upon continued incubation. This, as well as the fact that ((14)C) dicofol was mineralized, demonstrates that intermediates formed during DDT degradation are also metabolized. These results demonstrate that the pathway for DDT degradation in P. chrysosporium is clearly different from the major pathway proposed for microbial or environmental degradation of DDT. Like P. chrysosporium ME-446 and BKM-F-1767, the white rot fungi Pleurotus ostreatus, Phellinus weirii, and Polyporus versicolor also mineralized DDT.

  1. A Texas project illustrates the benefits of integrated gasification

    SciTech Connect (OSTI)

    Philcox, J. [Praxair Inc., Houston, TX (United States); Fenner, G.W. [Praxair Inc., Tonawanda, NY (United States)

    1997-07-14T23:59:59.000Z

    Gasification can be an attractive option for converting a variety of petroleum feedstocks to chemicals. Natural gas is commonly sued to produce acetic acid, isocyanates, plastics, and fibers. But low-cost, bottom-of-the-barrel feeds, such as vacuum resid, petroleum coke, and asphaltenes, also can be used. In any case, gasification products include synthesis gas, carbon monoxide, hydrogen, steam, carbon dioxide, and power. The more a gasification facility is integrated with utilities and other non-core operations of a production complex, the more economical the products are for all consumers. The paper discusses gasification of natural gas, light hydrocarbons (ethane, propanes, and butanes), and heavy hydrocarbons (distillates, heavy residues, asphalts, coals, petroleum coke). The paper then describes a Texas City Gasification Project, which gasifies methane to produce carbon monoxide, hydrogen, and alcohol. The plant is integrated with a cogeneration plant. Economics are discussed.

  2. High-precision optical measurements of 13 isotope ratios in organic compounds at

    E-Print Network [OSTI]

    Zare, Richard N.

    range with an average precision of 0.95 and 0.67 for ethane and propane, respec- tively. The calibrated accuracy for methane, ethane, and propane is within 3 of the values determined using isotope ratio mass place in chemistry, especially in geochemistry, for determining reaction mechanisms and pro- viding

  3. DOI: 10.1126/science.1194777 , 211 (2010);330Science

    E-Print Network [OSTI]

    Fineberg, Jay

    2010-01-01T23:59:59.000Z

    .colleagues, clients, or customers by , you can order high-quality copies for yourIf you wish to distribute hydrocarbon plumes is delayed with respect to that of ethane-, propane-, and butane-consuming communities. To identify potential propane- and ethane- consuming bacteria active in the deep plumes, we collected cells

  4. ORIGINAL RESEARCH ARTICLE published: 14 May 2013

    E-Print Network [OSTI]

    Girguis, Peter R.

    examined the metabolism of ethane (C2), propane (C3), and butane (C4) in anoxic sediments in contrast-chain alkanes, sulfate reduction INTRODUCTION Hydrocarbongases,includingmethane(C1),ethane(C2),propane (C3, ecological physiology, and diversity of microorganisms mediating this process and the global distribution

  5. 396 J. Phys. Chem. 1990, 94, 396-409 Reaction of Cyclopropane, Methylcyclopropane, and Propylene with Hydrogen on the

    E-Print Network [OSTI]

    Goodman, Wayne

    . Consequently, from an exam- ination of a relatively simple product distribution (methane, ethane, and propane hydrogenation to propane and the hydrogenolysis to methane and ethane, with the hydrogenation channel dominating the two surfaces for hydrogenolysis,the product distributions for the major reaction channels were CH4+ C

  6. Measurements of Laminar Flame Velocity for Components of Natural Gas

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    flame velocity of components of natural gas, methane, ethane, propane, and nbutane as well as of binary% by volume (1). The laminar flame velocities of methane/air, ethane/air, and propane/air mixtures have on a plenum chamber with the radial temperature distribution measurement made by a series of thermocouples

  7. Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon flamesq

    E-Print Network [OSTI]

    Senkan, Selim M.

    The formation of soot in premixed flames of methane, ethane, propane, and butane was studied at three different particle diameters at higher distances above the burner surface and propane, ethane, and butane flames came conditions in humans. Polycyclic aromatic hydro- carbons (PAH), the largest class of chemical carcinogens

  8. Reading Out Visual Information from Populations of Neurons in ITC and PFC Ethan Meyers1,2, David Freedman3,4, Earl Miller1,3, Gabriel Kreiman2,5, Tomaso Poggio1,2

    E-Print Network [OSTI]

    Kreiman, Gabriel

    Reading Out Visual Information from Populations of Neurons in ITC and PFC Ethan Meyers1,2, David were trained on the firing rates of 256 randomly chosen neurons from either ITC or PFC (only neurons/trial choice) is the main statistic we report. 443 ITC, 525 PFC neurons were recording from two rhesus macaque

  9. Catalytic dehydrogenation of ethane

    E-Print Network [OSTI]

    Place, Harold Glenn

    1955-01-01T23:59:59.000Z

    -Grew-Hill Pub. Co? 1950 ' Frey, F. E. and Huppke, W. F. , Ind. Ehg. Chem. , 25, 54 (1933). Burgin& J. , Gr oil& H. , and Roberts& R M & Nat'1. Petr. News, 30, R 432 (1938). Grosse, A. V. and Ipatieff, V. N. , Ind. ~En . Chem. , 32, (19) Riess, C. H...) Brooks, F. R. , et al. , Anal. Chem. , 21, 1105 (1949). (26) Johanson, L. N. and Watson, K. M , Nat'1. Petr. Neve, 1946. For Runs 1, 2, 3, and Composite Sample, conditions were the same, as follows: Flow rate - 0. 0515 cfm, mass of catalyst - 33. 5...

  10. Ethane/Ethylene Exports

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688Electricity Use as an IndicatorNatural GasRevenueMay9 70

  11. Direct growth of few-layer graphene on 6H-SiC and 3C-SiC/Si via propane chemical vapor deposition

    SciTech Connect (OSTI)

    Michon, A.; Vezian, S.; Portail, M. [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France); Ouerghi, A. [CNRS-LPN, Route de Nozay, 91460 Marcoussis (France); Zielinski, M.; Chassagne, T. [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)

    2010-10-25T23:59:59.000Z

    We propose to grow graphene on SiC by a direct carbon feeding through propane flow in a chemical vapor deposition reactor. X-ray photoemission and low energy electron diffraction show that propane allows to grow few-layer graphene (FLG) on 6H-SiC(0001). Surprisingly, FLG grown on (0001) face presents a rotational disorder similar to that observed for FLG obtained by annealing on (000-1) face. Thanks to a reduced growth temperature with respect to the classical SiC annealing method, we have also grown FLG/3C-SiC/Si(111) in a single growth sequence. This opens the way for large-scale production of graphene-based devices on silicon substrate.

  12. Nanostructure of Solid Precipitates Obtained by Expansion of Polystyrene-block-Polybutadiene Solutions in Near Critical Propane: Block Ratio and Micellar Solution Effects

    SciTech Connect (OSTI)

    Green, Jade [University of Wyoming, Laramie; Tyrrell, Zachary [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

    2011-01-01T23:59:59.000Z

    In contrast to incompressible liquid solutions, compressible near-critical solutions of block copolymers allow for controlling rapid structure transformations with pressure alone. For example, when dissolved in near-critical propane, polystyrene-block-polybutadiene can form a random molecular solution at high pressures, a micellar solution at moderate pressures, and a solvent-free precipitate at low pressures. In contrast to the unstructured virgin copolymer, such a propane-treated precipitate rapidly self-assembles toward structures characteristic of equilibrated block copolymers, such as lamellae, spheres, or cylinders, which depend on the block ratio rather than on the decompression rate or temperature, at least within the rate and temperature ranges investigated in this work. At lower temperatures, however, say below 40 C, glass transition of the styrene-butadiene diblocks can inhibit independent structure formation, while crystallization of their hydrogenated-butadiene analogues can preserve the micellar-solution structure.

  13. Deuteration Can Impact Micellization Pressure and Cloud Pressure of Polystyrene-block-polybutadiene and Polystyrene-block-polyisoprene in Compressible Propane

    SciTech Connect (OSTI)

    Winoto, Winoto [University of Wyoming, Laramie; Shen, Youqin [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

    2009-01-01T23:59:59.000Z

    The deuterated homopolymers and their corresponding polystyrene-block-polybutadiene and polystyrene-block-polyisoprene copolymers require lower cloud pressures than their hydrogenous analogues to dissolve in a compressible alkane solvent, such as propane. For symmetric diblocks, deuteration reduces the micellization pressure. By contrast, for asymmetric diblocks with a long diene block relative to the styrene block, deuteration can increase the micellization pressure. All in all, however, the deuteration effects, while measurable, do not qualitatively change the principal diblock properties in compressible propane solutions, such as pressure-induced micelle decomposition, micelle formation and micelle size, and their temperature dependence. Therefore, isotope labeling should be a useful approach to neutron-scattering characterization for styrene-diene block copolymers in compressible alkane systems.

  14. H-gallosilicate (MFI) propane aromatization catalyst: Influence of Si/Ga ratio on acidity, activity and deactivation due to coking

    SciTech Connect (OSTI)

    Choudhary, V.R.; Kinage, A.K.; Sivadinarayana, C. [National Chemical Lab., Pune (India)] [and others] [National Chemical Lab., Pune (India); and others

    1996-01-01T23:59:59.000Z

    Influence of bulk Si/Ga ratio of H-gallosilicate (MFI) on its degalliation (during calcination for removal of template and deammoniation of NH{sub 4} form), acidity/acid strength distribution (measured by stepwise thermal desorption and chemisorption of pyridine at 50-400{degrees}C using GC techniques and also by acid catalyzed model reactions viz. iso-octane cracking and toluene disproportionation) and initial activity/product selectivity and catalyst deactivation in propane aromatization (at 550{degrees}C) has been investigated. Framework Si/Ga ratio was measured by {sup 29}Si MAS NMR. Information on the external acid sites is obtained by isooctane cracking. The influence of poisoning of strong acid sites (by pyridine) on acid catalyzed model reactions and the effect of deactivation on the product distribution in the propane aromatization have also been studied. 21 refs., 19 figs., 3 tabs.

  15. Acid strength of support materials as a factor controlling oxidation state of palladium catalyst for propane combustion

    SciTech Connect (OSTI)

    Yazawa, Yoshiteru; Yoshida, Hisao; Takagi, Nobuyuki; Komai, Shinichi; Satsuma, Atsushi; Hattori, Tadashi

    1999-10-01T23:59:59.000Z

    The support effect on the low temperature catalytic combustion of propane over palladium catalyst was studied by using a series of metal oxides as support materials: MgO, ZrO{sub 2}, Al{sub 2}O{sub 3}, SiO{sub 2}, SiO{sub 2}-ZrO{sub 2}, SiO{sub 2}-Al{sub 2}O{sub 3}, and SO{sub 4}{sup 2{minus}}-ZrO{sub 2}. The catalytic activity varied with the kind of support materials; a support material with moderate acid strength gave maximum conversion. In order to discuss more details, 5 wt% Pd/ZrO{sub 2}, Pd/Al{sub 2}O{sub 3}, and Pd/SiO{sub 2}-Al{sub 2}O{sub 3} were subjected to catalytic testing under the various conditions, and the catalysts after the test were characterized by XRD and XPS. The activity changed with the oxygen concentration, and the concentration providing the maximum activity depended on the support material. The maximum activity was obtained at high concentration on Pd/SiO{sub 2}-Al{sub 2}O{sub 3}, at moderate concentration on Pd/Al{sub 2}O{sub 3}, and at low concentration on Pd/ZrO{sub 2}. This sequence corresponded to that of acid strength of the support materials measured by Hammett indicators. The relation between the oxidation state of palladium and its catalytic activity under the various mixtures indicated that the catalytic activity on each catalyst depends on the oxidation state of palladium, and that partially oxidized palladium is effective for propane combustion. Moreover, palladium on acidic support kept the metallic state even under high oxygen concentration, indicating that acidic support gives palladium the resistibility against oxidation. These results suggest one guideline for the design of active palladium catalyst; an acidic support must be chosen under the mixture of the higher oxygen concentration and vice versa.

  16. TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2006-07-06T23:59:59.000Z

    This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating agent overestimate the value of the VOCs in a sample. By overestimating the VOC content of a sample, we want to minimize false negatives. A false negative is defined as incorrectly estimating the VOC content of the sample to be below programmatic action limits when, in fact, the sample,exceeds the action limits. The disadvantage of overestimating the flammable VOC content of a sample is that additional cost may be incurred because additional sampling and GC-MS analysis may be required to confirm results over programmatic action limits. Therefore, choosing an appropriate calibration standard for the Ar-PDHID is critical to avoid false negatives and to minimize additional analytical costs.

  17. Vanadium oxide based nanostructured materials for catalytic oxidative dehydrogenation of propane : effect of heterometallic centers on the catalyst performance.

    SciTech Connect (OSTI)

    Khan, M. I.; Deb, S.; Aydemir, K.; Alwarthan, A. A.; Chattopadhyay, S.; Miller, J. T.; Marshall, C. L. (Chemical Sciences and Engineering Division); (Illinois Inst. of Tech.); (King Saud Univ.)

    2010-01-01T23:59:59.000Z

    Catalytic properties of a series of new class of catalysts materials-[Co{sub 3}(H{sub 2}O){sub 12}V{sub 18}O{sub 42} (XO{sub 4})].24H{sub 2}O (VNM-Co), [Fe{sub 3}(H{sub 2}O){sub 12}V{sub 18}O{sub 42}(XO{sub 4})].24H{sub 2}O (VNM-Fe) (X = V, S) and [H{sub 6}Mn{sub 3}(H{sub 2}O){sub 12}V{sub 18}O{sub 42}(VO{sub 4})].30H{sub 2}O for the oxidative dehydrogenation of propane is studied. The open-framework nanostructures in these novel materials consist of three-dimensional arrays of {l_brace}V{sub 18}O{sub 42}(XO{sub 4}){r_brace} (X = V, S) clusters interconnected by {l_brace}-O-M-O-{r_brace} (M = Mn, Fe, Co) linkers. The effect of change in the heterometallic center M (M = Mn, Co, Fe) of the linkers on the catalyst performance was studied. The catalyst material with Co in the linker showed the best performance in terms of propane conversion and selectivity at 350 C. The material containing Fe was most active but least selective and Mn containing catalyst was least active. The catalysts were characterized by Temperature Programmed Reduction (TPR), BET surface area measurement, Diffuse Reflectance Infrared Fourier Transform Spectroscopy, and X-ray Absorption Spectroscopy. TPR results show that all three catalysts are easily reducible and therefore are active at relatively low temperature. In situ X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure spectroscopy (EXAFS) studies revealed that the oxidation state of Co(II) remained unchanged up to 425 C (even after pretreatment). The reduction of Co(II) into metallic form starts at 425 C and this process is completed at 600 C.

  18. Performance and Emissions Characteristics of Bio-Diesel (B100)-Ignited Methane and Propane Combustion in a Four Cylinder Turbocharged Compression Ignition Engine

    SciTech Connect (OSTI)

    Shoemaker, N. T.; Gibson, C. M.; Polk, A. C.; Krishnan, S. R.; Srinivasan, K. K.

    2011-10-05T23:59:59.000Z

    Different combustion strategies and fuel sources are needed to deal with increasing fuel efficiency demands and emission restrictions. One possible strategy is dual fueling using readily available resources. Propane and natural gas are readily available with the current infrastructure and biodiesel is growing in popularity as a renewable fuel. This paper presents experimental results from dual fuel combustion of methane (as a surrogate for natural gas) and propane as primary fuels with biodiesel pilots in a 1.9 liter, turbocharged, 4 cylinder diesel engine at 1800 rev/min. Experiments were performed with different percentage energy substitutions (PES) of propane and methane and at different brake mean effective pressures (BMEP/bmep). Brake thermal efficiency (BTE) and emissions (NOx, HC, CO, CO2, O2 and smoke) were also measured. Maximum PES levels for B100-methane dual fuelling were limited to 70% at 2.5 bar bmep and 48% at 10 bar bmep, and corresponding values for B100-propane dual fuelling were 64% and 43%, respectively. Maximum PES was limited by misfire at 2.5 bar bmep and the onset of engine knock at 10 bar bmep. Dual fuel BTEs approached straight B100 values at 10 bar bmep while they were significantly lower than B100 values at 2.5 bar bmep. In general dual fuelling was beneficial in reducing NOx and smoke emissions by 33% and 50%, respectively from baseline B100 levels; however, both CO and THC emissions were significantly higher than baseline B100 levels at all PES and loads.

  19. Effects of pressure, temperature, and hydrogen during graphene growth on SiC(0001) using propane-hydrogen chemical vapor deposition

    SciTech Connect (OSTI)

    Michon, A.; Vezian, S.; Roudon, E.; Lefebvre, D.; Portail, M. [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France)] [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France); Zielinski, M.; Chassagne, T. [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)] [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)

    2013-05-28T23:59:59.000Z

    Graphene growth from a propane flow in a hydrogen environment (propane-hydrogen chemical vapor deposition (CVD)) on SiC differentiates from other growth methods in that it offers the possibility to obtain various graphene structures on the Si-face depending on growth conditions. The different structures include the (6{radical}3 Multiplication-Sign 6{radical}3)-R30 Degree-Sign reconstruction of the graphene/SiC interface, which is commonly observed on the Si-face, but also the rotational disorder which is generally observed on the C-face. In this work, growth mechanisms leading to the formation of the different structures are studied and discussed. For that purpose, we have grown graphene on SiC(0001) (Si-face) using propane-hydrogen CVD at various pressure and temperature and studied these samples extensively by means of low energy electron diffraction and atomic force microscopy. Pressure and temperature conditions leading to the formation of the different structures are identified and plotted in a pressure-temperature diagram. This diagram, together with other characterizations (X-ray photoemission and scanning tunneling microscopy), is the basis of further discussions on the carbon supply mechanisms and on the kinetics effects. The entire work underlines the important role of hydrogen during growth and its effects on the final graphene structure.

  20. Effect of heat recirculation on the self-sustained catalytic combustion of propane/air mixtures in a quartz reactor

    SciTech Connect (OSTI)

    Scarpa, A. [Dipartimento di Ingegneria Chimica, Universita degli Studi di Napoli ''Federico II'', P.le V. Tecchio 80, 80125 Naples (Italy); Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), and Center for Composite Materials (CCM), University of Delaware, 150 Academy Street, Newark, DE 19716 (United States); Pirone, R. [Istituto di Ricerche sulla Combustione-CNR, P.le V. Tecchio 80, 80125 Naples (Italy); Russo, G. [Dipartimento di Ingegneria Chimica, Universita degli Studi di Napoli ''Federico II'', P.le V. Tecchio 80, 80125 Naples (Italy); Vlachos, D.G. [Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), and Center for Composite Materials (CCM), University of Delaware, 150 Academy Street, Newark, DE 19716 (United States)

    2009-05-15T23:59:59.000Z

    The self-sustained catalytic combustion of propane is experimentally studied in a two-pass, quartz heat-recirculation reactor (HRR) and compared to that in a no (heat) recirculation reactor (NRR). Structured monolithic reactors with Pt/{gamma}-Al{sub 2}O{sub 3}, LaMnO{sub 3}/{gamma}-Al{sub 2}O{sub 3}, and Pt doped perovskite catalysts have been compared in the HRR and NRR configurations. Heat recirculation enhances combustion stability, by widening the operating window of self-sustained operation, and changes the mode of stability loss from blowout to extinction. It is found that thermal shields (upstream and downstream of the monolith) play no role in the stability of a HRR but increase the stability of a NRR. The stability of a HRR follows this trend: Pt/{gamma}-Al{sub 2}O{sub 3} > doped perovskite > LaMnO{sub 3}/{gamma}-Al{sub 2}O{sub 3}. Finally, a higher cell density monolith enlarges the operating window of self-sustained combustion, and allows further increase of the power density of the process. (author)

  1. Synthesis of Pt?Pd Core?Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene

    SciTech Connect (OSTI)

    Lei, Y.; Liu, Bin; Lu, Junling; Lobo-Lapidus, Rodrigo J.; Wu, Tianpin; Feng, Hao; Xia, Xiaoxing; Mane, Anil U.; Libera, Joseph A.; Greeley, Jeffrey P.; Miller, Jeffrey T.; Elam, J. W.

    2012-08-20T23:59:59.000Z

    Atomic layer deposition (ALD) was employed to synthesize supported Pt?Pd bimetallic particles in the 1 to 2 nm range. The metal loading and composition of the supported Pt?Pd nanoparticles were controlled by varying the deposition temperature and by applying ALD metal oxide coatings to modify the support surface chemistry. Highresolution scanning transmission electron microscopy images showed monodispersed Pt?Pd nanoparticles on ALD Al2O3 - and TiO2 -modi?ed SiO2 gel. X-ray absorption spectroscopy revealed that the bimetallic nanoparticles have a stable Pt-core, Pd-shell nanostructure. Density functional theory calculations revealed that the most stable surface con?guration for the Pt? Pd alloys in an H2 environment has a Pt-core, Pd-shell nanostructure. In comparison to their monometallic counterparts, the small Pt?Pd bimetallic core?shell nanoparticles exhibited higher activity in propane oxidative dehydrogenation as compared to their physical mixture.

  2. Dynamic light scattering in sooting premixed atmospheric-pressure methane-, propane-, ethene-, and propene-oxygen flames

    SciTech Connect (OSTI)

    Lamprecht, A.; Eimer, W.; Kohse-Hoeinghaus, K. [Univ. Bielefeld (Germany)] [Univ. Bielefeld (Germany)

    1999-07-01T23:59:59.000Z

    In a systematic investigation under well-defined flame conditions, dynamic light scattering (DLS) was applied to the determination of soot particle radii with the aim of examining the suitability of this technique for accurate soot particle sizing. In particular, flat premixed methane-, propane-, ethene-, and propene-oxygen flames at atmospheric pressure were investigated, and particle sizes were obtained as a function of stoichiometry and height above the burner surface. In combination with absorption measurements, soot volume fraction and particle number density were determined; also, the temperature was measured at each flame condition. In comparison to absorption techniques, attractive features of DLS are its independence of the particle refractive index and its insensitivity to fluorescence interference; also, it offers spatial resolution. In principle, additional information on the particle size distribution as well as on the global shape of the particles may be obtained from DLS experiments. This study is therefore an evaluation of the potential of DLS as a complement to other soot diagnostic techniques.

  3. Utilize Cementitious High Carbon Fly Ash (CHCFA) to Stabilize Cold In-Place Recycled (CIR) Asphalt Pavement as Base Coarse

    SciTech Connect (OSTI)

    Wen, Haifang; Li, Xiaojun; Edil, Tuncer; O'Donnell, Jonathan; Danda, Swapna

    2011-02-05T23:59:59.000Z

    The purpose of this study was to evaluate the performance of cementitious high carbon fly ash (CHCFA) stabilized recycled asphalt pavement as a base course material in a real world setting. Three test road cells were built at MnROAD facility in Minnesota. These cells have the same asphalt surface layers, subbases, and subgrades, but three different base courses: conventional crushed aggregates, untreated recycled pavement materials (RPM), and CHCFA stabilized RPM materials. During and after the construction of the three cells, laboratory and field tests were carried out to characterize the material properties. The test results were used in the mechanistic-empirical pavement design guide (MEPDG) to predict the pavement performance. Based on the performance prediction, the life cycle analyses of cost, energy consumption, and greenhouse gasses were performed. The leaching impacts of these three types of base materials were compared. The laboratory and field tests showed that fly ash stabilized RPM had higher modulus than crushed aggregate and RPM did. Based on the MEPDG performance prediction, the service life of the Cell 79 containing fly ash stabilized RPM, is 23.5 years, which is about twice the service life (11 years) of the Cell 77 with RPM base, and about three times the service life (7.5 years) of the Cell 78 with crushed aggregate base. The life cycle analysis indicated that the usage of the fly ash stabilized RPM as the base of the flexible pavement can significantly reduce the life cycle cost, the energy consumption, the greenhouse gases emission. Concentrations of many trace elements, particularly those with relatively low water quality standards, diminish over time as water flows through the pavement profile. For many elements, concentrations below US water drinking water quality standards are attained at the bottom of the pavement profile within 2-4 pore volumes of flow.

  4. Propane ammoxidation over the Mo-V-Te-Nb-O M1 phase: Reactivity of surface cations in hydrogen abstraction steps

    SciTech Connect (OSTI)

    Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

    2011-01-01T23:59:59.000Z

    Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C3 (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo-V-Te-Nb-O M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, {Delta}E, being {le} -1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo-O-V and Mo-O-Mo), and empty metal apical sites ({Delta}E > -1 eV). Atomic H binds more strongly to Te = O ({Delta}E {le} -3 eV) than to all the other sites, including V = O ({Delta}E = -2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E{sub a} {le} 1.01 eV) than V = O (E{sub a} = 1.70 eV on V{sup 5+} = O and 2.13 eV on V{sup 4+} = O). The higher-than-observed activity and the loose binding of Te = O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te = O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.

  5. Rutting Performance of Airport Hot-Mix Asphalt Characterized by Laboratory Performance Testing, Full-Scale Accelerated Pavement Testing, and Finite Element Modeling

    E-Print Network [OSTI]

    Rushing, John Ford

    2014-04-25T23:59:59.000Z

    California Bearing Ratio DoD Department of Defense DSR Dynamic Shear Rheometer ERDC U.S. Army Engineer Research and Development Center FAA Federal Aviation Administration FN flow number FT flow time HMA Hot Mix Asphalt HVS heavy vehicle simulator... aircraft continue to necessitate modifications in the procedures by which HMA mixtures are designed so that rutting does not become a prevalent distress on airport pavements. The Federal Aviation Administration (FAA) has predominantly required use...

  6. Shock tube and theoretical studies on the thermal decomposition of propane : evidence for a roaming radical channel.

    SciTech Connect (OSTI)

    Sivaramakrishnan, R.; Su, M.-C.; Michael, J. V.; Klippenstein, S. J.; Harding, L. B.; Ruscic, B. (Chemical Sciences and Engineering Division)

    2011-04-21T23:59:59.000Z

    The thermal decomposition of propane has been studied using both shock tube experiments and ab initio transition state theory-based master equation calculations. Dissociation rate constants for propane have been measured at high temperatures behind reflected shock waves using high-sensitivity H-ARAS detection and CH{sub 3} optical absorption. The two major dissociation channels at high temperature are C{sub 3}H{sub 8} {yields} CH{sub 3} + C{sub 2}H{sub 5} (eq 1a) and C{sub 3}H{sub 8} {yields} CH{sub 4} + C{sub 2}H{sub 4} (eq 1b). Ultra high-sensitivity ARAS detection of H-atoms produced from the decomposition of the product, C{sub 2}H{sub 5}, in (1a), allowed measurements of both the total decomposition rate constants, k{sub total}, and the branching to radical products, k{sub 1a}/k{sub total}. Theoretical analyses indicate that the molecular products are formed exclusively through the roaming radical mechanism and that radical products are formed exclusively through channel 1a. The experiments were performed over the temperature range 1417-1819 K and gave a minor contribution of (10 {+-} 8%) due to roaming. A multipass CH{sub 3} absorption diagnostic using a Zn resonance lamp was also developed and characterized in this work using the thermal decomposition of CH{sub 3}I as a reference reaction. The measured rate constants for CH{sub 3}I decomposition agreed with earlier determinations from this laboratory that were based on I-atom ARAS measurements. This CH{sub 3} diagnostic was then used to detect radicals from channel 1a allowing lower temperature (1202-1543 K) measurements of k1a to be determined. Variable reaction coordinate-transition state theory was used to predict the high pressure limits for channel (1a) and other bond fission reactions in C{sub 3}H{sub 8}. Conventional transition state theory calculations were also used to estimate rate constants for other tight transition state processes. These calculations predict a negligible contribution (<1%) from all other bond fission and tight transition state processes, indicating that the bond fission channel (1a) and the roaming channel (1b) are indeed the only active channels at the temperature and pressure ranges of the present experiments. The predicted reaction exo- and endothermicities are in excellent agreement with the current version of the Active Thermochemical Tables. Master equation calculations incorporating these transition state theory results yield predictions for the temperature and pressure dependence of the dissociation rate constants for channel 1a. The final theoretical results reliably reproduce the measured dissociation rate constants that are reported here and in the literature. The experimental data are well reproduced over the 500-2500 K and 1 x 10{sup -4} to 100 bar range (errors of {approx}15% or less) by the following Troe parameters for Ar as the bath gas: k{sub {infinity}} = 1.55 x 10{sup 24}T{sup -2.034} exp(-45490/T) s{sup -1}, k{sub 0} = 7.92 x 10{sup 53}T{sup -16.67} exp(-50380/T) cm{sup 3} s{sup -1}, and F{sub c} = 0.190 exp(-T/3091) + 0.810 exp(-T/128) + exp(-8829/T).

  7. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

    2011-12-15T23:59:59.000Z

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  8. SaltRx HT -Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0

    E-Print Network [OSTI]

    Hill, Chris

    SaltRx HT - Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0 A2. 0.1 M Bis-Tris Propane pH 7.0, 2.8 M Sodium Acetate pH 7.0 A3. 0.1 M Sodium Acetate pH 4.6, 1.5 M Ammonium Chloride A4. 0.1 M Bis-Tris Propane pH 7.0, 1.5 M Ammonium Chloride A5. 0.1 M Tris pH 8.5, 1.5 M Ammonium

  9. Structures, Mechanisms, and Kinetics of Ammoxidation and Selective Oxidation of Propane Over the M2 Phase of MoVNbTeO Catalysts

    SciTech Connect (OSTI)

    Goddard, William A. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Liu, Lianchi [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Mueller, Jonathan E. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Pudar, Sanja [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Nielsen, Robert J. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center

    2011-07-01T23:59:59.000Z

    We report here first-principles-based predictions of the structures, mechanisms, and activation barriers for propane activation by the M2 phase of the MoVNbTeO multi-metal oxide catalysts capable of the direct conversion of propane to acrylonitrile. Our approach is to combine extensive quantum mechanical (QM) calculations to establish the mechanisms for idealized representations of the surfaces for these catalytic systems and then to modify the parameters in the ReaxFF reactive force field for molecular dynamics (MD) calculations to describe accurately the activation barriers and reaction mechanisms of the chemical reactions over complex mixed metal oxides. The parameters for ReaxFF are derived entirely from QM without the use of empirical data so that it can be applied to novel systems on which there is little or no data. To understand the catalysis in these systems it is essential to determine the surface structures that control the surface chemistry. High quality three-dimensional (3D) Rietveld structures are now available for the M1 and M2 phases of the MoVNbTeO catalysts.

  10. Dynamics of Propane in Silica Mesopores Formed upon PropyleneHydrogenation over Pt Nanoparticles by Time-Resolved FT-IRSpectroscopy

    SciTech Connect (OSTI)

    Waslylenko, Walter; Frei, Heinz

    2007-01-31T23:59:59.000Z

    Propylene hydrogenation over Pt nanoparticles supported onmesoporous silica type SBA-15 was monitored by time-resolved FT-IRspectroscopy at 23 ms resolution using short propylene gas pulses thatjoined a continuous flow of hydrogen in N2 (1 atm total pressure).Experiments were conducted in the temperature range 323-413 K. Propanewas formed within 100 milliseconds or faster. The CH stretching regionrevealed distinct bands for propane molecules emerging inside thenanoscale channels of the silica support. Spectral analysis gave thedistribution of the propane product between support and surrounding gasphase as function of time. Kinetic analysis showed that the escape ofpropane molecules from the channels occurred within hundreds ofmilliseconds (3.1 + 0.4 s-1 at 383 K). A steady state distribution ofpropane between gas phase and mesoporous support is established as theproduct is swept from the catalyst zone by the continuous flow ofhydrogen co-reactant. This is the first direct spectroscopic observationof emerging products of heterogeneous catalysis on nanoporous supportsunder reaction conditions.

  11. Propane/Propylene Exports

    Gasoline and Diesel Fuel Update (EIA)

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  12. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

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  13. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

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  14. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

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  15. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

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  16. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

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  17. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  18. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  19. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  20. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  1. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  2. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  3. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  4. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  5. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  6. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  7. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

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  8. Residential propane price increases

    Gasoline and Diesel Fuel Update (EIA)

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  9. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

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  10. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

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  11. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

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  12. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

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  13. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

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  14. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

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  15. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

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  16. Residential propane prices stable

    Gasoline and Diesel Fuel Update (EIA)

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  17. Residential propane prices stable

    Gasoline and Diesel Fuel Update (EIA)

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  18. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

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  19. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

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  20. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

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