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Sample records for arbuckle saline aquifer

  1. Fluid Dynamics of Carbon Dioxide Disposal into Saline Aquifers

    SciTech Connect (OSTI)

    Garcia, Julio Enrique

    2003-12-18

    Injection of carbon dioxide (CO{sub 2}) into saline aquifers has been proposed as a means to reduce greenhouse gas emissions (geological carbon sequestration). Large-scale injection of CO{sub 2} will induce a variety of coupled physical and chemical processes, including multiphase fluid flow, fluid pressurization and changes in effective stress, solute transport, and chemical reactions between fluids and formation minerals. This work addresses some of these issues with special emphasis given to the physics of fluid flow in brine formations. An investigation of the thermophysical properties of pure carbon dioxide, water and aqueous solutions of CO{sub 2} and NaCl has been conducted. As a result, accurate representations and models for predicting the overall thermophysical behavior of the system CO{sub 2}-H{sub 2}O-NaCl are proposed and incorporated into the numerical simulator TOUGH2/ECO{sub 2}. The basic problem of CO{sub 2} injection into a radially symmetric brine aquifer is used to validate the results of TOUGH2/ECO2. The numerical simulator has been applied to more complex flow problem including the CO{sub 2} injection project at the Sleipner Vest Field in the Norwegian sector of the North Sea and the evaluation of fluid flow dynamics effects of CO{sub 2} injection into aquifers. Numerical simulation results show that the transport at Sleipner is dominated by buoyancy effects and that shale layers control vertical migration of CO{sub 2}. These results are in good qualitative agreement with time lapse surveys performed at the site. High-resolution numerical simulation experiments have been conducted to study the onset of instabilities (viscous fingering) during injection of CO{sub 2} into saline aquifers. The injection process can be classified as immiscible displacement of an aqueous phase by a less dense and less viscous gas phase. Under disposal conditions (supercritical CO{sub 2}) the viscosity of carbon dioxide can be less than the viscosity of the aqueous phase by a factor of 15. Because of the lower viscosity, the CO{sub 2} displacement front will have a tendency towards instability. Preliminary simulation results show good agreement between classical instability solutions and numerical predictions of finger growth and spacing obtained using different gas/liquid viscosity ratios, relative permeability and capillary pressure models. Further studies are recommended to validate these results over a broader range of conditions.

  2. Two-phase convective CO2 dissolution in saline aquifers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlyingmore » two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.« less

  3. Using Pressure and Volumetric Approaches to Estimate CO2 Storage Capacity in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Thibeau, Sylvain; Bachu, Stefan; Birkholzer, Jens; Holloway, Sam; Neele, Filip; Zhou, Quanlin

    2014-12-31

    Various approaches are used to evaluate the capacity of saline aquifers to store CO2, resulting in a wide range of capacity estimates for a given aquifer. The two approaches most used are the volumetric open aquifer and closed aquifer approaches. We present four full-scale aquifer cases, where CO2 storage capacity is evaluated both volumetrically (with open and/or closed approaches) and through flow modeling. These examples show that the open aquifer CO2 storage capacity estimation can strongly exceed the cumulative CO2 injection from the flow model, whereas the closed aquifer estimates are a closer approximation to the flow-model derived capacity. An analogy to oil recovery mechanisms is presented, where the primary oil recovery mechanism is compared to CO2 aquifer storage without producing formation water; and the secondary oil recovery mechanism (water flooding) is compared to CO2 aquifer storage performed simultaneously with extraction of water for pressure maintenance. This analogy supports the finding that the closed aquifer approach produces a better estimate of CO2 storage without water extraction, and highlights the need for any CO2 storage estimate to specify whether it is intended to represent CO2 storage capacity with or without water extraction.

  4. Optimization of Geological Environments for Carbon Dioxide Disposan in Saline Aquifers in the United States

    SciTech Connect (OSTI)

    Hovorka, Susan

    1999-02-01

    Recent research and applications have demonstrated technologically feasible methods, defined costs, and modeled processes needed to sequester carbon dioxide (CO{sub 2}) in saline-water-bearing formations (aquifers). One of the simplifying assumptions used in previous modeling efforts is the effect of real stratigraphic complexity on transport and trapping in saline aquifers. In this study we have developed and applied criteria for characterizing saline aquifers for very long-term sequestration of CO{sub 2}. The purpose of this pilot study is to demonstrate a methodology for optimizing matches between CO{sub 2} sources and nearby saline formations that can be used for sequestration. This project identified 14 geologic properties used to prospect for optimal locations for CO{sub 2} sequestration in saline-water-bearing formations. For this demonstration, we digitized maps showing properties of saline formations and used analytical tools in a geographic information system (GIS) to extract areas that meet variably specified prototype criteria for CO{sub 2} sequestration sites. Through geologic models, realistic aquifer properties such as discontinuous sand-body geometry are determined and can be used to add realistic hydrologic properties to future simulations. This approach facilitates refining the search for a best-fit saline host formation as our understanding of the most effective ways to implement sequestration proceeds. Formations where there has been significant drilling for oil and gas resources as well as extensive characterization of formations for deep-well injection and waste disposal sites can be described in detail. Information to describe formation properties can be inferred from poorly known saline formations using geologic models in a play approach. Resulting data sets are less detailed than in well-described examples but serve as an effective screening tool to identify prospects for more detailed work.

  5. Using Pressure and Volumetric Approaches to Estimate CO2 Storage Capacity in Deep Saline Aquifers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thibeau, Sylvain; Bachu, Stefan; Birkholzer, Jens; Holloway, Sam; Neele, Filip; Zhou, Quanlin

    2014-12-31

    Various approaches are used to evaluate the capacity of saline aquifers to store CO2, resulting in a wide range of capacity estimates for a given aquifer. The two approaches most used are the volumetric “open aquifer” and “closed aquifer” approaches. We present four full-scale aquifer cases, where CO2 storage capacity is evaluated both volumetrically (with “open” and/or “closed” approaches) and through flow modeling. These examples show that the “open aquifer” CO2 storage capacity estimation can strongly exceed the cumulative CO2 injection from the flow model, whereas the “closed aquifer” estimates are a closer approximation to the flow-model derived capacity. Anmore » analogy to oil recovery mechanisms is presented, where the primary oil recovery mechanism is compared to CO2 aquifer storage without producing formation water; and the secondary oil recovery mechanism (water flooding) is compared to CO2 aquifer storage performed simultaneously with extraction of water for pressure maintenance. This analogy supports the finding that the “closed aquifer” approach produces a better estimate of CO2 storage without water extraction, and highlights the need for any CO2 storage estimate to specify whether it is intended to represent CO2 storage capacity with or without water extraction.« less

  6. Comparison of Caprock Mineral Characteristics at Field Demonstration Sites for Saline Aquifer Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Griffith, C.A.; Lowry, G. (Carnegie Mellon University); Dzombak, D. (Carnegie Mellon University); Soong, Yee; Hedges, S.W.

    2008-10-01

    In 2003 the U.S Department of Energy initiated regional partnership programs to address the concern for rising atmospheric CO2. These partnerships were formed to explore regional and economical means for geologically sequestering CO2 across the United States and to set the stage for future commercial applications. Several options exist for geological sequestration and among these sequestering CO2 into deep saline aquifers is one of the most promising. This is due, in part, to the possibility of stabilized permanent storage through mineral precipitation from chemical interactions of the injected carbon dioxide with the brine and reservoir rock. There are nine field demonstration sites for saline sequestration among the regional partnerships in Phase II development to validate the overall commercial feasibility for CO2 geological sequestration. Of the nine sites considered for Phase II saline sequestration demonstration, seven are profiled in this study for their caprock lithologic and mineral characteristics.

  7. Estimating Plume Volume for Geologic Storage of CO2 in Saline Aquifers

    SciTech Connect (OSTI)

    Doughty, Christine

    2008-07-11

    Typically, when a new subsurface flow and transport problem is first being considered, very simple models with a minimal number of parameters are used to get a rough idea of how the system will evolve. For a hydrogeologist considering the spreading of a contaminant plume in an aquifer, the aquifer thickness, porosity, and permeability might be enough to get started. If the plume is buoyant, aquifer dip comes into play. If regional groundwater flow is significant or there are nearby wells pumping, these features need to be included. Generally, the required parameters tend to be known from pre-existing studies, are parameters that people working in the field are familiar with, and represent features that are easy to explain to potential funding agencies, regulators, stakeholders, and the public. The situation for geologic storage of carbon dioxide (CO{sub 2}) in saline aquifers is quite different. It is certainly desirable to do preliminary modeling in advance of any field work since geologic storage of CO{sub 2} is a novel concept that few people have much experience with or intuition about. But the parameters that control CO{sub 2} plume behavior are a little more daunting to assemble and explain than those for a groundwater flow problem. Even the most basic question of how much volume a given mass of injected CO{sub 2} will occupy in the subsurface is non-trivial. However, with a number of simplifying assumptions, some preliminary estimates can be made, as described below. To make efficient use of the subsurface storage volume available, CO{sub 2} density should be large, which means choosing a storage formation at depths below about 800 m, where pressure and temperature conditions are above the critical point of CO{sub 2} (P = 73.8 bars, T = 31 C). Then CO{sub 2} will exist primarily as a free-phase supercritical fluid, while some CO{sub 2} will dissolve into the aqueous phase.

  8. Field trip guide to selected outcrops, Arbuckle Mountains, Oklahoma

    SciTech Connect (OSTI)

    1991-11-17

    The Arbuckle Mountains, named for Brigadier General Matthew Arbuckle, are located in south-central Oklahoma. The formations that comprise the Arbuckle Mountains have been extensively studied for hydrocarbon source rock and reservoir rock characteristics that can be applied to the subsurface in the adjacent Anadarko and Ardmore basins. Numerous reports and guidebooks have been written concerning the Arbuckle Mountains. A few important general publications are provided in the list of selected references. The purpose of this handout is to provide general information on the geology of the Arbuckle Mountains and specific information on the four field trip stops, adapted from the literature. The four stops were at: (1) Sooner Rock and Sand Quarry; (2) Woodford Shale; (3) Hunton Anticline and Hunton Quarry; and (4) Tar Sands of Sulfur Area. As part of this report, two papers are included for more detail: Paleomagnetic dating of basinal fluid migration, base-metal mineralization, and hydrocarbon maturation in the Arbuckle Mountains, Oklahoma and Laminated black shale-bedded chert cyclicity in the Woodford Formation, southern Oklahoma.

  9. Formation dry-out from CO2 injection into saline aquifers: Part...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 54; 58; AQUIFERS; BRINES; CROSS SECTIONS; DIFFUSION; DISSOLUTION; EVAPORATION; FRESH WATER; GEOMETRY; INJECTION WELLS; MITIGATION; PERMEABILITY; POROSITY; PRECIPITATION; ...

  10. Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers

    SciTech Connect (OSTI)

    Wu, Yu-Shu; Chen, Zizhong; Kazemi, Hossein; Yin, Xiaolong; Pruess, Karsten; Oldenburg, Curt; Winterfeld, Philip; Zhang, Ronglei

    2014-09-30

    This report is the final scientific one for the award DE- FE0000988 entitled “Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers.” The work has been divided into six tasks. In task, “Development of a Three-Phase Non-Isothermal CO2 Flow Module,” we developed a fluid property module for brine-CO2 mixtures designed to handle all possible phase combinations of aqueous phase, sub-critical liquid and gaseous CO2, supercritical CO2, and solid salt. The thermodynamic and thermophysical properties of brine-CO2 mixtures (density, viscosity, and specific enthalpy of fluid phases; partitioning of mass components among the different phases) use the same correlations as an earlier fluid property module that does not distinguish between gaseous and liquid CO2-rich phases. We verified the fluid property module using two leakage scenarios, one that involves CO2 migration up a blind fault and subsequent accumulation in a secondary “parasitic” reservoir at shallower depth, and another investigating leakage of CO2 from a deep storage reservoir along a vertical fault zone. In task, “Development of a Rock Mechanical Module,” we developed a massively parallel reservoir simulator for modeling THM processes in porous media brine aquifers. We derived, from the fundamental equations describing deformation of porous elastic media, a momentum conservation equation relating mean stress, pressure, and temperature, and incorporated it alongside the mass and energy conservation equations from the TOUGH2 formulation, the starting point for the simulator. In addition, rock properties, namely permeability and porosity, are functions of effective stress and other variables that are obtained from the literature. We verified the simulator formulation and numerical implementation using analytical solutions and example problems from the literature. For the former, we matched a one-dimensional consolidation problem and a two-dimensional simulation of the Mandel-Cryer effect. For the latter, we obtained a good match of temperature and gas saturation profiles, and surface uplift, after injection of hot fluid into a model of a caldera structure. In task, “Incorporation of Geochemical Reactions of Selected Important Species,” we developed a novel mathematical model of THMC processes in porous and fractured saline aquifers, simulating geo-chemical reactions associated with CO2 sequestration in saline aquifers. Two computational frameworks, sequentially coupled and fully coupled, were used to simulate the reactions and transport. We verified capabilities of the THMC model to treat complex THMC processes during CO2 sequestration by analytical solutions and we constructed reactive transport models to analyze the THMC process quantitatively. Three of these are 1D reactive transport under chemical equilibrium, a batch reaction model with equilibrium chemical reactions, and a THMC model with CO2 dissolution. In task “Study of Instability in CO2 Dissolution-Diffusion-Convection Processes,” We reviewed literature related to the study of density driven convective flows and on the instability of CO2 dissolution-diffusion-convection processes. We ran simulations that model the density-driven flow instability that would occur during CO2 sequestration. CO2 diffused through the top of the system and dissolved in the aqueous phase there, increasing its density. Density fingers formed along the top boundary, and coalesced into a few prominent ones, causing convective flow that forced the fluid to the system bottom. These simulations were in two and three dimensions. We ran additional simulations of convective mixing with density contrast caused by variable dissolved CO2 concentration in saline water, modeled after laboratory experiments in which supercritical CO2 was circulated in the headspace above a brine saturated packed sand in a pressure vessel. As CO2 dissolved into the upper part of the saturated sand, liquid phase density increases causing instability and setting off convective mixing. We obtained good agreement with the laboratory experiments, which were characterized by finger development and associated mixing of dissolved CO2 into the system. We then varied a wide range of parameters and conceptual models in order to analyze the possibility of convective mixing under different conditions, such as various boundary conditions, and chemical reaction conditions. The CO2 fingers from different simulations showed great differences as time progressed, caused by permeability heterogeneity. The early time diffusive phenomenon was captured by fine grid resolution, and the permeability heterogeneity affected the pattern of the CO2 fingers. In addition, the fingers from three-dimensional simulations tended to be larger and flatter than the two-dimensional ones. In task “Implementation of Efficient Parallel Computing Technologies,” we made enhancements and modifications to our code in order to substantially increase the grid size that could be run. We installed and ran it on various platforms, including a multi-core PC and a cluster, and verified the numerical implementation and parallel code using an example problem from the literature. This problem, with a grid size of sixty million, utilized the cluster’s entire memory and all of its processors. In task “Implementation of General Fracture Conceptual Models,” we used the MINC approach, a generalization of the double-porosity concept, to model flow through porous and fractured media. In this approach, flow within the matrix is described by subdividing the matrix into nested volumes, with flow occurring between adjacent nested matrix volumes as well as between the fractures and the outer matrix volume. We generalized Hooke’s law to a thermo-multi- poroelastic medium, and derived from the fundamental equations describing deformation of porous and fractured elastic media a momentum conservation equation for thermo-multi- poroelastic media. This equation is a generalization to multi-poroelastic media of the one derived in Task 3.0 for single porosity media. We describe two simulations to provide model verification and application examples. The first, one-dimensional consolidation of a double-porosity medium, is compared to an analytical solution. The second is a match of published results from the literature, a simulation of CO2 injection into hypothetical aquifer-caprock systems.

  11. Two-phase convective CO2 dissolution in saline aquifers

    SciTech Connect (OSTI)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlying two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.

  12. Formation dry-out from CO2 injection into saline aquifers: Part 1, Effects of solids precipitation and their mitigation

    SciTech Connect (OSTI)

    Pruess, Karsten; Muller, Nadja

    2009-02-01

    Injection of CO{sub 2} into saline aquifers may cause formation dry-out and precipitation of salt near the injection well, which may reduce formation porosity, permeability, and injectivity. This paper uses numerical simulation to explore the role of different processes and parameters in the salt precipitation process and to examine injection strategies that could mitigate the effects. The main physical mechanisms affecting the dry-out and salt precipitation process include (1) displacement of brine away from the injection well by injected CO{sub 2}, (2) dissolution (evaporation) of brine into the flowing CO{sub 2} stream, (3) upflow of CO{sub 2} due to gravity effects (buoyancy), (4) backflow of brine toward the injection point due to capillary pressure gradients that oppose the pressure gradient in the CO{sub 2}-rich ('gas') phase, and (5) molecular diffusion of dissolved salt. The different mechanisms operate on a range of spatial scales. CO{sub 2} injection at constant rate into a homogeneous reservoir with uniform initial conditions is simulated in 1-D radial geometry, to resolve multiscale processes by taking advantage of the similarity property, i.e., the evolution of system conditions as a function of radial distance R and time t depends only on the similarity variable R{sup 2}/t. Simulations in 2-D vertical cross sections are used to examine the role of gravity effects. We find that counterflow of CO{sub 2} and brine can greatly increase aqueous phase salinity and can promote substantial salt precipitation even in formations with low dissolved solids. Salt precipitation can accentuate effects of gravity override. We find that injecting a slug of fresh water prior to commencement of CO{sub 2} injection can reduce salt precipitation and permeability loss near the injection well.

  13. Feasibility of Geophysical Monitoring of Carbon-Sequestrated Deep Saline Aquifers

    SciTech Connect (OSTI)

    Mallick, Subhashis; Alvarado, Vladimir

    2013-09-30

    As carbon dioxide (CO{sub 2}) is sequestered from the bottom of a brine reservoir and allowed to migrate upward, the effects of the relative permeability hysteresis due to capillary trapping and buoyancy driven migration tend to make the reservoir patchy saturated with different fluid phases over time. Seismically, such a patchy saturated reservoir induces an effective anisotropic behavior whose properties are primarily dictated by the nature of the saturation of different fluid phases in the pores and the elastic properties of the rock matrix. By combining reservoir flow simulation and modeling with seismic modeling, it is possible to derive these effective anisotropic properties, which, in turn, could be related to the saturation of CO{sub 2} within the reservoir volume any time during the post-injection scenario. Therefore, if time-lapse seismic data are available and could be inverted for the effective anisotropic properties of the reservoir, they, in combination with reservoir simulation could potentially predict the CO{sub 2} saturation directly from the time-lapse seismic data. It is therefore concluded that the time-lapse seismic data could be used to monitor the carbon sequestrated saline reservoirs. But for its successful implementation, seismic modeling and inversion methods must be integrated with the reservoir simulations. In addition, because CO{sub 2} sequestration induces an effective anisotropy in the sequestered reservoir and anisotropy is best detected using multicomponent seismic data compared to single component (P-wave) data, acquisition, processing, and analysis is multicomponent seismic data is recommended for these time-lapse studies. Finally, a successful implementation of using time-lapse seismic data for monitoring the carbon sequestrated saline reservoirs will require development of a robust methodology for inverting multicomponent seismic data for subsurface anisotropic properties.

  14. 2014 Carbon Storage | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... of CO2 Flow, Leakage and Subsurface Distribution - Electric Power Research Institute Inc. ... and Leakage Pathways in the Arbuckle Saline Aquifer: Reducing Uncertainty in CO2 ...

  15. Monitoring CO 2 sequestration into deep saline aquifer and associated salt intrusion using coupled multiphase flow modeling and time lapse electrical resistivity tomography

    SciTech Connect (OSTI)

    Chuan Lu; CHI Zhang; Hai Hanag; Timothy C. Johnson

    2014-04-01

    Successful geological storage and sequestration of carbon dioxide (CO2) require efficient monitoring of the migration of CO2 plume during and after large-scale injection in order to verify the containment of the injected CO2 within the target formation and to evaluate potential leakage risk. Field studies have shown that surface and cross-borehole electrical resistivity tomography (ERT) can be a useful tool in imaging and characterizing solute transport in heterogeneous subsurface. In this synthetic study, we have coupled a 3-D multiphase flow model with a parallel 3-D time-lapse ERT inversion code to explore the feasibility of using time-lapse ERT for simultaneously monitoring the migration of CO2 plume in deep saline formation and potential brine intrusion into shallow fresh water aquifer. Direct comparisons of the inverted CO2 plumes resulting from ERT with multiphase flow simulation results indicate the ERT could be used to delineate the migration of CO2 plume. Detailed comparisons on the locations, sizes and shapes of CO2 plume and intruded brine plumes suggest that ERT inversion tends to underestimate the area review of the CO2 plume, but overestimate the thickness and total volume of the CO2 plume. The total volume of intruded brine plumes is overestimated as well. However, all discrepancies remain within reasonable ranges. Our study suggests that time-lapse ERT is a useful monitoring tool in characterizing the movement of injected CO2 into deep saline aquifer and detecting potential brine intrusion under large-scale field injection conditions.

  16. Development of Science-Based Permitting Guidance for Geological Sequestration of CO2 in Deep Saline Aquifers Based on Modeling and Risk Assessment

    SciTech Connect (OSTI)

    Jean-Philippe Nicot; Renaud Bouroullec; Hugo Castellanos; Susan Hovorka; Srivatsan Lakshminarasimhan; Jeffrey Paine

    2006-06-30

    Underground carbon storage may become one of the solutions to address global warming. However, to have an impact, carbon storage must be done at a much larger scale than current CO{sub 2} injection operations for enhanced oil recovery. It must also include injection into saline aquifers. An important characteristic of CO{sub 2} is its strong buoyancy--storage must be guaranteed to be sufficiently permanent to satisfy the very reason that CO{sub 2} is injected. This long-term aspect (hundreds to thousands of years) is not currently captured in legislation, even if the U.S. has a relatively well-developed regulatory framework to handle carbon storage, especially in the operational short term. This report proposes a hierarchical approach to permitting in which the State/Federal Government is responsible for developing regional assessments, ranking potential sites (''General Permit'') and lessening the applicant's burden if the general area of the chosen site has been ranked more favorably. The general permit would involve determining in the regional sense structural (closed structures), stratigraphic (heterogeneity), and petrophysical (flow parameters such as residual saturation) controls on the long-term fate of geologically sequestered CO{sub 2}. The state-sponsored regional studies and the subsequent local study performed by the applicant will address the long-term risk of the particular site. It is felt that a performance-based approach rather than a prescriptive approach is the most appropriate framework in which to address public concerns. However, operational issues for each well (equivalent to the current underground injection control-UIC-program) could follow regulations currently in place. Area ranking will include an understanding of trapping modes. Capillary (due to residual saturation) and structural (due to local geological configuration) trappings are two of the four mechanisms (the other two are solubility and mineral trappings), which are the most relevant to the time scale of interest. The most likely pathways for leakage, if any, are wells and faults. We favor a defense-in-depth approach, in which storage permanence does not rely upon a primary seal only but assumes that any leak can be contained by geologic processes before impacting mineral resources, fresh ground water, or ground surface. We examined the Texas Gulf Coast as an example of an attractive target for carbon storage. Stacked sand-shale layers provide large potential storage volumes and defense-in-depth leakage protection. In the Texas Gulf Coast, the best way to achieve this goal is to establish the primary injection level below the total depth of most wells (>2,400 m-8,000 ft). In addition, most faults, particularly growth faults, present at the primary injection level do not reach the surface. A potential methodology, which includes an integrated approach comprising the whole chain of potential events from leakage from the primary site to atmospheric impacts, is also presented. It could be followed by the State/Federal Government, as well as by the operators.

  17. 2015 Carbon Storage Project Portfolio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Microalgae Commodities from Coal-Fired Power Plant Flue Gas CO2* MicroBio Engineering ... CO2 Sequestration in Arbuckle Saline Aquifer and by CO2-EOR at Wellington ...

  18. CX-007045: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Small-Scale Field Test Demonstrating Carbon Dioxide Sequestration in Arbuckle Saline AquiferCX(s) Applied: A1, A9Date: 09/20/2011Location(s): Lawrence, KansasOffice(s): Fossil Energy, National Energy Technology Laboratory

  19. Numerical simulation studies of the long-term evolution of a CO2 plume in a saline aquifer with a sloping caprock

    SciTech Connect (OSTI)

    Pruess, K.; Nordbotten, J.

    2010-12-28

    We have used the TOUGH2-MP/ECO2N code to perform numerical simulation studies of the long-term behavior of CO{sub 2} stored in an aquifer with a sloping caprock. This problem is of great practical interest, and is very challenging due to the importance of multi-scale processes. We find that the mechanism of plume advance is different from what is seen in a forced immiscible displacement, such as gas injection into a water-saturated medium. Instead of pushing the water forward, the plume advances because the vertical pressure gradients within the plume are smaller than hydrostatic, causing the groundwater column to collapse ahead of the plume tip. Increased resistance to vertical flow of aqueous phase in anisotropic media leads to reduced speed of updip plume advancement. Vertical equilibrium models that ignore effects of vertical flow will overpredict the speed of plume advancement. The CO{sub 2} plume becomes thinner as it advances, yet the speed of advancement remains constant over the entire simulation period of up to 400 years, with migration distances of more than 80 km. Our simulations include dissolution of CO{sub 2} into the aqueous phase and associated density increase, and molecular diffusion. However, no convection develops in the aqueous phase because it is suppressed by the relatively coarse (sub-) horizontal gridding required in a regional-scale model. A first crude sub-grid-scale model was developed to represent convective enhancement of CO{sub 2} dissolution. This process is found to greatly reduce the thickness of the CO{sub 2} plume, but, for the parameters used in our simulations, does not affect the speed of plume advancement.

  20. CX-008478: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Small Scale Field Test Demonstrating Carbon Dioxide Sequestration in the Arbuckle Saline Aquifer CX(s) Applied: A9, B3.1, B5.3 Date: 06/04/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  1. CX-008477: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Small Scale Field Test Demonstrating Carbon Dioxide Sequestration in the Arbuckle Saline Aquifer CX(s) Applied: A9, B3.1, B3.7, B5.3, B5.13 Date: 06/04/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  2. CX-008476: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Small Scale Field Test Demonstrating Carbon Dioxide Sequestration in the Arbuckle Saline Aquifer CX(s) Applied: A9, B1.15, B3.1, B3.7, B5.3, B5.13 Date: 06/04/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  3. CX-008475: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Small Scale Field Test Demonstrating Carbon Dioxide Sequestration in the Arbuckle Saline Aquifer CX(s) Applied: A9, B3.1, B3.7, B5.3 Date: 06/04/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  4. CX-008474: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Small Scale Field Test Demonstrating Carbon Dioxide Sequestration in the Arbuckle Saline Aquifer CX(s) Applied: B1.15, B3.6, B5.2 Date: 06/04/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  5. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in Deep Saline

    Office of Scientific and Technical Information (OSTI)

    Aquifers. (Conference) | SciTech Connect in Deep Saline Aquifers. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: 2012-06-01 OSTI Identifier: 1073284 Report Number(s): SAND2012-5175C DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the 49th Annual Meeting of The Clay Minerals Society held July

  6. THE SNAKE RIVER PLAIN AQUIFER THE SNAKE RIVER PLAIN AQUIFER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aquifer THE INL & THE SNAKE RIVER PLAIN AQUIFER THE SNAKE RIVER PLAIN AQUIFER underneath the Idaho National Laboratory is one of the most productive groundwater resources in the U.S. Each year about 2 million acre-feet of water is drawn from the aquifer. Approximately 95 percent of the water withdrawn from the aquifer is used for irrigation, 3 per- cent for domestic water, and 2 percent for industrial purposes. The aquifer is the primary water source for more than 280,000 people in

  7. Geochemical detection of carbon dioxide in dilute aquifers

    SciTech Connect (OSTI)

    Carroll, S; Hao, Y; Aines, R

    2009-03-27

    Carbon storage in deep saline reservoirs has the potential to lower the amount of CO{sub 2} emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO{sub 2} gas leak into dilute groundwater are important measures for the potential release of CO{sub 2} to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO{sub 2} storage reservoir. Specifically, we address the relationships between CO{sub 2} flux, groundwater flow, detection time and distance. The CO{sub 2} flux ranges from 10{sup 3} to 2 x 10{sup 6} t/yr (0.63 to 1250 t/m{sup 2}/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure.

  8. Effects of Increased Upward Flux of Saline Water Caused by CO2 Storage or Other Factors

    SciTech Connect (OSTI)

    Murdoch, Lawrence; Xie, Shuang; Falta, Ronald W.; Yonkofski, Catherine MR

    2015-08-01

    Injection of CO2 in deep saline aquifers is being considered to reduce greenhouse gases in the atmosphere, and this process is expected to increase the pressure in these deep aquifers. One potential consequence of pressurization is an increase in the upward flux of saline water. Saline groundwater occurs naturally at shallow depths in many sedimentary basins, so an upward flux of solutes could degrade the quality of freshwater aquifers and threaten aquatic ecosystems. One problem could occur where saline water flowed upward along preferential paths, like faults or improperly abandoned wells. Diffuse upward flow through the natural stratigraphy could also occur in response to basin pressurization. This process would be slower, but diffuse upward flow could affect larger areas than flow through preferential paths, and this motivated us to evaluate this process. We analyzed idealized 2D and 3D geometries representing the essential details of a shallow, freshwater aquifer underlain by saline ground water in a sedimentary basin. The analysis was conducted in two stages, one that simulated the development of a freshwater aquifer by flushing out saline water, and another that simulated the effect of a pulse-like increase in the upward flux from the basin. The results showed that increasing the upward flux from a basin increased the salt concentration and mass loading of salt to streams, and decrease the depth to the fresh/salt transition. The magnitude of these effects varied widely, however, from a small, slow process that would be challenging to detect, to a large, rapid response that could be an environmental catastrophe. The magnitude of the increased flux, and the initial depth to the fresh/salt transition in groundwater controlled the severity of the response. We identified risk categories for salt concentration, mass loading, and freshwater aquifer thickness, and we used these categories to characterize the severity of the response. This showed that risks would likely be minor if the upward flux was smaller than a few tenths of the magnitude of recharge, according to the 2D analyses. The 3D analyses also show that upward flux could occur without a significant increase in the risk categories. The major contribution of this work is that it shows how a large increase in diffuse upward flux from a basin could cause significant problems, but a small increase in upward flux may occur without significantly affecting risks to the shallow freshwater flow system. This heightens the importance of understanding interactions between shallow and deep hydrologic systems when characterizing CO2 storage projects.

  9. EIA - Natural Gas Pipeline Network - Aquifer Storage Reservoir...

    U.S. Energy Information Administration (EIA) Indexed Site

    Aquifer Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting ... Aquifer Underground Natural Gas Storage Reservoir Configuration Aquifer Underground ...

  10. Salinity driven oceanographic upwelling

    DOE Patents [OSTI]

    Johnson, David H.

    1986-01-01

    The salinity driven oceanographic upwelling is maintained in a mariculture device that includes a long main duct in the general shape of a cylinder having perforated cover plates at each end. The mariculture device is suspended vertically in the ocean such that one end of the main duct is in surface water and the other end in relatively deep water that is cold, nutrient rich and relatively fresh in comparison to the surface water which is relatively warm, relatively nutrient deficient and relatively saline. A plurality of elongated flow segregating tubes are disposed in the main duct and extend from the upper cover plate beyond the lower cover plate into a lower manifold plate. The lower manifold plate is spaced from the lower cover plate to define a deep water fluid flow path to the interior space of the main duct. Spacer tubes extend from the upper cover plate and communicate with the interior space of the main duct. The spacer tubes are received in an upper manifold plate spaced from the upper cover plate to define a surface water fluid flow path into the flow segregating tubes. A surface water-deep water counterflow is thus established with deep water flowing upwardly through the main duct interior for discharge beyond the upper manifold plate while surface water flows downwardly through the flow segregating tubes for discharge below the lower manifold plate. During such counterflow heat is transferred from the downflowing warm water to the upflowing cold water. The flow is maintained by the difference in density between the deep water and the surface water due to their differences in salinity. The upwelling of nutrient rich deep water is used for marifarming by fertilizing the nutrient deficient surface water.

  11. Salinity driven oceanographic upwelling

    DOE Patents [OSTI]

    Johnson, D.H.

    1984-08-30

    The salinity driven oceanographic upwelling is maintained in a mariculture device that includes a long main duct in the general shape of a cylinder having perforated cover plates at each end. The mariculture device is suspended vertically in the ocean such that one end of the main duct is in surface water and the other end in relatively deep water that is cold, nutrient rich and relatively fresh in comparison to the surface water which is relatively warm, relatively nutrient deficient and relatively saline. A plurality of elongated flow segregating tubes are disposed in the main duct and extend from the upper cover plate beyond the lower cover plate into a lower manifold plate. The lower manifold plate is spaced from the lower cover plate to define a deep water fluid flow path to the interior space of the main duct. Spacer tubes extend from the upper cover plate and communicate with the interior space of the main duct. The spacer tubes are received in an upper manifold plate spaced from the upper cover plate to define a surface water fluid flow path into the flow segregating tubes. A surface water-deep water counterflow is thus established with deep water flowing upwardly through the main duct interior for discharge beyond the upper manifold plate while surface water flows downwardly through the flow segregating tubes for discharge below the lower manifold plate. During such counterflow heat is transferred from the downflowing warm water to the upflowing cold water. The flow is maintained by the difference in density between the deep water and the surface water due to their differences in salinity. The upwelling of nutrient rich deep water is used for marifarming by fertilizing the nutrient deficient surface water. 1 fig.

  12. Groundwater in the Regional Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater in the Regional Aquifer Groundwater in the Regional Aquifer LANL maintains an extensive groundwater monitoring and surveillance program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at Los Alamos National Laboratory RELATED IMAGES http://farm4.staticflickr.com/3749/9827580556_473a91fd78_t.jpg Enlarge http://farm3.staticflickr.com/2856/9804364405_b25f74cbb2_t.jpg En

  13. An evaluation of aquifer intercommunication between the unconfined and Rattlesnake Ridge aquifers on the Hanford Site

    SciTech Connect (OSTI)

    Jensen, E.J.

    1987-10-01

    During 1986, Pacific Northwest Laboratory conducted a study of a portion of the Rattlesnake Ridge aquifer (confined aquifer) that lies beneath the B Pond - Gable Mountain Pond area of the Hanford Site. The purpose was to determine the extent of intercommunication between the unconfined aquifer and the uppermost regionally extensive confined aquifer, referred to as the Rattlesnake Ridge aquifer. Hydraulic head data and chemical data were collected from the ground water in the study area during December 1986. The hydraulic head data were used to determine the effects caused by water discharged to the ground from B Pond on both the water table of the unconfined aquifer and the potentiometric surface of the confined aquifer. The chemical data were collected to determine the extent of chemical constituents migrating from the unconfined aquifer to the confined aquifer. Analysis of chemical constituents in the Rattlesnake Ridge aquifer demonstrated that communication between the unconfined and confined aquifers had occurred. However, the levels of contaminants found in the Rattlesnake Ridge aquifer during this study were below the DOE Derived Concentration Guides.

  14. EIA - Natural Gas Pipeline Network - Aquifer Storage Reservoir

    U.S. Energy Information Administration (EIA) Indexed Site

    Configuration Aquifer Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Aquifer Underground Natural Gas Storage Reservoir Configuration Aquifer Underground Natural Gas Well

  15. Fresh Water Generation from Aquifer-Pressured Carbon Storage

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Bourcier, W L; Wolfe, T; Haussmann, C

    2010-02-19

    Can we use the pressure associated with sequestration to make brine into fresh water? This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). Possible products are: Drinking water, Cooling water, and Extra aquifer space for CO{sub 2} storage. The conclusions are: (1) Many saline formation waters appear to be amenable to largely conventional RO treatment; (2) Thermodynamic modeling indicates that osmotic pressure is more limiting on water recovery than mineral scaling; (3) The use of thermodynamic modeling with Pitzer's equations (or Extended UNIQUAC) allows accurate estimation of osmotic pressure limits; (4) A general categorization of treatment feasibility is based on TDS has been proposed, in which brines with 10,000-85,000 mg/L are the most attractive targets; (5) Brines in this TDS range appear to be abundant (geographically and with depth) and could be targeted in planning future CCS operations (including site selection and choice of injection formation); and (6) The estimated cost of treating waters in the 10,000-85,000 mg/L TDS range is about half that for conventional seawater desalination, due to the anticipated pressure recovery.

  16. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Annual Report FY09

    SciTech Connect (OSTI)

    Wolery, T; Aines, R; Hao, Y; Bourcier, W; Wolfe, T; Haussman, C

    2009-11-25

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine is reinjected into the formation at net volume reduction, such that the volume of fresh water extracted balances the volume of CO{sub 2} injected into the formation. This process provides additional CO{sub 2} storage capacity in the aquifer, reduces operational risks (cap-rock fracturing, contamination of neighboring fresh water aquifers, and seismicity) by relieving overpressure in the formation, and provides a source of low-cost fresh water to offset costs or operational water needs. This multi-faceted project combines elements of geochemistry, reservoir engineering, and water treatment engineering. The range of saline formation waters is being identified and analyzed. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations. Computer modeling is being used to evaluate processes in the storage aquifer, including the evolution of the pressure field. Water treatment costs are being evaluated by comparing the necessary process facilities to those in common use for seawater RO. There are presently limited brine composition data available for actual CCS sites by the site operators including in the U.S. the seven regional Carbon Sequestration Partnerships (CSPs). To work around this, we are building a 'catalog' of compositions representative of 'produced' waters (waters produced in the course of seeking or producing oil and gas), to which we are adding data from actual CCS sites as they become available. Produced waters comprise the most common examples of saline formation waters. Therefore, they are expected to be representative of saline formation waters at actual and potential future CCS sites. We are using a produced waters database (Breit, 2002) covering most of the United States compiled by the U.S. Geological Survey (USGS). In one instance to date, we have used this database to find a composition corresponding to the brine expected at an actual CCS site (Big Sky CSP, Nugget Formation, Sublette County, Wyoming). We have located other produced waters databases, which are usually of regional scope (e.g., NETL, 2005, Rocky Mountains basins).

  17. REACTIVE MULTIPHASE BEHAVIOR OF CO2 IN SALINE AQUIFERS BENEATH THE COLORADO PLATEAU

    SciTech Connect (OSTI)

    R.G. Allis; J. Moore; S. White

    2003-01-30

    Gas reservoirs developed within the Colorado Plateau and Southern Rocky Mountains region are natural laboratories for studying the factors that promote long-term storage of CO{sub 2}. They also provide sites for storing additional CO{sub 2} if it can be separated from the flue gases of coal-fired power plants in this part of the U.S.A. These natural reservoirs are developed primarily in sandstones and dolomites; shales, mudstones and anhydrite form seals. In many fields, stacked reservoirs are present, indicating that the gas has migrated up through the section. There are also geologically young travertine deposits at the surface, and CO{sub 2}-charged groundwater and springs in the vicinity of known CO{sub 2} occurrences. These near-surface geological and hydrological features also provide examples of the environmental effects of leakage of CO{sub 2} from reservoirs, and justify further study. During reporting period covered here (the first quarter of Year 3 of the project, i.e. October 1-December 31, 2002), the main achievements were: (1) Planning workshop for project participants as well as other Utah researchers involved in CO{sub 2} projects (22 October, 2002), and Utah Geological Survey, Salt Lake City; (2) Presentation of paper to special CO{sub 2} sequestration session at the Geological Society of America Annual Meeting, Denver, 29 October, 2002; (3) Presentation of paper to special CO{sub 2} sequestration session at the Fall Meeting of American Geophysical Union, San Francisco, 10 December, 2002; (4) Identification of dawsonite (sodium-aluminum carbonate) as a late stage mineral deposited in CO{sub 2} feedzone at Springerville, Arizona; (5) Successful matching of known physical constraints to flow beneath the Hunter cross section being used to simulate the effects of CO{sub 2} injection. In about 1000 years, most injected CO{sub 2} may be lost to the surface from the three shallowest reservoirs considered, assuming no reactive processes; and (6) Inclusion of reactive processes in numerical simulations, and indication that CO{sub 2} is sequestered for at 1000 years in form of dissolved CO{sub 2} and carbonate mineral precipitation.

  18. REACTIVE MULTIPHASE BEHAVIOR OF CO2 IN SALINE AQUIFERS BENEATH THE COLORADO PLATEAU

    SciTech Connect (OSTI)

    R.G. Allis; J. Moore; S. White

    2003-10-21

    Field and laboratory investigations of naturally occurring CO{sub 2}-reservoirs are being conducted to determine the characteristics of potential seal and reservoir units and the extent of the interactions that occur between the host rocks and the CO{sub 2} charged fluids. Efforts have focused on the Farnham Dome field, located in central Utah, and the Springerville-St. Johns field in Arizona and New Mexico. The Springerville-St. Johns field is particularly significant because of the presence of extensive travertine deposits that document release of CO{sub 2} to the atmosphere. CO{sub 2} accumulations at both fields occur in sedimentary rocks typical of CO{sub 2} reservoirs occurring on the Colorado Plateau. The main achievements during this quarter were: (1) a soil gas flux survey at the Springerville-St Johns field, (2) collection of some soil gas for chemical and isotopic analysis from this field, and (3) collection of travertine samples from an elevation range of over 1000 feet (330 m) for dating the time span of carbonate-saturated spring outflow at this field. Analytical results and interpretations are still in progress. When available they will allow contrast with soil gas measurements from Farnham Dome natural CO{sub 2} field in central Utah, which were reported in the previous quarterly report.

  19. EXPERIMENTAL DESIGN APPLICATIONS FOR MODELING AND ASSESSING CARBON DIOXIDE SEQUESTRATION IN SALINE AQUIFERS

    SciTech Connect (OSTI)

    Rogers, John

    2014-08-31

    This project was a computer modeling effort to couple reservoir simulation and ED/RSM using Sensitivity Analysis, Uncertainty Analysis, and Optimization Methods, to assess geologic, geochemical, geomechanical, and rock-fluid effects and factors on CO2 injectivity, capacity, and plume migration. The project objective was to develop proxy models to simplify the highly complex coupled geochemical and geomechanical models in the utilization and storage of CO2 in the subsurface. The goals were to investigate and prove the feasibility of the ED/RSM processes and engineering development, and bridge the gaps regarding the uncertainty and unknowns of the many geochemical and geomechanical interacting parameters in the development and operation of anthropogenic CO2 sequestration and storage sites. The bottleneck in this workflow is the high computational effort of reactive transport simulation models and large number of input variables to optimize with ED/RSM techniques. The project was not to develop the reactive transport, geomechanical, or ED/RSM software, but was to use what was commercially and/or publically available as a proof of concept to generate proxy or surrogate models. A detailed geologic and petrographic mineral assemblage and geologic structure of the doubly plunging anticline was defined using the USDOE RMOTC formations of interest data (e.g., Lower Sundance, Crow Mountain, Alcova Limestone, and Red Peak). The assemblage of 23 minerals was primarily developed from literature data and petrophysical (well log) analysis. The assemblage and structure was input into a commercial reactive transport simulator to predict the effects of CO2 injection and complex reactions with the reservoir rock. Significant impediments were encountered during the execution phase of the project. The only known commercial reactive transport simulator was incapable of simulating complex geochemistry modeled in this project. Significant effort and project funding was expended to determine the limitations of both the commercial simulator and the Lawrence Berkeley National Laboratory (LBNL) R&D simulator, TOUGHREACT available to the project. A simplified layer cake model approximating the volume of the RMOTC targeted reservoirs was defined with 1-3 minerals eventually modeled with limited success. Modeling reactive transport in porous media requires significant computational power. In this project, up to 24 processors were used to model a limited mineral set of 1-3 minerals. In addition, geomechanical aspects of injecting CO2 into closed, semi-open, and open systems in various well completion methods was simulated. Enhanced Oil Recovery (EOR) as a storage method was not modeled. A robust and stable simulation dataset or base case was developed and used to create a master dataset with embedded instructions for input to the ED/RSM software. Little success was achieved toward the objective of the project using the commercial simulator or the LBNL simulator versions available during the time of this project. Several hundred realizations were run with the commercial simulator and ED/RSM software, most having convergence problems and terminating prematurely. A proxy model for full field CO2 injection sequestration utilization and storage was not capable of being developed with software available for this project. Though the chemistry is reasonably known and understood, based on the amount of effort and huge computational time required, predicting CO2 sequestration storage capacity in geologic formations to within the program goals of ±30% proved unsuccessful.

  20. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Peters, Catherine A

    2013-02-28

    Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of mineral accessible surface area, and should not be used in reactive transport modeling. Our work showed that reaction rates would be overestimated by three to five times.

  1. REACTIVE MULTIPHASE BEHAVIOR OF CO2 IN SALINE AQUIFERS BENEATH THE COLORADO PLATEAU

    SciTech Connect (OSTI)

    R.G. Allis; J. Moore; S. White

    2003-06-30

    The six coal-fired power plants located in the Colorado Plateau and southern Rocky Mountain region of the U.S. produce 100 million tons of CO{sub 2} per year. Thick sequences of collocated sedimentary rocks represent potential sites for sequestration of the CO{sub 2}. Field and laboratory investigations of naturally occurring CO{sub 2}-reservoirs are being conducted to determine the characteristics of potential seal and reservoir units and the extent of the interactions that occur between the host rocks and the CO{sub 2} charged fluids. The results are being incorporated into a series of two-dimensional numerical models that represent the major chemical and physical processes induced by injection. During reporting period covered here (March 30 to June 30, 2003), the main achievements were: Presentation of three papers at the Second Annual Conference on Carbon Sequestration (May 5-8, Alexandria, Virginia); Presentation of a poster at the American Association of Petroleum Geologists meeting; Co-PI organized and chaired a special session on Geologic Carbon Dioxide Sequestration at the American Association of Petroleum Geologists annual convention in Salt Lake City (May 12-15).

  2. Sole Source Aquifer Protection Program (EPA)

    Broader source: Energy.gov [DOE]

    Section 1424(e) of the Safe Drinking Water Act of 1974 (Public Law 93-523, 42 U.S.C. 300 et. seq) authorizes the U.S. Environmental Protection Agency (EPA) to determine that an aquifer is the sole source of drinking water in an area and to review federally funded projects to ensure that they do not contaminate a sole source aquifer.

  3. 30 TAC 213 - Edwards Aquifer | Open Energy Information

    Open Energy Info (EERE)

    13 - Edwards Aquifer Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 30 TAC 213 - Edwards AquiferLegal Published NA Year...

  4. Reconstructing Past Ocean Salinity ((delta)18Owater)

    SciTech Connect (OSTI)

    Guilderson, T P; Pak, D K

    2005-11-23

    Temperature and salinity are two of the key properties of ocean water masses. The distribution of these two independent but related characteristics reflects the interplay of incoming solar radiation (insolation) and the uneven distribution of heat loss and gain by the ocean, with that of precipitation, evaporation, and the freezing and melting of ice. Temperature and salinity to a large extent, determine the density of a parcel of water. Small differences in temperature and salinity can increase or decrease the density of a water parcel, which can lead to convection. Once removed from the surface of the ocean where 'local' changes in temperature and salinity can occur, the water parcel retains its distinct relationship between (potential) temperature and salinity. We can take advantage of this 'conservative' behavior where changes only occur as a result of mixing processes, to track the movement of water in the deep ocean (Figure 1). The distribution of density in the ocean is directly related to horizontal pressure gradients and thus (geostrophic) ocean currents. During the Quaternary when we have had systematic growth and decay of large land based ice sheets, salinity has had to change. A quick scaling argument following that of Broecker and Peng [1982] is: the modern ocean has a mean salinity of 34.7 psu and is on average 3500m deep. During glacial maxima sea level was on the order of {approx}120m lower than present. Simply scaling the loss of freshwater (3-4%) requires an average increase in salinity a similar percentage or to {approx}35.9psu. Because much of the deep ocean is of similar temperature, small changes in salinity have a large impact on density, yielding a potentially different distribution of water masses and control of the density driven (thermohaline) ocean circulation. It is partly for this reason that reconstructions of past salinity are of interest to paleoceanographers.

  5. Geochemical Triggers of Arsenic Mobilization during Managed Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recharge | Stanford Synchrotron Radiation Lightsource Geochemical Triggers of Arsenic Mobilization during Managed Aquifer Recharge Monday, February 29, 2016 Managed aquifer recharge (MAR) is an increasingly used water enhancement strategy, which involves subsurface storage of water supplies in groundwater aquifers. While MAR projects have the potential to alleviate water deficits, they can also adversely impact groundwater quality by altering the native geochemistry of the aquifer and

  6. Treating nahcolite containing formations and saline zones

    DOE Patents [OSTI]

    Vinegar, Harold J

    2013-06-11

    A method for treating a nahcolite containing subsurface formation includes removing water from a saline zone in or near the formation. The removed water is heated using a steam and electricity cogeneration facility. The heated water is provided to the nahcolite containing formation. A fluid is produced from the nahcolite containing formation. The fluid includes at least some dissolved nahcolite. At least some of the fluid is provided to the saline zone.

  7. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Interim Progress Report

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Hao, Y; Bourcier, W L

    2009-07-22

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including nanofiltration (NF) and reverse osmosis (RO). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine would be reinjected into the formation at net volume reduction. This process provides additional storage space (capacity) in the aquifer, reduces operational risks by relieving overpressure in the aquifer, and provides a source of low-cost fresh water to offset costs or operational water needs. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations for brines typical of CCS sites. Computer modeling is being used to evaluate processes in the aquifer, including the evolution of the pressure field. This progress report deals mainly with our geochemical modeling of high-salinity brines and covers the first six months of project execution (September, 2008 to March, 2009). Costs and implementation results will be presented in the annual report. The brines typical of sequestration sites can be several times more concentrated than seawater, requiring specialized modeling codes typical of those developed for nuclear waste disposal calculations. The osmotic pressure developed as the brines are concentrated is of particular concern, as are precipitates that can cause fouling of reverse osmosis membranes and other types of membranes (e.g., NF). We have now completed the development associated with tasks (1) and (2) of the work plan. We now have a contract with Perlorica, Inc., to provide support to the cost analysis and nanofiltration evaluation. We have also conducted several preliminary analyses of the pressure effect in the reservoir in order to confirm that reservoir pressure can indeed be used to drive the reverse osmosis process. Our initial conclusions from the work to date are encouraging: (1) The concept of aquifer-pressured RO to provide fresh water associated with carbon dioxide storage appears feasible. (2) Concentrated brines such as those found in Wyoming are amenable to RO treatment. We have looked at sodium chloride brines from the Nugget Formation in Sublette County. 20-25% removal with conventional methods is realistic; higher removal appears achievable with NF. The less concentrated sulfate-rich brines from the Tensleep Formation in Sublette County would support >80% removal with conventional RO. (3) Brines from other proposed sequestration sites can now be analyzed readily. An osmotic pressure curve appropriate to these brines can be used to evaluate cost and equipment specifications. (4) We have examined a range of subsurface brine compositions that is potentially pertinent to carbon sequestration and noted the principal compositional trends pertinent to evaluating the feasibility of freshwater extraction. We have proposed a general categorization for the feasibility of the process based on total dissolved solids (TDS). (5) Withdrawing pressurized brine can have a very beneficial effect on reservoir pressure and total available storage capacity. Brine must be extracted from a deeper location in the aquifer than the point of CO{sub 2} injection to prevent CO{sub 2} from migrating to the brine extraction well.

  8. Pre-feasibility Study to Identify Opportunities for Increasing CO2 Storage in Deep, Saline Aquifers by Active Aquifer Management and Treatment of Produced Water

    SciTech Connect (OSTI)

    Stauffer, Philip H.

    2014-09-05

    In this report, we present initial estimates of CO2 injectivity and plume radius for injection of 0.1 MT/yr and 1 MT/yr. Results for 1 and 10 years of injection are used to show how the plume from a single injector well could grow through time for a simplified, idealized system. Most results are for a 2 km deep injection well, while several results from a deeper plume are also presented to demonstrate the impact of changing depth and temperature.

  9. Chemical and Isotopic Prediction of Aquifer Temperatures in the...

    Open Energy Info (EERE)

    of Aquifer Temperatures in the Geothermal System at Long Valley, California Authors R.O. Fournier, Michael L. Sorey, Robert H. Mariner and Alfred H. Truesdell Published Journal...

  10. Sole Source Aquifer Demonstration Program | Open Energy Information

    Open Energy Info (EERE)

    Demonstration Program Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Sole Source Aquifer Demonstration ProgramLegal...

  11. Aquifer thermal energy (heat and chill) storage

    SciTech Connect (OSTI)

    Jenne, E.A.

    1992-11-01

    As part of the 1992 Intersociety Conversion Engineering Conference, held in San Diego, California, August 3--7, 1992, the Seasonal Thermal Energy Storage Program coordinated five sessions dealing specifically with aquifer thermal energy storage technologies (ATES). Researchers from Sweden, The Netherlands, Germany, Switzerland, Denmark, Canada, and the United States presented papers on a variety of ATES related topics. With special permission from the Society of Automotive Engineers, host society for the 1992 IECEC, these papers are being republished here as a standalone summary of ATES technology status. Individual papers are indexed separately.

  12. Aquifer Sampling Tube Results for Fiscal Year 2003

    SciTech Connect (OSTI)

    Hartman, Mary J.; Peterson, Robert E.

    2003-10-27

    This report presents and discusses results of the fiscal year 2003 sampling event associated with aquifer tubes along the Columbia River in the northern Hanford Site. Aquifer tube data help define the extent of groundwater contamination near the river, determine vertical variations in contamination, monitor the performance of interim remedial actions near the river, and support impact studies.

  13. Tracer advection by steady groundwater flow in a stratified aquifer

    SciTech Connect (OSTI)

    Sposito, Garrison; Weeks, Scott W.

    1997-01-02

    The perfectly stratified aquifer has often been investigated as a simple, tractable model for exploring new theoretical issues in subsurface hydrology. Adopting this approach, we show that steady groundwater flows in the perfectly stratified aquifer are always confined to a set of nonintersecting permanent surfaces, on which both streamlines and vorticity lines lie. This foliation of the flow domain exists as well for steady groundwater flows in any isotropic, spatially heterogeneous aquifer. In the present model example it is a direct consequence of the existence of a stream function, we then demonstrate that tracer plume advection by steady groundwater flow in a perfectly stratified aquifer is never ergodic, regardless of the initial size of the tracer plume. This nonergodicity, which holds also for tracer advection in any isotropic, spatially heterogeneous aquifer, implies that stochastic theories of purely advective tracer plume movement err in assuming ergodic behavior to simplify probabilistic calculations of plume spatial concentration moments.

  14. Method for isolating two aquifers in a single borehole

    DOE Patents [OSTI]

    Burklund, Patrick W.

    1985-10-22

    A method for isolating and individually instrumenting separate aquifers within a single borehole. A borehole is first drilled from the ground surface, through an upper aquifer, and into a separating confining bed. A casing, having upper and lower sections separated by a coupling collar, is lowered into the borehole. The borehole is grouted in the vicinity of the lower section of the casing. A borehole is then drilled through the grout plug and into a lower aquifer. After the lower aquifer is instrumented, the borehole is grouted back into the lower portion of the casing. Then the upper section of the casing is unscrewed via the coupling collar and removed from the borehole. Finally, instrumentation is added to the upper aquifer and the borehole is appropriately grouted. The coupling collar is designed to have upper right-hand screw threads and lower left-hand screw thread, whereby the sections of the casing can be readily separated.

  15. Method for isolating two aquifers in a single borehole

    DOE Patents [OSTI]

    Burklund, P.W.

    1984-01-20

    A method for isolating and individually instrumenting separate aquifers within a single borehole is disclosed. A borehole is first drilled from the ground surface, through an upper aquifer, and into a separating confining bed. A casing, having upper and lower sections separated by a coupling collar, is lowered into the borehole. The borehole is grouted in the vicinity of the lower section of the casing. A borehole is then drilled through the grout plug and into a lower aquifer. After the lower aquifer is instrumented, the borehole is grouted back into the lower portion of the casing. Then the upper section of the casing is unscrewed via the coupling collar and removed from the borehole. Finally, instrumentation is added to the upper aquifer and the borehole is appropriately grouted. The coupling collar is designed to have upper right-hand screw threads and lower left-hand screw thread, whereby the sections of the casing can be readily separated.

  16. Appendix B Surface Infiltration and Aquifer Test Data

    Office of Legacy Management (LM)

    B Surface Infiltration and Aquifer Test Data This page intentionally left blank ... 1000 1100 1200 1300 1400 TIME (MIN) INF-8 TEST I 300 400 TIME (MIN) INF-8 TEST 2 200 250 ...

  17. Underground helium travels to the Earth's surface via aquifers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tweet EmailPrint Before it can put the party in party balloons, helium is carried from deep within the Earth's crust to the surface via aquifers, according to new research...

  18. Simulation analysis of the unconfined aquifer, Raft River Geothermal...

    Open Energy Info (EERE)

    analysis of the unconfined aquifer, Raft River Geothermal Area, Idaho-Utah Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Simulation analysis of the...

  19. On parameterization of the inverse problem for estimating aquifer

    Office of Scientific and Technical Information (OSTI)

    properties using tracer data (Journal Article) | SciTech Connect On parameterization of the inverse problem for estimating aquifer properties using tracer data Citation Details In-Document Search Title: On parameterization of the inverse problem for estimating aquifer properties using tracer data Authors: Kowalsky, M. B. ; Finsterle, S. ; Commer, M. ; Williams, K. H. ; Murray, C. ; Newcomer, D. ; Englert, A. ; Steefel, C. I. ; Hubbard, S. S. Publication Date: 2012-01-01 OSTI Identifier:

  20. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  1. Anaerobic biodegradation of BTEX in aquifer material. Environmental research brief

    SciTech Connect (OSTI)

    Borden, R.C.; Hunt, M.J.; Shafer, M.B.; Barlaz, M.A.

    1997-08-01

    Laboratory and field experiments were conducted in two petroleum-contaminated aquifers to examine the anaerobic biodegradation of benzene, toluene, ethylbenzene and xylene isomers (BTEX) under ambient conditions. Aquifer material was collected from locations at the source, mid-plume and end-plume at both sites, incubated under ambient conditions, and monitored for disappearance of the test compounds. In the mid-plume location at the second site, in-situ column experiments were also conducted for comparison with the laboratory microscosm and field-scale results. In the end-plume microcosms, biodegradation was variable with extensive biodegradation in some microcosms and little or no biodegradation in others.

  2. Legal and regulatory issues affecting aquifer thermal energy storage

    SciTech Connect (OSTI)

    Hendrickson, P.L.

    1981-10-01

    This document updates and expands the report with a similar title issued in October 1980. This document examines a number of legal and regulatory issues that potentially can affect implementation of the aquifer thermal energy storage (ATES) concept. This concept involves the storage of thermal energy in an underground aquifer until a later date when it can be effectively utilized. Either heat energy or chill can be stored. Potential end uses of the energy include district space heating and cooling, industrial process applications, and use in agriculture or aquaculture. Issues are examined in four categories: regulatory requirements, property rights, potential liability, and issues related to heat or chill delivery.

  3. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins. Applied

    Office of Scientific and Technical Information (OSTI)

    Studies in Reservoir Assessment and Dynamic Processes Affecting Industrial Operations (Technical Report) | SciTech Connect CO2 Saline Storage Demonstration in Colorado Sedimentary Basins. Applied Studies in Reservoir Assessment and Dynamic Processes Affecting Industrial Operations Citation Details In-Document Search Title: CO2 Saline Storage Demonstration in Colorado Sedimentary Basins. Applied Studies in Reservoir Assessment and Dynamic Processes Affecting Industrial Operations This

  4. Stormwater runoff policy on the Spokane/Rathdrum Prairie Aquifer

    SciTech Connect (OSTI)

    Hale, E.O.

    1990-01-01

    The Panhandle Health District, in conjunction with the Idaho Department of Water Resources, is developing a stormwater runoff control program under the US EPA Wellhead Protection Program. The goal of the project is to protect the Spokane Valley/Rathdrum Prairie Aquifer from widespread subsurface disposal of stormwater runoff via shallow injection wells. Studies conducted by the health district in 1976 and 1977 established that areas downgradient from urban land uses had elevated nitrate level sand that the aquifer is vulnerable to contamination from surface activities. The stormwater runoff controls are being developed in conjunction with similar programs, such as chemical storage and use, solid waste and subsurface sewage disposal. The expected result will be a groundwater management system that protects the resource by preventing contamination rather than a program that responds to poor water quality with costly remedial action.

  5. In Situ Biological Uranium Remediation within a Highly Contaminated Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ Biological Uranium Remediation within a Highly Contaminated Aquifer Matthew Ginder-Vogel1, Wei-Min Wu1, Jack Carley2, Phillip Jardine2, Scott Fendorf1 and Craig Criddle1 1Stanford University, Stanford, CA 2Oak Ridge National Laboratory, Oak Ridge, TN Microbial Respiration Figure 1. Uranium(VI) reduction is driven by microbial respiration resulting in the precipitation of uraninite. Uranium contamination of ground and surface waters has been detected at numerous sites throughout the

  6. Relationship of regional water quality to aquifer thermal energy storage

    SciTech Connect (OSTI)

    Allen, R.D.

    1983-11-01

    Ground-water quality and associated geologic characteristics may affect the feasibility of aquifer thermal energy storage (ATES) system development in any hydrologic region. This study sought to determine the relationship between ground-water quality parameters and the regional potential for ATES system development. Information was collected from available literature to identify chemical and physical mechanisms that could adversely affect an ATES system. Appropriate beneficiation techniques to counter these potential geochemical and lithologic problems were also identified through the literature search. Regional hydrology summaries and other sources were used in reviewing aquifers of 19 drainage regions in the US to determine generic geochemical characteristics for analysis. Numerical modeling techniques were used to perform geochemical analyses of water quality from 67 selected aquifers. Candidate water resources regions were then identified for exploration and development of ATES. This study identified six principal mechanisms by which ATES reservoir permeability may be impaired: (1) particulate plugging, (2) chemical precipitation, (3) liquid-solid reactions, (4) formation disaggregation, (5) oxidation reactions, and (6) biological activity. Specific proven countermeasures to reduce or eliminate these effects were found. Of the hydrologic regions reviewed, 10 were identified as having the characteristics necessary for ATES development: (1) Mid-Atlantic, (2) South-Atlantic Gulf, (3) Ohio, (4) Upper Mississippi, (5) Lower Mississippi, (6) Souris-Red-Rainy, (7) Missouri Basin, (8) Arkansas-White-Red, (9) Texas-Gulf, and (10) California.

  7. Use of natural radionuclides to predict the behavior of radwaste radionuclides in far-field aquifers

    SciTech Connect (OSTI)

    Hubbard, N.; Laul, J.C.; Perkins, R.W.

    1984-01-01

    In appropriate aquifers the natural radionuclides of the U and Th decay series are important sources of information about the behavior of radwaste radionuclides in far-field aquifers. The Wolfcamp Carbonate, Pennsylvanian Carbonate and Granite Wash aquifers in the Palo Duro Basin of the Texas Panhandle are prime examples of such aquifers. Sampling and analysis for key radionuclides in the ground waters of these aquifers are quite feasible and have been accomplished. Key early results are: (1) Ra does not appear to be retarded by sorption, (2) Th appears to be strongly sorbed, (3) kinetics seem to be different on time scales of days to months than on ones of hundreds of thousands of years, and (4) U and Th behave similarly when the time scales (half-lives) are similar, leading to the suggestion that uranium is in the +4 valence state in these aquifers. 10 references, 3 figures.

  8. Preliminary potentiometric map and flow dynamic characteristics for the upper-basalt confined aquifer system

    SciTech Connect (OSTI)

    Spane, F.A. Jr.; Raymond, R.G.

    1993-09-01

    This report presents the first comprehensive Hanford Site-wide potentiometric map for the upper-basalt confined aquifer system (i.e., the upper Saddle Mountains Basalt). In constructing the potentiometric map, over forty on-site and off-site monitoring wells and boreholes were used. The potentiometric map developed for the upper-basalt confined aquifer is consistent with the areal head pattern indicated for the Mabton interbed, which is a deeper and more areally extensive confined aquifer underlying the Hanford Site. Salient features for the upper-basalt confined aquifer system potentiometric map are described.

  9. Potential Risks of Freshwater Aquifer Contamination with Geosequestration

    SciTech Connect (OSTI)

    Jackson, Robert

    2013-09-30

    Substantial leakage of CO{sub 2} from deep geological strata to shallow potable aquifers is likely to be rare, but chemical detection of potential leakage nonetheless remains an integral component of any safe carbon capture and storage system. CO{sub 2} that infiltrates an unconfined freshwater aquifer will have an immediate impact on water chemistry by lowering pH in most cases and by altering the concentration of total dissolved solids. Chemical signatures in affected waters provide an important opportunity for early detection of leaks. In the presence of CO{sub 2}, trace elements such as Mn, Fe, and Ca can increase by an order of magnitude or more above control concentrations within 100 days. Therefore, these and other elements should be monitored along with pH as geochemical markers of potential CO{sub 2} leaks. Dissolved inorganic carbon and alkalinity can also be rapidly responsive to CO{sub 2} and are stable indicators of a leak. Importantly, such changes may be detectable long before direct changes in CO{sub 2} are observed. The experimental results also suggest that the relative severity of the impact of leaks on overlying drinking-water aquifers should be considered in the selection of CO{sub 2} sequestration sites. One primary selection criteria should be metal and metalloid availability, such as uranium and arsenic abundance, to carefully monitor chemical species that could trigger changes above maximum contaminant levels (MCLs). Overall, the risks of leakage from underground CO{sub 2} storage are real but appear to be manageable if systems are closely monitored.

  10. Regional assessment of aquifers for thermal-energy storage. Volume 2. Regions 7 through 12

    SciTech Connect (OSTI)

    Not Available

    1981-06-01

    This volume contains information on the geologic and hydrologic framework, major aquifers, aquifers which are suitable and unsuitable for annual thermal energy storage (ATES) and the ATES potential of the following regions of the US: Unglaciated Central Region; Glaciated Appalachians, Unglaciated Appalachians; Coastal Plain; Hawaii; and Alaska. (LCL)

  11. Effects of surfactants on the desorption of organic contaminants from aquifer materials. Doctoral thesis

    SciTech Connect (OSTI)

    Brickell, J.L.

    1989-08-01

    The efficiency of removing organic contaminants from groundwater aquifers by the pump and treat process is adversely affected by the retardation of the contaminant's mobility due to adsorption onto aquifer material. The use of surfactants in conjunction with the pump and treat process has the potential for improving contaminant mobility by solubilizing the adsorbed contaminant.

  12. The University of Minnesota aquifer thermal energy storage (ATES) field test facility -- system description, aquifer characterization, and results of short-term test cycles

    SciTech Connect (OSTI)

    Walton, M.; Hoyer, M.C.; Eisenreich, S.J.; Holm, N.L.; Holm, T.R.; Kanivetsky, R.; Jirsa, M.A.; Lee, H.C.; Lauer, J.L.; Miller, R.T.; Norton, J.L.; Runke, H. )

    1991-06-01

    Phase 1 of the Aquifer Thermal Energy Storage (ATES) Project at the University of Minnesota was to test the feasibility, and model, the ATES concept at temperatures above 100{degrees}C using a confined aquifer for the storage and recovery of hot water. Phase 1 included design, construction, and operation of a 5-MW thermal input/output field test facility (FTF) for four short-term ATES cycles (8 days each of heat injection, storage, and heat recover). Phase 1 was conducted from May 1980 to December 1983. This report describes the FTF, the Franconia-Ironton-Galesville (FIG) aquifer used for the test, and the four short-term ATES cycles. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are all included. The FTF consists of monitoring wells and the source and storage well doublet completed in the FIG aquifer with heat exchangers and a fixed-bed precipitator between the wells of the doublet. The FIG aquifer is highly layered and a really anisotropic. The upper Franconia and Ironton-Galesville parts of the aquifer, those parts screened, have hydraulic conductivities of {approximately}0.6 and {approximately}1.0 m/d, respectively. Primary ions in the ambient ground water are calcium and magnesium bicarbonate. Ambient temperature FIG ground water is saturated with respect to calcium/magnesium bicarbonate. Heating the ground water caused most of the dissolved calcium to precipitate out as calcium carbonate in the heat exchanger and precipitator. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water, suggesting dissolution of some constituents of the aquifer during the cycles. Further work on the ground water chemistry is required to understand water-rock interactions.

  13. Generalized thickness and configuration of the top of the intermediate aquifer, West-Central Florida

    SciTech Connect (OSTI)

    Corral, M.A. Jr.; Wolansky, R.M.

    1984-01-01

    The water-bearing units of the intermediate aquifer consist of discontinuous sand, gravel, shell, and limestone and dolomite beds in the Tamiami Formation of late Miocene age and the Hawthorn Formation of middle Miocene age. Within parts of Polk, Manatee, Hardee, De Soto, Sarasota, and Charlotte Counties, sand and clay beds within the Tampa Limestone that are hydraulically connected to the Hawthorn Formation are also included in the intermediate aquifer. 15 refs.

  14. A method for quick assessment of CO2 storage capacity in closedand semi-closed saline formations

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Tsang, C.F.; Rutqvist, J.

    2008-02-10

    Saline aquifers of high permeability bounded by overlying/underlying seals may be surrounded laterally by low-permeability zones, possibly caused by natural heterogeneity and/or faulting. Carbon dioxide (CO{sub 2}) injection into and storage in such 'closed' systems with impervious seals, or 'semi-closed' systems with nonideal (low-permeability) seals, is different from that in 'open' systems, from which the displaced brine can easily escape laterally. In closed or semi-closed systems, the pressure buildup caused by continuous industrial-scale CO{sub 2} injection may have a limiting effect on CO{sub 2} storage capacity, because geomechanical damage caused by overpressure needs to be avoided. In this research, a simple analytical method was developed for the quick assessment of the CO{sub 2} storage capacity in such closed and semi-closed systems. This quick-assessment method is based on the fact that native brine (of an equivalent volume) displaced by the cumulative injected CO{sub 2} occupies additional pore volume within the storage formation and the seals, provided by pore and brine compressibility in response to pressure buildup. With nonideal seals, brine may also leak through the seals into overlying/underlying formations. The quick-assessment method calculates these brine displacement contributions in response to an estimated average pressure buildup in the storage reservoir. The CO{sub 2} storage capacity and the transient domain-averaged pressure buildup estimated through the quick-assessment method were compared with the 'true' values obtained using detailed numerical simulations of CO{sub 2} and brine transport in a two-dimensional radial system. The good agreement indicates that the proposed method can produce reasonable approximations for storage-formation-seal systems of various geometric and hydrogeological properties.

  15. Salinity, temperature, oil composition, and oil recovery by waterflooding

    SciTech Connect (OSTI)

    Tang, G.Q.; Morrow, N.R.

    1997-11-01

    The effect of aging and displacement temperatures and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea sandstone with three crude oils and three reservoir brines (RB`s). Salinity was varied by changing the concentration of total dissolved solids (TDS`s) of the synthetic brine in proportion. Salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the RB with dilution of both the initial (connate) and invading brine or dilution of either. Aging and displacement temperatures were varied independently. For all crude oils, water wetness and oil recovery increased with increase in displacement temperature. Removal of light components from the crude oil resulted in increased water wetness. Addition of alkanes to the crude oil reduced the water wetness, and increased oil recovery. Relationships between waterflood recovery and rate and extent of oil recovery by spontaneous imbibition are summarized.

  16. Kinetics and Mechanisms of Calcite Reactions with Saline Waters

    SciTech Connect (OSTI)

    Gorman, Brian P

    2015-09-02

    Project Description: The general objective of the proposed research is to determine the kinetics and mechanisms of calcite reactions with saline waters over a wide range of saline water composition, pCO2, and modest ranges in T and P. This will be accomplished by studying both reaction rates and solubility from changes in solution chemistry, and making nanoscale observations of calcite precipitate surface morphology and composition at the micro-to-nano-scale to provide an understanding of controlling reaction mechanisms and pathways. The specific objectives necessary to reach the general objective are: a) determination of how pCO2, Ca2+, ionic strength and foreign ions influence reaction rates; and b) investigate the influence of these parameters on apparent kinetic solubility from dissolution and precipitation reactions. This information will clearly be central to the construction of reliable reaction-transport models to predict reservoir and formation response to increased CO2 in saline waters. This program was initially collaborative with John Morse at Texas A&M, however his passing shortly after the beginning of this program resulted in abbreviated research time and effort. Summary of Results: Early studies using electron microscopy and spectroscopy indicated that carbonate precipitation from natural seawater (NSW) conditions onto aragonite substrates was mediated by a surface amorphous calcium carbonate layer. It was hypothesized that this ACC layer (observed after < 5days reaction time) was responsible for the abnormal reaction kinetics and also served as a metastable seed layer for growth of epitaxial aragonite. Further studies of the ACC formation mechanism indicated a strong dependence on the Mg concentration in solution. Subsequent studies at shorter times (10 hrs) on calcite substrates and in a wide range of supersaturation conditions did not indicate any ACC layer. Instead, an epitaxial layer by layer growth mechanism was confirmed by grazing incidence X-ray diffraction, -Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, and electron diffraction. Extended time studies out to 45 days confirmed the epitaxial relationship of the overgrowth layer with the substrate. Under NSW conditions, overgrowths were found to have ~0.4 to 0.8 nm / hr growth rates and accommodating 4 at% Mg, resulting in a highly strained overgrowth layer. Following the initial layer by layer growth mechanism, the growth changes to Stranski-Krastanov type after a critical thickness of approximately 100 nm.

  17. Salinity gradient solar pond technology applied to potash solution mining

    SciTech Connect (OSTI)

    Martell, J.A.; Aimone-Martin, C.T.

    2000-06-12

    A solution mining facility at the Eddy Potash Mine, Eddy County, New Mexico has been proposed that will utilize salinity gradient solar pond (SGSP) technology to supply industrial process thermal energy. The process will include underground dissolution of potassium chloride (KCl) from pillars and other reserves remaining after completion of primary room and pillar mining using recirculating solutions heated in the SGSP. Production of KCl will involve cold crystallization followed by a cooling pond stage, with the spent brine being recirculated in a closed loop back to the SGSP for reheating. This research uses SGSP as a renewable, clean energy source to optimize the entire mining process, minimize environmental wastes, provide a safe, more economical extraction process and reduce the need for conventional processing by crushing, grinding and flotation. The applications of SGSP technology will not only save energy in the extraction and beneficiation processes, but also will produce excess energy available for power generation, desalination, and auxiliary structure heating.

  18. Study on the properties of saline HLLW in China

    SciTech Connect (OSTI)

    Liang, J.F.; Liu, X.G.; Song, C.L.; Jiao, R.Z.

    2008-07-01

    The properties and the components of HLLW (High-level Liquid Waste) were studied. The genuine saline HLLW is a blue-green liquid with 1.399 g/mL density. The activities of {sup 137}Cs, {sup 90}Sr, {sup 99}Tc, {sup 237}Np, {sup 239}Pu, {sup 241}Am, and total {alpha}/{beta}/{gamma} were determined. The extractive properties of actinide s in the HLLW were examined in a five-stage cross-extraction test. More than 98% of the Pu in HLLW is Pu{sup 4+}, and more than 70% of the Np is Np{sup 4+}. It was shown that >99.97% of the {alpha}-nuclides were extracted by 30% TRPO-kerosene from the HLLW. The separation performance of actinides is excellent. (authors)

  19. Evaluating impacts of CO2 gas intrusion into a confined sandstone aquifer: Experimental results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  20. Evaluating Impacts of CO2 Gas Intrusion Into a Confined Sandstone aquifer: Experimental Results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  1. Evaluating Impacts of CO2 Gas Intrusion Into a Confined Sandstone aquifer: Experimental Results

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnershipmore » Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.« less

  2. Microsoft PowerPoint - Salishan (M Celia) Apr09

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of cropland worldwide. 6. Increase Solar Power 700-fold, displacing coal. 7. Increase ... the many aspects of CCS Storage in Deep Saline Aquifers Storage in Deep Saline Aquifers ...

  3. Water Influx, and Its Effect on Oil Recovery: Part 1. Aquifer Flow, SUPRI TR-103

    SciTech Connect (OSTI)

    Brigham, William E.

    1999-08-09

    Natural water encroachment is commonly seen in many oil and gas reservoirs. In fact, overall, there is more water than oil produced from oil reservoirs worldwide. Thus it is clear that an understanding of reservoir/aquifer interaction can be an important aspect of reservoir management to optimize recovery of hydrocarbons. Although the mathematics of these processes are difficult, they are often amenable to analytical solution and diagnosis. Thus this will be the ultimate goal of a series of reports on this subject. This first report deals only with aquifer behavior, so it does not address these important reservoir/aquifer issues. However, it is an important prelude to them, for the insight gained gives important clues on how to address reservoir/aquifer problems. In general when looking at aquifer flow, there are two convenient inner boundary conditions that can be considered; constant pressure or constant flow rate. There are three outer boundary conditions that are convenient to consider; infinite, closed and constant pressure. And there are three geometries that can be solved reasonably easily; linear, radial and spherical. Thus there are a total of eighteen different solutions that can be analyzed.

  4. Apparatus and method for extraction of chemicals from aquifer remediation effluent water

    DOE Patents [OSTI]

    McMurtrey, Ryan D. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID); Moor, Kenneth S. (Idaho Falls, ID); Shook, G. Michael (Idaho Falls, ID); Moses, John M. (Dedham, MA); Barker, Donna L. (Idaho Falls, ID)

    2002-01-01

    An apparatus and method for extraction of chemicals from an aquifer remediation aqueous effluent are provided. The extraction method utilizes a critical fluid for separation and recovery of chemicals employed in remediating aquifers contaminated with hazardous organic substances, and is particularly suited for separation and recovery of organic contaminants and process chemicals used in surfactant-based remediation technologies. The extraction method separates and recovers high-value chemicals from the remediation effluent and minimizes the volume of generated hazardous waste. The recovered chemicals can be recycled to the remediation process or stored for later use.

  5. Wetland Flow and Salinity Budgets and Elements of a Decision Support System toward Implementation of Real-Time Seasonal Wetland Salinity Management

    SciTech Connect (OSTI)

    Quinn, N.W.T.; Ortega, R.; Rahilly, P.; Johnson, C.B.

    2011-12-17

    The project has provided science-based tools for the long-term management of salinity in drainage discharges from wetlands to the San Joaquin River. The results of the project are being used to develop best management practices (BMP) and a decision support system to assist wetland managers adjust the timing of salt loads delivered to the San Joaquin River during spring drawdown. Adaptive drainage management scheduling has the potential to improve environmental compliance with salinity objectives in the Lower San Joaquin River by reducing the frequency of violation of Vernalis salinity standards, especially in dry and critically dry years. The paired approach to project implementation whereby adaptively managed and traditional practices were monitored in a side-by-side fashion has provided a quantitative measure of the impacts of the project on the timing of salt loading to the San Joaquin River. The most significant accomplishments of the project has been the technology transfer to wetland biologists, ditch tenders and water managers within the Grasslands Ecological Area. This “learning by doing” has build local community capacity within the Grassland Water District and California Department of Fish and Game providing these institutions with new capability to assess and effectively manage salinity within their wetlands while simultaneously providing benefits to salinity management of the San Joaquin River.

  6. Sulfur isotope evidence for regional recharge of saline water during continental glaciation, north-central United States

    SciTech Connect (OSTI)

    Siegel, D.I. )

    1990-11-01

    Sulfate concentrations in ground water from the Cambrian-Ordovician aquifer of south-eastern Wisconsin and northern Illinois increase up to hundreds of times where the aquifer is confined beneath the Maquoketa Shale. There is no sulfate source in the aquifer or overlying rocks except for minor amounts of finely disseminated pyrite. Coinciding with increasing sulfate concentrations, {delta}{sup 34}S of the dissolved sulfate increases from less than {minus}5{per thousand} in the unconfined part of the aquifer to a nearly constant value of +20{per thousand} where the aquifer is confined and where sulfate reduction is minimal. The most likely source for this isotopically heavy sulfate is ground water associated with Silurian evaporites under Lake Michigan. It is uncertain if the sulfate-rich water was emplaced in pulses or mostly during the last glaciation.

  7. Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Bacon, Diana H.; Qafoku, Nikolla; Dai, Zhenxue; Keating, Elizabeth; Brown, Christopher F.

    2016-01-01

    Multiphase, reactive transport modeling was used to identify the mechanisms controlling trace metal release under elevated CO2 conditions from a well-characterized carbonate aquifer. Modeling was conducted for two experimental scenarios: batch experiments to simulate sudden, fast, and short-lived release of CO2 as would occur in the case of well failure during injection, and column experiments to simulate more gradual leaks such as those occurring along undetected faults, fractures, or well linings. Observed and predicted trace metal concentrations are compared to groundwater concentrations from this aquifer to determine the potential for leaking CO2 to adversely impact drinking water quality. Finally, a three-dimensional multiphase flow and reactive-transport simulation of CO2 leakage from an abandoned wellbore into a generalized model of the shallow, unconfined portion of the aquifer is used to determine potential impacts on groundwater quality. As a measure of adverse impacts on groundwater quality, both the EPAs MCL limits and the maximum trace metal concentration observed in the aquifer were used as threshold values.

  8. Evaluating the impact of aquifer layer properties on geomechanical response during CO2 geological sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Xu, Zhijie; Lin, Guang; Fang, Yilin

    2013-04-01

    Numerical models play an essential role in understanding the facts of carbon dioxide (CO2) geological sequestration in the life cycle of a storage reservoir. We present a series of test cases that reflect a broad and realistic range of aquifer reservoir properties to systematically evaluate and compare the impacts on the geomechanical response to CO2 injection. In this study, a coupled hydro-mechanical model was introduced to simulate the sequestration process, and a quasi-Monte Carlo sampling method was introduced to efficiently sample the value of aquifer properties and geometry parameters. Aquifer permeability was found to be of significant importance to the geomechanical response to the injection. To study the influence of uncertainty of the permeability distribution in the aquifer, an additional series of tests is presented, based on a default permeability distribution site sample with various distribution deviations generated by the Monte Carlo sampling method. The results of the test series show that different permeability distributions significantly affect the displacement and possible failure zone.

  9. Formation dry-out from CO2 injection into saline acquifers: Part...

    Office of Scientific and Technical Information (OSTI)

    From a mass balance for water dissolved into the flowing COsub 2 stream, and a ... at the dry-out front to temperature, pressure and salinity dependence of fluid properties. ...

  10. Formation dry-out from CO2 injection into saline acquifers: Part...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Formation dry-out from CO2 injection into saline acquifers: Part 2, Analytical model for salt precipitation You are accessing a ...

  11. Evaluating Impacts of CO2 Intrusion into an Unconsolidated Aquifer. I. Experimental Data

    SciTech Connect (OSTI)

    Lawter, Amanda R.; Qafoku, Nikolla; Wang, Guohui; Shao, Hongbo; Brown, Christopher F.

    2015-08-04

    Capture and deep subsurface sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Batch and column experiments combined with wet chemical extractions were conducted to evaluate these risks to groundwater quality and to understand effects of CO2 leakage on aquifer chemistry and mineralogy. Sediments from the High Plains aquifer in Kansas, a confined sandstone aquifer, were used to study time-dependent release of major, minor and trace elements when exposed to CO2 gas. Results showed that Ca, Ba, Si, Mg, Sr, Na, and K increased either instantaneously or followed nonlinear increasing trends with time, indicating dissolution and/or desorption reactions controlled their release. Other elements, such as Mn and Fe, were also released from all sediments, creating a potential for redox reactions to occur. Results from acid extractions confirmed sediments had appreciable amounts of contaminants that may potentially be released into the aqueous phase. However, results from the batch and column experiments demonstrated that only a few trace elements (e.g., As, Cu, Cr, Pb) were released, indicating the risk of groundwater quality degradation due to exposure to leakage of sequestered CO2 is low. Concentrations of Mo were consistently higher in the control experiments (absence of CO2) and were below detection in the presence of CO2 indicating a possible benefit of CO2 in groundwater aquifers. These investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  12. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and competency. The results from these investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological, deep subsurface CO2 storage and sequestration.

  13. Responses of estuarine circulation and salinity to the loss of intertidal flats – A modeling study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Zhaoqing; Wang, Taiping

    2015-08-25

    Intertidal flats in estuaries are coastal wetlands that provide critical marine habitats to support wide ranges of marine species. Over the last century many estuarine systems have experienced significant loss of intertidal flats due to anthropogenic impacts. This paper presents a modeling study conducted to investigate the responses of estuarine hydrodynamics to the loss of intertidal flats caused by anthropogenic actions in Whidbey Basin of Puget Sound on the northwest coast of North America. Changes in salinity intrusion limits in the estuaries, salinity stratification, and circulation in intertidal flats and estuaries were evaluated by comparing model results under the existingmore » baseline condition and the no-flat condition. Model results showed that loss of intertidal flats results in an increase in salinity intrusion, stronger mixing, and a phase shift in salinity and velocity fields in the bay front areas. Model results also indicated that loss of intertidal flats enhances two-layer circulation, especially the bottom water intrusion. Loss of intertidal flats increases the mean salinity but reduces the salinity range in the subtidal flats over a tidal cycle because of increased mixing. Salinity intrusion limits extend upstream in all three major rivers discharging into Whidbey Basin when no intertidal flats are present. Changes in salinity intrusion and estuarine circulation patterns due to loss of intertidal flats affect the nearshore habitat and water quality in estuaries and potentially increase risk of coastal hazards, such as storm surge and coastal flooding. Furthermore, model results suggested the importance of including intertidal flats and the wetting-and-drying process in hydrodynamic simulations when intertidal flats are present in the model domain.« less

  14. Saline Infusion Markedly Reduces Impedance and Improves Efficacy of Pulmonary Radiofrequency Ablation

    SciTech Connect (OSTI)

    Gananadha, Sivakumar Morris, David Lawson

    2004-08-15

    Radiofrequency ablation (RFA) is a relatively new technique that has been investigated for the treatment of lung tumors. We evaluated for the first time the in vivo use of saline infusion during radiofrequency ablation of sheep lung. We performed RFA on 5 sheep using open and closed chest RFA and the RITA starburst XL and Xli probes using saline infusion with the Xli probe. The impedance and volume of ablation were compared. A total of 16 ablations were produced, 5 percutaneously and 11 open. The impedance during percutaneous and open RFA without saline infusion was 110 {+-} 16.2 and 183.3 {+-} 105.8 O, respectively. With the saline infusion the impedance was 71.3 {+-} 22O and 103.6 {+-} 37.5O. The effect of this was a significantly larger volume of ablation using the saline infusion during percutaneous RFA (90.6 {+-} 23 cm{sup 3} vs 10.47 {+-} 2.9 cm{sup 3}, p = 0.01) and open RFA (107.8 {+-} 25.8 cm{sup 3} vs 24.9 {+-} 19.3 cm{sup 3}, p = 0.0002). Saline infusion during RFA is associated with lower impedance, higher power delivery and larger lesion size.

  15. Determination of the original-gas-in-place and aquifer properties in a water-drive reservoir by optimization technique

    SciTech Connect (OSTI)

    Chen, T.L.; Lin, Z.S.; Chen, Y.L.

    1995-10-01

    The purpose of this study was to estimate the original-gas-in-place (OGIP) of a water-drive reservoir using optimization algorithm for Port Arthur field, Texas, US. The properties of the associate aquifer were also obtained. The good agreement, between the results from this study and those from simulation study, would be demonstrated in this paper. In this study, material balance equation for a gas reservoir and van Everdingen-Hurst model for an aquifer were solved simultaneously to calculate cumulative gas production. The result was then compared with cumulative gas production measured in the field that observed at each pressure. The following parameters were manually adjusted to obtain: OGIP, thickness of the aquifer, water encroachment angle, ratio of aquifer to reservoir radius, and aquifer`s permeability. The procedure was then applied with simplex technique, an optimization algorithm, to adjust parameters automatically. When the difference between cumulative gas production calculated and observed was minimal, the parameters used in the model would be the results obtained. A water-drive gas reservoir, ``C`` sand gas reservoir in Port Arthur field, which had produced for about 12 years, was analyzed successfully. The results showed that the OGIP of 60.6 BCF estimated in this study was favorably compared with 56.2 BCF obtained by a numerical simulator in other study. In addition, the aquifer properties that were unavailable from the conventional plotting method can be estimated from this study. The estimated aquifer properties from this study were compared favorably with the core data.

  16. Geostatistical Simulation of Hydrofacies Heterogeneity of the West Thessaly Aquifer Systems in Greece

    SciTech Connect (OSTI)

    Modis, K. Sideri, D.

    2013-06-15

    Integrating geological properties, such as relative positions and proportions of different hydrofacies, is of highest importance in order to render realistic geological patterns. Sequential indicator simulation (SIS) and Plurigaussian simulation (PS) are alternative methods for conceptual and deterministic modeling for the characterization of hydrofacies distribution. In this work, we studied the spatial differentiation of hydrofacies in the alluvial aquifer system of West Thessaly basin in Greece. For this, we applied both SIS and PS techniques to an extensive set of borehole data from that basin. Histograms of model versus experimental hydrofacies proportions and indicative cross sections were plotted in order to validate the results. The PS technique was shown to be more effective in reproducing the spatial characteristics of the different hydrofacies and their distribution across the study area. In addition, the permeability differentiations reflected in the PS model are in accordance to known heterogeneities of the aquifer capacity.

  17. Water-supply potential of the Upper Floridan aquifer in the vicinity of Savannah, Georgia

    SciTech Connect (OSTI)

    Garza, R.; Krause, R.E. )

    1993-03-01

    The Upper Floridan aquifer is the primary source of freshwater in coastal Georgia. Groundwater withdrawal in the area of Savannah and in the adjacent coastal areas in Georgia and South Carolina has resulted in large regional water-level declines and a reversal of the hydraulic gradient that existed prior to development. Changes in gradient and decreasing water levels are causing lateral encroachment of seawater into the Upper Floridan aquifer at the northern end of Hilton Head Island, SC, and vertical intrusion of saltwater into the Upper and Lower Floridan aquifers in the Brunswick, GA., area. Concerns about future water-supply demands prompted the US Geological Survey and the Chatham County-Savannah Metropolitan Planning Commission to undertake a cooperative study to evaluate the ground-water resources in the Savannah, GA, area. A numerical ground-water flow model was developed and used in conjunction with other previously calibrated models in the coastal areas of Georgia and South Carolina to simulate the effects of additional ground-water withdrawal on water levels. Based on model simulations and the constraint of preventing additional water-level declines at the locations of encroachment and intrusion, the potential of the Upper Floridan aquifer to supply additional water in the Savannah area is limited under present hydrologic conditions. The potential for additional withdrawal in the vicinity of Savannah, GA, ranges from less than 1 million gallons per day (Mgal/d) to about 5 Mgal/d. Because of the limited water-supply potential, hypothetical alternatives of ground-water withdrawal were simulated to determine the effects on water levels. These simulations indicate that reduction and redistribution of ground-water withdrawal would not adversely affect water levels at the locations of encroachment and intrusion.

  18. Summary of three dimensional pump testing of a fractured rock aquifer in the western Siberian Basin

    SciTech Connect (OSTI)

    Nichols, R.L.; Looney, B.B.; Eddy-Dilek, C.A.; Drozhko, E.G.; Glalolenko, Y.V.; Mokrov, Y.G.; Ivanov, I.A.; Glagolev, A.V.; Vasil`kova, N.A.

    1996-10-30

    A group of scientists from the Savannah River Technology Center and Russia successfully completed a 17 day field investigation of a fractured rock aquifer at the MAYAK PA nuclear production facility in Russia. The test site is located in the western Siberian Basin near the floodplain of the Mishelyak river. The fractured rock aquifer is composed of orphyrites, tuff, tuffbreccia and lava and is overlain by 0.5--12 meters of elluvial and alluvial sediments. A network of 3 uncased wells (176, 1/96, and 2/96) was used to conduct the tests. Wells 176 and 2/96 were used as observation wells and the centrally located well 1/96 was used as the pumping well. Six packers were installed and inflated in each of the observation wells at a depth of up to 85 meters. The use of 6 packers in each well resulted in isolating 7 zones for monitoring. The packers were inflated to different pressures to accommodate the increasing hydrostatic pressure. A straddle packer assembly was installed in the pumping well to allow testing of each of the individual zones isolated in the observation wells. A constant rate pumping test was run on each of the 7 zones. The results of the pumping tests are included in Appendix A. The test provided new information about the nature of the fractured rock aquifers in the vicinity of the Mishelyak river and will be key information in understanding the behavior of contaminants originating from process wastes discharged to Lake Karachi. Results from the tests will be analyzed to determine the hydraulic properties of different zones within the fractured rock aquifer and to determine the most cost effective clean-up approach for the site.

  19. Low-Salinity Waterflooding to Improve Oil Recovery - Historical Field Evidence

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-11-01

    Waterflooding is by far the most widely applied method of improved oil recovery. Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of wa-terfloods. Laboratory water-flood tests and single-well tracer tests have shown that injection of dilute brine can increase oil recovery, but work designed to test the method on a field scale has not yet been undertaken. Historical waterflood records could unintentionally provide some evidence of improved recovery from waterflooding with lower salinity brine. Nu-merous fields in the Powder River basin of Wyoming have been waterflooded using low salinity brine (about 500 ppm) obtained from the Madison limestone or Fox Hills sandstone. Three Minnelusa formation fields in the basin were identified as potential candidates for waterflood comparisons based on the salinity of the connate and injection water. Historical pro-duction and injection data for these fields were obtained from the public record. Field waterflood data were manipulated to be displayed in the same format as laboratory coreflood re-sults. Recovery from fields using lower salinity injection wa-ter was greater than that using higher salinity injection wa-ter—matching recovery trends for laboratory and single-well tests.

  20. Flow and Transport in the Hanford 300 Area Vadose Zone-Aquifer-River System

    SciTech Connect (OSTI)

    Waichler, Scott R.; Yabusaki, Steven B.

    2005-07-13

    Contaminant migration in the 300 Area unconfined aquifer is strongly coupled to fluctuations in the Columbia River stage. To better understand the interaction between the river, aquifer, and vadose zone, a 2-D saturated-unsaturated flow and transport model was developed for a vertical cross-section aligned west-east across the Hanford Site 300 Area, nearly perpendicular to the river. The model was used to investigate water flow and tracer transport in the vadose zone-aquifer-river flow system, in support of the ongoing study of the 300 Area uranium plume. The STOMP simulator was used to model 1-year from 3/1/92 to 2/28/93, a period when hourly data were available for both groundwater and river levels. Net water flow to the river (per 1-meter width of shoreline) was 182 m3/y in the base case, but the cumulative exchange or total flow back and forth across the riverbed was 30 times greater. The low river case had approximately double the net water and Groundwater tracer flux into the river as compared to the base case.

  1. Metabolic interdependencies between phylogenetically novel fermenters and respiratory organisms in an unconfined aquifer

    SciTech Connect (OSTI)

    Wrighton, Kelly C.; Castelle, Cindy; Wilkins, Michael J.; Hug, Laura A.; Sharon, I.; Thomas, Brian C.; Handley, Kim M.; Mullin, Sean W.; Nicora, Carrie D.; Singh, Andrea; Lipton, Mary S.; Long, Philip E.; Williams, Kenneth H.; Banfield, Jillian F.

    2014-07-08

    Fermentation-based metabolism is an important ecosystem function often associated with environments rich in organic carbon, such as wetlands, sewage sludge, and the mammalian gut. The diversity of microorganisms and pathways involved in carbon and hydrogen cycling in sediments and aquifers and the impacts of these processes on other biogeochemical cycles remain poorly understood. Here we used metagenomics and proteomics to characterize microbial communities sampled from an aquifer adjacent to the Colorado River at Rifle, Colorado, USA, and document interlinked microbial roles in geochemical cycling. The organic carbon content in the aquifer was elevated via two acetate-based biostimulation treatments. Samples were collected at three time points, with the objective of extensive genome recovery to enable metabolic reconstruction of the community. Fermentative community members include genomes from a new phylum (ACD20), phylogenetically novel members of the Chloroflexi and Bacteroidetes, as well as candidate phyla genomes (OD1, BD1-5, SR1, WWE3, ACD58, TM6, PER, and OP11). These organisms have the capacity to produce hydrogen, acetate, formate, ethanol, butyrate, and lactate, activities supported by proteomic data. The diversity and expression of hydrogenases suggests the importance of hydrogen currency in the subsurface. Our proteogenomic data further indicate the consumption of fermentation intermediates by Proteobacteria can be coupled to nitrate, sulfate, and iron reduction. Thus, fermentation carried out by previously unstudied members of sediment microbial communities may be an important driver of diverse subsurface biogeochemical cycles.

  2. Collection of High Energy Yielding Strains of Saline Microalgae from the Hawaiian Islands: Final Technical Report, Year 1

    SciTech Connect (OSTI)

    York, R. H.

    1986-01-01

    Microalgae were collected from 48 locations in the Hawaiian Islands in 1985. The sites were an aquaculture tank; a coral reef; bays; a geothermal steam vent; Hawaiian fish ponds; a Hawaiian salt punawai (well); the ocean; river mouths; saline lakes; saline pools; saline ponds; a saline swamp; and the ponds, drainage ditches and sumps of commercial shrimp farms. From 4,800 isolations, 100 of the most productive clones were selected to be maintained by periodic transfer to sterile medium. Five clones were tested for growth rate and production in a full-spectrum-transmitting solarium.

  3. Information technology and decision support tools for stakeholder-driven river basin salinity management

    SciTech Connect (OSTI)

    Quinn, N.W.T; Cozad, D.B.; Lee, G.

    2010-01-01

    Innovative strategies for effective basin-scale salinity management have been developed in the Hunter River Basin of Australia and more recently in the San Joaquin River Basin of California. In both instances web-based stakeholder information dissemination has been a key to achieving a high level of stakeholder involvement and the formulation of effective decision support salinity management tools. A common element to implementation of salinity management strategies in both river basins has been the concept of river assimilative capacity for controlling export salt loading and the potential for trading of the right to discharge salt load to the river - the Hunter River in Australia and the San Joaquin River in California. Both rivers provide basin drainage and the means of exporting salt to the ocean. The paper compares and contrasts the use of monitoring, modeling and information dissemination in the two basins to achieve environmental compliance and sustain irrigated agriculture in an equitable and socially and politically acceptable manner.

  4. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption) in the aquifer sediments and will support site selection, risk assessment, policy-making, and public education efforts associated with geologic carbon sequestration.

  5. University of Minnesota aquifer thermal energy storage (ATES) project report on the third long-term cycle

    SciTech Connect (OSTI)

    Hoyer, M.C.; Hallgren, J.P.; Uebel, M.H.; Delin, G.N.; Eisenreich, S.J.; Sterling, R.L.

    1994-12-01

    The University of Minnesota aquifer thermal energy storage (ATES) system has been operated as a field test facility (FTF) since 1982. The objectives were to design, construct, and operate the facility to study the feasibility of high-temperature ATES in a confined aquifer. Four short-term and two long-term cycles were previously conducted, which provided a greatly increased understanding of the efficiency and geochemical effects of high-temperature aquifer thermal energy storage. The third long-term cycle (LT3) was conducted to operate the ATES system in conjunction with a real heating load and to further study the geochemical impact that heated water storage had on the aquifer. For LT3, the source and storage wells were modified so that only the most permeable portion, the Ironton-Galesville part, of the Franconia-Ironton-Galesville aquifer was used for storage. This was expected to improve storage efficiency by reducing the surface area of the heated volume and simplify analysis of water chemistry results by reducing the number of aquifer-related variables which need to be considered. During LT3, a total volume of 63.2 {times} 10{sup 3} m {sup 3} of water was injected at a rate of 54.95 m{sup 3}/hr into the storage well at a mean temperature of 104.7{degrees}C. Tie-in to the reheat system of the nearby Animal Sciences Veterinary Medicine (ASVM) building was completed after injection was completed. Approximately 66 percent (4.13 GWh) of the energy added to the aquifer was recovered. Approximately 15 percent (0.64 GWh) of the usable (10 building. Operations during heat recovery with the ASVM building`s reheat system were trouble-free. Integration into more of the ASVM (or other) building`s mechanical systems would have resulted in significantly increasing the proportion of energy used during heat recovery.

  6. Bicarbonate Impact on U(VI) Bioreduction in a Shallow Alluvial Aquifer

    SciTech Connect (OSTI)

    Long, Philip E.; Williams, Kenneth H.; Davis, James A.; Fox, Patricia M.; Wilkins, Michael J.; Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.; Berman, Elena S.; Gupta, Manish; Chandler, Darrell P.; Murray, Christopher J.; Peacock, Aaron D.; Giloteaux, L.; Handley, Kim M.; Lovley, Derek R.; Banfield, Jillian F.

    2015-02-01

    Field-scale biostimulation and desorption tracer experiments conducted in a uranium (U) contaminated, shallow alluvial aquifer have provided insight into the coupling of microbiology, biogeochemistry, and hydrogeology that control U mobility in the subsurface. Initial experiments successfully tested the concept that Fe-reducing bacteria such as Geobacter sp. could enzymatically reduce soluble U(VI) to insoluble U(IV) during in situ electron donor amendment (Anderson et al. 2003, Williams et al. 2011). In parallel, in situ desorption tracer tests using bicarbonate amendment demonstrated rate-limited U(VI) desorption (Fox et al. 2012). These results and prior laboratory studies underscored the importance of enzymatic U(VI)-reduction and suggested the ability to combine desorption and bioreduction of U(VI). Here we report the results of a new field experiment in which bicarbonate-promoted uranium desorption and acetate amendment were combined and compared to an acetate amendment-only experiment in the same experimental plot. Results confirm that bicarbonate amendment to alluvial aquifer desorbs U(VI) and increases the abundance of Ca-uranyl-carbonato complexes. At the same time, that the rate of acetate-promoted enzymatic U(VI) reduction was greater in the presence of added bicarbonate in spite of the increased dominance of Ca-uranyl-carbonato aqueous complexes. A model-simulated peak rate of U(VI) reduction was ~3.8 times higher during acetate-bicarbonate treatment than under acetate-only conditions. Lack of consistent differences in microbial community structure between acetate-bicarbonate and acetate-only treatments suggest that a significantly higher rate of U(VI) reduction the bicarbonate-impacted sediment may be due to a higher intrinsic rate of microbial reduction induced by elevated concentrations of the bicarbonate oxyanion. The findings indicate that bicarbonate amendment may be useful in improving the engineered bioremediation of uranium in aquifers.

  7. Electrodic voltages accompanying stimulated bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Williams, K.H.; N'Guessan, A.L.; Druhan, J.; Long, P.E.; Hubbard, S.S.; Lovley, D.R.; Banfield, J.F.

    2009-11-15

    The inability to track the products of subsurface microbial activity during stimulated bioremediation has limited its implementation. We used spatiotemporal changes in electrodic potentials (EP) to track the onset and persistence of stimulated sulfate-reducing bacteria in a uranium-contaminated aquifer undergoing acetate amendment. Following acetate injection, anomalous voltages approaching -900 mV were measured between copper electrodes within the aquifer sediments and a single reference electrode at the ground surface. Onset of EP anomalies correlated in time with both the accumulation of dissolved sulfide and the removal of uranium from groundwater. The anomalies persisted for 45 days after halting acetate injection. Current-voltage and current-power relationships between measurement and reference electrodes exhibited a galvanic response, with a maximum power density of 10 mW/m{sup 2} during sulfate reduction. We infer that the EP anomalies resulted from electrochemical differences between geochemically reduced regions and areas having higher oxidation potential. Following the period of sulfate reduction, EP values ranged from -500 to -600 mV and were associated with elevated concentrations of ferrous iron. Within 10 days of the voltage decrease, uranium concentrations rebounded from 0.2 to 0.8 {mu}M, a level still below the background value of 1.5 {mu}M. These findings demonstrate that EP measurements provide an inexpensive and minimally invasive means for monitoring the products of stimulated microbial activity within aquifer sediments and are capable of verifying maintenance of redox conditions favorable for the stability of bioreduced contaminants, such as uranium.

  8. Prickett and Lonnquist aquifer simulation program for the Apple II minicomputer

    SciTech Connect (OSTI)

    Hull, L.C.

    1983-02-01

    The Prickett and Lonnquist two-dimensional groundwater model has been programmed for the Apple II minicomputer. Both leaky and nonleaky confined aquifers can be simulated. The model was adapted from the FORTRAN version of Prickett and Lonnquist. In the configuration presented here, the program requires 64 K bits of memory. Because of the large number of arrays used in the program, and memory limitations of the Apple II, the maximum grid size that can be used is 20 rows by 20 columns. Input to the program is interactive, with prompting by the computer. Output consists of predicted lead values at the row-column intersections (nodes).

  9. Groundwaters of Florence (Italy): Trace element distribution and vulnerability of the aquifers

    SciTech Connect (OSTI)

    Bencini, A.; Ercolanelli, R.; Sbaragli, A.

    1993-11-01

    Geochemical and hydrogeological research has been carried out in Florence, to evaluate conductivity and main chemistry of groundwaters, the pattern of some possible pollutant chemical species (Fe, Mn, Cr, Cu, Pb, Zn, NO{sub 2}, NO{sub 3}), and the vulnerability of the aquifers. The plain is made up of Plio-Quaternary alluvial and lacustrine sediments for a maximum thickness of 600 m. Silts and clays, sometimes with lenses of sandy gravels, are dominant, while considerable deposits of sands, pebbles, and gravels occur along the course of the Arno river and its tributary streams, and represent the most important aquifer of the plain. Most waters show conductivity values around 1000-1200 {mu}S, and almost all of them have an alkaline-earth-bicarbonate chemical character. In western areas higher salt content of the groundwaters is evident. Heavy metal and NO{sub 2}, NO{sub 3} analyses point out that no important pollution phenomena affect the groundwaters; all mean values are below the maximum admissible concentration (MAC) for drinkable waters. Some anomalies of NO{sub 2}, NO{sub 3}, Fe, Mn, and Zn are present. The most plausible causes can be recognized in losses of the sewage system; use of nitrate compounds in agriculture; oxidation of well pipes. All the observations of Cr, Cu, and Pb are below the MAC; the median values of <3, 3.9, and 1.1 {mu}g/l, respectively, could be considered reference concentrations for groundwaters in calcareous lithotypes, under undisturbed natural conditions. Finally, a map of vulnerability shows that the areas near the Arno river are highly vulnerable, for the minimum thickness (or lacking) of sediments covering the aquifer. On the other hand, in the case of pollution, several factors not considered could significantly increase the self-purification capacity of the aquifer, such asdilution of groundwaters, bacteria oxidation of nitrogenous species, and sorption capacity of clay minerals and organic matter. 31 refs., 6 figs., 5 tabs.

  10. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  11. Total Reducing Capacity in Aquifer Minerals and Sediments: Quantifying the Potential to Attenuate Cr(VI) in Groundwater

    SciTech Connect (OSTI)

    Sisman, S. Lara

    2015-07-20

    Hexavalent chromium, Cr(VI), is present in the environment as a byproduct of industrial processes. Due to its mobility and toxicity, it is crucial to attenuate or remove Cr(VI) from the environment. The objective of this investigation was to quantify potential natural attenuation, or reduction capacity, of reactive minerals and aquifer sediments. Samples of reduced-iron containing minerals such as ilmenite, as well as Puye Formation sediments representing a contaminated aquifer in New Mexico, were reacted with chromate. The change in Cr(VI) during the reaction was used to calculate reduction capacity. This study found that minerals that contain reduced iron, such as ilmenite, have high reducing capacities. The data indicated that sample history may impact reduction capacity tests due to surface passivation. Further, this investigation identified areas for future research including: a) refining the relationships between iron content, magnetic susceptibility and reduction capacity, and b) long term kinetic testing using fresh aquifer sediments.

  12. Analysis of temperatures and water levels in wells to estimatealluvial aquifer hydraulic conductivities

    SciTech Connect (OSTI)

    Su, Grace W.; Jasperse, James; Seymour, Donald; Constantz, Jim

    2003-06-19

    Well water temperatures are often collected simultaneously with water levels; however, temperature data are generally considered only as a water quality parameter and are not utilized as an environmental tracer. In this paper, water levels and seasonal temperatures are used to estimate hydraulic conductivities in a stream-aquifer system. To demonstrate this method, temperatures and water levels are analyzed from six observation wells along an example study site, the Russian River in Sonoma County, California. The range in seasonal ground water temperatures in these wells varied from <0.28C in two wells to {approx}88C in the other four wells from June to October 2000. The temperature probes in the six wells are located at depths between 3.5 and 7.1 m relative to the river channel. Hydraulic conductivities are estimated by matching simulated ground water temperatures to the observed ground water temperatures. An anisotropy of 5 (horizontal to vertical hydraulic conductivity) generally gives the best fit to the observed temperatures. Estimated conductivities vary over an order of magnitude in the six locations analyzed. In some locations, a change in the observed temperature profile occurred during the study, most likely due to deposition of fine-grained sediment and organic matter plugging the streambed. A reasonable fit to this change in the temperature profile is obtained by decreasing the hydraulic conductivity in the simulations. This study demonstrates that seasonal ground water temperatures monitored in observation wells provide an effective means of estimating hydraulic conductivities in alluvial aquifers.

  13. A pilot test of partitioning for the simulated highly saline high level waste

    SciTech Connect (OSTI)

    Chen, Jing; Wang, Jianchen; Jing, Shan

    2007-07-01

    It is a problem how to treat the highly saline high level waste (HLW). A partitioning process for HLW was developed at INET. The partitioning process includes the removal of actinides by TRPO extraction, the removal of Sr by crown ether extraction, and the removal of Cs by ion exchange. A 72-hour test was carried out in a pilot facility using the simulated HLW. Nd and Zr were used to simulate Am and Pu, respectively. The decontamination factors are >3000, >500, >1000, {approx}150 and {approx}94 for U, Nd, Zr, Sr and Cs, respectively. The results meet the requirement to change the highly saline HLW into a non-{alpha} and intermediate level waste. (authors)

  14. SALINITY AND SODICITY INTERACTIONS OF WEATHERED MINESOILS IN NORTHWESTERN NEW MEXICO AND NORTH EASTERN ARIZONA

    SciTech Connect (OSTI)

    Brent Musslewhite; Song Jin

    2006-05-01

    Weathering characteristics of minesoils and rooting patterns of key shrub and grass species were evaluated at sites reclaimed for 6 to 14 years from three surface coal mine operations in northwestern New Mexico and northeastern Arizona. Non-weathered minesoils were grouped into 11 classifications based on electrical conductivity (EC) and sodium adsorption ratio (SAR). Comparisons of saturated paste extracts, from non-weathered and weathered minesoils show significant (p < 0.05) reductions in SAR levels and increased EC. Weathering increased the apparent stability of saline and sodic minesoils thereby reducing concerns of aggregate slaking and clay particle dispersion. Root density of four-wing saltbush (Atriplex canascens), alkali sacaton (Sporobolus airoides), and Russian wildrye (Psathyrostachys junceus) were nominally affected by increasing EC and SAR levels in minesoil. Results suggest that saline and sodic minesoils can be successfully reclaimed when covered with topsoil and seeded with salt tolerant plant species.

  15. Process for producing modified microorganisms for oil treatment at high temperatures, pressures and salinity

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1996-02-20

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. The processes are comprised of steps which successively limit the carbon sources and increase the temperature, pressure and salinity of the media. This is done until microbial strains are obtained that are capable of growing in essentially crude oil as a carbon source and at a temperature range from about 70 C to 90 C, at a pressure range from about 2,000 to 2,500 psi and at a salinity range from about 1.3 to 35%. 68 figs.

  16. Process for producing modified microorganisms for oil treatment at high temperatures, pressures and salinity

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow

    1996-02-20

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. The processes are comprised of steps which successively limit the carbon sources and increase the temperature, pressure and salinity of the media. This is done until microbial strains are obtained that are capable of growing in essentially crude oil as a carbon source and at a temperature range from about 70.degree. C. to 90.degree. C., at a pressure range from about 2,000 to 2,500 psi and at a salinity range from about 1.3 to 35%.

  17. Oil Recovery Increases by Low-Salinity Flooding: Minnelusa and Green River Formations

    SciTech Connect (OSTI)

    Eric P. Robertson

    2010-09-01

    Waterflooding is by far the most widely used method in the world to increase oil recovery. Historically, little consideration has been given in reservoir engineering practice to the effect of injection brine composition on waterflood displacement efficiency or to the possibility of increased oil recovery through manipulation of the composition of the injected water. However, recent work has shown that oil recovery can be significantly increased by modifying the injection brine chemistry or by injecting diluted or low salinity brine. This paper reports on laboratory work done to increase the understanding of improved oil recovery by waterflooding with low salinity injection water. Porous media used in the studies included outcrop Berea sandstone (Ohio, U.S.A.) and reservoir cores from the Green River formation of the Uinta basin (Utah, U.S.A.). Crude oils used in the experimental protocols were taken from the Minnelusa formation of the Powder River basin (Wyoming, U.S.A.) and from the Green River formation, Monument Butte field in the Uinta basin. Laboratory corefloods using Berea sandstone, Minnelusa crude oil, and simulated Minnelusa formation water found a significant relationship between the temperature at which the oil- and water-saturated cores were aged and the oil recovery resulting from low salinity waterflooding. Lower aging temperatures resulted in very little to no additional oil recovery, while cores aged at higher temperatures resulted in significantly higher recoveries from dilute-water floods. Waterflood studies using reservoir cores and fluids from the Green River formation of the Monument Butte field also showed significantly higher oil recoveries from low salinity waterfloods with cores flooded with fresher water recovering 12.4% more oil on average than those flooded with undiluted formation brine.

  18. A combined saline formation and gas reservoir CO2 injection pilotin Northern California

    SciTech Connect (OSTI)

    Trautz, Robert; Myer, Larry; Benson, Sally; Oldenburg, Curt; Daley, Thomas; Seeman, Ed

    2006-04-28

    A geologic sequestration pilot in the Thornton gas field in Northern California, USA involves injection of up to 4000 tons of CO{sub 2} into a stacked gas and saline formation reservoir. Lawrence Berkeley National Laboratory (LBNL) is leading the pilot test in collaboration with Rosetta Resources, Inc. and Calpine Corporation under the auspices of the U.S. Department of Energy and California Energy Commission's WESTCARB, Regional Carbon Sequestration Partnership. The goals of the pilot include: (1) Demonstrate the feasibility of CO{sub 2} storage in saline formations representative of major geologic sinks in California; (2) Test the feasibility of Enhanced Gas Recovery associated with the early stages of a CO{sub 2} storage project in a depleting gas field; (3) Obtain site-specific information to improve capacity estimation, risk assessment, and performance prediction; (4) Demonstrate and test methods for monitoring CO{sub 2} storage in saline formations and storage/enhanced recovery projects in gas fields; and (5) Gain experience with regulatory permitting and public outreach associated with CO{sub 2} storage in California. Test design is currently underway and field work begins in August 2006.

  19. Building Conceptual Models of Field-Scale Uranium Reactive Transport in a Dynamic Vadose Zone-Aquifer-River System

    SciTech Connect (OSTI)

    Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.

    2008-12-04

    Subsurface simulation is being used to build, test, and couple conceptual process models to better understand controls on a 0.4 km by 1.0 km uranium plume that has persisted above the drinking water standard in the groundwater of the Hanford 300 Area over the last 15 years. At this site, uranium-contaminated sediments in the vadose zone and aquifer are subject to significant variations in water levels and velocities driven by the diurnal, weekly, seasonal, and episodic Columbia River stage dynamics. Groundwater flow reversals typically occur twice a day with significant exchange of river water and groundwater in the near-river aquifer. Mixing of the dilute solution chemistry of the river with the groundwater complicates the uranium sorption behavior as the mobility of U(VI) has been shown experimentally to be a function of pH, carbonate, calcium, and uranium. Furthermore, uranium mass transfer between solid and aqueous phases has been observed to be rate-limited in the context of the high groundwater velocities resulting from the river stage fluctuations and the highly transmissive sediments (hydraulic conductivities ~1500 m/d). One- and two-dimensional vertical cross-sectional simulations of variably-saturated flow and reactive transport, based on laboratory-derived models of distributed rate mass transfer and equilibrium multicomponent surface complexation, are used to assess uranium transport at the dynamic vadose zone aquifer interface as well as changes to uranium mobility due to incursions of river water into the aquifer.

  20. Possible Impacts of Global Warming on Hydrology of the Ogallala Aquifer Region

    SciTech Connect (OSTI)

    Rosenberg, Norman J. ); Epstein, Daniel J. ); Wang, Dahong; Vail, Lance W. ); Srinivasan, Ragahvan; Arnold, J G.

    1998-12-01

    The Ogallala or High Plains aquifer provides water for about 20% of the irrigated land in the United States. About 20 km{sup 3} (16.6 million acre-feet) of water are withdrawn annually from this aquifer. In general, recharge has not compensated for withdrawals since major irrigation development began in this region in the 1940s. The mining of the Ogallala has been pictured as an analogue to climate change in that many GCMs predict a warmer and drier future for this region. We anticipate the possible impacts of climate change on the sustainability of the aquifer as a source of water for irrigation and other purposes in the region. We have applied HUMUS, the Hydrologic Unit Model of the U.S. to the Missouri and Arkansas-White-Red water resource regions that overlie the Ogallala. We have imposed three general circulation model (GISS, UKTR and BMRC) projections of future climate change on this region and simulated the changes that may be induced in water yields (runoff plus lateral flow) and ground water recharge. Each GCM was applied to HUMUS at three levels of global mean temperature (GMT) to represent increasing severity of climate change (a surrogate for time). HUMUS was also run at three levels of atmospheric CO2 concentration (hereafter denoted by[CO2]) in order to estimate the impacts of direct CO2 effects on photosynthesis and evapotranspiration. Since the UKTR and GISS GCMs project increased precipitation in the Missouri basin, water yields increase there. The BMRC GCM predicts sharply decreased precipitation and, hence, reduced water yields. Precipitation reductions are even greater in the Arkansas basin under BMRC as are the consequent water yield losses. GISS and UKTR climates lead to only moderate yield losses in the Arkansas. CO2-fertilization reverses these losses and yields increase slightly. CO2 fertilization increases recharge in the base (no climate change) case in both basins. Recharge is reduced under all three GCMs and severities of climate change.

  1. Aquifer Characteristics Data Report for the Weldon Spring Site chemical plant/raffinate pits and vicinity properties for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivity values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.

  2. Determining flow, recharge, and vadose zonedrainage in anunconfined aquifer from groundwater strontium isotope measurements, PascoBasin, WA

    SciTech Connect (OSTI)

    mjsingleton@lbl.gov

    2004-06-29

    Strontium isotope compositions (87Sr/86Sr) measured in groundwater samples from 273 wells in the Pasco Basin unconfined aquifer below the Hanford Site show large and systematic variations that provide constraints on groundwater recharge, weathering rates of the aquifer host rocks, communication between unconfined and deeper confined aquifers, and vadose zone-groundwater interaction. The impact of millions of cubic meters of wastewater discharged to the vadose zone (103-105 times higher than ambient drainage) shows up strikingly on maps of groundwater 87Sr/86Sr. Extensive access through the many groundwater monitoring wells at the site allows for an unprecedented opportunity to evaluate the strontium geochemistry of a major aquifer, hosted primarily in unconsolidated sediments, and relate it to both long term properties and recent disturbances. Groundwater 87Sr/86Sr increases systematically from 0.707 to 0.712 from west to east across the Hanford Site, in the general direction of groundwater flow, as a result of addition of Sr from the weathering of aquifer sediments and from diffuse drainage through the vadose zone. The lower 87Sr/86Sr groundwater reflects recharge waters that have acquired Sr from Columbia River Basalts. Based on a steady-state model of Sr reactive transport and drainage, there is an average natural drainage flux of 0-1.4 mm/yr near the western margin of the Hanford Site, and ambient drainage may be up to 30 mm/yr in the center of the site assuming an average bulk rock weathering rate of 10-7.5 g/g/yr.

  3. Storing carbon dioxide in saline formations : analyzing extracted water treatment and use for power plant cooling.

    SciTech Connect (OSTI)

    Dwyer, Brian P.; Heath, Jason E.; Borns, David James; Dewers, Thomas A.; Kobos, Peter Holmes; Roach, Jesse D.; McNemar, Andrea; Krumhansl, James Lee; Klise, Geoffrey T.

    2010-10-01

    In an effort to address the potential to scale up of carbon dioxide (CO{sub 2}) capture and sequestration in the United States saline formations, an assessment model is being developed using a national database and modeling tool. This tool builds upon the existing NatCarb database as well as supplemental geological information to address scale up potential for carbon dioxide storage within these formations. The focus of the assessment model is to specifically address the question, 'Where are opportunities to couple CO{sub 2} storage and extracted water use for existing and expanding power plants, and what are the economic impacts of these systems relative to traditional power systems?' Initial findings indicate that approximately less than 20% of all the existing complete saline formation well data points meet the working criteria for combined CO{sub 2} storage and extracted water treatment systems. The initial results of the analysis indicate that less than 20% of all the existing complete saline formation well data may meet the working depth, salinity and formation intersecting criteria. These results were taken from examining updated NatCarb data. This finding, while just an initial result, suggests that the combined use of saline formations for CO{sub 2} storage and extracted water use may be limited by the selection criteria chosen. A second preliminary finding of the analysis suggests that some of the necessary data required for this analysis is not present in all of the NatCarb records. This type of analysis represents the beginning of the larger, in depth study for all existing coal and natural gas power plants and saline formations in the U.S. for the purpose of potential CO{sub 2} storage and water reuse for supplemental cooling. Additionally, this allows for potential policy insight when understanding the difficult nature of combined potential institutional (regulatory) and physical (engineered geological sequestration and extracted water system) constraints across the United States. Finally, a representative scenario for a 1,800 MW subcritical coal fired power plant (amongst other types including supercritical coal, integrated gasification combined cycle, natural gas turbine and natural gas combined cycle) can look to existing and new carbon capture, transportation, compression and sequestration technologies along with a suite of extracting and treating technologies for water to assess the system's overall physical and economic viability. Thus, this particular plant, with 90% capture, will reduce the net emissions of CO{sub 2} (original less the amount of energy and hence CO{sub 2} emissions required to power the carbon capture water treatment systems) less than 90%, and its water demands will increase by approximately 50%. These systems may increase the plant's LCOE by approximately 50% or more. This representative example suggests that scaling up these CO{sub 2} capture and sequestration technologies to many plants throughout the country could increase the water demands substantially at the regional, and possibly national level. These scenarios for all power plants and saline formations throughout U.S. can incorporate new information as it becomes available for potential new plant build out planning.

  4. Aquifer thermal energy storage reference manual: seasonal thermal energy storage program

    SciTech Connect (OSTI)

    Prater, L.S.

    1980-01-01

    This is the reference manual of the Seasonal Thermal Energy Storage (STES) Program, and is the primary document for the transfer of technical information of the STES Program. It has been issued in preliminary form and will be updated periodically to include more technical data and results of research. As the program progresses and new technical data become available, sections of the manual will be revised to incorporate these data. This primary document contains summaries of: the TRW, incorporated demonstration project at Behtel, Alaska, Dames and Moore demonstration project at Stony Brook, New York, and the University of Minnesota demonstration project at Minneapolis-St. Paul, Minnesota; the technical support programs including legal/institutional assessment; economic assessment; environmental assessment; field test facilities; a compendia of existing information; numerical simulation; and non-aquifer STES concepts. (LCL)

  5. Abiotic/Biotic Degradation and Mineralization of N-Nitrosodimethylamine in Aquifer Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; McKinley, James P.; Breshears, Andrew T.; Crocker, Fiona H.

    2008-10-14

    The N-nitrosodimethylamine (NDMA) degradation rate and mineralization rate were measured in two aquifer sediments that received treatments to create oxic, reducing, and sequential reducing/oxic environments. Chemically reduced sediments rapidly abiotically degraded NDMA to nontoxic dimethylamine (DMA) to parts per trillion levels, then degraded to further products. NDMA was partially mineralized in reduced sediments (6 to 28 percent) at a slow rate (half-life 3,460 h) by an unknown abiotic/biotic pathway. In contrast, NDMA was mineralized more rapidly (half-life 342 h) and to a greater extent (30 to 81 percent) in oxic sediments with propane addition, likely by a propane monooxygenase pathway. NDMA mineralization in sequential reduced sediment followed by oxic sediment treatment did result in slightly more rapid mineralization and a greater mineralization extent relative to reduced systems. These increases were minor, so aerobic NDMA mineralization with oxygen and propane addition was the most viable in situ NDMA mineralization strategy.

  6. Contaminant transport in unconfined aquifer, input to low-level tank waste interim performance assessment

    SciTech Connect (OSTI)

    Lu, A.H., Westinghouse Hanford

    1996-08-14

    This report describes briefly the Hanford sitewide groundwater model and its application to the Low-Level Tank Waste Disposal (LLTWD) interim Performance Assessment (PA). The Well Intercept Factor (WIF) or dilution factor from a given areal flux entering the aquifer released from the LLTWD site are calculated for base case and various sensitivity cases. In conjunction with the calculation for released fluxes through vadose zone transport,the dose at the compliance point can be obtained by a simple multiplication. The relative dose contribution from the upstream sources was also calculated and presented in the appendix for an equal areal flux at the LLTWD site. The results provide input for management decisions on remediation action needed for reduction of the released fluxes from the upstream facilities to the allowed level to meet the required dose criteria.

  7. Geophysical Monitoring of Ground Surface Deformation Associated with a Confined Aquifer Storage and Recovery Operation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bonneville, Alain; Heggy, Essam; Strickland, Christopher E.; Normand, Jonathan; Dermond, Jeffrey A.; Fang, Yilin; Sullivan, E. C.

    2015-08-11

    A main issue in the storage of large volumes of fluids, mainly water and CO2, in the deep subsurface is to determine their field-scale-induced displacements and consequences on the mechanical behavior of the storage reservoir and surroundings. A quantifiable estimation of displacement can be made by combining the robust, cost-effective, and repeatable geophysical techniques of micro-gravimetry, differential global positioning system (DGPS), and differential synthetic aperture radar interferometry (DInSAR). These techniques were field tested and evaluated in an active large-volume aquifer storage and recovery (ASR) project in Pendleton, Oregon, USA, where three ASR wells are injecting up to 1.9 million m3/yr-1more » into basalt aquifers to a depth of about 150 m. Injection and recovery of water at the wells was accompanied by significant gravity anomalies and vertical deformation of the ground surface localized to the immediate surroundings of the injection wells as evidenced by DGPS and gravity measurements collected in 2011. At a larger scale, and between 2011 and 2013, DInSAR monitoring of the Pendleton area suggests the occurrence of sub-centimetric deformation in the western part of the city and close to the injection locations associated with the ASR cycle. A numerical simulation of the effect of the water injection gives results in good agreement with the observations and confirms the validity of the approach, which could be deployed in similar geological contexts to look at the mechanical effects of water and gas injections. The gravity signal reflects deep phenomena and gives additional insight into the repartition of fluids in the subsurface.« less

  8. Geophysical Monitoring of Ground Surface Deformation Associated with a Confined Aquifer Storage and Recovery Operation

    SciTech Connect (OSTI)

    Bonneville, Alain; Heggy, Essam; Strickland, Christopher E.; Normand, Jonathan; Dermond, Jeffrey A.; Fang, Yilin; Sullivan, E. C.

    2015-08-11

    A main issue in the storage of large volumes of fluids, mainly water and CO2, in the deep subsurface is to determine their field-scale-induced displacements and consequences on the mechanical behavior of the storage reservoir and surroundings. A quantifiable estimation of displacement can be made by combining the robust, cost-effective, and repeatable geophysical techniques of micro-gravimetry, differential global positioning system (DGPS), and differential synthetic aperture radar interferometry (DInSAR). These techniques were field tested and evaluated in an active large-volume aquifer storage and recovery (ASR) project in Pendleton, Oregon, USA, where three ASR wells are injecting up to 1.9 million m3/yr-1 into basalt aquifers to a depth of about 150 m. Injection and recovery of water at the wells was accompanied by significant gravity anomalies and vertical deformation of the ground surface localized to the immediate surroundings of the injection wells as evidenced by DGPS and gravity measurements collected in 2011. At a larger scale, and between 2011 and 2013, DInSAR monitoring of the Pendleton area suggests the occurrence of sub-centimetric deformation in the western part of the city and close to the injection locations associated with the ASR cycle. A numerical simulation of the effect of the water injection gives results in good agreement with the observations and confirms the validity of the approach, which could be deployed in similar geological contexts to look at the mechanical effects of water and gas injections. The gravity signal reflects deep phenomena and gives additional insight into the repartition of fluids in the subsurface.

  9. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    Office of Scientific and Technical Information (OSTI)

    3 (2014) 4684 - 4707 Energy Procedia GHGT-12 Geochemical impacts of carbon dioxide, brine, trace metal and organic leakage into an unconfined, oxidizing limestone aquifer Diana H. Bacon3'* *, Zhenxue Daib, Liange Zhengc "Pacific Northwest National Laboratory, Richland, Washington, USA bLos Alamos National Laboratory, Los Alamos, New Mexico, USA cLawrence Berkeley National Laboratory, Berkeley, California, USA Abstract An important risk at CO2 storage sites is the potential for groundwater

  10. Water geochemistry and hydrogeology of the shallow aquifer at Roosevelt Hot Springs, southern Utah: A hot dry rock prospect

    SciTech Connect (OSTI)

    Vuataz, F.D.; Goff, F.

    1987-12-01

    On the western edge of the geothermal field, three deep holes have been drilled that are very hot but mostly dry. Two of them (Phillips 9-1 and Acord 1-26 wells) have been studied by Los Alamos National Laboratory for the Hot Dry Rock (HDR) resources evaluation program. A review of data and recommendations have been formulated to evaluate the HDR geothermal potential at Roosevelt. The present report is directed toward the study of the shallow aquifer of the Milford Valley to determine if the local groundwater would be suitable for use as make-up water in an HDR system. This investigation is the result of a cooperative agreement between Los Alamos and Phillips Petroleum Co., formerly the main operator of the Roosevelt Hot Springs Unit. The presence of these hot dry wells and the similar setting of the Roosevelt area to the prototype HDR site at Fenton Hill, New Mexico, make Roosevelt a very good candidate site for creation of another HDR geothermal system. This investigation has two main objectives: to assess the water geochemistry of the valley aquifer, to determine possible problems in future make-up water use, such as scaling or corrosion in the wells and surface piping, and to assess the hydrogeology of the shallow groundwaters above the HDR zone, to characterize the physical properties of the aquifer. These two objectives are linked by the fact that the valley aquifer is naturally contaminated by geothermal fluids leaking out of the hydrothermal reservoir. In an arid region where good-quality fresh water is needed for public water supply and irrigation, nonpotable waters would be ideal for an industrial use such as injection into an HDR energy extraction system. 50 refs., 10 figs., 10 tabs.

  11. In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental Study

    SciTech Connect (OSTI)

    Xie, Xianjun; Wang, Yanxin; Pi, Kunfu; Liu, Chongxuan; Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu

    2015-09-15

    In situ arsenic removal from groundwater by an iron coating method has great potential to be a cost effective and simple groundwater remediation technique, especially in rural and remote areas where groundwater is used as the main source of drinking water. The in situ arsenic removal technique was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions., Its effectiveness was then evaluated in an actual high-arsenic groundwater environment. The mechanism of arsenic removal by the iron coating was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, an electron microprobe, and Fourier transformation infrared spectroscopy. A 4-step alternative cycle aquifer iron coating method was developed. A continuous injection of 5 mmol/L FeSO4 and 2.5 mmol/L NaClO for 96 hours can create a uniform coating of crystalline goethite on the surface of quartz sand in the columns without causing clogging. At a flow rate of 0.45 cm/min of the injection reagents (vi), the time for arsenic (as Na2HAsO4) to pass through the iron-coated quartz sand column was approximately 35 hours, which was much longer than that for tracer fluorescein sodium (approximately 2 hours). The retardation factor of arsenic was 23, and its adsorption capacity was 0.11 mol As per mol Fe, leading to an excellent arsenic removal. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As (V) and Fe (II) reagents. When the arsenic content in the groundwater was 233 ?g/L, the aqueous phase arsenic was completely removed with an arsenic adsorption of 0.05 mol As per mol Fe. Arsenic fixation resulted from a process of adsorption/co-precipitation, in which arsenic and iron likely formed the arsenic-bearing iron mineral phases with poor crystallinity by way of bidentate binuclear complexes. Thus, the high arsenic removal efficiency of the technique likely resulted from the expanded specific iron oxide/hydroxide surface area with poor crystallinity and from coprecipitation.

  12. Water/rock interaction efficiency and seawater dolomitization in the Eocene Avon Park Formation, Floridan Aquifer

    SciTech Connect (OSTI)

    Cander, H.S. )

    1990-05-01

    The Floridan aquifer has often been proposed as a system of extensive meteoric carbonate diagenesis and mixing zone dolomitization. However, the dominance of marine isotope (C, O, {sup 87}Sr/{sup 86}Sr) and trace element (Sr, Fe, Mn) compositions in dolomites and limestones in the Eocene Avon Park Formation, Floridan aquifer, suggests that the very active low temperature meteoric groundwater system has, over the past 40 m.y., been an inefficient mechanism of diagenesis. {delta}{sup 18}O values of all but two replacement dolomites sampled range from +2.0 to +5.1 (PDB) with high Sr concentrations (90-325 ppm), indicating dolomitization by near-normal marine water involving no significant interaction with meteoric groundwater. The two {delta}{sup 18}O-depleted (0.0 {plus minus} 1) dolomites have low Sr concentrations ({approximately}100 ppm) suggesting limited recrystallization in meteoric water. Several dolomite samples have radiogenic {sup 87}Sr/{sup 86}Sr compositions (0.70810-0.70883 {plus minus} 2), but have heavy oxygen isotope compositions (> +2.0) and high Sr concentrations (<200 ppm) suggesting precipitation from cold Miocene age or younger seawater that circulated through the Florida platform. Most limestone stable isotope compositions cluster around marine values (({delta}{sup 18}O = {minus}1 to +1, PDB) {delta}{sup 13}C = +0.5 to +2.5) and have Eocene seawater {sup 87}Sr/{sup 86}Sr compositions (0.70775 {plus minus} 2 to 0.70779 {plus minus} 2) with 400 to 500 ppm Sr. Isotopic compositions of limestones from the east coast of Florida are all within these ranges. Only some limestones from central Florida and the west coast contain depleted stable isotopic compositions and low Sr concentrations. The sample with the most depleted stable isotope values has a radiogenic {sup 87}Sr/{sup 86}Sr composition (0.70870 {plus minus} 2), suggesting that diagenetic meteoric water migrated through post-Miocene strata.

  13. Death Valley Lower Carbonate Aquifer Monitoring Program Wells Down gradient of the Proposed Yucca Mountain Nuclear Waste Repository

    SciTech Connect (OSTI)

    Inyo County

    2006-07-26

    Inyo County has participated in oversight activities associated with the Yucca Mountain Nuclear Waste Repository since 1987. The overall goal of these studies are the evaluation of far-field issues related to potential transport, by ground water, or radionuclides into Inyo County, including Death Valley, and the evaluation of a connection between the Lower Carbonate Aquifer (LCA) and the biosphere. Our oversight and completed Cooperative Agreement research, and a number of other investigators research indicate that there is groundwater flow between the alluvial and carbonate aquifers both at Yucca Mountain and in Inyo County. In addition to the potential of radionuclide transport through the LCA, Czarnecki (1997), with the US Geological Survey, research indicate potential radionuclide transport through the shallower Tertiary-age aquifer materials with ultimate discharge into the Franklin Lake Playa in Inyo County. The specific purpose of this Cooperative Agreement drilling program was to acquire geological, subsurface geology, and hydrologic data to: (1) establish the existence of inter-basin flow between the Amargosa Basin and Death Valley Basin; (2) characterize groundwater flow paths in the LCA through Southern Funeral Mountain Range, and (3) Evaluation the hydraulic connection between the Yucca Mountain repository and the major springs in Death Valley through the LCA.

  14. A controlled in situ field evaluation of a new dynamic vacuum slug test method in unconfined aquifers

    SciTech Connect (OSTI)

    Lauctes, B.A.; Schleyer, C.A.

    1995-09-01

    Most ground water site characterizations require initial estimates of the ground water flow velocity and potential downgradient extent of ground water contamination. The fundamental aquifer property, hydraulic conductivity, must be determined to make these essential estimates. Highly contaminated ground water often precludes conducting multi-well aquifer tests to evaluate hydraulic conductivity due to potential human health risks and ground water storage/treatment/disposal costs and logistics. Consequently, single-well slug tests are often sued, but the widely used pressure slug test method is not suitable for water table monitoring wells. As a result, a new slug test method was developed by GCL for unconfined aquifers. The new method was benchmarked against the widely used solid slug test method in a series of rising-head and falling-head slug tests. A statistical evaluation indicated no statistical difference (alpha = 0.05) between hydraulic conductivity values calculated from each method. The new dynamic vacuum method, designed specifically for use in water table monitoring wells, uses a continuous vacuum to draw air through the well screen exposed above the water table. The vacuum induces upwelling as air pressure inside the well casing drops below atmospheric pressure. Once upwelling equilibrates with the applied vacuum, the vacuum is released allowing the water to recover and the air pressure inside the casing to return to atmospheric pressure.

  15. Single-cell genomics reveal metabolic strategies for microbial growth and survival in an oligotrophic aquifer

    SciTech Connect (OSTI)

    Wilkins, Michael J.; Kennedy, David W.; Castelle, Cindy; Field, Erin; Stepanauskas, Ramunas; Fredrickson, Jim K.; Konopka, Allan

    2014-02-01

    Bacteria from the genus Pedobacter are a major component of microbial assemblages at Hanford Site and have been shown to significantly change in abundance in response to the subsurface intrusion of Columbia River water. Here we employed single cell genomics techniques to shed light on the physiological niche of these microorganisms. Analysis of four Pedobacter single amplified genomes (SAGs) from Hanford Site sediments revealed a chemoheterotrophic lifestyle, with the potential to exist under both aerobic and microaerophilic conditions via expression of both aa3?type and cbb3-type cytochrome c oxidases. These SAGs encoded a wide-range of both intra-and extra-cellular carbohydrate-active enzymes, potentially enabling the degradation of recalcitrant substrates such as xylan and chitin, and the utilization of more labile sugars such as mannose and fucose. Coupled to these enzymes, a diversity of transporters and sugar-binding molecules were involved in the uptake of carbon from the extracellular local environment. The SAGs were enriched in TonB-dependent receptors (TBDRs), which play a key role in uptake of substrates resulting from degradation of recalcitrant carbon. CRISPR-Cas mechanisms for resisting viral infections were identified in all SAGs. These data demonstrate the potential mechanisms utilized for persistence by heterotrophic microorganisms in a carbon-limited aquifer, and hint at potential linkages between observed Pedobacter abundance shifts within the 300 Area subsurface and biogeochemical shifts associated with Columbia River water intrusion.

  16. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect (OSTI)

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  17. Fractured rock aquifer tests in the Western Siberian Basin, Ozyorsk, Russia

    SciTech Connect (OSTI)

    Nichols, R.L.; Looney, B.B.; Eddy-Dilek, C.A.

    1997-10-01

    A series of multi-zone pumping tests was conducted in a contaminated fractured rock aquifer in the Western Siberian Basin, Ozyorsk, Russia. The tests were conducted adjacent to the Mishelyak River floodplain in fractured Paleozoic porphyrites, tufts, tuff breccia, and lava typical of the Ural mountain complex. Geophysical logs, borehole photography, core samples, and results from previous borehole contamination studies were used to identify the zones to be tested. A network of three uncased wells was tested using a system of inflatable packers, pressure transducers and data loggers. Seven zones were isolated and monitored in two of the uncased wells. A straddle packer assembly was used to isolate individual zones within the pumping well. Eight constant rate pumping tests were conducted. Results of the testing indicate that shallow groundwater migrates primarily in two intervals that are separated by an interval with low lateral conductivity. The water bearing intervals have moderate to high specific capacities (1.3 and 30 L/min/m). Several processes are responsible for fracturing present in the lower interval. The network of compound fractures produced a complex array of fracture intersections yielding a fractured media with hydraulic behavior similar to porous media. Models used for the analysis of pumping tests in porous media provide a good estimation of the hydraulic response of the lower interval to pumping. Future work will include more complex analysis of the data to determine hydraulic conductivity ellipses.

  18. Guidelines for conceptual design and evaluation of aquifer thermal energy storage

    SciTech Connect (OSTI)

    Meyer, C.F.; Hauz, W.

    1980-10-01

    Guidelines are presented for use as a tool by those considering application of a new technology, aquifer thermal energy storage (ATES). The guidelines will assist utilities, municipalities, industries, and other entities in the conceptual design and evaluation of systems employing ATES. The potential benefits of ATES are described, an overview is presented of the technology and its applications, and rules of thumb are provided for quickly judging whether a proposed project has sufficient promise to warrant detailed conceptual design and evaluation. The characteristics of sources and end uses of heat and chill which are seasonally mismatched and may benefit from ATES (industrial waste heat, cogeneration, solar heat, and winter chill, for space heating and air conditioning) are discussed. Storage and transport subsystems and their expected performance and cost are described. A 10-step methodology is presented for conceptual design of an ATES system and evaluation of its technical and economic feasibility in terms of energy conservation, cost savings, fuel substitution, improved dependability of supply, and abatement of pollution, with examples, and the methodology is applied to a hypothetical proposed ATES system, to illustrate its use.

  19. Evaluating Impacts of CO2 Intrusion into an Unconsolidated Aquifer: II. Modeling Results

    SciTech Connect (OSTI)

    Zheng, Liange; Qafoku, Nikolla; Lawter, Amanda R.; Wang, Guohui; Shao, Hongbo; Brown, Christopher F.

    2015-08-04

    Large scale deployment of CO2 geological sequestration requires the assessment of the risks. One of the potential risks is the impact of CO2 leakage on shallow groundwater overlying the sequestration site.The understanding of the key chemical processes and parameters are critical for building numerical models for risk assessment. Model interpretation of laboratory and field tests is an effective way to enhance such understanding. Column experiments in which CO2 charged synthetic groundwater flowed through a column packed with material from High Plains aquifer was conducted and concentration of several constituents in the effluent water was analyzed. In this paper, reactive transport model was developed to interpret the observed concentration changes, attempting to shed light on the chemical reactions and key parameters that control the concentration changes of these constituents. The reactive transport model catches the concentration changes of pH, Ca, Mg, Ba, Sr, Cs, As and Pb fairly well. Calcite dissolution and Ca-driven cation exchange reactions are the major drivers for the concentration changes of Ca, Ba, Sr, and Cs. The pH-driven adsorption/desorption reactions lead to a concentration increase of As and Pb. The volume fraction and reactive surface area of calcite, CEC and sorption capacity are key parameters in determining the magnitude of concentration increase. Model results also show that the dissolution of calcite with Ba impurity could be an alternative explanation of the increase in Ba concentration.

  20. Petrology of lower and middle Eocene carbonate rocks, Floridan aquifer, central Florida

    SciTech Connect (OSTI)

    Thayer, P.A.; Miller, J.A.

    1984-09-01

    Study of cores from a US Geological Survey test well near Polk City, Florida, indicates that the Avon Park-Lake City (Claibornian) and Oldsmar (Sabinian) Limestones, which comprise most of the Floridan aquifer in central Florida, can be divided into six microfacies: foraminiferal mudstone, foraminiferal wackestone-packstone, foraminiferal grainstone, nodular anhydrite, laminated dolomicrite, and replacement dolomite. Dolomite containing variable amounts of nodular anhydrite forms more than 90% of the Avon Park-Lake city interval, whereas thte Oldsmar is chiefly limestone. Several episodes of dolomite formation are recognized. Laminated dolomicrite formed syngenetically in a supratidal-sabhka environment. Crystalline dolomite with nodular anhydrite formed early by replacement of limestone through reflux of dense, magnesium-rich brines. Replacement dolomite not associated with evaporites and containing limpid crystals probably formed later by a mixed-water process in the subsurface environment. Late diagenetic processes affecting crystalline dolomites include hydration of anhydrite to gypsum, partial dissolution of gypsum, minor alteration of gypsum to calcite, and dissolution of calcian dolomite cores in stoichiometric crystals. Crystalline dolomite and grainstone are the only rock types that have high enough porosities and permeabilities to provide significant yields of water. Medium and finely crystalline dolomites show best values of porosity and permeability because they have high percentages of intercrystal and moldic pores that are well connected. Filling of pores by anhydrite or gypsum can significantly reduce porosity and permeability.

  1. An example of mixing-zone dolomite, Middle Eocene Avon Park Formation, Floridan aquifer system

    SciTech Connect (OSTI)

    Cander, H.S. )

    1994-07-01

    A late-formed dolomite cement in a core of the Middle Eocene Avon Park Formation, peninsular Florida, provides an example of dolomite cement from a mixing zone and illustrates how dolomite textural alteration and stabilization can occur at earth-surface conditions. The Avon Park Formation is a pervasively dolomitized peritidal platform carbonate 400 m thick in the Florida aquifer system. Typical Avon Park dolomite is inclusion-rich, fine-grained (< 40 mm), noncathodoluminescent, highly porous (average, 20%), and formed during the Eocene by normal to hypersaline seawater ([delta][sup 18]O = + 3.7[per thousand] PDB; [delta][sup 13]C = + 2.0[per thousand]; [sup 87]Sr/[sup 86]Sr = 0.70778; Sr = 167 ppm). In a 20 m interval in a core from southwest Florida, inclusion-free, cathodoluminescent dolomite overgrows the early-formed noncathodoluminescent marine dolomite. The cathodoluminescent dolomite cement profoundly alters the texture of Avon Park dolomite from typical Cenozoic-like porous, poorly crystalline dolomite to hard, dense, low-porosity, highly crystalline Paleozoic-like dolomite. The dolomite cement is not a replacement of limestone but an overgrowth of early-formed marine dolomite and pore-occluding cement. This study demonstrates that: (1) dolomite precipitated from a 75% seawater mixing-zone fluid that was both calcite saturated and sulfate-rich, and (2) dramatic textural maturation and stabilization in dolomite can occur in the near surface environment, without elevated temperature and burial conditions.

  2. Evaluation of materials for systems using cooled, treated geothermal or high-saline brines

    SciTech Connect (OSTI)

    Suciu, D.F.; Wikoff, P.M.

    1982-09-01

    Lack of adequate quantities of clean surface water for use in wet (evaporative) cooling systems indicates the use of high-salinity waste waters, or cooled geothermal brines, for makeup purposes. High-chloride, aerated water represents an extremely corrosive environment. In order to determine metals suitable for use in such an environment, metal coupons were exposed to aerated, treated geothermal brine salted to a chloride concentration of 10,000 and 50,000 ppM (mg/L) for periods of up to 30 days. The exposed coupons were evaluated to determine the general, pitting, and crevice corrosion characteristics of the metals. The metals exhibiting corrosion resistance at 50,000 ppM chloride were then evaluated at 100,000 and 200,000 ppM chloride. Since these were screening tests to select materials for components to be used in a cooling system, with primary emphasis on condenser tubing, several materials were exposed for 4 to 10 months in pilot cooling tower test units with heat transfer for further corrosion evaluation. The results of the screening tests indicate that ferritic stainless steels (29-4-2 and SEA-CURE) exhibit excellent corrosion resistance at all levels of chloride concentration. Copper-nickel alloys (70/30 and Monel 400) exhibited excellent corrosion resistance in the high-saline water. The 70/30 copper-nickel alloy, which showed excellent resistance to general corrosion, exhibited mild pitting in the 30-day tests. This pitting was not apparent, however, after 6 months of exposure in the pilot cooling tower tests. The nickel-base alloys exhibited excellent corrosion resistance, but their high cost prevents their use unless no other material is found feasible. Other materials tested, although unsuitable for condenser tubing material, would be suitable as tube sheet material.

  3. EA-1482: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Pilot Experiment for Geological Sequestration of Carbon Dioxide in Saline Aquifer Brine Formations, Frio Formation, Liberty County, Texas

  4. Environmental sensor networks and continuous data quality assurance to manage salinity within a highly regulated river basin

    SciTech Connect (OSTI)

    Quinn, N.W.T.; Ortega, R.; Holm, L.

    2010-01-05

    This paper describes a new approach to environmental decision support for salinity management in the San Joaquin Basin of California that focuses on web-based data sharing using YSI Econet technology and continuous data quality management using a novel software tool, Aquarius.

  5. EXPERIMENTAL EVALUATION OF CHEMICAL SEQUESTRATION OF CARBON DIOXIDE IN DEEP AQUIFER MEDIA - PHASE II

    SciTech Connect (OSTI)

    Neeraj Gupta; Bruce Sass; Jennifer Ickes

    2000-11-28

    In 1998 Battelle was selected by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) under a Novel Concepts project grant to continue Phase II research on the feasibility of carbon dioxide (CO{sub 2}) sequestration in deep saline formations. The focus of this investigation is to conduct detailed laboratory experiments to examine factors that may affect chemical sequestration of CO{sub 2} in deep saline formations. Reactions between sandstone and other geologic media from potential host reservoirs, brine solutions, and CO{sub 2} are being investigated under high-pressure conditions. Some experiments also include sulfur dioxide (SO{sub 2}) gases to evaluate the potential for co-injection of CO{sub 2} and SO{sub 2} related gases in the deep formations. In addition, an assessment of engineering and economic aspects is being conducted. This current Technical Progress Report describes the status of the project as of September 2000. The major activities undertaken during the quarter included several experiments conducted to investigate the effects of pressure, temperature, time, and brine composition on rock samples from potential host reservoirs. Samples (both powder and slab) were taken from the Mt. Simon Sandstone, a potential CO{sub 2} host formation in the Ohio, the Eau Claire Shale, and Rome Dolomite samples that form the caprock for Mt. Simon Sandstone. Also, a sample with high calcium plagioclase content from Frio Formation in Texas was used. In addition, mineral samples for relatively pure Anorthite and glauconite were experimented on with and without the presence of additional clay minerals such as kaolinite and montmorillonite. The experiments were run for one to two months at pressures similar to deep reservoirs and temperatures set at 50 C or 150 C. Several enhancements were made to the experimental equipment to allow for mixing of reactants and to improve sample collection methods. The resulting fluids (gases and liquids) as well as the rock samples were characterized to evaluate the geochemical changes over the experimental period. Preliminary results from the analysis are presented in the report. More detailed interpretation of the results will be presented in the technical report at the end of Phase II.

  6. Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium-contaminated aquife

    SciTech Connect (OSTI)

    Campbell, K M; K Kukkadapu, R K; Qafoku, N P; Peacock, A D; Lesher, E; Williams, K H; Bargar, J R; Wilkins, M J; Figueroa, L; Ranville, J; Davis, J A; Long, P E

    2012-05-23

    Localized zones or lenses of naturally reduced sediments have the potential to play a significant role in the fate and transport of redox-sensitive metals and metalloids in aquifers. To assess the mineralogy, microbiology and redox processes that occur in these zones, several cores from a region of naturally occurring reducing conditions in a U-contaminated aquifer (Rifle, CO) were examined. Sediment samples from a transect of cores ranging from oxic/suboxic Rifle aquifer sediment to naturally reduced sediment were analyzed for U and Fe content, oxidation state, and mineralogy; reduced S phases; and solid-phase organic C content using a suite of analytical and spectroscopic techniques on bulk sediment and size fractions. Solid-phase U concentrations were higher in the naturally reduced zone, with a high proportion of the U present as U(IV). The sediments were also elevated in reduced S phases and Fe(II), indicating it is very likely that U(VI), Fe(III), and SO4 reduction has occurred or is occurring in the sediment. The microbial community was assessed using lipid- and DNA-based techniques, and statistical redundancy analysis was performed to determine correlations between the microbial community and the geochemistry. Increased concentrations of solid-phase organic C and biomass in the naturally reduced sediment suggests that natural bioreduction is stimulated by a zone of increased organic C concentration associated with fine-grained material and lower permeability to groundwater flow. Characterization of the naturally bioreduced sediment provides an understanding of the natural processes that occur in the sediment under reducing conditions and how they may impact natural attenuation of radionuclides and other redox sensitive materials. Results also suggest the importance of recalcitrant organic C for maintaining reducing conditions and U immobilization.

  7. Using complex resistivity imaging to infer biogeochemical processes associated with bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Flores-Orozco, Adrian; Williams, Kenneth H.; Long, Philip E.; Hubbard, Susan S.; Kemna, Andreas

    2011-07-07

    Experiments at the Department of Energys Rifle Integrated Field Research Challenge (IFRC) site near Rifle, Colorado (USA) have demonstrated the ability to remove uranium from groundwater by stimulating the growth and activity of Geobacter species through acetate amendment. Prolonging the activity of these strains in order to optimize uranium bioremediation has prompted the development of minimally-invasive and spatially-extensive monitoring methods diagnostic of their in situ activity and the end products of their metabolism. Here we demonstrate the use of complex resistivity imaging for monitoring biogeochemical changes accompanying stimulation of indigenous aquifer microorganisms during and after a prolonged period (100+ days) of acetate injection. A thorough raw-data statistical analysis of discrepancies between normal and reciprocal measurements and incorporation of a new power-law phase-error model in the inversion were used to significantly improve the quality of the resistivity phase images over those obtained during previous monitoring experiments at the Rifle IRFC site. The imaging results reveal spatiotemporal changes in the phase response of aquifer sediments, which correlate with increases in Fe(II) and precipitation of metal sulfides (e.g., FeS) following the iterative stimulation of iron and sulfate reducing microorganism. Only modest changes in resistivity magnitude were observed over the monitoring period. The largest phase anomalies (>40 mrad) were observed hundreds of days after halting acetate injection, in conjunction with accumulation of Fe(II) in the presence of residual FeS minerals, reflecting preservation of geochemically reduced conditions in the aquifer a prerequisite for ensuring the long-term stability of immobilized, redox-sensitive contaminants, such as uranium.

  8. Using complex resistivity imaging to infer biogeochemical processes associated with bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Orozco, A. Flores; Williams, K.H.; Long, P.E.; Hubbard, S.S.; Kemna, A.

    2011-04-01

    Experiments at the Department of Energy's Rifle Integrated Field Research Challenge (IFRC) site near Rifle, Colorado (USA) have demonstrated the ability to remove uranium from groundwater by stimulating the growth and activity of Geobacter species through acetate amendment. Prolonging the activity of these strains in order to optimize uranium bioremediation has prompted the development of minimally-invasive and spatially-extensive monitoring methods diagnostic of their in situ activity and the end products of their metabolism. Here we demonstrate the use of complex resistivity imaging for monitoring biogeochemical changes accompanying stimulation of indigenous aquifer microorganisms during and after a prolonged period (100+ days) of acetate injection. A thorough raw-data statistical analysis of discrepancies between normal and reciprocal measurements and incorporation of a new power-law phase-error model in the inversion were used to significantly improve the quality of the resistivity phase images over those obtained during previous monitoring experiments at the Rifle IRFC site. The imaging results reveal spatiotemporal changes in the phase response of aquifer sediments, which correlate with increases in Fe(II) and precipitation of metal sulfides (e.g., FeS) following the iterative stimulation of iron and sulfate reducing microorganism. Only modest changes in resistivity magnitude were observed over the monitoring period. The largest phase anomalies (>40 mrad) were observed hundreds of days after halting acetate injection, in conjunction with accumulation of Fe(II) in the presence of residual FeS minerals, reflecting preservation of geochemically reduced conditions in the aquifer - a prerequisite for ensuring the long-term stability of immobilized, redox-sensitive contaminants, such as uranium.

  9. Permeability, geochemical, and water quality tests in support of an aquifer thermal energy storage site in Minnesota

    SciTech Connect (OSTI)

    Blair, S.C.; Deutsch, W.J.; Mitchell, P.J.

    1985-04-01

    This report describes the Underground Energy Storage Program's efforts to characterize physicochemical processes at DOE's ATES Field Test Facility (FTF) located on the University of Minnesota campus at St. Paul, Minnesota. Experimental efforts include: field tests at the St. Paul FTF to characterize fluid injectability and to evaluate the effectiveness of fluid-conditioning equipment, geochemical studies to investigate chemical reactions resulting from alterations to the aquifer's thermal regime, and laboratory tests on sandstone core from the site. Each experimental area is discussed and results obtained thus far are reported. 23 refs., 39 figs., 12 tabs.

  10. Stratigraphy of the unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory, Idaho

    SciTech Connect (OSTI)

    Anderson, S.R.; Liszewski, M.J.

    1997-08-01

    The unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory (INEL) are made up of at least 178 basalt-flow groups, 103 sedimentary interbeds, 6 andesite-flow groups, and 4 rhyolite domes. Stratigraphic units identified in 333 wells in this 890-mile{sup 2} area include 121 basalt-flow groups, 102 sedimentary interbeds, 6 andesite-flow groups, and 1 rhyolite dome. Stratigraphic units were identified and correlated using the data from numerous outcrops and 26 continuous cores and 328 natural-gamma logs available in December 1993. Basalt flows make up about 85% of the volume of deposits underlying the area.

  11. Field Evaluation of the Restorative Capacity of the Aquifer Downgradient of a Uranium In-Situ Recovery Mining Site

    SciTech Connect (OSTI)

    Reimus, Paul William

    2015-05-22

    A two-part field study was conducted in Smith Ranch-Highland in-situ recovery (ISR) near Douglas, Wyoming, to evaluate the restorative capacity of the aquifer downgradient (i.e., hydrologically downstream) of a Uranium ISR mining site with respect to the transport of uranium and other potential contaminants in groundwater after mining has ceased. The study was partially conducted by checking the Uranium content and the alkalinity of separate wells, some wells had been restored and others had not. A map and in-depth procedures of the study are included.

  12. /sup 234/U//sup 230/Th ratio as an indicator of redox state, and U, Th and Ra behavior in briney aquifers

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1985-06-01

    The /sup 234/U//sup 230/Th ratio serves as an in-situ indicator of the redox state in groundwater aquifers. The higher this ratio, the more U there is in the +6 state and thus a lesser reducing environment. Radium is retarded in the shallow aquifer and its sorption is dependent on the CaSO/sub 4/ content and redox state. Relative to Ra, U and Th are highly sorbed. The total retardation factor for Th is approx.1400 and mean sorption time for /sup 228/Th is approx.10 days in the shallow zone. The desorption rate of Ra is significantly slower in the shallow than in the deep aquifer. There is no effect of colloids in brines. 6 refs., 5 figs., 2 tabs.

  13. /sup 234/U//sup 230/Th ratio as an indicator of redox state, and U/sub 2/, Th, and Ra behavior in Briney aquifers

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1986-01-01

    The /sup 234/U//sup 230/Th ratio serves as an in-situ indicator of the redox state in groundwater aquifers. The higher this ratio, the more U there is in the +6 valance state and thus a less reducing environment. Radium sorption is retarded in the shallow aquifer and is dependent on the CaSO/sub 4/ content and the redox state. Relative to Ra, U and Th are highly sorbed. The total retardation factor for Th is approx. 1400 and mean sorption time for /sup 228/Th is approx. 10 days in the shallow zone. The desorption rate of Ra is significantly slower in the shallow than in the deep aquifer. There is no effect of colloids in brines.

  14. Analysis of Aquifer Response, Groundwater Flow, and PlumeEvolution at Site OU 1, Former Fort Ord, California

    SciTech Connect (OSTI)

    Jordan, Preston D.; Oldenburg, Curtis M.; Su, Grace W.

    2005-02-24

    This report presents a continuation from Oldenburg et al. (2002) of analysis of the hydrogeology, In-Situ Permeable Flow Sensor (ISPFS) results, aquifer response, and changes in the trichloroethylene (TCE) groundwater plume at Operational Unit 1 (OU 1) adjacent to the former Fritzsche Army Airfield at the former Fort Ord Army Base, located on Monterey Bay in northern Monterey County. Fuels and solvents were burned on a portion of OU 1 called the Fire Drill Area (FDA) during airport fire suppression training between 1962 and 1985. This activity resulted in soil and groundwater contamination in the unconfined A-aquifer. In the late 1980's, soil excavation and bioremediation were successful in remediating soil contamination at the site. Shortly thereafter, a groundwater pump, treat, and recharge system commenced operation. This system has been largely successful at remediating groundwater contamination at the head of the groundwater plume. However, a trichloroethylene (TCE) groundwater plume extends approximately 3000 ft (900 m) to the northwest away from the FDA. In the analyses presented here, we augment our prior work (Oldenburg et al., 2002) with new information including treatment-system totalizer data, recent water-level and chemistry data, and data collected from new wells to discern trends in contaminant migration and groundwater flow that may be useful for ongoing remediation efforts. Some conclusions from the prior study have been modified based on these new analyses, and these are pointed out clearly in this report.

  15. Simulation and resistivity modeling of a geothermal reservoir with waters of different salinity

    SciTech Connect (OSTI)

    Pruess, K.; Wilt, M.; Bodvarsson, G.S.; Goldstein, N.E.

    1982-10-01

    Apparent resistivities measured by means of repetitive dipole-dipole surveys show significant changes within the Cerro Prieto reservoir. The changes are attributed to production and natural recharge. To better understand the observed geophysical phenomena a simple reservoir simulation study combined with the appropriate DC resistivity calculations to determine the expected magnitude of apparent resistivity change. We consider production from a liquid-dominated reservoir with dimensions and parameters of the Cerro Prieto A reservoir and assume lateral and vertical recharge of colder and less saline waters. Based on rather schematic one- and two-dimensional reservoir simulations, we calculate changes in formation resistivity which we then transform into changes in apparent resistivity that would be observed at the surface. Simulated changes in apparent resistivities over the production zone show increases of 10 to 20% over a 3 year period at the current rate of fluid extraction. Changes of this magnitude are not only within our ability to discern using proper field techniques, but are consistent in magnitude with some of the observed effects. However, the patterns of apparent resistivity changes in the simulated dipole-dipole pseudosection only partially resemble the observed field data. This is explained by the fact that the actual fluid recharge into the A reservoir is more complicated than assumed in our simple, schematic recharge models.

  16. Laboratory measurements of large-scale carbon sequestration flows in saline reservoirs

    SciTech Connect (OSTI)

    Backhaus, Scott N

    2010-01-01

    Brine saturated with CO{sub 2} is slightly denser than the original brine causing it to sink to the bottom of a saline reservoir where the CO{sub 2} is safely sequestered. However, the buoyancy of pure CO{sub 2} relative to brine drives it to the top of the reservoir where it collects underneath the cap rock as a separate phase of supercritical fluid. Without additional processes to mix the brine and CO{sub 2}, diffusion in this geometry is slow and would require an unacceptably long time to consume the pure CO{sub 2}. However, gravity and diffusion-driven convective instabilities have been hypothesized that generate enhanced CO{sub 2}-brine mixing promoting dissolution of CO{sub 2} into the brine on time scale of a hundred years. These flows involve a class of hydrodynamic problems that are notoriously difficult to simulate; the simultaneous flow of mUltiple fluids (CO{sub 2} and brine) in porous media (rock or sediment). The hope for direct experimental confirmation of simulations is dim due to the difficulty of obtaining high resolution data from the subsurface and the high pressures ({approx}100 bar), long length scales ({approx}100 meters), and long time scales ({approx}100 years) that are characteristic of these flows. We have performed imaging and mass transfer measurements in similitude-scaled laboratory experiments that provide benchmarks to test reservoir simulation codes and enhance their predictive power.

  17. Effect of temperature, salinity and oil composition on wetting behavior and oil recovery by waterflooding

    SciTech Connect (OSTI)

    Tang, G.Q.; Morrow, N.R.

    1996-12-31

    The effect of aging and displacement temperatures, and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea Sandstone using three distinctly different crude oils and three reservoir brines. Brine concentration was varied by changing the concentration of total dissolved solids of the synthetic brine in proportion to give brine of twice, one tenth, and one hundredth of the reservoir brine concentration. Aging and displacement temperatures were varied independently. For all crude oils, water-wetness and oil recovery increased with increase in displacement temperature. Tests on the effect of brine concentration showed that salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the reservoir brine with dilution of both the initial (connate) and invading brine or dilution of either. Removal of light components from the crude oil resulted in increased water-wetness. Addition of alkanes to the crude oil reduced the water-wetness, and increased oil recovery. Relationships between waterflood recovery and wettability are summarized.

  18. Expanding the potential for saline formations : modeling carbon dioxide storage, water extraction and treatment for power plant cooling.

    SciTech Connect (OSTI)

    Not Available

    2011-04-01

    The National Water, Energy and Carbon Sequestration simulation model (WECSsim) is being developed to address the question, 'Where in the current and future U.S. fossil fuel based electricity generation fleet are there opportunities to couple CO{sub 2} storage and extracted water use, and what are the economic and water demand-related impacts of these systems compared to traditional power systems?' The WECSsim collaborative team initially applied this framework to a test case region in the San Juan Basin, New Mexico. Recently, the model has been expanded to incorporate the lower 48 states of the U.S. Significant effort has been spent characterizing locations throughout the U.S. where CO{sub 2} might be stored in saline formations including substantial data collection and analysis efforts to supplement the incomplete brine data offered in the NatCarb database. WECSsim calculates costs associated with CO{sub 2} capture and storage (CCS) for the power plant to saline formation combinations including parasitic energy costs of CO{sub 2} capture, CO{sub 2} pipelines, water treatment options, and the net benefit of water treatment for power plant cooling. Currently, the model can identify the least-cost deep saline formation CO{sub 2} storage option for any current or proposed coal or natural gas-fired power plant in the lower 48 states. Initial results suggest that additional, cumulative water withdrawals resulting from national scale CCS may range from 676 million gallons per day (MGD) to 30,155 MGD depending on the makeup power and cooling technologies being utilized. These demands represent 0.20% to 8.7% of the U.S. total fresh water withdrawals in the year 2000, respectively. These regional and ultimately nation-wide, bottom-up scenarios coupling power plants and saline formations throughout the U.S. can be used to support state or national energy development plans and strategies.

  19. Diuretic Agent and Normal Saline Infusion Technique for Ultrasound-Guided Percutaneous Nephrostomies in Nondilated Pelvicaliceal Systems

    SciTech Connect (OSTI)

    Yagci, Cemil Ustuner, Evren Atman, Ebru Dusunceli; Baltaci, Sumer; Uzun, Caglar Akyar, Serdar

    2013-04-15

    Percutaneous nephrostomy (PCN) in a nondilated pelvicaliceal system is technically challenging. We describe an effective method to achieve transient dilatation of the pelvicaliceal system via induction of diuresis using infusion of a diuretic agent in normal saline, therefore allowing easier access to the pelvicaliceal system. Under real-time ultrasound guidance, the technique had been tested in 22 nephrostomies with nondilated system (a total of 20 patients with 2 patients having bilateral nephrostomies) during a 5-year period. Patients were given 40 mg of furosemide in 250 ml of normal saline solution intravenously by rapid infusion. As soon as maximum calyceal dilatation of more than 5 mm was observed, which is usually 15 min later after the end of rapid infusion, patients were positioned obliquely, and PCN procedure under ultrasound guidance was performed. The procedure was successful in 19 of the nephrostomies in 17 patients with a success rate of 86.36 % per procedure and 85 % per patient in nondilated pelvicaliceal systems. No major nephrostomy-, drug-, or technique-related complications were encountered. The technique failed to work in three patients due to the presence of double J catheters and preexisting calyceal perforation which avoided transient dilation of the pelvicaliceal system with diuresis. Diuretic infusion in saline is a feasible and effective method for PCN in nondilated pelvicaliceal systems.

  20. Ground-water geochemistry and radionuclide activity in the Cambrian-Ordovician aquifer of Dodge and Fond du Lac counties, Wisconsin. Technical report

    SciTech Connect (OSTI)

    Weaver, T.R.; Bahr, J.M.; Anderson, M.P.

    1990-01-01

    Analyses of groundwater from wells in the Cambrian-Ordovician aquifer of eastern Wisconsin indicate that regions of the aquifer contain elevated concentrations of dissolved solids, chloride and sulfate. Groundwater from several wells in the area also approach or exceed the current drinking water standard for combined radium activity. Significant changes in groundwater chemistry occur where the aquifer becomes confined by the Maquoketa shale. Concentrations of Cl(-), SO4(2-) and Na(+) increase in the confined region, and the highest combined radium activities are typically observed in the area. Geochemical modeling implies that the observed changes in major ion groundwater chemistry occur in response to the presence of the confining unit which may act as a source of SO4(2-), through gypsum dissolution, and Na(+), through cation exchange. A finite difference groundwater flow model was linked to a particle tracking routine to determine groundwater flow paths and residence times in the aquifer near the boundary between unconfined and confined conditions. Results suggest that the presence of the confining unit produces a vertically stratified flow regime in the confined region.

  1. Impact of sedimentary provenance and weathering on arsenic distribution in aquifers of the Datong basin, China: Constraints from elemental geochemistry

    SciTech Connect (OSTI)

    Xie, Xianjun; Wang, Yanxin; Ellis, Andre; Liu, Chongxuan; Duan, Mengyu; Li, Junxia

    2014-11-01

    Arsenic (As)-contaminated aquifer sediments from Datong basin, China have been analyzed to infer the provenance and depositional environment related to As distribution in the aquifer sediments. The As content in the sediments ranged from 2.45 to 27.38 mg/kg with an average value of 9.54 mg/kg, which is comparable to the average value in modern unconsolidated sediments. However, minor variation in As concentration with depth has been observed in the core. There was a significant correlation between Fe, and Al and As, which was attributed to the adsorption or co-precipitation of As onto/with Fe oxides/hydroxides and/or Fe-coated clay minerals. Post-Archean Australian Shale (PAAS)-normalized REEs patterns of sediment samples along the borehole were constant, and the sediments had a notably restricted range of La-N/Yb-N ratios from 0.7 to 1.0. These results suggested that the provenance of the Datong basin remained similar throughout the whole depositional period. The analysis of major geochemical compositions confirmed that all core sediments were from the same sedimentary source and experienced significant sedimentary recycling. The co-variation of As, V/Al, Ni/Al and chemical index of alteration (CIA) values in the sediments along the borehole suggested that As distribution in the sediments was primarily controlled by weathering processes. The calculated CIA values of the sediments along the borehole indicate that a relative strong chemical weathering occurred during the deposition of sediments at depths of similar to 35 to 88 m, which was corresponding to the depth at which high As groundwater was observed at the site. Strong chemical weathering favored the deposition of Fe-bearing minerals including poorly crystalline and crystalline Fe oxide mineral phases and concomitant co-precipitation of As with these minerals in the sediments. Subsequent reductive dissolution of As-bearing poorly crystalline and crystalline Fe oxides would result in the enrichment of As in groundwater. In general, the chemical weathering during the deposition of the sediments governed the co-accumulation of Fe oxides and As in the aquifer sediments. And then, the reductive dissolution of Fe oxides/hydroxides is the mechanism of As enrichment in the groundwater in the Datong basin

  2. HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS

    SciTech Connect (OSTI)

    Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

    2012-01-01

    The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

  3. Natural Recharge to the Unconfined Aquifer System on the Hanford Site from the Greater Cold Creek Watershed: Progress Report 2004

    SciTech Connect (OSTI)

    Waichler, Scott R.; Wigmosta, Mark S.; Coleman, Andre M.

    2004-09-14

    Movement of contaminants in groundwater at the Hanford Site is heavily dependent on recharge to the unconfined aquifer. As the effects of past artificial discharges dissipate, the water table is expected to return to more natural conditions, and natural recharge will become the driving force when evaluating future groundwater flow conditions and related contaminant transport. Previous work on the relationship of natural recharge to groundwater movement at the Hanford Site has focused on direct recharge from infiltrating rainfall and snowmelt within the area represented by the Sitewide Groundwater Model (SGM) domain. However, part of the groundwater recharge at Hanford is provided by flow from Greater Cold Creek watershed (GCC), a large drainage area on the western boundary of the Hanford Site that includes Cold Creek Valley, Dry Creek Valley, and the Hanford side of Rattlesnake Mountain. This study was undertaken to estimate the recharge from GCC, which is believed to enter the unconfined aquifer as both infiltrating streamflow and shallow subsurface flow. To estimate recharge, the Distributed Hydrology-Soil-Vegetation Model (DHSVM) was used to simulate a detailed water balance of GCC from 1956 to 2001 at a spatial resolution of 200~m and a temporal resolution of one hour. For estimating natural recharge to Hanford from watersheds along its western and southwestern boundaries, the most important aspects that need to be considered are 1)~distribution and relative magnitude of precipitation and evapotranspiration over the watershed, 2)~streamflow generation at upper elevations and infiltration at lower elevations during rare runoff events, and 3)~permeability of the basalt bedrock surface underlying the soil mantle.

  4. Evaluating Impacts of CO2 and CH4 Gas Intrusion into an Unconsolidated Aquifer: Fate of As and Cd

    SciTech Connect (OSTI)

    Lawter, Amanda R.; Qafoku, Nikolla; Shao, Hongbo; Bacon, Diana H.; Brown, Christopher F.

    2015-07-10

    Abstract The sequestration of carbon dioxide (CO2) in deep underground reservoirs has been identified as an important strategy to decrease atmospheric CO2 levels and mitigate global warming, but potential risks on overlying aquifers currently lack a complete evaluation. In addition to CO2, other gases such as methane (CH4) may be present in storage reservoirs. This paper explores for the first time the combined effect of leaking CO2 and CH4 gasses on the fate of major, minor and trace elements in an aquifer overlying a potential sequestration site. Emphasis is placed on the fate of arsenic (As) and cadmium (Cd) released from the sediments or present as soluble constituents in the leaking brine. Results from macroscopic batch and column experiments show that the presence of CH4 (at a concentration of 1 % in the mixture CO2/CH4) does not have a significant effect on solution pH or the concentrations of most major elements (such as Ca, Ba, and Mg). However, the concentrations of Mn, Mo, Si and Na are inconsistently affected by the presence of CH4 (i.e., in at least one sediment tested in this study). Cd is not released from the sediments and spiked Cd is mostly removed from the aqueous phase most likely via adsorption. The fate of sediment associated As [mainly sorbed arsenite or As(III) in minerals] and spiked As [i.e., As5+] is complex. Possible mechanisms that control the As behavior in this system are discussed in this paper. Results are significant for CO2 sequestration risk evaluation and site selection and demonstrate the importance of evaluating reservoir brine and gas stream composition during site selection to ensure the safest site is being chosen.

  5. Subtask 2.17 - CO{sub 2} Storage Efficiency in Deep Saline Formations

    SciTech Connect (OSTI)

    Gorecki, Charles; Liu, Guoxiang; Braunberger, Jason; Klenner, Robert; Ayash, Scott; Dotzenrod, Neil; Steadman, Edward; Harju, John

    2014-02-01

    As the field of carbon capture and storage (CCS) continues to advance, and large-scale implementation of geologic carbon dioxide (CO{sub 2}) storage progresses, it will be important to understand the potential of geologic formations to store meaningful amounts of CO{sub 2}. Geologic CO{sub 2} storage in deep saline formations (DSFs) has been suggested as one of the best potential methods for reducing anthropogenic CO{sub 2} emission to the atmosphere, and as such, updated storage resource estimation methods will continue to be an important component for the widespread deployment of CCS around the world. While there have been several methodologies suggested in the literature, most of these methods are based on a volumetric calculation of the pore volume of the DSF multiplied by a storage efficiency term and do not consider the effect of site-specific dynamic factors such as injection rate, injection pattern, timing of injection, pressure interference between injection locations, and overall formation pressure buildup. These volumetric methods may be excellent for comparing the potential between particular formations or basins, but they have not been validated through real-world experience or full-formation injection simulations. Several studies have also suggested that the dynamic components of geologic storage may play the most important role in storing CO{sub 2} in DSFs but until now have not directly compared CO{sub 2} storage resource estimates made with volumetric methodologies to estimates made using dynamic CO{sub 2} storage methodologies. In this study, two DSFs, in geographically separate areas with geologically diverse properties, were evaluated with both volumetric and dynamic CO{sub 2} storage resource estimation methodologies to compare the results and determine the applicability of both approaches. In the end, it was determined that the dynamic CO{sub 2} storage resource potential is timedependent and it asymptotically approaches the volumetric CO{sub 2} storage resource potential over very long periods of time in the two systems that were evaluated. These results indicate that the volumetric assessments can be used as long as the appropriate storage efficiency terms are used and it is understood that it will take many wells over very long periods of time to fully realize the storage potential of a target formation. This subtask was funded through the Energy & Environmental Research Center (EERC)– U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the IEA Greenhouse Gas R&D Programme.

  6. Changes in Hepatic Blood Flow During Transcatheter Arterial Infusion with Heated Saline in Hepatic VX2 Tumor

    SciTech Connect (OSTI)

    Cao Wei; Li Jing; Wu Zhiqun; Zhou Changxi; Liu Xi; Wan Yi; Duan Yunyou

    2013-06-15

    Purpose. This study evaluates the influence of transcatheter arterial infusion with heated saline on hepatic arterial and portal venous blood flows to tumor and normal hepatic tissues in a rabbit VX2 tumor model. Methods. All animal experiments were approved by the institutional animal care and use committee. Twenty rabbits with VX2 liver tumors were divided into the following two groups: (a) the treated group (n = 10), which received a 60 mL transarterial injection of 60 Degree-Sign C saline via the hepatic artery; (b) the control group (n = 10), which received a 60 mL injection of 37 Degree-Sign C saline via the hepatic artery. Using ultrasonography, the blood flows in both the portal vein and hepatic artery were measured, and the changes in the hemodynamic indices were recorded before and immediately after the injection. The changes in the tumor and normal liver tissues of the two groups were histopathologically examined by hematoxylin and eosin staining after the injection. Results. After the transcatheter arterial heated infusion, there was a decrease in the hepatic arterial blood flow to the tumor tissue, a significant decrease in the hepatic artery mean velocity (P < 0.05), and a significant increase in the resistance index (P < 0.05). On hematoxylin and eosin staining, there were no obvious signs of tissue destruction in the normal liver tissue or the tumor tissue after heated perfusion, and coagulated blood plasma was observed in the cavities of intratumoral blood vessels in the treated group. Conclusions. The changes in tumor blood flow in the rabbit VX2 tumor model were presumably caused by microthrombi in the tumor vessels, and the portal vein likely mediated the heat loss in normal liver tissue during the transarterial heated infusion.

  7. Field-Derived Hydraulic Properties for Perched-Water Aquifer Wells 299-E33-350 and 299-E33-351, Hanford Site B-Complex Area

    SciTech Connect (OSTI)

    Newcomer, Darrell R.

    2014-07-01

    During February and March 2014, Pacific Northwest National Laboratory conducted hydraulic (slug) tests at 200-DV-1 Operable Unit wells 299-E33-350 (C8914) and 299-E33-351 (C8915) as part of B-Complex Area Perched-Water characterization activities at the Hanford Site 200-East Area. During the construction/completion phase of each well, two overlapping depth intervals were tested within the unconfined perched-water aquifer contained in the silty-sand subunit of the Cold Creek Unit. The purpose of the slug-test characterization was to provide estimates of transmissivity and hydraulic conductivity for the perched-water aquifer at these selected well locations.

  8. A GIS COST MODEL TO ASSESS THE AVAILABILITY OF FRESHWATER, SEAWATER, AND SALINE GROUNDWATER FOR ALGAL BIOFUEL PRODUCTION IN THE UNITED STATES

    SciTech Connect (OSTI)

    Venteris, Erik R.; Skaggs, Richard; Coleman, Andre M.; Wigmosta, Mark S.

    2013-03-15

    A key advantage of using microalgae for biofuel production is the ability of some algal strains to thrive in waters unsuitable for conventional crop irrigation such as saline groundwater or seawater. Nonetheless, the availability of sustainable water supplies will provide significant challenges for scale-up and development of algal biofuels. We conduct a limited techno-economic assessment based on the availability of freshwater, saline groundwater, and seawater for use in open pond algae cultivation systems. We explore water issues through GIS-based models of algae biofuel production, freshwater supply, and cost models for supplying seawater and saline groundwater. We estimate that combined, within the coterminous US these resources can support production on the order of 9.46E+7 m3 yr-1 (25 billion gallons yr-1) of renewable biodiesel. Achievement of larger targets requires the utilization of less water efficient sites and relatively expensive saline waters. Geographically, water availability is most favorable for the coast of the Gulf of Mexico and Florida peninsula, where evaporation relative to precipitation is moderate and various saline waters are economically available. As a whole, barren and scrub lands of the southwestern US have limited freshwater supplies so accurate assessment of alternative waters is critical.

  9. Stratigraphy of the unsaturated zone and uppermost part of the Snake River Plain aquifer at test area north, Idaho National Engineering Laboratory, Idaho

    SciTech Connect (OSTI)

    Anderson, S.R.; Bowers, B.

    1995-06-01

    A complex sequence of basalt flows and sedimentary interbeds underlies Test Area North (TAN) at the Idaho National Engineering Laboratory in eastern Idaho. Wells drilled to depths of at least 500 feet penetrate 10 basalt-flow groups and 5 to 10 sedimentary interbeds that range in age from about 940,000 to 1.4 million years. Each basalt-flow group consists of one or more basalt flows from a brief, single or compound eruption. All basalt flows of each group erupted from the same vent, and have similar ages, paleomagnetic properties, potassium contents, and natural-gamma emissions. Sedimentary interbeds consist of fluvial, lacustrine, and eolian deposits of clay, silt, sand, and gravel that accumulated for hundreds to hundreds of thousands of years during periods of volcanic quiescence. Basalt and sediment are elevated by hundreds of feet with respect to rocks of equivalent age south and cast of the area, a relation that is attributed to past uplift at TAN. Basalt and sediment are unsaturated to a depth of about 200 feet below land surface. Rocks below this depth are saturated and make up the Snake River Plain aquifer. The effective base of the aquifer is at a depth of 885 feet below land surface. Detailed stratigraphic relations for the lowermost part of the aquifer in the depth interval from 500 to 885 feet were not determined because of insufficient data. The stratigraphy of basalt-flow groups and sedimentary interbeds in the upper 500 feet of the unsaturated zone and aquifer was determined from natural-gamma logs, lithologic logs, and well cores. Basalt cores were evaluated for potassium-argon ages, paleomagnetic properties, petrographic characteristics, and chemical composition. Stratigraphic control was provided by differences in ages, paleomagnetic properties, potassium content, and natural-gamma emissions of basalt-flow groups and sedimentary interbeds.

  10. Transient Inverse Calibration of Site-Wide Groundwater Model to Hanford Operational Impacts from 1943 to 1996--Alternative Conceptual Model Considering Interaction with Uppermost Basalt Confined Aquifer

    SciTech Connect (OSTI)

    Vermeul, Vincent R.; Cole, Charles R.; Bergeron, Marcel P.; Thorne, Paul D.; Wurstner, Signe K.

    2001-08-29

    The baseline three-dimensional transient inverse model for the estimation of site-wide scale flow parameters, including their uncertainties, using data on the transient behavior of the unconfined aquifer system over the entire historical period of Hanford operations, has been modified to account for the effects of basalt intercommunication between the Hanford unconfined aquifer and the underlying upper basalt confined aquifer. Both the baseline and alternative conceptual models (ACM-1) considered only the groundwater flow component and corresponding observational data in the 3-Dl transient inverse calibration efforts. Subsequent efforts will examine both groundwater flow and transport. Comparisons of goodness of fit measures and parameter estimation results for the ACM-1 transient inverse calibrated model with those from previous site-wide groundwater modeling efforts illustrate that the new 3-D transient inverse model approach will strengthen the technical defensibility of the final model(s) and provide the ability to incorporate uncertainty in predictions related to both conceptual model and parameter uncertainty. These results, however, indicate that additional improvements are required to the conceptual model framework. An investigation was initiated at the end of this basalt inverse modeling effort to determine whether facies-based zonation would improve specific yield parameter estimation results (ACM-2). A description of the justification and methodology to develop this zonation is discussed.

  11. Environmental Controls on the Activity of Aquifer Microbial Communities in the 300 Area of the Hanford Site

    SciTech Connect (OSTI)

    Konopka, Allan; Plymale, Andrew E.; Carvajal, Denny A.; Lin, Xueju; McKinley, James P.

    2013-11-06

    Aquifer microbes in the 300 Area of the Hanford Site in southeastern Washington State, USA are periodically exposed to U(VI) concentrations that can range up to 10 ?M in small sediment fractures. Assays of 35 H-leucine incorporation indicated that both sediment-associated and planktonic microbes were metabolically active, and that organic C was growth-limiting in the sediments. Although bacteria suspended in native groundwater retained high activity when exposed to 100 ?M U(VI), they were inhibited by U(VI) < 1 ?M in synthetic groundwater that lacked added bicarbonate. Chemical speciation modeling suggested that positively-charged species and particularly (UO2)3(OH)5+ rose in concentration as more U(VI) was added to synthetic groundwater, but that carbonate complexes dominated U(VI) speciation in natural groundwater. U toxicity was relieved when increasing amounts of bicarbonate were added to synthetic groundwater containing 4.5 ?M U(VI). Pertechnetate, an oxyanion that is another contaminant of concern at the Hanford Site, was not toxic to groundwater microbes at concentrations up to 125 ?M.

  12. A comparative evaluation of conceptual models for the Snake River Plain aquifer at the Idaho Chemical Processing Plant, INEL

    SciTech Connect (OSTI)

    Prahl, C.J.

    1992-01-01

    Geologic and hydrologic data collected by the United States Geological Survey (USGS) are used to evaluate the existing ground water monitoring well network completed in the upper portion of the Snake River Plain aquifer (SRPA) beneath the Idaho Chemical Processing Plant (ICPP). The USGS data analyzed and compared in this study include: (a) lithologic, geophysical, and stratigraphic information, including the conceptual geologic models intrawell, ground water flow measurement (Tracejector tests) and (c) dedicated, submersible, sampling group elevations. Qualitative evaluation of these data indicate that the upper portion of the SRPA is both heterogeneous and anisotropic at the scale of the ICPP monitoring well network. Tracejector test results indicate that the hydraulic interconnection and spatial configuration of water-producing zones is extremely complex within the upper portion of the SRPA. The majority of ICPP monitoring wells currently are equipped to sample ground water only the upper lithostratigraphic intervals of the SRPA, primarily basalt flow groups E, EF, and F. Depth-specific hydrogeochemical sampling and analysis are necessary to determine if ground water quality varies significantly between the various lithostratigraphic units adjacent to individual sampling pumps.

  13. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite sorption sites proving to be of secondary importance. The Groundwater Geochemistry ROM was developed using nonlinear regression to fit the response surface with a quadratic polynomial. The goodness of fit was excellent for the CO2 flux to the atmosphere, and very good for predicting the volumes of groundwater exceeding the pH, TDS, As, Cd and Pb threshold values.

  14. Interpretation of Flow Logs from Nevada Test Site Boreholes to Estimate Hydraulic conductivity Using Numerical Simulations Constrained by Single-Well Aquifer Tests

    SciTech Connect (OSTI)

    Garcia, C. Amanda; Halford, Keith J.; Laczniak, Randell J.

    2010-02-12

    Hydraulic conductivities of volcanic and carbonate lithologic units at the Nevada Test Site were estimated from flow logs and aquifer-test data. Borehole flow and drawdown were integrated and interpreted using a radial, axisymmetric flow model, AnalyzeHOLE. This integrated approach is used because complex well completions and heterogeneous aquifers and confining units produce vertical flow in the annular space and aquifers adjacent to the wellbore. AnalyzeHOLE simulates vertical flow, in addition to horizontal flow, which accounts for converging flow toward screen ends and diverging flow toward transmissive intervals. Simulated aquifers and confining units uniformly are subdivided by depth into intervals in which the hydraulic conductivity is estimated with the Parameter ESTimation (PEST) software. Between 50 and 150 hydraulic-conductivity parameters were estimated by minimizing weighted differences between simulated and measured flow and drawdown. Transmissivity estimates from single-well or multiple-well aquifer tests were used to constrain estimates of hydraulic conductivity. The distribution of hydraulic conductivity within each lithology had a minimum variance because estimates were constrained with Tikhonov regularization. AnalyzeHOLE simulated hydraulic-conductivity estimates for lithologic units across screened and cased intervals are as much as 100 times less than those estimated using proportional flow-log analyses applied across screened intervals only. Smaller estimates of hydraulic conductivity for individual lithologic units are simulated because sections of the unit behind cased intervals of the wellbore are not assumed to be impermeable, and therefore, can contribute flow to the wellbore. Simulated hydraulic-conductivity estimates vary by more than three orders of magnitude across a lithologic unit, indicating a high degree of heterogeneity in volcanic and carbonate-rock units. The higher water transmitting potential of carbonate-rock units relative to volcanic-rock units is exemplified by the large difference in their estimated maximum hydraulic conductivity; 4,000 and 400 feet per day, respectively. Simulated minimum estimates of hydraulic conductivity are inexact and represent the lower detection limit of the method. Minimum thicknesses of lithologic intervals also were defined for comparing AnalyzeHOLE results to hydraulic properties in regional ground-water flow models.

  15. Dynamics of Microbial Community Composition and Function during In Situ Bioremediation of a Uranium-Contaminated Aquifer

    SciTech Connect (OSTI)

    Van Nostrand, Dr. Joy D.; Wu, Liyou; Wu, Weimin; Huang, Zhijian; Gentry, Terry J; Deng, Ye; Carley, Jack M; Carroll, Sue L; He, Zhili; Gu, Baohua; Luo, Jian; Criddle, Craig; Watson, David B; Jardine, Philip M; Marsh, Terence; Tiedje, James; Hazen, Terry; Zhou, Jizhong

    2011-01-01

    A pilot-scale system was established to examine the feasibility of in situ U(VI) immobilization at a highly contaminated aquifer (U.S. DOE Integrated Field Research Challenge site, Oak Ridge, TN). Ethanol was injected intermittently as an electron donor to stimulate microbial U(VI) reduction, and U(VI) concentrations fell to below the Environmental Protection Agency drinking water standard (0.03 mg liter 1). Microbial communities from three monitoring wells were examined during active U(VI) reduction and maintenance phases with GeoChip, a high-density, comprehensive functional gene array. The overall microbial community structure exhibited a considerable shift over the remediation phases examined. GeoChip-based analysis revealed that Fe(III)-reducing bacterial (FeRB), nitrate-reducing bacterial (NRB), and sulfate-reducing bacterial (SRB) functional populations reached their highest levels during the active U(VI) reduction phase (days 137 to 370), in which denitrification and Fe(III) and sulfate reduction occurred sequentially. A gradual decrease in these functional populations occurred when reduction reactions stabilized, suggesting that these functional populations could play an important role in both active U(VI) reduction and maintenance of the stability of reduced U(IV). These results suggest that addition of electron donors stimulated the microbial community to create biogeochemical conditions favorable to U(VI) reduction and prevent the reduced U(IV) from reoxidation and that functional FeRB, SRB, and NRB populations within this system played key roles in this process.

  16. Dynamics of microbial community composition and function during in-situ bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Nostrand, J.D. Van; Wu, L.; Wu, W.M.; Huang, A.; Gentry, T.J.; Deng, Y.; Carley, J.; Carrol, S.; He, Z.; Gu, B.; Luo, J.; Criddle, C.S.; Watson, D.B.; Jardine, P.M.; Marsh, T.L.; Tiedje, J.M.; Hazen, T.C.; Zhou, J.

    2010-08-15

    A pilot-scale system was established to examine the feasibility of in situ U(VI) immobilization at a highly contaminated aquifer (U.S. DOE Integrated Field Research Challenge site, Oak Ridge, TN). Ethanol was injected intermittently as an electron donor to stimulate microbial U(VI) reduction, and U(VI) concentrations fell to below the Environmental Protection Agency drinking water standard (0.03 mg liter{sup -1}). Microbial communities from three monitoring wells were examined during active U(VI) reduction and maintenance phases with GeoChip, a high-density, comprehensive functional gene array. The overall microbial community structure exhibited a considerable shift over the remediation phases examined. GeoChip-based analysis revealed that Fe(III)-reducing bacterial (FeRB), nitrate-reducing bacterial (NRB), and sulfate-reducing bacterial (SRB) functional populations reached their highest levels during the active U(VI) reduction phase (days 137 to 370), in which denitrification and Fe(III) and sulfate reduction occurred sequentially. A gradual decrease in these functional populations occurred when reduction reactions stabilized, suggesting that these functional populations could play an important role in both active U(VI) reduction and maintenance of the stability of reduced U(IV). These results suggest that addition of electron donors stimulated the microbial community to create biogeochemical conditions favorable to U(VI) reduction and prevent the reduced U(IV) from reoxidation and that functional FeRB, SRB, and NRB populations within this system played key roles in this process.

  17. Influence of Carbon and Microbial Community Priming on the Attenuation of Uranium in a Contaminated Floodplain Aquifer

    SciTech Connect (OSTI)

    Mouser, Paula J.; N'Guessan, A. Lucie; Qafoku, Nikolla; Sinha, M.; Williams, K. H.; Dangelmayr, M.; Resch, Charles T.; Peacock, Aaron D.; Wang, Zheming; Figueroa, Linda A.; Long, P. E.

    2015-07-01

    The capacity for subsurface sediments to sequester metal contaminants, such as uranium (U), and retain them after bioremediation efforts are completed is critical to site stewardship. Sediments enriched in natural organic matter are capable of sequestering significant quantities of U, but may also serve as sources to the aquifer, contributing to plume persistence. Two types of sediments were compared to better understand the mechanisms contributing to the sequestration and release of U in the presence of organic matter. Artificially bioreduced sediments were retrieved from a field experimental plot previously stimulated with acetate while naturally bioreduced sediments were collected from a location enriched in organic matter but never subject to acetate amendment. Batch incubations demonstrated that the artificially bioreduced sediments were primed to rapidly remove uranium from the groundwater whereas naturally bioreduced sediments initially released a sizeable portion of sediment U before U(VI)-removal commenced. Column experiments confirmed that U release persisted for 65 pore volumes in naturally bioreduced sediments, demonstrating the sink-source behavior of this sediment. Acetate addition to artificially bioreduced sediments shifted the microbial community from one dominated by sulfate-reducing bacteria within Desulfobacteraceae to the iron-reducing family Geobacteraceae and Firmicutes during U(VI) reduction. In contrast, initial Geobacteraceae communities innaturally reduced sediments were replaced by clone sequences with similarity to opportunistic Pseudomonas spp. during U release, while U(VI) removal occurred concurrent with enrichment of Firmicutes. These investigations stress the importance of characterizing zones with heterogeneous carbon pools at U contaminated sites prior to the determination of a remedial strategy.

  18. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  19. Review and problem definition of water/rock reactions associated with injection of spent geothermal fluids from a geothermal plant into aquifers

    SciTech Connect (OSTI)

    Elders, W.A.

    1986-07-01

    Among the technical problems faced by the burgeoning geothermal industry is the disposal of spent fluids from power plants. Except in unusual circumstances the normal practice, especially in the USA, is to pump these spent fluids into injection wells to prevent contamination of surface waters, and possibly in some cases, to reduce pressure drawdown in the producing aquifers. This report is a survey of experience in geothermal injection, emphasizing geochemical problems, and a discussion of approaches to their possible mitigation. The extraction of enthalpy from geothermal fluid in power plants may cause solutions to be strongly supersaturated in various dissolved components such as silica, carbonates, sulfates, and sulfides. Injection of such supersaturated solutions into disposal wells has the potential to cause scaling in the well bores and plugging of the aquifers, leading to loss of injectivity. Various aspects of the geochemistry of geothermal brines and their potential for mineral formation are discussed, drawing upon a literature survey. Experience of brine treatment and handling, and the economics of mineral extraction are also addressed in this report. Finally suggestions are made on future needs for possible experimental, field and theoretical studies to avoid or control mineral scaling.

  20. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in

    Office of Scientific and Technical Information (OSTI)

    Deep Saline Aquifers. (Conference) | SciTech Connect Surfaces in Deep Saline Aquifers. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: 2013-01-01 OSTI Identifier: 1063603 Report Number(s): SAND2013-0408C DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the CFSES Seminar, University of

  1. Potential Impacts of Leakage from Black Rock Reservoir on the Hanford Site Unconfined Aquifer: Initial Hypothetical Simulations of Flow and Contaminant Transport

    SciTech Connect (OSTI)

    Freedman, Vicky L.

    2008-01-30

    Initial scoping calculations of the unconfined aquifer at the Hanford Site were carried out for the U.S. Bureau of Reclamation (USBR) to investigate the potential impacts on the Hanford unconfined aquifer that would result from leakage from the proposed Black Rock Reservoir to the west. Although impacts on groundwater flow and contaminant transport were quantified based on numerical simulation results, the investigation represented a qualitative assessment of the potential lateral recharge that could result in adverse effects on the aquifer. Because the magnitude of the potential leakage is unknown, hypothetical bounding calculations were performed. When a quantitative analysis of the magnitude of the potential recharge from Black Rock Reservoir is obtained, the hydrologic impacts analysis will be revisited. The analysis presented in this report represents initial bounding calculations. A maximum lateral recharge (i.e., upland flux) was determined in the first part of this study by executing steady-state flow simulations that raised the water table no higher than the elevation attained in the Central Plateau during the Hanford operational period. This metric was selected because it assumed a maximum remobilization of contaminants that existed under previous fully saturated conditions. Three steady-state flow fields were then used to analyze impacts to transient contaminant transport: a maximum recharge (27,000 acre-ft/yr), a no additional flux (365 acre-ft/yr), and an intermediate recharge case (16,000 acre-ft/yr). The transport behavior of four radionuclides was assessed for a 300 year simulation period with the three flow fields. The four radionuclides are tritium, iodine-129, technetium-99, and uranium-238. Transient flow and transport simulations were used to establish hypothetical concentration distributions in the subsurface. Using the simulated concentration distributions in 2005 as initial conditions for steady-state flow runs, simulations were executed to investigate the relative effects on contaminant transport from the increased upland fluxes. Contaminant plumes were analyzed for 1) peak concentrations and arrival times at downstream points of compliance, 2) the area of the aquifer contaminated at or above the drinking water standard (DWS), and 3) the total activity remaining in the domain at the end of the simulation. In addition to this analysis, unit source release simulations from a hypothetical tracer were executed to determine relative travel times from the Central Plateau. The results of this study showed that increases in the lateral recharge had limited impact on regional flow directions but accelerated contaminant transport. Although contaminant concentrations may have initially increased for the more mobile contaminants (tritium, technetium-99, and iodine-129), the accelerated transport caused dilution and a more rapid decline in concentrations relative to the Base Case (no additional flux). For the low-mobility uranium-238, higher lateral recharge caused increases in concentration, but these concentrations never approached the DWS. In this preliminary investigation, contaminant concentrations did not exceed the DWS study metric. With the increases in upland fluxes, more mass was transported out of the aquifer, and concentrations were diluted with respect to the base case where no additional flux was considered.

  2. Potential Impacts of Leakage from Black Rock Reservoir on the Hanford Site Unconfined Aquifer: Initial Hypothetical Simulations of Flow and Contaminant Transport

    SciTech Connect (OSTI)

    Freedman, Vicky L.

    2007-03-09

    Initial scoping calculations of the unconfined aquifer at the Hanford Site were carried out for the U.S. Bureau of Reclamation (USBR) to investigate the potential impacts on the Hanford unconfined aquifer that would result from leakage from the proposed Black Rock Reservoir to the west. Although impacts on groundwater flow and contaminant transport were quantified based on numerical simulation results, the investigation represented a qualitative assessment of the potential lateral recharge that could result in adverse effects on the aquifer. Because the magnitude of the potential leakage is unknown, hypothetical bounding calculations were performed. When a quantitative analysis of the magnitude of the potential recharge from Black Rock Reservoir is obtained, the hydrologic impacts analysis will be revisited. The analysis presented in this report represent initial bounding calculations. A maximum lateral recharge (i.e., upland flux) was determined in the first part of this study by executing steady-state flow simulations that raised the water table no higher than the elevation attained in the Central Plateau during the Hanford operational period. This metric was selected because it assumed a maximum remobilization of contaminants that existed under previous fully saturated conditions. Three steady-state flow fields were then used to analyze impacts to transient contaminant transport: a maximum recharge (27,000 acre-ft/yr), a no additional flux (365 acre-ft/yr), and an intermediate recharge case (16,000 acre-ft/yr). The transport behavior of four radionuclides was assessed for a 300 year simulation period with the three flow fields. The four radionuclides are current contaminants of concern (COCs) in the Central Plateau and include tritium, iodine-129, technetium-99, and uranium-238. Transient flow and transport simulations were used to establish hypothetical concentration distributions in the subsurface. Using the simulated concentration distributions in 2005 as initial conditions for steady-state flow runs, simulations were executed to investigate the relative effects on contaminant transport from the increased upland fluxes. Contaminant plumes were analyzed for 1) peak concentrations and arrival times at downstream points of compliance, 2) the area of the aquifer contaminated at or above the drinking water standard (DWS), and 3) the total activity remaining in the domain at the end of the simulation. In addition to this analysis, unit source release simulations from a hypothetical tracer were executed to determine relative travel times from the Central Plateau. The results of this study showed that increases in the upland boundary fluxes 1) had little impact on regional flow directions and 2) accelerated contaminant transport. Although contaminant concentrations have initially increased for the more mobile contaminants (tritium, technetium-99, and iodine-129), the accelerated transport caused dilution and a more rapid decline in concentrations relative to the Base Case (no additional flux). For the low-mobility uranium-238, higher upland fluxes caused increases in concentration, but these concentrations never exceeded the DWS. No significant effects on contaminant concentrations were identified at the Core Zone, Columbia River, or buffer zone area separating these two compliance boundaries. When lateral recharge at the upland boundaries was increased, more mass was transported out of the aquifer and discharged into the Columbia River. These concentrations, however, were diluted with respect to the Base Case, where no potential leakage from the proposed reservoir was considered.

  3. In Situ Reduction of Aquifer Sediments to Create a Permeable Reactive Barrier to Remediate Chromate (CrO4 2-): BenchScale Tests to Determine Barrier Longevity

    SciTech Connect (OSTI)

    Szecsody, Jim E.; Fruchter, Jonathan S.; Vermeul, Vince R.; Williams, Mark D.; Devary, Brooks J.

    2005-01-02

    Laboratory tests were conducted to determine sediment geochemical properties needed to develop a design for implementation of the in-situ oxidation–reduction (redox) manipulation (ISRM) technology for chromate (CrO42–) remediation at a Superfund site and three other sites. A generalized hydrogeologic description of the Superfund site consist of a silty clay upper confining layer to a depth of ~6.71 m, the A1 unit from ~6.71 m to ~8.23 m, the A2 unit from ~8.23 m to ~10.67 m, and the A3 unit from ~10.67 m to ~12.19 m below ground surface. The A/B aquitard was encountered at a depth of ~12.19 m. The A1, A2, and A3 hydrostratigraphic units are all sandy gravels, but with considerable difference in fines content and subsequently, hydraulic conductivity. Hydraulic tests conducted in pilot test site monitoring wells indicate that the A1 unit has a 10 times lower hydraulic conductivity than the A2 unit, while the A3 unit hydraulic conductivity is significantly higher than that observed in the A2 unit (i.e., a trend of increasing permeability with depth). Calculated hydraulic conductivities, based on sieve analysis, show this same spatial trend. Results from a tracer injection test and electromagnetic borehole flow meter tests conducted at the site indicate a relatively high degree of formation heterogeneity. Laboratory experiments showed that chemical reduction yielded a redox capacity (0.26% iron(II)) that falls within the range of values observed in sediments analyzed from sites where field-scale deployment of the ISRM technology is currently in progress or being considered (0.1% Hanford 100D area, 0.24% Ft Lewis, 0.4% Moffett Federal Airfield). There was relatively little spatial variability in reducible iron (Fe) content between the three aquifer units. This mass of reducible Fe represents a sufficient quantity for a treatment zone emplaced to remain anoxic for 430 pore volumes, which would be expected to last tens of years, depending on aquifer flow rates and the concentration of oxidizing species in the groundwater. The geochemical analysis also indicated relatively low spatial variability in reducible Fe content although some depth dependent variability was indicated. Variation in the CrO42– concentration and flow rates between the A1 and A2 aquifer units indicated the necessity for greater reduction in the A2 aquifer unit, in order that both aquifer units prevent offsite CrO42– migration for the same amount of time. Results from these laboratory analyses of sediment core samples are used in conjunction with: (1) site specific geologic information obtained during installation of monitoring wells, (2) results from hydraulic tests conducted at the site, (3) electromagnetic borehole flow meter testing results, (4) results from a conservative tracer injection test, and (5) results of a series of S2O42– injection simulations of the field site, to develop a S2O42– injection strategy for deployment of the ISRM technology at sites to prevent offsite CrO42– migration.

  4. RPSEA Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 1 Figure 2 Crossplot of permeability vs. porosity of the Arbuckle dolomite core samples from Ogallah unit...

  5. Microsoft Word - Rockwood _CFC_ Silver Peak Area Final EA V4...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ...DWWJSPViolations.jsp?tinwsysisnumber296130&tinwsysstcodeNV These violations would not be a result of the encroachment of saline waters into the freshwater aquifer. ...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in Deep Saline Aquifers. Tenney, Craig M. January 2013 Towards First Principles prediction of Voltage ...

  7. Pore Models Track Reactions in Underground Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    extract from saline aquifers deep underground. The goal is to learn what will happen when fluids pass through the material should power plants inject carbon dioxide underground. ...

  8. Categorical Exclusion Determinations: B1.13 | Department of Energy

    Energy Savers [EERE]

    ... Offices(s): Western Area Power Administration June 26, 2012 CX-008439: Categorical Exclusion Determination Modeling Carbon Dioxide Sequestration in Saline Aquifer and Depleted Oil ...

  9. Chapter 7: Advancing Systems and Technologies to Produce Cleaner...

    Energy Savers [EERE]

    ... &D for advanced fossil power generation and carbon capture utilization and storage. ... leaky wells penetrating a deep saline aquifer in a mature sedimentary basin, ...

  10. NERSC-ScienceHighlightSlidesSeptember2010.ppt

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    ... * Quantum leap in supernova understanding. * Suggests that computer power is key limit. ... Nugent, LBNL. Numerical study of density driven flow for CO 2 storage in saline aquifers. ...

  11. 01-2016-2 | netl.doe.gov

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    types of CO2 storage targets (such as, saline aquifers, depleted oil and gas formations). ... from engineered systems, such as power plants or carbon capture facilities, which ...

  12. Search for: All records | SciTech Connect

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    Energy Technology Engineering Center (ETEC), Canoga ... systems (6) tuff (6) water (6) boiling (5) chemical ... and (2) CO2 disposal in a deep saline aquifer. less Full ...

  13. Search for: All records | SciTech Connect

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    ... States) Idaho National Engineering and Environmental ... Water-Steel Canister Interaction and H2 Gas Pressure Buildup ... for COsub 2 disposal in deep saline aquifers (Xu et al., ...

  14. QGESS: CO2 Impurity Design Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Health NOx Oxides of nitrogen SAS Saline aquifer sequestration SCR Selective catalytic reduction TWA Total Weighted Average National Energy Technology Laboratory Office of...

  15. THE OHIO RIVER VALLEY CO2 STORAGE PROJECT - PRELIMINARY ASSESSMENT OF DEEP SALINE RESERVOIRS AND COAL SEAMS

    SciTech Connect (OSTI)

    Michael J. Mudd; Howard Johnson; Charles Christopher; T.S. Ramakrishnan, Ph.D.

    2003-08-01

    This report describes the geologic setting for the Deep Saline Reservoirs and Coal Seams in the Ohio River Valley CO{sub 2} Storage Project area. The object of the current project is to site and design a CO{sub 2} injection facility. A location near New Haven, WV, has been selected for the project. To assess geologic storage reservoirs at the site, regional and site-specific geology were reviewed. Geologic reports, deep well logs, hydraulic tests, and geologic maps were reviewed for the area. Only one well within 25 miles of the site penetrates the deeper sedimentary rocks, so there is a large amount of uncertainty regarding the deep geology at the site. New Haven is located along the Ohio River on the border of West Virginia and Ohio. Topography in the area is flat in the river valley but rugged away from the Ohio River floodplain. The Ohio River Valley incises 50-100 ft into bedrock in the area. The area of interest lies within the Appalachian Plateau, on the western edge of the Appalachian Mountain chain. Within the Appalachian Basin, sedimentary rocks are 3,000 to 20,000 ft deep and slope toward the southeast. The rock formations consist of alternating layers of shale, limestone, dolomite, and sandstone overlying dense metamorphic continental shield rocks. The Rome Trough is the major structural feature in the area, and there may be some faults associated with the trough in the Ohio-West Virginia Hinge Zone. The area has a low earthquake hazard with few historical earthquakes. Target injection reservoirs include the basal sandstone/Lower Maryville and the Rose Run Sandstone. The basal sandstone is an informal name for sandstones that overlie metamorphic shield rock. Regional geology indicates that the unit is at a depth of approximately 9,100 ft below the surface at the project site and associated with the Maryville Formation. Overall thickness appears to be 50-100 ft. The Rose Run Sandstone is another potential reservoir. The unit is located approximately 1,100 ft above the basal sandstone and is 100-200 ft thick. The storage capacity estimates for a 20-mile radius from the injection well ranged from 39-78 million tons (Mt) for each formation. Several other oil and gas plays have hydraulic properties conducive for injection, but the formations are generally only 5-50 ft thick in the study area. Overlying the injection reservoirs are thick sequences of dense, impermeable dolomite, limestone, and shale. These layers provide containment above the potential injection reservoirs. In general, it appears that the containment layers are much thicker and extensive than the injection intervals. Other physical parameters for the study area appear to be typical for the region. Anticipated pressures at maximum depths are approximately 4,100 psi based on a 0.45 psi/ft pressure gradient. Temperatures are likely to be 150 F. Groundwater flow is slow and complex in deep formations. Regional flow directions appear to be toward the west-northwest at less than 1 ft per year within the basal sandstone. Vertical gradients are downward in the study area. A review of brine geochemistry indicates that formation fluids have high salinity and dissolved solids. Total dissolved solids ranges from 200,000-325,000 mg/L in the deep reservoirs. Brine chemistry is similar throughout the different formations, suggesting extensive mixing in a mature basin. Unconsolidated sediments in the Ohio River Valley are the primary source of drinking water in the study area.

  16. Modeling of fate and transport of co-injection of H2S with CO2 in deep saline formations

    SciTech Connect (OSTI)

    Zhang, W.; Xu, T.; Li, Y.

    2010-12-15

    The geological storage of CO{sub 2} in deep saline formations is increasing seen as a viable strategy to reduce the release of greenhouse gases into the atmosphere. However, costs of capture and compression of CO{sub 2} from industrial waste streams containing small quantities of sulfur and nitrogen compounds such as SO{sub 2}, H{sub 2}S and N{sub 2} are very expensive. Therefore, studies on the co-injection of CO{sub 2} containing other acid gases from industrial emissions are very important. In this paper, numerical simulations were performed to study the co-injection of H{sub 2}S with CO{sub 2} in sandstone and carbonate formations. Results indicate that the preferential dissolution of H{sub 2}S gas (compared with CO{sub 2} gas) into formation water results in the delayed breakthrough of H{sub 2}S gas. Co-injection of H{sub 2}S results in the precipitation of pyrite through interactions between the dissolved H{sub 2}S and Fe{sup 2+} from the dissolution of Fe-bearing minerals. Additional injection of H{sub 2}S reduces the capabilities for solubility and mineral trappings of CO{sub 2} compared to the CO{sub 2} only case. In comparison to the sandstone (siliciclastic) formation, the carbonate formation is less favorable to the mineral sequestration of CO{sub 2}. Different from CO{sub 2} mineral trapping, the presence of Fe-bearing siliciclastic and/or carbonate is more favorable to the H{sub 2}S mineral trapping.

  17. Geologic Controls of Hydraulic Conductivity in the Snake River Plain Aquifer At and Near the Idaho National Engineering and Environmental Laboratory, Idaho

    SciTech Connect (OSTI)

    S. R. Anderson; M. A. Kuntz; L. C. Davis

    1999-02-01

    The effective hydraulic conductivity of basalt and interbedded sediment that compose the Snake River Plain aquifer at and near the Idaho National Engineering and Environmental Laboratory (INEEL) ranges from about 1.0x10 -2 to 3.2x10 4 feet per day (ft/d). This six-order-of-magnitude range of hydraulic conductivity was estimated from single-well aquifer tests in 114 wells, and is attributed mainly to the physical characteristics and distribution of basalt flows and dikes. Hydraulic conductivity is greatest in thin pahoehoe flows and near-vent volcanic deposits. Hydraulic conductivity is least in flows and deposits cut by dikes. Estimates of hydraulic conductivity at and near the INEEL are similar to those measured in similar volcanic settings in Hawaii. The largest variety of rock types and the greatest range of hydraulic conductivity are in volcanic rift zones, which are characterized by numerous aligned volcanic vents and fissures related to underlying dikes. Three broad categories of hydraulic conductivity corresponding to six general types of geologic controls can be inferred from the distribution of wells and vent corridors. Hydraulic conductivity of basalt flows probably is increased by localized fissures and coarse mixtures of interbedded sediment, scoria, and basalt rubble. Hydraulic conductivity of basalt flows is decreased locally by abundant alteration minerals of probable hydrothermal origin. Hydraulic conductivity varies as much as six orders of magnitude in a single vent corridor and varies from three to five orders of magnitude within distances of 500 to 1,000 feet. Abrupt changes in hydraulic conductivity over short distances suggest the presence of preferential pathways and local barriers that may greatly affect the movement of ground water and the dispersion of radioactive and chemical wastes downgradient from points of waste disposal.

  18. Predictive modeling of CO{sub 2} sequestration in deep saline sandstone reservoirs: Impacts of geochemical kinetics

    SciTech Connect (OSTI)

    Balashov, Victor N.; Guthrie, George D.; Hakala, J. Alexandra; Lopano, Christina L. J.; Rimstidt, Donald; Brantley, Susan L.

    2013-03-01

    One idea for mitigating the increase in fossil-fuel generated CO{sub 2} in the atmosphere is to inject CO{sub 2} into subsurface saline sandstone reservoirs. To decide whether to try such sequestration at a globally significant scale will require the ability to predict the fate of injected CO{sub 2}. Thus, models are needed to predict the rates and extents of subsurface rock-water-gas interactions. Several reactive transport models for CO{sub 2} sequestration created in the last decade predicted sequestration in sandstone reservoirs of ~17 to ~90 kg CO{sub 2} m{sup -3|. To build confidence in such models, a baseline problem including rock + water chemistry is proposed as the basis for future modeling so that both the models and the parameterizations can be compared systematically. In addition, a reactive diffusion model is used to investigate the fate of injected supercritical CO{sub 2} fluid in the proposed baseline reservoir + brine system. In the baseline problem, injected CO{sub 2} is redistributed from the supercritical (SC) free phase by dissolution into pore brine and by formation of carbonates in the sandstone. The numerical transport model incorporates a full kinetic description of mineral-water reactions under the assumption that transport is by diffusion only. Sensitivity tests were also run to understand which mineral kinetics reactions are important for CO{sub 2} trapping. The diffusion transport model shows that for the first ~20 years after CO{sub 2} diffusion initiates, CO{sub 2} is mostly consumed by dissolution into the brine to form CO{sub 2,aq} (solubility trapping). From 20-200 years, both solubility and mineral trapping are important as calcite precipitation is driven by dissolution of oligoclase. From 200 to 1000 years, mineral trapping is the most important sequestration mechanism, as smectite dissolves and calcite precipitates. Beyond 2000 years, most trapping is due to formation of aqueous HCO{sub 3}{sup -}. Ninety-seven percent of the maximum CO{sub 2} sequestration, 34.5 kg CO{sub 2} per m{sup 3} of sandstone, is attained by 4000 years even though the system does not achieve chemical equilibrium until ~25,000 years. This maximum represents about 20% CO{sub 2} dissolved as CO{sub 2},aq, 50% dissolved as HCO{sub 3}{sup -}{sub ,aq}, and 30% precipitated as calcite. The extent of sequestration as HCO{sub 3}{sup -} at equilibrium can be calculated from equilibrium thermodynamics and is roughly equivalent to the amount of Na+ in the initial sandstone in a soluble mineral (here, oligoclase). Similarly, the extent of trapping in calcite is determined by the amount of Ca2+ in the initial oligoclase and smectite. Sensitivity analyses show that the rate of CO{sub 2} sequestration is sensitive to the mineral-water reaction kinetic constants between approximately 10 and 4000 years. The sensitivity of CO{sub 2} sequestration to the rate constants decreases in magnitude respectively from oligoclase to albite to smectite.

  19. The in-situ decontamination of sand and gravel aquifers by chemically enhanced solubilization of multiple-compound DNAPLs with surfactant solutions: Phase 1 -- Laboratory and pilot field-scale testing and Phase 2 -- Solubilization test and partitioning and interwell tracer tests. Final report

    SciTech Connect (OSTI)

    1997-10-24

    Laboratory, numerical simulation, and field studies have been conducted to assess the potential use of micellar-surfactant solutions to solubilize chlorinated solvents contaminating sand and gravel aquifers. Ninety-nine surfactants were screened for their ability to solubilize trichloroethene (TCE), perchloroethylene (PCE), and carbon tetrachloride (CTET). The field test was conducted in the alluvial aquifer which is located 20 to 30 meters beneath a vapor degreasing operation at Paducah Gaseous Diffusion Plant. This aquifer has become contaminated with TCE due to leakage of perhaps 40,000 liters of TCE, which has generated a plume of dissolved TCE extending throughout an area of approximately 3 km{sup 2} in the aquifer. Most of the TCE is believed to be present in the overlying lacustrine deposits and in the aquifer itself as a dense, non-aqueous phase liquid, or DNAPL. The objective of the field test was to assess the efficacy of the surfactant for in situ TCE solubilization. Although the test demonstrated that sorbitan monooleate was unsuitable as a solubilizer in this aquifer, the single-well test was demonstrated to be a viable method for the in situ testing of surfactants or cosolvents prior to proceeding to full-scale remediation.

  20. Analysis of Hydraulic Responses from the ER-6-1 Multiple-Well Aquifer Test, Yucca Flat FY 2004 Testing Program, Nevada Test Site, Nye County, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Greg Ruskauff

    2005-06-01

    This report documents the interpretation and analysis of the hydraulic data collected for the Fiscal Year (FY) 2004 Multiple-Well Aquifer Test-Tracer Test (MWAT-TT) conducted at the ER-6-1 Well Cluster in Yucca Flat Corrective Action Unit (CAU) 97, on the Nevada Test Site (NTS). The MWAT-TT was performed to investigate CAU-scale groundwater flow and transport processes related to the transport of radionuclides from sources on the NTS through the Lower Carbonate Aquifer (LCA) Hydrostratigraphic Unit (HSU). The ER-6-1 MWAT-TT was planned and executed by contractor participants for the Underground Test Area (UGTA) Project of the Environmental Restoration (ER) program of the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO). Participants included Stoller-Navarro Joint Venture (SNJV), the Environmental Engineering Services Contractor; Bechtel Nevada (BN); the Desert Research Institute (DRI); Los Alamos National Laboratory; and the University of Nevada, Las Vegas-Harry Reid Center. The SNJV team consists of the S.M. Stoller Corporation, Navarro Research and Engineering, Battelle Memorial Institute, INTERA Inc., and Weston Solutions, Inc. The MWAT-TT was implemented according to the ''Underground Test Area Project, ER-6-1 Multi-Well Aquifer Test - Tracer Test Plan'' (SNJV, 2004a) issued in April 2004. The objective of the aquifer test was to determine flow processes and local hydraulic properties for the LCA through long-term constant-rate pumping at the well cluster. This objective was to be achieved in conjunction with detailed sampling of the composite tracer breakthrough at the pumping well, as well as with depth-specific sampling and logging at multiple wells, to provide information for the depth-discrete analysis of formation hydraulic properties, particularly with regard to fracture properties.

  1. Field Test Report: Preliminary Aquifer Test Characterization Results for Well 299-W15-225: Supporting Phase I of the 200-ZP-1 Groundwater Operable Unit Remedial Design

    SciTech Connect (OSTI)

    Spane, Frank A.; Newcomer, Darrell R.

    2009-09-23

    This report examines the hydrologic test results for both local vertical profile characterization and large-scale hydrologic tests associated with a new extraction well (well 299-W15-225) that was constructed during FY2009 for inclusion within the future 200-West Area Groundwater Treatment System that is scheduled to go on-line at the end of FY2011. To facilitate the analysis of the large-scale hydrologic test performed at newly constructed extraction well 299-W15-225 (C7017; also referred to as EW-1 in some planning documents), the existing 200-ZP-1 interim pump-and-treat system was completely shut-down ~1 month before the performance of the large-scale hydrologic test. Specifically, this report 1) applies recently developed methods for removing barometric pressure fluctuations from well water-level measurements to enhance the detection of hydrologic test and pump-and-treat system effects at selected monitor wells, 2) analyzes the barometric-corrected well water-level responses for a preliminary determination of large-scale hydraulic properties, and 3) provides an assessment of the vertical distribution of hydraulic conductivity in the vicinity of newly constructed extraction well 299-W15-225. The hydrologic characterization approach presented in this report is expected to have universal application for meeting the characterization needs at other remedial action sites located within unconfined and confined aquifer systems.

  2. The in-situ decontamination of sand and gravel aquifers by chemically enhanced solubilization of multiple-component DNAPLS with surfactant solutions. Topical report

    SciTech Connect (OSTI)

    1995-01-01

    Laboratory, numerical simulation, and field studies have been conducted to assess the potential use of micellar-surfactant solutions to solubilize chlorinated solvents contaminating sand and gravel aquifers. Laboratory studies were conducted at the State University of New York at Buffalo (SUNY) while numerical simulation and field work were undertaken by INTERA Inc. in collaboration with Martin Marietta Energy Systems Inc. at the Paducah Gaseous Diffusion Plant (PGDP) in Kentucky. Ninety-nine surfactants were screened for their ability to solubilize trichloroethene (TCE), perchloroethylene (PCE), and carbon tetrachloride (CTET). Ten of these were capable of solubilizing TCE to concentrations greater than 15,000 mg/L, compared to its aqueous solubility of 1,100 mg/L. Four surfactants were identified as good solubilizers of all three chlorinated solvents. Of these, a secondary alcohol ethoxylate was the first choice for in situ testing because of its excellent solubilizing ability and its low propensity to sorb. However, this surfactant did not meet the Commonwealth of Kentucky`s acceptance criteria. Consequently, it was decided to use a surfactant approved for use by the Food and Drug Administration as a food-grade additive. As a 1% micellar-surfactant solution, this sorbitan monooleate has a solubilization capacity of 16,000 mg TCE/L, but has a higher propensity to sorb to clays than has the alcohol ethoxylate.

  3. User manual for AQUASTOR: a computer model for cost analysis of aquifer thermal energy storage coupled with district heating or cooling systems. Volume I. Main text

    SciTech Connect (OSTI)

    Huber, H.D.; Brown, D.R.; Reilly, R.W.

    1982-04-01

    A computer model called AQUASTOR was developed for calculating the cost of district heating (cooling) using thermal energy supplied by an aquifer thermal energy storage (ATES) system. The AQUASTOR model can simulate ATES district heating systems using stored hot water or ATES district cooling systems using stored chilled water. AQUASTOR simulates the complete ATES district heating (cooling) system, which consists of two principal parts: the ATES supply system and the district heating (cooling) distribution system. The supply system submodel calculates the life-cycle cost of thermal energy supplied to the distribution system by simulating the technical design and cash flows for the exploration, development, and operation of the ATES supply system. The distribution system submodel calculates the life-cycle cost of heat (chill) delivered by the distribution system to the end-users by simulating the technical design and cash flows for the construction and operation of the distribution system. The model combines the technical characteristics of the supply system and the technical characteristics of the distribution system with financial and tax conditions for the entities operating the two systems into one techno-economic model. This provides the flexibility to individually or collectively evaluate the impact of different economic and technical parameters, assumptions, and uncertainties on the cost of providing district heating (cooling) with an ATES system. This volume contains the main text, including introduction, program description, input data instruction, a description of the output, and Appendix H, which contains the indices for supply input parameters, distribution input parameters, and AQUASTOR subroutines.

  4. Predictions of long-term behavior of a large-volume pilot test for CO2 geological storage in a saline formation in the Central Valley, California

    SciTech Connect (OSTI)

    Doughty, Christine; Myer, Larry R.; Oldenburg, Curtis M.

    2008-11-01

    The long-term behavior of a CO{sub 2} plume injected into a deep saline formation is investigated, focusing on mechanisms that lead to plume stabilization. Key measures are plume migration distance and the time evolution of CO{sub 2} phase-partitioning, which are examined by developing a numerical model of the subsurface at a proposed power plant with CO{sub 2} capture in the San Joaquin Valley, California, where a large-volume pilot test of CO{sub 2} injection will be conducted. The numerical model simulates a four-year CO{sub 2} injection period and the subsequent evolution of the CO{sub 2} plume until it stabilizes. Sensitivity studies are carried out to investigate the effect of poorly constrained model parameters permeability, permeability anisotropy, and residual gas saturation.

  5. Use of environmental sensors and sensor networks to develop water and salinity budgets for seasonal wetland real-time water quality management

    SciTech Connect (OSTI)

    Quinn, N.W.T.; Ortega, R.; Rahilly, P.J.A,; Royer, C.W.

    2009-10-01

    Successful management of river salt loads in complex and highly regulated river basins such as the San Joaquin of California presents significant challenges to Information Technology. Models are used as means of simulating major hydrologic processes in the basin which affect water quality and can be useful as tools for organizing basin information in a structured and readily accessible manner. Models can also be used to extrapolate the results of system monitoring since it is impossible to collect data for every point and non-point source of a pollutant in the Basin. Fundamental to every model is the concept of mass balance. This paper describes the use of state-of-the-art sensor technologies deployed in concert to obtain the first water and salinity budgets for a 60,000 hectare tract of seasonally managed wetlands in the San Joaquin Basin of California.

  6. Long-term Variations of CO2 Trapped in Different Mechanisms in Deep Saline Formations: A Case Study of the Songliao Basin, China

    SciTech Connect (OSTI)

    Zhang, Wei; Li, Yilian; Xu, Tianfu; Cheng, Huilin; Zheng, Yan; Xiong, Peng

    2008-06-10

    The geological storage of CO{sub 2} in deep saline formations is increasing seen as a viable strategy to reduce the release of greenhouse gases to the atmosphere. There are numerous sedimentary basins in China, in which a number of suitable CO{sub 2} geologic reservoirs are potentially available. To identify the multi-phase processes, geochemical changes and mineral alteration, and CO{sub 2} trapping mechanisms after CO{sub 2} injection, reactive geochemical transport simulations using a simple 2D model were performed. Mineralogical composition and water chemistry from a deep saline formation of Songliao Basin were used. Results indicate that different storage forms of CO{sub 2} vary with time. In the CO{sub 2} injection period, a large amount of CO{sub 2} remains as a free supercritical phase (gas trapping), and the amount dissolved in the formation water (solubility trapping) gradually increases. Later, gas trapping decreases, solubility trapping increases significantly due to migration and diffusion of the CO{sub 2} plume, and the amount trapped by carbonate minerals increases gradually with time. The residual CO{sub 2} gas keeps dissolving into groundwater and precipitating carbonate minerals. For the Songliao Basin sandstone, variations in the reaction rate and abundance of chlorite, and plagioclase composition affect significantly the estimates of mineral alteration and CO{sub 2} storage in different trapping mechanisms. The effect of vertical permeability and residual gas saturation on the overall storage is smaller compared to the geochemical factors. However, they can affect the spatial distribution of the injected CO{sub 2} in the formations. The CO{sub 2} mineral trapping capacity could be in the order of ten kilogram per cubic meter medium for the Songliao Basin sandstone, and may be higher depending on the composition of primary aluminosilicate minerals especially the content of Ca, Mg, and Fe.

  7. System-Scale Model of Aquifer, Vadose Zone, and River Interactions for the Hanford 300 Area - Application to Uranium Reactive Transport

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Bacon, Diana H.; Freedman, Vicky L.; Parker, Kyle R.; Waichler, Scott R.; Williams, Mark D.

    2013-10-01

    This report represents a synthesis and integration of basic and applied research into a system-scale model of the Hanford 300 Area groundwater uranium plume, supported by the U.S. Department of Energys Richland Operations (DOE-RL) office. The report integrates research findings and data from DOE Office of Science (DOE-SC), Office of Environmental Management (DOE-EM), and DOE-RL projects, and from the site remediation and closure contractor, Washington Closure Hanford, LLC (WCH). The three-dimensional, system-scale model addresses water flow and reactive transport of uranium for the coupled vadose zone, unconfined aquifer, and Columbia River shoreline of the Hanford 300 Area. The system-scale model of the 300 Area was developed to be a decision-support tool to evaluate processes of the total system affecting the groundwater uranium plume. The model can also be used to address what if questions regarding different remediation endpoints, and to assist in design and evaluation of field remediation efforts. For example, the proposed cleanup plan for the Hanford 300 Area includes removal, treatment, and disposal of contaminated sediments from known waste sites, enhanced attenuation of uranium hot spots in the vadose and periodically rewetted zone, and continued monitoring of groundwater with institutional controls. Illustrative simulations of polyphosphate infiltration were performed to demonstrate the ability of the system-scale model to address these types of questions. The use of this model in conjunction with continued field monitoring is expected to provide a rigorous basis for developing operational strategies for field remediation and for defining defensible remediation endpoints.

  8. Computed solid phases limiting the concentration of dissolved constituents in basalt aquifers of the Columbia Plateau in eastern Washington. Geochemical modeling and nuclide/rock/groundwater interaction studies

    SciTech Connect (OSTI)

    Deutsch, W.J.; Jenne, E.A.; Krupka, K.M.

    1982-08-01

    A speciation-solubility geochemical model, WATEQ2, was used to analyze geographically-diverse, ground-water samples from the aquifers of the Columbia Plateau basalts in eastern Washington. The ground-water samples compute to be at equilibrium with calcite, which provides both a solubility control for dissolved calcium and a pH buffer. Amorphic ferric hydroxide, Fe(OH)/sub 3/(A), is at saturation or modestly oversaturated in the few water samples with measured redox potentials. Most of the ground-water samples compute to be at equilibrium with amorphic silica (glass) and wairakite, a zeolite, and are saturated to oversaturated with respect to allophane, an amorphic aluminosilicate. The water samples are saturated to undersaturated with halloysite, a clay, and are variably oversaturated with regard to other secondary clay minerals. Equilibrium between the ground water and amorphic silica presumably results from the dissolution of the glassy matrix of the basalt. The oversaturation of the clay minerals other than halloysite indicates that their rate of formation lags the dissolution rate of the basaltic glass. The modeling results indicate that metastable amorphic solids limit the concentration of dissolved silicon and suggest the same possibility for aluminum and iron, and that the processes of dissolution of basaltic glass and formation of metastable secondary minerals are continuing even though the basalts are of Miocene age. The computed solubility relations are found to agree with the known assemblages of alteration minerals in the basalt fractures and vesicles. Because the chemical reactivity of the bedrock will influence the transport of solutes in ground water, the observed solubility equilibria are important factors with regard to chemical-retention processes associated with the possible migration of nuclear waste stored in the earth's crust.

  9. User manual for AQUASTOR: a computer model for cost analysis of aquifer thermal-energy storage oupled with district-heating or cooling systems. Volume II. Appendices

    SciTech Connect (OSTI)

    Huber, H.D.; Brown, D.R.; Reilly, R.W.

    1982-04-01

    A computer model called AQUASTOR was developed for calculating the cost of district heating (cooling) using thermal energy supplied by an aquifer thermal energy storage (ATES) system. the AQUASTOR Model can simulate ATES district heating systems using stored hot water or ATES district cooling systems using stored chilled water. AQUASTOR simulates the complete ATES district heating (cooling) system, which consists of two prinicpal parts: the ATES supply system and the district heating (cooling) distribution system. The supply system submodel calculates the life-cycle cost of thermal energy supplied to the distribution system by simulating the technical design and cash flows for the exploration, development, and operation of the ATES supply system. The distribution system submodel calculates the life-cycle cost of heat (chill) delivered by the distribution system to the end-users by simulating the technical design and cash flows for the construction and operation of the distribution system. The model combines the technical characteristics of the supply system and the technical characteristics of the distribution system with financial and tax conditions for the entities operating the two systems into one techno-economic model. This provides the flexibility to individually or collectively evaluate the impact of different economic and technical parameters, assumptions, and uncertainties on the cost of providing district heating (cooling) with an ATES system. This volume contains all the appendices, including supply and distribution system cost equations and models, descriptions of predefined residential districts, key equations for the cooling degree-hour methodology, a listing of the sample case output, and appendix H, which contains the indices for supply input parameters, distribution input parameters, and AQUASTOR subroutines.

  10. Working Gas Capacity of Aquifers

    Gasoline and Diesel Fuel Update (EIA)

    3,274,385 3,074,251 2,818,148 3,701,510 3,585,867 3,100,219 1944-2015 Alaska 7,259 6,523 9,943 2013-2015 Lower 48 States 3,074,251 2,818,148 3,694,251 3,579,344 3,090,276 2011-2015 Alabama 16,740 15,408 23,651 22,968 28,683 29,187 1968-2015 Arkansas 4,368 4,409 2,960 3,964 3,866 2,272 1967-2015 California 203,653 242,477 170,586 268,548 235,181 204,077 1967-2015 Colorado 45,010 48,341 56,525 63,531 70,692 64,053 1967-2015 Connecticut 1973-1996 Delaware 1967-1975 Georgia 1974-1975 Illinois

  11. Groundwater in the Regional Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at...

  12. Natural Gas Aquifers Storage Capacity

    Gasoline and Diesel Fuel Update (EIA)

    2,086 11,809 11,254 9,720 9,459 9,992 1979-2014 Natural Gas Nonassociated, Wet After Lease Separation 12,004 11,704 11,111 9,578 9,322 9,766 1979-2014 Natural Gas Associated-Dissolved, Wet After Lease Separation 82 105 143 142 137 226 1979-2014 Dry Natural Gas 11,457 11,186 10,626 9,200 8,943 9,484 Separation

    2,004 11,704 11,111 9,578 9,322 9,766 1979-2014 Adjustments 263 120 179 49 42 310 1979-2014 Revision Increases 898 1,795 1,695 1,647 2,517 2,021 1979-2014 Revision Decreases 1,125

  13. Microsoft Word - S08542_Aquifer

    Office of Legacy Management (LM)

    ... This will be used to assess the progress of natural flushing ... All applicable requirements will be identified and adhered ... Access Access to tribal land is granted through a ...

  14. Investigation of CO2 plume behavior for a large-scale pilot test of geologic carbon storage in a saline formation

    SciTech Connect (OSTI)

    Doughty, C.

    2009-04-01

    The hydrodynamic behavior of carbon dioxide (CO{sub 2}) injected into a deep saline formation is investigated, focusing on trapping mechanisms that lead to CO{sub 2} plume stabilization. A numerical model of the subsurface at a proposed power plant with CO{sub 2} capture is developed to simulate a planned pilot test, in which 1,000,000 metric tons of CO{sub 2} is injected over a four-year period, and the subsequent evolution of the CO{sub 2} plume for hundreds of years. Key measures are plume migration distance and the time evolution of the partitioning of CO{sub 2} between dissolved, immobile free-phase, and mobile free-phase forms. Model results indicate that the injected CO{sub 2} plume is effectively immobilized at 25 years. At that time, 38% of the CO{sub 2} is in dissolved form, 59% is immobile free phase, and 3% is mobile free phase. The plume footprint is roughly elliptical, and extends much farther up-dip of the injection well than down-dip. The pressure increase extends far beyond the plume footprint, but the pressure response decreases rapidly with distance from the injection well, and decays rapidly in time once injection ceases. Sensitivity studies that were carried out to investigate the effect of poorly constrained model parameters permeability, permeability anisotropy, and residual CO{sub 2} saturation indicate that small changes in properties can have a large impact on plume evolution, causing significant trade-offs between different trapping mechanisms.

  15. Colusa County, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Generation Facilities in Colusa County, California Wadham Energy LP Biomass Facility Williams Biomass Facility Places in Colusa County, California Arbuckle, California Colusa,...

  16. Microsoft Word - NRAP_TRS_III_Mobilization_and_Transport_of_Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... GCS entails storage of CO2 in various geologic features such as deep saline aquifers, ... storage of CO2 collected from power plants (Bachu and Adams, 2003; Godec et al., 2011). ...

  17. CX-008441: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Modeling Carbon Dioxide Sequestration in Saline Aquifer and Depleted Oil Reservoir (Task 17 - Office Work) CX(s) Applied: A9, A11 Date: 06/26/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  18. TYPE REPORT DOCUMENT TITLE HERE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... for CO2 Storage from Coal-fired Power Facilities in the Black Warrior Basin of ... of Kansas Modeling CO2 Sequestration in a Saline Aquifer and Depleted Oil Reservoir to ...

  19. CX-008440: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Modeling Carbon Dioxide Sequestration in Saline Aquifer and Depleted Oil Reservoir (Task 17 - Seismic Survey) CX(s) Applied: B3.1 Date: 06/26/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  20. Microsoft Word - NRAP-TRS-III-004-2013_DevelopSurrogateModelsCO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... S. Injection and storage of CO 2 in deep saline aquifers: analytical solution for CO 2 ... Jared Ciferno Director Office of Coal and Power R&D National Energy Technology Laboratory ...

  1. Microsoft Word - NRAP-TRS-III-004-2014_Acid Gas Interactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... source of CO 2 , and fossil-fueled power plants account for almost half of the ... to inject CO 2 into deep saline aquifers (Hovorka, 2005; Alberta Geological Survey, 2009). ...

  2. Numerical Modeling Studies of The Dissolution-Diffusion-Convection...

    Office of Scientific and Technical Information (OSTI)

    CO2 Storage in Saline Aquifers Citation Details In-Document Search Title: Numerical Modeling Studies of The Dissolution-Diffusion-Convection ProcessDuring CO2 Storage in ...

  3. CX-002612: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Modeling Carbon Dioxide Sequestration in Saline Aquifer and Depleted Oil Reservoir to Evaluate Regional Carbon Dioxide Sequestration Potential of Ozark Plateau Aquifer System, South-Central KansasCX(s) Applied: B3.1, A9Date: 12/11/2009Location(s): Lawrence, KansasOffice(s): Fossil Energy, National Energy Technology Laboratory

  4. CX-002609: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Modeling Carbon Dioxide Sequestration in Saline Aquifer and Depleted Oil Reservoir to Evaluate Regional Carbon Dioxide Sequestration Potential of Ozark Plateau Aquifer System, South-Central KansasCX(s) Applied: B3.1, A9Date: 12/11/2009Location(s): Wichita, KansasOffice(s): Fossil Energy, National Energy Technology Laboratory

  5. Evaluation of Confining Layer Integrity Beneath the South District Wastewater Treatment Plant, Miami-Dade Water and Sewer Department, Dade County, Florida

    SciTech Connect (OSTI)

    Starr, R.C.; Green, T.S.; Hull, L.C.

    2001-02-28

    A review has been performed of existing information that describes geology, hydrogeology, and geochemistry at the South District Wastewater Treatment Plant, which is operated by the Miami-Dade Water and Sewer Department, in Dade County, Florida. Treated sanitary wastewater is injected into a saline aquifer beneath the plant. Detection of contaminants commonly associated with treated sanitary wastewater in the freshwater aquifer that overlies the saline aquifer has indicated a need for a reevaluation of the ability of the confining layer above the saline aquifer to prevent fluid migration into the overlying freshwater aquifer. Review of the available data shows that the geologic data set is not sufficient to demonstrate that a competent confining layer is present between the saline and freshwater aquifers. The hydrogeologic data also do not indicate that a competent confining layer is present. The geochemical data show that the freshwater aquifer is contaminated with treated wastewater, and the spatial patterns of contamination are consistent with upward migration through localized conduits through the Middle Confining Unit, such as leaking wells or natural features. Recommendations for collection and interpretation of additional site characterization data are provided.

  6. Evaluation of Confining Layer Integrity Beneath the South District Wastewater Treatment Plant, Miami-Dade Water and Sewer Department, Dade County, Florida

    SciTech Connect (OSTI)

    Starr, Robert Charles; Green, Timothy Scott; Hull, Laurence Charles

    2001-02-01

    A review has been performed of existing information that describes geology, hydrogeology, and geochemistry at the South District Wastewater Treatment Plant, which is operated by the Miami-Dade Water and Sewer Department, in Dade County, Florida. Treated sanitary wastewater is injected into a saline aquifer beneath the plant. Detection of contaminants commonly associated with treated sanitary wastewater in the freshwater aquifer that overlies the saline aquifer has indicated a need for a reevaluation of the ability of the confining layer above the saline aquifer to prevent fluid migration into the overlying freshwater aquifer. Review of the available data shows that the geologic data set is not sufficient to demonstrate that a competent confining layer is present between the saline and freshwater aquifers. The hydrogeologic data also do not indicate that a competent confining layer is present. The geochemical data show that the freshwater aquifer is contaminated with treated wastewater, and the spatial patterns of contamination are consistent with upward migration through localized conduits through the Middle Confining Unit, such as leaking wells or natural features. Recommendations for collection and interpretation of additional site characterization data are provided.

  7. Regional Analysis And Characterization Of Fractured Aquifers...

    Open Energy Info (EERE)

    become an important source of basic data that can be used to help characterize the nature and extent of hydraulic conductivity in fractured rocks. We plan to continue to...

  8. Water-related Issues Affecting Conventional Oil and Gas Recovery and Potential Oil-Shale Development in the Uinta Basin, Utah

    SciTech Connect (OSTI)

    Michael Vanden Berg; Paul Anderson; Janae Wallace; Craig Morgan; Stephanie Carney

    2012-04-30

    Saline water disposal is one of the most pressing issues with regard to increasing petroleum and natural gas production in the Uinta Basin of northeastern Utah. Conventional oil fields in the basin provide 69 percent of Utah?s total crude oil production and 71 percent of Utah?s total natural gas, the latter of which has increased 208% in the past 10 years. Along with hydrocarbons, wells in the Uinta Basin produce significant quantities of saline water ? nearly 4 million barrels of saline water per month in Uintah County and nearly 2 million barrels per month in Duchesne County. As hydrocarbon production increases, so does saline water production, creating an increased need for economic and environmentally responsible disposal plans. Current water disposal wells are near capacity, and permitting for new wells is being delayed because of a lack of technical data regarding potential disposal aquifers and questions concerning contamination of freshwater sources. Many companies are reluctantly resorting to evaporation ponds as a short-term solution, but these ponds have limited capacity, are prone to leakage, and pose potential risks to birds and other wildlife. Many Uinta Basin operators claim that oil and natural gas production cannot reach its full potential until a suitable, long-term saline water disposal solution is determined. The enclosed project was divided into three parts: 1) re-mapping the base of the moderately saline aquifer in the Uinta Basin, 2) creating a detailed geologic characterization of the Birds Nest aquifer, a potential reservoir for large-scale saline water disposal, and 3) collecting and analyzing water samples from the eastern Uinta Basin to establish baseline water quality. Part 1: Regulators currently stipulate that produced saline water must be disposed of into aquifers that already contain moderately saline water (water that averages at least 10,000 mg/L total dissolved solids). The UGS has re-mapped the moderately saline water boundary in the subsurface of the Uinta Basin using a combination of water chemistry data collected from various sources and by analyzing geophysical well logs. By re-mapping the base of the moderately saline aquifer using more robust data and more sophisticated computer-based mapping techniques, regulators now have the information needed to more expeditiously grant water disposal permits while still protecting freshwater resources. Part 2: Eastern Uinta Basin gas producers have identified the Birds Nest aquifer, located in the Parachute Creek Member of the Green River Formation, as the most promising reservoir suitable for large-volume saline water disposal. This aquifer formed from the dissolution of saline minerals that left behind large open cavities and fractured rock. This new and complete understanding the aquifer?s areal extent, thickness, water chemistry, and relationship to Utah?s vast oil shale resource will help operators and regulators determine safe saline water disposal practices, directly impacting the success of increased hydrocarbon production in the region, while protecting potential future oil shale production. Part 3: In order to establish a baseline of water quality on lands identified by the U.S. Bureau of Land Management as having oil shale development potential in the southeastern Uinta Basin, the UGS collected biannual water samples over a three-year period from near-surface aquifers and surface sites. The near-surface and relatively shallow groundwater quality information will help in the development of environmentally sound water-management solutions for a possible future oil shale and oil sands industry and help assess the sensitivity of the alluvial and near-surface bedrock aquifers. This multifaceted study will provide a better understanding of the aquifers in Utah?s Uinta Basin, giving regulators the tools needed to protect precious freshwater resources while still allowing for increased hydrocarbon production.

  9. Property:SalinityAverage | Open Energy Information

    Open Energy Info (EERE)

    + B Beowawe Hot Springs Geothermal Area + 700 + Blue Mountain Geothermal Area + 4,300 + Brady Hot Springs Geothermal Area + 3,500 + Bruchsal Geothermal Area + 100,000 + C Chena...

  10. Water and gas chemistry from HGP-A geothermal well: January 1980 flow test

    SciTech Connect (OSTI)

    Thomas, D.M.

    1980-09-01

    A two-week production test was conducted on the geothermal well HGP-A. Brine chemistry indicates that approximately six percent of the well fluids are presently derived from seawater and that this fraction will probably increase during continued production. Reservoir production is indicated to be from two chemically distinct aquifers: one having relatively high salinity and low production and the other having lower salinity and producing the bulk of the discharge.

  11. Death Valley Lower Carbonate Aquifer Monitoring Program Wells Down Gradient of the Proposed Yucca Mountain Nuclear Waste Repository, U. S. Department of Energy Grant DE-RW0000233 2010 Project Report, prepared by The Hydrodynamics Group, LLC for Inyo County Yucca Mountain Repository Assessment Office

    SciTech Connect (OSTI)

    King, Michael J; Bredehoeft, John D., Dr.

    2010-09-03

    Inyo County completed the first year of the U.S. Department of Energy Grant Agreement No. DE-RW0000233. This report presents the results of research conducted within this Grant agreement in the context of Inyo County's Yucca Mountain oversight program goals and objectives. The Hydrodynamics Group, LLC prepared this report for Inyo County Yucca Mountain Repository Assessment Office. The overall goal of Inyo County's Yucca Mountain research program is the evaluation of far-field issues related to potential transport, by ground water, of radionuclide into Inyo County, including Death Valley, and the evaluation of a connection between the Lower Carbonate Aquifer (LCA) and the biosphere. Data collected within the Grant is included in interpretive illustrations and discussions of the results of our analysis. The centeral elements of this Grant prgoram was the drilling of exploratory wells, geophysical surveys, geological mapping of the Southern Funeral Mountain Range. The cullimination of this research was 1) a numerical ground water model of the Southern Funeral Mountain Range demonstrating the potential of a hydraulic connection between the LCA and the major springs in the Furnace Creek area of Death Valley, and 2) a numerical ground water model of the Amargosa Valley to evaluate the potential for radionuclide transport from Yucca Mountain to Inyo County, California. The report provides a description of research and activities performed by The Hydrodynamics Group, LLC on behalf of Inyo County, and copies of key work products in attachments to this report.

  12. CX-008439: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Modeling Carbon Dioxide Sequestration in Saline Aquifer and Depleted Oil Reservoir (Task 17 - Borehole) CX(s) Applied: A9, B1.13, B3.1, B3.7 Date: 06/26/2012 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  13. Simulation of CO2 Sequestration at Rock Spring Uplift, Wyoming: Heterogeneity and Uncertainties in Storage Capacity, Injectivity and Leakage

    SciTech Connect (OSTI)

    Deng, Hailin; Dai, Zhenxue; Jiao, Zunsheng; Stauffer, Philip H.; Surdam, Ronald C.

    2011-01-01

    Many geological, geochemical, geomechanical and hydrogeological factors control CO{sub 2} storage in subsurface. Among them heterogeneity in saline aquifer can seriously influence design of injection wells, CO{sub 2} injection rate, CO{sub 2} plume migration, storage capacity, and potential leakage and risk assessment. This study applies indicator geostatistics, transition probability and Markov chain model at the Rock Springs Uplift, Wyoming generating facies-based heterogeneous fields for porosity and permeability in target saline aquifer (Pennsylvanian Weber sandstone) and surrounding rocks (Phosphoria, Madison and cap-rock Chugwater). A multiphase flow simulator FEHM is then used to model injection of CO{sub 2} into the target saline aquifer involving field-scale heterogeneity. The results reveal that (1) CO{sub 2} injection rates in different injection wells significantly change with local permeability distributions; (2) brine production rates in different pumping wells are also significantly impacted by the spatial heterogeneity in permeability; (3) liquid pressure evolution during and after CO{sub 2} injection in saline aquifer varies greatly for different realizations of random permeability fields, and this has potential important effects on hydraulic fracturing of the reservoir rock, reactivation of pre-existing faults and the integrity of the cap-rock; (4) CO{sub 2} storage capacity estimate for Rock Springs Uplift is 6614 {+-} 256 Mt at 95% confidence interval, which is about 36% of previous estimate based on homogeneous and isotropic storage formation; (5) density profiles show that the density of injected CO{sub 2} below 3 km is close to that of the ambient brine with given geothermal gradient and brine concentration, which indicates CO{sub 2} plume can sink to the deep before reaching thermal equilibrium with brine. Finally, we present uncertainty analysis of CO{sub 2} leakage into overlying formations due to heterogeneity in both the target saline aquifer and surrounding formations. This uncertainty in leakage will be used to feed into risk assessment modeling.

  14. Number of Existing Natural Gas Aquifers Storage Fields

    Gasoline and Diesel Fuel Update (EIA)

    Indiana 12 13 13 12 12 12 1999-2014 Iowa 4 4 4 4 4 4 1999-2014 Kentucky 3 3 3 3 3 2 1999-2014 Michigan 0 0 1999-2014 Minnesota 1 1 1 1 1 1 1999-2014 Missouri 1 1 1 1 1 1 1999-2014 ...

  15. Underground Thermal Energy Storage (UTES) Via Borehole and Aquifer...

    Office of Environmental Management (EM)

    Monitoring Well Piping Submersible Pump Intake Filter Screen with "Gravel" Pack Injection Valve -Anoxic -Sand&clay free -Keep CO2 in Solution -Min.drawdown & mounding Geophysical ...

  16. Enhancement of in situ microbial remediation of aquifers

    DOE Patents [OSTI]

    Fredrickson, J.K.; Brockman, F.J.; Streile, G.P.; Cary, J.W.; McBride, J.F.

    1993-11-30

    Methods are provided for remediating subsurface areas contaminated by toxic organic compounds. An innocuous oil, such as vegetable oil, mineral oil, or other immiscible organic liquid, is introduced into the contaminated area and permitted to move therethrough. The oil concentrates or strips the organic contaminants, such that the concentration of the contaminants is reduced and such contaminants are available to be either pumped out of the subsurface area or metabolized by microorganisms. Microorganisms may be introduced into the contaminated area to effect bioremediation of the contamination. The methods may be adapted to deliver microorganisms, enzymes, nutrients and electron donors to subsurface zones contaminated by nitrate in order to stimulate or enhance denitrification. 4 figures.

  17. Numerical Simulation of Reactive Flow in Hot Aquifers (Journal...

    Office of Scientific and Technical Information (OSTI)

    98 Report Number(s): LBNL--55513 Journal ID: ISSN 0375-6505; GTMCAT; R&D Project: G31902; TRN: US200430%%2076

  18. Numerical Simulation of Reactive Flow in Hot Aquifers (Journal...

    Office of Scientific and Technical Information (OSTI)

    69 Report Number(s): LBNL--55513 Journal ID: ISSN 0375-6505; GTMCAT; R&D Project: G31902; TRN: US200430%%2053

  19. On parameterization of the inverse problem for estimating aquifer...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Science (SC) Country of Publication: United States Language: English Subject: 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES Word Cloud More Like This ...

  20. On parameterization of the inverse problem for estimating aquifer...

    Office of Scientific and Technical Information (OSTI)

    Authors: Kowalsky, M. B. ; Finsterle, S. ; Commer, M. ; Williams, K. H. ; Murray, C. ; Newcomer, D. ; Englert, A. ; Steefel, C. I. ; Hubbard, S. S. Publication Date: 2012-01-01 ...

  1. Enhancement of in situ microbial remediation of aquifers

    DOE Patents [OSTI]

    Fredrickson, James K. (Kennewick, WA); Brockman, Fred J. (Kennewick, WA); Streile, Gary P. (both or Richland, WA); Cary, John W. (both or Richland, WA); McBride, John F. (Carrboro, NC)

    1993-01-01

    Methods are provided for remediating subsurface areas contaminated by toxic organic compounds. An innocuous oil, such as vegetable oil, mineral oil, or other immiscible organic liquid, is introduced into the contaminated area and permitted to move therethrough. The oil concentrates or strips the organic contaminants, such that the concentration of the contaminants is reduced and such contaminants are available to be either pumped out of the subsurface area or metabolized by microorganisms. Microorganisms may be introduced into the contaminated area to effect bioremediation of the contamination. The methods may be adapted to deliver microorganisms, enzymes, nutrients and electron donors to subsurface zones contaminated by nitrate in order to stimulate or enhance denitrification.

  2. The INL and the Snake River Plain Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recent monitoring by the U.S. Geological Survey, Idaho Department of Environmental ... Previous monitoring at the INL did not allow for collection of samples at the depths these ...

  3. Accidental Gas Emission From Shallow Pressurized Aquifers At...

    Open Energy Info (EERE)

    are characteristic of the potassic Roman Comagmatic Province and reflect a deep involvement of crustal material in the magma genesis. The lack of high temperature fumaroles...

  4. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins...

    Office of Scientific and Technical Information (OSTI)

    future increase in industrial efforts at CO2 storage in Colorado sedimentary basins. ... As a more sustainable energy industry is becoming a global priority, it is imperative to ...

  5. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins...

    Office of Scientific and Technical Information (OSTI)

    Applied Studies in Reservoir Assessment and Dynamic Processes Affecting Industrial ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  6. co2-saline-storage | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for 2-D seismic, 3-D seismic, vertical seismic profiling, crosswell seismic and microseismic technologies. Which Reservoir for Low Cost Capture, Transportation, and Storage? -...

  7. USD 307 Ell-Saline Wind Project | Open Energy Information

    Open Energy Info (EERE)

    - Yankton School District Wind Project

  8. Saline County, Missouri: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Malta Bend, Missouri Marshall, Missouri Miami, Missouri Mount Leonard, Missouri Nelson, Missouri Slater, Missouri Sweet Springs, Missouri Retrieved from "http:...

  9. Saline County, Kansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Kansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 38.8174853, -97.6982272 Show Map Loading map... "minzoom":false,"mappingservice":"googl...

  10. CO2 flood tests on whole core samples of the Mt. Simon sandstone, Illinois Basin

    SciTech Connect (OSTI)

    O'Connor, William K.; Rush, Gilbert E.

    2005-09-01

    Geological sequestration of CO2, whether by enhanced oil recovery (EOR), coal-bed methane (CBM) recovery, or saline aquifer injection is a promising near-term sequestration methodology. While tremendous experience exists for EOR, and CBM recovery has been demonstrated in existing fields, saline aquifer injection studies have only recently been initiated. Studies evaluating the availability of saline aquifers suitable for CO2 injection show great potential, however, the long-term fate of the CO2 injected into these ancient aqueous systems is still uncertain. For the subject study, a series of laboratory-scale CO2 flood tests were conducted on whole core samples of the Mt. Simon sandstone from the Illinois Basin. By conducting these tests on whole core samples rather than crushed core, an evaluation of the impact of the CO2 flood on the rock mechanics properties as well as the geochemistry of the core and brine solution has been possible. This empirical data could provide a valuable resource for the validation of reservoir models under development for these engineered CO2 systems.

  11. CX-010629: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Characterization of Sites for Near Miscible Carbon Dioxide Applications to Improve Oil Recovery in Arbuckle Reser CX(s) Applied: A9, B3.1, B3.6 Date: 07/09/2013 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  12. CX-010628: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Characterization of Sites for Near Miscible Carbon Dioxide Applications to Improve Oil Recovery in Arbuckle... CX(s) Applied: A9, B3.6, B4.4 Date: 07/09/2013 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  13. Climate change: Effects on reef island resources

    SciTech Connect (OSTI)

    Oberdorfer, J.A.; Buddemeier, R.W.

    1988-06-27

    The salinity, depth, quantity, and reliability of fresh groundwater resources on coral reef islands and coastlines are environmentally important parameters. Groundwater influences or controls the terrestrial flora, salinity, and nutrient levels in the near-shore benthic environment, the rate and nature of sediment diagenesis, and the density of human habitation. Data from a number of Indo-Pacific reef islands suggest that freshwater inventory is a function of rainfall and island dimensions. A numerical model (SUTRA) has been used to simulate the responses of atoll island groundwater to changes in recharge (precipitation), sea level, and loss of island area due to flooding. The model has been calibrated for Enjebi Island, Enewetak Atoll, where a moderately permeable, water-table aquifer overlies a high-permeability formation. Total freshwater inventory is a monotonic but nonlinear function of recharge. If recharge and island area are constant, rising sea level increases the inventory of fresh water by increasing the useful volume of the aquifer above the high-permeability zone. Flooding of land area reduces the total freshwater inventory approximately in proportion to the loss of recharge area. The most significant results of the model simulation, however, are the findings that the inventory of low-salinity water (and by extrapolation, potable water) is disproportionately sensitive to changes in recharge, island dimensions, or recharge. Island freshwater resources may therefore be unexpectedly vulnerable to climate change.

  14. Laboratory studies evaluating CO2 flood impact on the geomechanics of whole core samples

    SciTech Connect (OSTI)

    O'Connor, William K.

    2005-06-01

    Geological sequestration of CO2, whether by enhanced oil recovery (EOR), coal-bed methane (CBM) recovery, or saline aquifer injection is a promising near-term sequestration methodology. While tremendous experience exists for EOR, and CBM recovery has been demonstrated in existing fields, saline aquifer injection studies have only recently been initiated. Studies evaluating the availability of saline aquifers suitable for CO2 injection show great potential, however, the long-term fate of the injected CO2 in these ancient aqueous systems is still uncertain. Migration of the CO2 beyond the natural reservoir seals could become problematic, thus the identification of means to enhance the natural seals may help lead to the utilization of this sequestration methodology. Co-injection of a mineral reactant slurry, either with the CO2 or in separate, secondary injection wells, could provide a means to enhance the natural reservoir seals by providing the necessary cations for precipitation of mineral carbonates along the periphery of the injection plume. The subject study evaluates the merit of several mineral slurry co-injection strategies, by conduct of a series of laboratory-scale CO2 flood tests on whole core samples of the Mt. Simon sandstone from the Illinois Basin. By conducting these tests on whole core samples rather than crushed core, an evaluation of the impact of the CO2 flood on the rock mechanics properties as well as the geochemistry of the core and brine solution has been possible. This empirical data could provide a valuable resource for the validation of reservoir models under development for these engineered CO2 systems.

  15. Uranium Geochemistry in Vadose Zone and Aquifer Sediments from the 300 Area Uranium Plume

    SciTech Connect (OSTI)

    Zachara, John M.; Davis, Jim A.; Liu, Chongxuan; McKinley, James P.; Qafoku, Nik; Wellman, Dawn M.; Yabusaki, Steven B.

    2005-07-21

    This report documents research conducted by the RCS Project to update the record of decision for the 300-FF-5 Operable Unit on the Hanford Site.

  16. Analysis of Mineral Trapping for CO2 Disposal in Deep Aquifers

    Office of Scientific and Technical Information (OSTI)

    ... Porosity and permeability change ......12 3.2 Geochemical system ......While neither class of feldspar is thermodynamically stable ...

  17. Description of Rhodanobacter denitrificans sp. nov., isolated from nitrate-rich zones of a contaminated aquifer

    SciTech Connect (OSTI)

    Prakash, Om; Green, Stefan; Jasrotia, Puja; Overholt, Will; Canion, Andy; Watson, David B; Brooks, Scott C; Kostka,

    2012-01-01

    Bacterial strains 2APBS1T and 116-2 were isolated from the subsurface of a nuclear legacy waste site where sediments are co-contaminated with large amounts of acidity, nitrate, metal radionuclides and other heavy metals. A combination of physiological and genetic assays indicated that these strains represent the first members of the Rhodanobacter genus shown to be capable of complete denitrification. Cells of strain 2APBS1T and 116-2 were Gram negative, non-spore-forming, rods, 3-5 micro;m long and 0.25-0.5 m in diameter. The isolates were facultative anaerobes, and had temperature and pH optima for growth at 30 C and pH 6.5, respectively, and could tolerate up to 2.0 % NaCl, though growth improved in its absence. Strains 2APBS1T and 116-2 contained fatty acid profiles and 100 % Q-8 ubiquinone, that are characteristic features of the genus Rhodanobacter. Although strains 2APBS1T and 116-2 share high SSU rRNA gene sequence similarity to R. thiooxydans (>99%), DNA-DNA hybridization values were substantially below the 70% threshold used to designate novel species. Thus, based on genotypic, phylogenetic, chemotaxonomic and physiological differences, strains 2APBS1T and 116-2 are considered to represent a novel species of the genus Rhodanobacter, for which the name Rhodanobacter denitrificans sp. nov is proposed. The type strain is 2APBS1T (=DSM 23569T =JCM 17641T). Strain 116-2 (=DSM 24678 = JCM 17642) is a reference strain.

  18. Applied Studies and Technology: The Third Dimension—Variation in Groundwater Aquifers

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy Office of Legacy Management (LM) collects groundwater samples at a number of the 90 sites we manage. Some samples are taken solely to help us better understand the...

  19. Ground-Water Table and Chemical Changes in an Alluvial Aquifer During

    Energy Savers [EERE]

    Ground Source Heat Pump System Data Analysis Ground Source Heat Pump System Data Analysis Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech16_liu_040313.pdf More Documents & Publications Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Advanced Ground Source Heat Pump Technology for Very-Low-Energy Buildings Oak Ridge City Center

  20. Method and system for extraction of chemicals from aquifer remediation effluent water

    DOE Patents [OSTI]

    McMurtrey, Ryan D. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID); Moor, Kenneth S. (Idaho Falls, ID); Shook, G. Michael (Idaho Falls, ID); Barker, Donna L. (Idaho Falls, ID)

    2003-01-01

    A method and system for extraction of chemicals from an groundwater remediation aqueous effluent are provided. The extraction method utilizes a critical fluid for separation and recovery of chemicals employed in remediating groundwater contaminated with hazardous organic substances, and is particularly suited for separation and recovery of organic contaminants and process chemicals used in surfactant-based remediation technologies. The extraction method separates and recovers high-value chemicals from the remediation effluent and minimizes the volume of generated hazardous waste. The recovered chemicals can be recycled to the remediation process or stored for later use.

  1. 40 Years Of Dogger Aquifer Management In Ile-De-France, Paris...

    Open Energy Info (EERE)

    in the Paris Basin for more than 40 years. The most serious difficulties have been corrosion and scaling related problems that occurred in many geothermal loops in the...

  2. Tensiometer for shallow or deep measurements including vadose zone and aquifers

    DOE Patents [OSTI]

    Faybishenko, B.

    1999-08-24

    A two cell tensiometer is described in which water level in the lower cell is maintained at a relatively constant height, and in equilibrium with the water pressure of materials that surround the tensiometer. An isolated volume of air in the lower cell changes pressure proportionately to the changing water pressure of the materials that surround the tensiometer. The air pressure is measured remotely. The tensiometer can be used in drying as well as wetting cycles above and below the water table. 8 figs.

  3. Sleuthing the Fate of Water in Ancient Aquifers and Ice Cores...

    Office of Science (SC) Website

    ... When combined with other tracers, 85Kr measurements will improve the quality and reliability of groundwater flow and vulnerability assessments. A systematic survey of 39Ar ...

  4. Revised Hydrogeology for the Suprabasalt Aquifer System, 200-West Area and Vicinity, Hanford Site, Washington

    SciTech Connect (OSTI)

    Williams, Bruce A.; Bjornstad, Bruce N.; Schalla, Ronald; Webber, William D.

    2002-05-14

    The primary objective of this study was to refine the conceptual groundwater flow model for the 200-West Area and vicinity. This is the second of two reports that combine to cover the 200 Area Plateau, an area that holds the largest inventory of radionuclide and chemical waste on the Hanford Site.

  5. BPA, electric co-op and irrigation district testing aquifer recharge

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    during future incidents of springtime electricity oversupply. The pilot allows SWID to pump water from the Snake River for a longer period in the shoulder months of March and...

  6. Grouting project to protect Snake River Plain Aquifer completed ahead of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Business Forum & Expo | Department of Energy Group14 Engineering, Inc., Wins DOE Protege of the Year Award at the Small Business Forum & Expo Group14 Engineering, Inc., Wins DOE Protege of the Year Award at the Small Business Forum & Expo October 10, 2014 - 10:20am Addthis Sue Reilly, President of Group14 Engineering, Inc., accepted the award for DOE Protege of the Year at the Small Business Forum & Expo from Kevin Knobloch, DOE Chief of Staff (l), and John Hale III, Director

  7. Tensiometer for shallow or deep measurements including vadose zone and aquifers

    DOE Patents [OSTI]

    Faybishenko, Boris

    1999-01-01

    A two cell tensiometer is described in which water level in the lower cell is maintained at a relatively constant height, and in equilibrium with the water pressure of materials that surround the tensiometer. An isolated volume of air in the lower cell changes pressure proportionately to the changing water pressure of the materials that surround the tensiometer. The air pressure is measured remotely. The tensiometer can be used in drying as well as wetting cycles above and below the water table.

  8. Chickasaw National Recreational Area, Chickasaw, Oklahoma | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Chickasaw National Recreational Area, Chickasaw, Oklahoma Chickasaw National Recreational Area, Chickasaw, Oklahoma Photo of Comfort Station at the Chickasaw National Recreation Area The Chickasaw National Recreation Area is located 100 miles south of Oklahoma City, Oklahoma, on the Lake of the Arbuckles. To save taxpayers' money and minimize adverse impacts on the environment, the National Park Service (NPS) incorporated solar energy into the design of three new comfort stations. The

  9. Chief Information Officer (WFP) | Department of Energy

    Energy Savers [EERE]

    Energy Chickasaw National Recreational Area, Chickasaw, Oklahoma Chickasaw National Recreational Area, Chickasaw, Oklahoma Photo of Comfort Station at the Chickasaw National Recreation Area The Chickasaw National Recreation Area is located 100 miles south of Oklahoma City, Oklahoma, on the Lake of the Arbuckles. To save taxpayers' money and minimize adverse impacts on the environment, the National Park Service (NPS) recently incorporated solar energy into the design of three new comfort

  10. Applications of carbon dioxide capture and storage technologies in reducing emissions from fossil-fired power plants

    SciTech Connect (OSTI)

    Balat, M.; Balat, H.; Oz, C.

    2009-07-01

    The aim of this paper is to investigate the global contribution of carbon capture and storage technologies to mitigating climate change. Carbon capture and storage is a technology that comprises the separation of from carbon dioxide industrial- and energy-related sources, transport to a storage location (e.g., saline aquifers and depleted hydrocarbon fields), and long-term isolation from the atmosphere. The carbon dioxides emitted directly at the power stations are reduced by 80 to 90%. In contrast, the life cycle assessment shows substantially lower reductions of greenhouse gases in total (minus 65 to 79%).

  11. EA-1835: Midwest Regional Carbon Sequestration Partnership (MRCSP) Phase II Michigan Basin Project in Chester Township, Michigan

    Broader source: Energy.gov [DOE]

    NOTE: This EA has been cancelled. This EA will evaluate the environmental impacts of a proposal to provide approximately $65.5 million in financial assistance in a cost-sharing arrangement with the project proponent, MRCSP. MRCSP's proposed project would use CO2 captured from an existing natural gas processing plant in Chester Township, pipe it approximately 1 mile to an injection well, and inject it into a deep saline aquifer for geologic sequestration. This project would demonstrate the geologic sequestration of 1,000,000 metric tons of CO2 over a 4-year period. The project and EA are on hold.

  12. An Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins: Part 1: Evaluation of Phase 2 CO{sub 2} Injection Testing in the Deep Saline Gunter Sandstone Reservoir (Cambro-Ordovician Knox Group), Marvin Blan No. 1 Hancock County, Kentucky Part 2: Time-lapse Three-Dimensional Vertical Seismic Profile (3D-VSP) of Sequestration Target Interval with Injected Fluids

    SciTech Connect (OSTI)

    Richard Bowersox; John Hickman; Hannes Leetaru

    2012-12-01

    Part 1 of this report focuses on results of the western Kentucky carbon storage test, and provides a basis for evaluating injection and storage of supercritical CO{sub 2} in Cambro-Ordovician carbonate reservoirs throughout the U.S. Midcontinent. This test demonstrated that the Cambro- Ordovician Knox Group, including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite in stratigraphic succession from shallowest to deepest, had reservoir properties suitable for supercritical CO{sub 2} storage in a deep saline reservoir hosted in carbonate rocks, and that strata with properties sufficient for long-term confinement of supercritical CO{sub 2} were present in the deep subsurface. Injection testing with brine and CO{sub 2} was completed in two phases. The first phase, a joint project by the Kentucky Geological Survey and the Western Kentucky Carbon Storage Foundation, drilled the Marvin Blan No. 1 carbon storage research well and tested the entire Knox Group section in the open borehole â?? including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite â?? at 1152â??2255 m, below casing cemented at 1116 m. During Phase 1 injection testing, most of the 297 tonnes of supercritical CO{sub 2} was displaced into porous and permeable sections of the lowermost Beekmantown below 1463 m and Gunter. The wellbore was then temporarily abandoned with a retrievable bridge plug in casing at 1105 m and two downhole pressure-temperature monitoring gauges below the bridge plug pending subsequent testing. Pressure and temperature data were recorded every minute for slightly more than a year, providing a unique record of subsurface reservoir conditions in the Knox. In contrast, Phase 2 testing, this study, tested a mechanically-isolated dolomitic-sandstone interval in the Gunter. Operations in the Phase 2 testing program commenced with retrieval of the bridge plug and long-term pressure gauges, followed by mechanical isolation of the Gunter by plugging the wellbore with cement below the injection zone at 1605.7 m, then cementing a section of a 14-cm casing at 1470.4â??1535.6. The resultant 70.1-m test interval at 1535.6â??1605.7 m included nearly all of the Gunter sandstone facies. During the Phase 2 injection, 333 tonnes of CO{sub 2} were injected into the thick, lower sand section in the sandy member of the Gunter. Following the completion of testing, the injection zone below casing at 1116 m in the Marvin Blan No. 1 well, and wellbore below 305 m was permanently abandoned with cement plugs and the wellsite reclaimed. The range of most-likely storage capacities found in the Knox in the Marvin Blan No. 1 is 1000 tonnes per surface hectare in the Phase 2 Gunter interval to 8685 tonnes per surface hectare if the entire Knox section were available including the fractured interval near the base of the Copper Ridge. By itself the Gunter lacks sufficient reservoir volume to be considered for CO{sub 2} storage, although it may provide up to 18% of the reservoir volume available in the Knox. Regional extrapolation of CO{sub 2} storage potential based on the results of a single well test can be problematic, although indirect evidence of porosity and permeability can be demonstrated in the form of active saltwater-disposal wells injecting into the Knox. The western Kentucky region suitable for CO{sub 2} storage in the Knox is limited updip, to the east and south, by the depth at which the base of the Maquoketa shale lies above the depth required to ensure storage of CO{sub 2} in its supercritical state and the deepest a commercial well might be drilled for CO{sub 2} storage. The resulting prospective region has an area of approximately 15,600 km{sup 2}, beyond which it is unlikely that suitable Knox reservoirs may be developed. Faults in the subsurface, which serve as conduits for CO{sub 2} migration and compromise sealing strata, may mitigate the area with Knox reservoirs suitable for CO{sub 2} storage. The results of the injection tests in the Marvin Blan No. 1, however, provide a basis for evaluating supercritical CO{sub 2} storage in Cambro-Ordovician carbonate reservoirs throughout the Midcontinent. Reservoir seals were evaluated in the Knox and overlying strata. Within the Knox, permeabilities measured in vertical core plugs from the Beekmantown and Copper Ridge suggest that intraformational seals may problematic. Three stratigraphic intervals overlying the Knox in the Marvin Blan No. 1 well may provide seals for potential CO{sub 2} storage reservoirs in western Kentucky: Dutchtown Limestone, Black River Group, and Maquoketa Shale. The Dutchtown and Black River had permeabilities suggest that these intervals may act as secondary sealing strata. The primary reservoir seal for the Knox, however, is the Maquoketa. Maximum seal capacity calculated from permeabilities measured in vertical core plugs from the Maquoketa exceeded the net reservoir height in the Knox by about two orders of magnitude. Rock strength measured in core plugs from the Maquoketa suggest that it is unlikely that any CO{sub 2} migrating from the Knox would have sufficient pressure to fracture the Maquoketa. Part 2 of this report reviews the results of vertical seismic profiling in the Marvin Blan No. 1 well to model post-injection CO{sub 2} plume migration. Two three-dimensional vertical seismic profiles (3D-VSPâ??s) were acquired at the Kentucky Geological Survey Marvin Blan No. 1 CO{sub 2} sequestration research well, Hancock County, Kentucky. The initial (pre-injection) survey was performed on September 15â??16, 2010. This was followed by the injection of 333 tonnes of supercritical CO{sub 2} and then 584 m3 of 2% KCl water (to displace the remaining CO{sub 2} in the wellbore) on September 22, 2010. After injection, the well was shut in with a downhole pressure of 17.5 MPa at the injected reservoir depth of 1545.3 m. The second 3D-VSP was acquired on September 25â??26, 2010. These two 3D-VSP's were combined to produce a time-lapse 3D-VSP data volume in an attempt to monitor and image the subsurface changes caused by the injection. Less than optimum surface access and ambient subsurface noise from a nearby active petroleum pipeline hampered quality of the data, resulting in the inability to image the CO{sub 2} plume in the subsurface. However, some changes in the seismic response post-injection (both wavelet character and an apparent seismic "pull-down" within the injection zone) are interpreted to be a result of the injection process and imply that the technique could still be valid under different circumstances.

  13. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, Robert; Lu, Peng; Allen, Douglas; Soong, Yee; Hedges, Sheila; Fu, Jaw K.; Dobbs, Charles L.; Degalbo, Angelo; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20 C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  14. Inventory of Sources of Available Saline Waters for Microalgae Mass Culture in the State of Arizona

    SciTech Connect (OSTI)

    Wilson, L. G.; Olson, K. L.; Wallace, M. G.; Osborn, M. D.

    1986-06-25

    The Solar Energy Research Institute (SERI) is conducting research on the development of microalgae biomass systems for the production of liquid fuels. Particularly appealing at this time, is the idea of using indigenous resources of the Southwest for large-scale production of microalgae.

  15. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, Robert; Lu, Peng; Allen, Douglas; Soong, Yee; Hedges, Sheila; Fu, Jaw K.; Dobbs, Charles L.; Degalbo, Angelo; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20º C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  16. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, R.M.; Lu, Peng; Allen, D.E.; Soong, Yee; Hedges, S.W.; Fu, J.K.; Dobbs, C.L.; DeGalbo, A.D.; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20 °C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  17. Multimodel Predictive System for Carbon Dioxide Solubility in Saline Formation Waters

    SciTech Connect (OSTI)

    Wang, Zan; Small, Mitchell J.; Karamalidis, Athanasios K.

    2013-02-05

    The prediction of carbon dioxide solubility in brine at conditions relevant to carbon sequestration (i.e., high temperature, pressure, and salt concentration (T-P-X)) is crucial when this technology is applied. Eleven mathematical models for predicting CO{sub 2} solubility in brine are compared and considered for inclusion in a multimodel predictive system. Model goodness of fit is evaluated over the temperature range 304433 K, pressure range 74500 bar, and salt concentration range 07 m (NaCl equivalent), using 173 published CO{sub 2} solubility measurements, particularly selected for those conditions. The performance of each model is assessed using various statistical methods, including the Akaike Information Criterion (AIC) and the Bayesian Information Criterion (BIC). Different models emerge as best fits for different subranges of the input conditions. A classification tree is generated using machine learning methods to predict the best-performing model under different T-P-X subranges, allowing development of a multimodel predictive system (MMoPS) that selects and applies the model expected to yield the most accurate CO{sub 2} solubility prediction. Statistical analysis of the MMoPS predictions, including a stratified 5-fold cross validation, shows that MMoPS outperforms each individual model and increases the overall accuracy of CO{sub 2} solubility prediction across the range of T-P-X conditions likely to be encountered in carbon sequestration applications.

  18. Heat extraction from salinity-gradient solar ponds using heat pipe heat exchangers

    SciTech Connect (OSTI)

    Tundee, Sura; Terdtoon, Pradit; Sakulchangsatjatai, Phrut; Singh, Randeep; Akbarzadeh, Aliakbar

    2010-09-15

    This paper presents the results of experimental and theoretical analysis on the heat extraction process from solar pond by using the heat pipe heat exchanger. In order to conduct research work, a small scale experimental solar pond with an area of 7.0 m{sup 2} and a depth of 1.5 m was built at Khon Kaen in North-Eastern Thailand (16 27'N102 E). Heat was successfully extracted from the lower convective zone (LCZ) of the solar pond by using a heat pipe heat exchanger made from 60 copper tubes with 21 mm inside diameter and 22 mm outside diameter. The length of the evaporator and condenser section was 800 mm and 200 mm respectively. R134a was used as the heat transfer fluid in the experiment. The theoretical model was formulated for the solar pond heat extraction on the basis of the energy conservation equations and by using the solar radiation data for the above location. Numerical methods were used to solve the modeling equations. In the analysis, the performance of heat exchanger is investigated by varying the velocity of inlet air used to extract heat from the condenser end of the heat pipe heat exchanger (HPHE). Air velocity was found to have a significant influence on the effectiveness of heat pipe heat exchanger. In the present investigation, there was an increase in effectiveness by 43% as the air velocity was decreased from 5 m/s to 1 m/s. The results obtained from the theoretical model showed good agreement with the experimental data. (author)

  19. Collection and Characterization of Saline Microalgae From South Florida: Final Report, May 1986

    SciTech Connect (OSTI)

    Carlson, R. D.; Ryther, J. H.; Pendoley, P. D.; Jensen, P. R.; Blakeslee, M.

    1986-05-01

    In 1983, SERI initiated a microalgal species acquisition program to provide strains to be used in the development of microalgal culture technology for the production of fuels (Raymond 1984). From previous collection efforts (Barclay 1984, Tadros 1984) it was determined that desirous species should grow rapidly under fluctuating culture conditions and be capable of producing large concentrations of lipid.

  20. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    SciTech Connect (OSTI)

    Birkholzer, Jens; Apps, John; Zheng, Liange; Zhang, Yingqi; Xu, Tianfu; Tsang, Chin-Fu

    2008-10-01

    One promising approach to reduce greenhouse gas emissions is injecting CO{sub 2} into suitable geologic formations, typically depleted oil/gas reservoirs or saline formations at depth larger than 800 m. Proper site selection and management of CO{sub 2} storage projects will ensure that the risks to human health and the environment are low. However, a risk remains that CO{sub 2} could migrate from a deep storage formation, e.g. via local high-permeability pathways such as permeable faults or degraded wells, and arrive in shallow groundwater resources. The ingress of CO{sub 2} is by itself not typically a concern to the water quality of an underground source of drinking water (USDW), but it will change the geochemical conditions in the aquifer and will cause secondary effects mainly induced by changes in pH, in particular the mobilization of hazardous inorganic constituents present in the aquifer minerals. Identification and assessment of these potential effects is necessary to analyze risks associated with geologic sequestration of CO{sub 2}. This report describes a systematic evaluation of the possible water quality changes in response to CO{sub 2} intrusion into aquifers currently used as sources of potable water in the United States. Our goal was to develop a general understanding of the potential vulnerability of United States potable groundwater resources in the event of CO{sub 2} leakage. This goal was achieved in two main tasks, the first to develop a comprehensive geochemical model representing typical conditions in many freshwater aquifers (Section 3), the second to conduct a systematic reactive-transport modeling study to quantify the effect of CO{sub 2} intrusion into shallow aquifers (Section 4). Via reactive-transport modeling, the amount of hazardous constituents potentially mobilized by the ingress of CO{sub 2} was determined, the fate and migration of these constituents in the groundwater was predicted, and the likelihood that drinking water standards might be exceeded was evaluated. A variety of scenarios and aquifer conditions was considered in a sensitivity evaluation. The scenarios and conditions simulated in Section 4, in particular those describing the geochemistry and mineralogy of potable aquifers, were selected based on the comprehensive geochemical model developed in Section 3.

  1. Directory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sort items in descending order Object Created Object Last Modified Aquifer Impacts from Hydraulic Fracturing Aquifer Impacts from Hydraulic Fracturing Aquifer Impacts from...

  2. Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations

    SciTech Connect (OSTI)

    Birkholzer, J.T.; Nicot, J.-P.; Oldenburg, C.M.; Zhou, Q.; Kraemer, S.; Bandilla, K.W.

    2011-05-01

    Industrial-scale storage of CO{sub 2} in saline sedimentary basins will cause zones of elevated pressure, larger than the CO{sub 2} plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards along these conduits and mix with groundwater resources. This paper discusses the potential for such brine leakage to occur in temperature- and salinity-stratified systems. Using static mass-balance calculations as well as dynamic well flow simulations, we evaluate the minimum reservoir pressure that would generate continuous migration of brine up a leaking wellbore into a freshwater aquifer. Since the brine invading the well is denser than the initial fluid in the wellbore, continuous flow only occurs if the pressure perturbation in the reservoir is large enough to overcome the increased fluid column weight after full invasion of brine into the well. If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) properties, in particular the effective permeability of the wellbore and the magnitude of pressure increase. If brine flow occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement and the formation, the fluid/solute transfer between the migrating fluid and the surrounding rock units can strongly retard brine flow. At the same time, the threshold pressure for continuous flow to occur decreases compared to a case with no fluid/solute transfer.

  3. An Overview of Geologic Carbon Sequestration Potential in California

    SciTech Connect (OSTI)

    Cameron Downey; John Clinkenbeard

    2005-10-01

    As part of the West Coast Regional Carbon Sequestration Partnership (WESTCARB), the California Geological Survey (CGS) conducted an assessment of geologic carbon sequestration potential in California. An inventory of sedimentary basins was screened for preliminary suitability for carbon sequestration. Criteria included porous and permeable strata, seals, and depth sufficient for critical state carbon dioxide (CO{sub 2}) injection. Of 104 basins inventoried, 27 met the criteria for further assessment. Petrophysical and fluid data from oil and gas reservoirs was used to characterize both saline aquifers and hydrocarbon reservoirs. Where available, well log or geophysical information was used to prepare basin-wide maps showing depth-to-basement and gross sand distribution. California's Cenozoic marine basins were determined to possess the most potential for geologic sequestration. These basins contain thick sedimentary sections, multiple saline aquifers and oil and gas reservoirs, widespread shale seals, and significant petrophysical data from oil and gas operations. Potential sequestration areas include the San Joaquin, Sacramento, Ventura, Los Angeles, and Eel River basins, followed by the smaller Salinas, La Honda, Cuyama, Livermore, Orinda, and Sonoma marine basins. California's terrestrial basins are generally too shallow for carbon sequestration. However, the Salton Trough and several smaller basins may offer opportunities for localized carbon sequestration.

  4. Development of a coupled thermo-hydro-mechanical model in discontinuous media for carbon sequestration

    SciTech Connect (OSTI)

    Fang, Yilin; Nguyen, Ba Nghiep; Carroll, Kenneth C.; Xu, Zhijie; Yabusaki, Steven B.; Scheibe, Timothy D.; Bonneville, Alain

    2013-09-12

    Geomechanical alteration of porous media is generally ignored for most shallow subsurface applications, whereas CO2 injection, migration, and trapping in deep saline aquifers will be controlled by coupled multifluid flow, energy transfer, and geomechanical processes. The accurate assessment of the risks associated with potential leakage of injected CO2 and the design of effective injection systems requires that we represent these coupled processes within numerical simulators. The objectives of this study were to develop a coupled thermal-hydro-mechanical model into a single software, and to examine the coupling of thermal, hydrological, and geomechanical processes for simulation of CO2 injection into the subsurface for carbon sequestration. A numerical model is developed to couple nonisothermal multiphase hydrological and geomechanical processes for prediction of multiple interconnected processes for carbon sequestration in deep saline aquifers. The geomechanics model was based on Rigid Body-Spring Model (RBSM), one of the discrete methods to model discontinuous rock system. Poissons effect that was often ignored by RBSM was considered in the model. The simulation of large-scale and long-term coupled processes in carbon capture and storage projects requires large memory and computational performance. Global Array Toolkit was used to build the model to permit the high performance simulations of the coupled processes. The model was used to simulate a case study with several scenarios to demonstrate the impacts of considering coupled processes and Poissons effect for the prediction of CO2 sequestration.

  5. Shallow Carbon Sequestration Demonstration Project

    SciTech Connect (OSTI)

    Pendergrass, Gary; Fraley, David; Alter, William; Bodenhamer, Steven

    2013-09-30

    The potential for carbon sequestration at relatively shallow depths was investigated at four power plant sites in Missouri. Exploratory boreholes were cored through the Davis Shale confining layer into the St. Francois aquifer (Lamotte Sandstone and Bonneterre Formation). Precambrian basement contact ranged from 654.4 meters at the John Twitty Energy Center in Southwest Missouri to over 1100 meters near the Sioux Power Plant in St. Charles County. Investigations at the John Twitty Energy Center included 3D seismic reflection surveys, downhole geophysical logging and pressure testing, and laboratory analysis of rock core and water samples. Plans to perform injectivity tests at the John Twitty Energy Center, using food grade CO{sub 2}, had to be abandoned when the isolated aquifer was found to have very low dissolved solids content. Investigations at the Sioux Plant and Thomas Hill Energy Center in Randolph County found suitably saline conditions in the St. Francois. A fourth borehole in Platte County was discontinued before reaching the aquifer. Laboratory analyses of rock core and water samples indicate that the St. Charles and Randolph County sites could have storage potentials worthy of further study. The report suggests additional Missouri areas for further investigation as well.

  6. Application of Cutting-Edge 3D Seismic Attribute Technology to the Assessment of Geological Reservoirs for CO2 Sequestration

    SciTech Connect (OSTI)

    Christopher Liner; Jianjun Zeng; Po Geng Heather King Jintan Li; Jennifer Califf; John Seales

    2010-03-31

    The goals of this project were to develop innovative 3D seismic attribute technologies and workflows to assess the structural integrity and heterogeneity of subsurface reservoirs with potential for CO{sub 2} sequestration. Our specific objectives were to apply advanced seismic attributes to aide in quantifying reservoir properies and lateral continuity of CO{sub 2} sequestration targets. Our study area is the Dickman field in Ness County, Kansas, a type locality for the geology that will be encountered for CO{sub 2} sequestration projects from northern Oklahoma across the U.S. midcontent to Indiana and beyond. Since its discovery in 1962, the Dickman Field has produced about 1.7 million barrels of oil from porous Mississippian carbonates with a small structural closure at about 4400 ft drilling depth. Project data includes 3.3 square miles of 3D seismic data, 142 wells, with log, some core, and oil/water production data available. Only two wells penetrate the deep saline aquifer. Geological and seismic data were integrated to create a geological property model and a flow simulation grid. We systematically tested over a dozen seismic attributes, finding that curvature, SPICE, and ANT were particularly useful for mapping discontinuities in the data that likely indicated fracture trends. Our simulation results in the deep saline aquifer indicate two effective ways of reducing free CO{sub 2}: (a) injecting CO{sub 2} with brine water, and (b) horizontal well injection. A tuned combination of these methods can reduce the amount of free CO{sub 2} in the aquifer from over 50% to less than 10%.

  7. Integrated hydrogeological model of the general separations area. Volume 2: groundwater flow model

    SciTech Connect (OSTI)

    Flach, G.P.; Harris, M.K.

    1997-08-01

    This report models the Gordon aquifer, the Gordon confining unit, and the `lower` aquifer zone, `tan clay` confining zone, and `upper` aquifer zone of the Water Table aquifer. The report presents structure-contour and isopach maps of each unit.

  8. TIME-LAPSE SEISMIC MODELING & INVERSION OF CO2 SATURATION FOR SEQUESTRATION AND ENHANCED OIL RECOVERY

    SciTech Connect (OSTI)

    Mark A. Meadows

    2006-03-31

    Injection of carbon dioxide (CO2) into subsurface aquifers for geologic storage/sequestration, and into subsurface hydrocarbon reservoirs for enhanced oil recovery, has become an important topic to the nation because of growing concerns related to global warming and energy security. In this project we developed new ways to predict and quantify the effects of CO2 on seismic data recorded over porous reservoir/aquifer rock systems. This effort involved the research and development of new technology to: (1) Quantitatively model the rock physics effects of CO2 injection in porous saline and oil/brine reservoirs (both miscible and immiscible). (2) Quantitatively model the seismic response to CO2 injection (both miscible and immiscible) from well logs (1D). (3) Perform quantitative inversions of time-lapse 4D seismic data to estimate injected CO2 distributions within subsurface reservoirs and aquifers. This work has resulted in an improved ability to remotely monitor the injected CO2 for safe storage and enhanced hydrocarbon recovery, predict the effects of CO2 on time-lapse seismic data, and estimate injected CO2 saturation distributions in subsurface aquifers/reservoirs. We applied our inversion methodology to a 3D time-lapse seismic dataset from the Sleipner CO2 sequestration project, Norwegian North Sea. We measured changes in the seismic amplitude and traveltime at the top of the Sleipner sandstone reservoir and used these time-lapse seismic attributes in the inversion. Maps of CO2 thickness and its standard deviation were generated for the topmost layer. From this information, we estimated that 7.4% of the total CO2 injected over a five-year period had reached the top of the reservoir. This inversion approach could also be applied to the remaining levels within the anomalous zone to obtain an estimate of the total CO2 injected.

  9. Natural Gas Storage in Basalt Aquifers of the Columbia Basin, Pacific Northwest USA: A Guide to Site Characterization

    SciTech Connect (OSTI)

    Reidel, Steve P.; Spane, Frank A.; Johnson, Vernon G.

    2002-08-08

    This report provides the technical background and a guide to characterizing a site for storing natural gas in the Columbia River Basalt

  10. Behavior of natural uranium, thorium, and radium isotopes in the Wolfcamp brine aquifers, Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1984-10-01

    Previously reported results for Palo Duro deep brines show that Ra is highly soluble and not retarded. Relative to Ra, U and Th are highly sorbed. Uranium, like thorium, is in the +4 valence state, indicating a reducing environment. Additional data reported here support these results. However, one Wolfcamp brine sample gives somewhat different results. Radium appears to be somewhat sorbed. Uranium is largely in the +6 valence state, indicating a less reducing condition. In all brines, kinetics for sorption (/sup 228/Th) and desorption (/sup 224/Ra) are rapid. This Wolfcamp brine was tested for the effects of colloids for Ra, U, and Th concentrations. No effects were found.

  11. GeoChip-based analysis of functional microbial communities in a bioreduced uranium-contaminated aquifer during reoxidation by oxygen

    SciTech Connect (OSTI)

    Van Nostrand, J.D.; Wu, W.-M.; Wu, L.; Deng, Y.; Carley, J.; Carroll, S.; He, Z.; Gu, B.; Luo, J.; Criddle, C. S.; Watson, D. B.; Jardine, P. M.; Tiedje, J. M.; Hazen, T. C.; Zhou, J.

    2009-07-15

    A pilot-scale system was established for in situ biostimulation of U(VI) reduction by ethanol addition at the US Department of Energy's (DOE's) Field Research Center (Oak Ridge, TN). After achieving U(VI) reduction, stability of the bioreduced U(IV) was evaluated under conditions of (i) resting (no ethanol injection), (ii) reoxidation by introducing dissolved oxygen (DO), and (iii) reinjection of ethanol. GeoChip, a functional gene array with probes for N, S and C cycling, metal resistance and contaminant degradation genes, was used for monitoring groundwater microbial communities. High diversity of all major functional groups was observed during all experimental phases. The microbial community was extremely responsive to ethanol, showing a substantial change in community structure with increased gene number and diversity after ethanol injections resumed. While gene numbers showed considerable variations, the relative abundance (i.e. percentage of each gene category) of most gene groups changed little. During the reoxidation period, U(VI) increased, suggesting reoxidation of reduced U(IV). However, when introduction of DO was stopped, U(VI) reduction resumed and returned to pre-reoxidation levels. These findings suggest that the community in this system can be stimulated and that the ability to reduce U(VI) can be maintained by the addition of electron donors. This biostimulation approach may potentially offer an effective means for the bioremediation of U(VI)-contaminated sites.

  12. GeoChip-based analysis of functional microbial communities during the reoxidation of a bioreduced uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Van Nostrand, Joy; Wu, Weimin; Wu, Liyou; Deng, Ye; Carley, Jack M; Carroll, Sue L; He, Zhili; Gu, Baohua; Luo, Jian; Criddle, Craig; Watson, David B; Jardine, Philip M; Marsh, Terence; Tiedje, James; Hazen, T. C.; Zhou, Jizhong

    2009-01-01

    A pilot-scale system was established for in situ biostimulation of U(VI) reduction by ethanol addition at the US Department of Energy's (DOE's) Field Research Center (Oak Ridge, TN). After achieving U(VI) reduction, stability of the bioreduced U(IV) was evaluated under conditions of (i) resting (no ethanol injection), (ii) reoxidation by introducing dissolved oxygen (DO), and (iii) reinjection of ethanol. GeoChip, a functional gene array with probes for N, S and C cycling, metal resistance and contaminant degradation genes, was used for monitoring groundwater microbial communities. High diversity of all major functional groups was observed during all experimental phases. The microbial community was extremely responsive to ethanol, showing a substantial change in community structure with increased gene number and diversity after ethanol injections resumed. While gene numbers showed considerable variations, the relative abundance (i.e. percentage of each gene category) of most gene groups changed little. During the reoxidation period, U(VI) increased, suggesting reoxidation of reduced U(IV). However, when introduction of DO was stopped, U(VI) reduction resumed and returned to pre-reoxidation levels. These findings suggest that the community in this system can be stimulated and that the ability to reduce U(VI) can be maintained by the addition of electron donors. This biostimulation approach may potentially offer an effective means for the bioremediation of U(VI)-contaminated sites.

  13. A limited microbial consortium is responsible for longer-term biostimulation and bioreduction or uranium in a contaminated aquifer

    SciTech Connect (OSTI)

    Gihring, Thomas; Zhang, Gengxin; Brandt, Craig C; Brooks, Scott C; Carroll, Sue L; Criddle, Craig; Green, Stefan; Jardine, Philip M; Kostka, Joel; Lowe, Kenneth Alan; Mehlhorn, Tonia L; Overholt, Will; Watson, David B; Yang, Zamin; Wu, Wei-min; Schadt, Christopher Warren

    2011-01-01

    Subsurface amendments of slow-release substrates (e.g., emulsified vegetable oil [EVO]) are thought to be a pragmatic alternative to using short-lived, labile substrates for sustained uranium bioimmobilization within contaminated groundwater systems. Spatial and temporal dynamics of subsurface microbial communities during EVO amendment are unknown and likely differ significantly from those of populations stimulated by soluble substrates, such as ethanol and acetate. In this study, a one-time EVO injection resulted in decreased groundwater U concentrations that remained below initial levels for approximately 4 months. Pyrosequencing and quantitative PCR of 16S rRNA from monitoring well samples revealed a rapid decline in groundwater bacterial community richness and diversity after EVO injection, concurrent with increased 16S rRNA copy levels, indicating the selection of a narrow group of taxa rather than a broad community stimulation. Members of the Firmicutes family Veillonellaceae dominated after injection and most likely catalyzed the initial oil decomposition. Sulfate-reducing bacteria from the genus Desulforegula, known for long-chain fatty acid oxidation to acetate, also dominated after EVO amendment. Acetate and H{sub 2} production during EVO degradation appeared to stimulate NO{sub 3}{sup -}, Fe(III), U(VI), and SO{sub 4}{sup 2-} reduction by members of the Comamonadaceae, Geobacteriaceae, and Desulfobacterales. Methanogenic archaea flourished late to comprise over 25% of the total microbial community. Bacterial diversity rebounded after 9 months, although community compositions remained distinct from the preamendment conditions. These results demonstrated that a one-time EVO amendment served as an effective electron donor source for in situ U(VI) bioreduction and that subsurface EVO degradation and metal reduction were likely mediated by successive identifiable guilds of organisms.

  14. STOMP Subsurface Transport Over Multiple Phases Version 1.0 Addendum: ECKEChem Equilibrium-Conservation-Kinetic Equation Chemistry and Reactive Transport

    SciTech Connect (OSTI)

    White, Mark D.; McGrail, B. Peter

    2005-12-01

    Geologic sequestration is currently being practiced and scientifically evaluated as a critical component in a broad strategy, comprising new practices and technologies, for mitigating global climate change due to anthropogenic emissions of CO2. Demonstrating that geologic sequestration of CO2 is safe and effective, and gaining public acceptance of sequestration technologies are critically important in meeting these global climate change challenges. Monitored field-scale demonstrations of geologic sequestration of carbon dioxide will contribute greatly toward growing trust and confidence in the technology; however, pilot demonstrations ultimately will not be the norm for new geological sequestration deployments. Instead, scientists, engineers, regulators, and ultimately the public will rely on numerical simulations to predict the performance of geologic repositories for carbon dioxide sequestration. The U.S. Department of Energy (DOE), through the National Environmental Technology Laboratory (NETL) has requested the development of numerical simulation capabilities for quantifying the permanent storage capacity, leakage rates, and public risks associated with geologic sequestration of CO2. In conjunction with this request. the Zero Emissions Research and Technology Center (ZERT) has been created with the mission of conducting basic and applied research that support the development of new technologies for minimizing emissions of anthropogenic carbon dioxide and other greenhouse gases that impact global climate change. As a member of the ZERT Center, the Pacific Northwest National Laboratory (PNNL) is conducting research associated with geologic sequestration of CO2 that includes the thermochemistry of supercritical CO2-brine mixtures, mineralization kinetics, leakage and microseepage of CO2, and new materials for CO2 capture. In addition to these research activities, PNNL is developing new scalable CO2 reservoir simulation capabilities for its multifluid subsurface flow and transport simulator, STOMP (Subsurface Transport Over Multiple Phases). Prior to these code development activities, the STOMP simulator included sequential and scalable implementations for numerically simulating the injection of supercritical CO2 into deep saline aquifers. Additionally, the sequential implementations included operational modes that considered nonisothermal conditions and kinetic dissolution of CO2 into the saline aqueous phase. This addendum documents the advancement of these numerical simulation capabilities to include reactive transport in the STOMP simulator through the inclusion of the recently PNNL developed batch geochemistry solution module ECKEChem (Equilibrium-Conservation-Kinetic Equation Chemistry). Potential geologic reservoirs for sequestering CO2 include deep saline aquifers, hydrate-bearing formations, depleted or partially depleted natural gas and petroleum reservoirs, and coal beds. The mechanisms for sequestering carbon dioxide in geologic reservoirs include physical trapping, dissolution in the reservoir fluids, hydraulic trapping (hysteretic entrapment of nonwetting fluids), and chemical reaction. This document and the associated code development and verification work are concerned with the chemistry of injecting CO2 into geologic reservoirs. As geologic sequestration of CO2 via chemical reaction, namely precipitation reactions, are most dominate in deep saline aquifers, the principal focus of this document is the numerical simulation of CO2 injection, migration, and geochemical reaction in deep saline aquifers. The ECKEChem batch chemistry module was developed in a fashion that would allow its implementation into all operational modes of the STOMP simulator, making it a more versatile chemistry component. Additionally, this approach allows for verification of the ECKEChem module against more classical reactive transport problems involving aqueous systems.

  15. Restored Drill Cuttings for Wetlands Creation: Results of Mesocosm Approach to Emulate Field Conditions Under Varying Salinity and Hydrologic Conditions

    SciTech Connect (OSTI)

    Hester, Mark W.; Shaffer, Gary P.; Willis Jonathan M.; DesRoches, Dennis J.

    2001-02-21

    This study builds upon earlier research conducted by Southeastern Louisiana University concerning the efficacy of utilizing processed drill cuttings as an alternative substrate source for wetland rehabilitation (wetland creation and restoration). Previous research has indicated that processed drill cuttings exhibit a low degree of contaminant migration from the process drill cuttings to interstitial water and low toxicity, as tested by seven-day mysid shrimp chronic toxicity trials.

  16. Restored Drill Cuttings for Wetlands Creation: Results of Mesocosm Approach to Emulate Field Conditions Under Varying Salinity and Hydrologic Conditions

    SciTech Connect (OSTI)

    Hester, Mark W.; Shaffer, Gary P.; Willis, Jonathan M.; DesRoches, Dennis J.

    2002-06-03

    Both interstitial water and plant tissue associated with the DC-A substrate exhibited low metal concentrations. Also in agreement with the previous study, plant performance in the DC-A substrate was found to be comparable to plant performance in the dredge spoil and topsoil substrates. This was extremely important because it indicated that the drill cuttings themselves served as an excellent substrate for wetland plant growth, but that the processing and stabilization techniques and drilling fluid formulations required further refinement.

  17. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; et al

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in compositionmore » of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.« less

  18. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    SciTech Connect (OSTI)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; Griffith, C.; Hedges, S.; Dilmore, R.; Goodman, A.; Black, J.; Haese, R.; Deusner, C.; Bigalke, N.; Haeckel, M.; Fischer, S.; Liebscher, A.; Icenhower, J. P.; Daval, D.; Saldi, G. D.; Knauss, K. G.; Schmidt, M.; Mito, S.; Sorai, M.; Truche, L.

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in composition of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.

  19. Hunton Group core workshop and field trip

    SciTech Connect (OSTI)

    Johnson, K.S.

    1993-12-31

    The Late Ordovician-Silurian-Devonian Hunton Group is a moderately thick sequence of shallow-marine carbonates deposited on the south edge of the North American craton. This rock unit is a major target for petroleum exploration and reservoir development in the southern Midcontinent. The workshop described here was held to display cores, outcrop samples, and other reservoir-characterization studies of the Hunton Group and equivalent strata throughout the region. A field trip was organized to complement the workshop by allowing examination of excellent outcrops of the Hunton Group of the Arbuckle Mountains.

  20. Integrating CO₂ storage with geothermal resources for dispatchable renewable electricity

    SciTech Connect (OSTI)

    Buscheck, Thomas A.; Bielicki, Jeffrey M.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Edmunds, Thomas A.; Saar, Martin O.; Randolph, Jimmy B.

    2014-12-31

    We present an approach that uses the huge fluid and thermal storage capacity of the subsurface, together with geologic CO₂ storage, to harvest, store, and dispatch energy from subsurface (geothermal) and surface (solar, nuclear, fossil) thermal resources, as well as energy from electrical grids. Captured CO₂ is injected into saline aquifers to store pressure, generate artesian flow of brine, and provide an additional working fluid for efficient heat extraction and power conversion. Concentric rings of injection and production wells are used to create a hydraulic divide to store pressure, CO₂, and thermal energy. Such storage can take excess power from the grid and excess/waste thermal energy, and dispatch that energy when it is demanded, enabling increased penetration of variable renewables. Stored CO₂ functions as a cushion gas to provide enormous pressure-storage capacity and displaces large quantities of brine, which can be desalinated and/or treated for a variety of beneficial uses.

  1. Integrating CO₂ storage with geothermal resources for dispatchable renewable electricity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Buscheck, Thomas A.; Bielicki, Jeffrey M.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Edmunds, Thomas A.; Saar, Martin O.; Randolph, Jimmy B.

    2014-12-31

    We present an approach that uses the huge fluid and thermal storage capacity of the subsurface, together with geologic CO₂ storage, to harvest, store, and dispatch energy from subsurface (geothermal) and surface (solar, nuclear, fossil) thermal resources, as well as energy from electrical grids. Captured CO₂ is injected into saline aquifers to store pressure, generate artesian flow of brine, and provide an additional working fluid for efficient heat extraction and power conversion. Concentric rings of injection and production wells are used to create a hydraulic divide to store pressure, CO₂, and thermal energy. Such storage can take excess power frommore » the grid and excess/waste thermal energy, and dispatch that energy when it is demanded, enabling increased penetration of variable renewables. Stored CO₂ functions as a cushion gas to provide enormous pressure-storage capacity and displaces large quantities of brine, which can be desalinated and/or treated for a variety of beneficial uses.« less

  2. TOUGHREACT-Pitzer V1.21

    Energy Science and Technology Software Center (OSTI)

    2011-12-01

    TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media. The program is written in Fortran 77 and was developed by introducing reactive chemistry into the multiphase flow code TOUGH2 V2. Interactions between mineral assemblages and fluids can occur under local equilibrium or kinetic rates. The gas phase can be chemically active. Precipitation and dissolution reactions can change formation porosity and permeability, and can also modifymore » the unsaturated flow properties of the rock. The code is distributed with a comprehensive user?s guide that includes sample problems addressing geothermal reservoirs and hydrothermal systems, nuclear waste isolation, groundwater quality, sequestration of carbon dioxide in saline aquifers, and supergene copper enrichment.« less

  3. Log analysis of six boreholes in conjunction with geologic characterization above and on top of the Weeks Island salt dome

    SciTech Connect (OSTI)

    Sattler, A.R.

    1996-04-01

    Six boreholes were drilled during the geologic characterization and diagnostics of the Weeks Island sinkhole that is over the two-tiered salt mine which was converted for oil storage by the US Strategic Petroleum Reserve. These holes were drilled to provide for geologic characterization of the Weeks Island Salt Dome and its overburden in the immediate vicinity of the sinkhole (mainly through logs and core); to establish a crosswell configuration for seismic tomography; to establish locations for hydrocarbon detection and tracer injection; and to Provide direct observations of sinkhole geometry and material properties. Specific objectives of the logging program were to: (1) identify the top of and the physical state of the salt dome; (2) identify the water table; (3) obtain a relative salinity profile in the aquifer within the alluvium, which ranges from the water table directly to the top of the Weeks Island salt dome; and (4) identify a reflecting horizon seen on seismic profiles over this salt dome. Natural gamma, neutron, density, sonic, resistivity and caliper logs were run. Neutron and density logs were run from inside the well casing because of the extremely unstable condition of the deltaic alluvium overburden above the salt dome. The logging program provided important information about the salt dome and the overburden in that (1) the top of the salt dome was identified at {approximately}189 ft bgl (103 ft msl), and the top of the dome contains relatively few fractures; (2) the water table is approximately 1 ft msl, (3) this aquifer appears to become steadily more saline with depth; and (4) the water saturation of much of the alluvium over the salt dome is shown to be influenced by the prevalent heavy rainfall. This logging program, a part of the sinkhole diagnostics, provides unique information about this salt dome and the overburden.

  4. Maximization of permanent trapping of CO{sub 2} and co-contaminants in the highest-porosity formations of the Rock Springs Uplift (Southwest Wyoming): experimentation and multi-scale modeling

    SciTech Connect (OSTI)

    Piri, Mohammad

    2014-03-31

    Under this project, a multidisciplinary team of researchers at the University of Wyoming combined state-of-the-art experimental studies, numerical pore- and reservoir-scale modeling, and high performance computing to investigate trapping mechanisms relevant to geologic storage of mixed scCO{sub 2} in deep saline aquifers. The research included investigations in three fundamental areas: (i) the experimental determination of two-­‐phase flow relative permeability functions, relative permeability hysteresis, and residual trapping under reservoir conditions for mixed scCO{sub 2}-­‐brine systems; (ii) improved understanding of permanent trapping mechanisms; (iii) scientifically correct, fine grid numerical simulations of CO{sub 2} storage in deep saline aquifers taking into account the underlying rock heterogeneity. The specific activities included: (1) Measurement of reservoir-­‐conditions drainage and imbibition relative permeabilities, irreducible brine and residual mixed scCO{sub 2} saturations, and relative permeability scanning curves (hysteresis) in rock samples from RSU; (2) Characterization of wettability through measurements of contact angles and interfacial tensions under reservoir conditions; (3) Development of physically-­‐based dynamic core-­‐scale pore network model; (4) Development of new, improved high-­‐ performance modules for the UW-­‐team simulator to provide new capabilities to the existing model to include hysteresis in the relative permeability functions, geomechanical deformation and an equilibrium calculation (Both pore-­‐ and core-­‐scale models were rigorously validated against well-­‐characterized core-­‐ flooding experiments); and (5) An analysis of long term permanent trapping of mixed scCO{sub 2} through high-­‐resolution numerical experiments and analytical solutions. The analysis takes into account formation heterogeneity, capillary trapping, and relative permeability hysteresis.

  5. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    SciTech Connect (OSTI)

    Zheng, L.; Spycher, N.; Xu, T.; Apps, J.; Kharaka, Y.; Birkholzer, J.T.

    2010-11-05

    In this study, reactive transport simulations were used to assess the mobilization and transport of organics with supercritical CO{sub 2} (SCC), and the co-injection and transport of H{sub 2}S with SCC. These processes were evaluated at conditions of typical storage reservoirs, and for cases of hypothetical leakage from a reservoir to an overlying shallower fresh water aquifer. Modeling capabilities were developed to allow the simulation of multiphase flow and transport of H{sub 2}O, CO{sub 2}, H{sub 2}S, as well as specific organic compounds (benzene), coupled with multicomponent geochemical reaction and transport. This included the development of a new simulator, TMVOC-REACT, starting from existing modules of the TOUGH2 family of codes. This work also included an extensive literature review, calculation, and testing of phase-partitioning properties for mixtures of the phases considered. The reactive transport simulations presented in this report are primarily intended to illustrate the capabilities of the new simulator. They are also intended to help evaluate and understand various processes at play, in a more qualitative than quantitative manner, and only for hypothetical scenarios. Therefore, model results are not intended as realistic assessments of groundwater quality changes for specific locations, and they certainly do not provide an exhaustive evaluation of all possible site conditions, especially given the large variability and uncertainty in hydrogeologic and geochemical parameter input into simulations. The first step in evaluating the potential mobilization and transport of organics was the identification of compounds likely to be present in deep storage formations, and likely to negatively impact freshwater aquifers if mobilized by SCC. On the basis of a literature review related to the occurrence of these organic compounds, their solubility in water and SCC, and their toxicity (as reflected by their maximum contaminant levels MCL), benzene was selected as a key compound for inclusion into numerical simulations. Note that considering additional organic compounds and/or mixtures of such compounds in the simulations was beyond the scope of this study, because of the effort required to research, calculate, and validate the phase-partitioning data necessary for simulations. The injection of CO{sub 2} into a deep saline aquifer was simulated, followed by modeling the leaching of benzene by SCC and transport of benzene to an overlying aquifer along a hypothetical leakage pathway. One- and two-dimensional models were set up for this purpose. The target storage formation was assumed to initially contain about 10{sup -4} ppm benzene. Model results indicate that: (1) SCC efficiently extracts benzene from the storage formation. (2) Assuming equilibrium, the content of benzene in SCC is roportional to the concentration of benzene in the aqueous and solid phases. (3) Benzene may co-migrate with CO{sub 2} into overlying aquifers if a leakage pathway is present. Because the aqueous solubility of benzene in contact with CO{sub 2} is lower than the aqueous solubility of CO{sub 2}, benzene is actually enriched in the CO{sub 2} phase as the plume advances. (4) For the case studied here, the resulting aqueous benzene concentration in the overlying aquifer is on the same order of magnitude as the initial concentration in the storage formation. This generic modeling study illustrates, in a semi-quantitative manner, the possible mobilization of benzene by SCC. The extent to which the mobilization of this organic compound evolves temporally and spatially depends on a large number of controlling parameters and is largely site specific. Therefore, for more 'truly' predictive work, further sensitivity studies should be conducted, and further modeling should be integrated with site-specific laboratory and/or field experimental data. The co-injection of H{sub 2}S with CO{sub 2} into a deep saline aquifer was also simulated. In addition, the model considered leakage of the supercritical CO{sub 2}+H{sub 2}S mixture along a preferential pathway to an overlying fresh-water aquifer, followed by reaction of the CO{sub 2}+H{sub 2}S mixture with that aquifer. A simple 2-D model that included a storage formation and a sealing aquitard was developed to simulate the movement of H{sub 2}S in a typical CO{sub 2} storage formation. Model results indicate that H{sub 2}S is stripped off at the edge of the advancing supercritical plume, because of the H{sub 2}S preferential solubility in water compared to CO{sub 2}. The magnitude of H{sub 2}S preferential dissolution, however, decreases with decreasing temperature and pressure. To capture this behavior and evaluate the breakthrough of H{sub 2}S through a leakage pathway (from the deep storage formation to a shallower aquifer), another model was constructed, considering a storage formation, an overlying aquifer, and a vertical leakage pathway between them.

  6. The use of Ahuachapan fluid chemistry to indicate natural state conditions and reservoir processes during exploitation

    SciTech Connect (OSTI)

    Treusdell, A.H. ); Aunzo, Z.; Bodvarsson, G. ); Alonso, J.; Campos, A. )

    1989-01-01

    Chemical analyses of production fluids from Ahuachapan, El Salvador, have been used to indicate natural state reservoir fluid temperatures and chloride concentrations and reservoir processes resulting from exploitation. Geothermometer temperatures (Na--K--Ca and SiO{sub 2}) and calculated aquifer Cl for early flows show a gradient from about 265{degree}C and 9000 ppM Cl in the western part of the well field to 235{degree}C and 6000 ppM Cl in the eastern part. The geochemical temperatures are 10--20{degree}C higher than early downhole measurements. Since exploitation started, pressures have declined over most of the drilled area with boiling and excess-enthalpy discharges in the eastern and western parts. In the center of the field, a number of wells show mixing with cooler, less-saline water. These wells are nearly coincident with a major NE-SW oriented fault that may be the conduit for downward recharge of cooler fluids from an overlying aquifer. 12 refs., 9 figs., 1 tab.

  7. Calculating the probability of injected carbon dioxide plumes encountering faults

    SciTech Connect (OSTI)

    Jordan, P.D.

    2011-04-01

    One of the main concerns of storage in saline aquifers is leakage via faults. In the early stages of site selection, site-specific fault coverages are often not available for these aquifers. This necessitates a method using available fault data to estimate the probability of injected carbon dioxide encountering and migrating up a fault. The probability of encounter can be calculated from areal fault density statistics from available data, and carbon dioxide plume dimensions from numerical simulation. Given a number of assumptions, the dimension of the plume perpendicular to a fault times the areal density of faults with offsets greater than some threshold of interest provides probability of the plume encountering such a fault. Application of this result to a previously planned large-scale pilot injection in the southern portion of the San Joaquin Basin yielded a 3% and 7% chance of the plume encountering a fully and half seal offsetting fault, respectively. Subsequently available data indicated a half seal-offsetting fault at a distance from the injection well that implied a 20% probability of encounter for a plume sufficiently large to reach it.

  8. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from Subsurface Storage Reservoirs on Groundwater Quality

    SciTech Connect (OSTI)

    Shao, Hongbo; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Brown, Christopher F.

    2015-07-07

    The leakage of CO2 and the concomitant saline solutions from deep storage reservoirs to overlying groundwater aquifers is considered one of the major potential risks associated with geologic CO2 sequestration (GCS). Batch and column experiments were conducted to determine the fate of trace metals in groundwater in the scenarios of CO2 and metal contaminated brine leakage. The sediments used in this work were collected from an unconsolidated sand and gravel aquifer in Kansas, and contained 0-4 wt% carbonates. Cd and As were spiked into the reaction system to represent potential contaminants from the reservoir brine that could intrude into groundwater aquifers with leaking CO2 at initial concentrations of 114 and 40 ppb, respectively. Through this research we demonstrated that Cd and As were adsorbed on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. Cd concentrations were well below its MCL in both batch and column studies, even for sediment samples without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent were also significantly lower than influent concentration, suggesting that the sediments tested have the capacity to mitigate the coupled adverse effects of CO2 leakage and brine intrusion. However, the mitigation capacity of sediment is a function of its geochemical properties [e.g., the calcite content; the presence of adsorbed As(III); and the presence of P in the natural sediment]. The competitive adsorption between phosphate and arsenate may result in higher concentrations of As in the aqueous phase.

  9. Ground-water solutes and eolian processes: An example from the High Plains of Texas

    SciTech Connect (OSTI)

    Wood, W.W.; Sanford, W.E. (Geological Survey, Reston, VA (United States))

    1992-01-01

    Eolian dunes associated with saline-lake basins are important geologic features in arid and semiarid areas. The authors propose that eolian processes may also be important in controlling solute concentration and composition of ground water in these environments. A study of Double Lakes on the Southern High Plains of Texas suggests that approximately 200 megagrams of chloride enters this topographically closed basin from the surrounding water table aquifer, direct precipitation and surface runoff. Solute-transport simulation suggest that approximately 70 of the 200 megagrams of the chloride annually leaves the basin by diffusion and ground-water advection through a 30 meter-thick shale underlying the lake. The remaining 130 megagrams is hypothesized to be removed by eolian processes. Closed water-table contours around the lake and a hydrologic analysis suggest that it is improbable that solutes will reach the surrounding water-table aquifer by ground-water transport from this lake system. The conceptual eolian-transport model is further supported by observed chloride profiles in the unsaturated zone. When analyzed with estimates of recharge fluxes, these profiles suggest that approximately 150 megagrams of chloride enter the unsaturated zone downwind of the lake annually. Thus two independent methods suggest that 130 to 150 megagrams of chloride enter the unsaturated zone downwind of the lake annually. Thus two independent methods suggest that 130 to 150 megagrams of chloride are removed from the basin annually by eolian process and redeposited downwind of the lake. Eolian input to the ground water is consistent with the observed plume shape as well as with the solute and isotopic composition of ground water in the water-table aquifer downwind of the lake basin.

  10. RAPID/Roadmap/19-CO-h | Open Energy Information

    Open Energy Info (EERE)

    and Laramie-Fox Hills aquifers) is a geologic formation in which aquifers lie on top of each other in layers with confining layers separating the aquifers. The ground...

  11. RAPID/Roadmap/19-CO-b | Open Energy Information

    Open Energy Info (EERE)

    and Laramie-Fox Hills aquifers) is a geologic formation in which aquifers lie on top of each other in layers with confining layers separating the aquifers. The ground...

  12. Mathematical models as tools for probing long-term safety of CO2 storage

    SciTech Connect (OSTI)

    Pruess, Karsten; Birkholzer, Jens; Zhou, Quanlin

    2009-02-01

    Subsurface reservoirs being considered for storing CO{sub 2} include saline aquifers, oil and gas reservoirs, and unmineable coal seams (Baines and Worden, 2004; IPCC, 2005). By far the greatest storage capacity is in saline aquifers (Dooley et al., 2004), and our discussion will focus primarily on CO{sub 2} storage in saline formations. Most issues for safety and security of CO{sub 2} storage arise from the fact that, at typical temperature and pressure conditions encountered in terrestrial crust, CO{sub 2} is less dense than aqueous fluids. Accordingly, CO{sub 2} will experience an upward buoyancy force in most subsurface environments, and will tend to migrate upwards whenever (sub-)vertical permeable pathways are available, such as fracture zones, faults, or improperly abandoned wells (Bachu, 2008; Pruess, 2008a, b; Tsang et al., 2008). CO{sub 2} injection will increase fluid pressures in the target formation, thereby altering effective stress distributions, and potentially triggering movement along fractures and faults that could increase their permeability and reduce the effectiveness of a caprock in containing CO{sub 2} (Rutqvist et al., 2008; Chiaramonte et al., 2008). Induced seismicity as a consequence of fluid injection is also a concern (Healy et al., 1968; Raleigh et al., 1976; Majer et al., 2007). Dissolution of CO{sub 2} in the aqueous phase generates carbonic acid, which may induce chemical corrosion (dissolution) of minerals with associated increase in formation porosity and permeability, and may also mediate sequestration of CO{sub 2} as solid carbonate (Gaus et al., 2008). Chemical dissolution of caprock minerals could promote leakage of CO{sub 2} from a storage reservoir (Gherardi et al., 2007). Chemical dissolution and geomechanical effects could reinforce one another in compromising CO{sub 2} containment. Additional issues arise from the potential of CO{sub 2} to mobilize hazardous chemical species (Kharaka et al., 2006), and from migration of the large amounts of brine that would be mobilized by industrial-scale CO{sub 2} injection (Nicot et al., 2008; Birkholzer et al., 2008a, b).

  13. PM_Ph_II_CAIP_F.book

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... margin A20SM Area 20 caldera structural ... DRIAE Desert Research Institute recharge with ... LCA Lower carbonate aquifer LCA3 Lower carbonate aquifer-thrust plate LCCU ...

  14. Microsoft Word - Chap - 5-15-05.doc

    Office of Legacy Management (LM)

    ... Great Miami Aquifer, permitting contaminants to be transported to the aquifer as well. ... impact of operations on the surrounding environment, in accordance with DOE requirements. ...

  15. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... in the Parachute Creek Member of the Green River Formation, as the most promising ... This new and complete understanding the aquifer?s areal extent, thickness, water chemistry...

  16. ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-04-01

    ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

  17. Numerical Modeling of CO2 Sequestration in Geologic Formations -Recent Results and Open Challenges

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-03-08

    Rising atmospheric concentrations of CO2, and their role inglobal warming, have prompted efforts to reduce emissions of CO2 fromburning of fossil fuels. An attractive mitigation option underconsideration in many countries is the injection of CO2 from stationarysources, such as fossil-fueled power plants, into deep, stable geologicformations, where it would be stored and kept out of the atmosphere fortime periods of hundreds to thousands of years or more. Potentialgeologic storage reservoirs include depleted or depleting oil and gasreservoirs, unmineable coal seams, and saline formations. While oil andgas reservoirs may provide some attractive early targets for CO2 storage,estimates for geographic regions worldwide have suggested that onlysaline formations would provide sufficient storage capacity tosubstantially impact atmospheric releases. This paper will focus on CO2storage in saline formations.Injection of CO2 into a saline aquifer willgive rise to immiscible displacement of brine by the advancing CO2. Thelower viscosity of CO2 relative to aqueous fluids provides a potentialfor hydrodynamic instabilities during the displacement process. Attypical subsurface conditions of temperature and pressure, CO2 is lessdense than aqueous fluids and is subject to upward buoyancy force inenvironments where pressures are controlled by an ambient aqueous phase.Thus CO2 would tend to rise towards the top of a permeable formation andaccumulate beneath the caprock. Some CO2 will also dissolve in theaqueous phase, while the CO2-rich phase may dissolve some formationwaters, which would tend to dry out the vicinity of the injection wells.CO2 will make formation waters more acidic, and will induce chemicalrections that may precipitate and dissolve mineral phases (Xu et al.,2004). As a consequence of CO2 injection, significant pressurization offormation fluids would occur over large areas. These pressurizationeffects will change effective stresses, and may cause movement alongfaults with associated seismicity and increases in permeability thatcould lead to leakage from the storage reservoir (Rutqvist and Tsang,2005).

  18. Multi-kb Illumina reads Reveal Significant Strain Variation and Rare Organisms in Aquifer (2014 DOE JGI Genomics of Energy & Environment Meeting)

    SciTech Connect (OSTI)

    Sharon, Itai [UC Berkely

    2014-03-20

    Itai Sharon from the University of California at Berkely speaks at the 9th Annual Genomics of Energy & Environment Meeting on March 20, 2014 in Walnut Creek, Calif.

  19. Conceptual Models for Migration of Key Groundwater Contaminants Through the Vadose Zone and Into the Upper Unconfined Aquifer Below the B-Complex

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Bjornstad, Bruce N.; Keller, Jason M.; Thorne, Paul D.; Lanigan, David C.; Christensen, J. N.; Thomas, Gregory S.

    2010-07-01

    The B-Complex contains 3 major crib and trench disposal sites and 3 SST farms that have released nearly 346 mega-liters of waste liquids containing the following high groundwater risk drivers: ~14,000 kg of CN, 29,000 kg of Cr, 12,000 kg of U and 145 Ci of Tc-99. After a thorough review of available vadose zone sediment and pore water, groundwater plume, field gamma logging, field electrical resistivity studies, we developed conceptual models for which facilities have been the significant sources of the contaminants in the groundwater and estimated the masses of these contaminants remaining in the vadose zone and currently present in the groundwater in comparison to the totals released. This allowed us to make mass balance calculations on how consistent our knowledge is on the current deep vadose zone and groundwater distribution of contaminants. Strengths and weaknesses of the conceptual models are discussed as well as implications on future groundwater and deep vadose zone remediation alternatives. Our hypothesized conceptual models attribute the source of all of the cyanide and most of the Tc-99 currently in the groundwater to the BY cribs. The source of the uranium is the BX-102 tank overfill event and the source of most of the chromium is the B-7-A&B and B-8 cribs. Our mass balance estimates suggest that there are much larger masses of U, CN, and Tc remaining in the deep vadose zone within ~20 ft of the water table than is currently in the groundwater plumes below the B-Complex. This hypothesis needs to be carefully considered before future remediation efforts are chosen. The masses of these groundwater risk drivers in the the groundwater plumes have been increasing over the last decade and the groundwater plumes are migrating to the northwest towards the Gable Gap. The groundwater flow rate appears to flucuate in response to seasonal changes in hydraulic gradient. The flux of contaminants out of the deep vadose zone from the three proposed sources also appears to be transient such that the evolution of the contaminant plumes is transient.

  20. Quantity and quality of stormwater runoff recharged to the Floridan aquifer system through two drainage wells in the Orlando, Florida area

    SciTech Connect (OSTI)

    German, E.R.

    1989-01-01

    Quantity and quality of inflow to two drainage wells in the Orlando, Fla., area were determined for the period April 1982 through March 1983. The wells, located at Lake Midget and at Park Lake, are used to control the lake levels during rainy periods. The lakes receive stormwater runoff from mixed residential-commercial areas of about 64 acres (Lake Midget) and 96 acres (Park Lake) and would frequently flood adjacent areas if the wells did not drain the excess stormwater. These lakes and wells are typical of stormwater drainage systems in the area.

  1. Evaluation of repeated measurements of radon-222 concentrations in well water sampled from bedrock aquifers of the Piedmont near Richmond, Virginia, USA: Effects of lithology and well characteristics

    SciTech Connect (OSTI)

    Harris, Shelley A. . E-mail: saharris@vcu.edu; Billmeyer, Ernest R.; Robinson, Michael A.

    2006-07-15

    Radon ({sup 222}Rn) concentrations in 26 ground water wells of two distinct lithologies in the Piedmont of Virginia were measured to assess variation in ground water radon concentrations (GWRC), to evaluate differences in concentrations related to well characteristics, lithology, and spatial distributions, and to assess the feasibility of predicting GWRC. Wells were sampled in accordance with American Public Health Association Method 7500 Rn-B, with modifications to include a well shaft profile analysis that determined the minimum purge time sufficient to remove the equivalent of one column of water from each well. Statistically significant differences in GWRC were found in the Trssu (1482{+-}1711 pCi/L) and Mpg (7750{+-}5188 pCi/L) lithologies, however, no significant differences were found among GWRC at each well over time. Using multiple regression, 86% of the variability (R {sup 2}) in the GWRC was explained by the lithology, latitudinal class, and water table elevation of the wells. The GWRC in a majority of the wells studied exceed US Environmental Protection Agency designated maximum contaminant level and AMCL. Results support modifications to sampling procedures and indicate that, in previous studies, variations in GWRC concentrations over time may have been due in part to differences in sampling procedures and not in source water.

  2. Five-year summary and evaluation of operations and performance of the Utica aquifer and North Lake Basin Wetlands restoration project in 2004-2009.

    SciTech Connect (OSTI)

    LaFreniere, L. M.

    2011-09-13

    This document reviews the performance of the groundwater (and wetlands) restoration program implemented by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) at the former CCC/USDA grain storage facility in Utica, Nebraska, during the first five years (2004-2009) of this initiative. The report summarizes treatment system operational data and regulatory compliance monitoring results for the site during this period, together with the results of the targeted groundwater sampling and analysis for volatile organic compounds (VOCs) conducted in early 2010 (following completion of the fifth year of systems operation), to assess the initial five years of progress of the Utica remediation effort. On the basis of the 2003 groundwater sampling results, a remedial system employing 4 extraction wells (GWEX1-GWEX4), with groundwater treatment by spray irrigation and conventional air stripping, was implemented with the concurrence of the CCC/USDA and the agencies (Table 1.1). The principal components of the system are shown in Figure 1.3 and are briefly described in Section 1.2. Operation of well GWEX4 and the associated air stripper began on October 29, 2004, and routine operation of wells GWEX1-GWEX3 and the spray irrigation treatment units began on November 22, 2004.

  3. The Genome Sequence ofMethanohalophilus mahiiSLPTReveals Differences in the Energy Metabolism among Members of theMethanosarcinaceaeInhabiting Freshwater and Saline Environments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Spring, Stefan; Scheuner, Carmen; Lapidus, Alla; Lucas, Susan; Glavina Del Rio, Tijana; Tice, Hope; Copeland, Alex; Cheng, Jan-Fang; Chen, Feng; Nolan, Matt; et al

    2010-01-01

    Methanohalophilus mahiiis the type species of the genusMethanohalophilus, which currently comprises three distinct species with validly published names.Mhp. mahiirepresents moderately halophilic methanogenic archaea with a strictly methylotrophic metabolism. The type strain SLPTwas isolated from hypersaline sediments collected from the southern arm of Great Salt Lake, Utah. Here we describe the features of this organism, together with the complete genome sequence and annotation. The 2,012,424 bp genome is a single replicon with 2032 protein-coding and 63 RNA genes and part of theGenomic Encyclopedia of Bacteria and Archaeaproject. A comparison of the reconstructed energy metabolism in the halophilic speciesMhp. mahiiwith other representativesmoreof theMethanosarcinaceaereveals some interesting differences to freshwater species.less

  4. The Genome Sequence of Methanohalophilus mahii SLP T Reveals Differences in the Energy Metabolism among Members of the Methanosarcinaceae Inhabiting Freshwater and Saline Environments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Spring, Stefan; Scheuner, Carmen; Lapidus, Alla; Lucas, Susan; Glavina Del Rio, Tijana; Tice, Hope; Copeland, Alex; Cheng, Jan-Fang; Chen, Feng; Nolan, Matt; et al

    2010-01-01

    Methanohalophilus mahii is the type species of the genus Methanohalophilus , which currently comprises three distinct species with validly published names. Mhp. mahii represents moderately halophilic methanogenic archaea with a strictly methylotrophic metabolism. The type strain SLP T was isolated from hypersaline sediments collected from the southern arm of Great Salt Lake, Utah. Here we describe the features of this organism, together with the complete genome sequence and annotation. The 2,012,424 bp genome is a single replicon with 2032 protein-coding and 63 RNA genes and part of the Genomic Encyclopedia of Bacteria and Archaea project. A comparison of themore » reconstructed energy metabolism in the halophilic species Mhp. mahii with other representatives of the Methanosarcinaceae reveals some interesting differences to freshwater species.« less

  5. Lawrence Livermore National Laboratory (LLNL) Experimental Test Site (Site 300) Salinity Evaluation and Minimization Plan for Cooling Towers and Mechanical Equipment Discharges

    SciTech Connect (OSTI)

    Daily III, W D

    2010-02-24

    This document was created to comply with the Central Valley Regional Water Quality Control Board (CVRWQCB) Waste Discharge Requirement (Order No. 98-148). This order established new requirements to assess the effect of and effort required to reduce salts in process water discharged to the subsurface. This includes the review of technical, operational, and management options available to reduce total dissolved solids (TDS) concentrations in cooling tower and mechanical equipment water discharges at Lawrence Livermore National Laboratory's (LLNL's) Experimental Test Site (Site 300) facility. It was observed that for the six cooling towers currently in operation, the total volume of groundwater used as make up water is about 27 gallons per minute and the discharge to the subsurface via percolation pits is 13 gallons per minute. The extracted groundwater has a TDS concentration of 700 mg/L. The cooling tower discharge concentrations range from 700 to 1,400 mg/L. There is also a small volume of mechanical equipment effluent being discharged to percolation pits, with a TDS range from 400 to 3,300 mg/L. The cooling towers and mechanical equipment are maintained and operated in a satisfactory manner. No major leaks were identified. Currently, there are no re-use options being employed. Several approaches known to reduce the blow down flow rate and/or TDS concentration being discharged to the percolation pits and septic systems were reviewed for technical feasibility and cost efficiency. These options range from efforts as simple as eliminating leaks to implementing advanced and innovative treatment methods. The various options considered, and their anticipated effect on water consumption, discharge volumes, and reduced concentrations are listed and compared in this report. Based on the assessment, it was recommended that there is enough variability in equipment usage, chemistry, flow rate, and discharge configurations that each discharge location at Site 300 should be considered separately when deciding on an approach for reducing the salt discharge to the subsurface. The smaller units may justify moderate changes to equipment, and may benefit from increased cleaning frequencies, more accurate and suitable chemical treatment, and sources of make up water and discharge re-use. The larger cooling towers would be more suitable for automated systems where they don't already exist, re-circulation and treatment of blow down water, and enhanced chemical dosing strategies. It may be more technically feasible and cost efficient for the smaller cooling towers to be replaced by closed loop dry coolers or hybrid towers. There are several potential steps that could be taken at each location to reduce the TDS concentration and/or water use. These include: sump water filtration, minimization of drift, accurate chemical dosing, and use of scale and corrosion coupons for chemical calibration. The implementation of some of these options could be achieved by a step-wise approach taken at two representative facilities. Once viable prototype systems have been proven in the field, systematic implementation should proceed for the remaining systems, with cost, desired reduction, and general feasibility taken into consideration for such systems.

  6. Lake Whitney Comprehensive Water Quality Assessment, Phase 1B- Physical and Biological Assessment (USDOE)

    SciTech Connect (OSTI)

    Doyle, Robert D; Byars, Bruce W

    2009-11-24

    Baylor University Center for Reservoir and Aquatic Systems Research (CRASR) has conducted a phased, comprehensive evaluation of Lake Whitney to determine its suitability for use as a regional water supply reservoir. The area along the Interstate 35 corridor between Dallas / Fort Worth Metroplex and the Waco / Temple Centroplex represents one of the fastest growth areas in the State of Texas and reliable water supplies are critical to sustainable growth. Lake Whitney is situated midway between these two metropolitan areas. Currently, the City of Whitney as well as all of Bosque and Hill counties obtain their potable water from the Trinity Sands aquifer. Additionally, parts of the adjoining McLennan and Burleson counties utilize the Trinity sands aquifer system as a supplement to their surface water supplies. Population growth coupled with increasing demands on this aquifer system in both the Metroplex and Centroplex have resulted in a rapid depletion of groundwater in these rural areas. The Lake Whitney reservoir represents both a potentially local and regional solution for an area experiencing high levels of growth. Because of the large scope of this project as well as the local, regional and national implications, we have designed a multifaceted approach that will lead to the solution of numerous issues related to the feasibility of using Lake Whitney as a water resource to the region. Phase IA (USEPA, QAPP Study Elements 1-4) of this research focused on the physical limnology of the reservoir (bathymetry and fine scale salinity determination) and develops hydrodynamic watershed and reservoir models to evaluate how salinity would be expected to change with varying hydrologic and climatic factors. To this end, we implemented a basic water quality modeling program in collaboration with the Texas Parks and Wildlife Department and the Texas Commission on Environmental Quality to add to the developing long-term database on Lake Whitney. Finally, we conducted an initial assessment of knowledge of watershed and water quality related issues by local residents and stakeholders of Lake Whitney and design an intervention educational program to address any deficiencies discovered. Phase IA was funded primarily from EPA Cooperative Agreement X7-9769 8901-0. Phase IC (USEPA, QAPP Study Element 5) of this research focused on the ambient toxicity of the reservoir with respect to periodic blooms of golden algae. Phase IC was funded primarily from Cooperative Agreement EM-96638001. Phase 1B (USDOE, Study Elements 6-11) complemented work being done via EPA funding on study elements 1-5 and added five new study elements: 6) Salinity Transport in the Brazos Watershed to Lake Whitney; 7) Bacterial Assessment; 8) Organic Contaminant Analysis on Lake Whitney; 9) Plankton Photosynthesis; 10) Lake Whitney Resident Knowledge Assessment; and 11) Engineering Scoping Perspective: Recommendations for Use.

  7. Integrated Reflection Seismic Monitoring and Reservoir Modeling for Geologic CO2 Sequestration

    SciTech Connect (OSTI)

    John Rogers

    2011-12-31

    The US DOE/NETL CCS MVA program funded a project with Fusion Petroleum Technologies Inc. (now SIGMA) to model the proof of concept of using sparse seismic data in the monitoring of CO{sub 2} injected into saline aquifers. The goal of the project was to develop and demonstrate an active source reflection seismic imaging strategy based on deployment of spatially sparse surface seismic arrays. The primary objective was to test the feasibility of sparse seismic array systems to monitor the CO{sub 2} plume migration injected into deep saline aquifers. The USDOE/RMOTC Teapot Dome (Wyoming) 3D seismic and reservoir data targeting the Crow Mountain formation was used as a realistic proxy to evaluate the feasibility of the proposed methodology. Though the RMOTC field has been well studied, the Crow Mountain as a saline aquifer has not been studied previously as a CO{sub 2} sequestration (storage) candidate reservoir. A full reprocessing of the seismic data from field tapes that included prestack time migration (PSTM) followed by prestack depth migration (PSDM) was performed. A baseline reservoir model was generated from the new imaging results that characterized the faults and horizon surfaces of the Crow Mountain reservoir. The 3D interpretation was integrated with the petrophysical data from available wells and incorporated into a geocellular model. The reservoir structure used in the geocellular model was developed using advanced inversion technologies including Fusion's ThinMAN{trademark} broadband spectral inversion. Seal failure risk was assessed using Fusion's proprietary GEOPRESS{trademark} pore pressure and fracture pressure prediction technology. CO{sub 2} injection was simulated into the Crow Mountain with a commercial reservoir simulator. Approximately 1.2MM tons of CO{sub 2} was simulated to be injected into the Crow Mountain reservoir over 30 years and subsequently let 'soak' in the reservoir for 970 years. The relatively small plume developed from this injection was observed migrating due to gravity to the apexes of the double anticline in the Crow Mountain reservoir of the Teapot dome. Four models were generated from the reservoir simulation task of the project which included three saturation models representing snapshots at different times during and after simulated CO{sub 2} injection and a fully saturated CO{sub 2} fluid substitution model. The saturation models were used along with a Gassmann fluid substitution model for CO{sub 2} to perform fluid volumetric substitution in the Crow Mountain formation. The fluid substitution resulted in a velocity and density model for the 3D volume at each saturation condition that was used to generate a synthetic seismic survey. FPTI's (Fusion Petroleum Technologies Inc.) proprietary SeisModelPRO{trademark} full acoustic wave equation software was used to simulate acquisition of a 3D seismic survey on the four models over a subset of the field area. The simulated acquisition area included the injection wells and the majority of the simulated plume area.

  8. Coupled Fluid Energy Solute Transport

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    CFEST is a Coupled Fluid, Energy, and Solute Transport code for the study of a multilayered, nonisothermal ground-water system. It can model discontinuous as well as continuous layers, time-dependent and constant source/sinks, and transient as well as steady-state flow. The finite element method is used for analyzing isothermal and nonisothermal events in a confined aquifer system. Only single-phase Darcian flow is considered. In the Cartesian coordinate system, flow in a horizontal plane, in a verticalmore » plane, or in a fully three-dimensional region can be simulated. An option also exists for the axisymmetric analysis of a vertical cross section. The code employs bilinear quadrilateral elements in all two dimensional analyses and trilinear quadrilateral solid elements in three dimensional simulations. The CFEST finite element formulation can approximate discontinuities, major breaks in slope or thickness, and fault zones in individual hydrogeologic units. The code accounts for heterogeneity in aquifer permeability and porosity and accommodates anisotropy (collinear with the Cartesian coordinates). The variation in the hydraulic properties is described on a layer-by-layer basis for the different hydrogeologic units. Initial conditions can be prescribed hydraulic head or pressure, temperature, or concentration. CFEST can be used to support site, repository, and waste package subsystem assessments. Some specific applications are regional hydrologic characterization; simulation of coupled transport of fluid, heat, and salinity in the repository region; consequence assessment due to natural disruption or human intrusion scenarios in the repository region; flow paths and travel-time estimates for transport of radionuclides; and interpretation of well and tracer tests.« less

  9. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios K; Torres, Sharon G; Hakala, J Alexandra; Shao, Hongbo; Cantrell, Kirk J; Carroll, Susan

    2012-02-05

    Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising, however, possible CO₂ or CO₂-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define trace metal source terms from the reaction of supercritical CO₂, storage reservoir brines, reservoir and cap rocks. Storage reservoir source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from sandstones, shales, carbonates, evaporites, basalts and cements from the Frio, In Salah, Illinois Basin – Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution is tracked by measuring solution concentrations over time under conditions (e.g. pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for Maximum Contaminant Levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments due to the presence of CO₂. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rock exceed the MCLs by an order of magnitude while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the reservoir and caprock source term to further evaluate the impact of leakage on groundwater quality.

  10. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios; Torres, Sharon G.; Hakala, Jacqueline A.; Shao, Hongbo; Cantrell, Kirk J.; Carroll, Susan A.

    2013-01-01

    ABSTRACT: Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising; however, possible CO2 or CO2-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define to provide a range of concentrations that can be used as the trace element source term for reservoirs and leakage pathways in risk simulations. Storage source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from cements and sandstones, shales, carbonates, evaporites, and basalts from the Frio, In Salah, Illinois Basin, Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands, and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution was tracked by measuring solution concentrations over time under conditions (e.g., pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for maximum contaminant levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments because of the presence of CO2. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rocks exceed the MCLs byan order of magnitude, while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the trace element source term for reservoirs and leakage pathways in risk simulations to further evaluate the impact of leakage on groundwater quality.

  11. Intermediate Scale Laboratory Testing to Understand Mechanisms of Capillary and Dissolution Trapping during Injection and Post-Injection of CO2 in Heterogeneous Geological Formations

    SciTech Connect (OSTI)

    Illangasekare, Tissa; Trevisan, Luca; Agartan, Elif; Mori, Hiroko; Vargas-Johnson, Javier; Gonzalez-Nicolas, Ana; Cihan, Abdullah; Birkholzer, Jens; Zhou, Quanlin

    2015-03-31

    Carbon Capture and Storage (CCS) represents a technology aimed to reduce atmospheric loading of CO2 from power plants and heavy industries by injecting it into deep geological formations, such as saline aquifers. A number of trapping mechanisms contribute to effective and secure storage of the injected CO2 in supercritical fluid phase (scCO2) in the formation over the long term. The primary trapping mechanisms are structural, residual, dissolution and mineralization. Knowledge gaps exist on how the heterogeneity of the formation manifested at all scales from the pore to the site scales affects trapping and parameterization of contributing mechanisms in models. An experimental and modeling study was conducted to fill these knowledge gaps. Experimental investigation of fundamental processes and mechanisms in field settings is not possible as it is not feasible to fully characterize the geologic heterogeneity at all relevant scales and gathering data on migration, trapping and dissolution of scCO2. Laboratory experiments using scCO2 under ambient conditions are also not feasible as it is technically challenging and cost prohibitive to develop large, two- or three-dimensional test systems with controlled high pressures to keep the scCO2 as a liquid. Hence, an innovative approach that used surrogate fluids in place of scCO2 and formation brine in multi-scale, synthetic aquifers test systems ranging in scales from centimeter to meter scale developed used. New modeling algorithms were developed to capture the processes controlled by the formation heterogeneity, and they were tested using the data from the laboratory test systems. The results and findings are expected to contribute toward better conceptual models, future improvements to DOE numerical codes, more accurate assessment of storage capacities, and optimized placement strategies. This report presents the experimental and modeling methods and research results.

  12. Petroleum potential of lower and middle Paleozoic rocks in Nebraska portion of Mid-Continent

    SciTech Connect (OSTI)

    Carlson, M.P. )

    1989-08-01

    Central North America during the Paleozoic was characterized by northern (Williston) and southern (Anadarko) depositional regimes separated by a stable Transcontinental arch. Nebraska lies on the southern flank of this arch and contains the northern zero edges of the lower and middle Paleozoic rocks of the southern regime. Most of these rocks are secondary dolomites with zones of excellent intercrystalline porosity. The Reagan-LaMotte Sandstones and the overlying Arbuckle dolomites are overlapped by Middle Ordovician rocks toward the Transcontinental arch. Rocks equivalent to the Simpson consist of a basal sand (St. Peter) and overlying interbedded gray-green shales and dolomitic limestones. An uppermost shale facies is present in the Upper Ordovician (Viola-Maquoketa) eastward and southward across Nebraska. The dolomite facies extends northward into the Williston basin. The Silurian dolomites, originally more widely deposited, are overlapped by Devonian dolomites in southeastern Nebraska. Upper Devonian rocks exhibit a regional facies change from carbonate to green-gray shale to black shale southeastward across the Mid-Continent. Mississippian carbonates overlap the Devonian westward and northward across the Transcontinental arch. Pennsylvanian uplift and erosion were widespread, producing numerous stratigraphic traps. Sands related to the basal Pennsylvanian unconformity produce along the Cambridge arch. Arbuckle, Simpson, Viola, and Hunton production is present in the Forest City basin and along the Central Kansas uplift. Although source rocks are scarce and the maturation is marginal, current theories of long-distance oil migration encourage exploration in the extensive lower and middle Paleozoic reservoirs in this portion of the Mid-Continent.

  13. The geomechanics of CO{sub 2} storage in deep sedimentary formations

    SciTech Connect (OSTI)

    Rutqvist, J.

    2011-11-01

    This paper provides a review of the geomechanics and modeling of geomechanics associated with geologic carbon storage (GCS), focusing on storage in deep sedimentary formations, in particular saline aquifers. The paper first introduces the concept of storage in deep sedimentary formations, the geomechanical processes and issues related with such an operation, and the relevant geomechanical modeling tools. This is followed by a more detailed review of geomechanical aspects, including reservoir stress-strain and microseismicity, well integrity, caprock sealing performance, and the potential for fault reactivation and notable (felt) seismic events. Geomechanical observations at current GCS field deployments, mainly at the In Salah CO2 storage project in Algeria, are also integrated into the review. The In Salah project, with its injection into a relatively thin, low-permeability sandstone is an excellent analogue to the saline aquifers that might be used for large scale GCS in parts of Northwest Europe, the U.S. Midwest, and China. Some of the lessons learned at In Salah related to geomechanics are discussed, including how monitoring of geomechanical responses is used for detecting subsurface geomechanical changes and tracking fluid movements, and how such monitoring and geomechanical analyses have led to preventative changes in the injection parameters. Recently, the importance of geomechanics has become more widely recognized among GCS stakeholders, especially with respect to the potential for triggering notable (felt) seismic events and how such events could impact the long-term integrity of a CO{sub 2} repository (as well as how it could impact the public perception of GCS). As described in the paper, to date, no notable seismic event has been reported from any of the current CO{sub 2} storage projects, although some unfelt microseismic activities have been detected by geophones. However, potential future commercial GCS operations from large power plants will require injection at a much larger scale. For such largescale injections, a staged, learn-as-you-go approach is recommended, involving a gradual increase of injection rates combined with continuous monitoring of geomechanical changes, as well as siting beneath a multiple layered overburden for multiple flow barrier protection, should an unexpected deep fault reactivation occur.

  14. Probabilistic cost estimation methods for treatment of water extracted during CO2 storage and EOR

    SciTech Connect (OSTI)

    Graham, Enid J. Sullivan; Chu, Shaoping; Pawar, Rajesh J.

    2015-08-08

    Extraction and treatment of in situ water can minimize risk for large-scale CO2 injection in saline aquifers during carbon capture, utilization, and storage (CCUS), and for enhanced oil recovery (EOR). Additionally, treatment and reuse of oil and gas produced waters for hydraulic fracturing will conserve scarce fresh-water resources. Each treatment step, including transportation and waste disposal, generates economic and engineering challenges and risks; these steps should be factored into a comprehensive assessment. We expand the water treatment model (WTM) coupled within the sequestration system model CO2-PENS and use chemistry data from seawater and proposed injection sites in Wyoming, to demonstrate the relative importance of different water types on costs, including little-studied effects of organic pretreatment and transportation. We compare the WTM with an engineering water treatment model, utilizing energy costs and transportation costs. Specific energy costs for treatment of Madison Formation brackish and saline base cases and for seawater compared closely between the two models, with moderate differences for scenarios incorporating energy recovery. Transportation costs corresponded for all but low flow scenarios (<5000 m3/d). Some processes that have high costs (e.g., truck transportation) do not contribute the most variance to overall costs. Other factors, including feed-water temperature and water storage costs, are more significant contributors to variance. These results imply that the WTM can provide good estimates of treatment and related process costs (AACEI equivalent level 5, concept screening, or level 4, study or feasibility), and the complex relationships between processes when extracted waters are evaluated for use during CCUS and EOR site development.

  15. Probabilistic cost estimation methods for treatment of water extracted during CO2 storage and EOR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graham, Enid J. Sullivan; Chu, Shaoping; Pawar, Rajesh J.

    2015-08-08

    Extraction and treatment of in situ water can minimize risk for large-scale CO2 injection in saline aquifers during carbon capture, utilization, and storage (CCUS), and for enhanced oil recovery (EOR). Additionally, treatment and reuse of oil and gas produced waters for hydraulic fracturing will conserve scarce fresh-water resources. Each treatment step, including transportation and waste disposal, generates economic and engineering challenges and risks; these steps should be factored into a comprehensive assessment. We expand the water treatment model (WTM) coupled within the sequestration system model CO2-PENS and use chemistry data from seawater and proposed injection sites in Wyoming, to demonstratemore » the relative importance of different water types on costs, including little-studied effects of organic pretreatment and transportation. We compare the WTM with an engineering water treatment model, utilizing energy costs and transportation costs. Specific energy costs for treatment of Madison Formation brackish and saline base cases and for seawater compared closely between the two models, with moderate differences for scenarios incorporating energy recovery. Transportation costs corresponded for all but low flow scenarios (<5000 m3/d). Some processes that have high costs (e.g., truck transportation) do not contribute the most variance to overall costs. Other factors, including feed-water temperature and water storage costs, are more significant contributors to variance. These results imply that the WTM can provide good estimates of treatment and related process costs (AACEI equivalent level 5, concept screening, or level 4, study or feasibility), and the complex relationships between processes when extracted waters are evaluated for use during CCUS and EOR site development.« less

  16. Log analysis of six boreholes in conjunction with geologic characterization above and on top of the Weeks Island Salt Dome

    SciTech Connect (OSTI)

    Sattler, A.R.

    1996-06-01

    Six boreholes were drilled during the geologic characterization and diagnostics of the Weeks Island sinkhole that is over the two-tiered salt mine which was converted for oil storage by the U.S. Strategic Petroleum Reserve. These holes were drilled to provide for geologic characterization of the Weeks Island Salt Dome and its overburden in the immediate vicinity of the sinkhole (mainly through logs and core); to establish a crosswell configuration for seismic tomography; to establish locations for hydrocarbon detection and tracer injection; and to provide direct observations of sinkhole geometry and material properties. Specific objectives of the logging program were to: (1) identify the top of and the physical state of the salt dome; (2) identify the water table; (3) obtain a relative salinity profile in the aquifer within the alluvium, which ranges from the water table directly to the top of the Weeks Island salt dome; and (4) identify a reflecting horizon seen on seismic profiles over this salt dome. Natural gamma, neutron, density, sonic, resistivity and caliper logs were run.

  17. CONCEPTUAL DESIGN OF OPTIMIZED FOSSIL ENERGY SYSTEMS WITH CAPTURE AND SEQUESTRATION OF CARBON DIOXIDE

    SciTech Connect (OSTI)

    Joan M. Ogden

    2004-05-01

    In this third semi-annual progress report, we describe research results from an ongoing study of fossil hydrogen energy systems with CO{sub 2} sequestration. This work was performed under NETL Award No. DE-FC26-02NT41623, during the six-month period September 2003 through March 2004. The primary objective of the study is to better understand system design issues and economics for a large-scale fossil energy system co-producing H{sub 2} and electricity with CO{sub 2} sequestration. This is accomplished by developing analytic and simulation methods for studying the entire system in an integrated way. We examine the relationships among the different parts of a hydrogen energy system, and attempt to identify which variables are the most important in determining both the disposal cost of CO{sub 2} and the delivered cost of H{sub 2}. A second objective is to examine possible transition strategies from today's energy system toward one based on fossil-derived H{sub 2} and electricity with CO{sub 2} sequestration. We are carrying out a geographically specific case study of development of a fossil H{sub 2} system with CO{sub 2} sequestration, for the Midwestern United States, where there is presently substantial coal conversion capacity in place, coal resources are plentiful and potential sequestration sites in deep saline aquifers are widespread.

  18. CONCEPTUAL DESIGN OF OPTIMIZED FOSSIL ENERGY SYSTEMS WITH CAPTURE AND SEQUESTRATION OF CARBON DIOXIDE

    SciTech Connect (OSTI)

    Joan M. Ogden

    2003-06-26

    In this semi-annual progress report, we describe research results from an ongoing study of fossil hydrogen energy systems with CO{sub 2} sequestration. This work was performed under NETL Award No. DE-FC26-02NT41623, during the six-month period September 2002 through March 2003. The primary objective of the study is to better understand system design issues and economics for a large-scale fossil energy system co-producing H{sub 2} and electricity with CO{sub 2} sequestration. This is accomplished by developing analytic and simulation methods for studying the entire system in an integrated way. We examine the relationships among the different parts of a hydrogen energy system, and attempt to identify which variables are the most important in determining both the disposal cost of CO{sub 2} and the delivered cost of H{sub 2}. A second objective is to examine possible transition strategies from today's energy system toward one based on fossil-derived H{sub 2} and electricity with CO{sub 2} sequestration. We are carrying out a geographically specific case study of development of a fossil H{sub 2} system with CO{sub 2} sequestration, for the Midwestern United States, where there is presently substantial coal conversion capacity in place, coal resources are plentiful and potential sequestration sites in deep saline aquifers are widespread.

  19. Conceptual Design of Optimized Fossil Energy Systems with Capture and Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Joan M. Ogden

    2005-11-29

    In this final progress report, we describe research results from Phase I of a technical/economic study of fossil hydrogen energy systems with CO{sub 2} sequestration. This work was performed under NETL Award No. DE-FC26-02NT41623, during the period September 2002 through August 2005 The primary objective of the study is to better understand system design issues and economics for a large-scale fossil energy system co-producing H{sub 2} and electricity with CO{sub 2} sequestration. This is accomplished by developing analytic and simulation methods for studying the entire system in an integrated way. We examine the relationships among the different parts of a hydrogen energy system, and identify which variables are the most important in determining both the disposal cost of CO{sub 2} and the delivered cost of H{sub 2}. A second objective is to examine possible transition strategies from today's energy system toward one based on fossil-derived H{sub 2} and electricity with CO{sub 2} sequestration. We carried out a geographically specific case study of development of a fossil H{sub 2} system with CO{sub 2} sequestration, for the Midwestern United States, where there is presently substantial coal conversion capacity in place, coal resources are plentiful and potential sequestration sites in deep saline aquifers are widespread.

  20. CONCEPTUAL DESIGN OF OPTIMIZED FOSSIL ENERGY SYSTEMS WITH CAPTURE AND SEQUESTRATION OF CARBON DIOXIDE

    SciTech Connect (OSTI)

    Joan M. Ogden

    2003-12-01

    In this second semi-annual progress report, we describe research results from an ongoing study of fossil hydrogen energy systems with CO{sub 2} sequestration. This work was performed under NETL Award No. DE-FC26-02NT41623, during the six-month period March 2003 through September 2003. The primary objective of the study is to better understand system design issues and economics for a large-scale fossil energy system co-producing H{sub 2} and electricity with CO{sub 2} sequestration. This is accomplished by developing analytic and simulation methods for studying the entire system in an integrated way. We examine the relationships among the different parts of a hydrogen energy system, and attempt to identify which variables are the most important in determining both the disposal cost of CO{sub 2} and the delivered cost of H{sub 2}. A second objective is to examine possible transition strategies from today's energy system toward one based on fossil-derived H{sub 2} and electricity with CO{sub 2} sequestration. We are carrying out a geographically specific case study of development of a fossil H{sub 2} system with CO{sub 2} sequestration, for the Midwestern United States, where there is presently substantial coal conversion capacity in place, coal resources are plentiful and potential sequestration sites in deep saline aquifers are widespread.

  1. Biodiesel from aquatic species. Project report: FY 1993

    SciTech Connect (OSTI)

    Brown, L.M.; Sprague, S.; Jarvis, E.E.; Dunahay, T.G.; Roessler, P.G.; Zeiler, K.G.

    1994-01-01

    Researchers in the Biodiesel/Aquatic Species Project focus on the use of microalgae as a feedstock for producing renewable, high-energy liquid fuels. The program`s basic premise is that microalgae, which have been called the most productive biochemical factories in the world, can produce up to 30 times more oil per unit of growth area than land plants. It is estimated that 150 to 400 barrels of oil per acre per year (0.06 to 0.16 million liters/hectar) could be produced with microalgal oil technology. Initial commercialization of this technology is envisioned for the desert Southwest because this area provides high solar radiation and offers flat land that has few competing uses (hence low land costs). Similarly, there are large saline aquifers with few competing uses in the region. This water source could provide a suitable, low-cost medium for the growth of many microalgae. The primary area of research during FY 1993 was the effort to genetically improve microalgae in order to control the timing and magnitude of lipid accumulation. Increased lipid content will have a direct effect on fuel price, and the control of lipid content is a major project goal. The paper describes progress on the following: culture collection; molecular biology of lipid biosynthesis; microalgal transformation; and environmental, safety, and health and quality assurance.

  2. Modeling long-term CO2 storage, sequestration and cycling

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-11-11

    The application of numerical and analytical models to the problem of storage, sequestration and migration of carbon dioxide in geologic formations is discussed. A review of numerical and analytical models that have been applied to CO2 sequestration are presented, as well as a description of frameworks for risk analysis. Application of models to various issues related to carbon sequestration are discussed, including trapping mechanisms, density convection mixing, impurities in the CO2 stream, changes in formation porosity and permeability, the risk of vertical leakage, and the impacts on groundwater resources if leakage does occur. A discussion of the development and application of site-specific models first addresses the estimation of model parameters and the use of natural analogues to inform the development of CO2 sequestration models, and then surveys modeling that has been done at two commercial-scale CO2 sequestration sites, Sleipner and In Salah, along with a pilot-scale injection sites used to study CO2 sequestration in saline aquifers (Frio) and an experimental site designed to test monitoring of CO2 leakage in the vadose zone (ZERT Release Facility).

  3. Internet Based, GIS Catalog of Non-Traditional Sources of Cooling Water for Use at America's Coal-Fired Power Plants

    SciTech Connect (OSTI)

    J. Daniel Arthur

    2011-09-30

    In recent years, rising populations and regional droughts have caused coal-fired power plants to temporarily curtail or cease production due to a lack of available water for cooling. In addition, concerns about the availability of adequate supplies of cooling water have resulted in cancellation of plans to build much-needed new power plants. These issues, coupled with concern over the possible impacts of global climate change, have caused industry and community planners to seek alternate sources of water to supplement or replace existing supplies. The Department of Energy, through the National Energy Technology Laboratory (NETL) is researching ways to reduce the water demands of coal-fired power plants. As part of the NETL Program, ALL Consulting developed an internet-based Catalog of potential alternative sources of cooling water. The Catalog identifies alternative sources of water, such as mine discharge water, oil and gas produced water, saline aquifers, and publicly owned treatment works (POTWs), which could be used to supplement or replace existing surface water sources. This report provides an overview of the Catalog, and examines the benefits and challenges of using these alternative water sources for cooling water.

  4. The lifetime of carbon capture and storage as a climate-change mitigation technology

    SciTech Connect (OSTI)

    Juanes, Ruben

    2013-12-30

    In carbon capture and storage (CCS), CO2 is captured at power plants and then injected underground into reservoirs like deep saline aquifers for long-term storage. While CCS may be critical for the continued use of fossil fuels in a carbon-constrained world, the deployment of CCS has been hindered by uncertainty in geologic storage capacities and sustainable injection rates, which has contributed to the absence of concerted government policy. Here, we clarify the potential of CCS to mitigate emissions in the United States by developing a storage-capacity supply curve that, unlike current large-scale capacity estimates, is derived from the fluid mechanics of CO2 injection and trapping and incorporates injection-rate constraints. We show that storage supply is a dynamic quantity that grows with the duration of CCS, and we interpret the lifetime of CCS as the time for which the storage supply curve exceeds the storage demand curve from CO2 production. We show that in the United States, if CO2 production from power generation continues to rise at recent rates, then CCS can store enough CO2 to stabilize emissions at current levels for at least 100 years. This result suggests that the large-scale implementation of CCS is a geologically viable climate-change mitigation option in the United States over the next century.

  5. Uncertainty Quantification in CO{sub 2} Sequestration Using Surrogate Models from Polynomial Chaos Expansion

    SciTech Connect (OSTI)

    Zhang, Yan; Sahinidis, Nikolaos V.

    2013-04-06

    In this paper, surrogate models are iteratively built using polynomial chaos expansion (PCE) and detailed numerical simulations of a carbon sequestration system. Output variables from a numerical simulator are approximated as polynomial functions of uncertain parameters. Once generated, PCE representations can be used in place of the numerical simulator and often decrease simulation times by several orders of magnitude. However, PCE models are expensive to derive unless the number of terms in the expansion is moderate, which requires a relatively small number of uncertain variables and a low degree of expansion. To cope with this limitation, instead of using a classical full expansion at each step of an iterative PCE construction method, we introduce a mixed-integer programming (MIP) formulation to identify the best subset of basis terms in the expansion. This approach makes it possible to keep the number of terms small in the expansion. Monte Carlo (MC) simulation is then performed by substituting the values of the uncertain parameters into the closed-form polynomial functions. Based on the results of MC simulation, the uncertainties of injecting CO{sub 2} underground are quantified for a saline aquifer. Moreover, based on the PCE model, we formulate an optimization problem to determine the optimal CO{sub 2} injection rate so as to maximize the gas saturation (residual trapping) during injection, and thereby minimize the chance of leakage.

  6. Sensitivity of injection costs to input petrophysical parameters in numerical geologic carbon sequestration models

    SciTech Connect (OSTI)

    Cheng, C. L.; Gragg, M. J.; Perfect, E.; White, Mark D.; Lemiszki, P. J.; McKay, L. D.

    2013-08-24

    Numerical simulations are widely used in feasibility studies for geologic carbon sequestration. Accurate estimates of petrophysical parameters are needed as inputs for these simulations. However, relatively few experimental values are available for CO2-brine systems. Hence, a sensitivity analysis was performed using the STOMP numerical code for supercritical CO2 injected into a model confined deep saline aquifer. The intrinsic permeability, porosity, pore compressibility, and capillary pressure-saturation/relative permeability parameters (residual liquid saturation, residual gas saturation, and van Genuchten alpha and m values) were varied independently. Their influence on CO2 injection rates and costs were determined and the parameters were ranked based on normalized coefficients of variation. The simulations resulted in differences of up to tens of millions of dollars over the life of the project (i.e., the time taken to inject 10.8 million metric tons of CO2). The two most influential parameters were the intrinsic permeability and the van Genuchten m value. Two other parameters, the residual gas saturation and the residual liquid saturation, ranked above the porosity. These results highlight the need for accurate estimates of capillary pressure-saturation/relative permeability parameters for geologic carbon sequestration simulations in addition to measurements of porosity and intrinsic permeability.

  7. Biodiesel/Aquatic Species Project report, FY 1992

    SciTech Connect (OSTI)

    Brown, L.; Jarvis, E.; Dunahay, T.; Roessler, P.; Zeiler, K. ); Sprague, S. )

    1993-05-01

    The primary goal of the Biodiesel/Aquatic Species Project is to develop the technology for growing microalgae as a renewable biomass feedstock for the production of a diesel fuel substitute (biodiesel), thereby reducing the need for imported petroleum. Microalgae are of interest as a feedstock because of their high growth rates and tolerance to varying environmental conditions, and because the oils (lipids) they produce can be extracted and converted to substitute petroleum fuels such as biodiesel. Microalgae can be grown in arid and semi-arid regions with poor soil quality, and saline water from aquifers or the ocean can be used for growing microalgae. Biodiesel is an extremely attractive candidate to fulfill the need for a diesel fuel substitute. Biodiesel is a cleaner fuel than petroleum diesel; it is virtually free of sulfur, and emissions of hydrocarbons, carbon monoxide, and particulates during combustion are significantly reduced in comparison to emissions from petroleum diesel. Biodiesel provides essentially the same energy content and power output as petroleum-based diesel fuel.

  8. TOUGHREACT V2

    Energy Science and Technology Software Center (OSTI)

    2011-12-01

    TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media. The program is written in Fortran 77 and was developed by introducing reactive chemistry into the multiphase flow code TOUGH2 V2. Interactions between mineral assemblages and fluids can occur under local equilibrium or kinetic rates. The gas phase can be chemically active. Precipitation and dissolution reactions can change formation porosity and permeability, and can also modifymore » the unsaturated flow properties of the rock. The code is distributed with a comprehensive user?s guide that includes sample problems addressing geothermal reservoirs and hydrothermal systems, nuclear waste isolation, groundwater quality, sequestration of carbon dioxide in saline aquifers, and supergene copper enrichment. The TOUGHREACT V2 package supports the following fluid property modules packaged into TOUGH2 V2.0 (CR-1574): EOS1, EOS2, EOS3, EOS4, EOS7, EOS9, and ECO2N. New features in V2 include multi-site surface complexation and ion exchange, aqueous kinetics, restructuring for faster execution, and more flexible input formats.« less

  9. ECO2N V2.0

    Energy Science and Technology Software Center (OSTI)

    2015-02-01

    ECO2N V2.0 is a fluid property module for the TOUGH2 simulator (Version 2.1) that was designed for applications to geologic sequestration of CO2 in saline aquifers and enhanced geothermal reservoirs. ECO2N V2.0 is an enhanced version of the previous ECO2N V1.0 module (Pruess, 2005). It expands the temperature range up to about 300oC whereas V1.0 can only be used for temperatures below about 110oC. V2.0 includes a comprehensive description of the thermodynamic and thermophysical propertiesmore » of H2O - NaCl - CO2 mixtures, that reproduces fluid properties largely within experimental error for the temperature, pressure and salinity conditions 10 °C < T < 300 °C, P < 600 bar, and salinity up to halite saturation. This includes density, viscosity, and specific enthalpy of fluid phases as functions of temperature, pressure, and composition, as well as partitioning of mass components H2O, NaCl and CO2 among the different phases. In particular, V2.0 accounts for the effects of water on the thermophysical properties of the CO2-rich phase, which was ignored in V1.0, using a model consistent with the solubility models developed by Spycher and Pruess (2005, 2010). In terms of solubility models, V2.0 uses the same model for partitioning of mass components among the different phases (Spycher and Pruess, 2005) as V1.0 for the low temperature range (<99oC) but uses a new model (Spycher and Pruess, 2010) for the high temperature range (>109oC). In the transition range (99-109oC), a smooth interpolation is applied to estimate the partitioning as a function of the temperature. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO2-rich) phase, as well as two-phase (brine-CO2) mixtures. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. Note that the model cannot be applied to subcritical conditions that involves both liquid and gaseous CO2 unless thermol process is ignored (i.e.,isothermal run). For those cases, a user may use the fluid property module ECO2M (Pruess, 2011) instead« less

  10. Microsoft Word - S03840_MNT ZVI Treat Cells_Feb08.doc

    Office of Legacy Management (LM)

    Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at ... ESL-RPT-2008-01 Ground-Water Table and Chemical Changes in an Alluvial Aquifer During ...

  11. Microsoft Word - treact_manual.doc

    Office of Scientific and Technical Information (OSTI)

    ... Aquifer, Maryland (EOS9) NaHCO 3 type waters in coastal plain aquifers of the eastern ... No dispersion is allowed in TOUGHREACT. We treated the dispersion in a similar way as ...

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... updated). Monitoring wells with an "SC" suffix are completed in the upper sand aquifer of the Wind River Formation. Wells with a "DC" suffix are completed in the main sand aquifer. ...

  13. Microsoft Word - 10063127 DVP

    Office of Legacy Management (LM)

    ... updated). Monitoring wells with an "SC" suffix are completed in the upper sand aquifer of the Wind River Formation. Wells with a "DC" suffix are completed in the main sand aquifer. ...

  14. Microsoft Word - RIN 12064635 DVP

    Office of Legacy Management (LM)

    ... updated). Monitoring wells with an "SC" suffix are completed in the upper sand aquifer of the Wind River Formation. Wells with a "DC" suffix are completed in the main sand aquifer. ...

  15. Microsoft Word - 08071744_DocProd.doc

    Office of Legacy Management (LM)

    the Wind River Formation. Wells with a "DC" suffix are completed in the Main Sand aquifer, and K.G.S.3 well is completed in the uncontaminated Lower Sand aquifer of the Wind ...

  16. Microsoft Word - RIN 11063905 DVP

    Office of Legacy Management (LM)

    ... updated). Monitoring wells with an "SC" suffix are completed in the upper sand aquifer of the Wind River Formation. Wells with a "DC" suffix are completed in the main sand aquifer. ...

  17. Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing

    Office of Scientific and Technical Information (OSTI)

    Carbonate Aquifer (Journal Article) | SciTech Connect Journal Article: Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer Citation Details In-Document Search Title: Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer Multiphase, reactive transport modeling was used to identify the mechanisms controlling trace metal release under elevated CO2 conditions from a well-characterized carbonate aquifer. Modeling

  18. Results of Detailed Hydrologic Characterization Tests - Fiscal Year 2003

    SciTech Connect (OSTI)

    Spane, Frank A.; Newcomer, Darrell R.

    2004-09-13

    This report presents results obtained from detailed hydrologic characterization of the unconfined aquifer system conducted at the Hanford Site.

  19. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    AQUIFERS; EXPERIMENTAL DATA; GEOLOGIC STRUCTURES; GEOTHERMAL FLUIDS; GEOTHERMAL WELLS; PRODUCTION; SAND; DATA; ENERGY SYSTEMS; FLUIDS; GEOLOGY; INFORMATION; NORTH AMERICA;...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Energy Technology Engineering Center (ETEC), Canoga ... sciences (22) water (22) aquifers (21) ... power plants, into deep, stable geologicformations, ...

  1. quality guidelines | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    levels are provided for limitations of carbon steel pipelines, enhanced oil recovery (EOR), saline reservoir sequestration, and cosequestration of CO2 and H2S in saline...

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Energy Technology Engineering Center (ETEC), Canoga ... Systems Xu, Tianfu Deep saline formations and oil ... to moderately saline water (up to 6 molal for an ...

  3. Integrated mineralogical and fluid inclusion study of the Coso...

    Open Energy Info (EERE)

    inclusion homogenization temperatures and salinities demonstrate that cool, low salinity ground waters were present when the thermal plume was emplaced. Dilution of the thermal...

  4. Clean Cities: Arkansas Clean Cities coalition

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Arkansas by using alternate modes of transportation. She is also a member of the Saline Green Committee that increases awareness of the importance of reducing Saline County's...

  5. Compressed air energy storage: preliminary design and site development program in an aquifer. Final draft, Task 2: Volume 2 of 3. Characterize and explore potential sites and prepare research and development plan

    SciTech Connect (OSTI)

    1980-12-01

    The characteristics of sites in Indiana and Illinois which are being investigated as potential sites for compressed air energy storage power plants are documented. These characteristics include geological considerations, economic factors, and environmental considerations. Extensive data are presented for 14 specific sites and a relative rating on the desirability of each site is derived. (LCL)

  6. MODELING OF THE GROUNDWATER TRANSPORT AROUND A DEEP BOREHOLE NUCLEAR WASTE REPOSITORY

    SciTech Connect (OSTI)

    N. Lubchenko; M. Rodríguez-Buño; E.A. Bates; R. Podgorney; E. Baglietto; J. Buongiorno; M.J. Driscoll

    2015-04-01

    The concept of disposal of high-level nuclear waste in deep boreholes drilled into crystalline bedrock is gaining renewed interest and consideration as a viable mined repository alternative. A large amount of work on conceptual borehole design and preliminary performance assessment has been performed by researchers at MIT, Sandia National Laboratories, SKB (Sweden), and others. Much of this work relied on analytical derivations or, in a few cases, on weakly coupled models of heat, water, and radionuclide transport in the rock. Detailed numerical models are necessary to account for the large heterogeneity of properties (e.g., permeability and salinity vs. depth, diffusion coefficients, etc.) that would be observed at potential borehole disposal sites. A derivation of the FALCON code (Fracturing And Liquid CONvection) was used for the thermal-hydrologic modeling. This code solves the transport equations in porous media in a fully coupled way. The application leverages the flexibility and strengths of the MOOSE framework, developed by Idaho National Laboratory. The current version simulates heat, fluid, and chemical species transport in a fully coupled way allowing the rigorous evaluation of candidate repository site performance. This paper mostly focuses on the modeling of a deep borehole repository under realistic conditions, including modeling of a finite array of boreholes surrounded by undisturbed rock. The decay heat generated by the canisters diffuses into the host rock. Water heating can potentially lead to convection on the scale of thousands of years after the emplacement of the fuel. This convection is tightly coupled to the transport of the dissolved salt, which can suppress convection and reduce the release of the radioactive materials to the aquifer. The purpose of this work has been to evaluate the importance of the borehole array spacing and find the conditions under which convective transport can be ruled out as a radionuclide transport mechanism. Preliminary results show that modeling of the borehole array, including the surrounding rock, predicts convective flow in the system with physical velocities of the order of 10-5 km/yr over 105 years. This results in an escape length on the order of kilometers, which is comparable to the repository depth. However, a correct account of the salinity effects reduces convection velocity and escape length of the radionuclides from the repository.

  7. Intelligent Leak Detection System

    SciTech Connect (OSTI)

    2014-10-27

    apability of underground carbon dioxide storage to confine and sustain injected CO2 for a very long time is the main concern for geologic CO2 sequestration. If a leakage from a geological CO2 sequestration site occurs, it is crucial to find the approximate amount and the location of the leak in order to implement proper remediation activity. An overwhelming majority of research and development for storage site monitoring has been concentrated on atmospheric, surface or near surface monitoring of the sequestered CO2. This study aims to monitor the integrity of CO2 storage at the reservoir level. This work proposes developing in-situ CO2 Monitoring and Verification technology based on the implementation of Permanent Down-hole Gauges (PDG) or ?Smart Wells? along with Artificial Intelligence and Data Mining (AI&DM). The technology attempts to identify the characteristics of the CO2 leakage by de-convolving the pressure signals collected from Permanent Down-hole Gauges (PDG). Citronelle field, a saline aquifer reservoir, located in the U.S. was considered for this study. A reservoir simulation model for CO2 sequestration in the Citronelle field was developed and history matched. The presence of the PDGs were considered in the reservoir model at the injection well and an observation well. High frequency pressure data from sensors were collected based on different synthetic CO2 leakage scenarios in the model. Due to complexity of the pressure signal behaviors, a Machine Learning-based technology was introduced to build an Intelligent Leakage Detection System (ILDS). The ILDS was able to detect leakage characteristics in a short period of time (less than a day) demonstrating the capability of the system in quantifying leakage characteristics subject to complex rate behaviors. The performance of ILDS was examined under different conditions such as multiple well leakages, cap rock leakage, availability of an additional monitoring well, presence of pressure drift and noise in the pressure sensor and uncertainty in the reservoir model.

  8. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect (OSTI)

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  9. Evaluating the Suitability for CO2 Storage at the FutureGen 2.0 Site, Morgan County, Illinois, USA

    SciTech Connect (OSTI)

    Bonneville, Alain; Gilmore, Tyler J.; Sullivan, E. C.; Vermeul, Vincent R.; Kelley, Mark E.; White, Signe K.; Appriou, Delphine; Bjornstad, Bruce N.; Gerst, Jacqueline L.; Gupta, Neeraj; Horner, Jacob A.; McNeil, Caitlin; Moody, Mark A.; Rike, William M.; Spane, Frank A.; Thorne, Paul D.; Zeller, Evan R.; Zhang, Z. F.; Hoffman, Jeffrey; Humphreys, Kenneth K.

    2013-08-05

    FutureGen 2.0 site will be the first near-zero emission power plant with fully integrated long-term storage in a deep, non-potable saline aquifer in the United States. The proposed FutureGen 2.0 CO2 storage site is located in northeast Morgan County, Illinois, U.S.A., forty-eight kilometres from the Meredosia Energy Center where a large-scale oxy-combustion demonstration will be conducted. The demonstration will involve > 90% carbon capture, which will produce more than one million metric tons (MMT) of CO2 per year. The CO2 will be compressed at the power plant and transported via pipeline to the storage site. To examine CO2 storage potential of the site, a 1,467m characterization well (FGA#1) was completed in December 2011. The target reservoir for CO2 storage is the Mt. Simon Sandstone and Elmhurst Sandstone Member of the lower Eau Claire Formation for a combined thickness of 176 m. Confining beds of the overlying Lombard and Proviso Members (upper Eau Claire Formation) reach a thickness of 126 m. Characterization of the target injection zone and the overlying confining zone was based on wellbore data, cores, and geophysical logs, along with surface geophysical (2-D seismic profiles, magnetic and gravity), and structural data collected during the initial stage of the project . Based on this geological model, 3D simulations of CO2 injection and redistribution were conducted using STOMP-CO2, a multiphase flow and transport simulator. After this characterization stage, it appears that the injection site is a suitable geologic system for CO2 sequestration and that the injection zone is sufficient to receive up to 33 MMT of CO2 at a rate of 1.1 MMT/yr. GHGT-11 conference

  10. A Sea Floor Gravity Survey of the Sleipner Field to Monitor CO2 Migration

    SciTech Connect (OSTI)

    Mark Zumberge

    2011-09-30

    Carbon dioxide gas (CO{sub 2}) is a byproduct of many wells that produce natural gas. Frequently the CO{sub 2} separated from the valuable fossil fuel gas is released into the atmosphere. This adds to the growing problem of the climatic consequences of greenhouse gas contamination. In the Sleipner North Sea natural gas production facility, the separated CO{sub 2} is injected into an underground saline aquifer to be forever sequestered. Monitoring the fate of such sequestered material is important - and difficult. Local change in Earth's gravity field over the injected gas is one way to detect the CO{sub 2} and track its migration within the reservoir over time. The density of the injected gas is less than that of the brine that becomes displaced from the pore space of the formation, leading to slight but detectable decrease in gravity observed on the seafloor above the reservoir. Using equipment developed at Scripps Institution of Oceanography, we have been monitoring gravity over the Sleipner CO{sub 2} sequestration reservoir since 2002. We surveyed the field in 2009 in a project jointly funded by a consortium of European oil and gas companies and the US Department of Energy. The value of gravity at some 30 benchmarks on the seafloor, emplaced at the beginning of the monitoring project, was observed in a week-long survey with a remotely operated vehicle. Three gravity meters were deployed on the benchmarks multiple times in a campaign-style survey, and the measured gravity values compared to those collected in earlier surveys. A clear signature in the map of gravity differences is well correlated with repeated seismic surveys.

  11. Understanding Carbon Sequestration Options in the United States: Capabilities of a Carbon Management Geographic Information System

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Dooley, James J.; Brown, Daryl R.; Mizoguchi, Akiyoshi; Shiozaki, Mai

    2001-04-03

    While one can discuss various sequestration options at a national or global level, the actual carbon management approach is highly site specific. In response to the need for a better understanding of carbon management options, Battelle in collaboration with Mitsubishi Corporation, has developed a state-of-the-art Geographic Information System (GIS) focused on carbon capture and sequestration opportunities in the United States. The GIS system contains information (e.g., fuel type, location, vintage, ownership, rated capacity) on all fossil-fired generation capacity in the Untied States with a rated capacity of at least 100 MW. There are also data on other CO2 sources (i.e., natural domes, gas processing plants, etc.) and associated pipelines currently serving enhanced oil recovery (EOR) projects. Data on current and prospective CO2 EOR projects include location, operator, reservoir and oil characteristics, production, and CO2 source. The system also contains information on priority deep saline aquifers and coal bed methane basins with potential for sequestering CO2. The GIS application not only enables data storage, flexible map making, and visualization capabilities, but also facilitates the spatial analyses required to solve complex linking of CO2 sources with appropriate and cost-effective sinks. A variety of screening criteria (spatial, geophysical, and economic) can be employed to identify sources and sinks most likely amenable to deployment of carbon capture and sequestration systems. The system is easily updateable, allowing it to stay on the leading edge of capture and sequestration technology as well as the ever-changing business landscape. Our paper and presentation will describe the development of this GIS and demonstrate its uses for carbon management analysis.

  12. Matrix effect of sodium compounds on the determination of metal ions in aqueous solutions by underwater laser-induced breakdown spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Goueguel, Christian; McIntyre, Dustin L.; Jain, Jinesh; Karamalidis, Athanasios K.; Carson, Cantwell

    2015-06-30

    A significant portion of the carbon sequestration research being performed in the United States involves the risk assessment of injecting large quantities of carbon dioxide into deep saline aquifers. Leakage of CO2 has the potential to affect the quality of groundwater supplies in case contaminants migrate through underlying conduits. New remote sensing and near-surface monitoring technologies are needed to ensure that injection, abandoned, and monitoring wells are structurally sound, and that CO2 remains within the geologic storage reservoir. In this paper, we propose underwater laser-induced breakdown spectroscopy (underwater LIBS) as an analytical method for monitoring naturally occurring elements that canmore » act as tracers to detect a CO2 leak from storage sites. Laboratory-scale experiments were conducted to measure Sr2+, Ca2+, K+, and Li+ in bulk solutions to ascertain the analytical performance of underwater LIBS. We compared the effect of NaCl, Na2CO3, and Na2SO4 on the analytes calibration curves to determine underwater LIBS’ ability to analyze samples of sodium compounds. In all cases, the calibration curves showed a good linearity within 2 orders of magnitude. The limit of detections (LODs) obtained for K+ (30±1 ppb) and Li+ (60±2 ppb) were in ppb range, while higher LODs were observed for Ca2+ (0.94±0.14 ppm) and Sr2+ (2.89±0.11 ppm). Evaluation of the calibration curves for the analytes in mixed solutions showed dependence of the lines’ intensity with the sodium compounds. The intensities increased respectively in the presence of dissolved NaCl and Na2SO4, whereas the intensities slightly decreased in the presence of Na2CO3. Lastly, the capabilities of underwater LIBS to detect certain elements in the ppb or in the low ppm range make it particularly appealing for in situ monitoring of a CO2 leak.« less

  13. Leakage Risk Assessment for a Potential CO2 Storage Project in Saskatchewan, Canada

    SciTech Connect (OSTI)

    Houseworth, J.E.; Oldenburg, C.M.; Mazzoldi, A.; Gupta, A.K.; Nicot, J.-P.; Bryant, S.L.

    2011-05-01

    A CO{sub 2} sequestration project is being considered to (1) capture CO{sub 2} emissions from the Consumers Cooperative Refineries Limited at Regina, Saskatchewan and (2) geologically sequester the captured CO{sub 2} locally in a deep saline aquifer. This project is a collaboration of several industrial and governmental organizations, including the Petroleum Technology Research Centre (PTRC), Sustainable Development Technology Canada (SDTC), SaskEnvironment Go Green Fund, SaskPower, CCRL, Schlumberger Carbon Services, and Enbridge. The project objective is to sequester 600 tonnes CO{sub 2}/day. Injection is planned to start in 2012 or 2013 for a period of 25 years for a total storage of approximately 5.5 million tonnes CO{sub 2}. This report presents an assessment of the leakage risk of the proposed project using a methodology known as the Certification Framework (CF). The CF is used for evaluating CO{sub 2} leakage risk associated with geologic carbon sequestration (GCS), as well as brine leakage risk owing to displacement and pressurization of brine by the injected CO{sub 2}. We follow the CF methodology by defining the entities (so-called Compartments) that could be impacted by CO{sub 2} leakage, the CO{sub 2} storage region, the potential for leakage along well and fault pathways, and the consequences of such leakage. An understanding of the likelihood and consequences of leakage forms the basis for understanding CO{sub 2} leakage risk, and forms the basis for recommendations of additional data collection and analysis to increase confidence in the risk assessment.

  14. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30

    This project involves the use of an innovative new invention � Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude oilcontaining formations or saline aquifers. The term �globule� refers to the water or liquid carbon dioxide droplets sheathed with ultrafine particles dispersed in the continuous external medium, liquid CO{sub 2} or H{sub 2}O, respectively. The key to obtaining very small globules is the shear force acting on the two intermixing fluids, and the use of ultrafine stabilizing particles or nanoparticles. We found that using Kenics-type static mixers with a shear rate in the range of 2700 to 9800 s{sup -1} and nanoparticles between 100-300 nm produced globule sizes in the 10 to 20 μm range. Particle stabilized emulsions with that kind of globule size should easily penetrate oil-bearing formations or saline aquifers where the pore and throat size can be on the order of 50 μm or larger. Subsequent research focused on creating particle stabilized emulsions that are deemed particularly suitable for Permanent Sequestration of Carbon Dioxide. Based on a survey of the literature an emulsion consisting of 70% by volume of water, 30% by volume of liquid or supercritical carbon dioxide, and 2% by weight of finely pulverized limestone (CaCO{sub 3}) was selected as the most promising agent for permanent sequestration of CO{sub 2}. In order to assure penetration of the emulsion into tight formations of sandstone or other silicate rocks and carbonate or dolomite rock, it is necessary to use an emulsion consisting of the smallest possible globule size. In previous reports we described a high shear static mixer that can create such small globules. In addition to the high shear mixer, it is also necessary that the emulsion stabilizing particles be in the submicron size, preferably in the range of 0.1 to 0.2 μm (100 to 200 nm) size. We found a commercial source of such pulverized limestone particles, in addition we purchased under this DOE Project a particle grinding apparatus that can provide particles in the desired size range. Additional work focused on attempts to generate particle stabilized emulsions with a flow through, static mixer based apparatus under a variety of conditions that are suitable for permanent sequestration of carbon dioxide. A variety of mixtures of water, CO{sub 2} and particles may also provide suitable emulsions capable of PS. In addition, it is necessary to test the robustness of PSE formation as composition changes to be certain that emulsions of appropriate size and stability form under conditions that might vary during actual large scale EOR and sequestration operations. The goal was to lay the groundwork for an apparatus and formulation that would produce homogenous microemulsions of CO{sub 2}-in-water capable of readily mixing with the waters of deep saline aquifers and allow a safer and more permanent sequestration of carbon dioxide. In addition, as a beneficial use, we hoped to produce homogenous microemulsions of water-in-CO{sub 2} capable of readily mixing with pure liquid or supercritical CO{sub 2} for use in Enhanced Oil Recovery (EOR). However, true homogeneous microemulsions have proven very difficult to produce and efforts have not yielded either a formulation or a mixing strategy that gives emulsions that do not settle out or that can be diluted with the continuous phase in varying proportions. Other mixtures of water, CO{sub 2} and particles, that are not technically homogeneous microemulsions, may also provide suitable emulsions capable of PS and EOR. For example, a homogeneous emulsion that is not a microemulsion might also provide all of the necessary characteristics desired. These characteristics would include easy formation, stability over time, appropriate size and the potential for mineralization under conditions that would be encountered under actual large scale sequestration operations. This report also describes work with surrogate systems in order to test conditions.

  15. Oils and source rocks from the Anadarko Basin: Final report, March 1, 1985-March 15, 1995

    SciTech Connect (OSTI)

    Philp, R. P. [School of Geology and Geophysics, Univ. of Oklahoma, Norman, OK (United States)

    1996-11-01

    The research project investigated various geochemical aspects of oils, suspected source rocks, and tar sands collected from the Anadarko Basin, Oklahoma. The information has been used, in general, to investigate possible sources for the oils in the basin, to study mechanisms of oil generation and migration, and characterization of depositional environments. The major thrust of the recent work involved characterization of potential source formations in the Basin in addition to the Woodford shale. The formations evaluated included the Morrow, Springer, Viola, Arbuckle, Oil Creek, and Sylvan shales. A good distribution of these samples was obtained from throughout the basin and were evaluated in terms of source potential and thermal maturity based on geochemical characteristics. The data were incorporated into a basin modelling program aimed at predicting the quantities of oil that could, potentially, have been generated from each formation. The study of crude oils was extended from our earlier work to cover a much wider area of the basin to determine the distribution of genetically-related oils, and whether or not they were derived from single or multiple sources, as well as attempting to correlate them with their suspected source formations. Recent studies in our laboratory also demonstrated the presence of high molecular weight components(C{sub 4}-C{sub 80}) in oils and waxes from drill pipes of various wells in the region. Results from such a study will have possible ramifications for enhanced oil recovery and reservoir engineering studies.

  16. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    SciTech Connect (OSTI)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution features including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.

  17. Use of natural radionuclides to predict the behavior of radwaste radionuclides in far-field aquifiers

    SciTech Connect (OSTI)

    Hubbard, N.; Laul, J.C.; Perkins, R.W.

    1983-10-01

    In appropriate aquifers the natural radionuclides of the U and Th decay series are important sources of information about the behavior of radwaste radionuclides in far-field aquifers. The Wolfcamp Carbonate, Pennsylvanian Carbonate and Granite Wash aquifers in the Palo Duro Basin of the Texas Panhandle are prime examples of such aquifers. Sampling and analysis for key radionuclides in the ground waters of these aquifers are quite feasible and have been accomplished. Key early results are: (1) Ra does not appear to be retarded by sorption, (2) Th appears to be strongly sorbed, (3) kinetics seem to be different on time scales of days to months than on ones of hundreds of thousands of years, and (4) U and Th behave similarily when the time scales (half-lives) are similar, leading to the suggestion that uranium is in the +4 valence state in these aquifers. 10 references, 9 figures.

  18. An evaluation of baseline conditions at lease tract C-a, Rio Blanco County, Colorado

    SciTech Connect (OSTI)

    Barteaux, W.L.; Biezugbe, G.

    1987-09-01

    An analysis was made of baseline groundwater quality data from oil shale lease tract C-a, managed by Rio Blanco Oil Shale Company. The data are limited in several respects. All conclusions drawn from the data must be qualified with these limitations. Baseline conditions were determined by analyzing data from wells in the upper bedrock and lower bedrock aquifers and from the alluvial wells. Baseline data were considered all data collected before mining operations began. The water quality was then evaluated using the 1987 Colorado State Basic Standards for Ground Water as a basis. The maximum baseline values for several parameters in each aquifer exceed the standard values. The quality of the upper lower bedrock aquifers varies from region to region within the site. Data on the lower bedrock aquifer are insufficient for speculation on the cause of the variations. Variations in the upper bedrock aquifer are possibly caused by leakage of the lower bedrock aquifer. 16 refs., 9 figs., 9 tabs.

  19. In-situ remediation system for volatile organic compounds with deep recharge mechanism

    DOE Patents [OSTI]

    Jackson, Jr., Dennis G.; Looney, Brian B.; Nichols, Ralph L.; Phifer, Mark A.

    2001-01-01

    A method and apparatus for the treatment and remediation of a contaminated aquifer in the presence of an uncontaminated aquifer at a different hydraulic potential. The apparatus consists of a wellbore inserted through a first aquifer and into a second aquifer, an inner cylinder within the wellbore is supported and sealed to the wellbore to prevent communication between the two aquifers. Air injection is used to sparge the liquid having the higher static water level and, to airlift it to a height whereby it spills into the inner cylinder. The second treatment area provides treatment in the form of aeration or treatment with a material. Vapor stripped in sparging is vented to the atmosphere. Treated water is returned to the aquifer having the lower hydraulic potential.

  20. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic

    Office of Scientific and Technical Information (OSTI)

    Leakage into an Unconfined, Oxidizing Limestone Aquifer (Journal Article) | SciTech Connect Journal Article: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer An important risk at CO2 storage sites is the potential for groundwater quality impacts. As

  1. The Research Program | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Research Program What is the chemical and physical form of uranium in reduced aquifers? Uranium behavior in the Rifle, CO, aquifer. In order to directly interrogate the chemical and physical form of reduced uranium (U(IV)) in bioremediated sediments within the contaminated aquifer at the Rifle site, a novel technique was developed based on reactors installed in wells (center right). U(IV) was found to be bound to biomass (structural model shown in upper left-hand) within thin (microns)

  2. EIA CIPSEA Training

    Gasoline and Diesel Fuel Update (EIA)

    Configuration Aquifer Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Aquifer Underground Natural Gas Storage Reservoir Configuration Aquifer Underground Natural Gas Well Configuration

    Depleted Reservoir Storage Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Depleted Production Reservoir Underground Natural

  3. Natural Gas Vans To Help Clear the Air In Metro Denver

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Million Cubic Feet) Data Series: Total Storage Capacity Salt Caverns Storage Capacity Aquifers Storage Capacity Depleted Fields Storage Capacity Total Working Gas Capacity Working Gas Capacity of Salt Caverns Working Gas Capacity of Aquifers Working Gas Capacity of Depleted Fields Total Number of Existing Fields Number of Existing Salt Caverns Number of Existing Aquifers Number of Depleted Fields Period: Monthly Annual Download Series History Download Series History Definitions, Sources &

  4. Natural Gas Underground Storage Capacity (Summary)

    U.S. Energy Information Administration (EIA) Indexed Site

    Salt Caverns Storage Capacity Aquifers Storage Capacity Depleted Fields Storage Capacity Total Working Gas Capacity Working Gas Capacity of Salt Caverns Working Gas Capacity of Aquifers Working Gas Capacity of Depleted Fields Total Number of Existing Fields Number of Existing Salt Caverns Number of Existing Aquifers Number of Depleted Fields Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data

  5. Thermal well-test method

    DOE Patents [OSTI]

    Tsang, Chin-Fu; Doughty, Christine A.

    1985-01-01

    A well-test method involving injection of hot (or cold) water into a groundwater aquifer, or injecting cold water into a geothermal reservoir. By making temperature measurements at various depths in one or more observation wells, certain properties of the aquifer are determined. These properties, not obtainable from conventional well test procedures, include the permeability anisotropy, and layering in the aquifer, and in-situ thermal properties. The temperature measurements at various depths are obtained from thermistors mounted in the observation wells.

  6. Assessing the Effect of Timing of Availability for Carbon Dioxide Storage in the Largest Oil and Gas Pools in the Alberta Basin: Description of Data and Methodology

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Bachu, Stefan

    2007-03-05

    Carbon dioxide capture from large stationary sources and storage in geological media is a technologically-feasible mitigation measure for the reduction of anthropogenic emissions of CO2 to the atmosphere in response to climate change. Carbon dioxide (CO2) can be sequestered underground in oil and gas reservoirs, in deep saline aquifers, in uneconomic coal beds and in salt caverns. The Alberta Basin provides a very large capacity for CO2 storage in oil and gas reservoirs, along with significant capacity in deep saline formations and possible unmineable coal beds. Regional assessments of potential geological CO2 storage capacity have largely focused so far on estimating the total capacity that might be available within each type of reservoir. While deep saline formations are effectively able to accept CO2 immediately, the storage potential of other classes of candidate storage reservoirs, primarily oil and gas fields, is not fully available at present time. Capacity estimates to date have largely overlooked rates of depletion in these types of storage reservoirs and typically report the total estimated storage capacity that will be available upon depletion. However, CO2 storage will not (and cannot economically) begin until the recoverable oil and gas have been produced via traditional means. This report describes a reevaluation of the CO2 storage capacity and an assessment of the timing of availability of the oil and gas pools in the Alberta Basin with very large storage capacity (>5 MtCO2 each) that are being looked at as likely targets for early implementation of CO2 storage in the region. Over 36,000 non-commingled (i.e., single) oil and gas pools were examined with effective CO2 storage capacities being individually estimated. For each pool, the life expectancy was estimated based on a combination of production decline analysis constrained by the remaining recoverable reserves and an assessment of economic viability, yielding an estimated depletion date, or year that it will be available for CO2 storage. The modeling framework and assumptions used to assess the impact of the timing of CO2 storage resource availability on the regions deployment of CCS technologies is also described. The purpose of this report is to describe the data and methodology for examining the carbon dioxide (CO2) storage capacity resource of a major hydrocarbon province incorporating estimated depletion dates for its oil and gas fields with the largest CO2 storage capacity. This allows the development of a projected timeline for CO2 storage availability across the basin and enables a more realistic examination of potential oil and gas field CO2 storage utilization by the regions large CO2 point sources. The Alberta Basin of western Canada was selected for this initial examination as a representative mature basin, and the development of capacity and depletion date estimates for the 227 largest oil and gas pools (with a total storage capacity of 4.7 GtCO2) is described, along with the impact on source-reservoir pairing and resulting CO2 transport and storage economics. The analysis indicates that timing of storage resource availability has a significant impact on the mix of storage reservoirs selected for utilization at a given time, and further confirms the value that all available reservoir types offer, providing important insights regarding CO2 storage implementation to this and other major oil and gas basins throughout North America and the rest of the world. For CCS technologies to deploy successfully and offer a meaningful contribution to climate change mitigation, CO2 storage reservoirs must be available not only where needed (preferably co-located with or near large concentrations of CO2 sources or emissions centers) but also when needed. The timing of CO2 storage resource availability is therefore an important factor to consider when assessing the real opportunities for CCS deployment in a given region.

  7. Desorption Behavior of Carbon Tetrachloride and Chloroform in...

    Office of Scientific and Technical Information (OSTI)

    Behavior of Carbon Tetrachloride and Chloroform in contaminated Low Organic Carbon Aquifer Sediments Citation Details In-Document Search Title: Desorption Behavior of Carbon ...

  8. Anatomy of a Groundwater Uranium Plume

    Broader source: Energy.gov [DOE]

    Groundwater containing legacy contaminants (pollutants that remain after their sources have been controlled) moves through aquifers in response to the hydraulic gradient. As the groundwater moves,...

  9. What waters does LANL protect?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    does LANL protect? Google Earth Tour: Waters around LANL Jemez Mountains Headwaters Watersheds The Rio Grande Buckman Direct Diversion Project Groundwater in the Regional Aquifer...

  10. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    47 DOE/EIS-0287 Idaho HLW & FD EIS 4.8.2 SUBSURFACE WATER Subsurface water at INEEL occurs in the under- lying Snake River Plain Aquifer and the vadose zone (area of unsaturated soil and material above the aquifer). This section describes the regional and local hydrogeology, vadose zone hydrology, perched water, and subsurface water quality. 4.8.2.1 Regional Hydrogeology INEEL overlies the Snake River Plain Aquifer as shown in Figure 4-12. This aquifer is the major source of drinking water

  11. Microsoft Word - 13055299_DVP.docx

    Office of Legacy Management (LM)

    ... Well OBS-3 is also completed in the San AndresGlorieta aquifer. The LTSP requires monitoring for molybdenum, selenium, uranium, and polychlorinated biphenyls (PCBs); PCB ...

  12. Microsoft Word - RIN 12114945 DVP

    Office of Legacy Management (LM)

    ... Well OBS-3 is also completed in the San AndresGlorieta aquifer. The LTSP requires monitoring for molybdenum, selenium, uranium, and polychlorinated biphenyls (PCBs); PCB ...

  13. Microsoft Word - 14046116 14046117 DVP.docx

    Office of Legacy Management (LM)

    ... Wells HMC-951 and OBS-3 are also completed in the San Andres aquifer. The LTSP requires monitoring for molybdenum, selenium, uranium, and polychlorinated biphenyls (PCBs); PCB ...

  14. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... Wells HMC-951 and OBS-3 are also completed in the San AndresGlorieta aquifer. The LTSP requires monitoring for molybdenum, selenium, uranium, and polychlorinated biphenyls (PCBs); ...

  15. High Precision Geophysics & Detailed Structural Exploration ...

    Open Energy Info (EERE)

    in a shallow geothermal aquifer and support effective development of the low temperature reservoir and identification of deep up flow targets. These surveys and the drilling...

  16. 3D Magnetotelluric Characterization Of The Geothermal Anomaly...

    Open Energy Info (EERE)

    Magnetotelluric Characterization Of The Geothermal Anomaly In The Llucmajor Aquifer System (Majorca, Spain) Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  17. Semi-annual report for the unconventional gas recovery program, period ending March 31, 1980

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-06-01

    Four subprograms are reported on: methane recovery from coalbeds, Eastern gas shales, Western gas sands, and methane from geopressured aquifers. (DLC)

  18. Total Natural Gas Underground Storage Capacity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Capacity Salt Caverns Storage Capacity Aquifers Storage Capacity Depleted Fields Storage Capacity Total Working Gas Capacity Working Gas Capacity of Salt Caverns Working...

  19. Category:Federal Environmental Statutes | Open Energy Information

    Open Energy Info (EERE)

    Outer Continental Shelf Lands Act P Paleontological Resources Preservation Act S Safe Drinking Water Act Sole Source Aquifer Demonstration Program Retrieved from "http:...

  20. Earth Tidal Analysis | Open Energy Information

    Open Energy Info (EERE)

    of earth tide response of three deep, confined aquifers Earth Tidal Analysis At Raft River Geothermal Area (1980) Raft River Geothermal Area 1980 1980 Reservoir response to...

  1. Geothermometry At Long Valley Caldera Geothermal Area (Mariner...

    Open Energy Info (EERE)

    California R.O. Fournier, Michael L. Sorey, Robert H. Mariner, Alfred H. Truesdell (1979) Chemical and Isotopic Prediction of Aquifer Temperatures in the Geothermal System at Long...

  2. Environmental Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in aquifers requires very large simulations typically ranging from meters to kilometers and time scales of months to years or even centuries. This problem is aggravated by...

  3. DISCLAIMER

    Office of Legacy Management (LM)

    ... in the Alluvial Aquifer-Data . . through September 1997 ... U.S. Department of Energy environmental assessment ... be collected on site in a solar evaporation pond; the ...

  4. AS&T Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses from LM Monitoring ... February 2008 Ground-Water Table and Chemical Changes in an Alluvial Aquifer During ...

  5. http://www.em.doe.gov/Pages/groundwaterReport.aspx?plumeCode...

    Office of Environmental Management (EM)

    Legacy Management Plume Name: Chemical Plant (Quarry) Remediation Contractor: SM Stoller ... by naturally occurring chemical reduction process and absorption onto aquifer materials. ...

  6. Office of Civilian Radioactive Waste Management

    Energy Savers [EERE]

    ... to the Technical Data Management System under the ... and regional aquifers with topographically low outlets. ... 1983. Disposal of High-Level Nuclear Waste Above the Water Table in ...

  7. ECO2N - A Fluid Property Module for the TOUGH2 Code for Studies...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE. Assistant Secretary for Fossil Energy.Coal Country of Publication: United States Language: English Subject: 54; AQUIFERS; STORAGE; ENERGY MANAGEMENT; ENERGY ...

  8. Sandia Energy - Decision Support for Integrated Energy-Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    freshwater withdrawals thus competing with irrigated agriculture as the leading user of water. Proposed power plants must often target waterways and aquifers prone to overdraft...

  9. Selective sorption of technetium from groundwater (Conference...

    Office of Scientific and Technical Information (OSTI)

    Solutions contaminated with radionuclides were poured into lagoons and burial pits, which created a plume that has seeped into the sandy aquifers below the vadose zone. Technetium ...

  10. Groundwater Monitoring Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    92 natural sources, 102 regional aquifer wells, 41 intermediate-depth wells and springs, and 67 wells in alluvium in canyons. August 1, 2013 Map of LANL's groundwater...

  11. Flathead Electric Cooperative Facility Geothermal Heat Pump System Upgrade

    Broader source: Energy.gov [DOE]

    Project Will Take Advantage of Abundant Water in Shallow Aquifer. Demonstrate Low Temperature GSHP System Design. Provides a Baseline for Local Industrial Geothermal Project Costs and Benefits.

  12. Savannah River Site - R-Reactor Seepage Basins | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Strategy Exist? Yes Sole Source Aquifer? No Basis for Exit Strategy: Target Concentration Environmental Indicators (EIs) Groundwater Migration Under Control? No Current Human...

  13. http://www.em.doe.gov/Pages/groundwaterReport.aspx?plumeCode...

    Office of Environmental Management (EM)

    Source Aquifer? No Does an Exit Strategy Exist? No Basis for Exit Strategy: No Response Environmental Indicators (EIs) Groundwater Migration Under Control? No Confirmed by Lead...

  14. Savannah River Site - L-Area Burning/Rubble Pit | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Strategy Exist? Yes Sole Source Aquifer? No Basis for Exit Strategy: Target Concentration Environmental Indicators (EIs) Groundwater Migration Under Control? No Current Human...

  15. Savannah River Site - CMP Pits | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Strategy Exist? Yes Sole Source Aquifer? No Basis for Exit Strategy: Target Concentration Environmental Indicators (EIs) Groundwater Migration Under Control? No Current Human...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Cr(VI) Adsorption on Soils, Sediments and Model Mixtures of Kaolinite, Montmorillonite, ... into aquifers and shallow sediments and soils via many anthropogenic activities. ...

  17. Development of Surface Complexation Models of Cr(VI) Adsorption...

    Office of Scientific and Technical Information (OSTI)

    Cr(VI) Adsorption on Soils, Sediments and Model Mixtures of Kaolinite, Montmorillonite, ... into aquifers and shallow sediments and soils via many anthropogenic activities. ...

  18. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    rock (3) desalination (3) flocculation (3) safety (3) sandia national laboratories (3) water treatment (3) algae (2) aquifers (2) basic biological sciences (2) biofuels (2)...

  19. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (4) hydraulics (4) performance (4) seismicity (4) aquifers (3) carbon dioxide (3) Filter by Author Rutqvist, Jonny (38) Birkholzer, Jens (16) Tsang, Chin-Fu (12) Pruess,...

  20. EM News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at DOE headquarters. November 25, 2015 SRNS operators Stanley Creech (left) and Paul Dobson monitor the injection of silver chloride into an aquifer at SRS. Passive...

  1. Wardell Armstrong International | Open Energy Information

    Open Energy Info (EERE)

    Product: Provides consultancy and technical services for aquifer geothermal, wind, waste to energy and biomass projects. Coordinates: 50.443321, -4.93986 Show Map Loading...

  2. MSWGW

    Office of Legacy Management (LM)

    December 1997 United States Department of Energy Grand Junction Office Monticello Surface ... Ground water contamination is distributed in the shallow aquifer beginning at the ...

  3. Microsoft Word - S09545_EC012913

    Office of Legacy Management (LM)

    ... General observations from Figure 5 included the following: Upgradient locations (green... U.S. Department of Energy Enhanced Characterization Surficial Aquifer, Riverton, Wyoming, ...

  4. Idaho Section 319 Grant Application | Open Energy Information

    Open Energy Info (EERE)

    to library Form: Idaho Section 319 Grant Application Abstract This page provides access to an online form Section 319 Project Application for grants for watershed and aquifer...

  5. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Reduced Order Model for the Geochemical Impacts of Carbon Dioxide Brine and Trace Metal Leakage into an Unconfined Oxidizing Carbonate Aquifer Version Bacon Diana H carbon...

  6. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Citation Details...

  7. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1","Bacon, Diana...

  8. Microsoft Word - chap4.doc

    Office of Legacy Management (LM)

    the South Plume, South Field, and Waste Storage Area Aquifer Restoration Modules * ... treated effluent analytical results from samples collected in 2004 exceeded the surface ...

  9. JOINT EPA/DOE STATEMENT: Radiation Monitors Confirm That No Radiation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... The Particle Physics of You SRNS operators Stanley Creech (left) and Paul Dobson monitor the injection of silver chloride into an aquifer at SRS. Passive Groundwater Cleanup ...

  10. Chapter 7: Advancing Systems and Technologies to Produce Cleaner...

    Energy Savers [EERE]

    aquifers are likely very low in most settings, it is ... produced water treatment technologies will be ... present at surface pressure and temperature conditions). ...

  11. Effects of uranium-mining releases on ground-water quality in the Puerco River Basin, Arizona and New Mexico

    SciTech Connect (OSTI)

    Van Metre, P.C.; Wirt, L.; Lopes, T.J.; Ferguson, S.A.

    1997-12-31

    The purpose of this report is to describe: (1) the water quality of the Puerco River alluvial aquifer, (2) the movement of water between the Puerco River and underlying alluvial aquifer, and (3) changes in the water quality of the alluvial and bedrock aquifers related to releases of contaminants by uranium-mining activities. This report focuses on the alluvial aquifer near the reach of the Puerco River that was subjected to continuous flow containing mine-dewatering effluents and to flow containing mine-dewatering effluents and to flow from the tailings-pond spill.

  12. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2

    Office of Scientific and Technical Information (OSTI)

    leakage into aquifers (Journal Article) | SciTech Connect analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers Citation Details In-Document Search Title: Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    sciences (2) environmental sciences(54) (2) precipitation (2) probability (2) risk assessment (2) sediments (2) sorption (2) stomp (2) storage (2) transport (2) aquifer (1) ...

  14. Independent Technical Review of the X-740 Groundwater Remedy...

    Office of Scientific and Technical Information (OSTI)

    aquifer zone (the Gallia) - the behavior of the contamination in the Gallia is ... of Energy Office of Environmental Management (EM-32) to provide an independent ...

  15. Idaho Site Enlists Whey-Eating Microbes in Groundwater Cleanup

    Broader source: Energy.gov [DOE]

    IDAHO FALLS, Idaho – Workers at the Idaho site have enlisted microbes to help remediate previously contaminated groundwater and advance the protection of the Snake River Plain Aquifer.

  16. Groundwater Flow Systems at the Nevada Test Site, Nevada: A Synthesis of Potentiometric Contours, Hydrostratigraphy, and Geologic Structures

    SciTech Connect (OSTI)

    Fenelon, Joseph M.; Sweetkind, Donald S.; Laczniak, Randell J.

    2010-01-25

    Contaminants introduced into the subsurface of the Nevada Test Site by underground nuclear testing are of concern to the U.S. Department of Energy and regulators responsible for protecting human health and safety. The potential for contaminant movement away from the underground test areas and into the accessible environment is greatest by groundwater transport. The primary hydrologic control on this transport is evaluated and examined through a series of contour maps developed to represent the hydraulic-head distribution within each of the major aquifers underlying the area. Aquifers were identified and their extents delineated by merging and analyzing multiple hydrostratigraphic framework models developed by other investigators from existing geologic information. A map of the hydraulic-head distribution in each major aquifer was developed from a detailed evaluation and assessment of available water-level measurements. Multiple spreadsheets that accompany this report provide pertinent water-level and geologic data by well or drill hole. Aquifers are mapped and discussed in general terms as being one of two types: alluvial-volcanic, or carbonate. Both aquifer types are subdivided and mapped as independent regional and local aquifers, based on the continuity of their component rock. Groundwater-flow directions, approximated from potentiometric contours that were developed from the hydraulic-head distribution, are indicated on the maps and discussed for each of the regional aquifers and for selected local aquifers. Hydraulic heads vary across the study area and are interpreted to range in altitude from greater than 5,000 feet in a regional alluvial-volcanic aquifer beneath a recharge area in the northern part of the study area to less than 2,300 feet in regional alluvial-volcanic and carbonate aquifers in the southwestern part of the study area. Flow directions throughout the study area are dominantly south-southwest with some local deviations. Vertical hydraulic gradients between aquifer types are downward throughout most of the study area; however, flow from the alluvial-volcanic aquifer into the underlying carbonate aquifer, where both aquifers are present, is believed to be minor because of an intervening confining unit. Limited exchange of water between aquifer types occurs by diffuse flow through the confining unit, by focused flow along fault planes, or by direct flow where the confining unit is locally absent. Interflow between regional aquifers is evaluated and mapped to define major flow paths. These flow paths delineate tributary flow systems, which converge to form intermediate and regional flow systems. The implications of these flow systems in controlling transport of radionuclides away from the underground test areas at the Nevada Test Site are briefly discussed. Additionally, uncertainties in the delineation of aquifers, the development of potentiometric contours, and the identification of flow systems are identified and evaluated. Eleven tributary flow systems and three larger flow systems are mapped in the Nevada Test Site area. Flow systems within the alluvial-volcanic aquifer dominate the western half of the study area, whereas flow systems within the carbonate aquifer are most prevalent in the southeastern half of the study area. Most of the flow in the regional alluvial-volcanic aquifer that moves through the underground testing area on Pahute Mesa is discharged to the land surface at springs and seeps in Oasis Valley. Flow in the regional carbonate aquifer is internally compartmentalized by major geologic structures, primarily thrust faults, which constrain flow into separate corridors. Contaminants that reach the regional carbonate aquifer from testing areas in Yucca and Frenchman Flats flow toward downgradient discharge areas through the Alkali Flat-Furnace Creek Ranch or Ash Meadows flow systems and their tributaries.

  17. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Extracting, treating, and using these saline waters to cool the power plant is one way to develop more value from using saline formations as CO2 storage locations. WECSsim allows ...

  18. Thermophysical Properties of Sodium Nitrate and Sodium Chloride

    Office of Scientific and Technical Information (OSTI)

    The effect of density and viscosity of saline solutions has been long recognized. Here we focus our attention on the effect of vapor pressure lowering due to salinity. We present ...

  19. Sandia Energy - EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Use of Deep Saline Formations for Combined Thermoelectric Power Plant Water Needs and Carbon Sequestration at a Regional-Scale: Phase I Report (388) Study of the Use of Saline...

  20. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  1. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil gas and saline reservoirs Geological carbon...

  2. No-Impact Threshold Values for NRAP's Reduced Order Models

    SciTech Connect (OSTI)

    Last, George V.; Murray, Christopher J.; Brown, Christopher F.; Jordan, Preston D.; Sharma, Maneesh

    2013-02-01

    The purpose of this study was to develop methodologies for establishing baseline datasets and statistical protocols for determining statistically significant changes between background concentrations and predicted concentrations that would be used to represent a contamination plume in the Gen II models being developed by NRAP’s Groundwater Protection team. The initial effort examined selected portions of two aquifer systems; the urban shallow-unconfined aquifer system of the Edwards-Trinity Aquifer System (being used to develop the ROM for carbon-rock aquifers, and the a portion of the High Plains Aquifer (an unconsolidated and semi-consolidated sand and gravel aquifer, being used to development the ROM for sandstone aquifers). Threshold values were determined for Cd, Pb, As, pH, and TDS that could be used to identify contamination due to predicted impacts from carbon sequestration storage reservoirs, based on recommendations found in the EPA’s ''Unified Guidance for Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities'' (US Environmental Protection Agency 2009). Results from this effort can be used to inform a ''no change'' scenario with respect to groundwater impacts, rather than the use of an MCL that could be significantly higher than existing concentrations in the aquifer.

  3. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore » including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  4. In-Situ MVA of CO2 Sequestration Using Smart Field Technology

    SciTech Connect (OSTI)

    Mohaghegh, Shahab D.

    2014-09-01

    Capability of underground carbon dioxide storage to confine and sustain injected CO2 for a long period of time is the main concern for geologic CO2 sequestration. If a leakage from a geological CO2 sequestration site occurs, it is crucial to find the approximate amount and the location of the leak, in a timely manner, in order to implement proper remediation activities. An overwhelming majority of research and development for storage site monitoring has been concentrated on atmospheric, surface or near surface monitoring of the sequestered CO2 . This study aims to monitor the integrity of CO2 storage at the reservoir level. This work proposes developing in-situ CO2 Monitoring and Verification technology based on the implementation of Permanent Down-hole Gauges (PDG) or “Smart Wells” along with Artificial Intelligence and Data Mining (AI&DM). The technology attempts to identify the characteristics of the CO2 leakage by de-convolving the pressure signals collected from Permanent Down-hole Gauges (PDG). Citronelle field, a saline aquifer reservoir, located in the U.S. was considered as the basis for this study. A reservoir simulation model for CO2 sequestration in the Citronelle field was developed and history matched. PDGs were installed, and therefore were considered in the numerical model, at the injection well and an observation well. Upon completion of the history matching process, high frequency pressure data from PDGs were generated using the history matched numerical model using different CO2 leakage scenarios. Since pressure signal behaviors were too complicated to de-convolute using any existing mathematical formulations, a Machine Learning-based technology was introduced for this purpose. An Intelligent Leakage Detection System (ILDS) was developed as the result of this effort using the machine learning and pattern recognition technologies. The ILDS is able to detect leakage characteristics in a short period of time (less than a day from its occurrence) demonstrating the capability of the system in quantifying leakage characteristics subject to complex rate behaviors. The performance of ILDS is examined under different conditions such as multiple well leakages, cap rock leakage, availability of an additional monitoring well, presence of pressure drift and noise in the pressure sensor and uncertainty in the reservoir model.

  5. Training toward Advanced 3D Seismic Methods for CO2 Monitoring, Verification, and Accounting

    SciTech Connect (OSTI)

    Christopher Liner

    2012-05-31

    The objective of our work is graduate and undergraduate student training related to improved 3D seismic technology that addresses key challenges related to monitoring movement and containment of CO{sub 2}, specifically better quantification and sensitivity for mapping of caprock integrity, fractures, and other potential leakage pathways. We utilize data and results developed through previous DOE-funded CO{sub 2} characterization project (DE-FG26-06NT42734) at the Dickman Field of Ness County, KS. Dickman is a type locality for the geology that will be encountered for CO{sub 2} sequestration projects from northern Oklahoma across the U.S. midcontinent to Indiana and Illinois. Since its discovery in 1962, the Dickman Field has produced about 1.7 million barrels of oil from porous Mississippian carbonates with a small structural closure at about 4400 ft drilling depth. Project data includes 3.3 square miles of 3D seismic data, 142 wells, with log, some core, and oil/water production data available. Only two wells penetrate the deep saline aquifer. In a previous DOE-funded project, geological and seismic data were integrated to create a geological property model and a flow simulation grid. We believe that sequestration of CO{sub 2} will largely occur in areas of relatively flat geology and simple near surface, similar to Dickman. The challenge is not complex geology, but development of improved, lower-cost methods for detecting natural fractures and subtle faults. Our project used numerical simulation to test methods of gathering multicomponent, full azimuth data ideal for this purpose. Our specific objectives were to apply advanced seismic methods to aide in quantifying reservoir properties and lateral continuity of CO{sub 2} sequestration targets. The purpose of the current project is graduate and undergraduate student training related to improved 3D seismic technology that addresses key challenges related to monitoring movement and containment of CO{sub 2}, specifically better quantification and sensitivity for mapping of caprock integrity, fractures, and other potential leakage pathways. Specifically, our focus is fundamental research on (1) innovative narrow-band seismic data decomposition and interpretation, and (2) numerical simulation of advanced seismic data (multi-component, high density, full azimuth data) ideal for mapping of cap rock integrity and potential leakage pathways.

  6. Intelligent Leak Detection System

    Energy Science and Technology Software Center (OSTI)

    2014-10-27

    apability of underground carbon dioxide storage to confine and sustain injected CO2 for a very long time is the main concern for geologic CO2 sequestration. If a leakage from a geological CO2 sequestration site occurs, it is crucial to find the approximate amount and the location of the leak in order to implement proper remediation activity. An overwhelming majority of research and development for storage site monitoring has been concentrated on atmospheric, surface or nearmore » surface monitoring of the sequestered CO2. This study aims to monitor the integrity of CO2 storage at the reservoir level. This work proposes developing in-situ CO2 Monitoring and Verification technology based on the implementation of Permanent Down-hole Gauges (PDG) or “Smart Wells” along with Artificial Intelligence and Data Mining (AI&DM). The technology attempts to identify the characteristics of the CO2 leakage by de-convolving the pressure signals collected from Permanent Down-hole Gauges (PDG). Citronelle field, a saline aquifer reservoir, located in the U.S. was considered for this study. A reservoir simulation model for CO2 sequestration in the Citronelle field was developed and history matched. The presence of the PDGs were considered in the reservoir model at the injection well and an observation well. High frequency pressure data from sensors were collected based on different synthetic CO2 leakage scenarios in the model. Due to complexity of the pressure signal behaviors, a Machine Learning-based technology was introduced to build an Intelligent Leakage Detection System (ILDS). The ILDS was able to detect leakage characteristics in a short period of time (less than a day) demonstrating the capability of the system in quantifying leakage characteristics subject to complex rate behaviors. The performance of ILDS was examined under different conditions such as multiple well leakages, cap rock leakage, availability of an additional monitoring well, presence of pressure drift and noise in the pressure sensor and uncertainty in the reservoir model.« less

  7. Comprehensive, Quantitative Risk Assessment of CO{sub 2} Geologic Sequestration

    SciTech Connect (OSTI)

    Lepinski, James

    2013-09-30

    A Quantitative Failure Modes and Effects Analysis (QFMEA) was developed to conduct comprehensive, quantitative risk assessments on CO{sub 2} capture, transportation, and sequestration or use in deep saline aquifers, enhanced oil recovery operations, or enhanced coal bed methane operations. The model identifies and characterizes potential risks; identifies the likely failure modes, causes, effects and methods of detection; lists possible risk prevention and risk mitigation steps; estimates potential damage recovery costs, mitigation costs and costs savings resulting from mitigation; and ranks (prioritizes) risks according to the probability of failure, the severity of failure, the difficulty of early failure detection and the potential for fatalities. The QFMEA model generates the necessary information needed for effective project risk management. Diverse project information can be integrated into a concise, common format that allows comprehensive, quantitative analysis, by a cross-functional team of experts, to determine: What can possibly go wrong? How much will damage recovery cost? How can it be prevented or mitigated? What is the cost savings or benefit of prevention or mitigation? Which risks should be given highest priority for resolution? The QFMEA model can be tailored to specific projects and is applicable to new projects as well as mature projects. The model can be revised and updated as new information comes available. It accepts input from multiple sources, such as literature searches, site characterization, field data, computer simulations, analogues, process influence diagrams, probability density functions, financial analysis models, cost factors, and heuristic best practices manuals, and converts the information into a standardized format in an Excel spreadsheet. Process influence diagrams, geologic models, financial models, cost factors and an insurance schedule were developed to support the QFMEA model. Comprehensive, quantitative risk assessments were conducted on three (3) sites using the QFMEA model: (1) SACROC Northern Platform CO{sub 2}-EOR Site in the Permian Basin, Scurry County, TX, (2) Pump Canyon CO{sub 2}-ECBM Site in the San Juan Basin, San Juan County, NM, and (3) Farnsworth Unit CO{sub 2}-EOR Site in the Anadarko Basin, Ochiltree County, TX. The sites were sufficiently different from each other to test the robustness of the QFMEA model.

  8. Matrix effect of sodium compounds on the determination of metal ions in aqueous solutions by underwater laser-induced breakdown spectroscopy

    SciTech Connect (OSTI)

    Goueguel, Christian; McIntyre, Dustin L.; Jain, Jinesh; Karamalidis, Athanasios K.; Carson, Cantwell

    2015-06-30

    A significant portion of the carbon sequestration research being performed in the United States involves the risk assessment of injecting large quantities of carbon dioxide into deep saline aquifers. Leakage of CO2 has the potential to affect the quality of groundwater supplies in case contaminants migrate through underlying conduits. New remote sensing and near-surface monitoring technologies are needed to ensure that injection, abandoned, and monitoring wells are structurally sound, and that CO2 remains within the geologic storage reservoir. In this paper, we propose underwater laser-induced breakdown spectroscopy (underwater LIBS) as an analytical method for monitoring naturally occurring elements that can act as tracers to detect a CO2 leak from storage sites. Laboratory-scale experiments were conducted to measure Sr2+, Ca2+, K+, and Li+ in bulk solutions to ascertain the analytical performance of underwater LIBS. We compared the effect of NaCl, Na2CO3, and Na2SO4 on the analytes calibration curves to determine underwater LIBS’ ability to analyze samples of sodium compounds. In all cases, the calibration curves showed a good linearity within 2 orders of magnitude. The limit of detections (LODs) obtained for K+ (30±1 ppb) and Li+ (60±2 ppb) were in ppb range, while higher LODs were observed for Ca2+ (0.94±0.14 ppm) and Sr2+ (2.89±0.11 ppm). Evaluation of the calibration curves for the analytes in mixed solutions showed dependence of the lines’ intensity with the sodium compounds. The intensities increased respectively in the presence of dissolved NaCl and Na2SO4, whereas the intensities slightly decreased in the presence of Na2CO3. Lastly, the capabilities of underwater LIBS to detect certain elements in the ppb or in the low ppm range make it particularly appealing for in situ monitoring of a CO2 leak.

  9. Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-05-15

    Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

  10. Finite element model to predict the flow of underground contaminants due to leakage of chemical and/or radio active material from a buried containment. Final technical report

    SciTech Connect (OSTI)

    Anand, S.C.; Pandit, A.

    1983-06-01

    In the investigation, a Galerkin finite element model in two dimensions is developed to study the phenomena of mass transfer in porous media. In particular, the problems of the saltwater encroachment in coastal aquifers and the transport of hazardous wastes in groundwater environment are studied for a wide range of aquifer parameters. The coupled governing partial differential equations are nondimensionalized and solved for a two-dimensional, saturated aquifer in the vertical plane for both steady state and transient conditions using an iterative solution procedure. The flow transport is represented either in terms of the stream function or the freshwater hydraulic head.

  11. Thermal well-test method

    DOE Patents [OSTI]

    Tsang, C.F.; Doughty, C.A.

    1984-02-24

    A well-test method involving injection of hot (or cold) water into a groundwater aquifer, or injecting cold water into a geothermal reservoir is disclosed. By making temperature measurements at various depths in one or more observation wells, certain properties of the aquifer are determined. These properties, not obtainable from conventional well test procedures, include the permeability anisotropy, and layering in the aquifer, and in-situ thermal properties. The temperature measurements at various depths are obtained from thermistors mounted in the observation wells.

  12. Low enthalpy convective system in Western Ohio

    SciTech Connect (OSTI)

    Cannon, M.S.; Tabet, C.A.; Eckstein, Y.

    1980-01-01

    A distinct positive anomaly in the temperatures of the shallow (Pleistocene) aquifers along the Cincinnati-Findlay Arch in Western Ohio coincides with a low geothermal gradient. A conceptual model of convective currents associated with a tensional fault and/or fracture system along the crest of the Arch is suggested as an explanation of the anomaly. Hydrochemical information indicates that various quantities of warmer ground water, with the composition characteristics of deep bedrock aquifers, is present as an admixture in the shallow aquifers. This confirms the conceptual model of convection in fractures.

  13. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  14. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore » proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO₂ to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big Sky Carbon Sequestration Project the INL-CAES has developed a rapid, easy to use process that pre-concentrates trace metals, including REE, up to 100x while eliminating interfering ions (e.g. Ba, Cl). The process is straightforward, inexpensive, and requires little infrastructure, using only a single chromatography column with inexpensive, reusable, commercially available resins and wash chemicals. The procedure has been tested with synthetic brines (215,000 ppm or less TDS) and field water samples (up to 5,000 ppm TDS). Testing has produced data of high quality with REE capture efficiency exceeding 95%, while reducing interfering elements by > 99%.« less

  15. CO2 Sequestration Potential of Texas Low-Rank Coals

    SciTech Connect (OSTI)

    Duane McVay; Walter Ayers, Jr.; Jerry Jensen; Jorge Garduno; Gonzola Hernandez; Rasheed Bello; Rahila Ramazanova

    2006-08-31

    Injection of CO{sub 2} in coalbeds is a plausible method of reducing atmospheric emissions of CO{sub 2}, and it can have the additional benefit of enhancing methane recovery from coal. Most previous studies have evaluated the merits of CO{sub 2} disposal in high-rank coals. The objective of this research was to determine the technical and economic feasibility of CO{sub 2} sequestration in, and enhanced coalbed methane (ECBM) recovery from, low-rank coals in the Texas Gulf Coast area. Our research included an extensive coal characterization program, including acquisition and analysis of coal core samples and well transient test data. We conducted deterministic and probabilistic reservoir simulation and economic studies to evaluate the effects of injectant fluid composition (pure CO{sub 2} and flue gas), well spacing, injection rate, and dewatering on CO{sub 2} sequestration and ECBM recovery in low-rank coals of the Calvert Bluff formation of the Texas Wilcox Group. Shallow and deep Calvert Bluff coals occur in two, distinct, coalbed gas petroleum systems that are separated by a transition zone. Calvert Bluff coals < 3,500 ft deep are part of a biogenic coalbed gas system. They have low gas content and are part of a freshwater aquifer. In contrast, Wilcox coals deeper than 3,500 ft are part of a thermogenic coalbed gas system. They have high gas content and are part of a saline aquifer. CO{sub 2} sequestration and ECBM projects in Calvert Bluff low-rank coals of East-Central Texas must be located in the deeper, unmineable coals, because shallow Wilcox coals are part of a protected freshwater aquifer. Probabilistic simulation of 100% CO{sub 2} injection into 20 feet of Calvert Bluff coal in an 80-acre 5-spot pattern indicates that these coals can store 1.27 to 2.25 Bcf of CO{sub 2} at depths of 6,200 ft, with an ECBM recovery of 0.48 to 0.85 Bcf. Simulation results of flue gas injection (87% N{sub 2}-13% CO{sub 2}) indicate that these same coals can store 0.34 to 0.59 Bcf of CO{sub 2} with an ECBM recovery of 0.68 to 1.20 Bcf. Economic modeling of CO{sub 2} sequestration and ECBM recovery indicates predominantly negative economic indicators for the reservoir depths (4,000 to 6,200 ft) and well spacings investigated, using natural gas prices ranging from $2 to $12 per Mscf and CO{sub 2} credits based on carbon market prices ranging from $0.05 to $1.58 per Mscf CO{sub 2} ($1.00 to $30.00 per ton CO{sub 2}). Injection of flue gas (87% N{sub 2} - 13% CO{sub 2}) results in better economic performance than injection of 100% CO{sub 2}. CO{sub 2} sequestration potential and methane resources in low-rank coals of the Lower Calvert Bluff formation in East-Central Texas are significant. The potential CO{sub 2} sequestration capacity of the coals ranges between 27.2 and 49.2 Tcf (1.57 and 2.69 billion tons), with a mean value of 38 Tcf (2.2 billion tons), assuming a 72.4% injection efficiency. Estimates of recoverable methane resources range between 6.3 and 13.6 Tcf, with a mean of 9.8 Tcf, assuming a 71.3% recovery factor. Moderate increases in gas prices and/or carbon credits could generate attractive economic conditions that, combined with the close proximity of many CO{sub 2} point sources near unmineable coalbeds, could enable commercial CO{sub 2} sequestration and ECBM projects in Texas low-rank coals. Additional studies are needed to characterize Wilcox regional methane coalbed gas systems and their boundaries, and to assess potential of other low-rank coal beds. Results from this study may be transferable to other low-rank coal formations and regions.

  16. Microsoft Word - S05072_WaterQualityComplStrategy.doc

    Office of Legacy Management (LM)

    ... S05072 Page 9 MMTS Water Quality Compliance Strategy U.S. Department of Energy Doc. No. ... use of the alluvial aquifer for human consumption, irrigation, or livestock watering. ...

  17. Microsoft Word - Chap3 5-16-05.doc

    Office of Legacy Management (LM)

    ... Because the treatment process is not 100 percent efficient, a small amount of uranium is re-injected into the aquifer with the treated water. The re-injected groundwater increases ...

  18. Property:DOI | Open Energy Information

    Open Energy Info (EERE)

    System (Majorca, Spain) + 10.1016j.jappgeo.2008.05.006 + 4 40 Years Of Dogger Aquifer Management In Ile-De-France, Paris Basin, France + 10.1016j.geothermics.2010.09.005 +...

  19. ''A ground water resources study of a Pacific Ocean atoll - Tarawa, Gilbert Islands,'' by J. W. Lloyd, J. C. Miles, G. R. Chessmand, and S. F. Bugg

    SciTech Connect (OSTI)

    Wheatcraft, S.W.; Buddemeier, R.W.

    1981-10-01

    Several inherent problems in the methodology employed in the ground water resource study of Tarawa Atoll (Lloyd, et al., 1981) are described. Studies of Enewetak Atoll have provided data that require a significantly different conceptual model of the atoll hydrogeology system. Comparison of well, lagoon, and ocean tidal observations with a mathematical model that assumes horizontal tidal propagation indicates that the observed results are more consistent with a system that is controlled by vertical coupling between the unconsolidated surface aquifer and an underlying aquifer of more permeable limestone. This indicates that most fresh water recharged to the aquifer migrates downward and mixes with the sea water in a deeper aquifer providing easy exchange with the ocean. Lloyd, et al., do not take tidal mixing or vertical transport into account and it therefore seems likely that fresh water inventories are significantly overestimated. Failure to include these significant loss terms in the island water budget may also account for calculated heads above ground level. (JMT)

  20. LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reactions that occurred when dilute river water contacted the soil-aquifer and will enable development of new models for predicting the duration of natural flushing in the future. ...

  1. Modeling Hydrogeological and Geomenchanical Processes Related...

    Office of Scientific and Technical Information (OSTI)

    We consider a multilayer system in which the injection zone is situated below a sequence of caprock and aquifer layers that are intersected by a vertical fault zone. The fault zone ...

  2. Microsoft Word - Attach_A_Site Description 2007_Final.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    576-8401 Fax: (865) 576-5728 E-mail: reports@adonis.osti.gov DOENV25946--543-ATT-A ... and Abbreviations AA alluvial aquifer AEC Atomic Energy Commission ATCU argillic tuff ...

  3. Nevada Test Site Environmental Report Attachment A: Site Description

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    576-8401 Fax: (865) 576-5728 E-mail: reports@adonis.osti.gov DOENV25946--790-ATT A ... and Abbreviations AA alluvial aquifer AEC Atomic Energy Commission a.k.a. also known ...

  4. Microsoft Word - 1-SiteDescription Cover DisclaimerTitle Final...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    576-8401 Fax: (865) 576-5728 E-mail: reports@adonis.osti.gov DOENV25946--259 Nevada ... and Abbreviations AA alluvial aquifer AEC Atomic Energy Commission ATICU Ammonia ...

  5. Microsoft Word - Attachment A 2009 Final.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phone: (865) 576-8401 Fax: (865) 576-5728 E-mail: reports@adonis.osti.gov New Name for the ... and Abbreviations AA alluvial aquifer AEC Atomic Energy Commission a.k.a. also known ...

  6. DISCLAIMER

    Office of Legacy Management (LM)

    by U.S. Department of Energy Grand Junction Office ... in the Alluvial Aquifer-Data through September 1997 ... feed, will be pumped to a solar evaporation pond for final ...

  7. How many times can LANL reuse water?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    releasing it back into the environment cleaner than when it was pumped. These uses are in place, not theoretical. Most systems in New Mexico mine water from the aquifer, use it...

  8. Interpretation of earth tide response of three deep, confined...

    Open Energy Info (EERE)

    sfrom earth tide response. Except for the fact that barometric changes act both on the water surface in the well and on the aquifer as a whole while stress changes associated...

  9. C:\\ANNUAL\\Vol2chps.v8\\ANNUAL2.VP

    Gasoline and Diesel Fuel Update (EIA)

    Aquifer Field: A sub-surface facility for storing natural gas consisting of water-bearing ... temperature of 1 pound of water by 1 degree Fahrenheit at or near 39.2 degrees Fahrenheit. ...

  10. http://emdev.apps.em.doe.gov/EMDEV/Pages/groundwaterReport.aspx

    Office of Environmental Management (EM)

    The uppermost aquifer at the Maybell Disposal Site is the upper sandstone unit of the Brown Park Formation. The top of the unconfined groundwater table occurs at depths ranging...

  11. A Transient Model of the Geothermal System of the Long Valley...

    Open Energy Info (EERE)

    flow of hot water in a confined aquifer. The results give information on the transient nature of the geothermal system operating in the Long Valley caldera and on the application...

  12. BASELINE RISK ASSESSMENT OF GROUND WATER CONTAMINATION AT THE...

    Office of Legacy Management (LM)

    ... o 3 meters Iml) below the land surface, a shallow ... The natural ground water from the shallow aquifers is not ... in accordance with the requirements of the Uranium Mill ...

  13. A Semi-Analytical Solution for Large-Scale Injection-Induced...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: A Semi-Analytical Solution for Large-Scale Injection-Induced PressurePerturbation and Leakage in a Laterally Bounded Aquifer-AquitardSystem Citation Details ...

  14. A Semi-Analytical Solution for Large-Scale Injection-Induced...

    Office of Scientific and Technical Information (OSTI)

    Analytical solutions were obtained for (1) the Laplace-transform hydraulic head drawdownrise in the aquifer and in the aquitard, (2) the Laplace-transform rate and volume of ...

  15. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Bacon, Diana H. carbon...

  16. RAPID/Roadmap/19-TX-b | Open Energy Information

    Open Energy Info (EERE)

    19-TX-b.6 - Does the Developer Own the Overlying Land? In Texas, the right to acquire and pump ground water is tied to the ownership of the land overlying the groundwater aquifer....

  17. WATER POLLUTION CONTROL GENERAL PERMIT GNEV93001

    National Nuclear Security Administration (NNSA)

    ... III.D.2. "Aquifer" means a geological formation, group of formations or part of a ... III.D.4. "Composite" sample means a homogeneous combination of discrete samples which ...

  18. Microsoft Word - ExecSum.doc

    Office of Legacy Management (LM)

    ... for the well that was plugged and abandoned. * Re-injection Module - continued injecting water into the aquifer for most of the year via four existing re-injection wells. ...

  19. Microsoft Word - 08101885 DVP.doc

    Office of Legacy Management (LM)

    The water level was measured at each sampled well. Monitor wells with an "SC" s u f f i are completed in the Upper Sand aquifer of the Wind River Formation. Wells with a "DC" ...

  20. National Renewable Energy Laboratory Environmental Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... the Denver Basin, which include the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers, form a layered sequence of rock in an elongated bowl-shaped structural depression. ...

  1. 2009 NREL Environmental Performance Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... the Denver Basin, which include the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers, form a layered sequence of rock in an elongated bowl-shaped structural depression. ...

  2. Geohydrology of Enewetak Atoll islands and reefs

    SciTech Connect (OSTI)

    Buddemeier, R.W.

    1981-05-06

    Extensive tidal studies in island wells and the lagoon at Enewetak Atoll have shown that island ground water dynamics are controlled by a layered aquifer system. The surface aquifer of unconsolidated Holocene material extends to a depth of approximately 15 m, and has a hydraulic conductivity K = 60 m/day. From 15 to 60 m (approximate lagoon depth) the reef structure consists of successive layers of altered Pleistocene materials, with bulk permeability substantially higher than that of the surface aquifer. Because of wave set-up over the windward reef and the limited pass area for outflow at the south end of the atoll, lagoon tides rise in phase with the ocean tides but fall later than the ocean water level. This results in a net lagoon-to-ocean head which can act as the driving force for outflow through the permeable Pleistocene aquifer. This model suggests that fresh water, nutrients or radioactive contaminants found in island ground water or reef interstitial water may be discharged primarily into the ocean rather than the lagoon. Atoll island fresh water resources are controlled by recharge, seawater dilution due to vertical tidal mixing between the surface and deeper aquifers, and by loss due to entrainment by the outflowing water in the deeper aquifers. Estimated lagoon-ot-ocean transit times through the deep aquifer are on the order of a few years, which corresponds well to the freshwater residence time estimates based on inventory and recharge. Islands in close proximity to reef channels have more fresh ground water than others, which is consistent with a locally reduced hydraulic gradient and slower flow through the Pleistocene aquifers.

  3. Glossary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glossary Glossary Alluvial aquifer: The alluvial aquifer is composed of unconsolidated sediments (silt, sand, gravel, cobbles) deposited by stream flow. Alternate concentration limit: Concentration of a constituent that may exceed the maximum concentration limit; or, a limit for a constituent without a maximum concentration limit. If DOE demonstrates, and the U.S. Nuclear Regulatory Commission concurs, that human health and the environment would not be adversely affected, DOE may meet an

  4. Chemical logging of geothermal wells

    DOE Patents [OSTI]

    Allen, Charles A.; McAtee, Richard E.

    1981-01-01

    The presence of geothermal aquifers can be detected while drilling in geothermal formations by maintaining a chemical log of the ratio of the concentrations of calcium to carbonate and bicarbonate ions in the return drilling fluid. A continuous increase in the ratio of the concentrations of calcium to carbonate and bicarbonate ions is indicative of the existence of a warm or hot geothermal aquifer at some increased depth.

  5. Chemical logging of geothermal wells

    DOE Patents [OSTI]

    Allen, C.A.; McAtee, R.E.

    The presence of geothermal aquifers can be detected while drilling in geothermal formations by maintaining a chemical log of the ratio of the concentrations of calcium to carbonate and bicarbonate ions in the return drilling fluid. A continuous increase in the ratio of the concentrations of calcium to carbonate and bicarbonate ions is indicative of the existence of a warm or hot geothermal aquifer at some increased depth.

  6. Title:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-5 Rainfall and the Water Table: The Salinity of Soil http://education.arm.gov Rainfall and the Water Table: The Salinity of Soil: Grades 3-5 1 Rainfall and the Water Table: The Salinity of Soil Approximate Time Setup and initial experiment: 45 minutes, followed by several short time segments to observe, record, and add water to soil. Objective The student will be able to explain how an increase of rainfall influenced by climate change can affect the water table and soil salinity underground as

  7. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Michigan University","USDOE","58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs",,"The Michigan Geological...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (1) enhanced recovery (1) flotation (1) oil wells (1) reservoir rock (1) salinity (1) water (1) waterflooding (1) wettability (1) Filter by Author Mario Blanco (2) Patrick Shuler ...

  9. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PLAN (1066) Expanding the Potential for Saline Formations: Modeling Carbon Dioxide Storage, Water Extraction and Treatment for Power Plant Cooling (1108) Generic Disposal ...

  10. ST 27 cvr pgs.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... With inclusion of freshwater and saline water withdrawals for thermoelectric and ... Electric Power Research Institute, 2002 Mike Hightower, of Sandia's Energy Systems ...

  11. Albany, OR * Anchorage, AK * Morgantown, WV * Pittsburgh, PA...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Simon saline formation. The CO 2 pipeline will originate at the Meredosia power plant site and transport approximately 1 million metric tons (MMT) per year of compressed and ...

  12. DOE-Sponsored Project Begins Demonstrating CCUS Technology in...

    Broader source: Energy.gov (indexed) [DOE]

    Carbon dioxide (CO2) injection has begun at the world's first fully integrated coal power ... of a geologic structure called the Citronelle Dome, within the Paluxy saline formation. ...

  13. index | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Carbon storage involves injection of captured carbon dioxide (CO2) into saline reservoirs ... a multitude of optimization and operation issues realized by fossil fuel power plants. ...

  14. 03-2014 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... as previous endeavors to enhance power plant efficiency and reduce harmful ... Captured CO2 will be stored in the Mt. Simon Sandstone, a prolific saline reservoir in the ...

  15. PowerPoint Presentation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Operational Switch to STAD Canister at Power Plants 1. No near-term changes ... critical for the degraded cases defined - Saline water ( 35 Cl > seawater) could provide ...

  16. Water Infrastructure Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... with a national CO2 storage program utilizing geologic saline formations. Users can run power-plant specific scenarios to capture and store CO2 emissions while ...

  17. listing | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with High Frequency Magnetics Enabled Power NC State University Raleigh, NC EESTSPP... 1.2 - CO2 Storage Efficiency in Deep Saline Formations University of North Dakota ...

  18. Microsoft Word - NRAP-TRS-III-003-2014_Characterization of Experimenta...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... in regions considered for demonstrating geological saline CO 2 sequestration. Environ. ... John Wimer Director Office of Coal and Power R&D National Energy Technology Laboratory ...

  19. Type B Accident Investigation of the Exertional Heat Illnesses...

    Office of Environmental Management (EM)

    ... Treatment included intravenous administration of saline and electrolytes, measures to ... dragged to the Stage 3 shooting box, indicating he could not move under his own power. ...

  20. CPY Document

    Energy Savers [EERE]

    ... Farm LLC, Mexico, MO Central Electric Power Cooperative, Inc, Jefferson City, MO Jimko ... Sarpy LP, Milford, NE Weber & Sons Co, Saline, NE Ellusa Enterprises Inc, Omaha, NE ...