Powered by Deep Web Technologies
Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

E-Print Network 3.0 - ash blended cement Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CLSM mixture utilized... . CHARACTERIZATION AND APPLICATION OF CLASS F FLY ASH AND CLEAN-COAL ASH FOR CEMENT-BASED MATERIALS 2 The major... investigation. Two additional ash ......

2

Soil stabilization and pavement recycling with self-cementing coal fly ash  

SciTech Connect (OSTI)

This manual provides design information for self-cementing coal fly ash as the sole stabilizing agent for a wide range of engineering applications. As in any process, the application of sound engineering practices, appropriate testing, and evaluation of fly ash quality and characteristics will lend themselves to successful projects using the guidelines in this manual. Topics discussed include: self-cementing coal fly ash characteristics; laboratory mix design; stabilization of clay soils; stabilisation of granular materials; construction considerations; high sulfate ash; environmental considerations for fly ash stabilization; design considerations; state specification/guidelines/standards; and a sample of a typical stabilization specification.

NONE

2008-01-15T23:59:59.000Z

3

Hydration studies of calcium sulfoaluminate cements blended with fly ash  

SciTech Connect (OSTI)

The main objective of this work is to study the hydration and properties of calcium sulfoaluminate cement pastes blended with fly ash (FA) and the corresponding mortars at different hydration ages. Laboratory X-ray powder diffraction, rheological studies, thermal analysis, porosimetry and compressive strength measurements were performed. The analysis of the diffraction data by Rietveld method allowed quantifying crystalline phases and overall amorphous contents. The studied parameters were: i) FA content, 0, 15 and 30 wt.%; and ii) water addition, water-to-CSA mass ratio (w/CSA = 0.50 and 0.65), and water-to-binder mass ratio (w/b = 0.50). Finally, compressive strengths after 6 months of 0 and 15 wt.% FA [w/CSA = 0.50] mortars were similar: 73 ± 2 and 72 ± 3 MPa, respectively. This is justified by the filler effect of the FA as no strong evidences of reactivity of FA with CSA were observed. These results support the partial substitution of CSA cements with FA with the economic and environmental benefits.

García-Maté, M.; De la Torre, A.G. [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain)] [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain); León-Reina, L. [Servicios Centrales de Apoyo a la Investigación, Universidad de Málaga, 29071 Málaga (Spain)] [Servicios Centrales de Apoyo a la Investigación, Universidad de Málaga, 29071 Málaga (Spain); Aranda, M.A.G. [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain) [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain); CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain); Santacruz, I., E-mail: isantacruz@uma.es [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain)

2013-12-15T23:59:59.000Z

4

E-Print Network 3.0 - ash cements stabilized Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 6 By-Products Utilization Summary: OF WISCONSIN - MILWAUKEE 12;2 Use of Clean Coal Ash as Setting Time Regulator in Portland Cement by Zichao Wu... as setting time...

5

Influence of curing temperature on cement hydration and mechanical strength development of fly ash mortars  

SciTech Connect (OSTI)

The influence of fly ash and curing temperature on cement hydration and compressive strength development of mortars was investigated. Test parameters included type of fly ash (two different Class F fly ashes were tested), the level of cement replacement (10, 20 and 30% by mass), and curing temperature (20 C and 40 C). The mortar physical and microstructural properties were determined by means of thermal analyses, compressive strength measurements and SEM observations. Test results confirm that fly ash tends to increase significantly the rate of cement hydration at early age. Data also demonstrate that an elevation of the curing temperature reduces the long-term compressive strength of the reference mortar mixture. In contrast, an increase of the curing temperature seems to have no detrimental effect on the long-term compressive strength of the fly ash mixtures.

Maltais, Y.; Marchand, J. [Univ. Laval, Quebec (Canada). Centre de Recherche Interuniversitaire sur le Beton] [Univ. Laval, Quebec (Canada). Centre de Recherche Interuniversitaire sur le Beton

1997-07-01T23:59:59.000Z

6

ash cement concrete: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

early stage hydration of different classes of oilwell cement Bentz, Dale P. 410 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

7

ash substituted cements: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

early stage hydration of different classes of oilwell cement Bentz, Dale P. 199 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

8

Encapsulation of mixed radioactive and hazardous waste contaminated incinerator ash in modified sulfur cement  

SciTech Connect (OSTI)

Some of the process waste streams incinerated at various Department of Energy (DOE) facilities contain traces of both low-level radioactive (LLW) and hazardous constituents, thus yielding ash residues that are classified as mixed waste. Work is currently being performed at Brookhaven National Laboratory (BNL) to develop new and innovative materials for encapsulation of DOE mixed wastes including incinerator ash. One such material under investigation is modified sulfur cement, a thermoplastic developed by the US Bureau of Mines. Monolithic waste forms containing as much as 55 wt % incinerator fly ash from Idaho national Engineering Laboratory (INEL) have been formulated with modified sulfur cement, whereas maximum waste loading for this waste in hydraulic cement is 16 wt %. Compressive strength of these waste forms exceeded 27.6 MPa. Wet chemical and solid phase waste characterization analyses performed on this fly ash revealed high concentrations of soluble metal salts including Pb and Cd, identified by the Environmental Protection Agency (EPA) as toxic metals. Leach testing of the ash according to the EPA Toxicity Characteristic Leaching Procedure (TCLP) resulted in concentrations of Pb and Cd above allowable limits. Encapsulation of INEL fly ash in modified sulfur cement with a small quantity of sodium sulfide added to enhance retention of soluble metal salts reduced TCLP leachate concentrations of Pb and Cd well below EPA concentration criteria for delisting as a toxic hazardous waste. 12 refs., 4 figs., 2 tabs.

Kalb, P.D.; Heiser, J.H. III; Colombo, P.

1990-01-01T23:59:59.000Z

9

Production of cements from Illinois coal ash. Technical report, September 1, 1995--November 30, 1995  

SciTech Connect (OSTI)

The objective of this program is to convert Illinois coal combustion residues, such as fly ash, bottom ash, and boiler slag, into novel cementitious materials for use in the construction industry. Currently only about 30% of the 5 million tons of these coal combustion residues generated in Illinois each year are utilized, mainly as aggregate. These residues are composed largely Of SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, MgO, and CaO, which are also the major components of cement. The process being developed in this program will use the residues directly in the manufacture of cement products. Therefore, a much larger amount of residues can be utilized. To achieve the above objective, in the first phase (current year) samples of coal combustion residues will be blended and mixed, as needed, with a lime or cement kiln dust (CKD) to adjust the CaO composition. Six mixtures will be melted in a laboratory-scale furnace at CTL. The resulting products will then be tested for cementitious properties. Two preliminary blends have been tested. One blend used fly ash with limestone, while the other used fly ash with CKD. Each blend was melted and then quenched, and the resulting product samples were ground to a specific surface area similar to portland cement. Cementitious properties of these product samples were evaluated by compression testing of 1-inch cube specimens. The specimens were formed out of cement paste where a certain percentage of the cement paste is displaced by one of the sample products. The specimens were cured for 24 hours at 55{degrees}C and 100% relative humidity. The specimens made with the product samples obtained 84 and 89% of the strength of a pure portland cement control cube. For comparison, similar (pozzolanic) materials in standard concrete practice are required to have a compressive strength of at least 75% of that of the control.

Wagner, J.C. [Institute of Gas Technology, Chicago, IL (United States); Bhatty, J.I.; Mishulovich, A. [Construction Technology Labs., Inc., Washington, DC (United States)

1995-12-31T23:59:59.000Z

10

Engineering properties of miniature cement - fly ash compacts prepared by high pressure compaction  

E-Print Network [OSTI]

ENGINEERING PROPERTIES OF MINIATURE CEMENT - FLY ASH COMPACTS PREPARED BY HIGH PRESSURE COMPACTION E NGIRPR OT SFMMAFU AEU C-ALEYY HDOBPvvIi va vGI ge(iD(vI oannItI au NId(R E)L xrP1IeRPvT 9(evP(n uDnuPnnBIrv au vGI eI0DPeIBIrvR uae vGI i...IteII au LEHNFA -M Ho2FYoF EDtDRv 3456 L(7ae HDO7I8v? oP1Pn FrtPrIIePrt ENGINEERING PROPERTIES OF MINIATURE CEMENT - FLY ASH COMPACTS PREPARED BY HIGH PRESSURE COMPACTION E NGIRPR OT SFMMAFU AEU C-ALEYY E99ea1Ii (R va RvTnI (ri 8arvIrv OT? LP...

Bormann, Jeffrey Ray

1985-01-01T23:59:59.000Z

11

Effect of temperature on the hydration of Portland cement blended with siliceous fly ash  

SciTech Connect (OSTI)

The effect of temperature on the hydration of Portland cement pastes blended with 50 wt.% of siliceous fly ash is investigated within a temperature range of 7 to 80 °C. The elevation of temperature accelerates both the hydration of OPC and fly ash. Due to the enhanced pozzolanic reaction of the fly ash, the change of the composition of the C–S–H and the pore solution towards lower Ca and higher Al and Si concentrations is shifted towards earlier hydration times. Above 50 °C, the reaction of fly ash also contributes to the formation of siliceous hydrogarnet. At 80 °C, ettringite and AFm are destabilised and the released sulphate is partially incorporated into the C–S–H. The observed changes of the phase assemblage in dependence of the temperature are confirmed by thermodynamic modelling. The increasingly heterogeneous microstructure at elevated temperatures shows an increased density of the C–S–H and a higher coarse porosity. -- Highlights: •The reaction of quartz powder at 80 °C strongly enhances the compressive strength. •Almost no strength increase of fly ash blended OPC at 80 °C was found after 2 days. •Siliceous hydrogarnet is formed upon the reaction of fly ash at high temperatures. •Temperature dependent change of the system was simulated by thermodynamic modelling. •Destabilisation of ettringite above 50 °C correlates with sulphate content of C–S–H.

Deschner, Florian, E-mail: florian.deschner@gmail.com [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland)] [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Lothenbach, Barbara; Winnefeld, Frank [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland)] [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Neubauer, Jürgen [GeoZentrum Nordbayern, Mineralogy, University of Erlangen-Nuremberg, 91054 Erlangen (Germany)] [GeoZentrum Nordbayern, Mineralogy, University of Erlangen-Nuremberg, 91054 Erlangen (Germany)

2013-10-15T23:59:59.000Z

12

Production of cements from Illinois coal ash. Final technical report, September 1, 1995--August 31, 1996  

SciTech Connect (OSTI)

The objective of this program is to convert Illinois coal combustion residues, such as fly ash, bottom ash, and boiler slag, into novel cementitious materials for use in the construction industry. These residues are composed largely of SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, MgO, and CaO, which are also the major components of cement. Since the residues are used as an integral component of the cement and not just as additives to concrete, larger amounts of the residues can be utilized. The process uses submerged combustion to melt blends of coal combustion residues with lime, clay, and/or sand. The submerged combustion melter utilizes natural gas-oxidant firing directly into a molten bath to provide efficient melting of mineral-like materials. Use of this melter for cement production has many advantages over rotary kilns including very little, if any, grinding of the feed material, very low emissions, and compact size. During the first year of the program, samples of coal combustion residues were blended and mixed, as needed; with lime, clay, and/or sand to adjust the composition. Six mixtures, three with fly ash and three with bottom ash, were melted in a laboratory-scale furnace. The resultant products were used in mortar cubes and bars which were subjected to ASTM standard tests of cementitious properties. In the hydraulic activity test, mortar cubes were found to have a strength comparable to standard mortar cements. In the compressive strength test, mortar cubes were found to have strengths that exceeded ASTM blended cement performance specifications. In the ASR expansion test, mortar bars were subjected to alkali-silica reaction-induced expansion, which is a problem for siliceous aggregate-based concretes that are exposed to moisture. The mortar bars made with the products inhibited 85 to 97% of this expansion. These results show that residue-based products have an excellent potential as ASR-preventing additions in concretes.

Wagner, J.C.; Bhatty, J.L.; Mishulovich, A.

1997-05-01T23:59:59.000Z

13

The variability of fly ash and its effects on selected properties of fresh Portland cement/fly ash mortars  

E-Print Network [OSTI]

the needed quality control of concrete . Another source of concern results from the recent development of lignite and sub-bituminous coal as fuel sources. The ash produced from these coals is of a different chemical composition than traditional bituminous... 50 percent to greater than 200 percent of a control test. An exhaustive literature review has revealed neglig1ble information concerning the PAI of sub- b1tuminous and lignite ashes. Research is greatly needed to determine the ash properties...

McKerall, William Carlton

1980-01-01T23:59:59.000Z

14

THE IMPACT OF DISSOLVED SALTS ON PASTES CONTAINING FLY ASH, CEMENT AND SLAG  

SciTech Connect (OSTI)

The degree of hydration of a mixture of cementitious materials (Class F fly ash, blast furnace slag and portland cement) in highly concentrated alkaline salt solutions is enhanced by the addition of aluminate to the salt solution. This increase in the degree of hydration, as monitored with isothermal calorimetry, leads to higher values of dynamic Young's modulus and compressive strength and lower values of total porosity. This enhancement in performance properties of these cementitious waste forms by increased hydration is beneficial to the retention of the radionuclides that are also present in the salt solution. The aluminate ions in the solution act first to retard the set time of the mix but then enhance the hydration reactions following the induction period. In fact, the aluminate ions increase the degree of hydration by {approx}35% over the degree of hydration for the same mix with a lower aluminate concentration. An increase in the blast furnace slag concentration and a decrease in the water to cementitious materials ratio produced mixes with higher values of Young's modulus and lower values of total porosity. Therefore, these operational factors can be fine tuned to enhance performance properties of cementitious waste form. Empirical models for Young modulus, heat of hydration and total porosity were developed to predict the values of these properties. These linear models used only statistically significant compositional and operational factors and provided insight into those factors that control these properties.

Harbour, J.; Edwards, T.; Williams, V.

2009-09-21T23:59:59.000Z

15

Nano-ChemoMechanical assessment of Rice Husk Ash cement by wavelength dispersive spectroscopy and nanoindentation  

E-Print Network [OSTI]

Cement global production stands at 3 Giga tons making concrete the most consumed structural mateial worldwide. This massively produced material comes with a heavy environmental footprint rendering the cement industry ...

Abuhaikal, Muhannad (Muhannad A. R.)

2011-01-01T23:59:59.000Z

16

Unprocessed rice husk ash as a partial replacement of cement for low-cost concrete  

E-Print Network [OSTI]

Cement is a very valuable commodity as it can be used to construct structurally sound buildings and infrastructure. However, in many developing countries cement is expensive due to the unavailability of local resources to ...

Brown, Dorothy Kamilah

2012-01-01T23:59:59.000Z

17

E-Print Network 3.0 - ash cement matrixes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 13 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: to a construc- tion material...

18

E-Print Network 3.0 - ash belite cement Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(WTERT) Collection: Renewable Energy 77 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: to a construc- tion material...

19

The effects of the mechanical–chemical stabilization process for municipal solid waste incinerator fly ash on the chemical reactions in cement paste  

SciTech Connect (OSTI)

Highlights: ? Milling extracted MSWI fly ash. ? Increasing specific surface area, destruction of the crystalline texture, and increasing the amount of amorphous materials. ? Increasing heavy metal stability. ? Inducing pozzolanic reactions and increasing the early and later strength of the cement paste. - Abstract: A water extraction process can remove the soluble salts present in municipal solid waste incinerator (MSWI) fly ash, which will help to increase the stability of the synthetic materials produced from the MSWI fly ash. A milling process can be used to stabilize the heavy metals found in the extracted MSWI fly ash (EA) leading to the formation of a non-hazardous material. This milled extracted MSWI fly ash (MEA) was added to an ordinary Portland cement (OPC) paste to induce pozzolanic reactions. The experimental parameters included the milling time (96 h), water to binder ratios (0.38, 0.45, and 0.55), and curing time (1, 3, 7 and 28 days). The analysis procedures included inductively coupled plasma atomic emission spectroscopy (ICP/AES), BET, mercury intrusion porosimetry (MIP), X-ray diffraction (XRD), and nuclear magnetic resonance (NMR) imaging. The results of the analyses indicate that the milling process helped to stabilize the heavy metals in the MEA, with an increase in the specific surface area of about 50 times over that of OPC. The addition of the MEA to the OPC paste decreased the amount of Ca(OH){sub 2} and led to the generation of calcium–silicate–hydrates (C–S–H) which in turned increased the amount of gel pores and middle sized pores in the cement. Furthermore, a comparison shows an increase in the early and later strength over that of OPC paste without the addition of the milled extracted ash. In other words, the milling process could stabilize the heavy metals in the MEA and had an activating effect on the MEA, allowing it to partly substitute OPC in OPC paste.

Chen, Cheng-Gang [Department of Water Resources and Environmental Engineering, Tamkang University, 151, Ying-chung Road, Tamsui Dist., New Taipei City 251, Taiwan, ROC (China); Sun, Chang-Jung, E-mail: sun.3409@hotmail.com [Department of Environmental Technology and Management, Taoyuan Innovation Institute of Technology, 414, Sec. 3, Jhongshan E. Rd., Zhongli City, Taoyuan County 320, Taiwan, ROC (China); Gau, Sue-Huai; Wu, Ching-Wei; Chen, Yu-Lun [Department of Water Resources and Environmental Engineering, Tamkang University, 151, Ying-chung Road, Tamsui Dist., New Taipei City 251, Taiwan, ROC (China)

2013-04-15T23:59:59.000Z

20

Cement technology for borehole plugging: interim report on the effects of fly ash and salt on the physical properties of cementitious solids  

SciTech Connect (OSTI)

Results of initial studies of a systematic investigation to determine the effects of fly ash and salt on the physical properties of pozzolanic concretes and saltcretes are reported. Addition of fly ash to mortars decreased the set time and bleed characteristics and increased the compressive strength and permeability, but it had very little effect on the density or the thermal conductivity of the solid. The magnitude of these effects was only slightly related to the lime content of the fly ash. In the case of saltcretes, low-lime fly ash slightly decreased the set time and the bleed characteristics of the wet mix. However, a high-lime fly ash doubled the set time and decreased the bleed characteristics to essentially zero. The compressive strength of saltcretes was increased by the addition of fly ash and was independent of the lime content. Such additions had little effect on the thermal conductivity or density. The thermal conductivities of cement pastes containing fly ash showed a near-linear relationship with the density of the resulting solids. In the case of mortars, the thermal conductivity decreased with increasing temperature and showed some hysteresis in the initial heating cycle. After the first cycle, the thermal conductivity decreased from about 1.32 W/m.K at 350/sup 0/K to 1.27 W/m.K at 475/sup 0/K.

Moore, J.G.; Morgan, M.T.; McDaniel, E.W.; Greene, H.B.; West, W.A.

1980-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

A Directory of Dedicated Commemorative Groves, Trees and Display Plantings (sorted by common name)  

E-Print Network [OSTI]

) University of Idaho Arboretum Botanical Garden Paul Warnick Common Name Scientific Name Commemorating Ash North America Fraxinus pennsylvanica, americana etc. Idaho Public Utilities Executives' Course Aspen Groves, Trees and Display Plantings (sorted by common name) University of Idaho Arboretum Botanical

Waits, Lisette

22

Thermal Shock-resistant Cement  

SciTech Connect (OSTI)

We studied the effectiveness of sodium silicate-activated Class F fly ash in improving the thermal shock resistance and in extending the onset of hydration of Secar #80 refractory cement. When the dry mix cement, consisting of Secar #80, Class F fly ash, and sodium silicate, came in contact with water, NaOH derived from the dissolution of sodium silicate preferentially reacted with Class F fly ash, rather than the #80, to dissociate silicate anions from Class F fly ash. Then, these dissociated silicate ions delayed significantly the hydration of #80 possessing a rapid setting behavior. We undertook a multiple heating -water cooling quenching-cycle test to evaluate the cement’s resistance to thermal shock. In one cycle, we heated the 200 and #61616;C-autoclaved cement at 500 and #61616;C for 24 hours, and then the heated cement was rapidly immersed in water at 25 and #61616;C. This cycle was repeated five times. The phase composition of the autoclaved #80/Class F fly ash blend cements comprised four crystalline hydration products, boehmite, katoite, hydrogrossular, and hydroxysodalite, responsible for strengthening cement. After a test of 5-cycle heat-water quenching, we observed three crystalline phase-transformations in this autoclaved cement: boehmite and #61614; and #61543;-Al2O3, katoite and #61614; calcite, and hydroxysodalite and #61614; carbonated sodalite. Among those, the hydroxysodalite and #61614; carbonated sodalite transformation not only played a pivotal role in densifying the cementitious structure and in sustaining the original compressive strength developed after autoclaving, but also offered an improved resistance of the #80 cement to thermal shock. In contrast, autoclaved Class G well cement with and without Class F fly ash and quartz flour failed this cycle test, generating multiple cracks in the cement. The major reason for such impairment was the hydration of lime derived from the dehydroxylation of portlandite formed in the autoclaved cement, causing its volume to expand.

Sugama T.; Pyatina, T.; Gill, S.

2012-02-01T23:59:59.000Z

23

E-Print Network 3.0 - aluminate cement blended Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

predicting the setting times of Type I cement concrete and blended... -29, 1980. 20. Tay, J. .H., Properties of Pulverized Sludge Ash Blended Cement. ACI Materials Journals... OF...

24

Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

2010. Cement and concrete nanoscience and nanotechnology.of 100 Percent Fly Ash Concrete. 2005 World of Coal Ash (carbon dioxide in precast concrete. TECHNOLOGY REVIEW – A

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

25

E-Print Network 3.0 - ash based gepolymer Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: . CHARACTERIZATION AND APPLICATION OF CLASS F FLY ASH AND CLEAN-COAL ASH FOR CEMENT-BASED MATERIALS 2 The major... large amounts of conventional or...

26

E-Print Network 3.0 - aluminate cements hydration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

INTRODUCTION Many entities currently use fly ash in portland cement concrete (PCC) pavements... Transportation & Development and Louisiana State University incorporating...

27

Fly ash carbon passivation  

DOE Patents [OSTI]

A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

La Count, Robert B; Baltrus, John P; Kern, Douglas G

2013-05-14T23:59:59.000Z

28

Pioneer Grove | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth'sOklahoma/GeothermalOrangePeru:Job Corp Jump to: navigation,Grove Facility

29

Reduction of NO{sub x} emissions from cement kiln/calciner through the use of the NO{sub x}OUT process  

SciTech Connect (OSTI)

The post combustion reduction of NO{sub x} using urea has proven to be an effective method in controlling NO{sub x} from various combustion sources. This process, a selective non-catalytic reduction process known as NO{sub x}OUT, has been successfully demonstrated in a cement kiln/calciner operated by Ash Grove Cement. Testing was done under ten different kiln/calciner operating conditions. Using three to four injectors, NO{sub x} was efficiently reduced from 350--600 pounds per hour (3.5--6.0 lb/ton of clinker) to less than 100 pounds per hour (1.0 lb/ton of clinker). This calculates to a NO{sub x} reduction of > 80% for most cases. Chemical utilization was greater than 50%. A high degree of mixing and a long residence time at an appropriate temperature present in the preheater tower contributed to these excellent results. An average ammonia slip was four ppm above a baseline level at normalized stoichiometric ratio of 1. Based on this demonstration, cement kiln/calciners have been identified as an ideal application for the NO{sub x}OUT Process. NO{sub x} was efficiently and effectively reduced with minimal byproduct emissions and virtually no effect on plant operations.

Sun, W.H. [Nalco Fuel Tech., Naperville, IL (United States); Bisnett, M.J.; Kirk, D.W. [Nalco Fuel Tech, Santa Fe Springs, CA (United States); Steuch, H.E. [Ash Grove Cement Co., Portland, OR (United States); Hille, J. [Ash Grove Cement Co., Seattle, WA (United States)

1994-12-31T23:59:59.000Z

30

Wilders Grove Solid Waste Services Center | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Grove Solid Waste Services Center Project objective: Provide demonstration of Geothermal Heat Pumps viability on energy usage for future Service Centers planned by the City of...

31

Ash pelletization  

SciTech Connect (OSTI)

Ash pelletization is outlined under the following topics: projects with CSX involvement; US Generating (Cedar Bay), Jacksonville, FL; Hydra-Co (Salt City Project), Solvay, NY; Virginia Power, Yorktown Plant; US Generating; Indiantown, FL; Future Projects; Development of ash disposal site;s Reuse of ash product; and Utility Survey.

Woodall, M.

1994-12-31T23:59:59.000Z

32

Camp Grove Wind Farm | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreis aCallahan Divide Wind EnergyEnergyCameroon: EnergyGrove

33

Grove Theatre | Y-12 National Security Complex  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky LearningGetGraphene's 3DRiseAdministrationPolicyGrove

34

2007 world of coal ash conference proceedings  

SciTech Connect (OSTI)

The theme of the conference was science, applications and sustainability. Papers are presented under the following topics: aggregates/geotechnology; agriculture; ash facility; management; CCT products; cement and concrete; chemistry and mineralogy; emerging technology; environmental; LOI/beneficiation/handling; mercury; mining and regulations and standards. The poster papers are included as well.

NONE

2007-07-01T23:59:59.000Z

35

Compressive strength of concrete and mortar containing fly ash  

DOE Patents [OSTI]

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1997-01-01T23:59:59.000Z

36

Compressive strength of concrete and mortar containing fly ash  

DOE Patents [OSTI]

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-04-29T23:59:59.000Z

37

Compressive strength of concrete and mortar containing fly ash  

DOE Patents [OSTI]

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1998-01-01T23:59:59.000Z

38

Compressive strength of concrete and mortar containing fly ash  

DOE Patents [OSTI]

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1998-12-29T23:59:59.000Z

39

Forest Grove Light and Power- Energy Efficiency Rebate Programs  

Broader source: Energy.gov [DOE]

Forest Grove Light and Power offers a variety of rebates through their Conservation Services Department. Rebates vary based on technology, and are available to residential, commercial, and/or...

40

Approaches to the petrographic characterization of fly ash  

SciTech Connect (OSTI)

The enhanced understanding of fly ash properties provided by petrographic analysis, a level of detail chemical analysis cannot provide, will be essential in the upgrading and utilization of fly ash produced in boilers retrofitted to meet clean air standards. Howe et al estimated that over 25% of the fly ash produced in Kentucky in 1992 would not have met the Kentucky Department of Transportation limit of 3% loss-on-ignition (LOI) for class F fly ash used as a Portland cement admixture. The conversion of boilers to low-NO{sub x} emission units increases fly ash carbon, hence LOI, by 150-200% rendering the fly ash unsuitable for highway construction use in concrete. The preservation of fly ash`s market share will require increased attention to the removal of excess carbon from the fly ash. In this paper, we will discuss the basic components of fly ash. An example of the petrographic analysis of fly ash from a Kentucky power plant will be used to illustrate the partitioning of fly ash components by size, as well as within the fly ash collection system.

Hower, J.C.; Rathbone, R.F.; Graham, U.M. [Univ. of Kentucky, Lexington, KY (United States)] [and others

1995-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Comparison of modified sulfur cement and hydraulic cement for encapsulation of radioactive and mixed wastes  

SciTech Connect (OSTI)

The majority of solidification/stabilization systems for low-level radioactive waste (LLW) and mixed waste, both in the commercial sector and at Department of Energy (DOE) facilities, utilize hydraulic cement (such as portland cement) to encapsulate waste materials and yield a monolithic solid waste form for disposal. A new and innovative process utilizing modified sulfur cement developed by the US Bureau of Mines has been applied at Brookhaven National Laboratory (BNL) for the encapsulation of many of these problem'' wastes. Modified sulfur cement is a thermoplastic material, and as such, it can be heated above it's melting point (120{degree}C), combined with dry waste products to form a homogeneous mixture, and cooled to form a monolithic solid product. Under sponsorship of the DOE, research and development efforts at BNL have successfully applied the modified sulfur cement process for treatment of a range of LLWs including sodium sulfate salts, boric acid salts, and incinerator bottom ash and for mixed waste contaminated incinerator fly ash. Process development studies were conducted to determine optimal waste loadings for each waste type. Property evaluation studies were conducted to test waste form behavior under disposal conditions by applying relevant performance testing criteria established by the Nuclear Regulatory Commission (for LLW) and the Environmental Protection Agency (for hazardous wastes). Based on both processing and performance considerations, significantly greater waste loadings were achieved using modified sulfur cement when compared with hydraulic cement. Technology demonstration of the modified sulfur cement encapsulation system using production-scale equipment is scheduled for FY 1991. 12 refs., 8 figs., 3 tabs.

Kalb, P.D.; Heiser, J.H. III; Colombo, P.

1990-01-01T23:59:59.000Z

42

High-performance, high-volume fly ash concrete  

SciTech Connect (OSTI)

This booklet offers the construction professional an in-depth description of the use of high-volume fly ash in concrete. Emphasis is placed on the need for increased utilization of coal-fired power plant byproducts in lieu of Portland cement materials to eliminate increased CO{sub 2} emissions during the production of cement. Also addressed is the dramatic increase in concrete performance with the use of 50+ percent fly ash volume. The booklet contains numerous color and black and white photos, charts of test results, mixtures and comparisons, and several HVFA case studies.

NONE

2008-01-15T23:59:59.000Z

43

Properties of concrete incorporating high volumes of ASTM Class F fly ash  

E-Print Network [OSTI]

This thesis presents the results of research performed in developing high-volume fly ash (HVFA) concrete incorporating ASTM Type I cement and ASTM Class F fly ash from Big Brown Power Plant of TU Electric, Texas. In HVFA concrete, the proportion...

Li, Wei Tung

1995-01-01T23:59:59.000Z

44

E-Print Network 3.0 - artificial fly ash-clay Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fly ash-clay Page: << < 1 2 3 4 5 > >> 1 Study of composite cement containing burned oil shale Summary: studied. Context SiO2 CaO Al2O3 OPC BFS Class C fly ash Clays Metakaolin...

45

Corrosion-resistant Foamed Cements for Carbon Steels  

SciTech Connect (OSTI)

The cementitious material consisting of Secar #80, Class F fly ash, and sodium silicate designed as an alternative thermal-shock resistant cement for the Enhanced Geothermal System (EGS) wells was treated with cocamidopropyl dimethylamine oxide-based compound as foaming agent (FA) to prepare numerous air bubble-dispersed low density cement slurries of and #61603;1.3 g/cm3. Then, the foamed slurry was modified with acrylic emulsion (AE) as corrosion inhibitor. We detailed the positive effects of the acrylic polymer (AP) in this emulsion on the five different properties of the foamed cement: 1) The hydrothermal stability of the AP in 200 and #61616;C-autoclaved cements; 2) the hydrolysis-hydration reactions of the slurry at 85 and #61616;C; 3) the composition of crystalline phases assembled and the microstructure developed in autoclaved cements; 4) the mechanical behaviors of the autoclaved cements; and, 5) the corrosion mitigation of carbon steel (CS) by the polymer. For the first property, the hydrothermal-catalyzed acid-base interactions between the AP and cement resulted in Ca-or Na-complexed carboxylate derivatives, which led to the improvement of thermal stability of the AP. This interaction also stimulated the cement hydration reactions, enhancing the total heat evolved during cement’s curing. Addition of AP did not alter any of the crystalline phase compositions responsible for the strength of the cement. Furthermore, the AP-modified cement developed the porous microstructure with numerous defect-free cavities of disconnected voids. These effects together contributed to the improvement of compressive-strength and –toughness of the cured cement. AP modification of the cement also offered an improved protection of CS against brine-caused corrosion. There were three major factors governing the corrosion protection: 1) Reducing the extents of infiltration and transportation of corrosive electrolytes through the cement layer deposited on the underlying CS surfaces; 2) inhibiting the cathodic reactions at the corrosion site of CS; 3) extending the coverage of cement over CS surfaces; and, 4) improving the adherence of the cement to CS surfaces. Thus, the CS’s corrosion rate of 176 milli inch/per year (mpy) for 1 wt% FA-foamed cement without AP was considerably reduced to 69 mpy by adding only 2 wt% AP. Addition of AP at 10 wt% further reduced this rate to less than 10 mpy.

Sugama T.; Gill, S.; Pyatina, T., Muraca, A.; Keese, R.; Khan, A.; Bour, D.

2012-12-01T23:59:59.000Z

46

Alternative Fuel for Portland Cement Processing  

SciTech Connect (OSTI)

The production of cement involves a combination of numerous raw materials, strictly monitored system processes, and temperatures on the order of 1500 °C. Immense quantities of fuel are required for the production of cement. Traditionally, energy from fossil fuels was solely relied upon for the production of cement. The overarching project objective is to evaluate the use of alternative fuels to lessen the dependence on non-renewable resources to produce portland cement. The key objective of using alternative fuels is to continue to produce high-quality cement while decreasing the use of non-renewable fuels and minimizing the impact on the environment. Burn characteristics and thermodynamic parameters were evaluated with a laboratory burn simulator under conditions that mimic those in the preheater where the fuels are brought into a cement plant. A drop-tube furnace and visualization method were developed that show potential for evaluating time- and space-resolved temperature distributions for fuel solid particles and liquid droplets undergoing combustion in various combustion atmospheres. Downdraft gasification has been explored as a means to extract chemical energy from poultry litter while limiting the throughput of potentially deleterious components with regards to use in firing a cement kiln. Results have shown that the clinkering is temperature independent, at least within the controllable temperature range. Limestone also had only a slight effect on the fusion when used to coat the pellets. However, limestone addition did display some promise in regards to chlorine capture, as ash analyses showed chlorine concentrations of more than four times greater in the limestone infused ash as compared to raw poultry litter. A reliable and convenient sampling procedure was developed to estimate the combustion quality of broiler litter that is the best compromise between convenience and reliability by means of statistical analysis. Multi-day trial burns were conducted at a full-scale cement plant with alternative fuels to examine their compatibility with the cement production process. Construction and demolition waste, woodchips, and soybean seeds were used as alternative fuels at a full-scale cement production facility. These fuels were co-fired with coal and waste plastics. The alternative fuels used in this trial accounted for 5 to 16 % of the total energy consumed during these burns. The overall performance of the portland cement produced during the various trial burns performed for practical purposes very similar to the cement produced during the control burn. The cement plant was successful in implementing alternative fuels to produce a consistent, high-quality product that increased cement performance while reducing the environmental footprint of the plant. The utilization of construction and demolition waste, woodchips and soybean seeds proved to be viable replacements for traditional fuels. The future use of these fuels depends on local availability, associated costs, and compatibility with a facilityâ??s production process.

Anton K. Schindler; Steve R. Duke; Thomas E. Burch; Edward W. Davis; Ralph H. Zee; David I. Bransby; Carla Hopkins; Rutherford L. Thompson; Jingran Duan; Vignesh Venkatasubramanian; Stephen Giles.

2012-06-30T23:59:59.000Z

47

Final work plan : environmental site investigation at Sylvan Grove, Kansas.  

SciTech Connect (OSTI)

In 1998, carbon tetrachloride was found above the maximum contaminant level (MCL) of 5 {micro}g/L in groundwater from one private livestock well at Sylvan Grove, Kansas, by the Kansas Department of Health and Environment (KDHE). The 1998 KDHE sampling was conducted under the U.S. Department of Agriculture (USDA) private well sampling program. The Commodity Credit Corporation (CCC), a USDA agency, operated a grain storage facility in Sylvan Grove from 1954 to1966. Carbon tetrachloride is the contaminant of primary concern at sites associated with former CCC/USDA grain storage operations. Sylvan Grove is located in western Lincoln County, approximately 60 mi west of Salina (Figure 1.1). To determine whether the former CCC/USDA facility at Sylvan Grove is a potential contaminant source and its possible relationship to the contamination in groundwater, the CCC/USDA has agreed to conduct an investigation, in accordance with the Intergovernmental Agreement between the KDHE and the Farm Service Agency (FSA) of the USDA. This Work Plan presents historical data related to previous investigations, grain storage operations, local private wells and public water supply (PWS) wells, and local geologic and hydrogeologic conditions at Sylvan Grove. The findings from a review of all available documents are discussed in Section 2. On the basis of the analyses of historical data, the following specific technical objectives are proposed for the site investigation at Sylvan Grove: (1) Evaluate the potential source of carbon tetrachloride at the former CCC/USDA facility; (2) Determine the relationship of potential contamination (if present) at the former CCC/USDA facility to contamination identified in 1998 in groundwater samples from one private well to the west; and (3) Delineate the extent of potential contamination associated with the former CCC/USDA facility. The detailed scope of work is outlined in Section 3. The results of the proposed work will provide the basis for determining what future CCC/USDA actions may be necessary, with the ultimate goal of achieving classification of the Sylvan Grove site at no further action status. The proposed activities are to be performed on behalf of the CCC/USDA by the Environmental Science Division of Argonne National Laboratory, a nonprofit, multidisciplinary research center operated by the UChicago Argonne, LLC, for the U.S. Department of Energy. Argonne provides technical assistance to the CCC/USDA concerning environmental site characterization and remediation at former grain storage facilities. Argonne issued a Master Work Plan (Argonne 2002) that has been approved by the KDHE. The Master Work Plan describes the general scope of all investigations at former CCC/USDA facilities in Kansas and provides guidance for these investigations. That document should be consulted for the complete details of plans for work associated with the former CCC/USDA facility at Sylvan Grove.

LaFreniere, L. M. (Environmental Science Division)

2012-07-15T23:59:59.000Z

48

Utilizing New Binder Materials for Green Building has Zero Waste by Recycling Slag and Sewage Sludge Ash  

E-Print Network [OSTI]

binding material to save energy and to produce new innovative zero materials waste . The current research aims to investigate new binder materials as alternative of Portland cement. Alkali activated slag (AAS) blended with sewage sludge ash (SSA...

Zeedan, S. R.

2010-01-01T23:59:59.000Z

49

Leland Grove, Illinois: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey, Washington:Lakeville,Leighton Contractors Pty Ltd JumpLeland Grove,

50

Loxahatchee Groves, Florida: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(MonasterLowell Point, Alaska: Energy Resources JumpA,Loxahatchee Groves,

51

Willow Grove, Pennsylvania: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperative JumpWilliamson County, Tennessee: EnergyWillis,Grove, Pennsylvania:

52

Pecan Grove, Texas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy ResourcesLoading map...(UtilityCounty,OrleansPassadumkeag, Maine:Pawnee isPearland,Grove, Texas: Energy

53

Franklin Grove, Illinois: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates9. ItFranklin Grove, Illinois:

54

City of Grove City, Minnesota (Utility Company) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartmentAUDITOhio (Utility Company)Galion, OhioInformation Cove, TexasGriffin,Grove

55

City of Long Grove, Iowa (Utility Company) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartmentAUDITOhio (UtilityHolyrood, KansasLampasas, TexasLexingtonLodgepole,Long Grove

56

Problems in squeeze cementing  

SciTech Connect (OSTI)

For the past half century, work has been carried out to improve squeeze cementing. During the course of time, new techniques, equipment, cement and cement additives were introduced. Work is still underway to improve squeeze cementing. Basic concept of squeeze cementing, understanding the problems, planning for a squeeze job and then later testing of the job help in achieving the goal. Solutions were offered to some common problems, whereas many regional problems need time to time study and effort. Squeezing long perforations in highly permeable sand has always been a problem, for which some techniques were presented.

Toor, I.A.

1983-03-01T23:59:59.000Z

57

Hydrothermal reaction of fly ash. Final report  

SciTech Connect (OSTI)

The reactions which occur when fly ash is treated under hydrothermal conditions were investigated. This was done for the following primary reasons. The first of these is to determine the nature of the phases that form to assess the stabilities of these phases in the ambient environment and, finally, to assess whether these phases are capable of sequestering hazardous species. The second reason for undertaking this study was whether, depending on the composition of the ash and the presence of selected additives, it would be possible under hydrothermal conditions to form compounds which have cementitious properties. Formation of four classes of compounds, which bracket likely fly ash compositional ranges, were selected for study. The classes are calcium silicate hydrates, calcium selenates, and calcium aluminosulfates, and silicate-based glasses. Specific compounds synthesized were determined and their stability regions assessed. As part of stability assessment, the extent to which selected hazardous species are sequestered was determined. Finally, the cementing properties of these compounds were established. The results obtained in this program have demonstrated that mild hydrothermal conditions can be employed to improve the reactivity of fly ash. Such improvements in reactivity can result in the formation of monolithic forms which may exhibit suitable mechanical properties for selected applications as building materials. If the ashes involved are considered hazardous, the mechanical properties exhibited indicated the forms could be handled in a manner which facilitates their disposal.

Brown, P.W.

1994-12-31T23:59:59.000Z

58

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash  

DOE Patents [OSTI]

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-10-28T23:59:59.000Z

59

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash  

DOE Patents [OSTI]

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

Liskowitz, John W. (Belle Mead, NJ); Wecharatana, Methi (Parsippany, NJ); Jaturapitakkul, Chai (Bangkok, TH); Cerkanowicz, deceased, Anthony E. (late of Livingston, NJ)

1997-01-01T23:59:59.000Z

60

Feasible experimental study on the utilization of a 300 MW CFB boiler desulfurizating bottom ash for construction applications  

SciTech Connect (OSTI)

CFB boiler ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. The disposal in landfills has been the most common means of handling ash in circulating fluidized bed boiler power plants. However for a 300 MW CFB boiler power plant, there will be 600,000 tons of ash discharged per year and will result in great volumes and disposal cost of ash byproduct. It was very necessary to solve the utilization of CFB ash and to decrease the disposal cost of CFB ash. The feasible experimental study results on the utilization of the bottom ashes of a 300 MW CFB boiler in Baima power plant in China were reported in this paper. The bottom ashes used for test came from the discharged bottom ashes in a 100 MW CFB boiler in which the anthracite and limestone designed for the 300 MW CFB project was burned. The results of this study showed that the bottom ash could be used for cementitious material, road concrete, and road base material. The masonry cements, road concrete with 30 MPa compressive strength and 4.0 MPa flexural strength, and the road base material used for base courses of the expressway, the main road and the minor lane were all prepared with milled CFB bottom ashes in the lab. The better methods of utilization of the bottom ashes were discussed in this paper.

Lu, X.F.; Amano, R.S. [University of Wisconsin, Milwaukee, WI (United States). Dept. of Mechanical Engineering

2006-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The influence of high quantity of fly ash on reducing the expansion due to ASR in the presence of alkalis  

E-Print Network [OSTI]

A testing program was devised to study the role of high volume fly ash (HVFA) in reducing the expansion caused by alkali-silica reaction (ASR). A series of modified ASTM C 1260 tests were performed, where the replacement of cement by Class F fly ash...

Mohidekar, Saleel D.

2000-01-01T23:59:59.000Z

62

MARKET ASSESSMENT AND TECHNICAL FEASIBILITY STUDY OF PRESSURIZED FLUIDIZED BED COMBUSTION ASH USE  

SciTech Connect (OSTI)

Western Research Institute, in conjunction with the Electric Power Research Institute, Foster Wheeler International, Inc. and the US Department of Energy, has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for PFBC ashes. Ashes from the Foster Wheeler Energia Oy pilot-scale circulating PFBC tests in Karhula, Finland, combusting (1) low-sulfur subbituminous and (2) high-sulfur bituminous coal, and ash from the AEP's high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at WR1. The technical feasibility study examined the use of PFBC ash in construction-related applications, including its use as a cementing material in concrete and use in cement manufacturing, fill and embankment materials, soil stabilization agent, and use in synthetic aggregate production. Testing was also conducted to determine the technical feasibility of PFBC ash as a soil amendment for acidic and sodic problem soils and spoils encountered in agricultural and reclamation applications. The results of the technical feasibility testing indicated the following conclusions. PFBC ash does not meet the chemical requirements as a pozzolan for cement replacement. However, it does appear that potential may exist for its use in cement production as a pozzolan and/or as a set retardant. PFBC ash shows relatively high strength development, low expansion, and low permeability properties that make its use in fills and embankments promising. Testing has also indicated that PFBC ash, when mixed with low amounts of lime, develops high strengths, suitable for soil stabilization applications and synthetic aggregate production. Synthetic aggregate produced from PFBC ash is capable of meeting ASTM/AASHTO specifications for many construction applications. The residual calcium carbonate and calcium sulfate in the PFE3C ash has been shown to be of value in making PFBC ash a suitable soil amendment for acidic and sodic problem soils and mine spoils. In conclusion, PFBC ash represents a viable material for use in currently established applications for conventional coal combustion ashes. As such, PFBC ash should be viewed as a valuable resource, and commercial opportunities for these materials should be explored for planned PFBC installations.

A.E. Bland; T.H. Brown

1997-04-01T23:59:59.000Z

63

Borough of Grove City, Pennsylvania (Utility Company) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey:formBlueBombayInformation Grove City Place:

64

Walnut Grove, California: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 South Place: Salt Lake City,Division ofGrove, California: Energy Resources

65

River Grove, Illinois: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, searchVirginia Blue RidgeUniversityMedio, New Mexico:LimitedEdge, NewGrove is

66

EcoGrove Wind Farm | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6 No revision hasESEInformation Smart WindEco SunEcoGrove

67

Cherry Grove, Ohio: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information onChemithon EnterprisesGrove, Ohio: Energy Resources Jump

68

Elk Grove, California: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It is classifiedProject) | OpenTexas: Energy Resources4 ClimateGrove,

69

Activation of fly ash  

DOE Patents [OSTI]

Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

Corbin, David R. (New Castle, DE); Velenyi, Louis J. (Lyndhurst, OH); Pepera, Marc A. (Northfield, OH); Dolhyj, Serge R. (Parma, OH)

1986-01-01T23:59:59.000Z

70

Activation of fly ash  

DOE Patents [OSTI]

Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

Corbin, D.R.; Velenyi, L.J.; Pepera, M.A.; Dolhyj, S.R.

1986-08-19T23:59:59.000Z

71

Alex Benson Cement Plants  

E-Print Network [OSTI]

with steel balls which grind mix into a fine powder -> Final Cement Product Associated Air Pollution: o From health effects Relative News; o "EPA Clamps down on Cement Plant Pollution" http.4 million dollars for violating the Clean Air Act and 2 million dollars for pollution controls #12

Toohey, Darin W.

72

History and some potentials of oil shale cement  

SciTech Connect (OSTI)

The utilization of oil shale as a cement component is discussed. It was investigated in America and Europe during World War I. Additional development occurred in Western Europe, Russia, and China during the 1920s and 1930s. World War II provided further development incentives and a relatively mature technology was in place in Germany, Russia, and China prior to 1980. The utilization of oil shale in cement has taken a number of different paths. One approach has been to utilize the energy in the oil shale as the principal source for the cement plant and to use the combusted shale as a minor constituent of the plant's cement product. A second approach has been to use the combusted shale as a class C or cementitious fly-ash component in portland cement concrete. Other approaches utilizing eastern oil shale have been to use the combusted oil shale with additives as a specialty cement, or to cocombust the oil shale with coal and utilize the sulfur-rich combustion product.

Knutson, C.F.; Smith, R.P.; Russell, B.F. (Idaho National Engineering Lab., Idaho Falls, ID (USA))

1989-01-01T23:59:59.000Z

73

Oppenheimer&Groves : The duality that led to Trinity /.  

SciTech Connect (OSTI)

The alliance of J. Robert Oppenheimer, scientist, and Leslie R. Groves, military leader, is often interpreted as the classic example of the clash between the academic mind and the military style. Evidence suggests, instead, that it was a collaboration that led to the dawn of the nuclear age. Instead of a clash, it was collaboration and an implosion of the diverse talents needed for the success of this project. Discussion of these flawed and fascinating individuals still ignites controversy today. This presentation will explore the backgrounds and personalities of these two men and their work together to accomplish their mission. Was the aftermath inevitable, given a relationship based on respect, but perhaps not trust? The genesis of the modern military-industrial complex rested on the genius of these two men, though they personify two distinct American sub-cultures. What lessons can be drawn from their wartime and post-war relationship? What analogies can be drawn for current American values?

Connaughton, T. G. (Theresa G.); Smith, S. E. (Sharon E.)

2001-01-01T23:59:59.000Z

74

Market Assessment and Technical Feasibility Study of Pressurized Fluidized Bed Combustion Ash Use  

SciTech Connect (OSTI)

Western Research Institute in conjunction with the Electric Power Research Institute, Foster Wheeler Energy International, Inc. and the U.S. Department of Energy Technology Center (METC), has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for pressurized fluidized bed combustion (PFBC) ashes. The assessment is designed to address six applications, including: (1) structural fill, (2) road base construction, (3) supplementary cementing materials in portland cement, (4) synthetic aggregate, and (5) agricultural/soil amendment applications. Ash from low-sulfur subbituminous coal-fired Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, and ash from the high-sulfur bituminous coal-fired American Electric Power (AEP) bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing. This paper addresses the technical feasibility of ash use options for PFBC unit using low- sulfur coal and limestone sorbent (karhula ash) and high-sulfur coal and dolomite sorbents (AEP Tidd ash).

Bland, A.E.; Brown, T.H. [Western Research Inst., Laramie, WY (United States)

1996-12-31T23:59:59.000Z

75

A Review of Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

- Environmental Advantages. Available at http://www.ceratechinc.com/environmental- advantages.asp Cross, D., J. Stephens, J. Vollmer. 2005. Structural Applications of 100 Percent Fly Ash Concrete. 2005 World of Coal Ash (WOCA), Lexington, Kentucky, USAApril...://recocement.com/ Roskos, C., D. Cross, M. Berry, J. Stephens. 2011. Identification and Verification of Self-Cementing Fly Ash Binders for ?Green? Concrete. 2011 World of Coal Ash (WOCA) Conference ? May 9-12, 2011 in Denver CO, USA. Available at www.flyash.info/2011...

Hasanbeigi, A.; Price, L.; Lin, E.

2012-01-01T23:59:59.000Z

76

Thermodynamics and cement science  

SciTech Connect (OSTI)

Thermodynamics applied to cement science has proved to be very valuable. One of the most striking findings has been the extent to which the hydrate phases, with one conspicuous exception, achieve equilibrium. The important exception is the persistence of amorphous C-S-H which is metastable with respect to crystalline calcium silicate hydrates. Nevertheless C-S-H can be included in the scope of calculations. As a consequence, from comparison of calculation and experiment, it appears that kinetics is not necessarily an insuperable barrier to engineering the phase composition of a hydrated Portland cement. Also the sensitivity of the mineralogy of the AFm and AFt phase compositions to the presence of calcite and to temperature has been reported. This knowledge gives a powerful incentive to develop links between the mineralogy and engineering properties of hydrated cement paste and, of course, anticipates improvements in its performance leading to decreasing the environmental impacts of cement production.

Damidot, D., E-mail: damidot@ensm-douai.fr [Universite Lille Nord de France (France); EM Douai, LGCgE-MPE-GCE, Douai (France); Lothenbach, B. [Empa, Lab. Concrete and Construction Chemistry, Duebendorf (Switzerland); Herfort, D. [Cementir Holding (Denmark); Glasser, F.P. [Chemistry Department, University of Aberdeen, Aberdeen (United Kingdom)

2011-07-15T23:59:59.000Z

77

Cement Kiln Flue Gas Recovery Scrubber Project  

SciTech Connect (OSTI)

The Cement Kiln Flue Gas Recovery Scrubber Project was a technical success and demonstrated the following: CKD can be used successfully as the sole reagent for removing SO2 from cement kiln flue gas, with removal efficiencies of 90 percent or greater; Removal efficiencies for HCl and VOCs were approximately 98 percent and 70 percent, respectively; Particulate emissions were low, in the range of 0.005 to 0.007 grains/standard cubic foot; The treated CKD sorbent can be recycled to the kiln after its potassium content has been reduced in the scrubber, thereby avoiding the need for landfilling; The process can yield fertilizer-grade K2SO4, a saleable by-product; and Waste heat in the flue gas can provide the energy required for evaporation and crystallization in the by-product recovery operation. The demonstration program established the feasibility of using the Recovery Scrubber{trademark} for desulfurization of flue gas from cement kilns, with generally favorable economics, assuming tipping fees are available for disposal of ash from biomass combustion. The process appears to be suitable for commercial use on any type of cement kiln. EPA has ruled that CKD is a nonhazardous waste, provided the facility meets Performance Standards for the Management of CKD (U.S. Environmental Protection Agency 1999d). Therefore, regulatory drivers for the technology focus more on reduction of air pollutants and pollution prevention, rather than on treating CKD as a hazardous waste. Application of the Recovery Scrubbe{trademark} concept to other waste-disposal operations, where pollution and waste reductions are needed, appears promising.

National Energy Technology Laboratory

2001-11-30T23:59:59.000Z

78

Kinetics of fly ash beneficiation by carbon burnout. [Quarterly report], October 1, 1995--January 30, 1996  

SciTech Connect (OSTI)

The objective is to investigate the kinetics of beneficiation of fly ash by carbon burnout. The three year project that was proposed is a joint venture between Delmarva Power, a power generating company on the eastern shore of Maryland, and the University of Maryland Eastern Shore. The studies have focused on the beneficiation of fly ash by carbon burnout. The increasing use of coal fly ash as pozzolanic material in Portland cement concrete means that there is the highest economic potential in marketability of large volumes of fly ash. For the concrete industry to consider large scale use the fly ash must be of the highest quality. This means that the residual carbon content of the fly ash must have an acceptable loss on ignition (LOI) value, usually between 7--2% residual carbon. The economic gains to be had from low-carbon ash is a fact that is generally accepted by the electricity generating companies. However, since the cost of producing low-carbon in large quantities, based on present technology, far outweighs any financial gains, no electrical power company using coal as its fuel at present considers the effort worthwhile. The concrete industry would use fly ash in cement concrete mix if it can be assured of its LOI value. At present no utility company would give such assurance. Hence with several million tons of fly ash produced by a single power plant per year all that can be done is to dump the fly ash in landfills. The kinetics of fly ash beneficiation have been investigated in the zone II kinetic regime, using a Cahn TG 121 microbalance in the temperature 550--750{degrees}C. The P{sub 02} and total surface area dependence of the reaction kinetics were determined using a vacuum accessory attached to the microbalance and a surface area analyzer (ASAP 2010), respectively.

Dodoo, J.N.; Okoh, J.M.; Yilmaz, E.

1996-09-01T23:59:59.000Z

79

Assessment of gas-side fouling in cement plants  

SciTech Connect (OSTI)

The purpose of this study is to provide an assessment of gas-side fouling in cement plants with special emphasis on heat recovery applications. Exhaust gases in the cement industry which are suitable for heat recovery range in temperature from about 400 to 1300 K, are generally dusty, may be highly abrasive, and are often heavily laden with alkalies, sulfates, and chlorides. Particulates in the exhaust streams range in size from molecular to about 100 ..mu..m in diameter and come from both the raw feed as well as the ash in the coal which is the primary fuel used in the cement industry. The major types of heat-transfer equipment used in the cement industry include preheaters, gas-to-air heat exchangers, waste heat boilers, and clinker coolers. The most important gas-side fouling mechanisms in the cement industry are those due to particulate, chemical reaction, and corrosion fouling. Particulate transport mechanisms which appear to be of greatest importance include laminar and turbulent mass transfer, thermophoresis, electrophoresis, and inertial impaction. Chemical reaction mechanisms of particular importance include the deposition of alkali sulfates, alkali chlorides, spurrite, calcium carbonate, and calcium sulfate. At sufficiently low temperatures, sulfuric acid and water can condense on heat exchanger surfaces which can cause corrosion and also attract particulates in the flow. The deleterious effects of gas-side fouling in cement plants are due to: (1) increased capital costs; (2) increased maintenance costs; (3) loss of production; and (4) energy losses. A conservative order-of-magnitude analysis shows that the cost of gas-side fouling in US cement plants is $0.24 billion annually.

Marner, W.J.

1982-09-01T23:59:59.000Z

80

ULTRA-LIGHTWEIGHT CEMENT  

SciTech Connect (OSTI)

The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses tasks performed in the fourth quarter as well as the other three quarters of the past year. The subjects that were covered in previous reports and that are also discussed in this report include: Analysis of field laboratory data of active cement applications from three oil-well service companies; Preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; Summary of pertinent information from Russian ultra-lightweight cement literature review; and Comparison of compressive strengths of ULHS systems using ultrasonic and crush methods Results reported from the fourth quarter include laboratory testing of ULHS systems along with other lightweight cement systems--foamed and sodium silicate slurries. These comparison studies were completed for two different densities (10.0 and 11.5 lb/gal) and three different field application scenarios. Additional testing included the mechanical properties of ULHS systems and other lightweight systems. Studies were also performed to examine the effect that circulation by centrifugal pump during mixing has on breakage of ULHS.

Fred Sabins

2001-10-23T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Full-scale tests of sulfur polymer cement and non-radioactive waste in heated and unheated prototypical containers  

SciTech Connect (OSTI)

Sulfur polymer cement has been demonstrated to be superior to portland cement in the stabilization of numerous troublesome low- level radioactive wastes, notably mixed waste fly ash, which contains heavy metals. EG G Idaho, Inc. conducted full-scale, waste-stabilization tests with a mixture of sulfur polymer cement and nonradioactive incinerator ash poured over simulated steel and ash wastes. The container used to contain the simulated waste for the pour was a thin-walled, rectangular, steel container with no appendages. The variable in the tests was that one container and its contents were at 65{degree}F (18{degree}C) at the beginning of the pour, while the other was preheated to 275{degree}F (135{degree}C) and was insulated before the pour. The primary goal was to determine the procedures and equipment deemed operationally acceptable and capable of providing the best probability of passing the only remaining governmental test for sulfur polymer cement, the Nuclear Regulatory Commission's full-scale test. The secondary goal was to analyze the ability of the molten cement and ash mixture to fill different size pipes and thus eliminate voids in the resultant 24 ft{sup 3} monolith.

Darnell, G.R.; Aldrich, W.C.; Logan, J.A.

1992-02-01T23:59:59.000Z

82

Full-scale tests of sulfur polymer cement and non-radioactive waste in heated and unheated prototypical containers  

SciTech Connect (OSTI)

Sulfur polymer cement has been demonstrated to be superior to portland cement in the stabilization of numerous troublesome low- level radioactive wastes, notably mixed waste fly ash, which contains heavy metals. EG&G Idaho, Inc. conducted full-scale, waste-stabilization tests with a mixture of sulfur polymer cement and nonradioactive incinerator ash poured over simulated steel and ash wastes. The container used to contain the simulated waste for the pour was a thin-walled, rectangular, steel container with no appendages. The variable in the tests was that one container and its contents were at 65{degree}F (18{degree}C) at the beginning of the pour, while the other was preheated to 275{degree}F (135{degree}C) and was insulated before the pour. The primary goal was to determine the procedures and equipment deemed operationally acceptable and capable of providing the best probability of passing the only remaining governmental test for sulfur polymer cement, the Nuclear Regulatory Commission`s full-scale test. The secondary goal was to analyze the ability of the molten cement and ash mixture to fill different size pipes and thus eliminate voids in the resultant 24 ft{sup 3} monolith.

Darnell, G.R.; Aldrich, W.C.; Logan, J.A.

1992-02-01T23:59:59.000Z

83

Kinetics of fly ash beneficiation by carbon burnout. Quarterly report, January--March 1996  

SciTech Connect (OSTI)

The three year project that was proposed is a joint venture between Delmarva Power, a power generating company on the eastern shore of Maryland, and the University of Maryland Eastern Shore. The studies have focused on the benefication of fly ash by carbon burnout. The increasing use of coal fly ash as pozzolanic material in Portland cement concrete means that there is the highest economic potential in marketability of large volumes of fly ash. For the concrete industry to consider large scale use the fly ash must be of the highest quality. This means that the residual carbon content of the fly ash must have an acceptable loss on ignition (LOI) value, usually between 7-2% residual carbon. The economic gains to be had from low-carbon ash is a fact that is generally accepted by the electricity generating companies. However, since the cost of producing low-carbon in large quantities, based on present technology, far outweighs any financial gains, no electrical power company using coal as its fuel at present considers the effort worthwhile. The concrete industry would use fly ash in cement concrete mix if it can be assured of its LOI value. At present no utility company would give such assurance. Hence with several million tons of fly ash produced by a single power plant per year all that can be done is to dump the fly ash in landfills. The kinetics of fly ash benefication have been investigated in the zone II kinetic regime, using a Cahn TG 121 microbalance in the temperature 550-750{degrees}C. The P{sub O{sub 2}} and total surface area dependence of the reaction kinetics were determined using a vacuum accessory attached to the microbalance and a surface area analyzer (ASAP 2010), respectively. 16 refs., 7 figs., 3 tabs.

Dodoo, J.N.; Okoh, J.M.; Yilmaz, E.

1996-09-01T23:59:59.000Z

84

High temperature lightweight foamed cements  

DOE Patents [OSTI]

Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

Sugama, Toshifumi.

1989-10-03T23:59:59.000Z

85

High temperature lightweight foamed cements  

DOE Patents [OSTI]

Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed.

Sugama, Toshifumi (Mastic Beach, NY)

1989-01-01T23:59:59.000Z

86

STARDUST INVESTIGATION INTO THE CR CHONDRITE GROVE MOUNTAIN 021710  

SciTech Connect (OSTI)

We report the presolar grain inventory of the CR chondrite Grove Mountain 021710. A total of 35 C-anomalous grains ({approx}236 ppm) and 112 O-anomalous grains ({approx}189 ppm) were identified in situ using NanoSIMS ion imaging. Of 35 C-anomalous grains, 28 were determined to be SiC grains by Auger spectroscopy. Seven of the SiC grains were subsequently measured for N and Si isotopes, allowing classification as one nova grain, one Y grain, one Z grain, and four mainstream grains. Eighty-nine out of 112 O-anomalous grains belong to Group 1, indicating origins in low-to-intermediate-mass red giant and asymptotic giant branch stars. Twenty-one are Group 4 grains and have origins in supernovae. Auger spectroscopic elemental measurements of 35 O-anomalous grains show that 33 of them are ferromagnesian silicates. They have higher Mg/(Mg+Fe) ratios than those reported in other meteorites, suggesting a lower degree of alteration in the nebula and/or asteroid parent bodies. Only two oxide grains were identified, with stoichiometric compositions of MgAl{sub 2}O{sub 4} and SiO{sub 2}, respectively. The presolar silicate/oxide ratio of GRV 021710 is comparable with those of the CR3 chondrites (QUE 99177 and MET 00426) and primitive interplanetary dust particles. In order to search for presolar sulfides, the meteorite was also mapped for S isotopes. However, no presolar sulfides were found, suggesting a maximum abundance of 2 ppm. The scarcity of presolar sulfides may be due to their much faster sputtering rate by cosmic rays compared to silicates.

Zhao Xuchao; Lin Yangting [Key Laboratory of the Earth's Deep Interior, Institute of Geology and Geophysics, Chinese Academy of Sciences, 19 Beituchengxi Road, Beijing 100029 (China); Floss, Christine [Laboratory for Space Sciences and Physics Department, Washington University, One Brookings Drive, St. Louis, MO 63130 (United States); Bose, Maitrayee, E-mail: linyt@mail.igcas.ac.cn [Department of Chemistry and Biochemistry, Arizona State University, P.O. Box 871604, Tempe, AZ 85287 (United States)

2013-05-20T23:59:59.000Z

87

Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry  

SciTech Connect (OSTI)

The Benchmarking and Energy Savings Tool (BEST) Cement is a process-based tool based on commercially available efficiency technologies used anywhere in the world applicable to the cement industry. This version has been designed for use in China. No actual cement facility with every single efficiency measure included in the benchmark will likely exist; however, the benchmark sets a reasonable standard by which to compare for plants striving to be the best. The energy consumption of the benchmark facility differs due to differences in processing at a given cement facility. The tool accounts for most of these variables and allows the user to adapt the model to operational variables specific for his/her cement facility. Figure 1 shows the boundaries included in a plant modeled by BEST Cement. In order to model the benchmark, i.e., the most energy efficient cement facility, so that it represents a facility similar to the user's cement facility, the user is first required to input production variables in the input sheet (see Section 6 for more information on how to input variables). These variables allow the tool to estimate a benchmark facility that is similar to the user's cement plant, giving a better picture of the potential for that particular facility, rather than benchmarking against a generic one. The input variables required include the following: (1) the amount of raw materials used in tonnes per year (limestone, gypsum, clay minerals, iron ore, blast furnace slag, fly ash, slag from other industries, natural pozzolans, limestone powder (used post-clinker stage), municipal wastes and others); the amount of raw materials that are preblended (prehomogenized and proportioned) and crushed (in tonnes per year); (2) the amount of additives that are dried and ground (in tonnes per year); (3) the production of clinker (in tonnes per year) from each kiln by kiln type; (4) the amount of raw materials, coal and clinker that is ground by mill type (in tonnes per year); (5) the amount of production of cement by type and grade (in tonnes per year); (6) the electricity generated onsite; and, (7) the energy used by fuel type; and, the amount (in RMB per year) spent on energy. The tool offers the user the opportunity to do a quick assessment or a more detailed assessment--this choice will determine the level of detail of the energy input. The detailed assessment will require energy data for each stage of production while the quick assessment will require only total energy used at the entire facility (see Section 6 for more details on quick versus detailed assessments). The benchmarking tool provides two benchmarks--one for Chinese best practices and one for international best practices. Section 2 describes the differences between these two and how each benchmark was calculated. The tool also asks for a target input by the user for the user to set goals for the facility.

Galitsky, Christina; Price, Lynn; Zhou, Nan; Fuqiu , Zhou; Huawen, Xiong; Xuemin, Zeng; Lan, Wang

2008-07-30T23:59:59.000Z

88

California bearing ratio behavior of soil-stabilized class F fly ash systems  

SciTech Connect (OSTI)

Fly ash is a finely divided mineral residue resulting from the combustion of coal in power plants that occupies large extents of land and also causes environmental problems. Hence, concerted attempts are being made to effectively use fly ash in an environmentally friendly way instead of dumping. Several studies have been carried out for its bulk utilization, such as its addition to improve the California bearing ratio (CBR) of soil in roads and embankments. But a thorough mixing of fly ash with soil may not be possible in the field. Hence a study has been carried out on the CBR behavior of black cotton soil and Raichur fly ash (which is class F) in layers and compared with the same in mixes. The results show that the CBR values of soil-fly ash mixes are better than layers, as expected. To improve the strength of layers, cement is used as an additive to fly ash. The results show that black cotton soil can be improved with stabilized fly ash, solving its strength problem as well as the disposal problem of fly ash.

Leelavathamma, B.; Mini, K.M.; Pandian, N.S. [Indian Institute for Science, Bangalore (India). Dept. for Civil Engineering

2005-11-01T23:59:59.000Z

89

Effect of Sodium Carboxymethyl Celluloses on Water-catalyzed Self-degradation of 200-degree C-heated Alkali-Activated Cement  

SciTech Connect (OSTI)

We investigated the usefulness of sodium carboxymethyl celluloses (CMC) in promoting self-degradation of 200°C-heated sodium silicate-activated slag/Class C fly ash cementitious material after contact with water. CMC emitted two major volatile compounds, CO2 and acetic acid, creating a porous structure in cement. CMC also reacted with NaOH from sodium silicate to form three water-insensitive solid reaction products, disodium glycolate salt, sodium glucosidic salt, and sodium bicarbonate. Other water-sensitive solid reaction products, such as sodium polysilicate and sodium carbonate, were derived from hydrolysates of sodium silicate. Dissolution of these products upon contact with water generated heat that promoted cement’s self-degradation. Thus, CMC of high molecular weight rendered two important features to the water-catalyzed self-degradation of heated cement: One was the high heat energy generated in exothermic reactions in cement; the other was the introduction of extensive porosity into cement.

Sugama T.; Pyatina, T.

2012-05-01T23:59:59.000Z

90

Integrating Design Tools for Building Design ROBERT W. AMOR, LINDSAY J. GROVES and MIKE R. DONN  

E-Print Network [OSTI]

Integrating Design Tools for Building Design ROBERT W. AMOR, LINDSAY J. GROVES and MIKE R. DONN for architectural design. Currently a large amount of information is duplicated in describing a building to different design tools. To enable designers to use different design tools to evaluate a building design

Amor, Robert

91

Ashing properties of coal blends  

SciTech Connect (OSTI)

The fusion properties of sulfur materials present in coals were investigated. The treatment of the samples of eleven different coals is described. Thermal treatment of low temperature ashing (LTA) concentrates of eight of the coals was performed, and raw and wash ashing curves were examined to determine what quantitative correlations, if any, exist between ashing parameters and rank of coal. The actual form of the function which describes the ashing curve is derived.

Biggs, D.L.

1982-03-01T23:59:59.000Z

92

Utilization FLY ASH INFORMATION FROM  

E-Print Network [OSTI]

, quarries, and pits (34%), 6% for temporary stockpile, and 7% landfilled. Fly Ash In Europe, the utilization

Wisconsin-Milwaukee, University of

93

Evaluation of cement production using a pressurized fluidized-bed combustor  

SciTech Connect (OSTI)

There are several primary conclusions which can be reached and used to define research required in establishing the feasibility of using PFBC-derived materials as cement feedstock. 1. With appropriate blending almost any material containing the required cement-making materials can be utilized to manufacture cement. However, extensive blending with multiple materials or the use of ash in relatively small quantities would compromise the worth of this concept. 2. The composition of a potential feedstock must be considered not only with respect to the presence of required materials, but just as significantly, with respect to the presence and concentration of known deleterious materials. 3. The processing costs for rendering the feedstock into an acceptable composition and the energy costs associated with both processing and burning must be considered. It should be noted that the cost of energy to produce cement, expressed as a percentage of the price of the product is higher than for any other major industrial product. Energy consumption is, therefore, a major issue. 4. The need for conformance to environmental regulations has a profound effect on the cement industry since waste materials can neither be discharged to the atmosphere or be shipped to a landfill. 5. Fifth, the need for achieving uniformity in the composition of the cement is critical to controlling its quality. Unfortunately, certain materials in very small concentrations have the capability to affect the rate and extent to which the cementitious compound in portland cement are able to form. Particularly critical are variations in the ash, the sulfur content of the coal or the amount and composition of the stack dust returned to the kiln.

DeLallo, M.; Eshbach, R.

1994-01-01T23:59:59.000Z

94

E-Print Network 3.0 - ash bottom ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: of bottom ash, 3 million tons of boiler slag, and 28 million tons of clean-coal ash materials) were produced... CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By...

95

Modeling volcanic ash dispersal  

ScienceCinema (OSTI)

Explosive volcanic eruptions inject into the atmosphere large amounts of volcanic material (ash, blocks and lapilli). Blocks and larger lapilli follow ballistic and non-ballistic trajectories and fall rapidly close to the volcano. In contrast, very fine ashes can remain entrapped in the atmosphere for months to years, and may affect the global climate in the case of large eruptions. Particles having sizes between these two end-members remain airborne from hours to days and can cover wide areas downwind. Such volcanic fallout entails a serious threat to aircraft safety and can create many undesirable effects to the communities located around the volcano. The assessment of volcanic fallout hazard is an important scientific, economic, and political issue, especially in densely populated areas. From a scientific point of view, considerable progress has been made during the last two decades through the use of increasingly powerful computational models and capabilities. Nowadays, models are used to quantify hazard scenarios and/or to give short-term forecasts during emergency situations. This talk will be focused on the main aspects related to modeling volcanic ash dispersal and fallout with application to the well known problem created by the Eyjafjöll volcano in Iceland. Moreover, a short description of the main volcanic monitoring techniques is presented.

None

2011-10-06T23:59:59.000Z

96

Ash deposit workshop: Class outline  

SciTech Connect (OSTI)

Ash deposits formed from the combustion of coal and other fuels have plagued the steam production industry from the start. The ash fusion test has been around for over eighty years. As steam plant size increased, so have the problems associated with ash deposits. This workshop is designed to cover: (1) The basic types of deposits. (2) Causes of deposits. (3) Analytical procedures for resolving, or at least providing information about deposits and fuels, and (4) Deposit removal and reduction techniques.

Hatt, R. [Commercial Testing & Engineering Co., Lexington, KY (United States)

1996-12-31T23:59:59.000Z

97

Permeability of consolidated incinerator facility wastes stabilized with portland cement  

SciTech Connect (OSTI)

The Consolidated Incinerator Facility (CIF) at the Savannah River Site (SRS) burns low-level radioactive wastes and mixed wastes as a method of treatment and volume reduction. The CIF generates secondary waste, which consists of ash and offgas scrubber solution. Currently the ash is stabilized/solidified in the Ashcrete process. The scrubber solution (blowdown) is sent to the SRS Effluent Treatment Facility (ETF) for treatment as wastewater. In the past, the scrubber solution was also stabilized/solidified in the Ashcrete process as blowcrete, and will continue to be treated this way for listed waste burns and scrubber solutions that do not meet the ETF Waste Acceptance Criteria (WAC). The disposal plan for Ashcrete and special case blowcrete is to bury these containerized waste forms in shallow unlined trenches in E-Area. The WAC for intimately mixed, cement-based wasteforms intended for direct disposal specifies limits on compressive strength and permeability. Simulated waste and actual CIF ash and scrubber solution were mixed in the laboratory and cast into wasteforms for testing. Test results and related waste disposal consequences are given in this report.

Walker, B.W.

2000-04-19T23:59:59.000Z

98

The lime-soda sinter process for resource recovery from fly ash: A new look  

SciTech Connect (OSTI)

The lime-soda sinter process is one of the earliest and most thoroughly researched and evaluated of the several methods available for resource recovery from fly ash. The principle product, metallurgical grade alumina, is obtained with yields as high as 90% depending upon how much alumina needs to be left in the residue to form acceptable byproduct cement clinker. The process has the advantages of requiring a relatively low sintering temperature (1100-1200{degree}C), using conventional equipment of carbon steel construction, utilizing a variety of calcium and mineralizer raw materials, and producing only a single byproduct consisting of dicalcium silicate that has been shown to be an attractive raw material for the manufacture of portland cement. An economic feasibility study for a combined facility to produce alumina and cement from the fly ash generated by a 1000 MWe coal-fired power station shows a 10.5% return on average investment. This is increased to 14.2% when a disposal charge of $10/ton of fly ash consumed is credited to the process. Research has shown that the soda ash can be replaced by coal cleaning refuse or that the soda ash and one-fourth of the limestone can be replaced by FGD sludge with a savings in raw material cost in both cases. The return on average investment becomes 14.5% when the refuse is used and 15.2% when the sludge is used. The return could be increased further if an inexpensive fluxing agent were substituted for the alumina deliberately left in the residue. 12 refs., 2 figs., 7 tabs.

Burnet, G.

1991-01-01T23:59:59.000Z

99

Ash Chemistry in MSW Incineration Plants  

E-Print Network [OSTI]

Ash Chemistry in MSW Incineration Plants: Advanced Characterization and Thermodynamic to analyze MSW-derived ashes by use of CCSEM. Representative samples of 2nd -3rd pass and ESP/E-filter ashes

100

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

and a vertical shaft kiln at another cement manufacturingrotary kiln or vertical shaft kiln in a cement plant. Baseda vertical shaft kiln (VSK) at another cement manufacturing

Price, Lynn

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry  

E-Print Network [OSTI]

the small cement plants, earthen vertical kiln (and hollowcement plant in North China utilizing vertical shaft kilnsCement Industry Technical Conference: 75- Replacing Vertical Shaft Kilns

Galitsky, Christina

2009-01-01T23:59:59.000Z

102

Industrial properties of lignitic and lignocellulosic fly ashes from Turkish sources  

SciTech Connect (OSTI)

Fly ash is an inorganic matter from combustion of the carbonaceous solid fuels. More than half the electricity in Turkey is produced from lignite-fired power plants. This energy production has resulted in the formation of more than 13 million tons of fly ash waste annually. The presence of carbon in fly ash inducing common faults include adding unwanted black color and adsorbing process or product materials such as water and chemicals. One of the reasons for not using fly ash directly is its carbon content. For some uses carbon must be lower than 3%. Fly ash has been used for partial replacement of cement, aggregate, or both for nearly 70 years, and it is still used on a very limited scale in Turkey. The heavy metal content of industrial wastewaters is an important source of environmental pollution. Each of the three major oxides (SiO{sub 2} + Al{sub 2}O{sub 3} + Fe{sub 2}O{sub 3}) in fly ash can be ideal as a metal adsorbent.

Demirbas, A.; Cetin, S. [Selcuk University, Konya (Turkey)

2006-01-21T23:59:59.000Z

103

Unique method of ash disposal can benefit marine life  

SciTech Connect (OSTI)

As more communities turn to waste-to-energy facilities to help solve their solid waste disposal problems, the amount of ash created by these facilities increases. Incineration of solid waste produces particulate residues which are often rich in lead, cadmium, copper, and zinc because of the concentration which occurs as a result of reduction. It has been shown that such metals can sometimes be leached from ash residues, giving rise to special concerns that incineration ashes be disposed of in an environmentally acceptable manner. In urban coastal areas where landfills are few and increasingly distant, ocean disposal of stabilized incineration residues (SIR) may provide an acceptable alternative to current landfill practices. In May 1985, a research program was initiated at the Marine Sciences Research Center to examine the feasibility of utilizing SIR for artificial reef construction in the ocean. Results of these studies showed that particulate incineration residues could be combined with cement to form a solid block possessing physical properties necessary for ocean disposal. The stabilized residues were subjected to regulatory extraction protocols, and in no instance did the metal concentrations in the leachates exceed the regulatory limits for toxicity. Bioassays revealed no adverse effects on the phytoplankton communities exposed to elutriate concentrations higher than could be encountered under normal disposal conditions. The success of the laboratory studies resulted in securing the necessary permits for the placement of an artificial habitat constructed using SIR in coastal wasters. Results from this program are described.

Roethel, F.J.; Breslin, V.T. (State Univ. of New York, Stony Brook (USA))

1988-10-01T23:59:59.000Z

104

Cement advanced furnace and process  

SciTech Connect (OSTI)

This patent describes a suspension shaft furnace for producing discrete cement clinkers from discrete pellets of cement-forming batch materials which are gravity-migrated therethrough. It comprises a vertical furnace housing enclosing a top pellet-feeding and preheating zone comprising an elongate vertical shaft section opening into an intermediate fluidized bed section comprising fuel inlet conduits, an air-permeable clinker-impermeable support; a lower clinker-cooling section beneath the fluidized bed section; clinker-discharge means communicating between the fluidized bed section and the cooling section and air inlet means.

Litka, A.F.; Cohen, S.M.

1992-06-02T23:59:59.000Z

105

ADVANCED CEMENTS FOR GEOTHERMAL WELLS  

SciTech Connect (OSTI)

Using the conventional well cements consisting of the calcium silicate hydrates (CaO-SiO{sub 2}-H{sub 2}O system) and calcium aluminum silicate hydrates (CaO-Al{sub 2}O{sub 3}-SiO{sub 2}-H{sub 2}O system) for the integrity of geothermal wells, the serious concern confronting the cementing industries was their poor performance in mechanically supporting the metallic well casing pipes and in mitigating the pipe's corrosion in very harsh geothermal reservoirs. These difficulties are particularly acute in two geological regions: One is the deep hot downhole area ({approx} 1700 m depth at temperatures of {approx} 320 C) that contains hyper saline water with high concentrations of CO{sub 2} (> 40,000 ppm) in conjunction with {approx} 100 ppm H{sub 2}S at a mild acid of pH {approx} 5.0; the other is the upper well region between the well's surface and {approx} 1000 m depth at temperatures up to 200 C. The specific environment of the latter region is characterized by highly concentrated H{sub 2}SO{sub 4} (pH < 1.5) brine containing at least 5000 ppm CO{sub 2}. When these conventional cements are emplaced in these harsh environments, their major shortcoming is their susceptibility to reactions with hot CO{sub 2} and H{sub 2}SO4, thereby causing their deterioration brought about by CO{sub 2}-catalyzed carbonation and acid-initiated erosion. Such degradation not only reduced rapidly the strength of cements, lowering the mechanical support of casing pipes, but also increased the extent of permeability of the brine through the cement layer, promoting the rate of the pipe's corrosion. Severely carbonated and acid eroded cements often impaired the integrity of a well in less than one year; in the worst cases, casings have collapsed within three months, leading to the need for costly and time-consuming repairs or redrilling operations. These were the reasons why the geothermal well drilling and cementing industries were concerned about using conventional well cements, and further their deterioration was a major impediment in expediting the development of geothermal energy resources.

SUGAMA,T.

2007-01-01T23:59:59.000Z

106

Cast-Concrete Products Made with FBC Ash and Wet-Collected Coal-Ash  

E-Print Network [OSTI]

. DOI: 10.1061/ ASCE 0899-1561 2005 17:6 659 CE Database subject headings: Recycling; Ashes; Concrete et al. 1991 . Fluidized bed combustion FBC ash is the ash produced by an FBC boiler in which the coal

Wisconsin-Milwaukee, University of

107

Cement design key to subsalt success  

SciTech Connect (OSTI)

Failures in casing set across salt formations have cost the petroleum industry billions of dollars. One of the most effective weapons for halting casing damage in salt formations is a competent cement sheath across the whole salt zone formation. Good cement jobs are at least as important as casing design. Choice of cementing recipe and practice can ensure a lasting cementation and is a function of the formation, its inclusions and its boundaries. The paper discusses the gauge hole, salt creep, and well casing and cementing.

NONE

1996-07-01T23:59:59.000Z

108

High temperature synthetic cement retarder  

SciTech Connect (OSTI)

A synthetic cement retarder which provides excellent retardation and compressive strength development has been synthesized. The response properties and temperature ranges of the synthetic retarder far exceed those of commonly used retarders such as lignosulfonates. The chemical nature of the new retarder is discussed and compared to another synthetic retarder.

Eoff, L.S.; Buster, D.

1995-11-01T23:59:59.000Z

109

Process for cementing geothermal wells  

DOE Patents [OSTI]

A pumpable slurry of coal-filled furfuryl alcohol, furfural, and/or a low molecular weight mono- or copolymer thereof containing, preferably, a catalytic amount of a soluble acid catalyst is used to cement a casing in a geothermal well.

Eilers, Louis H. (Inola, OK)

1985-01-01T23:59:59.000Z

110

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during soot blowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon. 8 figs.

Hurley, J.P.; McCollor, D.P.; Selle, S.J.

1994-07-26T23:59:59.000Z

111

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

1994-01-01T23:59:59.000Z

112

2008 ACEEE Summer Study on Energy Efficiency in Buildings August 1722, 2008 Asilomar Conference Center Pacific Grove, California  

E-Print Network [OSTI]

2008 ACEEE Summer Study on Energy Efficiency in Buildings August 17­22, 2008 · Asilomar Conference Center · Pacific Grove, California 1 Targeting Energy Efficiency in Commercial Buildings Using Advanced energy use, prioritizes buildings for specific energy-efficiency retrofits, and tracks weather

Kissock, Kelly

113

ash dispersion utilizing: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in the USA for all coal ashes was approximately 34% in the year products containing clean coal ash compared to conventional coal ash. Utilization of clean coal ash is much...

114

CONSTRUCTION-GRADE CEMENT PRODUCTION FROM CONTAMINATED SEDIMENTS USING  

E-Print Network [OSTI]

1 CONSTRUCTION-GRADE CEMENT PRODUCTION FROM CONTAMINATED SEDIMENTS USING CEMENT-LOCKTM TECHNOLOGY A manufacturing technology for producing construction-grade cements from a wide variety of contaminated waste cementitious properties that allow it to be transformed into construction-grade cement. The Cement

Brookhaven National Laboratory

115

HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE  

SciTech Connect (OSTI)

Low cost material is needed for grouting abandoned retorts. Experimental work has shown that a hydraulic cement can be produced from Lurgi spent shale by mixing it in a 1:1 weight ratio with limestone and heating one hour at 1000°C. With 5% added gypsum, strengths up to 25.8 MPa are obtained. This cement could make an economical addition up to about 10% to spent shale grout mixes, or be used in ordinary cement applications.

Mehta, P.K.; Persoff, P.; Fox, J.P.

1980-06-01T23:59:59.000Z

116

Advanced Characterisation of Municipal Solid Waste Ashes  

E-Print Network [OSTI]

Advanced Characterisation of Municipal Solid Waste Ashes Preparatory thesis Randi Skytte Pedersen is to investigate Municipal Solid Waste (MSW) ashes with respect to particle sizes, structures and composition with characterisation of Municipal Solid Waste (MSW) ashes from the Danish power plant M°abjergværket, Holstebro. MSW

117

INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE  

E-Print Network [OSTI]

CEMENTS FROM SPENT OIL SHALE P.K. Mehta and P. Persoff AprilCement Manufacture from Oil Shale, U.S. Patent 2,904,445,CEMENTS FROM SPENT OIL SHALE P, K, Mehta Civil Engineering

Mehta, P.K.

2012-01-01T23:59:59.000Z

118

Concentration of carbon types from fly ash by density gradient centrifugation  

SciTech Connect (OSTI)

Although the increasing amount of unburned carbon in fly ash is known to preclude the use of ash in the cement industry, very little is known about the characteristics of the unburned carbon. Three types of carbon particles have been identified microscopically: inertinite, isotropic coke and anisotropic coke. This manuscript describes a method to isolate these three types of carbon. A preliminary enrichment, followed by density gradient centrifugation (DGC) with a high-density polytungstate media (2.85 g/cm{sup 3} max), resulted in an enrichment of inertinites from a starting concentration of 3.8% to 61%, isotropic coke from 13.4% to 65%, and anisotropic coke from 19.2% to 74%. Large scale runs (LS) have been conducted to accumulate sufficient sample for subsequent analyses. The recovery weights and petrography composition of the PS and LS fractions are very similar.

Maroto-Valer, M.M.; Taulbee, D.N.; Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

1998-12-31T23:59:59.000Z

119

The art of cross-writing in Grove Hall : two centuries of form and place-making in a Boston neighborhood  

E-Print Network [OSTI]

The Boston neighborhood of Grove Hall is presently engaged in a period of urban revival. New civic, commercial and residential projects are starting to fill in empty lots and rejuvenate historic yet dilapidated structures. ...

Rosenzweig, Gilad J

2013-01-01T23:59:59.000Z

120

Proceedings of the 2004 ACEEE Summer Study on Energy Efficiency in Buildings. August 22 -27, 2004 Asilomar Conference Center Pacific Grove, California.  

E-Print Network [OSTI]

Proceedings of the 2004 ACEEE Summer Study on Energy Efficiency in Buildings. August 22 - 27, 2004 · Asilomar Conference Center · Pacific Grove, California. Developing a Next-Generation Community College

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Relationship Between Engineering Properties, Mineralogy, and Microstructure in Cement-Based Hydroceramic Materials Cured at  

E-Print Network [OSTI]

. I. Introduction CEMENT is universally used in the construction of oil and geothermal wells. Cement

Bentz, Dale P.

122

Petrographic characterization of economizer fly ash  

SciTech Connect (OSTI)

Policies for reducing NOx emissions have led power plants to restrict O{sub 2}, resulting in high-carbon fly ash production. Therefore, some potentially useful fly ash, such as the economizer fly ash, is discarded without a thorough knowledge of its composition. In order to characterize this type of fly ash, samples were collected from the economizer Portuguese power plant burning two low-sulfur bituminous coals. Characterization was also performed on economizer fly ash subsamples after wet sieving, density and magnetic separation. Analysis included atomic absorption spectroscopy, loss-on-ignition, scanning electron microscopy/energy-dispersive X-ray spectroscopy, optical microscopy, and micro-Raman spectroscopy.

Valentim, B.; Hower, J.C.; Soares, S.; Guedes, A.; Garcia, C.; Flores, D.; Oliveira, A. [University of Porto, Oporto (Portugal). Center of Geology

2009-11-15T23:59:59.000Z

123

asbestos cement workers: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

early stage hydration of different classes of oilwell cement Bentz, Dale P. 152 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

124

asbestos cement dust: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

early stage hydration of different classes of oilwell cement Bentz, Dale P. 278 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

125

african portland cement: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

present in hardened cement blends in the long term Sheffield, University of 337 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

126

Multifunctional Corrosion-resistant Foamed Well Cement Composites...  

Broader source: Energy.gov (indexed) [DOE]

Multifunctional Corrosion-resistant Foamed Well Cement Composites Multifunctional Corrosion-resistant Foamed Well Cement Composites Multifunctional Corrosion-resistant Foamed Well...

127

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

flash distillation waste heat power generation demonstrationAdvanced Concepts of Waste Heat Recovery in Cement PlantsCement Ltd. also installed waste heat recovery equipment on

Worrell, Ernst

2008-01-01T23:59:59.000Z

128

Fracture model for cemented aggregates  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

A mechanisms-based fracture model applicable to a broad class of cemented aggregates and, among them, plastic-bonded explosive (PBX) composites, is presented. The model is calibrated for PBX 9502 using the available experimental data under uniaxial compression and tension gathered at various strain rates and temperatures. We show that the model correctly captures inelastic stress-strain responses prior to the load peak and it predicts the post-critical macro-fracture processes, which result from the growth and coalescence of micro-cracks. In our approach, the fracture zone is embedded into elastic matrix and effectively weakens the material's strength along the plane of the dominant fracture.

Zubelewicz, Aleksander; Thompson, Darla G.; Ostoja-Starzewski, Martin; Ionita, Axinte; Shunk, Devin; Lewis, Matthew W.; Lawson, Joe C.; Kale, Sohan; Koric, Seid

2013-01-01T23:59:59.000Z

129

Ultrasonic ash/pyrite liberation  

SciTech Connect (OSTI)

The objective of this project was to develop a coal preparation concept which employed ultrasonics to precondition coal prior to conventional or advanced physical beneficiation processes such that ash and pyrite separation were enhanced with improved combustible recovery. Research activities involved a series of experiments that subjected three different test coals, Illinois No. 6, Pittsburgh No. 8, and Upper Freeport, ground to three different size fractions (28 mesh [times] 0, 200 mesh [times] 0, and 325 mesh [times] 0), to a fixed (20 kHz) frequency ultrasonic signal prior to processing by conventional and microbubble flotation. The samples were also processed by conventional and microbubble flotation without ultrasonic pretreatment to establish baseline conditions. Product ash, sulfur and combustible recovery data were determined for both beneficiation processes.

Yungman, B.A.; Buban, K.S.; Stotts, W.F.

1990-06-01T23:59:59.000Z

130

Phosphate-bonded calcium aluminate cements  

DOE Patents [OSTI]

A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120 C to about 300 C to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate. 10 figures.

Sugama, T.

1993-09-21T23:59:59.000Z

131

Combustion with reduced carbon in the ash  

DOE Patents [OSTI]

Combustion of coal in which oxygen is injected into the coal as it emerges from burner produces ash having reduced amounts of carbon.

Kobayashi, Hisashi; Bool III, Lawrence E.

2005-12-27T23:59:59.000Z

132

Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry  

E-Print Network [OSTI]

Advanced Concepts of Waste Heat Recovery in Cement Plantsquantities of low grade waste heat from the kilns or clinkerthere is significant effect of waste heat recovery on dioxin

Galitsky, Christina

2009-01-01T23:59:59.000Z

133

The use of electrical impedance spectroscopy for monitoring the hydration products of Portland cement mortars with high percentage of pozzolans  

SciTech Connect (OSTI)

In this paper, mortars and pastes containing large replacement of pozzolan were studied by mechanical strength, thermogravimetric analysis (TGA), scanning electronic microscopy (SEM), mercury intrusion porosimetry (MIP) and electrical impedance spectroscopy (EIS). The effect of metakaolin (35%) and fly ash (60%) was evaluated and compared with an inert mineral addition (andalusite). The portlandite content was measured, finding that the pozzolanic reaction produced cementing systems with all portlandite fixed. The EIS measurements were analyzed by the equivalent electrical circuit (EEC) method. An EEC with three branches in parallel was applied. The dc resistance was related to the degree of hydration and allowed us to characterize plain and blended mortars. A constant phase element (CPE) quantified the electrical properties of the hydration products located in the solid–solution interface and was useful to distinguish the role of inert and pozzolanic admixtures present in the cement matrix.

Cruz, J.M. [Departamento de Física Aplicada, Universitat Politècnica de València, Camino de Vera, 46022, Valencia (Spain)] [Departamento de Física Aplicada, Universitat Politècnica de València, Camino de Vera, 46022, Valencia (Spain); Fita, I.C., E-mail: infifer@fis.upv.es [Departamento de Física Aplicada, Universitat Politècnica de València, Camino de Vera, 46022, Valencia (Spain); Soriano, L.; Payá, J.; Borrachero, M.V. [ICITECH, Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València (Spain)] [ICITECH, Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València (Spain)

2013-08-15T23:59:59.000Z

134

Treatment of fly ash for use in concrete  

DOE Patents [OSTI]

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT)

2012-05-15T23:59:59.000Z

135

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

obsolete vertical shaft kiln (VSK) cement plants, with theobsolete vertical shaft kiln (VSK) cement plants, with theobsolete vertical shaft kiln (VSK) cement plants, with the

Price, Lynn

2010-01-01T23:59:59.000Z

136

Mechanical and Thermal Properties of Fly Ash-based Geopolymer Cement.  

E-Print Network [OSTI]

??The geopolymer concrete is a more durable and green material with less CO2 emission and less energy consuming as compared with the widely used Portland… (more)

Fan, Fenghong

2015-01-01T23:59:59.000Z

137

Supply chain management in the cement industry  

E-Print Network [OSTI]

Traditionally supply chain management has played an operational role within cement and mineral extraction commodity companies. Recently, cost reduction projects have brought supply chain management into the limelight. In ...

Agudelo, Isabel

2009-01-01T23:59:59.000Z

138

A nanochemomechanical investigation of carbonated cement paste  

E-Print Network [OSTI]

Concrete, and in particular its principal component, cement paste, has an interesting relation with carbon dioxide. Concrete is a carbon dioxide generator-- it is estimated that 5-10% of atmospheric CO? comes from this ...

Vanzo, James (James F.)

2009-01-01T23:59:59.000Z

139

HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE  

E-Print Network [OSTI]

cement from spent oil shale," Vol. 10, No. 4, p. 54S,Colorado's primary oil shale resource for vertical modifiedSimulated effects of oil-shale development on the hydrology

Mehta, P.K.

2013-01-01T23:59:59.000Z

140

HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE  

E-Print Network [OSTI]

hydraulic cement from spent oil shale," Vol. 10, No. 4, p.J. W. , "Colorado's primary oil shale resource for verticalSimulated effects of oil-shale development on the hydrology

Mehta, P.K.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Wearability of Portland Cement Concrete Pavement Finishes  

E-Print Network [OSTI]

Major Subject: Civil Engineering NEARABILITY OF PORTLAND CENENT CONCRETE PAPFNENT FIVISNFS A Thesis by Nilliam Rem NcKeen Approved as to style and content by: (Chairman of Committ e) (Nember) August 1971 ABSTRACT Hearabil'tv of Portland Cement... portland cement, and an air entrainment admixture. Standard laboratory tests were performed on all aggregates to determine their properties. iv The test specimens were molded in a controlled environmental room and the anpropriate surface finish (burlap...

McKeen, William Rew

1971-01-01T23:59:59.000Z

142

Impact of Biodiesel on Ash Emissions and Lubricant Properties...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and...

143

Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreat...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter Minimizing Lubricant-Ash Requirement and Impact on Emission...

144

Development of an Accelerated Ash-Loading Protocol for Diesel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Poster presentation at the 2007...

145

The Development of a Small Engine Based Accelerated Ash Loading...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Accelerated Ash Loading Protocol The Development of a Small Engine Based Accelerated Ash Loading Protocol Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan....

146

Uncovering Fundamental Ash-Formation Mechanisms and Potential...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash properties deer12kamp.pdf More Documents...

147

Ash-Based Building Panels Production and Demonstration of Aerock Decking Building Product  

SciTech Connect (OSTI)

Western Research Institute (WRI) of Laramie, Wyoming and AeRock, LLC of Eagar, Arizona (formerly of Bellevue, Washington) partnered, under sponsorship of the U.S. Department of Energy National Energy Technology Laboratory (U.S. DOE-NETL), to support the development of rapid-setting, ash-based, fiber-incorporated ''green'' building products. Green building materials are a rapidly growing trend in the building and construction industry in the US. A two phase project was implemented wherein Phase I assessed, through chemical and physical testing, ash, ash-based cement and fiber composites exhibiting superior structural performance when applied to the AeRock mixing and extrusion process and involved the conduct of pilot-scale production trials of AeRock products, and wherein Phase II involved the design, construction, and operation of a commercial-scale plant to confirm production issues and to produce panels for performance evaluations. Phase I optimized the composite ingredients including ash-based cement, Class F and Class C DFGD ash, and various fiber reinforcements. Additives, such as retardants and accelerators, were also evaluated as related to extruder performance. The optimized composite from the Phase I effort was characterized by a modulus of rupture (MOR) measured between 1,931 and 2,221 psi flexural strength, comparable to other wood and non-wood building materials. Continuous extrusion of the optimum composite in the AeRock pilot-scale facility produced an excellent product that was assembled into a demonstration for exhibit and durability purposes. Finishes, from plain to marbled, from bright reds to muted earth tones and with various textures, could easily be applied during the mixing and extrusion process. The successful pilot-scale demonstration was in turn used to design the production parameters and extruder dies for a commercial scale demonstration at Ultrapanel Pty, Ltd of Ballarat, Australia under Phase II. The initial commercial-scale production trials showed green product sagging, as a result of the die design. After the third die was acquired and fitted to the extruder, satisfactory decking and structural panels were produced. Cured decking was shipped to the US but experienced significant breakage and damage during transport. Subsequent evaluations concluded that an alternative die design was needed that would produce a more robust product resistant to damage. In summary, AeRock Decking can be a commercially-viable non-wood alternative decking product. This project has provided WRI and AeRock the knowledge and understanding to make AeRock Decking a commercial success. However, a commercial demonstration that produces quality product and the subsequent evaluation of its performance is needed before commercial acceptance of the AeRock product.

Alan E. Bland; Jesse Newcomer

2007-06-30T23:59:59.000Z

148

Fly Ash Amendments Catalyze Soil Carbon Sequestration  

SciTech Connect (OSTI)

We tested the effects of four alkaline fly ashes {Class C (sub-bituminous), Class F (bituminous), Class F [bituminous with flue-gas desulfurization (FGD) products], and Class F (lignitic)} on a reaction that simulates the enzyme-mediated formation of humic materials in soils. The presence of FGD products completely halted the reaction, and the bituminous ash showed no benefit over an ash-free control. The sub-bituminous and lignitic fly ashes, however, increased the amount of polymer formed by several-fold. The strong synergetic effect of these ashes when enzyme is present apparently arises from the combined effects of metal oxide co-oxidation (Fe and Mn oxides), alkaline pH, and physical stabilization of the enzyme (porous silica cenospheres).

Amonette, James E.; Kim, Jungbae; Russell, Colleen K.; Palumbo, A. V.; Daniels, William L.

2003-09-15T23:59:59.000Z

149

Treatment of fly ash for use in concrete  

SciTech Connect (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett; Akash, Akash; Zhao, Qiang

2013-01-08T23:59:59.000Z

150

Treatment of fly ash for use in concrete  

DOE Patents [OSTI]

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett (Park City, UT); Akash, Akash (Salt lake City, UT); Zhao, Qiang (Natick, MA)

2012-05-08T23:59:59.000Z

151

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect (OSTI)

Work completed in this reporting period focused primarily on continuing measurements of the rate of ammonia loss from concrete, and the measurement of ammonia gas in the air above concrete and flowable fill immediately after placement. Concrete slabs were prepared to monitor the loss of ammonia during mixing, the concentration in the airspace above the slabs soon after placement, and the total quantity of ammonia evolved over a longer time period. Variables tested include temperature, ventilation rate, water:cementitious (W:C) ratio, and fly ash source. Short-term data indicate that for concrete placed in areas with poor air ventilation the fly ash NH{sub 3} concentration should not exceed about 90 to 145 mg/kg ash, depending on the water:cement ratio and the fly ash replacement rate, if a concentration of 10 ppm NH{sub 3} in the air is assumed to be the maximum acceptable level. Longer-term experiments showed that the ammonia loss rate is dependent on ammonia source (that is ammoniated ash vs. non-ammoniated ash with ammonia added to the water), and is also dependent on W:C ratio and temperature. Experiments were also conducted to study the loss of ammonia from fresh concrete during mixing. It was found that a high water:cementitious mix lost a greater percentage of ammonia than a low W:C mix, with a medium W:C mix losing an amount intermediate between these two. However, a larger batch size resulted in a smaller percentage of ammonia lost. The data suggest that a significant quantity of ammonia could be lost from Ready Mix concrete during transit, depending on the transit time, batch size, and mix proportions.

Robert F. Rathbone; Thomas L. Robl

2002-04-11T23:59:59.000Z

152

SENSITIVITY OF THE BOND STRENGTH TO THE STRUCTURE OF THE INTERFACE BETWEEN REINFORCEMENT AND CEMENT, AND THE  

E-Print Network [OSTI]

Ashland Petroleum Co. (Ashland, KY). Cement paste made from Portland cement (Type I) from Lafarge Corp

Chung, Deborah D.L.

153

Fe-containing phases in hydrated cements  

SciTech Connect (OSTI)

In this study synchrotron X-ray absorption spectroscopy (XAS) has been applied, an element specific technique which allows Fe-containing phases to be identified in the complex mineral mixture of hydrated cements. Several Fe species contributed to the overall Fe K-edge spectra recorded on the cement samples. In the early stage of cement hydration ferrite was the dominant Fe-containing mineral. Ferrihydrite was detected during the first hours of the hydration process. After 1 day the formation of Al- and Fe-siliceous hydrogarnet was observed, while the amount of ferrihydrite decreased. The latter finding agrees with thermodynamic modeling, which predicts the formation of Fe-siliceous hydrogarnet in Portland cement systems. The presence of Al- and Fe-containing siliceous hydrogarnet was further substantiated in the residue of hydrated cement by performing a selective dissolution procedure. - Highlights: • Fe bound to ferrihydrite at early age hydration • Fe found to be stable in siliceous hydrogarnet at longer term age hydration • Fe-containing AFt and AFm phases are less stable than siliceous hydrogarnet. • The study demonstrates EXAFS used to identify amorphous or poorly crystalline phases.

Dilnesa, B.Z., E-mail: belay.dilnesa@gmail.com [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Wieland, E. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Lothenbach, B. [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Dähn, R. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Scrivener, K.L. [Ecole Polytechnique Federal de Lausanne (EPFL), Laboratory for Construction Materials, 1015 Lausanne (Switzerland)

2014-04-01T23:59:59.000Z

154

INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE  

E-Print Network [OSTI]

20 to 40% of the oil shale, and explosively rubblizing andCEMENTS FROM SPENT OIL SHALE P.K. Mehta and P. Persoff AprilCement Manufacture from Oil Shale, U.S. Patent 2,904,445,

Mehta, P.K.

2012-01-01T23:59:59.000Z

155

Identification of Concrete Incompatibilities Using Cement Paste Rheology  

E-Print Network [OSTI]

as well as heat evolution abnormalities. The objectives of the present study were to examine the applicability of the dynamic shear rheometer (DSR) to measure cement paste rheology, and to identify cement and mineral/chemical admixture incompatibilities...

Jang, Se Hoon

2010-07-14T23:59:59.000Z

156

Development of an Improved Cement for Geothermal Wells  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Develop a novel, zeolite-containing lightweight, high temperature, high pressure geothermal cement, which will provide operators with an easy to use, flexible cementing system that saves time and simplifies logistics.

157

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

and energy savings per tonne of cement produced are estimated and then carbon dioxide emissionsand energy savings per tonne of cement produced are estimated and then carbon dioxide emissions

Worrell, Ernst

2008-01-01T23:59:59.000Z

158

Fluidized bed gasification ash reduction and removal process  

DOE Patents [OSTI]

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-12-04T23:59:59.000Z

159

Fluidized bed gasification ash reduction and removal system  

DOE Patents [OSTI]

In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

1984-02-28T23:59:59.000Z

160

Master Thesis: Simulation of plastic deformation in cemented carbide inserts  

E-Print Network [OSTI]

Master Thesis: Simulation of plastic deformation in cemented carbide inserts Background Sandvik in cemented carbide, high-speed steel and other hard materials such as diamond, cubic boron nitride in cemented carbide inserts will be performed using the FEM software Ansys and AdvantEdge. The work

Haviland, David

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Successful Alternatives to Conventional Cement Designs in the Williston Basin  

SciTech Connect (OSTI)

Since mid-1981, 36 wells have been cemented in the Williston Basin with a cementing system diametrically opposed to conventional cementing designs used for bonding across massive salt members. Since implementation, along with the use of relaxed invert emulsion oil mud, not one casing problem has arisen in the wells where these systems were used.

Bryant, G.A.

1984-05-01T23:59:59.000Z

162

NIST Special Publication 1173 Virtual Cement and Concrete  

E-Print Network [OSTI]

#12;NIST Special Publication 1173 Virtual Cement and Concrete Testing Laboratory Version 9.5 User;Virtual Cement and Concrete Testing Laboratory Version 9.5 User Guide Jeffrey W. Bullard1 Materials-8615 This document serves as the user's guide for the Virtual Cement and Con- crete Testing Laboratory (VCCTL

163

Fly ash enhanced metal removal process  

SciTech Connect (OSTI)

The primary objective of the study was to evaluate the effectiveness of fly ashes from local thermal power plants in the removal of cadmium, nickel, chromium, lead, and copper from aqueous waste streams. Physical and chemical characteristics of fly ashes were determined, batch isotherm studies were conducted. A practical application of using fly ash in treating spent electroless nickel (EN) plating baths by modified conventional precipitation or solid enhanced metal removal process (SEMR) was investigated. In addition to nickel the EN baths also contains completing agents such as ammonium citrate and succinic acid reducing agents such as phosphate and hypophosphite. SEMR experiments were conducted at different pHs, fly ash type and concentrations, and settling times.

Nonavinakere, S. [Plexus Scientific Corp., Annapolis, MD (United States); Reed, B.E. [West Virginia Univ., Morgantown, WV (United States). Dept. of Civil Engineering

1995-12-31T23:59:59.000Z

164

Fly ash system technology improves opacity  

SciTech Connect (OSTI)

Unit 3 of the Dave Johnston Power Plant east of Glenrock, WY, USA had problems staying at or below the opacity limits set by the state. The unit makes use of a Lodge Cottrell precipitator. When the plant changed to burning Power River Basin coal, ash buildup became a significant issue as the fly ash control system was unable to properly evacuate hoppers on the unit. To overcome the problem, the PLC on the unit was replaced with a software optimization package called SmartAsh for the precipitator fly ash control system, at a cost of $500,000. After the upgrade, there have been no plugged hoppers and the opacity has been reduced from around 20% to 3-5%. 2 figs.

NONE

2007-06-15T23:59:59.000Z

165

Flue gas desulfurization gypsum and fly ash  

SciTech Connect (OSTI)

The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

Not Available

1992-05-01T23:59:59.000Z

166

Hydrothermal reactions of fly ash. Final report  

SciTech Connect (OSTI)

The emphasis of the work done has been to determine the reactivities of two ashes believed to be representative of those generated. A bituminous ash and a lignitic ash have been investigated. The reactions of these ashes undergo when subjected to mild hydrothermal conditions were explored. The nature of the reactions which the ashes undergo when alkaline activators, calcium hydroxide and calcium sulfate are present was also investigated. It was determined that calcium silicate hydrate, calcium aluminate hydrate, and the calcium sulfoaluminate hydrate ettringite form under these conditions. It appears 3CaO{center_dot}Al{sub 2}O{sub 3}{center_dot}3CaSO{sub 4}{center_dot}32H{sub 2}O (ettringite) formation needs to be considered in ashes which contain significant amounts of sulfate. Therefore the stability region for ettringite was established. It was also determined that calcium silicate hydrate, exhibiting a high internal surface area, will readily form with hydrothermal treatment between 50{degrees} and 100{degrees}C. This phase is likely to have a significant capacity to take up heavy metals and oxyanions and this ability is being explored.

Brown, P.W.

1995-12-31T23:59:59.000Z

167

E-Print Network 3.0 - ash technical progress Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and economic benefits. (1) Fly ash... of coal in conventional and or advanced clean coal technology combustors. These include fly ash, bottom... ash, boiler slag, and flue...

168

E-Print Network 3.0 - ash borer agrilus Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Sample search results for: ash borer agrilus Page: << < 1 2 3 4 5 > >> 1 Ecology and Movement of Emerald Ash Borer (Agrilus planipennis)Ash Borer (Agrilus...

169

Capture of green-house carbon dioxide in Portland cement  

SciTech Connect (OSTI)

A novel process has been developed to sequester green-house carbon dioxide produced by the cement industry in precast cement products. Typically, 10--24 wt % of CO{sub 2} produced by calcination of calcium carbonate during clinkering of the cement may be captured. The carbonation process also cures the cement paste within minutes into hard bodies. The process maintains high pH conditions during curing, to allow conventional steel reinforcement of concrete. The process will save time and money to the cement industry, and at the same time, help them to comply with the Clean Air Act by sequestering the green-house carbon dioxide.

Wagh, A.S.; Singh, D.; Pullockaran, J.; Knox, L.

1993-12-31T23:59:59.000Z

170

INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE  

SciTech Connect (OSTI)

A process for making hydraulic cements from spent oil shale is described in this paper. Inexpensive cement is needed to grout abandoned in-situ retorts of spent shale for subsidence control, mitigation of leaching, and strengthening the retorted mass in order to recover oil from adjacent pillars of raw shale. A hydraulic cement was produced by heating a 1:1 mixture of Lurgi spent shale and CaCO{sub 3} at 1000 C for one hour. This cement would be less expensive than ordinary portland cement and is expected to fulfill the above requirements.

Mehta, P.K.; Persoff, P.

1980-04-01T23:59:59.000Z

171

Thermal stability of certain hydrated phases in systems made using portland cement. Final report  

SciTech Connect (OSTI)

As part of the study of hydraulic-cement system for use in possible underground isolation of nuclear wastes, this study was made to determine the temperature stability of ettringite and chloroaluminate. Either or both of these phases may be expected in a hydraulic cement system depending on the presence of salt (NaCl). The study of ettringite was made using 15 mixtures that contained portland cement, plaster, 2 levels of water, and in some mixtures, 1 of 6 pozzolans (3 fly ashes, 1 slag, a silica fume, a natural pozzolan), plus a 16th mixture with anhydrous sodium sulfate replacing plaster (CaSO4 . 1/2H20). Specimens were made and stored at 23, 50, and 75 C or 23, 75, and 100 C (all four temperatures in one case) for periodic examination by x-ray diffraction for phase compositiion and ettringite stability, and testing for compressive strength and restrained expansion. A more limited study of the stability of chloroaluminate was made along the same lines using fewer mixtures, salt instead of plaster, and higher temperatures plus some pressure. It was found that while some ettringette was decomposed at 75 C, depending on the composition of the mixture, all ettringite was undetectable by x-ray diffraction at 100 C, usually within a few days. The evidence indicates that the ettringite became amorphous and no significant test phases formed in its place. Since there was no corresponding loss in strength or reduction in volume, this loss of ettringite crystallinity was considered to be damaging. Based on much more limited data, chloroaluminate was found to decompose between 130 C at 25 psi and 170 C at 100 psi; no significant phases replaced it.

Buck, A.D.; Burkes, J.P.; Poole, T.S.

1985-08-01T23:59:59.000Z

172

Effect of MgO Additive on Volumetric Expansion of Self-Degradable Cements  

SciTech Connect (OSTI)

We identified hard-burned magnesium oxide (MgO) as a suitable expansive additive for improving the plugging performance of self-degradable, temporary sodium silicate-activated slag/Class C fly ash (SSASC) blend cement sealers into rock fractures in Enhanced Geothermal Systems (EGSs). MgO extended the volumetric expansion of sealers during their exposure to a hydrothermal environment at 200 C under pressures, ranging from 300 to 1500 psi. A great expansion ratc of 19.3% was observed by adding 3.0 wt% MgO under 300 psi pressure, thus promising to plug thoroughly inner fracture. When the pressure was increased from 300 psi to 1500 psi, the expansion rate of cement markedly reduced, corresponding to the formaLion of crack-free specimens and the improvement of compressive strength. However, with 3.0 wt% MgO, the specimens still engendered the generation of numerous visual cracks, although they were prepared under a high pressure of 1500 psi. The effective content of MgO in minimizing and eliminating the generation of cracks was 2.0 wt%, which provided a moderate expansion of {ge} 0.5%. The compressive strength of 2.0 wt% MgO specimens made under a pressure of 300 psi rose {approx} 1.7-fold to 4816 psi with an increasing pressure to 1500 psi. The in-situ growth of brucite crystal formed by the hydrothermal hydration of MgO was responsive for such an expansion of the SSASC cement; meanwhile. two crystalline hydrothermal reaction products, 1.1 nm tobermorite and calcium silicate hydrated, contributed to the development of the sealer's compressive strength. Thus, the increasing pressure seems to suppress and control a growth rate of brucite crystal in response to a lower extension of expansion. Furthermore, all MgO-conlaining SSASC sealers possessed the water-catalyzed self-degradable properties.

Sugama T.; Warren, J.; Butcher, T.

2011-09-30T23:59:59.000Z

173

How to run and cement liners  

SciTech Connect (OSTI)

Testing the top of a liner after it has been cemented is necessary to ensure a well's integrity. However, whether done with or without packers there are potential problems attendant with either method that can occur if the tests are not properly engineered. A discussion of these problems and ways to avoid them is presented.

Bowman, G.R.; Sherer, B.

1988-09-01T23:59:59.000Z

174

Burning hazardous waste in cement kilns  

SciTech Connect (OSTI)

The cement manufacturing process is one of the oldest in the world, having been in practice for over 2000 years. It is also one of the most energy intensive, with up to 65 percent of the cost of the product attributable to energy consumption. In addition to high energy demand, the process conditions include extremely high temperatures. Cement clinker forms when the correct mixture of raw materials is heated to 2650/sup 0/ F. This requires combustion temperatures exceeding 3000/sup 0/ F. under oxidizing conditions. To accomplish this, gas temperatures above 2000/sup 0/ F. occur for several seconds (typically five seconds), which is much longer than residence times in permitted hazardous waste incinerators. These conditions are extremely favorable to the destruction of organic compounds and have led to extensive investigation into the potential for burning hazardous waste in cement kilns. Cement kilns consuming hazardous wastes have been tested for air emissions under various operating conditions. The substantial body of information on the emissions and handling of hazardous wastes from these studies has demonstrated that effective destruction of wastes can be accomplished with the added benefits of energy conservation and no significant change in air emissions.

Chadbourne, J.F.; Helmsteller, A.J.

1983-06-01T23:59:59.000Z

175

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect (OSTI)

Work completed in this reporting period focused on the measurement of the rate of ammonia loss from mortar and concrete, and the measurement of ammonia gas in the air above the materials immediately after placement. The majority of mortar experiments have been completed, and testing has begun on concrete. The mortar experiments indicate that the rate of ammonia loss is greater in mortars prepared using a higher water content and water:cement (W:C) ratio, although the higher rate is primarily observed within the first 2 days, after which the loss rates are nearly the same. The source of low-calcium (Class F) fly ash exerted a negligible influence on the loss rate. However, mortar prepared using a higher-calcium fly ash evolved ammonia at a slightly slower rate than the Class F ash mortars. The data also indicate that an increase in ventilation increases the ammonia loss rate from mortar, and suggest that a well-ventilated space could substantially increase the loss of ammonia from mortar and, by inference, a concrete slab. Analysis of ammonia concentrations in the air above freshly-placed mortars in an enclosed space indicate that the fly ash ammonia concentration should not exceed 100 mg N/kg ash in confined space applications. For most other applications with some ventilation the maximum acceptable concentration would be approximately 200 mg/kg. Early results from experiments on concrete suggest that, under similar conditions, ammonia diffusion from concrete occurs at a higher rate than in mortar. In addition, increasing the slump of concrete through the use of chemical admixtures has only a minor effect on the ammonia loss rate.

Robert F. Rathbone; Thomas L. Robl

2001-10-11T23:59:59.000Z

176

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

SciTech Connect (OSTI)

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

177

Performance and evaluation of gas-engine-driven split-system cooling equipment at the Willow Grove Naval Air Station  

SciTech Connect (OSTI)

DOE`s Federal Energy Management Program supports efforts to reduce energy use and associated expenditures within the federal sector; one such effort, the New Technology Demonstration Program (NTDP)(formerly the Test Bed Demonstration program), seeks to evaluate new energy saving US technologies and secure their more timely adoption by the federal government. This report describes the field evaluation conducted to examine the performance of a 15-ton natural-gas-engine- driven, split-system, air-conditioning unit. The unit was installed at a multiple-use building at Willow Grove Naval Air Station, a regular and reserve training facility north of Philadelphia, and its performance was monitored under the NTDP.

Armstrong, P.R.; Schmelzer, J.R.

1997-01-01T23:59:59.000Z

178

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

1984-01-01T23:59:59.000Z

179

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, M.; Wai, C.M.; Nagy, Z.

1983-08-15T23:59:59.000Z

180

Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer  

SciTech Connect (OSTI)

In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na{sub 2}SiO{sub 3}) and 10 M sodium hydroxide (NaOH) solutions at mass ratio of Na{sub 2}SiO{sub 3}/NaOH of 1.5 and curing temperature of 65 deg. C for 48 h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0 MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

Chindaprasirt, Prinya [Department of Civil Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen 40002 (Thailand); Rattanasak, Ubolluk, E-mail: ubolluk@buu.ac.t [Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Burapha University, Chonburi 20131 (Thailand)

2010-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Eco-friendly fly ash utilization: potential for land application  

SciTech Connect (OSTI)

The increase in demand for power in domestic, agricultural, and industrial sectors has increased the pressure on coal combustion and aggravated the problem of fly ash generation/disposal. Consequently the research targeting effective utilization of fly ash has also gained momentum. Fly ash has proved to be an economical substitute for expensive adsorbents as well as a suitable raw material for brick manufacturing, zeolite synthesis, etc. Fly ash is a reservoir of essential minerals but is deficient in nitrogen and phosphorus. By amending fly ash with soil and/or various organic materials (sewage sludge, bioprocess materials) as well as microbial inoculants like mycorrhizae, enhanced plant growth can be realized. Based on the sound results of large scale studies, fly ash utilization has grown into prominent discipline supported by various internationally renowned organizations. This paper reviews attempts directed toward various utilization of fly ash, with an emphasis on land application of organic/microbial inoculants amended fly ash.

Malik, A.; Thapliyal, A. [Indian Institute of Technology Delhi, New Delhi (India)

2009-07-01T23:59:59.000Z

182

Market assessment and technical feasibility study of PFBC ash use  

SciTech Connect (OSTI)

The overall objectives of this study are to determine the market potential and the technical feasibility of using PFBC ash in high volume ash use applications. The information will be of direct use to the utility industry in assessing the economics of PFBC power generation in light of ash disposal avoidance through ash marketing. In addition, the research is expected to result in the generation of generic data on the use of PFBC ash that could lead to novel processing options and procedures. The specific objectives of the proposed research and demonstration effort are: Define resent and future market potential of PFBC ash for a range of applications (Phase I); assess the technical feasibility of PFBC ash use in construction, civil engineering and agricultural applications (Phase II); and demonstrate the most promising of the market and ash use options in full-scale field demonstrations (Phase III).

Smith, V.E.; Bland, A.E.; Brown, T.H. [Western Research Inst., Laramie, WY (United States); Georgiou, D.N. [Jacques, Whitford and Associates Ltd., Dartmouth, NS (Canada); Wheeldon, J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-10-01T23:59:59.000Z

183

ash utilization symposium: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Websites Summary: Center for By-Products Utilization USE OF CLASS F FLY ASH AND CLEAN-COAL ASH BLENDS FOR CAST Report No.CBU-1996-07 July 1996 Presented and Published at the...

184

POLYVINYLCHLORIDE WASTE WITH OIL SHALE ASH TO CAPTURE  

E-Print Network [OSTI]

alkaline oil shale ash. Solid heat carrier (Galoter process)-type oil shale retorting units, where the

V. Oja; A. Elenurm; I. Rohtla; E. Tearo; E. Tali

185

Performance and evaluation of gas-engine-driven rooftop air conditioning equipment at the Willow Grove Naval Air Station. Final report (revised October 21, 1996)  

SciTech Connect (OSTI)

The performance was evaluated of a new US cooling technology that has been installed for the first time at a federal facility. The technology is a 15-ton natural gas-engine-driven rooftop air conditioning unit made by Thermo King. Two units were installed to serve the Navy Exchange at Willow Grove. The savings potential at Willow Grove is described and that in the federal sector estimated. Conditions for implementation are discussed. In summary, the new technology is generally cost-effective at sites where marginal electricity cost (per MBtu at the meter) is more than 4 times the marginal gas cost (per MBtu at the meter) and annual full-load-equivalent cooling hours exceed 2,000.

Armstrong, P.R.; Katipamula, S.

1996-10-01T23:59:59.000Z

186

New techniques for monitoring cement hydration under simulated well conditions  

SciTech Connect (OSTI)

Fourier transform infrared spectroscopy and synchrotron X-ray powder diffraction methods are described for studying cement hydration chemistry at temperatures up to 200 C, covering the normal temperature range of wellbore cementing. The methods provide complementary information on the transformation of silicate, ferrite and sulfate minerals. The thermal decomposition of the cement mineral ettringite is shown to occur at 114 C in a sealed system in contact with water. The FTIR spectrum of a well cement slurry hydrating at 150 C and 2,000 psi is analyzed. The anomalous thickening time behavior of certain cements around 75--100 C is discussed in the light of new data on the hydration of a Class G cement at 65 and 95 C, with and without retarder.

Luke, K.; Hall, C.; Jones, T. [Schlumberger Cambridge Research (United Kingdom); Barnes, P.; Turillas, X.; Lewis, A. [Univ. of London (United Kingdom). Birkbeck College

1995-11-01T23:59:59.000Z

187

Effective Permeability Change in Wellbore Cement with Carbon Dioxide Reaction  

SciTech Connect (OSTI)

Portland cement, a common sealing material for wellbores for geological carbon sequestration was reacted with CO{sub 2} in supercritical, gaseous, and aqueous phases at various pressure and temperature conditions to simulate cement-CO{sub 2} reaction along the wellbore from carbon injection depth to the near-surface. Hydrated Portland cement columns (14 mm diameter x 90 mm length; water-to-cement ratio = 0.33) including additives such as steel coupons and Wallula basalt fragments were reacted with CO{sub 2} in the wet supercritical (the top half) and dissolved (the bottom half) phases under carbon sequestration condition with high pressure (10 MPa) and temperature (50 C) for 5 months, while small-sized hydrated Portland cement columns (7 mm diameter x 20 mm length; water-to-cement ratio = 0.38) were reacted with CO{sub 2} in dissolved phase at high pressure (10 MPa) and temperature (50 C) for 1 month or with wet CO{sub 2} in gaseous phase at low pressure (0.2 MPa) and temperature (20 C) for 3 months. XMT images reveal that the cement reacted with CO{sub 2} saturated groundwater had degradation depth of {approx}1 mm for 1 month and {approx}3.5 mm for 5 month, whereas the degradation was minor with cement exposure to supercritical CO{sub 2}. SEM-EDS analysis showed that the carbonated cement was comprised of three distinct zones; the innermost less degraded zone with Ca atom % > C atom %, the inner degraded zone with Ca atom % {approx} C atom % due to precipitation of calcite, the outer degraded zone with C atom % > Ca atom % due to dissolution of calcite and C-S-H, as well as adsorption of carbon to cement matrix. The outer degraded zone of carbonated cement was porous and fractured because of dissolution-dominated reaction by carbonic acid exposure, which resulted in the increase in BJH pore volume and BET surface area. In contrast, cement-wet CO{sub 2}(g) reaction at low P (0.2 MPa)-T (20 C) conditions for 1 to 3 months was dominated by precipitation of micron-sized calcite on the outside surface of cement, which resulted in the decrease in BJH pore volume and BET surface area. Cement carbonation and pore structure change are significantly dependent on pressure and temperature conditions as well as the phase of CO{sub 2}, which controls the balance between precipitation and dissolution in cement matrix. Geochemical modeling result suggests that ratio of solid (cement)-to-solution (carbonated water) has a significant effect on cement carbonation, thus the cement-CO{sub 2} reaction experiment needs to be conducted under realistic conditions representing the in-situ wellbore environment of carbon sequestration field site. Total porosity and air permeability for a duplicate cement column with water-to-cement ratio of 0.38 measured after oven-drying by Core Laboratories using Boyle's Law technique and steady-state method were 31% and 0.576 mD. A novel method to measure the effective liquid permeability of a cement column using X-ray micro-tomography images after injection of pressurized KI (potassium iodide) is under development by PNNL. Preliminary results indicate the permeability of a cement column with water-to-cement ratio of 0.38 is 4-8 mD. PNNL will apply the method to understand the effective permeability change of Portland cement by CO{sub 2}(g) reaction under a variety of pressure and temperature conditions to develop a more reliable well-bore leakage risk model.

Um, Wooyong; Jung, Hun Bok; Martin, Paul F.; McGrail, B. Peter

2011-11-01T23:59:59.000Z

188

An investigation of cement mortar thermal storage characteristics  

E-Print Network [OSTI]

energy storage characteristics of solid cement mortar cylinders. Two var1a- tions 1nvolving mechanically induced porosity were also investigated. Rocks, a commonly used sensible heat storage material, were tested to prov1de a reference for the cement... mortar. A numer1cal model, analogous to program available for rock bed storage systems, simulating the cement mortar cylinder storage section was developed. Heat transfer coefficients were calculated from the experimental data for use in the model...

Davis, Glenn Baker

2012-06-07T23:59:59.000Z

189

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

the small cement plants, earthen vertical kiln (and hollowcement plant in North China utilizing vertical shaft kilnscement has ordered a vertical roller mill for the new kiln

Worrell, Ernst

2008-01-01T23:59:59.000Z

190

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

Lime Institute. 2001. Energy Efficiency Opportunity Guide inIndustry, Office of Energy Efficiency, Natural Resourcesof a Cement Kiln, Energy Efficiency Demonstration Scheme,

Worrell, Ernst

2008-01-01T23:59:59.000Z

191

Multifunctional Corrosion-resistant Foamed Well Cement Composites  

Broader source: Energy.gov (indexed) [DOE]

Multifunctional Corrosion-resistant Foamed Well Cement Composites Project Officer: Dan KingGreg Stillman Total budget: 300 K April 24 , 2013 Principal Investigator: Dr. Toshifumi...

192

Optimization Online - The carbon leakage effect on the cement ...  

E-Print Network [OSTI]

Feb 8, 2015 ... This paper investigates the impact of these two policies on the cement sector ... Environmental policies, Generalized Nash Equilibrium Problem.

Elisabetta Allevi

2015-02-08T23:59:59.000Z

193

Development of an Improved Cement for Geothermal Wells  

Broader source: Energy.gov (indexed) [DOE]

availability. * Schedule slippage resulting from delays in the fabrication of Chandler Engineering specialized high pressurehigh temperature cement testing equipment. 6 | US...

194

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

on Power Generation by Waste Heat of the Kiln in NingguoPure Low Temperature & Waste Heat in Beijing Cement Ltd. ;flash distillation waste heat power generation demonstration

Worrell, Ernst

2008-01-01T23:59:59.000Z

195

Stabilizing coal-water mixtures with Portland cement  

DOE Patents [OSTI]

Coal-water mixes stabilized by the addition of Portland cement which may additionally contain retarding carbohydrates, or borax are described. 1 tab.

Steinberg, M.; Krishna, C.R.

1984-10-17T23:59:59.000Z

196

Identification of active agents for tetrachloroethylene degradation in Portland cement slurry containing ferrous iron  

E-Print Network [OSTI]

-EDS) were used to identify minerals in chemical mixtures that have high activities. Results indicate that active agents for PCE degradation in Portland cement slurries and in cement extracts might be one of several AFm phases. However, systems without cement...

Ko, Sae Bom

2006-08-16T23:59:59.000Z

197

Instantaneous In-Situ Determination of Water-Cement Ratio of Fresh Concrete  

E-Print Network [OSTI]

method for cement content determination of fresh concrete.Cement and Concrete Research, 1980. 10(1): p. 23-34. Hime,the cement content of plastic concrete. ASTM Bulletin, 1955.

Mancio, Mauricio; Moore, Jeffrey R.; Brooks, Zenzile; Monteiro, Paulo J. M.; Glaser, Steve D.

2010-01-01T23:59:59.000Z

198

Screening technology reduces ash in spiral circuits  

SciTech Connect (OSTI)

In 2006, the James River Coal Co. selected the Stack Sizer to remove the minus 100 mesh high ash clay fraction from the clean coal spiral product circuits at the McCoy-Elkhorn Bevins Branch prep plant and at the Blue Diamond Leatherwood prep plant in Kentucky. The Stack Sizer is a multi-deck, high-frequency vibrating screen capable of separations as fine as 75 microns when fitted with Derrick Corp.'s patented high open area urethane screen panels. Full-scale lab tests and more than 10 months of continuous production have confirmed that the Stack Sizer fitted with Derrick 100 micron urethane screen panels consistently produces a clean coal fraction that ranges from 8 to 10% ash. Currently, each five-deck Stack Sizer operating at the Bevins Branch and Leatherwood prep plants is producing approximately 33 tons per hour of clean coal containing about 9% ash. This represents a clean coal yield of about 75% and an ash reduction of about 11% from the feed slurry. 3 figs. 2 tabs.

Brodzik, P. [Derrick Corp., Buffalo, NY (United States)

2007-05-15T23:59:59.000Z

199

Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network [OSTI]

Modern Vertical Shaft Kiln Technology” World Cement 1 26cement has ordered a vertical roller mill for the new kiln

Worrell, Ernst

2008-01-01T23:59:59.000Z

200

E-Print Network 3.0 - affect cement penetration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a coating Summary: as an admixture in cement and as a coating on cement for electromagnetic interference shielding'' J. Cao, D... parameters that affect the shielding...

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

Wang, L. , 2008. Alternative fuel using and waste materialPolicy Research on Alternative Fuels for Cement Industry incement and using alternative fuels in the cement kiln. There

Price, Lynn

2010-01-01T23:59:59.000Z

202

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

UNFCCC), 2007 b. Energy efficiency measures at cementUNFCCC), 2007 c. Energy efficiency measures at cementBanerjee, R. , 2005. Energy Efficiency and Demand Side

Price, Lynn

2010-01-01T23:59:59.000Z

203

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

and MAIN, 1993. Energy Technology in the Cement Industrialof Demonstrated Energy Technologies (CADDET), Internationaland MAIN. 1993. Energy Technology in the Cement Industrial

Price, Lynn

2010-01-01T23:59:59.000Z

204

Cement (2010 MECS) | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational HealthcatalystsMaking Same -Cement (2010

205

High Temperature Cements | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation,Ohio:GreerHi Gtel Jump to: navigation,Solar Power Plant JumpDrillingCements

206

Cement Bond Log | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV EconomicsOregon: Energy ResourcesCeilingCement Bond

207

Communication Electric polarization in carbon fiber-reinforced cement  

E-Print Network [OSTI]

Communication Electric polarization in carbon fiber-reinforced cement Sihai Wen, D.D.L. Chung Abstract Electric polarization induced an increase of the measured electrical resistivity of carbon fiber of the cement paste through the use of carbon fibers that were more crystalline, the increase of the fiber

Chung, Deborah D.L.

208

Portland Cement Concrete Pavement Shannon Golden, Alabama DOT  

E-Print Network [OSTI]

Portland Cement Concrete Pavement Shannon Golden, Alabama DOT PORTLAND CEMENT CONCRETE PAVEMENT PROJECT · First in Alabama in more than 25 years! · IM-I059 (342) Etowah County ­ I-59 Concrete Pavement Rehabilitation with Unbonded Concrete Overlay ­ Length: 10.9 miles ­ Thickness: 11.0 to 13.5 inches ­ Volume: 300

209

Magnesium phosphate glass cements with ceramic-type properties  

DOE Patents [OSTI]

Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY)

1984-03-13T23:59:59.000Z

210

Magnesium-phosphate-glass cements with ceramic-type properties  

DOE Patents [OSTI]

Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

Sugama, T.; Kukacka, L.E.

1982-09-23T23:59:59.000Z

211

Water quality investigation of Kingston Fossil Plant dry ash stacking  

SciTech Connect (OSTI)

Changing to a dry ash disposal systems at Kingston Fossil Plant (KFP) raises several water quality issues. The first is that removing the fly ash from the ash pond could alter the characteristics of the ash pond discharge to the river. The second concerns proper disposal of the runoff and possibly leachate from the dry ash stack. The third is that dry ash stacking might change the potential for groundwater contamination at the KFP. This report addresses each of these issues. The effects on the ash pond and its discharge are described first. The report is intended to provide reference material to TVA staff in preparation of environmental review documents for new ash disposal areas at Kingston. Although the investigation was directed toward analysis of dry stacking, considerations for other disposal options are also discussed. This report was reviewed in draft form under the title Assessment of Kingston Fossil Plant Dry Ash Stacking on the Ash Pond and Groundwater Quality.'' 11 refs., 3 figs., 18 tabs.

Bohac, C.E.

1990-04-01T23:59:59.000Z

212

Manufacture of ceramic tiles from fly ash  

DOE Patents [OSTI]

The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants. 6 figs.

Hnat, J.G.; Mathur, A.; Simpson, J.C.

1999-08-10T23:59:59.000Z

213

Market assessment of PFBC ash use  

SciTech Connect (OSTI)

Pressurized fluidized bed combustion (PFBC) of coal is undergoing demonstration in the United States, as well as throughout the world. American Electric Power`s (AEP`s) bubbling PFBC 70 MWe Tidd demonstration program in Ohio and pilot-scale development at Foster Wheeler Energia Oy 10 MWth circulating PFBC at Karhula, Finland, have demonstrated the advantages of PFBC technology. Further technology development in the US is planned with the deployment of the technology at the MacIntosh Clean Coal project in Lakeland, Florida. Development of uses for solid wastes from PFBC coal-fired power systems is being actively pursued as part of the demonstration of PFBC technologies. Ashes collected from Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, operating on (1) low sulfur subbituminous and (2) high sulfur bituminous coal; and ash from the AEP`s high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at Western Research Institute (WRI).

Bland, A. E.; Brown, T. H., Western Research Institute

1998-01-01T23:59:59.000Z

214

Correlation of Process Data and Electrocheical Noise to Assess Kraft Digester Corrosion: Second Year at Spring Grove  

SciTech Connect (OSTI)

Electrochemical noise (EN) probes were deployed in the carbon steel continuous kraft digester at Spring Grove at four locations and at one location in the bottom cone of the associated flash tank for a second consecutive year of a corrosion study. The probes contained dual electrodes of 309LSi stainless steel overlay--representing a field repair material applied to a portion of the vessel--and dual electrodes of 312 stainless steel overlay. Current and potential noise, the temperature at each probe location, and the value of 23 process parameters (flow rates, liquor chemistry, etc.) were again monitored continuously for a period of almost one year. Historical vessel inspection data and post-test evaluation of the probe components were used to assess/compare EN corrosion activity with physical changes in wall thickness and corrosion patterns on the digester shell. In addition, attempts were made to correlate EN activity from each electrode type with process parameters. The results indicate the corrosion conditions aggressive to mild steel persist within the digester, as post-test inspection of the vessel revealed localized corrosion of mild steel in locations previously free of attack. Further, there was evidence that the depth of localized attack of exposed steel had increased in some locations. Nevertheless, the stainless steel overlay in the digester was essentially immune to corrosion, as evidenced by retained surface relief and heat tint associated with the original deposition process. The 309LSi electrodes also appeared visually pristine, and post-exposure metallographic examination of the 309LSi electrode materials revealed no attack. The 312 electrode materials were similar in appearance, but exhibited very minor interdendritic attack over the exposed surface. The silver electrodes in the probes were consumed (to Ag{sub 2}S) to variable degree over the course of the exposure indicating a useful life of not more than a year in digester service in this vessel. Since the stainless steel overlay electrodes were immune to corrosion during the exposure, the current and potential noise activity on these probes is likely related to redox processes on the electrode surfaces. Analysis of this activity as a function of position (and year) in the vessel suggests that redox chemistry/conditions vary by a significant amount on a consistent basis--even on opposite sides of the vessel at the same elevation--and that these differences are not identified by process parameters tracked at the mill. These variable environmental conditions (flow, temperature, liquor chemistry) appear to have little effect on stainless steel overlays under evaluation, but apparently can be quite corrosive to steel as determined in the initial study in the digester at Spring Grove. With the exception of start-up and shutdown activity, including brief upsets for ''hanging columns'' or brief maintenance periods, no regular correlation was observed between tracked process variables and EN activity on any of the probes. In combination with the variable redox activity, this result suggests that the liquor sampling and flow data compiled at the mill do not represent the corrosion conditions in the vessel particularly well.

Pawel, SJ

2004-04-27T23:59:59.000Z

215

Performance and evaluation of gas engine driven rooftop air conditioning equipment at the Willow Grove (PA) Naval Air Station  

SciTech Connect (OSTI)

In a field evaluation conducted for the US Department of Energy (DOE) Office of Federal Energy Management Program (FEMP), the Pacific Northwest Laboratory (PNL) examined the performance of a new US energy-related technology under the FEMP Test Bed Demonstration Program. The technology was a 15-ton natural gas engine driven roof top air conditioning unit. Two such units were installed on a naval retail building to provide space conditioning to the building. Under the Test Bed Demonstration Program, private and public sector interests are focused to support the installation and evaluation of new US technologies in the federal sector. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) with DOE were the American Gas Cooling Center, Philadelphia Electric Company, Thermo King Corporation, and the US Naval Air Station at Willow Grove, Pennsylvania. Equipment operating and service data as well as building interior and exterior conditions were secured for the 1992 cooling season. Based on a computer assessment of the building using standard weather data, a comparison was made with the energy and operating costs associated with the previous space conditioning system. Based on performance during the 1992 cooling season and adjusted to a normal weather year, the technology will save the site $6,000/yr in purchased energy costs. An additional $9,000 in savings due to electricity demand ratchet charge reductions will also be realized. Detailed information on the technology, the installation, and the results of the technology test are provided to illustrate the advantages to the federal sector of using this technology. A history of the CRADA development process is also reported.

Armstrong, P.R.; Conover, D.R.

1993-05-01T23:59:59.000Z

216

Mercury capture by distinct fly ash carbon forms  

SciTech Connect (OSTI)

Carbon was separated from the fly ash from a Kentucky power plant using density gradient centrifugation. Using a lithium heterolpolytungstate high-density media, relative concentrations of inertinite (up to 85% vol.), isotropic carbon (up to 79% vol.), and anisotropic carbon (up to 76% vol.) were isolated from the original fly ash. Mercury concentration was lowest in the parent fly ash (which contains non-carbon components); followed by inertinite, isotropic coke, mixed isotropic-anisotropic coke fraction, and, with the highest concentration, the anisotropic coke concentrate. The latter order corresponds to the increase in BET surface area of the fly ash carbons. Previous studies have demonstrated the capture of mercury by fly ash carbon. This study confirms prior work demonstrating the varying role of carbon types in the capture, implying that variability in the carbon content influences the amount of mercury retained on the fly ash.

Hower, J.C.; Maroto-Valer, M.M.; Taulbee, D.N.; Sakulpitakphon, T.

1999-07-01T23:59:59.000Z

217

Early containment of high-alkaline solution simulating low-level radioactive waste stream in clay-bearing blended cement  

SciTech Connect (OSTI)

Portland cement blended with fly ash and attapulgite clay was mixed with high-alkaline solution simulating low-level radioactive waste stream at a one-to-one weight ratio. Mixtures were adiabatically and isothermally cured at various temperatures and analyzed for phase composition, total alkalinity, pore solution chemistry, and transport properties as measured by impedance spectroscopy. Total alkalinity is characterized by two main drops. The early one corresponds to a rapid removal of phosphorous, aluminum, sodium, and to a lesser extent potassium solution. The second drop from about 10 h to 3 days is mainly associated with the removal of aluminum, silicon, and sodium. Thereafter, the total alkalinity continues descending, but at a lower rate. All pastes display a rapid flow loss that is attributed to an early precipitation of hydrated products. Hemicarbonate appears as early as one hour after mixing and is probably followed by apatite precipitation. However, the former is unstable and decomposes at a rate that is inversely related to the curing temperature. At high temperatures, zeolite appears at about 10 h after mixing. At 30 days, the stabilized crystalline composition Includes zeolite, apatite and other minor amounts of CaCO{sub 3}, quartz, and monosulfate Impedance spectra conform with the chemical and mineralogical data. The normalized conductivity of the pastes shows an early drop, which is followed by a main decrease from about 12 h to three days. At three days, the permeability of the cement-based waste as calculated by Katz-Thompson equation is over three orders of magnitude lower than that of ordinary portland cement paste. However, a further decrease in the calculated permeability is questionable. Chemical stabilization is favorable through incorporation of waste species into apatite and zeolite.

Kruger, A.A. [Westinghouse Hanford Co., Richland, WA (United States); Olson, R.A.; Tennis, P.D. [Northwestern Univ., Evanston, IL (United States). Center for Advanced Cement-Based Materials] [and others

1995-04-01T23:59:59.000Z

218

Effect of Elevated Curing Temperature on Early Hydration and Microstructure of Composite Cements  

E-Print Network [OSTI]

Effect of Elevated Curing Temperature on Early Hydration and Microstructure of Composite Cements J, Seascale, Cumbria, CA20 1PG, UK Abstract The heat of hydration of a number of composite cement systems has of composite cements based on the partial replacement of Portland cement by waste materials has become

Sheffield, University of

219

Abstract The concurrent goals of cement hydration are to percolate (bridge) the original  

E-Print Network [OSTI]

Cement hydration Ã? Low temperature calorimetry Ã? Microstructure Ã? Percolation Ã? Porosity Ã? Rheology Ã?, however, cement-based materials exhibit a highly dynamic (micro)structure that is extremely sen- sitive. Because many of the cement hydration prod- ucts form around the initial cement clinker par- ticles

Bentz, Dale P.

220

Time-dependent behaviour of hardened cement paste under isotropic loading  

E-Print Network [OSTI]

of hardened cement paste under isotropic loading, Cement and Concrete Research, doi: 10.1016/j.cemconres.2012.03.002 hal-00689716,version1-19Apr2012 Author manuscript, published in "Cement and Concrete Research (2012 the framework of the classical theory of porous media. The effects of water-to-cement ratio and chemical

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Energy, environmental and greenhouse gas effects of using alternative fuels in cement production  

E-Print Network [OSTI]

1 Energy, environmental and greenhouse gas effects of using alternative fuels in cement to an increase of AF use from 8.7% to 20.9% of the total energy consumption. 2. One of the alternative fuels used cement industry produces about 3.3 billion tonnes of cement annually. Cement production is energy

Columbia University

222

Z .Chemical Geology 152 1998 257271 The thermal and cementation histories of a sandstone petroleum  

E-Print Network [OSTI]

Z .Chemical Geology 152 1998 257­271 The thermal and cementation histories of a sandstone petroleum of the cement formed, the maturation of petroleum in the interbedded shales likely postdates cementation. q 1998 of partially cemented petroleum reservoirs may help in constraining the physical character of a reservoir

223

Determination of Ash in Biomass: Laboratory Analytical Procedure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ash in Biomass Laboratory Analytical Procedure (LAP) Issue Date: 7172005 A. Sluiter, B. Hames, R. Ruiz, C. Scarlata, J. Sluiter, and D. Templeton Technical Report NREL...

224

Data Summary Report for Hanford Site Coal Ash Characterization  

SciTech Connect (OSTI)

The purpose of this report is to present data and findings from sampling and analysis of five distinct areas of coal ash within the Hanford Site River Corridor

Sulloway, H. M.

2012-03-06T23:59:59.000Z

225

Development of an Accelerated Ash-Loading Protocol for Diesel...  

Broader source: Energy.gov (indexed) [DOE]

Accelerated Ash-Loading Protocol for Diesel Particulate Filters Bruce G. Bunting and Todd J. Toops Oak Ridge National Laboratory Adam Youngquist and Ke Nguyen University of...

226

Kinetics of beneficiated fly ash by carbon burnout  

SciTech Connect (OSTI)

The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called Loss On Ignition (LOI). The concrete producers` day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

Okoh, J.M.; Dodoo, J.N.D.; Diaz, A. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States). Dept. of Natural Sciences; Ferguson, W.; Udinskey, J.R. Jr.; Christiana, G.A. [Delmarva Power, Wilmington, DE (United States)

1997-12-31T23:59:59.000Z

227

alkaline coal ash: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

228

Energy Efficiency Improvement Opportunities for the Cement Industry  

SciTech Connect (OSTI)

This report provides information on the energy savings, costs, and carbon dioxide emissions reductions associated with implementation of a number of technologies and measures applicable to the cement industry. The technologies and measures include both state-of-the-art measures that are currently in use in cement enterprises worldwide as well as advanced measures that are either only in limited use or are near commercialization. This report focuses mainly on retrofit measures using commercially available technologies, but many of these technologies are applicable for new plants as well. Where possible, for each technology or measure, costs and energy savings per tonne of cement produced are estimated and then carbon dioxide emissions reductions are calculated based on the fuels used at the process step to which the technology or measure is applied. The analysis of cement kiln energy-efficiency opportunities is divided into technologies and measures that are applicable to the different stages of production and various kiln types used in China: raw materials (and fuel) preparation; clinker making (applicable to all kilns, rotary kilns only, vertical shaft kilns only); and finish grinding; as well as plant wide measures and product and feedstock changes that will reduce energy consumption for clinker making. Table 1 lists all measures in this report by process to which they apply, including plant wide measures and product or feedstock changes. Tables 2 through 8 provide the following information for each technology: fuel and electricity savings per tonne of cement; annual operating and capital costs per tonne of cement or estimated payback period; and, carbon dioxide emissions reductions for each measure applied to the production of cement. This information was originally collected for a report on the U.S. cement industry (Worrell and Galitsky, 2004) and a report on opportunities for China's cement kilns (Price and Galitsky, in press). The information provided in this report is based on publicly-available reports, journal articles, and case studies from applications of technologies around the world.

Price, Lynn; Worrell, Ernst; Galitsky, Christina; Price, Lynn

2008-01-31T23:59:59.000Z

229

Use of Finite-element Analysis to Improve Well Cementing in HTHP Conditions  

E-Print Network [OSTI]

stresses of San Antonio cement (left) and PEEQ of cement San Antonio and Barco formation (right) after hydraulic fracturing ........ 103 Figure 5.1 UCS (top left), Young?s modulus (top right), and Poisson?s ratio (bottom) for Halliburton Portland... cements ............................................... 110 Figure 5.2 Tensile strength for Halliburton Portland cements ................................... 111 Figure 5.3 Stress strain-curve and photo of uniaxial test for Halliburton Portland cement...

Arias, Henry

2013-07-30T23:59:59.000Z

230

Seasonal effects of volatile oils in ashe and redberry juniper on preference and digestibility by goats  

E-Print Network [OSTI]

(qnodon dactylon (L.) Pers.), ashe juniper (Juniperus ashei Buchholz) and live Oak [Quercus virginiana (Small) Sarg. var. fusiformis] during the spring and fall. Angora and Spanish goats were exposed to ashe female, ashe male, redberry female and redberry...

Riddle, Richard R.

1994-01-01T23:59:59.000Z

231

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants  

E-Print Network [OSTI]

Utilization of Ash Fractions from Alternative Biofuels used in Power Plants PSO Project No. 6356 July 2008 Renewable Energy and Transport #12;2 Utilization of Ash Fractions from Alternative Biofuels)...............................................................................7 2. Production of Ash Products from Mixed Biofuels

232

Cell Ashing for Trace Element Analysis: A New Approach Based on Ultraviolet/Ozone  

E-Print Network [OSTI]

: synchrotron spectromicroscopy; micro- chemical analysis; MEPHISTO; ashing; incineration; trace element. Ashing ashing is based on high-temperature incineration or on the exposure to oxygen plasma (1­ 4). We adopted

Gilbert, Pupa Gelsomina De Stasio

233

E-Print Network 3.0 - aluminum-fly ash metal Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

extent, bottom ash, contain elevated amounts of heavy metals, and fly ash... . The dioxinsfurans on ash then don't seem to create an environmental problem. Heavy metals are...

234

E-Print Network 3.0 - ash samples pressurized Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

group of seven fly ash samples, and have... of coal in conventional and or advanced clean coal technology combustors. These include fly ash, bottom... ash, boiler slag, and flue...

235

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network [OSTI]

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwater using  iron?oxide coated coal bottom ash  Johanna L.  using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

236

Characterization and modeling of the cemented sediment surrounding...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cement phase is likely the reaction between the glass and the sea water to from a Mg-silicate, here modeled as sepiolite. Citation: Strachan DM, JV Crum, JV Ryan, and A...

237

E-Print Network 3.0 - ash nasal lavage Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the people of North America for thousands of years. Of the nine ash... species, white ash (Fraxinus americana L.) and green ... Source: USDA, Forestry Service, Northern Research...

238

E-Print Network 3.0 - ash disposal area Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 83 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: combustion 1. Fly ash is...

239

E-Print Network 3.0 - ash cenospheres composites Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Composites Addition of fly ash cenospheres to polymer matrix influences all... , polyethylene, etc.). The effects of addition of fly ash cenospheres on polymer composites...

240

E-Print Network 3.0 - ashe higher education Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

higher abrasion... Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - ash ahto lobjakas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

242

E-Print Network 3.0 - ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

243

E-Print Network 3.0 - ash paving demonstration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AND DEMONSTRATION... Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

244

E-Print Network 3.0 - ash penurunan kadar Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

245

E-Print Network 3.0 - ash quarterly technical Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

246

E-Print Network 3.0 - ashes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural...

247

E-Print Network 3.0 - ash confinement time Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

. The ASH system for the MIPS bounds execution time using a framework inspired by Deutsch 12. Exceptions... Appears in SIGCOMM '96, August 1996. ASHs: ... Source:...

248

E-Print Network 3.0 - ash slag silica Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 91 By-Products Utilization Summary: pozzolans include coal fly ash, blast furnace slag, silica fume, and other combustion ashes. When...

249

E-Print Network 3.0 - ash deposition propensities Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ash, fouling, co-combustion 1... ;5 relative compositions of major ash species in coal, ... Source: Hawaii Natural Energy Institute Collection: Renewable Energy 51...

250

E-Print Network 3.0 - ash deposits part Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Reading Collection: Geosciences 24 Research Summary RECOAL: Reintegration of coal ash disposal sites and mitigation Summary: being used for coal ash deposits....

251

E-Print Network 3.0 - ash char deposits Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ash, fouling, co-combustion 1... ;5 relative compositions of major ash species in coal, ... Source: Hawaii Natural Energy Institute Collection: Renewable Energy 86...

252

E-Print Network 3.0 - ash intranasal instillation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... -Strength Materials (CLSM); 232, Fly Ash and Natural Pozzolans...

253

Process for the recovery of alumina from fly ash  

DOE Patents [OSTI]

An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

Murtha, M.J.

1983-08-09T23:59:59.000Z

254

IN HARM'S WAY: Lack Of Federal Coal Ash  

E-Print Network [OSTI]

IN HARM'S WAY: Lack Of Federal Coal Ash Regulations Endangers Americans And Their Environment 2010 Thirty-nine New Damage Cases of Contamination from Improperly Disposed Coal Combustion Waste, Editor and Contributing Author #12;IN HARM'S WAY: Lack of Federal Coal Ash Regulations Endangers

Short, Daniel

255

Potential for energy conservation in the cement industry  

SciTech Connect (OSTI)

This report assesses the potential for energy conservation in the cement industry. Energy consumption per ton of cement decreased 20% between 1972 and 1982. During this same period, the cement industry became heavily dependent on coal and coke as its primary fuel source. Although the energy consumed per ton of cement has declined markedly in the past ten years, the industry still uses more than three and a half times the fuel that is theoretically required to produce a ton of clinker. Improving kiln thermal efficiency offers the greatest opportunity for saving fuel. Improving the efficiency of finish grinding offers the greatest potential for reducing electricity use. Technologies are currently available to the cement industry to reduce its average fuel consumption per ton by product by as much as 40% and its electricity consumption per ton by about 10%. The major impediment to adopting these technologies is the cement industry's lack of capital as a result of low or no profits in recent years.

Garrett-Price, B.A.

1985-02-01T23:59:59.000Z

256

State Waste Discharge Permit application: 200-E Powerhouse Ash Pit  

SciTech Connect (OSTI)

As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department and Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-E Powerhouse Ash Pit. The 200-E Powerhouse Ash Waste Water discharges to the 200-E Powerhouse Ash Pit via dedicated pipelines. The 200-E Ash Waste Water is the only discharge to the 200-E Powerhouse Ash Pit. The 200-E Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

Atencio, B.P.

1994-06-01T23:59:59.000Z

257

State Waste Discharge Permit application: 200-W Powerhouse Ash Pit  

SciTech Connect (OSTI)

As part of the Hanford Federal Facility Agreement and Consent Order negotiations; the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. This document constitutes the State Waste Discharge Permit application for the 200-W Powerhouse Ash Pit. The 200-W Powerhouse Ash Waste Water discharges to the 200-W Powerhouse Ash Pit via dedicated pipelines. The 200-W Powerhouse Ash Waste Water is the only discharge to the 200-W Powerhouse Ash Pit. The 200-W Powerhouse is a steam generation facility consisting of a coal-handling and preparation section and boilers.

Atencio, B.P.

1994-06-01T23:59:59.000Z

258

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

2003-05-20T23:59:59.000Z

259

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

2002-09-10T23:59:59.000Z

260

Waste Heat Recovery in Cement Plants By Fluidized Beds  

E-Print Network [OSTI]

combustor is classified as a nonhaz ardous waste similar to fly ash. As such, the sol ids may be disposed in a landfill after obtaining the appropriate permits. The waste solids are coal ash, calcium sulfate, cal cium oxide, and inerts, all ingredients...; a mix 0 clay, limestone, and fly ash is melted into clinker The recoverable waste heat streams from this proc shown in Figure 1. Both a traditional design integrated design are shown. II: W Z 2100? F o ...J

Fraley, L. D.; Ksiao, H. K.; Thunem, C. B.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS  

SciTech Connect (OSTI)

The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

2001-04-01T23:59:59.000Z

262

Toxicity mitigation and solidification of municipal solid waste incinerator fly ash using alkaline activated coal ash  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Incinerator fly ash (IFA) is added to an alkali activated coal fly ash (CFA) matrix. Black-Right-Pointing-Pointer Means of stabilizing the incinerator ash for use in construction applications. Black-Right-Pointing-Pointer Concrete made from IFA, CFA and IFA-CFA mixes was chemically characterized. Black-Right-Pointing-Pointer Environmentally friendly solution to IFA disposal by reducing its toxicity levels. - Abstract: Municipal solid waste (MSW) incineration is a common and effective practice to reduce the volume of solid waste in urban areas. However, the byproduct of this process is a fly ash (IFA), which contains large quantities of toxic contaminants. The purpose of this research study was to analyze the chemical, physical and mechanical behaviors resulting from the gradual introduction of IFA to an alkaline activated coal fly ash (CFA) matrix, as a mean of stabilizing the incinerator ash for use in industrial construction applications, where human exposure potential is limited. IFA and CFA were analyzed via X-ray fluorescence (XRF), X-ray diffraction (XRD) and Inductive coupled plasma (ICP) to obtain a full chemical analysis of the samples, its crystallographic characteristics and a detailed count of the eight heavy metals contemplated in US Title 40 of the Code of Federal Regulations (40 CFR). The particle size distribution of IFA and CFA was also recorded. EPA's Toxicity Characteristic Leaching Procedure (TCLP) was followed to monitor the leachability of the contaminants before and after the activation. Also images obtained via Scanning Electron Microscopy (SEM), before and after the activation, are presented. Concrete made from IFA, CFA and IFA-CFA mixes was subjected to a full mechanical characterization; tests include compressive strength, flexural strength, elastic modulus, Poisson's ratio and setting time. The leachable heavy metal contents (except for Se) were below the maximum allowable limits and in many cases even below the reporting limit. The leachable Chromium was reduced from 0.153 down to 0.0045 mg/L, Arsenic from 0.256 down to 0.132 mg/L, Selenium from 1.05 down to 0.29 mg/L, Silver from 0.011 down to .001 mg/L, Barium from 2.06 down to 0.314 mg/L and Mercury from 0.007 down to 0.001 mg/L. Although the leachable Cd exhibited an increase from 0.49 up to 0.805 mg/L and Pd from 0.002 up to 0.029 mg/L, these were well below the maximum limits of 1.00 and 5.00 mg/L, respectively.

Ivan Diaz-Loya, E. [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Allouche, Erez N., E-mail: allouche@latech.edu [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Eklund, Sven; Joshi, Anupam R. [Department of Chemistry, Louisiana Tech University, Ruston, LA 71272 (United States); Kupwade-Patil, Kunal [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States)

2012-08-15T23:59:59.000Z

263

Evaluation of Vitrification Processing Step for Rocky Flats Incinerator Ash  

SciTech Connect (OSTI)

In 1997, Pacific Northwest National Laboratory (PNNL) staff developed a processing option for incinerator ash at the Rocky Flats Environmental Technology Sites (RFETS). This work was performed with support from Los Alamos National Laboratory (LANL) and Safe Sites of Colorado (SSOC). A description of the remediation needs for the RFETS incinerator ash is provided in a report summarizing the recommended processing option for treatment of the ash (Lucy et al. 1998). The recommended process flowsheet involves a calcination pretreatment step to remove carbonaceous material followed by a vitrification processing step for a mixture of glass tit and calcined incinerator ash. Using the calcination pretreatment step to remove carbonaceous material reduced process upsets for the vitrification step, allowed for increased waste loading in the final product, and improved the quality of the final product. Figure 1.1 illustrates the flow sheet for the recommended processing option for treatment of RFETS incinerator ash. In 1998, work at PNNL further developed the recommended flow sheet through a series of studies to better define the vitrification operating parameters and to address secondary processing issues (such as characterizing the offgas species from the calcination process). Because a prototypical rotary calciner was not available for use, studies to evaluate the offgas from the calcination process were performed using a benchtop rotary calciner and laboratory-scale equipment (Lucy et al. 1998). This report focuses on the vitrification process step after ash has been calcined. Testing with full-scale containers was performed using ash surrogates and a muffle furnace similar to that planned for use at RFETS. Small-scale testing was performed using plutonium-bearing incinerator ash to verify performance of the waste form. Ash was not obtained from RFETS because of transportation requirements to calcine the incinerator ash prior to shipment of the material. Because part of PNNL's work was to characterize the ash prior to calcination and to investigate the effect of calcination on product quality, representative material was obtained from LANL. Ash obtained from LANL was selected based on its similarity to that currently stored at RFETS. The plutonium-bearing ashes obtained from LANL are likely from a RFETS incinerator, but the exact origin was not identified.

Wigent, W.L.; Luey, J.K.; Scheele, R.D.; Li, H.

1999-04-08T23:59:59.000Z

264

Direct utilization - recovery of minerals from coal fly ash. Fossil Energy Program. Technical progress report, 1 July 1984-30 September 1984 including summary of work for FY84  

SciTech Connect (OSTI)

The research discussed in this report deals with resource recovery from coal conversion solid wastes. Progress is reported on two methods (the HiChlor and Lime-Sinter processes) for extracting metal values from power plant fly ash. Preliminary work is also reported on a method of making cement from the residue of the lime-sinter process. In the HiChlor Process, metal oxides in the fly ash are converted to volatile chlorides by reaction with chlorine in the presence of a reductant. Several versions of this approach are being investigated. The Lime-Sinter Process utilizes a solid state reaction to selectively convert the alumina in fly ash to a soluble form. Fly ash is mixed with limestone and a suitable mineralizer (to reduce the temperature required for sintering and to enhance alumina recovery) and then sintered in a high temperature kiln. Alumina is recovered by leaching the resulting clinker. A complex relationship between the calcium, alumina, silica, and sulfur constituents in the feed mixture controls the formation and extraction of aluminate compounds. Alumina recovery levels are enhanced by promoting the formation of less-soluble calcium compounds and/or more-soluble aluminum compounds. A study is underway to determine the degree to which flue gas scrubber sludge can be used both as a limestone substitute and as a sulfur bearing mineralizer. Results show that 20 to 25% of the limestone can be provided by the scrubber sludges. 25 refs.,25 figs., 10 tabs.

Burnet, G.; Murtha, M.J.; Benson, J.D.

1985-03-01T23:59:59.000Z

265

PALM TREE GROVE COLLEGEAVE.  

E-Print Network [OSTI]

53 (GR) BC54 (SD) BC90 (DW) BC91 (CH) 26 36 FAU/BC JOINT USE LIBRARY LIBERAL ARTS CHILLER BUILDING DAVIE WEST CHILLER BUILDING - DAVIE WEST FAU/BC JOINT CHILDCARE CENTER FAU/BC PARKING GARAGE BROWARD

Fernandez, Eduardo

266

General Groves takes charge  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky Learning Fun withGenepool QuarterlyGeneraland Ernest O.

267

Leslie Groves - Hanford Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region serviceMission StatementCenter for Learn More about FusionLeslie

268

Phenolic acids as bioindicators of fly ash deposit revegetation  

SciTech Connect (OSTI)

The floristic composition, the abundance, and the cover of pioneer plant species of spontaneously formed plant communities and the content of total phenolics and phenolic acids, as humus constituents, of an ash deposit after 7 years of recultivation were studied. The restoration of both the soil and the vegetation on the ash deposits of the 'Nikola Tesla-A' thermoelectric power plant in Obrenovac (Serbia) is an extremely slow process. Unfavorable physical and chemical characteristics, the toxicity of fly ash, and extreme microclimatic conditions prevented the development of compact plant cover. The abundance and cover of plants increased from the central part of the deposit towards its edges. Festuca rubra L., Crepis setosa Hall., Erigeron canadensis L., Cirsium arvense (L.) Scop., Calamagrostis epigeios (L.) Roth., and Tamarix gallica L. were the most abundant species, thus giving the highest cover. Humus generated during the decomposition process of plant remains represents a completely new product absent in the ash as the starting material. The amount of total phenolics and phenolic acids in fly ash increased from the center of the deposit towards its edges in correlation with the increase in plant abundance and cover. The presence of phenolic acids indicates the ongoing process of humus formation in the ash, in which the most abundant pioneer plants of spontaneously formed plant communities play the main role. Phenolic compounds can serve as reliable bioindicators in an assessment of the success of the recultivation process of thermoelectric power plants' ash deposits.

L. Djurdjevic; M. Mitrovic; P. Pavlovic; G. Gajic; O. Kostic [Institute for Biological Research 'Sinisa Stankovic,' Belgrade (Serbia and Montenegro). Department of Ecology

2006-05-15T23:59:59.000Z

269

Coal Ash Corrosion Resistant Materials Testing Program  

SciTech Connect (OSTI)

The "Coal Ash Corrosion Resistant Materials Testing Program" is being conducted by The Babcock & Wilcox Company (B&W), the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) at Reliant Energy?s Niles plant in Niles, Ohio to provide full-scale, in-situ testing of recently developed boiler superheater materials. Fireside corrosion is a key issue for improving efficiency of new coal fired power plants and improving service life in existing plants. In November 1998, B&W began development of a system to permit testing of advanced tube materials at metal temperatures typical of advanced supercritical steam temperatures (1100°F and higher) in a boiler exhibiting coal ash corrosive conditions. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. In the spring of 1999 a system consisting of three identical sections, each containing multiple segments of twelve different materials, was installed. The sections are cooled by reheat steam, and are located just above the furnace entrance in Niles? Unit #1, a 110 MWe unit firing high sulfur Ohio coal. In November 2001 the first section was removed for thorough metallurgical evaluation after 33 months of operation. The second and third sections remain in service and the second is expected to be removed in the fall of 2003; the last is tentatively planned for the fall of 2004. This paper describes the program; its importance; the design, fabrication, installation and operation of the test system; materials utilized; experience to date; and results of the evaluation of the first section.

McDonald, D.K.

2003-04-22T23:59:59.000Z

270

E-Print Network 3.0 - ash kinetics mechanism Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

. Some of these ash particles may contribute to surface sealing if rainfall kinetic energy is sufficient... ......

271

Dechlorination ability of municipal waste incineration fly ash for polychlorinated phenols  

E-Print Network [OSTI]

Dechlorination ability of municipal waste incineration fly ash for polychlorinated phenols Leona incineration fly ash at 200 °C under nitrogen atmosphere. Thermodynamic calculations have been carried out ash produced by municipal waste incineration (MWI) have clearly demonstrated that MWI fly ash can

Cirkva, Vladimir

272

Close Out Report for the Ash Pit Operable Unit I Area of Concern 2F  

E-Print Network [OSTI]

........................................................................4 3 ­ Clean fill staged prior to grading over the Ash Pit area.............................................................5 4 ­ Clean fill being graded at the Ash Pit I to the early 1950's. The Ash Pits were also used for disposal of coal ash from various buildings

273

Effects of Cutting Time, Stump Height, and Herbicide Application on Ash (Fraxinus Spp.)  

E-Print Network [OSTI]

or cutting heights. Keywords: Buprestidae, control, coppice, eradication, triclopyr E merald ash borer (EAB

274

Respiratory and Reproductive Characteristics of Eastern Mosquitofish (Gambusia holbrooki) Inhabiting a Coal Ash Settling Basin  

E-Print Network [OSTI]

) Inhabiting a Coal Ash Settling Basin B. P. Staub, W. A. Hopkins, J. Novak, J. D. Congdon Savannah River 2002/Accepted: 29 March 2002 Abstract. Coal fly ash and effluent from coal ash settling basins viable populations in areas contaminated by coal ash. While eastern mosquitofish are present

Hopkins, William A.

275

A Review of Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

and Resource Saving Technologies in Cement Industry.1:87–94. Blue World Crete. 2012. Technology. Available atOakey. 2009. CO 2 Capture Technologies for Cement Industry.

Hasanbeigi, Ali

2014-01-01T23:59:59.000Z

276

The use of scrap tires in rotary cement kilns  

SciTech Connect (OSTI)

The use of scrap tires as a supplemental fuel in the United States Portland cement industry has increased significantly in the past six years. In 1990, there were two kilns using tire-derived fuel (TDF), today 30 kilns use TDF. The outlook for continued and expanded use of TDF in the U.S. cement industry should be considered favorable, with 15 kilns conducting tests to determine TDF`s applicability or in the permitting process. The Council`s estimates are that by the end of 1996, the cement industry could be consuming some 75-100 million of the 253 million annually generated scrap tires in the United States. This level of TDF usage will make the cement industry the largest market segments for scrap tires in the United States. While the long-term outlook is at present positive, there are a series of factors that have, and will likely continue to adversely impact the near-term usage of TDF. These issues, as well as the factors that are likely to positively impact the cement kiln TDF market are the subject of this presentation.

Blumenthal, M. [Scrap Tire Management Council, Washington, DC (United States)

1996-12-31T23:59:59.000Z

277

NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration  

E-Print Network [OSTI]

NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration and Microstructure Development Modeling Package. Version 3.0 Dale P. Bentz #12;NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration

Bentz, Dale P.

278

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

production instantly reaches the current world best practice energyworld best practice and implement aggressive energy efficiency and carbon reduction measures in all cement productionenergy intensity of China’s cement production would reach current world

Ke, Jing

2013-01-01T23:59:59.000Z

279

Energy conservation potential of Portland cement particle size distribution control, Phase 2  

SciTech Connect (OSTI)

The main objectives of Phase 2 are to determine the feasibility of using cements with controlled particle size distributions (CPSD cements) in practical concrete applications, and to refine our estimates of the potential energy savings that may ensue from such use. The work in Phase 2 is divided into two main tasks, some parts of which will be carried out simultaneously: Task 1 will continue cement paste studies to optimize cement performance similar to those of Phase 1, but with particular emphasis on gypsum requirements, blended cements, and water-reducing admixtures. This task will also include preparation of sufficient CPSD cements for use in all Phase 2 work. Task 2 will be a comprehensive examination of the properties of concretes made with CPSD cements. This will include optimization of concrete mix designs to obtain the best possible performance for practical applications of both portland and blended cements. The effects of chemical admixtures and curing temperature variations will also be determined.

Helmuth, R.A; Whiting, D.A.

1983-01-01T23:59:59.000Z

280

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

2050 China Energy and CO2 Emissions Report. Science Press,Energy Savings and CO2 Emissions Reduction of China’s CementEnergy Savings and CO2 Emissions Reduction of China’s Cement

Ke, Jing

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

of granulated blast furnace slag and its effect on theblast furnace slag in cement results from the combined effects

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

282

Improved cement quality and grinding efficiency by means of closed mill circuit modeling  

E-Print Network [OSTI]

..............................................................................................................................185 Page x LIST OF FIGURES Figure 1.1. Portland Cement (after Bhatty et al., 2004). ....................................................1 Figure 1.2. A Simplified Schematic of a Dry Cement Manufacturing Process. ................3 Figure 1....................................13 Figure 2.2. Typical Particle Size Distribution of a Type I Portland Cement Sample. .....16 Figure 2.3. Rosin-Rammler Representation of Cement PSD...........................................21 Figure 2.4. Blaine Calculation within the Particle...

Mejeoumov, Gleb Gennadievich

2009-05-15T23:59:59.000Z

283

Downhole cement test in a very hot hole  

SciTech Connect (OSTI)

Completion of the commercial-sized Hot Dry Rock Geothermal Energy Project requires that hydraulic fractures be created between two inclined wellbores at a depth of about 4 km (15,000 ft). Isolation of a section of the open wellbore is necessary for pressurization to achieve the fracture connections. A cemented-in liner/PBR assembly is one of the methods used for zone isolation near the botton of the injection well. A downhole, pumped cement test was first conducted at a wellbore temperature of 275/sup 0/C (525/sup 0/F) to determine if a suitable slurry could be designed, pumped, and later recovered to assure the success of the cemented-in liner operation.

Pettitt, R.A.; Cocks, G.G.; Dreesen, D.N.; Sims, J.R.; Nicholson, R.W.; Boevers, B.

1982-01-01T23:59:59.000Z

284

Rapid setting of portland cement by greenhouse carbon dioxide capture  

SciTech Connect (OSTI)

Following the work by Berger et al. on rapid setting of calcium silicates by carbonation, a method of high-volume capture of CO{sub 2} in portland cement has been developed. Typically, 10--24 wt. % of CO{sub 2} produced by the calcination of calcium carbonate during clinkering, may be captured, and the set cement acquires most of its full strength in less than a day. The approach will have economic advantages in fabrication of precast structures, in emergency development of infrastructure during natural disasters, and in defense applications. Moreover, it will help the cement industry comply with the Clean Air Act of 1990 by sequestering the greenhouse carbon dioxide.

Wagh, A.S.; Singh, D.; Knox, L.J.

1994-04-01T23:59:59.000Z

285

Guide to Using Wood Ash as an Agricultural Soil Amendment  

E-Print Network [OSTI]

from larger commercial sources such as wood-burning biomass plants which produce heat or electricity in the soil. Wood ash is more soluble and reactive than ground limestone, and brings about a Benefits Recycles

New Hampshire, University of

286

Determination of Total Solids and Ash in Algal Biomass: Laboratory...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solids and Ash in Algal Biomass Laboratory Analytical Procedure (LAP) Issue Date: December 2, 2013 S. Van Wychen and L. M. L. Laurens Technical Report NRELTP-5100-60956 December...

287

Studies of fly ash using thermal analysis techniques  

SciTech Connect (OSTI)

Improved thermoanalytical methods have been developed that are capable of quantitative identification of various components of fly ash from a laboratory-scale fluidized bed combustion system. The thermogravimetric procedure developed can determine quantities of H{sub 2}O, Ca(OH){sub 2}, CaCO{sub 3}, CaSO{sub 4} and carbonaceous matter in fly ash with accuracy comparable to more time-consuming ASTM methods. This procedure is a modification of the Mikhail-Turcotte methods that can accurately analyze bed ash, with higher accuracy regarding the greater amount of carbonaceous matter in fly ash. In addition, in conjunction with FTIR and SEM/EDS analysis, the reduction mechanism of CaSO{sub 4} as CaSO{sub 4} + 4H{sub 2} = CaS + 4H{sub 2}O has been confirmed in this study. This mechanism is important in analyzing and evaluating sulfur capture in fluidized-bed combustion systems.

Li, Hanxu; Shen, Xiang-Zhong; Sisk, B. [Western Kentucky Univ., Bowling Green, KY (United States)

1996-12-31T23:59:59.000Z

288

ash upptag av: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1* Environmental Management and Restoration Websites...

289

Enhancement of phosphogypsum with high lime fly ash  

E-Print Network [OSTI]

ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1983 Major... Subject: Civil Engineering ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH'LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Approved as to style and content by: Dr. ona d Saylak (Chairman f Committee) Dr. W. edbetter ( ember) (Member) r. Lloyd Deuel, 3...

Gregory, Chuck Alan

1983-01-01T23:59:59.000Z

290

The Effect of Simulated Barium Carbonate Waste Stream on the Hydration of Composite Cement Systems  

E-Print Network [OSTI]

The Effect of Simulated Barium Carbonate Waste Stream on the Hydration of Composite Cement Systems cements, comprised of ordinary Portland cement (OPC) and blast furnace slag (BFS), are used to encapsulate it is not uncommon for up to 90% of the OPC to be replaced by BFS, which will have significant effects

Sheffield, University of

291

The effect of BaCO3 on the hydration of OPC and composite cements  

E-Print Network [OSTI]

The effect of BaCO3 on the hydration of OPC and composite cements Claire A. Utton* and Neil B of ordinary Portland cement (OPC) and up to 90% blast furnace slag (BFS), are used to encapsulate Intermediate. The effect of BaCO3 on the hydration properties of composite cements is being studied. This paper reports

Sheffield, University of

292

Virtual Cement and Concrete Testing Laboratory Educational Version 2.0 User Guide  

E-Print Network [OSTI]

1 Virtual Cement and Concrete Testing Laboratory Educational Version 2.0 User Guide Jeffrey W of the Virtual Cement and Concrete Testing Laboratory (VCCTL) software, version 2.0. Using the VCCTL software, cement hydration, computer modeling, concrete testing, microstructure, simulation, virtual laboratory

Magee, Joseph W.

293

Sulfur dioxide oxidation and plume formation at cement kilns  

SciTech Connect (OSTI)

Results of source sampling at the Glens Falls cement kiln in Glens Falls, N.Y., are reported for sulfur oxides, ammonia, hydrochloric acid, oxygen, and moisture content. The origin of a detached, high-opacity, persistent plume originating from the cement kiln stack is investigated. It is proposed that this plume is due to ammonium salts of SOx and sulfuric acid that have been formed in condensed water droplets in the plume by the pseudocatalytic action of ammonia. (1 diagram, 1 graph, 22 references, 7 tables)

Dellinger, B.; Grotecloss, G.; Fortune, C.R.; Cheney, J.L.; Homolya, J.B.

1980-10-01T23:59:59.000Z

294

Ash level meter for a fixed-bed coal gasifier  

DOE Patents [OSTI]

An ash level meter for a fixed-bed coal gasifier is provided which utilizes the known ash level temperature profile to monitor the ash bed level. A bed stirrer which travels up and down through the extent of the bed ash level is modified by installing thermocouples to measure the bed temperature as the stirrer travels through the stirring cycle. The temperature measurement signals are transmitted to an electronic signal process system by an FM/FM telemetry system. The processing system uses the temperature signals together with an analog stirrer position signal, taken from a position transducer disposed to measure the stirrer position to compute the vertical location of the ash zone upper boundary. The circuit determines the fraction of each total stirrer cycle time the stirrer-derived bed temperature is below a selected set point, multiplies this fraction by the average stirrer signal level, multiplies this result by an appropriate constant and adds another constant such that a 1 to 5 volt signal from the processor corresponds to a 0 to 30 inch span of the ash upper boundary level. Three individual counters in the processor store clock counts that are representative of: (1) the time the stirrer temperature is below the set point (500.degree. F.), (2) the time duration of the corresponding stirrer travel cycle, and (3) the corresponding average stirrer vertical position. The inputs to all three counters are disconnected during any period that the stirrer is stopped, eliminating corruption of the measurement by stirrer stoppage.

Fasching, George E. (Morgantown, WV)

1984-01-01T23:59:59.000Z

295

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; the effect of various low-NOx firing modes on ash properties and adsorptivity; and the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. This first project period, experiments were carried out to better understand the fundamental nature of the ozonation effect on ash. Carbon surfaces were characterized by surfactant adsorption, and by X-ray Photoelectron Spectroscopy before and after oxidation, both by air at 440 C and by ozone at room temperature. The results strongly suggest that the beneficial effect of ozonation is in large part due to chemical modification of the carbon surfaces.

Robert Hurt; Eric Suuberg; John Veranth

2001-12-26T23:59:59.000Z

296

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project was to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific issues addressed included: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity based on pilot-plant studies; and (3) the kinetics and mechanism of ash ozonation. This laboratory data has provided scientific and engineering support and underpinning for parallel process development activities. The development work on the ash ozonation process has now transitioned into a scale-up and commercialization project involving a multi-industry team and scheduled to begin in 2004. This report describes and documents the laboratory and pilot-scale work in the above three areas done at Brown University and the University of Utah during this three-year project.

Robert Hurt; Eric Suuberg; John Veranth; Xu Chen; Indrek Kulaots

2004-02-13T23:59:59.000Z

297

Computational studies of two-phase cement-CO2-brine interaction in wellbore environments  

SciTech Connect (OSTI)

Wellbore integrity is essential to ensuring long-term isolation of buoyant supercritical CO{sub 2} during geologic sequestration of CO{sub 2}. In this report, we summarize recent progress in numerical simulations of cement-brine-CO{sub 2} interactions with respect to migration of CO{sub 2} outside of casing. Using typical values for the hydrologic properties of cement, caprock (shale) and reservoir materials, we show that the capillary properties of good quality cement will prevent flow of CO{sub 2} into and through cement. Rather, CO{sub 2}, if present, is likely to be confined to the casing-cement or cement-formation interfaces. CO{sub 2} does react with the cement by diffusion from the interface into the cement, in which case it produces distinct carbonation fronts within the cement. This is consistent with observations of cement performance at the CO{sub 2}-enhanced oil recovery SACROC Unit in West Texas (Carey et al. 2007). For poor quality cement, flow through cement may occur and would produce a pattern of uniform carbonation without reaction fronts. We also consider an alternative explanation for cement carbonation reactions as due to CO{sub 2} derived from caprock. We show that carbonation reactions in cement are limited to surficial reactions when CO{sub 2} pressure is low (< 10 bars) as might be expected in many caprock environments. For the case of caprock overlying natural CO{sub 2} reservoirs for millions of years, we consider Scherer and Huet's (2009) hypothesis of diffusive steady-state between CO{sub 2} in the reservoir and in the caprock. We find that in this case, the aqueous CO{sub 2} concentration would differ little from the reservoir and would be expected to produce carbonation reaction fronts in cements that are relatively uniform as a function of depth.

Carey, James William [Los Alamos National Laboratory; Lichtner, Peter C [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

298

Coal Ash Corrosion Resistant Materials Testing  

SciTech Connect (OSTI)

In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a moderate alkali content (0.2% sodium equivalents), thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that aggressive alkali sulfate constituents were present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. Test Section A was removed in November 2001 after about 24 months of service at the desired steam temperature set point, with about 15.5 months of exposure at full temperature. A progress report, issued in October 2002, was written to document the performance of the candidate alloys in that test section. The evaluation described the condition of each tube sample after exposure. It involved a determination of the rate of wall thickness loss for these samples. In cases where there was more than one sample of a candidate material in the test section, an assessment was made of the performance of the alloy as a function of temperature. Test Sections B and C were examined during the November 2001 outage, and it was decided that, due to excessive wastage, certain tube samples needed to be removed and replaced in order to ensure that Test Sections B and C would have a chance of remaining in the boiler for their intended exposure period. These suspect tube samples were replaced and the two remaining test sections were put back into service. The tube samples that were removed from Test Sections B and C were set aside for later analysis at the end of the planned exposure period. Test Sections B and C were again examined approximately six months later. At that time, measured wall thickness losses raised concerns about additional tube samples. These suspect samples were also removed, set aside for later analysis, and replaced. The test sections then went back into service until the end of the second exposure period, which was concluded in May 2003 when, due to evidence of excessive wastage, the valves were opened increasing cooling steam flow and thereby effectively stopping corrosion. In August 2003, Test Sections B and C were removed for closer examination. Section C had experienced about 42 months of service at the desired team temperature set point with 28.5 months at temperature at full temperature. Additional suspect samples were removed from Test Section B, then, it was re-installed into the boiler (at the location originally occupied by Section C), where it remained in service until the end of the program. Due to this removal history, the samples from Test Section B had a total service duration that varied from a minimum of 15.5 months (for samples that performed poorly) to 37 months for samples the survived for the full intended service exposure for Section B. The figure below shows a schematic of Test Section B and indicates the length of service exposure for different locations. This report provides the results of the evaluation of Test Section B, including the samples that remained in the Test Section for the full exposure period as well as those that were removed early. This report also is intended to compare and summarize the results for all three test sections. The analysis of T

D. K. McDonald; P. L. Daniel; D. J. DeVault

2007-12-31T23:59:59.000Z

299

'The Overriding Demand for Energy Conservation in the Cement Industry' An Update  

E-Print Network [OSTI]

addi tives. While cement makes up only about 7 to 15 percent of the weight of concrete, it is 1:5y far the greatest contributor of energy content in the mixture. Cement, usually portland cement, is a product derived from pyro-processing calcareous... and argillaceous materials such as limestone and clay or shale into an intermediate fused material called clinker, which is subse quently ground together with a small amount of gypsum. Portland cement is the principal material produced by the U. S. cement...

Spellman, L. U.

1981-01-01T23:59:59.000Z

300

Cement fatigue and HPHT well integrity with application to life of well prediction  

E-Print Network [OSTI]

to the cyclic loading and few data sets may not be sufficient to give an adequate description of cement behavior under fatigue loading. Studies were conducted by Kim and Kim 2 on the fatigue behavior of high strength concrete using a type I Portland cement....3: Comparison of Max Stress Levels to Number of Cycles for Different Cement Strengths [2] Antrim 3 conducted fatigue studies on hardened ordinary Portland (type I) cement paste using 2 specimens; one with a high-water cement ratio of 0.7 and another...

Ugwu, Ignatius Obinna

2009-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Westinghouse Cementation Facility of Solid Waste Treatment System - 13503  

SciTech Connect (OSTI)

During NPP operation, several waste streams are generated, caused by different technical and physical processes. Besides others, liquid waste represents one of the major types of waste. Depending on national regulation for storage and disposal of radioactive waste, solidification can be one specific requirement. To accommodate the global request for waste treatment systems Westinghouse developed several specific treatment processes for the different types of waste. In the period of 2006 to 2008 Westinghouse awarded several contracts for the design and delivery of waste treatment systems related to the latest CPR-1000 nuclear power plants. One of these contracts contains the delivery of four Cementation Facilities for waste treatment, s.c. 'Follow on Cementations' dedicated to three locations, HongYanHe, NingDe and YangJiang, of new CPR-1000 nuclear power stations in the People's Republic of China. Previously, Westinghouse delivered a similar cementation facility to the CPR-1000 plant LingAo II, in Daya Bay, PR China. This plant already passed the hot functioning tests successfully in June 2012 and is now ready and released for regular operation. The 'Follow on plants' are designed to package three 'typical' kind of radioactive waste: evaporator concentrates, spent resins and filter cartridges. The purpose of this paper is to provide an overview on the Westinghouse experience to design and execution of cementation facilities. (authors)

Jacobs, Torsten; Aign, Joerg [Westinghouse Electric Germany GmbH, Global Waste Management, Tarpenring 6, D- 22419 Hamburg (Germany)] [Westinghouse Electric Germany GmbH, Global Waste Management, Tarpenring 6, D- 22419 Hamburg (Germany)

2013-07-01T23:59:59.000Z

302

Development of Bulk Nanocrystalline Cemented Tungsten Carbide for Industrial Applicaitons  

SciTech Connect (OSTI)

This report contains detailed information of the research program entitled "Development of Bulk Nanocrystalline Cemented Tungsten Carbide Materials for Industrial Applications". The report include the processes that were developed for producing nanosized WC/Co composite powders, and an ultrahigh pressure rapid hot consolidation process for sintering of nanosized powders. The mechanical properties of consolidated materials using the nanosized powders are also reported.

Z. Zak Fang, H. Y. Sohn

2009-03-10T23:59:59.000Z

303

Automated Assessment of Polyethylene Wear in Cemented Acetabular Components using  

E-Print Network [OSTI]

Automated Assessment of Polyethylene Wear in Cemented Acetabular Components using Anteroposterior, Ninewells Hospital, Dundee, DD1 9SY, UK Abstract Polyethylene wear in the acetabular components of hip to the polyethylene acetabular component of a prosthesis so that both it and the metal femoral head component can

St Andrews, University of

304

COMPOSITE PORTLAND CEMENT CONCRETE PAVEMENTS (Tollway) Effective: January 30, 2012  

E-Print Network [OSTI]

COMPOSITE PORTLAND CEMENT CONCRETE PAVEMENTS (Tollway) Effective: January 30, 2012 Revised: May 8 for special applications to composite pavements as shown and described on the Drawings and in this Special as required; 5. Constructing the composite pavement on a prepared subgrade, or subbase, without forms. 6

305

Leaching induced concentration profiles in the solid phase of cement  

SciTech Connect (OSTI)

Analysis of the solid phase of portland cement specimens by energy dispersive x-ray spectrometry before and after leaching provided elemental profiles within the cement. Releases of potassium were calculated from the solid phase profiles and were compared to releases determined from leachate analyses of potassium and cesium-137. The fraction of potassium released in the leachate was found to correlate closely to that of cesium-137 under varying time and temperature conditions, despite the different manner in which each was originally contained in the cement. Agreement was obtained among potassium releases as determined from the solid, potassium in the leachate and cesium-137 in the leachate. These correlations allowed the use of potassium as an analog for cesium-137 in cement. Profiles of potassium in the solid showed varying degrees of depletion. A specimen, sectioned immediately after leaching for 471 days, showed complete removal of potassium to 9 mm depth from the specimens surface. From 9 mm to the center of the specimen, an apparently linear increase in concentration was observed. Specimens that had been air dried prior to sectioning had profiles that were produced by evaporative transport of dissolved species toward the surface. Carbonation of the surface appears to have retarded migration of the dissolved material. This prevented it from reaching the outer edge and resulted in increased potassium concentrations several mm inside the surface. 9 refs., 10 figs., 2 tabs.

Fuhrmann, M.; Colombo, P.

1987-04-01T23:59:59.000Z

306

India's cement industry: Productivity, energy efficiency and carbon emissions  

SciTech Connect (OSTI)

Historical estimates of productivity growth in India's cement sector vary from indicating an improvement to a decline in the sector's productivity. The variance may be traced to the time period of study, source of data for analysis, and type of indices and econometric specifications used for reporting productivity growth. Analysis shows that in the twenty year period, 1973 to 1993, productivity in the aluminum sector increased by 0.8% per annum. An econometric analysis reveals that technical progress in India's cement sector has been biased towards the use of energy and capital, while it has been material and labor saving. The increase in productivity was mainly driven by a period of progress between 1983 and 1991 following partial decontrol of the cement sector in 1982. The authors examine the current changes in structure and energy efficiency in the sector. Their analysis shows that the Indian cement sector is moving towards world-best technology, which will result in fewer carbon emissions and more efficient energy use. However, substantial further energy savings and carbon reduction potentials still exist.

Schumacher, Katja; Sathaye, Jayant

1999-07-01T23:59:59.000Z

307

Surface effects of cement-based solidified waste forms  

E-Print Network [OSTI]

This study was performed in order to determine-nine if the surface characteristics of cement-based waste forms were different than those of the bulk material. This was done as a prelude to the potential development of an accelerated leach test...

Pavlonnis, George

1998-01-01T23:59:59.000Z

308

Regional distribution of diagenetic carbonate cement in Palaeocene deepwater  

E-Print Network [OSTI]

0QF, UK (Received 9 June 1998; revised 15 March 1999) ABSTRACT: Sandstones of the Palaeocene al., 1993), and by inorganic thermal breakdown of organic material at depths >1.5 km (Irwin et al., 1977). Within the Rannoch Formation of the Brent Group, sandstones contain >5% carbonate cement

Haszeldine, Stuart

309

Contact Mechanics Based Mechanical Characterization of Portland Cement Paste  

E-Print Network [OSTI]

that the calcium silicate hydrate (C-S-H) phase of hydrated portland cement has different properties on the nanometric scale than on the micron scale. Packing density of C-S-H particles is proposed as an explanation for the disparity in the measured results...

Jones, Christopher

2012-02-14T23:59:59.000Z

310

Study of composite cement containing burned oil shale  

E-Print Network [OSTI]

Study of composite cement containing burned oil shale Julien Ston Supervisors : Prof. Karen properties. SCMs can be by-products from various industries or of natural origin, such as shale. Oil shale correctly, give a material with some cementitious properties known as burned oil shale (BOS). This study

Dalang, Robert C.

311

More durable roof coverings such as steel and fiber cement  

E-Print Network [OSTI]

- heating equipment saves money. Tankless water heaters provide hot water on demand at a preset temperature- cement siding is termite- and water-resistant and warrantied to last 50 years. Increasing the amount natural daylighting. Xeriscaping, or using native plants, significantly reduces the need for watering

312

Metal recovery from fly ash generated from vitrification process for MSW ash  

SciTech Connect (OSTI)

Metal-bearing wastes have to be carefully treated because heavy metals could be leached out under uncontrolled conditions when disposed of in a landfill. Consequently, heavy metals should be principally recovered and recycled forever. From this standpoint, the author has been trying to develop a technology to recover heavy metals from toxic vitrification fly ash for recycling to smelters. After a number of laboratory-scale experiments, pilot plant tests were successfully carried out and the developed process has been proven to be commercially realized. The main features of the process are that it recovers almost 100% of the heavy metals, simultaneously separating the metals which are recovered in a lead smelter from those in a zinc smelter, and that the output of the process are only metallurgical products recyclable for smelters and the effluent water which can be released into the environment. The process is considered an ideal one for the treatment of toxic fly ash from the viewpoint of not only natural resources but also environmental conservation.

Izumikawa, Chiaki [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)] [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)

1996-12-31T23:59:59.000Z

313

SYNCHROTRON X-RAY MICROTOMOGRAPHY, ELECTRON PROBE MICROANALYSIS, AND NMR OF TOLUENE WASTE IN CEMENT.  

SciTech Connect (OSTI)

Synchrotron X-ray microtomography shows vesicular structures for toluene/cement mixtures, prepared with 1.22 to 3.58 wt% toluene. Three-dimensional imaging of the cured samples shows spherical vesicles, with diameters ranging from 20 to 250 {micro}m; a search with EPMA for vesicles in the range of 1-20 {micro}m proved negative. However, the total vesicle volume, as computed from the microtomography images, accounts for less than 10% of initial toluene. Since the cements were cured in sealed bottles, the larger portion of toluene must be dispersed within the cement matrix. Evidence for toluene in the cement matrix comes from {sup 29}Si MAS NMR spectroscopy, which shows a reduction in chain silicates with added toluene. Also, {sup 2}H NMR of d{sub 8}-toluene/cement samples shows high mobility for all, toluene and thus no toluene/cement binding. A model that accounts for all observations follows: For loadings below about 3 wt%, most toluene is dispersed in the cement matrix, with a small fraction of the initial toluene phase separating from the cement paste and forming vesicular structures that are preserved in the cured cement. Furthermore, at loadings above 3 wt%, the abundance of vesicles formed during toluene/cement paste mixing leads to macroscopic phase separation (most toluene floats to the surface of the cement paste).

BUTLER,L.G.

1999-07-22T23:59:59.000Z

314

Ghabezloo et al.: Poromechanical behaviour of hardened cement paste under isotropic loading Poromechanical behaviour of hardened cement paste  

E-Print Network [OSTI]

of the material is described in the framework of the mechanics of porous media. The poroelastic parameters the framework of the theory of porous media. Keywords: hardened cement paste, poromechanics, effective stress and Concrete Research, DOI 10.1016/j.cemconres.2008.06.007 * Corresponding Author : CERMES, Ecole Nationale des

Boyer, Edmond

315

Study on the Volatility of Cesium in Dry Ashing Pretreatment and Dissolution of Ash by Microwave Digestion System - 13331  

SciTech Connect (OSTI)

Based on the regulation of the activity concentration of Cs-137, Co-58, Co-60, Fe-55, Ni-59, Ni-63, Sr-90, Nb-94, and Tc-99, and the total alpha from the radioactive waste acceptance criteria, the measurement of the activity concentration of these nuclides in low and intermediate levels of radioactive waste such as in paper, cotton, vinyl and plastic samples was investigated. A dry ashing method was applied to obtain a concentration effect of the samples. Owing to the temperature dependence of the volatility for cesium, the temperature of 300 to 650 deg. C was examined. It was found that 450 deg. C is the optimum dry ashing temperature. After dry ashing, the produced ash was dissolved with HNO{sub 3}, HCl, and HF by a high-performance microwave digestion system. The ash sample, for the most part, was completely dissolved with 10 mL of HNO{sub 3}, 4 mL of HCl, and 0.25 mL of HF by a high-performance microwave digestion system using a nova high temperature rotor at 250 deg. C for 90 min until reaching 0.2 g. To confirm the reliability of cesium loss after the performance of the dry ashing procedure, a cesium standard solution for AAS and a Cs-137 standard solution for gamma spectrometry were added to a paper towel or a planchet of stainless steel, respectively. Cesium was measured by AAS, ICP-MS, and gamma spectrometry. The volatility of cesium did not occur until 450 deg. C ashing. (authors)

Choi, Kwang-Soon; Lee, Chang Heon; Ahn, Hong-Joo; Park, Yong Joon; Song, Kyuseok [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)] [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

316

Release of Ammonium and Mercury from NOx Controlled Fly Ash  

SciTech Connect (OSTI)

One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

Schroeder, K.T.; Cardone, C.R.; Kim, A.G

2007-07-01T23:59:59.000Z

317

Ash bed level control system for a fixed-bed coal gasifier  

DOE Patents [OSTI]

An ash level control system is provided which incorporates an ash level meter to automatically control the ash bed level of a coal gasifier at a selected level. The ash level signal from the ash level meter is updated during each cycle that a bed stirrer travels up and down through the extent of the ash bed level. The ash level signal is derived from temperature measurements made by thermocouples carried by the stirrer as it passes through the ash bed and into the fire zone immediately above the ash bed. The level signal is compared with selected threshold level signal to determine if the ash level is above or below the selected level once each stirrer cycle. A first counter is either incremented or decremented accordingly. The registered count of the first counter is preset in a down counter once each cycle and the preset count is counted down at a selected clock rate. A grate drive is activated to rotate a grate assembly supporting the ash bed for a period equal to the count down period to maintain the selected ash bed level. In order to avoid grate binding, the controller provides a short base operating duration time each stirrer cycle. If the ash bed level drops below a selected low level or exceeds a selected high level, means are provided to notify the operator.

Fasching, George E. (Morgantown, WV); Rotunda, John R. (Fairmont, WV)

1984-01-01T23:59:59.000Z

318

E-Print Network 3.0 - ash yellows 16sr Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ORANGE RED Eruption is imminent with significant emission of volcanic ash... that blast volcanic ash (tiny rock fragments) and gas more than 100,000 feet into the air....

319

Tephrochronology and Stratigraphy of Eocene and Oligocene Volcanic Ashes of East and Central Texas  

E-Print Network [OSTI]

using neutron activation analysis (NAA) of bulk ash and glass shards, inductively coupled plasma mass spectrometry (ICPMS) of bulk ash, and electron microprobe analysis of both apatite phenocrysts and glass shards to characterize their geochemistry...

Heintz, Mindi

2013-12-02T23:59:59.000Z

320

Leaching and standing water characteristics of bottom ash and composted manure blends  

E-Print Network [OSTI]

Coal burning electrical generating facilities produce roughly 91 million metric tons of ash byproducts annually. Typically, this ash is retained at the power plant sites, adding to the cost of managing wastes at the plants. Another waste material...

Mathis, James Gregory

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

E-Print Network 3.0 - ashing wet Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 4 By-Products Utilization Summary: A3, containing 20% clean coal ash and 5% wet collected Class F ash had compressive strengths... 0 Center for...

322

E-Print Network 3.0 - ash material analisis Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

was used in this work. An ASTM Class F fly ash... , and N3) were proportioned with clean coal fly ash containing 22% ... Source: Wisconsin-Milwaukee, University of - Department...

323

E-Print Network 3.0 - ashes total contents Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fly ash content for normal concrete... contained fly ash up to a maximum of 35% of clean-coal ... Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

324

E-Print Network 3.0 - alkali-activated fly ash Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 12 By-Products Utilization Summary: CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique... of...

325

E-Print Network 3.0 - activated fly ash Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 9 By-Products Utilization Summary: CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique... of...

326

E-Print Network 3.0 - ashing dry Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shrinkage of Non-Air Entrained HRWRA Concrete -0.05% 0.00% 0.05% 0... NS3, 33% Clean Coal Ash, 5% Class F Fly Ash Fig. 15 - ... Source: Wisconsin-Milwaukee, University of -...

327

E-Print Network 3.0 - ash formation transformations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chlorinated phenols because their presence in the ash could result in the formation of dioxins and furans... THE USE OF MUNICIPAL WASTE COMBUSTOR ASH AS A PARTIAL REPLACEMENT OF...

328

E-Print Network 3.0 - ash aqueous carbonation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash Summary: Jordanian oil shale ash was used as an adsorbent for the removal of...

329

E-Print Network 3.0 - ash silica fume Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

,and Bruce W. Ramme CBU-1996-08 REP-283 July 1996 Presented andPublished at the American Coal Ash Association... 's Twelfth International Coal Ash Use Symposium,Orlando,FL,January...

330

E-Print Network 3.0 - ash dosage du Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ash and iron-foundry baghouse dust in the manufacturing of economical self-compacting concrete... . CONCLUSIONS: The limestone-quarry fines and Class C fly ash showed...

331

E-Print Network 3.0 - ash transportation distance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ash and iron-foundry baghouse dust in the manufacturing of economical self-compacting concrete... . CONCLUSIONS: The limestone-quarry fines and Class C fly ash showed...

332

E-Print Network 3.0 - ash quality characterization Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ash and iron-foundry baghouse dust in the manufacturing of economical self-compacting concrete... . CONCLUSIONS: The limestone-quarry fines and Class C fly ash showed...

333

E-Print Network 3.0 - assess ash related Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

has been... Center for By-Products Utilization USE OF CLASS F FLY ASH AND CLEAN-COAL ASH BLENDS FOR CAST... Report No. CBU-1996-07 July 1996 Presented and Published at the...

334

Non-Destructive X-ray Measurement of Soot, Ash, Washcoat and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

X-ray Measurement of Soot, Ash, Washcoat and Regeneration Damage for DPFs Non-Destructive X-ray Measurement of Soot, Ash, Washcoat and Regeneration Damage for DPFs New commercially...

335

Opportunities for Energy Efficiency and Demand Response in the California Cement Industry  

SciTech Connect (OSTI)

This study examines the characteristics of cement plants and their ability to shed or shift load to participate in demand response (DR). Relevant factors investigated include the various equipment and processes used to make cement, the operational limitations cement plants are subject to, and the quantities and sources of energy used in the cement-making process. Opportunities for energy efficiency improvements are also reviewed. The results suggest that cement plants are good candidates for DR participation. The cement industry consumes over 400 trillion Btu of energy annually in the United States, and consumes over 150 MW of electricity in California alone. The chemical reactions required to make cement occur only in the cement kiln, and intermediate products are routinely stored between processing stages without negative effects. Cement plants also operate continuously for months at a time between shutdowns, allowing flexibility in operational scheduling. In addition, several examples of cement plants altering their electricity consumption based on utility incentives are discussed. Further study is needed to determine the practical potential for automated demand response (Auto-DR) and to investigate the magnitude and shape of achievable sheds and shifts.

Olsen, Daniel; Goli, Sasank; Faulkner, David; McKane, Aimee

2010-12-22T23:59:59.000Z

336

A Coupled Nanoindentation/SEM-EDS Study on Low Water/Cement Ratio Portland Cement Paste: Evidence for C-S-H/Ca(OH)[subscript 2] Nanocomposites  

E-Print Network [OSTI]

A low water/cement ratio (w/c=0.20) hydrated Portland cement paste was analyzed by grid-indentation coupled with ex situ scanning electron microscope-energy-dispersive X-ray spectra (SEM-EDS) analysis at each indentation ...

Chen, Jeffrey J.

337

Ash reduction system using electrically heated particulate matter filter  

DOE Patents [OSTI]

A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

2011-08-16T23:59:59.000Z

338

Continuous air agglomeration method for high carbon fly ash beneficiation  

DOE Patents [OSTI]

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahon L. (Pittsburgh, PA); Champagne, Kenneth J. (Monongahela, PA); Finseth, Dennis H. (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

339

Coal-ash slag attack and corrosion of refractories  

SciTech Connect (OSTI)

The corrosion characteristics of a variety of fused-cast refractories in contact with various coal-ash slags were investigated. A fused-cast chrome-spinel refractory exhibited excellent corrosion resistance to both acidic and basic coal-ash slags at 1500/sup 0/C, even in the absence of water cooling. The slag-refractory interaction was limited to the formation of a stable band of recrystallized hercynitic spinel. Alumina-chromia refractories were superior to alumina and magnesia-chrome refractories when exposed to acidic slags.

Bonar, J.A. (Carborundum Co., Niagara Falls, NY); Kennedy, C.R.; Swaroop, R.B.

1980-04-01T23:59:59.000Z

340

Scanning probe microscopy: Sulfate minerals in scales and cements  

SciTech Connect (OSTI)

The principles of scanning probe microscopy (SPM) are illustrated with examples from oilfield mineralogy, particularly emphasizing sulfate minerals involved in scale formation and cement hydration chemistry. The topography of the (010) cleavage surface of gypsum observed by atomic force microscopy shows atomically flat terraces separated by shallow steps often only one unit cell high. SPM allows direct observation of processes on mineral surfaces while they are in contact with solutions. The dissolution etching and crystal growth of gypsum and barite are discussed and rates of step migration estimated. The orientation of steps is related to the crystallographic axes. The action of phosphonate crystal growth inhibitor on gypsum and of a chelating scale solvent on barite are also shown. The multiphase microstructure of an oilwell cement clinker is described in relation to its hydration chemistry in contact with water and its reaction with sulfate ions.

Hall, C. [Schlumberger Cambridge Research (United Kingdom)

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Mt. Etna tropospheric ash retrieval and sensitivity analysis using Moderate Resolution Imaging  

E-Print Network [OSTI]

. In order to derive the ash plume optical thickness, the particle effective radius and the total mass, exploiting the distinct reflectivity of meteorological and volcanic clouds in the near infrared spectral as containing volcanic ash compared to the original method. The retrieved mean ash optical thick- ness at 0

Oxford, University of

342

MULTIPLE-SCALE DYNAMIC LEACHING OF A MUNICIPAL SOLID WASTE INCINERATION ASH  

E-Print Network [OSTI]

1 MULTIPLE-SCALE DYNAMIC LEACHING OF A MUNICIPAL SOLID WASTE INCINERATION ASH Waste Management (in source such as municipal solid waste (MSW) incineration ash, requires a knowledge of the so is proposed. Key words: Leaching, Waste, Incineration ash, Chromium, L/S ratio, Modelling. hal-00656672

Paris-Sud XI, Université de

343

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater  

E-Print Network [OSTI]

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater Reyad; available online 29 October 2003 Abstract A by-product fly ash from oil shale processing was converted shale; Ash; Zeolite; Cadmium and lead removal 1. Introduction Oil shale exists in Jordan with large

Shawabkeh, Reyad A.

344

Hydration and strength development of binder based on high-calcium oil shale fly ash  

SciTech Connect (OSTI)

The properties of high-calcium oil shale fly ash and low-calcium coal fly ash, which are produced in Israeli power stations, were investigated. High-calcium oil shale fly ash was found to contain a great amount of CaO{sub free} and SO{sub 3} in the form of lime and anhydrite. Mixtures of high-calcium oil shale fly ash and low-calcium coal fly ash, termed fly ash binder, were shown to cure and have improved strength. The influence of the composition and curing conditions on the compressive strength of fly ash binders was examined. The microstructure and the composition of fly ash binder after curing and long-term exposure in moist air, water and open air conditions were studied. It was determined that ettringite is the main variable in the strength and durability of cured systems. The positive effect of calcium silicate hydrates, CSH, which are formed by interaction of high-calcium oil shale fly ash and low-calcium coal fly ash components, on the carbonation and dehydration resistance of fly ash binder in open air is pronounced. It was concluded that high-calcium oil shale fly ash with high CaO{sub free} and SO{sub 3} content can be used as a binder for building products.

Freidin, C. [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)] [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)

1998-06-01T23:59:59.000Z

345

Correlation relations between mineralogical components in ash from Kaa-Khem coals  

SciTech Connect (OSTI)

Regression analysis was used to study correlation relations between the mineral components of coals. Regularities in the variability of the concentrations of individual ash-forming elements with changing ash contents of coals and changing seam depth were found. The X-ray diffraction characteristics of coal ashes and the qualitative composition of their mineralogical components are presented.

N.N. Yanchat; L.Kh. Tas-ool [Russian Academy of Sciences, Kyzyl (Russia). Tuvinian Institute for Complex Exploration of Natural Resources

2008-08-15T23:59:59.000Z

346

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M Sulloway

2007-10-31T23:59:59.000Z

347

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M. Sulloway

2007-09-26T23:59:59.000Z

348

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

SciTech Connect (OSTI)

China's cement industry, which produced 1,388 million metric tons (Mt) of cement in 2008, accounts for almost half of the world's total cement production. Nearly 40% of China's cement production is from relatively obsolete vertical shaft kiln (VSK) cement plants, with the remainder from more modern rotary kiln cement plants, including plants equipped with new suspension pre-heater and pre-calciner (NSP) kilns. Shandong Province is the largest cement-producing Province in China, producing 10% of China's total cement output in 2008. This report documents an analysis of the potential to improve the energy efficiency of NSP kiln cement plants in Shandong Province. Sixteen NSP kiln cement plants were surveyed regarding their cement production, energy consumption, and current adoption of 34 energy-efficient technologies and measures. Plant energy use was compared to both domestic (Chinese) and international best practice using the Benchmarking and Energy Saving Tool for Cement (BEST-Cement). This benchmarking exercise indicated an average technical potential primary energy savings of 12% would be possible if the surveyed plants operated at domestic best practice levels in terms of energy use per ton of cement produced. Average technical potential primary energy savings of 23% would be realized if the plants operated at international best practice levels. Energy conservation supply curves for both fuel and electricity savings were then constructed for the 16 surveyed plants. Using the bottom-up electricity conservation supply curve model, the cost-effective electricity efficiency potential for the studied cement plants in 2008 is estimated to be 373 gigawatt hours (GWh), which accounts for 16% of total electricity use in the 16 surveyed cement plants in 2008. Total technical electricity-saving potential is 915 GWh, which accounts for 40% of total electricity use in the studied plants in 2008. The fuel conservation supply curve model shows the total technical fuel efficiency potential equal to 7,949 terajoules (TJ), accounting for 8% of total fuel used in the studied cement plants in 2008. All the fuel efficiency potential is shown to be cost effective. Carbon dioxide (CO{sub 2}) emission reduction potential associated with cost-effective electricity saving is 383 kiloton (kt) CO{sub 2}, while total technical potential for CO{sub 2} emission reduction from electricity-saving is 940 ktCO{sub 2}. The CO{sub 2} emission reduction potentials associated with fuel-saving potentials is 950 ktCO{sub 2}.

Price, Lynn; Hasanbeigi, Ali; Lu, Hongyou; Wang, Lan

2009-10-01T23:59:59.000Z

349

Extension and replacement of aspalt cement with sulphur  

E-Print Network [OSTI]

material containing bitumen, sulphur, and mineral matter such as sand, rock, road metal and clinker (41). He recommended preparing the mixture in hot mix plants, and completely filling the voids between aggregate particles with sulphur-asphalt binder... Selection . Aggregate Selection Selection of Asphalt Cement and Sulphur Content 10 13 20 23 23 26 27 28 28 28 33 44 PAGE Selection of Moisture Condition and Compaction Effort . 45 Processing of Sulphur-Asphalt Emulsion (SAE) Binders...

Pickett, Daniel Ernest

1977-01-01T23:59:59.000Z

350

Polymer-cement geothermal-well-completion materials. Final report  

SciTech Connect (OSTI)

A program to develop high-temperature polymer cements was performed. Several formulations based on organic and semi-inorganic binders were evaluated on the basis of mechanical and thermal stability, and thickening time. Two optimized systems exhibited properties exceeding those required for use in geothermal wells. Both systems were selected for continued evaluation at the National Bureau of Standards and contingent upon the results, for field testing in geothermal wells.

Zeldin, A.N.; Kukacka, L.E.

1980-07-01T23:59:59.000Z

351

Corrosion of aluminium metal in OPC- and CAC-based cement matrices  

SciTech Connect (OSTI)

Corrosion of aluminium metal in ordinary Portland cement (OPC) based pastes produces hydrogen gas and expansive reaction products causing problems for the encapsulation of aluminium containing nuclear wastes. Although corrosion of aluminium in cements has been long known, the extent of aluminium corrosion in the cement matrices and effects of such reaction on the cement phases are not well established. The present study investigates the corrosion reaction of aluminium in OPC, OPC-blast furnace slag (BFS) and calcium aluminate cement (CAC) based systems. The total amount of aluminium able to corrode in an OPC and 4:1 BFS:OPC system was determined, and the correlation between the amount of calcium hydroxide in the system and the reaction of aluminium obtained. It was also shown that a CAC-based system could offer a potential matrix to incorporate aluminium metal with a further reduction of pH by introduction of phosphate, producing a calcium phosphate cement.

Kinoshita, Hajime, E-mail: h.kinoshita@sheffield.ac.uk [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom)] [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom); Swift, Paul; Utton, Claire [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom)] [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom); Carro-Mateo, Beatriz [The Public University of Navarra, C/Esquíroz, 30 trasera, Pamplona 31007 (Spain)] [The Public University of Navarra, C/Esquíroz, 30 trasera, Pamplona 31007 (Spain); Marchand, Geraldine [The National Institute of Applied Sciences (INSA) Lyon, 20 Avenue Albert Einstein 69621 Villeurbanne Cedex (France)] [The National Institute of Applied Sciences (INSA) Lyon, 20 Avenue Albert Einstein 69621 Villeurbanne Cedex (France); Collier, Nick [National Nuclear Laboratory, Chadwick House, Birchwood Park, Warrington, WA3 6AE (United Kingdom)] [National Nuclear Laboratory, Chadwick House, Birchwood Park, Warrington, WA3 6AE (United Kingdom); Milestone, Neil [Industrial Research Ltd., 69 Gracefield Road, Lower Hutt, 5040 (New Zealand)] [Industrial Research Ltd., 69 Gracefield Road, Lower Hutt, 5040 (New Zealand)

2013-08-15T23:59:59.000Z

352

BEyond thE BAcklAsh: equity and participation  

E-Print Network [OSTI]

BEyond thE BAcklAsh: equity and participation in bicycle planning. executive summary | May 2011 Camp Conor Clarke Joe Delia Jennifer Harris-Hernandez Sungbae Park Brian Paul Scott Richmond Sam Stein Jessame Hannus ValeriaTreves Bill DiPaola Kristen Jones Paul Steely White Katie Lyon-Hart We thank

Qiu, Weigang

353

Measurement of the Optical Proper-ties of Volcanic Ash  

E-Print Network [OSTI]

: ­ Scattering solar radiation. ­ Absorption in the infrared. For chemical reactions: ­ Particles become coatedMeasurement of the Optical Proper- ties of Volcanic Ash Daniel M. Peters and R. G. Grainger@atm.ox.ac.uk http://www.atm.ox.ac.uk 1 Abstract We have just commenced a laboratory project, the "Optical Properties

Oxford, University of

354

Spectroscopic research on infrared emittance of coal ash deposits  

SciTech Connect (OSTI)

This paper deals with thermal radiation characteristics of ash deposits on a pulverized coal combustion boiler of an electric power plant. Normal emittance spectra in the near to medium infrared (2.5-25 {mu}m) region and total normal emittances were measured on four kinds of ground ash deposits. Measurements were conducted in the 570-1460 K temperature range which is common for boiler furnaces, by both heating and cooling the ash samples, with the aim to study the effect of their thermal history. Dependence of emittance on wavelength, temperature and chemical composition was studied, too. Samples were tested for transparency (opacity) to verify the accuracy of results. It was determined that the thicknesses used for the ash powders are opaque for infrared radiation for thicknesses in the order of a millimeter. Tests have shown that spectral emittance increases with an increase of wavelength with a characteristic pattern common for all samples. Spectral normal emittance increases strongly with temperature at shorter wavelengths and remains high and unchanged at longer ones. Emittance spectra are not very sensitive to chemical composition of ashes especially beyond {lambda} {approx} 5 {mu}m. With an increase of temperature, total emittance of the powdered sample decreases to a minimum value around 1200 K. Further temperature rise induces an increase of total emittance due to sintering in the ash. On cooling, the emittance increases monotonically following the hysteresis. Quantitative directions for evaluating thermal radiation characteristics of ash deposits for the merits of the safety design of boiler furnaces were proposed. That comprises correlating the experimentally obtained emittance spectra with curves of simple analytical form, i.e., a continuous function of minimum emittance vs. wavelength. The proposed method can be extended to other specimens from the same furnace and used to determine correlations for thermal calculation of old and design of new furnaces - with similar geometry and combusting similar coal. The method is potentially applicable to completely different boiler furnaces combusting different coal, and the authors recommend running the tests with new deposit samples. The data will then be applicable to the thermal design of a whole new class of furnaces, having similar geometry and combusting similar coal. This is expected to greatly enhance the accuracy and precision of thermal calculation as well as the efficiency of thermal design of steam boilers. (author)

Saljnikov, Aleksandar; Komatina, Mirko; Gojak, Milan [Department of Thermomechanics, Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11120 Belgrade 35 (RS); Vucicevic, Biljana [Laboratory for Thermal Engineering, Institute of Nuclear Sciences VINCA, P.O. Box 522, Belgrade 11001 (RS); Goricanec, Darko [Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, Maribor 2000 (Slovenia); Stevanovic, Zoran [Faculty of Mining and Geology, University of Belgrade, Dusina 7, 11120 Belgrade 35 (RS)

2009-11-15T23:59:59.000Z

355

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

dioxide (CO2) emissions from fossil fuel combustion, as wellCO2 emissions (including cement process and fossil fuel combustion

Ke, Jing

2013-01-01T23:59:59.000Z

356

Microsoft Word - NETL-TRS-2-2013_Foamed Cement_20140124.docx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultimately, this research will provide industry the knowledge to ensure long-term well integrity and safe operation of wells in which foamed cements are used. Computed...

357

Policy Options for Encouraging Energy Efficiency Best Practices in Shandong Province's Cement Industry  

E-Print Network [OSTI]

Azure. Alternative Fuel Use in the Cement Sector in ShandongAlternative fuels ..6 Resource potential for alternative fuel use in Shandong

Price, Lynn

2013-01-01T23:59:59.000Z

358

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

Sustainable Development waste heat recovery World Wide FundTaishan Cement Works Waste Heat Recovery and Utilisation forPlant’s Low Temperature Waste Heat Power Generation Project.

Price, Lynn

2010-01-01T23:59:59.000Z

359

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

report of cement industry waste heat power generation. ChinaWorrell et al. , 2001). Waste heat recovery (WHR) poweradoption and utilization of waste heat recovery (WHR) power

Ke, Jing

2013-01-01T23:59:59.000Z

360

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

Banerjee, R. , 2005. Energy Efficiency and Demand SideKiln Systems,” Energy Efficiency in the Cement Industry (Ed.for Improving Energy Efficiency, Reducing Pollution and

Price, Lynn

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

cement industry Oxygen enrichment technology Post-combustionOther Benefits: ? Oxygen enrichment technology reduces fuelprocess. Oxy-fuel technology uses oxygen instead of air in

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

362

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

of Demonstrated Energy Technologies (CADDET), Internationaland MAIN. 1993. Energy Technology in the Cement IndustrialAugust 19, 2009. Energy Technology Support Unit (ETSU).

Price, Lynn

2010-01-01T23:59:59.000Z

363

Estimation of CO2 Emissions from China's Cement Production: Methodologies and Uncertainties  

E-Print Network [OSTI]

L. , 2006. Discussion of CO2 emission reduction in ChineseFurther discussion of CO2 emission reduction in Chinesecalculation method of CO2 emissions of cement production.

Ke, Jing

2014-01-01T23:59:59.000Z

364

Quantifying the Co-benefits of Energy-Efficiency Programs: A Case Study of the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

ingredient in cement: vertical shaft kilns and rotary kilns.cement was produced by plants using outdated vertical shaft kilns (Vertical shaft kilns (Mt) Rotary (NSP + other) kilns (Mt) Clinker production (Mt) Clinker-cement

Hasanbeigi, Ali

2014-01-01T23:59:59.000Z

365

Process to eliminate production of fly ash by wet bottom boilers  

SciTech Connect (OSTI)

This patent describes a process for the reduction of fly ash in a wet bottom boiler of the type having a primary and secondary furnace. It comprises collecting the fly ash from one of an electrostatic precipitator, a bag house, a cyclone collector, a multi- cyclone collector, a gravity separator and a sharply curved duct; removing the fly ash in a stream of carrier gas into the furnace; adding a fuel to the stream of carrier gas and fly ash; introducing the carrier gas and fly ash and fuel into one of the primary and secondary furnaces, wherein the fuel and the heat from at least one of the surrounding gas and molten slag provide energy to melt the fly ash; and discharging the melted fly ash with slag from the furnace bottom.

Breen, B.P.; Schrecengost, R.A.; Gabrielson, J.E.

1991-09-03T23:59:59.000Z

366

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents [OSTI]

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas fired furnances or boilers. Two concentric shells define a combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, A.H.

1982-04-30T23:59:59.000Z

367

Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic Sequestration Conditions Using X?ray Computed Microtomography  

SciTech Connect (OSTI)

ABSTRACT: X-ray microtomography (XMT), a nondestructive three-dimensional imaging technique, was applied to demonstrate its capability to visualize the mineralogical alteration and microstructure changes in hydrated Portland cement exposed to carbon dioxide under geologic sequestration conditions. Steel coupons and basalt fragments were added to the cement paste in order to simulate cement-steel and cement-rock interfaces. XMT image analysis showed the changes of material density and porosity in the degradation front (density: 1.98 g/cm3, porosity: 40%) and the carbonated zone (density: 2.27 g/cm3, porosity: 23%) after reaction with CO2- saturated water for 5 months compared to unaltered cement (density: 2.15 g/cm3, porosity: 30%). Three-dimensional XMT imaging was capable of displaying spatially heterogeneous alteration in cement pores, calcium carbonate precipitation in cement cracks, and preferential cement alteration along the cement-steel and cement-rock interfaces. This result also indicates that the interface between cement and host rock or steel casing is likely more vulnerable to a CO2 attack than the cement matrix in a wellbore environment. It is shown here that XMT imaging can potentially provide a new insight into the physical and chemical degradation of wellbore cement by CO2 leakage.

Jung, Hun Bok; Jansik, Danielle P.; Um, Wooyong

2013-01-01T23:59:59.000Z

368

Performance and evaluation of gas engine driven rooftop air conditioning equipment at the Willow Grove (PA) Naval Air Station. Interim report, 1992 cooling season  

SciTech Connect (OSTI)

In a field evaluation conducted for the US Department of Energy (DOE) Office of Federal Energy Management Program (FEMP), the Pacific Northwest Laboratory (PNL) examined the performance of a new US energy-related technology under the FEMP Test Bed Demonstration Program. The technology was a 15-ton natural gas engine driven roof top air conditioning unit. Two such units were installed on a naval retail building to provide space conditioning to the building. Under the Test Bed Demonstration Program, private and public sector interests are focused to support the installation and evaluation of new US technologies in the federal sector. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) with DOE were the American Gas Cooling Center, Philadelphia Electric Company, Thermo King Corporation, and the US Naval Air Station at Willow Grove, Pennsylvania. Equipment operating and service data as well as building interior and exterior conditions were secured for the 1992 cooling season. Based on a computer assessment of the building using standard weather data, a comparison was made with the energy and operating costs associated with the previous space conditioning system. Based on performance during the 1992 cooling season and adjusted to a normal weather year, the technology will save the site $6,000/yr in purchased energy costs. An additional $9,000 in savings due to electricity demand ratchet charge reductions will also be realized. Detailed information on the technology, the installation, and the results of the technology test are provided to illustrate the advantages to the federal sector of using this technology. A history of the CRADA development process is also reported.

Armstrong, P.R.; Conover, D.R.

1993-05-01T23:59:59.000Z

369

JV Task 6 - Coal Ash Resources Research Consortium Research  

SciTech Connect (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of coal combustion by-products (CCBs). CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCB utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program (JSRP), which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCB performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 1998 to 2007 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCBs. CARRC topical reports were prepared on several completed tasks. Specific CARRC 1998B2007 accomplishments included: (1) Development of several ASTM International Standard Guides for CCB utilization applications. (2) Organization and presentation of training courses for CCB professionals and teachers. (3) Development of online resources including the Coal Ash Resource Center, Ash from Biomass in Coal (ABC) of cocombustion ash characteristics, and the Buyer's Guide to Coal-Ash Containing Products. In addition, development of expanded information on the environmental performance of CCBs in utilization settings included the following: (1) Development of information on physical properties and engineering performance for concrete, soil-ash blends, and other products. (2) Training of students through participation in CARRC research projects. (3) Participation in a variety of local, national, and international technical meetings, symposia, and conferences by presenting and publishing CCB-related papers.

Debra Pflughoeft-Hassett; Tera Buckley; Bruce Dockter; Kurt Eylands; David Hassett; Loreal Heebink; Erick Zacher

2008-04-01T23:59:59.000Z

370

Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network [OSTI]

B. , 1990. “Utilisation of Waste Heat from the Cement RotaryAdvanced Concepts of Waste Heat Recovery in Cement Plants”a roller mill. Utilizing waste heat from the kiln exhaust,

Worrell, Ernst

2008-01-01T23:59:59.000Z

371

Technology for the Recovery of Fuel and Adsorbent Carbons from Coal Burning Utility Ash Ponds and Landfills  

SciTech Connect (OSTI)

Several sampling techniques were evaluated to recover representative core samples from the ash ponds at Western Kentucky Energy's Coleman Station. The most successful was a combination of continuous-flight augers and specially designed soft-sediment sampling tubes driven by a Hammerhead drill mounted on an amphibious ARGO vehicle. A total of 51 core samples were recovered and analyzed in 3 ft sections and it was determined that there are 1,354,974 tons of ash in Pond C. Of the over 1.35M tons of ash present, 14% or 190K tons can be considered as coarse (+100 mesh). Pond C contains approximately 88K tons of carbon, nearly half of which is coarse and potentially recoverable with spiral concentration while the fine carbon (-100 mesh) is recoverable with froth flotation. There are 1.27M tons of carbon-free ash, 12% of which is coarse and potentially usable as block sand. Spiral concentration testing on bulk samples showed that product grade of 30 to 38% C (4200 to 5500 Btu/lb) was obtainable. When this product was cleaned again in an additional stage of spiral concentration, the product grade was improved to 7200 to 8200 Btu/lb with an accompanying 13 to 29% decrease in yield. Release analysis of hydraulically classified pond ash showed that froth flotation could provide froth products with as high a grade as 9000 Btu/lb with a yield of 5%. Increasing yield to 10% reduced froth grade to 7000 Btu/lb. Batch flotation provided froth grades as high as 6500 Btu/lb with yields of 7% with 1.5 lb/ton SPP and 1 lb/ton frother. Column flotation test results were similar to those achieved in batch flotation in terms of both grade and yield, however, carbon recoveries were lower (<70%). High airflow rate was required to achieve >50% carbon recovery and using wash water improved froth grade. Bottom ash samples were recovered from each of the units at Coleman Station. Characterization confirmed that sufficient quantity and quality of material is generated to produce a marketable lightweight aggregate and recover a high-grade fuel product. Spiral concentration provided acceptable grade lightweight aggregate with yields of only 10 to 20%. Incorporating a sieve bend into the process to recover coarse, porous ash particles from the outside race of the spirals increased aggregate yield to as high as 75%, however, the carbon content of the aggregate also increased. An opening size of 28 mesh on the sieve bend appeared to be sufficient. Lightweight concrete blocks (28 to 32 lbs) were produced from bottom ash and results show that acceptable strength could be attained with a cement/concrete ratio as low as 1/4. A mobile Proof-of-Concept (POC) field unit was designed and fabricated to meet the processing objectives of the project. The POC plant consisted of two trailer-mounted modules and was completely self sufficient with respect to power and water requirements. The POC unit was hauled to Coleman Station and operated at a feed rate of 2 tph. Results showed that the spirals operated similarly to previous pilot-scale operations and a 500 lb composite sample of coarse carbon was collected with a grade of 51.7% C or 7279 Btu/lb. Flotation results compared favorably with release analysis and 500 lbs of composite froth product was collected with a grade of 35% C or 4925 Btu/lb. The froth product was dewatered to 39% moisture with vacuum filtration. Pan pelletization and briquetting were evaluated as a means of minimizing handling concerns. Rotary pan pelletization produced uniform pellets with a compressive strength of 4 lbf without the use of any binder. Briquettes were produced by blending the coarse and fine carbon products at a ratio of 1:10, which is the proportion that the two products would be produced in a commercial operation. Using 3% lime as a binder produced the most desirable briquettes with respect to strength, attrition and drop testing. Additionally, the POC carbon products compared favorably with commercial activated carbon when used for removal of mercury from simulated flue gas. A business model was generated to summarize anti

J.G. Groppo; T.L. Robl

2005-09-30T23:59:59.000Z

372

EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS  

SciTech Connect (OSTI)

Tests were performed in simulated flue gas streams using fly ash from the electrostatic precipitators of two full-scale utility boilers. One fly ash was from a Powder River Basin (PRB) coal, while the other was from Blacksville coal. Elemental Hg was injected upstream from samples of fly ash loaded onto filters housed in an oven at 120 or 180 C. Concentrations of oxidized and elemental Hg downstream from the filters were determined using the Ontario Hydro method. The gas stream composition and whether or not ash was present in the gas stream were the two most important variables affecting Hg oxidation. The presence of HCl, NO, NO{sub 2}, and SO{sub 2} were all important with respect to Hg oxidation, with NO{sub 2} and HCl being the most important. The presence of NO suppressed Hg oxidation in these tests. Although the two fly ashes were chemically and mineralogically diverse, there were generally no large differences in catalytic potential (for oxidizing Hg) between them. Similarly, no ash fraction appeared to be highly catalytic relative to other ash fractions. This includes fractions enriched in unburned carbon and fractions enriched in iron oxides. Although some differences of lesser magnitude were observed in the amount of oxidized Hg formed, levels of oxidized Hg generally tracked well with the surface areas of the different ashes and ash fractions. Therefore, although the Blacksville fly ash tended to show slightly more catalytic activity than the PRB fly ash, this could be due to the relatively high surface area of that ash. Similarly, for Blacksville fly ash, using nonmagnetic ash resulted in more Hg oxidation than using magnetic ash, but this again tracked well with the relative surface areas of the two ash fractions. Test results suggest that the gas matrix may be more important in Hg oxidation chemistry than the fly ash composition. Combustion tests were performed in which Blacksville and PRB fly ashes were injected into filtered (via a baghouse with Teflon bags) flue gas obtained while firing PRB coal in a 35 kW combustor. The Ontario Hydro method was used to determine the Hg speciation after fly ash injection. Wall effects in the combustor complicated interpretation of testing data, although a number of observations could still be made. The amount of Hg collected in the Ontario Hydro impingers was lower than anticipated, and is probably due to sorption of Hg by the fly ash. While firing PRB coal without any ash injection, the percent oxidized Hg in the gas stream was fairly high (average of 63%). The high levels of vapor phase oxidized Hg in these base line tests may be due to catalytic effects from the refractory materials in the combustor. When PRB fly ash was injected into a filtered PRB flue gas stream, the percentage of oxidized Hg in the gas stream decreased dramatically. Decreases in the percentage of oxidized Hg were also observed while injecting Blacksville fly ash, but to a lesser extent. Injecting whole Blacksville fly ash into the filtered PRB flue gas appeared to result in greater concentrations of oxidized Hg relative to the tests where whole PRB fly ash was injected. However, because the Blacksville fly ash has a relatively high surface area, this may be only a surface area effect.

Glenn A. Norton; Hongqun Yang; Robert C. Brown; Dennis L. Laudal; Grant E. Dunham; John Erjavec; Joseph M. Okoh

2002-01-31T23:59:59.000Z

373

Sulfur polymer cement for macroencapsulation of mixed waste debris  

SciTech Connect (OSTI)

In FY 1997, the US DOE Mixed Waste Focus Area (MWFA) sponsored a demonstration of the macroencapsulation of mixed waste debris using sulfur polymer cement (SPC). Two mixed wastes were tested--a D006 waste comprised of sheets of cadmium and a D008/D009 waste comprised of lead pipes and joints contaminated with mercury. The demonstration was successful in rendering these wastes compliant with Land Disposal Restrictions (LDR), thereby eliminating one Mixed Waste Inventory Report (MWIR) waste stream from the national inventory.

Mattus, C.H.

1998-06-01T23:59:59.000Z

374

EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS  

SciTech Connect (OSTI)

Tests were performed in simulated flue gas streams using two fly ash samples from the electrostatic precipitators of two full-scale utility boilers. One fly ash was derived from a Powder River Basin (PRB) coal, while the other was derived from Blacksville coal (Pittsburgh No. 8 seam). The tests were performed at temperatures of 120 and 180 C under different gas compositions using whole fly ash samples as well as magnetic and nonmagnetic concentrates from sized fly ash. Only the Blacksville ash contained magnetic phases. The whole and fractionated fly ash samples were analyzed for morphology, chemical composition, mineralogical composition, total organic carbon, porosity, and surface area. Mineralogically, the Blacksville ash was composed predominantly of magnetite, hematite, quartz, and mullite, while the PRB ash contained mostly quartz with lesser amounts of lime, periclase, and calcium aluminum oxide. The iron oxides in the Blacksville ash were concentrated almost entirely in the largest size fraction. As anticipated, there was not a clean separation of magnetic (Fe-rich) and nonmagnetic (aluminosilicate-rich) phases for the Blacksville ash. The Blacksville ash had a significantly higher surface area and a much higher unburned carbon content than the PRB ash. Elemental mercury (Hg) streams were injected into the simulated flue gas and passed over filters (housed in a convection oven) loaded with fly ash. Concentrations of total, oxidized, and elemental Hg downstream from the ash samples were determined by the Ontario Hydro Method. The gas stream composition and whether or not ash was present in the gas stream were the two most important variables. Based on the statistical analyses, the presence of HCl, NO, NO{sub 2}, and SO{sub 2} and all two-way gas interactions were significant. In addition, it appears that even four-factor interactions between those gases are significant. The HCl, NO{sub 2}, and SO{sub 2} were critical gases resulting in Hg oxidation, while the presence of NO appeared to suppress oxidation. The Blacksville fly ash tended to show slightly more catalytic activity than the PRB fly ash, but this could be largely due to the higher surface area of the Blacksville ash. Temperature was not a statistically important factor. The magnetic (Fe-rich) phases did not appear to be more catalytically active than the nonmagnetic phases, and unburned carbon did not appear to play a critical role in oxidation chemistry.

Unknown

2000-10-01T23:59:59.000Z

375

Corrosion of Metals in Composite Cements Anthony Setiadi*, J. Hill and N. B. Milestone  

E-Print Network [OSTI]

Corrosion of Metals in Composite Cements Anthony Setiadi*, J. Hill and N. B. Milestone. However, there may be issues regarding the corrosion of some of the metal components which arise from reprocessing and decommissioning due to the alkaline environment in the cement grouts. The corrosion

Sheffield, University of

376

Speciation of heavy metals in cement-stabilized waste forms: A micro-spectroscopic study  

E-Print Network [OSTI]

-ray fluorescence (XRF)) were used to investigate Co and Ni uptake by Hardened Cement Paste (HCP) with the aim. For Ni and Co, XRF mapping revealed a highly heterogeneous element distribution as far Elsevier B.V. All rights reserved. Keywords: Cement; Micro-XAS; Micro-XRF mapping; Ni; Co 1. Introduction

377

Carbon 39 (2001) 19952001 Silane-treated carbon fiber for reinforcing cement  

E-Print Network [OSTI]

Carbon 39 (2001) 1995­2001 Silane-treated carbon fiber for reinforcing cement *Yunsheng Xu, D-treated carbon fibers and silane-treated silica fume, relative to the values for cement paste with as-received carbon fibers and as-received silica fume. Silane treatment of fibers and silica fume contributed about

Chung, Deborah D.L.

378

The Effect of Cement Mechanical Properties and Reservoir Compaction on HPHT Well Integrity  

E-Print Network [OSTI]

Cement high- cycle fatigue failure constant B Cement high -cycle fatigue failure constant C Rock internal strength, psi Cr Volumetric solid...-grain compressibility, psi-1 Cbc Volumetric bulk-volume compressibility, psi-1 E Young?s modulus, psi F Critical force, lbf G...

Yuan, Zhaoguang

2012-11-15T23:59:59.000Z

379

Using artificial neural networks to predict the quality and performance of oilfield cements  

SciTech Connect (OSTI)

Inherent batch to batch variability, ageing and contamination are major factors contributing to variability in oilfield cement slurry performance. Of particular concern are problems encountered when a slurry is formulated with one cement sample and used with a batch having different properties. Such variability imposes a heavy burden on performance testing and is often a major factor in operational failure. We describe methods which allow the identification, characterization and prediction of the variability of oilfield cements. Our approach involves predicting cement compositions, particle size distributions and thickening time curves from the diffuse reflectance infrared Fourier transform spectrum of neat cement powders. Predictions make use of artificial neural networks. Slurry formulation thickening times can be predicted with uncertainties of less than {+-}10%. Composition and particle size distributions can be predicted with uncertainties a little greater than measurement error but general trends and differences between cements can be determined reliably. Our research shows that many key cement properties are captured within the Fourier transform infrared spectra of cement powders and can be predicted from these spectra using suitable neural network techniques. Several case studies are given to emphasize the use of these techniques which provide the basis for a valuable quality control tool now finding commercial use in the oilfield.

Coveney, P.V.; Hughes, T.L. [Schlumberger Cambridge Research Ltd., Cambridge (United Kingdom); Fletcher, P. [Schlumberger Dowell, Skene, Aberdeen (United Kingdom)

1996-12-31T23:59:59.000Z

380

Portland cement for SO/sub 2/ control in coal-fired power plants  

DOE Patents [OSTI]

A method is described for removing oxides of sulfur from the emissions of fossil fuel combustion by injecting portland cement into the boiler with the fuel, the combustion air, or downstream with the combustion gases. The cement products that result from this method is also described. 1 tab.

Steinberg, M.

1984-10-17T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Portland cement for SO.sub.2 control in coal-fired power plants  

DOE Patents [OSTI]

There is described a method of removing oxides of sulfur from the emissions of fossil fuel combustion by injecting portland cement into the boiler with the fuel, the combustion air, or downstream with the combustion gases. There is also described the cement products that result from this method.

Steinberg, Meyer (Melville, NY)

1985-01-01T23:59:59.000Z

382

Thermal Energy Storage/Waste Heat Recovery Applications in the Cement Industry  

E-Print Network [OSTI]

, and the Portland Cement Association have studied the potential benefits of using waste heat recovery methods and thermal energy storage systems in the cement manufacturing process. This work was performed under DOE Contract No. EC-77-C-01-50S4. The study has been...

Beshore, D. G.; Jaeger, F. A.; Gartner, E. M.

1979-01-01T23:59:59.000Z

383

Z .Chemical Geology 152 1998 227256 The thermal and cementation histories of a sandstone petroleum  

E-Print Network [OSTI]

Z .Chemical Geology 152 1998 227­256 The thermal and cementation histories of a sandstone petroleum-feldspars recovered at various depths from a deep well drilled through a carbonate-cemented sandstone petroleum of a sandstone petroleum xreservoir, Elk Hills, California. Part 2: In situ oxygen and carbon isotopic results

384

Impact of Hydrated Cement Paste Quality and Entrained Air-Void  

E-Print Network [OSTI]

Impact of Hydrated Cement Paste Quality and Entrained Air-Void System on the Durability of Concrete the characteristics of the entrained air-void system #12;Objectives · Review the current accepted relationship between is affected by the quality of the hydrated cement paste (HCP) and the presence of a properly entrained air

385

14 2010 Proceedings Symposium on Ash in North America GTR-NRS-P-72 SILVICS AND SILVICULTURE OF ASH IN MIXED HARDWOOD  

E-Print Network [OSTI]

IN MIXED HARDWOOD FORESTS OF THE SOUTHERN BOTTOMLANDS AND LOESSIAL HILLS Steve Meadows U.S. Forest Service wet bottomland sites. White ash is the primary ash species in the loessial hills and on other upland sites across the South. The natural range, distribution across site types, and associated forest cover

386

Effects of pulverized coal fly-ash addition as a wet-end filler in papermaking  

SciTech Connect (OSTI)

This experimental study is based on the innovative idea of using pulverized coal fly ash as a wet-end filler in papermaking. This is the first evaluation of the possible use of fly ash in the paper industry. Coal-based thermal power plants throughout the world are generating fly ash as a solid waste product. The constituents of fly ash can be used effectively in papermaking. Fly ash has a wide variation in particle size, which ranges from a few micrometers to one hundred micrometers. Fly ash acts as an inert material in acidic, neutral, and alkaline papermaking processes. Its physical properties such as bulk density (800-980 kg/m{sup 3}), porosity (45%-57%), and surface area (0.138-2.3076 m{sup 2}/g) make it suitable for use as a paper filler. Fly ash obtained from thermal power plants using pulverized coal was fractionated by a vibratory-sieve stack. The fine fraction with a particle size below 38 micrometers was used to study its effect on the important mechanical-strength and optical properties of paper. The effects of fly-ash addition on these properties were compared with those of kaolin clay. Paper opacity was found to be much higher with fly ash as a filler, whereas brightness decreased as the filler percentage increased Mechanical strength properties of the paper samples with fly ash as filler were superior to those with kaolin clay.

Sinha, A.S.K. [SLIET, Longowal (India). Dept. of Chemical Technology

2008-09-15T23:59:59.000Z

387

Idaho Nuclear Technology and Engineering Center (INTEC) (formerly ICPP) ash reutilization study  

SciTech Connect (OSTI)

Since 1984, the coal-fired plant at the Idaho Nuclear Technology and Engineering Center (INTEC, formerly Idaho Chemical Processing Plant) has been generating fly ash at a rate of approximately 1,000 tons per year. This ash is hydrated and placed in an ash bury pit near the coal-fired plant. The existing ash bury pit will be full in less than 1 year at its present rate of use. A conceptual design to build a new ash bury pit was completed, and the new pit is estimated to cost $1.7 million. This report evaluates ash reutilization alternatives that propose to eliminate this waste stream and save the $1.7 million required to build a new pit. The alternatives include using ash for landfill day cover, concrete admixture, flowable fill, soil stabilization, waste remediation, and carbon recovery technology. Both physical and chemical testing, under the guidance of the American Society for Testing and Materials, have been performed on ash from the existing pit and from different steps within the facility`s processes. The test results have been evaluated, compared to commercial ash, and are discussed as they relate to reutilization alternatives. This study recommends that the ash be used in flowable fill concrete for Deactivation and Demolition work at the Idaho National Engineering and Environmental Laboratory.

Langenwalter, T.; Pettet, M.; Ochoa, R.; Jensen, S.

1998-05-01T23:59:59.000Z

388

Ash reduction in clean coal spiral product circuits  

SciTech Connect (OSTI)

The article describes the Derrick Corporation's Stack Sizer{trademark} technology for high capacity fine wet cleaning with long-lasting high open-area urethane screen panels. After field trials, a Stack Sizer fitted with a 100-micron urethane panel is currently processing approximately 40 stph of clean coal spiral product having about 20% ash at McCoy-Elkhorn's Bevin Branch coal preparation plant in Kentucky, USA. Product yield is about 32.5 short tons per hour with 10% ash. The material is then fed to screen bowl centrifuges for further processing. At Blue Diamond Coal's Leatherwood preparation plant similar Stacker Sizers are achieving the same results. 2 figs., 3 tabs., 2 photo.

Brodzik, P.

2007-04-15T23:59:59.000Z

389

Ultrasonic ash/pyrite liberation. Final technical report  

SciTech Connect (OSTI)

The objective of this project was to develop a coal preparation concept which employed ultrasonics to precondition coal prior to conventional or advanced physical beneficiation processes such that ash and pyrite separation were enhanced with improved combustible recovery. Research activities involved a series of experiments that subjected three different test coals, Illinois No. 6, Pittsburgh No. 8, and Upper Freeport, ground to three different size fractions (28 mesh {times} 0, 200 mesh {times} 0, and 325 mesh {times} 0), to a fixed (20 kHz) frequency ultrasonic signal prior to processing by conventional and microbubble flotation. The samples were also processed by conventional and microbubble flotation without ultrasonic pretreatment to establish baseline conditions. Product ash, sulfur and combustible recovery data were determined for both beneficiation processes.

Yungman, B.A.; Buban, K.S.; Stotts, W.F.

1990-06-01T23:59:59.000Z

390

E-Print Network 3.0 - anhydrous portland cements Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Mathematics 32 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: times smaller than those of...

391

Long-term modeling of glass waste in portland cement- and clay-based matrices  

SciTech Connect (OSTI)

A set of ``templates`` was developed for modeling waste glass interactions with cement-based and clay-based matrices. The templates consist of a modified thermodynamic database, and input files for the EQ3/6 reaction path code, containing embedded rate models and compositions for waste glass, cement, and several pozzolanic materials. Significant modifications were made in the thermodynamic data for Th, Pb, Ra, Ba, cement phases, and aqueous silica species. It was found that the cement-containing matrices could increase glass corrosion rates by several orders of magnitude (over matrixless or clay matrix systems), but they also offered the lowest overall solubility for Pb, Ra, Th and U. Addition of pozzolans to cement decreased calculated glass corrosion rates by up to a factor of 30. It is shown that with current modeling capabilities, the ``affinity effect`` cannot be trusted to passivate glass if nuclei are available for precipitation of secondary phases that reduce silica activity.

Stockman, H.W.; Nagy, K.L. [Sandia National Labs., Albuquerque, NM (United States); Morris, C.E. [Wollongong Univ., NSW (Australia). Dept. of Civil and Mining Engineering

1995-12-01T23:59:59.000Z

392

Comparative analysis of the life cycle impact assessment of available cement inventories in the EU  

SciTech Connect (OSTI)

Life cycle impact assessment (LCIA) is one of basic steps in life cycle assessment methodology (LCA). This paper presents a comparative study of the LCIA of different life cycle inventories (LCI) for EU cements. The analysis unit used is the manufacture of 1 kg of cement, from 'cradle to gate'. The impact categories considered are those resulting from the manufacture of cement and include greenhouse effects, acidification, eutrophication and summer and winter smog, amongst others. The results of the study highlighted some inconsistencies in existing inventories. As for the LCIA, the main environmental interventions related to cement manufacture were classified and characterised and their effect on different impact categories analysed. Differences observed in evaluation of the impact of cement type were essentially related to their clinker content.

Josa, Alejandro [Technical University of Catalonia (UPC), School of Civil Engineering (ETSECCPB), C/Jordi Girona 1-3 Modul D2/C1, Barcelona 08034 (Spain)]. E-mail: alejandro.josa@upc.edu; Aguado, Antonio [Technical University of Catalonia (UPC), School of Civil Engineering (ETSECCPB), C/Jordi Girona 1-3 Modul D2/C1, Barcelona 08034 (Spain); Cardim, Arnaldo [Civil Engineering Department, Polytechnic School of Penambuco University, Rua Benfica, 455-Madalena, CEP 50.750-410 (Brazil); Byars, Ewan [Centre for Cement and Concrete, Department of Civil and Structural Engineering, University of Sheffield, Sir Frederick Mappin Building, Mappin Street, Sheffield S1 3JD (United Kingdom)

2007-05-15T23:59:59.000Z

393

The reactions and ashes of thermonuclear explosions on neutron stars  

E-Print Network [OSTI]

This paper reports on the detailed rp-process reaction flow on an accreting neutron star and the resulting ashes of a type I X-ray burst. It is obtained by coupling a 298 isotope reaction network to a self-consistent one-dimensional model calculation with a constant accretion rate of dM/dt=1.0e17g/s (0.09 Eddington).

J. L. Fisker; E. Brown; M. Liebendoerfer; F. -K. Thielemann; M. Wiescher

2004-08-04T23:59:59.000Z

394

Effects of Sediment Containing Coal Ash from the Kingston Ash Release on Embryo-Larval Development in the Fathead Minnow, Pimephales promelas (Rafinesque, 1820)  

SciTech Connect (OSTI)

The largest environmental release of coal ash in U.S. history occurred in December 2008 with the failure of a retention structure at the Tennessee Valley Authority (TVA) Kingston Fossil Plant in East Tennessee. A byproduct of coal-burning power plants, coal ash is enriched in metals and metalloids such as selenium and arsenic with known toxicity to fish including embryonic and larval stages. The effects of contact exposure to sediments containing up to 78 % coal ash from the Kingston spill on the early development of fish embryos and larvae were examined in 7-day laboratory tests with the fathead minnow (Pimephales promelas). No significant effects were observed on hatching success, incidences of gross developmental abnormalities, or embryo-larval survival. Results suggest that direct exposures to sediment containing residual coal ash from the Kingston ash release may not present significant risks to fish eggs and larvae in waterways affected by the spill.

Greeley Jr, Mark Stephen [ORNL] [ORNL; Elmore, Logan R [ORNL] [ORNL; McCracken, Kitty [ORNL] [ORNL; Sherrard, Rick [Tennessee Valley Authority (TVA)] [Tennessee Valley Authority (TVA)

2014-01-01T23:59:59.000Z

395

Modeling the formation and size distribution of fly ash  

SciTech Connect (OSTI)

A set of mathematical models has been developed to predict the size distribution of fly ash particles formed in pulverized coal combustion. The large particle mode of the size distribution, typically centered about 10 to 20 ..mu..m, is predicted by a simple breakup model that is based on the complete coalescence of molten mineral inclusions within fragments of the devolatilized coal char. The ultrafine particle mode, that is typically centered about 0.1 to 0.2 ..mu..m, is modeled in terms of ash volatilization, nucleation, and coagulation. Silica and alumina are reduced to volatile suboxides through reactions at the char surface. The volatile suboxides are transported from the char surface where they are oxidized back to the stable oxides in the bulk gas, and then nucleated in accordance with homogeneous nucleation theory. The ultrafine nuclei coagulate in accordance with Brownian coagulation theory. The predicted particle size spectra have been compared to measured size distributions from a pilot-scale combustor and a full-scale utility boiler. Considering the disproportionate loss of coarse particles in the pilot-scale unit, the agreement between the predicted and measured size distributions was considered reasonably good. Both the predicted ultrafine and large particle modes agreed reasonably well with the measured particle size distribution for the full scale boiler. The validated computer models were used to study the effect of changes in the coal ash content, coal particle size, and the combustion flame temperature.

Dahlin, R.S.

1985-01-01T23:59:59.000Z

396

Oil shale ash-layer thickness and char combustion kinetics  

SciTech Connect (OSTI)

A Hot-Recycled-Solids (HRS) oil shale retort is being studied at Lawrence Livermore National Laboratory. In the HRS process, raw shale is heated by mixing it with burnt retorted shale. Retorted shale is oil shale which has been heated in an oxygen deficient atmosphere to pyrolyze organic carbon, as kerogen into oil, gas, and a nonvolatile carbon rich residue, char. In the HRS retort process, the char in the spent shale is subsequently exposed to an oxygen environment. Some of the char, starting on the outer surface of the shale particle, is burned, liberating heat. In the HRS retort, the endothermic pyrolysis step is supported by heat from the exothermic char combustion step. The rate of char combustion is controlled by three resistances; the resistance of oxygen mass transfer through the gas film surrounding the solid particle, resistance to mass transfer through a ash layer which forms on the outside of the solid particles as the char is oxidized and the resistance due to the intrinsic chemical reaction rate of char and oxygen. In order to estimate the rate of combustion of the char in a typical oil shale particle, each of these resistances must be accurately estimated. We begin by modeling the influence of ash layer thickness on the over all combustion rate of oil shale char. We then present our experimental measurements of the ash layer thickness of oil shale which has been processed in the HRS retort.

Aldis, D.F.; Singleton, M.F.; Watkins, B.E.; Thorsness, C.B.; Cena, R.J.

1992-04-15T23:59:59.000Z

397

Hydration and leaching characteristics of cement pastes made from electroplating sludge  

SciTech Connect (OSTI)

The purpose of this study was to investigate the hydration and leaching characteristics of the pastes of belite-rich cements made from electroplating sludge. The compressive strength of the pastes cured for 1, 3, 7, 28, and 90 days was determined, and the condensation of silicate anions in hydrates was examined with the {sup 29}Si nuclear magnetic resonance (NMR) technology. The leachabilities of the electroplating sludge and the hardened pastes were studied with the multiple toxicity characteristic leaching procedure (MTCLP) and the tank leaching test (NEN 7345), respectively. The results showed that the electroplating sludge continued to leach heavy metals, including nickel, copper, and zinc, and posed a serious threat to the environment. The belite-rich cement made from the electroplating sludge was abundant in hydraulic {beta}-dicalcium silicate, and it performed well with regard to compressive-strength development when properly blended with ordinary Portland cements. The blended cement containing up to 40% the belite-rich cement can still satisfy the compressive-strength requirements of ASTM standards, and the pastes cured for 90 days had comparable compressive strength to an ordinary Portland cement paste. It was also found that the later hydration reaction of the blended cements was relatively more active, and high fractions of belite-rich cement increased the chain length of silicate hydrates. In addition, by converting the sludge into belite-rich cements, the heavy metals became stable in the hardened cement pastes. This study thus indicates a viable alternative approach to dealing with heavy metal bearing wastes, and the resulting products show good compressive strength and heavy-metal stability.

Chen, Ying-Liang [Department of Environmental Engineering, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China); Sustainable Environment Research Center, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China); Ko, Ming-Sheng [Institute of Mineral Resources Engineering, National Taipei University of Technology, No. 1, Sec. 3, Chunghsiao E. Rd., Taipei City 10608, Taiwan (China); Lai, Yi-Chieh [Department of Bioenvironmental Engineering, Chung Yuan Christian University, No. 200, Chung-Pei Rd., Chung-Li 32023, Taiwan (China); Chang, Juu-En, E-mail: juuen@mail.ncku.edu.tw [Department of Environmental Engineering, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China); Sustainable Environment Research Center, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China)

2011-06-15T23:59:59.000Z

398

Dynamic Evolution of Cement Composition and Transport Properties under Conditions Relevant to Geological Carbon Sequestration  

SciTech Connect (OSTI)

Assessing the possibility of CO{sub 2} leakage is one of the major challenges for geological carbon sequestration. Injected CO{sub 2} can react with wellbore cement, which can potentially change cement composition and transport properties. In this work, we develop a reactive transport model based on experimental observations to understand and predict the property evolution of cement in direct contact with CO{sub 2}-saturated brine under diffusion-controlled conditions. The model reproduced the observed zones of portlandite depletion and calcite formation. Cement alteration is initially fast and slows down at later times. This work also quantified the role of initial cement properties, in particular the ratio of the initial portlandite content to porosity (defined here as ?), in determining the evolution of cement properties. Portlandite-rich cement with large ? values results in a localized “sharp” reactive diffusive front characterized by calcite precipitation, leading to significant porosity reduction, which eventually clogs the pore space and prevents further acid penetration. Severe degradation occurs at the cement–brine interface with large ? values. This alteration increases effective permeability by orders of magnitude for fluids that preferentially flow through the degraded zone. The significant porosity decrease in the calcite zone also leads to orders of magnitude decrease in effective permeability, where fluids flow through the low-permeability calcite zone. The developed reactive transport model provides a valuable tool to link cement–CO{sub 2} reactions with the evolution of porosity and permeability. It can be used to quantify and predict long-term wellbore cement behavior and can facilitate the risk assessment associated with geological CO{sub 2} sequestration.

Brunet, Jean-Patrick Leopold; Li, Li; Karpyn, Zuleima T.; Strazisar, Brian; Bromhal Grant

2013-08-01T23:59:59.000Z

399

Acceptable approaches for beneficial use of cement kiln dust  

SciTech Connect (OSTI)

One beneficial use of cement kiln dust (CKD) is application of CKD to cropland as agricultural lime or fertilizer. However, the EPA has expressed a concern over land application of CKD when the metals constituents in the CKD are above the industry-wide median levels presented in EPA`s Report to Congress on Cement Kiln Dust. Under the Clean Water Act, EPA has established limits for metals concentrations in sewage sludge that is applied to the land for beneficial use of the nitrogen in the sludge. The limits for land application of sewage sludge were established based on the results of exposure risk assessments. A comparison of the median industry-wide metals concentrations in CKD to the metals concentration limits for land application of sewage sludge indicates that all trace metal concentrations IN CKD are below the corresponding sewage sludge land application limit, with the exception of the median level of arsenic from one data set. EPA has determined that land application of CKD with metals concentration limits at or below the industry-wide median concentrations does not pose a significant human cancer or non-cancer health risk. Therefore, with appropriate limits, CKD can be beneficially reused for land application on agricultural land in a manner that is protective of human health and the environment.

Schreiber, R.J.; Smeenk, S.D. [Schreiber, Yonley and Associates, St. Louis, MO (United States)

1998-12-31T23:59:59.000Z

400

Synthesis of belite cement clinker of high hydraulic reactivity  

SciTech Connect (OSTI)

This study is concerned with the increase of the cooling rate of belite clinker, by using the water quenching for the chemical stabilization of reactive belite, which improves the hydraulic properties of this clinker. The addition of adequate mineralizers, as NaF and Fe{sub 2}O{sub 3}, contributes to the improvement of the clinker properties obtained at low burning temperature. X-ray fluorescence spectroscopy, X-ray diffraction analysis and optical microscopy were used to determine the chemical and mineralogical compositions of this clinker. The samples were analyzed by means of a scanning electronic microscope connected with an energy-dispersive X-ray spectrometer to detect the composition of the belite phase and its morphology. Physical and mechanical properties of this clinker cement were determined. The results show that the belite clinker obtained at 1150 {sup o}C, with lime saturation factor 0.67, is characterized by a great hydraulic reactivity, similar to that of the ordinary alite clinker. The addition of 2% of NaF and the water quenching improved the chemical, mineralogical and structural properties, while improving the cement hydraulic properties.

Kacimi, Larbi [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)], E-mail: kacimi20002000@yahoo.fr; Simon-Masseron, Angelique [Laboratoire des Materiaux a Porosite Controlee, CNRS UMR 7016, Universite de Haute-Alsace, 3, rue Alfred-Werner, F-68093 Mulhouse cedex (France)], E-mail: A.Simon@univ-mulhouse.fr; Salem, Souria [Departement d'Architecture, Faculte de Genie Civile, USTO-Oran (Algeria)], E-mail: zinaisalem@yahoo.fr; Ghomari, Abdelhamid [Departement de Chimie, U.A.I.B., Route de Belahcel, Mostaganem (Algeria)], E-mail: belkey@hotmail.com; Derriche, Zoubir [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)

2009-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Demonstration of Mixed Waste Debris Macroencapsulation Using Sulfur Polymer Cement  

SciTech Connect (OSTI)

This report covers work performed during FY 1997 as part of the Evaluation of Sulfur Polymer Cement Fast-Track System Project. The project is in support of the ``Mercury Working Group/Mercury Treatment Demonstrations - Oak Ridge`` and is described in technical task plan (TTP) OR-16MW-61. Macroencapsulation is the treatment technology required for debris by the U.S. Environmental Protection Agency Land Disposal Restrictions (LDR) under the Resource Conservation and Recovery Act. Based upon the results of previous work performed at Oak Ridge, the concept of using sulfur polymer cement (SPC) for this purpose was submitted to the Mixed Waste Focus Area (MWFA). Because of the promising properties of the material, the MWFA accepted this Quick Win project, which was to demonstrate the feasibility of macroencapsulation of actual mixed waste debris stored on the Oak Ridge Reservation. The waste acceptance criteria from Envirocare, Utah, were chosen as a standard for the determination of the final waste form produced. During this demonstration, it was shown that SPC was a good candidate for macroencapsulation of mixed waste debris, especially when the debris pieces were dry. The matrix was found to be quite easy to use and, once the optimum operating conditions were identified, very straightforward to replicate for batch treatment. The demonstration was able to render LDR compliant more than 400 kg of mixed wastes stored at the Oak Ridge National Laboratory.

Mattus, C.H.

1998-07-01T23:59:59.000Z

402

Integrated production/use of ultra low-ash coal, premium liquids and clean char  

SciTech Connect (OSTI)

This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

Kruse, C.W.

1991-01-01T23:59:59.000Z

403

Investigation of the potential of fly ash as an adsorbent for removal of priority pollutants  

E-Print Network [OSTI]

billion. Application of the full complement of hazardous waste rules would increase the cost to over $3. 4 billion (EPRI, 1982). It is clear that the handling and disposal of fly ash will be increasingly costly. This cost increase will be compounded.... Several different applications are possible if fly ash shows reasonable adsorption for priority pollutants. For example, fly ash can be used for lining landfills to retard transport of contaminants mto the soil until more permanent disposal solutions...

Zardkoohi, Minoo

1993-01-01T23:59:59.000Z

404

2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus...  

Open Energy Info (EERE)

Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search OpenEI Reference...

405

INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS  

SciTech Connect (OSTI)

This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

2000-11-01T23:59:59.000Z

406

E-Print Network 3.0 - ash corrosion resistant Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 48 Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung* Summary: in improved resistance to...

407

E-Print Network 3.0 - agglomerating ash process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering ; Materials Science 8 Assembly and Testing of an On-Farm Manure to Energy Conversion BMP for Animal Waste Pollution Control Summary: index for animal manure ash...

408

E-Print Network 3.0 - ash fraxinus excelsior Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

we planted green ash trees... Identification of a Biomarker Gene for Fraxinus spp. Darla French and ... Source: Purdue University, Department of Forestry and Natural Resources,...

409

E-Print Network 3.0 - ash quality recycling Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... CANMET Conference on Quality of Concrete Structures and...

410

E-Print Network 3.0 - ash related problems Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the environment is an environmental problem created. It is generally conceded... . The dioxinsfurans on ash then don't seem to create an ... Source: Columbia University -...

411

E-Print Network 3.0 - ash inhalation exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in England and Summary: tests on blocks containing mixed ash. 1 See page 17, Dioxins, what they are, their sources, our exposure... into the potential exposure to dioxins...

412

E-Print Network 3.0 - ash impact sorbent Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for By-Products Utilization Collection: Engineering ; Materials Science 23 Leaching of Dioxins from Municipal Waste Combustor Residues Summary: , and baghouses) including fly ash,...

413

E-Print Network 3.0 - ash metal matrix Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

This list included inorganic metals, since they are known to occur in all ashes, and dioxins... of the best available tools for evaluating whether ... Source: Columbia University...

414

E-Print Network 3.0 - ash management regulations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Air and Waste Management Division U.S. Environmental... unacceptable levels of dioxins and furans. Thus they argue for cradle to grave ash management under Subtitle C......

415

E-Print Network 3.0 - ash particle deposition Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

RDF ASH GEORGE M. SAVAGE AND LUIS F. DIAZ Cal Recovery ... Source: Columbia University - Waste-to-Energy Research and Technology Council (WTERT) Collection: Renewable Energy 36...

416

E-Print Network 3.0 - ash ozonation technology Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ozonation technology Search Powered by Explorit Topic List Advanced Search Sample search results for: ash ozonation technology Page: << < 1 2 3 4 5 > >> 1 Fine volcanic Predicting...

417

Coal deposit characterization by gamma-gamma density/percent dry ash relationships  

E-Print Network [OSTI]

Density/Ash Relationship . APPLICATION OF THE GAMMA-GAMMA DENSITY/PERCENT DRY ASH RELATIONSHIPS The Density/Ash Relationship of a South Texas Lignite Deposit Characterization of a South Texas Lignite Deposit CONCLUSIONS REFERENCES. 52 53 53 53... 58 64 67 6g 80 87 LIST OF TABLES TABLE I Coal Classification by Rank. 2 Common Minerals in Coal. 3 Results of Linear Regression Analyses for a South Texas Lignite Deposit. 4 Variability of Geophysica11y-Derived Percent Dry Ash Values...

Wright, David Scott

1984-01-01T23:59:59.000Z

418

E-Print Network 3.0 - ash forming acid-resistant Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

European Summer Fly Ash Workshop," Warsaw, Poland, June 2005. Department... combustion of coal in conventional and advanced clean-coal technology combustors. These include fly...

419

E-Print Network 3.0 - ash financial aspects Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete, Bangkok, Thailand Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

420

E-Print Network 3.0 - ash separators Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete, Bangkok, Thailand Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

E-Print Network 3.0 - ash flowable fill Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization Summary: ash as filler. A highly flowable concrete is not necessarily self-compacting because SCC should... ;4. Kurita, M., and Nomura, T., "High-Flowable Steel...

422

E-Print Network 3.0 - ash sekitanbai wo Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-sulfurcoal combustionby-products generated by using both conventional and clean coal technologies. A clean coal ash Source: Wisconsin-Milwaukee, University of - Department...

423

E-Print Network 3.0 - ashes analisis espectroquimico Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-sulfurcoal combustionby-products generated by using both conventional and clean coal technologies. A clean coal ash Source: Wisconsin-Milwaukee, University of - Department...

424

E-Print Network 3.0 - ashes oral biotillgaenglighet Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-sulfurcoal combustionby-products generated by using both conventional and clean coal technologies. A clean coal ash Source: Wisconsin-Milwaukee, University of - Department...

425

E-Print Network 3.0 - ash projekt vaendoera Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

generated by using both conventional and clean coal technologies. A clean coal ash Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

426

Characterization of modified calcium-silicate cements exposed to acidic environment  

SciTech Connect (OSTI)

Portland cement which is used as a binder in concrete in the construction industry has been developed into a biomaterial. It is marketed as mineral trioxide aggregate and is used in dentistry. This material has been reported to be very biocompatible and thus its use has diversified. The extended use of this material has led to developments of newer versions with improved physical properties. The aim of this study was to evaluate the effect of acidic environments found in the oral cavity on fast setting calcium silicate cements with improved physical properties using a combination of techniques. Two fast setting calcium silicate cements (CSA and CFA) and two cement composites (CSAG and CFAG) were assessed by subjecting the materials to lactic acid/sodium lactate buffer gel for a period of 28 days. At weekly intervals the materials were viewed under the tandem scanning confocal microscope (TSM), and scanning electron microscope (SEM). The two prototype cements exhibited changes in their internal chemistry with no changes in surface characteristics. Since the changes observed were mostly sub-surface evaluation of surface characteristics of cement may not be sufficient in the determination of chemical changes occurring. - Research Highlights: {yields} An acidic environment affects modified fast setting calcium silicate-based cements. {yields} No surface changes are observed in acidic environment. {yields} An acidic environment causes sub-surface changes in the material chemistry which are only visible in fractured specimens. {yields} A combination of techniques is necessary in order to evaluate the chemical changes occurring.

Camilleri, Josette, E-mail: josette.camilleri@um.edu.mt

2011-01-15T23:59:59.000Z

427

Improved method and composition for immobilization of waste in cement-based material  

DOE Patents [OSTI]

A composition and method for fixation or immobilization of aqueous hazardous waste material in cement-based materials (grout) is disclosed. The amount of drainable water in the cured grout is reduced by the addition of an ionic aluminum compound to either the waste material or the mixture of waste material and dry-solid cement- based material. This reduction in drainable water in the cured grout obviates the need for large, expensive amounts of gelling clays in grout materials and also results in improved consistency and properties of these cement-based waste disposal materials.

Tallent, O.K.; Dodson, K.E.; McDaniel, E.W.

1987-10-01T23:59:59.000Z

428

Characterization and modeling of the cemented sediment surrounding the Iulia Felix glass  

SciTech Connect (OSTI)

About 1800 years ago a Roman Corbita sunk off the coast of Italy carrying a barrel of glass cullet to the floor of the Adriatic Sea. Samples of glass cullet and the cemented surrounding sediment have been characterized and the reaction between the glass and the sea water saturated with respect to calcite and dolomite has been modeled. Results from characterization and modeling show that the cement phase surrounding the sediment grains is a high-Mg calcite. The origin of the cement phase is likely the reaction between the glass and the sea water to from a Mg-silicate, here modeled as sepiolite.

Strachan, Denis M.; Crum, Jarrod V.; Ryan, Joseph V.; Silvestri, Alberta

2014-02-28T23:59:59.000Z

429

Carbon dioxide capture from a cement manufacturing process  

DOE Patents [OSTI]

A process of manufacturing cement clinker is provided in which a clean supply of CO.sub.2 gas may be captured. The process also involves using an open loop conversion of CaO/MgO from a calciner to capture CO.sub.2 from combustion flue gases thereby forming CaCO.sub.3/CaMg(CO.sub.3).sub.2. The CaCO.sub.3/CaMg(CO.sub.3).sub.2 is then returned to the calciner where CO.sub.2 gas is evolved. The evolved CO.sub.2 gas, along with other evolved CO.sub.2 gases from the calciner are removed from the calciner. The reactants (CaO/MgO) are feed to a high temperature calciner for control of the clinker production composition.

Blount, Gerald C. (North Augusta, SC); Falta, Ronald W. (Seneca, SC); Siddall, Alvin A. (Aiken, SC)

2011-07-12T23:59:59.000Z

430

Cement substitution by a combination of metakaolin and limestone  

SciTech Connect (OSTI)

This study investigates the coupled substitution of metakaolin and limestone in Portland cement (PC). The mechanical properties were studied in mortars and the microstructural development in pastes by X-ray diffraction, thermogravimetry analysis, mercury intrusion porosimetry and isothermal calorimetry. We show that 45% of substitution by 30% of metakaolin and 15% of limestone gives better mechanical properties at 7 and 28 days than the 100% PC reference. Our results show that calcium carbonate reacts with alumina from the metakaolin, forming supplementary AFm phases and stabilizing ettringite. Using simple mass balance calculations derived from thermogravimetry results, we also present the thermodynamic simulation for the system, which agrees fairly well with the experimental observations. It is shown that gypsum addition should be carefully balanced when using calcined clays because it considerably influences the early age strength by controlling the very rapid reaction of aluminates.

Antoni, M., E-mail: mathieu.antoni@epfl.ch [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland); Rossen, J. [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)] [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland); Martirena, F. [CIDEM-UCLV, Universidad Las Villas, Santa Clara (Cuba)] [CIDEM-UCLV, Universidad Las Villas, Santa Clara (Cuba); Scrivener, K. [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)] [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)

2012-12-15T23:59:59.000Z

431

In What Form is Lime Present in Portland Cement  

E-Print Network [OSTI]

to obtain Si02.33a0, In his conclusions Hebuffat does not consider it of importance whether alit consists of pure Si02.3CaO or a crystalline compound of Si02.2CaO with 3a0 and an aluminate. He says the aluminate in Portland dement can­ not be Al 203.30a..., Erd- meyer, Nev/berry's, Zulkowski, Rebuff at, Meyers, Richardson, Michaelis and Meade• d. Work of the Carbegie Institute of Washington on CaO #Si0 2 series and binary compounds of Al 2°3> Si0 2, MgO, CaO. On the presence of free lime in cement...

Wright, Claude W.

1910-01-01T23:59:59.000Z

432

Growth and elemental accumulation by canola on soil amended with coal fly ash  

SciTech Connect (OSTI)

To explore the agronomic potential of an Australian coal fly ash, we conducted two glasshouse experiments in which we measured chlorophyll fluorescence, CO{sub 2} assimilation (A), transpiration, stomatal conductance, biomass accumulation, seed yield, and elemental uptake for canola (Brassica napus) grown on soil amended with an alkaline fly ash. In Experiment 1, application of up to 25 Mg/ha of fly ash increased A and plant weight early in the season before flowering and seed yield by up to 21%. However, at larger rates of ash application A, plant growth, chlorophyll concentration, and yield were all reduced. Increases in early vigor and seed yield were associated with enhanced uptake of phosphorus (P) by the plants treated with fly ash. Fly ash application did not influence accumulation of B, Cu, Mo, or Zn in the stems at any stage of plant growth or in the seed at harvest, except Mo concentration, which was elevated in the seed. Accumulation of these elements was mostly in the leaves, where concentrations of Cu and Mo increased with any amount of ash applied while that of B occurred only with ash applied at 625 Mg/ha. In Experiment 2, fly ash applied at 500 Mg/ha and mixed into the whole 30 cm soil core was detrimental to growth and yield of canola, compared with restricting mixing to 5 or 15 cm depth. In contrast, application of ash at 250 Mg/ha with increasing depth of mixing increased A and seed yield. We concluded that fly ash applied at not more than 25 Mg/ha and mixed into the top 10 to 15 cm of soil is sufficient to obtain yield benefits.

Yunusa, I.A.M.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Murray, B.R.; Nissanka, S.P. [University of Technology Sydney, Sydney, NSW (Australia)

2008-05-15T23:59:59.000Z

433

High Carbon Fly Ash Treatment | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in the Madison SymmetricHigh Carbon Fly Ash Treatment

434

Blue Ash, Ohio: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey:form ViewBlackBloomfield,710541°,Ash, Ohio: Energy

435

Experimental study of potential wellbore cement carbonation by various phases of carbon dioxide during geologic carbon sequestration  

SciTech Connect (OSTI)

Hydrated Portland cement was reacted with carbon dioxide (CO2) in supercritical, gaseous, and aqueous phases to understand the potential cement alteration processes along the length of a wellbore, extending from deep CO2 storage reservoir to the shallow subsurface during geologic carbon sequestration. The 3-D X-ray microtomography (XMT) images displayed that the cement alteration was significantly more extensive by CO2-saturated synthetic groundwater than dry or wet supercritical CO2 at high P (10 MPa)-T (50°C) conditions. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis also exhibited a systematic Ca depletion and C enrichment in cement matrix exposed to CO2-saturated groundwater. Integrated XMT, XRD, and SEM-EDS analyses identified the formation of extensive carbonated zone filled with CaCO3(s), as well as the porous degradation front and the outermost silica-rich zone in cement after exposure to CO2-saturated groundwater. The cement alteration by CO2-saturated groundwater for 2-8 months overall decreased the porosity from 31% to 22% and the permeability by an order of magnitude. Cement alteration by dry or wet supercritical CO2 was slow and minor compared to CO2-saturated groundwater. A thin single carbonation zone was formed in cement after exposure to wet supercritical CO2 for 8 months or dry supercritical CO2 for 15 months. Extensive calcite coating was formed on the outside surface of a cement sample after exposure to wet gaseous CO2 for 1-3 months. The chemical-physical characterization of hydrated Portland cement after exposure to various phases of carbon dioxide indicates that the extent of cement carbonation can be significantly heterogeneous depending on CO2 phase present in the wellbore environment. Both experimental and geochemical modeling results suggest that wellbore cement exposure to supercritical, gaseous, and aqueous phases of CO2 during geologic carbon sequestration is unlikely to damage the wellbore integrity because cement alteration by all phases of CO2 is dominated by carbonation reaction. This is consistent with previous field studies of wellbore cement with extensive carbonation after exposure to CO2 for 3 decades. However, XMT imaging indicates that preferential cement alteration by supercritical CO2 or CO2-saturated groundwater can occur along the cement-steel or cement-rock interfaces. This highlights the importance of further investigation of cement degradation along the interfaces of wellbore materials to ensure permanent geologic carbon storage.

Jung, Hun Bok; Um, Wooyong

2013-08-16T23:59:59.000Z

436

Determination of Total Solids and Ash in Algal Biomass: Laboratory Analytical Procedure (LAP)  

SciTech Connect (OSTI)

This procedure describes the methods used to determine the amount of moisture or total solids present in a freeze-dried algal biomass sample, as well as the ash content. A traditional convection oven drying procedure is covered for total solids content, and a dry oxidation method at 575?C is covered for ash content.

Van Wychen, S.; Laurens, L. M. L.

2013-12-01T23:59:59.000Z

437

Measurement of the Optical Proper-ties of Volcanic Ash: Current status.  

E-Print Network [OSTI]

Measurement of the Optical Proper- ties of Volcanic Ash: Current status. Daniel M. Peters and R. G is to allow further assessment of the role of volcanic ash in atmospheric chem- istry, and radiative transfer. Applications of the measurements include: · Radiative transfer from: ­ Scattering solar radiation. ­ Absorption

Oxford, University of

438

Geochemical Constraints on the Origin of a Shallow Ash Occurrence: in the Mahanadi Basin, offshore India  

E-Print Network [OSTI]

Geochemical Constraints on the Origin of a Shallow Ash Occurrence: in the Mahanadi Basin, offshore sampled in the continental margins offshore India (Fig 1). A volcanic ash layer was recovered below seafloor Surrounding Sediments: Grey sediment in A is a nannofossil and plant debris bearing clay

New Hampshire, University of

439

FLY ASH GENERATION AND UTILIZATION -AN OVERVIEW* Tarun R. Naik, Ph.D., P.E.  

E-Print Network [OSTI]

. The Class F fly ashes are normally generated due to combustion of anthracite or bituminous coal. The Class CFLY ASH GENERATION AND UTILIZATION - AN OVERVIEW* By Tarun R. Naik, Ph.D., P.E. Director, Center GENERATION AND UTILIZATION - AN OVERVIEW By Tarun R. Naik, and Shiw S. Singh ABSTRACT This chapter describes

Wisconsin-Milwaukee, University of

440

Emission Control Technology, Performance/Durability -POSTER Effect of Accelerated Ash Loading on Performance of Diesel  

E-Print Network [OSTI]

on Performance of Diesel Particulate Filters and Morphology of Ash Layers Bruce G. Bunting and Todd J. Toops using a single-cylinder diesel engine has been developed for accelerated ash loading in catalyzed and non- catalyzed diesel particular filters (DPF) made of cordierite, SiC and mullite substrate

Pennycook, Steve

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network [OSTI]

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

442

Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1*  

E-Print Network [OSTI]

Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1* , L. S. Fisher1 , J of the potential for carbon sequestration in degraded mine lands, we have found that based on laboratory and field and its influence on carbon sequestration. Also, addition of fly ash to soil, while generally considered

Tiquia-Arashiro, Sonia M.

443

Experimental and numerical analysis of metal leaching from fly ash-amended highway bases  

E-Print Network [OSTI]

road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted vadose zone. Ã? 2011 Elsevier Ltd. All rights reserved. 1. Introduction Over 100 million tons of fly ash

Aydilek, Ahmet

444

E-modulus evolution and its relation to solids formation of pastes from commercial cements  

SciTech Connect (OSTI)

Models for early age E-modulus evolution of cement pastes are available in the literature, but their validation is limited. This paper provides correlated measurements of early age evolution of E-modulus and hydration of pastes from five commercial cements differing in limestone content. A recently developed methodology allowed continuous monitoring of E-modulus from the time of casting. The methodology is a variant of classic resonant frequency methods, which are based on determination of the first resonant frequency of a composite beam containing the material. The hydration kinetics - and thus the rate of formation of solids - was determined using chemical shrinkage measurements. For the cements studied similar relationships between E-modulus and chemical shrinkage were observed for comparable water-to-binder ratio. For commercial cements it is suggested to model the E-modulus evolution based on the amount of binder reacted, instead of the degree of hydration.

Maia, Lino, E-mail: lino.maia@fe.up.pt [LABEST - Laboratory for the Concrete Technology and Structural Behaviour, Faculdade de Engenharia, Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Centro de Ciencias Exatas e da Engenharia, Universidade da Madeira, Campus Universitario da Penteada, 9020-105 Funchal (Portugal); Azenha, Miguel, E-mail: miguel.azenha@civil.uminho.pt [ISISE - Institute for Sustainability and Innovation in Structural Engineering, Universidade do Minho, Escola de Engenharia, Campus de Azurem, 4800-058 Guimaraes (Portugal); Geiker, Mette, E-mail: mge@byg.dtu.dk [DTU - Department of Civil Engineering, Technical University of Denmark, Brovej, Building 118, DK-2800 Kgs. Lyngby (Denmark); NTNU - Department of Structural Engineering, Norwegian University of Science and Technology, Rich. Birkelandsvei 1A, 7491 Trondheim (Norway); Figueiras, Joaquim, E-mail: jafig@fe.up.pt [LABEST - Laboratory for the Concrete Technology and Structural Behaviour, Faculdade de Engenharia, Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal)

2012-07-15T23:59:59.000Z

445

Microsoft Word - NETL-TRS-003-2012_Cementing Research Needs_20121207...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Research Needs Related to Improving Primary Cement Isolation of Formations in Deep Offshore Wells 7 December 2012 Office of Fossil Energy NETL-TRS-3-2012 Disclaimer This report...

446

Effect of spatial variability on the bearing capacity of cement-treated ground  

E-Print Network [OSTI]

This paper presents a reliability assessment for the undrained bearing capacity of a surface strip foundation based on the results of a probabilistic study in which the shear strength and unit weight of cement-treated ...

Kasama, Kiyonobu

447

Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

2 abatement using the calcium looping cycle. Energy Environ.the CO 2 captured by the calcium looping system, use of the16. Flow diagram of calcium-looping CO 2 capture and cement

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

448

Sources of high temperature degradation of cement-based materials : nanoindentation and microporoelastic analysis  

E-Print Network [OSTI]

The effects of high temperature exposure on cement-based materials have been under investigation for quite some time, but a fundamental understanding of the sources of high temperature degradation has been limited by ...

DeJong, Matthew J. (Matthew Justin)

2005-01-01T23:59:59.000Z

449

Synthesis and Characterization of High Temperature Cement-Based Hydroceramic Materials   

E-Print Network [OSTI]

Cement-based materials are of importance in the construction of geothermal wells and high-temperature oil and gas wells. These materials fill the annulus between the well casing and the rock forming a protective layer, ...

Kyritsis, Konstantinos

2009-01-01T23:59:59.000Z

450

Effects of microorganisms growth on the long-term stability of cement and bitumen  

SciTech Connect (OSTI)

Cement is used as a coating matrix for nuclear waste or as an engineered barrier of waste repositories situated in geological formations. The effect of mineral acids excreted by bacteria (Thiobacillus) or organic acids produced by fungi, on the biodegradation of cement is discussed. Organic acids are quantitatively and qualitatively determined during growth of fungi over a two-year period. Even with high pH conditions, pH of the cement {approx} 11, growth of microorganisms occurs. Biodeterioration of cement is expressed in terms of bioleaching velocity of calcium and is observed by electron microscopy. Bitumen is commonly used as a matrix for the long-term storage of radioactive wastes. Long-term biodegrability of bitumen is discussed as a function of its chemical composition and various studied microorganisms.

Libert, M.F.; Sellier, R.; Jouquet, G.; Trescinski, M.; Spor, H. [Nuclear Research Center of Cadarache, St.Paul-Lez-Durance (France)

1993-12-31T23:59:59.000Z

451

Lattice Boltzmann simulations of the permeability and capillary adsorption of cement model microstructures  

SciTech Connect (OSTI)

The lattice Boltzmann method is used to investigate the permeability of microstructures of cement pastes generated using the numerical models CEMHYD3D (Bentz, 1997) and {mu}IC (Bishnoi and Scrivener, 2009). Results are reported as a function of paste water-to-cement ratio and degree of hydration. The permeability decreases with increasing hydration and decreasing water-to-cement ratio in agreement with experiment. However the permeability is larger than the experimental data recorded using beam bending methods (Vichit-Vadakan and Scherer, 2002). Notwithstanding, the lattice Boltzmann results compare favourably with alternate numerical methods of permeability calculation for cement model microstructures. In addition, we show early results for the liquid/vapour capillary adsorption and desorption isotherms in the same model {mu}IC structures. The broad features of the experimental capillary porosity isotherm are reproduced, although further work is required to adequately parameterise the model.

Zalzale, M. [Laboratory of Construction Materials, Ecole Polytechnique Federale de Lausanne, CH-1015 Lausanne (Switzerland)] [Laboratory of Construction Materials, Ecole Polytechnique Federale de Lausanne, CH-1015 Lausanne (Switzerland); McDonald, P.J., E-mail: p.mcdonald@surrey.ac.uk [Department of Physics, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)

2012-12-15T23:59:59.000Z

452

E-Print Network 3.0 - antibiotic-loaded cement spacers Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in this study. Sealed Reference Sample Sample Cement Paste 10 mm 10 mm 11.5mm 8mm Plastic Spacers 5 mm... based on Stokes equation actually suggests that some of the...

453

Portland cement mortar modified with latex and fiber glass for thin shell construction  

E-Print Network [OSTI]

and materials required for the elaborate formwork. Building codes are also in need of revision to include provisions for thin shell construction. The objective of this study was to investigate the possible potential use of portland cement mortar modified...

Raymond, Jewell Duane

1963-01-01T23:59:59.000Z

454

Assessment of durability performance of "Early-Opening-to-Traffic" Portland Cement Concrete pavement and patches  

E-Print Network [OSTI]

This study relates the assessment of durability to ''early-opening-to-traffic'' (EOT) portland cement concrete (PCC). Several factors were identified relative to the performance of EOT PCC. Each of these factors was considered in terms of freeze...

Shrestha, Pradhumna Babu

1999-01-01T23:59:59.000Z

455

Detecting and modeling cement failure in high pressure/ high temperature wells using finite-element method  

E-Print Network [OSTI]

conditions and are investigated simultaneously to more accurately predict cement failure. The results of this study show the relevant dependency of stress principles with temperature and pressure. These results clarify the deformation caused by any...

Shahri, Mehdi Abbaszadeh

2006-04-12T23:59:59.000Z

456

Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

Hilger, J. 2003. Combined Utilization of Oil Shale Energyand Oil Shale Minerals within the Production of Cement andOther Hydraulic Minerals. Oil Shale, Vol. 20, No. 3, pp.

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

457

Grinding of cement clinkers : linking multi-scale fracture properties to system chemistry, mineralogy and microstructure  

E-Print Network [OSTI]

Growing environmental concerns encourage the cement industry to improve its environmental performance, which in turn renews the interest in clinker grinding efficiency. Current knowledge on clinker grinding was built over ...

Wilson, William, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

458

Non-Linear Drying Diffusion and Viscoelastic Drying Shrinkage Modeling in Hardened Cement Pastes  

E-Print Network [OSTI]

modeling with an average diffusion coefficient and with determined viscoelastic parameters from creep tests agreed well compared to the shrinkage data from experiments, indicating that drying shrinkage of cement paste may be considered as a poroviscoelastic...

Leung, Chin K.

2010-07-14T23:59:59.000Z

459

Microsoft Word - NETL-TRS-2-2014_Addendum 1 to Foamed Cement...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Addendum 1 to Computed Tomography and Statistical Analysis of Bubble Size Distributions in Atmospheric-Generated Foamed Cement 6 March 2014 Office of Fossil Energy NETL-TRS-2-2014...

460

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

Potential (GWh) CO2 Emission Reduction Potential (kt CO 2 )Fuel Savings (TJ) CO2 Emission Reduction Potential (kt COPotentials and CO2 Emission Reductions in 16 Studied Cement

Price, Lynn

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

Energy Savings and CO2 Emissions Reduction of China’s CementEnergy Savings and CO2 Emissions Reduction of China’s Cementenergy savings and CO2 emission reduction potentials are

Ke, Jing

2013-01-01T23:59:59.000Z

462

Effects of composition and exposure on the solar reflectance of Portland cement concrete  

SciTech Connect (OSTI)

Increasing the solar reflectance (albedo) of a paved surface keeps it cooler in the sun, reducing convection of heat from pavement to air and thereby decreasing the ambient air temperature. Simulations of the influence of pavement albedo on air temperature in Los Angeles predict that increasing the albedo of 1,250 km2 of pavement by 0.25 would save cooling energy worth $15M yr-1, and reduce smog-related medical and lost-work expenses by $76M yr-1. Most sidewalks and a small fraction of roads and parking areas are paved with portland cement concrete, which can be made quite reflective through suitable choice of cement and aggregate. Variations with composition and environmental exposure of the albedos of portland cement concrete pavements were investigated through laboratory fabrication and exposure of 32 mixes of concrete. Twenty-four mixes yielded substandard, ''rough'' concretes due to high, unmet aggregate water demand. The albedos of the remaining eight ''smooth'' concrete mixes ranged from 0.41 to 0.77 (mean 0.59). Simulated weathering, soiling, and abrasion each reduced average concrete albedo (mean decreases 0.06, 0.05, and 0.19, respectively), though some samples became slightly more reflective through weathering or soiling. Simulated rain (wetting) strongly depressed the albedos of concretes (mean decrease 0.23) until their surfaces were dried. Concrete albedo grew as the cement hydration reaction progressed (mean increase 0.08), but stabilized within six weeks of casting. White-cement concretes were on average significantly more reflective than gray-cement concretes. The albedo of the most-reflective white-cement concrete was 0.18 to 0.39 higher than that of the most-reflective gray-cement concrete, depending on state of exposure. Concrete albedo generally correlated with cement albedo and sand albedo, and, after abrasion, with rock albedo. Cement albedo had a disproportionately strong influence on the reflectance of concrete. Efflorescence and surface carbonation whitened some gray-cement mixes.

Levinson, Ronnen; Akbari, Hashem

2001-12-21T23:59:59.000Z

463

Ash, calcium, phosphorus and magnesium content of the metacarpus of hereford cows under different nutritional and physiological conditions  

E-Print Network [OSTI]

ASH, CALCIUM, PHOSPHORUS AND MAGNESIUM CONTENT OF THE METACARPUS OF HEREFORD COWS UNDER DIFFERENT NUTRITIONAL AND PHYSIOLOGICAL CONDITIONS A Thesis By MOZAMMEL HAQUE Submitted to the Graduate College of the Texas A&M University in partial... centages of Calcium, Phosphorus snd Magnesium in Bone Ash for Cows Gi;en Different Treatments During Pre- And Post-Partum Periods 22 10 Analysis of Variance oi Calcium in Bone Ash Dun an's )tultiple tvange Test 1'or Calcium in Bone Ash. Analy...

Haque, Mozammel

2012-06-07T23:59:59.000Z

464

Evaluation of rice husk ash as filler in tread compounds  

SciTech Connect (OSTI)

Rice which is one of the largest agriculture crops produces around 22% of rice rusk during its milling process. This material is mainly used as fuel for energy generation, which results in an ash, which disposal represents an environmental issue. The rice husk ash (RHA) contains over than 70% of silica in an amorphous form and a lot of applications is being developed for it all over the world. The use of silica as a filler in the tire industry is growing since it contributes significantly to the reduction of fuel consumption of the automobiles, allowing at the same time better traction (safety). This paper presents an evaluation of the use of RHA as filler in rubber tread compounds prepared in lab scale and compares its performance with compounds prepared with commercial silica and carbon black, the fillers normally used in tire industry. Mechanical and rheological properties are evaluated, with emphasis for tan delta as an indicator of tread performance related with rolling resistance (fuel consumption) and wet grip/traction (safety)

Fernandes, M. R. S., E-mail: monica.fernandes@lanxess.com [Lanxess Elastômeros do Brasil S.A., Brasil and Instituto de Química, Universidade do Estado do Rio de Janeiro (UERJ) (Brazil); Furtado, C. R. G., E-mail: russi@globo.com, E-mail: ana.furtado.sousa@gmail.com; Sousa, A. M. F. de, E-mail: russi@globo.com, E-mail: ana.furtado.sousa@gmail.com [Instituto de Química, Universidade do Estado do Rio de Janeiro (UERJ) (Brazil)

2014-05-15T23:59:59.000Z

465

In situ analysis of ash deposits from black liquor combustion  

SciTech Connect (OSTI)

Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

1996-05-01T23:59:59.000Z

466

488-D Ash Basin Vegetative Cover Treatibility Study  

SciTech Connect (OSTI)

The 488-D Ash Basin is an unlined containment basin that received ash and coal reject material from the operation of a powerhouse at the USDOE's Savannah River Site, SC. They pyretic nature of the coal rejects has resulted in the formation of acidic drainage (AD), which has contributed to groundwater deterioration and threatens biota in down gradient wetlands. Establishment of a vegetative cover was examined as a remedial alternative for reducing AD generation within this system by enhanced utilization of rainwater and subsequent non-point source water pollution control. The low nutrient content, high acidity, and high salinity of the basin material, however, was deleterious to plant survivability. As such, studies to identify suitable plant species and potential adaptations, and pretreatment techniques in the form of amendments, tilling, and/or chemical stabilization were needed. A randomized block design consisting of three subsurface treatments (blocks) and five duplicated surface amendments (treatments) was developed. One hundred inoculated pine trees were planted on each plot. Herbaceous species were also planted on half of the plots in duplicated 1-m2 beds. After two growing seasons, deep ripping, subsurface amendments and surface covers were shown to be essential for the successful establishment of vegetation on the basin. This is the final report of the study.

Barton, Christopher; Marx, Don; Blake, John; Adriano, Domy; Koo, Bon-Jun; Czapka, Stephen

2003-01-01T23:59:59.000Z

467

Submicron carbon filament cement-matrix composites for electromagnetic interference shielding  

SciTech Connect (OSTI)

Carbon filaments of diameter 0.1 mm were found to be a much more effective additive than conventional carbon fibers of diameter 10 mm in providing cement pastes capable of electromagnetic interference shielding. With 0.54 vol. % filaments and a shield thickness of 4 mm, a shielding effectiveness of 30 dB was attained at 1--2 GHz. However, the filaments were less effective than the fibers for reinforcing and for providing strain sensing cement-matrix composites.

Fu, X.; Chung, D.D.L. [State Univ. of New York, Buffalo, NY (United States). Composite Materials Research Lab.] [State Univ. of New York, Buffalo, NY (United States). Composite Materials Research Lab.

1996-10-01T23:59:59.000Z

468

The physical and chemical aspects of the leaching behavior of metals from portland cement  

E-Print Network [OSTI]

THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1990 Major Subject: Chemistry THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Approved as to style and content by: David L. Cocke (Co...

Davis, Ricardo Corye

1990-01-01T23:59:59.000Z

469

Determining the effective diffusivity of ions in hazardous wastes solidified by portland cement  

E-Print Network [OSTI]

DETERMINING THE EFFECTIVE DIFFUSIVITY OF TONS IN HAZARDOUS WASTES SOLIDIFIED BY PORTLAND CEMENT A Thesis by GLEN GREGORY TAFFINDER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Civil Engineering DETERMINING THE EFFECTIVE DIFFUSIVITY OF TONS IN HAZARDOUS WASTES SOLIDIFIED BY PORTLAND CEMENT A Thesis by GLEN GREGORY TAFFINDER Approved as to scyle and content by: Bill...

Taffinder, Glen Gregory

1991-01-01T23:59:59.000Z

470

Preliminary non-destructive assessment of moisture content, hydration and dielectric properties of Portland cement concrete  

E-Print Network [OSTI]

PRELIMINARY NON-DESTRUCTIVE ASSESSMENT OF MOISTURE CONTENT, HYDRATION AND DIELECTRIC PROPERTIES OF PORTLAND CEMENT CONCRETE A Thesis by IVAN AVELAR LEZAMA Submitted to the Office of Graduate Studies of Texas A... AND DIELECTRIC PROPERTIES OF PORTLAND CEMENT CONCRETE A Thesis by IVAN AVELAR LEZAMA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

Avelar Lezama, Ivan

2007-04-25T23:59:59.000Z

471

The use of Devonian oil shales in the production of portland cement  

SciTech Connect (OSTI)

The Lafarge Corporation operates a cement plant at Alpena, Michigan in which Antrim shale, a Devonian oil shale, is used as part of the raw material mix. Using this precedent the authors examine the conditions and extent to which spent shale might be utilized in cement production. They conclude that the potential is limited in size and location but could provide substantial benefit to an oil shale operation meeting these criteria.

Schultz, C.W.; Lamont, W.E. [Alabama Univ., University, AL (United States); Daniel, J. [Lafarge Corp., Alpena, MI (United States)

1991-12-31T23:59:59.000Z

472

pH-dependent leaching of dump coal ash - retrospective environmental analysis  

SciTech Connect (OSTI)

Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

2009-07-01T23:59:59.000Z

473

Percutaneous Extraction of Cement Leakage After Vertebroplasty Under CT and Fluoroscopy Guidance: A New Technique  

SciTech Connect (OSTI)

Purpose: We report a new minimally invasive technique of extraction of cement leakage following percutaneous vertebroplasty in adults. Methods: Seven adult patients (five women, two men; mean age: 81 years) treated for vertebral compression fractures by percutaneous vertebroplasty had cement leakage into perivertebral soft tissues along the needle route. Immediately after vertebroplasty, the procedure of extraction was performed under computed tomography (CT) and fluoroscopy guidance: a Chiba needle was first inserted using the same route as the vertebroplasty until contact was obtained with the cement fragment. This needle was then used as a guide for an 11-gauge Trocar t'am (Thiebaud, France). After needle withdrawal, a 13-gauge endoscopy clamp was inserted through the cannula to extract the cement fragments. The whole procedure was performed under local anesthesia. Results: In each patient, all cement fragments were withdrawn within 10 min, without complication. Conclusions: This report suggests that this CT- and fluoroscopy-guided percutaneous technique of extraction could reduce the rate of cement leakage-related complications.

Amoretti, Nicolas, E-mail: amorettinicolas@yahoo.fr; Huwart, Laurent, E-mail: huwart.laurent@wanadoo.fr [Centre Hospitalo-Universitaire de Nice, Department of Radiology (France)

2012-12-15T23:59:59.000Z

474

Metal Bioavailability and Speciation in a Wetland Tailings Repository Amended with Biosolids Compost, Wood Ash, and Sulfate  

E-Print Network [OSTI]

Compost, Wood Ash, and Sulfate Pam S. DeVolder, Sally L. Brown,* Dean Hesterberg, and Kumi Pandya ABSTRACT tundra swans surface amendments: (i) biosolids compost plus wood ash, (ii) and other animals found in the area have tested positive compost wood ash a low SO2 4 addition as K2SO4, and (iii) for Pb poisoning

Brown, Sally

475

Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung*  

E-Print Network [OSTI]

Use of fly ash as an admixture for electromagnetic interference shielding Jingyao Cao, D.D.L. Chung The use of fly ash as an admixture results in enhancement of the electromagnetic interference (EMI of fly ash as an admixture for enhancing the electromagnetic interference (EMI) shielding. EMI shielding

Chung, Deborah D.L.

476

Journal of Hazardous Materials B132 (2006) 244252 Zeolite synthesis from paper sludge ash at low temperature  

E-Print Network [OSTI]

Journal of Hazardous Materials B132 (2006) 244­252 Zeolite synthesis from paper sludge ash at low 2005 Available online 4 November 2005 Abstract Paper sludge ash was partially converted into zeolites by reaction with 3 M NaOH solution at 90 C for 24 h. The paper sludge ash had a low abundance of Si

Downs, Robert T.

2006-01-01T23:59:59.000Z

477

J. Marshall Ash Proceedings of the American Mathematical Society, Vol. 108, No. 2. (Feb., 1990), p. 571.  

E-Print Network [OSTI]

Erratum J. Marshall Ash Proceedings of the American Mathematical Society, Vol. 108, No. 2. (Feb, February 1990 ERRATUM J. MARSHALL ASH The paper "A new proof of uniqueness for multiple trigonometric series" by J. Marshall Ash, which appeared in 107(2) October 1989, should have been entitled "A new proof

Ash, J. Marshall

478

Effects of curing temperature and NaOH addition on hydration and strength development of clinker-free CKD-fly ash binders  

SciTech Connect (OSTI)

Effects of curing temperature and NaOH addition on hydration and strength development of cement kiln dust (CKD)-fly ash (FA) binders were investigated. Pastes made with 50% CKD and 50% FA, having 0, 2, and 5% NaOH addition, and cured at temperatures of 24, 38, and 50 deg. C were evaluated. The hydration products of the binders were examined by thermogravimetric analysis (TGA) and X-ray diffraction (XRD) tests. The results indicate that the major crystalline hydration product of the CKD-FA binders is ettringite, and the ettringite is stable in the CKD-FA system at age over 100 days. Curing at elevated temperature is more effective for CKD-FA binder strength improvement than NaOH addition, the later often depressing ettringite formation in a CKD-FA system. At a proper curing temperature (38 deg. C), addition of a small amount of NaOH (2%) may increase CKD-FA binder strength; while at a high curing temperature (50 deg. C), addition of NaOH (2%) may reduce the binder strength.

Wang Kejin; Shah, Surendra P.; Mishulovich, Alexander

2004-02-01T23:59:59.000Z

479

Evaluating the Effects of the Kingston Fly Ash Release on Fish Reproduction: Spring 2009 - 2010 Studies  

SciTech Connect (OSTI)

On December 22, 2008, a dike containing fly ash and bottom ash at the Tennessee Valley Authority's (TVA) Kingston Fossil Plant in East Tennessee failed and released a large quantity of ash into the adjacent Emory River. Ash deposits from the spill extended 4 miles upstream of the facility to Emory River mile 6 and downstream to Tennessee River mile 564 ({approx}8.5 miles downstream of the confluence of the Emory River with the Clinch River, and {approx}4 miles downstream of the confluence of the Clinch River with the Tennessee River). A byproduct of coal combustion, fly ash contains a variety of metals and other elements which, at sufficient concentrations and in specific forms, can be harmful to biological systems. The ecological effects of fly ash contamination on exposed fish populations depend on the magnitude and duration of exposure, with the most significant risk considered to come from elevated levels of certain metals in the ash, particularly selenium, on fish reproduction and fish early life stages (Lemly 1993; Besser and others 1996). The ovaries of adult female fish in a lake contaminated by coal ash were reported to have an increased frequency of atretic oocytes (dead or damaged immature eggs) and reductions in the overall numbers of developing oocytes (Sorensen 1988) associated with elevated body burdens of selenium. Larval fish exposed to selenium through maternal transfer of contaminants to developing eggs in either contaminated bodies of water (Lemly 1999) or in experimental laboratory exposures (Woock and others 1987, Jezierska and others 2009) have significantly increased incidences of developmental abnormalities. Contact of fertilized eggs and developing embryos to ash in water and sediments may also pose an additional risk to the early life stages of exposed fish populations through direct uptake of metals and other ash constituents (Jezierska and others 2009). The establishment and maintenance of fish populations is intimately associated with the ability of individuals within a population to reproduce. Reproduction is thus generally considered to be the most critical life function affected by environmental contamination. From a regulatory perspective, the issue of potential contaminant-related effects on fish reproduction from the Kingston fly ash spill has particular significance because the growth and propagation of fish and other aquatic life is a specific classified use of the affected river systems. To address the potential effects of fly ash from the Kingston spill on the reproductive health of exposed fish populations, ORNL has undertaken a series of studies in collaboration with TVA that include: (1) a combined field study of metal bioaccumulation in ovaries and other fish tissues (Adams and others 2012) and the reproductive condition of sentinel fish species in reaches of the Emory and Clinch Rivers affected by the fly ash spill (the current report); (2) laboratory tests of the potential toxicity of fly ash from the spill area on fish embryonic and larval development (Greeley and others 2012); (3) additional laboratory experimentation focused on the potential effects of long-term exposures to fly ash on fish survival and reproductive competence (unpublished); and (4) a combined field and laboratory study examining the in vitro developmental success of embryos and larvae obtained from fish exposed in vivo for over two years to fly ash in the Emory and Clinch Rivers (unpublished). The current report focuses on the reproductive condition of adult female fish in reaches of the Emory and Clinch Rivers influenced by the fly ash spill at the beginning of the spring 2009 breeding season - the first breeding season immediately following the fly ash release - and during the subsequent spring 2010 breeding season. Data generated from this and related reproductive/early life stage studies provide direct input to ecological risk assessment efforts and complement and support other phases of the overall biomonitoring program associated with the fly ash spill.

Greeley Jr, Mark Stephen [ORNL; Adams, Marshall [ORNL; McCracken, Kitty [ORNL

2012-05-01T23:59:59.000Z

480

Energy efficiency and carbon dioxide emissions reduction opportunities in the U.S. cement industry  

SciTech Connect (OSTI)

This paper reports on an in-depth analysis of the U.S. cement industry, identifying cost-effective energy efficiency measures and potentials. The authors assess this industry at the aggregate level (Standard Industrial Classification 324), which includes establishments engaged in manufacturing hydraulic cements, including Portland, natural, masonry, and pozzolana when reviewing industry trends and when making international comparisons. Coal and coke are currently the primary fuels for the sector, supplanting the dominance of natural gas in the 1970s. Between 1970 and 1997, primary physical energy intensity for cement production (SIC 324) dropped 30%,from 7.9 GJ/t to 5.6 GJ/t, while carbon dioxide intensity due to fuel consumption (carbon dioxide emissions expressed in tons of carbon per ton cement) dropped 25%, from 0.16 tC/ton to 0.12 tC/ton. Carbon dioxide intensity due to fuel consumption and clinker calcination dropped 17%, from 0.29 tC/ton to 0.24 tC/ton. They examined 30 energy efficient technologies and measures and estimated energy savings, carbon dioxide savings, investment costs, and operation and maintenance costs for each of the measures. They constructed an energy conservation supply curve for U.S. cement industry which found a total cost-effective reduction of 0.6 GJ/ton of cement consisting of measures having a simple payback period of 3 years or less. This is equivalent to potential energy savings of 11% of 1994 energy use for cement making and a savings of 5% of total 1994 carbon dioxide emissions by the U.S. cement industry. Assuming the increased production of blended cement in the U.S., as is common in many parts of the world, the technical potential for energy efficiency improvement would not change considerably. However, the cost-effective potential, would increase to 1.1 GJ/ton cement or 18% of total energy use, and carbon dioxide emissions would be reduced by 16%.

Martin, Nathan; Worrell, Ernst; Price, Lynn

1999-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "ash grove cement" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

JV Task 120 - Coal Ash Resources Research Consortium Research  

SciTech Connect (OSTI)

The Coal Ash Resources Research Consortium{reg_sign} (CARRC{reg_sign}, pronounced 'cars') is the core coal combustion product (CCP) research group at the Energy & Environmental Research Center (EERC). CARRC focuses on performing fundamental and applied scientific and engineering research emphasizing the environmentally safe, economical use of CCPs. CARRC member organizations, which include utilities and marketers, are key to developing industry-driven research in the area of CCP utilization and ensuring its successful application. The U.S. Department of Energy is a partner in CARRC through the EERC Jointly Sponsored Research Program, which provides matching funds for industrial member contributions and facilitates an increased level of effort in CARRC. CARRC tasks were designed to provide information on CCP performance, including environmental performance, engineering performance, favorable economics, and improved life cycle of products and projects. CARRC technical research tasks are developed based on member input and prioritization. CARRC special projects are developed with members and nonmembers to provide similar information and to support activities, including the assembly and interpretation of data, support for standards development and technology transfer, and facilitating product development and testing. CARRC activities from 2007 to 2009 included a range of research tasks, with primary work performed in laboratory tasks developed to answer specific questions or evaluate important fundamental properties of CCPs. The tasks were included in four categories: (1) Environmental Evaluations of CCPs; (2) Evaluation of Impacts on CCPs from Emission Controls; (3) Construction and Product-Related Activities; and (4) Technology Transfer and Maintenance Tasks. All tasks are designed to work toward achieving the CARRC overall goal and supporting objectives. The various tasks are coordinated in order to provide broad and useful technical data for CARRC members. Special projects provide an opportunity for non-CARRC members to sponsor specific research or technology transfer consistent with CARRC goals. This report covers CARRC activities from January 2007 through March 2009. These activities have been reported in CARRC Annual Reports and in member meetings over the past 2 years. CARRC continues to work with industry and various government agencies with its research, development, demonstration, and promotional activities nearing completion at the time of submission of this report. CARRC expects to continue its service to the coal ash industry in 2009 and beyond to work toward the common goal of advancing coal ash utilization by solving CCP-related technical issues and promoting the environmentally safe, technically sound, and economically viable management of these complex and changing materials.

Debra Pflughoeft-Hassett; Loreal Heebink; David Hassett; Bruce Dockter; Kurt Eylands; Tera Buckley; Erick Zacher

2009-03-28T23:59:59.000Z

482

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures  

DOE Patents [OSTI]

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated.

Khan, M. Rashid (Morgantown, WV)

1990-01-01T23:59:59.000Z

483

E-Print Network 3.0 - air entraining cement Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

15 By-Products Utilization Summary: was carried out to utilize wood ash in making self- compacting controlled low-strength materials (CLSM), air-entrained... and non-air-...

484

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Cement Industry in China  

E-Print Network [OSTI]

Wang, L. , 2008. Alternative fuel using and waste materialPolicy Research on Alternative Fuels for Cement Industry inis very little use of alternative fuels (defined as waste

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

485

Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Cement Sector  

E-Print Network [OSTI]

Advanced Concepts of Waste Heat Recovery in Cement Plants”building controls, waste heat recovery or adjustable speedquantities of low grade waste heat from the kilns or clinker

Sathaye, J.

2011-01-01T23:59:59.000Z

486

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents [OSTI]

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas for further combustion in modified oil or gas fired furnaces or boilers. Two concentric shells define a combustion volume within the inner shell and a plenum between them through which combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, Albert H. (Huntington, NY)

1983-10-04T23:59:59.000Z

487

Investigation of Fly Ash and Activated Carbon Obtained from Pulverized Coal Boilers  

SciTech Connect (OSTI)

One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addressed the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addressed the possible connection between SCR reactors, fly ash properties and Hg capture. The project has determined the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed have also been determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control have been analyzed in an effort to determine the effects of SCR on the ash.

Edward K. Levy; Christopher Kiely; Zheng Yao

2006-08-31T23:59:59.000Z

488

Scale-Up and Demonstration of Fly Ash Oxonation Technology  

SciTech Connect (OSTI)

This is the fifth quarterly report under DOE Cooperative Agreement No.: DE-FC26-03NT41730. Due a number of circumstances, mostly associated with subcontractor agreements, the actual beginning of the project was delayed from its original award date of March 5, 2003. DOE's Project Manager was kept informed (verbally) by PPL's Project Manager throughout this period. Because of this delay, this is the fifth quarterly report and it refers to the time period from April-July 2005. (An additional month is included in this quarterly report as we have been in a data analyses mode and wanted to provide new data relative to the previous report). During this period, the project team has been reviewing and analyzing data from the onsite ozonation tests, as well as conducting additional laboratory ash and concrete tests. This report summarizes these activities including some preliminary results. No significant issues or concerns are identified.

Larry LaBuz; Rui Afonso

2005-06-30T23:59:59.000Z

489

Management of sewage sludge and ash containing radioactive materials.  

SciTech Connect (OSTI)

Approximately 50% of the seven to eight million metric tonnes of municipal sewage sludge produced annually in the US is reused. Beneficial uses of sewage sludge include agricultural land application, land reclamation, forestry, and various commercial applications. Excessive levels of contaminants, however, can limit the potential usefulness of land-applied sewage sludge. A recently completed study by a federal inter-agency committee has identified radioactive contaminants that could interfere with the safe reuse of sewage sludge. The study found that typical levels of radioactive materials in most municipal sewage sludge and incinerator ash do not present a health hazard to sewage treatment plant workers or to the general public. The inter-agency committee has developed recommendations for operators of sewage treatment plants for evaluating measured or estimated levels of radioactive material in sewage sludge and for determining whether actions to reduce potential exposures are appropriate.

Bachmaier, J. T.; Aiello, K.; Bastian, R. K.; Cheng, J.-J.; Chiu, W. A.; Goodman, J.; Hogan, R.; Jones, A. R.; Kamboj, S.; Lenhart, T.; Ott, W. R.; Rubin, A. B.; Salomon, S. N.; Schmidt, D. W.; Setlow, L. W.; Yu, C.; Wolbarst, A. B.; Environmental Science Division; Middlesex County Utilities Authority; U.S. EPA; N.J. Dept of Environmental Protection; NRC

2007-01-01T23:59:59.000Z

490

Energy efficiency for greenhouse gas emission reduction in China: The case of the cement industry  

SciTech Connect (OSTI)

A project at LBNL has combined two different approaches to investigate changes in efficiency in China`s cement industry, which currently accounts for over 6% of China`s total commercial energy use and over 1% of global carbon emissions. Cement output has doubled over the past five years, and will double again within 15 years. Addressing cement industry carbon emissions will be a key element of any program to control China`s carbon emissions. Macro-level analysis was used to investigate industry-wide trends, and detailed case studies of individual plants illuminated key issues in technology choice that fundamentally affect efficiency. In general, enterprises adopted technologies that increased output and improved quality, and had little regard for energy efficiency, though most new technologies and practices did improve efficiency. Changes in energy prices were a surprisingly weak factor in adoption of efficient technologies. Unexpectedly, many enterprises developed a strong preference for the least fuel-efficient technology, which allows power generation with kiln waste heat. This preference was motivated in a large part by the desire to achieve security in electricity supply, and by some reforms. This alternative has become increasingly popular, and threatens to reverse some progress made in reducing the carbon-intensiveness of China`s cement industry. Foreign technical assistance and more importantly, greater participation in China`s cement industry of foreign cement companies would speed the adoption of large scale very efficient precalciner plants. Paradoxically, improving energy efficiency in China`s cement industry is also a supply-side issue, improved reliability in China`s power network will make the more fuel-efficient alternative more attractive.

Sinton, J. [Lawrence Berkeley National Lab., Berkeley, CA (United States)

1996-12-31T23:59:59.000Z

491

Petrography and chemistry of sized fly ash from low-sulfur and high-sulfur coal sources  

SciTech Connect (OSTI)

Fly ash samples were collected in November and December, 1994, from two units representing high- and low-sulfur feed coals at a Kentucky power station. The ashes were wet screened at 100, 200, 325, and 500 mesh. The dried ({approximately}40 C) fractions were then weighed, split for petrographic and chemical analysis, mounted in epoxy and prepared as polished pellets, and analyzed for ash yield and carbon content. The November ashes had a similar size distribution in the +325 mesh fractions. The low-sulfur hot side and cool side ashes had a similar size distribution in the November ashes. In contrast, the December fly ashes showed the typical trend, the cool-side ash being finer (over 20% more ash in the {minus}500 mesh fraction) than the hot-side ash. Carbon tends to be relatively concentrated in the coarse fractions. The dominance of the {minus}325 mesh fractions in the overall size analysis implies, though, that carbon in the fine sizes is an important consideration in the utilization potential of the fly ash.

Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Trimble, A.S. [Franklin County High School, Frankfort, KY (United States); Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Palmer, C. [Geological Survey, Reston, VA (United States)

1996-12-31T23:59:59.000Z

492

Conversion of Fly Ash into Mesoporous Aluminosilicate Hsiao-Lan Chang, Chang-Min Chun, Ilhan A. Aksay, and Wei-Heng Shih*,  

E-Print Network [OSTI]

and aluminum sources. Fly ash, which is a byproduct of coal burning, contains mostly aluminosilicates. Recently, several authors have studied the conversion of fly ash into zeolites.5-7 Shige- moto et al.8 increased the yield of zeolites by first fusing the fly ash with NaOH. The reaction of fly ash with NaOH produced

Aksay, Ilhan A.

493

In-situ early-age hydration study of sulfobelite cements by synchrotron powder diffraction  

SciTech Connect (OSTI)

Eco-friendly belite calcium sulfoaluminate (BCSA) cement hydration behavior is not yet well understood. Here, we report an in-situ synchrotron X-ray powder diffraction study for the first hours of hydration of BCSA cements. Rietveld quantitative phase analysis has been used to establish the degree of reaction (?). The hydration of a mixture of ye'elimite and gypsum revealed that ettringite formation (? ? 70% at 50 h) is limited by ye'elimite dissolution. Two laboratory-prepared BCSA cements were also studied: non-active-BCSA and active-BCSA cements, with ?- and ??{sub H}-belite as main phases, respectively. Ye'elimite, in the non-active-BCSA system, dissolves at higher pace (? ? 25% at 1 h) than in the active-BCSA one (? ? 10% at 1 h), with differences in the crystallization of ettringite (? ? 30% and ? ? 5%, respectively). This behavior has strongly affected subsequent belite and ferrite reactivities, yielding stratlingite and other layered phases in non-active-BCSA. The dissolution and crystallization processes are reported and discussed in detail. -- Highlights: •Belite calcium sulfoaluminate cements early hydration mechanism has been determined. •Belite hydration strongly depends on availability of aluminum hydroxide. •Orthorhombic ye’elimite dissolved at a higher pace than cubic one. •Ye’elimite larger reaction degree yields stratlingite formation by belite reaction. •Rietveld method quantified gypsum, anhydrite and bassanite dissolution rates.

Álvarez-Pinazo, G.; Cuesta, A.; García-Maté, M.; Santacruz, I.; Losilla, E.R. [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain)] [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain); Sanfélix, S.G. [Unidad Técnica de Investigación de Materiales, AIDICO, Avda. Benjamín Franklin, 17 Paterna, Valencia (Spain)] [Unidad Técnica de Investigación de Materiales, AIDICO, Avda. Benjamín Franklin, 17 Paterna, Valencia (Spain); Fauth, F. [CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain)] [CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain); Aranda, M.A.G. [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain) [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain); CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain); De la Torre, A.G., E-mail: mgd@uma.es [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain)

2014-02-15T23:59:59.000Z

494

Determining the slag fraction, water/binder ratio and degree of hydration in hardened cement pastes  

SciTech Connect (OSTI)

A method for determining the original mix composition of hardened slag-blended cement-based materials based on analysis of backscattered electron images combined with loss on ignition measurements is presented. The method does not require comparison to reference standards or prior knowledge of the composition of the binders used. Therefore, it is well-suited for application to real structures. The method is also able to calculate the degrees of reaction of slag and cement. Results obtained from an experimental study involving sixty samples with a wide range of water/binder (w/b) ratios (0.30 to 0.50), slag/binder ratios (0 to 0.6) and curing ages (3 days to 1 year) show that the method is very promising. The mean absolute errors for the