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1

Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)  

DOE Green Energy (OSTI)

Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

Dr. Malgorzata Gulbinska

2009-08-24T23:59:59.000Z

2

Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)  

SciTech Connect

Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

Dr. Malgorzata Gulbinska

2009-08-24T23:59:59.000Z

3

Anode Materials  

Science Conference Proceedings (OSTI)

Table 6   Properties of polymeric mesh anodes used for construction applications...(a) Average current output

4

Anodic films  

DOE Green Energy (OSTI)

Surface layers are formed on many metals by anodic reaction. Such layers include the products of charge and discharge in many storage batteries, dielectric films used in electronic and optical circuits and display devices, layers responsible for passivity and corrosion protection, and films generated in metal shaping and finishing operations such as anodization, coloring, electropolishing, electrochemical machining and deburring. Anodic films are formed by solid-solid transformations or by dissolution-precipitation processes. Film properties and mechanisms of formation can be determined in situ by a number of optical techniques which have recently become available.

Muller, R.H.

1983-08-01T23:59:59.000Z

5

Thin film buried anode battery  

DOE Patents (OSTI)

A reverse configuration, lithium thin film battery (300) having a buried lithium anode layer (305) and process for making the same. The present invention is formed from a precursor composite structure (200) made by depositing electrolyte layer (204) onto substrate (201), followed by sequential depositions of cathode layer (203) and current collector (202) on the electrolyte layer. The precursor is subjected to an activation step, wherein a buried lithium anode layer (305) is formed via electroplating a lithium anode layer at the interface of substrate (201) and electrolyte film (204). The electroplating is accomplished by applying a current between anode current collector (201) and cathode current collector (202).

Lee, Se-Hee (Lakewood, CO); Tracy, C. Edwin (Golden, CO); Liu, Ping (Denver, CO)

2009-12-15T23:59:59.000Z

6

Anode Baking/Anode Properties  

Science Conference Proceedings (OSTI)

Feb 17, 2010... introducing a new state-of-the-art firing system, replacing the waste gas ... In this test, an anode core sample is exposed to CO2 at 960C for 7...

7

Anodizing Processes  

Science Conference Proceedings (OSTI)

Table 2   Typical products for which anodizing is used in final finishing...ft by 7 by 4 6063-T6 (d) Sulfuric acid (e) Seal, lacquer (f) Urban atmosphere Name plates Various sizes Various sizes 3003??1114 (g) Sulfuric acid Dye, seal Atmospheric exposure Percolator shell 125 mm diam by 150 5 in. diam by 6 ? Buff, chemical brighten Sulfuric acid Seal Coffee Seaplane-hull skin 2850...

8

Understanding Anode Overpotential  

Science Conference Proceedings (OSTI)

Industrial carbon anodes are produced from coke blends, but the effect of coke type on anodic overpotential has not been well studied. In this work, lab-scale...

9

FLUORINE CELL ANODE ASSEMBLY  

DOE Patents (OSTI)

An improved anode assembly is deslgned for use in electrolytlc cells ln the productlon of hydrogen and fluorlne from a moIten electrolyte. The anode assembly comprises a copper post, a copper hanger supported by the post, a plurality of carbon anode members, and bolt means for clamplng half of the anode members to one slde of the hanger and for clamplng the other half of the anode members to the other slde of the hanger. The heads of the clamplng bolts are recessed withln the anode members and carbon plugs are inserted ln the recesses above the bolt heads to protect the boIts agalnst corroslon. A copper washer is provided under the head of each clamplng boIt such that the anode members can be tightly clamped to the hanger with a resultant low anode jolnt resistance. (AEC)

Cable, R.E.; Goode, W.B. Jr.; Henderson, W.K.; Montillon, G.H.

1962-06-26T23:59:59.000Z

10

Anode Baking Furnace Operation  

Science Conference Proceedings (OSTI)

The course is directed toward plant managers, anode area managers, process engineers, technical managers, and baking furnace ... ENERGY MANAGEMENT.

11

Towards Eliminating Anode Effects  

Science Conference Proceedings (OSTI)

Retrofit of a Combined Breaker Feeder with a Chisel Bath Contact Detection System to Reduce Anode Effect Frequency in a Potroom Simulating Traffic in a...

12

Anode Raw Materials  

Science Conference Proceedings (OSTI)

Mar 4, 2013 ... Anodes for aluminum production are composed of coal tar pitch (CTP) ... This paper reports a study on the structure and porosity of calcined...

13

Anode Quality and Performance  

Science Conference Proceedings (OSTI)

Mar 6, 2013 ... Relationships between Coke Properties and Anode Properties Round Robin 19: Lorentz Petter Lossius1; Marvin Lubin2; Les Edwards2;...

14

Ellipsometry of anodic film growth  

DOE Green Energy (OSTI)

An automated computer interpretation of ellisometer measurements of anodic film growth was developed. Continuous mass and charge balances were used to utilize more fully the time dependence of the ellipsometer data and the current and potential measurements. A multiple-film model was used to characterize the growth of films which proceeds via a dissolution--precipitation mechanism; the model also applies to film growth by adsorption and nucleation mechanisms. The characteristic parameters for film growth describe homogeneous and heterogeneous crystallization rates, film porosities and degree of hydration, and the supersaturation of ionic species in the electrolyte. Additional descriptions which may be chosen are patchwise film formation, nonstoichiometry of the anodic film, and statistical variations in the size and orientation of secondary crystals. Theories were developed to describe the optical effects of these processes. An automatic, self-compensating ellipsometer was used to study the growth in alkaline solution of anodic films on silver, cadmium, and zinc. Mass-transport conditions included stagnant electrolyte and forced convection in a flow channel. Multiple films were needed to characterize the optical properties of these films. Anodic films grew from an electrolyte supersatuated in the solution-phase dissolution product. The degree of supersaturation depended on transport conditions and had a major effect on the structure of the film. Anodic reaction rates were limited by the transport of charge carriers through a primary surface layer. The primary layers on silver, zinc, and cadmium all appeared to be nonstoichiometric, containing excess metal. Diffusion coefficients, transference numbers, and the free energy of adsorption of zinc oxide were derived from ellipsometer measurements. 97 figures, 13 tables, 198 references.

Smith, C.G.

1978-08-01T23:59:59.000Z

15

Definition: Anode | Open Energy Information  

Open Energy Info (EERE)

Anode Anode Jump to: navigation, search Dictionary.png Anode The positive electrode in an electrochemical cell, or battery.[1] View on Wikipedia Wikipedia Definition An anode is an electrode through which electric current flows into a polarized electrical device. The direction of electric current is, by convention, opposite to the direction of electron flow. In other words, the electrons flow from the anode into, for example, an electrical circuit. Mnemonic: ACID (Anode Current into Device). A widespread misconception is that anode polarity is always positive (+). This is often incorrectly inferred from the correct fact that in all electrochemical devices, negatively charged anions move towards the anode (hence their name) and positively charged cations move away from it. In fact anode polarity

16

Low cost MCFC anodes  

DOE Green Energy (OSTI)

This paper outlines a project, funded under a DOE SBIR grant, which tested a potentially lower cost method of manufacturing MCFC stack anodes and evaluated the feasibility of using the technology in the existing M-C Power Corp. manufacturing facility. The procedure involves adding activator salts to the anode tape casting slurry with the Ni and Cr or Al powders. Two different processes occur during heat treatment in a reducing environment: sintering of the base Ni structure, and alloying or cementation of the Cr or Al powders. To determine whether it was cost-effective to implement the cementation alloying manufacturing process, the M-C Power manufacturing cost model was used to determine the impact of different material costs and processing parameters on total anode cost. Cost analysis included equipment expenditures and facility modifications required by the cementation alloying process.

Erickson, D.S.

1996-12-31T23:59:59.000Z

17

Sulfur tolerant anode materials  

DOE Green Energy (OSTI)

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-05-01T23:59:59.000Z

18

Anodes for alkaline electrolysis  

DOE Patents (OSTI)

A method of making an anode for alkaline electrolysis cells includes adsorption of precursor material on a carbonaceous material, conversion of the precursor material to hydroxide form and conversion of precursor material from hydroxide form to oxy-hydroxide form within the alkaline electrolysis cell.

Soloveichik, Grigorii Lev (Latham, NY)

2011-02-01T23:59:59.000Z

19

Nickel anode electrode  

DOE Patents (OSTI)

A nickel anode electrode fabricated by oxidizing a nickel alloying material to produce a material whose exterior contains nickel oxide and whose interior contains nickel metal throughout which is dispersed the oxide of the alloying material and by reducing and sintering the oxidized material to form a product having a nickel metal exterior and an interior containing nickel metal throughout which is dispersed the oxide of the alloying material.

Singh, Prabhakar (Bethel, CT); Benedict, Mark (Monroe, CT)

1987-01-01T23:59:59.000Z

20

Methanol fuel cell model: Anode  

Science Conference Proceedings (OSTI)

An isothermal, steady-state model of an anode in a direct methanol feed, polymer electrolyte fuel cell is presented. The anode is considered to be a porous electrode consisting of an electronically conducting catalyst structure that is thinly coated with an ion-selective polymer electrolyte. The pores are filled with a feed solution of 2 M methanol in water. Four species are transported in the anode: water, methanol, hydrogen ions, and carbon dioxide. All four species are allowed to transport in the x-direction through the depth of the electrode. Species movement in the pseudo y-direction is taken into account for water, methanol, and carbon dioxide by use of an effective mass-transfer coefficient. Butler-Volmer kinetics are observed for the methanol oxidation reaction. Predictions of the model have been fitted with kinetic parameters from experimental data, and a sensitivity analysis was performed to identify critical parameters affecting the anode`s performance. Kinetic limitations are a dominant factor in the performance of the system. At higher currents, the polymer electrolyte`s conductivity and the anode`s thickness were also found to be important parameters to the prediction of a polymer electrolyte membrane fuel cell anode`s behavior in the methanol oxidation region 0.5--0.6 V vs. a reversible hydrogen electrode.

Baxter, S.F. [Argonne National Lab., IL (United States); Battaglia, V.S.; White, R.E. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering

1999-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Anodization of process tubes  

SciTech Connect

This report discusses the presence of corrosion products upon aluminum process tubes removed from wet portions of F Pile which led to the suspicion that the tubes might be corroding at an accelerated rate because of water entrapped in the channels between the tubes and the graphite blocks. Corrosion was especially noted on those tubes that were tightly stuck within the blocks. Analysis of the corrosion products showed that the major constituent was a hydrated aluminum oxide, containing iron oxide, calcium carbonate, and other substances in lower concentrations. This led to placement of an order for the anodizing of 200 process tubes.

Pitzer, E.C.

1952-09-17T23:59:59.000Z

22

Uniform insulation applied-B ion diode  

DOE Patents (OSTI)

An applied-B field extraction ion diode has uniform insulation over an anode surface for increased efficiency. When the uniform insulation is accomplished with anode coils, and a charge-exchange foil is properly placed, and ions may be focused at a point on the z axis.

Seidel, D.B.; Slutz, S.A.

1986-04-11T23:59:59.000Z

23

Uniform insulation applied-B ion diode  

DOE Patents (OSTI)

An applied-B field extraction ion diode has uniform insulation over an anode surface for increased efficiency. When the uniform insulation is accomplished with anode coils, and a charge-exchange foil is properly placed, the ions may be focused at a point on the z axis.

Seidel, David B. (Albuquerque, NM); Slutz, Stephen A. (Albuquerque, NM)

1988-01-01T23:59:59.000Z

24

Anode film formation and control  

DOE Patents (OSTI)

A protective film is created about the anode within a cryolite-based electrolyte during electrolytic production of aluminum from alumina. The film functions to minimize corrosion of the anode by the cryolitic electrolyte and thereby extend the life of the anode. Various operating parameters of the electrolytic process are controlled to maintain the protective film about the anode in a protective state throughout the electrolytic reduction of alumina. Such parameters include electrolyte temperature, electrolyte ratio, current density, and Al[sub 2]O[sub 3] concentration. An apparatus is also disclosed to enable identification of the onset of anode corrosion due to disruption of the film to provide real time information regarding the state of the film. 3 figs.

Koski, O.; Marschman, S.C.

1990-05-01T23:59:59.000Z

25

Anode Effect Supression and Prediction - TMS  

Science Conference Proceedings (OSTI)

Apr 1, 2003 ... Anode Effect Supression and Prediction ... the overall effort to reduce the quantity of greenhouse gas emitted by the pots during anode effects.

26

Optimizing Anode Performance in DUBAL Reduction Cells  

Science Conference Proceedings (OSTI)

Reduction in Gross Carbon consumption by 5% over the past 4 years was achieved through optimization of anode quality, modification of anode design and...

27

Silicon-Graphene Anodes | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Anodes Technology available for licensing: Production process for low-cost, long-life, high-energy anodes with five times the specific energy slicon-grapheneelectrodes...

28

ADVANCED NUMERICAL APPROACH TO REDUCE THE ANODIC ...  

Science Conference Proceedings (OSTI)

Operation of an Open Type Anode Baking Furnace with a Temporary Crossover ... Wireless Communication for Secured Firing and Control Systems of Anode...

29

High Performance Sealing for Anode Baking Furnaces  

Science Conference Proceedings (OSTI)

Operation of an Open Type Anode Baking Furnace with a Temporary Crossover ... Wireless Communication for Secured Firing and Control Systems of Anode...

30

Energy Efficiency Improvement in Anode Baking Furnaces  

Science Conference Proceedings (OSTI)

One of the high energy consumption facilities in a smelter is the Anode Baking ... Hydro Aluminium's Historical Evolution of Closed Type Anode Baking Furnace...

31

Multi-anode ionization chamber  

DOE Patents (OSTI)

The present invention includes a high-energy detector having a cathode chamber, a support member, and anode segments. The cathode chamber extends along a longitudinal axis. The support member is fixed within the cathode chamber and extends from the first end of the cathode chamber to the second end of the cathode chamber. The anode segments are supported by the support member and are spaced along the longitudinal surface of the support member. The anode segments are configured to generate at least a first electrical signal in response to electrons impinging thereon.

Bolotnikov, Aleksey E. (South Setauket, NY); Smith, Graham (Port Jefferson, NY); Mahler, George J. (Rocky Point, NY); Vanier, Peter E. (Setauket, NY)

2010-12-28T23:59:59.000Z

32

Nanostructured Metal Oxide Anodes (Presentation)  

DOE Green Energy (OSTI)

This summarizes NREL's FY09 battery materials research activity in developing metal oxide nanostructured anodes to enable high-energy, durable and affordable li-ion batteries for HEVs and PHEVs.

Dillon, A. C.; Riley, L. A.; Lee, S.-H.; Kim, Y.-H.; Ban, C.; Gillaspie, D. T.; Pesaran, A.

2009-05-01T23:59:59.000Z

33

Nanostructured Metal Oxide Anodes (Presentation)  

SciTech Connect

This summarizes NREL's FY09 battery materials research activity in developing metal oxide nanostructured anodes to enable high-energy, durable and affordable li-ion batteries for HEVs and PHEVs.

Dillon, A. C.; Riley, L. A.; Lee, S.-H.; Kim, Y.-H.; Ban, C.; Gillaspie, D. T.; Pesaran, A.

2009-05-01T23:59:59.000Z

34

A study of certain trace metals in sea water using anodic stripping voltammetry  

E-Print Network (OSTI)

Anodic stripping voltammetry utilizing a thin film mercury composite graphite electrode has been evaluated and applied for the direct analysis of the metals, Zn,J Cu, Pb, and Cd in sea water. The electrode was observed to ...

Fitzgerald, William Francis, 1926-

1970-01-01T23:59:59.000Z

35

CARBON TECHNOLOGY: III: Anode Production/Performance  

Science Conference Proceedings (OSTI)

ANODE PROPERTY DEVELOPMENT DURING HEAT TREATMENT: Mona Jacobsen, Department of Thermal Energy and Hydro Power, the Norwegian Institute...

36

Hydriodic acid-anode-depolarized hydrogen generator  

SciTech Connect

Hydrogen is recovered from aqueous hydriodic acid in the presence of sulfuric acid, in an electrolysis cell having an anode and cathode compartment separated by a hydrogen ion permeable membrane, by electrochemically liberating iodine in the anode compartment by anodization of iodide anions, and electrochemically generating hydrogen in the cathode compartment from hydrogen cations that migrate across the membrane.

Maskalick, N.J.

1984-07-17T23:59:59.000Z

37

Solid Solution Lithium Alloy Cermet Anodes  

E-Print Network (OSTI)

Solid Solution Lithium Alloy Cermet Anodes Thomas J.94720 USA Abstract Lithium-magnesium solid solution alloysHeating mixtures of lithium nitride and magnesium provides a

Richardson, Thomas J.; Chen, Guoying

2006-01-01T23:59:59.000Z

38

Nano Structural Anodes for Radiation Detectors  

Nano Structural Anodes for Radiation Detectors Note: The technology described above is an early stage opportunity. Licensing rights to this intellectual property may

39

Carbon Technology III: Anode Quality Control - TMS  

Science Conference Proceedings (OSTI)

A fully automatic method for image analysis of porosity in baked carbon anodes has been developed. The method is based on optical microscopy, and is...

40

Hybrid Anode for Semiconductor Radiation Detectors - Energy ...  

The present invention relates to a novel hybrid anode configuration for a radiation detector that effectively reduces the edge effect of surface defects on the ...

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Thermodynamic and phase relations of intermetallic anode ...  

Science Conference Proceedings (OSTI)

The experimental data obtained are necessary for thermodynamic optimizations and direct estimations of the performance of respective anode materials in an...

42

Anode Raw Materials and Green Carbon  

Science Conference Proceedings (OSTI)

Mar 1, 2011 ... Property Profile of Lab- Scale Anodes Produced with 180C Mettler Coal Tar Pitch: Winfried Boenigk1; Claudia Boltersdorf1; Falk Lindner1;...

43

Surface modifications for carbon lithium intercalation anodes  

SciTech Connect

A prefabricated carbon anode containing predetermined amounts of passivating film components is assembled into a lithium-ion rechargeable battery. The modified carbon anode enhances the reduction of the irreversible capacity loss during the first discharge of a cathode-loaded cell. The passivating film components, such as Li.sub.2 O and Li.sub.2 CO.sub.3, of a predetermined amount effective for optimal passivation of carbon, are incorporated into carbon anode materials to produce dry anodes that are essentially free of battery electrolyte prior to battery assembly.

Tran, Tri D. (Livermore, CA); Kinoshita, Kimio (Cupertino, CA)

2000-01-01T23:59:59.000Z

44

60 TPH Single Line Green Anode Plant Commissionned at Qatalum  

Science Conference Proceedings (OSTI)

Abstract Scope, The first single line 60 t/h green anode plant ever was ... This green anode plant was designed to fulfil the anode requirements of the 585,000...

45

Remote control for anode-cathode adjustment  

DOE Patents (OSTI)

An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

Roose, Lars D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

46

Remote control for anode-cathode adjustment  

DOE Patents (OSTI)

An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode. 3 figs.

Roose, L.D.

1989-10-04T23:59:59.000Z

47

Structural micro-porous carbon anode for rechargeable lithium ...  

A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic ...

48

Baked Anode Density Improvement through Optimization of Green ...  

Science Conference Proceedings (OSTI)

Abstract Scope, At Alba, green anodes were manufactured as per the dry aggregate ... Amelios, A Performance Analysis Tool for Green Anode Plant.

49

CX-006909: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

9: Categorical Exclusion Determination CX-006909: Categorical Exclusion Determination Low-Cost Manufacturing of High-Capacity Prismatic Lithium-Ion Cell Alloy Anodes CX(s) Applied:...

50

CX-006753: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-006753: Categorical Exclusion Determination Coupled High Capacity Silicon Anode and Novel Cathode Cells for Automotive Applications CX(s) Applied: B5.1...

51

Brightness enhancement of plasma ion source by utilizing anode spot for nano applications  

Science Conference Proceedings (OSTI)

Anode spots are known as additional discharges on positively biased electrode immersed in plasmas. The anode spot plasma ion source (ASPIS) has been investigated as a high brightness ion source for nano applications such as focused ion beam (FIB) and nano medium energy ion scattering (nano-MEIS). The generation of anode spot is found to enhance brightness of ion beam since the anode spot increases plasma density near the extraction aperture. Brightness of the ASPIS has been estimated from measurement of emittance for total ion beam extracted through sub-mm aperture. The ASPIS is installed to the FIB system. Currents and diameters of the focused beams with/without anode spot are measured and compared. As the anode spot is turned on, the enhancement of beam current is observed at fixed diameter of the focused ion beam. Consequently, the brightness of the focused ion beam is enhanced as well. For argon ion beam, the maximum normalized brightness of 12 300 A/m{sup 2} SrV is acquired. The ASPIS is applied to nano-MEIS as well. The ASPIS is found to increase the beam current density and the power efficiency of the ion source for nano-MEIS. From the present study, it is shown that the ASPIS can enhance the performance of devices for nano applications.

Park, Yeong-Shin; Lee, Yuna; Chung, Kyoung-Jae; Hwang, Y. S. [Department of Nuclear Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); Kim, Yoon-Jae [Samsung Electronics Co. Ltd., Gyeonggi 445-701 (Korea, Republic of); Park, Man-Jin [Research Institute of Nano Manufacturing System, Seoul National University of Science and Technology, Seoul 139-743 (Korea, Republic of); Moon, Dae Won [Nanobio Fusion Research Center, Korea Research Institute of Standards and Science, Daejeon 305-600 (Korea, Republic of)

2012-02-15T23:59:59.000Z

52

Mesoporous Titanium Oxide Based Anodes for Batteries  

Presentation_namefor the U.S. Department of Energy Mesoporous TiO 2 Anodes for Lithium Ion Batteries Mesoporous TiO 2 ... Increased energy density ?Mesoporous TiO. 2 .

53

Working Principle of the Hollow-Anode Plasma Source Hollow-Anode Plasma  

NLE Websites -- All DOE Office Websites (Extended Search)

36240 36240 Plasma Sources Science and Technology 4 (1995) 571-575. Working Principle of the Hollow-Anode Plasma Source André Anders and Simone Anders Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 ABSTRACT The hollow-anode discharge is a special form of glow discharge. It is shown that a drastically reduced anode area is responsible for a positive anode voltage drop of 30-40 V and an increased anode sheath thickness. This leads to an ignition of a relatively dense plasma in front of the anode hole. Langmuir probe measurements inside a specially designed hollow anode plasma source give an electron density and temperature of n e = 10 9 -10 11 cm -3 and T e = 1 - 3 eV, respectively (nitrogen, current 100 mA, flow rate 5-50 scc/min). Driven by a pressure gradient, the "anode" plasma is blown through the anode hole and forms a bright plasma jet streaming with supersonic velocity (Mach number 1.2). The plasma stream can be used, for instance, in plasma-assisted deposition of thin films

54

Electrolytic Cell For Production Of Aluminum Employing Planar Anodes.  

SciTech Connect

A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising providing a molten salt electrolyte having alumina dissolved therein in an electrolytic cell. A plurality of anodes and cathodes having planar surfaces are disposed in a generally vertical orientation in the electrolyte, the anodes and cathodes arranged in alternating or interleaving relationship to provide anode planar surfaces disposed opposite cathode planar surfaces, the anode comprised of carbon. Electric current is passed through anodes and through the electrolyte to the cathodes depositing aluminum at the cathodes and forming carbon containing gas at the anodes.

Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR); Bradford, Donald R (Underwood, WA)

2004-10-05T23:59:59.000Z

55

Formation of Self-Organized Anode Patterns in Arc Discharge Simulations  

E-Print Network (OSTI)

Pattern formation and self-organization are phenomena commonly observed experimentally in diverse types of plasma systems, including atmospheric-pressure electric arc discharges. However, numerical simulations reproducing anode pattern formation in arc discharges have proven exceedingly elusive. Time-dependent three-dimensional thermodynamic nonequilibrium simulations reveal the spontaneous formation of self-organized patterns of anode attachment spots in the free-burning arc, a canonical thermal plasma flow established by a constant DC current between an axi-symmetric electrodes configuration in the absence of external forcing. The number of spots, their size, and distribution within the pattern depend on the applied total current and on the resolution of the spatial discretization, whereas the main properties of the plasma flow, such as maximum temperatures, velocity, and voltage drop, depend only on the former. The sensibility of the solution to the spatial discretization stresses the computational requirements for comprehensive arc discharge simulations. The obtained anode patterns qualitatively agree with experimental observations and confirm that the spots originate at the fringes of the arc - anode attachment. The results imply that heavy-species - electron energy equilibration, in addition to thermal instability, has a dominant role in the formation of anode spots in arc discharges.

Juan Pablo Trelles

2012-12-31T23:59:59.000Z

56

Lithium intercalation in porous carbon anodes  

DOE Green Energy (OSTI)

Carbon foams derived from the phase separation of polyacrylonitrile/solvent mixtures were investigated as lithium intercalation anodes for rechargeable lithium-ion batteries. The carbon foams have a bulk density of 0.35--0.5 g/cm{sup 3}, low surface area (< 50 m{sup 2}/g), and an average cell size of 5--10 {mu}m. Polyacrylonitrile-based carbon foams doped with phosphoric acid had capacity as high as 450 mAh/g. Carbon capacity increased with increasing phosphoric acid concentration in the doping solution. The doped porous carbon anodes exhibited good cyclability and excellent coulombic efficiency.

Tran, T.D.; Pekala, R.W. [Lawrence Livermore National Lab., CA (United States). Chemistry and Materials Science Dept.; Mayer, S.T. [Polystor Corp., Livermore, CA (United States)

1994-11-23T23:59:59.000Z

57

An Insoluble Titanium-Lead Anode for Sulfate Electrolytes  

SciTech Connect

The project is devoted to the development of novel insoluble anodes for copper electrowinning and electrolytic manganese dioxide (EMD) production. The anodes are made of titanium-lead composite material produced by techniques of powder metallurgy, compaction of titanium powder, sintering and subsequent lead infiltration. The titanium-lead anode combines beneficial electrochemical behavior of a lead anode with high mechanical properties and corrosion resistance of a titanium anode. In the titanium-lead anode, the titanium stabilizes the lead, preventing it from spalling, and the lead sheathes the titanium, protecting it from passivation. Interconnections between manufacturing process, structure, composition and properties of the titanium-lead composite material were investigated. The material containing 20-30 vol.% of lead had optimal combination of mechanical and electrochemical properties. Optimal process parameters to manufacture the anodes were identified. Prototypes having optimized composition and structure were produced for testing in operating conditions of copper electrowinning and EMD production. Bench-scale, mini-pilot scale and pilot scale tests were performed. The test anodes were of both a plate design and a flow-through cylindrical design. The cylindrical anodes were composed of cylinders containing titanium inner rods and fitting over titanium-lead bushings. The cylindrical design allows the electrolyte to flow through the anode, which enhances diffusion of the electrolyte reactants. The cylindrical anodes demonstrate higher mass transport capabilities and increased electrical efficiency compared to the plate anodes. Copper electrowinning represents the primary target market for the titanium-lead anode. A full-size cylindrical anode performance in copper electrowinning conditions was monitored over a year. The test anode to cathode voltage was stable in the 1.8 to 2.0 volt range. Copper cathode morphology was very smooth and uniform. There was no measurable anode weight loss during this time period. Quantitative chemical analysis of the anode surface showed that the lead content after testing remained at its initial level. No lead dissolution or transfer from the anode to the product occurred.A key benefit of the titanium-lead anode design is that cobalt additions to copper electrolyte should be eliminated. Cobalt is added to the electrolyte to help stabilize the lead oxide surface of conventional lead anodes. The presence of the titanium intimately mixed with the lead should eliminate the need for cobalt stabilization of the lead surface. The anode should last twice as long as the conventional lead anode. Energy savings should be achieved due to minimizing and stabilizing the anode-cathode distance in the electrowinning cells. The anode is easily substitutable into existing tankhouses without a rectifier change.The copper electrowinning test data indicate that the titanium-lead anode is a good candidate for further testing as a possible replacement for a conventional lead anode. A key consideration is the cost. Titanium costs have increased. One of the ways to get the anode cost down is manufacturing the anodes with fewer cylinders. Additional prototypes having different number of cylinders were constructed for a long-term commercial testing in a circuit without cobalt. The objective of the testing is to evaluate the need for cobalt, investigate the effect of decreasing the number of cylinders on the anode performance, and to optimize further the anode design in order to meet the operating requirements, minimize the voltage, maximize the life of the anode, and to balance this against a reasonable cost for the anode. It is anticipated that after testing of the additional prototypes, a whole cell commercial test will be conducted to complete evaluation of the titanium-lead anode costs/benefits.

Ferdman, Alla

2005-05-11T23:59:59.000Z

58

Applied Science  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Science Applied Science Correlation of predicted and measured iron oxidation states in mixed iron oxides H. D. Rosenfeld and W. L. Holstein Development of a quantitative measurement of a diesel spray core using synchrotron x-rays C.F. Powell, Y. Yue, S. Gupta, A. McPherson, R. Poola, and J. Wang Localized phase transformations by x-ray-induced heating R.A. Rosenberg, Q. Ma, W. Farrell, E.D. Crozier, G.J. Soerensen, R.A. Gordon, and D.-T. Jiang Resonant x-ray scattering at the Se edge in ferroelectric liquid crystal materials L. Matkin, H. Gleeson, R. Pindak, P. Mach, C. Huang, G. Srajer, and J. Pollmann Synchrotron-radiation-induced anisotropic wet etching of GaAs Q. Ma, D.C. Mancini, and R.A. Rosenberg Synchrotron-radiation-induced, selective-area deposition of gold on

59

Solution for a modular die-level anodic bonder  

E-Print Network (OSTI)

Anodic bonding is a common way to package silicon with Pyrex. The anodic bonding process requires high temperature, voltage, and moderate pressure to occur. Often, there are also expectations of alignment of features for ...

Khan, Christopher Joseph, 1982-

2004-01-01T23:59:59.000Z

60

Fuel cell system shutdown with anode pressure control  

DOE Patents (OSTI)

A venting methodology and pressure sensing and vent valving arrangement for monitoring anode bypass valve operating during the normal shutdown of a fuel cell apparatus of the type used in vehicle propulsion systems. During a normal shutdown routine, the pressure differential between the anode inlet and anode outlet is monitored in real time in a period corresponding to the normal closing speed of the anode bypass valve and the pressure differential at the end of the closing cycle of the anode bypass valve is compared to the pressure differential at the beginning of the closing cycle. If the difference in pressure differential at the beginning and end of the anode bypass closing cycle indicates that the anode bypass valve has not properly closed, a system controller switches from a normal shutdown mode to a rapid shutdown mode in which the anode inlet is instantaneously vented by rapid vents.

Clingerman, Bruce J. (Palmyra, NY); Doan, Tien M. (Columbia, MD); Keskula, Donald H. (Webster, NY)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Novel Design of Nanostructured Si Anode on Nanohair Array ...  

Science Conference Proceedings (OSTI)

Symposium, Nanostructured Materials for Lithium Ion Batteries and for Supercapacitors. Presentation Title, Novel Design of Nanostructured Si Anode on ...

62

Improving Baked Anode Density and Air Permeability Through ...  

Science Conference Proceedings (OSTI)

Presentation Title, Improving Baked Anode Density and Air Permeability Through Process Optimization and Coke Blending. Author(s), Bienvenu Ndjom,...

63

Sohar Aluminium's Anode Baking Furnace Operation  

Science Conference Proceedings (OSTI)

Gas consumption of less 1.9 GJ/t for a baking level (Lc) of greater than 33 angstrom has ... Historical and Future Challenges with the Vibrated Bulk Density Test Methods for ... Prebaked Anode from Coal Extract (2) - Effects of the Properties of...

64

Anode depolarizers in electrolytic hydrogen production  

SciTech Connect

Brookhaven National Laboratory manages an extensive program in the areas of hydrogen and energy storage potentials. As part of an ongoing portfolio analysis of projects, the prospects for applications for anode depolarizers are presented. The system requirements are outlined, and economic criteria are developed. It is concluded that moderate incentives exist for successful development. Research and Development priorities are formulated.

Beller, M.

1982-06-01T23:59:59.000Z

65

Virus-Enabled Silicon Anode for Lithium-Ion Batteries  

E-Print Network (OSTI)

Virus-Enabled Silicon Anode for Lithium-Ion Batteries Xilin Chen, Konstantinos Gerasopoulos emerged as one of the most promising next-generation anode materials for lithium-ion batteries due to its with remarkable cycling stability. KEYWORDS: silicon anode · lithium-ion battery · Tobacco mosaic virus · physical

Ghodssi, Reza

66

Use of under Calcined Coke to Produce Baked Anodes for ...  

Science Conference Proceedings (OSTI)

Studies on Impact of Calcined Petroleum from Different Sources on Anode Quality Study on Graphitization of Cathode Carbon Blocks for Aluminum Electrolysis.

67

ARTS - Anode & Rod Tracking System A New Tool for ...  

Science Conference Proceedings (OSTI)

Abstract Scope, ARTS is a combination of an anode and rod identification and tracking system, together with a customized database and analytical software.

68

Anodic oxidation of methanol using a new base electrocatalyst  

Science Conference Proceedings (OSTI)

Anodic oxidation of methanol, the reaction employed on the anode of the direct methanol fuel cell, is conventionally carried out using noble electrocatalysts. The best of these has been found to be a codeposited mixture of platinum and ruthenium. The use of base materials as anode catalysts requires, in addition to electrocatalytic activity, a low corrosion rate in the cell electrolyte. The authors present here some preliminary results of measurements of the anodic oxidation of methanol using a newly synthesized base electrocatalyst: this catalyst is passivated by the highly aggressive electrolyte.

Burstein, G.T.; Barnett, C.J.; Kucernak, A.R.J.; Williams, K.R. [Univ. of Cambridge (United Kingdom). Dept. of Materials Science and Metallurgy

1996-07-01T23:59:59.000Z

69

Ultrasound Removing Oxygen Gas Bubbles on Anode and ...  

Science Conference Proceedings (OSTI)

Cell voltage varies as the bubbles formed on the anodes surface. ... A Study on Heat Transfer Coefficient Distribution in High Pressure Hydrogen Quenching.

70

Composite Silicon Carbon Nano-fiber Anode for High Energy ...  

Science Conference Proceedings (OSTI)

Presentation Title, Composite Silicon Carbon Nano-fiber Anode for High .... of Super P Carbon Black and Silicon Carbide in Si-based Lithium Ion Batteries.

71

Investigation on Formation Mechanism of Non-Anode Effect Related ...  

Science Conference Proceedings (OSTI)

NAE-PFC will emit when there is not enough alumina under some or other anode's ... PFC and CO2 Emissions from an Australian Aluminium Smelter Using ...

72

Thermo-Electro-Mechanical Characterization of Anode Sealing ...  

Science Conference Proceedings (OSTI)

... and prepared in such a way that is representative of the industrial sealing process. ... Investigation on Air Reactivity and Electrolysis Consumption of Anode

73

High Performance Anode Material - Oak Ridge National Laboratory  

... low temperature, catalyst-free scalable process. The anode material consists of a vertically-aligned metal- core-shell nano-wire array.

74

Anode Dusting from a Potroom Perspective at Nordural And ...  

Science Conference Proceedings (OSTI)

Retrofit of a Combined Breaker Feeder with a Chisel Bath Contact Detection System to Reduce Anode Effect Frequency in a Potroom Simulating Traffic in a...

75

Bubble Transport by Electro-Magnetophoretic Foces at Anode ...  

Science Conference Proceedings (OSTI)

Retrofit of a Combined Breaker Feeder with a Chisel Bath Contact Detection System to Reduce Anode Effect Frequency in a Potroom Simulating Traffic in a...

76

Large Gas Bubbles under the Anodes of Aluminum Electrolysis Cells  

Science Conference Proceedings (OSTI)

Retrofit of a Combined Breaker Feeder with a Chisel Bath Contact Detection System to Reduce Anode Effect Frequency in a Potroom Simulating Traffic in a...

77

The Initiation, Propagation and Termination of Anode Effects in Hall ...  

Science Conference Proceedings (OSTI)

Retrofit of a Combined Breaker Feeder with a Chisel Bath Contact Detection System to Reduce Anode Effect Frequency in a Potroom Simulating Traffic in a...

78

Method to Reduce Camber in Anode-Supported SOFCs - Energy ...  

A) Typical camber developed in 7 cm x 7 cm anode-supported SOFC. B) Details on matched TEC backing layer opposite electrolyte surface for camber ...

79

Cathode/Anode Selection and Full Cell Performance for Stationary ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cathode/Anode Selection and Full Cell Performance for Stationary Li-ion Battery System. Author(s), Daiwon Choi, Donghai Wang, Vilayanur...

80

Hydro Aluminium's Historical Evolution of Closed Type Anode ...  

Science Conference Proceedings (OSTI)

The increasing demand for higher production and larger anodes during the last ... rebuilding of the furnaces are described, including maximum utilisation of the...

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Degradation of SOFC anodes and SOFC performance in coal ...  

Science Conference Proceedings (OSTI)

Symposium, Materials in Clean Power Systems V: Clean Coal-, Hydrogen ... of SOFC anodes and SOFC performance in coal syngas containing phosphine.

82

NANOTUBE COMPOSITE ANODE MATERIALS SUITABLE FOR LITHIUM ION ...  

The present invention provides a composite material suitable for use in an anode for a lithium ion battery, the composite material comprising a layer of a lithium ...

83

Passivation Behaviour of Copper Anodes with Various Chemical ...  

Science Conference Proceedings (OSTI)

May 1, 2007 ... Anode passivation is one of the existing problems faced by copper refineries with the increase of current density and impurities content of the...

84

Influence of Raw Materials on the Properties of Anodes & Their ...  

Science Conference Proceedings (OSTI)

Then the course will outline different process steps and describe the influence of raw materials, such as petroleum coke, coal tar pitch, and anode butts on the...

85

Anodization of Aluminum-Titanium Alloys for Solar Cell Applications  

Science Conference Proceedings (OSTI)

Presentation Title, Anodization of Aluminum-Titanium Alloys for Solar Cell ... Migration of Nanotechnology from Laboratory to Market Place: Arci Experience.

86

Reliability Model for Different Configurations of Planar-SOFC Anode ...  

Science Conference Proceedings (OSTI)

The temperature field and contaminant concentration on planar-SOFC anode are interpreted from DREAM-SOFC, a multi-physics solver. Due to larger active...

87

A Green Anode Plant Performance Analysis Tool Fully Embedded In ...  

Science Conference Proceedings (OSTI)

Presentation Title, A Green Anode Plant Performance Analysis Tool Fully Embedded In The Plant Control System. Author(s), Xavier Genin, Pasquale Calo,

88

Oxide-based SOFC Anode Materials - Available Technologies ...  

Researchers at PNNL have developed a new class of nickel-free anode materials, consisting of a composite of doped cerium oxide and doped strontium ...

89

Ultrathin Alumina Coated Carbon Nanotubes as Anodes for High ...  

Science Conference Proceedings (OSTI)

Presentation Title, Ultrathin Alumina Coated Carbon Nanotubes as Anodes for High Capacity Li-Ion Battery. Author(s), Indranil Lahiri, Wonbong Choi. On-Site...

90

Nanostructured Anodes for Lithium-Ion Batteries - Energy ...  

New Anodes for Lithium-ion Batteries Increase Energy Density Four-Fold Savannah River Nuclear Solutions (SRNS), managing contractor of the Savannah River Site (SRS ...

91

A Model for Predicting the Electrical Resistivity of Baked Anodes  

Science Conference Proceedings (OSTI)

One of the desired properties of the anodes is low electrical resistivity. A proper understanding of the effect of different parameters on electrical resistivity can...

92

Carbon Anode Modeling for Electric Energy Savings in  

Science Conference Proceedings (OSTI)

Presentation Title, Carbon Anode Modeling for Electric Energy Savings in the Aluminium Reduction Cell. Author(s), Dag Herman Andersen, Z. L. Zhang. On- Site...

93

Evolution of Anode Grade Calcined Coke - Programmaster.org  

Science Conference Proceedings (OSTI)

The term "anode grade coke" has been used as a broad definition to describe delayed coke with a sponge structure containing relatively low levels of trace...

94

Anode Paste Plants: Innovative Solution for Optimum Emission ...  

Science Conference Proceedings (OSTI)

Low PAH concentration streams from the anode former area are treated using a coke dry-scrubber whereas the higher concentration streams from the paste...

95

Determination of Coke Calcination Level and Anode Baking Level  

Science Conference Proceedings (OSTI)

Presentation Title, Determination of Coke Calcination Level and Anode Baking Level Application and Reproducibility of Lc Based Methods. Author(s), Stein...

96

Traceability of Raw Materials in Silos in an Anode Plant  

Science Conference Proceedings (OSTI)

Different coke and pitch mixtures are commonly used in anode manufacturing to meet various regulations and/or due to economics and availability. This makes it

97

Characterization of Dry Aggregates in Carbon Anodes by Image ...  

Science Conference Proceedings (OSTI)

Anodes are mainly composed of dry aggregates such as calcined petroleum coke and recycled materials with pitch as the binder. Granulometry of the dry...

98

Alternative Anode Reaction for Copper Electrowinning  

DOE Green Energy (OSTI)

This report describes a project funded by the Department of Energy, with additional funding from Bechtel National, to develop a copper electrowinning process with lower costs and lower emissions than the current process. This new process also includes more energy efficient production by using catalytic-surfaced anodes and a different electrochemical couple in the electrolyte, providing an alternative oxidation reaction that requires up to 50% less energy than is currently required to electrowin the same quantity of copper. This alternative anode reaction, which oxidizes ferric ions to ferrous, with subsequent reduction back to ferric using sulfur dioxide, was demonstrated to be technically and operationally feasible. However, pure sulfur dioxide was determined to be prohibitively expensive and use of a sulfur burner, producing 12% SO{sub 2}, was deemed a viable alternative. This alternate, sulfur-burning process requires a sulfur burner, waste heat boiler, quench tower, and reaction towers. The electrolyte containing absorbed SO{sub 2} passes through activated carbon to regenerate the ferrous ion. Because this reaction produces sulfuric acid, excess acid removal by ion exchange is necessary and produces a low concentration acid suitable for leaching oxide copper minerals. If sulfide minerals are to be leached or the acid unneeded on site, hydrogen was demonstrated to be a potential reductant. Preliminary economics indicate that the process would only be viable if significant credits could be realized for electrical power produced by the sulfur burner and for acid if used for leaching of oxidized copper minerals on site.

Not Available

2005-07-01T23:59:59.000Z

99

Novel Anode Materials For Solid Oxide Fuel Cells Dissertation committee  

E-Print Network (OSTI)

and fabrication of alternative anodes for direct methane oxidation in SOFC". Publisher: Twente University Press, P cells (SOFC). The principles and materials employed for SOFC are described. Emphasis is on the anode (PAFC), · the molten carbonate fuel cell (MCFC), · the solid oxide fuel cell (SOFC). Each type of fuel

Verweij, Henk

100

Electrolytic production of high purity aluminum using inert anodes  

DOE Patents (OSTI)

A method of producing commercial purity aluminum in an electrolytic reduction cell comprising inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The inert anodes used in the process preferably comprise a cermet material comprising ceramic oxide phase portions and metal phase portions.

Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Electrolytic production of high purity aluminum using ceramic inert anodes  

DOE Patents (OSTI)

A method of producing commercial purity aluminum in an electrolytic reduction cell comprising ceramic inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The ceramic inert anodes used in the process may comprise oxides containing Fe and Ni, as well as other oxides, metals and/or dopants.

Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Douglas A. (Murrysville, PA); DiMilia, Robert A. (Baton Rouge, LA); Dynys, Joseph M. (New Kensington, PA); Phelps, Frankie E. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

2002-01-01T23:59:59.000Z

102

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

A Better Anode Design to Improve A Better Anode Design to Improve Lithium-Ion Batteries A Better Anode Design to Improve Lithium-Ion Batteries Print Friday, 23 March 2012 13:53 Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds

103

Microsoft PowerPoint - NanoAnode for Li-ion Batteries SRNL-L9100...  

NLE Websites -- All DOE Office Websites (Extended Search)

Anodes for Lithium-Ion Batteries at a glance patent pending increase energy density longer cyclic life replaces graphite anodes simple and lower cost...

104

Inert anodes and advanced smelting of aluminum  

SciTech Connect

This report provides a broad assessment of open literature and patents that exist in the area of inert anodes and their related cathode systems and cell designs, technologies that are relevant for the advanced smelting of aluminum. The report also discusses the opportunities, barriers, and issued associated with these technologies from a technical, environmental, and economic viewpoint. It discusses the outlook for the direct retrofit of advanced reduction technologies to existing aluminum smelters, and compares retrofits to ''brown field'' usage and ''green field'' adoption of the technologies. A number of observations and recommendations are offered for consideration concerning further research and development efforts that may be directed toward these advanced technologies. The opportunities are discussed in the context of incremental progress that is being made in conventional Hall-Heroult cell systems.

ASME Technical Working Group on Inert Anode Technologies

1999-07-01T23:59:59.000Z

105

Carbonaceous materials as lithium intercalation anodes  

Science Conference Proceedings (OSTI)

Commercial and polymer-derived carbonaceous materials were examined as lithium intercalation anodes in propylene carbonate (pyrolysis graphites) electrolytes. The reversible capacity (180--355 mAh/g) and the irreversible capacity loss (15--200 % based on reversible capacity) depend on the type of binder, carbon type, morphology, and phosphorus doping concentration. A carbon-based binder was chosen for electrode fabrication, producing mechanically and chemically stable electrodes and reproducible results. Several types of graphites had capacity approaching LiC{sub 6}. Petroleum fuel green cokes doped with phosphorous gave more than a 20 % increase in capacity compared to undoped samples. Electrochemical characteristics are related to SEM, TEM, XRD and BET measurements.

Tran, T.D.; Feikert, J.H. [Lawrence Livermore National Lab., CA (United States); Mayer, S.T. [Polystor, Livermore, CA (United States); Song, X.; Kinoshita, K. [Lawrence Berkeley Lab., CA (United States)

1994-10-01T23:59:59.000Z

106

Carbonaceous materials as lithium intercalation anodes  

DOE Green Energy (OSTI)

Commercial and polymer-derived carbonaceous materials were examined as lithium intercalation anodes in propylene carbonate (pyrolysis < 1350C, carbons) and ethylene carbonate/dimethyl carbonate (graphites) electrolytes. The reversible capacity (180--355 mAh/g) and the irreversible capacity loss (15--200 % based on reversible capacity) depend on the type of binder, carbon type, morphology, and phosphorus doping concentration. A carbon-based binder was chosen for electrode fabrication, producing mechanically and chemically stable electrodes and reproducible results. Several types of graphites had capacity approaching LiC{sub 6}. Petroleum fuel green cokes doped with phosphorous gave more than a 20 % increase in capacity compared to undoped samples. Electrochemical characteristics are related to SEM, TEM, XRD and BET measurements.

Tran, T.D.; Feikert, J.H. [Lawrence Livermore National Lab., CA (United States); Mayer, S.T. [Polystor, Livermore, CA (United States); Song, X.; Kinoshita, K. [Lawrence Berkeley Lab., CA (United States)

1994-10-01T23:59:59.000Z

107

Inert Anode Life in Low Temperature Reduction Process  

Science Conference Proceedings (OSTI)

The production of aluminum metal by low temperature electrolysis utilizing metal non-consumable anodes and ceramic cathodes was extensively investigated. Tests were performed with traditional sodium fluoride--aluminum fluoride composition electrolytes, potassium fluoride-- aluminum fluoride electrolytes, and potassium fluoride--sodium fluoride--aluminum fluoride electrolytes. All of the Essential First-Tier Requirements of the joint DOE-Aluminum Industry Inert Anode Road Map were achieved and those items yet to be resolved for commercialization of this technology were identified. Methods for the fabrication and welding of metal alloy anodes were developed and tested. The potential savings of energy and energy costs were determined and potential environmental benefits verified.

Bradford, Donald R.

2005-06-30T23:59:59.000Z

108

Graphene/Si multilayer structure anodes for advanced half and ...  

paper composite as anodes for rechargeable LIBs with high ... Basic Energy Sciences, of the U.S. Department of Energy under Contract no. DE-AC02-05CH11231.

109

Inconel Inert Anode Current Collector for Solid Oxide Membrane  

Science Conference Proceedings (OSTI)

Abstract Scope, An innovative inert anode current collector is successfully developed and ... During electrolysis at 1423 K, magnesium cations in the flux are reduced at a ... Inclusions from Molten Steel Using a High Frequency Magnetic Field.

110

Viscoplastic Modeling of the Green Anode Forming Process  

Science Conference Proceedings (OSTI)

... viscoplastic constitutive law using the concept of natural configuration has been developed. ... Improving Fuel Gas Injection in Anode Baking Furnace ... USE OF COAL TAR PITCH COKE FOR PRODUCING PREBAKED ELECTRODES.

111

Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency  

E-Print Network (OSTI)

shift" (8). HydroQuebec's SNG-12 anode graphite was chosenElectrode laminates with SNG-12 graphite as the activePrevious experiments with SNG-12 graphite in coin cells with

Ridgway, Paul

2010-01-01T23:59:59.000Z

112

Porous anodic aluminum oxide scaffolds; formation mechanisms and applications  

E-Print Network (OSTI)

Nanoporous anodic aluminium oxide (AAO) can be created with pores that self-assemble into ordered configurations. Nanostructured metal oxides have proven to be very useful as scaffolds for growth of nanowires and nanotubes ...

Oh, Jihun

2010-01-01T23:59:59.000Z

113

BSA 08-14: A Multi-Anode Ionization Chamber  

BSA 08-14: A Multi-Anode Ionization Chamber. BNL Reference Number: BSA 08-14. Patent Status: U.S. Patent Number 7,858,949 was issued on December 28, 2010

114

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy....

115

Anode for a secondary, high-temperature electrochemical cell  

DOE Patents (OSTI)

A high-temperature, secondary electrochemical cell includes an anode containing lithium, an electrolyte containing lithium ions and a cathode containing a chalcogen material such as sulfur or a metallic sulfide. The anode includes a porous substrate formed of, for instance, a compacted mass of entangled metallic fibers providing interstitial crevices for receiving molten lithium metal. The surfaces of the interstitial crevices are provided with a coating of cobalt metal to enhance the retention of the molten lithium metal within the substrate.

Vissers, Donald R. (Naperville, IL); Tani, Benjamin S. (Chicago, IL)

1976-01-01T23:59:59.000Z

116

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, Eugene (Coram, NY)

1985-01-01T23:59:59.000Z

117

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, E.

1984-04-10T23:59:59.000Z

118

CX-005369: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Replacement of Big Hill Deep Anode Ground Bed Site for Cavern 103CX(s) Applied: B1.3Date: 02/22/2011Location(s): TexasOffice(s): Strategic Petroleum Reserve Field Office

119

Working Principle of the Hollow-Anode Plasma Source André Anders and Simone Anders  

NLE Websites -- All DOE Office Websites (Extended Search)

Working Principle of the Hollow-Anode Plasma Source Working Principle of the Hollow-Anode Plasma Source André Anders and Simone Anders Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 Abstract The hollow-anode discharge is a special form of glow discharge. It is shown that a drastically reduced anode area is responsible for a positive anode voltage drop of 30-40 V and an increased anode sheath thickness. This leads to an ignition of a relatively dense plasma in front of the anode hole. Langmuir probe measurements inside a specially designed hollow anode plasma source give an electron density and temperature of n e = 10 9 - 10 11 cm -3 and T e = 1 - 3 eV, respectively (nitrogen, current 100 mA, flow rate 5-50 scc/min). Driven by a pressure gradient, the "anode" plasma is blown through

120

Plant-scale anodic dissolution of unirradiated IFR fuel pins  

Science Conference Proceedings (OSTI)

This report discusses anodic dissolution which is a major operation in the pyrometallurgical process for recycling spent metal fuels from the Integral Fast Reactor (IFR), an advanced reactor design developed at Argonne National Laboratory. This process involves electrorefining the heavy metals (uranium and plutonium) from chopped, steel-clad fuel segments. The heavy metals are electrotransported from anodic dissolution baskets to solid and liquid cathodes in a molten salt electrolyte (LiCl-KCI) at 500{degrees}C. Uranium is recovered on a solid cathode mandrel, while a uranium-plutonium mixture is recovered in a liquid cadmium cathode. The anode configuration consists of four baskets mounted on an anode shaft. These baskets provide parallel circuits in the electrolyte and salt flow through the chopped fuelbed as the baskets are rotated. The baskets for the engineering-scale tests were sized to contain up to 2.5 kg of heavy metal. Anodic dissolution of 10 kg batches of chopped, steel-clad simulated tuel (U-10% Zr and U-Zr-Fs alloy) was demonstrated.

Gay, E.C.; Tomczuk, Z.; Miller, W.E.

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Low cost fuel cell diffusion layer configured for optimized anode water management  

DOE Patents (OSTI)

A fuel cell comprises a cathode gas diffusion layer, a cathode catalyst layer, an anode gas diffusion layer, an anode catalyst layer and an electrolyte. The diffusion resistance of the anode gas diffusion layer when operated with anode fuel is higher than the diffusion resistance of the cathode gas diffusion layer. The anode gas diffusion layer may comprise filler particles having in-plane platelet geometries and be made of lower cost materials and manufacturing processes than currently available commercial carbon fiber substrates. The diffusion resistance difference between the anode gas diffusion layer and the cathode gas diffusion layer may allow for passive water balance control.

Owejan, Jon P; Nicotera, Paul D; Mench, Matthew M; Evans, Robert E

2013-08-27T23:59:59.000Z

122

Applied Quantum Information Science  

Science Conference Proceedings (OSTI)

Applied Quantum Information Science. Summary: Theory is being developed and used to devise methods for preserving ...

2012-05-30T23:59:59.000Z

123

Battery with modular air cathode and anode cage  

DOE Patents (OSTI)

A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH)

1987-01-01T23:59:59.000Z

124

Battery with modular air cathode and anode cage  

DOE Patents (OSTI)

A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH); Turk, Thomas R. (Mentor, OH)

1988-01-01T23:59:59.000Z

125

The dependence of natural graphite anode performance on electrode density  

DOE Green Energy (OSTI)

The effect of electrode density for lithium intercalation and irreversible capacity loss on the natural graphite anode in lithium ion batteries was studied by electrochemical methods. Both the first-cycle reversible and irreversible capacities of the natural graphite anode decreased with an increase in the anode density though compression. The reduction in reversible capacity was attributed to a reduction in the chemical diffusion coefficient for lithium though partially agglomerated particles with a larger stress. For the natural graphite in this study the potentials for Li (de)insertion shifted between the first and second formation cycles and the extent of this shift was dependent on electrode density. The relation between this peak shift and the irreversible capacity loss are probably both due to the decrease in graphite surface area with compression.

Shim, Joongpyo; Striebel, Kathryn A.

2003-11-01T23:59:59.000Z

126

Pulsed neutron generator using shunt between anode and cathode  

SciTech Connect

A pulsed neutron generator for well logging is provided having a resistor connected between the anode and cathode. The resistor provides a direct current path whereby corona current can flow between the cathode and a corona point without the necessity for the ion source to conduct. In an alternative embodiment, the secondary coil of a pulsing transformer is connected in series with a resistor between the anode and cathode. In an alternative embodiment, a corona regulator in series with the collector-emitter of a transistor is connected between the cathode and anode of the neutron source and the base drive to the transistor is provided by a light-responsive solar cell activatable by an external lamp. Circuitry is provided for utilizing the various neutron sources.

Culver, R.B.

1976-12-07T23:59:59.000Z

127

Overview of SOFC Anode Interactions with Coal Gas Impurities  

SciTech Connect

An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

O. A. Marina; L. R. Pederson; R. Gemmen; K. Gerdes; H. Finklea; I. B. Celik

2010-03-01T23:59:59.000Z

128

Electrolytic production of metals using a resistant anode  

DOE Patents (OSTI)

An electrolytic process is described comprising evolving oxygen on an anode in a molten salt, the anode comprising an alloy comprising a first metal and a second metal, both metals forming oxides, the oxide of the first metal being more resistant than the second metal to attack by the molten salt, the oxide of the second metal being more resistant than the first metal to the diffusion of oxygen. The electrode may also be formed of CuAlO[sub 2] and/or Cu[sub 2]O. 2 figs.

Tarcy, G.P.; Gavasto, T.M.; Ray, S.P.

1986-11-04T23:59:59.000Z

129

Overview of SOFC Anode Interactions with Coal Gas Impurities  

Science Conference Proceedings (OSTI)

An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

2010-05-01T23:59:59.000Z

130

Electrolytic production of metals using a resistant anode  

DOE Patents (OSTI)

An electrolytic process comprising evolving oxygen on an anode in a molten salt, the anode comprising an alloy comprising a first metal and a second metal, both metals forming oxides, the oxide of the first metal being more resistant than the second metal to attack by the molten salt, the oxide of the second metal being more resistant than the first metal to the diffusion of oxygen. The electrode may also be formed of CuAlO.sub.2 and/or Cu.sub.2 O.

Tarcy, Gary P. (Plum Borough, PA); Gavasto, Thomas M. (New Kensington, PA); Ray, Siba P. (Plum Borough, PA)

1986-01-01T23:59:59.000Z

131

Novel Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

One of the unique advantages of SOFCs over other types of fuel cells is the potential for direct utilization of hydrocarbon fuels (it may involve internal reforming). Unfortunately, most hydrocarbon fuels contain sulfur, which would dramatically degrade SOFC performance at parts-per-million (ppm) levels. Low concentration of sulfur (ppm or below) is difficult to remove efficiently and cost-effectively. Therefore, knowing the exact poisoning process for state-of-the-art anode-supported SOFCs with Ni-YSZ cermet anodes, understanding the detailed anode poisoning mechanism, and developing new sulfur-tolerant anodes are essential to the promotion of SOFCs that run on hydrocarbon fuels. The effect of cell operating conditions (including temperature, H{sub 2}S concentration, cell voltage/current density, etc.) on sulfur poisoning and recovery of nickel-based anode in SOFCs was investigated. It was found that sulfur poisoning is more severe at lower temperature, higher H{sub 2}S concentration or lower cell current density (higher cell voltage). In-situ Raman spectroscopy identified the nickel sulfide formation process on the surface of a Ni-YSZ electrode and the corresponding morphology change as the sample was cooled in H{sub 2}S-containing fuel. Quantum chemical calculations predicted a new S-Ni phase diagram with a region of sulfur adsorption on Ni surfaces, corresponding to sulfur poisoning of Ni-YSZ anodes under typical SOFC operating conditions. Further, quantum chemical calculations were used to predict the adsorption energy and bond length for sulfur and hydrogen atoms on various metal surfaces. Surface modification of Ni-YSZ anode by thin Nb{sub 2}O{sub 5} coating was utilized to enhance the sulfur tolerance. A multi-cell testing system was designed and constructed which is capable of simultaneously performing electrochemical tests of 12 button cells in fuels with four different concentrations of H{sub 2}S. Through systematical study of state-of-the-art anode-supported SOFC button cells, it is seen that the long-term sulfur poisoning behavior of those cells indicate that there might be a second-stage slower degradation due to sulfur poisoning, which would last for a thousand hour or even longer. However, when using G-18 sealant from PNNL, the 2nd stage poisoning was effectively prohibited.

Lei Yang; Meilin Liu

2008-12-31T23:59:59.000Z

132

Controlling Activity and Stability of Ni-YSZ Catalysts for On-Anode Reforming  

DOE Green Energy (OSTI)

The purposes of the project are to develop an effective Ni-YSZ-based anode for on-anode reforming of methane and natural gas and develop methods to control endothermic steam reforming activity.

King, D.L.; Wang, Y.; Chin, Y-H.; Lin, Y.; Roh, H-S.; Rozmiarek, B.

2005-01-27T23:59:59.000Z

133

Solid state thin film battery having a high temperature lithium alloy anode  

SciTech Connect

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

Hobson, David O. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

134

Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method  

SciTech Connect

A battery structure including a cathode, a lithium metal anode and an electrolyte disposed between the lithium anode and the cathode utilizes a thin-film layer of lithium phosphorus oxynitride overlying so as to coat the lithium anode and thereby separate the lithium anode from the electrolyte. If desired, a preliminary layer of lithium nitride may be coated upon the lithium anode before the lithium phosphorous oxynitride is, in turn, coated upon the lithium anode so that the separation of the anode and the electrolyte is further enhanced. By coating the lithium anode with this material lay-up, the life of the battery is lengthened and the performance of the battery is enhanced.

Bates, John B. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

135

Pure Oxygen Anodes for Low- or Zero-carbon Energy Efficient ...  

Science Conference Proceedings (OSTI)

A solid electrolyte, e.g. zirconia, between the salt and anode removes the molten salt stability constraint, and can act as a container for a liquid metal anode.

136

Effect of Sulfur and Hydrocarbon Fuels on Titanate/Ceria SOFC Anodes  

DOE Green Energy (OSTI)

The purpose of the project is to develop low-cost, high-performance anodes that offer low polarization resistance as well as improved tolerance for nonidealities in anode environment such as redox cycles, sulfur and other poisons, and hydrocarbons.

Marina, O.A.; Pedersen, L.R.; Stevenson, J.W.

2005-01-27T23:59:59.000Z

137

New Green Anode Plant at EMAL Start-Up and Operation in the ...  

Science Conference Proceedings (OSTI)

... EMAL Aluminium Smelter project located in the Khalifa Port & Industrial Zone at Al Taweelah, halfway ... Energy Saving Technologies for Anode Manufacturing ... New Method for Representative Measurement of Anode Electrical Resistance.

138

Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts (Presentation)  

DOE Green Energy (OSTI)

This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.

Dinh, H.; Gennett, T.

2010-06-11T23:59:59.000Z

139

Silicon Anode Materials for All-Solid-State Lithium-ion Microbatteries  

Science Conference Proceedings (OSTI)

Symposium, Nanostructured Materials for Lithium Ion Batteries and for Supercapacitors. Presentation Title, Silicon Anode Materials for All-Solid-State...

140

Microstructure Change of SOFC Anode Caused by Electrochemical Redox Cycles  

E-Print Network (OSTI)

Power Systems. All Rights Reserved. 2 Contents Manufacturing development dependencies SOFC elements Reserved. 6 SOFC Elements: Independent of Construction Need to create and join the electrochemical Rights Reserved. 7 SOFC Stack Elements Fuel cell ­ Electrolyte, cathode, anode Interconnects ­ Deliver

Tokyo, University of

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Anode Materials for Rechargeable Li-Ion Batteries  

DOE Green Energy (OSTI)

This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

Fultz, B.

2001-01-12T23:59:59.000Z

142

Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites  

NLE Websites -- All DOE Office Websites (Extended Search)

Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Title Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Publication Type Journal Article Year of Publication 2012 Authors Ridgway, Paul L., Honghe Zheng, A. F. Bello, Xiangyun Song, Shidi Xun, Jin Chong, and Vincent S. Battaglia Journal Journal of The Electrochemical Society Volume 159 Issue 5 Pagination A520 Date Published 2012 ISSN 00134651 Abstract Battery grade graphite products from major suppliers to the battery industry were evaluated in 2325 coin cells with lithium counter electrodes. First and ongoing cycle efficiency, total and reversible capacity, cycle life and discharge rate performance were measured to compare these anode materials. We then ranked the graphites using a formula which incorporates these performance measures to estimate the cost of the overall system, relative to the cost of a system using MCMB. This analysis indicates that replacing MCMB with CCP-G8 (Conoco Phillips) would add little to no cost, whereas each of the other graphites would lead to a more costly system. Therefore we chose CCP-G8 as the new baseline graphite for the BATT program.

143

Novel carbonaceous materials used as anodes in lithium ion cells  

DOE Green Energy (OSTI)

The objective of this work is to synthesize disordered carbons used as anodes in lithium ion batteries, where the porosity and surface area are controlled. Both parameters are critical since the irreversible capacity obtained in the first cycle seems to be associated with the surface area (an exfoliation mechanism occurs in which the exposed surface area continues to increase).

Sandi, G.; Winans, R.E.; Carrado, K.A.

1997-09-01T23:59:59.000Z

144

FEM analysis of voltage drop in the anode connector induced by steel stub diameter reduction  

Science Conference Proceedings (OSTI)

Primary aluminium production is a high-energy consumption process, and improving the energy efficiency of smelters could be economically viable. An issue in the Hall-Heroult prebake anode technology is the voltage drop in the anode connector caused by ... Keywords: Aluminium reduction cell, Carbon anode, Energy efficiency, Finite element method, Stub hole, Thermo-electro-mechanical modelling

Hugues Fortin; Nedeltcho Kandev; Mario Fafard

2012-05-01T23:59:59.000Z

145

Structural micro-porous carbon anode for rechargeable lithium-ion batteries  

DOE Patents (OSTI)

A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc. 6 figs.

Delnick, F.M.; Even, W.R. Jr.; Sylwester, A.P.; Wang, J.C.F.; Zifer, T.

1995-06-20T23:59:59.000Z

146

Structural micro-porous carbon anode for rechargeable lithium-ion batteries  

DOE Patents (OSTI)

A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc.

Delnick, Frank M. (Albuquerque, NM); Even, Jr., William R. (Livermore, CA); Sylwester, Alan P. (Washington, DC); Wang, James C. F. (Livermore, CA); Zifer, Thomas (Manteca, CA)

1995-01-01T23:59:59.000Z

147

Layer-by-Layer Characterization of a Model Biofuel Cell Anode by (in Situ) Vibrational Spectroscopy  

E-Print Network (OSTI)

Layer-by-Layer Characterization of a Model Biofuel Cell Anode by (in Situ) Vibrational Spectroscopy during the construction of a model biofuel cell anode. The model anode was a layered structure formedDH to the CB layer confirmed successful enzyme immobilization. 1. Introduction Biofuel cells use microorganisms

Brolo, Alexandre G.

148

Reduced temperature aluminum production in an electrolytic cell having an inert anode  

DOE Patents (OSTI)

Aluminum is produced by electrolytic reduction of alumina in a cell having a cathode, an inert anode and a molten salt bath containing metal fluorides and alumina. The inert anode preferably contains copper, silver and oxides of iron and nickel. Reducing the molten salt bath temperature to about 900-950.degree. C. lowers corrosion on the inert anode constituents.

Dawless, Robert K. (Monroeville, PA); Ray, Siba P. (Murrysville, PA); Hosler, Robert B. (Sarver, PA); Kozarek, Robert L. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

2000-01-01T23:59:59.000Z

149

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

Better Anode Design to Improve Lithium-Ion Batteries Print Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

150

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

A Better Anode Design to Improve Lithium-Ion Batteries Print A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

151

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

A Better Anode Design to Improve Lithium-Ion Batteries Print A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

152

Silicon Based Anodes for Li-Ion Batteries  

SciTech Connect

Silicon is environmentally benign and ubiquitous. Because of its high specific capacity, it is considered one of the most promising candidates to replace the conventional graphite negative electrode used in today's Li ion batteries. Silicon has a theoretical specific capacity of nearly 4200 mAh/g (Li21Si5), which is 10 times larger than the specific capacity of graphite (LiC6, 372 mAh/g). However, the high capacity of silicon is associated with huge volume changes (more than 300 percent) when alloyed with lithium, which can cause severe cracking and pulverization of the electrode and lead to significant capacity loss. Significant scientific research has been conducted to circumvent the deterioration of silicon based anode materials during cycling. Various strategies, such as reduction of particle size, generation of active/inactive composites, fabrication of silicon based thin films, use of alternative binders, and the synthesis of 1-D silicon nanostructures have been implemented by a number of research groups. Fundamental mechanistic research has also been performed to better understand the electrochemical lithiation and delithiation process during cycling in terms of crystal structure, phase transitions, morphological changes, and reaction kinetics. Although efforts to date have not attained a commercially viable Si anode, further development is expected to produce anodes with three to five times the capacity of graphite. In this chapter, an overview of research on silicon based anodes used for lithium-ion battery applications will be presented. The overview covers electrochemical alloying of the silicon with lithium, mechanisms responsible for capacity fade, and methodologies adapted to overcome capacity degradation observed during cycling. The recent development of silicon nanowires and nanoparticles with significantly improved electrochemical performance will also be discussed relative to the mechanistic understanding. Finally, future directions on the development of silicon based anodes will be considered.

Zhang, Jiguang; Wang, Wei; Xiao, Jie; Xu, Wu; Graff, Gordon L.; Yang, Zhenguo; Choi, Daiwon; Li, Xiaolin; Wang, Deyu; Liu, Jun

2012-06-15T23:59:59.000Z

153

SOUTHVIEWDR Center for Applied  

E-Print Network (OSTI)

/Geology Chemistry Biological Sciences Geology Lab Bookstore Reed Milledge Payne Memorial Hall SANFORD DR Center CAES Activity Center Visitors Center (Four Towers) Greenhouses Center for Applied Isotope Study

Hall, Daniel

154

Corrosion of cermet anodes during low temperature electrolysis of alumina. Final report  

SciTech Connect

Successful development of inert anodes to replace carbon anodes in Hall cells has the potential benefits of lower energy consumption,lower operating costs, and reduced CO{sub 2} and CO emissions. Using inert anodes at reduced current density and reduced operating temperature (800 C) has potential for decreasing the corrosion rate of inert anodes. It may also permit the use of new materials for containment and insulation. This report describes the fabrication characteristics and the corrosion performance of 5324-17% Cu Cermet anodes in 100 hour tests. Although some good results were achieved, the corrosion rate at low temperature (800 C) is varied and not significantly lower than typical results at high temperature ({approximately} 960 C). This report also describes several attempts at 200 hour tests, with one anode achieving 177 hours of continuous operation and another achieving a total of 235 hours but requiring three separate tests of the same anode. The longest run did show a lower wear rate in the last test; but a high resistance layer developed on the anode surface and forced an unacceptably low current density. It is recommended that intermediate temperatures be explored as a more optimal environment for inert anodes. Other electrolyte chemistries and anode compositions (especially high conductivity anodes) should be considered to alleviate problems associated with lower temperature operation.

Kozarek, R.L.; Ray, S.P.; Dawless, R.K.; LaCamera, A.F.

1997-09-26T23:59:59.000Z

155

OPERATION OF SOLID OXIDE FUEL CELL ANODES WITH PRACTICAL HYDROCARBON FUELS  

DOE Green Energy (OSTI)

This work was carried out to achieve a better understanding of how SOFC anodes work with real fuels. The motivation was to improve the fuel flexibility of SOFC anodes, thereby allowing simplification and cost reduction of SOFC power plants. The work was based on prior results indicating that Ni-YSZ anode-supported SOFCs can be operated directly on methane and natural gas, while SOFCs with novel anode compositions can work with higher hydrocarbons. While these results were promising, more work was clearly needed to establish the feasibility of these direct-hydrocarbon SOFCs. Basic information on hydrocarbon-anode reactions should be broadly useful because reformate fuel gas can contain residual hydrocarbons, especially methane. In the Phase I project, we have studied the reaction mechanisms of various hydrocarbons--including methane, natural gas, and higher hydrocarbons--on two kinds of Ni-containing anodes: conventional Ni-YSZ anodes and a novel ceramic-based anode composition that avoid problems with coking. The effect of sulfur impurities was also studied. The program was aimed both at achieving an understanding of the interactions between real fuels and SOFC anodes, and providing enough information to establish the feasibility of operating SOFC stacks directly on hydrocarbon fuels. A combination of techniques was used to provide insight into the hydrocarbon reactions at these anodes during SOFC operation. Differentially-pumped mass spectrometry was be used for product-gas analysis both with and without cell operation. Impedance spectroscopy was used in order to understand electrochemical rate-limiting steps. Open-circuit voltages measurements under a range of conditions was used to help determine anode electrochemical reactions. Life tests over a wide range of conditions were used to establish the conditions for stable operation of anode-supported SOFC stacks directly on methane. Redox cycling was carried out on ceramic-based anodes. Tests on sulfur tolerance of Ni-YSZ anodes were carried out.

Scott A. Barnett; Jiang Liu; Yuanbo Lin

2004-07-30T23:59:59.000Z

156

Applied Energy Programs  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Energy Programs Applied Energy Programs Applied Energy Programs Los Alamos is using its world-class scientific capabilities to enhance national energy security by developing energy sources with limited environmental impact and by improving the efficiency and reliability of the energy infrastructure. CONTACT US Acting Program Director Melissa Fox (505) 663-5538 Email Applied Energy Program Office serves as the hub connecting the Laboratory's scientific and technical resources to DOE sponsors, DoD programs, and to industry. The Applied Energy Program Office manages Los Alamos National Laboratory programs funded by the Department of Energy's (DOE's) Offices of Energy Efficiency/Renewable Energy, Electricity Delivery and Energy Reliability, and Fossil Energy. With energy use increasing across the nation and the

157

"Plasma Thruster with Magnetically Insulated Anode: Inventor Yevgeny  

NLE Websites -- All DOE Office Websites (Extended Search)

Plasma Thruster with Magnetically Insulated Anode: Inventor Yevgeny Plasma Thruster with Magnetically Insulated Anode: Inventor Yevgeny Raitses This invention relates to a new plasma thruster for space applications. The key innovations of this thruster allow it to effectively ionize different propellants, including gases, liquids and solids, at different flow rates, and to operate with wallout losses. Due to these characteristics and the design simplicity, this thruster can be miniaturized to operate at low power levels, including, but not limited to a few watts input power, and regimes relevant to Cubesat applications. The new thruster uses plasma with magnetized electrons and non-magnetized ions and consists of at least two stages, ionization and acceleration, which are physically separated by the geometry, magnetic field topology and

158

Electrocatalyst for alcohol oxidation at fuel cell anodes  

DOE Patents (OSTI)

In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

Adzic, Radoslav (East Setauket, NY); Kowal, Andrzej (Cracow, PL)

2011-11-02T23:59:59.000Z

159

A study of the failure mechanism of chlorine anodes  

DOE Green Energy (OSTI)

Thin coating RuO{sub 2}{minus}TiO{sub 2} electrodes, which mimic the DSA anodes, have been prepared and tested for their activity toward the chlorine evolution reaction and subjected to life time testing. Rutherford Backscattering Spectrometry has been used concurrently with electrochemical measurements to analyze changes in the ruthenium content of the coating. The decrease in electrode activity is found to be closely related to a decrease in Ru content, and the measured profiles indicate that the loss takes place across the thin coating. Failure is observed for electrodes with a Ru content below a critical concentration, but there is no evidence for the build up of a pure TiO{sub 2} layer. AFM imaging of an anode after failure sustained the hypothesis of loss of material.

Vallet, C.E.; Zuhr, R.A. [Oak Ridge National Lab., TN (United States); Tilak, B.V.; Chen, C.P. [Occidental Chemical Corp., Grand Island, NY (United States)

1995-12-31T23:59:59.000Z

160

Alternative anodic reactions in water splitting. Final report  

DOE Green Energy (OSTI)

An anodic depolarization path to hydrogen production through water electrolysis has been examined, using lignite, grass and household wastes. Iron was removed from lignite by extensive washing. The degree of dissolution of lignite in 5 M H/sub 2/So/sub 4/ at 100/sup 0/C is ca. 0.1 wt %. Washed lignite dissolves less than unwashed material. Cyclic voltammograms showed peaks arising from dissolved organics. Increase of temperature produced more peaks. In alkaline solution, peaks disappeared. Oxidation currents were three times greater if the lignite particles were in contact with the electrode compared with their absence from solution. Platinum anodes oxidized lignite better than PbO/sub 2/. Redox systems, added to the electrolyte, helped compound formation. Grass and household wastes gave similar results but lower oxidation currents. Compounds present in solution prior to electrolysis dissolve off the internal surfaces of lignite particles. Increased oxidation currents, caused when lignite particles came in contact with the anode, arose, not because of enhanced electrochemical reactions, but from enhanced lignite dissolution following erosion. The organic compounds eventually form CO/sub 2/; the presence of heavy oils lasts for 10 hr. Current densities up to 750 mA cm/sup -2/ at ca. 1 V should be obtainable. The hydrocarbons are formed via a Kolbe mechanism from carboxylic acids. Speculative economic considerations show that the final cost of hydrogen produced, using lignite as an anode depolarizer, is considerably cheaper than that from natural gas: $0.40 per GJ, or less, compared to $5 per GJ.

Murphy, O.J.; Bockris, J. O'M.

1984-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency Title Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency Publication Type Journal Article Year of Publication 2009 Authors Ridgway, Paul L., Honghe Zheng, Xiangyun Song, Gao Liu, Philip N. Ross, and Vincent S. Battaglia Journal Electrochemical Society Volume 19 Start Page 51 Issue 25 Pagination 51-57 Abstract Vinylene Carbonate (VC) was added to the electrolyte in graphite-lithium half-cells. We report its effect on the coulombic efficiency (as capacity shift) of graphite electrodes under various formation cycling conditions. Cyclic voltammetry on glassy carbon showed that VC passivates the electrode against electrolyte reduction. The dQ/dV plots of the first lithiation of the graphite suggest that VC alters the SEI layer, and that by varying the cell formation rate, the initial ratio of ethylene carbonate to VC in the SEI layer can be controlled. VC was found to decrease first cycle efficiency and reversible capacity (in ongoing cycling) when used to excess. However, experiments with VC additive used with various formation rates did not show any decrease in capacity shift.

162

Crystalline structure transformation of carbon anodes during gasification  

Science Conference Proceedings (OSTI)

The crystalline structure transformation of five carbon anodes during gasification in air and carbon dioxide was studied using quantitative X-ray diffraction (XRD) analysis and high-resolution transmission electron microscopy (HRTEM). XRD analysis and HRTEM observations confirmed that anodes have a highly ordered graphitic structure. The examination of partially gasified samples indicated that crystalline structure transformation occurred in two stages during gasification. The first stage involved the consumption of disorganized carbon matter in the initial 15% conversion. Oxygen was found to be more reactive toward disorganized carbon at this stage of the gasification process compared to carbon dioxide. Following this stage, as more carbon was consumed, especially with the removal of smaller crystallites, it was found that the crystalline structure became more ordered with increasing conversion levels. This is due to the merging of neighboring crystallites, required to maintain the minimum energy configuration. In addition, the interaction between the pitch and the coke components was found to be strongly linked to the initial coke structure. 'Stress graphitization' occurred at the pitch-coke interface, which helps to enhance the structural development of the anodes. 26 refs., 9 figs., 3 tabs.

Kien N. Tran; Adam J. Berkovich; Alan Tomsett; Suresh K. Bhatia [University of Queensland, St. Lucia, Qld. (Australia). Division of Chemical Engineering

2008-05-15T23:59:59.000Z

163

Essays in applied microeconomics  

E-Print Network (OSTI)

This dissertation consists of three chapters on topics in applied microeconomics. In the first chapter. I investigate whether voters are more likely to support additional spending on local public services when they perceive ...

Aron-Dine, Aviva

2012-01-01T23:59:59.000Z

164

Position-sensitive proportional counter with low-resistance metal-wire anode  

DOE Patents (OSTI)

A position-sensitive proportional counter circuit is provided which allows the use of a conventional (low-resistance, metal-wire anode) proportional counter for spatial resolution of an ionizing event along the anode of the counter. A pair of specially designed active-capacitance preamplifiers are used to terminate the anode ends wherein the anode is treated as an RC line. The preamplifiers act as stabilized active capacitance loads and each is composed of a series-feedback, low-noise amplifier, a unity-gain, shunt-feedback amplifier whose output is connected through a feedback capacitor to the series-feedback amplifier input. The stabilized capacitance loading of the anode allows distributed RC-line position encoding and subsequent time difference decoding by sensing the difference in rise times of pulses at the anode ends where the difference is primarily in response to the distributed capacitance along the anode. This allows the use of lower resistance wire anodes for spatial radiation detection which simplifies the counter construction and handling of the anodes, and stabilizes the anode resistivity at high count rates (>10.sup.6 counts/sec).

Kopp, Manfred K. (Oak Ridge, TN)

1980-01-01T23:59:59.000Z

165

Applied Science/Techniques  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Science/Techniques Applied Science/Techniques Applied Science/Techniques Print The ALS is an excellent incubator of new scientific techniques and instrumentation. Many of the technical advances that make the ALS a world-class soft x-ray facility are developed at the ALS itself. The optical components in use at the ALS-mirrors and lenses optimized for x-ray wavelengths-require incredibly high-precision surfaces and patterns (often formed through extreme ultraviolet lithography at the ALS) and must undergo rigorous calibration and testing provided by beamlines and equipment from the ALS's Optical Metrology Lab and Berkeley Lab's Center for X-Ray Optics. New and/or continuously improved experimental techniques are also a crucial element of a thriving scientific facility. At the ALS, examples of such "technique" highlights include developments in lensless imaging, soft x-ray tomography, high-throughput protein analysis, and high-power coherent terahertz radiation.

166

Liquid Tin Anode Direct Coal Fuel Cell - CellTech Power  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Tin Anode Direct Coal Liquid Tin Anode Direct Coal Fuel Cell-CellTech Power Background Direct carbon solid oxide fuel cells (SOFCs) offer a theoretical efficiency advantage over traditional SOFCs operating on gasified carbon (syngas). CellTech Power LLC (CellTech) has been developing a liquid tin anode (LTA) SOFC that can directly convert carbonaceous fuels including coal into electricity without gasification. One of the most significant impediments

167

Process and apparatus for recovery of fissionable materials from spent reactor fuel by anodic dissolution  

DOE Patents (OSTI)

An electrochemical process and apparatus for the recovery of uranium and plutonium from spent metal clad fuel pins is disclosed. The process uses secondary reactions between U.sup.+4 cations and elemental uranium at the anode to increase reaction rates and improve anodic efficiency compared to prior art processes. In another embodiment of the process, secondary reactions between Cd.sup.+2 cations and elemental uranium to form uranium cations and elemental cadmium also assists in oxidizing the uranium at the anode.

Tomczuk, Zygmunt (Orland Park, IL); Miller, William E. (Naperville, IL); Wolson, Raymond D. (Lockport, IL); Gay, Eddie C. (Park Forest, IL)

1991-01-01T23:59:59.000Z

168

Si-Graphene Anodes (ANL-10-018 and ANL-11-034)  

AV AILABLE FOR LICENSING Production process for low-cost, long-life, high-energy anodes with five times the specific energy. The Invention An advanced ...

169

Performance of Lithium Ion Cell Anode Graphites Under Various Cycling Conditions  

E-Print Network (OSTI)

CA 94720 Performance of Lithium Ion Cell Anode Graphitesevaluated (in coin cells with lithium counter electrodes) asanode materials for lithium-ion cells intended for use in

Ridgway, Paul

2010-01-01T23:59:59.000Z

170

Fullerene Film as a Coating Material for Silicon Thick Film Anodes ...  

Science Conference Proceedings (OSTI)

Presentation Title, Fullerene Film as a Coating Material for Silicon Thick Film Anodes for Lithium Ion Batteries. Author(s), Arenst Andreas Arie. On-Site Speaker

171

BSA 99-05: Anodes to Oxidize Alcohol in Fuel Cells  

BSA 99-05: Anodes to Oxidize Alcohol in Fuel Cells. BNL Reference Number: BSA 99-05. Summary. ... Brookhaven National Laboratory conducts research in ...

172

Reduction of Anode Effect Duration in 400kA Prebake Cells  

Science Conference Proceedings (OSTI)

Retrofit of a Combined Breaker Feeder with a Chisel Bath Contact Detection System to Reduce Anode Effect Frequency in a Potroom Simulating Traffic in a...

173

High Energy Density Anode Materials Based on SiO-SnCo/FeC for ...  

Science Conference Proceedings (OSTI)

Abstract Scope, High energy density anode material SiO-SnCoC is synthesized by mechanical alloying method and tested for lithium battery applications.

174

Cyclability Study of Si/TiN/C Composite Anode with High Rate ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cyclability Study of Si/TiN/C Composite Anode with High Rate Capability for Lithium-Ion Batteries. Author(s), Jiguo Tu, Shuqiang Jiao,...

175

Study of the Behaviour of LSCM Anode Composites in a Segmented ...  

Science Conference Proceedings (OSTI)

Symposium, Energy Conversion/Fuel Cells. Presentation Title, Study of the Behaviour of LSCM Anode Composites in a Segmented Planar Solid Oxide Fuel Cell.

176

Aligned TiO2 Nanotubes as Long Durability Anodes for Lithium-Ion ...  

Science Conference Proceedings (OSTI)

Aligned TiO2 Nanotubes as Long Durability Anodes for Lithium-Ion Batteries Aniline Coated Carbon Cryogel with Improved Cyclic Stability for Supercapacitor ...

177

A MORE EFFICIENT ANODE MICROSTRUCTURE FOR SOFCs BASED ON PROTON CONDUCTORS  

Science Conference Proceedings (OSTI)

While the desired microstructure of the state-of-the-art Ni-YSZ anode for a solid oxide fuel cell (SOFC) based on YSZ is well known, the anode microstructure for a SOFC based on a proton conductor is yet to be optimized. In this study, we examined the effect of anode porosity on the performance of a SOFC based on BaZr{sub 0.1}Ce{sub 0.7}Y{sub 0.1}Yb{sub 0.1}O{sub 3??} (BZCYYb), a mixed ion (proton and oxygen anion) conductor with high ionic conductivity at intermediate temperatures. Three cells with Ni-BZCYYb cermet anodes of different porosities (37%, 42%, and 50%) and identical electrolytes and cathode components were fabricated and tested. Under typical fuel cell operating conditions, the cell with anode of the lowest porosity (37%), prepared without pore former, achieved the highest performance, demonstrating a peak power density of 1.2 W/cm{sup 2} at 750 C. This is radically different from the results of Ni-YSZ anodes for YSZ based cells, where high anode porosity (?55%) is necessary to achieve high performance. The observed increase in performance (or electrocatalytic activity for anode reactions) is attributed primarily to the unique microstructure of the anode fabricated without the use of pore forming precursors.

Rainwater, Ben H; Liu, Mingfei; Liu, Meilin

2012-01-01T23:59:59.000Z

178

Adsorption of Propane on the Magnesium Oxide (100) Surface and Synthesis of Anodized Aluminum Oxide.  

E-Print Network (OSTI)

??This work is divided into two parts: the adsorption of propane on the magnesium oxide (100) surface and the synthesis of anodized aluminum oxide. The (more)

Felty, Michael John

2008-01-01T23:59:59.000Z

179

Titanium Oxides Thin Film Anodes for All-Solid-State Lithium Ion ...  

Science Conference Proceedings (OSTI)

Metallic lithium is not a suitable anode material for all-solid-state thin film batteries ... Application of Biomass Waste Materials in the Nano Mineral Synthesis.

180

Pitch Production Using Solvent Extraction of Coal: Suitability as Carbon Anode Precursor.  

E-Print Network (OSTI)

??Albertan coal has been used to produce extracts as precursor for production of anode coke. Coal extractability was studied using digestion with Tetralin in a (more)

Mohammad Ali Pour, Mehdi

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Ractivit de l'anode et dsulfuration : effet du niveau de calcination du coke.  

E-Print Network (OSTI)

??Les proprits du coke et la performance des anodes sont affectes par le niveau de calcination du coke. Une densit de coke (VBD) leve implique (more)

Bergeron-Lagac, Charles-Luc

2012-01-01T23:59:59.000Z

182

Applied Mathematics | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Mathematics Applied Mathematics Our work in applied mathematics ranges from algorithm design, to development of software tools and technology, to advanced simulations in...

183

Structural transformation of nickel hydroxide films during anodic oxidation  

DOE Green Energy (OSTI)

The transformation of anodically formed nickel hydroxide/oxy-hydroxide electrodes has been investigated. A mechanism is proposed for the anodic oxidation reaction, in which the reaction interface between the reduced and oxidized phases of the electrode evolves in a nodular topography that leads to inefficient utilization of the active electrode material. In the proposed nodular transformation model for the anodic oxidation reaction, nickel hydroxide is oxidized to nickel oxy-hydroxide in the region near the metal substrate. Since the nickel oxy-hydroxide is considerably more conductive than the surrounding nickel hydroxide, as further oxidation occurs, nodular features grow rapidly to the film/electrolyte interface. Upon emerging at the electrolyte interface, the reaction boundary between the nickel hydroxide and oxy-hydroxide phases spreads laterally across the film/electrolyte interface, creating an overlayer of nickel oxy-hydroxide and trapping uncharged regions of nickel hydroxide within the film. The nickel oxy-hydroxide overlayer surface facilitates the oxygen evolution side reaction. Scanning tunneling microscopy of the electrode in its charged state revealed evidence of 80 {endash} 100 Angstrom nickel oxy-hydroxide nodules in the nickel hydroxide film. In situ spectroscopic ellipsometer measurements of films held at various constant potentials agree quantitatively with optical models appropriate to the nodular growth and subsequent overgrowth of the nickel oxy-hydroxide phase. A two-dimensional, numerical finite difference model was developed to simulate the current distribution along the phase boundary between the charged and uncharged material. The model was used to explore the effects of the physical parameters that govern the electrode behavior. The ratio of the conductivities of the nickel hydroxide and oxy-hydroxide phases was found to be the dominant parameter in the system.

Crocker, R.W.; Muller, R.H.

1992-05-01T23:59:59.000Z

184

PEMFC reconfigured anodes for enhancing CO tolerance with air bleed.  

DOE Green Energy (OSTI)

Practical PEM fuel cells based on perfluorinated ionomer membranes (eg Nafion), most probably will use reformed fuel as primary source for the anode feed. The reformate, besides hydrogen, may contain trace amounts of carbon monoxide (CO. from a few to hundreds ppm), whose presence is detrimental to the cell performance. Energy conversion at fuel cells depends on highly dispersed carbon-supported Pt, where the hydrogen electro-oxidatisn takes place. However, CO strongly adsorbs on the Pt surface leading to a decreasing of the Pt active Surface area and consequently to losses in electrical current that are unacceptable for a practical device.

Uribe, F. J. (Francisco J.); Zawodzinski, T. A. (Thomas A.), Jr.

2001-01-01T23:59:59.000Z

185

FREE STANDING NANOSTRUCTURED ANODES FOR LI-ION RECHARGEABLE BATTERIES  

DOE Green Energy (OSTI)

The free standing nanorodes of aluminum and cobalt oxides were grown on electrode and tested as the anodes directly in the half-cell. The average diameter and length of the nanorods are 80 nm and 200 nm respectively. The aligned nanorods demonstrated high initial capacity from 1200-1400 mAh/g at rate of 0.5C. The gradually decrease of initial capacity was observed. The preliminary characterization shows that the changes of the crystalline structure and morphology during cycling may be responsible for the capacity decay.

Au, M.

2009-07-20T23:59:59.000Z

186

Anode Materials for Rechargeable Li-Ion Batteries  

DOE Green Energy (OSTI)

This is the annual progress report for the Grant DE-FG03-00ER15035. This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. Our materials studies on electrode materials divide into electronic studies of the valence at and around Li atoms, and the crystal structures of these materials. We are addressing the basic questions of how these change with Li concentration, and what long-term changes take place during charge/discharge cycling of the materials.

B. Fultz

2001-01-12T23:59:59.000Z

187

Ni/YSZ Anode Interactions with Impurities in Coal Gas  

DOE Green Energy (OSTI)

Performance of solid oxide fuel cell (SOFC) with nickel/zirconia anodes on synthetic coal gas in the presence of low levels of phosphorus, arsenic, selenium, sulfur, hydrogen chloride, and antimony impurities were evaluated. The presence of phosphorus and arsenic led to the slow and irreversible SOFC degradation due to the formation of secondary phases with nickel, particularly close to the gas inlet. Phosphorus and antimony surface adsorption layers were identified as well. Hydrogen chloride and sulfur interactions with the nickel were limited to the surface adsorption only, whereas selenium exposure also led to the formation of nickel selenide for highly polarized cells.

Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Coffey, Greg W.

2009-10-16T23:59:59.000Z

188

Carbons for battery anodes prepared using inorganic templates  

DOE Green Energy (OSTI)

Unique carbons with demonstrated utility as anodes for lithium secondary batteries have been prepared by heating hydrocarbons within an inorganic template. Disordered carbons with novel and desirable molecular porosity were synthesized by the pyrolysis of pyrene at 700 C within a pillared clay. The clay was removed by treatment with acid, leaving behind carbons with 15 to 50 {angstrom} holes. These holey carbons, when converted into electrodes, allow rapid diffusion of the lithium into and out of a carbon. Favorable results have been obtained in several tests, for example, a reversible capacity of 825 mAh/g has been achieved, about four times greater than commercial batteries using convention pyrolytic carbon.

Winans, R.E.; Carrado, K.A.; Sandi, G. [Argonne National Lab., IL (United States). Chemistry Div.

1997-07-01T23:59:59.000Z

189

Applied Science/Techniques  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Science/Techniques Print Applied Science/Techniques Print The ALS is an excellent incubator of new scientific techniques and instrumentation. Many of the technical advances that make the ALS a world-class soft x-ray facility are developed at the ALS itself. The optical components in use at the ALS-mirrors and lenses optimized for x-ray wavelengths-require incredibly high-precision surfaces and patterns (often formed through extreme ultraviolet lithography at the ALS) and must undergo rigorous calibration and testing provided by beamlines and equipment from the ALS's Optical Metrology Lab and Berkeley Lab's Center for X-Ray Optics. New and/or continuously improved experimental techniques are also a crucial element of a thriving scientific facility. At the ALS, examples of such "technique" highlights include developments in lensless imaging, soft x-ray tomography, high-throughput protein analysis, and high-power coherent terahertz radiation.

190

Aerogel and xerogel composites for use as carbon anodes  

Science Conference Proceedings (OSTI)

A method for forming a reinforced rigid anode monolith and fuel and product of such method. The method includes providing a solution of organic aerogel or xerogel precursors including at least one of a phenolic resin, phenol (hydroxybenzene), resorcinol(1,3-dihydroxybenzene), or catechol(1,2-dihydroxybenzene); at least one aldehyde compound selected from the group consisting of formaldehyde, acetaldehyde, and furfuraldehyde; and an alkali carbonate or phosphoric acid catalyst; adding internal reinforcement materials comprising carbon to said precursor solution to form a precursor mixture; gelling said precursor mixture to form a composite gel; drying said composite gel; and pyrolyzing said composite gel to form a wettable aerogel/carbon composite or a wettable xerogel/carbon composite, wherein said composites comprise chars and said internal reinforcement materials, and wherein said composite is suitable for use as an anode with the chars being fuel capable of being combusted in a molten salt electrochemical fuel cell in the range from 500 C to 800 C to produce electrical energy. Additional methods and systems/compositions are also provided.

Cooper, John F. (Oakland, CA); Tillotson, Thomas M. (Tracy, CA); Hrubesh, Lawrence W. (Pleasanton, CA)

2010-10-12T23:59:59.000Z

191

Overview of SOFC Anode Interactions with Coal Gas Impurities  

Science Conference Proceedings (OSTI)

Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

2009-08-11T23:59:59.000Z

192

Modeling and Performance of Anode-Supported SOFC  

Science Conference Proceedings (OSTI)

A "one-dimensional", steady-state model of an SOFC stack was needed to support the design of balance-of-plant components for a 5 kW mobile SOFC system. This "stack module" was required to predict appropriate stack voltage responses to changes in fuel composition, fuel flow rate, stack temperature and current demand, with response characteristics that were adjustable to changes in stack component materials and dimensions as well as to electrode porosity. The spreadsheet-based stack module was derived from the work by Kim, Virkar et al (see J. Electrochem. Soc. 146(1) 69-78 (1999)), with modifications suggested by Riess and Schoonman, p291 in CRC Handbook of Electrochemistry (1997) CRC Press. The usual overpotential terms account for ohmic resistance of the cell components, losses due to charge transfer at the electrodes, and losses due to diffusion of reactants into and products out of the porous electrodes. Response of the module is compared to published cell and stack data. After fitting adjustable parameters to match particular cell performance characteristics, the module responds reasonably well to changes in temperature and fuel concentration. The module is used to analyze the performance of anode-supported cells that were fabricated at PNNL (see abstract submitted by Stevenson, Meinhardt, Simner, Habeger and Canfield, "Fabrication and Testing of Anode-Supported SOFC").

Chick, Lawrence A.; Stevenson, Jeffry W.; Meinhardt, Kerry D.; Simner, Steven P.; Jaffe, John E.; Williford, Rick E.

2001-02-28T23:59:59.000Z

193

In situ reduction and evaluation of anode supported single chamber solid oxide fuel cells  

E-Print Network (OSTI)

cracking (reaction VII) CH4 + H2O CO + 3H2 steam reforming (reaction VIII) CH4 + CO2 2CO + 2H2 dry.05.118 #12;Abstract Single chamber anode-supported fuel cells are investigated under several methane analyses of anode reduction are performed at 700°C. Carbon deposition is observed under diluted methane

194

Electrochemical Evaluation of Thin-Film Li-Si Anodes Prepared by Plasma Spraying  

DOE Green Energy (OSTI)

Thin-film electrodes of a plasma-sprayed Li-Si alloy were evaluated for use as anodes in high-temperature thermally activated (thermal) batteries. These anodes were prepared using 44% Li/56% Si (w/w) material as feed material in a special plasma-spray apparatus under helium or hydrogen, to protect this air- and moisture-sensitive material during deposition. Anodes were tested in single cells using conventional pressed-powder separators and lithiated pyrite cathodes at temperatures of 400 to 550 C at several different current densities. A limited number of 5-cell battery tests were also conducted. The data for the plasma-sprayed anodes was compared to that for conventional pressed-powder anodes. The performance of the plasma-sprayed anodes was inferior to that of conventional pressed-powder anodes, in that the cell emfs were lower (due to the lack of formation of the desired alloy phases) and the small porosity of these materials severely limited their rate capability. Consequently, plasma-sprayed Li-Si anodes would not be practical for use in thermal batteries.

GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.; SCHARRER,GREGORY L.

1999-09-08T23:59:59.000Z

195

Solid state thin film battery having a high temperature lithium alloy anode  

DOE Patents (OSTI)

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

Hobson, D.O.

1998-01-06T23:59:59.000Z

196

The effect of compression on natural graphite anode performance and matrix conductivity  

DOE Green Energy (OSTI)

Anodes for lithium-ion cells were constructed from three types of natural graphite, two coated spherical and one flaky. Anode samples were compressed from 0 to 300 kg/cm2 and studied in half-cells to study the relations between anode density, SEI formation and anode cyclability. The C/25 formation of the SEI layer was found to depend on the nature of the graphite and the anode density. Compression of the uncoated graphite lead to an increased conductivity, but only slight improvements in the efficiency of the formation process. Compression of the anodes made from the amorphous-carbon-coated graphites greatly improved both the reversible capacity and first-cycle efficiency. In addition, the fraction of the irreversible charge associated with the surface of the graphite increased with compression, from both an increase in the electrolyte contact as well as compression of the amorphous layer. The cyclability of all of the anodes tended to improve with compression. This suggests that it is the improvement in the conductivity of the anode plays more of a role in the improvement in the cyclability than the formation process.

Striebel, K.A.; Sierra, A.; Shim, J.; Wang, C.-W.; Sastry, A.M.

2004-03-11T23:59:59.000Z

197

Diagnostic Setup for Characterization of Near-Anode Processes in Hall Thrusters  

DOE Green Energy (OSTI)

A diagnostic setup for characterization of the near-anode processes in Hall thrusters was designed and assembled. Experimental results with a single floating probe show that radial probe insertion does not cause perturbations to the discharge and therefore can be used for near-anode measurements.

L. Dorf; Y. Raitses; N. J. Fisch

2003-05-29T23:59:59.000Z

198

Assembly of Colloidal Nanoparticles into Anodic Aluminum Oxide Templates by Dip-Coating Process  

Science Conference Proceedings (OSTI)

In this paper, the assembly behavior of colloidal nanoparticles into anodic aluminum oxide (AAO) templates is investigated. Approximately 20-nm-diameter iron oxide (Fe2O3) particles stabilized by oleic acid and 5-nm-diameter CdSe ... Keywords: Anodic aluminum oxide, colloid nanoparticle, dip coating, self-assembly

Il Seo; Chang-Woo Kwon; Hyun Ho Lee; Yong-Sang Kim; Ki-Bum Kim; Tae-Sik Yoon

2009-11-01T23:59:59.000Z

199

Carbon Supported Polyaniline as Anode Catalyst: Pathway to Platinum-Free Fuel Cells  

E-Print Network (OSTI)

The effectiveness of carbon supported polyaniline as anode catalyst in a fuel cell (FC) with direct formic acid electrooxidation is experimentally demonstrated. A prototype FC with such a platinum-free composite anode exhibited a maximum room-temperature specific power of about 5 mW/cm2

Zabrodskii, A G; Malyshkin, V G; Sapurina, I Y

2006-01-01T23:59:59.000Z

200

Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects  

Science Conference Proceedings (OSTI)

Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

2011-01-10T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

DOE Green Energy (OSTI)

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

202

Applied antineutrino physics workshop.  

Science Conference Proceedings (OSTI)

This workshop is the fourth one of a series that includes the Neutrino Geophysics Conference at Honolulu, Hawaii, which I attended in 2005. This workshop was organized by the Astro-Particle and Cosmology laboratory in the recently opened Condoret building of the University of Paris. More information, including copies of the presentations, on the workshop is available on the website: www.apc.univ-paris7.fr/AAP2007/. The workshop aims at opening neutrino physics to various fields such that it can be applied in geosciences, nuclear industry (reactor and spent fuel monitoring) and non-proliferation. The workshop was attended by over 60 people from Europe, USA, Asia and Brazil. The meeting was also attended by representatives of the Comprehensive nuclear-Test Ban Treaty (CTBT) and the International Atomic Energy Agency (IAEA). The workshop also included a workshop dinner on board of a river boat sailing the Seine river.

Lund, James C.

2008-01-01T23:59:59.000Z

203

CHARACTERIZATION OF COAL- AND PETROLEUM-DERIVED BINDER PITCHES AND THE INTERACTION OF PITCH/COKE MIXTURES IN PRE-BAKED CARBON ANODES.  

E-Print Network (OSTI)

??Carbon anodes are manufactured from calcined petroleum coke (i.e. sponge coke) and recycled anode butts as fillers, and coal tar pitch (SCTP) as the binder. (more)

Suriyapraphadilok, Uthaiporn

2008-01-01T23:59:59.000Z

204

Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Dinh (PI) Dinh (PI) Thomas Gennett National Renewable Energy Laboratory October 1, 2009 Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts This presentation does not contain any proprietary, confidential, or otherwise restricted information Objectives Develop cost-effective, reliable, durable fuel cells for portable power applications (e.g., cell phones, computers, etc.) that meet all DOE targets. Note that the energy density (Wh/L), volumetric (W/L), and specific power (W/kg) all depend on knowing the weight and volume of the entire DMFC system as well as the volume and concentration of fuel, which are system specific (power application and manufacturer dependent). In our model study the surface power density levels on HOPG will allow for indirect evaluation of our system to DOE's energy density

205

Anode reactive bleed and injector shift control strategy  

DOE Patents (OSTI)

A system and method for correcting a large fuel cell voltage spread for a split sub-stack fuel cell system. The system includes a hydrogen source that provides hydrogen to each split sub-stack and bleed valves for bleeding the anode side of the sub-stacks. The system also includes a voltage measuring device for measuring the voltage of each cell in the split sub-stacks. The system provides two levels for correcting a large stack voltage spread problem. The first level includes sending fresh hydrogen to the weak sub-stack well before a normal reactive bleed would occur, and the second level includes sending fresh hydrogen to the weak sub-stack and opening the bleed valve of the other sub-stack when the cell voltage spread is close to stack failure.

Cai, Jun [Rochester, NY; Chowdhury, Akbar [Pittsford, NY; Lerner, Seth E [Honeoye Falls, NY; Marley, William S [Rush, NY; Savage, David R [Rochester, NY; Leary, James K [Rochester, NY

2012-01-03T23:59:59.000Z

206

Lithium ion batteries with titania/graphene anodes  

DOE Patents (OSTI)

Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m.sup.2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO.sub.4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

Liu, Jun; Choi, Daiwon; Yang, Zhenguo; Wang, Donghai; Graff, Gordon L; Nie, Zimin; Viswanathan, Vilayanur V; Zhang, Jason; Xu, Wu; Kim, Jin Yong

2013-05-28T23:59:59.000Z

207

Anodic dissolution characteristics and electrochemical migration lifetimes of Sn solder in NaCl and Na2SO4 solutions  

Science Conference Proceedings (OSTI)

In situ water drop tests and anodic polarization tests of pure Sn solder were carried out in deaerated 0.001% NaCl and Na"2SO"4 solutions to determine the correlation between anodic dissolution characteristics and the electrochemical migration lifetime. ... Keywords: Anodic dissolution, Electrochemical migration, Life time, Na2SO4, NaCl, Sn solder

Ja-Young Jung; Shin-Bok Lee; Young-Chang Joo; Ho-Young Lee; Young-Bae Park

2008-07-01T23:59:59.000Z

208

EFFECT OF FUEL IMPURITY ON STRUCTURAL INTEGRITY OF Ni-YSZ ANODE OF SOFCs  

SciTech Connect

Electricity production through the integration of coal gasification with solid oxide fuel cells (SOFCs) may potentially be an efficient technique for clean energy generation. However, multiple minor and trace components are naturally present in coals. These impurities in coal gas not only degrade the electrochemical performance of Ni-YSZ anode used in SOFCs, but also severely endanger the structural integrity of the Ni-YSZ anode. In this paper, effect of the trace impurity of the coal syngases on the mechanical degradation of Ni-YSZ anode was studied by using an integrated experimental/modeling approach. Phosphorus is taken as an example of impurity. Anode-support button cell was used to experimentally explore the migration of phosphorous impurity in the Ni-YSZ anode of SOFCs. X-ray mapping was used to show elemental distributions and new phase formation. The subsequent finite element stress analyses were conducted using the actual microstructure of the anode to illustrate the degradation mechanism. It was found that volume expansion induced by the Ni phase change produces high stress level such that local failure of the Ni-YSZ anode is possible under the operating conditions

Liu, Wenning N.; Sun, Xin; Marina, Olga A.; Pederson, Larry R.; Khaleel, Mohammad A.

2011-01-01T23:59:59.000Z

209

LOW-TEMPERATURE, ANODE-SUPPORTED HIGH POWER DENSITY SOLID OXIDE FUEL CELLS WITH NANOSTRUCTURED ELECTRODES  

DOE Green Energy (OSTI)

A simple, approximate analysis of the effect of differing cathode and anode areas on the measurement of cell performance on anode-supported solid oxide fuel cells, wherein the cathode area is smaller than the anode area, is presented. It is shown that the effect of cathode area on cathode polarization, on electrolyte contribution, and on anode resistance, as normalized on the basis of the cathode area, is negligible. There is a small but measurable effect on anode polarization, which results from concentration polarization. Effectively, it is the result of a greater amount of fuel transported to the anode/electrolyte interface in cases wherein the anode area is larger than the cathode area. Experiments were performed on cells made with differing cathode areas and geometries. Cathodic and anodic overpotentials measured using reference electrodes, and the measured ohmic area specific resistances by current interruption, were in good agreement with expectations based on the analysis presented. At 800 C, the maximum power density measured with a cathode area of {approx}1.1 cm{sup 2} was {approx}1.65 W/cm{sup 2} compared to {approx}1.45 W/cm{sup 2} for cathode area of {approx}2 cm{sup 2}, for anode thickness of {approx}1.3 mm, with hydrogen as the fuel and air as the oxidant. At 750 C, the measured maximum power densities were {approx}1.3 W/cm{sup 2} for the cell with cathode area {approx}1.1 cm{sup 2}, and {approx}1.25 W/cm{sup 2} for the cell with cathode area {approx}2 cm{sup 2}.

Anil V. Virkar

2001-06-21T23:59:59.000Z

210

Development of metal-coated ceramic anodes for molten carbonate fuel cells. Final report  

DOE Green Energy (OSTI)

This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

1990-03-01T23:59:59.000Z

211

Development of metal-coated ceramic anodes for molten carbonate fuel cells  

DOE Green Energy (OSTI)

This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

1990-03-01T23:59:59.000Z

212

A Damage Model for Degradation in the Electrodes of solid oxide fuel cells: Modeling the effects of sulfur and antimony in the anode  

Science Conference Proceedings (OSTI)

Over their designed lifetime, high temperature electrochemical devices, such as solid oxide fuel cells (SOFCs), can experience degradation in their electrochemical performance due to environmental conditions, operating conditions, contaminants, and other factors. Understanding the different degradation mechanisms in SOFCs and other electrochemical devices is essential to reducing performance degradation and increasing the lifetime of these devices. In this paper SOFC degradation mechanisms are discussed and a damage model is presented which describes performance degradation in SOFCs due to damage or degradation in the electrodes of the SOFC. A degradation classification scheme is presented that divides the various SOFC electrode degradation mechanisms into categories based on their physical effects on the SOFC. The application of the damage model and the classification method is applied to sulfur poisoning and antimony poisoning which occur in the anode of SOFCs. For sulfur poisoning the model is able to predict the degradation in SOFC performance based on the operating temperature and voltage of the fuel cell and the concentration of gaseous sulfur species in the anode. For antimony poisoning the effects of nickel removal from the anode matrix is investigated.

Ryan, Emily M.; Xu, Wei; Sun, Xin; Khaleel, Mohammad A.

2012-07-15T23:59:59.000Z

213

Applied and Computational Mathematics Division  

Science Conference Proceedings (OSTI)

Applied and Computational Mathematics Division. Topic Areas. Mathematics; Scientific Computing; Visualization; Quantum Computing. ...

2013-05-09T23:59:59.000Z

214

Observation of isolated nanopores formed by patterned anodic oxidation of aluminum thin films  

SciTech Connect

We report the formation of confined nanometer-scale regions of porous anodic alumina from thin aluminum films. Confinement is achieved by masking a thin Al film with a sputtered SiO{sub 2} layer, patterned by nanoimprint lithography of a polystyrene transfer layer. Anodization in 0.3 molar oxalic acid creates vertically aligned pores that were imaged with a combination of focused ion beam milling and scanning electron microscopy. Triplets, pairs, and single pores were observed following the anodization of isolated mask features approximately 100 nm in diameter.

Huang Qiyu; Lye, W.-K.; Reed, Michael L. [School of Microelectronics, Shanghai Jiaotong University, 1954 Huashan Road, Shanghai 200030 (China); Department of Electrical and Computer Engineering University of Virginia, Charlottesville, Virginia 22904 (United States)

2006-06-05T23:59:59.000Z

215

Non-consumable anode and lining for aluminum electrolytic reduction cell  

DOE Patents (OSTI)

An oxidation resistant, non-consumable anode, for use in the electrolytic reduction of alumina to aluminum, has a composition comprising copper, nickel and iron. The anode is part of an electrolytic reduction cell comprising a vessel having an interior lined with metal which has the same composition as the anode. The electrolyte is preferably composed of a eutectic of AlF.sub.3 and either (a) NaF or (b) primarily NaF with some of the NaF replaced by an equivalent molar amount of KF or KF and LiF.

Beck, Theodore R. (Seattle, WA); Brooks, Richard J. (Seattle, WA)

1994-01-01T23:59:59.000Z

216

Process and apparatus for recovery of fissionable materials from spent reactor fuel by anodic dissolution  

DOE Patents (OSTI)

An electrochemical process and apparatus for the recovery of uranium and plutonium from spent metal clad fuel pins is disclosed. The process uses secondary reactions between U{sup +4} cations and elemental uranium at the anode to increase reaction rates and improve anodic efficiency compared to prior art processes. In another embodiment of the process, secondary reactions between Cd{sup +2} cations and elemental uranium to form uranium cations and elemental cadmium also assists in oxidizing the uranium at the anode. 5 figs.

Tomczuk, Z.; Miller, W.E.; Wolson, R.D.; Gay, E.C.

1989-08-25T23:59:59.000Z

217

Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum  

DOE Patents (OSTI)

An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

2000-01-01T23:59:59.000Z

218

ANODE, CATHODE AND THIN FILM STUDIES FOR LOW TEMPERATURE SOFC'S  

DOE Green Energy (OSTI)

In this research the microstructure {leftrightarrow} property relations in solid oxide fuel cells (SOFC's) are being studied to better understand the mechanisms involved in cell performance. The overall aim is to fabricate SOFC's with controlled, stable, high performance microstructure. Most cathode studies were completed in the last DOE contract; studies during this year focused more on the influence of nonstoichiometry on the electrical performance. Studies indicate that nonstoichiometric La{sub x}Sr{sub 0.20}MnO{sub 3}(x = 0.70, 0.75, and 0.79) cathode compositions exhibit the best properties. A series of studies using these compositions fired on at temperatures of 1100, 1200, 1300 and 1400 C were performed. In all instances, 1200 C was the optimum, with the x = 0.70 composition being the best. It has an overpotential of only 0.04V at 1 A/cm{sup 2}. SEM analyses indicated no second phases or interdiffusion is detectable. Studies on optimization of anode compositions yielded the optimum volume fraction of Ni (45vol%), the best sintering temperature/time (1400 C/2 h), and the best starting materials (glycine-nitrate derived NiO and normal YSZ). In essence these results simply reflect the optimum microstructure. As such, they are being used to guide the development of optimized anodes for lower temperature operation based on Cu/CeO{sub 2} cermets. Marked success has been achieved on the placement of thin YSZ electrolytes on porous Ni/YSZ electrodes. The process being used is a transfer technique in which dense YSZ films are initially fabricated on NaCl or polymeric substrates, followed by partial dissolution of the substrate and placement of the film on the porous substrate. This technique has allowed us to produce structures with film thicknesses ranging from 70 to 3000 nm, and grain sizes ranging from 2 to 300 nm. Cells based on electrolytes this thick should operate in the 400--700 C range.

Dr. Wayne Huebner; Dr. Harlan U. Anderson

1999-11-01T23:59:59.000Z

219

Argonne CNM News: Batteries Get a Quick Charge with New Anode Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Batteries Get a Quick Charge with New Anode Technology Batteries Get a Quick Charge with New Anode Technology Tijana Rajh Argonne nanoscientist Tijana Rajh holds a strip of material created from titanium dioxide nanotubes. A team of researchers led by Tijana Rajh (Group Leader, Argonne Center for Nanoscale Materials NanoBio Interfaces Group), and Christopher Johnson (Argonne's Chemical Sciences & Engineering Division), working under a CNM user science project, discovered that nanotubes composed of titanium dioxide can switch their phase as a battery is cycled, gradually boosting their operational capacity. New batteries produced with this material can be recharged up to half of their original capacity in less than 30 seconds. By switching out conventional graphite anodes with titanium nanotube anodes, a surprising phenomenon occurs. As the battery cycles through

220

Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion Batteries  

E-Print Network (OSTI)

Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium** Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, USA Lithium cells that use organic electrolytes. The equilibrium reaction potential of lithium titanium phosphate

Cui, Yi

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Method for Plutonium-Gallium Separation by Anodic Dissolution of a Solid Plutonium-Gallium Alloy  

DOE Patents (OSTI)

Purified plutonium and gallium are efficiently recovered from a solid plutonium-gallium (Pu-Ga) alloy by using an electrorefining process. The solid Pu-Ga alloy is the cell anode, preferably placed in a moving basket within the electrolyte. As the surface of the Pu-Ga anode is depleted in plutonium by the electrotransport of the plutonium to a cathode, the temperature of the electrolyte is sufficient to liquify the surface, preferably at about 500 C, resulting in a liquid anode layer substantially comprised of gallium. The gallium drips from the liquified surface and is collected below the anode within the electrochemical cell. The transported plutonium is collected on the cathode surface and is recovered.

Miller, William E.; Tomczuk, Zygmunt

1998-12-08T23:59:59.000Z

222

Amorphous Metallic Glass as New High Power and Energy Density Anodes For Lithium Ion Rechargeable Batteries  

E-Print Network (OSTI)

We have investigated the use of aluminum based amorphous metallic glass as the anode in lithium ion rechargeable batteries. Amorphous metallic glasses have no long-range ordered microstructure; the atoms are less closely ...

Meng, Shirley Y.

223

Investigation on Aluminum-Based Amorphous Metallic Glass as New Anode Material in Lithium Ion Batteries  

E-Print Network (OSTI)

Aluminum based amorphous metallic glass powders were produced and tested as the anode materials for the lithium ion rechargeable batteries. Ground Al??Ni₁?La₁? was found to have a ...

Meng, Shirley Y.

224

Catalytic activity of ZrO2 nanotube arrays prepared by anodization method  

Science Conference Proceedings (OSTI)

ZrO2 nanotube arrays were prepared by anodization method in aqueous electrolyte containing (NH4)2SO4 and NH4F. The morphology and structure of nanotube arrays were characterized through scanning ...

Xixin Wang; Jianling Zhao; Xiaorui Hou; Qi He; Chengchun Tang

2012-01-01T23:59:59.000Z

225

ESS 2012 Peer Review - Flow-Assisted Zinc Anode Batteries for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6&91&>09-+&@C:40(:&O7B0& %.PQRR340(+;"""GS8P(+:S:75& FLOW-ASSISTED ZINC ANODE BATTERIES FOR GRID-SCALE ELECTRICITY STORAGE Prof. Sanjoy Banerjee, banerjee@che.ccny.cuny.e...

226

Reactions of the Carbon Anode in Alternative Battery and Fuel Cell Configurations  

Science Conference Proceedings (OSTI)

A model is formulated by combining carbonate dissociation with pre-existing anode mechanisms involving heterogeneous reaction kinetics. The proposed model accounts for both the observed preponderance of CO{sub 2} evolution and dependence of rate on carbon anode microstructure. Implications of the model for the design of carbon batteries and fuel cells are discussed, and the laboratory cells used in earlier research are described. High coulombic efficiencies for the net reaction C + O{sub 2} = CO{sub 2} require severely limiting the thickness of paste anodes in powder-fed fuel cells while the unreacting surfaces of solid prismatic anodes must be isolated from the CO{sub 2} product atmosphere to prevent Boudouard corrosion, according to C + CO{sub 2} = 2CO.

Cooper, J F; Krueger, R

2003-10-01T23:59:59.000Z

227

Full Control of Pitch Burn during Baking: It's Impact on Anode Quality ...  

Science Conference Proceedings (OSTI)

... costs, negatively impact on operational safety and a higher fuel consumption. ... Historical and Future Challenges with the Vibrated Bulk Density Test Methods for ... Prebaked Anode from Coal Extract (2) - Effects of the Properties of...

228

Stability of Iridium Anode in Molten Oxide Electrolysis for Ironmaking: Influence of Slag Basicity  

E-Print Network (OSTI)

Molten oxide electrolysis (MOE) is a carbon-neutral, electrochemical technique to decompose metal oxide directly into liquid metal and oxygen gas upon use of an inert anode. What sets MOE apart from other technologies is ...

Kim, Hojong

229

Design and construction of rigs for studying surface condensation and creating anodized metal oxide surfaces  

E-Print Network (OSTI)

This thesis details the design and construction of a rig for studying surface condensation and a rig for creating anodized metal oxides (AMOs). The condensation rig characterizes condensation for different surfaces; this ...

Sun, Wei-Yang

2011-01-01T23:59:59.000Z

230

Geek-Up[08.20.10] -- Turning Trash Bags into Battery Anodes and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Other Agencies You are here Home Geek-Up08.20.10 -- Turning Trash Bags into Battery Anodes and Researching the Gut Microbiome Geek-Up08.20.10 -- Turning Trash Bags...

231

Molten Salt Multi-anode Reactive Alloy Coating(MARC) of Ta-W ...  

Science Conference Proceedings (OSTI)

In this study, Ta-W coated samples (Ta-7.31W, Ta-4.12W and Ta-1.92W) were prepared by multi-anode reactive alloy coating (MARC) process in molten salt...

232

Surface-Modified Copper Current Collector for Lithium Ion Battery Anode  

A team of Berkeley Lab researchers led by Gao Liu has developed an innovative approach to improve the adhesion of anode laminate to copper current collectors in lithium ion batteries. This nanotechnology directly addresses delamination of graphite ...

233

Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals  

DOE Patents (OSTI)

An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and ZnO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and ZnO: 0.2 to 0.99 NiO; 0.0001 to 0.8 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.3 ZnO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

Ray, Siba P. (Murrysville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

2002-01-01T23:59:59.000Z

234

Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals  

DOE Patents (OSTI)

An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and CoO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and CoO: 0.15 to 0.99 NiO; 0.0001 to 0.85 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.45 CoO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

2002-01-01T23:59:59.000Z

235

For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals  

DOE Patents (OSTI)

A cermet inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode comprises a ceramic phase including an oxide of Ni, Fe and M, where M is at least one metal selected from Zn, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mo, Hf and rare earths, preferably Zn and/or Co. Preferred ceramic compositions comprise Fe.sub.2 O.sub.3, NiO and ZnO or CoO. The cermet inert anode also comprises a metal phase such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. A preferred metal phase comprises Cu and Ag. The cermet inert anodes may be used in electrolytic reduction cells for the production of commercial purity aluminum as well as other metals.

Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Douglas A. (Murrysville, PA)

2002-01-01T23:59:59.000Z

236

Modeling of the anode side of a direct methanol fuel cell with analytical solutions  

E-Print Network (OSTI)

In this work, analytical solutions were derived (for any methanol oxidation reaction order) for the profiles of methanol concentration and proton current density by assuming diffusion mass transport mechanism, Tafel kinetics, and fast proton transport in the anodic catalyst layer of a direct methanol fuel cell. An expression for the Thiele modulus that allows to express the anodic overpotential as a function of the cell current, and kinetic and mass transfer parameters was obtained. For high cell current densities, it was found that the Thiele modulus ($\\phi^2$) varies quadratically with cell current density; yielding a simple correlation between anodic overpotential and cell current density. Analytical solutions were derived for the profiles of both local methanol concentration in the catalyst layer and local anodic current density in the catalyst layer. Under the assumptions of the model presented here, in general, the local methanol concentration in the catalyst layer cannot be expressed as an explicit fun...

Mosquera, Martn A

2010-01-01T23:59:59.000Z

237

Li-Ion Batteries from LiFePO4 Cathode and Anatase/Graphene Composite Anode for Stationary Energy Storage  

SciTech Connect

Li-ion batteries based on LiFePO4 cathode and anatase TiO2/graphene anode were investigated for possible stationary energy storage application. Fine-structured LiFePO4 was synthesized by novel molten surfactant approach. Anatase TiO2/graphene nanocomposite was prepared via self assembly method. The full cell that operated at flat 1.6V demonstrated negligible fade after more than 700 cycles. The LiFePO4/TiO2 combination Li-ion battery is inexpensive, environmentally benign, safe and stable. Therefore, it can be practically applied as stationary energy storage for renewable power sources.

Choi, Daiwon; Wang, Donghai; Viswanathan, Vilayanur V.; Bae, In-Tae; Wang, Wei; Nie, Zimin; Zhang, Jiguang; Graff, Gordon L.; Liu, Jun; Yang, Zhenguo; Duong, Tien Q.

2009-11-06T23:59:59.000Z

238

Designer carbons as potential anodes for lithium secondary batteries  

DOE Green Energy (OSTI)

Carbons are the material of choice for lithium secondary battery anodes. Our objective is to use designed synthesis to produce a carbon with a predictable structure. The approach is to pyrolyze aromatic hydrocarbons within a pillared clay. Results from laser desorption mass spectrometry, scanning tunneling microscopy, X-ray diffraction, and small angle neutron scattering suggest that we have prepared disordered, porous sheets of carbon, free of heteroatoms. One of the first demonstrations of template-directed carbon formation was reported by Tomita and co-workers, where polyacrylonitrile was carbonized at 700{degrees}C yielding thin films with relatively low surface areas. More recently, Schwarz has prepared composites using polyfurfuryl alcohol and pillared clays. In the study reported here, aromatic hydrocarbons and polymers which do not contain heteroatoms are being investigated. The alumina pillars in the clay should act as acid sites to promote condensation similar to the Scholl reaction. In addition, these precursors should readily undergo thermal polymerization, such as is observed in the carbonization of polycyclic aromatic hydrocarbons.

Winans, R.E.; Carrado, K.A.; Thiyagarajan, P. [and others

1995-07-01T23:59:59.000Z

239

Cathode Contact Materials for Anode-Supported Cell Development - Lawrence Berkeley National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Contact Materials for Anode- Cathode Contact Materials for Anode- Supported Cell Development- Lawrence Berkeley National Laboratory Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide

240

P-64: A Comparative Study of Metal Oxide Coated Indium-tin Oxide Anodes  

E-Print Network (OSTI)

Indium-tin oxide anodes capped with certain oxides of metals enhance while other oxides degrade the hole-injection and quantum efficiencies of organic light-emitting diodes (OLEDs). The oxides of tin, zinc, praseodymium, yttrium, gallium, terbium and titanium have been investigated. The power efficiency of an OLED with a 1nm thick praseodymium oxide cap is improved by 2.5 times over that of a conventional OLED without an oxide capped anode.

For Organic Light-Emitting; Chengfeng Qiu; Haiying Chen; Zhilang Xie; Man Wong; Hoi Sing Kwok

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Applied Optoelectronics | Open Energy Information  

Open Energy Info (EERE)

optical semiconductor devices, packaged optical components, optical subsystems, laser transmitters, and fiber optic transceivers. References Applied Optoelectronics1...

242

WEDGE-AND-STRIP ANODES FOR CENTROID-FINDING POSITION-SENSITIVE PHOTOM AND PARTICLE DETECTORS  

SciTech Connect

We discuss new anode geometries, employing position-dependent charge partitioning, which can be used with microchannel plates, planar proportional counters, and mesh dynode electron multipliers to obtain a two-dimensional position signal from each detected photon or particle. Only three or four anode electrodes and signal paths are required, yet images comprised of a number of detected events have little geometric distortion and the resolution is not limited by thermal noise inherent in resistive sheet anodes. We present an analysis of the geometrical image nonlinearity in the relationship between event centroid location and the charge partition ratios. Fabrication and testing of two wedge-and-strip anode systems are discussed. Images obtained with EUV radiation and microchannel plates that verify the predicted performance of this readout system are shown. We emphasize that the spatial resolution of the wedge-and-strip anode is in no way limited by the coarseness of the anode conductor pattern. The resolution is of the order of 0.4% of the image field size, and could be further improved by adopting low noise signal circuitry. Tradeoffs encountered in the design of practical x-ray, EUV, and charge particle image systems are discussed.

Martin, C.; Jelinsky, P.; Lampto, M.; Malina, R.F.; Anger, H.O.

1981-02-01T23:59:59.000Z

243

Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin  

Science Conference Proceedings (OSTI)

Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

2011-02-28T23:59:59.000Z

244

NFRC Procedures for Applied Films  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Films Applied Films Last update: 12/10/2013 07:29 PM NFRC now has a procedure for adding applied films to substrates in Optics5 and importing those applied film constructions into WINDOW5 to be used in a whole product calculation. The information presented below is provided to help simulators with this process. Feel free to contact us at WINDOWHelp@lbl.gov with questions or comments. NFRC Applied Film Procedure Applied Film Procedures (approved by NFRC) (PDF file) Approved Applied Film List (IGDB 33.0) (PDF file) NFRC Laminate Procedure Training Powerpoint with Examples (This Powerpoint presentation was used in the NFRC web based training sessions in December 2006 and January 2007) PowerPoint Presentation (PPT file) PowerPoint Presentation (PDF file) Help and Troubleshooting

245

Electrocatalysis of anodic and cathodic oxygen-transfer reactions  

SciTech Connect

The electrocatalysis of oxygen-transfer reactions is discussed in two parts. In Part I, the reduction of iodate (IO{sub 3}{sup {minus}}) is examined as an example of cathodic oxygen transfer. On oxide-covered Pt electrodes (PtO), a large cathodic current is observed in the presence of IO{sub 3}{sup {minus}} to coincide with the reduction of PtO. The total cathodic charge exceeds the amount required for reduction of PtO and IO{sub 3}{sup {minus}} to produce an adsorbed product. An electrocatalytic link between reduction of IO{sub 3}{sup {minus}} and reduction of PtO is indicated. In addition, on oxide-free Pt electrodes, the reduction of IO{sub 3}{sup {minus}} is determined to be sensitive to surface treatment. The electrocatalytic oxidation of CN{sup {minus}} is presented as an example of anodic oxygen transfer in Part II. The voltametric response of CN{sup {minus}} is virtually nonexistent at PbO{sub 2} electrodes. The response is significantly improved by doping PbO{sub 2} with Cu. Cyanide is also oxidized effectively at CuO-film electrodes. Copper is concluded to serve as an adsorption site for CN{sup {minus}}. It is proposed that an oxygen tunneling mechanism comparable to electron tunneling does not occur at the electrode-solution interface. The adsorption of CN{sup {minus}} is therefore considered to be a necessary prerequisite for oxygen transfer. 201 refs., 23 figs., 2 tabs.

Wels, B.R.

1990-09-21T23:59:59.000Z

246

Variation of anode grid surface morphology and its effect on operation of a triode virtual cathode oscillator  

Science Conference Proceedings (OSTI)

After repeatedly operation of a triode virtual cathode oscillator, the surface morphology of anode grid is studied by a scanning electron microscope. It is found that there are many quasi-periodic sawteeth formed on the anode grid, which are about 300-500 {mu}m in height, {approx}200 {mu}m in width, and 150-200 {mu}m in period. The formation of this sawteeth implies that there is possible Rayleigh-Taylor-like instability on the anode grid during the irradiation by high-current relativistic electron beam. These sawteeth enhance the electric field on anode grid, leading to more feasible of anode plasma generation, and more rapidly expansion of that plasma. As a result, the electron transmissivity of anode grid is decreased, the output microwave power of the virtual cathode oscillator is lowered and its operational performance is degraded.

Xu Qifu; Cai Dan; Zhang Qiang; Zhao Xuelong; Zhao Qi; Cheng Guoxin; Liu Lie [College of Optoelectronic Science and Engineering, National University of Defense Technology, Changsha 410073 (China)

2012-10-15T23:59:59.000Z

247

Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management  

Science Conference Proceedings (OSTI)

The entropy changes (?S) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

Viswanathan, Vilayanur V.; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A.; Williford, Ralph E.; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

2010-06-01T23:59:59.000Z

248

Energy Production from Coal Syngas Containing H2S via Solid Oxide Fuel Cells Utilizing Lanthanum Strontium Vanadate Anodes.  

E-Print Network (OSTI)

??Lanthanum strontium vanadate (LSV), a perovskite ceramic electrocatalyst suitable for use as a solid oxide fuel cell (SOFC) anode, has shown significant activity toward the (more)

Cooper, Matthew E.

2008-01-01T23:59:59.000Z

249

Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells  

SciTech Connect

During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

2001-11-05T23:59:59.000Z

250

Determination of the cathode and anode voltage drops in high power low-pressure amalgam lamps  

Science Conference Proceedings (OSTI)

For the first time, cathode and anode drops of powerful low-pressure amalgam lamps were measured. The lamp discharge current is 3.2 A, discharge current frequency is 43 kHz, linear electric power is 2.4 W/cm. The method of determination of a cathode drop is based on the change of a lamp operating voltage at variation of the electrode filament current at constant discharge current. The total (cathode plus anode) drop of voltage was measured by other, independent ways. The maximum cathode fall is 10.8 V; the anode fall corresponding to the maximal cathode fall is 2.4 V. It is shown that in powerful low pressure amalgam lamps the anode fall makes a considerable contribution (in certain cases, the basic one) to heating of electrodes. Therefore, the anode fall cannot be neglected, at design an electrode and ballast of amalgam lamps with operating discharge current frequency of tens of kHz.

Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation); Vasiliev, A. I., E-mail: vasiliev@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V.; Startsev, A. Yu. [Joint Stock Company NPO LIT (Russian Federation); Kudryavtsev, N. N. [Moscow Institute of Physics and Technology (State University) (Russian Federation)

2011-12-15T23:59:59.000Z

251

Geek-Up[08.20.10] -- Turning Trash Bags into Battery Anodes and Researching  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8.20.10] -- Turning Trash Bags into Battery Anodes and 8.20.10] -- Turning Trash Bags into Battery Anodes and Researching the Gut Microbiome Geek-Up[08.20.10] -- Turning Trash Bags into Battery Anodes and Researching the Gut Microbiome August 20, 2010 - 5:18pm Addthis Elizabeth Meckes Elizabeth Meckes Director of User Experience & Digital Technologies, Office of Public Affairs What are the key facts? An Argonne Scholar has figured out a way to convert grocery bags into carbon nanotubes that can be used as components for lithium-ion batteries. We have about three pounds of bacteria living in our gut -- most of which is helpful for our immune system development and metabolism. Scientists at Ames Laboratory are making batteries that are "greener" and more cost-efficient by using rare earth elements -- neodymium

252

Method for providing uranium articles with a corrosion resistant anodized coating  

SciTech Connect

Uranium articles are provided with anodized oxide coatings in an aqueous solution of an electrolyte selected from the group consisting of potassium phosphate, potassium hydroxide, ammonium hydroxide, and a mixture of potassium tetraborate and boric acid. The uranium articles are anodized at a temperature greater than about 75.degree. C. with a current flow of less than about 0.036 A/cm.sup.2 of surface area while the pH of the solution is maintained in a range of about 2 to 11.5. The pH values of the aqueous solution and the low current density utilized during the electrolysis prevent excessive dissolution of the uranium and porosity in the film or watering. The relatively high temperature of the electrolyte bath inhibits hydration and the attendant deleterious pitting so as to enhance corrosion resistance of the anodized coating.

Waldrop, Forrest B. (Powell, TN); Washington, Charles A. (Oak Ridge, TN)

1982-01-01T23:59:59.000Z

253

Effect of operating parameters and anode gas impurities upon polymer electrolyte fuel cells  

DOE Green Energy (OSTI)

PEM fuel cells are actively under development for transportation and other applications. Integration of a PEM fuel cell stack with a methanol reformer requires an understanding of single cell performance under a range of operating conditions using anode gas contaminated with impurities. The effect of temperature, pressure, and anode gas impurities on single cell PEM performance was investigated with platinum black electrodes. Single cell performance remained unchanged as temperature was varied between 80 and 100 at 3 atm pressure. High water partial pressures at 120C produced a mass transfer limiting current. While operation at 120C did not reverse CO{sub 2} poisoning, anode air addition proved effective. Air injection also decreased CO poisoning at injected concentrations up to 200 ppm CO. Higher single cell tolerance was observed for CH{sub 3}OH than CO. Up to 1 mole % CH{sub 3}OH in the gas phase reduced the current density by less than 10%.

Weisbrod, K.R.; Vanderborgh, N.E.

1994-07-01T23:59:59.000Z

254

Concentrated ion beam emitted from an enlarged cylindrical-anode-layer Hall plasma accelerator and mechanism  

SciTech Connect

An enlarged cylindrical-anode-layer Hall plasma accelerator with an outlet diameter of 150 mm is experimentally demonstrated to produce a concentrated ion beam, especially at a high discharge voltage, with a high current utilization efficiency of up to {approx}0.9. Numerical investigation based on the three-dimensional particle-in-cell method is performed to study the ion dynamics and elucidate the origin of the ion beam characteristics. The simulation results reveal that the equipotential lines play an important role in the surface near the anode emitting the ions. The ion emitting surface is determined by the magnetic field lines near the anode and the magnetic mirror contributes to the concentrated beam significantly. The high current utilization efficiency results from the appropriate obliquity of the magnetic mirror.

Geng, S. F.; Wang, C. X. [Southwestern Institute of Physics, Chengdu 610041 (China); Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong); Tang, D. L.; Qiu, X. M. [Southwestern Institute of Physics, Chengdu 610041 (China); Chu, Paul K. [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong)

2013-01-28T23:59:59.000Z

255

Breathing oscillations in enlarged cylindrical-anode-layer Hall plasma accelerator  

SciTech Connect

Breathing oscillations in the discharge of an enlarged cylindrical-anode-layer Hall plasma accelerator are investigated by three-dimensional particle-in-cell (PIC) simulation. Different from the traditional breathing mode in a circular Hall plasma accelerator, the bulk plasma oscillation here is trigged by the potential barrier generated by the concentrated ion beam and substantial enough to compete with the anode voltage. The electric field near the anode is suppressed by the potential barrier thereby decreasing the electron density by {approx}36%. The discharge is restored to the normal level after the concentrated beam explodes and then it completes one cycle of electro-driven breathing oscillation. The breathing mode identified by the PIC simulation has a frequency range of {approx}156 kHz-{approx}250 kHz and does not vary monotonically with the discharge voltage.

Geng, S. F.; Wang, C. X. [Southwestern Institute of Physics, Chengdu 610041 (China) [Southwestern Institute of Physics, Chengdu 610041 (China); Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Tang, D. L.; Qiu, X. M. [Southwestern Institute of Physics, Chengdu 610041 (China)] [Southwestern Institute of Physics, Chengdu 610041 (China); Fu, R. K. Y. [Plasma Technology Limited, Festival Walk Tower, Tat Chee Avenue, Kowloon, Hong Kong (China)] [Plasma Technology Limited, Festival Walk Tower, Tat Chee Avenue, Kowloon, Hong Kong (China); Chu, Paul K. [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)] [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)

2013-05-28T23:59:59.000Z

256

Formation of Si-based nano-island array on porous anodic alumina  

SciTech Connect

Si-based nano-island arrays were fabricated on porous anodic alumina by two methods. In the first method, a thick silicon film was first deposited onto the surface with highly ordered bowl array prepared by anodizing an Al foil, followed by the formation of a polycrystalline silicon nano-island array on the surface close to the bowl array after dissolving aluminum. In the second method, porous anodization was performed on an Al thin film on Si and a SiO{sub 2} nano-island array was subsequently formed electrochemically. Time-resolved atomic force microscopy and photoluminescence were used to investigate the growth process as well as the mechanism of the growth process. Our proposed mechanism as well as assumptions made to formulate the model were found to be in agreement with the experimental results.

Mei, Y.F. [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong (China)]. E-mail: yf.mei@plink.cityu.edu.hk; Huang, G.S. [National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093 (China); Li, Z.M. [Department of Physics, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong (China); Siu, G.G. [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong (China); Fu, Ricky K.Y. [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong (China); Yang, Y.M. [National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093 (China); Wu, X.L. [National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093 (China); Tang, Z.K. [Department of Physics, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong (China); Chu, Paul K. [Department of Physics and Materials Science, City University of Hong Kong, Kowloon, Hong Kong (China)

2004-11-08T23:59:59.000Z

257

Performance of Lithium Ion Cell Anode Graphites Under Various Cycling Conditions  

Science Conference Proceedings (OSTI)

Graphites MCMB-2810 and OMAC-15 (made by Osaka Gas Inc.), and SNG12 (Hydro Quebec, Inc.) were evaluated (in coin cells with lithium counter electrodes) as anode materials for lithium-ion cells intended for use in hybrid electric vehicles. Though the reversible capacity obtained for SNG was slightly higher than that of OMAC or MCMB, its 1st cycle efficiency was lower. Voltage vs capacity plots of cycling data show that the discharge and charge limits shift to higher capacity values due to continuation of anode side reactions. Varying the cycle charge and discharge limits was found to have no significant effect on fractional capacity shift per cycle.

Ridgway, Paul; Zheng, Honghe; Liu, Gao; Song, Xiangun; Guerfi, Abdelbast; Charest, Patrick; Zaghib, Karim; Battaglia, Vincent

2009-06-15T23:59:59.000Z

258

Fabrication of copper-based anodes via atmosphoric plasma spraying techniques  

SciTech Connect

A fuel electrode anode (18) for a solid oxide fuel cell is made by presenting a solid oxide fuel cell having an electrolyte surface (15), mixing copper powder with solid oxide electrolyte in a mixing step (24, 44) to provide a spray feedstock (30,50) which is fed into a plasma jet (32, 52) of a plasma torch to melt the spray feed stock and propel it onto an electrolyte surface (34, 54) where the spray feed stock flattens into lamellae layer upon solidification, where the layer (38, 59) is an anode coating with greater than 35 vol. % based on solids volume.

Lu, Chun (Monroeville, PA)

2012-04-24T23:59:59.000Z

259

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

DOE Green Energy (OSTI)

A study of the anodic oxidation of vinyl ethylene carbonate (VEC) was conducted with post-mortem analysis of reaction products by ATR-FTIR and gel permeation chromatography (GPC). The half-wave potential (E1/2) for oxidation of VEC is ca. 3.6 V producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by anodization of a commercial Li-ion battery electrolyte containing 2 percent VEC at 4.1 V showed the presence of a high molecular weight polymer. IR analysis indicated polycarbonate with alkyl carbonate rings linked by aliphatic methylene and methyl branches.

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-02-28T23:59:59.000Z

260

Sulfur tolerant anode materials. Quarterly report, January 1--March 31, 1988  

DOE Green Energy (OSTI)

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Dense Membranes for Anode Supported all Perovskite IT-SOFCs  

DOE Green Energy (OSTI)

Innovative wet chemical synthetic techniques were employed to obtain highly ionic conducting dense perovskites, mixed conducting porous perovskites, and electronically conducting perovskite membranes to be as electrolyte, cathode, anode, and interconnect for assembling all perovskite IT-SOFC system. Processing conditions were optimized to obtain well sintered LSM, LSF, LSCF, LNF, and LCF for SOFC cell and stacks working at 600-800 C. Series of nanocrystalline bulk and thin films of La{sub 0.8}Sr{sub 0.2}Ga{sub 0.83}Mg{sub 0.17}O{sub 2.815}, LaSr{sub 0.2}Fe{sub 0.8}O{sub 3}, LaSr{sub 0.2}Co{sub 0.8}Fe{sub 0.2}O{sub 3}, La{sub 0.8}Ni{sub 0.7}Fe{sub 0.3}O{sub 3}, LaCr{sub 0.7}Fe{sub 0.3}O{sub 3} were prepared at very low temperatures and characterized using XRD, SEM, HRTEM, XPS, EXAFS, and EIS techniques. The influence of preparation techniques on the microstructure, grain-size and consequently on the electrical transport properties were investigated. Processing conditions, sintering temperature (1200-1500 C) and time severely affected the grain size (< 0.1 {micro}m to 10 {micro}m) and the resistance in all grain-boundary (3 k{Omega} to175 k{Omega}). Through investigations of A and B site doping in perovskite materials, we have reduced cathode-electrolyte interfacial resistance, will be very effective for the SOFCs operating {approx} 750 C. Epitaxial films of LiFeNiO{sub 3}, for SOFCs cathode were deposited on LaAl{sub 2}O{sub 3}, MgO, and YSZ single crystals by pulsed laser deposition (PLD) method, and characterized using advanced spectroelectrochemical techniques. The film orientations depend on the substrate planes. Surface morphology of the films also depends on the substrate orientations. These films showed different electrode properties depending on the orientations. The porous characteristic of the electrode materials are achieved by the combination of combustion and microwave sintering using SiC as susceptor (1200-1400 C). Concurrently, the other oxygen ionic/protonic conducting oxides (perovskites, pyrochlores, and apatites) were also prepared, characterized and understood the role in the development of reduced temperature SOFCs. In this HBCU/MI -research and educational project, we have emphasized the need to expand research opportunities for talented undergraduate and graduate African American students and junior faculty in the field of power sources based on nanoscience. We have paired the selected three undergraduate and two graduate students with full time research staff (PDF), for experimental measurements and discussions via preparing students to present the work in regional, national and international conferences. These students on an average made one presentation per year out side the SUBR campus. The effort in this project yielded 7 publications in refereed journals and about 15 in conference proceedings including NETL annual review meetings. Further, we have initiated a collaborative research and educational outreach project entitled 'Center for Hydrogen Energy and Advanced Power [CHEAP]' with University of West Indies-St. Augustine, Trinidad & Tobago (T &T).

Rambabu Bobba

2007-09-15T23:59:59.000Z

262

Parasitic corrosion resistant anode for use in metal/air or metal/O.sub.2 cells  

SciTech Connect

A consumable metal anode which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

Joy, Richard W. (Santa Clara, CA); Smith, David F. (Boulder Creek, CA)

1983-01-01T23:59:59.000Z

263

Parasitic corrosion-resistant anode for use in metal/air or metal/O/sub 2/ cells  

DOE Patents (OSTI)

A consumable metal anode is described which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

Joy, R.W.; Smith, D.F.

1982-09-20T23:59:59.000Z

264

Aluminum bulk micromachining through an anodic oxide mask by electrochemical etching in an acetic acid/perchloric acid solution  

Science Conference Proceedings (OSTI)

A well-defined microstructure with microchannels and a microchamber was fabricated on an aluminum plate by four steps of a new aluminum bulk micromachining process: anodizing, laser irradiation, electrochemical etching, and ultrasonication. An aluminum ... Keywords: Aluminum, Anodizing, Bulk micromachining, Electrochemical etching, Laser irradiation

Tatsuya Kikuchi, Yuhta Wachi, Masatoshi Sakairi, Ryosuke O. Suzuki

2013-11-01T23:59:59.000Z

265

BNL | Accelerators for Applied Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Accelerators for Applied Research Accelerators for Applied Research Brookhaven National Lab operates several accelerator facilities dedicated to applied research. These facilities directly address questions and concerns on a tremendous range of fields, including medical imaging, cancer therapy, computation, and space exploration. Leading scientists lend their expertise to these accelerators and offer crucial assistant to collaborating researchers, pushing the limits of science and technology. Interested in gaining access to these facilities for research? See the contact number listed for each facility. RHIC tunnel Brookhaven Linac Isotope Producer The Brookhaven Linac Isoptope Producer (BLIP)-positioned at the forefront of research into radioisotopes used in cancer treatment and diagnosis-produces commercially unavailable radioisotopes for use by the

266

CRC handbook of applied thermodynamics  

Science Conference Proceedings (OSTI)

The emphasis of this book is on applied thermodynamics, featuring the stage of development of a process rather than the logical development of thermodynamic principles. It is organized according to the types of problems encountered in industry, such as probing research, process assessment, and process development. The applied principles presented can be used in most areas of industry including oil and gas production and processing, chemical processing, power generation, polymer production, food processing, synthetic fuels production, specialty chemicals and pharmaceuticals production, bioengineered processes, etc.

Palmer, D.A. (Amoco Chemical Corp., Naperville, IL (USA). Research and Development Dept.)

1987-01-01T23:59:59.000Z

267

Silicon-tin oxynitride glassy composition and use as anode for lithium-ion battery  

DOE Patents (OSTI)

Disclosed are silicon-tin oxynitride glassy compositions which are especially useful in the construction of anode material for thin-film electrochemical devices including rechargeable lithium-ion batteries, electrochromic mirrors, electrochromic windows, and actuators. Additional applications of silicon-tin oxynitride glassy compositions include optical fibers and optical waveguides.

Neudecker, Bernd J. (Knoxville, TN); Bates, John B. (Oak Ridge, TN)

2001-01-01T23:59:59.000Z

268

Phase transformations and microstructural design of lithiated metal anodes for lithium-ion rechargeable batteries  

E-Print Network (OSTI)

There has been great recent interest in lithium storage at the anode of Li-ion rechargeable battery by alloying with metals such as Al, Sn, and Sb, or metalloids such as Si, as an alternative to the intercalation of graphite. ...

Limthongkul, Pimpa, 1975-

2002-01-01T23:59:59.000Z

269

Nano-structured anode material for high-power battery system in electric vehicles.  

SciTech Connect

A new MSNP-LTO anode is developed to enable a high-power battery system that provides three times more power than any existing battery system. It shows excellent cycle life and low-temperature performance, and exhibits unmatched safety characteristics.

Amine, K.; Belharouak, I.; Chen, Z.; Taison, T.; Yumoto, H.; Ota, N.; Myung, S.-T.; Sun, Y.-K. (Chemical Sciences and Engineering Division); (Enerdel Lithium Power Systems); (Iwate Univ.); (Hanyang Univ.)

2010-07-27T23:59:59.000Z

270

A Comparison of Molten Sn and Bi for Solid Oxide Fuel Cell Anodes  

Science Conference Proceedings (OSTI)

Molten Sn and Bi were examined at 973 and 1073 K for use as anodes in solid oxide fuel cells with yttria-stabilized zirconia (YSZ) electrolytes. Cells were operated under battery conditions, with dry He flow in the anode compartment, to characterize the electrochemical oxidation of the metals at the YSZ interface. For both metals, the open-circuit voltages (OCVs) were close to that expected based on their oxidation thermodynamics, ~0.93 V for Sn and ~0.48 V for Bi. With Sn, the cell performance degraded rapidly after the transfer of approximately 0.5-1.5 Ccm{sup 2} of charge due to the formation of a SnO{sub 2} layer at the YSZ interface. At 973 K, the anode impedance at OCV for freshly reduced Sn was approximately 3 {ohm}cm{sup 2} but this increased to well over 250 {ohm}cm{sup 2} after the transfer of of charge. Following the transfer of 8.2 Ccm{sup 2} at 1073 K, the formation of a 10{micro}m thick SnO{sub 2} layer was confirmed by scanning electron microscopy. With Bi, the OCV anode impedance at 973 K was less than 0.25 {ohm}cm{sup 2} and remained constant until essentially all of the Bi had been oxidized to BiO{sub 2}. Some implications of these results for direct carbon fuel cells are discussed.

Jayakumar, A.; Lee, Sang Bok; Horns, A.; Vohs, J. M.; Gorte, R. J.

2010-01-01T23:59:59.000Z

271

Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries  

E-Print Network (OSTI)

,12 nanowires13-17 (NW), bundled Si nanotubes,18 and thin films19 as candidate anode materials in lithium ion morphology change. In particular, the axial void spaces of the Si NTs provide additional free surfaces physics, to account for experimental observations and to derive optimized dimen- sions in the tubes

Rogers, John A.

272

Primary cell of high energy density in which the anode active material is an alkali metal  

Science Conference Proceedings (OSTI)

A primary cell of high specific energy in which the anode active material is an alkali metal and the cathode active material is sulphur oxychloride which simultaneously acts as an electrolyte solvent, said electrolyte further containing a dissolved salt and a co-solvent. The co-solvent is chosen from among phosphoryl chloride and benzoyl chloride; the dissolved salt is lithium tetrachloroaluminate.

Gabano, J.

1983-02-01T23:59:59.000Z

273

Solution-Grown Silicon Nanowires for Lithium-Ion Battery Anodes  

E-Print Network (OSTI)

that lower- ing the price of batteries is a major goal, the cost of the processing and fabricationSolution-Grown Silicon Nanowires for Lithium-Ion Battery Anodes Candace K. Chan, Reken N. Patel interest in using nanomaterials for advanced lithium-ion battery electrodes, par- ticularly for increasing

Cui, Yi

274

Uncertainty Studies of Real Anode Surface Area in Computational Analysis for Molten Salt Electrorefining  

SciTech Connect

This study examines how much cell potential changes with five differently assumed real anode surface area cases. Determining real anode surface area is a significant issue to be resolved for precisely modeling molten salt electrorefining. Based on a three-dimensional electrorefining model, calculated cell potentials compare with an experimental cell potential variation over 80 hours of operation of the Mark-IV electrorefiner with driver fuel from the Experimental Breeder Reactor II. We succeeded to achieve a good agreement with an overall trend of the experimental data with appropriate selection of a mode for real anode surface area, but there are still local inconsistencies between theoretical calculation and experimental observation. In addition, the results were validated and compared with two-dimensional results to identify possible uncertainty factors that had to be further considered in a computational electrorefining analysis. These uncertainty factors include material properties, heterogeneous material distribution, surface roughness, and current efficiency. Zirconium's abundance and complex behavior have more impact on uncertainty towards the latter period of electrorefining at given batch of fuel. The benchmark results found that anode materials would be dissolved from both axial and radial directions at least for low burn-up metallic fuels after active liquid sodium bonding was dissolved.

Sungyeol Choi; Jaeyeong Park; Robert O. Hoover; Supathorn Phongikaroon; Michael F. Simpson; Kwang-Rag Kim; Il Soon Hwang

2011-09-01T23:59:59.000Z

275

LSCF Synthesis and Syngas Reactivity over LSCF-modified Ni/YSZ Anode.  

E-Print Network (OSTI)

??Simulated coal syngas reactivity over Ni/YSZ and LSCF (La0.6Sr0.4Co0.2Fe0.8)-modified Ni/YSZ anode of SOFC (solid oxide fuel cell) was investigated in this study. The contribution of (more)

Mirzababaei, Jelvehnaz

2011-01-01T23:59:59.000Z

276

California Energy Commission Apply Today!  

E-Print Network (OSTI)

photovoltaic project in the future. Peak Demand Savings: 95 kW Energy Savings: 1,510,849 kWh Annual Energy CostCalifornia Energy Commission Apply Today! "The College implemented all of the recommended projects Programs Office (916) 654-4147 pubprog@energy.state.ca.us "CEC financing allowed us to install many

277

implementing bioenergy applied research & development  

E-Print Network (OSTI)

1 A Northern Centre for Renewable Energy implementing bioenergy applied research & development plant measures to become carbon neutral and operate on renewable energy. UNBC is uniquely positioned for Climate Solutions, and UNBC. The Green University Centre will be a model of energy efficiency

Northern British Columbia, University of

278

Vehicle Technologies Office: Applied Battery Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Battery Research to someone by E-mail Share Vehicle Technologies Office: Applied Battery Research on Facebook Tweet about Vehicle Technologies Office: Applied Battery...

279

Dissolution of Plutonium Scrub Alloy and Anode Heel Materials in H-Canyon  

SciTech Connect

H-Canyon has a ''gap'' in dissolver operations during the last three months of FY03. One group of material to be processed during the gap is pre-existing scrub alloy material. There are 14 cans of material containing approximately 3.8 kilograms of plutonium. Of the 14 cans, it was anticipated that four cans contain salts, two cans contain anode heel materials, and eight cans contain scrub alloy buttons. H-Canyon desires to process the materials using a flowsheet similar to the SS and C (sand, slag and crucible) dissolution flowsheet used in F-Canyon. The materials will be loaded into carbon steel cans and then placed into aluminum metal charging bundles. Samples were sent to Savannah River Technology Center (SRTC) for characterization and flowsheet testing -- four MSE salts, two anode heels, and seven scrub alloy buttons. SRTC dissolved and characterized each of the samples. Two of them, originally thought to be MSE salts, were found to be graphite mold materials and were unsuitable for processing in H-Canyon. Characterization studies confirmed that the identification of the remaining items as MSE salts, scrub alloy buttons, and anode heel materials was correct. The MSE salts and anode heels solids are comprised primarily of plutonium, potassium, sodium and chloride. Both the MSE salts and anode heels left behind small amounts of residual solids. The scrub alloy buttons are comprised primarily of plutonium and aluminum. The solids dissolve readily with light, effervescent gas generation at the material surface and only trace amounts of NOx generation. Of the seven button samples, four dissolved completely. Two button samples contained small amounts of tantalum that did not dissolve. The last of the seven scrub alloy samples left a trace amount of residual plutonium solids. It is anticipated that the presence of undissolved fissile material is a function of where the sample was located relative to the button surface.

PIERCE, RA

2004-04-12T23:59:59.000Z

280

Liquid Tin Anode Direct Coal Fuel Cell Final Program Report  

DOE Green Energy (OSTI)

This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

Tao, Thomas

2012-01-26T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Trace metal characterization and speciation in geothermal effluent by multiple scanning anodic stripping voltammetry and atomic absorption analysis  

DOE Green Energy (OSTI)

Recent studies have shown geothermal power plants to have a significant environmental impact on the ground water of the area. The heavy metals arsenic and mercury are special problems, as both are concentrated by flora and fauna exposed to the effluent waters. Because the toxicity of these and other metallic pollutants present in geothermal effluent depends on the chemical form, or speciation, of the particular metal, any serious study of the environmental impact of a geothermal development should include studies of trace metal speciation, in addition to trace metal concentration. This proposal details a method for determining metal speciation in dilute waters. The method is based on ion-exchange and backed by atomic absorption spectrometry and multiple scanning anodic stripping voltammetry. Special laboratory studies will be performed on mercury, arsenic and selenium speciation in synthetic geothermal water. The method will be applied to three known geothermal areas in Washington and Oregon, with emphasis on the speciation of mercury, arsenic and selenium in these waters. The computer controlled electrochemical instrumentation was built and tested. Using this instrumentation, a new experimental procedure was developed to determine the chemical form (speciation) of metal ions in very dilute solutions (ng/ml). This method was tested on model systems including Pb, Cd, and As with C1/sup -/, CO/sub 3//sup 2 -/ and glycine ligands. Finally, the speciation of lead in a geothermal water was examined and the PbC1/sup +/ complex was observed and quantified.

Kowalski, B.R.

1979-05-25T23:59:59.000Z

282

Liquid Tin Anode Direct Coal Fuel Cell Final Program Report  

SciTech Connect

This SBIR program will result in improved LTA cell technology which is the fundamental building block of the Direct Coal ECL concept. As described below, ECL can make enormous efficiency and cost contributions to utility scale coal power. This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

Tao, Thomas

2012-01-26T23:59:59.000Z

283

CX-001227: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Replacement of Big Hill Deep Anode Ground Bed Site for Cavern 114CX(s) Applied: B1.3Date: 03/16/2010Location(s): Big Hill, TexasOffice(s): Fossil Energy, Strategic Petroleum Reserve Field Office

284

"Buried-Anode" Technology Leads to Advanced Lithium Batteries (Fact Sheet), The Spectrum of Clean Energy Innovation, NREL (National Renewable Energy Laboratory)  

NLE Websites -- All DOE Office Websites (Extended Search)

It all began in 2001, when three NREL researchers took their thin-film It all began in 2001, when three NREL researchers took their thin-film expertise from window technology research and applied it to a solid-state, thin-film lithium battery. The researchers knew that lithium batteries tended to degrade quickly because the fragile lithium metal anode was on the top of the battery, where any cracks in the encapsulant could lead to rapid failure. The team developed the concept of building the battery in reverse order, depositing first the solid-state electrolyte, made of lithium phosphorous oxynitride (LiPON), then the cathode, a metal oxide. Lithium is typically intercalated (chemically trapped) within the cathode material. Placing an initial charge on the battery causes the lithium ions to migrate out of the cathode

285

Microsoft Word - Poster Abstract_2010_NETL_ liquid metal anode.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

coal solid oxide fuel cells with liquid tin anodes coal solid oxide fuel cells with liquid tin anodes U.S. Dept of Energy, National Energy Technology Laboratory, Morgantown, WV 26507 Harry Abernathy, Kirk Gerdes, Randy Gemmen Phone: (304)285-4342, Kirk.Gerdes@NETL.DOE.GOV Fuel cells are one of the most efficient methods for converting the chemical energy in coal directly to electrical energy, minimizing the amount of carbon dioxide and other pollutants produced per kilowatt of electricity even before scrubbing and carbon sequestration. To use coal as a fuel source, even the most tolerant solid ceramic fuel cell systems require prior gasification of the coal into syngas, which significantly adds to total system cost. By replacing the ceramic fuel electrode of a traditional high temperature solid oxide fuel cell (SOFC) with a liquid metal

286

LOW-TEMPERATURE, ANODE-SUPPORTED HIGH POWER DENSITY SOLID OXIDE FUEL CELLS WITH NANOSTRUCTURED ELECTRODES  

DOE Green Energy (OSTI)

This report summarizes the work done during the entire project period, between October 1, 1999 and March 31, 2003, which includes a six-month no-cost extension. During the project, eight research papers have, either been, published, accepted for publication, or submitted for publication. In addition, several presentations have been made in technical meetings and workshops. The project also has provided support for four graduate students working towards advanced degrees. The principal technical objective of the project was to analyze the role of electrode microstructure on solid oxide fuel cell performance. Prior theoretical work conducted in our laboratory demonstrated that the particle size of composite electrodes has a profound effect on cell performance; the finer the particle size, the lower the activation polarization, the better the performance. The composite cathodes examined consisted of electronically conducting perovskites such as Sr-doped LaMnO{sub 3} (LSM) or Sr-doped LaCoO{sub 3} (LSC), which is also a mixed conductor, as the electrocatalyst, and yttria-stabilized zirconia (YSZ) or rare earth oxide doped CeO{sub 2} as the ionic conductor. The composite anodes examined were mixtures of Ni and YSZ. A procedure was developed for the synthesis of nanosize YSZ by molecular decomposition, in which unwanted species were removed by leaching, leaving behind nanosize YSZ. Anode-supported cells were made using the as-synthesized powders, or using commercially acquired powders. The electrolyte was usually a thin ({approx}10 microns), dense layer of YSZ, supported on a thick ({approx}1 mm), porous Ni + YSZ anode. The cathode was a porous mixture of electrocatalyst and an ionic conductor. Most of the cell testing was done at 800 C with hydrogen as fuel and air as the oxidant. Maximum power densities as high as 1.8 W/cm{sup 2} were demonstrated. Polarization behavior of the cells was theoretically analyzed. A limited amount of cell testing was done using liquid hydrocarbon fuels where reforming was achieved internally. Significant polarization losses also occur at the anode, especially at high fuel utilizations. An analysis of polarization losses requires that various contributions are isolated, and their dependence on pertinent parameters is quantitatively described. An investigation of fuel composition on gas transport through porous anodes was investigated and the role of fuel diluents was explored. This work showed that the molecular weight of the diluent has a significant effect on anode concentration polarization. This further showed that the presence of some molecular hydrogen is necessary to minimize polarization losses. Theoretical analysis has shown that the electrode microstructure has a profound effect on cell performance. In a series of experiments, cathode microstructural parameters were varied, without altering other parameters. Cathode microstructural parameters, especially three phase boundary (TPB) length, were estimated using techniques in quantitative stereology. Cell performance was quantitatively correlated with the relevant microstructural parameters, and charge transfer resistivity was explicitly evaluated. This is the first time that a fundamental parameter, which governs the activation polarization, has been quantitatively determined. An important parameter, which governs the cathodic activation polarization, and thus cell performance, is the ionic conductivity of the composite cathode. The traditional composite cathode is a mixture of LSM and YSZ. It is well known that Sr and Mg-doped LaGaO{sub 3} (LSGM), exhibits higher oxygen ion conductivity compared to YSZ. Cells were fabricated with composite cathodes comprising a mixture of LSM and LSGM. Studies demonstrated that LSGM-based composite cathodes exhibit excellent behavior. Studies have shown that Ni + YSZ is an excellent anode. In fact, in most cells, the principal polarization losses, at least at low fuel utilizations, are associated with the cathode. Theoretical analysis conducted in our group has also shown that anode-supported cells exhibi

Professor Anil V. Virkar

2003-05-23T23:59:59.000Z

287

NANOSTRUCTURED METAL OXIDES FOR ANODES OF LI-ION RECHARGEABLE BATTERIES  

DOE Green Energy (OSTI)

The aligned nanorods of Co{sub 3}O{sub 4} and nanoporous hollow spheres (NHS) of SnO{sub 2} and Mn{sub 2}O{sub 3} were investigated as the anodes for Li-ion rechargeable batteries. The Co{sub 3}O{sub 4} nanorods demonstrated 1433 mAh/g reversible capacity. The NHS of SnO{sub 2} and Mn{sub 2}O{sub 3} delivered 400 mAh/g and 250 mAh/g capacities respectively in multiple galvonastatic discharge-charge cycles. It was found that high capacity of NHS of metal oxides is sustainable attributed to their unique structure that maintains material integrity during cycling. The nanostructured metal oxides exhibit great potential as the new anode materials for Li-ion rechargeable batteries with high energy density, low cost and inherent safety.

Au, M.

2009-12-04T23:59:59.000Z

288

Cu2Sb thin films as anode for Na-ion batteries  

SciTech Connect

Cu2Sb thin films prepared by magnetron sputtering are evaluated as an anode material for Na-ion batteries. The starting material is composed of nanocrystallites with the desired tetragonal P4/nmm structure. The study of the reaction mechanism reveals the formation of an amorphous/nanocrystalline phase of composition close to Na3Sb as the final reaction product. The solid electrolyte interphase (SEI) material is mostly composed of carbonates (Na2CO3, NaCO3R). The Cu2Sb anode possesses moderate capacity retention with a reversible storage capacity (250 mAh/g) close to the theoretical value (323 mAh/g), an average reaction potential of around 0.55 V vs. Na/Na+, and a high rate performance (10 C-rate).

Baggetto, Loic [ORNL; Allcorn, Eric [University of Texas, Austin; Manthiram, Arumugam [University of Texas, Austin; Veith, Gabriel M [ORNL

2013-01-01T23:59:59.000Z

289

Li4Ti5O12 as an anode material for Li ion batteries in situ XRD and XPS studies.  

E-Print Network (OSTI)

?? This thesis examines parts of the kinetics and performance in Li-battery cells using lithium titanate anodes and lithium manganese oxide cathodes. Lithium titanate (Li4Ti5O12) (more)

Nordh, Tim

2013-01-01T23:59:59.000Z

290

Copper-tin anodes for rechargeable lithium batteries : an example of the matrix effect in an intermetallic system.  

DOE Green Energy (OSTI)

Lithium batteries are typically constructed from a lithium cobalt oxide cathode and a carbon anode. We have investigated intermetallic anode materials based on tin, which can provide a high capacity at a slightly higher voltage (400 mV) than metallic lithium and thus reduce the safety concerns associated with the carbon anode. In particular, we have investigated the copper-tin system at around the composition Cu{sub 6}Sn{sub 5} and have determined the effect on cycling and capacity of electrodes with various ratios of copper to tin. Anode compositions that are slightly copper rich (Cu{sub 6}Sn{sub 4}) were found to exhibit greater utilization of the tin than those with the stoichiometric bronze ratio (Cu{sub 6}Sn{sub 5}) or those having a slight excess of tin (Cu{sub 6}Sn{sub 6}). The differences in electrochemical behavior are explained in terms of an inert matrix model.

Kepler, K. D.

1998-09-02T23:59:59.000Z

291

Ni coarsening in the three-phase solid oxide fuel cell anode - a phase-field simulation study  

E-Print Network (OSTI)

Ni coarsening in Ni-yttria stabilized zirconia (YSZ) solid oxide fuel cell anodes is considered a major reason for anode degradation. We present a predictive, quantative modeling framework based on the phase-field approach to systematically examine coarsening kinetics in such anodes. The initial structures for simulations are experimentally acquired functional layers of anodes. Sample size effects and error analysis of contact angles are examined. Three phase boundary (TPB) lengths and Ni surface areas are quantatively identified on the basis of the active, dead-end, and isolated phase clusters throughout coarsening. Tortuosity evolution of the pores is also investigated. We find that phase clusters with larger characteristic length evolve slower than those with smaller length scales. As a result, coarsening has small positive effects on transport, and impacts less on the active Ni surface area than the total counter part. TPBs, however, are found to be sensitive to local morphological features and are only i...

Chen, Hsun-Yi; Cronin, J Scott; Wilson, James R; Barnett, Scott A; Thornton, Katsuyo

2012-01-01T23:59:59.000Z

292

THREE ESSAYS ON APPLIED ECONOMICS  

E-Print Network (OSTI)

In this dissertation three essays were presented. In the first two essays we measure the consumer welfare changes caused by U.S. meat price changes. In the third essay the dynamic structure of international gasoline prices using the time series methodology is investigated. In chapter II, we investigate the U.S. consumer behavior on meat consumption depending on a linear expenditure system (LES), and then we simulate the welfare effects of a set of price changes on the U.S. meat consumption. The simulation results show that the amount of consumer welfare change for each meat is not same across the meats under the same percentage change of price. The simulation results also show that when all the prices are doubled the total amount of CV reaches almost the same amount of current total quarterly expenditures for the three meats. In chapter III, we apply the compensating variation (CV) approach for the measurement of consumer welfare losses associated with beef price changes. We applied the long-run cointegrating relationship in vector error correction model (VECM) to estimate the Marshallian demand function. Apparently, the use of long-run cointegration in VECM in deriving the direct Marshallian demand function to measure the consumer welfare change is the first attempt in the literature. This is one of the contributions of the study. The simulation results show that the amount of consumer welfare change for beef is compatible with the one derived from LES methodology. In chapter IV, an empirical framework to summarize the interdependence of four international gasoline markets (New York, U.S. Gulf Coast, Rotterdam and Singapore) is presented. For that purpose, we employ a structural VECM and directed acyclic graphs (DAGs). To solve the identification problem in structural VECM, we apply DAGs derived from contemporaneous VECM innovations. The impulse response functions show that the time period in which a shock in a market affects the other market is very short. Forecast error variance decompositions (FEVD) shows that in all markets, except the U.S. Gulf Coast market, current and past shocks in their own market explained the most of the volatility in their own market in the Short-run.

Shin, Sang-Cheol

2008-08-01T23:59:59.000Z

293

Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes  

SciTech Connect

Hollow core-shell structured porous Si-C nanocomposites with void space up to tens of nanometers are designed to accommodate the volume expansion during lithiation for high-performance Li-ion battery anodes. An initial capacity of {approx}760 mAh/g after formation cycles (based on the entire electrode weight) with {approx}86% capacity retention over 100 cycles is achieved at a current density of 1 A/g. Good rate performance is also demonstrated.

Li, Xiaolin; Meduri, Praveen; Chen, Xilin; Qi, Wen N.; Engelhard, Mark H.; Xu, Wu; Ding, Fei; Xiao, Jie; Wang, Wei; Wang, Chong M.; Zhang, Jiguang; Liu, Jun

2012-06-14T23:59:59.000Z

294

Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries  

DOE Green Energy (OSTI)

During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

White, Ralph E.; Popov, Branko N.

2002-10-31T23:59:59.000Z

295

Carbon-coated silicon nanowire array films for high-performance lithium-ion battery anodes  

Science Conference Proceedings (OSTI)

Carbon-coated silicon nanowire array films prepared by metal catalytic etching of silicon wafers and pyrolyzing of carbon aerogel were used for lithium-ion battery anodes. The films exhibited an excellent first discharge capacity of 3344 ? mAh ? g ? 1 with a Coulombic efficiency of 84% at a rate of 150 ? mA ? g ? 1 between 2 and 0.02 V and a significantly enhanced cycling performance

Rui Huang; Xing Fan; Wanci Shen; Jing Zhu

2009-01-01T23:59:59.000Z

296

Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes  

SciTech Connect

Nanostructured ion beam-modified Ge electrodes fabricated directly on Ni current collector substrates were found to exhibit excellent specific capacities during electrochemical cycling in half-cell configuration with Li metal for a wide range of cycling rates. Structural characterization revealed that the nanostructured electrodes lose porosity during cycling but maintain excellent electrical contact with the metallic current collector substrate. These results suggest that nanostructured Ge electrodes have great promise for use as high performance Li ion battery anodes.

Rudawski, N. G.; Darby, B. L.; Yates, B. R.; Jones, K. S. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611-6400 (United States); Elliman, R. G. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, Australian Capital Territory 0200 (Australia); Volinsky, A. A. [Department of Mechanical Engineering, University of South Florida, Tampa Florida 33620 (United States)

2012-02-20T23:59:59.000Z

297

LOW-TEMPERATURE, ANODE-SUPPORTED HIGH POWER DENSITY SOLID OXIDE FUEL CELLS WITH NANOSTRUCTURED ELECTRODES  

DOE Green Energy (OSTI)

Anode-supported solid oxide fuel cells with Ni + yttria-stabilized zirconia (YSZ) anode, YSZ-samaria-doped ceria (SDC) bi-layer electrolyte and Sr-doped LaCoO{sub 3} (LSC) + SDC cathode were fabricated. Fuel used consisted of H{sub 2} diluted with He, N{sub 2}, H{sub 2}O or CO{sub 2}, mixtures of H{sub 2} and CO, and mixtures of CO and CO{sub 2}. Cell performance was measured at 800 C with above-mentioned fuel gas mixtures and air as oxidant. For a given concentration of the diluent, the cell performance was higher with He as the diluent than with N{sub 2} as the diluent. Mass transport through porous Ni-YSZ anode for H{sub 2}-H{sub 2}O, CO-CO{sub 2} binary systems and H{sub 2}-H{sub 2}O-diluent gas ternary systems was analyzed using multicomponent gas diffusion theory. At high concentrations of the diluent, the maximum achievable current density was limited by the anodic concentration polarization. From this measured limiting current density, the corresponding effective gas diffusivity was estimated. Highest effective diffusivity was estimated for fuel gas mixtures containing H{sub 2}-H{sub 2}O-He mixtures ({approx}0.34 cm{sup 2}/s), and the lowest for CO-CO{sub 2} mixtures ({approx}0.07 cm{sup 2}/s). The lowest performance was observed with CO-CO{sub 2} mixture as a fuel, which in part was attributed to the lowest effective diffusivity of the fuels tested.

Anil V. Virkar

2001-09-26T23:59:59.000Z

298

Applied Materials | Open Energy Information  

Open Energy Info (EERE)

Materials Materials Jump to: navigation, search Name Applied Materials Address 3050 Bowers Avenue Place Santa Clara, California Zip 95054 Sector Solar Stock Symbol AMAT Website http://www.appliedmaterials.co Coordinates 37.3775749°, -121.9794416° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.3775749,"lon":-121.9794416,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

299

Effect of Natural Gas Fuel Addition on the Oxidation of Fuel Cell Anode Gas  

DOE Green Energy (OSTI)

The anode exhaust gas from a fuel cell commonly has a fuel energy density between 15 and 25% that of the fuel supply, due to the incomplete oxidation of the input fuel. This exhaust gas is subsequently oxidized (catalytically or non-catalytically), and the resultant thermal energy is often used elsewhere in the fuel cell process. Alternatively, additional fuel can be added to this stream to enhance the oxidation of the stream, for improved thermal control of the power plant, or to adjust the temperature of the exhaust gas as may be required in other specialty co-generation applications. Regardless of the application, the cost of a fuel cell system can be reduced if the exhaust gas oxidation can be accomplished through direct gas phase oxidation, rather than the usual catalytic oxidation approach. Before gas phase oxidation can be relied upon however, combustor design requirements need to be understood. The work reported here examines the issue of fuel addition, primarily as related to molten-carbonate fuel cell technology. It is shown experimentally that without proper combustor design, the addition of natural gas can readily quench the anode gas oxidation. The Chemkin software routines were used to resolve the mechanisms controlling the chemical quenching. It is found that addition of natural gas to the anode exhaust increases the amount of CH3 radicals, which reduces the concentration of H and O radicals and results in decreased rates of overall fuel oxidation.

Randall S. Gemmen; Edward H. Robey, Jr.

1999-11-01T23:59:59.000Z

300

Composite solid oxide fuel cell anode based on ceria and strontium titanate  

DOE Patents (OSTI)

An anode and method of making the same wherein the anode consists of two separate phases, one consisting of a doped strontium titanate phase and one consisting of a doped cerium oxide phase. The strontium titanate phase consists of Sr.sub.1-xM.sub.xTiO.sub.3-.delta., where M is either yttrium (Y), scandium (Sc), or lanthanum (La), where "x" may vary typically from about 0.01 to about 0.5, and where .delta. is indicative of some degree of oxygen non-stoichiometry. A small quantity of cerium may also substitute for titanium in the strontium titanate lattice. The cerium oxide consists of N.sub.yCe.sub.1-yO.sub.2-.delta., where N is either niobium (Nb), vanadium (V), antimony (Sb) or tantalum (Ta) and where "y" may vary typically from about 0.001 to about 0.1 and wherein the ratio of Ti in said first phase to the sum of Ce and N in the second phase is between about 0.2 to about 0.75. Small quantities of strontium, yttrium, and/or lanthanum may additionally substitute into the cerium oxide lattice. The combination of these two phases results in better performance than either phase used separately as an anode for solid oxide fuel cell or other electrochemical device.

Marina, Olga A. (Richland, WA); Pederson, Larry R. (Richland, WA)

2008-12-23T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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301

Basic properties of a liquidt in anode solid oxide fuel cell  

Science Conference Proceedings (OSTI)

An unconventional high temperature fuel cell system, the liquidt in anode solid oxide fuel cell(LTA-SOFC), is discussed. A thermodynamic analysis of a solid oxide fuel cell with a liquid metal anode is developed. Pertinent thermo chemical and thermo physical properties of liquid tin in particular are detailed. An experimental setup for analysis of LTA-SOFC anode kinetics is described, and data for a planar cell under hydrogen indicated an effective oxygen diffusion coefficient of 5.310?5 cm2 s?1 at 800 ?C and 8.910?5 cm2 s?1 at 900 ?C. This value is similar to previously reported literature values for liquid tin. The oxygen conductivity through the tin, calculated from measured diffusion coefficients and theoretical oxygen solubility limits, is found to be on the same order of thatofyttria-stabilizedzirconia(YSZ), a traditional SOFC electrolyte material. As such,the ohmicloss due to oxygen transport through the tin layer must be considered in practical system cell design since the tin layer will usually be at least as thick as the electrolyte.

Harry Abernathy; RandallGemmen; KirkGerdes; Mark Koslowske; ThomasTao

2010-12-17T23:59:59.000Z

302

EERE Postdoctoral Research Awards: How to Apply  

NLE Websites -- All DOE Office Websites (Extended Search)

How to Apply to someone by E-mail Share EERE Postdoctoral Research Awards: How to Apply on Facebook Tweet about EERE Postdoctoral Research Awards: How to Apply on Twitter Bookmark...

303

Dense Membranes for Anode Supported all Perovskite IT-SOFCs  

DOE Green Energy (OSTI)

During this first year of the project, a post doctoral fellow (Dr. Hrudananda Jena), and two graduate students (Mr. Vinay B. V. Sivareddy, Aswin Somuru), were supported through this project funds. Also, partial support was provided to three undergraduate students (Jonthan Dooley, India Snowden, Jeremy Gilmore) majoring in Chemistry, Physics, and Engineering disciplines. Various wet chemical methods of synthesis have been attempted to prepare perovskite oxide powders with a hope to improve and engineer its properties to meet the requirements of Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFCs) components. Various compounds were synthesized, characterized by XRD, TEM, SEM, XPS, electron microprobe and their electrical transport properties were measured by EIS at elevated temperatures and compared. Sonochemical technique (power of ultra sonic probe 750 watt) combined with hydrothermal treatment of precursors for the preparation of calcium hydroxy apatites (Ca-HAp) was used for the first time. Ca-HAp was substituted with Sr and Mg (50% replacement of Ca in Ca-HAp) to study the effect of substitution on Ca-HAp. Calcium hydroxy apatite is a bioceramic and has potential applications as artificial bone, enamel materials. In this study we tried to investigate its use as proton conductors in PC-SOFC. The properties like electrical conductivity, crystal structure, compositions of CaHAp were studied and compared with the natural bone material. The comparison found to be excellent indicating the efficiency of the preparation techniques. The typical value of conductivity measured is 0.091 x 10{sup -6} Scm{sup -1} at 25 C and 19.26 x 10{sup -6} Scm{sup -1} at 850 C with an applied frequency of 100 kHz. The conductivity increases on increasing frequency and temperature and reaches 0.05mS/cm at 500 C. The crystal structure and phase stability of perovskites as well as apatites were investigated with respect to substitution of various iso-valent and alivalent ions to determine the % of solubility in the crystal lattice of perovskite, apatites. Various electrode and electrolyte material compositions were prepared and characterized by XRD, SEM, XPS and electron microprobe. The material compositions were selected based on their thermo-physical properties to achieve compatibility with each other in ideal fuel cell operating conditions. The series of electrode materials investigated are LaGa{sub 1-x}M{sub x}O{sub 3} (M = Mn, Mg, x = 0.1), LaCr{sub 1-x}M{sub x}O{sub 3} (M = Mn, Mg, Co, x=0.1), LaNi{sub 1-x}Fe{sub x}O{sub 3} (0 < x < 0.6) and Gd{sub 1-x}M{sub x}CoO{sub 3} (M=Ca, x=0.1). Attempts were made to prepare proton-conducting perovskites of SrCe{sub 1-x} M{sub x}O{sub 3} (M= Dy, Eu, Er, Tb, x=0.1) by using sonochemical and hydrothermal technique followed by microwave sintering processes. These compositions were prepared characterized by XRD, TEM, SEM and electrical conductivity of the pellets was measured. The interest of low temperature proton conducting electrolyte is to replace the well known oxide ion conducting solid electrolyte in SOFCs, thereby reducing the operating temperature of SOFC to lower temperature (i.e 400-600 C) and named it as PC-SOFC (proton conducting-solid oxide fuel cell).

Rambabu Bobba

2006-09-14T23:59:59.000Z

304

Weatherization and Intergovernmental Program: Apply for Weatherization  

NLE Websites -- All DOE Office Websites (Extended Search)

Apply Apply for Weatherization Assistance to someone by E-mail Share Weatherization and Intergovernmental Program: Apply for Weatherization Assistance on Facebook Tweet about Weatherization and Intergovernmental Program: Apply for Weatherization Assistance on Twitter Bookmark Weatherization and Intergovernmental Program: Apply for Weatherization Assistance on Google Bookmark Weatherization and Intergovernmental Program: Apply for Weatherization Assistance on Delicious Rank Weatherization and Intergovernmental Program: Apply for Weatherization Assistance on Digg Find More places to share Weatherization and Intergovernmental Program: Apply for Weatherization Assistance on AddThis.com... Plans, Implementation, & Results Weatherization Assistance Program Weatherization Services

305

Vehicle Technologies Office: Applied Battery Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Battery Research Applied battery research addresses the barriers facing the lithium-ion systems that are closest to meeting the technical energy and power requirements for...

306

Top-emission Si-based phosphor organic light emitting diode with Au doped ultrathin n-Si film anode and bottom Al mirror  

SciTech Connect

We report a highly efficient top-emission Si-based phosphor organic light emitting diode (PhOLED) with an ultrathin polycrystalline n-Si:Au film anode and a bottom Al mirror. This anode is formed by magnetron sputtering followed by Ni induced crystallization and then Au diffusion. By optimizing the thickness of the n-Si:Au film anode, the Au diffusion temperature, and the other parameters of the PhOLED, the highest current and power efficiencies of the n-Si:Au film anode PhOLED reached 85{+-}9 cd/A and 80{+-}8 lm/W, respectively, corresponding to an external quantum efficiency of 21{+-}2% and a power conversion efficiency of 15{+-}2%, respectively, which are about 60% and 110% higher than those of the indium tin oxide anode counterpart and 70% and 50% higher than those of the bulk n{sup +}-Si:Au anode counterpart, respectively.

Li, Y. Z.; Xu, W. J.; Ran, G. Z. [State Key Laboratory for Mesoscopic Physics, School of Physics, Peking University, Beijing 100871 (China); Qin, G. G. [State Key Laboratory for Mesoscopic Physics, School of Physics, Peking University, Beijing 100871 (China); Key Lab of Semiconductor Materials, CAS, Beijing 100083 (China)

2009-07-20T23:59:59.000Z

307

Doped Yttrium Chromite-Ceria Composite as a Redox-Stable and Sulfur-Tolerant Anode for Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

A Ca- and Co-doped yttrium chromite (YCCC) - samaria-doped ceria (SDC) composite was studied in relation to a potential use as a solid oxide fuel cell (SOFC) anode material. Tests performed using the yttria-stabilized zirconia (YSZ) electrolyte-supported cells revealed that the electrocatalytic activity of the YCCC-SDC anode towards hydrogen oxidation at 800 C was comparable to that of the Ni-YSZ anode. In addition, the YCCC-SDC anode exhibited superior sulfur tolerant characteristics showing less than 10% increase in a polarization resistance, fully reversible, upon exposure to 20 ppm H2S at 800 C. No performance degradation was observed during multiple reduction-oxidation (redox) cycles when the anode was intentionally exposed to the air environment followed by the reduction in hydrogen. The redox tolerance of the YCCC-SDC anode was attributed to the dimensional and chemical stability of the YCCC exhibiting minimal isothermal chemical expansion upon redox cycling.

Yoon, Kyung J.; Coyle, Christopher A.; Marina, Olga A.

2011-12-11T23:59:59.000Z

308

DARPA Learning Applied to Ground Robots (LAGR)  

Science Conference Proceedings (OSTI)

DARPA Learning Applied to Ground Robots (LAGR) Project (Concluded). Summary: The National Institute of Standards ...

2012-01-04T23:59:59.000Z

309

Improved anode catalysts for coal gas-fueled phosphoric acid fuel cells  

Science Conference Proceedings (OSTI)

The feasibility of adapting phosphoric acid fuel cells to operate on coal gas fuels containing significant levels of contaminants such as CO, H{sub 2}S and COS has been investigated. The overall goal was the development of low-cost, carbon-supported anode fuel cell catalysts that can efficiently operate with a fossil fuel-derived hydrogen gas feed contaminated with carbon monoxide and other impurities. This development would reduce the cost of gas cleanup necessary in a coal gas-fueled PAFC power plant, thereby reducing the final power cost of the electricity produced. The problem to date has been that the contaminant gases typically adsorb on catalytic sites and reduce the activity for hydrogen oxidation. An advanced approach investigated was to modify these alloy catalyst systems to operate efficiently on coal gas containing higher levels of contaminants by increasing the alloy catalyst impurity tolerance and ability to extract energy from the CO present through (1) generation of additional hydrogen by promoting the CO/H{sub 2} water shift reaction or (2) direct oxidation of CO to CO{sub 2} with the same result. For operation on anode gases containing high levels of CO, a Pt-Ti-Zn and Pt-Ti-Ni anode catalyst showed better performance over a Pt baseline or G87A-17-2 catalyst. The ultimate aim of this effort was to allow PAFC-based power plants to operate on coal gas fuels containing increased contaminant concentrations, thereby decreasing the need for and cost of rigorous coal gas cleanup procedures. 4 refs., 15 figs., 10 tabs.

Kackley, N.D.; McCatty, S.A.; Kosek, J.A.

1990-07-01T23:59:59.000Z

310

Surface treated natural graphite as anode material for high-power Li-ion battery applications.  

Science Conference Proceedings (OSTI)

High power application of Li-ion battery in hybrid electrical vehicles requires low cost and safe cell materials. Among the various carbon anode materials used in lithium ion batteries, natural graphite shows the most promise with advantages in performance and cost. However, natural graphite is not compatible with propylene carbonate (PC)-based electrolytes, which have a lower melting point and improved safety characteristics. The problem with it is that the molecules of propylene carbonate intercalate with Li+ into graphite, and that frequently leads to the exfoliation of the graphite matrix.

Liu, J.; Vissers, D. R.; Amine, K.; Barsukov, I. V.; Henry, F.; Doniger, J.; Chemical Engineering; Superior Graphite Co.

2006-01-01T23:59:59.000Z

311

Real Space Mapping of Li-Ion Transport in Amorphous Si Anodes with Nanometer Resolution  

SciTech Connect

The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. The evolution of Li-ion transport during the battery charging is directly observed.

Balke, Nina [ORNL; Jesse, Stephen [ORNL; Kim, Yoongu [Oak Ridge National Laboratory (ORNL); Adamczyk, Leslie A [ORNL; Tselev, Alexander [ORNL; Ivanov, Ilia N [ORNL; Dudney, Nancy J [ORNL; Kalinin, Sergei V [ORNL

2010-01-01T23:59:59.000Z

312

Photoactivation of the processes of formation of nanostructures by local anodic oxidation of a titanium film  

Science Conference Proceedings (OSTI)

Experimental results on the conditions of activation of probe nanolithography of a thin titanium film by means of local anodic oxidation are reported. It is established that ultraviolet stimulation reduces the geometric dimensions of nanometric oxide structures. The stimulation is accompanied by an increase in the amplitude and duration of the threshold voltage pulse, correspondingly, from 6 to 7 V and from 50 to 100 ms at the relative humidity 50%. The experimental data on the effect of the cantilever coating material and substrate temperature on the geometric dimensions of nanometric oxide structures are reported.

Ageev, O. A.; Alyab'eva, N. I.; Konoplev, B. G., E-mail: kbg@tsure.ru; Polyakov, V. V.; Smirnov, V. A. [Southern Federal University, Taganrog Institute of Technology (Russian Federation)

2010-12-15T23:59:59.000Z

313

"Buried-Anode" Technology Leads to Advanced Lithium Batteries (Fact Sheet)  

DOE Green Energy (OSTI)

A technology developed at the National Renewable Energy Laboratory has sparked a start-up company that has attracted funding from the Advanced Projects Research Agency-Energy (ARPA-E). Planar Energy, Inc. has licensed NREL's "buried-anode" technology and put it to work in solid-state lithium batteries. The company claims its large-format batteries can achieve triple the performance of today's lithium-ion batteries at half the cost, and if so, they could provide a significant boost to the emerging market for electric and plug-in hybrid vehicles.

Not Available

2011-02-01T23:59:59.000Z

314

Anodic Treatments  

Science Conference Proceedings (OSTI)

...pickled after being sand blasted. (d) Water from steam condensate or water treated by ion exchange should

315

Anode Baking  

Science Conference Proceedings (OSTI)

Feb 28, 2011 ... Gas consumption of less 1.9 GJ/t for a baking level (Lc) of greater than 33 angstrom has been maintained. Operation has been demonstrated...

316

A three-dimensional Macroporous Cu/SnO2 composite anode sheet prepared via a novel method  

SciTech Connect

Macroporous Cu/SnO2 composite anode sheets were prepared by a novel method which is based on slurry blending, tape casting, sintering, and reducing of metal oxides. Such composite Cu/SnO2 anode sheets have no conducting carbons and binders, and show improved discharge capacity and cycle life than the SnO2 electrode from conventional tape-casting method on Cu foil. This methodology produces limited wastes and is also adaptable to many other materials. It is easy for industrial scale production. With the optimization of particle size of the metal oxide, pore size, pore volume and other factors, this kind of macroporous Cu/SnO2 composite anode sheets could give significantly improved capacity and cycle life.

Xu, Wu; Canfield, Nathan L.; Wang, Deyu; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

2010-11-01T23:59:59.000Z

317

Oxidation Kinetics Modeling Applying Phase Field Approach  

Science Conference Proceedings (OSTI)

Presentation Title, Oxidation Kinetics Modeling Applying Phase Field Approach ... chemical reaction rates will increase exponentially and environmental attack...

318

Applied Chemicals and Materials Staff Directory  

Science Conference Proceedings (OSTI)

Applied Chemicals and Materials Staff Directory. ... accept either a name, organizational name, or ... MML Organization. Contact. Material Measurement ...

2012-10-12T23:59:59.000Z

319

Researcher, Los Alamos National Laboratory - Applied Physics...  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Physics Division | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response...

320

``Lithium-free'' thin-film battery with in situ plated Li anode  

Science Conference Proceedings (OSTI)

The Li-free thin-film battery with the cell configuration Li diffusion blocking overlayer/Cu/solid lithium electrolyte (Lipon)/LiCoO{sub 2} is activated by in situ plating of metallic Li at the Cu anode current collector during the initial charge. Electrochemical cycling between 4.2 and 3.0 V is demonstrated over 1,000 cycles at 1 mA/cm{sup 2} or over 500 cycles at 5 mA/cm{sup 2}. As corroborated by scanning electron microscopy during electrochemical cycling, the overlayer is imperative for a high cycle stability; otherwise the plated Li rapidly develops a detrimental morphology, and the battery loses most of its capacity within a few cycles. The Li-free thin-film battery retains the high potential of a Li cell while permitting its fabrication in air without the complications of a metallic Li anode. Thus, the Li-free thin-film battery survives solder reflow conditions, simulated by a rapid heating to 250 C for 10 min in air followed by quenching to room temperature, without any signs of degradation.

Neudecker, B.J.; Dudney, N.J.; Bates, J.B.

2000-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Improving Microstructure of Silicon/Carbon Nanofiber Composites as A Li Battery Anode  

SciTech Connect

We report the interfacial study of a silicon/carbon nanofiber (Si/CNF) nanocomposite material as a potentially high performance anode for rechargeable lithium ion batteries. The carbon nanofiber is hollow, with a graphitic interior and turbostratic exterior. Amorphous silicon layers were uniformly coated via chemical vapor deposition on both the exterior and interior surfaces of the CNF. The resulting Si/CNF composites were tested as anodes for Li ion batteries and exhibited capacities near 800 mAh g{sup -1} for 100 cycles. After cycling, we found that more Si had fallen off from the outer wall than from the inner wall of CNF. Theoretical calculations confirmed that this is due to a higher interfacial strength at the Si/C-edge interface at the inner wall than that of the Si/C-basal interface at the outer wall. Based upon the experimental analysis and theoretical calculation, we have proposed several interfacial engineering approaches to improve the performance of the electrodes by optimizing the microstructure of this nanocomposite.

Howe, Jane Y [ORNL; Burton, David J. [Applied Sciences, Inc.; Meyer III, Harry M [ORNL; Nazri, Maryam [Applied Sciences, Inc.; Nazri, G. Abbas [General Motors Corporation-R& D; Palmer, Andrew C. [Applied Sciences, Inc.; Lake, Patrick D. [Applied Sciences, Inc.

2013-01-01T23:59:59.000Z

322

ON THE ANODIC POLARIZATION BEHAVIOR OF CARBON STEEL IN HANFORD NUCLEAR WASTES  

Science Conference Proceedings (OSTI)

The effect of the important chemical constituents in the Hanford nuclear waste simulant on the anodic behavior of carbon steel was studied. Specifically, the effect of pH, nitrite concentration, nitrite/nitrate concentration ratios, total organic carbon and the chloride concentration on the open circuit potential, pitting potential and repassivation potential was evaluated. It was found that pH adjusting, although capable of returning the tank chemistry back to specification, did not significantly reduce the corrosivity of the stimulant compared to the present condition. Nitrite was found to be a potent inhibitor for carbon steel. A critical concentration of approximately 1.2M appeared to be beneficial to increase the difference of repassivation potential and open circuit potential considerably and thus prevent pitting corrosion from occurring. No further benefit was gained when increasing nitrite concentration to a higher level. The organic compounds were found to be weak inhibitors in the absence of nitrite and the change of chloride from 0.05M to 0.2M did not alter the anodic behavior dramatically.

BOOMER, K.D.

2007-01-31T23:59:59.000Z

323

Effects of Entropy Changes in Anode and Cathode on Thermo Behavior of Lithium Ion Batteries  

SciTech Connect

The entropies (?S) in various cathode and anode materials, as well as complete lithium ion bat-teries, were investigated by Electrochemical Thermodynamic Measurement System (ETMS). A thermodynamic model based on the fundamental properties of individual electrodes is used to obtain the transient and equilibrium temperature distribution of lithium ion batteries. The results from theoretical simulations are compared with the results obtained in experimental measure-ments. It is found that detailed shape of the entropy curves strongly depends on the manufac-turer of the materials even for the same nominal compositions. LiCoO2 has a much larger en-tropy change than those of LiNixCoyMnzO2. This means that LiNixCoyMnzO2 is much more thermodynamically stable than LiCoO2. The temperatures around the positive terminal of a prismatic battery are consistently higher than those at the negative terminal. When all other simulation parameters are the same, the effects of using battery-averaged entropy in the simulation tends to overestimate the predicted temperatures than using individual entropies for anode and cathode.

Williford, Ralph E.; Vishwanathan, Vilanyur V.; Zhang, Jiguang

2009-04-01T23:59:59.000Z

324

CHEMICAL ENGINEERING SCHOOL OF ENGINEERING & APPLIED SCIENCE  

E-Print Network (OSTI)

30 CHEMICAL ENGINEERING SCHOOL OF ENGINEERING & APPLIED SCIENCE MIAMI UNIVERSITY 2005-2006 The program leads to the degree, Bachelor of Science in Applied Science, with a major in Chemical Engineering The chemical engineering students learn to apply the concepts of chemistry, biochemistry and biological science

Dollar, Anna

325

Effect of anode film resistance on the charge/discharge capacity of a lithium-ion battery  

DOE Green Energy (OSTI)

Lithium-ion batteries are prone to failure, because both their capacity and rate capability decrease with cycling. Side reactions, which decrease the cell's cyclable lithium content, can be responsible for capacity fade. An increase in cyclable lithium content is also possible, but is limited by the initial overall lithium content. Formation of a solid electrolyte interphase film on the carbonaceous anode not only consumes cyclable lithium, but also increases the anode resistance, thus reducing the rate capability of the cell, as demonstrated via computer simulation of a lithium-ion cell. Simulations also suggest that the use of cutoff potentials may not effectively prevent undesired irreversible side reactions on overcharge or overdischarge.

Christensen, J.; Newman, J.

2003-04-10T23:59:59.000Z

326

Second coordinate readout in drift chambers by timing of the electromagnetic wave propagating along the anode wire  

Science Conference Proceedings (OSTI)

The feasibility of using an anode wire and surrounding electrodes in drift chambers as a transmission line for second coordinate readout has been studied. The method is based on propagation of the electromagnetic wave along the anode wire is determined by measurement, in an optimized electronic readout system, of the time difference between the arrivals of the signal to the ends of the wire. The resolution obtained on long wires (approx. 2 meters) is about 2 cm FWHM for minimum ionizing particles at a gas gain of approx. = 10/sup 5/.

Boie, R.A.; Radeka, V.; Rehak, P.; Xi, D.M.

1980-11-01T23:59:59.000Z

327

Electrodeposition of Ni5Sb2 nanowires array and its application as a high-performance anode material for lithium ion batteries  

Science Conference Proceedings (OSTI)

Single crystal Ni"5Sb"2 nanowires array is synthesized by direct-current electrodeposition technique. The initial specific discharge and charge capacity of the as-produced Ni"5Sb"2 nanowires array electrode as an anode material for lithium-ion batteries ... Keywords: Anode, Array structure, Charge/discharge capacity, Lithium-ion batteries, Nanowires

You-Wen Yang; Tian-Ying Li; Fei Liu; Wen-Bin Zhu; Xue-Liang Li; Yu-Cheng Wu; Ming-Guang Kong

2013-04-01T23:59:59.000Z

328

Microsoft PowerPoint - NanoAnode for Li-ion Batteries SRNL-L9100-2009-00153p1.ppt  

NLE Websites -- All DOE Office Websites (Extended Search)

Nanostructured Anodes for Lithium-Ion Nanostructured Anodes for Lithium-Ion Batteries at a glance  patent pending  increase energy density  longer cyclic life  replaces graphite anodes  simple and lower cost manufacturing Current carbon-based anodes are fabricated through a series of processes of mixing carbon, binder and conductive additives in organic solution, pasting the slurry on current collector and baking to remove solvent. It involves intensive labor, fire safety and environment emission control resulting in high cost. Background Savannah River Nuclear Solutions (SRNS), managing contractor of the Savannah River Site (SRS) for the Department of Energy, has developed new anodes for lithium-ion batteries that are reported to increase the energy density four-fold. It is

329

Fundamental & Applied Bioenergy | Clean Energy | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

a new generation of efficient bioenergy strategies that will reduce U.S. dependence on foreign oil and help curb carbon emissions. Fundamental and applied bioenergy research at...

330

Applied Control Strategies at a Cogeneration Plant.  

E-Print Network (OSTI)

?? The purpose of this paper is to demonstrate the effectiveness of classical strategies for dynamic control on authentic cogeneration processes. These strategies are applied (more)

Burns, Joseph William

2011-01-01T23:59:59.000Z

331

Applied Quantum Technology AQT | Open Energy Information  

Open Energy Info (EERE)

AQT Jump to: navigation, search Name Applied Quantum Technology (AQT) Place Santa Clara, California Zip 95054 Product California-based manufacturer of CIGS (copper indium gallium...

332

Demonstration of a Highly Efficient Solid Oxide Fuel Cell Power System Using Adiabatic Steam Reforming and Anode Gas Recirculation  

SciTech Connect

Solid oxide fuel cells (SOFC) are currently being developed for a wide variety of applications because of their high efficiency at multiple power levels. Applications for SOFCs encompass a large range of power levels including 1-2 kW residential combined heat and power applications, 100-250 kW sized systems for distributed generation and grid extension, and MW-scale power plants utilizing coal. This paper reports on the development of a highly efficient, small-scale SOFC power system operating on methane. The system uses adiabatic steam reforming of methane and anode gas recirculation to achieve high net electrical efficiency. The anode exit gas is recirculated and all of the heat and water required for the endothermic reforming reaction are provided by the anode gas emerging from the SOFC stack. Although the single-pass fuel utilization is only about 55%, because of the anode gas recirculation the overall fuel utilization is up to 93%. The demonstrated system achieved gross power output of 1650 to 2150 watts with a maximum net LHV efficiency of 56.7% at 1720 watts. Overall system efficiency could be further improved to over 60% with use of properly sized blowers.

Powell, Michael R.; Meinhardt, Kerry D.; Sprenkle, Vincent L.; Chick, Lawrence A.; Mcvay, Gary L.

2012-05-01T23:59:59.000Z

333

Factors Affecting Limiting Current in Solid Oxide Fuel Cells or Debunking the Myth of Anode Diffusion Polarization  

DOE Green Energy (OSTI)

Limiting current densities for solid oxide fuel cells were measured using both button cells and a flow-through cell. The cell anodes were supplied mixtures of humidified hydrogen and various inert gasses. It was demonstrated that the true limiting current in flow-through cells is reached when either: the hydrogen is nearly or completely depleted at the anode-electrolyte interface near the outlet; or when the concentration of steam at that interface becomes high enough to interfere with adsorption or transport of the remaining hydrogen near the triple-phase boundaries. Choice of inert gas had no effect on limiting currents in the flow-through tests, indicating that diffusion within the porous anode had no significant effect on cell performance at high currents. In the button cells, the apparent limiting currents were significantly changed by the choice of inert gas, indicating that they were determined by diffusion through the bulk gas within the support tube. It was concluded that the apparent limiting currents measured in button cells are influenced more by parameters of the experimental setup, such as the proximity of the fuel tube outlet, than by the physical properties of the anode.

Chick, Lawrence A.; Meinhardt, Kerry D.; Simner, Steven P.; Kirby, Brent W.; Powell, Michael R.; Canfield, Nathan L.

2011-04-25T23:59:59.000Z

334

Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony  

Science Conference Proceedings (OSTI)

The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

2011-02-27T23:59:59.000Z

335

The Effects of a Hydrogen Environment on the Lifetime of Small-Diameter Drift Chamber Anode Wires  

DOE Green Energy (OSTI)

Possible deterioration of anode sense wires used in a hydrogen-filled neutron detector is investigated. Wires were loaded with free weights and put into a wire detector environment. Stainless Steel, Tungsten, and Platinum wires did not break after exposure to charge equivalent to many wire lifetimes. Furthermore, exposure to hydrogen gas caused no noticeable surface degradation or change in wire yield strength.

King, J; Smith, T; Kunkle, J; Castelaz, J; Thomson, S; Burstein, Z; Bernstein, A; Rosenberg, L; Hefner, M

2005-04-29T23:59:59.000Z

336

Combined Theoretical and Experimental Investigation and Design of H2S Tolerant Anode for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

A solid oxide fuel cell (SOFC) is a high temperature fuel cell and it normally operates in the range of 850 to 1000 C. Coal syngas has been considered for use in SOFC systems to produce electric power, due to its high temperature and high hydrogen and carbon monoxide content. However, coal syngas also has contaminants like carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). Among these contaminants, H{sub 2}S is detrimental to electrode material in SOFC. Commonly used anode material in SOFC system is nickel-yttria stabilized zirconia (Ni-YSZ). The presence of H{sub 2}S in the hydrogen stream will damage the Ni anode and hinder the performance of SOFC. In the present study, an attempt was made to understand the mechanism of anode (Ni-YSZ) deterioration by H{sub 2}S. The study used computation methods such as quantum chemistry calculations and molecular dynamics to predict the model for anode destruction by H{sub 2}S. This was done using binding energies to predict the thermodynamics and Raman spectroscopy to predict molecular vibrations and surface interactions. On the experimental side, a test stand has been built with the ability to analyze button cells at high temperature under syngas conditions.

Gerardine G. Botte; Damilola Daramola; Madhivanan Muthuvel

2009-01-07T23:59:59.000Z

337

Anodic oxygen-transfer electrocatalysis at iron-doped lead dioxide electrodes  

SciTech Connect

The research illustrated in this thesis was performed under the guidance of Professor Dennis C. Johnson beginning in March 1987. Chapter 2 concentrates on the development and electrocatalytic properties of iron-doped {beta}-PbO{sub 2} films on noble-metal substrates. Chapter 3 focuses attention on the preparation and characterization of iron-doped {beta}-PbO{sub 2} films on titanium substrates (Fe-PbO{sub 2}/Ti). Chapter 4 discusses anodic evolution of ozone at Fe-PbO{sub 2}/Ti electrodes. Chapter 5 describes electrochemical incineration of p-benzoquinone (BQ) at Fe-PbO{sub 2}/Ti electrodes. In addition, the Appendix includes another published paper which is a detailed study of {alpha}-PbO{sub 2} films deposited on various types of stainless steel substrates.

Feng, Jianren

1994-10-01T23:59:59.000Z

338

Corrosion-resistant iridium-platinum anode material for high polarization application in corrosive acids  

DOE Patents (OSTI)

The present invention relates to highly corrosion resistant components for use in an electrochemical cell. Specifically, these components are resistant to corrosion under very extreme conditions such as exposure to aqua regia in the presence of a constant current density of 100mA/m{sup 2}. The components are comprised of an iridium-platinum alloy that comprises less than 30% iridium. In a preferred embodiment of the present invention, the iridium-platinum alloy comprises 15-20% iridium. In another preferred embodiment of the present invention, the iridium-platinum alloy is deposited on the surface of an electrochemical cell component by magnetron sputtering. The present invention also relates to a method for conducting an electrochemical reaction in the presence of highly corrosive acids under a high degree of polarization wherein the electrochemical cell comprises a component, preferably the anode, containing an iridium-platinum alloy that comprises less than 30% iridium.

Farmer, J.; Summers, L.; Lewis, P.

1993-09-08T23:59:59.000Z

339

Anode sputtering characteristics of the Berkeley 2.5 MV source  

SciTech Connect

An investigation was made of a number of parameters affecting the performance of the SuperHILAC 2.5 MV Adam injector source. The description will emphasize anode sputtered materials, and will discuss in some detail calcium and gold ion production. Parameters varied include electrode geometry, support gas type and electrode bias, to optimize beam intensity and electrode consumption. A factor of three improvement with high n$sup +$ gold ions appears evident with a new displaced electrode geometry. The source is operated in cold mode, is pulsed and operates usually at less than 0.6 amperes average current. Under these conditions source life has been measured to be sixteen hours at 25 percent duty factor when generating calcium ions with neon support gas. (auth)

Gavin, B.

1975-10-01T23:59:59.000Z

340

Mesoporous carbon -Cr2O3 composite as an anode material for lithium ion batteries  

SciTech Connect

Mesoporous carbon-Cr2O3 (M-C-Cr2O3) composite was prepared by co-assembly of in-situ formed phenolic resin, chromium precursor, and Pluronic block copolymer under acidic conditions, followed by carbonization at 750oC under Argon. The TEM results confirmed that the Cr2O3 nanoparticles, ranging from 10 to 20 nm, were well dispersed in the matrix of mesoporous carbon. The composite exhibited an initial reversible capacity of 710 mAh g-1 and good cycling stability, which is mainly due to the synergic effects of carbons within the composites, i.e. confining the crystal growth of Cr2O3 during the high temperature treatment step and buffering the volume change of Cr2O3 during the cycling step. This composite material is a promising anode material for lithium ion batteries.

Guo, Bingkun [ORNL; Chi, Miaofang [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Cost and energy consumption estimates for the aluminum-air battery anode fuel cycle  

DOE Green Energy (OSTI)

At the request of DOE's Office of Energy Storage and Distribution (OESD), Pacific Northwest Laboratory (PNL) conducted a study to generate estimates of the energy use and costs associated with the aluminum anode fuel cycle of the aluminum-air (Al-air) battery. The results of this analysis indicate that the cost and energy consumption characteristics of the mechanically rechargeable Al-air battery system are not as attractive as some other electrically rechargeable electric vehicle battery systems being developed by OESD. However, there are distinct advantages to mechanically rechargeable batteries, which may make the Al-air battery (or other mechanically rechargeable batteries) attractive for other uses, such as stand-alone applications. Fuel cells, such as the proton exchange membrane (PEM), and advanced secondary batteries may be better suited to electric vehicle applications. 26 refs., 3 figs., 25 tabs.

Humphreys, K.K.; Brown, D.R.

1990-01-01T23:59:59.000Z

342

Electrochemical and XRD characterization of platinum-ruthenium blacks for DMFC anodes.  

DOE Green Energy (OSTI)

It is generally accepted that Pt-Ru alloy catalysts with an atomic Pt-to-Ru ratio of 1:1 generate the best anode perform'ance in the direct methanol fuel cell (DMFG). However, at near-ambient cell operating temperatures, Gasteiger et al. reported that a catalyst with significantly lower Ru content, {approx} 10 at %, offers the highest activity towards methanol. Recently, Dinh et al. demonstrated that the activity of different Pt-Ru catalysts with the same Pt-to-Ru atomic ratio in the bulk might vary depending on the actual surface composition, which is often significantly different from that in the bulk phase, In this work, we study several experimental Pt-Ru catalysts (Johnson Matthey) with Pt-to-Ru atomic ratio ranging from 9: 1 to 1 :2. Electrocatalytic activity of these catalysts in methanol oxidation reaction is investigated in a regular DMFC 'and probed using voltammetric stripping of surhce CO.

Eickes, C. (Christian); Brosha, E. L. (Eric L.); Garzon, F. H. (Fernando H.); Purdy, G. M. (Geraldine M.); Zelenay, P. (Piotr); Morita, T. (Takanari); Thompsett, D. (David)

2002-01-01T23:59:59.000Z

343

Small angle x-ray scattering studies of carbon anodes used in lithium rechargeable batteries.  

DOE Green Energy (OSTI)

In ANL laboratories, disordered carbons with predictable surface area and porosity properties have been prepared using inorganic templates containing well defined pore sizes. The carbons have been tested in electrochemical cells as anodes in lithium secondary batteries. They deliver high specific capacity and display excellent performance in terms of the number of cycles run. In situ small angle X-ray scattering (SAXS) during electrochemical cycling was carried out at the Advanced Photon Source, at ANL. In order to monitor the carbon electrode structural changes upon cycling, an electrochemical cell was specially designed to allow for the application of electrical current and the collection of SAXS data at the same time. Results show that upon cycling the structure of the carbon remains unchanged, which is desirable in reversible systems.

Sandi, G.; Carrado, K. A.; Winans, R. E.; Seifert, S.; Johnson, C. S.

1999-11-16T23:59:59.000Z

344

Defective graphene as promising anode material for Na-ion battery and Ca-ion battery  

E-Print Network (OSTI)

We have investigated adsorption of Na and Ca on graphene with divacancy (DV) and Stone-Wales (SW) defect. Our results show that adsorption is not possible on pristine graphene. However, their adsorption on defective sheet is energetically favorable. The enhanced adsorption can be attributed to the increased charge transfer between adatoms and underlying defective sheet. With the increase in defect density until certain possible limit, maximum percentage of adsorption also increases giving higher battery capacity. For maximum possible DV defect, we can achieve maximum capacity of 1459 mAh/g for Na-ion batteries (NIBs) and 2900 mAh/g for Ca-ion batteries (CIBs). For graphene full of SW defect, we find the maximum capacity of NIBs and CIBs is around 1071 mAh/g and 2142 mAh/g respectively. Our results will help create better anode materials with much higher capacity and better cycling performance for NIBs and CIBs.

Datta, Dibakar; Shenoy, Vivek B

2013-01-01T23:59:59.000Z

345

Six Thousand Electrochemical Cycles of Double-Walled Silicon Nanotube Anodes for Lithium Ion Batteries  

DOE Green Energy (OSTI)

Despite remarkable progress, lithium ion batteries still need higher energy density and better cycle life for consumer electronics, electric drive vehicles and large-scale renewable energy storage applications. Silicon has recently been explored as a promising anode material for high energy batteries; however, attaining long cycle life remains a significant challenge due to materials pulverization during cycling and an unstable solid-electrolyte interphase. Here, we report double-walled silicon nanotube electrodes that can cycle over 6000 times while retaining more than 85% of the initial capacity. This excellent performance is due to the unique double-walled structure in which the outer silicon oxide wall confines the inner silicon wall to expand only inward during lithiation, resulting in a stable solid-electrolyte interphase. This structural concept is general and could be extended to other battery materials that undergo large volume changes.

Wu, H

2011-08-18T23:59:59.000Z

346

Applied technology section. Monthly report, March 1994  

Science Conference Proceedings (OSTI)

This is a monthly report giving the details on research currently being conducted at the Savannah River Technology Center. The following are areas of the research, engineering modeling and simulation, applied statistics, applied physics,experimental thermal hydraulics,and packaging and transportation.

Buckner, M.R.

1994-04-20T23:59:59.000Z

347

DRAFT GUIDANCE Applying for Other Uses of  

E-Print Network (OSTI)

DRAFT GUIDANCE Applying for Other Uses of Phosphogypsum: Submitting a Complete Petition 40 CFR 61 Assignment 0-2 #12;Applying for Other Uses of Phosphogypsum: Submitting a Complete Petition Table of Contents phosphogypsum in stacks? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.4. What

348

Applied Materials Inc AMAT | Open Energy Information  

Open Energy Info (EERE)

Inc AMAT Inc AMAT Jump to: navigation, search Name Applied Materials Inc (AMAT) Place Santa Clara, California Zip 95052-8039 Sector Solar Product US-based manufacturer of equipment used in solar (silicon, thin-film, BIPV), semiconductor, and LCD markets. References Applied Materials Inc (AMAT)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Applied Materials Inc (AMAT) is a company located in Santa Clara, California . References ↑ "Applied Materials Inc (AMAT)" Retrieved from "http://en.openei.org/w/index.php?title=Applied_Materials_Inc_AMAT&oldid=342244" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes

349

Applied Materials Wind Turbine | Open Energy Information  

Open Energy Info (EERE)

Wind Turbine Wind Turbine Jump to: navigation, search Name Applied Materials Wind Turbine Facility Applied Materials Sector Wind energy Facility Type Community Wind Facility Status In Service Owner Applied Materials Developer Applied Materials Energy Purchaser Applied Materials Location Gloucester MA Coordinates 42.62895426°, -70.65153122° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":42.62895426,"lon":-70.65153122,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

350

Categorical Exclusion Determinations: B1.3 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

February 22, 2011 February 22, 2011 CX-005371: Categorical Exclusion Determination West Hackberry Off-Site Services Contract, 2011-2013 CX(s) Applied: B1.3 Date: 02/22/2011 Location(s): West Hackberry, Texas Office(s): Strategic Petroleum Reserve Field Office February 22, 2011 CX-005370: Categorical Exclusion Determination Clean and Inspect West Hackberry (WHT-14) Brine Tank CX(s) Applied: B1.3 Date: 02/22/2011 Location(s): West Hackberry, Louisiana Office(s): Strategic Petroleum Reserve Field Office February 22, 2011 CX-005369: Categorical Exclusion Determination Replacement of Big Hill Deep Anode Ground Bed Site for Cavern 103 CX(s) Applied: B1.3 Date: 02/22/2011 Location(s): Texas Office(s): Strategic Petroleum Reserve Field Office February 10, 2011 CX-005510: Categorical Exclusion Determination

351

Categorical Exclusion Determinations: Strategic Petroleum Reserve Field  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

10, 2012 10, 2012 CX-008350: Categorical Exclusion Determination Re-work Bryan Mound 30" Crude Oil Pipeline Mainline Valves CX(s) Applied: B1.3 Date: 04/10/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office April 10, 2012 CX-008349: Categorical Exclusion Determination Replacement Anode Bed on West Hackberry 42-inch Crude Oil Pipeline at Gum Cove Road CX(s) Applied: B1.3 Date: 04/10/2012 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office March 28, 2012 CX-008351: Categorical Exclusion Determination Transport and Perform TD&I on Big Hill TX-29 Transformer CX(s) Applied: B1.3 Date: 03/28/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office February 23, 2012 CX-007816: Categorical Exclusion Determination

352

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

December 8, 2010 December 8, 2010 CX-004664: Categorical Exclusion Determination On-Site Controlled Environment Agriculture Production of Biomass and Biofuels CX(s) Applied: B3.6 Date: 12/08/2010 Location(s): Tucson, Arizona Office(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory December 7, 2010 CX-004820: Categorical Exclusion Determination Uranium Oxide Synthesis CX(s) Applied: B3.6 Date: 12/07/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office December 7, 2010 CX-004819: Categorical Exclusion Determination Gas-Filled Radiation Detector with Carbon Nanotube Anode CX(s) Applied: B3.6 Date: 12/07/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office December 7, 2010 CX-004818: Categorical Exclusion Determination

353

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

31 - 25240 of 31,917 results. 31 - 25240 of 31,917 results. Download CX-005696: Categorical Exclusion Determination Alaska-Tribe-Native Village of Mekoryuk CX(s) Applied: B2.5, B5.1 Date: 03/01/2011 Location(s): Mekoryuk, Alaska Office(s): Energy Efficiency and Renewable Energy http://energy.gov/nepa/downloads/cx-005696-categorical-exclusion-determination Download CX-001227: Categorical Exclusion Determination Replacement of Big Hill Deep Anode Ground Bed Site for Cavern 114 CX(s) Applied: B1.3 Date: 03/16/2010 Location(s): Big Hill, Texas Office(s): Fossil Energy, Strategic Petroleum Reserve Field Office http://energy.gov/nepa/downloads/cx-001227-categorical-exclusion-determination Download CX-006423: Categorical Exclusion Determination North Carolina-City-High Point CX(s) Applied: A1, A9, A11, B2.5, B5.1

354

Categorical Exclusion Determinations: Strategic Petroleum Reserve Field  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

20, 2010 20, 2010 CX-001669: Categorical Exclusion Determination Install Fence Around Bryan Mound K-9 Training Area CX(s) Applied: B1.11 Date: 04/20/2010 Location(s): Freeport, Texas Office(s): Fossil Energy, Strategic Petroleum Reserve Field Office April 7, 2010 CX-001518: Categorical Exclusion Determination Re-seal Polyurethane Overcoat on BH Substation Relay Building 814 CX(s) Applied: B1.3 Date: 04/07/2010 Location(s): Texas Office(s): Fossil Energy, Strategic Petroleum Reserve Field Office March 16, 2010 CX-001227: Categorical Exclusion Determination Replacement of Big Hill Deep Anode Ground Bed Site for Cavern 114 CX(s) Applied: B1.3 Date: 03/16/2010 Location(s): Big Hill, Texas Office(s): Fossil Energy, Strategic Petroleum Reserve Field Office March 3, 2010 CX-001004: Categorical Exclusion Determination

355

Applying System Engineering to Pharmaceutical Safety  

E-Print Network (OSTI)

While engineering techniques are used in the development of medical devices and have been applied to individual healthcare processes, such as the use of checklists in surgery and ICUs, the application of system engineering ...

Couturier, Matthieu

356

Applied Information Security, 1st edition  

Science Conference Proceedings (OSTI)

Applied Information Security guides readers through the installation and basic operation of IT Security software used in the industry today. Dos Commands; Password Auditors; Data Recovery & Secure Deletion; Packet Sniffer; Port Scanners; Vulnerability ...

Randy Boyle

2009-07-01T23:59:59.000Z

357

Baldrige FAQs: Applying for the Award  

Science Conference Proceedings (OSTI)

... often use their feedback reports in their strategic planning processes to focus ... How long does it take to apply for the ... How long will it take to do a self ...

2013-05-21T23:59:59.000Z

358

Applied Field Research Initiative Deep Vadose Zone  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Applied Field Research Initiative Applied Field Research Initiative Deep Vadose Zone Located on the Hanford Site in Richland, Washington, the Deep Vadose Zone Applied Field Research Initiative (DVZ AFRI) was established to protect water resources by addressing the challenge of preventing contamination in the deep vadose zone from reaching groundwater. Led by the Pacific Northwest National Laboratory, the Initiative is a collaborative effort that leverages Department of Energy (DOE) investments in basic science and applied research and the work of site contractors to address the complex deep vadose zone contamination challenges. Challenge Many vadose zone environments within the DOE complex consist of complex stratified layers of unconsolidated and water-unsaturated sediments that are, in many places, con-

359

Applied Virtual Intelligence in Oil & Gas Industry;  

E-Print Network (OSTI)

1 Applied Virtual Intelligence in Oil & Gas Industry; Past, Present, & Future Shahab D. Mohaghegh on a daily basis by almost everyone. Credit Card Fraud Detection Bank Loan Approval Bomb Sniffing Devices

Mohaghegh, Shahab

360

Factors determining the consumption of ruthenium during electrosynthesis of sodium hypochlorite with the use of ruthenium oxide-titanium anodes  

Science Conference Proceedings (OSTI)

The authors studied the rate of destruction of the active coating as a function of the electrolysis conditions during electrochemical production of sodium hypochlorite. Corrosion tests were carried out on specimens made by the thermochemical method, in an electrochemical cell without a diaphragm; the method used was based on neutron activation analysis. It was shown that losses of ruthenium can be lowered by conducting the electrolysis at low temperatures, higher current densities, and moderately low hypochlorite concentrations. However, the increase of current density may raise the ROTA potential above the critical value, when rapid anode failure is possible. It was also shown that under conditions such that the critical ROTA potential is not reached sodium hypochlorite solutions of fairly high concentrations can be obtained with a low comsumption of ruthenium, which is not possible with the use of many other anode materials.

Klement'eva, V.S.; Kubasov, V.L.; Lambrev, V.G.; Uzbekov, A.A.

1985-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

In search of high performance anode materials for Mg batteries: computational studies of Mg in Ge, Si, and Sn  

E-Print Network (OSTI)

We present ab initio studies of structures, energetics, and diffusion properties of Mg in Si, Ge, and Sn diamond structures to evaluate their potential as insertion type anode materials for Mg batteries. We show that Si could provide the highest specific capacities (3817 mAh g-1) and the lowest average insertion voltage (~0.15 eV vs. Mg) for Mg storage. Nevertheless, due to its significant percent lattice expansion (~216%) and slow Mg diffusion, Sn and Ge are more attractive; both anodes have lower lattice expansions (~120 % and ~178 %, respectively) and diffusion barriers (~0.50 and ~0.70 eV, respectively for single-Mg diffusion) than Si. We show that Mg-Mg interactions at different stages of charging can decrease significantly the diffusion barrier compared to the single atom diffusion, by up to 0.55 eV.

Malyi, Oleksandr I; Manzhos, Sergei; 10.1016/j.jpowsour.2013.01.114

2013-01-01T23:59:59.000Z

362

Improved anode catalysts for coal gas-fueled phosphoric acid fuel cells; Progress report No. 15, Quarterly No. 5, June 3--September 2, 1989  

SciTech Connect

The development, optimization and demonstration of contaminant-tolerant anode catalyst formulations for phosphoric acid fuel cells is the overall objective of this project. During this quarter, anode electrodes were prepared from the following carbon-supported catalysts for evaluation in the hydrogen/hydrogen test cell: 70Pt:10Ti:20Cr, 59Pt:26Ti:15Cu, 91Pt:6Ti:3Sn, 72Pt:22Ti:6Ru and 67Pt:33Ti:0.2Zn. The catalyst preparation with a target composition of 70Pt:20Ti:10Zn resulted in a material with very low Zn content, only 0.2%. This catalyst was processed into an anode electrode for testing, despite the low Zn content, since Pt--Ti materials have also shown promise as CO and H{sub 2}S-tolerant anode catalysts. 5 tabs.

Kackley, N.; Kosek, J.A.

1989-09-01T23:59:59.000Z

363

The effect of nitrogen on the cycling performance in thin-film Si1xNx anode Donggi Ahn, Chunjoong Kim, Joon-Gon Lee, Byungwoo Park  

E-Print Network (OSTI)

and hybrid electric vehicles. The theoretical capacity of the commercially used graphite anode (372 mA h t i c l e i n f o Article history: Received 11 December 2007 Accepted 29 April 2008 Available online

Park, Byungwoo

364

The effects of silicon doping on the performance of PMAN carbon anodes in Li-ion cells  

DOE Green Energy (OSTI)

Carbons derived from polymethylacrylonitrile (PMAN) have been studied for use as intercalation anodes in Li-ion cells. The effect of Si doping upon the electrochemical performance of PMAN carbons was studied using tetravinylsilane (TVS) and tetramethysilane (TMS) as sources of Si during the formation of the PMAN precursors. The carbons were characterized by galvanostatic cycling, cyclic voltammetry, and complex impedance. The presence of 9 to 11 w/o Si in the PMAN lattice greatly increased the irreversible capacity of these materials.

Guidotti, R.A.; Johnson, B.J. [Sandia National Labs., Albuquerque, NM (United States); Even, W. Jr. [Sandia National Labs., Livermore, CA (United States)

1996-05-01T23:59:59.000Z

365

Performance of a C4F8O Gas Radiator Ring Imaging Cherenkov Detector Using Multi-anode Photomultiplier Tubes  

E-Print Network (OSTI)

We report on test results of a novel ring imaging Cherenkov (RICH) detection system consisting of a 3 meter long gaseous C4F8O radiator, a focusing mirror, and a photon detector array based on Hamamatsu multi-anode photomultiplier tubes. This system was developed to identify charged particles in the momentum range from 3-70 GeV/c for the BTeV experiment.

M. Artuso; C. Boulahouache; S. Blusk; J. Butt; O. Dorjkhaidav; N. Menaa; R. Mountain; H. Muramatsu; R. Nandakumar; K. Randrianarivony; R. Sia; T. Skwarnicki; S. Stone; J. C. Wang; K. Zhang

2005-05-17T23:59:59.000Z

366

Enhanced electron transport in dye-sensitized solar cells using short ZnO nanotips on a rough metal anode.  

DOE Green Energy (OSTI)

Many efforts have been directed toward the enhancement of electron transport in dye-sensitized solar cells (DSSC) using one-dimensional nanoarchitectured semiconductors. However, the improvement resulting from these ordered 1-D nanostructured electrodes is often offset or diminished by the deterioration in other device parameters intrinsically associated with the use of these 1-D nanostructures, such as the two-sided effect of the length of the nanowires impacting the series resistance and roughness factor. In this work, we mitigate this problem by allocating part of the roughness factor to the collecting anode instead of imparting all the roughness factors onto the semiconductor layer attached to the anode. A microscopically rough Zn microtip array is used as an electron-collecting anode on which ZnO nanotips are grown to serve as the semiconductor component of the DSSC. For the same surface roughness factor, our Zn-microtip|ZnO-nanotip DSSC exhibits an enhanced fill factor compared with DSSCs that have ZnO nanowires supported by a planar anode. In addition, the open-circuit voltage of the Zn-microtip|ZnO-nanotip DSSC is also improved due to a favorable band shift at the Zn-ZnO interface, which raises the Fermi level of the semiconductor and consequently enlarges the energy gap between the quasi-Fermi level of ZnO and the redox species. With these improvements, the overall efficiency becomes 1.4% with an open-circuit voltage of 770 mV, while the surface roughness factor of ZnO is approximately 60. Electrochemical impedance spectroscopic study reveals that the electron collection time is much shorter than the electron lifetime, suggesting that fast electron collection occurs in our device due to the significantly reduced electron collection distance along the short ZnO nanotips. The overall improvement demonstrates a new approach to enhance the efficiency of dye-sensitized solar cells.

Yang, Z.; Xu, T.; Ito, Y.; Welp, U.; Kwok, W. K.; Materials Science Division; Northern Illinois Univ.

2009-10-22T23:59:59.000Z

367

Task 1: Modeling Study of CO Effects on Polymer Electrolyte Fuel Cell Anodes Task 2: Study of Ac Impedance as Membrane/Electrode Manufacturing Diagnostic Tool  

DOE Green Energy (OSTI)

Carbon monoxide poisoning of polymer electrolyte fuel cell anodes is a key problem to be overcome when operating a polymer electrolyte fuel cell (PEFC) on reformed fuels. CO adsorbs preferentially on the precious metal surface leading to substantial performance losses. Some recent work has explored this problem, primarily using various Pt alloys in attempts to lower the degree of surface deactivation. In their studies of hydrogen oxidation on Pt and Pt alloy (Pt/Sn, Pt/Ru) rotating disk electrodes exposed to H{sub 2}/CO mixtures, Gasteiger et al. showed that a small hydrogen oxidation current is observed well before the onset of major CO oxidative stripping (ca. 0.4 V) on Pt/Ru. However, these workers concluded that such current observed at low anode overpotentials was too low to be of practical value. Nonetheless, MST-11 researchers and others have found experimentally that it is possible to run a PEFC, e.g., with a Pt/Ru anode, in the presence of CO levels in the range 10--100 ppm with little voltage loss. Such experimental results suggest that, in fact, PEFC operation at significant current densities under low anode overpotentials is possible in the presence of such levels of CO, even before resorting to air bleeding into the anode feed stream. The latter approach has been shown to be effective in elimination of Pt anode catalyst poisoning effects at CO levels of 20--50 ppm for cells operating at 80 C with low Pt catalyst loading. The effect of oxygen bleeding is basically to lower P{sub CO} down to extremely low levels in the anode plenum thanks to the catalytic (chemical) oxidation of CO by dioxygen at the anode catalyst. In this modeling work the authors do not include specific description of oxygen bleeding effects and concentrate on the behavior of the anode with feed streams of H{sub 2} or reformate containing low levels of CO. The anode loss is treated in this work as a hydrogen and carbon monoxide electrode kinetics problem, but includes the effects of dilution of the feedstream with significant fractions of carbon dioxide and nitrogen and of mass transport losses in the gas diffusion backing. Not included in the anode model are ionic resistance and diffusion losses in the catalyst layer. They are looking to see if the overall pattern of polarization curves calculated based on such a purely kinetic model indeed mimics the central features of polarization curves observed for PEFCs operating on hydrogen with low levels of CO.

Thomas E. Springer

1998-01-30T23:59:59.000Z

368

Highly efficient blue organic light emitting devices with indium-free transparent anode on flexible substrates  

Science Conference Proceedings (OSTI)

Indium-free transparent conducting oxides may provide a lower cost solution for the transparent anode in flexible displays and energy efficient solid state lighting. We report herein a near room temperature sputtering process for generating an indium-free transparent conductive oxide (TCO) coating on a flexible substrate. Specifically, we deposited gallium-doped zinc oxide (GZO) uniformly over a 12 diameter area at room temperature on polyethylene terephthalate (PET). During deposition, the system heats to about 60oC due to the energetic sputtering conditions, without any noticeable damage to the PET substrate. The GZO films exhibit excellent physical, optical and electrical properties: roughness ~7 nm, transmittance >85% and resistivity ~ 10-3 ohm cm. Phosphorescent blue organic light-emitting devices (OLEDs) were fabricated on these substrates with comparable performance (16% external quantum efficiency and 33 lm/W power efficiency at 1mA/cm2) to that of devices fabricated on GZO (or ITO) deposited on glass substrates, suggesting flexible GZO/PET substrates may be used instead of high-cost and rigid ITO and glass for flexible displays and solid state lighting.

Wang, Liang; Swensen, James S.; Polikarpov, Evgueni; Matson, Dean W.; Bonham, Charles C.; Bennett, Wendy D.; Gaspar, Daniel J.; Padmaperuma, Asanga B.

2010-09-30T23:59:59.000Z

369

A Partial Oxidation Technique for Fuel-Cell Anode Exhaust-Gas Synthesis  

DOE Green Energy (OSTI)

This paper describes the performance of a gas generator used to synthesize the exhaust gas from the anode of a molten-carbonate fuel cell. The composition of this gas is estimated to be that of equilibrium at 1,250 F and 1 atm: 48% CO2 , 39% H2O, 5% CO, and 8% H2, with an energy content of approximately 39 Btu/scf (higher heating value). To synthesize a range of gas compositions around this point, the gas generator partially oxidizes a mixture of CH4 , O2 , and CO2 to generate energy densities between 20 and 60 Btu/scf at temperatures between 1,198 and 1,350 F. Results show that the technique provides a relatively high ratio of CO to H2 concentrations compared with the target composition (CO:H2 of 2, versus 0.71). A detailed chemical model shows that the likely cause is quenching of the CO and H2 chemistry below 2,000 F.

Edward H. Robey, Jr.; Randall S. Gemmen

1998-11-10T23:59:59.000Z

370

Conductive Rigid Skeleton Supported Silicon as High-Performance Li-Ion Battery Anodes  

Science Conference Proceedings (OSTI)

A cost effective and scalable method is developed to prepare a core-shell structured Si/B4C composite with graphite coating with high efficiency, exceptional rate performance and long-term stability. In this material, conductive B4C with high Mohs hardness serves not only as micro-/nano- millers in the ball-milling process to break down micron-sized Si but also as the conductive rigid skeleton to support the in-situ formed sub-10 nm Si particles to alleviate the volume expansion during charge/discharge. The Si/B4C composite is coated with a few graphitic layers to further improve the conductivity and stability of the composite. The Si/B4C/graphite (SBG) composite anode shows excellent cyclability with a specific capacity of ~822 mAh?g-1 (based on the weight of the entire electrode, including binder and conductive carbon) and ~94% capacity retention over 100 cycles at 0.8C rate. This new structure has the potential to provide adequate storage capacity and stability for practical applications, and good opportunity for large scale manufacturing using commercially available materials and technologies.

Chen, Xilin; Li, Xiaolin; Ding, Fei; Xu, Wu; Xiao, Jie; Cao, Yuliang; Meduri, Praveen; Liu, Jun; Graff, Gordon L.; Zhang, Jiguang

2012-08-08T23:59:59.000Z

371

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes  

SciTech Connect

Silicon is regarded as one of the most promising anode materials for next generation lithium-ion batteries. For use in practical applications, a Si electrode must have high capacity, long cycle life, high efficiency, and the fabrication must be industrially scalable. Here, we design and fabricate a yolk-shell structure to meet all these needs. The fabrication is carried out without special equipment and mostly at room temperature. Commercially available Si nanoparticles are completely sealed inside conformal, thin, self-supporting carbon shells, with rationally designed void space in between the particles and the shell. The well-defined void space allows the Si particles to expand freely without breaking the outer carbon shell, therefore stabilizing the solid-electrolyte interphase on the shell surface. High capacity (?2800 mAh/g at C/10), long cycle life (1000 cycles with 74% capacity retention), and high Coulombic efficiency (99.84%) have been realized in this yolk-shell structured Si electrode.

Liu, Nian; Wu, Hui; Mcdowell, Matthew T.; Yao, Yan; Wang, Chong M.; Cui, Yi

2012-05-02T23:59:59.000Z

372

How to Apply | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

How to Apply How to Apply How to Apply Awards are made through a formal process that has changed dramatically since 2011. So let us walk you through it step by step. "Innovation pays." - John Kao, Innovation Nation Submit a Letter of Intent On October 28, 2013, the U.S. Department of Energy (DOE) announced on the DOE SBIR website a preview version of the technical topics for which it will later accept funding applications. These topics will be found on the DOE's Funding Opportunity Announcements page. The EE SBIR page lists those topics that are cleantech (specific to EERE). We also recommend that you sign up for the EE-SBIR and DOE-SBIR mailing lists. The EE SBIR mailing list signup is at https://public.govdelivery.com/accounts/USEERE/subscriber/new?topic_id=USEERE_442.

373

Applied Field Research Initiative Attenuation Based Remedies  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

PA00133 - March 2011 PA00133 - March 2011 Applied Field Research Initiative Attenuation Based Remedies in the Subsurface Located at the Savannah River Site in Aiken, South Carolina, the Attenuation-Based Remedies in the Subsurface Applied Field Research Initiative (ABRS AFRI) was established to develop the tools, approaches and technologies that will be required to address the technical challenges associated characteriza- tion, remediation and long-term monitoring of recalcitrant compounds in the subsurface at Department of Energy (DOE) Environmental Management (EM) sites. The ABRS AFRI site provides a unique setting for researchers in both applied and basic science fields. A wealth of subsurface data is available to support research activities and remedial decision making.

374

Applied Process Engineering Laboratory | Open Energy Information  

Open Energy Info (EERE)

Applied Process Engineering Laboratory Applied Process Engineering Laboratory Name Applied Process Engineering Laboratory Address 350 Hills Street, Suite #101 Place Richland, Washington Zip 99354 Region Pacific Northwest Area Coordinates 46.3389754°, -119.2716263° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":46.3389754,"lon":-119.2716263,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

375

Modeling International Relationships in Applied General Equilibrium  

Open Energy Info (EERE)

Modeling International Relationships in Applied General Equilibrium Modeling International Relationships in Applied General Equilibrium (MIRAGE) Jump to: navigation, search LEDSGP green logo.png FIND MORE DIA TOOLS This tool is part of the Development Impacts Assessment (DIA) Toolkit from the LEDS Global Partnership. Tool Summary LAUNCH TOOL Name: Modeling International Relationships in Applied General Equilibrium (MIRAGE) Agency/Company /Organization: International Food Policy Research Institute, Centre d'Etudes Prospectives et d'Informations Internationales (CEPII) Focus Area: Economic Development Topics: Co-benefits assessment, - Macroeconomic Resource Type: Software/modeling tools User Interface: Desktop Application Complexity/Ease of Use: Moderate Website: www.ifpri.org/book-5076/ourwork/program/mirage-model RelatedTo: Global Trade Analysis Project (GTAP) Data Base

376

Applied Ventures LLC | Open Energy Information  

Open Energy Info (EERE)

Applied Ventures LLC Applied Ventures LLC Name Applied Ventures LLC Address 3050 Bowers Avenue Place Santa Clara, California Zip 95054 Region Southern CA Area Product Venture capital. Number of employees 1-10 Phone number (408) 727-5555 Website http://www.appliedventures.com Coordinates 37.37751°, -121.978721° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.37751,"lon":-121.978721,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

377

Three-dimensional microstructural changes in the NiYSZ solid oxide fuel cell anode during operation  

Science Conference Proceedings (OSTI)

Microstructural evolution in solid oxide fuel cell (SOFC) cermet anodes has been investigated using X-ray nanotomography along with differential absorption imaging. SOFC anode supports composed of Ni and yttria-stabilized zirconia (YSZ) were subjected to extended operation and selected regions were imaged using a transmission X-ray microscope. X-ray nanotomography provides unique insight into microstructure changes of all three phases (Ni, YSZ, pore) in three spatial dimensions, and its relation to performance degradation. Statistically significant 3D microstructural changes were observed in the anode Ni phase over a range of operational times, including phase size growth and changes in connectivity, interfacial contact area and contiguous triple-phase boundary length. These observations support microstructural evolution correlated to SOFC performance. We find that Ni coarsening is driven by particle curvature as indicated by the dihedral angles between the Ni, YSZ and pore phases, and hypothesize that growth occurs primarily by means of diffusion and particle agglomeration constrained by a pinning mechanism related to the YSZ phase. The decrease in Ni phase size after extended periods of time may be the result of a second process connected to a mobility-induced decrease in the YSZ phase size or non-uniform curvature resulting in a net decrease in Ni phase size.

Nelson G. J.; Chu Y.; Grew, K.N.; Izzo Jr. J.R.; Lombardo, J.J.; Harris, W.M.; Faes, A.; Hessler-Wyser, A.; Van herle, J.; Wang, S.; Virkar, A.V.; Chiu, W.K.S.

2012-04-07T23:59:59.000Z

378

Characterization and Quantification of Electronic and Ionic Ohmic Overpotential and Heat Generation in a Solid Oxide Fuel Cell Anode  

Science Conference Proceedings (OSTI)

The development of a solid oxide fuel cell (SOFC) with a higher efficiency and power density requires an improved understanding and treatment of the irreversibilities. Losses due to the electronic and ionic resistances, which are also known as ohmic losses in the form of Joule heating, can hinder the SOFC's performance. Ohmic losses can result from the bulk material resistivities as well as the complexities introduced by the cell's microstructure. In this work, two-dimensional (2D), electronic and ionic transport models are used to develop a method of quantification of the ohmic losses within the SOFC anode microstructure. This quantification is completed as a function of properties determined from a detailed microstructure characterization, namely, the tortuosity of the electronic and ionic phases, phase volume fraction, contiguity, and mean free path. A direct modeling approach at the level of the pore-scale microstructure is achieved through the use of a representative volume element (RVE) method. The correlation of these ohmic losses with the quantification of the SOFC anode microstructure are examined. It is found with this analysis that the contributions of the SOFC anode microstructure on ohmic losses can be correlated with the volume fraction, contiguity, and mean free path.

Grew, Kyle N.; Izzo, John R.; Chiu, Wilson K.S.

2011-08-16T23:59:59.000Z

379

Applying Adaptive Evolutionary Algorithms to Hard Problems  

E-Print Network (OSTI)

Applying Adaptive Evolutionary Algorithms to Hard Problems J.I. van Hemert1 jvhemert into two distinct parts. The main theme is adaptive evolutionary algorithms. The rst part covers. The second part mainly consists of the development of a library. Its use is aimed at evolutionary algorithms

Emmerich, Michael

380

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

21 - 4630 of 28,905 results. 21 - 4630 of 28,905 results. Download CX-011002: Categorical Exclusion Determination ePATHS - Electric Phase Change Material Assisted Thermal Heating System CX(s) Applied: B3.6, B5.1 Date: 09/12/2013 Location(s): Michigan Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-011002-categorical-exclusion-determination Download CX-011032: Categorical Exclusion Determination Novel Non-Carbonate Based Electrolytes for Silicon Anodes CX(s) Applied: B3.6 Date: 09/10/2013 Location(s): California Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-011032-categorical-exclusion-determination Download CX-011033: Categorical Exclusion Determination Novel Non-Carbonate Based Electrolytes for Silicon Anodes

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381

The Atomic AXAFS and XANES Techniques as Applied to Heterogeneous Catalysis and Electrocatalysis  

Science Conference Proceedings (OSTI)

X-Ray absorption spectroscopy (XAFS) is an attractive in situ and in operando technique. In recent years, the more conventional extended X-ray absorption fine structure (EXAFS) data analysis technique has been complemented by two newer analysis methods: the 'atomic' XAFS (AXAFS) technique, which analyzes the scattering from the absorber atom itself, and the {Delta}{mu} XANES technique, which uses a difference method to isolate the changes in the X-ray absorption near edge structure (XANES) due to adsorbates on a metal surface. With AXAFS it is possible to follow the electronic effect a support has on a metal particle; with {Delta}{mu} XANES it is possible to determine the adsorbate, the specific adsorption sites and adsorbate coverage on a metal catalyst. This unprecedented new information helps a great deal to unravel the complex kinetic mechanisms operating in working reactors or fuelcell systems. The fundamental principles and methodology for applying the AXAFS and {Delta}{mu} XANES techniques are given here, and then specific applications are summarized, including H adsorption on supported Pt in the gas phase, wateractivation at a Pt cathode and methanol oxidation at a Pt anode in an electrochemical cell, sulfur oxidation on Pt, and oxygenreduction on a Au/SnO{sub x} cathode. Finally, the future outlook for time and/or space resolved applications of these techniques is contemplated.

Ramaker, D.; Koningsberger, D

2010-01-01T23:59:59.000Z

382

Title Page Applied and Environmental Microbiology 1  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied and Environmental Microbiology 1 Applied and Environmental Microbiology 1 2 Title Natural Competence in Thermoanaerobacter and Thermoanaerobacterium Species 3 Running Title Thermonanerobacter Natural Competence 4 5 Authors and Affiliations 6 A. Joe Shaw 1,2 , David A. Hogsett 1 , Lee R. Lynd 1,2,3 * 7 1 Mascoma Corporation, Lebanon, NH 03766 8 2 Thayer School of Engineering, Dartmouth College, Hanover, NH 03755 9 3 Department of Biological Sciences, Dartmouth College, Hanover, NH 03755 10 11 Corresponding Author 12 Lee R. Lynd 13 Thayer School of Engineering, Dartmouth College, Hanover, NH 03755 14 Phone: 603.646.2231 15 Email: lee.lynd@dartmouth.edu 16 17 18 19 20 21 22 23 Copyright © 2010, American Society for Microbiology and/or the Listed Authors/Institutions. All Rights Reserved.

383

Fundamental & Applied Bioenergy | Clean Energy | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioenergy Bioenergy SHARE Fundamental and Applied Bioenergy Steven Brown (left) and Shihui Yang have developed a microbial strain with an improved ability to convert wood products to biofuel as part of research within the DOE BioEnergy Science Center.Source: ORNL News article ORNL researchers are investigating the biological mechanisms underlying production of biofuels so that those mechanisms can be improved and used to develop a new generation of efficient bioenergy strategies that will reduce U.S. dependence on foreign oil and help curb carbon emissions. Fundamental and applied bioenergy research at ORNL includes studies conducted within the BioEnergy Science Center and the following research areas: Bioconversion Science and Technology Plant-Microbe Interfaces

384

Apply for Beam Time | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Apply for Beam Time Apply for Beam Time NEXT PROPOSAL DEADLINE: March 7, 2014 @ 11:59 PM (Chicago time) Submit Proposal » SEE ALSO: Calendar: deadlines, run & review dates Help Page: frequently asked questions, tips for success, common errors, blank forms, instructions Review Criteria Sectors Directory: check CAT websites for info about managed beam time The Run 2014-2 proposal submission deadline is 11:59 p.m. (Chicago time) March 7, 2014. The system will open to accept proposals beginning December 20, 2013. NEW USERS: to avoid delays and to make the most of your time on site, read Become a User. You must register as a user and receive a badge number before submitting a proposal. About the Beam Time Request Process All beam time at the APS must be requested each cycle through the web-based

385

Applying DSM evaluation results to utility planning  

SciTech Connect

This paper describes the results of a study to assess the application of DSM evaluation results to utility forecasting and planning. The paper has three objectives: (1) identify forecasting and planning applications of evaluation studies, (2) identify major obstacles and problems associated with applying evaluation results to forecasting and planning, and (3) suggest approaches to address the major problems. The paper summarizes results from interviews with utilities, regulators, and consultants to determine how the utility industry currently applies evaluation results in forecasting and planning. The paper also includes results from a detailed case study of Sacramento Municipal Utility District (SMUD) and Southern California Edison Company (SCE), two utilities with large DSM programs and active evaluation efforts.

Baxter, L.W.

1995-07-01T23:59:59.000Z

386

Applied Environmental Microbiology | VIMSS - Virtual Institute for  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection of Soil Samples Collection of Soil Samples Identification of Natural Stressors Profiling of Microbial Population Field and Simulated Conceptual Model Facilities The Applied Environmental Microbiology (AEM) Core is the source of environmental data and samples that determine the stressors that will be studied, pro-vides the environments for growing the organisms to be tested, simulates stressed environments, and verifies the conceptual models to determine how these stress regulatory pathways control the biogeochemistry of contaminated sites. The specific goals of the AEM Core are to: Survey and map DOE sites contaminated by metals and radionuclides using chemical and molecular/ microbiological parameters to determine major microbial populations and potential stressors for Desulfovibrio vulgaris,

387

Statistical Uncertainty Analysis Applied to Criticality Calculation  

Science Conference Proceedings (OSTI)

In this paper, we present an uncertainty methodology based on a statistical approach, for assessing uncertainties in criticality prediction using monte carlo method due to uncertainties in the isotopic composition of the fuel. The methodology has been applied to criticality calculations with MCNP5 with additional stochastic input of the isotopic fuel composition. The stochastic input were generated using the latin hypercube sampling method based one the probability density function of each nuclide composition. The automatic passing of the stochastic input to the MCNP and the repeated criticality calculation is made possible by using a python script to link the MCNP and our latin hypercube sampling code.

Hartini, Entin; Andiwijayakusuma, Dinan; Susmikanti, Mike; Nursinta, A. W. [Centre for Nuclear Informatics Development, National Nuclear Energy Agency of Indonesia (Indonesia)

2010-06-22T23:59:59.000Z

388

Environmentally assisted cracking of nickel anode substrates in Li/SOCl{sub 2} cells: An engineering approach  

DOE Green Energy (OSTI)

Intergranular environmentally assisted cracking (EAC) of Ni anode substrates is likely to occur in a large proportion of Li/SOCl{sub 2} cells, but it is not generally detected because in the majority of cases it does not lead to catatrophic failure. However, EAC could become a problem for applications requiring continuous power with high reliability for 10--15 years. In the present work, we determine why simple galvanic couple constant-strain tests do not produce cracking, and introduce a constant strain test that does produce cracking. Objective of this investigation is to determine the stress threshold for cracking as a function of Ni composition and microstructure.

Cieslak, W.R.; Weigand, D.E.; Buchheit, R.G.

1993-06-01T23:59:59.000Z

389

The Applied Mathematics for Power Systems (AMPS)  

SciTech Connect

Increased deployment of new technologies, e.g., renewable generation and electric vehicles, is rapidly transforming electrical power networks by crossing previously distinct spatiotemporal scales and invalidating many traditional approaches for designing, analyzing, and operating power grids. This trend is expected to accelerate over the coming years, bringing the disruptive challenge of complexity, but also opportunities to deliver unprecedented efficiency and reliability. Our Applied Mathematics for Power Systems (AMPS) Center will discover, enable, and solve emerging mathematics challenges arising in power systems and, more generally, in complex engineered networks. We will develop foundational applied mathematics resulting in rigorous algorithms and simulation toolboxes for modern and future engineered networks. The AMPS Center deconstruction/reconstruction approach 'deconstructs' complex networks into sub-problems within non-separable spatiotemporal scales, a missing step in 20th century modeling of engineered networks. These sub-problems are addressed within the appropriate AMPS foundational pillar - complex systems, control theory, and optimization theory - and merged or 'reconstructed' at their boundaries into more general mathematical descriptions of complex engineered networks where important new questions are formulated and attacked. These two steps, iterated multiple times, will bridge the growing chasm between the legacy power grid and its future as a complex engineered network.

Chertkov, Michael [Los Alamos National Laboratory

2012-07-24T23:59:59.000Z

390

EG G Mound Applied Technologies payroll system  

SciTech Connect

EG G Mound Applied Technologies, Inc., manages and operates the Mound Facility, Miamisburg, Ohio, under a cost-plus-award-fee contract administered by the Department of Energy's Albuquerque Field Office. The contractor's Payroll Department is responsible for prompt payment in the proper amount to all persons entitled to be paid, in compliance with applicable laws, regulations, and legal decisions. The objective was to determine whether controls were in place to avoid erroneous payroll payments. EG G Mound Applied Technologies, Inc., did not have all the internal controls required by General Accounting Office Title 6, Pay, Leave, and Allowances.'' Specifically, they did not have computerized edits, separation of duties and responsibilities, and restricted access to payroll data files. This condition occurred because its managers were not aware of Title 6 requirements. As a result, the contractor could not assure the Department of Energy that payroll costs were processes accurately; and fraud, waste, or abuse of Department of Energy funds could go undetected. Our sample of 212 payroll transactions from a population of 66,000 in FY 1991 disclosed only two minor processing errors and no instances of fraud, waste or abuse.

Not Available

1992-02-07T23:59:59.000Z

391

Investigations on the use of anodic stripping voltammetry for the analyses of lead in saline environments  

SciTech Connect

Research is reported directed to modification of the anodic stripping voltammetry (ASV) analytic method in order to acquire data for lead from ambient sea water conditions, and development of a chemical model which uses these data to identify inorganic lead species for saline environments. Laboratory and field samples were analyzed for lead partitioning in: (a) KCl electrolyte solutions; (b) I.A.P.S.O. Standard Sea Water; (c) seawater samples from Quatsino Sound, British Columbia; (d) a series of seawater samples from San Francisco Bay; and (e) seawater samples from the Gulf of Mexico. The electrochemical traits of the lead species and the ASV oxidation potential expression are the fundamental constituents of the chemical model. The model uses the data from the analyses to provide the mass balance relationships for lead partitioned among the major anions in seawater. The laboratory analyses of KCl electrolyte and Standard Seawater give the following results. The modified ASV method and chemical model provide information on ambient labile and non-labile inorganic lead complexes in these saline solutions down to the parts-per-billion level. No purge and the simple electrodes cause some erratic behavior and spurious potentials, but the data are reproducible. In addition to Pb/sup 2 +/, the most dominant measured lead species in order include PbCO/sub 3//sup 0/, PbSO/sub 4//sup 0/, PbCl/sup +/, and Pb(NO/sub 3/)/sub 2//sup 0/ from the lead additions solution. The analyses of the field samples give the following results. Samples were taken from the partially anoxic basin in Quatsino Sound, British Columbia with one successful analysis which is for somewhat normal dissolved oxygen conditions. Data show that lead is partitioned among Pb/sup 2 +/, Pb(OH)/sub 2//sup 0/, PbCO/sub 3//sup 0/, and PbSO/sub 4//sup 0/. The analyses with purge for the San Francisco Bay water partitions lead among Pb/sup 2 +/, PbCO/sub 3//sup 0/, PbSO/sub 4//sup 0/, PbCl/sup +/, and PbOH/sup +/. With successive lead additions Pb(NO/sub 3/)/sub 2//sup 0/ is decidedly the dominant species.

Case, C.W.

1978-08-01T23:59:59.000Z

392

A Case Study of the Applied Learning Academy: Reconceptualized Quantum Design of Applied Learning  

E-Print Network (OSTI)

The purpose of this qualitative study was to examine the Applied Learning Academy (ALA) and allow the lessons learned from this public school to emerge from the narrative stories of past students, parents, teachers, administrators, and local business associates who have been directly involved and influenced by the applied learning teaching method. Accountability is critical for all public and charter schools. Districts have been trying to raise the standards with new programs and strategies in an effort to make learning experiences relevant to students? daily lives. Revisiting John Dewey?s philosophy from the progressive movement, project-based, service learning, community partnerships, and portfolio assessment helped to create the applied learning method. In the present study, a qualitative case study approach was utilized to identify successful factors, benefits, and drawbacks of applied learning in order to describe the transition of portfolio assessment, project-based learning, and community-based partnerships within the classroom and to understand the impact and misconceptions of applied learning as experienced through the Recognized Campus, ALA, a 6-8th public middle school within a large urban school district. Participant interviews, field observations, and historical records were collected which indicated that student centered project-based curriculum, small school size creating family relationships, community involvement with partnerships, service learning projects, and metacognitive development from portfolio assessments were the major factors that supported academic rigor and relevance because of the real educational applications in this applied learning middle school. Briefly defined, applied learning is when a problem is seen within the surrounding community, and the solution is generated by the students. This progressive 15-year impact of applied learning ultimately leads to the development of four applied learning schools despite the misconception that applied learning was a remedial or gifted program. Redefining applied learning for a better understanding developed a reconceptualized diagram borrowed from the quantum mechanics model. Reconceptualization expands the interpretation by increasing the intellectual flexibility. As the student becomes energized from the acquired knowledge of learning applicable skills through service learning, project-based curriculum, and portfolio assessment, the student?s academic growth should increase to a higher, educational ?energy level? supported by the critical, situated-learning, and feminist theories.

Gordon, Denise

2009-12-01T23:59:59.000Z

393

Applied Energy Management | Open Energy Information  

Open Energy Info (EERE)

Management Management Jump to: navigation, search Name Applied Energy Management Place Huntersville, North Carolina Zip 28078 Sector Efficiency, Renewable Energy Product North Carolina-based, energy efficiency and renewable energy service and construction company. Coordinates 35.409853°, -80.842716° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":35.409853,"lon":-80.842716,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

394

How to Apply for ENERGY STAR® Certification  

NLE Websites -- All DOE Office Websites (Extended Search)

ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü "How To" Series How to Apply for ENERGY STAR ® Certification Commercial buildings that earn EPA's ENERGY STAR certification perform in the top 25 percent of similar buildings nationwide, as verified by a Licensed Professional (a Professional Engineer or a Registered Architect). ENERGY STAR certified buildings use an average of 35 percent less energy and are responsible for 35 percent fewer greenhouse gas emissions than average buildings. To qualify for the ENERGY STAR, a property must achieve an ENERGY STAR score of 75 or higher on EPA's 1 - 100 scale, which compares a property's energy performance to

395

FY 1990 Applied Sciences Branch annual report  

DOE Green Energy (OSTI)

The Applied Sciences Branch actively supports the advancement of DOE/SERI goals for the development and implementation of the solar photovoltaic technology. The primary focus of the laboratories is to provide state-of-the-art analytical capabilities for materials and device characterization and fabrication. The branch houses a comprehensive facility which is capable of providing information on the full range of photovoltaic components. A major objective of the branch is to aggressively pursue collaborative research with other government laboratories, universities, and industrial firms for the advancement of photovoltaic technologies. Members of the branch disseminate research findings to the technical community in publications and presentations. This report contains information on surface and interface analysis, materials characterization, development, electro-optical characterization module testing and performance, surface interactions and FTIR spectroscopy.

Keyes, B.M.; Dippo, P.C. (eds.)

1991-11-01T23:59:59.000Z

396

Navigating without vision: Basic and applied research  

E-Print Network (OSTI)

ABSTRACT: We describe some of the results of our program of basic and applied research on navigating without vision. One basic research topic that we have studied extensively is path integration, a form of navigation in which perceived self-motion is integrated over time to obtain an estimate of current posilion and orientation. In experiments on pathway completion, one test of path integration ability, we have found that subjects who are passively guided over the outbound path without vision exhibit significant errors when attempting to return to the origin but are nevertheless sensitive to turns and segment lengths in the stimulus path. We have also found no major differences in path inlegration ability among blirid and sighted populations. A model we havc developed that attributes errors in path integration to errors in encoding the stimulus path is a good beginning toward understanding path integration performance. In otber research on path integration, in which optic flow information was manipulated in addition to the proprioceptive and vestibular information of nonvisual locomotion, we havc found that optic flow is a weak input to the path integration process. In other basic research, our studies of auditory distance perception in outdoor environments show systematic underestimation oC sound source distance. Our applied research has been concerned with developing and evaluating a navigation system for the visually impaired that uses three recent technologies: the Global Positioning System, Geographic Information Systems, and virtual acouslics. Our work shows that there is considerable promise of these three technologies in allowing visually impaired individuals to navigate and learn about unfamiliar environments without the assistance of human guides. (Optoni Vis Sci 2001;78:282-289)

Jack M. Loomis; Roberta L. Klatzky; Reginald G. Golledge

2001-01-01T23:59:59.000Z

397

Sn/SnOx Core-Shell Nanospheres: Synthesis, Anode Performance in Li Ion Batteries, and Superconductivity  

Science Conference Proceedings (OSTI)

Sn/SnO{sub x} core?shell nanospheres have been synthesized via a modified polyol process. Their size can be readily controlled by tuning the usage of surface stabilizers and the temperature. Anode performance in Li ion batteries and their superconducting properties is detailed. As anode materials, 45 nm nanospheres outperform both larger and smaller ones. Thus, they exhibit a capacity of about 3443 mAh cm{sup -3} and retain about 88% of after 10 cycles. We propose a model based on the microstructural evolution to explain the size impact on nanosphere performance. Magnetic measurements indicate that the nanospheres become superconducting below the transition temperature T{sub C} = 3.7 K, which is similar to the value obtained in bulk tin. Although T{sub C} does not significantly change with the size of the Sn core, we determined that the critical field H{sub C} of nanospheres can be as much as a factor of 30 larger compared to the bulk value. Alternating current measurements demonstrated that a transition from conventional to filamentary superconducting structure occurs in Sn/SnO{sub x} particles as their size increases. The transition is determined by the relationship between the particle size and the magnetic field penetration depth.

Wang, X.L.; Feygenson, M.; Aronson, M.C.; Han, W.-Q.

2010-09-09T23:59:59.000Z

398

Enhanced performance of graphite anode materials by AlF3 coating for lithium-ion batteries  

Science Conference Proceedings (OSTI)

In order to form the stable surface film and to further enhance the long-term cycling stability of the graphite anodes of lithium-ion batteries, the surface of graphite powders has been modified by AlF3 coating through chemical precipitation method. The AlF3-coated graphite shows no evident changes in the bulk structure and a thin AlF3-coating layer of about 2 nm thick is found to uniformly cover the graphite particles with 2 wt% AlF3 content. However, it delivers a higher initial discharge capacity and largely improved rate performances compared to the pristine graphite. Remarkably, AlF3 coated graphite demonstrated a much better cycle life. After 300 cycles, AlF3 coated graphite and uncoated graphite show capacity retention of 92% and 81%, respectively. XPS measurement shows that a more conductive solid electrode interface (SEI) layer was formed on AlF3 coated graphite as compared to uncoated graphite. SEM monograph also reveals that the AlF3-coated graphite particles have a much more stable surface morphology after long-term cycling. Therefore, the improved electrochemical performance of AlF3 coated graphite can be attributed to a more stable and conductive SEI formed on coated graphite anode during cycling process.

Ding, Fei; Xu, Wu; Choi, Daiwon; Wang, Wei; Li, Xiaolin; Engelhard, Mark H.; Chen, Xilin; Yang, Zhenguo; Zhang, Jiguang

2012-04-27T23:59:59.000Z

399

201/span>3 Short Course Applied Fundamentals in Interfacial Phenomena  

Science Conference Proceedings (OSTI)

Applied Fundamentals in Interfacial Phenomena Short Course held at the 104th AOCS Annual Meeting and Expo. 201/span>3 Short Course Applied Fundamentals in Interfacial Phenomena Applied Fundamentals in Interfacial Phenomena Saturday

400

A new phase in Ni-Sn-P system and its property as an anode material for lithium-ion batteries  

SciTech Connect

A new metastable phase was synthesized by ball milling. The new phase is tetragonal with lattice parameters a = 3.671 A and c = 4.033 A. It was found that the new phase transformed into equilibrium orthorhombic Ni{sub 2}SnP phase at 973 K. The initial capacity of the lithium battery with the tetragonal Ni{sub 2}SnP phase as anode material reaches 500.4 mAh/g, but decreases to 181.8 mAh/g after 25 cycles. However, its initial irreversible capacity is 102 mAh/g, which makes it a promising anode material.

Xia, Z.P.; Lin, Y. [Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Li, Z.Q. [Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)], E-mail: zongquanli@zju.edu.cn

2008-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Remediation of Mercury and Industrial Contaminants Applied Field...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative (RoMIC-AFRI) Remediation of Mercury and Industrial Contaminants Applied Field Research...

402

Computational Advances in Applied Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advances in Applied Energy Computational Advances in Applied Energy Friedmann-LLNL-SEAB.10.11.pdf More Documents & Publications Director's Perspective by George Miller...

403

Attenuation-Based Remedies in the Subsurface Applied Field Research...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Subsurface Applied Field Research Initiative (ABRS AFRI) Located at the Savannah River Site in Aiken, South Carolina, the Attenuation-Based Remedies in the Subsurface Applied...

404

Applying Climate Information for Adaptation Decision-Making:...  

Open Energy Info (EERE)

Applying Climate Information for Adaptation Decision-Making: A Guidance and Resource Document Jump to: navigation, search Tool Summary Name: Applying Climate Information for...

405

Applying physics, teamwork to fusion energy science | Princeton...  

NLE Websites -- All DOE Office Websites (Extended Search)

Applying physics, teamwork to fusion energy science American Fusion News Category: Massachusetts Institute of Technology (MIT) Link: Applying physics, teamwork to fusion energy...

406

Enhancement of electron lifetime in dye-sensitized solar cells using anodically grown TiO2 nanotube/nanoparticle composite photoanodes  

Science Conference Proceedings (OSTI)

Dye-sensitized solar cells (DSCs) based on TiO"2 nanotube/nanoparticle (NT/NP) composite photoanodes were fabricated including different NT content into the NP network. The NPs expose large surface area for the dye anchoring, while the incorporated nanotubes ... Keywords: Anodic oxidation, Charge transport, Dye-sensitized solar cell, Electron lifetime, TiO2 nanotubes

Andrea Lamberti, Adriano Sacco, Stefano Bianco, Marzia Quaglio, Diego Manfredi, Candido Fabrizio Pirri

2013-11-01T23:59:59.000Z

407

Influence of Reduction Pretreatment and Methane Reforming on Nickel Solubility in YSZ Grains and Nickel Sintering within Ni-YSZ SOFC Anode Materials  

Science Conference Proceedings (OSTI)

Internal reforming of hydrocarbon fuels (e.g. methane or natural gas) can improve the thermal efficiency of solid oxide fuel cells (SOFC) by balancing exothermic electrochemical oxidation of H2 and CO at the anode/cathode interface with endothermic steam reforming reactions on the anode1. Generally the rate of reforming is much greater than the rate of H2 and CO oxidation leading to extensive thermal gradients across the cell that can compromise the physical integrity of the cell. Therefore, methods to control reformation activity and predict thermal gradients are needed. Computational modeling is used to predict thermal gradients and fuel conversion profiles across the cell, thus accurate and predictable methane reforming kinetics are required. Significant discrepancies in activation energy, rate expressions, and rate constants for methane reforming over nickel-yttria stabilized zirconia (Ni-YSZ) are reported in the open literature1-4. The objective of this work is to provide clarity on factors leading to discrepancies in kinetic information reported in the literature and identify potential methods to control reforming rates over NiYSZ anodes. Effects of pretreatment and reforming on Ni microstructure and activity of NiYSZ anodes for methane reforming were examined under open-circuit conditions.

Strohm, James J.; King, David L.; Saraf, Laxmikant V.; Lea, Alan S.; Wang, Chong M.; Singh, Prabhakar

2009-08-15T23:59:59.000Z

408

Field Trial of impressed current, sacrificial anode, constant voltage and intermittent cathodic protection on a steel reinforced coastal bridge  

Science Conference Proceedings (OSTI)

Equipment has been designed and installed for a field trial being conducted on a coastal reinforced concrete bridge with a newly installed cathodic protection (CP) system. The purpose of the field trial is to determine the optimum form of intermittent CP for protecting coastal bridges. The forms of CP that were considered for the field trial are: (1) impressed current CP as the control; (2) currentinterrupted ICCP; (3) corrosion rate monitoring device controlled ICCP; (4) constant voltage CP; and (5) sacrificial anode CP. Once the test is initiated, the performance of these four forms of CP on a coastal RC bridge and their effectiveness in providing protection to reinforcing steel will be is compared with that achieved by present Oregon Department of Transportation ICCP practices. Details are presented on the set up of the experiment and the logic used to control CP intermittently. The field trial is scheduled to be started early 2007.

Bullard, S.J.; Covino, B.S., Jr.; Williamson, K.M.; Holcomb, G.R.; Ziomek-Moroz, M.; Eden, D.A. (Intercorr International Inc.); Cryer, C.B. (ODOT); Tran, H. (ODOT)

2007-03-01T23:59:59.000Z

409

Development of Low Cost Carbonaceous Materials for Anodes in Lithium-Ion Batteries for Electric and Hybrid Electric Vehicles  

DOE Green Energy (OSTI)

Final report on the US DOE CARAT program describes innovative R & D conducted by Superior Graphite Co., Chicago, IL, USA in cooperation with researchers from the Illinois Institute of Technology, and defines the proper type of carbon and a cost effective method for its production, as well as establishes a US based manufacturer for the application of anodes of the Lithium-Ion, Lithium polymer batteries of the Hybrid Electric and Pure Electric Vehicles. The three materials each representing a separate class of graphitic carbon, have been developed and released for field trials. They include natural purified flake graphite, purified vein graphite and a graphitized synthetic carbon. Screening of the available on the market materials, which will help fully utilize the graphite, has been carried out.

Barsukov, Igor V.

2002-12-10T23:59:59.000Z

410

Utility-Scale Silicon Carbide Semiconductor: Monolithic Silicon Carbide Anode Switched Thyristor for Medium Voltage Power Conversion  

Science Conference Proceedings (OSTI)

ADEPT Project: GeneSiC is developing an advanced silicon-carbide (SiC)-based semiconductor called an anode-switched thyristor. This low-cost, compact SiC semiconductor conducts higher levels of electrical energy with better precision than traditional silicon semiconductors. This efficiency will enable a dramatic reduction in the size, weight, and volume of the power converters and electronic devices it's used in.GeneSiC is developing its SiC-based semiconductor for utility-scale power converters. Traditional silicon semiconductors can't process the high voltages that utility-scale power distribution requires, and they must be stacked in complicated circuits that require bulky insulation and cooling hardware. GeneSiC's semiconductors are well suited for high-power applications like large-scale renewable wind and solar energy installations.

None

2010-09-01T23:59:59.000Z

411

Microstructural characterization and mechanical property of active soldering anodized 6061 Al alloy using Sn-3.5Ag-xTi active solders  

SciTech Connect

Active solders Sn-3.5Ag-xTi varied from x = 0 to 6 wt.% Ti addition were prepared by vacuum arc re-melting and the resultant phase formation and variation of microstructure with titanium concentration were analyzed using X-ray diffraction, optical microscopy and scanning electron microscopy. The Sn-3.5Ag-xTi active solders are used as metallic filler to join with anodized 6061 Al alloy for potential applications of providing a higher heat conduction path. Their joints and mechanical properties were characterized and evaluated in terms of titanium content. The mechanical property of joints was measured by shear testing. The joint strength was very dependent on the titanium content. Solder with a 0.5 wt.% Ti addition can successfully wet and bond to the anodized aluminum oxide layers of Al alloy and posses a shear strength of 16.28 {+-} 0.64 MPa. The maximum bonding strength reached 22.24 {+-} 0.70 MPa at a 3 wt.% Ti addition. Interfacial reaction phase and chemical composition were identified by a transmission electron microscope with energy dispersive spectrometer. Results showed that the Ti element reacts with anodized aluminum oxide to form Al{sub 3}Ti-rich and Al{sub 3}Ti phases at the joint interfaces. - Highlights: Black-Right-Pointing-Pointer Active solder joining of anodized Al alloy needs 0.5 wt.% Ti addition for Sn-3.5Ag. Black-Right-Pointing-Pointer The maximum bonding strength occurs at 3 wt.% Ti addition. Black-Right-Pointing-Pointer The Ti reacts with anodized Al oxide to form Al{sub 3}Ti-rich and Al{sub 3}Ti at joint interface.

Wang, Wei-Lin, E-mail: wangwl77@gmail.com; Tsai, Yi-Chia, E-mail: tij@itri.org.tw

2012-06-15T23:59:59.000Z

412

Applied Science and Technology Task Order Fiscal Year 2009 Year...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

09 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2009 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2009 Year-End...

413

Applied Science and Technology Task Order Fiscal Year 2010 Year...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2010 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2010 Year-End...

414

Applied Science and Technology Task Order Fiscal Year 2011 Year...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2011 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2011 Year-End...

415

Applied Science and Technology Task Order Fiscal Year 2008 Year...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2008 Year-End Summary Report Applied Science and Technology Task Order Fiscal Year 2008 Year-End...

416

Proceedings of the 2011 ACM Symposium on Applied Computing  

Science Conference Proceedings (OSTI)

Welcome to the 26th International Symposium on Applied Computing (SAC 2011). For the past 25 years, SAC has become a major international venue for computing researchers and applied practitioners to convene and share ideas on recent developments in a ...

William Chu; W. Eric Wong; Mathew J. Palakal; Chih-Cheng Hung

2011-03-01T23:59:59.000Z

417

Proceedings of the 2010 ACM Symposium on Applied Computing  

Science Conference Proceedings (OSTI)

Welcome to the 25th International Symposium on Applied Computing (SAC 2010). For the past 24 years, SAC has become a major international venue for computing researchers and applied practitioners to convene and share ideas on recent developments in a ...

Sung Y. Shin; Sascha Ossowski; Michael Schumacher; Mathew J. Palakal; Chih-Cheng Hung

2010-03-01T23:59:59.000Z

418

DOE - Office of Legacy Management -- Case School of Applied Science...  

Office of Legacy Management (LM)

Case School of Applied Science Ohio State University - OH 0-01 FUSRAP Considered Sites Site: Case School of Applied Science, Ohio State University (OH.0-01 ) Eliminated from...

419

Roadmap: Applied Engineering Manufacturing Systems Bachelor of Science  

E-Print Network (OSTI)

Roadmap: Applied Engineering ­ Manufacturing Systems ­ Bachelor of Science [AT 15000 Introduction to Human Communication 3 Fulfills Kent Core Additional Kent Core Requirement 3 See #12;Roadmap: Applied Engineering ­ Manufacturing Systems ­ Bachelor of Science [AT

Sheridan, Scott

420

Open Solicitations and How to Apply: the Loan Guarantee Program...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Open Solicitations and How to Apply: the Loan Guarantee Program Invites You to a Free Webinar Open Solicitations and How to Apply: the Loan Guarantee Program Invites You to a Free...

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

PLZT NANO PRE URSORS FOR HIGH ENERGY DENSITY APPLI ATIONS  

APPLI ATIONS & INDUSTRIES ENEFITS Pulsed Power Oil Exploration Capacitors Refer to SD # 12119 Thermistors Transducers Military & Defense Automotive

422

Dixson and Fu Receive NIST Applied Research Award  

Science Conference Proceedings (OSTI)

Dixson and Fu Receive NIST Applied Research Award. For Immediate Release: December 1, 1999. *. Bookmark and Share. ...

2013-07-19T23:59:59.000Z

423

Materials Research Applied to National Needs (MARANN) in Honor ...  

Science Conference Proceedings (OSTI)

Jul 31, 2012 ... About this Symposium. Meeting, 2013 TMS Annual Meeting & Exhibition. Symposium, Materials Research Applied to National Needs...

424

PHOTOGRAMMETRIC ENGINEERING & REMOTE SENSING 1 ADVISER: Immersive Scientific Visualization Applied  

E-Print Network (OSTI)

be applied to the terrain (Figure 2b). A custom pixel shader was integrated with ROAM to render the dynamic

Head III, James William

425

ISHED1: Applying the LEM Methodology to Heat Exchanger Design  

E-Print Network (OSTI)

ISHED1: Applying the LEM Methodology to Heat Exchanger Design Kenneth A. Kaufman Ryszard S. Michalski MLI 00-2 #12;2 ISHED1: APPLYING THE LEM METHODOLOGY TO HEAT EXCHANGER DESIGN Kenneth A. Kaufman-2 January 2000 #12;ISHED1: APPLYING THE LEM METHODOLOGY TO HEAT EXCHANGER DESIGN Abstract Evolutionary

Michalski, Ryszard S.

426

Applying Innovation System Concept in Agricultural Research for  

Open Energy Info (EERE)

Applying Innovation System Concept in Agricultural Research for Applying Innovation System Concept in Agricultural Research for Development: A learning module Jump to: navigation, search Tool Summary Name: Applying Innovation System Concept in Agricultural Research for Development: A learning module Agency/Company /Organization: International Livestock Research Institute Sector: Land Focus Area: Agriculture Topics: Policies/deployment programs Resource Type: Training materials Website: mahider.ilri.org/bitstream/10568/167/1/Innovation_System_Agric_LM.pdf Applying Innovation System Concept in Agricultural Research for Development: A learning module Screenshot References: Applying Innovation System Concept in Agricultural Research for Development: A learning module[1] Preface "Sustained agricultural growth requires, among others, increased

427

Vehicle Technologies Office: Lightweight Materials Long-Term Applied  

NLE Websites -- All DOE Office Websites (Extended Search)

Long-Term Applied Research: Magnesium and Carbon Fiber to someone by E-mail Long-Term Applied Research: Magnesium and Carbon Fiber to someone by E-mail Share Vehicle Technologies Office: Lightweight Materials Long-Term Applied Research: Magnesium and Carbon Fiber on Facebook Tweet about Vehicle Technologies Office: Lightweight Materials Long-Term Applied Research: Magnesium and Carbon Fiber on Twitter Bookmark Vehicle Technologies Office: Lightweight Materials Long-Term Applied Research: Magnesium and Carbon Fiber on Google Bookmark Vehicle Technologies Office: Lightweight Materials Long-Term Applied Research: Magnesium and Carbon Fiber on Delicious Rank Vehicle Technologies Office: Lightweight Materials Long-Term Applied Research: Magnesium and Carbon Fiber on Digg Find More places to share Vehicle Technologies Office: Lightweight

428

Effect of Nickel Microstructure on Methane Steam-Reforming Activity of Ni-YSZ Cermet Anode Catalyst  

Science Conference Proceedings (OSTI)

The activity of nickel-yttria stabilized zirconia (Ni-YSZ) solid oxide fuel cell (SOFC) cermet anodes for the steam reforming of methane has been investigated in the absence of electrochemical effects. The cermet was prepared by co-milling and sintering NiO and 5YSZ powders at 1375oC in air. During the high temperature sintering step, NiO dissolved into the YSZ particles to form a solid NiO-YSZ solution. During the subsequent catalyst reduction step, Ni exolved from the YSZ. As a result, many small Ni particles on the order of 10-20 nm formed at the surface of the YSZ. These small particles contribute significantly to the overall reforming activity, along with the large bulk Ni particles within the Ni-YSZ cermet. We have observed high initial activity that decreases by as much as an order of magnitude with time on stream, until the anode catalyst reaches a stable steady state activity. The time to reach this stable activity is a function of the reaction conditions and feed gas composition. Higher temperature, hydrogen partial pressure, and space velocity all accelerated the deactivation rate at a constant steam-to-carbon ratio of 3. Initial and lined out activities and average turnover frequencies were obtained for both Ni-YSZ and bulk Ni, based on a rate expression that is first order in methane and zero order in steam. Comparative tests at 750oC show high initial activity on a per-Ni site basis with both materials, but these turnover rates decline over a period of a few hours. Following lineout, there appears to be a negligible effect of Ni particle size on turnover rate. These results indicate the presence of structure sensitivity for methane reforming, but only with freshly calcined and reduced catalysts that may contain highly coordinatively unsaturated sites. There is an apparent structure insensitivity with aged catalysts where Ni particle sizes are generally 50 nm and greater. Under reaction conditions that employ high space velocities and low methane conversions, the water-gas-shift reaction does not establish thermodynamic equilibrium.

King, David L.; Strohm, James J.; Wang, Xianqin; Roh, Hyun-Seog; Wang, Chong M.; Chin, Ya-Huei; Wang, Yong; Lin, Yuehe; Rozmiarek, Robert T.; Singh, Prabhakar

2008-09-10T23:59:59.000Z

429

Layered carbon lattices and their influence on the nature of lithium bonding in lithium intercalated carbon anodes.  

DOE Green Energy (OSTI)

Ab initio molecular orbital calculations have been used to investigate the nature of lithium bonding in stage 1 lithium intercalated carbon anodes. This has been approximated by using layered carbon lattices such as coronene, (C{sub 24}H{sub 12}),anthracene, and anthracene substituted with boron. With two coronene carbon lattices forming a sandwich structure and intercalated with either 2, 3, 4 or 6 six lithiums, it has been found that the predominant mode of bonding for the lithium is at the carbon edge sites as opposed to bonding at interior carbon hexagon sites. Formation of all structures is thermodynamically allowed except for the two lithium case in which there is repulsion between the lattices. The optimized structure with six lithiums gives a reasonable approximation for the stage 1 lithium intercalated carbon anode. In this case the lithium to carbon ratio is 1:8 versus 1:6 occurring in the stage 1 graphite. The coronene lattices are eclipsed with a separation of 4.03 {angstrom}. However, there is a slight ruffling of the lattice. Separation between adjacent lithiums is either 3.32 {angstrom} or 2.98 {angstrom}. Even though the separation between lithiums is very small, composition of the molecular orbitals suggests that there is no lithium cluster formation. The highest occupied molecular orbitals are composed of a combination of lithium and carbon orbitals. In contrast, in the C{sub 60} fullerene lattice with three and five lithiums intercalated, there are molecular orbitals composed only of lithiums, indicative of cluster formation. For anthracene and boron substituted anthracene, lithium bonding takes place within the carbon hexagon sites. The separation between lithiums in a sandwich type structure with two anthracenes in the eclipsed conformation is 5.36 {angstrom}. The effect of boron in a carbon lattice has been evaluated by comparing the difference in behavior of a single anthracene lattice reacting with a dilithium cluster as compared to a 1, 4, 5, 8-tetraboroanthracene lattice. The effect of boron substitution is to increases lattice flexibility by allowing the lattice to twist and lithium to bond at adjacent hexagon sites. The thermodynamic feasibility of the reaction between the dilithium cluster and the boron substituted anthracene lattice is enhanced.

Scanlon, L.G.

1998-05-27T23:59:59.000Z

430

SOFC Anode Interaction with Trace Coal Syngas Species U.S. Dept of Energy, National Energy Technology Laboratory, Morgantown, WV 26507  

NLE Websites -- All DOE Office Websites (Extended Search)

SOFC Anode Interaction with Trace Coal Syngas Species SOFC Anode Interaction with Trace Coal Syngas Species U.S. Dept of Energy, National Energy Technology Laboratory, Morgantown, WV 26507 Gregory Hackett, Kirk Gerdes, Randall Gemmen Phone: (304)285-5279, Gregory.Hackett@NETL.DOE.GOV Utilization of coal as a fuel source for highly efficient integrated gasification fuel cell (IGFC) power generation facilities is technologically and environmentally attractive. IGFC plants are expected to offer the highest efficiency coal gasification processes, even when carbon capture and storage systems are included in the design. One element of IGFC research at the National Energy Technology Laboratory is the investigation of syngas cleanup processes for these integrated systems. Of particular interest are the effects of trace elements naturally contained in

431

Charge-transfer interfaces between metal and redox arylamine molecular films: As probed with anode interfacial engineering approach in single-layer organic diodes  

E-Print Network (OSTI)

We investigate the charge-transfer interfaces between metal and redox arylamine molecular films through studying the current-voltage characteristics of single-layer organic diodes with the aid of anode interfacial engineering method. The diode turn-on voltage is shown to be highly sensitive to the arylamine/metal charge-transfer interfaces and thus can serve as a probe in detecting such organic/metal interfaces. We show that the diode electrical performance could be tuned through engineering the arylamine/metal interfaces via controlling the factors of anode work function, arylamine substitute groups, and active layer surface morphology etc. The conduction mechanism of the diodes is shown to be injection limited, which could be well described with Richardson-Schottky thermonic emission model. Our work may provide some insight into the use of single-layer organic diode and interfacial engineering method to rapidly probe the organic/metal and even organic/organic charge-transfer interfaces.

J. C. Li; S. C. Blackstock; G. J. Szulczewski

2005-08-19T23:59:59.000Z

432

Novel motor design for rotating anode x-ray tubes operating in the fringe field of a magnetic resonance imaging system  

SciTech Connect

Purpose: Using hybrid x-ray/MR (XMR) systems for image guidance during interventional procedures could enhance the diagnosis and treatment of neurologic, oncologic, cardiovascular, and other disorders. The authors propose a close proximity hybrid system design in which a C-arm fluoroscopy unit is placed immediately adjacent to the solenoid magnet of a MR system with a minimum distance of 1.2 m between the x-ray and MR imaging fields of view. Existing rotating anode x-ray tube designs fail within MR fringe field environments because the magnetic fields alter the electron trajectories in the x-ray tube and act as a brake on the induction motor, reducing the rotation speed of the anode. In this study the authors propose a novel motor design that avoids the anode rotation speed reduction. Methods: The proposed design replaces the permanent magnet stator found in brushed dc motors with the radial component of the MR fringe field. The x-ray tube is oriented such that the radial component of the MR fringe field is orthogonal to the cathode-anode axis. Using a feedback position sensor and the support bearings as electrical slip rings, the authors use electrical commutation to eliminate the need for mechanical brushes and commutators. A vacuum compatible prototype of the proposed motor design was assembled, and its performance was evaluated at various operating conditions. The prototype consisted of a 3.1 in. diameter anode rated at 300 kHU with a ceramic rotor that was 5.6 in. in length and had a 2.9 in. diameter. The material chosen for all ceramic components was MACOR, a machineable glass ceramic developed by Corning Inc. The approximate weight of the entire assembly was 1750 g. The maximum rotation speed, angular acceleration, and acceleration time of the motor design were investigated, as well as the dependence of these parameters on rotor angular offset, magnetic field strength, and field orientation. The resonance properties of the authors' assembly were also evaluated to determine its stability during acceleration, and a pulse width modulation algorithm was implemented to control the rotation speed of the motor. Results: At a magnetic flux density of 41 mT orthogonal to the axis of rotation (on the lower end of the expected flux density in the MR suite) the maximum speed of the motor was found to be 5150 revolutions per minute (rpm). The acceleration time necessary to reach 3000 rpm was found to be approximately 10 s at 59 mT. The resonance frequency of the assembly with the anode attached was 1310 rpm (21.8 Hz) which is far below the desired operating speeds. Pulse width modulation provides an effective method to control the speed of the motor with a resolution of 100 rpm. Conclusions: The proposed design can serve as a direct replacement to the conventional induction motor used in rotating anode x-ray tubes. It does not suffer from a reduced rotation speed when operating in a MR environment. The presence of chromic steel bearings in the prototype prevented testing at the higher field strengths, and future iterations of the design could eliminate this shortcoming. The prototype assembly demonstrates proof of concept of the authors' design and overcomes one of the major obstacles for a MR compatible rotating anode x-ray tube.

Lillaney, Prasheel; Pelc, Norbert [Department of Radiology, Stanford University, Stanford, California 94305 and Department of Bioengineering, Stanford University, Stanford, California 94305 (United States); Shin Mihye [Department of Radiology, Stanford University, Stanford, California 94305 and Department of Mechanical Engineering, Stanford University, Stanford, California 94305 (United States); Hinshaw, Waldo; Fahrig, Rebecca [Department of Radiology, Stanford University, Stanford, California 94305 (United States); Bennett, N. Robert [Department of Radiology, Stanford University, Stanford, California 94305 and Qualcomm MEMS Technologies, San Jose, California 95134 (United States)

2013-02-15T23:59:59.000Z

433

Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy Storage  

Science Conference Proceedings (OSTI)

i-ion batteries based on commercially available LiFePO4 cathode and Li4Ti5O12 anode were investigated for potential stationary energy storage applications. The full cell that operated at flat 1.85V demonstrated stable cycling for 200 cycles followed by a rapid fade. A significant improvement in cycling stability was achieved via Ketjen black coating of the cathode. A Li-ion full cell with Ketjen black modified LiFePO4 cathode and an unmodified Li4Ti5O12 anode exhibited negligible fade after more than 1200 cycles with a capacity of ~130mAh/g. The improved stability, along with its cost-effectiveness, environmentally benignity and safety, make the LiFePO4/ Li4Ti5O12 Li-ion battery a promising option of storing renewable energy.

Wang, Wei; Choi, Daiwon; Yang, Zhenguo

2013-01-01T23:59:59.000Z

434

Three-dimensional numerical investigation of electron transport with rotating spoke in a cylindrical anode layer Hall plasma accelerator  

Science Conference Proceedings (OSTI)

The effects of increased magnetic field and pressure on electron transport with a rotating spoke in a cylindrical anode layer Hall plasma accelerator are investigated by three-dimensional particle-in-cell numerical simulation. The azimuthal rotation of electron transport with the spoke has a frequency of 12.5 MHz. It propagates in the direction of the E Multiplication-Sign B drift at a speed of {approx}1.0 Multiplication-Sign 10{sup 6} m/s (about 37% of the E Multiplication-Sign B drift speed). Local charge separation occurs because the azimuthal local electron density concentration is accompanied by an almost uniform azimuthal ion distribution. The non-axisymmetrical electron density concentration and axisymmetrical ion distribution introduce two azimuthal electric fields with opposite directions in the plasma discharge region. The axial electron shear flow is excited under the additional E{sub {theta}} Multiplication-Sign B field. The anomalous electron transport with the rotating spoke may be attributed to the axial electron shear flow induced by the two azimuthal electric fields with opposite directions as a result of the azimuthal local electron density concentration.

Tang, D. L.; Geng, S. F.; Qiu, X. M. [Southwestern Institute of Physics, Chengdu 610041 (China); Chu, Paul K. [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong)

2012-07-15T23:59:59.000Z

435

Performance of Anode-Supported Solid Oxide Fuel Cell with Thin Bi-Layer Electrolyte by Pulsed Laser Deposition  

Science Conference Proceedings (OSTI)

Anode-supported yttria stabilized zirconia (YSZ)/samaria doped ceria (SDC) bi-layer electrolytes with uniform thickness and high density were fabricated by pulsed laser deposition at 1000 degrees C. Fuel cells with such bi-layer electrolytes were fabricated and tested, yielding open circuit voltages from 0.94 to 1.0 V at 600-700 degrees C. Power densities from 0.4 to 1.0 W cm{sup -2} at 0.7 V were achieved in air at temperatures of 600-700 degrees C. Cell performance was improved in flowing oxygen, with an estimated peak power density of over 2 W cm{sup -2} at 650 degrees C, assuming the same overall resistance over the entire range of current density. The high cell performance was attributed to the very low ohmic resistance of the fuel cell, owing to the small thickness of the electrolyte. Stable performance was also demonstrated in that the voltage of the fuel cell showed very little change at a constant current density of 1 A cm{sup -2} during more than 400 hours of operation at 650 degrees C in flowing oxygen. SEM analysis of the fuel cell after testing showed that the bi-layer electrolyte had retained its chemical and mechanical integrity.

Lu, Zigui; Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.; Fisher, Daniel; Wu, Naijuan; Ignatiev, Alex

2012-07-15T23:59:59.000Z

436

Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries  

SciTech Connect

The commercial Li4Ti5O12 (LTO) is successfully modified by AlF3 via a low temperature process. After being calcined at 400oC for 5 hours, AlF3 reacts with LTO to form a composite material which mainly consists of Al3+ and F- co-doped LTO with small amounts of anatase TiO2 and Li3AlF6. Al3+ and F- co-doped LTO demonstrates largely improved rate capability comparing to the pristine LTO. Since the amount of the byproduct TiO2 is relatively small, the modified LTO electrodes retain the main voltage characteristics of LTO with a minor feature similar to those of anatase TiO2. The doped LTO anodes deliver higher discharge capacity and significantly improved high-rate performance when compared to the pristine LTO anode. They also demonstrate excellent long-term cycling stability at elevated temperatures. Therefore, Al3+ and F- co-doped LTO synthesized at low temperature is an excellent anode for stable and ultra-high power lithium-ion batteries.

Xu, Wu; Chen, Xilin; Wang, Wei; Choi, Daiwon; Ding, Fei; Zheng, Jianming; Nie, Zimin; Choi, Young Joon; Zhang, Jiguang; Yang, Zhenguo

2013-08-15T23:59:59.000Z

437

Thermodynamic analysis of interactions between Ni-based solid oxide fuel cells (SOFC) anodes and trace species in a survey of coal syngas  

Science Conference Proceedings (OSTI)

A thermodynamic analysis was conducted to characterize the effects of trace contaminants in syngas derived from coal gasification on solid oxide fuel cell (SOFC) anode material. The effluents from 15 different gasification facilities were considered to assess the impact of fuel composition on anode susceptibility to contamination. For each syngas case, the study considers the magnitude of contaminant exposure resulting from operation of a warm gas cleanup unit at two different temperatures and operation of a nickel-based SOFC at three different temperatures. Contaminant elements arsenic (As), phosphorous (P), and antimony (Sb) are predicted to be present in warm gas cleanup effluent and will interact with the nickel (Ni) components of a SOFC anode. Phosphorous is the trace element found in the largest concentration of the three contaminants and is potentially the most detrimental. Poisoning was found to depend on the composition of the syngas as well as system operating conditions. Results for all trace elements tended to show invariance with cleanup operating temperature, but results were sensitive to syngas bulk composition. Synthesis gas with high steam content tended to resist poisoning.

Andrew Martinez; Kirk Gerdes; Randall Gemmen; James Postona

2010-03-20T23:59:59.000Z

438

How to Apply for an SES Position | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

How to Apply for an SES Position How to Apply for an SES Position How to Apply for an SES Position The Senior Executive Service (SES) is an elite group of men and women meeting the highest professional standards who administer public programs at the top levels of the Federal government. SES employees' salaries are linked directly to individual performance. The U.S. Office of Personnel Management's (OPM) SES web page contains a host of information that may be benefical to you. To apply for current SES positions within the Federal Government, including the Department of Energy please visit the Office of Personnel Management's USAJOBS site. From this site, you may view, download and apply for vacancies of interest to you. DOE does not accept unsolicited resumes. You must apply to a specific

439

Apply for Our Jobs | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Apply for Our Jobs | National Nuclear Security Administration Apply for Our Jobs | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog The National Nuclear Security Administration Apply for Our Jobs Home > Federal Employment > Apply for Our Jobs Apply for Our Jobs Whether you're a student seeking to learn more about a future career, just starting out, at mid-career or an experienced executive, NNSA may have the

440

Apply for Our Jobs | National Nuclear Security Administration  

NLE Websites -- All DOE Office Websites (Extended Search)

Apply for Our Jobs | National Nuclear Security Administration Apply for Our Jobs | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog The National Nuclear Security Administration Apply for Our Jobs Home > Federal Employment > Apply for Our Jobs Apply for Our Jobs Whether you're a student seeking to learn more about a future career, just starting out, at mid-career or an experienced executive, NNSA may have the

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Challenges in Applying Diamond Coatings to Carbide Twist Drills  

Science Conference Proceedings (OSTI)

Despite of the attractive advantage of applying diamond coating to drills, ... Investigation of a Hybrid Cutting Tool Design for Shearing Operations of Sheet Metals.

442

NREL: Technology Transfer - Apply Now for Energy-Efficient Housing ...  

Apply Now for Energy-Efficient Housing ... and NREL's Residential Buildings Research Web site to learn about systems integration and energy analysis ...

443

1 SCRA Applied Research & Development offers the following ...  

Science Conference Proceedings (OSTI)

... and the rapid transition of results into US ... the Way (PLTW); National Science Foundation initiatives ... 6 SCRA Applied R&D 5300 International Blvd N ...

2012-10-26T23:59:59.000Z

444

Applied Process Engineering Laborotory APEL | Open Energy Information  

Open Energy Info (EERE)

Engineering Laborotory APEL Jump to: navigation, search Name Applied Process Engineering Laborotory (APEL) Place United States Sector Services Product General Financial & Legal...

445

Applied Mathematics and Plasma Physics, T-5: Theoretical, T:...  

NLE Websites -- All DOE Office Websites (Extended Search)

Pieter Swart Deputy Group Leader Kim Rasmussen Administration Charlotte Lehman Office Location TA-3, Bldg 508, Rm 204 Applied Mathematics and Plasma Physics, T-5 The group...

446

Mark Linne Dept. Applied Mechanics, Chalmers University, Gothenburg...  

NLE Websites -- All DOE Office Websites (Extended Search)

Optical and X-ray Measurements for Fuel Sprays Mark Linne Dept. Applied Mechanics, Chalmers University, Gothenburg, 41296, Sweden This talk will describe measurement needs across...

447

An improved Benders decomposition applied to a multi-layer ...  

E-Print Network (OSTI)

GLOBECOM 2007, Washington DC, USA, December 2007. [8] A. M. Costa, A survey on benders decomposition applied to fixed-charge network design...

448

Infrared Imagery Applied to A Large Buoyant Plume  

Science Conference Proceedings (OSTI)

The possibility of applying infrared imagery to the study of a large, hot plume materialized by carbon particles resulting from the incomplete combustion of fuel oil is investigated.

J-M. Brustet; B. Benech; P. Waldteufel

1981-05-01T23:59:59.000Z

449

Steel Research Applied to National Needs - A Company Perspective  

Science Conference Proceedings (OSTI)

Symposium, Materials Research Applied to National Needs (MARANN) in Honor of ... food packaging, transportation (auto, rail, and air), etc, to name just a few.

450

Geothermal: Sponsored by OSTI -- Extracting and Applying SV-SV...  

Office of Scientific and Technical Information (OSTI)

Extracting and Applying SV-SV Shear Modes from Vertical Vibrator Data Across Geothermal Prospects Final Report Geothermal Technologies Legacy Collection HelpFAQ | Site Map |...

451

Lagrangean Duality Applied on Vehicle Routing with Time Windows  

E-Print Network (OSTI)

Nov 6, 2001 ... Lagrangean Duality Applied on Vehicle Routing with Time Windows ... with the Vehicle Routing Problem with Time Windows (VRPTW).

452

Los Alamos Lab: International and Applied Technology Division...  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Electromagnetics, IAT-2 IAT-2 is a broad spectrum electromagnetics applications organization whose research and development activities address the Global Security...

453

How to Apply for NIST, Department of Commerce, and Other ...  

Science Conference Proceedings (OSTI)

... Search for Job Vacancies: Vacancy announcements contain important information that applicants need to know to apply for a specific job opening ...

2013-08-09T23:59:59.000Z

454

Modular Systems Biology applied to TGFbeta and DNA Damage Response...  

NLE Websites -- All DOE Office Websites (Extended Search)

Modular Systems Biology applied to TGFbeta and DNA Damage Response Signaling following Low Dose Radiation Francis Cucinotta NASA Johnson Space Center Abstract Modular systems...

455

urbino worldwide campus applied computer scienceComputer Architecture  

E-Print Network (OSTI)

urbino worldwide campus applied computer scienceComputer Architecture alessandro bogliolo isti information science and technology institute 1/16 05.03 Pipeline hazards 05 CPU 05.03 Pipeline hazards;urbino worldwide campus applied computer scienceComputer Architecture alessandro bogliolo isti

Bogliolo, Alessandro

456

Applying to EPA for Approval of Other Uses of Phosphogypsum  

E-Print Network (OSTI)

Applying to EPA for Approval of Other Uses of Phosphogypsum: Preparing and Submitting a Complete. EP-D-04-007, Work Assignment 0-2 December 2005 #12;ii Applying for Other Uses of Phosphogypsum phosphogypsum in stacks? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.4. What

457

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

21 - 8230 of 26,764 results. 21 - 8230 of 26,764 results. Download CX-001227: Categorical Exclusion Determination Replacement of Big Hill Deep Anode Ground Bed Site for Cavern 114 CX(s) Applied: B1.3 Date: 03/16/2010 Location(s): Big Hill, Texas Office(s): Fossil Energy, Strategic Petroleum Reserve Field Office http://energy.gov/nepa/downloads/cx-001227-categorical-exclusion-determination Download CX-001002: Categorical Exclusion Determination Replace Bryan Mound Oil/Water Separators CX(s) Applied: B1.3 Date: 03/01/2010 Location(s): Bryan Mound, Texas Office(s): Fossil Energy, Strategic Petroleum Reserve Field Office http://energy.gov/nepa/downloads/cx-001002-categorical-exclusion-determination Download CX-001003: Categorical Exclusion Determination West Hackberry Tank (WHT)-1 and WHT-10 Liner Removal/Reline

458

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

81 - 5590 of 8,172 results. 81 - 5590 of 8,172 results. Download CX-006753: Categorical Exclusion Determination Coupled High Capacity Silicon Anode and Novel Cathode Cells for Automotive Applications CX(s) Applied: B5.1 Date: 09/13/2011 Location(s): Maplewood, Minnesota Office(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-006753-categorical-exclusion-determination-0 Download CX-006754: Categorical Exclusion Determination Theory, Investigation and Stability of Cathode Electrocatalytic Activity CX(s) Applied: B3.6 Date: 09/13/2011 Location(s): Atlanta, Georgia Office(s): Fossil Energy, National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-006754-categorical-exclusion-determination Download CX-006755: Categorical Exclusion Determination

459

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

01 - 7310 of 26,764 results. 01 - 7310 of 26,764 results. Download CX-008348: Categorical Exclusion Determination Replace Big Hill Raw Water Intake System Oil Water Separator Tank with Concrete Tank CX(s) Applied: B1.3 Date: 04/16/2012 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office http://energy.gov/nepa/downloads/cx-008348-categorical-exclusion-determination Download CX-008349: Categorical Exclusion Determination Replacement Anode Bed on West Hackberry 42-inch Crude Oil Pipeline at Gum Cove Road CX(s) Applied: B1.3 Date: 04/10/2012 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office http://energy.gov/nepa/downloads/cx-008349-categorical-exclusion-determination Download CX-008350: Categorical Exclusion Determination Re-work Bryan Mound 30" Crude Oil Pipeline Mainline Valves

460

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

81 - 7490 of 28,905 results. 81 - 7490 of 28,905 results. Download CX-006995: Categorical Exclusion Determination Development of Cost-Competitive Advanced Thermoelectric Generators for Direct Conversion of Vehicle CX(s) Applied: B3.6 Date: 09/22/2011 Location(s): Canada and Singapore, Other Location, Indiana, Michigan, Nevada, Texas Office(s): Energy Efficiency and Renewable Energy http://energy.gov/nepa/downloads/cx-006995-categorical-exclusion-determination Download CX-006909: Categorical Exclusion Determination Low-Cost Manufacturing of High-Capacity Prismatic Lithium-Ion Cell Alloy Anodes CX(s) Applied: B3.6 Date: 09/29/2011 Location(s): California, Michigan, North Carolina, Tennesee Office(s): Energy Efficiency and Renewable Energy http://energy.gov/nepa/downloads/cx-006909-categorical-exclusion-determination

Note: This page contains sample records for the topic "anode cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Applied Mathematics | U.S. DOE Office of Science (SC)  

Office of Science (SC) Website

Applied Applied Mathematics Advanced Scientific Computing Research (ASCR) ASCR Home About Research Applied Mathematics Applied Mathematics Conferences And Workshops Computer Science Next Generation Networking Scientific Discovery through Advanced Computing (SciDAC) Computational Science Graduate Fellowship (CSGF) ASCR SBIR-STTR Facilities Science Highlights Benefits of ASCR Funding Opportunities Advanced Scientific Computing Advisory Committee (ASCAC) News & Resources Contact Information Advanced Scientific Computing Research U.S. Department of Energy SC-21/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-7486 F: (301) 903-4846 E: sc.ascr@science.doe.gov More Information » Research Applied Mathematics Print Text Size: A A A RSS Feeds FeedbackShare Page

462

Remediation of Mercury and Industrial Contaminants Applied Field Research  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Remediation of Mercury and Industrial Contaminants Applied Field Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative (RoMIC-AFRI) Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative (RoMIC-AFRI) Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative (RoMIC-AFRI) Located on the Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee, the RoMIC-AFRI was established to protect water resources by addressing the challenge of preventing contamination. The initiative at Oak Ridge is a collaborative effort that leverages DOE investments in basic science and applied research and the work of site contractors to address the complex challenges in the remediation of legacy waste at the Oak Ridge Reservation. The mission of the Remediation of Mercury and Industrial Contaminants

463

Applied Materials Switzerland SA Formerly HCT Shaping Systems SA | Open  

Open Energy Info (EERE)

Switzerland SA Formerly HCT Shaping Systems SA Switzerland SA Formerly HCT Shaping Systems SA Jump to: navigation, search Name Applied Materials Switzerland SA (Formerly HCT Shaping Systems SA) Place Chezeaux, Switzerland Zip 1033 Product Manufacturer of wire saws for the semiconductor and photovoltaic wafer slicing industries. References Applied Materials Switzerland SA (Formerly HCT Shaping Systems SA)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Applied Materials Switzerland SA (Formerly HCT Shaping Systems SA) is a company located in Chezeaux, Switzerland . References ↑ "[ Applied Materials Switzerland SA (Formerly HCT Shaping Systems SA)]" Retrieved from "http://en.openei.org/w/index.php?title=Applied_Materials_Switzerland_SA_Formerly_HCT_Shaping_Systems_SA&oldid=342245"

464

A High Temperature (400 to 650oC) Secondary Storage Battery Based on Liquid Sodium and Potassium Anodes  

DOE Green Energy (OSTI)

This STTR Phase I research program was on the development of high temperature (400 to 650 C), secondary batteries with roundtrip efficiency > 90% for integration with a 3 to 10 kW solid oxide fuel cell (SOFC) system. In fulfillment of this objective, advanced planar high temperature rechargeable batteries, comprised of an alkali metal ion conducting, highly refractory, beta'' alumina solid electrolyte (BASE) sandwiched between liquid sodium (or potassium) anode and liquid metal salt cathode, were developed at MSRI. The batteries have been successfully demonstrated at a working temperature as high as 600 C. To our knowledge, so far no work has been reported in the literature on planar rechargeable batteries based on BASE, and results obtained in Phase I for the very first time demonstrated the viability of planar batteries, though relatively low temperature tubular-based sodium-sulfur batteries and ZEBRA batteries have been actively developed by very limited non U.S. companies. The results of this Phase I work have fulfilled all the goals and stated objectives, and the achievements showed much promise for further, substantial improvements in battery design and performance. The important results of Phase I are briefly described in what follows: (1) Both Na-BASE and K-BASE discs and tubes have been successfully fabricated using MSRI's patented vapor phase process. Ionic conductivity measurements showed that Na-BASE had higher ionic conductivity than K-BASE, consistence with the literature. At 500 C, Na-BASE conductivity is 0.36 S/cm, which is more than 20 times higher than 8YSZ electrolyte used for SOFC at 800 C. The activation energy is 22.58 kJ/mol. (2) CuCl{sub 2}, FeCl{sub 2}, ZnCl{sub 2}, and AgCl were identified as suitable salts for Na/metal salt or K/metal salt electrochemical couples based on thermochemical data. Further open circuit voltage measurements matched those deduced from the thermochemical data. (3) Tubular cells with CuCl{sub 2} as the cathode and Na as the anode were constructed. However, it was discovered that CuCl{sub 2} was somewhat corrosive and dissolved iron, an element of the cathode compartment. Since protective coating technology was beyond this Phase I work scope, no further work on the CuCl{sub 2} cathode was pursued in Phase I. Notwithstanding, due to its very high OCV and high specific energy, CuCl{sub 2} cathode is a very attractive possibility for a battery capable of delivering higher specific energy with higher voltage. Further investigation of the Na-CuCl{sub 2} battery can be done by using suitable metal coating technologies developed at MSRI for high temperature applications. (4) In Phase I, FeCl{sub 2} and ZnCl{sub 2} were finalized as the potential cathodes for Na-metal salt batteries for delivering high specific energies. Planar Na-FeCl{sub 2} and Na-ZnCl{sub 2} cells were designed, constructed, and tested between 350 and 600 C. Investigation of charge/discharge characteristics showed they were the most promising batteries. Charge/discharge cycles were performed as many as 27 times, and charge/discharge current was as high as 500 mA. No failure was detected after 50 hours testing. (5) Three-cell planar stacks were designed, constructed, and evaluated. Preliminary tests showed further investigation was needed for optimization. (6) Freeze-thaw survival was remarkably good for planar BASE discs fabricated by MSRI's patented vapor phase process.

Tao, Greg; Weber, Neill

2007-06-08T23:59:59.000Z

465

Electrochemical studies of Mg-doped Li{sub 4}Ti{sub 5}O{sub 12} anodes.  

DOE Green Energy (OSTI)

Commercial lithium-ion batteries use carbon as the material of choice for the anode. However, because lithiated carbon has a voltage very close to the potential of metallic lithium, there are concerns about the safety of fully-charged carbon electrodes. The safety issue can be addressed by using a material that intercalates lithium at a higher voltage. A promising material is the lithium-titanium-oxide spinel material Li{sub 4}Ti{sub 5}O{sub 12} which can accommodate 3 Li{sup +} ions per formula unit (corresponding to 175 mAh/g) in a two-phase reaction at approximately 1.5 V versus lithium. One of the drawbacks of this system is that the end-member Li{sub 4}Ti{sub 5}O{sub 12} is electronically insulating, which limits electron transfer at the electrode surface. By doping this material with magnesium, Li{sub 4{minus}x}Mg{sub x}Ti{sub 5}O{sub 12}, we introduced mixed-valent Ti{sup 4+}/Ti{sup 3+} into the stoichiometric spinel structure and thereby increased the electronic conductivity by several orders of magnitude without sacrificing electrochemical performance. In this presentation we will provide data on the extent of the solid solution in Li{sub 4{minus}x}Mg{sub x}Ti{sub 5}O{sub 12}, the variation of electronic conductivity as a function of dopant concentration and the rate capability of the doped material.

Chen, C. H.; Jansen, A. N.; Vaughey, J.

1999-07-19T23:59:59.000Z

466

How to Apply for Senior Executive positions | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

How to Apply for Senior Executive positions How to Apply for Senior Executive positions How to Apply for Senior Executive positions To apply vacancies for SENIOR EXECUTIVE SERVICE (SES) , SENIOR LEVEL (SL), SCIENTIFIC AND PROFESSIONAL (ST) positions within the Department of Energy please visit OPM's website: http://www.usajobs.gov. From this site, you may download announcements for vacancies of interest to you. SENIOR EXECUTIVE SERVICE (SES) The Guide to Senior Executive Service Qualifications provides detailed information about executive qualifications and tips for writing effective qualification statements. What Are Executive Core Qualifications (ECQs) The Executive Core Qualifications (ECQs) define the competencies needed to build a federal corporate culture that drives for results, serves customers, and builds successful teams and coalitions within and outside

467

Energy Efficiency in Buildings in Switzerland - Applied Research...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency in Buildings in Switzerland - Applied Research on Vacuum Insulation, Passive Houses etc. Speaker(s): Armin Binz Date: January 21, 2003 - 12:00pm Location: Bldg....

468

Electrical capacitance volume tomography (ECVT) applied to bubbling fluid beds  

SciTech Connect

These presentation visuals illustrate the apparatus and method for applying Electrical Capacitance Volume Tomography (ECVT) to bubbling fluid beds to their solid fraction and bubble properties. Results are compared to estimated values.

Weber, J., Mei, J.

2012-01-01T23:59:59.000Z

469

A Stereo Photogrammetric Technique Applied to Orographic Convection  

Science Conference Proceedings (OSTI)

This paper describes a technique for photogrammetric analysis of stereo pairs of images that is applied to the study of orographic convection. The technique is designed for use with digital images and assumes detailed knowledge of the camera ...

Joseph A. Zehnder; Jiuxiang Hu; Anshuman Razdan

2007-06-01T23:59:59.000Z

470

Proceedings of the 2008 ACM symposium on Applied computing  

Science Conference Proceedings (OSTI)

Welcome to the 23rd Annual ACM Symposium on Applied Computing (SAC 2008). This international event is dedicated to computer scientists, engineers, and practitioners seeking innovative ideas in various areas of computer applications. This year, the conference ...

Roger L. Wainwright; Hisham M. Haddad

2008-03-01T23:59:59.000Z

471

DOE Solar Decathlon: How to Apply for the Solar Decathlon  

NLE Websites -- All DOE Office Websites (Extended Search)

Photos Videos Education Sponsors Volunteers History FAQs Contacts How To Apply for the Solar Decathlon Is your school interested in participating in the next U.S. Department of...

472

NEW MOTOR DESIGN CONCEPT FOR ENERGY SAVING APPLIED TO  

E-Print Network (OSTI)

SHARK, NEW MOTOR DESIGN CONCEPT FOR ENERGY SAVING APPLIED TO SWITCHED RELUCTANCE MOTOR by Ana of the cylindrical and Shark air gap Switched Reluctance Motors and their assistance during the experimental work with other motor technologies such

473

Los Alamos Lab: International and Applied Technology Division...  

NLE Websites -- All DOE Office Websites (Extended Search)

International Research and Analysis, IAT-1 IAT-1 has one of the most diverse work forces in the division. By applying its scientific and engineering skills to designated problems,...

474

Proceedings of the 2009 ACM symposium on Applied Computing  

Science Conference Proceedings (OSTI)

On behalf of the Organizing Committee, we welcome you to the 24th Annual ACM Symposium on Applied Computing (SAC 2009) hosted by Chaminade University in Hawaii. This international forum has been dedicated to computer scientists, engineers and practitioners ...

Sung Y. Shin; Sascha Ossowski

2009-03-01T23:59:59.000Z

475

18.337J / 6.338J Applied Parallel Computing (SMA 5505), Spring 2005  

E-Print Network (OSTI)

Applied Parallel Computing is an advanced interdisciplinary introduction to applied parallel computing on modern supercomputers.

Edelman, Alan

476

Ab initio Molecular Dynamics Simulations of the Initial Stages of Solid-electrolyte Interphase Formation on Lithium Ion Battery Graphitic Anodes  

E-Print Network (OSTI)

The decomposition of ethylene carbonate (EC) during the initial growth of solid-electrolyte interphase (SEI) films at the solvent-graphitic anode interface is critical to lithium ion battery operations. Ab initio molecular dynamics simulations of explicit liquid EC/graphite interfaces are conducted to study these electrochemical reactions. We show that carbon edge terminations are crucial at this stage, and that achievable experimental conditions can lead to surprisingly fast EC breakdown mechanisms, yielding decomposition products seen in experiments but not previously predicted.

Leung, Kevin; 10.1039/B925853A

2010-01-01T23:59:59.000Z

477

Predictions of particle size and lattice diffusion pathway requirements for sodium-ion anodes using eta-Cu6Sn5 thin films as a model system  

SciTech Connect

Geometrically well-defined Cu6Sn5 thin films were used as model systems to estimate the diffusion depth and diffusion pathway requirements of Li and Na ions in alloy anodes. eta-Cu6Sn5 anodes have an initial reversible capacity towards Li of 545 mAh g-1 (Li3.96Sn or 19.8 Li/Cu6Sn5) and a very low initial irreversible capacity of 1.6 Li/Cu6Sn5. In contrast, the reaction with Na is limited with a reversible capacity of 160 mAh g-1 compared to the expected 516 mAh g-1. The potential profile is analogous to that of pure Sn with an average potential of 0.3 V. X-ray diffraction and 119Sn-M ssbauer measurements show that this limited capacity is likely resulting from the limited diffusion of Na into the anode particles not the formation of a low Na-content phase. This is substantiated by the analysis of the structure of eta-Cu6Sn5 which revealed zig-zag and tunnel diffusion pathways with spherical voids with a diameter very close to that of Na+. Moreover, our results also indicate that an alloy of eta-Cu6Sn5 should have optimized particle sizes of about 10 nm in diameter to increase the Na-capacity significantly. An alternative system consisting of a mixture of Cu6Sn5 and Sn of nominal composition Cu6Sn10 has been studied as possible Na-ion anode material possessing higher storage capacity than pure Cu6Sn5. Indeed this mixture of phase delivers a larger initial reversible storage capacity up to 400 mAh g-1. Finally, we have evidenced that the presence of Cu in Cu6Sn5 and in Cu6Sn10 suppresses the anomalous electrolyte decomposition normally measured for pure Sn at 1.2 V during discharge.

Baggetto, Loic [ORNL; Jumas, Dr. Jean-Claude [Institut Charles Gerhardt, University of Montpellier II, FRANCE; Gorka, Joanna [ORNL; Bridges, Craig A [ORNL; Veith, Gabriel M [ORNL

2013-01-01T23:59:59.000Z

478

Anodes for Batteries  

SciTech Connect

The purpose of this chapter is to discuss, "constructive corrosion" as it occurs in power generated devices, specifically batteries.

Windisch, Charles F.

2003-01-01T23:59:59.000Z

479

Nanotube Composite Anode Materials  

Increased battery capacity, safety, ... Electric and plug-in hybrid electric vehicles; Portable electronic devices; Medical devices; and

480

Anode Green Mill  

Science Conference Proceedings (OSTI)

February 17, 2010. Room: 616. Location: Washington State Convention Center Session Chair: Lorentz Petter Lossius, Hydro Aluminium AS...

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481

Anode Effect, Process Control  

Science Conference Proceedings (OSTI)

Mar 13, 2012... concentration demonstrating both increased current efficiency (CE) and decreased kWh/kg compared to presently employed methodologies.

482

How to Apply the ENERGY STAR Certified Building Decal  

NLE Websites -- All DOE Office Websites (Extended Search)

How to Apply the ENERGY STAR How to Apply the ENERGY STAR Certified Building Decal Page Cyan-and-White Decal Instructions Application Instructions 2 How to Make a Glass Plaque 4 Cyan-and-White Paper Templates 5 "Etched-Look" Decal Instructions Application Instructions 7 How to Make a Glass Plaque 9 "Etched-Look" Paper Templates 10 How to Apply the ENERGY STAR Cyan and White Certified Building Decal What's in this package: Two sets of: ENERGY STAR logo decal 1. "Certified Building" lettering decal, with thick white paper on 2. one side and thin, semi-translucent paper on the other side. Paper templates of logo and lettering What you'll need: Level 1. Masking tape 2. Rubbing alcohol and a clean, soft cloth 3. Drivers license, credit card, or other rigid

483

How to Apply for Weatherization Assistance | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

How to Apply for Weatherization Assistance How to Apply for Weatherization Assistance How to Apply for Weatherization Assistance March 24, 2009 - 12:45pm Addthis Elizabeth Spencer Communicator, National Renewable Energy Laboratory A few weeks ago, the U.S. Department of Energy announced that it was investing $8 billion into weatherization and state energy grants-$5 billion of which is going directly to the Weatherization Assistance Program. And why is that interesting? Well, the Weatherization Assistance Program provides low-income families with free-of-charge, energy efficient upgrades to their homes. A more efficient home means that you pay less every month on your energy bills-and while that's the kind of upgrade anyone can benefit from, this program helps those who need those extra dollars the

484

Modular Applied General Equilibrium Tool (MAGNET) | Open Energy Information  

Open Energy Info (EERE)

Modular Applied General Equilibrium Tool (MAGNET) Modular Applied General Equilibrium Tool (MAGNET) Jump to: navigation, search Tool Summary Name: Modular Applied General Equilibrium Tool (MAGNET) Agency/Company /Organization: LEI Wageningen UR, the Netherlands Complexity/Ease of Use: Moderate Related Tools Ex Ante Appraisal Carbon-Balance Tool (EX-ACT) Climate Rapid Overview and Decision Support (C-ROADS) Simulator Partnership for Economic Policy Modeling and Policy Impact Analysis (MPIA) ... further results Find Another Tool FIND DEVELOPMENT IMPACTS ASSESSMENT TOOLS A modular global computable general equilibrium model that covers the whole economy and has been used extensively in agricultural, environmental, and trade policy analysis; builds on the GTAP model, and is the successor of LEITAP. Approach MAGNET is based on the Global Trade Analysis Project (GTAP) model and

485

Overview Of Electromagnetic Methods Applied In Active Volcanic Areas Of  

Open Energy Info (EERE)

Of Electromagnetic Methods Applied In Active Volcanic Areas Of Of Electromagnetic Methods Applied In Active Volcanic Areas Of Western United States Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Overview Of Electromagnetic Methods Applied In Active Volcanic Areas Of Western United States Details Activities (7) Areas (2) Regions (0) Abstract: A better understanding of active volcanic areas in the United States through electromagnetic geophysical studies received foundation from the many surveys done for geothermal exploration in the 1970's. Investigations by governmental, industrial, and academic agencies include (but are not limited to) mapping of the Cascades. Long Valley/Mono area, the Jemez volcanic field, Yellowstone Park, and an area in Colorado. For one example - Mt. Konocti in the Mayacamas Mountains, California - gravity,

486

Remote Gas Well Monitoring Technology Applied to Marcellus Shale Site |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Remote Gas Well Monitoring Technology Applied to Marcellus Shale Remote Gas Well Monitoring Technology Applied to Marcellus Shale Site Remote Gas Well Monitoring Technology Applied to Marcellus Shale Site February 10, 2012 - 12:00pm Addthis Washington, DC - A technology to remotely monitor conditions at energy-rich Marcellus Shale gas wells to help insure compliance with environmental requirements has been developed through a research partnership funded by the U.S. Department of Energy (DOE). NETL-RUA researcher Dr. Michael McCawley hasdeveloped a technology to remotely monitor theenvironment around energy-rich Marcellus Shale gas wells. Photo courtesy of West Virginia University.The technology - which involves three wireless monitoring modules to measure volatile organic compounds, dust, light and sound - is currently being tested at a Marcellus

487

Geobotanical Remote Sensing Applied To Targeting New Geothermal Resource  

Open Energy Info (EERE)

Geobotanical Remote Sensing Applied To Targeting New Geothermal Resource Geobotanical Remote Sensing Applied To Targeting New Geothermal Resource Locations In The Us Basin And Range With A Focus On Dixie Meadows, Nv Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Geobotanical Remote Sensing Applied To Targeting New Geothermal Resource Locations In The Us Basin And Range With A Focus On Dixie Meadows, Nv Details Activities (1) Areas (1) Regions (0) Abstract: This paper presents an overview of the work our collaboration is doing to increase the detailed mapped resource base for geothermal exploration in the Western US. We are imaging several large areas in the western US with high resolution airborne hyperspectral and satellite multispectral sensors. We have now entered the phase where the remote sensing techniques and tools we are developing are mature enough to be

488

Guidance for Federal Departments and Agencies on Establishing, Applying,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Guidance for Federal Departments and Agencies on Establishing, Guidance for Federal Departments and Agencies on Establishing, Applying, and Revising Categorical Exclusions Under the National Environmental Policy Act Guidance for Federal Departments and Agencies on Establishing, Applying, and Revising Categorical Exclusions Under the National Environmental Policy Act This guidance from the Council on Environmental Quality provides methods for substantiating categorical exclusions, clarifies the process for establishing categorical exclusions, outlines how agencies should engage the public when establishing and using categorical exclusions, describes how agencies can document the use of categorical exclusions, and recommends periodic agency review of existing categorical exclusions. Final Guidance for Federal Departments and Agencies on Establishing,

489

Guidance for Federal Departments and Agencies on Establishing, Applying,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

for Federal Departments and Agencies on Establishing, for Federal Departments and Agencies on Establishing, Applying, and Revising Categorical Exclusions Under the National Environmental Policy Act Guidance for Federal Departments and Agencies on Establishing, Applying, and Revising Categorical Exclusions Under the National Environmental Policy Act This guidance from the Council on Environmental Quality provides methods for substantiating categorical exclusions, clarifies the process for establishing categorical exclusions, outlines how agencies should engage the public when establishing and using categorical exclusions, describes how agencies can document the use of categorical exclusions, and recommends periodic agency review of existing categorical exclusions. Final Guidance for Federal Departments and Agencies on Establishing,

490

Process for applying control variables having fractal structures  

DOE Patents (OSTI)

A process and apparatus for the application of a control variable having a fractal structure to a body or process. The process of the present invention comprises the steps of generating a control variable having a fractal structure and applying the control variable to a body or process reacting in accordance with the control variable. The process is applicable to electroforming where first, second and successive pulsed-currents are applied to cause the deposition of material onto a substrate, such that the first pulsed-current, the second pulsed-current, and successive pulsed currents form a fractal pulsed-current waveform.

Bullock, IV, Jonathan S. (Oak Ridge, TN); Lawson, Roger L. (Oliver Springs, TN)

1996-01-01T23:59:59.000Z