National Library of Energy BETA

Sample records for area shale formation

  1. Method for maximizing shale oil recovery from an underground formation

    DOE Patents [OSTI]

    Sisemore, Clyde J.

    1980-01-01

    A method for maximizing shale oil recovery from an underground oil shale formation which has previously been processed by in situ retorting such that there is provided in the formation a column of substantially intact oil shale intervening between adjacent spent retorts, which method includes the steps of back filling the spent retorts with an aqueous slurry of spent shale. The slurry is permitted to harden into a cement-like substance which stabilizes the spent retorts. Shale oil is then recovered from the intervening column of intact oil shale by retorting the column in situ, the stabilized spent retorts providing support for the newly developed retorts.

  2. Primary oil-shale resources of the Green River Formation in the eastern Uinta Basin, Utah

    SciTech Connect (OSTI)

    Trudell, L.G.; Smith, J.W.; Beard, T.N.; Mason, G.M.

    1983-04-01

    Resources of potential oil in place in the Green River Formation are measured and estimated for the primary oil-shale resource area east of the Green River in Utah's Uinta Basin. The area evaluated (Ts 7-14 S, Rs 19-25 E) includes most of, and certainly the best of Utah's oil-shale resource. For resource evaluation the principal oil-shale section is divided into ten stratigraphic units which are equivalent to units previously evaluated in the Piceance Creek Basin of Colorado. Detailed evaluation of individual oil-shale units sampled by cores, plus estimates by extrapolation into uncored areas indicate a total resource of 214 billion barrels of shale oil in place in the eastern Uinta Basin.

  3. Characterization of DOE reference oil shales: Mahogany Zone, Parachute Creek Member, Green River Formation Oil Shale, and Clegg Creek Member, New Albany Shale

    SciTech Connect (OSTI)

    Miknis, F. P.; Robertson, R. E.

    1987-09-01

    Measurements have been made on the chemical and physical properties of two oil shales designated as reference oil shales by the Department of Energy. One oil shale is a Green River Formation, Parachute Creek Member, Mahogany Zone Colorado oil shale from the Exxon Colony mine and the other is a Clegg Creek Member, New Albany shale from Kentucky. Material balance Fischer assays, carbon aromaticities, thermal properties, and bulk mineralogic properties have been determined for the oil shales. Kerogen concentrates were prepared from both shales. The measured properties of the reference shales are comparable to results obtained from previous studies on similar shales. The western reference shale has a low carbon aromaticity, high Fischer assay conversion to oil, and a dominant carbonate mineralogy. The eastern reference shale has a high carbon aromaticity, low Fischer assay conversion to oil, and a dominant silicate mineralogy. Chemical and physical properties, including ASTM distillations, have been determined for shale oils produced from the reference shales. The distillation data were used in conjunction with API correlations to calculate a large number of shale oil properties that are required for computer models such as ASPEN. There was poor agreement between measured and calculated molecular weights for the total shale oil produced from each shale. However, measured and calculated molecular weights agreed reasonably well for true boiling point distillate fractions in the temperature range of 204 to 399/sup 0/C (400 to 750/sup 0/F). Similarly, measured and calculated viscosities of the total shale oils were in disagreement, whereas good agreement was obtained on distillate fractions for a boiling range up to 315/sup 0/C (600/sup 0/F). Thermal and dielectric properties were determined for the shales and shale oils. The dielectric properties of the reference shales and shale oils decreased with increasing frequency of the applied frequency. 42 refs., 34 figs., 24

  4. Evolution of porosity and geochemistry in Marcellus Formation black shale during weathering

    SciTech Connect (OSTI)

    Jin, Lixin; Ryan, Mathur; Rother, Gernot; Cole, David; Bazilevskaya, Ekaterina; Williams, Jennifer; Alex, Carone; Brantley, S. L.

    2013-01-01

    Soils developed on the Oatka Creek member of the Marcellus Formation in Huntingdon, Pennsylvania were analyzed to understand the evolution of black shale matrix porosity and the associated changes in elemental and mineralogical composition during infiltration of water into organic-rich shale. Making the reasonable assumption that soil erosion rates are the same as those measured in a nearby location on a less organic-rich shale, we suggest that soil production rates have on average been faster for this black shale compared to the gray shale in similar climate settings. This difference is attributed to differences in composition: both shales are dominantly quartz, illite, and chlorite, but the Oatka Creek member at this location has more organic matter (1.25 wt.% organic carbon in rock fragments recovered from the bottom of the auger cores and nearby outcrops) and accessory pyrite. During weathering, the extremely low-porosity bedrock slowly disaggregates into shale chips with intergranular pores and fractures. Some of these pores are eitherfilled with organic matter or air-filled but remain unconnected, and thus inaccessible to water. Based on weathering bedrock/soil profiles, disintegration is initiated with oxidation of pyrite and organic matter, which increases the overall porosity and most importantly allows water penetration. Water infiltration exposes fresh surface area and thus promotes dissolution of plagioclase and clays. As these dissolution reactions proceed, the porosity in the deepest shale chips recovered from the soil decrease from 9 to 7% while kaolinite and Fe oxyhydroxides precipitate. Eventually, near the land surface, mineral precipitation is outcompeted by dissolution or particle loss of illite and chlorite and porosity in shale chips increases to 20%. As imaged by computed tomographic analysis, weathering causes i) greater porosity, ii) greater average length of connected pores, and iii) a more branched pore network compared to the unweathered

  5. Evolution of porosity and geochemistry in Marcellus Formation black shale during weathering

    SciTech Connect (OSTI)

    Jin, Lixin; Mathur, Ryan; Rother, Gernot; Cole, David; Bazilevskaya, Ekaterina; Williams, Jennifer; Carone, Alex; Brantley, Susan L

    2013-01-01

    Soils developed on the Oatka Creek member of the Marcellus Formation in Huntingdon, Pennsylvania were analyzed to understand the evolution of black shale matrix porosity and the associated changes in elemental and mineralogical composition during infiltration of water into organic-rich shale. Making the reasonable assumption that soil erosion rates are the same as those measured in a nearby location on a less organic-rich shale, we suggest that soil production rates have on average been faster for this black shale compared to the gray shale in similar climate settings. This difference is attributed to differences in composition: both shales are dominantly quartz, illite, and chlorite, but the Oatka Creek member at this location has more organic matter (1.25 wt% organic carbon in rock fragments recovered from the bottom of the auger cores and nearby outcrops) and accessory pyrite. During weathering, the extremely low-porosity bedrock slowly disaggregates into shale chips with intergranular pores and fractures. Some of these pores are either filled with organic matter or air-filled but remain unconnected, and thus inaccessible to water. Based on weathering bedrock/soil profiles, disintegration is initiated with oxidation of pyrite and organic matter, which increases the overall porosity and most importantly allows water penetration. Water infiltration exposes fresh surface area and thus promotes dissolution of plagioclase and clays. As these dissolution reactions proceed, the porosity in the deepest shale chips recovered from the soil decrease from 9 to 7 % while kaolinite and Fe oxyhydroxides precipitate. Eventually, near the land surface, mineral precipitation is outcompeted by dissolution or particle loss of illite and chlorite and porosity in shale chips increases to 20%. As imaged by computed tomographic analysis, weathering causes i) greater porosity, ii) greater average length of connected pores, and iii) a more branched pore network compared to the

  6. Oil shale potential of the Heath and Tyler formations, Central Montana

    SciTech Connect (OSTI)

    Cox, W.E.; Cole, G.A.

    1981-01-01

    The units in the middle of the Heath formation below the gypsum beds were found to have the highest oil yields. That interval was generally 25 to 50 ft (7.6 to 15.2 m) thick. The upper portion of the Heath formation yielded as much as 9.8 gal/ton in section 9, and 14.9 gal/ton in section 10. The Tyler formation was determined to have very low oil potential, with the maximum yield being 2.2 gal/ton. The instability of some of the Heath slopes could present problems in the mining of oil shale. Specific stratigraphic horizons in which zones of high and low oil and metal contents occur would be extremely difficult to map in areas where the units have been displaced by landslide movement.

  7. Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations

    SciTech Connect (OSTI)

    Zoback, Mark D.; Kovscek, Anthony R.; Wilcox, Jennifer

    2013-09-30

    This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

  8. Formation resistivity as an indicator of oil generation in black shales

    SciTech Connect (OSTI)

    Hester, T.C.; Schmoker, J.W.

    1987-08-01

    Black, organic-rich shales of Late Devonian-Early Mississippi age are present in many basins of the North American craton and, where mature, have significant economic importance as hydrocarbon source rocks. Examples drawn from the upper and lower shale members of the Bakken Formation, Williston basin, North Dakota, and the Woodford Shale, Anadarko basin, Oklahoma, demonstrate the utility of formation resistivity as a direct in-situ indicator of oil generation in black shales. With the onset of oil generation, nonconductive hydrocarbons begin to replace conductive pore water, and the resistivity of a given black-shale interval increases from low levels associated with thermal immaturity to values approaching infinity. Crossplots of a thermal-maturity index (R/sub 0/ or TTI) versus formation resistivity define two populations representing immature shales and shales that have generated oil. A resistivity of 35 ohm-m marks the boundary between immature and mature source rocks for each of the three shales studied. Thermal maturity-resistivity crossplots make possible a straightforward determination of thermal maturity at the onset of oil generation, and are sufficiently precise to detect subtle differences in source-rock properties. For example, the threshold of oil generation in the upper Bakken shale occurs at R/sub 0/ = 0.43-0.45% (TTI = 10-12). The threshold increases to R/sub 0/ = 0.48-0.51% (TTI = 20-26) in the lower Bakken shale, and to R/sub 0/ = 0.56-0.57% (TTI = 33-48) in the most resistive Woodford interval.

  9. Inventory of Shale Formations in the US, Including Geologic, Hydrological, and Mechanical Characteristics

    SciTech Connect (OSTI)

    Dobson, Patrick; Houseworth, James

    2013-11-22

    The objective of this report is to build upon previous compilations of shale formations within many of the major sedimentary basins in the US by developing GIS data delineating isopach and structural depth maps for many of these units. These data are being incorporated into the LANL digital GIS database being developed for determining host rock distribution and depth/thickness parameters consistent with repository design. Methods were developed to assess hydrological and geomechanical properties and conditions for shale formations based on sonic velocity measurements.

  10. Paleontological overview of oil shale and tar sands areas in Colorado, Utah, and Wyoming.

    SciTech Connect (OSTI)

    Murphey, P. C.; Daitch, D.; Environmental Science Division

    2009-02-11

    In August 2005, the U.S. Congress enacted the Energy Policy Act of 2005, Public Law 109-58. In Section 369 of this Act, also known as the ''Oil Shale, Tar Sands, and Other Strategic Unconventional Fuels Act of 2005,'' Congress declared that oil shale and tar sands (and other unconventional fuels) are strategically important domestic energy resources that should be developed to reduce the nation's growing dependence on oil from politically and economically unstable foreign sources. In addition, Congress declared that both research- and commercial-scale development of oil shale and tar sands should (1) be conducted in an environmentally sound manner using management practices that will minimize potential impacts, (2) occur with an emphasis on sustainability, and (3) benefit the United States while taking into account concerns of the affected states and communities. To support this declaration of policy, Congress directed the Secretary of the Interior to undertake a series of steps, several of which are directly related to the development of a commercial leasing program for oil shale and tar sands. One of these steps was the completion of a programmatic environmental impact statement (PEIS) to analyze the impacts of a commercial leasing program for oil shale and tar sands resources on public lands, with an emphasis on the most geologically prospective lands in Colorado, Utah, and Wyoming. For oil shale, the scope of the PEIS analysis includes public lands within the Green River, Washakie, Uinta, and Piceance Creek Basins. For tar sands, the scope includes Special Tar Sand Areas (STSAs) located in Utah. This paleontological resources overview report was prepared in support of the Oil Shale and Tar Sands Resource Management Plan Amendments to Address Land Use Allocations in Colorado, Utah, and Wyoming and PEIS, and it is intended to be used by Bureau of Land Management (BLM) regional paleontologists and field office staff to support future projectspecific analyses

  11. Shale gas is natural gas trapped inside

    Broader source: Energy.gov (indexed) [DOE]

    Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary ... Fossil Energy Research Benefits FE's early investments in shale research in the 1970s ...

  12. Advanced Reservoir Characterization in the Antelope Shale to Establish the Viability of CO2 Enhanced Oil Recovery in California's Monterey Formation Siliceous Shales

    SciTech Connect (OSTI)

    Morea, Michael F.

    1999-11-01

    The primary objective of this research is to conduct advanced reservoir characterization and modeling studies in the Antelope Shale reservoir. Characterization studies will be used to determine the technical feasibility of implementing a CO2 enhanced oil recovery project in the Antelope Shale in Buena Vista Hills Field. The Buena Vista Hills pilot CO2 project will demonstrate the economic viability and widespread applicability of CO2 flooding in fractured siliceous shale reservoirs of the San Joaquin Valley. The research consists of four primary work processes: (1) Reservoir Matrix and Fluid Characterization; (2) Fracture characterization; (3) reservoir Modeling and Simulation; and (4) CO2 Pilot Flood and Evaluation. Work done in these areas is subdivided into two phases or budget periods. The first phase of the project will focus on the application of a variety of advanced reservoir characterization techniques to determine the production characteristics of the Antelope Shale reservoir. Reservoir models based on the results of the characterization work will be used to evaluate how the reservoir will respond to secondary recovery and EOR processes. The second phase of the project will include the implementation and evaluation of an advanced enhanced oil recovery (EOR) pilot in the United Anticline (West Dome) of the Buena Vista Hills Field.

  13. Advanced Reservoir Characterization in the Antelope Shale to Establish the Viability of C02 Enhanced Oil Recovery in California's Monterey Formation Siliceous Shales

    SciTech Connect (OSTI)

    Michael F. Morea.

    1998-04-23

    The primary objective of this research is to conduct advanced reservoir characterization and modeling studies in the Antelope Shale reservoir. Characterization studies will be used to determine the technical feasibility of implementing a CO2 enhanced oil recovery project in the Antelope Shale in Buena Vista Hills Field. The Buena Vista Hills pilot CO2 project will demonstrate the economic viability and widespread applicability of CO2 flooding in fractured siliceous shale reservoirs of the San Joaquin Valley. The research consists of four primary work processes: Reservoir Matrix and Fluid Characterization; Fracture Characterization; Reservoir Modeling and Simulation; and CO2 Pilot Flood and Evaluation. Work done in these areas is subdivided into two phases or budget periods. The first phase of the project will focus on the application of a variety of advanced reservoir characterization techniques to determine the production characteristics of the Antelope Shale reservoir. Reservoir models based on the results of the characterization work will be used to evaluate how the reservoir will respond to secondary recovery and EOR processes. The second phase of the project will include the implementation and evaluation of an advanced enhanced oil recovery (EOR) pilot in the United Anticline (West Dome) of the Buena Vista Hills Field.

  14. Advanced Reservoir Characterization in the Antelope Shale to Establish the Viability of CO2 Enhanced Oil Recovery in California's Monterey Formation Siliceous Shales

    SciTech Connect (OSTI)

    Morea, Michael F.

    1999-11-08

    The primary objective of this research is to conduct advanced reservoir characterization and modeling studies in the Antelope Shale reservoir. Characterization studies will be used to determine the technical feasibility of implementing a CO2 enhanced oil recovery project in the Antelope Shale in Buena Vista Hills Field. The Buena Vista Hills pilot CO2 project will demonstrate the economic viability and widespread applicability of CO2 flooding in fractured siliceous shale reservoirs of the San Joaquin Valley. The research consists of four primary work processes: (1) Reservoir Matrix and Fluid Characterization; (2) Fracture characterization; (3) reservoir Modeling and Simulation; and (4) CO2 Pilot Flood and Evaluation. Work done in these areas is subdivided into two phases or budget periods. The first phase of the project will focus on the application of a variety of advanced reservoir characterization techniques to determine the production characteristics of the Antelope Shale reservoir. Reservoir models based on the results of the characterization work will be used to evaluate how the reservoir will respond to secondary recovery and EOR processes. The second phase of the project will include the implementation and evaluation of an advanced enhanced oil recovery (EOR) pilot in the United Anticline (West Dome) of the Buena Vista Hills Field.

  15. Sedimentological, mineralogical and geochemical definition of oil-shale facies in the lower Parachute Creek Member of Green River Formation, Colorado

    SciTech Connect (OSTI)

    Cole, R.D.

    1984-04-01

    Sedimentological, mineralogical and geochemical studies of two drill cores penetrating the lower Saline zone of the Parachute Creek Member (middle L-4 oil-shale zone through upper R-2 zone) of the Green River Formation in north-central Piceance Creek basin, Colorado, indicate the presence of two distinct oil-shale facies. The most abundant facies has laminated stratification and frequently occurs in the L-4, L-3 and L-2 oil-shale zones. The second, and subordinate facies, has ''streaked and blebby'' stratification and is most abundant in the R-4, R-3 and R-2 zones. Laminated oil shale originated by slow, regular sedimentation during meromictic phases of ancient Lake Uinta, whereas streaked and blebby oil shale was deposited by episodic, non-channelized turbidity currents. Laminated oil shale has higher contents of nahcolite, dawsonite, quartz, K-feldspar and calcite, but less dolomite/ankerite and albite than streaked and blebby oil shale. Ca-Mg-Fe carbonate minerals in laminated oil shale have more variable compositions than those in streaked and blebby shales. Streaked and blebby oil shale has more kerogen and a greater diversity of kerogen particles than laminated oil shale. Such variations may produce different pyrolysis reactions when each shale type is retorted.

  16. Fast Track Reservoir Modeling of Shale Formations in the Appalachian Basin. Application to Lower Huron Shale in Eastern Kentucky

    SciTech Connect (OSTI)

    Grujic, Ognjen; Mohaghegh, Shahab; Bromhal, Grant

    2010-07-01

    In this paper a fast track reservoir modeling and analysis of the Lower Huron Shale in Eastern Kentucky is presented. Unlike conventional reservoir simulation and modeling which is a bottom up approach (geo-cellular model to history matching) this new approach starts by attempting to build a reservoir realization from well production history (Top to Bottom), augmented by core, well-log, well-test and seismic data in order to increase accuracy. This approach requires creation of a large spatial-temporal database that is efficiently handled with state of the art Artificial Intelligence and Data Mining techniques (AI & DM), and therefore it represents an elegant integration of reservoir engineering techniques with Artificial Intelligence and Data Mining. Advantages of this new technique are a) ease of development, b) limited data requirement (as compared to reservoir simulation), and c) speed of analysis. All of the 77 wells used in this study are completed in the Lower Huron Shale and are a part of the Big Sandy Gas field in Eastern Kentucky. Most of the wells have production profiles for more than twenty years. Porosity and thickness data was acquired from the available well logs, while permeability, natural fracture network properties, and fracture aperture data was acquired through a single well history matching process that uses the FRACGEN/NFFLOW simulator package. This technology, known as Top-Down Intelligent Reservoir Modeling, starts with performing conventional reservoir engineering analysis on individual wells such as decline curve analysis and volumetric reserves estimation. Statistical techniques along with information generated from the reservoir engineering analysis contribute to an extensive spatio-temporal database of reservoir behavior. The database is used to develop a cohesive model of the field using fuzzy pattern recognition or similar techniques. The reservoir model is calibrated (history matched) with production history from the most recently

  17. Reservoir characterization of the Clough area, Barnett Shale, Wise County, Texas. Topical report, January-July 1995

    SciTech Connect (OSTI)

    Hill, N.C.; Lancaster, D.E.

    1995-07-01

    The objective of this work was to learn more about the reservoir characteristics in the Barnett Shale. Specifically, from an analysis of pressure, production, interference, and fracture treatment data in three Mitchell Energy Corporation Cough area wells, the authors can infer the relationship between the induced hydraulic fractures and the natural fracture system in the reservoir. The authors are learning something about drainage area size, shape, and orientation.

  18. Advanced Reservoir Characterization in the Antelope Shale to Establish the Viability of CO{sub 2} Enhanced Oil Recovery in California's Monterey Formation Siliceous Shales

    SciTech Connect (OSTI)

    Michael F. Morea

    1997-03-14

    The Buena Vista Hills field is located about 25 miles southwest of Bakersfield, in Kern County, California, about two miles north of the city of Taft, and five miles south of the Elk Hills field. The Antelope Shale zone was discovered at the Buena Vista Hills field in 1952, and has since been under primary production. Little research was done to improve the completion techniques during the development phase in the 1950s, so most of the wells are completed with about 1000 ft of slotted liner. The proposed pilot consists of four existing producers on 20 acre spacing with a new 10 acre infill well drilled as the pilot CO{sub 2} injector. Most of the reservoir characterization of the first phase of the project will be performed using data collected in the pilot pattern wells. This is the first annual report of the project. It covers the period February 12, 1996 to February 11, 1997. During this period the Chevron Murvale 653Z-26B well was drilled in Section 26-T31S/R23E in the Buena Vista Hills field, Kern County, California. The Monterey Formation equivalent Brown and Antelope Shales were continuously cored, the zone was logged with several different kinds of wireline logs, and the well was cased to a total depth of 4907 ft. Core recovery was 99.5%. Core analyses that have been performed include Dean Stark porosity, permeability and fluid saturations, field wettability, anelastic strain recovery, spectral core gamma, profile permeametry, and photographic imaging. Wireline log analysis includes mineral-based error minimization (ELAN), NMR T2 processing, and dipole shear wave anisotropy. A shear wave vertical seismic profile was acquired after casing was set and processing is nearly complete.

  19. Oil shale research in China

    SciTech Connect (OSTI)

    Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

    1989-01-01

    There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

  20. NATURAL GAS FROM SHALE: Questions and Answers Shale Gas Glossary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glossary Acquifer - A single underground geological formation, or group of formations, containing water. Antrim Shale - A shale deposit located in the northern Michigan basin that is a Devonian age rock formation lying at a relatively shallow depth of 1,000 feet. Gas has been produced from this formation for several decades primarily via vertical, rather than horizontal, wells. The Energy Information Administration (EIA) estimates the technically recoverable Antrim shale resource at 20 trillion

  1. CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    Lauren P. Birgenheier; Michael D. Vanden Berg,

    2011-04-11

    An integrated detailed sedimentologic, stratigraphic, and geochemical study of Utah's Green River Formation has found that Lake Uinta evolved in three phases (1) a freshwater rising lake phase below the Mahogany zone, (2) an anoxic deep lake phase above the base of the Mahogany zone and (3) a hypersaline lake phase within the middle and upper R-8. This long term lake evolution was driven by tectonic basin development and the balance of sediment and water fill with the neighboring basins, as postulated by models developed from the Greater Green River Basin by Carroll and Bohacs (1999). Early Eocene abrupt global-warming events may have had significant control on deposition through the amount of sediment production and deposition rates, such that lean zones below the Mahogany zone record hyperthermal events and rich zones record periods between hyperthermals. This type of climatic control on short-term and long-term lake evolution and deposition has been previously overlooked. This geologic history contains key points relevant to oil shale development and engineering design including: (1) Stratigraphic changes in oil shale quality and composition are systematic and can be related to spatial and temporal changes in the depositional environment and basin dynamics. (2) The inorganic mineral matrix of oil shale units changes significantly from clay mineral/dolomite dominated to calcite above the base of the Mahogany zone. This variation may result in significant differences in pyrolysis products and geomechanical properties relevant to development and should be incorporated into engineering experiments. (3) This study includes a region in the Uinta Basin that would be highly prospective for application of in-situ production techniques. Stratigraphic targets for in-situ recovery techniques should extend above and below the Mahogany zone and include the upper R-6 and lower R-8.

  2. Advanced Reservoir Characterization in the Antelope Shale to Establish the Viability of CO2 Enhanced Oil Recovery in California's Monterey Formation Siliceous Shales, Class III

    SciTech Connect (OSTI)

    Perri, Pasquale R.; Cooney, John; Fong, Bill; Julander, Dale; Marasigan, Aleks; Morea, Mike; Piceno, Deborah; Stone, Bill; Emanuele, Mark; Sheffield, Jon; Wells, Jeff; Westbrook, Bill; Karnes, Karl; Pearson, Matt; Heisler, Stuart

    2000-04-24

    The primary objective of this project was to conduct advanced reservoir characterization and modeling studies in the Antelope Shale of the Bureau Vista Hills Field. Work was subdivided into two phases or budget periods. The first phase of the project focused on a variety of advanced reservoir characterization techniques to determine the production characteristics of the Antelope Shale reservoir. Reservoir models based on the results of the characterization work would then be used to evaluate how the reservoir would respond to enhanced oil recovery (EOR) processes such as of CO2 flooding. The second phase of the project would be to implement and evaluate a CO2 in the Buena Vista Hills Field. A successful project would demonstrate the economic viability and widespread applicability of CO2 flooding in siliceous shale reservoirs of the San Joaquin Valley.

  3. Shale Gas Spreads to the South | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science & Innovation » Oil & Gas » Shale » Shale Gas 101 Shale Gas 101 Shale Gas 101 This webpage has been developed to answer the many questions that people have about shale gas and hydraulic fracturing (or fracking). The information provided below explains the basics, including what shale gas is, where it's found, why it's important, how it's produced, and challenges associated with production. Natural gas production from "shale" formations (fine-grained sedimentary rocks

  4. Fire and explosion hazards of oil shale

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The US Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles. 10 refs., 54 figs., 29 tabs.

  5. Oil shale retorting method and apparatus

    SciTech Connect (OSTI)

    York, E.D.

    1983-03-22

    Disclosed is an improved method and apparatus for the retorting of oil shale and the formation of spent oil shale having improved cementation properties. The improved method comprises passing feed comprising oil shale to a contacting zone wherein the feed oil shale is contacted with heat transfer medium to heat said shale to retorting temperature. The feed oil shale is substantially retorted to form fluid material having heating value and forming partially spent oil shale containing carbonaceous material. At least a portion of the partially spent oil shale is passed to a combustion zone wherein the partially spent oil shale is contacted with oxidizing gas comprising oxygen and steam to substantially combust carbonaceous material forming spent oil shale having improved cementation properties.

  6. Two-level, horizontal free face mining system for in situ oil shale retorts

    SciTech Connect (OSTI)

    Cha, C.Y.; Ricketts, T.E.

    1986-09-16

    A method is described for forming an in-situ oil shale retort within a retort site in a subterranean formation containing oil shale, such an in-situ oil shale retort containing a fragmented permeable mass of formation particles containing oil shale formed within upper, lower and side boundaries of an in-situ oil shale retort site.

  7. What is shale gas and why is it important?

    Reports and Publications (EIA)

    2012-01-01

    Shale gas refers to natural gas that is trapped within shale formations. Shales are fine-grained sedimentary rocks that can be rich sources of petroleum and natural gas. Over the past decade, the combination of horizontal drilling and hydraulic fracturing has allowed access to large volumes of shale gas that were previously uneconomical to produce. The production of natural gas from shale formations has rejuvenated the natural gas industry in the United States.

  8. Class I cultural resource overview for oil shale and tar sands areas in Colorado, Utah and Wyoming.

    SciTech Connect (OSTI)

    O'Rourke, D.; Kullen, D.; Gierek, L.; Wescott, K.; Greby, M.; Anast, G.; Nesta, M.; Walston, L.; Tate, R.; Azzarello, A.; Vinikour, B.; Van Lonkhuyzen, B.; Quinn, J.; Yuen, R.; Environmental Science Division

    2007-11-01

    In August 2005, the U.S. Congress enacted the Energy Policy Act of 2005, Public Law 109-58. In Section 369 of this Act, also known as the 'Oil Shale, Tar Sands, and Other Strategic Unconventional Fuels Act of 2005', Congress declared that oil shale and tar sands (and other unconventional fuels) are strategically important domestic energy resources that should be developed to reduce the nation's growing dependence on oil from politically and economically unstable foreign sources. The Bureau of Land Management (BLM) is developing a Programmatic Environmental Impact Statement (PEIS) to evaluate alternatives for establishing commercial oil shale and tar sands leasing programs in Colorado, Wyoming, and Utah. This PEIS evaluates the potential impacts of alternatives identifying BLM-administered lands as available for application for commercial leasing of oil shale resources within the three states and of tar sands resources within Utah. The scope of the analysis of the PEIS also includes an assessment of the potential effects of future commercial leasing. This Class I cultural resources study is in support of the Draft Oil Shale and Tar Sands Resource Management Plan Amendments to Address Land Use Allocations in Colorado, Utah, and Wyoming and Programmatic Environmental Impact Statement and is an attempt to synthesize archaeological data covering the most geologically prospective lands for oil shale and tar sands in Colorado, Utah, and Wyoming. This report is based solely on geographic information system (GIS) data held by the Colorado, Utah, and Wyoming State Historic Preservation Offices (SHPOs). The GIS data include the information that the BLM has provided to the SHPOs. The primary purpose of the Class I cultural resources overview is to provide information on the affected environment for the PEIS. Furthermore, this report provides recommendations to support planning decisions and the management of cultural resources that could be impacted by future oil shale and tar

  9. Clean and Secure Energy from Domestic Oil Shale and Oil Sands...

    Office of Scientific and Technical Information (OSTI)

    and Mechanisms of Oil Shale Pyrolysis: A Chemical Structure Approach (November, 2014); ... Analysis of the Oil Shale Bearing Green River Formation, Uinta Basin, Utah (April, ...

  10. In situ oil shale retort with a generally T-shaped vertical cross section

    DOE Patents [OSTI]

    Ricketts, Thomas E.

    1981-01-01

    An in situ oil shale retort is formed in a subterranean formation containing oil shale. The retort contains a fragmented permeable mass of formation particles containing oil shale and has a production level drift in communication with a lower portion of the fragmented mass for withdrawing liquid and gaseous products of retorting during retorting of oil shale in the fragmented mass. The principal portion of the fragmented mass is spaced vertically above a lower production level portion having a generally T-shaped vertical cross section. The lower portion of the fragmented mass has a horizontal cross sectional area smaller than the horizontal cross sectional area of the upper principal portion of the fragmented mass above the production level.

  11. Advanced reservoir characterization in the Antelope Shale to establish the viability of CO{sub 2} enhanced oil recovery in California`s Monterey Formation siliceous shales. Annual report, February 12, 1996--February 11, 1997

    SciTech Connect (OSTI)

    Toronyi, R.M.

    1997-12-01

    The Buena Vista Hills field is located about 25 miles southwest of Bakersfield, in Kern County, California, about two miles north of the city of Taft, and five miles south of the Elk Hills field. The Antelope Shale zone was discovered at the Buena Vista Hills field in 1952, and has since been under primary production. Little research was done to improve the completion techniques during the development phase in the 1950s, so most of the wells are completed with about 1000 ft of slotted liner. The proposed pilot consists of four existing producers on 20 acre spacing with a new 10 acre infill well drilled as the pilot CO{sub 2} injector. Most of the reservoir characterization of the first phase of the project will be performed using data collected in the pilot pattern wells. This is the first annual report of the project. It covers the period February 12, 1996 to February 11, 1997. During this period the Chevron Murvale 653Z-26B well was drilled in Section 26-T31S/R23E in the Buena Vista Hills field, Kern County, California. The Monterey Formation equivalent Brown and Antelope Shales were continuously cored, the zone was logged with several different kinds of wireline logs, and the well was cased to a total depth of 4907 ft. Core recovery was 99.5%. Core analyses that have been performed include Dean Stark porosity, permeability and fluid saturations, field wettability, anelastic strain recovery, spectral core gamma, profile permeametry, and photographic imaging. Wireline log analysis includes mineral-based error minimization (ELAN), NMR T2 processing, and dipole shear wave anisotropy. A shear wave vertical seismic profile was acquired after casing was set and processing is nearly complete.

  12. Method for forming an in-situ oil shale retort in differing grades of oil shale

    SciTech Connect (OSTI)

    Ricketts, T.E.

    1984-04-24

    An in-situ oil shale retort is formed in a subterranean formation containing oil shale. The formation comprises at least one region of relatively richer oil shale and another region of relatively leaner oil shale. According to one embodiment, formation is excavated from within a retort site for forming at least one void extending horizontally across the retort site, leaving a portion of unfragmented formation including the regions of richer and leaner oil shale adjacent such a void space. A first array of vertical blast holes are drilled in the regions of richer and leaner oil shale, and a second array of blast holes are drilled at least in the region of richer oil shale. Explosive charges are placed in portions of the blast holes in the first and second arrays which extend into the richer oil shale, and separate explosive charges are placed in portions of the blast holes in the first array which extend into the leaner oil shale. This provides an array with a smaller scaled depth of burial (sdob) and closer spacing distance between explosive charges in the richer oil shale than the sdob and spacing distance of the array of explosive charges in the leaner oil shale. The explosive charges are detonated for explosively expanding the regions of richer and leaner oil shale toward the horizontal void for forming a fragmented mass of particles. Upon detonation of the explosive, greater explosive energy is provided collectively by the explosive charges in the richer oil shale, compared with the explosive energy produced by the explosive charges in the leaner oil shale, resulting in comparable fragmentation in both grades of oil shale.

  13. Oil shale combustion/retorting

    SciTech Connect (OSTI)

    Not Available

    1983-05-01

    The Morgantown Energy Technology Center (METC) conducted a number of feasibility studies on the combustion and retorting of five oil shales: Celina (Tennessee), Colorado, Israeli, Moroccan, and Sunbury (Kentucky). These studies generated technical data primarily on (1) the effects of retorting conditions, (2) the combustion characteristics applicable to developing an optimum process design technology, and (3) establishing a data base applicable to oil shales worldwide. During the research program, METC applied the versatile fluidized-bed process to combustion and retorting of various low-grade oil shales. Based on METC's research findings and other published information, fluidized-bed processes were found to offer highly attractive methods to maximize the heat recovery and yield of quality oil from oil shale. The principal reasons are the fluidized-bed's capacity for (1) high in-bed heat transfer rates, (2) large solid throughput, and (3) selectivity in aromatic-hydrocarbon formation. The METC research program showed that shale-oil yields were affected by the process parameters of retorting temperature, residence time, shale particle size, fluidization gas velocity, and gas composition. (Preferred values of yields, of course, may differ among major oil shales.) 12 references, 15 figures, 8 tables.

  14. A 4D Synchrotron X-Ray-Tomography Study of the Formation of Hydrocarbon- Migration Pathways in Heated Organic-Rich Shale

    SciTech Connect (OSTI)

    Hamed Panahi; Paul Meakin; Francois Renard; Maya Kobchenko; Julien Scheibert; Adriano Mazzini; Bjorn Jamtveit; Anders Malthe-Sorenssen; Dag Kristian Dysthe

    2013-04-01

    Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes that have received renewed interest in recent years because of the ever tightening supply of conventional hydrocarbons and the growing production of hydrocarbons from low-permeability tight rocks. Quantitative models for conversion of kerogen into oil and gas and the timing of hydrocarbon generation have been well documented. However, lack of consensus about the kinetics of hydrocarbon formation in source rocks, expulsion timing, and how the resulting hydrocarbons escape from or are retained in the source rocks motivates further investigation. In particular, many mechanisms have been proposed for the transport of hydrocarbons from the rocks in which they are generated into adjacent rocks with higher permeabilities and smaller capillary entry pressures, and a better understanding of this complex process (primary migration) is needed. To characterize these processes, it is imperative to use the latest technological advances. In this study, it is shown how insights into hydrocarbon migration in source rocks can be obtained by using sequential high-resolution synchrotron X-ray tomography. Three-dimensional images of several immature "shale" samples were constructed at resolutions close to 5 um. This is sufficient to resolve the source-rock structure down to the grain level, but very-fine-grained silt particles, clay particles, and colloids cannot be resolved. Samples used in this investigation came from the R-8 unit in the upper part of the Green River shale, which is organic rich, varved, lacustrine marl formed in Eocene Lake Uinta, USA. One Green River shale sample was heated in situ up to 400 degrees C as X-ray-tomography images were recorded. The other samples were scanned before and after heating at 400 degrees C. During the heating phase, the organic matter was decomposed, and gas was released. Gas expulsion from the low-permeability shales was coupled

  15. Clean and Secure Energy from Domestic Oil Shale and Oil Sands Resources

    SciTech Connect (OSTI)

    Spinti, Jennifer; Birgenheier, Lauren; Deo, Milind; Facelli, Julio; Hradisky, Michal; Kelly, Kerry; Miller, Jan; McLennan, John; Ring, Terry; Ruple, John; Uchitel, Kirsten

    2015-09-30

    This report summarizes the significant findings from the Clean and Secure Energy from Domestic Oil Shale and Oil Sands Resources program sponsored by the Department of Energy through the National Energy Technology Laboratory. There were four principle areas of research; Environmental, legal, and policy issues related to development of oil shale and oil sands resources; Economic and environmental assessment of domestic unconventional fuels industry; Basin-scale assessment of conventional and unconventional fuel development impacts; and Liquid fuel production by in situ thermal processing of oil shale Multiple research projects were conducted in each area and the results have been communicated via sponsored conferences, conference presentations, invited talks, interviews with the media, numerous topical reports, journal publications, and a book that summarizes much of the oil shale research relating to Utah’s Uinta Basin. In addition, a repository of materials related to oil shale and oil sands has been created within the University of Utah’s Institutional Repository, including the materials generated during this research program. Below is a listing of all topical and progress reports generated by this project and submitted to the Office of Science and Technical Information (OSTI). A listing of all peer-reviewed publications generated as a result of this project is included at the end of this report; Geomechanical and Fluid Transport Properties 1 (December, 2015); Validation Results for Core-Scale Oil Shale Pyrolysis (February, 2015); and Rates and Mechanisms of Oil Shale Pyrolysis: A Chemical Structure Approach (November, 2014); Policy Issues Associated With Using Simulation to Assess Environmental Impacts (November, 2014); Policy Analysis of the Canadian Oil Sands Experience (September, 2013); V-UQ of Generation 1 Simulator with AMSO Experimental Data (August, 2013); Lands with Wilderness Characteristics, Resource Management Plan Constraints, and Land Exchanges

  16. Advanced reservoir characterization in the Antelope Shale to establish the viability of CO2 enhanced oil recovery in California`s Monterey Formation siliceous shales. Annual report, February 7, 1997--February 6, 1998

    SciTech Connect (OSTI)

    Morea, M.F.

    1998-06-01

    The primary objective of this research is to conduct advanced reservoir characterization and modeling studies in the Antelope Shale reservoir. Characterization studies will be used to determine the technical feasibility of implementing a CO{sub 2} enhanced oil recovery project in the antelope Shale in Buena Vista Hills Field. The proposed pilot consists of four existing producers on 20 acre spacing with a new 10 acre infill well drilled as the pilot CO{sub 2} injector. Most of the reservoir characterization during Phase 1 of the project will be performed using data collected in the pilot pattern wells. During this period the following tasks have been completed: laboratory wettability; specific permeability; mercury porosimetry; acoustic anisotropy; rock mechanics analysis; core description; fracture analysis; digital image analysis; mineralogical analysis; hydraulic flow unit analysis; petrographic and confocal thin section analysis; oil geochemical fingerprinting; production logging; carbon/oxygen logging; complex lithologic log analysis; NMR T2 processing; dipole shear wave anisotropy logging; shear wave vertical seismic profile processing; structural mapping; and regional tectonic synthesis. Noteworthy technological successes for this reporting period include: (1) first (ever) high resolution, crosswell reflection images of SJV sediments; (2) first successful application of the TomoSeis acquisition system in siliceous shales; (3) first detailed reservoir characterization of SJV siliceous shales; (4) first mineral based saturation algorithm for SJV siliceous shales, and (5) first CO{sub 2} coreflood experiments for siliceous shale. Preliminary results from the CO{sub 2} coreflood experiments (2,500 psi) suggest that significant oil is being produced from the siliceous shale.

  17. Kerogen extraction from subterranean oil shale resources

    DOE Patents [OSTI]

    Looney, Mark Dean; Lestz, Robert Steven; Hollis, Kirk; Taylor, Craig; Kinkead, Scott; Wigand, Marcus

    2010-09-07

    The present invention is directed to methods for extracting a kerogen-based product from subsurface (oil) shale formations, wherein such methods rely on fracturing and/or rubblizing portions of said formations so as to enhance their fluid permeability, and wherein such methods further rely on chemically modifying the shale-bound kerogen so as to render it mobile. The present invention is also directed at systems for implementing at least some of the foregoing methods. Additionally, the present invention is also directed to methods of fracturing and/or rubblizing subsurface shale formations and to methods of chemically modifying kerogen in situ so as to render it mobile.

  18. Kerogen extraction from subterranean oil shale resources

    DOE Patents [OSTI]

    Looney, Mark Dean; Lestz, Robert Steven; Hollis, Kirk; Taylor, Craig; Kinkead, Scott; Wigand, Marcus

    2009-03-10

    The present invention is directed to methods for extracting a kerogen-based product from subsurface (oil) shale formations, wherein such methods rely on fracturing and/or rubblizing portions of said formations so as to enhance their fluid permeability, and wherein such methods further rely on chemically modifying the shale-bound kerogen so as to render it mobile. The present invention is also directed at systems for implementing at least some of the foregoing methods. Additionally, the present invention is also directed to methods of fracturing and/or rubblizing subsurface shale formations and to methods of chemically modifying kerogen in situ so as to render it mobile.

  19. Oil Shale Research in the United States | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research in the United States Oil Shale Research in the United States Profiles of Oil Shale Research and Development Activities In Universities, National Laboratories, and Public Agencies Oil Shale Research in the United States (7.2 MB) More Documents & Publications Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Applicability of a Hybrid Retorting Technology in the Green River Formation National Strategic Unconventional Resource Model

  20. Shale oil recovery process

    DOE Patents [OSTI]

    Zerga, Daniel P.

    1980-01-01

    A process of producing within a subterranean oil shale deposit a retort chamber containing permeable fragmented material wherein a series of explosive charges are emplaced in the deposit in a particular configuration comprising an initiating round which functions to produce an upward flexure of the overburden and to initiate fragmentation of the oil shale within the area of the retort chamber to be formed, the initiating round being followed in a predetermined time sequence by retreating lines of emplaced charges developing further fragmentation within the retort zone and continued lateral upward flexure of the overburden. The initiating round is characterized by a plurality of 5-spot patterns and the retreating lines of charges are positioned and fired along zigzag lines generally forming retreating rows of W's. Particular time delays in the firing of successive charges are disclosed.

  1. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    | Technically Recoverable Shale Oil and Shale Gas Resources i This report was ... September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil ...

  2. Preliminary evaluation of shale-oil resources in Missouri

    SciTech Connect (OSTI)

    Nuelle, L.M.; Sumner, H.S.

    1981-02-01

    This report is a preliminary overview of oil-shale potential in Missouri. Two types of oil shales occur in Missouri: (1) the platform marine type, represented by the Devonian Chattanooga Shale, and (2) black shales in Pennsylvanian cyclothems, many of which overlie currently mined coal beds. The Chattanooga Shale contains black, fissile, carbonaceous shales and reaches a thickness of around 70 ft in southwestern Missouri. Oil-yield data from Missouri are not available, but based on yields from other states, the Chattanooga of southwest Missouri is estimated to contain between 2.6 and 15.8 billion barrels of oil. Preliminary estimates of the black, hard, fissile, carbonaceous Pennsylvanian shales indicate they contain between 100 and 200 billion barrels of shale oil. Many of these units directly overlie currently mined coal seams and could be recovered with the coal, but they are now discarded as overburden. These shales also contain significant amounts of phosphates and uranium. Other Paleozoic units with limited oil-shale potential are the Ordovician Decorah and Maquoketa Formations and the Upper Devonian Grassy Creek Shale. Ambitious research programs are needed to evaluate Missouri oil-shale resources. Further investigations should include economic and technological studies and the drilling, mapping, and sampling of potential oil-shale units. Shrinking supplies of crude oil make such studies desirable.

  3. Zero Discharge Water Management for Horizontal Shale Gas Well...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (fracking), coupled with horizontal drilling, has facilitated exploitation of huge natural gas (gas) reserves in the Devonian-age Marcellus Shale Formation (Marcellus) of...

  4. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  5. Technically Recoverable Shale Oil and Shale Gas Resources

    U.S. Energy Information Administration (EIA) Indexed Site

    EIA/ARI World Shale Gas and Shale Oil Resource Assessment May, 17, 2013 2-1 SHALE GAS AND SHALE OIL RESOURCE ASSESSMENT METHODOLOGY INTRODUCTION This report sets forth Advanced Resources' methodology for assessing the in-place and recoverable shale gas and shale oil resources for the EIA/ARI "World Shale Gas and Shale Oil Resource Assessment." The methodology relies on geological information and reservoir properties assembled from the technical literature and data from publically

  6. LLNL oil shale project review: METC third annual oil shale contractors meeting

    SciTech Connect (OSTI)

    Cena, R.J.; Coburn, T.T.; Taylor, R.W.

    1988-01-01

    The Lawrence Livermore National Laboratory combines laboratory and pilot-scale experimental measurements with mathematical modeling of fundamental chemistry and physics to provide a technical base for evaluating oil shale retorting alternatives. Presented herein are results of four research areas of interest in oil shale process development: Recent Progress in Solid-Recycle Retorting and Related Laboratory and Modeling Studies; Water Generation During Pyrolysis of Oil Shale; Improved Analytical Methods and Measurements of Rapid Pyrolysis Kinetics for Western and Eastern Oil Shale; and Rate of Cracking or Degradation of Oil Vapor In Contact with Oxidized Shale. We describe operating results of a 1 tonne-per-day, continuous-loop, solid-recycle, retort processing both Western And Eastern oil shale. Sulfur chemistry, solid mixing limits, shale cooling tests and catalyst addition are all discussed. Using a triple-quadrupole mass spectrometer, we measure individual species evolution with greater sensitivity and selectivity. Herein we discuss our measurements of water evolution during ramped heating of Western and Eastern oil shale. Using improved analytical techniques, we determine isothermal pyrolysis kinetics for Western and Eastern oil shale, during rapid heating, which are faster than previously thought. Finally, we discuss the rate of cracking of oil vapor in contact with oxidized shale, qualitatively using a sand fluidized bed and quantitatively using a vapor cracking apparatus. 3 refs., 4 figs., 1 tab.

  7. Fire and explosion hazards of oil shale. Report of Investigations/1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This publication presents the results of investigations into the fire and explosion hazards of oil-shale rocks and dust. Three areas were examined: the explosibility and ignitability of oil-shale dust clouds, the fire hazards of oil-shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles.

  8. Maquoketa Shale Caprock Integrity Evaluation

    SciTech Connect (OSTI)

    Leetaru, Hannes

    2014-09-30

    The Knox Project objective is to evaluate the potential of formations within the Cambrian-Ordovician strata above the Mt. Simon Sandstone (St. Peter Sandstone and Potosi Dolomite) as potential targets for carbon dioxide (CO2) sequestration in the Illinois and Michigan Basins. The suitability of the St. Peter Sandstone and Potosi Dolomite to serve as reservoirs for CO2 sequestration is discussed in separate reports. In this report the data gathered from the Knox project, the Illinois Basin – Decatur Project (IBDP) and Illinois Industrial Carbon Capture and Sequestration project (IL-ICCS) are used to make some conclusions about the suitability of the Maquoketa shale as a confining layer for CO2 sequestration. These conclusions are then upscaled to basin-wide inferences based on regional knowledge. Data and interpretations (stratigraphic, petrophysical, fractures, geochemical, risk, seismic) applicable to the Maquoketa Shale from the above mentioned projects was inventoried and summarized. Based on the analysis of these data and interpretations, the Maquoketa Shale is considered to be an effective caprock for a CO2 injection project in either the Potosi Dolomite or St. Peter Sandstone because it has a suitable thickness (~200ft. ~61m), advantageous petrophysical properties (low effective porosity and low permeability), favorable geomechanical properties, an absence of observable fractures and is regionally extensive. Because it is unlikely that CO2 would migrate upward through the Maquoketa Shale, CO2, impact to above lying fresh water aquifers is unlikely. Furthermore, the observations indicate that CO2 injected into the St. Peter Sandstone or Potosi Dolomite may never even migrate up into the Maquoketa Shale at a high enough concentrations or pressure to threaten the integrity of the caprock. Site specific conclusions were reached by unifying the data and conclusions from the IBDP, ICCS and the Knox projects. In the Illinois Basin, as one looks further away from

  9. Assessment of Factors Influencing Effective CO{sub 2} Storage Capacity and Injectivity in Eastern Gas Shales

    SciTech Connect (OSTI)

    Godec, Michael

    2013-06-30

    -level characterizations for the CO{sub 2} storage capacity and injectivity potential of the targeted eastern shales. In total, these Eastern gas shales cover an area of over 116 million acres, may contain an estimated 6,000 trillion cubic feet (Tcf) of gas in place, and have a maximum theoretical storage capacity of over 600 million metric tons. Not all of this gas in-place will be recoverable, and economics will further limit how much will be economic to produce using EGR techniques with CO{sub 2} injection. Reservoir models were developed and simulations were conducted to characterize the potential for both CO{sub 2} storage and EGR for the target gas shale formations. Based on that, engineering costing and cash flow analyses were used to estimate economic potential based on future natural gas prices and possible financial incentives. The objective was to assume that EGR and CO{sub 2} storage activities would commence consistent with the historical development practices. Alternative CO{sub 2} injection/EGR scenarios were considered and compared to well production without CO{sub 2} injection. These simulations were conducted for specific, defined model areas in each shale gas play. The resulting outputs were estimated recovery per typical well (per 80 acres), and the estimated CO{sub 2} that would be injected and remain in the reservoir (i.e., not produced), and thus ultimately assumed to be stored. The application of this approach aggregated to the entire area of the four shale gas plays concluded that they contain nearly 1,300 Tcf of both primary production and EGR potential, of which an estimated 460 Tcf could be economic to produce with reasonable gas prices and/or modest incentives. This could facilitate the storage of nearly 50 Gt of CO{sub 2} in the Marcellus, Utica, Antrim, and Devonian Ohio shales.

  10. What is shale gas? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    What is shale gas? What is shale gas? What is shale gas? (694.01 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary How is shale gas produced?

  11. Shale gas - what happened? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shale gas - what happened? Shale gas - what happened? It seems like shale gas came out of nowhere - what happened? More Documents & Publications Natural Gas from Shale: Questions...

  12. Virginia Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Virginia Shale Proved Reserves (Billion Cubic ... Shale Natural Gas Proved Reserves as of Dec. 31 Virginia Shale Gas Proved Reserves, ...

  13. New Mexico Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Shale Production (Billion Cubic Feet) New Mexico Shale Production (Billion Cubic Feet) ... Referring Pages: Shale Natural Gas Estimated Production New Mexico Shale Gas Proved ...

  14. NATURAL GAS FROM SHALE: Questions and Answers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Representation of common equipment at a natural gas hydraulic fracturing drill pad. How is Shale Gas Produced? Shale gas formations are "unconventional" reservoirs - i.e., reservoirs of low "permeability." Permeability refers to the capacity of a porous, sediment, soil - or rock in this case - to transmit a fluid. This contrasts with a "conventional" gas reservoir produced from sands and carbonates (such as limestone). The bottom line is that in a conventional

  15. In the OSTI Collections: Oil Shales | OSTI, US Dept of Energy...

    Office of Scientific and Technical Information (OSTI)

    DoE, Office of Naval Petroleum and Oil Shale Reserves, U.S. Department of Energy (2004). ... on extraction of shale oil from the Green River Formation in Colorado, Utah, and Wyoming. ...

  16. Shale oil dearsenation process

    SciTech Connect (OSTI)

    Brickman, F.E.; Degnan, T.F.; Weiss, C.S.

    1984-10-29

    This invention relates to processing shale oil and in particular to processing shale oil to reduce the arsenic content. Specifically, the invention relates to treating shale oil by a combination of processes - coking and water washing. Many shale oils produced by conventional retorting processes contain inorganic materials, such as arsenic, which interfere with subsequent refining or catalytic hydroprocessing operations. Examples of these hydroprocessing operations are hydrogenation, denitrogenation, and desulfurization. From an environmental standpoint, removal of such contaminants may be desirable even if the shale oil is to be used directly as a fuel. Hence, it is desirable that contaminants such as arsenic be removed, or reduced to low levels, prior to further processing of the shale oil or prior to its use as a fuel.

  17. Shale Gas Glossary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glossary Shale Gas Glossary Shale Gas Glossary (286.97 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Modern Shale Gas Development in the United States: A Primer How is shale gas produced?

  18. Implementation of an anisotropic mechanical model for shale in Geodyn

    SciTech Connect (OSTI)

    Attaia, A.; Vorobiev, O.; Walsh, S.

    2015-05-15

    The purpose of this report is to present the implementation of a shale model in the Geodyn code, based on published rock material models and properties that can help a petroleum engineer in his design of various strategies for oil/gas recovery from shale rock formation.

  19. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  20. Water management practices used by Fayetteville shale gas producers.

    SciTech Connect (OSTI)

    Veil, J. A.

    2011-06-03

    Water issues continue to play an important role in producing natural gas from shale formations. This report examines water issues relating to shale gas production in the Fayetteville Shale. In particular, the report focuses on how gas producers obtain water supplies used for drilling and hydraulically fracturing wells, how that water is transported to the well sites and stored, and how the wastewater from the wells (flowback and produced water) is managed. Last year, Argonne National Laboratory made a similar evaluation of water issues in the Marcellus Shale (Veil 2010). Gas production in the Marcellus Shale involves at least three states, many oil and gas operators, and multiple wastewater management options. Consequently, Veil (2010) provided extensive information on water. This current study is less complicated for several reasons: (1) gas production in the Fayetteville Shale is somewhat more mature and stable than production in the Marcellus Shale; (2) the Fayetteville Shale underlies a single state (Arkansas); (3) there are only a few gas producers that operate the large majority of the wells in the Fayetteville Shale; (4) much of the water management information relating to the Marcellus Shale also applies to the Fayetteville Shale, therefore, it can be referenced from Veil (2010) rather than being recreated here; and (5) the author has previously published a report on the Fayetteville Shale (Veil 2007) and has helped to develop an informational website on the Fayetteville Shale (Argonne and University of Arkansas 2008), both of these sources, which are relevant to the subject of this report, are cited as references.

  1. World Shale Gas Resources: An Initial Assessment of 14 Regions Outside the United States

    Reports and Publications (EIA)

    2011-01-01

    The Energy Information Administration sponsored Advanced Resources International, Inc., to assess 48 gas shale basins in 32 countries, containing almost 70 shale gas formations. This effort has culminated in the report: World Shale Gas Resources: An Initial Assessment of 14 Regions Outside the United States.

  2. Manipulation of coupled osmotic flows for stabilisation of shales exposed to water-based drilling fluids

    SciTech Connect (OSTI)

    Oort, E. van; Hale, A.H.; Mody, F.K.

    1995-12-31

    Coupled osmotic flows have been studied as a means of stabilising shales exposed to water-based muds. The prime factor that governs the magnitude of chemical osmotic flow, i.e. the shale-fluid membrane efficiency, was investigated in detail. Its dependence on shale parameters, fluid parameters and external conditions was quantified. Membrane efficiency was found to increase with an increase in (hydrated) solute-to-pore-size ratio, with an increase in the shale`s high-surface area clay content and with a decrease shale permeability when increasing effective confining stress. Moreover, new drilling fluid chemistries for improving the efficiencies of low- and non-selective shale-fluid systems were identified. Induced osmotic flow with optimised shale-fluid membrane efficiencies in water-based environments is presented as a new strategy for improving wellbore stability in shales.

  3. Assessment of industry needs for oil shale research and development

    SciTech Connect (OSTI)

    Hackworth, J.H.

    1987-05-01

    Thirty-one industry people were contacted to provide input on oil shale in three subject areas. The first area of discussion dealt with industry's view of the shape of the future oil shale industry; the technology, the costs, the participants, the resources used, etc. It assessed the types and scale of the technologies that will form the industry, and how the US resource will be used. The second subject examined oil shale R D needs and priorities and potential new areas of research. The third area of discussion sought industry comments on what they felt should be the role of the DOE (and in a larger sense the US government) in fostering activities that will lead to a future commercial US oil shale shale industry.

  4. DOE - Office of Legacy Management -- Naval Oil Shale Reserves...

    Office of Legacy Management (LM)

    From the early 1940's through the early 1980's, the U.S. Department of Energy (DOE) conducted oil shale retort experiments in the Green River geologic formation. These retort ...

  5. Shale Reservoir Characterization

    Broader source: Energy.gov [DOE]

    Gas-producing shales are predominantly composed of consolidated clay-sized particles with a high organic content. High subsurface pressures and temperatures convert the organic matter to oil and...

  6. Technically Recoverable Shale Oil and Shale Gas Resources:

    Gasoline and Diesel Fuel Update (EIA)

    ... Source: Sachsenhofer et al., 2012 The Kovel-1 petroleum well is a key stratigraphic test ... have pursued shale gas leasing in Bulgaria but only one shale test well has been drilled. ...

  7. Technically Recoverable Shale Oil and Shale Gas Resources:

    Gasoline and Diesel Fuel Update (EIA)

    ... of the Paran Basin, although Amerisur Energy has discussed the shale potential of the ... Showing Flat-lying but Moderately Faulted Devonian Shale (Green) at Depths of 2 to 3 km. ...

  8. Process for oil shale retorting

    DOE Patents [OSTI]

    Jones, John B.; Kunchal, S. Kumar

    1981-10-27

    Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

  9. How is shale gas produced? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    How is shale gas produced? How is shale gas produced? How is shale gas produced? (3.81 MB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary Shale Gas Development Challenges: Fracture Fluids

  10. Natural Gas from Shale: Questions and Answers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shale: Questions and Answers Natural Gas from Shale: Questions and Answers Natural Gas from Shale: Questions and Answers (12.62 MB) More Documents & Publications Shale Gas Development Challenges: Fracture Fluids Shale Gas Glossary How is shale gas produced?

  11. Why is shale gas important? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Why is shale gas important? Why is shale gas important? Why is shale gas important? (1.27 MB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary How is shale gas produced?

  12. History of western oil shale

    SciTech Connect (OSTI)

    Russell, P.L.

    1980-01-01

    The history of oil shale in the United States since the early 1900's is detailed. Research on western oil shale probably began with the work of Robert Catlin in 1915. During the next 15 years there was considerable interest in the oil shales, and oil shale claims were located, and a few recovery plants were erected in Colorado, Nevada, Utah, Wyoming, and Montana. Little shale soil was produced, however, and the major oil companies showed little interest in producing shale oil. The early boom in shale oil saw less than 15 plants produce a total of less than 15,000 barrels of shale oil, all but about 500 barrels of which was produced by the Catlin Operation in Nevada and by the US Bureau of Mines Rulison, Colorado operation. Between 1930 and 1944 plentiful petroleum supplies at reasonable prices prevent any significant interest in shale oil, but oil shortages during World War II caused a resurgence of interest in oil shale. Between 1940 and 1969, the first large-scale mining and retorting operations in soil shale, and the first attempts at true in situ recovery of shale oil began. Only 75,000 barrels of shale oil were produced, but major advancements were made in developing mine designs and technology, and in retort design and technology. The oil embargo of 1973 together with a new offering of oil shale leases by the Government in 1974 resulted in the most concentrated efforts for shale oil production to date. These efforts and the future prospects for shale oil as an energy source in the US are discussed.

  13. Nineteenth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1986-01-01

    This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

  14. Oil shale retort apparatus

    DOE Patents [OSTI]

    Reeves, Adam A.; Mast, Earl L.; Greaves, Melvin J.

    1990-01-01

    A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

  15. Oil shale: Technology status report

    SciTech Connect (OSTI)

    Not Available

    1986-10-01

    This report documents the status of the US Department of Energy's (DOE) Oil Shale Program as of the end of FY 86. The report consists of (1) a status of oil shale development, (2) a description of the DOE Oil Shale Program, (3) an FY 86 oil shale research summary, and (4) a summary of FY 86 accomplishments. Discoveries were made in FY 86 about the physical and chemical properties and behavior of oil shales, process chemistry and kinetics, in situ retorting, advanced processes, and the environmental behavior and fate of wastes. The DOE Oil Shale Program shows an increasing emphasis on eastern US oil shales and in the development of advanced oil shale processing concepts. With the award to Foster Wheeler for the design of oil shale conceptual plants, the first step in the development of a systems analysis capability for the complete oil shale process has been taken. Unocal's Parachute Creek project, the only commercial oil shale plant operating in the United States, is operating at about 4000 bbl/day. The shale oil is upgraded at Parachute Creek for input to a conventional refinery. 67 refs., 21 figs., 3 tabs.

  16. West Virginia Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) West Virginia Shale Proved Reserves (Billion ... Shale Natural Gas Proved Reserves as of Dec. 31 West Virginia Shale Gas Proved Reserves, ...

  17. North Dakota Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) North Dakota Shale Proved Reserves (Billion ... Shale Natural Gas Proved Reserves as of Dec. 31 North Dakota Shale Gas Proved Reserves, ...

  18. Louisiana--North Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Louisiana--North Shale Proved Reserves (Billion ... Shale Natural Gas Proved Reserves as of Dec. 31 North Louisiana Shale Gas Proved Reserves, ...

  19. Fractured shale reservoirs: Towards a realistic model

    SciTech Connect (OSTI)

    Hamilton-Smith, T.

    1996-09-01

    Fractured shale reservoirs are fundamentally unconventional, which is to say that their behavior is qualitatively different from reservoirs characterized by intergranular pore space. Attempts to analyze fractured shale reservoirs are essentially misleading. Reliance on such models can have only negative results for fractured shale oil and gas exploration and development. A realistic model of fractured shale reservoirs begins with the history of the shale as a hydrocarbon source rock. Minimum levels of both kerogen concentration and thermal maturity are required for effective hydrocarbon generation. Hydrocarbon generation results in overpressuring of the shale. At some critical level of repressuring, the shale fractures in the ambient stress field. This primary natural fracture system is fundamental to the future behavior of the fractured shale gas reservoir. The fractures facilitate primary migration of oil and gas out of the shale and into the basin. In this process, all connate water is expelled, leaving the fractured shale oil-wet and saturated with oil and gas. What fluids are eventually produced from the fractured shale depends on the consequent structural and geochemical history. As long as the shale remains hot, oil production may be obtained. (e.g. Bakken Shale, Green River Shale). If the shale is significantly cooled, mainly gas will be produced (e.g. Antrim Shale, Ohio Shale, New Albany Shale). Where secondary natural fracture systems are developed and connect the shale to aquifers or to surface recharge, the fractured shale will also produce water (e.g. Antrim Shale, Indiana New Albany Shale).

  20. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, Richard G.; Walton, Otis R.; Lewis, Arthur E.; Braun, Robert L.

    1985-01-01

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

  1. Solar retorting of oil shale

    DOE Patents [OSTI]

    Gregg, David W.

    1983-01-01

    An apparatus and method for retorting oil shale using solar radiation. Oil shale is introduced into a first retorting chamber having a solar focus zone. There the oil shale is exposed to solar radiation and rapidly brought to a predetermined retorting temperature. Once the shale has reached this temperature, it is removed from the solar focus zone and transferred to a second retorting chamber where it is heated. In a second chamber, the oil shale is maintained at the retorting temperature, without direct exposure to solar radiation, until the retorting is complete.

  2. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

    1983-09-21

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

  3. World Shale Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deputy Administrator The U.S. has experienced a rapid increase in natural gas and oil production from shale and other tight resources 2 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0...

  4. Method for explosive expansion toward horizontal free faces for forming an in situ oil shale retort

    DOE Patents [OSTI]

    Ricketts, Thomas E.

    1980-01-01

    Formation is excavated from within a retort site in formation containing oil shale for forming a plurality of vertically spaced apart voids extending horizontally across different levels of the retort site, leaving a separate zone of unfragmented formation between each pair of adjacent voids. Explosive is placed in each zone, and such explosive is detonated in a single round for forming an in situ retort containing a fragmented permeable mass of formation particles containing oil shale. The same amount of formation is explosively expanded upwardly and downwardly toward each void. A horizontal void excavated at a production level has a smaller horizontal cross-sectional area than a void excavated at a lower level of the retort site immediately above the production level void. Explosive in a first group of vertical blast holes is detonated for explosively expanding formation downwardly toward the lower void, and explosive in a second group of vertical blast holes is detonated in the same round for explosively expanding formation upwardly toward the lower void and downwardly toward the production level void for forming a generally T-shaped bottom of the fragmented mass.

  5. Intergrated study of the Devonian-age black shales in eastern Ohio. Final report

    SciTech Connect (OSTI)

    Gray, J.D.; Struble, R.A.; Carlton, R.W.; Hodges, D.A.; Honeycutt, F.M.; Kingsbury, R.H.; Knapp, N.F.; Majchszak, F.L.; Stith, D.A.

    1982-09-01

    This integrated study of the Devonian-age shales in eastern Ohio by the Ohio Department of Natural Resources, Division of Geological Survey is part of the Eastern Gas Shales Project sponsored by the US Department of Energy. The six areas of research included in the study are: (1) detailed stratigraphic mapping, (2) detailed structure mapping, (3) mineralogic and petrographic characterization, (4) geochemical characterization, (5) fracture trace and lineament analysis, and (6) a gas-show monitoring program. The data generated by the study provide a basis for assessing the most promising stratigraphic horizons for occurrences of natural gas within the Devonian shale sequence and the most favorable geographic areas of the state for natural gas exploration and should be useful in the planning and design of production-stimulation techniques. Four major radioactive units in the Devonian shale sequence are believed to be important source rocks and reservoir beds for natural gas. In order of potential for development as an unconventional gas resource, they are (1) lower and upper radioactive facies of the Huron Shale Member of the Ohio Shale, (2) upper Olentangy Shale (Rhinestreet facies equivalent), (3) Cleveland Shale Member of the Ohio Shale, and (4) lower Olentangy Shale (Marcellus facies equivalent). These primary exploration targets are recommended on the basis of areal distribution, net thickness of radioactive shale, shows of natural gas, and drilling depth to the radioactive unit. Fracture trends indicate prospective areas for Devonian shale reservoirs. Good geological prospects in the Devonian shales should be located where the fracture trends coincide with thick sequences of organic-rich highly radioactive shale.

  6. In the OSTI Collections: Oil Shales | OSTI, US Dept of Energy Office of

    Office of Scientific and Technical Information (OSTI)

    Scientific and Technical Information Oil Shales Extraction Water Use History References Additional References Research Organizations Reports Available through OSTI's SciTech Connect Petroleum is commonly extracted from pores in rock formations below the earth's surface. Different kinds of rock have petroleum in their pores, but the petroleum is not part of the rock itself. Kerogen, another hydrocarbon material, is a constituent material of a type of rock called oil shale. While oil shales

  7. Shale gas - what happened? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    gas - what happened? Shale gas - what happened? It seems like shale gas came out of nowhere - what happened? (571.05 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Natural Gas from Shale Challenges associated with shale gas production

  8. Method of operating an oil shale kiln

    DOE Patents [OSTI]

    Reeves, Adam A.

    1978-05-23

    Continuously determining the bulk density of raw and retorted oil shale, the specific gravity of the raw oil shale and the richness of the raw oil shale provides accurate means to control process variables of the retorting of oil shale, predicting oil production, determining mining strategy, and aids in controlling shale placement in the kiln for the retorting.

  9. The twentieth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1987-01-01

    This book contains 20 selections. Some of the titles are: The technical contributions of John Ward Smith in oil shale research; Oil shale rubble fires: ignition and extinguishment; Fragmentation of eastern oil shale for in situ recovery; A study of thermal properties of Chinese oil shale; and Natural invasion of native plants on retorted oil shale.

  10. Validation Results for Core-Scale Oil Shale Pyrolysis

    SciTech Connect (OSTI)

    Staten, Josh; Tiwari, Pankaj

    2015-03-01

    This report summarizes a study of oil shale pyrolysis at various scales and the subsequent development a model for in situ production of oil from oil shale. Oil shale from the Mahogany zone of the Green River formation was used in all experiments. Pyrolysis experiments were conducted at four scales, powdered samples (100 mesh) and core samples of 0.75”, 1” and 2.5” diameters. The batch, semibatch and continuous flow pyrolysis experiments were designed to study the effect of temperature (300°C to 500°C), heating rate (1°C/min to 10°C/min), pressure (ambient and 500 psig) and size of the sample on product formation. Comprehensive analyses were performed on reactants and products - liquid, gas and spent shale. These experimental studies were designed to understand the relevant coupled phenomena (reaction kinetics, heat transfer, mass transfer, thermodynamics) at multiple scales. A model for oil shale pyrolysis was developed in the COMSOL multiphysics platform. A general kinetic model was integrated with important physical and chemical phenomena that occur during pyrolysis. The secondary reactions of coking and cracking in the product phase were addressed. The multiscale experimental data generated and the models developed provide an understanding of the simultaneous effects of chemical kinetics, and heat and mass transfer on oil quality and yield. The comprehensive data collected in this study will help advance the move to large-scale in situ oil production from the pyrolysis of oil shale.

  11. H. R. 1476: A bill to amend the Internal Revenue Code of 1986 to clarify the application of the credit for producing fuel from a nonconventional source with respect to gas produced from a tight formation and to make such credit permanent with respect to such gas and gas produced from Devonian shale. Introduced in the House of Representatives, One Hundredth First Congress, First Session, March 16, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The determination of whether gas is produced from geopressured brines, Devonian shales, coal seams, or a tight formation is made from section 503 of the Natural Gas Policy Act of 1978. Permanent credit is for gas produced from a tight formation or Devonian shale only and applies to gas sold after July 1, 1987. The credit allowed for any taxable year shall not exceed the sum of the regular tax reduced by the sum of other credits allowable under other subsections of the Internal Revenue Code.

  12. Assessment of oil-shale technology in Brazil. Final technical report, October 27, 1980-July 27, 1981

    SciTech Connect (OSTI)

    Not Available

    1981-07-27

    The development of an oil shale industry in the United States will require the solution of a variety of technical, economic, environmental, and health and safety problems. This assessment investigates whether US oil shale developers might benefit from the experience gained by the Brazilians in the operation of their Usina Prototipo do Irati oil shale demonstration plant at Sao Mateus do Sul, and from the data generated from their oil shale research and development programs. A chapter providing background information on Brazil and the Brazilian oil shale deposits is followed by an examination of the potential recovery processes applicable to Brazilian oil shale. The evolution of the Brazilian retorting system is reviewed and compared with the mining and retorting proposed for US shales. Factors impacting on the economics of shale oil production in Brazil are reviewed and compared to economic analyses of oil shale production in the US. Chapters examining the consequences of shale development in terms of impact on the physical environment and the oil shale worker complete the report. Throughout the report, where data permits, similarities and differences are drawn between the oil shale programs underway in Brazil and the US. In addition, research areas in which technology or information transfer could benefit either or both countries' oil shale programs are identified.

  13. Apparatus for oil shale retorting

    DOE Patents [OSTI]

    Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA); Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA)

    1986-01-01

    A cascading bed retorting process and apparatus in which cold raw crushed shale enters at the middle of a retort column into a mixer stage where it is rapidly mixed with hot recycled shale and thereby heated to pyrolysis temperature. The heated mixture then passes through a pyrolyzer stage where it resides for a sufficient time for complete pyrolysis to occur. The spent shale from the pyrolyzer is recirculated through a burner stage where the residual char is burned to heat the shale which then enters the mixer stage.

  14. Shale Gas Development Challenges: Air | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air Shale Gas Development Challenges: Air Shale Gas Development Challenges: Air (921.93 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Challenges associated with shale gas production How is shale gas produced?

  15. Shale Gas Development Challenges: Earthquakes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Earthquakes Shale Gas Development Challenges: Earthquakes Shale Gas Development Challenges: Induced Seismic Events (750.17 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Challenges associated with shale gas production Shale Gas Development Challenges: Fracture Fluids

  16. Shale Gas Development Challenges: Water | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Shale Gas Development Challenges: Water Shale Gas Development Challenges: Water (1003.99 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Development Challenges: Fracture Fluids Shale Gas Development Challenges: Air

  17. SciTech Connect: "oil shale"

    Office of Scientific and Technical Information (OSTI)

    oil shale" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "oil shale" Semantic Semantic Term Title: Full Text: Bibliographic Data: Creator ...

  18. Shale Research & Development | Department of Energy

    Energy Savers [EERE]

    Shale Research & Development Shale Research & Development UNCONVENTIONAL OIL AND NATURAL GAS America's abundant unconventional oil and gas (UOG) resources, which include natural ...

  19. Shale Gas Development Challenges: Surface Impacts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Surface Impacts Shale Gas Development Challenges: Surface Impacts Shale Gas Development Challenges: Surface Impacts (657.75 KB) More Documents & Publications Natural Gas from ...

  20. NATURAL GAS FROM SHALE: Questions and Answers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    These deposits occur in shale "plays" - a set of discovered, undiscovered or possible natural gas accumulations that exhibit similar geological characteristics. Shale plays are ...

  1. Oil shale: The environmental challenges III

    SciTech Connect (OSTI)

    Petersen, K.K.

    1983-01-01

    This book presents the papers of a symposium whose purpose was to discuss the environmental and socio-economic aspects of oil shale development. Topics considered include oil shale solid waste disposal, modeling spent shale disposal, water management, assessing the effects of oil shale facilities on water quality, wastewater treatment and use at oil shale facilities, potential air emissions from oil shale retorting, the control of air pollutant emissions from oil shale facilities, oil shale air emission control, socioeconomic research, a framework for mitigation agreements, the Garfield County approach to impact mitigation, the relationship of applied industrial hygiene programs and experimental toxicology programs, and industrial hygiene programs.

  2. In situ method for recovering hydrocarbon from subterranean oil shale deposits

    SciTech Connect (OSTI)

    Friedman, R.H.

    1987-11-03

    This patent describes in situ method for recovering hydrocarbons from subterranean oil shale deposits, the deposits comprising mineral rock and kerogen, comprising (a) penetrating the oil shale deposit with at least one well; (b) forming a zone of fractured and/or rubbilized oil shale material adjacent the well by hydraulic or explosive fracturing; (c) introducing a hydrogen donor solvent including tetralin into the portion of the oil shale formation treated in step (b) in a volume sufficient to fill substantially all of the void space created by the fracturing and rubbilizing treatment; (d) applying hydrogen to the tetralin and maintaining a predetermined pressure for a predetermined period of time sufficient to cause disintegration of the oil shale material; (e) thereafter introducing an oxidative environment into the portion of the oil shale deposit (f) producing the solvent in organic fragments to the surface of the earth, and (g) separating the organic fragments from the solvent.

  3. Gas seal for an in situ oil shale retort and method of forming thermal barrier

    DOE Patents [OSTI]

    Burton, III, Robert S.

    1982-01-01

    A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

  4. Geologic analysis of Devonian Shale cores

    SciTech Connect (OSTI)

    1982-02-01

    Cleveland Cliffs Iron Company was awarded a DOE contract in December 1977 for field retrieval and laboratory analysis of cores from the Devonian shales of the following eleven states: Michigan, Illinois, Indiana, Ohio, New York, Pennsylvania, West Virginia, Maryland, Kentucky, Tennessee and Virginia. The purpose of this project is to explore these areas to determine the amount of natural gas being produced from the Devonian shales. The physical properties testing of the rock specimens were performed under subcontract at Michigan Technological University (MTU). The study also included LANDSAT information, geochemical research, structural sedimentary and tectonic data. Following the introduction, and background of the project this report covers the following: field retrieval procedures; laboratory procedures; geologic analysis (by state); references and appendices. (ATT)

  5. Assessment of industry needs for oil shale research and development. Final report

    SciTech Connect (OSTI)

    Hackworth, J.H.

    1987-05-01

    Thirty-one industry people were contacted to provide input on oil shale in three subject areas. The first area of discussion dealt with industry`s view of the shape of the future oil shale industry; the technology, the costs, the participants, the resources used, etc. It assessed the types and scale of the technologies that will form the industry, and how the US resource will be used. The second subject examined oil shale R&D needs and priorities and potential new areas of research. The third area of discussion sought industry comments on what they felt should be the role of the DOE (and in a larger sense the US government) in fostering activities that will lead to a future commercial US oil shale shale industry.

  6. Pressurized fluidized-bed hydroretorting of Eastern oil shales. Progress report, December 1991--February 1992

    SciTech Connect (OSTI)

    Lau, F.S.; Mensinger, M.C.; Roberts, M.J.; Rue, D.M.

    1992-03-01

    The objective is to perform the research necessary to develop the pressurized fluidized-bed hydroretorting (PFH) process for producing oil from Easter oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. Accomplishments for this period are presented for the following tasks: Testing of Process Improvement Concepts; Beneficiation Research; Operation of PFH on Beneficiated Shale; Environmental Data and Mitigation Analyses; Sample Procurement, Preparation, and Characterization; and Project Management and Reporting. 24 figs., 19 tabs. (AT)

  7. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  8. Favorable conditions noted for Australia shale oil

    SciTech Connect (OSTI)

    Not Available

    1986-09-01

    After brief descriptions of the Rundle, Condor, and Stuart/Kerosene Creek oil shale projects in Queensland, the competitive advantages of oil shale development and the state and federal governments' attitudes towards an oil shale industry in Australia are discussed. It is concluded that Australia is the ideal country in which to start an oil shale industry.

  9. Method for closing a drift between adjacent in situ oil shale retorts

    DOE Patents [OSTI]

    Hines, Alex E.

    1984-01-01

    A row of horizontally spaced-apart in situ oil shale retorts is formed in a subterranean formation containing oil shale. Each row of retorts is formed by excavating development drifts at different elevations through opposite side boundaries of a plurality of retorts in the row of retorts. Each retort is formed by explosively expanding formation toward one or more voids within the boundaries of the retort site to form a fragmented permeable mass of formation particles containing oil shale in each retort. Following formation of each retort, the retort development drifts on the advancing side of the retort are closed off by covering formation particles within the development drift with a layer of crushed oil shale particles having a particle size smaller than the average particle size of oil shale particles in the adjacent retort. In one embodiment, the crushed oil shale particles are pneumatically loaded into the development drift to pack the particles tightly all the way to the top of the drift and throughout the entire cross section of the drift. The closure between adjacent retorts provided by the finely divided oil shale provides sufficient resistance to gas flow through the development drift to effectively inhibit gas flow through the drift during subsequent retorting operations.

  10. Method for closing a drift between adjacent in-situ oil shale retorts

    SciTech Connect (OSTI)

    Hines, A.E.

    1984-04-10

    A row of horizontally spaced-apart in situ oil shale retorts is formed in a subterranean formation containing oil shale. Each row of retorts is formed by excavating development drifts at different elevations through opposite side boundaries of a plurality of retorts in the row of retorts. Each retort is formed by explosively expanding formation toward one or more voids within the boundaries of the retort site to form a fragmented permeable mass of formation particles containing oil shale in each retort. Following formation of each retort, the retort development drifts on the advancing side of the retort are closed off by covering formation particles within the development drift with a layer of crushed oil shale particles having a particle size smaller than the average particle size of oil shale particles in the adjacent retort. In one embodiment, the crushed oil shale particles are pneumatically loaded into the development drift to pack the particles tightly all the way to the top of the drift and throughout the entire cross section of the drift. The closure between adjacent retorts provided by the finely divided oil shale provides sufficient resistance to gas flow through the development drift to effectively inhibit gas flow through the drift during subsequent retorting operations.

  11. Pores in Marcellus Shale: A Neutron Scattering and FIB-SEM Study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gu, Xin; Cole, David R.; Rother, Gernot; Mildner, David F. R.; Brantley, Susan L.

    2015-01-26

    The production of natural gas has become more and more important in the United States because of the development of hydraulic fracturing techniques, which significantly increase the permeability and fracture network of black shales. The pore structure of shale is a controlling factor for hydrocarbon storage and gas migration. In this work, we investigated the porosity of the Union Springs (Shamokin) Member of the Marcellus Formation from a core drilled in Centre County, PA, USA, using ultrasmall-angle neutron scattering (USANS), small-angle neutron scattering (SANS), focused ion beam scanning electron microscopy (FIB-SEM), and nitrogen gas adsorption. The scattering of neutrons bymore » Marcellus shale depends on the sample orientation: for thin sections cut in the plane of bedding, the scattering pattern is isotropic, while for thin sections cut perpendicular to the bedding, the scattering pattern is anisotropic. The FIB-SEM observations allow attribution of the anisotropic scattering patterns to elongated pores predominantly associated with clay. The apparent porosities calculated from scattering data from the bedding plane sections are lower than those calculated from sections cut perpendicular to the bedding. A preliminary method for estimating the total porosity from the measurements made on the two orientations is presented. This method is in good agreement with nitrogen adsorption for both porosity and specific surface area measurements. Neutron scattering combined with FIB-SEM reveals that the dominant nanosized pores in organic-poor, clay-rich shale samples are water-accessible sheetlike pores within clay aggregates. In contrast, bubble-like organophilic pores in kerogen dominate organic-rich samples. Lastly, developing a better understanding of the distribution of the water-accessible pores will promote more accurate models of water–mineral interactions during hydrofracturing.« less

  12. Pores in Marcellus Shale: A Neutron Scattering and FIB-SEM Study

    SciTech Connect (OSTI)

    Gu, Xin; Cole, David R.; Rother, Gernot; Mildner, David F. R.; Brantley, Susan L.

    2015-01-26

    The production of natural gas has become more and more important in the United States because of the development of hydraulic fracturing techniques, which significantly increase the permeability and fracture network of black shales. The pore structure of shale is a controlling factor for hydrocarbon storage and gas migration. In this work, we investigated the porosity of the Union Springs (Shamokin) Member of the Marcellus Formation from a core drilled in Centre County, PA, USA, using ultrasmall-angle neutron scattering (USANS), small-angle neutron scattering (SANS), focused ion beam scanning electron microscopy (FIB-SEM), and nitrogen gas adsorption. The scattering of neutrons by Marcellus shale depends on the sample orientation: for thin sections cut in the plane of bedding, the scattering pattern is isotropic, while for thin sections cut perpendicular to the bedding, the scattering pattern is anisotropic. The FIB-SEM observations allow attribution of the anisotropic scattering patterns to elongated pores predominantly associated with clay. The apparent porosities calculated from scattering data from the bedding plane sections are lower than those calculated from sections cut perpendicular to the bedding. A preliminary method for estimating the total porosity from the measurements made on the two orientations is presented. This method is in good agreement with nitrogen adsorption for both porosity and specific surface area measurements. Neutron scattering combined with FIB-SEM reveals that the dominant nanosized pores in organic-poor, clay-rich shale samples are water-accessible sheetlike pores within clay aggregates. In contrast, bubble-like organophilic pores in kerogen dominate organic-rich samples. Lastly, developing a better understanding of the distribution of the water-accessible pores will promote more accurate models of water–mineral interactions during hydrofracturing.

  13. Geologic framework of the Jurassic (Oxfordian) Smackover Formation the Alabama coastal waters area

    SciTech Connect (OSTI)

    Tew, B.H.; Mancini, E.A. ); Mink R.M.; Mann, S.D. ); Mancini, E.A.

    1993-09-01

    The Jurassic (Oxfordian) Smackover Formation is a prolific hydrocarbon-producing geologic unit in the onshore Gulf of Mexico area, including southwest Alabama. However, no Smackover strata containing commercial accumulations of oil or gas have thus far been discovered in the Alabama state coastal waters area (ACW). This study of the regional geologic framework of the Smackover Formation was done to characterize the unit in the ACW and to compare strata in the ACW with productive Smackover intervals in the onshore area. In the study area, the Smackover Formation was deposited on a highly modified carbonate associated with pre-Smackover topographic features. In the onshore Alabama, north of the Wiggins arch complex, an inner ramp developed in the area of the Mississippi interior salt basin and the Manila and Conecuh embayments. South of the Wiggins arch complex in extreme southern onshore Alabama and in the ACW, an outer ramp formed that was characterized by a much thicker Smackover section. In the outer ramp setting, four lithofacies associations are recognized: lower, middle, and upper outer ramp lithofacies (ORL) and the coastal dolostone lithofacies. The coastal dolostone lithofacies accounts for most of the reservoir-grade porosity in the outer ramp setting. The lower, middle, and upper ORL, for the most part, are nonporous. Volumetrically, intercrystalline porosity is the most important pore type in the coastal dolostone lithofacies. Numerous data in the ACW area indicate that halokinesis has created structural conditions favorable for accumulation and entrapment of oil and gas in the outer ramp lithofacies of the Smackover. Prolific hydrocarbon source rocks are present in the ACW, as evidenced by the significant natural gas accumulations in the Norphlet Formation. To date, however, reservoir quality rocks of the coastal dolostone lithofacies coincident with favorable structural conditions have not been encountered in the ACW.

  14. Natural Gas from Shale | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shale Natural Gas from Shale Office of Fossil Energy research helped refine cost-effective horizontal drilling and hydraulic fracturing technologies, protective environmental practices and data development, making hundreds of trillions of cubic feet of gas technically recoverable where they once were not. Fossil Energy Research Benefits - Natural Gas from Shale (697.8 KB) More Documents & Publications Shale gas - what happened? Shale Gas Glossary Return on Investment

  15. Carbon sequestration in depleted oil shale deposits

    SciTech Connect (OSTI)

    Burnham, Alan K; Carroll, Susan A

    2014-12-02

    A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

  16. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    ... the La Luna-1 stratigraphic test in the MMVB later that year (results not disclosed). ... ConocoPhillips expects to drill its first exploration well to test the La Luna Shale in ...

  17. Oil Shale and Other Unconventional Fuels Activities | Department...

    Office of Environmental Management (EM)

    Naval Reserves Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on ...

  18. Secure Fuels from Domestic Resources - Oil Shale and Tar Sands...

    Office of Environmental Management (EM)

    Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Profiles of Companies Engaged in Domestic Oil Shale ...

  19. New Mexico Shale Proved Reserves (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves (Billion Cubic Feet) New Mexico Shale Proved Reserves (Billion Cubic Feet) ... Shale Natural Gas Proved Reserves as of Dec. 31 New Mexico Shale Gas Proved Reserves, ...

  20. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Algeria Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  1. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Argentina Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  2. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Australia Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  3. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Canada Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  4. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Chad Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  5. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    China Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  6. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Eastern Europe Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or

  7. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Egypt Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  8. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    India and Pakistan Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or

  9. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Indonesia Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  10. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Jordan Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  11. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Kazakhstan Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  12. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Libya Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  13. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Mexico Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  14. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Morocco Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  15. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Northern South America Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or

  16. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Western Europe Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or

  17. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Oman Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  18. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    South America Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee

  19. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Poland Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  20. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Russia Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  1. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    South Africa Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee

  2. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Spain Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  3. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Thailand Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  4. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Tunisia Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  5. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Turkey Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the

  6. Technically Recoverable Shale Oil and Shale Gas Resources:

    U.S. Energy Information Administration (EIA) Indexed Site

    Kingdom Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 September 2015 September 2015 U.S. Energy Information Administration | Technically Recoverable Shale Oil and Shale Gas Resources i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of

  7. Nondestructive analysis of oil shales with PGNAA technique

    SciTech Connect (OSTI)

    Maly, J.; Bozorgmanesh, H.

    1984-02-01

    The feasibility of nondestructive analysis of oil shales using the prompt gamma neutron activation analysis (PGNAA) technique was studied. The PGNAA technique, developed originally for continuous analysis of coal on the belt, was applied to the analysis of eight oil-shale samples, containing between 9 and 60 gallons of oil per ton and 0.8% to 3.4% hydrogen. The PGNAA technique was modified using four neutron moderation conditions: non-moderated neutrons; non-moderated and partially moderated neutrons reflected from a water box behind the source; neutrons moderated in a water box behind and in front of the source; and neutrons strongly moderated in a polyethylene block placed in front of the source and with reflected neutrons from a water box behind the source. The studied oil shales were measured in their aluminum or wooden (masonite) boxes. The obtained Ge-Li spectra were processed by LSI-11/23 computer, using the modified programs previously developed by SAI for continuous coal analysis. The results of such processing (the peak areas for several gamma lines) were corrected and plotted against the weight percent of each analyzed element (from the chemical analysis). Response curves developed for H, C, N, S, Na, Mg, Al, Si, Ti, Ca, Fe and K show generally good linear proportions of peak area to the weight percent of the element. For hydrogen determination, NMD conditions had to be used where the response curve was not linear, but followed a curve whose slope rose with hydrogen concentration. This effect is caused by improving neutron self-moderation in sample boxes of rich oil shales, as compared to poor self-moderation of neutrons in very lean oil shales. The moisture in oil shales was measured by microwave absorption technique in small masonite boxes. This method was calibrated four times using oil-shale samples mixed gradually with larger and larger amounts of water.

  8. New Albany shale flash pyrolysis under hot-recycled-solid conditions: Chemistry and kinetics, II

    SciTech Connect (OSTI)

    Coburn, T.T.; Morris, C.J.

    1990-11-01

    The authors are continuing a study of recycle retorting of eastern and western oil shales using burnt shale as the solid heat carrier. Stripping of adsorbed oil from solid surfaces rather than the primary pyrolysis of kerogen apparently controls the release rate of the last 10--20% of hydrocarbons. Thus, the desorption rate defines the time necessary for oil recovery from a retort and sets the minimum hold-time in the pyrolyzer. A fluidized-bed oil shale retort resembles a fluidized-bed cat cracker in this respect. Recycled burnt shale cokes oil and reduces yield. The kerogen H/C ratio sets an upper limit on yield improvements unless external hydrogen donors are introduced. Steam can react with iron compounds to add to the H-donor pool. Increased oil yield when New Albany Shale pyrolyzes under hot-recycled-solid, steam-fluidization conditions has been confirmed and compared with steam retorting of acid-leached Colorado oil shale. In addition, with retorted, but unburnt, Devonian shale present at a recycle ratio of 3, the authors obtain 50% more oil-plus-gas than with burnt shale present. Procedures to make burnt shale more like unburnt shale can realize some increase in oil yield at high recycle ratios. Reduction with H{sub 2} and carbon deposition are possibilities that the authors have tested in the laboratory and can test in the pilot retort. Also, eastern spent shale burned at a high temperature (775 C, for example) cokes less oil than does spent shale burned at a low temperature (475 C). Changes in surface area with burn temperature contribute to this effect. 15 refs., 8 figs., 4 tabs.

  9. NATURAL GAS FROM SHALE: Questions and Answers It Seems Like Shale...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    It Seems Like Shale Gas Came Out of Nowhere - What Happened? Knowledge of gas shale resources and even production techniques has been around a long time (see "Technological ...

  10. Geological and geophysical evaluation of the Naricual Formation, Musipan-El Carito area, eastern Venezuela basin

    SciTech Connect (OSTI)

    Abud, J.; Oviedo, P.; Hernandex, J.; Garcia, E.; Escalona, N. )

    1990-05-01

    The recent giant oil discoveries in the lower Tertiary sedimentary sequence of the Monagas overthrust belt, Eastern Venezuela basin require short- and medium-term development plans based on technical production geological studies and models. The present study consists of a detailed geological and geophysical evaluation to define the reservoir in the producing Naricual Formation in the Musipan-El Carito areas, located west of El Furrial oil field. Due to its geological and reservoir characteristics, the northern Monagas area is considered as the top priority production alternative for the Venezuelan oil industry for the next 20 yr. The structural pattern of the area is related to major compressional stress applied northwest and from the northeast. Two fault systems are associated with this compression: (1) first-order, east-west-trending reverse faults dipping to the north, and (2) second-order, north-south-trending right-lateral strike-slip faults. The proposed sedimentological model is that of a paleodelta prograding from north to south. The depositional environment ranges from internal to continental shelf (barrier bars, tidal and distributary channels, lagoonal and associated facies). The STOIP in the Naricual Formation is 4.8 billion bbls, 52% of which is light-grade oil and 48% is medium-grade oil. The results of reservoir pressure analyses suggest lateral communication within the Naricual Formation between the Furrial and Musipan areas and give evidence of a permeability barrier between the Furrial-Musipan and El Carito areas. Depth vs. API gravity plots indicate a direct relationship between crude oil type and depth. The application of the results of the integrated reservoir studies gives precise answers to the production behavior of wells. An adjusted development plan is now under way to guarantee a rational, optimum recovery of the oil reserves.

  11. Pressurized fluidized-bed hydroretorting of Eastern oil shales

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S. ); Schultz, C.W. ); Parekh, B.K. ); Misra, M. ); Bonner, W.P. )

    1992-11-01

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

  12. Combuston method of oil shale retorting

    DOE Patents [OSTI]

    Jones, Jr., John B.; Reeves, Adam A.

    1977-08-16

    A gravity flow, vertical bed of crushed oil shale having a two level injection of air and a three level injection of non-oxygenous gas and an internal combustion of at least residual carbon on the retorted shale. The injection of air and gas is carefully controlled in relation to the mass flow rate of the shale to control the temperature of pyrolysis zone, producing a maximum conversion of the organic content of the shale to a liquid shale oil. The parameters of the operation provides an economical and highly efficient shale oil production.

  13. Pyrolysis and hydrocarbon source bed potential of the Upper Devonian Woodford Shale, Hovey Channel, southern Permian basin, west Texas

    SciTech Connect (OSTI)

    Hussain, M.; Bloom, M.A. )

    1991-03-01

    The Upper Devonian Woodford Shale in the Hovey Channel area, southern Permian basin, is 50 m thick and composed largely of brown to black, pyritic, spore-bearing, organic-rich, fissile shale an chert. Total organic carbon, distillable hydrocarbons, genetic potential, organic carbon index, hydrogen index, temperature of maximum hydrocarbon generation, and kerogen transformation index of the Woodford Shale suggest a matured to overmatured, gas-generating source bed. The total organic carbon content of the formation ranged from a low of 0.77% in the cherty samples to a high of 4.59% in a shaley sample, averaging 2.18%. Distillable hydrocarbon content of the samples is fairly high (averaging 1.72 mg HC/gm{degree} rock), varying from 0.90 mg HC/gm{degree} rock to 3.22 mg HC/gm{degree} rock. Genetic potential evaluated in terms of both residual and total generative potential showed above average potential, averaging 3.25 mg HC/gm{degree} rock for the residual and 4.90 mg HC/gm{degree} rock for the total, respectively. Live organic carbon index values ranged from 11-28%, characterizing the formation as a moderate to good source bed. Hydrogen index values ranged from 73 mg HC/gm{degree} C org to 155 mg HC/gm{degree} C org, suggesting overmaturity and gas-generation potential of the source bed. Temperature of maximum hydrocarbon generation values and kerogen transformation ratio values (averaging 0.34) also indicate overmatured nature of the Woodford Shale.

  14. Influence of frequency, grade, moisture and temperature on Green River oil shale dielectric properties and electromagnetic heating processes

    SciTech Connect (OSTI)

    Hakala, J. Alexandra [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Stanchina, William [Univ. of Pittsburgh, PA (United States); National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Soong, Yee [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Hedges, Sheila [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

    2011-01-01

    Development of in situ electromagnetic (EM) retorting technologies and design of specific EM well logging tools requires an understanding of various process parameters (applied frequency, mineral phases present, water content, organic content and temperature) on oil shale dielectric properties. In this literature review on oil shale dielectric properties, we found that at low temperatures (<200 C) and constant oil shale grade, both the relative dielectric constant (?') and imaginary permittivity (?'') decrease with increased frequency and remain constant at higher frequencies. At low temperature and constant frequency, ?' decreases or remains constant with oil shale grade, while ?'' increases or shows no trend with oil shale grade. At higher temperatures (>200 C) and constant frequency, epsilon' generally increases with temperature regardless of grade while ?'' fluctuates. At these temperatures, maximum values for both ?' and ?'' differ based upon oil shale grade. Formation fluids, mineral-bound water, and oil shale varve geometry also affect measured dielectric properties. This review presents and synthesizes prior work on the influence of applied frequency, oil shale grade, water, and temperature on the dielectric properties of oil shales that can aid in the future development of frequency- and temperature-specific in situ retorting technologies and oil shale grade assay tools.

  15. Characterization of raw and burnt oil shale from Dotternhausen: Petrographical and mineralogical evolution with temperature

    SciTech Connect (OSTI)

    Thiéry, Vincent; Bourdot, Alexandra; Bulteel, David

    2015-08-15

    The Toarcian Posidonia shale from Dotternhausen, Germany, is quarried and burnt in a fluidized bed reactor to produce electricity. The combustion residue, namely burnt oil shale (BOS), is used in the adjacent cement work as an additive in blended cements. The starting material is a typical laminated oil shale with an organic matter content ranging from 6 to 18%. Mineral matter consists principally of quartz, feldspar, pyrite and clays. After calcination in the range, the resulting product, burnt oil shale, keeps the macroscopic layered texture however with different mineralogy (anhydrite, lime, iron oxides) and the formation of an amorphous phase. This one, studied under STEM, reveals a typical texture of incipient partial melting due to a long retention time (ca. 30 min) and quenching. An in-situ high temperature X-ray diffraction (HTXRD) allowed studying precisely the mineralogical changes associated with the temperature increase. - Highlights: • We present oil shale/burnt oil shale characterization. • The Posidonia Shale is burnt in a fluidized bed. • Mineralogical evolution with temperature is complex. • The burnt oil shale is used in composite cements.

  16. Regional geology and petroleum potential of Bakken Formation, southwestern Manitoba

    SciTech Connect (OSTI)

    Martiniuk, C.D.

    1988-07-01

    The Bakken Formation has been documented as an excellent petroleum source rock within the Williston basin and has, in some localities, been established as a producing zone. Recent exploration in the Daly field of southwestern Manitoba has led to the discovery and subsequent development of several oil pools within the middle member of the Bakken. The 21 active wells within these pools have produced 20,773.8 m/sup 3/ (130,667.2 bbl) of oil (40.2/degrees/ API) as of December 31, 1987. Through much of the Williston basin, the Bakken typically consists of three members: a lower, highly radioactive, black shale member; a middle siltstone member; and an upper black shale member (identical to the lower member). In southwestern Manitoba, the lower member is absent in most areas due to nondeposition and overstep of the overlying middle member. In these areas, the middle member unconformably overlies eroded red dolomitic shales of the Devonian Lyleton (Three Forks) Formation. The middle member is a relatively uniform blanket deposit averaging 4 m (13 ft) thick. It consists of interbedded tan to greenish-gray, very fine to medium-grained, well-sorted dolomitic sandstone and siltstone with angular to subrounded grains. Oil accumulation in the middle member is largely the result of stratigraphic trapping and appears, in part, to be localized where a basal sandstone (associated with middle member thickening) is concentrated in minor erosional lows on the Lyleton surface. The black shales of the upper member form a thin (2 m or 6.6 ft average), uniform cap throughout the map area and are overlain by the carbonates of the Mississippian Lodgepole Formation (Souris Valley Beds). Maximum thickness of the Bakken reaches 32 m (105 ft) in the Waskada field area, where the lower shale member is locally present.

  17. Challenges associated with shale gas production | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Challenges associated with shale gas production Challenges associated with shale gas production What challenges are associated with shale gas production? (1012.02 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Development Challenges: Air Shale Gas Development Challenges: Fracture Fluids

  18. Evaluation of Devonian-shale potential in Ohio

    SciTech Connect (OSTI)

    Komar, C. A.

    1981-01-01

    The purpose of this report is to inform interested oil and gas operators about EGSP results as they pertain to the Devonian gas shales of the Appalachian basin in eastern Ohio. Geologic data and interpretations are summarized, and areas where the accumulation of gas may be large enough to justify commercial production are outlined. Because the data presented in this report are generalized and not suitable for evaluation of specific sites for exploration, the reader should consult the various reports cited for more detail and discussion of the data, concepts, and interpretations presented. A complete list of EGSP sponsored work pertinent to the Devonian shales in Ohio is contained as an appendix to this report. Radioactive shale zones are also mapped.

  19. Eastern States Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Shale Production (Billion Cubic Feet) Eastern States Shale Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 2 2 -...

  20. Pennsylvania Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Shale Production (Billion Cubic Feet) Pennsylvania Shale Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 1 1 65...

  1. Colorado Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Colorado Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0...

  2. North Dakota Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Shale Production (Billion Cubic Feet) North Dakota Shale Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 3 3 25...

  3. Gas Shale Plays? The Global Transition

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    in TOC, thermally mature in the gas to oil windows, and among the most prospective in Europe for shale development. Figure VIII-5 exhibits organic-rich shales that are typically...

  4. Method for forming an in situ oil shale retort with horizontal free faces

    DOE Patents [OSTI]

    Ricketts, Thomas E.; Fernandes, Robert J.

    1983-01-01

    A method for forming a fragmented permeable mass of formation particles in an in situ oil shale retort is provided. A horizontally extending void is excavated in unfragmented formation containing oil shale and a zone of unfragmented formation is left adjacent the void. An array of explosive charges is formed in the zone of unfragmented formation. The array of explosive charges comprises rows of central explosive charges surrounded by a band of outer explosive charges which are adjacent side boundaries of the retort being formed. The powder factor of each outer explosive charge is made about equal to the powder factor of each central explosive charge. The explosive charges are detonated for explosively expanding the zone of unfragmented formation toward the void for forming the fragmented permeable mass of formation particles having a reasonably uniformly distributed void fraction in the in situ oil shale retort.

  5. NATURAL GAS FROM SHALE: Questions and Answers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Challenges are Associated with Shale Gas Production? Developing any energy resource - whether conventional or non-conventional like shale - carries with it the possibility and risk of environmental, public health, and safety issues. Some of the challenges related to shale gas production and hydraulic fracturing include: * Increased consumption of fresh water (volume and sources); * Induced seismicity (earthquakes) from shale flowback water disposal;Chemical disclosure of fracture fluid

  6. Oil shale technology. Final report

    SciTech Connect (OSTI)

    NONE

    1995-03-01

    This collaborative project with industrial participants studied oil shale retorting through an integrated program of fundamental research, mathematical model development and operation of a 4-tonne-per-day solid recirculation oil shale test unit. Quarterly, project personnel presented progress and findings to a Project Guidance Committee consisting of company representatives and DOE program management. We successfully operated the test unit, developed the oil shale process (OSP) mathematical model, evaluated technical plans for process scale up and determined economics for a successful small scale commercial deployment, producing premium motor fuel, specility chemicals along with electricity co-production. In budget negotiations, DOE funding for this three year CRADA was terminated, 17 months prematurely, as of October 1993. Funds to restore the project and continue the partnership have not been secured.

  7. Australian developments in oil shale processing

    SciTech Connect (OSTI)

    Baker, G.L.

    1981-01-01

    This study gives some background on Australian oil shale deposits, briefly records some history of oil shale processing in the country and looks at the current status of the various proposals being considered to produce syncrudes from Australian oil shales. 5 refs.

  8. Oil shale technology and evironmental aspects

    SciTech Connect (OSTI)

    Scinta, J.

    1982-01-01

    Oil shale processes are a combination of mining, retorting, and upgrading facilities. This work outlines the processing steps and some design considerations required in an oil shale facility. A brief overview of above ground and in situ retorts is presented; 6 retorts are described. The development aspects which the oil shale industry is addressing to protect the environment are presented.

  9. High efficiency shale oil recovery

    SciTech Connect (OSTI)

    Adams, D.C.

    1992-01-01

    The overall project objective is to demonstrate the high efficiency of the Adams Counter-Current shale oil recovery process. The efficiency will first be demonstrated on a small scale, in the current phase, after which the demonstration will be extended to the operation of a small pilot plant. Thus the immediate project objective is to obtain data on oil shale retorting operations in a small batch rotary kiln that will be representative of operations in the proposed continuous process pilot plant. Although an oil shale batch sample is sealed in the batch kiln from the start until the end of the run, the process conditions for the batch are the same as the conditions that an element of oil shale would encounter in a continuous process kiln. Similar chemical and physical (heating, mixing) conditions exist in both systems. The two most important data objectives in this phase of the project are to demonstrate (1) that the heat recovery projected for this project is reasonable and (2) that an oil shale kiln will run well and not plug up due to sticking and agglomeration. The following was completed and is reported on this quarter: (1) A software routine was written to eliminate intermittently inaccurate temperature readings. (2) We completed the quartz sand calibration runs, resolving calibration questions from the 3rd quarter. (3) We also made low temperature retorting runs to identify the need for certain kiln modifications and kiln modifications were completed. (4) Heat Conductance data on two Pyrolysis runs were completed on two samples of Occidental oil shale.

  10. DOE Gas Hydrate R&D: Shale Gas Déjà Vu?

    Office of Energy Efficiency and Renewable Energy (EERE)

    More than 30 years ago, DOE looked into the future and saw the potentially large benefit of developing promising but difficult-to-extract unconventional natural gas resources, particularly those from shale formations. As a result, it began sponsoring research and development (R&D), partnering with industry and academia, and, among other things, invested about $137 million in the Eastern Gas Shale Program between 1978 and 1992.

  11. Sulfide-Driven Arsenic Mobilization from Arsenopyrite and Black Shale Pyrite

    SciTech Connect (OSTI)

    Zhu, W.; Young, L; Yee, N; Serfes, M; Rhine, E; Reinfelder, J

    2008-01-01

    We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As-1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O2), hypoxic (2% O2, 98% N2), and anoxic (5% H2, 95% N2) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (-1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black

  12. Oil-shale utilization at Morgantown, WV

    SciTech Connect (OSTI)

    Shang, J.Y.; Notestein, J.E.; Mei, J.S.; Romanosky, R.R.; King, J.A.; Zeng, L.W.

    1982-01-01

    Fully aware of the nation's need to develop high-risk and long-term research in eastern oil-shale and low-grade oil-shale utilization in general, the US DOE/METC initiated an eastern oil-shale characterization program. In less than 3 months, METC produced shale oil from a selected eastern-US oil shale with a Fischer assay of 8.0 gallons/ton. In view of the relatively low oil yield from this particular oil shale, efforts were directed to determine the process conditions which give the highest oil yield. A 2-inch-diameter electrically heated fluidized-bed retort was constructed, and Celina oil shale from Tennessee was selected to be used as a representative eastern oil shale. After more than 50 runs, the retorting data were analyzed and reviewed and the best oil-yield operating condition was determined. In addition, while conducting the oil-shale retorting experiments, a number of technical problems were identified, addressed, and overcome. Owing to the inherent high rates of heat and mass transfers inside the fluidized bed, the fluidized-bed combustor and retorting appear to be a desirable process technology for an effective and efficient means for oil-shale utilization. The fluidized-bed operation is a time-tested, process-proven, high-throughput, solid-processing operation which may contribute to the efficient utilization of oil-shale energy.

  13. Jordan ships oil shale to China

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Jordan and China have signed an agreement to develop oil shale processing technology that could lead to a 200 ton/day oil shale plant in Jordan. China will process 1200 tons of Jordanian oil shale at its Fu Shun refinery. If tests are successful, China could build the demonstration plant in Jordan's Lajjun region, where the oil shale resource is estimated at 1.3 billion tons. China plans to send a team to Jordan to conduct a plant design study. A Lajjun oil shale complex could produce as much as 50,000 b/d of shale oil. An earlier 500 ton shipment of shale is said to have yielded promising results.

  14. Regional geologic characteristics relevant to horizontal drilling, Woodford Shale, Anadarko basin, Oklahoma

    SciTech Connect (OSTI)

    Hester, T.C.; Schmoker, J.W. )

    1991-06-01

    Horizontal drilling in the Late Devonian-Early Mississippian Bakken Formation of the Williston basin has spurred new interest in other black shales as primary hydrocarbon reservoirs. The Late Devonian-Early Mississippian Woodford Shale, which is similar in some respects to the Bakken Formation, is a major source of oil and gas in the Anadarko basin of Oklahoma and could prove to be a significant reservoir rock as well. The three regional geologic characteristics of the Woodford discussed here are of likely importance to horizontal drilling programs, although direct relations to drilling strategy cannot be developed until empirical data from horizontal tests become available. First, the Woodford Shale is composed of three distinct depositional units (the upper, middle, and lower informal members) with different physical and geochemical properties. Second, a paleotopographic high that was rising before and during Woodford deposition divided the Woodford Shale into northeast and southwest depocenters. Third, Woodford depositional patterns are overprinted by thermal-maturity trends shaped primarily by differential burial of the Woodford during Pennsylvanian and Permian time. The Woodford Shale northeast of the forebulge is generally immature to marginally mature, whereas its thermal maturity southwest of the forebulge ranges from mature to postmature with respect to oil generation. A formation resistivity of about 35 ohm-m approximates the updip limit of oil-saturated Woodford Shale from which free oil might be produced from fracture systems.

  15. Conductivity heating a subterranean oil shale to create permeability and subsequently produce oil

    SciTech Connect (OSTI)

    Van Meurs, P.; DeRouffignac, E.P.; Vinegar, H.J.; Lucid, M.F.

    1989-12-12

    This patent describes an improvement in a process in which oil is produced from a subterranean oil shale deposit by extending at least one each of heat-injecting and fluid-producing wells into the deposit, establishing a heat-conductive fluid-impermeable barrier between the interior of each heat-injecting well and the adjacent deposit, and then heating the interior of each heat-injecting well at a temperature sufficient to conductively heat oil shale kerogen and cause pyrolysis products to form fractures within the oil shale deposit through which the pyrolysis products are displaced into at least one production well. The improvement is for enhancing the uniformity of the heat fronts moving through the oil shale deposit. Also described is a process for exploiting a target oil shale interval, by progressively expanding a heated treatment zone band from about a geometric center of the target oil shale interval outward, such that the formation or extension of vertical fractures from the heated treatment zone band to the periphery of the target oil shale interval is minimized.

  16. Spring and summer contrast in new particle formation over nine forest areas in North America

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, F.; Luo, G.; Pryor, S. C.; Pillai, P. R.; Lee, S. H.; Ortega, J.; Schwab, J. J.; Hallar, A. G.; Leaitch, W. R.; Aneja, V. P.; et al

    2015-08-06

    Recent laboratory chamber studies indicate a significant role for highly oxidized low volatility organics in new particle formation (NPF) but the actual role of these highly oxidized low volatility organics in atmospheric NPF remains uncertain. Here, particle size distributions (PSDs) measured in nine forest areas in North America are used to characterize the occurrence and intensity of NPF and to evaluate model simulations using an empirical formulation in which formation rate is a function of the concentrations of sulfuric acid and low volatility organics from alpha-pinene oxidation (Nucl-Org), and using an ion-mediated nucleation mechanism (excluding organics; Nucl-IMN). On average, NPFmoreoccurred on ~ 70 % of days during March for the four forest sites with springtime PSD measurements, while NPF occurred on only ~ 10 % of days in July for all nine forest sites. Both Nucl-Org and Nucl-IMN schemes capture the observed high frequency of NPF in spring, but the Nucl-Org scheme significantly over-predicts while the Nucl-IMN scheme slightly under-predicts NPF and particle number concentrations in summer. Statistical analyses of observed and simulated ultrafine particle number concentrations and frequency of NPF events indicate that the scheme without organics agrees better overall with observations. The two schemes predict quite different nucleation rates (including their spatial patterns), concentrations of cloud condensation nuclei, and aerosol first indirect radiative forcing in North America, highlighting the need to reduce NPF uncertainties in regional and global earth system models.less

  17. Ignition technique for an in situ oil shale retort

    DOE Patents [OSTI]

    Cha, Chang Y.

    1983-01-01

    A generally flat combustion zone is formed across the entire horizontal cross-section of a fragmented permeable mass of formation particles formed in an in situ oil shale retort. The flat combustion zone is formed by either sequentially igniting regions of the surface of the fragmented permeable mass at successively lower elevations or by igniting the entire surface of the fragmented permeable mass and controlling the rate of advance of various portions of the combustion zone.

  18. Water management technologies used by Marcellus Shale Gas Producers.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-07-30

    Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

  19. Production of hydrogen from oil shale

    SciTech Connect (OSTI)

    Schora, F. C.; Feldkirchner, H. L.; Janka, J. C.

    1985-12-24

    A process for production of hydrogen from oil shale fines by direct introduction of the oil shale fines into a fluidized bed at temperatures about 1200/sup 0/ to about 2000/sup 0/ F. to obtain rapid heating of the oil shale. The bed is fluidized by upward passage of steam and oxygen, the steam introduced in the weight ratio of about 0.1 to about 10 on the basis of the organic carbon content of the oil shale and the oxygen introduced in less than the stoichiometric quantity for complete combustion of the organic carbonaceous kerogen content of the oil shale. Embodiments are disclosed for heat recovery from the spent shale and heat recovery from the spent shale and product gas wherein the complete process and heat recovery is carried out in a single reaction vessel. The process of this invention provides high conversion of organic carbon component of oil shale and high production of hydrogen from shale fines which when used in combination with a conventional oil shale hydroconversion process results in increased overall process efficiency of greater than 15 percent.

  20. Extractors manual for Oil Shale Data Base System: Major Plants Data Base

    SciTech Connect (OSTI)

    Not Available

    1986-08-01

    To date, persons working in the development of oil shale technology have found limited amounts of reference data. If data from research and development could be made publicly available, however, several functions could be served. The duplication of work could be avoided, documented test material could serve as a basis to promote further developments, and research costs could possibly be reduced. To satisfy the engineering public's need for experimental data and to assist in the study of technical uncertainties in oil shale technology, the Department of Energy (DOE) has initiated the development of a data system to store the results of Government-sponsored research. A technology-specific data system consists of data that are stored for that technology in each of the specialized data bases that make up the Morgantown Energy Technology Center (METC) data system. The Oil Shale Data System consists of oil shale data stored in the Major Plants Data Base (MPDB), Test Data Data Base (TDDB), Resource Extraction Data Base (REDB), and Math Modeling Data Base (MMDB). To capture the results of Government-sponsored oil shale research programs, documents have been written to specify the data that contractors need to report and the procedures for reporting them. The documents identify and define the data from oil shale projects to be entered into the MPDB, TDDB, REDB, and MMDB, which will meet the needs of users of the Oil Shale Data System. This document addresses what information is needed and how it must be formatted for entry to the MPDB for oil shale. The data that are most relevant to potential Oil Shale Data System users have been divided into four categories: project tracking needs; economic/commercialization needs; critical performance needs; and modeling and research and development needs. 2 figs., 31 tabs.

  1. Nanoscale simulation of shale transport properties using the lattice Boltzmann method: Permeability and diffusivity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Li; Zhang, Lei; Kang, Qinjun; Viswanathan, Hari S.; Yao, Jun; Tao, Wenquan

    2015-01-28

    Here, porous structures of shales are reconstructed using the markov chain monte carlo (MCMC) method based on scanning electron microscopy (SEM) images of shale samples from Sichuan Basin, China. Characterization analysis of the reconstructed shales is performed, including porosity, pore size distribution, specific surface area and pore connectivity. The lattice Boltzmann method (LBM) is adopted to simulate fluid flow and Knudsen diffusion within the reconstructed shales. Simulation results reveal that the tortuosity of the shales is much higher than that commonly employed in the Bruggeman equation, and such high tortuosity leads to extremely low intrinsic permeability. Correction of the intrinsicmore » permeability is performed based on the dusty gas model (DGM) by considering the contribution of Knudsen diffusion to the total flow flux, resulting in apparent permeability. The correction factor over a range of Knudsen number and pressure is estimated and compared with empirical correlations in the literature. We find that for the wide pressure range investigated, the correction factor is always greater than 1, indicating Knudsen diffusion always plays a role on shale gas transport mechanisms in the reconstructed shales. Specifically, we found that most of the values of correction factor fall in the slip and transition regime, with no Darcy flow regime observed.« less

  2. Assessment of Long-Term Research Needs for Shale-Oil Recovery (FERWG-III)

    SciTech Connect (OSTI)

    Penner, S.S.

    1981-03-01

    The Fossil Energy Research Working Group (FERWG), at the request of E. Frieman (Director, Office of Energy Research) and G. Fumich, Jr. (Assistant Secretary for Fossil Fuels), has reviewed and evaluated the U.S. programs on shale-oil recovery. These studies were performed in order to provide an independent assessment of critical research areas that affect the long-term prospects for shale-oil availability. This report summarizes the findings and research recommendations of FERWG.

  3. Shale Oil Value Enhancement Research

    SciTech Connect (OSTI)

    James W. Bunger

    2006-11-30

    Raw kerogen oil is rich in heteroatom-containing compounds. Heteroatoms, N, S & O, are undesirable as components of a refinery feedstock, but are the basis for product value in agrochemicals, pharmaceuticals, surfactants, solvents, polymers, and a host of industrial materials. An economically viable, technologically feasible process scheme was developed in this research that promises to enhance the economics of oil shale development, both in the US and elsewhere in the world, in particular Estonia. Products will compete in existing markets for products now manufactured by costly synthesis routes. A premium petroleum refinery feedstock is also produced. The technology is now ready for pilot plant engineering studies and is likely to play an important role in developing a US oil shale industry.

  4. Oil shale fines process developments in Brazil

    SciTech Connect (OSTI)

    Lisboa, A.C.; Nowicki, R.E. ); Piper, E.M. )

    1989-01-01

    The Petrobras oil shale retorting process, utilizes the particle range of +1/4 inch - 3 1/2 inches. The UPI plant in Sao Mateus do Sul has over 106,000 hours of operation, has processed over 6,200,000 metric tons of shale and has produced almost 3,000,000 barrels of shale oil. However, the nature of the raw oil shale is such that the amount of shale less than 1/4 inch that is mined and crushed and returned to the mine site is about 20 percent, thereby, increasing the cost of oil produced by a substantial number. Petrobras has investigated several systems to process the fines that are not handled by the 65 MTPH UPI plant and the 260 MTPH commercial plant. This paper provides an updated status of each of these processes in regard to the tests performed, potential contributions to an integrated use of the oil shale mine, and future considerations.

  5. NATURAL GAS FROM SHALE: Questions and Answers Why is Shale Gas Important?

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Why is Shale Gas Important? With the advance of extraction technology, shale gas production has led to a new abundance of natural gas supply in the United States over the past decade, and is expected to continue to do so for the foreseeable future. According to the Energy Information Administration (EIA), the unproved technically recoverable U.S. shale gas resource is estimated at 482 trillion cubic feet. 1 Estimated proved and unproved shale gas resources amount to a combined 542 trillion cubic

  6. Comparative dermotoxicity of shale oils

    SciTech Connect (OSTI)

    Holland, L.M.; Wilson, J.S.; Foreman, M.E.

    1980-01-01

    When shale oils are applied at higher dose levels the standard observation of tumor production and latency are often obscured by a severe inflammatory response leading to epidermal degeneration. The two experiments reported here are still in progress, however the interim results are useful in assessing both the phlogistic and tumorigenic properties of three shale oils. Three shale oils were tested in these experiments. The first crude oil (OCSO No. 6) was produced in a modified in situ report at Occidental Oil Company's Logan Wash site near Debeque, Colorado. The second crude oil (PCSO II) was produced in the above ground Paraho vertical-kiln retort located at Anvil Points near Rifle, Colorado and the third oil was the hydrotreated daughter product of the Paraho crude (PCSO-UP). Experiment I was designed to determine the highest dose level at which tumor latency could be measured without interference from epidermal degeneration. Experiment II was designed to determine the effect of application frequency on both tumor response and inflammatory phenomena. Complete epidermal degeneration was used as the only measure of severe inflammation. Relative tumorigenicity was based on the number of tumor bearing mice without regard to multiple tumors on individual animals. In both experiments, tumor occurrence was confirmed one week after initial appearance. The sex-related difference in inflammatory response is striking and certanly has significance for experimental design. An increased phlogistic sensitivity expressed in male mice could affect the meaning of an experiment where only one sex was used.

  7. Developments in oil shale in 1987

    SciTech Connect (OSTI)

    Knutson, C.F.; Dana, G.F.; Solti, G.; Qian, J.L.; Ball, F.D.; Hutton, A.C.; Hanna, J.; Russell, P.L.; Piper, E.M.

    1988-10-01

    Oil shale development continued at a slow pace in 1987. The continuing interest in this commodity is demonstrated by the 342 oil shale citations added to the US Department of Energy Energy Database during 1987. The Unocal project in Parachute, Colorado, produced 600,000 bbl of synfuel in 1987. An appreciable amount of 1987's activity was associated with the nonsynfuel uses of oil shale. 4 figs., 2 tabs.

  8. DOE Science Showcase - Oil Shale Research | OSTI, US Dept of...

    Office of Scientific and Technical Information (OSTI)

    U.S. Agency oil shale information in Science.gov International oil shale information ... Oil Shale Calculator, the U.S. Geological Survey Visit the Science Showcase homepage.

  9. Can We Accurately Model Fluid Flow in Shale?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The source of shale oil and gas is kerogen, an organic material in the shale, but until now kerogen hasn't been incorporated in mathematical models of shale gas reservoirs. Paulo ...

  10. DOE Science Showcase - Oil Shale Research | OSTI, US Dept of...

    Office of Scientific and Technical Information (OSTI)

    Oil Shale Research Oil shale has been recognized as a potentially valuable U.S. energy resource for a century. Obstacles to its use have included the expense of current shale-oil ...

  11. Texas--State Offshore Shale Proved Reserves (Billion Cubic Feet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Texas--State Offshore Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 ... Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 TX, State Offshore Shale ...

  12. Approach to Recover Hydrocarbons from Currently Off-Limit Areas of the Antrim Formation, MI Using Low-Impact Technologies

    SciTech Connect (OSTI)

    James Wood; William Quinlan

    2008-09-30

    The goal of this project was to develop and execute a novel drilling and completion program in the Antrim Shale near the western shoreline of Northern Michigan. The target was the gas in the Lower Antrim Formation (Upper Devonian). Another goal was to see if drilling permits could be obtained from the Michigan DNR that would allow exploitation of reserves currently off-limits to exploration. This project met both of these goals: the DNR (Michigan Department of Natural Resources) issued permits that allow drilling the shallow subsurface for exploration and production. This project obtained drilling permits for the original demonstration well AG-A-MING 4-12 HD (API: 21-009-58153-0000) and AG-A-MING 4-12 HD1 (API: 21-009-58153-0100) as well as for similar Antrim wells in Benzie County, MI, the Colfax 3-28 HD and nearby Colfax 2-28 HD which were substituted for the AG-A-MING well. This project also developed successful techniques and strategies for producing the shallow gas. In addition to the project demonstration well over 20 wells have been drilled to date into the shallow Antrim as a result of this project's findings. Further, fracture stimulation has proven to be a vital step in improving the deliverability of wells to deem them commercial. Our initial plan was very simple; the 'J-well' design. We proposed to drill a vertical or slant well 30.48 meters (100 feet) below the glacial drift, set required casing, then angle back up to tap the resource lying between the base to the drift and the conventional vertical well. The 'J'-well design was tested at Mancelona Township in Antrim County in February of 2007 with the St. Mancelona 2-12 HD 3.

  13. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  14. CARMA LARGE AREA STAR FORMATION SURVEY: OBSERVATIONAL ANALYSIS OF FILAMENTS IN THE SERPENS SOUTH MOLECULAR CLOUD

    SciTech Connect (OSTI)

    Fernndez-Lpez, M.; Looney, L.; Lee, K.; Segura-Cox, D.; Arce, H. G.; Plunkett, A.; Mundy, L. G.; Storm, S.; Teuben, P. J.; Pound, M.; Isella, A.; Kauffmann, J.; Tobin, J. J.; Rosolowsky, E.; Kwon, W.; Ostriker, E.; Tassis, K.; Shirley, Y. L.

    2014-08-01

    We present the N{sub 2}H{sup +} (J = 1 ? 0) map of the Serpens South molecular cloud obtained as part of the CARMA Large Area Star Formation Survey. The observations cover 250 arcmin{sup 2} and fully sample structures from 3000 AU to 3pc with a velocity resolution of 0.16kms{sup 1}, and they can be used to constrain the origin and evolution of molecular cloud filaments. The spatial distribution of the N{sub 2}H{sup +} emission is characterized by long filaments that resemble those observed in the dust continuum emission by Herschel. However, the gas filaments are typically narrower such that, in some cases, two or three quasi-parallel N{sub 2}H{sup +} filaments comprise a single observed dust continuum filament. The difference between the dust and gas filament widths casts doubt on Herschel ability to resolve the Serpens South filaments. Some molecular filaments show velocity gradients along their major axis, and two are characterized by a steep velocity gradient in the direction perpendicular to the filament axis. The observed velocity gradient along one of these filaments was previously postulated as evidence for mass infall toward the central cluster, but these kind of gradients can be interpreted as projection of large-scale turbulence.

  15. Michigan Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Michigan Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 3,281 2,894 2,499 2010's 2,306 1,947 1,345 1,418 1,432 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Michigan Shale Gas

  16. Montana Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Montana Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 140 125 137 2010's 186 192 216 229 482 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Montana Shale Gas Proved Reserves,

  17. Montana Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Production (Billion Cubic Feet) Montana Shale Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 12 13 7 2010's 13 13 16 19 42 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Estimated Production Montana Shale Gas Proved Reserves, Reserves Changes, and Production Shale

  18. Kansas Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Kansas Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2010's 2 3 4 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Kansas Shale Gas Proved Reserves, Res

  19. Gas Shale Plays? The Global Transition

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    wells, and install the extensive surface infrastructure needed to transport product to market. Industry is cautious regarding China's likely pace of shale gas development. Even...

  20. Gas Shale Plays? The Global Transition

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    and transportation capacity in the Horn River Basin is being expanded to provide improved market access for its growing shale gas production. Pipeline infrastructure is being...

  1. Shale Gas 101 | Department of Energy

    Energy Savers [EERE]

    ... Protection Agency U.S. Government Accountability Office Clean Coal Carbon Capture and Storage Oil & Gas Methane Hydrate LNG Offshore Drilling Enhanced Oil Recovery Shale

  2. Ohio Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Ohio Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 0 0 2010's 0 0 483 2,319 6,384 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Ohio Shale Gas Proved Reserves, Reserves

  3. Oklahoma Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Oklahoma Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 944 3,845 6,389 2010's 9,670 10,733 12,572 12,675 16,653 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Oklahoma Shale Gas

  4. Pennsylvania Shale Proved Reserves (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Proved Reserves (Billion Cubic Feet) Pennsylvania Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 96 88 3,790 2010's 10,708 23,581 32,681 44,325 56,210 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Pennsylvania Shale

  5. Natural Gas from Shale | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas from Shale Office of Fossil Energy research helped refine cost-effective horizontal drilling and hydraulic fracturing technologies, protective environmental practices ...

  6. Virginia Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Production (Billion Cubic Feet) Virginia Shale Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2010's 3 3 3 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Estimated Production Virginia Shale Gas Proved Reserves, Reserves Changes, and Production Shale Gas

  7. West Virginia Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Shale Production (Billion Cubic Feet) West Virginia Shale Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 0 11 2010's 80 192 345 498 869 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Estimated Production West Virginia Shale Gas Proved Reserves, Reserves Changes,

  8. Wyoming Shale Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Production (Billion Cubic Feet) Wyoming Shale Production (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 0 0 2010's 0 0 7 102 29 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Estimated Production Wyoming Shale Gas Proved Reserves, Reserves Changes, and Production Shale Gas

  9. Oil Shale and Other Unconventional Fuels Activities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Naval Reserves » Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on reviewing the potential of oil shale as a strategic resource for liquid fuels. The Fossil Energy program in oil shale focuses on reviewing the potential of oil shale as a strategic resource for liquid fuels. It is generally agreed that worldwide petroleum supply will eventually reach its productive limit, peak, and begin a

  10. Documentation of INL's In Situ Oil Shale Retorting Water Usage...

    Office of Scientific and Technical Information (OSTI)

    Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics Model Citation Details In-Document Search Title: Documentation of INL's In Situ Oil Shale Retorting ...

  11. ,"West Virginia Natural Gas Gross Withdrawals from Shale Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  12. ,"Tennessee Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  13. ,"Missouri Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  14. ,"Louisiana Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  15. ,"Wyoming Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  16. ,"Michigan Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  17. ,"Mississippi Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  18. ,"Virginia Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  19. ,"Oregon Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  20. COLLOQUIUM: "The Environmental Footprint of Shale Gas Extraction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Footprint of Shale Gas Extraction and Hydraulic Fracturing" Professor Robert Jackson Duke University Presentation: PDF icon WC09JAN2013RBJackson.pdf Shale gas extraction is ...

  1. ,"Oklahoma Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  2. ,"Utah Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  3. ,"Ohio Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  4. ,"Montana Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  5. ,"South Dakota Natural Gas Gross Withdrawals from Shale Gas ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  6. Kerogen extraction from subterranean oil shale resources (Patent...

    Office of Scientific and Technical Information (OSTI)

    Kerogen extraction from subterranean oil shale resources Title: Kerogen extraction from subterranean oil shale resources The present invention is directed to methods for extracting ...

  7. Shale Gas Application in Hydraulic Fracturing Market is likely...

    Open Energy Info (EERE)

    on unconventional reservoirs such as coal bed methane, tight gas, tight oil, shale gas, and shale oil. Over the period of time, hydraulic fracturing technique has found...

  8. Calif--San Joaquin Basin onsh Shale Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    onsh Shale Proved Reserves (Billion Cubic Feet) Calif--San Joaquin Basin onsh Shale Proved Reserves (Billion Cubic Feet) No Data Available For This Series - No Data Reported; --...

  9. Alaska (with Total Offshore) Shale Production (Billion Cubic...

    Gasoline and Diesel Fuel Update (EIA)

    company data. Release Date: 11192015 Next Release Date: 12312016 Referring Pages: Shale Natural Gas Estimated Production Alaska Shale Gas Proved Reserves, Reserves Changes,...

  10. ,"Louisiana (with State Offshore) Shale Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    for" ,"Data 1","Louisiana (with State Offshore) Shale Proved Reserves (Billion Cubic ... Contents","Data 1: Louisiana (with State Offshore) Shale Proved Reserves (Billion Cubic ...

  11. ,"Alabama (with State Offshore) Shale Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Alabama (with State Offshore) Shale Proved Reserves (Billion Cubic ... Contents","Data 1: Alabama (with State Offshore) Shale Proved Reserves (Billion Cubic ...

  12. ,"Texas (with State Offshore) Shale Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas (with State Offshore) Shale Proved Reserves (Billion Cubic ... to Contents","Data 1: Texas (with State Offshore) Shale Proved Reserves (Billion Cubic ...

  13. ,"Texas--State Offshore Shale Proved Reserves (Billion Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas--State Offshore Shale Proved Reserves (Billion Cubic ... "Back to Contents","Data 1: Texas--State Offshore Shale Proved Reserves (Billion Cubic ...

  14. ,"Alaska (with Total Offshore) Shale Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Alaska (with Total Offshore) Shale Proved Reserves (Billion Cubic ... to Contents","Data 1: Alaska (with Total Offshore) Shale Proved Reserves (Billion Cubic ...

  15. ,"North Dakota Shale Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Dakota Shale Proved Reserves (Billion ... 9:24:07 AM" "Back to Contents","Data 1: North Dakota Shale Proved Reserves (Billion ...

  16. ,"Louisiana--North Shale Proved Reserves (Billion Cubic Feet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana--North Shale Proved Reserves (Billion Cubic ... "Back to Contents","Data 1: Louisiana--North Shale Proved Reserves (Billion Cubic ...

  17. Documentation of INL's In Situ Oil Shale Retorting Water Usage...

    Office of Scientific and Technical Information (OSTI)

    Oil Shale Retorting Water Usage System Dynamics Model Citation Details In-Document Search Title: Documentation of INL's In Situ Oil Shale Retorting Water Usage System Dynamics ...

  18. Methods of Managing Water in Oil Shale Development - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cost of producing potable water is low Reuse of water in drilling procedures Significant dewatering of the oil shale deposit Applications and Industries Oil shale drilling ...

  19. CARMA LARGE AREA STAR FORMATION SURVEY: STRUCTURE AND KINEMATICS OF DENSE GAS IN SERPENS MAIN

    SciTech Connect (OSTI)

    Lee, Katherine I.; Storm, Shaye; Mundy, Lee G.; Teuben, Peter; Pound, Marc W.; Salter, Demerese M.; Chen, Che-Yu; Fernndez-Lpez, Manuel; Looney, Leslie W.; Segura-Cox, Dominique; Rosolowsky, Erik; Arce, Hctor G.; Plunkett, Adele L.; Ostriker, Eve C.; Shirley, Yancy L.; Kwon, Woojin; Kauffmann, Jens; Tobin, John J.; Volgenau, N. H.; Tassis, Konstantinos; and others

    2014-12-20

    We present observations of N{sub 2}H{sup +} (J = 1 ? 0), HCO{sup +} (J = 1 ? 0), and HCN (J = 1 ? 0) toward the Serpens Main molecular cloud from the CARMA Large Area Star Formation Survey (CLASSy). We mapped 150 arcmin{sup 2} of Serpens Main with an angular resolution of ?7''. The gas emission is concentrated in two subclusters (the NW and SE subclusters). The SE subcluster has more prominent filamentary structures and more complicated kinematics compared to the NW subcluster. The majority of gas in the two subclusters has subsonic to sonic velocity dispersions. We applied a dendrogram technique with N{sub 2}H{sup +}(1-0) to study the gas structures; the SE subcluster has a higher degree of hierarchy than the NW subcluster. Combining the dendrogram and line fitting analyses reveals two distinct relations: a flat relation between nonthermal velocity dispersion and size, and a positive correlation between variation in velocity centroids and size. The two relations imply a characteristic depth of 0.15 pc for the cloud. Furthermore, we have identified six filaments in the SE subcluster. These filaments have lengths of ?0.2 pc and widths of ?0.03 pc, which is smaller than a characteristic width of 0.1 pc suggested by Herschel observations. The filaments can be classified into two types based on their properties. The first type, located in the northeast of the SE subcluster, has larger velocity gradients, smaller masses, and nearly critical mass-per-unit-length ratios. The other type, located in the southwest of the SE subcluster, has the opposite properties. Several YSOs are formed along two filaments which have supercritical mass per unit length ratios, while filaments with nearly critical mass-per-unit-length ratios are not associated with YSOs, suggesting that stars are formed on gravitationally unstable filaments.

  20. Application of the sup 187 Re- sup 187 Os system to black shale geochronometry

    SciTech Connect (OSTI)

    Ravizza, G.; Turekain, K.K. )

    1989-12-01

    The decay of {sup 187}Re to {sup 187}Os provides a tool for determining depositional ages of black shales. Re and Os concentrations and Os isotopic compositions of whole rock samples of the Bakken Shale, a Mississippian/Devonian boundary black shale, yield a whole rock isochron with an age of 354 {plus minus} 49 Ma. This age is in agreement with the accepted age of the Bakken Shale ({approx}360 Ma). The initial {sup 187}Os/{sup 186}Os ratio of the isochron is 6.2 {plus minus} 3.3. This value is indistinguishable from the {sup 187}Os/{sup 186}Os ratios observed in modern Black Sea sediments. The concentration of common Os in Bakken Shale samples is strongly correlated with total nitrogen, indicating that a large fraction of the Os in these samples is associated with a hydrogenous component, which overwhelms any Os supplied to the sediment in association with detrital material or cosmic dust. The dominance of the hydrogenous component imparts a relatively homogeneous initial {sup 187}Os/{sup 186}Os ratio to the sediment at the time of deposition. The degree of scatter about the isochron exceeds the degree of scatter expected from either analytical error or from the estimated degree of initial isotopic heterogeneity. The pattern of scatter is consistent with postdepositional mobilization of Re and/or Os on a small spatial scale. The author suggest that this mobilization may be a consequence of petroleum formation and migration in the Bakken Shale.

  1. Indirect heating pyrolysis of oil shale

    DOE Patents [OSTI]

    Jones, Jr., John B.; Reeves, Adam A.

    1978-09-26

    Hot, non-oxygenous gas at carefully controlled quantities and at predetermined depths in a bed of lump oil shale provides pyrolysis of the contained kerogen of the oil shale, and cool non-oxygenous gas is passed up through the bed to conserve the heat

  2. Chemical kinetics and oil shale process design

    SciTech Connect (OSTI)

    Burnham, A.K.

    1993-07-01

    Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

  3. Stratigraphy and organic petrography of Mississippian and Devonian oil shale at the Means Project, East-Central Kentucky

    SciTech Connect (OSTI)

    Solomon, B.J.; Hutton, A.C.; Henstridge, D.A.; Ivanac, J.F.

    1985-02-01

    The Means Oil Shale Project is under consideration for financial assistance by the US Synthetic Fuels Corporation. The project site is located in southern Montgomery County, about 45 miles east of Lexington, Kentucky. In the site area the Devonian Ohio Shale and the Mississippian Sunbury Shale are under study; these oil shales were deposited in the Appalachian Basin. The objective of the Means Project is to mine, using open pit methods, an ore zone which includes the Sunbury and upper Cleveland and which excludes the Bedford interburden. The thick lower grade oil shale below this ore zone renders the higher grade shale at the base of the Huron commercially unattractive. The oil shale at Means has been classified as a marinite, an oil shale containing abundant alginite of marine origin. Lamalginite is the dominant liptinite and comprises small, unicellular alginite with weak to moderate fluorescence at low rank and a distinctive lamellar form. Telalginite, derived from large colonial or thick-walled, unicellular algae, is common in several stratigraphic intervals.

  4. Tectonic mechanisms for formation of the Central Basin platform and adjacent basinal areas, Permian basin, Texas and New Mexico

    SciTech Connect (OSTI)

    Yang, Kennming; Dorobek, S.L. )

    1992-04-01

    Formation of the Central Basin platform (CBP), with the Delaware basin to its west and the Midland basin to its east, has been attributed to the crustal deformation in the foreland area of the Marathon Orogen during the late Paleozoic. Because of complexities in the areal distribution and magnitudes of uplift along the length of the CBP, its formative mechanisms are still controversial. Previous interpretations about the mechanisms for uplift of the CBP are based on the characteristics of the boundary faults between the CBP and adjacent basinal areas. Here, an integrated tectonic model is proposed for formation of the uplift and adjacent basins based on studies of the structure of sedimentary layers overlying Precambrian basement rocks of the uplift and restoration of the lower Paleozoic strata in the Delaware basin.

  5. An assessment of using oil shale for power production in the Hashemite Kingdom of Jordan

    SciTech Connect (OSTI)

    Hill, L.J.; Holcomb, R.S.; Petrich, C.H.; Roop, R.D.

    1990-11-01

    This report addresses the oil shale-for-power-production option in Jordan. Under consideration are 20- and 50-MW demonstration units and a 400-MW, commercial-scale plant with, at the 400-MW scale, a mining operation capable of supplying 7.8 million tonnes per year of shale fuel and also capable of disposal of up to 6.1 million tonnes per year of wetted ash. The plant would be a direct combustion facility, burning crushed oil shale through use of circulating fluidized bed combustion technology. The report emphasizes four areas: (1) the need for power in Jordan, (2) environmental aspects of the proposed oil shale-for-power plant(s), (3) the engineering feasibility of using Jordan's oil shale in circulating fluidized bed combustion (CFBC) boiler, and (4) the economic feasibility of the proposed plant(s). A sensitivity study was conducted to determine the economic feasibility of the proposed plant(s) under different cost assumptions and revenue flows over the plant's lifetime. The sensitivity results are extended to include the major extra-firm benefits of the shale-for-power option: (1) foreign exchange savings from using domestic energy resources, (2) aggregate income effects of using Jordan's indigenous labor force, and (3) a higher level of energy security. 14 figs., 47 tabs.

  6. Shale Gas Development Challenges: Fracture Fluids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fracture Fluids Shale Gas Development Challenges: Fracture Fluids Shale Gas Development Challenges: Fracture Fluids (904.72 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary Report of the Task Force on FracFocus 2.0

  7. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO?

    SciTech Connect (OSTI)

    Middleton, Richard S.; Carey, James William; Currier, Robert P.; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Jimnez-Martnez, Joaqun; Porter, Mark L.; Viswanathan, Hari S.

    2015-06-01

    Hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO? as a working fluid for shale gas production. We theorize and outline potential advantages of CO? including enhanced fracturing and fracture propagation, reduction of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO?. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO? proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.

  8. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO₂

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Middleton, Richard S.; Carey, James William; Currier, Robert P.; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Jiménez-Martínez, Joaquín; Porter, Mark L.; Viswanathan, Hari S.

    2015-06-01

    Hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO₂ as a working fluid for shale gas production. We theorize and outline potential advantages of CO₂ including enhanced fracturing and fracture propagation, reductionmore » of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO₂. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO₂ proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.« less

  9. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO₂

    SciTech Connect (OSTI)

    Middleton, Richard S.; Carey, James William; Currier, Robert P.; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Jiménez-Martínez, Joaquín; Porter, Mark L.; Viswanathan, Hari S.

    2015-06-01

    Hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO₂ as a working fluid for shale gas production. We theorize and outline potential advantages of CO₂ including enhanced fracturing and fracture propagation, reduction of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO₂. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO₂ proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.

  10. Differential thermal analysis of the reaction properties of raw and retorted oil shale with air

    SciTech Connect (OSTI)

    Wang, T.F.

    1984-01-01

    The results of a study to determine the kinetics of combustion of oil shale and its char by using differential thermal analysis are reported. The study indicates that Colorado oil shale and its char combustion rate is the fastest while Fushun oil shale and its char combustion rate is the slowest among the six oil shales used in this work. Oil shale samples used were Fushun oil shale, Maoming oil shale, Huang county oil shale, and Colorado oil shale.