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Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
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1

INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE  

E-Print Network [OSTI]

indicate that coal-derived asphaltenes exhibit an acid-baseanyone functional group is asphaltenes is amphoteric. Theseto oil, and 31.6% to asphaltenes) of a bituminous coal when

Seth, M.

2010-01-01T23:59:59.000Z

2

Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor  

SciTech Connect (OSTI)

Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150{sup o}C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650{sup o}C in the upper part of the fluidized bed combustor seemed to be responsible for the reduction of gaseous chlorine and, consequently, limited mercury emissions reduction during cofiring. 36 refs., 3 figs. 1 tab.

Yan Cao; Hongcang Zhou; Junjie Fan; Houyin Zhao; Tuo Zhou; Pauline Hack; Chia-Chun Chan; Jian-Chang Liou; Wei-ping Pan [Western Kentucky University (WKU), Bowling Green, KY (USA). Institute for Combustion Science and Environmental Technology (ICSET)

2008-12-15T23:59:59.000Z

3

E-Print Network 3.0 - anthracite coal gasification Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

quickly became popular as a household... like Pittsburgh later became principal markets for bituminous coal, which was cheaper than anthracite... : anthracite,...

4

Impacts of halogen additions on mercury oxidation, in a slipstream selective catalyst reduction (SCR), reactor when burning sub-bituminous coal  

SciTech Connect (OSTI)

This paper presents a comparison of impacts of halogen species on the elemental mercury (Hg(0)) oxidation in a real coal-derived flue gas atmosphere. It is reported there is a higher percentage of Hg(0) in the flue gas when burning sub-bituminous coal (herein Powder River Basin (PRB) coal) and lignite, even with the use of selective catalytic reduction (SCR). The higher Hg(0) concentration in the flue gas makes it difficult to use the wet-FGD process for the mercury emission control in coal-fired utility boilers. Investigation of enhanced Hg(0) oxidation by addition of hydrogen halogens (HF, HCl, HBr, and HI) was conducted in a slipstream reactor with and without SCR catalysts when burning PRB coal. Two commercial SCR catalysts were evaluated. SCR catalyst no. 1 showed higher efficiencies of both NO reduction and Hg(0) oxidation than those of SCR catalyst no. 2. NH{sub 3} addition seemed to inhibit the Hg(0) oxidation, which indicated competitive processes between NH{sub 3} reduction and Hg(0) oxidation on the surface of SCR catalysts. The hydrogen halogens, in the order of impact on Hg(0) oxidation, were HBr, HI, and HCl or HF. Addition of HBr at approximately 3 ppm could achieve 80% Hg(0) oxidation. Addition of HI at approximately 5 ppm could achieve 40% Hg(0) oxidation. In comparison to the empty reactor, 40% Hg(0) oxidation could be achieved when HCl addition was up to 300 ppm. The enhanced Hg(0) oxidation by addition of HBr and HI seemed not to be correlated to the catalytic effects by both evaluated SCR catalysts. The effectiveness of conversion of hydrogen halogens to halogen molecules or interhalogens seemed to be attributed to their impacts on Hg(0) oxidation. 30 refs., 4 figs.

Yan Cao; Zhengyang Gao; Jiashun Zhu; Quanhai Wang; Yaji Huang; Chengchung Chiu; Bruce Parker; Paul Chu; Wei-ping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

2008-01-01T23:59:59.000Z

5

Process for separating anthracite coal from impurities  

SciTech Connect (OSTI)

A process is described for separating a first mixture including previously mined anthracite coal, klinker-type cinder ash and other refuse consisting of: a. separating the first mixture to produce a refuse portion and a second mixture consisting of anthracite and klinker-type cinder ash, b. reducing the average particle size in the second mixture to a uniform size, c. subjecting the second mixture to a separating magnetic field to produce a klinker-type cinder ash portion and an anthracite coal portion.

Stiller, D.W.; Stiller, A.H.

1985-05-06T23:59:59.000Z

6

Anthracite Power & Light | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCT Biomass Facility Jumpvolcanic region, California |Anthracite

7

THE EFFECTS OF SOLVENTS ON SUB-BITUMINOUS COAL BELOW ITS PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

48. Table 1. Roland seam coal analyses Proximate analysis: (some ext'racts of Roland seam coal - 4 hours extraction at5. Extraction of Roland seam coal with solvent mixtures for

Grens III., Edward A.

2013-01-01T23:59:59.000Z

8

INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE  

E-Print Network [OSTI]

alkali con- alkali-soluble Seam coal over the temperaturefor the Pittsburgh Seam coal. Another important conclusionVI, Composition of Roland seam coal--ultimate analysis~ wt%,

Seth, M.

2010-01-01T23:59:59.000Z

9

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

variations in coal from rank to rank, mine to mine, seam tocoal was supplied by the Wyodak t. Resources Development Corporation from the Roland top seam

Holten, R.R.

2010-01-01T23:59:59.000Z

10

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

Holten, R.R.

2010-01-01T23:59:59.000Z

11

THE EFFECTS OF SOLVENTS ON SUB-BITUMINOUS COAL BELOW ITS PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

not hexane-solubles ("asphaltenes"), and pyridine- but notfractionated into oils, asphaltenes, and preasphaltenes, alltE;! nded to be largely asphaltenes and preasphaltenes, and

Grens III., Edward A.

2013-01-01T23:59:59.000Z

12

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

molecular-weight ranges of asphaltenes and preasphaltenes.consecutive reactions: coal asphaltenes oil Since the firstfirst being con- verted to asphaltenes. Recently, Sternberg,

Holten, R.R.

2010-01-01T23:59:59.000Z

13

Fine Anthracite Coal Washing Using Spirals  

SciTech Connect (OSTI)

The spiral performed well in cleaning the coarse 8 x 16 mesh size fraction, as demonstrated by the Ep ranging from 0.091 to 0.177. This is in line with typical spiral performance. In addition, the presence of the coarser size fraction did not significantly affect spiral performance on the typical 16 x 100 mesh fraction, in which the Ep ranged from 0.144 to 0.250. Changes in solids concentration and flow rate did not show a clear correlation with spiral performance. However, for difficult-to-clean coals with high near-gravity material, such as this anthracite, a single-stage spiral cleaning such a wide size fraction may not be able to achieve the clean coal ash and yield specifications required. In the first place, while the performance of the spiral on the coarse 8 x 16 mesh fraction is good with regard to Ep, the cutpoints (SG50s) are high (1.87 to 1.92), which may result in a clean coal with a higher-than-desired ash content. And second, the combination of the spiral's higher overall cutpoint (1.80) with the high near-gravity anthracite results in significant misplaced material that increases the clean coal ash error. In a case such as this, one solution may be to reclean the clean coal and middlings from the first-stage spiral in a second stage spiral.

R.P. Killmeyer; P.H. Zandhuis; M.V. Ciocco; W. Weldon; T. West; D. Petrunak

2001-05-31T23:59:59.000Z

14

Hg and Se capture and fly ash carbons from combustion of complex pulverized feed blends mainly of anthracitic coal rank in Spanish power plants  

SciTech Connect (OSTI)

In this work, the petrology and chemistry of fly ashes produced in a Spanish power plant from the combustion of complex pulverized feed blends made up of anthracitic/meta-anthracitic coals, petroleum, and natural coke are investigated. It was found that the behavior of fly ash carbons derived from anthracitic coals follows relatively similar patterns to those established for the carbons from the combustion of bituminous coals. Fly ashes were sampled in eight hoppers from two electrostatic precipitator (ESP) rows. The characterization of the raw ashes and their five sieved fractions (from {gt}150 to {lt}25 {mu}m) showed that glassy material, quartz, oxides, and spinels in different proportions are the main inorganic components. As for the organic fraction, the dominant fly ash carbons are anisotropic carbons, mainly unburned carbons derived from anthracitic vitrinite. The concentration of Se and Hg increased in ashes of the second ESP row, this increase being related to the higher proportion of anisotropic unburned carbons, particularly those largely derived from anthracitic vitrinite in the cooler ashes of the ESP (second row) and also related to the decrease in the flue gas temperature. This suggests that the flue gas temperature plays a major role in the concentration of mercury for similar ratios of unburned carbons. It was also found that Hg is highly concentrated in the medium-coarser fractions of the fly ashes ({gt} 45 {mu}m), there being a positive relationship between the amount of these carbons, which are apparently little modified during the combustion process, in the medium-coarse fractions of the ashes and the Hg retention. According to the results obtained, further research on this type of fly ash could be highly productive. 28 refs., 10 figs., 8 tabs.

I. Surez-Ruiz; J.C. Hower; G.A. Thomas [Instituto Nacional del Carbon (INCAR-CSIC), Oviedo (Spain)

2007-01-15T23:59:59.000Z

15

JV Task 126 - Mercury Control Technologies for Electric Utilities Burning Bituminous Coal  

SciTech Connect (OSTI)

The EERC developed an applied research consortium project to test cost-effective mercury (Hg) control technologies for utilities burning bituminous coals. The project goal was to test innovative Hg control technologies that have the potential to reduce Hg emissions from bituminous coal-fired power plants by {ge}90% at costs of one-half to three-quarters of current estimates for activated carbon injection (ACI). Hg control technology evaluations were performed using the EERC's combustion test facility (CTF). The CTF was fired on pulverized bituminous coals at 550,000 Btu/hr (580 MJ/hr). The CTF was configured with the following air pollution control devices (APCDs): selective catalytic reduction (SCR) unit, electrostatic precipitator (ESP), and wet flue gas desulfurization system (WFDS). The Hg control technologies investigated as part of this project included ACI (three Norit Americas, Inc., and eleven Envergex sorbents), elemental mercury (Hg{sup 0}) oxidation catalysts (i.e., the noble metals in Hitachi Zosen, Cormetech, and Hitachi SCR catalysts), sorbent enhancement additives (SEAs) (a proprietary EERC additive, trona, and limestone), and blending with a Powder River Basin (PRB) subbituminous coal. These Hg control technologies were evaluated separately, and many were also tested in combination.

Jason Laumb; John Kay; Michael Jones; Brandon Pavlish; Nicholas Lentz; Donald McCollor; Kevin Galbreath

2009-03-29T23:59:59.000Z

16

High-pressure gasification of Montana subbituminous coal  

SciTech Connect (OSTI)

A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

Goyal, A.; Bryan, B.; Rehmat, A.

1991-01-01T23:59:59.000Z

17

Method for providing improved solid fuels from agglomerated subbituminous coal  

DOE Patents [OSTI]

A method is provided for separating agglomerated subbituminous coal and the heavy bridging liquid used to form the agglomerates. The separation is performed by contacting the agglomerates with inert gas or steam at a temperature in the range of 250.degree. to 350.degree. C. at substantially atmospheric pressure.

Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Pawlak, Wanda (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

1989-01-01T23:59:59.000Z

18

Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.  

E-Print Network [OSTI]

??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola… (more)

Lumadue, Matthew

2012-01-01T23:59:59.000Z

19

Bituminous pavement recycling Aravind K. and Animesh Das  

E-Print Network [OSTI]

Bituminous pavement recycling Aravind K. and Animesh Das Department of Civil Engineering IIT Kanpur Introduction The bituminous pavement rehabilitation alternatives are mainly overlaying, recycling and reconstruction. In the recycling process the material from deteriorated pavement, known as reclaimed asphalt

Das, Animesh

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Use of POTW biosolids in bituminous concrete  

SciTech Connect (OSTI)

Although wastewater treatment helps alleviate water pollution, it creates residual by-products that can pose a disposal dilemma. Four main practices are presently employed to dispose of wastewater treatment plant sludge: land application, composting, incineration, and landfilling. A fifth disposal method that may help to alleviate the sludge disposal problem in future years is the incorporation of sludge into useful end products such as fertilizer or construction materials. This research was designed to evaluate the properties of bituminous concrete mixes that had anaerobically digested sewage sludge incorporated into their design. In doing so, it was desired to verify the work of Wells concerning sludge incorporation into bituminous concrete mixes using today`s asphalts. Hot mix and cold mix designs were studied.

Smith, R.C. [Jones and Henry Engineers, Ltd., Toledo, OH (United States); Angelbeck, D.I. [Univ. of Toledo, OH (United States)

1995-11-01T23:59:59.000Z

22

Incinerator residue in bituminous base construction  

E-Print Network [OSTI]

for use of the material in a bituminous base. Preliminary investigation on the optimum mix design included Hveem stability, Marshall stability and Durability tests, A test section consisting of the experimental hot-mixed pavement, littercrete, and a... for flexural fatigue tests, Hveem and Marshall stabilities, thermal expansion, direct tension, splitting tensile and Schmidt tests. Four in. (10. 2 cm. ) diameter cores were taken after compaction (before traffic) and after six months in service. Samples...

Haynes, Joseph Anthony

1975-01-01T23:59:59.000Z

23

Emissions, Monitoring, and Control of Mercury from Subbituminous Coal-Fired Power Plants - Phase II  

SciTech Connect (OSTI)

Western Research Institute (WRI), in conjunction with Western Farmers Electric Cooperative (WFEC), has teamed with Clean Air Engineering of Pittsburgh PA to conduct a mercury monitoring program at the WEFC Hugo plant in Oklahoma. Sponsored by US Department of Energy Cooperative Agreement DE-FC-26-98FT40323, the program included the following members of the Subbituminous Energy Coalition (SEC) as co-sponsors: Missouri Basin Power Project; DTE Energy; Entergy; Grand River Dam Authority; and Nebraska Public Power District. This research effort had five objectives: (1) determine the mass balance of mercury for subbituminous coal-fired power plant; (2) assess the distribution of mercury species in the flue gas (3) perform a comparison of three different Hg test methods; (4) investigate the long-term (six months) mercury variability at a subbituminous coal-fired power plant; and (5) assess operation and maintenance of the Method 324 and Horiba CEMS utilizing plant personnel.

Alan Bland; Jesse Newcomer; Allen Kephart; Volker Schmidt; Gerald Butcher

2008-10-31T23:59:59.000Z

24

Evaluation of co-cokes from bituminous coal with vacuum resid or decant oil, and evaluation of anthracites, as precursors to graphite.  

E-Print Network [OSTI]

??Graphite is utilized as a neutron moderator and structural component in some nuclear reactor designs. During the reactor operaction the structure of graphite is damaged… (more)

Nyathi, Mhlwazi

2011-01-01T23:59:59.000Z

25

Process for removing pyritic sulfur from bituminous coals  

DOE Patents [OSTI]

A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

1990-01-01T23:59:59.000Z

26

Influence of the degree of metamorphism and reduction of the anthracites of the Donbas on the properties of the products of their thermal treatment  

SciTech Connect (OSTI)

In the reported experiments, the influence of high-temperature treatment on the structure and properties of anthracites of the Donbas of different degrees of metamorphism and reduction has been studied. It has been shown that on thermal treatment up to 1250/degree/C feebly metamorphosed anthracites achieve structural orderedness to a considerable degree and their use in the electrode industry is possible. The predominating influence of the degree of metamorphism of the initial anthracites on the physicochemical properties of the products of their thermal treatment, as compared with that of the degree of reduction, has been established. 5 refs.

Eremin, I.V.; Ivanov, V.P.; Maloletnev, A.S.; Danilova, R.A.

1981-01-01T23:59:59.000Z

27

Two-stage coprocessing of subbituminous coals and bitumen or heavy oil  

SciTech Connect (OSTI)

Pretreatment of subbituminous coal with an appropriately formulated mix of carbon monoxide and water, in presence of bitumen or heavy oil, results in very fast reactions characterized by a high degree of coal solubilization and deoxygenation. The reaction is catalysed by a mixture of alkali metal carbonates and proceeds readily at 380-400/sup 0/C. The first-stage reaction product appears to be susceptible to further catalytic hydrogenation at 420-460/sup 0/C with gaseous hydrogen yielding 65-70% (on daf feed) of hydrogen-rich distillable oil, composed mainly of naphtha and middle oil. The process flowsheet is presented and the comparative economics of two-stage carbon monoxide/steam-hydrogen and hydrogen-hydrogen coprocessing schemes are discussed.

Ignasiak, B.; Ohuchi, T.; Clark, P.; Aitchison, D.; Lee, T.

1986-09-01T23:59:59.000Z

28

Development of a stack plume opacity index for subbituminous coal-fired utility boilers  

SciTech Connect (OSTI)

Powder River Basin subbituminous coals were burned using conventional and low-NO{sub x} combustion conditions in a drop-tube furnace equipped with a multicyclone ash collection device. Fine ash fractions (< 2 {micro}m in diameter) collected during the tests were analyzed using computer-controlled scanning electron microscopy (CCSEM). Advances in particulate sample preparation methods enabled the CCSEM analysis of individual ash particles with submicron diameters as small as 0.1 {micro}m. The fine ash samples produced from the conventional combustion of coal consisted of discrete spherical particles, whereas particle agglomerates were characteristic of the low-NO{sub x} ash samples. Particle-size distributions of the low-NO{sub x} fine ash fractions were coarser because of the agglomeration. Theoretical light-scattering calculations indicate that for a given coal, the ash produced in low-NO{sub x} conditions causes less opacity as compared to conventional combustion conditions. The following phases were abundant in the ashes: Ca aluminosilicate, Ca aluminate, aluminosilicate, silica, (Ca, Mg)O, CaSO{sub 4}, Na{sub 2} SO{sub 4}, and (Na, K)Cl. Primary mechanisms that produced the fine ash include the thermal metamorphism of small (0.1 to 5 {micro}m) mineral grains and the vaporization and subsequent condensation of organically bound Na, Mg, and Ca, Empirical equations for estimating the concentration of fine ash produced from burning subbituminous coals were formulated into an opacity index based on CCSEM coal mineral and fine ash analyses and on drop-tube furnace testing results. The effects of ash electrical resistivity on electrostatic precipitator collection efficiency are also considered in the index.

Galbreath, K.C.; Zygarlicke, C.J.; McCollor, D.P.; Toman, D.L. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center

1995-12-31T23:59:59.000Z

29

E-Print Network 3.0 - australian bituminous coal Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

extractable material from perhydrous vitrinites Summary: an important role in their coking ability 19. The development of a mobile phase during the bituminous coal... to...

30

Combustion of high-sulfur coal and anthracite wastes in a rotary kiln combustor with an advanced internal air distributor  

SciTech Connect (OSTI)

Fluid bed combustors have received extensive testing with both high-sulfur coal and anthracite wastes. Rotary kilns are effective and popular devices for waste combustion. The Angelo Rotary Furnace{trademark} has been developed to improve the operation of rotary pyrolyzer/combustor systems through enhanced air distribution, which in this process is defined as staged, swirled combustion air injection. Fourteen of these new furnaces have been installed worldwide. Two units in Thailand, designed for rice hull feed with occasional lignite feed, have been recently started up. An older unit in Pennsylvania is being upgraded with a new, more advanced air distribution system for a series of tests this fall in which inexpensive high-sulfur coal and anthracite wastes will be fired with limestone. The purposes of these tests are to determine the burning characteristics of these two fuels in this system, to discover the Ca/S ratios necessary for operation of a rotary kiln combusting these fuels, and to observe the gas-borne emissions from the furnace. An extensive preliminary design study will be performed on a commercial installation for combustion of anthracite wastes. 14 refs., 5 figs., 1 tab.

Cobb, J.T. Jr. (Pittsburgh Univ., PA (USA)); Ahn, Y.K. (Gilbert/Commonwealth, Inc., Reading, PA (USA)); Angelo, J.F. (Universal Energy International, Inc., Little Rock, AR (USA))

1990-01-01T23:59:59.000Z

31

Pore size distribution and accessible pore size distribution in bituminous coals  

SciTech Connect (OSTI)

The porosity and pore size distribution of coals determine many of their properties, from gas release to their behavior on carbonization, and yet most methods of determining pore size distribution can only examine a restricted size range. Even then, only accessible pores can be investigated with these methods. Small-angle neutron scattering (SANS) and ultra small-angle neutron scattering (USANS) are increasingly used to characterize the size distribution of all of the pores non-destructively. Here we have used USANS/SANS to examine 24 well-characterized bituminous and subbituminous coals: three from the eastern US, two from Poland, one from New Zealand and the rest from the Sydney and Bowen Basins in Eastern Australia, and determined the relationships of the scattering intensity corresponding to different pore sizes with other coal properties. The range of pore radii examinable with these techniques is 2.5 nm to 7 {micro}m. We confirm that there is a wide range of pore sizes in coal. The pore size distribution was found to be strongly affected by both rank and type (expressed as either hydrogen or vitrinite content) in the size range 250 nm to 7 {micro}m and 5 to 10 nm, but weakly in intermediate regions. The results suggest that different mechanisms control coal porosity on different scales. Contrast-matching USANS and SANS were also used to determine the size distribution of the fraction of the pores in these coals that are inaccessible to deuterated methane, CD{sub 4}, at ambient temperature. In some coals most of the small ({approx} 10 nm) pores were found to be inaccessible to CD{sub 4} on the time scale of the measurement ({approx} 30 min - 16 h). This inaccessibility suggests that in these coals a considerable fraction of inherent methane may be trapped for extended periods of time, thus reducing the effectiveness of methane release from (or sorption by) these coals. Although the number of small pores was less in higher rank coals, the fraction of total pores that was inaccessible was not rank dependent. In the Australian coals, at the 10 nm to 50 nm size scales the pores in inertinites appeared to be completely accessible to CD{sub 4}, whereas the pores in the vitrinite were about 75% inaccessible. Unlike the results for total porosity that showed no regional effects on relationships between porosity and coal properties, clear regional differences in the relationships between fraction of closed porosity and coal properties were found. The 10 to 50 nm-sized pores of inertinites of the US and Polish coals examined appeared less accessible to methane than those of the inertinites of Australian coals. This difference in pore accessibility in inertinites may explain why empirical relationships between fluidity and coking properties developed using Carboniferous coals do not apply to Australian coals.

Sakurovs, Richard [ORNL; He, Lilin [ORNL; Melnichenko, Yuri B [ORNL; Radlinski, Andrzej Pawell [ORNL; Blach, Tomasz P [ORNL

2012-01-01T23:59:59.000Z

32

Liquefaction of calcium-containing subbituminous coals and coals of lower rank  

DOE Patents [OSTI]

A process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation scale, made up largely of calcium carbonate deposits, e.g., vaterite, which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. A solution of a compound or salt characterized by the formula MX, where M is a Group IA metal of the Periodic Table of the Elements, and X is an anion which is capable of forming water-insoluble, thermally stable calcium compounds, is maintained in contact with a particulate coal feed sufficient to impregnate said salt or compound into the pores of the coal. On separation of the impregnated particulate coal from the solution, the coal can be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of vaterite or other forms of calcium carbonate on reactor surfaces, auxiliary equipment and the like; and the Group IA metal which remains within the liquefaction bottoms catalyzes the reaction when the liquefaction bottoms are subjected to a gasification reaction.

Gorbaty, Martin L. (Sanwood, NJ); Taunton, John W. (Seabrook, TX)

1980-01-01T23:59:59.000Z

33

Investigation of the combustion characteristics of Zonguldak bituminous coal using DTA and DTG  

SciTech Connect (OSTI)

Combustion characteristics of coking, semicoking, and noncoking Turkish bituminous coal samples from Zonguldak basin were investigated applying differential thermal analysis (DTA) and differential thermogravimetry (DTG) techniques. Results were compared with that of the coke from Zonguldak bituminous coal, a Turkish lignite sample from Soma, and a Siberian bituminous coal sample. The thermal data from both techniques showed some differences depending on the proximate analyses of the samples. Noncombustible components of the volatile matter led to important changes in thermal behavior. The data front both methods were, evaluated jointly, and some thermal properties were interpreted considering these methods in a complementary combination.

Haykiri-Acma, H.; Yaman, S.; Kucukbayrak, S.; Okutan, H. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

2006-06-21T23:59:59.000Z

34

Physical and mechanical properties of bituminous mixtures containing oil shales  

SciTech Connect (OSTI)

Rutting of bituminous surfaces on the Jordanian highways is a recurring problem. Highway authorities are exploring the use of extracted shale oil and oil shale fillers, which are abundant in Jordan. The main objectives of this research are to investigate the rheological properties of shale oil binders (conventional binder with various percentages of shale oil), in comparison with a conventional binder, and to investigate the ability of mixes to resist deformation. The latter is done by considering three wearing course mixes containing three different samples of oil shale fillers--which contained three different oil percentages--together with a standard mixture containing limestone filler. The Marshall design method and the immersion wheel tracking machine were adopted. It was concluded that the shale oil binders displayed inconsistent physical properties and therefore should be treated before being used. The oil shale fillers have provided mixes with higher ability to resist deformation than the standard mix, as measured by the Marshall quotients and the wheel tracking machine. The higher the percentages of oil in the oil shale fillers, the lower the ability of the mixes to resist deformation.

Katamine, N.M.

2000-04-01T23:59:59.000Z

35

Surface Properties of Photo-Oxidized Bituminous Coals: Final report  

SciTech Connect (OSTI)

Natural weathering has a detrimental effect on the hydrophobic nature of coal, which in turn can influence clean-coal recovery during flotation. Few techniques are available that can establish the quality of coal surfaces and that have a short analysis time to provide input for process control. Luminescence emissions which can be quantified with an optical microscope and photometer system, are measurably influenced by degree of weathering as well as by mild storage deterioration. In addition, it has been shown that when vitrinite is irradiated with a relatively high intensity flux of violet- or ultraviolet- light in the presence of air, photo-oxidation of the surface occurs. The combination of measuring the change in luminescence emission intensity with degree of surface oxidation provided the impetus for the current investigation. The principal aim of this research was to determine whether clear correlations could be established among surface oxygen functionality, hydrophobicity induced by photo-oxidation, and measurements of luminescence intensity and alteration. If successful, the project would result in quantitative luminescence techniques based on optical microscopy that would provide a measure of the changes in surface properties as a function of oxidation and relate them to coal cleanability. Two analytical techniques were designed to achieve these goals. Polished surfaces of vitrain bands or a narrow size fraction of powdered vitrain concentrates were photo-oxidized using violet or ultraviolet light fluxes and then changes in surface properties and chemistry were measured using a variety of near-surface analytical techniques. Results from this investigation demonstrate that quantitative luminescence intensity measurements can be performed on fracture surfaces of bituminous rank coals (vitrains) and that the data obtained do reveal significant variations depending upon the level of surface oxidation. Photo-oxidation induced by violet or ultraviolet light fluxes does result in a progressive and significant increase in the amount of near-surface oxygen concentration at about the same level regardless of bituminous coal rank. These incremental changes in oxygen concentration appear to lower the hydrophobicity as shown by contact angle measurements on polished surfaces. Although this influence diminished as coal rank increased, the level of oxygen uptake was about the same, suggesting that the type of oxygen functionality formed during oxidation may be of great importance in modifying surface hydrophobicity. Changes in functional-group chemistry, measured by a variety of near-surface techniques, showed a general increase in the concentration of carbonyl-containing groups while those of CH{sub 2} groups decreased. All of these observations follow the trends observed in previous investigations of naturally weathered coals. The photo-oxidation technique also resulted in the development of phenolic, ester and anhydride moieties instead of the expected emplacement of carboxylic acid groups which are normally associated with naturally weathered coals. The importance of this observation is that esters and anhydrides would result in a more hydrophobic surface in comparison to the more hydrophilic surface resulting from acid functionality. This observation is consistent with the results of film flotation of UV-irradiated powdered vitrain in which floatability was generally observed to increase with increasing photo- oxidation.

NONE

1998-09-01T23:59:59.000Z

36

Supporting Information for Historical gaseous and primary aerosol emissions in  

E-Print Network [OSTI]

2104002XXX Bituminous/ Subbituminous Coal Distillate oil 2104004XXX Distillate Oil SO2, PM Natural gas Bituminous/ Subbituminous Coal 101003XX Lignite 2101002XXX Electric Utility Bituminous/ Subbituminous Coal Residual oil 101004XX External Combustion Boilers Residual Oil NOx, SO2, PM 2101005XXX Electric Utility

Meskhidze, Nicholas

37

Assessment of underground coal gasification in bituminous coals. Volume I. Executive summary. Final report  

SciTech Connect (OSTI)

This report describes the bituminous coal resources of the United States, identifies those resources which are potentially amenable to Underground Coal Gasification (UCG), identifies products and markets in the vicinity of selected target areas, identifies UCG concepts, describes the state of the art of UCG in bituminous coal, and presents three R and D programs for development of the technology to the point of commercial viability. Of the 670 billion tons of bituminous coal remaining in-place as identified by the National Coal Data System, 32.2 billion tons or 4.8% of the total are potentially amenable to UCG technology. The identified amenable resource was located in ten states: Alabama, Colorado, Illinois, Kentucky, New Mexico, Ohio, Oklahoma, Utah, Virginia, and West Virginia. The principal criteria which eliminated 87.3% of the resource was the minimum thickness (42 inches). Three R and D programs were developed using three different concepts at two different sites. Open Borehole, Hydraulic Fracture, and Electrolinking concepts were developed. The total program costs for each concept were not significantly different. The study concludes that much of the historical information based on UCG in bituminous coals is not usable due to the poor siting of the early field tests and a lack of adequate diagnostic equipment. This information gap requires that much of the early work be redone in view of the much improved understanding of the role of geology and hydrology in the process and the recent development of analytical tools and methods.

None

1981-01-01T23:59:59.000Z

38

Operation of the NRCh constriction of boilers in 300 MW energy units during combustion of anthracite dust  

SciTech Connect (OSTI)

Operation of the furnace constriction of boilers in 300 MW units during combustion of anthracite dust with liquid slag removal now requires special attention on the part of both operating personnel at thermal power plants and designers. The reason behind this is charring of the studs and carborundum mass on the roof portion of the constriction with subsequent exposure of the tubes; external high-temperature corrosion of the tubes on the roof portion and on the upper incline of the constriction with subsequent tapering of the tube walls to 1.5 mm and their breaking; the presence of corrosion-fatigue destruction of the tube walls in the upper incline of the constriction with formation of scale, transverse deep grooves and fissures on the front side of the tubes. Overall, at the present time the constriction is a point of failure that requires intensified control and greater repair costs to replace damaged sections of the heating surfaces. In conjunction with this, complex analysis of operation of the constriction has been carried out.

Kaminskii, V.P.; Mironov, S.N.

1982-03-01T23:59:59.000Z

39

Fixed-bed gasification research using US coals. Volume 9. Gasification of Elkhorn bituminous coal  

SciTech Connect (OSTI)

A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the ninth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Elkhorn bituminous coal. The period of gasificastion test was September 13 to October 12, 1983. 9 refs., 24 figs., 35 tabs.

Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

1985-05-01T23:59:59.000Z

40

Fixed-bed gasification research using US coals. Volume 7. Gasification of Piney Tipple bituminous coal  

SciTech Connect (OSTI)

A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the seventh volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Piney Tipple bituminous coal. The period of the gasification test was July 18-24, 1983. 6 refs., 20 figs., 17 tabs.

Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

1985-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Fixed-bed gasification research using US coals. Volume 2. Gasification of Jetson bituminous coal  

SciTech Connect (OSTI)

A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report describes the gasification testing of Jetson bituminous coal. This Western Kentucky coal was gasified during an initial 8-day and subsequent 5-day period. Material flows and compositions are reported along with material and energy balances. Operational experience is also described. 4 refs., 24 figs., 17 tabs.

Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

1985-03-31T23:59:59.000Z

42

JV Task-123 Determination of Trace Element Concentrations at an Eastern Bituminous Coal Plant Employing an SCR and Wet FGD  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC), in partnership with Babcock & Wilcox (B&W) and with funding from U.S. Department of Energy (DOE), conducting tests to prove that a high level of mercury control (>90%) can be achieved at a power plant burning a high-sulfur eastern bituminous coal. With funding from the Electric Power Research Institute (EPRI), DOE, and Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates Program, the EERC completed an additional sampling project to provide data as to the behavior of a number of trace elements across the various pollution control devices, with a special emphasis on the wet flue gas desulfurization (FGD) system. Results showed that the concentrations of almost all the elements of interest leaving the stack were very low, and a high percentage of the trace elements were captured in the electrostatic precipitator (ESP) (for most, >80%). Although, with a few exceptions, the overall mass balances were generally quite good, the mass balances across the wet FGD were more variable. This is most likely a result of some of the concentrations being very low and also the uncertainties in determining flows within a wet FGD.

Dennis Laudal

2008-05-01T23:59:59.000Z

43

Assessment of underground coal gasification in bituminous coals: potential UCG products and markets. Final report, Phase I  

SciTech Connect (OSTI)

The following conclusions were drawn from the study: (1) The US will continue to require new sources of energy fuels and substitutes for petrochemical feedstocks into the foreseeable future. Most of this requirement will be met using coal. However, the cost of mining, transporting, cleaning, and preparing coal, disposing of ash or slag and scrubbing stack gases continues to rise; particularly, in the Eastern US where the need is greatest. UCG avoids these pitfalls and, as such, should be considered a viable alternative to the mining of deeper coals. (2) Of the two possible product gases LBG and MBG, MBG is the most versatile. (3) The most logical use for UCG product in the Eastern US is to generate power on-site using a combined-cycle or co-generation system. Either low or medium Btu gas (LBG or MBG) can be used. (4) UCG should be an option whenever surface gasification is considered; particularly, in areas where deeper, higher sulfur coal is located. (5) There are environmental and social benefits to use of UCG over surface gasification in the Eastern US. (6) A site could be chosen almost anywhere in the Illinois and Ohio area where amenable UCG coal has been determined due to the existence of existing transportation or transmission systems. (7) The technology needs to be demonstrated and the potential economic viability determined at a site in the East-North-Central US which has commercial quantities of amenable bituminous coal before utilities will show significant interest.

None

1982-01-31T23:59:59.000Z

44

Development of a pilot-scale kinetic extruder feeder system and test program. Phase I report  

SciTech Connect (OSTI)

This report describes the work done under Phase I, the moisture tolerance testing of the Kinetic Extruder. The following coals were used in the test program: Western Bituminous (Utah), Eastern Bituminous (Pennsylvania), North Dakota Lignite, Sub-Bituminous (Montana), and Eastern Bituminous coal mixed with 20-percent Limestone. The coals were initially tested at the as-received moisture level and subsequently tested after surface moisture was added by water spray. Test results and recommendations for future research and development work are presented.

None

1982-03-01T23:59:59.000Z

45

COAL LIQUEFACTION STUDIES USING PHOSPHORIC ACID AT MODERATE TEMPERATURES AND PRESSURES  

E-Print Network [OSTI]

Analys of Wyodak Roland Seam Coal Froximate Analysis C,T. &THF-extractabilities of a seam coal increased from 12% MAFused Wyodak Roland seam sub-bituminous coal. Consistent with

McLean, J.B.

2010-01-01T23:59:59.000Z

46

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base  

SciTech Connect (OSTI)

By applying the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite production can be modeled with a single Hubbert curve that extends to the practical end of commercial production of this highest-rank coal. The production of bituminous coal from existing mines is about 80% complete and can be carried out at the current rate for the next 20 years. The production of subbituminous coal from existing mines can be carried out at the current rate for 40-45 years. Significant new investment to extend the existing mines and build new ones would have to commence in 2009 to sustain the current rate of coal production, 1 billion tons per year, in 2029. In view of the existing data, we conclude that there is no spare coal production capacity of the size required for massive coal conversion to liquid transportation fuels. Our analysis is independent of other factors that will prevent large-scale coal liquefaction projects: the inefficiency of the process and either emissions of greenhouse gases or energy cost of sequestration.

Croft, Gregory D. [University of California, Department of Civil and Environmental Engineering (United States); Patzek, Tad W. [University of Texas, Department of Petroleum and Geosystems Engineering (United States)], E-mail: patzek@mail.utexas.edu

2009-09-15T23:59:59.000Z

47

Conventional coal preparation in the United States  

SciTech Connect (OSTI)

Processing of bituminous and anthracite coal is widely practiced in the United States and, as mentioned earlier, about 80 percent of the production of these coals is processed as clean coal in preparation plants. Subbituminous coal is not widely processed, primarily because these low rank raw coals are low in sulfur (0.5 to 1.0 percent) and relatively low in ash (8 to 15 percent). They are also relatively low in heat content due to their high inherent moisture. Lignite coals, to the best of the authors{close_quote} knowledge, are not presently being processed in Conventional Coal Preparation plants. This is due to their unstable nature and putting them in water in a coal preparation plant is likely to cause severe degradation in particle size and add to their already high inherent moisture content. The following are the benefits of clean coal processing: produces a uniform product which can be utilized more efficiently; produces a higher quality product which results in higher efficiency at the power station or the steel mill; reduces sulfur dioxide and other adverse stack emissions during coal firing which is a very important environmental consideration; reduces ash or slag handling costs by the user; reduces shipping costs; and reduces handling and storage costs. Processing any stable raw coal in a coal preparation plant will always produce a higher grade product which is a more efficient and a more environmentally acceptable fuel for use at power stations, steel mills, home heating or industrial boilers.

Beck, M.K.; Taylor, B.

1993-12-31T23:59:59.000Z

48

Preparation for upgrading western subbituminous coal  

SciTech Connect (OSTI)

The objective of this project was to establish the physical and chemical characteristics of western coal and determine the best preparation technologies for upgrading this resource. Western coal was characterized as an abundant, easily mineable, clean, low-sulfur coal with low heating value, high moisture, susceptibility to spontaneous ignition, and considerable transit distances from major markets. Project support was provided by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The research was conducted by the Western Research Institute, (WRI) in Laramie, Wyoming. The project scope of work required the completion of four tasks: (1) project planning, (2) literature searches and verbal contacts with consumers and producers of western coal, (3) selection of the best technologies to upgrade western coal, and (4) identification of research needed to develop the best technologies for upgrading western coals. The results of this research suggest that thermal drying is the best technology for upgrading western coals. There is a significant need for further research in areas involving physical and chemical stabilization of the dried coal product. Excessive particle-size degradation and resulting dustiness, moisture reabsorption, and high susceptibility to spontaneous combustion are key areas requiring further research. Improved testing methods for the determination of equilibrium moisture and susceptibility to spontaneous ignition under various ambient conditions are recommended.

Grimes, R.W.; Cha, C.Y.; Sheesley, D.C.

1990-11-01T23:59:59.000Z

49

Study of physical and chemical properties of vitrinites. Inferences on depositional and coalification controls  

E-Print Network [OSTI]

, textural and coking properties was carried out on vitrains from the Puertollano, Blanzy­Montçeau, Asturias (subbituminous/high volatile C bituminous coals). The characteristics of the Puertollano vitrains described here can also be attributed to the telocollinite (>80% vol.) for the high volatile C bituminous coal

Paris-Sud XI, Université de

50

Determination of Mercury in Coal by Isotope Dilution Cold-Vapor Generation Inductively  

E-Print Network [OSTI]

Articles Determination of Mercury in Coal by Isotope Dilution Cold-Vapor Generation Inductively. Approximately 93% of U.S. coal consumption is used to generate electricity, and the U.S. EPA has estimated2 developed for high-accuracy determinations of mer- cury in bituminous and sub-bituminous coals. A closed

51

Evaluation of Control Strategies to Effectively Meet 70-90% Mercury Reduction on an Eastern Bituminous Coal Cyclone Boiler with SCR  

SciTech Connect (OSTI)

This is the final site report for testing conducted at Public Service of New Hampshire's (PSNH) Merrimack Unit 2 (MK2). This project was funded through the DOE/NETL Innovations for Existing Plants program. It was a Phase III project with the goal to develop mercury control technologies that can achieve 50-70% mercury capture at costs 25-50% less than baseline estimates of $50,000-$70,000/lb of mercury removed. While results from testing at Merrimack indicate that the DOE goal was partially achieved, further improvements in the process are recommended. Merrimack burned a test blend of eastern bituminous and Venezuelan coals, for a target coal sulfur content of 1.2%, in its 335-MW Unit 2. The blend ratio is approximately a 50/50 split between the two coals. Various sorbent injection tests were conducted on the flue gas stream either in front of the air preheater (APH) or in between the two in-series ESPs. Initial mercury control evaluations indicated that, without SO3 control, the sorbent concentration required to achieve 50% control would not be feasible, either economically or within constraints specific to the maximum reasonable particle loading to the ESP. Subsequently, with SO{sub 3} control via trona injection upstream of the APH, economically feasible mercury removal rates could be achieved with PAC injection, excepting balance-of-plant concerns. The results are summarized along with the impacts of the dual injection process on the air heater, ESP operation, and particulate emissions.

Tom Campbell

2008-12-31T23:59:59.000Z

52

Preconversion processing of bituminous coals: New directions to improved direct catalytic coal liquefaction. Final report, September 20, 1991--September 19, 1993  

SciTech Connect (OSTI)

One of the main goals for competitive coal liquefaction is to decrease gas yields to reduce hydrogen consumption. Complexing this element as methane and ethane decreases process efficiently and is less cost effective. To decrease the gas yield and increase the liquid yield, an effective preconversion process has been explored on the basis of the physically associated molecular nature of coal. Activities have been focused on two issues: (1) maximizing the dissolution of associated coal and (2) defining the different reactivity associated with a wide molecular weight distribution. Two-step soaking at 350{degrees}C and 400{degrees}C in a recycle oil was found to be very effective for coal solubilization. No additional chemicals, catalysts, and hydrogen are required for this preconversion process. High-volatile bituminous coals tested before liquefaction showed 80--90% conversion with 50--55% oil yields. New preconversion steps suggested are as follows: (1) dissolution of coal with two-step high-temperature soaking, (2) separation into oil and heavy fractions of dissolved coal with vacuum distillation, and (3) selective liquefaction of the separated heavy fractions under relatively mild conditions. Laboratory scale tests of the proposed procedure mode using a small autoclave showed a 30% increase in the oil yield with a 15--20% decrease in the gas yield. This batch operation projects a substantial reduction in the ultimate cost of coal liquefaction.

Not Available

1993-09-01T23:59:59.000Z

53

Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil  

SciTech Connect (OSTI)

In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

2009-05-15T23:59:59.000Z

54

Fly Ash Amendments Catalyze Soil Carbon Sequestration  

SciTech Connect (OSTI)

We tested the effects of four alkaline fly ashes {Class C (sub-bituminous), Class F (bituminous), Class F [bituminous with flue-gas desulfurization (FGD) products], and Class F (lignitic)} on a reaction that simulates the enzyme-mediated formation of humic materials in soils. The presence of FGD products completely halted the reaction, and the bituminous ash showed no benefit over an ash-free control. The sub-bituminous and lignitic fly ashes, however, increased the amount of polymer formed by several-fold. The strong synergetic effect of these ashes when enzyme is present apparently arises from the combined effects of metal oxide co-oxidation (Fe and Mn oxides), alkaline pH, and physical stabilization of the enzyme (porous silica cenospheres).

Amonette, James E.; Kim, Jungbae; Russell, Colleen K.; Palumbo, A. V.; Daniels, William L.

2003-09-15T23:59:59.000Z

55

THE 3R ANTHRACITE CLEAN COAL TECHNOLOGY Economical Conversion of Browncoal to Anthracite Type Clean  

E-Print Network [OSTI]

pac i ties. The 3R An thra cite Clean Coal end prod uct and tech nol ogy may ad van ta geously be in

Edward Someus

56

Catalytic Two-Stage Liquefaction (CTSL{trademark}) process: Laboratory scale studies modelling and technical assessment. Final report, [October 1, 1988--June 30, 1993  

SciTech Connect (OSTI)

Reported herein are the details and results of Laboratory-Scale experiments using sub-bituminous and bituminous coal concluded at Hydrocarbon Research, Inc., under DOE Contract No. AC22-88PCB8818 during the period October 1, 1988 to June 30, 1993. The work described in this report is primarily concerned with tests on a Laboratory Scale primarily using microautoclaves. Experiments were conducted evaluating coal, solvents, start-up oils, catalysts, thermal treatments, C0{sub 2} addition and sulfur compound effects. Other microautoclave tests are included in the companion topical reports for this contract, DE-88818-TOP-01 & 02 on Sub-Bituminous and Bituminous Bench-Scale and PDU activities. In addition to the Laboratory Scale Studies, kinetic data and modelling results from Bench-Scale and Microautoclave tests are interpreted and presented along with some economic updates and sensitivity studies.

Comolli, A.G.; Johanson, E.S.; Lee, L.K.; Popper, G.A.; Smith, T.O.

1993-06-01T23:59:59.000Z

57

Michael Murray, Ph.D. National Wildlife Federation  

E-Print Network [OSTI]

1 Michael Murray, Ph.D. National Wildlife Federation Great Lakes Natural Resource Center Ann Arbor context #12;2 Source: Cassedy and Grossman, Introduction to Energy, 1998 #12;3 Coal Ranks · Anthracite ­ highest rank, high energy content · Bituminous ­ second highest rank, high energy content; typically

O'Donnell, Tom

58

FLY ASH GENERATION AND UTILIZATION -AN OVERVIEW* Tarun R. Naik, Ph.D., P.E.  

E-Print Network [OSTI]

. The Class F fly ashes are normally generated due to combustion of anthracite or bituminous coal. The Class CFLY ASH GENERATION AND UTILIZATION - AN OVERVIEW* By Tarun R. Naik, Ph.D., P.E. Director, Center GENERATION AND UTILIZATION - AN OVERVIEW By Tarun R. Naik, and Shiw S. Singh ABSTRACT This chapter describes

Wisconsin-Milwaukee, University of

59

The variability of fly ash and its effects on selected properties of fresh Portland cement/fly ash mortars  

E-Print Network [OSTI]

the needed quality control of concrete . Another source of concern results from the recent development of lignite and sub-bituminous coal as fuel sources. The ash produced from these coals is of a different chemical composition than traditional bituminous... 50 percent to greater than 200 percent of a control test. An exhaustive literature review has revealed neglig1ble information concerning the PAI of sub- b1tuminous and lignite ashes. Research is greatly needed to determine the ash properties...

McKerall, William Carlton

1980-01-01T23:59:59.000Z

60

CO{sub 2} Sequestration Potential of Charqueadas Coal Field in Brazil  

SciTech Connect (OSTI)

The I2B coal seam in the Charqueadas coal field has been evaluated as a target for enhanced coal bed methane production and CO{sub 2} sequestration. The samples were low rank coals (high volatile bituminous and sub-bituminous) obtained from the I2B seam as ?3? cores. Such properties as sorption capacity, internal structure of the samples, porosity and permeability were of primary interest in this characterization study.

Romanov, V [NETL

2012-10-23T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Next Generation Metallic Iron Nodule Technology in Electric Furnace Steelmaking  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose objective is to investigate reducing processing temperature, controlling the gas temperature and gas atmosphere over metalized iron nodules, and effectively using sub-bituminous coal as a reductant for producing high quality metalized iron nodules at low cost.

62

Exploratory research on novel coal liquefaction concept. Progress report, April 1, 1996--June 30, 1996  

SciTech Connect (OSTI)

Activities this quarter were conducted under Tasks 2, 3, and 5. Task 2 work concentrated on evaluating the effects of low-severity, first-stage reaction conditions on coal conversions of lignite, subbituminous, and bituminous coals. The impact of artificially weathering bituminous coal was investigated. Large quantities of first-stage product were made using the one-liter reactor for subsequent filtration and catalytic upgrading tests. Test conditions and coal conversions for all microautoclave and one-liter tests made this quarter are presented. Filtration tests examined lignite, subbituminous, and bituminous coal products. The effects on resid conversion of second-stage reaction conditions and catalyst recycle were studied. Task 3 work included the successful transfer of first-stage reactor products to a receiver and the design of an interstage filter. Task 5 work included an ongoing review of the technical and patent literature and expansion of the annotated bibliography. Mass and elemental balances were obtained for selected tests.

Burke, F.P.; Brandes, S.D.; Winschel, R.A.

1996-08-12T23:59:59.000Z

63

Pilot plant assessment of blend properties and their impact on critical power plant components  

SciTech Connect (OSTI)

A series of tests were performed to determine the effects of blending eastern bituminous coals with western subbituminous coals on utility boiler operation. Relative to the baseline bituminous coal, the testing reported here indicated that there were significant impacts to boiler performance due to the blending of the eastern and western coals. Results indicated that fuel blending can be used to adequately control flue gas emissions of both SO{sub 2} and NO{sub x} at the expense of reduced milling efficiency, increased sootblowing in the high-temperature and low-temperature regions of the boiler and, to a lesser extent, decreased collection efficiency for an electrostatic precipitator. The higher reactivity of the subbituminous coal increased the overall combustion efficiency, which may tend to decrease the impact of milling efficiency losses. The extent of these impacts was directly related to the percentage of subbituminous coal in the blends. At the lowest blend ratios of subbituminous coal, the impacts were greatly reduced.

NONE

1996-10-01T23:59:59.000Z

64

Measurement of Sorption-Induced Strain  

SciTech Connect (OSTI)

Strain caused by the adsorption of gases was measured in samples of subbituminous coal from the Powder River basin of Wyoming, U.S.A. and high-volatile bituminous coal from east-central Utah, U.S.A. using an apparatus developed jointly at the Idaho National Laboratory (Idaho Falls, Idaho, U.S.A.) and Colorado School of Mines (Golden, Colorado, U.S.A.). The apparatus can be used to measure strain on multiple small coal samples based on the optical detection of the longitudinal strain instead of the more common usage of strain gauges, which require larger samples and longer equilibration times. With this apparatus, we showed that the swelling and shrinkage processes were reversible and that accurate strain data could be obtained in a shortened amount of time. A suite of strain curves was generated for these coals using gases that included carbon dioxide, nitrogen, methane, helium, and various mixtures of these gases. A Langmuir-type equation was applied to satisfactorily model the strain data obtained for pure gases. The sorption-induced strain measured in the subbituminous coal was larger than the high-volatile bituminous coal for all gases tested over the range of pressures used in the experimentation, with the CO2-induced strain for the subbituminous coal over twice as great at the bituminous coal.

Eric P. Robertson; Richard L. Christiansen

2005-05-01T23:59:59.000Z

65

Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies. Final report, [October 1, 1988--July 31, 1993  

SciTech Connect (OSTI)

This is the final report of a four year and ten month contract starting on October 1, 1988 to July 31, 1993 with the US Department of Energy to study and improve Close-Coupled Catalytic Two-Stage Direct Liquefaction of coal by producing high yields of distillate with improved quality at lower capital and production costs in comparison to existing technologies. Laboratory, Bench and PDU scale studies on sub-bituminous and bituminous coals are summarized and referenced in this volume. Details are presented in the three topical reports of this contract; CTSL Process Bench Studies and PDU Scale-Up with Sub-Bituminous Coal-DE-88818-TOP-1, CTSL Process Bench Studies with Bituminous Coal-DE-88818-TOP-2, and CTSL Process Laboratory Scale Studies, Modelling and Technical Assessment-DE-88818-TOP-3. Results are summarized on experiments and studies covering several process configurations, cleaned coals, solid separation methods, additives and catalysts both dispersed and supported. Laboratory microautoclave scale experiments, economic analysis and modelling studies are also included along with the PDU-Scale-Up of the CTSL processing of sub-bituminous Black Thunder Mine Wyoming coal. During this DOE/HRI effort, high distillate yields were maintained at higher throughput rates while quality was markedly improved using on-line hydrotreating and cleaned coals. Solid separations options of filtration and delayed coking were evaluated on a Bench-Scale with filtration successfully scaled to a PDU demonstration. Directions for future direct coal liquefaction related work are outlined herein based on the results from this and previous programs.

Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.; Popper, G.A.; Stalzer, R.H.; Smith, T.O.

1993-06-01T23:59:59.000Z

66

Modelling of NO{sub x} reduction strategies applied to 350 MW(e) utility boilers  

SciTech Connect (OSTI)

A computational fluid dynamics model has been combined with a NO{sub x} chemistry post-processor to predict the formation and destruction of nitric oxide in three-dimensional furnaces burning pulverized fuel. The model considers the complex interaction of turbulent flow, heat transfer, combustion, and NO{sub x} reaction chemistry. Lagrangian particle dynamics are used to track burning pulverized coal particles through the computational cells. Fuel nitrogen is released in proportion to the burnout of the particle. A range of combustion NO{sub x} reduction strategies has been applied to two 350 MW(e) utility boilers burning different coals. A medium volatile bituminous coal is fired using low NO{sub x} burners in one furnace and a sub-bituminous coal is burnt using conventional swirl burners in a different furnace. The strategies include: burner out of service, overfire air, reduction in excess air, change in particle size, and fuel reburn. In general NO{sub x} predictions are better for the sub-bituminous coal than for the medium volatile bituminous coal. Typical NO{sub x} prediction errors are {+-} 10 percent.

Visona, S.P.; Singh, B. [AUSTA Electric, Brisbane (Australia); Stanmore, B.R. [Dept. of Chemical Engineering, Brisbane (Australia)

1997-07-01T23:59:59.000Z

67

THE 3R ANTHRACITE CLEAN COAL TECHNOLOGY Economical Conversion of Browncoal to Anthracite Type Clean Coal by Low Temperature Carbonization Pre-Treatment Process  

E-Print Network [OSTI]

The pre ven tive pre-treat ment of low grade solid fu els is safer, faster, better, and less costly vs. the “end-of-the-pipe ” post treat ment so lu tions. The “3R ” (Re cy cle-Re duce-Re use) in te grated en vi ron-ment con trol tech nol ogy pro vides pre ven tive pre-treat ment of low grade solid fu els, such as brown coal and con tam i nated solid fu els to achieve high grade cleansed fu els with an thra cite and coke com-pa ra ble qual ity. The goal of the 3R tech nol ogy is to pro vide cost ef fi cient and en vi ron men tally sus-tain able so lu tions by pre ven tive pre-treat ment means for ex tended op er a tions of the solid fuel com-bus tion power plants with ca pac ity up to 300 MWe power ca pac i ties. The 3R An thra cite Clean Coal end prod uct and tech nol ogy may ad van ta geously be in te grated to the oxyfuel – oxy-fir ing, Fos ter Wheeler an thra cite arc-fired util ity type boiler and Heat Pipe Re former tech nol o gies in com bi na tion with CO2 cap ture and stor age pro grams. The 3R tech nol ogy is pat ented orig i nal so lu tion. Ad van tages. Feedstock flex i bil ity: ap pli ca tion of pre-treated multi fu els from wider fuel se lec tion and avail abil ity. Im proved burn ing ef fi ciency. Tech nol ogy flex i bil ity: ef fi cient and ad van ta geous inter-link to proven boiler tech nol o gies, such as oxyfuel and arc-fired boil ers. Near zero pol lut ants for haz ard ous-air-pol lut ants: pre ven tive sep a ra tion of halo gens and heavy met als into small vol ume streams prior uti li za tion of cleansed fu els. ?97 % or ganic sul phur re moval achieved by the 3R ther-

Edward Someus

68

New coal technology to flourish at Kentucky plant  

SciTech Connect (OSTI)

Within four years a 76 MW (net) advanced supercritical coal unit, TC2, will go into service at the Trimble County power plant on the Ohio River near Louiseville, KY, USA. The unit is designed to burn a blend of eastern bituminous and western sub-bituminous Powder River Basin coals. TC2 is one of four US power plants to receive a $125 m tax credit under the 2005 EPACT Qualifying Advanced Coal Program for high efficiency and low emission generating units. Trimble County is owned and operated by E.ON US subsidiaries Kentucky Utilities and Louiseville Gas & Electric. It was originally designed to accommodate four 500 MW coal-fired units fired by bituminous coal from the Illinois Basin. 1 photo.

Blankinship, S.

2007-08-15T23:59:59.000Z

69

INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

this substance could be added to a poor coking coal in ordersubstance from the coal called the "coking principle." Itcoking properties. These attempts failed, but they provided the starting point for further investigation of coal

Dorighi, G.P.

2010-01-01T23:59:59.000Z

70

ENERGY AND ENVIRONMENT DIVISION. INTERACTION OF ORGANIC SOLVENT WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

I. Analysis of Roland seam coal by the Commercial TestingTable II. Analysis of Roland Seam Coal by the University ofextraction of Rolland Seam coal at 2500C for 4 hr. Yields

Lindsey, D.

2011-01-01T23:59:59.000Z

71

INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

Extraction of Roland Seam Coal vi th Pyridine, Quinoline,analysis of the Roland Seam Coal used in this investigation.I. Analysis of Roland seam coal by the Commercial Testing

Dorighi, G.P.

2010-01-01T23:59:59.000Z

72

Western fuels symposium. 19th international conference on lignite, brown, and subbituminous coals. Proceedings  

SciTech Connect (OSTI)

Topics covered at the conference include: advanced power systems; environmental issues and control technologies - multipollutants and mercury; power plant systems performance; fuel by-products utilization; fuel properties and upgrading; coalbed methane and water minimization; and carbon sequestration. A few of the papars only consist of a printout of the overheads/viewgraphs. The proceedings are also available on CD-ROM.

NONE

2004-07-01T23:59:59.000Z

73

INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

Mass Spectroscopy Oil, Asphaltene, Preasphaltene Separationextract which contained an asphaltene fraction amounting tofractions of oils, asphaltenes, and preasphaltenes by its

Dorighi, G.P.

2010-01-01T23:59:59.000Z

74

Evaluation of an alternative bituminous material as a soil stabilizer  

E-Print Network [OSTI]

granular base materials, the PRB material coated soil or aggregate particles and decreased the volume of voids, which can be thought as potential water flow channels. Consequently, the PRB material is expected to reduce permeability....

Kim, Yong-Rak

1999-01-01T23:59:59.000Z

75

Predictors of plasticity in bituminous coals. Final technical report  

SciTech Connect (OSTI)

A group of 40 hvb coals, mostly from western Kentucky fields, has been examined with regard to ASTM Gieseler plastometric properties. Twenty-nine of these coals have also been studied over a range of temperatures by isothermal Gieseler plastometry. Raw Gieseler data provide melting and coking slopes and readily calculable fluidity spans. Maximum fluidity by slope intersection is a more consistent measure than observed maximum fluidity. Isothermal slopes and maximum fluidities follow Arrhenius temperature dependencies, with activation energies related systematically to fluid properties. These freshly sampled coals are also characterized by chemical, physical and petrographic criteria, by quantitative solvent extractions, by pyrolysis gas chromatography, by Fourier Transform infrared analysis of coals and extraction residues, by the HPLC analysis of coal extracts, and by optical microscopy of coals and Gieseler semi-coke residues. Multiple linear regression analysis yields three-term expressions which estimate maximum fluidities (both ASTM and isothermal) with R values of .90 to .92. Slopes and critical temperatures are similarly predictable. Plastometer experiments with selected coals under superatmospheric pressures show both melting slopes and maximum fluidities to be sharply increased, the latter by one to three orders of magnitude. Some suggestions are offered to accommodate this new information into the general body of knowledge concerning the phenomenon of plasticity in mid-ranked coals. 81 references, 28 figures, 40 tables.

Lloyd, W. G.; Reasoner, J. W.; Hower, J. C.; Yates, L. P.; Clark, C. P.; Davis, E.; Fitzpatrick, A.; Irefin, A.; Jiminez, A.; Jones, T. M.

1984-02-01T23:59:59.000Z

76

Updated Costs (June 2011 Basis) for Selected Bituminous Baseline...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 - GEE IGCC without CO 2 capture * Case 2 - GEE IGCC with CO 2 capture * Case 9 - Subcritical PC without CO 2 capture * Case 10 - Subcritical PC with CO 2 capture * Case 11 -...

77

Updated Costs (June 2011 Basis) for Selected Bituminous Baseline Cases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field Emission SEM with EDAXUpdated Capital Cost

78

NETL - Bituminous Baseline Performance and Cost Interactive Tool | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Powerstories onFocus Area EnergyMohawkaccrediationNASA-SurfaceNEPA Home

79

E-Print Network 3.0 - abandoned anthracite mines Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the most likely exposure scenario... to this are Native Americans who live around the uranium mines and personnel who may work around the sites... . In addition, the number of...

80

E-Print Network 3.0 - anthracite mines mines Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Land Management over Endangered Species Act violations connected to Grand Canyon uranium mining... of the Arizona 1 uranium mine, located just north of Grand Canyon...

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

E-Print Network 3.0 - anthracite Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Source: Fusiongnition Research Experiment (FIRE) Collection: Plasma Physics and Fusion 75 Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions...

82

The status of coal briquetting technology in Korea  

SciTech Connect (OSTI)

Anthracite is the only indigenous fossil fuel resource produced in Korea and is an important main source of residential fuel. Due to its particular characteristics, the best way to use Korean coal is in the form of briquettes, called {open_quotes}Yontan.{close_quotes} The ability to use this coal as briquettes was a great discovery made nearly 50 years ago and since then, has made a great contribution to the energy consumption of low and middle income households. Korean anthracite in coal briquette form has been used widely for household heating purposes. Collieries in Korea produced no more than one million tons of anthracite annually in the 1960s. Production, however, increased substantially up to about 17 million tons per year in the mid-1970s. In 1986, Korea succeeded in raising its coal production to 24.2 million tons, which was the maximum production level achieved by the Korean coal industrial sector. Since then, anthracite production has fallen. In 1991, coal output dropped to 15.1 million tons, a decrease of 12.2 percent from the 17.2 million tons produced in 1990, due to falling coal demand and rising labor costs. The role of coal as an energy source will be more important in the future to meet projected economic growth in Korea. While the production of indigenous Korean anthracite is expected to decrease under a coal mining rationalization policy, imports of bituminous coal will increase rapidly and will be used as an oil substitute in industry and power generation. In this chapter, general aspects of the Korean coal industry and coal utilization for residential uses, especially the Yontan coal briquetting techniques, are discussed. In addition, coal briquetting technology applications suitable for the APEC region will be presented.

Choi, Woo-Zin

1993-12-31T23:59:59.000Z

83

Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification  

SciTech Connect (OSTI)

This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

None

1982-01-01T23:59:59.000Z

84

EA-1616: National Carbon Research Center Project at Southern Company Services' Power Systems Development Facility near Wilsonville, Alabama  

Broader source: Energy.gov [DOE]

This EA evaluates and updates the potential environmental impacts of DOE’s proposed continued operations of the NCCC Project at the PSDF plant. The NCCC is designed to test and evaluate carbon dioxide (CO2) control technologies for power generation facilities, including CO2 capture solvents and sorbents, mass-transfer devices, lower cost water-gas shift reactors, and scaled-up membrane technologies. Additionally, the NCCC evaluates methods to integrate CO2 capture technologies with other coal-based power plant systems by testing both pre-combustion and post-combustion technologies. The NCCC provides the capability to test these systems under a wide range of fuels, including bituminous and sub-bituminous coals, lignites and biomass/coal mixtures. The goal of the NCCC project is to accelerate the development, optimization, and commercialization of viable CO2 control technologies.

85

In-situ coal gasification: a new technology  

SciTech Connect (OSTI)

While the technology for underground gasification of Western US subbituminous coals is advancing through efforts at the Hanna and Hoe Creek test sites, the development of an Eastern bituminous coal technology has only begun. The Pricetown 1 field test proved the feasibility of gasifying the thin-seam, swelling bituminous coal resources. Key issues remaining to be demonstrated include an effective linkage method, means of controlling gas production and composition, and scale-up. A major field-test program could entail three phases: (1) resolving the linkage and process control problems in the Appalachian basin, (2) assessing the technology in the untested Illinois basin, and (3) testing a multimodule commercial-scale prototype.

Agarwal, A.K.; Zielinski, R.E.; Seabaugh, P.W.; Liberatore, A.J.; Martin, J.W.

1982-01-01T23:59:59.000Z

86

Coal desulfurization in a rotary kiln combustor. Final report, March 15, 1990--July 31, 1991  

SciTech Connect (OSTI)

The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

Cobb, J.T. Jr.

1992-09-11T23:59:59.000Z

87

Coal desulfurization in a rotary kiln combustor  

SciTech Connect (OSTI)

The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

Cobb, J.T. Jr.

1992-09-11T23:59:59.000Z

88

Coal Reburning for Cyclone Boiler NO[sub x] Control Demonstration  

SciTech Connect (OSTI)

The project involves retrofitting/testing the reburning technology at Wisconsin Power Light's 100 MWe Nelson Dewey unit No. 2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO[sub x] emission levels. The final set of performance tests on Lamar coal were carried out from September 27 through October 9, 1992. Hazardous air pollutant (HAP) testing was performed on Lamar coal from November 2 through November 9, 1992. Also, parametric optimization testing on western sub-bituminous coal was performed from November 16 through December 11, 1992. Both the HAP and western fuel testing were additions to the original project testing scope of Phase III. As of the end of this quarterly report period, project Phase III testing is complete. Preliminary results with western sub-bituminous coal indicate NO[sub 4] reductions in excess of 50% down to the 50% load range. In general, similar reductions are experienced but at a less aggressive stoichiometry in the reburn zone. Accordingly, an additional few percent of NO[sub 4] reduction at the same stoichiometry are noted with the western fuel compared to Lamar results.

Not Available

1992-01-01T23:59:59.000Z

89

Coal Reburning for Cyclone Boiler NO{sub x} Control Demonstration. Quarterly report No. 11, October--December 1992  

SciTech Connect (OSTI)

The project involves retrofitting/testing the reburning technology at Wisconsin Power & Light`s 100 MWe Nelson Dewey unit No. 2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO{sub x} emission levels. The final set of performance tests on Lamar coal were carried out from September 27 through October 9, 1992. Hazardous air pollutant (HAP) testing was performed on Lamar coal from November 2 through November 9, 1992. Also, parametric optimization testing on western sub-bituminous coal was performed from November 16 through December 11, 1992. Both the HAP and western fuel testing were additions to the original project testing scope of Phase III. As of the end of this quarterly report period, project Phase III testing is complete. Preliminary results with western sub-bituminous coal indicate NO{sub 4} reductions in excess of 50% down to the 50% load range. In general, similar reductions are experienced but at a less aggressive stoichiometry in the reburn zone. Accordingly, an additional few percent of NO{sub 4} reduction at the same stoichiometry are noted with the western fuel compared to Lamar results.

Not Available

1992-12-31T23:59:59.000Z

90

DOE Underground-Coal-Conversion-Program field-test activities for 1979 and 1980. [Pricetown 1, Hoe Creek 3, Hanna IV, and SDB 1  

SciTech Connect (OSTI)

Under the US Department of Energy's Underground-Coal-Conversion program, four field tests were completed in 1979 and preparations were begun in 1980 for two additional field tests to be operated in 1981. The Laramie Energy Technology Center (LETC) and Sandia National Laboratories (SNL) completed Hanna IV, an air gasification test in Wyoming subbituminous coal. The Morgantown Energy Technology Center (METC) completed Pricetown 1, an air gasification test in West Virginia bituminous coal. Lawrence Livermore National Laboratory (LLNL) completed Hoe Creek 3, a steam-oxygen gasification test in Wyoming subbituminous coal. Gulf Research and Development Co. completed Steeply Dipping Beds (SDB) Test 1, primarily an air gasification test in Wyoming subbituminous coal and the first SDB test in the US. In 1980, Gulf R and D Co. began preparation of SDB Test 2, scheduled for operation in the fall of 1981. The DOE project teams at LETC, METC, LLNL, and SNL, in association with the Washington Irrigation and Development Co. (WIDCo), Washington Water Power (WWP), and the State of Washington, are preparing a field test site in the Centralia-Chehalis coal district of Washington. A series of large coal block tests will be completed prior to the field test, scheduled for operation in 1982 or 1983. This field test will utilize a directionally drilled link and steam-oxygen gasification system. This paper summarizes the results of the four recently completed field tests and the plans for additional tests.

Bartke, T.C.

1983-08-01T23:59:59.000Z

91

Rice Hull Silica, A Silicon Carbide Precursor For Collagen, Lignin And Silicon Metal Powder Bindered Anthracite Briquettes.  

E-Print Network [OSTI]

??Foundry coke is currently the primary energy source of U.S. iron foundries employing cupolas to produce iron. The availability, cost and environmental impact of this… (more)

Jiles, Allura

2013-01-01T23:59:59.000Z

92

Coal Reburning for Cyclone Boiler NO{sub x} Control Demonstration. Quarterly report No. 12, January--March 1993  

SciTech Connect (OSTI)

The project involves retrofitting/testing the reburning technology at Wisconsin Power & Light`s 100 MWe Nelson Dewey Unit {number_sign}2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO{sub x} emission levels. Based upon the data collected and evaluated f or reburn No{sub x} reduction performance with the Lamar Indiana bituminous coal f or boiler loads of 110 MW, 82 MW, and 60 MW, average NO{sub x} reductions of 52.4%, 50.1% and 35.8%, respectively were achieved. Average emissions of NO{sub x}with reburn in operation were 290 ppm (.39 lb/million Btu) , 265 ppm (.36 lb/million Btu) and 325 ppm (.44 lb/million Btu) respectively, all corrected to 3% 02 content. Boiler efficiency losses due to increased unburned carbon in the ash were 0.1% at 110 NW, .25% at 83 MW and 1.5% at 60 MW. Reburn performance results with western sub-bituminous coal at 110 MW, 82 MW and 60 MW boiler loads indicated NO{sub x} reductions of 55.4%, 52.1% and 52.6% respectively. Under optimal conditions, NO{sub x} reductions approaching 63% were achieved with the more reactive western sub-bituminous coal. Boiler efficiency losses due to increased unburned carbon in the ash were unchanged at full load, a loss of 0.2% at 83 MW and a loss of .3% at low load, much improved over results with the Lamar coal.

Not Available

1993-07-01T23:59:59.000Z

93

Coal Reburning for Cyclone Boiler NO[sub x] Control Demonstration  

SciTech Connect (OSTI)

The project involves retrofitting/testing the reburning technology at Wisconsin Power Light's 100 MWe Nelson Dewey Unit [number sign]2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO[sub x] emission levels. Based upon the data collected and evaluated f or reburn No[sub x] reduction performance with the Lamar Indiana bituminous coal f or boiler loads of 110 MW, 82 MW, and 60 MW, average NO[sub x] reductions of 52.4%, 50.1% and 35.8%, respectively were achieved. Average emissions of NO[sub x]with reburn in operation were 290 ppm (.39 lb/million Btu) , 265 ppm (.36 lb/million Btu) and 325 ppm (.44 lb/million Btu) respectively, all corrected to 3% 02 content. Boiler efficiency losses due to increased unburned carbon in the ash were 0.1% at 110 NW, .25% at 83 MW and 1.5% at 60 MW. Reburn performance results with western sub-bituminous coal at 110 MW, 82 MW and 60 MW boiler loads indicated NO[sub x] reductions of 55.4%, 52.1% and 52.6% respectively. Under optimal conditions, NO[sub x] reductions approaching 63% were achieved with the more reactive western sub-bituminous coal. Boiler efficiency losses due to increased unburned carbon in the ash were unchanged at full load, a loss of 0.2% at 83 MW and a loss of .3% at low load, much improved over results with the Lamar coal.

Not Available

1993-01-01T23:59:59.000Z

94

Mineral matter transformations in a pressurized drop-tube furnace  

SciTech Connect (OSTI)

To meet the objectives of the program, a pressurized combustion vessel was built to allow the operating parameters of a direct-fired gas turbine combustor to be simulated. One goal in building this equipment was to design the gas turbine simulator as small as possible to reduce the quantity of test fuel needed, while not undersizing the combustor such that wall effects had a significant effect on the measured combustion performance. Based on computer modeling, a rich-lean, two-stage, nonslagging combustor was constructed to simulate a direct-fired gas turbine. This design was selected to maximize the information that could be obtained on the impact of low-rank coal`s unique properties on the gas turbine combustor, its turbomachinery, and the required hot-gas cleanup devices (such as high-temperature/high-pressure (HTHP) cyclones). Seventeen successful combustion tests using coal-water fuels were completed. These tests included seven tests with a commercially available Otisca Industries-produced, Taggart seam bituminous fuel and five tests each with physically and chemically cleaned Beulah-Zap lignite and a chemically cleaned Kemmerer subbituminous fuel. LRC-fueled heat engine testing conducted at the Energy and Environmental Research Center (EERC) has indicated that LRC fuels perform very well in short residence time heat engine combustion systems. Analyses of the emission and fly ash samples highlighted the superior burnout experienced by the LRC fuels as compared to the bituminous fuel even under a longer residence time profile for the bituminous fuel.

Swanson, M.L.; Tibbetts, J.E.

1992-12-31T23:59:59.000Z

95

Mineral matter transformations in a pressurized drop-tube furnace  

SciTech Connect (OSTI)

To meet the objectives of the program, a pressurized combustion vessel was built to allow the operating parameters of a direct-fired gas turbine combustor to be simulated. One goal in building this equipment was to design the gas turbine simulator as small as possible to reduce the quantity of test fuel needed, while not undersizing the combustor such that wall effects had a significant effect on the measured combustion performance. Based on computer modeling, a rich-lean, two-stage, nonslagging combustor was constructed to simulate a direct-fired gas turbine. This design was selected to maximize the information that could be obtained on the impact of low-rank coal's unique properties on the gas turbine combustor, its turbomachinery, and the required hot-gas cleanup devices (such as high-temperature/high-pressure (HTHP) cyclones). Seventeen successful combustion tests using coal-water fuels were completed. These tests included seven tests with a commercially available Otisca Industries-produced, Taggart seam bituminous fuel and five tests each with physically and chemically cleaned Beulah-Zap lignite and a chemically cleaned Kemmerer subbituminous fuel. LRC-fueled heat engine testing conducted at the Energy and Environmental Research Center (EERC) has indicated that LRC fuels perform very well in short residence time heat engine combustion systems. Analyses of the emission and fly ash samples highlighted the superior burnout experienced by the LRC fuels as compared to the bituminous fuel even under a longer residence time profile for the bituminous fuel.

Swanson, M.L.; Tibbetts, J.E.

1992-01-01T23:59:59.000Z

96

Enhancement of pulverized coal combustion by plasma technology  

SciTech Connect (OSTI)

Plasma-assisted pulverized coal combustion is a promising technology for thermal power plants (TPP). This article reports one- and three- dimensional numerical simulations, as well as laboratory and industrial measurements of coal combustion using a plasma-fuel system (PFS). The chemical kinetic and fluid mechanics involved in this technology are analysed. The results show that a PFS, can be used to promote early ignition and enhanced stabilization of a pulverized coal flame. It is shown that this technology, in addition to enhancing the combustion efficiency of the flame, reduces harmful emissions from power coals of all ranks (brown, bituminous, anthracite and their mixtures). Data summarising the experience of 27 pulverized coal boilers in 16 thermal power plants in several countries (Russia, Kazakhstan, Korea, Ukraine, Slovakia, Mongolia and China), embracing steam productivities from 75 to 670 tons per hour (TPH), are presented. Finally, the practical computation of the characteristics of the PFS, as function of coal properties, is discussed.

Gorokhovski, M.A.; Jankoski, Z.; Lockwood, F.C.; Karpenko, E.I.; Messerle, V.E.; Ustimenko, A.B. [University of Rouen, Rouen (France)

2007-07-01T23:59:59.000Z

97

Evaluation of reclaimed rubber in bituminous pavements. Final report, July 1993-April 1995  

SciTech Connect (OSTI)

Section 1038 of the 1991 Intermodel Surface Transportation efficiency Act (ISTEA) mandated use of crumb rubber from scrap tires in asphalt pavement starting in FY 94. To gain some experience, the Illinois Department of Transportation (IDOT) constructed five demonstration projects in 1993 and one in 1994. All used the `dry process` to introduce crumb rubber into the mix. With the dry process, crumb rubber is added to the heated aggregate prior to addition of asphalt cement (AC). Three projects used very low addition rates. Each was divided into five equal segments. One segment, the control, used no crumb rubber. The other segments used 1/2, 1, 1 1/2 and 2 pounds of crumb rubber per ton of hot mix. The other three projects each used 20 pounds of crumb rubber per ton of hot mix. Both batch plants and drier-drum plants were used, and the crumb rubber was supplied in pre-measured batch-size packets, 50-pound paper bags and 2000-pound super sacks.

Trepanier, J.

1995-06-01T23:59:59.000Z

98

E-Print Network 3.0 - adaptation and use of bituminous materials...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University, School of Forest Resources and Environmental Science, Aspen FACE (Free-Air Carbon Dioxide Enrichment) Experiment Collection: Environmental Sciences and Ecology ;...

99

Development and evaluation of an automated reflectance microscope system for the petrographic characterization of bituminous coals  

SciTech Connect (OSTI)

The development of automated coal petrographic techniques will lessen the demands on skilled personnel to do routine work. This project is concerned with the development and successful testing of an instrument which will meet these needs. The fundamental differences in reflectance of the three primary maceral groups should enable their differentiation in an automated-reflectance frequency histogram (reflectogram). Consequently, reflected light photometry was chosen as the method for automating coal petrographic analysis. Three generations of an automated system (called Rapid Scan Versions I, II and III) were developed and evaluated for petrographic analysis. Their basic design was that of a reflected-light microscope photometer with an automatic stage, interfaced with a minicomputer. The hardware elements used in the Rapid Scan Version I limited the system's flexibility and presented problems with signal digitization and measurement precision. Rapid Scan Version II was designed to incorporate a new microscope photometer and computer system. A digital stepping stage was incorporated into the Rapid Scan Version III system. The precision of reflectance determination of this system was found to be +- 0.02 percent reflectance. The limiting factor in quantitative interpretation of Rapid Scan reflectograms is the resolution of reflectance populations of the individual maceral groups. Statistical testing indicated that reflectograms were highly reproducible, and a new computer program, PETAN, was written to interpret the curves for vitrinite reflectance parameters ad petrographic.

Hoover, D. S.; Davis, A.

1980-10-01T23:59:59.000Z

100

Eastern gas shales bibliography selected annotations: gas, oil, uranium, etc. Citations in bituminous shales worldwide  

SciTech Connect (OSTI)

This bibliography contains 2702 citations, most of which are annotated. They are arranged by author in numerical order with a geographical index following the listing. The work is international in scope and covers the early geological literature, continuing through 1979 with a few 1980 citations in Addendum II. Addendum I contains a listing of the reports, well logs and symposiums of the Unconventional Gas Recovery Program (UGR) through August 1979. There is an author-subject index for these publications following the listing. The second part of Addendum I is a listing of the UGR maps which also has a subject-author index following the map listing. Addendum II includes several important new titles on the Devonian shale as well as a few older citations which were not found until after the bibliography had been numbered and essentially completed. A geographic index for these citations follows this listing.

Hall, V.S. (comp.)

1980-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Solvent extraction of bituminous coals using light cycle oil: characterization of diaromatic products in liquids  

SciTech Connect (OSTI)

Many studies of the pyrolytic degradation of coal-derived and petroleum-derived aviation fuels have demonstrated that the coal-derived fuels show better thermal stability, both with respect to deposition of carbonaceous solids and cracking to gases. Much previous work at our institute has focused on the use of refined chemical oil (RCO), a distillate from the refining of coal tar, blended with light cycle oil (LCO) from catalytic cracking of vacuum gas oil. Hydroprocessing of this blend forms high concentrations of tetralin and decalin derivatives that confer particularly good thermal stability on the fuel. However, possible supply constraints for RCO make it important to consider alternative ways to produce an 'RCO-like' product from coal in an inexpensive process. This study shows the results of coal extraction using LCO as a solvent. At 350{sup o}C at a solvent-to-coal ratio of 10:1, the conversions were 30-50 wt % and extract yields 28-40 wt % when testing five different coals. When using lower LCO/coal ratios, conversions and extract yields were much smaller; lower LCO/coal ratios also caused mechanical issues. LCO is thought to behave similarly to a nonpolar, non-hydrogen donor solvent, which would facilitate heat-induced structural relaxation of the coal followed by solubilization. The main components contributed from the coal to the extract when using Pittsburgh coal are di- and triaromatic compounds. 41 refs., 3 figs., 12 tabs.

Josefa M. Griffith; Caroline E. Burgess Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States). EMS Energy Institute

2009-09-15T23:59:59.000Z

102

Evaluation of methods of mixing lime in bituminous paving mixtures in batch and drum plants  

E-Print Network [OSTI]

prepared mixtures, field mixtures obtained at the plant and pavement cores. Laboratory tests included Hveem and Marshall stability, resilient modulus and indirect tension. Mixture conditioning to evaluate resistance to moisture damage included vacuum... Mixed and Compacted Specimens Tensile Strength Ratio for Laboratory Mixed and Compacted Specimens 14 Marshall Stability Before and After 7-days Soaking in Water for Lab Mixed and Compacted Specimens 36 FIGURE Page 15 16 Hveem Stability Before...

Button, Joseph Wade

1984-01-01T23:59:59.000Z

103

Predictors of plasticity in bituminous coals. Technical progress report No. 7  

SciTech Connect (OSTI)

The 40-coal database for the prediction of the plastic properties of hvb coals has been completed. Statistical analysis has been commenced. Most of the 37 ostensibly independent experimental variables and the 22 derived variables are shown to have little or no predictive power. Approximately a dozen independent variables appear to be systematically related to plasticity. Maximum fluidity can be determined in several ways from Gieseler plastometer data. Under both ASTM and isothermal conditions, maximum fluidity can be predicted using just two independent variables with a standard linear regression model of the form ln(maximum fluidity) = ..beta../sub 0/ + ..beta../sub 1/*V/sub 1/ + ..beta../sub 2/*V/sub 2/ with correlation coefficients greater than .85. The use of three or four independent variables permits predictions with R greater than .90. Pyrolysis gas chromatography has emerged as a powerful and relatively inexpensive new tool for the characterization of coals. In conjunction with studies of extraction, extract characteristics, and residue swelling, pyrolysis/GC affords insights into the basic factors determining the plastic behavior of coals.

Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Clark, C.P.; Davis, E.; Fitzpatrick, A.; Reagles, C.L.; Whitt, J.M.

1983-06-13T23:59:59.000Z

104

Predictors of plasticity in bituminous coals. Technical progress report No. 2, March 1, 1982  

SciTech Connect (OSTI)

The approach of this study is to secure three dozen (or more) coals of varying rank, composition and plasticity, and to analyze these coals carefully by standard chemical and petrographic techniques. The bitumen fractions will be determined, both by THF (asphaltenes but not preasphaltenes) and DMF (everything). Pyrolysis gas chromatography on both whole coals and extracted residues will compare capacities to generate metaplast. Extracts from coals with plasticities differing by at least four orders of magnitude will be examined for identifiable differences; extraction residues will be subjected to differential FTIR analysis. All of the data will be combined and subjected to systematic statistical analysis with the objective of identifying predictors of coal plasticity. This report describes the work in the first six months of the study. During this period equipment and instrumentation has been obtained, 24 coal samples have been obtained, the nonclassical methods have been developed and checked out, and an appreciable amount of experimentl data has been obtained.

Lloyd, W. G.; Reasoner, J. W.; Hower, J. C.; Yates, L. P.; Clark, C. P.; Jones, T. M.; Sturgeon, L. P.; Whitt, J. M.

1982-03-01T23:59:59.000Z

105

Predictors of plasticity in bituminous coals. Technical progress report No. 5. [Gieseler plastometer  

SciTech Connect (OSTI)

The forty fresh coal samples have been obtained, and the proximate, ultimate and petrographic characterization on all samples is now completed. ASTM Gieseler plastometry analyses have been completed on all 40 coals, in quadruplicate, and the melting and coking slopes and intersection maximum fluidities have been estimated. Significant progress has been made in completing the nonstandard analyses which will provide an important part of the project database. Fifteen coals have been subjected to the 20-run sets of isothermal Gieseler analyses; the balance of this group is expected to be completed by mid-1983. Pyrolysis gas chromatogrpahy has been completed for 36 of the 40 coals. Quantitative extractions have now been completed for 32 of the 40 coals, both with tegrahydrofuran and with dimethylformamide. FTIR spectra have been obtained in sets of three (whole coal, residue from THF extraction, residue from DMF extraction) for 31 of the 40 coals. This report also includes a descriptive study by optical microscopy of selected coals and semi-cokes derived from these coals. Future work will include correlation analysis of the completed datasets, and an intensive study of the characteristics of six or seven coals selected from the present set.

Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Whitt, J.M.

1982-12-01T23:59:59.000Z

106

Predictors of plasticity in bituminous coals. Technical progress report No. 3, June 1, 1982  

SciTech Connect (OSTI)

An additional 13 coals have been obtained, bringing the total to 37. Classical chemical and petrographic characterizations have been completed for most of the coals now in hand. The database for analytical pyrolysis/gas chromatography and for quantitative extraction (THF and DMF) has been more than doubled. The procedures for Fourier Transform infrared analysis have been further modified, making use of a new micropulverizer and drying system, and a procedure for the production of uniform and reproducible KBr pellets has been developed and is now in use. The first analytical isothermal plastometry (AIP) data have been obtained, on two highly plastic coals, and additional data are now being generated. Additional work will be carried out with the pyrolysis/GC system and the THF and DMF extraction work. With the progress made in FTIR spectra acquisition, it is expected to complete acquisition and storage of raw coal spectra and to commence application of techniques to provide differential spectrometric information. HPLC analysis of extracts now appears ready for standardization of procedure. Finally, with the data available, statistical analytical work will be initiated.

Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Jones, T.M.; Sturgeon, L.P.; Whitt, J.M.

1982-06-01T23:59:59.000Z

107

Predictors of plasticity in bituminous coals. Technical progress report No. 4, Part I of II  

SciTech Connect (OSTI)

We have substantially enlarged the analytical database developed from the first 37 coals obtained for this study. Pyrolysis/GC has now been completed for 30 coals, and THF and DMF quantitative extractions for 23 coals. FT-IR spectra have been obtained and disc-stored for all coals; differential analysis of these data is now commencing. The first statistical trial runs have been made. ASTM maximum fluidity can be predicted by a simple two-variable regression equation with R = 0.95. This initial success encourages us to undertake a more sophisticated examination of the interdependencies which are becoming evident as the database is built. Under the original work plan we are to enter an intensive Phase 2 study of six selected coals by January 1983.

Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Jones, T.M.; Whitt, J.M.

1982-09-01T23:59:59.000Z

108

Predictors of plasticity in bituminous coals. Technical progress report No. 1  

SciTech Connect (OSTI)

The first dozen coals - high volatile B and C from western Kentucky - have been identified and samples obtained. Classical analyses are nearly completed on this first group. Method development work has been undertaken and is substantially completed for pyrolysis gas chromatography, quantitative extraction of bitumen fraction, and isothermal plastometry. The principal item of new equipment, a Fourier transform infrared spectrometer, has been purchased and has been delivered. It is planned to acquire and to commence classical (ASTM and petrographic) characterization of the second dozen coals to be used, and to commence the systematic acquisition of isothermal plastometric data, GC pyrograms, and quantitative extractions. Development work will be initiated on the statistical analytical approaches to be used, with the expectation of commencing the first statistical analysis in May 1982.

Lloyd, W.G.; Reasoner, J.W.; Jiminez, A.; Hower, J.C.; Yates, L.P.; Jones, T.M.

1981-12-01T23:59:59.000Z

109

Predictors of plasticity in bituminous coals. Technical progress report No. 8  

SciTech Connect (OSTI)

The greater part of the present study on predictors of coal fluidity has now been completed, with most of the developed database presented in the preceding Technical Progress Report. The one critical area in which we have fallen behind schedule is that of isothermal fluidity measurements at superatmospheric pressures. During the past quarter we have made several modifications to the experimental high-pressure Gieseler plastometer, and have been able to complete over 60 superatmospheric runs. This work will be completed and analyzed within the period of the 90-day no-cost extension which has been granted. The extra time has permitted completion of additional experiments in solvent extraction. During this period we have also completed characterization of THF extracts by HPLC, and characterization of coals, coal extraction residues and selected extracts by FTIR. 13 references, 25 tables.

Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Clark, C.P.; Davis, E.; Fitzpatrick, A.; Reagles, C.L.; Whitt, J.M.

1983-09-01T23:59:59.000Z

110

Predictors of plasticity in bituminous coals. Technical progress report No. 6  

SciTech Connect (OSTI)

We have completed the pyrolysis/gas chromatographic analysis of all 40 coals in the present study, at two temperatures, 450/sup 0/ and 650/sup 0/C. We have also completed triplicate quantitative extraction analyses of all 40 coals, using tetrahydrofuran as the extractant solvent, and have completed a parallel set of extractions using N,N-dimethylformamide as the extractant solvent. In addition, we have completed analysis of over 100 additional isothermal Gieseler plastometer runs, and have made the first series of quantitative estimates of H(aromatic)/H(aliphatic) ratios from Fourier Transform Infrared Spectroscopy data. Exploratory work has begun on the petrographic characterization of the semi-coke residues from Gieseler plastometer runs, and also in characterizing THF extracts by thin layer chromatography and by column chromatography (quantitative group separations). Proximate, ultimate and petrographic characterization of the 40 coals has been completed previously. We are now prepared to start a study, using freshly re-sampled coals, of the effects of varying pressure upon the several parameters of fluidity.

Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Fitzpatrick, A.; Whitt, J.M.

1983-03-01T23:59:59.000Z

111

Thermo-Viscoelastic-Viscoplastic-Viscodamage-Healing Modeling of Bituminous Materials: Theory and Computation  

E-Print Network [OSTI]

……………… ……… 341 9.6. Extrapolation of the Rutting in 3D.……....………… 348 9.7. Comparison with Experimental Results.….………… 351 9.8. Conclusions………………………………………… 354 xviii CHAPTER Page X CONCLUSIONS AND RECOMMENDATIONS..…………… 356 10... prediction using viscoelastic- viscoplastic model and experimental data for the cyclic stress control test at 19oC when the stress amplitude is 750kPa. (a) Loading cycles 1-30; (b) Loading cycles 970-980……………….. 268 7.36 Comparison of the VE...

Darabi Konartakhteh, Masoud

2012-10-19T23:59:59.000Z

112

Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar  

SciTech Connect (OSTI)

In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

2006-10-15T23:59:59.000Z

113

Encoal mild coal gasification project: Final design modifications report  

SciTech Connect (OSTI)

The design, construction and operation Phases of the Encoal Mild Coal Gasification Project have been completed. The plant, designed to process 1,000 ton/day of subbituminous Power River Basin (PRB) low-sulfur coal feed and to produce two environmentally friendly products, a solid fuel and a liquid fuel, has been operational for nearly five years. The solid product, Process Derived Fuel (PDF), is a stable, low-sulfur, high-Btu fuel similar in composition and handling properties to bituminous coal. The liquid product, Coal Derived Liquid (CDL), is a heavy, low-sulfur, liquid fuel similar in properties to heavy industrial fuel oil. Opportunities for upgrading the CDL to higher value chemicals and fuels have been identified. Significant quantities of both PDF and CDL have been delivered and successfully burned in utility and industrial boilers. A summary of the Project is given.

NONE

1997-07-01T23:59:59.000Z

114

KINETIC STUDY OF COAL AND BIOMASS CO-PYROLYSIS USING THERMOGRAVIMETRY  

SciTech Connect (OSTI)

The objectives of this study are to investigate thermal behavior of coal and biomass blends in inert gas environment at low heating rates and to develop a simplified kinetic model using model fitting techniques based on TGA experimental data. Differences in thermal behavior and reactivity in co-pyrolysis of Powder River Basin (PRB) sub-bituminous coal and pelletized southern yellow pine wood sawdust blends at low heating rates are observed. Coal/wood blends have higher reactivity compared to coal alone in the lower temperature due to the high volatile matter content of wood. As heating rates increase, weight loss rates increase. The experiment data obtained from TGA has a better fit with proposed two step first order reactions model compared single first order reaction model.

Wang, Ping; Hedges, Sheila; Chaudharib, Kiran; Turtonb, Richard

2013-10-29T23:59:59.000Z

115

Lawrence Livermore National Laboratory underground coal gasification data base. [US DOE-supported field tests; data  

SciTech Connect (OSTI)

The Department of Energy has sponsored a number of field projects to determine the feasibility of converting the nation's vast coal reserves into a clean efficient energy source via underground coal gasification (UCG). Due to these tests, a significant data base of process information has developed covering a range of coal seams (flat subbituminous, deep flat bituminous and steeply dipping subbituminous) and processing techniques. A summary of all DOE-sponsored tests to data is shown. The development of UCG on a commercial scale requires involvement from both the public and private sectors. However, without detailed process information, accurate assessments of the commercial viability of UCG cannot be determined. To help overcome this problem the DOE has directed the Lawrence Livermore National Laboratory (LLNL) to develop a UCG data base containing raw and reduced process data from all DOE-sponsored field tests. It is our intent to make the data base available upon request to interested parties, to help them assess the true potential of UCG.

Cena, R. J.; Thorsness, C. B.

1981-08-21T23:59:59.000Z

116

Thermodynamic properties of pulverized coal during rapid heating devolatilization processes. Quarterly progress report, April--June 1993  

SciTech Connect (OSTI)

Knowledge of the thermodynamic and morphological properties of coal associated with rapid heating decomposition pathways is essential to progress in coal utilization technology. Specifically, knowledge of the heat of devolatilization, surface area and density of coal as a function of rank characteristics, temperature and extent of devolatilization in the context of rapid heating conditions is essential to the fundamental determination of kinetic parameters of coal devolatilization. These same properties are also needed to refine existing devolatilization sub-models utilized in large-scale modeling of coal combustion systems. The objective of this research is to obtain data on the thermodynamic properties and morphology of coal under conditions of rapid heating. Specifically, the total heat of devolatilization, external surface area, BET surface area and true density will be measured for representative coal samples. The coal ranks to be investigated will include a high volatile A bituminous (PSOC 1451 D) and a low volatile bituminous (PSOC 1516D). An anthracite (PSOC 1468) will be used as a non-volatile coal reference. In addition, for one coal, the contribution of each of the following components to the overall heat of devolatilization will be measured: the specific heat of coal/char during devolatilization, the heat of thermal decomposition of the coal, the specific heat capacity of tars, and the heat of vaporization of tars.

Proscia, W.M.; Freihaut, J.D.

1993-08-01T23:59:59.000Z

117

Oxidative derivatization and solubilization of coal. Final report. Period: October 1, 1986 - April 30, 1988  

SciTech Connect (OSTI)

We investigated the solubilization of coal by oxidative means to produce motor fuels. Nitric acid was used in the first of two approaches taken to cleave aliphatic linkages in coal and reduce the size of its macrostructure. Mild conditions, with temperatures up to a maximum of 75 C, and nitric acid concentrations below 20% by weight, characterize this process. The solid product, obtained in high yields, is soluble in polar organic solvents. Lower alcohols, methanol in particular, are of interest as carrier solvents in diesel fuel applications. Coals investigated were New York State peat, Wyodak subbituminous coal, North Dakota lignite, and Illinois No. 6 bituminous coal. The lower tank coals were easily converted and appear well suited to the process, while the bituminous Illinois No. 6 and Pitt Seam coals were unreactive. We concentrated our efforts on Wyodak coal and North Dakota lignite. Reaction conditions with regards to temperature, acid concentration, and time were optimized to obtain high product selectivity at maximum conversion. A continuous process scheme was developed for single pass coal conversions of about 50% to methanol-soluble product.

Schulz, J.G.; Porowski, E.N.; Straub, A.M.

1988-05-01T23:59:59.000Z

118

Market assessment of PFBC ash use  

SciTech Connect (OSTI)

Pressurized fluidized bed combustion (PFBC) of coal is undergoing demonstration in the United States, as well as throughout the world. American Electric Power`s (AEP`s) bubbling PFBC 70 MWe Tidd demonstration program in Ohio and pilot-scale development at Foster Wheeler Energia Oy 10 MWth circulating PFBC at Karhula, Finland, have demonstrated the advantages of PFBC technology. Further technology development in the US is planned with the deployment of the technology at the MacIntosh Clean Coal project in Lakeland, Florida. Development of uses for solid wastes from PFBC coal-fired power systems is being actively pursued as part of the demonstration of PFBC technologies. Ashes collected from Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, operating on (1) low sulfur subbituminous and (2) high sulfur bituminous coal; and ash from the AEP`s high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at Western Research Institute (WRI).

Bland, A. E.; Brown, T. H., Western Research Institute

1998-01-01T23:59:59.000Z

119

Alaska coal geology, resources, and coalbed methane potential  

SciTech Connect (OSTI)

Estimated Alaska coal resources are largely in Cretaceous and Tertiary rocks distributed in three major provinces, Northern Alaska-Slope, Central Alaska-Nenana, and Southern Alaska-Cook Inlet. Cretaceous resources, predominantly bituminous coal and lignite, are in the Northern Alaska-Slope coal province. Most of the Tertiary resources, mainly lignite to subbituminous coal with minor amounts of bituminous and semianthracite coals, are in the other two provinces. The combined measured, indicated, inferred, and hypothetical coal resources in the three areas are estimated to be 5,526 billion short tons (5,012 billion metric tons), which constitutes about 87 percent of Alaska's coal and surpasses the total coal resources of the conterminous United States by 40 percent. Coal mining has been intermittent in the Central Alaskan-Nenana and Southern Alaska-Cook Inlet coal provinces, with only a small fraction of the identified coal resource having been produced from some dozen underground and strip mines. Alaskan coals have a lower sulfur content (averaging 0.3 percent) than most coals in the conterminous United States and are within or below the minimum sulfur value mandated by the 1990 Clean Air Act amendments. Another untapped potential resource is coalbed methane estimated to total 1,000 trillion cubic feet (28 trillion cubic meters).

Romeo M. Flores; Gary D. Stricker; Scott A. Kinney

2005-11-15T23:59:59.000Z

120

Hardgrove grindability study of Powder River Basin and Appalachian coal components in the blend to a midwestern power station  

SciTech Connect (OSTI)

Five coals representing four distinct coal sources blended at a midwestern power station were subjected to detailed analysis of their Hardgrove grindability. The coals are: a low-sulfur, high volatile A bituminous Upper Elkhorn No. 3 coal (Pike County, KY); a medium-sulfur, high volatile A bituminous Pittsburgh coal (southwestern PA); a low-sulfur, subbituminous Wyodak coal from two mines in the eastern Powder River Basin (Campbell County, WY). The feed and all samples processed in the Hardgrove grindability test procedure were analyzed for their maceral and microlithotype content. The high-vitrinite Pittsburgh coal and the relatively more petrographically complex Upper Elkhorn No. 3 coal exhibit differing behavior in grindability. The Pittsburgh raw feed, 16x30 mesh fraction (HGI test fraction), and the {minus}30 mesh fraction (HGI reject) are relatively similar petrographically, suggesting that the HGI test fraction is reasonably representative of the whole feed. The eastern Kentucky coal is not as representative of the whole feed, the HGI test fraction having lower vitrinite than the rejected {minus}30 mesh fraction. The Powder River Basin coals are high vitrinite and show behavior similar to the Pittsburgh coal.

Padgett, P.L.; Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States)

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Catalytic steam gasification reactivity of HyperCoals produced from different rank of coals at 600-775{degree}C  

SciTech Connect (OSTI)

HyperCoal is a clean coal with ash content <0.05 wt %. HyperCoals were prepared from a brown coal, a sub-bituminous coal, and a bituminous raw coal by solvent extraction method. Catalytic steam gasification of these HyperCoals was carried out with K{sub 2}CO{sub 3} at 775, 700, 650, and 600 {degree}C, and their rates were compared. HyperCoals produced from low-rank coals were more reactive than those produced from the high-rank coals. XRD measurements were carried out to understand the difference in gasification reactivity of HyperCoals. Arrhenius plot of ln (k) vs 1/T in the temperature range 600-825{degree}C was a curve rather than a straight line. The point of change was observed at 700{degree}C for HyperCoals from low-rank coals and at 775{degree}C for HyperCoals from high-rank coals. Using HyperCoal produced from low-rank coals as feedstock, steam gasification of coal may be possible at temperatures less than 650{degree}C. 22 refs., 6 figs., 2 tabs.

Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group, Energy Technology Research Institute

2008-11-15T23:59:59.000Z

122

TOXIC SUBSTANCES FROM COAL COMBUSTION--A COMPREHENSIVE ASSESSMENT, PHASE II: ELEMENT MODES OF OCCURRENCE FOR THE OHIO 5/6/7, WYODAK AND NORTH DAKOTA COAL SAMPLES  

SciTech Connect (OSTI)

This study reports on the second phase (Phase II) of USGS research activities in support of DOE contract DE-AC22-95PC95101 ''Toxic Substances From Coal Combustion--A Comprehensive Assessment'', funded under DOE Interagency Agreement DE-AI22-95PC95145. The purpose of the study was to provide a quantitative and semi-quantitative characterization of the modes of occurrence of trace elements in coal samples investigated under Phase II, including (1) Ohio 5/6/7, an Ohio bituminous coal sample blended from the No.5, No.6, and No.7 beds; (2) North Dakota, a lignite sample from the Falkirk Mine, Underwood, ND, and (3) Wyodak, a sub-bituminous coal sample from the Cordero Mine, Gillette, WY. Samples from these coal beds were selected for their range in rank and commercial applicability. Results of this research provide basic information on the distribution of elements in Phase II coal samples, information needed for development of a commercial predictive model for trace-element behavior during coal combustion.

Allan Kolker; Stanley J. Mroczkowski; Curtis A. Palmer; Kristen O. Dennen; Robert B. Finkelman; John H. Bullock Jr.

2002-05-30T23:59:59.000Z

123

The Mesaba Energy Project: Clean Coal Power Initiative, Round 2  

SciTech Connect (OSTI)

The Mesaba Energy Project is a nominal 600 MW integrated gasification combine cycle power project located in Northeastern Minnesota. It was selected to receive financial assistance pursuant to code of federal regulations (?CFR?) 10 CFR 600 through a competitive solicitation under Round 2 of the Department of Energy?s Clean Coal Power Initiative, which had two stated goals: (1) to demonstrate advanced coal-based technologies that can be commercialized at electric utility scale, and (2) to accelerate the likelihood of deploying demonstrated technologies for widespread commercial use in the electric power sector. The Project was selected in 2004 to receive a total of $36 million. The DOE portion that was equally cost shared in Budget Period 1 amounted to about $22.5 million. Budget Period 1 activities focused on the Project Definition Phase and included: project development, preliminary engineering, environmental permitting, regulatory approvals and financing to reach financial close and start of construction. The Project is based on ConocoPhillips? E-Gas? Technology and is designed to be fuel flexible with the ability to process sub-bituminous coal, a blend of sub-bituminous coal and petroleum coke and Illinois # 6 bituminous coal. Major objectives include the establishment of a reference plant design for Integrated Gasification Combined Cycle (?IGCC?) technology featuring advanced full slurry quench, multiple train gasification, integration of the air separation unit, and the demonstration of 90% operational availability and improved thermal efficiency relative to previous demonstration projects. In addition, the Project would demonstrate substantial environmental benefits, as compared with conventional technology, through dramatically lower emissions of sulfur dioxide, nitrogen oxides, volatile organic compounds, carbon monoxide, particulate matter and mercury. Major milestones achieved in support of fulfilling the above goals include obtaining Site, High Voltage Transmission Line Route, and Natural Gas Pipeline Route Permits for a Large Electric Power Generating Plant to be located in Taconite, Minnesota. In addition, major pre-construction permit applications have been filed requesting authorization for the Project to i) appropriate water sufficient to accommodate its worst case needs, ii) operate a major stationary source in compliance with regulations established to protect public health and welfare, and iii) physically alter the geographical setting to accommodate its construction. As of the current date, the Water Appropriation Permits have been obtained.

Stone, Richard; Gray, Gordon; Evans, Robert

2014-07-31T23:59:59.000Z

124

Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry  

SciTech Connect (OSTI)

High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2005-12-01T23:59:59.000Z

125

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China  

E-Print Network [OSTI]

factor of bituminous coal, coking coal, and coke consumed inprice of Bituminous coal, coking coal, and coke consumed in

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

126

Enhanced Combustion Low NOx Pulverized Coal Burner  

SciTech Connect (OSTI)

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

2007-06-30T23:59:59.000Z

127

Coal in National Petroleum Reserve in Alaska (NPRA): framework geology and resources  

SciTech Connect (OSTI)

The North Slope of Alaska contains huge resources of coal, much of which lies within NPRA. The main coal-bearing units, the Corwin and Chandler Formations of the Nanushuk Group (Lower and Upper Cretaceous), underlie about 20,000 mi/sup 2/ (51,800 km/sup 2/) of NPRA. They contain low-sulfur, low-ash, and probable coking-quality coal in gently dipping beds as thick as 20 ft (6.1 m) within stratigraphic intervals as thick as 4500 ft (1370 m). Lesser coal potential occurs in other Upper Cretaceous units and in Lower Mississippian and Tertiary strata. The river-dominated Corwin and Umiat deltas controlled the distribution of Nanushuk Group coal-forming environments. Most organic deposits formed on delta plains; fewer formed in alluvial plain or delta-front environments. Most NPRA coal beds are expected to be lenticular and irregular, as they probably accumulated in interdistributary basins, infilled bays, or inland flood basins, whereas some blanket beds may have formed on broad, slowly sinking, delta lobes. The major controls of coal rank and degree of deformation were depth of burial and subsequent tectonism. Nanushuk Group coal resources in NPRA are estimated to be as much as 2.75 trillion short tons. This value is the sum of 1.42 trillion short tons of near-surface (< 500 ft or 150 m of overburden) bituminous coal, 1.25 trillion short tons of near-surface subbituminous coal, and 0.08 trillion shorts tons of more deeply buried subbituminous coal. These estimates indicate that the North Slope may contain as much as one-third of the United States coal potential.

Sable, E.G.; Stricker, G.D.

1985-04-01T23:59:59.000Z

128

Alaska has 4. 0 trillion tons of low-sulfur coal: Is there a future for this resource  

SciTech Connect (OSTI)

The demand for and use of low-sulfur coal may increase because of concern with acid rain. Alaska's low-sulfur coal resources can only be described as enormous: 4.0 trillion tons of hypothetical onshore coal. Mean total sulfur content is 0.34% (range 0.06-6.6%, n = 262) with a mean apparent rank of subbituminous B. There are 50 coal fields in Alaska; the bulk of the resources are in six major fields or regions: Nenana, Cook Inlet, Matanuska, Chignik-Herendeen Bay, North Slope, and Bering River. For comparison, Carboniferous coals in the Appalachian region and Interior Province have a mean total sulfur content of 2.3% (range 0.1-19.0%, n = 5,497) with a mean apparent rank of high-volatile A bituminous coal, and Rocky Mountain and northern Great Plains Cretaceous and Tertiary coals have a mean total sulfur content of 0.86% (range 0.02-19.0%, n = 2,754) with a mean apparent rank of subbituminous B. Alaskan coal has two-fifths the total sulfur of western US coals and one-sixth that of Carboniferous US coals. Even though Alaska has large resources of low-sulfur coal, these resources have not been developed because of (1) remote locations and little infrastructure, (2) inhospitable climate, and (3) long distances to potential markets. These resources will not be used in the near future unless there are some major, and probably violent, changes in the world energy picture.

Stricker, G.D. (Geological Survey, Denver, CO (USA))

1990-05-01T23:59:59.000Z

129

Low-rank coal study : national needs for resource development. Volume 2. Resource characterization  

SciTech Connect (OSTI)

Comprehensive data are presented on the quantity, quality, and distribution of low-rank coal (subbituminous and lignite) deposits in the United States. The major lignite-bearing areas are the Fort Union Region and the Gulf Lignite Region, with the predominant strippable reserves being in the states of North Dakota, Montana, and Texas. The largest subbituminous coal deposits are in the Powder River Region of Montana and Wyoming, The San Juan Basin of New Mexico, and in Northern Alaska. For each of the low-rank coal-bearing regions, descriptions are provided of the geology; strippable reserves; active and planned mines; classification of identified resources by depth, seam thickness, sulfur content, and ash content; overburden characteristics; aquifers; and coal properties and characteristics. Low-rank coals are distinguished from bituminous coals by unique chemical and physical properties that affect their behavior in extraction, utilization, or conversion processes. The most characteristic properties of the organic fraction of low-rank coals are the high inherent moisture and oxygen contents, and the correspondingly low heating value. Mineral matter (ash) contents and compositions of all coals are highly variable; however, low-rank coals tend to have a higher proportion of the alkali components CaO, MgO, and Na/sub 2/O. About 90% of the reserve base of US low-rank coal has less than one percent sulfur. Water resources in the major low-rank coal-bearing regions tend to have highly seasonal availabilities. Some areas appear to have ample water resources to support major new coal projects; in other areas such as Texas, water supplies may be constraining factor on development.

Not Available

1980-11-01T23:59:59.000Z

130

Advanced Utility Mercury-Sorbent Field-Testing Program  

SciTech Connect (OSTI)

This report summarizes the work conducted from September 1, 2003 through December 31, 2007 on the project entitled Advanced Utility Mercury-Sorbent Field-Testing Program. The project covers the testing at the Detroit Edison St. Clair Plant and the Duke Power Cliffside and Buck Stations. The St. Clair Plant used a blend of subbituminous and bituminous coal and controlled the particulate emissions by means of a cold-side ESP. The Duke Power Stations used bituminous coals and controlled their particulate emissions by means of hot-side ESPs. The testing at the Detroit Edison St. Clair Plant demonstrated that mercury sorbents could be used to achieve high mercury removal rates with low injection rates at facilities that burn subbituminous coal. A mercury removal rate of 94% was achieved at an injection rate of 3 lb/MMacf over the thirty day long-term test. Prior to this test, it was believed that the mercury in flue gas of this type would be the most difficult to capture. This is not the case. The testing at the two Duke Power Stations proved that carbon- based mercury sorbents can be used to control the mercury emissions from boilers with hot-side ESPs. It was known that plain PACs did not have any mercury capacity at elevated temperatures but that brominated B-PAC did. The mercury removal rate varies with the operation but it appears that mercury removal rates equal to or greater than 50% are achievable in facilities equipped with hot-side ESPs. As part of the program, both sorbent injection equipment and sorbent production equipment was acquired and operated. This equipment performed very well during this program. In addition, mercury instruments were acquired for this program. These instruments worked well in the flue gas at the St. Clair Plant but not as well in the flue gas at the Duke Power Stations. It is believed that the difference in the amount of oxidized mercury, more at Duke Power, was the difference in instrument performance. Much of the equipment was purchased used and all of the equipment has nearly reached the end of its useful service.

Ronald Landreth

2007-12-31T23:59:59.000Z

131

Coal Direct Chemical Looping Retrofit to Pulverized Coal Power Plants for In-Situ CO2 Capture  

SciTech Connect (OSTI)

A novel Coal Direct Chemical Looping (CDCL) system is proposed to effectively capture CO2 from existing PC power plants. The work during the past three years has led to an oxygen carrier particle with satisfactory performance. Moreover, successful laboratory, bench scale, and integrated demonstrations have been performed. The proposed project further advanced the novel CDCL technology to sub-pilot scale (25 kWth). To be more specific, the following objectives attained in the proposed project are: 1. to further improve the oxygen carrying capacity as well as the sulfur/ash tolerance of the current (working) particle; 2. to demonstrate continuous CDCL operations in an integrated mode with > 99% coal (bituminous, subbituminous, and lignite) conversion as well as the production of high temperature exhaust gas stream that is suitable for steam generation in existing PC boilers; 3. to identify, via demonstrations, the fate of sulfur and NOx; 4. to conduct thorough techno-economic analysis that validates the technical and economical attractiveness of the CDCL system. The objectives outlined above were achieved through collaborative efforts among all the participants. CONSOL Energy Inc. performed the techno-economic analysis of the CDCL process. Shell/CRI was able to perform feasibility and economic studies on the large scale particle synthesis and provide composite particles for the sub-pilot scale testing. The experience of B&W (with boilers) and Air Products (with handling gases) assisted the retrofit system design as well as the demonstration unit operations. The experience gained from the sub-pilot scale demonstration of the Syngas Chemical Looping (SCL) process at OSU was able to ensure the successful handling of the solids. Phase 1 focused on studies to improve the current particle to better suit the CDCL operations. The optimum operating conditions for the reducer reactor such as the temperature, char gasification enhancer type, and flow rate were identified. The modifications of the existing bench scale reactor were completed in order to use it in the next phase of the project. In Phase II, the optimum looping medium was selected, and bench scale demonstrations were completed using them. Different types of coal char such as those obtained from bituminous, subbituminous, and lignite were tested. Modifications were made on the existing sub-pilot scale unit for coal injection. Phase III focused on integrated CDCL demonstration in the sub-pilot scale unit. A comprehensive ASPEN® simulations and economic analysis was completed by CONSOL t is expected that the CDCL process will be ready for further demonstrations in a scale up unit upon completion of the proposed project.

Zeng, Liang; Li, Fanxing; Kim, Ray; Bayham, Samuel; McGiveron, Omar; Tong, Andrew; Connell, Daniel; Luo, Siwei; Sridhar, Deepak; Wang, Fei; Sun, Zhenchao; Fan, Liang-Shih

2013-09-30T23:59:59.000Z

132

Pulverized coal combustion characterization at the KEPRI  

SciTech Connect (OSTI)

A pilot-scale combustion test facility that can be utilized to burn pulverized coals such as anthracite coals, bituminous coals, and their blends at the rate of 200 kg/hr has been constructed to study coal-related impacts on utility boiler operations. The impacts include pulverizer performance, combustion stability, slagging, fouling, heat transfer, erosion, corrosion, pollutant emission, etc. The facility, a scale-down model of an existing boiler in Korea, consists of all the necessary components for the boiler with a distributed control system except steam generation components which have been replaced with slag panels, fouling probes, and heat exchangers. The facility, in addition, incorporates the advanced boiler technologies including tangentially-fired burners, flue gas recirculation, direct sorbent injection for desulfurization, electrostatic precipitator, wet scrubber, etc., and employs an opacity meter and gas analyzers. Low NOx burners and gas reburning system will be facilitated in the future to study low emission boiler systems being demonstrated in the developed countries. This paper represents preliminary test results including flame shapes, fouling based on the fouling factor, and pollutant emission with different coals and combustion aerodynamics. Flow fields in the furnace have been changed by varying the swirl number and the burner configurations in terms of single-wall, opposed-wall, and corner firing mode. An extensive investigation will continue to find optimum conditions for various coals of interest.

Cha, D.J.; Kim, S.C.; Bae, B.H.; Kim, T.H.; Shin, Y.J.; Lee, H.D.; Park, O.Y.; Choi, B.S.

1997-12-31T23:59:59.000Z

133

Sulfur and ash reduction potential and selected chemical and physical properties of United States coals. [Contains glossary  

SciTech Connect (OSTI)

This report presents the washability and comprehensive characterization results of 184 raw coal channel samples, including anthracite, bituminous and lignite coals, collected from the Central Region of the United States. This is the second of a three volume report on the coals of the United States. All the data are presented in six appendices. Statistical techniques and definitions are presented in Appendix A, and a glossary of terms is presented in Appendix B. The complete washability data and an in-depth characterization of each sample are presented alphabetically by state in Appendix C. In Appendix D, a statistical evaluation is given for the composited washability data, selected chemical and physical properties and washability data interpolated at various levels of Btu recovery. This presentation is shown by state, section, and region where four or more samples were collected. Appendix E presents coalbed codes and names for the Central Region coals. Graphical summations are presented by state, section and region showing the effects of crushing on impurity reductions, and the distribution of raw and clean coal samples meeting various levels of SO{sub 2} emissions. 35 figs., 5 tabs.

Cavallaro, J.A.; Deurbrouck, A.W.; Killmeyer, R.P.; Fuchs, W. (USDOE Pittsburgh Energy Technology Center, PA (USA). Coal Preparation Div.); Jacobsen, P.S. (Burns and Roe Services Corp., Pittsburgh, PA (USA))

1991-02-01T23:59:59.000Z

134

EERC pilot-scale CFBC evaluation facility Project CFB test results  

SciTech Connect (OSTI)

Project CFB was initiated at the University of North Dakota Energy and Environmental Research Center (EERC) in May 1988. Specific goals of the project were to (1) construct a circulating fluidized-bed combustor (CFBC) facility representative of the major boiler vendors' designs with the capability of producing scalable data, (2) develop a database for use in making future evaluations of CFBC technology, and (3) provide a facility for evaluating fuels, free of vendor bias for use in the - energy industry. Five coals were test-burned in the 1-MWth unit: North Dakota and Asian lignites, a Wyoming subbituminous, and Colorado and Pennsylvania bituminous coats. A total of 54 steady-state test periods were conducted, with the key test parameters being the average combustor temperature, excess air, superficial gas velocity, calcium-to-sulfur molar ratio, and the primary air-to-secondary air split. The capture for a coal fired in a CFBC is primarily dependent upon the total alkali-to-sulfur ratio. The required alkali-to ratio for 90% sulfur retention ranged from 1.4 to 4.9, depending upon coal type. While an alkali-to-ratio of 4.9 was required to meet 90% sulfur retention for the Salt Creek coal versus 1.4 for the Asian lignite, the total amount of sorbent addition required is much less for the Salt Creek coal, 4.2 pound sorbent per million Btu coal input, versus 62 pound/million Btu for the Asian lignite. The bituminous coals tested show optimal capture at combustor temperatures of approximately 1550[degree]F, with low-rank coals having optimal sulfur capture approximately 100[degree]F lower.

Mann, M.D.; Hajicek, D.R.; Henderson, A.K.; Moe, T.A.

1992-09-01T23:59:59.000Z

135

EERC pilot-scale CFBC evaluation facility Project CFB test results. Topical report, Task 7.30  

SciTech Connect (OSTI)

Project CFB was initiated at the University of North Dakota Energy and Environmental Research Center (EERC) in May 1988. Specific goals of the project were to (1) construct a circulating fluidized-bed combustor (CFBC) facility representative of the major boiler vendors` designs with the capability of producing scalable data, (2) develop a database for use in making future evaluations of CFBC technology, and (3) provide a facility for evaluating fuels, free of vendor bias for use in the - energy industry. Five coals were test-burned in the 1-MWth unit: North Dakota and Asian lignites, a Wyoming subbituminous, and Colorado and Pennsylvania bituminous coats. A total of 54 steady-state test periods were conducted, with the key test parameters being the average combustor temperature, excess air, superficial gas velocity, calcium-to-sulfur molar ratio, and the primary air-to-secondary air split. The capture for a coal fired in a CFBC is primarily dependent upon the total alkali-to-sulfur ratio. The required alkali-to ratio for 90% sulfur retention ranged from 1.4 to 4.9, depending upon coal type. While an alkali-to-ratio of 4.9 was required to meet 90% sulfur retention for the Salt Creek coal versus 1.4 for the Asian lignite, the total amount of sorbent addition required is much less for the Salt Creek coal, 4.2 pound sorbent per million Btu coal input, versus 62 pound/million Btu for the Asian lignite. The bituminous coals tested show optimal capture at combustor temperatures of approximately 1550{degree}F, with low-rank coals having optimal sulfur capture approximately 100{degree}F lower.

Mann, M.D.; Hajicek, D.R.; Henderson, A.K.; Moe, T.A.

1992-09-01T23:59:59.000Z

136

Coal plasticity at high heating rates and temperatures. Final technical progress report  

SciTech Connect (OSTI)

Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

Gerjarusak, S.; Peters, W.A.; Howard, J.B.

1995-05-01T23:59:59.000Z

137

Coalbed methane potential of the Pechora Coalfield, Timan-Pechora Basin, Russia  

SciTech Connect (OSTI)

A comparison of the more important geologic attributes of coal beds in the coalbed methane producing regions of the United States to Permian coal beds in the Pechora Coalfield, Timan-Pechora Basin, Russia indicates a high potential for commercial coalbed methane production. Although the depositional and structural histories, as well as the age, of the coal beds in the Pechora Coalfield are different than coal beds in U.S. basins, coal quality attributes are similar. The more prospective part of the coal-bearing sequence is as thick as 1600 m and contains more than 150 coal beds that individually are as thick as 4 m. These coal beds are composed primarily of rank ranges from subbituminous to anthracite (,0.5->2.5% R[sub 0]), with the highest rank coal located near the city of Vorkuta. Published data indicates that the gas content of coals is as high as 28-35 m[sup 3]/ton, with an average value of 18 m[sup 3]/ton. About 700 MMCM of gas per year is emmitted from coal mines. Pore pressures in the coal beds are unknown, however, interbedded sandstones in some parts of the basin are overpressured. The commonly occurring problem, in mid-latitude coalbed methane well, of excessive amounts of water may be alleviated in this high-latitude coal field. We suggest that the wide-spread occurrence of permafrost in the Pechora Coalfield may form an effective barrier to down-dip water flow, thereby facilitating the dewatering state. In summary, the quality of coal beds in the Pechora Coalfield are similar to methane producing coal beds in the United States and should, therefore, be favorable for commercial rates of gas production.

Yakutseni, V.P.; Petrova, Y.E. (VNIGRI, St. Petersburg (Russian Federation)); Law, B.E.; Ulmishek, G.F. (Geological Survey, Denver, CO (United States))

1996-01-01T23:59:59.000Z

138

Coalbed methane potential of the Pechora Coalfield, Timan-Pechora Basin, Russia  

SciTech Connect (OSTI)

A comparison of the more important geologic attributes of coal beds in the coalbed methane producing regions of the United States to Permian coal beds in the Pechora Coalfield, Timan-Pechora Basin, Russia indicates a high potential for commercial coalbed methane production. Although the depositional and structural histories, as well as the age, of the coal beds in the Pechora Coalfield are different than coal beds in U.S. basins, coal quality attributes are similar. The more prospective part of the coal-bearing sequence is as thick as 1600 m and contains more than 150 coal beds that individually are as thick as 4 m. These coal beds are composed primarily of rank ranges from subbituminous to anthracite (,0.5->2.5% R{sub 0}), with the highest rank coal located near the city of Vorkuta. Published data indicates that the gas content of coals is as high as 28-35 m{sup 3}/ton, with an average value of 18 m{sup 3}/ton. About 700 MMCM of gas per year is emmitted from coal mines. Pore pressures in the coal beds are unknown, however, interbedded sandstones in some parts of the basin are overpressured. The commonly occurring problem, in mid-latitude coalbed methane well, of excessive amounts of water may be alleviated in this high-latitude coal field. We suggest that the wide-spread occurrence of permafrost in the Pechora Coalfield may form an effective barrier to down-dip water flow, thereby facilitating the dewatering state. In summary, the quality of coal beds in the Pechora Coalfield are similar to methane producing coal beds in the United States and should, therefore, be favorable for commercial rates of gas production.

Yakutseni, V.P.; Petrova, Y.E. [VNIGRI, St. Petersburg (Russian Federation); Law, B.E.; Ulmishek, G.F. [Geological Survey, Denver, CO (United States)

1996-12-31T23:59:59.000Z

139

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report  

SciTech Connect (OSTI)

Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

1997-11-01T23:59:59.000Z

140

Production of Substitute Natural Gas from Coal  

SciTech Connect (OSTI)

The goal of this research program was to develop and demonstrate a novel gasification technology to produce substitute natural gas (SNG) from coal. The technology relies on a continuous sequential processing method that differs substantially from the historic methanation or hydro-gasification processing technologies. The thermo-chemistry relies on all the same reactions, but the processing sequences are different. The proposed concept is appropriate for western sub-bituminous coals, which tend to be composed of about half fixed carbon and about half volatile matter (dry ash-free basis). In the most general terms the process requires four steps (1) separating the fixed carbon from the volatile matter (pyrolysis); (2) converting the volatile fraction into syngas (reforming); (3) reacting the syngas with heated carbon to make methane-rich fuel gas (methanation and hydro-gasification); and (4) generating process heat by combusting residual char (combustion). A key feature of this technology is that no oxygen plant is needed for char combustion.

Andrew Lucero

2009-01-31T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Low-Cost Options for Moderate Levels of Mercury Control  

SciTech Connect (OSTI)

On March 15, 2005, EPA issued the Clean Air Mercury Rule, requiring phased-in reductions of mercury emissions from electric power generators. ADA-ES, Inc., with support from DOE/NETL and industry partners, is conducting evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. DOE/NETL targets for total mercury removal are {ge}55% (lignite), {ge}65% (subbituminous), and {ge}80% (bituminous). Based on work done to date at various scales, meeting the removal targets appears feasible. However, work needs to progress to more thoroughly document and test these promising technologies at full scale. This is the final site report for tests conducted at MidAmerican's Louisa Station, one of three sites evaluated in this DOE/NETL program. The other two sites in the program are MidAmerican's Council Bluff Station and Entergy's Independence Station. MidAmerican's Louisa Station burns Powder River Basin (PRB) coal and employs hot-side electrostatic precipitators with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal.

Sharon Sjostrom

2006-03-31T23:59:59.000Z

142

Market Assessment and Technical Feasibility Study of Pressurized Fluidized Bed Combustion Ash Use  

SciTech Connect (OSTI)

Western Research Institute in conjunction with the Electric Power Research Institute, Foster Wheeler Energy International, Inc. and the U.S. Department of Energy Technology Center (METC), has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for pressurized fluidized bed combustion (PFBC) ashes. The assessment is designed to address six applications, including: (1) structural fill, (2) road base construction, (3) supplementary cementing materials in portland cement, (4) synthetic aggregate, and (5) agricultural/soil amendment applications. Ash from low-sulfur subbituminous coal-fired Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, and ash from the high-sulfur bituminous coal-fired American Electric Power (AEP) bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing. This paper addresses the technical feasibility of ash use options for PFBC unit using low- sulfur coal and limestone sorbent (karhula ash) and high-sulfur coal and dolomite sorbents (AEP Tidd ash).

Bland, A.E.; Brown, T.H. [Western Research Inst., Laramie, WY (United States)

1996-12-31T23:59:59.000Z

143

PULSE COMBUSTOR DESIGN QUALIFICATION TEST AND CLEAN COAL FEEDSTOCK TEST - VOLUME I AND VOLUME II  

SciTech Connect (OSTI)

For this Cooperative Agreement, the pulse heater module is the technology envelope for an indirectly heated steam reformer. The field of use of the steam reformer pursuant to this Cooperative Agreement with DOE is for the processing of sub-bituminous coals and lignite. The main focus is the mild gasification of such coals for the generation of both fuel gas and char--for the steel industry is the main focus. An alternate market application for the substitution of metallurgical coke is also presented. This project was devoted to qualification of a 253-tube pulse heater module. This module was designed, fabricated, installed, instrumented and tested in a fluidized bed test facility. Several test campaigns were conducted. This larger heater is a 3.5 times scale-up of the previous pulse heaters that had 72 tubes each. The smaller heater has been part of previous pilot field testing of the steam reformer at New Bern, North Carolina. The project also included collection and reduction of mild gasification process data from operation of the process development unit (PDU). The operation of the PDU was aimed at conditions required to produce char (and gas) for the Northshore Steel Operations. Northshore Steel supplied the coal for the process unit tests.

Unknown

2002-02-08T23:59:59.000Z

144

Power Systems Development Facility. Environmental Assessment  

SciTech Connect (OSTI)

The objective of the PSDF would be to provide a modular facility which would support the development of advanced, pilot-scale, coal-based power systems and hot gas clean-up components. These pilot-scale components would be designed to be large enough so that the results can be related and projected to commercial systems. The facility would use a modular approach to enhance the flexibility and capability for testing; consequently, overall capital and operating costs when compared with stand-alone facilities would be reduced by sharing resources common to different modules. The facility would identify and resolve technical barrier, as well as-provide a structure for long-term testing and performance assessment. It is also intended that the facility would evaluate the operational and performance characteristics of the advanced power systems with both bituminous and subbituminous coals. Five technology-based experimental modules are proposed for the PSDF: (1) an advanced gasifier module, (2) a fuel cell test module, (3) a PFBC module, (4) a combustion gas turbine module, and (5) a module comprised of five hot gas cleanup particulate control devices. The final module, the PCD, would capture coal-derived ash and particles from both the PFBC and advanced gasifier gas streams to provide for overall particulate emission control, as well as to protect the combustion turbine and the fuel cell.

Not Available

1993-06-01T23:59:59.000Z

145

Pulverization Induced Charge: In-Line Dry Coal Cleaning  

SciTech Connect (OSTI)

The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to boilers in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

Schaefer, J.L.; Stencel, J.M.

1997-05-13T23:59:59.000Z

146

PULVERIZATION INDUCED CHARGE: IN-LINE DRY COAL CLEANING  

SciTech Connect (OSTI)

The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to burners in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

JOHN M. STENCEL

1998-07-01T23:59:59.000Z

147

Pulverization Induced Charge: In-Line Dry Coal Cleaning  

SciTech Connect (OSTI)

The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to burners in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

John M. Stencel

1998-05-26T23:59:59.000Z

148

Pulverization Induced Charge: In-Line Dry Coal Cleaning  

SciTech Connect (OSTI)

The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to burners in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

John M. Stencel

1998-01-21T23:59:59.000Z

149

Canadian Mineralogist Vol. Z, pp.219-228 (1986) PETROGRAPHIC HARACTERIZATION OF THE SOLID PRODUCTS OF COAL-PITCH COPROCESSING*  

E-Print Network [OSTI]

Petrographic studies were conducted on four solid residues resulting from the hydrogenation process of l) Forestburg sub-bituminous coal alone, 2) the coal with a non-coking solvent (anthracene oil), 3) pitch (Cold Lake vacuum-bottom deposits), and 4) a mixture of coal and pitch. The purpose was to determine the amounts of coal-and pitch-derived solids in the residues. All the residues were produced under identical severe conditions of liquefaction to promote tle formation of solids. The coal processed witl anttracene oil gives a residue consisting mainly of isotropic huminitic solids. If the coal is hydrogenated under similar conditions but without a solvent, the predominant residual solids are anisotropic semicokes displaying coarse mosaic textures, which form from vitroplast. The residual products from the hydrogenated Cold Lake vacuum-bottom deposits are also dominantly adsotropic semicokes; these display coarse mosaics and flow textures, and form by the $owth and coalescence of mesophase spherules. Both coal- and pitch-derived solids are identified in a residue produced by coprocessing the Forestburg coal with the pitch from tle Cold Lake vacuum-bottom deposits. It is concluded that the huminite macerals in the coal generate the fine-grained, mosaic-textured semicokes, whereas the pitch produces the coarse mosaics and flow-textured semicokes.

Judith Potter; Brian D. Kybett; Parviz Rahimi; John; T. Price

150

Development of an advanced, continuous mild gasification process for the production of co-products technical evaluation. Final report  

SciTech Connect (OSTI)

The University of North Dakota Energy and Environmental Research Center (EERC) and the AMAX Research and Development Center are cooperating in the development of a Mild Gasification process that will rapidly devolatilize coals of all ranks at relatively low temperatures between 930{degree} and 1470{degree}F (500{degree}and 800{degree}C) and near atmospheric pressure to produce primary products that include a reactive char, a hydrocarbon condensate, and a low-Btu gas. These will be upgraded in a ``coal refinery`` system having the flexibility to optimize products based on market demand. Task 2 of the four-task development sequence primarily covered bench-scale testing on a 10-gram thermogravimetric analyzer (TGA) and a 1 to 4-lb/hr continuous fluidized-bed reactor (CFBR). Tests were performed to determine product yields and qualities for the two major test coals-one a high-sulfur bituminous coal from the Illinois Basin (Indiana No. 3) and the other a low-sulfur subbituminous coal from the Powder River Basin (Wyodak). Results from Task 3, on product upgrading tests performed by AMAX Research and Development (R&D), are also reported. Task 4 included the construction, operation of a Process Research Unit (PRU), and the upgrading of the products. An economic evaluation of a commercial facility was made, based on the data produced in the PRU, CFBR, and the physical cleaning steps.

Ness, R.O. Jr.; Runge, B.; Sharp, L.

1992-11-01T23:59:59.000Z

151

Power Systems Development Facility Gasification Test Campaign TC17  

SciTech Connect (OSTI)

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results gasification operation with Illinois Basin bituminous coal in PSDF test campaign TC17. The test campaign was completed from October 25, 2004, to November 18, 2004. System startup and initial operation was accomplished with Powder River Basin (PRB) subbituminous coal, and then the system was transitioned to Illinois Basin coal operation. The major objective for this test was to evaluate the PSDF gasification process operational stability and performance using the Illinois Basin coal. The Transport Gasifier train was operated for 92 hours using PRB coal and for 221 hours using Illinois Basin coal.

Southern Company Services

2004-11-30T23:59:59.000Z

152

Development of an advanced, continuous mild gasification process for the production of co-products technical evaluation  

SciTech Connect (OSTI)

The University of North Dakota Energy and Environmental Research Center (EERC) and the AMAX Research and Development Center are cooperating in the development of a Mild Gasification process that will rapidly devolatilize coals of all ranks at relatively low temperatures between 930[degree] and 1470[degree]F (500[degree]and 800[degree]C) and near atmospheric pressure to produce primary products that include a reactive char, a hydrocarbon condensate, and a low-Btu gas. These will be upgraded in a coal refinery'' system having the flexibility to optimize products based on market demand. Task 2 of the four-task development sequence primarily covered bench-scale testing on a 10-gram thermogravimetric analyzer (TGA) and a 1 to 4-lb/hr continuous fluidized-bed reactor (CFBR). Tests were performed to determine product yields and qualities for the two major test coals-one a high-sulfur bituminous coal from the Illinois Basin (Indiana No. 3) and the other a low-sulfur subbituminous coal from the Powder River Basin (Wyodak). Results from Task 3, on product upgrading tests performed by AMAX Research and Development (R D), are also reported. Task 4 included the construction, operation of a Process Research Unit (PRU), and the upgrading of the products. An economic evaluation of a commercial facility was made, based on the data produced in the PRU, CFBR, and the physical cleaning steps.

Ness, R.O. Jr.; Runge, B.; Sharp, L.

1992-11-01T23:59:59.000Z

153

A compact XRF unit for determining total sulphur content in coals  

SciTech Connect (OSTI)

A microcomputer based x-ray fluorescence (XRF) unit was developed for off-line determination of total sulphur content in coal samples. The unit consisted of the x-ray exciting/measuring set and the microcomputer with a plug-in interface card, An Fe-55 radioisotope was used as the exciting source while a krypton-filled proportional counter was used to measure x-rays from the samples. The x-ray spectrum was simultaneously displayed on the microcomputer screen. For quantitative determination of sulphur, the intensities of sulphur K x-rays as well as calcium K x-rays and scattered x-rays were taken into account. The unit was tested with finely-ground, dried and compressed lignite, subbituminous and bituminous samples. It was found that for low-calcium coals the results were in good agreement with those obtained from the standard chemical analysis method within {+-}0.2 %S and within {+-}0.5 %S for high-calcium coals.

Sumitra, T.; Chankow, N.; Punnachaiya, S.; Srisatit, S. [Chulalongkorn Univ., Bangkok (Thailand)

1994-12-31T23:59:59.000Z

154

ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS  

SciTech Connect (OSTI)

ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

2002-12-30T23:59:59.000Z

155

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

with less carbon and energy density than coal, is highlyfossil energy plants, volume 1: Bituminous coal and naturalfossil energy power plants, Volume 1: Bituminous coal and

Lu, Xiaoming

2012-01-01T23:59:59.000Z

156

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network [OSTI]

U.S. and China is for other bituminous coal and clean coal.U.S. and China is for other bituminous coal and clean coal.

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

157

Study of mercury oxidation by a selective catalytic reduction catalyst in a pilot-scale slipstream reactor at a utility boiler burning bituminous coal  

SciTech Connect (OSTI)

One of the cost-effective mercury control technologies in coal-fired power plants is the enhanced oxidation of elemental mercury in selective catalytic reduction (SCR) followed by the capture of the oxidized mercury in the wet scrubber. This paper is the first in a series of two in which the validation of the SCR slipstream test and Hg speciation variation in runs with or without SCR catalysts inside the SCR slipstream reactor under special gas additions (HCl, Cl{sub 2}, SO{sub 2}, and SO{sub 3}) are presented. Tests indicate that the use of a catalyst in a SCR slipstream reactor can achieve greater than 90% NO reduction efficiency with a NH{sub 3}/NO ratio of about 1. There is no evidence to show that the reactor material affects mercury speciation. Both SCR catalysts used in this study exhibited a catalytic effect on the elemental mercury oxidation but had no apparent adsorption effect. SCR catalyst 2 seemed more sensitive to the operational temperature. The spike gas tests indicated that HCl can promote Hg{sup 0} oxidation but not Cl{sub 2}. The effect of Cl{sub 2} on mercury oxidation may be inhibited by higher concentrations of SO{sub 2}, NO, or H{sub 2}O in real flue-gas atmospheres within the typical SCR temperature range (300-350{sup o}C). SO{sub 2} seemed to inhibit mercury oxidation; however, SO{sub 3} may have some effect on the promotion of mercury oxidation in runs with or without SCR catalysts. 25 refs., 9 figs., 2 tabs.

Yan Cao; Bobby Chen; Jiang Wu; Hong Cui; John Smith; Chi-Kuan Chen; Paul Chu; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

2007-01-15T23:59:59.000Z

158

Postcombustion and its influences in 135 MWe CFB boilers  

SciTech Connect (OSTI)

In the cyclone of a circulating fluidized bed (CFB) boiler, a noticeable increment of flue gas temperature, caused by combustion of combustible gas and unburnt carbon content, is often found. Such phenomenon is defined as post combustion, and it could introduce overheating of reheated and superheated steam and extra heat loss of exhaust flue gas. In this paper, mathematical modeling and field measurements on post combustion in 135MWe commercial CFB boilers were conducted. A novel one-dimensional combustion model taking post combustion into account was developed. With this model, the overall combustion performance, including size distribution of various ashes, temperature profile, and carbon content profiles along the furnace height, heat release fraction in the cyclone and furnace were predicted. Field measurements were conducted by sampling gas and solid at different positions in the boiler under different loads. The measured data and corresponding model-calculated results were compared. Both prediction and field measurements showed post combustion introduced a temperature increment of flue gas in the cyclone of the 135MWe CFB boiler in the range of 20-50{sup o}C when a low-volatile bituminous coal was fired. Although it had little influence on ash size distribution, post combustion had a remarkable influence on the carbon content profile and temperature profile in the furnace. Moreover, it introduced about 4-7% heat release in the cyclone over the total heat release in the boiler. This fraction slightly increased with total air flow rate and boiler load. Model calculations were also conducted on other two 135MWe CFB boilers burning lignite and anthracite coal, respectively. The results confirmed that post combustion was sensitive to coal type and became more severe as the volatile content of the coal decreased. 15 refs., 11 figs., 4 tabs.

Shaohua Li; Hairui Yang; Hai Zhang; Qing Liu; Junfu Lu; Guangxi Yue [Tsinghua University, Beijing (China). Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering

2009-09-15T23:59:59.000Z

159

Small boiler uses waste coal  

SciTech Connect (OSTI)

Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

Virr, M.J. [Spinheat Ltd. (United States)

2009-07-15T23:59:59.000Z

160

Subsurface definition of the Allegheny Group coalbed methane prospect interval in Southwestern Pennsylvania and new gas content results  

SciTech Connect (OSTI)

A preliminary reconnaissance of coalbed methane gas content data from exploratory coal cores and pre-existing data implies that the greater the depth and rank, the greater the total and cumulative gas content. The coal seams studied, ranging in age from the Pennsylvanian-Permian Dunkard Group to the Middle Pennsylvanian Allegheny Group, are from the Main Bituminous Field and two of the anthracite fields. Consequently, the Pennsylvania Geological Survey and the West Virginia Geological and Economic Survey conducted a mapping investigation to evaluate the regional geology of the coal-bearing intervals and its influence on coalbed methane potential. Phase I of this study involved the entire Pennsylvanian coal-bearing interval; Phase II focused on a stratigraphic delineation and evaluation of Allegheny coalbeds and associated sandstones. A variety of cross sections and isopach maps show several prospective coalbeds and facies relationships with channel-fill sandstones. This suggests that some of these sandstones may be traps for coalbed methane. Often overlooked in reservoir characterization is the quality of a coal seam. Coal rank, grade, and type influence the reserves and production of coalbed methane; the higher the rank, the greater adsorptive capacity of the coal. The integration of coal quality with other critical tools of exploration may increase the success rate of finding {open_quotes}sweet spots.{close_quotes} Additional Pennsylvania Geological Survey drilling occurred in Beaver, Lawrence, Somerset, and Washington counties. Gas contents were graphically displayed against depth, thickness, and time for a variety of samples from 21 coal seams; average gas composition and Btu values were determined for selected samples.

Markowski, A.K. [Pennsylvania Dept. of Conservation and Natural Resources-Bureau of Topographic and Geologic Survey, Harrisburg, PA (United States)

1996-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - ar kr xe Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1. The mechanism... report an experiment designed to study the trapping of Xe by sublimation - condensation process... of anthracite. This ex- periment allowed us to probe...

162

MARKET ASSESSMENT AND TECHNICAL FEASIBILITY STUDY OF PRESSURIZED FLUIDIZED BED COMBUSTION ASH USE  

SciTech Connect (OSTI)

Western Research Institute, in conjunction with the Electric Power Research Institute, Foster Wheeler International, Inc. and the US Department of Energy, has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for PFBC ashes. Ashes from the Foster Wheeler Energia Oy pilot-scale circulating PFBC tests in Karhula, Finland, combusting (1) low-sulfur subbituminous and (2) high-sulfur bituminous coal, and ash from the AEP's high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at WR1. The technical feasibility study examined the use of PFBC ash in construction-related applications, including its use as a cementing material in concrete and use in cement manufacturing, fill and embankment materials, soil stabilization agent, and use in synthetic aggregate production. Testing was also conducted to determine the technical feasibility of PFBC ash as a soil amendment for acidic and sodic problem soils and spoils encountered in agricultural and reclamation applications. The results of the technical feasibility testing indicated the following conclusions. PFBC ash does not meet the chemical requirements as a pozzolan for cement replacement. However, it does appear that potential may exist for its use in cement production as a pozzolan and/or as a set retardant. PFBC ash shows relatively high strength development, low expansion, and low permeability properties that make its use in fills and embankments promising. Testing has also indicated that PFBC ash, when mixed with low amounts of lime, develops high strengths, suitable for soil stabilization applications and synthetic aggregate production. Synthetic aggregate produced from PFBC ash is capable of meeting ASTM/AASHTO specifications for many construction applications. The residual calcium carbonate and calcium sulfate in the PFE3C ash has been shown to be of value in making PFBC ash a suitable soil amendment for acidic and sodic problem soils and mine spoils. In conclusion, PFBC ash represents a viable material for use in currently established applications for conventional coal combustion ashes. As such, PFBC ash should be viewed as a valuable resource, and commercial opportunities for these materials should be explored for planned PFBC installations.

A.E. Bland; T.H. Brown

1997-04-01T23:59:59.000Z

163

HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

Stefano Orsino

2005-03-30T23:59:59.000Z

164

SAMPLING, ANALYSIS, AND PROPERTIES OF PRIMARY PM-2.5: APPLICATION TO COAL-FIRED UTILITY BOILERS  

SciTech Connect (OSTI)

A dilution sampler was used to examine the effects of dilution ratio and residence time on the particulate emissions from a pilot-scale pulverized coal combustor. Measurements include the particle size distribution from 0.003 to 2.5 {micro}m, PM{sub 2.5} mass emission rate and PM2.5 composition (OC/EC, major ions, and elemental). Hot filter samples were also collected simultaneously in order to compare the dilution sampler measurement with standard stack sampling methodologies such as EPA Method 5. Measurements were made both before and after the bag-house, the particle control device used on the coal combustor. Measurements were made with three different coal types and a coal-biomass blend. The residence time and dilution ratio do not influence the PM{sub 2.5} mass emission rate, but have a significant effect on the size distribution and total number emissions. Measurements made before the bag-house showed increasing the residence time dramatically decreases the total particle number concentration, and shifts the particle mass to larger sizes. The effects of residence time can be explained quantitatively by the coagulation of the emitted particles. Measurements made after the bag-house were not affected by coagulation due to the lower concentration of particles. Nucleation of sulfuric acid vapor within the dilution was an important source of ultrafine particles. This nucleation is strongly a function of dilution ratio because of the competition between condensation and nucleation. At low dilution ratios condensation dominates and little nucleation is observed; increasing the dilution ratio promotes nucleation because of the corresponding decrease in available surface area per unit volume for condensation. No nucleation was observed after the bag house where conditions greatly favor nucleation over condensation; we suspect that the bag house removed the SO{sub 3} in the flue gas. Exhaust SO{sub 3} levels were not measured during these experiments. Dilution caused the enrichment of selenium, ammonium and sulfate in the PM{sub 2.5} emissions compared to the hot filter samples. The enrichment of selenium was independent of dilution ratio or residence time. The enrichment of ammonium and sulfate increased with increasing dilution ratio. PM{sub 2.5} emission profiles for four different fuels (two eastern bituminous coals, a western sub-bituminous coal, and coal-wood blend) were developed. These profiles compared well with profiles from similar coal sources, while showing unique characteristics due to differences in fuel composition.

Allen L. Robinson; Spyros N. Pandis; Eric Lipsky; Charles Stainer; Natalie Anderson; Satoshi Takahama; Sarah Rees

2003-02-01T23:59:59.000Z

165

ULTRA HIGH EFFICIENCY ESP DEVELOPMENT FOR AIR TOXICS CONTROL  

SciTech Connect (OSTI)

Because more than 90 percent of U.S. coal-fired utility boilers are equipped with electrostatic precipitators (ESPs), retrofitable ESP technologies represent a logical approach towards achieving the Department of Energy's (DOE) goal of a major reduction in fine particulate and mercury emissions (air toxics) from coal based power systems. EPA's recent issuance of significantly tightened ambient air standards for particles smaller than 2.5 {micro}m (PM{sub 2.5}) creates a new urgency for developing cost-effective means to control fine particulate emissions. This challenge is compounded by the on-going switch in the utility industry to low-sulfur Powder River Basin (PRB) coals, that generate higher resistivity and difficult-to-collect fly ash. Particulate emissions can increase by a factor of ten when a utility switches to a low-sulfur coal. Numerous power plants are presently limited in operation by the inability of their ESPs to control opacity at high loads. In Phase I of this program, ABB investigated five technologies to improve the collection of fine particulate and trace metals in ESPs. These included: (1) flue-gas cooling, (2) flue-gas humidification, (3) pulsed energization, (4) wet ESP and precharger modules, and (5) sorbent injection for mercury control. Tests were conducted with an Eastern bituminous coal and a Powder River Basin sub-bituminous low-sulfur coal in an integrated pilot-scale combustor and ESP test facility. The impacts of the different retrofit technologies on ESP performance, individually and in combination, were evaluated indepth through advanced sampling and measurement techniques. In Phase II, the most promising concepts identified from Phase I testing, flue-gas cooling and humidification, pulsed energization, and sorbent injection at low flue-gas temperatures for mercury control, were integrated into a commercially oriented sub-scale system for field testing at Commonwealth Edison's Waukegan Unit No. 8. The main objective of the proposed Phase II testing was to determine longer term ESP performance and mercury capture improvements with the above enhancements for a range of low-sulfur coals currently fired by utilities. Unanticipated cost growth in readying the Pilot Plant for shipment and during slipstream construction at the utility host site resulted in the issuance of a preemptive stop work order from ABB until a detailed technical and budgetary review of the project could be completed. Four program recovery scenarios were developed and presented to the DOE. After careful review of these options, it was decided to terminate the program and although the Pilot Plant installation was essentially completed, no testing was performed. The Pilot Plant was subsequently decommissioned and the host site returned to its preprogram condition.

David K. Anderson

1999-11-01T23:59:59.000Z

166

Upgrading low rank coal using the Koppelman Series C process  

SciTech Connect (OSTI)

Development of the K-Fuel technology began after the energy shortage of the early 1970s in the United States led energy producers to develop the huge deposits of low-sulfur coal in the Powder River Basin (PRB) of Wyoming. PRB coal is a subbituminous C coal containing about 30 wt % moisture and having heating values of about 18.6 megajoules/kg (8150 Btu/lb). PRB coal contains from 0.3 to 0.5 wt % sulfur, which is nearly all combined with the organic matrix in the coal. It is in much demand for boiler fuel because of the low-sulfur content and the low price. However, the low-heating value limits the markets for PRB coal to boilers specially designed for the high- moisture coal. Thus, the advantages of the low-sulfur content are not available to many potential customers having boilers that were designed for bituminous coal. This year about 250 million tons of coal is shipped from the Powder River Basin of Wyoming. The high- moisture content and, consequently, the low-heating value of this coal causes the transportation and combustion of the coal to be inefficient. When the moisture is removed and the heating value increased the same bundle of energy can be shipped using one- third less train loads. Also, the dried product can be burned much more efficiently in boiler systems. This increase in efficiency reduces the carbon dioxide emissions caused by use of the low-heating value coal. Also, the processing used to remove water and restructure the coal removes sulfur, nitrogen, mercury, and chlorides from the coal. This precombustion cleaning is much less costly than stack scrubbing. PRB coal, and other low-rank coals, tend to be highly reactive when freshly mined. These reactive coals must be mixed regularly (every week or two) when fresh, but become somewhat more stable after they have aged for several weeks. PRB coal is relatively dusty and subject to self-ignition compared to bituminous coals. When dried using conventional technology, PRB coal is even more dusty and more susceptible to spontaneous combustion than the raw coal. Also, PRB coal, if dried at low temperature, typically readsorbs about two- thirds of the moisture removed by drying. This readsorption of moisture releases the heat of adsorption of the water which is a major cause of self- heating of low-rank coals at low temperature.

Merriam, N.W., Western Research Institute

1998-01-01T23:59:59.000Z

167

Next Generation Metallic Iron Nodule Technology in Electric Arc Steelmaking - Phase II  

SciTech Connect (OSTI)

The current trend in the steel industry is a gradual decline in conventional steelmaking from taconite pellets in blast furnaces, and an increasing number of alternative processes using metallic scrap iron, pig iron and metallized iron ore products. Currently, iron ores from Minnesota and Michigan are pelletized and shipped to the lower Great Lakes ports as blast furnace feed. The existing transportation system and infrastructure is geared to handling these bulk materials. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the needs of the emerging steel industry while utilizing the existing infrastructure and materials handling. A recent commercial installation employing Kobe Steel’s ITmk3 process, was installed in Northeastern Minnesota. The basic process uses a moving hearth furnace to directly reduce iron oxides to metallic iron from a mixture of iron ore, coals and additives. The resulting products can be shipped using the existing infrastructure for use in various steelmaking processes. The technology reportedly saves energy by 30% over the current integrated steelmaking process and reduces emissions by more than 40%. A similar large-scale pilot plant campaign is also currently in progress using JFE Steel’s Hi-QIP process in Japan. The objective of this proposal is to build upon and improve the technology demonstrated by Kobe Steel and JFE, by further reducing cost, improving quality and creating added incentive for commercial development. This project expands previous research conducted at the University of Minnesota Duluth’s Natural Resources Research Institute and that reported by Kobe and JFE Steel. Three major issues have been identified and are addressed in this project for producing high-quality nodular reduced iron (NRI) at low cost: (1) reduce the processing temperature, (2) control the furnace gas atmosphere over the NRI, and (3) effectively use sub-bituminous coal as a reductant. From over 4000 laboratory tube and box furnace tests, it was established that the correct combination of additives, fluxes, and reductant while controlling the concentration of CO and CO2 in the furnace atmosphere (a) lowers the operating temperature, (b) decreases the use of reductant coal (c) generates less micro nodules of iron, and (d) promotes desulphurization. The laboratory scale work was subsequently verified on 12.2 m (40 ft) long pilot scale furnace. High quality NRI could be produced on a routine basis using the pilot furnace facility with energy provided from oxy-gas or oxy-coal burner technologies. Specific strategies were developed to allow the use of sub-bituminous coals both as a hearth material and as part of the reaction mixture. Computational Fluid Dynamics (CFD) modeling was used to study the overall carbothermic reduction and smelting process. The movement of the furnace gas on a pilot hearth furnace and larger simulated furnaces and various means of controlling the gas atmosphere were evaluated. Various atmosphere control methods were identified and tested during the course of the investigation. Based on the results, the appropriate modifications to the furnace were made and tested at the pilot scale. A series of reduction and smelting tests were conducted to verify the utility of the processing conditions. During this phase, the overall energy use characteristics, raw materials, alternative fuels, and the overall economics predicted for full scale implementation were analyzed. The results indicate that it should be possible to lower reaction temperatures while simultaneously producing low sulfur, high carbon NRI if the right mix chemistry and atmosphere are employed. Recommendations for moving the technology to the next stage of commercialization are presented.

Donald R. Fosnacht; Iwao Iwasaki; Richard F. Kiesel; David J. Englund; David W. Hendrickson; Rodney L. Bleifuss

2010-12-22T23:59:59.000Z

168

Enhanced Combustion Low NOx Pulverized Coal Burner  

SciTech Connect (OSTI)

For more than two decades, ALSTOM Power Inc. (ALSTOM) has developed a range of low cost, in-furnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes ALSTOM's internally developed TFS 2000 firing system, and various enhancements to it developed in concert with the U.S. Department of Energy (DOE). As of 2004, more than 200 units representing approximately 75,000 MWe of domestic coal fired capacity have been retrofit with ALSTOM low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coals to 0.10 lb/MMBtu for subbituminous coals, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing (retrofit) boiler equipment. If enacted, proposed Clear Skies legislation will, by 2008, require an average, effective, domestic NOx emissions rate of 0.16 lb/MMBtu, which number will be reduced to 0.13 lb/MMBtu by 2018. Such levels represent a 60% and 67% reduction, respectively, from the effective 2000 level of 0.40 lb/MMBtu. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. In light of these needs, ALSTOM, in cooperation with the DOE, is developing an enhanced combustion, low NOx pulverized coal burner which, when integrated with ALSTOM's state-of-the-art, globally air staged low NOx firing systems, will provide a means to achieve less than 0.15 lb/MMBtu NOx at less than 3/4 the cost of an SCR with low to no impact on balance of plant issues when firing a high volatile bituminous coal. Such coals can be more economic to fire than subbituminous or Powder River Basin (PRB) coals, but are more problematic from a NOx control standpoint as existing firing system technologies do not provide a means to meet current or anticipated regulations absent the use of an SCR. The DOE/ALSTOM program performed large pilot scale combustion testing in ALSTOM's Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut. During this work, the near-field combustion environment was optimized to maximize NOx reduction while minimizing the impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down under globally reducing conditions. Initially, ALSTOM utilized computational fluid dynamic modeling to evaluate a series of burner and/or near field stoichiometry controls in order to screen promising design concepts in advance of the large pilot scale testing. The third and final test, to be executed, will utilize several variants of the best nozzle tip configuration and compare performance with 3 different coals. The fuels to be tested will cover a wide range of coals commonly fired at US utilities. The completion of this work will provide sufficient data to allow ALSTOM to design, construct, and demonstrate a commercial version of an enhanced combustion low NOx pulverized coal burner. A preliminary cost/performance analysis of the developed enhanced combustion low NOx burner applied to ALSTOM's state-of-the-art TFS 2000 firing system was performed to show that the burner enhancements is a cost effective means to reduce NOx.

Ray Chamberland; Aku Raino; David Towle

2006-09-30T23:59:59.000Z

169

TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS  

SciTech Connect (OSTI)

With a major worldwide effort now ongoing to reduce greenhouse gas emissions, cofiring of renewable biomass fuels at conventional coal-fired utilities is seen as one of the lower-cost options to achieve such reductions. The Energy & Environmental Research Center has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw, alfalfa stems, and hybrid poplar were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal and an Absaloka subbituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pc in a bench-scale downfired furnace. A literature investigation was undertaken on mineral uptake and storage by plants considered for biomass cofiring in order to understand the modes of occurrence of inorganic elements in plant matter. Sixteen essential elements, C, H, O, N, P, K, Ca, Mg, S, Zn, Cu, Fe, Mn, B, Mo, and Cl, are found throughout plants. The predominant inorganic elements are K and Ca, which are essential to the function of all plant cells and will, therefore, be evenly distributed throughout the nonreproductive, aerial portions of herbaceous biomass. Some inorganic constituents, e.g., N, P, Ca, and Cl, are organically associated and incorporated into the structure of the plant. Cell vacuoles are the repository for excess ions in the plant. Minerals deposited in these ubiquitous organelles are expected to be most easily leached from dry material. Other elements may not have specific functions within the plant, but are nevertheless absorbed and fill a need, such as silica. Other elements, such as Na, are nonessential, but are deposited throughout the plant. Their concentration will depend entirely on extrinsic factors regulating their availability in the soil solution, i.e., moisture and soil content. Similarly, Cl content is determined less by the needs of the plant than by the availability in the soil solution; in addition to occurring naturally, Cl is present in excess as the anion complement in K fertilizer applications. An analysis was performed on existing data for switchgrass samples from ten different farms in the south-central portion of Iowa, with the goal of determining correlations between switchgrass elemental composition and geographical and seasonal changes so as to identify factors that influence the elemental composition of biomass. The most important factors in determining levels of various chemical compounds were found to be seasonal and geographical differences related to soil conditions. Combustion testing was performed to obtain deposits typical of boiler fouling and slagging conditions as well as fly ash. Analysis methods using computer-controlled scanning electron microscopy and chemical fractionation were applied to determine the composition and association of inorganic materials in the biomass samples. Modified sample preparation techniques and mineral quantification procedures using cluster analysis were developed to characterize the inorganic material in these samples. Each of the biomass types exhibited different inorganic associations in the fuel as well as in the deposits and fly ash. Morphological analyses of the wheat straw show elongated 10-30-{micro}m amorphous silica particles or phytoliths in the wheat straw structure. Alkali such as potassium, calcium, and sodium is organically bound and dispersed in the organic structure of the biomass materials. Combustion test results showed that the blends fed quite evenly, with good burnout. Significant slag deposit formation was observed for the 100% wheat straw, compared to bituminous and subbituminous coals burned under similar conditions. Although growing rapidly, the fouling deposits of the biomass and coal-biomass blends were significantly weaker than those of the coals. Fouling was only slightly worse for the 100% wheat straw fuel compared to the coals. The wheat straw ash was found to show the greatest similar

Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

2001-08-01T23:59:59.000Z

170

Co-pyrolysis of low rank coals and biomass: Product distributions  

SciTech Connect (OSTI)

Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

Soncini, Ryan M.; Means, Nicholas C.; Weiland, Nathan T.

2013-10-01T23:59:59.000Z

171

STUDIES OF THE SPONTANEOUS COMBUSTION OF LOW RANK COALS AND LIGNITES  

SciTech Connect (OSTI)

Spontaneous combustion has always been a problem in coal utilization especially in the storage and transportation of coal. In the United States, approximately 11% of underground coal mine fires are attributed to spontaneous coal combustion. The incidence of such fires is expected to increase with increased consumption of lower rank coals. The cause is usually suspected to be the reabsorption of moisture and oxidation. To understand the mechanisms of spontaneous combustion this study was conducted to (1) define the initial and final products during the low temperature (10 to 60 C) oxidation of coal at different partial pressures of O{sub 2}, (2) determine the rate of oxidation, and (3) measure the reaction enthalpy. The reaction rate (R) and propensity towards spontaneous combustion were evaluated in terms of the initial rate method for the mass gained due to adsorbed O{sub 2}. Equipment that was used consisted of a FT-IR (Fourier Transform-Infrared Spectrometer, Perkin Elmer), an accelerated surface area porosimeter (ASAP, Micromeritics model 2010), thermogravimetric analyzer (TGA, Cahn Microbalance TG 121) and a differential scanning calorimeter (DSC, Q1000, thermal analysis instruments). Their combination yielded data that established a relation between adsorption of oxygen and reaction enthalpy. The head space/ gas chromatograph/ mass spectrometer system (HS/GC/MS) was used to identify volatiles evolved during oxidation. The coal samples used were Beulah lignite and Wyodak (sub-bituminous). Oxygen (O{sub 2}) absorption rates ranged from 0.202 mg O{sub 2}/mg coal hr for coal sample No.20 (Beulah pyrolyzed at 300 C) to 6.05 mg O{sub 2}/mg coal hr for coal sample No.8 (wyodak aged and pyrolyzed at 300 C). Aging of coal followed by pyrolysis was observed to contribute to higher reaction rates. Reaction enthalpies ranged from 0.42 to 1580 kcal/gm/mol O{sub 2}.

Joseph M. Okoh; Joseph N.D. Dodoo

2005-07-26T23:59:59.000Z

172

Measurement and Modeling of Sorption-Induced Strain and Permeability Changes in Coal  

SciTech Connect (OSTI)

Strain caused by the adsorption of gases was measured in samples of subbituminous coal from the Powder River basin of Wyoming, U.S.A., and high-volatile bituminous coal from the Uinta-Piceance basin of Utah, U.S.A. using a newly developed strain measurement apparatus. The apparatus can be used to measure strain on multiple small coal samples based on the optical detection of the longitudinal strain. The swelling and shrinkage (strain) in the coal samples resulting from the adsorption of carbon dioxide, nitrogen, methane, helium, and a mixture of gases was measured. Sorption-induced strain processes were shown to be reversible and easily modeled with a Langmuir-type equation. Extended Langmuir theory was applied to satisfactorily model strain caused by the adsorption of gas mixtures using the pure gas Langmuir strain constants. The amount of time required to obtain accurate strain data was greatly reduced compared to other strain measurement methods. Sorption-induced changes in permeability were also measured as a function of pres-sure. Cleat compressibility was found to be variable, not constant. Calculated variable cleat-compressibility constants were found to correlate well with previously published data for other coals. During permeability tests, sorption-induced matrix shrinkage was clearly demonstrated by higher permeability values at lower pore pressures while holding overburden pressure constant. Measured permeability data were modeled using three dif-ferent permeability models from the open literature that take into account sorption-induced matrix strain. All three models poorly matched the measured permeability data because they overestimated the impact of measured sorption-induced strain on permeabil-ity. However, by applying an experimentally derived expression to the measured strain data that accounts for the confining overburden pressure, pore pressure, coal type, and gas type, the permeability models were significantly improved.

Eric P. Robertson

2005-10-01T23:59:59.000Z

173

A novel concept for high conversion of coal to liquids. Final report, 1 September 1988--31 August 1992  

SciTech Connect (OSTI)

A batch microreactor was designed and fabricated as a means of investigating maximum yields of liquids obtainable in very short reaction times of the order of a few seconds, and the maximum ratios of liquids/hydrocarbon (HC) gases obtainable under those conditions. A Wyodak sub-bituminous coal, crushed and sieved to {minus}200 mesh particle size, was used in the experiments, with a temperature of 500{degrees}C and a pressure of 1500 psi. The fine coal particles were fed dry to the reactor and heated to reaction temperature in times of one to two seconds. At a time of 3 seconds at reaction temperature, in a single pass a liquid yield of 60% by weight of the coal was obtained, accompanied by a ratio of liquids/(HC) gases of 30/1. When the unreacted solids were recycled to the reactor, and the results combined with those of the first pass, a liquid yield of 82% by weight of the coal was achieved, accompanied by a ratio of liquids/HC gases of 30/1. This ratio represents only about 3 wt percent HC gases, much lower that is produced in current advanced technologies, and represents a large saving in hydrogen consumption. A simulated distillation technique was applied to the liquids. The liquid product contained 86% by weight (of the liquids) total distillables (boiling point below 538{degrees}C), including 70% by weight of low-boiling fractions in the gasoline, kerosene and gas oil range (boiling point up to 325{degrees}C). The liquid product exhibited a H/C ratio of 1.5, which is considerably higher than observed in current advanced technologies for the primary liquids. Several catalysts were investigated. Iron catalysts, specifically ferric chloride hexahydrate and ferric sulfate pentahydrate, each produced these high conversions and high ratios of liquids/HC gases.

Wiser, W.H.; Shabtai, J.

1994-04-01T23:59:59.000Z

174

Coal-transformation chemistry. Fourth quarterly progress report  

SciTech Connect (OSTI)

Pyrene, perylene, anthracene, 9,10-diphenylanthracene, naphthalene and biphenyl have been employed as electron transfer agents in the reduction of Illinois No. 6 coal with potassium in tetrahydrofuran. These electron transfer agents are about equally effective for the reduction of this coal at short reaction times (3 hours). We conclude that the anions of biphenyl and naphthalene achieve a greater degree of electron transfer to the coal molecules and that the use of these anions enhances the fragmentation reactions of the coal. Illinois No. 6 bituminous coal and Colorado subbituminous coal were reacted with potassium dissolved in a mixture of monoglyme and triglyme at -50/sup 0/C. The reduction reaction proceeded via solvated electrons rather than by an electron transfer reaction. The coals were then alkylated with methyl iodide and their solubilities in tetrahydrofuran were determined. The Illinois coal reductively alkylated via solvated electrons was considerably less soluble in tetrahydrofuran than the same coal reductively alkylated with potassium and naphthalene in tetrahydrofuran. A sample of Illinois No. 6 coal which had been reductively butylated with n-butyl-1-/sup 13/C iodide was hydrolyzed. Carbon nmr spectroscopy of the hydrolyzed coal revealed that the resonances previously assigned either to the presence of n-butyl carboxylates or to n-butyl tertiary ethers were removed. This observation provides definite evidence that only carboxylates were present in the original alkylated product. Selective alkylation of the acidic hydroxyl groups in Illinois No. 6 coal was carried out using tetrabutylammonium hydroxide as a phase transfer catalyst and iodomethane or 1-iodobutane as alkylating agent as described by Liotta. The tetrahydrofuran solubility of the product was significantly improved in a reaction where reductively butylated coal was subsequently coal was subsequently methylated using Liotta's procedure.

Stock, Leon M.; Blain, D. A.; Handy, C. I.; Heimann, P.; Huang, C. B.; King, H. -H.; Landschulz, W.; Willis, R. S.

1980-01-01T23:59:59.000Z

175

Prime coats materials and methods  

E-Print Network [OSTI]

A prime coat is the application of a suitable bituminous binder applied to a nonbituminous granular base as a preliminary treatment before the application of a bituminous surfacing. The purpose of this research is to establish practical applications...

Mantilla, Christian Augusto

1994-01-01T23:59:59.000Z

176

Future Impacts of Coal Distribution Constraints on Coal Cost  

E-Print Network [OSTI]

a particular type of coal, each of which is inherentlyThere are four classes of coal: bituminous, sub-bituminous,minerals Metallic ores Coal Crude petroleum Gasoline Fuel

McCollum, David L

2007-01-01T23:59:59.000Z

177

DIRECT LIQUEFACTION PROOF OF CONCEPT  

SciTech Connect (OSTI)

The eighth bench scale test of POC program, Run PB-08, was successfully completed from August 8 to August 26, 1997. A total of five operating conditions were tested aiming at evaluating the reactivity of different pyrolysis oils in liquefaction of a Wyoming sub-bituminous coal (Black Thunder coal). For the first time, water soluble promoters were incorporated into the iron-based GelCat to improve the dispersion of the promoter metals in the feed blend. The concentration of the active metals, Mo and Fe, was 100 and 1000 ppm of moisture-free coal, respectively. Black Thunder coal used in this run was the same batch as tested in HTI?s Run POC-02. Similar to Runs PB-01 through 7, this run employed two back mixed slurry reactors, an interstage gas/slurry separator and a direct-coupled hydrotreater. In addition to the hot vapor from the second stage separator, the first stage separator overhead liquid was also fed to the hydrotreater, which was packed with Criterion C-411 hydrotreating catalyst. Pyrolysis oil was produced off-line from a pyrolysis unit acquired from University of Wyoming. Solids rejection was achieved by purging out pressure filter solid. The recycle solvents consisted of O-6 separator bottoms and pressure filter liquid (PFL). The Run PB-08 proceeded very smoothly without any interruptions. Coal conversion consistently above 90W% was achieved. High resid conversion and distillate yield have been obtained from co-processing of coal and 343°C+ (650°F+) pyrolysis oil. Light gas (C1-C3 ) yield was minimized and hydrogen consumption was reduced due to the introduction of pyrolysis oil, compared with conventional coal-derived solvent. Catalytic activity was improved by incorporating a promoter metal into the iron-based GelCat. It seemed that lowering the first stage temperature to 435°C might increase the hydrogenation function of the promoter metal. In comparison with previous coal-waste coprocessing run (PB-06), significant improvements in the process performance were achieved due to catalyst modification and integration of pyrolysis technique into liquefaction.

NONE

1998-09-01T23:59:59.000Z

178

Montana Integrated Carbon to Liquids (ICTL) Demonstration Program  

SciTech Connect (OSTI)

Integrated carbon?to?liquids technology (ICTL) incorporates three basic processes for the conversion of a wide range of feedstocks to distillate liquid fuels: (1) Direct Microcatalytic Coal Liquefaction (MCL) is coupled with biomass liquefaction via (2) Catalytic Hydrodeoxygenation and Isomerization (CHI) of fatty acid methyl esters (FAME) or trigylceride fatty acids (TGFA) to produce liquid fuels, with process derived (3) CO{sub 2} Capture and Utilization (CCU) via algae production and use in BioFertilizer for added terrestrial sequestration of CO{sub 2}, or as a feedstock for MCL and/or CHI. This novel approach enables synthetic fuels production while simultaneously meeting EISA 2007 Section 526 targets, minimizing land use and water consumption, and providing cost competitive fuels at current day petroleum prices. ICTL was demonstrated with Montana Crow sub?bituminous coal in MCL pilot scale operations at the Energy and Environmental Research Center at the University of North Dakota (EERC), with related pilot scale CHI studies conducted at the University of Pittsburgh Applied Research Center (PARC). Coal?Biomass to Liquid (CBTL) Fuel samples were evaluated at the US Air Force Research Labs (AFRL) in Dayton and greenhouse tests of algae based BioFertilizer conducted at Montana State University (MSU). Econometric modeling studies were also conducted on the use of algae based BioFertilizer in a wheat?camelina crop rotation cycle. We find that the combined operation is not only able to help boost crop yields, but also to provide added crop yields and associated profits from TGFA (from crop production) for use an ICTL plant feedstock. This program demonstrated the overall viability of ICTL in pilot scale operations. Related work on the Life Cycle Assessment (LCA) of a Montana project indicated that CCU could be employed very effectively to reduce the overall carbon footprint of the MCL/CHI process. Plans are currently being made to conduct larger?scale process demonstration studies of the CHI process in combination with CCU to generate synthetic jet and diesel fuels from algae and algae fertilized crops. Site assessment and project prefeasibility studies are planned with a major EPC firm to determine the overall viability of ICTL technology commercialization with Crow coal resources in south central Montana.

Fiato, Rocco; Sharma, Ramesh; Allen, Mark; Peyton, Brent; Macur, Richard; Cameron, Jemima

2013-09-30T23:59:59.000Z

179

NEW SOLID FUELS FROM COAL AND BIOMASS WASTE  

SciTech Connect (OSTI)

Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable fuel. These fuels will be converted to energy while reducing CO{sub 2} emissions from power generating boilers and mitigating global warming concerns. This report describes the sludge analysis, solid fuel preparation and production, combustion performance, environmental emissions and required equipment.

Hamid Farzan

2001-09-24T23:59:59.000Z

180

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

SciTech Connect (OSTI)

We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst–capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst–capture agents on (1) the syngas composition, (2) CO{sub 2} and H{sub 2}S capture, and (3) the steam–coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO–CaCO{sub 3} chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO{sub 3} was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO–CaCO{sub 3} cycles. The increased steam–coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2–4% per CaO–CaCO{sub 3} cycle. We also discuss an important application of this combined gasifier–calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO{sub 4} and ash in the precalcined feedstock.

Siefert, Nicholas S.; Shekhawat, Dushyant; Litster, Shawn; Berry, David, A

2013-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals  

SciTech Connect (OSTI)

This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, pH, Photosynthetically Activate Radiation (PAR) and dissolved oxygen (DO); and a ~2 gallons per minute (gpm) algae culture dewatering system. Among the three algae strains, Scenedesmus showed the most tolerance to temperature and irradiance conditions in Phoenix and the best self-settling characteristics. Experimental findings and operational strategies determined through these tests guided the operation of the algae cultivation system for the scale-up study. Effect of power plant flue gas, especially heavy metals, on algae growth and biomass adsorption were evaluated as well.

Sun, Xiaolei; Rink, Nancy

2011-04-30T23:59:59.000Z

182

Coal Ash Behavior in Reducing Environments (CABRE) III Year 6 - Activity 1.10 - Development of a National Center for Hydrogen  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC) has been conducting research on gasification for six decades. One of the objectives of this gasification research has been to maximize carbon conversion and the water–gas shift process for optimal hydrogen production and syngas quality. This research focus and experience were a perfect fit for the National Center for Hydrogen Technology ® (NCHT®) Program at the EERC for improving all aspects of coal gasification, which ultimately aids in the production and purification of hydrogen. A consortia project was developed under the NCHT Program to develop an improved predictive model for ash formation and deposition under the project entitled “Coal Ash Behavior in Reducing Environments (CABRE) III: Development of the CABRE III Model.” The computer-based program is now applicable to the modeling of coal and ash behavior in both entrained-flow and fluidized-bed gasification systems to aid in overall gasification efficiency. This model represents a significant improvement over the CABRE II model and runs on a Microsoft Windows PC platform. The major achievements of the CABRE III model are partitioning of inorganic transformations between various phases for specific gas cleanup equipment; slag property predictions, including standard temperature–viscosity curves and slag flow and thickness; deposition rates in gasification cleanup equipment; provision for composition analysis for all input and output streams across all process equipment, including major elements and trace elements of interest; composition analysis of deposit streams for various deposit zones, including direct condensation on equipment surfaces (Zone A), homogeneous particulate deposition (Zone B), and entrained fly ash deposition (Zone C); and physical removal of ash in cyclones based on D50 cut points. Another new feature of the CABRE III model is a user-friendly interface and detailed reports that are easily exportable into Word documents, Excel spreadsheets, or as pdf files. The user interface provides stepwise guides with built-in checks for efficient entry of required input data on fuels of interest to allow a successful execution of the model. The model was developed with data from several fuels selected by the sponsors, including bituminous coal, subbituminous coal, lignite, and petroleum coke (petcoke). The data from these fuels were obtained using small pilot-scale entrained-flow and fluidized-bed gasifiers at the Energy & Environmental Research Center (EERC). The CABRE III model is expected to further advance the knowledge base for the NCHT® Program and, more importantly, allow for prediction of the slagging and fouling characteristics of fuels in reducing environments. The information obtained from this program will potentially also assist in maintaining prolonged gasifier operation free from failure or facilitate troubleshooting to minimize downtime in the event of a problem.

Stanislowski, Joshua; Azenkeng, Alexander; McCollor, Donald; Galbreath, Kevin; Jensen, Robert; Lahr, Brent

2012-03-31T23:59:59.000Z

183

OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS  

SciTech Connect (OSTI)

The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

Constance Senior

2004-12-31T23:59:59.000Z

184

ITP Mining: Energy and Environmental Profile of the U.S. Mining...  

Broader source: Energy.gov (indexed) [DOE]

1 Combustion Engineering, Combustion-Fossil Power, Chapter 2-7, 1991. Coal 2-1 Energy and Environmental Profile of the U.S. Mining Industry Anthracite - Hard and very...

185

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect (OSTI)

The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

Michael L. Swanson

2005-08-30T23:59:59.000Z

186

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

187

Low-rank coal oil agglomeration  

DOE Patents [OSTI]

A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

Knudson, Curtis L. (Grand Forks, ND); Timpe, Ronald C. (Grand Forks, ND)

1991-01-01T23:59:59.000Z

188

Assessment of China's Energy-Saving and Emission-Reduction Accomplishments and Opportunities During the 11th Five Year Plan  

E-Print Network [OSTI]

Swedish National Energy Administration ton coal equivalenttCO 2 ) Energy Electricity * bituminous coal Costs areare needed, such as energy price reform (coal, electricity,

Levine, Mark D.

2010-01-01T23:59:59.000Z

189

Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network [OSTI]

In addition, the coking coal market began to deteriorateits permeability. Bituminous, or coking coal, is blended andmerchant coke plants, coking coal is heated in a low-oxygen,

Worrell, Ernst

2011-01-01T23:59:59.000Z

190

Inventory of China's Energy-Related CO2 Emissions in 2008  

E-Print Network [OSTI]

gas petroleum waxes coking coal t C/TJ other bituminous coalprocesses of coal washing, coking, petroleum refineries, gaslosses include coal washing, coking, petroleum refining, gas

Fridley, David

2011-01-01T23:59:59.000Z

191

Resource Limits and Conversion Efficiency with Implications for Climate Change  

E-Print Network [OSTI]

historical trends in coal seam thickness and depth andanthracite and bituminous coal seams exceeding 28 inches indepths in ever thinner coal seams. The goal of Part I of

Croft, Gregory Donald

2009-01-01T23:59:59.000Z

192

ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL  

E-Print Network [OSTI]

H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d Con£. , 2, 35 (1932);

Mobley, David Paul

2013-01-01T23:59:59.000Z

193

THE CHEMISTRY OF COAL MODEL COMPOUNDS -CLEAVAGE OF ALIPHATIC BRIDGES BETWEEN AROMATIC NUCLEI CATALYSED BY LEWIS ACIDS  

E-Print Network [OSTI]

and Background I. II. III. IV. II. Coal Liquefaction . •Coal Structure • • . Lewis Acid Catalysts. Scope andOrganic Structure of Bituminous Coal", Proceedings, Stanford

Taylor, Newell D.

2011-01-01T23:59:59.000Z

194

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Preparations for conducting large-scale combustion tests with caking bituminous coal continued during the start of this quarter. Major project accomplishments related to bituminous coal testing included: a CFD preheat model and evaluation, an update of the process flow diagram and a detailed preheat burner mechanical design (suitable for construction) for firing bituminous coal. Installation and testing of the 85 MMBtu/h bituminous coal preheating system was planned to take place before the end of December. Based on the inability to conduct testing in Riley's Commercial Burner Test Facility (CBTF) during freezing weather, a schedule review indicated required site work for testing bituminous coal at the CBTF could not be completed before freezing weather set in at the site. Further bituminous preheat modification work was put on hold and efforts turned to securing the test facility over the winter season. Bituminous coal tests are therefore delayed; April-May 2005 is earliest estimate of when testing can resume. A request for a time extension was submitted to DOE to extend the project through September 2005 to allow time to secure additional funding and complete the bituminous coal testing. Removal of the PRB PC Preheater from the CBTF burner deck was completed. Decommissioning of the CBTF for the winter was also completed.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-12-31T23:59:59.000Z

195

Coal is a combustible sedimentary rock and a valuable economic resource. During the Pennsylvanian Period  

E-Print Network [OSTI]

Coal is a combustible sedimentary rock and a valuable economic resource. During the Pennsylvanian of years produced the bituminous coals currently found in southwestern Indiana. Bituminous coals in Indiana currently ranks as the seventh-largest coal-producing state in the nation and has an estimated 17.57 billion

Polly, David

196

Carbon Vol. 28, Nos. 213. pp. 261-279, 1990 Printed in Great Britain.  

E-Print Network [OSTI]

: carbon formation from catalyzed CO decomposition over iron and from liquid phase coking of hydrocarbons. preparation of carbons via catalytic cracking of CO and coking processes, 2. carbon active sites of concern. In par- ticular. we envisioned gasifying plentiful anthracite coal, with its attendant mineral matter

197

Catalysts for coal liquefaction processes  

DOE Patents [OSTI]

Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

Garg, D.

1986-10-14T23:59:59.000Z

198

Catalytic coal liquefaction process  

DOE Patents [OSTI]

An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

Garg, D.; Sunder, S.

1986-12-02T23:59:59.000Z

199

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base  

E-Print Network [OSTI]

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base Gregory D. Croft1 and Tad W that could be used to create mega- scale conversion of coal to liquid transportation fuels. In a separate the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite

Patzek, Tadeusz W.

200

Vitrinite reflectance anisotropy as a tectonic fabric element  

SciTech Connect (OSTI)

The anisotropy of the coal maceral vitrinite was analyzed in relation to the tectonic setting of a coal from the Southern Anthracite Field in Pennsylvania. For the coal studied, the maximum-intermediate reflectance plane essentially paralleled the axial plane of the synclinorium (N66/sup 0/E strike, 64/sup 0/SE dip).

Hower, J.C. (Univ. of Kentucky, Lexington); Davis, A.

1981-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Coal liquefaction process using pretreatment with a binary solvent mixture  

DOE Patents [OSTI]

An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300.degree. C. before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil.

Miller, Robert N. (Allentown, PA)

1986-01-01T23:59:59.000Z

202

Catalytic coal liquefaction process  

DOE Patents [OSTI]

An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

1986-01-01T23:59:59.000Z

203

Catalysts for coal liquefaction processes  

DOE Patents [OSTI]

Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

Garg, Diwakar (Macungie, PA)

1986-01-01T23:59:59.000Z

204

FAR AND MIDINFRARED SPECTROSCOPY OF COMPLEX ORGANIC MATTER OF ASTROCHEMICAL INTEREST: COAL, HEAVY PETROLEUM FRACTIONS, AND  

E-Print Network [OSTI]

, HEAVY PETROLEUM FRACTIONS, AND ASPHALTENES Franco Cataldo1,2 , D. A. GarcíaHernández3,4 , Arturo), heavy aromatic fraction (BQ1) and asphaltenes derived from BQ1 were used together with anthracite coal asphaltenes fraction. Particularly interesting is the ability of BQ1 to match the band pattern

205

Prediction of metallurgical coke strength from the petrographic composition of coal blends  

SciTech Connect (OSTI)

Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

2009-07-01T23:59:59.000Z

206

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network [OSTI]

other bituminous coal and coking coal. Small differences incoal (used as fuel) Coking coal Coke oven coke Natural gasrange for typical NCVs of coking coal of 26.6 to 29.8Mj/kg.

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

207

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

5. Power generation via IGCC from bituminous coal. It shouldElectricity Generation (KWh/gallon FT Liquid) Coal-to-PowerElectricity Generation (KWh/gallon FT Liquid) Coal-to-Power

Lu, Xiaoming

2012-01-01T23:59:59.000Z

208

FRAGMENTATION OF COAL AND IMPROVED DISPERSION OF LIQUEFACTION CATALYSTS USING IONIC LIQUIDS.  

E-Print Network [OSTI]

??Coal has been utilized for coal-to-liquid fuels and coal-to-chemical industries both historically in South Africa and recently in China. Abundant bituminous and low-rank coal reserves… (more)

Cetiner, Ruveyda

2011-01-01T23:59:59.000Z

209

asian villages asia: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

GCLS AND BITUMINOUS GEOMEMBRANES H. Bannour1 regarding the behavior of geosynthetic clay liners (GCLs) as part of a composite liner, focused Paris-Sud XI, Universit de 68...

210

asian regional conference: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

GCLS AND BITUMINOUS GEOMEMBRANES H. Bannour1 regarding the behavior of geosynthetic clay liners (GCLs) as part of a composite liner, focused Paris-Sud XI, Universit de 15...

211

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network [OSTI]

other bituminous coal and clean coal. The NCV used in theadded to the rest of the clean coal used in the industry andand added to the reported clean coal used as a fuel in the

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

212

SAS Output  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Bituminous Coal BIT Source: 1 205.30000 Distillate Fuel Oil DFO Source: 1 161.38600 Geothermal GEO Estimate from EIA, Office of Integrated Analysis and Forecasting 16.59983 Jet...

213

Low-rank coal oil agglomeration  

DOE Patents [OSTI]

A low-rank coal oil agglomeration process is described. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and is usually coal-derived.

Knudson, C.L.; Timpe, R.C.

1991-07-16T23:59:59.000Z

214

CONDITIONING TECHNOLOGY FOR RADIOACTIVE WASTE RESULTED FROM THE TREATMENT OF LIQUID WASTE FROM THE ROMANIAN NUCLEAR POWER PLANT  

SciTech Connect (OSTI)

For the conditioning of spent resins contaminated with radionuclides, such as: 137Cs, 134Cs, 60Co, 58Co, 57Co, 54Mn, etc., techniques of direct immobilization in cement, bitumen and organic polymers have been tested. The selected process was the bituminization using industrial bitumen, I 60-70, made in Romania, which had very good characteristics. The paper presents stages of the research project, technical conditions for the process and advantages of the bituminization of spent resins.

ARSENE, CARMEN; ANDREI, VERONICA; NEGOIU, DUMITRU

2003-02-27T23:59:59.000Z

215

Possibilities of coke manufacture in nonpollutant conditions  

SciTech Connect (OSTI)

The paper presents some possibilities to obtain coke briquettes from anthracite, using as binders petroleum pitch, wheat flour, cement, plaster, ashes from power-plants dried from the electrofilters. Specific thermal post-treatment were proposed for each case, such as: oxidation or heating at low temperatures (under 300 C). As a result the authors obtained coke briquettes to be used in small equipment, with no pollutant pyrogenetic treatment.

Barca, F.; Panaitescu, C.; Vidrighin, C.; Peleanu, I. [Politehnica Univ. Bucharest (Romania); Albastroiu, P. [S.C. ICEM S.A., Bucharest (Romania)

1994-12-31T23:59:59.000Z

216

Coal liquefaction process using pretreatment with a binary solvent mixture  

DOE Patents [OSTI]

An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

Miller, R.N.

1986-10-14T23:59:59.000Z

217

Antigua and Barbuda: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCT Biomass Facility Jumpvolcanic region, California |AnthraciteJump

218

Process for increasing the bitumen content of oil sands froth  

SciTech Connect (OSTI)

A process is described for the removal of solids and water from a feed bituminous froth containing bitumen, solids and water in a gravity settling vessel have an existing bituminous froth layer floating on a quiescent body of water defining a bitumen-water interface therebetween comprising the steps of heating the feed bituminous froth to a temperature in the range of 85 to 100 C, feeding the heated froth into the body of water at a level below the bitumen-water interface whereby water and solids contained in the feed froth separate from the froth and the bitumen rises to accumulate in the existing bituminous froth layer, discharging solids-containing under flow from the vessel, monitoring the level of the bitumen-water interface and controlling the discharge of solids-containing under flow responsive to the monitoring of the bitumen-water interface at a rate such that the said interface is maintained at an effective level above the level at which the feed bituminous froth is fed into the body of water, and recovering a bitumen-enriched layer as an overflow.

Tipman, R.N.; Rajan, V.S.V.; Wallace, D.

1993-06-29T23:59:59.000Z

219

Methane de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale combustion tests with caking bituminous coal was on hold this quarter mainly due to Riley's Commercial Burner Test Facility (CBTF) not having adequate weatherproofing to support operation under freezing conditions. The CBTF was secured and decommissioned for the winter season. CBTF bituminous coal tests shall continue to remain on hold now as a result of project funding limitations, however. No further modifications at the CBTF are planned until needed support is obtained. Activities this quarter have concentrated on finding additional support for the project. Currently, GTI has been granted a no-cost time extension through September 2005 and efforts to secure more support will continue in hopes that large-scale preheat caking bituminous combustion tests will be carried out as planned.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2005-03-31T23:59:59.000Z

220

Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance  

SciTech Connect (OSTI)

A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

Andrew Seltzer; Zhen Fan

2011-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Resource characterization series (final)  

SciTech Connect (OSTI)

Coals from the Princess Reserve District in northeastern Kentucky were obtained from the R-series cores and from Kentucky Geological Survey collections. The coals span the stratigraphic section from the Bruin coal near the base of the Breathitt Formation to a coal near the top of the Conemaugh Formation. The Princess District coals are high volatile C and B bituminous. High volatile A bituminous coals occur in southern Lawrence County. Reflectance highs and reactive maceral lows were noted in the Princess 3 and Princess 7 coals in along a north-south trend which may be parallel to the Waverly Arch.

Hower, J.C.; Wild, G.D.

1981-01-01T23:59:59.000Z

222

Create a Consortium and Develop Premium Carbon Products from Coal  

SciTech Connect (OSTI)

The objective of these projects was to investigate alternative technologies for non-fuel uses of coal. Special emphasis was placed on developing premium carbon products from coal-derived feedstocks. A total of 14 projects, which are the 2003 Research Projects, are reported herein. These projects were categorized into three overall objectives. They are: (1) To explore new applications for the use of anthracite in order to improve its marketability; (2) To effectively minimize environmental damage caused by mercury emissions, CO{sub 2} emissions, and coal impounds; and (3) To continue to increase our understanding of coal properties and establish coal usage in non-fuel industries. Research was completed in laboratories throughout the United States. Most research was performed on a bench-scale level with the intent of scaling up if preliminary tests proved successful. These projects resulted in many potential applications for coal-derived feedstocks. These include: (1) Use of anthracite as a sorbent to capture CO{sub 2} emissions; (2) Use of anthracite-based carbon as a catalyst; (3) Use of processed anthracite in carbon electrodes and carbon black; (4) Use of raw coal refuse for producing activated carbon; (5) Reusable PACs to recycle captured mercury; (6) Use of combustion and gasification chars to capture mercury from coal-fired power plants; (7) Development of a synthetic coal tar enamel; (8) Use of alternative binder pitches in aluminum anodes; (9) Use of Solvent Extracted Carbon Ore (SECO) to fuel a carbon fuel cell; (10) Production of a low cost coal-derived turbostratic carbon powder for structural applications; (11) Production of high-value carbon fibers and foams via the co-processing of a low-cost coal extract pitch with well-dispersed carbon nanotubes; (12) Use of carbon from fly ash as metallurgical carbon; (13) Production of bulk carbon fiber for concrete reinforcement; and (14) Characterizing coal solvent extraction processes. Although some of the projects funded did not meet their original goals, the overall objectives of the CPCPC were completed as many new applications for coal-derived feedstocks have been researched. Future research in many of these areas is necessary before implementation into industry.

Frank Rusinko; John Andresen; Jennifer E. Hill; Harold H. Schobert; Bruce G. Miller

2006-01-01T23:59:59.000Z

223

EIS-0357- Gilberton Coal-to-Clean Fuels and Power Project in Giberton, PA  

Broader source: Energy.gov [DOE]

This Environmental Impact Statement (EIS) assesses the potential environmental impacts that would result from a proposed Department of Energy (DOE) action to provide cost-shared funding for construction and operation of facilities near Gilberton, Pennsylvania, which have been proposed by WMPI PTY, LLC, for producing electricity, steam, and liquid fuels from anthracite coal waste (culm). The project was selected by DOE under the Clean Coal Power Initiative (CCPI) to demonstrate the integration of coal waste gasification and Fischer-Tropsch (F-T) synthesis of liquid hydrocarbon fuels at commercial scale.

224

PREVENTTVE FACILITIES AND EMERGENCY OPERATIONS IN CASE OFFIRES IN CdF COAL MINES  

E-Print Network [OSTI]

). The upper group consists of a bituminous soft coal, the lower coke coal. The field is sharply folded alongPREVENTTVE FACILITIES AND EMERGENCY OPERATIONS IN CASE OFFIRES IN CdF COAL MINES J.P. AMARTIN HJSJL a stricl methodology. It has been possjble then to resume coal winning, which has cor.tmued until

Boyer, Edmond

225

Influence of coal on coke properties and blast-furnace operation  

SciTech Connect (OSTI)

With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

2007-07-01T23:59:59.000Z

226

REMEDIAT1NG AT MANUFACTURED GAS  

E-Print Network [OSTI]

, comhusti- hle gas manufactured Pfrom coke, coal, and oil 1 served as the major gas- eous fuel for urban for the three primary gas production meth- ods: coal carbonization, carbureted water gas production, and oil gas, and metals. Tar resid- uals were produced from the vola- tiIe component of bituminous coals in coal

Peters, Catherine A.

227

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale PRB testing during the current quarter was cut short due to the inability of the coal mill to meet the 85 MMBtu/h design firing rate. The project was therefore redirected toward design, installation and testing of the 85-million Btu/h preheater for bituminous coal. Based on extensive pilot-scale testing completed earlier in the project, 2-D modeling and preliminary design activities were started based on the use of staged, annular protective air films to control temperature and prevent deposition on the preheater walls. A total of 14 2-D modeling cases were completed for the modified preheater for bituminous coal. The preheater concept modeled was based on an expanding preheater chamber where the diameter of the chamber is increased in steps along its length and annular cooling/protective air is introduced at each step. A process flow diagram for the bituminous coal preheating system and a preliminary preheater design drawing were developed based on the modeling results. A project schedule to complete design, installation and testing of the 85 MMBtu/h bituminous coal preheating system before the end of December was also developed.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-09-30T23:59:59.000Z

228

Recent technologies and processes for enhanced safety in bitumen or cement solidification of Li/ml radwaste  

SciTech Connect (OSTI)

SGN has more than 20 years of experience in the treatment of low and medium level radioactive wastes. SGN industrialized two major types of radwaste processes: bituminization and cement solidification. The R&D work on these two processes is discussed.

Tchemitcheff, F.

1993-12-31T23:59:59.000Z

229

Adhesion in bitumen-aggregate systems and quantification of the effect of water on the adhesive bond  

E-Print Network [OSTI]

This research is intended to contribute toward the understanding, development, and implementation of a more fundamental design process for bituminous pavement materials, utilizing thermodynamic properties of the materials involved.... The theory developed by van Oss, Chaudhury and Good forms the basis of this research. Optimization of techniques to characterize surface energy, as well as consideration and evaluation of additional factors that influence adhesion...

Hefer, Arno Wilhelm

2005-02-17T23:59:59.000Z

230

Fluid substitution in rocks saturated with viscoelastic fluids Dina Makarynska1  

E-Print Network [OSTI]

- terest in production from bituminous and heavy-oil reservoirs. Heavy-oil reserves account for more than 6 trillion barrels-in-place worldwide -- triple the world's reserves of conventional oil and gas Batzle et al , Jyoti Behura3 , and Mike Batzle4 ABSTRACT Heavy oils have high densities and extremely high viscosities

231

Equations for predicting the layer stiffness moduli in pavement systems containing lime-flyash stabilized materials  

E-Print Network [OSTI]

in site 2. Site 2 resurfaced with 2 in. NIAC jn Dctober 1980. originally constructed of one-course bituminous surface treatment. All ten sections of the test site were re-surfaced in October, 1980, with a 2-inch hot mix concrete overlay. Varying...

Alam, Shah Manzoor

1984-01-01T23:59:59.000Z

232

Construction Package No. 2. Final Earthwork and Roadwork (RADL Item 7-28)  

SciTech Connect (OSTI)

The final earthwork, aggregate surfacing, roadwork and paving for the Barstow Solar Pilot Plant are presented. The work consisted of applying weed killer to surfaces to be paved, constructing bituminous pavements, restoring existing compacted aggregate base roadways, and stripping and removing existing grade from the core area for compacted aggregate surfacing.

Not Available

1980-07-01T23:59:59.000Z

233

Rencontres Gosynthtiques -9-11 avril 2013, Dijon DBITS DANS UNE TANCHIT COMPOSITE GOMEMBRANE  

E-Print Network [OSTI]

years regarding the behaviour of geosynthetic clay liners (GCLs) as part of a composite liner composed, geosynthetic clay liner, bituminous geomembrane, flow rate 1. Introduction Les géomembranes bitumineuses (GM to an alternative design for a canal projected in France at the moment. Keywords: Geosynthetics, composite liners

Paris-Sud XI, Université de

234

Erroneous coal maturity assessment caused by low temperature oxidation  

E-Print Network [OSTI]

Erroneous coal maturity assessment caused by low temperature oxidation Y. Copard J. R. Disnar, J. F on different outcrop coals from the French Massif Central revealed abnormally high Tmax values, which initially observed for medium to low volatile bituminous coals (Rr1.5%), was accompanied by a very clear exponential

Paris-Sud XI, Université de

235

C/H{sub 2}O reaction under supercritical conditions and their repercussions in the preparation of activated carbon  

SciTech Connect (OSTI)

Two chars prepared by carbonization of oak wood and anthracite were used to perform a comparative study of the gasification with supercritical water (SCW) and with steam. This work reports the effects of the type of char, the activating agent, temperature, flow rate, and particle size employed on the kinetics, mechanism of reaction, and the characteristics of the activated carbons obtained. The results show that the reactivity of the two chars is much higher with SCW than with steam. Although this increase can be explained in terms of the greater penetration of SCW and diffusional effects in the pore structure of the chars, some aspects suggest a possible change in the mechanism of reaction favored by the formation of clusters in SCW. The evolution of porosity was also found to differ when the char was gasified with SCW and with steam, being governed strongly by the starting material. When the oak char was activated with SCW, the smallest microporosity was broadened from the very first moments due to its very open pore structure, providing carbons with larger micropores and some mesoporosity. In contrast, in the case of the anthracite char, with a narrower pore structure, the evolution of the porosity was slower and less uniform, favoring external gasification of the particle. Accordingly, the carbons had a broader distribution of micropores, and mesoporosity was scarce.

Salvador, F.; Senchez-Montero, M.J.; Izquierdo, C. [University of Salamanca, Salamanca (Spain)

2007-09-15T23:59:59.000Z

236

Upgrading of low-rank coals for conventional and advanced combustion systems  

SciTech Connect (OSTI)

Low-rank coals, subbituminous, lignitic, and brown coals, have a ubiquitous presence in the world, being found in all continents. Close to half of the world`s estimated coal resources are low- rank coals. Many countries have no alternative economic source of energy. In the lower 48 states of the United States, there are 220 billion tons of economically recoverable reserves of lignite and subbituminous coal. Add to this quantity 5 trillion tons of predominantly subbituminous coal in Alaska, and the combined amount represents the largest supply of the lowest-cost fuels available for generating electric power in the United States. However, to use these coals cost-effectively and in an environmentally acceptable way, it is imperative that their properties and combustion/gasification behavior be well understood. The Energy and Environmental Research Center (EERC) takes a cradle-to-grave approach (i.e., mining, precleaning, combustion/gasification, postcleaning, and reuse and disposal of residues) for all aspects of coal processing and utilization. The environmental impact of these activities must be matched with the appropriate technologies. Experience over many years has shown that variations in coal and ash properties have a critical impact on design, reliability and efficiency of operation, and environmental compliance when low-rank coals are burned in conventional systems. This chapter reviews the significant technical issues of beneficiation, which includes reduction in moisture as well as ash (including sulfur), in relation to low-rank coal properties and their impact on conventional and advanced power systems. Finally, the development and utilization of low-rank coal resources are briefly discussed in view of policy, economic, and strategic issues.

Young, B.C.; Musich, M.A.; Jones, M.L.

1993-12-31T23:59:59.000Z

237

Pelletizing lignite  

DOE Patents [OSTI]

Lignite is formed into high strength pellets having a calorific value of at least 9,500 Btu/lb by blending a sufficient amount of an aqueous base bituminous emulsion with finely-divided raw lignite containing its inherent moisture to form a moistened green mixture containing at least 3 weight % of the bituminous material, based on the total dry weight of the solids, pelletizing the green mixture into discrete green pellets of a predetermined average diameter and drying the green pellets to a predetermined moisture content, preferrably no less than about 5 weight %. Lignite char and mixture of raw lignite and lignite char can be formed into high strength pellets in the same general manner.

Goksel, Mehmet A. (Houghton, MI)

1983-11-01T23:59:59.000Z

238

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

SciTech Connect (OSTI)

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

239

Chemical comminution of coal  

SciTech Connect (OSTI)

The objective of the present research is to study the chemical reactivity of a mixture of methyl alcohol and aqueous sodium hydroxide solution in the temperature range 298 to 363 K, and a caustic concentration of 0 to 10 wt. %, on an Iowa bituminous coal. The sample studied was collected from coal zone 4, equivalent to most historical references to Laddsdale coal. The coals in this zone are typical high-sulfur, high-ash middle Pennsylvania Cherokee group coals. The apparent rank is high-volatile C bituminous coal. The relatively high content of sulfur and 23 other elements in these coals is related to near neutral (6-8) pH conditions in the depositional and early diagenetic environments, and to postdepositional sphalerite/calcite/pyrite/kaolinite/barite mineralization.

Mamaghani, A.H.; Beddow, J.K.; Vetter, A.F.

1987-02-01T23:59:59.000Z

240

Photochemical oxidation of coals and some selected model compounds by using copper(II) chloride  

SciTech Connect (OSTI)

The H-donor ability of different rank coals was examined by using a copper(II)chloride-acetonitrile system as the dehydrogenator. A bituminous coal and two lignites were irradiated in the UV in the presence of copper(II)chloride in acetonitrile. The coal was dehydrogenated while the Cu(II) was reduced to CU(I). Considerable amounts of aliphatic or alicyclic hydrogen were removed from the coals. In the process, while the oxygen contents of coals do not increase, more condensed aromatic products occur. It was concluded that lignites are better reducing agents than bituminous coals. A photooxidation mechanism is proposed on the basis of the model compound reaction. Photooxidation of alcohols (ethanol, 2-propanol, benzyl alcohol, 4-hydroxybenzyl alcohol, and diphenyl carbinol), a hydroaromatic compound (tetrahydronaphthalene), and an aromatic ether (dibenzyl ether) was performed under similar reaction conditions.

Yilmaz, M.

1999-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Coal metamorphism in the upper portion of the Pennsylvanian Sturgis Formation in Western Kentucky  

SciTech Connect (OSTI)

Coals from the Pennsylvanian upper Sturgis Formation (Mississippian and Virginian) were sampled from a borehole in Union County, western Kentucky. The coals exhibited two discrete levels of metamorphism. The lower rank coals of high-volatile C bituminous rank were assumed to represent the normal level of metamorphism. A second set of coals of high-volatile A bituminous rank was found to be associated with sphalerite, chlorite, and twinned calcite. The latter mineral assemblages indicate that hydrothermal metamorphism was responsible for the anomalous high rank. Consideration of the sphalerite fluid-inclusion temperatures from nearby ores and coals and the time - temperature aspects of the coal metamorphism suggests that the hydrothermal metamorphic event was in the 150 to 200 C range for a brief time (10/sup 5/-10/sup 5/and yr), as opposed to the longer term (25-50m yr) 60 to 75 C ambient metamorphism.

Hower, J.C.

1983-12-01T23:59:59.000Z

242

Petrography of the Herrin (No. 11) coal in western Kentucky  

SciTech Connect (OSTI)

The Herrin (No.11) coal in western Kentucky is in the upper part of the Pennsylvanian (Des Moinesian) Carbondale Formation. Samples were obtained from 13 mines in Kentucky and one mine in Illinois in three equal benches from two to three channels for a total of 93 samples. The rank of the coal (as vitrinite reflectance) is high volatile C bituminous in the Moorman Syncline and high volatile A bituminous in the Webster Syncline. Reflectance does not vary between mines in the Moorman Syncline. The percentage of total vitrinite macerals for each mine is over 85% and the percentage of total vitrinite plus liptinite macerals is over 89% (average over 90%) (both on dry, mineral-free basis). 37 refs.

Hower, J.C.; Wild, G.D.

1981-06-01T23:59:59.000Z

243

Coal transformation chemistry third quarterly progress report  

SciTech Connect (OSTI)

A Colorado subbituminous coal was reacted with potassium and naphthalene in tetrahydrofuran. This was then alkylated with n-butyl iodide and the solubility in tetrahydrofuran was determined. The solubility was found to be less than in a corresponding reaction with Illinois No. 6 coal. The solubilization of a Colorado subbituminous coal by reacting it with potassium in liquid ammonia, followed by alkylation is discussed. The preliminary results from a reaction of Illinois No. 6 coal with tetrabutylammonium hydroxide and methyl iodide are reported. Reductive acylation of coal is being studied at the present time using trifluoroacetic anhydride as a quenching reagent. /sup 19/F is a candidate for nmr studies and chemical shifts for trifluoroacetyl derivatives of phenols, thiols, and amides indicate that fluorine may be useful as a sensitive probe for reactive species in coal. The effort on donor solvent coal chemistry was directed to the role played by pericyclic reactions in the liquefaction process. The acceptors were reduced by the deuterated donors. The isotopic distribution of the reduction product indicates that free radical processes occur preferentially. Thus, the pericyclic reactions appear to be unimportant at the threshold reaction temperatures of 350 to 425/sup 0/C. The reactions of aromatic ethers with inorganic sulfide at 400/sup 0/C produces thiophenols.

Stock, Leon M.; Blain, D. A.; Handy, C. I.; Huang, C. B.; King, H. H.; Landschulz, W.; Willis, R. S.

1980-01-01T23:59:59.000Z

244

May 23, 2013 ABC and Innovative  

E-Print Network [OSTI]

-girders with CIP deck ­ Span length, 90-150 ft. ­ 2012 Average Cost, $125/SF · 3-span CIP slab bridge ­ Span length have bituminous overlay and one has 5" composite CIP overlay ­ Details can be modified for higher ADT in one week (vs. 4-5 weeks for CIP slab, 2-3 weeks for precast beam/CIP deck) ­ No falsework required

Minnesota, University of

245

The H-Coal pilot plant and the Breckinridge Project  

SciTech Connect (OSTI)

A large coal-liquefaction pilot plant is in operation at Catlettsburg, Kentucky, expanding on the H-Coal technology. The pilot plant operated very successfully during 1981, confirming research yield data on eastern bituminous coal, demonstrating operability of the process, and resulting in a significant accumulation of engineering data. Ashland Synthetic Fuels, Inc., and Bechtel Petroleum, Inc., are developing the Breckinridge Project, a commercial coal-liquefaction plant proposed for Breckinridge County, Kentucky, based on the H-Coal technology.

Wigglesworth, T.H.

1982-05-01T23:59:59.000Z

246

College Of Wooster 2012 Greenhouse Gas Emissions From Coal and Natural Gas Combustion Default Values From EPA Greenhouse Gas Rule  

E-Print Network [OSTI]

56410 CO2 = 1 X 10 -3 X Fuel X HHV X EF Where CO2 = Annual CO2 mass emissions for the specific fuel type high heat value. EF =Fuel default CO2 Emission Factor from Table C-1Page 56410 CO2 Coal CO2 = 1 X 10 -3 Default CO2 Emission Factor For Bituminous Coal = 93.40 kg/mmbtu Default CH4 Emission Factor

Wilson, Mark A.

247

Sustainable development with clean coal  

SciTech Connect (OSTI)

This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

NONE

1997-08-01T23:59:59.000Z

248

Association of coal metamorphism and hydrothermal mineralization in Rough Creek fault zone and Fluorspar District, Western Kentucky  

SciTech Connect (OSTI)

The ambient coal rank (metamorphism) of the Carboniferous coals in the Western Kentucky coalfield ranges from high volatile A bituminous (vitrinite maximum reflectance up to 0.75% R/sub max/) in the Webster syncline (Webster and southern Union Counties) to high volatile C bituminous (0.45 to 0.60% R/sub max/) over most of the remainder of the area. Anomalous patterns of metamorphism, however, have been noted in coals recovered from cores and mines in fault blocks of the Rough Creek fault zone and Fluorspar District. Coals in Gil-30 borehole (Rough Creek faults, Bordley Quadrangle, Union County) vary with no regard for vertical position, from high volatile C(0.55% R/sub max/) to high volatile A (0.89%R/sub max) bituminous. Examination of the upper Sturgis Formation (Missourian/Virgilian) coals revealed that the higher rank (generally above 0.75% R/sub max/) coals had vein mineral assemblages of sphalerite, twinned calcite, and ferroan dolomite. Lower rank coals had only untwinned calcite. Several sites in Webster County contain various coals (Well (No. 8) to Coiltwon (No. 14)) with vitrinite reflectances up to 0.83% R/sub max/ and associated sphalerite mineralization. Mississippian and Lower Pennsylvanian (Caseyville Formation Gentry coal) coals in the mineralized Fluorspar District have ranks to nearly medium volatile bituminous (1.03% R/sub max/). The regional rank trend exhibited by the fualt zones is generally higher rank than the surrounding areas. Sphalerite mineralization in itself is not unique within Illinois basin coals, but if it was partly responsible for the metamorphism of these coals, then the fluid temperature must have been higher within the above mentioned fault complexes.

Hower, J.C.; Fiene, F.L.; Trinkle, E.J.

1983-09-01T23:59:59.000Z

249

Computer simulation as a NOx reduction design tool  

SciTech Connect (OSTI)

Nalco Mobotec engineers were charged with reducing emissions on a utility boiler converted from burning oil to eastern bituminous coal using the company's Rotamix selective noncatalytic reduction (SNCR) system which injects urea into the furnace. A CFD simulation of the existing boiler was first conducted and then the furnace was simulated with the SNCR system added and the design was optimised. Operating and capital costs were minimised by optimal placement of 50 injector ports. 6 figs., 2 tabs.

Liu, G.; Higgins, B.S. [Nalco Mobotec (United States)

2008-10-15T23:59:59.000Z

250

(c) 2008-2011. Minh Ha-Duong. Rodica Loisel. CIRED Reproduction allowed. share alike. attribution. Blue cells: Numerical assumptions defining the scenario  

E-Print Network [OSTI]

,00 Gt CO2 generated G = g B 4,50 Gt CO2 stored S = s B Carbon dioxide emissions and coal types 2,38 t CO2 generated by t of coal (bituminous grade) Coal Types CO2 emissions 2050 2,101 Gt of coal consumed « Expected fatalities for one wedge of CCS in 2050 » Defines the « wedge of CCS at baseload coal power plants

251

Formation and retention of methane in coal. Final report  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

252

Formation and retention of methane in coal  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

253

Study of catalytic diffusion in coal. Final report for 1983/1984 SOMED Project. [Determination of pore (hole) size and pore shape distribution  

SciTech Connect (OSTI)

The purpose of our studies is to determine the pore (hole) size and pore shape distribution in standard bituminous coal samples from various Alabama coal seams such as that of the Mary Lee, Black Creek and Pratt during and after swelling of the coal with different solvents at various temperatures. These samples come from the Penn State Coal Sample Bank at Pennsylvania State University Coal Research Section and from Alabama's Mineral Industries. Methods have been developed in the laboratory whereby free radical probes of varying sizes can be diffused into the coal under various conditions. These probes can be detected and the environment surrounding the probes can be deduced by electron paramagnetic resonance (EPR) methods. To date, we have found that not only can the shape and size of the pores be determined, but that the size distribution varies from one bituminous coal seam to another, even for coal of the same rank, suggesting a different optimal catalyst should be used for each seam. The effect of oxygen on the coal samples during grinding has been studied; however, the free radical technique appears to be insensitive to the presence of oxygen effects. It is our goal to determine the structural differences between various bituminous coals. 9 references, 9 figures, 1 table.

Kispert, L.D.

1984-09-01T23:59:59.000Z

254

Study of catalytic diffusion in coal. Final report, 1983-1984  

SciTech Connect (OSTI)

The purpose of these studies is to determine the pore (hole) size and pore shape distribution in standard bituminous coal samples from various Alabama coal seams such as that of the Mary Lee, Black Creek and Pratt during and after swelling of the coal with different solvents at various temperatures. These samples come from the Penn State Coal Sample Bank at Pennsylvania State University Coal Research Section and from Alabama's Mineral Industries. Methods were developed in the laboratory whereby free-radical probes of varying sizes can be diffused into the coal under various conditions. These probes can be detected and the environment surrounding the probes can be deduced by electron paramagnetic resonance (EPR) methods. To date, it has been found that not only can the shape and size of the pores be determined, but that the size distribution varies from one bituminous coal seam to another, even for coal of the same rank, suggesting a different optimal catalyst should be used for each seam. The effect of oxygen on the coal samples during grinding has been studied; however, the free radical technique appears to be insensitive to the presence of oxygen effects. The goal is to determine the structural differences between various bituminous coals.

Kispert, L.D.

1984-09-01T23:59:59.000Z

255

Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Pilot-Scale Test Results  

SciTech Connect (OSTI)

This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, ''Field Testing of a Wet FGD Additive.'' The objective of the project is to demonstrate the use of a flue gas desulfurization (FGD) additive, Degussa Corporation's TMT-15, to prevent the reemissions of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate that the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine TMT salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project will conduct pilot and full-scale tests of the TMT-15 additive in wet FGD absorbers. The tests are intended to determine required additive dosage requirements to prevent Hg{sup 0} reemissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Power River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, TXU Generation Company LP, Southern Company, and Degussa Corporation. TXU Generation has provided the Texas lignite/PRB co-fired test site for pilot FGD tests, Monticello Steam Electric Station Unit 3. Southern Company is providing the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot and full-scale jet bubbling reactor (JBR) FGD systems to be tested. A third utility, to be named later, will provide the high-sulfur Eastern bituminous coal full-scale FGD test site. Degussa Corporation is providing the TMT-15 additive and technical support to the test program. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High Sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. This topical report presents the results from the Task 2 and Task 4 pilot-scale additive tests. The Task 3 and Task 5 full-scale additive tests will be conducted later in calendar year 2006.

Gary M. Blythe

2006-03-01T23:59:59.000Z

256

Process for solvent refining of coal using a denitrogenated and dephenolated solvent  

DOE Patents [OSTI]

A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.

Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

1984-01-01T23:59:59.000Z

257

A study of the volatile matter of coal as a function of the heating rate  

SciTech Connect (OSTI)

A study of the volatile matter yields as a function of the heating rate was conducted. A suite of 21 coal and coke samples varying in rank from anthracitic to lignitic and heating rates from 10{degrees}C/min to about 450{degrees}C/min were used in the study. Heating rates up to 60{degrees}C per minute, which are typically used in ASTM Test Method 5142 (instrumental Proximate Analysis), were achieved in a macro thermogravimetric analysis (TGA) system. Heating rates of 50-200{degrees}C/min were obtained in a micro TGA system. All measurements were made in a nitrogen atmosphere. The results of the study illustrate the dependence of the volatile matter yield on the heating rate. For most coals and cokes the optimum heating rate for determining volatile matter values that agree with those obtained by ASTM Method D 3175 appears to be in the 100-150{degrees}C range.

Yanes, E.; Wilhite, D.; Riley, J.M. Jr. [Western Kentucky Univ., Bowling Green, KY (United States)] [and others

1996-12-31T23:59:59.000Z

258

Applications and experiences with super duplex stainless steel in wet FGD scrubber systems  

SciTech Connect (OSTI)

The paper presents the properties of the author`s company`s proprietary super duplex stainless steel. Work is presented showing the development of a more realistic laboratory solution representing typical limestone slurries found in real flue gas desulfurization (FGD) systems. The importance of additions of metal ions such as Fe{sup 3+} and Mn{sup 2+} as well as partially oxidized sulfur species is demonstrated. Results are presented comparing the crevice corrosion resistance of super duplex stainless steel in these slurries with other commonly used wrought and cast stainless steels, for both simulated anthracite and lignite type slurries. Data from loop tests on the erosion resistance of a range of alloys in simulated FGD slurries is presented. The results clearly show the superior resistance of super duplex stainless steel to both crevice corrosion and erosion in FGD slurries. Finally the experiences in UK FGD systems with both cast and wrought super duplex stainless steel are presented.

Francis, R.; Byrne, G.; Warburton, G.; Hebdon, S. [Weir Materials Ltd., Manchester (United Kingdom)

1998-12-31T23:59:59.000Z

259

The relationship between the thermoplastic behavior of blends and their component coals  

SciTech Connect (OSTI)

The thermoplastic behaviors of a number of coking coal blends were measured using proton magnetic resonance thermal analysis (PMRTA) to determine to what extent they were affected by interactions between the component coals. Most blends showed evidence that at temperatures near their temperatures of maximum fluidity the extent to which they fused was different to that expected if the coals did not interact. Only blends of coking coals of different rank fused to a greater extent than expected in the absence of interactions. Semi-anthracite, low rank coals and charcoal reduced the extent of fusion of coking coals to values below those expected if they were acting as inert diluents. These interactions are interpreted as being mediated by transfer of volatile material between the coals on heating.

Sakurovs, R.

1999-07-01T23:59:59.000Z

260

Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995  

SciTech Connect (OSTI)

ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

NONE

1998-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS  

SciTech Connect (OSTI)

Low rank fuels such as subbituminous coals and lignites contain significant amounts of moisture compared to higher rank coals. Typically, the moisture content of subbituminous coals ranges from 15 to 30 percent, while that for lignites is between 25 and 40 percent, where both are expressed on a wet coal basis. High fuel moisture has several adverse impacts on the operation of a pulverized coal generating unit. High fuel moisture results in fuel handling problems, and it affects heat rate, mass rate (tonnage) of emissions, and the consumption of water needed for evaporative cooling. This project deals with lignite and subbituminous coal-fired pulverized coal power plants, which are cooled by evaporative cooling towers. In particular, the project involves use of power plant waste heat to partially dry the coal before it is fed to the pulverizers. Done in a proper way, coal drying will reduce cooling tower makeup water requirements and also provide heat rate and emissions benefits. The technology addressed in this project makes use of the hot circulating cooling water leaving the condenser to heat the air used for drying the coal (Figure 1). The temperature of the circulating water leaving the condenser is usually about 49 C (120 F), and this can be used to produce an air stream at approximately 43 C (110 F). Figure 2 shows a variation of this approach, in which coal drying would be accomplished by both warm air, passing through the dryer, and a flow of hot circulating cooling water, passing through a heat exchanger located in the dryer. Higher temperature drying can be accomplished if hot flue gas from the boiler or extracted steam from the turbine cycle is used to supplement the thermal energy obtained from the circulating cooling water. Various options such as these are being examined in this investigation. This is the eleventh Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report.

Edward Levy

2005-10-01T23:59:59.000Z

262

Cooperative research in coal liquefaction. Final report, May 1, 1992--April 30, 1993  

SciTech Connect (OSTI)

Research on sulfate and metal (Mo, Sn) promoted Fe{sub 2}O{sub 3} catalysts in the current year focused on optimization of conditions. Parameters varied included temperature, solvent, solvent-to-coal ratio, and the effect of presulfiding versus in situ sulfiding. Oil yields were found to increase approximately proportionately with both temperature and solvent-to-coal ratio. The donor solvent, tetralin, proved to give better total conversion and oil yields than either 1-methylnaphthalene or Wilsonville recycle oil. A significant enhancement of both total liquefaction yields and oil yields from lignites and subbituminous coals has been achieved by incorporating iron into the coal matrix by cation exchange. A study has been conducted on the synthesis of iron, molybdenum, and tungsten catalysts using a laser pyrolysis technique.

Huffman, G.P. [ed.

1996-03-01T23:59:59.000Z

263

Coprocessing of Highvale coal with Athabasca bitumen in syngas mixtures  

SciTech Connect (OSTI)

Coprocessing of Alberta subbituminous coal with bitumen is currently under investigation at the Alberta Research Council. The high oxygen content of the coal results in high hydrogen consumption. The present study compares the effectiveness of syngas/water mixtures catalyzed by potassium carbonate for coprocessing Highvale coal with Athabasca bitumen. Single-stage (solubilization) experiments were performed with syngas (5.1 MPa) at 390/sup 0/C in a stirred autoclave. In simulated two-stage experiments, the second (upgrading) stage employed hydrogen (8.5 MPa) at 440/sup 0/C with a potassium molybdate/dimethyl disulphide catalyst. Coal conversion improved from 47 to 78% systematically when the carbon monoxide: hydrogen ratio was varied from 1:3 to 7:1. The additional yield was confined to pyridine extractable material. In simulated two-stage experiments similar coal conversions were observed when using carbon monoxide/water (91%) or hydrogen (88%) in the first stage.

Parker, R.J.; Clark, P.D.; Ignasiak, B.L.; Lee, T.; Ohuchi, T.

1986-04-01T23:59:59.000Z

264

Large-block experiments in underground coal gasification  

SciTech Connect (OSTI)

A major objective of the nation's energy program is to develop processes for cleanly producing fuels from coal. One of the more promising of these is underground coal gasification (UCG). If successful, UCG would quadruple recoverable U.S. coal reserves. Under the sponsorship of the Department of Energy (DOE), Lawrence Livermore National Laboratory (LLNL) performed an early series of UCG field experiments from 1976 through 1979. The Hoe Creek series of tests were designed to develop the basic technology of UCG at low cost. The experiments were conducted in a 7.6-m thick subbituminous coal seam at a relatively shallow depth of 48 m at a site near Gillette, Wyoming. On the basis of the Hoe Creek results, more extensive field experiments were designed to establish the feasibility of UCG for commercial gas production under a variety of gasification conditions. Concepts and practices in UCG are described, and results of the field tests are summarized.

Not Available

1982-11-01T23:59:59.000Z

265

Low-rank coal study: national needs for resource development. Volume 3. Technology evaluation  

SciTech Connect (OSTI)

Technologies applicable to the development and use of low-rank coals are analyzed in order to identify specific needs for research, development, and demonstration (RD and D). Major sections of the report address the following technologies: extraction; transportation; preparation, handling and storage; conventional combustion and environmental control technology; gasification; liquefaction; and pyrolysis. Each of these sections contains an introduction and summary of the key issues with regard to subbituminous coal and lignite; description of all relevant technology, both existing and under development; a description of related environmental control technology; an evaluation of the effects of low-rank coal properties on the technology; and summaries of current commercial status of the technology and/or current RD and D projects relevant to low-rank coals.

Not Available

1980-11-01T23:59:59.000Z

266

Power Systems Development Facility Gasification Test Campaing TC14  

SciTech Connect (OSTI)

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details test campaign TC14 of the PSDF gasification process. TC14 began on February 16, 2004, and lasted until February 28, 2004, accumulating 214 hours of operation using Powder River Basin (PRB) subbituminous coal. The gasifier operating temperatures varied from 1760 to 1810 F at pressures from 188 to 212 psig during steady air blown operations and approximately 160 psig during oxygen blown operations.

Southern Company Services

2004-02-28T23:59:59.000Z

267

Development of fireside performance indices - task 8. Topical report, March 1996  

SciTech Connect (OSTI)

The primary goal of the Fireside Performance Indices (FPI) research project at the Energy & Environmental Research Center (EERC) was to develop a series of indices to reliably predict the fireside performance of subbituminous coals in utility boilers. Individual utilities must respond quickly and effectively to changing fuel markets because of competition within the U.S. coal-fired power industry. Spot-market purchases of coal have become commonplace. The economics associated with sulfur emissions control have caused many utilities to use Powder River Basin (PRB) subbituminous coals. The PRB coals usually provide a lower-cost, medium-heating-value, low-sulfur fuel option. Although these coals possess similar overall or bulk compositional properties, their fireside performance characteristics vary considerably within a given boiler. Consequently, bulk compositional parameters and, hence, conventional indices such as the base-to-acid ratio, stagging factor, and fouling factor are inappropriate for predicting the fireside performance of PRB coals. The development of the computer-controlled scanning electron microscopy (CCSEM) and chemical fractionation methods, however, has enabled a more thorough characterization of the inorganic constituents of PRB, coals that contribute to the following adverse operational effects: stagging, fouling, opacity, erosion and poor grindability, slag tapping, and sootblower performance. Eight predictive indices have been developed based primarily on CCSEM and chemical fractionation analysis parameters to predict the propensity of a given coal or coal blend to cause operational problems. The indices were formulated using bench-, pilot-, and full-scale combustion testing data from previous research projects combined with bench-scale data from this project to identify the primary coal inorganic properties that cause ash-related problems in utility boilers.

NONE

1995-11-01T23:59:59.000Z

268

Risk Assessment and Monitoring of Stored CO2 in Organic Rocks Under Non-Equilibrium Conditions  

SciTech Connect (OSTI)

The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However. the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ? T ? 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (? 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and shale cores, which were pressurized with high pressure CO2, determine the fate of sequestered CO2 in these cores. Our results suggested that Illinois bituminous coal in its unperturbed state, i.e., when not pressurized with CO2, showed large variations in the mechanical properties. Modulus varied from 0.7 GPa to 3.4 GPa even though samples were extracted from a single large chunk of coal. We did not observe any glass transition for Illinois bituminous coal at - 100oC ? T ? 300oC, however, when the coal was pressurized with CO2 at ambient ? P ? 20.7 MPa, the viscosity of the coal decreased and inversely scaled with the CO2 pressure. The decrease in viscosity as a function of pressure could pose CO2 injection problems for coal as lower viscosity would allow the solid coal to flow to plug the fractures, fissures, and cleats. Our experiments also showed a very small fraction of CO2 was absorbed in coal; and when CO2 pressurized coals were exposed to atmospheric conditions, the loss of CO2 from coals was massive. Half of the sequestered gas from the coal cores was lost in less than 20 minutes. Our shockwave experiments on Illinois bituminous coal, New Albany shale (Illinois), Devonian shale (Ohio), and Utica shale (Ohio) presented clear evidence that the significant emission of the sequestered CO2 from these formations cannot be discounted during seismic activity, especially if caprock is compromised. It is argued that additional shockwave studies, both compressive and transverse, would be required for successfully mapping the risks associated with sequestering high pressure CO2 in coal and shale formations.

Malhotra, Vivak

2014-06-30T23:59:59.000Z

269

Coal combustion under conditions of blast furnace injection  

SciTech Connect (OSTI)

Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal with particular reference to the coals from the Illinois Basin. Although this research is not yet completed the results to date support the following conclusions: (1) based on the results of computer modeling, lower rank bituminous coals, including coal from the Illinois Basin, compare well in their injection properties with a variety of other bituminous coals, although the replacement ratio improves with increasing rank; (2) based on the results of petrographic analysis of material collected from an active blast furnace, it is clear the coal derived char is entering into the raceway of the blast furnace; (3) the results of reactivity experiments on a variety of coal chars at a variety of reaction temperatures show that lower rank bituminous coals, including coal from the Illinois basin, yield chars with significantly higher reactivities in both air and CO{sub 2} than chars from higher rank Appalachian coals and blast furnace coke. These results indicate that the chars from the lower rank coals should have a superior burnout rate in the tuyere and should survive in the raceway environment for a shorter time. These coals, therefore, will have important advantages at high rates of injection that may overcome their slightly lower replacement rates.

Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

1995-12-01T23:59:59.000Z

270

Investigate the effectivness of calcium-treated coals in the capture of sulfur gases generated in staged fired combustors. Third quarterly technical progress report, May 1-July 31, 1983  

SciTech Connect (OSTI)

In this quarter's work, a new procedure was developed to add calcium to pulverized coal. The method has been found to increase the calcium content of bituminous coal to 12% calcium by weight, which corresponds to a Ca/S ratio of greater than 2. Progress was also made on the combustion test facility this quarter. A new modification of the low-flow coal feeder has made that system steady and reliable. With the furnace wired and plumbed, and the other subsystems complete, the facility is almost ready to burn the treated coals.

Porter, J. H.; Manning, M. P.; Benedek, K. R.; Sharma, P. K.

1983-09-01T23:59:59.000Z

271

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale combustion tests with caking bituminous coal has stopped. This stoppage has come about due to limitations in current funding available to continue large scale research and development activities at Riley's Commercial Burner Test Facility (CBTF) of the PC Preheat technology. The CBTF was secured and decommissioned in the previous quarter; work this quarter has focused on disposition of PC Preheat experimental equipment at the CBTF as well as methods for disposal of about 100 tons of residual PRB test coal in storage. GTI was granted a no-cost time extension through September 2005; a final report is due in December 2005.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2005-06-30T23:59:59.000Z

272

Petrographic characterization of economizer fly ash  

SciTech Connect (OSTI)

Policies for reducing NOx emissions have led power plants to restrict O{sub 2}, resulting in high-carbon fly ash production. Therefore, some potentially useful fly ash, such as the economizer fly ash, is discarded without a thorough knowledge of its composition. In order to characterize this type of fly ash, samples were collected from the economizer Portuguese power plant burning two low-sulfur bituminous coals. Characterization was also performed on economizer fly ash subsamples after wet sieving, density and magnetic separation. Analysis included atomic absorption spectroscopy, loss-on-ignition, scanning electron microscopy/energy-dispersive X-ray spectroscopy, optical microscopy, and micro-Raman spectroscopy.

Valentim, B.; Hower, J.C.; Soares, S.; Guedes, A.; Garcia, C.; Flores, D.; Oliveira, A. [University of Porto, Oporto (Portugal). Center of Geology

2009-11-15T23:59:59.000Z

273

System studies guiding fossil energy RD & D  

SciTech Connect (OSTI)

The article describes the following recently completed studies, all of which may be accessed on NETL's website: http://netl.doe.gov/energy-analyses/ref-shelf.html: Cost and performance baseline for fossil energy power plants - volume 1: bituminous coal and natural gas to electricity (May 2007); Increasing security and reducing carbon emissions of the US transportation sector: a transformational role for coal with biomass (August 2007); Industrial size gasification for syngas, substitute natural gas, and power production (April 2007); and Carbon dioxide capture from existing coal-fired power plants (December 2006). 2 figs.

NONE

2007-12-31T23:59:59.000Z

274

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents [OSTI]

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

Rashid Khan, M.

1988-05-05T23:59:59.000Z

275

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents [OSTI]

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

Khan, M. Rashid (Morgantown, WV)

1989-01-01T23:59:59.000Z

276

Assessment of solid-waste characteristics and control technology for oil-shale retorting. Final report for September 1983-February 1985  

SciTech Connect (OSTI)

The report presents information on oil-shale deposits in the eastern and western parts of the United States, their geological subdivisions, locations, tonnage, and physical and chemical characteristics. Characteristics of solid and liquid wastes produced from various oil-shale-processing technologies and control methods are presented. Also included are results from an experimental study to construct liners and covers for disposal of spent shale. A compilation of available data on the auto-ignition potential of raw and spent shales indicates a similarity between raw-shale fines and bituminous coals.

Agarwal, A.K.

1986-05-01T23:59:59.000Z

277

Emissions mitigation of blended coals through systems optimization  

SciTech Connect (OSTI)

For coal fired power stations, such as those located in the US, that have installed NOx and SOx emissions abatement equipment substantial carbon dioxide reduction could be achieved by shifting from pure PRB coal to blended coals with local bituminous coal. Don Labbe explains how. The article is based on a presentation at Power-Gen Asia 2009, which takes place 7-9 October in Bangkok, Thailand and an ISA POWID 2009 paper (19th Annual Joint ISA POWID/EPRI Controlls and Instrumentation Conference, Chicago, Illinois, May 2009). 4 refs., 3 figs.

Don Labbe [IOM Invensys Operations Management (United States)

2009-10-15T23:59:59.000Z

278

Radioactive waste treatment technologies and environment  

SciTech Connect (OSTI)

The radioactive waste treatment and conditioning are the most important steps in radioactive waste management. At the Slovak Electric, plc, a range of technologies are used for the processing of radioactive waste into a form suitable for disposal in near surface repository. These technologies operated by JAVYS, PLc. Nuclear and Decommissioning Company, PLc. Jaslovske Bohunice are described. Main accent is given to the Bohunice Radwaste Treatment and Conditioning Centre, Bituminization plant, Vitrification plant, and Near surface repository of radioactive waste in Mochovce and their operation. Conclusions to safe and effective management of radioactive waste in the Slovak Republic are presented. (authors)

HORVATH, Jan; KRASNY, Dusan [JAVYS, PLc. - Nuclear and Decommisioning Company, PLc. (Slovakia)

2007-07-01T23:59:59.000Z

279

CO2 Sequestration in Unmineable Coal Seams: Potential Environmental Impacts  

SciTech Connect (OSTI)

An initial investigation into the potential environmental impacts of CO2 sequestration in unmineable coal seams has been conducted, focusing on changes in the produced water during enhanced coalbed methane (ECBM) production using a CO2 injection process (CO2-ECBM). Two coals have been used in this study, the medium volatile bituminous Upper Freeport coal (APCS 1) of the Argonne Premium Coal Samples series, and an as-mined Pittsburgh #8 coal, which is a high volatile bituminous coal. Coal samples were reacted with either synthetic produced water or field collected produced water and gaseous carbon dioxide at 40 ?C and 50 bar to evaluate the potential for mobilizing toxic metals during CO2-ECBM/sequestration. Microscopic and x-ray diffraction analysis of the post-reaction coal samples clearly show evidence of chemical reaction, and chemical analysis of the produced water shows substantial changes in composition. These results suggest that changes to the produced water chemistry and the potential for mobilizing toxic trace elements from coalbeds are important factors to be considered when evaluating deep, unmineable coal seams for CO2 sequestration.

Hedges, S.W.; Soong, Yee; McCarthy Jones, J.R.; Harrison, D.K.; Irdi, G.A.; Frommell, E.A.; Dilmore, R.M.; Pique, P.J.; Brown, T.D

2005-09-01T23:59:59.000Z

280

Petrology of the Devonian gas-bearing shale along Lake Erie helps explain gas shows  

SciTech Connect (OSTI)

Comprehensive petrologic study of 136 thin sections of the Ohio Shale along Lake Erie, when combined with detailed stratigraphic study, helps explain the occurrence of its gas shows, most of which occur in the silty, greenish-gray, organic poor Chagrin Shale and Three Lick Bed. Both have thicker siltstone laminae and more siltstone beds than other members of the Ohio Shale and both units also contain more clayshales. The source of the gas in the Chagrin Shale and Three Lick Bed of the Ohio Shale is believed to be the bituminous-rich shales of the middle and lower parts of the underlying Huron Member of the Ohio Shale. Eleven petrographic types were recognized and extended descriptions are provided of the major ones - claystones, clayshales, mudshales, and bituminous shales plus laminated and unlaminated siltstones and very minor marlstones and sandstones. In addition three major types of lamination were identified and studied. Thirty-two shale samples were analyzed for organic carbon, whole rock hydrogen and whole rock nitrogen with a Perkin-Elmer 240 Elemental Analyzer and provided the data base for source rock evaluation of the Ohio Shale.

Broadhead, R.F.; Potter, P.E.

1980-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

The Self-Ignition Temperatures of Bitumen Mixtures Containing Transition Metal Nitrates  

SciTech Connect (OSTI)

Information is provided on the self-ignition temperature (SIT) of blown bitumen asphalt mixed with sodium nitrate and some chemicals that are added in the bituminization process to adjust pH and to immobilize the radioactive isotopes of Cs, Sr, and I. In each ignition temperature test, the prepared bitumen sample was heated at a constant rate of temperature increase, and the ignition point was measured. Among the tested chemicals added to the bitumen, Ni(NO{sub 3}){sub 2} shows a relatively large SIT decrease, and furthermore, the mixture of Ni(NO{sub 3}){sub 2} and AgNO{sub 3} has been shown to greatly lower the SIT of blown bitumen. It is suggested that, in general, segregation of these nitrates should be avoided in bituminization, and care should be taken in handling Ag in a Purex reprocessing plant from the viewpoint of waste treatment. Furthermore, the oxidation effects of Fe(NO{sub 3}){sub 3} were tested by measuring torque of the bitumen sample. It was confirmed that the addition of Fe(NO{sub 3}){sub 3} to bitumen rapidly oxidizes the bitumen and increases the viscosity of the bitumen mixture.

Okada, Ken; Nomura, Masao; Fujii, Yasuhiko [Tokyo Institute of Technology (Japan)

2000-01-15T23:59:59.000Z

282

Coal rank trends in western Kentucky coal field and relationship to hydrocarbon occurrence  

SciTech Connect (OSTI)

Extensive oil and gas development has occurred in the high volatile C bituminous region north of the Rough Creek fault zone, but few pools are known within the Webster syncline south of the fault zone. The rank of the Middle Pennsylvanian coals can be used to estimate the level of maturation of the Devonian New Albany Shale, a likely source rock for much of the oil and gas in the coal field. Based on relatively few data points, previous studies on the maturation of the New Albany Shale, which lies about 1 km below the Springfield coal, indicate an equivalent medium volatile bituminous (1.0-1.2% R{sub max}) rank in the Fluorspar district. New Albany rank decreases to an equivalent high volatile B/C (0.6% R{sub max}) north of the Rough Creek fault zone. Whereas the shale in the latter region is situated within the oil generation window, the higher rank region is past the peak of the level of maturation of the New Albany Shale. The significance of the New Albany reflectancy is dependent on the suppression of vitrinite reflectance in organic-rich shales. The possibility of reflectance suppression would imply that the shales could be more mature than studies have indicated.

Hower, J.C.; Rimmer, S.M.; Williams, D.A.; Beard, J.G. (Univ. of Kentucky, Lexington (USA))

1989-09-01T23:59:59.000Z

283

Field Testing of a Wet FGD Additive for Enhanced Mercury Control  

SciTech Connect (OSTI)

This document is the final report for DOE-NETL Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project has been to demonstrate the use of two flue gas desulfurization (FGD) additives, Evonik Degussa Corporation's TMT-15 and Nalco Company's Nalco 8034, to prevent the re-emission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project was intended to demonstrate whether such additives can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project involved pilot- and full-scale tests of the additives in wet FGD absorbers. The tests were intended to determine required additive dosages to prevent Hg{sup 0} re-emissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Powder River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, Luminant Power (was TXU Generation Company LP), Southern Company, IPL (an AES company), Evonik Degussa Corporation and the Nalco Company. Luminant Power provided the Texas lignite/PRB co-fired test site for pilot FGD tests and project cost sharing. Southern Company provided the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, the pilot- and full-scale jet bubbling reactor (JBR) FGD systems tested, and project cost sharing. IPL provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Evonik Degussa Corporation provided the TMT-15 additive, and the Nalco Company provided the Nalco 8034 additive. Both companies also supplied technical support to the test program as in-kind cost sharing. The project was conducted in six tasks. Of the six tasks, Task 1 involved project planning and Task 6 involved management and reporting. The other four tasks involved field testing on FGD systems, either at pilot or full scale. These four tasks included: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High-sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Plant Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. The pilot-scale tests were completed in 2005 and the full-scale test using high-sulfur coal was completed in 2006; only the TMT-15 additive was tested in these efforts. The Task 5 full-scale additive tests conducted at Southern Company's Plant Yates Unit 1 were completed in 2007, and both the TMT-15 and Nalco 8034 additives were tested.

Gary Blythe; MariJon Owens

2007-12-31T23:59:59.000Z

284

Feasible experimental study on the utilization of a 300 MW CFB boiler desulfurizating bottom ash for construction applications  

SciTech Connect (OSTI)

CFB boiler ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. The disposal in landfills has been the most common means of handling ash in circulating fluidized bed boiler power plants. However for a 300 MW CFB boiler power plant, there will be 600,000 tons of ash discharged per year and will result in great volumes and disposal cost of ash byproduct. It was very necessary to solve the utilization of CFB ash and to decrease the disposal cost of CFB ash. The feasible experimental study results on the utilization of the bottom ashes of a 300 MW CFB boiler in Baima power plant in China were reported in this paper. The bottom ashes used for test came from the discharged bottom ashes in a 100 MW CFB boiler in which the anthracite and limestone designed for the 300 MW CFB project was burned. The results of this study showed that the bottom ash could be used for cementitious material, road concrete, and road base material. The masonry cements, road concrete with 30 MPa compressive strength and 4.0 MPa flexural strength, and the road base material used for base courses of the expressway, the main road and the minor lane were all prepared with milled CFB bottom ashes in the lab. The better methods of utilization of the bottom ashes were discussed in this paper.

Lu, X.F.; Amano, R.S. [University of Wisconsin, Milwaukee, WI (United States). Dept. of Mechanical Engineering

2006-12-15T23:59:59.000Z

285

Optimization of the process of plasma ignition of coal  

SciTech Connect (OSTI)

Results are given of experimental and theoretical investigations of plasma ignition of coal as a result of its thermochemical preparation in application to the processes of firing up a boiler and stabilizing the flame combustion. The experimental test bed with a commercial-scale burner is used for determining the conditions of plasma ignition of low-reactivity high-ash anthracite depending on the concentration of coal in the air mixture and velocity of the latter. The calculations produce an equation (important from the standpoint of practical applications) for determining the energy expenditure for plasma ignition of coal depending on the basic process parameters. The tests reveal the difficulties arising in firing up a boiler with direct delivery of pulverized coal from the mill to furnace. A scheme is suggested, which enables one to reduce the energy expenditure for ignition of coal and improve the reliability of the process of firing up such a boiler. Results are given of calculation of plasma thermochemical preparation of coal under conditions of lower concentration of oxygen in the air mixture.

Peregudov, V.S. [Russian Academy of Sciences, Novosibirsk (Russian Federation)

2009-04-15T23:59:59.000Z

286

Data base for the analysis of compositional characteristics of coal seams and macerals. Final report. Part 2. A multivariate study of the interrelationships among selected variables of the organic fraction of samples of United States' coals  

SciTech Connect (OSTI)

Multivariate statistical techniques have been applied to study interrelationships among 12 variables within a set of 277 coals representing whole-seam channel, column, and core samples obtained from each of the 6 coal provinces of the United States, and varying in rank from lignite through anthracite. The data are maintained in computerized data base at The Pennsylvania State University Coal Research Section. The variables selected are components of the elemental analysis (carbon, oxygen, organic sulfur, hydrogen, and nitrogen), selected components of the proximate analysis (volatile matter and moisture), calorific value, reflectance of vitrinite, and the relative proportions of the 3 maceral groups (total vitrinite, inertinite, and liptinite group macerals). Faactor analyses performed on the entire data set and on subsets separated on the basis of rank, geographic location, and by cluster analysis indicated that rank is the most important factor in determining the amount of variation of each data set. The rank-dependent variables for the entire data set are carbon, reflectance, oxygen, volatile matter, calorific value, and moisture. The maceral groups account for the next greatest source of variation. Organic sulfur is independent of the first 2 factors and is the third most important source of variation. Cluster analyses indicated that the most significant partitioning produces 4 groups which are differentiated primarily on the basis of rank, maceral composition, and organic sulfur content. Factor analyses of the individual groups provide insights into the coalification processes of these more homogeneous coal associations.

Gerencher, J.J. Jr.

1983-01-01T23:59:59.000Z

287

Role of microbial iron reduction in the dissolution of iron hydroxysulfate minerals - article no. G01012  

SciTech Connect (OSTI)

Reduction of structural sulfate in the iron-hydroxysulfate mineral jarosite by sulfate-reducing bacteria has previously been demonstrated. The primary objective of this work was to evaluate the potential for anaerobic dissolution of the iron-hydroxysulfate minerals jarosite and schwertmannite at neutral pH by iron-reducing bacteria. Mineral dissolution was tested using a long-term cultivar, Geobacter metallireducens strain GS-15, and a fresh isolate Geobacter sp. strain ENN1, previously undescribed. ENN1 was isolated from the discharge site of Shadle Mine, in the southern anthracite coalfield of Pennsylvania, where schwertmannite was the predominant iron-hydroxysulfate mineral. When jarosite from Elizabeth Mine (Vermont) was provided as the sole terminal electron acceptor, resting cells of both G. metallireducens and ENN1 were able to reduce structural Fe(III), releasing Fe{sup +2}, SO{sub 4}{sup -2}, and K{sup +} ions. A lithified jarosite sample from Utah was more resistant to microbial attack, but slow release of Fe{sup +2} was observed. Neither bacterium released Fe{sup +2} from poorly crystalline synthetic schwertmannite. Our results indicate that exposure of jarosite to iron-reducing conditions at neutral pH is likely to promote the mobility of hazardous constituents and should therefore be considered in evaluating waste disposal and/or reclamation options involving jarosite-bearing materials.

Jones, E.J.P.; Nadeau, T.L.; Voytek, M.A.; Landa, E.R. [US Geological Survey, Reston, VA (United States)

2006-03-28T23:59:59.000Z

288

Technical support to the Solvent Refined Coal (SRC) demonstration projects: assessment of current research and development  

SciTech Connect (OSTI)

A program to demonstrate Solvent Refined Coal (SRC) technology has been initiated by the US Department of Energy (DOE) in partnership with two industrial groups. Project management responsibility has been assigned to the Oak Ridge Operations Office (ORO) of DOE. ORO requested that the Oak Ridge National Laboratory assess current research and development (R and D) activities and develop recommendations for those activities that might contribute to successful completion of the SRC demonstration plant projects. The objectives of this final report are to discuss in detail the problem areas in SRC; to discuss the current and planned R and D investigations relevant to the problems identified; and to suggest appropriate R and D activities in support of designs for the SRC demonstration plants. Four types of R and D activities are suggested: continuation of present and planned activities; coordination of activities and results, present and proposed; extension/redirection of activities not involving major equipment purchase or modifications; and new activities. Important examples of the first type of activity include continuation of fired heater, slurry rheology, and slurry mixing studies at Ft. Lewis. Among the second type of activity, coordination of data acquisition and interpretation is recommended in the areas of heat transfer, vapor/liquid equilibria, and physical properties. Principal examples of recommendations for extension/redirection include screening studies at laboratory scale on the use of carbonaceous precoat (e.g., anthracite) infiltration, and 15- to 30-day continuous tests of the Texaco gasifier at the Texaco Montebello facility (using SRC residues).

Edwards, M.S.; Rodgers, B.R.; Brown, C.H.; Carlson, P.K.; Gambill, W.R.; Gilliam, T.M.; Holmes, J.M.; Krishnan, R.P.; Parsly, L.F.

1980-12-01T23:59:59.000Z

289

Far- and mid-infrared spectroscopy of complex organic matter of astrochemical interest: coal, heavy petroleum fractions, and asphaltenes  

E-Print Network [OSTI]

The coexistence of a large variety of molecular species (i.e., aromatic, cycloaliphatic and aliphatic) in several astrophysical environments suggests that unidentified IR emission (UIE) occurs from small solid particles containing a mix of aromatic and aliphatic structures (e.g., coal, petroleum, etc.), renewing the astronomical interest on this type of materials. A series of heavy petroleum fractions namely DAE, RAE, BQ-1, and asphaltenes derived from BQ-1 were used together with anthracite coal and bitumen as model compounds in matching the band pattern of the emission features of proto-planetary nebulae (PPNe). All the model materials were examined in the mid-infrared (2.5-16.7 um) and for the first time in the far-infrared (16.7-200 um), and the IR bands were compared with the UIE from PPNe. The best match of the PPNe band pattern is offered by the BQ-1 heavy aromatic oil fraction and by its asphaltenes fraction. Particularly interesting is the ability of BQ-1 to match the band pattern of the aromatic-ali...

Cataldo, F; Manchado, A

2012-01-01T23:59:59.000Z

290

Opportunities for coal to methanol conversion  

SciTech Connect (OSTI)

The accumulations of mining residues in the anthracite coal regions of Pennsylvania offer a unique opportunity to convert the coal content into methanol that could be utilized in that area as an alternative to gasoline or to extend the supplies through blending. Additional demand may develop through the requirements of public utility gas turbines located in that region. The cost to run this refuse through coal preparation plants may result in a clean coal at about $17.00 per ton. After gasification and synthesis in a 5000 ton per day facility, a cost of methanol of approximately $3.84 per million Btu is obtained using utility financing. If the coal is to be brought in by truck or rail from a distance of approximately 60 miles, the cost of methanol would range between $4.64 and $5.50 per million Btu depending upon the mode of transportation. The distribution costs to move the methanol from the synthesis plant to the pump could add, at a minimum, $2.36 per million Btu to the cost. In total, the delivered cost at the pump for methanol produced from coal mining wastes could range between $6.20 and $7.86 per million Btu.

Not Available

1980-04-01T23:59:59.000Z

291

Enhancing Carbon Reactivity in Mercury Control in Lignite-Fired Systems  

SciTech Connect (OSTI)

This project was awarded through the U.S. Department of Energy (DOE) National Energy Technology Laboratory Program Solicitation DE-PS26-03NT41718-01. The Energy & Environmental Research Center (EERC) led a consortium-based effort to resolve mercury (Hg) control issues facing the lignite industry. The EERC team-the Electric Power Research Institute (EPRI); the URS Corporation; the Babcock & Wilcox Company; ADA-ES; Apogee; Basin Electric Power Cooperative; Otter Tail Power Company; Great River Energy; Texas Utilities; Montana-Dakota Utilities Co.; Minnkota Power Cooperative, Inc.; BNI Coal Ltd.; Dakota Westmoreland Corporation; the North American Coal Corporation; SaskPower; and the North Dakota Industrial Commission-demonstrated technologies that substantially enhanced the effectiveness of carbon sorbents to remove Hg from western fuel combustion gases and achieve a high level ({ge} 55% Hg removal) of cost-effective control. The results of this effort are applicable to virtually all utilities burning lignite and subbituminous coals in the United States and Canada. The enhancement processes were previously proven in pilot-scale and limited full-scale tests. Additional optimization testing continues on these enhancements. These four units included three lignite-fired units: Leland Olds Station Unit 1 (LOS1) and Stanton Station Unit 10 (SS10) near Stanton and Antelope Valley Station Unit 1 (AVS1) near Beulah and a subbituminous Powder River Basin (PRB)-fired unit: Stanton Station Unit 1 (SS1). This project was one of three conducted by the consortium under the DOE mercury program to systematically test Hg control technologies available for utilities burning lignite. The overall objective of the three projects was to field-test and verify options that may be applied cost-effectively by the lignite industry to reduce Hg emissions. The EERC, URS, and other team members tested sorbent injection technologies for plants equipped with electrostatic precipitators (ESPs) and spray dryer absorbers combined with fabric filters (SDAs-FFs). The work focused on technology commercialization by involving industry and emphasizing the communication of results to vendors and utilities throughout the project.

Chad Wocken; Michael Holmes; John Pavlish; Jeffrey Thompson; Katie Brandt; Brandon Pavlish; Dennis Laudal; Kevin Galbreath; Michelle Olderbak

2008-06-30T23:59:59.000Z

292

Enzymantic Conversion of Coal to Liquid Fuels  

SciTech Connect (OSTI)

The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time, corresponding to the consumption of aromatic intermediates as they undergo ring cleavage. The results show that this process happens within 1 hour when using extracellular enzymes, but takes several days when using live organisms. In addition, live organisms require specific culture conditions, control of contaminants and fungicides in order to effectively produce extracellular enzymes that degrade coal. Therefore, when comparing the two enzymatic methods, results show that the process of using extracellular lignin degrading enzymes, such as laccase and manganese peroxidase, appears to be a more efficient method of decomposing bituminous coal.

Richard Troiano

2011-01-31T23:59:59.000Z

293

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

Large-scale combustion tests with caking bituminous coal has stopped. This stoppage has come about due to limitations in current funding available to continue large scale research and development activities at Riley Power's Commercial Burner Test Facility (CBTF) of the PC Preheat technology. The CBTF was secured and decommissioned in the previous quarter; work this quarter work completed the securing the proper disposition of all PC Preheat experimental equipment at the PSCF and CBTF and completing negotiations with AES Westover (a power plant in Johnson City, New York) to accept 130 tons of residual PRB test coal in storage. The coal transport to Westover occurred at the end of August. GTI was granted a no-cost time extension through September 2005; immediate efforts are focused on completing a draft final report, which is due in October 31, 2005 and the final report in December.

Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2005-09-30T23:59:59.000Z

294

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

Kenneth E. Baldrey

2003-01-01T23:59:59.000Z

295

Evaluation and demonstration of the chemically active fluid bed. Final report May 75-Jul 81  

SciTech Connect (OSTI)

The report gives results of the operation of a 17-MW Chemically Active Fluid Bed (CAFB) demonstration unit, retrofitted to a natural gas boiler. The CAFB process gasifies high-sulfur, high-metals-content liquid and solid fuels. Residual oil, lignite, and bituminous coal were gasified separately or together between November 1979 and June 1981. Design and operational areas where upgrading would be beneficial were identified. Continuous monitors were used to measure boiler flue gas emissions of SO2, NOx, CO, oxygen, CO2, and opacity. Periodic manual emission tests were conducted for particulate, SO2, and NOx, using EPA reference methods. Emissions of these three criteria pollutants were generally lower than New Source Performance Standards for utility boilers, although occasionally excessive particulate and SO2 emissions were observed. NOx emissions were consistently lower than those from natural gas combustion. Results of detailed chemical analyses and biological assays are reported.

Sommer, R.E.; Werner, A.S.; Kowszun, Z.

1984-02-01T23:59:59.000Z

296

On the natural radionuclides distribution in Romanian coals of different type and rank  

SciTech Connect (OSTI)

The paper presents the natural radionuclides distribution in the Romanian coals of different type and rank, from peats to bituminous coals, in comparison with their concentrations in the sedimentary metamorphic rocks. Discussions are carried out on the following principal elements that include the natural radioactive isotopes: K, La, Sm, Lu, Re and the natural radioactive families of U, Ra, and Th. The stable microelements ppm in the coals were investigated by the Instrumental Neutron Activation Analysis (INAA), carried out at the VVRS 2 Reactor of the Atomic Physics Institute of Bucharest (Romania), as well as by UV spectral analysis. They have indicated a maximum concentration of these elements in the lignites. It must be outlined that the peats have the lowest concentration of these elements, taking into account the ionic exchange possibility into the peat beds. The concentration of the macro- and microelements included in the metamorphic rocks and in the terrestrial crust as a whole is compared with obtained results.

Georgescu, I.I.; Barca, F.; Panaitescu, C. [Univ. Politehnica Bucharest (Romania)

1995-12-31T23:59:59.000Z

297

Characterization of air toxics from a laboratory coal-fired combustor  

SciTech Connect (OSTI)

Emissions of hazardous air pollutants from coal combustion were studied in a laboratory-scale combustion facility, with emphasis on fine particles in three size ranges of less than 7.5 {mu}m diameter. Vapors were also measured. Substances under study included organic compounds, anions, elements, and radionuclides. Fly ash was generated by firing a bituminous coal in a combuster for 40 h at each of two coal feed rates. Flue gas was sampled under two conditions. Results for organic compounds, anions, and elements show a dependence on particle size consistent with published power plant data. Accumulation of material onto surface layers was inferred from differences in chemical composition between the plume simulating dilution sampler and hot flue samples. Extracts of organic particulate material were fractionated into different polarity fractions and analyzed by GC/MS. In Phase II, these laboratory results will be compared to emissions from a full-scale power plant burning the same coal.

NONE

1995-04-03T23:59:59.000Z

298

Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process  

SciTech Connect (OSTI)

This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

1981-06-01T23:59:59.000Z

299

Recycled brake linings as partial aggregate substitute in asphalt paving. Construction and final report. Report for July 1992-August 1996  

SciTech Connect (OSTI)

The purpose of this project was to evaluate the performance of asphalt containing various percentages of brake lining as an aggregate, and compare its performance to that of normal asphalt containing natural aggregate. This project is an effort to explore alternate ways to use waste product. Four test section of FB-2 Modified mix containing brake lining materials were placed in July 1992 along with one control section on SR 3022 in Mercer county. To date all sections are performing satisfactory, and Brake linings should be recommended as a viable partial replacement of aggregate in bituminous materials. This study only considered the performance of only off-spec brake linings, therefore, any performance data or enviromental effects of placement of used brake material should be addressed.

Miller, P.A.; Sukley, R.

1996-09-01T23:59:59.000Z

300

Exploratory study of some potential environmental impacts of CO2 sequestration in unmineable coal seams  

SciTech Connect (OSTI)

An initial investigation into the potential environmental impacts of CO2 sequestration in unmineable coal seams has been conducted, focusing on changes in the produced water during enhanced coalbed methane (ECBM) production, using a CO2 injection process (CO2-ECBM). A high volatile bituminous coal, Pittsburgh No. 8, was reacted with synthetic produced water and gaseous carbon dioxide at 40°C and 50 bar to evaluate the potential for mobilisation of toxic metals during CO2-ECBM/sequestration. Microscopic and X-ray diffraction analysis of the post-reaction coal samples clearly show evidence of chemical reaction and chemical analysis of the synthetic produced water shows substantial changes in composition. These results suggest that changes to the produced water chemistry and the potential for mobilising toxic trace elements from coal beds are important factors to be considered when evaluating deep, unmineable coal seams for CO2 sequestration.

Hedges, S.W.; Soong, Y.; Jones, R.J.; Harrison, D.K.; Irdi, G.A.; Frommell, E.A.; Dilmore, R.M.; White, C.M.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

CONSOL Energy invests in West Virginia CTL plant  

SciTech Connect (OSTI)

Working with Synthesis Energy Systems (SES), America's leading bituminous coal producer assists with the engineering design package for a coal gasification and liquefaction plant to be located near Benwood in West Virginia. Coal will be converted to syngas using SES's proprietary U-GAS technology. The syngas is expected to be used to produce about 720,000 metric tons per year of methanol. The U-GAS technology is licensed from the Gas Technology Institute (GTI). The article explains how the GTI gasification process works. It is based on a surge-stage fluidised bed for production of low-to-medium calorific value synthesis gas from a variety of feedstocks, including coal. 2 figs.

NONE

2008-10-15T23:59:59.000Z

302

Nucla circulating atmospheric fluidized bed demonstration project. Final report  

SciTech Connect (OSTI)

Colorado-Ute Electric Association began a study to evaluate options for upgrading and extending the life of its Nucla power station in 1982. Located in southwestern Colorado near the town of Nucla, this station was commissioned in 1959 with a local bituminous coal as its design fuel for three identical stoker-fired units, each rated at 12.6 MW(e). Poor station efficiency, high fuel costs, and spiraling boiler maintenance costs forced the Nucla Station into low priority in the CUEA dispatch order as early as 1981. Among the options CUEA considered was to serve as a host utility to demonstrate Atmospheric Fluidized Bed Combustion (AFBC) technology. The anticipated environmental benefits and apparent attractive economics of a circulating AFBC led to Colorado-Ute`s decision to proceed with the design and construction of a demonstration project in 1984 at the Nucla facility.

Not Available

1991-10-01T23:59:59.000Z

303

Nucla circulating atmospheric fluidized bed demonstration project  

SciTech Connect (OSTI)

Colorado-Ute Electric Association began a study to evaluate options for upgrading and extending the life of its Nucla power station in 1982. Located in southwestern Colorado near the town of Nucla, this station was commissioned in 1959 with a local bituminous coal as its design fuel for three identical stoker-fired units, each rated at 12.6 MW(e). Poor station efficiency, high fuel costs, and spiraling boiler maintenance costs forced the Nucla Station into low priority in the CUEA dispatch order as early as 1981. Among the options CUEA considered was to serve as a host utility to demonstrate Atmospheric Fluidized Bed Combustion (AFBC) technology. The anticipated environmental benefits and apparent attractive economics of a circulating AFBC led to Colorado-Ute's decision to proceed with the design and construction of a demonstration project in 1984 at the Nucla facility.

Keith, Raymond E.

1991-10-01T23:59:59.000Z

304

LIMB Demonstration Project Extension. Quarterly report no. 8, February, March, and April, 1989  

SciTech Connect (OSTI)

The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full- scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

Not Available

1989-06-15T23:59:59.000Z

305

LIMB Demonstration Project Extension  

SciTech Connect (OSTI)

The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full- scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

Not Available

1989-06-15T23:59:59.000Z

306

Petrographic characterization of Kentucky coal. Final report. Part III. Petrographic characterization of the Upper Elkhorn No. 2 coal zone of eastern Kentucky  

SciTech Connect (OSTI)

This report presents the study of the Upper Elkhorn No. 2 coal zone in the Big Sandy Reserve District and the surrounding area of eastern Kentucky. The seams were analyzed using megascopic and microscopic petrography and chemical methods. The Upper Elkhorn No. 2 consists predominantly of clarain. A fair degree of correlation of fusain bands and clay partings between data sites is apparent. Microscopically, the vitrinite group of macerals are dominant. A rank increase from high volatile B to high volatile A bituminous to the southwest was noted. Pseudovitrinite is associated negatively with vitrinite and has a higher reflectance and microhardness than vitrinite. Both factors may indicate source material and/or environmental differences in the respective origins of the maceral. High inertinite and lipinite areas, low ash and sulfur contents, and the distribution of thin coals may be indicative of paleotopographic highs. 62 references, 26 figures, 8 tables.

Raione, R.P.; Hower, J.C.

1984-01-01T23:59:59.000Z

307

Intra- and inter-unit variation in fly ash petrography: Examples from a western Kentucky power station  

SciTech Connect (OSTI)

Fly ash was collected from eight mechanical and ten baghouse hoppers at each of twin 150-MW wall-fired units in a western Kentucky power station. The fuel burned at that time was a blend of low-sulfur, high volatile bituminous Central Appalachian coals. The baghouse ash showed less variation between units than the mechanical units. The coarser mechanical fly ash showed significant differences in the amount of total carbon and in the ratio of isotropic coke to both total carbons and total coke; the latter excluding inertinite and other unburned, uncoked coal. There was no significant variation in ratios of inorganic fly ash constituents. The inter-unit differences in the amount and forms of mechanical fly ash carbon appear to be related to differences in pulverizer efficiency, leading to greater amounts of coarse coal, therefore unburned carbon, in one of the units.

Hower, J.C.; Rathbone, R.F. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Goodman, J. [Prestonburg High School, KY (United States)

1998-12-31T23:59:59.000Z

308

POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE  

SciTech Connect (OSTI)

The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

B.K. PAREKH; D. TAO; J.G. GROPPO

1998-02-03T23:59:59.000Z

309

Increase of unit efficiency by improved waste heat recovery  

SciTech Connect (OSTI)

For coal-fired power plants with flue gas desulfurization by wet scrubbing and desulfurized exhaust gas discharge via cooling tower, a further improvement of new power plant efficiency is possible by exhaust gas heat recovery. The waste heat of exhaust gas is extracted in a flue gas cooler before the wet scrubber and recovered for combustion air and/or feedwater heating by either direct or indirect coupling of heat transfer. Different process configurations for heat recovery system are described and evaluated with regard to net unit improvement. For unite firing bituminous coal an increase of net unit efficiency of 0.25 to 0.7 percentage points and for lignite 0.7 to 1.6 percentage points can be realized depending on the process configurations of the heat recovery systems.

Bauer, G.; Lankes, F.

1998-07-01T23:59:59.000Z

310

Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends  

SciTech Connect (OSTI)

Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

2008-05-15T23:59:59.000Z

311

Reducing power production costs by utilizing petroleum coke. Annual report  

SciTech Connect (OSTI)

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

Galbreath, K.C.

1998-07-01T23:59:59.000Z

312

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE  

SciTech Connect (OSTI)

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

NONE

1998-09-01T23:59:59.000Z

313

USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS  

SciTech Connect (OSTI)

U.S. low rank coals contain relatively large amounts of moisture, with the moisture content of subbituminous coals typically ranging from 15 to 30 percent and that for lignites from 25 and 40 percent. High fuel moisture has several adverse impacts on the operation of a pulverized coal generating unit, for it can result in fuel handling problems and it affects heat rate, stack emissions and maintenance costs. Theoretical analyses and coal test burns performed at a lignite fired power plant show that by reducing the fuel moisture, it is possible to improve boiler performance and unit heat rate, reduce emissions and reduce water consumption by the evaporative cooling tower. The economic viability of the approach and the actual impact of the drying system on water consumption, unit heat rate and stack emissions will depend critically on the design and operating conditions of the drying system. The present project evaluated the low temperature drying of high moisture coals using power plant waste heat to provide the energy required for drying. Coal drying studies were performed in a laboratory scale fluidized bed dryer to gather data and develop models on drying kinetics. In addition, analyses were carried out to determine the relative costs and performance impacts (in terms of heat rate, cooling tower water consumption and emissions) of drying along with the development of optimized drying system designs and recommended operating conditions.

Edward K. Levy; Nenad Sarunac; Harun Bilirgen; Hugo Caram

2006-03-01T23:59:59.000Z

314

A CHARACTERIZATION AND EVALUATION OF COAL LIQUEFACTION PROCESS STREAMS  

SciTech Connect (OSTI)

This is the first Annual Technical Report of activities under DOE Contract No. DE-AC22-94PC93054. Activities from the first three quarters of the fiscal 1998 year were reported previously as Quarterly Technical Progress Reports (DOE/PC93054-57, DOE/PC93054-61, and DOE/PC93054-66). Activities for the period July 1 through September 30, 1998, are reported here. This report describes CONSOL's characterization of process-derived samples obtained from HTI Run PB-08. These samples were derived from operations with Black Thunder Mine Wyoming subbituminous coal, simulated mixed waste plastics, and pyrolysis oils derived from waste plastics and waste tires. Comparison of characteristics among the PB-08 samples was made to ascertain the effects of feed composition changes. A comparison also was made to samples from a previous test (Run PB-06) made in the same processing unit, with Black Thunder Mine coal, and in one run condition with co-fed mixed plastics.

G.A. Robbins; R.A. Winschel; S.D. Brandes

1999-05-01T23:59:59.000Z

315

The key to minimizing minesite versus utility laboratory analyses on Powder River Basin coals  

SciTech Connect (OSTI)

Powder River Basin (PRB) coals are continuing to expand their areas of use into regions previously reserved for higher ranked coals. PRB coals are subbituminous by rank. Inherent moisture values of 25 to 30 percent are the norm. PRB coals, being lower rank in nature, also tend to oxidize very easily. These factors combined produce a coal which can cause analysis problems for laboratories unaccustomed to PRB coals. In fact, even laboratories that deal with this type of coal on a daily basis can experience analytical difficulties. Special care needs to be taken by both minesite laboratory and the utility laboratory to ensure accurate analyses. Cooperation between both parties is the key to reproducible analyses. Only by working together can parties fully analyze the situation and develop analytical methods acceptable to both. This paper will describe the methods employed by the Caballo Rojo Mine (CRM) and the Georgia Power Company (GPC) to resolve laboratory analysis differences found during shipments by CRM to GPC beginning in 1994. The following topics are discussed: initial comparative results, analytical investigations, the cooperative process, recent comparative results, and conclusions.

Rexin, M.G.

1995-08-01T23:59:59.000Z

316

Small-scale circulating fluidized bed combustor (CFBC) system for heat and power in remote areas  

SciTech Connect (OSTI)

Demand for heating and electric power has steadily increased in remote areas. The use of locally available fuel to achieve self sufficiency has become an important objective. Energy demands may require steam generation for district heating, power generation and process consumption. In addition, the steam generation unit can also be required to burn waste that includes MSW and sewage sludge. To meet these demands, new systems must be installed that use local fuel. This paper describes a lower cost CFBC for use in remote areas. With the support of DOE METC, in late summer 1994, DONLEE performed a test burn at its 10 MM btu/hr pilot CFBC using subbituminous coal from Wyoming. The Wyoming coal`s sulfur dioxide emissions were very low due to the low sulfur content of the Wyoming coal and the excellent efficiency at temperatures as low as 1,500 F thereby indicating no limestone addition was needed for sulfur capture. The CFBC testing indicated emissions met all of the environmental requirements, both Federal and state. These requirements include: particulates, SO{sub 2}, CO, NO{sub x}, opacity, chlorinated dioxins/furans, etc. The unit can be fabricated in modules, making the installation easier and less expensive for use in remote areas. The design is highly reliable and can be fully automated thereby requiring limited staffing.

Stuart, J.M.; Korenberg, J. [DONLEE Technologies Inc., York, PA (United States)

1995-12-31T23:59:59.000Z

317

Energy and environmental research emphasizing low-rank coal -- Task 5.1, Stability issues  

SciTech Connect (OSTI)

Low-sulfur subbituminous and lignite coals have high moisture content and, consequently, low heating value, leading to boiler derating in US midwestern and eastern utilities as well as switching and/or blending coals to achieve SO{sub 2} compliance. In the drive to develop cost-effective coal-drying processes, coal developers have focused on heat content of the products and generally neglected the critical stability issues of friability and dusting, moisture reabsorption, and spontaneous heating. The Energy and Environmental Research Center (EERC), in an effort to establish new standards for dried products, has used established methods and has developed new ones to evaluate the propensity of lump western coals, raw and dried, to produce dust and absorb water. Three drying methods--air, hydrothermal, and saturated steam--were used to generate low-moisture upgraded products. New indices for dust generation and friability were determined to assess the effects of moisture removal and upgrading methodology on coal stability. Analysis of the dried coals using various strength tests indicated that the reduction in moisture made the lump coal unstable, yielding substantially higher dust and friability indices relative to those of the raw coals.

Anderson, C.M.; Musich, M.A.; Dewall, R.A.; Richter, J.J.

1995-04-01T23:59:59.000Z

318

Indirect conversion of coal to methanol and gasoline: product price vs product slate  

SciTech Connect (OSTI)

The Oak Ridge National Laboratory (ORNL) conducts process analysis and engineering evaluation studies for the Department of Energy to provide, on a consistent basis, technical and economic assessments of processes and systems for coal conversion and utilization. Such assessments permit better understanding of the relative technical and economic potential of these processes. The objective of the work described here was to provide an assessment of the technical feasibility, economic competitiveness, and environmental acceptability of selected indirect coal liquefaction processes on a uniform, consistent, and impartial basis. Particular emphasis is placed on production of methanol as a principal product or methanol production for conversion to gasoline. Potential uses for the methanol are combustion in peaking-type turbines or blending with gasoline to yield motor fuel. Conversion of methanol to gasoline is accomplished through the use of the Mobil methanol-to-gasoline (MTG) process. Under the guidance of ORNL, Fluor Engineers and Constructors, Houston Division, prepared four conceptual process designs for indirect conversion of a Western subbituminous coal to either methanol or gasoline. The conceptual designs are based on the use of consistent technology for the core of the plant (gasification through methanol synthesis) with additional processing as necessary for production of different liquid products of interest. The bases for the conceptual designs are given. The case designations are: methanol production for turbine-grade fuel; methanol production for gasoline blending; gasoline production with coproduction of SNG; and gasoline production maximized.

Wham, R.M.; McCracken, D.J.; Forrester, R.C. III

1980-01-01T23:59:59.000Z

319

Catalytic co-processing of coal with bitumen and bitumen derived liquids  

SciTech Connect (OSTI)

Experimental studies on the co-processing of coal with bitumen and bitumen derived liquids are described. A subbituminous coal was coprocessed with Athabasca bitumen and its various liquid fractions in a batch autoclave under hydrogen pressure at reaction temperatures varying from 400 to 440{degrees}C. Both thermal and catalytic coprocessing experiments were conducted. The catalysts used were molten halide type and included ZnCl{sub 2}, MoCl{sub 5}, KCl, CuCl, and SnCl{sub 2}. Higher reaction temperature resulted in higher conversion of asphaltenes into both maltenes and coke and gases. As a result the H/C atomic ratio of the unconverted asphaltenes decreased with temperature. Higher reaction time on the other hand allowed maltenes to be converted to asphaltenes. While all the catalysts tested had catalytic effects on asphaltene conversion, MoCl{sub 5} was found to provide the highest conversion of asphaltenes due to its ability to hydrogenate the radicals formed due to asphaltene cracking. Processing of coal with bitumen derived liquids provided higher yields than those obtained with virgin bitumen. The H/C ratios were also higher for the products obtained with bitumen derived liquids.

Chakma, A.; Zaman, J. [Univ. of Calgary, Alberta (Canada)

1993-12-31T23:59:59.000Z

320

Improving conversion rates in low severity coal liquefaction  

SciTech Connect (OSTI)

A series of reactions were run with lignite coal and subbituminous coal. The purpose was: (1) to prove the importance that various treatments have in producing high conversion rates in low severity coal liquefaction, and (2) to determine their independent and combined effectiveness. The coal was pretreated with HCI and methanol. Molybdenum naphthanate and nickel octoate were independently used as catalysts. Also, the cyclic olefin, 1, 4, 5, 8, 9, 10-hexahydroanthracene (HHA), was tested as a hydrogen donor. By using all of these treatments with molybdenum naphthanate as the catalyst, the best conversion rate of 56% was achieved. This project was made possible by the U.S. Department of Energy (DOE) University Coal Research (UCR) Internship Program. This program is managed and operated for DOE by the Oak Ridge Institute for Science and Education (ORISE). Participants are assigned to universities conducting fossil energy-related research under UCR grants from the Pittsburgh Technology Center (PETC). All research was performed at Auburn University under the supervision of Dr. Christine W. Curtis.

Williams, B. [West Georgia College, Carrollton, GA (United States)

1995-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994  

SciTech Connect (OSTI)

Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

1995-04-01T23:59:59.000Z

322

Power Systems Development Facility  

SciTech Connect (OSTI)

This report discusses Test Campaign TC12 of the Kellogg Brown & Root, Inc. (KBR) Transport Gasifier train with a Siemens Westinghouse Power Corporation (SW) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Gasifier is an advanced circulating fluidized-bed reactor designed to operate as either a combustor or a gasifier using a particulate control device (PCD). While operating as a gasifier, either air or oxygen can be used as the oxidant. Test run TC12 began on May 16, 2003, with the startup of the main air compressor and the lighting of the gasifier start-up burner. The Transport Gasifier operated until May 24, 2003, when a scheduled outage occurred to allow maintenance crews to install the fuel cell test unit and modify the gas clean-up system. On June 18, 2003, the test run resumed when operations relit the start-up burner, and testing continued until the scheduled end of the run on July 14, 2003. TC12 had a total of 733 hours using Powder River Basin (PRB) subbituminous coal. Over the course of the entire test run, gasifier temperatures varied between 1,675 and 1,850 F at pressures from 130 to 210 psig.

None

2003-07-01T23:59:59.000Z

323

JV 58-Effects of Biomass Combustion on SCR Catalyst  

SciTech Connect (OSTI)

A portable slipstream selective catalytic reduction (SCR) reactor was installed at a biomass cofired utility boiler to examine the rates and mechanisms of catalyst deactivation when exposed to biomass combustion products. The catalyst was found to deactivate at a much faster rate than typically found in a coal-fired boiler, although this may have been the result of high ash loading rather than a general property of biomass combustion. Deactivation was mainly the result of alkali and alkaline-earth sulfate formation and growth in catalyst pores, apparently caused by alkaline-earth ash deposition on or near the pore sites. The high proportion of biomass in the fuel contributed to elevated levels of alkali and alkaline-earth material in the ash when compared to coal ash, and these higher levels provided more opportunity for sulfate formation. Based on laboratory tests, neither catalyst material nor ammonia contributed measurably to ash mass gains via sulfation. A model constructed using both field and laboratory data was able to predict catalyst deactivation of catalysts under subbituminous coal firing but performed poorly at predicting catalyst deactivation under cofiring conditions. Because of the typically higher-than coal levels of alkali and alkaline-earth elements present in biomass fuels that are available for sulfation at typical SCR temperatures, the use of SCR technology and biomass cofiring needs to be carefully evaluated prior to implementation.

Bruce C. Folkedahl; Christopher J. Zygarlicke; Joshua R. Strege; Donald P. McCollor; Jason D. Laumb; Lingbu Kong

2006-08-31T23:59:59.000Z

324

COFIRING OF BIOMASS AT THE UNIVERSITY OF NORTH DAKOTA  

SciTech Connect (OSTI)

A project funded by the U.S. Department of Energy's National Energy Technology Laboratory was completed by the Energy & Environmental Research Center to explore the potential for cofiring biomass at the University of North Dakota (UND). The results demonstrate how 25% sunflower hulls can be cofired with subbituminous coal and provide a 20% return on investment or 5-year payback for the modifications required to enable firing biomass. Significant outcomes of the study are as follows. A complete resource assessment presented all biomass options to UND within a 100-mile radius. Among the most promising options in order of preference were sunflower hulls, wood residues, and turkey manure. The firing of up to 28% sunflower hulls by weight was completed at the university's steam plant to identify plant modifications that would be necessary to enable cofiring sunflower hulls. The results indicated investments in a new equipment could be less than $408,711. Data collected from test burns, which were not optimized for biomass firing, resulted in a 15% reduction in sulfur and NO{sub x} emissions, no increase in opacity, and slightly better boiler efficiency. Fouling and clinkering potential were not evaluated; however, no noticeable detrimental effects occurred during testing. As a result of this study, UND has the potential to achieve a cost savings of approximately $100,000 per year from a $1,500,000 annual fossil fuel budget by implementing the cofiring of 25% sunflower hulls.

Phillip N. Hutton

2002-01-01T23:59:59.000Z

325

Power Systems Development Facility Gasification Test Campaing TC18  

SciTech Connect (OSTI)

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details Test Campaign TC18 of the PSDF gasification process. Test campaign TC18 began on June 23, 2005, and ended on August 22, 2005, with the gasifier train accumulating 1,342 hours of operation using Powder River Basin (PRB) subbituminous coal. Some of the testing conducted included commissioning of a new recycle syngas compressor for gasifier aeration, evaluation of PCD filter elements and failsafes, testing of gas cleanup technologies, and further evaluation of solids handling equipment. At the conclusion of TC18, the PSDF gasification process had been operated for more than 7,750 hours.

Southern Company Services

2005-08-31T23:59:59.000Z

326

Power Systems Development Facility Gasification Test Campaign TC16  

SciTech Connect (OSTI)

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report discusses Test Campaign TC16 of the PSDF gasification process. TC16 began on July 14, 2004, lasting until August 24, 2004, for a total of 835 hours of gasification operation. The test campaign consisted of operation using Powder River Basin (PRB) subbituminous coal and high sodium lignite from the North Dakota Freedom mine. The highest gasifier operating temperature mostly varied from 1,760 to 1,850 F with PRB and 1,500 to 1,600 F with lignite. Typically, during PRB operations, the gasifier exit pressure was maintained between 215 and 225 psig using air as the gasification oxidant and between 145 and 190 psig while using oxygen as the oxidant. With lignite, the gasifier operated only in air-blown mode, and the gasifier outlet pressure ranged from 150 to 160 psig.

Southern Company Services

2004-08-24T23:59:59.000Z

327

Power Systems Development Facility  

SciTech Connect (OSTI)

This report discusses Test Campaign TC15 of the Kellogg Brown & Root, Inc. (KBR) Transport Gasifier train with a Siemens Power Generation, Inc. (SPG) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Gasifier is an advanced circulating fluidized-bed reactor designed to operate as either a combustor or gasifier using a particulate control device (PCD). While operating as a gasifier, either air or oxygen can be used as the oxidant. Test run TC15 began on April 19, 2004, with the startup of the main air compressor and the lighting of the gasifier startup burner. The Transport Gasifier was shutdown on April 29, 2004, accumulating 200 hours of operation using Powder River Basin (PRB) subbituminous coal. About 91 hours of the test run occurred during oxygen-blown operations. Another 6 hours of the test run was in enriched-air mode. The remainder of the test run, approximately 103 hours, took place during air-blown operations. The highest operating temperature in the gasifier mixing zone mostly varied from 1,800 to 1,850 F. The gasifier exit pressure ran between 200 and 230 psig during air-blown operations and between 110 and 150 psig in oxygen-enhanced air operations.

Southern Company Services

2004-04-30T23:59:59.000Z

328

Kinetics of coal pyrolysis and devolatilization  

SciTech Connect (OSTI)

An experimentally based, conceptual model of the devolatilization of a HV bituminous coal is outlined in this report. This model contends that the relative dominance of a process type-chemical kinetic, heat transport, mass transport -- varies with the extent of reaction for a given set of heating conditions and coal type and with experimental conditions for a given coal type and extent of reaction. The rate of devolatilization mass loss process is dominated initially by heat transfer processes, then coupled mass transfer and chemical kinetics, and finally by chemical processes alone. However, the chemical composition of the initial tars are determined primarily by the chemical characteristics of the parent coal. Chemically controlled gas phase reactions of the initial tars and coupled mass transfer and chemically controlled reactions of heavy tars determine the bulk of the light gas yields. For a HV bituminous coal this conceptual model serves to quantify the Two-Component Hypothesis'' of volatiles evolution. The model postulates that the overall rates of coal devolatilization should vary with coal type insofar as the characteristics of the parent coal determine the potential tar yield and the chemical characteristics of the initial tars. Experimental evidence indicates chemical characteristics and yields of primary'' tars vary significantly with coal type. Consequently, the conceptual model would indicate a shift from transport to chemical dominance of rate processes with variation in coal type. Using the conceptual model, United Technologies Research Center has been able to correlate initial mass loss with a heat transfer index for a wide range of conditions for high tar yielding coals. 33 refs., 30 figs., 6 tabs.

Not Available

1987-01-01T23:59:59.000Z

329

Occupational and traning requirements for expanded coal production (as of October 1980). [Forecasting to 1995  

SciTech Connect (OSTI)

This study was initiated because of the anticipated rapid growth in trained personnel requirements in bituminous coal mining, and because the industry had already experienced significant problems in recruiting skilled manpower in the course of its employment expansion during the 1970's. Employment in bituminous coal mining is projected to nearly double, from 234,000 in 1977 to 456,000 in 1995, as the net result of a projected threefold increase in coal output to nearly 2.0 billion in 1995 and of an expected significant improvement in overall productivity. A large proportion of current coal mining employees are in occupations which require significant amounts of training for effective work performance. Employment growth to 1955 will be most rapid in those occupations requiring the greatest training or educational preparation. The new training infrastructure which has emerged to meet these needs includes both internal, company-operated training programs and those offered by various external providers. Among the latter are: Vocational schools, community colleges, and university extension departments; public agencies, such as MSHA and state mining departments; coal industry trade associations; and vendors or training consultant groups. The Conference Board survey of coal industry training programs, conducted in late 1979, was designed to provide comprehensive data on the scope of the coal industry's own training activities and on related training issues, based on a mail questionnaire survey addressed to all companies producing 300,000 or more tons per year. The training programs are described with emphasis on time changes, regional effects and implications for a coordinated plan.

Not Available

1982-04-01T23:59:59.000Z

330

Effect of coal type, residence time, and combustion configuration on the submicron aerosol composition and size distribution from pulverized coal combustion  

SciTech Connect (OSTI)

Pulverized samples of Utah bituminous, Beulah (North Dakota) low Na lignite, Deulah high Na lignite and Texas (San Miguel) lignite coals were burned at a rate of 2.5 kg/hr in a laboratory furnace under various (overall fuel lean) combustion conditions. Particle size distributions (PSD) and size segregated particle filter samples were taken at various positions within the convection section. Temperature and gas concentrations were measured throughout. The evolution of the submicron PSD within the convection section for the four coals was similar, although the location of the initial particle mode at the convection section inlet varied with coal type. While stage combustion of the Utah bituminous coal had a variable effect on the volume of submicron aerosol produced, staged combustion of two of the three lignites (Beulah low Na and Texas) caused a definite increase in the submicron aerosol volume. Chemical analysis of the size segregated particle samples show the trace elements, As, Pb, Zn, and the major elements, Na and K to be enriched in the submicron aerosol. Auger depth profiles show these small particles to be comprised of a core enriched in Fe, Si, Ca and Mg and surface layers enriched in Na and K. These results point to a mechanism of homogeneous nucleation of low vapor pressure species followed by successive layering of progressively more volatile species. Volatile species are enriched in the submicron aerosol due to the large surface areas provided. Modeling efforts show that while coagulation may be the dominant mechanism to describe the aerosol evolving within the convection section, it cannot be used solely to predict the PSD. Another mechanism, presumably surface area dependent growth (condensation) must be included.

Linak, W.P.

1985-01-01T23:59:59.000Z

331

Power Systems Development Facility Gasification Test Campaign TC24  

SciTech Connect (OSTI)

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC24, the first test campaign using a bituminous coal as the feedstock in the modified Transport Gasifier configuration. TC24 was conducted from February 16, 2008, through March 19, 2008. The PSDF gasification process operated for about 230 hours in air-blown gasification mode with about 225 tons of Utah bituminous coal feed. Operational challenges in gasifier operation were related to particle agglomeration, a large percentage of oversize coal particles, low overall gasifier solids collection efficiency, and refractory degradation in the gasifier solids collection unit. The carbon conversion and syngas heating values varied widely, with low values obtained during periods of low gasifier operating temperature. Despite the operating difficulties, several periods of steady state operation were achieved, which provided useful data for future testing. TC24 operation afforded the opportunity for testing of various types of technologies, including dry coal feeding with a developmental feeder, the Pressure Decoupled Advanced Coal (PDAC) feeder; evaluating a new hot gas filter element media configuration; and enhancing syngas cleanup with water-gas shift catalysts. During TC24, the PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane.

Southern Company Services

2008-03-30T23:59:59.000Z

332

Low NO{sub x}/SO{sub x} Burner retrofit for utility cyclone boilers. Quarterly technical progress report, June--September 1990  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the LNS Burner as retrofitted to the host cyclone boiler for effective low-cost control of NO{sub x} and SO{sub x} emissions while firing a bituminous coal. The LNS Burner employs a simple, innovative combustion process to burn pulverized coal at high temperatures and provides effective, low-cost control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions. The coal ash contains sulfur and is removed in the form of molten slag and flyash. Cyclone-fired boiler units are typically older units firing high-sulfur bituminous coals at very high temperatures which results in very high NO{sub x} and SO{sub x} emissions. The addition of conventional emission control equipment, such as wet scrubbers, to these older cyclone units in order to meet current and future environmental regulations is generally not economic. Further, the units are generally not compatible with low sulfur coal switching for S0{sub 2} control or selective catalytic reduction technologies for NO{sub x} control. Because the LNS Burner operates at the same very high temperatures as a typical cyclone boiler and produces a similar slag product, it may offer a viable retrofit option for cyclone boiler emission control. This was confirmed by the Cyclone Boiler Retrofit Feasibility Study carried out by TransAlta and an Operating Committee formed of cyclone boiler owners in 1989. An existing utility cyclone boiler, was then selected for the evaluation of the cost and performance study. It was concluded that the LNS Burner retrofit would be a cost-effective option for control of cyclone boiler emissions. A full-scale demonstration of the LNS Burner retrofit was selected in October 1988 as part of the DOE`s Clean Coal Technology Program Round II.

Not Available

1990-12-31T23:59:59.000Z

333

Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the LNS Burner as retrofitted to the host cyclone boiler for effective low-cost control of NO{sub x} and SO{sub x} emissions while firing a bituminous coal. The LNS Burner employs a simple, innovative combustion process to burn pulverized coal at high temperatures and provides effective, low-cost control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions. The coal ash contains sulfur and is removed in the form of molten slag and flyash. Cyclone-fired boiler units are typically older units firing high-sulfur bituminous coals at very high temperatures which results in very high NO{sub x} and SO{sub x} emissions. The addition of conventional emission control equipment, such as wet scrubbers, to these older cyclone units in order to meet current and future environmental regulations is generally not economic. Further, the units are generally not compatible with low sulfur coal switching for S0{sub 2} control or selective catalytic reduction technologies for NO{sub x} control. Because the LNS Burner operates at the same very high temperatures as a typical cyclone boiler and produces a similar slag product, it may offer a viable retrofit option for cyclone boiler emission control. This was confirmed by the Cyclone Boiler Retrofit Feasibility Study carried out by TransAlta and an Operating Committee formed of cyclone boiler owners in 1989. An existing utility cyclone boiler, was then selected for the evaluation of the cost and performance study. It was concluded that the LNS Burner retrofit would be a cost-effective option for control of cyclone boiler emissions. A full-scale demonstration of the LNS Burner retrofit was selected in October 1988 as part of the DOE's Clean Coal Technology Program Round II.

Not Available

1990-01-01T23:59:59.000Z

334

Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology  

SciTech Connect (OSTI)

The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

Swanson, Michael; Henderson, Ann

2012-04-01T23:59:59.000Z

335

Field Testing of Activated Carbon Injection Options for Mercury Control at TXU's Big Brown Station  

SciTech Connect (OSTI)

The primary objective of the project was to evaluate the long-term feasibility of using activated carbon injection (ACI) options to effectively reduce mercury emissions from Texas electric generation plants in which a blend of lignite and subbituminous coal is fired. Field testing of ACI options was performed on one-quarter of Unit 2 at TXU's Big Brown Steam Electric Station. Unit 2 has a design output of 600 MW and burns a blend of 70% Texas Gulf Coast lignite and 30% subbituminous Powder River Basin coal. Big Brown employs a COHPAC configuration, i.e., high air-to-cloth baghouses following cold-side electrostatic precipitators (ESPs), for particulate control. When sorbent injection is added between the ESP and the baghouse, the combined technology is referred to as TOXECON{trademark} and is patented by the Electric Power Research Institute in the United States. Key benefits of the TOXECON configuration include better mass transfer characteristics of a fabric filter compared to an ESP for mercury capture and contamination of only a small percentage of the fly ash with AC. The field testing consisted of a baseline sampling period, a parametric screening of three sorbent injection options, and a month long test with a single mercury control technology. During the baseline sampling, native mercury removal was observed to be less than 10%. Parametric testing was conducted for three sorbent injection options: injection of standard AC alone; injection of an EERC sorbent enhancement additive, SEA4, with ACI; and injection of an EERC enhanced AC. Injection rates were determined for all of the options to achieve the minimum target of 55% mercury removal as well as for higher removals approaching 90%. Some of the higher injection rates were not sustainable because of increased differential pressure across the test baghouse module. After completion of the parametric testing, a month long test was conducted using the enhanced AC at a nominal rate of 1.5 lb/Macf. During the time that enhanced AC was injected, the average mercury removal for the month long test was approximately 74% across the test baghouse module. ACI was interrupted frequently during the month long test because the test baghouse module was bypassed frequently to relieve differential pressure. The high air-to-cloth ratio of operations at this unit results in significant differential pressure, and thus there was little operating margin before encountering differential pressure limits, especially at high loads. This limited the use of sorbent injection as the added material contributes to the overall differential pressure. This finding limits sustainable injection of AC without appropriate modifications to the plant or its operations. Handling and storage issues were observed for the TOXECON ash-AC mixture. Malfunctioning equipment led to baghouse dust hopper plugging, and storage of the stagnant material at flue gas temperatures resulted in self-heating and ignition of the AC in the ash. In the hoppers that worked properly, no such problems were reported. Economics of mercury control at Big Brown were estimated for as-tested scenarios and scenarios incorporating changes to allow sustainable operation. This project was funded under the U.S. Department of Energy National Energy Technology Laboratory project entitled 'Large-Scale Mercury Control Technology Field Testing Program--Phase II'.

John Pavlish; Jeffrey Thompson; Christopher Martin; Mark Musich; Lucinda Hamre

2009-01-07T23:59:59.000Z

336

Fine particle clay catalysts for coal liquefaction. Quarterly technical progress report, November 9, 1991--February 8, 1992  

SciTech Connect (OSTI)

The investigation of methods for the production and testing of iron-pillared clay catalysts was continued in this quarter. The surface area of the mixed alumina/iron pillared clay catalyst decreased to 51 m{sup 2}/g on sulfidation. Thus the stability of the alumina pillars during the sulfidation and thermal treatments prevented the total collapse that occurred in the case of the iron-pillared clays. Previously the mixed alumina/iron pillared clays were tested for hydrocracking activities with bibenzyl. This testing was extended to a determination of activity with a second model compound substrate (pyrene), representative of the polynuclear aromatic systems present in coal. Testing of the mixed alumina/iron-pillared catalysts with 1-methylnaphthalene gave interesting results that demonstrate shape selectivity. The clay-supported iron hydroxyoxide catalysts prepared by impregnation of iron species on acidic clays were further investigated. Sulfidation of these catalysts using the carbon disulfide in situ method gave hydrocracking activities with bibenzyl that were somewhat less than those obtained by presulfidation with H{sub 2}/H{sub 2}S mixtures. Liquefaction of Wyodak subbituminous coal was very successful with the iron impregnated clay catalyst, giving a highly soluble product. High conversions were also obtained with the mixed alumina/iron-pillared clay catalyst, but the yield of oil-solubles was considerably lower. Several new catalysts were synthesized with the idea of decreasing the pillar density and thereby increasing the micropore volume. These catalysts were prepared by first pillaring with an organic ammonium pillaring agent, then introducing a lower number of silica or alumina pillars. Finally the iron component was added either before or after thermal removal of organic pillars.

Olson, E.S.

1995-10-01T23:59:59.000Z

337

Mild coal pretreatment to improve liquefaction reactivity. Final technical report, September 1990--February 1994  

SciTech Connect (OSTI)

Recent research efforts in direct coal liquefaction are focused on lowering the level of reaction severity, identification and determination of the causes of retrogressive reactions, and improving the economics of the process. Ambient pretreatment of coals using methanol and a trace amount of hydrochloric acid was extensively studied in connection with low severity coal liquefaction. Ambient pretreatment of eight Argonne coals using methanol/HCl improved THF-soluble conversions 24.5 wt % (maf basis) for Wyodak subbituminous coal and 28.4 wt % for Beulah-Zap lignite with an average increase of 14.9 wt % for the eight Argonne coals at 623 K (350{degrees}C) reaction temperature and 30 minutes reaction time. Optimal pretreatment conditions were determined using Wyodak and Illinois No. 6 coals. Acid concentration was the most important pretreatment variable studied; liquefaction reactivity increased with increasing acid concentration up to 2 vol %. The FTIR spectra of treated and untreated Wyodak coal samples demonstrated formation of carboxylic functional groups during pretreatment, a result of divalent (Ca, Mg) cationic bridge destruction. The extent of liquefaction reactivity directly correlated with the amount of calcium removed during pretreatment, and results from calcium ``addback`` experiments supported the observation that calcium adversely affected coal reactivity at low severity reaction conditions. Model compound studies using benzyl phenyl ether demonstrated that calcium cations catalyzed retrogressive reactions, inhibited hydrogenation reactions at low severity reaction conditions, and were more active at higher reaction temperatures. Based on kinetic data, mechanisms for hydrogenation-based inhibition and base-catalyzed retrogressive reactions are proposed. The base-catalyzed retrogressive reactions are shown to occur via a hydrogen abstraction mechanism where hydrogenation inhibition reactions are shown to take place via a surface quenching mechanism.

Miller, R.L.; Shams, K.G.

1994-07-01T23:59:59.000Z

338

Western Coal/Great Lakes Alternative export-coal conference  

SciTech Connect (OSTI)

This conference dealt with using the Great Lakes/St. Lawrence Seaway as an alternative to the East and Gulf Coasts for the exporting of coal to Europe and the potential for a piece of the European market for the subbituminous coals of Montana and Wyoming. The topics discussed included: government policies on coal exports; the coal reserves of Montana; cost of rail transport from Western mines to Lake Superior; the planning, design, and operation of the Superior Midwest Energy Terminal at Superior, Wisconsin; direct transfer of coal from self-unloading lakers to large ocean vessels; concept of total transportation from mines to users; disadvantage of a nine month season on the Great Lakes; costs of maritime transport of coal through the Great Lakes to Europe; facilities at the ice-free, deep water port at Sept Iles; the use of Western coals from an environmental and economic viewpoint; the properties of Western coal and factors affecting its use; the feasibility of a slurry pipeline from the Powder River Basin to Lake Superior; a systems analysis of the complete hydraulic transport of coal from the mine to users in Europe; the performance of the COJA mill-burner for the combustion of superfine coal; demand for steam coal in Western Europe; and the effect the New Source Performance Standards will have on the production and use of Western coal. A separate abstract was prepared for each of the 19 papers for the Energy Data Base (EDB); 17 will appear in Energy Research Abstracts (ERA) and 11 in Energy Abstracts for Policy Analysis (EAPA). (CKK)

Not Available

1981-01-01T23:59:59.000Z

339

Quarterly technical progress report, October 1-December 30, 1983  

SciTech Connect (OSTI)

Several new initiatives were begun in coal preparation, including a project to develop a liquid CO/sub 2/ coalescence process that will produce a superclean coal containing less than 1% ash. Another new project in this area is focusing on chemical coal cleaning for the removal of harmful trace elements, such as arsenic, lead, and zinc. Milestones were reached in both of our major electron beam flue gas cleanup projects. In the area of coal-water mixtures, our major industrial contracts are now approaching critical milestones. The analysis of our in-house combustion testing of micronized coal-water mixtures in PETC's 700-horsepower oil-designed boiler has been completed. By reducing the coal particle size from 90% minus 200 mesh down to 87% minus 19 microns, the carbon conversion efficiency increased from a level of 96% to 98%. Combustion tests with a commercially available CWM showed that combustion air enriched to 23% oxygen reduced the needed air preheat temperature from 370/sup 0/ to 200/sup 0/F. Work also got underway in the new projects selected last summer to investigate advanced direct liquefaction processes. At Kerr-McGee, three scoping runs on their 350 pound/day integrated bench-scale unit were successfully completed. The objective of these runs was to evaluate subbituminous coal process options in terms of catalyst performance, distillate yields, and generation of coke precursors. Cities Service began its project on the characterization of hydrogen donor solvents in two-stage liquefaction. 7 figures, 33 tables.

Not Available

1984-04-01T23:59:59.000Z

340

Miocene fluvial-tidal sedimentation in a residual forearc basin of the Northeastern Pacific Rim: Cook Inlet, Alaska case study  

SciTech Connect (OSTI)

Cook Inlet in southern Alaska represents a Cenozoic residual forearc basin in a convergent continental margin, where the Pacific Plate is being subducted beneath the North American Plate. This basin accumulated the >6,700-m-thick, mainly nonmarine, Eocene-Pliocene Kenai Group. These rocks contain biogenic coal-bed methane estimated to be as high as 245 TCF. Lignites to subbituminous coals with subsurface R{sub o} ranging from 0.38 to 0.73 percent and the stage of clay-mineral diagenesis and expandibility indicate a thermally {open_quotes}cool{close_quotes} basin. Miocene Tyonek and Beluga Formations compose 65 percent (>4,300 m thick) of the Kenai Group. The Tyonek includes conglomeratic sandstones, siltstones, mudstones, coals, and carbonaceous shales, interpreted as braided- stream deposits. These fluvial deposits are interbecided with burrowed, lenticular, and flaser-bedded sandstones, siltstones, and mudstones, interpreted as tidal deposits. Tyonek framework conglomerates formed in wet alluvial fans incised on paleovalleys of the Chugach terrane. Coal-forming mires are well developed on abandoned braided-stream deposits. Tyonek drainages formed in high-gradient alluvial plains inundated by tides similar to environments in the modern upper Cook Inlet. The upper Miocene Beluga consists of sandstones, siltstones, mudstones, carbonaceous shales, and coals deposited in meandering (low sinuosity) and anastomosed fluvial systems. These fluvial deposits alternated vertically with deposits of coal-forming mires. The Beluga drainages formed in low-gradient alluvial plains. The high-gradient Tyonek alluvial plain was probably controlled by provenance uplift and eustatic change, whereas the low-gradient Beluga alluvial plain was influenced by subdued provenance uplift and rapid basin subsidence. Rapid sedimentation on both these low- and high-gradient alluvial plains, which kept up with subsidence, produced a thermally {open_quotes}cool{close_quotes} basin.

Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1996-12-31T23:59:59.000Z

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341

Miocene fluvial-tidal sedimentation in a residual forearc basin of the Northeastern Pacific Rim: Cook Inlet, Alaska case study  

SciTech Connect (OSTI)

Cook Inlet in southern Alaska represents a Cenozoic residual forearc basin in a convergent continental margin, where the Pacific Plate is being subducted beneath the North American Plate. This basin accumulated the >6,700-m-thick, mainly nonmarine, Eocene-Pliocene Kenai Group. These rocks contain biogenic coal-bed methane estimated to be as high as 245 TCF. Lignites to subbituminous coals with subsurface R[sub o] ranging from 0.38 to 0.73 percent and the stage of clay-mineral diagenesis and expandibility indicate a thermally [open quotes]cool[close quotes] basin. Miocene Tyonek and Beluga Formations compose 65 percent (>4,300 m thick) of the Kenai Group. The Tyonek includes conglomeratic sandstones, siltstones, mudstones, coals, and carbonaceous shales, interpreted as braided- stream deposits. These fluvial deposits are interbecided with burrowed, lenticular, and flaser-bedded sandstones, siltstones, and mudstones, interpreted as tidal deposits. Tyonek framework conglomerates formed in wet alluvial fans incised on paleovalleys of the Chugach terrane. Coal-forming mires are well developed on abandoned braided-stream deposits. Tyonek drainages formed in high-gradient alluvial plains inundated by tides similar to environments in the modern upper Cook Inlet. The upper Miocene Beluga consists of sandstones, siltstones, mudstones, carbonaceous shales, and coals deposited in meandering (low sinuosity) and anastomosed fluvial systems. These fluvial deposits alternated vertically with deposits of coal-forming mires. The Beluga drainages formed in low-gradient alluvial plains. The high-gradient Tyonek alluvial plain was probably controlled by provenance uplift and eustatic change, whereas the low-gradient Beluga alluvial plain was influenced by subdued provenance uplift and rapid basin subsidence. Rapid sedimentation on both these low- and high-gradient alluvial plains, which kept up with subsidence, produced a thermally [open quotes]cool[close quotes] basin.

Stricker, G.D.; Flores, R.M. (Geological Survey, Denver, CO (United States))

1996-01-01T23:59:59.000Z

342

Investigation of mechanisms of ash deposit formation from low-rank coal combustion: Final report  

SciTech Connect (OSTI)

This project was undertaken to determine the chemical behavior of alkali metal and other species implicated in the ash fouling which can occur during the combustion of low rank coals. The coal combustion was studied in unaugmented premixed pulverized coal flames. Vapor species were measured by molecular beam mass spectrometry. Temperatures were also measured, and time-resolved coal/ash particulate samples were collected and analyzed. A major part of the research on this project was devoted to: (1) the development and refinement of techniques for the MBMS analysis of trace quantities of unstable and reactive high temperature vapor species from the pulverized coal flames; and (2) the time-resolved sampling and collection of particulates. The equipment is now operating very satisfactorily. Inorganic species, some of which were present at parts-per-million levels, were quantitatively sampled and measured in the pulverized coal flames. Time-resolved particulate samples which were free of vapor deposited contaminants were collected without the use of an interfering substrate. Profiles of the alkali metal species in Beulah lignite and Decker subbituminous coal flames were obtained. It was found in both flames that sodium is volatilized as the atomic species early (milliseconds) in the combustion process. The gaseous Na reacts, also in milliseconds, to form an unknown species which is probably an oxide fume, but which is not NaOH or Na/sub 2/SO/sub 4/. This is probably the mechanism for the formation of the alkali ''fumes'' observed in other systems. Measurements were also made of a number of other gaseous species, and time-resolved coal/ash samples were obtained and analyzed. 27 refs., 23 figs., 8 tabs.

Greene, F.T.; O'Donnell, J.E.

1987-08-01T23:59:59.000Z

343

Large-Scale Mercury Control Technology Testing for Lignite-Fired Utilities - Oxidation Systems for Wet FGD  

SciTech Connect (OSTI)

Mercury (Hg) control technologies were evaluated at Minnkota Power Cooperative's Milton R. Young (MRY) Station Unit 2, a 450-MW lignite-fired cyclone unit near Center, North Dakota, and TXU Energy's Monticello Steam Electric Station (MoSES) Unit 3, a 793-MW lignite--Powder River Basin (PRB) subbituminous coal-fired unit near Mt. Pleasant, Texas. A cold-side electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber are used at MRY and MoSES for controlling particulate and sulfur dioxide (SO{sub 2}) emissions, respectively. Several approaches for significantly and cost-effectively oxidizing elemental mercury (Hg{sup 0}) in lignite combustion flue gases, followed by capture in an ESP and/or FGD scrubber were evaluated. The project team involved in performing the technical aspects of the project included Babcock & Wilcox, the Energy & Environmental Research Center (EERC), the Electric Power Research Institute, and URS Corporation. Calcium bromide (CaBr{sub 2}), calcium chloride (CaCl{sub 2}), magnesium chloride (MgCl{sub 2}), and a proprietary sorbent enhancement additive (SEA), hereafter referred to as SEA2, were added to the lignite feeds to enhance Hg capture in the ESP and/or wet FGD. In addition, powdered activated carbon (PAC) was injected upstream of the ESP at MRY Unit 2. The work involved establishing Hg concentrations and removal rates across existing ESP and FGD units, determining costs associated with a given Hg removal efficiency, quantifying the balance-of-plant impacts of the control technologies, and facilitating technology commercialization. The primary project goal was to achieve ESP-FGD Hg removal efficiencies of {ge}55% at MRY and MoSES for about a month.

Steven A. Benson; Michael J. Holmes; Donald P. McCollor; Jill M. Mackenzie; Charlene R. Crocker; Lingbu Kong; Kevin C. Galbreath

2007-03-31T23:59:59.000Z

344

Coal preparation: The essential clean coal technology  

SciTech Connect (OSTI)

This chapter is a brief introduction to a broad topic which has many highly specialized areas. The aim is to summarize the essential elements of coal preparation and illustrate its important role in facilitating the clean use of coal. Conventional coal preparation is the essential first step in ensuring the economic and environmentally acceptable use of coal. The aim of coal preparation is to produce saleable products of consistent, specified quality which satisfy customer requirements while optimizing the utilization of the coal resource. Coal preparation covers all aspects of preparing coal for the market. It includes size reduction, blending and homogenization and, most importantly, the process of physical beneficiation or washing, which involves separation of undesirable mineral matter from the coal substance itself. Coal preparation can be performed at different levels of sophistication and cost. The degree of coal preparation required is decided by considering the quality of the raw coal, transport costs and, in particular, the coal quality specified by the consumer. However, the cost of coal beneficiation rises rapidly with the complexity of the process and some coal is lost with the waste matter because of process inefficiencies, therefore each situation requires individual study to determine the optimum coal preparation strategy. The necessary expertise is available within APEC countries such as Australia. Coals destined for iron making are almost always highly beneficiated. Physical beneficiation is mostly confined to the higher rank, hard coals, but all other aspects of coal preparation can be applied to subbituminous and lignitic coals to improve their utilization. Also, there are some interesting developments aimed specifically at reducing the water content of lower rank coals.

Cain, D.

1993-12-31T23:59:59.000Z

345

Upgrading low-rank coals using the liquids from coal (LFC) process  

SciTech Connect (OSTI)

Three unmistakable trends characterize national and international coal markets today that help to explain coal`s continuing and, in some cases, increasing share of the world`s energy mix: the downward trend in coal prices is primarily influenced by an excess of increasing supply relative to increasing demand. Associated with this trend are the availability of capital to expand coal supplies when prices become firm and the role of coal exports in international trade, especially for developing nations; the global trend toward reducing the transportation cost component relative to the market, preserves or enhances the producer`s profit margins in the face of lower prices. The strong influence of transportation costs is due to the geographic relationships between coal producers and coal users. The trend toward upgrading low grade coals, including subbituminous and lignite coals, that have favorable environmental characteristics, such as low sulfur, compensates in some measure for decreasing coal prices and helps to reduce transportation costs. The upgrading of low grade coal includes a variety of precombustion clean coal technologies, such as deep coal cleaning. Also included in this grouping are the coal drying and mild pyrolysis (or mild gasification) technologies that remove most of the moisture and a substantial portion of the volatile matter, including organic sulfur, while producing two or more saleable coproducts with considerable added value. SGI International`s Liquids From Coal (LFC) process falls into this category. In the following sections, the LFC process is described and the coproducts of the mild pyrolysis are characterized. Since the process can be applied widely to low rank coals all around the world, the characteristics of coproducts from three different regions around the Pacific Rim-the Powder River Basin of Wyoming, the Beluga Field in Alaska near the Cook Inlet, and the Bukit Asam region in south Sumatra, Indonesia - are compared.

Nickell, R.E.; Hoften, S.A. van

1993-12-31T23:59:59.000Z

346

Oxidation of Mercury in Products of Coal Combustion  

SciTech Connect (OSTI)

Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

2009-09-14T23:59:59.000Z

347

Final Treatment Center Project for Liquid and Wet Radioactive Waste in Slovakia  

SciTech Connect (OSTI)

The Final Treatment Center (FTC) for Mochovce nuclear power plant (NPP) is designed for treatment and final conditioning of radioactive liquid and wet waste produced from plant operation. Mochovce NNP uses a Russian VVER-440 type reactor. Treated wastes comprise radioactive concentrates, spent resin and sludge. VUJE Inc. as an experienced company in field of treatment of radioactive waste in Slovakia has been chosen as main contractor for technological part of FTC. This paper describes the capacity, flow chart, overall waste flow and parameters of the main components in the FTC. The initial project was submitted for approval to the Slovak Electric plc. in 2003. The design and manufacture of main components were performed in 2004 and 2005. FTC construction work started early in 2004. Initial non-radioactive testing of the system is planned for summer 2006 and then radioactive tests are to be followed. A one-year trial operation of facility is planned for completion in 2007. SE - VYZ will be operates the FTC during trial operation and after its completion. SE - VYZ is subsidiary company of Slovak Electric plc. and it is responsible for treatment with radioactive waste and spent fuel in the Slovak republic. SE - VYZ has, besides of other significant experience with operation of Jaslovske Bohunice Treatment Centre. The overall capacity of the FTC is 870 m{sup 3}/year of concentrates and 40 m{sup 3}/year of spent resin and sludge. Bituminization and cementation were provided as main technologies for treatment of these wastes. Treatment of concentrate is performed by bituminization. Concentrate and bitumen are metered into a thin film evaporator with rotating wiping blades. Surplus water is evaporated and concentrate salts are embedded in bitumen. Bitumen product is discharged into 200 l steel drums. Spent resin and sludge are decanted, dried and mixed with bitumen. These mixtures are also discharged into 200 l steel drums. Drums are moved along bituminization line on a roller conveyor. After the drums cool, they are capped and removed from the conveyor and placed in a storage hall. Drums with bitumen product are loaded into Fiber Reinforced Concrete containers (FRC) and grouted with cement. Cement grout is prepared from mixture of cement, additive and radioactive concentrates. By formulating the cement grout with evaporator concentrates the maximum radioactivity is fixed in cement matrix and volume of final waste product is minimized. A batch mixer with rotating blades is used produce the cement grout. FRCs loaded with bitumen drums are placed on roller conveyor and moved along the cementation line. Grouted FRCs are stored in the expedition hall for 28 days of curing and then transported to final disposal. After placed in operation the FTC provides treatment for all liquid and wet LLW produced from the operation of the Mochovce NPP. The final product of the FTC is a FRC loaded with 7 drums of waste fixed in bitumen and the space between the drums is grouted with cement. This container meets all limits for final disposal in the National Radioactive Waste Repository at Mochovce. (authors)

Kravarik, K.; Stubna, M.; Pekar, A.; Krajc, T.; Zatkulak, M.; Holicka, Z. [VUJE, Inc., Okruzna 5, 918 64 Trnava (Slovakia); Slezak, M. [SE - VYZ, 919 31 Jaslovske Bohunice (Slovakia)

2006-07-01T23:59:59.000Z

348

Process performance of Ahlstrom Pyroflow PCFB pilot plant  

SciTech Connect (OSTI)

Ahlstrom Pyropower has designed and built a 10 MW{sub th} (34 MMBtu) pressurized circulating fluidized bed (PCFB) pilot plant in Karhula, Finland. The unit is now operating. Data from this unit supports the design of a nominal 80 MW, Des Moines Energy Center 1 (DMEC-1) PCFB Repowering Project. The pilot plant PCFB combustor is of square cross-section. It is housed in a 3.6 m (11.8 ft) diameter pressure vessel. A high pressure high temperature gas cleaning unit downstream of the PCFB exhaust is installed in a separate 2.6 m (8.5 ft) diameter pressure vessel. The maximum plant operating pressure is 16 bar (232 psia). The fuel is fed in slurry form; sorbent is also fed along with the fuel. The net heat input per unit cross section of the combustor is the highest of any known combustion mode. The heat release can go up to 40 MW/m{sup 2} (12.6 MMBtu/ft{sup 2} hr). Many types of coals including high sulfur, bituminous Illinois No. 6 coal and Western sub bituminous, low sulfur Powder River Basin coal were tested. Combustion efficiencies in the range of 99.5 to 99.9% have been consistently observed. Emissions of various gases such as NO{sub x} SO{sub 2} and CO at different operating pressures and loads were monitored. The gas emissions have been lower than expected based on atmospheric circulating fluidized bed boiler experience. The sulfur retention is over 95 % with a Ca/S molar ratio of 1 to 2 for high sulfur Illinois No.6 coal. A GAVS molar ratio of 2.5 to 3.5 was observed to retain 95 % of sulfur with low sulfur Powder River Basin coal. All gaseous emissions during testing with Illinois No. 6 coal and Powder River Basin coal are well within the projected limits for the DMEC1 project. Emission data from tests with Illinois No. 6 coal and Powder River Basin coal are presented in the paper.

Sellakumar, K.M. [R& D Center, Ahlstrom Pyropower, Inc., San Diego, CA (United States); Isaksson, J.; Tiensuu, J. [Ahlstroem Pyropower, Inc., Karhula (Finland). Hans Ahlstroem Lab.

1993-05-01T23:59:59.000Z

349

Process performance of Ahlstrom Pyroflow PCFB pilot plant  

SciTech Connect (OSTI)

Ahlstrom Pyropower has designed and built a 10 MW[sub th] (34 MMBtu) pressurized circulating fluidized bed (PCFB) pilot plant in Karhula, Finland. The unit is now operating. Data from this unit supports the design of a nominal 80 MW, Des Moines Energy Center 1 (DMEC-1) PCFB Repowering Project. The pilot plant PCFB combustor is of square cross-section. It is housed in a 3.6 m (11.8 ft) diameter pressure vessel. A high pressure high temperature gas cleaning unit downstream of the PCFB exhaust is installed in a separate 2.6 m (8.5 ft) diameter pressure vessel. The maximum plant operating pressure is 16 bar (232 psia). The fuel is fed in slurry form; sorbent is also fed along with the fuel. The net heat input per unit cross section of the combustor is the highest of any known combustion mode. The heat release can go up to 40 MW/m[sup 2] (12.6 MMBtu/ft[sup 2] hr). Many types of coals including high sulfur, bituminous Illinois No. 6 coal and Western sub bituminous, low sulfur Powder River Basin coal were tested. Combustion efficiencies in the range of 99.5 to 99.9% have been consistently observed. Emissions of various gases such as NO[sub x] SO[sub 2] and CO at different operating pressures and loads were monitored. The gas emissions have been lower than expected based on atmospheric circulating fluidized bed boiler experience. The sulfur retention is over 95 % with a Ca/S molar ratio of 1 to 2 for high sulfur Illinois No.6 coal. A GAVS molar ratio of 2.5 to 3.5 was observed to retain 95 % of sulfur with low sulfur Powder River Basin coal. All gaseous emissions during testing with Illinois No. 6 coal and Powder River Basin coal are well within the projected limits for the DMEC1 project. Emission data from tests with Illinois No. 6 coal and Powder River Basin coal are presented in the paper.

Sellakumar, K.M. (R D Center, Ahlstrom Pyropower, Inc., San Diego, CA (United States)); Isaksson, J.; Tiensuu, J. (Ahlstroem Pyropower, Inc., Karhula (Finland). Hans Ahlstroem Lab.)

1993-05-01T23:59:59.000Z

350

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN CO-FIRING BIOMASS WITH COAL  

SciTech Connect (OSTI)

This is the seventh Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. Two additional biomass co-firing test burns were conducted during this quarter. In the first test (Test 12), up to 20% by weight dry hardwood sawdust and switchgrass was comilled with Galatia coal and injected through the single-register burner. Liquid ammonia was intermittently added to the primary air stream to increase fuel-bound nitrogen and simulate cofiring with chicken litter. Galatia coal is a medium-sulfur ({approx} 1.2% S), high chlorine ({approx}0.5%) Illinois Basin coal. In the second test (Test 13), up to 20% by weight dry hardwood sawdust and switchgrass was comilled with Jim Walters No.7 mine coal and injected through the single-register burner. Jim Walters No.7 coal is a low-volatility, low-sulfur ({approx} 0.7% S) Eastern bituminous coal. The results of these tests are presented in this quarterly report. Progress has continued to be made in implementing a modeling approach to combine reaction times and temperature distributions from computational fluid dynamic models of the pilot-scale combustion furnace with char burnout and chemical reaction kinetics to predict NO{sub x} emissions and unburned carbon levels in the furnace exhaust. The Configurable Fireside Simulator has been delivered from REI, Inc. and is being tested with exiting CFD solutions. Preparations are under way for a final pilot-scale combustion experiment using the single-register burner fired with comilled mixtures of Jim Walters No.7 low-volatility bituminous coal and switchgrass. Because of the delayed delivery of the Configurable Fireside Simulator, it is planned to ask for a no-cost time extension for the project until the end of this calendar year. Finally, a paper describing this project that included preliminary results from the first four cofiring tests was presented at the 12th European Conference and Technology Exhibition on Biomass for Energy, Industry and Climate Protection in Amsterdam, The Netherlands, in June, 2002.

Larry G. Felix; P. Vann Bush

2002-07-01T23:59:59.000Z

351

Update on use of mine pool water for power generation.  

SciTech Connect (OSTI)

In 2004, nearly 90 percent of the country's electricity was generated at power plants using steam-based systems (EIA 2005). Electricity generation at steam electric plants requires a cooling system to condense the steam. With the exception of a few plants using air-cooled condensers, most U.S. steam electric power plants use water for cooling. Water usage occurs through once-through cooling or as make-up water in a closed-cycle system (generally involving one or more cooling towers). According to a U.S. Geological Survey report, the steam electric power industry withdrew about 136 billion gallons per day of fresh water in 2000 (USGS 2005). This is almost the identical volume withdrawn for irrigation purposes. In addition to fresh water withdrawals, the steam electric power industry withdrew about 60 billion gallons per day of saline water. Many parts of the United States are facing fresh water shortages. Even areas that traditionally have had adequate water supplies are reaching capacity limits. New or expanded steam electric power plants frequently need to turn to non-traditional alternate sources of water for cooling. This report examines one type of alternate water source-groundwater collected in underground pools associated with coal mines (referred to as mine pool water in this report). In 2003, the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) funded Argonne National Laboratory (Argonne) to evaluate the feasibility of using mine pool water in Pennsylvania and West Virginia. That report (Veil et al. 2003) identified six small power plants in northeastern Pennsylvania (the Anthracite region) that had been using mine pool water for over a decade. It also reported on a pilot study underway at Exelon's Limerick Generating Station in southeastern Pennsylvania that involved release of water from a mine located about 70 miles upstream from the plant. The water flowed down the Schuylkill River and augmented the natural flow so that the Limerick plant could withdraw a larger volume of river water. The report also included a description of several other proposed facilities that were planning to use mine pool water. In early 2006, NETL directed Argonne to revisit the sites that had previously been using mine pool water and update the information offered in the previous report. This report describes the status of mine pool water use as of summer 2006. Information was collected by telephone interviews, electronic mail, literature review, and site visits.

Veil, J. A.; Puder, M. G.; Environmental Science Division

2006-09-30T23:59:59.000Z

352

INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS  

SciTech Connect (OSTI)

This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

2000-11-01T23:59:59.000Z

353

Development and evaluation of coal/water mixture combustion technology. Final report  

SciTech Connect (OSTI)

The objective was to advance the technology for the preparation, storage, handling and combustion of highly-loaded coal/water mixtures. A systematic program to prepare and experimentally evaluate coal/water mixtures was conducted to develop mixtures which (1) burn efficiently using combustion chambers and burners designed for oil, (2) can be provided at a cost less than that of No. 6 oil, and (3) can be easily transported and stored. The program consisted of three principal tasks. The first was a literature survey relevant to coal/water mixture technology. The second involved slurry preparation and evaluation of rheological and stability properties, and processing techniques. The third consisted of combustion tests to characterize equipment and slurry parameters. The first task comprised a complete search of the literature, results of which are tabulated in Appendix A. Task 2 was involved with the evaluation of composition and process variables on slurry rheology and stability. Three bituminous coals, representing a range of values of volatile content, ash content, and hardness were used in the slurries. Task 3 was concerned with the combustion behavior of coal/water slurry. The studies involved first upgrading of an experimental furnace facility, which was used to burn slurry fuels, with emphasis on studying the effect on combustion of slurry properties such as viscosity and particle size, and the effect of equipment parameters such as secondary air preheat and atomization.

Scheffee, R.S.; Rossmeissl, N.P.; Skolnik, E.G.; McHale, E.T.

1981-08-01T23:59:59.000Z

354

The methods of steam coals usage for coke production  

SciTech Connect (OSTI)

Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

1998-07-01T23:59:59.000Z

355

Determination of the effects caused by different polymers on coal fluidity during carbonization using high-temperature {sup 1}H NMR and rheometry  

SciTech Connect (OSTI)

The effects of blending polyethylene (PE), polystyrene (PS), poly(ethyleneterephthalate) (PET), a flexible polyurethane (FPU), and a car shredded fluff waste (CSF) on fluidity development of a bituminous coal during carbonization have been studied by means of high-torque, small-amplitude controlled-strain rheometry and in situ high-temperature {sup 1}H NMR spectroscopy. The most detrimental effects were caused by PET and PS, which completely destroyed the fluidity of the coal. The CSF had a deleterious effect on coal fluidity similar to that of PET, although the deleterious effect on the viscoelastic properties of the coal were less pronounced than those of PET and PS. On the contrary, the addition of 10 wt % PE caused a slight reduction in the concentration of fluid hydrogen and an increase in the minimum complex viscosity, and the addition of 10 wt % FPU reduced the concentration of fluid hydrogen without changing the viscoelastic properties of the coal. Although these results suggest that these two plastics could potentially be used as additives in coking blends without compromising coke porosity, it was found that the semicoke strengths were reduced by adding 2 wt % FPU and 5 wt % PE. Therefore, it is unlikely that more than 2 wt % of a plastic waste could be added to a coal blend without deterioration in coke quality. 35 refs., 11 figs., 3 tabs.

Miguel Castro Diaz; Lucky Edecki; Karen M. Steel; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2008-01-15T23:59:59.000Z

356

Task 27 -- Alaskan low-rank coal-water fuel demonstration project  

SciTech Connect (OSTI)

Development of coal-water-fuel (CWF) technology has to-date been predicated on the use of high-rank bituminous coal only, and until now the high inherent moisture content of low-rank coal has precluded its use for CWF production. The unique feature of the Alaskan project is the integration of hot-water-drying (HWD) into CWF technology as a beneficiation process. Hot-water-drying is an EERC developed technology unavailable to the competition that allows the range of CWF feedstock to be extended to low-rank coals. The primary objective of the Alaskan Project, is to promote interest in the CWF marketplace by demonstrating the commercial viability of low-rank coal-water-fuel (LRCWF). While commercialization plans cannot be finalized until the implementation and results of the Alaskan LRCWF Project are known and evaluated, this report has been prepared to specifically address issues concerning business objectives for the project, and outline a market development plan for meeting those objectives.

NONE

1995-10-01T23:59:59.000Z

357

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

358

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 10, February 17--May 31, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). One of the two flue gas ducts leading from the boiler has been retrofitted with the CZD technology. The first existing ESP installed in the station is immediately behind the air preheater. The second ESP, installed about 15 years ago, is about 80 feet away from the first ESP. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2}

Not Available

1993-11-15T23:59:59.000Z

359

Studies of the combustion of coal/refuse derived fuels using thermogravimetric-Fourier transform infrared-mass spectrometry  

SciTech Connect (OSTI)

The materials used in this project included two bituminous coals, a medium molecular weight PVC resin, cellulose, and shredded newspaper. Analytical data for the samples are given. A TA Instruments Model 951 Thermogravimetric Analyzer (TG) interfaced to a Perkin Elmer 1650 Fourier Transform Infrared Spectrometer (FTIR) was used in this study. The horizontal quartz furnace of the TG was connected to the 10 cm gas cell of the FTIR using an insulated teflon tube heated to a temperature of 150{degrees}C. The TG was also interfaced to a VG Thermolab Mass Spectrometer (MS) using a fused silica capillary sampling tube heated to approximately 170{degrees}C. A teflon splitter divides the gases from the TG into two parts, one to the FTIR ({approximately}95%), and the other to the MS ({approximately}5%). A schematic of the TG-FTIR-MS system, is presented. In the TG experiments, all samples ({approximately}300 mg each) were heated in air (50 ML/min) at a rate of 10{degrees}C/min to 700{degrees}C. The spectra and profiles of gaseous species evolving from the TG system were recorded and analyzed by the TGA-FTIR-MS analytical system. The results of the experiments are given.

Lu, H.; Li, J.; Lloyd, W.G. [and others

1995-08-01T23:59:59.000Z

360

H-coal liquefaction: moving toward commercial reality  

SciTech Connect (OSTI)

The successful operation of the H-Coal pilot plant has allowed Ashland management to vigorously pursue the option to build a commercial plant. Ashland Synthetic Fuels has applied to the United States Synthetic Fuels Corporation for a loan guarantee to construct a commercial H-Coal liquefaction facility in Breckinridge County, Kentucky. Ashland would like to develop this project with four other partners. In November 1981, Bechtel Inc., joined Ashland in the development of the Breckinridge Project. Under this recent agreement, the two companies will cooperate to prepare a detailed project cost estimate, an environmental impact statement, secure the necessary permits, and form a joint venture group to facilitate the involvement of other companies to develop this facility. The future of the Breckinridge project depends completely on the United States Synthetic Fuels Corporation. If this government agency declines to supply the loan guarantees for this project there is little chance the facility will be built. Capital requirements have been estimated at $5,200,000,000. The proposed Breckinridge liquefaction facility would process 18,500 tons of high-sulphur bituminous coal per day and produce 50,000 barrels per day of liquid product.

Schneiderman, S.J.

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Modeling the behavior of selenium in Pulverized-Coal Combustion systems  

SciTech Connect (OSTI)

The behavior of Se during coal combustion is different from other trace metals because of the high degree of vaporization and high vapor pressures of the oxide (SeO{sub 2}) in coal flue gas. In a coal-fired boiler, these gaseous oxides are absorbed on the fly ash surface in the convective section by a chemical reaction. The composition of the fly ash (and of the parent coal) as well as the time-temperature history in the boiler therefore influences the formation of selenium compounds on the surface of the fly ash. A model was created for interactions between selenium and fly ash post-combustion. The reaction mechanism assumed that iron reacts with selenium at temperatures above 1200 C and that calcium reacts with selenium at temperatures less than 800 C. The model also included competing reactions of SO{sub 2} with calcium and iron in the ash. Predicted selenium distributions in fly ash (concentration versus particle size) were compared against measurements from pilot-scale experiments for combustion of six coals, four bituminous and two low-rank coals. The model predicted the selenium distribution in the fly ash from the pilot-scale experiments reasonably well for six coals of different compositions. (author)

Senior, Constance; Otten, Brydger Van; Wendt, Jost O.L.; Sarofim, Adel [Reaction Engineering International, 77 W. 200 South, Salt Lake City, UT 84101 (United States)

2010-11-15T23:59:59.000Z

362

Use of a predictive model for the impact of cofiring coal/biomass blends on slagging and fouling propensity  

SciTech Connect (OSTI)

The paper describes an investigation of slagging and fouling effects when cofiring coal/biomass blends by using a predictive model for large utility boilers. This model is based on the use a zone computational method to determine the midsection temperature profile throughout a boiler, coupled with a thermo-chemical model, to define and assess the risk of elevated slagging and fouling levels during cofiring of solid fuels. The application of this prediction tool was made for a 618 MW thermal wall-fired pulverized coal boiler, cofired with a typical medium volatile bituminous coal and two substitute fuels, sewage sludge and sawdust. Associated changes in boiler efficiency as well as various heat transfer and thermodynamic parameters of the system were analyzed with slagging and fouling effects for different cofiring ratios. The results of the modeling revealed that, for increased cofiring of sewage sludge, an elevated risk of slagging and high-temperature fouling occurred, in complete contrast to the effects occurring with the utilization of sawdust as a substitute fuel. 30 refs., 9 figs.,1 tab.

Piotr Plaza; Anthony J. Griffiths; Nick Syred; Thomas Rees-Gralton [Cardiff University, Cardiff (United Kingdom). Centre for Research in Energy

2009-07-15T23:59:59.000Z

363

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

Kenneth E. Baldrey

2002-05-01T23:59:59.000Z

364

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a flue gas conditioning system was completed at PacifiCorp Jim Bridger Power Plant. Performance testing was underway. Results will be detailed in the next quarterly and subsequent technical summary reports. Also in this quarter, discussions were initiated with a prospective long-term candidate plant. This plant fires a bituminous coal and has opacity performance issues related to fly ash re-entrainment. Ammonia conditioning has been proposed here, but there is interest in liquid additives as a safer alternative.

Kenneth E. Baldrey

2002-01-01T23:59:59.000Z

365

Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels  

SciTech Connect (OSTI)

This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

Steven Markovich

2010-06-30T23:59:59.000Z

366

Co-production of electricity and alternate fuels from coal. Final report, August 1995  

SciTech Connect (OSTI)

The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

NONE

1995-12-31T23:59:59.000Z

367

Use of molecular modeling to determine the interaction and competition of gases within coal for carbon dioxide sequestration  

SciTech Connect (OSTI)

Molecular modeling was employed to both visualize and probe our understanding of carbon dioxide sequestration within a bituminous coal. A large-scale (>20,000 atoms) 3D molecular representation of Pocahontas No. 3 coal was generated. This model was constructed based on a the review data of Stock and Muntean, oxidation and decarboxylation data for aromatic clustersize frequency of Stock and Obeng, and the combination of Laser Desorption Mass Spectrometry data with HRTEM, enabled the inclusion of a molecular weight distribution. The model contains 21,931 atoms, with a molecular mass of 174,873 amu, and an average molecular weight of 714 amu, with 201 structural components. The structure was evaluated based on several characteristics to ensure a reasonable constitution (chemical and physical representation). The helium density of Pocahontas No. 3 coal is 1.34 g/cm{sup 3} (dmmf) and the model was 1.27 g/cm{sup 3}. The structure is microporous, with a pore volume comprising 34% of the volume as expected for a coal of this rank. The representation was used to visualize CO{sub 2}, and CH{sub 4} capacity, and the role of moisture in swelling and CO{sub 2}, and CH{sub 4} capacity reduction. Inclusion of 0.68% moisture by mass (ash-free) enabled the model to swell by 1.2% (volume). Inclusion of CO{sub 2} enabled volumetric swelling of 4%.

Jeffrey D. Evanseck; Jeffry D. Madura; Jonathan P. Mathews

2006-04-21T23:59:59.000Z

368

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 9, November 17, 1992--February 16, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically on electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The waste product is composed of magnesium and calcium sulfite and sulfate, with some excess lime. This product mixed with fly ash is self-stabilizing because of the excess lime values, and thus tends to retain heavy metals in insoluble forms within the fly ash. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). Progress is described for the ninth quarter.

Not Available

1993-10-01T23:59:59.000Z

369

The effect of water temperature on the adsorption equilibrium of dissolved organic matter and atrazine on granular activated carbon  

SciTech Connect (OSTI)

The influence of water temperature on the adsorption of natural dissolved organic matter (DOM) on activated carbon has not been investigated intensively yet. In this study, batch experiments with granular activated carbon (GAC) F300, from bituminous coal, have been carried out at three temperatures (5, 20, 35{sup o} C) using a humic acid model water and different types of surface water (lake, river, canal). Furthermore, the adsorption of an anthropogenic contaminant, atrazine, was quantified in the absence and presence of DOM. The results indicate a significant influence of water temperature on the adsorption equilibrium of DOM and atrazine. Contrary to expectations, DOM and atrazine adsorption in surface water tends to be increased with increasing water temperature, whereas the extent of this effect is dependent on the type and concentration of DOM. Furthermore, the temperature effect on atrazine adsorption is controlled by competition of DOM and atrazine on adsorption sites. Some assumptions are proposed and discussed for explaining the temperature effects observed in the batch studies. 39 refs., 4 figs., 2 tabs.

Bernd Schreiber; Viktor Schmalz; Thomas Brinkmann; Eckhard Worch [Dresden University of Technology, Dresden (Germany). Institute of Water Chemistry

2007-09-15T23:59:59.000Z

370

TVA`s Cumberland Units 1&2 SO{sub 2} removal system - an update  

SciTech Connect (OSTI)

Tennessee Valley Authority`s Cumberland Fossil Plant (CUF) is a Phase I facility listed under the 1990 CAA Amendments. Units 1 & 2 are two 1300 MWe coal fired units which presently bum an eastern bituminous coal containing approximately 2.8% sulfur. The Flue Gas Desulfurization (FGD) system reduces sulfur dioxide (SO{sub 2}) emissions from Units 1 and 2 by means of wet limestone - forced oxidation scrubbing. The absorber modules were provided by ABB Environmental Systems (ABBES) with balance of plant engineering, construction management, and startup provided by Raytheon Engineers and Constructors (RE&C) under a partnership arrangement with TVA. The FGD systems for Unit 1 & 2 were brought on-line October 12, 1994 and December 14, 1994, respectively. This paper will present a brief description of the overall project, the design basis, challenging problems and solutions during construction and initial startup. Specific topics will include: (1) Optimization studies underway; (2) Unique design aspects of the facility; (3) A description of the absorber and supporting systems including the limestone barge unloader, ball mill system for reagent preparation, and draft system upgrades; and (4) Experience gained in management of a large project under the unique partnership agreement.

Buckner, J.H. [Tennessee Valley Authority, Chattanooga, TN (United States); Brodsky, I.S. [Raytheon Engineers & Constructors, Philadelphia, PA (United States); Muraskin, D.J. [ABB Environmental Systems, Birmingham, AL (United States)

1995-06-01T23:59:59.000Z

371

Biological removal of organic constituents in quench waters from high-Btu coal-gasification pilot plants  

SciTech Connect (OSTI)

Studies were initiated to assess the efficiency of bench-scale, activated-sludge treatment for removal of organic constituents from coal-gasification process effluents. Samples of pilot-plant, raw-gas quench waters were obtained from the HYGAS process of the Institute of Gas Technology and from the slagging, fixed-bed (SFB) process of the Grand Forks Energy Technology Center. The types of coal employed were Bituminous Illinois No. 6 for the HYGAS and Indian Head lignite for the SFB process. These pilot-plant quench waters, while not strictly representative of commercial condensates, were considered useful to evaluate the efficiency of biological oxidation for the removal of organics. Biological-reactor influent and effluent samples were extracted using a methylene chloride pH-fractionation method into acid, base, and neutral fractions, which were analyzed by capillary-column gas-chromatography/mass-spectrometry. Influent acid fractions of both HYGAS and SFB condensates showed that nearly 99% of extractable and chromatographable organic material comprised phenol and alkylated phenols. Activated-sludge treatment removed these compounds almost completely. Removal efficiency of base-fraction organics was generally good, except for certain alkylated pyridines. Removal of neutral-fraction organics was also good, except for certain alkylated benzenes, certain polycyclic aromatic hydrocarbons, and certain cycloalkanes and cycloalkenes, especially at low influent concentrations.

Stamoudis, V C; Luthy, R G

1980-02-01T23:59:59.000Z

372

Correlation method for chemical communication of coal  

SciTech Connect (OSTI)

In spite of many experimental studies of the chemical comminution of coal, there have been only a few reported attempts to correlate experimental data and mathematically model the process. This paper presents a strain energy model based on the thermodynamic analysis. The capillary-imbibition number is proposed as an important parameter for characterization of chemicals used in comminution. The authors discuss the development of a phenomenological model for chemical comminution to study the relative effects of the governing process. Sensitivity studies carried out with this model indicated that the mechanism of chemical transfer into bedding planes and comminution of coal is dominantly a capillary-imbibition-induced flow phenomenon and to a lesser extent a diffusion-controlled process. The authors also tested this hypothesis using experimental data. As reported, the maximum comminution rates for the middle Pennsylvania Cherokee C-bituminous coal with NaOH solutions were within the range of 6-8% caustic concentration. Hence, it is concluded that this contradicts the author's earlier work (1988), which reported that capillary-imbibition number (reciprocal of the surface-tension number) decreases with increasing caustic concentration. This conclusion is misleading because the authors simply present a set of data on capillary-imbibition number vs NaOH concentration, and it alone cannot determine the caustic concentration for the maximum comminution rate.

Civan, F.; Knapp, R.M. (School of Petroleum and Geological Engineering, Univ. of Oklahoma, Norman, OK (US))

1991-06-01T23:59:59.000Z

373

Deep coal resources in the Cherokee Group (middle Pennsylvanian) in eastern Kansas  

SciTech Connect (OSTI)

Evaluation of over 800 gamma-ray/density and gamma-ray/neutron logs run for oil and gas tests in eastern Kansas shows a wide distribution of coal in the Cherokee Group in this area. With nearly 300 million tons (270 million metric tons) of high-volatile bituminous coal produced in southeastern Kansas, this group was important for further evaluation. Studies of the coals in the Cherokee Group too deep to strip mine in the Cherokee basin and the Forest City basin indicate a coal resource of nearly 50 billion tons (45 billion metric tons). This figure represents coal from 27 different coal beds in the three reliability categories of measured, indicated, and inferred. Most of the coal is recognized as thin bedded (< 28 in. or < 70 cm) like most of the coal beds in the outcrop belt in southeastern Kansas. Six coals beds with a total of over 1.4 billion tons (1.3 billion metric tons) of resources are present where coal thicknesses exceed 42 in. (105 cm) in parts of 12 different counties. Resource quantities of the Cherokee Group coal beds were made using Pacer and Garnet software developed for the National Coal Resources Data System (NCRDS) of the US Geological Survey.

Brady, L.L.; Livingston, N.D.

1989-03-01T23:59:59.000Z

374

Upgraded coal interest group. First quarterly technical progress report, October 1, 1994--December 31, 1994  

SciTech Connect (OSTI)

The interest group got under way effective January 1, 1994, with nine utility members, EPRI, Bechtel, and the Illinois Clean Coal Institute. DOE participation was effective October 1, 1994. The first meeting was held on April 22, 1994 in Springfield, Illinois and the second meeting was held on August 10--11, 1994 at Johnstown, Pennsylvania. Technical reviews were prepared in several areas, including the following: status of low rank coal upgrading, advanced physical coal cleaning, organic sulfur removal from coal, handling of fine coal, combustion of coal water slurries. It was concluded that, for bituminous coals, processing of fines from coal cleaning plants or impoundments was going to be less costly than processing of coal, since the fines were intrinsically worth less and advanced upgrading technologies require fine coal. Penelec reported on benefits of NOX reductions when burning slurry fuels. Project work was authorized in the following areas: Availability of fines (CQ, Inc.), Engineering evaluations (Bechtel), and Evaluation of slurry formulation and combustion demonstrations (EER/MATS). The first project was completed.

Weber, W. [Electric Power Research Inst., Chattanooga, TN (United States); Lebowitz, H.E. [Fossil Fuel Sciences, Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

375

Fate of trace elements in UK coals during gasification processes  

SciTech Connect (OSTI)

Five UK coals were selected to cover the range of mineral matter and ash contents typically encountered in UK bituminous coals. Trace element analysis was performed on both the whole coals and size separated fractions using ICP analysis for 21 trace elements, including Be, Cr, Co, Ni, As, Cd, Sb, Hg, and Pb, elements deemed to be the most environmentally hazardous. Small quantities of each coal were gasified in a laboratory gasifier in an atmosphere of N{sub 2} containing 15% O{sub 2}. Samples of bed ash, cyclone ash, and a fine gas-filtered ash were collected and analyzed to determine the partition of the trace elements between the gasification products. Mass balance calculations showed that the recovery of the trace elements varied from 20 to 97%; the low recovery of some trace elements highlighting the difficulties of collecting representative samples from a laboratory system. A parallel study on samples taken from a pilot plant gasifier showed significantly higher recovery rates, indicating the value of larger scale trials.

Bushell, A.J.; Williamson, J. [Imperial College of Science, Technology and Medicine, London (United Kingdom)

1996-12-31T23:59:59.000Z

376

Hydrothermal reactions of fly ash. Final report  

SciTech Connect (OSTI)

The emphasis of the work done has been to determine the reactivities of two ashes believed to be representative of those generated. A bituminous ash and a lignitic ash have been investigated. The reactions of these ashes undergo when subjected to mild hydrothermal conditions were explored. The nature of the reactions which the ashes undergo when alkaline activators, calcium hydroxide and calcium sulfate are present was also investigated. It was determined that calcium silicate hydrate, calcium aluminate hydrate, and the calcium sulfoaluminate hydrate ettringite form under these conditions. It appears 3CaO{center_dot}Al{sub 2}O{sub 3}{center_dot}3CaSO{sub 4}{center_dot}32H{sub 2}O (ettringite) formation needs to be considered in ashes which contain significant amounts of sulfate. Therefore the stability region for ettringite was established. It was also determined that calcium silicate hydrate, exhibiting a high internal surface area, will readily form with hydrothermal treatment between 50{degrees} and 100{degrees}C. This phase is likely to have a significant capacity to take up heavy metals and oxyanions and this ability is being explored.

Brown, P.W.

1995-12-31T23:59:59.000Z

377

National Coal Quality Inventory (NACQI)  

SciTech Connect (OSTI)

The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

Robert Finkelman

2005-09-30T23:59:59.000Z

378

Engineering Development of Advanced Physical Fine Coal Cleaing for Premium Fuel Applications  

SciTech Connect (OSTI)

The ash in six common bituminous coals, Taggart, Winifrede, Elkhorn No. 3, Indiana VII, Sunnyside and Hiawatha, could be liberated by fine grinding to allow preparation of clean coal meeting premium fuel specifications (< 1- 2 lb/ MBtu ash and <0.6 lb/ MBtu sulfur) by laboratory and bench- scale column flotation or selective agglomeration. Over 2,100 tons of coal were cleaned in the PDU at feed rates between 2,500 and 6,000 lb/ h by Microcel? column flotation and by selective agglomeration using recycled heptane as the bridging liquid. Parametric testing of each process and 72- hr productions runs were completed on each of the three test coals. The following results were achieved after optimization of the operating parameters: The primary objective was to develop the design base for commercial fine coal cleaning facilities for producing ultra- clean coals which can be converted into coal-water slurry premium fuel. The coal cleaning technologies to be developed were advanced column flotation and selective agglomeration, and the goal was to produce fuel meeting the following specifications -- Less than 2 pounds of ash per million Btu (860 grams per gigajoule) and

Frank J. Smit; Gene L. Schields; Mehesh C. Jha; Nick Moro

1997-09-26T23:59:59.000Z

379

Geochemistry of coal from Cretaceous Corwin and Chandler formations, National Petroleum Reserve in Alaska (NPRA)  

SciTech Connect (OSTI)

Ninety coal samples from these formations within NPRA were collected and analyzed in order to evaluate coal quality and elemental distribution. Their apparent rank ranges from lignite A in the northern part of NPRA to high-volatile AS bituminous coal in the southern part. Mean vitrinite reflectance values range from 0.65 to 0.74%. Some Corwin Formation coal samples west of NPRA have coking potential with free-swelling indexes between 3.0 and 5.0. Compared to other western United States Cretaceous coal, NPRA coal is significantly lower in ash, volatile matter, O, Si, Al, Ca, Fe, Ti, Cu, F, Li, Mn, Mo, Pb, Sb, Se, Th, and Zn. Statistical comparisons of element concentrations indicate that the mean content of Si, Al, K, Li, Sc, Y, and Yb increases as the mean ash content increases (correlation coefficient at least 0.7). Sulfur values are extremely low (0.1%), and elements that normally show positive correlation with sulfur, such as Fe, As, Cd, Co, Cu, Mo, Pb, and Zn, are also low. Therefore, coal from NPRA can be characterized by low ash and sulfur contents and low contents of elements of environmental concern, such as As, Be, Hg, Mo, Sb, and Se. The elements found to have positive correlations with ash content are probably present as aluminosilicate or stable oxide minerals. Variations in element content and quality of NPRA coal were probably influenced by the geochemical conditions that existed in the Corwin and Umiat delta systems.

Affolter, R.H.; Stricker, G.D.

1985-04-01T23:59:59.000Z

380

Coal Reburning for Cyclone Boiler NO{sub x} Control Demonstration. Quarterly report No. 10, July--September 1992  

SciTech Connect (OSTI)

The Coal Reburning for Cyclone Boiler NO{sub x}, Control Demonstration project progress for July, August, and September 1992 is identified in this tenth quarterly report and pertains to the on-going activities of Phase III Operation and Disposition. The project involves retrofitting/testing the reburning technology at Wisconsin Power & Light`s 100 MWe Nelson Dewey Unit {number_sign}2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO{sub x} emission levels. Phase III activities emphasized continuation of long-term testing. WP&L is operating the reburn system in full automatic in a load following mode, using Lamar coal, which is an Indiana bituminous medium sulfur content fuel. Reductions in NO{sub x} emissions continue at the 50%+ level with no apparent significant adverse impacts to boiler operation. As of the end of September, a second set of performance tests were initiated to determine if any performance impacts as a result of long-term operation have occurred. Data evaluation continued in an effort to design a testing sequence to more precisely evaluate reburn impact on unburned carbon. These tests will be carried out during the second set of performance tests in early October. Performance and mathematical modeling are being carried out to understand the cause of the reduction in furnace exit gas temperature observed during reburn testing on Lamar coal and to predict whether the same phenomenon will occur on future units where reburn technology is being considered.

Not Available

1992-12-18T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Coal Reburning for Cyclone Boiler NO[sub x] Control Demonstration  

SciTech Connect (OSTI)

The Coal Reburning for Cyclone Boiler NO[sub x], Control Demonstration project progress for July, August, and September 1992 is identified in this tenth quarterly report and pertains to the on-going activities of Phase III Operation and Disposition. The project involves retrofitting/testing the reburning technology at Wisconsin Power Light's 100 MWe Nelson Dewey Unit [number sign]2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO[sub x] emission levels. Phase III activities emphasized continuation of long-term testing. WP L is operating the reburn system in full automatic in a load following mode, using Lamar coal, which is an Indiana bituminous medium sulfur content fuel. Reductions in NO[sub x] emissions continue at the 50%+ level with no apparent significant adverse impacts to boiler operation. As of the end of September, a second set of performance tests were initiated to determine if any performance impacts as a result of long-term operation have occurred. Data evaluation continued in an effort to design a testing sequence to more precisely evaluate reburn impact on unburned carbon. These tests will be carried out during the second set of performance tests in early October. Performance and mathematical modeling are being carried out to understand the cause of the reduction in furnace exit gas temperature observed during reburn testing on Lamar coal and to predict whether the same phenomenon will occur on future units where reburn technology is being considered.

Not Available

1992-12-18T23:59:59.000Z

382

Thermoeconomic design optimization of a KRW-based IGCC power plant  

SciTech Connect (OSTI)

This report discussed the cost and efficiency optimization of an integrated gasification-combined-cycle (IGCC) power plant design and the effects of important design options and parameters. Advanced thermoeconomic techniques were used to evaluate and optimize a given IGCC concept which uses Illinois No. 6 bituminous coal, air-blown KRW coal gasifiers, a hot gas cleanup system, and GE MS7001F gas turbines. Three optimal design concepts are presented and discussed in the report. Two of the concepts are characterized by minimum cost of electricity at two different values of the steam high pressure. The third concept represents the thermodynamic optimum. This study identified several differences between the original design and the design of the optimized cases. Compared with the original concept, significant annual savings are achieved in the cost optimal cases. Comparisons were made between results obtained using both the old and the new performance data for the MS7001F gas turbine. This report discusses the effects of gasification temperature, steam high pressure, coal moisture, and various design options on the overall plant efficiency and cost of electricity. Cost sensitivity studies were conducted and recommendations for future studies were made.

Tsatsaronis, G.; Lin, L.; Pisa, J.; Tawfik, T. (Tennessee Technological Univ., Cookeville, TN (United States). Center for Electric Power)

1991-11-01T23:59:59.000Z

383

Comparison of salient features of alternative CO{sub 2} recovery processes  

SciTech Connect (OSTI)

In the case of direct coal combustion, the recovery of carbon dioxide (CO{sub 2}) is complicated by dilution of the flue gas with nitrogen (N{sub 2}) from the combustion air, as well as with excess air, which invariably accompanies coal combustion. For a representative boiler using bituminous coal, the mole fraction of CO{sub 2} in the flue gas is in the range of 10--15%. For coal gasification, no excess air is provided. In fact, the air supplied is inadequate for complete combustion. The mole fraction of carbon monoxide (CO) plus CO{sub 2} in the fuel gas from the Kellogg-Rust-Westinghouse (KRW) gasifier, which is the gasifier for which these CO{sub 2} recovery processes are designed, is about 22% for an air-blown gasifier and 59.1% for an oxygen-blown gasifier. The CO can be converted to CO{sub 2} via the water-gas shift reaction. Because of the higher CO{sub 2} partial pressure, recovery of the CO{sub 2} from this shifted synthesis gas requires a less costly recovery system than that which would be required for recovery following direct coal combustion in air. This analysis is intended to provide a first-order estimate of the effects of CO{sub 2} recovery on the cost and performance of a gasifier and to compare these effects for common commercial CO{sub 2} recovery processes.

Molburg, J.C.; Thimmapuram, P.; Doctor, R.D.

1994-06-01T23:59:59.000Z

384

Thermoeconomic design optimization of a KRW-based IGCC power plant. Final report  

SciTech Connect (OSTI)

This report discussed the cost and efficiency optimization of an integrated gasification-combined-cycle (IGCC) power plant design and the effects of important design options and parameters. Advanced thermoeconomic techniques were used to evaluate and optimize a given IGCC concept which uses Illinois No. 6 bituminous coal, air-blown KRW coal gasifiers, a hot gas cleanup system, and GE MS7001F gas turbines. Three optimal design concepts are presented and discussed in the report. Two of the concepts are characterized by minimum cost of electricity at two different values of the steam high pressure. The third concept represents the thermodynamic optimum. This study identified several differences between the original design and the design of the optimized cases. Compared with the original concept, significant annual savings are achieved in the cost optimal cases. Comparisons were made between results obtained using both the old and the new performance data for the MS7001F gas turbine. This report discusses the effects of gasification temperature, steam high pressure, coal moisture, and various design options on the overall plant efficiency and cost of electricity. Cost sensitivity studies were conducted and recommendations for future studies were made.

Tsatsaronis, G.; Lin, L.; Pisa, J.; Tawfik, T. [Tennessee Technological Univ., Cookeville, TN (United States). Center for Electric Power

1991-11-01T23:59:59.000Z

385

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect (OSTI)

This NETL sponsored effort seeks to develop continuous technologies for the production of carbon products, which may be thought of as the heavier products currently produced from refining of crude petroleum and coal tars obtained from metallurgical grade coke ovens. This effort took binder grade pitch, produced from liquefaction of West Virginia bituminous grade coal, all the way to commercial demonstration in a state of the art arc furnace. Other products, such as crude oil, anode grade coke and metallurgical grade coke were demonstrated successfully at the bench scale. The technology developed herein diverged from the previous state of the art in direct liquefaction (also referred to as the Bergius process), in two major respects. First, direct liquefaction was accomplished with less than a percent of hydrogen per unit mass of product, or about 3 pound per barrel or less. By contrast, other variants of the Bergius process require the use of 15 pounds or more of hydrogen per barrel, resulting in an inherent materials cost. Second, the conventional Bergius process requires high pressure, in the range of 1500 psig to 3000 psig. The WVU process variant has been carried out at pressures below 400 psig, a significant difference. Thanks mainly to DOE sponsorship, the WVU process has been licensed to a Canadian Company, Quantex Energy Inc, with a commercial demonstration unit plant scheduled to be erected in 2011.

Elliot Kennel; Chong Chen; Dady Dadyburjor; Mark Heavner; Manoj Katakdaunde; Liviu Magean; James Mayberry; Alfred Stiller; Joseph Stoffa; Christopher Yurchick; John Zondlo

2009-12-31T23:59:59.000Z

386

Effects of temperature and acidic pre-treatment on Fenton-driven oxidation of MTBE-spent granular activated carbon  

SciTech Connect (OSTI)

The effects of temperature and acidic pretreatment on Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC, derived from bituminous coal) were investigated. Limiting factors in MTBE removal in GAC include the heterogeneous distribution of amended Fe, and slow intraparticle diffusive transport of MTBE and hydrogen peroxide (H{sub 2}O{sub 2}) into the 'reactive zone'. Acid pretreatment of GAC before Fe amendment altered the surface chemistry of the GAC, lowered the pH point of zero charge, and resulted in greater penetration and more uniform distribution of Fe in GAC. This led to a condition where Fe, MTBE, and H{sub 2}O{sub 2} coexisted over a larger volume of the GAC contributing to greater MTBE oxidation and removal. H{sub 2}O{sub 2} reaction and MTBE removal in GAC increased with temperature. Modeling H{sub 2}O{sub 2} transport and reaction in GAC indicated that H{sub 2}O{sub 2} penetration was inversely proportional with temperature and tortuosity, and occurred over a larger fraction of the total volume of small GAC particles (0.3 mm diameter) relative to large particles (1.2 mm diameter). Acidic pretreatment of GAC, Fe-amendment, elevated reaction temperature, and use of small GAC particles are operational parameters that improve Fenton-driven oxidation of MTBE in GAC. 29 refs., 6 figs., 1 tab.

Kan, E.; Huling, S.G. [Robert S. Kerr Environmental Research Center, Ada, OK (United States)

2009-03-01T23:59:59.000Z

387

System Analysis of Nuclear-Assisted Syngas Production from Coal  

SciTech Connect (OSTI)

A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via hightemperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 64.4% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency.

E. A. Harvego; M. G. McKellar; J. E. O'Brien

2009-07-01T23:59:59.000Z

388

Surface Area, Volume, Mass, and Density Distributions for Sized Biomass Particles  

SciTech Connect (OSTI)

This final technical report describes work performed at Morehouse College under DOE Grant No. DE-FC26-04NT42130 during the period July 01, 2004 to June 30, 2007 which covers the entire performance period of the project. 25 individual biomass particles (hardwood sawdust AI14546 in the size range of 100-200 microns) were levitated in an electrodynamic balance (EDB) and their external surface area, volume, and drag coefficient/mass (C{sub d}/m) ratios were characterized applying highly specialized video based and high-speed diode array imaging systems. Analysis methods were employed using shape and drag information to calculate mass and density distributions for these particles. Results of these measurements and analyses were validated by independent mass measurements using a particle weighing and counting technique. Similar information for 28 PSOC 1451D bituminous coal particles was retrieved from a previously published work. Using these two information, density correlations for coal/biomass blends were developed. These correlations can be used to estimate the density of the blend knowing either the volume fraction or the mass fraction of coal in the blend. The density correlations presented here will be useful in predicting the burning rate of coal/biomass blends in cofiring combustors. Finally, a discussion on technological impacts and economic projections of burning biomass with coal in US power plants is presented.

Ramanathan Sampath

2007-06-30T23:59:59.000Z

389

Task 3.0: Advanced power systems. Semi-annual report, April 1--June 30, 1993  

SciTech Connect (OSTI)

A variety of activities are incorporated into the Advanced Power Systems program. Tasks included are (1) fuel utilization properties, (2) pressurized combustion, (3) catalytic gasification, and (4) hot-gas cleanup. ATRAN is stochastic and combines initial coal inorganics in a random manner in order to predict the resulting fly ash particle size and composition. ASHPERT, is an expert system yielding a first-order estimate of fly ash size and composition. Both models are designed to emulate pulverized-coal combustion. Input data required include identity, chemistry, size, quantity, and mineral-to-coal associations. The pressurized combustion task has focused on the construction of a versatile reactor system to simulate pressurized fluidized-bed combustion. Both castable and monolithic refractories have been investigated in determining slag prevention under a variety of conditions. Catalytic gasification coupled with a molten carbonate fuel cell offers an extremely efficient and environmentally sound power generating system using coal. Work with an Illinois No. 6 bituminous coal has not been successful. Continued efforts will focus on using the more reactive low-rank coals to try to achieve this goal. Hot-gas cleanup is the critical issue in many of the proposed advanced power system operations on coal. The key to successful ash removal is an understanding of the properties of the ash to be collected as well as the interactions of this material with the barrier itself. The knowledge base under development will assist in assessing many of these barrier material issues for a variety of coal ashes.

McCollor, D.P.; Zygarlicke, C.J.; Mann, M.D.; Willson, W.G.; Hurley, J.P.

1993-07-01T23:59:59.000Z

390

Coal diesel combined-cycle project. Comprehensive report to Congress: Clean Coal Technology Program  

SciTech Connect (OSTI)

One of the projects selected for funding is a project for the design, construction, and operation of a nominal 90 ton-per-day 14-megawatt electrical (MWe), diesel engine-based, combined-cycle demonstration plant using coal-water fuels (CWF). The project, named the Coal Diesel Combined-Cycle Project, is to be located at a power generation facility at Easton Utilities Commission`s Plant No. 2 in Easton, Talbot County, Maryland, and will use Cooper-Bessemer diesel engine technology. The integrated system performance to be demonstrated will involve all of the subsystems, including coal-cleaning and slurrying systems; a selective catalytic reduction (SCR) unit, a dry flue gas scrubber, and a baghouse; two modified diesel engines; a heat recovery steam generation system; a steam cycle; and the required balance of plant systems. The base feedstock for the project is bituminous coal from Ohio. The purpose of this Comprehensive Report is to comply with Public Law 102-154, which directs the DOE to prepare a full and comprehensive report to Congress on each project selected for award under the CCT-V Program.

Not Available

1994-05-01T23:59:59.000Z

391

Advanced emissions control development project. Phase I, Final report, November 1, 1993--February 19, 1996  

SciTech Connect (OSTI)

The primary objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Ideally, the project aim is to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESP`s), fabric filters (baghouse), and wet flue gas desulfurization. B&W`s Clean Environment Development Facility (CEDF) and the AECDP equipment combined to form a state-of-the-art facility for integrated evaluation of combustion and post-combustion emissions control options. Phase 1 activities were primarily aimed at providing a reliable, representative test facility for conducting air toxic emissions control development work later in the project. This report summarizes the AECDP Phase I activities which consisted of the design, installation, shakedown, verification, and air toxics benchmarking of the AECDP facility. All verification and air toxic tests were conducted with a high sulfur, bituminous Ohio coal.

NONE

1996-02-29T23:59:59.000Z

392

Coal and nuclear power: Illinois' energy future  

SciTech Connect (OSTI)

This conference was sponsored by the Energy Resources Center, University of Illinois at Chicago; the US Department of Energy; the Illinois Energy Resources Commission; and the Illinois Department of Energy and Natural Resources. The theme for the conference, Coal and Nuclear Power: Illinois' Energy Future, was based on two major observations: (1) Illinois has the largest reserves of bituminous coal of any state and is surpassed in total reserves only by North Dakota, and Montana; and (2) Illinois has made a heavy commitment to the use of nuclear power as a source of electrical power generation. Currently, nuclear power represents 30% of the electrical energy produced in the State. The primary objective of the 1982 conference was to review these two energy sources in view of the current energy policy of the Reagan Administration, and to examine the impact these policies have on the Midwest energy scene. The conference dealt with issues unique to Illinois as well as those facing the entire nation. A separate abstract was prepared for each of the 30 individual presentations.

Not Available

1982-01-01T23:59:59.000Z

393

Pricetown I underground coal gasification field test: operations report  

SciTech Connect (OSTI)

An Underground Coal Gasification (UCG) field test in bituminous coal was successfully completed near Pricetown, West Virginia. The primary objective of this field test was to determine the viability of the linked vertical well (LVV) technology to recover the 900 foot deep, 6 foot thick coal seam. A methane rich product gas with an average heating value of approximately 250 Btu/SCF was produced at low air injection flow rates during the reverse combustion linkage phase. Heating value of the gas produced during the linkage enhancement phase was 221 Btu/SCF with air injection. The high methane formation has been attributed to the thermal and hydrocracking of tars and oils along with hydropyrolysis and hydrogasification of coal char. The high heating value of the gas was the combined effect of residence time, flow pattern, injection flow rate, injection pressure, and back pressure. During the gasification phase, a gas with an average heating value of 125 Btu/SCF was produced with only air injection, which resulted in an average energy production of 362 MMBtu/day.

Agarwal, A.K.; Seabaugh, P.W.; Zielinski, R.E.

1981-01-01T23:59:59.000Z

394

Suppression of fine ash formation in pulverized coal flames. Quarterly technical progress report No. 11, April 1, 1995--June 30, 1995  

SciTech Connect (OSTI)

Previous work has shown that pulverized bituminous coals that were treated by coal cleaning (via froth flotation) or aerodynamic sizing exhibited altered aerosol emission characteristics. Specifically, the emissions of aerosol for the cleaned and sized coals increased by as much as one order of magnitude. The goals of the present program are to: (1) perform measurements on carefully characterized coals to identify the means by which the coal treatment increases aerosol yields; (2) investigate means by which coal cleaning can be done in a way that will not increase aerosol yields; and (3) identify whether this mechanism can be used to reduce aerosol yields from systems burning straight coal. The current experimental series focuses on the use of artificial char to study sodium vaporization and aerosol formation associated with dispersed sodium and mineral inclusions. Artificial char has the advantage over natural coal in that the composition can be precisely controlled, such that the influences of specific mineral composition and content can be investigated. The study showed: the addition of calcite had no effect of the aerosol yield; increased amounts of pyrite did not lead to increased residual ash formation; in spite of the increase in mineral content, the yield of aerosol on the backup filter did not correlate with the amount of added minerals; and the general trend was for reduced aerosol yields as the amount of bentonite increased which suggested that the bentonite was effective at complexing sodium and reducing its overall vaporization.

Kramlich, J.C.; Chenevert, B.; Park, Jungsung

1995-08-02T23:59:59.000Z

395

Suppression of fine ash formation in pulverized coal flames. Quarterly technical progress report No. 4, July 1, 1993--September 30, 1993  

SciTech Connect (OSTI)

Laboratory work and studies of full-scale coal-fired boilers have identified two general mechanisms for ash production. The vast majority of the ash is formed from mineral matter that coalesces as the char burns, yielding particles that are normally larger than 0.5 {mu}m. The second major mechanism is the generation of a submicron aerosol through a vaporization/condensation mechanism. Previous work has shown that pulverized bituminous coals that were treated by coal cleaning (via froth flotation) or aerodynamic sizing exhibited altered aerosol emission characteristics. Specifically, the emissions of aerosol for the cleaned and sized coals increased by as much as one order of magnitude. The goals of the present progress are to: (1) perform measurements on carefully characterized coals to identify the means by which the coal treatment increases aerosol yields; (2) investigate means by which coal cleaning can be done in a way that will not increase aerosol yields; (3) identify whether this mechanism can be used to reduce aerosol yields from systems burning straight coal. This paper discusses model description and model formulation, and reports on the progress of furnace design and construction, and coal selection.

Kramlich, J.C.; Hoffman, D.A.; Butcher, E.K.

1993-10-29T23:59:59.000Z

396

Evaluating the status of the Texaco gasifier  

SciTech Connect (OSTI)

Conclusions after a series of runs at steady state conditions in the pilot plant are: (1) Western Kentucky No. 9 coal (either run-of-mine or washed) can be gasified without pretreatment; (2) other coking bituminous coal may also be able to be gasified without pretreatment; (3) pretreatment is not required to achieve satisfactory ash agglomeration; (4) balanced ash agglomeration with satisfactory removal of the agglomerates has been achieved and stable operation of ash agglomeration is possible during periods of short upset; (5) solutions appear to have been found for prevention of clinkering and sintering by alternative venturi design, modification in the oxygen feed system and increasing the superficial velocity of the gas; (6) under certain circumstances fines recycle has been achieved with stable operation and fluidization; (7) the process can be operated at pressures up to 60 psig without adversely affecting other process parameters; (8) a wide range of operating conditions can be used while maintaining system operability; and (9) in a single test water cooling of the cyclone appears to prevent ash deposition on the cooled surfaces which confirms the experience of Westinghouse with ash deposition prevention in their fluidized bed gasifier. 11 references, 12 tables.

Perry, H.

1981-01-01T23:59:59.000Z

397

Pinon Pine Power Project. Annual report, January 1--December 31, 1996  

SciTech Connect (OSTI)

This annual report has been prepared to present the status of the Pinon Pine Power Project, a nominal 107 MWe (gross) coal-fired integrated gasification combined-cycle (IGCC) power plant addition to Sierra Pacific Power Company`s (SPPCo) system. This project will also serve as a demonstration project cost-shared by the US Department of Energy (DOE) and SPPCo under DOE`s Clean Coal Technology (CCT) Program. The goal of the CCT Program is to demonstrate advanced coal utilization technologies that are energy efficient, reliable and able to achieve substantial reductions in emissions as compared with existing coal technologies. The Pinon Pine Power Project will demonstrate an IGCC system utilizing the Kellogg-Rust-Westinghouse (KRW) fluidized-bed gasification process operating in an air-blown mode with in-bed desulfurization and hot gas clean-up with a western bituminous coal as the design fuel. Testing will also be performed on a high-sulfur eastern coal. The Pinon Pine Power Project will be constructed and operated at SPPCo`s Tracy Power Station, an existing power generation facility located on a rural 724-acre plot approximately 17 miles east of Reno, NV. This new unit is designated as Tracy Unit No. 4.

NONE

1997-12-31T23:59:59.000Z

398

Pinon Pine Power Project. Annual report, August 1992--December 1993  

SciTech Connect (OSTI)

This annual report has been prepared to present the status of the Pinon Pine Power Project, a nominal 104 MWe (gross) integrated gasification combined-cycle (IGCC) power plant addition to Sierra Pacific Power Company`s (SPPCo) system. This project will also serve as a demonstration project cost-shared by the US Department of Energy (DOE) and SPPCo under DOE`s Clean Coal Technology (CCT) Program. The goal of the CCT Program is to demonstrate advanced coal utilization technologies that are energy efficient and reliable and that are able to achieve substantial reductions in emissions as compared with existing coal technologies. The Pinon Pine Power Project will demonstrate an IGCC system utilizing the Kellogg-Rust-Westinghouse (KRW) fluidized-bed gasification process operating in an air-blown mode with in-bed desulfurization and hot gas clean-up with a western bituminous coal. The Pinon Pine Power Project will be constructed and operated at SPPCo`s Tracy Power Station, an existing power generation facility located on a rural 724-acre plot approximately 17 miles east of Reno, NV.

NONE

1994-11-01T23:59:59.000Z

399

Petrology of Jurassic (Kimmeridgian) coals, Atlantic Continental Shelf, New Jersey  

SciTech Connect (OSTI)

Ten coals of Kimmeridgian age were recovered from the COST B-3 borehole, offshore New Jersey. Separation of the coal from other cuttings was done at 1.8 specific gravity, meaning that partings and mineral-rich lithotypes were lost in processing. The coals are distributed over an interval of 3.49 to 3.93 km depth. Coal rank, by vitrinite maximum reflectance, spans the lower portion of the high volatile A bituminous range. A single Cretaceous coal with 0.32%R[sub max] occurs at 2.08 km depth. Vitrinite content ranges from 51 to over 90% with vitrinite content generally increasing upward in the section. Telinite with resinite cell fillings is an important vitrinite form. Resinite occurs in concentrations of up to 9% in the Jurassic coals and is nearly 12% in the Cretaceous lignite. Fusinite plus semifusinite ranges from 2 to 31%. Inertinite occurs in a wide variety of forms from low-reflectance semifusinite to massive, structureless fusinite. Inertodetrinite also is a component of the abundant detrital bands of some of the Jurassic coals. The gravity separation did not eliminate all mineral matter. Massive pyrite and marcasite occur in several coals and clay occurs with the detrital minerals.

Hower, J.C.; Wild, G.D. (Univ. of Kentucky, Lexington, KY (United States))

1993-08-01T23:59:59.000Z

400

Influence of conversion to low NO{sub x} combustion on fly ash petrology and mineralogy: A case study  

SciTech Connect (OSTI)

The wall-fired 116 MW unit 2 at the John Sherman Cooper Station, Pulaski County, Kentucky, was converted to low-NO{sub x} combustion in the winter of 1993--1994. The fly ash from before and after conversion was studied in detail. The coal feed, which did not change significantly over the study, was from southeastern Kentucky and had an ash range of 10--12% and a sulfur range of 1.5--1.9%. The coal rank was high volatile bituminous A with a vitrinite reflectance (R{sub max}) of about 0.8%. The coal had about 17% by volume inertinite macerals (mineral-free basis). The fly ash carbon can be divided into three types: anisotropic coke, isotropic coke and inertinite. The post-conversion fly ash has nearly twice the amount of carbon as the pre-conversion ash and shows an increase in anisotropic coke. Mullite and quartz were observed petrographically to be more abundant in the post-conversion fly ash, although only the mullite increase was confirmed by XRD. The proportion of glass is slightly less in the post-conversion ash and is accompanied by one-third drop in the amount of cenospheres.

Robl, T.L.; Hower, J.C.; Graham, U.M.; Rathbone, R.F. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Medina, S.S. [East Kentucky Power Cooperative, Winchester, KY (United States)

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "anthracite bituminous subbituminous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Air-blown Integrated Gasification Combined Cycle demonstration project  

SciTech Connect (OSTI)

Clean Power Cogeneration, Inc. (CPC) has requested financial assistance from DOE for the design construction, and operation of a normal 1270 ton-per-day (120-MWe), air-blown integrated gasification combined-cycle (IGCC) demonstration plant. The demonstration plant would produce both power for the utility grid and steam for a nearby industrial user. The objective of the proposed project is to demonstrate air-blown, fixed-bed Integrated Gasification Combined Cycle (IGCC) technology. The integrated performance to be demonstrated will involve all the subsystems in the air-blown IGCC system to include coal feeding; a pressurized air-blown, fixed-bed gasifier capable of utilizing caking coal; a hot gas conditioning systems for removing sulfur compounds, particulates, and other contaminants as necessary to meet environmental and combustion turbine fuel requirements; a conventional combustion turbine appropriately modified to utilize low-Btu coal gas as fuel; a briquetting system for improved coal feed performance; the heat recovery steam generation system appropriately modified to accept a NO{sub x} reduction system such as the selective catalytic reduction process; the steam cycle; the IGCC control systems; and the balance of plant. The base feed stock for the project is an Illinois Basin bituminous high-sulfur coal, which is a moderately caking coal. 5 figs., 1 tab.

Not Available

1991-01-01T23:59:59.000Z

402

The application of soft X-ray microscopy to the in-situ analysis of sporopollenin/sporinite in a rank variable suite of organic rich sediments  

SciTech Connect (OSTI)

Soft X-ray imaging and carbon near edge absorption fine structure spectroscopy (C-NEXAFS) has been used for the in-situ analysis of sporinite in a rank variable suite of organic rich sediments extending from recent up to high volatile A bituminous coal. The acquisition of chemically based images (contrast based on the 1s - 1{pi}* transition of unsaturated carbon), revealed a homogeneous chemical structure in the spore exine. C-NEXAFS microanalysis indicates chemical structural evolution in sporopollenin/sporinite with increases in maturation. The most significant change in the C-NEXAFS spectrum is an increase in unsaturated carbon, presumably aromatic, with rank. The rate of aromatization in sporinite exceeds that of the surrounding vitrinite. Increases in the concentration of unsaturated carbon are compensated by losses of aliphatic and hydroxylated aliphatic carbon components. Carboxyl groups are present in low and variable concentrations. Absorption due to carboxyl persists in the most mature specimen in this series, a high volatile A rank coal. The reactions which drive sporopollenin chemical structural evolution during diagenesis presumably involve dehydration, Diels-Alder cyclo-addition, and dehydrogenation reactions which ultimately lead to a progressively aromatized bio/geopolymer.

Cody, G.D.; Botto, R.E. [Argonne National Lab., IL (United States). Chemistry Div.; Ade, H. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Physics; Wirick, S. [State Univ. of New York, Stony Brook, NY (United States). Dept. of Physics

1997-07-01T23:59:59.000Z

403

Coal upgrading program for Usti nad Labem, Czech Republic: Task 8.3. Topical report, October 1994--August 1995  

SciTech Connect (OSTI)

Coal has been a major energy source in the Czech Republic given its large coal reserves, especially brown coal and lignite (almost 4000 million metric tons) and smaller reserves of hard, mainly bituminous, coal (over 800 million tons). Political changes since 1989 have led to the reassessment of the role of coal in the future economy as increasing environmental regulations affect the use of the high-sulfur and high-ash brown coal and lignite as well as the high-ash hard coal. Already, the production of brown coal has declined from 87 million metric tons per year in 1989 to 67 million metric tons in 1993 and is projected to decrease further to 50 million metric tons per year of brown coal by the year 2000. As a means of effectively utilizing its indigenous coal resources, the Czech Republic is upgrading various technologies, and these are available at different stages of development, demonstration, and commercialization. The purpose of this review is to provide a database of information on applicable technologies that reduce the impact of gaseous (SO{sub 2}, NO{sub x}, volatile organic compounds) and particulate emissions from the combustion of coal in district and residential heating systems.

Young, B.C.; Musich, M.A.

1995-10-01T23:59:59.000Z

404

Research and development of CWM technology toward clean coal use  

SciTech Connect (OSTI)

In this chapter, three subjects were presented from among our technical efforts to develop clean coal applications to improve environmental quality. The three subjects are briefly summarized as follows: development of technology aimed at producing and utilizing exclusively low ash CWM; development of technology to produce CWM from various pond coals; development of technology to upgrade LRC and utilize CWM for both a boiler fuel and a gasification feedstock. We are fully convinced that the first and second of the above technologies have reached the level of practical use through demonstration tests. As to the third, we have almost finished a 10 kg/h coal slurry bench-scale test and have a plan to construct an upgrading pilot plant of 350 kg/h which will be completed in the fall 1994. We will hopefully establish upgrading technology through pilot-scale demonstration testing in 1995. With this technology, not just utilization of LRCs will be expanded, but also highly efficient use of coal will be accelerated. Thus, C0{sub 2} emission will also be strongly reduced. In ending, we would like to stress our efforts on research and development of environmentally friendly technologies as well as COM and CWM technologies based on bituminous and steaming coals.

Shibata, Kazuhiro

1993-12-31T23:59:59.000Z

405

Sampling of power plant stacks for air toxic emissions: Final report for Phases 1 and 2  

SciTech Connect (OSTI)

A test program to collect and analyze size-fractionated stack gas particulate samples for selected inorganic hazardous air pollutants (HAPs) was conducted . Specific goals of the program are (1) the collection of one-gram quantities of size-fractionated stack gas particulate matter for bulk (total) and surface chemical characterization, and (2) the determination of the relationship between particle size, bulk and surface (leachable) composition, and unit load. The information obtained from this program identifies the effects of unit load, particle size, and wet FGD system operation on the relative toxicological effects of exposure to particulate emissions. Field testing was conducted in two phases. The Phase I field program was performed over the period of August 24 through September 20, 1992, at the Tennessee Valley Authority Widows Creek Unit 8 Power Station, located near Stevenson (Jackson County), Alabama, on the Tennessee River. Sampling activities for Phase II were conducted from September 11 through October 14, 1993. Widows Creek Unit 8 is a 575-megawatt plant that uses bituminous coal averaging 3.7% sulfur and 13% ash. Downstream of the boiler, a venture wet scrubbing system is used for control of both sulfur dioxide and particulate emissions. There is no electrostatic precipitator (ESP) in this system. This system is atypical and represents only about 5% of the US utility industry. However, this site was chosen for this study because of the lack of information available for this particulate emission control system.

NONE

1995-04-28T23:59:59.000Z

406

Coal transformation chemistry. Second quarterly progress report, June 1, 1980-August 31, 1980  

SciTech Connect (OSTI)

A review of the information concerning the structure of Illinois No. 6 coal obtained in this laboratory and elsewhere provides the basis for a proposed structure for this bituminous coal. All the available facts concerning reduction, reductive alkylation, hydrogen atom exchange, oxidation, functional group analysis and so forth have been used to define a structural segment consisting of about 1000 atoms with a molecular weight in excess of 6000. This work is discussed in Part A. The study of the reductive alkylation reaction of Illinois No. 6 coal in liquid ammonia has been directed toward the optimization of the reaction conditions for the achievement of maximum solubility. The latest results indicate that about 55% of the original Illinois No. 6 coal can be converted to products which are soluble in tetrahydrofuran using potassium in liquid ammonia as the reducing agent and n-butyl iodide in tetrahydrofuran as the reducing alkylating agent. These observations are treated in Part B. The effort on donor solvent coal chemistry was directed to the role played by pericyclic reactions in the liquefaction process. The reactivity of a number of donors has been examined including 1,2- and 1,4-dihydronaphthalene. Although the research is not yet complete, the preliminary results indicate that free radical processes occur preferentially. Thus, the pericyclic reactions appear to be unimportant at the threshold reaction temperatures of 350 to 425/sup 0/C. This work is described in Part C.

Stock, Leon M.; Alemany, L. B.; Handy, C. I.; King, H. -H.

1980-01-01T23:59:59.000Z

407

Process for hydrocracking carbonaceous material in liquid carrier  

DOE Patents [OSTI]

Solid carbonaceous material is hydrocracked to provide aliphatic and aromatic hydrocarbons for use as gaseous and liquid fuels or chemical feed stock. Particulate carbonaceous material such as coal in slurry with recycled product oil is preheated in liquid state to a temperature of 600.degree.-1200.degree. F. in the presence of hydrogen gas. The product oil acts as a sorbing agent for the agglomerating bitumins to minimize caking within the process. In the hydrocracking reactor, the slurry of oil and carbonaceous particles is heated within a tubular passageway to vaporize the oil and form a gas-solid mixture which is further heated to a hydropyrolysis temperature in excess of 1200.degree. F. The gas-solid mixture is quenched by contact with additional oil to condense normally liquid hydrocarbons for separation from the gases. A fraction of the hydrocarbon liquid product is recycled for quenching and slurrying with the carbonaceous feed. Hydrogen is recovered from the gas for recycle and additional hydrogen is produced by gasification of residual char.

Duncan, Dennis A. (Downers Grove, IL)

1980-01-01T23:59:59.000Z

408

LARGE-SCALE MECURY CONTROL TECHNOLOGY TESTING FOR LIGNITE-FIRED UTILITIES-OXIDATION SYSTEMS FOR WET FGD  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC) is conducting a consortium-based effort directed toward resolving the mercury (Hg) control issues facing the lignite industry. Specifically, the EERC team--the EERC, EPRI, URS, ADA-ES, Babcock & Wilcox, the North Dakota Industrial Commission, SaskPower, and the Mercury Task Force, which includes Basin Electric Power Cooperative, Otter Tail Power Company, Great River Energy, Texas Utilities (TXU), Montana-Dakota Utilities Co., Minnkota Power Cooperative, BNI Coal Ltd., Dakota Westmoreland Corporation, and the North American Coal Company--has undertaken a project to significantly and cost-effectively oxidize elemental mercury in lignite combustion gases, followed by capture in a wet scrubber. This approach will be applicable to virtually every lignite utility in the United States and Canada and potentially impact subbituminous utilities. The oxidation process is proven at the pilot-scale and in short-term full-scale tests. Additional optimization is continuing on oxidation technologies, and this project focuses on longer-term full-scale testing. The lignite industry has been proactive in advancing the understanding of and identifying control options for Hg in lignite combustion flue gases. Approximately 1 year ago, the EERC and EPRI began a series of Hg-related discussions with the Mercury Task Force as well as utilities firing Texas and Saskatchewan lignites. This project is one of three being undertaken by the consortium to perform large-scale Hg control technology testing to address the specific needs and challenges to be met in controlling Hg from lignite-fired power plants. This project involves Hg oxidation upstream of a system equipped with an electrostatic precipitator (ESP) followed by wet flue gas desulfurization (FGD). The team involved in conducting the technical aspects of the project includes the EERC, Babcock & Wilcox, URS, and ADA-ES. The host sites include Minnkota Power Cooperative Milton R. Young Unit 2 and TXU Monticello Unit 3. The work involves establishing Hg oxidation levels upstream of air pollution control devices (APCDs) and removal rates across existing ESP and FGD units, determining costs associated with those removal rates, investigating the possibility of the APCD acting as a multipollutant control device, quantifying the balance of plant impacts of the control technologies, and facilitating technology commercialization.

Michael J. Holmes; Steven A. Benson; Jeffrey S. Thompson

2004-03-01T23:59:59.000Z

409

ADVANCED POWER SYSTEMS ANALYSIS TOOLS  

SciTech Connect (OSTI)

The use of Energy and Environmental Research Center (EERC) modeling tools and improved analytical methods has provided key information in optimizing advanced power system design and operating conditions for efficiency, producing minimal air pollutant emissions and utilizing a wide range of fossil fuel properties. This project was divided into four tasks: the demonstration of the ash transformation model, upgrading spreadsheet tools, enhancements to analytical capabilities using the scanning electron microscopy (SEM), and improvements to the slag viscosity model. The ash transformation model, Atran, was used to predict the size and composition of ash particles, which has a major impact on the fate of the combustion system. To optimize Atran key factors such as mineral fragmentation and coalescence, the heterogeneous and homogeneous interaction of the organically associated elements must be considered as they are applied to the operating conditions. The resulting model's ash composition compares favorably to measured results. Enhancements to existing EERC spreadsheet application included upgrading interactive spreadsheets to calculate the thermodynamic properties for fuels, reactants, products, and steam with Newton Raphson algorithms to perform calculations on mass, energy, and elemental balances, isentropic expansion of steam, and gasifier equilibrium conditions. Derivative calculations can be performed to estimate fuel heating values, adiabatic flame temperatures, emission factors, comparative fuel costs, and per-unit carbon taxes from fuel analyses. Using state-of-the-art computer-controlled scanning electron microscopes and associated microanalysis systems, a method to determine viscosity using the incorporation of grey-scale binning acquired by the SEM image was developed. The image analysis capabilities of a backscattered electron image can be subdivided into various grey-scale ranges that can be analyzed separately. Since the grey scale's intensity is dependent on the chemistry of the particle, it is possible to map chemically similar areas which can also be related to the viscosity of that compound at temperature. A second method was also developed to determine the elements associated with the organic matrix of the coals, which is currently determined by chemical fractionation. Mineral compositions and mineral densities can be determined for both included and excluded minerals, as well as the fraction of the ash that will be represented by that mineral on a frame-by-frame basis. The slag viscosity model was improved to provide improved predictions of slag viscosity and temperature of critical viscosity for representative Powder River Basin subbituminous and lignite coals.

Robert R. Jensen; Steven A. Benson; Jason D. Laumb

2001-08-31T23:59:59.000Z

410

The Mochovce final treatment center for liquid radioactive waste introduced to active trial operation  

SciTech Connect (OSTI)

The Final Treatment Centre (FTC) for Mochovce Nuclear Power Plant (NPP) have been designed for treatment and final conditioning of radioactive liquid and wet waste produced by named NPP equipped with Russian VVER-440 type of reactors. Treated wastes comprise radioactive concentrates, spent resin and sludge. VUJE Inc. as an experienced company in field of treatment of radioactive waste in Slovakia has been chosen as main contractor for technological part of FTC. During the realisation of project the future operator of Centre required the contractor to solve the treatment of wastes produced in the process of NPP A-1 decommissioning. On the basis of this requirement the project was modified in order to enable manipulations with waste products from A-1 NPP transported to Centre in steel drums. The initial project was prepared in 2003. The design and manufacture of main components were performed in 2004 and 2005. FTC civil works started in August 2004. Initial nonradioactive testing of the system parts were carried out from April to September 2006, then the tests of systems started with model concentrates and non-radioactive resins. After the processes evaluation the radioactive test performed from February 2007. A one-year trial operation of facility is planned for completion during 2007 and 2008. The company JAVYS, Inc. is responsible for radioactive waste and spent fuel treatment in the Slovak republic and will operate the FTC during trial operation and after its completion. This Company has also significant experience with operation of Jaslovske Bohunice Treatment Centre. The overall capacity of the FTC is 820 m{sup 3}/year of concentrates and 40 m{sup 3}/year of spent resin and sludge. Bituminization and cementation were provided as main technologies for treatment of these wastes. Treatment of concentrate is performed by bituminization on Thin Film Evaporator with rotating wiping blades. Spent resin and sludge are decanted, dried and mixed with bitumen in blade homogeniser. The bitumen product is discharged into 200 dm{sup 3} steel drums. Drums with bitumen product or drums originated from A-1 NPP are loaded into Fibre Reinforced Concrete containers (FRC) and grouted with cement. Cement grout is prepared from the mixture of cement, additive and radioactive over-concentrate. By formulating the cement grout with evaporator concentrates the maximum radioactivity is fixed in cement matrix and volume of final waste product is minimized. A batch mixer with rotating blades is used to produce the cement grout. The grouted FRC containers are stored in the expedition hall and after 28 days of curing are transported to final disposal. After the start of routine operation, the FTC provides treatment for all liquid and wet LLW produced from the operation of the Mochovce NPP. The final product of the FTC is a FRC loaded with bitumen product in drums and filled with radioactive cement product. This container meets all limits for final disposal in the National Radioactive Waste Repository at Mochovce. This paper introducing the main parts of FTC and describes the technological procedures including the basic technological parameters for both used technologies, their working capacity and the overall waste flow. The evaluation of experience gained in the phases of Centre construction and commissioning and partially trial operation as well is a part of this paper (Evaluation of completion works process and time schedule, the process of individual system parts testing, testing of systems using model media, radioactive testing and trial operation). (authors)

Krajc, T.; Stubna, M.; Kravarik, K.; Zatkulak, M. [VUJE Trnava, Inc. (Slovakia); Slezak, M.; Remias, V. [Javys - Jadrova a vyradovacia spolocnost, a.s. - Nuclear and Decommissioning Company, plc., Tomasikova 22, 821 02 Bratislava (Slovakia)

2007-07-01T23:59:59.000Z

411

CO{sub 2} SEQUESTRATION POTENTIAL OF TEXAS LOW-RANK COALS  

SciTech Connect (OSTI)

The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. There were three main objectives for this reporting period, which related to obtaining accurate parameters for reservoir model description and modeling reservoir performance of CO{sub 2} sequestration and enhanced coalbed methane recovery. The first objective was to collect and desorb gas from 10 sidewall core coal samples from an Anadarko Petroleum Corporation well (APCL2 well) at approximately 6,200-ft depth in the Lower Calvert Bluff Formation of the Wilcox Group in east-central Texas. The second objective was to measure sorptive capacities of these Wilcox coal samples for CO{sub 2}, CH{sub 4}, and N{sub 2}. The final objective was to contract a service company to perform pressure transient testing in Wilcox coal beds in a shut-in well, to determine permeability of deep Wilcox coal. Bulk density of the APCL2 well sidewall core samples averaged 1.332 g/cc. The 10 sidewall core samples were placed in 4 sidewall core canisters and desorbed. Total gas content of the coal (including lost gas and projected residual gas) averaged 395 scf/ton on an as-received basis. The average lost gas estimations were approximately 45% of the bulk sample total gas. Projected residual gas was 5% of in-situ gas content. Six gas samples desorbed from the sidewall cores were analyzed to determine gas composition. Average gas composition was approximately 94.3% methane, 3.0% ethane, and 0.7% propane, with traces of heavier hydrocarbon gases. Carbon dioxide averaged 1.7%. Coal from the 4 canisters was mixed to form one composite sample that was used for pure CO{sub 2}, CH{sub 4}, and N{sub 2} isotherm analyses. The composite sample was 4.53% moisture, 37.48% volatile matter, 9.86% ash, and 48.12% fixed carbon. Mean vitrinite reflectance was 0.54%. Coal rank was high-volatile C to B bituminous. Comparison of the desorbed gas content (395 scf/ton, as received) at reservoir pressure (2,697 psi) with the sorption isotherm indicates that Lower Calvert Bluff coal at this well site is oversaturated, but lost gas may have been overestimated. This high gas content suggests that little or no depressurization would be required to initiate methane production. Sorption isotherms results indicate that the sorptive capacity of CO{sub 2} is about 2.5 times that of CH{sub 4} at 1,000 psia. This ratio is similar to that of higher rank bituminous coals from other basins (e.g., Carroll, and Pashin, 2003), and it is very low in comparison to results of other low-rank coals and to the values that we used in our preliminary reservoir modeling. If this value from the APCL2 well is representative, Wilcox coals in this area will sequester less CO{sub 2} on a per ton basis than we had earlier inferred. However, because measured methane contents are higher, enhanced coalbed methane production potential is greater than we earlier inferred. Pressure transient testing for determining coal fracture permeability will be conducted soon by Pinnacle Technologies. The data from these analyses will be used to finalize our coal model for the reservoir simulation phase of the project.

Duane A. McVay; Walter B. Ayers Jr; Jerry L. Jensen

2005-02-01T23:59:59.000Z

412

Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures  

SciTech Connect (OSTI)

The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal performance between the various coproduct cases is further complicated by the fact that the carbon footprint is not the same when carbon leaving with the coproduct are accounted for. The economic analysis and demand for a particular coproduct in the market place is a more meaningful comparison of the various coproduction scenarios. The first year cost of electricity calculated for the bituminous coal is $102.9/MWh while that for the lignite is $108.1/MWh. The calculated cost of hydrogen ranged from $1.42/kg to $2.77/kg depending on the feedstock, which is lower than the DOE announced hydrogen cost goal of $3.00/kg in July 14, 2005. Methanol cost ranged from $345/MT to $617/MT, while the market price is around $450/MT. For Fischer-Tropsch liquids, the calculated cost ranged from $65/bbl to $112/bbl, which is comparable to the current market price of crude oil at around $100/bbl. It should be noted, however, that F-T liquids contain no sulfur and nitrogen compounds. The calculated cost of alcohol ranged from $4.37/gal to $5.43/gal, while it ranged from $2.20/gal to $3.70/gal in a DOE funded study conducted by Louisiana State University. The Louisiana State University study consisted of a significantly larger plant than our study and benefited from economies of scale. When the plant size in our study is scaled up to similar size as in the Louisiana State University study, cost of alcohol is then reduced to a range of $3.24/gal to $4.28/gal, which is comparable. Urea cost ranged from $307/MT to $428/MT, while the market price is around $480/MT.

Rao, A. D.; Chen, Q.; Samuelsen, G. S.

2012-09-30T23:59:59.000Z

413

Novel Sorbent-Based Process for High Temperature Trace Metal Removal  

SciTech Connect (OSTI)

The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

Gokhan Alptekin

2008-09-30T23:59:59.000Z

414

The use of NMR techniques for the analysis of water in coal and the effect of different coal drying techniques on the structure and reactivity of coal. Final report  

SciTech Connect (OSTI)

Western Research Institute has conducted a study of different methods of coal drying as pretreatment steps before liquefaction. The objectives of this study were to develop a combined che