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Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Fly ash chemical classification based on lime  

Science Conference Proceedings (OSTI)

Typically, total lime content (CaO) of fly ash is shown in fly ash reports, but its significance is not addressed in US specifications. For certain applications a low lime ash is preferred. When a class C fly ash must be cementitious, lime content above 20% is required. A ternary S-A-C phase diagram pilot is given showing the location of fly ash compositions by coal rank and source in North America. Fly ashes from subbituminous coal from the Powder River Basin usually contain sufficient lime to be cementitious but blending with other coals may result in calcium being present in phases other than tricalcium aluminate. 9 refs., 1 fig.

Fox, J. [BASF Construction Chemicals, LLC (United States)

2007-07-01T23:59:59.000Z

2

Fly ash as a liming material for corn production  

Science Conference Proceedings (OSTI)

Fly ash produced as a by-product of subbituminous coal combustion can potentially serve as an alternative liming material without negatively affecting corn (Zea mays L.) production in areas where use of conventional liming materials can be uneconomical due to transportation costs. A study was conducted to determine if fly ash produced from the Nebraska Public Power District Gerald Gentleman Power Station located in Sutherland, NE could be used as an alternative liming material. Combinations of dry fly ash (DFA), wet fly ash (WFA), beet lime (by-product of sugar beet (Beta vulgaris L.) processing) (BL), and agricultural lime (AGL) were applied at rates ranging from 0.43 to 1.62 times the recommended lime rate to plots on four acidic soils (Anselmo fine sandy loam, Hord fine sandy loam, Holdrege sandy loam, and Valentine fine sand). Soil samples were collected to a depth of 0.2 m from plots and analyzed for pH before lime applications and twice periodically after lime application. The Hord and Valentine soils were analyzed for exchangeable Ca, Mg, K, Na,and Al for determination of percent Al saturation on selected treatments and sampling dates. Corn grain yields were determined annually. It is concluded that the fly ash utilized in this study and applied at rates in this study, increases soil pH comparable to agricultural lime and is an appropriate alternative liming material.

Tarkalson, D.D.; Hergert, G.W.; Stevens, W.B.; McCallister, D.L.; Kackman, S.D. [University of Nebraska, North Platte, NE (US)

2005-05-01T23:59:59.000Z

3

Limestone and Ash Storage Silos and Lime Preparation Equipment, Part  

NLE Websites -- All DOE Office Websites (Extended Search)

Limestone and Ash Storage Silos and Lime Preparation Equipment, Part Limestone and Ash Storage Silos and Lime Preparation Equipment, Part of the System to Inject Limestone Sorbent for SO, Control. Nucla, CO Nucla...continued Before being repowered, the plant consisted of three 12 MWe coal stoker- fired units built in 1959, which were taken out of service in 1984 due to low efficiency and high fuel cost. Antici- pating a need for additional power in the early 1990s. and after review of many power generation alternatives, CUEA started constmction of the re- powered Nucla CFB plant in Novem- ber 1984 and completed the project in May 1987. The original boilers were replaced with a new Fympower Corp. CFB bailer, a new high pressure 74 MWe steam turbine generator was installed, the three original 12 MWe steam turbines were

4

Activation Of Fly Ash-Lime Reactions By Curing At Elevated Temperature And By Addition Of Phosphogypsum.  

E-Print Network (OSTI)

??Pozzolanic reactions play a key role in improving the compressive strengths of compacted fly ash-lime specimens. Based on studies performed with cement amended fly ash… (more)

Asha, K

2011-01-01T23:59:59.000Z

5

Evaluation of Leachate Chemistry from Coal Refuse Blended and Layered with Fly Ash.  

E-Print Network (OSTI)

??Alkaline fly ash has been studied as a liming agent within coal refuse fills to reclaim acid-forming refuse. Previous studies focused on bulk blending ash… (more)

Hunt, Joseph Edward

2008-01-01T23:59:59.000Z

6

Regeneration of lime from sulfates for fluidized-bed combustion  

DOE Patents (OSTI)

In a fluidized-bed combustor the evolving sulfur oxides are reacted with CaO to form calcium sulfate which is then decomposed in the presence of carbonaceous material, such as the fly ash recovered from the combustion, at temperatures of about 900.degree. to 1000.degree. C., to regenerate lime. The regenerated lime is then recycled to the fluidized bed combustor to further react with the evolving sulfur oxides. The lime regenerated in this manner is quite effective in removing the sulfur oxides.

Yang, Ralph T. (Middle Island, NY); Steinberg, Meyer (Huntington Station, NY)

1980-01-01T23:59:59.000Z

7

LI  

Office of Legacy Management (LM)

\ \ LI g. / This document con&s of lf pages. No. 1 &of #copies, Series fl . .! ' \ ' > .b P .--r ' i ' ./' MJDIFICATION NO. k sUPPLEMENTALAMw24ENrto CONTRACT NO. A T (30-l)-1335 M O D IFICATION NO. 4 CONTRACTOR AND A D D m S : KIDIFICATION TO: -EINESTIEUTED CCSTOFWORKr TOTAT,ESTIIUTEDC~T OFWRKI INCREASEIN C O M K rSSI~ OBLlDATIONt NEMTOTALCOMMISSION OBLIOaTIONt PAYl%NTTDBEMADEBY: HORIZONS, INCORPOlZATED R-inceton, New Jersey AIBNDSCOPEOFK#tK,EXTENDTR?M AND OTflER CHANOES $&31,lbOO (exclusive of fixed fee of $20,550.00) @549,484.00 (exchsive of fixed fee of $27,950.00) $l50,000.00 $rrS, 740*~ Division of Disburseaaent, United States T reasury Department, New York, New PO&. Submlt invoices to8 United State8 Atomic Energy Commission, P. 0. Box 30, Anaonia Station,

8

Gypsum treated fly ash as a liner for waste disposal facilities  

SciTech Connect

Fly ash has potential application in the construction of base liners for waste containment facilities. While most of the fly ashes improve in the strength with curing, the ranges of permeabilities they attain may often not meet the basic requirement of a liner material. An attempt has been made in the present context to reduce the hydraulic conductivity by adding lime content up to 10% to two selected samples of class F fly ashes. The use of gypsum, which is known to accelerate the unconfined compressive strength by increasing the lime reactivity, has been investigated in further improving the hydraulic conductivity. Hydraulic conductivities of the compacted specimens have been determined in the laboratory using the falling head method. It has been observed that the addition of gypsum reduces the hydraulic conductivity of the lime treated fly ashes. The reduction in the hydraulic conductivity of the samples containing gypsum is significantly more for samples with high amounts of lime contents (as high as 1000 times) than those fly ashes with lower amounts of lime. However there is a relatively more increase in the strengths of the samples with the inclusion of gypsum to the fly ashes at lower lime contents. This is due to the fact that excess lime added to fly ash is not effectively converted into pozzolanic compounds. Even the presence of gypsum is observed not to activate these reactions with excess lime. On the other hand the higher amount of lime in the presence of sulphate is observed to produce more cementitious compounds which block the pores in the fly ash. The consequent reduction in the hydraulic conductivity of fly ash would be beneficial in reducing the leachability of trace elements present in the fly ash when used as a base liner.

Sivapullaiah, Puvvadi V., E-mail: siva@civil.iisc.ernet.in [Department of Civil Engineering, Indian Institute of Science, Bangalore 560012 (India); Baig, M. Arif Ali, E-mail: reach2arif@gmail.com [Department of Civil Engineering, Indian Institute of Science, Bangalore 560012 (India)

2011-02-15T23:59:59.000Z

9

Process for the recovery of alumina from fly ash  

DOE Patents (OSTI)

An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

Murtha, M.J.

1983-08-09T23:59:59.000Z

10

Deborah Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

Deborah Rebecca Ash Deborah Ash Energy Analysis and Environmental Impacts Department Energy Efficiency Standards Group Lawrence Berkeley National Laboratory 1 Cyclotron Road MS...

11

Study on Aluminum Foam with Fly Ash Increase Viscosity  

Science Conference Proceedings (OSTI)

May 1, 2007 ... Study on Aluminum Foam with Fly Ash Increase Viscosity by Yong Wang, Guang- chun Yao, and Bing Li. Publisher: TMS. Product Format: PDF.

12

Climate VISION: Private Sector Initiatives: Lime  

Office of Scientific and Technical Information (OSTI)

Lime Association (NLA), representing approximately 95% of U.S. commercial lime production, is very pleased to submit this letter in response to President Bush's challenge to...

13

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-10-28T23:59:59.000Z

14

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1997-01-01T23:59:59.000Z

15

Climate VISION: Private Sector Initiatives: Lime: Results  

Office of Scientific and Technical Information (OSTI)

The National Lime Association (NLA) is pleased to report that between 2002 and 2008, the energy-related CO2 intensity of lime produced by NLA member companies has been reduced by...

16

Lime Wind | Open Energy Information  

Open Energy Info (EERE)

Lime Wind Lime Wind Facility Lime Wind Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Joseph Millworks Inc Developer Joseph Millworks Inc Energy Purchaser Idaho Power Location Huntington OR Coordinates 44.406667°, -117.310278° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":44.406667,"lon":-117.310278,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

17

Volatile fatty acid fermentation of lime-treated bagasse by rumen microorganisms  

E-Print Network (OSTI)

This thesis describes the design and operation of a batch, anaerobic, in vitro fermentation of sugarcane bagasse by a mixed culture of ruminal microflora. The bagasse was supplemented with a small amount of alfalfa (0.16 g alfalfa/g bagasse) to provide necessary nutrients. The volatile fatty acid (VFA) product concentrations, yields and proportions of each acid for six different bagasse concentrations (10, 20, 35, 50, 75, and 100 g/L) are reported. Bagasse was treated with calcium hydroxide to increase the digestibility of the cell wall carbohydrates. The treatment conditions were: Ca(OH)2 loading = 10 g/100 g dry bagasse, water loading = 8.5 g/g dry bagasse, temperature 100'C, and treatment time = 1 hour. Compared to untreated bagasse, the lime-treated bagasse gave higher total VFA concentrations, faster rates of acidogenesis, and more stable molar proportions of individual VFA'S. The highest total VFA concentration obtained from lime-treated bagasse was 690 mM (45 g/L). By applying the lime pretreatment, the total VFA concentrations increased over 80% for a 10 g dry bagasse/L loading fermentation (from 4.5g VFA/L to 8.5 g VFAAL) With lime pretreatment, approximately 71 to 96% of the final total VFA yields were accomplished within the initial three days of fermentation, whereas only 52 to 67% were achieved without pretreatment during the same time period. At all solid loadings, the VFA molar compositions resulting from lime-treated bagasse were quite constant: acetate, 64-70%; propionate, 21-28%; butyrate, 6.5-7.6%; and other acids were about 1% each. In this thesis, we examined the effect of higher substrate concentration up to 100 g dry bagasse/L. For untreated bagasse, the VFA yields were fairly constant regardless of substrate concentration (ca. 0.37 g VFA/g dry substrate). However, for lime-treated bagasse, the total VFA yields decreased as the substrate concentrations increased. The best total VFA yield obtained from 10 g/L lime-treated bagasse was 0.63 g VFA/g dry raw substrate (or 0.82 g VFA/g dry ash-free substrate or 0.94 g VFA/g dry ash-free, lignin- free substrate). This is greater than yields previously reported in the literature using lignocellulosic substrates, and hence demonstrates the superiority of this very effective lime pretreatment.

Lee, Chang-Ming

1993-01-01T23:59:59.000Z

18

Climate VISION: Private Sector Initiatives: Lime: Resources and...  

Office of Scientific and Technical Information (OSTI)

"lime". NLA represents the interests of its members in Washington, provides input on standards and specifications for lime, and funds and manages research on current and new uses...

19

Climate VISION: Private Sector Initiatives: Lime: Work Plans  

Office of Scientific and Technical Information (OSTI)

Us LIME Letters of IntentAgreements Work Plans GHG Inventory Protocols Resources & Links Energy Management Industry Associations Software Tools Training Calendar Results Lime -...

20

Climate VISION: Private Sector Initiatives: Lime: Resource and...  

Office of Scientific and Technical Information (OSTI)

Us LIME Letters of IntentAgreements Work Plans GHG Inventory Protocols Resources & Links Energy Management Industry Associations Software Tools Training Calendar Results Lime -...

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Effect of Long-term Lime and Potassium Applications on Quantity-Intensity (Q/I) Relationships in Sandy Soil1  

E-Print Network (OSTI)

in Sandy Soil1 D. L. SPARKS AND W. C. LiEBHARDT2 ABSTRACT The effects of long-term lime and K applications on quan- tity-intensity (Q/I) relationships were investigated on the Ap and B21t horizons of a Kalmia soil, and chloritized ver- miculite. Soil pH and exchangeable bases increased with depth and with lime additions

Sparks, Donald L.

22

White Ash Biology  

NLE Websites -- All DOE Office Websites (Extended Search)

White Ash Biology Name: blondi Location: NA Country: NA Date: NA Question: 1. Is the white ash tree endangered or is it a protected variety? 2. How does the white ash tree...

23

Hydration and strength development of binder based on high-calcium oil shale fly ash  

Science Conference Proceedings (OSTI)

The properties of high-calcium oil shale fly ash and low-calcium coal fly ash, which are produced in Israeli power stations, were investigated. High-calcium oil shale fly ash was found to contain a great amount of CaO{sub free} and SO{sub 3} in the form of lime and anhydrite. Mixtures of high-calcium oil shale fly ash and low-calcium coal fly ash, termed fly ash binder, were shown to cure and have improved strength. The influence of the composition and curing conditions on the compressive strength of fly ash binders was examined. The microstructure and the composition of fly ash binder after curing and long-term exposure in moist air, water and open air conditions were studied. It was determined that ettringite is the main variable in the strength and durability of cured systems. The positive effect of calcium silicate hydrates, CSH, which are formed by interaction of high-calcium oil shale fly ash and low-calcium coal fly ash components, on the carbonation and dehydration resistance of fly ash binder in open air is pronounced. It was concluded that high-calcium oil shale fly ash with high CaO{sub free} and SO{sub 3} content can be used as a binder for building products.

Freidin, C. [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)

1998-06-01T23:59:59.000Z

24

Cementitious binder from fly ash and other industrial wastes  

SciTech Connect

In this paper, investigations were undertaken to formulate cementitious binder by judicious blending of fly ash with Portland cement as well as by admixing fly ash with calcined phosphogypsum, fluorogypsum, lime sludge, and chemical activators of different finenesses. The effect of addition of calcined clay in these types of binders was studied. Data showed that cementitious binders of high compressive strength and water retentivity can be produced. The strength of masonry mortars increased with the addition of chemical activators. The strength development of binders takes place through formation of ettringite. C-S-H, and C{sub 4}AH{sub 13}. The binders are eminently suitable for partial replacement (up to 25%) of the cement in concrete without any detrimental affect on the strength. The results showed that fly ash can be used in the range from 45% to 70% in formulating these binders along with other industrial wastes to help in mitigating environmental pollution.

Singh, M.; Garg, M. [Central Building Research Inst., Roorkee (India)] [Central Building Research Inst., Roorkee (India)

1999-03-01T23:59:59.000Z

25

Ash Static Liquefaction  

Science Conference Proceedings (OSTI)

This laboratory study was focused on assessing fundamental geotechnical engineering properties of fly ash.  It involved the testing of fly ash recovered from the existing ash ponds and from dry fly ash silos operated by 5 participating utilities.  Materials from 22 different sites were involved in the testing program.  To provide comprehensive fundamental understanding of the similarities and differences between the samples, a series of basic geotechnical engineering characterization ...

2012-12-28T23:59:59.000Z

26

Activation of fly ash  

DOE Patents (OSTI)

Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

Corbin, D.R.; Velenyi, L.J.; Pepera, M.A.; Dolhyj, S.R.

1986-08-19T23:59:59.000Z

27

Activation of fly ash  

DOE Patents (OSTI)

Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

Corbin, David R. (New Castle, DE); Velenyi, Louis J. (Lyndhurst, OH); Pepera, Marc A. (Northfield, OH); Dolhyj, Serge R. (Parma, OH)

1986-01-01T23:59:59.000Z

28

Climate VISION: Private Sector Initiatives: Lime: GHG Inventory...  

Office of Scientific and Technical Information (OSTI)

GHG Inventory Protocols Read the CO2 Emissions Calculation Protocol for the Lime industry (PDF 229 KB) Download Acrobat Reader...

29

Optimizing Ash Handling - SmartAshTM System Evaluation  

Science Conference Proceedings (OSTI)

High ash levels in electrostatic precipitator (ESP) hoppers are notorious for increasing particulate matter (PM) emissions and plume opacity. Conventional means of monitoring hopper ash levels and fly ash handling system performance have been time-consuming and problematic. Neundorfer, Inc., has developed a fly ash conveying system-monitoring package (SmartAshSystem) that provides improved monitoring of fly ash removal process parameters and provides graphical depictions of ash system performance. Additi...

2007-11-21T23:59:59.000Z

30

LOW-TEMPERATURE ASH SINTERING AND STRENGTH DEVELOPMENT  

DOE Green Energy (OSTI)

The objective of the project is to develop fundamental sintering-viscosity relationships for coal-type ash at relatively low temperatures, with the end result being a simplified soot-blowing index for power systems. This involves correlating several important factors which control the ease of deposit removal, including deposit strength, deposit porosity, chemical composition, and temperature. Testing was performed on ashes derived from three coals and two biomass materials along with a standard soda-lime glass. The coals were selected because detailed analyses as well as ash samples were already available. Sintering characteristics of the ashes were to be determined by observation using an HSM and video recording system, with a stainless steel microscope stage chamber constructed to allow the use of corrosive gas atmospheres. The measurements would allow calculation of the viscosity of liquid phases as the sintering progressed, using the Frenkel and other sintering models. The sintering behavior and viscosity would be correlated with ash mineralogy and chemistry and information on bench-scale deposit strength and porosity to develop an initial relationship to predict deposit removability.

Christopher J. Zygarlicke; Donald P. McCollor; John P. Kay

1999-10-01T23:59:59.000Z

31

Fly Ash Systems  

Science Conference Proceedings (OSTI)

..., ASM International, 2006, p 499â??500ASM Handbook, Vol 13C, Corrosion: Environments and IndustriesCorrosion and Erosion of Ash-Handling

32

Wet Bottom Ash Systems  

Science Conference Proceedings (OSTI)

..., ASM International, 2006, p 499â??500ASM Handbook, Vol 13C, Corrosion: Environments and IndustriesCorrosion and Erosion of Ash-Handling

33

Dancing in the ashes.  

E-Print Network (OSTI)

??The following novel is the third draft of my creative thesis entitled Dancing in the Ashes . It is an exploration of the Detroit rave… (more)

Malesh, Vytautas Adolph

2009-01-01T23:59:59.000Z

34

Yuyi Li  

NLE Websites -- All DOE Office Websites (Extended Search)

Yuyi Li Yuyi Li Yuyi Li Electrochemical Technologies Group Lawrence Berkeley National Laboratory 1 Cyclotron Road MS 62-0203 Berkeley CA 94720 Office Location: 62-0325 (510) 486-6894 YuyiLi@lbl.gov I am the lab manager of the Batteries for Advanced Transportation Technologies (BATT) program. I support the research operation of all electrochemistry groups in different areas. My goal is to provide the best service to researchers, so they can focus on scientific research and free from distractions, such as running out of lab supplies or equipment malfunctions. I was born and raised in Guangdong province of China, and immigrated to the U.S at age 19. After I earned a bachelor degree in chemical engineering from UCLA, I had worked in the R&D department of an organic photovoltaic

35

Yuyi Li  

NLE Websites -- All DOE Office Websites (Extended Search)

Office Location: 62-0325 (510) 486-6894 YuyiLi@lbl.gov I am the lab manager of the Batteries for Advanced Transportation Technologies (BATT) program. I support the research...

36

Ash cloud aviation advisories  

SciTech Connect

During the recent (12--22 June 1991) Mount Pinatubo volcano eruptions, the US Air Force Global Weather Central (AFGWC) requested assistance of the US Department of Energy`s Atmospheric Release Advisory Capability (ARAC) in creating volcanic ash cloud aviation advisories for the region of the Philippine Islands. Through application of its three-dimensional material transport and diffusion models using AFGWC meteorological analysis and forecast wind fields ARAC developed extensive analysis and 12-hourly forecast ash cloud position advisories extending to 48 hours for a period of five days. The advisories consisted of ``relative`` ash cloud concentrations in ten layers (surface-5,000 feet, 5,000--10,000 feet and every 10,000 feet to 90,000 feet). The ash was represented as a log-normal size distribution of 10--200 {mu}m diameter solid particles. Size-dependent ``ashfall`` was simulated over time as the eruption clouds dispersed. Except for an internal experimental attempt to model one of the Mount Redoubt, Alaska, eruptions (12/89), ARAC had no prior experience in modeling volcanic eruption ash hazards. For the cataclysmic eruption of 15--16 June, the complex three-dimensional atmospheric structure of the region produced dramatically divergent ash cloud patterns. The large eruptions (> 7--10 km) produced ash plume clouds with strong westward transport over the South China Sea, Southeast Asia, India and beyond. The low-level eruptions (< 7 km) and quasi-steady-state venting produced a plume which generally dispersed to the north and east throughout the support period. Modeling the sequence of eruptions presented a unique challenge. Although the initial approach proved viable, further refinement is necessary and possible. A distinct need exists to quantify eruptions consistently such that ``relative`` ash concentrations relate to specific aviation hazard categories.

Sullivan, T.J.; Ellis, J.S. [Lawrence Livermore National Lab., CA (United States); Schalk, W.W.; Nasstrom, J.S. [EG and G, Inc., Pleasanton, CA (United States)

1992-06-25T23:59:59.000Z

37

Lime Energy formerly Electric City Corporation | Open Energy Information  

Open Energy Info (EERE)

Energy formerly Electric City Corporation Energy formerly Electric City Corporation Jump to: navigation, search Name Lime Energy (formerly Electric City Corporation) Place Elk Grove Village, Illinois Zip 60007 Product Developer, manufacturer and integrator of energy savings technologies and building automation systems. Specialist in demand response systems. References Lime Energy (formerly Electric City Corporation)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Lime Energy (formerly Electric City Corporation) is a company located in Elk Grove Village, Illinois . References ↑ "Lime Energy (formerly Electric City Corporation)" Retrieved from "http://en.openei.org/w/index.php?title=Lime_Energy_formerly_Electric_City_Corporation&oldid=348375"

38

The effect of additives on lime dissolution rates. Final report  

Science Conference Proceedings (OSTI)

Based on the previous years` studies concerning the efficiency of SO{sub 2} removal by spray dryers with high sulfur coal flue gas, the work for year five included investigations of lime dissolution rates at different slaking conditions and with the effect of additives. The prominent additives that have significant effects on lime dissolution rates were tested with the mini pilot spray drying absorber to see their effects on spray drying desulfurization applications. The mechanisms of these additive effects along with the properties of hygroscopic additives have been discussed and incorporated into the spray drying desulfurization model ``SPRAYMOD-M.`` Slaking conditions are very important factors in producing high quality lime slurry in spray drying desulfurization processes. At optimal slaking conditions, the slaked lime particles are very fine (3-5{mu}m) and the slaked lime has high BET surface areas which are beneficial to the desulfurization. The slaked lime dissolution rate experiments in our study are designed to determine how much lime can dissolve in a unit time if the initial lime surface area is kept constant. The purpose of the dissolution rate study for different additives is to find those effective additives that can enhance lime dissolution rates and to investigate the mechanisms of the dissolution rate enhancement properties for these additives. The applications of these additives on spray drying desulfurization are to further verify the theory that dissolution rate is a rate limiting step in the whole spray drying desulfurization process as well as to test the feasibility of these additives on enhancing SO{sub 2} removal in spray dryers.

Khang, S.J.

1996-07-31T23:59:59.000Z

39

Ash Handling System Maintenance Guide  

Science Conference Proceedings (OSTI)

This Ash Handling System Maintenance Guide provides fossil plant maintenance personnel with current maintenance information on this system. This guide will assist plant maintenance personnel in improving the reliability and reducing the maintenance costs for the ash handling system.

2005-12-23T23:59:59.000Z

40

LI I  

Office of Legacy Management (LM)

LI LI I (I LI 1 m r - m " P pr II II I I c - 81-r J-7 . ba OAK RCEIGE MBTSC3NAL liJM!DRAT~F-zY OPERATED OY OPERATED OY MAflTlN MAHlETTA @El&Y ?Z!SEMS, HE. MAflTlN MAHlETTA @El&Y ?Z!SEMS, HE. FOR THE UNfTEfl STATES FOR THE UNfTEfl STATES ORNL/RASA-88/59 RESULTS OF THE RADIOLOGICAL SURVEY AT DIEBOLD SAFE COMPANY, 1550 GRAND BOULEVARD, HAMILTON, OHIO (HOOol) R. D. Foley L. M. Floyd OEPARTMENT Of ENERGY This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Techni- cal Information, P.O. Box 62, Oak Ridge, TN 37831; prices available from (615) 576-840 1, FTS 626-840 1. Available to the public from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Rd. S ringfield, VA 22161.

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

C: LI  

Office of Legacy Management (LM)

C: C: LI c1 T - P- LI m m m c I C F II c( L e3 I 7 ,' r,L .zpl I-' . "* IL.8 -1 p @ z> Cerfification Docket for the Remedid Action Performed at the G ranite City Site in G ranite City, Illinois, June 7993 Department of Energy Former Sites Restoration Division Oak Ridge Operations O ffice September 7994 613 Printed on recycledhcydable paper. 4.1514023.6 .- CERTIFICATION DOCKET FOR THE REMEDIAL ACTION PERFORMED AT THE GRANITE CITY SITE IN GRANITE CITY, ILLINOIS, JUNE 1993 SEPTEMBER 1994 Prepared for UNITED STATES DEPARTMENT OF ENERGY Oak Ridge Operations Office Under Contract No. DE-ACOS-91OR21949 Bechtel National, Inc. Oak Ridge, Tennessee Bechtel Job No. 14501 CONTENTS "I_ FIGURES ............................................. TABLES .............................................

42

L LI LI I I  

Office of Legacy Management (LM)

rA.,/q rA.,/q c - ofrd L LI LI I I c I I I - I I - c c F ORNL/RASA-9413 Results of the Supplementary Radiological Survey at the Former C. H. Schnoor and Company Site, 644 Garfield Street, Springdale, Pennsylvania (CVPOOl) R. L Coleman M. E. Murray IS. S. Brown This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientiic and Techni- cal Information, P.O. Box 62, Oak Ridge, TN 37631; prices available from (615) 576640 1, IT3 626640 1. Available to the public from the National Technical Information Service, U.S. Department of Commerce, 5265 Port Royal Rd., Springfield, VA 22161. 1 I I I This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any

43

Continuing disposal of coal ash  

Science Conference Proceedings (OSTI)

The large volume of power-plant coal ash produced and stricter Federal water pollution controls are making ash disposal increasingly difficult for utilities. The protection of surface and ground water quality required in the Resource conservation and Recovery Act of 1976 (RCRA) and the Federal Water Pollution Control Act's Clean Water Act (CWA) amendments of 1977 have raised the cost of disposal to a level where an acceptable method must be found. The Electric Power Research Institute's Coal Ash Disposal Manual (EPRI-FM--1257) describes-ash chemistry, disposal site selection, site monitoring and reclamation, and other information of interest to utilities that are making cost estimates and procedure evaluations. (DCK)

Lihach, N.; Golden, D.

1980-03-01T23:59:59.000Z

44

Comparison between MSW Ash and RDF Ash from Incineration Process  

E-Print Network (OSTI)

, the unwashed incineration ash were tested and analyzed for TCLP (Toxicity Characteristic Leaching Procedure of auxiliary air. The flue gases are PEER-REVIEW 963 #12;eventually led through air pollution control system to prevent visible flue gas emissions due to higher moisture content. TCLP ANALYSIS Samples of fly ash

Columbia University

45

Operational Implications of Airborne Volcanic Ash  

Science Conference Proceedings (OSTI)

Volcanic ash clouds pose a real threat to aircraft safety. The ash is abrasive and capable of causing serious damage to aircraft engines, control surfaces, windshields, and landing lights. In addition, ash can clog the pitot—static systems, which ...

Gary L. Hufford; Leonard J. Salinas; James J. Simpson; Elliott G. Barske; David C. Pieri

2000-04-01T23:59:59.000Z

46

Incineration and incinerator ash processing  

Science Conference Proceedings (OSTI)

Parallel small-scale studies on the dissolution and anion exchange recovery of plutonium from Rocky Flats Plant incinerator ash were conducted at the Los Alamos National Laboratory and at the Rocky Flats Plant. Results from these two studies are discussed in context with incinerator design considerations that might help to mitigate ash processing related problems. 11 refs., 1 fig., 1 tab.

Blum, T.W.

1991-01-01T23:59:59.000Z

47

Coal Ash Carbon Removal Technologies  

Science Conference Proceedings (OSTI)

Market resistance to the use of ash containing elevated levels of carbon and/or ammonia has become a major concern for coal-fired facilities in recent years as a result of increased use of nitrogen oxide (NOx) reduction environmental control technologies. EPRI initiated this state of practice assessment to help power producers evaluate alternatives for ash beneficiation.

2001-11-01T23:59:59.000Z

48

Prickly Ash and Prickly Pear  

NLE Websites -- All DOE Office Websites (Extended Search)

Prickly Ash and Prickly Pear Prickly Ash and Prickly Pear Nature Bulletin No. 649-A October 1, 1977 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation PRICKLY ASH AND PRICKLY PEAR In the plant kingdom, as among people, there are so-me that we avoid. They have few virtues, if any, and our experiences with them are painful or have unpleasant after effects. Poison ivy is a notorious example. Prickly Ash, a shrub, is another. Although not poisonous it is thickly armed with wicked thorns and has no ornamental, economic or wildlife value. In 1821 when the first section lines were established in Cook County, the surveyor recorded -- for the benefit of land buyers -- the principal kinds of trees and other vegetation observed along each mile. He frequently encountered prickly ash in thickets near the Little Calumet River and also the north and south branches of the Chicago River.

49

Wood Residues as Fuel Source for Lime Kilns  

E-Print Network (OSTI)

One of the main obstacles to total energy self sufficiency of kraft mills appears to be the fossil fuel requirements of the lime kilns. If an economical technology can be developed which allows fossil fuel to be replaced in whole or in part by wood-based fuel, the savings in fossil fuel by the pulp and paper industry would be very substantial. Our study focuses around the direct in-situ combustion of hog fuel fed from the cold feed end in order to substantially reduce the fossil fuel fired from the hot product discharge end of the lime kiln. Thus far we have carried out two series of tests using two different pilot-scale kilns and dry limestone in the first test series and mill produced lime mud in the second test series. Mill scale trials have just been completed and the preliminary results indicate that our approach is potentially a very cost-effective and simple option to substantially reduce or possibly eliminate fossil-fuel usage in lime kilns.

Azarniouch, M. K.; Philp, R. J.

1984-01-01T23:59:59.000Z

50

Kinetic Modeling and Assessment of Lime Pretreatment of Poplar Wood  

E-Print Network (OSTI)

Because of widespread availability, low cost, sustainability, and potential supply far greater than that of food crops, lignocellulosic biomass is one of the most promising feedstocks for producing biofuels through fermentation processes. Among lignocellulose choices, poplar wood is appealing because of high energy potential, above-average carbon mitigation potential, fast growth, and high yields. Lignocellulose structural features limit accessibility of enzymes or microorganisms. To overcome these limitations, pretreatment is required. Among several choices of pretreatment, lime pretreatment is preferred because lime is the cheapest alkali, safest to handle, easy to recover, and compatible with oxidants. The main effect of lime pretreatment is to degrade lignin, which occurs with good carbohydrate preservation and is enhanced with oxidants. Among several choices of oxidant, oxygen and air are preferred because of low cost and widespread availability. This study systematically assesses the effects of lime pretreatment on poplar wood using four different modes: long-term oxidative, long-term non-oxidative, short-term constant pressure, and short-term varying pressure. Long-term pretreatments use temperatures between 25 and 65° C, air if oxidant is used, and last several weeks. Short-term pretreatments use temperatures between 110 and 180° C, pressurized oxygen, and last several minutes to hours. Pretreatment was assessed on the basis of 3-day enzymatic digestibility using enzyme loadings of 15 FPU/g glucan in raw biomass. The results were used to recommend pretreatment conditions based on highest overall yield of glucan (after combined pretreatment and enzymatic hydrolysis) for each pretreatment mode. For each pretreatment mode, kinetic models for delignification and carbohydrates degradation were obtained and used to determine the conditions (temperature, pressure, and time) that maximize glucan preservation subjected to a target lignin yield. This study led to conclude that the most robust, and selective mode of lime pretreatment is varying pressure.

Sierra Ramirez, Rocio

2010-12-01T23:59:59.000Z

51

Insurance coverage for coal ash liabilities  

Science Conference Proceedings (OSTI)

The paper discusses how liability insurance can be a valuable tool for limiting coal ash liabilities.

Elkind, D.L. [Dickstein Shapiro LLP (United States)

2009-07-01T23:59:59.000Z

52

Ash Deposit Physical and Chemical Analysis  

Science Conference Proceedings (OSTI)

This report focuses on identifying ash deposit materials and mounting them to a heat transfer surface for further study. A group of synthetic slag of various compositions was also produced using a sodium silicate binder, Powder River Basin (PRB) bottom ash, and ash cenospheres for porosity to test the effects of pulse detonation techniques on the removal of ash deposits.

2010-12-17T23:59:59.000Z

53

Integrated Fly Ash Pond Management  

Science Conference Proceedings (OSTI)

This report is directed toward solving new challenges to meeting U.S. Environmental Protection Agency (USEPA) National Pollutant Discharge Elimination System (NPDES) discharge limits for ammonia and selected metals from coal-fired power plants. Based on the field and laboratory study of fly ash ponds at five operating coal-fired power plants, the physical, chemical, and biological processes that occur in fly ash sluicing systems are discussed and recommendations are made as to how to best manage the pond...

2009-11-24T23:59:59.000Z

54

Genetic Transformation and Regeneration of Green Ash (Fraxinus pennsylvanica) for Resistance to the Emerald Ash Borer  

E-Print Network (OSTI)

bats, tool handles, furniture, and firewood. However, the emerald ash borer (EAB) (Agrilus planipennis) develop an efficient regeneration and genetic transformation system for green ash, (2) regenerateGenetic Transformation and Regeneration of Green Ash (Fraxinus pennsylvanica) for Resistance

55

Long duration ash probe  

DOE Patents (OSTI)

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

1994-01-01T23:59:59.000Z

56

LOW VELOCITY SHPERE IMPACT OF SODA LIME SILICATE GLASS  

Science Conference Proceedings (OSTI)

This report summarizes TARDEC-sponsored work at Oak Ridge National Laboratory (ORNL) during the FY11 involving low velocity ( 30 m/s or 65 mph) ball impact testing of Starphire soda lime silicate glass. The intent was to better understand low velocity impact response in the Starphire for sphere densities that bracketed that of rock. Five sphere materials were used: borosilicate glass, soda-lime silicate glass, steel, silicon nitride, and alumina. A gas gun was fabricated to produce controlled velocity delivery of the spheres against Starphire tile targets. Minimum impact velocities to initiate fracture in the Starphire were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the any of the five sphere-Starphire-target combinations.

Morrissey, Timothy G [ORNL; Fox, Ethan E [ORNL; Wereszczak, Andrew A [ORNL; Vuono, Daniel J [ORNL

2012-01-01T23:59:59.000Z

57

Lime pretreatment and enzymatic hydrolysis of corn stover  

E-Print Network (OSTI)

Renewable energy sources, such as lignocellulosic biomass, are environmentally friendly because they emit less pollution without contributing net carbon dioxide to the atmosphere. Among lignocellulosic biomass, corn stover is a very useful feedstock to economically produce environmentally friendly biofuels. Corn stover was pretreated with an excess of calcium hydroxide (0.5 g Ca(OH)2/g raw biomass) in non-oxidative and oxidative conditions at 25, 35, 45, and 55oC. The optimal condition is 55oC for 4 weeks with aeration, determined by yields of glucan and xylan. The overall yields of glucose (g glucan hydrolyzed/100 g original glucan) and xylose (g xylan hydrolyzed/100 g original xylan) were 91.3 and 51.8 at 15 FPU/g cellulose, respectively. Furthermore, when considering the dissolved fragments of glucan and xylan in the pretreatment liquors, the overall yields of glucose and xylose were 93.2 and 79.5 at 15 FPU/g cellulose, respectively. The pretreatment liquor has no inhibitory effect on ethanol fermentation using Saccharomyces cerevisiae D5A. At the recommended condition, only 0.073 g Ca(OH)2 was consumed per g of raw corn stover. Under extensive delignification conditions, 87.5% of the initial lignin was removed. Extensive delignfication required oxidative treatment and additional lime consumption. Deacetylation quickly reached a plateau within 1 week. Delignification highly depended on temperature and the presence of oxygen. Lignin and hemicellulose were selectively removed, but cellulose was not affected by lime pretreatment in mild temperatures (25 ?? 55oC). The delignification kinetic models of corn stover were empirically determined by three simultaneous first-order reactions. The activation energies for the oxidative delignification were estimated as 50.15 and 54.21 kJ/mol in the bulk and residual phases, respectively. Crystallinity slightly increased with delignification because amorphous components (lignin, hemicellulose) were removed. However, the increased crystallinity did not negatively affect the 3-d sugar yield of enzyme hydrolysis. Oxidative lime pretreatment lowered the acetyl and lignin contents to obtain high digestibility, regardless of crystallinity. The enzymatic digestibility of lime-treated biomass was affected by the change of structural features (acetylation, lignification, and crystallization) resulting from the treatment. The non-linear models for 3-d hydrolysis yields of glucan and xylan were empirically established as a function of the residual lignin fraction for the corn stover pretreated with lime and air.

Kim, Se Hoon

2003-05-01T23:59:59.000Z

58

Development of fly ash-based slope protection materials for waste disposal ponds. Topical report, Task 7.7  

Science Conference Proceedings (OSTI)

A research project was conducted to develop a cost-effective slope protection material for a 100-acre scrubber sludge disposal pond located at the Sherco power plant. The technical objective of the project was to formulate and evaluate the performance of a slope protection material produced using self-cementing coal combustion by-products. The material was to have sufficient durability and erosion resistance to protect the underlying bottom ash fill and clay liner from wave erosion for at least 5 years when it was placed on the interior side slopes of the pond. The two coal combustion by-products that were considered for use in the slope protection material were 1) a spray dryer waste and 2) a subbituminous coal fly ash. The spray dryer waste was approximately a 50:50 mixture of subbituminous coal fly ash and reacted, lime-based scrubber sorbent. The subbituminous coal fly ash was produced from a cyclone-fired boiler. Both by-products displayed self-cementing behavior when mixed with water. The results of the field tests indicated that a slope protection slab prepared from Sherco spray dryer waste placed with a 20% moisture content showed almost no deterioration after 20 months in the field. A slab prepared from a mixture of 25% Riverside fly ash and 75% bottom ash with a moisture content of 18% showed a slight loss of material from the surface of the slab, but no substantial deterioration after 20 months in the field. Two other materials containing Riverside fly ash that were prepared with higher moisture contents showed somewhat more deterioration after 20 months, although none of the field test slabs appeared to have failed in that time period.

Moretti, C.J.

1993-02-01T23:59:59.000Z

59

Revegetation of an Acid Mine Drainage - Impacted Soil Using Low Rates of Lime and Compost.  

E-Print Network (OSTI)

??AbstractA study was designed to determine whether a degraded soil overlain by acid mine drainage (AMD) precipitates could be remediated with low rates of lime… (more)

Lupton, Mary Kay

2008-01-01T23:59:59.000Z

60

Fly ash utilization in McLean County, North Dakota. Topical report, Task 7.25  

SciTech Connect

In 1989, the McLean County Commissioners requested assistance from personnel at the University of North Dakota Energy and Environmental Research Center (EERC) with the construction of a section of road and a boat ramp in their county. Assistance was sought from the EERC because the county`s construction plans called for partial replacement of the lime and portland cement normally used for soil stabilization with fly ash. Since the EERC had recently conducted several research projects dealing with the use of coal combustion by-products for road construction, the commissioners requested that EERC personnel help to determine appropriate formulas for the stabilized soil mixtures to be used for both the road and boat ramp applications. An additional incentive was provided when the management of the Coal Creek Power Plant offered to donate the necessary fly ash at no cost. This project was performed as a joint venture between McLean County and the EERC. The EERC was primarily responsible for conducting a laboratory testing program to develop soil stabilization mixtures for the two construction activities. These mixtures were to contain a relatively high percentage of fly ash and to exhibit sufficient strength and durability so that the road and boat ramp would both have a service life of 20 years or more. McLean County would be primarily responsible for the road and boat ramp construction activities. The funding for the EERC portion of the project was provided by the US Department of Energy through a joint venture support program.

Moretti, C.J.

1993-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Water Management in Ash-Handling Systems  

Science Conference Proceedings (OSTI)

In 1980, EPA proposed revisions to the effluent standards and guidelines for fly ash and bottom ash transport systems. This review of utility practices provides a comprehensive account of the operation of and problems experienced in wet handling of bottom and fly ash and suggests areas for further research.

1987-08-24T23:59:59.000Z

62

Bottom Ash System Maintenance Guide  

Science Conference Proceedings (OSTI)

This guide provides information to personnel involved in the bottom ash system and its components, including good maintenance practices, condition monitoring, predictive and preventive maintenance techniques, probable failure modes, and troubleshooting guidance. The guide was developed primarily to provide detailed maintenance and troubleshooting information but also includes basic system information.

2000-10-31T23:59:59.000Z

63

Abstract for Yingchuan Li  

NLE Websites -- All DOE Office Websites (Extended Search)

Yingchuan Li University of Wisconsin-Madison Electroweak Baryogenesis in MSSM and Electric Dipole Moment Constraints Among all the baryogenesis mechanisms, electroweak baryogenesis...

64

Li-Z  

NLE Websites -- All DOE Office Websites (Extended Search)

and Top-of-the-Atmosphere from Modeling and Observations Z. Li and A. Trishchenko Canada Centre for Remote Sensing Ottawa, Ontario, Canada M. Cribb Intermap Technologies Ltd....

65

Long-term lime pretreatment of poplar wood  

E-Print Network (OSTI)

Lignocellulosic biomass (e.g., poplar wood) provides a unique and sustainable resource for environmentally safe organic fuels and chemicals. The core of this study is the pretreatment step involved in bioconversion processes. Pretreatment is required to realize high yields vital to commercial success. The focus of the pretreatment step is to methodically change key features of the biomass to favor enzymatic hydrolysis. This work assesses the compositional changes due to oxidative and non-oxidative longterm lime pretreatment of poplar wood (up to 4 weeks of pretreatment) at mild temperatures (25ºC to 65ºC), and their effect on the enzymatic yield of glucan and xylan. The most important pretreatment yield of lignin was 54 g lignin remaining/100 g lignin in raw biomass, and was accomplished for 4-week lime pretreatment at 65ºC in oxidative conditions. The corresponding pretreatment yields of glucan and xylan were 85.9 g glucan recovered/100 g glucan in raw biomass and 80.2 g xylan recovered/100 g xylan in raw biomass respectively. For poplar wood oxidatively pretreated with lime for 4 weeks at 65ºC and enzymatically hydrolyzed with an enzyme loading of 15 FPU/g glucan in raw biomass during a 3-day period, the best overall yields of glucan and xylan, were 80.7 g glucan hydrolyzed/100 g glucan in raw biomass and 66.9 g xylan hydrolyzed/100 g xylan in raw biomass respectively. The corresponding hydrolysis yields were 94.0 g glucan hydrolyzed/100 g glucan in treated biomass and 83.5 g xylan hydrolyzed/100 g xylan in treated biomass respectively. Because there is a previous study of long-term lime pretreatment of corn stover (Kim, 2004), the data obtained in this work show the effect of using woody lignocellulose as substrate. From the comparison, resulted that in the case of poplar wood oxidatively pretreated at 65ºC for 4 weeks, less lignin was removed and more carbohydrates were solubilized, however the hydrolysis yield of glucan was almost equal and the hydrolysis yield of xylan was higher than the reported by Kim for corn stover oxidatively pretreated at 55ºC for 4 weeks. The overall yield of glucan resulted lower in the case of poplar wood because of the lower pretreatment yield of glucan. Thus, it is important to complete the mass balances including an analysis on the pretreatment liquor to determine if the solubilized glucan was degraded.

Sierra Ramirez, Rocio

2005-12-01T23:59:59.000Z

66

Neutron spectroscopic factors of 7Li and astrophysical 6Li(n,g)7Li reaction rates  

E-Print Network (OSTI)

Angular distributions of the 7Li(6Li,6Li)7Li elastic scattering and the 7Li(6Li,7Li_{g.s.})6Li, 7Li(6Li,7Li*_{0.48})6Li transfer reactions at Ec.m. = 23.7 MeV were measured with the Q3D magnetic spectrograph. The optical potential of 6Li+7Li was obtained by fitting the elastic scattering differential cross sections. Based on the distorted wave Born approximation (DWBA) analysis, spectroscopic factors of 7Li=6Li+n were determined to be 0.73 +- 0.05 and 0.90 +- 0.09 for the ground and first exited states in 7Li, respectively. Using the spectroscopic factors, the cross sections of the 6Li(n,g)7Li direct neutron capture reactions and the astrophysical 6Li(n,g)7Li reaction rates were derived.

Jun Su; Zhihong Li; Bing Guo; Xixiang Bai; Zhichang Li; Jiancheng Liu; Youbao Wang; Gang Lian; Sheng Zeng; Baoxiang Wang; Shengquan Yan; Yunju Li; Ertao Li; Qiwen Fan; Weiping Liu

2010-01-25T23:59:59.000Z

67

LIME: A coordination model and middleware supporting mobility of hosts and agents  

Science Conference Proceedings (OSTI)

LIME (Linda in a mobile environment) is a model and middleware supporting the development of applications that exhibit the physical mobility of hosts, logical mobility of agents, or both. LIME adopts a coordination perspective inspired by work on the ... Keywords: Mobile computing, middleware, tuple spaces

Amy L. Murphy; Gian Pietro Picco; Gruia-Catalin Roman

2006-07-01T23:59:59.000Z

68

Cement Additives from Fly Ash Opportunity  

NLE Websites -- All DOE Office Websites (Extended Search)

Device and Method for Separating Minerals, Carbon and Device and Method for Separating Minerals, Carbon and Cement Additives from Fly Ash Opportunity Research is currently active on the patented technology "Device and Method for Separating Minerals, Carbon, and Cement Additives from Fly Ash." The technology is available for licensing and/or further collaborative research from the U.S. Depart- ment of Energy's National Energy Technology Laboratory (NETL). Overview This invention includes a device, along with a method, to recover and use fly ash as a source of high purity carbon, ash, and minerals. The device and associated method can isolate components of the fly ash based on size and electrical charge. By improving beneficiation and usage methods, fly ash can be transformed from a waste material to a valuable by-product. Recent shifts to low nitrogen

69

Low Velocity Sphere Impact of a Soda Lime Silicate Glass  

SciTech Connect

This report summarizes TARDEC-sponsored work at Oak Ridge National Laboratory (ORNL) during the FY11 involving low velocity (< 30 m/s or < 65 mph) ball impact testing of Starphire soda lime silicate glass. The intent was to better understand low velocity impact response in the Starphire for sphere densities that bracketed that of rock. Five sphere materials were used: borosilicate glass, soda-lime silicate glass, steel, silicon nitride, and alumina. A gas gun was fabricated to produce controlled velocity delivery of the spheres against Starphire tile targets. Minimum impact velocities to initiate fracture in the Starphire were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the any of the five sphere-Starphire-target combinations. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) Frictional effects contribute to fracture initiation. (2) Spheres with a lower elastic modulus require less force to initiate fracture in the Starphire than spheres with a higher elastic modulus. (3) Contact-induced fracture did not initiate in the Starphire SLS for impact kinetic energies < 150 mJ. Fracture sometimes initiated or kinetic energies between {approx} 150-1100 mJ; however, it tended to occur when lower elastic modulus spheres were impacting it. Contact-induced fracture would always occur for impact energies > 1100 mJ. (4) The force necessary to initiate contact-induced fracture is higher under dynamic or impact conditions than it is under quasi-static indentation conditions. (5) Among the five used sphere materials, silicon nitride was the closest match to 'rock' in terms of both density and (probably) elastic modulus.

Wereszczak, Andrew A [ORNL; Fox, Ethan E [ORNL; Morrissey, Timothy G [ORNL; Vuono, Daniel J [ORNL

2011-10-01T23:59:59.000Z

70

Compositional Analysis of Beneficiated Fly Ashes  

Science Conference Proceedings (OSTI)

... Fly ash is a byproduct of combustion of coal in coal-fired powerplants through ... to be disposed of at a significant cost to power plant companies, and ...

1997-09-03T23:59:59.000Z

71

Treatment of fly ash for use in concrete  

DOE Patents (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT)

2012-05-15T23:59:59.000Z

72

Use of Class C Fly Ash in High-Volume Fly Ash Concrete Applications  

Science Conference Proceedings (OSTI)

Although the use of fly ash in concrete is a well-established practice, the volume of high-calcium Class C ash used lags behind that of low-calcium Class F ash. Because Class C may be the only type of ash produced in some western states, this disparity can significantly limit its use potential. The literature results presented in this report represent the first phase of a longer term research effort to provide technical information supporting the increased use of Class C ash in concrete applications.

2007-09-24T23:59:59.000Z

73

A Laboratory Study of Hydrated Lime Properties in Dilute Phase Conveyance  

Science Conference Proceedings (OSTI)

Recent regulatory actions are reducing allowable emissions of sulfur trioxide (SO3) from coal-fired power plants. Therefore, the need to economically and reliably remove SO3 from flue gas streams is taking on additional urgency. Three sorbents are commonly used for SO3 removal151hydrated lime, trisodium hydrogendicarbonate dihydrate (trona), and sodium bisulfate. Hydrated lime has been shown to be an economical choice; however, dilute phase conveyance from storage hoppers to duct injection lances has bee...

2010-12-31T23:59:59.000Z

74

Recovery Act Workers Complete Environmental Cleanup of Coal Ash...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Complete Environmental Cleanup of Coal Ash Basin Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin The Savannah River Site (SRS) recently cleaned up a 17-acre...

75

Recovery Act Workers Complete Environmental Cleanup of Coal Ash...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Workers Complete Environmental Cleanup of Coal Ash Basin Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin The Savannah River Site (SRS) recently cleaned up a...

76

An introduction to LIME 1.0 and its use in coupling codes for multiphysics simulations.  

Science Conference Proceedings (OSTI)

LIME is a small software package for creating multiphysics simulation codes. The name was formed as an acronym denoting 'Lightweight Integrating Multiphysics Environment for coupling codes.' LIME is intended to be especially useful when separate computer codes (which may be written in any standard computer language) already exist to solve different parts of a multiphysics problem. LIME provides the key high-level software (written in C++), a well defined approach (with example templates), and interface requirements to enable the assembly of multiple physics codes into a single coupled-multiphysics simulation code. In this report we introduce important software design characteristics of LIME, describe key components of a typical multiphysics application that might be created using LIME, and provide basic examples of its use - including the customized software that must be written by a user. We also describe the types of modifications that may be needed to individual physics codes in order for them to be incorporated into a LIME-based multiphysics application.

Belcourt, Noel; Pawlowski, Roger Patrick; Schmidt, Rodney Cannon; Hooper, Russell Warren

2011-11-01T23:59:59.000Z

77

Treatment of fly ash for use in concrete  

DOE Patents (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT); Akash, Akash (Salt lake City, UT); Zhao, Qiang (Natick, MA)

2012-05-08T23:59:59.000Z

78

Treatment of fly ash for use in concrete  

DOE Patents (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett; Akash, Akash; Zhao, Qiang

2013-01-08T23:59:59.000Z

79

C LI CI  

Office of Legacy Management (LM)

LI LI CI - - 11 C LI I I Mb II II OAK RIDGE NATIONAL LABORATORY UPERml BY M A R T IN M A R IETTA ENERGY S Y S T E M S , INC. FOR THE UNfTEG STATES OEPARTMENT OF ENERGY ORNLITM-10007 RADIOLOGICAL SURVEY OF THE PERIMETER FENCE LINE OF THE FORMER COTTER SITE, HAZELWOOD, M ISSOURI (LM002) R. F. Carrier W . D. Cottrell FILE COPY This report was prepared as an account of work sponsored by an agency of the UnitedStatesGovernment. NeithertheUnitedStatesGovernment noranyagency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein

80

SODIUM POLYPHOSPHATE-MODIFIED CLASS C/CLASS F FLY ASH BLEND CEMENTS FOR GEOTHERMAL WELLS.  

DOE Green Energy (OSTI)

The authors investigated the usefulness of the coal combustion by-products, Class C fly ash (C) and Class F fly ash (F), in developing cost-effective acid-resistant phosphate-based cements for geothermal wells. In the temperature range of 20-100 C, sodium polyphosphate (NaP) as the acidic cement-forming solution preferentially reacted with calcium sulfate and lime in the C as the base solid reactant through the exothermic acid-base reaction route, rather than with the tricalcium aluminate in C. This reaction led to the formation of hydroxyapatite (HOAp). In contrast, there was no acid-base reaction between the F as the acidic solid reactant and NaP. After autoclaving the cements at 250 C, a well-crystallized HOAp phase was formed in the NaP-modified C cement that was responsible for densifying the cement's structure, thereby conferring low water permeability and good compressive strength on the cement. however, the HOAp was susceptible to hot CO{sub 2}-laden H{sub 2}SO{sub 4} solution (pH 1.1), allowing some acid erosion of the cement. On the other hand, the mullite in F hydrothermally reacted with the Na from NaP to form the analcime phase. Although this phase played a pivotal role in abating acid erosion, its generation created an undesirable porous structure in the cement. They demonstrated that blending fly ash with a C/F ratio of 70/30 resulted in the most suitable properties for acid-resistant phosphate-based cement systems.

SUGAMA, T.; BROTHERS, L.E.; KASPEREIT, D.

2006-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The effect of hydrated lime on Salmonella enteritidis survival in poultry litter and poult performance  

E-Print Network (OSTI)

The presence of Salmonella and/or Campylobacter in poultry litter may contribute to contaminated processed carcasses. Initially in our first study, we evaluated the effect of 5, 10, or 20% added lime on in vitro survival of Salmonella enteritidis in used poultry litter during incubations of 24, 48, or 96 h. In experiment one, addition of lime at any concentration reduced Salmonella recovery from artificially-contaminated litter by more than 1.79 log 10 cfu to undetectable levels based on direct plating within 24 h. In experiment 2, litter was experimentally inoculated with 10? cfu/g Salmonella enteritidis and 5g samples were pH-corrected to neutral prior to tetrathionate enrichment (24 h) and BGA plating (24 h) for detection of positive or negative samples. At 24 or 48 h, 10/10 (100%) of untreated (control) litter samples were positive for Salmonella. Addition of lime resulted in significantly reduced Salmonella recovery incidence at 24 h. These data suggest that the addition of hydrated lime can markedly reduce Salmonella recovery in a relatively short time (<24 h) period. In the second study, the effect of blending hydrated lime (0, .2, 1, or 5% wt/v) into new wood shavings prior to poult placement on poult growth and recovery of Salmonella, Campylobacter, coliforms, total aerobic cfu at 21 or 49 d was evaluated in 2 experiments. A third experiment evaluated the effect of pre-placement lime treatment of litter of one of two similar turkey brooder houses, on the same premise and under commercial contract, on these parameters at 21 or 35 days-of-age. Although pre-placement treatment of litter with lime significantly increased recovery of Salmonella from the litter during poult growth in 1 of 3 experiments, this effect was not consistent. Lime treatment did not affect coliform recovery in any experiment, but caused a very small but significant reduction in recoverable aerobic cfu in 2 experiments. Treatment of litter with one concentration of lime caused significantly increased body weights in 2 of three experiments, suggesting a beneficial effect of lime treatment of litter on turkey growth during this period.

Stanush, Deborah Denise

2000-01-01T23:59:59.000Z

82

Yan Li | BNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Yan Li Yan Li Assistant Computational Scientist Education Ph.D., Physics, University of Illinois at Urbana-Champaign B.S. Physics, Peking University, China Professional Affiliations American Physical Society (APS) American Chemical Society (ACS) Areas of Interest First-principles simulations of nanostructures, surface and interfaces Optical and excited state properties of materials Weak interactions in organic self-assemblies, molecular crystals and biomaterials Multilevel computational modeling of large and complex systems Experience 2011 -present, Assistant Computational Scientist, Computational Science Center, Brookhaven National Lab 2010 - 2011, Research Associate, Computational Science Center, Brookhaven National Lab 2006 - 2010, Postdoctoral Researcher, University of California,

83

Rocky Flats ash test procedure (sludge stabilization)  

SciTech Connect

Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. This test will also gain information on the effects of the glovebox atmosphere (moisture) on the stabilized material. This document provides instructions for testing Rocky Flats Ash in the HC-21C muffle furnace process.

Winstead, M.L.

1995-09-14T23:59:59.000Z

84

Fusibility and sintering characteristics of ash  

Science Conference Proceedings (OSTI)

The temperature characteristics of ash fusibility are studied for a wide range of bituminous and brown coals, lignites, and shales with ratios R{sub B/A} of their alkaline and acid components between 0.03 and 4. Acritical value of R{sub B/A} is found at which the fusion temperatures are minimal. The sintering properties of the ashes are determined by measuring the force required to fracture a cylindrical sample. It is found that the strength of the samples increases sharply at certain temperatures. The alkali metal content of the ashes has a strong effect on their sintering characteristics.

Ots, A. A., E-mail: aots@sti.ttu.ee [Tallinn University of Technology (Estonia)

2012-03-15T23:59:59.000Z

85

I!' L;I)  

Office of Legacy Management (LM)

".>;jy i.jp. i,Zz>-c C,+;) ir,i:%J :' 0 p 'd-i I ) f) ic.c iq -.I ,'c i - * w. 3'2 , phi ': r-t;, ; *.i .; I' L;I) --, -II s;.,yE;J-,;* I' ;, f: >,p.yg ,p ' .L (3 i>;'...

86

Investigation of Ammonia Adsorption on Fly Ash and Potential Impacts of Ammoniated Ash  

Science Conference Proceedings (OSTI)

Problems associated with ammoniated fly ash have become a major concern for coal-fired facilities in recent years due to the increased use of ammonia-based environmental control technologies. Of particular note is more frequent use of ammonia-based NOx control systems and electrostatic precipitator (ESP) conditioning with ammonia. To help power producers evaluate and mitigate the impacts of ammoniated ash, this project provides crucial information in the areas of fly ash characterization, adsorption test...

1999-12-10T23:59:59.000Z

87

Sugarcane juice extraction and preservation, and long-term lime pretreatment of bagasse  

E-Print Network (OSTI)

New technologies, such as an efficient vapor-compression evaporator, a stationary lime kiln (SLK), and the MixAlco process, compelled us to re-evaluate methods for producing sugar from cane. These technologies allow more water and lime to be used, and they add more value to bagasse. Extracting and preserving the sugars, and lime pretreating the bagasse to enhance biodigestibility, all at the same time in a pile, was demonstrated to be unfeasible; therefore, sugar extraction must occur before lime treating the bagasse. Sugar extraction should occur countercurrently by lixiviation, where liquid moves in stages opposite to the soaked bagasse (megasse), which is conveyed by screw-press conveyors that gently squeeze the fiber in each stage, improving extraction. The performance of a pilot-scale screw-press conveyor was tested for dewatering capabilities and power consumption. The unoptimized equipment decreased megasse moisture from 96 to 89%. Simulation of the process suggested that eight stages are necessary to achieve 98% recovery from typical sugarcane. The cumulative power for the screw-press conveyor system was 17.0±2.1 hp?h/ton dry fiber. Thin raw juice preserved with lime for several months showed no sucrose degradation and no quality deterioration, except for reducing sugar destruction. The lime loading needed for 1-year preservation is 0.20 g Ca(OH)2/g sucrose. Shorter times require less lime. After preservation, the juice was carbonated and filtered, and the resulting sludge pelletized. Due to their high organic content, the pellets were too weak for calcination temperatures used in the SLK. The organics must be decreased prior to pelletization and sodium must be supplemented as a binding agent. Long-term lime pretreatment of bagasse showed two delignification phases: bulk (rapid) and residual (slow). These were modeled by two simultaneous first-order reactions. Treatments with air purging and higher temperatures (50 ? 57oC) delignified more effectively, especially during the residual phase, thus yielding higher cellulase-enzyme digestibilities after 2 ? 8 weeks of treatment. At temperatures > 60oC, pure oxygen purging is preferred. Fresh bagasse was of better quality than old bagasse. Treatment with NaOH yielded a larger bulk delignification phase than Ca(OH)2. Long-term lime pulping of bagasse was unsuitable for copy-quality paper, but it was appropriate for strawboard and other filler applications.

Granda Cotlear, Cesar Benigno

2004-12-01T23:59:59.000Z

88

Proceedings: Tenth International Ash Use Symposium, Volume 2: Ash Use R&D and Clean Coal By-Products  

Science Conference Proceedings (OSTI)

Topics discussed at the tenth symposium on coal ash use included fundamental ash use research, product marketing, applied research, ash management and the environment, and commercial applications. Intense international research interest continues in coal ash use due to the prospects of avoiding disposal costs and generating revenue from by-product sales.

1993-01-22T23:59:59.000Z

89

Validation of the new mixture design and testing protocol for lime stabilization  

E-Print Network (OSTI)

The Mississippi Department of Transportation (MDOT) has used hydrated lime for over 30 years to stabilize subgrades. In 1998 a project was initiated to assess material properties and performance derived from lime treated subgrades (LTS). This thesis describes some pertinent findings of the study. In situ properties of lime stabilized subgrades are identified based on Falling Weight Deflectometer (FWD) deflection measurements, Ground Penetration Radar (GPR) profiles, and Dynamic Cone Penetrometer (DCP) logs. The in situ properties are compared to laboratory strength and resilient modulus test results for the same materials to establish reliable design resilient and strength properties for these stabilized layers. A laboratory mixture design and testing protocol is presented for lime stabilized subgrades. Comparison of field test data and laboratory test data shows that laboratory design test properties were achieved in the field. These properties are used in a mechanistic analysis to assess the effectiveness of the lime stabilized subgrades in Mississippi. The LTS layers in the four pavements evaluated, are effective structural layers.

Yusuf, Fateh Ul Anam Muhammad Shafee

2001-01-01T23:59:59.000Z

90

Case Studies in Ash Pond Management, Volume 2  

Science Conference Proceedings (OSTI)

"Toward Developing Integrated Strategies for Managing Multiple Constituents in Ash Pond Discharges," EPRI's second workshop on Ash Pond Management, was hosted by TVA on May 16, 2006, in Chattanooga, Tennessee. The presentations in this workshop reflected specific research challenges identified by participants in the first Ash Pond Management workshop, held in 2004. Among the presentations given in this second workshop were the following: Ash Pond Limnology Optimizing Ash Pond Treatment of Ammonia Predic...

2007-03-26T23:59:59.000Z

91

Fluidized bed gasification ash reduction and removal process  

DOE Patents (OSTI)

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-12-04T23:59:59.000Z

92

Fluidized bed gasification ash reduction and removal system  

DOE Patents (OSTI)

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-02-28T23:59:59.000Z

93

Winter'04Ash4-5  

NLE Websites -- All DOE Office Websites (Extended Search)

process, fly ash is used as a raw material to substitute for part of the clay and shale, which are the two main raw materials of a conventional brick. Test bricks produced...

94

The 1983 Ash Wednesday Fires in Australia  

Science Conference Proceedings (OSTI)

Australia experienced the most disastrous bushfires in over 40 years on Ash Wednesday, 16 February 1983. This article describes the meteorological conditions prior to, during and after these fires, and includes photographs from GMS-2. It also ...

M. E. Voice; F. J. Gauntlett

1984-03-01T23:59:59.000Z

95

Coal Ash Contaminants in Wetlands | SREL Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracey Tuberville, and Bill Hopkins The ash plume wetland (APW). The APW received coal combustion wastes from a breach in a receiving basin in the 1970s. Several trace metals...

96

Airborne Volcanic Ash Forecast Area Reliability  

Science Conference Proceedings (OSTI)

In support of aircraft flight safety operations, daily comparisons between modeled, hypothetical, volcanic ash plumes calculated with meteorological forecasts and analyses were made over a 1.5-yr period. The Hybrid Single-Particle Lagrangian ...

Barbara J. B. Stunder; Jerome L. Heffter; Roland R. Draxler

2007-10-01T23:59:59.000Z

97

Ashe County- Wind Energy System Ordinance  

Energy.gov (U.S. Department of Energy (DOE))

In 2007 Ashe County adopted a wind ordinance to regulate the use of wind-energy systems in unincorporated areas of the county and to describe the conditions by which a permit for installing such a...

98

NETL: Events - World of Coal Ash 2007  

NLE Websites -- All DOE Office Websites (Extended Search)

(WOCA) 2007 conference, jointly sponsored by the American Coal Ash Association and the University of Kentucky Center for Applied Energy Research, will be held May 7-10, 2007 at...

99

Carbon-in-Ash Monitor Demonstration  

Science Conference Proceedings (OSTI)

Based on the lack of publicly available performance and operational data for the current carbon-in-ash monitor (CIAM) commercial offerings, EPRI and Southern Company initiated a demonstration of several commercial technologies on Southern Company's coal-fired units.

2000-09-25T23:59:59.000Z

100

Ash Deposit Physical and Chemical Analysis  

Science Conference Proceedings (OSTI)

As part of the Electric Power Research Institutes (EPRIs) ongoing Boiler Tube Failure Reduction (BTFR) program, this report has been compiled to discuss chemical and mechanical mechanisms that lead to the formation of ash deposits. Ash deposits are a known cause of several boiler tube failure mechanisms, which can not only impact plant performance, but also lead to millions of dollars in lost revenue due to forced outages.

2010-12-17T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Coal Ash: Characteristics, Management, and Environmental Issues  

Science Conference Proceedings (OSTI)

Coal-fired power plants in the United States produce more than 92 million tons of coal ash per year. About 40% is beneficially used in a variety of applications, and about 60% is managed in storage and disposal sites. This technical update summarizes information and data on the physical and chemical characteristics of coal ash, beneficial use applications, disposal practices, and management practices to mitigate environmental concerns.

2009-09-17T23:59:59.000Z

102

Ash Deposit Physical and Chemical Analysis  

Science Conference Proceedings (OSTI)

As part of the Electric Power Research Institutes (EPRIs) ongoing Boiler Tube Failure Reduction (BTFR) program, this report has been compiled to discuss chemical and mechanical mechanisms that lead to the formation of ash deposits. Ash deposits are a known cause of a number of boiler tube failure mechanisms, which can not only impact plant performance, but lead to millions of dollars in lost revenue due to forced outages.

2010-12-17T23:59:59.000Z

103

Densification of pond ash by blasting  

Science Conference Proceedings (OSTI)

Fly ash from thermal power plants is disposed, in huge quantities in ash ponds, which occupy large land areas otherwise useful for agriculture, housing, or other development. For effective rehabilitation of ash ponds, densification of the slurry deposit is essential to increase the bearing capacity and to improve its resistance to liquefaction. Extensive field trials were carried out to evaluate the effectiveness of deep blasting for densification of deposited fly ash. Ninety explosions comprising 15 single blasts, with varying depths and quantities of charges, and 3 group blasts, each having 25 charges placed at various spacings, were carried out. The compaction achieved in terms of an increase in relative density was evaluated from surface settlement measurements. Extensive field monitoring was undertaken through pore-water pressure measurements, vibration measurements, penetration tests, and block vibration tests. For the average charge of 2--4 g of explosive per cubic meter of untreated deposit, the average relative density was found to improve from 50% to 56--58%. Analysis of the test results indicates that deep blasting may be an effective technique for modest compaction of loose fly ash deposits. The field testing program presented in this paper provides valuable information that can be used for planning blast densification of fly ash deposits.

Gandhi, S.R.; Dey, A.K.; Selvam, S. [Indian Inst. of Tech., Madras (India)

1999-10-01T23:59:59.000Z

104

Marketing coal ash, slag, and sludge  

SciTech Connect

Investigates the selling of by-products of coal-fired power generation--fly ash, bottom ash, boiler slag, and scrubber sludge--by utilities for use in highways, parking lots, cement, roofing, bricks, and blocks. Points out that the EPA has drafted tough new regulations for solid-waste storage, transportation, and disposal that may soon cost power plants $25-$40 a ton to dispose of wastes. Reports that the EPRI is studying high-volume by-product applications that have low technology requirements (e.g. fly ash for use in highways, parking lots, and utility construction) and medium-volume, medium-technology applications (e.g. by-products used for cement manufacture, asphalt, blocks, bricks, roofing granules, and wallboards). Reveals that EPRI plans to eventually identify a representative set of perhaps half a dozen basic fly ashes, characterize them, do proportion studies of existing concrete mixes (including those with fly ash in them), and then develop guidelines for fly ash proportions in concrete.

Lihach, N.; Golden, D.; Komai, R.; Maulbetsch, J.

1982-12-01T23:59:59.000Z

105

Li2ikk+  

Office of Legacy Management (LM)

Li2ikk+ Li2ikk+ 0/-/.3~+ ' Department of Energy Washington, DC 20585 m 19 1999 Mr. William R. Augustine Deputy Chief Programs Management Division U.S. Army Corps of Engineers Depanment of the Army Washington. D.C. 203 14-1000 Dear Mr. Augustine: I am writing to you as a follow-up to discussions our staffs have had regarding two former Department of the Army facilities in the Formerly Used Defense Sites (FUDS) program where the former Atomic Energy Commission (AEC) also conducted activities. These sites are the former Marion Engineer Depot and the former Scioto Ordnance Plant, both just outside of Marion, Ohio. The Department of Energy (DOE) has records relating to both of these facilities. Since there has been public concern regarding the possibility of residual radioactivity at

106

A theory manual for multi-physics code coupling in LIME.  

SciTech Connect

The Lightweight Integrating Multi-physics Environment (LIME) is a software package for creating multi-physics simulation codes. Its primary application space is when computer codes are currently available to solve different parts of a multi-physics problem and now need to be coupled with other such codes. In this report we define a common domain language for discussing multi-physics coupling and describe the basic theory associated with multiphysics coupling algorithms that are to be supported in LIME. We provide an assessment of coupling techniques for both steady-state and time dependent coupled systems. Example couplings are also demonstrated.

Belcourt, Noel; Bartlett, Roscoe Ainsworth; Pawlowski, Roger Patrick; Schmidt, Rodney Cannon; Hooper, Russell Warren

2011-03-01T23:59:59.000Z

107

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

Science Conference Proceedings (OSTI)

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

108

li(2)-98.pdf  

NLE Websites -- All DOE Office Websites (Extended Search)

Analysis of ARESE Measurements Regarding Cloud Absorption Z. Li and A. Trishchenko Canada Centre for Remote Sensing Ottawa, Ontario, Canada H. W. Barker Atmospheric Environment...

109

li(1)-98.pdf  

NLE Websites -- All DOE Office Websites (Extended Search)

Forcing by Smoke Aerosols Determined from Satellite and Surface Measurements Z. Li Canada Centre for Remote Sensing Ottawa, Ontario, Canada L. Kou Intermap Technologies Ottawa,...

110

WELL BEING WEDNESDAY Oven Baked Chicken Tandoori with Side Salad, Fresh Lime &  

E-Print Network (OSTI)

WELL BEING WEDNESDAY Low Fat Oven Baked Chicken Tandoori with Side Salad, Fresh Lime & Homemade with a reduced Fat Tomato Sauce HM V £3.80 Jacket Potato Fillings Low Fat Cottage Cheese Deli Style Coleslaw with Low Fat Mayonnaise Lean Mince Chilli Con Carne Grated Welsh Cheddar Tuna Mayonnaise ­ (responsibly

Davies, Christopher

111

Extraction of trace metals from fly ash  

DOE Patents (OSTI)

A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

1984-01-01T23:59:59.000Z

112

Extraction of trace metals from fly ash  

DOE Patents (OSTI)

A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, M.; Wai, C.M.; Nagy, Z.

1983-08-15T23:59:59.000Z

113

Marketing coal ash, slag, and sludge  

Science Conference Proceedings (OSTI)

The increase in coal-fired power plants and tighter environmental problems have put utilities in the position of marketing coal ash, slag, and sludge by turning waste products into a resource. Many utilities are looking beyond road and structural fill uses in their marketing efforts. Slag can be made into sandblasting grit, aggregate, and roofing granules, or used for soil stabilization or the chemical fixation of municipal wastes. Composition and collection variations discourage many utilities from marketing their by-products, while availability can be a problem for customers if the power plant should shut down. Other problems include storage and transportation, competition, and institutional barriers. Documentation of the fly ash, bottom ash, boiler slag, and scrubber waste markets by the Electric Power Research Institute considers these factors and develops a marketing method to help utilities evaluate and promote their product. (DCK)

Lihach, N.; Golden, D.; Komai, R.; Maulbetsch, J.

1982-12-01T23:59:59.000Z

114

Energy Efficient Microwave Hybrid Processing of Lime for Cement, Steel, and Glass Industries  

SciTech Connect

In this study, the microwave materials interactions were studied through dielectric property measurements, process modeling, and lab scale microwave hybrid calcination tests. Characterization and analysis were performed to evaluate material reactions and energy usage. Processing parameters for laboratory scale and larger scale calcining experiments were developed for MAT limestone calcination. Early stage equipment design concepts were developed, with a focus on microwave post heating treatment. The retrofitting of existing rotary calcine equipment in the lime industry was assessed and found to be feasible. Ceralink sought to address some of the major barriers to the uptake of MAT identified as the need for (1) team approach with end users, technology partners, and equipment manufacturers, (2) modeling that incorporates kiln materials and variations to the design of industrial microwave equipment. This project has furthered the commercialization effort of MAT by working closely with an industrial lime manufacturer to educate them regarding MAT, identifying equipment manufacturer to supply microwave equipment, and developing a sophisticated MAT modeling with WPI, the university partner. MAT was shown to enhance calcining through lower energy consumption and faster reaction rates compared to conventional processing. Laboratory testing concluded that a 23% reduction in energy was possible for calcining small batches (5kg). Scale-up testing indicated that the energy savings increased as a function of load size and 36% energy savings was demonstrated (22 kg). A sophisticated model was developed which combines simultaneous microwave and conventional heating. Continued development of this modeling software could be used for larger scale calcining simulations, which would be a beneficial low-cost tool for exploring equipment design prior to actual building. Based on these findings, estimates for production scale MAT calcining benefits were calculated, assuming uptake of MAT in the US lime industry. This estimate showed that 7.3 TBTU/year could be saved, with reduction of 270 MMlbs of CO2 emissions, and $29 MM/year in economic savings. Taking into account estimates for MAT implementation in the US cement industry, an additional 39 TBTU/year, 3 Blbs of CO2 and $155 MM/year could be saved. One of the main remaining barriers to commercialization of MAT for the lime and cement industries is the sheer size of production. Through this project, it was realized that a production size MAT rotary calciner was not feasible, and a different approach was adapted. The concept of a microwave post heat section located in the upper portion of the cooler was devised and appears to be a more realistic approach for MAT implementation. Commercialization of this technology will require (1) continued pilot scale calcining demonstrations, (2) involvement of lime kiln companies, and (3) involvement of an industrial microwave equipment provider. An initial design concept for a MAT post-heat treatment section was conceived as a retrofit into the cooler sections of existing lime rotary calciners with a 1.4 year payback. Retrofitting will help spur implementation of this technology, as the capital investment will be minimal for enhancing the efficiency of current rotary lime kilns. Retrofits would likely be attractive to lime manufacturers, as the purchase of a new lime kiln is on the order of a $30 million dollar investment, where as a MAT retrofit is estimated on the order of $1 million. The path for commercialization lies in partnering with existing lime kiln companies, who will be able to implement the microwave post heat sections in existing and new build kilns. A microwave equipment provider has been identified, who would make up part of the continued development and commercialization team.

Fall, Morgana L; Yakovlev, Vadim; Sahi, Catherine; Baranova, Inessa; Bowers, Johnney G; Esquenazi , Gibran L

2012-02-10T23:59:59.000Z

115

Jet Engine Coatings Resist Volcanic Ash Damage - Materials ...  

Science Conference Proceedings (OSTI)

Apr 27, 2011 ... Upon cooling, the molten ash forms a brittle glass that flakes off, taking the coating with it. Like sand, ash is made mostly of silica and poses a ...

116

Development of High-Volume Fly Ash Blended Cements  

Science Conference Proceedings (OSTI)

High-volume fly ash (HVFA) blended cement can be produced either by intergrinding fly ash with portland cement clinker or by blending dry fly ash with portland cement. Production of HVFA cement using the intergrinding method may be the most cost-effective and practical of the two approaches. This report documents the results of commercial-scale production of HVFA blended cements using up to 55 percent fly ash to replace the portland cement.

2001-10-11T23:59:59.000Z

117

Use of Coal Ash in Highway Construction: Michigan Demonstration Project  

Science Conference Proceedings (OSTI)

A 3000-ft-length fly ash base under a highway shoulder will help demonstrate the impact of reused ash on structural integrity and groundwater. This report provides valuable design details for utilities seeking to increase ash reuse and for state highway design engineers responsible for preparing construction specifications.

1989-01-10T23:59:59.000Z

118

ASH VITRIFICATION -A TECHNOLOGY READY FOR TRANSFER  

E-Print Network (OSTI)

methods for treating ash in the near future [1]. The lack of specific rules by RCRA has led to confusion the Toxic Characterization Leaching Procedure (TCLP) extraction tests conducted on slag samples which were(ml!!l) in TCLP Extract Arsenic BQL · Barium 0.8 Cadmium 0.010 Chromium BOL Lead 0.43 Mercury 0.0007 Selenium BOL

Columbia University

119

UJ LiJ  

NLE Websites -- All DOE Office Websites (Extended Search)

- - o >- tD o UJ :> LiJ o W ~ Central Nevada-23 UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY Federal Center, Denver, Colorado 80225 ANALYSIS OF HYDRAULIC TESTS IN HOT CREEK VALLEY, NEVADA June 1970 Open-file report Prepared Under Contract AT(29-2)-474 for the Nevada Operations Office U.S. Atomic Energy Commission USGS-474-82 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately

120

Plutonium dissolution from Rocky Flats Plant incinerator ash  

SciTech Connect

Rockwell Hanford Operations (Rockwell) soon will commence recovery of plutonium from Rocky Flats Plant incinerator ash. In preparation for this processing, Rockwell undertook literature and laboratory studies to identify, select and optimize plutonium dissolution methods for treating the ash. Ash reburning, followed by dissolution in nitric acid containing calcium fluoride, was selected as the processing method for the ash. Recommended values of process parameters were identified. Using the selected process, 99.5% plutonium recovery was achieved, leaving about 12.7 wt % heel residue for an equal weight composite of the three ashes tested. 15 refs., 26 figs.

Delegard, C.H.

1985-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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121

First principles study of Li diffusion in I-Li_{2}NiO_{2} structure  

E-Print Network (OSTI)

First principles computations have been used to study Li mobility in the orthorhombic Li2NiO2 structure with the Immm space group (I-Li2NiO2). Understanding Li mobility in I-Li2NiO2 structure other than the conventional ...

Ceder, Gerbrand

122

Full quantitative phase analysis of hydrated lime using the Rietveld method  

SciTech Connect

Full quantitative phase analysis (FQPA) using X-ray powder diffraction and Rietveld refinements is a well-established method for the characterization of various hydraulic binders such as Portland cement and hydraulic limes. In this paper, the Rietveld method is applied to hydrated lime, a non-hydraulic traditional binder. The potential presence of an amorphous phase in this material is generally ignored. Both synchrotron radiation and a conventional X-ray source were used for data collection. The applicability of the developed control file for the Rietveld refinements was investigated using samples spiked with glass. The results were cross-checked by other independent methods such as thermal and chemical analyses. The sample microstructure was observed by transmission electron microscopy. It was found that the consistency between the different methods was satisfactory, supporting the validity of FQPA for this material. For the samples studied in this work, the amount of amorphous material was in the range 2-15 wt.%.

Lassinantti Gualtieri, Magdalena, E-mail: magdalena.gualtieri@unimore.it [Dipartimento Ingegneria dei Materiali e dell'Ambiente, Universita Degli Studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41100 Modena (Italy); Romagnoli, Marcello; Miselli, Paola; Cannio, Maria [Dipartimento Ingegneria dei Materiali e dell'Ambiente, Universita Degli Studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41100 Modena (Italy)] [Dipartimento Ingegneria dei Materiali e dell'Ambiente, Universita Degli Studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41100 Modena (Italy); Gualtieri, Alessandro F. [Dipartimento di Scienze della Terra, Universita Degli Studi di Modena e Reggio Emilia, I-41100 Modena (Italy)] [Dipartimento di Scienze della Terra, Universita Degli Studi di Modena e Reggio Emilia, I-41100 Modena (Italy)

2012-09-15T23:59:59.000Z

123

Removal of beryllium from drinking water by chemical coagulation and lime softening  

SciTech Connect

The effectiveness of conventional drinking water treatment and lime softening was evaluated for beryllium removal from two drinking water sources. Jar test studies were conducted to determine how common coagulants (aluminum sulfate and ferric chloride) and lime softening performed in removing beryllium from spiked waters. Centrifugation was used to simulate filtration. The two source waters used were raw Ohio River water and groundwater from the Great Miami Aquifer. The impact of initial beryllium concentration, coagulant dose, turbidity and pH on beryllium removal was examined and optimum treatment conditions were determined. Jar tests using alum and ferric chloride coagulants were able to achieve 95% and 85% removal of beryllium respectively from surface water. Removal efficiency increased as the pH was increased. Based on the data collected in the study, coprecipitation and precipitation are the two likely mechanisms responsible for beryllium removal.

Lytle, D.A.; Summers, R.S.; Sorg, T.J.

1992-01-01T23:59:59.000Z

124

Fly ash and concrete: a study determines whether biomass, or coal co-firing fly ash, can be used in concrete  

SciTech Connect

Current US national standards for using fly ash in concrete (ASTM C618) state that fly ash must come from coal combustion, thus precluding biomass-coal co-firing fly ash. The co-fired ash comes from a large and increasing fraction of US power plants due to rapid increases in co-firing opportunity fuels with coal. The fly ashes include coal fly ash, wood fly ash from pure wood combustion, biomass and coal co-fired fly ash SW1 and SW2. Also wood fly ash is blended with Class C or Class F to produce Wood C and Wood E. Concrete samples were prepared with fly ash replacing cement by 25%. All fly ash mixes except wood have a lower water demand than the pure cement mix. Fly ashes, either from coal or non coal combustion, increase the required air entraining agent (AEA) to meet the design specification of the mixes. If AEA is added arbitrarily without considering the amount or existence of fly ash results could lead to air content in concrete that is either too low or too high. Biomass fly ash does not impact concrete setting behaviour disproportionately. Switch grass-coal co-fired fly ash and blended wood fly ash generally lie within the range of pure coal fly ash strength. The 56 day flexure strength of all the fly ash mixes is comparable to that of the pure cement mix. The flexure strength from the coal-biomass co-fired fly ash does not differ much from pure coal fly ash. All fly ash concrete mixes exhibit lower chloride permeability than the pure cement mixes. In conclusion biomass coal co-fired fly ash perform similarly to coal fly ash in fresh and hardened concrete. As a result, there is no reason to exclude biomass-coal co-fired fly ash in concrete.

Wang, Shuangzhen; Baxter, Larry

2006-08-01T23:59:59.000Z

125

Manufacture of ceramic tiles from fly ash  

DOE Patents (OSTI)

The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants.

Hnat, James G. (Collegeville, PA); Mathur, Akshay (Tampa, FL); Simpson, James C. (Perkiomenville, PA)

1999-01-01T23:59:59.000Z

126

Manufacture of ceramic tiles from fly ash  

DOE Patents (OSTI)

The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants. 6 figs.

Hnat, J.G.; Mathur, A.; Simpson, J.C.

1999-08-10T23:59:59.000Z

127

Fundamental Study of Low NOx Combustion Fly Ash Utilization  

SciTech Connect

This study is principally concerned with characterizing the organic part of coal combustion fly ashes. High carbon fly ashes are becoming more common as by-products of low-NOx combustion technology, and there is need to learn more about this fraction of the fly ash. The project team consists of two universities, Brown and Princeton, and an electrical utility, New England Power. A sample suite of over forty fly ashes has been gathered from utilities across the United States, and includes ashes from a coals ranging in rank from bituminous to lignite. The characterizations of these ashes include standard tests (LOI, Foam Index), as well as more detailed characterizations of their surface areas, porosity, extractability and adsorption behavior. The ultimate goal is, by better characterizing the material, to enable broadening the range of applications for coal fly ash re-use beyond the current main market as a pozzolanic agent for concretes. The potential for high carbon-content fly ashes to substitute for activated carbons is receiving particular attention. The work performed to date has already revealed how very different the surfaces of different ashes produced by the same utility can be, with respect to polarity of the residual carbon. This can help explain the large variations in acceptability of these ashes as concrete additives.

E. M. Suubert; I. Kuloats; K. Smith; N. Sabanegh; R.H. Hurt; W. D. Lilly; Y. M. Gao

1997-05-01T23:59:59.000Z

128

Comparative Modeling of Li-Ion Cell and LiFePO4 - Programmaster ...  

Science Conference Proceedings (OSTI)

Presentation Title, Comparative Modeling of Li-Ion Cell and LiFePO4 Cell for Automotive ... The cathode active material of a LiFePO4 cell is assumed to undergo ...

129

Lithium Super-Ionic Sulfide Carbon (LiSISC) Composite for Li-S ...  

Lithium Super-Ionic Sulfide Carbon (LiSISC) Composite for Li-S Batteries Note: The technology described above is an early stage opportunity. Licensing ...

130

Factors Controlling the Solubility of Mercury Adsorbed on Fly Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

N:\R&D_Projects_Partial\FlyAsh&CCBs\Meetings\2005_04_WorldOfCoalAsh\AnnKim\HgSol N:\R&D_Projects_Partial\FlyAsh&CCBs\Meetings\2005_04_WorldOfCoalAsh\AnnKim\HgSol ubility_Paper.doc Factors Controlling the Solubility of Mercury Adsorbed on Fly Ash Ann G. Kim 1 and Karl Schroeder 2 1 ORISE Research Fellow, National Energy Technology Laboratory, U.S. Department of Energy, 626 Cochrans Mill Rd., Pittsburgh, PA 15236-0940 2 Research Group Leader, National Energy Technology Laboratory, U.S. Department of Energy, 626 Cochrans Mill Rd., Pittsburgh, PA 15236-0940 KEYWORDS Coal Utilization By-Products, leaching, activated carbon, pH ABSTRACT It is expected that increased controls on Hg emissions will shift the environmental burden from the flue gas to the solid coal utilization by-products (CUB), such as fly ash and flue-gas

131

In-Plant Ash-Handling Reference Manual  

Science Conference Proceedings (OSTI)

Despite problems with ash-handling systems that have led to failures in electrostatic precipitators, there has been no extensive reference manual for specifying, operating, and maintaining such systems. The comprehensive manual compiled in this study serves as a reference for every phase of boiler bottom ash- and fly ash-handling systems design and operation as well as a primer for those unfamiliar with these systems.

1986-12-01T23:59:59.000Z

132

Recovery of aluminum and other metal values from fly ash  

DOE Patents (OSTI)

The invention relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

McDowell, W.J.; Seeley, F.G.

1979-11-01T23:59:59.000Z

133

Recovery of aluminum and other metal values from fly ash  

DOE Patents (OSTI)

The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

1981-01-01T23:59:59.000Z

134

The Effect of Ammonia on Mercury Partitioning in Fly Ash  

Science Conference Proceedings (OSTI)

Management options and environmental assessments for fly ash are driven primarily by their physical and chemical characteristics. This report describes the results of a laboratory study on the leaching of mercury from several paired fly ash samples from facilities employing powdered activated carbon (PAC) injection for mercury control. While previous EPRI research has shown that mercury leaching from ash with PAC is negligible, it has also been found that ammonia complexes can increase the mobility of so...

2008-03-25T23:59:59.000Z

135

Identification of Arsenic Species in Coal Ash Particles  

Science Conference Proceedings (OSTI)

Identification of the chemical species and compounds of arsenic in individual coal fly ash particles will help provide a scientifically sound basis for assessing health risks from inhalation of these particles. This report presents the results of an analytical chemistry study of coal-combustion ash, with some work also completed on oil-combustion ash and copper smelter dust collected from several sources in the United States and Europe. Results showed that most arsenic is present on the surface of coal a...

1998-08-13T23:59:59.000Z

136

NETL: Utilization Projects - Managing High-Carbon Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

Managing High-Carbon Ash Managing High-Carbon Ash Task 1: Effect of Coal Quality The objective of this task is to assess if fuel selection is an important factor determining ash quality. Work on this task will involve each of the three participating organizations. Ash samples from three coals will be generated under identical firing conditions in the pilot furnace at the University of Utah, and the matching ash and coal samples sent to Brown. Additional matching sets of coal and ash will be obtained from commercial-scale firing at Southern Company. The ashes will be characterized for LOI and surfactant adsorption activity under standard conditions and trends with fuel type identified. At the same time, chars will be prepared from the matching coal set under standard conditions in a laboratory furnace and also characterized for surfactant adsorptivity. A variety of standard conditions may need to be explored. The combined data set will be analyzed to determine cross correlations between ash behavior, standard laboratory char behavior, and parent coal properties. Our goal is to be able to anticipate ash behavior either (a) from coal properties directly, or (b) from the properties of chars made by a simple laboratory procedure. Either could be the basis for a coal quality index -- one based on fuel properties and the other based on a simple screening test.

137

Embankment Loading on Saturated Coal Ash: Centrifuge Demonstration Test  

Science Conference Proceedings (OSTI)

When an embankment of coal combustion residuals or soil is built over a coal ash pond, pore water pressures can accumulate in the underlying saturated ash deposits and trigger a rapid slope failure. This report documents a scale model test completed to obtain data on the conditions that may lead to a slope failure. A 6.5-inch tall sand embankment was built on top of a 6-inch thick deposit of saturated fly ash. The strength of the fly ash was characterized using consolidated undrained triaxial ...

2013-12-10T23:59:59.000Z

138

Data Summary Report for Hanford Site Coal Ash Characterization  

Science Conference Proceedings (OSTI)

The purpose of this report is to present data and findings from sampling and analysis of five distinct areas of coal ash within the Hanford Site River Corridor

Sulloway, H. M.

2012-03-06T23:59:59.000Z

139

Coal Fly Ash as Alternative Source of Smelter Grade Alumina  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, COM 2011. Symposium, COM 2011 (held with the World Gold Conference), POSTER SESSION. Presentation Title, Coal Fly Ash as

140

HIGH STRENGTH PHOSPHATE CEMENT USING INDUSTRIAL BYPRODUCT ASHES ...  

industries that use fossil fuels. Approximately one third of this ash is recycled in the cement based products as an additive. Typically, ...

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Kinetics of beneficiated fly ash by carbon burnout  

Science Conference Proceedings (OSTI)

The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called Loss On Ignition (LOI). The concrete producers` day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

Okoh, J.M.; Dodoo, J.N.D.; Diaz, A. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States). Dept. of Natural Sciences; Ferguson, W.; Udinskey, J.R. Jr.; Christiana, G.A. [Delmarva Power, Wilmington, DE (United States)

1997-12-31T23:59:59.000Z

142

Mechanical Activation of Deposited Fly Ash by Grinding  

Science Conference Proceedings (OSTI)

May 1, 2007 ... According to laboratory experience the breaking of fly ash particles is required to increase its hydraulic potential (Opoczky, 2001). Aim of the ...

143

NETL: News Release - Novel Treatment of Fly Ash Yields Safer...  

NLE Websites -- All DOE Office Websites (Extended Search)

successfully tested at near full-scale levels. Easily integrated with existing ash handling equipment, the simple-to-operate, cost-efficient technology can be retrofitted to...

144

Proportioning CLSM Using Fly Ash and GGBS - Programmaster.org  

Science Conference Proceedings (OSTI)

Presentation Title, Proportioning CLSM Using Fly Ash and GGBS. Author(s), Udayashankar B C, Raghavendra T. On-Site Speaker (Planned), Udayashankar  ...

145

Rebound characteristics for ash particles impacting a planar surface  

Science Conference Proceedings (OSTI)

The formation of ash deposition on the heat transfer tubes in a boiler reduces the heat transfer coefficient by about 25%. Because of these fouling layers

2013-01-01T23:59:59.000Z

146

Environmental Performance Assessment of Coal Ash Use Sites: Waukegan Ash Embankment  

Science Conference Proceedings (OSTI)

A comprehensive database on the environmental effects of reusing coal combustion residues is essential to increased application of these products. This report discusses changes in soils, vegetation, and groundwater quality around an embankment containing coal fly ash and develops an approach for building a statistically sound environmental performance database.

1991-01-03T23:59:59.000Z

147

Long-Range Forecast Trajectories of Volcanic Ash from Redoubt Ash from Redoubt Volcano Eruptions  

Science Conference Proceedings (OSTI)

The Redoubt Volcano in Alaska began a series of eruptions on 14 December 1989. Volcanic ash was often reported to reach heights where, as it moved with the upper-level flow, it could affect aircraft operations thousands of km from the eruption. ...

Jerome L. Heffter; Barbara J. B. Stunder; Glenn D. Rolph

1990-12-01T23:59:59.000Z

148

Environmental Performance Assessment of Coal Ash Use Sites: Little Canada Structural Ash Fill  

Science Conference Proceedings (OSTI)

An insufficient database on the environmental effects of reusing coal combustion residues hampers increased utilization of these products. This report discusses the changes in soils, vegetation, and groundwater quality around a structural fill containing coal fly ash and develops an approach for building a statistically sound environmental performance database.

1990-06-06T23:59:59.000Z

149

Investigation of particle isolation in Li-ion battery electrodes...  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigation of particle isolation in Li-ion battery electrodes using 7Li NMR spectroscopy Title Investigation of particle isolation in Li-ion battery electrodes using 7Li NMR...

150

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network (OSTI)

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwater using  iron?oxide coated coal bottom ash  Johanna L.  using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

151

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants  

E-Print Network (OSTI)

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants PSO Project No. 6356 July 2008 Renewable Energy and Transport #12;2 Utilization of Ash Fractions from Alternative Biofuels)...............................................................................7 2. Production of Ash Products from Mixed Biofuels

152

Hazards Associated with the Use of Bone Ash in Contact with Molten ...  

Science Conference Proceedings (OSTI)

Bone ash itself is non-toxic and environmentally benign. However recent evidence indicates that bone ash can be reduced upon contact with aluminum alloys to ...

153

IN HARM'S WAY: Lack Of Federal Coal Ash  

E-Print Network (OSTI)

IN HARM'S WAY: Lack Of Federal Coal Ash Regulations Endangers Americans And Their Environment 2010 Thirty-nine New Damage Cases of Contamination from Improperly Disposed Coal Combustion Waste, Editor and Contributing Author #12;IN HARM'S WAY: Lack of Federal Coal Ash Regulations Endangers

Short, Daniel

154

Characterization of Ammonia Leaching from Coal Fly Ash  

Science Conference Proceedings (OSTI)

This interim report presents the results of a preliminary laboratory assessment of the leaching of ammonia from coal ashes that have been ammoniated by pollution control devices installed on power plants to reduce nitrogen oxide (NOx) emissions. This laboratory assessment project was designed to measure the leaching rates of ammonia from ashes in a disposal environment.

2001-11-30T23:59:59.000Z

155

Infiltration Processing of Metal Matrix-Fly Ash Particle Composites  

Science Conference Proceedings (OSTI)

Metal Matrix composites can provide improved functional properties compared to solid metal castings while saving production energy and raw material costs. Ash-derived metal matrix composites, in particular, can provide high value-added use to coal fly ash. This report describes research on use of pressure infiltration techniques to produce composites for automotive component applications.

1997-09-16T23:59:59.000Z

156

Use of Coal Ash in Highway Construction: Michigan Demonstration Project  

Science Conference Proceedings (OSTI)

This report documents the construction and performance testing of a 3000-ft length of fly ash base under a highway shoulder. Following three years of service, the road shoulder shows no signs of premature deterioration. This report should aid utilities seeking to increase ash-use rates in highway-related projects, as well as state highway design engineers responsible for preparing construction specifications.

1991-03-05T23:59:59.000Z

157

Manganese Occurrence Near Three Coal Ash Impoundments in Illinois  

Science Conference Proceedings (OSTI)

This report describes research performed to better understand the cause of elevated manganese concentrations sometimes found in groundwater near coal ash management facilities. Three impoundments in Illinois were selected for detailed field and laboratory studies of conditions conducive to manganese release from coal ash as well as natural soils.

2002-09-24T23:59:59.000Z

158

The recycling of the coal fly ash in glass production  

Science Conference Proceedings (OSTI)

The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

2006-09-15T23:59:59.000Z

159

Ashe County - Wind Energy System Ordinance | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ashe County - Wind Energy System Ordinance Ashe County - Wind Energy System Ordinance Ashe County - Wind Energy System Ordinance < Back Eligibility Agricultural Commercial Industrial Institutional Investor-Owned Utility Local Government Multi-Family Residential Municipal Utility Nonprofit Residential Rural Electric Cooperative Schools State Government Tribal Government Utility Savings Category Wind Buying & Making Electricity Program Info State North Carolina Program Type Solar/Wind Permitting Standards Provider Ashe County Planning Department In 2007 Ashe County adopted a wind ordinance to regulate the use of wind-energy systems in unincorporated areas of the county and to describe the conditions by which a permit for installing such a system may be obtained. This policy was adopted in the context of an ongoing debate over

160

Purple traps yield Reservation's first detection of Emerald Ash Borer  

NLE Websites -- All DOE Office Websites (Extended Search)

traps yield Reservation's first detection of Emerald Ash Borer traps yield Reservation's first detection of Emerald Ash Borer The question of whether or not DOE's forests are infested with Emerald Ash Borer (EAB) has been answered. On May 10, a trap on Highway 95 at the Highway 58 interchange produced the first instance of the destructive non-native insect in Roane County. Five days later, a second trap on Bethel Valley Road near the East Portal turned up the first capture in Anderson County. "Unfortunately, these finds signal the beginning of a decline of ash species throughout the reservation" according to Greg Byrd, forester with the ORNL Natural Resources Program. "Dieback will become more prominent as the insect populations expand. Native ash trees have little defense against this pest, which was

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Element associations in ash from waste combustion in fluidized bed  

SciTech Connect

The incineration of MSW in fluidized beds is a commonly applied waste management practice. The composition of the ashes produced in a fluidized bed boiler has important environmental implications as potentially toxic trace elements may be associated with ash particles and it is therefore essential to determine the mechanisms controlling the association of trace elements to ash particles, including the role of major element composition. The research presented here uses micro-analytical techniques to study the distribution of major and trace elements and determine the importance of affinity-based binding mechanisms in separate cyclone ash particles from MSW combustion. Particle size and the occurrence of Ca and Fe were found to be important factors for the binding of trace elements to ash particles, but the binding largely depends on random associations based on the presence of a particle when trace elements condensate in the flue gas.

Karlfeldt Fedje, K., E-mail: karinka@chalmers.s [Department of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers University of Technology, Kemivaegen 10, 412 96 Goeteborg (Sweden); Rauch, S. [Department of Civil and Environmental Engineering, Division of Water Environment Technology, Chalmers University of Technology, Sven Hultins Gata 8, 412 96 Goeteborg (Sweden); Cho, P.; Steenari, B.-M. [Department of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers University of Technology, Kemivaegen 10, 412 96 Goeteborg (Sweden)

2010-07-15T23:59:59.000Z

162

State Waste Discharge Permit application: 200-W Powerhouse Ash Pit  

Science Conference Proceedings (OSTI)

As part of the Hanford Federal Facility Agreement and Consent Order negotiations; the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-W Powerhouse Ash Pit. The 200-W Powerhouse Ash Waste Water discharges to the 200-W Powerhouse Ash Pit via dedicated pipelines. The 200-W Powerhouse Ash Waste Water is the only discharge to the 200-W Powerhouse Ash Pit. The 200-W Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

Atencio, B.P.

1994-06-01T23:59:59.000Z

163

COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS  

SciTech Connect

The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

2001-04-01T23:59:59.000Z

164

Toxicity mitigation and solidification of municipal solid waste incinerator fly ash using alkaline activated coal ash  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Incinerator fly ash (IFA) is added to an alkali activated coal fly ash (CFA) matrix. Black-Right-Pointing-Pointer Means of stabilizing the incinerator ash for use in construction applications. Black-Right-Pointing-Pointer Concrete made from IFA, CFA and IFA-CFA mixes was chemically characterized. Black-Right-Pointing-Pointer Environmentally friendly solution to IFA disposal by reducing its toxicity levels. - Abstract: Municipal solid waste (MSW) incineration is a common and effective practice to reduce the volume of solid waste in urban areas. However, the byproduct of this process is a fly ash (IFA), which contains large quantities of toxic contaminants. The purpose of this research study was to analyze the chemical, physical and mechanical behaviors resulting from the gradual introduction of IFA to an alkaline activated coal fly ash (CFA) matrix, as a mean of stabilizing the incinerator ash for use in industrial construction applications, where human exposure potential is limited. IFA and CFA were analyzed via X-ray fluorescence (XRF), X-ray diffraction (XRD) and Inductive coupled plasma (ICP) to obtain a full chemical analysis of the samples, its crystallographic characteristics and a detailed count of the eight heavy metals contemplated in US Title 40 of the Code of Federal Regulations (40 CFR). The particle size distribution of IFA and CFA was also recorded. EPA's Toxicity Characteristic Leaching Procedure (TCLP) was followed to monitor the leachability of the contaminants before and after the activation. Also images obtained via Scanning Electron Microscopy (SEM), before and after the activation, are presented. Concrete made from IFA, CFA and IFA-CFA mixes was subjected to a full mechanical characterization; tests include compressive strength, flexural strength, elastic modulus, Poisson's ratio and setting time. The leachable heavy metal contents (except for Se) were below the maximum allowable limits and in many cases even below the reporting limit. The leachable Chromium was reduced from 0.153 down to 0.0045 mg/L, Arsenic from 0.256 down to 0.132 mg/L, Selenium from 1.05 down to 0.29 mg/L, Silver from 0.011 down to .001 mg/L, Barium from 2.06 down to 0.314 mg/L and Mercury from 0.007 down to 0.001 mg/L. Although the leachable Cd exhibited an increase from 0.49 up to 0.805 mg/L and Pd from 0.002 up to 0.029 mg/L, these were well below the maximum limits of 1.00 and 5.00 mg/L, respectively.

Ivan Diaz-Loya, E. [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Allouche, Erez N., E-mail: allouche@latech.edu [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Eklund, Sven; Joshi, Anupam R. [Department of Chemistry, Louisiana Tech University, Ruston, LA 71272 (United States); Kupwade-Patil, Kunal [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States)

2012-08-15T23:59:59.000Z

165

Behavior of Ammoniated Fly Ash: Effects of Ammonia on Fly Ash Handling, Disposal, and End-Use  

Science Conference Proceedings (OSTI)

The implementation of ammonia-based nitrogen oxides (NOx) control technologies has had the undesired side effect of creating potential problems for operating units due to ammonia-contaminated fly ash. The work described in this report is a continuation of long-term EPRI efforts to address various industry concerns associated with ammoniated fly ash.

2002-02-22T23:59:59.000Z

166

Categorical Exclusion 4566, Ash Removal Project  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FOrnI FOrnI Project Title: Ash Removal Project (4566) Program or Program Office: Y -12 Site Office Location: Oak Ridge Tennessee Project Description: This work scope is to split, containerize, package, transport and disposition one hundred and two (102) cans of mixed waste. General Administration/Management OA I - Routine business actions OA2 * Administrative contract amendments OA4 - Interpretations/rulings for existing regulations OA5 - Regulatory interpretations without environmental effect OA6 - Procedural rule makings upgrade OA 7 - Transfer of property, use unchanged OA8 . Award of technical supportlM&O/personal service contracts OA9 - Info gathering, analysis, documentation, dissemination, and training OA 10 - Reports on non-DOE legislation OA II -

167

Phenolic acids as bioindicators of fly ash deposit revegetation  

Science Conference Proceedings (OSTI)

The floristic composition, the abundance, and the cover of pioneer plant species of spontaneously formed plant communities and the content of total phenolics and phenolic acids, as humus constituents, of an ash deposit after 7 years of recultivation were studied. The restoration of both the soil and the vegetation on the ash deposits of the 'Nikola Tesla-A' thermoelectric power plant in Obrenovac (Serbia) is an extremely slow process. Unfavorable physical and chemical characteristics, the toxicity of fly ash, and extreme microclimatic conditions prevented the development of compact plant cover. The abundance and cover of plants increased from the central part of the deposit towards its edges. Festuca rubra L., Crepis setosa Hall., Erigeron canadensis L., Cirsium arvense (L.) Scop., Calamagrostis epigeios (L.) Roth., and Tamarix gallica L. were the most abundant species, thus giving the highest cover. Humus generated during the decomposition process of plant remains represents a completely new product absent in the ash as the starting material. The amount of total phenolics and phenolic acids in fly ash increased from the center of the deposit towards its edges in correlation with the increase in plant abundance and cover. The presence of phenolic acids indicates the ongoing process of humus formation in the ash, in which the most abundant pioneer plants of spontaneously formed plant communities play the main role. Phenolic compounds can serve as reliable bioindicators in an assessment of the success of the recultivation process of thermoelectric power plants' ash deposits.

L. Djurdjevic; M. Mitrovic; P. Pavlovic; G. Gajic; O. Kostic [Institute for Biological Research 'Sinisa Stankovic,' Belgrade (Serbia and Montenegro). Department of Ecology

2006-05-15T23:59:59.000Z

168

High Volume Fly Ash Blended Cements: Status Report  

Science Conference Proceedings (OSTI)

At present, the production of high-volume fly ash (HVFA) concrete involves the addition of large volumes of fly ash as a separate ingredient at a ready-mixed concrete batch plant. This necessitates additional storage silos and quality control at the job site. In order to resolve these issues, CANMET, in partnership with Electric Power Research Institute, U.S.A., undertook a major research project to develop blended cements incorporating high volumes of ASTM Class fly ash. The blended cements are made by ...

1999-10-28T23:59:59.000Z

169

Recovery of iron oxide from coal fly ash  

DOE Patents (OSTI)

A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

Dobbins, Michael S. (Ames, IA); Murtha, Marlyn J. (Ames, IA)

1983-05-31T23:59:59.000Z

170

Arsenic and Selenium Speciation in Fly Ash and Wastewater  

Science Conference Proceedings (OSTI)

The objective of the work is to predict As and Se behavior in pond wastewater based on coal and power plant characteristics so that utilities will have tools for selection of coals (and blends) that will allow them to meet applicable water quality regulations in the ash pond discharge. Arsenic and selenium were chosen as the focus of this work because the behavior of arsenic and selenium is not well correlated with pH in ash pond water, but with speciation of these oxyanions in the fly ash. Furthermore, ...

2005-03-28T23:59:59.000Z

171

Scale-up and Demonstration of Fly Ash Ozonation Technology  

Science Conference Proceedings (OSTI)

This project is the first large pilot scale test of a new process to passivate the carbon in ash so that it can be used in concrete without physically removing the carbon from the ash. The tests were conducted at PPL's Montour SES, sponsored by DOE and supported by EPRI. Near full-scale industrial equipment was used to expose fly ash, carbon mixtures to ozone to see if ozone would passivate the surface of carbon so that it would not react with air entraining agents that are used by concrete manufacturers...

2005-11-29T23:59:59.000Z

172

Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power Plants  

E-Print Network (OSTI)

Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power color from pulp mill effluent using coal ash. Prevent coal ash adsorbent from leaching arsenic, chromium, lead, and zinc. Define a treatment procedure using coal ash that will result in the maximum

Hutcheon, James M.

173

Respiratory and Reproductive Characteristics of Eastern Mosquitofish (Gambusia holbrooki) Inhabiting a Coal Ash Settling Basin  

E-Print Network (OSTI)

) Inhabiting a Coal Ash Settling Basin B. P. Staub, W. A. Hopkins, J. Novak, J. D. Congdon Savannah River 2002/Accepted: 29 March 2002 Abstract. Coal fly ash and effluent from coal ash settling basins viable populations in areas contaminated by coal ash. While eastern mosquitofish are present

Hopkins, William A.

174

Coal- and Ash-Handling Systems Reliability Conference and Workshop Proceedings  

Science Conference Proceedings (OSTI)

This report presents papers, discussion summaries, and conclusions from an EPRI workshop on reliability problems with coal- and ash-handling systems in power plants. Held in October 1980 in St. Louis, the workshop covered yard and in-plant coal handling, frozen coal, fugitive dust, fly ash handling, bottom ash handling, and ash disposal.

1981-08-01T23:59:59.000Z

175

Proceedings: Tenth International Ash Use Symposium, Volume 1: High-Volume Uses/Concrete Applications  

Science Conference Proceedings (OSTI)

Topics discussed at the tenth symposium on coal ash use included fundamental ash use research, product marketing, applied research, ash management and the environment, and commercial applications. Intense international research interest continues in coal ash use due to the prospects of avoiding disposal costs and generating revenue from by-product sales.

1993-01-22T23:59:59.000Z

176

Thermal Stability of LiPF6 Salt and Li-ion Battery ElectrolytesContaining LiPF6  

DOE Green Energy (OSTI)

The thermal stability of the neat LiPF6 salt and of 1 molal solutions of LiPF6 in prototypical Li-ion battery solvents was studied with thermogravimetric analysis (TGA) and on-line FTIR. Pure LiPF6 salt is thermally stable up to 380 K in a dry inert atmosphere, and its decomposition path is a simple dissociation producing LiF as solid and PF5 as gaseous products. In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF6 and water vapor to form POF3 and HF. No new products were observed in 1 molal solutions of LiPF6 in EC, DMC and EMC by on-line TGA-FTIR analysis. The storage of the same solutions in sealed containers at 358 K for 300 420 hrs. did not produce any significant quantity of new products as well. In particular, noalkylflurophosphates were found in the solutions after storage at elevated temperature. In the absence of either an impurity like alcohol or cathode active material that may (or may not) act as a catalyst, there is no evidence of thermally induced reaction between LiPF6 and the prototypical Li-ion battery solvents EC, PC, DMC or EMC.

Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

2006-03-08T23:59:59.000Z

177

Women @ Energy: Yan Li | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Yan Li Yan Li Women @ Energy: Yan Li March 12, 2013 - 9:23am Addthis Yan Li is a Computational Physicist at the Computational Science Center at Brookhaven National Laboratory. Yan Li is a Computational Physicist at the Computational Science Center at Brookhaven National Laboratory. Yan Li is a Computational Physicist at the Computational Science Center at Brookhaven National Laboratory. Her work is mainly focused on developing and applying advanced computational tools to investigate material properties of crystal, surfaces/interfaces and nanostructures. Yan got her Ph.D in Physics from University of Illinois at Urbana-Champaign. Before becoming a staff scientist at BNL, Yan worked at the University of California, Davis as a postodoral researcher. Yan holds a Bachelors of

178

Adsorption of Trace Elements on Fresh and Weathered Coal Fly Ash  

Science Conference Proceedings (OSTI)

A variety of trace elements are associated with fly ash produced by coal combustion. These trace elements are potentially of concern for human health if they are released to the environment, and thus it is important to understand their mobility in coal fly ash management settings. In the fly ash management environment, the ash may react with meteoric fluid to release trace elements into groundwater or surface water. However, fly ash particles also have a relatively high surface area and have the ability ...

2012-05-23T23:59:59.000Z

179

Jet Engine Coatings Resist Volcanic Ash Damage - Materials ...  

Science Conference Proceedings (OSTI)

Posted on: 4/27/2011 12:00:00 AM... Concerns about the damage that volcanic ash clouds can inflict on aircraft engines resulted in last year's $2 billion ...

180

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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181

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1998-12-29T23:59:59.000Z

182

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1998-01-01T23:59:59.000Z

183

Compressive strength of concrete and mortar containing fly ash  

DOE Patents (OSTI)

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-04-29T23:59:59.000Z

184

Guideline for Control and Prevention of Fly Ash Erosion  

Science Conference Proceedings (OSTI)

Boiler tube failures (BTFs) represent the largest portion of availability loss in the fossil boiler industry at about 4%. Approximately 25% of all tube failures are due to fly ash erosion (FAE).

2011-11-04T23:59:59.000Z

185

Volcanic Ash Forecast Transport And Dispersion (VAFTAD) Model  

Science Conference Proceedings (OSTI)

The National Oceanic and Atmospheric Administration (NOAA) Air Resources Laboratory (ARL) has developed a Volcanic Ash Forecast Transport And Dispersion (VAFTAD) model for emergency response use focusing on hazards to aircraft flight operations. ...

Jerome L. Heffter; Barbara J. B. Stunder

1993-12-01T23:59:59.000Z

186

Optical properties of fly ash. Volume 2, Final report  

Science Conference Proceedings (OSTI)

Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executive summary of the whole program followed by the dissertation of Ghosal and Ebert. Volume 2 contains the dissertation of Ebert which covers the measurements of the optical constants of slags, and calculations of the radiant properties of fly ash dispersions. A list of publications and conference presentations resulting from the work is also included.

Self, S.A.

1994-12-01T23:59:59.000Z

187

Recoverable immobilization of transuranic elements in sulfate ash  

DOE Patents (OSTI)

Disclosed is a method of reversibly immobilizing sulfate ash at least about 20% of which is sulfates of transuranic elements. The ash is mixed with a metal which can be aluminum, cerium, samarium, europium, or a mixture thereof, in amounts sufficient to form an alloy with the transuranic elements, plus an additional amount to reduce the transuranic element sulfates to elemental form. Also added to the ash is a fluxing agent in an amount sufficient to lower the percentage of the transuranic element sulfates to about 1% to about 10%. The mixture of the ash, metal, and fluxing agent is heated to a temperature sufficient to melt the fluxing agent and the metal. The mixture is then cooled and the alloy is separated from the remainder of the mixture.

Greenhalgh, Wilbur O. (Richland, WA)

1985-01-01T23:59:59.000Z

188

Local field effects at Li K edges in electron energy-loss spectra of Li, Li{sub 2}O and LiF  

Science Conference Proceedings (OSTI)

Local field effects (LFEs) in low-losses of electron energy-loss spectra of Li, Li{sub 2}O, and LiF were calculated using the density functional theory under the generalized gradient approximation. By including the lithium 1s semicore state in the pseudopotentials, the amplitude of LFE was assessed all the way up to the Li K edge (from 0 to 80 eV). They are found to be much larger for semicore levels (2s of oxygen, 2s of fluorine, and 1s of lithium) than for the valence electron energy-loss region. LFEs at the Li K edge are studied in detail. In particular, for q=0 they are shown to increase with the inhomogeneities of the compounds (from Li to LiF). The influence of the magnitude and the direction of q is also presented. Both parameters have negligible effect in the case of Li metal but changes are quite substantial for Li{sub 2}O and LiF. This is in agreement with the isotropy and the delocalization of the metallic bonding as compared to the ionic one. LFEs at the Li K edge are, however, whatever the compound, much smaller than those observed at transition metal M{sub 2,3} edges situated at similar energy positions. This result can be accounted for by considering the wave functions associated with the initial and final states involved in both edges. For lithium battery materials, most often presenting a transition metal edge close to the Li K edge, these findings imply significant consequences with respect to the interpretation of their electron energy-loss spectroscopy spectra. In particular, LFE can be expected to be stronger in positive electrodes than in negative ones.

Mauchamp, V.; Moreau, P.; Ouvrard, G.; Boucher, F. [Institut des Materiaux Jean Rouxel, UMR 6502, Universite de Nantes-CNRS, 2, Rue de la Houssiniere, 44322 Nantes Cedex (France)

2008-01-15T23:59:59.000Z

189

KINETICS OF FLY ASH BENEFICIATION BY CARBON BURNOUT  

SciTech Connect

Surface area analyses performed on fly ash samples reveal that the surface area is controlled by carbon content. The higher surface areas found in large particles are due to the presence of highly porous carbonaceous particles. Adsorption-desorption isotherms and t-plots of fly ash samples indicate that fly ash is porous. BJH Adsorption/Desorption pore size analysis reveal that pore diameters are independent of sieve size. They appear to be dependent only on the nature of the material which confers porosity. Based on the results of Brown and Dykstra (41) it is reasonable to assume that calculations of reaction rates at temperatures above 550 C were confounded by weight losses from processes other than carbon oxidation and, therefore, are not useful in determination of the temperature dependence of carbon oxidation in fly ash. The results of the present study indicate that temperatures below 550 C should be used for future studies in order to satisfactorily assess the temperature dependence of carbon oxidation in fly ash. Furthermore, it is also advisable that percent carbon determinations be performed on fly ash samples after the oxidation reactions to determine whether all carbon present in fly ash is oxidized. This will ensure that reaction rates are representative of the complete oxidation of carbon. An inverse relationship was determined between reaction rates and oxygen concentration for this study. As discussed, this may be due to volatilization of volatiles from fly ash and ease of transport of products away from the reaction sites by the action of the vacuum applied to the samples. A more accurate determination of oxygen dependence of carbon oxidation can be accomplished by the use of specialty gases containing different concentrations of oxygen which could eliminate the need to apply vacuum to the samples.

Dr. Joseph N.D. Dodoo; Dr. Joseph M. Okoh

2000-11-01T23:59:59.000Z

190

Triboelectric Fly Ash Beneficiation: Summary Report, Phase IV  

Science Conference Proceedings (OSTI)

The Center for Applied Energy Research (CAER) at the University of Kentucky has devised new approaches for extracting marketable fly ash from high carbon combustion ashes. Dry beneficiation technology based on pneumatic transport, triboelectric principles has emerged with the potential for high efficiency removal of carbon at low cost and with no secondary waste products. (EPRI Interim Report TR-109016, November, 1997; EPRI Interim Report TR-111647, November 1998; EPRI Report TE-113673, September 1999; E...

2000-11-27T23:59:59.000Z

191

Li-ion Batteries and Beyond  

Science Conference Proceedings (OSTI)

Mar 12, 2012 ... Energy Nanomaterials: Li-ion Batteries and Beyond Sponsored by: The Minerals, Metals and Materials Society, TMS Materials Processing and ...

192

Ash level meter for a fixed-bed coal gasifier  

DOE Patents (OSTI)

An ash level meter for a fixed-bed coal gasifier is provided which utilizes the known ash level temperature profile to monitor the ash bed level. A bed stirrer which travels up and down through the extent of the bed ash level is modified by installing thermocouples to measure the bed temperature as the stirrer travels through the stirring cycle. The temperature measurement signals are transmitted to an electronic signal process system by an FM/FM telemetry system. The processing system uses the temperature signals together with an analog stirrer position signal, taken from a position transducer disposed to measure the stirrer position to compute the vertical location of the ash zone upper boundary. The circuit determines the fraction of each total stirrer cycle time the stirrer-derived bed temperature is below a selected set point, multiplies this fraction by the average stirrer signal level, multiplies this result by an appropriate constant and adds another constant such that a 1 to 5 volt signal from the processor corresponds to a 0 to 30 inch span of the ash upper boundary level. Three individual counters in the processor store clock counts that are representative of: (1) the time the stirrer temperature is below the set point (500.degree. F.), (2) the time duration of the corresponding stirrer travel cycle, and (3) the corresponding average stirrer vertical position. The inputs to all three counters are disconnected during any period that the stirrer is stopped, eliminating corruption of the measurement by stirrer stoppage.

Fasching, George E. (Morgantown, WV)

1984-01-01T23:59:59.000Z

193

Photoionization spectroscopy of ionic metal dimers: LiCu and LiAg  

Science Conference Proceedings (OSTI)

Electronic spectra are reported for the heteronuclear metal dimers LiCu and LiAg, with resonant one-color two-photon ionization (R2PI). The dimers are produced in a pulsed supersonic molecular beam by laser vaporization of either a copper or silver rod coated with a thin film of vacuum deposited lithium metal. A total of twelve excited electronic states for LiCu and seven for LiAg are observed. Analysis of the vibrational progressions yields ground and excited state vibrational frequencies and dissociation energies for both LiCu and LiAg. In addition, selected vibronic bands are rotationally resolved. This data, together with that obtained by Morse and co-workers for LiCu [J. Chem. Phys. (to be published)], gives bond lengths for LiCu and LiAg (r{sub 0}{sup {double_prime}}=2.26 and 2.41 {Angstrom}, respectively). The bond lengths for LiCu and LiAg are significantly shorter than expected by comparison to the homonuclear diatomics Li{sub 2} and Cu{sub 2} or Ag{sub 2}. Dissociation energies in the heteronuclear dimers are also much greater than the mean of the corresponding homonuclear dimer values. These trends indicate that ionic character plays a leading role in the ground-state bonding. {copyright} {ital 1997 American Institute of Physics.}

Brock, L.R.; Knight, A.M.; Reddic, J.E.; Pilgrim, J.S.; Duncan, M.A. [Department of Chemistry, University of Georgia, Athens, Georgia 30602 (United States)

1997-04-01T23:59:59.000Z

194

Coal Ash Corrosion Resistant Materials Testing  

Science Conference Proceedings (OSTI)

In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a moderate alkali content (0.2% sodium equivalents), thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that aggressive alkali sulfate constituents were present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. Test Section A was removed in November 2001 after about 24 months of service at the desired steam temperature set point, with about 15.5 months of exposure at full temperature. A progress report, issued in October 2002, was written to document the performance of the candidate alloys in that test section. The evaluation described the condition of each tube sample after exposure. It involved a determination of the rate of wall thickness loss for these samples. In cases where there was more than one sample of a candidate material in the test section, an assessment was made of the performance of the alloy as a function of temperature. Test Sections B and C were examined during the November 2001 outage, and it was decided that, due to excessive wastage, certain tube samples needed to be removed and replaced in order to ensure that Test Sections B and C would have a chance of remaining in the boiler for their intended exposure period. These suspect tube samples were replaced and the two remaining test sections were put back into service. The tube samples that were removed from Test Sections B and C were set aside for later analysis at the end of the planned exposure period. Test Sections B and C were again examined approximately six months later. At that time, measured wall thickness losses raised concerns about additional tube samples. These suspect samples were also removed, set aside for later analysis, and replaced. The test sections then went back into service until the end of the second exposure period, which was concluded in May 2003 when, due to evidence of excessive wastage, the valves were opened increasing cooling steam flow and thereby effectively stopping corrosion. In August 2003, Test Sections B and C were removed for closer examination. Section C had experienced about 42 months of service at the desired team temperature set point with 28.5 months at temperature at full temperature. Additional suspect samples were removed from Test Section B, then, it was re-installed into the boiler (at the location originally occupied by Section C), where it remained in service until the end of the program. Due to this removal history, the samples from Test Section B had a total service duration that varied from a minimum of 15.5 months (for samples that performed poorly) to 37 months for samples the survived for the full intended service exposure for Section B. The figure below shows a schematic of Test Section B and indicates the length of service exposure for different locations. This report provides the results of the evaluation of Test Section B, including the samples that remained in the Test Section for the full exposure period as well as those that were removed early. This report also is intended to compare and summarize the results for all three test sections. The analysis of T

D. K. McDonald; P. L. Daniel; D. J. DeVault

2007-12-31T23:59:59.000Z

195

Modification of LiCl-LiBr-KBr electrolyte for LiAl/FeS{sub 2} batteries  

DOE Green Energy (OSTI)

The bipolar LiAl/FeS{sub 2} battery is being developed to achieve the high performance and long cycle life needed for electric vehicle application. The molten-salt (400 to 440 C operation) electrolyte composition for this battery has evolved to support these objectives. An earlier change to LiCl-LiBr-KBr electrolyte is responsible for significantly increased cycle life (up to 1,000 cycles). Recent electrolyte modification has significantly improved cell performance; approximately 50% increased power, with increased high rate capacity utilization. Results are based on power-demanding EV driving profile test at 600 W/kg. The effects of adding small amounts (1--5 mol%) of LiF and LiI to LiCl-LiBr-KBr electrolyte are discussed. By cyclic voltammetry, the modified electrolytes exhibit improved FeS{sub 2} electrochemistry. Electrolyte conductivity is little changed, but high current density (200 mA/cm{sup 2}) performance improved by approximately 50%. A specific feature of the LiI addition is an enhanced cell overcharge tolerance rate from 2.5 to 5 mA/cm{sup 2}. The rate of overcharge tolerance is related to electrolyte properties and negative electrode lithium activity. As a result, the charge balancing of a bipolar battery configuration with molten-salt electrolyte is improved to accept greater cell-to-cell deviations.

Kaun, T.D.; Jansen, A.N.; Henriksen, G.L.; Vissers, D.R. [Argonne National Lab., IL (United States). Chemical Technology Div.

1996-06-01T23:59:59.000Z

196

Kinetic measurement and prediction of the hydrogen outgassing from the polycrystalline LiH/Li2O/LiOH system  

DOE Green Energy (OSTI)

Due to the exothermic reaction of lithium hydride (LiH) salt with water during transportation and handling, there is always a thin film of lithium hydroxide (LiOH) present on the LiH surface. In dry or vacuum storage, this thin LiOH film slowly decomposes. We have used temperature-programmed reaction/decomposition (TPR) in combination with the isoconversion method of thermal analysis to determine the outgassing kinetics of H{sub 2}O from pure LiOH and H{sub 2} and H{sub 2}O from this thin LiOH film. H{sub 2} production via the reaction of LiH with LiOH, forming a lithium oxide (Li{sub 2}O) interlayer, is thermodynamically favored, with the rate of further reaction limited by diffusion through the Li{sub 2}O and the stability of the decomposing LiOH. Lithium hydroxide at the LiOH/vacuum interface also decomposes easily to Li{sub 2}O, releasing H{sub 2}O which subsequently reacts with LiH in a closed system to form H{sub 2}. At the onset of dry decomposition, where H{sub 2} is the predominant product, the activation energy for outgassing from a thin LiOH film is lower than that for bulk LiOH. However, as the reactions at the LiH/Li{sub 2}O/LiOH and at the LiOH/vacuum interfaces proceed, the overall activation energy barrier for the outgassing approaches that of bulk LiOH decomposition. The kinetics developed here predicts a hydrogen evolution profile in good agreement with hydrogen release observed during long term isothermal storage.

Dinh, L N; Grant, D M; Schildbach, M A; Smith, R A; Siekhaus, W J; Balazs, B; Leckey, J H; Kirkpatrick, J; McLean II, W

2005-04-06T23:59:59.000Z

197

Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems  

SciTech Connect

Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

Natalie J. Gese; Batric Pesic

2013-03-01T23:59:59.000Z

198

Leaching of Mixtures of Biochar and Fly Ash  

SciTech Connect

Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments.2, 5, 6 Both the residual char from biomass pyrolysis7-9, 12 (biochar) and fly ash from coal combustion1, 13, 14 have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations.10, 11, 16 Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and reduces available aluminum.3, 17 Combinations of these benefits likely lead to the observed increased yields for crops including corn and sugarcane.17 with biochar addition to soil. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) 8, 17 than do unammended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way.18 Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes.15 Here, we are examining the properties of mixtures of biochar, fly ash, and soil and evaluating leaching of organic carbon and metals from the mixtures.

Palumbo, Anthony Vito [ORNL; Porat, Iris [ORNL; Phillips, Jana Randolph [ORNL; Amonette, J. E. [Pacific Northwest National Laboratory (PNNL); Drake, Meghan M [ORNL; Brown, Steven D [ORNL; Schadt, Christopher Warren [ORNL

2009-01-01T23:59:59.000Z

199

Atsun Solar Electric Technology Co Ang Li Tiansheng | Open Energy...  

Open Energy Info (EERE)

Co (Ang Li Tiansheng) Place Zaozhuang, Shandong Province, China Product Chinese PV cell and module maker. References Atsun Solar Electric Technology Co (Ang Li Tiansheng)1...

200

Metal Oxide-Graphene Nanocomposites for Li-Ion Battery  

Science Conference Proceedings (OSTI)

Presentation Title, Metal Oxide-Graphene Nanocomposites for Li-Ion Battery. Author(s), Donghai Wang, Daiwon Choi, Juan Li, Zhenguo Yang, Zimin Nie, Rong ...

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

LiDAR (Lewicki & Oldenburg) | Open Energy Information  

Open Energy Info (EERE)

LiDAR (Lewicki & Oldenburg) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: LiDAR (Lewicki & Oldenburg) Exploration Activity Details Location...

202

LiDAR (Lewicki & Oldenburg, 2005) | Open Energy Information  

Open Energy Info (EERE)

LiDAR (Lewicki & Oldenburg, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: LiDAR (Lewicki & Oldenburg, 2005) Exploration Activity Details...

203

LiDAR (Lewicki & Oldenburg, 2004) | Open Energy Information  

Open Energy Info (EERE)

LiDAR (Lewicki & Oldenburg, 2004) Exploration Activity Details Location Unspecified Exploration Technique LiDAR Activity Date Usefulness useful DOE-funding Unknown References...

204

Fine ash formation during pulverized coal combustion  

Science Conference Proceedings (OSTI)

In this study, 15 pulverized coal samples were burnt in a drop-tube furnace to investigate the formation of fine particulates and the influence of coal ash properties on their emission. Coal combustion was carried out at 1673 K in air. Fine particles were collected by a cyclone and a low-pressure impactor. The elemental compositions of the collected particles were analyzed by scanning electron microscopy with energy-dispersive X-ray spectroscopy. We examined the chemical compositions of the fine particles as a function of particle diameter and examined the proportions of the elements in the parent coal samples. We determined that almost all particles less than 0.22 {mu}m in diameter were formed by means of volatilization-condensation of SiO{sub 2} and Al{sub 2}O{sub 3} in the coal. We also demonstrated that the amount of SiO{sub 2} in particle size less than 0.22 {mu}m in diameter was related to the amount of fine included quartz and clay minerals in the parent coal. The primary components of particles greater than 0.76 {mu}m in diameter were SiO{sub 2} and Al{sub 2}O{sub 3}, and as the diameter of the particles decrease, the mass fractions of iron, magnesium, calcium, and phosphorus increased. However, the particle diameter at which this tendency commenced differed depending on the element. Particles between 0.22 and 0.76 {mu}m in diameter were thought to have been formed by the fragmentation and coalescence of particles in the coal and by the simultaneous condensation of volatilized elements onto other particles. 17 refs., 12 figs., 1 tab.

Tsuyoshi Teramae; Takayuki Takarada [Idemitsu Kosan Company, Limited, Chiba (Japan). Coal and Environmental Research Laboratory

2009-04-15T23:59:59.000Z

205

The ultra-high lime with aluminum process for removing chloride from recirculating cooling water  

E-Print Network (OSTI)

Chloride is a deleterious ionic species in cooling water systems because it is important in promoting corrosion. Chloride can be removed from cooling water by precipitation as calcium chloroaluminate using ultra-high lime with aluminum process (UHLA). The research program was conducted to study equilibrium characteristics and kinetics of chloride removal by UHLA process, study interactions between chloride and sulfate or silica, and develop a model for multicomponent removal by UHLA. Kinetics of chloride removal with UHLA was investigated. Chloride removal was found to be fast and therefore, removal kinetics should not be a limitation to applying the UHLA process. Equilibrium characteristics of chloride removal with UHLA were characterized. Good chloride removal was obtained at reasonable ranges of lime and aluminum doses. However, the stoichiometry of chloride removal with UHLA deviated from the theoretical stoichiometry of calcium chloroaluminate precipitation. Equilibrium modeling of experimental data and XRD analysis of precipitated solids indicated that this deviation was due to the formation of other solid phases such as tricalcium hydroxyaluminate and tetracalcium hydroxyaluminate. Effect of pH on chloride removal was characterized. Optimum pH for maximum chloride removal was pH 12 ± 0.2. Results of equilibrium experiments at different temperatures indicated that final chloride concentrations slightly increased when water temperature increased at temperatures below 40oC. However, at temperatures above 40oC, chloride concentration substantially increased with increasing water temperature. An equilibrium model was developed to describe chemical behavior of chloride removal from recycled cooling water using UHLA. Formation of a solid solution of calcium chloroaluminate, tricalcium hydroxyaluminate, and tetracalcium hydroxyaluminate was found to be the best mechanism to describe the chemical behavior of chloride removal with UHLA. Results of experiments that studied interactions between chloride and sulfate indicated that sulfate is preferentially removed over chloride. Final chloride concentration increased with increasing initial sulfate concentration. Silica was found to have only a small effect on chloride removal. The equilibrium model was modified in order to include sulfate and silica reactions along with chloride in UHLA process and it was able to accurately predict the chemical behavior of simultaneous removal of chloride, sulfate, and silica with UHLA.

Abdel-wahab, Ahmed Ibraheem Ali

2005-05-01T23:59:59.000Z

206

2003 Conference on Unburned Carbon on Utility Fly Ash  

NLE Websites -- All DOE Office Websites (Extended Search)

2003 Conference on Unburned Carbon on Utility Fly Ash 2003 Conference on Unburned Carbon on Utility Fly Ash October 28, 2003 Table of Contents Disclaimer Participants List [PDF-31KB] Papers and Presentations Control Measures Predictive Performance Tools (Including Instrumentation) Processing and Utilization of High-LOI Fly Ash Beneficiation of High-LOI Fly Ash Characterization of High-LOI Fly Ash Poster Presentations Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

207

ADVANCED POWER SYSTEMS ASH BEHAVIOR IN POWER SYSTEMS  

SciTech Connect

The overall goal of this initiative is to develop fundamental knowledge of ash behavior in power systems for the purpose of increasing power production efficiency, reducing operation and maintenance costs, and reducing greenhouse gas emissions into the atmosphere. The specific objectives of this initiative focus primarily on ash behavior related to advanced power systems and include the following: ? Determine the current status of the fundamental ash interactions and deposition formation mechanisms as already reported through previous or ongoing projects at the EERC or in the literature. ? Determine sintering mechanisms for temperatures and particle compositions that are less well known and remain for the most part undetermined. ? Identify the relationship between the temperature of critical viscosity (Tcv ) as measured in a viscometer and the crystallization occurring in the melt. ? Perform a literature search on the use of heated-stage microscopy (HSM) for examining in situ ash-sintering phenomena and then validate the use of HSM in the determination of viscosity in spherical ash particles. ? Ascertain the formation and stability of specific mineral or amorphous phases in deposits typical of advanced power systems. ? Evaluate corrosion for alloys being used in supercritical combustion systems.

CHRISTOPHER J. ZYGARLICKE; DONALD P. MCCOLLOR; JOHN P. KAY; MICHAEL L. SWANSON

1998-09-01T23:59:59.000Z

208

ADVANCED POWER SYSTEMS ASH BEHAVIOR IN POWER SYSTEMS  

Science Conference Proceedings (OSTI)

The overall goal of this initiative is to develop fundamental knowledge of ash behavior in power systems for the purpose of increasing power production efficiency, reducing operation and maintenance costs, and reducing greenhouse gas emissions into the atmosphere. The specific objectives of this initiative focus primarily on ash behavior related to advanced power systems and include the following: ? Determine the current status of the fundamental ash interactions and deposition formation mechanisms as already reported through previous or ongoing projects at the EERC or in the literature. ? Determine sintering mechanisms for temperatures and particle compositions that are less well known and remain for the most part undetermined. ? Identify the relationship between the temperature of critical viscosity (Tcv ) as measured in a viscometer and the crystallization occurring in the melt. ? Perform a literature search on the use of heated-stage microscopy (HSM) for examining in situ ash-sintering phenomena and then validate the use of HSM in the determination of viscosity in spherical ash particles. ? Ascertain the formation and stability of specific mineral or amorphous phases in deposits typical of advanced power systems. ? Evaluate corrosion for alloys being used in supercritical combustion systems.

CHRISTOPHER J. ZYGARLICKE; DONALD P. MCCOLLOR; JOHN P. KAY; MICHAEL L. SWANSON

1998-09-01T23:59:59.000Z

209

ENVIRONMENTAL EVALUATION FOR UTILIZATION OF ASH IN SOIL STABILIZATION  

Science Conference Proceedings (OSTI)

The Minnesota Pollution Control Agency (MPCA) approved the use of coal ash in soil stabilization, indicating that environmental data needed to be generated. The overall project goal is to evaluate the potential for release of constituents into the environment from ash used in soil stabilization projects. Supporting objectives are: (1) To ensure sample integrity through implementation of a sample collection, preservation, and storage protocol to avoid analyte concentration or loss. (2) To evaluate the potential of each component (ash, soil, water) of the stabilized soil to contribute to environmental release of analytes of interest. (3) To use laboratory leaching methods to evaluate the potential for release of constituents to the environment. (4) To facilitate collection of and to evaluate samples from a field runoff demonstration effort. The results of this study indicated limited mobility of the coal combustion fly ash constituents in laboratory tests and the field runoff samples. The results presented support previous work showing little to negligible impact on water quality. This and past work indicates that soil stabilization is an environmentally beneficial CCB utilization application as encouraged by the U.S. Environmental Protection Agency. This project addressed the regulatory-driven environmental aspect of fly ash use for soil stabilization, but the demonstrated engineering performance and economic advantages also indicate that the use of CCBs in soil stabilization can and should become an accepted engineering option.

David J. Hassett; Loreal V. Heebink

2001-08-01T23:59:59.000Z

210

Ash bed level control system for a fixed-bed coal gasifier  

DOE Patents (OSTI)

An ash level control system is provided which incorporates an ash level meter to automatically control the ash bed level of a coal gasifier at a selected level. The ash level signal from the ash level meter is updated during each cycle that a bed stirrer travels up and down through the extent of the ash bed level. The ash level signal is derived from temperature measurements made by thermocouples carried by the stirrer as it passes through the ash bed and into the fire zone immediately above the ash bed. The level signal is compared with selected threshold level signal to determine if the ash level is above or below the selected level once each stirrer cycle. A first counter is either incremented or decremented accordingly. The registered count of the first counter is preset in a down counter once each cycle and the preset count is counted down at a selected clock rate. A grate drive is activated to rotate a grate assembly supporting the ash bed for a period equal to the count down period to maintain the selected ash bed level. In order to avoid grate binding, the controller provides a short base operating duration time each stirrer cycle. If the ash bed level drops below a selected low level or exceeds a selected high level, means are provided to notify the operator.

Fasching, George E. (Morgantown, WV); Rotunda, John R. (Fairmont, WV)

1984-01-01T23:59:59.000Z

211

$^7$Li Abundances in Halo Stars: Testing Stellar Evolution Models and the Primordial $^7$Li Abundance  

E-Print Network (OSTI)

A large number of stellar evolution models with [Fe/H] = -2.3 and -3.3 have been calculated in order to determine the primordial $^7$Li abundance and to test current stellar evolution models by a comparison to the extensive database of Li abundances in extremely metal poor halo stars observed by Thorburn (1994). Standard models do a good job of fitting the observed Li abundances in stars hotter than 5600 K. They predict a primordial $^7$Li abundance of Log N(Li) = 2.24\\pm 0.03$. Models which include microscopic diffusion predict a downward curvature in the $^7$Li destruction isochrones at hot temperatures which is not present in the observations. Thus, the observations clearly rule out models which include uninhibited microscopic diffusion of $^7$Li from the surface of the star. The [Fe/H] = -2.3 stellar models which include both diffusion and rotational mixing provide an excellent match to the observations. Both the plateau stars and the heavily depleted cool stars are well fit by these models. The rotational mixing leads to considerable $^7$Li depletion in these models and the primordial $^7$Li abundance inferred from these models is Log N(Li) = $3.08\\pm 0.1$.

Brian Chaboyer; P. Demarque

1994-03-21T23:59:59.000Z

212

Technology for the Recovery of Fuel and Adsorbent Carbons from Coal Burning Utility Ash Ponds and Landfills  

Science Conference Proceedings (OSTI)

Several sampling techniques were evaluated to recover representative core samples from the ash ponds at Western Kentucky Energy's Coleman Station. The most successful was a combination of continuous-flight augers and specially designed soft-sediment sampling tubes driven by a Hammerhead drill mounted on an amphibious ARGO vehicle. A total of 51 core samples were recovered and analyzed in 3 ft sections and it was determined that there are 1,354,974 tons of ash in Pond C. Of the over 1.35M tons of ash present, 14% or 190K tons can be considered as coarse (+100 mesh). Pond C contains approximately 88K tons of carbon, nearly half of which is coarse and potentially recoverable with spiral concentration while the fine carbon (-100 mesh) is recoverable with froth flotation. There are 1.27M tons of carbon-free ash, 12% of which is coarse and potentially usable as block sand. Spiral concentration testing on bulk samples showed that product grade of 30 to 38% C (4200 to 5500 Btu/lb) was obtainable. When this product was cleaned again in an additional stage of spiral concentration, the product grade was improved to 7200 to 8200 Btu/lb with an accompanying 13 to 29% decrease in yield. Release analysis of hydraulically classified pond ash showed that froth flotation could provide froth products with as high a grade as 9000 Btu/lb with a yield of 5%. Increasing yield to 10% reduced froth grade to 7000 Btu/lb. Batch flotation provided froth grades as high as 6500 Btu/lb with yields of 7% with 1.5 lb/ton SPP and 1 lb/ton frother. Column flotation test results were similar to those achieved in batch flotation in terms of both grade and yield, however, carbon recoveries were lower (50% carbon recovery and using wash water improved froth grade. Bottom ash samples were recovered from each of the units at Coleman Station. Characterization confirmed that sufficient quantity and quality of material is generated to produce a marketable lightweight aggregate and recover a high-grade fuel product. Spiral concentration provided acceptable grade lightweight aggregate with yields of only 10 to 20%. Incorporating a sieve bend into the process to recover coarse, porous ash particles from the outside race of the spirals increased aggregate yield to as high as 75%, however, the carbon content of the aggregate also increased. An opening size of 28 mesh on the sieve bend appeared to be sufficient. Lightweight concrete blocks (28 to 32 lbs) were produced from bottom ash and results show that acceptable strength could be attained with a cement/concrete ratio as low as 1/4. A mobile Proof-of-Concept (POC) field unit was designed and fabricated to meet the processing objectives of the project. The POC plant consisted of two trailer-mounted modules and was completely self sufficient with respect to power and water requirements. The POC unit was hauled to Coleman Station and operated at a feed rate of 2 tph. Results showed that the spirals operated similarly to previous pilot-scale operations and a 500 lb composite sample of coarse carbon was collected with a grade of 51.7% C or 7279 Btu/lb. Flotation results compared favorably with release analysis and 500 lbs of composite froth product was collected with a grade of 35% C or 4925 Btu/lb. The froth product was dewatered to 39% moisture with vacuum filtration. Pan pelletization and briquetting were evaluated as a means of minimizing handling concerns. Rotary pan pelletization produced uniform pellets with a compressive strength of 4 lbf without the use of any binder. Briquettes were produced by blending the coarse and fine carbon products at a ratio of 1:10, which is the proportion that the two products would be produced in a commercial operation. Using 3% lime as a binder produced the most desirable briquettes with respect to strength, attrition and drop testing. Additionally, the POC carbon products compared favorably with commercial activated carbon when used for removal of mercury from simulated flue gas. A business model was generated to summarize anti

J.G. Groppo; T.L. Robl

2005-09-30T23:59:59.000Z

213

Technology for the Recovery of Fuel and Adsorbent Carbons from Coal Burning Utility Ash Ponds and Landfills  

SciTech Connect

Several sampling techniques were evaluated to recover representative core samples from the ash ponds at Western Kentucky Energy's Coleman Station. The most successful was a combination of continuous-flight augers and specially designed soft-sediment sampling tubes driven by a Hammerhead drill mounted on an amphibious ARGO vehicle. A total of 51 core samples were recovered and analyzed in 3 ft sections and it was determined that there are 1,354,974 tons of ash in Pond C. Of the over 1.35M tons of ash present, 14% or 190K tons can be considered as coarse (+100 mesh). Pond C contains approximately 88K tons of carbon, nearly half of which is coarse and potentially recoverable with spiral concentration while the fine carbon (-100 mesh) is recoverable with froth flotation. There are 1.27M tons of carbon-free ash, 12% of which is coarse and potentially usable as block sand. Spiral concentration testing on bulk samples showed that product grade of 30 to 38% C (4200 to 5500 Btu/lb) was obtainable. When this product was cleaned again in an additional stage of spiral concentration, the product grade was improved to 7200 to 8200 Btu/lb with an accompanying 13 to 29% decrease in yield. Release analysis of hydraulically classified pond ash showed that froth flotation could provide froth products with as high a grade as 9000 Btu/lb with a yield of 5%. Increasing yield to 10% reduced froth grade to 7000 Btu/lb. Batch flotation provided froth grades as high as 6500 Btu/lb with yields of 7% with 1.5 lb/ton SPP and 1 lb/ton frother. Column flotation test results were similar to those achieved in batch flotation in terms of both grade and yield, however, carbon recoveries were lower (<70%). High airflow rate was required to achieve >50% carbon recovery and using wash water improved froth grade. Bottom ash samples were recovered from each of the units at Coleman Station. Characterization confirmed that sufficient quantity and quality of material is generated to produce a marketable lightweight aggregate and recover a high-grade fuel product. Spiral concentration provided acceptable grade lightweight aggregate with yields of only 10 to 20%. Incorporating a sieve bend into the process to recover coarse, porous ash particles from the outside race of the spirals increased aggregate yield to as high as 75%, however, the carbon content of the aggregate also increased. An opening size of 28 mesh on the sieve bend appeared to be sufficient. Lightweight concrete blocks (28 to 32 lbs) were produced from bottom ash and results show that acceptable strength could be attained with a cement/concrete ratio as low as 1/4. A mobile Proof-of-Concept (POC) field unit was designed and fabricated to meet the processing objectives of the project. The POC plant consisted of two trailer-mounted modules and was completely self sufficient with respect to power and water requirements. The POC unit was hauled to Coleman Station and operated at a feed rate of 2 tph. Results showed that the spirals operated similarly to previous pilot-scale operations and a 500 lb composite sample of coarse carbon was collected with a grade of 51.7% C or 7279 Btu/lb. Flotation results compared favorably with release analysis and 500 lbs of composite froth product was collected with a grade of 35% C or 4925 Btu/lb. The froth product was dewatered to 39% moisture with vacuum filtration. Pan pelletization and briquetting were evaluated as a means of minimizing handling concerns. Rotary pan pelletization produced uniform pellets with a compressive strength of 4 lbf without the use of any binder. Briquettes were produced by blending the coarse and fine carbon products at a ratio of 1:10, which is the proportion that the two products would be produced in a commercial operation. Using 3% lime as a binder produced the most desirable briquettes with respect to strength, attrition and drop testing. Additionally, the POC carbon products compared favorably with commercial activated carbon when used for removal of mercury from simulated flue gas. A business model was generated to summarize anti

J.G. Groppo; T.L. Robl

2005-09-30T23:59:59.000Z

214

Testing the ecological stability of ectomycorrhizal symbiosis: effects of heat, ash and mycorrhizal colonization on Pinus muricata seedling performance  

E-Print Network (OSTI)

metal pan and heating it in a soil drying oven. During thesoil heating and ash addition, using a drying oven and ash

Peay, Kabir G.; Bruns, Thomas D.; Garbelotto, Matteo

2010-01-01T23:59:59.000Z

215

Ashe County, North Carolina ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Ashe County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Ashe County, North Carolina ASHRAE Standard ASHRAE 169-2006 Climate...

216

Extracting Alumina from Coal Fly Ash Using Acid Sintering-Leaching ...  

Science Conference Proceedings (OSTI)

Presentation Title, Extracting Alumina from Coal Fly Ash Using Acid ... Coal fly- ash from coal-fired power plants is rich in Al2O3 content with potential use as a ...

217

An Advanced System to Monitor the 3D Structure of Diffuse Volcanic Ash Clouds  

Science Conference Proceedings (OSTI)

Major disruptions of the aviation system from recent volcanic eruptions have intensified discussions and increased the international consensus to improve volcanic ash warnings. Central to making progress is to better discern low volcanic ash ...

J.-P. Vernier; T. D. Fairlie; J. J. Murray; A. Tupper; C. Trepte; D. Winker; J. Pelon; A. Garnier; J. Jumelet; M. Pavolonis; A. H. Omar; K. A. Powell

218

Continuous air Agglomeration Method for high Carbon fly ash Beneficiation  

DOE Patents (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carbon-free mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahan L.; Champagne, Kenneth J.; Finseth, Dennis H.

1998-09-29T23:59:59.000Z

219

Ash reduction system using electrically heated particulate matter filter  

DOE Patents (OSTI)

A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

2011-08-16T23:59:59.000Z

220

Continuous air agglomeration method for high carbon fly ash beneficiation  

DOE Patents (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahon L. (Pittsburgh, PA); Champagne, Kenneth J. (Monongahela, PA); Finseth, Dennis H. (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

FLY ASH GENERATION AND UTILIZATION -AN OVERVIEW* Tarun R. Naik, Ph.D., P.E.  

E-Print Network (OSTI)

a sodium-based sorbent such as sodium bicarbonate, soda ash, trona, or nahcalite (ICF Northwest, 1988). By

Wisconsin-Milwaukee, University of

222

Evaluation of an Ecolotree TM CAP for Closure of Coal Ash Disposal Sites  

Science Conference Proceedings (OSTI)

Once they are filled or become inactive, coal ash disposal ponds at power plant sites must meet state and federal regulations for permanent closure. In-place closure of ash ponds typically requires an impermeable cover to protect groundwater from leachate generated by stormwater infiltration through the ash. This report documents the construction, maintenance, and performance of the EcolotreeTM Cap (Tree Cap) -- an ash pond closure alternative consisting of poplar trees, grasses, and surface soil amendme...

1999-06-16T23:59:59.000Z

223

Using Zeolites Synthesized from Fly Ash to Reduce Ammonia Loss to the Environment  

Science Conference Proceedings (OSTI)

This interim report describes studies using zeolites synthesized from fly ash to reduce ammonia loss to the environment.

2002-02-19T23:59:59.000Z

224

Mercury Leachability From Concretes That Contain Fly Ashes and Activated Carbon Sorbents  

Science Conference Proceedings (OSTI)

This report presents new laboratory data on the leaching of mercury from concrete that contains fly ash and powdered activated carbon (PAC) sorbents used to capture mercury. The concretes studied during this project were made with fly ashes from lignite and subbituminous coal, including fly ashes containing PAC. Only very low levels of mercuryless than 5 parts per trillionwere leached from the fly ash concretes in both 18-hour and 7-day laboratory leach tests.

2007-07-18T23:59:59.000Z

225

Ion Beam Preparation of Li-Ion Battery Electrodes Li-Ion  

Science Conference Proceedings (OSTI)

One key factor to producing such batteries is the electrode architecture. In order to tune the morphologies of Li-ion battery electrodes, a dual beam Focused Ion ...

226

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

Science Conference Proceedings (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M. Sulloway

2007-09-26T23:59:59.000Z

227

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M Sulloway

2007-10-31T23:59:59.000Z

228

Fly Ash Construction Manual for Road and Site Applications, Volumes 1 and 2  

Science Conference Proceedings (OSTI)

This two-volume construction manual details the use of fly ash in high-volume road construction and site development, covering all project elements from ash procurement to finishing. It addresses the use of fly ash in fills, embankments, backfills, subgrade stabilization, pavement base course, and slurried backfills, as well as its application as a soil amendment.

1988-10-28T23:59:59.000Z

229

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater  

E-Print Network (OSTI)

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater Reyad; available online 29 October 2003 Abstract A by-product fly ash from oil shale processing was converted shale; Ash; Zeolite; Cadmium and lead removal 1. Introduction Oil shale exists in Jordan with large

Shawabkeh, Reyad A.

230

Swirling Melting Characteristics of Fly Ashes from Co-Firing of MSWI in China  

Science Conference Proceedings (OSTI)

Melting treatment is an efficient for heavy metal stabilization in MSW fly ash. The fly ashes from co-firing of municipal solid waste and coal incinerator were melted in the swirling melting furnace system under various temperatures. The melting characteristics ... Keywords: fly ash, co-firing, melting, melting temperature, heavy metals, fixation rate

Wang Xue-tao; Jiao You-zhou; Xu Bin; Jin Bao-sheng

2009-10-01T23:59:59.000Z

231

Nanotechnology in Li-ion Batteries  

DOE Green Energy (OSTI)

This is the second of three talks on nanostructures for li-ion batteries. The talks provide an up-to-date review of the issues and challenges facing Li-ion battery research with special focus on how nanostructures/ nanotechnology are being applied to this field. Novel materials reported as prospective candidates for anode, cathode and electrolyte will be summarized. The expected role of nanostructures in improving the performance of Li-ion batteries and the actual pros and cons of using such structures in this device will be addressed. Electrochemical experiments used to study Li-ion batteries will also be discussed. This includes the introduction to the standard experimental set-up and how experimental data (from charge-discharge experiments, cyclic voltammetry, impedance spectroscopy, etc) are interpreted.

Mukaibo, Hitomi (University of Florida, Martin Research Group)

2010-06-04T23:59:59.000Z

232

Definition: LiDAR | Open Energy Information  

Open Energy Info (EERE)

LiDAR LiDAR Jump to: navigation, search Dictionary.png LiDAR Light Detection and Ranging (LiDAR) is an active remote sensing technology that uses optical measurements of scattered light to find range (Young, 2006). Measurements can be made from aircraft- or land-based sensors. Distance to an object is determined by the time delay between transmission and detection of a laser pulse. It is accurate to within 0.1 m (at 1-m resolution, 0.3 m at 3-m resolution) and has the ability to measure the land surface elevation beneath the vegetation canopy. View on Wikipedia Wikipedia Definition Also Known As Light Detection And Ranging Related Terms DEM, Digital Elevation Model tran LikeLike UnlikeLike You like this.Sign Up to see what your friends like. smission lines,transmission line,transmission

233

Vehicle Specifications Battery Type: Li-Ion  

NLE Websites -- All DOE Office Websites (Extended Search)

1 All-Electric Conversion of the USPS Long Life Vehicle (LLV) Vehicle Specifications Battery Type: Li-Ion Pack Locations: Underbody (inboard of frame rails) Nominal System Voltage:...

234

Negative Electrodes for Li-Ion Batteries  

DOE Green Energy (OSTI)

Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

Kinoshita, Kim; Zaghib, Karim

2001-10-01T23:59:59.000Z

235

Ambient Operation of Li/Air Batteries  

Science Conference Proceedings (OSTI)

In this work, Li/air batteries based on nonaqueous electrolytes were investigated in ambient conditions (with an oxygen partial pressure of 0.21 atm and relative humidity of ~20%). A heat-sealable polymer membrane was used as both an oxygen-diffusion membrane and as a moisture barrier for Li/air batteries. The membrane also can minimize the evaporation of the electrolyte from the batteries. Li/air batteries with this membrane can operate in ambient conditions for more than one month with a specific energy of 362 Wh kg-1, based on the total weight of the battery including its packaging. Among various carbon sources used in this work, Li/air batteries using Ketjenblack (KB) carbon-based air electrodes exhibited the highest specific energy. However, KB-based air electrodes expanded significantly and absorbed much more electrolyte than electrodes made from other carbon sources. The weight distribution of a typical Li/air battery using the KB-based air electrode was dominated by the electrolyte (~70%). Lithium-metal anodes and KB-carbon anodes account for only 5.12% and 5.78% of the battery weight, respectively. We also found that only ~ 20% of the mesopore volume of the air electrode was occupied by reaction products after discharge. To further improve the specific energy of the Li/air batteries, the microstructure of the carbon electrode needs to be further improved to absorb much less electrolyte while still holding significant amounts of reaction products

Zhang, Jiguang; Wang, Deyu; Xu, Wu; Xiao, Jie; Williford, Ralph E.

2010-07-01T23:59:59.000Z

236

Aluminum - Fly Ash Metal Matrix Composites as Advanced Automobile Material  

Science Conference Proceedings (OSTI)

Metal matrix composites such as silicon carbide-aluminum, alumina-aluminum, and graphite-aluminum represent a class of emerging materials with significant potential for commercial use in the auto and aerospace industries. In industrial foundry trials, a joint industry and Department of Energy project demonstrated a promising new process for producing a low cost aluminum metal matrix composite containing fly ash particles.

2001-08-16T23:59:59.000Z

237

Novel Ash Beneficiation Processes for Managing Unburned Carbon and Ammonia  

Science Conference Proceedings (OSTI)

This report describes new fly ash beneficiation concepts for managing deleterious effects of unburned carbon and ammonia contamination associated with low nitrogen oxides (low-NOx) combustion systems. The report contains technical data, scientific discussion, and a description of ongoing development and scale-up activities.

2002-12-10T23:59:59.000Z

238

Thermal analysis and characterization of Elephant grass ash  

Science Conference Proceedings (OSTI)

Conference Tools for 2014 TMS Annual Meeting & Exhibition ... Here, ashes from incineration of elephant grass are characterized and its incorporation into clay to produce ... Moreover, thermal analysis was performed including gas emission ... Differential characterization of Ikperejere Iron shale and Iron sandstone deposit.

239

Learning from Roman Seawater Concrete  

NLE Websites -- All DOE Office Websites (Extended Search)

The ancient Romans, however, made concrete by mixing lime and volcanic rock. For underwater structures, lime and volcanic ash were mixed to form mortar, and this mortar and...

240

Spectroscopic research on infrared emittance of coal ash deposits  

SciTech Connect

This paper deals with thermal radiation characteristics of ash deposits on a pulverized coal combustion boiler of an electric power plant. Normal emittance spectra in the near to medium infrared (2.5-25 {mu}m) region and total normal emittances were measured on four kinds of ground ash deposits. Measurements were conducted in the 570-1460 K temperature range which is common for boiler furnaces, by both heating and cooling the ash samples, with the aim to study the effect of their thermal history. Dependence of emittance on wavelength, temperature and chemical composition was studied, too. Samples were tested for transparency (opacity) to verify the accuracy of results. It was determined that the thicknesses used for the ash powders are opaque for infrared radiation for thicknesses in the order of a millimeter. Tests have shown that spectral emittance increases with an increase of wavelength with a characteristic pattern common for all samples. Spectral normal emittance increases strongly with temperature at shorter wavelengths and remains high and unchanged at longer ones. Emittance spectra are not very sensitive to chemical composition of ashes especially beyond {lambda} {approx} 5 {mu}m. With an increase of temperature, total emittance of the powdered sample decreases to a minimum value around 1200 K. Further temperature rise induces an increase of total emittance due to sintering in the ash. On cooling, the emittance increases monotonically following the hysteresis. Quantitative directions for evaluating thermal radiation characteristics of ash deposits for the merits of the safety design of boiler furnaces were proposed. That comprises correlating the experimentally obtained emittance spectra with curves of simple analytical form, i.e., a continuous function of minimum emittance vs. wavelength. The proposed method can be extended to other specimens from the same furnace and used to determine correlations for thermal calculation of old and design of new furnaces - with similar geometry and combusting similar coal. The method is potentially applicable to completely different boiler furnaces combusting different coal, and the authors recommend running the tests with new deposit samples. The data will then be applicable to the thermal design of a whole new class of furnaces, having similar geometry and combusting similar coal. This is expected to greatly enhance the accuracy and precision of thermal calculation as well as the efficiency of thermal design of steam boilers. (author)

Saljnikov, Aleksandar; Komatina, Mirko; Gojak, Milan [Department of Thermomechanics, Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11120 Belgrade 35 (RS); Vucicevic, Biljana [Laboratory for Thermal Engineering, Institute of Nuclear Sciences VINCA, P.O. Box 522, Belgrade 11001 (RS); Goricanec, Darko [Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, Maribor 2000 (Slovenia); Stevanovic, Zoran [Faculty of Mining and Geology, University of Belgrade, Dusina 7, 11120 Belgrade 35 (RS)

2009-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy Storage  

Science Conference Proceedings (OSTI)

i-ion batteries based on commercially available LiFePO4 cathode and Li4Ti5O12 anode were investigated for potential stationary energy storage applications. The full cell that operated at flat 1.85V demonstrated stable cycling for 200 cycles followed by a rapid fade. A significant improvement in cycling stability was achieved via Ketjen black coating of the cathode. A Li-ion full cell with Ketjen black modified LiFePO4 cathode and an unmodified Li4Ti5O12 anode exhibited negligible fade after more than 1200 cycles with a capacity of ~130mAh/g. The improved stability, along with its cost-effectiveness, environmentally benignity and safety, make the LiFePO4/ Li4Ti5O12 Li-ion battery a promising option of storing renewable energy.

Wang, Wei; Choi, Daiwon; Yang, Zhenguo

2013-01-01T23:59:59.000Z

242

A Limnological Approach to the Management of Fly Ash Disposal Ponds  

Science Conference Proceedings (OSTI)

Fly ash disposal ponds are found at half of the U.S. coal burning power plants and receive a mixture of fly ash and water used to sluice the ash from the power plant to the pond. Leaching of metals, notably Cu, As, and Se, from fly ash can be decreased by control of inflow pH, but their release through the discharge to surface waters remains a problem, particularly for Se. Comanagement of low volume wastes of varying chemical composition and volume with fly ash make the management of water quality at the...

2004-12-27T23:59:59.000Z

243

Giant resonance study by 6li scattering  

E-Print Network (OSTI)

Nuclear incompressibility Knm is an important parameter in the nuclear matter equation of state (EOS). The locations of the isocalar giant monopole resonance (ISGMR) and giant dipole resonance (ISGDR) of nuclei are directly related to Knm and thus can give the most effective constraint on the value of the Knm. In order to determine Knm accurately, a systematic study of the ISGMR and ISGDR over a wide range of nuclei is necessary. Alpha inelastic scattering at small angles has been successfully used to study the ISGMR of heavy and medium nuclei where the monopole resonance is concentrated in a broad peak. For light nuclei (Aradioactive nuclei with inverse reactions using 6Li as a target. Data for elastic scattering of 240 MeV 6Li ions and inelastic scattering to low-lying states and giant resonances was taken for 24Mg, 28Si and 116Sn. A data analysis procedure was developed for double folding calculations. The optical potential parameters for 6Li + 24Mg, 6Li + 28Si and 6Li + 116Sn scattering systems were obtained by fitting elastic scattering data. Multipole analyses were carried out for inelastic scattering to high lying isoscalar giant resonances with multipolarities L=0 - 3. The results for the ISGMR and ISGQR are in agreement with those obtained with 240 MeV ? scattering, however the agreement for the ISGDR and HEOR is not so good, indicating the uncertainty in extracting these strengths. This work has shown that 240 MeV 6Li scattering is a viable way to study the ISGMR and ISGQR and can be particularly useful in rare isotope studies where 6Li can be used as the target.

Chen, Xinfeng

2008-05-01T23:59:59.000Z

244

A Combined 6,7Li NMR and Molecular Dynamics Study of Li Diffusion in Li2TiO3  

SciTech Connect

Understanding lithium diffusion properties in electrode materials is important for designing rechargeable lithium-ion batteries with improved performance. In this work, the lithium dynamics in layered Li2TiO3 were characterized using a combination of 6,7Li nuclear magnetic resonance (NMR) over a wide temperature range (150 to 500 K), and molecular dynamics (MD) simulations. The 7Li static NMR and stimulated echo experiments show slow and partial lithium diffusion in Li2TiO3. The high-field (21.1 T) 6Li magic angle spinning NMR shows a new tetrahedral lithium site along with the three crystallographic octahedral sites in Li2TiO3 sample. MD simulations predict that lithium can occupy a tetrahedral site if two or more vacancies exist in the vicinity, which may result, for example, from the presence of a Ti defect in the LiTi2 layer. 6Li two-dimensional (2D) exchange NMR experiments show evidence of lithium diffusion between the pure Li and LiTi2 layers along the c axis. Although the 2D exchange NMR data is not sensitive to lithium diffusion in the ab plane, MD simulations show that lithium diffusion in the pure Li layer is equally probable. Combining these results, a detailed picture of the lithium diffusion pathways in Li2TiO3 is presented.

Vijayakumar, M.; Kerisit, Sebastien N.; Yang, Zhenguo; Graff, Gordon L.; Liu, Jun; Sears, Jesse A.; Burton, Sarah D.; Rosso, Kevin M.; Hu, Jian Z.

2009-10-27T23:59:59.000Z

245

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents (OSTI)

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas fired furnances or boilers. Two concentric shells define a combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, A.H.

1982-04-30T23:59:59.000Z

246

Rate-dependent morphology of Li2O2 growth in Li-O2 batteries  

E-Print Network (OSTI)

Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter we develop a nanoscale continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes, based on a theory of electrochemical non-equilibrium thermodynamics originally applied to Li-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory predicts a transition from complex to uniform morphologies of Li2O2 with increasing current. Discrete particle growth at low discharge rates becomes suppressed at high rates, resulting in a film of electronically insulating Li2O2 that limits cell performance. We predict that the transition between these surface growth modes occurs at current densities close to the exchange current density of the cathode reaction, consistent with experimental observations.

Horstmann, B; Mitchell, R; Bessler, W G; Shao-Horn, Y; Bazant, M Z

2013-01-01T23:59:59.000Z

247

Evaluation of Concrete Containing Fly Ash With High Carbon Content and/or Small Amounts of Wood  

Science Conference Proceedings (OSTI)

This report provides a comprehensive database of information on the impacts of the use of high carbon coal ashes and concretes with small amounts of wood ash on the performance of concretes. It is expected these data will support easing the restrictions on the use of high carbon ashes and any wood ash products in concrete in the ASTM standards.

1998-06-25T23:59:59.000Z

248

The Physical and Chemical Properties of Fly Ash from Coal Gasification and Study on Its Recycling Utilization  

Science Conference Proceedings (OSTI)

Aiming at the difficulties in utilization of fly ash from coal gasification, the physical and chemical properties of fly ash were investigated. This research studied recycling utilization on using fly ash as one of cement raw materials for cement clinker. ... Keywords: fly ash, X-ray diffraction (XRD), Scanning Electron Microscope (SEM), recycling utilization

Guohua Qiu; Weiqiang Zeng; Zhenglun Shi; Mengxiang Fang; Zhongyang Luo

2010-12-01T23:59:59.000Z

249

To be published in Waste Management (2010) Bodnan et al. MINERALOGY AND PORE WATER CHEMISTRY OF A BOILER ASH  

E-Print Network (OSTI)

OF A BOILER ASH FROM A MSW FLUIDIZED-BED INCINERATOR F. Bodénan* , D. Guyonnet, P. Piantone, P. Blanc BRGM presents an investigation of the mineralogy and pore water chemistry of a boiler ash sampled from to as "boiler ash", is analogous to what Abbas et al. (2003) refer to as "hopper ash" (see Fig. 1 of Abbas et al

Paris-Sud XI, Université de

250

Leaching of mixtures of biochar and fly ash  

Science Conference Proceedings (OSTI)

Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments. Both the residual char from biomass pyrolysis (biochar) and fly ash from coal combustion have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations. Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and decreases available aluminum. A combination of these benefits likely is responsible for observed increases in yields for crops such as corn and sugarcane. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) than do unamended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way. Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil. Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes. In the present study, we examined the properties of mixtures of biochar, fly ash, and soil and evaluated the leaching of organic carbon and metals from these mixtures. The carbon sorption experiments showed release of carbon from biochar, rather than sorption, except at the highest concentrations in the Biochar HW sample. Similar results were obtained by others for oxidative leaching of bituminous coal, in which more C was released as dissolved C than was oxidized to CO2 by the oxygen in water. We confirmed that both fly ash and two types of biochar (oak char [OKEB], and hardwood [HW] char) exhibited minimal leaching of heavy metals including Cr, Ni, Zn, Ga, and Ag, and no detectable leaching of Pb or Cd (data not shown) under the conditions tested. The Biochar HW had a slightly higher C/N ratio (334) and pH (7.7) than did the Biochar OKEB (284 and 6.5). There was no toxicity exhibited by the fly ash (not shown) or biochar leachates as measured by the Microtox© assay under the conditions tested. In previous results no toxicity was reported in testing the fly ash samples except for one high-pH sample. The most notable leachate component from both types of biochar, but not the fly ash, was organic carbon with the HW biochar leaching less organic carbon than the OKEB biochar (5.71 ppm vs. 59.3 ppm). Alone (in batch sorption experiments), or in mixtures of 90% soil and 10% biochar (column studies), we noted significant loss of carbon from the biochar into soluble components. However, when we added fly ash to the column experiments (80% soil, 10% fly ash, and 10% biochar) we observed significant decreases in the amounts of C leached (20% for HW, and 47% for OKEB). The results indicate that applying a combination of fly ash and biochar may result in maximizing the amount of carbon sequestration in soil while also increasing beneficial soil properties and fertility. The lower amount of carbon leached from the HW biochar compared to the OKEB biochar is likely due to the more recalcitrant form of the carbon in the HW char, due to its preparation at a higher temperature (600 ºC) than the OKEB biochar (450 ºC). High heat treatment temperatures during biochar preparation increase both the total carbon content of the biochar and the proportion of the carbon that is present in fused aromatic rings resistant to chemical and physical degradation.

Palumbo, Anthony V.; Porat, Iris; Phillips, Jana R.; Amonette, James E.; Drake, Meghan M.; Brown, Steven D.; Schadt, Christopher W.

2009-06-22T23:59:59.000Z

251

JV Task 6 - Coal Ash Resources Research Consortium Research  

DOE Green Energy (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of coal combustion by-products (CCBs). CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCB utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program (JSRP), which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCB performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 1998 to 2007 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCBs. CARRC topical reports were prepared on several completed tasks. Specific CARRC 1998B2007 accomplishments included: (1) Development of several ASTM International Standard Guides for CCB utilization applications. (2) Organization and presentation of training courses for CCB professionals and teachers. (3) Development of online resources including the Coal Ash Resource Center, Ash from Biomass in Coal (ABC) of cocombustion ash characteristics, and the Buyer's Guide to Coal-Ash Containing Products. In addition, development of expanded information on the environmental performance of CCBs in utilization settings included the following: (1) Development of information on physical properties and engineering performance for concrete, soil-ash blends, and other products. (2) Training of students through participation in CARRC research projects. (3) Participation in a variety of local, national, and international technical meetings, symposia, and conferences by presenting and publishing CCB-related papers.

Debra Pflughoeft-Hassett; Tera Buckley; Bruce Dockter; Kurt Eylands; David Hassett; Loreal Heebink; Erick Zacher

2008-04-01T23:59:59.000Z

252

Fly Ash and Mercury Oxidation/Chlorination Reactions  

Science Conference Proceedings (OSTI)

Mercury is a known pollutant that has detrimental effect on human health and environment. The anthropogenic emissions of mercury account for 10 to 30% of worldwide mercury emissions. There is a need to control/reduce anthropogenic mercury emissions. Many mercury control technologies are available but their effectiveness is dependent on the chemical form of mercury, because different chemical forms of mercury have different physical and chemical properties. Mercury leaves the boiler in its elemental form but goes through various transformations in the post-combustion zone. There is a need to understand how fly ash and flue gas composition affect speciation, partitioning, and reactions of mercury under the full range of post-combustion zone conditions. This knowledge can then be used to predict the chemical transformation of mercury (elemental, oxidized or particulate) in the post combustion zone and thus help with the control of mercury emissions from coal-burning power plants. To accomplish this goal present study was conducted using five coal fly ashes. These ashes were characterized and their catalytic activity was compared under selected reaction conditions in a fixed bed reactor. Based on the results from these fly ash experiments, three key components (carbon, iron oxide and calcium oxide) were chosen. These three components were then used to prepare model fly ashes. Silica/alumina was used as a base for these model fly ashes. One, two or three component model fly ashes were then prepared to investigate mercury transformation reactions. The third set of experiments was performed with CuO and CuCl2 catalysts to further understand the mercury oxidation process. Based on the results of these three studies the key components were predicted for different fly ash compositions under variety of flue gas conditions. A fixed bed reactor system was used to conduct this study. In all the experiments, the inlet concentration of Hg0(g) was maintained at 35 {micro}g/m3 using a diffusion tube as the source of Hg0(g). All experiments were conducted using 4% O2 in nitrogen mix as a reaction gas, and other reactants (HCl, H2O and SO2, NO2, Br2) were added as required. The fixed bed reactor was operated over a temperature range of 200 to 400 C. In each experiment, the reactor effluent was analyzed using the modified Ontario-Hydro method. After each experiment, fly ash particles were also analyzed for mercury. The results show that the ability of fly ash to adsorb and/or oxidize mercury is primarily dependent on its carbon, iron and calcium content. There can be either one or more than one key component at a particular temperature and flue gas condition. Surface area played a secondary role in effecting the mercury transformations when compared to the concentration of the key component in the fly ash. Amount of carbon and surface area played a key important role in the adsorption of mercury. Increased concentration of gases in the flue gas other than oxygen and nitrogen caused decreased the amount of mercury adsorbed on carbon surface. Mercury adsorption by iron oxide primarily depended on the crystalline structure of iron oxide. {alpha}-Iron oxide had no effect on mercury adsorption or oxidation under most of the flue gas conditions, but ?-iron oxide adsorbed mercury under most of the flue gas conditions. Bromine is a very good oxidizing agent for mercury. But in the presence of calcium oxide containing fly ashes, all the oxidized mercury would be reduced to elemental form. Among the catalysts, it was observed that presence of free lattice chlorine in the catalyst was very important for the oxidation of mercury. But instead of using the catalyst alone, using it along with carbon may better serve the purpose by providing the adsorption surface for mercury and also some extra surface area for the reaction to occur (especially for fly ashes with low surface area).

Sukh Sidhu; Patanjali Varanasi

2008-12-31T23:59:59.000Z

253

LiDAR | Open Energy Information  

Open Energy Info (EERE)

LiDAR LiDAR Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: LiDAR Details Activities (10) Areas (5) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Remote Sensing Techniques Exploration Sub Group: Active Sensors Parent Exploration Technique: Active Sensors Information Provided by Technique Lithology: Stratigraphic/Structural: delineate faults, create high-resolution DEMS, quantify fault kinemaics, develop lineament maps Hydrological: Thermal: Cost Information Low-End Estimate (USD): 300.0030,000 centUSD 0.3 kUSD 3.0e-4 MUSD 3.0e-7 TUSD / sq. mile Median Estimate (USD): 850.0085,000 centUSD 0.85 kUSD 8.5e-4 MUSD 8.5e-7 TUSD / sq. mile High-End Estimate (USD): 1,300.00130,000 centUSD 1.3 kUSD 0.0013 MUSD 1.3e-6 TUSD / sq. mile

254

P LI I CI L I  

Office of Legacy Management (LM)

LI LI I - CI L - I 111 Ir LI C C c c c Ic c L ORNL/RASA-90/8 OAK RIDGE NATIONAL LABORATORY RADIOLOGICAL SURVEY OF THE FORMER BAKER BROTHERSJNC. SITE, 2551-2555 HARLEAU PLACE, TOLEDO,OHIO (BTOOOl) MABAGEO BY MABAGEO BY MAUTIH MARIETTA ENBGY SYSTEM, INC. AWTIH MAftIETTA ENBGY SYSTEM, INC. FOR THE UNITE0 STATES FOR THE UNITE0 STATES OEPARTMENT OF EtdERGY OEPARTMENT OF EtdERGY R. D. Foley L. M. Floyd _-. This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Techni- cal Information, P.O. Box 62, Oak Ridge, TN 37631; prices available from (615) 5766401. PTS 6266401. Available to the public from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Rd., Springfield, VA 22161.

255

Blue Ash, Ohio: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Blue Ash, Ohio: Energy Resources Blue Ash, Ohio: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.2320029°, -84.3782734° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.2320029,"lon":-84.3782734,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

256

Utilization of Biomineralization Processes with Fly Ash for Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Utilization of Biomineralization Processes with Fly Ash Utilization of Biomineralization Processes with Fly Ash for Carbon Sequestration Y. Roh (rohy@ornl.gov; 865-576-9931) T. J. Phelps (phelpstj1@ornl.gov; 865-574-7290) Environmental Sciences Division, Oak Ridge National Laboratory*, Oak Ridge, TN 37831-6036 A. D. McMillan (mcmillanad@ornl.gov; 865-241-4554) R. J. Lauf (laufrj@ornl.gov; 865-574-5176) Metal and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6085 *Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under contract number DE-AC05-00OR22725 Introduction The Department of Energy (DOE) Energy Information Administration estimates atmospheric greenhouse gas releases may exceed 8 billion metric tons by the year 2010 heightening its international environmental concern. Carbon dioxide will dominate the

257

Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Site (SRS) recently cleaned up a 17- Site (SRS) recently cleaned up a 17- acre basin containing coal ash residues from Cold War operations. The American Recovery and Reinvestment Act project was safely completed at a cost of $8.9 million, $2.9 million under budget. The manmade earthen basin received ash from the former R Area Pow- erhouse operations, which ended in 1964. The first of five reactors con- structed at SRS, the R Reactor produced nuclear materials for national defense. Recovery Act funding allowed SRS to accelerate cleanup of the basin and complete the project five years earlier than the target set in a regu- latory schedule. In late 2010, the U.S. Environmental Protection Agency and South Carolina Department of Health and Environmental Control determined the closure met all regulatory requirements after inspection

258

Preventing ash agglomeration during gasification of high-sodium lignite  

Science Conference Proceedings (OSTI)

Various additives were evaluated to assess their ability to prevent ash agglomeration during the gasification of high-sodium lignite. Additives that showed promise in simple muffle furnace tests included meta-kaolin, vermiculite, two types of silica fume, and one type of bauxite. Additives that were tested and rejected included dolomite, calcite, sand flour, kaolinite, fine kaolin, and calcined bauxite. Based on the muffle furnace test results, the meta-kaolin was selected for a follow-on demonstration in a pilot-scale coal gasifier. Pilot-scale testing showed that the addition of coarse (minus 14-mesh, 920-{mu}m mean size) meta-kaolin at a feed rate roughly equivalent to the ash content of the lignite (10 wt %) successfully prevented agglomeration and deposition problems during gasification of high-sodium lignite at a maximum operating temperature of 927{sup o}C (1700{sup o}F). 13 refs., 24 figs., 1 tab.

Robert S. Dahlin; Johnny R. Dorminey; WanWang Peng; Roxann F. Leonard; Pannalal Vimalchand [Southern Research Institute and Southern Company Services, Wilsonville, AL (USA). Power Systems Development Facility

2009-01-15T23:59:59.000Z

259

Coal-ash spills highlight ongoing risk to ecosystems  

SciTech Connect

Two recent large-scale spills of coal combustion waste have highlighted the old problem of handling the enormous quantity of solid waste produced by coal. Both spills happened at power plants run by the Tennessee Valley Authority (TVA). In December 2008 a holding pond for coal ash collapsed at a power plant in Kingstom, Tenn., releasing coal-ash sludge onto farmland and into rivers: in January 2009 a break in a pipe removing water from a holding pond for gypsum caused a spill at Widows Creek Fossil Plant in Stevenson, Ala. The article discusses the toxic outcome of such disasters on ecosystems, quoting work by Willaim Hopkins at Virginia Polytechnic Institute and State University and recommendations and reports of the US EPA. 2 photos.

Chatterjee, R.

2009-05-01T23:59:59.000Z

260

Microsoft Word - CX-Ashe-CGSFiberInstallation_WEB.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

5, 2011 5, 2011 REPLY TO ATTN OF: KEP-4 SUBJECT: Environmental Clearance Memorandum Debbie Ruckwardt Electrical Engineer - TEP-CSB-1 Proposed Action: Installing fiber optic cables between Bonneville Power Administration's (BPA) Ashe Substation and Energy Northwest's Columbia Generating Station (CGS). Budget Information: Work Order # 00261540 PP&A Project No.: PP&A 1864 Categorical Exclusion Applied (from Subpart D, 10 C.F.R. Part 1021): B1.3, Routine maintenance activities...for structures, rights of way, infrastructures such as roads, equipment... routine maintenance activities, corrective....are required to maintain...infrastructures...in a condition suitable for a facility to be used for its designed purpose. Location: The project takes place between BPA's Ashe Substation and Energy Northwest's

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Ash Fork, Arizona: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Ash Fork, Arizona: Energy Resources Ash Fork, Arizona: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 35.2250114°, -112.4840675° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.2250114,"lon":-112.4840675,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

262

A Laboratory Method for Ash Particle Size Determination  

Science Conference Proceedings (OSTI)

Increasing stringent particulate emissions limits are putting more pressure on power producers to improve electrostatic precipitator (ESP) performance. In an effort to select the most cost effective upgrade option, many power plant engineers are using ESP computer models to estimate the impact of the available options. These models are sensitive to the fly ash particle size distribution used in the calculations, but the actual distribution is rarely known. Furthermore, measuring this distribution has, in...

2005-03-23T23:59:59.000Z

263

Ash Properties Analysis from Co-Firing Biomass and Coal  

Science Conference Proceedings (OSTI)

Power plant interest in renewable energy has been increasing, especially in response to legislative requirements to include renewables in the generation mix. One promising renewable strategy is co-firing biomass with coal, in pulverized coal- (PC-) fired units. The objective of this research is to provide quantitative data on full-scale test burn samples to demonstrate changes in ash characteristics and to identify anomalies affecting particulate material (PM) collection efficiency that result from co-fi...

2011-09-06T23:59:59.000Z

264

First-principles investigation of Li intercalation kinetics in phospho-olivines  

E-Print Network (OSTI)

This thesis focuses broadly on characterizing and understanding the Li intercalation mechanism in phospho-olivines, namely LiFePO? and Li(Fe,Mn)PO?, using first-principles calculations. Currently Li-ion battery technology ...

Malik, Rahul

2013-01-01T23:59:59.000Z

265

A new way to stabilize fly ash from municipal incinerators  

Science Conference Proceedings (OSTI)

Heavy metals and toxic chlorinated organics, added to very low grain-size distributions, make fly ashes from municipal incinerators a very hazardous waste. For their disposal, the present general trend is, not only to stabilize chemically the ashes, i.e., to reduce the leachability of the toxic substances, but also to stabilize them mechanically, i.e., to convert them into massive, resistant, and unleachable solids. This paper describes various stabilization methods used on representative European fly ash samples, which led to the development of a new stabilization technique taking place in four stages: elimination of the alkali chlorides by dissolution; addition of a moderate quantity of phosphoric acid; calcination; and solidification with Portland clinker or cement. The principal advantages of the process are as follows: the polychlorodibenzodioxins-polychlorodibenzofurans are destroyed, the reactivity of the heavy metals is reduced drastically, the final solids have satisfactory mechanical properties, and the increase in weight of the waste to be disposed of does not exceed one fourth. Comparative results of TCLP extraction tests are presented.

Derie, R. [Free Univ. of Brussels (Belgium). Dept. of Ore Dressing

1996-12-31T23:59:59.000Z

266

Mesoscale Phase Distribution in Li-ion Battery Electrode Materials...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science SSRL Phone List People Search Maps Mesoscale Phase Distribution in Li-ion Battery Electrode Materials Friday, May 31, 2013 Li-ion batteries are regarded as key devices...

267

Li ion Motors Corp formerly EV Innovations Inc | Open Energy...  

Open Energy Info (EERE)

Page Edit with form History Facebook icon Twitter icon Li ion Motors Corp formerly EV Innovations Inc Jump to: navigation, search Name Li-ion Motors Corp (formerly EV...

268

Microsoft Word - LiFe battery highlight long bh  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Highlight - May 2013 Mesoscale Phase Distribution in Li-ion Battery Electrode Materials Li-ion batteries are regarded as key devices in the effort to develop efficient...

269

The utility of LiDAR for landscape biodiversity assessment.  

E-Print Network (OSTI)

??The potential of LiDAR to inform landscape biodiversity assessments is investigated. The objectives of this research are to examine how LiDAR discrete return and full… (more)

Miura, N

2010-01-01T23:59:59.000Z

270

LiBeB and Big Bang Nucleosynthesis  

E-Print Network (OSTI)

The dual origin of population II Li7, in both big bang nucleosynthesis and galactic cosmic-ray nucleosynthesis is discussed. It is argued that with additional Li6 data, stringent limits on the degree of Li7 depletion can be obtained. Li7 depletion is also constrained by the concordance of big bang predictions with observational determinations of light element abundances. Stringent limits can also be obtained for a fixed primordial D/H abundance.

Keith A. Olive; Brian D. Fields

1999-02-20T23:59:59.000Z

271

Ca, Li and Mg Based Lightweight Intermetallics for Hydrogen Storage  

Science Conference Proceedings (OSTI)

... Nanoparticle Catalysts for Hydrogen Production from Methanol and Methane · Ca, Li and Mg Based Lightweight Intermetallics for Hydrogen Storage.

272

Superheater Tube Corrosion in Wood Gasifier Ash Deposits  

DOE Green Energy (OSTI)

The upper operating temperature of tubes in heat exchangers/steam generators is strongly influenced by the degradation that can occur because of the reaction of the exchanger/generator tubing with the deposits that accumulate on the surface of the tubes. In fact, severe corrosion has been observed in some biomass fired systems, particularly with elevated potassium and chlorine concentrations in the deposits. Wood gasifiers have recently been and are currently being constructed at several sites in North America. In these systems, the syngas is burned to produce steam and the performance of the heat exchanger tubes under ash deposits is of great concern. As temperatures of the heat exchangers are increased in an effort to increase their operating efficiency, the performance of the tubes is of greater interest. The corrosion behavior of alloy steel tubes as a function of temperature has been investigated by exposing samples of selected alloys to ash collected from the steam generator fired by syngas produced in wood gasifiers. This study compares corrosion rates from laboratory exposures of synthesis gas and ash at 500 C and 600 C. This study investigated the material performance of four ferritic steels and one austenitic steel exposed to conditions expected on the fireside of a wood gasifier. The purpose of this study was to identify an effective method for determining material performance for samples exposed to both the process gas and the fly ash that is typically observed within the steam generator for times up to 1000 hours. Mass changes were measured for all of the samples, but this information can be misleading concerning material performance due to the difficulty in sufficiently cleaning the samples after exposure in the ash. Therefore, small cross sections of the samples were collected and imaged using optical microscopy. Oxide thicknesses were measured along with metal losses. The metal loss information provides a clear indication of material performance. The metal loss rates for the ferritic steels at 500 C were almost half of those observed at 600 C and the rates decreased with increasing exposure time. It was also reported that the metal loss rates generally decrease with increasing chromium concentration.

Bestor, Michael A [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

2011-01-01T23:59:59.000Z

273

Li4Ti5O12 as an anode material for Li ion batteries in situ XRD and XPS studies.  

E-Print Network (OSTI)

?? This thesis examines parts of the kinetics and performance in Li-battery cells using lithium titanate anodes and lithium manganese oxide cathodes. Lithium titanate (Li4Ti5O12)… (more)

Nordh, Tim

2013-01-01T23:59:59.000Z

274

Li Diffusion and High-Voltage Cycling Behavior of Thin-Film LiCoO2 Cathodes  

DOE Green Energy (OSTI)

Mass transport and thermodynamic properties of Li{sub x}CoO{sub 2} were studied by the potentiostatic intermittent titration technique (PITT) using solid-state thin-film batteries that provide a well-defined diffusion geometry. Both the chemical diffusion coefficient and the thermodynamic factor have minima at the phase boundaries of the Li/vacancy ordered phase ''Li{sub 0.5}CoO{sub 2}''. The self-diffusion coefficient of Li has a minimum at x = 0.5 associated with the Li/vacancy ordering. As the degree of ordering increases, the nonmonotonic variations become more pronounced when approaching x = 0.5 in Li{sub x}CoO{sub 2}. We also show that thin-film LiCoO{sub 2} cathodes having grains of sub-micrometer size combined with the Li upon electrolyte exhibit excellent capacity retention when charged up to 4.5 V.

Jang, Y.-I.

2001-10-02T23:59:59.000Z

275

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Accomplish Cleanup of Second Cold War Coal Ash Accomplish Cleanup of Second Cold War Coal Ash Basin Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin American Recovery and Reinvestment Act workers recently cleaned up a second basin containing coal ash residues from Cold War operations at the Savannah River Site (SRS). About $24 million from the Recovery Act funded the environmental restoration project, allowing SRS to complete the project at least five years ahead of schedule. The work is part of a larger Recovery Act cleanup of the P Area scheduled for completion by the end of September 2011. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin More Documents & Publications Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin Recovery Act Workers Add Time Capsule Before Sealing Reactor for Hundreds

276

UMass-Li-air-final-SUBMITTED.pptx  

NLE Websites -- All DOE Office Websites (Extended Search)

u, Z hichuan X u, H ubert G asteiger, S huo C hen, K imberly H amad---Schifferli, a nd Y ang S hao---Horn, J ACS, (2010) Li 2 O 2 C oats t he S urface o f C arbon a nd L i 2 CO 3...

277

The Future of Fusion Jiangang Li (j_li@ipp.ac.cn)  

E-Print Network (OSTI)

: 5,2kW JP: 6.3kW China:1.5kW (growing 10% /y) India: 0.7kW Bangladesh: 210 Watts RenewableThe Future of Fusion Jiangang Li (j_li@ipp.ac.cn) Institute of Plasma Physics, CAS, Hefei, China 38MillionTCE Coal Oil Gas Nuclear Renewable 16.13 Billion TCE 29.01 Billion TCE 2005--2050average annual

278

Electrostatic Precipitator Performance Modeling of High Carbon Ash Using EPRI's ESPM  

Science Conference Proceedings (OSTI)

To meet reduced nitrogen oxide (NOX) emission limits, many power producers installed low-NOX combustion systems that raised the level of carbon in the ash. However, carbon can be difficult to collect in an electrostatic precipitator and, consequently, the particulate emissions from many affected units increased. EPRI initiated this study to better understand carbon capture in electrostatic precipitators (ESPs), improve collection of high carbon ashes, and predict the collection of such ashes with its ESP...

2007-03-19T23:59:59.000Z

279

Development of New Industrial Ashalloy Material Using Fly-Ash Cenospheres  

Science Conference Proceedings (OSTI)

Metal matrix composites can provide improved functional properties compared to solid metal castings, while saving production energy and raw material costs in the process. In particular, ash-derived metal matrix composites can provide utilities a high value-added market for their coal fly ash. This report describes research on a promising manufacturing process for one such application -- pressure infiltration techniques to produce lead-ash composites for automotive battery applications.

1997-12-02T23:59:59.000Z

280

Mercury Emissions from Curing Concretes that Contain Fly Ash and Activated Carbon Sorbents  

Science Conference Proceedings (OSTI)

This report presents new laboratory data on the release of mercury from concrete containing fly ash and powdered activated carbon sorbents used to capture mercury. The concretes studied in this project were made with fly ashes from lignite and subbituminous coal, including fly ashes containing powdered activated carbon (PAC). Minute quantities of mercury were emitted from five concretes during the standard 28-day curing process and throughout an additional 28 days of curing for two of these concretes. Ge...

2006-09-07T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Fly Ash Carbon Burn-Out at TVA's Colbert and Shawnee Stations: Site Specific Application Study  

Science Conference Proceedings (OSTI)

Fly ash beneficiation using Carbon Burn-Out (CBO) technology offers the opportunity to market fly ash that was previously landfilled. This site application study of beneficiating pulverized coal boiler fly ash at Tennessee Valley Authority's Colbert and Shawnee Stations indicates this process is a cost effective solution for decreasing solid waste disposal, increasing landfill life, improving boiler heat rate, and generating a positive revenue stream.

1996-07-02T23:59:59.000Z

282

Assessment of Impacts of NOx Reduction Technologies on Coal Ash Use: Volume 1: North American Perspective  

Science Conference Proceedings (OSTI)

This two-volume report provides documentation about physical and chemical effects combustion and post-combustion low-NOx technologies have on coal fly ash. U.S., European, and, to a lesser degree, Japanese experience is discussed. The report assesses the effect of low-NOx technologies on fly ash markets in a general manner. Options for beneficiating fly ash for specific markets also appear.

1997-01-04T23:59:59.000Z

283

Use of High Carbon Fly Ash as a Component of Raw Mix for Cement Manufacture  

Science Conference Proceedings (OSTI)

In the production of concrete, fly ash often serves as a supplementary cementing material, but some fly ashes may not be suitable for this use due to excess unburned carbon. This report presents the results of a literature investigation, bench-scale laboratory study, and pilot-scale tests of the feasibility of using such high carbon fly ashes in the manufacture of portland cement.

1998-06-30T23:59:59.000Z

284

Geochemical Investigation of Pyrite Codisposal with Sluiced Fly Ash and Implications for Selecting Remedial Actions  

Science Conference Proceedings (OSTI)

Oxidation of pyrite results in acid generation as well as the release of sulfate, iron, and other metals to solution. When pyritic coal mill rejects are codisposed with coal ash, pyrite oxidation and the subsequent interaction of oxidation products with the ash primarily control leachate quality. The geochemistry of the pyrite/ash system has implications for management and remediation actions at codisposal facilities. Utilities can use the results of this research to make decisions regarding such facilit...

1995-08-08T23:59:59.000Z

285

International School on LiDAR Technology Laboratory Manual for LiDAR Data Processing  

E-Print Network (OSTI)

impart hands-on-training on working with LiDAR data. A duration of 12 hours has been assigned for data processing, which is spread over four days during the school. The laboratoryisplannedtobeconductedattheComputerCentreofIITKanpurwhereeach participant would be able to learn on his/her own. The LiDAR data processing exercises have been designed around the TerraSolid software (Terrascan, Terramatch, Terramodeller and Terraphoto). This manual consists of detailed instructions for LiDAR data processing. The instructions have been divided into four parts. The first part deals with importing raw LiDAR data and trajectory within Terrascan, creation of projects and different kinds of visualizations. In the second part, LiDAR data are corrected for the inherent errors using the overlap analysis. The corrected data are passed into the classification process which is covered in the third part of the manual. The use of routines and macros is shown to classify LiDAR data into ground points, low points, below surface points, building points etc. At this stage anorthophotograph is also employed to help in the classification process. Finally, the fourth part of laboratory manual shows how to generate vector models for

Bapna Ravish; Ghosh Suddhasheel; Biswas Susham; Y Surya Aditya

2008-01-01T23:59:59.000Z

286

Thermal Stability of Li-Ion Cells  

DOE Green Energy (OSTI)

The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial SONY cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity in the open circuit cell condition. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC). Microcalorimetry was used to measure the time dependence of heat generating side reactions also as a function of SOC. Components of cells were measured using differential scanning calorimetry (DSC) to study the thermal reactivity of the individual electrodes to determine the temperature regimes and conditions of the major thermal reactions. Thermal decomposition of the SEI layer at the anodes was identified as the initiating source for thermal runaway. The cells with Li{sub x}CoO{sub 2} cathodes showed greater sensitivity to SOC and higher accelerating heating rates than seen for the cells with Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2}cathodes. Lower temperature reactions starting as low as 40 C were also observed that were SOC dependent but not accelerating. These reactions were also measured in the microcalorimeter and observed to decay over time with a power-law dependence and are believed to result in irreversible capacity loss in the cells.

ROTH,EMANUEL P.

1999-09-17T23:59:59.000Z

287

Thermal Barrier Coatings Resistant to Attack by Molten Fly Ash in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Thermal Barrier Coatings Resistant to Attack by Molten Fly Ash in Integrated Gas Combined Cycle Turbine Engines. Author(s), Andrew D.

288

INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS  

SciTech Connect

This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

2000-11-01T23:59:59.000Z

289

Optimum Condition of Vanadium Recovery from Power Plant Fly-ash ...  

Science Conference Proceedings (OSTI)

Abstract Scope, In this study, recovery of vanadium from power plant fly-ash was developed using a hydro metallurgical process consisted of acidic leaching ...

290

The Leaching Behavior of Heavy Metals in MSWI Bottom Ash ... - TMS  

Science Conference Proceedings (OSTI)

May 1, 2007 ... The Leaching Behavior of Heavy Metals in MSWI Bottom Ash by Carbonation Reaction with Diffeent Water Content by Nam-Il Um, Kwang-Suk ...

291

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus...  

Open Energy Info (EERE)

.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search GEOTHERMAL...

292

Removal of Thiosalts using Biomass Ash from Pulp and Paper Mill ...  

Science Conference Proceedings (OSTI)

Biomass ash used in this study is collected from Corner Brook Pulp and Paper Mill, NL and Zellstoff Celgar Mill, BC and is characterized to understand the ...

293

and Se(VI) Ions onto Biomass Ash - Programmaster.org  

Science Conference Proceedings (OSTI)

Biomass ash used in this study is collected from Zellstoff Celgar Mill, British Columbia, Canada and is characterized to determine the physico-chemical ...

294

Speciation of Selenium, Arsenic, and Zinc in Class C Fly Ash  

Science Conference Proceedings (OSTI)

A major environmental concern associated with coal fly ash is the mobilization of trace elements that may contaminate water. To better evaluate proper use of fly ash, determine appropriate disposal methods, and monitor postdisposal conditions, it is important to understand the speciation of trace elements in fly ash and their possible environmental impact. The speciation of selenium, arsenic, and zinc was determined in five representative Class C fly ash samples from combustion of sub-bituminous Powder River Basin coal using synchrotron-based X-ray absorption spectroscopy to provide an improved understanding of the mechanisms of trace element association with the fly ash. Selenium in all fly ash samples occurs predominantly as Se(IV), with the exception of one sample, in which there was a minor amount of Se(0). Se(0) is likely associated with the high content of unburned coal in the sample. Arsenic exists in the fly ash as a single phase most consistent with calcium pyroarsenate. In contrast, zinc occurs as two distinct species in the silicate glass matrix of the fly ash. This work demonstrates that residual carbon in fly ash may reduce potential Se mobility in the environment by retaining it as less soluble elemental Se instead of Se(IV). Further, this work suggests that As and Zn in Class C fly ash will display substantially different release and mobilization behaviors in aquatic environments. While As release will primarily depend upon the dissolution and hydrolysis of calcium pyroarsenate, Zn release will be controlled by the dissolution of alkaline aluminosilicate glass in the ash.

Luo, Yun; Giammar, Daniel E.; Huhmann, Brittany L.; Catalano, Jeffrey G. (WU)

2011-11-17T23:59:59.000Z

295

Growth and elemental accumulation by canola on soil amended with coal fly ash  

SciTech Connect

To explore the agronomic potential of an Australian coal fly ash, we conducted two glasshouse experiments in which we measured chlorophyll fluorescence, CO{sub 2} assimilation (A), transpiration, stomatal conductance, biomass accumulation, seed yield, and elemental uptake for canola (Brassica napus) grown on soil amended with an alkaline fly ash. In Experiment 1, application of up to 25 Mg/ha of fly ash increased A and plant weight early in the season before flowering and seed yield by up to 21%. However, at larger rates of ash application A, plant growth, chlorophyll concentration, and yield were all reduced. Increases in early vigor and seed yield were associated with enhanced uptake of phosphorus (P) by the plants treated with fly ash. Fly ash application did not influence accumulation of B, Cu, Mo, or Zn in the stems at any stage of plant growth or in the seed at harvest, except Mo concentration, which was elevated in the seed. Accumulation of these elements was mostly in the leaves, where concentrations of Cu and Mo increased with any amount of ash applied while that of B occurred only with ash applied at 625 Mg/ha. In Experiment 2, fly ash applied at 500 Mg/ha and mixed into the whole 30 cm soil core was detrimental to growth and yield of canola, compared with restricting mixing to 5 or 15 cm depth. In contrast, application of ash at 250 Mg/ha with increasing depth of mixing increased A and seed yield. We concluded that fly ash applied at not more than 25 Mg/ha and mixed into the top 10 to 15 cm of soil is sufficient to obtain yield benefits.

Yunusa, I.A.M.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Murray, B.R.; Nissanka, S.P. [University of Technology Sydney, Sydney, NSW (Australia)

2008-05-15T23:59:59.000Z

296

Impedance studies on Li-ion cathodes  

DOE Green Energy (OSTI)

This paper describes the author's 2- and 3-electrode impedance results of metal oxide cathodes. These results were extracted from impedance data on 18650 Li-ion cells. The impedance results indicate that the ohmic resistance of the cell is very nearly constant with state-of-charge (SOC) and temperature. For example, the ohmic resistance of 18650 Li-ion cells is around 60 m{Omega} for different SOCS (4.1V to 3.0V) and temperatures from 35 C to {minus}20 C. However, the interfacial impedance shows a modest increase with SOC and a huge increase of between 10 and 100 times with decreasing temperature. For example, in the temperature regime (35 C down to {minus}20 C) the overall cell impedance has increased from nearly 200 m{Omega} to 8,000 m{Omega}. Most of the increase in cell impedance comes from the metal oxide cathode/electrolyte interface.

NAGASUBRAMANIAN, GANESAN

2000-04-17T23:59:59.000Z

297

Development of an ash particle deposition model considering build-up and removal mechanisms  

SciTech Connect

Slagging and fouling on heat exchanger surfaces in power boilers fired with fossil fuels and fuel mixtures has a significant influence on boiler efficiency and availability. Mathematical modelling has long been considered a suitable method to assist boiler operators to determine optimized operating conditions for an existing furnace. The ultimate goal in ash deposition prediction is hereby the determination of the total amount of material deposited and hence the determination of the total reduction in efficiency. Depending on the fuels fired the total deposited mass is a combination of ash particle deposition and ash particle erosion due to non-sticky particles. The novel ash particle deposition model presented in this work considers deposition of sticky ash particles, cleansing of deposit by non-sticky sand particles and sticking of sand due to contact with sticky ash. The steady-state modelling results for the total amount of ash deposited on the deposition probe of an entrained flow reactor presented in this work agree well with the experimental data. Only at very high fractions of sand added as non-sticky material, a significant influence of the sand on the overall mass deposited was found. Since the model considers sticking of non-sticking sand due to contact with sticky ash, the fraction of sand deposited on the probe was especially studied. Using a correction factor to consider the influence of operating time on the steady-state simulations led to good agreement between simulations and experimental data. 12 refs., 10 figs.

Kjell Strandstroem; Christian Muellera; Mikko Hupa [Abo Akademi Process Chemistry Centre, Abo (Finland)

2007-12-15T23:59:59.000Z

298

Release of Mercury During Curing of Concrete Containing Fly Ash and Mercury Sorbent Material  

Science Conference Proceedings (OSTI)

This report provides laboratory data on mercury release during the initial curing stage of concrete made with fly ash or mixtures of fly ash and activated carbon containing mercury. These experiments suggest that mercury is not released from these concretes during initial curing.

2002-12-09T23:59:59.000Z

299

Research Summary RECOAL: Reintegration of coal ash disposal sites and mitigation  

E-Print Network (OSTI)

and Herzegovina; UBAL University of Banja Luka, Bosnia and Herzegovina; FAZ University of Zagreb, Croatia; BTUC risks of farmed and barren alkaline coal ash landfills in Tuzla, Bosnia and Herzegovina. Environmental its research on the thermo-electric plant (TEP) and associated coal ash sites at Tuzla, Bosnia

300

Quantifying the availability and the stability of trace cationic elements in fly ash  

E-Print Network (OSTI)

-Products Associated with Coal Mining Interactive Forum: Southern Illinois University at Carbondale, Carbondale, IL in this paper to deter- mine these parameters for model elements Cu(II), Cd(II), and Ni(II) in fly ash 50 mM EDTA extraction. Ã? 2006 Elsevier Ltd. All rights reserved. 1. Introduction Coal fly ash has

Ragsdell, Kenneth M.

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Use of High-Calcium Fly Ash in Cement-Based Construction Materials  

E-Print Network (OSTI)

in blended cements with minimum (less than 10%) portland cement in the blend. Keywords: Fly ash; concrete impact assessments. INTRODUCTION #12;3 Coal is the most widely used source of energy for power production, total coal ash production in the world was estimated to be 600 million tons, of which 100 million tons

Wisconsin-Milwaukee, University of

302

Use of Ash from the Incineration of Urban Garbage into Clayey ...  

Science Conference Proceedings (OSTI)

The waste is a type of fly-ash resulting from the incineration of a selected part of urban ... Analysis of Carbon Fiber Recovered from Optimized Processes of ... Clayey Ceramic Incorporated with Powder from the Sintering Plant of a ... Influence of Fly Ash and Fluorgypsum on Hydration Heat and Mortar Strength of Cement.

303

Resuspension of Relic Volcanic Ash and Dust from Katmai: Still an Aviation Hazard  

Science Conference Proceedings (OSTI)

Northwest winds were strong enough to continuously resuspend relic volcanic ash from the Katmai volcano cluster and the Valley of Ten Thousand Smokes on 20–21 September 2003. The ash cloud reached over 1600 m and extended over 230 km into the ...

David Hadley; Gary L. Hufford; James J. Simpson

2004-10-01T23:59:59.000Z

304

Rapid response to the Chaiten eruption, Chile, May 2008: ash fallout and impact  

E-Print Network (OSTI)

Rapid response to the Chaiten eruption, Chile, May 2008: ash fallout and impact David Pyle AGU, 90 (24), 205-7, 16 June 2009. #12;Satellite imagery records widespread ash fallout across central eruption of rhyolite since Katmai (1912). #12;Thick fallout deposits near Chaiten volcano (January 2009

305

Fly Ash Design Manual for Road and Site Applications: Volumes 1 and 2  

Science Conference Proceedings (OSTI)

This two-volume design manual describes the use of fly ash as a construction material in high-volume applications like structural fills, highway embankments, grouting, roller-compacted concrete, and land reclamation. The engineering data and construction procedures presented should help coal ash managers and power plant managers incorporate such applications in by-product management plans.

1992-04-01T23:59:59.000Z

306

Fly Ash Design Manual for Road and Site Applications: Volumes 1 and 2  

Science Conference Proceedings (OSTI)

This two-volume design manual describes the use of fly ash as a construction material in high-volume applications like structural fills, highway embankments, grouting, roller-compacted concrete, and land reclamation. The engineering data and construction procedures presented should help coal ash managers and power plant managers incorporate such applications in by-product management plans.

1992-06-01T23:59:59.000Z

307

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network (OSTI)

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

308

Effect of particle size and volume fraction on tensile properties of fly ash/polyurea composites  

E-Print Network (OSTI)

particles. In addition, the composites filled with 20% fly ash became softer. These samples showed lower, composites, tensile properties 1. INTRODUCTION Fly ash, a waste by-product generated abundantly in electric processibility of the filled materials5 . Furthermore, as a waste by-product, its usage decreases the overall

Nemat-Nasser, Sia

309

High-Volume Fly Ash Utilization Projects in the United States and Canada: Second Edition  

Science Conference Proceedings (OSTI)

Fly ash--an increasing disposal problem for utilities operating coal-fired power plants--has considerable unrealized potential as a construction material. In a wide-ranging survey, this study documented more than 250 U.S. and Canadian construction projects employing fly ash in high volume for backfill, landfill, hydraulic fill, embankments, pavement base courses, soil amendment, subgrade stabilization, and grout.

1986-02-24T23:59:59.000Z

310

488-D Ash Basin Vegetative Cover Treatibility Study  

SciTech Connect

The 488-D Ash Basin is an unlined containment basin that received ash and coal reject material from the operation of a powerhouse at the USDOE's Savannah River Site, SC. They pyretic nature of the coal rejects has resulted in the formation of acidic drainage (AD), which has contributed to groundwater deterioration and threatens biota in down gradient wetlands. Establishment of a vegetative cover was examined as a remedial alternative for reducing AD generation within this system by enhanced utilization of rainwater and subsequent non-point source water pollution control. The low nutrient content, high acidity, and high salinity of the basin material, however, was deleterious to plant survivability. As such, studies to identify suitable plant species and potential adaptations, and pretreatment techniques in the form of amendments, tilling, and/or chemical stabilization were needed. A randomized block design consisting of three subsurface treatments (blocks) and five duplicated surface amendments (treatments) was developed. One hundred inoculated pine trees were planted on each plot. Herbaceous species were also planted on half of the plots in duplicated 1-m2 beds. After two growing seasons, deep ripping, subsurface amendments and surface covers were shown to be essential for the successful establishment of vegetation on the basin. This is the final report of the study.

Barton, Christopher; Marx, Don; Blake, John; Adriano, Domy; Koo, Bon-Jun; Czapka, Stephen

2003-01-01T23:59:59.000Z

311

Characterization of Slag, Fly Ash and Portland Cement for Saltstone  

SciTech Connect

Batch-to-batch variability in the chemical and physical properties of the fly ash, slag and portland cement (binders) will be an ongoing concern over the many years that salt waste from Tank 50 will be processed into grout at the Saltstone Processing Facility. This batch-to-batch variability in the properties of the binder materials translates to variability in the fresh and cured properties of Saltstone. Therefore, it is important to quantify the batch-to-batch variability of the binder materials and the resultant variation in grout properties. This report is the starting point for that process by providing the baseline (reference point) binder properties to which future batches of binder materials can be compared. For this characterization effort, properties of fly ash, slag and portland cement were obtained and documented in this report. These properties included particle size distribution by laser light scattering and dry sieving, particle size and morphology by scanning electron microscopy, true, aerated and tapped densities, chemical composition, rheological properties of the water based slurries made from individual binder material, and volatility through thermogravimetric analysis and differential thermal analysis. The properties presented in this report also provide a baseline data set to assist in problem solving efforts when or if unanticipated and/or unwanted processing events occur at the Saltstone Processing Facility.

Harbour, J

2006-02-01T23:59:59.000Z

312

Use of ash from municipal solid waste combustion. Final report  

DOE Green Energy (OSTI)

This report details the results of efforts to integrate municipal solid waste combustion ash into a high strength portland cement concrete matrix comprised of multiple waste materials. The material developed by this research was to be used to construct a large underground storage vault to house the Friendly Mobile Barrier, a safety barrier system for use at highway crossings for the high speed rail system. The subcontractor, Environmental Solutions, Inc., of Richmond, Virginia, worked with researchers at Pennsylvania State University and the State University of New York--Stony Brook to develop and test the material. The result of this work is a portland cement concrete matrix which utilizes 80.01% recycled materials, and a field-applicable method for incorporating MSW ash as a component at volumes up to 9.78%. Twenty-eight day strengths of over 4000 psi were achieved, with 315 day strengths of 6500 psi. All structural, chemical and environmental testing showed the material to be competitive with conventional concrete.

NONE

1997-07-01T23:59:59.000Z

313

In situ analysis of ash deposits from black liquor combustion  

DOE Green Energy (OSTI)

Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

1996-05-01T23:59:59.000Z

314

Argonne CNM HighlightL Hard X-ray characterization of fly ash geopolymers  

NLE Websites -- All DOE Office Websites (Extended Search)

Hard X-ray characterization of fly ash geopolymers Hard X-ray characterization of fly ash geopolymers Calcium Map Calcium map of an activated fly ash geopolymer displays regions of high calcium concentration (circled). Their distribution suggests localization as a discrete calcium-rich phase within the lower-calcium aluminosilicate geopolymer gel. Use of the Hard X-Ray Nanoprobe (HXN) has provided the first access to the nature of heterogeneity in real fly ash-derived geopolymers at the nanoscale. Direct evidence of the formation of discrete high-calcium nanometer-sized particles within a hydroxide-activated geopolymer synthesized from a low-calcium fly ash has been obtained using HXN fluorescence characterization. Additionally, the team of CNM users from the University of Melbourne, the Universidad del Valle of Colombia, and the

315

pH-dependent leaching of dump coal ash - retrospective environmental analysis  

Science Conference Proceedings (OSTI)

Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

2009-07-01T23:59:59.000Z

316

Mercury retention by fly ashes from coal combustion: Influence of the unburned carbon content  

Science Conference Proceedings (OSTI)

The objective of this study was to evaluate the effect of unburned carbon particles present in fly ashes produced by coal combustion on mercury retention. To achieve this objective, the work was divided into two parts. The aim of the first part of the study was to estimate the amount of mercury captured by the fly ashes during combustion in power stations and the relationship of this retention to the unburned carbon content. The second part was a laboratory-scale study aimed at evaluating the retention of mercury concentrations greater than those produced in power stations by fly ashes of different characteristics and by unburned carbon particles. From the results obtained it can be inferred that the unburned carbon content is not the only variable that controls mercury capture in fly ashes. The textural characteristics of these unburned particles and of other components of fly ashes also influence retention.

Lopez-Anton, M.A.; Diaz-Somoano, M.; Martinez-Tarazona, M.R. [CSIC, Oviedo (Spain)

2007-01-31T23:59:59.000Z

317

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin American Recovery and Reinvestment Act workers recently cleaned up a second basin containing coal ash residues from Cold War operations at the Savannah River Site (SRS). About $24 million from the Recovery Act funded the environmental restoration project, allowing SRS to complete the project at least five years ahead of schedule. The work is part of a larger Recovery Act cleanup of the P Area scheduled for completion by the end of September 2011. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin More Documents & Publications EIS-0220: Final Environmental Impact Statement EIS-0220: Final Environmental Impact Statement

318

Electrochemical Performances of LiMnPO4 Synthesized from Non-Stoichiometric Li/Mn Ratio  

Science Conference Proceedings (OSTI)

In this paper we report the influences of the initial lithium content on the structural, electrochemical and magnetic properties of nonstoichiometric LixMnPO4 (0.5?x?1.2) nano-particles. It has been revealed Mn2P2O7 is the main impurity when Li1.0. The different functions of Mn2P2O7 and Li3PO¬4 impurities in the non-stoichiometric compounds have been investigated systematically. At a slow rate of C/50 the reversible capacity of both Li0.5MnPO4 and Li0.8MnPO4 increases with cycling indicating a gradual activation of more sites to accommodate a reversible diffusion of Li+ ions which may be related to the interaction between Mn2P2O7 and LiMnPO4 nanoparticles. Among all the different compositions, Li1.1MnPO4 exhibits the most stable cycling ability probably due to the existence of a trace amount of Li3PO4 impurity which functions as a solid state electrolyte on the surface. The magnetic properties and X-ray absorption spectroscopy (XAS) of MnPO4?H2O precursor, pure and carbon coated LiMnPO4 and all the other non-stoichiometric LixMnPO4 are also investigated to identify the key steps to prepare a high performance LiMnPO4.

Xiao, Jie; Chernova, Natalya; Upreti, Shailesh; Chen, Xilin; Li, Zheng; Deng, Zhiqun; Choi, Daiwon; Xu, Wu; Nie, Zimin; Graff, Gordon L.; Liu, Jun; Whittingham, M. S.; Zhang, Jiguang

2011-09-12T23:59:59.000Z

319

Feasible experimental study on the utilization of a 300 MW CFB boiler desulfurizating bottom ash for construction applications  

SciTech Connect

CFB boiler ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. The disposal in landfills has been the most common means of handling ash in circulating fluidized bed boiler power plants. However for a 300 MW CFB boiler power plant, there will be 600,000 tons of ash discharged per year and will result in great volumes and disposal cost of ash byproduct. It was very necessary to solve the utilization of CFB ash and to decrease the disposal cost of CFB ash. The feasible experimental study results on the utilization of the bottom ashes of a 300 MW CFB boiler in Baima power plant in China were reported in this paper. The bottom ashes used for test came from the discharged bottom ashes in a 100 MW CFB boiler in which the anthracite and limestone designed for the 300 MW CFB project was burned. The results of this study showed that the bottom ash could be used for cementitious material, road concrete, and road base material. The masonry cements, road concrete with 30 MPa compressive strength and 4.0 MPa flexural strength, and the road base material used for base courses of the expressway, the main road and the minor lane were all prepared with milled CFB bottom ashes in the lab. The better methods of utilization of the bottom ashes were discussed in this paper.

Lu, X.F.; Amano, R.S. [University of Wisconsin, Milwaukee, WI (United States). Dept. of Mechanical Engineering

2006-12-15T23:59:59.000Z

320

18 2010 Proceedings Symposium on Ash in North America GTR-NRS-P-72 GENETIC TRANSFORMATION OF FRAXINUS SPP. FOR  

E-Print Network (OSTI)

handles, and for fiber in the manufacture of fine papers. White ash is the primary commercial hardwood protocol for green ash. We are also investigating an adventitious shoot regeneration system using leaf18 2010 Proceedings Symposium on Ash in North America GTR-NRS-P-72 GENETIC TRANSFORMATION

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Investigation on the utilization of coal fly ash as amendment to compost for vegetation in acid soil  

Science Conference Proceedings (OSTI)

The use of fly ash as amendment to compost is presented. Plant growth/yields of corn collard greens, mustard greens, and sorgum is described. The treatment parameters such as fly ash to compost ratio, fly ash-amended compost to soil ratio, type of compost used for treatment etc. are discussed. 2 refs., 5 figs., 8 tabs. (CBS)

Menon, M.P.

1990-04-16T23:59:59.000Z

322

Low Dose Radiation Research Program: Chaun-Yuan Li  

NLE Websites -- All DOE Office Websites (Extended Search)

Chaun-Yuan Li Chaun-Yuan Li Radiation Biology Research, Duke University Medical Center Funded Projects Molecular Characterization of the Role of SOD Genes in Mammalian Cellular Response to Low Dose Ionizing, abstract, description. Technical Abstracts 2006 Workshop: The Roles of Superoxide Dismutage (SOD) in Low Dose Radiation Induced Adaptive Response Yang, Z., Chuang, E., Batinic-Haberle, I., and Li, C.-Y. 2005 Workshop: Molecular Characterization of the Roles of SOD Genes in Mammalian Cellular Response to Low Dose Radiation Li, C.-Y., Guo, Z., Yang, Z., and Chuang, E. 2003 Workshop: Molecular Characterization of the Roles of SOD Genes in Mammalian Cellular Response to Low Dose Radiation Li, C.-Y. and Chuang, E. Publications Li, F., Sonveaux, P., Rabbani, Z.N., Liu, S., Yan, B., Huang, Q.,

323

Evaluating the Effects of the Kingston Fly Ash Release on Fish Reproduction: Spring 2009 - 2010 Studies  

Science Conference Proceedings (OSTI)

On December 22, 2008, a dike containing fly ash and bottom ash at the Tennessee Valley Authority's (TVA) Kingston Fossil Plant in East Tennessee failed and released a large quantity of ash into the adjacent Emory River. Ash deposits from the spill extended 4 miles upstream of the facility to Emory River mile 6 and downstream to Tennessee River mile 564 ({approx}8.5 miles downstream of the confluence of the Emory River with the Clinch River, and {approx}4 miles downstream of the confluence of the Clinch River with the Tennessee River). A byproduct of coal combustion, fly ash contains a variety of metals and other elements which, at sufficient concentrations and in specific forms, can be harmful to biological systems. The ecological effects of fly ash contamination on exposed fish populations depend on the magnitude and duration of exposure, with the most significant risk considered to come from elevated levels of certain metals in the ash, particularly selenium, on fish reproduction and fish early life stages (Lemly 1993; Besser and others 1996). The ovaries of adult female fish in a lake contaminated by coal ash were reported to have an increased frequency of atretic oocytes (dead or damaged immature eggs) and reductions in the overall numbers of developing oocytes (Sorensen 1988) associated with elevated body burdens of selenium. Larval fish exposed to selenium through maternal transfer of contaminants to developing eggs in either contaminated bodies of water (Lemly 1999) or in experimental laboratory exposures (Woock and others 1987, Jezierska and others 2009) have significantly increased incidences of developmental abnormalities. Contact of fertilized eggs and developing embryos to ash in water and sediments may also pose an additional risk to the early life stages of exposed fish populations through direct uptake of metals and other ash constituents (Jezierska and others 2009). The establishment and maintenance of fish populations is intimately associated with the ability of individuals within a population to reproduce. Reproduction is thus generally considered to be the most critical life function affected by environmental contamination. From a regulatory perspective, the issue of potential contaminant-related effects on fish reproduction from the Kingston fly ash spill has particular significance because the growth and propagation of fish and other aquatic life is a specific classified use of the affected river systems. To address the potential effects of fly ash from the Kingston spill on the reproductive health of exposed fish populations, ORNL has undertaken a series of studies in collaboration with TVA that include: (1) a combined field study of metal bioaccumulation in ovaries and other fish tissues (Adams and others 2012) and the reproductive condition of sentinel fish species in reaches of the Emory and Clinch Rivers affected by the fly ash spill (the current report); (2) laboratory tests of the potential toxicity of fly ash from the spill area on fish embryonic and larval development (Greeley and others 2012); (3) additional laboratory experimentation focused on the potential effects of long-term exposures to fly ash on fish survival and reproductive competence (unpublished); and (4) a combined field and laboratory study examining the in vitro developmental success of embryos and larvae obtained from fish exposed in vivo for over two years to fly ash in the Emory and Clinch Rivers (unpublished). The current report focuses on the reproductive condition of adult female fish in reaches of the Emory and Clinch Rivers influenced by the fly ash spill at the beginning of the spring 2009 breeding season - the first breeding season immediately following the fly ash release - and during the subsequent spring 2010 breeding season. Data generated from this and related reproductive/early life stage studies provide direct input to ecological risk assessment efforts and complement and support other phases of the overall biomonitoring program associated with the fly ash spill.

Greeley Jr, Mark Stephen [ORNL; Adams, Marshall [ORNL; McCracken, Kitty [ORNL

2012-05-01T23:59:59.000Z

324

JV Task 120 - Coal Ash Resources Research Consortium Research  

Science Conference Proceedings (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') is the core coal combustion product (CCP) research group at the Energy & Environmental Research Center (EERC). CARRC focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of CCPs. CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCP utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program, which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCP performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 2007 to 2009 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCPs. The tasks were included in four categories: (1) Environmental Evaluations of CCPs; (2) Evaluation of Impacts on CCPs from Emission Controls; (3) Construction and Product-Related Activities; and (4) Technology Transfer and Maintenance Tasks. All tasks are designed to work toward achieving the CARRC overall goal and supporting objectives. The various tasks are coordinated in order to provide broad and useful technical data for CARRC members. Special projects provide an opportunity for non-CARRC members to sponsor specific research or technology transfer consistent with CARRC goals. This report covers CARRC activities from January 2007 through March 2009. These activities have been reported in CARRC Annual Reports and in member meetings over the past 2 years. CARRC continues to work with industry and various government agencies with its research, development, demonstration, and promotional activities nearing completion at the time of submission of this report. CARRC expects to continue its service to the coal ash industry in 2009 and beyond to work toward the common goal of advancing coal ash utilization by solving CCP-related technical issues and promoting the environmentally safe, technically sound, and economically viable management of these complex and changing materials.

Debra Pflughoeft-Hassett; Loreal Heebink; David Hassett; Bruce Dockter; Kurt Eylands; Tera Buckley; Erick Zacher

2009-03-28T23:59:59.000Z

325

Nuclear engineer Li wins Presidential Early Career Award | Argonne...  

NLE Websites -- All DOE Office Websites (Extended Search)

Photon Source. Click to enlarge. Argonne's Advanced Photon Source. Click to enlarge. Nuclear engineer Li wins Presidential Early Career Award By Jared Sagoff * January 15, 2014...

326

Electrochemical Performance of LiFeMnPO4  

Science Conference Proceedings (OSTI)

Symposium, Energy Storage: Materials, Systems, and Applications. Presentation Title, Electrochemical Performance of LiFeMnPO4: A Comparison of Synthesis ...

327

One-Pot Mechanochemical Processing of Cathode Materials for Li ...  

Science Conference Proceedings (OSTI)

Environmental Assessment of Li-CNT Battery Production ... The Production of High-Quality Magnesite Ore Concentrate With Permroll Type Magnetic Separator.

328

Electrode Materials for Rechargeable Li-ion Batteries: a New ...  

High-energy density Li-ion batteries available in the market today have low power and progressively lose their energy due to voltage fade during ...

329

A Comparison of Li-Ion Battery Recycling Options  

NLE Websites -- All DOE Office Websites (Extended Search)

1 A Comparison of Li-Ion Battery Recycling Options Linda Gaines and Jennifer Dunn Center for Transportation Research Argonne National Laboratory SAE World Congress April 2012 PAPER...

330

Integrating SOC Dependent Material Properties into Li-Ion Battery ...  

Science Conference Proceedings (OSTI)

During battery operation, Li flows into and out of electrode particles, causing microstructural changes and deformation-induced degradation. A variety of models ...

331

NEHRP - Northern California LiDAR Hillshades in Google ...  

Science Conference Proceedings (OSTI)

Library. Northern California LiDAR Hillshades in Google Earth. ... Increasing the disk cache size in Google Earth to 2000MB is advised. ...

332

Ultrathin Surface Coatings for Enhanced Cycleability of Li-Ion ...  

Science Conference Proceedings (OSTI)

Characterization of Battery Cycling by In-Situ Microscopy · Chemical ... as Li-ion Battery Electrodes · In Situ and In Operando Studies of High Capacity Cathodes.

333

LiDAR (Monaster And Coolbaugh, 2007) | Open Energy Information  

Open Energy Info (EERE)

Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon LiDAR (Monaster And Coolbaugh, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal...

334

Direct Nuclear Reactions in Lithium-Lithium Systems: 7Li+7Li at Elab = 2 - 16 MeV  

E-Print Network (OSTI)

Angular distributions of 7Li(7Li,t), (7Li,alpha) and (7Li,6He) reactions were measured for laboratory energies from 2 - 16 MeV. Exact finite range DWBA analyses were performed with the aim to identify contributions of direct processes and to investigate the applicability of DWBA to such few nucleon systems. It turned out that DWBA can be successfully applied to estimate differential and total cross sections of direct transfer processes in 7Li+7Li interaction. The direct mechanism was found to play a dominant role in most of these reactions but significant contributions of other, strongly energy dependent processes were also established. It is suggested that these processes might be due to isolated resonances superimposed on the backround of statistical fluctuations arising from interference of compound nucleus and direct transfer contributions.

P. Rosenthal; H. Freiesleben; B. Gehrmann; I. Gotzhein; K. W. Potthast; B. Kamys; Z. Rudy

2008-01-15T23:59:59.000Z

335

Thin-film Li-LiMn{sub 2}O{sub 4} batteries  

DOE Green Energy (OSTI)

Thin-film rechargeable Li-LiMn{sub 2}O{sub 4} batteries have been fabricated and characterized. Following deposition by electron beam evaporation of LiMn{sub 2}O{sub 4}, the amorphous as-deposited cathode films 1 cm{sup 2} in area by 0.3 to 4 {mu}m thick were annealed at 700{degree}C to 800{degree}C in oxygen in order to form the crystalline spinel phase. The capacity of the cells between 4.5 V to 3.8 V depended on the annealing conditions and ranged from 50 {mu}Ah/mg to 120 {mu}Ah/mg. When cycled over this range, the batteries exhibited excellent secondary performance with capacity losses as low as 0.001% per cycle. On charging to 5.3 V, a plateau with a median voltage of 5.1 V was observed. The total charge extracted between 3.8 V to 5.3 V corresponded to about 1Li/Mn{sub 2}O{sub 4}.

Bates, J.B.; Lubben, D.; Dudney, N.J.

1994-11-01T23:59:59.000Z

336

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures  

SciTech Connect

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated.

Khan, M. Rashid (Morgantown, WV)

1990-01-01T23:59:59.000Z

337

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures  

DOE Patents (OSTI)

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated. 7 figs.

Khan, M.R.

1989-05-12T23:59:59.000Z

338

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents (OSTI)

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas for further combustion in modified oil or gas fired furnaces or boilers. Two concentric shells define a combustion volume within the inner shell and a plenum between them through which combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, Albert H. (Huntington, NY)

1983-10-04T23:59:59.000Z

339

Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment  

Science Conference Proceedings (OSTI)

Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energy release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.

Chen, C.C.; Lee, W.J.; Shih, S.I.; Mou, J.L. [National Cheng Kung University, Tainan (Taiwan). Dept. of Environmental Engineering

2009-07-01T23:59:59.000Z

340

Predicted Structure, Thermo-Mechanical Properties and Li Ion Transport in LiAlF4 Glass  

Science Conference Proceedings (OSTI)

Materials with the LiAlF{sub 4} composition are of interest as protective electrode coatings in Li ion battery applications due to their high cationic conductivity. Here classical molecular dynamics calculations are used to produce amorphous model structures by simulating a quench from the molten state. These are analysed in terms of their individual pair correlation functions and atomic coordination environments. This indicates that amorphous LiAlF{sub 4} is formed of a network of corner sharing AlF{sub 6} octahedra. Li ions are distributed within this network, primarily associated with non-bridging fluorine atoms. The nature of the octahedral network is further analysed through intra- and interpolyhedral bond angle distributions and the relative populations of bridging and non-bridging fluorine ions are calculated. Network topology is considered through the use of ring statistics, which indicates that, although topologically well connected, LiAlF{sub 4} contains an appreciable number of corner-linked branch-like AlF{sub 6} chains. Thermal expansion values are determined above and below the predicted glass transition temperature of 1340 K. Finally, movement of Li ions within the network is examined with predictions of the mean squared displacements, diffusion coefficients and Li ion activation energy. Different regimes for lithium ion movement are identified, with both diffusive and sessile Li ions observed. For migrating ions, a typical trajectory is illustrated and discussed in terms of a hopping mechanism for Li transport.

Stechert, T. R.; Rushton, M. J. D.; Grimes, R. W.; Dillon, A. C.

2012-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Selected test results from the LiFeBatt iron phosphate Li-ion battery.  

DOE Green Energy (OSTI)

In this paper the performance of the LiFeBatt Li-ion cell was measured using a number of tests including capacity measurements, capacity as a function of temperature, ohmic resistance, spectral impedance, high power partial state of charge (PSOC) pulsed cycling, pulse power measurements, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the iron phosphate Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, and wind farm energy smoothing. Test results have indicated that the LiFeBatt battery technology can function up to a 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h discharge rate (1C). The utility PSOC cycle test at up to the 4C{sub 1} pulse rate completed 8,394 PSOC pulsed cycles with a gradual loss in capacity of 10 to 15% depending on how the capacity loss is calculated. The majority of the capacity loss occurred during the initial 2,000 cycles, so it is projected that the LiFeBatt should PSOC cycle well beyond 8,394 cycles with less than 20% capacity loss. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were only very small changes after cycling. Finally, at a 1C charge rate, the over charge/voltage abuse test resulted in the cell venting electrolyte at 110 C after 30 minutes and then open-circuiting at 120 C with no sparks, fire, or voltage across the cell.

Ingersoll, David T.; Hund, Thomas D.

2008-09-01T23:59:59.000Z

342

Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge  

E-Print Network (OSTI)

Using a novel electrochemical phase-field model, we question the common belief that LiXFePO? nanoparticles always separate into Li-rich and Li-poor phases during battery discharge. For small currents, spinodal decomposition ...

Bai, Peng

343

Development of New Industrial Ashalloy Material Using Fly Ash Cenospheres "Lead-Lite" Project  

Science Conference Proceedings (OSTI)

One potential high-value utilization method for power plant fly ash is to mix it with an alloy to make a metal matrix composite. In the case of this project, the fly ash is mixed with lead to make a composite with low density and improved hardness. This new material can be used in the auto industry to make lighter battery components. This report describes the results of corrosion tests of several lead samples and lead-fly ash composite samples at room temperature for more than 1500 days. This long-term d...

1999-11-10T23:59:59.000Z

344

Salt-soda sinter process for recovering aluminum from fly ash  

DOE Patents (OSTI)

A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na.sub.2 CO.sub.3 to a temperature in the range 700.degree.-900.degree. C. for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acid-soluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

1981-01-01T23:59:59.000Z

345

Devolatilization and ash comminution of two different sewage sludges under fluidized bed combustion conditions  

Science Conference Proceedings (OSTI)

Two different wet sewage sludges have been characterized under fluidized bed combustion conditions with reference to their devolatilization behavior and ash comminution with the aid of different and complementary experimental protocols. Analysis of the devolatilization process allowed to determine the size of fuel particle able to achieve effective lateral spreading of the volatile matter across the cross-section of medium-scale combustors. Primary fragmentation and primary ash particle characterization pointed out the formation of a significant amount of relatively large fragments. The mechanical properties of these fragments have been characterized by means of elutriation/abrasion tests using both quartz and sludge ash beds. (author)

Solimene, R.; Urciuolo, M.; Cammarota, A.; Chirone, R. [Istituto di Ricerche sulla Combustione (IRC) - CNR, Napoli (Italy); Salatino, P. [Istituto di Ricerche sulla Combustione (IRC) - CNR, Napoli (Italy); Dipartimento di Ingegneria Chimica Universita degli Studi di Napoli Federico II, Napoli (Italy); Damonte, G.; Donati, C.; Puglisi, G. [ECODECO Gruppo A2A, Giussago (PV) (Italy)

2010-04-15T23:59:59.000Z

346

Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants  

E-Print Network (OSTI)

Over the past decade increasing concern over the potential environmental impact associated with the emissions of both gaseous and particulate pollutants has resulted in the promulgation of strict regulatory standards governing such emissions. In this regard, particular attention has been placed upon the control of sulfur dioxide (SO2) from major fuel burning installations. The provisions of the 1977 Amendments to the Clean Air Act which relate to the Prevention of Significant Deterioration (PSD) and the New Source Performance Standards (NSPS) have made consideration of this problem of significant additional importance in the context of increased coal utilization. There exist three general methods for the control of sulfur dioxide emissions from pulverized coal-fired boiler equipment. These are: (1) coal cleaning to remove pyritic sulfur, (2) conventional wet, nonregenerable scrubbing with alkaline slurry and solution processes, and (3) dry processes which involve direct introduction of lime or limestone into the firebox, or a spray dryer operated with nonregenerable alkaline sorbents coupled with a fabric filter collector. Equipment requirements, SO2 removal criteria, general economics, and potential applications of these latter two approaches within category (3) will be discussed.

Schwartz, M. H.

1979-01-01T23:59:59.000Z

347

I I LI I L I  

Office of Legacy Management (LM)

LI LI - I L I 1 II C c - ORNL/RASA-9618 OAK RlDGE NATlONAl. LA8ORATORY Results of the Independent Radiological Verification Survey at B&T Metals, 425 West Town Street, Columbus, Ohio (cooolv) M . E. Murray V. P. Patania C. A. Johnson M N M E D *wD OPEbM~ B V WUCNEEDllW?ME IWiARCH CoRpoRAng FoRTHEwITf@%tATeB ltEpAAMwTmBMeR(Ly ORNL-27 (34el ~~- L._~ This report has been reproduced directly from the best available copy. Avaiiable to DOE and DOE contractors from the Office of Scientific and Technical information, P.O. Box 62, Oak Ridge, TN 3783 1; prices available from (615) 576-8301, FlS 626-8401. Available to the public from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Rd., Springfield, VA 22161. This report was prepared as an account of work sponsored by an agency of the

348

Lithium Lorentz Force Accelerator Thruster (LiLFA)  

E-Print Network (OSTI)

Lithium Lorentz Force Accelerator Thruster (LiLFA) Adam Coulon Princeton University Electric #12;LiLFA Thruster · Lithium vapor ionizes in the electric field · A current evolves in the plasma and Control System Position Sensing Detector #12;Lithium Reservoir Argon Flow Copper Water Flow Piston/Lithium

Petta, Jason

349

FLIGHT: Clock Calibration Using Fluorescent Lighting Zhenjiang Li1,4, Wenwei Chen1, Cheng Li1, Mo Li1, Xiang-yang Li2, Yunhao Liu3,4  

E-Print Network (OSTI)

FLIGHT: Clock Calibration Using Fluorescent Lighting Zhenjiang Li1,4, Wenwei Chen1, Cheng Li1, Mo propose a novel clock calibration approach called FLIGHT, which leverages the fact that the fluorescent, Performance Keywords Clock calibration, Fluorescent lighting, Energy efficiency 1. INTRODUCTION Maintaining

Liu, Yunhao

350

Molecular dynamics simulation of Li surface erosion and bubble formation  

E-Print Network (OSTI)

Molecular dynamics simulation of Li surface erosion and bubble formation Z. Insepov *, A. Hassanein Structure and dynamical properties of liquid Li containing He atoms were studied by the Molecular Dynamics devices. Molecular dynamics (MD) method is capable of studying important collision processes and providing

Harilal, S. S.

351

Phase Field Model of Li-Plating in Lithium Ion Battery  

Science Conference Proceedings (OSTI)

Abstract Scope, Li plating limits the maximum safe charging rate of Li-ion batteries, and thus the amount of energy that can be captured by regenerative braking.

352

Polymer electrolytes for a rechargeable li-Ion battery  

SciTech Connect

Lithium-ion polymer electrolyte battery technology is attractive for many consumer and military applications. A Li{sub x}C/Li{sub y}Mn{sub 2}O{sub 4} battery system incorporating a polymer electrolyte separator base on novel Li-imide salts is being developed under sponsorship of US Army Research Laboratory (Fort Monmouth NJ). This paper reports on work currently in progress on synthesis of Li-imide salts, polymer electrolyte films incorporating these salts, and development of electrodes and cells. A number of Li salts have been synthesized and characterized. These salts appear to have good voltaic stability. PVDF polymer gel electrolytes based on these salts have exhibited conductivities in the range 10{sup -4} to 10{sub -3} S/cm.

Argade, S.D.; Saraswat, A.K.; Rao, B.M.L. [Technochem Co., Greensboro, NC (United States); Lee, H.S.; Xiang, C.L.; McBreen, J. [Brookhaven National Lab., Upton, NY (United States)

1996-10-01T23:59:59.000Z

353

Alanine-assisted low-temperature combustion synthesis of nanocrystalline LiMn{sub 2}O{sub 4} for lithium-ion batteries  

SciTech Connect

Nanocrystalline LiMn{sub 2}O{sub 4} powders have been synthesized by combustion process in a single step using a novel fuel, L-alanine. Thermogravimetric analysis and differential thermal analysis of the gel indicate a sharp combustion at a temperature as low as 149 deg. C. Quantitative phase analysis of X-ray diffraction data shows about 97% of phase purity in the as-synthesized powder, which on further calcination at 700 deg. C becomes single phase LiMn{sub 2}O{sub 4}. High Brunauer, Emmett, and Teller surface area values obtained for ash (53 m{sup 2}/g) and calcined powder (23 m{sup 2}/g) indicate the ultrafine nature of the powder. Average crystallite size is found to be {approx}60-70 nm from X-ray diffraction analysis and transmission electron microscopy. Fourier transformed infra-red spectrum shows two strong bands at 615 and 511 cm{sup -1} originating from asymmetrical stretching of MnO{sub 6} octahedra. A nominal composition of Li{sub 0.88} Mn{sub 2}O{sub 4} is calculated from the inductive coupled plasma analysis. From UV-vis spectroscopy, an optical band gap of 1.43 eV is estimated which is assigned to a transition between t{sub 2g} and e{sub g} bands of Mn 3d. Electrochemical charge-discharge profiles show typical LiMn{sub 2}O{sub 4} behavior with a specific capacity of 76 mAh/g.

Raja, M.W. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India); Mahanty, S. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India); Ghosh, Paromita [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India); Basu, R.N. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India)]. E-mail: rnbasu@cgcri.res.in; Maiti, H.S. [Fuel Cell and Battery Section, Electroceramics Division, Central Glass and Ceramic Research Institute, Kolkata 700 032 (India)

2007-08-07T23:59:59.000Z

354

Apparatus having inductively coupled coaxial coils for measuring buildup of slay or ash in a furnace  

DOE Patents (OSTI)

The buildup of slag or ash on the interior surface of a furnace wall is monitored by disposing two coils to form a transformer which is secured adjacent to the inside surface of the furnace wall. The inductive coupling between the two coils of the transformer is affected by the presence of oxides of iron in the slag or ash which is adjacent to the transformer, and the application of a voltage to one winding produces a voltage at the other winding that is related to the thickness of the slag or ash buildup on the inside surface of the furnace wall. The output of the other winding is an electrical signal which can be used to control an alarm or the like or provide an indication of the thickness of the slag or ash buildup at a remote location.

Mathur, Mahendra P. (Pittsburgh, PA); Ekmann, James M. (Bethel Park, PA)

1989-01-01T23:59:59.000Z

355

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains  

Open Energy Info (EERE)

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains 2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: 2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Details Activities (0) Areas (0) Regions (0) Abstract: Diverse latest Pliocene volcanic and plutonic rocks in the north-central Caucasus Mountains of southern Russia are newly interpreted as components of a large caldera system that erupted a compositionally zoned rhyolite-dacite ash-flow sheet at 2.83 ± 0.02 Ma (sanidine and biotite 40Ar/39Ar). Despite its location within a cratonic collision zone, the Chegem system is structurally and petrologically similar to typical

356

Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility | Open  

Open Energy Info (EERE)

Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Facility Hunt's Ash Springs Sector Geothermal energy Type Pool and Spa Location Hiko, Nevada Coordinates Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

357

Treated bottom ash medium and method of arsenic removal from drinking water  

DOE Patents (OSTI)

A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

Gadgil, Ashok (El Cerrito, CA)

2009-06-09T23:59:59.000Z

358

Kinetics of fly ash beneficiation by carbon burnout. Quarterly report, October 1996--December 1996  

Science Conference Proceedings (OSTI)

The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called {open_quotes}Loss On Ignition{close_quotes} (LOI). The concrete producer`s day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

Dodoo, J.N.; Okoh, J.M.; Diaz, A. [and others

1997-06-01T23:59:59.000Z

359

STATE-OF-THE-ART: FLY ASH, SILICA FUME AND SLAG UTILIZATION IN USA  

E-Print Network (OSTI)

Backfill. 1.0 Introduction At the present time, coal fired electric power plants in the USA produce, ease of handling, and moisture insensitivity, etc. [2,11]. 2.1.2 Backfills Fly ash is used

Wisconsin-Milwaukee, University of

360

Smyrna's Ashes: Humanitarianism, Genocide, and the Birth of the Middle East  

E-Print Network (OSTI)

burning of the city of Izmir, Smyrna’s Ashes is an importantof Smyrna came a new city, Izmir, and a new Turkish nation.Gardens (Kensington), 165 Izmir, 1 Index / 249 Jerusalem, 67

Tusan, Michelle

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

M-2: Extracting Alumina from Coal Fly Ash with Ammonium Sulfate ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The whole process of extracting alumina from coal fly ash ... Decrease of Heat Consumption at Nepheline Processing to Alumina and By- Products ... Flash -and CFB Calciners, History and Difficulties of Development of Two ...

362

The potential for use of waste-to-energy facility ash: Executive summary. Final report  

DOE Green Energy (OSTI)

This executive summary presents an overview of the investigations, findings, conclusions, and recommendations of the Long Island Regional Planning Board (LIRPB) study of the Potential for Beneficial Use of Waste-to-Energy Facility Ash. The full report consists of the following volumes: Executive Summary; Volume 1: Long Island Ash Management Status; Volume 2: Sampling and Testing Procedures; Volume 3: Environmental Properties; Volume 4: Engineering Properties; Volume 5: Environmental Assessment; Volume 6: Engineering and Economic Evaluation; and Volume 7: Legal and Institutional Issues. Volumes one through seven are briefly summarized in this executive summary with the exception of Volume 2 of the report, which serves as the documentation of the sampling conditions and testing methods used in measuring chemical and physical properties of the ash tested. The study investigated the feasibility of the use of incinerator ash as a substitute for natural aggregate in construction applications.

Koppelman, L.E.; Tanenbaum, E.G. [Long Island Regional Planning Board, Hauppauge, NY (United States)

1994-05-01T23:59:59.000Z

363

Recovery of Metal Oxides From Fly Ash, Volumes 1-3  

Science Conference Proceedings (OSTI)

By processing fly ash to obtain metal oxides and other commercial products, utilities can realize both sales revenues and reduced disposal costs. A commercial-scale processing plant could be ready for demonstration by 1992.

1984-06-01T23:59:59.000Z

364

Application of advanced technologies to ash-related problems in boilers  

DOE Green Energy (OSTI)

Prediction of ash behavior in boilers has, for many years, been based on relatively simple relationships involving the composition of inorganic material in fuels. In recent years, advanced analyses for both fuels and deposits have seen increasing use in the solid fuel combustion community. The combination of the standard and advanced analyses, together with a knowledge of boiler design and operating conditions, allow better interpretation of ash behavior in boilers than has previously been possible. This paper discusses several case histories where advanced technologies have been applied to interpret ash behavior in boilers where standard techniques were insufficient. Included in the discussion are: (1) the behavior of blends of fuels; (2) explanations for markedly different behavior between fuels with similar ASTM characteristics; and (3) effects of boiler operating conditions on ash deposit formation.

Baxter, L.L. (Sandia National Labs., Livermore, CA (United States). Combustion Research Facility); Richards, G.; Harb, J. (Brigham Young Univ., Provo, UT (United States). Chemical Engineering Dept.)

1994-01-01T23:59:59.000Z

365

Removal of radium from acidic solutions containing same by adsorption on coal fly ash  

DOE Patents (OSTI)

The invention is a process for the removal of radium from acidic aqueous solutions. In one aspect, the invention is a process for removing radium from an inorganic-acid solution. The process comprises contacting the solution with coal fly ash to effect adsorption of the radium on the ash. The radium-containing ash then is separated from the solution. The process is simple, comparatively inexpensive, and efficient. High radium-distribution coefficients are obtained even at room temperature. Coal fly ash is an inexpensive, acid-resistant, high-surface-area material which is available in large quantities throughout the United States. The invention is applicable, for example, to the recovery of .sup.226 Ra from nitric acid solutions which have been used to leach radium from uranium-mill tailings.

Scheitlin, Frank M. (Oak Ridge, TN)

1984-01-01T23:59:59.000Z

366

The use of oil shale ash in the production of biodiesel from waste vegetable oil  

Science Conference Proceedings (OSTI)

Oil shale ash obtained from combustion of local oil shale deposits was used in this study as a heterogeneous catalyst to produce biodiesel from waste vegetable oil (WVO). Two alcohols with high and low boiling points

A. Al-Otoom; M. Allawzi; A. Ajlouni; F. Abu-Alrub; M. Kandah

2012-01-01T23:59:59.000Z

367

Utilizing fly ash particles to produce low-cost metal matrix composites  

Science Conference Proceedings (OSTI)

Metal matrix composites (MMCs) are a blend of fine ceramic particles mixed with metals such as aluminium or magnesium. Fly ash is considerably cheaper than ceramics; aluminium-fly ash composites cost less than 60% of conventional aluminium-SiC composites making them attractive to automakers striving for lower weight and cheaper materials for brake rotors or brake drums. Ultalite.com has consulted with US researchers to to find the optimum requirements of the fly ash needed to make MMCs. Particle size 20-40 microns, low calcium oxide content and spherical particles were identified. The desired particles once extracted are stirred into molten aluminum and the resulting composite is into ingots for shipment to a casting facility. Dynamometer testing has shown that aluminium-fly ash composite brake drums have better performance and wear than cast iron drums. 6 figs., 1 tab.

Withers, G. [Ultalite.com, Melbourne, Vic. (Australia)

2008-07-01T23:59:59.000Z

368

Lubricant-derived ash : in-engine sources and opportunities for reduction  

E-Print Network (OSTI)

Diesel particulate filters (DPF) are an effective means for meeting increasingly stringent emissions regulations that limit particulate matter. Over time, ash primarily derived from metallic additives in the engine oil ...

Watson, Simon A. G. (Simon Andrew Glean)

2010-01-01T23:59:59.000Z

369

An Advanced System to Monitor the 3D Structure of Diffuse Volcanic Ash Clouds  

Science Conference Proceedings (OSTI)

Major disruptions of the aviation system from recent volcanic eruptions have intensified discussions about and increased the international consensus toward improving volcanic ash warnings. Central to making progress is to better discern low ...

J.-P. Vernier; T. D. Fairlie; J. J. Murray; A. Tupper; C. Trepte; D. Winker; J. Pelon; A. Garnier; J. Jumelet; M. Pavolonis; A. H. Omar; K. A. Powell

2013-09-01T23:59:59.000Z

370

Dynamic studies of {sup 11}Li and its core {sup 9}Li on {sup 208}Pb near the Coulomb barrier  

SciTech Connect

We measured the scattering of the halo nucleus {sup 11}Li and its core {sup 9}Li on the lead target at TRIUMF at energies below and around to the Coulomb barrier. We report here on our preliminary analysis of the inclusive breakup reaction.

Cubero, M.; Borge, M. J. G.; Alcorta, M.; Madurga, M.; Tengblad, O. [Inst. Estructura de la Materia, CSIC, Serrano 113bis, E28006 Madrid (Spain); Acosta, L.; Martel, I.; Sanchez-Benitez, A. M. [Departamento de Fisica Aplicada, Universidad de Huelva, E-21071, Huelva (Spain); Alvarez, M. A. G.; Gomez-Camacho, J. [Departamento de FAMN, Universidad de Sevilla, E-41080 Sevilla (Spain); Centro Nacional de Aceleradores, Universidad de Sevilla-Junta de Andalucia-CSIC, Av. Thomas A. Edison, 41092 Sevilla (Spain); Diget, C. [Department of Physics, University of York, York (United Kingdom); Galaviz, D. [CFNUL, Universidade de Lisboa, Av. Prof. Gama Pinto 2, 1649-003, Lisboa (Portugal); Fernandez-Garcia, J. P.; Lay, J. A.; Moro, A. M.; Mukha, I. [Departamento de FAMN, Universidad de Sevilla, E-41080 Sevilla (Spain); Shotter, A.; Walden, P. [TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada)

2010-04-26T23:59:59.000Z

371

Kinetic measurement and prediction of the hydrogen outgassing from the polycrystalline LiH/LiOH system  

DOE Green Energy (OSTI)

In this report, we present the use of temperature programmed reaction/decomposition (TPR) in the isoconversion mode to measure outgassing kinetics and to make kinetic prediction concerning hydrogen release from the polycrystalline LiH/LiOH system in the absence of any external H{sub 2}O source.

Dinh, L N; Grant, D M; Schildbach, M A; Smith, R A; Leckey, J H; Siekhaus, W J; Balazs, B; McLean II, W

2005-03-09T23:59:59.000Z

372

The use of sulfer modified bottom ash (SMBA) as an aggregate in asphaltic mixtures  

E-Print Network (OSTI)

Of the 20 million tons of bottom ash and boiler slag generated annually in the United States less than 40 percent is used. The eastern half of Texas is served by 18 coal burning electric power generating plants which produce approximately 3.8 million tons of bottom ash each year. This is also the section of the state in which the sources of quality aggregates are either few. dwindling or nonexistent. While a small fraction of the bottom ash is utilized, the rest is delegated to landfills or on-site disposal areas. Increasing attention is being given to development of new, high-volume uses for this safe and readily available by-product. One such use is as an aggregate in road construction. The use of bottom ash as an aggregate for both roadway surfaces and base courses has been limited due to its absorbency and friability. The former tends to increase asphalt binder demand while the latter adversely affects its ability to withstand the crushing effects of traffic loads. On the other hand, bottom ash is lighter in weight and generally much cheaper than conventional quality aggregates such as limestone, sand and gavel. This research was designed to up-firade the load-bearing characteristics of bottom ash and maximize its use 'in asphaltic concrete roadway mixtures through the use of sulfur. The process essentially coats the ash with liquid sulfur which upon cooling fills the voids on the surface of the particles while increasing their crush resistance. The results of this investigation indicate that asphaltic concrete mix designs in which bottom ash represents from 5 0 to I 00 percent of the aggregate fraction can be achieved.

Chimakurthy, Harshavardhan

1998-01-01T23:59:59.000Z

373

Mitigation of SCR-Ammonia Related Aqueous Effects in a Fly Ash Pond  

Science Conference Proceedings (OSTI)

Contaminated fly ash resulting from secondary injection of ammonia to mitigate SO3 produced by a selective catalytic reduction (SCR) system altered the water quality of a fly ash pond at a coal-fired power generation station. This project attempted to improve water quality by encouraging the growth of algae in the pond to remove ammonia, while keeping other important parameters (pH, total suspended solids, Biological Oxygen Demand, and metals) within allowable limits.

2006-02-07T23:59:59.000Z

374

Field Test of a Semi-Continuous Fly Ash Unburned Carbon Monitor: Cyclone Boiler Application  

Science Conference Proceedings (OSTI)

Unburned carbon (UBC) is the measure of the carbon level in the fly ash of a coal-fired boiler—with increased carbon indicating less-complete and less-efficient combustion. Boiler design is one important factor that affects UBC levels. Cyclone boilers burn coal at high combustion temperatures (ca. 1650°C) and exhibit relatively high, but quite variable, fly ash UBC levels. Recently, because of competitive fuel pricing and reduced SO2 and NOX emissions, cyclone boilers ...

2013-12-17T23:59:59.000Z

375

Program on Technology Innovation: Formation of Large Particle Ash in Coal-Fired Boilers  

Science Conference Proceedings (OSTI)

The objective of this project was to obtain a better understanding of the process that underlies the formation of large particle ash (LPA) in coal-fired boilers. As an approach, sample sets of coal, fireside ash deposits, and LPA were collected from selected boilers identified by the Electric Power Research Institute (EPRI) and were characterized using scanning electron microscopy (SEM) and x-ray microanalysis techniques. The coals were characterized to determine the abundance, size, and composition of t...

2010-02-08T23:59:59.000Z

376

Structure of neutron-rich Isotopes {sup 8}Li and {sup 9}Li and allowance for it in elastic scattering  

Science Conference Proceedings (OSTI)

The differential cross sections for elastic proton scattering on the unstable neutron-rich nuclei {sup 8}Li and {sup 9}Li at E = 700 and 60 MeV per nucleon were considered. The {sup 8}Li nucleus was treated on the basis of the three-body {alpha}-t-n model, while the {sup 9}Li nucleus was considered within the {alpha}-t-n and {sup 7}Li-n-n models. The cross sections in question were calculated within Glauber diffraction theory. A comparison of the results with available experimental data made it possible to draw conclusions on the quality of the wave functions and potential used in the calculations.

Ibraeva, E. T., E-mail: ibr@inp.k [National Nuclear Center of the Republic of Kazakhstan, Institute for Nuclear Physics (Kazakhstan); Zhusupov, M. A.; Imambekov, O.; Sagindykov, Sh. Sh. [Al Farabi Kazakh National University (Kazakhstan)

2008-07-15T23:59:59.000Z

377

LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery  

SciTech Connect

This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

Ko, Suk M. (Huntsville, AL)

1980-01-01T23:59:59.000Z

378

The Laconia, New Hampshire bottom ash paving project: Volume 3, Physical Performance Testing Report  

SciTech Connect

Bottom ash is the principal waste stream from the combustion of municipal solid waste (MSW). It is comprised of grate ash (97%), the slag material discharged at the end of the grate system, and grate sifting (3%), the material that melts or falls through the grate structure. This project was conducted to demonstrate the feasibility of using municipal solid waste grate ash as an aggregate substitute in the construction of a pavement binder course for a portion of Rt. 3 in Laconia, New Hampshire. The research was conducted over a two year period during 1993 and 1994. This study is the culmination of an earlier two year characterization study between 1990 and 1992 that documented the physical and environmental characteristics of the bottom ash as it was produced at the Concord, N.H. waste-to-energy (@) facility and used in an asphaltic binder course. Together, these two studies provide a complete evaluation of the potential for using grate ash or bottom ash in asphalt binder course or as recycled asphalt pavement (RAP) in base courses in pavements.

NONE

1996-03-01T23:59:59.000Z

379

Encapsulation of mixed radioactive and hazardous waste contaminated incinerator ash in modified sulfur cement  

Science Conference Proceedings (OSTI)

Some of the process waste streams incinerated at various Department of Energy (DOE) facilities contain traces of both low-level radioactive (LLW) and hazardous constituents, thus yielding ash residues that are classified as mixed waste. Work is currently being performed at Brookhaven National Laboratory (BNL) to develop new and innovative materials for encapsulation of DOE mixed wastes including incinerator ash. One such material under investigation is modified sulfur cement, a thermoplastic developed by the US Bureau of Mines. Monolithic waste forms containing as much as 55 wt % incinerator fly ash from Idaho national Engineering Laboratory (INEL) have been formulated with modified sulfur cement, whereas maximum waste loading for this waste in hydraulic cement is 16 wt %. Compressive strength of these waste forms exceeded 27.6 MPa. Wet chemical and solid phase waste characterization analyses performed on this fly ash revealed high concentrations of soluble metal salts including Pb and Cd, identified by the Environmental Protection Agency (EPA) as toxic metals. Leach testing of the ash according to the EPA Toxicity Characteristic Leaching Procedure (TCLP) resulted in concentrations of Pb and Cd above allowable limits. Encapsulation of INEL fly ash in modified sulfur cement with a small quantity of sodium sulfide added to enhance retention of soluble metal salts reduced TCLP leachate concentrations of Pb and Cd well below EPA concentration criteria for delisting as a toxic hazardous waste. 12 refs., 4 figs., 2 tabs.

Kalb, P.D.; Heiser, J.H. III; Colombo, P.

1990-01-01T23:59:59.000Z

380

Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes  

SciTech Connect

There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with fly ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.

Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Skilbeck, C.G. [University of Technology Sydney, Sydney, NSW (Australia). Dept. of Environmental Science

2009-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Microsoft Word - li_z.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Impact of the Vertical Variation of Cloud Droplet Size Impact of the Vertical Variation of Cloud Droplet Size on the Estimation of Cloud Liquid Water Path and Its Potential for Rain Detection Z. Li, R. Chen, and F-L Chang Earth System Science Interdisciplinary Center, University of Maryland College Park, Maryland Introduction Liquid water path (LWP) is an important cloud microphysical property that determines the climatic effects of boundary layer clouds. Satellites provide the only means of acquiring global and long-term LWP estimates. The LWP is estimated from satellite measurements of either microwave radiation emitted by the cloud or visible/near infrared (NIR) solar reflectance from the cloud. LWP can be retrieved from the microwave signature emitted by cloud droplets. Microwave retrievals of

382

Recycling of Li-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 Linda Gaines Center for Transportation Research Argonne National Laboratory Recycling of Li-Ion Batteries Illinois Sustainable Technology Center University of Illinois We don't want to trade one crisis for another!  Battery material shortages are unlikely - We demonstrated that lithium demand can be met - Recycling mitigates potential scarcity  Life-cycle analysis checks for unforeseen impacts  We need to find something to do with the used materials - Safe - Economical 2 We answer these questions to address material supply issues  How many electric-drive vehicles will be sold in the US and world-wide?  What kind of batteries might they use? - How much lithium would each battery use?  How much lithium would be needed each year?

383

CI L C C I LI C  

Office of Legacy Management (LM)

CI CI L C C - I LI C c C I I I I I I I L rr ORNL/RASA-94/l 0t-t. 27-6 \O [I ,-' :..L, &ml OAK RIDGE NATIONAL LABORATORY RESULTS OF THE RADIOLOGICAL SURVEY at the former HERRING-HALL-MARVIN SAFE COMPANY (3rd Floor) 1550 Grand Boulevard, Hamilton, Ohio (HOOOl) M. E. Murray C. A. Johnson MANA6ED BY MARTIN MARIETTA ENERGY SYSTEMS, INC. FOR THE UNITE0 STATES DEPARTMENT OF ENEMY This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical Information, P.O. Box 62, Oak Ridge, TN 37831; prices available from (615) 576-8401, FTS 6268401. Available to the public from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Rd., Springfield, VA 22161.

384

Evaluation of potential risks from ash disposal site leachate  

SciTech Connect

A risk-based approach is used to evaluate potential human health risks associated with a discharge from an ash disposal site into a small stream. The RIVRISK model was used to estimate downstream concentrations and corresponding risks. The modeling and risk analyses focus on boron, the constituent of greatest potential concern to public health at the site investigated, in Riddle Run, Pennsylvania. Prior to performing the risk assessment, the model is validated by comparing observed and predicted results. The comparison is good and an uncertainty analysis is provided to explain the comparison. The hazard quotient (HQ) for boron is predicted to be greater than 1 at presently regulated compliance points over a range of flow rates. The reference dose (RfD) currently recommended by the United States Environmental Protection Agency (US EPA) was used for the analyses. However, the toxicity of boron as expressed by the RfD is now under review by both the U.S. EPA and the World Health Organization. Alternative reference doses being examined would produce predicted boron hazard quotients of less than 1 at nearly all flow conditions.

Mills, W.B.; Loh, J.Y.; Bate, M.C.; Johnson, K.M. [Tetra Tech, Lafayette, CA (United States)] [Tetra Tech, Lafayette, CA (United States)

1999-04-01T23:59:59.000Z

385

Fibrous Fillers to Manufacture Ultra High Ash/Performance Paper  

SciTech Connect

The paper industry is one of the largest users of energy and emitters of CO2 in the US manufacturing industry. In addition to that, it is facing tremendous financial pressure due to lower cost imports. The fine paper industry has shrunk from 15 million tons per year production to 10 million tons per year in the last 5 years. This has resulted in mill closures and job loses. The AF&PA and the DOE formed a program called Agenda 2020 to help in funding to develop breakthrough technologies to provide help in meeting these challenges. The objectives of this project were to optimize and scale-up Fibrous Fillers technology, ready for commercial deployment and to develop ultra high ash/high performance paper using Fibrous Fillers. The goal was to reduce energy consumption, carbon footprint, and cost of manufacturing paper and related industries. GRI International (GRI) has been able to demonstrate the techno - economic feasibility and economic advantages of using its various products in both handsheets as well as in commercial paper mills. GRI has also been able to develop sophisticated models that demonstrate the effect of combinations of GRI's fillers at multiple filler levels. GRI has also been able to develop, optimize, and successfully scale-up new products for use in commercial paper mills.

Dr. VIjay K. Mathur

2009-04-30T23:59:59.000Z

386

Effects of Nonaqueous Electrolytes on Primary Li-Air Batteries  

SciTech Connect

The effects of nonaqueous electrolytes on the performance of primary Li-air batteries operated in dry air environment have been investigated. Organic solvents with low volatility and low moisture absorption are necessary to minimize the change of electrolyte compositions and the reaction between Li anode and water during the discharge process. The polarity of aprotic solvents outweighs the viscosity, ion conductivity and oxygen solubility on the performance of Li-air batteries once these latter properties attain certain reasonable level, because the solvent polarity significantly affects the number of tri-phase regions formed by oxygen, electrolyte, and active carbons (with catalyst) in the air electrode. The most feasible electrolyte formulation is the system of LiTFSI in PC/EC mixtures, whose performance is relatively insensitive to PC/EC ratio and salt concentration. The quantity of such electrolyte added to a Li-air cell has notably effects on the discharge performance of the Li-air battery as well, and a maximum in capacity is observed as a function of electrolyte amount. The coordination effect from the additives or co-solvents [tris(pentafluorophenyl)borane and crown ethers in this study] also greatly affects the discharge performance of a Li-air battery.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-06-14T23:59:59.000Z

387

Understanding Li+ Battery Operation Lessens Charging Safety Concerns  

E-Print Network (OSTI)

Abstract: Due to the high energy/power density, in relation to the weight and volume of Lithium-ion (Li+) battery technology, there are some lingering safety concerns when charging and discharging the batteries. Although an already mature technology, improvements to Li+ battery operation are ongoing. This application note describes some of those improvements. It also presents various charging control schemes to ensure that the cells are properly charged using constant-current, constant-voltage (CCCV) approaches. Several charging circuits illustrate approaches for single-cell and multiple-cell Li+ chargers.

unknown authors

2007-01-01T23:59:59.000Z

388

Effects of electrolyte salts on the performance of Li-O2 batteries  

SciTech Connect

It is well known that the stability of nonaqueous electrolyte is critical for the rechargeable Li-O2 batteries. Although stability of many solvents used in the electrolytes has been investigated, considerably less attention has been paid to the stability of electrolyte salt which is the second major component. Herein, we report the systematic investigation of the stability of seven common lithium salts in tetraglyme used as electrolytes for Li-O2 batteries. The discharge products of Li-O2 reaction were analyzed by X-ray diffraction, X-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy. The performance of Li-O2 batteries was strongly affected by the salt used in the electrolyte. Lithium tetrafluoroborate (LiBF4) and lithium bis(oxalato)borate (LiBOB) decompose and form LiF and lithium borates, respectively during the discharge of Li-O2 batteries. Several other salts, including lithium bis(trifluoromethane)sulfonamide (LiTFSI), lithium trifluoromethanesulfonate (LiTf), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4) , and lithium bromide (LiBr) led to the discharge products which mainly consisted of Li2O2 and only minor signs of decomposition of LiTFSI, LiTf, LPF6 and LiClO4 were detected. LiBr showed the best stability during the discharge process. As for the cycling performance, LiTf and LiTFSI were the best among the studied salts. In addition to the instability of lithium salts, decomposition of tetraglyme solvent was a more significant factor contributing to the limited cycling stability. Thus a more stable nonaqueous electrolyte including organic solvent and lithium salt still need to be further developed to reach a fully reversible Li-O2 battery.

Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Burton, Sarah D.; Cosimbescu, Lelia; Gross, Mark E.; Zhang, Jiguang

2013-02-05T23:59:59.000Z

389

Giants reveal what dwarfs conceal: Li abundance in lower RGB stars as diagnostic of the primordial Li  

E-Print Network (OSTI)

The discrepancy between cosmological Li abundance inferred from Population II dwarf stars and that derived from WMAP/BBNS is still far from being solved.We investigated, as an alternative route, the use of Li abundances in Population II lower RGB stars as empirical diagnostic of the cosmological Li. Both theory and observations suggest that the surface A(Li) in red giants after the completion of the first dredge-up and before the RGB bump, are significantly less sensitive to the efficiency of atomic diffusion, compared with dwarf stars. Standard stellar models computed under different physical assumptions show that the inclusion of the atomic diffusion has an impact of 0.07dex in the determination of A(Li)0 (much smaller than the case of MS stars) and it is basically unaffected by reasonable variations of other parameters (overshooting, age,initial Y, mixing length). We have determined the surface Li content of 17 Halo lower RGB stars,in the metallicity range [Fe/H]=-3.4 /-1.4 dex. The initial Li has then bee...

Mucciarelli, A; Bonifacio, P

2011-01-01T23:59:59.000Z

390

Trophic structure and metal bioaccumulation differences in multiple fish species exposed to coal ash-associated metals  

Science Conference Proceedings (OSTI)

On December 22, 2008 a dike containing coal fly ash from the Tennessee Valley Authority Kingston Fossil Plant near Kingston Tennessee USA failed and resulted in the largest coal ash spill in U.S. history. Coal ash, the by-product of coal combustion, is known to contain multiple contaminants of concern, including arsenic and selenium. The purpose of this study was to investigate the bioaccumulation of arsenic and selenium and to identify possible differences in trophic dynamics in feral fish at various sites in the vicinity of the Kingston coal ash spill. Elevated levels of arsenic and selenium were observed in various tissues of largemouth bass, white crappie, bluegill and redear sunfish from sites associated with the Kingston coal ash spill. Highest concentrations of selenium were found in redear sunfish with liver concentrations as high as 24.83 mg/kg dry weight and ovary concentrations up to 10.40 mg/kg dry weight at coal ash-associated sites. To help explain the elevated selenium levels observed in redear sunfish, investigations into the gut pH and trophic dynamics of redear sunfish and bluegill were conducted which demonstrated a large difference in the gut physiology between these two species. Redear sunfish stomach and intestinal pH was found to be 1.1 and 0.16 pH units higher than in bluegill, respectively. In addition, fish from coal ash-associated sites showed enrichment of 15N & 13C compared to no ash sites, indicating differences in food web dynamics between sites. These results imply the incorporation of coal ash-associated compounds into local food webs and/or a shift in diet at ash sites compared to the no ash reference sites. Based on these results, further investigation into a broader food web at ash-associated sites is warranted.

Otter, Ryan [Middle Tennessee State University; Bailey, Frank [Middle Tennessee State University; Fortner, Allison M [ORNL; Adams, Marshall [ORNL

2012-01-01T23:59:59.000Z

391

Risk ranking of bioaccessible metals from fly ash dissolved in simulated lung and gut fluids  

Science Conference Proceedings (OSTI)

Power plant fly ash from two fuels, coal and a mixture of coal and shredded tires were evaluated for trace metal solubility in simulated human lung and gut fluids (SLF and SGF, respectively) to estimate bioaccessibility. The proportion of bioaccessible to total metal ranged from zero (V) to 80% (Zn) for coal-derived ash in SLF and from 2 (Th) to 100% (Cu) for tire-derived fly ash in SGF. The tire-derived ash contained much more Zn. However, Zn ranked only 5th of the various toxic metals in SGF compared with international regulations for ingestion. On the basis of total concentrations, the metals closest to exceeding limits based on international regulations for inhalation were Cr, Pb, and Al. On dissolution in SLF, the most limiting metals were Pb, Cu, and Zn. For metals exposed to SGF there was no relative change in the top metal, Al, before and after dissolution but the second-ranked metal shifted from Pb to Ni. In most cases only a proportion of the total metal concentrations in either fly ash was soluble, and hence bioaccessible, in either biofluid. When considering the regulatory limits for inhalation of particulates, none of the metal concentrations measured were as hazardous as the fly ash particulates themselves. However, on the basis of the international ingestion regulations for Al, the maximum mass of fly ash that could be ingested is only 1 mg per day (10 mg based on bioaccessibility). It is possible that such a small mass could be consumed by exposed individuals or groups. 39 refs., 1 fig., 3 tabs.

John Twining; Peter McGlinn; Elaine Loi; Kath Smith; Reto Giere [Australian Nuclear Science and Technology Organisation, Menai, NSW (Australia)

2005-10-01T23:59:59.000Z

392

Electrochemical Investigation of Al–Li/LixFePO4 Cells in Oligo(ethylene glycol) Dimethyl Ether/LiPF6  

DOE Green Energy (OSTI)

1 M LiPF{sub 6} dissolved in oligo(ethylene glycol) dimethyl ether with a molecular weight, 500 g mol{sup -1} (OEGDME500, 1 M LiPF{sub 6}), was investigated as an electrolyte in experimental Al-Li/LiFePO{sub 4} cells. More than 60 cycles were achieved using this electrolyte in a Li-ion cell with an Al-Li alloy as an anode sandwiched between two Li x FePO{sub 4} electrodes (cathodes). Charging efficiencies of 96-100% and energy efficiencies of 86-89% were maintained during 60 cycles at low current densities. A theoretical investigation revealed that the specific energy can be increased up to 15% if conventional LiC{sub 6} anodes are replaced by Al-Li alloy electrodes. The specific energy and the energy density were calculated as a function of the active mass per electrode surface (charge density). The results reveal that for a charge density of 4 mAh cm{sup -2} about 160 mWh g{sup -1} can be reached with Al-Li/LiFePO{sub 4} batteries. Power limiting diffusion processes are discussed, and the power capability of Al-Li/LiFePO{sub 4} cells was experimentally evaluated using conventional electrolytes.

Wang, X.J.; Zhou, Y.N.; Lee, H.S.; Nam, K.W.; Yang, X.Q.; Haas, O.

2011-02-01T23:59:59.000Z

393

LiDAR (Laney, 2005) | Open Energy Information  

Open Energy Info (EERE)

LiDAR (Laney, 2005) LiDAR (Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: LiDAR (Laney, 2005) Exploration Activity Details Location Unspecified Exploration Technique LiDAR Activity Date Usefulness not indicated DOE-funding Unknown Notes Design of Sampling Strategies to Detect CO2 Emissions From Hidden Geothermal Systems, Lewicki, Oldenburg and Kennedy. The objective of this project is to investigate geothermal CO2 monitoring in the near surface as a tool to discover hidden geothermal reservoirs. A primary goal of this project is to develop an approach that places emphasis on cost and time-efficient near-surface exploration methods and yields results to guide and focus more cost-intensive geophysical measurements, installation of

394

Batteries - Next-generation Li-ion batteries Breakout session  

NLE Websites -- All DOE Office Websites (Extended Search)

Next-generation Li-ion batteries Next-generation Li-ion batteries EV Everywhere Workshop July 26, 2012 Breakout Session #1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the Targets * Overall, everything is achievable, but, clearly, the cost targets are dramatic, particularly for AEV 300. (I have discussed this with Yet-Ming Chiang, who has a good feel for cost reductions, both their importance and interesting approaches.) * AEV 100 achievable with a good silicon/graphite composite anode and LMRNMC (unsure timeline) * AEV 300 would require cycleable Li-metal anode and UHVHC cathode (can't get there with Li-ion intercalation on both electrodes) (unsure timeline) Barriers Interfering with Reaching the Targets * Pack - too high a fraction of inactive materials/inefficient engineering designs.

395

Electrochemical Experiments Used to Study Li-ion Batteries  

DOE Green Energy (OSTI)

This is the third of three talks on nanostructures for Li-ion batteries. The talks provide an up-to-date review of the issues and challenges facing Li-ion battery research with special focus on how nanostructures/nanotechnology are being applied to this field. Novel materials reported as prospective candidates for anode, cathode and electrolyte will be summarized. The expected role of nanostructures in improving the performance of Li-ion batteries and the actual pros and cons of using such structures in this device will be addressed. Electrochemical experiments used to study Li-ion batteries will also be discussed. This includes the introduction to the standard experimental set-up and how experimental data (from charge-discharge experiments, cyclic voltammetry, impedance spectroscopy, etc) are interpreted.

Mukaibo, Hitomi (University of Florida, Martin Research Group)

2010-06-04T23:59:59.000Z

396

Li-Ion Batteries for Transportation Applications II  

Science Conference Proceedings (OSTI)

Oct 27, 2009 ... Energy Storage: Materials, Systems, and Applications: Li-Ion Batteries for ... storage and utilization of renewable energies like solar and wind. Cost ... Rahul Singhal1; Karina Asmar1; Ram Katiyar1; 1University of Puerto Rico

397

Transport and Failure in Li-ion Batteries | Stanford Synchrotron...  

NLE Websites -- All DOE Office Websites (Extended Search)

Transport and Failure in Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well...

398

Jan-Mou Li - Research Staff - Center for Transportation Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

Publications: Han, L. D., Li, J-M., and Urbanik, T. (2009) Impacts of Inter-Cycle Demand Fluctuations on Delay. Journal of Transportation Engineering, Vol. 135, No. 5, pp....

399

Li batteries with porous sol-gel cathodes  

Science Conference Proceedings (OSTI)

The structure presented is a high-capacity micro battery, lithium based, consisting of porous cathode, solid electrolyte and silver anode. A spinel LiNi"0"."4La"0"."1Mn"1"."5O"4 sol-gel layer was deposited on a porous ceramic substrate to give high specific ... Keywords: Layer oxides, Li ion batteries, Porous cathode, Sol-gel

Antonela Dima; Francesco Della Corte; Maurizio Casalino; Ivo Rendina

2007-04-01T23:59:59.000Z

400

TREATMENT OF CYANIDE SOLUTIONS AND SLURRIES USING AIR-SPARGED HYDROCYCLONE (ASH) TECHNOLOGY  

Science Conference Proceedings (OSTI)

The two-year Department of Energy (DOE) project ''Treatment of Cyanide Solutions and Slurries Using Air-Sparged Hydrocyclone (ASH) Technology'' (ASH/CN) has been completed. This project was also sponsored by industrial partners, ZPM Inc., Elbow Creek Engineering, Solvay Minerals, EIMCO-Baker Process, Newmont Mining Corporation, Cherokee Chemical Co., Placer Dome Inc., Earthworks Technology, Dawson Laboratories and Kennecott Minerals. Development of a new technology using the air-sparged hydrocyclone (ASH) as a reactor for either cyanide recovery or destruction was the research objective. It was expected that the ASH could potentially replace the conventional stripping tower presently used for HCN stripping and absorption with reduced power costs. The project was carried out in two phases. The first phase included calculation of basic processing parameters for ASH technology, development of the flowsheet, and design/adaptation of the ASH mobile system for hydrogen cyanide (HCN) recovery from cyanide solutions. This was necessary because the ASH was previously used for volatile organics removal from contaminated water. The design and modification of the ASH were performed with the help from ZPM Inc. personnel. Among the modifications, the system was adapted for operation under negative pressure to assure safe operating conditions. The research staff was trained in the safe use of cyanide and in hazardous material regulations. Cyanide chemistry was reviewed resulting in identification of proper chemical dosages for cyanide destruction, after completion of each pilot plant run. The second phase of the research consisted of three field tests that were performed at the Newmont Mining Corporation gold cyanidation plant near Midas, Nevada. The first field test was run between July 26 and August 2, 2002, and the objective was to demonstrate continuous operation of the modified ASH mobile system. ASH units were applied for both stripping and absorption, to recover cyanide, using the acidification-volatilization-reabsorption chemistry. Plant barren cyanide solution was used during the field tests. The original ASH system used for the field tests had been designed and fabricated by ZPM Inc. to remove volatile organic compounds from ground water. The system, even with a number of modifications, could not operate at optimum conditions for cyanide recovery. Reactors and pumps installed in the mobile system only allowed for the treatment of clear solutions, not slurries. Also the original mobile system was limited with respect to Q, the relative air flow rate, and the extent of recovery in a single stage. Due to the lack of automatic controls, the system required constant supervision of the University of Utah (U/U) team. In spite of these difficulties, application of the ASH mobile system was particularly attractive due to compactness of the apparatus and less than 1 second residence time of the aqueous phase in the cyclones. The performance of the ASH system was evaluated by comparison with theoretical predictions.

Jan D. Miller; Terrence Chatwin; Jan Hupka; Doug Halbe; Tao Jiang; Bartosz Dabrowski; Lukasz Hupka

2003-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Bioaccumulation Studies Associated with the Kingston Fly Ash Spill, Spring 2009 - Fall 2010  

SciTech Connect

In December 2008, an ash dike at the Tennessee Valley Authority (TVA) Kingston Fossil Plant ruptured, releasing over one billion gallons of coal fly ash into the Emory and Clinch Rivers. Coal fly ash may contain several contaminants of concern, but of these selenium (Se) and arsenic (As) have been highlighted because of their toxicity and tendency to bioaccumulate in aquatic food chains. To assess the potential impact of the spilled fly ash on humans and the environment, a comprehensive biological and environmental monitoring program was established, for which resident aquatic organisms (among other sample media) are collected to determine contaminant exposure and evaluate the risk to humans and wildlife. Studies on bioaccumulation and fish health are major components of the TVA Biological Monitoring Program for the Kingston fly ash project. These studies were initiated in early Spring 2009 for the purposes of: (1) documenting the levels of fly ash-associated metals in various tissues of representative sentinel fish species in the area of the fly ash spill, (2) determining if exposure to fly ash-associated metals causes short, intermediate, or long-term health effects on these sentinel fish species, (3) assessing if there are causal relationships between exposure (to metals) and effects on fish, (4) evaluating, along with information regarding other ecological and physicochemical studies, the nature and route of contaminant transfer though food chains into higher level consumers, (5) providing important information for the Ecological Risk Assessment (ERA) for the Kingston fly ash project, and (6) serving as an important technology transfer or model study focused on how to best evaluate the environmental effects of fly ash, not only at the Kingston site, but also at sites on other aquatic systems where coal-fired generating stations are located. This report summarizes the bioaccumulation results from the first two years of study after the fly ash spill, including four seasonal collections: Spring 2009, Fall 2009, Spring 2010, and Fall 2010. Both the Spring and Fall studies have focused on 3-4 sentinel fish species that represent different feeding habits, behaviors, and home ranges. In addition to bioaccumulation studies, the Spring investigations also included evaluation of fish health and reproductive integrity on the same fish used for bioaccumulation. Two associated reports present the fish health (Adams et al 2012) and reproductive studies (Greeley et al 2012) conducted in 2009 and 2010. The fish health study conducted in conjunction with the bioaccumulation and reproductive study is critical for assessing and evaluating possible causal relationships between contaminant exposure (bioaccumulation) and the response of fish to exposure as reflected by the various measurements of fish health. This report emphasizes evaluation of arsenic and selenium bioaccumulation in fish and consists of four related studies (Sections 2-5) including, (1) bioaccumulation in liver and ovaries, (2) bioaccumulation in whole body gizzard shad (Dorosoma cepedianum), (3) bioaccumulation in muscle tissue or fillets, and (4) a reconstruction analysis which establishes the relationship between selenium in muscle tissue and that of the whole body of bluegill (Lepomis machrochirus). Metals other than arsenic and selenium are evaluated separately in Section 6. This report focuses on selenium and arsenic for the following reasons: (1) based on baseline studies conducted in early 2009 in the Emory and Clinch River, only two potentially fly-ash related metals, selenium and arsenic, appeared to be elevated above background or reference levels, (2) selenium and arsenic are two of the metals in coal ash that are known to bioaccumulate and cause toxicity in wildlife, and (3) based on bioaccumulation studies of bluegill and carp (Cyprinus carpio) in the Stilling Pond during Spring 2009, which would represent a worst case situation for metal bioaccumulation, selenium and arsenic were the only two metals consistently elevated above background levels in fish. E

Adams, Marshall [ORNL; Brandt, Craig C [ORNL; Fortner, Allison M [ORNL

2012-05-01T23:59:59.000Z

402

Fluoro-Carbonate Solvents for Li-Ion Cells  

DOE Green Energy (OSTI)

A number of fluoro-carbonate solvents were evaluated as electrolytes for Li-ion cells. These solvents are fluorine analogs of the conventional electrolyte solvents such as dimethyl carbonate, ethylene carbonate, diethyl carbonate in Li-ion cells. Conductivity of single and mixed fluoro carbonate electrolytes containing 1 M LiPF{sub 6} was measured at different temperatures. These electrolytes did not freeze at -40 C. We are evaluating currently, the irreversible 1st cycle capacity loss in carbon anode in these electrolytes and the capacity loss will be compared to that in the conventional electrolytes. Voltage stability windows of the electrolytes were measured at room temperature and compared with that of the conventional electrolytes. The fluoro-carbon electrolytes appear to be more stable than the conventional electrolytes near Li voltage. Few preliminary electrochemical data of the fluoro-carbonate solvents in full cells are reported in the literature. For example, some of the fluorocarbonate solvents appear to have a wider voltage window than the conventional electrolyte solvents. For example, methyl 2,2,2 trifluoro ethyl carbonate containing 1 M LiPF{sub 6} electrolyte has a decomposition voltage exceeding 6 V vs. Li compared to <5 V for conventional electrolytes. The solvent also appears to be stable in contact with lithium at room temperature.

NAGASUBRAMANIAN,GANESAN

1999-09-17T23:59:59.000Z

403

Comparison of Small Polaron Migration and Phase Separation in Olivine LiMnPO? and LiFePO? using Hybrid Density Functional Theory  

E-Print Network (OSTI)

Using hybrid density functional theory based on the Heyd-Scuseria-Ernzerhof (HSE06) functional, we compared polaron migration and phase separation in olivine LiMnPO? to LiFePO?. The barriers for free hole and electron ...

Ong, Shyue Ping

404

Electrochemical characterization of Li4Ti5O12/C anode material prepared by starch-sol-assisted rheological phase method for Li-ion battery  

Science Conference Proceedings (OSTI)

Li4Ti5O12/C composite was synthesized by starch-sol-assisted rheological phase method using inexpensive raw material starch as carbon coating precursor. The Li4Ti5O12/C powder was characterized ...

Zhenpo Wang, Guowei Xie, Lijun Gao

2012-01-01T23:59:59.000Z

405

Fly ash properties and mercury sorbent affect mercury release from curing concrete  

Science Conference Proceedings (OSTI)

The release of mercury from concrete containing fly ashes from various generator boilers and powdered activated carbon sorbent used to capture mercury was measured in laboratory experiments. Release of gaseous mercury from these concretes was less than 0.31% of the total quantity of mercury present. The observed gaseous emissions of mercury during the curing process demonstrated a dependency on the organic carbon content of the fly ash, with mercury release decreasing with increasing carbon content. Further, lower gaseous emissions of mercury were observed for concretes incorporating ash containing activated carbon sorbent than would be expected based on the observed association with organic carbon, suggesting that the powdered activated carbon more tightly binds the mercury as compared to unburned carbon in the ash. Following the initial 28-day curing interval, mercury release diminished with time. In separate leaching experiments, average mercury concentrations leached from fly ash concretes were less than 4.1 ng/L after 18 h and 7 days, demonstrating that less than 0.02% of the mercury was released during leaching. 25 refs., 4 figs., 5 tabs.

Danold W. Golightly; Chin-Min Cheng; Linda K. Weavers; Harold W. Walker; William E. Wolfe [State University, Columbus, OH (United States). Department of Civil and Environmental Engineering and Geodetic Science

2009-04-15T23:59:59.000Z

406

Role of fly ash in the removal of organic pollutants from wastewater  

Science Conference Proceedings (OSTI)

Fly ash, a relatively abundant and inexpensive material, is currently being investigated as an adsorbent for the removal of various organic pollutants from wastewater. The wastewater contains various types of phenolic compounds, such as chloro, nitro, amino, and other substituted compounds. Various types of pesticides, such as lindane, malathion, carbofuran, etc., and dyes, such as, methylene blue, crystal violet, malachite green, etc., are also present in the wastewater. These contaminants pollute the water stream. These organic pollutants, such as phenolic compounds, pesticides, and dyes, etc., can be removed very effectively using fly ash as adsorbent. This article presents a detailed review on the role of fly ash in the removal of organic pollutants from wastewater. Adsorption of various pollutants using fly ash has been reviewed. The adsorption mechanism and other influencing factors, favorable conditions, and competitive ions, etc., on the adsorption process have also been discussed in this paper. It is evident from the review that fly ash has demonstrated good removal capabilities for various organic compounds. 171 refs., 3 figs., 5 tabs.

M. Ahmaruzzaman [National Institute of Technology, Silchar (India). Department of Chemistry

2009-03-15T23:59:59.000Z

407

Tensile strength of ash cake beds at high-temperature conditions  

SciTech Connect

The Energy and Environmental Research Center (EERC) is working with Electric Power Research Institute (EPRI) and a consortium of companies in partnership with the US Department of Energy (DOE) to perform the research necessary to determine the factors that cause hot-gas cleanup filters to be blinded by ash or to develop deposits that can bridge the filters and cause them to fail. The primary deliverable will be a graphics-driven computer model that can be used as an engineering tool to help predict ash-related hot-gas filter problems based on analyses of coal and sorbent, as well as system operating parameters. This paper presents preliminary testing data on determining the tensile strengths of coal ash particles at elevated temperatures and simulated combustor gas conditions. The range in temperatures for tensile testing is ambient to 900 C. The simulated gas atmosphere includes carbon dioxide, water vapor, oxygen, sulfur dioxide, sodium chloride, hydrochloric acid, and nitrogen. At present, all testing has been performed using ash from the Westinghouse advanced particle filter (APF) at the American Electric Power Service Corporation (AEP) Tidd pressurized fluidized-bed combustor (PFBC) demonstration plant in Ohio. Other sources of filter ashes, including several from non-American PFBC systems, will also be evaluated.

Dockter, B.A.; Hurley, J.P.

1996-12-31T23:59:59.000Z

408

Use of Brazilian sugarcane bagasse ash in concrete as sand replacement  

SciTech Connect

Sugarcane today plays a major role in the worldwide economy, and Brazil is the leading producer of sugar and alcohol, which are important international commodities. The production process generates bagasse as a waste, which is used as fuel to stoke boilers that produce steam for electricity cogeneration. The final product of this burning is residual sugarcane bagasse ash (SBA), which is normally used as fertilizer in sugarcane plantations. Ash stands out among agroindustrial wastes because it results from energy generating processes. Many types of ash do not have hydraulic or pozzolanic reactivity, but can be used in civil construction as inert materials. The present study used ash collected from four sugar mills in the region of Sao Carlos, SP, Brazil, which is one of the world's largest producers of sugarcane. The ash samples were subjected to chemical characterization, sieve analysis, determination of specific gravity, X-ray diffraction, scanning electron microscopy, and solubilization and leaching tests. Mortars and concretes with SBA as sand replacement were produced and tests were carried out: compressive strength, tensile strength and elastic modulus. The results indicated that the SBA samples presented physical properties similar to those of natural sand. Several heavy metals were found in the SBA samples, indicating the need to restrict its use as a fertilizer. The mortars produced with SBA in place of sand showed better mechanical results than the reference samples. SBA can be used as a partial substitute of sand in concretes made with cement slag-modified Portland cement.

Sales, Almir, E-mail: almir@ufscar.b [Department of Civil Engineering, UFSCar, Via Washington Luis, km 235, Monjolinho, 13565-905 Sao Carlos, SP (Brazil); Lima, Sofia Araujo, E-mail: sofiaalima@yahoo.com.b [Department of Civil Engineering, UFSCar, Via Washington Luis, km 235, Monjolinho, 13565-905 Sao Carlos, SP (Brazil)

2010-06-15T23:59:59.000Z

409

Development of Oxidative Lime Pretreatment and Shock Treatment to Produce Highly Digestible Lignocellulose for Biofuel and Ruminant Feed Applications  

E-Print Network (OSTI)

At present, the United States generates biofuels (ethanol) from corn grain. Unfortunately, low crop yields and limited growth regions result in limited availability. Furthermore, the use of staple food crops for ethanol production has generated a highly controversial food vs. fuel debate. Because of its high abundance and relatively low cost, lignocellulosic biomass is a promising alternative feedstock for biofuel production; however, structural features of lignocellulose limit accessibility of enzymes or microorganisms. These structural barriers include high lignin content, acetyl groups on hemicellulose, high cellulose crystallinity, cellulose degree of polymerization, and small pore volume. To overcome these barriers, a variety of pretreatment processes (chemical and mechanical) have been developed. Oxidative-lime pretreatment (OLP) is highly effective at reducing lignin content and removing acetyl groups from hemicellulose. Combining OLP with a mechanical treatment process greatly enhances the enzymatic digestibility of lignocellulose. Recommended OLP conditions were determined for Dacotah (120 °C, 6.89-bar O2, 240 min) and Alamo (110 °C, 6-89-bar O2, 240 min) switchgrass. Using recommended conditions, 72-h glucan digestibilities (g glucan hydrolyzed/100 g glucan in raw biomass; 15 filter paper units/g raw glucan) of 85.2 and 88.5 were achieved for Dacotah and Alamo, respectively. Adding ball milling to OLP further enhanced glucan digestibility to 91.1 (Dacotah) and 90.0 (Alamo). In previous studies, shock treatment achieved promising results, but was often inconsistent. This work refined shock treatment with a focus on using consistent procedures and performance analysis. The combination of OLP and shock treatment enhanced the 72-h glucan digestibility of several promising biomass feedstocks: bagasse (74.0), corn stover (92.0), poplar wood (94.0), sorghum (71.8), and switchgrass (89.0). Highly digestible lignocellulose can also be used as ruminant animal feed. Shock treatment plus OLP increased the total digestible nutrients (TDNN; g nutrients digested/100 g organic matter) of corn stover from 51.9 (untreated) to 72.6. Adding in pre-washed corn stover solubles to produce a combined feed (17.8 percent corn stover solubles and 82.2 percent shock OLP corn stover) increased TDNN to 74.9. Mixing in enough solubilized protein to match the crude protein content of corn grain further improved TDNN to 75.5, only 12.6 less than corn grain.

Falls, Matthew David

2011-08-01T23:59:59.000Z

410

Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material  

E-Print Network (OSTI)

We investigated the structural stability and electrochemical properties of LiMnBO3 in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on monoclinic ...

Kim, Jae Chul

411

Electrochemical Behavior and Li Diffusion Study of LiCoO? Thin Film Electrodes Prepared by PLD  

E-Print Network (OSTI)

Preferred c-axis oriented LiCoO? thin films were prepared on the SiO?/Si (SOS) substrates by pulsed laser deposition (PLD). Thin film electrodes without carbon and binder are ideal samples to study the electrochemical ...

Xia, H.

412

Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material  

E-Print Network (OSTI)

We investigated the structural stability and electrochemical properties of LiMnBO[subscript 3] in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on ...

Kim, Jae Chul

413

Abstract--This paper determines if Li/CFx or LiFePO4 is beneficial for State of Charge Indicator (SOCI) design for  

E-Print Network (OSTI)

;Lithium-ion battery Modern Li-ion Battery Cathode:Anode: e-e- u o b e y e- Electrolyte LiPF6 in Ethylene Goals lithium-ion #12;Electric-Vehicle BatteriesHigh voltage cathodes Alloy anodes Li l d 2 4 6 1000 /kg Electronic Li-ion Batteries Theoretical Energy Density Source: TIAX, LLC #12;Lithium-ion battery Battery

Manic, Milos

414

Vacancy-driven anisotropic defect distribution in the battery-cathode material LiFePO4  

Science Conference Proceedings (OSTI)

Li-ion mobility in LiFePO{sub 4}, a key property for energy applications, is impeded by Fe antisite defects (Fe{sub Li}) that form in select b-axis channels. Here we combine first-principles calculations, statistical mechanics, and scanning transmission electron microscopy to identify the origin of the effect: Li vacancies (V{sub Li}) are confined in one-dimensional b-axis channels, shuttling between neighboring Fe{sub Li}. Segregation in select channels results in shorter Fe{sub Li}-Fe{sub Li} spans, whereby the energy is lowered by the V{sub Li}'s spending more time bound to end-point Fe{sub Li}'s. V{sub Li}-Fe{sub Li}-V{sub Li} complexes also form, accounting for observed electron energy loss spectroscopy features.

Lee, Jaekwang [Vanderbilt University; Zhou, Wu [Vanderbilt University; Idrobo Tapia, Juan C [ORNL; Pennycook, Stephen J [ORNL; Pantelides, Sokrates T. [Vanderbilt University; Biegalski, Michael D [ORNL

2011-01-01T23:59:59.000Z

415

Leaching and toxicity behavior of coal-biomass waste cocombustion ashes  

Science Conference Proceedings (OSTI)

Land disposal of ash residues, obtained from the cocombustion of Greek lignite with biomass wastes, is known to create problems due to the harmful constituents present. In this regard, the leachability of trace elements from lignite, biomass, and blends cocombustion ashes was investigated by using the Toxicity Characteristic Leaching Procedure (TCLP) of the US Environmental Protection Agency (US EPA). In this work, the toxicity of the aqueous leachates and the concentrations of the metals obtained from the leaching procedure were measured using the Microtox test (Vibrio fischen) and inductive coupled plasma-atomic emission spectrometer (ICP-AES), respectively. The toxic effects of most leachates on Vibrio fischeri were found to be significantly low in both 45% and 82% screening test protocols. However, the liquid sample originating from olive kernels fly ash (FA4) caused the highest toxic effect in both protocols, which can be attributed to its relatively high concentrations of As, Cd, Co, Cu, Mn, Ni, and Zn.

Skodras, G.; Prokopidou, M.; Sakellaropoulos, G.P. [Aristotle University in Thessaloniki, Thessaloniki (Greece). Dept. for Chemical Engineering

2006-08-15T23:59:59.000Z

416

Lemons, and Limes  

E-Print Network (OSTI)

Abstract: Green initiatives bring home the issue of wasting standby power. Through reducing their usage of standby power, U.S. households can save an average of $100 per year. Battery life in portable devices is important, but this application note shows that power-saving appliances in our homes are also critical to reduce environmental waste. Maxim is taking the lead in energy-efficient integrated circuits, and this document lists examples of Maxim parts used to reduce power in appliances, computers, and set-top boxes. Jim Henson's creation, Kermit the Frog says, "It's not easy being green. " We concur that saving energy is difficult, but very necessary. Smart circuit designers and progressive companies are meeting consumer's expectations in this aspect. And the smallest details are critical: power efficiency is one measured in microamperes (µAs), one-millionth of an ampere. For comparison, a 60W incandescent light bulb draws 0.5A. That is 500,000µA. Why is it necessary to measure so precisely? Because it is the sum of all currents that count and like any budget, one must reduce every cost, no matter how small. Obviously in a battery-powered device, customers are sensitive about battery life. Not so obviously, plug-in appliances also have a cost associated with just being plugged in. When a device is "off", but displays a power indicator while waiting for a remote command, button, or timer, it is consuming standby power. What is the cost of standby power? That 60W bulb can cost $14.65 * a month if it runs 24/7. An appliance that draws 1W in standby power can cost $0.25 without doing any practical work. Walk around a typical home and count the appliances, TVs, radios, stereos,

unknown authors

2011-01-01T23:59:59.000Z

417

Lemons, and Limes  

E-Print Network (OSTI)

Abstract: Green initiatives bring home the issue of wasting standby power. Through reducing their usage of standby power, U.S. households can save an average of $100 per year. Battery life in portable devices is important, but this application note shows that power-saving appliances in our homes are also critical to reduce environmental waste. Maxim is taking the lead in energy-efficient integrated circuits, and this document lists examples of Maxim parts used to reduce power in appliances, computers, and set-top boxes. Jim Henson's creation, Kermit the Frog says, "It's not easy being green. " We concur that saving energy is difficult, but very necessary. Smart circuit designers and progressive companies are meeting consumer's expectations in this aspect. And the smallest details are critical: power efficiency is one measured in microamperes (µAs), one-millionth of an ampere. For comparison, a 60W incandescent light bulb draws 0.5A. That is 500,000µA. Why is it necessary to measure so precisely? Because it is the sum of all currents that count and like any budget, one must reduce every cost, no matter how small. Obviously in a batterypowered device, customers are sensitive about battery life. Not so obviously, plug-in appliances Attend this brief webcast by Maxim on TechOnline

unknown authors

2011-01-01T23:59:59.000Z

418

In situ XRD Studies of Li-ion Cells with Mixed LiMn2O4 and LiCo1/3Ni1/3Mn1/3O2 Composite Cathode  

Science Conference Proceedings (OSTI)

The structural changes of the composite cathode made by mixing spinel LiMn2O4 and layered LiNi1/3Co1/3Mn1/3O2 in 1:1 wt% in both Li-half and Li-ion cells during charge/discharge are studied by in situ XRD. During the first charge up to {approx}5.2 V vs. Li/Li+, the in situ XRD spectra for the composite cathode in the Li-half cell track the structural changes of each component. At the early stage of charge, the lithium extraction takes place in the LiNi1/3Co1/3Mn1/3O2 component only. When the cell voltage reaches at {approx}4.0 V vs. Li/Li+, lithium extraction from the spinel LiMn2O4 component starts and becomes the major contributor for the cell capacity due to the higher rate capability of LiMn2O4. When the voltage passed 4.3 V, the major structural changes are from the LiNi1/3Co1/3Mn1/3O2 component, while the LiMn2O4 component is almost unchanged. In the Li-ion cell using a MCMB anode and a composite cathode cycled between 2.5 V and 4.2 V, the structural changes are dominated by the spinel LiMn2O4 component, with much less changes in the layered LiNi1/3Co1/3Mn1/3O2 component, comparing with the Li-half cell results. These results give us valuable information about the structural changes relating to the contributions of each individual component to the cell capacity at certain charge/discharge state, which are helpful in designing and optimizing the composite cathode using spinel- and layered-type materials for Li-ion battery research.

Nam, K.; Yoon, W; Shin, H; Chung, K; Choi, S; Yang, X

2009-01-01T23:59:59.000Z

419

The reaction of clean Li surfaces with small molecules in ultrahigh vacuum. 2: Water  

DOE Green Energy (OSTI)

Reactions at the Li/H{sub 2}O interface were studied at 160 to 290 K in ultrahigh vacuum by a combination of spectroscopic ellipsometry and Auger electron spectroscopy. Ice multilayers, ca. 100 ML thick, were deposited on clean Li at 160 K. The evaporation rate of water at 160 K is sufficiently slow that the ice layer remains on the surface for about 1 h. After 10 min at 160 k, a pure LiOH layer ca. 70 {angstrom} thick is produced, and after 1 h there is evidence of a slow conversion to LiOH to Li{sub 2}O in the layer, probably at the Li/LiOH interface. Raising the temperature to 240 K results in desorption of the adsorbed water and conversion of all the LiOH to a porous (60% void) layer composed mostly of Li{sub 2}O (35%) with some metallic Li mixed in. Raising the temperature further to 290 K results in densification of the layer by both collapse of the voids and by diffusion of Li into the interstices of the Li{sub 2}O, increasing the Li content to 27% and shrinking the film thickness to 26 {angstrom}. Based on these results, a model for the behavior of small amounts of water in Li battery electrolyte is presented.

Zhuang, G.; Ross, P.N. Jr.; Kong, F.P.; McLarnon, F. [Lawrence Berkeley National Lab., CA (United States). Chemical Sciences Div.]|[Univ. of California, Berkeley, CA (United States). Environmental Energy Technologies Div.

1998-01-01T23:59:59.000Z

420

Mechanical Properties and Durability of Concrete Made with High-Volume Fly Ash Blended Cement Produced in a Cement Plant: Commercial -Scale Trial Results  

Science Conference Proceedings (OSTI)

This interim report documents the preliminary results of the commercial-scale production of a high-volume fly ash (HVFA) blended cement, using up to 55 percent fly ash to replace the portland cement.

2000-12-12T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Crystal structure of the N-terminal region of human Ash2L shows a winged-helix motif involved in DNA binding  

Science Conference Proceedings (OSTI)

Ash2L is a core component of the MLL family histone methyltransferases and has an important role in regulating the methylation of histone H3 on lysine 4. Here, we report the crystal structure of the N-terminal domain of Ash2L and reveal a new function of Ash2L. The structure shows that Ash2L contains an atypical PHD finger that does not have histone tail-binding activity. Unexpectedly, the structure shows a previously unrecognized winged-helix motif that directly binds to DNA. The DNA-binding-deficient mutants of Ash2L reduced Ash2L localization to the HOX locus. Strikingly, a single mutation in Ash2L{sub WH} (K131A) breaks the chromatin domain boundary, suggesting that Ash2L also has a role in chromosome demarcation.

Chen, Yong; Wan, Bingbing; Wang, Kevin C.; Cao, Fang; Yang, Yuting; Protacio, Angeline; Dou, Yali; Chang, Howard Y.; Lei, Ming (Michigan-Med); (HHMI)

2011-09-06T23:59:59.000Z

422

Virtual Globe visualization of ash-aviation encounters, with the special case of the 1989 Redoubt-KLM incident  

Science Conference Proceedings (OSTI)

The impact of natural hazards on the local environment causes major issues for those agencies responsible for warning and understanding of the risks. Analysis of past events can assist and improve future warning capabilities. Here, volcanic ash-aviation ... Keywords: Dispersion modeling and Virtual Globes, Puff, Volcanic ash

P. W. Webley

2011-01-01T23:59:59.000Z

423

The role of ammonia on mercury leaching from coal fly ash Jianmin Wang a,*, Tian Wang a  

E-Print Network (OSTI)

analysis of fly ash disposal in mined areas. In: Proceedings of the 12th International Symposium on CoalThe role of ammonia on mercury leaching from coal fly ash Jianmin Wang a,*, Tian Wang a , Harmanjit, 2005). CAIR permanently caps emissions of NOx and SOx from large stationary sources including coal

Ragsdell, Kenneth M.

424

Direct seeding of ash (Fraxinus excelsior L.) and sycamore (Acer pseudoplatanus L.): The effects of sowing date,  

E-Print Network (OSTI)

Direct seeding of ash (Fraxinus excelsior L.) and sycamore (Acer pseudoplatanus L.): The effects September 2006 Abstract Direct seeding is an alternative method to conventional planting for woodland-emergent herbicides, and cultivation and protection on the emergence and survival of direct-sown ash (Fraxinus

425

Proceedings, World Of Coal Ash, April 11-15, 2005, Lexington, KY, USA Pultrusion of Fabric Reinforced High Flyash  

E-Print Network (OSTI)

Proceedings, World Of Coal Ash, April 11-15, 2005, Lexington, KY, USA Pultrusion of Fabric Reinforced High Flyash Blended Cement Composites Barzin Mobasher(1) , Alva Peled (2) , and Jitendra of elasticity. #12;Proceedings, World Of Coal Ash, April 11-15, 2005, Lexington, KY, USA In addition to ease

Mobasher, Barzin

426

Volcanic Ash Transport from Mount Asama to the Tokyo Metropolitan Area Influenced by Large-Scale Local Wind Circulation  

Science Conference Proceedings (OSTI)

The eruption of the Mount Asama volcano on 16 September 2004 produced an ash cloud and led to ashfall in the Tokyo metropolitan area that lies on the Kanto Plain. Satellite images showed the ash cloud drifting toward the south in the morning but ...

Nobumitsu Tsunematsu; Tomohiro Nagai; Toshiyuki Murayama; Ahoro Adachi; Yasuhiro Murayama

2008-04-01T23:59:59.000Z

427

Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants  

DOE Green Energy (OSTI)

This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

2003-12-31T23:59:59.000Z

428

(A small-scale study of Rocky Flats uncalcined incinerator ash dissolution and filtrate anion exchange)  

SciTech Connect

Small scale experimentation was conducted with incinerator ash in the nitric/hydrofluoric acid cascade dissolver and the anion exchange systems at Rocky Flats and Los Alamos National Laboratories for the purpose of determining the following: to determine the relationship between calcium fluoride dissolution feed levels and plutonium dissolution yields. To determine the relationship between calcium fluoride feed levels to dissolution, and the performance of anion exchange when processing dissolution filtrate. To determine the effect of carbonaceous materials on the dissolution and anion exchange when recovering plutonium from incinerator ash.

Not Available

1990-01-01T23:59:59.000Z

429

The Effects of Trona Use in Flue Gas on Fly Ash Pond Management  

Science Conference Proceedings (OSTI)

In this study, researchers analyzed the effect of the use of trona on the dynamics of a fly ash pond (FAP) at a plant in Ohio, using both field and laboratory measurements. They compared the chemical concentrations and biological dynamics in the FAP from four years before the onset of trona use with those from two years after trona use was implemented. They compared the chemical composition of fly ash from two generating units with trona injection systems with that from a generating unit without trona. T...

2011-06-21T23:59:59.000Z

430

Leaching Assessment of Fly Ash, Flue Gas Desulfurization Filter Cake, and Fixated Scrubber Solids  

Science Conference Proceedings (OSTI)

The by-products of coal combustion (for example, fly ash and flue gas desulfurization filter cake) are an important environmental concern due to potential leaching of trace constituents and the large volume of residues produced. About 40% of these by-products may be utilized as raw materials outside of the energy sector; the remaining 60% of the coal combustion products (CCPs) are disposed of as waste. At Plant 14090, the subject of this report, fly ash and scrubber sludge are blended with quicklime ...

2012-12-03T23:59:59.000Z

431

Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants  

SciTech Connect

This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

2003-12-31T23:59:59.000Z

432

Radiolytic gas generation in concrete made with incinerator ash containing transuranium nuclides  

DOE Green Energy (OSTI)

The effects of various factors on H/sub 2/ generation by alpha radiolysis of concrete containing TRU incinerator ash were studied. Methods for reducing H/sub 2/ generation were investigated. Samples of Portland and high-alumina cement containing up to 30% calcined ash (dry basis) were doped with /sup 238/PuO/sub 2/. Gas pressures were measured as a function of radiation dose; gas compositions were determined. Gas yields were calculated in terms of G values (molecules produced per 100 eV of alpha energy absorbed). These yields were used to estimate pressures in containers of radioactive concrete waste during storage. 4 figures.

Bibler, N.E.

1979-01-01T23:59:59.000Z

433

Li-Ion Batteries from LiFePO4 Cathode and Anatase/Graphene Composite Anode for Stationary Energy Storage  

SciTech Connect

Li-ion batteries based on LiFePO4 cathode and anatase TiO2/graphene anode were investigated for possible stationary energy storage application. Fine-structured LiFePO4 was synthesized by novel molten surfactant approach. Anatase TiO2/graphene nanocomposite was prepared via self assembly method. The full cell that operated at flat 1.6V demonstrated negligible fade after more than 700 cycles. The LiFePO4/TiO2 combination Li-ion battery is inexpensive, environmentally benign, safe and stable. Therefore, it can be practically applied as stationary energy storage for renewable power sources.

Choi, Daiwon; Wang, Donghai; Viswanathan, Vilayanur V.; Bae, In-Tae; Wang, Wei; Nie, Zimin; Zhang, Jiguang; Graff, Gordon L.; Liu, Jun; Yang, Zhenguo; Duong, Tien Q.

2009-11-06T23:59:59.000Z

434

Entrained-flow dry-bottom gasification of high-ash coals in coal-water slurries  

SciTech Connect

It was shown that the effective use of dry ash removal during entrained-flow gasification of coal-water slurries consists in simplification of the ash storage system and utilization of coal ash, a decrease in the coal demand, a reduction in the atmospheric emissions of noxious substances and particulate matter, and abandonment of the discharge of water used for ash slurry. According to the results of gasification of coal-water slurries (5-10 {mu}m) in a pilot oxygen-blow unit at a carbon conversion of >91%, synthesis gas containing 28.5% CO, 32.5% H{sub 2}, 8.2% CO{sub 2}, 1.5% CH{sub 4}, the rest being nitrogen, was obtained. The fly ash in its chemical composition, particle size, and density meets the requirements of the European standard EN 450 as a cement additive for concrete manufacture.

E.G. Gorlov; V.G. Andrienko; K.B. Nefedov; S.V. Lutsenko; B.K. Nefedov [Institute for Fossil Fuels, Moscow (Russian Federation)

2009-04-15T23:59:59.000Z

435

Prevention of trace and major element leaching from coal combustion products by hydrothermally-treated coal ash  

Science Conference Proceedings (OSTI)

The most important structural components of coal ash obtained by coal combustion in 'Nikola Tesla A' power plant located near Belgrade (Serbia) are amorphous alumosilicate, alpha-quartz, and mullite. The phase composition of coal ash can be altered to obtain zeolite type NaA that crystallizes in a narrow crystallization field (SiO{sub 2}/Al{sub 2}O{sub 3}; Na{sub 2}O/SiO{sub 2}; H{sub 2}O/Na{sub 2}O ratios). Basic properties (crystallization degree, chemical composition, the energy of activation) of obtained zeolites were established. Coal ash extracts treated with obtained ion-exchange material showed that zeolites obtained from coal ash were able to reduce the amounts of iron, chromium, nickel, zinc, copper, lead, and manganese in ash extracts, thus proving its potential in preventing pollution from dump effluent waters.

Adnadjevic, B.; Popovic, A.; Mikasinovic, B. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

2009-07-01T23:59:59.000Z

436

Qing'an Li - Argonne National Laboratories, Materials Sicence Division  

NLE Websites -- All DOE Office Websites (Extended Search)

EM > Qing'an Li EM > Qing'an Li Qing'an Li Scientific Associate Sr Bldg. 223, A-113 Phone: 630-252-3996 This e-mail address is being protected from spambots. You need JavaScript enabled to view it. Biography Qing'an Li was an Assistant Research Scientist at Institute of Physics, Chinese Academy of Sciences after receiving his doctorate in July 1993 working on superconducting electronics. He was a postdoctoral fellow at University of Tokyo, Japan working on superconducting electronics in 1996. In 1997, he became a Visiting Scientist (postdoc) at the Materials Science Division of the Argonne National Laboratory, and started to study the transport properties of colossal magnetoresistance (CMR) materials in the Emerging Materials group. At the Institute of Physics, Chinese Academy of Sciences, Li was an Associated Research Scientist in 2000, a Research scientist, and Professor in 2001, working on magnetic and transport properties of transition metal oxides. In 2006, he visited the Materials Science Division of the Argonne National Laboratory as a Visiting Scientist, working on the transport properties of intermetallic compounds of rare-earth and transition metals, transition metal oxides, etc. and became a Scientific Associate Sr. in Emerging Materials group in 2009.

437

Degradation Reactions in SONY-Type Li-Ion Batteries  

DOE Green Energy (OSTI)

Thermal instabilities were identified in SONY-type lithium-ion cells and correlated with interactions of cell constituents and reaction products. Three temperature regions of interaction were identified and associated with the state of charge (degree of Li intercalation) of the cell. Anodes were shown to undergo exothermic reactions as low as 100°C involving the solid electrolyte interface (SEI) layer and the LiPF6 salt in the electrolyte (EC: PC: DEC/LiPF6). These reactions could account for the thermal runaway observed in these cells beginning at 100°C. Exothermic reactions were also observed in the 200°C-300°C region between the intercalated lithium anodes, the LiPF6 salt and the PVDF. These reactions were followed by a high- temperature reaction region, 300°C-400°C, also involving the PVDF binder and the intercalated lithium anodes. The solvent was not directly involved in these reactions but served as a moderator and transport medhun. Cathode exotherrnic reactions with the PVDF binder were observed above 200oC and increased with the state of charge (decreasing Li content). This offers an explanation for the observed lower thermal runaway temperatures for charged cells.

Nagasubramanian, G.; Roth, E. Peter

1999-05-04T23:59:59.000Z

438

Low Dose Radiation Research Program: Jian Jian Li  

NLE Websites -- All DOE Office Websites (Extended Search)

Jian Jian Li Jian Jian Li School of Health Sciences, Purdue University Newly Funded Projects Regulation of NF-kB and Mn SOD in Low Dose Radiation-Induced Adaptive Responses in Mouse and Human Skin Cells, abstract, description. Technical Abstracts 2006 Workshops: NF-kB Mediated Signaling Network in Low Dose X-Ray Induced Adaptive Protection on Mouse and Human Skin Epithelial Cells Ahmed, K.M., Fan, M., Spitz, and Li, J.J. 2005 Workshops: Adaptive Response of Mouse Skin Epithelial Cells to Low Dose Ionizing Radiation: Induction of NF-κB, MnSOD, 14-3-3ζ and Cyclin B1. Li, J.J., Ahmed, K.M., Fan, M., Dong, S., Spitz, D.R., and Yu, C.-R. 2003 Workshops: Gene Expression Profiles of Human Skin Keratinocytes Exposed to Acute and Chronic Ionizing Radiation Li, J.J., Ozeki, M., Wang, T., Tamae, D., Nelson, D., Wyrobek, A., and

439

Extraction of Mangrove Biophysical Parameters Using Airborne LiDAR  

E-Print Network (OSTI)

Abstract: Tree parameter determinations using airborne Light Detection and Ranging (LiDAR) have been conducted in many forest types, including coniferous, boreal, and deciduous. However, there are only a few scientific articles discussing the application of LiDAR to mangrove biophysical parameter extraction at an individual tree level. The main objective of this study was to investigate the potential of using LiDAR data to estimate the biophysical parameters of mangrove trees at an individual tree scale. The Variable Window Filtering (VWF) and Inverse Watershed Segmentation (IWS) methods were investigated by comparing their performance in individual tree detection and in deriving tree position, crown diameter, and tree height using the LiDAR-derived Canopy Height Model (CHM). The results demonstrated that each method performed well in mangrove forests with a low percentage of crown overlap conditions. The VWF method yielded a slightly higher accuracy for mangrove parameter extractions from LiDAR data compared with the IWS method. This is because the VWF method uses an adaptive circular filtering window size based on an allometric relationship. As a result of the VWF method, the position

Wasinee Wannasiri; Masahiko Nagai; Kiyoshi Honda; Phisan Santitamnont; Poonsak Miphokasap

2013-01-01T23:59:59.000Z

440

Characteristics of ashes from different locations at the MSW incinerator equipped with various air pollution control devices  

Science Conference Proceedings (OSTI)

The characteristics of ashes from different locations at a municipal solid waste incinerator (MSWI) equipped with a water spray tower (WST) as a cooling system, and a spray dryer adsorber (SDA), a bag filter (BF) and a selective catalytic reactor (SCR) as air pollution control devices (APCD) was investigated to provide the basic data for further treatment of ashes. A commercial MSWI with a capacity of 100 tons per day was selected. Ash was sampled from different locations during the normal operation of the MSWI and was analyzed to obtain chemical composition, basicity, metal contents and leaching behavior of heavy metals. Basicity and pH of ash showed a broad range between 0.08-9.07 and 3.5-12.3, respectively. Some major inorganics in ash were identified and could affect the basicity. This could be one of the factors to determine further treatment means. Partitioning of hazardous heavy metals such as Pb, Cu, Cr, Hg and Cd was investigated. Large portions of Hg and Cd were emitted from the furnace while over 90% of Pb, Cu and Cr remained in bottom ash. However 54% of Hg was captured by WST and 41% by SDA/BF and 3.6% was emitted through the stack, while 81.5% of Cd was captured by SDA/BF. From the analysis data of various metal contents in ash and leach analysis, such capturing of metal was confirmed and some heavy metals found to be easily released from ash. Based on the overall characteristics of ash in different locations at the MSWI during the investigation, some considerations and suggestions for determining the appropriate treatment methods of ash were made as conclusions.

Song, Geum-Ju; Kim, Ki-Heon; Seo, Yong-Chil; Kim, Sam-Cwan

2004-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash li lime" from the National Library of EnergyBeta (NLEBeta).
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441

Investigation on the utilization of coal fly ash as amendment to compost for vegetation in acid soil. Technical terminal report  

Science Conference Proceedings (OSTI)

Application of fly ash-amended composts as manure enhances the crop yield of certain plants like corn, sorghum, collard and mustard greens. Organic compost made out of grass and leaves (home-made) is better than the commercial composts for amendment with fly ash. A 20--40% fly ash in the amended compost and a soil to ash-amended compost ratio of 3:1 are recommended for making bed for plantation. Organic compost mixed with fly ash, due to reduced porosity, will help the bed to retain water and conserve water supply to plants. Organic compost will release to the manure additional quantities of N, P, and S that are not substantially available in fly ash. It appears that chemical reaction and/or mineralization occurs during composting of fly ash with organic manure to release more N, P, K and S to the system. Potassium is more elevated in all plants grown in potted soil treated with fly ash-amended compost than in those grown in soil or soil treated with organic manure. Contrary to expectation Ca in fly ash is not effectively used by plants as the latter treated with ash- amended compost is not rich in Ca. This suggests that Ca may be tied up as insoluble CaSO{sub 4} in the manure so that it may not be bioavailable to the plant. Uptake of boron by bean, bell pepper and egg plant is considerably higher than that absorbed by corn, sorghum and greens resulting in poor yield for the former.

Menon, M.P.

1991-08-01T23:59:59.000Z

442

Investigation on the utilization of coal fly ash as amendment to compost for vegetation in acid soil  

Science Conference Proceedings (OSTI)

Application of fly ash-amended composts as manure enhances the crop yield of certain plants like corn, sorghum, collard and mustard greens. Organic compost made out of grass and leaves (home-made) is better than the commercial composts for amendment with fly ash. A 20--40% fly ash in the amended compost and a soil to ash-amended compost ratio of 3:1 are recommended for making bed for plantation. Organic compost mixed with fly ash, due to reduced porosity, will help the bed to retain water and conserve water supply to plants. Organic compost will release to the manure additional quantities of N, P, and S that are not substantially available in fly ash. It appears that chemical reaction and/or mineralization occurs during composting of fly ash with organic manure to release more N, P, K and S to the system. Potassium is more elevated in all plants grown in potted soil treated with fly ash-amended compost than in those grown in soil or soil treated with organic manure. Contrary to expectation Ca in fly ash is not effectively used by plants as the latter treated with ash- amended compost is not rich in Ca. This suggests that Ca may be tied up as insoluble CaSO{sub 4} in the manure so that it may not be bioavailable to the plant. Uptake of boron by bean, bell pepper and egg plant is considerably higher than that absorbed by corn, sorghum and greens resulting in poor yield for the former.

Menon, M.P.

1991-08-01T23:59:59.000Z

443

Li6La3SnMO12 (M = Sb, Nb, Ta), a Family of Lithium Garnets with High Li-Ion Conductivity  

Science Conference Proceedings (OSTI)

In order to investigate the influence of covalent bonding within the garnet framework on the conductivity of Li+ in the interstitial space, the Li+ conductivities in the family of Sn-based compounds Li6La3 SnMO12 (M = Sb, Nb, Ta) have been obtained and are compared with those of Li6La3ZrMO12. Refinement of the neutron diffraction pattern of Li6La3 SnNbO12shows that the interstitial tetrahedral sites (24d ) are about half-occupied and most of the Li in the interstitial bridging octahedral sites are displaced from the center position (48g ). The Sb-based compound has the largest lattice parameter while the Ta-based compound has the highest Li+-ion conductivity of 0.42 10 4 Scm 1.

Bridges, Craig A [ORNL; Goodenough, J. B. [University of Texas, Austin; Gupta, Dr Asha [University of Texas, Austin; Nakanishi, Masahiro [ORNL; Paranthaman, Mariappan Parans [ORNL; Sokolov, Alexei P [ORNL; Bi, Zhonghe [ORNL; Li, Yutao [University of Texas, Austin; Han, Jiantao [University of Texas, Austin; Dong, Youzhong [South China University of Technology, Guangzhou, PR China; Wang, Long [University of Texas, Austin; Xu, Maowen [University of Texas, Austin

2012-01-01T23:59:59.000Z

444

Review on Current State of Li-ion Batteries  

DOE Green Energy (OSTI)

This is an up-to-date review of the issues and challenges facing Li-ion battery research with special focus on how nanostructures/ nanotechnology are being applied to this field. Novel materials reported as prospective candidates for anode, cathode and electrolyte will be summarized. The expected role of nanostructures in improving the performance of Li-ion batteries and the actual pros and cons of using such structures in this device will be addressed. Electrochemical experiments used to study Li-ion batteries will also be discussed. This includes the introduction to the standard experimental set-up and how experimental data (from charge-discharge experiments, cyclic voltammetry, impedance spectroscopy, etc) are interpreted.

Mukaibo, Hitomi (University of Florida, Martin Research Group)

2010-06-04T23:59:59.000Z

445

TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE  

E-Print Network (OSTI)

TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE WAVELENGTH Grand Forks, ND 58202-9018 Keywords: scanning electron microscopy, trace metals, coal analysis ABSTRACT Scanningelectron microscopy with wavelength-dispersive spectrometry has been used to measure trace metals in coal

Laughlin, Robert B.

446

Low-Cost Ash-Derived Construction Materials: State-of-the-Art Assessment  

Science Conference Proceedings (OSTI)

Existing technologies have been successfully applied in the manufacturing of construction materials that incorporate coal combustion byproducts. This report describes an extensive literature review on coal ash use in low-cost building materials, including information on technical and economic feasibility.

1992-04-01T23:59:59.000Z

447

New Air-Entraining Admixtures for Concrete Using High-Carbon Fly Ash  

Science Conference Proceedings (OSTI)

A promising new air-entraining admixture has been developed by the leading North American admixture producer. Independent, EPRI-sponsored testing indicated the admixture was suitable for use with concretes that contain fly ashes with levels of unburned carbon higher than the typical 3-4 percent allowed in the concrete industry.

2002-03-20T23:59:59.000Z

448

Investigation on the Parameters Affecting the De-Icing Salt Scaling Resistance of Fly Ash Concrete  

Science Conference Proceedings (OSTI)

In scaling of concrete by de-icing salts, the mortar near the surface flakes or peels away. This report presents the results of an R&D laboratory study to examine the scaling of high ash content concrete from the use of salts used routinely in cold climates to melt ice and snow on roads and sidewalks.

1998-06-29T23:59:59.000Z

449

BENEFICIAL USE OF ASH AND CHAR FROM BIOMASS GASIFICATION Naomi Klinghoffer  

E-Print Network (OSTI)

1 BENEFICIAL USE OF ASH AND CHAR FROM BIOMASS GASIFICATION Naomi Klinghoffer Columbia University in the future. A common way to recover energy from biomass is through gasification where synthesis gas gasification conditions. Specifically, it is desired to produce a porous char which could be used as a catalyst

Columbia University

450

Fly ash-amended compost as a manure for agricultural crops  

Science Conference Proceedings (OSTI)

Homemade organic compost prepared from lawn grass clippings was amended with fine fly ash collected from a coal-fired power plant (SRS 484.D. Savannah River Site, Aiken, SC) to investigate its usefulness as a manure in enhancing nutrient uptake and increasing dry matter yield in selected agricultural crops. Three treatments were compared: five crops (mustard, collard, string beans, bell pepper, and eggplant) were each grown on three kinds of soil: soil alone, soil amended with composted grass clippings, and soil amended with the mixed compost of grass clippings and 20% fly ash. The fly ash-amended compost was found to be effective in enhancing the dry matter yield of collard greens and mustard greens by 378% and 348%, respectively, but string beans, bell pepper, and eggplant did not show any significant increase in dry matter yield. Analysis of the above-ground biomass of these last three plants showed they assimilated high levels of boron, which is phytotoxic; and this may be the reason for their poor growth. Soils treated with fly ash-amended compost often gave higher concentrations than the control for K, Ca, Mg, S, Zn, and B in the Brassica crops. 18 refs., 2 figs., 5 tabs.

Menon, M.P.; Sajwan, K.S.; Ghuman, G.S.; James, J.; Chandra, K. (Savannah State College, GA (United States))

1993-11-01T23:59:59.000Z

451

Effect of coal fly ash-amended organic compost as a manure for agricultural crops  

Science Conference Proceedings (OSTI)

Coal-fired electric power plants generate large quantities of fly ash as a byproduct. In continuation of previous studies on the utilization of fly ash as an amendment to organic compost for use as a manure for agricultural crops, the authors have now determined the effects of this manure on the yield and uptake of selected elements by several plants including collard green, corn, mustard green, bell pepper, egg plant, and climbing beans. An amended compost containing 30-40% fly ash with a compost:soil ratio of 1:3 was found to be most effective to enhance the yield and nutrient uptake of most of the plants. At 20% fly ash level, no increase in yield of any of the above crops was observed. The uptake of K, Mg, Mn, and P was increased in most plants. Boron which is known to be detrimental to the growth of plants above certain level was also found to be increased in plants nourished with the manure.

Ghuman, G.S.; Menon, M.P.; James, J.; Chandra, K.; Sajwan, K. (Savannah State College, GA (United States))

1991-04-01T23:59:59.000Z

452

Mercury Control Research: Effects of Fly Ash and Flue Gas Parameters on Mercury Speciation  

E-Print Network (OSTI)

and fly ash parameters on the oxidation of HgOin simulated flue gases containing hydrogen chloride (Hel-combustion region are unknown, and the major reaction pathways for Hg oxidation in combustion flue gases remain in the oxidation ofHgo in flue gases containingHC!. Thus, an important parameter that influences the oxidation of

Columbia University

453

The Road to Reuse: York County's Ash Management Program David E. Vollero  

E-Print Network (OSTI)

Recovery Center (York County RRC) commenced operations in 1989 and has since processed all County RRC is complemented by other components of York County's integrated solid waste management system-combustible wastes and York County RRC ash residue, and public education programs emphasizing waste minimization

Columbia University

454

9th Annual North American Waste to Energy Conference Ash Recycling: Partnering for Progress  

E-Print Network (OSTI)

Townships as the host municipalities, PennDOT as a potential major end-user, MYRES as the RRC opaator the RRC's ash. After exhaustive research, YCSWA selected AAR's technology and commWlicated those benefits Center (RRC) in Manchester Township, Pennsylvania; and owns and operates the Yard Waste Compot Site

Columbia University

455

Interpretation of Accurate UV Polarization Lidar Measurements: Application to Volcanic Ash Number Concentration Retrieval  

Science Conference Proceedings (OSTI)

In this paper, accurate UV polarization measurements are performed on a volcanic ash cloud after long-range transport at Lyon, France (45.76°N, 4.83°E). The volcanic particles are released from the mid-April 2010 eruption of the Eyjafjallajökull ...

A. Miffre; G. David; B. Thomas; M. Abou Chacra; P. Rairoux

2012-04-01T23:59:59.000Z

456

Long-Term Leaching Tests With High Ash Fusion Maryland Coal Slag  

Science Conference Proceedings (OSTI)

Extraction-procedure toxicity tests showed that the solid residue materials resulting from the Texaco coal gasification process using fluxed high ash fusion Maryland coal were nonhazardous. Contaminant concentration in the leachate was below or only slightly above the primary maximum contaminant limits (PMCL) established for public drinking water supplies.

1991-04-04T23:59:59.000Z

457

How carbon-based sorbents will impact fly ash utilization and disposal  

Science Conference Proceedings (OSTI)

The injection of activated carbon flue gas to control mercury emissions will result in a fly ash and activated carbon mixture. The potential impact of this on coal combustion product disposal and utilization is discussed. The full paper (and references) are available at www.acaa-usa.org. 1 tab., 2 photos.

Pflughoeft-Hassett, D.F.; Hassett, D.J.; Buckley, T.D.; Heebink, L.V.; Pavlish, J.H. [Energy and Environmental Research Center (United States)

2008-07-01T23:59:59.000Z

458

Surface tension measurements of coal ash slags under reducing conditions at atmospheric pressure  

Science Conference Proceedings (OSTI)

The global demand for reduced CO{sub 2} emission from power plants can be answered by coal gasification techniques. To develop integrated gasification combined cycles that incorporate hot syngas cleaning facilities, detailed knowledge of the thermophysical properties of coal ashes is imperative. Currently, the surface tension of liquid coal ash slags in a reducing environment was studied by means of the sessile drop method. Three different algorithms were employed to analyze the acquired drop images. The slags under consideration were obtained from black and brown coals as well as from an experimental gasification reactor. Typically, a sharp surface tension decrease with temperature was found in the melting interval of the ashes. This was followed by a temperature range of smooth drop contours during which a slight rise of the surface tension could mostly be observed. Bubbles at the circumference of the drops started to appear when approaching the measurement temperature limit of 1550{sup o}C. With regard to the temperature regime of uncorrugated drop profiles, coal ash slags exhibited surface tension values between 400 and 700 mN/m. 32 refs., 9 figs., 1 tab.

Tobias Melchior; Gunther Putz; Michael Mueller [Forschungszentrum Juelich GmbH, Juelich (Germany). Institute of Energy Research

2009-09-15T23:59:59.000Z

459

Comments on ``Failures in detecting volcanic ash from a satellite-based technique''  

E-Print Network (OSTI)

of active vol- canism (pp. 45­64). Washington, DC: American Geophysical Union. Davies, M. A., & Rose, W. I inter- national symposium on volcanic ash and aviation safety, Seattle, WA. Washington, DC: US GPO. US, causing severe restrictions to air traffic for many hours. This cloud was tracked without any split-window

Bluth, Gregg

460

Factors Influencing Volcanic Ash Dispersal from the 1995 and 1996 Eruptions of Mount Ruapehu, New Zealand  

Science Conference Proceedings (OSTI)

The prediction of the dispersal of volcanic ash from events such as the Ruapehu eruptions of 1995 and 1996 is important, not only for civil-defense authorities who need to warn people in downwind areas, but for airline companies that have to ...