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Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
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1

Removal of ash from Indian Assam coking coal using sodium hydroxide and acid solutions  

SciTech Connect (OSTI)

Mineral matter (ash) removal from Assam coking coal by leaching with different concentrations of sodium hydroxide and acid (HCl, H{sub 2}SO{sub 4}, HNO{sub 3}, and HF) solutions has been investigated at a temperature of 75 C. The parameters tested were concentration of NaOH, type of acid, concentration of acids, and number of acid leaching steps. Total ash removed increased with increase of NaOH and acid concentrations up to the range studied. For the same experimental conditions, treatment of caustic leached coal in HCl acid resulted in better demineralization than in H{sub 2}SO{sub 4} or HNO{sub 3} acid. In the NaOH-HNO{sub 3} leaching method, a higher concentration (>20%) of HNO{sub 3} acid had an adverse effect on the de-ashing of coal. The NaOH-HF leaching process has been found to be the most effective method of coal de-ashing. The two acid treatment steps (HCl-H{sub 2}SO{sub 4}/HCl-HNO{sub 3}) after caustic leaching are the next most effective methods of coal de-ashing. The removal of mineral matter (including S) from coal is expected to decrease the graphite reactivity and thus the atmospheric pollution (due to the generation of smaller quantities of CO and SO{sub 2} gases).

Kumar, M.; Shankar, R.H.

2000-03-01T23:59:59.000Z

2

SnSb@carbon nanocable anchored on graphene sheets for sodium ion batteries  

Science Journals Connector (OSTI)

The development of materials with unique nanostructures is an effective strategy for the improvement of sodium storage in sodium ion batteries to achieve stable cycling performance and good ... , SnSbcore/carbon-...

Li Li; Kuok Hau Seng; Dan Li; Yongyao Xia; Hua Kun Liu; Zaiping Guo

2014-10-01T23:59:59.000Z

3

Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer  

SciTech Connect (OSTI)

In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na{sub 2}SiO{sub 3}) and 10 M sodium hydroxide (NaOH) solutions at mass ratio of Na{sub 2}SiO{sub 3}/NaOH of 1.5 and curing temperature of 65 deg. C for 48 h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0 MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

Chindaprasirt, Prinya [Department of Civil Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen 40002 (Thailand); Rattanasak, Ubolluk, E-mail: ubolluk@buu.ac.t [Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Burapha University, Chonburi 20131 (Thailand)

2010-04-15T23:59:59.000Z

4

Disposal of boiler ash  

SciTech Connect (OSTI)

As more boilers are converted from oil to solid fuels such as coal, the quantity of ash requiring disposal will increase dramatically. The factors associated with the development of land disposal systems for ash landfills are presented, including ash characterization, site selection procedures, design parameters, and costs.

Atwell, J.S.

1981-08-01T23:59:59.000Z

5

Fly ash carbon passivation  

DOE Patents [OSTI]

A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

La Count, Robert B; Baltrus, John P; Kern, Douglas G

2013-05-14T23:59:59.000Z

6

Lead contents of coal, coal ash and fly ash  

Science Journals Connector (OSTI)

Flameless atomic absorption spectrometry is applied for the determination of Pb in coal, coal ash and fly ash. Lead concentrations in coal and coal ash ranging from respectively 7 to 110 µg...?1 and 120 to 450 µg...

C. Block; R. Dams

1975-12-01T23:59:59.000Z

7

Mutagenicity and genotoxicity of coal fly ash water leachate  

SciTech Connect (OSTI)

Fly ash is a by-product of coal-fired electricity generation plants. The prevalent practice of disposal is as slurry of ash and water to storage or ash ponds located near power stations. This has lain to waste thousands of hectares of land all over the world. Since leaching is often the cause of off-site contamination and pathway of introduction into the human environment, a study on the genotoxic effects of fly ash leachate is essential. Leachate prepared from the fly ash sample was analyzed for metal content, and tested for mutagenicity and genotoxicity. Analyses of metals show predominance of the metals - sodium, silicon, potassium, calcium, magnesium, iron, manganese, zinc, and sulphate. The Ames Salmonella mutagenicity assay, a short-term bacterial reverse mutation assay, was conducted on two-tester strains of Salmonella typhimurium strains TA97a and TA102. For genotoxicity, the alkaline version of comet assay on fly ash leachate was carried in vitro on human blood cells and in vivo on Nicotiana plants. The leachate was directly mutagenic and induced significantconcentration-dependent increases in DNA damage in whole blood cells, lymphocytes, and in Nicotiana plants. The comet parameters show increases in tail DNA percentage (%), tail length (mu m), and olive tail moment (arbitrary units). Our results indicate that leachate from fly ash dumpsites has the genotoxic potential and may lead to adverse effects on vegetation and on the health of exposed human populations.

Chakraborty, R.; Mukherjee, A. [University of Calcutta, Calcutta (India). Dept. of Botany

2009-03-15T23:59:59.000Z

8

The Fusibility of Blended Coal Ash  

Science Journals Connector (OSTI)

Ash fusibility temperatures (AFT) of coal ash are found at temperatures below the predicted liquidus temperature and, for ashes from blended coals, are generally nonlinear with respect to the blend proportion. ... ashing. ...

G. W. Bryant; G. J. Browning; H. Emanuel; S. K. Gupta; R. P. Gupta; J. A. Lucas; T. F. Wall

2000-02-25T23:59:59.000Z

9

Utilization FLY ASH INFORMATION FROM  

E-Print Network [OSTI]

, quarries, and pits (34%), 6% for temporary stockpile, and 7% landfilled. Fly Ash In Europe, the utilization

Wisconsin-Milwaukee, University of

10

Changes in trace element contents in ashes of oil shale fueled PF and CFB boilers during operation  

Science Journals Connector (OSTI)

Abstract Two oil shale combustion technologies, pulverized firing (PF) and circulated fluidized bed (CFB) were compared with respect to partitioning of selected elements (Ba, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, Rb, Sb, Sn, Sr, Th, Tl, U, V, and Zn) in the ashes along the flue gas ducts. The ash samples were characterized by high-resolution ICP-MS. The average contents of toxic heavy metals in fly ash samples from the CFB boiler are lower compared to the PF boiler. Main differences in trace element contents between combustion technologies were as follows: Cd content in the fly ash samples of PF boiler was up to 0.9 mg/kg while in CFB boiler it remained below 0.1 mg/kg in all analyzed ash samples; Hg was observed in the ashes of electrostatic precipitator (ESP) of CFB boiler while in the PF boiler it was close to or below detection limit. In the PF boiler content of Sn was detected only in the ashes of ESPs, while in CFB boiler it was evenly distributed between bottom and fly ash samples. Highest content among heavy metals in ash samples was observed for Pb in the last field of ESP of the PF boiler (142 mg/kg).

Janek Reinik; Natalya Irha; Eiliv Steinnes; Gary Urb; Jekaterina Jefimova; Eero Piirisalu; Jüri Loosaar

2013-01-01T23:59:59.000Z

11

ASH EMISSIVITY CHARACTERIZATION AND PREDICTION  

SciTech Connect (OSTI)

The increased use of western subbituminous coals has generated concerns regarding highly reflective ash disrupting heat transfer in the radiant zone of pulverized-fuel boilers. Ash emissivity and reflectivity is primarily a function of ash particle size, with reflective deposits expected to consist of very small refractory ash materials such as CaO, MgO, or sulfate materials such as Na{sub 2}SO{sub 4}. For biomass fuels and biomass-coal blends, similar reflectivity issues may arise as a result of the presence of abundant organically associated calcium and potassium, which can transform during combustion to fine calcium, and potassium oxides and sulfates, which may act as reflective ash. The relationship of reflectivity to ash chemistry is a second-order effect, with the ash particle size distribution and melting point being determined by the size and chemistry of the minerals present in the starting fuel. Measurement of the emission properties of ash and deposits have been performed by several research groups (1-6) using both laboratory methods and measurements in pilot- and full-scale combustion systems. A review of the properties and thermal properties of ash stresses the important effect of ash deposits on heat transfer in the radiant boiler zone (1).

Christopher J. Zygarlicke; Donald P. McCollor; Charlene R. Crocker

1999-12-01T23:59:59.000Z

12

Modeling volcanic ash dispersal  

ScienceCinema (OSTI)

Explosive volcanic eruptions inject into the atmosphere large amounts of volcanic material (ash, blocks and lapilli). Blocks and larger lapilli follow ballistic and non-ballistic trajectories and fall rapidly close to the volcano. In contrast, very fine ashes can remain entrapped in the atmosphere for months to years, and may affect the global climate in the case of large eruptions. Particles having sizes between these two end-members remain airborne from hours to days and can cover wide areas downwind. Such volcanic fallout entails a serious threat to aircraft safety and can create many undesirable effects to the communities located around the volcano. The assessment of volcanic fallout hazard is an important scientific, economic, and political issue, especially in densely populated areas. From a scientific point of view, considerable progress has been made during the last two decades through the use of increasingly powerful computational models and capabilities. Nowadays, models are used to quantify hazard scenarios and/or to give short-term forecasts during emergency situations. This talk will be focused on the main aspects related to modeling volcanic ash dispersal and fallout with application to the well known problem created by the Eyjafjöll volcano in Iceland. Moreover, a short description of the main volcanic monitoring techniques is presented.

None

2011-10-06T23:59:59.000Z

13

E-Print Network 3.0 - ash bottom ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: of bottom ash, 3 million tons of boiler slag, and 28 million tons of clean-coal ash materials) were produced... CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By...

14

Comparing properties of coal ash and alternative-fuel ash  

Science Journals Connector (OSTI)

The results of investigating ash produced in burning alternative kinds of fuel are discussed. Its impact on the environment is evaluated, and possibilities of recovering it are studied.

E. P. Dick; G. A. Ryabov; A. N. Tugov; A. N. Soboleva

2007-03-01T23:59:59.000Z

15

Coal fly ash disposal in the ocean: an alternative worth considering  

SciTech Connect (OSTI)

Chemical and biological experiments measured the solubility of 16 elements in coal fly ash and the short-term toxicity of coal fly ash to clams and phytoplankton. Of the elements studied, 10 to 60% of the As, Br, Cr, Sb, Se, Ni, Pb, and Sr dissolved within a 24-hour period. Elements which were less than 10% soluble in 24-hours included Cu, Zn, Na, La, Sc, Fe, Co and Eu. Littleneck clams (Protothaca staminea) were exposed to coal fly ash in flowing seawater for a 25-day period. At the end of the exposure Cu concentration in gills was 15 ..mu..g g/sup -1/ dry wt compared to 6 ..mu..g g/sup -1/ in control clams. Elements that were not elevated in the exposed clams were Mn, Fe, Ni, Zn, Se and As. The effects of the soluble fraction of coal fly ash on primary production was measured by /sup 14/C uptake rate on coastal phytoplankton. The addition of soluble coal fly ash material had no effect on the /sup 14/C uptake rate of phytoplankton. These measurements were made in the productive Washington shelf water during August. The literature indicates coal fly ash has a relatively low toxicity to plants and animals. Disposal methods could be designed so EPA water quality criteria levels would not be exceeded except in the immediate vicinity of the dumpsite.

Crecelius, E.A.

1981-10-01T23:59:59.000Z

16

Development of Artificial Ash Accelerated Accumulation Test ...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Artificial Ash Accelerated Accumulation Test Development of Artificial Ash Accelerated Accumulation Test Poster presented at the 16th Directions in Engine-Efficiency and Emissions...

17

Prickly Ash and Prickly Pear  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Prickly Ash and Prickly Pear Prickly Ash and Prickly Pear Nature Bulletin No. 649-A October 1, 1977 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation PRICKLY ASH AND PRICKLY PEAR In the plant kingdom, as among people, there are so-me that we avoid. They have few virtues, if any, and our experiences with them are painful or have unpleasant after effects. Poison ivy is a notorious example. Prickly Ash, a shrub, is another. Although not poisonous it is thickly armed with wicked thorns and has no ornamental, economic or wildlife value. In 1821 when the first section lines were established in Cook County, the surveyor recorded -- for the benefit of land buyers -- the principal kinds of trees and other vegetation observed along each mile. He frequently encountered prickly ash in thickets near the Little Calumet River and also the north and south branches of the Chicago River.

18

Geochemistry and mineralogy of fly-ash from the Mae Moh lignite deposit, Thailand  

SciTech Connect (OSTI)

The concentration of 21 elements in fly ash from three boilers (75 MW, 150 MW, and 300 MW) at the EGAT power plant, Mae Moh, Thailand, were determined by INAA. The concentration of 10 major elements was determined by XRF. As, Co, Cr, Ni, Mo, and Sb generally increase in concentration going from bottom ash (BA) through the sequence of electrostatic precipitator ashes (ESPA) and reach maxima of As (352 ppm), Co (45 ppm), Cr (105 ppm), Mo (32 ppm), Ni (106 ppm), and Sb (15 ppm) in the ESPA. Ce, Cs, Fe, Hf, La, Sc, Ta, Tb, and Yb did not exhibit concentration trends or are variable except in the case of one boiler, which showed an increase going from BA to ESPA. Only Br decreased in composition going from BA to ESPA. Rb, Sm, U, and Th showed marked variation in trends. The major elements identified by EDS were Al, Si, S, K, Ca, Fe, and Ba, with minor amounts of Mg, Na, Ti, Mn, and Sr. Al, Si, K, and Ca occur together and are present in most of the fly-ash particles. Ba was found as a major component with Ca, Al, and Si. Fe and Ca are usually associated with sulfur. Some small spheres (< 5 {mu}m) are comprised almost entirely of Fe (probably as oxide). Symplectite textures are noted in high-Fe phases. All elements except Br are significantly enriched in the fly ash relative to the coal, which contains 35% ash. Particle chemistry is consistent with the major mineral phases identified by XRD, which include: quartz, magnetite, mullite, gehlenite, anorthite, hematite, anhydrite, and clinopyroxene.

Hart, B.R.; Powell, M.A.; Fyfe, W.S. [Univ. of Western Ontario, London, Ontario (Canada). Dept. of Geology; Ratanasthien, B. [Univ. of Chaing Mai (Thailand). Dept. of Geology

1995-01-01T23:59:59.000Z

19

Use of Ekibastuzsk coal ash as a filler for acid resistant plaster  

SciTech Connect (OSTI)

Acid resistant plasters are used extensively at thermal power plants for protection of gas conduits, ash traps with spouts and hydraulic valves, and the internal surfaces of smoke pump housings. The surface being protected is preliminarily cleaned and a No. 16-20 steel grid attached to the surface by electrial welding. In producing the acid resistant plaster, 14-17 parts by weight of sodium silicofluoride are added to 100 parts by weight of sodium water glass; the remainder consists of andesite or diabase meal to the required consistency. The water glass fulfills the role of a binder; the sodium silicofluoride accelerates solidification of the water glass and the andesite and diabase meal serve as fillers. We found, tested in the laboratory and used successfully (under experimental-industrial conditions) a substitute for andesite and diabase meal. This substitute was ash of Ekibastuzsk coal, which was not only comparable to the meal in regard to quality of the acid resistant plaster, but even exceeded andesite and diabase meal in regard to several qualitative indicators. At the present time, a formula is being developed for an acid resistant plaster produced on the basis of water glass, sodium silicofluoride and ash of Ekibastuzsk coal. In order to verify the possibility of using other ashes instead of andesite and diabase meal, we also tested, under laboratory conditions, acid resistant plasters using ash from thermal power plants (TPP's) also burning Karagandinsk, Kuuchekinsk, Kuznetsk and Kansko-Achinsk coals. In compositions produced with polymer binders, Kansko-Achinsk coal ash was one of the best fillers, providing the most favorable physico-mechanical properties of the composition.

Korsakov, F.F.; Isichenko, I.I.; Kabanov, G.A.

1981-01-01T23:59:59.000Z

20

Simulation of Coal Ash Particle Deposition Experiments  

Science Journals Connector (OSTI)

Simulation of Coal Ash Particle Deposition Experiments† ... Ichikawa et al.(7) measured deposition behavior for ash particles from ashing tests for a series of five coals, using a nominally 1 m tall × 60 mm diameter ash-heating tube that was fitted with a cooled, temperature-controlled particle impact probe oriented at a 30° angle to the atmospheric pressure air flow. ...

Weiguo Ai; John M. Kuhlman

2011-01-20T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Insurance coverage for coal ash liabilities  

SciTech Connect (OSTI)

The paper discusses how liability insurance can be a valuable tool for limiting coal ash liabilities.

Elkind, D.L. [Dickstein Shapiro LLP (United States)

2009-07-01T23:59:59.000Z

22

Recycling of sodium waste  

Science Journals Connector (OSTI)

Recycling of sodium waste ... Methods for handling and recycling a dangerous and costly chemical. ...

Bettina Hubler-Blank; Michael Witt; Herbert W. Roesky

1993-01-01T23:59:59.000Z

23

Effect of Coal Ash Composition on Ash Fusion Temperatures  

Science Journals Connector (OSTI)

Experiments have been conducted in which mixtures of selected coal ashes and SiO2, Al2O3, CaO, Fe2O3, and MgO were subjected to the standard test for ash fusibility. ... One property that specifically gives detail information on the suitability of a coal source [Alpern, B., Nahuys, J., Martinez, L. Mineral matter in ashy and non-washable coals-its influence on chem. ...

Wen J. Song; Li H. Tang; Xue D. Zhu; Yong Q. Wu; Zi B. Zhu; Shuntarou Koyama

2009-08-11T23:59:59.000Z

24

Energy-level and lifetime measurements for Sb iv and Sb v  

Science Journals Connector (OSTI)

A study of the beam-foil spectrum produced by a 1-MeV beam of antimony ions has yielded lifetimes for nine lowlying terms of Sb iv and six of Sb v. Decay-curve analysis incorporating...

Pinnington, E H; Ansbacher, W; Kernahan, J A; Gosselin, R N; Bahr, J L; Inamdar, A S

1985-01-01T23:59:59.000Z

25

Lattice thermal conductivity of Bi, Sb, and Bi-Sb alloy from first principles  

E-Print Network [OSTI]

Using first principles, we calculate the lattice thermal conductivity of Bi, Sb, and Bi-Sb alloys, which are of great importance for thermoelectric and thermomagnetic cooling applications. Our calculation reveals that the ...

Lee, Sangyeop

26

Moon Dust and Coal Ash  

Science Journals Connector (OSTI)

... struck by the similarity between the preliminary descriptions of moon dust and that of the ash residue collected from pulverized ... residue collected from pulverized coal-fired boilers (that is, pulverized fuel ...

A. B. HART; E. RAASK

1969-08-16T23:59:59.000Z

27

Sustainable Use of Biofuel by Recycling Ash to Forests:? Treatment of Biofuel Ash  

Science Journals Connector (OSTI)

Sustainable Use of Biofuel by Recycling Ash to Forests:? Treatment of Biofuel Ash ... Ash samples from combustion of biofuels in a circulating fluidized bed and grate-firing combustion plants are studied. ...

Maryam Mahmoudkhani; Tobias Richards; Hans Theliander

2007-04-26T23:59:59.000Z

28

Cast-Concrete Products Made with FBC Ash and Wet-Collected Coal-Ash  

E-Print Network [OSTI]

. DOI: 10.1061/ ASCE 0899-1561 2005 17:6 659 CE Database subject headings: Recycling; Ashes; Concrete et al. 1991 . Fluidized bed combustion FBC ash is the ash produced by an FBC boiler in which the coal

Wisconsin-Milwaukee, University of

29

Transport properties in AlInSb/InAsSb heterostructures  

SciTech Connect (OSTI)

Based on theoretical studies of transport properties in InAsSb-based quantum well heterostructures, we propose a material design for InAsSb quantum well with AlInSb barrier. Variation of electron mobility and two-dimensional electron gas concentration in Al{sub y}In{sub 1?y}Sb/InAs{sub 1?x}Sb{sub x} heterostructures over the compositional range of which InAsSb is fully strained to AlInSb are investigated, where impact from dislocation scattering could be minimized. In comparison with InAs and InSb based quantum well heterostructures, InAsSb is advantageous in achieving the highest electron mobility despite of alloy disorder scattering. The maximum mobility of 37?000 cm{sup 2}/V s is attainable in 15?nm InAs{sub 0.2}Sb{sub 0.8} quantum well with Al{sub 0.24}In{sub 0.76}Sb barrier and there is great potential for further improvement. Our InAsSb based quantum well heterostructure is proved to be a robust structure for high-speed applications.

Zhang, Yuwei; Zhang, Yang, E-mail: zhang-yang@semi.ac.cn; Wang, Chengyan; Zeng, Yiping [Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China)

2013-12-28T23:59:59.000Z

30

Method of making an InAsSb/InAsSbP diode lasers  

DOE Patents [OSTI]

InAsSb/InAsSbP/InAs Double Heterostructures (DH) and Separate Confinement Heterostructure Multiple Quantum Well (SCH-MQW) structures are taught wherein the ability to tune to a specific wavelength within 3 {micro}m to 5 {micro}m is possible by varying the ratio of As:Sb in the active layer. 9 figs.

Razeghi, M.

1997-08-19T23:59:59.000Z

31

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

1994-01-01T23:59:59.000Z

32

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during soot blowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon. 8 figs.

Hurley, J.P.; McCollor, D.P.; Selle, S.J.

1994-07-26T23:59:59.000Z

33

Fly ash chemical classification based on lime  

SciTech Connect (OSTI)

Typically, total lime content (CaO) of fly ash is shown in fly ash reports, but its significance is not addressed in US specifications. For certain applications a low lime ash is preferred. When a class C fly ash must be cementitious, lime content above 20% is required. A ternary S-A-C phase diagram pilot is given showing the location of fly ash compositions by coal rank and source in North America. Fly ashes from subbituminous coal from the Powder River Basin usually contain sufficient lime to be cementitious but blending with other coals may result in calcium being present in phases other than tricalcium aluminate. 9 refs., 1 fig.

Fox, J. [BASF Construction Chemicals, LLC (United States)

2007-07-01T23:59:59.000Z

34

Leaching of boron from coal ash  

Science Journals Connector (OSTI)

Leaching of boron from coal ash ... First High-Resolution 11B Nuclear Magnetic Resonance (NMR) Spectra of Coal Fly Ash by Satellite-Transition Magic Angle Spinning (STMAS) NMR ... First High-Resolution 11B Nuclear Magnetic Resonance (NMR) Spectra of Coal Fly Ash by Satellite-Transition Magic Angle Spinning (STMAS) NMR ...

James A. Cox; Gary L. Lundquist; Andrzej Przyjazny; C. David Schmulbach

1978-06-01T23:59:59.000Z

35

Ohmic contacts to n-GaSb  

E-Print Network [OSTI]

in the semiconductor is measured during the deposition of the metal contact. In using method 1, the I-V characteristics is plotted. The thermionic emission theory predicts the current-voltage characteristics of Schottky diodes as [13]: J(rhcrmionic) = A" T' exp... of different work functions. This situation is also true for metal contacts to n-GaSb. Polyakov et al. [14] examined the Schottky diodes of Al, Au, In, Pd, Ga, and Sb on Te doped n-GaSb. They used the C-V measurements methods. They reported that barrier...

Yang, Zhengchong

2012-06-07T23:59:59.000Z

36

Pollen Influx and Volcanic Ash  

Science Journals Connector (OSTI)

...Artemisia) blooms in the fall and a dis-proportionate percentage...were recorded. The five pollen groups plotted in Fig. 5 were selected...expected to occur during the fall and perhaps winter months...probability of an initial ash-fall in late summer. Certain acid-resist-ant...

Peter J. Mehringer Jr.; Eric Blinman; Kenneth L. Petersen

1977-10-21T23:59:59.000Z

37

Coal Ash and Clean Coal  

Science Journals Connector (OSTI)

... IT is the normal view that the incombustible part of coal is not only a useless but even objectionable diluent. At times in the past, ... , familiar with the theory of contact catalysis of gas reactions, have speculated that the ash constituents might well play an active role in the processes of carbonisation and combustion. ...

H. J. HODSMAN

1926-09-04T23:59:59.000Z

38

Growth mechanisms of GaSb heteroepitaxial films on Si with an AlSb buffer layer  

SciTech Connect (OSTI)

The initial growth stages of GaSb epilayers on Si substrates and the role of the AlSb buffer layer were studied by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). Heteroepitaxy of GaSb and AlSb on Si both occur by Volmer-Weber (i.e., island mode) growth. However, the AlSb and GaSb islands have distinctly different characteristics as revealed through an atomic-resolution structural study using Z-contrast of HAADF-STEM imaging. While GaSb islands are sparse and three dimensional, AlSb islands are numerous and flattened. The introduction of 3D island-forming AlSb buffer layer facilitates the nucleation of GaSb islands. The AlSb islands-assisted nucleation of GaSb islands results in the formation of drastically higher quality planar film at a significantly smaller thickness of films. The interface of the AlSb and GaSb epilayers with the Si substrate was further investigated with energy dispersive X-ray spectrometry to elucidate the key role of the AlSb buffer layer in the growth of GaSb epilayers on Si substrates.

Vajargah, S. Hosseini; Botton, G. A. [Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario L8S 4L7 (Canada) [Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Canadian Centre for Electron Microscopy, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Ghanad-Tavakoli, S. [Centre for Emerging Device Technologies, McMaster University, Hamilton, Ontario L8S 4L7 (Canada)] [Centre for Emerging Device Technologies, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Preston, J. S.; Kleiman, R. N. [Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1 (Canada) [Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Centre for Emerging Device Technologies, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Department of Engineering Physics, McMaster University, Hamilton, Ontario L8S 4L7 (Canada)

2013-09-21T23:59:59.000Z

39

Petrographic characterization of economizer fly ash  

SciTech Connect (OSTI)

Policies for reducing NOx emissions have led power plants to restrict O{sub 2}, resulting in high-carbon fly ash production. Therefore, some potentially useful fly ash, such as the economizer fly ash, is discarded without a thorough knowledge of its composition. In order to characterize this type of fly ash, samples were collected from the economizer Portuguese power plant burning two low-sulfur bituminous coals. Characterization was also performed on economizer fly ash subsamples after wet sieving, density and magnetic separation. Analysis included atomic absorption spectroscopy, loss-on-ignition, scanning electron microscopy/energy-dispersive X-ray spectroscopy, optical microscopy, and micro-Raman spectroscopy.

Valentim, B.; Hower, J.C.; Soares, S.; Guedes, A.; Garcia, C.; Flores, D.; Oliveira, A. [University of Porto, Oporto (Portugal). Center of Geology

2009-11-15T23:59:59.000Z

40

ACCELERATED PROCESSING OF SB4 AND PREPARATION FOR SB5 PROCESSING AT DWPF  

SciTech Connect (OSTI)

The Defense Waste Processing Facility (DWPF) initiated processing of Sludge Batch 4 (SB4) in May 2007. SB4 was the first DWPF sludge batch to contain significant quantities of HM or high Al sludge. Initial testing with SB4 simulants showed potential negative impacts to DWPF processing; therefore, Savannah River National Laboratory (SRNL) performed extensive testing in an attempt to optimize processing. SRNL's testing has resulted in the highest DWPF production rates since start-up. During SB4 processing, DWPF also began incorporating waste streams from the interim salt processing facilities to initiate coupled operations. While DWPF has been processing SB4, the Liquid Waste Organization (LWO) and the SRNL have been preparing Sludge Batch 5 (SB5). SB5 has undergone low-temperature aluminum dissolution to reduce the mass of sludge for vitrification and will contain a small fraction of Purex sludge. A high-level review of SB4 processing and the SB5 preparation studies will be provided.

Herman, C

2008-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Make It Work: Implementing SB 375  

E-Print Network [OSTI]

bridging of project and plan level review has been difficultStrengthening Plan-Level Review under SB 375 …………………………………that if an adequate plan-level review is conducted for a “

Altmaier, Monica; Barbour, Elisa; Eggleton, Christian; Gage, Jeffier; Hayter, Jason; Zahner, Ayrin

2009-01-01T23:59:59.000Z

42

ACAA fly ash basics: quick reference card  

SciTech Connect (OSTI)

Fly ash is a fine powdery material created when coal is burned to generate electricity. Before escaping into the environment via the utility stacks, the ash is collected and may be stored for beneficial uses or disposed of, if necessary. The use of fly ash provides environmental benefits, such as the conservation of natural resources, the reduction of greenhouse gas emissions and eliminating the needed for ash disposal in landfills. It is also a valuable mineral resource that is used in construction and manufacturing. Fly ash is used in the production of Portland cement, concrete, mortars and stuccos, manufactured aggregates along with various agricultural applications. As mineral filler, fly ash can be used for paints, shingles, carpet backing, plastics, metal castings and other purposes. This quick reference card is intended to provide the reader basic source, identification and composition, information specifically related to fly ash.

NONE

2006-07-01T23:59:59.000Z

43

Ultrasonic ash/pyrite liberation  

SciTech Connect (OSTI)

The objective of this project was to develop a coal preparation concept which employed ultrasonics to precondition coal prior to conventional or advanced physical beneficiation processes such that ash and pyrite separation were enhanced with improved combustible recovery. Research activities involved a series of experiments that subjected three different test coals, Illinois No. 6, Pittsburgh No. 8, and Upper Freeport, ground to three different size fractions (28 mesh [times] 0, 200 mesh [times] 0, and 325 mesh [times] 0), to a fixed (20 kHz) frequency ultrasonic signal prior to processing by conventional and microbubble flotation. The samples were also processed by conventional and microbubble flotation without ultrasonic pretreatment to establish baseline conditions. Product ash, sulfur and combustible recovery data were determined for both beneficiation processes.

Yungman, B.A.; Buban, K.S.; Stotts, W.F.

1990-06-01T23:59:59.000Z

44

The fluidized bed combustion ash management puzzle  

SciTech Connect (OSTI)

As the electric and industrial power generation industry upgrades and expands, the amount of coal and other solid fuels also expands. With increased environmental controls, the introduction of a competitive market for power, and the increased interest in opportunity fuels will increase the usage of Fluidized Bed Combustion (FBC) boilers in the power industry. The combustion of these solid fuels will generate combustion ashes. Power generators, including FBC boilers owners, have traditionally looked to landfills for the disposal of their ash. With the tighter environmental controls being placed on landfills at the federal and state level, power generators are beginning to see constantly escalating tipping fees which now make the landfill option less attractive. In some instances, landfills are beginning to refuse to accept ash regardless of the tipping fee. In view of this, the power generators are now struggling to find a place to store or dispose of the ash that is produced by their power boiler. Other disposal alternatives such as backhaul to the mine and beneficial reuse are now being considered. Either alternative presents its own set of technical and environmental variables to be considered in developing an effective ash management plan. To be effective, these plans need to incorporate an aggressive, yet realistic, role to support beneficial reuse of the ash. Many applications exist for reuse of the various types of ash. The applications for conventional ashes such as those from pulverized coal boilers and stoker fired boilers are mature and more commonplace. The uses for FBC ash are not as well researched and demonstrated and therefore the marketing opportunities for FBC ash continue to require development. FBC boiler owners and operators must be willing to accept the challenges posed in developing these reuse applications for FBC ash for the market to accept the applications for FBC ash and allow the full value of the FBC ash to be realized.

Fitzgerald, H.B. [ReUse Technology, Inc., Kennesaw, GA (United States)

1996-12-31T23:59:59.000Z

45

Lattice-matched epitaxial GaInAsSb/GaSb thermophotovoltaic devices  

SciTech Connect (OSTI)

The materials development of Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} alloys for lattice-matched thermophotovoltaic (TPV) devices is reported. Epilayers with cutoff wavelength 2--2.4 {micro}m at room temperature and lattice-matched to GaSb substrates were grown by both low-pressure organometallic vapor phase epitaxy and molecular beam epitaxy. These layers exhibit high optical and structural quality. For demonstrating lattice-matched thermophotovoltaic devices, p- and n-type doping studies were performed. Several TPV device structures were investigated, with variations in the base/emitter thicknesses and the incorporation of a high bandgap GaSb or AlGaAsSb window layer. Significant improvement in the external quantum efficiency is observed for devices with an AlGaAsSb window layer compared to those without one.

Wang, C.A.; Choi, H.K.; Turner, G.W.; Spears, D.L.; Manfra, M.J. [Massachusetts Inst. of Tech., Lexington, MA (United States). Lincoln Lab.; Charache, G.W. [Lockheed Martin, Inc., Schenectady, NY (United States)

1997-05-01T23:59:59.000Z

46

Performance improvement of Ge-Sb-Te material by GaSb doping for phase change memory  

SciTech Connect (OSTI)

Effects of GaSb doping on phase change characteristics of Ge-Sb-Te material are investigated by in situ resistance and x-ray diffraction measurement, optical spectroscopy, and x-ray photoelectron spectroscopy. The crystallization temperature and data retention of Ge-Sb-Te material increase significantly by the addition of GaSb, which results from the high thermal stability of amorphous GaSb. In addition, GaSb-doped Ge-Sb-Te material exhibits faster crystallization speed due to the change in electronic states as a result of the formation of chemical bonds with Ga element. Incorporation of GaSb is highly effective way to enhance the comprehensive performance of Ge-Sb-Te material for phase change memory.

Lu, Yegang [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China) [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211 (China); Graduate School of Chinese Academy of Sciences, Beijing 100049 (China); Zhang, Zhonghua; Song, Sannian; Cheng, Limin; Song, Zhitang [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China)] [State Key Laboratory of Functional Materials for Informatics, Laboratory of Nanotechnology, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Shen, Xiang; Wang, Guoxiang; Dai, Shixun [Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211 (China)] [Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211 (China)

2013-06-17T23:59:59.000Z

47

Nepheline Formation Potential in Sludge Batch 4 (SB4)  

SciTech Connect (OSTI)

The effect of crystallization on glass durability is complex and depends on several interrelated factors including the change in residual glass composition, the formation of internal stress or microcracks, and the preferential attack at the glass-crystal interface. Perhaps one of the most significant effects is the type and extent (or fraction) of crystallization and the resulting change to the residual glass composition. A strong increase in glass dissolution (or decrease in durability) has been observed in previous studies in glasses that formed aluminum-containing crystals, such as NaAlSiO{sub 4} (nepheline) and LiAlSi{sub 2}O{sub 6}, and crystalline SiO{sub 2}. Although the addition of Al{sub 2}O{sub 3} to borosilicate glasses enhances the durability of the waste form (through creation of network-forming tetrahedral Na{sup +}-[AlO{sub 4/2}]{sup -} pairs), the combination of high Al{sub 2}O{sub 3} and Na{sub 2}O can lead to the formation of nepheline (NaAlSiO{sub 4}). Given the projected high concentration of Al{sub 2}O{sub 3} in SB4 and the potential use of a high Na{sub 2}O based glass (as a result of the use of a high Na{sub 2}O frit and/or a less washed sludge) to improve melt rate, the potential formation of nepheline in various SB4 systems is being assessed. Li et al. (2003) indicate that sodium alumino-borosilicate glasses are prone to nepheline crystallization if their compositions projected on the Na{sub 2}O-Al{sub 2}O{sub 3}-SiO{sub 2} ternary fall within the nepheline primary phase field. In particular, durable glasses with SiO{sub 2}/(SiO{sub 2}+Na{sub 2}O+ Al{sub 2}O{sub 3}) > 0.62, where the oxides are expressed as mass fractions in the glass, do not precipitate nepheline as their primary phase. Twelve SB4-based glasses have been identified or classified as ''prone to nepheline formation'' using a ''less conservative'' discriminator value of 0.65. Ten of the 12 glasses are Frit 320 based, and 8 of these 10 target a 40% WL-independent of the SB4 blending scenario used. This is not unexpected due to the higher alkali content of Frit 320 (12% Na{sub 2}O) relative to Frit 418 (8% Na{sub 2}O) and the fact that as WLs increase, the Na{sub 2}O and Al{sub 2}O{sub 3} concentrations increase and the SiO{sub 2} concentrations decrease in this series of glasses. Using the ''less conservative'' value as a guide will not only increase the probability of forming nepheline but will also allow the assessment of several different blending scenarios, both frits, and different WLs which will provide valuable insight into the frit selection process for SB4. More specifically, blending strategies, frit compositions, and WLs that avoid nepheline formation could be used to guide the frit selection process or to make compositional adjustments to the frit. The durability of these 12 glasses (of both quenched and centerline canister cooled versions) will be measured with the results being documented in a subsequent report.

PEELER, D

2005-04-01T23:59:59.000Z

48

Cast Stone Formulation At Higher Sodium Concentrations  

SciTech Connect (OSTI)

A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leachability indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the l

Fox, K. M.; Roberts, K. A.; Edwards, T. B.

2014-02-28T23:59:59.000Z

49

Cement Additives from Fly Ash Opportunity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Device and Method for Separating Minerals, Carbon and Device and Method for Separating Minerals, Carbon and Cement Additives from Fly Ash Opportunity Research is currently active on the patented technology "Device and Method for Separating Minerals, Carbon, and Cement Additives from Fly Ash." The technology is available for licensing and/or further collaborative research from the U.S. Depart- ment of Energy's National Energy Technology Laboratory (NETL). Overview This invention includes a device, along with a method, to recover and use fly ash as a source of high purity carbon, ash, and minerals. The device and associated method can isolate components of the fly ash based on size and electrical charge. By improving beneficiation and usage methods, fly ash can be transformed from a waste material to a valuable by-product. Recent shifts to low nitrogen

50

Volcanic ash impacts on critical infrastructure  

Science Journals Connector (OSTI)

Volcanic eruptions can produce a wide range of hazards. Although phenomena such as pyroclastic flows and surges, sector collapses, lahars and ballistic blocks are the most destructive and dangerous, volcanic ash is by far the most widely distributed eruption product. Although ash falls rarely endanger human life directly, threats to public health and disruption to critical infrastructure services, aviation and primary production can lead to significant societal impacts. Even relatively small eruptions can cause widespread disruption, damage and economic loss. Volcanic eruptions are, in general, infrequent and somewhat exotic occurrences, and consequently in many parts of the world, the management of critical infrastructure during volcanic crises can be improved with greater knowledge of the likely impacts. This article presents an overview of volcanic ash impacts on critical infrastructure, other than aviation and fuel supply, illustrated by findings from impact assessment reconnaissance trips carried out to a wide range of locations worldwide by our international research group and local collaborators. ‘Critical infrastructure’ includes those assets, frequently taken for granted, which are essential for the functioning of a society and economy. Electricity networks are very vulnerable to disruption from volcanic ash falls. This is particularly the case when fine ash is erupted because it has a greater tendency to adhere to line and substation insulators, where it can cause flashover (unintended electrical discharge) which can in turn cause widespread and disruptive outages. Weather conditions are a major determinant of flashover risk. Dry ash is not conductive, and heavy rain will wash ash from insulators, but light rain/mist will mobilise readily-soluble salts on the surface of the ash grains and lower the ash layer’s resistivity. Wet ash is also heavier than dry ash, increasing the risk of line breakage or tower/pole collapse. Particular issues for water supply managers include: monitoring turbidity levels in raw water intakes, and if necessary increasing chlorination to compensate for higher turbidity; managing water demand; and communicating monitoring results with the public to allay fears of contamination. Ash can cause major damage to wastewater disposal systems. Ash deposited onto impervious surfaces such as roads and car parks is very easily washed into storm drains, where it can form intractable masses and lead to long-term flooding problems. It can also enter wastewater treatment plants (WWTPs), both through sewer lines and by direct fallout. Damage to modern \\{WWTPs\\} can run into millions of dollars. Ash falls reduce visibility creating hazards for ground transportation. Dry ash is also readily remobilised by vehicle traffic and wind, and dry and wet ash deposits will reduce traction on paved surfaces, including airport runways. Ash cleanup from road and airports is commonly necessary, but the large volumes make it logistically challenging. Vehicles are vulnerable to ash; it will clog filters and brake systems and abrade moving parts within engines. Lastly, modern telecommunications networks appear to be relatively resilient to volcanic ash fall. Signal attenuation and interference during ash falls has not been reported in eruptions over the past 20 years, with the exception of interference from ash plume-generated lightning. However, some telecommunications equipment is vulnerable to airborne ash, in particular heating, ventilation and air-conditioning (HVAC) systems which may become blocked from ash ingestion leading to overheating. This summary of volcanic ash impacts on critical infrastructure provides insight into the relative vulnerability of infrastructure under a range of different ashfall scenarios. Identifying and quantifying these impacts is an essential step in building resilience within these critical systems. We have attempted to consider interdependencies between sectors in a holistic way using systems thinking. As modern society becomes increasingly complex and interdependent this

Thomas M. Wilson; Carol Stewart; Victoria Sword-Daniels; Graham S. Leonard; David M. Johnston; Jim W. Cole; Johnny Wardman; Grant Wilson; Scott T. Barnard

2012-01-01T23:59:59.000Z

51

COAL ASH RESOURCES RESEARCH CONSORTIUM  

SciTech Connect (OSTI)

The Coal Ash Resources Research Consortium (CARRC, pronounced ?cars?) is the core coal combustion by-product (CCB) research group at the Energy & Environmental Research Center (EERC). CARRC focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of CCBs. CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCB utilization and ensuring its successful application. CARRC continued the partnership of industry partners, university researchers, and the U.S. Department of Energy (DOE) addressing needs in the CCB industry through technical research and development projects. Technology transfer also continued through distribution and presentation of the results of research activities to appropriate audiences, with emphasis on reaching government agency representatives and end users of CCBs. CARRC partners have evolved technically and have jointly developed an understanding of the layers of social, regulatory, legal, and competition issues that impact the success of CCB utilization as applies to the CCB industry in general and to individual companies. Many CARRC tasks are designed to provide information on CCB performance including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC activities from 1993?1998 included a variety of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCBs. The tasks summarized in this report are 1) The Demonstration of CCB Use in Small Construction Projects, 2) Application of CCSEM (computer-controlled scanning electron microscopy) for Coal Combustion By-Product Characterization, 3) Development of a Procedure to Determine Heat of Hydration for Coal Combustion By-Products, 4) Investigation of the Behavior of High-Calcium Coal Combustion By-Products, 5) Development of an Environmentally Appropriate Leaching Procedure for Coal Combustion By-Products, 6) Set Time of Fly Ash Concrete, 7) Coal Ash Properties Database (CAPD), 8) Development of a Method for Determination of Radon Hazard in CCBs, 9) Development of Standards and Specifications, 10) Assessment of Fly Ash Variability, and 11) Development of a CCB Utilization Workshop. The primary goal of CARRC is to work with industry to solve CCB-related problems and promote the environmentally safe, technically sound, and economical utilization and disposal of these highly complex materials. CARRC 1993?1998 accomplishments included: C Updating the CAPD to a user-friendly database management system, and distributing it to CARRC members. C ASTM standard preparation for a guide to using CCBs as waste stabilization agents. C Preliminary identification of specific mineral transformations resulting from fly ash hydration. C Limited determination of the effects of fly ash on the set time of concrete. C Statistical evaluation of a select set of fly ashes from several regional coal-fired power plants. C Development and presentation of a workshop on CCB utilization focused on government agency representatives and interested parties with limited CCB utilization experience. C Participation in a variety of local, national, and international technical meetings, symposia, and conferences by presenting and publishing CCB-related papers.

NONE

1998-12-01T23:59:59.000Z

52

Characterization of ash cenospheres in fly ash from Australian power stations  

SciTech Connect (OSTI)

Ash cenospheres in fly ashes from five Australian power stations have been characterized. The experimental data show that ash cenosphere yield varies across the power stations. Ash partitioning occurred in the process of ash cenosphere formation during combustion. Contradictory to conclusions from the literature, iron does not seem to be essential to ash cenosphere formation in the cases examined in the present work. Further investigation was also undertaken on a series of size-fractioned ash cenosphere samples from Tarong power station. It is found that about 70 wt% of ash cenospheres in the bulk sample have sizes between 45 and 150 {mu}m. There are two different ash cenosphere structures, that is, single-ring structure and network structure. The percentage of ash cenospheres of a network structure increases with increasing ash cenosphere size. Small ash cenospheres (in the size fractions {lt}150 {mu}m) have a high SiO{sub 2}/Al{sub 2}O{sub 3} ratio, and the majority of the ash cenospheres are spherical and of a single-ring structure. Large ash cenosphere particles (in the size fractions of 150-250 {mu}m and {gt}250 {mu}m) have a low SiO{sub 2}/Al{sub 2}O{sub 3} ratio, and a high proportion of the ash cenospheres are nonspherical and of a network structure. A novel quantitative technique has been developed to measure the diameter and wall thickness of ash cenospheres on a particle-to-particle basis. A monolayer of size-fractioned ash cenospheres was dispersed on a pellet, which was then polished carefully before being examined using a scanning electron microscope and image analysis. The ash cenosphere wall thickness broadly increases with increasing ash cenosphere size. The ratios between wall thickness and diameter of ash cenospheres are limited between an upper bound of about 10.5% and a lower bound of about 2.5%, irrespective of the ash cenosphere size. 52 refs., 9 figs., 4 tabs.

Ling-ngee Ngu; Hongwei Wu; Dong-ke Zhang [Curtin University of Technology, Perth, WA (Australia). Centre for Fuels and Energy and Department of Chemical Engineering

2007-12-15T23:59:59.000Z

53

Submersible sodium pump  

DOE Patents [OSTI]

An electromagnetic submerged pump has an outer cylindrical stator with an inner cylindrical conductive core for the submerged pumping of sodium in the cylindrical interstitial volume defined between the stator and core. The cylindrical interstitial volume is typically vertically oriented, and defines an inlet at the bottom and an outlet at the top. The outer stator generates upwardly conveyed toroidal magnetic fields, which fields convey preferably from the bottom of the pump to the top of the pump liquid sodium in the cold leg of a sodium cooled nuclear reactor. The outer cylindrical stator has a vertically disposed duct surrounded by alternately stacked layers of coil units and laminates. 14 figs.

Brynsvold, G.V.; Lopez, J.T.; Olich, E.E.; West, C.W.

1989-11-21T23:59:59.000Z

54

Treatment of fly ash for use in concrete  

DOE Patents [OSTI]

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT)

2012-05-15T23:59:59.000Z

55

Application of Coal Fly Ash in Air Quality Management  

Science Journals Connector (OSTI)

Application of Coal Fly Ash in Air Quality Management ... It has been found from the literature that fly ash possesses potential application in the management of air quality. ... Application of Zeolite Synthesized from Fly Ash in Air Quality Management ...

M. Ahmaruzzaman; V.K Gupta

2012-11-05T23:59:59.000Z

56

Detailed Characterization of Lubricant-Derived Ash-Related Species...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Characterization of Lubricant-Derived Ash-Related Species in Diesel Exhaust and Aftertreatment Systems Detailed Characterization of Lubricant-Derived Ash-Related Species in Diesel...

57

The Development of a Small Engine Based Accelerated Ash Loading...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Accelerated Ash Loading Protocol The Development of a Small Engine Based Accelerated Ash Loading Protocol Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan....

58

Uncovering Fundamental Ash-Formation Mechanisms and Potential...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash properties deer12kamp.pdf More Documents...

59

Reducing Lubricant Ash Impact on Exhaust Aftertreatment with...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Under the test...

60

Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreat...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter Minimizing Lubricant-Ash Requirement and Impact on Emission...

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Utilization of Coal Ash As Recycling Material Options in View Point of Geoenvironment  

Science Journals Connector (OSTI)

Disposed coal ash is result from the residual of coal refinery processes and become environmentalimportant issues. Coal ash consists of bottom ash and fly ash. The number of coal ash production is abundant, and c...

Ahmad Rifa’I; Noriyuki Yasufuku; Kiyoshi Omine…

2010-01-01T23:59:59.000Z

62

Settlement of footing on compacted ash bed  

SciTech Connect (OSTI)

Compacted coal ash fills exhibit capillary stress due to contact moisture and preconsolidation stress due to the compaction process. As such, the conventional methods of estimating settlement of footing on cohesionless soils based on penetration tests become inapplicable in the case of footings on coal ash fills, although coal ash is also a cohesionless material. Therefore, a method of estimating load-settlement behavior of footings resting on coal ash fills accounting for the effect of capillary and preconsolidation stresses is presented here. The proposed method has been validated by conducting plate load tests on laboratory prepared compacted ash beds and comparing the observed and predicted load-settlement behavior. Overestimation of settlement greater than 100% occurs when capillary and preconsolidation stresses are not accounted for, as is the case in conventional methods.

Ramasamy, G.; Pusadkar, S.S. [IIT Roorkee, Roorkee (India). Dept. of Civil Engineering

2007-11-15T23:59:59.000Z

63

SB 375 IMPLEMENTATION: FROM PLAN TO REALITY  

E-Print Network [OSTI]

Development Cross-Agency Facilitation and Coordination Funding and Support for Sustainable Communities sustainable communities in a post-SB 375 world. · Urban Greening: $41.5 million in capital projects and plans Planning - Guidance documents - Metrics and indicators - Connecting dots across state agencies - Building

California at Davis, University of

64

Treatment of fly ash for use in concrete  

DOE Patents [OSTI]

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT); Akash, Akash (Salt lake City, UT); Zhao, Qiang (Natick, MA)

2012-05-08T23:59:59.000Z

65

Treatment of fly ash for use in concrete  

DOE Patents [OSTI]

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett; Akash, Akash; Zhao, Qiang

2013-01-08T23:59:59.000Z

66

Coal Ash Corrosion Resistant Materials Testing  

SciTech Connect (OSTI)

In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a moderate alkali content (0.2% sodium equivalents), thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that aggressive alkali sulfate constituents were present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. Test Section A was removed in November 2001 after about 24 months of service at the desired steam temperature set point, with about 15.5 months of exposure at full temperature. A progress report, issued in October 2002, was written to document the performance of the candidate alloys in that test section. The evaluation described the condition of each tube sample after exposure. It involved a determination of the rate of wall thickness loss for these samples. In cases where there was more than one sample of a candidate material in the test section, an assessment was made of the performance of the alloy as a function of temperature. Test Sections B and C were examined during the November 2001 outage, and it was decided that, due to excessive wastage, certain tube samples needed to be removed and replaced in order to ensure that Test Sections B and C would have a chance of remaining in the boiler for their intended exposure period. These suspect tube samples were replaced and the two remaining test sections were put back into service. The tube samples that were removed from Test Sections B and C were set aside for later analysis at the end of the planned exposure period. Test Sections B and C were again examined approximately six months later. At that time, measured wall thickness losses raised concerns about additional tube samples. These suspect samples were also removed, set aside for later analysis, and replaced. The test sections then went back into service until the end of the second exposure period, which was concluded in May 2003 when, due to evidence of excessive wastage, the valves were opened increasing cooling steam flow and thereby effectively stopping corrosion. In August 2003, Test Sections B and C were removed for closer examination. Section C had experienced about 42 months of service at the desired team temperature set point with 28.5 months at temperature at full temperature. Additional suspect samples were removed from Test Section B, then, it was re-installed into the boiler (at the location originally occupied by Section C), where it remained in service until the end of the program. Due to this removal history, the samples from Test Section B had a total service duration that varied from a minimum of 15.5 months (for samples that performed poorly) to 37 months for samples the survived for the full intended service exposure for Section B. The figure below shows a schematic of Test Section B and indicates the length of service exposure for different locations. This report provides the results of the evaluation of Test Section B, including the samples that remained in the Test Section for the full exposure period as well as those that were removed early. This report also is intended to compare and summarize the results for all three test sections. The analysis of T

D. K. McDonald; P. L. Daniel; D. J. DeVault

2007-12-31T23:59:59.000Z

67

Sodium to sodium carbonate conversion process  

DOE Patents [OSTI]

A method of converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO.sub.2 are introduced into a thin film evaporator with the CO.sub.2 present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more metal ions of Sb, As, Ba, Be, Cd, Cr, Pb, Hg, Ni, Se, Ag and T1 can be converted into a low level non-hazardous waste using the thin film evaporator of the invention.

Herrmann, Steven D. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

68

Sodium to sodium carbonate conversion process  

DOE Patents [OSTI]

A method is described for converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO{sub 2} are introduced into a thin film evaporator with the CO{sub 2} present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more metal ions of Sb, As, Ba, Be, Cd, Cr, Pb, Hg, Ni, Se, Ag and Tl can be converted into a low level non-hazardous waste using the thin film evaporator of the invention. 3 figs.

Herrmann, S.D.

1997-10-14T23:59:59.000Z

69

Recent progress in InGaAsSb/GaSb TPV devices  

SciTech Connect (OSTI)

AstroPower is developing InGaAsSb thermophotovoltaic (TPV) devices. This photovoltaic cell is a two-layer epitaxial InGaAsSb structure formed by liquid-phase epitaxy on a GaSb substrate. The (direct) bandgap of the In{sub 1{minus}x}Ga{sub x}As{sub 1{minus}y}Sb{sub y} alloy is 0.50 to 0.55 eV, depending on its exact alloy composition (x,y); and is closely lattice-matched to the GaSb substrate. The use of the quaternary alloy, as opposed to a ternary alloy--such as, for example InGaAs/InP--permits low bandgap devices optimized for 1,000 to 1,500 C thermal sources with, at the same time, near-exact lattice matching to the GaSb substrate. Lattice matching is important since even a small degree of lattice mismatch degrades device performance and reliability and increases processing complexity. Internal quantum efficiencies as high as 95% have been measured at a wavelength of 2 microns. At 1 micron wavelengths, internal quantum efficiencies of 55% have been observed. The open-circuit voltage at currents of 0.3 A/cm{sup 2} is 0.220 volts and 0.280 V for current densities of 2 A/cm{sup 2}. Fill factors of 56% have been measured at 60 mA/cm{sup 2}. However, as current density increases there is some decrease in fill factor. The results to date show that the GaSb-based quaternary compounds provide a viable and high performance energy conversion solution for thermophotovoltaic systems operating with 1,000 to 1,500 C source temperatures.

Shellenbarger, Z.A.; Mauk, M.G.; DiNetta, L.C. [AstroPower, Inc., Newark, DE (United States); Charache, G.W. [Lockheed Martin Corp., Schenectady, NY (United States)

1996-05-01T23:59:59.000Z

70

Ash Deposition Behavior of Upgraded Brown Coal and Bituminous Coal  

Science Journals Connector (OSTI)

Ash Deposition Behavior of Upgraded Brown Coal and Bituminous Coal ... Ash with a low melting point causes slagging and fouling problems in pulverized coal combustion boilers. ... The ash composition in coal and operational conditions in boilers such as heat load greatly affect the ash deposition behavior. ...

Katsuya Akiyama; Haeyang Pak; Toshiya Tada; Yasuaki Ueki; Ryo Yoshiie; Ichiro Naruse

2010-07-22T23:59:59.000Z

71

Fusibility and sintering characteristics of ash  

SciTech Connect (OSTI)

The temperature characteristics of ash fusibility are studied for a wide range of bituminous and brown coals, lignites, and shales with ratios R{sub B/A} of their alkaline and acid components between 0.03 and 4. Acritical value of R{sub B/A} is found at which the fusion temperatures are minimal. The sintering properties of the ashes are determined by measuring the force required to fracture a cylindrical sample. It is found that the strength of the samples increases sharply at certain temperatures. The alkali metal content of the ashes has a strong effect on their sintering characteristics.

Ots, A. A., E-mail: aots@sti.ttu.ee [Tallinn University of Technology (Estonia)

2012-03-15T23:59:59.000Z

72

Rocky Flats ash test procedure (sludge stabilization)  

SciTech Connect (OSTI)

Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. This test will also gain information on the effects of the glovebox atmosphere (moisture) on the stabilized material. This document provides instructions for testing Rocky Flats Ash in the HC-21C muffle furnace process.

Winstead, M.L.

1995-09-14T23:59:59.000Z

73

Fluidized bed gasification ash reduction and removal process  

DOE Patents [OSTI]

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-12-04T23:59:59.000Z

74

Fluidized bed gasification ash reduction and removal system  

DOE Patents [OSTI]

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-02-28T23:59:59.000Z

75

RHEOLOGICAL AND ELEMENTAL ANALYSES OF SIMULANT SB5 SLURRY MIX EVAPORATOR-MELTER FEED TANK SLURRIES  

SciTech Connect (OSTI)

The Defense Waste Processing Facility (DWPF) will complete Sludge Batch 5 (SB5) processing in fiscal year 2010. DWPF has experienced multiple feed stoppages for the SB5 Melter Feed Tank (MFT) due to clogs. Melter throughput is decreased not only due to the feed stoppage, but also because dilution of the feed by addition of prime water (about 60 gallons), which is required to restart the MFT pump. SB5 conditions are different from previous batches in one respect: pH of the Slurry Mix Evaporator (SME) product (9 for SB5 vs. 7 for SB4). Since a higher pH could cause gel formation, due in part to greater leaching from the glass frit into the supernate, SRNL studies were undertaken to check this hypothesis. The clogging issue is addressed by this simulant work, requested via a technical task request from DWPF. The experiments were conducted at Aiken County Technology Laboratory (ACTL) wherein a non-radioactive simulant consisting of SB5 Sludge Receipt and Adjustment Tank (SRAT) product simulant and frit was subjected to a 30 hour SME cycle at two different pH levels, 7.5 and 10; the boiling was completed over a period of six days. Rheology and supernate elemental composition measurements were conducted. The caustic run exhibited foaming once, after 30 minutes of boiling. It was expected that caustic boiling would exhibit a greater leaching rate, which could cause formation of sodium aluminosilicate and would allow gel formation to increase the thickness of the simulant. Xray Diffraction (XRD) measurements of the simulant did not detect crystalline sodium aluminosilicate, a possible gel formation species. Instead, it was observed that caustic conditions, but not necessarily boiling time, induced greater thickness, but lowered the leach rate. Leaching consists of the formation of metal hydroxides from the oxides, formation of boric acid from the boron oxide, and dissolution of SiO{sub 2}, the major frit component. It is likely that the observed precipitation of Mg(OH){sub 2} and Mn(OH){sub 2} caused the increase in yield stress. The low pH run exhibited as much as an order of magnitude greater B and Li (frit components) leachate concentrations in the supernate. At high pH a decrease of B leaching was found and this was attributed to adsorption onto Mg(OH){sub 2}. A second leaching experiment was performed without any sludge to deconvolute the leach rate behavior of Frit 418 from those of the SB5 sludge-Frit 418 system. At high pH, the sludgeless system demonstrated very fast leaching of all the frit components, primarily due to fast dissolution of the main component, silica, by hydroxide anion; various semiconductor studies have established this reactivity. Overall, the frit-water system exhibited greater leaching from a factor two to almost three orders of magnitude (varying by conditions and species). The slower leaching of the sludge system is possibly due to a greater ionic strength or smaller driving force. Another possible reason is a physical effect, coating of the frit particles with sludge; this would increase the mass transfer resistance to leaching. Based on this study, the cause of clogs in the melter feed loop is still unknown. A possible explanation is that the SME product, like the simulant, is too thin and could contribute to a loss of two-phase flow which could cause plugging of a restricted and poorly mixed zone like the melter feed loop. This is feasible since a previous study of a slurry showed an increase in resistance to flow at lower flow rates. Testing with a radioactive SME sample is underway and should help understand this potential mechanism.

Fernandez, A.

2010-02-08T23:59:59.000Z

76

Fly ash system technology improves opacity  

SciTech Connect (OSTI)

Unit 3 of the Dave Johnston Power Plant east of Glenrock, WY, USA had problems staying at or below the opacity limits set by the state. The unit makes use of a Lodge Cottrell precipitator. When the plant changed to burning Power River Basin coal, ash buildup became a significant issue as the fly ash control system was unable to properly evacuate hoppers on the unit. To overcome the problem, the PLC on the unit was replaced with a software optimization package called SmartAsh for the precipitator fly ash control system, at a cost of $500,000. After the upgrade, there have been no plugged hoppers and the opacity has been reduced from around 20% to 3-5%. 2 figs.

NONE

2007-06-15T23:59:59.000Z

77

Aqueous alteration of municipal solid waste ash  

SciTech Connect (OSTI)

Municipal solid waste (MSW) ash is composed largely of amorphous oxides and approximately 20% minerals including halite, magnetite, hematite, quartz, gypsum, calcite, and rutile. It is also enriched in toxic trace metals by up to three orders of magnitude over average soil. The thermodynamic stabilities and rates of dissolution of the minerals and glasses in MSW ash will determine whether the ash is an environmental problem. The authors have used batch reactors at 20, 40, and 60 C over time periods up to 60 days to simulate longer reaction times for ash under cooler landfill conditions. Soluble salts are most quickly dissolved, giving solutions dominated by Ca[sup 2+], Na[sup +], K[sup +], SO[sub 2][sup 2[minus

Kirby, C.S.; Rimstidt, J.D. (Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States))

1992-01-01T23:59:59.000Z

78

Carbonation of FBC ash by sonochemical treatment  

Science Journals Connector (OSTI)

This work explores the sonochemical-enhanced carbonation of FBC ash for direct disposal in landfills. Tests have been conducted using four ashes originating from three commercial CFBC boilers. Experiments with additives such as NaCl and seawater have also been carried out. Tests were performed at low (20°, 40 °C) and high (60°, 80 °C) temperatures. Sonicated samples were analyzed using TGA, TGA–FTIR and XRD techniques to determine the influence of other calcium compounds (OCC). The particle size reduction brought about by sonication was quantified using wet sieving. The ash reactivity displays a strong temperature dependency with almost complete carbonation achieved in minutes at higher temperatures. Additives were found to increase the level of hydration of the ashes, in line with previous work; however, carbonation levels were unaffected. TGA, TGA–FTIR and XRD analysis of the samples indicated participation of OCC, which were also formed during hydration.

A. Rao; E.J. Anthony; L. Jia; A. Macchi

2007-01-01T23:59:59.000Z

79

Rocky Flats Ash test procedure (sludge stabilization)  

SciTech Connect (OSTI)

Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. The test will provide information to determine charge sizes, soak times and mesh screen sizes (if available at time of test) for stabilization of Rocky Flats Ash items to be processed in the HC-21C Muffle Furnace Process. Once the charge size and soak times have been established, a program for the temperature controller of the HC-21C Muffle Furnace process will be generated for processing Rocky Flats Ash.

Funston, G.A.

1995-06-14T23:59:59.000Z

80

Hydrothermal reactions of fly ash. Final report  

SciTech Connect (OSTI)

The emphasis of the work done has been to determine the reactivities of two ashes believed to be representative of those generated. A bituminous ash and a lignitic ash have been investigated. The reactions of these ashes undergo when subjected to mild hydrothermal conditions were explored. The nature of the reactions which the ashes undergo when alkaline activators, calcium hydroxide and calcium sulfate are present was also investigated. It was determined that calcium silicate hydrate, calcium aluminate hydrate, and the calcium sulfoaluminate hydrate ettringite form under these conditions. It appears 3CaO{center_dot}Al{sub 2}O{sub 3}{center_dot}3CaSO{sub 4}{center_dot}32H{sub 2}O (ettringite) formation needs to be considered in ashes which contain significant amounts of sulfate. Therefore the stability region for ettringite was established. It was also determined that calcium silicate hydrate, exhibiting a high internal surface area, will readily form with hydrothermal treatment between 50{degrees} and 100{degrees}C. This phase is likely to have a significant capacity to take up heavy metals and oxyanions and this ability is being explored.

Brown, P.W.

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Flue gas desulfurization gypsum and fly ash  

SciTech Connect (OSTI)

The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

Not Available

1992-05-01T23:59:59.000Z

82

E-Print Network 3.0 - ash technical progress Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and economic benefits. (1) Fly ash... of coal in conventional and or advanced clean coal technology combustors. These include fly ash, bottom... ash, boiler slag, and flue...

83

E-Print Network 3.0 - ash blended cement Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CLSM mixture utilized... . CHARACTERIZATION AND APPLICATION OF CLASS F FLY ASH AND CLEAN-COAL ASH FOR CEMENT-BASED MATERIALS 2 The major... investigation. Two additional ash ......

84

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

SciTech Connect (OSTI)

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

85

Characteristics and distribution of potential ash tree hosts for emerald ash borer  

Science Journals Connector (OSTI)

The emerald ash borer (EAB) (Agrilus planipennis) is a recently discovered (July 2002) exotic insect pest, which has caused the death of millions of ash trees (Fraxinus spp.) in Detroit, MI, USA and has also spread into other areas of Michigan, isolated locations in Indiana, Ohio, Maryland and Virginia, and nearby Windsor, Ont., in Canada. Ash trees occur in many different forest ecosystems in North America, are one of the more widely planted trees in urban areas, and are a valuable commercial timber species. If emerald ash borer populations are not contained and eventually eradicated, the ash resource in North America could be devastated. The destruction caused by EAB and its rate of spread are likely to be strongly influenced by the spatial distribution and status of the ash tree host, but general information regarding the abundance, health and distribution of ash trees is diffused throughout the literature. Here, we summarize what is currently known regarding the characteristics and potential spatial distribution of various species of Fraxinus in natural and planted ecosystems in North America and evaluate this information with specific regard to assessing the relative risk of ash populations to EAB.

David W. MacFarlane; Shawna Patterson Meyer

2005-01-01T23:59:59.000Z

86

Utilization of ash from fluidized bed boilers  

SciTech Connect (OSTI)

Combustion ash from a fluidized bed combustion (FBC) boiler contains not only carbon, but also silica alumina, quicklime as a sorbent, and a calcium sulfate by-product. These substances react chemically during fluidized bed combustion, and with the addition of water, they start an ettringite reaction and solidify. We determined the conditions necessary for producing hard solids through the study of the composition, curing methods, and characteristics of the solidified ash. We then used two types of road base material, crushed stone and solidified ash from an FBC boiler, to construct a test road at a site with a great deal of heavy traffic. Construction began in 1985, and since then, periodic tests have been performed to evaluate the performance of the road base materials. The testing of the manufacturing techniques centered on the amount and manner that water was added to the mixture and the curing methods of the mixture. Additional testing focused on the handling of the ash powder, the mixtures, and the solidified ash. Since 1991, under the sponsorship of MITI, the Center for Coal Utilization, in conjunction with Naruto Salt Mfg., Ltd., Nippon Hodo Co., Ltd., and Kawasaki Heavy Industries, Ltd., has used the referenced results to undertake a joint research and development project aimed at the eventual practical application of the technology. In 1993, a pilot facility to solidify ash with the fluidized bed boiler of 75 t/h capacity was completed. At present, all the discharged ash from the pilot facility is being solidified, and experiments on solidification and road base application techniques are underway. Actual road base tests are also in progress, and we are continuing research to meet the national certification requirements for road base materials.

Takada, Tomoaki [Kawasaki Heavy Industries Co., Ltd., Akashi (Japan)

1994-12-31T23:59:59.000Z

87

Thermal Evaporation and Characterization of Sb2Se3 Thin Film for Substrate Sb2Se3/CdS Solar Cells  

Science Journals Connector (OSTI)

Thermal Evaporation and Characterization of Sb2Se3 Thin Film for Substrate Sb2Se3/CdS Solar Cells ... Here we report Sb2Se3 solar cells fabricated from thermal evaporation. ... Sb2Se3; thermal evaporation; thin film; solar cells ...

Xinsheng Liu; Jie Chen; Miao Luo; Meiying Leng; Zhe Xia; Ying Zhou; Sikai Qin; Ding-Jiang Xue; Lu Lv; Han Huang; Dongmei Niu; Jiang Tang

2014-06-12T23:59:59.000Z

88

E-Print Network 3.0 - amorphous ge-sb-te films Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

times in GeSbTe films irradiated... commercial phase-change optical recording systems, such as those based on GeSbTe Ref. 3 or AglnSbTe,4 use... the crystalline and...

89

Ash aerosol formation from oxy-coal combustion and its relation to ash deposit chemistry  

Science Journals Connector (OSTI)

Abstract Ash aerosol and ash deposit formation during oxy-coal combustion were explored through experiments in a self-sustained 100 kW rated down-fired oxy-fuel combustor. Inlet oxidant conditions consisted of 50% inlet oxygen with CO2 (hereafter denoted as OXY50 conditions). A Berner low pressure impactor (BLPI), a scanning mobility particle sizer (SMPS), and an aerodynamic particle sizer (APS) were used to obtain size segregated ash aerosol samples and to determine the particle size distributions (PSD). A novel surface temperature controlled ash deposition probe system that allowed inside and outside deposits to be separated was used to collect the ash deposits. The ash aerosol \\{PSDs\\} given by the BLPI and those produced by SMPS/APS were consistent with each other. Data suggested that oxy-coal combustion under these conditions did not change the formation mechanisms controlling the bulk ash aerosol composition, but it did increase the formation of ultra-fine particles initially formed through metal vaporization, due to increased vaporization of silicon at the higher combustion temperature. The smaller particles contained within the deposits had higher Si and lower Na and S concentrations under OXY50 conditions than for air combustion. Moreover, the ash aerosol composition for particle sizes less than 2.4 ?m was related to the composition of the inside deposits. A higher Na in the ash aerosol resulted in higher Na in inside deposits with comparable absolute Na concentrations in both those aerosol particles and those inside deposits particles. The contribution of S and Si to the inside deposits showed that S in the vaporization modes together with Si in the ultrafine vaporization mode, contributed significantly to the composition of the inside deposits. These results provided direct evidence that prediction of the chemistry of the initial deposit layer (but not of the bulk deposits) required knowledge of the size segregated chemistry of the ash aerosol.

Zhonghua Zhan; Andrew Fry; Yanwei Zhang; Jost O.L. Wendt

2014-01-01T23:59:59.000Z

90

SLUDGE BATCH 7 ACCEPTANCE EVALUATION: RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB7 QUALIFICATION SAMPLE PREPARED AT SRNL  

SciTech Connect (OSTI)

Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Seven (SB7) for processing in the Defense Waste Processing Facility (DWPF). The SB7 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB6. The radionuclide concentrations were measured or estimated in the Tank 51 SB7 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter qualification sample of Tank 51 sludge slurry (HTF-51-10-125) received on September 18, 2010. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. With consultation from the Liquid Waste Organization, the qualification sample was then modified by several washes and decants, which included addition of Pu from H Canyon and sodium nitrite per the Tank Farm corrosion control program. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Tank 40. Determining the radionuclide concentrations in this Tank 51 SB7 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2010-0031. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task I.2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task III.2.) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB7 will be taken and transferred to SRNL for measurement of these radionuclides. The results presented in this report are those necessary for DWPF to assess if the Tank 51 SB7 sample prepared at SRNL meets the requirements for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria evaluation, and the DWPF Solid Waste Characterization Program. Concentrations are given for thirty-four radionuclides along with total alpha and beta activity. Values for total gamma and total gamma plus beta activities are also calculated.

Pareizs, J.; Hay, M.

2011-02-22T23:59:59.000Z

91

K2CsSb Cathode Development  

SciTech Connect (OSTI)

K{sub 2}CsSb is an attractive photocathode for high current applications. With a quantum efficiency of >4% at 532nm and >10% at 355nm, it is the only cathode to have demonstrated an average current of 35mA in an accelerator environment We describe ongoing cathode development work. for the energy recovery linac being constructed at BNL Several cathodes have been created on both copper and stainless steel substrates, and their spatial uniformity and spectral response have been characterized. Preliminary lifetime measurements have been performed at high average current densities (>1 mA/mm{sup 2}).

Smedley,J.; Rao, T.; Wang, E.

2008-10-01T23:59:59.000Z

92

Coal ash behavior in reducing environments  

SciTech Connect (OSTI)

This project is a four-year program designed to investigate the transformations and properties of coal ash in reducing environment systems. This project is currently midway through its third year. The work to date has emphasized four areas of research: (1) the development of quantitative techniques to analyze reduced species, (2) the production of gasification-type samples under closely controlled conditions, (3) the systematic gasification of specific coals to produce information about their partitioning during gasification, and (4) the study of the physical properties of ashes and slags under reducing atmospheres. The project is organized into three tasks which provide a strong foundation for the project. Task 1, Analytical Methods Development, has concentrated on the special needs of analyzing samples produced under a reducing atmosphere as opposed to the more often studied combustion systems. Task 2, Inorganic Partitioning and Ash Deposition, has focused on the production of gasification-type samples under closely controlled conditions for the study of inorganic partitioning that may lead to deposition. Task 3, Ash and Slag Physical Properties, has made large gains in the areas of sintering and strength development of coal ashes under reducing atmospheres for the evaluation of deposition problems. Results are presented for all three tasks.

Benson, S.A.; Erickson, T.A.; Brekke, D.W.; Folkedahl, B.C.; Tibbetts, J.E.; Nowok, J.W.

1994-10-01T23:59:59.000Z

93

Leaching of elements from bottom ash, economizer fly ash, and fly ash from two coal-fired power plants  

Science Journals Connector (OSTI)

To assess how elements leach from several types of coal combustion products (CCPs) and to better understand possible risks from CCP use or disposal, coal ashes were sampled from two bituminous-coal-fired power plants. One plant located in Ohio burns high-sulfur (about 3.9%) Upper Pennsylvanian Pittsburgh coal from the Monongahela Group of the Central Appalachian Basin; the other in New Mexico burns low-sulfur (about 0.76%) Upper Cretaceous Fruitland Formation coal from the San Juan Basin, Colorado Plateau. The sampled \\{CCPs\\} from the Ohio plant were bottom ash (BA), economizer fly ash (EFA), and fly ash (FA); the sampled \\{CCPs\\} from the New Mexico plant were BA, mixed FA/EFA, FA, and cyclone-separated coarse and fine fractions of a FA/EFA and FA blend. Subsamples of each ash were leached using the long-term leaching (60-day duration) component of the synthetic groundwater leaching procedure (SGLP) or the toxicity characteristic leaching procedure (TCLP, 18-hour duration). These ashes were all alkaline. Leachate concentrations and leachabilities of the elements from the \\{CCPs\\} were similar between corresponding CCP types (BA, EFA, and FA) from each plant. The leachabilities of most elements were lowest in BA (least leachable) and increased from EFA to FA (most leachable). Ca and Sr were leached more from EFA than from either BA or FA. Leachability of most elements also increased as FA particle size decreased, possibly due in part to increasing specific surface areas. Several oxyanion-forming elements (As, Mo, Se, U, and V) leached more under SGLP than under TCLP; the opposite was true for most other elements analyzed.

Kevin B. Jones; Leslie F. Ruppert; Sharon M. Swanson

2012-01-01T23:59:59.000Z

94

Influence of Particle Morphology on the Hydraulic Behavior of Coal Ash and Sand  

Science Journals Connector (OSTI)

Residues of thermo electrical power plants are generically known as ashes, and can be classifies as slag, bottom ash and fly ash. Slag has a high content of unburned ... %) and coarse grains or clods. Bottom ash ...

Karla Salvagni Heineck; Rosemar Gomes Lemos…

2010-07-01T23:59:59.000Z

95

Ash limitation of physical coal beneficiation for medium–high ash coal—A geochemistry perspective  

Science Journals Connector (OSTI)

Abstract Nowadays the industrial coal beneficiation in China could only reduce the ash yield to about 10%, which could not meet the requirement or standard of environment protection. In this work, the possibility of reducing the ash yield was studied from the aspect of geochemistry. The channel samples were collected from two coal seams in Guizhou and Shanxi province, China and then conducted analysis by combining data from coals worldwide. The result reveals that the same coal seam or the coals deposited in the same peat swamp show a significantly positive correlation between ash yield and Al2O3 + SiO2 content, and the intercept of regression equation on the ash axis is always less than 5% (generally 2–5%). Overall, the coal from China is featured with a higher intercept compared with that in the other countries. The intercept of 2–5% on the ash axis indicates an original inorganic component in coal-forming peat. The research result also presents a theoretical limitation of coal ash by coal cleaning, because 2–5% of inorganic components in medium–high quality ash coal could hardly be separated by traditional physical coal beneficiation.

Wenfeng Wang; Weiduo Hao; Simon Xu; Fuchang Qian; Shuxun Sang; Yong Qin

2014-01-01T23:59:59.000Z

96

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, M.; Wai, C.M.; Nagy, Z.

1983-08-15T23:59:59.000Z

97

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

1984-01-01T23:59:59.000Z

98

Grain characteristics and engineering properties of coal ash  

Science Journals Connector (OSTI)

?Ash produced by the coal fired thermal plants is often used as ... the grain characteristics and the engineering properties of coal ash. The results of x-ray diffraction, ... characteristic that may be used for ...

A. Trivedi; V. K. Sud

2002-12-01T23:59:59.000Z

99

The Leaching of Major and Trace Elements from Coal Ash  

Science Journals Connector (OSTI)

Most power stations currently operate wet ash disposal systems. However, this method of ash disposal is being subjected to increasing scrutiny as there is a potential for contamination of surface and groundwat...

D. R. Jones

1995-01-01T23:59:59.000Z

100

High carbon fly ash finds uses in highway construction  

SciTech Connect (OSTI)

The beneficial use of high carbon fly ash in a highway construction project is discussed. The fly ash also had a relatively high content of mercury and some other heavy metals. 1 fig., 4 photos.

Wen, H.; Patton, R. [University of Wisconsin at Madison, Madison, WI (United States). Recycled Materials Resources Center

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Leaching of Selected Elements from Coal Ash Dumping  

Science Journals Connector (OSTI)

Coal ash obtained by coal combustion in the "Nikola Tesla A ... ionic strength of river water, we extracted coal ash with distilled water and 0.002 M–...3. The results show that changes in river water ionic ...

A. Popovic; D. Radmanovic; D. Djordjevic; P. Polic

2005-01-01T23:59:59.000Z

102

Eco-friendly fly ash utilization: potential for land application  

SciTech Connect (OSTI)

The increase in demand for power in domestic, agricultural, and industrial sectors has increased the pressure on coal combustion and aggravated the problem of fly ash generation/disposal. Consequently the research targeting effective utilization of fly ash has also gained momentum. Fly ash has proved to be an economical substitute for expensive adsorbents as well as a suitable raw material for brick manufacturing, zeolite synthesis, etc. Fly ash is a reservoir of essential minerals but is deficient in nitrogen and phosphorus. By amending fly ash with soil and/or various organic materials (sewage sludge, bioprocess materials) as well as microbial inoculants like mycorrhizae, enhanced plant growth can be realized. Based on the sound results of large scale studies, fly ash utilization has grown into prominent discipline supported by various internationally renowned organizations. This paper reviews attempts directed toward various utilization of fly ash, with an emphasis on land application of organic/microbial inoculants amended fly ash.

Malik, A.; Thapliyal, A. [Indian Institute of Technology Delhi, New Delhi (India)

2009-07-01T23:59:59.000Z

103

It's Elemental - The Element Sodium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Neon Neon Previous Element (Neon) The Periodic Table of Elements Next Element (Magnesium) Magnesium The Element Sodium [Click for Isotope Data] 11 Na Sodium 22.98976928 Atomic Number: 11 Atomic Weight: 22.98976928 Melting Point: 370.95 K (97.80°C or 208.04°F) Boiling Point: 1156 K (883°C or 1621°F) Density: 0.97 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 1 Group Name: Alkali Metal What's in a name? From the English word soda and from the Medieval Latin word sodanum, which means "headache remedy." Sodium's chemical symbol comes from the Latin word for sodium carbonate, natrium. Say what? Sodium is pronounced as SO-dee-em. History and Uses: Although sodium is the sixth most abundant element on earth and comprises

104

POLYVINYLCHLORIDE WASTE WITH OIL SHALE ASH TO CAPTURE  

E-Print Network [OSTI]

alkaline oil shale ash. Solid heat carrier (Galoter process)-type oil shale retorting units, where the

V. Oja; A. Elenurm; I. Rohtla; E. Tearo; E. Tali

105

Measurement of the Sintering Kinetics of Coal Ash  

Science Journals Connector (OSTI)

Measurement of the Sintering Kinetics of Coal Ash ... A new technique has been developed to determine the sintering rate of coal ash based on the measurement of the pressure-drop across a pellet of ash. ... The technique developed in this study shows a good repeatability of the rate of sintering and confirms that viscous flow is the dominant mechanism for sintering of coal ash. ...

A. Y. Al-Otoom; L. K. Elliott; T. F. Wall; B. Moghtaderi

2000-08-16T23:59:59.000Z

106

Coal-ash spills highlight ongoing risk to ecosystems  

Science Journals Connector (OSTI)

Coal-ash spills highlight ongoing risk to ecosystems ... A holding pond for coal ash collapsed, releasing billions of gallons of coal-ash sludge onto nearby farmland and into the waters of the Emory and Tennessee rivers. ... For decades, researchers, environmental advocates, local communities, and even the U.S. EPA have been concerned about the ongoing risks posed by the unregulated management of coal ash. ...

Rhitu Chatterjee

2009-03-25T23:59:59.000Z

107

Zeolite formation from coal fly ash and its adsorption potential  

SciTech Connect (OSTI)

The possibility in converting coal fly ash (CFA) to zeolite was evaluated. CFA samples from the local power plant in Prachinburi province, Thailand, were collected during a 3-month time span to account for the inconsistency of the CFA quality, and it was evident that the deviation of the quality of the raw material did not have significant effects on the synthesis. The zeolite product was found to be type X. The most suitable weight ratio of sodium hydroxide (NaOH) to CFA was approximately 2.25, because this gave reasonably high zeolite yield with good cation exchange capacity (CEC). The silica (Si)-to-aluminum (Al) molar ratio of 4.06 yielded the highest crystallinity level for zeolite X at 79% with a CEC of 240 meq/100 g and a surface area of 325 m{sup 2}/g. Optimal crystallization temperature and time were 90{sup o}C and 4 hr, respectively, which gave the highest CEC of approximately 305 meq/100 g. Yields obtained from all experiments were in the range of 50-72%. 29 refs., 5 tabs., 7 figs.

Duangkamol Ruen-ngam; Doungmanee Rungsuk; Ronbanchob Apiratikul; Prasert Pavasant [Chulalongkorn University, Bangkok (Thailand). Department of Chemical Engineering

2009-10-15T23:59:59.000Z

108

Fractionation and transport of nutrients among coal ash residues and in soil covered with fly ash-amended organic compost  

Science Journals Connector (OSTI)

Coal-fired power plants generate different types of ash residues and discharge small particles and vapors to the atmosphere. The ash residues which account for the major part ... the byproducts are collected and ...

M. P. Menon; K. S. Sajwan; G. S. Ghuman; J. James…

1993-07-01T23:59:59.000Z

109

Impact of Coal Ash Lagoons Upon the Surrounding Soils  

Science Journals Connector (OSTI)

Ash and slag are the waste products from thermal power stations (TPS). In one Polish TPS, 10,000 Mg of slag, and 48,700 Mg of ash are produced every year. All the slag is utilizedi whereas the ash is tipped of...

E. S. Kempa; A. J?drczak

1990-01-01T23:59:59.000Z

110

Maintaining and Improving Marketability of Coal Fly Ash  

E-Print Network [OSTI]

1 Maintaining and Improving Marketability of Coal Fly Ash John N. Ward Ben Franklin Headwaters;2 A Headline You May Have Seen What is the future of coal fly ash utilization in a mercury controls world? What is produced when coal is consumed by power plants Fly ash can be used beneficially in numerous applications

111

Utilization of CFB fly ash for construction applications  

SciTech Connect (OSTI)

Disposal in landfills has been the most common means of handling ash in circulating fluidized bed (CFB) boiler power plants. Recently, larger CFB boilers with generating capacities up to 300 MWe are currently being planned, resulting in increased volumes and disposal cost of ash by-product. Studies have shown that CFB ashes do not pose environmental concerns that should significantly limit their potential utilization. Many uses of CFB ash are being investigated by Foster Wheeler, which can provide more cost-effective ash management. Construction applications have been identified as one of the major uses for CFB ashes. Typically, CFB ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. However, CFB ashes can be used for other construction applications that require less stringent specifications including soil stabilization, road base, structural fill, and synthetic aggregate. In this study, potential construction applications were identified for fly ashes from several CFB boilers firing diverse fuels such as petroleum coke, refuse derived fuel (RDF) and coal. The compressive strength of hydrated fly ashes was measured in order to screen their potential for use in various construction applications. Based on the results of this work, the effects of both ash chemistry and carbon content on utilization potential were ascertained. Actual beneficial uses of ashes evaluated in this study are also discussed.

Conn, R.E.; Sellakumar, K.; Bland, A.E.

1999-07-01T23:59:59.000Z

112

Inductively Coupled Plasma Reactive Ion Etching of AlGaAsSb and InGaAsSb for Quaternary Antimonide MIM Thermophotovoltaics  

SciTech Connect (OSTI)

In this letter we report on the inductively coupled plasma reactive ion etching (ICP-RIE) of InGaAsSb and AlGaAsSb for the fabrication of quaternary monolithic interconnected module (MIM) thermophotovoltaic (TPV) devices. A rapid dry etch process is described that produces smooth surfaces using BCl[sub]3 for AlGaAsSb and InGaAsSb capped with GaSb. Uncapped InGaAsSb was etched by adding an H[sub]2 plasma preclean to reduce surface oxides. InGaAsSb etch rate was studied as a function of accelerating voltage, RF power, temperature and pressure. The etch conditions found for InGaAsSb were used for AlGaAsSb etching to determine the effectiveness for isolation of the MIM cells.

Palmisiano, M. N.; Peake, G. M.; Shul, R. J.; Ashby, C. I.; Cederberg, J. G.; Hafich, M. J.; Biefeld, R. M.

2002-10-01T23:59:59.000Z

113

Enhanced optical property in quaternary GaInAsSb/AlGaAsSb quantum wells  

SciTech Connect (OSTI)

High quality GaInAsSb/AlGaAsSb quantum wells (QWs) have been grown by molecular beam epitaxy using proper interface treatments. By controlling the group-V elements at interfaces, we obtained excellent optical quality QWs, which were free from undesired localized trap states, which may otherwise severely affect the exciton recombination. Strong and highly efficient exciton emissions up to room temperature with a wavelength of 2.2 ?m were observed. A comprehensive investigation on the QW quality was carried out using temperature dependent and power dependent photoluminescence (PL) measurements. The PL emission intensity remains nearly constant at low temperatures and is free from the PL quenching from the defect induced localized states. The temperature dependent emission energy had a bulk-like behavior, indicating high quality well/barrier interfaces. Because of the uniformity of the QWs and smooth interfaces, the low temperature limit of inhomogeneous line width broadening is as small as 5?meV.

Lin, Chien-Hung, E-mail: chlin.ee97g@g2.nctu.edu.tw; Lee, Chien-Ping [Department of Electronics Engineering, National Chiao Tung University, 1001 University Road, Hsinchu 30010, Taiwan (China)

2014-10-21T23:59:59.000Z

114

The reaction mechanism of SnSb and Sb thin film anodes for Na-ion batteries studied by X-ray diffraction, 119Sn and 121Sb M ssbauer spectroscopies  

SciTech Connect (OSTI)

The electrochemical reaction of Sb and SnSb anode materials with Na results in the formation of amorphous materials. To understand the resulting phases and electrochemical capacities we studied the reaction products local order using 119Sn and 121Sb M ssbauer spectroscopies in conjunction with measurements performed on model powder compounds of Na-Sn and Na-Sb to further clarify the reactions steps. For pure Sb the discharge (sodiation) starts with the formation of an amorphous phase composed of atomic environments similar to those found in NaSb, and proceeds further by the formation of environments similar to that present in Na3Sb. The reversible reaction takes place during a large portion of the charge process. At full charge the anode material still contains a substantial fraction of Na, which explains the lack of recrystallization into crystalline Sb. The reaction of SnSb yields Na3Sb crystalline phase at full discharge at higher temperatures (65 and 95 C) while the room temperature reaction yields amorphous compounds. The electrochemically-driven, solid-state amorphization reaction occurring at room temperature is governed by the simultaneous formation of Na-coordinated Sn and Sb environments, as monitored by the decrease (increase) of the 119Sn (121Sb) M ssbauer isomer shifts. Overall, the monitoring of the hyperfine parameters enables to correlate the changes in Na content to the individual Sn and Sb local chemical environments.

Baggetto, Loic [ORNL; Hah, Hien-Yoong [University of Tennessee (UT) Space Institute; Jumas, Dr. Jean-Claude [Institut Charles Gerhardt, University of Montpellier II, FRANCE; Johnson, Prof. Dr. Charles E. [University of Tennessee (UT) Space Institute; Johnson, Jackie A. [University of Tennessee (UT) Space Institute; Keum, Jong Kahk [ORNL; Bridges, Craig A [ORNL; Veith, Gabriel M [ORNL

2014-01-01T23:59:59.000Z

115

Thermophysical Properties of Sodium Nitrate and Sodium Chloride  

Office of Scientific and Technical Information (OSTI)

Thermophysical Properties of Sodium Nitrate and Sodium Chloride Thermophysical Properties of Sodium Nitrate and Sodium Chloride Solutions and Their Effects on Fluid Flow in Unsaturated Media Tianfu Xu and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 ABSTRACT. Understanding movement of saline sodium nitrate (NaNO 3 ) waste solutions is important for assessing the contaminant migration near leaking waste storage tanks in the unsaturated zone at the Hanford site (Washington, USA). The purpose of this study is to contribute a basic understanding of effects of the thermophysical behavior of NaNO 3 solutions on fluid flow in unsaturated media. We first present mathematical expressions for the dependence of density, viscosity, solubility and vapor pressure of

116

Screening technology reduces ash in spiral circuits  

SciTech Connect (OSTI)

In 2006, the James River Coal Co. selected the Stack Sizer to remove the minus 100 mesh high ash clay fraction from the clean coal spiral product circuits at the McCoy-Elkhorn Bevins Branch prep plant and at the Blue Diamond Leatherwood prep plant in Kentucky. The Stack Sizer is a multi-deck, high-frequency vibrating screen capable of separations as fine as 75 microns when fitted with Derrick Corp.'s patented high open area urethane screen panels. Full-scale lab tests and more than 10 months of continuous production have confirmed that the Stack Sizer fitted with Derrick 100 micron urethane screen panels consistently produces a clean coal fraction that ranges from 8 to 10% ash. Currently, each five-deck Stack Sizer operating at the Bevins Branch and Leatherwood prep plants is producing approximately 33 tons per hour of clean coal containing about 9% ash. This represents a clean coal yield of about 75% and an ash reduction of about 11% from the feed slurry. 3 figs. 2 tabs.

Brodzik, P. [Derrick Corp., Buffalo, NY (United States)

2007-05-15T23:59:59.000Z

117

Improving clay content measurement in oxidic and volcanic ash soils of Hawaii by increasing dispersant concentration and ultrasonic energy levels  

Science Journals Connector (OSTI)

Abstract Quantifying clay content is a fundamental step in predicting and managing soil behaviors such as nutrient and water retention. However, clay measurements are underestimated when using standard methods of dispersion in soils rich in oxides and volcanic ash-derived non-crystalline minerals. Increasing levels of the chemical dispersant and ultrasonic energy are two simple techniques found to increase dispersion and clay measurements in temperate soils, but their effects are less known for oxidic and volcanic ash soils. In this study we investigated the effects of increasing dispersion concentration and ultrasonic energy on clay measurements for a range of oxidic and volcanic ash soils from Hawaii. While doubling and tripling the standard sodium hexametaphosphate concentration of 0.441 g L? 1 did not increase estimates of clay content, increasing levels of ultrasonic energy up to 1600 J mL? 1 significantly increased measured clay content for all oxide and volcanic ash soils. The response to ultrasonication was dependent on soil carbon, oxide content, and surface charge, with more energy needed to disperse soils higher in carbon, oxides, and positive charge. Scanning electron microscopy revealed damage to the sand fraction in some soils when ultrasonicated, but the extent of this damage was viewed as negligible. Porous sand-sized particles resembling pumice grains were also observed in some soils, suggesting that conventional particle size analysis and clay interpretations may not adequately describe surface related behaviors.

Joshua H.S. Silva; Jonathan L. Deenik; Russell S. Yost; Gregory L. Bruland; Susan E. Crow

2015-01-01T23:59:59.000Z

118

Characterization of improved InSb interfaces  

Science Journals Connector (OSTI)

Improved quality surfaces on n?type InSb have been produced using a low?temperature chemical vapor deposition (LTCVD) of SiO2 by pyrolytic decomposition of silane in the presence of oxygen. Preservation of the thin natural oxide on the InSbsurface through a suitable LTCVD process results in a surface state density ?1010 eV?1?cm?2 and without C–V hysteresis. Confirmation of these results is made by both quasistatic C–V and conductance measurements on MIS structures. Complications introduced by the presence of lateral nonuniformity of the LTCVD oxide and thus in the surface potential have been accounted for in the observed low density measurements. The presence chemical identification and thickness of the natural oxide both before and after the LTCVD process has been idependently confirmed by XPS. The apparent oxidation state and resultant electrical properties are identified with changes in LTCVD reactor conditions.

J. D. Langan; C. R. Viswanathan

1979-01-01T23:59:59.000Z

119

Sodium loop framework structural analysis  

SciTech Connect (OSTI)

This document provides the structural analysis of the Sodium Loop framework in a drop condition. The drop is similar to the US Department of Transportation non-bulk, performance-oriented packaging (Packaging Group I) drop test. The drop height evaluated for the Sodium Loop framework is 5.9 ft.

Nguyen, P.M.

1995-06-06T23:59:59.000Z

120

Planning for sustainable communities: Regional incentives and local policy under SB375  

E-Print Network [OSTI]

#12;SB 375: Sustainable Communities & Climate Protection Act (2008) isolation dispersion automobility

California at Davis, University of

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The variability of fly ash and its effects on selected properties of fresh Portland cement/fly ash mortars  

E-Print Network [OSTI]

fly ash production. Researchers have subsequently had the opportunity to develop a full body of knowledge concerning bitum1nous ash and its applications. The first s1gn1ficant use of b1tuminous fly ash probably occurred 20 in the 1940's when...THE VARIABILITY OF FLY ASH AND ITS EFFECTS ON SELECTED PROPERTIES OF FRESH PORTLAND CEi'1ENT/FLY ASH MORTARS A Thesis by WILLIAM CARLTON MCKERALL Submitted to the Graduate Co11ege of Texas A&M Uni ver s i ty in partia1 fu1fi11ment...

McKerall, William Carlton

1980-01-01T23:59:59.000Z

122

Tables of thermodynamic properties of sodium  

SciTech Connect (OSTI)

The thermodynamic properties of saturated sodium, superheated sodium, and subcooled sodium are tabulated as a function of temperature. The temperature ranges are 380 to 2508 K for saturated sodium, 500 to 2500 K for subcooled sodium, and 400 to 1600 K for superheated sodium. Tabulated thermodynamic properties are enthalpy, heat capacity, pressure, entropy, density, instantaneous thermal expansion coefficient, compressibility, and thermal pressure coefficient. Tables are given in SI units and cgs units.

Fink, J.K.

1982-06-01T23:59:59.000Z

123

Fly ash and concrete: a study determines whether biomass, or coal co-firing fly ash, can be used in concrete  

SciTech Connect (OSTI)

Current US national standards for using fly ash in concrete (ASTM C618) state that fly ash must come from coal combustion, thus precluding biomass-coal co-firing fly ash. The co-fired ash comes from a large and increasing fraction of US power plants due to rapid increases in co-firing opportunity fuels with coal. The fly ashes include coal fly ash, wood fly ash from pure wood combustion, biomass and coal co-fired fly ash SW1 and SW2. Also wood fly ash is blended with Class C or Class F to produce Wood C and Wood E. Concrete samples were prepared with fly ash replacing cement by 25%. All fly ash mixes except wood have a lower water demand than the pure cement mix. Fly ashes, either from coal or non coal combustion, increase the required air entraining agent (AEA) to meet the design specification of the mixes. If AEA is added arbitrarily without considering the amount or existence of fly ash results could lead to air content in concrete that is either too low or too high. Biomass fly ash does not impact concrete setting behaviour disproportionately. Switch grass-coal co-fired fly ash and blended wood fly ash generally lie within the range of pure coal fly ash strength. The 56 day flexure strength of all the fly ash mixes is comparable to that of the pure cement mix. The flexure strength from the coal-biomass co-fired fly ash does not differ much from pure coal fly ash. All fly ash concrete mixes exhibit lower chloride permeability than the pure cement mixes. In conclusion biomass coal co-fired fly ash perform similarly to coal fly ash in fresh and hardened concrete. As a result, there is no reason to exclude biomass-coal co-fired fly ash in concrete.

Wang, Shuangzhen; Baxter, Larry

2006-08-01T23:59:59.000Z

124

Independent Oversight Review, Sodium Bearing Waste Treatment...  

Energy Savers [EERE]

Federal - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Federal - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project -...

125

Independent Oversight Review, Sodium Bearing Waste Treatment...  

Energy Savers [EERE]

Contractor - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Contractor - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project...

126

SB Electronics Breaks Ground on New Factory | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

SB Electronics Breaks Ground on New Factory SB Electronics Breaks Ground on New Factory SB Electronics Breaks Ground on New Factory April 29, 2010 - 5:22pm Addthis U.S. Rep. Peter Welch (from left), Vermont Lt. Gov. Brian Dubie, SBE board member Win Hunter, SBE board chair Stan Fishkin, Assi U.S. Rep. Peter Welch (from left), Vermont Lt. Gov. Brian Dubie, SBE board member Win Hunter, SBE board chair Stan Fishkin, Assi Paul Lester Communications Specialist, Office of Energy Efficiency and Renewable Energy A Vermont company broke ground on a new factory that will produce cutting-edge technology for electric and hybrid cars and create more than 100 jobs. The event ushering in SB Electronics' power ring capacitor facility in Barre was attended by Vermont Gov. Jim Douglas and federal, state and local

127

Photoelectric and luminescence properties of GaSb-Based nanoheterostructures with a deep Al(As)Sb/InAsSb/Al(As)Sb quantum well grown by metalorganic vapor-phase epitaxy  

SciTech Connect (OSTI)

The luminescence and photoelectric properties of heterostructures with a deep Al(As)Sb/InAsSb/Al(As)Sb quantum well grown on n-GaSb substrates by metalorganic vapor-phase epitaxy are investigated. Intense superlinear luminescence and increased optical power as a function of the pump current in the photon energy range of 0.6-0.8 eV are observed at temperatures of T = 77 and 300 K. The photoelectric, current-voltage, and capacitance characteristics of these heterostructures are studied in detail. The photosensitivity is examined with photodetectors operating in the photovoltaic mode in the spectral range of 0.9-2.0 {mu}m. The sensitivity maximum at room temperature is observed at a wavelength of 1.55 {mu}m. The quantum efficiency, detectivity, and response time of the photodetectors were estimated. The quantum efficiency and detectivity at the peak of the photosensitivity spectrum are as high as {eta} = 0.6-0.7 and D{sub {lambda}max}{sup *} = (5-7) Multiplication-Sign 10{sup 10} cm Hz{sup 1/2} W{sup -1}, respectively. The photodiode response time determined as the rise time of the photoresponse pulse from 0.1 to the level 0.9 is 100-200 ps. The photodiode transmission bandwidth is 2-3 GHz. Photodetectors with a deep Al(As)Sb/InAsSb/Al(As)Sb quantum well grown on n-GaSb substrates are promising foruse in heterodyne detection systems and in information technologies.

Mikhailova, M. P.; Andreev, I. A., E-mail: igor@iropt9.ioffe.ru; Ivanov, E. V.; Konovalov, G. G.; Grebentshikova, E. A.; Yakovlev, Yu. P. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Hulicius, E.; Hospodkova, A.; Pangrac, Y. [Academy of Sciences of the Czech Republic, Institute of Physics (Czech Republic)] [Academy of Sciences of the Czech Republic, Institute of Physics (Czech Republic)

2013-08-15T23:59:59.000Z

128

Simulation of sodium boiling experiments with THERMIT sodium version  

E-Print Network [OSTI]

Natural and forced convection experiments(SBTF and French) are simulated with the sodium version of the thermal-hydraulic computer code THERMIT. Simulation is done for the test secti- -on with the pressure-velocity boundary ...

Huh, Kang Yul

1982-01-01T23:59:59.000Z

129

Application of solid ash based catalysts in heterogeneous catalysis  

SciTech Connect (OSTI)

Solid wastes, fly ash, and bottom ash are generated from coal and biomass combustion. Fly ash is mainly composed of various metal oxides and possesses higher thermal stability. Utilization of fly ash for other industrial applications provides a cost-effective and environmentally friendly way of recycling this solid waste, significantly reducing its environmental effects. On the one hand, due to the higher stability of its major component, aluminosilicates, fly ash could be employed as catalyst support by impregnation of other active components for various reactions. On the other hand, other chemical compounds in fly ash such as Fe{sub 2}O{sub 3} could also provide an active component making fly ash a catalyst for some reactions. In this paper, physicochemical properties of fly ash and its applications for heterogeneous catalysis as a catalyst support or catalyst in a variety of catalytic reactions were reviewed. Fly-ash-supported catalysts have shown good catalytic activities for H{sub 2} production, deSOx, deNOx, hydrocarbon oxidation, and hydrocracking, which are comparable to commercially used catalysts. As a catalyst itself, fly ash can also be effective for gas-phase oxidation of volatile organic compounds, aqueous-phase oxidation of organics, solid plastic pyrolysis, and solvent-free organic synthesis. 107 refs., 4 figs., 2 tabs.

Shaobin Wang [Curtin University of Technology, Perth, WA (Australia). Department of Chemical Engineering

2008-10-01T23:59:59.000Z

130

Ash fusibility and compositional data of solid recovered fuels  

Science Journals Connector (OSTI)

Several approaches are established to analyse the fouling and slagging propensities of coal ashes, but the same cannot be said of solid recovered fuel (SRF) ashes. This work has been conducted by using some fouling and slagging indicators, which are commonly applicable to coal ashes, on SRF ashes to ascertain their applicability. In this work, laboratory prepared ashes derived from municipal solid waste (MSW), sewage sludge, demolition wood, shredded rubber tyres, and plastic/paper fluff are analysed for their fusibility leading to fouling and slagging using three approaches; the ash fusibility temperatures (AFT), ternary phase diagrams, and fouling/slagging indices. The results from each approach are examined to determine the inclination of the ashes toward fouling and slagging. A subsequent inter-comparison of the methods was conducted to validate the methods which are in agreement and are applicable to SRF ashes. The study showed that ternary equilibrium phase diagram SiO2–CaO–Al2O3, various fouling and slagging indices, and AFT can be used to complement each other to predict ash fusion properties, fouling and slagging propensities of SRF ashes.

Gregory Dunnu; Jörg Maier; Günter Scheffknecht

2010-01-01T23:59:59.000Z

131

GaInAsSb/A1GaAsSb/Sb Thermophotovoltaic Devices With an Internal Back-Surface Reflector Formed by Wafer Bonding  

SciTech Connect (OSTI)

A novel implementation for GAInAsSb/AlGaAsSb/GaSb TPV cells with an internal back-surface reflector (BSR) formed by wafer bonding to GaAs is demonstrated. The SiO{sub x}/Ti/Au internal BSR enhances optical absorption within the device, while the dielectric layer provides electrical isolation. This configuration has the potential to improve TPV device performance; is compatible with monolithic series-interconnection of TPV cells for building voltage; and can mitigate the requirements of filters used for front-surface spectral control. At a short-circuit density of 0.4 A/cm{sup 2}, the open-circuit voltage of a single TPV cell is 0.2 V, compared to 0.37 and 1.8 V for 2- and 10-junction series-interconnected TPV cells, respectively.

C.A. Wang; R.K. Huang; D.A. Shiau; M.K. Connors; P.G. Murphy; P.W. O'brien; A.C. Anderson; D.M. DePoy; G. Nichols; M.N. Palmasiano

2002-12-18T23:59:59.000Z

132

Manufacture of ceramic tiles from fly ash  

DOE Patents [OSTI]

The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants. 6 figs.

Hnat, J.G.; Mathur, A.; Simpson, J.C.

1999-08-10T23:59:59.000Z

133

Organometallic Vapor Phase Epitaxy of n-GaSb and n-GaInAsSb for Low Resistance Ohmic Contacts  

SciTech Connect (OSTI)

A comparison of n-GaSb and n-GaInAsSb epilayers for ohmic contacts in GaSb-based devices is studied. The epilayers were grown by organometallic vapor phase epitaxy and doped with Te. At similar electron concentrations, the atomic Te concentration, as determined by secondary ion mass spectroscopy, is more than 2 times higher in n-GaSb compared to n-GaInAsSb. In addition, the electron mobility is lower in n-GaSb than n-GaInAsSb at similar electron concentrations. The electron concentration saturates at about 1.3 x 10{sup 18} cm{sup -3} for n-GaSb, but linearly increases for n-GaInAsSb. Pd/Ge/Au/Pt/Au metallization was studied for ohmic contacts. A specific contact resistivity of 1 x 10{sup -5}{Omega}-cm{sup 2} for n-GaSb was measured. The specific contact resistivity can be greatly improved by contacting n-GaInAsSb, and a significantly lower specific contact resistivity of 2 x 10{sup -6} {Omega}-cm{sup 2} for n-GaInAsSb was measured.

C.A. Wang; D.A. Shiau; R.K. Huang; C.T. Harris; M.K. Connors

2003-07-10T23:59:59.000Z

134

Vertical cavity surface emitting laser emitting at 1.56 microns with AlGaAsSb/AlAsSb distributed Bragg reflectors  

SciTech Connect (OSTI)

The authors report 77K operation of an optically pumped vertical cavity surface emitting laser with an Sb-based cavity. The structure consists of 15 and 20 pair AlGaAsSb/AlAsSb top and bottom reflectors and a bulk InGaAs active region.

Blum, O.; Klem, J.F.; Lear, K.L.; Vawter, G.A.; Kurtz, S.R.

1998-07-01T23:59:59.000Z

135

Coal fly ash interaction with environmental fluids: Geochemical and strontium isotope results from combined column and batch leaching experiments  

SciTech Connect (OSTI)

The major element and Sr isotope systematics and geochemistry of coal fly ash and its interactions with environmental waters were investigated using laboratory flow-through column leaching experiments (sodium carbonate, acetic acid, nitric acid) and sequential batch leaching experiments (water, acetic acid, hydrochloric acid). Column leaching of Class F fly ash samples shows rapid release of most major elements early in the leaching procedure, suggesting an association of these elements with soluble and surface bound phases. Delayed release of certain elements (e.g., Al, Fe, Si) signals gradual dissolution of more resistant silicate or glass phases as leaching continues. Strontium isotope results from both column and batch leaching experiments show a marked increase in {sup 87}Sr/{sup 86}Sr ratio with continued leaching, yielding a total range of values from 0.7107 to 0.7138. For comparison, the isotopic composition of fluid output from a fly ash impoundment in West Virginia falls in a narrow range around 0.7124. The experimental data suggest the presence of a more resistant, highly radiogenic silicate phase that survives the combustion process and is leached after the more soluble minerals are removed. Strontium isotopic homogenization of minerals in coal does not always occur during the combustion process, despite the high temperatures encountered in the boiler. Early-released Sr tends to be isotopically uniform; thus the Sr isotopic composition of fly ash could be distinguishable from other sources and is a useful tool for quantifying the possible contribution of fly ash leaching to the total dissolved load in natural surface and ground waters.

Brubaker, Tonya M.; Stewart, Brian W.; Capo, Rosemary C.; Schroeder, Karl T.; Chapman, Elizabeth C.; Spivak-Birndorf, Lev J.; Vesper, Dorothy J.; Cardone, Carol R.; Rohar, Paul C.

2013-05-01T23:59:59.000Z

136

Ground beef shelf life assessment as influenced by sodium lactate, sodium propionate, sodium diacetate, and soy protein concentrate  

E-Print Network [OSTI]

In phase I all-beef and soy-added ground beef patties containing sodium lactate, sodium propionate, and sodium diacetate at various levels and combinations were stored for nine months at -10°C. Upon cooking, the addition of sodium lactate increased...

Grones, Kelly Leann

2012-06-07T23:59:59.000Z

137

Does the Addition of Fly Ash to Concrete Present a Radon Hazard? J. A. Siegel1  

E-Print Network [OSTI]

Street, Suite 450, Austin, Texas, 78701, USA Summary: Fly ash, a waste material from coal-fired power of fly ash [9]. Fly ash is a waste material from coal fired power plants; when added to concrete, fly ashDoes the Addition of Fly Ash to Concrete Present a Radon Hazard? J. A. Siegel1 , M. Juenger1 and J

Siegel, Jeffrey

138

Use of High-Calcium Fly Ash in Cement-Based Construction Materials  

E-Print Network [OSTI]

, total coal ash production in the world was estimated to be 600 million tons, of which 100 million tons with ASTM 618, coal fly ash is classified into two main categories, Class F fly ash (low-calcium) and Class coal, and Class C fly ash is generated from burning of lignite and subbituminous coals. Class F fly ash

Wisconsin-Milwaukee, University of

139

Factors Controlling the Solubility of Mercury Adsorbed on Fly Ash  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

N:\R&D_Projects_Partial\FlyAsh&CCBs\Meetings\2005_04_WorldOfCoalAsh\AnnKim\HgSol N:\R&D_Projects_Partial\FlyAsh&CCBs\Meetings\2005_04_WorldOfCoalAsh\AnnKim\HgSol ubility_Paper.doc Factors Controlling the Solubility of Mercury Adsorbed on Fly Ash Ann G. Kim 1 and Karl Schroeder 2 1 ORISE Research Fellow, National Energy Technology Laboratory, U.S. Department of Energy, 626 Cochrans Mill Rd., Pittsburgh, PA 15236-0940 2 Research Group Leader, National Energy Technology Laboratory, U.S. Department of Energy, 626 Cochrans Mill Rd., Pittsburgh, PA 15236-0940 KEYWORDS Coal Utilization By-Products, leaching, activated carbon, pH ABSTRACT It is expected that increased controls on Hg emissions will shift the environmental burden from the flue gas to the solid coal utilization by-products (CUB), such as fly ash and flue-gas

140

NETL: Utilization Projects - Managing High-Carbon Ash  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Managing High-Carbon Ash Managing High-Carbon Ash Task 1: Effect of Coal Quality The objective of this task is to assess if fuel selection is an important factor determining ash quality. Work on this task will involve each of the three participating organizations. Ash samples from three coals will be generated under identical firing conditions in the pilot furnace at the University of Utah, and the matching ash and coal samples sent to Brown. Additional matching sets of coal and ash will be obtained from commercial-scale firing at Southern Company. The ashes will be characterized for LOI and surfactant adsorption activity under standard conditions and trends with fuel type identified. At the same time, chars will be prepared from the matching coal set under standard conditions in a laboratory furnace and also characterized for surfactant adsorptivity. A variety of standard conditions may need to be explored. The combined data set will be analyzed to determine cross correlations between ash behavior, standard laboratory char behavior, and parent coal properties. Our goal is to be able to anticipate ash behavior either (a) from coal properties directly, or (b) from the properties of chars made by a simple laboratory procedure. Either could be the basis for a coal quality index -- one based on fuel properties and the other based on a simple screening test.

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Development of an Accelerated Ash-Loading Protocol for Diesel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ash Loading Protocol Rapid Aging and Poisoning Protocols to AssessFuel and Lube Effects on Diesel Aftertreatment (Agreement 13415) Neutron Imaging of Advanced Engine Technologies...

142

Determination of Ash in Biomass: Laboratory Analytical Procedure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ash in Biomass Laboratory Analytical Procedure (LAP) Issue Date: 7172005 A. Sluiter, B. Hames, R. Ruiz, C. Scarlata, J. Sluiter, and D. Templeton Technical Report NREL...

143

Development of an Accelerated Ash-Loading Protocol for Diesel...  

Broader source: Energy.gov (indexed) [DOE]

Accelerated Ash-Loading Protocol for Diesel Particulate Filters Bruce G. Bunting and Todd J. Toops Oak Ridge National Laboratory Adam Youngquist and Ke Nguyen University of...

144

Data Summary Report for Hanford Site Coal Ash Characterization  

SciTech Connect (OSTI)

The purpose of this report is to present data and findings from sampling and analysis of five distinct areas of coal ash within the Hanford Site River Corridor

Sulloway, H. M.

2012-03-06T23:59:59.000Z

145

Reburning Characteristics of Residual Carbon in Fly Ash from CFB Boilers  

Science Journals Connector (OSTI)

The content of residual carbon in fly ash of CFB boilers is a litter high especially when ... of fly ash through collection, recirculation in CFB furnace or external combustor is a possibly ... ash and correspond...

S. H. Zhang; H. H. Luo; H. P. Chen…

2010-01-01T23:59:59.000Z

146

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants  

E-Print Network [OSTI]

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants PSO Project No. 6356 July 2008 Renewable Energy and Transport #12;2 Utilization of Ash Fractions from Alternative Biofuels)...............................................................................7 2. Production of Ash Products from Mixed Biofuels

147

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network [OSTI]

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationarea to volume ratio of coal ash is 200 times greater than1 mm diameters and spherical coal ash particles with 5 ?m

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

148

Coal Fly Ash as a Source of Iron in Atmospheric Dust. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Coal Fly Ash as a Source of Iron in Atmospheric Dust. Coal Fly Ash as a Source of Iron in Atmospheric Dust. Abstract: Anthropogenic coal fly ash aerosols may represent a...

149

Seasonal effects of volatile oils in ashe and redberry juniper on preference and digestibility by goats  

E-Print Network [OSTI]

(qnodon dactylon (L.) Pers.), ashe juniper (Juniperus ashei Buchholz) and live Oak [Quercus virginiana (Small) Sarg. var. fusiformis] during the spring and fall. Angora and Spanish goats were exposed to ashe female, ashe male, redberry female and redberry...

Riddle, Richard R.

1994-01-01T23:59:59.000Z

150

Experimental Study on Ash-Returned Reactor of CFB Atmospheric Air Gasifier  

Science Journals Connector (OSTI)

In an attempt to improve the gasification efficiency and decrease the carbon content in fly ash of atmospheric air CFB gasifiers, an innovatory equipment by name ash-returned ... ash, and hence the coal conversio...

Zhang Shihong; Tian Luning; Zhou Xianrong…

2010-01-01T23:59:59.000Z

151

E-Print Network 3.0 - aluminum-fly ash metal Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

extent, bottom ash, contain elevated amounts of heavy metals, and fly ash... . The dioxinsfurans on ash then don't seem to create an environmental problem. Heavy metals are...

152

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network [OSTI]

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwater using  iron?oxide coated coal bottom ash  Johanna L.  using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

153

Investigation of mechanisms of ash deposit formation from low-rank coal combustion: Final report  

SciTech Connect (OSTI)

This project was undertaken to determine the chemical behavior of alkali metal and other species implicated in the ash fouling which can occur during the combustion of low rank coals. The coal combustion was studied in unaugmented premixed pulverized coal flames. Vapor species were measured by molecular beam mass spectrometry. Temperatures were also measured, and time-resolved coal/ash particulate samples were collected and analyzed. A major part of the research on this project was devoted to: (1) the development and refinement of techniques for the MBMS analysis of trace quantities of unstable and reactive high temperature vapor species from the pulverized coal flames; and (2) the time-resolved sampling and collection of particulates. The equipment is now operating very satisfactorily. Inorganic species, some of which were present at parts-per-million levels, were quantitatively sampled and measured in the pulverized coal flames. Time-resolved particulate samples which were free of vapor deposited contaminants were collected without the use of an interfering substrate. Profiles of the alkali metal species in Beulah lignite and Decker subbituminous coal flames were obtained. It was found in both flames that sodium is volatilized as the atomic species early (milliseconds) in the combustion process. The gaseous Na reacts, also in milliseconds, to form an unknown species which is probably an oxide fume, but which is not NaOH or Na/sub 2/SO/sub 4/. This is probably the mechanism for the formation of the alkali ''fumes'' observed in other systems. Measurements were also made of a number of other gaseous species, and time-resolved coal/ash samples were obtained and analyzed. 27 refs., 23 figs., 8 tabs.

Greene, F.T.; O'Donnell, J.E.

1987-08-01T23:59:59.000Z

154

Coal Ash Corrosion Resistant Materials Testing  

SciTech Connect (OSTI)

In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a reasonably high alkali content, thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was well within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that the aggressive alkali-iron-trisulfate constituent was present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. This report provides the results of the evaluation of Test Section C, including the samples that remained in the Test Section for the full exposure period as well as those that were removed early. The analysis of Test Section C followed much the same protocol that was employed in the assessment of Test Section A. Again, the focus was on determining and documenting the relative corrosion rates of the candidate materials. The detailed results of the investigation are included in this report as a series of twelve appendices. Each appendix is devoted to the performance of one of the candidate alloys. The table below summarizes metal loss rate for the worst case sample of each of the candidate materials for both Test Sections A and C. The body of this report compares these for all of the samples in the test section. The 'Coal Ash Corrosion Resistant Materials Testing Program' is being conducted by The Babcock & Wilcox Company (B&W), the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) at Reliant Energy's Niles plant in Niles, Ohio to provide full-scale, in-situ testing of recently developed boiler superheater materials. Fireside corrosion is a key issue for improving efficiency of new coal fired power plants and improving service life in existing plants. In November 1998, B&W began development of a system to permit testing of advanced tube materials at metal temperatures typical of advanced supercritical steam temperatures (1100 F and higher) in a boiler exhibiting coal ash corrosive conditions. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. In the spring of 1999 a system consisting of three identical sections, each containing multiple segments of twelve different materials, was installed. The sections are cooled by reheat steam, and are located just above the furnace entrance in Niles Unit No.1, a 110 MWe unit firing high sulfur Ohio coal. In November 2001 the first section was removed for thorough metallurgical evaluation after 29 months of operation. The second section was removed in August of 2003. Its evaluation has been completed and is the subject of this report. The final section remains in service and is expected to be removed in the spring of 2005. This paper describes the program; its importance, the design, fabrication, installation and operation of the test system, materials utilized, and experience to date. This report briefly reviews the results of the evaluation of the first section and then presents the results of the evaluation of the second section.

D. K. McDonald; P. L. Daniel; D. J. DeVault

2003-08-31T23:59:59.000Z

155

Durability and microstructure characteristics of alkali activated coal bottom ash geopolymer cement  

Science Journals Connector (OSTI)

Abstract Many studies have focused on the production of mortar and concrete without cement. This is referred to as geopolymer mortar or concrete. This paper discusses the effect of alkali oxides (Na2O = 8, 12, 16 wt.% and SiO2 = 0, 4, 8, 12 wt.%) on compressive strength, microstructure and durability of circulating fluidized bed combustion coal bottom ash (CBA) geopolymer cements (GC). Durability and morphology tests were carried out through heating and freezing tests. The highest compressive strength (25.83 MPa) was achieved at Na2O wt.% = 12, SiO2 wt.% = 8. The optimum atomic ratios for a compact microstructure were obtained for Si/Al between 3.5 and 4 and Si/Na close to 0.5. Following the sintering, the main reaction products (N-A-S-H gel) became more amorphous at 800 °C, attaining Si/Al and Si/Na atomic ratios of 4.54 and 0.98. Sodium carbonate formation was observed at 800 °C. Also, the strength loss of GC was only 6.77% after 30 freeze-thaw cycles. The results show that durable geopolymer concrete without cement can be produced by using waste bottom coal ash. Therefore, the production of geopolymer concrete has a high environmental impact, decreasing waste material in addition to global warming.

?lker Bekir Topçu; Mehmet U?ur Toprak; Tayfun Uyguno?lu

2014-01-01T23:59:59.000Z

156

Effect of Sb incorporation on structure and magnetic properties of quaternary ferromagnetic semiconductor (Ga, Mn)(As, Sb) thin films  

SciTech Connect (OSTI)

GaAs-based quaternary ferromagnetic semiconductor (Ga, Mn)(As, Sb) has been successfully prepared by molecular-beam epitaxy. High-resolution x-ray diffraction measurements indicate that the lattice constant has a notable alteration with changing Sb content. Magnetic measurements demonstrate the same evolution of the Curie temperature T{sub C} and the effective Mn content x{sub eff} with increasing Sb content. The incorporation of low Sb content is of benefit to increasing x{sub eff}, thus, increasing T{sub C}. However, higher Sb content degrades the crystal quality, resulting in a decrease of x{sub eff}. Experimental results show that T{sub C} is proportional to the product of x{sub eff} and p{sup 1/3}, which is consistent with the Zener Model. The exchange energy N{sub 0}? is calculated to be ?1.09 eV, which is similar to that of (Ga, Mn)As.

Deng, J. J.; Che, J. T.; Chen, J.; Wang, W. J.; Hu, B. [Mathematics and Physics Department, North China Electric Power University, Beijing 102206 (China)] [Mathematics and Physics Department, North China Electric Power University, Beijing 102206 (China); Wang, H. L.; Zhao, J. H. [Institute of Semiconductors, State Key Laboratory of Superlattices and Microstructures, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China)] [Institute of Semiconductors, State Key Laboratory of Superlattices and Microstructures, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China)

2013-12-28T23:59:59.000Z

157

Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF Performance and Engine Efficiency  

Broader source: Energy.gov [DOE]

Results illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash properties

158

Investigation of the Fe1+xSb system  

Science Journals Connector (OSTI)

X-ray diffraction, bulk magnetization, and Fe57 Mössbauer spectroscopic measurements on Fe1+xSb system for various values of x (0.14?x?0.35) are reported. The x-ray data suggest that the ASTM (American Society for Testing and Materials) data file for Fe1+xSb should be modified. The lattice Néel temperatures obtained from magnetic susceptibility and Mössbauer spectroscopic measurements are in nice agreement with each other and decrease linearly with increase in x. The Néel temperatures for the ordering of interstitial Fe atoms are higher than 60 K and increase with x. The low-temperature Mössbauer spectra have been analyzed in terms of a Lorentzian distribution of the magnetic hyperfine field at lattice sites, a low-field site, and a relatively high-field interstitial site. Also included are comments on the low magnetic moment of Fe in Fe1+xSb.

R. Kumar; K. S. Harchand; Vishwamittar; K. Chandra; P. Jernberg; T. Ericsson; R. Wappling

1985-07-01T23:59:59.000Z

159

E-Print Network 3.0 - ash cenospheres composites Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Composites Addition of fly ash cenospheres to polymer matrix influences all... , polyethylene, etc.). The effects of addition of fly ash cenospheres on polymer composites...

160

E-Print Network 3.0 - ash slag silica Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 91 By-Products Utilization Summary: pozzolans include coal fly ash, blast furnace slag, silica fume, and other combustion ashes. When...

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - ash deposition propensities Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ash, fouling, co-combustion 1... ;5 relative compositions of major ash species in coal, ... Source: Hawaii Natural Energy Institute Collection: Renewable Energy 51...

162

E-Print Network 3.0 - ash deposits part Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Reading Collection: Geosciences 24 Research Summary RECOAL: Reintegration of coal ash disposal sites and mitigation Summary: being used for coal ash deposits....

163

E-Print Network 3.0 - ash char deposits Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ash, fouling, co-combustion 1... ;5 relative compositions of major ash species in coal, ... Source: Hawaii Natural Energy Institute Collection: Renewable Energy 86...

164

E-Print Network 3.0 - ash nasal lavage Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the people of North America for thousands of years. Of the nine ash... species, white ash (Fraxinus americana L.) and green ... Source: USDA, Forestry Service, Northern Research...

165

E-Print Network 3.0 - ash intranasal instillation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Residue: Origins, Fate and Potential for Treatment Summary: in the form of ash (Liberti et al. 2005). The management of this ash presents a unique challenge... or...

166

Characterization of the Thermal Transport Through a Temporally-Varying Ash Layer.  

E-Print Network [OSTI]

??Ash deposits in commercial coal-fired boilers frequently pose serious maintenance challenges and decrease thermal efficiency. A better understanding of fundamental thermal transport properties in ash… (more)

Cundick,Darron Palmer 1979-

2008-01-01T23:59:59.000Z

167

E-Print Network 3.0 - ash disposal area Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 83 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: combustion 1. Fly ash is...

168

E-Print Network 3.0 - ashe higher education Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

higher abrasion... Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

169

E-Print Network 3.0 - ash quarterly technical Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

170

E-Print Network 3.0 - ash paving demonstration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AND DEMONSTRATION... Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

171

E-Print Network 3.0 - ash penurunan kadar Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

172

E-Print Network 3.0 - ashes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

173

E-Print Network 3.0 - ash ahto lobjakas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

174

E-Print Network 3.0 - ash based gepolymer Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: . CHARACTERIZATION AND APPLICATION OF CLASS F FLY ASH AND CLEAN-COAL ASH FOR CEMENT-BASED MATERIALS 2 The major... large amounts of conventional or...

175

E-Print Network 3.0 - ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

176

E-Print Network 3.0 - ash projekt vaendoera Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

177

Characterization of the properties for phase-change material GeSb  

Science Journals Connector (OSTI)

Te-free environmentally friendly GeSb phase-change material has been investigated. Eutectic Ge15Sb85...composition, which has a proper high crystallization temperature of 230°C, is a good candidate for the applic...

Yifeng Gu; Ting Zhang; Zhitang Song; Yanbo Liu; Bo Liu; Songlin Feng

2010-04-01T23:59:59.000Z

178

Study of ash deposition during coal combustion under oxyfuel conditions  

Science Journals Connector (OSTI)

This paper presents a comparative study on ash deposition of two selected coals, Russian coal and lignite, under oxyfuel (O2/CO2) and air combustion conditions. The comparison is based on experimental results and subsequent evaluation of the data and observed trends. Deposited as well as remaining filter ash (fine ash) samples were subjected to XRD and ICP analyses in order to study the chemical composition and mineral transformations undergone in the ash under the combustion conditions. The experimental results show higher deposition propensities under oxyfuel conditions; the possible reasons for this are investigated by analyzing the parameters affecting the ash deposition phenomena. Particle size seems to be larger for the Russian coal oxy-fired ash, leading to increased impaction on the deposition surfaces. The chemical and mineralogical compositions do not seem to differ significantly between air and oxyfuel conditions. The differences in the physical properties of the flue gas between air combustion and oxyfuel combustion, e.g. density, viscosity, molar heat capacity, lead to changes in the flow field (velocities, particle trajectory and temperature) that together with the ash particle size shift seem to play a role in the observed ash deposition phenomena.

L. Fryda; C. Sobrino; M. Glazer; C. Bertrand; M. Cieplik

2012-01-01T23:59:59.000Z

179

The recycling of the coal fly ash in glass production  

SciTech Connect (OSTI)

The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

2006-09-15T23:59:59.000Z

180

Reactivity of fly ashes in a spray dryer FGD process  

SciTech Connect (OSTI)

During the period 1981-1982, a study was performed to determine the ability of various fly ashes to retain sulfur dioxide in a pilot plant spray dryer/fabric filter flue gas desulfurization system. This knowledge would provide design engineers with the necessary data to determine whether the fly ash from a particular utility could be used as an effective supplement or substitute for slaked lime in a spray dryer system. The study commenced with the collection of 22 fly ashes from lignite, subbituminous, and bituminous eastern and western coals. The ashes were contacted with the flue gas entering the pilot plant by two different techniques. In the first, the ashes were slurried in water and injected into the spray dryer through a spinning disk atomizer. In the second, the ashes were injected as a dry additive into the flue gas upstream of the spray dryer. Analyses were conducted to determine the ability of each ash to retain sulfur dioxide in the system followed by statistical correlations of the sulfur retention with the physical/chemical properties of each ash. 17 references, 32 figures, 19 tables.

Davis, W.T.; Reed, G.D.

1983-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

IN HARM'S WAY: Lack Of Federal Coal Ash  

E-Print Network [OSTI]

IN HARM'S WAY: Lack Of Federal Coal Ash Regulations Endangers Americans And Their Environment 2010 Thirty-nine New Damage Cases of Contamination from Improperly Disposed Coal Combustion Waste, Editor and Contributing Author #12;IN HARM'S WAY: Lack of Federal Coal Ash Regulations Endangers

Short, Daniel

182

The Sodium-Restricted Diet  

E-Print Network [OSTI]

The value of salt has long been known. Feuds and wars were waged for the possession of salt during man's early development. The common expressions "salt of the earth" and "worth his weight in salt" all show the high value placed on salt. Taxes were... collected for possession of salt. Even the word "salary" is connected with salt. Salt remains valuable to us as a source of sodium, an essential nutrient needed by our body to function properly. The body needs sodium to form tissue - to aid a child...

Anonymous,

1979-01-01T23:59:59.000Z

183

Ashe County - Wind Energy System Ordinance | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Ashe County - Wind Energy System Ordinance Ashe County - Wind Energy System Ordinance Ashe County - Wind Energy System Ordinance < Back Eligibility Agricultural Commercial Industrial Institutional Investor-Owned Utility Local Government Multi-Family Residential Municipal Utility Nonprofit Residential Rural Electric Cooperative Schools State Government Tribal Government Utility Savings Category Wind Buying & Making Electricity Program Info State North Carolina Program Type Solar/Wind Permitting Standards Provider Ashe County Planning Department In 2007 Ashe County adopted a wind ordinance to regulate the use of wind-energy systems in unincorporated areas of the county and to describe the conditions by which a permit for installing such a system may be obtained. This policy was adopted in the context of an ongoing debate over

184

Purple traps yield Reservation's first detection of Emerald Ash Borer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

traps yield Reservation's first detection of Emerald Ash Borer traps yield Reservation's first detection of Emerald Ash Borer The question of whether or not DOE's forests are infested with Emerald Ash Borer (EAB) has been answered. On May 10, a trap on Highway 95 at the Highway 58 interchange produced the first instance of the destructive non-native insect in Roane County. Five days later, a second trap on Bethel Valley Road near the East Portal turned up the first capture in Anderson County. "Unfortunately, these finds signal the beginning of a decline of ash species throughout the reservation" according to Greg Byrd, forester with the ORNL Natural Resources Program. "Dieback will become more prominent as the insect populations expand. Native ash trees have little defense against this pest, which was

185

State Waste Discharge Permit application: 200-E Powerhouse Ash Pit  

SciTech Connect (OSTI)

As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department and Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-E Powerhouse Ash Pit. The 200-E Powerhouse Ash Waste Water discharges to the 200-E Powerhouse Ash Pit via dedicated pipelines. The 200-E Ash Waste Water is the only discharge to the 200-E Powerhouse Ash Pit. The 200-E Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

Atencio, B.P.

1994-06-01T23:59:59.000Z

186

State Waste Discharge Permit application: 200-W Powerhouse Ash Pit  

SciTech Connect (OSTI)

As part of the Hanford Federal Facility Agreement and Consent Order negotiations; the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-W Powerhouse Ash Pit. The 200-W Powerhouse Ash Waste Water discharges to the 200-W Powerhouse Ash Pit via dedicated pipelines. The 200-W Powerhouse Ash Waste Water is the only discharge to the 200-W Powerhouse Ash Pit. The 200-W Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

Atencio, B.P.

1994-06-01T23:59:59.000Z

187

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

2003-05-20T23:59:59.000Z

188

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

2002-09-10T23:59:59.000Z

189

Born-Oppenheimer breakdown effects and hyperfine structure in the rotational spectra of SbF and SbCl  

Science Journals Connector (OSTI)

Pure rotational spectra have been measured for the ground electronic states of SbF and SbCl. The molecules were prepared by laser ablation of Sb metal in the presence of SF6 or Cl2, respectively. Their spectra were measured with a cavity pulsed jet Fourier transform microwave spectrometer. Although both molecules have two unpaired electrons, they are subject to Hund’s coupling case (c), and have X10+ ground states. The spectra have been interpreted with the formalism of 1?+ molecules. For both molecules spectra of several isotopomers have been measured in the ground and first excited vibrational states. Large hyperfine splittings attributable to both nuclear quadrupole coupling and nuclear spin-rotation coupling have been observed. A Dunham-type analysis has produced unusually large Born-Oppenheimer breakdown parameters, which are interpreted in terms of the electronic structures of the molecules.

Stephen A. Cooke; Michael C.L. Gerry

2005-01-01T23:59:59.000Z

190

Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Abstract: Sodium ion (Na+) batteries...

191

Effect of fuel properties on the bottom ash generation rate by a laboratory fluidized bed combustor  

SciTech Connect (OSTI)

The range of fuels that can be accommodated by an FBC boiler system is affected by the ability of the fuel, sorbent, and ash-handling equipment to move the required solids through the boiler. Of specific interest is the bottom ash handling equipment, which must have sufficient capacity to remove ash from the system in order to maintain a constant bed inventory level, and must have sufficient capability to cool the ash well below the bed temperature. Quantification of a fuel's bottom ash removal requirements can be useful for plant design. The effect of fuel properties on the rate of bottom ash production in a laboratory FBC test system was examined. The work used coal products ranging in ash content from 20 to 40+ wt. %. The system's classification of solids by particle size into flyash and bottom ash was characterized using a partition curve. Fuel fractions in the size range characteristic of bottom ash were further analyzed for distributions of ash content with respect to specific gravity, using float sink tests. The fuel fractions were then ashed in a fixed bed. In each case, the highest ash content fraction produced ash with the coarsest size consist (characteristic of bottom ash). The lower ash content fractions were found to produce ash in the size range characteristic of flyash, suggesting that the high ash content fractions were largely responsible for the production of bottom ash. The contributions of the specific gravity fractions to the composite ash in the fuels were quantified. The fuels were fired in the laboratory test system. Fuels with higher amounts of high specific gravity particles, in the size ranges characteristic of bottom ash, were found to produce more bottom ash, indicating the potential utility of float sink methods in the prediction of bottom ash removal requirements.

Rozelle, P.L.; Pisupati, S.V.; Scaroni, A.W. [Penn State University, University Park, PA (United States). Dept. of Energy & Geoenvironmental Engineering

2007-06-15T23:59:59.000Z

192

Crystal structure and bonding characteristics of In-doped {beta}-Zn{sub 4}Sb{sub 3}  

SciTech Connect (OSTI)

The effects of indium impurity on the crystal structure and bonding characteristics of In-doped {beta}-Zn{sub 4}Sb{sub 3} were investigated by powder X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The XRD Rietveld refinement indicates that the indium impurity preferentially substitutes one of Sb atoms in Sb-Sb dimer at the 12c Sb(2) site and simultaneously leads to the increase of Zn occupancy. The observations of binding energy shift and a new valence state in Sb 3d core-level XPS spectra can be attributed to the charge transfer from In and Zn to Sb. As a result, more electropositive Zn atoms are needed to maintain the charge balance. The reduction of the lattice thermal conductivity is ascribed to the formation of the asymmetric Sb-In bond, resulting in much low lattice thermal conductivity of 0.49 W{sup -1} K{sup -1} of Zn{sub 4}Sb{sub 2.96}In{sub 0.04}. - Graphical abstract: The indium impurity substitutes one of Sb atoms in Sb-Sb dimer, resulting the charge transfer from In to Sb, which leads to the binding energy of Sb 3d core level XPS spectra shift to low value. Highlights: Black-Right-Pointing-Pointer The indium impurity preferentially substitutes one of Sb atoms in Sb-Sb dimer at the 12c Sb(2) site. Black-Right-Pointing-Pointer The occupancy of Zn increases by the In substitution for Sb, whereas that of Sb keeps constant. Black-Right-Pointing-Pointer The binding energy of Sb 3d shifts to low value. Black-Right-Pointing-Pointer The charge transfer occurs from In and Zn to Sb.

Tang, Dingguo [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China) [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China); Key Laboratory of Catalysis and Materials Science of the State Ethnic Affair Commission and Ministry of Education, South-Central University for Nationalities, Wuhan 430074 (China); Zhao, Wenyu, E-mail: wyzhao@whut.edu.cn [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China)] [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China); Cheng, Sudan; Wei, Ping; Yu, Jian [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China)] [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China); Zhang, Qingjie, E-mail: zhangqj@whut.edu.cn [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China)] [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China)

2012-09-15T23:59:59.000Z

193

Electronic-Structure of the Semimetals Bi and Sb  

E-Print Network [OSTI]

We have developed a third-neighbor tight-binding model, with spin-orbit coupling included, to treat the electronic properties of Bi and Sb. This model successfully reproduces the features near the Fermi surface that will be most important...

LIU, Y.; Allen, Roland E.

1995-01-01T23:59:59.000Z

194

Categorical Exclusion 4566, Ash Removal Project  

Broader source: Energy.gov (indexed) [DOE]

FOrnI FOrnI Project Title: Ash Removal Project (4566) Program or Program Office: Y -12 Site Office Location: Oak Ridge Tennessee Project Description: This work scope is to split, containerize, package, transport and disposition one hundred and two (102) cans of mixed waste. General Administration/Management OA I - Routine business actions OA2 * Administrative contract amendments OA4 - Interpretations/rulings for existing regulations OA5 - Regulatory interpretations without environmental effect OA6 - Procedural rule makings upgrade OA 7 - Transfer of property, use unchanged OA8 . Award of technical supportlM&O/personal service contracts OA9 - Info gathering, analysis, documentation, dissemination, and training OA 10 - Reports on non-DOE legislation OA II -

195

Coal Ash Corrosion Resistant Materials Testing Program  

SciTech Connect (OSTI)

The "Coal Ash Corrosion Resistant Materials Testing Program" is being conducted by The Babcock & Wilcox Company (B&W), the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) at Reliant Energy?s Niles plant in Niles, Ohio to provide full-scale, in-situ testing of recently developed boiler superheater materials. Fireside corrosion is a key issue for improving efficiency of new coal fired power plants and improving service life in existing plants. In November 1998, B&W began development of a system to permit testing of advanced tube materials at metal temperatures typical of advanced supercritical steam temperatures (1100°F and higher) in a boiler exhibiting coal ash corrosive conditions. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. In the spring of 1999 a system consisting of three identical sections, each containing multiple segments of twelve different materials, was installed. The sections are cooled by reheat steam, and are located just above the furnace entrance in Niles? Unit #1, a 110 MWe unit firing high sulfur Ohio coal. In November 2001 the first section was removed for thorough metallurgical evaluation after 33 months of operation. The second and third sections remain in service and the second is expected to be removed in the fall of 2003; the last is tentatively planned for the fall of 2004. This paper describes the program; its importance; the design, fabrication, installation and operation of the test system; materials utilized; experience to date; and results of the evaluation of the first section.

McDonald, D.K.

2003-04-22T23:59:59.000Z

196

Distribution of arsenic and mercury in lime spray dryer ash  

SciTech Connect (OSTI)

The partitioning of As and Hg in various components of lime spray dryer (LSD) ash samples from a coal-fired boiler was characterized to better understand the form and fate of these elements in flue gas desulfurization byproducts. LSD ash samples, collected from the McCracken Power Plant on the Ohio State University campus, were separated by a 140-mesh (106 {mu}m) sieve into two fractions: a fly-ash-/unburned-carbon-enriched fraction (> 106 {mu}m) and a calcium-enriched fraction (< 106 {mu}m). Unburned carbon and fly ash in the material > 106 {mu}m were subsequently separated by density using a lithium heteropolytungstate solution. The concentrations of As and Hg were significant in all fractions. The level of As was consistently greater in the calcium-enriched fraction, while Hg was evenly distributed in all components of LSD ash. Specific surface area was an important factor controlling the distribution of Hg in the different components of LSD ash, but not for As. Comparing the LSD ash data to samples collected from the economizer suggests that As was effectively captured by fly ash at 600{sup o}C, while Hg was not. Leaching tests demonstrated that As and Hg were more stable in the calcium-enriched fraction than in the fly-ash- or carbon-enriched fractions, potentially because of the greater pH of the leachate and subsequently greater stability of small amounts of calcium solids containing trace elements in these fractions. 37 refs., 8 figs., 2 tabs.

Panuwat Taerakul; Ping Sun; Danold W. Golightly; Harold W. Walker; Linda K. Weavers [Ohio State University, Columbus, OH (United States). Department of Civil and Environmental Engineering and Geodetic Science

2006-08-15T23:59:59.000Z

197

Interdiffusion in NiMnSb/V/NiMnSb: X-ray and neutron reflectivity investigation of ion beam sputtered trilayer systems  

SciTech Connect (OSTI)

The new trilayer system NiMnSb/V/NiMnSb on MgO(001) was investigated by means of vibrating sample magnetometry (VSM), x-ray, and neutron reflectivity. VSM revealed a coercive field H{sub c}=23 Oe and a hysteresis loop similar to that of an uncoupled ferromagnet. The x-ray and neutron reflectivity data proved that interface roughnesses of 10 {Angstrom} are present. A detailed analysis yielded significant interdiffusion at the NiMnSb/V interfaces which is one possible explanation for the weak magnetoresistance effect measured in similar NiMnSb-based multilayer systems. {copyright} {ital 1999 American Institute of Physics.}

Schlomka, J.; Tolan, M.; Press, W. [Institut fuer Experimentelle und Angewandte Physik, Christian-Albrechts-Universitaet zu Kiel, 24098 Leibnizstrasse 17-19, Kiel (Germany)] [Institut fuer Experimentelle und Angewandte Physik, Christian-Albrechts-Universitaet zu Kiel, 24098 Leibnizstrasse 17-19, Kiel (Germany); Fitzsimmons, M.R. [Manuel Lujan, Jr. Neutron Scattering Center, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Manuel Lujan, Jr. Neutron Scattering Center, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Siebrecht, R. [Institut Laue-Langevin, 38042 Grenoble, Cedex 9 (France)] [Institut Laue-Langevin, 38042 Grenoble, Cedex 9 (France); Schubert, D.W. [GKSS Forschungszentrum, 21502 Geesthacht (Germany)] [GKSS Forschungszentrum, 21502 Geesthacht (Germany); Simon, P. [Max Planck Institut fuer Polymerforschung, 55021 Mainz (Germany)] [Max Planck Institut fuer Polymerforschung, 55021 Mainz (Germany)

1999-11-01T23:59:59.000Z

198

Thermomechanical Analysis of Coal Ash:? The Influence of the Material for the Sample Assembly  

Science Journals Connector (OSTI)

Although the proposed temperatures were low compared to conventional AFTs, especially for iron-rich samples, the use of TMA appeared to be an excellent tool for routine characterization of ash fusibility of various coals. ... BN, C, and Al2O3 assemblies are not suitable in studying the thermal behavior of coal ashes due to reactions with components of the ash. ... ashing. ...

G. W. Bryant; G. J. Browning; S. K. Gupta; J. A. Lucas; R. P. Gupta; T. F. Wall

2000-02-25T23:59:59.000Z

199

Environmental hazard assessment of coal fly ashes using leaching and ecotoxicity tests  

E-Print Network [OSTI]

Environmental hazard assessment of coal fly ashes using leaching and ecotoxicity tests V. Tsiridis t The environmental hazard of six coal fly ash samples collected from various coal incineration plants were examined- bustion, considerable amounts of coal fly ash are still produced. Although coal fly ash can be moderately

Short, Daniel

200

Influence of substituting Sn for Sb on the thermoelectric transport properties of CoSb{sub 3}-based skutterudites  

SciTech Connect (OSTI)

Band structure calculations that incorporate impurity effects suggest that a band resonant state may be formed in p-type CoSb{sub 3}-based skutterudites by replacing Sb atoms with Sn dopant atoms. Such resonant states have the potential to greatly improve thermoelectric energy conversion efficiency by increasing the density of states variation near the Fermi level, thereby increasing the Seebeck coefficient at a given carrier concentration. Through transport measurements of the Seebeck coefficient, electrical conductivity, thermal conductivity, and Hall coefficient, we show that a practical band resonant state is not achieved by Sn doping. Compared to undoped CoSb{sub 3}, the dimensionless figure of merit (ZT) in Sn-doped CoSb{sub 3} is enhanced slightly at high temperatures to a value of 0.2, mostly due to a reduction in thermal conductivity. The Fermi level is calculated not to reach the band resonant state induced by Sn impurity atoms within the range of Sn concentrations examined here.

Hui, Si [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Nielsen, Michele D. [Department of Mechanical and Aerospace Engineering, Ohio State University, Columbus, Ohio 43210 (United States); Homer, Mark R.; Medlin, Douglas L. [Sandia National Laboratories, Livermore, California 94550 (United States); Tobola, Janusz [AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, 30-059 Krakow (Poland); Salvador, James R. [Chemical and Materials Systems Laboratory, GM R and D Center, Warren, Michigan 48090 (United States); Heremans, Joseph P. [Department of Mechanical and Aerospace Engineering, Ohio State University, Columbus, Ohio 43210 (United States); Department of Physics, Ohio State University, Columbus, Ohio 43210 (United States); Pipe, Kevin P. [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, Michigan 48109 (United States); Uher, Ctirad [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States)

2014-03-14T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Recovery of iron oxide from coal fly ash  

DOE Patents [OSTI]

A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

Dobbins, Michael S. (Ames, IA); Murtha, Marlyn J. (Ames, IA)

1983-05-31T23:59:59.000Z

202

Electrical, optical, and thermal properties of Sn-doped phase change material Ge2Sb2Te5  

Science Journals Connector (OSTI)

In this article, effect of Sn on the electrical, optical, and thermal properties of Ge2Sb2Te5 is studied. Ge2Sb2Te5, Ge1.55Sb2Te5Sn0.45, and Ge1.1Sb2Te5Sn0.9...alloys are prepared by melt quenching technique and ...

Gurinder Singh; Aman Kaura; Monika Mukul; S. K. Tripathi

2013-01-01T23:59:59.000Z

203

Hydrogen passivation of Se and Te in AlSb M. D. McCluskey and E. E. Haller  

E-Print Network [OSTI]

Hydrogen passivation of Se and Te in AlSb M. D. McCluskey and E. E. Haller Lawrence Berkeley observed local vibrational modes LVM's arising from DX-hydrogen complex in AlSb. Hydrogen was diffused into bulk AlSb:Se and AlSb:Te by annealing in sealed quartz ampoules with either hydrogen gas or methanol CH

McCluskey, Matthew

204

The Development of a Small Engine Based Ash Loading Protocol  

Broader source: Energy.gov [DOE]

When 5% lubrication oil is added to diesel fuel in a small engine test, ash increases linearly and at the back of a filter, the amount depending on the differences in substrate and wash-coat type.

205

Determination of Total Solids and Ash in Algal Biomass: Laboratory...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solids and Ash in Algal Biomass Laboratory Analytical Procedure (LAP) Issue Date: December 2, 2013 S. Van Wychen and L. M. L. Laurens Technical Report NRELTP-5100-60956 December...

206

Transcending Portland Cement with 100 percent fly ash concrete  

SciTech Connect (OSTI)

The use of concrete, made with 100% fly ash and no Portland cement, in buildings at the Transportation Institute in Bozeman, MT, USA, is described. 3 refs., 7 figs.

Cross, D.; Akin, M.; Stephens, J.; Cuelh, E. [Montana State University, MT (United States)

2009-07-01T23:59:59.000Z

207

Coal ash composition of Australian low rank coals  

Science Journals Connector (OSTI)

The iron-containing phases in nine precipitator ashes of widely differing composition have been analyzed by57Fe Mössbauer spectroscopy. The importance of the relative proportion of calcium ferrite to magnesioferr...

L. J. Brown; J. D. Cashion; R. C. Ledger

1992-04-01T23:59:59.000Z

208

INAA multielemental analysis of Nigerian bituminous coal and coal ash  

Science Journals Connector (OSTI)

Instrumental neutron activation analysis (INAA) was used to analyzed Nigerian bituminous coal and ash. Good statistical agreement (p...?0.05) between the literature and reported elemental values of USGS AGV-1 sam...

V. O. Ogugbuaja; W. D. James

1995-03-01T23:59:59.000Z

209

Coal Ash from Thermal Power Plants in Finland  

Science Journals Connector (OSTI)

This review summarizes formation mechanisms of coal ash, its chemistry and use pattern in the Finnish industry. Coal is composed of organic and inorganic materials. The properties of coal varies from one region t...

Arun B. Mukherjee; Ryunosuke Kikuchi

1999-01-01T23:59:59.000Z

210

The mild hydrothermal synthesis of hydrogrossular from coal ash  

Science Journals Connector (OSTI)

In this study, an attempt was made to synthesize hydrogrossular, a group of garnet minerals, under hydrothermal conditions at temperatures below 180°C, using coal ash, which is the solid waste from thermal...

Satoru Fujita; Kenzi Suzuki; Yasuo Shibasaki

2002-04-01T23:59:59.000Z

211

Ultimate bearing capacity of footings on coal ash  

Science Journals Connector (OSTI)

Coal ash is recognized as an alternative fill material to the conventional natural soils near a coal fired thermal power station where its large ... This paper presents experimental investigations on footings on

Ashutosh Trivedi; Vijay Kumar Sud

2005-11-01T23:59:59.000Z

212

Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin  

Broader source: Energy.gov [DOE]

The Savannah River Site (SRS) recently cleaned up a 17-acre basin containing coal ash residues from Cold War operations. The American Recovery and Reinvestment Act project was safely completed at a...

213

Optical properties of fly ash. Volume 2, Final report  

SciTech Connect (OSTI)

Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executive summary of the whole program followed by the dissertation of Ghosal and Ebert. Volume 2 contains the dissertation of Ebert which covers the measurements of the optical constants of slags, and calculations of the radiant properties of fly ash dispersions. A list of publications and conference presentations resulting from the work is also included.

Self, S.A.

1994-12-01T23:59:59.000Z

214

Guide to Using Wood Ash as an Agricultural Soil Amendment  

E-Print Network [OSTI]

wastes Increases soil pH Add plant nutrients Low cost #12;UNH COOPERATIVE EXTENSION Food & Agriculture and scab-susceptible potatoes varieties thrive in acid soils, and should not be supplemented with wood ash

New Hampshire, University of

215

SLUDGE BATCH 7 (SB7) WASHING DEMONSTRATION TO DETERMINE SULFATE/OXALATE REMOVAL EFFICIENCY AND SETTLING BEHAVIOR  

SciTech Connect (OSTI)

To support Sludge Batch 7 (SB7) washing, a demonstration of the proposed Tank Farm washing operation was performed utilizing a real-waste test slurry generated from Tank 4, 7, and 12 samples. The purpose of the demonstration was twofold: (1) to determine the settling time requirements and washing strategy needed to bring the SB7 slurry to the desired endpoint; and (2) to determine the impact of washing on the chemical and physical characteristics of the sludge, particularly those of sulfur content, oxalate content, and rheology. Seven wash cycles were conducted over a four month period to reduce the supernatant sodium concentration to approximately one molar. The long washing duration was due to the slow settling of the sludge and the limited compaction. Approximately 90% of the sulfur was removed through washing, and the vast majority of the sulfur was determined to be soluble from the start. In contrast, only about half of the oxalate was removed through washing, as most of the oxalate was initially insoluble and did not partition to the liquid phase until the latter washes. The final sulfur concentration was 0.45 wt% of the total solids, and the final oxalate concentration was 9,900 mg/kg slurry. More oxalate could have been removed through additional washing, although the washing would have reduced the supernatant sodium concentration.The yield stress of the final washed sludge (35 Pa) was an order of magnitude higher than that of the unwashed sludge ({approx}4 Pa) and was deemed potentially problematic. The high yield stress was related to the significant increase in insoluble solids that occurred ({approx}8 wt% to {approx}18 wt%) as soluble solids and water were removed from the slurry. Reduction of the insoluble solids concentration to {approx}14 wt% was needed to reduce the yield stress to an acceptable level. However, depending on the manner that the insoluble solids adjustment was performed, the final sodium concentration and extent of oxalate removal would be prone to change. As such, the strategy for completing the final wash cycle is integral to maintaining the proper balance of chemical and physical requirements.

Reboul, S.; Click, D.; Lambert, D.

2010-12-10T23:59:59.000Z

216

Effects of Sediment Containing Coal Ash from the Kingston Ash Release on Embryo-Larval Development in the Fathead Minnow, Pimephales promelas (Rafinesque, 1820)  

Science Journals Connector (OSTI)

The largest environmental release of coal ash in US history occurred in December 2008 ... Plant in East Tennessee. A byproduct of coal-burning power plants, coal ash is enriched in metals and metalloids such ... ...

Mark S. Greeley Jr.; Logan R. Elmore…

2014-02-01T23:59:59.000Z

217

Enhancement of phosphogypsum with high lime fly ash  

E-Print Network [OSTI]

ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1983 Major... Subject: Civil Engineering ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH'LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Approved as to style and content by: Dr. ona d Saylak (Chairman f Committee) Dr. W. edbetter ( ember) (Member) r. Lloyd Deuel, 3...

Gregory, Chuck Alan

1983-01-01T23:59:59.000Z

218

Use of Biomass Gasification Fly Ash in Lightweight Plasterboard  

Science Journals Connector (OSTI)

In addition, the overall environmental benefit of waste gasification plus ash utilization of a difficult fly ash makes the overall process attractive. ... Only the Autonomous Government of Catalonia has established regional regulations for waste management, including limited recycling for some wastes considered as byproducts. ... viability of gasifying untreated olive stone, also called "orujillo", a byproduct of the olive oil industry that comprises both olive stone and pulp. ...

C. Leiva; A. Gómez-Barea; L. F. Vilches; P. Ollero; J. Vale; C. Fernández-Pereira

2006-11-24T23:59:59.000Z

219

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; the effect of various low-NOx firing modes on ash properties and adsorptivity; and the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. This first project period, experiments were carried out to better understand the fundamental nature of the ozonation effect on ash. Carbon surfaces were characterized by surfactant adsorption, and by X-ray Photoelectron Spectroscopy before and after oxidation, both by air at 440 C and by ozone at room temperature. The results strongly suggest that the beneficial effect of ozonation is in large part due to chemical modification of the carbon surfaces.

Robert Hurt; Eric Suuberg; John Veranth

2001-12-26T23:59:59.000Z

220

Ash level meter for a fixed-bed coal gasifier  

DOE Patents [OSTI]

An ash level meter for a fixed-bed coal gasifier is provided which utilizes the known ash level temperature profile to monitor the ash bed level. A bed stirrer which travels up and down through the extent of the bed ash level is modified by installing thermocouples to measure the bed temperature as the stirrer travels through the stirring cycle. The temperature measurement signals are transmitted to an electronic signal process system by an FM/FM telemetry system. The processing system uses the temperature signals together with an analog stirrer position signal, taken from a position transducer disposed to measure the stirrer position to compute the vertical location of the ash zone upper boundary. The circuit determines the fraction of each total stirrer cycle time the stirrer-derived bed temperature is below a selected set point, multiplies this fraction by the average stirrer signal level, multiplies this result by an appropriate constant and adds another constant such that a 1 to 5 volt signal from the processor corresponds to a 0 to 30 inch span of the ash upper boundary level. Three individual counters in the processor store clock counts that are representative of: (1) the time the stirrer temperature is below the set point (500.degree. F.), (2) the time duration of the corresponding stirrer travel cycle, and (3) the corresponding average stirrer vertical position. The inputs to all three counters are disconnected during any period that the stirrer is stopped, eliminating corruption of the measurement by stirrer stoppage.

Fasching, George E. (Morgantown, WV)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project was to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific issues addressed included: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity based on pilot-plant studies; and (3) the kinetics and mechanism of ash ozonation. This laboratory data has provided scientific and engineering support and underpinning for parallel process development activities. The development work on the ash ozonation process has now transitioned into a scale-up and commercialization project involving a multi-industry team and scheduled to begin in 2004. This report describes and documents the laboratory and pilot-scale work in the above three areas done at Brown University and the University of Utah during this three-year project.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen; Indrek Kulaots

2004-02-13T23:59:59.000Z

222

Lattice Vibrations in La(Ce)Fe4Sb12 and CoSb3: Inelastic Neutron Scattering and Theory  

SciTech Connect (OSTI)

We present results of time-of-flight inelastic neutron scattering phonon density of states measurements on (La,Ce){sub 0.9}Fe{sub 4}Sb{sub 12} and CoSb{sub 3} as well as of a detailed comparison with lattice dynamical models in the literature. The MARI experimental setup is replicated by a theory for scattering from a polycrystalline material. The model considered for the filled materials is a local density approximation (LDA) based short-range force constant model and those considered for CoSb{sub 3} are the LDA-based model with the La-related parameters removed and a semiempirical model. We show that the presence of La significantly affects the shape of the spectrum. We also conclude that upon filling the Sb intrasquare force constants are weakened and that the transition-metal Sb bonds are almost unchanged.

Feldman, J. L. [Naval Research Laboratory, Washington, D.C.; Dai, Pengcheng [ORNL; Enck, Thomas P [ORNL; Sales, Brian C [ORNL; Mandrus, David [ORNL; Singh, David J [ORNL

2006-01-01T23:59:59.000Z

223

InGaAsSb thermophotovoltaic diode physics evaluation  

SciTech Connect (OSTI)

The hotside operating temperatures for many projected thermophotovoltaic (TPV) conversion system applications are approximately 1,000 C, which sets an upper limit on the TPV diode bandgap of 0.6 eV from efficiency and power density considerations. This bandgap requirement has necessitated the development of new diode material systems, never previously considered for energy generation. To date, InGaAsSb quaternary diodes grown lattice-matched on GaSb substrates have achieved the highest performance. This report relates observed diode performance to electro-optic properties such as minority carrier lifetime, diffusion length and mobility and provides initial links to microstructural properties. This analysis has bounded potential diode performance improvements. For the 0.52 eV InGaAsSb diodes used in this analysis the measured dark current is 2 {times} 10{sup {minus}5} A/cm{sup 2}, versus a potential Auger limit 1 {times} 10{sup {minus}5} A/cm{sup 2}, a radiative limit of 2 {times} 10{sup {minus}6} A/cm{sup 2} (no photon recycling), and an absolute thermodynamic limit of 1.4 {times} 10{sup {minus}7} A/cm{sup 2}. These dark currents are equivalent to open circuit voltage gains of 20 mV (7%), 60 mV (20%) and 140 mV (45%), respectively.

Charache, G.W.; Baldasaro, P.F.; Danielson, L.R. [Lockheed-Martin, Inc., Schenectady, NY (United States)] [and others

1998-06-01T23:59:59.000Z

224

An overview of the behaviour of biomass during combustion: Part II. Ash fusion and ash formation mechanisms of biomass types  

Science Journals Connector (OSTI)

Abstract An extended overview of the phase–mineral transformations of organic and inorganic matter during biomass combustion was conducted in Part I of the present work. The ash fusion and ash formation mechanisms of biomass types and sub-types during combustion are described in the present Part II. For that purpose the identified systematic associations based on the occurrence, content and origin of elements and phases in the biomass ash (BA) system, namely (1) Si–Al–Fe–Na–Ti (mostly glass, silicates and oxyhydroxides); (2) Ca–Mg–Mn (commonly carbonates, oxyhydroxides, glass, silicates and some phosphates and sulphates); and (3) K–P–S–Cl (normally phosphates, sulphates, chlorides, glass and some silicates and carbonates); were used as classification of \\{BAs\\} into four types (“S”, “C”, “K” and “CK”) and six sub-types with high, medium and low acid tendencies and their description was given. Then, topics related to ash fusion behaviour such as: some general considerations and observations about ash melting; ash fusion temperatures (AFTs) of biomass and their comparisons with coal; relationships between \\{AFTs\\} and inorganic composition of biomass and coal; and ash fusion mechanisms of biomass and coal are characterized. Further, issues connected with the ash formation mechanisms of BA types and sub-types are discussed. Subsequently, aspects related to potential applications of ash formation mechanisms for BA types and sub-types, namely some key technological problems (fusion, slagging and fouling predictions, low ash fusion temperatures, co-combustion and application of BA) and environmental risks (volatilization, capture and water leaching of hazardous elements) are described. Finally, it is emphasized that the application of this new classification approach based on combined phase–mineral and chemical composition of biomass and BA has not only fundamental importance, but also has potential applications in prediction of behaviour and properties connected with the innovative and sustainable utilization of biomass and BA. It is also demonstrated that the definitive utilization, technological and environmental advantages and challenges related to biomass and BA associate preferentially with their specific types and sub-types and they could be predictable to some extent by using the above or similar combined chemical and phase–mineral classification approaches.

Stanislav V. Vassilev; David Baxter; Christina G. Vassileva

2014-01-01T23:59:59.000Z

225

Independent Oversight Assessment, Idaho Cleanup Project Sodium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Bearing Waste Treatment Project - November 2012 November 2012 Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project This...

226

Viscosity of Liquid Sodium and Potassium  

Science Journals Connector (OSTI)

2 November 1936 research-article Viscosity of Liquid Sodium and Potassium Y. S. Chiong The Royal Society is collaborating with JSTOR to digitize, preserve, and extend...

1936-01-01T23:59:59.000Z

227

Sodium sulfide leaching of low-grade jamesonite concentrate in production of sodium pyroantimoniate  

Science Journals Connector (OSTI)

Sodium sulfide leaching of a low-grade jamesonite concentrate in the production of sodium pyroantimoniate through the air oxidation process and the influencing factors on the leaching rate of antimony were...

Tian-zu Yang PhD; Ming-xi Jiang…

2005-06-01T23:59:59.000Z

228

Prediction of Chinese Coal Ash Fusion Temperatures in Ar and H2 Atmospheres  

Science Journals Connector (OSTI)

Analysis of coal ashes on a weight percent basis shows that they consist mainly of SiO2, Al2O3, Fe2O3, CaO, and MgO, so that the properties of coal ashes at high temperature might be modeled by a five system SiO2?Al2O3?Fe2O3?CaO?MgO synthetic ash. ... The peaks from lab. ashes and corresponding combustion ashes derived from the same coals show clear differences which may be related to the evapn. of potassium during combustion and the reactions of the mineral residues to form combustion ash. ...

Wen J. Song; Li H. Tang; Xue D. Zhu; Yong Q. Wu; Zi B. Zhu; Shuntarou Koyama

2009-03-03T23:59:59.000Z

229

Role of Fly Ash in the Removal of Organic Pollutants from Wastewater  

Science Journals Connector (OSTI)

In India the problem is further compounded by the use of wet fly ash collection systems by a large number of power plants, which results in degradation of the pozzolanic characteristics of ash, an essential ingredient for several ash-based products. ... To accommodate the many new subbituminous fly ashes, the American Society for Testing and Materials (ASTM) established two classes of fly ash, Class F from bituminous coal and Class C from subbituminous and lignite coal. ... Thermal power plant waste material (bottom ash) was utilized as a potential adsorbent for the textile dye malachite green. ...

M. Ahmaruzzaman

2009-02-27T23:59:59.000Z

230

Nepheline Formation Potential in Sludge Batch 4 (SB4) and Its Impact on Durability: Selecting Glasses for a Phase 2 Study  

SciTech Connect (OSTI)

The likelihood for the formation of nepheline in Sludge Batch 4 (SB4) glass systems and the potential impact of nepheline on the durability of these systems is part of the frit development efforts for SB4. The effect of crystallization on glass durability is complex and depends on several interrelated factors including the change in residual glass composition, the formation of internal stress or microcracks, and the preferential attack at the glass-crystal interface. Perhaps one of the most significant effects is the type and extent (or fraction) of crystallization and the change to the residual glass composition. A strong increase in glass dissolution (or decrease in durability) has been observed in previous studies in glasses that formed aluminum-containing crystals, such as NaAlSiO{sub 4} (nepheline) and LiAlSi{sub 2}O{sub 6}, and crystalline SiO{sub 2}. Although it is well known that the addition of Al{sub 2}O{sub 3} to borosilicate glasses enhances the durability of the waste form (through creation of network-forming tetrahedral Na{sup +}-[AlO{sub 4/2}]{sup -} pairs), the combination of high Al{sub 2}O{sub 3} and Na{sub 2}O can lead to the formation of nepheline (NaAlSiO{sub 4}). Given the projected high concentration of Al{sub 2}O{sub 3} in SB4 and the potential use of a high Na{sub 2}O based frit to improve melt rate and a high Na{sub 2}O sludge due to settling problems, the potential formation of nepheline in various SB4 systems continues to be assessed. The most recent compositional projections from the Closure Business Unit (CBU) for SB4 may be framed around three decision areas: the sodium molarity of the sludge (at values of 1M Na and 1.6M Na), the SB3 heel that will be included in the batch (expressed in inches of SB3 sludge with values of 0, 40, and 127''), and the introduction of an ARP stream into the sludge (which is represented by six options: no ARP, ARPa, ARPe, ARPk, ARPm, and ARPv). Candidate frits are being identified for these options via a paper study approach with the intent of downselecting to a set of key frits whose operating windows (i.e., waste loading intervals that meet Product Composition Control System (PCCS) Measurement Acceptability Region (MAR) criteria) are robust to and/or selectively optimal for these sludge options. The primary or key frits that appear attractive on paper (i.e., down selected via the paper study) will be transferred into SRNL's experimental studies supporting SB4; specifically, the melt-rate studies, chemical process cell flowsheet runs and, if needed, a glass variability study.

Peeler, D

2005-08-15T23:59:59.000Z

231

Phase-change optical recording materials based on GeSb  

Science Journals Connector (OSTI)

GeSb based materials are investigated for phase-change optical recording. Physical properties and amorphization / crystallization behavior are determined. Recording characteristics are...

Dimitrov, Dimitre

232

From plan to practice: implementing SB 617, California's regulatory review reform.  

E-Print Network [OSTI]

??SB 617 (Calderon & Pavley, 2011) is an ambitious experiment to improve state regulations and increase government transparency. The statute reforms California’s regulatory review process… (more)

Marin, Angela K.

2013-01-01T23:59:59.000Z

233

Study on the Volatility of Cesium in Dry Ashing Pretreatment and Dissolution of Ash by Microwave Digestion System - 13331  

SciTech Connect (OSTI)

Based on the regulation of the activity concentration of Cs-137, Co-58, Co-60, Fe-55, Ni-59, Ni-63, Sr-90, Nb-94, and Tc-99, and the total alpha from the radioactive waste acceptance criteria, the measurement of the activity concentration of these nuclides in low and intermediate levels of radioactive waste such as in paper, cotton, vinyl and plastic samples was investigated. A dry ashing method was applied to obtain a concentration effect of the samples. Owing to the temperature dependence of the volatility for cesium, the temperature of 300 to 650 deg. C was examined. It was found that 450 deg. C is the optimum dry ashing temperature. After dry ashing, the produced ash was dissolved with HNO{sub 3}, HCl, and HF by a high-performance microwave digestion system. The ash sample, for the most part, was completely dissolved with 10 mL of HNO{sub 3}, 4 mL of HCl, and 0.25 mL of HF by a high-performance microwave digestion system using a nova high temperature rotor at 250 deg. C for 90 min until reaching 0.2 g. To confirm the reliability of cesium loss after the performance of the dry ashing procedure, a cesium standard solution for AAS and a Cs-137 standard solution for gamma spectrometry were added to a paper towel or a planchet of stainless steel, respectively. Cesium was measured by AAS, ICP-MS, and gamma spectrometry. The volatility of cesium did not occur until 450 deg. C ashing. (authors)

Choi, Kwang-Soon; Lee, Chang Heon; Ahn, Hong-Joo; Park, Yong Joon; Song, Kyuseok [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)] [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

234

Recovery of acids and sodium hydroxide from solutions of sodium sulfate and sodium chloride with the use of bipolar membranes  

SciTech Connect (OSTI)

The authors examined the kinetic laws governing the electrodialysis recovery of hydrochloric acid and sulfuric acid, as well as sodium hydroxide, from 1M sodium chloride and 0.5 M sodium sulfate solutions and from a mixture of these salts with the use of the MB-1, MB-2, and MB-3 bipolar membranes. Kinetic plots of the current density and the concentration of the acid and the base in the chambers next to the bipolar membranes during the electrodialysis treatment of 1M sodium chloride, 0.5 M sodium sulfate, and solutions are presented. It was established that it is better to use the MB-3 membrane for the electrodialysis conversion of sodium chloride and sodium sulfate into acids and sodium hydroxide owing to the high rate and current efficiency and low expenditure of electrical energy and degree of contamination of the products obtained by the salts. It was also established that the resistance of the MB-1 and MB-2 bipolar membranes is almost an order of magnitude higher than that of the MB-3 membrane.

Bobrinskaya, G.A.; Pavlova, T.V.; Shatalov, A.Ya.

1985-09-01T23:59:59.000Z

235

2003 Conference on Unburned Carbon on Utility Fly Ash  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2003 Conference on Unburned Carbon on Utility Fly Ash 2003 Conference on Unburned Carbon on Utility Fly Ash October 28, 2003 Table of Contents Disclaimer Participants List [PDF-31KB] Papers and Presentations Control Measures Predictive Performance Tools (Including Instrumentation) Processing and Utilization of High-LOI Fly Ash Beneficiation of High-LOI Fly Ash Characterization of High-LOI Fly Ash Poster Presentations Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

236

Prediction of ash deposition in pulverized coal combustion systems  

SciTech Connect (OSTI)

A predictive scheme based on CCSEM flyash data and Computational Fluid Dynamics (CFD) has been developed to study the slagging propensity of coals. The model has been applied to predict the deposition potential of three UK coals; Bentinck, Daw Mill and Silverdale, in a pilot scale single burner ash deposition test facility and an utility size multi-burner front wall-fired furnace. The project is part of a collaborative research program sponsored by the UK Department of Trade and Industry and involved various industrial organizations and universities. The objective of the project is to understand the fundamental aspects of slagging in pulverized coal-fired combustion systems. This paper is a sequel to the poster paper entitled: The Prediction of Ash Deposition in a Coal Fired Axi-symmetric Furnace, presented in the last Engineering Foundation Conference. The present model predicts the relative slagging propensity of the three coals correctly. The predicted deposition patterns are also consistent with the observations. The results from the model indicate a preferential deposition of iron during the initial stage of ash deposition. The average compositions of the deposits become closer to that of the bulk ash when the accumulation of ash deposits is taken into account.

Lee, F.C.C.; Riley, G.S. [National Power PLC, Swindon (United Kingdom); Lockwood, F.C. [Imperial Coll. of Science, Technology and Medicine, London (United Kingdom). Dept. of Mechanical Engineering

1996-12-31T23:59:59.000Z

237

Release of Ammonium and Mercury from NOx Controlled Fly Ash  

SciTech Connect (OSTI)

One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

Schroeder, K.T.; Cardone, C.R.; Kim, A.G

2007-07-01T23:59:59.000Z

238

ADVANCED POWER SYSTEMS ASH BEHAVIOR IN POWER SYSTEMS  

SciTech Connect (OSTI)

The overall goal of this initiative is to develop fundamental knowledge of ash behavior in power systems for the purpose of increasing power production efficiency, reducing operation and maintenance costs, and reducing greenhouse gas emissions into the atmosphere. The specific objectives of this initiative focus primarily on ash behavior related to advanced power systems and include the following: ? Determine the current status of the fundamental ash interactions and deposition formation mechanisms as already reported through previous or ongoing projects at the EERC or in the literature. ? Determine sintering mechanisms for temperatures and particle compositions that are less well known and remain for the most part undetermined. ? Identify the relationship between the temperature of critical viscosity (Tcv ) as measured in a viscometer and the crystallization occurring in the melt. ? Perform a literature search on the use of heated-stage microscopy (HSM) for examining in situ ash-sintering phenomena and then validate the use of HSM in the determination of viscosity in spherical ash particles. ? Ascertain the formation and stability of specific mineral or amorphous phases in deposits typical of advanced power systems. ? Evaluate corrosion for alloys being used in supercritical combustion systems.

CHRISTOPHER J. ZYGARLICKE; DONALD P. MCCOLLOR; JOHN P. KAY; MICHAEL L. SWANSON

1998-09-01T23:59:59.000Z

239

ENVIRONMENTAL EVALUATION FOR UTILIZATION OF ASH IN SOIL STABILIZATION  

SciTech Connect (OSTI)

The Minnesota Pollution Control Agency (MPCA) approved the use of coal ash in soil stabilization, indicating that environmental data needed to be generated. The overall project goal is to evaluate the potential for release of constituents into the environment from ash used in soil stabilization projects. Supporting objectives are: (1) To ensure sample integrity through implementation of a sample collection, preservation, and storage protocol to avoid analyte concentration or loss. (2) To evaluate the potential of each component (ash, soil, water) of the stabilized soil to contribute to environmental release of analytes of interest. (3) To use laboratory leaching methods to evaluate the potential for release of constituents to the environment. (4) To facilitate collection of and to evaluate samples from a field runoff demonstration effort. The results of this study indicated limited mobility of the coal combustion fly ash constituents in laboratory tests and the field runoff samples. The results presented support previous work showing little to negligible impact on water quality. This and past work indicates that soil stabilization is an environmentally beneficial CCB utilization application as encouraged by the U.S. Environmental Protection Agency. This project addressed the regulatory-driven environmental aspect of fly ash use for soil stabilization, but the demonstrated engineering performance and economic advantages also indicate that the use of CCBs in soil stabilization can and should become an accepted engineering option.

David J. Hassett; Loreal V. Heebink

2001-08-01T23:59:59.000Z

240

Influence of Coal Ash/Organic Waste Application on Distribution of Trace Metals in Soil, Plant, and Water  

Science Journals Connector (OSTI)

This study was conducted to evaluate effects of coal ash mixture (coal ash, biosolids and yard waste compost ratio of ... fruits, and its leaching potential into groundwater. Coal ash mixture was applied at rates...

Yuncong Li; Min Zhang; Peter Stoffella; Zhenli He…

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Ash bed level control system for a fixed-bed coal gasifier  

DOE Patents [OSTI]

An ash level control system is provided which incorporates an ash level meter to automatically control the ash bed level of a coal gasifier at a selected level. The ash level signal from the ash level meter is updated during each cycle that a bed stirrer travels up and down through the extent of the ash bed level. The ash level signal is derived from temperature measurements made by thermocouples carried by the stirrer as it passes through the ash bed and into the fire zone immediately above the ash bed. The level signal is compared with selected threshold level signal to determine if the ash level is above or below the selected level once each stirrer cycle. A first counter is either incremented or decremented accordingly. The registered count of the first counter is preset in a down counter once each cycle and the preset count is counted down at a selected clock rate. A grate drive is activated to rotate a grate assembly supporting the ash bed for a period equal to the count down period to maintain the selected ash bed level. In order to avoid grate binding, the controller provides a short base operating duration time each stirrer cycle. If the ash bed level drops below a selected low level or exceeds a selected high level, means are provided to notify the operator.

Fasching, George E. (Morgantown, WV); Rotunda, John R. (Fairmont, WV)

1984-01-01T23:59:59.000Z

242

Atlas Sodium Automated Batch Synthesis System  

E-Print Network [OSTI]

Atlas Sodium Automated Batch Synthesis System (Syrris) June 2013 #12;Introduction to the system · The Atlas Sodium system consists of an Atlas base equipped with a 400ºC hotplate, a stacking dry bath systemL) for automated addition and/or removal of solution. · The system is computer controlled by the Atlas software

Subramanian, Venkat

243

The abundance of AsH3 in Jupiter  

SciTech Connect (OSTI)

Both ground-based and airborne observations of the AsH3 Q-branch at 2126/cm, in conjunction with newly-analyzed laboratory comparison spectra at AsH3, are employed in the derivation of a new estimate of Jovian As abundance. The mole fraction on AsH3 in the Jovian atmosphere is 0.22 + or - 0.11 ppb; this is merely 0.5 times the solar abundance, and a factor-of-9 less than the mole fraction found in Saturn, duplicating the pattern noted in the relative abundance of P in these two planets and furnishing a useful constraint for models of heavy element incorporation in the outer planets' gaseous envelopes. 20 refs.

Noll, K.S.; Larson, H.P.; Geballe, T.R. (Arizona Univ., Tucson (USA) Joint Astronomy Centre, Hilo, HI (USA))

1990-02-01T23:59:59.000Z

244

Direct imaging of InSb (110)-(1x1) surface grown by molecular beam epitaxy  

SciTech Connect (OSTI)

High-resolution transmission electron microscopy under a profile imaging condition (HR-profile TEM) was employed to determine the structural model for the InSb(110)-(1x1) relaxation surface grown by molecular beam epitaxy (MBE). HR-profile TEM analyses indicate that the chevron model, which is widely accepted for zinc-blende-type III-V(110)-(1x1) surfaces prepared by cleavage, is also applicable to the InSb(110)-(1x1) surface prepared under an Sb-rich MBE condition. The assignment of atomic species (In or Sb) of InSb(110)-(1x1) surfaces was confirmed based on a HR-profile TEM image that captures the connected facets of InSb(110)-(1x1) and InSb(111)B-(2x2). On the basis of the well-known atomic species of InSb(111)B-(2x2), the atomic species of the InSb(110)-(1x1) surface were deduced straightforwardly: the atoms shifted upward and downward at the topmost layer of the InSb(110)-(1x1) surface are Sb and In, respectively. The atomic arrangements of the InSb(110)-(1x1)-InSb(111)B-(2x2) facet determined by HR-profile TEM may represent the atomic arrangements of zinc-blende-type III-V(331)B surfaces.

Mishima, T. D. [Homer L. Dodge Department of Physics and Astronomy, and Center for Semiconductor Physics in Nanostructures, University of Oklahoma, Norman, Oklahoma 73019 (United States)

2011-10-01T23:59:59.000Z

245

Sodium Heat Engine Development Program  

SciTech Connect (OSTI)

The Sodium Heat Engine (SHE) is an efficient thermoelectric conversion device which directly generates electricity from a thermally regenerative electrochemical cell that relies on the unique conduction properties of {beta}{double prime}-alumina solid electrolyte (BASE). Laboratory models of a variety of SHE devices have demonstrated the feasibility and efficiency of the system, engineering development of large prototype devices has been slowed by a series of materials and fabrication problems. Failure of the electrolyte tubes has been a recurring problem and a number of possible causes have been postulated. To address these issues, a two-phase engineering development program was undertaken. This report summarizes the final results of the first phase of the program, which included extensive materials characterization activities, a study of applicable nondestructive evaluation methods, an investigation of possible stress states that would contribute to fracture, and certain operational issues associated with the electromagnetic pumps used in the SHE prototype. Mechanical and microstructural evaluation of commercially obtained BASE tubes revealed that they should be adequate for SHE applications and that sodium exposure produced no appreciable deleterious strength effects. Processing activities to produce a more uniform and smaller grain size for the BASE tubes were completed using isostatic pressing, extrusion, and slip casting. Green tubes were sintered by conventional and microwave plasma methods. Of particular interest is the residual stress state in the BASE tubes, and both analysis and nondestructive evaluation methods were employed to evaluate these stresses. X-ray and neutron diffraction experiments were performed to determine the bulk residual stresses in commercially fabricated BASE tubes; however, tube-to-tube variations and variations among the various methods employed did not allow formulation of a definitive definition of the as-fabricated stress state.

Singh, J.P.; Kupperman, D.S.; Majumdar, S.; Dorris, S.; Gopalsami, N.; Dieckman, S.L.; Jaross, R.A.; Johnson, D.L.; Gregar, J.S.; Poeppel, R.B.; Raptis, A.C.; Valentin, R.A.

1992-01-01T23:59:59.000Z

246

Analysis of Polychlorinated Dibenzofurans (PCDFs) in Fly Ash from a Waste Incineration Plant  

Science Journals Connector (OSTI)

......Article | 0 Benzofurans 0 Coal Ash 0 Particulate Matter...purification Carbon chemistry Coal Ash Gas Chromatography-Mass...Education,Departmentof Chemistry,42099 Konya,Turkey...obtained from various combustion processes.The combustionprocess......

Mustafa Pehlivan; Erol Pehlivan; Hüseyin Kara

1994-01-01T23:59:59.000Z

247

Effect of the Additives on the Desulphurization Rate of Flash Hydrated and Agglomerated CFB Fly Ash  

Science Journals Connector (OSTI)

CFB fly ash from separators was mixed with ... and water or additives was pumped into a CFB combustion chamber by a sludge pump. Because ... the temperature of flue gas was high in CFB, the fly ash was hydrated f...

D. X. Li; H. L. Li; M. Xu; J. F. Lu; Q. Liu…

2010-01-01T23:59:59.000Z

248

E-Print Network 3.0 - ash aqueous carbonation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash Summary: Jordanian oil shale ash was used as an adsorbent for the removal of...

249

SINGLE ELEMENT TEST PREDICTIONS FOR STRESS-STRAIN BEHAVIOR OF PANKI FLY-ASH  

E-Print Network [OSTI]

: Fly-ash is a waste product produced by burning of coal at thermal power plants. It is often used. Introduction Fly-ash is a fine powdery material, produced by burning of coal at thermal power plants. Fly

Prashant, Amit

250

E-Print Network 3.0 - ash silica fume Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

,and Bruce W. Ramme CBU-1996-08 REP-283 July 1996 Presented andPublished at the American Coal Ash Association... 's Twelfth International Coal Ash Use Symposium,Orlando,FL,January...

251

E-Print Network 3.0 - ash dosage du Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ash and iron-foundry baghouse dust in the manufacturing of economical self-compacting concrete... . CONCLUSIONS: The limestone-quarry fines and Class C fly ash showed...

252

E-Print Network 3.0 - ash quality characterization Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ash and iron-foundry baghouse dust in the manufacturing of economical self-compacting concrete... . CONCLUSIONS: The limestone-quarry fines and Class C fly ash showed...

253

Elemental characterization of coal ash and its leachates using sequential extraction techniques  

Science Journals Connector (OSTI)

Over 50 million tons of coal ash are produced annually in North America. Technological ... but have also increased contaminant concentrations in the ash of coal-fired boiler applications. The leaching of heavy .....

S. Landsberger; J. F. Cerbus; S. Larson

1995-05-01T23:59:59.000Z

254

Ash Transformations in the Real-Scale Pulverized Coal Combustion of South African and Colombian Coals  

Science Journals Connector (OSTI)

In this work, the formation of ash particles in the combustion of South African Klein Kopie coal and a Colombian coal was studied by measuring the ash particle characteristics upstream of the electrostatic precip...

Terttaliisa Lind; Esko I. Kauppinen…

1996-01-01T23:59:59.000Z

255

Tephrochronology and Stratigraphy of Eocene and Oligocene Volcanic Ashes of East and Central Texas  

E-Print Network [OSTI]

using neutron activation analysis (NAA) of bulk ash and glass shards, inductively coupled plasma mass spectrometry (ICPMS) of bulk ash, and electron microprobe analysis of both apatite phenocrysts and glass shards to characterize their geochemistry...

Heintz, Mindi

2013-12-02T23:59:59.000Z

256

Leaching and standing water characteristics of bottom ash and composted manure blends  

E-Print Network [OSTI]

Coal burning electrical generating facilities produce roughly 91 million metric tons of ash byproducts annually. Typically, this ash is retained at the power plant sites, adding to the cost of managing wastes at the plants. Another waste material...

Mathis, James Gregory

2001-01-01T23:59:59.000Z

257

E-Print Network 3.0 - activated fly ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 9 By-Products Utilization Summary: CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique... of...

258

E-Print Network 3.0 - ashing dry Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shrinkage of Non-Air Entrained HRWRA Concrete -0.05% 0.00% 0.05% 0... NS3, 33% Clean Coal Ash, 5% Class F Fly Ash Fig. 15 - ... Source: Wisconsin-Milwaukee, University of -...

259

E-Print Network 3.0 - alkaline coal ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... ") UTILIZING CLEAN-COAL ASH 1 This project was for the...

260

E-Print Network 3.0 - ashing wet Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 4 By-Products Utilization Summary: A3, containing 20% clean coal ash and 5% wet collected Class F ash had compressive strengths... 0 Center for...

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

E-Print Network 3.0 - ash utilization symposium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... ") UTILIZING CLEAN-COAL ASH 1 This project was for the...

262

E-Print Network 3.0 - ash material analisis Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

was used in this work. An ASTM Class F fly ash... , and N3) were proportioned with clean coal fly ash containing 22% ... Source: Wisconsin-Milwaukee, University of - Department...

263

E-Print Network 3.0 - ash dispersion utilizing Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Center for By-Products Utilization HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R... , utilization rate of such ashes is much lower compared to a...

264

E-Print Network 3.0 - alkali-activated fly ash Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 12 By-Products Utilization Summary: CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique... of...

265

E-Print Network 3.0 - ashes total contents Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fly ash content for normal concrete... contained fly ash up to a maximum of 35% of clean-coal ... Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

266

E-Print Network 3.0 - ash formation transformations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chlorinated phenols because their presence in the ash could result in the formation of dioxins and furans... THE USE OF MUNICIPAL WASTE COMBUSTOR ASH AS A PARTIAL REPLACEMENT OF...

267

High-performance, high-volume fly ash concrete  

SciTech Connect (OSTI)

This booklet offers the construction professional an in-depth description of the use of high-volume fly ash in concrete. Emphasis is placed on the need for increased utilization of coal-fired power plant byproducts in lieu of Portland cement materials to eliminate increased CO{sub 2} emissions during the production of cement. Also addressed is the dramatic increase in concrete performance with the use of 50+ percent fly ash volume. The booklet contains numerous color and black and white photos, charts of test results, mixtures and comparisons, and several HVFA case studies.

NONE

2008-01-15T23:59:59.000Z

268

Continuous air agglomeration method for high carbon fly ash beneficiation  

DOE Patents [OSTI]

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahon L. (Pittsburgh, PA); Champagne, Kenneth J. (Monongahela, PA); Finseth, Dennis H. (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

269

Continuous air Agglomeration Method for high Carbon fly ash Beneficiation  

SciTech Connect (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carbon-free mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahan L.; Champagne, Kenneth J.; Finseth, Dennis H.

1998-09-29T23:59:59.000Z

270

In-Situ Method for Treating Residual Sodium  

DOE Patents [OSTI]

A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

Sherman, Steven R.; Henslee, S. Paul

2005-07-19T23:59:59.000Z

271

In-situ method for treating residual sodium  

SciTech Connect (OSTI)

A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

Sherman, Steven R. (Idaho Falls, ID); Henslee, S. Paul (Idaho Falls, ID)

2005-07-19T23:59:59.000Z

272

The Sensitivity of DPF Performance to the Spatial Distribution of Ash Generated from Six Lubricant Formulations  

Broader source: Energy.gov [DOE]

Discusses potential of DPF pressure drop reduction by optimizing the spatial distribution of ash inside DPF inlet channel

273

Analysis of Senate Bill 365: Analysis of the Potential Impacts of SB 365: Out-of-State Carriers  

E-Print Network [OSTI]

be 8,374. Public Health Implications • Enrollees of out-of-the potential health implications of SB 365. • Severalto consider the health implications of SB 365 with regard to

California Health Benefits Review Program (CHBRP)

2007-01-01T23:59:59.000Z

274

AlSb Formation in UHV by Laser Annealing of Evaporated A1 and Sb Films. Characterization by AES and XPS  

Science Journals Connector (OSTI)

Results reported here involve the interaction of a pulsed and doubled Nd:YAG laser beam with multilayer A1 and Sb metallic samples (in stoichiometric proportion) which has been studied under ultra-high-vacuum (UHV

E. Petit; P. Warnant; P. A. Thiry; R. Caudano

1986-01-01T23:59:59.000Z

275

physica status solidi, 19 June 2012 Amorphous structures of Ge/Sb/Te  

E-Print Network [OSTI]

physica status solidi, 19 June 2012 Amorphous structures of Ge/Sb/Te alloys: Density functional functional simulations, Ge/Sb/Te alloys. Corresponding author: e-mail r.jones@fz-juelich.de, Phone: +49 discussed the alloy As30Ge10Si12Te48, and Te-based alloys have been well represented ever since. Alloys

276

Unravelling the atomic structure of AgInSbTe phase change materials: Theoretical perspective  

E-Print Network [OSTI]

E*PCOS2011 Unravelling the atomic structure of AgInSbTe phase change materials: Theoretical-GST. Key words: phase change materials, Ag/In/Sb/Te alloys, density functional, molecular dynamics 1. INTRODUCTION Phase change (PC) materials are chalcogenide alloys that switch very rapidly between the amorphous

277

GaSb/GaAs type II quantum dot solar cells for enhanced infrared spectral response  

E-Print Network [OSTI]

GaSb/GaAs type II quantum dot solar cells for enhanced infrared spectral response R. B Technology Materials, University of New Mexico, 1313 Goddard SE, Albuquerque, New Mexico 87106 Received 27 infrared spectral response of GaAs-based solar cells that incorporate type II GaSb quantum dots QDs formed

Jalali. Bahram

278

Ultralow noise midwave infrared InAsGaSb strain layer superlattice avalanche photodiode  

E-Print Network [OSTI]

Ultralow noise midwave infrared InAs­GaSb strain layer superlattice avalanche photodiode InAs­GaSb strain layer superlattice p+ -n- -n homojunction avalanche photodiodes APDs grown by solid characteristics. © 2007 American Institute of Physics. DOI: 10.1063/1.2817608 Photodiodes operating in the eye

Krishna, Sanjay

279

Describing Leaf Area Distribution in Loblolly Pine Trees with Johnson's SB Function  

E-Print Network [OSTI]

of leaf area of a wide variety of loblolly pine trees. FOR. SCI. 51(2):93­101. Key Words: ProbabilityDescribing Leaf Area Distribution in Loblolly Pine Trees with Johnson's SB Function Mauricio Jerez fractions of leaf area calculated with fitted SB functions matched measured values well; cumulative values

Cao, Quang V.

280

Interface Reactions and Electrical Characteristics of Au/GaSb Contacts  

SciTech Connect (OSTI)

The reaction of Au with GaSb occurs at a relatively low temperature (100 C). Upon annealing, a AuSb{sub 2} compound and several Au-Ga phases are produced. Phase transitions occur toward higher Ga concentration with increasing annealing temperatures. Furthermore, the depth of the contact also increases with increased annealing temperature. They found that the AuSb{sub 2} compound forms on the GaSb surface, with the compound crystal partially ordered with respect to the substrate. The transition of Schottky- to ohmic-contact behavior in Au/n-type GaSb occurs simultaneously with the formation of the AuGa compound at about a 250 C annealing temperature. This ohmic contact forms without the segregation of dopants at the metallic compound/GaSb interface. Therefore it is postulated that transition from Schottky- to ohmic-contact behavior is obtained through a series of tunneling transitions of electrons through defects in the depletion region in the Au/n-type GaSb contacts. Contact resistivities of 6-7 x 10{sup -6} {Omega}-cm{sup 2} were obtained with the annealing temperature between 300 and 350 C for 30 seconds. In Au/p-type GaSb contacts, the resistivity was independent of the annealing temperature. This suggested that the carrier transport in p-type contact dominated by thermionic emission.

H. Ehsani; R.J. Gutmann; G.W. Charache

2000-07-07T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Development of an electronic device quality aluminum antimonide (AlSb) semiconductor for solar cell applications  

DOE Patents [OSTI]

Electronic device quality Aluminum Antimonide (AlSb)-based single crystals produced by controlled atmospheric annealing are utilized in various configurations for solar cell applications. Like that of a GaAs-based solar cell devices, the AlSb-based solar cell devices as disclosed herein provides direct conversion of solar energy to electrical power.

Sherohman, John W; Yee, Jick Hong; Combs, III, Arthur W

2014-11-11T23:59:59.000Z

282

Hydrogen embrittlement of type 410 stainless steel in sodium chloride, sodium sulfate, and sodium hydroxide environments at 90 C  

SciTech Connect (OSTI)

Susceptibility of martensitic type 410 (UNS S41000) stainless steel (SS) to environmental cracking was evaluated at 90 C in concentrated sodium chloride, sodium sulfate and sodium hydroxide solutions, all of which are environments related to steam turbine conditions, using the slow strain rate testing (SSRT) technique. In NaCl, the effects of solution pH, concentration, and anodic and cathodic polarization were investigated. Tests were supplemented by detailed electron fractography and hydrogen permeation measurements. A clear correlation was found between the degree of embrittlement and the amount of hydrogen permeating the steel, suggesting a hydrogen-induced cracking mechanism.

Gonzalez-Rodriguez, J.G.; Salinas-Bravo, V.M. [Inst. de Investigaciones Electricas, Cuernavaca (Mexico). Dept. Fisico Quimica Aplicada; Martinez-Villafane, A. [Centro de Investigaciones en Materiales Avanzados Leon Tolstoi, Chihuahua (Mexico)

1997-06-01T23:59:59.000Z

283

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater  

E-Print Network [OSTI]

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater Reyad; available online 29 October 2003 Abstract A by-product fly ash from oil shale processing was converted shale; Ash; Zeolite; Cadmium and lead removal 1. Introduction Oil shale exists in Jordan with large

Shawabkeh, Reyad A.

284

Hydration and strength development of binder based on high-calcium oil shale fly ash  

SciTech Connect (OSTI)

The properties of high-calcium oil shale fly ash and low-calcium coal fly ash, which are produced in Israeli power stations, were investigated. High-calcium oil shale fly ash was found to contain a great amount of CaO{sub free} and SO{sub 3} in the form of lime and anhydrite. Mixtures of high-calcium oil shale fly ash and low-calcium coal fly ash, termed fly ash binder, were shown to cure and have improved strength. The influence of the composition and curing conditions on the compressive strength of fly ash binders was examined. The microstructure and the composition of fly ash binder after curing and long-term exposure in moist air, water and open air conditions were studied. It was determined that ettringite is the main variable in the strength and durability of cured systems. The positive effect of calcium silicate hydrates, CSH, which are formed by interaction of high-calcium oil shale fly ash and low-calcium coal fly ash components, on the carbonation and dehydration resistance of fly ash binder in open air is pronounced. It was concluded that high-calcium oil shale fly ash with high CaO{sub free} and SO{sub 3} content can be used as a binder for building products.

Freidin, C. [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)] [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)

1998-06-01T23:59:59.000Z

285

Spectroscopy of infrared emission characteristics of thermal power plant boiler coal ash deposits  

Science Journals Connector (OSTI)

Thermal radiation characteristics of ash deposits on a coal combustion boiler of an electric power plant are investigated. Normal emittance spectra in 2.5-25 µm wavelength region and total normal emittance are measured on four kinds of ash at 600-1100K ... Keywords: ash deposit, emittance, pulverized coal combustion boiler furnace, spectroscopic measurement, thermal radiation

Aleksandar Saljnikov; Darko Goricanec; Danijela Dobersek; Dorde Kozic

2007-05-01T23:59:59.000Z

286

Correlation relations between mineralogical components in ash from Kaa-Khem coals  

SciTech Connect (OSTI)

Regression analysis was used to study correlation relations between the mineral components of coals. Regularities in the variability of the concentrations of individual ash-forming elements with changing ash contents of coals and changing seam depth were found. The X-ray diffraction characteristics of coal ashes and the qualitative composition of their mineralogical components are presented.

N.N. Yanchat; L.Kh. Tas-ool [Russian Academy of Sciences, Kyzyl (Russia). Tuvinian Institute for Complex Exploration of Natural Resources

2008-08-15T23:59:59.000Z

287

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M Sulloway

2007-10-31T23:59:59.000Z

288

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M. Sulloway

2007-09-26T23:59:59.000Z

289

Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power Plants  

E-Print Network [OSTI]

/0702/citing-global- warming-georgia-judge-blocks-coal-plant/picture1.jpg/5307532-1-eng-US/picture1.jpgColor Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power color from pulp mill effluent using coal ash. Prevent coal ash adsorbent from leaching arsenic

Hutcheon, James M.

290

IEEE PHOTONICS TECHNOLOGY LETTERS 1 High-Power 2.3-m GaSb-Based Linear Laser Array  

E-Print Network [OSTI]

2.3-m laser. Al Ga As Sb cladding layers. Details of the lasers' heterostructure design can be foundIEEE PHOTONICS TECHNOLOGY LETTERS 1 High-Power 2.3-m GaSb-Based Linear Laser Array L. Shterengas, G--High-power 2.3- m In(Al)GaAsSb­GaSb type-I double quantum-well diode laser arrays were fabricated

291

Illinois SB 1987: the Clean Coal Portfolio Standard Law  

SciTech Connect (OSTI)

On January 12, 2009, Governor Rod Blagojevich signed SB 1987, the Clean Coal Portfolio Standard Law. The legislation establishes emission standards for new coal-fueled power plants power plants that use coal as their primary feedstock. From 2009-2015, new coal-fueled power plants must capture and store 50 percent of the carbon emissions that the facility would otherwise emit; from 2016-2017, 70 percent must be captured and stored; and after 2017, 90 percent must be captured and stored. SB 1987 also establishes a goal of having 25 percent of electricity used in the state to come from cost-effective coal-fueled power plants that capture and store carbon emissions by 2025. Illinois is the first state to establish a goal for producing electricity from coal-fueled power plants with carbon capture and storage (CCS). To support the commercial development of CCS technology, the legislation guarantees purchase agreements for the first Illinois coal facility with CCS technology, the Taylorville Energy Center (TEC); Illinois utilities are required to purchase at least 5 percent of their electricity supply from the TEC, provided that customer rates experience only modest increases. The TEC is expected to be completed in 2014 with the ability to capture and store at least 50 percent of its carbon emissions.

NONE

2009-01-15T23:59:59.000Z

292

SciTech Connect: Thermodynamic and transport properties of sodium...  

Office of Scientific and Technical Information (OSTI)

on thermophysical properties of sodium have been included in this critical assessment. Thermodynamic properties of sodium liquid and vapor that have been assessed...

293

High-capacity hydrogen storage in lithium and sodium amidoboranes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

capacity hydrogen storage in lithium and sodium amidoboranes. High-capacity hydrogen storage in lithium and sodium amidoboranes. Abstract: A substantial effort worldwide has been...

294

Event:Sustainable Biomass for Electricity Conference (SB4E) | Open Energy  

Open Energy Info (EERE)

Biomass for Electricity Conference (SB4E) Biomass for Electricity Conference (SB4E) Jump to: navigation, search Calendar.png Sustainable Biomass for Electricity Conference (SB4E): on 2012/05/02 The Conference on Sustainable Biomass for Electricity (SB4E), organized by UN-Energy in cooperation with the Global Bioenergy Partnership (GBEP) and other partners, will consider the role of biomass technologies in decarbonizing the global energy system. Acknowledging the readily available and cost effective potential for emission reductions that could be achieved through the large-scale deployment of sustainable biomass for electricity production, the SB4E Conference will provide an opportunity for governments, international organizations and the private sector to share knowledge, lessons, best practices and experiences and to join efforts

295

BEyond thE BAcklAsh: equity and participation  

E-Print Network [OSTI]

BEyond thE BAcklAsh: equity and participation in bicycle planning. executive summary | May 2011 Camp Conor Clarke Joe Delia Jennifer Harris-Hernandez Sungbae Park Brian Paul Scott Richmond Sam Stein Jessame Hannus ValeriaTreves Bill DiPaola Kristen Jones Paul Steely White Katie Lyon-Hart We thank

Qiu, Weigang

296

Cathode-Luminescence of Rare Earths in Coal Ash  

Science Journals Connector (OSTI)

... Samples of a number of Indian coals (from Darjeeling, Assam, Raniganj, Jharia and Hyderabad) were incinerated in thin layers ... in an electric furnace at 400° C. The presence of rare earths in the ashes so obtained could not be detected by arc spectrographic analysis with a current of 10 ...

BIBHUTI MUKHERJEE

1949-03-12T23:59:59.000Z

297

Thermal properties of high-volume fly ash  

E-Print Network [OSTI]

volume of concrete placed is receiving renewed interest. Concrete mixtures in which the fly ash replaces Academic Group on Concrete Technology, Universidad Auto´noma de Nuevo Leo´n, Monterrey, Nuevo Leo´n, Mexico are critical in assessing the potential energy efficiency of HVFA concrete structures, such as residential

Bentz, Dale P.

298

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 ``Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core`` problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-12-01T23:59:59.000Z

299

IAEA sodium void reactivity benchmark calculations  

SciTech Connect (OSTI)

In this paper, the IAEA-1 992 Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core'' problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

Hill, R.N.; Finck, P.J.

1992-01-01T23:59:59.000Z

300

Spectroscopic research on infrared emittance of coal ash deposits  

SciTech Connect (OSTI)

This paper deals with thermal radiation characteristics of ash deposits on a pulverized coal combustion boiler of an electric power plant. Normal emittance spectra in the near to medium infrared (2.5-25 {mu}m) region and total normal emittances were measured on four kinds of ground ash deposits. Measurements were conducted in the 570-1460 K temperature range which is common for boiler furnaces, by both heating and cooling the ash samples, with the aim to study the effect of their thermal history. Dependence of emittance on wavelength, temperature and chemical composition was studied, too. Samples were tested for transparency (opacity) to verify the accuracy of results. It was determined that the thicknesses used for the ash powders are opaque for infrared radiation for thicknesses in the order of a millimeter. Tests have shown that spectral emittance increases with an increase of wavelength with a characteristic pattern common for all samples. Spectral normal emittance increases strongly with temperature at shorter wavelengths and remains high and unchanged at longer ones. Emittance spectra are not very sensitive to chemical composition of ashes especially beyond {lambda} {approx} 5 {mu}m. With an increase of temperature, total emittance of the powdered sample decreases to a minimum value around 1200 K. Further temperature rise induces an increase of total emittance due to sintering in the ash. On cooling, the emittance increases monotonically following the hysteresis. Quantitative directions for evaluating thermal radiation characteristics of ash deposits for the merits of the safety design of boiler furnaces were proposed. That comprises correlating the experimentally obtained emittance spectra with curves of simple analytical form, i.e., a continuous function of minimum emittance vs. wavelength. The proposed method can be extended to other specimens from the same furnace and used to determine correlations for thermal calculation of old and design of new furnaces - with similar geometry and combusting similar coal. The method is potentially applicable to completely different boiler furnaces combusting different coal, and the authors recommend running the tests with new deposit samples. The data will then be applicable to the thermal design of a whole new class of furnaces, having similar geometry and combusting similar coal. This is expected to greatly enhance the accuracy and precision of thermal calculation as well as the efficiency of thermal design of steam boilers. (author)

Saljnikov, Aleksandar; Komatina, Mirko; Gojak, Milan [Department of Thermomechanics, Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11120 Belgrade 35 (RS); Vucicevic, Biljana [Laboratory for Thermal Engineering, Institute of Nuclear Sciences VINCA, P.O. Box 522, Belgrade 11001 (RS); Goricanec, Darko [Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, Maribor 2000 (Slovenia); Stevanovic, Zoran [Faculty of Mining and Geology, University of Belgrade, Dusina 7, 11120 Belgrade 35 (RS)

2009-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Soil stabilization and pavement recycling with self-cementing coal fly ash  

SciTech Connect (OSTI)

This manual provides design information for self-cementing coal fly ash as the sole stabilizing agent for a wide range of engineering applications. As in any process, the application of sound engineering practices, appropriate testing, and evaluation of fly ash quality and characteristics will lend themselves to successful projects using the guidelines in this manual. Topics discussed include: self-cementing coal fly ash characteristics; laboratory mix design; stabilization of clay soils; stabilisation of granular materials; construction considerations; high sulfate ash; environmental considerations for fly ash stabilization; design considerations; state specification/guidelines/standards; and a sample of a typical stabilization specification.

NONE

2008-01-15T23:59:59.000Z

302

Environment impact from ash disposal of the thermal power plant 'Kosova A'  

Science Journals Connector (OSTI)

Mining activities impact on environment is as old as these activities themselves. It is estimated that thermal power plants in Kosova produce about 1.6 million tons of ash per year, and all ash produced is disposed as waste material. The main problems for environment pollution are the ash dumps containing more than 40 million tons of ash cover about 150 ha of land. The ash dumps sites of the thermal power plant Kosovo 'A', which are situated among settlement, present one of the most serious problems in the environment and are one of the potential dangers for underground and surface water.

Sabri Avdullahi; Isalm Fejza; Raif Bytyqi

2010-01-01T23:59:59.000Z

303

Ash Research from Palm Coast, Florida to Banff, Canada: Entry of Biomass in Modern Power Boilers  

Science Journals Connector (OSTI)

Six laboratories participated, and each performed five analyses, on three bituminous coal samples, focusing on their content of calcite, kaolinite, pyrite, and quartz. ... CCSEM of these ashes revealed that the fly ashes and deposits contained high quantities of salts, especially KCl, and varying quantities of K- and Ca-silicates, whereas the bottom ashes consisted of a mixture of quartz, K-, Ca-, and Al-silicates. ... Wang and Baxter(134) presented a work that systematically investigated the performance of biomass fly ash concrete, including mixtures of biomass fly ash and calcium hydroxide, with respect to strength, kinetics, and durability. ...

Flemming J. Frandsen

2009-04-23T23:59:59.000Z

304

Ash vaporization in circulating fluidized bed coal combustion  

SciTech Connect (OSTI)

In this work, the vaporization of the ash-forming constituents in circulating fluidized bed combustion (CFBC) in a full-scale 80 MW{sub th} unit was studied. Ash vaporization in CFBC was studied by measuring the fly ash aerosols in a full-scale boiler upstream of the electrostatic precipitator (ESP) at the flue gas temperature of 125{degree}C. The fly ash number size distributions showed two distinct modes in the submicrometer size range, at particle diameters 0.02 and 0.3 {mu}m. The concentration of the ultrafine 0.02-{mu}m mode showed a large variation with time and it decreased as the measurements advanced. The concentration of the 0.02-{mu}m mode was two orders of magnitude lower than in the submicrometer mode observed earlier in the bubbling FBC and up to three orders of magnitude lower than in the pulverized coal combustion. Scanning electron micrographs showed few ultrafine particles. The intermediate mode at 0.3 {mu}m consisted of particles irregular in shape, and hence in this mode the particles had not been formed via a gas to particle route. We propose that the 0.3-{mu}m mode had been formed from the partial melting of the very fine mineral particles in the coal. The mass size distribution in the size range 0.01-70 {mu}m was unimodal with maximum at 20 {mu}m. Less than 1% of the fly ash particles was found in the submicrometer size range. 35 refs., 8 figs., 3 tabs.

Lind, T.; Kauppinen, E.I.; Maenhaut, W. [Univ. of Gent (Belgium); Shah, A.; Huggins, F. [Univ. of Kentucky, Lexington, KY (United States)

1996-04-01T23:59:59.000Z

305

Sodium Alanate Nanoparticles for Hydrogen Storage.  

E-Print Network [OSTI]

??Preparation and characterization of sodium alanate (NaAlH4) based hydrogen storage materials are described in this book. The effect of the NaAlH4 particle size, particularly in… (more)

Baldé, C.P.

2008-01-01T23:59:59.000Z

306

Kinetics of wet sodium vapor complex plasma  

SciTech Connect (OSTI)

In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

2014-04-15T23:59:59.000Z

307

Utilization of SRS pond ash in controlled low strength material. Technical report  

SciTech Connect (OSTI)

Design mixes for Controlled Low Strength Material (CLSM) were developed which incorporate pond ashes (fly ashes) from the A-Area Ash Pile, the old F-Area Ash Basin and the D-Area Ash Basin. CLSM is a pumpable, flowable, excavatable backfill used in a variety of construction applications at SRS. Results indicate that CLSM which meets all of the SRS design specifications for backfill, can be made with the A-, D-, and F-Area pond ashes. Formulations for the design mixes are provided in this report. Use of the pond ashes may result in a cost savings for CLSM used at SRS and will utilize a by-product waste material, thereby decreasing the amount of material requiring disposal.

Langton, C.A.; Rajendran, N.

1995-12-01T23:59:59.000Z

308

Test research of bed ash coolers for a 50 MWe CFB boiler  

SciTech Connect (OSTI)

CFB boilers have been developed and commercialized in China. As one of the main auxiliaries of FBC boilers, the bed ash cooler plays an important role in regular operation of the boilers. A 50 MWe 2-shaped CFB boiler will be put into operation in North China. Many kinds of bed ash cooling systems for this boiler had been designed and compared. Then the optimum bed ash coolers were determined and made. Experimental research and pilot-scale test for the bed ash coolers were also carried out. The result indicates that the bed ash cooler can be operated reliably and can meet the demand for cooling bed ash of the 50 MWe CFB boiler. The test data are very useful for further improving the performance of ash coolers.

Chen, H.P.; Lu, J.D.; Lin, Z.J.; Liu, D.C. [Huazhong Univ. of Science and Technology, Wuhan, Hubei (China). National Lab. of Coal Combustion; Hu, L.L.; Xie, P.J.; Yan, H.X.; Liu, M.C. [Hubei Boiler Auxiliary Factory, Jingshan, Hubei (China)

1995-12-31T23:59:59.000Z

309

Effects of Bi doping on the thermoelectric properties of ? -Zn 4 Sb 3  

Science Journals Connector (OSTI)

The thermoelectricproperties of Bi-doped compounds ( Zn 1 ? x Bi x ) 4 Sb 3 ( x = 0 0.0025 0.005 0.01 ) were studied experimentally as well as theoretically. The results indicate that low-temperature ( T 9975 Bi 0.0025 ) 4 Sb 3 reduces remarkably as compared with that of Zn 4 Sb 3 due to enhanced phonon scattering of impurity (dopant).Electrical resistivity and Seebeck coefficient increase monotonically with increase in the Bi content resulting mainly from decrease in carrier concentration. Moreover first-principle calculations were performed on the occupation options of Bi atoms in ? -Zn 4 Sb 3 which show that Bi will preferentially occupy the Zn sites and not Sb sites and act as donors being consistent with the experimental observations. In addition the lightly doped compound ( Zn 0.9975 Bi 0.0025 ) 4 Sb 3 exhibits the best thermoelectric performance due to the improvement in both its thermal conductivity and Seebeck coefficient whose figure of merit Z T is about 1.5 times larger than that of ? -Zn 4 Sb 3 at 300 K.

X. Y. Qin; M. Liu; L. Pan; H. X. Xin; J. H. Sun; Q. Q. Wang

2011-01-01T23:59:59.000Z

310

Leaching of mixtures of biochar and fly ash  

SciTech Connect (OSTI)

Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments. Both the residual char from biomass pyrolysis (biochar) and fly ash from coal combustion have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations. Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and decreases available aluminum. A combination of these benefits likely is responsible for observed increases in yields for crops such as corn and sugarcane. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) than do unamended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way. Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil. Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes. In the present study, we examined the properties of mixtures of biochar, fly ash, and soil and evaluated the leaching of organic carbon and metals from these mixtures. The carbon sorption experiments showed release of carbon from biochar, rather than sorption, except at the highest concentrations in the Biochar HW sample. Similar results were obtained by others for oxidative leaching of bituminous coal, in which more C was released as dissolved C than was oxidized to CO2 by the oxygen in water. We confirmed that both fly ash and two types of biochar (oak char [OKEB], and hardwood [HW] char) exhibited minimal leaching of heavy metals including Cr, Ni, Zn, Ga, and Ag, and no detectable leaching of Pb or Cd (data not shown) under the conditions tested. The Biochar HW had a slightly higher C/N ratio (334) and pH (7.7) than did the Biochar OKEB (284 and 6.5). There was no toxicity exhibited by the fly ash (not shown) or biochar leachates as measured by the Microtox© assay under the conditions tested. In previous results no toxicity was reported in testing the fly ash samples except for one high-pH sample. The most notable leachate component from both types of biochar, but not the fly ash, was organic carbon with the HW biochar leaching less organic carbon than the OKEB biochar (5.71 ppm vs. 59.3 ppm). Alone (in batch sorption experiments), or in mixtures of 90% soil and 10% biochar (column studies), we noted significant loss of carbon from the biochar into soluble components. However, when we added fly ash to the column experiments (80% soil, 10% fly ash, and 10% biochar) we observed significant decreases in the amounts of C leached (20% for HW, and 47% for OKEB). The results indicate that applying a combination of fly ash and biochar may result in maximizing the amount of carbon sequestration in soil while also increasing beneficial soil properties and fertility. The lower amount of carbon leached from the HW biochar compared to the OKEB biochar is likely due to the more recalcitrant form of the carbon in the HW char, due to its preparation at a higher temperature (600 şC) than the OKEB biochar (450 şC). High heat treatment temperatures during biochar preparation increase both the total carbon content of the biochar and the proportion of the carbon that is present in fused aromatic rings resistant to chemical and physical degradation.

Palumbo, Anthony V.; Porat, Iris; Phillips, Jana R.; Amonette, James E.; Drake, Meghan M.; Brown, Steven D.; Schadt, Christopher W.

2009-06-22T23:59:59.000Z

311

The Sodium Process Facility at Argonne National Laboratory-West  

SciTech Connect (OSTI)

Argonne National Laboratory-West (ANL-W) has approximately 680,000 liters of raw sodium stored in facilities on site. As mandated by the State of Idaho and the US Department of Energy (DOE), this sodium must be transformed into a stable condition for land disposal. To comply with this mandate, ANL-W designed and built the Sodium Process Facility (SPF) for the processing of this sodium into a dry, sodium carbonate powder. The major portion of the sodium stored at ANL-W is radioactively contaminated. The sodium will be processed in three separate and distinct campaigns: the 290,000 liters of Fermi-1 primary sodium, the 50,000 liters of the Experimental Breeder Reactor-II (EBR-II) secondary sodium, and the 330,000 liters of the EBR-II primary sodium. The Fermi-1 and the EBR-II secondary sodium contain only low-level of radiation, while the EBR-II primary sodium has radiation levels up to 0.5 mSv (50 mrem) per hour at 1 meter. The EBR-II primary sodium will be processed last, allowing the operating experience to be gained with the less radioactive sodium prior to reacting the most radioactive sodium. The sodium carbonate will be disposed of in 270 liter barrels, four to a pallet. These barrels are square in cross-section, allowing for maximum utilization of the space on a pallet, minimizing the required landfill space required for disposal.

Michelbacher, J.A.; Henslee, S.P. McDermott, M.D.; Price, J.R.; Rosenberg, K.E.; Wells, P.B.

1998-07-01T23:59:59.000Z

312

Energy level spectroscopy of InSb quantum wells using quantum-well LED emission  

Science Journals Connector (OSTI)

We have investigated the low-temperature optical properties of InSb quantum-well (QW) light-emitting diodes, with different barrier compositions, as a function of well width. Three devices were studied: QW1 had a 20 nm undoped InSb quantum well with a barrier composition of Al0.143In0.857Sb, QW2 had a 40 nm undoped InSb well with a barrier composition of Al0.077In0.923Sb, and QW3 had a 100 nm undoped InSb well with a barrier composition of Al0.025In0.975Sb. For QW1, the signature of two transitions (CB1-HH1 and CB1-HH2) can be seen in the measured spectrum, whereas for QW2 and QW3 the signature of a large number of transitions is present in the measured spectra. In particular transitions to HH2 can be seen, the first time this has been observed in AlInSb/InSb heterostructures. To identify the transitions that contribute to the measured spectra, the spectra have been simulated using an eight-band k.p calculation of the band structure together with a first-order time-dependent perturbation method (Fermi golden rule) calculation of spectral emittance, taking into account broadening. In general there is good agreement between the measured and simulated spectra. For QW2 we attribute the main peak in the experimental spectrum to the CB2-HH1 transition, which has the highest overall contribution to the emission spectrum of QW2 compared with all the other interband transitions. This transition normally falls into the category of “forbidden transitions,” and in order to understand this behavior we have investigated the momentum matrix elements, which determine the selection rules of the problem.

T. G. Tenev; A. Palyi; B. I. Mirza; G. R. Nash; M. Fearn; S. J. Smith; L. Buckle; M. T. Emeny; T. Ashley; J. H. Jefferson; C. J. Lambert

2009-02-02T23:59:59.000Z

313

Electronic and structural response of InSb to ultra-short and ultra-intense laser pulses  

E-Print Network [OSTI]

intensity of Ac 2. 00 gauss. cm. lrn(&(l'1)) for lnSb for a field intensity of A&i ? 2. 23 gauss cm. Im(e(E)) for InSb for a field intensity of A&i -- 2. 40 gauss cm. hn(e(E)) for InSb for a field intensity of A&i 2. 82 gauss cm. Im(&(E)) for InSb for a...-correlation function for InSb for a field intcnsit, y of Ac ? 2. 00 gauss cin. 21 Tiiiic. cvoluti&m of thc pair-correlation function for lnSb for a field intensity of As = 2. 46 gauss cm. 44 Time evolution of the pair-correlation function for InSb for a field...

Burzo, Andrea Mihaela

2001-01-01T23:59:59.000Z

314

JV Task 6 - Coal Ash Resources Research Consortium Research  

SciTech Connect (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of coal combustion by-products (CCBs). CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCB utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program (JSRP), which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCB performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 1998 to 2007 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCBs. CARRC topical reports were prepared on several completed tasks. Specific CARRC 1998B2007 accomplishments included: (1) Development of several ASTM International Standard Guides for CCB utilization applications. (2) Organization and presentation of training courses for CCB professionals and teachers. (3) Development of online resources including the Coal Ash Resource Center, Ash from Biomass in Coal (ABC) of cocombustion ash characteristics, and the Buyer's Guide to Coal-Ash Containing Products. In addition, development of expanded information on the environmental performance of CCBs in utilization settings included the following: (1) Development of information on physical properties and engineering performance for concrete, soil-ash blends, and other products. (2) Training of students through participation in CARRC research projects. (3) Participation in a variety of local, national, and international technical meetings, symposia, and conferences by presenting and publishing CCB-related papers.

Debra Pflughoeft-Hassett; Tera Buckley; Bruce Dockter; Kurt Eylands; David Hassett; Loreal Heebink; Erick Zacher

2008-04-01T23:59:59.000Z

315

Characterization of GaSb/GaAs interfacial misfit arrays using x-ray diffraction  

Science Journals Connector (OSTI)

We report a nondestructive large-area method to characterize dislocation formation at a highly lattice-mismatched interface. The analysis is based on x-ray diffraction and reciprocal space mapping using a standard lab-based diffractometer. We use this technique to identify and analyze a two-dimensional array of 90° misfit dislocations at a GaSb/GaAs interface. The full width at half maximum of the GaSb 004 reciprocal lattice point is shown to decrease with increasing GaSb epilayer thickness as expected from theoretical models. Based on these measurements the variation in the spatial dislocation frequency is calculated to be 1%.

Charles J. Reyner; Jin Wang; Kalyan Nunna; Andrew Lin; Baolai Liang; Mark S. Goorsky; D. L. Huffaker

2011-01-01T23:59:59.000Z

316

EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS  

SciTech Connect (OSTI)

Tests were performed in simulated flue gas streams using two fly ash samples from the electrostatic precipitators of two full-scale utility boilers. One fly ash was derived from a Powder River Basin (PRB) coal, while the other was derived from Blacksville coal (Pittsburgh No. 8 seam). The tests were performed at temperatures of 120 and 180 C under different gas compositions using whole fly ash samples as well as magnetic and nonmagnetic concentrates from sized fly ash. Only the Blacksville ash contained magnetic phases. The whole and fractionated fly ash samples were analyzed for morphology, chemical composition, mineralogical composition, total organic carbon, porosity, and surface area. Mineralogically, the Blacksville ash was composed predominantly of magnetite, hematite, quartz, and mullite, while the PRB ash contained mostly quartz with lesser amounts of lime, periclase, and calcium aluminum oxide. The iron oxides in the Blacksville ash were concentrated almost entirely in the largest size fraction. As anticipated, there was not a clean separation of magnetic (Fe-rich) and nonmagnetic (aluminosilicate-rich) phases for the Blacksville ash. The Blacksville ash had a significantly higher surface area and a much higher unburned carbon content than the PRB ash. Elemental mercury (Hg) streams were injected into the simulated flue gas and passed over filters (housed in a convection oven) loaded with fly ash. Concentrations of total, oxidized, and elemental Hg downstream from the ash samples were determined by the Ontario Hydro Method. The gas stream composition and whether or not ash was present in the gas stream were the two most important variables. Based on the statistical analyses, the presence of HCl, NO, NO{sub 2}, and SO{sub 2} and all two-way gas interactions were significant. In addition, it appears that even four-factor interactions between those gases are significant. The HCl, NO{sub 2}, and SO{sub 2} were critical gases resulting in Hg oxidation, while the presence of NO appeared to suppress oxidation. The Blacksville fly ash tended to show slightly more catalytic activity than the PRB fly ash, but this could be largely due to the higher surface area of the Blacksville ash. Temperature was not a statistically important factor. The magnetic (Fe-rich) phases did not appear to be more catalytically active than the nonmagnetic phases, and unburned carbon did not appear to play a critical role in oxidation chemistry.

Unknown

2000-10-01T23:59:59.000Z

317

Improvement in the quantum sensitivity of InAs/InAsSb/InAsSbP heterostructure photodiodes  

SciTech Connect (OSTI)

InAs/InAs{sub 0.88}Sb{sub 0.12}/InAs{sub 0.50}Sb{sub 0.20}P{sub 0.30} heterostructure photodiodes operating at room temperature in the spectral range 1-4.8 {mu}m are developed. It is shown that the formation of a curvilinear reflecting surface constituted by a number of hemispheres on the rearside of the photodiode chip leads to an increase in the quantum sensitivity of the photodiodes by a factor of 1.5-1.7 at wavelengths in the range 2.2-4.8 {mu}m. At an exposed photodiode area of 0.9 mm{sup 2} and a p-n junction area of 0.15 mm{sup 2}, a zero-bias differential resistance of 30 {Omega} and a quantum sensitivity of 0.24 electron/photon at a wavelength of 3 {mu}m are obtained. The operation of a photodiode with re-reflection of the photon flux in the crystal due to reflection from the curvilinear surface of the rearside of the photodiode chip is theoretically analyzed. The possibility of effective conversion of the re-reflected flux of photons into a photocurrent, with a simultaneous decrease in the p-n junction area, is demonstrated. An increase in the quantum sensitivity in the short-wavelength spectral range 1-2.2 {mu}m by 35% relative to the calculated data is observed, which is probably due to impact ionization in the narrow-gap active region.

Imenkov, A. N.; Grebenshchikova, E. A., E-mail: eagr.iropt7@mail.ioffe.ru; Starostenko, D. A.; Sherstnev, V. V.; Konovalov, G. G.; Andreev, I. A.; Yakovlev, Yu. P. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)

2013-05-15T23:59:59.000Z

318

14 2010 Proceedings Symposium on Ash in North America GTR-NRS-P-72 SILVICS AND SILVICULTURE OF ASH IN MIXED HARDWOOD  

E-Print Network [OSTI]

IN MIXED HARDWOOD FORESTS OF THE SOUTHERN BOTTOMLANDS AND LOESSIAL HILLS Steve Meadows U.S. Forest Service wet bottomland sites. White ash is the primary ash species in the loessial hills and on other upland sites across the South. The natural range, distribution across site types, and associated forest cover

319

Blue Ash, Ohio: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Blue Ash, Ohio: Energy Resources Blue Ash, Ohio: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.2320029°, -84.3782734° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.2320029,"lon":-84.3782734,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

320

Utilization of Biomineralization Processes with Fly Ash for Carbon Sequestration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization of Biomineralization Processes with Fly Ash Utilization of Biomineralization Processes with Fly Ash for Carbon Sequestration Y. Roh (rohy@ornl.gov; 865-576-9931) T. J. Phelps (phelpstj1@ornl.gov; 865-574-7290) Environmental Sciences Division, Oak Ridge National Laboratory*, Oak Ridge, TN 37831-6036 A. D. McMillan (mcmillanad@ornl.gov; 865-241-4554) R. J. Lauf (laufrj@ornl.gov; 865-574-5176) Metal and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6085 *Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under contract number DE-AC05-00OR22725 Introduction The Department of Energy (DOE) Energy Information Administration estimates atmospheric greenhouse gas releases may exceed 8 billion metric tons by the year 2010 heightening its international environmental concern. Carbon dioxide will dominate the

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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321

Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin  

Broader source: Energy.gov (indexed) [DOE]

Site (SRS) recently cleaned up a 17- Site (SRS) recently cleaned up a 17- acre basin containing coal ash residues from Cold War operations. The American Recovery and Reinvestment Act project was safely completed at a cost of $8.9 million, $2.9 million under budget. The manmade earthen basin received ash from the former R Area Pow- erhouse operations, which ended in 1964. The first of five reactors con- structed at SRS, the R Reactor produced nuclear materials for national defense. Recovery Act funding allowed SRS to accelerate cleanup of the basin and complete the project five years earlier than the target set in a regu- latory schedule. In late 2010, the U.S. Environmental Protection Agency and South Carolina Department of Health and Environmental Control determined the closure met all regulatory requirements after inspection

322

Limestone and Ash Storage Silos and Lime Preparation Equipment, Part  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Limestone and Ash Storage Silos and Lime Preparation Equipment, Part Limestone and Ash Storage Silos and Lime Preparation Equipment, Part of the System to Inject Limestone Sorbent for SO, Control. Nucla, CO Nucla...continued Before being repowered, the plant consisted of three 12 MWe coal stoker- fired units built in 1959, which were taken out of service in 1984 due to low efficiency and high fuel cost. Antici- pating a need for additional power in the early 1990s. and after review of many power generation alternatives, CUEA started constmction of the re- powered Nucla CFB plant in Novem- ber 1984 and completed the project in May 1987. The original boilers were replaced with a new Fympower Corp. CFB bailer, a new high pressure 74 MWe steam turbine generator was installed, the three original 12 MWe steam turbines were

323

Ultrasonic ash/pyrite liberation. Final technical report  

SciTech Connect (OSTI)

The objective of this project was to develop a coal preparation concept which employed ultrasonics to precondition coal prior to conventional or advanced physical beneficiation processes such that ash and pyrite separation were enhanced with improved combustible recovery. Research activities involved a series of experiments that subjected three different test coals, Illinois No. 6, Pittsburgh No. 8, and Upper Freeport, ground to three different size fractions (28 mesh {times} 0, 200 mesh {times} 0, and 325 mesh {times} 0), to a fixed (20 kHz) frequency ultrasonic signal prior to processing by conventional and microbubble flotation. The samples were also processed by conventional and microbubble flotation without ultrasonic pretreatment to establish baseline conditions. Product ash, sulfur and combustible recovery data were determined for both beneficiation processes.

Yungman, B.A.; Buban, K.S.; Stotts, W.F.

1990-06-01T23:59:59.000Z

324

Ash reduction in clean coal spiral product circuits  

SciTech Connect (OSTI)

The article describes the Derrick Corporation's Stack Sizer{trademark} technology for high capacity fine wet cleaning with long-lasting high open-area urethane screen panels. After field trials, a Stack Sizer fitted with a 100-micron urethane panel is currently processing approximately 40 stph of clean coal spiral product having about 20% ash at McCoy-Elkhorn's Bevin Branch coal preparation plant in Kentucky, USA. Product yield is about 32.5 short tons per hour with 10% ash. The material is then fed to screen bowl centrifuges for further processing. At Blue Diamond Coal's Leatherwood preparation plant similar Stacker Sizers are achieving the same results. 2 figs., 3 tabs., 2 photo.

Brodzik, P.

2007-04-15T23:59:59.000Z

325

Microsoft Word - CX-Ashe-CGSFiberInstallation_WEB.doc  

Broader source: Energy.gov (indexed) [DOE]

5, 2011 5, 2011 REPLY TO ATTN OF: KEP-4 SUBJECT: Environmental Clearance Memorandum Debbie Ruckwardt Electrical Engineer - TEP-CSB-1 Proposed Action: Installing fiber optic cables between Bonneville Power Administration's (BPA) Ashe Substation and Energy Northwest's Columbia Generating Station (CGS). Budget Information: Work Order # 00261540 PP&A Project No.: PP&A 1864 Categorical Exclusion Applied (from Subpart D, 10 C.F.R. Part 1021): B1.3, Routine maintenance activities...for structures, rights of way, infrastructures such as roads, equipment... routine maintenance activities, corrective....are required to maintain...infrastructures...in a condition suitable for a facility to be used for its designed purpose. Location: The project takes place between BPA's Ashe Substation and Energy Northwest's

326

Ash Fork, Arizona: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Ash Fork, Arizona: Energy Resources Ash Fork, Arizona: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 35.2250114°, -112.4840675° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.2250114,"lon":-112.4840675,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

327

Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char  

SciTech Connect (OSTI)

In the study, two fly ash samples from Texaco gasifiers were compared to coal char and the physical and chemical properties and reactivity of samples were investigated by scanning electron microscopy (SEM), SEM-energy-dispersive spectrometry (EDS), X-ray diffraction (XRD), N{sub 2} and CO{sub 2} adsorption method, and isothermal thermogravimetric analysis. The main results were obtained. The carbon content of gasified fly ashes exhibited 31-37%, which was less than the carbon content of 58-59% in the feed coal. The fly ashes exhibited higher Brunauer-Emmett-Teller (BET) surface area, richer meso- and micropores, more disordered carbon crystalline structure, and better CO{sub 2} gasification reactivity than coal char. Ashes in fly ashes occurred to agglomerate into larger spherical grains, while those in coal char do not agglomerate. The minerals in fly ashes, especial alkali and alkaline-earth metals, had a catalytic effect on gasification reactivity of fly ash carbon. In the low-temperature range, the gasification process of fly ashes is mainly in chemical control, while in the high-temperature range, it is mainly in gas diffusion control, which was similar to coal char. In addition, the carbon in fly ashes was partially gasified and activated by water vapor and exhibited higher BET surface area and better gasification activity. Consequently, the fact that these carbons in fly ashes from entrained flow gasifiers are reclaimed and reused will be considered to be feasible. 15 refs., 7 figs., 5 tabs.

Jing Gu; Shiyong Wu; Youqing Wu; Ye Li; Jinsheng Gao [East China University of Science and Technology, Shanghai (China). Department of Chemical Engineering for Energy Resources and Key Laboratory of Coal Gasification of Ministry of Education

2008-11-15T23:59:59.000Z

328

Construction of an embankment with a fly and bottom ash mixture: field performance study  

SciTech Connect (OSTI)

Fly ash and bottom ash are coal combustion by-products (CCBPs) that are generated in large quantities throughout the world. It is often economical to dispose ash as mixtures rather than separately; that notwithstanding, only a few studies have been performed to investigate the behavior of fly and bottom ash mixtures, particularly those with high contents of fly ash. Also, there is very limited data available in the literature on the field performance of structures constructed using ash mixtures. This paper describes the construction and the instrumentation of a demonstration embankment built with an ash mixture (60:40 by weight of fly ash:bottom ash) on State Road 641, Terre Haute, Ind. Monitoring of the demonstration embankment was conducted for a period of 1 year from the start of construction of the embankment. The settlement of the embankment stabilized approximately 5 months after the end of its construction. According to horizontal inclinometer readings, the differential settlement at the top of the embankment is about 5 mm. Results from field quality control tests performed during construction of the demonstration embankment and monitoring data from vertical and horizontal inclinometers and settlement plates indicate that the ash mixture investigated can be considered an acceptable embankment construction material.

Yoon, S.; Balunaini, U.; Yildirim, I.Z.; Prezzi, M.; Siddiki, N.Z. [Louisiana Transportation Research Center, Baton Rouge, LA (United States)

2009-06-15T23:59:59.000Z

329

Effects of pulverized coal fly-ash addition as a wet-end filler in papermaking  

SciTech Connect (OSTI)

This experimental study is based on the innovative idea of using pulverized coal fly ash as a wet-end filler in papermaking. This is the first evaluation of the possible use of fly ash in the paper industry. Coal-based thermal power plants throughout the world are generating fly ash as a solid waste product. The constituents of fly ash can be used effectively in papermaking. Fly ash has a wide variation in particle size, which ranges from a few micrometers to one hundred micrometers. Fly ash acts as an inert material in acidic, neutral, and alkaline papermaking processes. Its physical properties such as bulk density (800-980 kg/m{sup 3}), porosity (45%-57%), and surface area (0.138-2.3076 m{sup 2}/g) make it suitable for use as a paper filler. Fly ash obtained from thermal power plants using pulverized coal was fractionated by a vibratory-sieve stack. The fine fraction with a particle size below 38 micrometers was used to study its effect on the important mechanical-strength and optical properties of paper. The effects of fly-ash addition on these properties were compared with those of kaolin clay. Paper opacity was found to be much higher with fly ash as a filler, whereas brightness decreased as the filler percentage increased Mechanical strength properties of the paper samples with fly ash as filler were superior to those with kaolin clay.

Sinha, A.S.K. [SLIET, Longowal (India). Dept. of Chemical Technology

2008-09-15T23:59:59.000Z

330

Idaho Nuclear Technology and Engineering Center (INTEC) (formerly ICPP) ash reutilization study  

SciTech Connect (OSTI)

Since 1984, the coal-fired plant at the Idaho Nuclear Technology and Engineering Center (INTEC, formerly Idaho Chemical Processing Plant) has been generating fly ash at a rate of approximately 1,000 tons per year. This ash is hydrated and placed in an ash bury pit near the coal-fired plant. The existing ash bury pit will be full in less than 1 year at its present rate of use. A conceptual design to build a new ash bury pit was completed, and the new pit is estimated to cost $1.7 million. This report evaluates ash reutilization alternatives that propose to eliminate this waste stream and save the $1.7 million required to build a new pit. The alternatives include using ash for landfill day cover, concrete admixture, flowable fill, soil stabilization, waste remediation, and carbon recovery technology. Both physical and chemical testing, under the guidance of the American Society for Testing and Materials, have been performed on ash from the existing pit and from different steps within the facility`s processes. The test results have been evaluated, compared to commercial ash, and are discussed as they relate to reutilization alternatives. This study recommends that the ash be used in flowable fill concrete for Deactivation and Demolition work at the Idaho National Engineering and Environmental Laboratory.

Langenwalter, T.; Pettet, M.; Ochoa, R.; Jensen, S.

1998-05-01T23:59:59.000Z

331

Classification of carbon in Canadian fly ashes and their implications in the capture of mercury  

Science Journals Connector (OSTI)

Fly ashes produced from Canadian power plants using pulverized coal and fluidized bed combustors were examined for their carbon content to determine their ability to capture mercury. The feed coal used in these power plants were lignite, subbituminous, high and medium volatile bituminous, their blends, and also blends of coal with petroleum coke (Petcoke). The carbon and mercury content of the coals and fly ashes were determined using the ASTM standard method and by the cold vapour atomic absorption spectrometry method. The carbon content of the fly ash was concentrated by strong acid digestion using \\{HCl\\} and HF. The quantitative and qualitative analyses of the carbon concentrate were made by using a reflected light microscope. The results show that the carbon content of fly ash appears to be partially related to depositional environment during coalification and to the rank of the coal. The Hg captured by the fly ash depends on the rank and blend of the feed coals and the type of carbon in the fly ash. The isotropic vitrinitic char is mostly responsible for the capture of most Hg in fly ash. The inadvertent increase in carbon content due to the blending of coal with petroleum coke did not increase the amount Hg captured by the fly ash. The fly ash collected by the hot side electrostatic precipitator has a low Hg content and no relation between the Hg and carbon content of the ash was observed. These results indicate that the quantity of carbon in the fly ash alone does not determine the amount Hg captured. The types of carbon present (isotropic and anisotropic vitrinitic, isotropic inertinitic and anisotropic Petcoke), the halogen content, the types of fly ash control devices, and the temperatures of the fly ash control devices all play major roles in the capture of Hg.

Fariborz Goodarzi; James C. Hower

2008-01-01T23:59:59.000Z

332

Leaching characteristics of arsenic and selenium from coal fly ash: role of calcium  

SciTech Connect (OSTI)

Understanding the leaching behavior of arsenic (As) and selenium (Se) in coal fly ash is important in evaluating the potential environmental impact of coal fly ash. Batch experiments were employed to systematically investigate the leaching behavior of As and Se in two major types of coal fly ashes, bituminous coal ash and sub-bituminous coal ash, and to determine the underlying processes that control As and Se leaching. The effects of pH, solid/liquid (S/L) ratio, calcium addition, and leaching time on the release of As and Se were studied. Overall, bituminous coal ash leached significantly more As and Se than sub-bituminous coal ash, and Se was more readily leachable, in both absolute concentration and relative fraction, than As for both types of fly ashes. Adsorption/desorption played a major role on As and Se leaching from bituminous coal ashes. However, calcium precipitation played the most important role in reducing As and Se leaching from sub-bituminous coal ashes in the entire experimental pH range. The leaching of As and Se from bituminous coal ashes generally increased with increases in the S/L ratio and leaching time. However, for sub-bituminous coal ashes, the leaching of As was not detected under most experimental conditions, while the leaching of Se increased with increases in the S/L ratio and leaching time. As{sup V} and Se{sup IV} were found to be the major species in all ash leachates in this study. 46 refs., 7 figs., 1 tab.

Tian Wang; Jianmin Wang; Yulin Tang; Honglan Shi; Ken Ladwig [Missouri University of Science and Technology, Rolla, MO (United States). Department of Civil, Architectural, and Environmental Engineering, and Environmental Research Center (ERC)

2009-05-15T23:59:59.000Z

333

The reactions and ashes of thermonuclear explosions on neutron stars  

E-Print Network [OSTI]

This paper reports on the detailed rp-process reaction flow on an accreting neutron star and the resulting ashes of a type I X-ray burst. It is obtained by coupling a 298 isotope reaction network to a self-consistent one-dimensional model calculation with a constant accretion rate of dM/dt=1.0e17g/s (0.09 Eddington).

J. L. Fisker; E. Brown; M. Liebendoerfer; F. -K. Thielemann; M. Wiescher

2004-08-04T23:59:59.000Z

334

Effects of Sediment Containing Coal Ash from the Kingston Ash Release on Embryo-Larval Development in the Fathead Minnow, Pimephales promelas (Rafinesque, 1820)  

SciTech Connect (OSTI)

The largest environmental release of coal ash in U.S. history occurred in December 2008 with the failure of a retention structure at the Tennessee Valley Authority (TVA) Kingston Fossil Plant in East Tennessee. A byproduct of coal-burning power plants, coal ash is enriched in metals and metalloids such as selenium and arsenic with known toxicity to fish including embryonic and larval stages. The effects of contact exposure to sediments containing up to 78 % coal ash from the Kingston spill on the early development of fish embryos and larvae were examined in 7-day laboratory tests with the fathead minnow (Pimephales promelas). No significant effects were observed on hatching success, incidences of gross developmental abnormalities, or embryo-larval survival. Results suggest that direct exposures to sediment containing residual coal ash from the Kingston ash release may not present significant risks to fish eggs and larvae in waterways affected by the spill.

Greeley Jr, Mark Stephen [ORNL] [ORNL; Elmore, Logan R [ORNL] [ORNL; McCracken, Kitty [ORNL] [ORNL; Sherrard, Rick [Tennessee Valley Authority (TVA)] [Tennessee Valley Authority (TVA)

2014-01-01T23:59:59.000Z

335

Modelling fly ash generation for UK power station coals  

SciTech Connect (OSTI)

An in-depth characterization has been made of three UK bituminous coals and the combustion products from these coals when burned at a power station and on a range of experimental combustion facilities. The coals were chosen to represent the range of ash compositions and slagging propensities found at UK power stations. CCSEM analysis of the pulverized coals has been performed to provide quantitative data on the size and chemical composition of individual mineral occurrences, and to determine the nature of the mineral-mineral and mineral-organic associations in the pulverized fuel. In a similar way the size and chemical composition of individual fly ash particle has been determined. The mineral-mineral association information has been used to predict the effects of mineral coalescence, the dominant mineral transformation process for UK power station coals. The CCSEM information correctly identifies the types of mineral-mineral association and hence the predicted effects of coalescence. The limitations of the information are inherent in the analysis of a cross-section, but useful information for the modelling of ash generation may still be obtained.

Wigley, F.; Williamson, J. [Imperial Coll., London (United Kingdom). Dept. of Materials

1996-12-31T23:59:59.000Z

336

Oil shale ash-layer thickness and char combustion kinetics  

SciTech Connect (OSTI)

A Hot-Recycled-Solids (HRS) oil shale retort is being studied at Lawrence Livermore National Laboratory. In the HRS process, raw shale is heated by mixing it with burnt retorted shale. Retorted shale is oil shale which has been heated in an oxygen deficient atmosphere to pyrolyze organic carbon, as kerogen into oil, gas, and a nonvolatile carbon rich residue, char. In the HRS retort process, the char in the spent shale is subsequently exposed to an oxygen environment. Some of the char, starting on the outer surface of the shale particle, is burned, liberating heat. In the HRS retort, the endothermic pyrolysis step is supported by heat from the exothermic char combustion step. The rate of char combustion is controlled by three resistances; the resistance of oxygen mass transfer through the gas film surrounding the solid particle, resistance to mass transfer through a ash layer which forms on the outside of the solid particles as the char is oxidized and the resistance due to the intrinsic chemical reaction rate of char and oxygen. In order to estimate the rate of combustion of the char in a typical oil shale particle, each of these resistances must be accurately estimated. We begin by modeling the influence of ash layer thickness on the over all combustion rate of oil shale char. We then present our experimental measurements of the ash layer thickness of oil shale which has been processed in the HRS retort.

Aldis, D.F.; Singleton, M.F.; Watkins, B.E.; Thorsness, C.B.; Cena, R.J.

1992-04-15T23:59:59.000Z

337

Unique method of ash disposal can benefit marine life  

SciTech Connect (OSTI)

As more communities turn to waste-to-energy facilities to help solve their solid waste disposal problems, the amount of ash created by these facilities increases. Incineration of solid waste produces particulate residues which are often rich in lead, cadmium, copper, and zinc because of the concentration which occurs as a result of reduction. It has been shown that such metals can sometimes be leached from ash residues, giving rise to special concerns that incineration ashes be disposed of in an environmentally acceptable manner. In urban coastal areas where landfills are few and increasingly distant, ocean disposal of stabilized incineration residues (SIR) may provide an acceptable alternative to current landfill practices. In May 1985, a research program was initiated at the Marine Sciences Research Center to examine the feasibility of utilizing SIR for artificial reef construction in the ocean. Results of these studies showed that particulate incineration residues could be combined with cement to form a solid block possessing physical properties necessary for ocean disposal. The stabilized residues were subjected to regulatory extraction protocols, and in no instance did the metal concentrations in the leachates exceed the regulatory limits for toxicity. Bioassays revealed no adverse effects on the phytoplankton communities exposed to elutriate concentrations higher than could be encountered under normal disposal conditions. The success of the laboratory studies resulted in securing the necessary permits for the placement of an artificial habitat constructed using SIR in coastal wasters. Results from this program are described.

Roethel, F.J.; Breslin, V.T. (State Univ. of New York, Stony Brook (USA))

1988-10-01T23:59:59.000Z

338

Intense terahertz emission from molecular beam epitaxy-grown GaAs/GaSb(001)  

SciTech Connect (OSTI)

Intense terahertz (THz) electromagnetic wave emission was observed in undoped GaAs thin films deposited on (100) n-GaSb substrates via molecular beam epitaxy. GaAs/n-GaSb heterostructures were found to be viable THz sources having signal amplitude 75% that of bulk p-InAs. The GaAs films were grown by interruption method during the growth initiation and using various metamorphic buffer layers. Reciprocal space maps revealed that the GaAs epilayers are tensile relaxed. Defects at the i-GaAs/n-GaSb interface were confirmed by scanning electron microscope images. Band calculations were performed to infer the depletion region and electric field at the i-GaAs/n-GaSb and the air-GaAs interfaces. However, the resulting band calculations were found to be insufficient to explain the THz emission. The enhanced THz emission is currently attributed to a piezoelectric field induced by incoherent strain and defects.

Sadia, Cyril P.; Laganapan, Aleena Maria; Agatha Tumanguil, Mae; Estacio, Elmer; Somintac, Armando; Salvador, Arnel [National Institute of Physics, University of the Philippines Diliman, Quezon City 1101 (Philippines); Que, Christopher T. [Physics Department, De La Salle University, 2401 Taft Avenue, Manila 1004 (Philippines); Yamamoto, Kohji; Tani, Masahiko [Research Center for Development of Far-Infrared Region, University of Fukui, Fukui 910-8507 (Japan)

2012-12-15T23:59:59.000Z

339

The tin impurity in Bi0.5Sb1.5Te3 alloys  

Broader source: Energy.gov [DOE]

Extends work on tin to p-type thermoelectric alloys of formula Bi(2-x)Sb(x)Te(3) doped with Sn. Both single crystals and polycrystals prepared using powder metallurgical techniques are studied and properties reported.

340

Structural and Magnetic Properties of Co-Mn-Sb Thin films  

SciTech Connect (OSTI)

Thin Co-Mn-Sb films of different compositions were investigated and utilized as electrodes in alumina based magnetic tunnel junctions with CoFe counterelectrode. The preparation conditions were optimized with respect to magnetic and structural properties. The Co-Mn-Sb/Al-O interface was analyzed by x-ray absorption spectroscopy and magnetic circular dichroism with particular focus on the element-specific magnetic moments. Co-Mn-Sb crystallizes in different complex cubic structures depending on its composition. The magnetic moments of Co and Mn are ferromagnetically coupled in all cases. A tunnel magnetoresistance ratio of up to 24% at 13 K was found and indicates that Co-Mn-Sb is not a ferromagnetic half-metal. These results are compared to recent works on the structure and predictions of the electronic properties.

Meinert, M.; Schmalhorst, J.-M.; Ebke, D.; Liu, N. N.; Thomas, A.; Reiss, G.; Kanak, J.; Stobiecki, T.; Arenholz, E.

2009-12-17T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Structural transformation of Sb-based high-speed phase-change material  

Science Journals Connector (OSTI)

On heating, amorphous Ag3.1In3.7Sb76.4Te16.5 crystallizes at 416 K in an A7 structure type with atomic sites randomly occupied by the four constituent elements. At 545 K the compound decomposes into two crystalline phases: AgInTe2 is stable up to the melting point, while Sb89Te11 has a modulated layer structure with a temperature-dependent layer period.

Matsunaga, T.

2012-10-23T23:59:59.000Z

342

Theoretical study of defect formation during the initial stages of native-oxide growth on GaSb (001)  

SciTech Connect (OSTI)

The formation of defects during the initial stages of native-oxide growth on the GaSb (001)-?(4?×?3) surface has been studied computationally using spin-unrestricted density functional theory. It is found that insertion into a Ga-Sb adatom dimer to form a peroxo Ga-O-O-Sb bridge is the most energetically favorable process with insertion into Ga-Sb back-bonds being somewhat less so. A Ga-O-O-Ga bridge between dimers is also favorable, but Sb-O-O-Sb bridges show little if any stability. In the course of analyzing molecular adsorption, a particularly reactive site has been identified that leads to O{sub 2} dissociation with little or no barrier. This process is initiated in the vicinity of an Sb-Sb dimer in the terminating layer and leads to sub-surface Ga and Sb defect sites (i.e., coordinatively unsaturated atoms) and to strained Ga-Sb bonds that may be susceptible to further O{sub 2} attack. However, the defects formed in these reactions do not produce states in the gap.

Bermudez, V. M., E-mail: victor.bermudez@nrl.navy.mil [Electronics Science and Technology Division, U.S. Naval Research Laboratory, Washington, DC 20375 (United States)

2014-04-07T23:59:59.000Z

343

Superheater Tube Corrosion in Wood Gasifier Ash Deposits  

SciTech Connect (OSTI)

The upper operating temperature of tubes in heat exchangers/steam generators is strongly influenced by the degradation that can occur because of the reaction of the exchanger/generator tubing with the deposits that accumulate on the surface of the tubes. In fact, severe corrosion has been observed in some biomass fired systems, particularly with elevated potassium and chlorine concentrations in the deposits. Wood gasifiers have recently been and are currently being constructed at several sites in North America. In these systems, the syngas is burned to produce steam and the performance of the heat exchanger tubes under ash deposits is of great concern. As temperatures of the heat exchangers are increased in an effort to increase their operating efficiency, the performance of the tubes is of greater interest. The corrosion behavior of alloy steel tubes as a function of temperature has been investigated by exposing samples of selected alloys to ash collected from the steam generator fired by syngas produced in wood gasifiers. This study compares corrosion rates from laboratory exposures of synthesis gas and ash at 500 C and 600 C. This study investigated the material performance of four ferritic steels and one austenitic steel exposed to conditions expected on the fireside of a wood gasifier. The purpose of this study was to identify an effective method for determining material performance for samples exposed to both the process gas and the fly ash that is typically observed within the steam generator for times up to 1000 hours. Mass changes were measured for all of the samples, but this information can be misleading concerning material performance due to the difficulty in sufficiently cleaning the samples after exposure in the ash. Therefore, small cross sections of the samples were collected and imaged using optical microscopy. Oxide thicknesses were measured along with metal losses. The metal loss information provides a clear indication of material performance. The metal loss rates for the ferritic steels at 500 C were almost half of those observed at 600 C and the rates decreased with increasing exposure time. It was also reported that the metal loss rates generally decrease with increasing chromium concentration.

Bestor, Michael A [ORNL] [ORNL; Keiser, James R [ORNL] [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)] [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

2011-01-01T23:59:59.000Z

344

THE IMPACT OF A TANK 40H DECANT ON THE PROJECTED OPERATING WINDOWS FOR SB4 AND GLASS SELECTION STRATEGY IN SUPPORT OF THE VARIABILITY STUDY  

SciTech Connect (OSTI)

The Liquid Waste Organization (LWO) has requested that the Savannah River National Laboratory (SRNL) to assess the impact of a 100K gallon decant volume from Tank 40H on the existing sludge-only Sludge Batch 4 (SB4)-Frit 510 flowsheet and the coupled operations flowsheet (SB4 with the Actinide Removal Process (ARP)). Another potential SB4 flowsheet modification of interest includes the addition of 3 wt% sodium (on a calcined oxide basis) to a decanted sludge-only or coupled operations flowsheet. These potential SB4 flowsheet modifications could result in significant compositional shifts to the SB4 system. This paper study provides an assessment of the impact of these compositional changes to the projected glass operating windows and to the variability study for the Frit 510-SB4 system. The influence of the compositional changes on melt rate was not assessed in this study nor was it requested. Nominal Stage paper study assessments were completed using the projected compositions for the various flowsheet options coupled with Frit 510 (i.e., variation was not applied to the sludge and frit compositions). In order to gain insight into the impacts of sludge variation and/or frit variation (due to the procurement specifications) on the projected operating windows, three versions of the Variation Stage assessment were performed: (1) the traditional Variation Stage assessment in which the nominal Frit 510 composition was coupled with the extreme vertices (EVs) of each sludge, (2) an assessment of the impact of possible frit variation (within the accepted frit specification tolerances) on each nominal SB4 option, and (3) an assessment of the impact of possible variation in the Frit 510 composition due to the vendor's acceptance specifications coupled with the EVs of each sludge case. The results of the Nominal Stage assessment indicate very little difference among the various flowsheet options. All of the flowsheets provide DWPF with the possibility of targeting waste loadings (WLs) from the low 30s to the low 40s with Frit 510. In general, the Tank 40H decant has a slight negative impact on the operating window, but DWPF still has the ability to target current WLs (34%) and higher WLs if needed. While the decant does not affect practical WL targets in DWPF, melt rate could be reduced due to the lower Na{sub 2}O content. If true, the addition of 3 wt% Na{sub 2}O to the glass system may regain melt rate, assuming that the source of alkali is independent of the impact on melt rate. Coupled operations with Frit 510 via the addition of ARP to the decanted SB4 flowsheet also appears to be viable based on the projected operating windows. The addition of both ARP and 3 wt% Na{sub 2}O to a decanted Tank 40H sludge may be problematic using Frit 510. Although the Nominal Stage assessments provide reasonable operating windows for the SB4 flowsheets being considered with Frit 510, introduction of potential sludge and/or frit compositional variation does have a negative impact. The magnitude of the impact on the projected operating windows is dependent on the specific flowsheet options as well as the applied variation. The results of the traditional Variation Stage assessments indicate that the three proposed Tank 40H decanted flowsheet options (Case No.2--100K gallon decant, Case No.3--100K gallon decant and 3 wt% Na{sub 2}O addition and Case No.4--100K gallon decant and ARP) demonstrate a relatively high degree of robustness to possible sludge variation over WLs of interest with Frit 510. However, the case where the addition of both ARP and 3 wt% Na{sub 2}O is considered was problematic during the traditional Variation Stage assessment. The impact of coupling the frit specifications with the nominal SB4 flowsheet options on the projected operating windows is highly dependent on whether the upper WLs are low viscosity or liquidus temperature limited in the Nominal Stage assessments. Systems that are liquidus temperature limited exhibit a high degree of robustness to the applied frit and sludge variation, while those that are low viscosity li

Raszewski, F; Tommy Edwards, T; David Peeler, D

2008-02-07T23:59:59.000Z

345

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin |  

Broader source: Energy.gov (indexed) [DOE]

Accomplish Cleanup of Second Cold War Coal Ash Accomplish Cleanup of Second Cold War Coal Ash Basin Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin American Recovery and Reinvestment Act workers recently cleaned up a second basin containing coal ash residues from Cold War operations at the Savannah River Site (SRS). About $24 million from the Recovery Act funded the environmental restoration project, allowing SRS to complete the project at least five years ahead of schedule. The work is part of a larger Recovery Act cleanup of the P Area scheduled for completion by the end of September 2011. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin More Documents & Publications Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin Recovery Act Workers Add Time Capsule Before Sealing Reactor for Hundreds

346

Integrated production/use of ultra low-ash coal, premium liquids and clean char  

SciTech Connect (OSTI)

This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

Kruse, C.W.

1991-01-01T23:59:59.000Z

347

Mineralogical characterization of Sasol feed coals and corresponding gasification ash constituents  

SciTech Connect (OSTI)

Feed coal and coarse ash particles (heated rock fragments and clinkers), produced from Sasol-Lurgi gasifier tests under different operating conditions, have been characterized by quantitative X-ray diffraction, electron microprobe analysis, and associated chemical techniques, as a basis for better understanding of the relations between the mineralogical and physical properties of the ash particles. Crystalline phases in the ashes include quartz particles inherited directly from the feed coal, as well as anorthite, mullite, and diopside, derived from solid-state reactions or crystallization of a silicate melt during the gasification process. Glass, cooled from the melt, is also abundant in the ash materials. The abundance of large particles of hard minerals in the coal or the ash, such as quartz, anorthite, pyrite, and diopside, has been correlated with a laboratory-determined abrasion index and may contribute significantly to wear on mechanical equipment during coal- or ash-handling operations. 21 refs., 3 figs., 9 tabs.

Aivo B. Hlatshwayo; Ratale H. Matjie; Zhongsheng Li; Colin R. Ward [Sasol Technology (Proprietary) Limited, Sasolburg (South Africa)

2009-05-15T23:59:59.000Z

348

An Empirical Method for the Prediction of Coal Ash Slag Viscosity  

Science Journals Connector (OSTI)

An Empirical Method for the Prediction of Coal Ash Slag Viscosity ... Samples were prepared by ashing coals to completion at 815 °C; then a slag was generated under nitrogen at >1650 °C with the appropriate amount of reagent grade calcium carbonate (CaCO3) as flux added. ... (5)?Watt, J. D.; Fereday, F. The Flow Properties of Slags Formed from the Ashes of British Coals:? Part 1. Viscosity of Homogeneous Liquid Slags in Relation to Slag Composition. ...

G. J. Browning; G. W. Bryant; H. J. Hurst; J. A. Lucas; T. F. Wall

2003-04-16T23:59:59.000Z

349

A review of ash in conventional and advanced coal-based power systems  

SciTech Connect (OSTI)

Process conditions are briefly described for conventional and advanced power systems. The advanced systems include both combustion and gasification processes. We discuss problems in coal-based power generation systems, including deposition, agglomeration and sintering of bed materials, and ash attack are discussed. We also discuss methods of mitigating ash problems and anticipated changes anticipated in ash use by converting from conventional to advanced systems.

Holcombe, N.T.

1995-12-31T23:59:59.000Z

350

E-Print Network 3.0 - ash upptag av Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Processing Conference Proceedings ASME 1994 MONTGOMERY COUNTY Summary: for cooling the condensate and auxiliary cooling water. Incombustible material and ash residue from the...

351

MARKET ASSESSMENT AND TECHNICAL FEASIBILITY STUDY OF PRESSURIZED FLUIDIZED BED COMBUSTION ASH USE  

SciTech Connect (OSTI)

Western Research Institute, in conjunction with the Electric Power Research Institute, Foster Wheeler International, Inc. and the US Department of Energy, has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for PFBC ashes. Ashes from the Foster Wheeler Energia Oy pilot-scale circulating PFBC tests in Karhula, Finland, combusting (1) low-sulfur subbituminous and (2) high-sulfur bituminous coal, and ash from the AEP's high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at WR1. The technical feasibility study examined the use of PFBC ash in construction-related applications, including its use as a cementing material in concrete and use in cement manufacturing, fill and embankment materials, soil stabilization agent, and use in synthetic aggregate production. Testing was also conducted to determine the technical feasibility of PFBC ash as a soil amendment for acidic and sodic problem soils and spoils encountered in agricultural and reclamation applications. The results of the technical feasibility testing indicated the following conclusions. PFBC ash does not meet the chemical requirements as a pozzolan for cement replacement. However, it does appear that potential may exist for its use in cement production as a pozzolan and/or as a set retardant. PFBC ash shows relatively high strength development, low expansion, and low permeability properties that make its use in fills and embankments promising. Testing has also indicated that PFBC ash, when mixed with low amounts of lime, develops high strengths, suitable for soil stabilization applications and synthetic aggregate production. Synthetic aggregate produced from PFBC ash is capable of meeting ASTM/AASHTO specifications for many construction applications. The residual calcium carbonate and calcium sulfate in the PFE3C ash has been shown to be of value in making PFBC ash a suitable soil amendment for acidic and sodic problem soils and mine spoils. In conclusion, PFBC ash represents a viable material for use in currently established applications for conventional coal combustion ashes. As such, PFBC ash should be viewed as a valuable resource, and commercial opportunities for these materials should be explored for planned PFBC installations.

A.E. Bland; T.H. Brown

1997-04-01T23:59:59.000Z

352

E-Print Network 3.0 - agglomerating ash process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 8 Assembly and Testing of an On-Farm Manure to Energy Conversion BMP for Animal Waste Pollution Control Summary: index for animal manure ash...

353

Ash chemistry and mineralogy of an Indonesian coal during combustion: Part 1 Drop-tube observations  

Science Journals Connector (OSTI)

The paper reports a systematic and comprehensive laboratory investigation into the ash chemistry and mineralogical changes undergone by a low-rank Indonesian coal during combustion. Combustion experiments conducted in a drop-tube furnace included ash formation experiments (using cyclone and filter arrangement) under closely controlled conditions in the range of 1200–1400 °C and deposition experiments at a probe temperature of 750 °C. Tests conducted with raw coal, coal/additive mixtures and washed coal indicated significant changes in ash characteristics. Of the ash formation and deposit samples examined, the raw coal + bauxite showed the lowest glass content and high contents of corundum indicating low ash deposition propensities. When compared to the ash formation samples, the deposit samples showed even significantly lower glass contents and were enriched in quartz. With the exception of the raw coal + bauxite sample, all are characterized by high silica and iron and moderate aluminium contents. In contrast, the raw coal + bauxite sample have low silica and much higher alumina contents which is in agreement with XRD observations. QEMSCAN™ results showed that the ash particles are sparsely distributed suggesting lack of a deposit initiation layer. Experimental observations suggest that the use of raw coal with bauxite would appear to offer the best performance with respect to handling ash-related issues. Present findings are of practical significance to power utilities employing Indonesian coal as there is no comprehensive work reported in the literature on ash chemistry and mineralogy of such coals.

H.B. Vuthaluru; D. French

2008-01-01T23:59:59.000Z

354

E-Print Network 3.0 - ash forming acid-resistant Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

European Summer Fly Ash Workshop," Warsaw, Poland, June 2005. Department... combustion of coal in conventional and advanced clean-coal technology combustors. These include fly...

355

E-Print Network 3.0 - ash financial aspects Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete, Bangkok, Thailand Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

356

E-Print Network 3.0 - ash separators Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete, Bangkok, Thailand Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

357

E-Print Network 3.0 - ash flowable fill Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: ash as filler. A highly flowable concrete is not necessarily self-compacting because SCC should... ;4. Kurita, M., and Nomura, T., "High-Flowable Steel...

358

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus...  

Open Energy Info (EERE)

Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search OpenEI Reference...

359

INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS  

SciTech Connect (OSTI)

This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

2000-11-01T23:59:59.000Z

360

Prediction of Chinese coal ash fusion temperatures in Ar and H{sub 2} atmospheres  

SciTech Connect (OSTI)

The ash fusion temperatures (AFTs) of 21 typical Chinese coal ash samples and 60 synthetic ash samples were measured in Ar and H{sub 2} atmospheres. The computer software package FactSage was used to calculate the temperatures corresponding to different proportions of the liquid phase and predict the phase equilibria of synthetic ash samples. Empirical liquidus models were derived to correlate the AFTs under both Ar and H{sub 2} atmospheres of 60 synthetic ash samples, with their liquidus temperatures calculated by FactSage. These models were used to predict the AFTs of 21 Chinese coal ash samples in Ar and H{sub 2} atmospheres, and then the AFT differences between the atmospheres were analyzed. The results show that, for both atmospheres, there was an apparently linear correlation and good agreement between the AFTs of synthetic ash samples and the liquidus temperatures calculated by FactSage (R > 0.89, and {sigma} < 30{sup o}C). These models predict the AFTs of coal ash samples with a high level of accuracy (SE < 30{sup o}C). Because the iron oxides in coal ash samples fused under a H{sub 2} atmosphere are reduced to metallic iron and lead to changes of mineral species and micromorphology, the AFTs in a H{sub 2} atmosphere are always higher than those with an Ar atmosphere. 34 refs., 9 figs., 7 tabs.

Wen J. Song; Li H. Tang; Xue D. Zhu; Yong Q. Wu; Zi B. Zhu; Shuntarou Koyama [East China University of Science and Technology, Shanghai (China)

2009-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Characterization and modeling of toxic fly ash constituents in the environment.  

E-Print Network [OSTI]

??Coal fly ash is a by-product of coal combustion that has drawn renewed public scrutiny due to the negative environmental impacts from accidental release of… (more)

Zhu, Zhenwei

2011-01-01T23:59:59.000Z

362

Coal deposit characterization by gamma-gamma density/percent dry ash relationships  

E-Print Network [OSTI]

: pb = C + Va(pa) Equation 3 where C is a constant. Ash content can therefore be geophysically determined as variations In log-derived bulk density measurements are in direct response to variations in ash content. However, when any of the above... by applying the relationships between geophysi cally-derived gamma-gamma density and laboratory-derived percent dry ash. The linear gamma-gamma density/percent dry ash relationship is dependent upon a constant fuel ratio (percent fixed carbon...

Wright, David Scott

1984-01-01T23:59:59.000Z

363

E-Print Network 3.0 - ash corrosion resistant Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 48 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: in improved resistance to...

364

E-Print Network 3.0 - ash cement matrixes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 13 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: to a construc- tion material...

365

E-Print Network 3.0 - ash confinement time Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 36 ccsd-00002019,version1-18Oct2004 Stabilization of Burn Conditions in an ITER FEAT Summary: with Uncertainties in the Helium Ash Confinement...

366

E-Print Network 3.0 - ash quality recycling Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... CANMET Conference on Quality of Concrete Structures and...

367

E-Print Network 3.0 - ash fraxinus excelsior Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

we planted green ash trees... Identification of a Biomarker Gene for Fraxinus spp. Darla French and ... Source: Purdue University, Department of Forestry and Natural Resources,...

368

E-Print Network 3.0 - ash related problems Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the environment is an environmental problem created. It is generally conceded... . The dioxinsfurans on ash then don't seem to create an ... Source: Columbia University -...

369

E-Print Network 3.0 - ash inhalation exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in England and Summary: tests on blocks containing mixed ash. 1 See page 17, Dioxins, what they are, their sources, our exposure... into the potential exposure to dioxins...

370

E-Print Network 3.0 - ash impact sorbent Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for By-Products Utilization Collection: Engineering ; Materials Science 23 Leaching of Dioxins from Municipal Waste Combustor Residues Summary: , and baghouses) including fly ash,...

371

E-Print Network 3.0 - ash management regulations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Air and Waste Management Division U.S. Environmental... unacceptable levels of dioxins and furans. Thus they argue for cradle to grave ash management under Subtitle C......

372

A Method for Making In Situ Emittance Measurements of Coal Ash Deposits.  

E-Print Network [OSTI]

??A major problem associated with any power generation process in which coal is burned is the formation of ash and slag from the inorganic constituents… (more)

Moore, Travis J.

2009-01-01T23:59:59.000Z

373

Extracting Coal Ash Content from Laser-Induced Breakdown Spectroscopy (LIBS) Spectra by Multivariate Analysis  

Science Journals Connector (OSTI)

Laser-induced breakdown spectroscopy (LIBS) combined with partial least squares (PLS) analysis has been applied for the quantitative analysis of the ash content of coal in this...

Yao, Shunchun; Lu, Jidong; Dong, Meirong; Chen, Kai; Li, Junyan; Li, Jun

2011-01-01T23:59:59.000Z

374

E-Print Network 3.0 - altered volcanic ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: when hot ash flows enter the sea. Volcanic activity was practically absent on Gran Canaria between 9... expected the Slump scarp Subaerial volcanics Sealevel Distal...

375

JOURNAL DE PHYSIQUE CoZZoque C8, supplgment au n08, Tome 42, aoGt 2980, page C8-519 ELECTRICAL RESISTIVITY AND THERMOELECTRIC POWER OF LIQUID Ge-Sb AND Pb-Sb ALLOYS  

E-Print Network [OSTI]

Fig. 1. v Electrical resistivity of liquid Pbl-x~bx alloys as a function of temperature. the liquid were quoted as dt%Sb Fig. 2. - Electrical resistivity of liquid Pb-Sb alloys at 660°C and Ge-Sb alloysJOURNAL DE PHYSIQUE CoZZoque C8, supplgment au n08, Tome 42, aoGt 2980, page C8-519 ELECTRICAL

Boyer, Edmond

376

Beta-Decay Matrix Elements in Sb122  

Science Journals Connector (OSTI)

An electronic computer has been used to investigate the six nuclear matrix elements which enter into the 2- to 2+ 1.40-MeV beta transition in the decay of Sb122. Data from beta-gamma angular correlation, beta-circularly polarized gamma angular correlation, nuclear orientation, and nuclear resonance experiments were used in this analysis. As a further aid, the Feenberg-Ahrens relations between certain of the nuclear matrix elements were employed to catalog the solutions and to simplify the search problem. In order to discover how the remaining ambiguity of these solutions could most easily be reduced, for each of the solutions calculations were made of the predicted results of all possible experiments on this beta transition. These calculations show how sufficient experimental data can be obtained to determine unambiguously all six nuclear matrix elements. In an appendix all the theoretical formulas which give the experimental observables for a first forbidden 2- to 2+ beta transition in terms of the nuclear matrix elements are summarized.

F. M. Pipkin; J. Sanderson; W. Weyhmann

1963-03-15T23:59:59.000Z

377

Oxidation resistant coatings for CoSb3  

Science Journals Connector (OSTI)

Doped cobalt antimonides are used as components of thermoelectric devices at temperatures not exceeding 450 °C because of poor thermal and chemical stability. In absence of oxygen they degrade by sublimation of antimony while in air they easily oxidize to form volatile antimony oxides and non-volatile thick double oxide scales [1]. In both cases protective coatings are indispensable to ensure safe performance of thermoelectric devices over extended times. The most promising solution reported so far is a thick aerogel coating which practically stops antimony loss by sublimation. The assessment of coating effectiveness is generally based on thermogravimetric tests in vacuum so permeability of oxygen and protection from oxidation cannot be evaluated. The paper presents investigations on the development of protective coatings which would prevent oxidation of CoSb3. Two types of coatings were applied: magnetron sputtered Cr-Si thin layers [2] and thick enamel layers. Testing involved interrupted oxidation in air for 20-80 h at 500 °C and 600 °C. The Cr-Si thin layers appeared oxygen-tight at 500 °C while the enamel layers - even at 600 °C.

2012-01-01T23:59:59.000Z

378

PRELIMINARY FRIT DEVELOPMENT AND MELT RATE TESTING FOR SLUDGE BATCH 6 (SB6)  

SciTech Connect (OSTI)

The Liquid Waste Organization (LWO) provided the Savannah River National Laboratory (SRNL) with a Sludge Batch 6 (SB6) composition projection in March 2009. Based on this projection, frit development efforts were undertaken to gain insight into compositional effects on the predicted and measured properties of the glass waste form and to gain insight into frit components that may lead to improved melt rate for SB6-like compositions. A series of Sludge Batch 6 (SB6) based glasses was selected, fabricated and characterized in this study to better understand the ability of frit compositions to accommodate uncertainty in the projected SB6 composition. Acceptable glasses (compositions where the Product Composition Control System (PCCS) Measurement Acceptability Region (MAR) predicted acceptable properties, good chemical durability was measured, and no detrimental nepheline crystallization was observed) can be made using Frit 418 with SB6 over a range of Na{sub 2}O and Al{sub 2}O{sub 3} concentrations. However, the ability to accommodate variation in the sludge composition limits the ability to utilize alternative frits for potential improvements in melt rate. Frit 535, which may offer improvements in melt rate due to its increased B2O3 concentration, produced acceptable glasses with the baseline SB6 composition at waste loadings of 34 and 42%. However, the PCCS MAR results showed that it is not as robust as Frit 418 in accommodating variation in the sludge composition. Preliminary melt rate testing was completed in the Melt Rate Furnace (MRF) with four candidate frits for SB6. These four frits were selected to evaluate the impacts of B{sub 2}O{sub 3} and Na{sub 2}O concentrations in the frit relative to those of Frit 418, although they are not necessarily candidates for SB6 vitrification. Higher concentrations of B{sub 2}O{sub 3} in the frit relative to that of Frit 418 appeared to improve melt rate. However, when a higher concentration of B{sub 2}O{sub 3} was coupled with a lower concentration of Na{sub 2}O relative to Frit 418, melt rate did not appear to improve. It is expected that a SB6 composition projection with less uncertainty will be received during analysis of the Tank 51 E-1 sample, which will be pulled after the completion of aluminum dissolution in August 2009. At that time, additional frit development work will be performed to seek improved melt rates while maintaining viable projected operating windows. This later work will ultimately lead to a frit recommendation for SB6.

Fox, K.; Miller, D.; Edwards, T.

2009-07-21T23:59:59.000Z

379

Reaction of Sodium Borohydride with Wool  

Science Journals Connector (OSTI)

... It has recently been found that sodium borohydride in alkaline solution rapidly dissolves wool under conditions of temperature and pH milder than many in current use. The reaction ... in current use. The reaction has been studied as follows: 1 gm. of solvent-scoured Merino ...

J. M. GILLESPIE

1959-01-31T23:59:59.000Z

380

In sodium tests of ultrasonic transducers  

SciTech Connect (OSTI)

Ultrasonic techniques are seen as suitable candidates for the in-service inspection and for the continuous surveillance of sodium cooled reactors (SFR). These techniques need the development and the qualification of immersed ultrasonic transducers, and materials. This paper presents some developments performed by CEA (DTN and LIST) and AREVA (NDE Solutions), and some results. (authors)

Lhuillier, C.; Descombin, O.; Baque, F. [CEA, DTN, 13108 Saint Paul lez Durance Cedex (France); Marchand, B. [CEA, LIST, 91191 Gif-sur-Yvette (France); Saillant, J. F. [AREVA/NDE Solutions, 4 rue Thomas Dumorey, 71109 Chalon sur Saone Cedex (France); Augem, J. M. [EDF, 12-14 avenue Dutrievoz, 69628 Villeurbanne (France)

2011-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Inhibition Of Washed Sludge With Sodium Nitrite  

SciTech Connect (OSTI)

This report describes the results of electrochemical tests used to determine the relationship between the concentration of the aggressive anions in washed sludge and the minimum effective inhibitor concentration. Sodium nitrate was added as the inhibitor because of its compatibility with the DWPF process. A minimum of 0.05M nitrite is required to inhibit the washed sludge simulant solution used in this study. When the worst case compositions and safety margins are considered, it is expected that a minimum operating limit of nearly 0.1M nitrite will be specified. The validity of this limit is dependent on the accuracy of the concentrations and solubility splits previously reported. Sodium nitrite additions to obtain 0.1M nitrite concentrations in washed sludge will necessitate the additional washing of washed precipitate in order to decrease its sodium nitrite inhibitor requirements sufficiently to remain below the sodium limits in the feed to the DWPF. Nitrite will be the controlling anion in "fresh" washed sludge unless the soluble chloride concentration is about ten times higher than predicted by the solubility splits. Inhibition of "aged" washed sludge will not be a problem unless significant chloride dissolution occurs during storage. It will be very important tomonitor the composition of washed sludge during processing and storage.

Congdon, J. W.; Lozier, J. S.

2012-09-25T23:59:59.000Z

382

Density functional simulations of phase change materials: disordered phases of Ge8Sb2Te11 and Ag/In/Sb/Te alloys  

E-Print Network [OSTI]

E*PCOS2009 Density functional simulations of phase change materials: disordered phases of Ge8Sb2Te75.0Te17.7 (AIST). These represent two families used widely as phase change materials: pseudobinary and more flexible than those of Ag. Key words: Phase change materials, density functional calculations

383

Recent progress in GaInAsSb thermophotovoltaics grown by organometallic vapor phase epitaxy  

SciTech Connect (OSTI)

Studies on the materials development of Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} alloys for thermophotovoltaic (TPV) devices are reviewed. Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} epilayers were grown lattice matched to GaSb substrates by organometallic vapor phase epitaxy (OMVPE) using all organometallic precursors including triethylgallium, trimethylindium, tertiarybutylarsine, and trimethylantimony with diethyltellurium and dimethylzinc as the n- and p-type dopants, respectively. The overall material quality of these alloys depends on growth temperature, In content, V/III ratio, substrate misorientation, and to a lesser extent, growth rate. A mirror-like surface morphology and room temperature photoluminescence (PL) are obtained for GaInAsSb layers with peak emission in the wavelength range between 2 and 2.5 {micro}m. The crystal quality improves for growth temperature decreasing from 575 to 525 C, and with decreasing In content, as based on epilayer surface morphology and low temperature PL spectra. A trend of smaller full width at half-maximum for low temperature PL spectra is observed as the growth rate is increased from 1.5 to 2.5 and 5 {micro}m/h. In general, GaInAsSb layers grown on (100) GaSb substrates with a 6{degree} toward (111)B misorientation exhibited overall better material quality than layers grown on the more standard substrate (100)2{degree} toward (110). Consistent growth of high performance lattice-matched GaInAsSb TPV devices is also demonstrated.

Wang, C.A.; Choi, H.K.; Oakley, D.C. [Massachusetts Inst. of Tech., Lexington, MA (United States). Lincoln Lab.; Charache, G.W. [Lockheed Martin, Inc., Schenectady, NY (United States)

1998-06-01T23:59:59.000Z

384

OMVPE growth and characterization of GaInAsSb for thermophotovoltaics  

SciTech Connect (OSTI)

Studies on the materials development of Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} alloys for thermophotovoltaic (TPV) devices are reviewed. Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} epilayers were grown lattice matched to GaSb substrates by organometallic vapor phase epitaxy (OMVPE) using all organometallic precursors including triethylgallium, trimethylindium, tertiarybutylarsine, and trimethylantimony with diethyltellurium and dimethylzinc as the n- and p-type dopants, respectively. The overall material quality of these alloys depends on growth temperature, In content, V/III ratio, substrate misorientation, and to a lesser extent, growth rate. A mirror-like surface morphology and room temperature photoluminescence (PL) are obtained for GaInAsSb layers with peak emission in the wavelength range between 2 and 2.5 {micro}m. The crystal quality improves for growth temperature decreasing from 575 to 525 C, and with decreasing In content, as based on epilayer surface morphology and low temperature PL spectra. A trend of smaller full width at half-maximum for low temperature PL spectra is observed as the growth rate is increased from 1.5 to 2.5 and 5 {micro}m/h. In general, GaInAsSb layers grown on (100) GaSb substrates with a 6{degree} toward (111)B misorientation exhibited overall better material quality than layers grown on the more standard substrate (100) 2{degree} toward (110). Consistent growth of high performance lattice-matched GaInAsSb TPV devices is also demonstrated.

Wang, C.A.; Charache, G.W.

1998-06-01T23:59:59.000Z

385

Atomic structure of amorphous and crystallized Ge{sub 15}Sb{sub 85}  

SciTech Connect (OSTI)

Ge{sub 15}Sb{sub 85} is a promising material for phase-change memory applications owing to its very short crystallization times. As deposited amorphous samples of sputter deposited Ge{sub 15}Sb{sub 85} have been investigated by extended x-ray absorption fine structure (EXAFS) measurements on both, Sb and Ge K absorption edges. After crystallizing the specimen, x-ray diffraction (XRD) and EXAFS measurements have been performed to analyze the atomic structure at different annealing conditions. Thus, experimental techniques focusing on the long range order as well as on the local order have been combined. Sb atoms have on average 3.2(2) nearest neighbors, while Ge atoms have 4.0(3). The Ge-Ge and Ge-Sb bond lengths are determined to 2.46(2) and 2.66(1) A, respectively and agree well with those observed in the amorphous phase of the common phase-change material Ge{sub 2}Sb{sub 2}Te{sub 5}. After crystallizing the sample at 250 deg. C, very different EXAFS spectra with modified Ge-Sb bond lengths are observed. The higher concentration of Ge neighbors at the Ge edge as compared to the as-deposited sample is indicative for phase separation. For the corresponding sample, XRD does not show reflections of Ge, which indicates that the agglomeration of Ge is amorphous or below the coherence length of the x-radiation. The EXAFS spectrum shows a superposition of two phases: one with bond lengths which agree with sp{sup 3}-hybridized Ge [2.43(1) A] and another one with longer Ge-Ge bond lengths [2.79(8) A]. This result can be explained by phase separation in the material.

Zalden, Peter; Eijk, Julia van; Wuttig, Matthias [I. Physikalisches Institut (IA), RWTH Aachen, 52056 Aachen (Germany); Bichara, Christophe [CiNaM-Centre Interdisciplinaire de Nanoscience de Marseille, Campus de Luminy, 13288 Marseille (France); Braun, Carolin; Bensch, Wolfgang [Institut fuer Anorganische Chemie, Universitaet Kiel, Max-Eyth Str. 2, 24118 Kiel (Germany)

2010-05-15T23:59:59.000Z

386

Gypsum and Polyacrylamide Soil Amendments Used With High Sodium Wastewater  

E-Print Network [OSTI]

Using wastewater for irrigation of crops represents an attractive alternative to disposal. Typically, municipal wastewaters are high in sodium, and the resulting high sodium absorption ratio (SAR) alters the soil structure making it more impermeable...

Gardiner, Duane

387

Growth and elemental accumulation by canola on soil amended with coal fly ash  

SciTech Connect (OSTI)

To explore the agronomic potential of an Australian coal fly ash, we conducted two glasshouse experiments in which we measured chlorophyll fluorescence, CO{sub 2} assimilation (A), transpiration, stomatal conductance, biomass accumulation, seed yield, and elemental uptake for canola (Brassica napus) grown on soil amended with an alkaline fly ash. In Experiment 1, application of up to 25 Mg/ha of fly ash increased A and plant weight early in the season before flowering and seed yield by up to 21%. However, at larger rates of ash application A, plant growth, chlorophyll concentration, and yield were all reduced. Increases in early vigor and seed yield were associated with enhanced uptake of phosphorus (P) by the plants treated with fly ash. Fly ash application did not influence accumulation of B, Cu, Mo, or Zn in the stems at any stage of plant growth or in the seed at harvest, except Mo concentration, which was elevated in the seed. Accumulation of these elements was mostly in the leaves, where concentrations of Cu and Mo increased with any amount of ash applied while that of B occurred only with ash applied at 625 Mg/ha. In Experiment 2, fly ash applied at 500 Mg/ha and mixed into the whole 30 cm soil core was detrimental to growth and yield of canola, compared with restricting mixing to 5 or 15 cm depth. In contrast, application of ash at 250 Mg/ha with increasing depth of mixing increased A and seed yield. We concluded that fly ash applied at not more than 25 Mg/ha and mixed into the top 10 to 15 cm of soil is sufficient to obtain yield benefits.

Yunusa, I.A.M.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Murray, B.R.; Nissanka, S.P. [University of Technology Sydney, Sydney, NSW (Australia)

2008-05-15T23:59:59.000Z

388

Speciation of Selenium, Arsenic, and Zinc in Class C Fly Ash  

SciTech Connect (OSTI)

A major environmental concern associated with coal fly ash is the mobilization of trace elements that may contaminate water. To better evaluate proper use of fly ash, determine appropriate disposal methods, and monitor postdisposal conditions, it is important to understand the speciation of trace elements in fly ash and their possible environmental impact. The speciation of selenium, arsenic, and zinc was determined in five representative Class C fly ash samples from combustion of sub-bituminous Powder River Basin coal using synchrotron-based X-ray absorption spectroscopy to provide an improved understanding of the mechanisms of trace element association with the fly ash. Selenium in all fly ash samples occurs predominantly as Se(IV), with the exception of one sample, in which there was a minor amount of Se(0). Se(0) is likely associated with the high content of unburned coal in the sample. Arsenic exists in the fly ash as a single phase most consistent with calcium pyroarsenate. In contrast, zinc occurs as two distinct species in the silicate glass matrix of the fly ash. This work demonstrates that residual carbon in fly ash may reduce potential Se mobility in the environment by retaining it as less soluble elemental Se instead of Se(IV). Further, this work suggests that As and Zn in Class C fly ash will display substantially different release and mobilization behaviors in aquatic environments. While As release will primarily depend upon the dissolution and hydrolysis of calcium pyroarsenate, Zn release will be controlled by the dissolution of alkaline aluminosilicate glass in the ash.

Luo, Yun; Giammar, Daniel E.; Huhmann, Brittany L.; Catalano, Jeffrey G. (WU)

2011-11-17T23:59:59.000Z

389

Sintering and fouling characterization of ashes with high calcium oxide content  

SciTech Connect (OSTI)

This research work has taken into consideration the behavior of Estonian oil shale ash with high calcium oxide content under typical FB conditions while focusing the main attention on bed agglomeration and fireside deposits. The different types of ashes tested included: (1) ash collected from the cyclone of a PF oil shale boiler, (2) ash collected from the electrostatic precipitator of the same boiler, and (3) oil shale ash prepared by standard laboratory procedures. The ashes were tested for their compression strength, a sintering test under laboratory conditions. First, cylindrical pellets were made from the ash samples. Then the pellets were exposed for four hours to various atmospheres, and various temperatures in the range 300--1,050 C, in a tube furnace. After the exposure, the pellets were tested for compression strength, and the pellet crushing stress was taken as an indicator for the degree of sintering. The compression tests were complemented with chemical analyses of heat treated ash pellets. Changes of mass and dimensions of the heat treated pellets were also recorded. Some experiments were also made to simulate the impact energy of different ash particles, to investigate the buildup of ash deposits on the heat transfer surfaces of boilers. The tests showed that significant sintering occurred under most of the conditions tested. The sintering of the oil shale ash was found to be dependent on both heat treatment temperature and gas atmosphere. Higher pressure at pellet making resulted in some cases in increased sintering. Based on these results, it was concluded that bed sintering would probably not be a problem in a FBC, but fouling of the heat transfer surfaces after the fluidized bed combustor could be a potential problem, in particular, at flue gas temperatures in the range 600 to 900 C.

Ots, A.; Parve, T. [Tallinn Technical Univ. (Estonia); Skrifvars, B.J.; Hupa, M. [Abo Akademi, Turku (Finland)

1995-12-31T23:59:59.000Z

390

Controlled Experiments on the Effects of Lubricant/Additive (Low-Ash, Ashless) Characteristics on DPF Degradation  

Broader source: Energy.gov [DOE]

Effects of lubricant additive chemistries and exhaust conditions on ash properties affecting diesel particulate filter performance. Comparison of ash characteristics such as packing density and elemental composition in field and laboratory aged DPFs.

391

Influence of combustion conditions and coal properties on physical properties of fly ash generated from pulverized coal combustion  

SciTech Connect (OSTI)

To develop combustion technology for upgrading the quality of fly ash, the influences of the coal properties, such as the size of pulverized coal particles and the two-stage combustion ratio during the combustion, on the fly ash properties were investigated using our test furnace. The particle size, density, specific surface area (obtained by the Blaine method), and shape of fly ash particles of seven types of coal were measured. It was confirmed that the size of pulverized coal particles affects the size of the ash particles. Regarding the coal properties, the fuel ratio affected the ash particle size distribution. The density and shape of the ash particles strongly depended on their ash size. Our results indicated that the shape of the ash particles and the concentration of unburned carbon affected the specific surface area. The influence of the two-stage combustion ratio was limited. 8 refs., 13 figs., 3 tabs.

Hiromi Shirai; Hirofumi Tsuji; Michitaka Ikeda; Toshinobu Kotsuji [Central Research Institute of Electric Power Industry, Kanagawa (Japan)

2009-07-15T23:59:59.000Z

392

Anion exchange method for the sequential determination of uranium, thorium and lead-210 in coal and coal ash  

Science Journals Connector (OSTI)

A radiochemical procedure is presented for the sequential determination of uranium isotopes, thorium isotopes, and210Pb in coal and coal ash. This procedure consists of dry ashing the...210Pb is measured by beta ...

V. R. Casella; C. T. Bishop; A. A. Glosby…

1981-01-01T23:59:59.000Z

393

Effectiveness of wood ash containing charcoal as a fertilizer for a forest plantation in a temperate region  

Science Journals Connector (OSTI)

Amendment of forest soils with mixed wood ash (MWA) generated in biomass power plants can prevent the depletion of ... that results from the intensive harvesting of forest plantations. Unlike fly wood ash, MWA co...

Martín Santalla; Beatriz Omil; Roque Rodríguez-Soalleiro; Agustín Merino

2011-09-01T23:59:59.000Z

394

Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1*  

E-Print Network [OSTI]

Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1* , L. S. Fisher1 , J of the potential for carbon sequestration in degraded mine lands, we have found that based on laboratory and field and its influence on carbon sequestration. Also, addition of fly ash to soil, while generally considered

Tiquia-Arashiro, Sonia M.

395

Market Assessment and Technical Feasibility Study of Pressurized Fluidized Bed Combustion Ash Use  

SciTech Connect (OSTI)

Western Research Institute in conjunction with the Electric Power Research Institute, Foster Wheeler Energy International, Inc. and the U.S. Department of Energy Technology Center (METC), has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for pressurized fluidized bed combustion (PFBC) ashes. The assessment is designed to address six applications, including: (1) structural fill, (2) road base construction, (3) supplementary cementing materials in portland cement, (4) synthetic aggregate, and (5) agricultural/soil amendment applications. Ash from low-sulfur subbituminous coal-fired Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, and ash from the high-sulfur bituminous coal-fired American Electric Power (AEP) bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing. This paper addresses the technical feasibility of ash use options for PFBC unit using low- sulfur coal and limestone sorbent (karhula ash) and high-sulfur coal and dolomite sorbents (AEP Tidd ash).

Bland, A.E.; Brown, T.H. [Western Research Inst., Laramie, WY (United States)

1996-12-31T23:59:59.000Z

396

California bearing ratio behavior of soil-stabilized class F fly ash systems  

SciTech Connect (OSTI)

Fly ash is a finely divided mineral residue resulting from the combustion of coal in power plants that occupies large extents of land and also causes environmental problems. Hence, concerted attempts are being made to effectively use fly ash in an environmentally friendly way instead of dumping. Several studies have been carried out for its bulk utilization, such as its addition to improve the California bearing ratio (CBR) of soil in roads and embankments. But a thorough mixing of fly ash with soil may not be possible in the field. Hence a study has been carried out on the CBR behavior of black cotton soil and Raichur fly ash (which is class F) in layers and compared with the same in mixes. The results show that the CBR values of soil-fly ash mixes are better than layers, as expected. To improve the strength of layers, cement is used as an additive to fly ash. The results show that black cotton soil can be improved with stabilized fly ash, solving its strength problem as well as the disposal problem of fly ash.

Leelavathamma, B.; Mini, K.M.; Pandian, N.S. [Indian Institute for Science, Bangalore (India). Dept. for Civil Engineering

2005-11-01T23:59:59.000Z

397

Radioactivity of coals and ashes from Çatalazi coal-fired power plant in Turkey  

Science Journals Connector (OSTI)

......from 15 countries(4). The combustion of coal in a CFPP leads to an increase...of utilization of Turkish coal combustion fly ash in concrete production...7440-29-1 Thorium | Coal analysis Coal Ash analysis chemistry Environmental Exposure analysis......

Hüseyin Aytekin; Ridvan Baldik

2012-04-01T23:59:59.000Z

398

Updating for Ash Cooler Fluidized Air System of a 410 t/h CFB Boiler  

Science Journals Connector (OSTI)

The paper presents an updating scheme for ash cooler fluidized air system of a 410 t/h CFB boiler. The ash cooler fluidized air, which is originally designed, is provided by the independent configuration of two forced fans. By analyzing and studying ...

Gao Jian-qiang; Chen Hong-wei; Zhang Wei

2009-10-01T23:59:59.000Z

399

Resuspension of Relic Volcanic Ash and Dust from Katmai: Still an Aviation Hazard  

Science Journals Connector (OSTI)

Northwest winds were strong enough to continuously resuspend relic volcanic ash from the Katmai volcano cluster and the Valley of Ten Thousand Smokes on 20–21 September 2003. The ash cloud reached over 1600 m and extended over 230 km into the ...

David Hadley; Gary L. Hufford; James J. Simpson

2004-10-01T23:59:59.000Z

400

E-Print Network 3.0 - artificial fly ash-clay Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fly ash-clay Page: << < 1 2 3 4 5 > >> 1 Study of composite cement containing burned oil shale Summary: studied. Context SiO2 CaO Al2O3 OPC BFS Class C fly ash Clays Metakaolin...

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network [OSTI]

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

402

Re-imaging coal: novel process removes mercury while retaining ash sales  

SciTech Connect (OSTI)

A two-stage thermal pretreatment process for removing moisture and mercury from raw coal has been developed by the Western Research Institute. This allows sales of ash from power plants to continue since no sorbents end up in the ash. 3 figs., 1 photo.

Bland, A. [Western Research Institute (United States)

2008-07-01T23:59:59.000Z

403

Properties of concrete incorporating high volumes of ASTM Class F fly ash  

E-Print Network [OSTI]

This thesis presents the results of research performed in developing high-volume fly ash (HVFA) concrete incorporating ASTM Type I cement and ASTM Class F fly ash from Big Brown Power Plant of TU Electric, Texas. In HVFA concrete, the proportion...

Li, Wei Tung

1995-01-01T23:59:59.000Z

404

Effect of Fly Ash on Solidification and Heavy Metals Chemical Speciation of Sludge  

Science Journals Connector (OSTI)

In order to explore new municipal sewage sludge treatment method and reduce its harm for environment, fly ash discarded from power plant was used as conditioner in sludge treatment in the paper. The properties of sewage sludge were changed after adding ... Keywords: fly ash, sludge, compressive strength, heavy metal, speciation

Yongjian Piao; Mingsong Wu; Xun Xu; Qingliang Zhao; Fugui Zhang; Nanqi Ren

2011-01-01T23:59:59.000Z

405

Determination of Total Solids and Ash in Algal Biomass: Laboratory Analytical Procedure (LAP)  

SciTech Connect (OSTI)

This procedure describes the methods used to determine the amount of moisture or total solids present in a freeze-dried algal biomass sample, as well as the ash content. A traditional convection oven drying procedure is covered for total solids content, and a dry oxidation method at 575?C is covered for ash content.

Van Wychen, S.; Laurens, L. M. L.

2013-12-01T23:59:59.000Z

406

Geochemical Constraints on the Origin of a Shallow Ash Occurrence: in the Mahanadi Basin, offshore India  

E-Print Network [OSTI]

Geochemical Constraints on the Origin of a Shallow Ash Occurrence: in the Mahanadi Basin, offshore sampled in the continental margins offshore India (Fig 1). A volcanic ash layer was recovered below seafloor Surrounding Sediments: Grey sediment in A is a nannofossil and plant debris bearing clay

New Hampshire, University of

407

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke  

Science Journals Connector (OSTI)

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke ... The ash pits have since gone through an extensive remedial process. ... The other metals investigated (i.e., Fe, Cu, Zn, and Pb) also were present predominantly as sulfates. ...

L. Jia; E. J. Anthony; J. P. Charland

2002-02-27T23:59:59.000Z

408

Improvement of the Coal Ash Slagging Tendency by Coal Washing and Additive Blending with Mullite Generation  

Science Journals Connector (OSTI)

Four typical coals and two pretreatment methods were investigated to prevent slagging by facilitating mullite formation in coal ash at a high temperature. ... Both security and economy in power plant can be improved substantially as long as ash deposition and slagging tendency alleviated. ... Pilot-projects about coal washing and coal blending economic benefit are looking forward to put into practice. ...

Zhenyu Huang; Yan Li; Dan Lu; Zhijun Zhou; Zhihua Wang; Junhu Zhou; Kefa Cen

2013-03-11T23:59:59.000Z

409

Performance Study of K2CsSb Photocathode Inside a DC High Voltage Gun  

SciTech Connect (OSTI)

In the past decade, there has been considerable interest in the generation of tens of mA average current in a photoinjector. Until recently, GaAs:Cs cathodes and K{sub 2}CsSb cathodes have been tested successfully in DC and RF injectors respectively for this application. Our goal is to test the K{sub 2}CsSb photocathode inside a DC gun. Since the multialkali cathode is a compound with constant characteristics over its entire thickness, we anticipate that the lifetime issues seen in GaAs:Cs due to surface damage by ion bombardment would be minimized. Hence successful operation of the K{sub 2}CsSb cathode in a DC gun could lead to a relatively robust electron source capable of delivering ampere level currents. In order to test the performance of a K{sub 2}CsSb cathode in a DC gun, we have designed and built a load lock system that allows the fabrication of the cathode at Brookhaven National Lab (BNL) and its testing at Jefferson Lab (JLab). In this paper, we will present the performance of the K{sub 2}CsSb photocathode in the preparation chamber and in the DC gun.

McCarter J. L.; Rao T.; Smedley, J.; Grames, J.; Mammei, R.; Poelker, M.; Suleiman, R.

2011-09-01T23:59:59.000Z

410

Semiconductor structures having electrically insulating and conducting portions formed from an AlSb-alloy layer  

DOE Patents [OSTI]

The semiconductor structure comprises a plurality of semiconductor layers formed on a substrate including at least one layer of a III-V compound semiconductor alloy comprising aluminum (Al) and antimony (Sb), with at least a part of the AlSb-alloy layer being chemically converted by an oxidation process to form superposed electrically insulating and electrically conducting portions. The electrically insulating portion formed from the AlSb-alloy layer comprises an oxide of aluminum (e.g., Al{sub 2}O{sub 3}), while the electrically conducting portion comprises Sb. A lateral oxidation process allows formation of the superposed insulating and conducting portions below monocrystalline semiconductor layers for forming many different types of semiconductor structures having particular utility for optoelectronic devices such as light-emitting diodes, edge-emitting lasers, vertical-cavity surface-emitting lasers, photodetectors and optical modulators (waveguide and surface normal), and for electronic devices such as heterojunction bipolar transistors, field-effect transistors and quantum-effect devices. The invention is expected to be particularly useful for forming light-emitting devices for use in the 1.3--1.6 {mu}m wavelength range, with the AlSb-alloy layer acting to define an active region of the device and to effectively channel an electrical current therein for efficient light generation. 10 figs.

Spahn, O.B.; Lear, K.L.

1998-03-10T23:59:59.000Z

411

Lattice-registered growth of GaSb on Si (211) with molecular beam epitaxy  

SciTech Connect (OSTI)

A GaSb film was grown on a Si(211) substrate using molecular beam epitaxy indicating full lattice relaxation as well as full lattice registration and dislocation-free growth in the plane perpendicular to the [01 - 1]-direction. Heteroepitaxy of GaSb on a Si(211) substrate is dominated by numerous first order and multiple higher order micro-twins. The atomic-resolved structural study of GaSb films by high-angle annular dark-field scanning transmission electron microscopy reveals that slight tilt, along with twinning, favors the lattice registry to Si(211) substrates. Preferential bonding of impinging Ga and Sb atoms at the interface due to two distinctive bonding sites on the Si(211) surface enables growth that is sublattice-ordered and free of anti-phase boundaries. The role of the substrate orientation on the strain distribution of GaSb epilayers is further elucidated by investigating the local change in the lattice parameter using the geometric phase analysis method and hence effectiveness of the lattice tilting in reducing the interfacial strain was confirmed further.

Hosseini Vajargah, S.; Botton, G. A. [Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Canadian Centre for Electron Microscopy, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Ghanad-Tavakoli, S. [Centre for Emerging Device Technologies, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Preston, J. S.; Kleiman, R. N. [Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1 (Canada); Centre for Emerging Device Technologies, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Department of Engineering Physics, McMaster University, Hamilton, Ontario L8S 4L7 (Canada)

2012-11-01T23:59:59.000Z

412

Evaluation of rice husk ash as filler in tread compounds  

Science Journals Connector (OSTI)

Rice which is one of the largest agriculture crops produces around 22% of rice rusk during its milling process. This material is mainly used as fuel for energy generation which results in an ash which disposal represents an environmental issue. The rice husk ash (RHA) contains over than 70% of silica in an amorphous form and a lot of applications is being developed for it all over the world. The use of silica as a filler in the tire industry is growing since it contributes significantly to the reduction of fuel consumption of the automobiles allowing at the same time better traction (safety). This paper presents an evaluation of the use of RHA as filler in rubber tread compounds prepared in lab scale and compares its performance with compounds prepared with commercial silica and carbon black the fillers normally used in tire industry. Mechanical and rheological properties are evaluated with emphasis for tan delta as an indicator of tread performance related with rolling resistance (fuel consumption) and wet grip/traction (safety).

2014-01-01T23:59:59.000Z

413

Controlling ettringite formation in FBC fly ash geopolymer concrete  

Science Journals Connector (OSTI)

Abstract Fluidized bed coal combstion (FBC) is extensively used in small self-generation power plants. The fly ash obtained from this FBC process contains high quantity of calcium and sulfate compounds which hinders its use in the construction industry. In addition, its reactivity is low and additional source material or additive is, therefore, needed to increase the reaction. This research studied the use of Al(OH)3 and high concentrations of NaOH to control ettringite formation in the FBC fly ash geopolymer. Two replacement levels of 2.5 wt.% and 5.0 wt.% of Al(OH)3 and three NaOH concentrations of 10, 12 and 15 M were used in the study. Results indicated that the NaOH concentration affected the ettringite formation and strength of the FBC geopolymer. No ettringite was formed at high NaOH concentration of 15 M which helped the dissolution of calcium sulfate and formed the additional calcium hydroxide. The subsequent pozzolanic reaction led to strength gain of the geopolymer. For 15 M NaOH, the addition of 2.5 wt.% Al(OH)3 promoted the reaction and formed a dense matrix of alumino silicate compound. Relatively high 7-day compressive strength of 30 MPa was obtained.

Prinya Chindaprasirt; Siwanant Thaiwitcharoen; Supranee Kaewpirom; Ubolluk Rattanasak

2013-01-01T23:59:59.000Z

414

Argonne CNM HighlightL Hard X-ray characterization of fly ash geopolymers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hard X-ray characterization of fly ash geopolymers Hard X-ray characterization of fly ash geopolymers Calcium Map Calcium map of an activated fly ash geopolymer displays regions of high calcium concentration (circled). Their distribution suggests localization as a discrete calcium-rich phase within the lower-calcium aluminosilicate geopolymer gel. Use of the Hard X-Ray Nanoprobe (HXN) has provided the first access to the nature of heterogeneity in real fly ash-derived geopolymers at the nanoscale. Direct evidence of the formation of discrete high-calcium nanometer-sized particles within a hydroxide-activated geopolymer synthesized from a low-calcium fly ash has been obtained using HXN fluorescence characterization. Additionally, the team of CNM users from the University of Melbourne, the Universidad del Valle of Colombia, and the

415

Influence of curing temperature on cement hydration and mechanical strength development of fly ash mortars  

SciTech Connect (OSTI)

The influence of fly ash and curing temperature on cement hydration and compressive strength development of mortars was investigated. Test parameters included type of fly ash (two different Class F fly ashes were tested), the level of cement replacement (10, 20 and 30% by mass), and curing temperature (20 C and 40 C). The mortar physical and microstructural properties were determined by means of thermal analyses, compressive strength measurements and SEM observations. Test results confirm that fly ash tends to increase significantly the rate of cement hydration at early age. Data also demonstrate that an elevation of the curing temperature reduces the long-term compressive strength of the reference mortar mixture. In contrast, an increase of the curing temperature seems to have no detrimental effect on the long-term compressive strength of the fly ash mixtures.

Maltais, Y.; Marchand, J. [Univ. Laval, Quebec (Canada). Centre de Recherche Interuniversitaire sur le Beton] [Univ. Laval, Quebec (Canada). Centre de Recherche Interuniversitaire sur le Beton

1997-07-01T23:59:59.000Z

416

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin |  

Broader source: Energy.gov (indexed) [DOE]

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin American Recovery and Reinvestment Act workers recently cleaned up a second basin containing coal ash residues from Cold War operations at the Savannah River Site (SRS). About $24 million from the Recovery Act funded the environmental restoration project, allowing SRS to complete the project at least five years ahead of schedule. The work is part of a larger Recovery Act cleanup of the P Area scheduled for completion by the end of September 2011. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin More Documents & Publications EIS-0220: Final Environmental Impact Statement EIS-0220: Final Environmental Impact Statement

417

Simulation of Coal Ash Particle Deposition Experiments (Copyright 2011, American Chemical Society)  

SciTech Connect (OSTI)

Existing experimental ash particle deposition measurements from the literature have been simulated using the computational fluid dynamics (CFD) discrete phase model (DPM) Lagrangian particle tracking method and an existing ash particle deposition model based on the Johnson?Kendall?Roberts (JKR) theory, in the Fluent commercial CFD code. The experimental heating tube was developed to simulate ash temperature histories in a gasifier; ash-heating temperatures ranged from 1873 to 1573 K, spanning the ash-melting temperature. The present simulations used the realizable k?? turbulence model to compute the gas flow field and the heat transfer to a cooled steel particle impact probe and DPM particle tracking for the particle trajectories and temperatures. A user-defined function (UDF) was developed to describe particle sticking/rebounding and particle detachment on the impinged wall surface. Expressions for the ash particle Young’s modulus in the model, E, versus the particle temperature and diameter were developed by fitting to the E values that were required to match the experimental ash sticking efficiencies from several particle size cuts and ash-heating temperatures for a Japanese bituminous coal. A UDF that implemented the developed stiffness parameter equations was then used to predict the particle sticking efficiency, impact efficiency, and capture efficiency for the entire ash-heating temperature range. Frequency histogram comparisons of adhesion and rebound behavior by particle size between model and experiments showed good agreement for each of the four ash-heating temperatures. However, to apply the present particle deposition model to other coals, a similar validation process would be necessary to develop the effective Young’s modulus versus the particle diameter and temperature correlation for each new coal.

Ai, Weiguo; Kuhlman, John M

2011-01-20T23:59:59.000Z

418

Feasible experimental study on the utilization of a 300 MW CFB boiler desulfurizating bottom ash for construction applications  

SciTech Connect (OSTI)

CFB boiler ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. The disposal in landfills has been the most common means of handling ash in circulating fluidized bed boiler power plants. However for a 300 MW CFB boiler power plant, there will be 600,000 tons of ash discharged per year and will result in great volumes and disposal cost of ash byproduct. It was very necessary to solve the utilization of CFB ash and to decrease the disposal cost of CFB ash. The feasible experimental study results on the utilization of the bottom ashes of a 300 MW CFB boiler in Baima power plant in China were reported in this paper. The bottom ashes used for test came from the discharged bottom ashes in a 100 MW CFB boiler in which the anthracite and limestone designed for the 300 MW CFB project was burned. The results of this study showed that the bottom ash could be used for cementitious material, road concrete, and road base material. The masonry cements, road concrete with 30 MPa compressive strength and 4.0 MPa flexural strength, and the road base material used for base courses of the expressway, the main road and the minor lane were all prepared with milled CFB bottom ashes in the lab. The better methods of utilization of the bottom ashes were discussed in this paper.

Lu, X.F.; Amano, R.S. [University of Wisconsin, Milwaukee, WI (United States). Dept. of Mechanical Engineering

2006-12-15T23:59:59.000Z

419

Maternal Transfer of Contaminants to Eggs in Common Grackles (Quiscalus quiscala) Nesting on Coal Fly Ash Basins  

E-Print Network [OSTI]

common grackles (Quiscalus quis- cala) nesting in association with coal fly ash settling basins be warranted. The disposal of slurried coal combustion waste (hereafter, ash) into open settling impoundments grackles (Quiscalus quiscala) nesting at coal ash settling basins for trace elements to determine

Hopkins, William A.

420

Coal ash as an absorbent to remove SO2, and its activity change in NO?NH3 reaction  

Science Journals Connector (OSTI)

After being activated with NaOH aqueous solution, coal ash showed a maximal sorption capacity of about...3 SO2/g ash. Catalytic activity of coal ash for the NO?NH3 reaction was gradually depressed by the presence...

F. Nozaki; O. Watanabe; T. Sodesawa

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung*  

E-Print Network [OSTI]

Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung The use of fly ash as an admixture results in enhancement of the electromagnetic interference (EMI of fly ash as an admixture for enhancing the electromagnetic interference (EMI) shielding. EMI shielding

Chung, Deborah D.L.

422

Journal of Hazardous Materials B132 (2006) 244252 Zeolite synthesis from paper sludge ash at low temperature  

E-Print Network [OSTI]

Journal of Hazardous Materials B132 (2006) 244­252 Zeolite synthesis from paper sludge ash at low 2005 Available online 4 November 2005 Abstract Paper sludge ash was partially converted into zeolites by reaction with 3 M NaOH solution at 90 C for 24 h. The paper sludge ash had a low abundance of Si

Downs, Robert T.

423

Smoking Status and Occupational Exposure Affects Oxidative DNA Injury in Boilermakers Exposed to Metal Fume and Residual Oil Fly Ash  

Science Journals Connector (OSTI)

...sensitization by residual oil fly ash particles...composition of residual oil fly ash determines...coupled plasma sector field mass spectrometry...particulate-mediated cytokine production in lung epithelial...et al. Residual oil fly ash induces cytotoxicity...probably through cumulative oxidative DNA damage...

Sutapa Mukherjee; Lyle J. Palmer; Jee Young Kim; David B. Aeschliman; Robert S. Houk; Mark A. Woodin; and David C. Christiani

2004-03-01T23:59:59.000Z

424

Filtration of Sludge and Sodium Nonatitanate Solutions  

SciTech Connect (OSTI)

The proposed facility designs for the ion exchange and solvent extraction flowsheets under development to treat high level waste at the Savannah River Site use crossflow filtration to remove entrained sludge and monosodium titanate (MST). Bench-scale and pilot-scale testing performed with simulated feed streams showed much lower filtration rates than desired for the process. This report documents an investigation of the impact on filtration of using Honeywell sodium nonatitanate (ST), rather than MST, for strontium and actinide removal.

Poirier, M.R.

2000-10-16T23:59:59.000Z

425

Surface core-level shift of InSb(111)-2×2  

Science Journals Connector (OSTI)

Surface core-level photoemission of InSb(111)-2×2 was performed using a synchrotron radiation light source. There were two surface components of the In 4d core level. A higher binding component of In 4d is attributed to the surface In bonded to Sb atoms. The lower binding component with smaller intensity is due to the surface In cluster atoms. On the other hand, we were not able to observe any surface components in the Sb 4d core level. This puzzling behavior is interpreted with a different contribution of surface and bulk Madelung potential to the surface core-level shifts in relation with the atomic geometry. © 1996 The American Physical Society.

Jeong Won Kim; Sehun Kim; Jae Myung Seo; Shin-ichiro Tanaka; Masao Kamada

1996-08-15T23:59:59.000Z

426

Unambiguous determination of carrier concentration and mobility for InAs/GaSb superlattice photodiode optimization  

SciTech Connect (OSTI)

In this communication we report on electrical properties of nonintentionally doped (nid) type II InAs/GaSb superlattice grown by molecular beam epitaxy. We present a simple technological process which, thanks to the suppression of substrate, allows direct Hall measurement on superlattice structures grown on conductive GaSb substrate. Two samples were used to characterize the transport: one grown on a semi-insulating GaAs substrate and another grown on n-GaSb substrate where a etch stop layer was inserted to remove the conductive substrate. Mobilities and carrier concentrations have been measured as a function of temperature (77-300 K), and compared with capacitance-voltage characteristic at 80 K of a photodiode comprising a similar nid superlattice.

Cervera, C.; Rodriguez, J. B.; Perez, J. P.; Aiet-Kaci, H.; Chaghi, R.; Christol, P. [Institut d'Electronique du Sud (IES), UMR CNRS 5214, Case 067, Universite Montpellier 2, 34095 Montpellier Cedex 05 (France); Konczewicz, L.; Contreras, S. [Groupe d'Etude des Semiconducteurs (GES), UMR CNRS 5650, Case 074, Universite Montpellier 2, 34095 Montpellier Cedex 5 (France)

2009-08-01T23:59:59.000Z

427

Sodium Plugging Test Loop - Nuclear Engineering Division (Argonne)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sodium Plugging Test Loop Sodium Plugging Test Loop Sodium Plugging Test Loop Overview Other Facilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sodium Plugging Test Loop This experimental setup is part of the Global Nuclear Energy Partnership (GNEP) Advanced Fuel Cycle R&D work carried out at Argonne on advanced sodium component technology. Bookmark and Share For long range sodium technology research and development, employing supercritical CO2 Brayton cycle power conversion technology as an advanced balance of plant technology is being considered. The component that provides the interface between the sodium and supercritical CO2 is a compact heat exchanger known as a printed circuit heat exchanger (PCHE). This heat exchanger has very small coolant flow passages that may foul or

428

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment |  

Broader source: Energy.gov (indexed) [DOE]

Obtains Patent for Nuclear Reactor Sodium Cleanup Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. Piping in the east boiler basement of the sodium processing building was color coded for easy identification. Orange indicates sodium and green identifies cooling water.

429

Low-Pressure Sodium Lighting Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Low-Pressure Sodium Lighting Basics Low-Pressure Sodium Lighting Basics Low-Pressure Sodium Lighting Basics August 16, 2013 - 10:17am Addthis Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color rendition. Typical applications include highway and security lighting, where color is not important. Low-pressure sodium lamps work somewhat like fluorescent lamps. Like high-intensity discharge lighting, low-pressure sodium lamps require up to 10 minutes to start and have to cool before they can restart. Therefore, they are most suitable for applications in which they stay on for hours at a time. They are not suitable for use with motion detectors. The chart below compares low-pressure sodium lamps and high-intensity

430

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment |  

Broader source: Energy.gov (indexed) [DOE]

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. Piping in the east boiler basement of the sodium processing building was color coded for easy identification. Orange indicates sodium and green identifies cooling water.

431

Electrical characteristics and thermal stability of HfO{sub 2} metal-oxide-semiconductor capacitors fabricated on clean reconstructed GaSb surfaces  

SciTech Connect (OSTI)

HfO{sub 2}/GaSb interfaces fabricated by high-vacuum HfO{sub 2} deposition on clean reconstructed GaSb surfaces were examined to explore a thermally stable GaSb metal-oxide-semiconductor structure with low interface-state density (D{sub it}). Interface Sb-O bonds were electrically and thermally unstable, and post-metallization annealing at temperatures higher than 200?°C was required to stabilize the HfO{sub 2}/GaSb interfaces. However, the annealing led to large D{sub it} in the upper-half band gap. We propose that the decomposition products that are associated with elemental Sb atoms act as interface states, since a clear correlation between the D{sub it} and the Sb coverage on the initial GaSb surfaces was observed.

Miyata, Noriyuki, E-mail: nori.miyata@aist.go.jp; Mori, Takahiro; Yasuda, Tetsuji [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); Ohtake, Akihiro [National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044 (Japan); Ichikawa, Masakazu [The University of Tokyo, Tokyo 113-8656 (Japan)

2014-06-09T23:59:59.000Z

432

Evaluating the Effects of the Kingston Fly Ash Release on Fish Reproduction: Spring 2009 - 2010 Studies  

SciTech Connect (OSTI)

On December 22, 2008, a dike containing fly ash and bottom ash at the Tennessee Valley Authority's (TVA) Kingston Fossil Plant in East Tennessee failed and released a large quantity of ash into the adjacent Emory River. Ash deposits from the spill extended 4 miles upstream of the facility to Emory River mile 6 and downstream to Tennessee River mile 564 ({approx}8.5 miles downstream of the confluence of the Emory River with the Clinch River, and {approx}4 miles downstream of the confluence of the Clinch River with the Tennessee River). A byproduct of coal combustion, fly ash contains a variety of metals and other elements which, at sufficient concentrations and in specific forms, can be harmful to biological systems. The ecological effects of fly ash contamination on exposed fish populations depend on the magnitude and duration of exposure, with the most significant risk considered to come from elevated levels of certain metals in the ash, particularly selenium, on fish reproduction and fish early life stages (Lemly 1993; Besser and others 1996). The ovaries of adult female fish in a lake contaminated by coal ash were reported to have an increased frequency of atretic oocytes (dead or damaged immature eggs) and reductions in the overall numbers of developing oocytes (Sorensen 1988) associated with elevated body burdens of selenium. Larval fish exposed to selenium through maternal transfer of contaminants to developing eggs in either contaminated bodies of water (Lemly 1999) or in experimental laboratory exposures (Woock and others 1987, Jezierska and others 2009) have significantly increased incidences of developmental abnormalities. Contact of fertilized eggs and developing embryos to ash in water and sediments may also pose an additional risk to the early life stages of exposed fish populations through direct uptake of metals and other ash constituents (Jezierska and others 2009). The establishment and maintenance of fish populations is intimately associated with the ability of individuals within a population to reproduce. Reproduction is thus generally considered to be the most critical life function affected by environmental contamination. From a regulatory perspective, the issue of potential contaminant-related effects on fish reproduction from the Kingston fly ash spill has particular significance because the growth and propagation of fish and other aquatic life is a specific classified use of the affected river systems. To address the potential effects of fly ash from the Kingston spill on the reproductive health of exposed fish populations, ORNL has undertaken a series of studies in collaboration with TVA that include: (1) a combined field study of metal bioaccumulation in ovaries and other fish tissues (Adams and others 2012) and the reproductive condition of sentinel fish species in reaches of the Emory and Clinch Rivers affected by the fly ash spill (the current report); (2) laboratory tests of the potential toxicity of fly ash from the spill area on fish embryonic and larval development (Greeley and others 2012); (3) additional laboratory experimentation focused on the potential effects of long-term exposures to fly ash on fish survival and reproductive competence (unpublished); and (4) a combined field and laboratory study examining the in vitro developmental success of embryos and larvae obtained from fish exposed in vivo for over two years to fly ash in the Emory and Clinch Rivers (unpublished). The current report focuses on the reproductive condition of adult female fish in reaches of the Emory and Clinch Rivers influenced by the fly ash spill at the beginning of the spring 2009 breeding season - the first breeding season immediately following the fly ash release - and during the subsequent spring 2010 breeding season. Data generated from this and related reproductive/early life stage studies provide direct input to ecological risk assessment efforts and complement and support other phases of the overall biomonitoring program associated with the fly ash spill.

Greeley Jr, Mark Stephen [ORNL; Adams, Marshall [ORNL; McCracken, Kitty [ORNL

2012-05-01T23:59:59.000Z

433

Synthesis and Characterization of Ag-or Sb-Doped ZnO Nanorods by a Facile Hydrothermal Route  

E-Print Network [OSTI]

Synthesis and Characterization of Ag- or Sb-Doped ZnO Nanorods by a Facile Hydrothermal Route Oleg Stefan Cel Mare BouleVard, MD-2004 Chisinau, Republic of MoldoVa, AdVanced Materials Processing ZnO nanorods doped with Ag and Sb have been synthesized by a facile hydrothermal technique. Crystal

Kik, Pieter

434

Evaluation Of Glass Density To Support The Estimation Of Fissile Mass Loadings From Iron Concentrations In SB8 Glasses  

SciTech Connect (OSTI)

The Department of Energy – Savannah River (DOE-SR) has provided direction to Savannah River Remediation (SRR) to maintain fissile concentration in glass below 897 g/m{sup 3}. In support of that guidance, the Savannah River National Laboratory (SRNL) provided a technical basis and a supporting Microsoft® Excel® spreadsheet for the evaluation of fissile loading in Sludge Batch 5 (SB5), Sludge Batch 6 (SB6), Sludge Batch 7a (SB7a), and Sludge Batch 7b (SB7b) glass based on the iron (Fe) concentration in glass as determined by the measurements from the Slurry Mix Evaporator (SME) acceptability analysis. SRR has since requested that the necessary density information be provided to allow SRR to update the Excel® spreadsheet so that it may be used to maintain fissile concentration in glass below 897 g/m{sup 3} during the processing of Sludge Batch 8 (SB8). One of the primary inputs into the fissile loading spreadsheet includes an upper bound for the density of SB8-based glasses. Thus, these bounding density values are to be used to assess the fissile concentration in this glass system. It should be noted that no changes are needed to the underlying structure of the Excel-based spreadsheet to support fissile assessments for SB8. However, SRR should update the other key inputs to the spreadsheet that are based on fissile and Fe concentrations reported from the SB8 Waste Acceptance Product Specification (WAPS) sample.

Edwards, T. B.; Peeler, D. K.; Kot, W. K.; Gan, H.; Pegg, I. L.

2013-04-30T23:59:59.000Z

435

Genomic and Transcriptomic Analyses of the Facultative Methanotroph Methylocystis sp. Strain SB2 Grown on Methane or Ethanol  

Science Journals Connector (OSTI)

...Methylocystis sp. Strain SB2 Grown on Methane or Ethanol Alexey Vorobev a Sheeja Jagadevan a Sunit...cultures grown with either methane or ethanol. Evidence for use of the canonical methane...Methylocystis sp. strain SB2 grown with ethanol compared to methane revealed that on ethanol...

Alexey Vorobev; Sheeja Jagadevan; Sunit Jain; Karthik Anantharaman; Gregory J. Dick; Stéphane Vuilleumier; Jeremy D. Semrau

2014-03-07T23:59:59.000Z

436

Suppression of bulk conductivity in InAs/GaSb broken gap composite quantum wells  

SciTech Connect (OSTI)

The two-dimensional topological insulator state in InAs/GaSb quantum wells manifests itself by topologically protected helical edge channel transport relying on an insulating bulk. This work investigates a way of suppressing bulk conductivity by using gallium source materials of different degrees of impurity concentrations. While highest-purity gallium is accompanied by clear conduction through the sample bulk, intentional impurity incorporation leads to a bulk resistance over 1 M?, independent of applied magnetic fields. In addition, ultra high electron mobilities for GaAs/AlGaAs structures fabricated in a molecular beam epitaxy system used for the growth of Sb-based samples are reported.

Charpentier, Christophe; Fält, Stefan; Reichl, Christian; Nichele, Fabrizio; Nath Pal, Atindra; Pietsch, Patrick; Ihn, Thomas; Ensslin, Klaus; Wegscheider, Werner [Laboratory for Solid State Physics, ETH Zürich, 8093 Zürich (Switzerland)] [Laboratory for Solid State Physics, ETH Zürich, 8093 Zürich (Switzerland)

2013-09-09T23:59:59.000Z

437

JV Task 120 - Coal Ash Resources Research Consortium Research  

SciTech Connect (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') is the core coal combustion product (CCP) research group at the Energy & Environmental Research Center (EERC). CARRC focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of CCPs. CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCP utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program, which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCP performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 2007 to 2009 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCPs. The tasks were included in four categories: (1) Environmental Evaluations of CCPs; (2) Evaluation of Impacts on CCPs from Emission Controls; (3) Construction and Product-Related Activities; and (4) Technology Transfer and Maintenance Tasks. All tasks are designed to work toward achieving the CARRC overall goal and supporting objectives. The various tasks are coordinated in order to provide broad and useful technical data for CARRC members. Special projects provide an opportunity for non-CARRC members to sponsor specific research or technology transfer consistent with CARRC goals. This report covers CARRC activities from January 2007 through March 2009. These activities have been reported in CARRC Annual Reports and in member meetings over the past 2 years. CARRC continues to work with industry and various government agencies with its research, development, demonstration, and promotional activities nearing completion at the time of submission of this report. CARRC expects to continue its service to the coal ash industry in 2009 and beyond to work toward the common goal of advancing coal ash utilization by solving CCP-related technical issues and promoting the environmentally safe, technically sound, and economically viable management of these complex and changing materials.

Debra Pflughoeft-Hassett; Loreal Heebink; David Hassett; Bruce Dockter; Kurt Eylands; Tera Buckley; Erick Zacher

2009-03-28T23:59:59.000Z

438

Recent Sodium Technology Development for the Decommissioning of the Rapsodie and Superphenix Reactors and the Management of Sodium Wastes  

SciTech Connect (OSTI)

The Commissariat a l'Energie Atomique (CEA) has recently developed and/or conducted experiments on several processes in support of the decommissioning of two French liquid-metal fast reactors (LMFRs), Rapsodie and Superphenix, as well as on the treatment of CEA sodium wastes. CEA has demonstrated that it is possible to define appropriate and efficient processes to meet the different situations encountered in decommissioning LMFRs. Mechanical techniques derived from standard technologies have been successfully applied to fast reactor decommissioning to complete primary vessel draining from sodium. In addition, specific chemical processes have been developed to deal safely with metallic sodium reactivity. Sodium-contaminated equipment has been successfully cleaned by reacting sodium with water mist in an atmosphere with carbon dioxide to form inert sodium carbonate. Bulk sodium has been successfully converted into aqueous caustic soda by injection of liquid-metallic sodium into sodium hydroxide solution. Several processes were also defined to deal with specific sodium wastes. In all cases the principle is based on a sodium/water chemical reaction where the released hydrogen and heat are controlled. With the development of a wide variety of processes, all steps in the decommissioning of LMFRs are assumed to be now properly mastered.

Rodriguez, G.; Gastaldi, O.; Baque, F. [Commissariat a l'Energie Atomique Cadarache (France)

2005-04-15T23:59:59.000Z

439

JOURNAL DE PHYSIQUE Colloque Cl, supplment au no 1 , Tome 35, Janvier 1974, page Cl-43 TUDE DES STRUCTURES MAGNTIQUES DE CeSb ET GdSb  

E-Print Network [OSTI]

champ hyperfin transféré (H,,,) au site du noyau de I'ion non magnétique (l'ion Sb dans le cas présent noyau de I'ion non iiiagnétique est nul si l'ordre magnétique est du type I I ; il est différent de zéro

Boyer, Edmond

440

Carrier lifetime reduction in 1.5 m AlGaAsSb saturable absorbers with air and AlAsSb barriers  

E-Print Network [OSTI]

The SESAM structures consist of a 60-period InGaAsP/InP distributed Bragg reflector DBR and a 7-nm-thick Al exponential carrier decay time of 20 ps can be achieved. The studied AlGaAsSb absorbers were deposited on InGaAsP depth, the saturation fluence, the inverse absorption, the nonsaturable absorption, and the carrier de

Keller, Ursula

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Electrical and thermoelectric properties of 90% Bi{sub 2}Te{sub 3}-5% Sb{sub 2}Te{sub 3}-5% Sb{sub 2}Se{sub 3} single crystals doped with SbI{sub 3}  

SciTech Connect (OSTI)

Bi{sub 2}Te{sub 3}-Sb{sub 2}Te{sub 3}-Sb{sub 2}Se{sub 3} alloys with Sb{sub 2}Te{sub 3} and Sb{sub 2}Se{sub 3} contents up to 10 mol%, e.g., the 90% Bi{sub 2}Te{sub 3}-5% Sb{sub 2}Te{sub 3}-5% Sb{sub 2}Se{sub 3} alloy, are among the best n-type thermoelectric materials for Peltier coolers used near room temperature. In this work, the electrical and thermoelectric properties of Sbl{sub 3}doped 90% Bi{sub 2}Te{sub 3}-5% Sb{sub 2}Te{sub 3}-5% Sb{sub 2}Se{sub 3} alloys were characterized at temperatures ranging from 80K to 600K. The temperature dependencies of the Hall coefficient, carrier mobility, Seebeck coefficient and thermal conductivity were measured, and the scattering parameter and bandgap energy were determined.

Hyun, D.B.; Hwang, J.S.; Shim, J.D.; Kolomoets, N.V. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Div. of Metals] [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Div. of Metals; Oh, T.S. [Hong Ik Univ., Seoul (Korea, Republic of). Dept. of Metallurgy and Materials Science] [Hong Ik Univ., Seoul (Korea, Republic of). Dept. of Metallurgy and Materials Science

1998-12-04T23:59:59.000Z

442

TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations by operando-XRD and Mossbauer techniques  

E-Print Network [OSTI]

TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations We report the electrochemical study of TiSnSb towards Li, as a negative electrode for Li-ion batteries. TiSnSb can reversibly take up more than 5 lithiums per formula unit leading to reversible

Boyer, Edmond

443

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures  

DOE Patents [OSTI]

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated.

Khan, M. Rashid (Morgantown, WV)

1990-01-01T23:59:59.000Z

444

Methods for Characterization of Composition of Fly Ashes from Coal-Fired Power Stations:? A Critical Overview  

Science Journals Connector (OSTI)

HTA and LTA are laboratory-produced coal ashes that are originated at (i) regulated temperatures, commonly at 500?815 °C in air (after the spontaneous coal combustion), and (ii) oxygen plasma ashing (normally at 150?200 °C), respectively. ... The wet disposal of ash, from the coal-fired thermal power plants, involves its mixing with water and its impoundment in the ash ponds or lagoons. ... The fabric, mineralogy, and chem. of high-calcium ash deposits from the Agios Dimitrios pulverized-lignite power plant in northern Greece were investigated as a key to the ability to improve the performance of the power plant. ...

Stanislav V. Vassilev; Christina G. Vassileva

2005-04-06T23:59:59.000Z

445

Geopolymer concretes: a green construction technology rising from the ash  

SciTech Connect (OSTI)

Researchers at Louisiana Tech University have embarked on a multi-year research initiative to develop applications for inorganic polymer concrete, or geopolymer concrete, in the area of civil construction, and to bring solve of these applications to market. One objective was to produce a spray-on coating for use in the harsh environment of wastewater conveyance and treatment facilities. Another project is to establish relationships between fly ash composition and particle size distribution and the mechanical attributes and workability of the resulting geopolymer concrete. A third project is to develop a 'smart' geopolymer concrete whose response to a given electric current can be correlated to the stress level to which the structure is subjected. 1 fig., 6 photos.

Allouche, E. [Louisiana Tech University, LA (United States)

2009-07-01T23:59:59.000Z

446

Management of sewage sludge and ash containing radioactive materials.  

SciTech Connect (OSTI)

Approximately 50% of the seven to eight million metric tonnes of municipal sewage sludge produced annually in the US is reused. Beneficial uses of sewage sludge include agricultural land application, land reclamation, forestry, and various commercial applications. Excessive levels of contaminants, however, can limit the potential usefulness of land-applied sewage sludge. A recently completed study by a federal inter-agency committee has identified radioactive contaminants that could interfere with the safe reuse of sewage sludge. The study found that typical levels of radioactive materials in most municipal sewage sludge and incinerator ash do not present a health hazard to sewage treatment plant workers or to the general public. The inter-agency committee has developed recommendations for operators of sewage treatment plants for evaluating measured or estimated levels of radioactive material in sewage sludge and for determining whether actions to reduce potential exposures are appropriate.

Bachmaier, J. T.; Aiello, K.; Bastian, R. K.; Cheng, J.-J.; Chiu, W. A.; Goodman, J.; Hogan, R.; Jones, A. R.; Kamboj, S.; Lenhart, T.; Ott, W. R.; Rubin, A. B.; Salomon, S. N.; Schmidt, D. W.; Setlow, L. W.; Yu, C.; Wolbarst, A. B.; Environmental Science Division; Middlesex County Utilities Authority; U.S. EPA; N.J. Dept of Environmental Protection; NRC

2007-01-01T23:59:59.000Z

447

INVESTIGATION OF FLY ASH AND ACTIVATED CARBON OBTAINED FROM PULVERIZED COAL BOILERS  

SciTech Connect (OSTI)

One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addresses the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addresses the possible connection between SCR reactors, fly ash properties and Hg capture. The project is determining the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed are also being determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control, are being analyzed to determine the effect of SCR on the ash.

Edward K. Levy; Christopher Kiely

2005-11-01T23:59:59.000Z

448

Hydrothermal treatment of MSWI bottom ash forming acid-resistant material  

SciTech Connect (OSTI)

To recycle municipal solid waste incinerator (MSWI) bottom ash, synthesis of hydrothermal minerals from bottom ash was performed to stabilize heavy metals. MSWI bottom ash was mixed with SiO{sub 2}, Al(OH){sub 3}, and Mg(OH){sub 2} so its chemical composition was similar to that of hydrothermal clay minerals. These solid specimens were mixed with water at a liquid/solid ratio of 5. The reaction temperature was 200 deg. C, and reactions were performed for 24-240 h. Generation of kaolinite/smectite mixed-layer clay mineral was found in the samples after the reaction of the mixture of bottom ash, SiO{sub 2}, and Mg(OH){sub 2}. Calcium silicate hydrate minerals such as tobermorite and xonotlite were also generated. X-ray powder diffraction suggested the presence of amorphous materials. Leaching tests at various pHs revealed that the concentration of heavy metals in the leachates from MSWI bottom ash hydrothermally treated with SiO{sub 2} and Mg(OH){sub 2} was lower than that in leachates from non-treated bottom ash, especially under acid conditions. Hydrothermal treatment with modification of chemical composition may have potential for the recycling of MSWI bottom ash.

Etoh, Jiro [Department of Urban and Environmental Engineering, Faculty of Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395 (Japan)], E-mail: etoh@doc.kyushu-u.ac.jp; Kawagoe, Takeshi [Department of Earth System Engineering, Graduate School of Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395 (Japan); Shimaoka, Takayuki [Department of Urban and Environmental Engineering, Faculty of Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395 (Japan); Watanabe, Koichiro [Department of Earth System Engineering, Faculty of Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395 (Japan)

2009-03-15T23:59:59.000Z

449

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents [OSTI]

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas for further combustion in modified oil or gas fired furnaces or boilers. Two concentric shells define a combustion volume within the inner shell and a plenum between them through which combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, Albert H. (Huntington, NY)

1983-10-04T23:59:59.000Z

450

Assessment of the effect of high ash content in pulverized coal combustion  

SciTech Connect (OSTI)

The existing literature on CFD-based coal combustion modelling is applicable mainly for coals of low ash content and the calculations are done on an ash-free basis. In Indian coals, the ash content may be significantly higher, up to 40% or more. Studies reported in the literature show that the mineral matter in the coal may have a number of effects on the combustion characteristics. In the present study, a sensitivity analysis is performed, using the CFD code CFX of AEA Technology, on the likely effect of ash content on the char reactivity, oxygen diffusion rate for char combustion and on the radiative heat transfer parameters. The results show that the effect of enhanced char reactivity is negligible whereas reduced oxygen diffusion rates due to a thicker ash layer may result in a significant reduction in char oxidation rates with a resultant decrease in the peak temperature in the furnace. The global parameters such as the peak temperature and the flue gas temperature remain relatively insensitive to the presence of high ash content. These results are consistent with the experimental observations of Kurose et al. . Kurose, M. Ikeda, H. Makino, Combustion characteristics of high ash coal in pulverized coal combustion, J. Fuel 80 (2001) 1447-1455).

Jayanti, S.; Maheswaran, K.; Saravanan, V. [Indian Institute of Technology, Madras (India). Dept. of Chemical Engineering

2007-05-15T23:59:59.000Z

451

Assessing determinants of industrial waste reuse: The case of coal ash in the United States  

Science Journals Connector (OSTI)

Abstract Devising effective strategies to facilitate waste reuse depends on the solid understanding of reuse behaviors. However, previous studies of reuse behavior have been limited in scope, focusing mostly on household recycling behaviors or very limited types of industrial wastes. To gain a better understanding of the business reuse behaviors, this study examined the impact of various factors in technical, economic, regulatory, and behavioral categories in the case of coal ash generated in the United States. The results of fixed effect models for fly ash and bottom ash particularly showed the significance role of the behavioral factor. In both models, a proxy variable, which represents knowledge sharing among the power plants or the utility's decision-making, turned out to be statistically significant and had the largest coefficient estimates among a group of variables. This finding may imply that the characteristics of waste reuse behavior are determined more by business decision-making behaviors than by market or institutional factors. However, the role of the behavioral variable was stronger in the bottom ash models than in the fly ash models. While the reuse of bottom ash was determined primarily by the behavioral variable, fly ash reuse was determined by more diverse factors including economic and regulatory variables. This could be explained by material characteristics in relation to competing resources and the nature of reuse applications.

Joo Young Park

2014-01-01T23:59:59.000Z

452

Ash content prediction of coarse coal by image analysis and GA-SVM  

Science Journals Connector (OSTI)

Abstract Ash content is one of the most important indexes of coal quality, and fast prediction of ash content is urgent and important for coal processing industry. The aim of this paper is to propose a method of ash content prediction of coarse coal by the use of image analysis and GA-SVM. Coal particles on the surface were randomly selected to measure the ash content, and a semi-automatic local-segmentation algorithm was proposed to identify the corresponding coal particle regions. Thirty-eight features were extracted, and selected by GA. Ash content prediction model was established by SVM, and K-CV method is used to determine the hyper-parameters (c, g) of SVM. RMSE and R-square were used to measure the prediction effects of ash content. Results indicated that the prediction effects of narrow size fractions are better than wide size fraction, and larger size fraction is more accurate than smaller size fraction in ash content prediction.

Zelin Zhang; Jianguo Yang; Yuling Wang; Dongyang Dou; Wencheng Xia

2014-01-01T23:59:59.000Z

453

Characterization of fly ashes from circulating fluidized bed combustion (CFBC) boilers cofiring coal and petroleum coke  

SciTech Connect (OSTI)

The chemistry, mineralogy, morphology, and particle size distribution were investigated in fly ashes from the burning of Datong (ShanXi, China) bituminous coal and the cofiring of Mideast high-sulfur petroleum coke (PC) with 30:70 (cal %) and 50:50 (cal %) blends of Datong bituminous coal in two commercial CFBC boilers. With the exception of CaO, the amounts of major oxides in the fly ashes from cofiring PC and coal were close to those of the common coal fly ashes. The PC-coal fly ashes were enriched in Ni, V, and Mo, implying these trace elements were mainly derived from PC. Ni and V, along with several other elements, such as Cr, Cu, Se, Pb, U, Th, and possibly As and Cd, increased in content with a decrease in temperature of the electrostatic precipitator (ESP). The results of chemistry, mineralogy, and morphology studies suggested that the desulfurization rate of the CFBC boilers at current conditions was low, and the PC tends to coarsen the fly ash particles and increase the loss on ignition (LOI) values, making these fly ashes unsuitable for use as a cement additive or a mineral admixture in concrete. Further studies on the combustion status of the CFBC boilers are needed if we want to be able to increase the desulfurization rate and produce high-quality fly ashes for broader and full utilization. 22 refs., 4 figs., 4 tabs.

Feihu Li; Jianping Zhai; Xiaoru Fu; Guanghong Sheng [Nanjing University, Nanjing (China). State Key Laboratory of Pollution Control & Resource Reuse, School of the Environment

2006-08-15T23:59:59.000Z

454

Factors contributing to the breakdown of sodium beta-alumina  

SciTech Connect (OSTI)

Clarification of the breakdown process occurring during charge transfer in sodium beta alumina solid electrolytes was derived from: (1) studying the effects of molten sodium contact at 350/sup 0/C on single crystal sodium beta alumina and polycrystalline sodium beta alumina; (2) determination of critical current density by monitoring acoustic emissions accompanying crack growth in sodium/sodium beta alumina/sodium cells subjected to linear current ramping at 1 mA cm/sup -2/ sec/sup -1/; (3) failure analysis conducted on cycled electrolytes, some from commercial sodium/sulfur cells, which had been subjected to up to 703 Ahr cm/sup -2/ of charge transfer. Gray coloration developing in beta aluminas in contact with molten sodium was found to be a consequence of formation, through reduction by sodium, of oxygen vacancies charge compensated by electrons. Electronic conductivity of the electrolyte increases as a result. No second phase formation was detected. Colored electrolytes from sodium/sulfur cells show evidence of a newly recognized degradation mechanism in which fracture occurs when sodium is reduced and deposited internally under pressure as metal in regions where an electronic conductivity gradient exists. Heating colored beta aluminas in air produces reoxidation and bleaching. Kinetics and other properties of the coloration and bleaching processes were determined. Critical current density was found to bear an inverse relation to average electrolyte grain size. Evidence was found in the cycled electrolytes for a slow crack growth mechanism and a progressive mode of degradation advancing from the sulfur electrode interface. Implications of the findings for the construction and operation of sodium/sulfur battery systems are discussed.

Buechele, A.C.

1982-05-01T23:59:59.000Z

455

The use of PFBC ashes to ameliorate acid conditions: An equilibrium and greenhouse study  

SciTech Connect (OSTI)

Pilot-scale development at the Foster Wheeler Energia Oy 10 MW{sub th} circulating PFBC at Karhula, Finland, has demonstrated the advantages of pressurized fluidized bed combustion (PFBC) technology. Commercial scale deployment of the technology at the Lakeland Utilities MacIntosh Unit No. 4 has been proposed. Development of uses for the ashes from PFBC systems is being actively pursued as part of commercial demonstration of PFBC technologies. Western Research Institute (WRI), in conjunction with the US Department of Energy (DOE), Federal Energy Technology Center (FETC), Foster Wheeler Energy International, Inc., and the Electric Power Research Institute (EPRI), conducted a laboratory scale investigation of the technical feasibility of PFBC ash as an amendment for acidic soils and spoils encountered in agricultural and reclamation applications. Ashes were collected from the Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, operating on (1) low-sulfur subbituminous and (2) high-sulfur bituminous coals. The results of the technical feasibility testing indicated the following: (1) PFBC fly ash (Karhula-low S fly ash) and ag-lime (CaCO{sub 3}) were used as amendments attempting to ameliorate acid spoil conditions. These materials were found to be effective acid mine spoil amendments. (2) The greenhouse study demonstrated that PFBC ash and/or bed ash amended spoils resulted in similar seed germination numbers as compared to the ag-lime amended spoils. (3) The greenhouse study also demonstrated that PFBC fly ash and/or bed ash amended spoils resulted in comparable plant productivity to the ag-lime amended spoils. In fact, all amendments resulted in statistically the same levels of plant production for each plant species.

Brown, T.H.; Bland, A.E.

1999-07-01T23:59:59.000Z

456

Conversion of Fly Ash into Mesoporous Aluminosilicate Hsiao-Lan Chang, Chang-Min Chun, Ilhan A. Aksay, and Wei-Heng Shih*,  

E-Print Network [OSTI]

and aluminum sources. Fly ash, which is a byproduct of coal burning, contains mostly aluminosilicates. Recently, several authors have studied the conversion of fly ash into zeolites.5-7 Shige- moto et al.8 increased the yield of zeolites by first fusing the fly ash with NaOH. The reaction of fly ash with NaOH produced

Aksay, Ilhan A.

457

Study on ash deposition under oxyfuel combustion of coal/biomass blends  

Science Journals Connector (OSTI)

Combustion in an O2/CO2 mixture (oxyfuel) has been recognized as a promising technology for CO2 capture as it produces a high CO2 concentration flue gas. Furthermore, biofuels in general contribute to CO2 reduction in comparison with fossil fuels as they are considered CO2 neutral. Ash formation and deposition (surface fouling) behavior of coal/biomass blends under O2/CO2 combustion conditions is still not extensively studied. Aim of this work is the comparative study of ash formation and deposition of selected coal/biomass blends under oxyfuel and air conditions in a lab scale pulverized coal combustor (drop tube). The fuels used were Russian and South African coals and their blends with Shea meal (cocoa). A horizontal deposition probe, equipped with thermocouples and heat transfer sensors for on line data acquisition, was placed at a fixed distance from the burner in order to simulate the ash deposition on heat transfer surfaces (e.g. water or steam tubes). Furthermore, a cascade impactor (staged filter) was used to obtain size distributed ash samples including the submicron range at the reactor exit. The deposition ratio and propensity measured for the various experimental conditions were higher in all oxyfuel cases. The SEM/EDS and ICP analyses of the deposit and cascade impactor ash samples indicate K interactions with the alumina silicates and to a smaller extend with Cl, which was all released in the gas phase, in both the oxyfuel and air combustion samples. Sulfur was depleted in both the air or oxyfuel ash deposits. S and K enrichment was detected in the fine ash stages, slightly increased under air combustion conditions. Chemical equilibrium calculations were carried out to facilitate the interpretation of the measured data; the results indicate that temperature dependence and fuels/blends ash composition are the major factors affecting gaseous compounds and ash composition rather than the combustion environment, which seems to affect the fine ash (submicron) ash composition, and the ash deposition mechanisms.

L. Fryda; C. Sobrino; M. Cieplik; W.L. van de Kamp

2010-01-01T23:59:59.000Z

458

Crystallization of Coal Ash Slags at High Temperatures and Effects on the Viscosity  

Science Journals Connector (OSTI)

The coal samples were ashed in a muffle furnace at 815 °C, according to the Chinese Standard GB/T1574-2007. ... Shenfu and Beisu coals are enriched in glass modifying oxides (CaO + Fe2O3 + MgO > 30%), while the contents of Al2O3 in Baodian coal ash is higher than 30%; therefore, they exhibit the crystalline slag behavior. ... compn. of coals and coal ashes from a wide variety of deposits (41) were studied by a melting test, x-ray diffractometry, light microscopy, differential-thermal, thermogravimetric and chem. ...

Haiping Yuan; Qinfeng Liang; Xin Gong

2012-04-16T23:59:59.000Z

459

Risk Ranking of Bioaccessible Metals from Fly Ash Dissolved in Simulated Lung and Gut Fluids  

Science Journals Connector (OSTI)

Power plant fly ash from two fuels, coal and a mixture of coal and shredded tires, were evaluated for trace metal solubility in simulated human lung and gut fluids (SLF and SGF, respectively) to estimate bioaccessibility. ... The proportion of bioaccessible to total metal ranged from zero (V) to 80% (Zn) for coal-derived ash in SLF and from 2 (Th) to 100% (Cu) for tire-derived fly ash in SGF. ... On dissolution in SLF, the most limiting metals were Pb, Cu, and Zn. ...

John Twining; Peter McGlinn; Elaine Loi; Kath Smith; Reto Gieré

2005-08-30T23:59:59.000Z

460

A novel approach for the improvement of open circuit voltage and fill factor of InGaAsSb/GaSb thermophotovoltaic cells  

SciTech Connect (OSTI)

Heterojunction n-Al{sub 0.25}Ga{sub 0.75}As{sub 0.02}Sb{sub 098}/p-In{sub 0.16}Ga{sub 0.84}As{sub 0.04}Sb{sub 0.96} thermophotovoltaic (TPV) cells were grown by molecular-beam epitaxy on n-GaSb-substrates. In the spectral range from 1 {micro}m to 2.1 {micro}m these cells, as well as homojunction n-p-In{sub 0.16}Ga{sub 0.84}As{sub 0.04}Sb{sub 0.96} cells, have demonstrated internal quantum efficiencies exceeding 80%, despite about a 200 meV barrier in the conduction band at the heterointerface. Estimation shows that the thermal emission of the electrons photogenerated in p-region over this barrier can provide high efficiency for hetero-cells if the electron recombination time in p-In{sub 0.16}Ga{sub 0.84}As{sub 0.04}Sb{sub 0.96}is longer than 10 ns. Keeping the same internal efficiency as homojunction cells, hetero-cells provide a unique opportunity to decrease the dark forward current and thereby increase open circuit voltage (V{sub {proportional_to}}) and fill factor at a given illumination level. It is shown that the decrease of the forward current in hetero-cells is due to the lower recombination rate in n-type wider-bandgap space-charge region and to the suppression of the hole component of the forward current. The improvement in V{sub {proportional_to}} reaches 100% at illumination level equivalent to 1 mA/cm{sup 2} and it decreases to 5% at the highest illumination levels (2--3 A/cm{sup 2}), where the electron current component dominates in both the homo- and heterojunction cells. Values of V{sub {proportional_to}} as high as 310 meV have been obtained for a hetero-cell at illumination levels of 3 A/cm{sup 2}. Under this condition, the expected fill factor value is about 72% for a hetero-cell with improved series resistance. The heterojunction concept provides excellent prospects for further reduction of the dark forward current in TPV cells.

Garbuzov, D.Z.; Martinelli, R.U.; Khalfin, V.; Lee, H.; Morris, N.A.; Taylor, G.C.; Connolly, J.C. [Sarnoff Corp., Princeton, NJ (United States); Charache, G.W.; DePoy, D.M. [Lockheed-Martin, Inc., Schenectady, NY (United States)

1997-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash sb sodium" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Performance Study of K2CsSb Photocathode inside a DC High Voltage Gun  

SciTech Connect (OSTI)

In the past decade, there has been considerable interest in the generation of tens of mA average current in a photoinjector. Until recently, GaAs:Cs cathodes and K2CsSb cathodes have been tested successfully in DC and RF injectors respectively for this application. Our goal is to test the GaAs:Cs in RF injector and the K2CsSb cathode in the DC gun in order to widen our choices. Since the multialkali cathode is a compound with uniform stochiometry over its entire thickness, we anticipate that the life time issues seen in GaAs:Cs due surface damage by ion bombardment would be minimized with this material. Hence successful operation of the K2CsSb cathode in DC gun could lead to a relatively robust electron source capable of delivering ampere level currents. In order to test the performance of K2CsSb cathode in a DC gun, we have designed and built a load lock system that would allow the fabrication of the cathode at BNL and its testing at JLab. In this paper, we will present the design of the load-lock system, cathode fabrication, and the cathode performance in the preparation chamber and in the DC gun.

T. Rao, J. Smedley, J.M. Grames, R. Mammei, J.L. McCarter, M. Poelker, R. Suleiman

2011-03-01T23:59:59.000Z

462

Thermophotovoltaic furnace–generator for the home using low bandgap GaSb cells  

Science Journals Connector (OSTI)

It is well known that distributed combined heat and power (CHP) systems for commercial and industrial buildings are economically desirable because they conserve energy. Here, a thermophotovoltaic (TPV) unit is described that brings CHP into the home providing both heat and electric power by replacing the typical home heating furnace with a combined TPV furnace–generator. First, the design of a 1.5 kWelectric/12.2 kWthermal TPV furnace–generator is described along with the key components that make it possible. Diffused junction GaSb cells are one of these key components. Secondly, an economic cost target is determined for this system where the cost of the photovoltaic array will be key to the economical implementation of this concept. Finally, it is argued that the GaSb cells and arrays can be manufactured at the required low cost. The cost target can be reached because the GaSb cells in the TPV furnace–generator can produce an electrical power density of 1 W cm?2 which is 100 times higher than the typical solar cell. The cost target can also be reached because the GaSb cell fabrication process parallels the silicon solar cell process where no toxic gases are used, no wafer polish is required and cast polycrystalline cells can be used.

L M Fraas; J E Avery; H X Huang

2003-01-01T23:59:59.000Z

463

Development of Nanostructures in Thermoelectric Pb-Te-Sb Alloys , L. A. Collins2  

E-Print Network [OSTI]

in the figure of merit of thermoelectric materials. Fabrication of nanostructured thermoelectric materials via the discovery of materials with a high thermoelectric figure of merit, zT, defined as S2 T/, where immiscible thermoelectric materials: PbTe-Sb2Te3. This ternary system was selected for investigation because

464

0.52eV Quaternary InGaAsSb Thermophotovoltaic Diode Technology  

SciTech Connect (OSTI)

Thermophotovoltaic (TPV) diodes fabricated from 0.52eV lattice-matched InGaAsSb alloys are grown by Metal Organic Vapor Phase Epitaxy (MOVPE) on GaSb substrates. 4cm{sup 2} multi-chip diode modules with front-surface spectral filters were tested in a vacuum cavity and attained measured efficiency and power density of 19% and 0.58 W/cm{sup 2} respectively at operating at temperatures of T{sub radiator} = 950 C and T{sub diode} = 27 C. Device modeling and minority carrier lifetime measurements of double heterostructure lifetime specimens indicate that diode conversion efficiency is limited predominantly by interface recombination and photon energy loss to the GaSb substrate and back ohmic contact. Recent improvements to the diode include lattice-matched p-type AlGaAsSb passivating layers with interface recombination velocities less than 100 cm/s and new processing techniques enabling thinned substrates and back surface reflectors. Modeling predictions of these improvements to the diode architecture indicate that conversion efficiencies from 27-30% and {approx}0.85 W/cm{sup 2} could be attained under the above operating temperatures.

MW Dashiell; JF Beausang; G Nichols; DM Depoy; LR Danielson; H Ehsani; KD Rahner; J Azarkevich; P Talamo; E Brown; S Burger; P Fourspring; W Topper; PF Baldasaro; CA Wang; R Huang; M Connors; G Turner; Z Shellenbarger; G Taylor; Jizhong Li; R Marinelli; D Donetski; S Anikeev; G Belenky; S Luryi; DR Taylor; J Hazel

2004-06-09T23:59:59.000Z

465

Semimetallic antiferromagnetism in the half-Heusler compound CuMnSb Ruben Weht,2  

E-Print Network [OSTI]

CuMnSb, the first antiferromagnet AFM in the Mn-based class of Heuslers and half-Heuslers that contains several conventional and half metallic ferromagnets, shows a peculiar stability of its magnetic order in high magnetic fields. Density functional based studies reveal an unusual nature of its unstable

Pickett, Warren

466

Colorado State Forest Service SB09-020 --Responsibility for Responding to Wildland Fires  

E-Print Network [OSTI]

SB09-020 clarifies the roles and responsibilities of fire protection districts, county sheriffs and responsibilities progressively from local jurisdiction to fire protection district jurisdiction to county: · The fire chief of the fire protection district is responsible for all fires, including wildland fires

467

Ambipolar Field Effect in Sb-Doped Bi2Se3 Nanoplates by Solvothermal Synthesis  

E-Print Network [OSTI]

ranging from electronics to energy conversion. Despite much exciting progress in the field, high and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025. The carrier concentration of these Bi2Se3 nanoplates is controlled by compensational Sb doping during

Cui, Yi

468

Grain refinement and texture development of cast bi90sb10 alloy via severe plastic deformation  

E-Print Network [OSTI]

recrystallization and causes the development of a bimodal microstructure consisting of fine grains (5-30 micron) and coarse grains (50-300 micron). ECAE processing of homogenizied Bi-Sb alloy causes grain refinement and produces a more uniform microstructure...

Im, Jae-taek

2009-05-15T23:59:59.000Z

469

Fact Sheet: Sodium-Beta Batteries (October 2012)  

Broader source: Energy.gov (indexed) [DOE]

Sodium-Beta Batteries Sodium-Beta Batteries Improving the performance and reducing the cost of sodium-beta batteries for large-scale energy storage Sodium-beta batteries (Na-beta batteries or NBBs) use a solid beta-alumina (ß˝-Al 2 O 3 ) electrolyte membrane that selectively allows sodium ion transport between a positive electrode (e.g., a metal halide) and a negative sodium electrode. NBBs typically operate at temperatures near 350˚C. They are increasingly used in renewable storage and utility applications due to their high round-trip efficiency, high energy densities, and energy storage capacities ranging from a few kilowatt-hours to multiple megawatt-hours. In fact, U.S. utilities

470

Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

II. Phase Equilibria II. Phase Equilibria Title Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria Publication Type Journal Article Year of Publication 1996 Authors Ridgway, Paul L., Frank R. McLarnon, and John S. Newman Journal Journal of the Electrochemistry Society Volume 143 Issue 2 Pagination 412-417 Keywords 25 ENERGY STORAGE, 36 MATERIALS SCIENCE, ALUMINIUM OXIDES, equilibrium, performance, PHASE DIAGRAMS, PHOSPHIDES, PHOSPHORUS ADDITIONS, SODIUM