Sample records for ash li lime

  1. Evaluation of lime-fly ash stabilized bases and subgrades using static and dynamic deflection systems 

    E-Print Network [OSTI]

    Raba, Gary W.

    1982-01-01T23:59:59.000Z

    structural evaluations of the subgrade and its overlying pavement layers for test sites in Texas. Six evaluations of the lime-fly ash stabilization technique, based on dual parametric results, are given in this thesis. ACKNOWLEDGMENTS The author wishes... FOR TEST SITE 5 H. DFFLECTION MEASUREMENTS FOR TEST SITE 8 VITA PAGE 141 141 154 160 160 172 181 181 195 202 213 213 213 215 220 227 231 238 245 252 259 268 275 LIST OF TABLES TABLE PAGE 10. 12. 13. 14. Lime-Fly Ash...

  2. Regeneration of lime from sulfates for fluidized-bed combustion

    DOE Patents [OSTI]

    Yang, Ralph T. (Middle Island, NY); Steinberg, Meyer (Huntington Station, NY)

    1980-01-01T23:59:59.000Z

    In a fluidized-bed combustor the evolving sulfur oxides are reacted with CaO to form calcium sulfate which is then decomposed in the presence of carbonaceous material, such as the fly ash recovered from the combustion, at temperatures of about 900.degree. to 1000.degree. C., to regenerate lime. The regenerated lime is then recycled to the fluidized bed combustor to further react with the evolving sulfur oxides. The lime regenerated in this manner is quite effective in removing the sulfur oxides.

  3. LI

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling CorpNewCF INDUSTRIES,L? .-I I2 m.m\ LI g. / This

  4. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    SciTech Connect (OSTI)

    Cetin, Bora [Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742 (United States); Aydilek, Ahmet H., E-mail: aydilek@umd.edu [Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742 (United States); Li, Lin [Department of Civil and Environmental Engineering, Jackson State University, Jackson, MS 17068 (United States)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer This study is the evaluation of leaching potential of fly ash-lime mixed soils. Black-Right-Pointing-Pointer This objective is met with experimental and numerical analysis. Black-Right-Pointing-Pointer Zn leaching decreases with increase in fly ash content while Ba, B, Cu increases. Black-Right-Pointing-Pointer Decrease in lime content promoted leaching of Ba, B and Cu while Zn increases. Black-Right-Pointing-Pointer Numerical analysis predicted lower field metal concentrations. - Abstract: A study was conducted to evaluate the leaching potential of unpaved road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater impacts of barium, boron, copper, and zinc leaching. This objective was met by a combination of batch water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted on soil alone, fly ash alone, and URM-fly ash-lime kiln dust mixtures. The results indicated that an increase in fly ash and lime content has significant effects on leaching behavior of heavy metals from URM-fly ash mixture. An increase in fly ash content and a decrease in lime content promoted leaching of Ba, B and Cu whereas Zn leaching was primarily affected by the fly ash content. Numerically predicted field metal concentrations were significantly lower than the peak metal concentrations obtained in laboratory column leach tests, and field concentrations decreased with time and distance due to dispersion in soil vadose zone.

  5. Process for the recovery of alumina from fly ash

    DOE Patents [OSTI]

    Murtha, M.J.

    1983-08-09T23:59:59.000Z

    An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

  6. The Needs of Texas Soils for Lime.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1919-01-01T23:59:59.000Z

    Department of Agriculture. STS PAGE ............................................. What lime does 5 ............................................. Acidity of soils 7 ............................................. Sources of lime 8... of Texas soils for lime, as far as our present information permits. WHST LIME DOES Lime performs sereral functions in the soil, some of which are favor- able to increased crops and the maintenance of fertility, some favorable to certain crops...

  7. Sulfate Induced Heave: Addressing Ettringite Behavior in Lime Treated Soils and in Cementitious Materials

    E-Print Network [OSTI]

    Kochyil Sasidharan Nair, Syam Kumar

    2012-02-14T23:59:59.000Z

    , due to the formation of expansive minerals like ettringite and thaumasite, has been recognized as a problem in Portland cement concrete, stabilized soils, weathered cements, alkaline fly ashes, FGD wastes, chromite ore processing residues and cement... moles of Ca2+, 2 moles of Al3+, 3 moles of SO42-, and 32 moles of water are required. Calcium ions are provided by lime, Portland cement, or fly ash; alumina is supplied by dissolution of oxyhydroxides and phyllosilicates; and sulfates are supplied...

  8. Climate VISION: Private Sector Initiatives: Lime

    Office of Scientific and Technical Information (OSTI)

    Lime Association (NLA), representing approximately 95% of U.S. commercial lime production, is very pleased to submit this letter in response to President Bush's challenge to...

  9. Ash pelletization

    SciTech Connect (OSTI)

    Woodall, M.

    1994-12-31T23:59:59.000Z

    Ash pelletization is outlined under the following topics: projects with CSX involvement; US Generating (Cedar Bay), Jacksonville, FL; Hydra-Co (Salt City Project), Solvay, NY; Virginia Power, Yorktown Plant; US Generating; Indiantown, FL; Future Projects; Development of ash disposal site;s Reuse of ash product; and Utility Survey.

  10. Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

    DOE Patents [OSTI]

    Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

    1997-01-01T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

  11. Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1997-10-28T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

  12. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    E-Print Network [OSTI]

    Aydilek, Ahmet

    December 2011 Available online xxxx Keywords: Coal combustion by products Fly ash Heavy metals Leaching road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater is produced in the United States as a by-product of burning coal in electric power plants (ACAA, 2009

  13. Effects of Lime and Carbonate of Lime on Acid Phosphate. 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1917-01-01T23:59:59.000Z

    question whether part of the readion does not take place in the filter paper, when the fertilizer is being washed with water to re- move the water-soluble phosphoric acid. To test this, we mixed carbonate of lime with acid phosphate and determined... EXPERIMENTS. We made some pot experiments to test the effect of lime on acid phosphate, but we are not altogether ea'tisfied with the mgy some of these crops grew. Details: Soils 3653, 4643, 4580, 4596, 4581, 4589, 4591. Additions : Ac 1 gram acid...

  14. Enhancement of phosphogypsum with high lime fly ash

    E-Print Network [OSTI]

    Gregory, Chuck Alan

    1983-01-01T23:59:59.000Z

    , the effects of source size and background soil radiation were included. The quantity of radon released fzom the pile depended on the following (26): 1. The specific activity of Ra-226 in the phosphogypsum 2. The eminating power of the radon (the amount... of radon released per unit generated). 3. The atmospheric pressure 4 ~ The di f fus ion coef f ic ient, which includes the effects of 23 moisture, for the radon in the phosphogypsum. For example, high moisture content or water standing on the pile...

  15. Enhancement of phosphogypsum with high lime fly ash 

    E-Print Network [OSTI]

    Gregory, Chuck Alan

    1983-01-01T23:59:59.000Z

    Investigation. Detailed Investigation. 51 58 IV CONCLUSIONS V RECOMMENDATIONS 114 REFERENCES 115 APPENDIX A APPENDIX B APPENDIX C Historical Summary of the Wet Process Phosphoric Acid Industry. . . . . . . . . . . . . . . Hemihydrate and Hemihydrate-Dihydrate... generally exist in three different forms. 1. dihydrous (CaSO& 2H20) 2 . hemihydrous (CaSOd 1/2 H20) 3. anhydrous (CaSO ) It is these crystals, called phosphogypsum, that are filtered from the acid solution and piped to stockpiles in slurry form...

  16. The Needs of Texas Soils for Lime

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1919-01-01T23:59:59.000Z

    drill or a lime spreader. Lime spreaders are sold by manufacturers of agricul- tural implements. Stone lime niay be placed in piles on the ground, covered with earth. allotred to .slake, and then spread, but this is not a very good method. The best..., clays and clay loams of East 1 Texas ancl the gulf coast section which experiments have shown to be acid. The chemist of tPfe Texas Experiment Station will test samples for aciclity free of charge. .As a rule, 1000 pounds per acre of lime-, stone...

  17. Climate VISION: Private Sector Initiatives: Lime: Resources and...

    Office of Scientific and Technical Information (OSTI)

    Industry Associations National Lime Association The National Lime Association is the trade association for U.S. and Canadian manufacturers of high calcium quicklime, dolomitic...

  18. Sulfate induced heave in lime stabilized soil

    E-Print Network [OSTI]

    Bredenkamp, Sanet

    1994-01-01T23:59:59.000Z

    The addition of hydrated lime to clay soils is one of the most common methods of soil stabilization. However, when sulfates are present in the soil, the calcium in the lime reacts with the sulfates to form ettringite, an expandable mineral...

  19. Hydration and strength development of binder based on high-calcium oil shale fly ash

    SciTech Connect (OSTI)

    Freidin, C. [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)] [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)

    1998-06-01T23:59:59.000Z

    The properties of high-calcium oil shale fly ash and low-calcium coal fly ash, which are produced in Israeli power stations, were investigated. High-calcium oil shale fly ash was found to contain a great amount of CaO{sub free} and SO{sub 3} in the form of lime and anhydrite. Mixtures of high-calcium oil shale fly ash and low-calcium coal fly ash, termed fly ash binder, were shown to cure and have improved strength. The influence of the composition and curing conditions on the compressive strength of fly ash binders was examined. The microstructure and the composition of fly ash binder after curing and long-term exposure in moist air, water and open air conditions were studied. It was determined that ettringite is the main variable in the strength and durability of cured systems. The positive effect of calcium silicate hydrates, CSH, which are formed by interaction of high-calcium oil shale fly ash and low-calcium coal fly ash components, on the carbonation and dehydration resistance of fly ash binder in open air is pronounced. It was concluded that high-calcium oil shale fly ash with high CaO{sub free} and SO{sub 3} content can be used as a binder for building products.

  20. Climate VISION: Private Sector Initiatives: Lime: Results

    Office of Scientific and Technical Information (OSTI)

    Association (NLA) is pleased to report that between 2002 and 2008, the energy-related CO2 intensity of lime produced by NLA member companies has been reduced by an aggregate 5%....

  1. Cement technology for borehole plugging: interim report on the effects of fly ash and salt on the physical properties of cementitious solids

    SciTech Connect (OSTI)

    Moore, J.G.; Morgan, M.T.; McDaniel, E.W.; Greene, H.B.; West, W.A.

    1980-03-01T23:59:59.000Z

    Results of initial studies of a systematic investigation to determine the effects of fly ash and salt on the physical properties of pozzolanic concretes and saltcretes are reported. Addition of fly ash to mortars decreased the set time and bleed characteristics and increased the compressive strength and permeability, but it had very little effect on the density or the thermal conductivity of the solid. The magnitude of these effects was only slightly related to the lime content of the fly ash. In the case of saltcretes, low-lime fly ash slightly decreased the set time and the bleed characteristics of the wet mix. However, a high-lime fly ash doubled the set time and decreased the bleed characteristics to essentially zero. The compressive strength of saltcretes was increased by the addition of fly ash and was independent of the lime content. Such additions had little effect on the thermal conductivity or density. The thermal conductivities of cement pastes containing fly ash showed a near-linear relationship with the density of the resulting solids. In the case of mortars, the thermal conductivity decreased with increasing temperature and showed some hysteresis in the initial heating cycle. After the first cycle, the thermal conductivity decreased from about 1.32 W/m.K at 350/sup 0/K to 1.27 W/m.K at 475/sup 0/K.

  2. Climate VISION: Private Sector Initiatives: Lime: GHG Inventory...

    Office of Scientific and Technical Information (OSTI)

    GHG Inventory Protocols Read the CO2 Emissions Calculation Protocol for the Lime industry (PDF 229 KB) Download Acrobat Reader...

  3. acid lime plants: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acid lime plants First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effects of Lime and Carbonate of Lime...

  4. Activation of fly ash

    DOE Patents [OSTI]

    Corbin, D.R.; Velenyi, L.J.; Pepera, M.A.; Dolhyj, S.R.

    1986-08-19T23:59:59.000Z

    Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

  5. Activation of fly ash

    DOE Patents [OSTI]

    Corbin, David R. (New Castle, DE); Velenyi, Louis J. (Lyndhurst, OH); Pepera, Marc A. (Northfield, OH); Dolhyj, Serge R. (Parma, OH)

    1986-01-01T23:59:59.000Z

    Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

  6. Sulfate induced heave in lime stabilized soil 

    E-Print Network [OSTI]

    Bredenkamp, Sanet

    1994-01-01T23:59:59.000Z

    . The electrical conductivity is then related to sulfate content in soils. Expansion tests were performed to determine the amount of expansion that occurs when lime is added to soils with different sulfate contents. A model that relates the amount of expansion...

  7. Effects of lime rate, lime ECCE, and B rate on rose clover and coastal bermudagrass dry matter yields 

    E-Print Network [OSTI]

    Villavicencio Batres, Rodolfo

    1990-01-01T23:59:59.000Z

    that soil pH was only affected by lime rate at the soil surface after 5 months, indicates that CaCO3 andior the dissolution products of CaCO3 did not readily leach through the soil profile when the lime was surface applied. Lime ECCE Effects Soil pH (0...EFFECTS OF LIME RATE, LIME ECCE, AND B RATE ON ROSE CLOVER AND COASTAL BERMUDAGRASS DRY MATTER YIELDS A Thesis by RODOLFO VILLAVICENCIO BATRES Submitted to the Office of Graduate Studies of Texas A8 M University in partial fulfiliment...

  8. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14T23:59:59.000Z

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  9. EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01T23:59:59.000Z

    Tests were performed in simulated flue gas streams using two fly ash samples from the electrostatic precipitators of two full-scale utility boilers. One fly ash was derived from a Powder River Basin (PRB) coal, while the other was derived from Blacksville coal (Pittsburgh No. 8 seam). The tests were performed at temperatures of 120 and 180 C under different gas compositions using whole fly ash samples as well as magnetic and nonmagnetic concentrates from sized fly ash. Only the Blacksville ash contained magnetic phases. The whole and fractionated fly ash samples were analyzed for morphology, chemical composition, mineralogical composition, total organic carbon, porosity, and surface area. Mineralogically, the Blacksville ash was composed predominantly of magnetite, hematite, quartz, and mullite, while the PRB ash contained mostly quartz with lesser amounts of lime, periclase, and calcium aluminum oxide. The iron oxides in the Blacksville ash were concentrated almost entirely in the largest size fraction. As anticipated, there was not a clean separation of magnetic (Fe-rich) and nonmagnetic (aluminosilicate-rich) phases for the Blacksville ash. The Blacksville ash had a significantly higher surface area and a much higher unburned carbon content than the PRB ash. Elemental mercury (Hg) streams were injected into the simulated flue gas and passed over filters (housed in a convection oven) loaded with fly ash. Concentrations of total, oxidized, and elemental Hg downstream from the ash samples were determined by the Ontario Hydro Method. The gas stream composition and whether or not ash was present in the gas stream were the two most important variables. Based on the statistical analyses, the presence of HCl, NO, NO{sub 2}, and SO{sub 2} and all two-way gas interactions were significant. In addition, it appears that even four-factor interactions between those gases are significant. The HCl, NO{sub 2}, and SO{sub 2} were critical gases resulting in Hg oxidation, while the presence of NO appeared to suppress oxidation. The Blacksville fly ash tended to show slightly more catalytic activity than the PRB fly ash, but this could be largely due to the higher surface area of the Blacksville ash. Temperature was not a statistically important factor. The magnetic (Fe-rich) phases did not appear to be more catalytically active than the nonmagnetic phases, and unburned carbon did not appear to play a critical role in oxidation chemistry.

  10. LimeAmps | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |Jilin ZhongdiantouLichuan City Yujiang RiverLijiangLimeAmps Jump to:

  11. Lime slurry use at the Industrial Wastewater Pretreatment Facility

    SciTech Connect (OSTI)

    Rice, L.E. [Allied-Signal Aerospace Co., Kansas City, MO (United States). Kansas City Div.; Hughes, R.W. [Professional Services Group, Inc., Kansas City, MO (United States); Baggett, G. [Genex/Praxair, Inc., Kansas City, MO (United States)

    1996-04-01T23:59:59.000Z

    The use of lime slurry at the IWPF demonstrated many benefits. Hazardous chemical use was reduced, solids handling was improved, water quality was enhanced and there has been a cost savings. The lime slurry also enabled the plant to begin treating the soluble oil waste, which we were not able to do in the past.

  12. Wood Residues as Fuel Source for Lime Kilns 

    E-Print Network [OSTI]

    Azarniouch, M. K.; Philp, R. J.

    1984-01-01T23:59:59.000Z

    product discharge end of the lime kiln. Thus far we have carried out two series of tests using two different pilot-scale kilns and dry limestone in the first test series and mill produced lime mud in the second test series. Mill scale trials have just been...

  13. Lime kiln source characterization: Lime manufacturing industry Fourier transform infrared spectroscopy. Final report

    SciTech Connect (OSTI)

    Toney, M.L.

    1999-07-01T23:59:59.000Z

    The purpose of this testing program is to obtain uncontrolled and controlled hydrogen chloride (HCl) and speciated hydrocarbon Hazardous Air Pollutants (HAPs) emissions data from lime production plants to support a national emission standard for hazardous air pollutants (NESHAP). This report presents data from the Fourier Transform Infrared Spectroscopy (FTIR) measurements. FTIR source testing was conducted for the following purposes: Quantify HCl emission levels; and Gather screening (i.e., qualitative) data on other HAP emissions.

  14. The effect of additives on lime dissolution rates. Final report

    SciTech Connect (OSTI)

    Khang, S.J.

    1996-07-31T23:59:59.000Z

    Based on the previous years` studies concerning the efficiency of SO{sub 2} removal by spray dryers with high sulfur coal flue gas, the work for year five included investigations of lime dissolution rates at different slaking conditions and with the effect of additives. The prominent additives that have significant effects on lime dissolution rates were tested with the mini pilot spray drying absorber to see their effects on spray drying desulfurization applications. The mechanisms of these additive effects along with the properties of hygroscopic additives have been discussed and incorporated into the spray drying desulfurization model ``SPRAYMOD-M.`` Slaking conditions are very important factors in producing high quality lime slurry in spray drying desulfurization processes. At optimal slaking conditions, the slaked lime particles are very fine (3-5{mu}m) and the slaked lime has high BET surface areas which are beneficial to the desulfurization. The slaked lime dissolution rate experiments in our study are designed to determine how much lime can dissolve in a unit time if the initial lime surface area is kept constant. The purpose of the dissolution rate study for different additives is to find those effective additives that can enhance lime dissolution rates and to investigate the mechanisms of the dissolution rate enhancement properties for these additives. The applications of these additives on spray drying desulfurization are to further verify the theory that dissolution rate is a rate limiting step in the whole spray drying desulfurization process as well as to test the feasibility of these additives on enhancing SO{sub 2} removal in spray dryers.

  15. Influence of the composition of cement kiln dust on its interaction with fly ash and slag

    SciTech Connect (OSTI)

    Chaunsali, Piyush, E-mail: chaunsa2@illinois.edu [Department of Civil and Environmental Engineering, University of Illinois, Urbana-Champaign, IL 61801 (United States)] [Department of Civil and Environmental Engineering, University of Illinois, Urbana-Champaign, IL 61801 (United States); Peethamparan, Sulapha, E-mail: speetham@clarkson.edu [Department of Civil and Environmental Engineering, Clarkson University, Potsdam, NY 13699 (United States)] [Department of Civil and Environmental Engineering, Clarkson University, Potsdam, NY 13699 (United States)

    2013-12-15T23:59:59.000Z

    Cement kiln dust (CKD), a by-product of the cement industry, contains significant amounts of alkali, free lime, chloride and sulfate. Wide variation reported in the chemical composition of CKDs limits their potential application as a sustainable binder component in concrete. In the current study, the performance of two different CKDs as components in a novel binder is evaluated. Several binders are developed by blending CKDs with fly ash or slag. Binders with 70% CKD were prepared at a water-to-binder ratio of 0.4, and heat-cured at 75 °C to accelerate the strength development. The hydration progress was monitored using X-ray diffraction, and morphological examination was performed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Ettringite and calcium aluminosilicate hydrate (C-A-S-H) were identified as the main hydration products in the hardened binder system. Strength development of CKD-based binder was found to be significantly influenced by its free lime and sulfate contents. -- Highlights: •Interaction of cement kiln dust with fly ash and slag was explored. •CKD with higher free lime and sulfate content increased the strength of binder. •C-S-H like reaction gel with fibrillar morphology is observed in CKD-based binders.

  16. Evaluation of lime-fly ash stabilized bases and subgrades using static and dynamic deflection systems

    E-Print Network [OSTI]

    Raba, Gary W.

    1982-01-01T23:59:59.000Z

    , 000 E /E(=l I O. I E( = 2, 000, 000 5 6 7 8 8 IO II (2 (3 I4 H, inches Figure 9. Surface Curvature Index - Thickness re(ation for various pavement systems [after Maj(dzadeh (23)]. 0. 7 0, 6 0. 5 0. 4 0. 3 0. 2 X u" II4 'X & lo' 'X H...=9 E~= 20, 000 psi Hfa H=4 H=5 6 7 H = IO a H = II X H-l4 O. l X 0. 0 O. l I. O IO EI /E2 Ratio 100 500 Figure 10. Surface Curvature Index - Modu1ar Ratio Relationship for various pavement systems [after Majidzadeh (23)]. 36 200...

  17. RETENTION OF Cd, Cu, Pb AND Zn BY WOOD ASH, LIME AND FUME DUST

    E-Print Network [OSTI]

    Ma, Lena

    to immobilize metals from wastewater and soils (Viraraghavan and Rao, 1991). Various methods to remediate heavy metal contaminated soils and wastes exist, including thermal, biological, and physical/chemical treatments. However, most current treatment technologies are either too costly or only partially effective

  18. Ashing properties of coal blends

    SciTech Connect (OSTI)

    Biggs, D.L.

    1982-03-01T23:59:59.000Z

    The fusion properties of sulfur materials present in coals were investigated. The treatment of the samples of eleven different coals is described. Thermal treatment of low temperature ashing (LTA) concentrates of eight of the coals was performed, and raw and wash ashing curves were examined to determine what quantitative correlations, if any, exist between ashing parameters and rank of coal. The actual form of the function which describes the ashing curve is derived.

  19. Precipitation kinetics in ultra-high lime softening 

    E-Print Network [OSTI]

    Peacock, Edward Dale

    1986-01-01T23:59:59.000Z

    PRECIPITATION KINETICS IN ULTRA-HIGH LIME SOFTENING A Thesis EDWARD DALE PEACOCK Submitted to the Graduate College of Texas ABM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August l986 Major... Subject: Civil Engineering PRECIPITATION KINETICS IN ULTRA-HIGH LIME SOFTENING A Thesis by EDWARD DALE PEACOCK Approved as to style and content by: Bill Batchelor (Chair of Commi e) T D. eynol s (Member) Michael T. Lo necker (Member) Donald Mc...

  20. Coal ash utilization in India

    SciTech Connect (OSTI)

    Michalski, S.R.; Brendel, G.F.; Gray, R.E. [GAI Consultants, Inc., Pittsburgh, PA (United States)

    1998-12-31T23:59:59.000Z

    This paper describes methods of coal combustion product (CCP) management successfully employed in the US and considers their potential application in India. India produces about 66 million tons per year (mty) of coal ash from the combustion of 220 mty of domestically produced coal, the average ash content being about 30--40 percent as opposed to an average ash content of less than 10 percent in the US In other words, India produces coal ash at about triple the rate of the US. Currently, 95 percent of this ash is sluiced into slurry ponds, many located near urban centers and consuming vast areas of premium land. Indian coal-fired generating capacity is expected to triple in the next ten years, which will dramatically increase ash production. Advanced coal cleaning technology may help reduce this amount, but not significantly. Currently India utilizes two percent of the CCP`s produced with the remainder being disposed of primarily in large impoundments. The US utilizes about 25 percent of its coal ash with the remainder primarily being disposed of in nearly equal amounts between dry landfills and impoundments. There is an urgent need for India to improve its ash management practice and to develop efficient and environmentally sound disposal procedures as well as high volume ash uses in ash haulback to the coalfields. In addition, utilization should include: reclamation, structural fill, flowable backfill and road base.

  1. E-Print Network 3.0 - ash bottom ash Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: of bottom ash, 3 million tons of boiler slag, and 28 million tons of clean-coal ash materials) were produced... CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By...

  2. Modeling volcanic ash dispersal

    ScienceCinema (OSTI)

    None

    2011-10-06T23:59:59.000Z

    Explosive volcanic eruptions inject into the atmosphere large amounts of volcanic material (ash, blocks and lapilli). Blocks and larger lapilli follow ballistic and non-ballistic trajectories and fall rapidly close to the volcano. In contrast, very fine ashes can remain entrapped in the atmosphere for months to years, and may affect the global climate in the case of large eruptions. Particles having sizes between these two end-members remain airborne from hours to days and can cover wide areas downwind. Such volcanic fallout entails a serious threat to aircraft safety and can create many undesirable effects to the communities located around the volcano. The assessment of volcanic fallout hazard is an important scientific, economic, and political issue, especially in densely populated areas. From a scientific point of view, considerable progress has been made during the last two decades through the use of increasingly powerful computational models and capabilities. Nowadays, models are used to quantify hazard scenarios and/or to give short-term forecasts during emergency situations. This talk will be focused on the main aspects related to modeling volcanic ash dispersal and fallout with application to the well known problem created by the Eyjafjöll volcano in Iceland. Moreover, a short description of the main volcanic monitoring techniques is presented.

  3. Commercial Demonstration of the Manufactured Aggregate Processing Technology Utilizing Spray Dryer Ash

    SciTech Connect (OSTI)

    Roy Scandrol

    2004-11-01T23:59:59.000Z

    This quarterly report covers the period from July 1st, 2004 through September 30th, 2004. It covers: technical development, permitting status, engineering status, construction status, operations summary and marketing support activities for this period. Plant startup, including equipment and system debugging, is underway. Minor adjustments to the SDA feed system, pug mill, and extruder were completed. Testing of admixtures to prevent the wetted SDA from sticking is continuing. The power plant is implementing a lime optimization program to reduce the calcium hydroxide values in the ash.

  4. Reuse of Drill Cutting Ash as a Stabilizing Agent for Niger Delta Soils

    E-Print Network [OSTI]

    Alayaki, F. M.; Al-Tabbaa, A.; Ayotamuno, M. J.

    2015-01-01T23:59:59.000Z

    in Onne Oil and Gas Free Zone, Rivers State, Nigeria. B. Niger Delta Soils The peculiar geology of Niger Delta and the derived soils have striking peculiarity that is different from other common laterite soils. Previous studies revealed that the in... to that in use at the North Sea. The binders were Portland cement, hydrated lime, pulverized fuel ash, blast furnace slag, MgO cements, zeolites, silica fume, and cement kiln dust. The study showed that the binders could effectively immobilized the toxic...

  5. Ash deposit workshop: Class outline

    SciTech Connect (OSTI)

    Hatt, R. [Commercial Testing & Engineering Co., Lexington, KY (United States)

    1996-12-31T23:59:59.000Z

    Ash deposits formed from the combustion of coal and other fuels have plagued the steam production industry from the start. The ash fusion test has been around for over eighty years. As steam plant size increased, so have the problems associated with ash deposits. This workshop is designed to cover: (1) The basic types of deposits. (2) Causes of deposits. (3) Analytical procedures for resolving, or at least providing information about deposits and fuels, and (4) Deposit removal and reduction techniques.

  6. Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion

    SciTech Connect (OSTI)

    Shen, M.; Yang, R.T.

    1980-09-30T23:59:59.000Z

    Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

  7. Impacts of ocean acidification and mitigative hydrated lime addition on Pacific oyster larvae

    E-Print Network [OSTI]

    Impacts of ocean acidification and mitigative hydrated lime addition on Pacific oyster larvae, and for other species. Keywords: Ocean acidification; Pacific oyster; Larval stages; Hydrated lime; Shellfish No.: 577 Title of Project: Impacts of ocean acidification and mitigative hydrated lime addition

  8. Wood Residues as Fuel Source for Lime Kilns

    E-Print Network [OSTI]

    Azarniouch, M. K.; Philp, R. J.

    1984-01-01T23:59:59.000Z

    One of the main obstacles to total energy self sufficiency of kraft mills appears to be the fossil fuel requirements of the lime kilns. If an economical technology can be developed which allows fossil fuel to be replaced in whole or in part by wood...

  9. Heavy metal leaching from coal fly ash amended container substrates during Syngonium production

    SciTech Connect (OSTI)

    Li, Q.S.; Chen, J.J.; Li, Y.C. [University of Florida, Apopka, FL (United States)

    2008-02-15T23:59:59.000Z

    Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production. A great concern over this proposed beneficial use, however, is the potential contamination of surface and ground water by heavy metals. In this study, three fly ashes collected from Florida, Michigan, and North Carolina and a commercial dolomite were amended in a basal substrate. The formulated substrates were used to produce Syngonium podophyllum Schott 'Berry Allusion' in 15-cm diameter containers in a shaded greenhouse. Leachates from the containers were collected during the entire six months of plant production and analyzed for heavy metal concentrations. There were no detectable As, Cr, Hg, Pb, and Se in the leachates; Cd and Mo were only detected in few leachate samples. The metals constantly detected were Cu, Mn, Ni, and Zn. The total amounts of Cu, Mn, Ni, and Zn leached during the six-month production period were 95, 210, 44, and 337 {mu} g per container, indicating that such amounts in leachates may contribute little to contamination of surface and ground water. In addition, plant growth indices and fresh and dry weights of S. podophyllum 'Berry Allusion' produced from fly ash and dolomite-amended substrates were comparable except for the plants produced from the substrate amended with fly ash collected from Michigan which had reduced growth indices and fresh and dry weights. Thus, selected fly ashes can be alternatives to commercial dolomites as amendments to container substrates for ornamental plant production. The use of fly ashes as container substrate amendments should represent a new market for the beneficial use of this coal combustion byproduct.

  10. LOW VELOCITY SHPERE IMPACT OF SODA LIME SILICATE GLASS

    SciTech Connect (OSTI)

    Morrissey, Timothy G [ORNL; Fox, Ethan E [ORNL; Wereszczak, Andrew A [ORNL; Vuono, Daniel J [ORNL

    2012-01-01T23:59:59.000Z

    This report summarizes TARDEC-sponsored work at Oak Ridge National Laboratory (ORNL) during the FY11 involving low velocity ( 30 m/s or 65 mph) ball impact testing of Starphire soda lime silicate glass. The intent was to better understand low velocity impact response in the Starphire for sphere densities that bracketed that of rock. Five sphere materials were used: borosilicate glass, soda-lime silicate glass, steel, silicon nitride, and alumina. A gas gun was fabricated to produce controlled velocity delivery of the spheres against Starphire tile targets. Minimum impact velocities to initiate fracture in the Starphire were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the any of the five sphere-Starphire-target combinations.

  11. Kinetic Modeling and Assessment of Lime Pretreatment of Poplar Wood

    E-Print Network [OSTI]

    Sierra Ramirez, Rocio

    2012-02-14T23:59:59.000Z

    biomass is one of the most promising feedstocks for producing biofuels through fermentation processes. Among lignocellulose choices, poplar wood is appealing because of high energy potential, above-average carbon mitigation potential, fast growth... KINETIC MODELING AND ASSESSMENT OF LIME PRETREATMENT OF POPLAR WOOD A Dissertation by ROCIO SIERRA RAMIREZ Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

  12. High-surface-area hydrated lime for SO2 control

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Moran, D.L. (Illinois State Geological Survey, Champaign, IL (United States). Minerals Engineering Section)

    1993-03-01T23:59:59.000Z

    Since 1986, the Illinois State Geological Survey (ISGS), has been developing a process to produce high-surface-area hydrated lime (HSAHL) with more activity for adsorbing SO2 than commercially available hydrated lime. HSAHL prepared by the ISGS method as considerably higher surface area and porosity, and smaller mean particle diameter and crystallite size than commercial hydrated lime. The process has been optimized in a batch, bench-scale reactor and has been scaled-up to a 20--100 lb/hr process optimization unit (POU). Experiments have been conducted to optimize the ISGS hydration process and identify key parameters influencing hydrate properties for SO2 capture (surface area, porosity, particle size, and crystallite size). The known how is available to tailor properties of hydrated limes for specific SO2 removal applications. Pilot-scale tests conducted with the HSAHL under conditions typical of burning high-sulfur coals have achieved up to 90% SO2 capture in various DSI systems. The removal results are enough to bring most high-sulfur coals into compliance with acid rain legislation goals for the year 2000. The focus of the POU program is to generate critical engineering data necessary for the private sector to scale-up the process to a commercial level and provide estimates of the optimal cost of construction and operation of a commercial plant. ISGS is currently participating in a clean coal technology program (CCT-1) by providing 50 tons of HSAHL for a demonstration test at Illinois Power's Hennepin station in January 1993.

  13. LiME : A Linux based MPLS Emulator Abhijit Gadgil and Abhay Karandikar

    E-Print Network [OSTI]

    Karandikar, Abhay

    (API) for plugging in actual implementation thereby enabling a network device (called Device Under TestME to inject MPLS traÃ?c into the external world. Rest of the paper is organized as follows. Section 2 discusses

  14. Long duration ash probe

    DOE Patents [OSTI]

    Hurley, J.P.; McCollor, D.P.; Selle, S.J.

    1994-07-26T23:59:59.000Z

    A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during soot blowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon. 8 figs.

  15. Long duration ash probe

    DOE Patents [OSTI]

    Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

    1994-01-01T23:59:59.000Z

    A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

  16. LI I

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell:F E ,"^ I 1' . _c mUIIILGUformerLI

  17. 07Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) - Energy Innovation Portal AdvancedUsingLi Thermal Neutron

  18. 08Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) - Energy Innovation Portal AdvancedUsingLi Thermal1Thermal

  19. 5Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . S . D E P ABeHHeHeLi

  20. 10Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less is more:culturingProtonAPRIL/MAY9Hydrate ModelingBBe(p,HeLi

  1. A cement kiln flue-dust evaluated as a soil liming material 

    E-Print Network [OSTI]

    Stacha, Raimund

    1973-01-01T23:59:59.000Z

    production. The present lime study includes several of the predominate acid soil types in Texas. They should aid in furnishing soil testing laboratories with information which would facilitate better lime recommendations to Texas farmers as well... not determined. The present studies which include several of the predominate acid soil types in Texas should evaluate the usefulness of this local material as well as to further lime research in Texas to benefit soil test recommendations. 14 MATERIALS...

  2. ash dispersion utilizing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the USA for all coal ashes was approximately 34% in the year products containing clean coal ash compared to conventional coal ash. Utilization of clean coal ash is much...

  3. Precipitation kinetics in ultra-high lime softening

    E-Print Network [OSTI]

    Peacock, Edward Dale

    1986-01-01T23:59:59.000Z

    was provided by two more tubing pumps. Fluid surfaces were protected from COE contamination by a constant pressure nftrogen blanket. The reactor was operated for a period of time greater than or equal to lD hydraulic retentfon times or 7 times the ratio..., the ultra-high lime process has been proposed as a method to eliminate the constituents of chemical scale which reduce the recycle capacity of water in cooling systems. Reported herein are the results of a bench scale reactor study designed to evaluate...

  4. Advanced Characterisation of Municipal Solid Waste Ashes

    E-Print Network [OSTI]

    Advanced Characterisation of Municipal Solid Waste Ashes Preparatory thesis Randi Skytte Pedersen is to investigate Municipal Solid Waste (MSW) ashes with respect to particle sizes, structures and composition with characterisation of Municipal Solid Waste (MSW) ashes from the Danish power plant M°abjergværket, Holstebro. MSW

  5. The effects of lime and amines on the aging of asphalts and recycling agents

    E-Print Network [OSTI]

    Wisneski, Mary Luvola

    1995-01-01T23:59:59.000Z

    amounts of quick lime (CaO) and hydrated lime (Ca(OH),) on SHRP AAA-I and SHRP AAF-1. The second experiment was to determine the effects of three different amines and various amounts of CaO on aged SHRP AAA-I and SHRP AAF-I rejuvenated with ABM-F2, YBF-F2...

  6. Extension Bulletin E-1566 Revised September 2011 Facts About Soil Acidity and Lime

    E-Print Network [OSTI]

    materials to neutralize soil acidity. Pure calcium carbonate has a value of 100, and all other materials carbonate equivalent? Calcium carbonate equivalent (CCE) refers to the equivalent amount (pounds) of pure calcium carbonate in a ton or cubic yard of lime material. If a lime material has a NV of 85, it will have

  7. Sugarcane juice extraction and preservation, and long-term lime pretreatment of bagasse 

    E-Print Network [OSTI]

    Granda Cotlear, Cesar Benigno

    2005-02-17T23:59:59.000Z

    New technologies, such as an efficient vapor-compression evaporator, a stationary lime kiln (SLK), and the MixAlco process, compelled us to re-evaluate methods for producing sugar from cane. These technologies allow more water and lime to be used...

  8. Control of Lime Kiln Heat Balance is Key to Reduced Fuel Consumption 

    E-Print Network [OSTI]

    Kramm, D. J.

    1982-01-01T23:59:59.000Z

    This article discusses the various heat loads in a pulp mill lime sludge kiln, pointing out which heat loads cannot be reduced and which heat loads can, and how a reduction in energy use can be achieved. In almost any existing rotary lime sludge...

  9. A study of the effects of repeated loadings and free water on the stability of a lime stabilized clay 

    E-Print Network [OSTI]

    Jantos, Carl Thomas

    1959-01-01T23:59:59.000Z

    . Sere Percent Lime (Raw Soil) Triaxial Results . 9, Twe Percent Lime Triaxial Results . 10. Four Percent Lime Triaxial Results 37 37 40 LIST OF FIGURES 1. Triaxial Compression Device and Universal Testing Nachine . 2. Harvard Nlniature Compactor... Equipment 3. Typical Test Speoimens 4. Ltterberg Limits - Brasos River Clay 5. Modified JULS80 Compaction - Brasos River Clay 6. Nohr's Circles and Rupture Envelopes 7, 0 Percent Lime (Raw Soil) Triaxial Test, 15 psi 45 47 48 Lateral Pressure 49 S...

  10. Petrographic characterization of economizer fly ash

    SciTech Connect (OSTI)

    Valentim, B.; Hower, J.C.; Soares, S.; Guedes, A.; Garcia, C.; Flores, D.; Oliveira, A. [University of Porto, Oporto (Portugal). Center of Geology

    2009-11-15T23:59:59.000Z

    Policies for reducing NOx emissions have led power plants to restrict O{sub 2}, resulting in high-carbon fly ash production. Therefore, some potentially useful fly ash, such as the economizer fly ash, is discarded without a thorough knowledge of its composition. In order to characterize this type of fly ash, samples were collected from the economizer Portuguese power plant burning two low-sulfur bituminous coals. Characterization was also performed on economizer fly ash subsamples after wet sieving, density and magnetic separation. Analysis included atomic absorption spectroscopy, loss-on-ignition, scanning electron microscopy/energy-dispersive X-ray spectroscopy, optical microscopy, and micro-Raman spectroscopy.

  11. Effective Thermal Conductivity of Soda-Lime Silicate Glassmelts with Different Iron Contents Between 1100C and 1500C

    E-Print Network [OSTI]

    Pilon, Laurent

    Effective Thermal Conductivity of Soda-Lime Silicate Glassmelts with Different Iron Contents collected for soda- lime silicate glasses with iron content ranging from 0.008 to 1.1 wt% and temperatures, refractory walls wear more rapidly for clear glassmelts compared with colored ones.1 Soda-lime silicate glass

  12. ACAA fly ash basics: quick reference card

    SciTech Connect (OSTI)

    NONE

    2006-07-01T23:59:59.000Z

    Fly ash is a fine powdery material created when coal is burned to generate electricity. Before escaping into the environment via the utility stacks, the ash is collected and may be stored for beneficial uses or disposed of, if necessary. The use of fly ash provides environmental benefits, such as the conservation of natural resources, the reduction of greenhouse gas emissions and eliminating the needed for ash disposal in landfills. It is also a valuable mineral resource that is used in construction and manufacturing. Fly ash is used in the production of Portland cement, concrete, mortars and stuccos, manufactured aggregates along with various agricultural applications. As mineral filler, fly ash can be used for paints, shingles, carpet backing, plastics, metal castings and other purposes. This quick reference card is intended to provide the reader basic source, identification and composition, information specifically related to fly ash.

  13. LI Co-Facilitator Position Information & Application Leadership Institute (LI)

    E-Print Network [OSTI]

    Sheridan, Jennifer

    1 LI Co-Facilitator Position Information & Application Leadership Institute (LI) Office for Equity for the Co-Facilitator Position in the Leadership Institute. What follows is an overview of LI, a description of LI Co-Facilitator role, and the application. What is the Leadership Institute (LI)? The LI

  14. INDEX OF REFRACTION OF SHOCK LOADED SODA-LIME GLASS

    SciTech Connect (OSTI)

    Alexander, C. S. [Sandia National Laboratories, Albuquerque NM 87185 (United States)

    2009-12-28T23:59:59.000Z

    Soda-lime glass (SLG) is a potential low-cost VISAR window for use at moderate shock pressures (up to 2430 GPa) where the material remains transparent. In order for SLG to be practical as a VISAR window, the correction factor, which describes the frequency correction related to the strain dependence of the refractive index, and hence the index of refraction itself, must be characterized as a function of pressure. Characterization data are reported in this paper and compared to previous results. The present data show good agreement with those of Dandekar [J. Appl. Phys. 84, 6614 (1998)] and separate study results by Gibbons and Ahrens [J. Geophys. Res. 76, 5489 (1971)] up to 7 GPa. However, at stresses over 7 GPa, marked discrepancies are evident between the present data and that of Gibbons and Ahrens. Differences in test methods may explain these discrepancies.

  15. In What Form is Lime Present in Portland Cement

    E-Print Network [OSTI]

    Wright, Claude W.

    1910-01-01T23:59:59.000Z

    to obtain Si02.33a0, In his conclusions Hebuffat does not consider it of importance whether alit consists of pure Si02.3CaO or a crystalline compound of Si02.2CaO with 3a0 and an aluminate. He says the aluminate in Portland dement can­ not be Al 203.30a... Chemist follows: Si0 2, 23.20: A120 3, 8.10: P e 2 0 3 , 2.71: MgO, 1.00 S 0 3 > 1.20: CaO, 63.50. Total 100.71. On the basis of the calculation for uncombined lime given in a previous part of this paper, this cement con­ tains ? per cent...

  16. Low Velocity Sphere Impact of a Soda Lime Silicate Glass

    SciTech Connect (OSTI)

    Wereszczak, Andrew A [ORNL; Fox, Ethan E [ORNL; Morrissey, Timothy G [ORNL; Vuono, Daniel J [ORNL

    2011-10-01T23:59:59.000Z

    This report summarizes TARDEC-sponsored work at Oak Ridge National Laboratory (ORNL) during the FY11 involving low velocity (< 30 m/s or < 65 mph) ball impact testing of Starphire soda lime silicate glass. The intent was to better understand low velocity impact response in the Starphire for sphere densities that bracketed that of rock. Five sphere materials were used: borosilicate glass, soda-lime silicate glass, steel, silicon nitride, and alumina. A gas gun was fabricated to produce controlled velocity delivery of the spheres against Starphire tile targets. Minimum impact velocities to initiate fracture in the Starphire were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the any of the five sphere-Starphire-target combinations. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) Frictional effects contribute to fracture initiation. (2) Spheres with a lower elastic modulus require less force to initiate fracture in the Starphire than spheres with a higher elastic modulus. (3) Contact-induced fracture did not initiate in the Starphire SLS for impact kinetic energies < 150 mJ. Fracture sometimes initiated or kinetic energies between {approx} 150-1100 mJ; however, it tended to occur when lower elastic modulus spheres were impacting it. Contact-induced fracture would always occur for impact energies > 1100 mJ. (4) The force necessary to initiate contact-induced fracture is higher under dynamic or impact conditions than it is under quasi-static indentation conditions. (5) Among the five used sphere materials, silicon nitride was the closest match to 'rock' in terms of both density and (probably) elastic modulus.

  17. A study of the rate of gain of strength in lime stabilized soil 

    E-Print Network [OSTI]

    Nichols, Sterling Ramsdell, Jr

    1960-01-01T23:59:59.000Z

    0 37 ~ o ~ 4'7 APPEEDIX C. Electron Nicrographs . . . . . . . . . . . 75 LIST OF TABLES Table Page i. Cation-Exchange Capacity of Clay Minerals 15 2. Results of pH Test on Lime Treate Clay a o o o o o 3. X-Ray Diffraction Data 4... Triaxial Compressi. on Test Results 12. Triaxisl Compression Test Results 13. Triaxial Compression Test Results 14. Triaxial Compression Test Results 15. Triaxial Compression Test Results Least Squares Raw Soil. 1$ Lime Content 2$ Lime Content 4...

  18. Equations for predicting the layer stiffness moduli in pavement systems containing lime-flyash stabilized materials 

    E-Print Network [OSTI]

    Alam, Shah Manzoor

    1984-01-01T23:59:59.000Z

    . progressive stiffening of some of the test sections. For low PI clayey soils, the optimum lime-flyash ratios for long term stiff- ness gains were found to be 0. 08 to 0. 5 using a minimum of 2C lime. For very low PI coarse sandy soils, 20 to 405 flyash... Analysis Number 3 Effect of Time on Lime-flyash Stabilized Layers . CHAPTER V. CONCLUSIONS AND RECONNENDATIONS . . . , . . . REFERENCES APPENDIX A Typical layouts and sections of Test sites . . . . . 8 Fitted Dynaflect deflections results C Results...

  19. Volcanic ash in feed coal and its influence on coal combustion products

    SciTech Connect (OSTI)

    Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.; Brownfield, I.K.; Hower, J.C.; Stricker, G.D.; O'Connor, J.T.

    2000-07-01T23:59:59.000Z

    The US Geological Survey and the University of Kentucky Center for Applied Energy Research are collaborating with an Indiana Utility to determine the physical and chemical properties of feed coal and coal combustion products (CCPs) from a coal-fired power plant. The plant utilizes a low-sulfur (.23--.47 weight percent S) coal from the Powder River Basin, Wyoming. Scanning Electron Microscope (SEM) and X-ray diffraction (XRD) analysis of feed coal samples identified two mineral suites. A primary suite (not authigenic) consisting of quartz (detrital and volcanic beta-form grains), biotite, and minor zircon and a secondary authigenic mineral suite containing calcite, alumino-phosphates (crandallite and gorceixite), kaolinite, quartz, anatase, barite, and pyrite. The authigenic minerals are attributed to air-fall and reworked volcanic ash that was deposited in peat-forming mires. The Powder River Basin feed coals contain higher amounts of Ba, Ca, Mg, Na, Sr, and P compared to other analyzed eastern coals. These elements are associated with alumino-phosphate, biotite, calcite, and clay minerals. The element associations are indicative of coal that incorporated volcanic ash during deposition. XRD analysis of CCPs revealed a predominance of glass, perovskite, lime, gehlenite, quartz, and phosphates with minor amounts of periclase, anhydrite, hematite, and spinel group minerals in the fly ash; and quartz, plagioclase (albite and anorthite), pyroxene (augite and fassaite), rhodonite, and akermanite in the bottom ash. Microprobe and SEM analysis of fly ash samples revealed quartz, zircon, monazite, euhedral laths of corundum with merrillite, hematite, dendritic spinels/ferrites, and rounded grains of wollastonite with periclase. The abundant Ca and Mg mineral phases in the fly ashes are related to the presence of carbonate, clay, and phosphate minerals in the feed coal. The Ca- and Mg-rich mineral phases in the CCPs can be attributed to volcanic minerals deposited in the peat-forming mire. Dissolution and alteration of these minerals occurred either in the peat-forming sate or during coalification/diagenesis contributing to the authigenic mineral suite. Additionally, detrital mineral input and epigenetic ground-water flow may have affected the geochemistry of the feed coal.

  20. Combustion with reduced carbon in the ash

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.

    2005-12-27T23:59:59.000Z

    Combustion of coal in which oxygen is injected into the coal as it emerges from burner produces ash having reduced amounts of carbon.

  1. ash leachate generation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    72 Key To Ash Sources FGD-1 MPU 8 Materials Science Websites Summary: Key To Ash Sources FGD-1 MPU 8 FGD-2 Alliant Energy FGD-3 WPS Pulliam Ash 12;Center for By-Products...

  2. ash quality characterization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    78 Key To Ash Sources FGD-1 MPU 8 Materials Science Websites Summary: Key To Ash Sources FGD-1 MPU 8 FGD-2 Alliant Energy FGD-3 WPS Pulliam Ash 12;Center for By-Products...

  3. Treatment of fly ash for use in concrete

    DOE Patents [OSTI]

    Boxley, Chett (Park City, UT)

    2012-05-15T23:59:59.000Z

    A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

  4. ash blended cement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    biomass blends Texas A&M University - TxSpace Summary: , low ash partially composted manure LAPC, high ash raw manure HARM, and high ash partially composted manure HAPC)...

  5. Validation of the new mixture design and testing protocol for lime stabilization

    E-Print Network [OSTI]

    Yusuf, Fateh Ul Anam Muhammad Shafee

    2001-01-01T23:59:59.000Z

    describes some pertinent findings of the study. In situ properties of lime stabilized subgrades are identified based on Falling Weight Deflectometer (FWD) deflection measurements, Ground Penetration Radar (GPR) profiles, and Dynamic Cone Penetrometer (DCP...

  6. Sulfate Induced Heave: Addressing Ettringite Behavior in Lime Treated Soils and in Cementitious Materials 

    E-Print Network [OSTI]

    Kochyil Sasidharan Nair, Syam Kumar

    2012-02-14T23:59:59.000Z

    threshold level of soluble sulfates in soils that can trigger substantial ettringite growth. The third part of this dissertation identifies alternative, probable mechanisms of swelling when sulfate laden soils are stabilized with lime. The swelling distress...

  7. Validation of the new mixture design and testing protocol for lime stabilization 

    E-Print Network [OSTI]

    Yusuf, Fateh Ul Anam Muhammad Shafee

    2001-01-01T23:59:59.000Z

    and testing protocol is presented for lime stabilized subgrades. Comparison of field test data and laboratory test data shows that laboratory design test properties were achieved in the field. These properties are used in a mechanistic analysis to assess...

  8. The effect of hydrated lime on Salmonella enteritidis survival in poultry litter and poult performance 

    E-Print Network [OSTI]

    Stanush, Deborah Denise

    2000-01-01T23:59:59.000Z

    The presence of Salmonella and/or Campylobacter in poultry litter may contribute to contaminated processed carcasses. Initially in our first study, we evaluated the effect of 5, 10, or 20% added lime on in vitro survival of Salmonella enteritidis...

  9. Legume establishment, nodulation, and forage production as influenced by N, P, K fertilizers and lime

    E-Print Network [OSTI]

    Martillo Chalen, Eduardo Enrique

    1983-01-01T23:59:59.000Z

    LEGUME ESTABLISHMEJ'JT, NODL'LATION, AND FORAGE PRODUCTION AS INFLUE. 'JCZD BY N, P, K FERTILIZERS AND LIME A thesis by EDUARDO ENRIQUZ MARTII, 0 CHA EIJ Submitted to the Graduate College of Texas ASM University in partial fulfillment... of the requirement for tne degree of MASTER OF SCIENCE December 1983 Major Subject: Agronomy LEGUME ESTABLISHMENT, NODULATION, AND FORAGE PRODUCTION AS INFLUENCED BY N, P, K FERTILIZERS AND LIME A thesis EDUARDO ENRIQUE MARTILLO CHALEN Approved as to style...

  10. Equations for predicting the layer stiffness moduli in pavement systems containing lime-flyash stabilized materials

    E-Print Network [OSTI]

    Alam, Shah Manzoor

    1984-01-01T23:59:59.000Z

    EOUATIONS FOR PREDICTING THE LAYER STIFFNESS ' MODULI IN PAVEMENT SYSTEMS CONTAINING LIME-FLYASH STABILIZED MATERIALS A Thesis by SHAH MANZOOR ALAM Submitted to the Graduate College of Texas AN University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1984 Major Subject: Civil Engineering EI)UATIONS FOR PREDICTING THE LAYER STIFFNESS MDDULI IN PAVEMENT SYSTEMS CONTAINING LIME-FLYASH STABILIZED MATERIALS A Thesis by SHAH MANZOOR ALAM Approved...

  11. Liming effects on slash pine (Pinus elliottii Englm.) seedlings growing on acid soils 

    E-Print Network [OSTI]

    Elzner, John Thomas

    1978-01-01T23:59:59.000Z

    . . . . . . . . . . lg Comparison of treatment means on selected soils using Duncan's New Nultiple Range Test . . . . . . . . . . . . . . . . , . , 20 pH and percent exchangeable Al neutralized with lime rates based on initial exchangeable Al content...* , 842* 95. 02* . 051 . 0060 . 0001 408. 0 . 0328 Error 33 . 072 . 053 . 155 . 004 . 147 . 018 . 0033 . 0002 336. 8 . 0151 *P~ 0. 05 Table 4. ? Comparison of treatment means on selected soils using Duncan's New Multiple Range Test. Lime rate, ! Exch...

  12. AEC Lowman Station - coal switching and magnesium-enhanced lime scrubbing to lower operating costs

    SciTech Connect (OSTI)

    Inkenhaus, W.; Babu, M.; Smith, K. [Dravo Lime Co., Pittsburgh, PA (United States); Loper, L. [Alabama Electric Coopreative, Leroy, AL (United States)

    1997-12-31T23:59:59.000Z

    AEC`s Lowman Station is located in Leroy, Alabama. There are three coal-fired boilers at this station. Unit 1 is capable of generating 85 MW without a flue gas desulfurization, FGD, system. Units 2 and 3, with a total of 516 MW output capacity, are equipped with FGD systems. The FGD plant was designed for wet limestone FGD with natural oxidation. Lowman Station burned low sulfur, 1.3 to 1.8% sulfur, coal. In January of 1996 AEC switched Units 2 and 3 from limestone to magnesium-enhanced lime FGD operation. It was determined that the plant could take advantage of the higher SO{sub 2} removal efficiency of the magnesium-enhanced lime system. Major benefits resulting from this conversion were AEC`s ability to switch to a lower cost high sulfur coal while meeting the stringent SO{sub 2} emission requirements. Power cost savings resulted from the lower liquid to gas ratio required by the magnesium-enhanced lime process. Three recirculation pumps per module were reduced to a single operating pump per module, lowering the scrubber pressure drop. Significant cost reduction in the operating costs of the ball mill was realized due to modifications made to slake lime instead of grinding limestone. Prior to switching, personnel from AEC and Dravo Lime Company ran a four week test on magnesium-enhanced lime to obtain scrubber performance data including SO{sub 2} removal efficiencies on the modules while burning a 1.8% sulfur coal. This paper discusses the plant modifications that were needed to make the switch, cost justifications due to coal switching, and AEC`s operating experiences to date. AEC and Dravo Lime Company working together as a team conducted detailed cost studies, followed by extensive field tests and implemented the plant modifications. This plant continues to operate burning higher sulfur coal with the magnesium-enhanced lime FGD system.

  13. Development of dredged ash disposal area, Paradise fossil plant

    SciTech Connect (OSTI)

    Not Available

    1989-02-01T23:59:59.000Z

    Paradise Steam-Electric Plant coal-fired facility in Muhlenberg County, Kentucky. This project is to construct a dredge pond near the Jacobs Creek ash pond capable of storing fly ash dredged from the ash pond. This will provide approximately 10 years of additional fly ash storage in the fly ash pond. Effluent from the dredge pond will be returned to the Jacobs Creek ash pond for discharge to Jacobs Creek. 4 figs., 5 tabs.

  14. An introduction to LIME 1.0 and its use in coupling codes for multiphysics simulations.

    SciTech Connect (OSTI)

    Belcourt, Noel; Pawlowski, Roger Patrick; Schmidt, Rodney Cannon; Hooper, Russell Warren

    2011-11-01T23:59:59.000Z

    LIME is a small software package for creating multiphysics simulation codes. The name was formed as an acronym denoting 'Lightweight Integrating Multiphysics Environment for coupling codes.' LIME is intended to be especially useful when separate computer codes (which may be written in any standard computer language) already exist to solve different parts of a multiphysics problem. LIME provides the key high-level software (written in C++), a well defined approach (with example templates), and interface requirements to enable the assembly of multiple physics codes into a single coupled-multiphysics simulation code. In this report we introduce important software design characteristics of LIME, describe key components of a typical multiphysics application that might be created using LIME, and provide basic examples of its use - including the customized software that must be written by a user. We also describe the types of modifications that may be needed to individual physics codes in order for them to be incorporated into a LIME-based multiphysics application.

  15. ashes oral biotillgaenglighet: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ash 1. Halima Hadiahmetovi?; D. D. Sarajevo; M. Sc; Raza Sunulahpai?; Bosnia Herzegovina 97 Leachate Geochemical Results for Ash Samples from the June 2007 Angora...

  16. Development of an Accelerated Ash-Loading Protocol for Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Poster presentation at the 2007...

  17. Ashe County - Wind Energy System Ordinance | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Tribal Government Utility Program Info State North Carolina Program Type SolarWind Permitting Standards Provider Ashe County Planning Department In 2007 Ashe County...

  18. Impact of Biodiesel on Ash Emissions and Lubricant Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and...

  19. ash intranasal instillation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    there is no mixing of insufficiently thermally treated material with bottom ash. Good fire control Columbia University 17 Characteristics and Uses for Ash Environmental...

  20. ash deposition propensities: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environments (>3.5 km), banded iron, volcanic ashes Summary diagrams available Clastic depositional environments Harbor, David 57 Ash Dump Site Manager: EHS&RM Biology and...

  1. Uncovering Fundamental Ash-Formation Mechanisms and Potential...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis of Ash Formation and Transport Key Parameters Affecting DPF Performance Degradation and Impact on Lifetime Fuel Economy Non-Destructive X-ray Measurement of Soot, Ash,...

  2. Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter Minimizing Lubricant-Ash Requirement and Impact on Emission...

  3. Ash Chemistry in MSW Incineration Plants

    E-Print Network [OSTI]

    Ash Chemistry in MSW Incineration Plants: Advanced Characterization and Thermodynamic Introduction to Municipal Solid Waste Incineration 2 Chapter 2 Plants Considered and Samples Collected 5 Chapter 3 Mapping of Ash Chemistry in MSWI Plants 8 Chapter 4 Advanced Characterization Methods 12 4

  4. Fly Ash Amendments Catalyze Soil Carbon Sequestration

    SciTech Connect (OSTI)

    Amonette, James E.; Kim, Jungbae; Russell, Colleen K.; Palumbo, A. V.; Daniels, William L.

    2003-09-15T23:59:59.000Z

    We tested the effects of four alkaline fly ashes {Class C (sub-bituminous), Class F (bituminous), Class F [bituminous with flue-gas desulfurization (FGD) products], and Class F (lignitic)} on a reaction that simulates the enzyme-mediated formation of humic materials in soils. The presence of FGD products completely halted the reaction, and the bituminous ash showed no benefit over an ash-free control. The sub-bituminous and lignitic fly ashes, however, increased the amount of polymer formed by several-fold. The strong synergetic effect of these ashes when enzyme is present apparently arises from the combined effects of metal oxide co-oxidation (Fe and Mn oxides), alkaline pH, and physical stabilization of the enzyme (porous silica cenospheres).

  5. Treatment of fly ash for use in concrete

    SciTech Connect (OSTI)

    Boxley, Chett; Akash, Akash; Zhao, Qiang

    2013-01-08T23:59:59.000Z

    A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

  6. Treatment of fly ash for use in concrete

    DOE Patents [OSTI]

    Boxley, Chett (Park City, UT); Akash, Akash (Salt lake City, UT); Zhao, Qiang (Natick, MA)

    2012-05-08T23:59:59.000Z

    A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

  7. The impact of weathering and aging on a LIMB ash stockpile material

    SciTech Connect (OSTI)

    Beeghly, J.H. [Dravo Lime Co., Pittsburgh, PA (United States); Bigham, J.M. [Ohio State Univ., Columbus, OH (United States). Dept. of Natural Resources; Dick, W.A.; Stehouwer, R.C. [Ohio State Univ., Wooster, OH (United States). Dept. of Natural Resources; Wolfe, W.B. [Ohio State Univ., Columbus, OH (United States). Dept. of Civil Engineering

    1995-03-01T23:59:59.000Z

    A 1,500 ton temporary storage pile of water conditioned LIMB (Lime Injected Multistage Burner) ash by-product from the Ohio Edison Edgewater plant Lorain, OH was constructed in July, 1991 at a coal company near New Philadelphia, Ohio. This stockpile was created for dry FGD by-product material to be held in reserve for a land application uses field demonstration. High volume, beneficial uses of dry FGD by-products, such as for mine reclamation and embankment stabilization, will require temporary stockpiling of the by-product. Purpose for constructing this pile was to study changes with time in the LIMB by-product material when exposed to weathering. This by-product material was studied over a 2 1/2 year period. The water to control fugitive dust was added in the ash conditioner at the power plant while being loaded into dump trucks. Amount of water normally added in the conditioning process is close to the optimum moisture content of 40--50 % (dry weight basis), to construct a compacted road embankment or road base. Four environmental operating permits required for construction of the storage pile were obtained, three from Ohio EPA (air, water and solid waste), and one from the Ohio Division of Reclamation (revised reclamation area permit). There was no significant environmental impacts from storm runoff or leachate water from the LIMB ash stockpile during the initial 18 month period through December, 1992. After 2 1/2 years of storage, the potential value of the LIMB material for use as a road embankment material or soil conditioner has declined significantly. Ettringite formation occurs. Aging allows the expansive reaction to take place before its potential use as compacted structural fill or embankment.

  8. Neutron spectroscopic factors of 7Li and astrophysical 6Li(n,g)7Li reaction rates

    E-Print Network [OSTI]

    Jun Su; Zhihong Li; Bing Guo; Xixiang Bai; Zhichang Li; Jiancheng Liu; Youbao Wang; Gang Lian; Sheng Zeng; Baoxiang Wang; Shengquan Yan; Yunju Li; Ertao Li; Qiwen Fan; Weiping Liu

    2010-01-25T23:59:59.000Z

    Angular distributions of the 7Li(6Li,6Li)7Li elastic scattering and the 7Li(6Li,7Li_{g.s.})6Li, 7Li(6Li,7Li*_{0.48})6Li transfer reactions at Ec.m. = 23.7 MeV were measured with the Q3D magnetic spectrograph. The optical potential of 6Li+7Li was obtained by fitting the elastic scattering differential cross sections. Based on the distorted wave Born approximation (DWBA) analysis, spectroscopic factors of 7Li=6Li+n were determined to be 0.73 +- 0.05 and 0.90 +- 0.09 for the ground and first exited states in 7Li, respectively. Using the spectroscopic factors, the cross sections of the 6Li(n,g)7Li direct neutron capture reactions and the astrophysical 6Li(n,g)7Li reaction rates were derived.

  9. Advanced mineral calciner for regeneration of lime. Final report, March 1995--May 1997

    SciTech Connect (OSTI)

    Namazian, M.; Nickeson, R.; Lovas, B.; Miller, G.; Kelly, J.

    1997-12-31T23:59:59.000Z

    There are approximately 800 pulp, paper and paperboard mills in the United States. Pulp and paper is the ninth largest industry in US, uses 2.8 quads of energy per year and ranks third among all domestic US industries in the cost of energy consumed. A significant fraction of the energy consumed in pulp and paper plants is needed to recover chemicals that are used in breaking down the wood chips into pulp. In particular, 0.1 quads of energy per year are used to regenerate lime. Furthermore, pulp and paper plant operations generate 9,870 tons of NOx per year. Additionally over two million tons of spent lime are sent to landfills each year. In addition, growth in paper demand and changes in plant processes (e.g., bleaching), as a result of environmental pressures, will continue to drive the need for more lime regeneration capacity. Unless the increased capacity can be delivered productively and inexpensively, the growth in pulp and paper may occur in overseas markets. Furthermore, if new environmental constraints cannot be met at low cost, existing US pulp and paper production capacity may also move off-shore. The advanced mineral calciner (AMC) technology was developed to address this lime regeneration need. Prior to describing the technology, and the program of work that was used to test the concept, conventional lime regeneration systems and their limitations are described.

  10. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-12-04T23:59:59.000Z

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  11. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-02-28T23:59:59.000Z

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  12. Fly ash enhanced metal removal process

    SciTech Connect (OSTI)

    Nonavinakere, S. [Plexus Scientific Corp., Annapolis, MD (United States); Reed, B.E. [West Virginia Univ., Morgantown, WV (United States). Dept. of Civil Engineering

    1995-12-31T23:59:59.000Z

    The primary objective of the study was to evaluate the effectiveness of fly ashes from local thermal power plants in the removal of cadmium, nickel, chromium, lead, and copper from aqueous waste streams. Physical and chemical characteristics of fly ashes were determined, batch isotherm studies were conducted. A practical application of using fly ash in treating spent electroless nickel (EN) plating baths by modified conventional precipitation or solid enhanced metal removal process (SEMR) was investigated. In addition to nickel the EN baths also contains completing agents such as ammonium citrate and succinic acid reducing agents such as phosphate and hypophosphite. SEMR experiments were conducted at different pHs, fly ash type and concentrations, and settling times.

  13. Environmental aspects of the Brandywine ash site

    SciTech Connect (OSTI)

    Simek, E.; Potera, G.; Schuller, R.; Herritt, M.; Wagner, R.

    1984-05-01T23:59:59.000Z

    The Brandywine ash site, located in Prince Georges County, Maryland, is owned and operated by the Potomac Electric Power Company (PEPCO). This site was designed specifically for the storage of the large quantities of coal ash produced at PEPCO's nearby Chalk Point Generating Station. Environmental Resources Management, Inc. (ERM), with assistance from the Maryland Department of Natural Resources, Tidewater Administration, conducted a study of this site for the Maryland Power Plant Siting Program (PPSP) to determine if ash constituents are adversely affecting the environment. Section 1 of this report is an introduction to coal ash and its physical/chemical characteristics. Section 2 describes the environment at the site and in adjacent areas. Within this setting, a description of the facility is presented as Section 3. Section 4 relies on the previous sections to point out any likely effects of the facility on the environment and to discount unlikely interactions. Key conclusions are presented in Section 5.

  14. EFFECTS OF COMPOST AND LIME APPLICATION ON SOIL CHEMICAL PROPERTIES, SOIL MICROBIAL COMMUNITY, AND FUSARIUM WILT IN

    E-Print Network [OSTI]

    Ma, Lena

    1 EFFECTS OF COMPOST AND LIME APPLICATION ON SOIL CHEMICAL PROPERTIES, SOIL MICROBIAL COMMUNITY compost as an antagonistic suppression approach to combat soil-borne disease effects on crop yields the effect of compost and lime on soil chemical properties, the soil microbial community (including Fusarium

  15. Stabilization/solidification of TSCA incinerator ash

    SciTech Connect (OSTI)

    Spence, R.D.; Trotter, D.R.; Francis, C.L.; Morgan, I.L.

    1994-06-01T23:59:59.000Z

    Stabilization/solidification is a well-known waste treatment technique that utilizes different additives and processes. The Phoenix Ash Technology of the Technical Innovation Development Engineering Company is such a technique that uses Cass C fly ash and mechanical pressure to make brick waste forms out of solid wastes, such as the bottom ash from the Toxic Substances Control Act incinerator at the Oak Ridge K-25 Site. One advantage of this technique is that no volume increase over the bulk volume of the bottom ash occurs. This technique should have the same high pH stabilization for Resource Conservation and Recovery Act metals as similar techniques. Also, consolidation of the bottom ash minimizes the potential problems of material dispersion and container corrosion. The bottom ash was spiked with {sup 99}{Tc} to test the effectiveness of the bricks as a physical barrier. The {sup 99}{Tc} leachability index measured for these bricks was 6.8, typical for the pertechnetate anion in cementitious waste forms, indicating that these bricks have accessible porosity as high as that of other cementitious waste forms, despite the mechanical compression, higher waste form density, and water resistant polymer coating.

  16. Utilization of pulverized fuel ash in Malta

    SciTech Connect (OSTI)

    Camilleri, Josette [Department of Building and Civil Engineering, Faculty of Architecture and Civil Engineering, University of Malta, Msida (Malta); Sammut, Michael [Department of Pathology, St. Luke's Hospital, G'Mangia (Malta); Montesin, Franco E. [Department of Building and Civil Engineering, Faculty of Architecture and Civil Engineering, University of Malta, Msida (Malta)]. E-mail: franco.montesin@um.edu.mt

    2006-07-01T23:59:59.000Z

    In Malta all of the waste produced is mixed and deposited at various sites around the island. None of these sites were purpose built, and all of the waste is above groundwater level. The landfills are not engineered and do not contain any measures to collect leachate and gases emanating from the disposal sites. Another waste, which is disposed of in landfills, is pulverized fuel ash (PFA), which is a by-product of coal combustion by the power station. This has been disposed of in landfill, because its use has been precluded due to the radioactivity of the ashes. The aim of this study was to analyze the chemical composition of the pulverized fuel ash and to attempt to utilize it as a cement replacement in normal concrete mixes in the construction industry. The levels of radiation emitted from the ashes were measured by gamma spectrometry. The results of this study revealed that although at early ages cement replacement by PFA resulted in a reduction in compressive strength (P = 0), when compared to the reference concrete at later ages the strengths measured on concrete cores were comparable to the reference concrete (P > 0.05). The utilization of PFA up to 20% cement replacement in concrete did not raise the radioactivity of the concrete. In conclusion, utilization of PFA in the construction industry would be a better way of disposing of the ashes rather than controlling the leachate and any radioactivity emitted by the landfilled ashes.

  17. A theory manual for multi-physics code coupling in LIME.

    SciTech Connect (OSTI)

    Belcourt, Noel; Bartlett, Roscoe Ainsworth; Pawlowski, Roger Patrick; Schmidt, Rodney Cannon; Hooper, Russell Warren

    2011-03-01T23:59:59.000Z

    The Lightweight Integrating Multi-physics Environment (LIME) is a software package for creating multi-physics simulation codes. Its primary application space is when computer codes are currently available to solve different parts of a multi-physics problem and now need to be coupled with other such codes. In this report we define a common domain language for discussing multi-physics coupling and describe the basic theory associated with multiphysics coupling algorithms that are to be supported in LIME. We provide an assessment of coupling techniques for both steady-state and time dependent coupled systems. Example couplings are also demonstrated.

  18. Evaluation of methods of mixing lime in bituminous paving mixtures in batch and drum plants 

    E-Print Network [OSTI]

    Button, Joseph Wade

    1984-01-01T23:59:59.000Z

    ) Joseph Wade Button, B. S. , Texas ASM University Co-Chairmen of Advisory Committee: Mr. Bob M. Gallaway and Dr. Dallas N. Little A field test was conducted to evaluate the use of hydrated lime as an antistrip additive in hot mix asphalt concrete.... Lime was added in the pugmill of the batch plant, on the cold feed belt, and through the fines feeder of the drum mix plant. The asphalt and aggregates used were characterized in the laboratory. Asphalt concrete mixture tests included laboratory...

  19. Cement kiln flue dust as a source of lime and potassium in four East Texas soils 

    E-Print Network [OSTI]

    Poole, Warren David

    1975-01-01T23:59:59.000Z

    (18) a 5. 3 (84) a 4. 8 (76) a 4. 2 (66) a 3. 8 (61) a 5. 2 (82) a 4. 1 (64) a 5. 0 (80) a *Duncan's Multiple Range Test. ? = . 05. Differences in yield due to rate of applied lime material followed by the same letter are not significantly...CEMENT KILN FLUE DUST AS A SOURCE OF LIME AND POTASSIUM IN FOUR EAST TEXAS SOILS A Thesis by WARREN DAVID POOLE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER...

  20. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01T23:59:59.000Z

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  1. The effect of hydrated lime on Salmonella enteritidis survival in poultry litter and poult performance

    E-Print Network [OSTI]

    Stanush, Deborah Denise

    2000-01-01T23:59:59.000Z

    or negative samples. At 24 or 48 h, 10/10 (100%) of untreated (control) litter samples were positive for Salmonella. Addition of lime resulted in significantly reduced Salmonella recovery incidence at 24 h. These data suggest that the addition of hydrated...

  2. Hydrothermal reaction of fly ash. Final report

    SciTech Connect (OSTI)

    Brown, P.W.

    1994-12-31T23:59:59.000Z

    The reactions which occur when fly ash is treated under hydrothermal conditions were investigated. This was done for the following primary reasons. The first of these is to determine the nature of the phases that form to assess the stabilities of these phases in the ambient environment and, finally, to assess whether these phases are capable of sequestering hazardous species. The second reason for undertaking this study was whether, depending on the composition of the ash and the presence of selected additives, it would be possible under hydrothermal conditions to form compounds which have cementitious properties. Formation of four classes of compounds, which bracket likely fly ash compositional ranges, were selected for study. The classes are calcium silicate hydrates, calcium selenates, and calcium aluminosulfates, and silicate-based glasses. Specific compounds synthesized were determined and their stability regions assessed. As part of stability assessment, the extent to which selected hazardous species are sequestered was determined. Finally, the cementing properties of these compounds were established. The results obtained in this program have demonstrated that mild hydrothermal conditions can be employed to improve the reactivity of fly ash. Such improvements in reactivity can result in the formation of monolithic forms which may exhibit suitable mechanical properties for selected applications as building materials. If the ashes involved are considered hazardous, the mechanical properties exhibited indicated the forms could be handled in a manner which facilitates their disposal.

  3. Approaches to the petrographic characterization of fly ash

    SciTech Connect (OSTI)

    Hower, J.C.; Rathbone, R.F.; Graham, U.M. [Univ. of Kentucky, Lexington, KY (United States)] [and others

    1995-08-01T23:59:59.000Z

    The enhanced understanding of fly ash properties provided by petrographic analysis, a level of detail chemical analysis cannot provide, will be essential in the upgrading and utilization of fly ash produced in boilers retrofitted to meet clean air standards. Howe et al estimated that over 25% of the fly ash produced in Kentucky in 1992 would not have met the Kentucky Department of Transportation limit of 3% loss-on-ignition (LOI) for class F fly ash used as a Portland cement admixture. The conversion of boilers to low-NO{sub x} emission units increases fly ash carbon, hence LOI, by 150-200% rendering the fly ash unsuitable for highway construction use in concrete. The preservation of fly ash`s market share will require increased attention to the removal of excess carbon from the fly ash. In this paper, we will discuss the basic components of fly ash. An example of the petrographic analysis of fly ash from a Kentucky power plant will be used to illustrate the partitioning of fly ash components by size, as well as within the fly ash collection system.

  4. Energy Efficient Microwave Hybrid Processing of Lime for Cement, Steel, and Glass Industries

    SciTech Connect (OSTI)

    Fall, Morgana L; Yakovlev, Vadim; Sahi, Catherine; Baranova, Inessa; Bowers, Johnney G; Esquenazi\t, Gibran L

    2012-02-10T23:59:59.000Z

    In this study, the microwave materials interactions were studied through dielectric property measurements, process modeling, and lab scale microwave hybrid calcination tests. Characterization and analysis were performed to evaluate material reactions and energy usage. Processing parameters for laboratory scale and larger scale calcining experiments were developed for MAT limestone calcination. Early stage equipment design concepts were developed, with a focus on microwave post heating treatment. The retrofitting of existing rotary calcine equipment in the lime industry was assessed and found to be feasible. Ceralink sought to address some of the major barriers to the uptake of MAT identified as the need for (1) team approach with end users, technology partners, and equipment manufacturers, (2) modeling that incorporates kiln materials and variations to the design of industrial microwave equipment. This project has furthered the commercialization effort of MAT by working closely with an industrial lime manufacturer to educate them regarding MAT, identifying equipment manufacturer to supply microwave equipment, and developing a sophisticated MAT modeling with WPI, the university partner. MAT was shown to enhance calcining through lower energy consumption and faster reaction rates compared to conventional processing. Laboratory testing concluded that a 23% reduction in energy was possible for calcining small batches (5kg). Scale-up testing indicated that the energy savings increased as a function of load size and 36% energy savings was demonstrated (22 kg). A sophisticated model was developed which combines simultaneous microwave and conventional heating. Continued development of this modeling software could be used for larger scale calcining simulations, which would be a beneficial low-cost tool for exploring equipment design prior to actual building. Based on these findings, estimates for production scale MAT calcining benefits were calculated, assuming uptake of MAT in the US lime industry. This estimate showed that 7.3 TBTU/year could be saved, with reduction of 270 MMlbs of CO2 emissions, and $29 MM/year in economic savings. Taking into account estimates for MAT implementation in the US cement industry, an additional 39 TBTU/year, 3 Blbs of CO2 and $155 MM/year could be saved. One of the main remaining barriers to commercialization of MAT for the lime and cement industries is the sheer size of production. Through this project, it was realized that a production size MAT rotary calciner was not feasible, and a different approach was adapted. The concept of a microwave post heat section located in the upper portion of the cooler was devised and appears to be a more realistic approach for MAT implementation. Commercialization of this technology will require (1) continued pilot scale calcining demonstrations, (2) involvement of lime kiln companies, and (3) involvement of an industrial microwave equipment provider. An initial design concept for a MAT post-heat treatment section was conceived as a retrofit into the cooler sections of existing lime rotary calciners with a 1.4 year payback. Retrofitting will help spur implementation of this technology, as the capital investment will be minimal for enhancing the efficiency of current rotary lime kilns. Retrofits would likely be attractive to lime manufacturers, as the purchase of a new lime kiln is on the order of a $30 million dollar investment, where as a MAT retrofit is estimated on the order of $1 million. The path for commercialization lies in partnering with existing lime kiln companies, who will be able to implement the microwave post heat sections in existing and new build kilns. A microwave equipment provider has been identified, who would make up part of the continued development and commercialization team.

  5. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

    1984-01-01T23:59:59.000Z

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  6. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15T23:59:59.000Z

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  7. ash utilization symposium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Center for By-Products Utilization USE OF CLASS F FLY ASH AND CLEAN-COAL ASH BLENDS FOR CAST Report No.CBU-1996-07 July 1996 Presented and Published at the...

  8. Eco-friendly fly ash utilization: potential for land application

    SciTech Connect (OSTI)

    Malik, A.; Thapliyal, A. [Indian Institute of Technology Delhi, New Delhi (India)

    2009-07-01T23:59:59.000Z

    The increase in demand for power in domestic, agricultural, and industrial sectors has increased the pressure on coal combustion and aggravated the problem of fly ash generation/disposal. Consequently the research targeting effective utilization of fly ash has also gained momentum. Fly ash has proved to be an economical substitute for expensive adsorbents as well as a suitable raw material for brick manufacturing, zeolite synthesis, etc. Fly ash is a reservoir of essential minerals but is deficient in nitrogen and phosphorus. By amending fly ash with soil and/or various organic materials (sewage sludge, bioprocess materials) as well as microbial inoculants like mycorrhizae, enhanced plant growth can be realized. Based on the sound results of large scale studies, fly ash utilization has grown into prominent discipline supported by various internationally renowned organizations. This paper reviews attempts directed toward various utilization of fly ash, with an emphasis on land application of organic/microbial inoculants amended fly ash.

  9. ash solvent extraction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alessandro 2013-01-01 27 ASH PNEUMATIC TRANSPORT UNDER ELECTROFILTERS OF UNIT 5 THERMAL POWER PLANT TUZLA CiteSeer Summary: Ash pneumatic transport is basic on fact that at...

  10. An investigation of the use of lime as a soil additive to modify the detrimental effects of frost action 

    E-Print Network [OSTI]

    Earnest, Clyde Talley

    1959-01-01T23:59:59.000Z

    OF LITERATURE Lime Stabilisation . B, Frost Action . C, Lime as a Frost Modifying Soil Additive IIX PURPOSE AND SCOPE OF THIS WORK IV METHOD OF TESTING A. General B. Selection of Materials C, Preliminary Tests D. Sample Preparation . E. Test Procedure... with the addition of lime . Figure 5. General view of the equipment Figure 6. Samples with insulation ready for testing Figure 7 Base plate and water reservoir shaving heat ex- 55 change coil Figure 8. Bquipment used in the preparation of samples . Figure Q...

  11. 10Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less is more:culturingProtonAPRIL/MAY9Hydrate ModelingBBe(p,HeLiLi

  12. 2007 world of coal ash conference proceedings

    SciTech Connect (OSTI)

    NONE

    2007-07-01T23:59:59.000Z

    The theme of the conference was science, applications and sustainability. Papers are presented under the following topics: aggregates/geotechnology; agriculture; ash facility; management; CCT products; cement and concrete; chemistry and mineralogy; emerging technology; environmental; LOI/beneficiation/handling; mercury; mining and regulations and standards. The poster papers are included as well.

  13. Screening technology reduces ash in spiral circuits

    SciTech Connect (OSTI)

    Brodzik, P. [Derrick Corp., Buffalo, NY (United States)

    2007-05-15T23:59:59.000Z

    In 2006, the James River Coal Co. selected the Stack Sizer to remove the minus 100 mesh high ash clay fraction from the clean coal spiral product circuits at the McCoy-Elkhorn Bevins Branch prep plant and at the Blue Diamond Leatherwood prep plant in Kentucky. The Stack Sizer is a multi-deck, high-frequency vibrating screen capable of separations as fine as 75 microns when fitted with Derrick Corp.'s patented high open area urethane screen panels. Full-scale lab tests and more than 10 months of continuous production have confirmed that the Stack Sizer fitted with Derrick 100 micron urethane screen panels consistently produces a clean coal fraction that ranges from 8 to 10% ash. Currently, each five-deck Stack Sizer operating at the Bevins Branch and Leatherwood prep plants is producing approximately 33 tons per hour of clean coal containing about 9% ash. This represents a clean coal yield of about 75% and an ash reduction of about 11% from the feed slurry. 3 figs. 2 tabs.

  14. Zinc Fertilization Plus Liming to Reduce Cadmium Uptake by Romaine Lettuce on Cd-Mineralized Lockwood Soil

    E-Print Network [OSTI]

    Chaney, Rufus L; Green, Carrie E.; Ajwa, Husein A; Smith, Richard F

    2009-01-01T23:59:59.000Z

    Cd accumulation by lettuce from biosolids amended soils withmine waste contaminated or biosolids-amended soils with Cd:of a highly Cd enriched biosolids also found that liming

  15. Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants 

    E-Print Network [OSTI]

    Schwartz, M. H.

    1979-01-01T23:59:59.000Z

    pulverized coal-fired boiler equipment. These are: (1) coal cleaning to remove pyritic sulfur, (2) conventional wet, nonregenerable scrubbing with alkaline slurry and solution processes, and (3) dry processes which involve direct introduction of lime...

  16. Properties of concrete containing wood/coal fly ash mixtures

    SciTech Connect (OSTI)

    Boylan, D.M.; Larrimore, C.L.; Fouad, F.

    1999-07-01T23:59:59.000Z

    Utilities are increasingly interested in co-firing wood with coal in existing pulverized coal units. The co-firing technology is a means of developing a relatively low-cost renewable energy resource, as well as of supporting customers and community by making energy with biomass that might otherwise have been land-filled. However, recent changes in the ASTM C618 standard for fly ash as cement replacement restrict the definition of fly ash that includes non-coal sources. As a result, wood co-firing could affect the market for the fly ash, reducing ash sales revenue, increasing ash disposal costs, and overall substantially increasing the cost of the co-firing technology. In order to address concerns about the effect of wood ash/coal ash mixtures on concrete properties, a study was conducted by University of Alabama at Birmingham, Southern Company, EPRI, and the State of Alabama. This study compared the effects on properties of concrete made with fly ash from coal and made with fly ash from co-firing up to 30% wood with coal. Fly ashes from three plants were used, with two of the ashes from actual co-firing experience and the third an artificial blend of wood and coal ash. Concrete test cylinders were made of several cement/fly ash mixes, and enough were made to allow testing periodically over a one year time period. Test measurements included workability, setting time, air content, compressive and flexural strength, rapid chloride permeability and freeze thaw. It was concluded on the basis of these tests that the wood ash content had no detrimental effect on the plastic and hardened properties of the concrete.

  17. Liming effects on slash pine (Pinus elliottii Englm.) seedlings growing on acid soils

    E-Print Network [OSTI]

    Elzner, John Thomas

    1978-01-01T23:59:59.000Z

    Growth Liming CHAPTER III. NETHODS Experimental Design Soil Treatments Greenhouse Care Laboratory Analysis Statistical Analysis . CHAPTER IV. RESULTS . Soils Exchangeable Aluminum Extractable Aluminum Exchangeable Acidity pH Calcium Page 1... growth; and under very acid conditions, phosphorus may be tied up with soluble aluminum (Shoulders and McKee, 1973). Solubility of aluminum is strongly influenced by pH and may interfere with the uptake of phosphorus and subsequent growth of southern...

  18. The Relation of Lime and Phosphoric Acid to the Growth and Bone Development of White Rats.

    E-Print Network [OSTI]

    Blum, J. K. (Joseph Kelly)

    1931-01-01T23:59:59.000Z

    LIBRARY, A & M COLLEGE. CAMPUS. TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR College Station, Brazos County, Texas BULLETIN NO. 441 DECEMBER, 1931 DIVISION OF CHEMISTRY The Relation of Lime and Phosphoric Acid to the Growth... and Bone Development of White Rats 2 ., .t .I* .-. /.' AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS--. .. T. 0. WALTON, President ..- STATION STAFF+ ADMINISTRATION: VETERINARY SCIENCE: A B. CONNER M S. Director *M. FRANCIS, D. V. M., Chief. R: E...

  19. The ultra-high lime with aluminum process for removing chloride from recirculating cooling water

    E-Print Network [OSTI]

    Abdel-wahab, Ahmed Ibraheem Ali

    2004-09-30T23:59:59.000Z

    THE ULTRA-HIGH LIME WITH ALUMINUM PROCESS FOR REMOVING CHLORIDE FROM RECIRCULATING COOLING WATER A Dissertation by AHMED IBRAHEEM ALI ABDEL-WAHAB Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...-WAHAB Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved as to style and content by: Bill Batchelor (Chair of Committee) Robin L. Autenrieth (Member...

  20. Water quality investigation of Kingston Fossil Plant dry ash stacking

    SciTech Connect (OSTI)

    Bohac, C.E.

    1990-04-01T23:59:59.000Z

    Changing to a dry ash disposal systems at Kingston Fossil Plant (KFP) raises several water quality issues. The first is that removing the fly ash from the ash pond could alter the characteristics of the ash pond discharge to the river. The second concerns proper disposal of the runoff and possibly leachate from the dry ash stack. The third is that dry ash stacking might change the potential for groundwater contamination at the KFP. This report addresses each of these issues. The effects on the ash pond and its discharge are described first. The report is intended to provide reference material to TVA staff in preparation of environmental review documents for new ash disposal areas at Kingston. Although the investigation was directed toward analysis of dry stacking, considerations for other disposal options are also discussed. This report was reviewed in draft form under the title Assessment of Kingston Fossil Plant Dry Ash Stacking on the Ash Pond and Groundwater Quality.'' 11 refs., 3 figs., 18 tabs.

  1. Manufacture of ceramic tiles from fly ash

    DOE Patents [OSTI]

    Hnat, James G. (Collegeville, PA); Mathur, Akshay (Tampa, FL); Simpson, James C. (Perkiomenville, PA)

    1999-01-01T23:59:59.000Z

    The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants.

  2. Manufacture of ceramic tiles from fly ash

    DOE Patents [OSTI]

    Hnat, J.G.; Mathur, A.; Simpson, J.C.

    1999-08-10T23:59:59.000Z

    The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants. 6 figs.

  3. Market assessment of PFBC ash use

    SciTech Connect (OSTI)

    Bland, A. E.; Brown, T. H., Western Research Institute

    1998-01-01T23:59:59.000Z

    Pressurized fluidized bed combustion (PFBC) of coal is undergoing demonstration in the United States, as well as throughout the world. American Electric Power`s (AEP`s) bubbling PFBC 70 MWe Tidd demonstration program in Ohio and pilot-scale development at Foster Wheeler Energia Oy 10 MWth circulating PFBC at Karhula, Finland, have demonstrated the advantages of PFBC technology. Further technology development in the US is planned with the deployment of the technology at the MacIntosh Clean Coal project in Lakeland, Florida. Development of uses for solid wastes from PFBC coal-fired power systems is being actively pursued as part of the demonstration of PFBC technologies. Ashes collected from Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, operating on (1) low sulfur subbituminous and (2) high sulfur bituminous coal; and ash from the AEP`s high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at Western Research Institute (WRI).

  4. Coal ash by-product reutilization

    SciTech Connect (OSTI)

    Muncy, J. [Potomac Electric Power Co., Washington, DC (United States); Miller, B. [DYNA Corp., Upper Marlboro, MD (United States)

    1997-09-01T23:59:59.000Z

    Potomac Electric Power Company (PEPCO) has as part of its vision and value statement that, ``We are responsible stewards of environmental and corporate resources.`` With this moral imperative in mind, a project team was charged with initiating the Coal Pile Liner Project--installing a membrane liner under the existing coal storage pile at the Morgantown Generating Station. The existing coal yard facilities were constructed prior to the current environmental regulations, and it became necessary to upgrade the storage facilities to be environmentally friendly. The project team had two objectives in this project: (1) prevent coal pile leachate from entering the groundwater system; (2) test the viability of using coal ash by-products as an aggregate substitute for concrete applications. Both objectives were met, and two additional benefits were achieved as well: (1) the use of coal ash by-products as a coal liner produced significant cost savings to the project directly; (2) the use of coal ash by-products reduced plant operation and maintenance expenses.

  5. SINGLE ELEMENT TEST PREDICTIONS FOR STRESS-STRAIN BEHAVIOR OF PANKI FLY-ASH

    E-Print Network [OSTI]

    Prashant, Amit

    : Fly-ash is a waste product produced by burning of coal at thermal power plants. It is often used. Introduction Fly-ash is a fine powdery material, produced by burning of coal at thermal power plants. Fly-ash need to dispose fly-ash from these ponds. Fly-ash is often used as structural fill in order to dispose

  6. A New Vision for High-Capacity Hybrid Li-ion/Li-O2 Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduces A New Vision for High-Capacity Hybrid Li-ionLi-O2 Batteries Diagram illustrating the CEES all-in-one vision for a high-capacity Li-ionLi-O2 cell. Illustration of CEES'...

  7. Mercury capture by distinct fly ash carbon forms

    SciTech Connect (OSTI)

    Hower, J.C.; Maroto-Valer, M.M.; Taulbee, D.N.; Sakulpitakphon, T.

    1999-07-01T23:59:59.000Z

    Carbon was separated from the fly ash from a Kentucky power plant using density gradient centrifugation. Using a lithium heterolpolytungstate high-density media, relative concentrations of inertinite (up to 85% vol.), isotropic carbon (up to 79% vol.), and anisotropic carbon (up to 76% vol.) were isolated from the original fly ash. Mercury concentration was lowest in the parent fly ash (which contains non-carbon components); followed by inertinite, isotropic coke, mixed isotropic-anisotropic coke fraction, and, with the highest concentration, the anisotropic coke concentrate. The latter order corresponds to the increase in BET surface area of the fly ash carbons. Previous studies have demonstrated the capture of mercury by fly ash carbon. This study confirms prior work demonstrating the varying role of carbon types in the capture, implying that variability in the carbon content influences the amount of mercury retained on the fly ash.

  8. Determination of Ash in Biomass: Laboratory Analytical Procedure...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ash in Biomass Laboratory Analytical Procedure (LAP) Issue Date: 7172005 A. Sluiter, B. Hames, R. Ruiz, C. Scarlata, J. Sluiter, and D. Templeton Technical Report NREL...

  9. Kinetics of beneficiated fly ash by carbon burnout

    SciTech Connect (OSTI)

    Okoh, J.M.; Dodoo, J.N.D.; Diaz, A. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States). Dept. of Natural Sciences; Ferguson, W.; Udinskey, J.R. Jr.; Christiana, G.A. [Delmarva Power, Wilmington, DE (United States)

    1997-12-31T23:59:59.000Z

    The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called Loss On Ignition (LOI). The concrete producers` day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

  10. ash transportation distance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ash 1. Halima Hadiahmetovi?; D. D. Sarajevo; M. Sc; Raza Sunulahpai?; Bosnia Herzegovina 4 Dimensional contraction via Markov transportation distance Francois...

  11. Data Summary Report for Hanford Site Coal Ash Characterization

    SciTech Connect (OSTI)

    Sulloway, H. M.

    2012-03-06T23:59:59.000Z

    The purpose of this report is to present data and findings from sampling and analysis of five distinct areas of coal ash within the Hanford Site River Corridor

  12. ash aqueous carbonation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon content, specific surface area Aydilek, Ahmet 3 Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1* Environmental Management and Restoration Websites...

  13. alkaline coal ash: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  14. Detailed Characterization of Lubricant-Derived Ash-Related Species...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Species in the Ring Pack and Ash Emissions and Their Dependence on Crankcase Oil Properties Key Parameters Affecting DPF Performance Degradation and Impact on Lifetime Fuel Economy...

  15. The variability of fly ash and its effects on selected properties of fresh Portland cement/fly ash mortars

    E-Print Network [OSTI]

    McKerall, William Carlton

    1980-01-01T23:59:59.000Z

    the needed quality control of concrete . Another source of concern results from the recent development of lignite and sub-bituminous coal as fuel sources. The ash produced from these coals is of a different chemical composition than traditional bituminous... 50 percent to greater than 200 percent of a control test. An exhaustive literature review has revealed neglig1ble information concerning the PAI of sub- b1tuminous and lignite ashes. Research is greatly needed to determine the ash properties...

  16. Arsenic remediation of drinking water using iron-oxide coated coal bottom ash

    E-Print Network [OSTI]

    MATHIEU, JOHANNA L.

    2010-01-01T23:59:59.000Z

    using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwater using  iron?oxide coated coal bottom ash  Johanna L.  using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

  17. E-Print Network 3.0 - ash related problems Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ash related problems Page: << < 1 2 3 4 5 > >> 1 By-Products Utilization Summary: of clean coal ash will increase. Finding practical solutions to this "ash problem" is essential...

  18. Utilization of Ash Fractions from Alternative Biofuels used in Power Plants

    E-Print Network [OSTI]

    Utilization of Ash Fractions from Alternative Biofuels used in Power Plants PSO Project No. 6356 July 2008 Renewable Energy and Transport #12;2 Utilization of Ash Fractions from Alternative Biofuels)...............................................................................7 2. Production of Ash Products from Mixed Biofuels

  19. Cell Ashing for Trace Element Analysis: A New Approach Based on Ultraviolet/Ozone

    E-Print Network [OSTI]

    Gilbert, Pupa Gelsomina De Stasio

    : synchrotron spectromicroscopy; micro- chemical analysis; MEPHISTO; ashing; incineration; trace element. Ashing ashing is based on high-temperature incineration or on the exposure to oxygen plasma (1­ 4). We adopted

  20. Li4SiO4-Li3PO4 system as protective layer in Li-metal batteries

    E-Print Network [OSTI]

    Zhang, Liying

    2012-01-01T23:59:59.000Z

    protective layer in Li-metal batteries Liying Zhang 1 , LeiThe application of Li-metal batteries is plagued with issues

  1. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    E-Print Network [OSTI]

    Jaiswal, A.

    2010-01-01T23:59:59.000Z

    12 for High Rate Li-ion Batteries A. Jaiswal 1 , C. R. Hornenext generation of Li-ion batteries for consumer electronics

  2. 6Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . S . D E 25Heα, X)Li

  3. 6Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . S . D E 25Heα, X)Li

  4. 8Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHe GeneralLi

  5. 8Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHe GeneralLi

  6. 9Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHeBBeLi General

  7. 9Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHeBBeLi General

  8. C LI CI

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -KWatertown Arsenal'.I Y.itBurrisIllLI CI -

  9. A cement kiln flue-dust evaluated as a soil liming material

    E-Print Network [OSTI]

    Stacha, Raimund

    1973-01-01T23:59:59.000Z

    A CEMENT KILN FLUE-DUST EVALUATED AS A SOIl LIMING MATERIAL A Thesis by RAIMUND STACHA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE 1973 NJSbj t...:~StlCh tt A CEMENT KILN FLUE-DUST EVALUATED AS A SOIL I IMING MATERIAL A Thesis by RAIMUND STACHA Approved as to style and content by: (Chairman of Committee) (Head of Department) (Me er) (Member) (Member) (Member) (Member) 1973 ABSTRACT A...

  10. A study of the durability of lime as a stabilizing agent of clay soils 

    E-Print Network [OSTI]

    Wise, Harvey Earl

    1958-01-01T23:59:59.000Z

    tested for their strength in a triaxLal testing 4ovioe, using lateral pressures of ths same order as those used bp the Texas Highwgr Seysrtsmnt (15), Thop mare tested for their Atterberg limits to asoertain if thep nero still ha- flienoad bp the lime... of thks factor Fox ths first ssi3. , tho yexeentagaxof kins used moxa too~ four& sirv eight, and ten, For the second soils the percentages vere tao, ~ and ton It uas shomn l8 the test of the first eamyle that the same information could be obtaLnek RF...

  11. The Relation of Lime and Phosphoric Acid to the Growth and Bone Development of White Rats. 

    E-Print Network [OSTI]

    Blum, J. K. (Joseph Kelly)

    1931-01-01T23:59:59.000Z

    LIBRARY, A & M COLLEGE. CAMPUS. TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR College Station, Brazos County, Texas BULLETIN NO. 441 DECEMBER, 1931 DIVISION OF CHEMISTRY The Relation of Lime and Phosphoric Acid to the Growth... SULLIVXN, 'As.hsfant Chief E. B. REYNOLDS, Ph. D., Chief S. D. PEARCE, Secretary R. E KARPER M S. Agronomist J. H. ROGERS Feed Inspector P. C: MANGE~SD~RF,'SC. D., Agrqnomist K. L. KIRKLAND, B. S., Feed Inspector I D T KILLOUGH M. S. Agronomzst S. D...

  12. Effects of the maximum soil aggregates size and cyclic wetting-drying on the stiffness of a lime-treated clayey soil

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Effects of the maximum soil aggregates size and cyclic wetting-drying on the stiffness of a lime-treated clayey soil Anh Minh TANG, BEng, PhD; Minh Ngoc VU, BEng; Yu-Jun CUI, BEng, PhD Ecole des Ponts Paris soils used for embankment. Several studies show that lime treatment significantly modifies the physical

  13. ICSE6 Paris -August 27-31, 2012 Herrier, Berger, Bonelli The Friant-Kern canal : a forgotten example of lime-treated structure

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    : a forgotten example of lime-treated structure in hydraulic conditions Gontran HERRIER1 , Eric BERGER2 in the paper. The treated clay was replaced and compacted by a sheep- foot roller, to achieve a typical in the 70's . Despite the fact that the lime-treated soil has been in constant direct contact

  14. Physico-chemical modifications of the interactions between hemp fibres and a lime mineral matrix: impacts on mechanical properties of mortars

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Physico-chemical modifications of the interactions between hemp fibres and a lime mineral matrix interactions between hemp fibres and a lime-based mineral matrix, the consequences of various chemical treatments onto hemp fibres characteristics were measured using scanning electron microscopy, thermal

  15. E-Print Network 3.0 - ash quarterly technical Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

  16. E-Print Network 3.0 - ash based geopolymer Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Summary: . CHARACTERIZATION AND APPLICATION OF CLASS F FLY ASH AND CLEAN-COAL ASH FOR CEMENT-BASED MATERIALS 2 The major... large amounts of conventional or...

  17. E-Print Network 3.0 - ash Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

  18. E-Print Network 3.0 - ash penurunan kadar Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

  19. E-Print Network 3.0 - ash paving demonstration Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AND DEMONSTRATION... Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

  20. E-Print Network 3.0 - ashes Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

  1. E-Print Network 3.0 - ash ahto lobjakas Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

  2. E-Print Network 3.0 - ash based gepolymer Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utilization Summary: . CHARACTERIZATION AND APPLICATION OF CLASS F FLY ASH AND CLEAN-COAL ASH FOR CEMENT-BASED MATERIALS 2 The major... large amounts of conventional or...

  3. IN HARM'S WAY: Lack Of Federal Coal Ash

    E-Print Network [OSTI]

    Short, Daniel

    IN HARM'S WAY: Lack Of Federal Coal Ash Regulations Endangers Americans And Their Environment 2010 Thirty-nine New Damage Cases of Contamination from Improperly Disposed Coal Combustion Waste, Editor and Contributing Author #12;IN HARM'S WAY: Lack of Federal Coal Ash Regulations Endangers

  4. Biological impact studies of the Faulkner ash site

    SciTech Connect (OSTI)

    Klose, P.N.; Potera, G.T.

    1984-08-01T23:59:59.000Z

    The Potomac Electric Power Company (PEPCO) has operated the Faulkner coal ash storage facility in southern Charles County, Maryland since 1970. This site handles all the coal ash produced at the nearby Morgantown Generating Stations. Environmental Resources Management, Inc. (ERM) produced an earlier report (Simek, et al., 1983) for PPSP entitled, Environmental Aspects of the Faulkner Ash Site. That report presented a compilation of existing data and newly-generated field information on the ash site and its influence on the local environment. Several questions remained as a result of the analyses carried out for the above study. These were: (a) Are trees downgradient of the site accumulating metals associated with the ash. (b) Is Zekiah Swamp Run being affected by dissolved or precipitated metals. (c) Are invertebrates in Zekiah Swamp Run accumulating metals from the ash site. The studies described herein present data on each of the three questions. Results indicate that no adverse effects on water quality, invertebrates, or trees are occurring. Elevated levels of aluminum, cadmium, and manganese were found throughout the watershed, both above and below the ash site, but no relationship to the ash site could be established.

  5. Recovery of Li from alloys of Al- Li and Li- Al using engineered scavenger compounds

    DOE Patents [OSTI]

    Riley, W. D. (Albany, OR); Jong, B. W. (Corvallis, OR); Collins, W. K. (Albany, OR); Gerdemann, S. J. (Albany, OR)

    1994-01-01T23:59:59.000Z

    A method of producing lithium of high purity from lithium aluminum alloys using an engineered scavenger compound, comprising: I) preparing an engineered scavenger compound by: a) mixing and heating compounds of TiO2 and Li2CO3 at a temperature sufficient to dry the compounds and convert Li.sub.2 CO.sub.3 to Li.sub.2 O; and b) mixing and heating the compounds at a temperature sufficient to produce a scavenger Li.sub.2 O.3TiO.sub.2 compound; II) loading the scavenger into one of two electrode baskets in a three electrode cell reactor and placing an Al-Li alloy in a second electrode basket of the three electrode cell reactor; III) heating the cell to a temperature sufficient to enable a mixture of KCl-LiCl contained in a crucible in the cell to reach its melting point and become a molten bath; IV) immersing the baskets in the bath until an electrical connection is made between the baskets to charge the scavenger compound with Li until there is an initial current and voltage followed by a fall off ending current and voltage; and V) making a connection between the basket electrode containing engineered scavenger compound and a steel rod electrode disposed between the basket electrodes and applying a current to cause Li to leave the scavenger compound and become electrodeposited on the steel rod electrode.

  6. LimeSurvey -Crdit mobilit pour le PATGS http://survey2.ulb.ac.be/limesurvey/admin/admin.php?action=showprintablesurvey&sid=35186[4/10/2013 14:30:04

    E-Print Network [OSTI]

    Cerf, Nicolas

    TEMPLATE Département Enseignement #12;LimeSurvey - Crédit mobilité pour le PATGS http://survey2.ulb dépenses prévues Informations sur le séjour TEMPLATE #12;LimeSurvey - Crédit mobilité pour le PATGS http://survey réponse ici : TEMPLATE #12;LimeSurvey - Crédit mobilité pour le PATGS http://survey2.ulb

  7. Analysis of volatile contaminants in US Navy fleet soda lime. Technical report, August 1992-May 1995

    SciTech Connect (OSTI)

    Lillo, R.S.; Ruby, R.; Gummin, D.D.; Porter, W.R.; Caldwell, J.M.

    1995-06-01T23:59:59.000Z

    Contamination was suspected of U.S. Navy Fleet soda lime (High Performance Sodasorb(R)) when an ammonia-like odor was reported during its use in August 1992. This material contained indicator dye and was used for carbon dioxide absorption during diving. This incident had a major impact on the U.S Navy diving program when the Navy temporarily banned use of Sodasorb(R) and authorized Sofnolime(R) as an interim replacement. The Naval Medical Research Institute was immediately assigned to investigate. Testing involved sampling from the headspace (gas space) inside closed buckets and from an apparatus simulating conditions during operational diving. Volatile organic compounds were analyzed by gas chromatography and mass spectrometry; ammonia and amines were measured by infrared spectroscopy. Significant amounts of ammonia (up to 30 ppm), ethyl and diethyl amines (up to several ppm), and various aliphatic hydrocarbons (up to 60 ppm) were detected during testing of both Sodasorb(R) and Sofnolime(R). Contaminants were slowly removed by gas flow and did not return. The source(s) of the ammonia and amines are unknown, although they may result from the breakdown of the indicator dye. Hydrocarbon contamination appeared to result from the materials of which the bucket is constructed. Based on these findings, the U.S. Navy is expected to phase in non-indicating soda lime that will be required to meet defined contaminant limits.

  8. STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH

    SciTech Connect (OSTI)

    Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

    2003-05-20T23:59:59.000Z

    The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

  9. STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH

    SciTech Connect (OSTI)

    Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

    2002-09-10T23:59:59.000Z

    The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

  10. State Waste Discharge Permit application: 200-E Powerhouse Ash Pit

    SciTech Connect (OSTI)

    Atencio, B.P.

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department and Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-E Powerhouse Ash Pit. The 200-E Powerhouse Ash Waste Water discharges to the 200-E Powerhouse Ash Pit via dedicated pipelines. The 200-E Ash Waste Water is the only discharge to the 200-E Powerhouse Ash Pit. The 200-E Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

  11. State Waste Discharge Permit application: 200-W Powerhouse Ash Pit

    SciTech Connect (OSTI)

    Atencio, B.P.

    1994-06-01T23:59:59.000Z

    As part of the Hanford Federal Facility Agreement and Consent Order negotiations; the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-W Powerhouse Ash Pit. The 200-W Powerhouse Ash Waste Water discharges to the 200-W Powerhouse Ash Pit via dedicated pipelines. The 200-W Powerhouse Ash Waste Water is the only discharge to the 200-W Powerhouse Ash Pit. The 200-W Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

  12. COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

    2001-04-01T23:59:59.000Z

    The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

  13. Fluidization characteristics of power-plant fly ashes and fly ash-charcoal mixtures. [MS Thesis; 40 references

    SciTech Connect (OSTI)

    Nguyen, C.T.

    1980-03-01T23:59:59.000Z

    As a part of the continuing research on aluminum recovery from fly ash by HiChlor process, a plexiglass fluidization column system was constructed for measurement of fluidization parameters for power-plant fly ashes and fly ash-charcoal mixtures. Several bituminous and subbituminous coal fly ashes were tested and large differences in fluidization characteristics were observed. Fly ashes which were mechanically collected fluidized uniformly at low gas flow rates. Most fly ashes which were electrostatically precipitated exhibited channeling tendency and did not fluidize uniformly. Fluidization characteristics of electrostatically collected ashes improve when the finely divided charcoal powder is added to the mixture. The fluidization of the mixture was aided initially by a mechanical stirrer. Once the fluidization had succeeded, the beds were ready to fluidize without the assistance of a mechanical action. Smooth fluidization and large bed expansion were usually observed. The effects of charcoal size and aspect ratio on fluidization characteristics of the mixtures were also investigated. Fluidization characteristics of a fly ash-coal mixture were tested. The mixture fluidized only after being oven-dried for a few days.

  14. Toxicity mitigation and solidification of municipal solid waste incinerator fly ash using alkaline activated coal ash

    SciTech Connect (OSTI)

    Ivan Diaz-Loya, E. [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Allouche, Erez N., E-mail: allouche@latech.edu [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Eklund, Sven; Joshi, Anupam R. [Department of Chemistry, Louisiana Tech University, Ruston, LA 71272 (United States); Kupwade-Patil, Kunal [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States)

    2012-08-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Incinerator fly ash (IFA) is added to an alkali activated coal fly ash (CFA) matrix. Black-Right-Pointing-Pointer Means of stabilizing the incinerator ash for use in construction applications. Black-Right-Pointing-Pointer Concrete made from IFA, CFA and IFA-CFA mixes was chemically characterized. Black-Right-Pointing-Pointer Environmentally friendly solution to IFA disposal by reducing its toxicity levels. - Abstract: Municipal solid waste (MSW) incineration is a common and effective practice to reduce the volume of solid waste in urban areas. However, the byproduct of this process is a fly ash (IFA), which contains large quantities of toxic contaminants. The purpose of this research study was to analyze the chemical, physical and mechanical behaviors resulting from the gradual introduction of IFA to an alkaline activated coal fly ash (CFA) matrix, as a mean of stabilizing the incinerator ash for use in industrial construction applications, where human exposure potential is limited. IFA and CFA were analyzed via X-ray fluorescence (XRF), X-ray diffraction (XRD) and Inductive coupled plasma (ICP) to obtain a full chemical analysis of the samples, its crystallographic characteristics and a detailed count of the eight heavy metals contemplated in US Title 40 of the Code of Federal Regulations (40 CFR). The particle size distribution of IFA and CFA was also recorded. EPA's Toxicity Characteristic Leaching Procedure (TCLP) was followed to monitor the leachability of the contaminants before and after the activation. Also images obtained via Scanning Electron Microscopy (SEM), before and after the activation, are presented. Concrete made from IFA, CFA and IFA-CFA mixes was subjected to a full mechanical characterization; tests include compressive strength, flexural strength, elastic modulus, Poisson's ratio and setting time. The leachable heavy metal contents (except for Se) were below the maximum allowable limits and in many cases even below the reporting limit. The leachable Chromium was reduced from 0.153 down to 0.0045 mg/L, Arsenic from 0.256 down to 0.132 mg/L, Selenium from 1.05 down to 0.29 mg/L, Silver from 0.011 down to .001 mg/L, Barium from 2.06 down to 0.314 mg/L and Mercury from 0.007 down to 0.001 mg/L. Although the leachable Cd exhibited an increase from 0.49 up to 0.805 mg/L and Pd from 0.002 up to 0.029 mg/L, these were well below the maximum limits of 1.00 and 5.00 mg/L, respectively.

  15. Evaluation of Vitrification Processing Step for Rocky Flats Incinerator Ash

    SciTech Connect (OSTI)

    Wigent, W.L.; Luey, J.K.; Scheele, R.D.; Li, H.

    1999-04-08T23:59:59.000Z

    In 1997, Pacific Northwest National Laboratory (PNNL) staff developed a processing option for incinerator ash at the Rocky Flats Environmental Technology Sites (RFETS). This work was performed with support from Los Alamos National Laboratory (LANL) and Safe Sites of Colorado (SSOC). A description of the remediation needs for the RFETS incinerator ash is provided in a report summarizing the recommended processing option for treatment of the ash (Lucy et al. 1998). The recommended process flowsheet involves a calcination pretreatment step to remove carbonaceous material followed by a vitrification processing step for a mixture of glass tit and calcined incinerator ash. Using the calcination pretreatment step to remove carbonaceous material reduced process upsets for the vitrification step, allowed for increased waste loading in the final product, and improved the quality of the final product. Figure 1.1 illustrates the flow sheet for the recommended processing option for treatment of RFETS incinerator ash. In 1998, work at PNNL further developed the recommended flow sheet through a series of studies to better define the vitrification operating parameters and to address secondary processing issues (such as characterizing the offgas species from the calcination process). Because a prototypical rotary calciner was not available for use, studies to evaluate the offgas from the calcination process were performed using a benchtop rotary calciner and laboratory-scale equipment (Lucy et al. 1998). This report focuses on the vitrification process step after ash has been calcined. Testing with full-scale containers was performed using ash surrogates and a muffle furnace similar to that planned for use at RFETS. Small-scale testing was performed using plutonium-bearing incinerator ash to verify performance of the waste form. Ash was not obtained from RFETS because of transportation requirements to calcine the incinerator ash prior to shipment of the material. Because part of PNNL's work was to characterize the ash prior to calcination and to investigate the effect of calcination on product quality, representative material was obtained from LANL. Ash obtained from LANL was selected based on its similarity to that currently stored at RFETS. The plutonium-bearing ashes obtained from LANL are likely from a RFETS incinerator, but the exact origin was not identified.

  16. Soil Acidity and Liming L. A. Redmon, M. L. McFarland, V. A. Haby, and D. H. Bade

    E-Print Network [OSTI]

    Soil Acidity and Liming L. A. Redmon, M. L. McFarland, V. A. Haby, and D. H. Bade Department of Soil and Crop Sciences The Agriculture Program The Texas A&M University System SCS-2001-06 What Causes SoilAcidity? Various environmental, climatic, and cultural factors can af- fect formation of acid soils

  17. Mutagenicity and genotoxicity of coal fly ash water leachate

    SciTech Connect (OSTI)

    Chakraborty, R.; Mukherjee, A. [University of Calcutta, Calcutta (India). Dept. of Botany

    2009-03-15T23:59:59.000Z

    Fly ash is a by-product of coal-fired electricity generation plants. The prevalent practice of disposal is as slurry of ash and water to storage or ash ponds located near power stations. This has lain to waste thousands of hectares of land all over the world. Since leaching is often the cause of off-site contamination and pathway of introduction into the human environment, a study on the genotoxic effects of fly ash leachate is essential. Leachate prepared from the fly ash sample was analyzed for metal content, and tested for mutagenicity and genotoxicity. Analyses of metals show predominance of the metals - sodium, silicon, potassium, calcium, magnesium, iron, manganese, zinc, and sulphate. The Ames Salmonella mutagenicity assay, a short-term bacterial reverse mutation assay, was conducted on two-tester strains of Salmonella typhimurium strains TA97a and TA102. For genotoxicity, the alkaline version of comet assay on fly ash leachate was carried in vitro on human blood cells and in vivo on Nicotiana plants. The leachate was directly mutagenic and induced significantconcentration-dependent increases in DNA damage in whole blood cells, lymphocytes, and in Nicotiana plants. The comet parameters show increases in tail DNA percentage (%), tail length (mu m), and olive tail moment (arbitrary units). Our results indicate that leachate from fly ash dumpsites has the genotoxic potential and may lead to adverse effects on vegetation and on the health of exposed human populations.

  18. Phenolic acids as bioindicators of fly ash deposit revegetation

    SciTech Connect (OSTI)

    L. Djurdjevic; M. Mitrovic; P. Pavlovic; G. Gajic; O. Kostic [Institute for Biological Research 'Sinisa Stankovic,' Belgrade (Serbia and Montenegro). Department of Ecology

    2006-05-15T23:59:59.000Z

    The floristic composition, the abundance, and the cover of pioneer plant species of spontaneously formed plant communities and the content of total phenolics and phenolic acids, as humus constituents, of an ash deposit after 7 years of recultivation were studied. The restoration of both the soil and the vegetation on the ash deposits of the 'Nikola Tesla-A' thermoelectric power plant in Obrenovac (Serbia) is an extremely slow process. Unfavorable physical and chemical characteristics, the toxicity of fly ash, and extreme microclimatic conditions prevented the development of compact plant cover. The abundance and cover of plants increased from the central part of the deposit towards its edges. Festuca rubra L., Crepis setosa Hall., Erigeron canadensis L., Cirsium arvense (L.) Scop., Calamagrostis epigeios (L.) Roth., and Tamarix gallica L. were the most abundant species, thus giving the highest cover. Humus generated during the decomposition process of plant remains represents a completely new product absent in the ash as the starting material. The amount of total phenolics and phenolic acids in fly ash increased from the center of the deposit towards its edges in correlation with the increase in plant abundance and cover. The presence of phenolic acids indicates the ongoing process of humus formation in the ash, in which the most abundant pioneer plants of spontaneously formed plant communities play the main role. Phenolic compounds can serve as reliable bioindicators in an assessment of the success of the recultivation process of thermoelectric power plants' ash deposits.

  19. Research Summary RECOAL: Reintegration of coal ash disposal sites and mitigation

    E-Print Network [OSTI]

    Research Summary RECOAL: Reintegration of coal ash disposal sites and mitigation of pollution being used for coal ash deposits. Pollutants present in the ash can contaminate water resources and soil its research on the thermo-electric plant (TEP) and associated coal ash sites at Tuzla, Bosnia

  20. Close Out Report for the Ash Pit Operable Unit I Area of Concern 2F

    E-Print Network [OSTI]

    I to the early 1950's. The Ash Pits were also used for disposal of coal ash from various buildingsFinal Close Out Report for the Ash Pit Operable Unit I Area of Concern 2F February 5, 2004..................................................................................................2 Figure 1 - Ash Level Verification Borings

  1. Helium Ash Simulation Studies with Divertor Helium Pumping in JET Internal Transport Barrier Discharges

    E-Print Network [OSTI]

    Helium Ash Simulation Studies with Divertor Helium Pumping in JET Internal Transport Barrier Discharges

  2. Dechlorination ability of municipal waste incineration fly ash for polychlorinated phenols

    E-Print Network [OSTI]

    Cirkva, Vladimir

    Dechlorination ability of municipal waste incineration fly ash for polychlorinated phenols Leona incineration fly ash at 200 °C under nitrogen atmosphere. Thermodynamic calculations have been carried out ash produced by municipal waste incineration (MWI) have clearly demonstrated that MWI fly ash can

  3. Respiratory and Reproductive Characteristics of Eastern Mosquitofish (Gambusia holbrooki) Inhabiting a Coal Ash Settling Basin

    E-Print Network [OSTI]

    Hopkins, William A.

    ) Inhabiting a Coal Ash Settling Basin B. P. Staub, W. A. Hopkins, J. Novak, J. D. Congdon Savannah River 2002/Accepted: 29 March 2002 Abstract. Coal fly ash and effluent from coal ash settling basins viable populations in areas contaminated by coal ash. While eastern mosquitofish are present

  4. Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI

    SciTech Connect (OSTI)

    McOwen, Dennis W.; Delp, Samuel A.; Paillard, Elie; Herriot, Cristelle; Han, Sang D.; Boyle, Paul D.; Sommer, Roger D.; Henderson, Wesley A.

    2014-04-17T23:59:59.000Z

    Lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA) and lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) are two salts proposed for lithium battery electrolyte applications, but little is known about the manner in which the DCTA- and TDI- anions coordinate Li+ cations. To explore this in-depth, crystal structures are reported here for two solvates with LiDCTA: (G2)1:LiDCTA and (G1)1:LiDCTA with diglyme and monoglyme, respectively, and seven solvates with LiTDI: (G1)2:LiTDI, (G2)2:LiTDI, (G3)1:LiTDI, (THF)1:LiTDI, (EC)1:LiTDI, (PC)1:LiTDI and (DMC)1/2:LiTDI with monoglyme, diglyme, triglyme, tetrahydrofuran, ethylene carbonate, propylene carbonate and dimethyl carbonate, respectively. These latter solvate structures are compared with the previously reported acetonitrile (AN)2:LiTDI structure. The solvates indicate that the LiTDI salt is much less associated than the LiDCTA salt and that the ions in LiTDI, when aggregated in solvates, have a very similar TDI-...Li+ cation mode of coordination through both the anion ring and cyano nitrogen atoms. Such coordination facilitates the formation of polymeric ion aggregates, instead of dimers. Insight into such ion speciation is instrumental for understanding the electrolyte properties of aprotic solvent mixtures with these salts.

  5. Recovery of iron oxide from coal fly ash

    DOE Patents [OSTI]

    Dobbins, Michael S. (Ames, IA); Murtha, Marlyn J. (Ames, IA)

    1983-05-31T23:59:59.000Z

    A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

  6. Making Li-air batteries rechargeable: material challenges. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li-air batteries rechargeable: material challenges. Making Li-air batteries rechargeable: material challenges. Abstract: A Li-air battery could potentially provide three to five...

  7. Determination of Total Solids and Ash in Algal Biomass: Laboratory...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solids and Ash in Algal Biomass Laboratory Analytical Procedure (LAP) Issue Date: December 2, 2013 S. Van Wychen and L. M. L. Laurens Technical Report NRELTP-5100-60956 December...

  8. ash impact sorbent: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of aircraft systems 1. Silicate parti- cles in the ash clouds can enter the engines and melt. In the past Oxford, University of First Page Previous Page 1 2 3 4 5 6 7 8...

  9. altered volcanic ash: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    near the volcano. Major eruptions are much rarer. They can eject both ash and gases like sulfur dioxide high into the atmosphere-- 80,000 feet or more. Although much of...

  10. ash upptag av: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1* Environmental Management and Restoration Websites...

  11. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

    1997-01-01T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

  12. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1997-04-29T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

  13. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

    1998-01-01T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

  14. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1998-12-29T23:59:59.000Z

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

  15. ash particle deposition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coal fly ash by reaction with nitrogen oxides can occur in the smokestack, but with the aging Dutta, Prabir K. 5 Particle deposition in ventilation ducts University of California...

  16. Guide to Using Wood Ash as an Agricultural Soil Amendment

    E-Print Network [OSTI]

    New Hampshire, University of

    from larger commercial sources such as wood-burning biomass plants which produce heat or electricity in the soil. Wood ash is more soluble and reactive than ground limestone, and brings about a Benefits Recycles

  17. Optical properties of fly ash. Volume 2, Final report

    SciTech Connect (OSTI)

    Self, S.A.

    1994-12-01T23:59:59.000Z

    Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executive summary of the whole program followed by the dissertation of Ghosal and Ebert. Volume 2 contains the dissertation of Ebert which covers the measurements of the optical constants of slags, and calculations of the radiant properties of fly ash dispersions. A list of publications and conference presentations resulting from the work is also included.

  18. ash cenospheres composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Composite Material Lab., Central Gupta, Nikhil 3 Journal of Composite Materials, July 2006, Vol. 40 no. 13, 1163-1174 1163 Thermal Expansion of AluminumFly Ash...

  19. Studies of fly ash using thermal analysis techniques

    SciTech Connect (OSTI)

    Li, Hanxu; Shen, Xiang-Zhong; Sisk, B. [Western Kentucky Univ., Bowling Green, KY (United States)

    1996-12-31T23:59:59.000Z

    Improved thermoanalytical methods have been developed that are capable of quantitative identification of various components of fly ash from a laboratory-scale fluidized bed combustion system. The thermogravimetric procedure developed can determine quantities of H{sub 2}O, Ca(OH){sub 2}, CaCO{sub 3}, CaSO{sub 4} and carbonaceous matter in fly ash with accuracy comparable to more time-consuming ASTM methods. This procedure is a modification of the Mikhail-Turcotte methods that can accurately analyze bed ash, with higher accuracy regarding the greater amount of carbonaceous matter in fly ash. In addition, in conjunction with FTIR and SEM/EDS analysis, the reduction mechanism of CaSO{sub 4} as CaSO{sub 4} + 4H{sub 2} = CaS + 4H{sub 2}O has been confirmed in this study. This mechanism is important in analyzing and evaluating sulfur capture in fluidized-bed combustion systems.

  20. ash leaching methods: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in individualpyrite grains in Illinois6 coal at levels up 6 coal. The same trace metals were detected in pyrite and clay grains from Pittsburgh 8 coal. Ash Laughlin,...

  1. ash technical progress: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ash from the four 43 Technical Brief CiteSeer Summary: ii iiiFOREWARD The Depleted Uranium Technical Brief is designed to convey available information and knowledge about...

  2. ash corrosion resistant: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    date: 02.2008 Start date of the consortium (including the Commission Services) 12;2 Handbook on treatment of coal ash disposal sites Preface 162 Nitration of Benzoapyrene...

  3. Recoverable immobilization of transuranic elements in sulfate ash

    DOE Patents [OSTI]

    Greenhalgh, Wilbur O. (Richland, WA)

    1985-01-01T23:59:59.000Z

    Disclosed is a method of reversibly immobilizing sulfate ash at least about 20% of which is sulfates of transuranic elements. The ash is mixed with a metal which can be aluminum, cerium, samarium, europium, or a mixture thereof, in amounts sufficient to form an alloy with the transuranic elements, plus an additional amount to reduce the transuranic element sulfates to elemental form. Also added to the ash is a fluxing agent in an amount sufficient to lower the percentage of the transuranic element sulfates to about 1% to about 10%. The mixture of the ash, metal, and fluxing agent is heated to a temperature sufficient to melt the fluxing agent and the metal. The mixture is then cooled and the alloy is separated from the remainder of the mixture.

  4. Environmental aspects of the faulkner ash site. Final report

    SciTech Connect (OSTI)

    Simek, E.M.; Hewitt, M.A.; Potera, G.T.

    1983-01-01T23:59:59.000Z

    The Potomac Electric Power Company (PEPCO) has owned and operated the Faulkner coal ash storage facility in southern Charles County, Maryland since 1970. This site was designed and is operated specifically to handle, in an environmentally sound manner, the large quantities of coal ash produced at the nearby Morgantown Generating Station. This report describes the site, its setting, and its interactions with the local environment.

  5. Ash level meter for a fixed-bed coal gasifier

    DOE Patents [OSTI]

    Fasching, George E. (Morgantown, WV)

    1984-01-01T23:59:59.000Z

    An ash level meter for a fixed-bed coal gasifier is provided which utilizes the known ash level temperature profile to monitor the ash bed level. A bed stirrer which travels up and down through the extent of the bed ash level is modified by installing thermocouples to measure the bed temperature as the stirrer travels through the stirring cycle. The temperature measurement signals are transmitted to an electronic signal process system by an FM/FM telemetry system. The processing system uses the temperature signals together with an analog stirrer position signal, taken from a position transducer disposed to measure the stirrer position to compute the vertical location of the ash zone upper boundary. The circuit determines the fraction of each total stirrer cycle time the stirrer-derived bed temperature is below a selected set point, multiplies this fraction by the average stirrer signal level, multiplies this result by an appropriate constant and adds another constant such that a 1 to 5 volt signal from the processor corresponds to a 0 to 30 inch span of the ash upper boundary level. Three individual counters in the processor store clock counts that are representative of: (1) the time the stirrer temperature is below the set point (500.degree. F.), (2) the time duration of the corresponding stirrer travel cycle, and (3) the corresponding average stirrer vertical position. The inputs to all three counters are disconnected during any period that the stirrer is stopped, eliminating corruption of the measurement by stirrer stoppage.

  6. STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH

    SciTech Connect (OSTI)

    Robert Hurt; Eric Suuberg; John Veranth

    2001-12-26T23:59:59.000Z

    The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; the effect of various low-NOx firing modes on ash properties and adsorptivity; and the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. This first project period, experiments were carried out to better understand the fundamental nature of the ozonation effect on ash. Carbon surfaces were characterized by surfactant adsorption, and by X-ray Photoelectron Spectroscopy before and after oxidation, both by air at 440 C and by ozone at room temperature. The results strongly suggest that the beneficial effect of ozonation is in large part due to chemical modification of the carbon surfaces.

  7. STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH

    SciTech Connect (OSTI)

    Robert Hurt; Eric Suuberg; John Veranth; Xu Chen; Indrek Kulaots

    2004-02-13T23:59:59.000Z

    The overall objective of the present project was to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific issues addressed included: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity based on pilot-plant studies; and (3) the kinetics and mechanism of ash ozonation. This laboratory data has provided scientific and engineering support and underpinning for parallel process development activities. The development work on the ash ozonation process has now transitioned into a scale-up and commercialization project involving a multi-industry team and scheduled to begin in 2004. This report describes and documents the laboratory and pilot-scale work in the above three areas done at Brown University and the University of Utah during this three-year project.

  8. Ash Reduction of Corn Stover by Mild Hydrothermal Preprocessing

    SciTech Connect (OSTI)

    M. Toufiq Reza; Rachel Emerson; M. Helal Uddin; Garold Gresham; Charles J. Coronella

    2014-04-22T23:59:59.000Z

    Lignocellulosic biomass such as corn stover can contain high ash content, which may act as an inhibitor in downstream conversion processes. Most of the structural ash in biomass is located in the cross-linked structure of lignin, which is mildly reactive in basic solutions. Four organic acids (formic, oxalic, tartaric, and citric) were evaluated for effectiveness in ash reduction, with limited success. Because of sodium citrate’s chelating and basic characteristics, it is effective in ash removal. More than 75 % of structural and 85 % of whole ash was removed from the biomass by treatment with 0.1 g of sodium citrate per gram of biomass at 130 °C and 2.7 bar. FTIR, fiber analysis, and chemical analyses show that cellulose and hemicellulose were unaffected by the treatment. ICP–AES showed that all inorganics measured were reduced within the biomass feedstock, except sodium due to the addition of Na through the treatment. Sodium citrate addition to the preconversion process of corn stover is an effective way to reduced physiological ash content of the feedstock without negatively impacting carbohydrate and lignin content.

  9. Mixed Salts of LiTFSI and LiBOB for Stable LiFePO4-Based Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in LiTFSI-based electrolytes effectively prevents the severe corrosion to Al current collectors that often is observed in LiTFSI-based electrolytes, which have high thermal...

  10. ReproducedfromJournalofEnvironmentalQuality.PublishedbyASA,CSSA,andSSSA.Allcopyrightsreserved. Ecosystem Function in Alluvial Tailings after Biosolids and Lime Addition

    E-Print Network [OSTI]

    Brown, Sally

    JournalofEnvironmentalQuality.PublishedbyASA,CSSA,andSSSA.Allcopyrightsreserved. Ecosystem Function in Alluvial Tailings after Biosolids and Lime Addition Sally Brown,* Mark Sprenger, this site requires an alternative assessment meth-Municipal biosolids and agricultural limestone were

  11. Investigation of the benefits of carbonate cementation due to addition of low percentage of hydrated lime in the base courses of pavements 

    E-Print Network [OSTI]

    Bhuiyan, Jasim Uddin

    1994-01-01T23:59:59.000Z

    Texas, limestone and caliche soil, were tested extensively to examine the effect of carbonate cementation due to the addition of small percentages of lime. Testing included mineralogical analysis of the two materials, strength analysis in terms of texas...

  12. Clay formation and metal fixation during weathering of coal fly ash

    SciTech Connect (OSTI)

    Zevenbergen, C.; Bradley, J.P.; Reeuwijk, L.P. Van; Shyam, A.K.; Hjelmar, O.; Comans, R.N.J.

    1999-10-01T23:59:59.000Z

    The enormous and worldwide production of coal fly ash cannot be durably isolated from the weathering cycle, and the weathering characteristics of fly ash must be known to understand the long-term environmental impact. The authors studied the weathering of two coal fly ashes and compared them with published data from weathered volcanic ash, it's closest natural analogue. Both types of ash contain abundant aluminosilicate glass, which alters to noncrystalline clay. However, this study reveals that the kinetics of coal fly ash weathering are more rapid than those of volcanic ash because the higher pH of fresh coal fly ash promotes rapid dissolution of the glass. After about 10 years of weathering, the noncrystalline clay content of coal fly ash is higher than that of 250-year-old volcanic ash. The observed rapid clay formation together with heavy metal fixation imply that the long-term environmental impact of coal fly ash disposal may be less severe and the benefits more pronounced than predicted from previous studies on unweathered ash. Their findings suggest that isolating coal fly ash from the weathering cycle may be counterproductive because, in the long-term under conditions of free drainage, fly ash is converted into fertile soil capable of supporting agriculture.

  13. Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries Hyunjung Lee an increase in the cut-off voltage of the cell from 4.2 V to 4.4 V (vs. graphite). As an alterna- tive, we can

  14. Li Tec | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |Jilin Zhongdiantou NewKoreaLaorLeopold Kostal GmbHLi County JiaxingLiLi

  15. Technical status report development of lime based in-duct scrubbing - A cost effective SO/sub 2/ control technology

    SciTech Connect (OSTI)

    Shilling, N.Z.; Samuel, E.A.; Pennline, H.

    1986-04-01T23:59:59.000Z

    Lime Based In-Duct Scrubbing (LIBIDS) was one of the candidate technologies receiving contract awards for pilot demonstration by the U.S. Department of Energy under the Acid Rain Precurser program. The concept as developed by General Electric utilizes rotary atomization of lime slurry directly within flue gas carrying ductwork to remove SO/sub 2/. This promises to be a very low capital cost method of SO/sub 2/ control with capital plus levelized operating cost estimated to be $364/KW. Several significant technical milestones have been passed relative to proof of principle and ultimate commercialization. Based on positive results from a laboratory and supporting analytical work, a detailed engineering design has begun for a pilot plant.

  16. Capacity Fade Studies of LiCoO2 Based Li-ion Cells Cycled at

    E-Print Network [OSTI]

    Popov, Branko N.

    in capacity of commercially available Sony 18650 Cells cycled at different temperatures. Perform rate of a Sony 18650 Li-ion cell Cathode (positive electrode) - LiCoO2. Anode (negative electrode) - MCMB. Cell capacity ­ 1.8 Ah #12;Characteristics of a Sony 18650 Li-ion cell Characteristics Positive LiCoO2 Negative

  17. Interactions and dynamics in Li+Li2 ultracold collisions Marko T. Cvitas,a

    E-Print Network [OSTI]

    Honvault, Pascal

    Interactions and dynamics in Li+Li2 ultracold collisions Marko T. Cvitas,a Pavel Soldán electronic state 4 A of lithium trimer is developed and used to study spin-polarized Li+Li2 collisions There is great interest in the properties of molecules formed in laser-cooled atomic gases by processes

  18. Facile synthesis of Li2Spolypyrrole composite structures for high-performance Li2S cathodes

    E-Print Network [OSTI]

    Cui, Yi

    Facile synthesis of Li2S­polypyrrole composite structures for high-performance Li2S cathodes Zhi demon- strate facile, in situ synthesis of Li2S­polypyrrole composites for use as high-performance Li2S polysulfides during cycling. Poly- pyrrole, being a conducting polymer, also helps to facilitate elec- tronic

  19. Metal recovery from fly ash generated from vitrification process for MSW ash

    SciTech Connect (OSTI)

    Izumikawa, Chiaki [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)] [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)

    1996-12-31T23:59:59.000Z

    Metal-bearing wastes have to be carefully treated because heavy metals could be leached out under uncontrolled conditions when disposed of in a landfill. Consequently, heavy metals should be principally recovered and recycled forever. From this standpoint, the author has been trying to develop a technology to recover heavy metals from toxic vitrification fly ash for recycling to smelters. After a number of laboratory-scale experiments, pilot plant tests were successfully carried out and the developed process has been proven to be commercially realized. The main features of the process are that it recovers almost 100% of the heavy metals, simultaneously separating the metals which are recovered in a lead smelter from those in a zinc smelter, and that the output of the process are only metallurgical products recyclable for smelters and the effluent water which can be released into the environment. The process is considered an ideal one for the treatment of toxic fly ash from the viewpoint of not only natural resources but also environmental conservation.

  20. Study on the Volatility of Cesium in Dry Ashing Pretreatment and Dissolution of Ash by Microwave Digestion System - 13331

    SciTech Connect (OSTI)

    Choi, Kwang-Soon; Lee, Chang Heon; Ahn, Hong-Joo; Park, Yong Joon; Song, Kyuseok [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)] [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

    2013-07-01T23:59:59.000Z

    Based on the regulation of the activity concentration of Cs-137, Co-58, Co-60, Fe-55, Ni-59, Ni-63, Sr-90, Nb-94, and Tc-99, and the total alpha from the radioactive waste acceptance criteria, the measurement of the activity concentration of these nuclides in low and intermediate levels of radioactive waste such as in paper, cotton, vinyl and plastic samples was investigated. A dry ashing method was applied to obtain a concentration effect of the samples. Owing to the temperature dependence of the volatility for cesium, the temperature of 300 to 650 deg. C was examined. It was found that 450 deg. C is the optimum dry ashing temperature. After dry ashing, the produced ash was dissolved with HNO{sub 3}, HCl, and HF by a high-performance microwave digestion system. The ash sample, for the most part, was completely dissolved with 10 mL of HNO{sub 3}, 4 mL of HCl, and 0.25 mL of HF by a high-performance microwave digestion system using a nova high temperature rotor at 250 deg. C for 90 min until reaching 0.2 g. To confirm the reliability of cesium loss after the performance of the dry ashing procedure, a cesium standard solution for AAS and a Cs-137 standard solution for gamma spectrometry were added to a paper towel or a planchet of stainless steel, respectively. Cesium was measured by AAS, ICP-MS, and gamma spectrometry. The volatility of cesium did not occur until 450 deg. C ashing. (authors)

  1. Release of Ammonium and Mercury from NOx Controlled Fly Ash

    SciTech Connect (OSTI)

    Schroeder, K.T.; Cardone, C.R.; Kim, A.G

    2007-07-01T23:59:59.000Z

    One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

  2. Ash bed level control system for a fixed-bed coal gasifier

    DOE Patents [OSTI]

    Fasching, George E. (Morgantown, WV); Rotunda, John R. (Fairmont, WV)

    1984-01-01T23:59:59.000Z

    An ash level control system is provided which incorporates an ash level meter to automatically control the ash bed level of a coal gasifier at a selected level. The ash level signal from the ash level meter is updated during each cycle that a bed stirrer travels up and down through the extent of the ash bed level. The ash level signal is derived from temperature measurements made by thermocouples carried by the stirrer as it passes through the ash bed and into the fire zone immediately above the ash bed. The level signal is compared with selected threshold level signal to determine if the ash level is above or below the selected level once each stirrer cycle. A first counter is either incremented or decremented accordingly. The registered count of the first counter is preset in a down counter once each cycle and the preset count is counted down at a selected clock rate. A grate drive is activated to rotate a grate assembly supporting the ash bed for a period equal to the count down period to maintain the selected ash bed level. In order to avoid grate binding, the controller provides a short base operating duration time each stirrer cycle. If the ash bed level drops below a selected low level or exceeds a selected high level, means are provided to notify the operator.

  3. Technology for the Recovery of Fuel and Adsorbent Carbons from Coal Burning Utility Ash Ponds and Landfills

    SciTech Connect (OSTI)

    J.G. Groppo; T.L. Robl

    2005-09-30T23:59:59.000Z

    Several sampling techniques were evaluated to recover representative core samples from the ash ponds at Western Kentucky Energy's Coleman Station. The most successful was a combination of continuous-flight augers and specially designed soft-sediment sampling tubes driven by a Hammerhead drill mounted on an amphibious ARGO vehicle. A total of 51 core samples were recovered and analyzed in 3 ft sections and it was determined that there are 1,354,974 tons of ash in Pond C. Of the over 1.35M tons of ash present, 14% or 190K tons can be considered as coarse (+100 mesh). Pond C contains approximately 88K tons of carbon, nearly half of which is coarse and potentially recoverable with spiral concentration while the fine carbon (-100 mesh) is recoverable with froth flotation. There are 1.27M tons of carbon-free ash, 12% of which is coarse and potentially usable as block sand. Spiral concentration testing on bulk samples showed that product grade of 30 to 38% C (4200 to 5500 Btu/lb) was obtainable. When this product was cleaned again in an additional stage of spiral concentration, the product grade was improved to 7200 to 8200 Btu/lb with an accompanying 13 to 29% decrease in yield. Release analysis of hydraulically classified pond ash showed that froth flotation could provide froth products with as high a grade as 9000 Btu/lb with a yield of 5%. Increasing yield to 10% reduced froth grade to 7000 Btu/lb. Batch flotation provided froth grades as high as 6500 Btu/lb with yields of 7% with 1.5 lb/ton SPP and 1 lb/ton frother. Column flotation test results were similar to those achieved in batch flotation in terms of both grade and yield, however, carbon recoveries were lower (<70%). High airflow rate was required to achieve >50% carbon recovery and using wash water improved froth grade. Bottom ash samples were recovered from each of the units at Coleman Station. Characterization confirmed that sufficient quantity and quality of material is generated to produce a marketable lightweight aggregate and recover a high-grade fuel product. Spiral concentration provided acceptable grade lightweight aggregate with yields of only 10 to 20%. Incorporating a sieve bend into the process to recover coarse, porous ash particles from the outside race of the spirals increased aggregate yield to as high as 75%, however, the carbon content of the aggregate also increased. An opening size of 28 mesh on the sieve bend appeared to be sufficient. Lightweight concrete blocks (28 to 32 lbs) were produced from bottom ash and results show that acceptable strength could be attained with a cement/concrete ratio as low as 1/4. A mobile Proof-of-Concept (POC) field unit was designed and fabricated to meet the processing objectives of the project. The POC plant consisted of two trailer-mounted modules and was completely self sufficient with respect to power and water requirements. The POC unit was hauled to Coleman Station and operated at a feed rate of 2 tph. Results showed that the spirals operated similarly to previous pilot-scale operations and a 500 lb composite sample of coarse carbon was collected with a grade of 51.7% C or 7279 Btu/lb. Flotation results compared favorably with release analysis and 500 lbs of composite froth product was collected with a grade of 35% C or 4925 Btu/lb. The froth product was dewatered to 39% moisture with vacuum filtration. Pan pelletization and briquetting were evaluated as a means of minimizing handling concerns. Rotary pan pelletization produced uniform pellets with a compressive strength of 4 lbf without the use of any binder. Briquettes were produced by blending the coarse and fine carbon products at a ratio of 1:10, which is the proportion that the two products would be produced in a commercial operation. Using 3% lime as a binder produced the most desirable briquettes with respect to strength, attrition and drop testing. Additionally, the POC carbon products compared favorably with commercial activated carbon when used for removal of mercury from simulated flue gas. A business model was generated to summarize anti

  4. Non-Destructive X-ray Measurement of Soot, Ash, Washcoat and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    X-ray Measurement of Soot, Ash, Washcoat and Regeneration Damage for DPFs Non-Destructive X-ray Measurement of Soot, Ash, Washcoat and Regeneration Damage for DPFs New commercially...

  5. Geotechnical properties of fly and bottom ash mixtures for use in highway embankments

    SciTech Connect (OSTI)

    Kim, B.; Prezzi, M.; Salgado, R. [Korean Institute for Water & Environment, Taejon (Republic of Korea). Dam Safety Research Center

    2005-07-01T23:59:59.000Z

    Class F fly ash and bottom ash are the solid residue byproducts produced by coal-burning electric utilities. They are usually disposed of together as a waste in utility disposal sites with a typical disposal rate of 80% fly ash and 20% bottom ash. Direct use of these materials in construction projects consuming large volumes of materials, such as highway embankment construction, not only provides a promising solution to the disposal problem, but also an economic alternative to the use of traditional materials. Representative samples of class F fly and bottom ash were collected from two utility power plants in Indiana and tested for their mechanical properties (compaction, permeability, strength, stiffness, and compressibility). Three mixtures of fly and bottom ash with different mixture ratios (i.e., 50, 75, and 100% fly ash content by weight) were prepared for testing. Test results indicated that ash mixtures compare favorably with conventional granular materials.

  6. E-Print Network 3.0 - ashing wet Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 4 By-Products Utilization Summary: A3, containing 20% clean coal ash and 5% wet collected Class F ash had compressive strengths... 0 Center for...

  7. E-Print Network 3.0 - ashing dry Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shrinkage of Non-Air Entrained HRWRA Concrete -0.05% 0.00% 0.05% 0... NS3, 33% Clean Coal Ash, 5% Class F Fly Ash Fig. 15 - ... Source: Wisconsin-Milwaukee, University of -...

  8. E-Print Network 3.0 - ash material analisis Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    was used in this work. An ASTM Class F fly ash... , and N3) were proportioned with clean coal fly ash containing 22% ... Source: Wisconsin-Milwaukee, University of - Department...

  9. E-Print Network 3.0 - alkali-activated fly ash Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering ; Materials Science 12 By-Products Utilization Summary: CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique... of...

  10. E-Print Network 3.0 - activated fly ash Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering ; Materials Science 9 By-Products Utilization Summary: CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique... of...

  11. E-Print Network 3.0 - ashes total contents Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fly ash content for normal concrete... contained fly ash up to a maximum of 35% of clean-coal ... Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

  12. Tephrochronology and Stratigraphy of Eocene and Oligocene Volcanic Ashes of East and Central Texas

    E-Print Network [OSTI]

    Heintz, Mindi

    2013-12-02T23:59:59.000Z

    using neutron activation analysis (NAA) of bulk ash and glass shards, inductively coupled plasma mass spectrometry (ICPMS) of bulk ash, and electron microprobe analysis of both apatite phenocrysts and glass shards to characterize their geochemistry...

  13. In vivo imaging of C. elegans ASH neurons: cellular response and adaptation to chemical repellents

    E-Print Network [OSTI]

    Schafer, William R.

    Erratum In vivo imaging of C. elegans ASH neurons: cellular response and adaptation to chemical neurons highlighted. From the ASH cell body, the dendrite runs anteriorly until the tip of the head ending

  14. Soil stabilization using optimum quantity of calcium chloride with Class F fly ash

    E-Print Network [OSTI]

    Choi, Hyung Jun

    2006-10-30T23:59:59.000Z

    Ash at 90days ............... 38 5-13 Stress Strain Curve of 6% CaCl2+10% Fly Ash at 90days ............... 39 5-14 Stress Strain Curve of 4% CaCl2+15% Fly Ash at 90days ............... 39 5-15 Environmental Scanning Electron Microscopy... (E-SEM) of Class F Fly Ash ................................................................................. 40 5-16 Environmental Scanning Electron Microscopy (E-SEM) of Control Soil after 7 Days of Curing...

  15. High-performance, high-volume fly ash concrete

    SciTech Connect (OSTI)

    NONE

    2008-01-15T23:59:59.000Z

    This booklet offers the construction professional an in-depth description of the use of high-volume fly ash in concrete. Emphasis is placed on the need for increased utilization of coal-fired power plant byproducts in lieu of Portland cement materials to eliminate increased CO{sub 2} emissions during the production of cement. Also addressed is the dramatic increase in concrete performance with the use of 50+ percent fly ash volume. The booklet contains numerous color and black and white photos, charts of test results, mixtures and comparisons, and several HVFA case studies.

  16. Ash reduction system using electrically heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

    2011-08-16T23:59:59.000Z

    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  17. Continuous air agglomeration method for high carbon fly ash beneficiation

    DOE Patents [OSTI]

    Gray, McMahon L. (Pittsburgh, PA); Champagne, Kenneth J. (Monongahela, PA); Finseth, Dennis H. (Pittsburgh, PA)

    2000-01-01T23:59:59.000Z

    The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

  18. Coal-ash slag attack and corrosion of refractories

    SciTech Connect (OSTI)

    Bonar, J.A. (Carborundum Co., Niagara Falls, NY); Kennedy, C.R.; Swaroop, R.B.

    1980-04-01T23:59:59.000Z

    The corrosion characteristics of a variety of fused-cast refractories in contact with various coal-ash slags were investigated. A fused-cast chrome-spinel refractory exhibited excellent corrosion resistance to both acidic and basic coal-ash slags at 1500/sup 0/C, even in the absence of water cooling. The slag-refractory interaction was limited to the formation of a stable band of recrystallized hercynitic spinel. Alumina-chromia refractories were superior to alumina and magnesia-chrome refractories when exposed to acidic slags.

  19. RESEARCH NEEDS IN MINERAL BY-PRODUCTS UTILIZATION: FLY ASH, SILICA FUME AND SLAG

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    of coal in electric power plants. It is captured by either mechanical separators, electrostatic. 2.0 Research Needs Concerning Fly Ash Utilization 2.1 CLSM Fly Ash Slurry Controlled low strength materials (CLSM), as classified by ACI Committee 229, have been produced using fly ash slurry [9

  20. Correlation relations between mineralogical components in ash from Kaa-Khem coals

    SciTech Connect (OSTI)

    N.N. Yanchat; L.Kh. Tas-ool [Russian Academy of Sciences, Kyzyl (Russia). Tuvinian Institute for Complex Exploration of Natural Resources

    2008-08-15T23:59:59.000Z

    Regression analysis was used to study correlation relations between the mineral components of coals. Regularities in the variability of the concentrations of individual ash-forming elements with changing ash contents of coals and changing seam depth were found. The X-ray diffraction characteristics of coal ashes and the qualitative composition of their mineralogical components are presented.

  1. INCO-WBC-1-509173 Reintegration of coal ash disposal sites and mitigation of

    E-Print Network [OSTI]

    1 INCO-WBC-1-509173 RECOAL Reintegration of coal ash disposal sites and mitigation of pollution of coal ash disposal sites Due date of deliverable: 12.2007 Actual submission date: 02.2008 Start date of the consortium (including the Commission Services) #12;2 Handbook on treatment of coal ash disposal sites Preface

  2. TRACE ELEMENTS LEACHING FROM ORGANIC SOILS STABILIZED WITH HIGH CARBON FLY ASH

    E-Print Network [OSTI]

    Aydilek, Ahmet

    and Se for organic soil-HCFA mixtures. Keywords: organic soil, fly ash, coal combustion products, CCPs INTRODUCTION Fly ash is a silt-size particulate collected by air pollution control systems at coal fly ashes (HCFAs) generally are disposed in landfills (Hodges and Keating 1999). However, many HCFAs

  3. Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater Reyad; available online 29 October 2003 Abstract A by-product fly ash from oil shale processing was converted shale; Ash; Zeolite; Cadmium and lead removal 1. Introduction Oil shale exists in Jordan with large

  4. Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit

    SciTech Connect (OSTI)

    S. W. Clark and H. M Sulloway

    2007-10-31T23:59:59.000Z

    This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

  5. Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit

    SciTech Connect (OSTI)

    S. W. Clark and H. M. Sulloway

    2007-09-26T23:59:59.000Z

    This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

  6. Rechargeable Li/CO2O2 (2 : 1) battery and Li/CO2 Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen

    E-Print Network [OSTI]

    Wang, Wei Hua

    Rechargeable Li/CO2­O2 (2 : 1) battery and Li/CO2 battery Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen A Li/CO2­O2 (2 : 1, volume ratio) battery and a Li/CO2 battery with discharging specific capacities of 1808 mA h gÀ1 and 1032 mA h gÀ1 , respectively, are reported. Li2CO3 is the main discharge

  7. THE {sup 7}Li/{sup 6}Li ISOTOPE RATIO NEAR THE SUPERNOVA REMNANT IC 443

    SciTech Connect (OSTI)

    Taylor, C. J.; Ritchey, A. M.; Federman, S. R. [Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606 (United States); Lambert, D. L., E-mail: corbin.taylor@rockets.utoledo.edu, E-mail: steven.federman@utoledo.edu, E-mail: aritchey@astro.washington.edu, E-mail: dll@astro.as.utexas.edu [W. J. McDonald Observatory, University of Texas at Austin, Austin, TX 78712 (United States)

    2012-05-01T23:59:59.000Z

    We present an analysis of {sup 7}Li/{sup 6}Li isotope ratios along four sight lines that probe diffuse molecular gas near the supernova remnant IC 443. Recent gamma-ray observations have revealed the presence of shock-accelerated cosmic rays interacting with the molecular cloud surrounding the remnant. Our results indicate that the {sup 7}Li/{sup 6}Li ratio is lower in regions more strongly affected by these interactions, a sign of recent Li production by cosmic rays. We find that {sup 7}Li/{sup 6}Li Almost-Equal-To 7 toward HD 254755, which is located just outside the visible edge of IC 443, while {sup 7}Li/{sup 6}Li Almost-Equal-To 3 along the line of sight to HD 43582, which probes the interior region of the supernova remnant. No evidence of {sup 7}Li synthesis by neutrino-induced spallation is found in material presumably contaminated by the ejecta of a core-collapse supernova. The lack of a neutrino signature in the {sup 7}Li/{sup 6}Li ratios near IC 443 is consistent with recent models of Galactic chemical evolution, which suggest that the {nu}-process plays only a minor role in Li production.

  8. Thermal Stability of LiPF6 Salt and Li-ion Battery ElectrolytesContaining LiPF6

    SciTech Connect (OSTI)

    Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

    2006-03-08T23:59:59.000Z

    The thermal stability of the neat LiPF6 salt and of 1 molal solutions of LiPF6 in prototypical Li-ion battery solvents was studied with thermogravimetric analysis (TGA) and on-line FTIR. Pure LiPF6 salt is thermally stable up to 380 K in a dry inert atmosphere, and its decomposition path is a simple dissociation producing LiF as solid and PF5 as gaseous products. In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF6 and water vapor to form POF3 and HF. No new products were observed in 1 molal solutions of LiPF6 in EC, DMC and EMC by on-line TGA-FTIR analysis. The storage of the same solutions in sealed containers at 358 K for 300 420 hrs. did not produce any significant quantity of new products as well. In particular, noalkylflurophosphates were found in the solutions after storage at elevated temperature. In the absence of either an impurity like alcohol or cathode active material that may (or may not) act as a catalyst, there is no evidence of thermally induced reaction between LiPF6 and the prototypical Li-ion battery solvents EC, PC, DMC or EMC.

  9. Volcanic ash: What it is and how it forms

    SciTech Connect (OSTI)

    Heiken, G.

    1991-09-13T23:59:59.000Z

    There are four basic eruption processes that produce volcanic ash: (1) decompression of rising magma, gas bubble growth, and fragmentation of the foamy magma in the volcanic vent (magmatic), (2) explosive mixing of magma with ground or surface water (hydrovolcanic), (3) fragmentation of country rock during rapid expansion of steam and/or hot water (phreatic), and (4) breakup of lava fragments during rapid transport from the vent. Variations in eruption style and the characteristics of volcanic ashes produced during explosive eruptions depend on many factors, including magmatic temperature, gas content, viscosity and crystal content of the magma before eruption, the ratio of magma to ground or surface water, and physical properties of the rock enclosing the vent. Volcanic ash is composed of rock and mineral fragments, and glass shards, which is less than 2 mm in diameter. Glass shard shapes and sizes depend upon size and shape of gas bubbles present within the magma immediately before eruption and the processes responsible for fragmentation of the magma. Shards range from slightly curved, thin glass plates, which were broken from large, thin-walled spherical bubble walls, to hollow needles broken from pumiceous melts containing gas bubbles stretched by magma flow within the volcanic vent. Pumice fragments make up the coarser-grained portions of the glass fraction. Particle sizes range from meters for large blocks expelled near the volcanic vent to nanometers for fine ash and aerosol droplets within well-dispersed eruption plumes. 18 refs., 6 figs., 1 tab.

  10. Maintaining and Improving Marketability of Coal Fly Ash

    E-Print Network [OSTI]

    is produced when coal is consumed by power plants Fly ash can be used beneficially in numerous applications-fired power plants work to create cleaner skies, they'll likely fill up landfills with millions more tons.05 0.05 #12;6 Challenge: Mercury Controls One approach to reducing mercury emissions from power plants

  11. Soil stabilization and pavement recycling with self-cementing coal fly ash

    SciTech Connect (OSTI)

    NONE

    2008-01-15T23:59:59.000Z

    This manual provides design information for self-cementing coal fly ash as the sole stabilizing agent for a wide range of engineering applications. As in any process, the application of sound engineering practices, appropriate testing, and evaluation of fly ash quality and characteristics will lend themselves to successful projects using the guidelines in this manual. Topics discussed include: self-cementing coal fly ash characteristics; laboratory mix design; stabilization of clay soils; stabilisation of granular materials; construction considerations; high sulfate ash; environmental considerations for fly ash stabilization; design considerations; state specification/guidelines/standards; and a sample of a typical stabilization specification.

  12. Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Growth Process of Li2S2Li2S in Lithium-Sulfur Batteries. Abstract: Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially...

  13. Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hu, JH Kwak, and Z Yang.2009."Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System."International Journal of Hydrogen Energy 34(10):4331-4339. doi:10.1016...

  14. A comparison of ZnO films deposited on indium tin oxide and soda lime glass under identical conditions

    SciTech Connect (OSTI)

    Deka, Angshuman; Nanda, Karuna Kar [Materials Research Centre, Indian Institute of Science, Bangalore - 560012 (India)

    2013-06-15T23:59:59.000Z

    ZnO films have been grown via a vapour phase transport (VPT) on soda lime glass (SLG) and indium-tin oxide (ITO) coated glass. ZnO film on ITO had traces of Zn and C which gives them a dark appearance while that appears yellowish-white on SLG. X-ray photoelectron spectroscopy studies confirm the traces of C in the form of C-O. The photoluminescence studies reveal a prominent green luminescence band for ZnO film on ITO.

  15. Stabilize ash using Clemson`s sintering process (Part 1 -- Phase 1 results): Mixed waste fly ash stabilization. Innovative technology summary report

    SciTech Connect (OSTI)

    Not Available

    1998-12-01T23:59:59.000Z

    Incineration of applicable Department of Energy (DOE) mixed wastes has produced a secondary waste stream of radioactive and Resource Conservation and Recovery Act (RCRA) hazardous fly ash that also requires treatment before land disposal. Unlike bottom ash, fly ash usually contains constituents making efficient stabilization difficult. For example, fly ash from the DOE Waste Experimental Reduction Facility (WERF) incinerator at the Idaho National Engineering and Environmental Laboratory (INEEL) contains volatile metals, metal salts, high concentrations of zinc, and unburned organic residues. All of these constituents can effect the stabilization process. The Department of Energy, and in particular the Mixed Waste Focus Area (MWFA) of EM-50, has stated the need for improved stabilization methods would accept a higher ash waste loading while meeting waste form disposal criteria. These alternative stabilization technologies should include delivery systems to minimize worker exposure and minimize secondary waste generation, while maximizing operational flexibility and radionuclide containment. Currently, the standard practice for stabilizing ash is mixing with Portland cement at room temperature. This standard practice produces a significant increase of waste material volume or has difficulty in adequately stabilizing the components in the fly ash to ensure regulatory requirements are consistently satisfied. To address these fly ash stabilization shortcomings, the MWFA, a DOE/EM-50 program, invested in the development of several fly ash stabilization alternatives, including the Clemson University sintering method.

  16. Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung*

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    in the United States generate 80 million tons of fly ash as a by-product each year, primarily from coal combustion [1]. Fly ash is typically disposed in landfills, but it is preferred to convert fly ashUse of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung

  17. Time-resolved measurement of photon emission during fast crack propagation in three-point bending fracture of silica glass and soda lime glass

    SciTech Connect (OSTI)

    Shiota, Tadashi, E-mail: tshiota@ceram.titech.ac.jp; Sato, Yoshitaka; Yasuda, Kouichi [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1-S7-13 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan)] [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1-S7-13 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan)

    2014-03-10T23:59:59.000Z

    Simultaneous time-resolved measurements of photon emission (PE) and fast crack propagation upon bending fracture were conducted in silica glass and soda lime glass. Observation of fracture surfaces revealed that macroscopic crack propagation behavior was similar between the silica glass and soda lime glass when fracture loads for these specimens were comparable and cracks propagated without branching. However, a large difference in the PE characteristics was found between the two glasses. In silica glass, PE (645–655?nm) was observed during the entire crack propagation process, whereas intense PE (430–490?nm and 500–600?nm) was observed during the initial stages of propagation. In contrast, only weak PE was detected in soda lime glass. These results show that there is a large difference in the atomic processes involved in fast crack propagation between these glasses, and that PE can be used to study brittle fracture on the atomic scale.

  18. Coulomb dissociation of [sup 11]Li

    SciTech Connect (OSTI)

    Ieki, K.; Sackett, D.; Galonsky, A.; Bertulani, C.A.; Kruse, J.J.; Lynch, W.G.; Morrissey, D.J.; Orr, N.A.; Schulz, H.; Sherrill, B.M.; Sustich, A.; Winger, J.A. (National Superconducting Cyclotron Laboratory and Department of Physics, Michigan State Unversity, East Lansing, Michigan 48824 (United States)); Deak, F.; Horvath, A.; Kiss, A. (Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7 H-1088 Budapest 8 (Hungary)); Seres, Z. (KFKI Research Institute for Particle and Nuclear Physics of the Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary)); Kolata, J.J. (Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)); Warner, R.E. (Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States)); Humphrey, D.L. (Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States))

    1993-02-08T23:59:59.000Z

    Kinematically complete measurements for Coulomb dissociation of [sup 11]Li into [sup 9]Li+2[ital n] were made at 28 MeV/nucleon. The [ital n]-[ital n] correlation function suggests a large source size for the two-neutron emission. The electromagnetic excitation spectrum of [sup 11]Li has a peak, as anticipated in low-energy dipole resonance models, but a large post-breakup Coulomb acceleration of the [sup 9]Li fragment is observed, indicating a very short lifetime of the excited state and favoring direct breakup as the dissociation mechanism.

  19. Regeneratively cooled coal combustor/gasifier with integral dry ash removal

    DOE Patents [OSTI]

    Beaufrere, A.H.

    1982-04-30T23:59:59.000Z

    A coal combustor/gasifier is disclosed which produces a low or medium combustion gas fired furnances or boilers. Two concentric shells define a combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

  20. A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries

    E-Print Network [OSTI]

    1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

  1. Response of rice to ammonium and nitrate nitrogen applied at various stages of plant growth on limed and unlimed Beaumont and Lake Charles clays 

    E-Print Network [OSTI]

    Gay, William Blalock, III

    1962-01-01T23:59:59.000Z

    and Patna1k (1 ) partially support th1s explanation. They found that lime at ths rate of one percent of the weight of the so11 increased mineralisat1on of nitrogen, but most of the n1trogen in their tests accumulated as ammonia rather than nitrate under...RESPONSE OF RICE TO AMMONIUM AND NITRATE NITROGEN APPLIED AT VARIOUS STAGES OF PLANT GROWTH ON LIMED AND UNLINED BEAUNONT AND LAKE CHARLES CLAYS A Thesis By William B. Gay, III Submitted to the Graduate Sohool of the Agricultural...

  2. 08LI_1~1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) - Energy Innovation Portal AdvancedUsingLi Thermal1

  3. 09LI_1~1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) - Energy Innovation Portal AdvancedUsingLi6,6,0 Dear093, 2009

  4. JV Task 6 - Coal Ash Resources Research Consortium Research

    SciTech Connect (OSTI)

    Debra Pflughoeft-Hassett; Tera Buckley; Bruce Dockter; Kurt Eylands; David Hassett; Loreal Heebink; Erick Zacher

    2008-04-01T23:59:59.000Z

    The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of coal combustion by-products (CCBs). CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCB utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program (JSRP), which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCB performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 1998 to 2007 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCBs. CARRC topical reports were prepared on several completed tasks. Specific CARRC 1998B2007 accomplishments included: (1) Development of several ASTM International Standard Guides for CCB utilization applications. (2) Organization and presentation of training courses for CCB professionals and teachers. (3) Development of online resources including the Coal Ash Resource Center, Ash from Biomass in Coal (ABC) of cocombustion ash characteristics, and the Buyer's Guide to Coal-Ash Containing Products. In addition, development of expanded information on the environmental performance of CCBs in utilization settings included the following: (1) Development of information on physical properties and engineering performance for concrete, soil-ash blends, and other products. (2) Training of students through participation in CARRC research projects. (3) Participation in a variety of local, national, and international technical meetings, symposia, and conferences by presenting and publishing CCB-related papers.

  5. EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS

    SciTech Connect (OSTI)

    Glenn A. Norton; Hongqun Yang; Robert C. Brown; Dennis L. Laudal; Grant E. Dunham; John Erjavec; Joseph M. Okoh

    2002-01-31T23:59:59.000Z

    Tests were performed in simulated flue gas streams using fly ash from the electrostatic precipitators of two full-scale utility boilers. One fly ash was from a Powder River Basin (PRB) coal, while the other was from Blacksville coal. Elemental Hg was injected upstream from samples of fly ash loaded onto filters housed in an oven at 120 or 180 C. Concentrations of oxidized and elemental Hg downstream from the filters were determined using the Ontario Hydro method. The gas stream composition and whether or not ash was present in the gas stream were the two most important variables affecting Hg oxidation. The presence of HCl, NO, NO{sub 2}, and SO{sub 2} were all important with respect to Hg oxidation, with NO{sub 2} and HCl being the most important. The presence of NO suppressed Hg oxidation in these tests. Although the two fly ashes were chemically and mineralogically diverse, there were generally no large differences in catalytic potential (for oxidizing Hg) between them. Similarly, no ash fraction appeared to be highly catalytic relative to other ash fractions. This includes fractions enriched in unburned carbon and fractions enriched in iron oxides. Although some differences of lesser magnitude were observed in the amount of oxidized Hg formed, levels of oxidized Hg generally tracked well with the surface areas of the different ashes and ash fractions. Therefore, although the Blacksville fly ash tended to show slightly more catalytic activity than the PRB fly ash, this could be due to the relatively high surface area of that ash. Similarly, for Blacksville fly ash, using nonmagnetic ash resulted in more Hg oxidation than using magnetic ash, but this again tracked well with the relative surface areas of the two ash fractions. Test results suggest that the gas matrix may be more important in Hg oxidation chemistry than the fly ash composition. Combustion tests were performed in which Blacksville and PRB fly ashes were injected into filtered (via a baghouse with Teflon bags) flue gas obtained while firing PRB coal in a 35 kW combustor. The Ontario Hydro method was used to determine the Hg speciation after fly ash injection. Wall effects in the combustor complicated interpretation of testing data, although a number of observations could still be made. The amount of Hg collected in the Ontario Hydro impingers was lower than anticipated, and is probably due to sorption of Hg by the fly ash. While firing PRB coal without any ash injection, the percent oxidized Hg in the gas stream was fairly high (average of 63%). The high levels of vapor phase oxidized Hg in these base line tests may be due to catalytic effects from the refractory materials in the combustor. When PRB fly ash was injected into a filtered PRB flue gas stream, the percentage of oxidized Hg in the gas stream decreased dramatically. Decreases in the percentage of oxidized Hg were also observed while injecting Blacksville fly ash, but to a lesser extent. Injecting whole Blacksville fly ash into the filtered PRB flue gas appeared to result in greater concentrations of oxidized Hg relative to the tests where whole PRB fly ash was injected. However, because the Blacksville fly ash has a relatively high surface area, this may be only a surface area effect.

  6. Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems

    SciTech Connect (OSTI)

    Natalie J. Gese; Batric Pesic

    2013-03-01T23:59:59.000Z

    Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

  7. Characterization of Li-ion Batteries using Neutron Diffraction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques Characterization of Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques 2011 DOE...

  8. Characterization of Materials for Li-ion Batteries: Success Stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success...

  9. The preservation potential of ash layers in the deep-sea: the example of the 1991-Pinatubo ash in the South China Sea

    E-Print Network [OSTI]

    Wetzel, Andreas

    - burrowing animals re-opened their connection to the sea floor to obtain water for respiration and/or food deposited organic fluff with the underlying ash. Consequently, ash deposits thinner than 1 mm have not often of background sedimentation, the availability of benthic food on and within the sediment and pore water oxygen

  10. Construction of an embankment with a fly and bottom ash mixture: field performance study

    SciTech Connect (OSTI)

    Yoon, S.; Balunaini, U.; Yildirim, I.Z.; Prezzi, M.; Siddiki, N.Z. [Louisiana Transportation Research Center, Baton Rouge, LA (United States)

    2009-06-15T23:59:59.000Z

    Fly ash and bottom ash are coal combustion by-products (CCBPs) that are generated in large quantities throughout the world. It is often economical to dispose ash as mixtures rather than separately; that notwithstanding, only a few studies have been performed to investigate the behavior of fly and bottom ash mixtures, particularly those with high contents of fly ash. Also, there is very limited data available in the literature on the field performance of structures constructed using ash mixtures. This paper describes the construction and the instrumentation of a demonstration embankment built with an ash mixture (60:40 by weight of fly ash:bottom ash) on State Road 641, Terre Haute, Ind. Monitoring of the demonstration embankment was conducted for a period of 1 year from the start of construction of the embankment. The settlement of the embankment stabilized approximately 5 months after the end of its construction. According to horizontal inclinometer readings, the differential settlement at the top of the embankment is about 5 mm. Results from field quality control tests performed during construction of the demonstration embankment and monitoring data from vertical and horizontal inclinometers and settlement plates indicate that the ash mixture investigated can be considered an acceptable embankment construction material.

  11. Utilization of ash from municipal solid waste combustion. Final report, Phase I

    SciTech Connect (OSTI)

    Jones, C.M.; Hartman, R.M.; Kort, D.; Rapues, N.

    1994-09-01T23:59:59.000Z

    This ash study investigates several aspects of Municipal Waste Combustion (MWC) ash utilization to develop an alternative to the present disposal practice of landfilling in a lined monofill. Ash was investigated as a daily or final cover for municipal waste in the landfill to prevent erosion and as a road construction aggregate. Samples of eight mixtures of ash and other materials, and one sample of soil were analyzed for chemical constituents. Biological tests on these mixters were conducted, along with erosion tests and sieve analyses. A chemical analysis of each sieve size was conducted. Geotechnical properties of the most promising materials were made. Findings to this point include: all ash samples take have passed the EPA TCLP testing; chemical analysis of bottom and combined ash samples indicate less than expected variability; selected ash mixtures exhibited very low coefficients of hydraulic conductivity; all but one of the ash mixtures exhibited greater erosion resistance than the currently used landfill cover material; MWC combined analysis indicates this is a viable alternative for landfill cover; MWC ash size reactions and chemical analysis show bottom and combined ash to be a viable alternative for road construction.

  12. Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char

    SciTech Connect (OSTI)

    Jing Gu; Shiyong Wu; Youqing Wu; Ye Li; Jinsheng Gao [East China University of Science and Technology, Shanghai (China). Department of Chemical Engineering for Energy Resources and Key Laboratory of Coal Gasification of Ministry of Education

    2008-11-15T23:59:59.000Z

    In the study, two fly ash samples from Texaco gasifiers were compared to coal char and the physical and chemical properties and reactivity of samples were investigated by scanning electron microscopy (SEM), SEM-energy-dispersive spectrometry (EDS), X-ray diffraction (XRD), N{sub 2} and CO{sub 2} adsorption method, and isothermal thermogravimetric analysis. The main results were obtained. The carbon content of gasified fly ashes exhibited 31-37%, which was less than the carbon content of 58-59% in the feed coal. The fly ashes exhibited higher Brunauer-Emmett-Teller (BET) surface area, richer meso- and micropores, more disordered carbon crystalline structure, and better CO{sub 2} gasification reactivity than coal char. Ashes in fly ashes occurred to agglomerate into larger spherical grains, while those in coal char do not agglomerate. The minerals in fly ashes, especial alkali and alkaline-earth metals, had a catalytic effect on gasification reactivity of fly ash carbon. In the low-temperature range, the gasification process of fly ashes is mainly in chemical control, while in the high-temperature range, it is mainly in gas diffusion control, which was similar to coal char. In addition, the carbon in fly ashes was partially gasified and activated by water vapor and exhibited higher BET surface area and better gasification activity. Consequently, the fact that these carbons in fly ashes from entrained flow gasifiers are reclaimed and reused will be considered to be feasible. 15 refs., 7 figs., 5 tabs.

  13. Coal-ash spills highlight ongoing risk to ecosystems

    SciTech Connect (OSTI)

    Chatterjee, R.

    2009-05-01T23:59:59.000Z

    Two recent large-scale spills of coal combustion waste have highlighted the old problem of handling the enormous quantity of solid waste produced by coal. Both spills happened at power plants run by the Tennessee Valley Authority (TVA). In December 2008 a holding pond for coal ash collapsed at a power plant in Kingstom, Tenn., releasing coal-ash sludge onto farmland and into rivers: in January 2009 a break in a pipe removing water from a holding pond for gypsum caused a spill at Widows Creek Fossil Plant in Stevenson, Ala. The article discusses the toxic outcome of such disasters on ecosystems, quoting work by Willaim Hopkins at Virginia Polytechnic Institute and State University and recommendations and reports of the US EPA. 2 photos.

  14. Ash reduction in clean coal spiral product circuits

    SciTech Connect (OSTI)

    Brodzik, P.

    2007-04-15T23:59:59.000Z

    The article describes the Derrick Corporation's Stack Sizer{trademark} technology for high capacity fine wet cleaning with long-lasting high open-area urethane screen panels. After field trials, a Stack Sizer fitted with a 100-micron urethane panel is currently processing approximately 40 stph of clean coal spiral product having about 20% ash at McCoy-Elkhorn's Bevin Branch coal preparation plant in Kentucky, USA. Product yield is about 32.5 short tons per hour with 10% ash. The material is then fed to screen bowl centrifuges for further processing. At Blue Diamond Coal's Leatherwood preparation plant similar Stacker Sizers are achieving the same results. 2 figs., 3 tabs., 2 photo.

  15. DFT+U Study of Polaronic Conduction in Li2O2 and Li2CO3: Implications for Li-Air Batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    DFT+U Study of Polaronic Conduction in Li2O2 and Li2CO3: Implications for Li-Air Batteries J. M-air batteries are known to be Li2O2 and residual Li2CO3. Recent experiments indicate that the charge transport through these materials is the main limiting factor for the battery performance. It has been also shown

  16. Effects of Sediment Containing Coal Ash from the Kingston Ash Release on Embryo-Larval Development in the Fathead Minnow, Pimephales promelas (Rafinesque, 1820)

    SciTech Connect (OSTI)

    Greeley Jr, Mark Stephen [ORNL] [ORNL; Elmore, Logan R [ORNL] [ORNL; McCracken, Kitty [ORNL] [ORNL; Sherrard, Rick [Tennessee Valley Authority (TVA)] [Tennessee Valley Authority (TVA)

    2014-01-01T23:59:59.000Z

    The largest environmental release of coal ash in U.S. history occurred in December 2008 with the failure of a retention structure at the Tennessee Valley Authority (TVA) Kingston Fossil Plant in East Tennessee. A byproduct of coal-burning power plants, coal ash is enriched in metals and metalloids such as selenium and arsenic with known toxicity to fish including embryonic and larval stages. The effects of contact exposure to sediments containing up to 78 % coal ash from the Kingston spill on the early development of fish embryos and larvae were examined in 7-day laboratory tests with the fathead minnow (Pimephales promelas). No significant effects were observed on hatching success, incidences of gross developmental abnormalities, or embryo-larval survival. Results suggest that direct exposures to sediment containing residual coal ash from the Kingston ash release may not present significant risks to fish eggs and larvae in waterways affected by the spill.

  17. The reactions and ashes of thermonuclear explosions on neutron stars

    E-Print Network [OSTI]

    J. L. Fisker; E. Brown; M. Liebendoerfer; F. -K. Thielemann; M. Wiescher

    2004-08-04T23:59:59.000Z

    This paper reports on the detailed rp-process reaction flow on an accreting neutron star and the resulting ashes of a type I X-ray burst. It is obtained by coupling a 298 isotope reaction network to a self-consistent one-dimensional model calculation with a constant accretion rate of dM/dt=1.0e17g/s (0.09 Eddington).

  18. Oil shale ash-layer thickness and char combustion kinetics

    SciTech Connect (OSTI)

    Aldis, D.F.; Singleton, M.F.; Watkins, B.E.; Thorsness, C.B.; Cena, R.J.

    1992-04-15T23:59:59.000Z

    A Hot-Recycled-Solids (HRS) oil shale retort is being studied at Lawrence Livermore National Laboratory. In the HRS process, raw shale is heated by mixing it with burnt retorted shale. Retorted shale is oil shale which has been heated in an oxygen deficient atmosphere to pyrolyze organic carbon, as kerogen into oil, gas, and a nonvolatile carbon rich residue, char. In the HRS retort process, the char in the spent shale is subsequently exposed to an oxygen environment. Some of the char, starting on the outer surface of the shale particle, is burned, liberating heat. In the HRS retort, the endothermic pyrolysis step is supported by heat from the exothermic char combustion step. The rate of char combustion is controlled by three resistances; the resistance of oxygen mass transfer through the gas film surrounding the solid particle, resistance to mass transfer through a ash layer which forms on the outside of the solid particles as the char is oxidized and the resistance due to the intrinsic chemical reaction rate of char and oxygen. In order to estimate the rate of combustion of the char in a typical oil shale particle, each of these resistances must be accurately estimated. We begin by modeling the influence of ash layer thickness on the over all combustion rate of oil shale char. We then present our experimental measurements of the ash layer thickness of oil shale which has been processed in the HRS retort.

  19. Modeling the formation and size distribution of fly ash

    SciTech Connect (OSTI)

    Dahlin, R.S.

    1985-01-01T23:59:59.000Z

    A set of mathematical models has been developed to predict the size distribution of fly ash particles formed in pulverized coal combustion. The large particle mode of the size distribution, typically centered about 10 to 20 ..mu..m, is predicted by a simple breakup model that is based on the complete coalescence of molten mineral inclusions within fragments of the devolatilized coal char. The ultrafine particle mode, that is typically centered about 0.1 to 0.2 ..mu..m, is modeled in terms of ash volatilization, nucleation, and coagulation. Silica and alumina are reduced to volatile suboxides through reactions at the char surface. The volatile suboxides are transported from the char surface where they are oxidized back to the stable oxides in the bulk gas, and then nucleated in accordance with homogeneous nucleation theory. The ultrafine nuclei coagulate in accordance with Brownian coagulation theory. The predicted particle size spectra have been compared to measured size distributions from a pilot-scale combustor and a full-scale utility boiler. Considering the disproportionate loss of coarse particles in the pilot-scale unit, the agreement between the predicted and measured size distributions was considered reasonably good. Both the predicted ultrafine and large particle modes agreed reasonably well with the measured particle size distribution for the full scale boiler. The validated computer models were used to study the effect of changes in the coal ash content, coal particle size, and the combustion flame temperature.

  20. Respirable aerosols from fluidized bed coal combustion. 3. Elemental composition of fly ash

    SciTech Connect (OSTI)

    Weissman, S.H.; Carpenter, R.L.; Newton, G.J.

    1983-02-01T23:59:59.000Z

    Fluidized bed coal combustion is a promising technology for using coal in an environmentally acceptable manner. Trace elemental constituents in fly ash from an experimental atmospheric pressure fluidized bed combustor (AFBC) are reported and compared with pulverized-coal combustor (PCC) ash data and those from other fluidized bed combustors. Bulk and size-separated particles were collected and analyzed by using spark source mass spectrometry.Fluidized bed combustor ash was similar to PCC ash in minor and trace element composition. However, AFBC ash showed less size dependence of elemental composition than has been reported for PCC ash. Bulk particle elemental composition varied with sampling position within the effluent stream. Penetration of elements through each cleanup stage and elemental enrichment were a function of the cleanup stage and the element under consideration.

  1. Integrated production/use of ultra low-ash coal, premium liquids and clean char

    SciTech Connect (OSTI)

    Kruse, C.W.

    1991-01-01T23:59:59.000Z

    This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  2. A review of ash in conventional and advanced coal-based power systems

    SciTech Connect (OSTI)

    Holcombe, N.T.

    1995-12-31T23:59:59.000Z

    Process conditions are briefly described for conventional and advanced power systems. The advanced systems include both combustion and gasification processes. We discuss problems in coal-based power generation systems, including deposition, agglomeration and sintering of bed materials, and ash attack are discussed. We also discuss methods of mitigating ash problems and anticipated changes anticipated in ash use by converting from conventional to advanced systems.

  3. INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS

    SciTech Connect (OSTI)

    G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

    2000-11-01T23:59:59.000Z

    This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

  4. Respirable aerosols from fluidized bed coal combustion. 3. Elemental composition of fly ash

    SciTech Connect (OSTI)

    Weissman, S.H.

    1983-02-01T23:59:59.000Z

    Trace element constituents in fly ash from an experimental atmospheric fluidized bed combustor (AFBC) are reported and compared with pulverized coal combustor (PCC) data and those from other fluidized bed combustors. Bulk and size-separated particles were collected and analyzed using spark source mass spectrometry. Fluidized bed combustion ash was similar to PCC ash in minor and trace element composition, but AFBC ash showed less size dependence of elemental composition. Bulk particle elemental composition varied with sampling position within the effluent stream. Penetration of elements through each cleanup stage and elemental enrichment were a function of the cleanup stage and the element under consideration.

  5. Coal deposit characterization by gamma-gamma density/percent dry ash relationships

    E-Print Network [OSTI]

    Wright, David Scott

    1984-01-01T23:59:59.000Z

    Density/Ash Relationship . APPLICATION OF THE GAMMA-GAMMA DENSITY/PERCENT DRY ASH RELATIONSHIPS The Density/Ash Relationship of a South Texas Lignite Deposit Characterization of a South Texas Lignite Deposit CONCLUSIONS REFERENCES. 52 53 53 53... 58 64 67 6g 80 87 LIST OF TABLES TABLE I Coal Classification by Rank. 2 Common Minerals in Coal. 3 Results of Linear Regression Analyses for a South Texas Lignite Deposit. 4 Variability of Geophysica11y-Derived Percent Dry Ash Values...

  6. Active control of the resistive wall mode with power saturation Li Li, Yue Liu, and Yueqiang Liu

    E-Print Network [OSTI]

    Active control of the resistive wall mode with power saturation Li Li, Yue Liu, and Yueqiang Liu://pop.aip.org/about/rights_and_permissions #12;Active control of the resistive wall mode with power saturation Li Li,1,a) Yue Liu,1 and Yueqiang, 116024, People's Republic of China 2 Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX

  7. Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li+ ion transport in LiNi0.5Mn1.5O4 through Control of Site Disorder. Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control of Site Disorder. Abstract: High voltage spinel...

  8. Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries Hyun diameters less than 10 nm and lengths of several micrometers. Galvanostatic battery testing showed that Li, lithium ion battery, LiMn2O4 nanowires, high power density, Jahn-Teller distortion T he high energy

  9. Asymptotic normalization coefficients for B-8 -> Be-7+p from a study of Li-8 -> Li-7+n 

    E-Print Network [OSTI]

    Trache, L.; Azhari, A.; Carstoiu, F.; Clark, HL; Gagliardi, Carl A.; Lui, YW; Mukhamedzhanov, AM; Tang, X.; Timofeyuk, N.; Tribble, Robert E.

    2003-01-01T23:59:59.000Z

    Asymptotic normalization coefficients (ANCs) for Li-8-->Li-7+n have been extracted from the neutron transfer reaction C-13(Li-7,Li-8)C-12 at 63 MeV. These are related to the ANCs in B-8-->Be-7 + p using charge symmetry. ...

  10. Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Simplified Electrochemical and Thermal Model of LiFePO4- Graphite Li-Ion Batteries for Fast Charge, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed for battery management system (BMS) applications and comprehensive aging investigations. Based on a modified

  11. Comment on Li pellet Conditioning in TFTR

    SciTech Connect (OSTI)

    R.V. Budny

    2011-05-23T23:59:59.000Z

    Li pellet conditioning in TFTR results in a reduction of the edge electron density which allows increased neutral beam penetration, central heating, and fueling. Consequently the temperature profiles became more peaked with higher central Ti, Te, and neutron emission rates.

  12. Negative Electrodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Kinoshita, Kim; Zaghib, Karim

    2001-10-01T23:59:59.000Z

    Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

  13. Kinetics of fly ash beneficiation by carbon burnout. [Quarterly report], October 1, 1995--January 30, 1996

    SciTech Connect (OSTI)

    Dodoo, J.N.; Okoh, J.M.; Yilmaz, E.

    1996-09-01T23:59:59.000Z

    The objective is to investigate the kinetics of beneficiation of fly ash by carbon burnout. The three year project that was proposed is a joint venture between Delmarva Power, a power generating company on the eastern shore of Maryland, and the University of Maryland Eastern Shore. The studies have focused on the beneficiation of fly ash by carbon burnout. The increasing use of coal fly ash as pozzolanic material in Portland cement concrete means that there is the highest economic potential in marketability of large volumes of fly ash. For the concrete industry to consider large scale use the fly ash must be of the highest quality. This means that the residual carbon content of the fly ash must have an acceptable loss on ignition (LOI) value, usually between 7--2% residual carbon. The economic gains to be had from low-carbon ash is a fact that is generally accepted by the electricity generating companies. However, since the cost of producing low-carbon in large quantities, based on present technology, far outweighs any financial gains, no electrical power company using coal as its fuel at present considers the effort worthwhile. The concrete industry would use fly ash in cement concrete mix if it can be assured of its LOI value. At present no utility company would give such assurance. Hence with several million tons of fly ash produced by a single power plant per year all that can be done is to dump the fly ash in landfills. The kinetics of fly ash beneficiation have been investigated in the zone II kinetic regime, using a Cahn TG 121 microbalance in the temperature 550--750{degrees}C. The P{sub 02} and total surface area dependence of the reaction kinetics were determined using a vacuum accessory attached to the microbalance and a surface area analyzer (ASAP 2010), respectively.

  14. Speciation of Selenium, Arsenic, and Zinc in Class C Fly Ash

    SciTech Connect (OSTI)

    Luo, Yun; Giammar, Daniel E.; Huhmann, Brittany L.; Catalano, Jeffrey G. (WU)

    2011-11-17T23:59:59.000Z

    A major environmental concern associated with coal fly ash is the mobilization of trace elements that may contaminate water. To better evaluate proper use of fly ash, determine appropriate disposal methods, and monitor postdisposal conditions, it is important to understand the speciation of trace elements in fly ash and their possible environmental impact. The speciation of selenium, arsenic, and zinc was determined in five representative Class C fly ash samples from combustion of sub-bituminous Powder River Basin coal using synchrotron-based X-ray absorption spectroscopy to provide an improved understanding of the mechanisms of trace element association with the fly ash. Selenium in all fly ash samples occurs predominantly as Se(IV), with the exception of one sample, in which there was a minor amount of Se(0). Se(0) is likely associated with the high content of unburned coal in the sample. Arsenic exists in the fly ash as a single phase most consistent with calcium pyroarsenate. In contrast, zinc occurs as two distinct species in the silicate glass matrix of the fly ash. This work demonstrates that residual carbon in fly ash may reduce potential Se mobility in the environment by retaining it as less soluble elemental Se instead of Se(IV). Further, this work suggests that As and Zn in Class C fly ash will display substantially different release and mobilization behaviors in aquatic environments. While As release will primarily depend upon the dissolution and hydrolysis of calcium pyroarsenate, Zn release will be controlled by the dissolution of alkaline aluminosilicate glass in the ash.

  15. Ambient Operation of Li/Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Wang, Deyu; Xu, Wu; Xiao, Jie; Williford, Ralph E.

    2010-07-01T23:59:59.000Z

    In this work, Li/air batteries based on nonaqueous electrolytes were investigated in ambient conditions (with an oxygen partial pressure of 0.21 atm and relative humidity of ~20%). A heat-sealable polymer membrane was used as both an oxygen-diffusion membrane and as a moisture barrier for Li/air batteries. The membrane also can minimize the evaporation of the electrolyte from the batteries. Li/air batteries with this membrane can operate in ambient conditions for more than one month with a specific energy of 362 Wh kg-1, based on the total weight of the battery including its packaging. Among various carbon sources used in this work, Li/air batteries using Ketjenblack (KB) carbon-based air electrodes exhibited the highest specific energy. However, KB-based air electrodes expanded significantly and absorbed much more electrolyte than electrodes made from other carbon sources. The weight distribution of a typical Li/air battery using the KB-based air electrode was dominated by the electrolyte (~70%). Lithium-metal anodes and KB-carbon anodes account for only 5.12% and 5.78% of the battery weight, respectively. We also found that only ~ 20% of the mesopore volume of the air electrode was occupied by reaction products after discharge. To further improve the specific energy of the Li/air batteries, the microstructure of the carbon electrode needs to be further improved to absorb much less electrolyte while still holding significant amounts of reaction products

  16. Ash Fork, Arizona: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcatAntrimArkansas County,Minnesota:Arthur,Ascent SolarAscoenergyAsh

  17. Blue Ash, Ohio: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022 |Bleckley County,Minnesota:Open EnergyAsh, Ohio:

  18. Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy Storage

    SciTech Connect (OSTI)

    Wang, Wei; Choi, Daiwon; Yang, Zhenguo

    2013-01-01T23:59:59.000Z

    i-ion batteries based on commercially available LiFePO4 cathode and Li4Ti5O12 anode were investigated for potential stationary energy storage applications. The full cell that operated at flat 1.85V demonstrated stable cycling for 200 cycles followed by a rapid fade. A significant improvement in cycling stability was achieved via Ketjen black coating of the cathode. A Li-ion full cell with Ketjen black modified LiFePO4 cathode and an unmodified Li4Ti5O12 anode exhibited negligible fade after more than 1200 cycles with a capacity of ~130mAh/g. The improved stability, along with its cost-effectiveness, environmentally benignity and safety, make the LiFePO4/ Li4Ti5O12 Li-ion battery a promising option of storing renewable energy.

  19. Biomonitoring of the genotoxic potential of aqueous extracts of soils and bottom ash resulting from municipal solid waste

    E-Print Network [OSTI]

    Mailhes, Corinne

    municipal solid waste incineration, using the comet and micronucleus tests on amphibian (Xenopus laevis ash resulting from municipal solid waste incineration (MSWIBA percolate), using amphibian larvae waste incineration bottom ash; Percolate 1. Introduction Environmental management of municipal solid

  20. Determination of Total Solids and Ash in Algal Biomass: Laboratory Analytical Procedure (LAP)

    SciTech Connect (OSTI)

    Van Wychen, S.; Laurens, L. M. L.

    2013-12-01T23:59:59.000Z

    This procedure describes the methods used to determine the amount of moisture or total solids present in a freeze-dried algal biomass sample, as well as the ash content. A traditional convection oven drying procedure is covered for total solids content, and a dry oxidation method at 575?C is covered for ash content.

  1. California bearing ratio behavior of soil-stabilized class F fly ash systems

    SciTech Connect (OSTI)

    Leelavathamma, B.; Mini, K.M.; Pandian, N.S. [Indian Institute for Science, Bangalore (India). Dept. for Civil Engineering

    2005-11-01T23:59:59.000Z

    Fly ash is a finely divided mineral residue resulting from the combustion of coal in power plants that occupies large extents of land and also causes environmental problems. Hence, concerted attempts are being made to effectively use fly ash in an environmentally friendly way instead of dumping. Several studies have been carried out for its bulk utilization, such as its addition to improve the California bearing ratio (CBR) of soil in roads and embankments. But a thorough mixing of fly ash with soil may not be possible in the field. Hence a study has been carried out on the CBR behavior of black cotton soil and Raichur fly ash (which is class F) in layers and compared with the same in mixes. The results show that the CBR values of soil-fly ash mixes are better than layers, as expected. To improve the strength of layers, cement is used as an additive to fly ash. The results show that black cotton soil can be improved with stabilized fly ash, solving its strength problem as well as the disposal problem of fly ash.

  2. Site-specific study on stabilization of acid-generating mine tailings using coal fly ash

    SciTech Connect (OSTI)

    Shang, J.Q.; Wang, H.L.; Kovac, V.; Fyfe, J. [University of Western Ontario, London, ON (Canada). Dept. of Civil & Environmental Engineering

    2006-03-15T23:59:59.000Z

    A site-specific study on stabilizing acid-generating mine tailings from Sudbury Mine using a coal fly ash from Nanticoke Generating Station is presented in this paper. The objective of the study is to evaluate the feasibility of codisposal of the fly ash and mine tailings to reduce environmental impacts of Sudbury tailings disposal sites. The study includes three phases, i.e., characterization of the mine tailings, and coal fly ash, oxidation tests on the mine tailings and kinetic column permeation tests. The results of the experiments indicate that when permeated with acid mine drainage, the hydraulic conductivity of Nanticoke coal fly ash decreased more than three orders of magnitude (from 1 x 10{sup -6} to 1 x 10{sup -9} cm/s), mainly due to chemical reactions between the ash solids and acid mine drainage. Furthermore, the hydraulic gradient required for acid mine drainage to break through the coal fly ash is increased up to ten times (from 17 to 150) as compared with that for water. The results also show that the leachate from coal fly ash neutralizes the acidic pore fluid of mine tailings. The concentrations of trace elements in effluents from all kinetic column permeation tests indicated that coplacement of coal fly ash with mine tailings has the benefit of immobilizing trace elements, especially heavy metals. All regulated element concentrations from effluent during testing are well below the leachate quality criteria set by the local regulatory authority.

  3. Market Assessment and Technical Feasibility Study of Pressurized Fluidized Bed Combustion Ash Use

    SciTech Connect (OSTI)

    Bland, A.E.; Brown, T.H. [Western Research Inst., Laramie, WY (United States)

    1996-12-31T23:59:59.000Z

    Western Research Institute in conjunction with the Electric Power Research Institute, Foster Wheeler Energy International, Inc. and the U.S. Department of Energy Technology Center (METC), has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for pressurized fluidized bed combustion (PFBC) ashes. The assessment is designed to address six applications, including: (1) structural fill, (2) road base construction, (3) supplementary cementing materials in portland cement, (4) synthetic aggregate, and (5) agricultural/soil amendment applications. Ash from low-sulfur subbituminous coal-fired Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, and ash from the high-sulfur bituminous coal-fired American Electric Power (AEP) bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing. This paper addresses the technical feasibility of ash use options for PFBC unit using low- sulfur coal and limestone sorbent (karhula ash) and high-sulfur coal and dolomite sorbents (AEP Tidd ash).

  4. Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1*

    E-Print Network [OSTI]

    Tiquia-Arashiro, Sonia M.

    Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1* , L. S. Fisher1 , J of the potential for carbon sequestration in degraded mine lands, we have found that based on laboratory and field and its influence on carbon sequestration. Also, addition of fly ash to soil, while generally considered

  5. Emission Control Technology, Performance/Durability -POSTER Effect of Accelerated Ash Loading on Performance of Diesel

    E-Print Network [OSTI]

    Pennycook, Steve

    on Performance of Diesel Particulate Filters and Morphology of Ash Layers Bruce G. Bunting and Todd J. Toops using a single-cylinder diesel engine has been developed for accelerated ash loading in catalyzed and non- catalyzed diesel particular filters (DPF) made of cordierite, SiC and mullite substrate

  6. MULTIPLE-SCALE DYNAMIC LEACHING OF A MUNICIPAL SOLID WASTE INCINERATION ASH

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 MULTIPLE-SCALE DYNAMIC LEACHING OF A MUNICIPAL SOLID WASTE INCINERATION ASH Waste Management (in source such as municipal solid waste (MSW) incineration ash, requires a knowledge of the so percolating through waste evolve over time, for a given percolation scenario (infiltration rate, waste source

  7. Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power Plants

    E-Print Network [OSTI]

    Hutcheon, James M.

    permits. To improve the aesthetic qualities of the effluent, coal ash (from local power plants_mill_discharge.jpg 2. Coal Power Plant http://www.csmonitor.com/var/ezflow_site/storage/images/media/images/2008Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power

  8. Soil stabilization using optimum quantity of calcium chloride with Class F fly ash 

    E-Print Network [OSTI]

    Choi, Hyung Jun

    2006-10-30T23:59:59.000Z

    in soil to verify the effectiveness and optimum ratio of calcium chloride and Class F fly ash in soil stabilization. Mix design was programmed at pure calcium chloride concentrations at 0% to 6% and Class F fly ash at 10 to 15%. Laboratory tests showed...

  9. Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    2004-01-01T23:59:59.000Z

    Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

  10. Canopy, litter and allelopathic effects of Ashe juniper (Juniperus ashei, Buchholz) on understory vegetation

    E-Print Network [OSTI]

    Yager, Lisa Yvonne

    1993-01-01T23:59:59.000Z

    , subirrigated litter treatment, and surface watered litter treatment. . 87 Figure 12 Drying rates of Ashe juniper litter when watered every 2, 3, and 4 days. . 92 LIST OF TABLES Table Page 1 Field treatments to test the influence of Ashe juniper canopy...

  11. Ash, calcium, phosphorus and magnesium content of the metacarpus of hereford cows under different nutritional and physiological conditions 

    E-Print Network [OSTI]

    Haque, Mozammel

    1967-01-01T23:59:59.000Z

    ASH, CALCIUM, PHOSPHORUS AND MAGNESIUM CONTENT OF THE METACARPUS OF HEREFORD COWS UNDER DIFFERENT NUTRITIONAL AND PHYSIOLOGICAL CONDITIONS A Thesis By MOZAMMEL HAQUE Submitted to the Graduate College of the Texas A&M University in partial... centages of Calcium, Phosphorus snd Magnesium in Bone Ash for Cows Gi;en Different Treatments During Pre- And Post-Partum Periods 22 10 Analysis of Variance oi Calcium in Bone Ash Dun an's )tultiple tvange Test 1'or Calcium in Bone Ash. Analy...

  12. Excitation functions of {sup 6,7}Li+{sup 7}Li reactions at low energies

    SciTech Connect (OSTI)

    Prepolec, L.; Soic, N.; Blagus, S.; Miljanic, D.; Siketic, Z.; Skukan, N.; Uroic, M. [Ruder Boskovic Institute, Bijenicka c. 54, HR-10000 Zagreb (Croatia); Milin, M. [Faculty of Science, University of Zagreb, Bijenicka c. 32, HR-10000 Zagreb (Croatia)

    2009-08-26T23:59:59.000Z

    Differential cross sections of {sup 6,7}Li+{sup 7}Li nuclear reactions have been measured at forward angles (10 deg. and 20 deg.), using particle identification detector telescopes, over the energy range 2.75-10.00 MeV. Excitation functions have been obtained for low-lying residual-nucleus states. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) at beam energy about 8 MeV, first observed by Wyborny and Carlson in 1971 at 0 deg., has been observed at 10 deg., but is less evident at 20 deg. The cross section obtained for the {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(g.s,0{sup +}) reaction is about ten times smaller. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) reaction could correspond to excited states in {sup 14}C, at excitation energies around 30 MeV.

  13. Tracking Cardinality Distributions in Network Aiyou Chen, Li Li and Jin Cao

    E-Print Network [OSTI]

    Li, Li Erran

    Tracking Cardinality Distributions in Network Traffic Aiyou Chen, Li Li and Jin Cao Bell Labs distributions of distinct communicating peers or flows. For example, during the worm outbreak, the port scanning in the host distributions of distinct communicating peers or flows. In this paper, we develop an efficient

  14. REGULAR ARTICLE Variational grand-canonical electronic structure of Li+Li

    E-Print Network [OSTI]

    Baer, Roi

    , is applied to the di-lithium (Li?Li) system at temperatures around T & 104 K and electronic chemical the other is ``spin polarized''. This crossing causes near-dis- continuous jumps in calculated properties in strong laser interaction with matter, nuclear and shock- wave physics, astrophysics, and liquid metals [1

  15. Minimum-Energy Topology Control Algorithms in Ad Hoc Joseph Y. Halpern Li (Erran) Li

    E-Print Network [OSTI]

    Halpern, Joseph Y.

    for an extended period of time. In order to accomplish this without a renewable energy source, energy conservationMinimum-Energy Topology Control Algorithms in Ad Hoc Networks1 Joseph Y. Halpern Li (Erran) Li Dept Holmdel, NJ 07733 halpern@cs.cornell.edu erranlli@dnrc.bell-labs.com August 7, 2004 1 Based on "Minimum-Energy

  16. pH-dependent leaching of dump coal ash - retrospective environmental analysis

    SciTech Connect (OSTI)

    Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

    2009-07-01T23:59:59.000Z

    Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

  17. Treatment technologies for hazardous ashes generated from possible incineration of navy waste. Technical note

    SciTech Connect (OSTI)

    Torres, T.

    1990-10-01T23:59:59.000Z

    The Navy recognizes that thermal treatment of Navy hazardous wastes (HW) should, under the terms of the Resource Conservation and Recovery Act of 1976, be avoided. Combustion waste disposal may nonetheless become unavoidable in certain cases, even after all possible process enhancements that avoid HW production are implemented. Even then, some toxic constituents that may be present in the waste will not be destroyed by incineration and will persist in the ash residue produced by incineration. Such incinerator ashes will have to be disposed of in HW landfills. The Navy is thus evaluating methods of treatment of such ash to remove or immobilize the toxic constituents that persist following incineration in order to render the waste treatment residue nonhazardous. Appropriate technology identified in this work can be applied to ash produced by HW combuster operated by the Navy, if any, or be required for ash produced by commercial generators handling Navy HWs.

  18. Use of rubber and bentonite added fly ash as a liner material

    SciTech Connect (OSTI)

    Cokca, Erdal; Yilmaz, Zeka

    2004-07-01T23:59:59.000Z

    In many countries regulations require all hazardous waste disposal facilities to be lined with suitable impermeable barriers to protect against contamination. In this study, a series of laboratory tests on rubber and bentonite added fly ash were conducted. The aim of the tests was to evaluate the feasibility of utilizing fly ash, rubber and bentonite as a low hydraulic conductivity liner material. Type C fly ash was obtained from Soma thermal power plant in Turkey; rubber in pulverized form was waste from the retreading industry. To investigate the properties of rubber and bentonite added fly ash, hydraulic conductivity, leachate analysis, unconfined compression, split tensile strength, one-dimensional consolidation, swell and freeze/thaw cycle tests were performed. The overall evaluation of results have revealed that rubber and bentonite added fly ash showed good promise and a candidate for construction of a liner.

  19. In situ analysis of ash deposits from black liquor combustion

    SciTech Connect (OSTI)

    Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

    1996-05-01T23:59:59.000Z

    Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

  20. Evaluation of rice husk ash as filler in tread compounds

    SciTech Connect (OSTI)

    Fernandes, M. R. S., E-mail: monica.fernandes@lanxess.com [Lanxess Elastômeros do Brasil S.A., Brasil and Instituto de Química, Universidade do Estado do Rio de Janeiro (UERJ) (Brazil); Furtado, C. R. G., E-mail: russi@globo.com, E-mail: ana.furtado.sousa@gmail.com; Sousa, A. M. F. de, E-mail: russi@globo.com, E-mail: ana.furtado.sousa@gmail.com [Instituto de Química, Universidade do Estado do Rio de Janeiro (UERJ) (Brazil)

    2014-05-15T23:59:59.000Z

    Rice which is one of the largest agriculture crops produces around 22% of rice rusk during its milling process. This material is mainly used as fuel for energy generation, which results in an ash, which disposal represents an environmental issue. The rice husk ash (RHA) contains over than 70% of silica in an amorphous form and a lot of applications is being developed for it all over the world. The use of silica as a filler in the tire industry is growing since it contributes significantly to the reduction of fuel consumption of the automobiles, allowing at the same time better traction (safety). This paper presents an evaluation of the use of RHA as filler in rubber tread compounds prepared in lab scale and compares its performance with compounds prepared with commercial silica and carbon black, the fillers normally used in tire industry. Mechanical and rheological properties are evaluated, with emphasis for tan delta as an indicator of tread performance related with rolling resistance (fuel consumption) and wet grip/traction (safety)

  1. 488-D Ash Basin Vegetative Cover Treatibility Study

    SciTech Connect (OSTI)

    Barton, Christopher; Marx, Don; Blake, John; Adriano, Domy; Koo, Bon-Jun; Czapka, Stephen

    2003-01-01T23:59:59.000Z

    The 488-D Ash Basin is an unlined containment basin that received ash and coal reject material from the operation of a powerhouse at the USDOE's Savannah River Site, SC. They pyretic nature of the coal rejects has resulted in the formation of acidic drainage (AD), which has contributed to groundwater deterioration and threatens biota in down gradient wetlands. Establishment of a vegetative cover was examined as a remedial alternative for reducing AD generation within this system by enhanced utilization of rainwater and subsequent non-point source water pollution control. The low nutrient content, high acidity, and high salinity of the basin material, however, was deleterious to plant survivability. As such, studies to identify suitable plant species and potential adaptations, and pretreatment techniques in the form of amendments, tilling, and/or chemical stabilization were needed. A randomized block design consisting of three subsurface treatments (blocks) and five duplicated surface amendments (treatments) was developed. One hundred inoculated pine trees were planted on each plot. Herbaceous species were also planted on half of the plots in duplicated 1-m2 beds. After two growing seasons, deep ripping, subsurface amendments and surface covers were shown to be essential for the successful establishment of vegetation on the basin. This is the final report of the study.

  2. Rate-dependent morphology of Li2O2 growth in Li-O2 batteries

    E-Print Network [OSTI]

    Horstmann, B; Mitchell, R; Bessler, W G; Shao-Horn, Y; Bazant, M Z

    2013-01-01T23:59:59.000Z

    Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter we develop a nanoscale continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes, based on a theory of electrochemical non-equilibrium thermodynamics originally applied to Li-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory predicts a transition from complex to uniform morphologies of Li2O2 with increasing current. Discrete particle growth at low discharge rates becomes suppressed at high rates, resulting in a film of electronically insulating Li2O2 that limits cell performance. We predict that the transition between these surface growth modes occurs at current densities close to the exchange current density of the cathode reaction, consistent with experimental observations.

  3. Coal fly ash basins as an attractive nuisance to birds: Parental provisioning exposes nestlings to harmful trace elements

    E-Print Network [OSTI]

    Hopkins, William A.

    inhabiting settling impoundments receiving slurried ash from a coal-fired power plant located on the U. SCoal fly ash basins as an attractive nuisance to birds: Parental provisioning exposes nestlings Keywords: Coal fly ash basin Common Grackle Contaminants Quiscalus quiscala Selenium a b s t r a c t Birds

  4. Evaluation of the effects of coal fly ash amendments on the toxicity of a contaminated marine sediment

    SciTech Connect (OSTI)

    Burgess, R.M.; Perron, M.M.; Friedman, C.L.; Suuberg, E.M.; Pennell, K.G.; Cantwell, M.G.; Pelletier, M.C.; Ho, K.T.; Serbst, J.R.; Ryba, S.A. [US EPA, Narragansett, RI (USA). Office for Research and Development

    2009-01-15T23:59:59.000Z

    Approaches for cleaning up contaminated sediments range from dredging to in situ treatment. In this study, we discuss the effects of amending reference and contaminated sediments with coal fly ash to reduce the bioavailability and toxicity of a field sediment contaminated with polycyclic aromatic hydrocarbons (PAHs). Six fly ashes and a coconut charcoal were evaluated in 7-d whole sediment toxicity tests with a marine amphipod (Ampelisca abdita) and mysid (Americamysis bahia). Fly ashes with high carbon content and the coconut charcoal showed proficiency at reducing toxicity. Some of the fly ashes demonstrated toxicity in the reference treatments. It is suspected that some of this toxicity is related to the presence of ammonia associated with fly ashes as a result of postoxidation treatment to reduce nitrous oxide emissions. Relatively simple methods exist to remove ammonia from fly ash before use, and fly ashes with low ammonia content are available. Fly ashes were also shown to effectively reduce overlying water concentrations of several PAHs. No evidence was seen of the release of the metals cadmium, copper, nickel, or lead from the fly ashes. A preliminary 28-d polychaete bioaccumulation study with one of the high-carbon fly ashes and a reference sediment was also performed. Although preliminary, no evidence was seen of adverse effects to worm growth or lipid content or of accumulation of PAHs or mercury from exposure to the fly ash. These data show fly ashes with high carbon content could represent viable remedial materials for reducing the bioavailability of organic contaminants in sediments.

  5. J. Marshall Ash Proceedings of the American Mathematical Society, Vol. 108, No. 2. (Feb., 1990), p. 571.

    E-Print Network [OSTI]

    Ash, J. Marshall

    Erratum J. Marshall Ash Proceedings of the American Mathematical Society, Vol. 108, No. 2. (Feb, February 1990 ERRATUM J. MARSHALL ASH The paper "A new proof of uniqueness for multiple trigonometric series" by J. Marshall Ash, which appeared in 107(2) October 1989, should have been entitled "A new proof

  6. County looks at turning waste ash into money Two companies using grant to investigate ways to recycle incinerator byproduct

    E-Print Network [OSTI]

    Columbia University

    in York County generates about 160,000 tons of ash per year, and attempts to dispose of it have caused Technology Inc. will seek to use the ash in synthetic stones called Brixx, which also re-use coal wasteCounty looks at turning waste ash into money Two companies using grant to investigate ways

  7. Feasible experimental study on the utilization of a 300 MW CFB boiler desulfurizating bottom ash for construction applications

    SciTech Connect (OSTI)

    Lu, X.F.; Amano, R.S. [University of Wisconsin, Milwaukee, WI (United States). Dept. of Mechanical Engineering

    2006-12-15T23:59:59.000Z

    CFB boiler ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. The disposal in landfills has been the most common means of handling ash in circulating fluidized bed boiler power plants. However for a 300 MW CFB boiler power plant, there will be 600,000 tons of ash discharged per year and will result in great volumes and disposal cost of ash byproduct. It was very necessary to solve the utilization of CFB ash and to decrease the disposal cost of CFB ash. The feasible experimental study results on the utilization of the bottom ashes of a 300 MW CFB boiler in Baima power plant in China were reported in this paper. The bottom ashes used for test came from the discharged bottom ashes in a 100 MW CFB boiler in which the anthracite and limestone designed for the 300 MW CFB project was burned. The results of this study showed that the bottom ash could be used for cementitious material, road concrete, and road base material. The masonry cements, road concrete with 30 MPa compressive strength and 4.0 MPa flexural strength, and the road base material used for base courses of the expressway, the main road and the minor lane were all prepared with milled CFB bottom ashes in the lab. The better methods of utilization of the bottom ashes were discussed in this paper.

  8. Metal Bioavailability and Speciation in a Wetland Tailings Repository Amended with Biosolids Compost, Wood Ash, and Sulfate

    E-Print Network [OSTI]

    Brown, Sally

    Compost, Wood Ash, and Sulfate Pam S. DeVolder, Sally L. Brown,* Dean Hesterberg, and Kumi Pandya ABSTRACT tundra swans surface amendments: (i) biosolids compost plus wood ash, (ii) and other animals found in the area have tested positive compost wood ash a low SO2 4 addition as K2SO4, and (iii) for Pb poisoning

  9. Kinetics of fly ash beneficiation by carbon burnout. Quarterly report, January--March 1996

    SciTech Connect (OSTI)

    Dodoo, J.N.; Okoh, J.M.; Yilmaz, E.

    1996-09-01T23:59:59.000Z

    The three year project that was proposed is a joint venture between Delmarva Power, a power generating company on the eastern shore of Maryland, and the University of Maryland Eastern Shore. The studies have focused on the benefication of fly ash by carbon burnout. The increasing use of coal fly ash as pozzolanic material in Portland cement concrete means that there is the highest economic potential in marketability of large volumes of fly ash. For the concrete industry to consider large scale use the fly ash must be of the highest quality. This means that the residual carbon content of the fly ash must have an acceptable loss on ignition (LOI) value, usually between 7-2% residual carbon. The economic gains to be had from low-carbon ash is a fact that is generally accepted by the electricity generating companies. However, since the cost of producing low-carbon in large quantities, based on present technology, far outweighs any financial gains, no electrical power company using coal as its fuel at present considers the effort worthwhile. The concrete industry would use fly ash in cement concrete mix if it can be assured of its LOI value. At present no utility company would give such assurance. Hence with several million tons of fly ash produced by a single power plant per year all that can be done is to dump the fly ash in landfills. The kinetics of fly ash benefication have been investigated in the zone II kinetic regime, using a Cahn TG 121 microbalance in the temperature 550-750{degrees}C. The P{sub O{sub 2}} and total surface area dependence of the reaction kinetics were determined using a vacuum accessory attached to the microbalance and a surface area analyzer (ASAP 2010), respectively. 16 refs., 7 figs., 3 tabs.

  10. Response of rice to ammonium and nitrate nitrogen applied at various stages of plant growth on limed and unlimed Beaumont and Lake Charles clays

    E-Print Network [OSTI]

    Gay, William Blalock, III

    1962-01-01T23:59:59.000Z

    RESPONSE OF RICE TO AMMONIUM AND NITRATE NITROGEN APPLIED AT VARIOUS STAGES OF PLANT GROWTH ON LIMED AND UNLINED BEAUNONT AND LAKE CHARLES CLAYS A Thesis By William B. Gay, III Submitted to the Graduate Sohool of the Agricultural... BEAUMONT AND LAKE CHARLES CLAYS A Thesis By Nilliam B. Gay, III Chairman of Committee Head of the Department of Soil Sc Crop Sciences ACKNOWLEDGEMENTS I would like to express my appreciation to Dr. A. G. Caldwell for his 1nterest and guidance...

  11. Evaluating the Effects of the Kingston Fly Ash Release on Fish Reproduction: Spring 2009 - 2010 Studies

    SciTech Connect (OSTI)

    Greeley Jr, Mark Stephen [ORNL; Adams, Marshall [ORNL; McCracken, Kitty [ORNL

    2012-05-01T23:59:59.000Z

    On December 22, 2008, a dike containing fly ash and bottom ash at the Tennessee Valley Authority's (TVA) Kingston Fossil Plant in East Tennessee failed and released a large quantity of ash into the adjacent Emory River. Ash deposits from the spill extended 4 miles upstream of the facility to Emory River mile 6 and downstream to Tennessee River mile 564 ({approx}8.5 miles downstream of the confluence of the Emory River with the Clinch River, and {approx}4 miles downstream of the confluence of the Clinch River with the Tennessee River). A byproduct of coal combustion, fly ash contains a variety of metals and other elements which, at sufficient concentrations and in specific forms, can be harmful to biological systems. The ecological effects of fly ash contamination on exposed fish populations depend on the magnitude and duration of exposure, with the most significant risk considered to come from elevated levels of certain metals in the ash, particularly selenium, on fish reproduction and fish early life stages (Lemly 1993; Besser and others 1996). The ovaries of adult female fish in a lake contaminated by coal ash were reported to have an increased frequency of atretic oocytes (dead or damaged immature eggs) and reductions in the overall numbers of developing oocytes (Sorensen 1988) associated with elevated body burdens of selenium. Larval fish exposed to selenium through maternal transfer of contaminants to developing eggs in either contaminated bodies of water (Lemly 1999) or in experimental laboratory exposures (Woock and others 1987, Jezierska and others 2009) have significantly increased incidences of developmental abnormalities. Contact of fertilized eggs and developing embryos to ash in water and sediments may also pose an additional risk to the early life stages of exposed fish populations through direct uptake of metals and other ash constituents (Jezierska and others 2009). The establishment and maintenance of fish populations is intimately associated with the ability of individuals within a population to reproduce. Reproduction is thus generally considered to be the most critical life function affected by environmental contamination. From a regulatory perspective, the issue of potential contaminant-related effects on fish reproduction from the Kingston fly ash spill has particular significance because the growth and propagation of fish and other aquatic life is a specific classified use of the affected river systems. To address the potential effects of fly ash from the Kingston spill on the reproductive health of exposed fish populations, ORNL has undertaken a series of studies in collaboration with TVA that include: (1) a combined field study of metal bioaccumulation in ovaries and other fish tissues (Adams and others 2012) and the reproductive condition of sentinel fish species in reaches of the Emory and Clinch Rivers affected by the fly ash spill (the current report); (2) laboratory tests of the potential toxicity of fly ash from the spill area on fish embryonic and larval development (Greeley and others 2012); (3) additional laboratory experimentation focused on the potential effects of long-term exposures to fly ash on fish survival and reproductive competence (unpublished); and (4) a combined field and laboratory study examining the in vitro developmental success of embryos and larvae obtained from fish exposed in vivo for over two years to fly ash in the Emory and Clinch Rivers (unpublished). The current report focuses on the reproductive condition of adult female fish in reaches of the Emory and Clinch Rivers influenced by the fly ash spill at the beginning of the spring 2009 breeding season - the first breeding season immediately following the fly ash release - and during the subsequent spring 2010 breeding season. Data generated from this and related reproductive/early life stage studies provide direct input to ecological risk assessment efforts and complement and support other phases of the overall biomonitoring program associated with the fly ash spill.

  12. JV Task 120 - Coal Ash Resources Research Consortium Research

    SciTech Connect (OSTI)

    Debra Pflughoeft-Hassett; Loreal Heebink; David Hassett; Bruce Dockter; Kurt Eylands; Tera Buckley; Erick Zacher

    2009-03-28T23:59:59.000Z

    The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') is the core coal combustion product (CCP) research group at the Energy & Environmental Research Center (EERC). CARRC focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of CCPs. CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCP utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program, which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCP performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 2007 to 2009 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCPs. The tasks were included in four categories: (1) Environmental Evaluations of CCPs; (2) Evaluation of Impacts on CCPs from Emission Controls; (3) Construction and Product-Related Activities; and (4) Technology Transfer and Maintenance Tasks. All tasks are designed to work toward achieving the CARRC overall goal and supporting objectives. The various tasks are coordinated in order to provide broad and useful technical data for CARRC members. Special projects provide an opportunity for non-CARRC members to sponsor specific research or technology transfer consistent with CARRC goals. This report covers CARRC activities from January 2007 through March 2009. These activities have been reported in CARRC Annual Reports and in member meetings over the past 2 years. CARRC continues to work with industry and various government agencies with its research, development, demonstration, and promotional activities nearing completion at the time of submission of this report. CARRC expects to continue its service to the coal ash industry in 2009 and beyond to work toward the common goal of advancing coal ash utilization by solving CCP-related technical issues and promoting the environmentally safe, technically sound, and economically viable management of these complex and changing materials.

  13. First-principles investigation of Li intercalation kinetics in phospho-olivines

    E-Print Network [OSTI]

    Malik, Rahul

    2013-01-01T23:59:59.000Z

    This thesis focuses broadly on characterizing and understanding the Li intercalation mechanism in phospho-olivines, namely LiFePO? and Li(Fe,Mn)PO?, using first-principles calculations. Currently Li-ion battery technology ...

  14. Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures

    DOE Patents [OSTI]

    Khan, M. Rashid (Morgantown, WV)

    1990-01-01T23:59:59.000Z

    A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated.

  15. Investigation of Fly Ash and Activated Carbon Obtained from Pulverized Coal Boilers

    SciTech Connect (OSTI)

    Edward K. Levy; Christopher Kiely; Zheng Yao

    2006-08-31T23:59:59.000Z

    One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addressed the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addressed the possible connection between SCR reactors, fly ash properties and Hg capture. The project has determined the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed have also been determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control have been analyzed in an effort to determine the effects of SCR on the ash.

  16. Regeneratively cooled coal combustor/gasifier with integral dry ash removal

    DOE Patents [OSTI]

    Beaufrere, Albert H. (Huntington, NY)

    1983-10-04T23:59:59.000Z

    A coal combustor/gasifier is disclosed which produces a low or medium combustion gas for further combustion in modified oil or gas fired furnaces or boilers. Two concentric shells define a combustion volume within the inner shell and a plenum between them through which combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

  17. A=8Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for 8Li) GENERAL: See also

  18. A=8Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for 8Li) GENERAL: See also

  19. A=8Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for 8Li) GENERAL: See

  20. Protection of Li Anodes Using Dual Phase Electrolytes

    Broader source: Energy.gov (indexed) [DOE]

    the laboratory scale Li-S cells. Partners BASF SE, Germany * Development of Li-S battery materials 3 Project Objectives * Develop a unique electrolyte providing two liquid phases...

  1. Hydrogen storage in LiH: A first principle study

    SciTech Connect (OSTI)

    Banger, Suman, E-mail: sumanphy28@gmail.com; Nayak, Vikas, E-mail: sumanphy28@gmail.com; Verma, U. P., E-mail: sumanphy28@gmail.com [School of Studies in Physics, Jiwaji University, Gwalior-474011 (India)

    2014-04-24T23:59:59.000Z

    First principles calculations have been performed on the Lithium hydride (LiH) using the full potential linearized augmented plane wave (FP-LAPW) method within the framework of density functional theory. We have extended our calculations for LiH+2H and LiH+6H in NaCl structure. The structural stability of three compounds have been studied. It is found that LiH with 6 added Hydrogen atoms is most stable. The obtained results for LiH are in good agreement with reported experimental data. Electronic structures of three compounds are also studied. Out of three the energy band gap in LiH is ?3.0 eV and LiH+2H and LiH+6H are metallic.

  2. Development of Li+ alumino-silicate ion source

    E-Print Network [OSTI]

    Roy, P.K.

    2009-01-01T23:59:59.000Z

    Development of a Li + alumino-silicate ion source ? P. K.kinetic energy. Alumino-silicates sources of K + and Cs +and sintering the Li alumino- silicate to the substrate to

  3. Lithium Source For High Performance Li-ion Cells

    Broader source: Energy.gov (indexed) [DOE]

    Designs: For Cell (Li5FeO4+LiV3O8) vs. Carbon Anode (with 5% Irreversible Loss) Composite Cathode Materials Potential to achieve higher energy density (Whkg and WhL) at...

  4. Petrography and chemistry of sized fly ash from low-sulfur and high-sulfur coal sources

    SciTech Connect (OSTI)

    Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Trimble, A.S. [Franklin County High School, Frankfort, KY (United States); Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Palmer, C. [Geological Survey, Reston, VA (United States)

    1996-12-31T23:59:59.000Z

    Fly ash samples were collected in November and December, 1994, from two units representing high- and low-sulfur feed coals at a Kentucky power station. The ashes were wet screened at 100, 200, 325, and 500 mesh. The dried ({approximately}40 C) fractions were then weighed, split for petrographic and chemical analysis, mounted in epoxy and prepared as polished pellets, and analyzed for ash yield and carbon content. The November ashes had a similar size distribution in the +325 mesh fractions. The low-sulfur hot side and cool side ashes had a similar size distribution in the November ashes. In contrast, the December fly ashes showed the typical trend, the cool-side ash being finer (over 20% more ash in the {minus}500 mesh fraction) than the hot-side ash. Carbon tends to be relatively concentrated in the coarse fractions. The dominance of the {minus}325 mesh fractions in the overall size analysis implies, though, that carbon in the fine sizes is an important consideration in the utilization potential of the fly ash.

  5. Scale-Up and Demonstration of Fly Ash Oxonation Technology

    SciTech Connect (OSTI)

    Larry LaBuz; Rui Afonso

    2005-06-30T23:59:59.000Z

    This is the fifth quarterly report under DOE Cooperative Agreement No.: DE-FC26-03NT41730. Due a number of circumstances, mostly associated with subcontractor agreements, the actual beginning of the project was delayed from its original award date of March 5, 2003. DOE's Project Manager was kept informed (verbally) by PPL's Project Manager throughout this period. Because of this delay, this is the fifth quarterly report and it refers to the time period from April-July 2005. (An additional month is included in this quarterly report as we have been in a data analyses mode and wanted to provide new data relative to the previous report). During this period, the project team has been reviewing and analyzing data from the onsite ozonation tests, as well as conducting additional laboratory ash and concrete tests. This report summarizes these activities including some preliminary results. No significant issues or concerns are identified.

  6. Improved Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas Edward

    2012-01-01T23:59:59.000Z

    commercial Li-ion batteries today use graphite or a mixturein certain primary batteries). Graphite has a potential of

  7. Sodium and oxygen in Nigerian coals: Possible effects on ash fouling

    SciTech Connect (OSTI)

    Ewa, I.O.B.; Elegbe, S.B.; Adetunji, J. [Ahmadu Bello Univ., Zaria (Nigeria)

    1996-09-01T23:59:59.000Z

    Ash fouling during heat transfers in coal power-plants has been known to be an engineering problem caused by high sodium levels of the feed-coals. Instrumental Neutron Activation Analysis (INAA) was used in determining the concentration of some alkali elements (Na, Ca, Mg) associated with ash fouling for eight Nigerian coals mined at Onyeama, Ogbete, Enugu, Gombe, Okaba, Afikpo, Lafia and Asaba. Sodium levels were generally low (0.001-0.036%). Oxygen concentrations considered as an indicative measure of the wettability of each of the coals were determined. The possible effects of the concentration of these elements on ash fouling were discussed. 8 refs., 3 tabs.

  8. The prospects for highbeta tokamaks with Li walls 1

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    . Why Li walls ? 2. Magnetic propulsion of liquid Li. 3. Plasma profiles in the non­recycling regime. 4 can be magnetically propulsed along the plasma facing surfaces in the tokamak chamber. This allows the stabilizing wall right at the plasma boundary. 2. Intense (V ' 20 m=sec) magnetic propulsion allows to keep Li

  9. Current collectors for rechargeable Li-Air batteries

    SciTech Connect (OSTI)

    Veith, Gabriel M [ORNL; Dudney, Nancy J [ORNL

    2011-01-01T23:59:59.000Z

    Here we report the negative influence of porous nickel foam for use as current collectors in rechargeable Li-air batteries. Uncoated nickel foam promotes the decomposition of LiPF6-organic carbonate electrolytes under normal charging conditions reported for rechargeable Li-air cells. We have identified Ni free porous carbon supports as more appropriate cathode current collectors.

  10. Corrosion of lithium in LiCl-LiOH-H/sub 2/O-system solutions

    SciTech Connect (OSTI)

    Demidov, A.I.; Kungurtsev, O.A.; Morachevskii, A.G.

    1988-07-10T23:59:59.000Z

    This communication presents the results of an investigation of the corrosion of lithium in solutions of the system LiCl-LiOH-H/sub 2/O at 298 K. The reaction rate of lithium with the electrolyte was calculated on the basis of volumetric measurements. The investigation was carried out in a standard electrochemical cell furnished with a branch pipe for the collection of hydrogen. The results demonstrated that in the absence of polarization the lithium corrosion rate decreased as the concentration of lithium chloride in the electrolyte increased, and also that at lower concentrations of LiOH, additions of LiCl exerted a stronger influence on the corrosion rate of the metal.

  11. A Critical Review of the Li Insertion Mechanisms in LiFePO[subscript 4] Electrodes

    E-Print Network [OSTI]

    Malik, Rahul

    With the ever-growing public and now commercial sentiment supporting the widespread adoption of low and zero-emission vehicles, it is unsurprising that Li-ion batteries which currently assume the bulk of the cost of ...

  12. Dingzeyu Li LE Schapiro (CEPSR), Columbia University

    E-Print Network [OSTI]

    Grinspun, Eitan

    Dingzeyu Li LE Schapiro (CEPSR), Columbia University West th St New York, NY , USA ( ) - dli@cs.columbia.edu http://www.cs.columbia.edu/~dli/ Education Columbia University, New York, USA Sept. - present - PhD Research, Advisor: Changxi Zheng, Columbia Computer Graphics Group, Columbia University, New York, Aug

  13. DlcSsoo |LI Metallurgy Department

    E-Print Network [OSTI]

    DlcSsoo |£LI s TT^rrrc^ G en 2 L-V I 7 Risø-R-523 Metallurgy Department Progress Report;Risø-R-523 METALLURGY DEPARTMENT PROGRESS REPORT FOR THE PERIOD 1 JANUARY TO 31 DECEMBER 1984 Abstract. The activities of the Metallurgy Department at Risø during 1984 are described. The work is presented in three

  14. Performance study of commercial LiCoO2 and spinel-based Li-ion cells

    E-Print Network [OSTI]

    Popov, Branko N.

    -ion cells and Sony 18650 cells using non-stoichiometric spinel and LiCoO2, respectively, as positive at the cathode and loss of active material at both electrodes due to electrolyte oxidation. For the Sony cells Science B.V. All rights reserved. Keywords: Li-ion cells; LiCoO2; Cell-Batt1 ; Capacity fade; Sony 18650

  15. Thermal Stability of Li-Ion Cells

    SciTech Connect (OSTI)

    ROTH,EMANUEL P.

    1999-09-17T23:59:59.000Z

    The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial SONY cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity in the open circuit cell condition. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC). Microcalorimetry was used to measure the time dependence of heat generating side reactions also as a function of SOC. Components of cells were measured using differential scanning calorimetry (DSC) to study the thermal reactivity of the individual electrodes to determine the temperature regimes and conditions of the major thermal reactions. Thermal decomposition of the SEI layer at the anodes was identified as the initiating source for thermal runaway. The cells with Li{sub x}CoO{sub 2} cathodes showed greater sensitivity to SOC and higher accelerating heating rates than seen for the cells with Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2}cathodes. Lower temperature reactions starting as low as 40 C were also observed that were SOC dependent but not accelerating. These reactions were also measured in the microcalorimeter and observed to decay over time with a power-law dependence and are believed to result in irreversible capacity loss in the cells.

  16. Kinetics of fly ash beneficiation by carbon burnout. Quarterly report, October 1996--December 1996

    SciTech Connect (OSTI)

    Dodoo, J.N.; Okoh, J.M.; Diaz, A. [and others

    1997-06-01T23:59:59.000Z

    The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called {open_quotes}Loss On Ignition{close_quotes} (LOI). The concrete producer`s day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

  17. STATE-OF-THE-ART: FLY ASH, SILICA FUME AND SLAG UTILIZATION IN USA

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    improvement, land reclamations, slurried flowable ash, water pollution control, etc. The medium technology Backfill. 1.0 Introduction At the present time, coal fired electric power plants in the USA produce

  18. FLY ASH GENERATION AND UTILIZATION -AN OVERVIEW* Tarun R. Naik, Ph.D., P.E.

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    from conventional as well as advanced coal combustion technologies are addressed. Constructive use improvement, land reclamation, slurried flowable ash, and water pollution control. The medium technology matrix composites, polymer matrix composites, and several other filler applications. INTRODUCTION Coal

  19. PREDICTIONS FOR STRESS-STRAIN BEHAVIOR OF PANKI FLY-ASH USING MODIFIED CAM CLAY MODEL

    E-Print Network [OSTI]

    Prashant, Amit

    -ash is a fine powdery silty material, produced by burning of coal at thermal power plants. It shows specific by slurry disposal technique. A series of triaxial compression tests have been performed on overconsolidated

  20. ash forming acid-resistant: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ash Dieback Update Date: Tuesday 26th March 2013 Time: 1400 - 1700hrs Location: Stirling Management Centre University of Stirling Stirling FK9 4LA To attend please return the...

  1. Iron distribution among phases in high- and low-sulfur coal fly ash

    SciTech Connect (OSTI)

    Hower, J.C.; Graham, U.M.; Rathbone, R.F. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Dyar, M.D.; Taylor, M.E. [West Chester Univ., PA (United States). Dept. of Geology and Astronomy

    1995-12-31T23:59:59.000Z

    Moessbauer spectroscopy, reflected-light optical microscopy, scanning-electron microscopy, wet chemical, and X-ray diffraction studies were conducted on six fly ash samples. The fly ashes, representing the combustion by-products of coals with total sulfur contents of less than 2% to greater than 4%, ranged from 17.6 to 32.0% Fe{sub 2}O{sub 3} by XRF analysis. Wet chemical analysis was used to determine the Fe{sup 3+}/{summation}Fe content of the ashes, which ranged from 72% to 83%. Optical analysis of the ashes indicated that the spinel, encompassing iron oxides of various compositions, ranges from 4.0 to 12.6% (vol.). Moessbauer analyses confirmed the presence of three Fe-bearing phases: magnetite, hematite (possibly of two different compositions), and glass. The variation in the Fe-oxidation state follows the variation in the sulfur, consequently pyrite, content of the feed coal.

  2. Notes on the efficacy of wet versus dry screening of fly ash

    SciTech Connect (OSTI)

    Valentim, B.; Hower, J.C.; Flores, D.; Guedes, A. [Center and Department of Geology, Oporto (Portugal)

    2008-08-15T23:59:59.000Z

    The methodology used to obtain fly ash subsamples of different sizes is generally based on wet or dry sieving methods. However, the worth of such methods is not certain if the methodology applied is not mentioned in the analytical procedure. After performing a fly ash mechanical dry, sieving, the authors compared those results with the ones obtained by laser diffraction on the same samples and found unacceptable discrepancies. A preliminary, study of a wet sieving analysis carried out on an economizer fly ash sample showed that this method was more effective than the dry sieving. The importance of standardizing the way samples are handled, pretreated and presented to the instrument of analysis are suggested and interlaboratory reproducibility trials are needed to create a common standard methodology to obtain large amounts of fly ash size fraction subsamples.

  3. Apparatus having inductively coupled coaxial coils for measuring buildup of slay or ash in a furnace

    DOE Patents [OSTI]

    Mathur, Mahendra P. (Pittsburgh, PA); Ekmann, James M. (Bethel Park, PA)

    1989-01-01T23:59:59.000Z

    The buildup of slag or ash on the interior surface of a furnace wall is monitored by disposing two coils to form a transformer which is secured adjacent to the inside surface of the furnace wall. The inductive coupling between the two coils of the transformer is affected by the presence of oxides of iron in the slag or ash which is adjacent to the transformer, and the application of a voltage to one winding produces a voltage at the other winding that is related to the thickness of the slag or ash buildup on the inside surface of the furnace wall. The output of the other winding is an electrical signal which can be used to control an alarm or the like or provide an indication of the thickness of the slag or ash buildup at a remote location.

  4. Lubricant-derived ash : in-engine sources and opportunities for reduction

    E-Print Network [OSTI]

    Watson, Simon A. G. (Simon Andrew Glean)

    2010-01-01T23:59:59.000Z

    Diesel particulate filters (DPF) are an effective means for meeting increasingly stringent emissions regulations that limit particulate matter. Over time, ash primarily derived from metallic additives in the engine oil ...

  5. Leaching of Metals from Fly ash-Amended Permeable Reactive Barriers Doina L. Morar 1

    E-Print Network [OSTI]

    Aydilek, Ahmet

    (Petzrick 2001). Unfortunately, this HCC fly ash cannot be beneficially reused in the construction industry organic and inorganic pollutants. Specific reactive materials such as wood chips, limestone, manure (USEPA

  6. Removal of radium from acidic solutions containing same by adsorption on coal fly ash

    DOE Patents [OSTI]

    Scheitlin, Frank M. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    The invention is a process for the removal of radium from acidic aqueous solutions. In one aspect, the invention is a process for removing radium from an inorganic-acid solution. The process comprises contacting the solution with coal fly ash to effect adsorption of the radium on the ash. The radium-containing ash then is separated from the solution. The process is simple, comparatively inexpensive, and efficient. High radium-distribution coefficients are obtained even at room temperature. Coal fly ash is an inexpensive, acid-resistant, high-surface-area material which is available in large quantities throughout the United States. The invention is applicable, for example, to the recovery of .sup.226 Ra from nitric acid solutions which have been used to leach radium from uranium-mill tailings.

  7. E-Print Network 3.0 - ash management regulations Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    REGULATOR IN PORTLAND CEMENT 6 Traditionally about 3 to 5% gypsum is inter... of clean-coal ash (CCA) was used to replace gypsum as a setting time regulator and mineral...

  8. Review of WTE ash utilization processes under development in northwest Europe Athanasios Bourtsalas

    E-Print Network [OSTI]

    ferrous and non-ferrous, and also minerals from incinerator bottom ash (IBA). Also, since water systems for the discharged IBA has increased metal extraction efficiency and quality of residues

  9. aluminum-fly ash metal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Journal of Composite Materials, July 2006, Vol. 40 no. 13, 1163-1174 1163 Thermal Expansion of AluminumFly Ash...

  10. Comparison of photosynthetic responses of Ashe juniper and live oak on the Edwards Plateau, Texas 

    E-Print Network [OSTI]

    Bendevis, Mira Arpe

    2009-06-02T23:59:59.000Z

    gas exchange and water relations at the leaf level of the two dominant tree species, Ashe juniper and live oak (Quercus virginiana P. Mill. Var. fusiformis), is important to assess the impact of juniper encroachment on the aquifer. Photosynthesis...

  11. Is there a bound dineutron in {sup 11}Li?

    SciTech Connect (OSTI)

    Ieki, K.; Galonsky, A.; Sackett, D.; Kruse, J.J.; Lynch, W.G.; Morrissey, D.J.; Orr, N.A.; Sherrill, B.M.; Winger, J.A. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)] [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Deak, F.; Horvath, A.; Kiss, A. [Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7, H-1088 Budapest 8 (Hungary)] [Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7, H-1088 Budapest 8 (Hungary); Seres, Z. [Central Research Institute for Physics, Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary)] [Central Research Institute for Physics, Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary); Kolata, J.J. [Physics Department, University of Notre Dame, Notre Dame, Indiana 46556 (United States)] [Physics Department, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Warner, R.E. [Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States)] [Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States); Humphrey, D.L. [Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States)] [Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States)

    1996-10-01T23:59:59.000Z

    Photodisintegration of {sup 11}Li was accomplished by sending a beam of {sup 11}Li at 28 MeV/nucleon through the equivalent photon field of a lead target. By measuring the complete kinematics of the disintegration products, {sup 9}Li+{ital n}+{ital n}, we constructed the correlation of the angle between the two neutrons in the rest frame of the {sup 11}Li. The correlation is independent of angle. This result argues against the existence of a bound dineutron in the ground state of {sup 11}Li. {copyright} {ital 1996 The American Physical Society.}

  12. Making Li-air batteries rechargeable: material challenges

    SciTech Connect (OSTI)

    Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

    2013-02-25T23:59:59.000Z

    A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

  13. Influence of age/size and grazing history on understory relationships of Ashe juniper

    E-Print Network [OSTI]

    Fuhlendorf, Samuel Dean

    1992-01-01T23:59:59.000Z

    INFLUENCE OF AGE/SIZE AND GRAZING HISTORY ON UNDERSTORY RELATIONSHIPS OF ASHE JUNIPER A Thesis by SAMUEL DEAN FUHLENDORF Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE August 1992 Major Subject: Rangeland Ecology and Management INFLUENCE OF AGE/SIZE AND GRAZING HISTORY ON UNDERSTORY RELATIONSHIPS OF ASHE JUNIPER A Thesis by SAMUEL DEAN FUHLENDORF Approved as to style and content by...

  14. Investigation of the potential of fly ash as an adsorbent for removal of priority pollutants

    E-Print Network [OSTI]

    Zardkoohi, Minoo

    1993-01-01T23:59:59.000Z

    . Aydin Akgerman Adsorption isotherms for adsorption of phenol, p-chlorophenol, 2, 4, dichlorophenol, cadmium and lead from water onto fly ash were determined. These isotherms were modeled by the Freundlich isotherm. The value of Freundlich isotherm..., parameter n indicated that the adsorption isotherms for contaminants studied were unfavorable. Phenol displayed a much higher aAinity for fly ash than chlorophenol and 2, 4 dichlorophenol Adsorption isotherms for the trace metals studied were slightly...

  15. The use of sulfer modified bottom ash (SMBA) as an aggregate in asphaltic mixtures

    E-Print Network [OSTI]

    Chimakurthy, Harshavardhan

    1998-01-01T23:59:59.000Z

    , bottom ash is lighter in weight and generally much cheaper than conventional quality aggregates such as limestone, sand and gravel. This research was designed to up-grade the load-bearing charactcnstics of bottom ash and maximize its usc m asphaltic... and gravel. According to a study done by Hafizuddin Ahmad in 1974, sulfur was used extensively in sand-asphalt sulfur to upgrade marginal aggregates for use in asphaltic mixtures, was developed at Texas Transportation Institute (TT1) (JO). TTI's work...

  16. Electrolyte effects in Li(Si)/FeS{sub 2} thermal batteries

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.

    1994-10-01T23:59:59.000Z

    The most common electrochemical couple for thermally activated (``thermal``) batteries is the Li-alloy/FeS{sub 2} system. The most common Li-alloys used for anodes are 20% Li-80% Al and 44% Li-56% Si (by weight); liquid Li immobilized with iron powder has also been used. The standard electrolyte that has been used in thermal batteries over the years is the LiCl-KCl eutectic that melts at 352{degrees}C. The LiCl-LiBr-LiF eutectic had the best rate and power characteristics. This electrolyte melts at 436{degrees}C and shows very low polarization because of the absence of Li+ gradients common with the LiCl-KCl eutectic. The low-melting electrolytes examined included a KBr-LiBr-LiCl eutectic (melting at 321{degrees}C), a LiBr-KBr-LiF eutectic (melting at 313{degrees}C), and a CsBr-LiBr-KBr eutectic (melting at 238{degrees}C). The CsBr-based salt had poor conductivity and was not studied further. The LiBr-KBr-LiF eutectic outperformed the KBr-LiBr-LiCl eutectic and was selected for more extensive testing. Because of their lower melting points and larger liquidi relative to the LiCl-KCl eutectic, the low-melting electrolytes are prime candidates for long-life applications (i.e., for activated lives of one hour or more). This paper will detail the relative performance of the Li(Si)/FeS{sub 2} couple using primarily the LiCl-KCl (standard) eutectic, the LiCl-LiBr-LiF (all-Li) eutectic, and the LiBr-KBr-LiF (low-melting) eutectic electrolytes. Most of the tests were conducted with 5-cell batteries; validation tests were also carried out with appropriate full-sized batteries.

  17. Investigation of fly ash carbon by thermal analysis and optical microscopy

    SciTech Connect (OSTI)

    Hill, R. [Boral Material Technologies Inc., San Antonio, TX (United States)] [Boral Material Technologies Inc., San Antonio, TX (United States); Rathbone, R.; Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research] [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1998-10-01T23:59:59.000Z

    A previous study investigated various fly ashes that had comparable loss on ignition values, but significant differences with respect to air entrainment performance. Thermal analysis data suggested that a poorly performing fly ash, with respect to air entrainment, contained a higher proportion of carbon that gasifies (oxidizes) at comparatively low temperatures. A relatively high abundance of isotropic carbon was identified in the poor-performing ash using optical microscopy. The present investigation examined a larger collection of fly ash samples to determine if thermal analysis could be used as a prognostic tool for fly ash performance. An attempt was made to correlate mortar air and foam index values for each sample with differential thermal analysis (DTA) data. Optical microscopy and BET surface area analysis were used as supportive techniques. No clear relationship could be established with the thermal or optical methods, although fly ash performance did correlate well with BET surface area. A low temperature component of the DTA exotherms was considered to be a function of inorganic catalytic species that reside on the carbon surface and lower the ignition temperature.

  18. Effect of temperature on the hydration of Portland cement blended with siliceous fly ash

    SciTech Connect (OSTI)

    Deschner, Florian, E-mail: florian.deschner@gmail.com [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland)] [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Lothenbach, Barbara; Winnefeld, Frank [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland)] [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Neubauer, Jürgen [GeoZentrum Nordbayern, Mineralogy, University of Erlangen-Nuremberg, 91054 Erlangen (Germany)] [GeoZentrum Nordbayern, Mineralogy, University of Erlangen-Nuremberg, 91054 Erlangen (Germany)

    2013-10-15T23:59:59.000Z

    The effect of temperature on the hydration of Portland cement pastes blended with 50 wt.% of siliceous fly ash is investigated within a temperature range of 7 to 80 °C. The elevation of temperature accelerates both the hydration of OPC and fly ash. Due to the enhanced pozzolanic reaction of the fly ash, the change of the composition of the C–S–H and the pore solution towards lower Ca and higher Al and Si concentrations is shifted towards earlier hydration times. Above 50 °C, the reaction of fly ash also contributes to the formation of siliceous hydrogarnet. At 80 °C, ettringite and AFm are destabilised and the released sulphate is partially incorporated into the C–S–H. The observed changes of the phase assemblage in dependence of the temperature are confirmed by thermodynamic modelling. The increasingly heterogeneous microstructure at elevated temperatures shows an increased density of the C–S–H and a higher coarse porosity. -- Highlights: •The reaction of quartz powder at 80 °C strongly enhances the compressive strength. •Almost no strength increase of fly ash blended OPC at 80 °C was found after 2 days. •Siliceous hydrogarnet is formed upon the reaction of fly ash at high temperatures. •Temperature dependent change of the system was simulated by thermodynamic modelling. •Destabilisation of ettringite above 50 °C correlates with sulphate content of C–S–H.

  19. Selenium And Arsenic Speciation in Fly Ash From Full-Scale Coal-Burning Utility Plants

    SciTech Connect (OSTI)

    Huggins, F.E.; Senior, C.L.; Chu, P.; Ladwig, K.; Huffman, G.P.; /Kentucky U. /Reaction Engin. Int. /Elect. Power Res. Inst., Palo Alto

    2007-07-09T23:59:59.000Z

    X-ray absorption fine structure spectroscopy has been used to determine directly the oxidation states and speciation of selenium and arsenic in 10 fly ash samples collected from full-scale utility plants. Such information is needed to assess the health risk posed by these elements in fly ash and to understand their behavior during combustion and in fly ash disposal options, such as sequestration in tailings ponds. Selenium is found predominantly as Se(IV) in selenite (SeO{sub 3}{sup 2-}) species, whereas arsenic is found predominantly as As(V) in arsenate (AsO{sub 4}{sup 3-}) species. Two distinct types of selenite and arsenate spectra were observed depending upon whether the fly ash was derived from eastern U.S. bituminous (Fe-rich) coals or from western subbituminous or lignite (Ca-rich) coals. Similar spectral details were observed for both arsenic and selenium in the two different types of fly ash, suggesting that the post-combustion behavior and capture of both of these elements are likely controlled by the same dominant element or phase in each type of fly ash.

  20. The Laconia, New Hampshire bottom ash paving project: Volume 3, Physical Performance Testing Report

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    Bottom ash is the principal waste stream from the combustion of municipal solid waste (MSW). It is comprised of grate ash (97%), the slag material discharged at the end of the grate system, and grate sifting (3%), the material that melts or falls through the grate structure. This project was conducted to demonstrate the feasibility of using municipal solid waste grate ash as an aggregate substitute in the construction of a pavement binder course for a portion of Rt. 3 in Laconia, New Hampshire. The research was conducted over a two year period during 1993 and 1994. This study is the culmination of an earlier two year characterization study between 1990 and 1992 that documented the physical and environmental characteristics of the bottom ash as it was produced at the Concord, N.H. waste-to-energy (@) facility and used in an asphaltic binder course. Together, these two studies provide a complete evaluation of the potential for using grate ash or bottom ash in asphalt binder course or as recycled asphalt pavement (RAP) in base courses in pavements.

  1. Encapsulation of mixed radioactive and hazardous waste contaminated incinerator ash in modified sulfur cement

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1990-01-01T23:59:59.000Z

    Some of the process waste streams incinerated at various Department of Energy (DOE) facilities contain traces of both low-level radioactive (LLW) and hazardous constituents, thus yielding ash residues that are classified as mixed waste. Work is currently being performed at Brookhaven National Laboratory (BNL) to develop new and innovative materials for encapsulation of DOE mixed wastes including incinerator ash. One such material under investigation is modified sulfur cement, a thermoplastic developed by the US Bureau of Mines. Monolithic waste forms containing as much as 55 wt % incinerator fly ash from Idaho national Engineering Laboratory (INEL) have been formulated with modified sulfur cement, whereas maximum waste loading for this waste in hydraulic cement is 16 wt %. Compressive strength of these waste forms exceeded 27.6 MPa. Wet chemical and solid phase waste characterization analyses performed on this fly ash revealed high concentrations of soluble metal salts including Pb and Cd, identified by the Environmental Protection Agency (EPA) as toxic metals. Leach testing of the ash according to the EPA Toxicity Characteristic Leaching Procedure (TCLP) resulted in concentrations of Pb and Cd above allowable limits. Encapsulation of INEL fly ash in modified sulfur cement with a small quantity of sodium sulfide added to enhance retention of soluble metal salts reduced TCLP leachate concentrations of Pb and Cd well below EPA concentration criteria for delisting as a toxic hazardous waste. 12 refs., 4 figs., 2 tabs.

  2. EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS

    SciTech Connect (OSTI)

    Glenn A. Norton

    1999-10-01T23:59:59.000Z

    Tests were performed in simulated flue gas streams using two fly ash samples from the electrostatic precipitators of two full-scale utility boilers. One fly ash was derived from a Powder River Basin (PRB) coal, while the other was derived from Blacksville coal (Pittsburgh No. 8 seam). The tests were performed at temperatures of 120 and 180 C under different gas compositions. Elemental mercury (Hg) streams were injected into the simulated flue gas and passed over filters (housed in a convection oven) loaded with fly ash. The Ontario Hydro method was used to determine the total amount of Hg passing through the filter as well as the percentages of elemental and oxidized Hg collected. Results indicated that substantial amounts of Hg oxidation did not occur with either fly ash, regardless of the temperature used for testing. When oxidation was observed, the magnitude of the oxidation was comparable between the two fly ashes. These results suggest that the gas matrix may be more important than the ash components with respect to the distribution of Hg species observed in gaseous effluents at coal-fired power plants.

  3. Models of neutron star atmospheres enriched with nuclear burning ashes

    E-Print Network [OSTI]

    Nättilä, Joonas; Kajava, Jari J E; Poutanen, Juri

    2015-01-01T23:59:59.000Z

    Low-mass X-ray binaries hosting neutron stars (NS) exhibit thermonuclear (type-I) X-ray bursts, which are powered by unstable nuclear burning of helium and/or hydrogen into heavier elements deep in the NS "ocean". In some cases the burning ashes may rise from the burning depths up to the NS photosphere by convection, leading to the appearance of the metal absorption edges in the spectra, which then force the emergent X-ray burst spectra to shift toward lower energies. These effects may have a substantial impact on the color correction factor $f_c$ and the dilution factor $w$, the parameters of the diluted blackbody model $F_E \\approx w B_E(f_c T_{eff})$ that is commonly used to describe the emergent spectra from NSs. The aim of this paper is to quantify how much the metal enrichment can change these factors. We have developed a new NS atmosphere modeling code, which has a few important improvements compared to our previous code required by inclusion of the metals. The opacities and the internal partition func...

  4. 488-4D ASH LANDFILL CLOSURE CAP HELP MODELING

    SciTech Connect (OSTI)

    Phifer, M.

    2014-11-17T23:59:59.000Z

    At the request of Area Completion Projects (ACP) in support of the 488-4D Landfill closure, the Savannah River National Laboratory (SRNL) has performed Hydrologic Evaluation of Landfill Performance (HELP) modeling of the planned 488-4D Ash Landfill closure cap to ensure that the South Carolina Department of Health and Environmental Control (SCDHEC) limit of no more than 12 inches of head on top of the barrier layer (saturated hydraulic conductivity of no more than 1.0E-05 cm/s) in association with a 25-year, 24-hour storm event is not projected to be exceeded. Based upon Weber 1998 a 25-year, 24-hour storm event at the Savannah River Site (SRS) is 6.1 inches. The results of the HELP modeling indicate that the greatest peak daily head on top of the barrier layer (i.e. geosynthetic clay liner (GCL) or high density polyethylene (HDPE) geomembrane) for any of the runs made was 0.079 inches associated with a peak daily precipitation of 6.16 inches. This is well below the SCDHEC limit of 12 inches.

  5. Hydration studies of calcium sulfoaluminate cements blended with fly ash

    SciTech Connect (OSTI)

    García-Maté, M.; De la Torre, A.G. [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain)] [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain); León-Reina, L. [Servicios Centrales de Apoyo a la Investigación, Universidad de Málaga, 29071 Málaga (Spain)] [Servicios Centrales de Apoyo a la Investigación, Universidad de Málaga, 29071 Málaga (Spain); Aranda, M.A.G. [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain) [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain); CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain); Santacruz, I., E-mail: isantacruz@uma.es [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain)

    2013-12-15T23:59:59.000Z

    The main objective of this work is to study the hydration and properties of calcium sulfoaluminate cement pastes blended with fly ash (FA) and the corresponding mortars at different hydration ages. Laboratory X-ray powder diffraction, rheological studies, thermal analysis, porosimetry and compressive strength measurements were performed. The analysis of the diffraction data by Rietveld method allowed quantifying crystalline phases and overall amorphous contents. The studied parameters were: i) FA content, 0, 15 and 30 wt.%; and ii) water addition, water-to-CSA mass ratio (w/CSA = 0.50 and 0.65), and water-to-binder mass ratio (w/b = 0.50). Finally, compressive strengths after 6 months of 0 and 15 wt.% FA [w/CSA = 0.50] mortars were similar: 73 ± 2 and 72 ± 3 MPa, respectively. This is justified by the filler effect of the FA as no strong evidences of reactivity of FA with CSA were observed. These results support the partial substitution of CSA cements with FA with the economic and environmental benefits.

  6. Characteristics of fly ashes from full-scale coal-fired power plants and their relationship to mercury adsorption

    SciTech Connect (OSTI)

    Yongqi Lu; Massoud Rostam-Abadi; Ramsay Chang; Carl Richardson; Jennifer Paradis [Illinois State Geological Survey, Champaign, IL (United States)

    2007-08-15T23:59:59.000Z

    Nine fly ash samples were collected from the particulate collection devices of four full-scale pulverized coal utility boilers burning eastern bituminous coals and three cyclone utility boilers burning either Powder River Basin coals or PRB blends. As-received fly ash samples were mechanically sieved to obtain six size fractions. Unburned carbon content, mercury content, and Brunauer-Emmett-Teller surface areas of as-received fly ashes and their size fractions were measured. In addition, UBC particles were examined by scanning electron microscopy, high-resolution transmission microscopy, and thermogravimetry to obtain information on their surface morphology, structure, and oxidation reactivity. It was found that the UBC particles contained amorphous carbon, ribbon-shaped graphitic carbon, and highly ordered graphite structures. The mercury contents of the UBCs in raw ash samples were comparable to those of the UBC-enriched samples, indicating that mercury was mainly adsorbed on the UBC in fly ash. The UBC content decreased with a decreasing particle size range for all nine ashes. The mercury content of the UBCs in each size fraction, however, generally increased with a decreasing particle size for the nine ashes. The mercury contents and surface areas of the UBCs in the PRB-CYC ashes were about 8 and 3 times higher than UBCs in the EB-PC ashes, respectively. It appeared that both the particle size and surface area of UBC could contribute to mercury capture. The particle size of the UBC in PRB-CYC ash and thus the external mass transfer was found to be the major factor impacting the mercury adsorption. Both the particle size and surface reactivity of the UBC in EB-PC ash, which generally had a lower carbon oxidation reactivity than the PRB-PC ashes, appeared to be important for the mercury adsorption. 26 refs., 16 figs., 2 tabs.

  7. Trophic structure and metal bioaccumulation differences in multiple fish species exposed to coal ash-associated metals

    SciTech Connect (OSTI)

    Otter, Ryan [Middle Tennessee State University; Bailey, Frank [Middle Tennessee State University; Fortner, Allison M [ORNL; Adams, Marshall [ORNL

    2012-01-01T23:59:59.000Z

    On December 22, 2008 a dike containing coal fly ash from the Tennessee Valley Authority Kingston Fossil Plant near Kingston Tennessee USA failed and resulted in the largest coal ash spill in U.S. history. Coal ash, the by-product of coal combustion, is known to contain multiple contaminants of concern, including arsenic and selenium. The purpose of this study was to investigate the bioaccumulation of arsenic and selenium and to identify possible differences in trophic dynamics in feral fish at various sites in the vicinity of the Kingston coal ash spill. Elevated levels of arsenic and selenium were observed in various tissues of largemouth bass, white crappie, bluegill and redear sunfish from sites associated with the Kingston coal ash spill. Highest concentrations of selenium were found in redear sunfish with liver concentrations as high as 24.83 mg/kg dry weight and ovary concentrations up to 10.40 mg/kg dry weight at coal ash-associated sites. To help explain the elevated selenium levels observed in redear sunfish, investigations into the gut pH and trophic dynamics of redear sunfish and bluegill were conducted which demonstrated a large difference in the gut physiology between these two species. Redear sunfish stomach and intestinal pH was found to be 1.1 and 0.16 pH units higher than in bluegill, respectively. In addition, fish from coal ash-associated sites showed enrichment of 15N & 13C compared to no ash sites, indicating differences in food web dynamics between sites. These results imply the incorporation of coal ash-associated compounds into local food webs and/or a shift in diet at ash sites compared to the no ash reference sites. Based on these results, further investigation into a broader food web at ash-associated sites is warranted.

  8. Spectroscopy of Lambda-9Li by electroproduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; et al

    2015-03-01T23:59:59.000Z

    Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e?K+)Li?9 reaction. Method: Electroproduction of the hypernucleus Li?9 has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a Be9 target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The crossmore »section to low-lying states of Li?9 is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.36±0.08 (stat.) ±0.08 (syst.) MeV was measured, in agreement with an earlier experiment.« less

  9. Spectroscopy of Lambda-9Li by electroproduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; Boeglin, W. U.; Breuer, H.; Brindza, P.; Bydzovsky, P.; Camsonne, A.; Chang, C. C.; Chen, J. -P.; Choi, Seonho; Chudakov, E. A.; Cisbani, E.; Colilli, S.; Coman, L.; Craver, B. J.; De Cataldo, G.; de Jager, C. W.; De Leo, R.; Deur, A. P.; Ferdi, C.; Feuerbach, R. J.; Folts, E.; Fratoni, R.; Frullani, S.; Garibaldi, F.; Gayou, O.; Giuliani, F.; Gomez, J.; Gricia, M.; Hansen, J. O.; Hayes, D.; Higinbotham, D. W.; Holmstrom, T. K.; Hyde, C. E.; Ibrahim, H. F.; Iodice, M.; Jiang, X.; Kaufman, L. J.; Kino, K.; Kross, B.; Lagamba, L.; LeRose, J. J.; Lindgren, R. A.; Lucentini, M.; Margaziotis, D. J.; Markowitz, P.; Meziani, Z. E.; McCormick, K.; Michaels, R. W.; Millener, D. J.; Miyoshi, T.; Moffit, B.; Monaghan, P. A.; Moteabbed, M.; Camacho, C. Munoz; Nanda, S.; Nappi, E.; Nelyubin, V. V.; Norum, B. E.; Okasyasu, Y.; Paschke, K. D.; Perdrisat, C. F.; Piasetzky, E.; Punjabi, V. A.; Qiang, Y.; Reimer, P. E.; Reinhold, J.; Reitz, B.; Roche, R. E.; Rodriguez, V. M.; Saha, A.; Santavenere, F.; Sarty, A. J.; Segal, J.; Shahinyan, A.; Singh, J.; Sirca, S.; Snyder, R.; Solvignon, P. H.; Sotona, M.; Subedi, R.; Sulkosky, V. A.; Suzuki, T.; Ueno, H.; Ulmer, P. E.; Veneroni, P.; Voutier, E.; Wojtsekhowski, B. B.; Zheng, X.; Zorn, C.

    2015-03-01T23:59:59.000Z

    Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e?K+)Li?9 reaction. Method: Electroproduction of the hypernucleus Li?9 has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a Be9 target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The cross section to low-lying states of Li?9 is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.36±0.08 (stat.) ±0.08 (syst.) MeV was measured, in agreement with an earlier experiment.

  10. Predicting the Operating Behavior of Ceramic Filters from Thermo-Mechanical Ash Properties

    SciTech Connect (OSTI)

    Hemmer, G.; Kasper, G.

    2002-09-19T23:59:59.000Z

    Stable operation, in other words the achievement of a succession of uniform filtration cycles of reasonable length is a key issue in high-temperature gas filtration with ceramic media. Its importance has rather grown in recent years, as these media gain in acceptance due to their excellent particle retention capabilities. Ash properties have been known for some time to affect the maximum operating temperature of filters. However, softening and consequently ''stickiness'' of the ash particles generally depend on composition in a complex way. Simple and accurate prediction of critical temperature ranges from ash analysis--and even more so from coal analysis--is still difficult without practical and costly trials. In general, our understanding of what exactly happens during break-down of filtration stability is still rather crude and general. Early work was based on the concept that ash particles begin to soften and sinter near the melting temperatures of low-melting, often alkaline components. This softening coincides with a fairly abrupt increase of stickiness, that can be detected with powder mechanical methods in a Jenicke shear cell as first shown by Pilz (1996) and recently confirmed by others (Kamiya et al. 2001 and 2002, Kanaoka et al. 2001). However, recording {sigma}-{tau}-diagrams is very time consuming and not the only off-line method of analyzing or predicting changes in thermo-mechanical ash behavior. Pilz found that the increase in ash stickiness near melting was accompanied by shrinkage attributed to sintering. Recent work at the University of Karlsruhe has expanded the use of such thermo-analytical methods for predicting filtration behavior (Hemmer 2001). Demonstrating their effectiveness is one objective of this paper. Finally, our intent is to show that ash softening at near melting temperatures is apparently not the only phenomenon causing problems with filtration, although its impact is certainly the ''final catastrophe''. There are other significant changes in regeneration at intermediate temperatures, which may lead to long-term deterioration.

  11. On-line carbon-in-ash monitors: Survey and demonstration

    SciTech Connect (OSTI)

    Sorge, J.; Larrimore, L.

    1998-02-01T23:59:59.000Z

    Fly ash unburned carbon (UBC) level is an important consideration for combustion efficiency as well as ash marketing. The presence of unburned carbon in fly ash has been shown to be a function of furnace design, coal quality, the ability of the pulverizer to grind the coal, and heat release rate. Boilers are designed to take these factors into consideration. However, the Clean Air Act Amendments of 1990 drove many utilities to switch coal supplies and install low NO{sub x} burners. Higher carbon-in-ash levels have been the result of these changes in coal quality and the staged combustion characteristics associated with low NO{sub x} burners. Over the past few years, several instruments for the on-line determination and monitoring of the unburned carbon content of ash samples have been developed. However, to date they have not been deployed widely in the U.S. despite potential uses for combustion optimization and as an aid in fly ash marketing. Based on the lack of publicly available performance and operation data available for the current CIAM (carbon-in-ash monitor) commercial offerings, Southern Company initiated a demonstration of several commercial technologies on its coal-fired units. As part of a DOE Clean Coal Project demonstrating advanced wall-fired combustion techniques for the reduction on NO{sub x} emissions from coal-fired boilers, the CAM, SEKAM and FOCUS systems were installed at Georgia Power Company`s Plant Hammond Unit 4. CAM and M&W instruments were also placed at Alabama Power Company`s Plant Gaston Unit 4. The testing of the instruments was conducted from November 1995 through August 1996.

  12. Experimental simulation of internal short circuit in Li-ion and Li-ion-Polymer cells

    SciTech Connect (OSTI)

    Cai, Wei [ORNL; Wang, Hsin [ORNL; Maleki, Hossein [Motorola Mobility; Howard, Jason [Motorola Mobility; Lara-Curzio, Edgar [ORNL

    2011-01-01T23:59:59.000Z

    A multi-parameter controlled pinch test was developed to study the occurrence of internal short circuits in Li-ion and Li-ion-polymer cells. By tuning the control parameters (i.e., cell voltage as well as pinching area, load, and speed), the pinch test can reproducibly create ~1 to 2 mm wide internal short between a cell jelly-roll s inner layer electrodes. This recreates conditions similar to those that may occur during service. Furthermore, the pinch test is used to determine thermal stability of two Li-ion-polymer cells of different designs built by the same manufacturer. The pinch test method can be used to help distinguish cells with design features or characteristics that lower risk of potential thermal events created by internal short circuits.

  13. Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1

    E-Print Network [OSTI]

    Zhou, Yaoqi

    Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1 , Wen Chao Lee1 This study demonstrates the feasibility of using water and the contents of waste Li-ion batteries for the electrodes in a Li-liquid battery system. Li metal was collected electrochemically from a waste Li

  14. Li overlayer formation, oxidation and sputtering characteristics of Al-Li alloys and W/Al-Li composites for fusion applications

    SciTech Connect (OSTI)

    Krauss, A.R. (Argonne National Lab., IL (USA)); DeWald, A.B.; Scott, P.; Savage, H. (Corium Industries, Inc., Atlanta, GA (USA))

    1990-01-01T23:59:59.000Z

    The next generation of long pulse fusion devices will impose severe requirements on the properties of plasma-facing materials. In devices such as ITER, a divertor design is being considered, using a divertor plate which would be either tungsten or a low-Z material such as graphite or beryllium. Strongly segregating lithium alloys have been proposed as a means of producing a self-sustaining low-Z overlayer which lowers plasma Z{sub eff} and resists self-sputtering. Aluminum-lithium alloys are among the better-characterized lithium-bearing alloys, and it has been demonstrated that lithium segregates strongly in aluminum. However, aluminum has a relatively low melting point, and for low lithium concentrations, the lithium diffusion rate is too slow to replenish lithium at the rate at which it is eroded by the incoming plasma. It has been suggested previously that the superionic {beta} phase Al-Li alloy (48--54 at. % Li) should have high enough diffusivity to be able to replenish surface lithium, and that incorporation of the {beta}-phase AlLi in a composite with tungsten would provide high temperature strength and melt layer stability, along with significantly better thermal conductivity than pure tungsten. Such a composite has been fabricated, as well as a variation containing titanium as a means of controlling oxidation at grain boundaries. The Li overlayer formation, erosion, and replenishment are characterized for the {beta}-phase LiAl alloy, and W-AlLi and W-Ti-AlLi composites. It is found that if there is no oxide layer to inhibit the Li segregation, Li diffusion is extremely rapid, and an oxygen-free Li overlayer is formed which is stable under continuous ion beam sputtering. 21 refs., 7 figs.

  15. Combined SO{sub 2}/NO{sub x} control using ferrous{center_dot}EDTA and a secondary additive in a lime-based aqueous scrubber system

    SciTech Connect (OSTI)

    Mendelsohn, M.H.; Livengood, C.D.; Harkness, J.B.L.

    1991-12-01T23:59:59.000Z

    Integration of NO{sub x} control into existing flue-gas desulfurization (FGD) systems addresses site-specific control requirements while minimizing retrofit difficulties. Argonne has studied the use of the metal-chelate additives, such as ferrous{center_dot}EDTA in various wet FGD chemistries, to promote combined SO{sub 2}/NO{sub x} scrubbing. A major process problem is oxidation of the iron to the ferric species, leading to a significant decrease in NO{sub x}-removal capability. Argonne discovered a class of organic compounds that, when used with ferrous{center_dot}EDTA in a sodium carbonate chemistry, could maintain high levels of NO{sub x} removal. However, those antioxidant/reducing agents are not effective in a lime-based chemistry, and a broader investigation of antioxidants was initiated. This paper discusses results of that investigation, which found a practical antioxidant/reducing agent capable of maintaining NO{sub x} removals of about 50% (compared with about 15% without the agent) in a lime-based FGD chemistry with FE(II){center_dot}EDTA. 5 refs., 10 figs.

  16. Combined SO sub 2 /NO sub x control using ferrouster dot EDTA and a secondary additive in a lime-based aqueous scrubber system. [Sodium ascorbate

    SciTech Connect (OSTI)

    Mendelsohn, M.H.; Livengood, C.D.; Harkness, J.B.L.

    1991-01-01T23:59:59.000Z

    Integration of NO{sub x} control into existing flue-gas desulfurization (FGD) systems addresses site-specific control requirements while minimizing retrofit difficulties. Argonne has studied the use of the metal-chelate additives, such as ferrous{center dot}EDTA in various wet FGD chemistries, to promote combined SO{sub 2}/NO{sub x} scrubbing. A major process problem is oxidation of the iron to the ferric species, leading to a significant decrease in NO{sub x}-removal capability. Argonne discovered a class of organic compounds that, when used with ferrous{center dot}EDTA in a sodium carbonate chemistry, could maintain high levels of NO{sub x} removal. However, those antioxidant/reducing agents are not effective in a lime-based chemistry, and a broader investigation of antioxidants was initiated. This paper discusses results of that investigation, which found a practical antioxidant/reducing agent capable of maintaining NO{sub x} removals of about 50% (compared with about 15% without the agent) in a lime-based FGD chemistry with FE(II){center dot}EDTA. 5 refs., 10 figs.

  17. TREATMENT OF CYANIDE SOLUTIONS AND SLURRIES USING AIR-SPARGED HYDROCYCLONE (ASH) TECHNOLOGY

    SciTech Connect (OSTI)

    Jan D. Miller; Terrence Chatwin; Jan Hupka; Doug Halbe; Tao Jiang; Bartosz Dabrowski; Lukasz Hupka

    2003-03-31T23:59:59.000Z

    The two-year Department of Energy (DOE) project ''Treatment of Cyanide Solutions and Slurries Using Air-Sparged Hydrocyclone (ASH) Technology'' (ASH/CN) has been completed. This project was also sponsored by industrial partners, ZPM Inc., Elbow Creek Engineering, Solvay Minerals, EIMCO-Baker Process, Newmont Mining Corporation, Cherokee Chemical Co., Placer Dome Inc., Earthworks Technology, Dawson Laboratories and Kennecott Minerals. Development of a new technology using the air-sparged hydrocyclone (ASH) as a reactor for either cyanide recovery or destruction was the research objective. It was expected that the ASH could potentially replace the conventional stripping tower presently used for HCN stripping and absorption with reduced power costs. The project was carried out in two phases. The first phase included calculation of basic processing parameters for ASH technology, development of the flowsheet, and design/adaptation of the ASH mobile system for hydrogen cyanide (HCN) recovery from cyanide solutions. This was necessary because the ASH was previously used for volatile organics removal from contaminated water. The design and modification of the ASH were performed with the help from ZPM Inc. personnel. Among the modifications, the system was adapted for operation under negative pressure to assure safe operating conditions. The research staff was trained in the safe use of cyanide and in hazardous material regulations. Cyanide chemistry was reviewed resulting in identification of proper chemical dosages for cyanide destruction, after completion of each pilot plant run. The second phase of the research consisted of three field tests that were performed at the Newmont Mining Corporation gold cyanidation plant near Midas, Nevada. The first field test was run between July 26 and August 2, 2002, and the objective was to demonstrate continuous operation of the modified ASH mobile system. ASH units were applied for both stripping and absorption, to recover cyanide, using the acidification-volatilization-reabsorption chemistry. Plant barren cyanide solution was used during the field tests. The original ASH system used for the field tests had been designed and fabricated by ZPM Inc. to remove volatile organic compounds from ground water. The system, even with a number of modifications, could not operate at optimum conditions for cyanide recovery. Reactors and pumps installed in the mobile system only allowed for the treatment of clear solutions, not slurries. Also the original mobile system was limited with respect to Q, the relative air flow rate, and the extent of recovery in a single stage. Due to the lack of automatic controls, the system required constant supervision of the University of Utah (U/U) team. In spite of these difficulties, application of the ASH mobile system was particularly attractive due to compactness of the apparatus and less than 1 second residence time of the aqueous phase in the cyclones. The performance of the ASH system was evaluated by comparison with theoretical predictions.

  18. Bioaccumulation Studies Associated with the Kingston Fly Ash Spill, Spring 2009 - Fall 2010

    SciTech Connect (OSTI)

    Adams, Marshall [ORNL; Brandt, Craig C [ORNL; Fortner, Allison M [ORNL

    2012-05-01T23:59:59.000Z

    In December 2008, an ash dike at the Tennessee Valley Authority (TVA) Kingston Fossil Plant ruptured, releasing over one billion gallons of coal fly ash into the Emory and Clinch Rivers. Coal fly ash may contain several contaminants of concern, but of these selenium (Se) and arsenic (As) have been highlighted because of their toxicity and tendency to bioaccumulate in aquatic food chains. To assess the potential impact of the spilled fly ash on humans and the environment, a comprehensive biological and environmental monitoring program was established, for which resident aquatic organisms (among other sample media) are collected to determine contaminant exposure and evaluate the risk to humans and wildlife. Studies on bioaccumulation and fish health are major components of the TVA Biological Monitoring Program for the Kingston fly ash project. These studies were initiated in early Spring 2009 for the purposes of: (1) documenting the levels of fly ash-associated metals in various tissues of representative sentinel fish species in the area of the fly ash spill, (2) determining if exposure to fly ash-associated metals causes short, intermediate, or long-term health effects on these sentinel fish species, (3) assessing if there are causal relationships between exposure (to metals) and effects on fish, (4) evaluating, along with information regarding other ecological and physicochemical studies, the nature and route of contaminant transfer though food chains into higher level consumers, (5) providing important information for the Ecological Risk Assessment (ERA) for the Kingston fly ash project, and (6) serving as an important technology transfer or model study focused on how to best evaluate the environmental effects of fly ash, not only at the Kingston site, but also at sites on other aquatic systems where coal-fired generating stations are located. This report summarizes the bioaccumulation results from the first two years of study after the fly ash spill, including four seasonal collections: Spring 2009, Fall 2009, Spring 2010, and Fall 2010. Both the Spring and Fall studies have focused on 3-4 sentinel fish species that represent different feeding habits, behaviors, and home ranges. In addition to bioaccumulation studies, the Spring investigations also included evaluation of fish health and reproductive integrity on the same fish used for bioaccumulation. Two associated reports present the fish health (Adams et al 2012) and reproductive studies (Greeley et al 2012) conducted in 2009 and 2010. The fish health study conducted in conjunction with the bioaccumulation and reproductive study is critical for assessing and evaluating possible causal relationships between contaminant exposure (bioaccumulation) and the response of fish to exposure as reflected by the various measurements of fish health. This report emphasizes evaluation of arsenic and selenium bioaccumulation in fish and consists of four related studies (Sections 2-5) including, (1) bioaccumulation in liver and ovaries, (2) bioaccumulation in whole body gizzard shad (Dorosoma cepedianum), (3) bioaccumulation in muscle tissue or fillets, and (4) a reconstruction analysis which establishes the relationship between selenium in muscle tissue and that of the whole body of bluegill (Lepomis machrochirus). Metals other than arsenic and selenium are evaluated separately in Section 6. This report focuses on selenium and arsenic for the following reasons: (1) based on baseline studies conducted in early 2009 in the Emory and Clinch River, only two potentially fly-ash related metals, selenium and arsenic, appeared to be elevated above background or reference levels, (2) selenium and arsenic are two of the metals in coal ash that are known to bioaccumulate and cause toxicity in wildlife, and (3) based on bioaccumulation studies of bluegill and carp (Cyprinus carpio) in the Stilling Pond during Spring 2009, which would represent a worst case situation for metal bioaccumulation, selenium and arsenic were the only two metals consistently elevated above background levels in fish. E

  19. Four-year prospective study of the respiratory effects of volcanic ash from Mt. St. Helens

    SciTech Connect (OSTI)

    Buist, A.S.; Vollmer, W.M.; Johnson, L.R.; Bernstein, R.S.; McCamant, L.E.

    1986-04-01T23:59:59.000Z

    This report describes the 4-yr follow-up of 712 loggers exposed over an extended period to varying levels of fresh volcanic ash from the 1980 eruptions of Mt. St. Helens. Concerns related to the irritant effect the ash might have on the airways and also to its fibrogenic potential if exposures were intense and continued over many years. Our subjects were divided into 3 groups: high, low, and no exposure. Baseline testing was begun in June 1980, 1 month after the major eruption, and follow-up testing continued on an annual basis through 1984; 88% of the loggers have been tested at least 3 times. Analysis of lung function data showed that a significant, exposure-related decline in FEV1 occurred during the first year after the eruption. The decline was short-lived, however, and by 1984 the differences between exposure groups were no longer significant. Self-reported symptoms of cough, phlegm, and wheeze showed a similar pattern. No ash-related changes were seen in chest roentgenograms taken in 1980 and in 1984. Our findings are consistent with the hypothesis that the inhaled ash caused mucus hypersecretion and/or airway inflammation that reversed when the exposure levels decreased. The ash levels to which the loggers were exposed were low compared with permissible occupational levels for nuisance dusts, but generally higher than the total suspended particulate levels permissible in ambient air.

  20. Coal Fly Ash as a Source of Iron in Atmospheric Dust

    SciTech Connect (OSTI)

    Chen, Haihan; Laskin, Alexander; Baltrusaitis, Jonas; Gorski, Christopher A.; Scherer, Michelle; Grassian, Vicki H.

    2012-01-18T23:59:59.000Z

    Anthropogenic coal fly ash aerosols may represent a significant source of bioavailable iron in the open ocean. Few measurements have been made to compare the solubility of atmospheric iron from anthropogenic aerosols and other sources. We report an investigation of the iron dissolution of three fly ash samples in acidic aqueous solutions and compare the solubilities with that of Arizona test dust, a reference material of mineral dust. The effects of pH, cloud processing, and solar irradiation on Fe solubility were explored. Similar to previously reported results on mineral dust, iron in aluminosilicate phases provide predominant dissolved iron compared with iron in oxides. Iron solubility of fly ash is higher than Arizona test dust, especially at the higher pH conditions investigated. Simulated atmospheric processing elevates iron solubility due to significant changes in the morphology aluminosilicate glass, a dominantly material in fly ash particle. Iron continuously releases into the aqueous solution as fly ash particles break up into smaller fragments. The assessment of dissolved atmospheric iron deposition fluxes, and their effect on the biogeochemistry at ocean surface should be constrained by taking into account the source, environment pH, Fe speciation, and solar radiation.

  1. Investigation of MSWI fly ash melting characteristic by DSC-DTA

    SciTech Connect (OSTI)

    Li, Rundong [Institute of Clean Energy and Environmental Engineering, Liaoning Key Laboratory of Clean Energy, Shenyang Institute of Aeronautical Engineering, Shenyang 110136 (China)], E-mail: leerd@mail.tsinghua.edu.cn; Wang, Lei; Yang, Tianhua; Raninger, Bernhard [Institute of Clean Energy and Environmental Engineering, Liaoning Key Laboratory of Clean Energy, Shenyang Institute of Aeronautical Engineering, Shenyang 110136 (China)

    2007-07-01T23:59:59.000Z

    The melting process of MSWI (Municipal Solid Waste Incineration) fly ash has been studied by high-temperature DSC-DTA experiments. The experiments were performed at a temperature range of 20-1450 deg. C, and the considerable variables included atmosphere (O{sub 2} and N{sub 2}), heating rates (5 deg. C/min, 10 deg. C/min, 20 deg. C/min) and CaO addition. Three main transitions were observed during the melting process of fly ash: dehydration, polymorphic transition and fusion, occurring in the temperature range of 100-200 deg. C, 480-670 deg. C and 1101-1244 deg. C, respectively. The apparent heat capacity and heat requirement for melting of MSWI fly ash were obtained by DSC (Differential Scanning Calorimeter). A thermodynamic modeling to predict the heat requirements for melting process has been presented, and it agrees well with the experimental data. Finally, a zero-order kinetic model of fly ash melting transition was established. The apparent activation energy of MSWI fly ash melting transition was obtained.

  2. Sorption of cadmium and lead by clays from municipal incinerator ash-water suspensions

    SciTech Connect (OSTI)

    Roy, W.R.; Krapac, I.G.; Steele, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1993-07-01T23:59:59.000Z

    The effect of Cl complexation in extracts of a flue gas-scrubber incinerator fly ash sample on the sorption of Cd and Ph by kaolinite and illite was investigated using batch-sorption methods. In the pH range of 5 to 9, Cl complexation may reduce sorption and thus increase the mobility of these metals. When an ash-water suspension was acidified to pH 6.85, the dissolution of Cl and Ca essentially eliminated Cd sorption because of complexation and cationic competition. Cadmium would be considered as either mobile or very mobile under these conditions. Lead was not soluble in the pH-6.85 suspension. At pH 12, the approximate pH of water in contact with flue gas-scrubber fly ash, Cd was essentially insoluble and Ph occurred as anionic Ph hydroxide. Anionic Ph was sorbed by the two clays, and the extent of sorption was not influenced by Cl or carbonate complexation. Sorption constants, derived from isotherms, suggested that Ph would be relatively immobile in saturated soil-water systems. The recent concern that highly alkaline, flue gas-scrubber fly ash may release environmentally significant concentrations of mobile Ph when placed in an ash-disposal site with a soil liner should be reevaluated in light of this study. 37 refs., 6 figs., 3 tabs.

  3. Characterization of Li-ion Batteries using Neutron Diffraction...

    Broader source: Energy.gov (indexed) [DOE]

    Li-ion batteries Using Neutron Diffraction and Infrared Imaging Techniques: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2011 Vehicle...

  4. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio...

  5. Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry via Scanning Ion Conductance Microscopy A. L. Lipson, R. S. Ginder, and M. C. Hersam, Northwestern University...

  6. Characterization of Materials for Li-ion Batteries: Success Stories...

    Broader source: Energy.gov (indexed) [DOE]

    Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2010 Vehicle Technologies Annual Merit Review and Peer...

  7. LiU E-Press Newsletter Autumn, 2008

    E-Print Network [OSTI]

    Zhao, Yuxiao

    to Increase Biogas Yields by Anders Ek was one of the winners. For more information about LiU E-Press and how

  8. Fly ash-enhanced aluminum composites for automotive parts. [Reports for April to June, 1998, and July to September, 1998

    SciTech Connect (OSTI)

    Golden, Dean; Rohatgi, Pradeep

    1998-10-15T23:59:59.000Z

    The objectives of this report are to produce and evaluate the use of aluminum ''ashalloys''--metal matrix composites that incorporate coal fly ash--in the commercial manufacture of cast automotive parts. Some highlights are: (1) Ashalloy ingot with ''C'' type fly ash was synthesized using stir casting techniques similar to the successful castings of ''F'' type fly ash. Agglomeration was noted. Stirring periods were increased up to 45 minutes compared to the normal 5 minutes to determine whether the shear force of stirring would disagglomerate the clusters noted with this type of fly ash. The resulting sample showed clustering. (2) The ashalloy ingots of ''C'' type fly ash were remelted and poured into permanent molds using a cloth filter to screen out clusters. There was no major reduction in clusters of fly ash particles in the composite since the filter with the mesh size larger than 1 x 1 mm was used. The composite melt would not flow through when filters with smaller openings were used. (3) The fly ash sample from Wisconsin Electric Power Company was sent for classification. (4) A 1 lb. sample of JTM-processed fly ash was sent to Wisconsin Electric Power Company for classification and 10 lb. of same fly ash was sent to The Jet Pulverizer Company for jet milling. (5) Experiments on fly ash pretreatment as well as synthesis of ash alloy are continuing. (6) Attempts are being made to apply high speed shear mixing with selected liquids to disperse the clusters noted in ashalloy with the ''C'' type fly ash base. Stir casting processes have been developed to incorporate type ''F'' fly ash of different sizes and measuring tensile data on cast bars. This data enables selection of the optimum size of fly ash to meet specific property requirements. Attempts are underway to develop stir casting techniques to incorporate ''C'' type fly ash in cast aluminum alloys. It is expected that the next milestone for making trial parts will be completed on schedule by June 1999.

  9. Suppression of fine ash formation in pulverized coal flames. Final technical report, September 30, 1992--January 31, 1996

    SciTech Connect (OSTI)

    Kramlich, J.C.; Chenevert, B.; Park, Jungsung; Hoffman, D.A.; Butcher, E.K.

    1996-07-19T23:59:59.000Z

    Coal ash, and particularly fine fly ash, remain one of the principal practical and environmental problems in coal-based power generation. In particular, submicron aerosols are identified with direct inhalation risk. Submicron ash is thought to arise from mineral vaporization during char combustion, followed by nucleation, condensation and coagulation to yield an aerosol. While aerosols are predominantly made out of volatile alkali minerals, they also can include refractory oxides that are chemically reduced to more volatile forms within the char particle and vaporized. Most of the ash of size greater than 1 {mu}m is generated by agglomeration of mineral as the char particle bums out. These two principal mechanisms are thought to account for most of the ash generated in coal combustion. Previous research has shown that various forms of coal treatment can influence the yields of fine ash from combustion. The research reported here investigates various forms of treatment, including physical coal cleaning, aerodynamic sizing, degree of grinding, and combinations of these on both aerosol yields and on yields of fine residual ash (1-4 {mu}m). The work also includes results from the combustion of artificial chars that include individual mineral elements. This research shows that these various forms of coal treatment can significantly change ash characteristics. While none of the treatments affected the bulk of the residual ash size distribution significantly, the yield of the ash aerosol mode (d<0.5 {mu}m) and fine residual ash mode (1-4 {mu}m) are changed by the treatments.

  10. Characterization of ash residues from 15 waste-to-energy facilities pursuant to the May, 1994 U.S. EPA ``Sampling and analysis of municipal refuse incineration ash`` guidance document

    SciTech Connect (OSTI)

    Berry, J.; Lyons, M. [Wheelabrator Environmental Systems Inc., Hampton, NH (United States)

    1996-12-31T23:59:59.000Z

    Wheelabrator Environmental Systems Inc. (Wheelabrator) currently owns and/or operates 21 power plants, 15 of which are municipal waste combustion (MWC) facilities. In response to a May, 1994 US Supreme Court decision, all MWC facilities are required by the US Environmental Protection (EPA) to determine if the facility ash residues are hazardous waste. This paper presents the results of ash characterizations done at Wheelabrator MWC facilities. All Wheelabrator MWC facilities are equipped with WES-PHix{reg_sign} ash stabilization systems. The ash from these facilities consistently yields test results well below regulatory thresholds. However, installing a state-of-the-art ash stabilization system does not guarantee that ash is accurately characterized. Proper sampling protocols and proper analytical technique are critical to insuring accurate characterization. This paper identifies typical issues encountered during sample collection, sample preparation, an toxicity test extraction procedures. The consistently low toxicity test results for ash from Wheelabrator facilities can be attributed to the effectiveness of the WES-PHix{reg_sign} ash stabilization process. The sample collection protocols developed by Wheelabrator, and proper toxicity test extraction and analytical procedures followed by the laboratories, ensure accurate characterization.

  11. Liming Terminology and Analysis

    E-Print Network [OSTI]

    Balser, Teri C.

    Neutralizing power per weight of material relative to pure CaCO3 CaCO3 + 2H+ Ca2+ + CO2 + H2O Ca(OH)2 + 2H+ Ca2 Recommendation in IA 6 inch incorporation depth Buffer pH Target pH 6.5 Target pH 6.9 ----- CaCO3 to apply (lb

  12. Novel Laser-Based Manufacturing of nano-LiFePO4-Based Materials for High Power Li Ion Batteries

    E-Print Network [OSTI]

    Horne, Craig R.; Jaiswal, Abhishek; Chang, On; Crane, S.; Doeff, Marca M.; Wang, Emile

    2006-01-01T23:59:59.000Z

    17-18, 2007 Novel Laser-Based Manufacturing of nano-LiFePO 4laser-based process for synthesizing nanomaterials, NanoParticle Manufacturing (

  13. Novel Laser-Based Manufacturing of nano-LiFePO4-Based Materials for High Power Li Ion Batteries

    E-Print Network [OSTI]

    Horne, Craig R.; Jaiswal, Abhishek; Chang, On; Crane, S.; Doeff, Marca M.; Wang, Emile

    2006-01-01T23:59:59.000Z

    II “Olivines in Lithium Batteries” The Beckman Institute,for High Power Li Ion Batteries C.R. Horne 1 , A. Jaiswal

  14. Momentum distributions for ([sup 11]Li, [sup 9]Li+[ital n]+[ital n]) breakup reactions

    SciTech Connect (OSTI)

    Esbensen, H.; Bertsch, G.F.; Ieki, K. (Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States) Physics Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States) Institute of Nuclear Theory and Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-07-01T23:59:59.000Z

    We have calculated the momentum distributions of the three fragments emitted in the breakup reaction ([sup 11]Li,[sup 9]Li+[ital n]+[ital n]), induced by the Coulomb field from a heavy target, and made comparisons to recent three-body coincidence measurements. Our three-body model for [sup 11]Li provides a good description of the measured relative momentum distribution for the two emitted neutrons, and also for the single-neutron momentum distribution. The predicted distribution for the [sup 9]Li recoil is much narrower than observed; a plausible explanation is presented.

  15. Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4

    E-Print Network [OSTI]

    Bazant, Martin Z.

    Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4 Betar continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory

  16. Petrography and chemistry of high-carbon fly ash from the Shawnee Power Station, Kentucky

    SciTech Connect (OSTI)

    Hower, J.C.; Thomas, G.A.; Robertson, J.D.; Wong, A.S. [Univ. of Kentucky, Lexington, KY (United States); Clifford, D.S.; Eady, J.D. [Tennessee Valley Authority, Chattanooga, TN (United States)

    1996-01-01T23:59:59.000Z

    The Shawnee power station in western Kentucky consists of ten 150-MW units, eight of which burn low-sulfur (< 1 wt %) eastern Kentucky and central West Virginia coal. The other units burn medium- and high-sulfur (> 1 wt %) coal in an atmospheric fluidized-bed combustion unit and in a research unit. The eight low-sulfur coal units were sampled in a 1992 survey of Kentucky utilities. Little between-unit variation is seen in the ash-basis major oxide and minor element chemistry. The carbon content of the fly ashes varies from 5 to 25 wt %. Similarly, the isotropic and anisotropic coke in the fly ash varies from 6% to 42% (volume basis). Much of the anisotropic coke is a thin-walled macroporous variety, but there is a portion that is a thick-walled variety similar to a petroleum coke.

  17. Petrography and chemistry of fly ash from the Shawnee Power Station, Kentucky

    SciTech Connect (OSTI)

    Hower, J.C.; Thomas, G.A.; Wild, G.D. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Clifford, D.S.; Eady, J.D. [Tennessee Valley Authority, Chattanooga, TN (United States)

    1994-12-31T23:59:59.000Z

    The Shawnee Power Station in western Kentucky consists of ten 150 MW units, eight of which burn low-sulfur eastern Kentucky and central West Virginia coal. The other units bum medium and high-sulfur coal in an AFBC unit and in a research unit. The eight low-sulfur coal units were sampled in a 1992 survey of Kentucky utilities. Little between-unit variation is seen in the ash-basis major oxide and minor element chemistry. The carbon content of the fly ashes varies from 5 to 25%. Similarly, the isotropic and anisotropic coke in the fly ash varies from 6 to 42% (volume basis). Much of the anisotropic coke is a thin-walled macroporous variety but there is a portion which is a thick-walled variety similar to a petroleum coke.

  18. Ash plume properties retrieved from infrared images: a forward and inverse modeling approach

    E-Print Network [OSTI]

    Cerminara, Matteo; Valade, Sébastien; Harris, Andrew J L

    2014-01-01T23:59:59.000Z

    We present a coupled fluid-dynamic and electromagnetic model for volcanic ash plumes. In a forward approach, the model is able to simulate the plume dynamics from prescribed input flow conditions and generate the corresponding synthetic thermal infrared (TIR) image, allowing a comparison with field-based observations. An inversion procedure is then developed to retrieve ash plume properties from TIR images. The adopted fluid-dynamic model is based on a one-dimensional, stationary description of a self-similar (top-hat) turbulent plume, for which an asymptotic analytical solution is obtained. The electromagnetic emission/absorption model is based on the Schwarzschild's equation and on Mie's theory for disperse particles, assuming that particles are coarser than the radiation wavelength and neglecting scattering. [...] Application of the inversion procedure to an ash plume at Santiaguito volcano (Guatemala) has allowed us to retrieve the main plume input parameters, namely the initial radius $b_0$, velocity $U_...

  19. Leaching and toxicity behavior of coal-biomass waste cocombustion ashes

    SciTech Connect (OSTI)

    Skodras, G.; Prokopidou, M.; Sakellaropoulos, G.P. [Aristotle University in Thessaloniki, Thessaloniki (Greece). Dept. for Chemical Engineering

    2006-08-15T23:59:59.000Z

    Land disposal of ash residues, obtained from the cocombustion of Greek lignite with biomass wastes, is known to create problems due to the harmful constituents present. In this regard, the leachability of trace elements from lignite, biomass, and blends cocombustion ashes was investigated by using the Toxicity Characteristic Leaching Procedure (TCLP) of the US Environmental Protection Agency (US EPA). In this work, the toxicity of the aqueous leachates and the concentrations of the metals obtained from the leaching procedure were measured using the Microtox test (Vibrio fischen) and inductive coupled plasma-atomic emission spectrometer (ICP-AES), respectively. The toxic effects of most leachates on Vibrio fischeri were found to be significantly low in both 45% and 82% screening test protocols. However, the liquid sample originating from olive kernels fly ash (FA4) caused the highest toxic effect in both protocols, which can be attributed to its relatively high concentrations of As, Cd, Co, Cu, Mn, Ni, and Zn.

  20. ASHE PDC: The Quality and Patient Safety Movement Posted on: 3.15.2011 11:50:52 AM Posted by Jennifer Kovacs, Managing Editor

    E-Print Network [OSTI]

    Vaziri, Ashkan

    ASHE PDC: The Quality and Patient Safety Movement Posted on: 3.15.2011 11:50:52 AM Posted for Patient Care and Hospital Facilities?" at the ASHE PDC Summit in Tampa, Florida. Benneyan is director

  1. Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge

    E-Print Network [OSTI]

    Bai, Peng

    Using a novel electrochemical phase-field model, we question the common belief that LiXFePO? nanoparticles always separate into Li-rich and Li-poor phases during battery discharge. For small currents, spinodal decomposition ...

  2. High Capacity MoO3 Nanoparticle Li-Ion Battery Anode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    energy functional were employed.) 10 AccomplishmentStatus Theoretical changes in Li-ion intercalated -MoO 3 Mo Li O * Four Li inserted in a theoretical nanoparticle. * 9 ps...

  3. Thermodynamic and kinetic properties of the Li-graphite system from first-principles calculations

    E-Print Network [OSTI]

    Ceder, Gerbrand

    We present an ab initio study of the thermodynamics and kinetics of Li [subscript x]C[subscript 6], relevant for anode Li intercalation in rechargeable Li batteries. In graphite, the interlayer interactions are dominated ...

  4. A HIGH CURRENT DENSITY LI+ ALUMINO-SILICATE ION SOURCE FOR TARGET HEATING EXPERIMENTS

    E-Print Network [OSTI]

    Roy, Prabir K.

    2011-01-01T23:59:59.000Z

    CURRENT DENSITY LI+ ALUMINO-SILICATE ION SOURCE FOR TARGETCURRENT DENSITY LI + ALUMINO-SILICATE ION SOURCE FOR TARGETcm) Li + doped alumino-silicate source with a pulse duration

  5. Homogeneous Factorisations of Graphs and Michael Giudici a, Cai Heng Li a

    E-Print Network [OSTI]

    Giudici, Michael

    Homogeneous Factorisations of Graphs and Digraphs Michael Giudici a, Cai Heng Li a Primoz Potocnik@maths.uwa.edu.au (Michael Giudici), li@maths.uwa.edu.au (Cai Heng Li), primoz.potocnik@fmf.uni-lj.si (Primoz Preprint

  6. Lithium Diffusion in Li4Ti5O12 at High Temperatures. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Diffusion in Li4Ti5O12 at High Temperatures. Lithium Diffusion in Li4Ti5O12 at High Temperatures. Abstract: Synthesis of the spinel lithium titanate Li4Ti5O12 by an...

  7. Primordial Li abundance and massive particles

    SciTech Connect (OSTI)

    Latin-Capital-Letter-Eth apo, H. [Department of Physics, Akdeniz University, TR-07058, Antalya (Turkey)

    2012-10-20T23:59:59.000Z

    The problem of the observed lithium abundance coming from the Big Bang Nucleosynthesis is as of yet unsolved. One of the proposed solutions is including relic massive particles into the Big Bang Nucleosynthesis. We investigated the effects of such particles on {sup 4}HeX{sup -}+{sup 2}H{yields}{sup 6}Li+X{sup -}, where the X{sup -} is the negatively charged massive particle. We demonstrate the dominance of long-range part of the potential on the cross-section.

  8. I I LI I L I

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell:F E ,"^ I 1' . _ .t.fiom I -'LI -

  9. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See72AJ02)72AJ02) (See95TI07)Li

  10. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04)4He (1992TI02)Li

  11. A=9Li (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not

  12. A=9Li (1984AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01) (See Energy

  13. A=9Li (1988AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01) (See

  14. A=9Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01) (See2004TI06)

  15. A=9Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01)

  16. A=9Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01)66LA04) (See

  17. A=9Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01)66LA04)

  18. Ying Li | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contributeSecuritysupports neighbors's/UTAnaYeYing Li

  19. LiDAR | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOf Kilauea Volcano,Lakefront Tow(Redirected from Lewisburg,LiDAR Jump to:

  20. A=15Li (1981AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01) (See0AJ04)1AJ01) (Not illustrated) 15Li

  1. A=16Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy Level6AJ04)6AJ04)Li

  2. Feasibility of using reject fly ash in cement-based stabilization/solidification processes

    SciTech Connect (OSTI)

    Poon, C.S.; Qiao, X.C.; Cheeseman, C.R.; Lin, Z.S. [Hong Kong Polytechnic University, Kowloon (China). Dept. of Civil & Structural Engineering

    2006-01-15T23:59:59.000Z

    Stabilization/solidification (s/s) has been routinely used for the final treatment of hazardous wastes prior to land disposal. These processes involve adding one or more solidifying reagents into the waste to transform it into a monolithic solid with improved structural integrity. Cement-based systems with partial replacement by pulverized fuel ash (PFA) have been widely used to minimize leaching of contaminants from hazardous wastes. The finer fraction of PFA ({lt}45 {mu} m, fine fly ash, MA), produced by passing the raw ash through a classifying process is commonly used in s/s processes. Low-grade fly ash is rejected (rFA) from the ash classifying process, and is largely unused due to high carbon content and large particle size but represents a significant proportion of PFA. This paper presents experimental results of a study that has assessed the feasibility of using rFA in the cement-based s/s of a synthetic heavy metal waste. Results were compared to mixes containing fFA. The strength results show that cement-based waste forms with rFA replacement are suitable for disposal at landfill and that the addition of heavy metal sludge can increase the degree of hydration of fly ash and decrease the porosity of samples. Adding Ca(OH){sub 2} and flue gas desulphurization sludge reduces the retarding effect of heavy metals on strength development. The results of the Toxicity Characteristic Leaching Procedure and Dynamic Leach Test show that rFA can be used in cement-based s/s wastes without compromising performance of the product.

  3. Computation of probabilistic hazard maps and source parameter estimation for volcanic ash transport and dispersion

    SciTech Connect (OSTI)

    Madankan, R. [Department of Mechanical and Aerospace Engineering, University at Buffalo (United States); Pouget, S. [Department of Geology, University at Buffalo (United States); Singla, P., E-mail: psingla@buffalo.edu [Department of Mechanical and Aerospace Engineering, University at Buffalo (United States); Bursik, M. [Department of Geology, University at Buffalo (United States); Dehn, J. [Geophysical Institute, University of Alaska, Fairbanks (United States); Jones, M. [Center for Computational Research, University at Buffalo (United States); Patra, A. [Department of Mechanical and Aerospace Engineering, University at Buffalo (United States); Pavolonis, M. [NOAA-NESDIS, Center for Satellite Applications and Research (United States); Pitman, E.B. [Department of Mathematics, University at Buffalo (United States); Singh, T. [Department of Mechanical and Aerospace Engineering, University at Buffalo (United States); Webley, P. [Geophysical Institute, University of Alaska, Fairbanks (United States)

    2014-08-15T23:59:59.000Z

    Volcanic ash advisory centers are charged with forecasting the movement of volcanic ash plumes, for aviation, health and safety preparation. Deterministic mathematical equations model the advection and dispersion of these plumes. However initial plume conditions – height, profile of particle location, volcanic vent parameters – are known only approximately at best, and other features of the governing system such as the windfield are stochastic. These uncertainties make forecasting plume motion difficult. As a result of these uncertainties, ash advisories based on a deterministic approach tend to be conservative, and many times over/under estimate the extent of a plume. This paper presents an end-to-end framework for generating a probabilistic approach to ash plume forecasting. This framework uses an ensemble of solutions, guided by Conjugate Unscented Transform (CUT) method for evaluating expectation integrals. This ensemble is used to construct a polynomial chaos expansion that can be sampled cheaply, to provide a probabilistic model forecast. The CUT method is then combined with a minimum variance condition, to provide a full posterior pdf of the uncertain source parameters, based on observed satellite imagery. The April 2010 eruption of the Eyjafjallajökull volcano in Iceland is employed as a test example. The puff advection/dispersion model is used to hindcast the motion of the ash plume through time, concentrating on the period 14–16 April 2010. Variability in the height and particle loading of that eruption is introduced through a volcano column model called bent. Output uncertainty due to the assumed uncertain input parameter probability distributions, and a probabilistic spatial-temporal estimate of ash presence are computed.

  4. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31T23:59:59.000Z

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  5. Journal of Hazardous Materials B132 (2006) 244252 Zeolite synthesis from paper sludge ash at low temperature

    E-Print Network [OSTI]

    Downs, Robert T.

    2006-01-01T23:59:59.000Z

    Journal of Hazardous Materials B132 (2006) 244­252 Zeolite synthesis from paper sludge ash at low consists of organic fibers, inorganic clay-sized materials, and about 60% water, and is incinerated and 9. Alternative processing methods of zeolite synthesis, including the addition of ash

  6. Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li

    E-Print Network [OSTI]

    Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li Lithium-halogen exchange reactions are essentially inert. 2 t-BuLi t-BuI + RLi t-BuLi isobutene + isobutane + LiI Lithium-halogen exchange reactions, and lithium iodide. H OEtBr H H OEtLi H1.1 eq n-BuLi Et2O, !80 °C Lau, K. S.; Schlosser, M. J. Org. Chem. 1978

  7. Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants

    SciTech Connect (OSTI)

    M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

    2003-12-31T23:59:59.000Z

    This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

  8. Comparative analysis of methods for determination of arsenic in coal and coal ash

    SciTech Connect (OSTI)

    Vukasinovic-Pesic, V.L.; Blagojevic, N.Z.; Rajakovic, L.V. [University of Montenegro, Podgorica (Montenegro)

    2009-07-01T23:59:59.000Z

    In this paper the comparative analysis of different methods for the preparation and analysis of arsenic content in coal and coal ash have been presented. The suggested method is coal digestion method, i.e., coal ash digestion using the mixture of acids: nitric and sulphuric in presence of vanadium-pentoxide as catalyzer. The comparative analysis of different recording techniques (AAS-GH, AAS-GF and ICP-AES) has also been presented. For arsenic recording the suggested technique is AAS-GF technique. The obtained results show that the method of high precision, high sensitivity and high reproductivity has been obtained.

  9. Intra- and inter-unit variation in fly ash petrography: Examples from a western Kentucky power station

    SciTech Connect (OSTI)

    Hower, J.C.; Rathbone, R.F. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Goodman, J. [Prestonburg High School, KY (United States)

    1998-12-31T23:59:59.000Z

    Fly ash was collected from eight mechanical and ten baghouse hoppers at each of twin 150-MW wall-fired units in a western Kentucky power station. The fuel burned at that time was a blend of low-sulfur, high volatile bituminous Central Appalachian coals. The baghouse ash showed less variation between units than the mechanical units. The coarser mechanical fly ash showed significant differences in the amount of total carbon and in the ratio of isotropic coke to both total carbons and total coke; the latter excluding inertinite and other unburned, uncoked coal. There was no significant variation in ratios of inorganic fly ash constituents. The inter-unit differences in the amount and forms of mechanical fly ash carbon appear to be related to differences in pulverizer efficiency, leading to greater amounts of coarse coal, therefore unburned carbon, in one of the units.

  10. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A. (National Research Council of Canada, Ottawa, ON (Canada). Div. of Chemistry)

    1989-01-01T23:59:59.000Z

    Ash reduction of the cokes and fly ash samples derived from the Athabasca oil sands bitumen was attempted by dissolving the mineral matter in acids. The samples used for this investigation included Syncrude fluid coking coke, Suncor delayed coking coke and the two fly ash samples obtained from the combustion of these cokes. All samples were analyzed for C,H,N,O, and S before and after acid demineralization and the analyses results compared. Further, the ash from the samples before and after acid demineralization was analyzed for silica, alumina, iron titanium, nickel and vanadium to assess the acid leaching of these elements. CP/MAS, /sup 13/C NMR spectroscopic study of the demineralized coke and fly ash samples was also attempted.

  11. Air stable Al2O3-coated Li2NiO2 cathode additive as a surplus current consumer in a Li-ion cell

    E-Print Network [OSTI]

    Cho, Jaephil

    increases to 2.75V (2.85V vs. graphite), its discharge capacity decreases to 120 mAh/g, which corresponds for the irreversible capacity of the Li-ion cell using LiCoO2 and natural graphite as cathode and anode materials the complete decomposition of the Li2NiO2. 1. Introduction Most Li secondary batteries use LiCoO2 as a cathode

  12. Spectroscopy of Lambda-9Li by electroproduction

    E-Print Network [OSTI]

    G. M. Urciuoli; F. Cusanno; S. Marrone; A. Acha; P. Ambrozewicz; K. A. Aniol; P. Baturin; P. Y. Bertin; H. Benaoum; K. I. Blomqvist; W. U. Boeglin; H. Breuer; P. Brindza; P. Bydzovsky; A. Camsonne; C. C. Chang; J. -P. Chen; Seonho Choi; E. A. Chudakov; E. Cisbani; S. Colilli; L. Coman; B. J. Craver; G. De Cataldo; C. W. de Jager; R. De Leo; A. P. Deur; C. Ferdi; R. J. Feuerbach; E. Folts; R. Fratoni; S. Frullani; F. Garibaldi; O. Gayou; F. Giuliani; J. Gomez; M. Gricia; J. O. Hansen; D. Hayes; D. W. Higinbotham; T. K. Holmstrom; C. E. Hyde; H. F. Ibrahim; M. Iodice; X. Jiang; L. J. Kaufman; K. Kino; B. Kross; L. Lagamba; J. J. LeRose; R. A. Lindgren; M. Lucentini; D. J. Margaziotis; P. Markowitz; Z. E. Meziani; K. McCormick; R. W. Michaels; D. J. Millener; T. Miyoshi; B. Moffit; P. A. Monaghan; M. Moteabbed; C. Munoz Camacho; S. Nanda; E. Nappi; V. V. Nelyubin; B. E. Norum; Y. Okasyasu; K. D. Paschke; C. F. Perdrisat; E. Piasetzky; V. A. Punjabi; Y. Qiang; P. E. Reimer; J. Reinhold; B. Reitz; R. E. Roche; V. M. Rodriguez; A. Saha; F. Santavenere; A. J. Sarty; J. Segal; A. Shahinyan; J. Singh; S. Sirca; R. Snyder; P. H. Solvignon; M. Sotona; R. Subedi; V. A. Sulkosky; T. Suzuki; H. Ueno; P. E. Ulmer; P. Veneroni; E. Voutier; B. B. Wojtsekhowski; X. Zheng; C. Zorn

    2014-10-01T23:59:59.000Z

    In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Electroproduction of the hypernucleus Lambda-9Li has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a 9Be target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. The cross section to low-lying states of Lambda-9Li is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A Lambda separation energy of 8.36 +- 0.08 (stat.) +- 0.08 (syst.) MeV was measured, in agreement with an earlier experiment.

  13. Universal Accumulators with Efficient Nonmembership Jiangtao Li1

    E-Print Network [OSTI]

    Li, Ninghui

    Universal Accumulators with Efficient Nonmembership Proofs Jiangtao Li1 , Ninghui Li2 , and Rui Xue of Illinois at Urbana-Champaign rxue@uiuc.edu Abstract. Based on the notion of accumulators, we propose a new cryptographic scheme called universal accumulators. This scheme enables one to commit to a set of values using

  14. Molecular dynamics simulation of Li surface erosion and bubble formation

    E-Print Network [OSTI]

    Harilal, S. S.

    .49.Sf Keywords: Liquid metal; Lithium; Ion-surface interactions 1. Introduction Bombardment Structure and dynamical properties of liquid Li containing He atoms were studied by the Molecular Dynamics characteristics of light low-energy ions on a liquid Li surface and their diffusion properties have attracted much

  15. Community-Based Cloud for Emergency Management , Qingrui Li1

    E-Print Network [OSTI]

    Li, Juan "Jen"

    number of recent disasters, such as the Indonesian volcanic eruption, Gulf of Mexico oil spill, Haitian, University of New Mexico j.li@ndsu.edu, qingrui.li@ndsu.edu, samee.khan@ndsu.edu, nghani@ece.unm.edu Abstract

  16. Implications of Li divertor and other liquid-metal technologies

    E-Print Network [OSTI]

    plasma-facing systems can rapidly remove heat. h Continuous recovery of damaged surfaces exposed to large. Nuclear Mater. 290-293 (2001) 19. #12;Secondary ion fraction and deuterium- saturation studies of liquid (sputteringions/sputteredatoms) Incident particle energy (eV) Secondary Li ion fraction (non D-sat.) Secondary Li

  17. Ethylmethylcarbonate, a promising solvent for Li-ion rechargeable batteries

    SciTech Connect (OSTI)

    Ein-Eli, Y.; Thomas, S.R.; Koch, V. [Covalent Associates Inc., Woburn, MA (United States); Aurbach, D.; Markovsky, B.; Schechter, A. [Bar-Ilan Univ., Ramat Gan (Israel). Dept. of Chemistry

    1996-12-01T23:59:59.000Z

    Ethylmethylcarbonate (EMC) has been found to be a promising solvent for rechargeable Li-ion batteries. Graphite electrodes, which are usually sensitive to the composition of the electrolyte solution, can be successfully cycled at high reversible capacities in several Li salt solutions in this solvent (LiAsF{sub 6}, LiPF{sub 6}, etc.). These results are interesting because lithium ions cannot intercalate into graphite in diethyl carbonate solutions and cycle poorly in dimethyl carbonate solutions. To understand the high compatibility of EMC for Li-ion battery systems as compared with the other two open-chain alkyl carbonates mentioned above, the surface chemistry developed in both Li and carbon electrodes in EMC solution was studied and compared with that developed on these electrodes in other alkyl carbonate solutions. Basically, the major surface species formed on both electrodes in EMC include ROLi, ROCO{sub 2}Li, and Li{sub 2}CO{sub 3} species. The uniqueness of EMC as a battery solvent is discussed in light of these studies.

  18. Fluorinated Electrolyte for 5-V Li-Ion Chemistry

    Broader source: Energy.gov (indexed) [DOE]

    battery for PHEV and EV applications. Approach 5 LiNi 0.5 Mn 1.5 O 4 1.2M LiPF 6 ECEMC (37 wt%) Graphite, cycled at RT and 55 o C Technical Accomplishments and Progress...

  19. Characterization of LI+ Alumino-Silicate Ion Source for Target Heating Experiments

    E-Print Network [OSTI]

    Roy, P.K.

    2013-01-01T23:59:59.000Z

    OF LI + ALUMINO-SILICATE ION SOURCE FOR TARGET HEATINGcm) Li + doped alumino-silicate source to pro- duce shortdiameter lithium alumino-silicate ion source is presented.

  20. Effective bending stiffness for plates with microcracks D. C. Simkins Jr, S. Li

    E-Print Network [OSTI]

    Li, Shaofan

    Effective bending stiffness for plates with microcracks D. C. Simkins Jr, S. Li Summary. C. Simkins Jr, S. Li (&) Department of Civil and Environmental Engineering, University of California

  1. Conversion of Fly Ash into Mesoporous Aluminosilicate Hsiao-Lan Chang, Chang-Min Chun, Ilhan A. Aksay, and Wei-Heng Shih*,

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    and aluminum sources. Fly ash, which is a byproduct of coal burning, contains mostly aluminosilicates. Recently not only eliminates the disposal problem of fly ash but also turns an otherwise waste materialConversion of Fly Ash into Mesoporous Aluminosilicate Hsiao-Lan Chang, Chang-Min Chun, Ilhan A

  2. Localization of vacancies and mobility of lithium ions in Li{sub 2}ZrO{sub 3} as obtained by {sup 6,7}Li NMR

    SciTech Connect (OSTI)

    Baklanova, Ya. V., E-mail: baklanovay@ihim.uran.ru [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation); Arapova, I. Yu.; Buzlukov, A.L.; Gerashenko, A.P.; Verkhovskii, S.V.; Mikhalev, K.N. [Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, 18 Kovalevskaya str., 620990 Ekaterinburg (Russian Federation); Denisova, T.A.; Shein, I.R.; Maksimova, L.G. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation)

    2013-12-15T23:59:59.000Z

    The {sup 6,7}Li NMR spectra and the {sup 7}Li spin–lattice relaxation rate were measured on polycrystalline samples of Li{sub 2}ZrO{sub 3}, synthesized at 1050 K and 1300 K. The {sup 7}Li NMR lines were attributed to corresponding structural positions of lithium Li1 and Li2 by comparing the EFG components with those obtained in the first-principles calculations of the charge density in Li{sub 2}ZrO{sub 3}. For both samples the line width of the central {sup 7}Li transition and the spin–lattice relaxation time decrease abruptly at the temperature increasing above ?500 K, whereas the EFG parameters are averaged (??{sub Q}?=42 (5) kHz) owing to thermally activated diffusion of lithium ions. - Graphical abstract: Path of lithium ion hopping in lithium zirconate Li{sub 2}ZrO{sub 3}. - Highlights: • Polycrystalline samples Li{sub 2}ZrO{sub 3} with monoclinic crystal structure synthesized at different temperatures were investigated by {sup 6,7}Li NMR spectroscopy. • Two {sup 6,7}Li NMR lines were attributed to the specific structural positions Li1 and Li2. • The distribution of vacancies was clarified for both lithium sites. • The activation energy and pathways of lithium diffusion in Li{sub 2}ZrO{sub 3} were defined.

  3. Structure of neutron-rich Isotopes {sup 8}Li and {sup 9}Li and allowance for it in elastic scattering

    SciTech Connect (OSTI)

    Ibraeva, E. T., E-mail: ibr@inp.k [National Nuclear Center of the Republic of Kazakhstan, Institute for Nuclear Physics (Kazakhstan); Zhusupov, M. A.; Imambekov, O.; Sagindykov, Sh. Sh. [Al Farabi Kazakh National University (Kazakhstan)

    2008-07-15T23:59:59.000Z

    The differential cross sections for elastic proton scattering on the unstable neutron-rich nuclei {sup 8}Li and {sup 9}Li at E = 700 and 60 MeV per nucleon were considered. The {sup 8}Li nucleus was treated on the basis of the three-body {alpha}-t-n model, while the {sup 9}Li nucleus was considered within the {alpha}-t-n and {sup 7}Li-n-n models. The cross sections in question were calculated within Glauber diffraction theory. A comparison of the results with available experimental data made it possible to draw conclusions on the quality of the wave functions and potential used in the calculations.

  4. Effect of particle size and volume fraction on tensile properties of fly ash/polyurea composites

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    Effect of particle size and volume fraction on tensile properties of fly ash/polyurea composites polyurea and the polyurea matrix for the composites based on Isonate® 2143L (diisocyanate) and Versalink® P of the composites. Particle size and volume fraction were varied to study their effects on the tensile properties

  5. High temperature behavior of electrostatic precipitator ash from municipal solid waste combustors

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    combustors Lydie Le Forestier a,*, Guy Libourel b,c a ISTO, UMR 6113 CNRS-Université d'Orléans, Polytech, a destruction of pathogenic agents and a possible recovery of energy. Whatever MSW combustor used, combustion of MSW produces two kinds of solid residues: (i) bottom ashes recovered from the primary combustor

  6. High-Carbon Fly Ash in Manufacturing Conductive CLSM and Concrete

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    ; Slurries; Steel fibers; Recycling. Introduction In response to Phase II of the Clean Air Act Amendments of 1990, many electric utilities operating coal-fired power plants installed low NOx nitrogen oxides it in nonconcrete applications. The physical characteristics of the coal fly ash vary widely and depend on the type

  7. Optimization of cement and fly ash particle sizes to produce sustainable concretes Dale P. Bentz a,

    E-Print Network [OSTI]

    Bentz, Dale P.

    Optimization of cement and fly ash particle sizes to produce sustainable concretes Dale P. Bentz a and Technology, 100 Bureau Drive, Stop 7313, Gaithersburg, MD 20899-7313, USA b Roman Cement LLC, Salt Lake City form 29 April 2011 Accepted 30 April 2011 Available online 7 May 2011 Keywords: Blended cement Design

  8. TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE

    E-Print Network [OSTI]

    Laughlin, Robert B.

    TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE WAVELENGTH Grand Forks, ND 58202-9018 Keywords: scanning electron microscopy, trace metals, coal analysis ABSTRACT Scanningelectron microscopy with wavelength-dispersive spectrometry has been used to measure trace metals in coal

  9. The impact of conversion to low-NO{sub x} burners on ash characteristics

    SciTech Connect (OSTI)

    Robi, T.L.; Hower, J.C.; Graham, U.M.; Groppo, J.G.; Rathbone, R.F.; Taulbee, D.N. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Medina, S.S. [East Kentucky Power Cooperative, Winchester, KY (United States)

    1995-12-31T23:59:59.000Z

    A research initiative focusing on the changes in coal-combustion byproducts that result from the conversion of coal-fired boilers to low-NO{sub x} burners has been implemented at the Center for Applied Energy Research (CAER). This paper presents selected results from the first such study, the conversion of East Kentucky Power`s 116 MW, wall-fired unit {number_sign}1 at the John Sherman Cooper Station in Pulaski County, Kentucky. Samples of the coal feedstock and fly ash recovered in several downstream collection vessels were collected prior to and following conversion and extensively analyzed. The results presented in this report include total carbon, petrography, mineralogy, particle size, and leaching characteristics. The major changes noted in the fly-ash properties include an increase in carbon content, a slight increase in particle size, and a decrease in glassy components in the ash following conversion. Those changes induced by the conversion to low-NO{sub x} burners are evaluated in terms of the potential impact on the marketability of the fly ash.

  10. Evaluation of leaching and ecotoxicological properties of sewage sludge-fly ash mixtures

    SciTech Connect (OSTI)

    C.A. Papadimitriou; I. Haritou; P. Samaras; A.I. Zouboulis [Technological Educational Institute of West Macedonia, Kozani (Greece)

    2008-03-15T23:59:59.000Z

    The objectives of this work were the evaluation of sewage sludge stabilization by mixing with fly ash, the examination of the physicochemical properties of the produced materials and their leachates and the assessment of their environmental impact by the evaluation of the ecotoxic characteristics. Different ratios of fly ash and sewage sludge (1:1, 1:2, 1:3, 1:6, and 1:9) were mixed for 48 and 72 h. After mixing, the liquid phase of the produced materials was analyzed for total coliforms and Escherichia coli, while the solid residue was dried and tested for the leaching characteristics by the application of TCLP and EN 12457-2 standard leaching methods. Furthermore, the produced leachates were analyzed for their content of specific metals, while their ecotoxicological characteristics were determined by the use of toxicity bioassays, using the marine photobacterium Vibrio fischeri and the crustacean Daphnia magna. The phytotoxicity of sewage sludge-fly ash mixtures was also determined by utilizing seeds of three higher plants (one monocotyl and two dicotyls). The mixtures exhibited low metal leaching in all cases, while the ecotoxic properties increased with the increase of fly ash/sewage sludge ratio. The phytotoxicity testing showed increased root length growth inhibition.

  11. How carbon-based sorbents will impact fly ash utilization and disposal

    SciTech Connect (OSTI)

    Pflughoeft-Hassett, D.F.; Hassett, D.J.; Buckley, T.D.; Heebink, L.V.; Pavlish, J.H. [Energy and Environmental Research Center (United States)

    2008-07-01T23:59:59.000Z

    The injection of activated carbon flue gas to control mercury emissions will result in a fly ash and activated carbon mixture. The potential impact of this on coal combustion product disposal and utilization is discussed. The full paper (and references) are available at www.acaa-usa.org. 1 tab., 2 photos.

  12. Fibrous Fillers to Manufacture Ultra-High Ash/Performance Paper

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to demonstrate the economic and technological viability of fibrous filler to manufacture paper containing up to 50% ash, at equal or better quality and performance than conventional alternatives and at a lower cost.

  13. Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2 3 G. Montes that could possibly4 contribute to reducing carbon dioxide emissions is the in-situ mineral sequestration (long term5 geological storage) or the ex-situ mineral sequestration (controlled industrial reactors

  14. Optimizing recovery using on-line ash analyzers or sorting for dollars

    SciTech Connect (OSTI)

    Litz, P.

    1995-08-01T23:59:59.000Z

    The quest for profitability in the complex coal industry requires continual examination of common practices looking for better and more cost effective methods of performing these tasks. As the available coal reserves become more difficult to mine and the quality decreases, this examination process grows in importance. Over the past fifteen years, we have all seen major changes in the methods used to mine, clean and load coal in an attempt to increase the bottom line and proliferate a safer work place. The long wall mining method has greatly increased the profitably of the larger mines that have the reserves and the seams suitable for this method. Bigger and faster conveyor belts have increased loading capacities and decreased time spent performing the task. New technology in the cleaning and preparation of coal has also assisted in increasing yield and thus decreasing the final cost of a ton of coal. What about the smaller mines that do not have the mining conditions or reserves for a longwall or the monetary resources to upgrade belt lines and preparation plants, they to must remain profitable. The on-line ash analyzer is one answer that is not only for the smaller mines but can show quick and substantial returns for the larger operations. The on-line ash analyzer is a nuclear device that is mounted directly on the conveyor belt to produce an instantaneous ash analysis on the coal as it moves beneath the detector. The on-line ash analyzer is described.

  15. Dewatering Fly Ash Slurries Using Geotextile Containers M. E. Kutay1

    E-Print Network [OSTI]

    Aydilek, Ahmet

    during its settlement. However, the hydraulic compatibility of a geotextile with the contact soil is also for ensuring hydraulic compatibility is that the geotextile should not be clogged during the dewatering process ash slurries. A testing program that included filter press and hanging bag tests was implemented

  16. Evaluation of Leaching Protocols for Testing of High-Carbon Coal Fly AshSoil Mixtures

    E-Print Network [OSTI]

    Aydilek, Ahmet

    from coal-fired power plants, which burn over 1 billion t of coal annually (Kim 2006). This generationEvaluation of Leaching Protocols for Testing of High-Carbon Coal Fly Ash­Soil Mixtures Jason Becker: Beneficial reuse of coal combustion byproducts, e.g., in highway construction, requires an evaluation

  17. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M. (Huntsville, AL)

    1980-01-01T23:59:59.000Z

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  18. Selenium(IV) and (VI) sorption by soils surrounding fly ash management facilities

    SciTech Connect (OSTI)

    Hyun, S.; Burns, P.E.; Murarka, I.; Lee, L.S. [Purdue University, West Lafayette, IN (United States)

    2006-11-15T23:59:59.000Z

    Leachate derived from unlined coal ash disposal facilities is one of the most significant anthropogenic sources of selenium to the environment. To establish a practical framework for predicting transport of selenium in ash leachate, sorption of Se(IV) and Se(VI) from 1 mM CaSO{sub 4} was measured for 18 soils obtained down-gradient from three ash landfill sites and evaluated with respect to several soil properties. Furthermore, soil attenuation from lab-generated ash leachate and the effect of Ca{sup 2+} and SO{sub 4}{sup 2-} concentrations as well as pH on both Se(IV) and Se(VI) was quantified for a subset of soils. For both Se(IV) and Se(VI), pH combined with either percentage clay or dithionite-citrate-bicarbonate (DCB)-extractable Fe described {gt} 80% of the differences in sorption across all soils, yielding an easy approach for making initial predictions regarding site-specific selenium transport to sensitive water bodies. Se(IV) consistently exhibited an order of magnitude greater sorption than Se(VI). Selenium sorption was highest at lower pH values, with Se(IV) sorption decreasing at pH values above 6, whereas Se(VI) decreased over the entire pH range (2.5-10). Using these pH adsorption envelopes, the likely effect of ash leachate-induced changes in soil pore water pH with time on selenium attenuation by down gradient soils can be predicted. Selenium sorption increased with increasing Ca{sup 2+} concentrations while SO{sub 4}2- suppressed sorption well above enhancements by Ca{sup 2+}. Soil attenuation of selenium from ash leachates agreed well with sorption measured from 1 mM CaSO{sub 4}, indicating that 1 mM CaSO{sub 4} is a reasonable synthetic leachate for assessing selenium behavior at ash landfill sites.

  19. Fish Health Studies Associated with the Kingston Fly Ash Spill, Spring 2009 - Fall 2010

    SciTech Connect (OSTI)

    Adams, Marshall [ORNL; Fortner, Allison M [ORNL

    2012-05-01T23:59:59.000Z

    On December 22, 2008, over 4 million cubic meters of fly ash slurry was released into the Emory River when a dike surrounding a solid waste containment area at the Tennessee Valley Authority's (TVA) Kingston Fossil Plant ruptured. One component of TVA's response to the spill is a biological monitoring program to assess short- and long-term ecological responses to the ash and associated chemicals, including studies on fish health and contaminant bioaccumulation. These studies were initiated in early Spring 2009 for the purposes of: (1) documenting the levels of fly ash-associated metals in various tissues of representative sentinel fish species in the area of the fly ash spill, (2) determining if exposure to fly ash-associated metals causes short, intermediate, or long-term health effects on these sentinel fish species, (3) assessing if there are causal relationships between exposure to metals and health effects on fish, (4) evaluating, along with information from other ecological and physicochemical studies, the nature and route of contaminant transfer though food chains into higher level consumers, (5) providing important information for the Ecological Risk Assessment (ERA) for the Kingston fly ash project, and (6) serving as an important technology information transfer or model study focused on how to best evaluate the environmental effects of fly ash (and related environmental stressors), not only at the Kingston site, but also at sites on other aquatic systems where coal-fired generating stations are located. This report presents the results of the first two years of the fish health study. To date, fish health and bioaccumulation studies have been conducted from Spring 2009 though Fall 2011 and includes 6 seasonal studies: Spring 2009, Fall 2009, Spring 2010, Fall 2010, Spring 2011, and Fall 2011. Both the Spring and Fall studies have focused on 3-4 sentinel fish species that represent different feeding habits, behaviors, and home ranges. In addition to fish health and bioaccumulation, the Spring investigations also included reproductive integrity studies on the same fish used for bioaccumulation and fish health. In this report, results of the fish health studies from Spring 2009 through Fall 2010 are presented while an associated report will present the fish reproductive studies conducted during Spring 2009 and Spring 2010. A report on fish bioaccumulation was submitted to TVA in June 2011. The fish health study conducted in conjunction with the bioaccumulation and reproductive study is critical for assessing and evaluating possible causal relationships between contaminant exposure (bioaccumulation) and the response of fish to exposure as reflected by the various measurements of fish health.

  20. Material review of Li ion battery separators

    SciTech Connect (OSTI)

    Weber, Christoph J., E-mail: Christoph.Weber@freudenberg-nw.com; Geiger, Sigrid, E-mail: Christoph.Weber@freudenberg-nw.com [Freudenberg Vliesstoffe SE and Co KG, 69465 Weinheim (Germany); Falusi, Sandra; Roth, Michael [Freudenberg Forschungsdienste SE and Co KG, 69465 Weinheim (Germany)

    2014-06-16T23:59:59.000Z

    Separators for Li Ion batteries have a strong impact on cell production, cell performance, life, as well as reliability and safety. The separator market volume is about 500 million m{sup 2} mainly based on consumer applications. It is expected to grow strongly over the next decade for mobile and stationary applications using large cells. At present, the market is essentially served by polyolefine membranes. Such membranes have some technological limitations, such as wettability, porosity, penetration resistance, shrinkage and meltdown. The development of a cell failure due to internal short circuit is potentially closely related to separator material properties. Consequently, advanced separators became an intense area of worldwide research and development activity in academia and industry. New separator technologies are being developed especially to address safety and reliability related property improvements.