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Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
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1

Preventing ash agglomeration during gasification of high-sodium lignite  

Science Conference Proceedings (OSTI)

Various additives were evaluated to assess their ability to prevent ash agglomeration during the gasification of high-sodium lignite. Additives that showed promise in simple muffle furnace tests included meta-kaolin, vermiculite, two types of silica fume, and one type of bauxite. Additives that were tested and rejected included dolomite, calcite, sand flour, kaolinite, fine kaolin, and calcined bauxite. Based on the muffle furnace test results, the meta-kaolin was selected for a follow-on demonstration in a pilot-scale coal gasifier. Pilot-scale testing showed that the addition of coarse (minus 14-mesh, 920-{mu}m mean size) meta-kaolin at a feed rate roughly equivalent to the ash content of the lignite (10 wt %) successfully prevented agglomeration and deposition problems during gasification of high-sodium lignite at a maximum operating temperature of 927{sup o}C (1700{sup o}F). 13 refs., 24 figs., 1 tab.

Robert S. Dahlin; Johnny R. Dorminey; WanWang Peng; Roxann F. Leonard; Pannalal Vimalchand [Southern Research Institute and Southern Company Services, Wilsonville, AL (USA). Power Systems Development Facility

2009-01-15T23:59:59.000Z

2

HIGH SODIUM SIMULANT TESTING TO SUPPORT SB8 SLUDGE PREPARATION  

Science Conference Proceedings (OSTI)

Scoping studies were completed for high sodium simulant SRAT/SME cycles to determine any impact to CPC processing. Two SRAT/SME cycles were performed with simulant having sodium supernate concentration of 1.9M at 130% and 100% of the Koopman Minimum Acid requirement. Both of these failed to meet DWPF processing objectives related to nitrite destruction and hydrogen generation. Another set of SRAT/SME cycles were performed with simulant having a sodium supernate concentration of 1.6M at 130%, 125%, 110%, and 100% of the Koopman Minimum Acid requirement. Only the run at 110% met DWPF processing objectives. Neither simulant had a stoichiometric factor window of 30% between nitrite destruction and excessive hydrogen generation. Based on the 2M-110 results it was anticipated that the 2.5M stoichiometric window for processing would likely be smaller than from 110-130%, since it appeared that it would be necessary to increase the KMA factor by at least 10% above the minimum calculated requirement to achieve nitrite destruction due to the high oxalate content. The 2.5M-130 run exceeded the DWPF hydrogen limits in both the SRAT and SME cycle. Therefore, testing of this wash endpoint was halted. This wash endpoint with this minimum acid requirement and mercury-noble metal concentration profile appears to be something DWPF should not process due to an overly narrow window of stoichiometry. The 2M case was potentially processable in DWPF, but modifications would likely be needed in DWPF such as occasionally accepting SRAT batches with undestroyed nitrite for further acid addition and reprocessing, running near the bottom of the as yet ill-defined window of allowable stoichiometric factors, potentially extending the SRAT cycle to burn off unreacted formic acid before transferring to the SME cycle, and eliminating formic acid additions in the frit slurry.

Newell, J.

2012-09-19T23:59:59.000Z

3

SODIUM POLYPHOSPHATE-MODIFIED CLASS C/CLASS F FLY ASH BLEND CEMENTS FOR GEOTHERMAL WELLS.  

DOE Green Energy (OSTI)

The authors investigated the usefulness of the coal combustion by-products, Class C fly ash (C) and Class F fly ash (F), in developing cost-effective acid-resistant phosphate-based cements for geothermal wells. In the temperature range of 20-100 C, sodium polyphosphate (NaP) as the acidic cement-forming solution preferentially reacted with calcium sulfate and lime in the C as the base solid reactant through the exothermic acid-base reaction route, rather than with the tricalcium aluminate in C. This reaction led to the formation of hydroxyapatite (HOAp). In contrast, there was no acid-base reaction between the F as the acidic solid reactant and NaP. After autoclaving the cements at 250 C, a well-crystallized HOAp phase was formed in the NaP-modified C cement that was responsible for densifying the cement's structure, thereby conferring low water permeability and good compressive strength on the cement. however, the HOAp was susceptible to hot CO{sub 2}-laden H{sub 2}SO{sub 4} solution (pH 1.1), allowing some acid erosion of the cement. On the other hand, the mullite in F hydrothermally reacted with the Na from NaP to form the analcime phase. Although this phase played a pivotal role in abating acid erosion, its generation created an undesirable porous structure in the cement. They demonstrated that blending fly ash with a C/F ratio of 70/30 resulted in the most suitable properties for acid-resistant phosphate-based cement systems.

SUGAMA, T.; BROTHERS, L.E.; KASPEREIT, D.

2006-02-01T23:59:59.000Z

4

Time-course analysis of the Shewanella amazonensis SB2B proteome in response to sodium chloride shock  

SciTech Connect

Organisms in the genus Shewanella have become models for response to environmental stress. One of the most important environmental stresses is change in osmolarity. In this study, we experimentally determine the response mechanisms of Shewanella amazonensis SB2B during osmotic stress. Osmotic stress in SB2B was induced through exposure to NaCl, and the time-course proteomics response was measured using liquid chromatography mass spectrometry. Protein trends were qualitatively compared to gene expression trends and to phenotypic characterization. Osmotic stress affects motility, and has also been associated with a change in the membrane fatty acid composition (due to induction of branched chain amino acid degradation pathways); however, we show this is not the case for SB2B. Although proteins and genes involved with branched chain amino acid degradation are induced, fatty acid degradation pathways are not induced and no change in the fatty acid profile occurs in SB2B as a result of osmotic shock. The most extensive response of SB2B over the time course of acclimation to high salt involves an orchestrated sequence of events comprising increased expression of signal transduction associated with motility and restricted cell division and DNA replication. After SB2B has switched to increased branched chain amino acid degradation, motility, and cellular replication proteins return to pre-perturbed levels.

Parnell, John J.; Callister, Stephen J.; Rompato, Giovanni; Nicora, Carrie D.; Pasa-Tolic, Ljiljana; Williamson, Ashley; Pfrender, Michael E.

2011-06-29T23:59:59.000Z

5

Sodium  

SciTech Connect

Some of the properties of sodium are reviewed, particularly its properties which make it useful as a FBR coolant. The FFTF and other sodium research facilities at HEDL are described. (DLC)

1979-09-27T23:59:59.000Z

6

FLY ASH GENERATION AND UTILIZATION -AN OVERVIEW* Tarun R. Naik, Ph.D., P.E.  

E-Print Network (OSTI)

a sodium-based sorbent such as sodium bicarbonate, soda ash, trona, or nahcalite (ICF Northwest, 1988). By

Wisconsin-Milwaukee, University of

7

Ash Deposit Physical and Chemical Analysis  

Science Conference Proceedings (OSTI)

This report focuses on identifying ash deposit materials and mounting them to a heat transfer surface for further study. A group of synthetic slag of various compositions was also produced using a sodium silicate binder, Powder River Basin (PRB) bottom ash, and ash cenospheres for porosity to test the effects of pulse detonation techniques on the removal of ash deposits.

2010-12-17T23:59:59.000Z

8

Deborah Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

Deborah Rebecca Ash Deborah Ash Energy Analysis and Environmental Impacts Department Energy Efficiency Standards Group Lawrence Berkeley National Laboratory 1 Cyclotron Road MS...

9

White Ash Biology  

NLE Websites -- All DOE Office Websites (Extended Search)

White Ash Biology Name: blondi Location: NA Country: NA Date: NA Question: 1. Is the white ash tree endangered or is it a protected variety? 2. How does the white ash tree...

10

DWPF simulant CPC studies for SB8  

SciTech Connect

The Savannah River National Laboratory (SRNL) accepted a technical task request (TTR) from Waste Solidification Engineering to perform simulant tests to support the qualification of Sludge Batch 8 (SB8) and to develop the flowsheet for SB8 in the Defense Waste Processing Facility (DWPF). These efforts pertained to the DWPF Chemical Process Cell (CPC). Separate studies were conducted for frit development and glass properties (including REDOX). The SRNL CPC effort had two primary phases divided by the decision to drop Tank 12 from the SB8 constituents. This report focuses on the second phase with SB8 compositions that do not contain the Tank 12 piece. A separate report will document the initial phase of SB8 testing that included Tank 12. The second phase of SB8 studies consisted of two sets of CPC studies. The first study involved CPC testing of an SB8 simulant for Tank 51 to support the CPC demonstration of the washed Tank 51 qualification sample in the SRNL Shielded Cells facility. SB8-Tank 51 was a high iron-low aluminum waste with fairly high mercury and moderate noble metal concentrations. Tank 51 was ultimately washed to about 1.5 M sodium which is the highest wash endpoint since SB3-Tank 51. This study included three simulations of the DWPF Sludge Receipt and Adjustment Tank (SRAT) cycle and Slurry Mix Evaporator (SME) cycle with the sludge-only flowsheet at nominal DWPF processing conditions and three different acid stoichiometries. These runs produced a set of recommendations that were used to guide the successful SRNL qualification SRAT/SME demonstration with actual Tank 51 washed waste. The second study involved five SRAT/SME runs with SB8-Tank 40 simulant. Four of the runs were designed to define the acid requirements for sludge-only processing in DWPF with respect to nitrite destruction and hydrogen generation. The fifth run was an intermediate acid stoichiometry demonstration of the coupled flowsheet for SB8. These runs produced a set of processing recommendations for DWPF along with some data related to Safety Class documentation at DWPF. Some significant observations regarding SB8 follow: Reduced washing in Tank 51 led to an increase in the wt.% soluble solids of the DWPF feed. If wt.% total solids for the SRAT and SME product weren’t adjusted upward to maintain insoluble solids levels similar to past sludge batches, then the rheological properties of the slurry went below the low end of the DWPF design bases for the SRAT and SME. Much higher levels of dissolved manganese were found in the SRAT and SME products than in recent sludge batches. Closed crucible melts were more reduced than expected. The working hypothesis is that the soluble Mn is less oxidizing than assumed in the REDOX calculations. A change in the coefficient for Mn in the REDOX equation was recommended in a separate report. The DWPF (Hsu) stoichiometric acid equation was examined in detail to better evaluate how to control acid in DWPF. The existing DWPF equation can likely be improved without changing the required sample analyses through a paper study using existing data. The recommended acid stoichiometry for initial SB8 SRAT batches is 115-120% stoichiometry until some processing experience is gained. The conservative range (based on feed properties) of stoichiometric factors derived in this study was from 110-147%, but SRNL recommends using only the lower half of this range, 110-126% even after initial batches provide processing experience. The stoichiometric range for sludge-only processing appears to be suitable for coupled operation based on results from the run in the middle of the range. Catalytic hydrogen was detectable (>0.005 vol%) in all SRAT and SME cycles. Hydrogen reached 30-35% of the SRAT and SME limits at the mid-point of the stoichiometry window (bounding noble metals and acid demand).

Koopman, D. C.; Zamecnik, J. R.

2013-06-25T23:59:59.000Z

11

Ash Static Liquefaction  

Science Conference Proceedings (OSTI)

This laboratory study was focused on assessing fundamental geotechnical engineering properties of fly ash.  It involved the testing of fly ash recovered from the existing ash ponds and from dry fly ash silos operated by 5 participating utilities.  Materials from 22 different sites were involved in the testing program.  To provide comprehensive fundamental understanding of the similarities and differences between the samples, a series of basic geotechnical engineering characterization ...

2012-12-28T23:59:59.000Z

12

Activation of fly ash  

DOE Patents (OSTI)

Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

Corbin, D.R.; Velenyi, L.J.; Pepera, M.A.; Dolhyj, S.R.

1986-08-19T23:59:59.000Z

13

Activation of fly ash  

DOE Patents (OSTI)

Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

Corbin, David R. (New Castle, DE); Velenyi, Louis J. (Lyndhurst, OH); Pepera, Marc A. (Northfield, OH); Dolhyj, Serge R. (Parma, OH)

1986-01-01T23:59:59.000Z

14

Optimizing Ash Handling - SmartAshTM System Evaluation  

Science Conference Proceedings (OSTI)

High ash levels in electrostatic precipitator (ESP) hoppers are notorious for increasing particulate matter (PM) emissions and plume opacity. Conventional means of monitoring hopper ash levels and fly ash handling system performance have been time-consuming and problematic. Neundorfer, Inc., has developed a fly ash conveying system-monitoring package (SmartAshSystem) that provides improved monitoring of fly ash removal process parameters and provides graphical depictions of ash system performance. Additi...

2007-11-21T23:59:59.000Z

15

DWPF SIMULANT CPC STUDIES FOR SB8  

SciTech Connect

Prior to processing a Sludge Batch (SB) in the Defense Waste Processing Facility (DWPF), flowsheet studies using simulants are performed. Typically, the flowsheet studies are conducted based on projected composition(s). The results from the flowsheet testing are used to 1) guide decisions during sludge batch preparation, 2) serve as a preliminary evaluation of potential processing issues, and 3) provide a basis to support the Shielded Cells qualification runs performed at the Savannah River National Laboratory (SRNL). SB8 was initially projected to be a combination of the Tank 40 heel (Sludge Batch 7b), Tank 13, Tank 12, and the Tank 51 heel. In order to accelerate preparation of SB8, the decision was made to delay the oxalate-rich material from Tank 12 to a future sludge batch. SB8 simulant studies without Tank 12 were reported in a separate report.1 The data presented in this report will be useful when processing future sludge batches containing Tank 12. The wash endpoint target for SB8 was set at a significantly higher sodium concentration to allow acceptable glass compositions at the targeted waste loading. Four non-coupled tests were conducted using simulant representing Tank 40 at 110-146% of the Koopman Minimum Acid requirement. Hydrogen was generated during high acid stoichiometry (146% acid) SRAT testing up to 31% of the DWPF hydrogen limit. SME hydrogen generation reached 48% of of the DWPF limit for the high acid run. Two non-coupled tests were conducted using simulant representing Tank 51 at 110-146% of the Koopman Minimum Acid requirement. Hydrogen was generated during high acid stoichiometry SRAT testing up to 16% of the DWPF limit. SME hydrogen generation reached 49% of the DWPF limit for hydrogen in the SME for the high acid run. Simulant processing was successful using previously established antifoam addition strategy. Foaming during formic acid addition was not observed in any of the runs. Nitrite was destroyed in all runs and no N2O was detected during SME processing. Mercury behavior was consistent with that seen in previous SRAT runs. Mercury was stripped below the DWPF limit on 0.8 wt% for all runs. Rheology yield stress fell within or below the design basis of 1-5 Pa. The low acid Tank 40 run (106% acid stoichiometry) had the highest yield stress at 3.78 Pa.

Newell, J.

2013-09-25T23:59:59.000Z

16

Fly Ash Systems  

Science Conference Proceedings (OSTI)

..., ASM International, 2006, p 499â??500ASM Handbook, Vol 13C, Corrosion: Environments and IndustriesCorrosion and Erosion of Ash-Handling

17

Wet Bottom Ash Systems  

Science Conference Proceedings (OSTI)

..., ASM International, 2006, p 499â??500ASM Handbook, Vol 13C, Corrosion: Environments and IndustriesCorrosion and Erosion of Ash-Handling

18

Dancing in the ashes.  

E-Print Network (OSTI)

??The following novel is the third draft of my creative thesis entitled Dancing in the Ashes . It is an exploration of the Detroit rave… (more)

Malesh, Vytautas Adolph

2009-01-01T23:59:59.000Z

19

Ash cloud aviation advisories  

SciTech Connect

During the recent (12--22 June 1991) Mount Pinatubo volcano eruptions, the US Air Force Global Weather Central (AFGWC) requested assistance of the US Department of Energy`s Atmospheric Release Advisory Capability (ARAC) in creating volcanic ash cloud aviation advisories for the region of the Philippine Islands. Through application of its three-dimensional material transport and diffusion models using AFGWC meteorological analysis and forecast wind fields ARAC developed extensive analysis and 12-hourly forecast ash cloud position advisories extending to 48 hours for a period of five days. The advisories consisted of ``relative`` ash cloud concentrations in ten layers (surface-5,000 feet, 5,000--10,000 feet and every 10,000 feet to 90,000 feet). The ash was represented as a log-normal size distribution of 10--200 {mu}m diameter solid particles. Size-dependent ``ashfall`` was simulated over time as the eruption clouds dispersed. Except for an internal experimental attempt to model one of the Mount Redoubt, Alaska, eruptions (12/89), ARAC had no prior experience in modeling volcanic eruption ash hazards. For the cataclysmic eruption of 15--16 June, the complex three-dimensional atmospheric structure of the region produced dramatically divergent ash cloud patterns. The large eruptions (> 7--10 km) produced ash plume clouds with strong westward transport over the South China Sea, Southeast Asia, India and beyond. The low-level eruptions (< 7 km) and quasi-steady-state venting produced a plume which generally dispersed to the north and east throughout the support period. Modeling the sequence of eruptions presented a unique challenge. Although the initial approach proved viable, further refinement is necessary and possible. A distinct need exists to quantify eruptions consistently such that ``relative`` ash concentrations relate to specific aviation hazard categories.

Sullivan, T.J.; Ellis, J.S. [Lawrence Livermore National Lab., CA (United States); Schalk, W.W.; Nasstrom, J.S. [EG and G, Inc., Pleasanton, CA (United States)

1992-06-25T23:59:59.000Z

20

DWPF SB6 INITIAL CPC FLOWSHEET TESTING SB6-1 TO SB6-4L TESTS OF SB6-A AND SB6-B SIMULANTS  

Science Conference Proceedings (OSTI)

The Defense Waste Processing Facility (DWPF) will transition from Sludge Batch 5 (SB5) processing to Sludge Batch 6 (SB6) processing in late fiscal year 2010. Tests were conducted using non-radioactive simulants of the expected SB6 composition to determine the impact of varying the acid stoichiometry during the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) processes. The work was conducted to meet the Technical Task Request (TTR) HLW/DWPF/TTR-2008-0043, Rev.0 and followed the guidelines of a Task Technical and Quality Assurance Plan (TT&QAP). The flowsheet studies are performed to evaluate the potential chemical processing issues, hydrogen generation rates, and process slurry rheological properties as a function of acid stoichiometry. These studies were conducted with the estimated SB6 composition at the time of the study. This composition assumed a blend of 101,085 kg of Tank 4 insoluble solids and 179,000 kg of Tank 12 insoluble solids. The current plans are to subject Tank 12 sludge to aluminum dissolution. Liquid Waste Operations assumed that 75% of the aluminum would be dissolved during this process. After dissolution and blending of Tank 4 sludge slurry, plans included washing the contents of Tank 51 to {approx}1M Na. After the completion of washing, the plan assumes that 40 inches on Tank 40 slurry would remain for blending with the qualified SB6 material. There are several parameters that are noteworthy concerning SB6 sludge: (1) This is the second batch DWPF will be processing that contains sludge that has had a significant fraction of aluminum removed through aluminum dissolution; (2) The sludge is high in mercury, but the projected concentration is lower than SB5; (3) The sludge is high in noble metals, but the projected concentrations are lower than SB5; and(4) The sludge is high in U and Pu - components that are not added in sludge simulants. Six DWPF process simulations were completed in 4-L laboratory-scale equipment using two projections of the SB6 blend simulant composition (Tank 40 simulant after Tank 51 transfer is complete). The more washed simulant (SB6-A) had a set of four SRAT and SME simulations at varying acid stoichiometry levels (90%, 100%, 120% and 150%) using the Koopman Acid Prediction Calculation. Two additional SRAT simulations were made using SB6-B blend simulant at 100% and 120% of acid stoichiometry. SME cycles were noted performed for the SB6B simulants to allow the SRAT products to be used for melt rate testing.

Lambert, D.; Pickenheim, B.; Best, D.

2009-09-09T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Ash Handling System Maintenance Guide  

Science Conference Proceedings (OSTI)

This Ash Handling System Maintenance Guide provides fossil plant maintenance personnel with current maintenance information on this system. This guide will assist plant maintenance personnel in improving the reliability and reducing the maintenance costs for the ash handling system.

2005-12-23T23:59:59.000Z

22

AlGaAsSb/GaSb Distributed Bragg Reflectors Grown by Organometallic Vapor Phase Epitaxy  

SciTech Connect

The first AlGaAsSb/GaSb quarter-wave distributed Bragg reflectors grown by metallic vapor phase epitaxy are reported. The peak reflectance is 96% for a 10-period structure.

C.A. Wang; C.J. Vineis; D.R. Calawa

2002-02-13T23:59:59.000Z

23

ESH100.2.SB.2  

NLE Websites -- All DOE Office Websites (Extended Search)

Safety & Health Procedure Number ESH100.2.SB.2 Procedure Title Ensure Nuclear Criticality Safety Procedure Manager COFFING, STEPHEN A. Status Active Subject Matter Expert...

24

Continuing disposal of coal ash  

Science Conference Proceedings (OSTI)

The large volume of power-plant coal ash produced and stricter Federal water pollution controls are making ash disposal increasingly difficult for utilities. The protection of surface and ground water quality required in the Resource conservation and Recovery Act of 1976 (RCRA) and the Federal Water Pollution Control Act's Clean Water Act (CWA) amendments of 1977 have raised the cost of disposal to a level where an acceptable method must be found. The Electric Power Research Institute's Coal Ash Disposal Manual (EPRI-FM--1257) describes-ash chemistry, disposal site selection, site monitoring and reclamation, and other information of interest to utilities that are making cost estimates and procedure evaluations. (DCK)

Lihach, N.; Golden, D.

1980-03-01T23:59:59.000Z

25

Method of making an InAsSb/InAsSbP diode lasers  

DOE Patents (OSTI)

InAsSb/InAsSbP/InAs Double Heterostructures (DH) and Separate Confinement Heterostructure Multiple Quantum Well (SCH-MQW) structures are taught wherein the ability to tune to a specific wavelength within 3 .mu.m to 5 .mu.m is possible by varying the ratio of As:Sb in the active layer.

Razeghi, Manijeh (Wilmette, IL)

1997-01-01T23:59:59.000Z

26

Operational Implications of Airborne Volcanic Ash  

Science Conference Proceedings (OSTI)

Volcanic ash clouds pose a real threat to aircraft safety. The ash is abrasive and capable of causing serious damage to aircraft engines, control surfaces, windshields, and landing lights. In addition, ash can clog the pitot—static systems, which ...

Gary L. Hufford; Leonard J. Salinas; James J. Simpson; Elliott G. Barske; David C. Pieri

2000-04-01T23:59:59.000Z

27

Comparison between MSW Ash and RDF Ash from Incineration Process  

E-Print Network (OSTI)

, the unwashed incineration ash were tested and analyzed for TCLP (Toxicity Characteristic Leaching Procedure of auxiliary air. The flue gases are PEER-REVIEW 963 #12;eventually led through air pollution control system to prevent visible flue gas emissions due to higher moisture content. TCLP ANALYSIS Samples of fly ash

Columbia University

28

Sludge Batch 7 (SB7) Washing and Settling Demonstration  

Generate test slurry Wash per SB7 plan Quantify settling vs wash cycle and time Sampling and analysis. SB7 Washing and Settling Demonstration 5 ...

29

Incineration and incinerator ash processing  

Science Conference Proceedings (OSTI)

Parallel small-scale studies on the dissolution and anion exchange recovery of plutonium from Rocky Flats Plant incinerator ash were conducted at the Los Alamos National Laboratory and at the Rocky Flats Plant. Results from these two studies are discussed in context with incinerator design considerations that might help to mitigate ash processing related problems. 11 refs., 1 fig., 1 tab.

Blum, T.W.

1991-01-01T23:59:59.000Z

30

Coal Ash Carbon Removal Technologies  

Science Conference Proceedings (OSTI)

Market resistance to the use of ash containing elevated levels of carbon and/or ammonia has become a major concern for coal-fired facilities in recent years as a result of increased use of nitrogen oxide (NOx) reduction environmental control technologies. EPRI initiated this state of practice assessment to help power producers evaluate alternatives for ash beneficiation.

2001-11-01T23:59:59.000Z

31

Prickly Ash and Prickly Pear  

NLE Websites -- All DOE Office Websites (Extended Search)

Prickly Ash and Prickly Pear Prickly Ash and Prickly Pear Nature Bulletin No. 649-A October 1, 1977 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation PRICKLY ASH AND PRICKLY PEAR In the plant kingdom, as among people, there are so-me that we avoid. They have few virtues, if any, and our experiences with them are painful or have unpleasant after effects. Poison ivy is a notorious example. Prickly Ash, a shrub, is another. Although not poisonous it is thickly armed with wicked thorns and has no ornamental, economic or wildlife value. In 1821 when the first section lines were established in Cook County, the surveyor recorded -- for the benefit of land buyers -- the principal kinds of trees and other vegetation observed along each mile. He frequently encountered prickly ash in thickets near the Little Calumet River and also the north and south branches of the Chicago River.

32

Insurance coverage for coal ash liabilities  

Science Conference Proceedings (OSTI)

The paper discusses how liability insurance can be a valuable tool for limiting coal ash liabilities.

Elkind, D.L. [Dickstein Shapiro LLP (United States)

2009-07-01T23:59:59.000Z

33

Treated bottom ash medium and method of arsenic removal from drinking water  

DOE Patents (OSTI)

A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

Gadgil, Ashok (El Cerrito, CA)

2009-06-09T23:59:59.000Z

34

Chemical kinetic studies on dry sorbents. Final report. [Sodium bicarbonate  

Science Conference Proceedings (OSTI)

The scope of this research investigation has included a review of potential additives suitable for dry flue-gas desulfurization (FGD) and a bench scale laboratory study to determine the chemical kinetics for the reaction of five different sorbents with sulfur dioxide. The sorbents chosen included sodium bicarbonate (NaHCO/sub 3/), soda ash (Na/sub 2/CO/sub 3/), trona, lime (CaO) and hydrated lime (Ca(OH)/sub 2/). This study has shown that: (1) The reaction rate increases with temperature for soda ash and calcium oxide. The reaction temperature has an inverse effect on sodium bicarbonate and trona due, primarily, to the simultaneous thermal activation reaction. The calcium hydroxide-SO/sub 2/ reaction increased up to 550/sup 0/F, and then decreased, due to uneven gas flow distribution. (2) The reaction rates for soda ash, calcium oxide and calcium hydroxide were increased by decreasing their particle size. This effect was not confirmed for sodium bicarbonate and trona where reaction temperature was the most important reaction parameter. (3) Reaction with soda ash was found to be limited by the presence of an impervious ash layer which prevented interparticle gaseous diffusion. Calcium oxide and calcium hydroxide were found to be limited by a slow chemical reaction rate. Results on the rate-limiting steps for sodium bicarbonate and trona were inconclusive because of the simultaneous thermal activation reaction. (4) The effect of thermal activation was to increase the reaction rate for sodium bicarbonate and trona at lower temperatures. This effect was less pronounced at higher temperatures. (5) Results obtained for nitric oxide show limited adsorption for the five sorbents tested as compared to the finding for sulfur dioxide.

Davis, W.T.; Keener, T.C.

1982-02-15T23:59:59.000Z

35

Integrated Fly Ash Pond Management  

Science Conference Proceedings (OSTI)

This report is directed toward solving new challenges to meeting U.S. Environmental Protection Agency (USEPA) National Pollutant Discharge Elimination System (NPDES) discharge limits for ammonia and selected metals from coal-fired power plants. Based on the field and laboratory study of fly ash ponds at five operating coal-fired power plants, the physical, chemical, and biological processes that occur in fly ash sluicing systems are discussed and recommendations are made as to how to best manage the pond...

2009-11-24T23:59:59.000Z

36

Genetic Transformation and Regeneration of Green Ash (Fraxinus pennsylvanica) for Resistance to the Emerald Ash Borer  

E-Print Network (OSTI)

bats, tool handles, furniture, and firewood. However, the emerald ash borer (EAB) (Agrilus planipennis) develop an efficient regeneration and genetic transformation system for green ash, (2) regenerateGenetic Transformation and Regeneration of Green Ash (Fraxinus pennsylvanica) for Resistance

37

Long duration ash probe  

DOE Patents (OSTI)

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

1994-01-01T23:59:59.000Z

38

Fly ash chemical classification based on lime  

Science Conference Proceedings (OSTI)

Typically, total lime content (CaO) of fly ash is shown in fly ash reports, but its significance is not addressed in US specifications. For certain applications a low lime ash is preferred. When a class C fly ash must be cementitious, lime content above 20% is required. A ternary S-A-C phase diagram pilot is given showing the location of fly ash compositions by coal rank and source in North America. Fly ashes from subbituminous coal from the Powder River Basin usually contain sufficient lime to be cementitious but blending with other coals may result in calcium being present in phases other than tricalcium aluminate. 9 refs., 1 fig.

Fox, J. [BASF Construction Chemicals, LLC (United States)

2007-07-01T23:59:59.000Z

39

Lattice-matched epitaxial GaInAsSb/GaSb thermophotovoltaic devices  

DOE Green Energy (OSTI)

The materials development of Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} alloys for lattice-matched thermophotovoltaic (TPV) devices is reported. Epilayers with cutoff wavelength 2--2.4 {micro}m at room temperature and lattice-matched to GaSb substrates were grown by both low-pressure organometallic vapor phase epitaxy and molecular beam epitaxy. These layers exhibit high optical and structural quality. For demonstrating lattice-matched thermophotovoltaic devices, p- and n-type doping studies were performed. Several TPV device structures were investigated, with variations in the base/emitter thicknesses and the incorporation of a high bandgap GaSb or AlGaAsSb window layer. Significant improvement in the external quantum efficiency is observed for devices with an AlGaAsSb window layer compared to those without one.

Wang, C.A.; Choi, H.K.; Turner, G.W.; Spears, D.L.; Manfra, M.J. [Massachusetts Inst. of Tech., Lexington, MA (United States). Lincoln Lab.; Charache, G.W. [Lockheed Martin, Inc., Schenectady, NY (United States)

1997-05-01T23:59:59.000Z

40

Performance improvement of Ge-Sb-Te material by GaSb doping for phase change memory  

SciTech Connect

Effects of GaSb doping on phase change characteristics of Ge-Sb-Te material are investigated by in situ resistance and x-ray diffraction measurement, optical spectroscopy, and x-ray photoelectron spectroscopy. The crystallization temperature and data retention of Ge-Sb-Te material increase significantly by the addition of GaSb, which results from the high thermal stability of amorphous GaSb. In addition, GaSb-doped Ge-Sb-Te material exhibits faster crystallization speed due to the change in electronic states as a result of the formation of chemical bonds with Ga element. Incorporation of GaSb is highly effective way to enhance the comprehensive performance of Ge-Sb-Te material for phase change memory.

Lu, Yegang [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China) [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211 (China); Graduate School of Chinese Academy of Sciences, Beijing 100049 (China); Zhang, Zhonghua; Song, Sannian; Cheng, Limin; Song, Zhitang [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China)] [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Shen, Xiang; Wang, Guoxiang; Dai, Shixun [Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211 (China)] [Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211 (China)

2013-06-17T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Encapsulation of mixed radioactive and hazardous waste contaminated incinerator ash in modified sulfur cement  

Science Conference Proceedings (OSTI)

Some of the process waste streams incinerated at various Department of Energy (DOE) facilities contain traces of both low-level radioactive (LLW) and hazardous constituents, thus yielding ash residues that are classified as mixed waste. Work is currently being performed at Brookhaven National Laboratory (BNL) to develop new and innovative materials for encapsulation of DOE mixed wastes including incinerator ash. One such material under investigation is modified sulfur cement, a thermoplastic developed by the US Bureau of Mines. Monolithic waste forms containing as much as 55 wt % incinerator fly ash from Idaho national Engineering Laboratory (INEL) have been formulated with modified sulfur cement, whereas maximum waste loading for this waste in hydraulic cement is 16 wt %. Compressive strength of these waste forms exceeded 27.6 MPa. Wet chemical and solid phase waste characterization analyses performed on this fly ash revealed high concentrations of soluble metal salts including Pb and Cd, identified by the Environmental Protection Agency (EPA) as toxic metals. Leach testing of the ash according to the EPA Toxicity Characteristic Leaching Procedure (TCLP) resulted in concentrations of Pb and Cd above allowable limits. Encapsulation of INEL fly ash in modified sulfur cement with a small quantity of sodium sulfide added to enhance retention of soluble metal salts reduced TCLP leachate concentrations of Pb and Cd well below EPA concentration criteria for delisting as a toxic hazardous waste. 12 refs., 4 figs., 2 tabs.

Kalb, P.D.; Heiser, J.H. III; Colombo, P.

1990-01-01T23:59:59.000Z

42

Electronic and thermoelectric properties of CoSbS and FeSbS  

SciTech Connect

We present a combined theoretical and experimental study of the potential thermoelectric performance of three transition metal antimonide sulfides, CoSbS, FeSbS and NiSbS. From theory we find that NiSbS is metallic and hence of little interest regarding thermoelectric performance. CoSbS and FeSbS are both semiconductors with rather heavy valence and conduction bands, whose thermopower can exceed 200 $\\mu$V/K at temperatures of 900 K and carrier concentrations of 10$^{21}$cm$^{-3}$, which is similar to the $n$-type high performance thermoelectric filled skutterudites. The experimental results on several non-optimized $n$-type CoSbS samples confirm its semiconducting nature and indicate a potential for good high temperature thermoelectric performance, finding a ZT for two of the samples of 0.35 at 773 K. Substantially higher ZT values may be possible if the lattice thermal conductivity can be reduced by alloying and the effects of extrinsic scattering, which appear to be substantial in the experimental results, are reduced.

Parker, David S [ORNL; Singh, David J [ORNL; Sales, Brian C [ORNL; McGuire, Michael A [ORNL; May, Andrew F [ORNL; Wang, Hsin [ORNL

2013-01-01T23:59:59.000Z

43

Water Management in Ash-Handling Systems  

Science Conference Proceedings (OSTI)

In 1980, EPA proposed revisions to the effluent standards and guidelines for fly ash and bottom ash transport systems. This review of utility practices provides a comprehensive account of the operation of and problems experienced in wet handling of bottom and fly ash and suggests areas for further research.

1987-08-24T23:59:59.000Z

44

Bottom Ash System Maintenance Guide  

Science Conference Proceedings (OSTI)

This guide provides information to personnel involved in the bottom ash system and its components, including good maintenance practices, condition monitoring, predictive and preventive maintenance techniques, probable failure modes, and troubleshooting guidance. The guide was developed primarily to provide detailed maintenance and troubleshooting information but also includes basic system information.

2000-10-31T23:59:59.000Z

45

Role of Sb Compositions on the Properties of InAs/GaAsSb Quantum Dots (QDs)  

Science Conference Proceedings (OSTI)

QD size, uniformity and density in InAs/GaAsSb material system for increasing Sb content are studied using Atomic Force Microscopy (AFM). AFM results show that QD density and uniformity improve with Sb content increase. The improvement of QD uniformity is ensured by the narrowing of the analysis of AFM scans. To obtain minimum VBO, InAs/GaAsSb with various Sb compositions is investigated by PL and TRPL measurements. PL data shows a blue-shift as excitation power increases as evidence of a type II band structure. Since the PL peak of 8 and 13 % Sb samples did not shift while that of 15 % Sb sample is blue-shifted with increasing the excitation power it is concluded that InAs QDs/GaAs0.86Sb0.14 would have minimum valence band offset. This tendency is supported by the change of a carrier lifetime estimated from TRPL data.

Ban, K. Y.; Bremner, S. P.; Kuciauskas, D.; Dahal, S. N.; Honsberg, C. B.

2012-01-01T23:59:59.000Z

46

Donor behavior of Sb in ZnO  

Science Conference Proceedings (OSTI)

Electrical behavior of Sb in ZnO:Sb layers doped in a wide concentration range was studied using temperature dependent Hall effect measurements. The layers were grown by plasma-enhanced molecular beam epitaxy, and the Sb concentration was changed by varying the Sb flux, resulting in electron concentrations in the range of 10{sup 16} to nearly 10{sup 20} cm{sup -3}. Upon annealing, the electron concentration increased slightly and more notable was that the electron mobility significantly improved, reaching a room-temperature value of 110 cm{sup 2}/V s and a low-temperature value of 145 cm{sup 2}/V s, close to the maximum of {approx}155 cm{sup 2}/V s set by ionized impurity scattering. Hall data and structural data suggest that Sb predominantly occupies Zn sublattice positions and acts as a shallow donor in the whole concentration range studied. In the layers with high Sb content ({approx}1 at. %), acceptor-type compensating defects (possibly Sb on oxygen sites and/or point-defect complexes involving Sb{sub O}) are formed. The increase of electron concentration with increasing oxygen pressure and the increase in ZnO:Sb lattice parameter at high Sb concentrations suggest that acceptors involving Sb{sub O} rather than Sb{sub Zn}-2V{sub Zn} complexes are responsible for the compensation of the donors.

Liu, H. Y.; Izyumskaya, N.; Avrutin, V.; Oezguer, Ue.; Morkoc, H. [Department of Electrical and Computer Engineering, Virginia Commonwealth University, Richmond, Virginia 23284 (United States); Yankovich, A. B.; Kvit, A. V.; Voyles, P. M. [Department of Materials Science and Engineering, University Wisconsin-Madison, Madison, Wisconsin 53706 (United States)

2012-08-01T23:59:59.000Z

47

Type I Mid-Infrared MQW Lasers using AlInAsSb barriers and InAsSb wells  

E-Print Network (OSTI)

Type I Mid-Infrared MQW Lasers using AlInAsSb barriers and InAsSb wells Leslie G. Vaughn*a , L and interband lasers, Shockley-Read-Hall losses increase. The simplest structure is Type-I multiple quantum well. One such system with InAsSb wells and AlInAsSb barriers has been unable to exceed 175K under CW

New Mexico, University of

48

Recent progress in InGaAsSb/GaSb TPV devices  

DOE Green Energy (OSTI)

AstroPower is developing InGaAsSb thermophotovoltaic (TPV) devices. This photovoltaic cell is a two-layer epitaxial InGaAsSb structure formed by liquid-phase epitaxy on a GaSb substrate. The (direct) bandgap of the In{sub 1{minus}x}Ga{sub x}As{sub 1{minus}y}Sb{sub y} alloy is 0.50 to 0.55 eV, depending on its exact alloy composition (x,y); and is closely lattice-matched to the GaSb substrate. The use of the quaternary alloy, as opposed to a ternary alloy--such as, for example InGaAs/InP--permits low bandgap devices optimized for 1,000 to 1,500 C thermal sources with, at the same time, near-exact lattice matching to the GaSb substrate. Lattice matching is important since even a small degree of lattice mismatch degrades device performance and reliability and increases processing complexity. Internal quantum efficiencies as high as 95% have been measured at a wavelength of 2 microns. At 1 micron wavelengths, internal quantum efficiencies of 55% have been observed. The open-circuit voltage at currents of 0.3 A/cm{sup 2} is 0.220 volts and 0.280 V for current densities of 2 A/cm{sup 2}. Fill factors of 56% have been measured at 60 mA/cm{sup 2}. However, as current density increases there is some decrease in fill factor. The results to date show that the GaSb-based quaternary compounds provide a viable and high performance energy conversion solution for thermophotovoltaic systems operating with 1,000 to 1,500 C source temperatures.

Shellenbarger, Z.A.; Mauk, M.G.; DiNetta, L.C. [AstroPower, Inc., Newark, DE (United States); Charache, G.W. [Lockheed Martin Corp., Schenectady, NY (United States)

1996-05-01T23:59:59.000Z

49

Tensile strength of ash cake beds at high-temperature conditions  

SciTech Connect

The Energy and Environmental Research Center (EERC) is working with Electric Power Research Institute (EPRI) and a consortium of companies in partnership with the US Department of Energy (DOE) to perform the research necessary to determine the factors that cause hot-gas cleanup filters to be blinded by ash or to develop deposits that can bridge the filters and cause them to fail. The primary deliverable will be a graphics-driven computer model that can be used as an engineering tool to help predict ash-related hot-gas filter problems based on analyses of coal and sorbent, as well as system operating parameters. This paper presents preliminary testing data on determining the tensile strengths of coal ash particles at elevated temperatures and simulated combustor gas conditions. The range in temperatures for tensile testing is ambient to 900 C. The simulated gas atmosphere includes carbon dioxide, water vapor, oxygen, sulfur dioxide, sodium chloride, hydrochloric acid, and nitrogen. At present, all testing has been performed using ash from the Westinghouse advanced particle filter (APF) at the American Electric Power Service Corporation (AEP) Tidd pressurized fluidized-bed combustor (PFBC) demonstration plant in Ohio. Other sources of filter ashes, including several from non-American PFBC systems, will also be evaluated.

Dockter, B.A.; Hurley, J.P.

1996-12-31T23:59:59.000Z

50

Cement Additives from Fly Ash Opportunity  

NLE Websites -- All DOE Office Websites (Extended Search)

Device and Method for Separating Minerals, Carbon and Device and Method for Separating Minerals, Carbon and Cement Additives from Fly Ash Opportunity Research is currently active on the patented technology "Device and Method for Separating Minerals, Carbon, and Cement Additives from Fly Ash." The technology is available for licensing and/or further collaborative research from the U.S. Depart- ment of Energy's National Energy Technology Laboratory (NETL). Overview This invention includes a device, along with a method, to recover and use fly ash as a source of high purity carbon, ash, and minerals. The device and associated method can isolate components of the fly ash based on size and electrical charge. By improving beneficiation and usage methods, fly ash can be transformed from a waste material to a valuable by-product. Recent shifts to low nitrogen

51

Compositional Analysis of Beneficiated Fly Ashes  

Science Conference Proceedings (OSTI)

... Fly ash is a byproduct of combustion of coal in coal-fired powerplants through ... to be disposed of at a significant cost to power plant companies, and ...

1997-09-03T23:59:59.000Z

52

GaInSb and GaInAsSb thermophotovoltaic device fabrication and characterization  

DOE Green Energy (OSTI)

Thermophotovoltaic (TPV) devices have been fabricated using epitaxial ternary and quaternary layers grown on GaSb substrates. The GaInSb layers were grown by organometallic vapor phase epitaxy (OMVPE) and the InGaAsSb lattice-matched layers were grown by liquid phase epitaxy (LPE). Device fabrication steps include unannealed p-type ohmic contacts, annealed Sn/Au n-type ohmic contacts, and a thick Ag top-surface contact using a lift-off process. Devices are characterized primarily by dark I-V, photo I-V, and quantum efficiency measurements, which are correlated to microscopic and macroscopic material properties. Particular emphasis has been on material enhancements to increase quantum efficiency and decrease dark saturation current density. TPV device performance is presently limited by the base diffusion length, typically 1 to 2 microns.

Hitchcock, C.; Gutmann, R.; Borrego, J.; Ehsani, H.; Bhat, I. [Rensselaer Polytechnic Inst., Troy, NY (United States); Freeman, M.; Charache, G. [Lockheed Martin, Inc., Schenectady, NY (United States)

1997-05-01T23:59:59.000Z

53

Treatment of fly ash for use in concrete  

DOE Patents (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT)

2012-05-15T23:59:59.000Z

54

Use of Class C Fly Ash in High-Volume Fly Ash Concrete Applications  

Science Conference Proceedings (OSTI)

Although the use of fly ash in concrete is a well-established practice, the volume of high-calcium Class C ash used lags behind that of low-calcium Class F ash. Because Class C may be the only type of ash produced in some western states, this disparity can significantly limit its use potential. The literature results presented in this report represent the first phase of a longer term research effort to provide technical information supporting the increased use of Class C ash in concrete applications.

2007-09-24T23:59:59.000Z

55

Recovery Act Workers Complete Environmental Cleanup of Coal Ash...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Complete Environmental Cleanup of Coal Ash Basin Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin The Savannah River Site (SRS) recently cleaned up a 17-acre...

56

Recovery Act Workers Complete Environmental Cleanup of Coal Ash...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Workers Complete Environmental Cleanup of Coal Ash Basin Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin The Savannah River Site (SRS) recently cleaned up a...

57

AlSb/InAs HIGH ELECTRON MOBILITY TRANSISTORS - Energy ...  

The Naval Research Laboratory (NRL) has developed materials growth and fabrication technology for the manufacture of high-speed, low power AlSb/InAs high electron ...

58

Bulk growth of GaSb and Ga{sub 1{minus}x}In{sub x}Sb  

DOE Green Energy (OSTI)

GaSb and InGaSb have been demonstrated to be suitable choices for high efficiency thermophotovoltaic (TPV) cells. Synthesis and growth of bulk GaSb single crystals and GaInSb polycrystals have been carried out by the vertical Bridgman technique, with a baffle immersed in the melt and by complete encapsulation of the melt by low melting temperature alkali halides or oxides. The critical roles of the baffle and the encapsulation are discussed. Efforts in obtaining device grade GaSb with superior structural and electrical properties and compositionally homogeneous GaInSb are described, emphasizing the key steps in the growth cycle developed to obtain good crystalline quality.

Dutta, P.S.; Ostrogorsky, A.G.; Gutmann, R.J.

1997-05-01T23:59:59.000Z

59

Study of cesium volatility from sodium carbonate based melts  

SciTech Connect

Purpose of this study was to obtain thermodynamic data on cesium volatility from sodium carbonate-based molten salts for application to the Rockwell-ETEC molten salt oxidation process. At 1073 to 1373 K, volatility tests were conducted on a horizontal and a vertical transpiration apparatus using a carrier gas composed of CO{sub 2}(g) and H{sub 2}O(g) which was passed over or bubbled through a sodium carbonate bath containing cesium carbonate and various additives. The major vapor species was identified to be CsOH(g) except when greater than 3% chloride is present in the melt, then the major vapor species is CsCl(g). The decrease in volatility of cesium as a function of cesium concentration in Cs{sub 2}CO{sub 3{minus}}Na{sub 2}CO{sub 3} mixtures follows Raoult`s law very closely. Thus, this system exhibits close to ideal solution behavior. Addition of 22.5 wt % sodium sulfate decreases the cesium volatility by just under a factor of 2, and the addition of 10.0 wt % sodium chloride increases the cesium volatility about an order of magnitude. The addition of 2.0 wt % ash, molecular sieve, or silica show little or no effect. However, the data indicate that higher concentrations of ash will decrease the cesium volatility. For the addition of 22.5 wt % sodium sulfate the activity coefficient, {gamma}(Cs{sub 2}CO{sub 3}){sup {1/2}}, is calculated to be 0.720 {plus_minus} 0.068, and for the addition of 10.0 wt % sodium chloride, the activity coefficient, {gamma}(CsCl), is calculated to be 8.118 {plus_minus} 2.317. Assuming that Henry`s law applies, these activity coefficients are used to extrapolate the effect on cesium retention in the molten salt oxidizer of sulfate and chloride at lower cesium concentrations.

Ebbinghaus, B.B.; Krikorian, O.H.; Adamson, M.G.; Fleming, D.L.

1993-12-01T23:59:59.000Z

60

Self-degradable Slag/Class F Fly Ash-Blend Cements  

DOE Green Energy (OSTI)

Self-degradable slag/Class F fly ash blend pozzolana cements were formulated, assuming that they might serve well as alternative temporary fracture sealers in Enhanced Geothermal System (EGS) wells operating at temperatures of {ge} 200 C. Two candidate formulas were screened based upon material criteria including an initial setting time {ge} 60 min at 85 C, compressive strength {ge} 2000 psi for a 200 C autoclaved specimen, and the extent of self-degradation of cement heated at {ge} 200 C for it was contacted with water. The first screened dry mix formula consisted of 76.5 wt% slag-19.0 wt% Class F fly ash-3.8 wt% sodium silicate as alkali activator, and 0.7 wt% carboxymethyl cellulose (CMC) as the self-degradation promoting additive, and second formula comprised of 57.3 wt% slag, 38.2 wt% Class F fly ash, 3.8 wt% sodium silicate, and 0.7 wt% CMC. After mixing with water and autoclaving it at 200 C, the aluminum-substituted 1.1 nm tobermorite crystal phase was identified as hydrothermal reaction product responsible for the development of a compressive strength of 5983 psi. The 200 C-autoclaved cement made with the latter formula had the combined phases of tobermorite as its major reaction product and amorphous geopolymer as its minor one providing a compressive strength of 5271 psi. Sodium hydroxide derived from the hydrolysis of sodium silicate activator not only initiated the pozzolanic reaction of slag and fly ash, but also played an important role in generating in-situ exothermic heat that significantly contributed to promoting self-degradation of cementitious sealers. The source of this exothermic heat was the interactions between sodium hydroxide, and gaseous CO{sub 2} and CH{sub 3}COOH by-products generated from thermal decomposition of CMC at {ge} 200 C in an aqueous medium. Thus, the magnitude of this self-degradation depended on the exothermic temperature evolved in the sealer; a higher temperature led to a sever disintegration of sealer. The exothermic temperature was controlled by the extent of thermal decomposition of CMC, demonstrating that CMC decomposed at higher temperature emitted more gaseous reactants. Hence, such large emission enhanced the evolution of in-situ exothermic heat. In contrast, the excessive formation of geopolymer phase due to more incorporation of Class F fly ash into this cementitious system affected its ability to self-degrade, reflecting that there was no self-degradation. The geopolymer was formed by hydrothermal reactions between sodium hydroxide from sodium silicate and mullite in Class F fly ash. Thus, the major reason why geopolymer-based cementitiuos sealers did not degrade after heated sealers came in contact with water was their lack of free sodium hydroxide.

Sugama, T.; Warren, J.; Butcher, T. (BNL); Lance Brothers (Halliburton); Bour, D. (AltaRock Energy, Inc.)

2011-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Treatment of fly ash for use in concrete  

DOE Patents (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT); Akash, Akash (Salt lake City, UT); Zhao, Qiang (Natick, MA)

2012-05-08T23:59:59.000Z

62

Treatment of fly ash for use in concrete  

DOE Patents (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett; Akash, Akash; Zhao, Qiang

2013-01-08T23:59:59.000Z

63

Coal Ash Corrosion Resistant Materials Testing  

Science Conference Proceedings (OSTI)

In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a moderate alkali content (0.2% sodium equivalents), thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that aggressive alkali sulfate constituents were present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. Test Section A was removed in November 2001 after about 24 months of service at the desired steam temperature set point, with about 15.5 months of exposure at full temperature. A progress report, issued in October 2002, was written to document the performance of the candidate alloys in that test section. The evaluation described the condition of each tube sample after exposure. It involved a determination of the rate of wall thickness loss for these samples. In cases where there was more than one sample of a candidate material in the test section, an assessment was made of the performance of the alloy as a function of temperature. Test Sections B and C were examined during the November 2001 outage, and it was decided that, due to excessive wastage, certain tube samples needed to be removed and replaced in order to ensure that Test Sections B and C would have a chance of remaining in the boiler for their intended exposure period. These suspect tube samples were replaced and the two remaining test sections were put back into service. The tube samples that were removed from Test Sections B and C were set aside for later analysis at the end of the planned exposure period. Test Sections B and C were again examined approximately six months later. At that time, measured wall thickness losses raised concerns about additional tube samples. These suspect samples were also removed, set aside for later analysis, and replaced. The test sections then went back into service until the end of the second exposure period, which was concluded in May 2003 when, due to evidence of excessive wastage, the valves were opened increasing cooling steam flow and thereby effectively stopping corrosion. In August 2003, Test Sections B and C were removed for closer examination. Section C had experienced about 42 months of service at the desired team temperature set point with 28.5 months at temperature at full temperature. Additional suspect samples were removed from Test Section B, then, it was re-installed into the boiler (at the location originally occupied by Section C), where it remained in service until the end of the program. Due to this removal history, the samples from Test Section B had a total service duration that varied from a minimum of 15.5 months (for samples that performed poorly) to 37 months for samples the survived for the full intended service exposure for Section B. The figure below shows a schematic of Test Section B and indicates the length of service exposure for different locations. This report provides the results of the evaluation of Test Section B, including the samples that remained in the Test Section for the full exposure period as well as those that were removed early. This report also is intended to compare and summarize the results for all three test sections. The analysis of T

D. K. McDonald; P. L. Daniel; D. J. DeVault

2007-12-31T23:59:59.000Z

64

CAST STONE FORMULATION AT HIGHER SODIUM CONCENTRATIONS  

SciTech Connect

A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

Fox, K.; Edwards, T.; Roberts, K.

2013-10-02T23:59:59.000Z

65

CAST STONE FORMULATION AT HIGHER SODIUM CONCENTRATIONS  

SciTech Connect

A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

Fox, K.; Roberts, K.; Edwards, T.

2013-09-17T23:59:59.000Z

66

SLUDGE BATCH 7 ACCEPTANCE EVALUATION: RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB7 QUALIFICATION SAMPLE PREPARED AT SRNL  

SciTech Connect

Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Seven (SB7) for processing in the Defense Waste Processing Facility (DWPF). The SB7 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB6. The radionuclide concentrations were measured or estimated in the Tank 51 SB7 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter qualification sample of Tank 51 sludge slurry (HTF-51-10-125) received on September 18, 2010. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. With consultation from the Liquid Waste Organization, the qualification sample was then modified by several washes and decants, which included addition of Pu from H Canyon and sodium nitrite per the Tank Farm corrosion control program. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Tank 40. Determining the radionuclide concentrations in this Tank 51 SB7 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2010-0031. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task I.2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task III.2.) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB7 will be taken and transferred to SRNL for measurement of these radionuclides. The results presented in this report are those necessary for DWPF to assess if the Tank 51 SB7 sample prepared at SRNL meets the requirements for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria evaluation, and the DWPF Solid Waste Characterization Program. Concentrations are given for thirty-four radionuclides along with total alpha and beta activity. Values for total gamma and total gamma plus beta activities are also calculated.

Pareizs, J.; Hay, M.

2011-02-22T23:59:59.000Z

67

Rocky Flats ash test procedure (sludge stabilization)  

SciTech Connect

Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. This test will also gain information on the effects of the glovebox atmosphere (moisture) on the stabilized material. This document provides instructions for testing Rocky Flats Ash in the HC-21C muffle furnace process.

Winstead, M.L.

1995-09-14T23:59:59.000Z

68

Fusibility and sintering characteristics of ash  

Science Conference Proceedings (OSTI)

The temperature characteristics of ash fusibility are studied for a wide range of bituminous and brown coals, lignites, and shales with ratios R{sub B/A} of their alkaline and acid components between 0.03 and 4. Acritical value of R{sub B/A} is found at which the fusion temperatures are minimal. The sintering properties of the ashes are determined by measuring the force required to fracture a cylindrical sample. It is found that the strength of the samples increases sharply at certain temperatures. The alkali metal content of the ashes has a strong effect on their sintering characteristics.

Ots, A. A., E-mail: aots@sti.ttu.ee [Tallinn University of Technology (Estonia)

2012-03-15T23:59:59.000Z

69

Investigation of Ammonia Adsorption on Fly Ash and Potential Impacts of Ammoniated Ash  

Science Conference Proceedings (OSTI)

Problems associated with ammoniated fly ash have become a major concern for coal-fired facilities in recent years due to the increased use of ammonia-based environmental control technologies. Of particular note is more frequent use of ammonia-based NOx control systems and electrostatic precipitator (ESP) conditioning with ammonia. To help power producers evaluate and mitigate the impacts of ammoniated ash, this project provides crucial information in the areas of fly ash characterization, adsorption test...

1999-12-10T23:59:59.000Z

70

METHOD FOR REMOVING SODIUM OXIDE FROM LIQUID SODIUM  

DOE Patents (OSTI)

A method is described for removing sodium oxide from a fluent stream of liquid sodium by coldtrapping the sodium oxide. Apparatus utilizing this method is disclosed in United States Patent No. 2,745,552. Sodium will remain in a molten state at temperatures below that at which sodium oxide will crystallize out and form solid deposits, therefore, the contaminated stream of sodium is cooled to a temperature at which the solubility of sodium oxide in sodium is substantially decreased. Thereafter the stream of sodium is passed through a bed of stainless steel wool maintained at a temperature below that of the stream. The stream is kept in contact with the wool until the sodium oxide is removed by crystal growth on the wool, then the stream is reheated and returned to the system. This method is useful in purifying reactor coolants where the sodium oxide would otherwise deposit out on the walls and eventually plug the coolant tubes.

Bruggeman, W.H.; Voorhees, B.G.

1957-12-01T23:59:59.000Z

71

Proceedings: Tenth International Ash Use Symposium, Volume 2: Ash Use R&D and Clean Coal By-Products  

Science Conference Proceedings (OSTI)

Topics discussed at the tenth symposium on coal ash use included fundamental ash use research, product marketing, applied research, ash management and the environment, and commercial applications. Intense international research interest continues in coal ash use due to the prospects of avoiding disposal costs and generating revenue from by-product sales.

1993-01-22T23:59:59.000Z

72

Effect of antimony nano-scale surface-structures on a GaSb/AlAsSb distributed Bragg reflector  

SciTech Connect

Effects of antimony crystallization on the surface of GaSb during low temperature molecular beam epitaxy growth are investigated. The geometry of these structures is studied via transmission electron and atomic force microscopies, which show the surface metal forms triangular-shaped, elongated nano-wires with a structured orientation composed entirely of crystalline antimony. By depositing antimony on a GaSb/AlAsSb distributed Bragg reflector, the field is localized within the antimony layer. Polarization dependent transmission measurements are carried out on these nano-structures deposited on a GaSb/AlAsSb distributed Bragg reflector. It is shown that the antimony-based structures at the surface favor transmission of light polarized perpendicular to the wires.

Husaini, S.; Shima, D.; Ahirwar, P.; Rotter, T. J.; Hains, C. P.; Dang, T.; Bedford, R. G.; Balakrishnan, G. [Air Force Research Laboratory, Sensors Directorate, Wright-Patterson AFB, Dayton, OH 45433 (United States)] [Air Force Research Laboratory, Sensors Directorate, Wright-Patterson AFB, Dayton, OH 45433 (United States)

2013-02-11T23:59:59.000Z

73

Case Studies in Ash Pond Management, Volume 2  

Science Conference Proceedings (OSTI)

"Toward Developing Integrated Strategies for Managing Multiple Constituents in Ash Pond Discharges," EPRI's second workshop on Ash Pond Management, was hosted by TVA on May 16, 2006, in Chattanooga, Tennessee. The presentations in this workshop reflected specific research challenges identified by participants in the first Ash Pond Management workshop, held in 2004. Among the presentations given in this second workshop were the following: Ash Pond Limnology Optimizing Ash Pond Treatment of Ammonia Predic...

2007-03-26T23:59:59.000Z

74

Fluidized bed gasification ash reduction and removal process  

DOE Patents (OSTI)

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-12-04T23:59:59.000Z

75

Fluidized bed gasification ash reduction and removal system  

DOE Patents (OSTI)

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-02-28T23:59:59.000Z

76

Winter'04Ash4-5  

NLE Websites -- All DOE Office Websites (Extended Search)

process, fly ash is used as a raw material to substitute for part of the clay and shale, which are the two main raw materials of a conventional brick. Test bricks produced...

77

The 1983 Ash Wednesday Fires in Australia  

Science Conference Proceedings (OSTI)

Australia experienced the most disastrous bushfires in over 40 years on Ash Wednesday, 16 February 1983. This article describes the meteorological conditions prior to, during and after these fires, and includes photographs from GMS-2. It also ...

M. E. Voice; F. J. Gauntlett

1984-03-01T23:59:59.000Z

78

Coal Ash Contaminants in Wetlands | SREL Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracey Tuberville, and Bill Hopkins The ash plume wetland (APW). The APW received coal combustion wastes from a breach in a receiving basin in the 1970s. Several trace metals...

79

Airborne Volcanic Ash Forecast Area Reliability  

Science Conference Proceedings (OSTI)

In support of aircraft flight safety operations, daily comparisons between modeled, hypothetical, volcanic ash plumes calculated with meteorological forecasts and analyses were made over a 1.5-yr period. The Hybrid Single-Particle Lagrangian ...

Barbara J. B. Stunder; Jerome L. Heffter; Roland R. Draxler

2007-10-01T23:59:59.000Z

80

Ashe County- Wind Energy System Ordinance  

Energy.gov (U.S. Department of Energy (DOE))

In 2007 Ashe County adopted a wind ordinance to regulate the use of wind-energy systems in unincorporated areas of the county and to describe the conditions by which a permit for installing such a...

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

NETL: Events - World of Coal Ash 2007  

NLE Websites -- All DOE Office Websites (Extended Search)

(WOCA) 2007 conference, jointly sponsored by the American Coal Ash Association and the University of Kentucky Center for Applied Energy Research, will be held May 7-10, 2007 at...

82

Carbon-in-Ash Monitor Demonstration  

Science Conference Proceedings (OSTI)

Based on the lack of publicly available performance and operational data for the current carbon-in-ash monitor (CIAM) commercial offerings, EPRI and Southern Company initiated a demonstration of several commercial technologies on Southern Company's coal-fired units.

2000-09-25T23:59:59.000Z

83

Ash Deposit Physical and Chemical Analysis  

Science Conference Proceedings (OSTI)

As part of the Electric Power Research Institutes (EPRIs) ongoing Boiler Tube Failure Reduction (BTFR) program, this report has been compiled to discuss chemical and mechanical mechanisms that lead to the formation of ash deposits. Ash deposits are a known cause of several boiler tube failure mechanisms, which can not only impact plant performance, but also lead to millions of dollars in lost revenue due to forced outages.

2010-12-17T23:59:59.000Z

84

Coal Ash: Characteristics, Management, and Environmental Issues  

Science Conference Proceedings (OSTI)

Coal-fired power plants in the United States produce more than 92 million tons of coal ash per year. About 40% is beneficially used in a variety of applications, and about 60% is managed in storage and disposal sites. This technical update summarizes information and data on the physical and chemical characteristics of coal ash, beneficial use applications, disposal practices, and management practices to mitigate environmental concerns.

2009-09-17T23:59:59.000Z

85

Ash Deposit Physical and Chemical Analysis  

Science Conference Proceedings (OSTI)

As part of the Electric Power Research Institutes (EPRIs) ongoing Boiler Tube Failure Reduction (BTFR) program, this report has been compiled to discuss chemical and mechanical mechanisms that lead to the formation of ash deposits. Ash deposits are a known cause of a number of boiler tube failure mechanisms, which can not only impact plant performance, but lead to millions of dollars in lost revenue due to forced outages.

2010-12-17T23:59:59.000Z

86

Effect of Sodium Carboxymethyl Celluloses on Water-catalyzed Self-degradation of 200-degree C-heated Alkali-Activated Cement  

SciTech Connect

We investigated the usefulness of sodium carboxymethyl celluloses (CMC) in promoting self-degradation of 200°C-heated sodium silicate-activated slag/Class C fly ash cementitious material after contact with water. CMC emitted two major volatile compounds, CO2 and acetic acid, creating a porous structure in cement. CMC also reacted with NaOH from sodium silicate to form three water-insensitive solid reaction products, disodium glycolate salt, sodium glucosidic salt, and sodium bicarbonate. Other water-sensitive solid reaction products, such as sodium polysilicate and sodium carbonate, were derived from hydrolysates of sodium silicate. Dissolution of these products upon contact with water generated heat that promoted cement’s self-degradation. Thus, CMC of high molecular weight rendered two important features to the water-catalyzed self-degradation of heated cement: One was the high heat energy generated in exothermic reactions in cement; the other was the introduction of extensive porosity into cement.

Sugama T.; Pyatina, T.

2012-05-01T23:59:59.000Z

87

Densification of pond ash by blasting  

Science Conference Proceedings (OSTI)

Fly ash from thermal power plants is disposed, in huge quantities in ash ponds, which occupy large land areas otherwise useful for agriculture, housing, or other development. For effective rehabilitation of ash ponds, densification of the slurry deposit is essential to increase the bearing capacity and to improve its resistance to liquefaction. Extensive field trials were carried out to evaluate the effectiveness of deep blasting for densification of deposited fly ash. Ninety explosions comprising 15 single blasts, with varying depths and quantities of charges, and 3 group blasts, each having 25 charges placed at various spacings, were carried out. The compaction achieved in terms of an increase in relative density was evaluated from surface settlement measurements. Extensive field monitoring was undertaken through pore-water pressure measurements, vibration measurements, penetration tests, and block vibration tests. For the average charge of 2--4 g of explosive per cubic meter of untreated deposit, the average relative density was found to improve from 50% to 56--58%. Analysis of the test results indicates that deep blasting may be an effective technique for modest compaction of loose fly ash deposits. The field testing program presented in this paper provides valuable information that can be used for planning blast densification of fly ash deposits.

Gandhi, S.R.; Dey, A.K.; Selvam, S. [Indian Inst. of Tech., Madras (India)

1999-10-01T23:59:59.000Z

88

Marketing coal ash, slag, and sludge  

SciTech Connect

Investigates the selling of by-products of coal-fired power generation--fly ash, bottom ash, boiler slag, and scrubber sludge--by utilities for use in highways, parking lots, cement, roofing, bricks, and blocks. Points out that the EPA has drafted tough new regulations for solid-waste storage, transportation, and disposal that may soon cost power plants $25-$40 a ton to dispose of wastes. Reports that the EPRI is studying high-volume by-product applications that have low technology requirements (e.g. fly ash for use in highways, parking lots, and utility construction) and medium-volume, medium-technology applications (e.g. by-products used for cement manufacture, asphalt, blocks, bricks, roofing granules, and wallboards). Reveals that EPRI plans to eventually identify a representative set of perhaps half a dozen basic fly ashes, characterize them, do proportion studies of existing concrete mixes (including those with fly ash in them), and then develop guidelines for fly ash proportions in concrete.

Lihach, N.; Golden, D.; Komai, R.; Maulbetsch, J.

1982-12-01T23:59:59.000Z

89

Human Sodium Risks  

NLE Websites -- All DOE Office Websites (Extended Search)

comes from restaurants and it can be hard for a person to tell how much sodium is in restaurant foods. Brands of foods matter: Different brands of the same foods may have...

90

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

Science Conference Proceedings (OSTI)

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

91

SB Electronics Breaks Ground on New Factory | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

SB Electronics Breaks Ground on New Factory SB Electronics Breaks Ground on New Factory SB Electronics Breaks Ground on New Factory April 29, 2010 - 5:22pm Addthis U.S. Rep. Peter Welch (from left), Vermont Lt. Gov. Brian Dubie, SBE board member Win Hunter, SBE board chair Stan Fishkin, Assi U.S. Rep. Peter Welch (from left), Vermont Lt. Gov. Brian Dubie, SBE board member Win Hunter, SBE board chair Stan Fishkin, Assi Paul Lester Communications Specialist, Office of Energy Efficiency and Renewable Energy A Vermont company broke ground on a new factory that will produce cutting-edge technology for electric and hybrid cars and create more than 100 jobs. The event ushering in SB Electronics' power ring capacitor facility in Barre was attended by Vermont Gov. Jim Douglas and federal, state and local

92

Modeling of InGaSb thermophotovoltaic cells and materials  

DOE Green Energy (OSTI)

A closed form computer program has been developed for the simulation and optimization of In{sub x}Ga{sub 1{minus}x}Sb thermophotovoltaic cells operating at room temperature. The program includes material parameter models of the energy bandgap, optical absorption constant, electron and hole mobility, intrinsic carrier concentration and index of refraction for any composition of GaInSb alloys.

Zierak, M.; Borrego, J.M.; Bhat, I.; Gutmann, R.J. [Rensselaer Polytechnic Inst., Troy, NY (United States); Charache, G. [Lockheed Martin, Inc., Schenectady, NY (United States)

1997-05-01T23:59:59.000Z

93

Structural and optical studies of nitrogen incorporation into GaSb-based GaInSb quantum wells  

Science Conference Proceedings (OSTI)

We investigate the incorporation of nitrogen into (Ga,In)Sb grown on GaSb and report room temperature photoluminescence from GaInSb(N) quantum wells. X-ray diffraction and channeling nuclear reaction analysis, together with Rutherford backscattering, were employed to identify the optimal molecular beam epitaxial growth conditions that minimized the incorporation of non-substitutional nitrogen into GaNSb. Consistent with this hypothesis, GaInSb(N) quantum wells grown under the conditions that minimized non-substitutional nitrogen exhibited room temperature photoluminescence, indicative of significantly improved radiative efficiency. Further development of this material system could enable type-I laser diodes emitting throughout the (3-5 {mu}m) wavelength range.

Nair, Hari P.; Crook, Adam M.; Bank, Seth R. [Microelectronics Research Center, Electrical and Computer Engineering, University of Texas at Austin, 10100 Burnet Rd, Austin, Texas 78712 (United States); Yu, Kin M. [Electronic Materials Program, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2012-01-09T23:59:59.000Z

94

Sodium sulfur battery seal  

DOE Patents (OSTI)

This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

Mikkor, Mati (Ann Arbor, MI)

1981-01-01T23:59:59.000Z

95

Extraction of trace metals from fly ash  

DOE Patents (OSTI)

A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

1984-01-01T23:59:59.000Z

96

Extraction of trace metals from fly ash  

DOE Patents (OSTI)

A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, M.; Wai, C.M.; Nagy, Z.

1983-08-15T23:59:59.000Z

97

Marketing coal ash, slag, and sludge  

Science Conference Proceedings (OSTI)

The increase in coal-fired power plants and tighter environmental problems have put utilities in the position of marketing coal ash, slag, and sludge by turning waste products into a resource. Many utilities are looking beyond road and structural fill uses in their marketing efforts. Slag can be made into sandblasting grit, aggregate, and roofing granules, or used for soil stabilization or the chemical fixation of municipal wastes. Composition and collection variations discourage many utilities from marketing their by-products, while availability can be a problem for customers if the power plant should shut down. Other problems include storage and transportation, competition, and institutional barriers. Documentation of the fly ash, bottom ash, boiler slag, and scrubber waste markets by the Electric Power Research Institute considers these factors and develops a marketing method to help utilities evaluate and promote their product. (DCK)

Lihach, N.; Golden, D.; Komai, R.; Maulbetsch, J.

1982-12-01T23:59:59.000Z

98

Jet Engine Coatings Resist Volcanic Ash Damage - Materials ...  

Science Conference Proceedings (OSTI)

Apr 27, 2011 ... Upon cooling, the molten ash forms a brittle glass that flakes off, taking the coating with it. Like sand, ash is made mostly of silica and poses a ...

99

Development of High-Volume Fly Ash Blended Cements  

Science Conference Proceedings (OSTI)

High-volume fly ash (HVFA) blended cement can be produced either by intergrinding fly ash with portland cement clinker or by blending dry fly ash with portland cement. Production of HVFA cement using the intergrinding method may be the most cost-effective and practical of the two approaches. This report documents the results of commercial-scale production of HVFA blended cements using up to 55 percent fly ash to replace the portland cement.

2001-10-11T23:59:59.000Z

100

Sodium sulfur battery seal  

SciTech Connect

This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

Topouzian, Armenag (Birmingham, MI)

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Phase equilibrium and intermediate phases in the Eu-Sb system  

SciTech Connect

Rapid heating rate thermal analysis, X-ray diffraction, fluorescence spectrometry, and differential dissolution method were used to study the high-temperature phase equilibrium in the Eu-Sb system within the composition range between 37 and 96 at% Sb. The techniques were effective in determination of the vapor-solid-liquid equilibrium since intermediate phases except Eu{sub 4}Sb{sub 3} evaporated incongruently after melting. A thermal procedure was developed to determine the liquidus and solidus lines of the T-x diagram. Six stable phases were identified: two phases, EuSb{sub 2} and Eu{sub 4}Sb{sub 3}, melt congruently at 1045{+-}10 deg. C and 1600{+-}15 deg. C, the Eu{sub 2}Sb{sub 3}, Eu{sub 11}Sb{sub 10}, Eu{sub 5}Sb{sub 4}, and Eu{sub 5}Sb{sub 3} phases melt incongruently at 850{+-}8 deg. C, 950{+-}10 deg. C, 1350{+-}15 deg. C, and 1445{+-}15 deg. C, respectively. The exact composition shifting of Sb-rich decomposable phases towards Eu{sub 4}Sb{sub 3}, the most refractory compound, was determined. The topology of the Eu-Sb phase diagram was considered together with that of the Yb-Sb system. - Graphical abstract: The high-temperature range of the T-x phase diagram for the Eu-Sb system. Highlights: > The phase relations in the Eu-Sb system were studied over a large composition and temperature scale. > The liquidus and solidus lines of the T-x diagram were well established using effective techniques. > In the system, six binary phases are stable and they melt incongruently except EuSb{sub 2} and Eu{sub 4}Sb{sub 3}. > Incongruent evaporation was found to be typical of all the phases besides Eu{sub 4}Sb{sub 3}.

Abdusalyamova, M.N. [Institute of Chemistry of Tajik Academy of Sciences, Ajni Str. 299/2, 734063 Dushanbe (Tajikistan); Vasilyeva, I.G., E-mail: kamarz@niic.nsc.ru [Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, Lavrentiev Avenue, 3, 630090 Novosibirsk (Russian Federation)

2011-10-15T23:59:59.000Z

102

Use of Coal Ash in Highway Construction: Michigan Demonstration Project  

Science Conference Proceedings (OSTI)

A 3000-ft-length fly ash base under a highway shoulder will help demonstrate the impact of reused ash on structural integrity and groundwater. This report provides valuable design details for utilities seeking to increase ash reuse and for state highway design engineers responsible for preparing construction specifications.

1989-01-10T23:59:59.000Z

103

ASH VITRIFICATION -A TECHNOLOGY READY FOR TRANSFER  

E-Print Network (OSTI)

methods for treating ash in the near future [1]. The lack of specific rules by RCRA has led to confusion the Toxic Characterization Leaching Procedure (TCLP) extraction tests conducted on slag samples which were(ml!!l) in TCLP Extract Arsenic BQL · Barium 0.8 Cadmium 0.010 Chromium BOL Lead 0.43 Mercury 0.0007 Selenium BOL

Columbia University

104

SURVEY OF SODIUM PUMP TECHNOLOGY  

SciTech Connect

A review is presented of the current status of sodium pump development as related to nuclear power applications. A description is given of the design features and performance characteristics of the more important types of sodium and sodium-- potassium alloy (NaK) pumps. Some requirements for sodium pumps for future large liquid metal reactor systems are presented with some preliminary consideration of the potential of various pump types to meet these requirements. (auth)

Nixon, D.R.

1963-06-01T23:59:59.000Z

105

Plutonium dissolution from Rocky Flats Plant incinerator ash  

SciTech Connect

Rockwell Hanford Operations (Rockwell) soon will commence recovery of plutonium from Rocky Flats Plant incinerator ash. In preparation for this processing, Rockwell undertook literature and laboratory studies to identify, select and optimize plutonium dissolution methods for treating the ash. Ash reburning, followed by dissolution in nitric acid containing calcium fluoride, was selected as the processing method for the ash. Recommended values of process parameters were identified. Using the selected process, 99.5% plutonium recovery was achieved, leaving about 12.7 wt % heel residue for an equal weight composite of the three ashes tested. 15 refs., 26 figs.

Delegard, C.H.

1985-06-01T23:59:59.000Z

106

The influence of high quantity of fly ash on reducing the expansion due to ASR in the presence of alkalis  

E-Print Network (OSTI)

A testing program was devised to study the role of high volume fly ash (HVFA) in reducing the expansion caused by alkali-silica reaction (ASR). A series of modified ASTM C 1260 tests were performed, where the replacement of cement by Class F fly ash was 58% by mass of cement. A reactive siliceous aggregate was used. The influence of inherent alkalis in cement to the reaction was also studied. The test results confirm that HVFA significantly helps in controlling expansion caused by ASR. The test period was extended to 28 days to assess if more reproducible results can be obtained. The results indicate that reducing the alkalinity of the sodium hydroxide solution by 50%, to 0.5N is sufficient to determine the potential reactivity of aggregates. The reduction of alkalinity of sodium hydroxide to 0.25N, however, produced results, which were beyond interpretation. Concrete using High Volume Fly Ash was tested for strength to ascertain if the reactive aggregates or the percentage of internal alkalis in the cement influenced the strength. This report discusses the test results for only part of a broader research program in progress at the Texas Transportation Institute, Texas A&M University.

Mohidekar, Saleel D.

2000-01-01T23:59:59.000Z

107

Fly ash and concrete: a study determines whether biomass, or coal co-firing fly ash, can be used in concrete  

SciTech Connect

Current US national standards for using fly ash in concrete (ASTM C618) state that fly ash must come from coal combustion, thus precluding biomass-coal co-firing fly ash. The co-fired ash comes from a large and increasing fraction of US power plants due to rapid increases in co-firing opportunity fuels with coal. The fly ashes include coal fly ash, wood fly ash from pure wood combustion, biomass and coal co-fired fly ash SW1 and SW2. Also wood fly ash is blended with Class C or Class F to produce Wood C and Wood E. Concrete samples were prepared with fly ash replacing cement by 25%. All fly ash mixes except wood have a lower water demand than the pure cement mix. Fly ashes, either from coal or non coal combustion, increase the required air entraining agent (AEA) to meet the design specification of the mixes. If AEA is added arbitrarily without considering the amount or existence of fly ash results could lead to air content in concrete that is either too low or too high. Biomass fly ash does not impact concrete setting behaviour disproportionately. Switch grass-coal co-fired fly ash and blended wood fly ash generally lie within the range of pure coal fly ash strength. The 56 day flexure strength of all the fly ash mixes is comparable to that of the pure cement mix. The flexure strength from the coal-biomass co-fired fly ash does not differ much from pure coal fly ash. All fly ash concrete mixes exhibit lower chloride permeability than the pure cement mixes. In conclusion biomass coal co-fired fly ash perform similarly to coal fly ash in fresh and hardened concrete. As a result, there is no reason to exclude biomass-coal co-fired fly ash in concrete.

Wang, Shuangzhen; Baxter, Larry

2006-08-01T23:59:59.000Z

108

Effect of Sb on the Properties of GaInP Top Cells (Presentation)  

DOE Green Energy (OSTI)

The summary of this report is that: (1) Sb can be used to increase V{sub oc} of a GaInP top cell; (2) the photovoltaic quality of GaInP is relatively unaffected by the presence of Sb; and (3) Sb-doped GaInP/GaAs tandem cells show promise for achieving efficiencies over 32%.

Olson, J. M.; McMahon, W. E.; Kurtz, S.

2006-05-01T23:59:59.000Z

109

Fundamental Study of Low NOx Combustion Fly Ash Utilization  

SciTech Connect

This study is principally concerned with characterizing the organic part of coal combustion fly ashes. High carbon fly ashes are becoming more common as by-products of low-NOx combustion technology, and there is need to learn more about this fraction of the fly ash. The project team consists of two universities, Brown and Princeton, and an electrical utility, New England Power. A sample suite of over forty fly ashes has been gathered from utilities across the United States, and includes ashes from a coals ranging in rank from bituminous to lignite. The characterizations of these ashes include standard tests (LOI, Foam Index), as well as more detailed characterizations of their surface areas, porosity, extractability and adsorption behavior. The ultimate goal is, by better characterizing the material, to enable broadening the range of applications for coal fly ash re-use beyond the current main market as a pozzolanic agent for concretes. The potential for high carbon-content fly ashes to substitute for activated carbons is receiving particular attention. The work performed to date has already revealed how very different the surfaces of different ashes produced by the same utility can be, with respect to polarity of the residual carbon. This can help explain the large variations in acceptability of these ashes as concrete additives.

E. M. Suubert; I. Kuloats; K. Smith; N. Sabanegh; R.H. Hurt; W. D. Lilly; Y. M. Gao

1997-05-01T23:59:59.000Z

110

Manufacture of ceramic tiles from fly ash  

DOE Patents (OSTI)

The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants.

Hnat, James G. (Collegeville, PA); Mathur, Akshay (Tampa, FL); Simpson, James C. (Perkiomenville, PA)

1999-01-01T23:59:59.000Z

111

Manufacture of ceramic tiles from fly ash  

DOE Patents (OSTI)

The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants. 6 figs.

Hnat, J.G.; Mathur, A.; Simpson, J.C.

1999-08-10T23:59:59.000Z

112

Low cost high power GaSB photovoltaic cells  

Science Conference Proceedings (OSTI)

High power density and high capacity factor are important attributes of a thermophotovoltaics (TPV) system and GaSb cells are enabling for TPV systems. A TPV cogeneration unit at an off grid site will compliment solar arrays producing heat and electricity on cloudy days with the solar arrays generating electricity on sunny days. Herein

Lewis M. Fraas; Han X. Huang; Shi-Zhong Ye; She Hui; James Avery; Russell Ballantyne

1997-01-01T23:59:59.000Z

113

Low cost high power GaSb thermophotovoltaic cells  

Science Conference Proceedings (OSTI)

High power density and high capacity factor are important attributes of a TPV system and GaSb cells are enabling for TPV systems. A TPV cogeneration unit at an off grid site will compliment solar arrays producing heat and electricity on cloudy days with the solar arrays generating electricity on sunny days. Herein

Lewis M. Fraas; Han X. Huang; Shi-Zhong Ye; James Avery; Russell Ballantyne

1997-01-01T23:59:59.000Z

114

It's Elemental - The Element Sodium  

NLE Websites -- All DOE Office Websites (Extended Search)

Neon Neon Previous Element (Neon) The Periodic Table of Elements Next Element (Magnesium) Magnesium The Element Sodium [Click for Isotope Data] 11 Na Sodium 22.98976928 Atomic Number: 11 Atomic Weight: 22.98976928 Melting Point: 370.95 K (97.80°C or 208.04°F) Boiling Point: 1156 K (883°C or 1621°F) Density: 0.97 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 1 Group Name: Alkali Metal What's in a name? From the English word soda and from the Medieval Latin word sodanum, which means "headache remedy." Sodium's chemical symbol comes from the Latin word for sodium carbonate, natrium. Say what? Sodium is pronounced as SO-dee-em. History and Uses: Although sodium is the sixth most abundant element on earth and comprises

115

Factors Controlling the Solubility of Mercury Adsorbed on Fly Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

N:\R&D_Projects_Partial\FlyAsh&CCBs\Meetings\2005_04_WorldOfCoalAsh\AnnKim\HgSol N:\R&D_Projects_Partial\FlyAsh&CCBs\Meetings\2005_04_WorldOfCoalAsh\AnnKim\HgSol ubility_Paper.doc Factors Controlling the Solubility of Mercury Adsorbed on Fly Ash Ann G. Kim 1 and Karl Schroeder 2 1 ORISE Research Fellow, National Energy Technology Laboratory, U.S. Department of Energy, 626 Cochrans Mill Rd., Pittsburgh, PA 15236-0940 2 Research Group Leader, National Energy Technology Laboratory, U.S. Department of Energy, 626 Cochrans Mill Rd., Pittsburgh, PA 15236-0940 KEYWORDS Coal Utilization By-Products, leaching, activated carbon, pH ABSTRACT It is expected that increased controls on Hg emissions will shift the environmental burden from the flue gas to the solid coal utilization by-products (CUB), such as fly ash and flue-gas

116

Coal desulfurization with sodium hypochlorite.  

E-Print Network (OSTI)

??Wet desulfurization of Pittsburgh No. 8 coal and Illinois No. 6 coal were conducted with sodium hypochlorite in the laboratory. Pittsburgh No. 8 coal was… (more)

Li, Wei, M.S.

2004-01-01T23:59:59.000Z

117

TANK 40 FINAL SB7B CHEMICAL CHARACTERIZATION RESULTS  

SciTech Connect

A sample of Sludge Batch 7b (SB7b) was taken from Tank 40 in order to obtain radionuclide inventory analyses necessary for compliance with the Waste Acceptance Product Specifications (WAPS). The SB7b WAPS sample was also analyzed for chemical composition including noble metals and fissile constituents, and these results are reported here. These analyses along with the WAPS radionuclide analyses will help define the composition of the sludge in Tank 40 that is currently being fed to the Defense Waste Processing Facility (DWPF) as SB7b. At the Savannah River National Laboratory (SRNL) the 3-L Tank 40 SB7b sample was transferred from the shipping container into a 4-L high density polyethylene bottle and solids were allowed to settle over the weekend. Supernate was then siphoned off and circulated through the shipping container to complete the transfer of the sample. Following thorough mixing of the 3-L sample, a 558 g sub-sample was removed. This sub-sample was then utilized for all subsequent analytical samples. Eight separate aliquots of the slurry were digested, four with HNO{sub 3}/HCl (aqua regia) in sealed Teflon{reg_sign} vessels and four with NaOH/Na{sub 2}O{sub 2} (alkali or peroxide fusion) using Zr crucibles. Two Analytical Reference Glass - 1 (ARG-1) standards were digested along with a blank for each preparation. Each aqua regia digestion and blank was diluted to 1:100 mL with deionized water and submitted to Analytical Development (AD) for inductively coupled plasma - atomic emission spectroscopy (ICP-AES) analysis, inductively coupled plasma - mass spectrometry (ICP-MS) analysis, atomic absorption spectroscopy (AA) for As and Se, and cold vapor atomic absorption spectroscopy (CV-AA) for Hg. Equivalent dilutions of the alkali fusion digestions and blank were submitted to AD for ICP-AES analysis. Tank 40 SB7b supernate was collected from a mixed slurry sample in the SRNL Shielded Cells and submitted to AD for ICP-AES, ion chromatography (IC), total base/free OH{sup -}/other base, total inorganic carbon/total organic carbon (TIC/TOC) analyses, and Cs-137 gamma scan. Weighted dilutions of slurry were submitted for IC, TIC/TOC, and total base/free OH{sup -}/other base analyses. Activities for U-233, U-235, and Pu-239 were determined from the ICP-MS data for the aqua regia digestions of the Tank 40 WAPS slurry using the specific activity of each isotope. The Pu-241 value was determined from a Pu-238/-241 method developed by SRNL AD and previously described. The following conclusions were drawn from the analytical results reported here: (1) The ratios of the major elements for the SB7b WAPS sample are different from those measured for the SB7a WAPS sample. There is less Al and Mn relative to Fe than the previous sludge batch. (2) The elemental composition of this sample and the analyses conducted here are reasonable and consistent with DWPF batch data measurements in light of DWPF pre-sample concentration and SRAT product heel contributions to the DWPF SRAT receipt analyses. The element ratios for Al/Fe, Ca/Fe, Mn/Fe, and U/Fe agree within 10% between this work and the DWPF Sludge Receipt and Adjustment Tank (SRAT) receipt analyses. (3) Sulfur in the SB7b WAPS sample is 82% soluble, slightly less than results reported for SB3, SB4, and SB6 samples but unlike the 50% insoluble sulfur observed in the SB5 WAPS sample. In addition, 23% of the soluble sulfur is not present as sulfate in SB7b. (4) The average activities of the fissile isotopes of interest in the SB7b WAPS sample are (in {mu}Ci/g of total dried solids): 4.22E-02 U-233, 6.12E-04 U-235, 1.08E+01 Pu-239, and 5.09E+01 Pu-241. The full radionuclide composition will be reported in a future document. (5) The fission product noble metal and Ag concentrations appear to have largely peaked in previous DWPF sludge batches, with the exception of Ru, which still shows a slight increase in SB7b.

Bannochie, C.

2012-03-15T23:59:59.000Z

118

Magnetic properties of MnSb inclusions formed in GaSb matrix directly during molecular beam epitaxial growth  

Science Conference Proceedings (OSTI)

Despite of intensive search for the proper semiconductor base materials for spintronic devices working at room temperature no appropriate material based on ferromagnetic semiconductors has been found so far. We demonstrate that the phase segregated system with MnSb hexagonal inclusions inside the GaSb matrix, formed directly during the molecular beam epitaxial growth reveals the ferromagnetic properties at room temperature and is a good candidate for exploitation in spintronics. Furthermore, the MnSb inclusions with only one crystalline structure were identified in this GaMn:MnSb granular material. The SQUID magnetometry confirmed that this material exhibits ferromagnetic like behavior starting from helium up to room temperature. Moreover, the magnetic anisotropy was found which was present also at room temperature, and it was proved that by choosing a proper substrate it is possible to control the direction of easy axis of inclusions' magnetization moment between in-plane and out-of-plane; the latter is important in view of potential applications in spintronic devices.

Lawniczak-Jablonska, Krystyna; Wolska, Anna; Klepka, Marcin T.; Kret, Slawomir; Kurowska, Boguslawa; Kowalski, Bogdan J. [Institute of Physics PAS, al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gosk, Jacek [Institute of Experimental Physics, University of Warsaw, Hoza 69, 00-681 Warsaw (Poland); Faculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw (Poland); Twardowski, Andrzej; Wasik, Dariusz; Kwiatkowski, Adam [Institute of Experimental Physics, University of Warsaw, Hoza 69, 00-681 Warsaw (Poland); Sadowski, Janusz [Institute of Physics PAS, al. Lotnikow 32/46, 02-668 Warsaw (Poland); MAX-Lab, Lund University, SE-221 00 Lund (Sweden)

2011-04-01T23:59:59.000Z

119

In-Plant Ash-Handling Reference Manual  

Science Conference Proceedings (OSTI)

Despite problems with ash-handling systems that have led to failures in electrostatic precipitators, there has been no extensive reference manual for specifying, operating, and maintaining such systems. The comprehensive manual compiled in this study serves as a reference for every phase of boiler bottom ash- and fly ash-handling systems design and operation as well as a primer for those unfamiliar with these systems.

1986-12-01T23:59:59.000Z

120

Recovery of aluminum and other metal values from fly ash  

DOE Patents (OSTI)

The invention relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

McDowell, W.J.; Seeley, F.G.

1979-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Recovery of aluminum and other metal values from fly ash  

DOE Patents (OSTI)

The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

1981-01-01T23:59:59.000Z

122

The Effect of Ammonia on Mercury Partitioning in Fly Ash  

Science Conference Proceedings (OSTI)

Management options and environmental assessments for fly ash are driven primarily by their physical and chemical characteristics. This report describes the results of a laboratory study on the leaching of mercury from several paired fly ash samples from facilities employing powdered activated carbon (PAC) injection for mercury control. While previous EPRI research has shown that mercury leaching from ash with PAC is negligible, it has also been found that ammonia complexes can increase the mobility of so...

2008-03-25T23:59:59.000Z

123

Identification of Arsenic Species in Coal Ash Particles  

Science Conference Proceedings (OSTI)

Identification of the chemical species and compounds of arsenic in individual coal fly ash particles will help provide a scientifically sound basis for assessing health risks from inhalation of these particles. This report presents the results of an analytical chemistry study of coal-combustion ash, with some work also completed on oil-combustion ash and copper smelter dust collected from several sources in the United States and Europe. Results showed that most arsenic is present on the surface of coal a...

1998-08-13T23:59:59.000Z

124

NETL: Utilization Projects - Managing High-Carbon Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

Managing High-Carbon Ash Managing High-Carbon Ash Task 1: Effect of Coal Quality The objective of this task is to assess if fuel selection is an important factor determining ash quality. Work on this task will involve each of the three participating organizations. Ash samples from three coals will be generated under identical firing conditions in the pilot furnace at the University of Utah, and the matching ash and coal samples sent to Brown. Additional matching sets of coal and ash will be obtained from commercial-scale firing at Southern Company. The ashes will be characterized for LOI and surfactant adsorption activity under standard conditions and trends with fuel type identified. At the same time, chars will be prepared from the matching coal set under standard conditions in a laboratory furnace and also characterized for surfactant adsorptivity. A variety of standard conditions may need to be explored. The combined data set will be analyzed to determine cross correlations between ash behavior, standard laboratory char behavior, and parent coal properties. Our goal is to be able to anticipate ash behavior either (a) from coal properties directly, or (b) from the properties of chars made by a simple laboratory procedure. Either could be the basis for a coal quality index -- one based on fuel properties and the other based on a simple screening test.

125

Embankment Loading on Saturated Coal Ash: Centrifuge Demonstration Test  

Science Conference Proceedings (OSTI)

When an embankment of coal combustion residuals or soil is built over a coal ash pond, pore water pressures can accumulate in the underlying saturated ash deposits and trigger a rapid slope failure. This report documents a scale model test completed to obtain data on the conditions that may lead to a slope failure. A 6.5-inch tall sand embankment was built on top of a 6-inch thick deposit of saturated fly ash. The strength of the fly ash was characterized using consolidated undrained triaxial ...

2013-12-10T23:59:59.000Z

126

Data Summary Report for Hanford Site Coal Ash Characterization  

Science Conference Proceedings (OSTI)

The purpose of this report is to present data and findings from sampling and analysis of five distinct areas of coal ash within the Hanford Site River Corridor

Sulloway, H. M.

2012-03-06T23:59:59.000Z

127

Coal Fly Ash as Alternative Source of Smelter Grade Alumina  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, COM 2011. Symposium, COM 2011 (held with the World Gold Conference), POSTER SESSION. Presentation Title, Coal Fly Ash as

128

HIGH STRENGTH PHOSPHATE CEMENT USING INDUSTRIAL BYPRODUCT ASHES ...  

industries that use fossil fuels. Approximately one third of this ash is recycled in the cement based products as an additive. Typically, ...

129

Kinetics of beneficiated fly ash by carbon burnout  

Science Conference Proceedings (OSTI)

The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called Loss On Ignition (LOI). The concrete producers` day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

Okoh, J.M.; Dodoo, J.N.D.; Diaz, A. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States). Dept. of Natural Sciences; Ferguson, W.; Udinskey, J.R. Jr.; Christiana, G.A. [Delmarva Power, Wilmington, DE (United States)

1997-12-31T23:59:59.000Z

130

Mechanical Activation of Deposited Fly Ash by Grinding  

Science Conference Proceedings (OSTI)

May 1, 2007 ... According to laboratory experience the breaking of fly ash particles is required to increase its hydraulic potential (Opoczky, 2001). Aim of the ...

131

NETL: News Release - Novel Treatment of Fly Ash Yields Safer...  

NLE Websites -- All DOE Office Websites (Extended Search)

successfully tested at near full-scale levels. Easily integrated with existing ash handling equipment, the simple-to-operate, cost-efficient technology can be retrofitted to...

132

Study on Aluminum Foam with Fly Ash Increase Viscosity  

Science Conference Proceedings (OSTI)

May 1, 2007 ... Study on Aluminum Foam with Fly Ash Increase Viscosity by Yong Wang, Guang- chun Yao, and Bing Li. Publisher: TMS. Product Format: PDF.

133

Proportioning CLSM Using Fly Ash and GGBS - Programmaster.org  

Science Conference Proceedings (OSTI)

Presentation Title, Proportioning CLSM Using Fly Ash and GGBS. Author(s), Udayashankar B C, Raghavendra T. On-Site Speaker (Planned), Udayashankar  ...

134

Rebound characteristics for ash particles impacting a planar surface  

Science Conference Proceedings (OSTI)

The formation of ash deposition on the heat transfer tubes in a boiler reduces the heat transfer coefficient by about 25%. Because of these fouling layers

2013-01-01T23:59:59.000Z

135

Thermophysical Properties of Sodium Nitrate and Sodium Chloride  

Office of Scientific and Technical Information (OSTI)

Thermophysical Properties of Sodium Nitrate and Sodium Chloride Thermophysical Properties of Sodium Nitrate and Sodium Chloride Solutions and Their Effects on Fluid Flow in Unsaturated Media Tianfu Xu and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 ABSTRACT. Understanding movement of saline sodium nitrate (NaNO 3 ) waste solutions is important for assessing the contaminant migration near leaking waste storage tanks in the unsaturated zone at the Hanford site (Washington, USA). The purpose of this study is to contribute a basic understanding of effects of the thermophysical behavior of NaNO 3 solutions on fluid flow in unsaturated media. We first present mathematical expressions for the dependence of density, viscosity, solubility and vapor pressure of

136

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network (OSTI)

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwater using  iron?oxide coated coal bottom ash  Johanna L.  using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

137

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants  

E-Print Network (OSTI)

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants PSO Project No. 6356 July 2008 Renewable Energy and Transport #12;2 Utilization of Ash Fractions from Alternative Biofuels)...............................................................................7 2. Production of Ash Products from Mixed Biofuels

138

Environmental Performance Assessment of Coal Ash Use Sites: Waukegan Ash Embankment  

Science Conference Proceedings (OSTI)

A comprehensive database on the environmental effects of reusing coal combustion residues is essential to increased application of these products. This report discusses changes in soils, vegetation, and groundwater quality around an embankment containing coal fly ash and develops an approach for building a statistically sound environmental performance database.

1991-01-03T23:59:59.000Z

139

Long-Range Forecast Trajectories of Volcanic Ash from Redoubt Ash from Redoubt Volcano Eruptions  

Science Conference Proceedings (OSTI)

The Redoubt Volcano in Alaska began a series of eruptions on 14 December 1989. Volcanic ash was often reported to reach heights where, as it moved with the upper-level flow, it could affect aircraft operations thousands of km from the eruption. ...

Jerome L. Heffter; Barbara J. B. Stunder; Glenn D. Rolph

1990-12-01T23:59:59.000Z

140

Environmental Performance Assessment of Coal Ash Use Sites: Little Canada Structural Ash Fill  

Science Conference Proceedings (OSTI)

An insufficient database on the environmental effects of reusing coal combustion residues hampers increased utilization of these products. This report discusses the changes in soils, vegetation, and groundwater quality around a structural fill containing coal fly ash and develops an approach for building a statistically sound environmental performance database.

1990-06-06T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Evaluation of Leachate Chemistry from Coal Refuse Blended and Layered with Fly Ash.  

E-Print Network (OSTI)

??Alkaline fly ash has been studied as a liming agent within coal refuse fills to reclaim acid-forming refuse. Previous studies focused on bulk blending ash… (more)

Hunt, Joseph Edward

2008-01-01T23:59:59.000Z

142

Hazards Associated with the Use of Bone Ash in Contact with Molten ...  

Science Conference Proceedings (OSTI)

Bone ash itself is non-toxic and environmentally benign. However recent evidence indicates that bone ash can be reduced upon contact with aluminum alloys to ...

143

GaSb substrates with extended IR wavelength for advanced space based applications  

SciTech Connect

GaSb substrates have advantages that make them attractive for implementation of a wide range of infrared (IR) detectors with higher operating temperatures for stealth and space based applications. A significant aspect that would enable widespread commercial application of GaSb wafers for very long wavelength IR (VLWIR) applications is the capability for transmissivity beyond 15 m. Due largely to the GaSb (antisite) defect and other point defects in undoped GaSb substrates, intrinsic GaSb is still slightly p-type and strongly absorbs in the VLWIR. This requires backside thinning of the GaSb substrate for IR transmissivity. An extremely low n-type GaSb substrate is preferred to eliminate thinning and provide a substrate solution for backside illuminated VLWIR devices. By providing a more homogeneous radial distribution of the melt solute to suppress GaSb formation and controlling the cooling rate, ultra low doped n:GaSb has been achieved. This study examines the surface properties and IR transmission spectra of ultra low doped GaSb substrates at both room and low temperatures. Atomic force microscopy (AFM), homoepitaxy by MBE, and infrared Fourier transform (FTIR) analysis was implemented to examine material quality. As compared with standard low doped GaSb, the ultra low doped substrates show over 50% transmission and consistent wavelength transparency past 23 m with improved %T at low temperature. Homoepitaxy and AFM results indicate the ultra low doped GaSb has a low thermal desorbtion character and qualified morphology. In summary, improvements in room temperature IR transmission and extended wavelength characteristics have been shown consistently for ultra low doped n:GaSb substrates.

Allen, Lisa P.; Flint, Patrick; Dallas, Gordon; Bakken, Daniel; Blanchat, Kevin; Brown, Gail J.; Vangala, Shivashankar R.; Goodhue, William D.; Krishnaswami, Kannan

2009-05-01T23:59:59.000Z

144

IN HARM'S WAY: Lack Of Federal Coal Ash  

E-Print Network (OSTI)

IN HARM'S WAY: Lack Of Federal Coal Ash Regulations Endangers Americans And Their Environment 2010 Thirty-nine New Damage Cases of Contamination from Improperly Disposed Coal Combustion Waste, Editor and Contributing Author #12;IN HARM'S WAY: Lack of Federal Coal Ash Regulations Endangers

Short, Daniel

145

Characterization of Ammonia Leaching from Coal Fly Ash  

Science Conference Proceedings (OSTI)

This interim report presents the results of a preliminary laboratory assessment of the leaching of ammonia from coal ashes that have been ammoniated by pollution control devices installed on power plants to reduce nitrogen oxide (NOx) emissions. This laboratory assessment project was designed to measure the leaching rates of ammonia from ashes in a disposal environment.

2001-11-30T23:59:59.000Z

146

Infiltration Processing of Metal Matrix-Fly Ash Particle Composites  

Science Conference Proceedings (OSTI)

Metal Matrix composites can provide improved functional properties compared to solid metal castings while saving production energy and raw material costs. Ash-derived metal matrix composites, in particular, can provide high value-added use to coal fly ash. This report describes research on use of pressure infiltration techniques to produce composites for automotive component applications.

1997-09-16T23:59:59.000Z

147

Process for the recovery of alumina from fly ash  

DOE Patents (OSTI)

An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

Murtha, M.J.

1983-08-09T23:59:59.000Z

148

Use of Coal Ash in Highway Construction: Michigan Demonstration Project  

Science Conference Proceedings (OSTI)

This report documents the construction and performance testing of a 3000-ft length of fly ash base under a highway shoulder. Following three years of service, the road shoulder shows no signs of premature deterioration. This report should aid utilities seeking to increase ash-use rates in highway-related projects, as well as state highway design engineers responsible for preparing construction specifications.

1991-03-05T23:59:59.000Z

149

Manganese Occurrence Near Three Coal Ash Impoundments in Illinois  

Science Conference Proceedings (OSTI)

This report describes research performed to better understand the cause of elevated manganese concentrations sometimes found in groundwater near coal ash management facilities. Three impoundments in Illinois were selected for detailed field and laboratory studies of conditions conducive to manganese release from coal ash as well as natural soils.

2002-09-24T23:59:59.000Z

150

The recycling of the coal fly ash in glass production  

Science Conference Proceedings (OSTI)

The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

2006-09-15T23:59:59.000Z

151

Substrate misorientation effects on epitaxial GaInAsSb  

DOE Green Energy (OSTI)

The effect of substrate misorientation on the growth of GaInAsSb was studied for epilayers grown lattice-matched to GaSb substrates by low-pressure organometallic vapor phase epitaxy. The substrates were (100) misoriented 2 or 6{degree} toward (110), (111)A, or (111)B. The surface is mirror-like and featureless for layers grown with a 6{degree} toward (111)B misorientation, while, a slight texture was observed for layers grown on all other misorientations. The optical quality of layers, as determined by the full width at half-maximum of photoluminescence spectra measured at 4K, is significantly better for layers grown on substrates with a 6{degree} toward (111)B misorientation. The incorporation of Zn as a p-type dopant in GaInAsSb is about 1.5 times more efficient on substrates with 6{degree} toward (111)B misorientation compared to 2{degree} toward (110) misorientation. The external quantum efficiency of thermophotovoltaic devices is not, however, significantly affected by substrate misorientation.

Wang, C.A.; Choi, H.K.; Oakley, D.C. [Massachusetts Inst. of Tech., Lexington, MA (United States). Lincoln Lab.; Charache, G.W. [Lockheed Martin Corp., Schenectady, NY (United States)

1997-12-01T23:59:59.000Z

152

Ashe County - Wind Energy System Ordinance | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ashe County - Wind Energy System Ordinance Ashe County - Wind Energy System Ordinance Ashe County - Wind Energy System Ordinance < Back Eligibility Agricultural Commercial Industrial Institutional Investor-Owned Utility Local Government Multi-Family Residential Municipal Utility Nonprofit Residential Rural Electric Cooperative Schools State Government Tribal Government Utility Savings Category Wind Buying & Making Electricity Program Info State North Carolina Program Type Solar/Wind Permitting Standards Provider Ashe County Planning Department In 2007 Ashe County adopted a wind ordinance to regulate the use of wind-energy systems in unincorporated areas of the county and to describe the conditions by which a permit for installing such a system may be obtained. This policy was adopted in the context of an ongoing debate over

153

Purple traps yield Reservation's first detection of Emerald Ash Borer  

NLE Websites -- All DOE Office Websites (Extended Search)

traps yield Reservation's first detection of Emerald Ash Borer traps yield Reservation's first detection of Emerald Ash Borer The question of whether or not DOE's forests are infested with Emerald Ash Borer (EAB) has been answered. On May 10, a trap on Highway 95 at the Highway 58 interchange produced the first instance of the destructive non-native insect in Roane County. Five days later, a second trap on Bethel Valley Road near the East Portal turned up the first capture in Anderson County. "Unfortunately, these finds signal the beginning of a decline of ash species throughout the reservation" according to Greg Byrd, forester with the ORNL Natural Resources Program. "Dieback will become more prominent as the insect populations expand. Native ash trees have little defense against this pest, which was

154

Element associations in ash from waste combustion in fluidized bed  

SciTech Connect

The incineration of MSW in fluidized beds is a commonly applied waste management practice. The composition of the ashes produced in a fluidized bed boiler has important environmental implications as potentially toxic trace elements may be associated with ash particles and it is therefore essential to determine the mechanisms controlling the association of trace elements to ash particles, including the role of major element composition. The research presented here uses micro-analytical techniques to study the distribution of major and trace elements and determine the importance of affinity-based binding mechanisms in separate cyclone ash particles from MSW combustion. Particle size and the occurrence of Ca and Fe were found to be important factors for the binding of trace elements to ash particles, but the binding largely depends on random associations based on the presence of a particle when trace elements condensate in the flue gas.

Karlfeldt Fedje, K., E-mail: karinka@chalmers.s [Department of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers University of Technology, Kemivaegen 10, 412 96 Goeteborg (Sweden); Rauch, S. [Department of Civil and Environmental Engineering, Division of Water Environment Technology, Chalmers University of Technology, Sven Hultins Gata 8, 412 96 Goeteborg (Sweden); Cho, P.; Steenari, B.-M. [Department of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers University of Technology, Kemivaegen 10, 412 96 Goeteborg (Sweden)

2010-07-15T23:59:59.000Z

155

State Waste Discharge Permit application: 200-W Powerhouse Ash Pit  

Science Conference Proceedings (OSTI)

As part of the Hanford Federal Facility Agreement and Consent Order negotiations; the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-W Powerhouse Ash Pit. The 200-W Powerhouse Ash Waste Water discharges to the 200-W Powerhouse Ash Pit via dedicated pipelines. The 200-W Powerhouse Ash Waste Water is the only discharge to the 200-W Powerhouse Ash Pit. The 200-W Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

Atencio, B.P.

1994-06-01T23:59:59.000Z

156

Simulation of sodium boiling experiments with THERMIT sodium version  

E-Print Network (OSTI)

Natural and forced convection experiments(SBTF and French) are simulated with the sodium version of the thermal-hydraulic computer code THERMIT. Simulation is done for the test secti- -on with the pressure-velocity boundary ...

Huh, Kang Yul

1982-01-01T23:59:59.000Z

157

COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS  

SciTech Connect

The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

2001-04-01T23:59:59.000Z

158

Water simulation of sodium reactors  

Science Conference Proceedings (OSTI)

The thermal hydraulic simulation of a large sodium reactor by a scaled water model is examined. The Richardson Number, friction coefficient and the Peclet Number can be closely matched with the water system at full power and the similarity is retained for buoyancy driven flows. The simulation of thermal-hydraulic conditions in a reactor vessel provided by a scaled water experiment is better than that by a scaled sodium test. Results from a correctly scaled water test can be tentatively extrapolated to a full size sodium system.

Grewal, S.S.; Gluekler, E.L.

1981-06-28T23:59:59.000Z

159

Behavior of Ammoniated Fly Ash: Effects of Ammonia on Fly Ash Handling, Disposal, and End-Use  

Science Conference Proceedings (OSTI)

The implementation of ammonia-based nitrogen oxides (NOx) control technologies has had the undesired side effect of creating potential problems for operating units due to ammonia-contaminated fly ash. The work described in this report is a continuation of long-term EPRI efforts to address various industry concerns associated with ammoniated fly ash.

2002-02-22T23:59:59.000Z

160

Toxicity mitigation and solidification of municipal solid waste incinerator fly ash using alkaline activated coal ash  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Incinerator fly ash (IFA) is added to an alkali activated coal fly ash (CFA) matrix. Black-Right-Pointing-Pointer Means of stabilizing the incinerator ash for use in construction applications. Black-Right-Pointing-Pointer Concrete made from IFA, CFA and IFA-CFA mixes was chemically characterized. Black-Right-Pointing-Pointer Environmentally friendly solution to IFA disposal by reducing its toxicity levels. - Abstract: Municipal solid waste (MSW) incineration is a common and effective practice to reduce the volume of solid waste in urban areas. However, the byproduct of this process is a fly ash (IFA), which contains large quantities of toxic contaminants. The purpose of this research study was to analyze the chemical, physical and mechanical behaviors resulting from the gradual introduction of IFA to an alkaline activated coal fly ash (CFA) matrix, as a mean of stabilizing the incinerator ash for use in industrial construction applications, where human exposure potential is limited. IFA and CFA were analyzed via X-ray fluorescence (XRF), X-ray diffraction (XRD) and Inductive coupled plasma (ICP) to obtain a full chemical analysis of the samples, its crystallographic characteristics and a detailed count of the eight heavy metals contemplated in US Title 40 of the Code of Federal Regulations (40 CFR). The particle size distribution of IFA and CFA was also recorded. EPA's Toxicity Characteristic Leaching Procedure (TCLP) was followed to monitor the leachability of the contaminants before and after the activation. Also images obtained via Scanning Electron Microscopy (SEM), before and after the activation, are presented. Concrete made from IFA, CFA and IFA-CFA mixes was subjected to a full mechanical characterization; tests include compressive strength, flexural strength, elastic modulus, Poisson's ratio and setting time. The leachable heavy metal contents (except for Se) were below the maximum allowable limits and in many cases even below the reporting limit. The leachable Chromium was reduced from 0.153 down to 0.0045 mg/L, Arsenic from 0.256 down to 0.132 mg/L, Selenium from 1.05 down to 0.29 mg/L, Silver from 0.011 down to .001 mg/L, Barium from 2.06 down to 0.314 mg/L and Mercury from 0.007 down to 0.001 mg/L. Although the leachable Cd exhibited an increase from 0.49 up to 0.805 mg/L and Pd from 0.002 up to 0.029 mg/L, these were well below the maximum limits of 1.00 and 5.00 mg/L, respectively.

Ivan Diaz-Loya, E. [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Allouche, Erez N., E-mail: allouche@latech.edu [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Eklund, Sven; Joshi, Anupam R. [Department of Chemistry, Louisiana Tech University, Ruston, LA 71272 (United States); Kupwade-Patil, Kunal [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States)

2012-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


161

SLUDGE BATCH 7 (SB7) WASHING DEMONSTRATION TO DETERMINE SULFATE/OXALATE REMOVAL EFFICIENCY AND SETTLING BEHAVIOR  

SciTech Connect

To support Sludge Batch 7 (SB7) washing, a demonstration of the proposed Tank Farm washing operation was performed utilizing a real-waste test slurry generated from Tank 4, 7, and 12 samples. The purpose of the demonstration was twofold: (1) to determine the settling time requirements and washing strategy needed to bring the SB7 slurry to the desired endpoint; and (2) to determine the impact of washing on the chemical and physical characteristics of the sludge, particularly those of sulfur content, oxalate content, and rheology. Seven wash cycles were conducted over a four month period to reduce the supernatant sodium concentration to approximately one molar. The long washing duration was due to the slow settling of the sludge and the limited compaction. Approximately 90% of the sulfur was removed through washing, and the vast majority of the sulfur was determined to be soluble from the start. In contrast, only about half of the oxalate was removed through washing, as most of the oxalate was initially insoluble and did not partition to the liquid phase until the latter washes. The final sulfur concentration was 0.45 wt% of the total solids, and the final oxalate concentration was 9,900 mg/kg slurry. More oxalate could have been removed through additional washing, although the washing would have reduced the supernatant sodium concentration.The yield stress of the final washed sludge (35 Pa) was an order of magnitude higher than that of the unwashed sludge ({approx}4 Pa) and was deemed potentially problematic. The high yield stress was related to the significant increase in insoluble solids that occurred ({approx}8 wt% to {approx}18 wt%) as soluble solids and water were removed from the slurry. Reduction of the insoluble solids concentration to {approx}14 wt% was needed to reduce the yield stress to an acceptable level. However, depending on the manner that the insoluble solids adjustment was performed, the final sodium concentration and extent of oxalate removal would be prone to change. As such, the strategy for completing the final wash cycle is integral to maintaining the proper balance of chemical and physical requirements.

Reboul, S.; Click, D.; Lambert, D.

2010-12-10T23:59:59.000Z

162

Low-Pressure Sodium Lighting  

Energy.gov (U.S. Department of Energy (DOE))

Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color rendition. Typical applications include highway and...

163

IMPACT OF SB4 TANK 40 DECANT AND ARP/MCU ADDITIONS WITH/WITHOUT ADDED CAUSTIC ON DWPF CPC PERFORMANCE  

DOE Green Energy (OSTI)

The Savannah River National Laboratory (SRNL) was requested to investigate the impact of decanting supernate from the Sludge Batch four (SB4) feed in Tank 40. The specific questions concerned the potential impact on the stoichiometric acid window determined for SB4 with respect to overall hydrogen generation rates, nitrite destruction in the Sludge Receipt and Adjustment Tank (SRAT) and the rheology of the sludge, SRAT product, and Slurry Mix Evaporator (SME) product slurries. The scope included considering an addition of sodium hydroxide to Tank 40 to partially offset the sodium lost during decanting as well as considering the impact of bounding quantities of Actinide Removal Process (ARP) feed and Modular Caustic-Side Solvent Extraction Unit (MCU) feed on these same parameters. Simulated SB4 waste was first adjusted to match the dilution that has occurred in Tank 40 during the initial period of SB4 operations in the DWPF. The adjusted simulant was decanted an equivalent of 100,000 gallons relative to 413,740 gallons projected supernate volume. The decanted simulant was divided into two equal parts. One part received an addition of sodium hydroxide to increase the Na{sub 2}O content of the calcined sludge solids by about 3%. The baseline decanted simulant and caustic adjusted simulant were each tested in three pairs of DWPF process simulations of the SRAT and SME cycles. The simulations were at the nominal SB4 acid stoichiometry of 130% with and without bounding ARP/MCU additions and at 170% of acid without ARP/MCU. The 170% case without ARP/MCU was considered bounding relative to 170% with ARP/MCU based on calculated acid requirements. No significant negative impacts on the proposed acid operating window for the SRAT and SME cycles were noted in the simulations. Nitrite was successfully destroyed and mercury reduced in all six SRAT cycles. Hydrogen was produced in all six SRAT and SME cycles, but the levels were below the DWPF SRAT and SME cycle limits in all cases. Relatively insignificant rheological changes were noted other than the previously established thinning from higher acid additions. SRAT and SME processing at 130% acid stoichiometry with and without ARP/MCU additions were very similar. MCU nitric acid content, however, shifted the normal acid addition prior to boiling toward more formic acid and less nitric acid than without MCU. SRNL found no technical issues processing the proposed Tank 40 decant (with or without added NaOH) from the standpoint of the impact on the DWPF SRAT and SME cycles subject to the inherent uncertainties in modeling the ARP noble metal concentrations. The noble metals in the ARP were set to the same weight percents in the total solids that they were measured at in the SB4 waste, which was considered likely to be bounding on the actual noble metal content of the ARP transfer to DWPF. Assumptions for formate loss and nitrite to nitrate conversion can be left at the current levels.

Koopman, D; David Best, D; Frances Williams, F

2008-04-18T23:59:59.000Z

164

Method of making AlInSb by metal-organic chemical vapor deposition  

DOE Patents (OSTI)

A method for producing aluminum-indium-antimony materials by metal-organic chemical vapor deposition (MOCVD). This invention provides a method of producing Al.sub.X In.sub.1-x Sb crystalline materials by MOCVD wherein an Al source material, an In source material and an Sb source material are supplied as a gas to a heated substrate in a chamber, said Al source material, In source material, and Sb source material decomposing at least partially below 525.degree. C. to produce Al.sub.x In.sub.1-x Sb crystalline materials wherein x is greater than 0.002 and less than one.

Biefeld, Robert M. (Albuquerque, NM); Allerman, Andrew A. (Albuquerque, NM); Baucom, Kevin C. (Albuquerque, NM)

2000-01-01T23:59:59.000Z

165

Categorical Exclusion 4566, Ash Removal Project  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FOrnI FOrnI Project Title: Ash Removal Project (4566) Program or Program Office: Y -12 Site Office Location: Oak Ridge Tennessee Project Description: This work scope is to split, containerize, package, transport and disposition one hundred and two (102) cans of mixed waste. General Administration/Management OA I - Routine business actions OA2 * Administrative contract amendments OA4 - Interpretations/rulings for existing regulations OA5 - Regulatory interpretations without environmental effect OA6 - Procedural rule makings upgrade OA 7 - Transfer of property, use unchanged OA8 . Award of technical supportlM&O/personal service contracts OA9 - Info gathering, analysis, documentation, dissemination, and training OA 10 - Reports on non-DOE legislation OA II -

166

Phenolic acids as bioindicators of fly ash deposit revegetation  

Science Conference Proceedings (OSTI)

The floristic composition, the abundance, and the cover of pioneer plant species of spontaneously formed plant communities and the content of total phenolics and phenolic acids, as humus constituents, of an ash deposit after 7 years of recultivation were studied. The restoration of both the soil and the vegetation on the ash deposits of the 'Nikola Tesla-A' thermoelectric power plant in Obrenovac (Serbia) is an extremely slow process. Unfavorable physical and chemical characteristics, the toxicity of fly ash, and extreme microclimatic conditions prevented the development of compact plant cover. The abundance and cover of plants increased from the central part of the deposit towards its edges. Festuca rubra L., Crepis setosa Hall., Erigeron canadensis L., Cirsium arvense (L.) Scop., Calamagrostis epigeios (L.) Roth., and Tamarix gallica L. were the most abundant species, thus giving the highest cover. Humus generated during the decomposition process of plant remains represents a completely new product absent in the ash as the starting material. The amount of total phenolics and phenolic acids in fly ash increased from the center of the deposit towards its edges in correlation with the increase in plant abundance and cover. The presence of phenolic acids indicates the ongoing process of humus formation in the ash, in which the most abundant pioneer plants of spontaneously formed plant communities play the main role. Phenolic compounds can serve as reliable bioindicators in an assessment of the success of the recultivation process of thermoelectric power plants' ash deposits.

L. Djurdjevic; M. Mitrovic; P. Pavlovic; G. Gajic; O. Kostic [Institute for Biological Research 'Sinisa Stankovic,' Belgrade (Serbia and Montenegro). Department of Ecology

2006-05-15T23:59:59.000Z

167

Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power Plants  

E-Print Network (OSTI)

Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power color from pulp mill effluent using coal ash. Prevent coal ash adsorbent from leaching arsenic, chromium, lead, and zinc. Define a treatment procedure using coal ash that will result in the maximum

Hutcheon, James M.

168

Respiratory and Reproductive Characteristics of Eastern Mosquitofish (Gambusia holbrooki) Inhabiting a Coal Ash Settling Basin  

E-Print Network (OSTI)

) Inhabiting a Coal Ash Settling Basin B. P. Staub, W. A. Hopkins, J. Novak, J. D. Congdon Savannah River 2002/Accepted: 29 March 2002 Abstract. Coal fly ash and effluent from coal ash settling basins viable populations in areas contaminated by coal ash. While eastern mosquitofish are present

Hopkins, William A.

169

Coal- and Ash-Handling Systems Reliability Conference and Workshop Proceedings  

Science Conference Proceedings (OSTI)

This report presents papers, discussion summaries, and conclusions from an EPRI workshop on reliability problems with coal- and ash-handling systems in power plants. Held in October 1980 in St. Louis, the workshop covered yard and in-plant coal handling, frozen coal, fugitive dust, fly ash handling, bottom ash handling, and ash disposal.

1981-08-01T23:59:59.000Z

170

Proceedings: Tenth International Ash Use Symposium, Volume 1: High-Volume Uses/Concrete Applications  

Science Conference Proceedings (OSTI)

Topics discussed at the tenth symposium on coal ash use included fundamental ash use research, product marketing, applied research, ash management and the environment, and commercial applications. Intense international research interest continues in coal ash use due to the prospects of avoiding disposal costs and generating revenue from by-product sales.

1993-01-22T23:59:59.000Z

171

High Volume Fly Ash Blended Cements: Status Report  

Science Conference Proceedings (OSTI)

At present, the production of high-volume fly ash (HVFA) concrete involves the addition of large volumes of fly ash as a separate ingredient at a ready-mixed concrete batch plant. This necessitates additional storage silos and quality control at the job site. In order to resolve these issues, CANMET, in partnership with Electric Power Research Institute, U.S.A., undertook a major research project to develop blended cements incorporating high volumes of ASTM Class fly ash. The blended cements are made by ...

1999-10-28T23:59:59.000Z

172

Recovery of iron oxide from coal fly ash  

DOE Patents (OSTI)

A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

Dobbins, Michael S. (Ames, IA); Murtha, Marlyn J. (Ames, IA)

1983-05-31T23:59:59.000Z

173

Arsenic and Selenium Speciation in Fly Ash and Wastewater  

Science Conference Proceedings (OSTI)

The objective of the work is to predict As and Se behavior in pond wastewater based on coal and power plant characteristics so that utilities will have tools for selection of coals (and blends) that will allow them to meet applicable water quality regulations in the ash pond discharge. Arsenic and selenium were chosen as the focus of this work because the behavior of arsenic and selenium is not well correlated with pH in ash pond water, but with speciation of these oxyanions in the fly ash. Furthermore, ...

2005-03-28T23:59:59.000Z

174

Scale-up and Demonstration of Fly Ash Ozonation Technology  

Science Conference Proceedings (OSTI)

This project is the first large pilot scale test of a new process to passivate the carbon in ash so that it can be used in concrete without physically removing the carbon from the ash. The tests were conducted at PPL's Montour SES, sponsored by DOE and supported by EPRI. Near full-scale industrial equipment was used to expose fly ash, carbon mixtures to ozone to see if ozone would passivate the surface of carbon so that it would not react with air entraining agents that are used by concrete manufacturers...

2005-11-29T23:59:59.000Z

175

Temperature dependence of the dielectric response of AlSb  

SciTech Connect

Spectroscopic ellipometry was used to determine the optical response of an intrinsic AlSb film as a function of temperature. The 1.5 {mu}m thick film was grown on a (001) GaAs substrate by molecular beam epitaxy. Measurements were done at temperatures from 300 K to the growth temperature of 800 K over a spectral range of 0.7 to 5.0 eV. To avoid oxidation artifacts, measurements were done with the film in situ. The data were analyzed using a parametric semiconductor model for its temperature dependence.

Jung, Y. W.; Kim, T. J.; Kim, Y. D. [Nano-Optical Property Laboratory and Department of Physics, Kyung Hee University, Seoul (Korea, Republic of); Shin, S. H.; Kim, S. Y.; Song, J. D. [Center for Spintronics Research, Korea Institute of Science and Technology, Seoul (Korea, Republic of)

2011-12-23T23:59:59.000Z

176

Tank 40 Final SB7b Chemical Characterization Results  

SciTech Connect

A sample of Sludge Batch 7b (SB7b) was taken from Tank 40 in order to obtain radionuclide inventory analyses necessary for compliance with the Waste Acceptance Product Specifications (WAPS). The SB7b WAPS sample was also analyzed for chemical composition including noble metals and fissile constituents. At the Savannah River National Laboratory (SRNL) the 3-L Tank 40 SB7b sample was transferred from the shipping container into a 4-L high density polyethylene bottle and solids were allowed to settle over the weekend. Supernate was then siphoned off and circulated through the shipping container to complete the transfer of the sample. Following thorough mixing of the 3-L sample, a 558 g sub-sample was removed. This sub-sample was then utilized for all subsequent analytical samples. Eight separate aliquots of the slurry were digested, four with HNO{sub 3}/HCl (aqua regia) in sealed Teflon? vessels and four with NaOH/Na{sub 2}O{sub 2} (alkali or peroxide fusion) using Zr crucibles. Two Analytical Reference Glass ? 1 (ARG-1) standards were digested along with a blank for each preparation. Each aqua regia digestion and blank was diluted to 1:100 mL with deionized water and submitted to Analytical Development (AD) for inductively coupled plasma ? atomic emission spectroscopy (ICP-AES) analysis, inductively coupled plasma ? mass spectrometry (ICP-MS) analysis, atomic absorption spectroscopy (AA) for As and Se, and cold vapor atomic absorption spectroscopy (CV-AA) for Hg. Equivalent dilutions of the alkali fusion digestions and blank were submitted to AD for ICP-AES analysis. Tank 40 SB7b supernate was collected from a mixed slurry sample in the SRNL Shielded Cells and submitted to AD for ICP-AES, ion chromatography (IC), total base/free OH{sup -}/other base, total inorganic carbon/total organic carbon (TIC/TOC) analyses, and Cs-137 gamma scan. Weighted dilutions of slurry were submitted for IC, TIC/TOC, and total base/free OH-/other base analyses. Activities for U-233, U-235, and Pu-239 were determined from the ICP-MS data for the aqua regia digestions of the Tank 40 WAPS slurry using the specific activity of each isotope. The Pu-241 value was determined from a Pu-238/-241 method.

Bannochie, C. J.

2012-11-06T23:59:59.000Z

177

Key results from SB8 simulant flowsheet studies  

SciTech Connect

Key technically reviewed results are presented here in support of the Defense Waste Processing Facility (DWPF) acceptance of Sludge Batch 8 (SB8). This report summarizes results from simulant flowsheet studies of the DWPF Chemical Process Cell (CPC). Results include: Hydrogen generation rate for the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles of the CPC on a 6,000 gallon basis; Volume percent of nitrous oxide, N2O, produced during the SRAT cycle; Ammonium ion concentrations recovered from the SRAT and SME off-gas; and, Dried weight percent solids (insoluble, soluble, and total) measurements and density.

Koopman, D. C.

2013-04-26T23:59:59.000Z

178

Adsorption of Trace Elements on Fresh and Weathered Coal Fly Ash  

Science Conference Proceedings (OSTI)

A variety of trace elements are associated with fly ash produced by coal combustion. These trace elements are potentially of concern for human health if they are released to the environment, and thus it is important to understand their mobility in coal fly ash management settings. In the fly ash management environment, the ash may react with meteoric fluid to release trace elements into groundwater or surface water. However, fly ash particles also have a relatively high surface area and have the ability ...

2012-05-23T23:59:59.000Z

179

Jet Engine Coatings Resist Volcanic Ash Damage - Materials ...  

Science Conference Proceedings (OSTI)

Posted on: 4/27/2011 12:00:00 AM... Concerns about the damage that volcanic ash clouds can inflict on aircraft engines resulted in last year's $2 billion ...

180

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1998-12-29T23:59:59.000Z

182

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1998-01-01T23:59:59.000Z

183

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-04-29T23:59:59.000Z

184

Guideline for Control and Prevention of Fly Ash Erosion  

Science Conference Proceedings (OSTI)

Boiler tube failures (BTFs) represent the largest portion of availability loss in the fossil boiler industry at about 4%. Approximately 25% of all tube failures are due to fly ash erosion (FAE).

2011-11-04T23:59:59.000Z

185

Volcanic Ash Forecast Transport And Dispersion (VAFTAD) Model  

Science Conference Proceedings (OSTI)

The National Oceanic and Atmospheric Administration (NOAA) Air Resources Laboratory (ARL) has developed a Volcanic Ash Forecast Transport And Dispersion (VAFTAD) model for emergency response use focusing on hazards to aircraft flight operations. ...

Jerome L. Heffter; Barbara J. B. Stunder

1993-12-01T23:59:59.000Z

186

Optical properties of fly ash. Volume 2, Final report  

Science Conference Proceedings (OSTI)

Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executive summary of the whole program followed by the dissertation of Ghosal and Ebert. Volume 2 contains the dissertation of Ebert which covers the measurements of the optical constants of slags, and calculations of the radiant properties of fly ash dispersions. A list of publications and conference presentations resulting from the work is also included.

Self, S.A.

1994-12-01T23:59:59.000Z

187

Recoverable immobilization of transuranic elements in sulfate ash  

DOE Patents (OSTI)

Disclosed is a method of reversibly immobilizing sulfate ash at least about 20% of which is sulfates of transuranic elements. The ash is mixed with a metal which can be aluminum, cerium, samarium, europium, or a mixture thereof, in amounts sufficient to form an alloy with the transuranic elements, plus an additional amount to reduce the transuranic element sulfates to elemental form. Also added to the ash is a fluxing agent in an amount sufficient to lower the percentage of the transuranic element sulfates to about 1% to about 10%. The mixture of the ash, metal, and fluxing agent is heated to a temperature sufficient to melt the fluxing agent and the metal. The mixture is then cooled and the alloy is separated from the remainder of the mixture.

Greenhalgh, Wilbur O. (Richland, WA)

1985-01-01T23:59:59.000Z

188

AlGaAsSb buffer/barrier on GaAs substrate for InAs channel devices with high electron mobility and practical reliability  

Science Conference Proceedings (OSTI)

Keywords: AlGaAsSb, Hall elements, InAs, Sb, buffer/barriers, deep quantum well, field effect transistors, reliability

S. Miya; S. Muramatsu; N. Kuze; K. Nagase; T. Iwabuchi; A. Ichii; M. Ozaki; I. Shibasaki

1996-03-01T23:59:59.000Z

189

GaSb/GaP compliant interface for high electron mobility AlSb/InAs heterostructures on (001) GaP  

Science Conference Proceedings (OSTI)

We report on the epitaxial growth of an AlSb/InAs heterostructure on a (001) GaP substrate. We investigate the conditions for the most efficient relaxation of GaSb islands on GaP. In particular, we show that the GaP surface treatment and the growth temperature are crucial for the formation of a two-dimensional periodic array of 90 deg. misfit dislocations at the episubstrate interface. With this relaxation process, an AlSb/InAs heterostructure exhibiting a room temperature mobility of 25 500 cm{sup 2} V{sup -1} s{sup -1} on GaP is demonstrated. This result paves the way to the integration of Sb-based devices on Si substrates through the use of GaP/Si templates.

El Kazzi, S.; Desplanque, L.; Coinon, C.; Wallart, X. [Institut d'Electronique, de Microelectronique, et de Nanotechnologie, UMR-CNRS 8520, BP 60069, 59652 Villeneuve d'Ascq Cedex (France); Wang, Y.; Ruterana, P. [CIMAP UMR 6252 CNRS-ENSICAEN-CEA-UCBN, 6, Boulevard du Marechal Juin, 14050 Caen Cedex (France)

2010-11-08T23:59:59.000Z

190

Structural studies and optical and electrical properties of novel Gd3+-doped Sb2Se3 nanorods  

Science Conference Proceedings (OSTI)

Gd3+-doped Sb2Se3 nanorods were synthesized by coreduction method at 180°C and pH = 12 for 48 h. Powder XRD patterns indicate that the GdxSb2-xSe3 crystals (x ...

Abdolali Alemi; Younes Hanifehpour; Sang Woo Joo; Bong-Ki Min; Tae Hwan Oh

2012-01-01T23:59:59.000Z

191

KINETICS OF FLY ASH BENEFICIATION BY CARBON BURNOUT  

SciTech Connect

Surface area analyses performed on fly ash samples reveal that the surface area is controlled by carbon content. The higher surface areas found in large particles are due to the presence of highly porous carbonaceous particles. Adsorption-desorption isotherms and t-plots of fly ash samples indicate that fly ash is porous. BJH Adsorption/Desorption pore size analysis reveal that pore diameters are independent of sieve size. They appear to be dependent only on the nature of the material which confers porosity. Based on the results of Brown and Dykstra (41) it is reasonable to assume that calculations of reaction rates at temperatures above 550 C were confounded by weight losses from processes other than carbon oxidation and, therefore, are not useful in determination of the temperature dependence of carbon oxidation in fly ash. The results of the present study indicate that temperatures below 550 C should be used for future studies in order to satisfactorily assess the temperature dependence of carbon oxidation in fly ash. Furthermore, it is also advisable that percent carbon determinations be performed on fly ash samples after the oxidation reactions to determine whether all carbon present in fly ash is oxidized. This will ensure that reaction rates are representative of the complete oxidation of carbon. An inverse relationship was determined between reaction rates and oxygen concentration for this study. As discussed, this may be due to volatilization of volatiles from fly ash and ease of transport of products away from the reaction sites by the action of the vacuum applied to the samples. A more accurate determination of oxygen dependence of carbon oxidation can be accomplished by the use of specialty gases containing different concentrations of oxygen which could eliminate the need to apply vacuum to the samples.

Dr. Joseph N.D. Dodoo; Dr. Joseph M. Okoh

2000-11-01T23:59:59.000Z

192

Triboelectric Fly Ash Beneficiation: Summary Report, Phase IV  

Science Conference Proceedings (OSTI)

The Center for Applied Energy Research (CAER) at the University of Kentucky has devised new approaches for extracting marketable fly ash from high carbon combustion ashes. Dry beneficiation technology based on pneumatic transport, triboelectric principles has emerged with the potential for high efficiency removal of carbon at low cost and with no secondary waste products. (EPRI Interim Report TR-109016, November, 1997; EPRI Interim Report TR-111647, November 1998; EPRI Report TE-113673, September 1999; E...

2000-11-27T23:59:59.000Z

193

Observation of Band Alignment Transition in InAs/GaAsSb Quantum Dots by Photoluminescence  

Science Conference Proceedings (OSTI)

The band alignment of InAs quantum dots (QDs) embedded in GaAsSb barriers with various Sb compositions is investigated by photoluminescence (PL) measurements. InAs/GaAsSb samples with 13% and 15% Sb compositions show distinct differences in emission spectra as the PL excitation power increases. Whilst no discernible shift is seen for the 13% sample, a blue-shift of PL spectra following a 1/3 exponent of the excitation power is observed for the 15% sample suggesting a transition from a type I to type II band alignment. Time-resolved PL data show a significant increase in carrier lifetime as the Sb composition increases between 13% and 15% implying that the transformation from a type I to type II band alignment occurs between 13% and 15% Sb compositions. These results taken together lead to the conclusion that a zero valence band offset (VBO) can be achieved for the InAs/GaAsSb system in the vicinity of 14% Sb composition.

Ban, K. Y.; Kuciauskas, D.; Bremner, S. P.; Honsberg, C. B.

2012-05-15T23:59:59.000Z

194

SB 4 Interim Well Stimulation Treatment Regulations Notice of Proposed Emergency Rulemaking Action  

E-Print Network (OSTI)

SB 4 Interim Well Stimulation Treatment Regulations Notice of Proposed Emergency Rulemaking Action Page 1 of 10 SB 4 INTERIM WELL STIMULATION TREATMENT REGULATIONS NOTICE OF PROPOSED EMERGENCY that the California Department of Conservation (Department) proposes to adopt emergency regulations necessary

195

GaInAsSb materials for thermophotovoltaics  

DOE Green Energy (OSTI)

Ga{sub 1{minus}x}In{sub x}As{sub 1{minus}y}Sb{sub y} (0.06 < x < 0.2, 0.05 < y < 0.18) epilayers were grown lattice-matched to GaSb substrates by organometallic vapor phase epitaxy (OMVPE) and molecular beam epitaxy (MBE). For lattice-matched alloys, mirror-like surface morphologies were obtained by both OMVPE and MBE. The 4K photoluminescence (PL) of all layers had a full-width at half-maximum (FWHM) of less than 10 meV for PL peak emission < 1.9 {micro}m. PL FWHM increased to 30 meV for peak emission {approximately}2.12 {micro}m for OMVPE-grown layers. Nominally undoped layers are p-type with typical 300 K hole concentration of {approximately}9 {times} 10{sup 15} cm{sup {minus}3} and hole mobility {approximately}450 to 580 cm{sup 2}/V-s for OMVPE-grown layers, p- and n-type doping is reported for layers grown with either technique. The ideality factor of diode structures is {approximately}2 for both techniques.

Wang, C.A.; Turner, G.W.; Manfra, M.J.; Choi, H.K.; Spears, D.L. [Massachusetts Inst. of Tech., Lexington, MA (United States). Lincoln Lab.

1996-12-01T23:59:59.000Z

196

Ash level meter for a fixed-bed coal gasifier  

DOE Patents (OSTI)

An ash level meter for a fixed-bed coal gasifier is provided which utilizes the known ash level temperature profile to monitor the ash bed level. A bed stirrer which travels up and down through the extent of the bed ash level is modified by installing thermocouples to measure the bed temperature as the stirrer travels through the stirring cycle. The temperature measurement signals are transmitted to an electronic signal process system by an FM/FM telemetry system. The processing system uses the temperature signals together with an analog stirrer position signal, taken from a position transducer disposed to measure the stirrer position to compute the vertical location of the ash zone upper boundary. The circuit determines the fraction of each total stirrer cycle time the stirrer-derived bed temperature is below a selected set point, multiplies this fraction by the average stirrer signal level, multiplies this result by an appropriate constant and adds another constant such that a 1 to 5 volt signal from the processor corresponds to a 0 to 30 inch span of the ash upper boundary level. Three individual counters in the processor store clock counts that are representative of: (1) the time the stirrer temperature is below the set point (500.degree. F.), (2) the time duration of the corresponding stirrer travel cycle, and (3) the corresponding average stirrer vertical position. The inputs to all three counters are disconnected during any period that the stirrer is stopped, eliminating corruption of the measurement by stirrer stoppage.

Fasching, George E. (Morgantown, WV)

1984-01-01T23:59:59.000Z

197

Event:Sustainable Biomass for Electricity Conference (SB4E) | Open Energy  

Open Energy Info (EERE)

Biomass for Electricity Conference (SB4E) Biomass for Electricity Conference (SB4E) Jump to: navigation, search Calendar.png Sustainable Biomass for Electricity Conference (SB4E): on 2012/05/02 The Conference on Sustainable Biomass for Electricity (SB4E), organized by UN-Energy in cooperation with the Global Bioenergy Partnership (GBEP) and other partners, will consider the role of biomass technologies in decarbonizing the global energy system. Acknowledging the readily available and cost effective potential for emission reductions that could be achieved through the large-scale deployment of sustainable biomass for electricity production, the SB4E Conference will provide an opportunity for governments, international organizations and the private sector to share knowledge, lessons, best practices and experiences and to join efforts

198

The quantum efficiency of InGaAsSb thermophotovoltaic diodes  

DOE Green Energy (OSTI)

Uncoated InGaAsSb/GaSb thermophotovoltaic (TPV) diodes with 0.56 eV (2.2 {micro}m) bandgaps exhibit external quantum efficiencies of 59% at 2 {micro}m, which corresponds to an internal quantum efficiency of 95%. The structures were grown by molecular-beam epitaxy. The devices have electron diffusion lengths as long as 29 {micro}m in 8-{micro}m-wide p-InGaAsSb layers and hole diffusion lengths of 3 {micro}m in 6-{micro}m-wide n-InGaAsSb layers. The electron and hole diffusion lengths appear to increase with increasing p- and n-layer widths, respectively. These excellent minority carrier transport properties of InGaAsSb are well-suited to efficient TPV diode operation.

Martinelli, R.U.; Garbuzov, D.Z.; Lee, H.; Morris, N.; Odubanjo, T.; Taylor, G.C.; Connolly, J.C. [Sarnoff Corp., Princeton, NJ (United States)

1997-10-01T23:59:59.000Z

199

Formation and prevention of agglomerated deposits during the gasification of high-sodium lignite  

Science Conference Proceedings (OSTI)

A high-sodium lignite from the Freedom mine in North Dakota was tested in the transport gasifier at the Power Systems Development Facility (PSDF). During the first use of the high-sodium lignite in October 2003, agglomerated deposits formed at various locations in the transport gasifier system. An extensive laboratory testing program was carried out to characterize the deposits, understand the mechanism of the deposit formation, and test various methods of preventing or minimizing the agglomeration. The results of the deposit analysis and initial lab studies suggested that sodium released from the lignite was deposited on the surface of the sand bed material, resulting in the formation of sticky sodium silicates. Additional laboratory tests indicated that the agglomeration could be avoided or minimized by replacing the sand with a nonreactive bed material (e.g., coarse coal ash), operating at slightly reduced temperatures and using certain types of additives. By using these procedures, we completely eliminated the deposition problems in a subsequent gasification run in August 2004. 10 refs., 10 figs.

Robert S. Dahlin; WanWang Peng; Matt Nelson; Pannalal Vimalchand; Guohai Liu [Southern Research Institute and Southern Company Services, Wilsonville, AL (United States). Power Systems Development Facility

2006-12-15T23:59:59.000Z

200

Vacuum pyrolysis of sodium stearate  

DOE Green Energy (OSTI)

Vacuum pyrolysis of sodium stearate was studied to provide useful information for Green River oil shale pyrolysis. Sodium stearate is a typical compound of carboxylic acid salts amounting to 3.6% of total organic materials in the oil shale by methanol extraction. Sodium stearate contained in a stainless steel miniature reactor was heated at 450/sup 0/C in a fluidized sand bath. Pyrolysis times ranged from 15 to 120 minutes. The amounts of gas and liquid products were measured and composition determined by gas chromatography. Ethane, methane, propylene plus propane, hydrogen, carbon dioxide, and carbon monoxide are the major gaseous products, in order of decreasing concentration. The predominant liquid product is a C/sub 17/ alkene with C/sub 12/-C/sub 21/ alkene/alkane pairs present. The first order decomposition rate constant for sodium stearate at 450/sup 0/C was calculated to be 6.4 x 10/sup -3/ min./sup -1/. 18 refs., 7 figs.

Chong, S.L.

1985-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Seal for sodium sulfur battery  

SciTech Connect

This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

Topouzian, Armenag (Birmingham, MI); Minck, Robert W. (Lathrup Village, MI); Williams, William J. (Northville, MI)

1980-01-01T23:59:59.000Z

202

Volume efficient sodium sulfur battery  

SciTech Connect

In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

Mikkor, Mati (Ann Arbor, MI)

1980-01-01T23:59:59.000Z

203

Leaching of Mixtures of Biochar and Fly Ash  

SciTech Connect

Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments.2, 5, 6 Both the residual char from biomass pyrolysis7-9, 12 (biochar) and fly ash from coal combustion1, 13, 14 have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations.10, 11, 16 Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and reduces available aluminum.3, 17 Combinations of these benefits likely lead to the observed increased yields for crops including corn and sugarcane.17 with biochar addition to soil. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) 8, 17 than do unammended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way.18 Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes.15 Here, we are examining the properties of mixtures of biochar, fly ash, and soil and evaluating leaching of organic carbon and metals from the mixtures.

Palumbo, Anthony Vito [ORNL; Porat, Iris [ORNL; Phillips, Jana Randolph [ORNL; Amonette, J. E. [Pacific Northwest National Laboratory (PNNL); Drake, Meghan M [ORNL; Brown, Steven D [ORNL; Schadt, Christopher Warren [ORNL

2009-01-01T23:59:59.000Z

204

Energy Basics: Low-Pressure Sodium Lighting  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Pressure Sodium Lighting Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color...

205

Fine ash formation during pulverized coal combustion  

Science Conference Proceedings (OSTI)

In this study, 15 pulverized coal samples were burnt in a drop-tube furnace to investigate the formation of fine particulates and the influence of coal ash properties on their emission. Coal combustion was carried out at 1673 K in air. Fine particles were collected by a cyclone and a low-pressure impactor. The elemental compositions of the collected particles were analyzed by scanning electron microscopy with energy-dispersive X-ray spectroscopy. We examined the chemical compositions of the fine particles as a function of particle diameter and examined the proportions of the elements in the parent coal samples. We determined that almost all particles less than 0.22 {mu}m in diameter were formed by means of volatilization-condensation of SiO{sub 2} and Al{sub 2}O{sub 3} in the coal. We also demonstrated that the amount of SiO{sub 2} in particle size less than 0.22 {mu}m in diameter was related to the amount of fine included quartz and clay minerals in the parent coal. The primary components of particles greater than 0.76 {mu}m in diameter were SiO{sub 2} and Al{sub 2}O{sub 3}, and as the diameter of the particles decrease, the mass fractions of iron, magnesium, calcium, and phosphorus increased. However, the particle diameter at which this tendency commenced differed depending on the element. Particles between 0.22 and 0.76 {mu}m in diameter were thought to have been formed by the fragmentation and coalescence of particles in the coal and by the simultaneous condensation of volatilized elements onto other particles. 17 refs., 12 figs., 1 tab.

Tsuyoshi Teramae; Takayuki Takarada [Idemitsu Kosan Company, Limited, Chiba (Japan). Coal and Environmental Research Laboratory

2009-04-15T23:59:59.000Z

206

Protective tubes for sodium heated water tubes  

DOE Patents (OSTI)

A heat exchanger in which water tubes are heated by liquid sodium which minimizes the results of accidental contact between the water and the sodium caused by failure of one or more of the water tubes. A cylindrical protective tube envelopes each water tube and the sodium flows axially in the annular spaces between the protective tubes and the water tubes.

Essebaggers, Jan (39 Honeyman Dr., Succasunna, NJ 07876)

1979-01-01T23:59:59.000Z

207

DWPF SIMULANT CPC STUDIES FOR SB7B  

Science Conference Proceedings (OSTI)

Lab-scale DWPF simulations of Sludge Batch 7b (SB7b) processing were performed. Testing was performed at the Savannah River National Laboratory - Aiken County Technology Laboratory (SRNL-ACTL). The primary goal of the simulations was to define a likely operating window for acid stoichiometry for the DWPF Sludge Receipt and Adjustment Tank (SRAT). In addition, the testing established conditions for the SRNL Shielded Cells qualification simulation of SB7b-Tank 40 blend, supported validation of the current glass redox model, and validated the coupled process flowsheet at the nominal acid stoichiometry. An acid window of 105-140% by the Koopman minimum acid (KMA) equation (107-142% DWPF Hsu equation) worked for the sludge-only flowsheet. Nitrite was present in the SRAT product for the 105% KMA run at 366 mg/kg, while SME cycle hydrogen reached 94% of the DWPF Slurry Mix Evaporator (SME) cycle limit in the 140% KMA run. The window was determined for sludge with added caustic (0.28M additional base, or roughly 12,000 gallons 50% NaOH to 820,000 gallons waste slurry). A suitable processing window appears to be 107-130% DWPF acid equation for sludge-only processing allowing some conservatism for the mapping of lab-scale simulant data to full-scale real waste processing including potentially non-conservative noble metal and mercury concentrations. This window should be usable with or without the addition of up to 7,000 gallons of caustic to the batch. The window could potentially be wider if caustic is not added to SB7b. It is recommended that DWPF begin processing SB7b at 115% stoichiometry using the current DWPF equation. The factor could be increased if necessary, but changes should be made with caution and in small increments. DWPF should not concentrate past 48 wt.% total solids in the SME cycle if moderate hydrogen generation is occurring simultaneously. The coupled flowsheet simulation made more hydrogen in the SRAT and SME cycles than the sludge-only run with the same acid stoichiometric factor. The slow acid addition in MCU seemed to alter the reactions that consumed the small excess acid present such that hydrogen generation was promoted relative to sludge-only processing. The coupled test reached higher wt.% total solids, and this likely contributed to the SME cycle hydrogen limit being exceeded at 110% KMA. It is clear from the trends in the SME processing GC data, however, that the frit slurry formic acid contributed to driving the hydrogen generation rate above the SME cycle limit. Hydrogen generation rates after the second frit addition generally exceeded those after the first frit addition. SRAT formate loss increased with increasing acid stoichiometry (15% to 35%). A substantial nitrate gain which was observed to have occurred after acid addition (and nitrite destruction) was reversed to a net nitrate loss in runs with higher acid stoichiometry (nitrate in SRAT product less than sum of sludge nitrate and added nitric acid). Increased ammonium ion formation was also indicated in the runs with nitrate loss. Oxalate loss on the order 20% was indicated in three of the four acid stoichiometry runs and in the coupled flowsheet run. The minimum acid stoichiometry run had no indicated loss. The losses were of the same order as the official analytical uncertainty of the oxalate concentration measurement, but were not randomly distributed about zero loss, so some actual loss was likely occurring. Based on the entire set of SB7b test data, it is recommended that DWPF avoid concentrating additional sludge solids in single SRAT batches to limit the concentrations of noble metals to SB7a processing levels (on a grams noble metal per SRAT batch basis). It is also recommended that DWPF drop the formic acid addition that accompanies the process frit 418 additions, since SME cycle data showed considerable catalytic activity for hydrogen generation from this additional acid (about 5% increase in stoichiometry occurred from the frit formic acid). Frit 418 also does not appear to need formic acid addition to prevent gel formation in

Koopman, D.

2011-11-01T23:59:59.000Z

208

DWPF SIMULANT CPC STUDIES FOR SB7B  

DOE Green Energy (OSTI)

Lab-scale DWPF simulations of Sludge Batch 7b (SB7b) processing were performed. Testing was performed at the Savannah River National Laboratory - Aiken County Technology Laboratory (SRNL-ACTL). The primary goal of the simulations was to define a likely operating window for acid stoichiometry for the DWPF Sludge Receipt and Adjustment Tank (SRAT). In addition, the testing established conditions for the SRNL Shielded Cells qualification simulation of SB7b-Tank 40 blend, supported validation of the current glass redox model, and validated the coupled process flowsheet at the nominal acid stoichiometry. An acid window of 105-140% by the Koopman minimum acid (KMA) equation (107-142% DWPF Hsu equation) worked for the sludge-only flowsheet. Nitrite was present in the SRAT product for the 105% KMA run at 366 mg/kg, while SME cycle hydrogen reached 94% of the DWPF Slurry Mix Evaporator (SME) cycle limit in the 140% KMA run. The window was determined for sludge with added caustic (0.28M additional base, or roughly 12,000 gallons 50% NaOH to 820,000 gallons waste slurry). A suitable processing window appears to be 107-130% DWPF acid equation for sludge-only processing allowing some conservatism for the mapping of lab-scale simulant data to full-scale real waste processing including potentially non-conservative noble metal and mercury concentrations. This window should be usable with or without the addition of up to 7,000 gallons of caustic to the batch. The window could potentially be wider if caustic is not added to SB7b. It is recommended that DWPF begin processing SB7b at 115% stoichiometry using the current DWPF equation. The factor could be increased if necessary, but changes should be made with caution and in small increments. DWPF should not concentrate past 48 wt.% total solids in the SME cycle if moderate hydrogen generation is occurring simultaneously. The coupled flowsheet simulation made more hydrogen in the SRAT and SME cycles than the sludge-only run with the same acid stoichiometric factor. The slow acid addition in MCU seemed to alter the reactions that consumed the small excess acid present such that hydrogen generation was promoted relative to sludge-only processing. The coupled test reached higher wt.% total solids, and this likely contributed to the SME cycle hydrogen limit being exceeded at 110% KMA. It is clear from the trends in the SME processing GC data, however, that the frit slurry formic acid contributed to driving the hydrogen generation rate above the SME cycle limit. Hydrogen generation rates after the second frit addition generally exceeded those after the first frit addition. SRAT formate loss increased with increasing acid stoichiometry (15% to 35%). A substantial nitrate gain which was observed to have occurred after acid addition (and nitrite destruction) was reversed to a net nitrate loss in runs with higher acid stoichiometry (nitrate in SRAT product less than sum of sludge nitrate and added nitric acid). Increased ammonium ion formation was also indicated in the runs with nitrate loss. Oxalate loss on the order 20% was indicated in three of the four acid stoichiometry runs and in the coupled flowsheet run. The minimum acid stoichiometry run had no indicated loss. The losses were of the same order as the official analytical uncertainty of the oxalate concentration measurement, but were not randomly distributed about zero loss, so some actual loss was likely occurring. Based on the entire set of SB7b test data, it is recommended that DWPF avoid concentrating additional sludge solids in single SRAT batches to limit the concentrations of noble metals to SB7a processing levels (on a grams noble metal per SRAT batch basis). It is also recommended that DWPF drop the formic acid addition that accompanies the process frit 418 additions, since SME cycle data showed considerable catalytic activity for hydrogen generation from this additional acid (about 5% increase in stoichiometry occurred from the frit formic acid). Frit 418 also does not appear to need formic acid addition to prevent gel formation in

Koopman, D.

2011-11-01T23:59:59.000Z

209

2003 Conference on Unburned Carbon on Utility Fly Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

2003 Conference on Unburned Carbon on Utility Fly Ash 2003 Conference on Unburned Carbon on Utility Fly Ash October 28, 2003 Table of Contents Disclaimer Participants List [PDF-31KB] Papers and Presentations Control Measures Predictive Performance Tools (Including Instrumentation) Processing and Utilization of High-LOI Fly Ash Beneficiation of High-LOI Fly Ash Characterization of High-LOI Fly Ash Poster Presentations Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

210

LOW-TEMPERATURE ASH SINTERING AND STRENGTH DEVELOPMENT  

DOE Green Energy (OSTI)

The objective of the project is to develop fundamental sintering-viscosity relationships for coal-type ash at relatively low temperatures, with the end result being a simplified soot-blowing index for power systems. This involves correlating several important factors which control the ease of deposit removal, including deposit strength, deposit porosity, chemical composition, and temperature. Testing was performed on ashes derived from three coals and two biomass materials along with a standard soda-lime glass. The coals were selected because detailed analyses as well as ash samples were already available. Sintering characteristics of the ashes were to be determined by observation using an HSM and video recording system, with a stainless steel microscope stage chamber constructed to allow the use of corrosive gas atmospheres. The measurements would allow calculation of the viscosity of liquid phases as the sintering progressed, using the Frenkel and other sintering models. The sintering behavior and viscosity would be correlated with ash mineralogy and chemistry and information on bench-scale deposit strength and porosity to develop an initial relationship to predict deposit removability.

Christopher J. Zygarlicke; Donald P. McCollor; John P. Kay

1999-10-01T23:59:59.000Z

211

ADVANCED POWER SYSTEMS ASH BEHAVIOR IN POWER SYSTEMS  

SciTech Connect

The overall goal of this initiative is to develop fundamental knowledge of ash behavior in power systems for the purpose of increasing power production efficiency, reducing operation and maintenance costs, and reducing greenhouse gas emissions into the atmosphere. The specific objectives of this initiative focus primarily on ash behavior related to advanced power systems and include the following: ? Determine the current status of the fundamental ash interactions and deposition formation mechanisms as already reported through previous or ongoing projects at the EERC or in the literature. ? Determine sintering mechanisms for temperatures and particle compositions that are less well known and remain for the most part undetermined. ? Identify the relationship between the temperature of critical viscosity (Tcv ) as measured in a viscometer and the crystallization occurring in the melt. ? Perform a literature search on the use of heated-stage microscopy (HSM) for examining in situ ash-sintering phenomena and then validate the use of HSM in the determination of viscosity in spherical ash particles. ? Ascertain the formation and stability of specific mineral or amorphous phases in deposits typical of advanced power systems. ? Evaluate corrosion for alloys being used in supercritical combustion systems.

CHRISTOPHER J. ZYGARLICKE; DONALD P. MCCOLLOR; JOHN P. KAY; MICHAEL L. SWANSON

1998-09-01T23:59:59.000Z

212

ADVANCED POWER SYSTEMS ASH BEHAVIOR IN POWER SYSTEMS  

Science Conference Proceedings (OSTI)

The overall goal of this initiative is to develop fundamental knowledge of ash behavior in power systems for the purpose of increasing power production efficiency, reducing operation and maintenance costs, and reducing greenhouse gas emissions into the atmosphere. The specific objectives of this initiative focus primarily on ash behavior related to advanced power systems and include the following: ? Determine the current status of the fundamental ash interactions and deposition formation mechanisms as already reported through previous or ongoing projects at the EERC or in the literature. ? Determine sintering mechanisms for temperatures and particle compositions that are less well known and remain for the most part undetermined. ? Identify the relationship between the temperature of critical viscosity (Tcv ) as measured in a viscometer and the crystallization occurring in the melt. ? Perform a literature search on the use of heated-stage microscopy (HSM) for examining in situ ash-sintering phenomena and then validate the use of HSM in the determination of viscosity in spherical ash particles. ? Ascertain the formation and stability of specific mineral or amorphous phases in deposits typical of advanced power systems. ? Evaluate corrosion for alloys being used in supercritical combustion systems.

CHRISTOPHER J. ZYGARLICKE; DONALD P. MCCOLLOR; JOHN P. KAY; MICHAEL L. SWANSON

1998-09-01T23:59:59.000Z

213

ENVIRONMENTAL EVALUATION FOR UTILIZATION OF ASH IN SOIL STABILIZATION  

Science Conference Proceedings (OSTI)

The Minnesota Pollution Control Agency (MPCA) approved the use of coal ash in soil stabilization, indicating that environmental data needed to be generated. The overall project goal is to evaluate the potential for release of constituents into the environment from ash used in soil stabilization projects. Supporting objectives are: (1) To ensure sample integrity through implementation of a sample collection, preservation, and storage protocol to avoid analyte concentration or loss. (2) To evaluate the potential of each component (ash, soil, water) of the stabilized soil to contribute to environmental release of analytes of interest. (3) To use laboratory leaching methods to evaluate the potential for release of constituents to the environment. (4) To facilitate collection of and to evaluate samples from a field runoff demonstration effort. The results of this study indicated limited mobility of the coal combustion fly ash constituents in laboratory tests and the field runoff samples. The results presented support previous work showing little to negligible impact on water quality. This and past work indicates that soil stabilization is an environmentally beneficial CCB utilization application as encouraged by the U.S. Environmental Protection Agency. This project addressed the regulatory-driven environmental aspect of fly ash use for soil stabilization, but the demonstrated engineering performance and economic advantages also indicate that the use of CCBs in soil stabilization can and should become an accepted engineering option.

David J. Hassett; Loreal V. Heebink

2001-08-01T23:59:59.000Z

214

Fly ash as a liming material for corn production  

Science Conference Proceedings (OSTI)

Fly ash produced as a by-product of subbituminous coal combustion can potentially serve as an alternative liming material without negatively affecting corn (Zea mays L.) production in areas where use of conventional liming materials can be uneconomical due to transportation costs. A study was conducted to determine if fly ash produced from the Nebraska Public Power District Gerald Gentleman Power Station located in Sutherland, NE could be used as an alternative liming material. Combinations of dry fly ash (DFA), wet fly ash (WFA), beet lime (by-product of sugar beet (Beta vulgaris L.) processing) (BL), and agricultural lime (AGL) were applied at rates ranging from 0.43 to 1.62 times the recommended lime rate to plots on four acidic soils (Anselmo fine sandy loam, Hord fine sandy loam, Holdrege sandy loam, and Valentine fine sand). Soil samples were collected to a depth of 0.2 m from plots and analyzed for pH before lime applications and twice periodically after lime application. The Hord and Valentine soils were analyzed for exchangeable Ca, Mg, K, Na,and Al for determination of percent Al saturation on selected treatments and sampling dates. Corn grain yields were determined annually. It is concluded that the fly ash utilized in this study and applied at rates in this study, increases soil pH comparable to agricultural lime and is an appropriate alternative liming material.

Tarkalson, D.D.; Hergert, G.W.; Stevens, W.B.; McCallister, D.L.; Kackman, S.D. [University of Nebraska, North Platte, NE (US)

2005-05-01T23:59:59.000Z

215

Chloride substitution in sodium borohydride  

Science Conference Proceedings (OSTI)

The dissolution of sodium chloride and sodium borohydride into each other resulting in formation of solid solutions of composition Na(BH{sub 4}){sub 1-x}Cl{sub x} is studied. The dissolution reaction is facilitated by two methods: ball milling or combination of ball milling and annealing at 300 deg. C for three days of NaBH{sub 4}-NaCl samples in molar ratios of 0.5:0.5 and 0.75:0.25. The degree of dissolution is studied by Rietveld refinement of synchrotron radiation powder X-ray diffraction (SR-PXD) data. The results show that dissolution of 10 mol% NaCl into NaBH{sub 4}, forming Na(BH{sub 4}){sub 0.9}Cl{sub 0.1}, takes place during ball milling. A higher degree of dissolution of NaCl in NaBH{sub 4} is obtained by annealing resulting in solid solutions containing up to 57 mol% NaCl, i.e. Na(BH{sub 4}){sub 0.43}Cl{sub 0.57}. In addition, annealing results in dissolution of 10-20 mol% NaBH{sub 4} into NaCl. The mechanism of the dissolution during annealing and the decomposition pathway of the solid solutions are studied by in situ SR-PXD. Furthermore, the stability upon hydrogen release and uptake were studied by Sieverts measurements. - Graphical Abstract: Dissolution of sodium chloride and sodium borohydride into each other resulting in formation of solid solutions of composition Na(BH{sub 4}){sub 1-x}Cl{sub x} is studied. Dissolution is facilitated by two methods: ball milling or annealing at 300 deg. C for three days of NaBH{sub 4}-NaCl samples. Sample compositions and dissolution mechanism are studied by Rietveld refinement of synchrotron radiation powder X-ray diffraction data. Highlights: > Studies of dissolution of sodium chloride and sodium borohydride into each other. > Solid state diffusion facilitated by mechanical and thermal treatments. > Dissolution is more efficiently induced by heating than by mechanical treatment. > Mechanism for dissolution studied by Rietveld refinement of in situ SR-PXD data.

Ravnsbaek, Dorthe B.; Rude, Line H. [Center for Materials Crystallography (CMC), Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Arhus C (Denmark); Jensen, Torben R., E-mail: trj@chem.au.dk [Center for Materials Crystallography (CMC), Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Arhus C (Denmark)

2011-07-15T23:59:59.000Z

216

GaSb/GaAs quantum dot formation and demolition studied with cross-sectional scanning tunneling microscopy  

Science Conference Proceedings (OSTI)

We present a cross-sectional scanning tunneling microscopy study of GaSb/GaAs quantum dots grown by molecular beam epitaxy. Various nanostructures are observed as a function of the growth parameters. During growth, relaxation of the high local strain fields of the nanostructures plays an important role in their formation. Pyramidal dots with a high Sb content are often accompanied by threading dislocations above them. GaSb ring formation is favored by the use of a thin GaAs first cap layer and a high growth temperature of the second cap layer. At these capping conditions, strain-driven Sb diffusion combined with As/Sb exchange and Sb segregation remove the center of a nanostructure, creating a ring. Clusters of GaSb without a well defined morphology also appear regularly, often with a highly inhomogeneous structure which is sometimes divided up in fragments.

Smakman, E. P.; Garleff, J. K.; Rambabu, P.; Koenraad, P. M. [Department of Applied Physics, Eindhoven University of Technology, Eindhoven 5612 AZ (Netherlands); Young, R. J.; Hayne, M. [Department of Physics, Lancaster University, Lancaster LA1 4YB (United Kingdom)

2012-04-02T23:59:59.000Z

217

Relaxation of photoinduced spins and carriers in ferromagnetic InMnSb films  

SciTech Connect

The authors report time resolved measurements and control of photoinduced spin and carrier relaxations in InMnSb ferromagnetic films with 2% Mn content (grown by low-temperature molecular beam epitaxy) using femtosecond laser pulses, and compare them to analogous measurements on InBeSb and InSb films. In this work, magneto-optical Kerr effect and standard pump-probe techniques provided a direct measure of the photoexcited spin and carrier lifetimes, respectively. They observe decrease in relaxations times in the high laser fluence regime and an absence of temperature dependence of the relaxation times.

Nontapot, K.; Kini, R. N.; Gifford, A.; Merritt, T. R.; Khodaparast, G. A.; Wojtowicz, T.; Liu, X.; Furdyna, J. K. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland); Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

2007-04-02T23:59:59.000Z

218

Ash bed level control system for a fixed-bed coal gasifier  

DOE Patents (OSTI)

An ash level control system is provided which incorporates an ash level meter to automatically control the ash bed level of a coal gasifier at a selected level. The ash level signal from the ash level meter is updated during each cycle that a bed stirrer travels up and down through the extent of the ash bed level. The ash level signal is derived from temperature measurements made by thermocouples carried by the stirrer as it passes through the ash bed and into the fire zone immediately above the ash bed. The level signal is compared with selected threshold level signal to determine if the ash level is above or below the selected level once each stirrer cycle. A first counter is either incremented or decremented accordingly. The registered count of the first counter is preset in a down counter once each cycle and the preset count is counted down at a selected clock rate. A grate drive is activated to rotate a grate assembly supporting the ash bed for a period equal to the count down period to maintain the selected ash bed level. In order to avoid grate binding, the controller provides a short base operating duration time each stirrer cycle. If the ash bed level drops below a selected low level or exceeds a selected high level, means are provided to notify the operator.

Fasching, George E. (Morgantown, WV); Rotunda, John R. (Fairmont, WV)

1984-01-01T23:59:59.000Z

219

Fire suppressing apparatus. [sodium fires  

DOE Patents (OSTI)

Apparatus for smothering a liquid sodium fire comprises a pan, a perforated cover on the pan, and tubed depending from the cover and providing communication between the interior of the pan and the ambient atmosphere through the perforations in the cover. Liquid caught in the pan rises above the lower ends of the tubes and thus serves as a barrier which limits the amount of air entering the pan.

Buttrey, K.E.

1980-12-19T23:59:59.000Z

220

Cementitious binder from fly ash and other industrial wastes  

SciTech Connect

In this paper, investigations were undertaken to formulate cementitious binder by judicious blending of fly ash with Portland cement as well as by admixing fly ash with calcined phosphogypsum, fluorogypsum, lime sludge, and chemical activators of different finenesses. The effect of addition of calcined clay in these types of binders was studied. Data showed that cementitious binders of high compressive strength and water retentivity can be produced. The strength of masonry mortars increased with the addition of chemical activators. The strength development of binders takes place through formation of ettringite. C-S-H, and C{sub 4}AH{sub 13}. The binders are eminently suitable for partial replacement (up to 25%) of the cement in concrete without any detrimental affect on the strength. The results showed that fly ash can be used in the range from 45% to 70% in formulating these binders along with other industrial wastes to help in mitigating environmental pollution.

Singh, M.; Garg, M. [Central Building Research Inst., Roorkee (India)] [Central Building Research Inst., Roorkee (India)

1999-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Activation Of Fly Ash-Lime Reactions By Curing At Elevated Temperature And By Addition Of Phosphogypsum.  

E-Print Network (OSTI)

??Pozzolanic reactions play a key role in improving the compressive strengths of compacted fly ash-lime specimens. Based on studies performed with cement amended fly ash… (more)

Asha, K

2011-01-01T23:59:59.000Z

222

Testing the ecological stability of ectomycorrhizal symbiosis: effects of heat, ash and mycorrhizal colonization on Pinus muricata seedling performance  

E-Print Network (OSTI)

metal pan and heating it in a soil drying oven. During thesoil heating and ash addition, using a drying oven and ash

Peay, Kabir G.; Bruns, Thomas D.; Garbelotto, Matteo

2010-01-01T23:59:59.000Z

223

Ashe County, North Carolina ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Ashe County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Ashe County, North Carolina ASHRAE Standard ASHRAE 169-2006 Climate...

224

Extracting Alumina from Coal Fly Ash Using Acid Sintering-Leaching ...  

Science Conference Proceedings (OSTI)

Presentation Title, Extracting Alumina from Coal Fly Ash Using Acid ... Coal fly- ash from coal-fired power plants is rich in Al2O3 content with potential use as a ...

225

An Advanced System to Monitor the 3D Structure of Diffuse Volcanic Ash Clouds  

Science Conference Proceedings (OSTI)

Major disruptions of the aviation system from recent volcanic eruptions have intensified discussions and increased the international consensus to improve volcanic ash warnings. Central to making progress is to better discern low volcanic ash ...

J.-P. Vernier; T. D. Fairlie; J. J. Murray; A. Tupper; C. Trepte; D. Winker; J. Pelon; A. Garnier; J. Jumelet; M. Pavolonis; A. H. Omar; K. A. Powell

226

Continuous air Agglomeration Method for high Carbon fly ash Beneficiation  

DOE Patents (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carbon-free mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahan L.; Champagne, Kenneth J.; Finseth, Dennis H.

1998-09-29T23:59:59.000Z

227

Ash reduction system using electrically heated particulate matter filter  

DOE Patents (OSTI)

A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

2011-08-16T23:59:59.000Z

228

Continuous air agglomeration method for high carbon fly ash beneficiation  

DOE Patents (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahon L. (Pittsburgh, PA); Champagne, Kenneth J. (Monongahela, PA); Finseth, Dennis H. (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

229

Hydrothermal synthesis of Sb2S3nanorods using iodine via redox mechanism  

Science Conference Proceedings (OSTI)

Crystalline antimony sulfide (Sb2S3) with nanorods morphology was successfully prepared via hydrothermal method by the reaction of elemental sulfur, antimony, and iodine as starting materials with high yield at 180°C for 24 ...

Abdolali Alemi; Sang Woo Joo; Younes Hanifehpour; Aliakbar Khandar; Ali Morsali; Bong-Ki Min

2011-01-01T23:59:59.000Z

230

Glass-like thermal transport in AgSbTe2 | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass-like thermal transport in AgSbTe2: nano-scale insights to improve thermoelectric efficiency May 16, 2013 Inelastic neutron scattering data showing the phonon dispersions...

231

Structure and Magnetic Properties of the RScSb Compounds (R ...  

Science Conference Proceedings (OSTI)

They crystallize in the tetragonal CeScSi-type structure (tI12, I4/ mmm, an ordered variant of the La2Sb-type). The lattice ...

232

Intense terahertz emission from molecular beam epitaxy-grown GaAs/GaSb(001)  

SciTech Connect

Intense terahertz (THz) electromagnetic wave emission was observed in undoped GaAs thin films deposited on (100) n-GaSb substrates via molecular beam epitaxy. GaAs/n-GaSb heterostructures were found to be viable THz sources having signal amplitude 75% that of bulk p-InAs. The GaAs films were grown by interruption method during the growth initiation and using various metamorphic buffer layers. Reciprocal space maps revealed that the GaAs epilayers are tensile relaxed. Defects at the i-GaAs/n-GaSb interface were confirmed by scanning electron microscope images. Band calculations were performed to infer the depletion region and electric field at the i-GaAs/n-GaSb and the air-GaAs interfaces. However, the resulting band calculations were found to be insufficient to explain the THz emission. The enhanced THz emission is currently attributed to a piezoelectric field induced by incoherent strain and defects.

Sadia, Cyril P.; Laganapan, Aleena Maria; Agatha Tumanguil, Mae; Estacio, Elmer; Somintac, Armando; Salvador, Arnel [National Institute of Physics, University of the Philippines Diliman, Quezon City 1101 (Philippines); Que, Christopher T. [Physics Department, De La Salle University, 2401 Taft Avenue, Manila 1004 (Philippines); Yamamoto, Kohji; Tani, Masahiko [Research Center for Development of Far-Infrared Region, University of Fukui, Fukui 910-8507 (Japan)

2012-12-15T23:59:59.000Z

233

Evaluation of an Ecolotree TM CAP for Closure of Coal Ash Disposal Sites  

Science Conference Proceedings (OSTI)

Once they are filled or become inactive, coal ash disposal ponds at power plant sites must meet state and federal regulations for permanent closure. In-place closure of ash ponds typically requires an impermeable cover to protect groundwater from leachate generated by stormwater infiltration through the ash. This report documents the construction, maintenance, and performance of the EcolotreeTM Cap (Tree Cap) -- an ash pond closure alternative consisting of poplar trees, grasses, and surface soil amendme...

1999-06-16T23:59:59.000Z

234

Using Zeolites Synthesized from Fly Ash to Reduce Ammonia Loss to the Environment  

Science Conference Proceedings (OSTI)

This interim report describes studies using zeolites synthesized from fly ash to reduce ammonia loss to the environment.

2002-02-19T23:59:59.000Z

235

Mercury Leachability From Concretes That Contain Fly Ashes and Activated Carbon Sorbents  

Science Conference Proceedings (OSTI)

This report presents new laboratory data on the leaching of mercury from concrete that contains fly ash and powdered activated carbon (PAC) sorbents used to capture mercury. The concretes studied during this project were made with fly ashes from lignite and subbituminous coal, including fly ashes containing PAC. Only very low levels of mercuryless than 5 parts per trillionwere leached from the fly ash concretes in both 18-hour and 7-day laboratory leach tests.

2007-07-18T23:59:59.000Z

236

Cu2Sb thin film electrodes prepared by pulsed laser deposition f or lithium batteries  

DOE Green Energy (OSTI)

Thin films of Cu2Sb, prepared on stainless steel and copper substrates with a pulsed laser deposition technique at room temperature, have been evaluated as electrodes in lithium cells. The electrodes operate by a lithium insertion/copper extrusion reaction mechanism, the reversibility of which is superior when copper substrates are used, particularly when electrochemical cycling is restricted to the voltage range 0.65-1.4 V vs. Li/Li+. The superior performance of Cu2Sb films on copper is attributed to the more active participation of the extruded copper in the functioning of the electrode. The continual and extensive extrusion of copper on cycling the cells leads to the isolation of Li3Sb particles and a consequent formation of Sb. Improved cycling stability of both types of electrodes was obtained when cells were cycled between 0.65 and 1.4 V. A low-capacity lithium-ion cell with Cu2Sb and LiNi0.8Co0.15Al0.05O2 electrodes, laminated from powders, shows excellent cycling stability over the voltage range 3.15 - 2.2 V, the potential difference corresponding to approximately 0.65-1.4 V for the Cu2Sb electrode vs. Li/Li+. Chemical self-discharge of lithiated Cu2Sb electrodes by reaction with the electrolyte was severe when cells were allowed to relax on open circuit after reaching a lower voltage limit of 0.1 V. The solid electrolyte interphase (SEI) layer formed on Cu2Sb electrodes after cells had been cycled between 1.4 and 0.65 V vs. Li/Li+ was characterized by Fourier-transform infrared spectroscopy; the SEI layer contributes to the large irreversible capacity loss on the initial cycle of these cells. The data contribute to a better understanding of the electrochemical behavior of intermetallic electrodes in rechargeable lithium batteries.

Song, Seung-Wan; Reade, Ronald P.; Cairns, Elton J.; Vaughey, Jack T.; Thackeray, Michael M.; Striebel, Kathryn A.

2003-08-01T23:59:59.000Z

237

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

Science Conference Proceedings (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M. Sulloway

2007-09-26T23:59:59.000Z

238

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M Sulloway

2007-10-31T23:59:59.000Z

239

Hydration and strength development of binder based on high-calcium oil shale fly ash  

Science Conference Proceedings (OSTI)

The properties of high-calcium oil shale fly ash and low-calcium coal fly ash, which are produced in Israeli power stations, were investigated. High-calcium oil shale fly ash was found to contain a great amount of CaO{sub free} and SO{sub 3} in the form of lime and anhydrite. Mixtures of high-calcium oil shale fly ash and low-calcium coal fly ash, termed fly ash binder, were shown to cure and have improved strength. The influence of the composition and curing conditions on the compressive strength of fly ash binders was examined. The microstructure and the composition of fly ash binder after curing and long-term exposure in moist air, water and open air conditions were studied. It was determined that ettringite is the main variable in the strength and durability of cured systems. The positive effect of calcium silicate hydrates, CSH, which are formed by interaction of high-calcium oil shale fly ash and low-calcium coal fly ash components, on the carbonation and dehydration resistance of fly ash binder in open air is pronounced. It was concluded that high-calcium oil shale fly ash with high CaO{sub free} and SO{sub 3} content can be used as a binder for building products.

Freidin, C. [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)

1998-06-01T23:59:59.000Z

240

Fly Ash Construction Manual for Road and Site Applications, Volumes 1 and 2  

Science Conference Proceedings (OSTI)

This two-volume construction manual details the use of fly ash in high-volume road construction and site development, covering all project elements from ash procurement to finishing. It addresses the use of fly ash in fills, embankments, backfills, subgrade stabilization, pavement base course, and slurried backfills, as well as its application as a soil amendment.

1988-10-28T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater  

E-Print Network (OSTI)

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater Reyad; available online 29 October 2003 Abstract A by-product fly ash from oil shale processing was converted shale; Ash; Zeolite; Cadmium and lead removal 1. Introduction Oil shale exists in Jordan with large

Shawabkeh, Reyad A.

242

Swirling Melting Characteristics of Fly Ashes from Co-Firing of MSWI in China  

Science Conference Proceedings (OSTI)

Melting treatment is an efficient for heavy metal stabilization in MSW fly ash. The fly ashes from co-firing of municipal solid waste and coal incinerator were melted in the swirling melting furnace system under various temperatures. The melting characteristics ... Keywords: fly ash, co-firing, melting, melting temperature, heavy metals, fixation rate

Wang Xue-tao; Jiao You-zhou; Xu Bin; Jin Bao-sheng

2009-10-01T23:59:59.000Z

243

Ab-Initio Determination of Novel Crystal Structures of the Thermoelectric Material MgAgSb  

Science Conference Proceedings (OSTI)

Materials with the half-Heusler structure possess interesting electrical and magnetic properties, including potential for thermoelectric applications. MgAgSb is compositionally and structurally related to many half-Heusler materials, but has not been extensively studied. This work presents the high-temperature X-ray diffraction analysis of MgAgSb between 27 and 420 C, complemented with thermoelectric property measurements. MgAgSb is found to exist in three different structures in this temperature region, taking the half-Heusler structure at high temperatures, a Cu2Sb-related structure at intermediate temperatures, and a previously unreported tetragonal structure at room temperature. All three structures are related by a distorted Mg-Sb rocksalt-type sublattice, differing primarily in the Ag location among the available tetrahedral sites. Transition temperatures between the three phases correlate well with discontinuities in the Seebeck coefficient and electrical conductivity; the best performance occurs with the novel room temperature phase. For application of MgAgSb as a thermoelectric material, it may be desirable to develop methods to stabilize the room temperature phase at higher temperatures.

Kirkham, Melanie J [ORNL; Moreira Dos Santos, Antonio F [ORNL; Rawn, Claudia J [ORNL; Lara-Curzio, Edgar [ORNL; Sharp, Jeff W. [Marlow Industries, Inc; Thompson, Alan [Marlow Industries, Inc

2012-01-01T23:59:59.000Z

244

www.mdpi.com/journal/ijms Fly Ash-based Geopolymer Lightweight Concrete Using Foaming Agent  

E-Print Network (OSTI)

Abstract: In this paper, we report the results of our investigation on the possibility of producing foam concrete by using a geopolymer system. Class C fly ash was mixed with an alkaline activator solution (a mixture of sodium silicate and NaOH), and foam was added to the geopolymeric mixture to produce lightweight concrete. The NaOH solution was prepared by dilute NaOH pellets with distilled water. The reactives were mixed to produce a homogeneous mixture, which was placed into a 50 mm mold and cured at two different curing temperatures (60 °C and room temperature), for 24 hours. After the curing process, the strengths of the samples were tested on days 1, 7, and 28. The water absorption, porosity, chemical composition, microstructure, XRD and FTIR analyses were studied. The results showed that the sample which was cured at 60 °C (LW2) produced the maximum compressive strength for all tests, (11.03 MPa, 17.59 MPa, and 18.19 MPa) for days 1, 7, and 28, respectively. Also, the water absorption and porosity of LW2 were reduced by 6.78 % and 1.22 % after 28 days, respectively. The SEM showed that the LW2 sample had a denser matrix than LW1. This was because LW2 was heat cured, which caused the

Mohd Mustafa; Al Bakri Abdullah; Kamarudin Hussin; Mohamed Bnhussain; Khairul Nizar Ismail; Zarina Yahya; Rafiza Abdul Razak

2012-01-01T23:59:59.000Z

245

Aluminum - Fly Ash Metal Matrix Composites as Advanced Automobile Material  

Science Conference Proceedings (OSTI)

Metal matrix composites such as silicon carbide-aluminum, alumina-aluminum, and graphite-aluminum represent a class of emerging materials with significant potential for commercial use in the auto and aerospace industries. In industrial foundry trials, a joint industry and Department of Energy project demonstrated a promising new process for producing a low cost aluminum metal matrix composite containing fly ash particles.

2001-08-16T23:59:59.000Z

246

Novel Ash Beneficiation Processes for Managing Unburned Carbon and Ammonia  

Science Conference Proceedings (OSTI)

This report describes new fly ash beneficiation concepts for managing deleterious effects of unburned carbon and ammonia contamination associated with low nitrogen oxides (low-NOx) combustion systems. The report contains technical data, scientific discussion, and a description of ongoing development and scale-up activities.

2002-12-10T23:59:59.000Z

247

Thermal analysis and characterization of Elephant grass ash  

Science Conference Proceedings (OSTI)

Conference Tools for 2014 TMS Annual Meeting & Exhibition ... Here, ashes from incineration of elephant grass are characterized and its incorporation into clay to produce ... Moreover, thermal analysis was performed including gas emission ... Differential characterization of Ikperejere Iron shale and Iron sandstone deposit.

248

Sodium technology, 1972--1973  

SciTech Connect

References to 897 publications on sodium and NaK technology cited in Nuclear Science Abstracts Volume 26 (1972) through Volume 27 (1973 through June) are contained in this bibliography. Keyword indexing is displayed under each citation to provide information on the contents of the document. References are arranged in order by the original NSA abstract number which approximately places them in chronological order. Sequence numbers appear beside each reference, and the personal author index refers to these sequence numbers. The subject index refers to the original abstract numbers. (auth)

1974-02-01T23:59:59.000Z

249

Spectroscopic research on infrared emittance of coal ash deposits  

SciTech Connect

This paper deals with thermal radiation characteristics of ash deposits on a pulverized coal combustion boiler of an electric power plant. Normal emittance spectra in the near to medium infrared (2.5-25 {mu}m) region and total normal emittances were measured on four kinds of ground ash deposits. Measurements were conducted in the 570-1460 K temperature range which is common for boiler furnaces, by both heating and cooling the ash samples, with the aim to study the effect of their thermal history. Dependence of emittance on wavelength, temperature and chemical composition was studied, too. Samples were tested for transparency (opacity) to verify the accuracy of results. It was determined that the thicknesses used for the ash powders are opaque for infrared radiation for thicknesses in the order of a millimeter. Tests have shown that spectral emittance increases with an increase of wavelength with a characteristic pattern common for all samples. Spectral normal emittance increases strongly with temperature at shorter wavelengths and remains high and unchanged at longer ones. Emittance spectra are not very sensitive to chemical composition of ashes especially beyond {lambda} {approx} 5 {mu}m. With an increase of temperature, total emittance of the powdered sample decreases to a minimum value around 1200 K. Further temperature rise induces an increase of total emittance due to sintering in the ash. On cooling, the emittance increases monotonically following the hysteresis. Quantitative directions for evaluating thermal radiation characteristics of ash deposits for the merits of the safety design of boiler furnaces were proposed. That comprises correlating the experimentally obtained emittance spectra with curves of simple analytical form, i.e., a continuous function of minimum emittance vs. wavelength. The proposed method can be extended to other specimens from the same furnace and used to determine correlations for thermal calculation of old and design of new furnaces - with similar geometry and combusting similar coal. The method is potentially applicable to completely different boiler furnaces combusting different coal, and the authors recommend running the tests with new deposit samples. The data will then be applicable to the thermal design of a whole new class of furnaces, having similar geometry and combusting similar coal. This is expected to greatly enhance the accuracy and precision of thermal calculation as well as the efficiency of thermal design of steam boilers. (author)

Saljnikov, Aleksandar; Komatina, Mirko; Gojak, Milan [Department of Thermomechanics, Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11120 Belgrade 35 (RS); Vucicevic, Biljana [Laboratory for Thermal Engineering, Institute of Nuclear Sciences VINCA, P.O. Box 522, Belgrade 11001 (RS); Goricanec, Darko [Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, Maribor 2000 (Slovenia); Stevanovic, Zoran [Faculty of Mining and Geology, University of Belgrade, Dusina 7, 11120 Belgrade 35 (RS)

2009-11-15T23:59:59.000Z

250

A Limnological Approach to the Management of Fly Ash Disposal Ponds  

Science Conference Proceedings (OSTI)

Fly ash disposal ponds are found at half of the U.S. coal burning power plants and receive a mixture of fly ash and water used to sluice the ash from the power plant to the pond. Leaching of metals, notably Cu, As, and Se, from fly ash can be decreased by control of inflow pH, but their release through the discharge to surface waters remains a problem, particularly for Se. Comanagement of low volume wastes of varying chemical composition and volume with fly ash make the management of water quality at the...

2004-12-27T23:59:59.000Z

251

Sb(III) and Sb(V) Sorption onto Al-Rich Phases: Hydrous Al Oxide and the Clay Minerals Kaolinite KGa-1b and Oxidized and Reduced Nontronite NAu-1  

SciTech Connect

We have studied the immobilization of Sb(III) and Sb(V) by Al-rich phases - hydrous Al oxide (HAO), kaolinite (KGa-1b), and oxidized and reduced nontronite (NAu-1) - using batch experiments to determine the uptake capacity and the kinetics of adsorption and Extended X-ray Absorption Fine Structure (EXAFS) Spectroscopy to characterize the molecular environment of adsorbed Sb. Both Sb(III) and Sb(V) are adsorbed in an inner-sphere mode on the surfaces of the studied substrates. The observed adsorption geometry is mostly bidentate corner-sharing, with some monodentate complexes. The kinetics of adsorption is relatively slow (on the order of days), and equilibrium adsorption isotherms are best fit using the Freundlich model. The oxidation state of the structural Fe within nontronite affects the adsorption capacity: if the clay is reduced, the adsorption capacity of Sb(III) is slightly decreased, while Sb(V) uptake is increased significantly. This may be a result of the presence of dissolved Fe(II) in the reduced nontronite suspensions or associated with the structural rearrangements in nontronite due to reduction. These research findings indicate that Sb can be effectively immobilized by Al-rich phases. The increase in Sb(V) uptake in response to reducing structural Fe in clay can be important in natural settings since Fe-rich clays commonly go through oxidation-reduction cycles in response to changing redox conditions.

Ilgen, Anastasia G.; Trainor, Thomas P. (Alaska Fairbanks)

2012-11-13T23:59:59.000Z

252

Batteries with Orthorhombic Sodium Manganese Oxide Cathodes  

Berkeley National Laboratory researchers have discovered a low-cost, low-toxicity manganese oxide for rechargeable lithium and sodium batteries.

253

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-10-28T23:59:59.000Z

254

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1997-01-01T23:59:59.000Z

255

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents (OSTI)

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas fired furnances or boilers. Two concentric shells define a combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, A.H.

1982-04-30T23:59:59.000Z

256

Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes  

SciTech Connect

An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane, such as membranes based on NASICON-type materials, in an electrolytic cell. In the process, water is reduced at a cathode to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution are oxidized in the anolyte compartment to produce chlorine gas which reacts with water to produce hypochlorous and hydrochloric acid. Sodium ions are transported from the anolyte compartment to the catholyte compartment across the sodium ion conductive ceramic membrane. Sodium hydroxide is transported from the catholyte compartment to the anolyte compartment to produce sodium hypochlorite within the anolyte compartment.

Balagopal, Shekar; Malhotra, Vinod; Pendleton, Justin; Reid, Kathy Jo

2012-09-18T23:59:59.000Z

257

Evaluation of Concrete Containing Fly Ash With High Carbon Content and/or Small Amounts of Wood  

Science Conference Proceedings (OSTI)

This report provides a comprehensive database of information on the impacts of the use of high carbon coal ashes and concretes with small amounts of wood ash on the performance of concretes. It is expected these data will support easing the restrictions on the use of high carbon ashes and any wood ash products in concrete in the ASTM standards.

1998-06-25T23:59:59.000Z

258

The Physical and Chemical Properties of Fly Ash from Coal Gasification and Study on Its Recycling Utilization  

Science Conference Proceedings (OSTI)

Aiming at the difficulties in utilization of fly ash from coal gasification, the physical and chemical properties of fly ash were investigated. This research studied recycling utilization on using fly ash as one of cement raw materials for cement clinker. ... Keywords: fly ash, X-ray diffraction (XRD), Scanning Electron Microscope (SEM), recycling utilization

Guohua Qiu; Weiqiang Zeng; Zhenglun Shi; Mengxiang Fang; Zhongyang Luo

2010-12-01T23:59:59.000Z

259

To be published in Waste Management (2010) Bodnan et al. MINERALOGY AND PORE WATER CHEMISTRY OF A BOILER ASH  

E-Print Network (OSTI)

OF A BOILER ASH FROM A MSW FLUIDIZED-BED INCINERATOR F. Bodénan* , D. Guyonnet, P. Piantone, P. Blanc BRGM presents an investigation of the mineralogy and pore water chemistry of a boiler ash sampled from to as "boiler ash", is analogous to what Abbas et al. (2003) refer to as "hopper ash" (see Fig. 1 of Abbas et al

Paris-Sud XI, Université de

260

Magnetic order near 270 K in mineral and synthetic Mn 2 FeSbO 6 ilmenite  

Science Conference Proceedings (OSTI)

The structural and magnetic properties of Mn 2 FeSbO 6 single-crystalline mineral and ceramic samples synthesized under thermobaric treatment have been investigated

R. Mathieu; S. A. Ivanov; G. V. Bazuev; M. Hudl; P. Lazor; I. V. Solovyev; P. Nordblad

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Structure and Magnetic Properties of Cu3Ni2SbO6 and Cu3Co2SbO6 Delafossites with Honeycomb Lattices  

Science Conference Proceedings (OSTI)

The crystal structures of two Delafossites, Cu3Ni2SbO6 and Cu3Co2SbO6, are determined by high resolution synchrotron powder X-ray diffraction. The Ni and Co are ordered with respect to Sb in the layer of edge sharing octahedra, forming magnetic layers with honeycomb geometry. High-resolution electron microscopy confirms ordering, and selected-area electron diffraction patterns identify examples of the stacking polytypes. Low temperature synthetic treatments result in disordered stacking of the layers, but heating just below their melting points results in nearly fully ordered stacking variants. The major variant in both cases is a monoclinic distortion of a 6-layer Delafossite polytype, but a significant amount of a 2-layer polytype is also present for the Ni case. The antiferromagnetic ordering with transitions, at 22.3 and 18.5 K for Ni and Co variants, respectively, is investigated by temperature and field dependent magnetization, as well as specific heat. The sharp magnetic transitions support the presence of well developed 2:1 ordering of the Co:Sb or Ni:Sb ions in the honeycomb layers. Neutron diffraction measurements at 4 K are used to determine the magnetic structures. For both the Ni and Co phases, the propagation vector is k = [100], and can be described as alternating ferromagnetic chains in the metal-oxide plane giving an overall antiferromagntic zigzag alignment. While orientation of the magnetic moments of the Co is along the b-axis, the Ni moments are in the ac plane, approximately parallel to the stacking direction. Bulk magnetization properties are discussed in terms of their magnetic structures.

Roudebush, J. H. [Princeton University; Andersen, N. [Technical University of Denmark; Ramlau, R. [Max Planck Institute for the Chemical Physics of Solids; Garlea, Vasile O [ORNL; Toft-Petersen, R. [Helmholtz-Zentrum Berlin; Norby, P. [Technical University of Denmark; Schneider, R. [Laboratory for Electron Microscopy, Karlsruhe Institute of Technology; Hay, J. N. [Princeton University; Cava, R J [Princeton University

2013-01-01T23:59:59.000Z

262

Leaching of mixtures of biochar and fly ash  

Science Conference Proceedings (OSTI)

Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments. Both the residual char from biomass pyrolysis (biochar) and fly ash from coal combustion have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations. Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and decreases available aluminum. A combination of these benefits likely is responsible for observed increases in yields for crops such as corn and sugarcane. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) than do unamended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way. Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil. Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes. In the present study, we examined the properties of mixtures of biochar, fly ash, and soil and evaluated the leaching of organic carbon and metals from these mixtures. The carbon sorption experiments showed release of carbon from biochar, rather than sorption, except at the highest concentrations in the Biochar HW sample. Similar results were obtained by others for oxidative leaching of bituminous coal, in which more C was released as dissolved C than was oxidized to CO2 by the oxygen in water. We confirmed that both fly ash and two types of biochar (oak char [OKEB], and hardwood [HW] char) exhibited minimal leaching of heavy metals including Cr, Ni, Zn, Ga, and Ag, and no detectable leaching of Pb or Cd (data not shown) under the conditions tested. The Biochar HW had a slightly higher C/N ratio (334) and pH (7.7) than did the Biochar OKEB (284 and 6.5). There was no toxicity exhibited by the fly ash (not shown) or biochar leachates as measured by the Microtox© assay under the conditions tested. In previous results no toxicity was reported in testing the fly ash samples except for one high-pH sample. The most notable leachate component from both types of biochar, but not the fly ash, was organic carbon with the HW biochar leaching less organic carbon than the OKEB biochar (5.71 ppm vs. 59.3 ppm). Alone (in batch sorption experiments), or in mixtures of 90% soil and 10% biochar (column studies), we noted significant loss of carbon from the biochar into soluble components. However, when we added fly ash to the column experiments (80% soil, 10% fly ash, and 10% biochar) we observed significant decreases in the amounts of C leached (20% for HW, and 47% for OKEB). The results indicate that applying a combination of fly ash and biochar may result in maximizing the amount of carbon sequestration in soil while also increasing beneficial soil properties and fertility. The lower amount of carbon leached from the HW biochar compared to the OKEB biochar is likely due to the more recalcitrant form of the carbon in the HW char, due to its preparation at a higher temperature (600 şC) than the OKEB biochar (450 şC). High heat treatment temperatures during biochar preparation increase both the total carbon content of the biochar and the proportion of the carbon that is present in fused aromatic rings resistant to chemical and physical degradation.

Palumbo, Anthony V.; Porat, Iris; Phillips, Jana R.; Amonette, James E.; Drake, Meghan M.; Brown, Steven D.; Schadt, Christopher W.

2009-06-22T23:59:59.000Z

263

JV Task 6 - Coal Ash Resources Research Consortium Research  

DOE Green Energy (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of coal combustion by-products (CCBs). CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCB utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program (JSRP), which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCB performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 1998 to 2007 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCBs. CARRC topical reports were prepared on several completed tasks. Specific CARRC 1998B2007 accomplishments included: (1) Development of several ASTM International Standard Guides for CCB utilization applications. (2) Organization and presentation of training courses for CCB professionals and teachers. (3) Development of online resources including the Coal Ash Resource Center, Ash from Biomass in Coal (ABC) of cocombustion ash characteristics, and the Buyer's Guide to Coal-Ash Containing Products. In addition, development of expanded information on the environmental performance of CCBs in utilization settings included the following: (1) Development of information on physical properties and engineering performance for concrete, soil-ash blends, and other products. (2) Training of students through participation in CARRC research projects. (3) Participation in a variety of local, national, and international technical meetings, symposia, and conferences by presenting and publishing CCB-related papers.

Debra Pflughoeft-Hassett; Tera Buckley; Bruce Dockter; Kurt Eylands; David Hassett; Loreal Heebink; Erick Zacher

2008-04-01T23:59:59.000Z

264

Element-specific study of the temperature dependent magnetization of Co-Mn-Sb thin films  

SciTech Connect

Magnetron sputtered thin Co-Mn-Sb films were investigated with respect to their element-specific magnetic properties. Stoichiometric Co{sub 1}Mn{sub 1}Sb{sub 1} crystallized in the C1{sub b} structure has been predicted to be half-metallic and is therefore of interest for spintronics applications. It should show a characteristic antiferromagnetic coupling of the Mn and Co magnetic moments and a transition temperature T{sub C} of about 480K. Although the observed transition temperature of our 20nm thick Co{sub 32.4}Mn{sub 33.7}Sb{sub 33.8}, Co{sub 37.7}Mn{sub 34.1}Sb{sub 28.2} and Co{sub 43.2}Mn{sub 32.6}Sb{sub 24.2} films is in quite good agreement with the expected value, we found a ferromagnetic coupling of the Mn and Co magnetic moments which indicates that the films do not crystallize in the C1{sub b} structure and are probably not fully spin-polarized. The ratio of the Co and Mn moments does not change up to the transition temperature and the temperature dependence of the magnetic moments can be well described by the mean field theory.

Schmalhorst, J.; Ebke, D.; Meinert, M.; Thomas, A.; Reiss, G.; Arenholz, E.

2008-09-30T23:59:59.000Z

265

Performance Study of K2CsSb Photocathode Inside a DC High Voltage Gun  

SciTech Connect

In the past decade, there has been considerable interest in the generation of tens of mA average current in a photoinjector. Until recently, GaAs:Cs cathodes and K{sub 2}CsSb cathodes have been tested successfully in DC and RF injectors respectively for this application. Our goal is to test the K{sub 2}CsSb photocathode inside a DC gun. Since the multialkali cathode is a compound with constant characteristics over its entire thickness, we anticipate that the lifetime issues seen in GaAs:Cs due to surface damage by ion bombardment would be minimized. Hence successful operation of the K{sub 2}CsSb cathode in a DC gun could lead to a relatively robust electron source capable of delivering ampere level currents. In order to test the performance of a K{sub 2}CsSb cathode in a DC gun, we have designed and built a load lock system that allows the fabrication of the cathode at Brookhaven National Lab (BNL) and its testing at Jefferson Lab (JLab). In this paper, we will present the performance of the K{sub 2}CsSb photocathode in the preparation chamber and in the DC gun.

McCarter J. L.; Rao T.; Smedley, J.; Grames, J.; Mammei, R.; Poelker, M.; Suleiman, R.

2011-09-01T23:59:59.000Z

266

Semiconductor structures having electrically insulating and conducting portions formed from an AlSb-alloy layer  

DOE Patents (OSTI)

A semiconductor structure. The semiconductor structure comprises a plurality of semiconductor layers formed on a substrate including at least one layer of a III-V compound semiconductor alloy comprising aluminum (Al) and antimony (Sb), with at least a part of the AlSb-alloy layer being chemically converted by an oxidation process to form superposed electrically insulating and electrically conducting portions. The electrically insulating portion formed from the AlSb-alloy layer comprises an oxide of aluminum (e.g. Al.sub.2 O.sub.3), while the electrically conducting portion comprises Sb. A lateral oxidation process allows formation of the superposed insulating and conducting portions below monocrystalline semiconductor layers for forming many different types of semiconductor structures having particular utility for optoelectronic devices such as light-emitting diodes, edge-emitting lasers, vertical-cavity surface-emitting lasers, photodetectors and optical modulators (waveguide and surface normal), and for electronic devices such as heterojunction bipolar transistors, field-effect transistors and quantum-effect devices. The invention is expected to be particularly useful for forming light-emitting devices for use in the 1.3-1.6 .mu.m wavelength range, with the AlSb-alloy layer acting to define an active region of the device and to effectively channel an electrical current therein for efficient light generation.

Spahn, Olga B. (Albuquerque, NM); Lear, Kevin L. (Albuquerque, NM)

1998-01-01T23:59:59.000Z

267

Lattice-registered growth of GaSb on Si (211) with molecular beam epitaxy  

Science Conference Proceedings (OSTI)

A GaSb film was grown on a Si(211) substrate using molecular beam epitaxy indicating full lattice relaxation as well as full lattice registration and dislocation-free growth in the plane perpendicular to the [01 - 1]-direction. Heteroepitaxy of GaSb on a Si(211) substrate is dominated by numerous first order and multiple higher order micro-twins. The atomic-resolved structural study of GaSb films by high-angle annular dark-field scanning transmission electron microscopy reveals that slight tilt, along with twinning, favors the lattice registry to Si(211) substrates. Preferential bonding of impinging Ga and Sb atoms at the interface due to two distinctive bonding sites on the Si(211) surface enables growth that is sublattice-ordered and free of anti-phase boundaries. The role of the substrate orientation on the strain distribution of GaSb epilayers is further elucidated by investigating the local change in the lattice parameter using the geometric phase analysis method and hence effectiveness of the lattice tilting in reducing the interfacial strain was confirmed further.

Hosseini Vajargah, S.; Botton, G. A. [Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Canadian Centre for Electron Microscopy, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Ghanad-Tavakoli, S. [Centre for Emerging Device Technologies, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Preston, J. S.; Kleiman, R. N. [Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Centre for Emerging Device Technologies, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Department of Engineering Physics, McMaster University, Hamilton, Ontario L8S 4L7 (Canada)

2012-11-01T23:59:59.000Z

268

Fly Ash and Mercury Oxidation/Chlorination Reactions  

Science Conference Proceedings (OSTI)

Mercury is a known pollutant that has detrimental effect on human health and environment. The anthropogenic emissions of mercury account for 10 to 30% of worldwide mercury emissions. There is a need to control/reduce anthropogenic mercury emissions. Many mercury control technologies are available but their effectiveness is dependent on the chemical form of mercury, because different chemical forms of mercury have different physical and chemical properties. Mercury leaves the boiler in its elemental form but goes through various transformations in the post-combustion zone. There is a need to understand how fly ash and flue gas composition affect speciation, partitioning, and reactions of mercury under the full range of post-combustion zone conditions. This knowledge can then be used to predict the chemical transformation of mercury (elemental, oxidized or particulate) in the post combustion zone and thus help with the control of mercury emissions from coal-burning power plants. To accomplish this goal present study was conducted using five coal fly ashes. These ashes were characterized and their catalytic activity was compared under selected reaction conditions in a fixed bed reactor. Based on the results from these fly ash experiments, three key components (carbon, iron oxide and calcium oxide) were chosen. These three components were then used to prepare model fly ashes. Silica/alumina was used as a base for these model fly ashes. One, two or three component model fly ashes were then prepared to investigate mercury transformation reactions. The third set of experiments was performed with CuO and CuCl2 catalysts to further understand the mercury oxidation process. Based on the results of these three studies the key components were predicted for different fly ash compositions under variety of flue gas conditions. A fixed bed reactor system was used to conduct this study. In all the experiments, the inlet concentration of Hg0(g) was maintained at 35 {micro}g/m3 using a diffusion tube as the source of Hg0(g). All experiments were conducted using 4% O2 in nitrogen mix as a reaction gas, and other reactants (HCl, H2O and SO2, NO2, Br2) were added as required. The fixed bed reactor was operated over a temperature range of 200 to 400 C. In each experiment, the reactor effluent was analyzed using the modified Ontario-Hydro method. After each experiment, fly ash particles were also analyzed for mercury. The results show that the ability of fly ash to adsorb and/or oxidize mercury is primarily dependent on its carbon, iron and calcium content. There can be either one or more than one key component at a particular temperature and flue gas condition. Surface area played a secondary role in effecting the mercury transformations when compared to the concentration of the key component in the fly ash. Amount of carbon and surface area played a key important role in the adsorption of mercury. Increased concentration of gases in the flue gas other than oxygen and nitrogen caused decreased the amount of mercury adsorbed on carbon surface. Mercury adsorption by iron oxide primarily depended on the crystalline structure of iron oxide. {alpha}-Iron oxide had no effect on mercury adsorption or oxidation under most of the flue gas conditions, but ?-iron oxide adsorbed mercury under most of the flue gas conditions. Bromine is a very good oxidizing agent for mercury. But in the presence of calcium oxide containing fly ashes, all the oxidized mercury would be reduced to elemental form. Among the catalysts, it was observed that presence of free lattice chlorine in the catalyst was very important for the oxidation of mercury. But instead of using the catalyst alone, using it along with carbon may better serve the purpose by providing the adsorption surface for mercury and also some extra surface area for the reaction to occur (especially for fly ashes with low surface area).

Sukh Sidhu; Patanjali Varanasi

2008-12-31T23:59:59.000Z

269

Limestone and Ash Storage Silos and Lime Preparation Equipment, Part  

NLE Websites -- All DOE Office Websites (Extended Search)

Limestone and Ash Storage Silos and Lime Preparation Equipment, Part Limestone and Ash Storage Silos and Lime Preparation Equipment, Part of the System to Inject Limestone Sorbent for SO, Control. Nucla, CO Nucla...continued Before being repowered, the plant consisted of three 12 MWe coal stoker- fired units built in 1959, which were taken out of service in 1984 due to low efficiency and high fuel cost. Antici- pating a need for additional power in the early 1990s. and after review of many power generation alternatives, CUEA started constmction of the re- powered Nucla CFB plant in Novem- ber 1984 and completed the project in May 1987. The original boilers were replaced with a new Fympower Corp. CFB bailer, a new high pressure 74 MWe steam turbine generator was installed, the three original 12 MWe steam turbines were

270

Microsoft Word - CX-Ashe-CGSFiberInstallation_WEB.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

5, 2011 5, 2011 REPLY TO ATTN OF: KEP-4 SUBJECT: Environmental Clearance Memorandum Debbie Ruckwardt Electrical Engineer - TEP-CSB-1 Proposed Action: Installing fiber optic cables between Bonneville Power Administration's (BPA) Ashe Substation and Energy Northwest's Columbia Generating Station (CGS). Budget Information: Work Order # 00261540 PP&A Project No.: PP&A 1864 Categorical Exclusion Applied (from Subpart D, 10 C.F.R. Part 1021): B1.3, Routine maintenance activities...for structures, rights of way, infrastructures such as roads, equipment... routine maintenance activities, corrective....are required to maintain...infrastructures...in a condition suitable for a facility to be used for its designed purpose. Location: The project takes place between BPA's Ashe Substation and Energy Northwest's

271

Ash Fork, Arizona: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Ash Fork, Arizona: Energy Resources Ash Fork, Arizona: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 35.2250114°, -112.4840675° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.2250114,"lon":-112.4840675,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

272

Blue Ash, Ohio: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Blue Ash, Ohio: Energy Resources Blue Ash, Ohio: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.2320029°, -84.3782734° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.2320029,"lon":-84.3782734,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

273

Utilization of Biomineralization Processes with Fly Ash for Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Utilization of Biomineralization Processes with Fly Ash Utilization of Biomineralization Processes with Fly Ash for Carbon Sequestration Y. Roh (rohy@ornl.gov; 865-576-9931) T. J. Phelps (phelpstj1@ornl.gov; 865-574-7290) Environmental Sciences Division, Oak Ridge National Laboratory*, Oak Ridge, TN 37831-6036 A. D. McMillan (mcmillanad@ornl.gov; 865-241-4554) R. J. Lauf (laufrj@ornl.gov; 865-574-5176) Metal and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6085 *Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under contract number DE-AC05-00OR22725 Introduction The Department of Energy (DOE) Energy Information Administration estimates atmospheric greenhouse gas releases may exceed 8 billion metric tons by the year 2010 heightening its international environmental concern. Carbon dioxide will dominate the

274

Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Site (SRS) recently cleaned up a 17- Site (SRS) recently cleaned up a 17- acre basin containing coal ash residues from Cold War operations. The American Recovery and Reinvestment Act project was safely completed at a cost of $8.9 million, $2.9 million under budget. The manmade earthen basin received ash from the former R Area Pow- erhouse operations, which ended in 1964. The first of five reactors con- structed at SRS, the R Reactor produced nuclear materials for national defense. Recovery Act funding allowed SRS to accelerate cleanup of the basin and complete the project five years earlier than the target set in a regu- latory schedule. In late 2010, the U.S. Environmental Protection Agency and South Carolina Department of Health and Environmental Control determined the closure met all regulatory requirements after inspection

275

Coal-ash spills highlight ongoing risk to ecosystems  

SciTech Connect

Two recent large-scale spills of coal combustion waste have highlighted the old problem of handling the enormous quantity of solid waste produced by coal. Both spills happened at power plants run by the Tennessee Valley Authority (TVA). In December 2008 a holding pond for coal ash collapsed at a power plant in Kingstom, Tenn., releasing coal-ash sludge onto farmland and into rivers: in January 2009 a break in a pipe removing water from a holding pond for gypsum caused a spill at Widows Creek Fossil Plant in Stevenson, Ala. The article discusses the toxic outcome of such disasters on ecosystems, quoting work by Willaim Hopkins at Virginia Polytechnic Institute and State University and recommendations and reports of the US EPA. 2 photos.

Chatterjee, R.

2009-05-01T23:59:59.000Z

276

A Laboratory Method for Ash Particle Size Determination  

Science Conference Proceedings (OSTI)

Increasing stringent particulate emissions limits are putting more pressure on power producers to improve electrostatic precipitator (ESP) performance. In an effort to select the most cost effective upgrade option, many power plant engineers are using ESP computer models to estimate the impact of the available options. These models are sensitive to the fly ash particle size distribution used in the calculations, but the actual distribution is rarely known. Furthermore, measuring this distribution has, in...

2005-03-23T23:59:59.000Z

277

Ash Properties Analysis from Co-Firing Biomass and Coal  

Science Conference Proceedings (OSTI)

Power plant interest in renewable energy has been increasing, especially in response to legislative requirements to include renewables in the generation mix. One promising renewable strategy is co-firing biomass with coal, in pulverized coal- (PC-) fired units. The objective of this research is to provide quantitative data on full-scale test burn samples to demonstrate changes in ash characteristics and to identify anomalies affecting particulate material (PM) collection efficiency that result from co-fi...

2011-09-06T23:59:59.000Z

278

A new way to stabilize fly ash from municipal incinerators  

Science Conference Proceedings (OSTI)

Heavy metals and toxic chlorinated organics, added to very low grain-size distributions, make fly ashes from municipal incinerators a very hazardous waste. For their disposal, the present general trend is, not only to stabilize chemically the ashes, i.e., to reduce the leachability of the toxic substances, but also to stabilize them mechanically, i.e., to convert them into massive, resistant, and unleachable solids. This paper describes various stabilization methods used on representative European fly ash samples, which led to the development of a new stabilization technique taking place in four stages: elimination of the alkali chlorides by dissolution; addition of a moderate quantity of phosphoric acid; calcination; and solidification with Portland clinker or cement. The principal advantages of the process are as follows: the polychlorodibenzodioxins-polychlorodibenzofurans are destroyed, the reactivity of the heavy metals is reduced drastically, the final solids have satisfactory mechanical properties, and the increase in weight of the waste to be disposed of does not exceed one fourth. Comparative results of TCLP extraction tests are presented.

Derie, R. [Free Univ. of Brussels (Belgium). Dept. of Ore Dressing

1996-12-31T23:59:59.000Z

279

Structural Characterization of Doped GaSb Single Crystals by X-ray Topography  

Science Conference Proceedings (OSTI)

We characterized GaSb single crystals containing different dopants (Al, Cd and Te), grown by the Czochralski method, by x-ray topography and high angular resolution x-ray diffraction. Lang topography revealed dislocations parallel and perpendicular to the crystal's surface. Double-crystal GaSb 333 x-ray topography shows dislocations and vertical stripes than can be associated with circular growth bands. We compared our high-angular resolution x-ray diffraction measurements (rocking curves) with the findings predicted by the dynamical theory of x-ray diffraction. These measurements show that our GaSb single crystals have a relative variation in the lattice parameter ({Delta}d/d) on the order of 10{sup -5}. This means that they can be used as electronic devices (detectors, for example) and as x-ray monochromators.

Honnicke, M.G.; Mazzaro, I.; Manica, J.; Benine, E.; M da Costa, E.; Dedavid, B. A.; Cusatis, C.; Huang, X. R.

2009-09-13T23:59:59.000Z

280

Spiral growth of topological insulator Sb{sub 2}Te{sub 3} nanoplates  

SciTech Connect

Sb{sub 2}Te{sub 3} nanoplates synthesized by vapor phase deposition method have been systemically investigated employing atomic force microscopy, which exhibit regular spiral structures on the surface. The height of spiral steps is determined to be 1 nm corresponding to one quintuple layer, with an inter-step separation ranging from 500 nm to 1 {mu}m. Growth mechanism of spiral structures on the Sb{sub 2}Te{sub 3} nanoplate surface is elucidated, which can be applied to other layered materials with van der Waals epitaxy growth. The electrostatic properties of Sb{sub 2}Te{sub 3} nanoplates with spiral structures are also simultaneously characterized.

Hao Guolin; Qi Xiang; Fan Yinping; Xue Lin; Peng Xiangyang; Wei Xiaolin; Zhong Jianxin [Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, Xiangtan University, Hunan 411105 (China) and Laboratory for Quantum Engineering and Micro-Nano Energy Technology and Faculty of Materials and Optoelectronic Physics, Xiangtan University, Hunan 411105 (China)] [Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, Xiangtan University, Hunan 411105 (China) and Laboratory for Quantum Engineering and Micro-Nano Energy Technology and Faculty of Materials and Optoelectronic Physics, Xiangtan University, Hunan 411105 (China)

2013-01-07T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Thermoelectric performance of electron and hole doped PtSb2  

Science Conference Proceedings (OSTI)

We investigate the thermoelectric properties of electron and hole doped PtSb2. Our results show that for doping of 0.04 holes per unit cell (1:5 1020 cm 3) PtSb2 shows a high Seebeck coefficient at room temperature, which can also be achieved at other temperatures by controlling the carrier concentration (both electron and hole). The electrical conductivity becomes temperature independent when the doping exceeds some 0.2 electrons/holes per unit cell. The figure of merit at 800 K in electron and hole doped PtSb2 is comparatively low at 0.13 and 0.21, respectively, but may increase significantly with As alloying due to the likely opening of a band gap and reduction of the lattice thermal conductivity

Saeed, Yasir [King Abdullah University of Science and Technology (KAUST), Thuwal, Kingdom of Saudi Arabia; Singh, Nirprenda [King Abdullah University of Science and Technology (KAUST), Thuwal, Kingdom of Saudi Arabia; Schwingenschlogl, Udo [King Abdullah University of Science and Technology (KAUST), Thuwal, Kingdom of Saudi Arabia; Parker, David S [ORNL

2013-01-01T23:59:59.000Z

282

Electron Scattering in InSb Quantum Wells due to Micro-twin Defects  

Science Conference Proceedings (OSTI)

The transport electron scattering due to micro-twin (MT) defects in InSb quantum wells (QWs) has been investigated at room temperature (RT). A linear-regression-based scattering analysis showed that Matthiessen's rule is applicable to the RT electron mobility in 20-nm-thick InSb QWs that contain MTs (whose density is 5.6x10{sup 2}-1.2x10{sup 4} /cm) and threading dislocations (8.7x10{sup 8}-3.2x10{sup 9} /cm{sup 2}) as dominant structural defects. For such an InSb QW whose local electron mobility in its non-MT regions is 2.8x10{sup 4}-4.5x10{sup 4} cm{sup 2}/(Vs), the MT-originated energy barrier against the electron transport is deduced to be 0.081-0.093 eV at RT.

Mishima, T. D.; Santos, M. B. [Homer L. Dodge Department of Physics and Astronomy, and Center for Semiconductor Physics in Nanostructure University of Oklahoma, 440 W. Brooks St., Norman, OK 73019 (United States)

2011-12-26T23:59:59.000Z

283

Cu2Sb thin films as anode for Na-ion batteries  

SciTech Connect

Cu2Sb thin films prepared by magnetron sputtering are evaluated as an anode material for Na-ion batteries. The starting material is composed of nanocrystallites with the desired tetragonal P4/nmm structure. The study of the reaction mechanism reveals the formation of an amorphous/nanocrystalline phase of composition close to Na3Sb as the final reaction product. The solid electrolyte interphase (SEI) material is mostly composed of carbonates (Na2CO3, NaCO3R). The Cu2Sb anode possesses moderate capacity retention with a reversible storage capacity (250 mAh/g) close to the theoretical value (323 mAh/g), an average reaction potential of around 0.55 V vs. Na/Na+, and a high rate performance (10 C-rate).

Baggetto, Loic [ORNL; Allcorn, Eric [University of Texas, Austin; Manthiram, Arumugam [University of Texas, Austin; Veith, Gabriel M [ORNL

2013-01-01T23:59:59.000Z

284

In-Situ Method for Treating Residual Sodium  

DOE Patents (OSTI)

A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

Sherman, Steven R.; Henslee, S. Paul

2005-07-19T23:59:59.000Z

285

Adhesion effect of interface layers on pattern fabrication with GeSbTe as laser thermal lithography film  

Science Conference Proceedings (OSTI)

Adhesion of pattern structures is a very important issue in laser thermal lithography. In this paper, Si"3N"4 and ZnS-SiO"2 were investigated as interface layers to improve patterns' adhesion to substrate on pattern fabrication with Ge"2Sb"2Te"5 as laser ... Keywords: Adhesion, GeSbTe, Interface layers, Thermal lithography, Thin films, Wet etching

Changmeng Deng; Yongyou Geng; Yiqun Wu; Yang Wang; Jinsong Wei

2013-03-01T23:59:59.000Z

286

The Crystallization Behavior of Stochiometric and Off-stochiometric Ga-Sb-Te Materials for Phase-Change Memory  

Science Conference Proceedings (OSTI)

The stoichiometric Ga{sub 4}Sb{sub 6}Te{sub 3} and Ga-Sb materials were systematically studied. The alloy Ga{sub 4}Sb{sub 6}Te{sub 3} shows a fast crystallization speed, very high crystallization temperature, T{sub x}, and high electrical contrast. Although stoichiometric GaSb has similar performance and even faster crystallization speed, the electrical contrast is much lower. The other off-stoichiometric compounds we studied all have higher T{sub x} than Ge{sub 2}Sb{sub 2}Te{sub 5} indicating a good amorphous stability. By raising the Sb/Te ratio with GaSb incorporation, T{sub x} and the recrystallization time of melt-quenched, amorphous samples can be effectively increased. The stoichiometric Ga{sub 4}Sb{sub 6}Te{sub 3} with less likelihood of phase-segregation compared to nonstoichiometric compounds is a promising candidate for phase-change memory.

H Cheng; S Raoux; J Jordan-Sweet

2011-12-31T23:59:59.000Z

287

Superheater Tube Corrosion in Wood Gasifier Ash Deposits  

DOE Green Energy (OSTI)

The upper operating temperature of tubes in heat exchangers/steam generators is strongly influenced by the degradation that can occur because of the reaction of the exchanger/generator tubing with the deposits that accumulate on the surface of the tubes. In fact, severe corrosion has been observed in some biomass fired systems, particularly with elevated potassium and chlorine concentrations in the deposits. Wood gasifiers have recently been and are currently being constructed at several sites in North America. In these systems, the syngas is burned to produce steam and the performance of the heat exchanger tubes under ash deposits is of great concern. As temperatures of the heat exchangers are increased in an effort to increase their operating efficiency, the performance of the tubes is of greater interest. The corrosion behavior of alloy steel tubes as a function of temperature has been investigated by exposing samples of selected alloys to ash collected from the steam generator fired by syngas produced in wood gasifiers. This study compares corrosion rates from laboratory exposures of synthesis gas and ash at 500 C and 600 C. This study investigated the material performance of four ferritic steels and one austenitic steel exposed to conditions expected on the fireside of a wood gasifier. The purpose of this study was to identify an effective method for determining material performance for samples exposed to both the process gas and the fly ash that is typically observed within the steam generator for times up to 1000 hours. Mass changes were measured for all of the samples, but this information can be misleading concerning material performance due to the difficulty in sufficiently cleaning the samples after exposure in the ash. Therefore, small cross sections of the samples were collected and imaged using optical microscopy. Oxide thicknesses were measured along with metal losses. The metal loss information provides a clear indication of material performance. The metal loss rates for the ferritic steels at 500 C were almost half of those observed at 600 C and the rates decreased with increasing exposure time. It was also reported that the metal loss rates generally decrease with increasing chromium concentration.

Bestor, Michael A [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

2011-01-01T23:59:59.000Z

288

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Accomplish Cleanup of Second Cold War Coal Ash Accomplish Cleanup of Second Cold War Coal Ash Basin Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin American Recovery and Reinvestment Act workers recently cleaned up a second basin containing coal ash residues from Cold War operations at the Savannah River Site (SRS). About $24 million from the Recovery Act funded the environmental restoration project, allowing SRS to complete the project at least five years ahead of schedule. The work is part of a larger Recovery Act cleanup of the P Area scheduled for completion by the end of September 2011. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin More Documents & Publications Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin Recovery Act Workers Add Time Capsule Before Sealing Reactor for Hundreds

289

Microstructural stability in LPE Ga{sub x}In{sub (1{minus}x)}As{sub y}Sb{sub (1{minus}y)}/GaSb heterostructures  

DOE Green Energy (OSTI)

The morphological and structural characteristics associated with the growth of lattice matched In{sub x}Ga{sub (1{minus}x)}As{sub y}Sb{sub (1{minus}y)}/GaSb (100) heterostructures is presented. The experiments focused on studying the effect of growth on vicinal surfaces tilted from the exact (100) orientation as well as variations in epilayer chemistry. It was found that variations in these process parameters had very strong effects on both the nucleation characteristics of the epilayer and the atomistic scale homogeneity of the alloy. The <100> and <110> variants in compositional modulation/phase separation were detected, as well as the evolution of weak (110) ordering. These results are discussed in the context of other studies on phase stability in III-V epitaxial structures, especially in terms of surface reconstruction and kinetic effects near conditions of spinodal decomposition.

Chen, C.Y.; Bucklen, V.; Rajan, K. [Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Materials Science and Engineering; Freeman, M.; Cardines, R.P. [Lockheed-Martin, Inc., Schenectady, NY (United States)

1998-06-01T23:59:59.000Z

290

SO/sub 2/ scrubbing: more work for sodium  

SciTech Connect

The effects that dry scrubbing of flue gases with sodium sorbents could have on supplies of naturally-occurring sodium compounds such as nahcolite and trona are discussed.

Not Available

1984-07-18T23:59:59.000Z

291

Great thermoelectric power factor enhancement of CoSb{sub 3} through the lightest metal element filling  

Science Conference Proceedings (OSTI)

Lithium, the lightest metal element with a small ionic radius, is successfully filled into the voids of CoSb{sub 3} by utilizing the high pressure synthesis technique. The synthesized Li{sub 0.4}Co{sub 4}Sb{sub 12} shows the largest thermoelectric power factor of 6000 {mu}W m{sup -1} K{sup -2} among all elemental filled CoSb{sub 3} materials. This significantly enhanced thermoelectric power factor is attributed to the large carrier mobility of Li{sub 0.4}Co{sub 4}Sb{sub 12}, 61 cm{sup 2} V{sup -1} s{sup -1}, featuring a good electron crystal property for the Li-filled CoSb{sub 3} samples.

Zhang Jianjun; Xu Bo; Wang Limin; Yu Dongli; Liu Zhongyuan; He Julong; Tian Yongjun [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, Hebei 066004 (China)

2011-02-14T23:59:59.000Z

292

Electrostatic Precipitator Performance Modeling of High Carbon Ash Using EPRI's ESPM  

Science Conference Proceedings (OSTI)

To meet reduced nitrogen oxide (NOX) emission limits, many power producers installed low-NOX combustion systems that raised the level of carbon in the ash. However, carbon can be difficult to collect in an electrostatic precipitator and, consequently, the particulate emissions from many affected units increased. EPRI initiated this study to better understand carbon capture in electrostatic precipitators (ESPs), improve collection of high carbon ashes, and predict the collection of such ashes with its ESP...

2007-03-19T23:59:59.000Z

293

Development of New Industrial Ashalloy Material Using Fly-Ash Cenospheres  

Science Conference Proceedings (OSTI)

Metal matrix composites can provide improved functional properties compared to solid metal castings, while saving production energy and raw material costs in the process. In particular, ash-derived metal matrix composites can provide utilities a high value-added market for their coal fly ash. This report describes research on a promising manufacturing process for one such application -- pressure infiltration techniques to produce lead-ash composites for automotive battery applications.

1997-12-02T23:59:59.000Z

294

Mercury Emissions from Curing Concretes that Contain Fly Ash and Activated Carbon Sorbents  

Science Conference Proceedings (OSTI)

This report presents new laboratory data on the release of mercury from concrete containing fly ash and powdered activated carbon sorbents used to capture mercury. The concretes studied in this project were made with fly ashes from lignite and subbituminous coal, including fly ashes containing powdered activated carbon (PAC). Minute quantities of mercury were emitted from five concretes during the standard 28-day curing process and throughout an additional 28 days of curing for two of these concretes. Ge...

2006-09-07T23:59:59.000Z

295

Fly Ash Carbon Burn-Out at TVA's Colbert and Shawnee Stations: Site Specific Application Study  

Science Conference Proceedings (OSTI)

Fly ash beneficiation using Carbon Burn-Out (CBO) technology offers the opportunity to market fly ash that was previously landfilled. This site application study of beneficiating pulverized coal boiler fly ash at Tennessee Valley Authority's Colbert and Shawnee Stations indicates this process is a cost effective solution for decreasing solid waste disposal, increasing landfill life, improving boiler heat rate, and generating a positive revenue stream.

1996-07-02T23:59:59.000Z

296

Assessment of Impacts of NOx Reduction Technologies on Coal Ash Use: Volume 1: North American Perspective  

Science Conference Proceedings (OSTI)

This two-volume report provides documentation about physical and chemical effects combustion and post-combustion low-NOx technologies have on coal fly ash. U.S., European, and, to a lesser degree, Japanese experience is discussed. The report assesses the effect of low-NOx technologies on fly ash markets in a general manner. Options for beneficiating fly ash for specific markets also appear.

1997-01-04T23:59:59.000Z

297

Use of High Carbon Fly Ash as a Component of Raw Mix for Cement Manufacture  

Science Conference Proceedings (OSTI)

In the production of concrete, fly ash often serves as a supplementary cementing material, but some fly ashes may not be suitable for this use due to excess unburned carbon. This report presents the results of a literature investigation, bench-scale laboratory study, and pilot-scale tests of the feasibility of using such high carbon fly ashes in the manufacture of portland cement.

1998-06-30T23:59:59.000Z

298

Geochemical Investigation of Pyrite Codisposal with Sluiced Fly Ash and Implications for Selecting Remedial Actions  

Science Conference Proceedings (OSTI)

Oxidation of pyrite results in acid generation as well as the release of sulfate, iron, and other metals to solution. When pyritic coal mill rejects are codisposed with coal ash, pyrite oxidation and the subsequent interaction of oxidation products with the ash primarily control leachate quality. The geochemistry of the pyrite/ash system has implications for management and remediation actions at codisposal facilities. Utilities can use the results of this research to make decisions regarding such facilit...

1995-08-08T23:59:59.000Z

299

Thermal Barrier Coatings Resistant to Attack by Molten Fly Ash in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Thermal Barrier Coatings Resistant to Attack by Molten Fly Ash in Integrated Gas Combined Cycle Turbine Engines. Author(s), Andrew D.

300

INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS  

SciTech Connect

This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

2000-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Optimum Condition of Vanadium Recovery from Power Plant Fly-ash ...  

Science Conference Proceedings (OSTI)

Abstract Scope, In this study, recovery of vanadium from power plant fly-ash was developed using a hydro metallurgical process consisted of acidic leaching ...

302

The Leaching Behavior of Heavy Metals in MSWI Bottom Ash ... - TMS  

Science Conference Proceedings (OSTI)

May 1, 2007 ... The Leaching Behavior of Heavy Metals in MSWI Bottom Ash by Carbonation Reaction with Diffeent Water Content by Nam-Il Um, Kwang-Suk ...

303

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus...  

Open Energy Info (EERE)

.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search GEOTHERMAL...

304

Removal of Thiosalts using Biomass Ash from Pulp and Paper Mill ...  

Science Conference Proceedings (OSTI)

Biomass ash used in this study is collected from Corner Brook Pulp and Paper Mill, NL and Zellstoff Celgar Mill, BC and is characterized to understand the ...

305

and Se(VI) Ions onto Biomass Ash - Programmaster.org  

Science Conference Proceedings (OSTI)

Biomass ash used in this study is collected from Zellstoff Celgar Mill, British Columbia, Canada and is characterized to determine the physico-chemical ...

306

Radial power flattening in sodium fast reactors  

E-Print Network (OSTI)

In order to improve a new design for a uranium startup sodium cooled fast reactor which was proposed at MIT, this thesis evaluated radial power flattening by varying the fuel volume fraction at a fixed U-235 enrichment of ...

Krentz-Wee, Rebecca (Rebecca Elizabeth)

2012-01-01T23:59:59.000Z

307

Low-temperature Sodium-Beta Battery  

Rechargeable metallic sodium batteries have application in large-scale energy storage applications such as electric power generation and distribution, in motive applications such as electric vehicles, hybrids, and plug-in hybrids, and for aerospace ...

308

A novel approach for the improvement of open circuit voltage and fill factor of InGaAsSb/GaSb thermophotovoltaic cells  

DOE Green Energy (OSTI)

Heterojunction n-Al{sub 0.25}Ga{sub 0.75}As{sub 0.02}Sb{sub 098}/p-In{sub 0.16}Ga{sub 0.84}As{sub 0.04}Sb{sub 0.96} thermophotovoltaic (TPV) cells were grown by molecular-beam epitaxy on n-GaSb-substrates. In the spectral range from 1 {micro}m to 2.1 {micro}m these cells, as well as homojunction n-p-In{sub 0.16}Ga{sub 0.84}As{sub 0.04}Sb{sub 0.96} cells, have demonstrated internal quantum efficiencies exceeding 80%, despite about a 200 meV barrier in the conduction band at the heterointerface. Estimation shows that the thermal emission of the electrons photogenerated in p-region over this barrier can provide high efficiency for hetero-cells if the electron recombination time in p-In{sub 0.16}Ga{sub 0.84}As{sub 0.04}Sb{sub 0.96}is longer than 10 ns. Keeping the same internal efficiency as homojunction cells, hetero-cells provide a unique opportunity to decrease the dark forward current and thereby increase open circuit voltage (V{sub {proportional_to}}) and fill factor at a given illumination level. It is shown that the decrease of the forward current in hetero-cells is due to the lower recombination rate in n-type wider-bandgap space-charge region and to the suppression of the hole component of the forward current. The improvement in V{sub {proportional_to}} reaches 100% at illumination level equivalent to 1 mA/cm{sup 2} and it decreases to 5% at the highest illumination levels (2--3 A/cm{sup 2}), where the electron current component dominates in both the homo- and heterojunction cells. Values of V{sub {proportional_to}} as high as 310 meV have been obtained for a hetero-cell at illumination levels of 3 A/cm{sup 2}. Under this condition, the expected fill factor value is about 72% for a hetero-cell with improved series resistance. The heterojunction concept provides excellent prospects for further reduction of the dark forward current in TPV cells.

Garbuzov, D.Z.; Martinelli, R.U.; Khalfin, V.; Lee, H.; Morris, N.A.; Taylor, G.C.; Connolly, J.C. [Sarnoff Corp., Princeton, NJ (United States); Charache, G.W.; DePoy, D.M. [Lockheed-Martin, Inc., Schenectady, NY (United States)

1997-10-01T23:59:59.000Z

309

Method of preparing silicon from sodium fluosilicate  

DOE Patents (OSTI)

A process for preparing high purity silicon metal from Na.sub.2 SiF.sub.6 (sodium fluosilicate). The sodium fluosilicate is heated to decomposition temperature to form NaF, which retains most of the impurities, and gaseous SiF.sub.4. The SiF.sub.4 is then reduced by the bomb reduction method using a reductant having a low packing density.

Schmidt, Frederick A. (Ames, IA); Rehbein, David (Ames, IA); Chiotti, Premo (Ames, IA)

1984-01-01T23:59:59.000Z

310

UCOP Office of Research SB 13 Notice October 10, 2005 Page 1 FACT SHEET: Chaptered Legislation  

E-Print Network (OSTI)

research proposals before state agencies are permitted to disclose personal information to researchers. I identifiable data from California state agencies; · UC officials who work with researchers on data security? · SB 13 places new restrictions on the circumstances under which state agencies are permitted

Russell, Lynn

311

Structural evolution and characterization of heteroepitaxial GaSb thin films on Si(111) substrates  

Science Conference Proceedings (OSTI)

This paper describes the structural evolution and characterization of heteroepitaxial GaSb thin films on Si(111) substrates. The growth process used a combination of atomic sources which included the rf sputtering of Sb and the thermal effusion of Ga. The formation of crystalline GaSb thin films required that initially a monolayer thick Sb buffer layer be applied directly to a clean H-passivated Si(111) substrate surface. The resulting film was characterized by high resolution x-ray diffraction, Rutherford backscattering spectrometry, transmission electron microscopy, secondary ion mass spectroscopy, and atomic force microscopy (AFM). The AFM images were taken from the material after several periods of growth to determine the evolution of crystal structure with thickness. Atomic force microscopy images of the film surface showed that the heteroepitaxial layers were formed via the Stranski-Krastanov growth mechanism. This result is consistent with the heteroepitaxial growth of systems representing large differences in lattice constant. The hole mobility and carrier concentration in the deposited material were determined by the Hall measurement, performed at room temperature and on a 140 nm thick sample, to be 66 cm{sup 2}/V sec and 3x10{sup 19} cm{sup -3}, respectively. The carrier mobility was relatively low as expected for measurements taken at room temperature.

Nguyen, Thang; Varhue, Walter; Cross, Michael; Pino, Robinson; Adams, Edward; Lavoie, Mark; Lee, Jaichan [School of Engineering, University of Vermont, Burlington, Vermont 05405 (United States); IBM Corporation, Essex Junction, Vermont 05452 (United States); Department of Materials Science and Engineering, Sung Kyun Kwan University, Suwon 440-746 (Korea, Republic of)

2007-04-01T23:59:59.000Z

312

Development of InAsSb-based light emitting diodes for chemical sensing systems  

SciTech Connect

Mid-infrared (3--6 {micro}m) LED`s are being developed for use in chemical sensor systems. As rich, InAsSb heterostructures are particularly suited for optical emitters in the mid-infrared region. The authors are investigating both InAsSb-InAs multiple quantum well (MQW) and InAsSb-InAsP strained layer superlattice (SLS) structures for use as the active region for light emitting diodes (LED`s). The addition of phosphorus to the InAs barriers increases the light and heavy hole splitting and hence reduces non-radiative Auger recombination and provides for better electron and hole confinement in the InAsSb quantum well. Low temperature (< 20 K) photoluminescence (PL) emission from MQW structures is observed between 3.2 to 6.0 {micro}m for InAsSb wells between 70 to 100 {angstrom} and antimony mole fractions between 0.04 to 0.18. Room temperature PL has been observed to 6.4 {micro}m in MQW structures. The additional confinement by InAsP barriers results in low temperature PL being observed over a narrower range (3.2 to 5.0 {micro}m) for the similar well thicknesses with antimony mole fractions between 0.10 to 0.24. Room temperature photoluminescence was observed to 5.8 {micro}m in SLS structures. The addition of a p-AlAsSb layer between the n-type active region (MQW or SLS) and a p-GaAsSb contact layer improves electron confinement of the active region and increases output power by a factor of 4. Simple LED emitters have been fabricated which exhibit an average power at room temperature of > 100 {micro}W at 4.0 {micro}m for SLS active regions. These LED`s have been used to detect CO{sub 2} concentrations down to 24 ppm in a first generation, non-cryogenic sensor system. They will report on the development of novel LED device designs that are expected to lead to further improvements in output power.

Allerman, A.A.; Kurtz, S.R.; Biefeld, R.M.; Baucom, K.C.; Burkhatt, J.H.

1998-02-01T23:59:59.000Z

313

Speciation of Selenium, Arsenic, and Zinc in Class C Fly Ash  

Science Conference Proceedings (OSTI)

A major environmental concern associated with coal fly ash is the mobilization of trace elements that may contaminate water. To better evaluate proper use of fly ash, determine appropriate disposal methods, and monitor postdisposal conditions, it is important to understand the speciation of trace elements in fly ash and their possible environmental impact. The speciation of selenium, arsenic, and zinc was determined in five representative Class C fly ash samples from combustion of sub-bituminous Powder River Basin coal using synchrotron-based X-ray absorption spectroscopy to provide an improved understanding of the mechanisms of trace element association with the fly ash. Selenium in all fly ash samples occurs predominantly as Se(IV), with the exception of one sample, in which there was a minor amount of Se(0). Se(0) is likely associated with the high content of unburned coal in the sample. Arsenic exists in the fly ash as a single phase most consistent with calcium pyroarsenate. In contrast, zinc occurs as two distinct species in the silicate glass matrix of the fly ash. This work demonstrates that residual carbon in fly ash may reduce potential Se mobility in the environment by retaining it as less soluble elemental Se instead of Se(IV). Further, this work suggests that As and Zn in Class C fly ash will display substantially different release and mobilization behaviors in aquatic environments. While As release will primarily depend upon the dissolution and hydrolysis of calcium pyroarsenate, Zn release will be controlled by the dissolution of alkaline aluminosilicate glass in the ash.

Luo, Yun; Giammar, Daniel E.; Huhmann, Brittany L.; Catalano, Jeffrey G. (WU)

2011-11-17T23:59:59.000Z

314

Growth and elemental accumulation by canola on soil amended with coal fly ash  

SciTech Connect

To explore the agronomic potential of an Australian coal fly ash, we conducted two glasshouse experiments in which we measured chlorophyll fluorescence, CO{sub 2} assimilation (A), transpiration, stomatal conductance, biomass accumulation, seed yield, and elemental uptake for canola (Brassica napus) grown on soil amended with an alkaline fly ash. In Experiment 1, application of up to 25 Mg/ha of fly ash increased A and plant weight early in the season before flowering and seed yield by up to 21%. However, at larger rates of ash application A, plant growth, chlorophyll concentration, and yield were all reduced. Increases in early vigor and seed yield were associated with enhanced uptake of phosphorus (P) by the plants treated with fly ash. Fly ash application did not influence accumulation of B, Cu, Mo, or Zn in the stems at any stage of plant growth or in the seed at harvest, except Mo concentration, which was elevated in the seed. Accumulation of these elements was mostly in the leaves, where concentrations of Cu and Mo increased with any amount of ash applied while that of B occurred only with ash applied at 625 Mg/ha. In Experiment 2, fly ash applied at 500 Mg/ha and mixed into the whole 30 cm soil core was detrimental to growth and yield of canola, compared with restricting mixing to 5 or 15 cm depth. In contrast, application of ash at 250 Mg/ha with increasing depth of mixing increased A and seed yield. We concluded that fly ash applied at not more than 25 Mg/ha and mixed into the top 10 to 15 cm of soil is sufficient to obtain yield benefits.

Yunusa, I.A.M.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Murray, B.R.; Nissanka, S.P. [University of Technology Sydney, Sydney, NSW (Australia)

2008-05-15T23:59:59.000Z

315

Crystal structure and chemical bonding of the intermetallic Zintl phase Yb[subscript 11]AlSb[subscript 9  

SciTech Connect

High resolution single crystal synchrotron X-ray diffraction data measured at 15(2) K were used to solve the structure of the complex intermetallic Zintl phase, Yb{sub 11}AlSb{sub 9} (space group Iba2), made up of Yb cations and polyanions along with isolated Sb anions. The 15(2) K cell parameters are a = 11.7383(4) {angstrom}, b = 12.3600(4) {angstrom}, c = 16.6796(6) {angstrom}. The temperature dependence of the structure was investigated through high resolution synchrotron powder X-ray diffraction (PXRD) data measured from 90 K to 1000 K. Rietveld refinements of the crystal structure revealed near linear thermal expansion of Yb{sub 11}AlSb{sub 9} with expansion coefficients of 1.49(2) x 10{sup -5} K{sup -1}, 1.71(3) x 10{sup -5} K{sup -1}, 1.13(1) x 10{sup -5} K{sup -1} for a, b and c, respectively. The chemical bonding in Yb{sub 11}AlSb{sub 9} was analyzed using atomic Hirshfeld surfaces, and the analysis supports the presence of the structural elements of Yb cations, [AlSb{sub 4}]{sup 9-} tetrahedra, [Sb{sub 2}]{sup 4-} dimers and isolated Sb{sup 3-} anions. However, indications of interatomic interactions between the Zintl anions and the Yb cations were also observed.

Kastbjerg, Sofie; Uvarov, Catherine A.; Kauzlarich, Susan M.; Chen, Yu-Sheng; Nishibori, Eiji; Spackman, Mark A.; Iversen, Bo Brummerstedt (Aarhus); (UWA); (UCD); (UC); (Nagoya)

2012-10-09T23:59:59.000Z

316

Development of an ash particle deposition model considering build-up and removal mechanisms  

SciTech Connect

Slagging and fouling on heat exchanger surfaces in power boilers fired with fossil fuels and fuel mixtures has a significant influence on boiler efficiency and availability. Mathematical modelling has long been considered a suitable method to assist boiler operators to determine optimized operating conditions for an existing furnace. The ultimate goal in ash deposition prediction is hereby the determination of the total amount of material deposited and hence the determination of the total reduction in efficiency. Depending on the fuels fired the total deposited mass is a combination of ash particle deposition and ash particle erosion due to non-sticky particles. The novel ash particle deposition model presented in this work considers deposition of sticky ash particles, cleansing of deposit by non-sticky sand particles and sticking of sand due to contact with sticky ash. The steady-state modelling results for the total amount of ash deposited on the deposition probe of an entrained flow reactor presented in this work agree well with the experimental data. Only at very high fractions of sand added as non-sticky material, a significant influence of the sand on the overall mass deposited was found. Since the model considers sticking of non-sticking sand due to contact with sticky ash, the fraction of sand deposited on the probe was especially studied. Using a correction factor to consider the influence of operating time on the steady-state simulations led to good agreement between simulations and experimental data. 12 refs., 10 figs.

Kjell Strandstroem; Christian Muellera; Mikko Hupa [Abo Akademi Process Chemistry Centre, Abo (Finland)

2007-12-15T23:59:59.000Z

317

Release of Mercury During Curing of Concrete Containing Fly Ash and Mercury Sorbent Material  

Science Conference Proceedings (OSTI)

This report provides laboratory data on mercury release during the initial curing stage of concrete made with fly ash or mixtures of fly ash and activated carbon containing mercury. These experiments suggest that mercury is not released from these concretes during initial curing.

2002-12-09T23:59:59.000Z

318

Research Summary RECOAL: Reintegration of coal ash disposal sites and mitigation  

E-Print Network (OSTI)

and Herzegovina; UBAL University of Banja Luka, Bosnia and Herzegovina; FAZ University of Zagreb, Croatia; BTUC risks of farmed and barren alkaline coal ash landfills in Tuzla, Bosnia and Herzegovina. Environmental its research on the thermo-electric plant (TEP) and associated coal ash sites at Tuzla, Bosnia

319

Quantifying the availability and the stability of trace cationic elements in fly ash  

E-Print Network (OSTI)

-Products Associated with Coal Mining Interactive Forum: Southern Illinois University at Carbondale, Carbondale, IL in this paper to deter- mine these parameters for model elements Cu(II), Cd(II), and Ni(II) in fly ash 50 mM EDTA extraction. Ă? 2006 Elsevier Ltd. All rights reserved. 1. Introduction Coal fly ash has

Ragsdell, Kenneth M.

320

Use of High-Calcium Fly Ash in Cement-Based Construction Materials  

E-Print Network (OSTI)

in blended cements with minimum (less than 10%) portland cement in the blend. Keywords: Fly ash; concrete impact assessments. INTRODUCTION #12;3 Coal is the most widely used source of energy for power production, total coal ash production in the world was estimated to be 600 million tons, of which 100 million tons

Wisconsin-Milwaukee, University of

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Use of Ash from the Incineration of Urban Garbage into Clayey ...  

Science Conference Proceedings (OSTI)

The waste is a type of fly-ash resulting from the incineration of a selected part of urban ... Analysis of Carbon Fiber Recovered from Optimized Processes of ... Clayey Ceramic Incorporated with Powder from the Sintering Plant of a ... Influence of Fly Ash and Fluorgypsum on Hydration Heat and Mortar Strength of Cement.

322

Resuspension of Relic Volcanic Ash and Dust from Katmai: Still an Aviation Hazard  

Science Conference Proceedings (OSTI)

Northwest winds were strong enough to continuously resuspend relic volcanic ash from the Katmai volcano cluster and the Valley of Ten Thousand Smokes on 20–21 September 2003. The ash cloud reached over 1600 m and extended over 230 km into the ...

David Hadley; Gary L. Hufford; James J. Simpson

2004-10-01T23:59:59.000Z

323

Rapid response to the Chaiten eruption, Chile, May 2008: ash fallout and impact  

E-Print Network (OSTI)

Rapid response to the Chaiten eruption, Chile, May 2008: ash fallout and impact David Pyle AGU, 90 (24), 205-7, 16 June 2009. #12;Satellite imagery records widespread ash fallout across central eruption of rhyolite since Katmai (1912). #12;Thick fallout deposits near Chaiten volcano (January 2009

324

Fly Ash Design Manual for Road and Site Applications: Volumes 1 and 2  

Science Conference Proceedings (OSTI)

This two-volume design manual describes the use of fly ash as a construction material in high-volume applications like structural fills, highway embankments, grouting, roller-compacted concrete, and land reclamation. The engineering data and construction procedures presented should help coal ash managers and power plant managers incorporate such applications in by-product management plans.

1992-04-01T23:59:59.000Z

325

Fly Ash Design Manual for Road and Site Applications: Volumes 1 and 2  

Science Conference Proceedings (OSTI)

This two-volume design manual describes the use of fly ash as a construction material in high-volume applications like structural fills, highway embankments, grouting, roller-compacted concrete, and land reclamation. The engineering data and construction procedures presented should help coal ash managers and power plant managers incorporate such applications in by-product management plans.

1992-06-01T23:59:59.000Z

326

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network (OSTI)

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

327

Effect of particle size and volume fraction on tensile properties of fly ash/polyurea composites  

E-Print Network (OSTI)

particles. In addition, the composites filled with 20% fly ash became softer. These samples showed lower, composites, tensile properties 1. INTRODUCTION Fly ash, a waste by-product generated abundantly in electric processibility of the filled materials5 . Furthermore, as a waste by-product, its usage decreases the overall

Nemat-Nasser, Sia

328

High-Volume Fly Ash Utilization Projects in the United States and Canada: Second Edition  

Science Conference Proceedings (OSTI)

Fly ash--an increasing disposal problem for utilities operating coal-fired power plants--has considerable unrealized potential as a construction material. In a wide-ranging survey, this study documented more than 250 U.S. and Canadian construction projects employing fly ash in high volume for backfill, landfill, hydraulic fill, embankments, pavement base courses, soil amendment, subgrade stabilization, and grout.

1986-02-24T23:59:59.000Z

329

488-D Ash Basin Vegetative Cover Treatibility Study  

SciTech Connect

The 488-D Ash Basin is an unlined containment basin that received ash and coal reject material from the operation of a powerhouse at the USDOE's Savannah River Site, SC. They pyretic nature of the coal rejects has resulted in the formation of acidic drainage (AD), which has contributed to groundwater deterioration and threatens biota in down gradient wetlands. Establishment of a vegetative cover was examined as a remedial alternative for reducing AD generation within this system by enhanced utilization of rainwater and subsequent non-point source water pollution control. The low nutrient content, high acidity, and high salinity of the basin material, however, was deleterious to plant survivability. As such, studies to identify suitable plant species and potential adaptations, and pretreatment techniques in the form of amendments, tilling, and/or chemical stabilization were needed. A randomized block design consisting of three subsurface treatments (blocks) and five duplicated surface amendments (treatments) was developed. One hundred inoculated pine trees were planted on each plot. Herbaceous species were also planted on half of the plots in duplicated 1-m2 beds. After two growing seasons, deep ripping, subsurface amendments and surface covers were shown to be essential for the successful establishment of vegetation on the basin. This is the final report of the study.

Barton, Christopher; Marx, Don; Blake, John; Adriano, Domy; Koo, Bon-Jun; Czapka, Stephen

2003-01-01T23:59:59.000Z

330

Characterization of Slag, Fly Ash and Portland Cement for Saltstone  

SciTech Connect

Batch-to-batch variability in the chemical and physical properties of the fly ash, slag and portland cement (binders) will be an ongoing concern over the many years that salt waste from Tank 50 will be processed into grout at the Saltstone Processing Facility. This batch-to-batch variability in the properties of the binder materials translates to variability in the fresh and cured properties of Saltstone. Therefore, it is important to quantify the batch-to-batch variability of the binder materials and the resultant variation in grout properties. This report is the starting point for that process by providing the baseline (reference point) binder properties to which future batches of binder materials can be compared. For this characterization effort, properties of fly ash, slag and portland cement were obtained and documented in this report. These properties included particle size distribution by laser light scattering and dry sieving, particle size and morphology by scanning electron microscopy, true, aerated and tapped densities, chemical composition, rheological properties of the water based slurries made from individual binder material, and volatility through thermogravimetric analysis and differential thermal analysis. The properties presented in this report also provide a baseline data set to assist in problem solving efforts when or if unanticipated and/or unwanted processing events occur at the Saltstone Processing Facility.

Harbour, J

2006-02-01T23:59:59.000Z

331

Use of ash from municipal solid waste combustion. Final report  

DOE Green Energy (OSTI)

This report details the results of efforts to integrate municipal solid waste combustion ash into a high strength portland cement concrete matrix comprised of multiple waste materials. The material developed by this research was to be used to construct a large underground storage vault to house the Friendly Mobile Barrier, a safety barrier system for use at highway crossings for the high speed rail system. The subcontractor, Environmental Solutions, Inc., of Richmond, Virginia, worked with researchers at Pennsylvania State University and the State University of New York--Stony Brook to develop and test the material. The result of this work is a portland cement concrete matrix which utilizes 80.01% recycled materials, and a field-applicable method for incorporating MSW ash as a component at volumes up to 9.78%. Twenty-eight day strengths of over 4000 psi were achieved, with 315 day strengths of 6500 psi. All structural, chemical and environmental testing showed the material to be competitive with conventional concrete.

NONE

1997-07-01T23:59:59.000Z

332

In situ analysis of ash deposits from black liquor combustion  

DOE Green Energy (OSTI)

Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

1996-05-01T23:59:59.000Z

333

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin American Recovery and Reinvestment Act workers recently cleaned up a second basin containing coal ash residues from Cold War operations at the Savannah River Site (SRS). About $24 million from the Recovery Act funded the environmental restoration project, allowing SRS to complete the project at least five years ahead of schedule. The work is part of a larger Recovery Act cleanup of the P Area scheduled for completion by the end of September 2011. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin More Documents & Publications EIS-0220: Final Environmental Impact Statement EIS-0220: Final Environmental Impact Statement

334

Argonne CNM HighlightL Hard X-ray characterization of fly ash geopolymers  

NLE Websites -- All DOE Office Websites (Extended Search)

Hard X-ray characterization of fly ash geopolymers Hard X-ray characterization of fly ash geopolymers Calcium Map Calcium map of an activated fly ash geopolymer displays regions of high calcium concentration (circled). Their distribution suggests localization as a discrete calcium-rich phase within the lower-calcium aluminosilicate geopolymer gel. Use of the Hard X-Ray Nanoprobe (HXN) has provided the first access to the nature of heterogeneity in real fly ash-derived geopolymers at the nanoscale. Direct evidence of the formation of discrete high-calcium nanometer-sized particles within a hydroxide-activated geopolymer synthesized from a low-calcium fly ash has been obtained using HXN fluorescence characterization. Additionally, the team of CNM users from the University of Melbourne, the Universidad del Valle of Colombia, and the

335

pH-dependent leaching of dump coal ash - retrospective environmental analysis  

Science Conference Proceedings (OSTI)

Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

2009-07-01T23:59:59.000Z

336

Mercury retention by fly ashes from coal combustion: Influence of the unburned carbon content  

Science Conference Proceedings (OSTI)

The objective of this study was to evaluate the effect of unburned carbon particles present in fly ashes produced by coal combustion on mercury retention. To achieve this objective, the work was divided into two parts. The aim of the first part of the study was to estimate the amount of mercury captured by the fly ashes during combustion in power stations and the relationship of this retention to the unburned carbon content. The second part was a laboratory-scale study aimed at evaluating the retention of mercury concentrations greater than those produced in power stations by fly ashes of different characteristics and by unburned carbon particles. From the results obtained it can be inferred that the unburned carbon content is not the only variable that controls mercury capture in fly ashes. The textural characteristics of these unburned particles and of other components of fly ashes also influence retention.

Lopez-Anton, M.A.; Diaz-Somoano, M.; Martinez-Tarazona, M.R. [CSIC, Oviedo (Spain)

2007-01-31T23:59:59.000Z

337

Gypsum treated fly ash as a liner for waste disposal facilities  

SciTech Connect

Fly ash has potential application in the construction of base liners for waste containment facilities. While most of the fly ashes improve in the strength with curing, the ranges of permeabilities they attain may often not meet the basic requirement of a liner material. An attempt has been made in the present context to reduce the hydraulic conductivity by adding lime content up to 10% to two selected samples of class F fly ashes. The use of gypsum, which is known to accelerate the unconfined compressive strength by increasing the lime reactivity, has been investigated in further improving the hydraulic conductivity. Hydraulic conductivities of the compacted specimens have been determined in the laboratory using the falling head method. It has been observed that the addition of gypsum reduces the hydraulic conductivity of the lime treated fly ashes. The reduction in the hydraulic conductivity of the samples containing gypsum is significantly more for samples with high amounts of lime contents (as high as 1000 times) than those fly ashes with lower amounts of lime. However there is a relatively more increase in the strengths of the samples with the inclusion of gypsum to the fly ashes at lower lime contents. This is due to the fact that excess lime added to fly ash is not effectively converted into pozzolanic compounds. Even the presence of gypsum is observed not to activate these reactions with excess lime. On the other hand the higher amount of lime in the presence of sulphate is observed to produce more cementitious compounds which block the pores in the fly ash. The consequent reduction in the hydraulic conductivity of fly ash would be beneficial in reducing the leachability of trace elements present in the fly ash when used as a base liner.

Sivapullaiah, Puvvadi V., E-mail: siva@civil.iisc.ernet.in [Department of Civil Engineering, Indian Institute of Science, Bangalore 560012 (India); Baig, M. Arif Ali, E-mail: reach2arif@gmail.com [Department of Civil Engineering, Indian Institute of Science, Bangalore 560012 (India)

2011-02-15T23:59:59.000Z

338

Feasible experimental study on the utilization of a 300 MW CFB boiler desulfurizating bottom ash for construction applications  

SciTech Connect

CFB boiler ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. The disposal in landfills has been the most common means of handling ash in circulating fluidized bed boiler power plants. However for a 300 MW CFB boiler power plant, there will be 600,000 tons of ash discharged per year and will result in great volumes and disposal cost of ash byproduct. It was very necessary to solve the utilization of CFB ash and to decrease the disposal cost of CFB ash. The feasible experimental study results on the utilization of the bottom ashes of a 300 MW CFB boiler in Baima power plant in China were reported in this paper. The bottom ashes used for test came from the discharged bottom ashes in a 100 MW CFB boiler in which the anthracite and limestone designed for the 300 MW CFB project was burned. The results of this study showed that the bottom ash could be used for cementitious material, road concrete, and road base material. The masonry cements, road concrete with 30 MPa compressive strength and 4.0 MPa flexural strength, and the road base material used for base courses of the expressway, the main road and the minor lane were all prepared with milled CFB bottom ashes in the lab. The better methods of utilization of the bottom ashes were discussed in this paper.

Lu, X.F.; Amano, R.S. [University of Wisconsin, Milwaukee, WI (United States). Dept. of Mechanical Engineering

2006-12-15T23:59:59.000Z

339

18 2010 Proceedings Symposium on Ash in North America GTR-NRS-P-72 GENETIC TRANSFORMATION OF FRAXINUS SPP. FOR  

E-Print Network (OSTI)

handles, and for fiber in the manufacture of fine papers. White ash is the primary commercial hardwood protocol for green ash. We are also investigating an adventitious shoot regeneration system using leaf18 2010 Proceedings Symposium on Ash in North America GTR-NRS-P-72 GENETIC TRANSFORMATION

340

Investigation on the utilization of coal fly ash as amendment to compost for vegetation in acid soil  

Science Conference Proceedings (OSTI)

The use of fly ash as amendment to compost is presented. Plant growth/yields of corn collard greens, mustard greens, and sorgum is described. The treatment parameters such as fly ash to compost ratio, fly ash-amended compost to soil ratio, type of compost used for treatment etc. are discussed. 2 refs., 5 figs., 8 tabs. (CBS)

Menon, M.P.

1990-04-16T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

High pressure transport characteristics of Bi[subscript 2]Te[subscript 3], Sb[subscript 2]Te[subscript 3], and BiSbTe[subscript 3  

Science Conference Proceedings (OSTI)

This paper presents ambient and high pressure measurements of transport properties of the Bi2Te3-Sb2Te3 series of materials. The electrical resistivity, thermal conductivity, and Seebeck coefficient have been measured on both end compounds and the direct solid solution of the two at pressure up to 10 GPa. An additional discussion involving the high pressure structure will be presented. From this, it was determined that these materials undergo at least two structural phase transitions between 0 and 20 GPa and a discussion is presented regarding this and the changes in the transport properties.

Jacobsen, M.K.; Sinogeikin, S.V.; Kumar, R.S.; Cornelius, A.L. (UNLV); (CIW)

2012-07-25T23:59:59.000Z

342

Evaluating the Effects of the Kingston Fly Ash Release on Fish Reproduction: Spring 2009 - 2010 Studies  

Science Conference Proceedings (OSTI)

On December 22, 2008, a dike containing fly ash and bottom ash at the Tennessee Valley Authority's (TVA) Kingston Fossil Plant in East Tennessee failed and released a large quantity of ash into the adjacent Emory River. Ash deposits from the spill extended 4 miles upstream of the facility to Emory River mile 6 and downstream to Tennessee River mile 564 ({approx}8.5 miles downstream of the confluence of the Emory River with the Clinch River, and {approx}4 miles downstream of the confluence of the Clinch River with the Tennessee River). A byproduct of coal combustion, fly ash contains a variety of metals and other elements which, at sufficient concentrations and in specific forms, can be harmful to biological systems. The ecological effects of fly ash contamination on exposed fish populations depend on the magnitude and duration of exposure, with the most significant risk considered to come from elevated levels of certain metals in the ash, particularly selenium, on fish reproduction and fish early life stages (Lemly 1993; Besser and others 1996). The ovaries of adult female fish in a lake contaminated by coal ash were reported to have an increased frequency of atretic oocytes (dead or damaged immature eggs) and reductions in the overall numbers of developing oocytes (Sorensen 1988) associated with elevated body burdens of selenium. Larval fish exposed to selenium through maternal transfer of contaminants to developing eggs in either contaminated bodies of water (Lemly 1999) or in experimental laboratory exposures (Woock and others 1987, Jezierska and others 2009) have significantly increased incidences of developmental abnormalities. Contact of fertilized eggs and developing embryos to ash in water and sediments may also pose an additional risk to the early life stages of exposed fish populations through direct uptake of metals and other ash constituents (Jezierska and others 2009). The establishment and maintenance of fish populations is intimately associated with the ability of individuals within a population to reproduce. Reproduction is thus generally considered to be the most critical life function affected by environmental contamination. From a regulatory perspective, the issue of potential contaminant-related effects on fish reproduction from the Kingston fly ash spill has particular significance because the growth and propagation of fish and other aquatic life is a specific classified use of the affected river systems. To address the potential effects of fly ash from the Kingston spill on the reproductive health of exposed fish populations, ORNL has undertaken a series of studies in collaboration with TVA that include: (1) a combined field study of metal bioaccumulation in ovaries and other fish tissues (Adams and others 2012) and the reproductive condition of sentinel fish species in reaches of the Emory and Clinch Rivers affected by the fly ash spill (the current report); (2) laboratory tests of the potential toxicity of fly ash from the spill area on fish embryonic and larval development (Greeley and others 2012); (3) additional laboratory experimentation focused on the potential effects of long-term exposures to fly ash on fish survival and reproductive competence (unpublished); and (4) a combined field and laboratory study examining the in vitro developmental success of embryos and larvae obtained from fish exposed in vivo for over two years to fly ash in the Emory and Clinch Rivers (unpublished). The current report focuses on the reproductive condition of adult female fish in reaches of the Emory and Clinch Rivers influenced by the fly ash spill at the beginning of the spring 2009 breeding season - the first breeding season immediately following the fly ash release - and during the subsequent spring 2010 breeding season. Data generated from this and related reproductive/early life stage studies provide direct input to ecological risk assessment efforts and complement and support other phases of the overall biomonitoring program associated with the fly ash spill.

Greeley Jr, Mark Stephen [ORNL; Adams, Marshall [ORNL; McCracken, Kitty [ORNL

2012-05-01T23:59:59.000Z

343

Coherent optical phonon spectroscopy studies of femtosecond-laser modified Sb{sub 2}Te{sub 3} films  

Science Conference Proceedings (OSTI)

We performed time-resolved reflectivity measurements to monitor changes in optical phonon modes in Sb{sub 2}Te{sub 3} thin films under femtosecond laser irradiation. We found that a phonon mode at 3.64 THz appears after high-fluence laser irradiation, in addition to the phonon modes of Sb{sub 2}Te{sub 3}. We determined that the additional mode is due to Te segregation as a result of laser-induced decomposition of the Sb{sub 2}Te{sub 3} film. This experiment clearly illustrates the irreversible effects of femtosecond laser irradiation during the measurement of coherent optical phonon dynamics in Sb{sub 2}Te{sub 3}.

Li Yuwei; Wang Guoyu [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States); Center for Solar and Thermal Energy Conversion, University of Michigan, Michigan 48109 (United States); Stoica, Vladimir A. [Center for Solar and Thermal Energy Conversion, University of Michigan, Michigan 48109 (United States); Applied Physics Program, University of Michigan, Ann Arbor, Michigan 48109 (United States); Endicott, Lynn [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States); Uher, Ctirad; Clarke, Roy [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States); Center for Solar and Thermal Energy Conversion, University of Michigan, Michigan 48109 (United States); Applied Physics Program, University of Michigan, Ann Arbor, Michigan 48109 (United States)

2010-10-25T23:59:59.000Z

344

Optical anisotropy of GaSb type-II nanorods on vicinal (111)B GaAs  

SciTech Connect

We form self-assembled GaSb type-II nanorods on a vicinal (111)B GaAs substrate by molecular beam epitaxy and study their optical anisotropy. The GaSb nanorods are elongated and aligned along the [-1 0 1] direction, where the average length, width, and height are about 84, 30, and 2.5 nm. In polarized photoluminescence (PL) measurements, the peak of the GaSb nanorods is observed at about 1.1 eV, where the PL intensity is largest for the [-1 0 1] polarization and smallest for the polarization perpendicular to it. The degree of polarization is more than 20% and depends on the recombination energy. By comparing with a theoretical model based on 4 x 4 Luttinger-Kohn Hamiltonian, we find that the experimental results are explained by considering the Sb/As inter-diffusion and the nanorod height distribution.

Kawazu, Takuya; Noda, Takeshi; Mano, Takaaki; Sakuma, Yoshiki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Akiyama, Yoshihiro [Toyota Technological Institute, 2-12-1 Hisakata, Tempaku-ku, Nagoya (Japan); Sakaki, Hiroyuki [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Toyota Technological Institute, 2-12-1 Hisakata, Tempaku-ku, Nagoya (Japan)

2011-12-05T23:59:59.000Z

345

Molecular beam epitaxial growth of metamorphic AlInSb/GaInSb high-electron-mobility-transistor structures on GaAs substrates for low power and high frequency applications  

Science Conference Proceedings (OSTI)

We report on molecular beam epitaxial growth of AlInSb/GaInSb metamorphic high-electron-mobility-transistor structures for low power, high frequency applications on 4 in. GaAs substrates. The structures consist of a Ga{sub 0.4}In{sub 0.6}Sb channel embedded in Al{sub 0.4}In{sub 0.6}Sb barrier layers which are grown on top of an insulating metamorphic buffer, which is based on the linear exchange of Ga versus In and a subsequent exchange of As versus Sb. Precise control of group V fluxes and substrate temperature in the Al{sub 0.4}In{sub 0.6}As{sub 1-x}Sb{sub x} buffer is essential to achieve high quality device structures. Good morphological properties were achieved demonstrated by the appearance of crosshatching and root mean square roughness values of 2.0 nm. Buffer isolation is found to be >100 k{Omega}/{open_square} for optimized growth conditions. Hall measurements at room temperature reveal electron densities of 2.8x10{sup 12} cm{sup -2} in the channel at mobility values of 21.000 cm{sup 2}/V s for single-sided Te volume doping and 5.4x10{sup 12} cm{sup -2} and 17.000 cm{sup 2}/V s for double-sided Te {delta}-doping, respectively.

Loesch, R.; Aidam, R.; Kirste, L.; Leuther, A. [Fraunhofer Institute for Applied Solid-State Physics (IAF), Tullastrasse 72, 79108 Freiburg (Germany)

2011-02-01T23:59:59.000Z

346

JV Task 120 - Coal Ash Resources Research Consortium Research  

Science Conference Proceedings (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') is the core coal combustion product (CCP) research group at the Energy & Environmental Research Center (EERC). CARRC focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of CCPs. CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCP utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program, which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCP performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 2007 to 2009 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCPs. The tasks were included in four categories: (1) Environmental Evaluations of CCPs; (2) Evaluation of Impacts on CCPs from Emission Controls; (3) Construction and Product-Related Activities; and (4) Technology Transfer and Maintenance Tasks. All tasks are designed to work toward achieving the CARRC overall goal and supporting objectives. The various tasks are coordinated in order to provide broad and useful technical data for CARRC members. Special projects provide an opportunity for non-CARRC members to sponsor specific research or technology transfer consistent with CARRC goals. This report covers CARRC activities from January 2007 through March 2009. These activities have been reported in CARRC Annual Reports and in member meetings over the past 2 years. CARRC continues to work with industry and various government agencies with its research, development, demonstration, and promotional activities nearing completion at the time of submission of this report. CARRC expects to continue its service to the coal ash industry in 2009 and beyond to work toward the common goal of advancing coal ash utilization by solving CCP-related technical issues and promoting the environmentally safe, technically sound, and economically viable management of these complex and changing materials.

Debra Pflughoeft-Hassett; Loreal Heebink; David Hassett; Bruce Dockter; Kurt Eylands; Tera Buckley; Erick Zacher

2009-03-28T23:59:59.000Z

347

Method of making a sodium sulfur battery  

SciTech Connect

A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another.

Elkins, Perry E. (Santa Ana, CA)

1981-01-01T23:59:59.000Z

348

Glass-like phonon scattering from a spontaneous nanostructure in AgSbTe2  

Science Conference Proceedings (OSTI)

Materials with very low thermal conductivity are of high interest for both thermoelectric and optical phase-change applications. Synthetic nanostructuring is most promising to suppress thermal conductivity by scattering phonons, but challenges remain in producing bulk samples. We show that in crystalline AgSbTe2, a spontaneously-forming nanostructure leads to a suppression of thermal conductivity to a glass-like level. Our mappings of phonon mean-free-paths provide a novel bottom- up microscopic account of thermal conductivity, and also reveal intrinsic anisotropies associated with the nanostructure. Ground-state degeneracy in AgSbTe2 leads to the natural formation of nanoscale domains with different orderings on the cation sublattice, and correlated atomic displacements, which efficiently scatter phonons. This mechanism is general and points to a new avenue in nano- scale engineering of materials, to achieve low thermal conductivities for efficient thermoelectric converters and phase-change memory devices.

Abernathy, Douglas L [ORNL; Ehlers, Georg [ORNL; Huq, Ashfia [ORNL; Ma, Jie [ORNL; May, Andrew F [ORNL; McGuire, Michael A [ORNL; Sales, Brian C [ORNL; Delaire, Olivier A [ORNL; Hong, Tao [ORNL; Tian, Wei [ORNL

2013-01-01T23:59:59.000Z

349

Mid-infrared InAs/AlGaSb superlattice quantum-cascade lasers  

SciTech Connect

We report on the demonstration of mid-infrared InAs/AlGaSb superlattice quantum-cascade lasers operating at 10 {mu}m. The laser structures are grown on n-InAs (100) substrate by solid-source molecular-beam epitaxy. An InAs/AlGaSb chirped superlattice structure providing a large oscillator strength and fast carrier depopulation is employed as the active part. The observed minimum threshold current density at 80 K is 0.7 kA/cm{sup 2}, and the maximum operation temperature in pulse mode is 270 K. The waveguide loss of an InAs plasmon waveguide is estimated, and the factors that determine the operation temperature are discussed.

Ohtani, K.; Fujita, K.; Ohno, H. [Laboratory for Nanoelectronics and Semiconductor Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai (Japan)

2005-11-21T23:59:59.000Z

350

Time resolved magneto-optical studies of ferromagnetic InMnSb films  

SciTech Connect

We report time resolved magneto-optical measurements in InMnSb ferromagnetic films with 2% and 2.8% Mn contents grown by low temperature molecular beam epitaxy. In order to probe a possible interaction between the spins of photoexcited carriers and the Mn ions, we measured spin dynamics before and after aligning the Mn ions by applying an external magnetic field at temperatures above and below the samples' Curie temperatures. We observed no significant temperature or magnetic field dependence in the relaxation times and attribute the observed dynamics entirely to the relaxation of photoexcited electrons in the conduction band where the s-d coupling with the localized Mn ions is significantly weaker compared to the p-d exchange coupling. We observed several differences in the optical response of our InMnSb samples which could have been influenced mainly by the samples' growth conditions.

Frazier, M.; Kini, R. N.; Nontapot, K.; Khodaparast, G. A. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Wojtowicz, T. [Institute of Physics, Polish Academy of Sciences 02-668 Warsaw (Poland); Liu, X.; Furdyna, J. K. [Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

2008-02-11T23:59:59.000Z

351

Relating x-ray attenuation measurements to water content and distribution in SB-15D core  

DOE Green Energy (OSTI)

Making improved estimates of the water content of The Geysers reservoir is fundamental to efficient and economic long term production of steam power from the resource. A series of coordinated physical properties measurements form core recovered from the SB-15D, reported in this volume in a series of papers, have been made to better understand water storage and to relate water content and distribution to observable geophysical properties such as electrical conductivity and seismic velocities. A principal objective here is to report new interpretations of x-ray scans made within 72 hours of core recovery from SB-15D, which suggest, taking advantage of preliminary measurements of capillary suction for metagraywacke, that water content was low in much of the preserved core.

Bonner, B.P.; Roberts, J.J.; Schneberk, D.J

1996-09-30T23:59:59.000Z

352

Type-I superconductivity in YbSb2 single crystals  

SciTech Connect

We present evidence of type-I superconductivity in YbSb2 single crystals from dc and ac magnetization, heat capacity, and resistivity measurements. The critical temperature and critical field are determined to be Tc? 1.3 K and Hc? 55 Oe. A small Ginzburg-Landau parameter ?= 0.05, together with typical magnetization isotherms of type-I superconductors, small critical field values, a strong differential paramagnetic effect signal, and a field-induced change from second- to first-order phase transition, confirms the type-I nature of the superconductivity in YbSb2. A possible second superconducting state is observed in the radio-frequency susceptibility measurements, with Tc(2)? 0.41 K and Hc(2)? 430 Oe.

Zhao, Liang L.; Lausberg, Stefan; Kim, Hyunsoo; Tanatar, Makariy A.; Brando, Manuel; Prozorov, Ruslan; Morosan, E.

2012-06-25T23:59:59.000Z

353

Subpicosecond spin relaxation in GaAsSb multiple quantum wells K. C. Hall,a)  

E-Print Network (OSTI)

Subpicosecond spin relaxation in GaAsSb multiple quantum wells K. C. Hall,a) S. W. Leonard, and H quantum wells are measured at 295 K using time-resolved circular dichroism induced by 1.5 m, 100 fs pulses times shorter than those in InGaAs and InGaAsP wells with similar band gaps. The shorter relaxation

Van Driel, Henry M.

354

Elastic Properties of the Zintl Ferromagnet Yb14MnSb11  

SciTech Connect

We report measurements of the elastic moduli as a function of temperature (5-300) K and magnetic field (0-2 T) for the Zintl ferromagnet Yb{sub 14}MnSb{sub 11}, which is believed to be a rare example of an underscreened Kondo lattice. The elastic moduli measured below the Curie temperature in this complex ferromagnet exhibit unusual lattice stiffening that is independent of the magnetic field and can be adequately modeled using the Landau theory.

Bhattacharya, Sriparna [University of Tennessee, Knoxville (UTK); Marinescu, D. C. [Clemson University; Morris, James R [ORNL; Sergienko, Ivan A [ORNL; Sales, Brian C [ORNL; Mandrus, D. [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL); Keppens, V. [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

355

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures  

SciTech Connect

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated.

Khan, M. Rashid (Morgantown, WV)

1990-01-01T23:59:59.000Z

356

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures  

DOE Patents (OSTI)

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated. 7 figs.

Khan, M.R.

1989-05-12T23:59:59.000Z

357

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents (OSTI)

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas for further combustion in modified oil or gas fired furnaces or boilers. Two concentric shells define a combustion volume within the inner shell and a plenum between them through which combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, Albert H. (Huntington, NY)

1983-10-04T23:59:59.000Z

358

Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment  

Science Conference Proceedings (OSTI)

Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energy release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.

Chen, C.C.; Lee, W.J.; Shih, S.I.; Mou, J.L. [National Cheng Kung University, Tainan (Taiwan). Dept. of Environmental Engineering

2009-07-01T23:59:59.000Z

359

INHIBITION OF WASHED SLUDGE WITH SODIUM NITRITE  

SciTech Connect

This report describes the results of electrochemical tests used to determine the relationship between the concentration of the aggressive anions in washed sludge and the minimum effective inhibitor concentration. Sodium nitrate was added as the inhibitor because of its compatibility with the DWPF process. A minimum of 0.05M nitrite is required to inhibit the washed sludge simulant solution used in this study. When the worst case compositions and safety margins are considered, it is expected that a minimum operating limit of nearly 0.1M nitrite will be specified. The validity of this limit is dependent on the accuracy of the concentrations and solubility splits previously reported. Sodium nitrite additions to obtain 0.1M nitrite concentrations in washed sludge will necessitate the additional washing of washed precipitate in order to decrease its sodium nitrite inhibitor requirements sufficiently to remain below the sodium limits in the feed to the DWPF. Nitrite will be the controlling anion in "fresh" washed sludge unless the soluble chloride concentration is about ten times higher than predicted by the solubility splits. Inhibition of "aged" washed sludge will not be a problem unless significant chloride dissolution occurs during storage. It will be very important tomonitor the composition of washed sludge during processing and storage.

Congdon, J.; Lozier, J.

2012-09-25T23:59:59.000Z

360

Development of New Industrial Ashalloy Material Using Fly Ash Cenospheres "Lead-Lite" Project  

Science Conference Proceedings (OSTI)

One potential high-value utilization method for power plant fly ash is to mix it with an alloy to make a metal matrix composite. In the case of this project, the fly ash is mixed with lead to make a composite with low density and improved hardness. This new material can be used in the auto industry to make lighter battery components. This report describes the results of corrosion tests of several lead samples and lead-fly ash composite samples at room temperature for more than 1500 days. This long-term d...

1999-11-10T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Salt-soda sinter process for recovering aluminum from fly ash  

DOE Patents (OSTI)

A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na.sub.2 CO.sub.3 to a temperature in the range 700.degree.-900.degree. C. for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acid-soluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

1981-01-01T23:59:59.000Z

362

Devolatilization and ash comminution of two different sewage sludges under fluidized bed combustion conditions  

Science Conference Proceedings (OSTI)

Two different wet sewage sludges have been characterized under fluidized bed combustion conditions with reference to their devolatilization behavior and ash comminution with the aid of different and complementary experimental protocols. Analysis of the devolatilization process allowed to determine the size of fuel particle able to achieve effective lateral spreading of the volatile matter across the cross-section of medium-scale combustors. Primary fragmentation and primary ash particle characterization pointed out the formation of a significant amount of relatively large fragments. The mechanical properties of these fragments have been characterized by means of elutriation/abrasion tests using both quartz and sludge ash beds. (author)

Solimene, R.; Urciuolo, M.; Cammarota, A.; Chirone, R. [Istituto di Ricerche sulla Combustione (IRC) - CNR, Napoli (Italy); Salatino, P. [Istituto di Ricerche sulla Combustione (IRC) - CNR, Napoli (Italy); Dipartimento di Ingegneria Chimica Universita degli Studi di Napoli Federico II, Napoli (Italy); Damonte, G.; Donati, C.; Puglisi, G. [ECODECO Gruppo A2A, Giussago (PV) (Italy)

2010-04-15T23:59:59.000Z

363

PROGRAM TOPIC: GASIFICATION TECHNOLOGIES PREVENTING AGGLOMERATION PROBLEMS DURING GASIFICATION OF HIGH-SODIUM LIGNITE  

E-Print Network (OSTI)

Previous gasification studies have shown that sodium vapor released from high-sodium lignites can react with silica to form sticky sodium silicates. 1,2,3

Robert S. Dahlin; Johnny R. Dorminey; Southern Company Services; Wanwang Peng; Southern Company Services; Pannalal Vimalch; Southern Company Services

2008-01-01T23:59:59.000Z

364

The electrical conductivity of sodium polysulfide melts  

DOE Green Energy (OSTI)

The sodium polysulfide melt has been described by a macroscopic model. This model considers the melt to be composed of sodium cations, monosulfide anions, and neutral sulfur solvent. The transport equations of concentrated-solution theory are used to derived the governing equations for this binaryelectrolyte melt model. These equations relate measurable transport properties to fundamental transport parameters. The focus of this research is to measure the electrical conductivity of sodium polysulfide melts and calculate one of fundamental transport parameters from the experimental data. The conductance cells used in the conductivity measurements are axisymmetric cylindrical cells with a microelectrode. The electrode effects, including double-layer capacity, charge transfer resistance, and concentration overpotential, were minimized by the use of the alternating current at an adequately high frequency. The high cell constants of the conductance cells not only enhanced the experimental accuracy but also made the electrode effects negligible. The electrical conductivities of sodium polysulfide Na{sub 2}S{sub 4} and Na{sub 2}S{sub 5} were measured as a function of temperature (range: 300 to 360{degree}C). Variations between experiments were only up to 2%. The values of the Arrhenius activation energy derived from the experimental data are about 33 kJ/mol. The fundamental transport parameter which quantifies the interaction within sodium cations and monosulfide anions are of interest and expected to be positive. Values of it were calculated from the experimental conductivity data and most of them are positive. Some negative values were obtained probably due to the experimental errors of transference number, diffusion coefficient, density or conductivity data.

Meihui Wang

1992-06-01T23:59:59.000Z

365

Viscosity and density tables of sodium chloride solutions  

DOE Green Energy (OSTI)

A file is presented containing tabulated data extracted from the scientific literature on the density and viscosity of aqueous sodium chloride solutions. Also included is a bibliography of the properties of aqueous sodium chloride solutions. (MHR)

Fair, J.A.; Ozbek, H. (comps.) [comps.

1977-04-01T23:59:59.000Z

366

Structure and Properties of Piezoelectric Sodium Bismuth Titanate ...  

Science Conference Proceedings (OSTI)

Presentation Title, Structure and Properties of Piezoelectric Sodium Bismuth Titanate ... Nanostructures and Their Potential for Mechanical Energy Scavenging.

367

Sodium and sulfur release and recapture during black liquor burning  

DOE Green Energy (OSTI)

The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

1995-08-01T23:59:59.000Z

368

Apparatus having inductively coupled coaxial coils for measuring buildup of slay or ash in a furnace  

DOE Patents (OSTI)

The buildup of slag or ash on the interior surface of a furnace wall is monitored by disposing two coils to form a transformer which is secured adjacent to the inside surface of the furnace wall. The inductive coupling between the two coils of the transformer is affected by the presence of oxides of iron in the slag or ash which is adjacent to the transformer, and the application of a voltage to one winding produces a voltage at the other winding that is related to the thickness of the slag or ash buildup on the inside surface of the furnace wall. The output of the other winding is an electrical signal which can be used to control an alarm or the like or provide an indication of the thickness of the slag or ash buildup at a remote location.

Mathur, Mahendra P. (Pittsburgh, PA); Ekmann, James M. (Bethel Park, PA)

1989-01-01T23:59:59.000Z

369

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains  

Open Energy Info (EERE)

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains 2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: 2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Details Activities (0) Areas (0) Regions (0) Abstract: Diverse latest Pliocene volcanic and plutonic rocks in the north-central Caucasus Mountains of southern Russia are newly interpreted as components of a large caldera system that erupted a compositionally zoned rhyolite-dacite ash-flow sheet at 2.83 ± 0.02 Ma (sanidine and biotite 40Ar/39Ar). Despite its location within a cratonic collision zone, the Chegem system is structurally and petrologically similar to typical

370

Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility | Open  

Open Energy Info (EERE)

Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Facility Hunt's Ash Springs Sector Geothermal energy Type Pool and Spa Location Hiko, Nevada Coordinates Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

371

Kinetics of fly ash beneficiation by carbon burnout. Quarterly report, October 1996--December 1996  

Science Conference Proceedings (OSTI)

The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called {open_quotes}Loss On Ignition{close_quotes} (LOI). The concrete producer`s day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

Dodoo, J.N.; Okoh, J.M.; Diaz, A. [and others

1997-06-01T23:59:59.000Z

372

STATE-OF-THE-ART: FLY ASH, SILICA FUME AND SLAG UTILIZATION IN USA  

E-Print Network (OSTI)

Backfill. 1.0 Introduction At the present time, coal fired electric power plants in the USA produce, ease of handling, and moisture insensitivity, etc. [2,11]. 2.1.2 Backfills Fly ash is used

Wisconsin-Milwaukee, University of

373

Smyrna's Ashes: Humanitarianism, Genocide, and the Birth of the Middle East  

E-Print Network (OSTI)

burning of the city of Izmir, Smyrna’s Ashes is an importantof Smyrna came a new city, Izmir, and a new Turkish nation.Gardens (Kensington), 165 Izmir, 1 Index / 249 Jerusalem, 67

Tusan, Michelle

2012-01-01T23:59:59.000Z

374

M-2: Extracting Alumina from Coal Fly Ash with Ammonium Sulfate ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The whole process of extracting alumina from coal fly ash ... Decrease of Heat Consumption at Nepheline Processing to Alumina and By- Products ... Flash -and CFB Calciners, History and Difficulties of Development of Two ...

375

The potential for use of waste-to-energy facility ash: Executive summary. Final report  

DOE Green Energy (OSTI)

This executive summary presents an overview of the investigations, findings, conclusions, and recommendations of the Long Island Regional Planning Board (LIRPB) study of the Potential for Beneficial Use of Waste-to-Energy Facility Ash. The full report consists of the following volumes: Executive Summary; Volume 1: Long Island Ash Management Status; Volume 2: Sampling and Testing Procedures; Volume 3: Environmental Properties; Volume 4: Engineering Properties; Volume 5: Environmental Assessment; Volume 6: Engineering and Economic Evaluation; and Volume 7: Legal and Institutional Issues. Volumes one through seven are briefly summarized in this executive summary with the exception of Volume 2 of the report, which serves as the documentation of the sampling conditions and testing methods used in measuring chemical and physical properties of the ash tested. The study investigated the feasibility of the use of incinerator ash as a substitute for natural aggregate in construction applications.

Koppelman, L.E.; Tanenbaum, E.G. [Long Island Regional Planning Board, Hauppauge, NY (United States)

1994-05-01T23:59:59.000Z

376

Recovery of Metal Oxides From Fly Ash, Volumes 1-3  

Science Conference Proceedings (OSTI)

By processing fly ash to obtain metal oxides and other commercial products, utilities can realize both sales revenues and reduced disposal costs. A commercial-scale processing plant could be ready for demonstration by 1992.

1984-06-01T23:59:59.000Z

377

Application of advanced technologies to ash-related problems in boilers  

DOE Green Energy (OSTI)

Prediction of ash behavior in boilers has, for many years, been based on relatively simple relationships involving the composition of inorganic material in fuels. In recent years, advanced analyses for both fuels and deposits have seen increasing use in the solid fuel combustion community. The combination of the standard and advanced analyses, together with a knowledge of boiler design and operating conditions, allow better interpretation of ash behavior in boilers than has previously been possible. This paper discusses several case histories where advanced technologies have been applied to interpret ash behavior in boilers where standard techniques were insufficient. Included in the discussion are: (1) the behavior of blends of fuels; (2) explanations for markedly different behavior between fuels with similar ASTM characteristics; and (3) effects of boiler operating conditions on ash deposit formation.

Baxter, L.L. (Sandia National Labs., Livermore, CA (United States). Combustion Research Facility); Richards, G.; Harb, J. (Brigham Young Univ., Provo, UT (United States). Chemical Engineering Dept.)

1994-01-01T23:59:59.000Z

378

Removal of radium from acidic solutions containing same by adsorption on coal fly ash  

DOE Patents (OSTI)

The invention is a process for the removal of radium from acidic aqueous solutions. In one aspect, the invention is a process for removing radium from an inorganic-acid solution. The process comprises contacting the solution with coal fly ash to effect adsorption of the radium on the ash. The radium-containing ash then is separated from the solution. The process is simple, comparatively inexpensive, and efficient. High radium-distribution coefficients are obtained even at room temperature. Coal fly ash is an inexpensive, acid-resistant, high-surface-area material which is available in large quantities throughout the United States. The invention is applicable, for example, to the recovery of .sup.226 Ra from nitric acid solutions which have been used to leach radium from uranium-mill tailings.

Scheitlin, Frank M. (Oak Ridge, TN)

1984-01-01T23:59:59.000Z

379

The use of oil shale ash in the production of biodiesel from waste vegetable oil  

Science Conference Proceedings (OSTI)

Oil shale ash obtained from combustion of local oil shale deposits was used in this study as a heterogeneous catalyst to produce biodiesel from waste vegetable oil (WVO). Two alcohols with high and low boiling points

A. Al-Otoom; M. Allawzi; A. Ajlouni; F. Abu-Alrub; M. Kandah

2012-01-01T23:59:59.000Z

380

Utilizing fly ash particles to produce low-cost metal matrix composites  

Science Conference Proceedings (OSTI)

Metal matrix composites (MMCs) are a blend of fine ceramic particles mixed with metals such as aluminium or magnesium. Fly ash is considerably cheaper than ceramics; aluminium-fly ash composites cost less than 60% of conventional aluminium-SiC composites making them attractive to automakers striving for lower weight and cheaper materials for brake rotors or brake drums. Ultalite.com has consulted with US researchers to to find the optimum requirements of the fly ash needed to make MMCs. Particle size 20-40 microns, low calcium oxide content and spherical particles were identified. The desired particles once extracted are stirred into molten aluminum and the resulting composite is into ingots for shipment to a casting facility. Dynamometer testing has shown that aluminium-fly ash composite brake drums have better performance and wear than cast iron drums. 6 figs., 1 tab.

Withers, G. [Ultalite.com, Melbourne, Vic. (Australia)

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Lubricant-derived ash : in-engine sources and opportunities for reduction  

E-Print Network (OSTI)

Diesel particulate filters (DPF) are an effective means for meeting increasingly stringent emissions regulations that limit particulate matter. Over time, ash primarily derived from metallic additives in the engine oil ...

Watson, Simon A. G. (Simon Andrew Glean)

2010-01-01T23:59:59.000Z

382

An Advanced System to Monitor the 3D Structure of Diffuse Volcanic Ash Clouds  

Science Conference Proceedings (OSTI)

Major disruptions of the aviation system from recent volcanic eruptions have intensified discussions about and increased the international consensus toward improving volcanic ash warnings. Central to making progress is to better discern low ...

J.-P. Vernier; T. D. Fairlie; J. J. Murray; A. Tupper; C. Trepte; D. Winker; J. Pelon; A. Garnier; J. Jumelet; M. Pavolonis; A. H. Omar; K. A. Powell

2013-09-01T23:59:59.000Z

383

CHEMICALLY BONDED CEMENTS FROM BOILER ASH AND SLUDGE WASTES. PHASE I REPORT AUGUST 1997 - JULY 1998  

Science Conference Proceedings (OSTI)

In exploring methods to recycle boiler ash (BA) and waste water treatment sludge (WWTS), by-products generated from Keyspan's power plants, into commercially viable materials, we synthesized chemically bonded cements (CBC) offering the following three specific characteristics; (1) immobilization of hazardous heavy metals, such as Pb, Ni, and V, (2) rapid hardening and setting properties, and (3) development of high mechanical strength. The CBCs were prepared through an acid-base reaction between these by-products acting as the solid base reactants and the sodium polyphosphate solution as the cement-forming acid reactant, followed by a hydrating reaction. Furthermore, two additives, the calcium aluminate cements (CAC) and the calcium silicate cements (CSC) were incorporated into the CBC systems to improve their properties. Using a CBC formulation consisting of 53.8 wt% WWTS, 23.1 wt% CSC, and 23.1 wt% [40 wt% -(-NaPO{sub 3}-)-{sub n}]{sub 2} the Toxicity Characteristics Leaching Procedure (TCLP) tests showed that the concentrations of Pb, Ni, and V metals leached out from the specimens were minimal. This formulation originally contained {approx} 28800 mg/kg of Pb, {approx} 6300 mg/kg of Ni, and {approx} 11130 mg/kg of V; the amounts leaching into the acid extraction fluid were only 0.15 mg/L of Pb, 0.15 mg/L of Ni, and 4.63 mgiL of V. On the other hand, CBC specimens derived from a formulation consisting of 42 wt% BA, 18 wt% CAC and 40 wt% [40 wt% -(-NaPO{sub 3}-)-{sub n}] displayed an excellent compressive strength of 10.8 MPa at an early curing age of 2 hours after mixing at room temperature. The reason for its rapid hardening was due to a high exothermic energy evolved by the acid-base reaction. Furthermore, when these specimens were immersed for 28 days in water at 25 C, and exposed for 20 hours to steam at 80 C, a very high compressive strength of 3.32 MPa developed. Two physico-chemical factors played an important role in improving the mechanical strength of the specimens: One was the formation of two well-crystallized phases, hydroxyapatite [Ca{sub 5}(PO{sub 4}){sub 3}(OH)] and sodium vanadium sulfate hydrate [Na{sub 2}V(SO{sub 4}){sub 2},4H{sub 2}O], as the reaction products in the cement bodies; the other factor reflected the dense microstructure developed by the growth of these crystalline reaction products. Accordingly, the CBCs derived from these by-products have a high potential for use as remediating material for hazardous heavy metal-contaminated soils, as rapid-setting repair patching and filling materials for damaged roadways and bridge decks, and also as binders in precast concrete products, such as blocks, slabs, and pipes.

SUGAMA,T.; YAGER,K.A.

2002-08-05T23:59:59.000Z

384

Corrosion performance of advanced structural materials in sodium.  

SciTech Connect

This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L. (Nuclear Engineering Division)

2012-05-16T23:59:59.000Z

385

The use of sulfer modified bottom ash (SMBA) as an aggregate in asphaltic mixtures  

E-Print Network (OSTI)

Of the 20 million tons of bottom ash and boiler slag generated annually in the United States less than 40 percent is used. The eastern half of Texas is served by 18 coal burning electric power generating plants which produce approximately 3.8 million tons of bottom ash each year. This is also the section of the state in which the sources of quality aggregates are either few. dwindling or nonexistent. While a small fraction of the bottom ash is utilized, the rest is delegated to landfills or on-site disposal areas. Increasing attention is being given to development of new, high-volume uses for this safe and readily available by-product. One such use is as an aggregate in road construction. The use of bottom ash as an aggregate for both roadway surfaces and base courses has been limited due to its absorbency and friability. The former tends to increase asphalt binder demand while the latter adversely affects its ability to withstand the crushing effects of traffic loads. On the other hand, bottom ash is lighter in weight and generally much cheaper than conventional quality aggregates such as limestone, sand and gavel. This research was designed to up-firade the load-bearing characteristics of bottom ash and maximize its use 'in asphaltic concrete roadway mixtures through the use of sulfur. The process essentially coats the ash with liquid sulfur which upon cooling fills the voids on the surface of the particles while increasing their crush resistance. The results of this investigation indicate that asphaltic concrete mix designs in which bottom ash represents from 5 0 to I 00 percent of the aggregate fraction can be achieved.

Chimakurthy, Harshavardhan

1998-01-01T23:59:59.000Z

386

Mitigation of SCR-Ammonia Related Aqueous Effects in a Fly Ash Pond  

Science Conference Proceedings (OSTI)

Contaminated fly ash resulting from secondary injection of ammonia to mitigate SO3 produced by a selective catalytic reduction (SCR) system altered the water quality of a fly ash pond at a coal-fired power generation station. This project attempted to improve water quality by encouraging the growth of algae in the pond to remove ammonia, while keeping other important parameters (pH, total suspended solids, Biological Oxygen Demand, and metals) within allowable limits.

2006-02-07T23:59:59.000Z

387

Field Test of a Semi-Continuous Fly Ash Unburned Carbon Monitor: Cyclone Boiler Application  

Science Conference Proceedings (OSTI)

Unburned carbon (UBC) is the measure of the carbon level in the fly ash of a coal-fired boiler—with increased carbon indicating less-complete and less-efficient combustion. Boiler design is one important factor that affects UBC levels. Cyclone boilers burn coal at high combustion temperatures (ca. 1650°C) and exhibit relatively high, but quite variable, fly ash UBC levels. Recently, because of competitive fuel pricing and reduced SO2 and NOX emissions, cyclone boilers ...

2013-12-17T23:59:59.000Z

388

Program on Technology Innovation: Formation of Large Particle Ash in Coal-Fired Boilers  

Science Conference Proceedings (OSTI)

The objective of this project was to obtain a better understanding of the process that underlies the formation of large particle ash (LPA) in coal-fired boilers. As an approach, sample sets of coal, fireside ash deposits, and LPA were collected from selected boilers identified by the Electric Power Research Institute (EPRI) and were characterized using scanning electron microscopy (SEM) and x-ray microanalysis techniques. The coals were characterized to determine the abundance, size, and composition of t...

2010-02-08T23:59:59.000Z

389

Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes  

SciTech Connect

There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with fly ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.

Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Skilbeck, C.G. [University of Technology Sydney, Sydney, NSW (Australia). Dept. of Environmental Science

2009-07-15T23:59:59.000Z

390

The Laconia, New Hampshire bottom ash paving project: Volume 3, Physical Performance Testing Report  

SciTech Connect

Bottom ash is the principal waste stream from the combustion of municipal solid waste (MSW). It is comprised of grate ash (97%), the slag material discharged at the end of the grate system, and grate sifting (3%), the material that melts or falls through the grate structure. This project was conducted to demonstrate the feasibility of using municipal solid waste grate ash as an aggregate substitute in the construction of a pavement binder course for a portion of Rt. 3 in Laconia, New Hampshire. The research was conducted over a two year period during 1993 and 1994. This study is the culmination of an earlier two year characterization study between 1990 and 1992 that documented the physical and environmental characteristics of the bottom ash as it was produced at the Concord, N.H. waste-to-energy (@) facility and used in an asphaltic binder course. Together, these two studies provide a complete evaluation of the potential for using grate ash or bottom ash in asphalt binder course or as recycled asphalt pavement (RAP) in base courses in pavements.

NONE

1996-03-01T23:59:59.000Z

391

Large-scale sodium spray fire code validation (SOFICOV) test  

Science Conference Proceedings (OSTI)

A large-scale, sodium, spray fire code validation test was performed in the HEDL 850-m/sup 3/ Containment System Test Facility (CSTF) as part of the Sodium Spray Fire Code Validation (SOFICOV) program. Six hundred fifty eight kilograms of sodium spray was sprayed in an air atmosphere for a period of 2400 s. The sodium spray droplet sizes and spray pattern distribution were estimated. The containment atmosphere temperature and pressure response, containment wall temperature response and sodium reaction rate with oxygen were measured. These results are compared to post-test predictions using SPRAY and NACOM computer codes.

Jeppson, D.W.; Muhlestein, L.D.

1985-01-01T23:59:59.000Z

392

Evaluation of potential risks from ash disposal site leachate  

SciTech Connect

A risk-based approach is used to evaluate potential human health risks associated with a discharge from an ash disposal site into a small stream. The RIVRISK model was used to estimate downstream concentrations and corresponding risks. The modeling and risk analyses focus on boron, the constituent of greatest potential concern to public health at the site investigated, in Riddle Run, Pennsylvania. Prior to performing the risk assessment, the model is validated by comparing observed and predicted results. The comparison is good and an uncertainty analysis is provided to explain the comparison. The hazard quotient (HQ) for boron is predicted to be greater than 1 at presently regulated compliance points over a range of flow rates. The reference dose (RfD) currently recommended by the United States Environmental Protection Agency (US EPA) was used for the analyses. However, the toxicity of boron as expressed by the RfD is now under review by both the U.S. EPA and the World Health Organization. Alternative reference doses being examined would produce predicted boron hazard quotients of less than 1 at nearly all flow conditions.

Mills, W.B.; Loh, J.Y.; Bate, M.C.; Johnson, K.M. [Tetra Tech, Lafayette, CA (United States)] [Tetra Tech, Lafayette, CA (United States)

1999-04-01T23:59:59.000Z

393

Fibrous Fillers to Manufacture Ultra High Ash/Performance Paper  

SciTech Connect

The paper industry is one of the largest users of energy and emitters of CO2 in the US manufacturing industry. In addition to that, it is facing tremendous financial pressure due to lower cost imports. The fine paper industry has shrunk from 15 million tons per year production to 10 million tons per year in the last 5 years. This has resulted in mill closures and job loses. The AF&PA and the DOE formed a program called Agenda 2020 to help in funding to develop breakthrough technologies to provide help in meeting these challenges. The objectives of this project were to optimize and scale-up Fibrous Fillers technology, ready for commercial deployment and to develop ultra high ash/high performance paper using Fibrous Fillers. The goal was to reduce energy consumption, carbon footprint, and cost of manufacturing paper and related industries. GRI International (GRI) has been able to demonstrate the techno - economic feasibility and economic advantages of using its various products in both handsheets as well as in commercial paper mills. GRI has also been able to develop sophisticated models that demonstrate the effect of combinations of GRI's fillers at multiple filler levels. GRI has also been able to develop, optimize, and successfully scale-up new products for use in commercial paper mills.

Dr. VIjay K. Mathur

2009-04-30T23:59:59.000Z

394

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. Piping in the east boiler basement of the sodium processing building was color coded for easy identification. Orange indicates sodium and green identifies cooling water.

395

Sodium Plugging Test Loop - Nuclear Engineering Division (Argonne)  

NLE Websites -- All DOE Office Websites (Extended Search)

Sodium Plugging Test Loop Sodium Plugging Test Loop Sodium Plugging Test Loop Overview Other Facilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sodium Plugging Test Loop This experimental setup is part of the Global Nuclear Energy Partnership (GNEP) Advanced Fuel Cycle R&D work carried out at Argonne on advanced sodium component technology. Bookmark and Share For long range sodium technology research and development, employing supercritical CO2 Brayton cycle power conversion technology as an advanced balance of plant technology is being considered. The component that provides the interface between the sodium and supercritical CO2 is a compact heat exchanger known as a printed circuit heat exchanger (PCHE). This heat exchanger has very small coolant flow passages that may foul or

396

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Obtains Patent for Nuclear Reactor Sodium Cleanup Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. Piping in the east boiler basement of the sodium processing building was color coded for easy identification. Orange indicates sodium and green identifies cooling water.

397

Low-Pressure Sodium Lighting Basics | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Low-Pressure Sodium Lighting Basics Low-Pressure Sodium Lighting Basics Low-Pressure Sodium Lighting Basics August 16, 2013 - 10:17am Addthis Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color rendition. Typical applications include highway and security lighting, where color is not important. Low-pressure sodium lamps work somewhat like fluorescent lamps. Like high-intensity discharge lighting, low-pressure sodium lamps require up to 10 minutes to start and have to cool before they can restart. Therefore, they are most suitable for applications in which they stay on for hours at a time. They are not suitable for use with motion detectors. The chart below compares low-pressure sodium lamps and high-intensity

398

Tool development and application: pressure, temperature, spectral gamma ray logging of the SB-15 well  

DOE Green Energy (OSTI)

Sandia`s involvement with downhole instrumentation dates from the mid 1970s when work was centered on the development of a high-temperature acoustic borehole televiewer, and the establishment of a list of high- temperature component parts such as resistors, integrated circuits, and sensors. This work evolved into the development of memory logging devices for the US Continental Scientific Drilling Program. These tools were of low cost and very easy to use. Their deployment resulted in scientific advancement in understanding geothermal formations, and a thrust of the current program is to move memory tools from the scientific realm to the commercial environment. The tools developed and utilized in the SB-15 well among other field tests are completely self- contained in that power is obtained from batteries and data are stored in an electronic memory system. Three memory tools form the backbone of the initial Sandia tool suite. Pressure/temperature measurements are necessary for the evaluation of geothermal reservoirs, and they are relatively simple to make. Thus, the initial Sandia program concentrated on such a tool, and it has been successfully used in SB-15. This tool will form the basis for future tools since many engineering principles were proven in its evolution. This pressure/temperature tool combination is very useful in characterizing the geothermal reservoir. Another tool in the Sandia suite measures the natural gamma rays from the formation. This spectral gamma ray tool is useful in defining lithology, paleoflows, and certain clays. SB-15 well logging history and a preliminary interpretation of the data is presented in this report.

Sattler, A.R.; Norman, R.; Henfling, J.A.

1996-12-01T23:59:59.000Z

399

Pairing phenomenon in doubly odd neutron rich {sup 136}Sb nucleus  

Science Conference Proceedings (OSTI)

Based on p-n and n-n pairing gap energies giving by K. Kaneko et al. (2003), we make modifications on the kh5082 interaction. Calculations and study of some nuclear properties for {sup 136}Sb nucleus are developed in the framework of the nuclear shell model by means of OXBASH structure code. We get the same energetic sequence as the recent experimental values of single particle energies. The effective charge values e{sub p}=1.35e and e{sub n}=0.9e, and factors given by V. I. Isakov are used to evaluate multipole electromagnetic moments.

Laouet, N.; Benrachi, F. [Laboratoire de Physique Mathematique et Subatomique Mentouri University, Constantine (Algeria)

2012-06-27T23:59:59.000Z

400

Grain refinement and texture development of cast bi90sb10 alloy via severe plastic deformation  

E-Print Network (OSTI)

The purpose of this work was to study learn about grain refinement mechanisms and texture development in cast n-type Bi90Sb10 alloy caused by severe plastic deformation. The practical objective is to produce a fine grained and textured microstructure in Bi90Sb10 alloy with enhanced thermoelectric performance and mechanical strength. In the study, twelve millimeter diameter cast bars of Bi90Sb10 alloy were encapsulated in square cross section aluminum 6061 alloy containers. The composite bars were equal channel angular (ECAE) extruded through a 90 degree angle die at high homologous temperature. Various extrusion conditions were studied including punch speed (0.1, 0.3 and 0.6 in/min), extrusion temperature (220, 235 and 250oC), number of extrusion passes (1, 2 and 4), route (A, BC and C), and exit channel area reduction ratio (half and quarter area of inlet channel). The affect of an intermediate long term heat treatment (for 100 hours at 250oC under 10-3 torr vacuum) was explored. Processed materials were characterized by optical microscopy, x-ray diffraction, energy dispersive spectroscopy, wavelength dispersive spectroscopy and scanning electron microscopy. Texture was analyzed using the {006} reflection plane to identify the orientation of the basal poles in processed materials. The cast grains were irregularly shaped, had a grain size of hundreds-of-microns to millimeters, and showed inhomogeneous chemical composition. Severe plastic deformation refines the cast grains through dynamic recrystallization and causes the development of a bimodal microstructure consisting of fine grains (5-30 micron) and coarse grains (50-300 micron). ECAE processing of homogenizied Bi-Sb alloy causes grain refinement and produces a more uniform microstructure. Texture results show that ECAE route C processing gives a similar or slightly stronger texture than ECAE route A processing. In both cases, the basal-plane poles become aligned with the shear direction. Reduction area exit channel extrusion is more effective for both grain refinement and texture enhancement than simple ECAE processing.

Im, Jae-taek

2007-05-01T23:59:59.000Z

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401

Growth of an {alpha}-Sn film on an InSb(111) A-(2x2) surface  

Science Conference Proceedings (OSTI)

We have investigated the initial growth process of {alpha}-Sn films on the In-terminated InSb(111)A-(2x2) surface using low-energy electron diffraction (LEED) and high-resolution core-level photoelectron spectroscopy. Taking the LEED observation and the Sn coverage-dependent integrated intensities of the In 4d, Sb 4d, and Sn 4d core-level spectra into account, we conclude that the {alpha}-Sn film grows epitaxially by a bilayer mode and that there is no interdiffusion of the substrate atoms as suggested in the literature. Furthermore, the coverage-dependent In 4d and Sn 4d core levels indicate that the In vacancy site of InSb(111)A-(2x2) surface is not the preferable Sn absorption site.

Kondo, Daiyu; Sakamoto, Kazuyuki; Shima, Masahide; Takeyama, Wakaba [Department of Physics, Graduate School of Science, Tohoku University, Sendai 980-8578 (Japan); Nakamura, Kenya; Ono, Kanta; Oshima, Masaharu [Department of Applied Chemistry, Graduate School of Engineering, University of Tokyo, Tokyo 113-0033 (Japan); Kasukabe, Yoshitaka [Department of Electronic Engineering/International Student Center, Tohoku University, Sendai 980-8578 (Japan)

2004-12-15T23:59:59.000Z

402

Trophic structure and metal bioaccumulation differences in multiple fish species exposed to coal ash-associated metals  

Science Conference Proceedings (OSTI)

On December 22, 2008 a dike containing coal fly ash from the Tennessee Valley Authority Kingston Fossil Plant near Kingston Tennessee USA failed and resulted in the largest coal ash spill in U.S. history. Coal ash, the by-product of coal combustion, is known to contain multiple contaminants of concern, including arsenic and selenium. The purpose of this study was to investigate the bioaccumulation of arsenic and selenium and to identify possible differences in trophic dynamics in feral fish at various sites in the vicinity of the Kingston coal ash spill. Elevated levels of arsenic and selenium were observed in various tissues of largemouth bass, white crappie, bluegill and redear sunfish from sites associated with the Kingston coal ash spill. Highest concentrations of selenium were found in redear sunfish with liver concentrations as high as 24.83 mg/kg dry weight and ovary concentrations up to 10.40 mg/kg dry weight at coal ash-associated sites. To help explain the elevated selenium levels observed in redear sunfish, investigations into the gut pH and trophic dynamics of redear sunfish and bluegill were conducted which demonstrated a large difference in the gut physiology between these two species. Redear sunfish stomach and intestinal pH was found to be 1.1 and 0.16 pH units higher than in bluegill, respectively. In addition, fish from coal ash-associated sites showed enrichment of 15N & 13C compared to no ash sites, indicating differences in food web dynamics between sites. These results imply the incorporation of coal ash-associated compounds into local food webs and/or a shift in diet at ash sites compared to the no ash reference sites. Based on these results, further investigation into a broader food web at ash-associated sites is warranted.

Otter, Ryan [Middle Tennessee State University; Bailey, Frank [Middle Tennessee State University; Fortner, Allison M [ORNL; Adams, Marshall [ORNL

2012-01-01T23:59:59.000Z

403

Risk ranking of bioaccessible metals from fly ash dissolved in simulated lung and gut fluids  

Science Conference Proceedings (OSTI)

Power plant fly ash from two fuels, coal and a mixture of coal and shredded tires were evaluated for trace metal solubility in simulated human lung and gut fluids (SLF and SGF, respectively) to estimate bioaccessibility. The proportion of bioaccessible to total metal ranged from zero (V) to 80% (Zn) for coal-derived ash in SLF and from 2 (Th) to 100% (Cu) for tire-derived fly ash in SGF. The tire-derived ash contained much more Zn. However, Zn ranked only 5th of the various toxic metals in SGF compared with international regulations for ingestion. On the basis of total concentrations, the metals closest to exceeding limits based on international regulations for inhalation were Cr, Pb, and Al. On dissolution in SLF, the most limiting metals were Pb, Cu, and Zn. For metals exposed to SGF there was no relative change in the top metal, Al, before and after dissolution but the second-ranked metal shifted from Pb to Ni. In most cases only a proportion of the total metal concentrations in either fly ash was soluble, and hence bioaccessible, in either biofluid. When considering the regulatory limits for inhalation of particulates, none of the metal concentrations measured were as hazardous as the fly ash particulates themselves. However, on the basis of the international ingestion regulations for Al, the maximum mass of fly ash that could be ingested is only 1 mg per day (10 mg based on bioaccessibility). It is possible that such a small mass could be consumed by exposed individuals or groups. 39 refs., 1 fig., 3 tabs.

John Twining; Peter McGlinn; Elaine Loi; Kath Smith; Reto Giere [Australian Nuclear Science and Technology Organisation, Menai, NSW (Australia)

2005-10-01T23:59:59.000Z

404

Report on sodium compatibility of advanced structural materials.  

SciTech Connect

This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T. (Nuclear Engineering Division)

2012-07-09T23:59:59.000Z

405

Super-radiance in the sodium resonance lines from sodium iodide arc lamps  

Science Conference Proceedings (OSTI)

Super-radiance observed within the centers of the sodium resonance D lines emitted by arc lamps containing sodium iodide as additive in a high-pressure mercury plasma environment was studied by high-resolution emission spectroscopy. The spectral radiance of these self-reversed lines including super-radiance was simulated by considering a local enhancement of the source function due to the presence of an additional source of radiation near the arc wall. Causes of this hitherto unrecognized source of radiation are given.

Karabourniotis, D. [Department of Physics, Institute of Plasma Physics, University of Crete, 71003 Heraklion (Greece); Drakakis, E. [Department of Electrical Engineering, Technological Educational Institute, Heraklion (Greece)

2010-08-09T23:59:59.000Z

406

Intersubband Transitions in Narrow InAs/AlSb Quantum Wells D. C. Larrabee, J. Tang, M. Liang, G. A. Khodaparast, J. Kono  

E-Print Network (OSTI)

Intersubband Transitions in Narrow InAs/AlSb Quantum Wells D. C. Larrabee, J. Tang, M. Liang, G. A investigated intersubband transitions (ISBTs) in InAs/AlSb multiple quantum wells with well widths from 2.1 to 10 nm. The ISBT energy increased with decreasing well width and temperature. To explain these well

Kono, Junichiro

407

Electrodeposition of Ni5Sb2 nanowires array and its application as a high-performance anode material for lithium ion batteries  

Science Conference Proceedings (OSTI)

Single crystal Ni"5Sb"2 nanowires array is synthesized by direct-current electrodeposition technique. The initial specific discharge and charge capacity of the as-produced Ni"5Sb"2 nanowires array electrode as an anode material for lithium-ion batteries ... Keywords: Anode, Array structure, Charge/discharge capacity, Lithium-ion batteries, Nanowires

You-Wen Yang; Tian-Ying Li; Fei Liu; Wen-Bin Zhu; Xue-Liang Li; Yu-Cheng Wu; Ming-Guang Kong

2013-04-01T23:59:59.000Z

408

GaSb-based Type-I QW LEDs and addressable arrays operated at wavelengths up to 3.66 m  

E-Print Network (OSTI)

Sb-based quantum wells (QW) light emitting diodes (LED) and LED arrays operating at room temperature at wavelengths. Kipshidze, D.Westerfeld, D. Snyder, M.Johnson, G. Belenky, "GaSb-Based Type I Quantum Well Light Emitting Diode Addressable Array Operated at Wavelengths up to 3.66 µm", IEEE Photonics Technol. Lett. 21, 1087

409

Magnetic order near 270 K in mineral and synthetic Mn{sub 2}FeSbO{sub 6} ilmenite  

SciTech Connect

The structural and magnetic properties of Mn{sub 2}FeSbO{sub 6} single-crystalline mineral and ceramic samples synthesized under thermobaric treatment have been investigated, and compared to theoretical predictions based on first-principles electronic structure calculations. This ilmenite system displays a sharp magnetic transition just below the room temperature related to a ferrimagnetic ordering of the Mn{sup 2+} and Fe{sup 3+} cations, which makes Mn{sub 2}FeSbO{sub 6} a promising candidate for designing functional magnetic materials.

Mathieu, R.; Hudl, M.; Nordblad, P. [Department of Engineering Sciences, Uppsala University, Box 534, SE-75121 Uppsala (Sweden); Ivanov, S. A. [Department of Engineering Sciences, Uppsala University, Box 534, SE-75121 Uppsala (Sweden); Department of Inorganic Materials, Karpov' Institute of Physical Chemistry, Vorontsovo pole, 10 105064, Moscow K-64 (Russian Federation); Bazuev, G. V. [Institute of Solid-State Chemistry, Ural Branch of the Russian Academy of Science, 620999, Ekaterinburg GSP-145 (Russian Federation); Lazor, P. [Department of Earth Sciences, Uppsala University, Villavaegen 16, SE-75236 Uppsala (Sweden); Solovyev, I. V. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

2011-05-16T23:59:59.000Z

410

Design and fabrication of 6.1-.ANG. family semiconductor devices using semi-insulating A1Sb substrate  

DOE Patents (OSTI)

For the first time, an aluminum antimonide (AlSb) single crystal substrate is utilized to lattice-match to overlying semiconductor layers. The AlSb substrate establishes a new design and fabrication approach to construct high-speed, low-power electronic devices while establishing inter-device isolation. Such lattice matching between the substrate and overlying semiconductor layers minimizes the formation of defects, such as threaded dislocations, which can decrease the production yield and operational life-time of 6.1-.ANG. family heterostructure devices.

Sherohman, John W. (Livermore, CA); Coombs, III, Arthur W. (Patterson, CA); Yee, Jick Hong (Livermore, CA); Wu, Kuang Jen J. (Cupertino, CA)

2007-05-29T23:59:59.000Z

411

Factors contributing to the breakdown of sodium beta-alumina  

DOE Green Energy (OSTI)

Clarification of the breakdown process occurring during charge transfer in sodium beta alumina solid electrolytes was derived from: (1) studying the effects of molten sodium contact at 350/sup 0/C on single crystal sodium beta alumina and polycrystalline sodium beta alumina; (2) determination of critical current density by monitoring acoustic emissions accompanying crack growth in sodium/sodium beta alumina/sodium cells subjected to linear current ramping at 1 mA cm/sup -2/ sec/sup -1/; (3) failure analysis conducted on cycled electrolytes, some from commercial sodium/sulfur cells, which had been subjected to up to 703 Ahr cm/sup -2/ of charge transfer. Gray coloration developing in beta aluminas in contact with molten sodium was found to be a consequence of formation, through reduction by sodium, of oxygen vacancies charge compensated by electrons. Electronic conductivity of the electrolyte increases as a result. No second phase formation was detected. Colored electrolytes from sodium/sulfur cells show evidence of a newly recognized degradation mechanism in which fracture occurs when sodium is reduced and deposited internally under pressure as metal in regions where an electronic conductivity gradient exists. Heating colored beta aluminas in air produces reoxidation and bleaching. Kinetics and other properties of the coloration and bleaching processes were determined. Critical current density was found to bear an inverse relation to average electrolyte grain size. Evidence was found in the cycled electrolytes for a slow crack growth mechanism and a progressive mode of degradation advancing from the sulfur electrode interface. Implications of the findings for the construction and operation of sodium/sulfur battery systems are discussed.

Buechele, A.C.

1982-05-01T23:59:59.000Z

412

In-situ Reflectance Monitoring of GaSb Substrate Oxide Desorption  

DOE Green Energy (OSTI)

The use of specular reflectance to monitor GaSb substrate oxide desorption in-situ is reported. Substrates were loaded into the organometallic vapor phase epitaxy reactor either as-received (epi-ready) or after receiving a solvent degrease, acid etch and rinse. A variety of surface preparations and anneal conditions were investigated. HCL was used as the etchant, and in certain cases was followed by an additional etch in Br{sub 2}-HCl-HNO{sub 3}-CH{sub 3}COOH for comparison. Rinse comparisons included 2-propanol, methanol, and deionized water. Substrates were heated to either 525, 550, or 575 C. Features observed in the in-situ reflectance associated with the oxide desorption process were interpreted based on the starting oxide chemistry and thickness. Based on in-situ reflectance and ex-situ atomic force microscopy data, a recommendation on a reproducible GaSb substrate preparation technique suitable for high-quality epitaxial growth is suggested.

C.J. Vineis; C.A. Wang; K.F. Jensen

2000-08-21T23:59:59.000Z

413

SeZnSb alloy and its nano tubes, graphene composites properties  

Science Conference Proceedings (OSTI)

Composite can alter the individual element physical property, could be useful to define the specific use of the material. Therefore, work demonstrates the synthesis of a new composition Se{sub 96}-Zn{sub 2}-Sb{sub 2} and its composites with 0.05% multi-walled carbon nano tubes and 0.05% bilayer graphene, in the glassy form. The diffused amorphous structure of the multi walled carbon nano tubes and bilayer gaphene in the Se{sub 96}-Zn{sub 2}-Sb{sub 2} alloy have been analyzed by using the Raman, X-ray photoluminescence spectroscopy, Furrier transmission infrared spectra, photoluminescence, UV/visible absorption spectroscopic measurements. The diffused prime Raman bands (G and D) have been appeared for the multi walled carbon nano tubes and graphene composites, while the X-ray photoluminescence core energy levels peak shifts have been observed for the composite materials. Subsequently the photoluminescence property at room temperature and a drastic enhancement (upto 80%) in infrared transmission percentage has been obtained for the bilayer graphene composite, along with optical energy band gaps for these materials have been evaluated 1.37, 1.39 and 1.41 eV.

Singh, Abhay Kumar [Department of Physics, Indian Institute of Physics, Bangalore-560012 (India)

2013-04-15T23:59:59.000Z

414

Thermoelectric and thermodynamic properties of half-Heulser alloy YPdSb from first principles calculations  

SciTech Connect

The structural, electronic, thermoelectric and thermodynamic properties of ternary half-Heusler compound YPdSb are investigated using the first principle calculations. It is found that YPdSb is an indirect semiconductor. The calculated band gap is 0.161 eV with spin-orbital coupling including and 0.235 eV without spin-orbital coupling including, respectively. The electronic transport properties are obtained via Boltzman transport theory. The predicted Seebeck coefficient is 240 {mu}V/K and the thermoelectric performance can be optimized by n-type doping at room temperature. Moreover, the lattice dynamical results regarding the phonon dispersion curves, phonon density of states and thermodynamic properties are reported. Thermodynamics (heat capacity and Debye temperature) as well as mean phonon free path and the thermal conductivity in a temperature range of 0-300 K are determined. - Graphical Abstract: (a) The dependence of the Seebeck coefficient on chemical potential at 300 K. (b) The dependence of the thermopower factor on chemical potential at 300 K. Highlights: Black-Right-Pointing-Pointer The Seebeck coefficient and the thermopower factor are calculated. Black-Right-Pointing-Pointer The lattice dynamics and thermodynamic properties are obtained.

Kong, Fanjie, E-mail: fanjiekong@gmail.com [Department of Physics, Yancheng Institute of Technology, Jiangsu 224051 (China)] [Department of Physics, Yancheng Institute of Technology, Jiangsu 224051 (China); Hu, Yanfei [School of Science, Sichuan University of Science and Engineering, Zigong 643000 (China)] [School of Science, Sichuan University of Science and Engineering, Zigong 643000 (China); Hou, Haijun [School of Materials Science and Engineering, Yancheng Institute of Technology, Jiangsu 224051 (China)] [School of Materials Science and Engineering, Yancheng Institute of Technology, Jiangsu 224051 (China); Liu, Yanhua [School of information engineering, Yancheng Institute of Technology, Jiangsu 224051 (China)] [School of information engineering, Yancheng Institute of Technology, Jiangsu 224051 (China); Wang, Baolin [Department of Physics, Yancheng Institute of Technology, Jiangsu 224051 (China)] [Department of Physics, Yancheng Institute of Technology, Jiangsu 224051 (China); Wang, Lili [Computer Application Institute of CAEP, Academy of Engineering Physics of China, Mianyang 621900 (China)] [Computer Application Institute of CAEP, Academy of Engineering Physics of China, Mianyang 621900 (China)

2012-12-15T23:59:59.000Z

415

Optical anisotropy of InAs/GaSb broken-gap quantum wells  

Science Conference Proceedings (OSTI)

We investigate in detail the optical anisotropy of absorption of linearly polarized light in InAs/GaSb quantum wells grown on GaSb along the [001] direction, which can be used as an active region of different laser structures. The energy level positions, the wave functions, the optical matrix elements, and the absorption coefficients are calculated using the eight-band k {center_dot} p model and the Burt-Foreman envelope function theory. In these calculations, the Schroedinger and Poisson equations are solved self-consistently taking the lattice-mismatched strain into account. We find that a realistic Hamiltonian, which has the C{sub 2v} symmetry, results in considerable anisotropy of optical matrix elements for different directions of light polarization and different directions of the initial-state in-plane wave vector, including low-symmetry directions. We trace how the optical matrix elements and absorption are modified when spin-orbit interaction and important symmetry breaking mechanisms are taken into account (structural inversion asymmetry, bulk inversion asymmetry, and interface Hamiltonian). These mechanisms result in an almost 100% anisotropy of the absorption coefficients as the light polarization vector rotates in the plane of the structure and in a plane normal to the interfaces.

Zakharova, A. A., E-mail: anna.alex.zakharova@gmail.com; Semenikhin, I. A. [Russian Academy of Sciences, Institute of Physics and Technology (Russian Federation); Chao, K. A. [Lund University, Department of Physics (Sweden)

2012-05-15T23:59:59.000Z

416

Ba{sub 5}Ti{sub 12}Sb{sub 19+x}, a polar intermetallic compound with a stuffed gamma-brass structure  

Science Conference Proceedings (OSTI)

The polar intermetallic compound Ba{sub 5}Ti{sub 12}Sb{sub 19+x} (xbrass type with a primitive cell. A complex three-dimensional framework of Ti atoms, in the form of linked planar Ti{sub 9} clusters, is stuffed within the gamma-brass-type Ba-Sb substructure. Notwithstanding its relationship to the gamma-brass structure, the compound does not appear to conform to the Hume-Rothery electron concentration rules. Band structure calculations on an idealized Ba{sub 5}Ti{sub 12}Sb{sub 19} model suggest that the availability of bonding states above the Fermi level is responsible for the partial occupation, but only to a limited degree, of an additional Sb site within the structure. Magnetic measurements indicated Pauli paramagnetic behaviour. - A gamma-brass substructure built up of Ba-Sb clusters is stuffed with planar Ti{sub 9} clusters.

Bie Haiying [Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2 (Canada); Mar, Arthur, E-mail: arthur.mar@ualberta.c [Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2 (Canada)

2009-11-15T23:59:59.000Z

417

Atomic layer deposition of Al{sub 2}O{sub 3} on GaSb using in situ hydrogen plasma exposure  

SciTech Connect

In this report, we study the effectiveness of hydrogen plasma surface treatments for improving the electrical properties of GaSb/Al{sub 2}O{sub 3} interfaces. Prior to atomic layer deposition of an Al{sub 2}O{sub 3} dielectric, p-GaSb surfaces were exposed to hydrogen plasmas in situ, with varying plasma powers, exposure times, and substrate temperatures. Good electrical interfaces, as indicated by capacitance-voltage measurements, were obtained using higher plasma powers, longer exposure times, and increasing substrate temperatures up to 250 Degree-Sign C. X-ray photoelectron spectroscopy reveals that the most effective treatments result in decreased SbO{sub x}, decreased Sb, and increased GaO{sub x} content at the interface. This in situ hydrogen plasma surface preparation improves the semiconductor/insulator electrical interface without the use of wet chemical pretreatments and is a promising approach for enhancing the performance of Sb-based devices.

Ruppalt, Laura B.; Cleveland, Erin R.; Champlain, James G.; Prokes, Sharka M.; Brad Boos, J.; Park, Doewon; Bennett, Brian R. [Electronics Science and Technology Division, Naval Research Laboratory, Washington, DC 20375 (United States)

2012-12-03T23:59:59.000Z

418

TREATMENT OF CYANIDE SOLUTIONS AND SLURRIES USING AIR-SPARGED HYDROCYCLONE (ASH) TECHNOLOGY  

Science Conference Proceedings (OSTI)

The two-year Department of Energy (DOE) project ''Treatment of Cyanide Solutions and Slurries Using Air-Sparged Hydrocyclone (ASH) Technology'' (ASH/CN) has been completed. This project was also sponsored by industrial partners, ZPM Inc., Elbow Creek Engineering, Solvay Minerals, EIMCO-Baker Process, Newmont Mining Corporation, Cherokee Chemical Co., Placer Dome Inc., Earthworks Technology, Dawson Laboratories and Kennecott Minerals. Development of a new technology using the air-sparged hydrocyclone (ASH) as a reactor for either cyanide recovery or destruction was the research objective. It was expected that the ASH could potentially replace the conventional stripping tower presently used for HCN stripping and absorption with reduced power costs. The project was carried out in two phases. The first phase included calculation of basic processing parameters for ASH technology, development of the flowsheet, and design/adaptation of the ASH mobile system for hydrogen cyanide (HCN) recovery from cyanide solutions. This was necessary because the ASH was previously used for volatile organics removal from contaminated water. The design and modification of the ASH were performed with the help from ZPM Inc. personnel. Among the modifications, the system was adapted for operation under negative pressure to assure safe operating conditions. The research staff was trained in the safe use of cyanide and in hazardous material regulations. Cyanide chemistry was reviewed resulting in identification of proper chemical dosages for cyanide destruction, after completion of each pilot plant run. The second phase of the research consisted of three field tests that were performed at the Newmont Mining Corporation gold cyanidation plant near Midas, Nevada. The first field test was run between July 26 and August 2, 2002, and the objective was to demonstrate continuous operation of the modified ASH mobile system. ASH units were applied for both stripping and absorption, to recover cyanide, using the acidification-volatilization-reabsorption chemistry. Plant barren cyanide solution was used during the field tests. The original ASH system used for the field tests had been designed and fabricated by ZPM Inc. to remove volatile organic compounds from ground water. The system, even with a number of modifications, could not operate at optimum conditions for cyanide recovery. Reactors and pumps installed in the mobile system only allowed for the treatment of clear solutions, not slurries. Also the original mobile system was limited with respect to Q, the relative air flow rate, and the extent of recovery in a single stage. Due to the lack of automatic controls, the system required constant supervision of the University of Utah (U/U) team. In spite of these difficulties, application of the ASH mobile system was particularly attractive due to compactness of the apparatus and less than 1 second residence time of the aqueous phase in the cyclones. The performance of the ASH system was evaluated by comparison with theoretical predictions.

Jan D. Miller; Terrence Chatwin; Jan Hupka; Doug Halbe; Tao Jiang; Bartosz Dabrowski; Lukasz Hupka

2003-03-31T23:59:59.000Z

419

Bioaccumulation Studies Associated with the Kingston Fly Ash Spill, Spring 2009 - Fall 2010  

SciTech Connect

In December 2008, an ash dike at the Tennessee Valley Authority (TVA) Kingston Fossil Plant ruptured, releasing over one billion gallons of coal fly ash into the Emory and Clinch Rivers. Coal fly ash may contain several contaminants of concern, but of these selenium (Se) and arsenic (As) have been highlighted because of their toxicity and tendency to bioaccumulate in aquatic food chains. To assess the potential impact of the spilled fly ash on humans and the environment, a comprehensive biological and environmental monitoring program was established, for which resident aquatic organisms (among other sample media) are collected to determine contaminant exposure and evaluate the risk to humans and wildlife. Studies on bioaccumulation and fish health are major components of the TVA Biological Monitoring Program for the Kingston fly ash project. These studies were initiated in early Spring 2009 for the purposes of: (1) documenting the levels of fly ash-associated metals in various tissues of representative sentinel fish species in the area of the fly ash spill, (2) determining if exposure to fly ash-associated metals causes short, intermediate, or long-term health effects on these sentinel fish species, (3) assessing if there are causal relationships between exposure (to metals) and effects on fish, (4) evaluating, along with information regarding other ecological and physicochemical studies, the nature and route of contaminant transfer though food chains into higher level consumers, (5) providing important information for the Ecological Risk Assessment (ERA) for the Kingston fly ash project, and (6) serving as an important technology transfer or model study focused on how to best evaluate the environmental effects of fly ash, not only at the Kingston site, but also at sites on other aquatic systems where coal-fired generating stations are located. This report summarizes the bioaccumulation results from the first two years of study after the fly ash spill, including four seasonal collections: Spring 2009, Fall 2009, Spring 2010, and Fall 2010. Both the Spring and Fall studies have focused on 3-4 sentinel fish species that represent different feeding habits, behaviors, and home ranges. In addition to bioaccumulation studies, the Spring investigations also included evaluation of fish health and reproductive integrity on the same fish used for bioaccumulation. Two associated reports present the fish health (Adams et al 2012) and reproductive studies (Greeley et al 2012) conducted in 2009 and 2010. The fish health study conducted in conjunction with the bioaccumulation and reproductive study is critical for assessing and evaluating possible causal relationships between contaminant exposure (bioaccumulation) and the response of fish to exposure as reflected by the various measurements of fish health. This report emphasizes evaluation of arsenic and selenium bioaccumulation in fish and consists of four related studies (Sections 2-5) including, (1) bioaccumulation in liver and ovaries, (2) bioaccumulation in whole body gizzard shad (Dorosoma cepedianum), (3) bioaccumulation in muscle tissue or fillets, and (4) a reconstruction analysis which establishes the relationship between selenium in muscle tissue and that of the whole body of bluegill (Lepomis machrochirus). Metals other than arsenic and selenium are evaluated separately in Section 6. This report focuses on selenium and arsenic for the following reasons: (1) based on baseline studies conducted in early 2009 in the Emory and Clinch River, only two potentially fly-ash related metals, selenium and arsenic, appeared to be elevated above background or reference levels, (2) selenium and arsenic are two of the metals in coal ash that are known to bioaccumulate and cause toxicity in wildlife, and (3) based on bioaccumulation studies of bluegill and carp (Cyprinus carpio) in the Stilling Pond during Spring 2009, which would represent a worst case situation for metal bioaccumulation, selenium and arsenic were the only two metals consistently elevated above background levels in fish. E

Adams, Marshall [ORNL; Brandt, Craig C [ORNL; Fortner, Allison M [ORNL

2012-05-01T23:59:59.000Z

420

High temperature behavior of electrostatic precipitator ash from municipal solid waste combustors  

E-Print Network (OSTI)

combustion may cause the oxidation of mercury, and chloride mercury #12;13 13 species may be the major form combustion and gasification flue gases, Environ. Sci. Technol. 30 (1996) 2421-2426. [23] S.B. Ghorishi, C Ms. Ref. No.: HAZMAT-D-07-00176 Accepted manuscript #12;2 2 Abstract Municipal solid waste (MSW) flue

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Fly ash properties and mercury sorbent affect mercury release from curing concrete  

Science Conference Proceedings (OSTI)

The release of mercury from concrete containing fly ashes from various generator boilers and powdered activated carbon sorbent used to capture mercury was measured in laboratory experiments. Release of gaseous mercury from these concretes was less than 0.31% of the total quantity of mercury present. The observed gaseous emissions of mercury during the curing process demonstrated a dependency on the organic carbon content of the fly ash, with mercury release decreasing with increasing carbon content. Further, lower gaseous emissions of mercury were observed for concretes incorporating ash containing activated carbon sorbent than would be expected based on the observed association with organic carbon, suggesting that the powdered activated carbon more tightly binds the mercury as compared to unburned carbon in the ash. Following the initial 28-day curing interval, mercury release diminished with time. In separate leaching experiments, average mercury concentrations leached from fly ash concretes were less than 4.1 ng/L after 18 h and 7 days, demonstrating that less than 0.02% of the mercury was released during leaching. 25 refs., 4 figs., 5 tabs.

Danold W. Golightly; Chin-Min Cheng; Linda K. Weavers; Harold W. Walker; William E. Wolfe [State University, Columbus, OH (United States). Department of Civil and Environmental Engineering and Geodetic Science

2009-04-15T23:59:59.000Z

422

Role of fly ash in the removal of organic pollutants from wastewater  

Science Conference Proceedings (OSTI)

Fly ash, a relatively abundant and inexpensive material, is currently being investigated as an adsorbent for the removal of various organic pollutants from wastewater. The wastewater contains various types of phenolic compounds, such as chloro, nitro, amino, and other substituted compounds. Various types of pesticides, such as lindane, malathion, carbofuran, etc., and dyes, such as, methylene blue, crystal violet, malachite green, etc., are also present in the wastewater. These contaminants pollute the water stream. These organic pollutants, such as phenolic compounds, pesticides, and dyes, etc., can be removed very effectively using fly ash as adsorbent. This article presents a detailed review on the role of fly ash in the removal of organic pollutants from wastewater. Adsorption of various pollutants using fly ash has been reviewed. The adsorption mechanism and other influencing factors, favorable conditions, and competitive ions, etc., on the adsorption process have also been discussed in this paper. It is evident from the review that fly ash has demonstrated good removal capabilities for various organic compounds. 171 refs., 3 figs., 5 tabs.

M. Ahmaruzzaman [National Institute of Technology, Silchar (India). Department of Chemistry

2009-03-15T23:59:59.000Z

423

Use of Brazilian sugarcane bagasse ash in concrete as sand replacement  

SciTech Connect

Sugarcane today plays a major role in the worldwide economy, and Brazil is the leading producer of sugar and alcohol, which are important international commodities. The production process generates bagasse as a waste, which is used as fuel to stoke boilers that produce steam for electricity cogeneration. The final product of this burning is residual sugarcane bagasse ash (SBA), which is normally used as fertilizer in sugarcane plantations. Ash stands out among agroindustrial wastes because it results from energy generating processes. Many types of ash do not have hydraulic or pozzolanic reactivity, but can be used in civil construction as inert materials. The present study used ash collected from four sugar mills in the region of Sao Carlos, SP, Brazil, which is one of the world's largest producers of sugarcane. The ash samples were subjected to chemical characterization, sieve analysis, determination of specific gravity, X-ray diffraction, scanning electron microscopy, and solubilization and leaching tests. Mortars and concretes with SBA as sand replacement were produced and tests were carried out: compressive strength, tensile strength and elastic modulus. The results indicated that the SBA samples presented physical properties similar to those of natural sand. Several heavy metals were found in the SBA samples, indicating the need to restrict its use as a fertilizer. The mortars produced with SBA in place of sand showed better mechanical results than the reference samples. SBA can be used as a partial substitute of sand in concretes made with cement slag-modified Portland cement.

Sales, Almir, E-mail: almir@ufscar.b [Department of Civil Engineering, UFSCar, Via Washington Luis, km 235, Monjolinho, 13565-905 Sao Carlos, SP (Brazil); Lima, Sofia Araujo, E-mail: sofiaalima@yahoo.com.b [Department of Civil Engineering, UFSCar, Via Washington Luis, km 235, Monjolinho, 13565-905 Sao Carlos, SP (Brazil)

2010-06-15T23:59:59.000Z

424

Fact Sheet: Sodium-Beta Batteries (October 2012)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium-Beta Batteries Sodium-Beta Batteries Improving the performance and reducing the cost of sodium-beta batteries for large-scale energy storage Sodium-beta batteries (Na-beta batteries or NBBs) use a solid beta-alumina (ß˝-Al 2 O 3 ) electrolyte membrane that selectively allows sodium ion transport between a positive electrode (e.g., a metal halide) and a negative sodium electrode. NBBs typically operate at temperatures near 350˚C. They are increasingly used in renewable storage and utility applications due to their high round-trip efficiency, high energy densities, and energy storage capacities ranging from a few kilowatt-hours to multiple megawatt-hours. In fact, U.S. utilities

425

Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria  

NLE Websites -- All DOE Office Websites (Extended Search)

II. Phase Equilibria II. Phase Equilibria Title Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria Publication Type Journal Article Year of Publication 1996 Authors Ridgway, Paul L., Frank R. McLarnon, and John S. Newman Journal Journal of the Electrochemistry Society Volume 143 Issue 2 Pagination 412-417 Keywords 25 ENERGY STORAGE, 36 MATERIALS SCIENCE, ALUMINIUM OXIDES, equilibrium, performance, PHASE DIAGRAMS, PHOSPHIDES, PHOSPHORUS ADDITIONS, SODIUM COMPOUNDS, SODIUM SULFIDES, SODIUM-SULFUR BATTERIES Abstract Equilibrium open-circuit cell voltage data from a sodium/{beta}{double_prime}-alumina/phosphorus-sulfur cell utilizing P/S ratios of 0, 0.143, and 0.332 and a sodium atom fraction ranging from 0 to 0.4 were interpreted to construct ternary phase diagrams of the Na-P-S ternary system at 350 and 400 C.

426

Review of Chemical Processes for the Synthesis of Sodium Borohydride  

NLE Websites -- All DOE Office Websites (Extended Search)

Review of Chemical Processes for the Synthesis of Sodium Borohydride Review of Chemical Processes for the Synthesis of Sodium Borohydride Millennium Cell Inc. Prepared by Ying Wu Michael T. Kelly Jeffrey V. Ortega Under DOE Cooperative Agreement DE-FC36-04GO14008 August 2004 Table of Contents Introduction..................................................................................................................................... 1 Section 1: Commercially Practiced Sodium Borohydride Synthesis Process ............................... 2 The Brown-Schlesinger Process ................................................................................................. 2 The Bayer Process.......................................................................................................................

427

METHOD FOR REDUCING THE IMPURITY RESISTIVITY OF SODIUM  

DOE Patents (OSTI)

The inherent resistivity of sodium, at cryogenic temperatures, can be reduced by clustering the impurity atoms within the crystal latiice structure of the sodium, thereby reducing the effective electron collision cross section and thus reducing the number of collisions between the electrons and such lattice imperfections. The clustering is effected by heating the sodium to a temperature approaching its melting point, and maintaining the temperature for a period of time ranging generally from two to six days. (AEC)

Post, R.F.; Taylor, C.E.

1963-08-13T23:59:59.000Z

428

PROCESSING OF SODIUM--POTASSIUM NIOBATE CERAMICS.  

SciTech Connect

Sintering studies of undoped (Na{sub 0.5}K{sub 0.5})NbO{sub 3} and the same material doped with 1/2, 1, 2, and 4 mole percent BaO and 2 mole % B{sub 2}O{sub 3} were made. The persistence of a second phase after calcining to form the compound led to a study of reactions occurring during calcination. The calcining of sodium-potassium niobates involves the formation of an intermediate compound (the second phase) and its subsequent reaction with sodium oxide and potassium oxide to form (Na{sub 0.5}K{sub 0.5})NbO{sub 3}. Sintering data show that up to 1/2 mole % BaO added to the system increases the initial densification. However, the sintered bodies then exhibit densification and form sharp cubic grains and large voids. Indications are that a liquid phase is the major contributor to densification of this system through the mechanism of particle rearrangement, and that the contribution of any sintering mechanism to densification is negligible.

Powell, B.R. Jr.

1971-01-01T23:59:59.000Z

429

Sodium tetraphenylborate solubility and dissolution rates  

DOE Green Energy (OSTI)

The rate of solid sodium tetraphenylborate (NaTPB) dissolution in In-Tank Precipitation salt solutions has been experimentally determined. The data indicates that the dissolution rate of solid NaTPB is a minor contributor the lag time experienced in the 1983 Salt Decontamination Demonstration Test and should not be considered as the rate determining step. Current analytical models for predicting the time to reach the composite lower flammability limit assume that the lag time is not more than 6 hours, and the data supports this assumption (i.e., dissolution by itself requires much less than 6 hours). The data suggests that another step--such as mass transport, the reaction of a benzene precursor or the mixing behavior--is the rate determining factor for benzene release to the vapor space in Tank 48H. In addition, preliminary results from this program show that the degree of agitation employed is not a significant parameter in determining the rate of NaTPB dissolution. As a result of this study, an improved equation for predicting equilibrium tetraphenylborate solubility with respect to temperature and sodium ion concentration has been determined.

Barnes, M.J.; Peterson, R.A.; Swingle, R.F.; Reeves, C.T.

1995-12-31T23:59:59.000Z

430

Sodium Reactor Experiment decommissioning. Final report  

Science Conference Proceedings (OSTI)

The Sodium Reactor Experiment (SRE) located at the Rockwell International Field Laboratories northwest of Los Angeles was developed to demonstrate a sodium-cooled, graphite-moderated reactor for civilian use. The reactor reached full power in May 1958 and provided 37 GWh to the Southern California Edison Company grid before it was shut down in 1967. Decommissioning of the SRE began in 1974 with the objective of removing all significant radioactivity from the site and releasing the facility for unrestricted use. Planning documentation was prepared to describe in detail the equipment and techniques development and the decommissioning work scope. A plasma-arc manipulator was developed for remotely dissecting the highly radioactive reactor vessels. Other important developments included techniques for using explosives to cut reactor vessel internal piping, clamps, and brackets; decontaminating porous concrete surfaces; and disposing of massive equipment and structures. The documentation defined the decommissioning in an SRE dismantling plan, in activity requirements for elements of the decommissioning work scope, and in detailed procedures for each major task.

Carroll, J.W.; Conners, C.C.; Harris, J.M.; Marzec, J.M.; Ureda, B.F.

1983-08-15T23:59:59.000Z

431

Sodium Bearing Waste Treatment Project ? Countdown to Startup  

NLE Websites -- All DOE Office Websites (Extended Search)

Date: March 19, 2012 Media Contact: Natalie Packer, 208-533-0253 Sodium Bearing Waste Treatment Project Countdown to Startup Marking completion of another major...

432

Energy absorber for sodium-heated heat exchanger  

DOE Patents (OSTI)

A heat exchanger is described in which water-carrying tubes are heated by liquid sodium and in which the results of accidental contact between the water and the sodium caused by failure of one or more of the water tubes is minimized. An energy absorbing chamber contains a compressible gas and is connected to the body of flowing sodium by a channel so that, in the event of a sodium-water reaction, products of the reaction will partially fill the energy absorbing chamber to attenuate the rise in pressure within the heat exchanger.

Essebaggers, J.

1975-12-01T23:59:59.000Z

433

Battery Electrode Materials Based on Layered Sodium Titanates  

Berkeley Lab researcher Marca Doeff and colleagues have developed a new electrode material based on a layered sodium titanate compound that can be ...

434

Interaction of sodium vapor and graphite studied by ...  

Science Conference Proceedings (OSTI)

The kinetics of the reaction between graphite and sodium vapor is analyzed with support ... High temperature compression test to determine the anode paste ...

435

Low Temperature Sodium-Sulfur Grid Storage and EV Battery  

Berkeley Lab researcher Gao Liu has developed an innovative design for a battery, made primarily of sodium and sulfur, that holds promise for both ...

436

Low Temperature Sodium-Sulfur Grid Storage and EV Battery ...  

Berkeley Lab researcher Gao Liu has developed an innovative design for a battery, made primarily of sodium and sulfur, that holds promise for both large-scale grid ...

437

NASICON-Type Electrolytes for Low Temperature Sodium Battery ...  

Science Conference Proceedings (OSTI)

Presentation Title, NASICON-Type Electrolytes for Low Temperature Sodium Battery Applications. Author(s), Hui Zhang, Xingbo Liu. On-Site Speaker ( Planned) ...

438

ESS 2012 Peer Review - Sodium Intercalation Battery for Stationary...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

LLC 35 Hartwell Avenue Lexington, MA 02421-3102 www.TIAXLLC.com Sodium Intercalation Battery for Stationary Storage Energy Storage Systems Program (ESS) Peer Review and Update...

439

Sodium cobalt bronze batteries and a method for making same  

SciTech Connect

A solid state secondary battery utilizing a low cost, environmentally sound, sodium cobalt bronze electrode. A method is provided for producing same.

Doeff, Marca M. (Hayward, CA); Ma, Yanping (Berkeley, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard (Lafayette, CA)

1999-01-01T23:59:59.000Z

440

Reductive Sulfur-fixation Smelting of Stibnite Concentrate in Sodium ...  

Science Conference Proceedings (OSTI)

Abstract Scope, A new process to extracted antimony directly from stibnite concentrate by reductive sulfur-fixation smelting in sodium molten salt has been ...

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.