Sample records for annual fossil-fuel co2

  1. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    E-Print Network [OSTI]

    Gurney, Kevin R.

    2010-01-01T23:59:59.000Z

    interannual variations in fossil fuel emissions. J. Geophys.Treat CO 2 from fossil fuel burning: global distribution ofdioxide emissions from fossil fuel consumption and cement

  2. Regional patterns of radiocarbon and fossil fuel-derived CO 2 in surface air across North America

    E-Print Network [OSTI]

    Hsueh, Diana Y; Krakauer, Nir Y; Randerson, James T; Xu, Xiaomei; Trumbore, Susan E; Southon, John R

    2007-01-01T23:59:59.000Z

    dioxide emissions from fossil fuel consumption and cementindependent budgeting of fossil fuel CO 2 over Europe by COregional, and national fossil fuel CO 2 emissions, Carbon

  3. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    E-Print Network [OSTI]

    Gurney, Kevin R.

    2010-01-01T23:59:59.000Z

    resolution fossil fuel combustion CO 2 emission fluxes for2002, includes detail on combustion technology and forty-atmosphere is that due to the combustion of fossil fuels and

  4. Regional patterns of radiocarbon and fossil fuel-derived CO 2 in surface air across North America

    E-Print Network [OSTI]

    Hsueh, Diana Y; Krakauer, Nir Y; Randerson, James T; Xu, Xiaomei; Trumbore, Susan E; Southon, John R

    2007-01-01T23:59:59.000Z

    changes resulting from fossil-fuel CO 2 release and cosmic-for recently added fossil fuel CO 2 in the atmosphere anddioxide emissions from fossil fuel consumption and cement

  5. Seasonal and latitudinal variability of troposphere ?14CO2: Post bomb contributions from fossil fuels, oceans, the stratosphere, and the terrestrial biosphere

    E-Print Network [OSTI]

    Randerson, J. T; Enting, I. G; Schuur, E. A. G; Caldeira, K.; Fung, I. Y

    2002-01-01T23:59:59.000Z

    CO 2 Emissions From Fossil-Fuel Burning, Hydraulic Cementof seasonal variation in fossil fuel CO 2 emissions, Tellus,contributions from fossil fuels, oceans, the stratosphere,

  6. Wavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements

    E-Print Network [OSTI]

    Ray, Jaideep

    Wavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements J. Ray1, V: Develop a technique to estimate anthropogenic (fossil- fuel) CO2 emissions from sparse observations · Motivations: ­ An alternative to estimating ffCO2 emission using bottom-up (economic model) techniques

  7. Atmospheric O2//N2 changes, 19932002: Implications for the partitioning of fossil fuel CO2 sequestration

    E-Print Network [OSTI]

    Ho, David

    Atmospheric O2//N2 changes, 1993­­2002: Implications for the partitioning of fossil fuel CO2. Cassar (2005), Atmospheric O2/N2 changes, 1993­2002: Implications for the partitioning of fossil fuel CO2. The O2/N2 ratio of air is falling because combustion of fossil fuel and biomass both con- sume O2

  8. Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the United States

    SciTech Connect (OSTI)

    Zhou, Yuyu; Gurney, Kevin R.

    2011-07-01T23:59:59.000Z

    Quantification of the spatial distribution of sector-specific fossil fuel CO2 emissions provides strategic information to public and private decision-makers on climate change mitigation options and can provide critical constraints to carbon budget studies being performed at the national to urban scales. This study analyzes the spatial distribution and spatial drivers of total and sectoral fossil fuel CO2 emissions at the state and county levels in the United States. The spatial patterns of absolute versus per capita fossil fuel CO2 emissions differ substantially and these differences are sector-specific. Area-based sources such as those in the residential and commercial sectors are driven by a combination of population and surface temperature with per capita emissions largest in the northern latitudes and continental interior. Emission sources associated with large individual manufacturing or electricity producing facilities are heterogeneously distributed in both absolute and per capita metrics. The relationship between surface temperature and sectoral emissions suggests that the increased electricity consumption due to space cooling requirements under a warmer climate may outweigh the savings generated by lessened space heating. Spatial cluster analysis of fossil fuel CO2 emissions confirms that counties with high (low) CO2 emissions tend to be clustered close to other counties with high (low) CO2 emissions and some of the spatial clustering extends to multi-state spatial domains. This is particularly true for the residential and transportation sectors, suggesting that emissions mitigation policy might best be approached from the regional or multi-state perspective. Our findings underscore the potential for geographically focused, sector-specific emissions mitigation strategies and the importance of accurate spatial distribution of emitting sources when combined with atmospheric monitoring via aircraft, satellite and in situ measurements. Keywords: Fossil-fuel; Carbon dioxide emissions; Sectoral; Spatial cluster; Emissions mitigation policy

  9. Regional patterns of radiocarbon and fossil fuel-derived CO2 in surface air across North America

    E-Print Network [OSTI]

    Krakauer, Nir Y.

    Regional patterns of radiocarbon and fossil fuel-derived CO2 in surface air across North America-scale fossil fuel plumes in surface air. We collected corn (Zea mays) across North America during the summer-Maryland region showed a larger fossil fuel influence with a mean D14 C of 58.8% ± 3.9% and 55.2% ± 2

  10. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    Riley, W.J.

    2008-01-01T23:59:59.000Z

    of radiocarbon and fossil fuel-derived CO2 in surface air2004), Estimates of annual fossil-fuel CO 2 emitted for eachindependent budgeting of fossil fuel CO2 over Europe by (

  11. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    independent budgeting of fossil fuel CO 2 over Europe by (CO2008), Where do fossil fuel carbon dioxide emissions from2004), Estimates of annual fossil-fuel CO 2 emitted for each

  12. Quantification of fossil fuel CO2 emissions at the building/street scale for a large US city

    SciTech Connect (OSTI)

    Gurney, Kevin R.; Razlivanov, I.; Song, Yang; Zhou, Yuyu; Benes, Bedrich; Abdul- Massih, Michel

    2012-08-15T23:59:59.000Z

    In order to advance the scientific understanding of carbon exchange with the land surface, build an effective carbon monitoring system and contribute to quantitatively-based U.S. climate change policy interests, fine spatial and temporal quantification of fossil fuel CO2 emissions, the primary greenhouse gas, is essential. Called the Hestia Project, this research effort is the first to use bottom-up methods to quantify all fossil fuel CO2 emissions down to the scale of individual buildings, road segments, and industrial/electricity production facilities on an hourly basis for an entire urban landscape. a large city (Indianapolis, Indiana USA). Here, we describe the methods used to quantify the on-site fossil fuel CO2 emissions across the city of Indianapolis, Indiana. This effort combines a series of datasets and simulation tools such as a building energy simulation model, traffic data, power production reporting and local air pollution reporting. The system is general enough to be applied to any large U.S. city and holds tremendous potential as a key component of a carbon monitoring system in addition to enabling efficient greenhouse gas mitigation and planning. We compare our estimate of fossil fuel emissions from natural gas to consumption data provided by the local gas utility. At the zip code level, we achieve a bias adjusted pearson r correlation value of 0.92 (p<0.001).

  13. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14T23:59:59.000Z

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known signal-to-noise problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  14. CO2 emissions mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine V.; Wada, Kenichi; Van Vuuren, Detlef

    2015-01-01T23:59:59.000Z

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher and decrease with mitigation. A first deviation from the optimal transition pathway relaxes global emission targets until 2030, in accordance with the Copenhagen pledges and regionally-specific low-carbon technology targets. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger - twice and more - than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear cut across models, as we find carbon leakage effects ranging from positive to negative because leakage and substitution patterns of coal, oil, and gas differ. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  15. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    SciTech Connect (OSTI)

    Gurney, Kevin R.; Mendoza, Daniel L.; Zhou, Yuyu; Fischer, Marc L.; Miller, Chris C.; Geethakumar, Sarath; de la Rue du Can, Stephane

    2009-03-19T23:59:59.000Z

    Quantification of fossil fuel CO{sub 2} emissions at fine space and time resolution is emerging as a critical need in carbon cycle and climate change research. As atmospheric CO{sub 2} measurements expand with the advent of a dedicated remote sensing platform and denser in situ measurements, the ability to close the carbon budget at spatial scales of {approx}100 km{sup 2} and daily time scales requires fossil fuel CO{sub 2} inventories at commensurate resolution. Additionally, the growing interest in U.S. climate change policy measures are best served by emissions that are tied to the driving processes in space and time. Here we introduce a high resolution data product (the 'Vulcan' inventory: www.purdue.edu/eas/carbon/vulcan/) that has quantified fossil fuel CO{sub 2} emissions for the contiguous U.S. at spatial scales less than 100 km{sup 2} and temporal scales as small as hours. This data product, completed for the year 2002, includes detail on combustion technology and 48 fuel types through all sectors of the U.S. economy. The Vulcan inventory is built from the decades of local/regional air pollution monitoring and complements these data with census, traffic, and digital road data sets. The Vulcan inventory shows excellent agreement with national-level Department of Energy inventories, despite the different approach taken by the DOE to quantify U.S. fossil fuel CO{sub 2} emissions. Comparison to the global 1{sup o} x 1{sup o} fossil fuel CO{sub 2} inventory, used widely by the carbon cycle and climate change community prior to the construction of the Vulcan inventory, highlights the space/time biases inherent in the population-based approach.

  16. Device for separating CO2 from fossil-fueled power plant emissions

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Judkins, Roddie R. (Knoxville, TN); Wilson, Kirk A. (Knoxville, TN)

    2002-04-23T23:59:59.000Z

    A gas separation device includes an inner conduit, and a concentric outer conduit. An electrically conductive filter media, preferably a carbon fiber composite molecular sieve, is provided in the annular space between the inner conduit and the outer conduit. Gas flows through the inner conduit and the annular space between the inner conduit and the outer conduit, so as to contact the filter media. The filter media preferentially adsorbs at least one constituent of the gas stream. The filter media is regenerated by causing an electric current to flow through the filter media. The inner conduit and outer conduit are preferably electrically conductive whereby the regeneration of the filter media can be electrically stimulated. The invention is particularly useful for the removal of CO.sub.2 from the exhaust gases of fossil-fueled power plants.

  17. Analysis of CO2 Emissions from Fossil Fuel in Korea: 19611994 Ki-Hong Choi

    E-Print Network [OSTI]

    .......................................................................................................7 3.2 Energy Consumption and CO2 Emissions ................................................................8 3.2.1 Energy Consumption Pattern Appendix 3. Emission Coefficient of Electricity

  18. Final Progress Report: Direct Experiments on the Ocean Disposal of Fossil Fuel CO2.

    SciTech Connect (OSTI)

    James P. Barry; Peter G. Brewer

    2004-05-25T23:59:59.000Z

    OAK-B135 This report summarizes activities and results of investigations of the potential environmental consequences of direct injection of carbon dioxide into the deep-sea as a carbon sequestration method. Results of field experiments using small scale in situ releases of liquid CO2 are described in detail. The major conclusions of these experiments are that mortality rates of deep sea biota will vary depending on the concentrations of CO2 in deep ocean waters that result from a carbon sequestration project. Large changes in seawater acidity and carbon dioxide content near CO2 release sites will likely cause significant harm to deep-sea marine life. Smaller changes in seawater chemistry at greater distances from release sites will be less harmful, but may result in significant ecosystem changes.

  19. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation inOpen EnergyCallawayCapara Energia S ACarbon Clear JumpSources

  20. Policy Choice:Forest or Fuel? The demand for biofuels, driven by the desire to reduce fossil fuel use and CO2 emissions, has resulted in

    E-Print Network [OSTI]

    Policy Choice:Forest or Fuel? The demand for biofuels, driven by the desire to reduce fossil fuel, combined with the expanded demand for biofuels, will result in higher food prices, since less land by using biofuels (vegetable oils). But the use of biofuels may not reduce CO2 emissions, even when

  1. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    dioxide emissions from fossil fuel consumption and cementannual variations in fossil fuel emissions, J. Geophys.2008 Contribution of ocean, fossil fuel, land biosphere, and

  2. Regional patterns of radiocarbon and fossil fuel-derived CO 2 in surface air across North America

    E-Print Network [OSTI]

    Hsueh, Diana Y; Krakauer, Nir Y; Randerson, James T; Xu, Xiaomei; Trumbore, Susan E; Southon, John R

    2007-01-01T23:59:59.000Z

    carbon sources. Possible future applications include testing for leaks from subterranean CO 2 sequestration

  3. Fossil Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fossil Fuels A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Abu-Khamsin, Sidqi - Department of Petroleum Engineering, King Fahd University of Petroleum and Minerals...

  4. Atmospheric Lifetime of Fossil Fuel Carbon Dioxide

    E-Print Network [OSTI]

    Scherer, Norbert F.

    Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

  5. The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-11-02T23:59:59.000Z

    Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nations CO2 storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.

  6. Towards constraints on fossil fuel emissions from total column carbon dioxide

    E-Print Network [OSTI]

    Keppel-Aleks, G.; Wennberg, P. O; O'Dell, C. W; Wunch, D.

    2013-01-01T23:59:59.000Z

    G. Keppel-Aleks et al. : Fossil fuel constraints from X CO 2P. P. : Assess- ment of fossil fuel carbon dioxide and otherstrong localized sources: fossil fuel power plant emissions

  7. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    dioxide emissions from fossil-fuel combustion R. J. Andresdioxide emis- sions from fossil-fuel use in North America,S. : High resolution fossil fuel combustion CO 2 emission

  8. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01T23:59:59.000Z

    emissions from traded fossil fuels; Top), production (F Pr )Regional, and National Fossil-Fuel CO 2 Emissions (Carbonfrom the burning of fossil fuels are conventionally

  9. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    C. Sutherland (1999), Net sea-air CO 2 flux over the globalvariability of regional CO 2 fluxes, 1988 2003, Globalvariations of atmospheric CO 2 and climate, Tellus, Ser. B,

  10. Yankee Ticket Prices and Fossil Fuels 10 April 2008

    E-Print Network [OSTI]

    Hansen, James E.

    higher. Eventually, sales volume will begin to decline, but fossil fuel moguls will make more money than unconventional fossil fuels such as tar shale and tar sands on a large scale. That choice cannot be left is captured and sequestered) and unconventional fossil fuels are not tapped #12;substantially. Peak CO2 can

  11. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    emissions from fossil-fuel combustion R. J. Andres 1 , T. A.resolution fossil fuel combustion CO 2 emission fluxes forCO 2 emissions from fuel combustion, 2010 edition, OECD/IEA,

  12. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G. [Oak Ridge National Lab., TN (United States); Andres, R.J. [University of Alaska, Fairbanks, AK (United States). Inst. of Northern Engineering

    1995-12-01T23:59:59.000Z

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  13. GEOPHYSICAL RESEARCH LETTERS, VOL. 28, NO. 13, PAGES 2637-2640, JULY 1, 2001 Ocean release of fossil fuel CO2: A case study

    E-Print Network [OSTI]

    Drange, Helge

    a 220 MW gas power plant, it is found that the volume of the near-source water with a pH-reduction 0 are 200, 400 and 800 Gg-CO2, corresponding to CO2 emissions from conventional 55-220 MW gas power plants], a local 3-dimensional large eddy simulation (LES) code (

  14. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    NONE

    1998-03-01T23:59:59.000Z

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  15. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    independent budgeting of fossil fuel CO 2 over Europe by (CO2008 Where do fossil fuel carbon dioxide emissions frompatterns and mixing of fossil fuel-derived CO 2 is important

  16. annual evaluation maitrise: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Progress Report ADVANCED RESERVOIR CHARACTERIZATION AND EVALUATION OF CO2 Fossil Fuels Websites Summary: Sixth Annual Technical Progress Report ADVANCED RESERVOIR...

  17. Effects of aqueous effluents from in situ fossil fuel processing technologies on aquatic systems. Annual progress report, January 1-December 31, 1979

    SciTech Connect (OSTI)

    Bergman, H.L.

    1980-01-04T23:59:59.000Z

    This is the third annual progress report for a continuing EPA-DOE jointly funded project to evaluate the effects of aqueous effluents from in situ fossil-fuel processing technologies on aquatic biota. The project is organized into four project tasks: (1) literature review; (2) process water screening; (3) methods development; and (4) recommendations. Our Bibliography of aquatic ecosystem effects, analytical methods and treatment technologies for organic compounds in advanced fossil-fuel processing effluents was submitted to the EPA for publication. The bibliography contains 1314 citations indexed by chemicals, keywords, taxa and authors. We estimate that the second bibliography volume will contain approximately 1500 citations and be completed in February. We compiled results from several laboratories of inorganic characterizations of 19 process waters: 55 simulated in situ oil-shale retort waters; and Hanna-3, Hanna-4B 01W and Lawrence Livermore Hoe Creek underground coal gasification condenser waters. These process waters were then compared to a published summary of the analyses from 18 simulated in situ oil-shale retort waters. We completed this year 96-h flow-through toxicity bioassays with fathead minnows and rainbow trout and 48-h flow-through bioassays with Daphnia pulicaria exposed to 5 oil-shale process waters, 1 tar-sand process water, 2 underground coal gasification condenser waters, 1 post-gasification backflood condenser water, as well as 2 bioassays with fossil-fuel process water constituents. The LC/sub 50/ toxicity values for these respective species when exposed to these waters are given in detail. (LTN)

  18. DOES FOSSIL FUEL COMBUSTION LEAD TO GLOBAL WARMING? Stephen E. Schwartz

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    to increased CO2. Accurate knowledge of the net forcing due to fossil fuel combustion is necessary both. The sulfate forcing is estimated to be offsetting 70% of the forcing by CO2 derived from fossil fuel is comparable to that by CO2 is shown to be a consequence of the steeply increasing rates of emissions over

  19. Fossil fuel furnace reactor

    DOE Patents [OSTI]

    Parkinson, William J. (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  20. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    dioxide (CO2) emissions from fossil fuel combustion, as wellCO2 emissions (including cement process and fossil fuel combustion

  1. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:May 2015 All Issues submit Greening up fossil fuels with carbon...

  2. Progress of fossil fuel science

    SciTech Connect (OSTI)

    Demirbas, M.F.

    2007-07-01T23:59:59.000Z

    Coal is the most abundant and widely distributed fossil fuel. More than 45% of the world's electricity is generated from coal, and it is the major fuel for generating electricity worldwide. The known coal reserves in the world are enough for more than 215 years of consumption, while the known oil reserves are only about 39 times of the world's consumption and the known natural gas reserves are about 63 times of the world's consumption level in 1998. In recent years, there have been effective scientific investigations on Turkish fossil fuels, which are considerable focused on coal resources. Coal is a major fossil fuel source for Turkey. Turkish coal consumption has been stable over the past decade and currently accounts for about 24% of the country's total energy consumption. Lignite coal has had the biggest share in total fossil fuel production, at 43%, in Turkey. Turkish researchers may investigate ten broad pathways of coal species upgrading, such as desulfurization and oxydesulfurization, pyrolysis and hydropyrolysis, liquefaction and hydroliquefaction, extraction and supercritical fluid extraction, gasification, oxidation, briquetting, flotation, and structure identification.

  3. Introduction Fossil fuel combustion by aviation, shipping and road

    E-Print Network [OSTI]

    Haak, Hein

    fifth of the total global anthropogenic emissions of CO2. These emissions are growing more rapidly than to global CO emissions are estimated to be much smaller, likely due to more efficient fuel combustion. Road96 Introduction Fossil fuel combustion by aviation, shipping and road traffic contributes about one

  4. Carbon Capture and Storage from Fossil Fuel Use 1 Howard Herzog and Dan Golomb

    E-Print Network [OSTI]

    Institute of Technology Laboratory for Energy and the Environment Glossary Carbon sequestration: captureCarbon Capture and Storage from Fossil Fuel Use 1 Howard Herzog and Dan Golomb Massachusetts gas wells. Carbon capture: the separation and entrapment of CO2 from large stationary sources. CO2

  5. ith fossil-fuel combustion and land-use activities threatening to double

    E-Print Network [OSTI]

    Chambers, Jeff

    that undisturbed neotropical forests remove a significant portion of human-derived CO2 emissions fromW ith fossil-fuel combustion and land- use activities threatening to double atmospheric carbon indicate that CO2 doubling enhances the production of woody tissue per unit leaf area by about 25% (ref. 5

  6. Production of CO2 in Soil Profiles of a California Annual Grassland

    E-Print Network [OSTI]

    Fierer, Noah

    Production of CO2 in Soil Profiles of a California Annual Grassland Noah Fierer,1 * Oliver A play a key role in the global cycling of carbon (C), storing organic C, and releasing CO2 to the atmosphere. Although a large number of studies have focused on the CO2 flux at the soilair inter- face

  7. Hybrid solar-fossil fuel power generation

    E-Print Network [OSTI]

    Sheu, Elysia J. (Elysia Ja-Zeng)

    2012-01-01T23:59:59.000Z

    In this thesis, a literature review of hybrid solar-fossil fuel power generation is first given with an emphasis on system integration and evaluation. Hybrid systems are defined as those which use solar energy and fuel ...

  8. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings OIRA Comparison Document Fossil Fuel-Generated Energy...

  9. Fossil fuels supplies modeling and research

    SciTech Connect (OSTI)

    Leiby, P.N.

    1996-06-01T23:59:59.000Z

    The fossil fuel supplies modeling and research effort focuses on models for US Strategic Petroleum Reserve (SPR) planning and management. Topics covered included new SPR oil valuation models, updating models for SPR risk analysis, and fill-draw planning. Another task in this program area is the development of advanced computational tools for three-dimensional seismic analysis.

  10. OPTIMAL OPERATION OF AN INTEGRATED ENERGY PARK INCLUDING FOSSIL FUEL POWER GENERATION,

    E-Print Network [OSTI]

    Stanford University

    OPTIMAL OPERATION OF AN INTEGRATED ENERGY PARK INCLUDING FOSSIL FUEL POWER GENERATION, CO2 CAPTURE AND WIND A THESIS SUBMITTED TO THE DEPARTMENT OF ENERGY RESOURCES ENGINEERING OF STANFORD UNIVERSITY of Master of Science in Energy Resources Engineering. (Louis J. Durlofsky) Principal Co-Adviser I certify

  11. ATMOSPHERIC CO2 A GLOBAL LIMITING RESOURCE

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    Carbondioxideatmosphericburden,PgC Land use Fossil CO2 from land use emissions ­ not fossil fuel combustion ­ was the dominant CO2 Comparison of CO2 mixing ratio from fossil fuel combustion and land use changes 400 380 360 340 cores 0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 Forcing,Wm -2 #12;ATMOSPHERIC CO2 EMISSIONS Time series 1700

  12. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    The CO2 emissions from external production of electricityCO2) emissions from fossil fuel combustion, as well as the consumption of large amount of electricity,

  13. Use of experience curves to estimate the future cost of power plants with CO2 capture

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

    2007-01-01T23:59:59.000Z

    2004. Experience curves for power plant emission controlassessments of fossil fuel power plants with CO 2 capturethe future cost of power plants with CO 2 capture Edward S.

  14. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,BelcherBlundellBowles,Energy InformationFossil Fuels

  15. accelerating co2 emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    based on the empirical relationship between CO2 per capita emissions (due to fossil fuel combustion and cement production) and corresponding HDI. In order to project per capita...

  16. Opportunism and competition in the non-fossil fuel obligation

    E-Print Network [OSTI]

    Watson, Andrew

    Opportunism and competition in the non-fossil fuel obligation Paolo Agnolucci July 2005 Tyndall are the responsibility of the author(s) alone and not the Tyndall Centre. #12;Summary The Non-Fossil Fuel Order (NFFO Electricity; Renewable Policy, Non-Fossil Fuel Obligation; Moral Hazard; Post-contractual Opportunism #12

  17. No Fossil Fuel - Kingston | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcerns Jump to:Neppelsource History(CTI PFAN)Fossil Fuel - Kingston

  18. Fourth Annual Technical Progress Report ADVANCED RESERVOIR CHARACTERIZATION AND EVALUATION OF CO2

    E-Print Network [OSTI]

    Schechter, David S.

    to conducting waterflooding in naturally fractured reservoirs. As the flow rate increases, contact time betweenFourth Annual Technical Progress Report ADVANCED RESERVOIR CHARACTERIZATION AND EVALUATION OF CO2 is being accomplished by conducting research in four areas: 1) extensive characterization of the reservoirs

  19. Annual Energy Review - financial indicators section

    Reports and Publications (EIA)

    2012-01-01T23:59:59.000Z

    Annual statistics on consumer energy prices and expenditures, fossil fuel production prices and value, and value of fossil fuel imports and exports back to 1949.

  20. alternative fossil fuel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Fuels? Alternative Fuels, the Smart Choice: Alternative fuels - biodiesel, electricity, ethanol (E85), natural gas 3 From fossil fuels to renewable energies...

  1. Sales of Fossil Fuels Produced from Federal and Indian Lands...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    8 Table 6. Sales of fossil fuel production from federal and Indian lands by statearea, FY 2003-13 trillion Btu State 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 Alabama...

  2. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    by electricity generation/CHP facilities by distillate fuelFossil Fuel Consumption for Electricity and Heat GenerationFossil Fuel Consumption for Electricity and Heat Generation

  3. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  4. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    per kWh), but that CO2 emissions from hydropower plantswill be less than CO2 emissions from fossil-fuel plants.kg/ha) 2. Difference in CO2 emissions vs. control plot (kg/

  5. fossil fuels | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlinPapersWindey Wind Home Rmckeel's Home Kyoung's

  6. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.NewofGeothermal Heat AnnualGreen BusinessGreenGovGreening up

  7. Global impact of fossil fuel combustion on atmospheric NO x Larry W. Horowitz

    E-Print Network [OSTI]

    Jacob, Daniel J.

    Global impact of fossil fuel combustion on atmospheric NO x Larry W. Horowitz Advanced Study University, Cambridge, MA 02138 (email djj@io.harvard.edu) #12; Abstract. Fossil fuel combustion of fossil fuel combustion on the global distribution of NO x . In the model, we tag fossil fuel NO x and its

  8. Ethical Corporation: By Invitation -Climate change: Calling the fossil fuel abolitionists EC Newsdesk

    E-Print Network [OSTI]

    Hoffman, Andrew J.

    in a fossil fuel-based economy. Fossil fuels are our primary source of energy and support our entire wayEthical Corporation: By Invitation - Climate change: Calling the fossil fuel abolitionists EC Newsdesk 28 May 08 Where is the green Wilberforce? By Invitation: Climate change: Calling the fossil fuel

  9. co2-use-reuse | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    provide economic benefits for fossil fuel-fired power plants or industrial processes. CO2 utilization through enhanced oil recovery (EOR) could also be pursued as a means to...

  10. Modeling the release of CO2 in the deep ocean

    E-Print Network [OSTI]

    Liro, Christopher R.

    1991-01-01T23:59:59.000Z

    The idea of capturing and disposing of carbon dioxide (CO2) from the flue gas of fossil fuel-fired power plants has recently received attention as a possible mitigation strategy to counteract potential global warming due ...

  11. CO2 interaction with aquifer and seal on geological timescales: the Miller oilfield, UK North Sea

    E-Print Network [OSTI]

    Lu, Jiemin

    2008-01-01T23:59:59.000Z

    Carbon Capture and Storage (CCS) has been identified as a feasible technology to reduce CO2 emissions whilst permitting the continued use of fossil fuels. Injected CO2 must remain efficiently isolated from the atmosphere ...

  12. The dilemma of fossil fuel use and global climate change

    SciTech Connect (OSTI)

    Judkins, R.R.; Fulkerson, W. (Oak Ridge National Lab., TN (USA)); Sanghvi, M.K. (Amoco Corp., Chicago, IL (USA))

    1991-01-01T23:59:59.000Z

    The use of fossil fuels and relationship to climate change is discussed. As the use of fossil fuels has grown, the problems of protecting the environment and human health and safety have also grown, providing a continuing challenge to technological and managerial innovation. Today that challenge is to control atmospheric emissions from combustion, particularly those emissions that cause acidic deposition, urban pollution, and increasing concentrations of greenhouse gases. Technology for reducing acidic deposition is available and needs only to be adopted, and the remedies for urban pollution are being developed and tested. How effective or expensive these will be remains to be determined. The control of emissions of the greenhouse gas, CO{sub 2}, seems possible only be reducing the total amounts of fossil fuels used worldwide, and by substituting efficient natural gas technologies for coal. Long before physical depletion forces the transition away from fossil fuels, it is at least plausible and even likely that the greenhouse effect will impose a show-stopping constraint. If such a transition were soon to be necessary, the costs would be very high because substitute energy sources are either limited or expensive or undesirable for other reasons. Furthermore, the costs would be unevenly felt and would be more oppressive for developing nations because they would be least able to pay and, on average, their use rates of fossil fuels are growing much faster than those of many industrialized countries. It is prudent, therefore, to try to manage the use of fossil fuels as if a greenhouse constraint is an important possibility.

  13. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13T23:59:59.000Z

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  14. CO2 Injection in the Subsurface Kjetil Haugen

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    fuel. Nevertheless, natural gas combustion results in sub- stantial quantities of CO2. Instead Warming Fossil fuels produce CO2 upon combustion. CO2 is a greenhouse gas and contributes to global warm. Thus, replacing oil and coal with less carbon-intensive natural gas, is probably the fastest way

  15. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet [Carnegie Institution for Science, Stanford, CA; Michalak, Anna M. [Carnegie Institution for Science, Stanford, CA; van Bloemen Waanders, Bart Gustaaf [Sandia National Laboratories, Albuquerque, NM; McKenna, Sean Andrew [IBM Research, Mulhuddart, Dublin 15, Ireland

    2013-04-01T23:59:59.000Z

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  16. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    SciTech Connect (OSTI)

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31T23:59:59.000Z

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  17. Energy Conclave 2010 The global energy concerns of depleting fossil fuels and climate change have put

    E-Print Network [OSTI]

    Srivastava, Kumar Vaibhav

    at the rapidly increasing energy demand, the limited supply of fossil fuels and the increased concern over globalEnergy Conclave 2010 8th - 15th The global energy concerns of depleting fossil fuels and climate

  18. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); Summers, Cathy A. (Albany, OR); Gerdemann, Steve (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul (Independence, OR); Patrick, Brian R. (Chicago, IL)

    2011-10-18T23:59:59.000Z

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  19. Future climate trends from a first-difference atmospheric carbon dioxide regression model involving emissions scenarios for business as usual and for peak fossil fuel

    E-Print Network [OSTI]

    Leggett, L M W

    2014-01-01T23:59:59.000Z

    This paper investigates the implications of the future continuation of the demonstrated past (1960-2012) strong correlation between first-difference atmospheric CO2 and global surface temperature. It does this, for the period from the present to 2050, for a comprehensive range of future global fossil fuel energy use scenarios. The results show that even for a business-as-usual (the mid-level IPCC) fossil fuel use estimate, global surface temperature will rise at a slower rate than for the recent period 1960-2000. Concerning peak fossil fuel, for the most common scenario the currently observed (1998-2013)temperature plateau will turn into a decrease. The observed trend to date for temperature is compared with that for global climate disasters: these peaked in 2005 and are notably decreasing. The temperature and disaster results taken together are consistent with either a reduced business-as-usual fossil fuel use scenario into the future, or a peak fossil fuel scenario, but not with the standard business-as-usu...

  20. Integrated High Temperature Coal to Hydrogen System with CO2 Separation: Semi-Annual Progress Report 1

    SciTech Connect (OSTI)

    Ruud, J A; Ku, A; Ramaswamy, V; Wei, W

    2005-12-21T23:59:59.000Z

    This is the first semi-annual progress report for the program "Integrated High Temperature Coal to Hydrogen System with CO2 Separation." The objective of the program is to develop a detailed design for a single high-temperature syngas-cleanup module to produce a pure stream of H2 from a coal-based system and to develop the new high-temperature membrane materials at the core of that design. The novel one-box process combines a shift reactor with a high-temperature CO2-selective membrane to convert CO to CO2, remove sulfur compounds, and remove CO2 in a simple, compact, fully integrated system. In the first six months of the program, a conceptual design for the one-box system was developed in Task 1 and the performance targets for the system and the membrane were evaluated. In Task 2.1 processes were developed for creating pore architectures in ceramics that are applicable to membrane structures. In Task 2.2, candidate materials were identified that have the potential for separation of CO2 and H2S at high temperatures.

  1. Dirty Little Secrets: Inferring Fossil-Fuel Subsidies from Patterns in Emission Intensities1

    E-Print Network [OSTI]

    Spino, Claude

    Dirty Little Secrets: Inferring Fossil-Fuel Subsidies from Patterns in Emission Intensities1 database of directly measured fossil-fuel subsidies exists at the in- ternational level. I develop and to develop a database of comparable fossil-fuel subsidies for 155 countries from 1980 to 2010. Finally, I

  2. Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz

    E-Print Network [OSTI]

    Jacob, Daniel J.

    Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz Advanced Study Program, MA 02138 (email djj@io.harvard.edu) #12;Abstract. Fossil fuel combustion is the largest global source-dimensional model of tropospheric chemistry and transport to study the impact of fossil fuel combustion

  3. 2007-No54-BoilingPoint Health and Greenhouse Gas Impacts of Biomass and Fossil Fuel

    E-Print Network [OSTI]

    Kammen, Daniel M.

    2007-No54-BoilingPoint Theme Health and Greenhouse Gas Impacts of Biomass and Fossil Fuel Energy of fossil-fuel energy systems. These scenarios are analysed for various environmental and health impacts from fossil fuels and other energy sources reported by IEA []. In all of these countries except Kenya

  4. Urban and rural site regional fossil fuel CO2 observations from Hungary using multi elevation sampling

    E-Print Network [OSTI]

    ) and the minimum saturation mixing ratio (SMRmin) along the back trajectories associated with the observed air massAccess Solid Earth OpenAccess The Cryosphere OpenAccess Cold trap dehydration in the Tropical Tropopause Layer is evident from the data in isen- tropic scatter plots between the sonde-observed mixing ratio (OMR

  5. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    E-Print Network [OSTI]

    Gurney, Kevin R.

    2010-01-01T23:59:59.000Z

    from the electricity production sector which represents alllargest emitting sector, electricity production, exhibits ashow the Vulcan electricity production sector having the

  6. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    E-Print Network [OSTI]

    Gurney, Kevin R.

    2010-01-01T23:59:59.000Z

    to consumers from the DOE/EIA (38) was used to constructof Energys Energy Information Administration (DOE/EIA) (9).Furthermore, the DOE/EIA defines emissions by economic

  7. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    E-Print Network [OSTI]

    Gurney, Kevin R.

    2010-01-01T23:59:59.000Z

    of Energy/Energy Information Administration. Natural Gasof Energy/Energy Information Administration . Emission ofStates 2006, Energy Information Administration, Office of

  8. Supplement to: The CO2 release and Oxygen uptake from Fossil Fuel Emission

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    , gas works etc.) 0913 0921 0922 0923 0925 089 Consumption by natural gas fields & plants Consumption 0912 104 Consumption by crude petroleum fields Natural gas - Flared and vented Table 1: Overview: Stockholm University, Department of Applied Environmental Science, Stockholm, Sweden 4 now at: Tokyo

  9. Production of Hydrogen and Electricity from Coal with CO2 Capture

    E-Print Network [OSTI]

    1 Production of Hydrogen and Electricity from Coal with CO2 Capture Princeton University: Tom use (transportation and heating) responsible for ~2/3 of global CO2 emissions CO2 capture energy carriers are needed: electricity and hydrogen. If CO2 sequestration is viable, fossil fuel

  10. Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification

    E-Print Network [OSTI]

    are a strong motivation to reduce CO2 emissions from industrial processes. Burning of fossil fuel to generate electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gasEnhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification Youn-Sang Bae

  11. PCI INSTRUMENT FOR HYDROGENATION STUDIES As we are aware, earth is fast running out of fossil fuels. Additionally, use of fossil fuels

    E-Print Network [OSTI]

    Subramaniam, Anandh

    PCI INSTRUMENT FOR HYDROGENATION STUDIES As we are aware, earth is fast running out of fossil fuels. Additionally, use of fossil fuels contributes to pollution and global warming. Solar energy is envisaged as an eco-friendly alternative to traditional fuels. The multi-organization project "Generation, Storage

  12. Ex post evaluations of CO2 based taxes: a survey

    E-Print Network [OSTI]

    Watson, Andrew

    of fossil fuels, and which are introduced with the explicit intention of abating CO2 emissions. This paper and, especially, subsidies, has been called into question. Secondly, the CO2-based taxes themselves and subsidies), it is unlikely that they have been cost-effective (in the sense of attaining their environmental

  13. annual foliage growth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    effective use of social 187 A year of transformation, growth and success ANNUAL REPORT Fossil Fuels Websites Summary: ......

  14. Title: Strategic Investing for a Sustainable Future: A New Approach to the Campaign for Divestment in the Fossil Fuel Industry

    E-Print Network [OSTI]

    Angenent, Lars T.

    in the Fossil Fuel Industry Host: Charles H. Greene, Director, Ocean Resources and Ecosystems Program to encourage university divestment in the fossil fuel industry is achieving national attention. Student groups to convince the fossil fuel industry that it must play a constructive role in the transition from fossil fuels

  15. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; George Farthing; Dan Rowley; Tim R. Armstrong; R.D. Carneim; P.F. Becher; C-H. Hsueh; Aaron L. Wagner; Jon P. Wagner

    2002-04-30T23:59:59.000Z

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, inc., Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur.

  16. New Optimal Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    John Coggin; Jonas Ivasauskas; Russell G. May; Michael B. Miller; Rena Wilson

    2006-09-30T23:59:59.000Z

    Accomplishments during Phase II of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring. During this program work period, major progress has been experienced in the development of the sensor hardware, and the planning of the system installation and operation. The major focus of the next work period will be the installation of sensors in the Hamilton, Ohio power plant, and demonstration of high-temperature strain gages during mechanical testing of SOFC components.

  17. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Todd, Jr., Lee T.; Boggess, Ronald J.; Carson, Ronald J.; Falkenberg, Virginia P.; Flanagan, Patrick; Hettinger, Jr., William P.; Kimel, Kris; Kupchella, Charles E.; Magid, Lee J.; McLaughlin, Barbara; Royster, Wimberly C.; Streepey, Judi L.; Wells, James H.; Stencel, John; Derbyshire, Frank J.; Hanley, Thomas R.; Magid, Lee J.; McEllistrem, Marc T.; Riley, John T.; Steffen, Joseph M.

    1992-01-01T23:59:59.000Z

    A one-year USDOE/EPSCOR Traineeship Grant, entitled Clean Uses of Fossil Fuels.'' was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  18. Classification of fossil fuels according to structural-chemical characteristics

    SciTech Connect (OSTI)

    A.M. Gyul'maliev; G.S. Golovin; S.G. Gagarin [Institute for Fossil Fuels, Moscow (Russian Federation)

    2007-10-15T23:59:59.000Z

    On the basis of a set of linear equations that relate the amount of major elements n{sub E} (E = C, H, O, N, S) in the organic matter of fossil fuels to structural characteristics, such as the number of cycles R, the number of atoms n{sub E}, the number of mutual chemical bonds, the degree of unsaturation of the structure {delta}, and the extent of its reduction B, a structural-chemical classification of fossil coals that is closely related to the parameters of the industrial-genetic classification (GOST 25543-88) is proposed. Structural-chemical classification diagrams are constructed for power-generating coals of Russia; coking coals; and coals designed for nonfuel purposes including the manufacture of adsorbents, synthetic liquid fuel, ion exchangers, thermal graphite, and carbon-graphite materials.

  19. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect (OSTI)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30T23:59:59.000Z

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  20. Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect (OSTI)

    Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

    2001-11-06T23:59:59.000Z

    Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

  1. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    from Fuel Combustion in 2004.. 34Emissions from Fuel Combustion in California, Million MetricEmission Estimates from the Combustion of Fossil Fuels in

  2. Supported polyethylenimine adsorbents for CO2 capture from flue gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Gray, M.L.; Pennline, H.W.

    2008-10-01T23:59:59.000Z

    Anthropogenic CO2 emissions produced from fossil fuel combustion are believed to contribute to undesired consequences in global climate. Major contributors towards CO2 emissions are fossil fuel-fired power plants for electricity production. For this reason, CO2 capture from flue gas streams together with permanent sequestration in geologic formations is being considered a viable solution towards mitigation of the major greenhouse gas1. Technologies based on chemical absorption with alkanolamines have been assessed for first generation CO2 post-combustion capture primarily due to its advanced stage of development. However, limitations associated with these chemical solvents (i.e., low CO2 loadings, amine degradation by oxygen, equipment corrosion) manifest themselves in high capital and operating costs with reduced thermal efficiencies. Therefore, necessary design and development of alternative, lower cost approaches for CO2 capture from coal-fired combustion streams are warranted.

  3. Carbon Capture by Fossil Fuel Power Plants: An Economic Analysis

    E-Print Network [OSTI]

    Silver, Whendee

    working paper "CO2 Regulations and Electricity Prices: Cost Estimates for Coal-Fired Power Plants." We capabilities at new coal-fired power plants. The corresponding break-even values for natural gas plants source of CO2 emissions. For the U.S. alone, coal-fired and natural gas power plants contributed more

  4. EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE AND SEQUESTRATION -DOE/NETL May 4 7, 2009 Detection of CO2 Seepage from Geological

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE AND SEQUESTRATION - DOE/NETL May 4 7, 2009 Detection of CO2 Seepage from Geological Sequestration Sites Using an Array of Downhole Pressure Gauges Jalal Jalali and Shahab D. Mohaghegh, West Virginia University #12;EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE

  5. ATMOSPHERIC CO2 --A GLOBAL LIMITING RESOURCE: HOW MUCH FOSSIL CARBON CAN WE BURN?

    E-Print Network [OSTI]

    of emissions from fossil fuel combustion. An increase in atmospheric CO2 would enhance Earth's naturalATMOSPHERIC CO2 -- A GLOBAL LIMITING RESOURCE: HOW MUCH FOSSIL CARBON CAN WE BURN? S. E. Schwartz, NY www.bnl.gov ABSTRACT Carbon dioxide (CO2) is building up in the atmosphere, largely because

  6. Sharing global CO2 emission reductions among one billion high emitters

    E-Print Network [OSTI]

    Sharing global CO2 emission reductions among one billion high emitters Shoibal Chakravartya of a country to estimate how its fossil fuel CO2 emissions are distributed among its citizens, from which we distributions. For example, re- ducing projected global emissions in 2030 by 13 GtCO2 would require

  7. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Adam Calihman; Andy Girard; Pamela M. Van Calcar; Richard Mackay; Tom Barton; Sara Rolfe

    2001-01-30T23:59:59.000Z

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, Inc., Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. Membranes testing during this reporting period were greater than 1 mm thick and had the general perovskite composition AB{sub 1-x}B'{sub x}O{sub 3-{delta}}, where 0.05 {<=} x {<=} 0.3. These materials demonstrated hydrogen separation rates between 1 and 2 mL/min/cm{sup 2}, which represents roughly 20% of the target goal for membranes of this thickness. The sintered membranes were greater than 95% dense, but the phase purity decreased with increasing dopant concentration. The quantity of dopant incorporated into the perovskite phase was roughly constant, with excess dopant forming an additional phase. Composite materials with distinct ceramic and metallic phases, and thin film perovskites (100 {micro}m) also were successfully prepared, but have not yet been tested for hydrogen transport. Finally, porous platinum was identified as a excellent catalyst for evaluation of membrane materials, however, lower cost nickel catalyst systems are being developed.

  8. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Richard A. Mackay; Adam E. Calihman; Lyrik Y. Pitzman; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Mike J. Holmes; Aaron L. Wagner

    2001-07-30T23:59:59.000Z

    Eltron Research Inc., and team members, are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, ceramic, cermet (ceramic/metal), and thin film membranes were prepared, characterized, and evaluated for H{sub 2} transport. For selected ceramic membrane compositions an optimum range for transition metal doping was identified, and it was determined that highest proton conductivity occurred for two-phase ceramic materials. Furthermore, a relationship between transition metal dopant atomic number and conductivity was observed. Ambipolar conductivities of {approx}6 x 10{sup -3} S/cm were achieved for these materials, and {approx} 1-mm thick membranes generated H{sub 2} transport rates as high as 0.3 mL/min/cm{sup 2}. Cermet membranes during this quarter were found to have a maximum conductivity of 3 x 10{sup -3} S/cm, which occurred at a metal phase contact of 36 vol.%. Homogeneous dense thin films were successfully prepared by tape casting and spin coating; however, there remains an unacceptably high difference in shrinkage rates between the film and support, which led to membrane instability. Further improvements in high pressure membrane seals also were achieved during this quarter, and a maximum pressure of 100 psig was attained. CoorsTek optimized many of the processing variables relevant to manufacturing scale production of ceramic H{sub 2} transport membranes, and SCI used their expertise to deposit a range of catalysts compositions onto ceramic membrane surfaces. Finally, MTI compiled relevant information regarding Vision 21 fossil fuel plant operation parameters, which will be used as a starting point for assessing the economics of incorporating a H{sub 2} separation unit.

  9. Modules for estimating solid waste from fossil-fuel technologies

    SciTech Connect (OSTI)

    Crowther, M.A.; Thode, H.C. Jr.; Morris, S.C.

    1980-10-01T23:59:59.000Z

    Solid waste has become a subject of increasing concern to energy industries for several reasons. Increasingly stringent air and water pollution regulations result in a larger fraction of residuals in the form of solid wastes. Control technologies, particularly flue gas desulfurization, can multiply the amount of waste. With the renewed emphasis on coal utilization and the likelihood of oil shale development, increased amounts of solid waste will be produced. In the past, solid waste residuals used for environmental assessment have tended only to include total quantities generated. To look at environmental impacts, however, data on the composition of the solid wastes are required. Computer modules for calculating the quantities and composition of solid waste from major fossil fuel technologies were therefore developed and are described in this report. Six modules have been produced covering physical coal cleaning, conventional coal combustion with flue gas desulfurization, atmospheric fluidized-bed combustion, coal gasification using the Lurgi process, coal liquefaction using the SRC-II process, and oil shale retorting. Total quantities of each solid waste stream are computed together with the major components and a number of trace elements and radionuclides.

  10. Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect (OSTI)

    Carl R. Evenson; Richard N. Kleiner; James E. Stephan; Frank E. Anderson

    2006-04-30T23:59:59.000Z

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this final quarter of the no cost extension several planar membranes of a cermet composition referred to as EC101 containing a high permeability metal and a ceramic phase were prepared and permeability testing was performed.

  11. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUELS PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard Mackay; Stewart Schesnack; Scott Morrison; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-07-31T23:59:59.000Z

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This report presents hydrogen permeation data during long term tests and tests at high pressure in addition to progress with cermet, ceramic/ceramic, and thin film membranes.

  12. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Stewart Schesnack; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-04-30T23:59:59.000Z

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (i) mixed conducting ceramic/ceramic composites, (ii) mixed conducting ceramic/metal (cermet) composites, (iii) cermets with hydrogen permeable metals, and (iv) hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This report describes resent results for long-term hydrogen permeation and chemical stability measurements, new mixed conducting cermets, progress in cermet, thin film, and thin-walled tube fabrication, hydrogen absorption measurements for selected compositions, and membrane facilitated alkane to olefin conversion.

  13. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13T23:59:59.000Z

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  14. Aquifer Management for CO2 Sequestration

    E-Print Network [OSTI]

    Anchliya, Abhishek

    2010-07-14T23:59:59.000Z

    to the Computer Modeling Group (CMG) and Kappa Engineering for providing the uninterrupted license of the software packages. I am grateful to Mr. Bob Brugman from CMG for his help with the GEM-GHG (Green House Gas) module of CMG. I would like to extend my... biological sinks of CO 2 and decreasing the carbon intensity of fossil fuels should be considered. Out of all the potential mitigation options for stabilizing atmospheric GHG concentrations, including injection into deep oceans, depleted oil reservoirs...

  15. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31T23:59:59.000Z

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  16. annual dangerous waste: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Community: We are pleased Cakoni, Fioralba 298 Fellows Program 2011 Annual Report Fossil Fuels Websites Summary: of the Hellman Fellows program, which now provides annual...

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    We are pleased Cakoni, Fioralba 150 Fellows Program 2011 Annual Report Fossil Fuels Websites Summary: of the Hellman Fellows program, which now provides annual fellowship...

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    Community: We are pleased Cakoni, Fioralba 208 Fellows Program 2011 Annual Report Fossil Fuels Websites Summary: of the Hellman Fellows program, which now provides annual...

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  1. annual volume ii: Topics by E-print Network

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    Community: We are pleased Cakoni, Fioralba 298 Fellows Program 2011 Annual Report Fossil Fuels Websites Summary: of the Hellman Fellows program, which now provides annual...

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    Community: We are pleased Cakoni, Fioralba 151 Fellows Program 2011 Annual Report Fossil Fuels Websites Summary: of the Hellman Fellows program, which now provides annual...

  3. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; George Farthing; Dan Rowley; Tim R. Armstrong; M.K. Ferber; Aaron L. Wagner; Jon P. Wagner

    2002-07-30T23:59:59.000Z

    Eltron Research Inc. and their team members are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, new cermet compositions were tested that demonstrated similar performance to previous materials. A 0.5-mm thick membrane achieved at H{sub 2} transport rate of 0.2 mL/min/cm{sup 2} at 950 C, which corresponded to an ambipolar conductivity of 3 x 10{sup -3} S/cm. Although these results were equivalent to those for other cermet compositions, this new composition might be useful if it demonstrates improved chemical or mechanical stability. Ceramic/ceramic composite membranes also were fabricated and tested; however, some reaction did occur between the proton- and electron-conducting phases, which likely compromised conductivity. This sample only achieved a H{sub 2} transport rate of {approx} 0.006 mL/min/cm{sup 2} and an ambipolar conductivity of {approx}4 x 10{sup -4} S/cm. Chemical stability tests were continued, and candidate ceramic membranes were found to react slightly with carbon monoxide under extreme testing conditions. A cermet compositions did not show any reaction with carbon monoxide, but a thick layer of carbon formed on the membrane surface. The most significant technical accomplishment this quarter was a new high-pressure seal composition. This material maintained a pressure differential across the membrane of {approx} 280 psi at 800 C, and is still in operation.

  4. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard Mackay; Stewart R. Schesnack; Scott R. Morrison; Thomas F. Barton; Sara L. Rolfe; U. Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-10-30T23:59:59.000Z

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Over the past 12 months, this project has focused on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. The ceramic/ceramic composites demonstrate the lowest hydrogen permeation rates, with a maximum of approximately 0.1 mL/min/cm{sup 2} for 0.5-mm thick membranes at 800 to 950 C. Under equivalent conditions, cermets achieve a hydrogen permeation rate near 1 mL/min/cm{sup 2}, and the metal phase also improves structural stability and surface catalysis for hydrogen dissociation. Furthermore, if metals with high hydrogen permeability are used in cermets, permeation rates near 4 mL/min/cm{sup 2} are achievable with relatively thick membranes. Layered composite membranes have by far the highest permeation rates with a maximum flux in excess of 200 mL {center_dot} min{sup -1} {center_dot} cm{sup -2}. Moreover, these permeation rates were achieved at a total pressure differential across the membrane of 450 psi. Based on these results, effort during the next year will focus on this category of membranes. This report contains long-term hydrogen permeation data over eight-months of continuous operation, and permeation results as a function of operating conditions at high pressure for layered composite membranes. Additional progress with cermet and thin film membranes also is presented.

  5. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Adam E. Calihman; Lyrik Y. Pitzman; Pamela M. Van Calcar; Richard A. Mackay; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Tim R. Armstrong; Mike J. Holmes; Aaron L. Wagner

    2001-04-30T23:59:59.000Z

    Eltron Research Inc., and team members, are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, it was demonstrated that increasing the transition metal loading in a model perovskite composition resulted in an increase in hydrogen flux. Improved flux corresponded to the emergence of additional phases in the ceramic membrane, and highest flux was achieved for a composite consisting of pseudo-cubic and rhombohedral perovskite phases. A 0.9-mm thick membrane of this material generated a hydrogen flux in excess of 0.1 mL/min/cm{sup 2}, which was approximately 35 times greater than analogs with lower transition metal levels. The dopant level and crystal structure also correlated with membrane density and coefficient of thermal expansion, but did not appear to affect grain size or shape. Additionally, preliminary ceramic-metal (cermet) composite membranes demonstrated a 10-fold increase in flux relative to analogous membranes composed of only the ceramic component. The hydrogen flux for these cermet samples corresponded to a conductivity of {approx} 10{sup -3} S/cm, which was consistent with the predicted proton conductivity of the ceramic phase. Increasing the sweep gas flow rate in test reactors was found to significantly increase hydrogen flux, as well as apparent material conductivity for all samples tested. Adding humidity to the feed gas stream produced a small increase in hydrogen flux. However, the catalyst on ceramic membrane surfaces did not affect flux, which suggested that the process was membrane-diffusion limited. Representative samples and fabrication processes were evaluated on the basis of manufacturing practicality. it was determined that optimum membrane densification occurs over a very narrow temperature range for the subject ceramics. Additionally, calcination temperatures currently employed result in powders that are difficult mill and screen. These issues must be addressed to improve large-scale fabricability.

  6. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Alexandra Z. LaGuardia; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Mike J. Holmes; Aaron L. Wagner

    2001-10-30T23:59:59.000Z

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, Inc., Sued Chemie, Argonne National Laboratory and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, mixed proton/electron conductivity and hydrogen transport was measured as a function of metal phase content for a range of ceramic/metal (cermet) compositions. It was found that optimum performance occurred at 44 wt.% metal content for all compositions tested. Although each cermet appeared to have a continuous metal phase, it is believed that hydrogen transport increased with increasing metal content partially due to beneficial surface catalyst characteristics resulting from the metal phase. Beyond 44 wt.% there was a reduction in hydrogen transport most likely due to dilution of the proton conducting ceramic phase. Hydrogen separation rates for 1-mm thick cermet membranes were in excess of 0.1 mL/min/cm{sup 2}, which corresponded to ambipolar conductivities between 1 x 10{sup -3} and 8 x 10{sup -3} S/cm. Similar results were obtained for multiphase ceramic membranes comprised of a proton-conducting perovskite and electron conducting metal oxide. These multi-phase ceramic membranes showed only a slight improvement in hydrogen transport upon addition of a metal phase. The highest hydrogen separation rates observed this quarter were for a cermet membrane containing a hydrogen transport metal. A 1-mm thick membrane of this material achieved a hydrogen separation rate of 0.3 mL/min/cm{sup 2} at only 700 C, which increased to 0.6 mL/min/cm{sup 2} at 950 C.

  7. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Stewart R. Schesnack; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-01-30T23:59:59.000Z

    Eltron Research Inc., and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying composite membrane composition and microstructure to maximize hydrogen permeation without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, a composite metal membrane based on an inexpensive hydrogen permeable metal achieved permeation rates in excess of 25 mL/min/cm{sup 2}. Preliminary attempts to incorporate this metal into a cermet were successful, and a thick cermet membrane (0.83 mm) with 40 vol.% metal phase achieved a permeation rate of nearly 0.4 mL/min/cm{sup 2}. Increasing the metal phase content and decreasing membrane thickness should significantly increase permeation, while maintaining the benefits derived from cermets. Two-phase ceramic/ceramic composite membranes had low hydrogen permeability, likely due to interdiffusion of constituents between the phases. However, these materials did demonstrate high resistance to corrosion, and might be good candidates for other composite membranes. Temperature-programmed reduction measurements indicated that model cermet materials absorbed 2.5 times as much hydrogen than the pure ceramic analogs. This characteristic, in addition to higher electron conductivity, likely explains the relatively high permeation for these cermets. Incorporation of catalysts with ceramics and cermets increased hydrogen uptake by 800 to more than 900%. Finally, new high-pressure seals were developed for cermet membranes that maintained a pressure differential of 250 psi. This result indicated that the approach for high-pressure seal development could be adapted for a range of compositions. Other items discussed in this report include mechanical testing, new proton conducting ceramics, supported thin films, and alkane to olefin conversion.

  8. Communication : S4FE2009 (International Conference on Sustainable Fossil Fuels for Future Energy), Rome, 6 au 10 juillet 2009

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Communication : S4FE2009 (International Conference on Sustainable Fossil Fuels for Future Energy on Sustainable Fossil Fuels for Future Energy), Rome : Italy (2009)" #12;Communication : S4FE2009 (International Conference on Sustainable Fossil Fuels for Future Energy), Rome, 6 au 10 juillet 2009 2 FFiigguurree 11

  9. Arizona: Solar Panels Replace Inefficient Fossil Fuel-Powered...

    Energy Savers [EERE]

    Energy Program project results in annual estimated cost savings of 313,000 for reduced consumption of gasoline, diesel, propane, and electricity. Location Arizona Partners State...

  10. Implications of "peak oil" for atmospheric CO2 and climate

    E-Print Network [OSTI]

    Kharecha, P A

    2007-01-01T23:59:59.000Z

    Peaking of global oil production may have a large effect on future atmospheric CO2 amount and climate change, depending upon choices made for subsequent energy sources. We suggest that, if estimates of oil and gas reserves by the Energy Information Administration are realistic, it is feasible to keep atmospheric CO2 from exceeding approximately 450 ppm, provided that future exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration, must be phased out before mid-century to achieve this limit on atmospheric CO2. We also suggest that it is important to "stretch" oil reserves via energy efficiency, thus avoiding the need to extract liquid fuels from coal or unconventional fossil fuels. We argue that a rising price on carbon emissions is probably needed to keep CO2 beneath the 450 ppm ceiling.

  11. Impacts of Renewable Generation on Fossil Fuel Unit Cycling: Costs and Emissions (Presentation)

    SciTech Connect (OSTI)

    Brinkman, G.; Lew, D.; Denholm, P.

    2012-09-01T23:59:59.000Z

    Prepared for the Clean Energy Regulatory Forum III, this presentation looks at the Western Wind and Solar Integration Study and reexamines the cost and emissions impacts of fossil fuel unit cycling.

  12. Woodfuel scoping study Increasing the use of woodfuel as a substitute for fossil fuels is important

    E-Print Network [OSTI]

    Woodfuel scoping study Increasing the use of woodfuel as a substitute for fossil fuels is important tonnes of material a year from currently UMW in England by 2020. New government subsidies for heat

  13. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011

    Broader source: Energy.gov [DOE]

    This paper was prepared in response to recent requests that the U.S. Energy Information Administration (EIA) provide updated summary information regarding fossil fuel production on federal and...

  14. Fossil fuel potential of Turkey: A statistical evaluation of reserves, production, and consumption

    SciTech Connect (OSTI)

    Korkmaz, S.; Kara-Gulbay, R.; Turan, M. [Karadeniz Technical University, Trabzon (Turkey)

    2008-07-01T23:59:59.000Z

    Since Turkey is a developing country with tremendous economic growth, its energy demand is also getting increased. Of this energy, about 70% is supplied from fossil fuels and the remaining 30% is from renewable sources. Among the fossil fuels, 90% of oil, natural gas, and coal are imported, and only 10% is from domestic sources. All the lignite is supplied from domestic sources. The total share of renewable sources and lignite in the total energy production is 45%. In order for Turkey to have sufficient and reliable energy sources, first the renewable energy sources must be developed, and energy production from fossil fuels, except for lignite, must be minimized. Particularly, scarcity of fossil fuels and increasing oil prices have a strong effect on economic growth of the country.

  15. Integration and Optimization of Trigeneration Systems with Solar Energy, Biofuels, Process Heat and Fossil Fuels

    E-Print Network [OSTI]

    Tora, Eman

    2012-02-14T23:59:59.000Z

    at developing a systematic approach to integrate solar energy into industrial processes to drive thermal energy transfer systems producing power, cool, and heat. Solar energy is needed to be integrated with other different energy sources (biofuels, fossil fuels...

  16. Integration and Optimization of Trigeneration Systems with Solar Energy, Biofuels, Process Heat and Fossil Fuels

    E-Print Network [OSTI]

    Tora, Eman

    2012-02-14T23:59:59.000Z

    at developing a systematic approach to integrate solar energy into industrial processes to drive thermal energy transfer systems producing power, cool, and heat. Solar energy is needed to be integrated with other different energy sources (biofuels, fossil fuels...

  17. EFFECTS OF CO2 LEAKAGES FROM STORAGE SITES ON THE QUALITY OF POTABLE GROUNDWATER

    E-Print Network [OSTI]

    was packed into two fixed-bed PVC columns. In the one column, gas CO2 and water were co-injected while only gas effect due mainly to the combustion of fossil fuels and CO2 emissions in the atmosphere

  18. THE INCREASING CONCENTRATION OF ATMOSPHERIC CO2: HOW MUCH, WHEN, AND WHY?

    E-Print Network [OSTI]

    emissions when fuel consumption is expressed in energy units. Table 1: CO2 Emission Rates for Fossil, and we examine the trends in both. We review the extent to which cause and effect can be demonstrated between the trends in fossil-fuel burning and the trends in atmospheric CO2 concentration. Finally, we

  19. Complex Flow and Composition Path in CO2 Injection Schemes from Density Effects

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    causes for acceleration in global warming. Because fossil fuels will be a critical component of the world (1) allows for reduction of the CO2 concentration in the atmosphere to reduce global warming and (2) has become more attractive from the standpoint of global warming concerns. The increase in the CO2

  20. Fixation of CO2 by chrysotile in low-pressure dry and moist carbonation: Ex-situ and in-situ characterizations

    E-Print Network [OSTI]

    Long, Bernard

    . Emitted in large proportions, especially from (stationary) fossil-fuel based power plants, carbon dioxide­1200 °C), humidity (0­10 mol %) and CO2 partial pressure (20­67 mol %), thermal preconditioning

  1. "Peak Oil"Paper Revised and Temperature Analysis Code (1) The paper"Implications of`Peak Oil'for Atmospheric CO2 and Climate", recently revised and

    E-Print Network [OSTI]

    Hansen, James E.

    to the dichotomy between scenarios with declining emissions and"business-as-usual"scenarios. We have minimized is phased out except where the CO2 is captured and stored, and use of unconventional fossil fuels

  2. association euratom-tekes annual: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Community: We are pleased Cakoni, Fioralba 246 Fellows Program 2011 Annual Report Fossil Fuels Websites Summary: of the Hellman Fellows program, which now provides annual...

  3. Geological Sequestration Training and Research Program in Capture and Transport: Development of the Most Economical Separation Method for CO2 Capture

    SciTech Connect (OSTI)

    Vahdat, Nader

    2013-09-30T23:59:59.000Z

    The project provided hands-on training and networking opportunities to undergraduate students in the area of carbon dioxide (CO2) capture and transport, through fundamental research study focused on advanced separation methods that can be applied to the capture of CO2 resulting from the combustion of fossil-fuels for power generation . The project teams approach to achieve its objectives was to leverage existing Carbon Capture and Storage (CCS) course materials and teaching methods to create and implement an annual CCS short course for the Tuskegee University community; conduct a survey of CO2 separation and capture methods; utilize data to verify and develop computer models for CO2 capture and build CCS networks and hands-on training experiences. The objectives accomplished as a result of this project were: (1) A comprehensive survey of CO2 capture methods was conducted and mathematical models were developed to compare the potential economics of the different methods based on the total cost per year per unit of CO2 avoidance; and (2) Training was provided to introduce the latest CO2 capture technologies and deployment issues to the university community.

  4. METHODOLOGIES FOR REVIEW OF THE HEALTH AND SAFETY ASPECTS OF PROPOSED NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL SITES AND FACILITIES. VOLUME 9 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01T23:59:59.000Z

    Specific Considerations Fossil Fuel Coal r. a. b. Normalliquid dominated) and fossil-fuel fired (either coal, oil,Specific Cons iderations Fossil Fuel Coal Oil 1. 1. 3. L 1

  5. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation in CarbonofBiotinsBoston CollegeBrazil

  6. RADIOLOGICAL HEALTH AND RELATED STANDARDS FOR NUCLEAR POWER PLANTS. VOLUME 2 OF HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01T23:59:59.000Z

    IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy and Environment

  7. Seasonal exchange of CO 2 and delta18 O-CO 2 varies with postfire succession in boreal forest ecosystems

    E-Print Network [OSTI]

    Welp, L. R; Randerson, J. T; Liu, H. P

    2006-01-01T23:59:59.000Z

    shows no unidirectional, fossil fuel controlled trend (asthe ocean, stratosphere, fossil fuels, and other terrestrialwhich the secular trend from fossil fuel emissions has been

  8. Summary of research on hydrogen production from fossil fuels conducted at NETL

    SciTech Connect (OSTI)

    Shamsi, Abolghasem

    2008-03-30T23:59:59.000Z

    In this presentation we will summarize the work performed at NETL on the production of hydrogen via partial oxidation/dry reforming of methane and catalytic decomposition of hydrogen sulfide. We have determined that high pressure resulted in greater carbon formation on the reforming catalysts, lower methane and CO2 conversions, as well as a H2/CO ratio. The results also showed that Rh/alumina catalyst is the most resistant toward carbon deposition both at lower and at higher pressures. We studied the catalytic partial oxidation of methane over Ni-MgO solid solutions supported on metal foams and the results showed that the foam-supported catalysts reach near-equilibrium conversions of methane and H2/CO selectivities. The rates of carbon deposition differ greatly among the catalysts, varying from 0.24 mg C/g cat h for the dipped foams to 7.0 mg C/g cat h for the powder-coated foams, suggesting that the exposed Cr on all of the foam samples may interact with the Ni-MgO catalyst to kinetically limit carbon formation. Effects of sulfur poisoning on reforming catalysts were studies and pulse sulfidation of catalyst appeared to be reversible for some of the catalysts but not for all. Under pulse sulfidation conditions, the 0.5%Rh/alumina and NiMg2Ox-1100C (solid solution) catalysts were fully regenerated after reduction with hydrogen. Rh catalyst showed the best overall activity, less carbon deposition, both fresh and when it was exposed to pulses of H2S. Sulfidation under steady state conditions significantly reduced catalyst activity. Decomposition of hydrogen sulfide into hydrogen and sulfur was studied over several supported metal oxides and metal oxide catalysts at a temperature range of 650-850C. H2S conversions and effective activation energies were estimated using Arrhenius plots. The results of these studies will further our understanding of catalytic reactions and may help in developing better and robust catalysts for the production of hydrogen from fossil fuels

  9. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    SciTech Connect (OSTI)

    Riley, W.J.; Hsueh, D.Y.; Randerson, J.T.; Fischer, M.L.; Hatch, J.G.; Pataki, D.E.; Wang, W.; Goulden, M.L.

    2008-05-01T23:59:59.000Z

    Characterizing flow patterns and mixing of fossil fuel-derived CO{sub 2} is important for effectively using atmospheric measurements to constrain emissions inventories. Here we used measurements and a model of atmospheric radiocarbon ({sup 14}C) to investigate the distribution and fluxes of atmospheric fossil fuel CO{sub 2} across the state of California. We sampled {sup 14}C in annual C{sub 3} grasses at 128 sites and used these measurements to test a regional model that simulated anthropogenic and ecosystem CO{sub 2} fluxes, transport in the atmosphere, and the resulting {sup 14}C of annual grasses ({Delta}{sub g}). Average measured {Delta}{sub g} in Los Angeles, San Francisco, the Central Valley, and the North Coast were 27.7 {+-} 20.0, 44.0 {+-} 10.9, 48.7 {+-} 1.9, and 59.9 {+-} 2.5{per_thousand}, respectively, during the 2004-2005 growing season. Model predictions reproduced regional patterns reasonably well, with estimates of 27.6 {+-} 2.4, 39.4 {+-} 3.9, 46.8 {+-} 3.0, and 59.3 {+-} 0.2{per_thousand} for these same regions and corresponding to fossil fuel CO{sub 2} mixing ratios (Cf) of 13.7, 6.1, 4.8, and 0.3 ppm. {Delta}{sub g} spatial heterogeneity in Los Angeles and San Francisco was higher in the measurements than in the predictions, probably from insufficient spatial resolution in the fossil fuel inventories (e.g., freeways are not explicitly included) and transport (e.g., within valleys). We used the model to predict monthly and annual transport patterns of fossil fuel-derived CO{sub 2} within and out of California. Fossil fuel CO{sub 2} emitted in Los Angeles and San Francisco was predicted to move into the Central Valley, raising Cf above that expected from local emissions alone. Annually, about 21, 39, 35, and 5% of fossil fuel emissions leave the California airspace to the north, east, south, and west, respectively, with large seasonal variations in the proportions. Positive correlations between westward fluxes and Santa Ana wind conditions were observed. The southward fluxes over the Pacific Ocean were maintained in a relatively coherent flow within the marine boundary layer, while the eastward fluxes were more vertically dispersed. Our results indicate that state and continental scale atmospheric inversions need to consider areas where concentration measurements are sparse (e.g., over the ocean to the south and west of California), transport within and across the marine boundary layer, and terrestrial boundary layer dynamics. Measurements of {Delta}{sub g} can be very useful in constraining these estimates.

  10. Air Pollution Control Regulations: No. 13- Particulate Emissions from Fossil Fuel Fired Steam or Hot Water Generating Units (Rhode Island)

    Broader source: Energy.gov [DOE]

    The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and wood-fired steam or hot water generating units.

  11. Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings

    Broader source: Energy.gov [DOE]

    Document details Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in a Supplemental Notice of Proposed Rulemaking.

  12. Optimal Design of a Fossil Fuel-Based Hydrogen Infrastructure with Carbon Capture and Sequestration: Case Study in Ohio

    E-Print Network [OSTI]

    Johnson, Nils; Yang, Christopher; Ni, Jason; Johnson, Joshua; Lin, Zhenhong; Ogden, Joan M

    2005-01-01T23:59:59.000Z

    M.W. , Initiating hydrogen infrastructures: preliminaryNatural Gas Based Hydrogen Infrastructure Optimizingof a Fossil Fuel-Based Hydrogen Infrastructure with Carbon

  13. Background Energy efficiency has become a growing concern in a world driven by a fossil fuel economy. To this end,

    E-Print Network [OSTI]

    Dawson, Jeff W.

    Background Energy efficiency has become a growing concern in a world driven by a fossil fuel have been developed at Brayton Energy Canada, but several difficulties are encountered

  14. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2004-09-01T23:59:59.000Z

    An innovative Diffusion Driven Desalination (DDD) process was recently described where evaporation of mineralized water is driven by diffusion within a packed bed. The energy source to drive the process is derived from low pressure condensing steam within the main condenser of a steam power generating plant. Since waste heat is used to drive the process, the main cost of fresh water production is attributed to the energy cost of pumping air and water through the packed bed. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A combined thermodynamic and dynamic analysis demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3'' Hg. Throughout the past year, the main focus of the desalination process has been on the diffusion tower and direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. An experimental DDD facility has been fabricated, and temperature and humidity data have been collected over a range of flow and thermal conditions. The analyses agree quite well with the current data and the information available in the literature. Direct contact condensers with and without packing have been investigated. It has been experimentally observed that the fresh water production rate is significantly enhanced when packing is added to the direct contact condensers.

  15. An Evaluation of some Health Risks of the Pollution from Fossil Fuel Combustion

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Workshop Economic Evaluation of Damage Caused by Acidifying Pollutants London, May 9 - 11,version1-3Apr2014 Author manuscript, published in "UN/ECE Workshop Economic Evaluation of Damage Caused94-27 An Evaluation of some Health Risks of the Pollution from Fossil Fuel Combustion Guy Landrieu

  16. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    SciTech Connect (OSTI)

    Linville, B. (ed.)

    1982-10-01T23:59:59.000Z

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  17. Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities

    E-Print Network [OSTI]

    Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities Biomass energy input basis in the upcoming calendar year? - Please check "yes" or "no." 12. Types of Biomass Fuel Used - Please report the quantity and supplier of the following types of biomass fuel used

  18. Estimating particulate matter health impact related to the combustion of different fossil fuels

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Estimating particulate matter health impact related to the combustion of different fossil fuels generated a web map service that allows to access information on fuel dependent health effects due a simulation. Combined with a dedicated emission inventory PM2.5 maps specified by fuel type were generated

  19. Impacts of Wind and Solar on Fossil-Fueled Generators: Preprint

    SciTech Connect (OSTI)

    Lew, D.; Brinkman, G.; Kumar, N.; Besuner, P.; Agan, D.; Lefton, S.

    2012-08-01T23:59:59.000Z

    High penetrations of wind and solar power will impact the operations of the remaining generators on the power system. Regional integration studies have shown that wind and solar may cause fossil-fueled generators to cycle on and off and ramp down to part load more frequently and potentially more rapidly. Increased cycling, deeper load following, and rapid ramping may result in wear-and-tear impacts on fossil-fueled generators that lead to increased capital and maintenance costs, increased equivalent forced outage rates, and degraded performance over time. Heat rates and emissions from fossil-fueled generators may be higher during cycling and ramping than during steady-state operation. Many wind and solar integration studies have not taken these increased cost and emissions impacts into account because data have not been available. This analysis considers the cost and emissions impacts of cycling and ramping of fossil-fueled generation to refine assessments of wind and solar impacts on the power system.

  20. 55Home Power #21 February / March 1991 ALTERNATIVES TO FOSSIL FUELED

    E-Print Network [OSTI]

    55Home Power #21 February / March 1991 BioGas ALTERNATIVES TO FOSSIL FUELED ENGINE among letters from Home Power readers. I would like to share some perspectives on steam power and its! Producing steam requires heating water to above boiling temperature under pressure. Water boils at 212 F

  1. AN EVALUATION OF THE WILDLIFE IMPACTS OF OFFSHORE WIND DEVELOPMENT RELATIVE TO FOSSIL FUEL

    E-Print Network [OSTI]

    Firestone, Jeremy

    AN EVALUATION OF THE WILDLIFE IMPACTS OF OFFSHORE WIND DEVELOPMENT RELATIVE TO FOSSIL FUEL POWER. Jarvis All Rights Reserved #12;AN EVALUATION OF THE WILDLIFE IMPACTS OF OFFSHORE WIND DEVELOPMENT in offshore wind energy. I would also like to thank my committee members, Dr. Jeremy Firestone

  2. CO2-Driven Enhanced Gas Recovery and Storage in Depleted Shale Reservoir-A Numerical Simulation Study

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    are driving initiatives to develop carbon management technologies, including geologic sequestration of CO2 of carbon dioxide (CO2), especially from the combustion of fossil fuels, are being linked to global climate change and are of considerable concern. These concerns are driving initiatives to develop carbon

  3. Combustion-Assisted CO2 Capture Using MECC Membranes

    SciTech Connect (OSTI)

    Sherman, Steven R [ORNL; Gray, Dr. Joshua R. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Brinkman, Dr. Kyle S. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Huang, Dr. Kevin [University of South Carolina, Columbia

    2012-01-01T23:59:59.000Z

    Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO2 from power plant flue gas. Here a modified MECC CO2 capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO2 driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO2 in the flue gas may be captured, and a compressed CO2 product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO2 capture system, and has the potential to meet U.S. DOE s goal that deployment of a CO2 capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

  4. 1 Characterization of carbonaceous aerosols outflow from India and 2 Arabia: Biomass/biofuel burning and fossil fuel combustion

    E-Print Network [OSTI]

    Dickerson, Russell R.

    /biofuel burning and fossil fuel combustion 3 S. A. Guazzotti,1 D. T. Suess,1,2 K. R. Coffee,1,3 P. K. Quinn,4 T. S with potassium 17 (indicative of combustion sources), and mass concentration of submicrometer non-sea- 18 salt Peninsula, where dominance of fossil fuel combustion is suggested by 30 results from single

  5. Schewel and Schipper 1 FOSSIL FREIGHT: HOW MUCH FOSSIL FUEL DOES IT TAKE TO MOVE FOSSIL1

    E-Print Network [OSTI]

    Kammen, Daniel M.

    understanding of the full cost of5 fossil fuel reliance, and help create the foundation for models to analyzeSchewel and Schipper 1 FOSSIL FREIGHT: HOW MUCH FOSSIL FUEL DOES IT TAKE TO MOVE FOSSIL1 FUEL?2.schewel@berkeley.edu)13 UC Berkeley Energy and Resources Group14 310 Barrows Hall15 UC Berkeley16 Berkeley CA 9470917 Cell

  6. METHODOLOGIES FOR REVIEW OF THE HEALTH AND SAFETY ASPECTS OF PROPOSED NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL SITES AND FACILITIES. VOLUME 9 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01T23:59:59.000Z

    IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy and Environment

  7. Fossil fuel gasification technical evaluation services. Topical report 1978-80

    SciTech Connect (OSTI)

    Detman, R.F.

    1982-12-30T23:59:59.000Z

    The Exxon, Mountain Fuel, Cities Service/Rockwell, Westinghouse, BGC slagging Lurgi and Peatgas processes for fossil fuel gasification were evaluated. The Lurgi and HYGAS processes had been evaluated in earlier studies. For producing SNG from coal, only the Westinghouse conceptual design appeared competitive with HYGAS on eastern coal. All coal gasification processes were competitive with or better than Lurgi on eastern coal. The Mountain Fuel process was more costly than Lurgi or HYGAS on a western coal.

  8. The urgency of the development of CO2 capture from ambient air

    E-Print Network [OSTI]

    Venkataraman, Latha

    for review June 1, 2011) CO2 capture and storage (CCS) has the potential to develop into an important tool to address climate change. Given society's present reliance on fossil fuels, widespread adoption of CCS appears indispensable for meeting stringent climate targets. We argue that for conventional CCS to become

  9. Atmospheric inverse modeling to constrain regionalscale CO2 budgets at high spatial and temporal resolution

    E-Print Network [OSTI]

    Michalak, Anna M.

    a simple diagnostic flux model that splits the net ecosystem exchange into its major components of gross stateoftheart data sets for advected background CO2 and anthropogenic fossil fuel emissions as well as highly grid cell, thus permitting description of the surface in a very high resolution. The model is tested

  10. Assessment of a multi-stage underwater vehicle concept using a fossil-fuel Stirling engine

    SciTech Connect (OSTI)

    Reader, G.T.; Potter, I.J. [Univ. of Calgary, Alberta (Canada). Dept. of Mechanical Engineering

    1995-12-31T23:59:59.000Z

    The Stirling Engine because of its inherent closed-cycle operation can be readily modified to work in an airless environment even if the primary source of energy is a fossil fuel. Thus, Stirling engines are well suited for use in the underwater environment and have been operated successfully in manned military submarines since the early 1980s. In recent years fossil fueled Stirling systems have been also proposed for use in small unmanned underwater vehicles (UUVs). However, in this case the need to carry an onboard oxygen supply in a very confined space has presented a number of design difficulties. These are identified in the paper. However, if the oxidant supply to the engine is provided by the membrane extraction of dissolved oxygen from seawater and/or disposable fuel/oxidant pods are used then the UUV Stirling system becomes more attractive. If this latter concept is extended to include multi-stage vehicles then it can be shown that fossil fueled Stirlings could also be put to effective use in long range-long endurance underwater vehicular operations.

  11. Contribution of Ocean, Fossil Fuel, Land Biosphere and Biomass Burning Carbon1 Fluxes to Seasonal and Interannual Variability in Atmospheric CO22

    E-Print Network [OSTI]

    Mahowald, Natalie

    1 Contribution of Ocean, Fossil Fuel, Land Biosphere and Biomass Burning Carbon1 Fluxes to Seasonal et al., 1989].18 Anthropogenic fossil fuel combustion and cement manufacture drive most of the recent by deforestation, discussed below) over the last 50 years. The fossil fuel plus4 cement input, in contrast

  12. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground

    SciTech Connect (OSTI)

    Oldenburg

    2009-07-30T23:59:59.000Z

    July 21, 2009 Berkeley Lab summer lecture: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  13. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    SciTech Connect (OSTI)

    Oldenburg, Curtis M. (LBNL Earth Sciences Division) [LBNL Earth Sciences Division

    2009-07-21T23:59:59.000Z

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  14. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Oldenburg, Curtis M [LBNL Earth Sciences Division

    2011-04-28T23:59:59.000Z

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  15. Co2 geological sequestration

    SciTech Connect (OSTI)

    Xu, Tianfu

    2004-11-18T23:59:59.000Z

    Human activities are increasingly altering the Earth's climate. A particular concern is that atmospheric concentrations of carbon dioxide (CO{sub 2}) may be rising fast because of increased industrialization. CO{sub 2} is a so-called ''greenhouse gas'' that traps infrared radiation and may contribute to global warming. Scientists project that greenhouse gases such as CO{sub 2} will make the arctic warmer, which would melt glaciers and raise sea levels. Evidence suggests that climate change may already have begun to affect ecosystems and wildlife around the world. Some animal species are moving from one habitat to another to adapt to warmer temperatures. Future warming is likely to exceed the ability of many species to migrate or adjust. Human production of CO{sub 2} from fossil fuels (such as at coal-fired power plants) is not likely to slow down soon. It is urgent to find somewhere besides the atmosphere to put these increased levels of CO{sub 2}. Sequestration in the ocean and in soils and forests are possibilities, but another option, sequestration in geological formations, may also be an important solution. Such formations could include depleted oil and gas reservoirs, unmineable coal seams, and deep saline aquifers. In many cases, injection of CO2 into a geological formation can enhance the recovery of hydrocarbons, providing value-added byproducts that can offset the cost of CO{sub 2} capture and sequestration. Before CO{sub 2} gas can be sequestered from power plants and other point sources, it must be captured. CO{sub 2} is also routinely separated and captured as a by-product from industrial processes such as synthetic ammonia production, H{sub 2} production, and limestone calcination. Then CO{sub 2} must be compressed into liquid form and transported to the geological sequestration site. Many power plants and other large emitters of CO{sub 2} are located near geological formations that are amenable to CO{sub 2} sequestration.

  16. POWER PLANT RELIABILITY-AVAILABILITY AND STATE REGULATION. VOLUME 7 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01T23:59:59.000Z

    and Related Standards for Fossil-Fuel and Geo- thermal Powerposed Nuclear, Geothermal, and Fossil-Fuel Sites and Facili-NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN

  17. EA-1778: Proposed Rule, 10 CFR 433 and 435, Energy Conservation and Fossil Fuel-Generated Energy

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of DOE's Proposed Rule, 10 CFR Part 433, Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Commercial and Multi-Family High-Rise Residential Buildings and 10 CFR Part 435, Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Low-Rise Residential Buildings.

  18. Liquid fossil-fuel technology. Quarterly technical progress report, January-March 1983

    SciTech Connect (OSTI)

    Linville, B. (ed.)

    1983-07-01T23:59:59.000Z

    Accomplishments for the quarter ending March 1983 are presented under the following headings: liquid fossil fuel cycle, processing, utilization, and project integration and technology transfer. Feature articles for this quarter are: (1) abandoned oil field reports issued; (2) oilfield water data bank report published; (3) microbial enhanced recovery report issued; (4) polymer-augmented project could be economic today; (5) carbon dioxide EOR estimates given; (6) BETC passes 65th milestone; and (7) fifty achievements for fifty years (1918-1968). BETC publications are also listed. (ATT)

  19. Projecting human development and CO2 emissions

    E-Print Network [OSTI]

    Costa, Lus; Kropp, Jrgen P

    2012-01-01T23:59:59.000Z

    We estimate cumulative CO2 emissions during the period 2000 to 2050 from developed and developing countries based on the empirical relationship between CO2 per capita emissions (due to fossil fuel combustion and cement production) and corresponding HDI. In order to project per capita emissions of individual countries we make three assumptions which are detailed below. First, we use logistic regressions to fit and extrapolate the HDI on a country level as a function of time. This is mainly motivated by the fact that the HDI is bounded between 0 and 1 and that it decelerates as it approaches 1. Second, we employ for individual countries the correlations between CO2 per capita emissions and HDI in order to extrapolate their emissions. This is an ergodic assumption. Third, we let countries with incomplete data records evolve similarly as their close neighbors (in the emissions-HDI plane, see Fig. 1 in the main text) with complete time series of CO2 per capita emissions and HDI. Country-based emissions estimates a...

  20. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    CALEB CalTrans CARB CEC CEM CHP CO 2 DMV EEA U.S. EIA EMFAC2 2.1 Electricity and CHPemissions CO 2 (Mt) Electricity/CHP* coal petroleum products

  1. Long-term tradeoffs between nuclear- and fossil-fuel burning

    SciTech Connect (OSTI)

    Krakowski, R.A.

    1996-12-31T23:59:59.000Z

    A global energy/economics/environmental (E{sup 3}) model has been adapted with a nuclear energy/materials model to understand better {open_quotes}top-level{close_quotes}, long-term trade offs between civilian nuclear power, nuclear-weapons proliferation, fossil-fuel burning, and global economic welfare. Using a {open_quotes}business-as-usual{close_quotes} (BAU) point-of-departure case, economic, resource, proliferation-risk implications of plutonium recycle in LAIRs, greenhouse-gas-mitigating carbon taxes, and a range of nuclear energy costs (capital and fuel) considerations have been examined. After describing the essential elements of the analysis approach being developed to support the Los Alamos Nuclear Vision Project, preliminary examples of parametric variations about the BAU base-case scenario are presented. The results described herein represent a sampling from more extensive results collected in a separate report. The primary motivation here is: (a) to compare the BAU basecase with results from other studies; (b) to model on a regionally resolved global basis long-term (to year {approximately}2100) evolution of plutonium accumulation in a variety of forms under a limited range of fuel-cycle scenarios; and (c) to illustrate a preliminary connectivity between risks associated with nuclear proliferation and fossil-fuel burning (e.g., greenhouse-gas accumulations).

  2. Characterization and Simulation of ECBM: History Matching of Forecasting CO2 Sequestration in Marshal County, West Virginia.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    . Bromhal, National Energy Technology Laboratory Copyright 2010, Society of Petroleum Engineers This paper injection. Introduction Sustain economic growth by providing sufficient energy and controlling the CO2 emissions as byproduct of producing Energy from fossil fuels is one of the most challenging tasks

  3. A Framework for Environmental Assessment of CO2 Capture and Storage Systems

    E-Print Network [OSTI]

    Sathre, Roger

    2013-01-01T23:59:59.000Z

    the benefits of fossil fuel energy sources while avoidingquantity of energy stored underground in fossil fuels willworlds primary energy [1]. Fossil fuels are used to produce

  4. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P. (University of Hartford, West Hartford, CT); Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01T23:59:59.000Z

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energys National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of staining upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  5. RADIOLOGICAL EMERGENCY RESPONSE PLANNING FOR NUCLEAR POWER PLANTS IN CALIFORNIA. VOLUME 4 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Yen, W.W.S.

    2010-01-01T23:59:59.000Z

    IMPACTS OF NUCLEAR. GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy and Environment

  6. CONTROL OF POPULATION DENSITIES SURROUNDING NUCLEAR POWER PLANTS. VOLUME 5 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, jA.V.

    2010-01-01T23:59:59.000Z

    IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy and Environment

  7. A REVIEW OF LIGHT-WATER REACTOR SAFETY STUDIES. VOLUME 3 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01T23:59:59.000Z

    IMPACTS OF FOSSIL-FUEL NUCLEAR, GEOTHERMAL, AND ELECTRIC GENERATION IN CALIFORNIA Energy and Environment

  8. POWER PLANT RELIABILITY-AVAILABILITY AND STATE REGULATION. VOLUME 7 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01T23:59:59.000Z

    IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy and Environment

  9. A REVIEW OF AIR QUALITY MODELING TECHNIQUES. VOLUME 8 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Rosen, L.C.

    2010-01-01T23:59:59.000Z

    IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy and Environment

  10. An overview of alternative fossil fuel price and carbon regulation scenarios

    E-Print Network [OSTI]

    Wiser, Ryan; Bolinger, Mark

    2004-01-01T23:59:59.000Z

    s (EIA) Annual Energy Outlook (AEO) projections for naturalcontained in each Annual Energy Outlook. Results from AEOGlobal Insight (2003) Annual Energy Outlook 2004 (2003) Year

  11. CO2 sequestration | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 sequestration CO2 sequestration Leads No leads are available at this time. Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable Atomically Dispersed Palladium on...

  12. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    E-Print Network [OSTI]

    Zhou, Nan

    2011-01-01T23:59:59.000Z

    GW coal-fired power plants, and annual CO 2 emissions wouldGW coal-fired power plants, and annual CO 2 emissions would

  13. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    U.S. EPA), 2005.. Emission Inventory Improvement Program,National Greenhouse Gas Inventories, Annex 8A.2: Reportingin the fossil CO 2 emissions inventories, and verify whether

  14. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01T23:59:59.000Z

    all commercial primary energy: fossil fuels, nuclear, andintensity of energy embodied in trade fossil fuels Kayafossil fuel inputs (22). We further adjusted regional energy

  15. Byrne, et al., 2008. In Peter Droege eds. Urban Energy Transition: From Fossil Fuels to Renewable Power.

    E-Print Network [OSTI]

    Delaware, University of

    Byrne, et al., 2008. In Peter Droege eds. Urban Energy Transition: From Fossil Fuels to Renewable to significantly increase the share of such emissions attributed to Southern countries. Nevertheless, on a per and industrializing countries are derived by assuming the same trend for change in the national shares of emissions

  16. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/02

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions. (DMC)

  17. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/01

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985 and 2025. Residential, commercial, and industrial energy demands are forecast as well as the impacts of energy technology implementation and market penetration using a set of energy technology assumptions. (DMC)

  18. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/03

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions.

  19. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect (OSTI)

    Sharon Falcone Miller; Bruce G. Miller [Pennsylvania State University, University Park, PA (United States). Energy Institute

    2007-12-15T23:59:59.000Z

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  20. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    fuel combustion are attributable to natural gas consumption.Combustion in 2004 (million metric tonne (Mt) of CO 2 ) Fuel Motor Gasoline Natural Gascombustion in 2004. California relies heavily on imported natural gas.

  1. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01T23:59:59.000Z

    International Energy Agency (OECD/IEA): CO 2 emissions fromcombustion, 2010 edition, OECD/IEA, Paris, 2010. Kashiwagi,data are generated by the IEA and are a no- table feature of

  2. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    SciTech Connect (OSTI)

    Michael Petrik; Robert Ruhl

    2012-03-31T23:59:59.000Z

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled ??Small Scale SOFC Demonstration using Bio-based and Fossil Fuels.? Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  3. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

    1997-01-01T23:59:59.000Z

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  4. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    SciTech Connect (OSTI)

    Dale, Virginia H [ORNL; Parish, Esther S [ORNL; Kline, Keith L [ORNL

    2015-01-01T23:59:59.000Z

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most of which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.

  5. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05T23:59:59.000Z

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  6. BNL | CO2 Laser

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Laser The ATF is one of the only two facilities worldwide operating picosecond, terawatt-class CO2 lasers. Our laser system consists of a picoseconds pulse-injector based on...

  7. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Robert Dilmore, Peng Lu, Douglas Allen, Yee Soong,*, Sheila Hedges, Jaw K. Fu,4

    E-Print Network [OSTI]

    Zhu, Chen

    sources (such as fossil fuel-fired power plants) and the long-term storage of CO2 in underground, brine-b utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester

  8. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Appendix 1- List of U.S. EIA Energy Survey Form Form NumberEnergy Consumption Survey EIA-851A Domestic Uranium858 Uranium Marketing Annual Survey EIA-860 Annual Electric

  9. Regulation, Allocation, and Leakage in Cap-and-Trade Markets for CO2

    E-Print Network [OSTI]

    Bushnell, Jim B; Chen, Yihsu

    2009-01-01T23:59:59.000Z

    Daniel Kahn. Allocation of co2 emissions al- lowances in theRasmussen. Allocation of co2 emissions permits: A generalthe aggregate annual CO2 emissions for each of the key

  10. Improving the photocatalytic reduction of CO2 to CO through immobilization of a molecular Re catalyst on TiO2

    E-Print Network [OSTI]

    Windle, Christopher D.; Pastor, Ernest; Reynal, Anna; Whitwood, Adrian C.; Vaynzof, Yana; Durrant, James R.; Perutz, Robin N.; Reisner, Erwin

    2015-01-29T23:59:59.000Z

    and utilisation (CCU) tech- nologies. The green conversion of CO2 into the energy carrier CO is particularly attractive as it could be used, in combination with H2, as an important chemical feedstock to form syngas, and replace the steam reforming of fossil fuels... in the petro- chemical industry. Sustainable syngas provides a direct route to a greener chemical industry sector and the generation of transport fuel through FischerTropsch chemistry.[1] Photoelectrocatalytic CO2 reduction has been achieved on semiconductors...

  11. Nuclear Energy R&D Imperative 3: Enable a Transition Away from Fossil Fuel in the Transportation and Industrial Sectors

    SciTech Connect (OSTI)

    David Petti; J. Stephen Herring

    2010-03-01T23:59:59.000Z

    As described in the Department of Energy Office of Nuclear Energys Nuclear Energy R&D Roadmap, nuclear energy can play a significant role in supplying energy for a growing economy while reducing both our dependence on foreign energy supplies and emissions from the burning of fossil fuels. The industrial and transportation sectors are responsible for more than half of the greenhouse gas emissions in the U.S., and imported oil supplies 70% of the energy used in the transportation sector. It is therefore important to examine the various ways nuclear energy can facilitate a transition away from fossil fuels to secure environmentally sustainable production and use of energy in the transportation and manufacturing industry sectors. Imperative 3 of the Nuclear Energy R&D Roadmap, entitled Enable a Transition Away from Fossil Fuels by Producing Process Heat for use in the Transportation and Industrial Sectors, addresses this need. This document presents an Implementation Plan for R&D efforts related to this imperative. The expanded use of nuclear energy beyond the electrical grid will contribute significantly to overcoming the three inter-linked energy challenges facing U.S. industry: the rising and volatile prices for premium fossil fuels such as oil and natural gas, dependence on foreign sources for these fuels, and the risks of climate change resulting from carbon emissions. Nuclear energy could be used in the industrial and transportation sectors to: Generate high temperature process heat and electricity to serve industrial needs including the production of chemical feedstocks for use in manufacturing premium fuels and fertilizer products, Produce hydrogen for industrial processes and transportation fuels, and Provide clean water for human consumption by desalination and promote wastewater treatment using low-grade nuclear heat as a useful additional benefit. Opening new avenues for nuclear energy will significantly enhance our nations energy security through more effective utilization of our countrys resources while simultaneously providing economic stability and growth (through predictable energy prices and high value jobs), in an environmentally sustainable and secure manner (through lower land and water use, and decreased byproduct emissions). The reduction in imported oil will also increase the retention of wealth within the U.S. economy while still supporting economic growth. Nuclear energy is the only non-fossil fuel that has been demonstrated to reliably supply energy for a growing industrial economy.

  12. FutureGen: Stepping-Stone to Sustainable Fossil-Fuel Power Generation

    SciTech Connect (OSTI)

    Zitney, S.E.

    2006-11-01T23:59:59.000Z

    This presentation will highlight the U.S. Department of Energy's FutureGen Initiative. The nearly $1 billion government-industry project is a stepping-stone toward future coal-fired power plants that will produce hydrogen and electricity with zero-emissions, including carbon dioxide. The 275-megawatt FutureGen plant will initiate operations around 2012 and employ advanced coal gasification technology integrated with combined cycle electricity generation, hydrogen production, and carbon capture and sequestration. The initiative is a response to a presidential directive to develop a hydrogen economy by drawing upon the best scientific research to address the issue of global climate change. The FutureGen plant will be based on cutting-edge power generation technology as well as advanced carbon capture and sequestration systems. The centerpiece of the project will be coal gasification technology that can eliminate common air pollutants such as sulfur dioxide and nitrogen oxides and convert them to useable by-products. Gasification will convert coal into a highly enriched hydrogen gas, which can be burned much more cleanly than directly burning the coal itself. Alternatively, the hydrogen can be used in a fuel cell to produce ultra-clean electricity, or fed to a refinery to help upgrade petroleum products. Carbon sequestration will also be a key feature that will set the Futuregen plant apart from other electric power plant projects. The initial goal will be to capture 90 percent of the plant's carbon dioxide, but capture of nearly 100 percent may be possible with advanced technologies. Once captured, the carbon dioxide will be injected as a compressed fluid deep underground, perhaps into saline reservoirs. It could even be injected into oil or gas reservoirs, or into unmineable coal seams, to enhance petroleum or coalbed methane recovery. The ultimate goal for the FutureGen plant is to show how new technology can eliminate environmental concerns over the future use of coal--the most abundant fossil fuel in the United States with supplies projected to last 250 years. FutureGen's co-production of power and hydrogen will also serve as a stepping-stone to an environmentally sustainable energy future.

  13. annual performance assessment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Symposium, June 4-7, 2006 ASSESSMENT OF SHOULDER-BED, INVASION, AND LAMINATION Fossil Fuels Websites Summary: Annual Logging Symposium held in Veracruz, Mexico, June 4-7, 2006....

  14. CO2.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    STORAGE & ENHANCED OIL RECOVERY Objective R MOTC can play a signifi cant role in carbon dioxide (CO 2 ) storage and enhanced oil recovery technology development and fi eld...

  15. EMSL - CO2 sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    co2-sequestration en Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable Atomically Dispersed Palladium on Alumina. http:www.emsl.pnl.govemslwebpublications...

  16. Seasonal and latitudinal variability of troposphere ?14CO2: Post bomb contributions from fossil fuels, oceans, the stratosphere, and the terrestrial biosphere

    E-Print Network [OSTI]

    Randerson, J. T; Enting, I. G; Schuur, E. A. G; Caldeira, K.; Fung, I. Y

    2002-01-01T23:59:59.000Z

    Sci. , 57(1), 3 16, 2000. Glasstone, S. , and P. J. Dolan,Johnston et al. , 1976; Glasstone and Dolan, 1977]. As manyinto the lower stratosphere [Glasstone and Dolan, 1977]. The

  17. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    Antarctica Key Biscayne FL Kumukahi HA Kazakhstan SaryTau Kazakhstan Plateau Wisconsin Tower La Jolla CA Lampedusa

  18. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    Storhofdi Iceland Canary Islands Jubany Antarctica KeyGuam Halley Bay Antarctica Canary Islands Key Biscayne FL

  19. Separation and Capture of CO2 from Large Stationary Sources and Sequestration in Geological Formations: A Summary of the 2003 Critical Review

    SciTech Connect (OSTI)

    White, C.M.; Strazisar, B.R.; Granite, E.J.; Hoffman, J.S.; Pennline, H.W.

    2003-06-01T23:59:59.000Z

    Increasing amounts of carbon dioxide (CO2) in the atmosphere, and the resulting global warming effect, is a major air quality concern. CO2 is the most abundant greenhouse gas emitted by fossil-fuel combustion for power generation, transportation, and heating. Reducing worldwide emissions of CO2 will require many mitigation measures, including reductions in energy consumption, more efficient use of available energy, renewable energy sources, and carbon sequestration. The feasibility of capturing CO2 from large point sources and subsequent geological sequestration is the subject of this years Critical Review.

  20. An overview of alternative fossil fuel price and carbon regulation scenarios

    SciTech Connect (OSTI)

    Wiser, Ryan; Bolinger, Mark

    2004-10-01T23:59:59.000Z

    The benefits of the Department of Energy's research and development (R&D) efforts have historically been estimated under business-as-usual market and policy conditions. In recognition of the insurance value of R&D, however, the Office of Energy Efficiency and Renewable Energy (EERE) and the Office of Fossil Energy (FE) have been exploring options for evaluating the benefits of their R&D programs under an array of alternative futures. More specifically, an FE-EERE Scenarios Working Group (the Working Group) has proposed to EERE and FE staff the application of an initial set of three scenarios for use in the Working Group's upcoming analyses: (1) a Reference Case Scenario, (2) a High Fuel Price Scenario, which includes heightened natural gas and oil prices, and (3) a Carbon Cap-and-Trade Scenario. The immediate goal is to use these scenarios to conduct a pilot analysis of the benefits of EERE and FE R&D efforts. In this report, the two alternative scenarios being considered by EERE and FE staff--carbon cap-and-trade and high fuel prices--are compared to other scenarios used by energy analysts and utility planners. The report also briefly evaluates the past accuracy of fossil fuel price forecasts. We find that the natural gas prices through 2025 proposed in the FE-EERE Scenarios Working Group's High Fuel Price Scenario appear to be reasonable based on current natural gas prices and other externally generated gas price forecasts and scenarios. If anything, an even more extreme gas price scenario might be considered. The price escalation from 2025 to 2050 within the proposed High Fuel Price Scenario is harder to evaluate, primarily because few existing forecasts or scenarios extend beyond 2025, but, at first blush, it also appears reasonable. Similarly, we find that the oil prices originally proposed by the Working Group in the High Fuel Price Scenario appear to be reasonable, if not conservative, based on: (1) the current forward market for oil, (2) current oil prices, (3) externally generated oil price forecasts, and (4) the historical difficulty in accurately forecasting oil prices. Overall, a spread between the FE-EERE High Oil Price and Reference scenarios of well over $8/bbl is supported by the literature. We conclude that a wide range of carbon regulation scenarios are possible, especially within the time frame considered by EERE and FE (through 2050). The Working Group's Carbon Cap-and-Trade Scenario is found to be less aggressive than many Kyoto-style targets that have been analyzed, and similar in magnitude to the proposed Climate Stewardship Act. The proposed scenario is more aggressive than some other scenarios found in the literature, however, and ignores carbon banking and offsets and does not allow nuclear power to expand. We are therefore somewhat concerned that the stringency of the proposed carbon regulation scenario in the 2010 to 2025 period will lead to a particularly high estimated cost of carbon reduction. As described in more detail later, we encourage some flexibility in the Working Group's ultimate implementation of the Carbon Cap-and-Trade Scenario. We conclude by identifying additional scenarios that might be considered in future analyses, describing a concern with the proposed specification of the High Fuel Price Scenario, and highlighting the possible difficulty of implementing extreme scenarios with current energy modeling tools.

  1. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Administration (U.S. EIA), 2005a. Energy Information2003. Annual Coal Report 2004. Washington, DC: EIA. U.S.Administration (U.S. EIA), 2005b. Energy Information

  2. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    EI-81, Energy Information Administration, U.S.Department ofTable_ID=293 U.S. Energy Information Administration (U.S.EIA), 2005a. Energy Information Administration, 2003. Annual

  3. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    2006. California Crude Oil Production and Imports AprilProduction Report (Quarterly) EIA-856 Monthly Foreign Crude OilProduction Annual Report of Natural and Supplemental Gas Supply and Disposition Domestic Crude Oil

  4. Estimates of health risks associated with radionuclide emissions from fossil-fueled steam-electric generating plants. Final report

    SciTech Connect (OSTI)

    Nelson, C.

    1995-08-01T23:59:59.000Z

    Under the Title III, Section 112 of the 1990 Clean Air Act Amendment, Congress directed the U.S. Environmental Protection Agency (EPA) to perform a study of the hazards to public resulting from pollutants emitted by electric utility system generating units. Radionuclides are among the groups of pollutants listed in the amendment. This report updates previously published data and estimates with more recently available information regarding the radionuclide contents of fossil fuels, associated emissions by steam-electric power plants, and potential health effects to exposed population groups.

  5. Assessing the health risks of natural CO2 seeps in Italy

    SciTech Connect (OSTI)

    Roberts, J.J.; Wood, R.A.; Haszeldine, R.S. [Scottish Carbon Capture and Storage, School of GeoSciences, Grant Institute, University of Edinburgh, West Mains Road, Edinburgh EH9 3JW, Scotland (United Kingdom)

    2011-10-04T23:59:59.000Z

    Industrialized societies which continue to use fossil fuel energy sources are considering adoption of Carbon Capture and Storage (CCS) technology to meet carbon emission reduction targets. Deep geological storage of CO2 onshore faces opposition regarding potential health effects of CO2 leakage from storage sites. There is no experience of commercial scale CCS with which to verify predicted risks of engineered storage failure. Studying risk from natural CO2 seeps can guide assessment of potential health risks from leaking onshore CO2 stores. Italy and Sicily are regions of intense natural CO2 degassing from surface seeps. These seeps exhibit a variety of expressions, characteristics (e.g., temperature/ flux), and location environments. Here we quantify historical fatalities from CO2 poisoning using a database of 286 natural CO2 seeps in Italy and Sicily. We find that risk of human death is strongly influenced by seep surface expression, local conditions (e.g., topography and wind speed), CO2 flux, and human behavior. Risk of accidental human death from these CO2 seeps is calculated to be 10-8 year-1 to the exposed population. This value is significantly lower than that of many socially accepted risks. Seepage from future storage sites is modeled to be less than Italian natural flux rates. With appropriate hazard management, health risks from unplanned seepage at onshore storage sites can be adequately minimized.

  6. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    IP [2012] 7 C O 2 (CO2) . CO2 amine methanol, ether . Amine amine CO2 CO2 .Amine CO2 (functional group) amine amine+ +promoter .Amine CO2 CO2 . . , methanol ether methanol, ether promoter CO2 CO2 H2S, COS CO2 . Methanol rectisol process, di-methylene ether polypropylene glycol selexol (-30oC) . CO2

  7. TransCom 3 inversion intercomparison: Impact of transport model errors on the interannual variability of regional CO 2 fluxes, 1988-2003

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    dioxide emissions from fossil fuel consumption and cementthe consumption and flaring of fossil fuels, 1980 present,of the increase: fossil fuel burning and deforestation.

  8. Geologic carbon sequestration as a global strategy to mitigate CO2 emissions: Sustainability and environmental risk

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01T23:59:59.000Z

    the bulk of its energy from fossil fuel in a manner thatabove business-as-usual fossil-fuel energy use. Estimates ofenergy is considered cheap enough to replace fossil fuels.

  9. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01T23:59:59.000Z

    Patel M (2009) Non-energy use of fossil fuels and resulting2000, global non-energy use of fossil fuels was equivalentanalyzing non-energy uses of fossil fuels as petrochemical

  10. Radiative forcing and temperature response to changes in urban albedos and associated CO2 offsets

    E-Print Network [OSTI]

    Menon, Surabi

    2010-01-01T23:59:59.000Z

    if the energy supply is from fossil fuels. The objective ofIf this energy supply were from fossil fuels, one mightdemand (if energy supplied is from fossil fuels) for cooling

  11. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    E-Print Network [OSTI]

    Zhou, Nan

    2010-01-01T23:59:59.000Z

    electricity savings would be 5450 TWh and CO2 emissions inelectricity savings would be 5450 TWh and annual CO2 emissionselectricity consumption could be reduced by 9503 TWh, and CO2 emissions

  12. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    E-Print Network [OSTI]

    Zhou, Nan

    2010-01-01T23:59:59.000Z

    2050 China Energy and CO2 Emissions Report (in Chinese) (the energy saving and CO2 emission reduction potential of9503 TWh, and annual CO2 emissions would be 16% lower than

  13. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    E-Print Network [OSTI]

    Zhou, Nan

    2010-01-01T23:59:59.000Z

    energy saving and CO2 emission reduction potential of theTWh and annual CO2 emissions reduction would be 35% lowerwould result in a CO2 emissions reduction of over 9.1

  14. What are the likely roles of fossil fuels in the next 15, 50, and 100 years, with or without active controls on greenhouse gas emissions

    SciTech Connect (OSTI)

    Kane, R.L. (USDOE Assistant Secretary for Fossil Energy, Washington, DC (USA)); South, D.W. (Argonne National Lab., IL (USA))

    1990-01-01T23:59:59.000Z

    Since the industrial revolution, the production and utilization of fossil fuels have been an engine driving economic and industrial development in many countries worldwide. However, future reliance on fossil fuels has been questioned due to emerging concerns about greenhouse gas (GHG) emissions, particularly carbon dioxide (CO{sub 2}), and its potential contribution to global climate change (GCC). While substantial uncertainties exist regarding the ability to accurately predict climate change and the role of various greenhouse gases, some scientists and policymakers have called for immediate action. As a result, there have been many proposals and worldwide initiatives to address the perceived problem. In many of these proposals, the premise is that CO{sub 2} emissions constitute the principal problem, and, correspondingly, that fossil-fuel combustion must be curtailed to resolve this problem. This paper demonstrates that the worldwide fossil fuel resource base and infrastructure are extensive and thus, will continue to be relied on in developed and developing countries. Furthermore, in the electric generating sector (the focus of this paper), numerous clean coal technologies (CCTs) are currently being demonstrated (or are under development) that have higher conversion efficiencies, and thus lower CO{sub 2} emission rates than conventional coal-based technologies. As these technologies are deployed in new power plant or repowering applications to meet electrical load growth, CO{sub 2} (and other GHG) emission levels per unit of electricity generated will be lower than that produced by conventional fossil-fuel technologies. 37 refs., 14 figs., 11 tabs.

  15. renewable sources of power. Demand for fossil fuels surely will overrun supply s

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2, 2015Visiting8.pdfand Characterization of aHome *NRC FORM 741OFrenewable

  16. Radiative forcing and temperature response to changes in urban albedos and associated CO2 offsets

    E-Print Network [OSTI]

    Menon, Surabi

    2010-01-01T23:59:59.000Z

    energy demand (if energy supplied is from fossil fuels) fordemand for energy to cool interior spaces in summer. If this energy supply were from fossil fuels,

  17. Abstract Atmospheric CO2 partial pressure (pCO2) was as low as 18 Pa during the Pleistocene and is projected to

    E-Print Network [OSTI]

    Antonovics, Janis

    Abstract Atmospheric CO2 partial pressure (pCO2) was as low as 18 Pa during the Pleistocene and is projected to increase from 36 to 70 Pa CO2 before the end of the 21st century. High pCO2 often increases the growth and repro- duction of C3 annuals, whereas low pCO2 decreases growth and may reduce or prevent

  18. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01T23:59:59.000Z

    In almost all cases, the emissions related to traded fuelsextraction (F Er ) and production (F Pr ) emissions (i.e. ,the net effect of emissions from traded fossil fuels; Top),

  19. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect (OSTI)

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30T23:59:59.000Z

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  20. Development of Nano-crystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases

    SciTech Connect (OSTI)

    Hai Xiao; Junhang Dong; Jerry Lin; Van Romero

    2011-12-31T23:59:59.000Z

    This is a final technical report for the first project year from July 1, 2005 to Jan 31, 2012 for DoE/NETL funded project ??DE-FC26-05NT42439: Development of Nanocrystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases.? This report summarizes the technical progresses and achievements towards the development of novel nanocrystalline doped ceramic material-enabled optical fiber sensors for in situ and real time monitoring the gas composition of flue or hot gas streams involved in fossil-fuel based power generation and hydrogen production.

  1. Electrolysis byproduct D2O provides a third way to mitigate CO2

    SciTech Connect (OSTI)

    Schenewerk, William Ernest [self, Los Angeles, CA (United States)

    2009-09-01T23:59:59.000Z

    Rapid atomic power deployment may be possible without using fast breeder reactors or making undue demands on uranium resource. Using by-product D2O and thorium-U233 in CANDU and RBMK piles may circumvent need for either fast breeder reactors or seawater uranium. Atmospheric CO2 is presently increasing 2.25%/year in proportion to 2.25%/year exponential fossil fuel consumption increase. Roughly 1/3 anthropologic CO2 is removed by various CO2 sinks. CO2 removal is modelled as being proportional to 45-year-earlier CO2 amount above 280 ppm-C Water electrolysis produces roughly 0.1 kg-D20/kWe-y. Material balance assumes each electrolysis stage increases D2O bottoms concentration times 3. Except for first two electrolysis stages, all water from hydrogen consumption is returned to electrolysis. The unique characteristic of this process is the ability to economically burn all deuterium-enriched H2 in vehicles. Condensate from vehicles returns to appropriate electrolysis stage. Fuel cell condensate originally from reformed natural gas may augment second-sage feed. Atomic power expansion is 5%/year, giving 55000 GWe by 2100. World primary energy increases 2.25%/y, exceeding 4000 EJ/y by 2100. CO2 maximum is roughly 600 ppm-C around year 2085. CO2 declines back below 300 ppm-C by 2145 if the 45-year-delay seawater sink remains effective.

  2. Root-derived CO2 efflux via xylem stream rivals soil CO2 efflux.

    SciTech Connect (OSTI)

    Aubrey, Doug, P.; Teskey, Robert, O.

    2009-07-01T23:59:59.000Z

    Respiration consumes a large portion of annual gross primary productivity in forest ecosystems and is dominated by belowground metabolism. Here, we present evidence of a previously unaccounted for internal CO2 flux of large magnitude from tree roots through stems. If this pattern is shown to persist over time and in other forests, it suggests that belowground respiration has been grossly underestimated. Using an experimental Populus deltoides plantation as a model system, we tested the hypothesis that a substantial portion of the CO2 released from belowground autotrophic respiration remains within tree root systems and is transported aboveground through the xylem stream rather than diffusing into the soil atmosphere. On a daily basis, the amount of CO2 that moved upward from the root system into the stem via the xylem stream (0.26 mol CO2 m?2 d?1) rivalled that which diffused from the soil surface to the atmosphere (0.27 mol CO2 m?2 d?1). We estimated that twice the amount of CO2 derived from belowground autotrophic respiration entered the xylem stream as diffused into the soil environment. Our observations indicate that belowground autotrophic respiration consumes substantially more carbohydrates than previously recognized and challenge the paradigm that all root-respired CO2 diffuses into the soil atmosphere.

  3. Separation of CO2 from flue gas using electrochemical cells

    SciTech Connect (OSTI)

    Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

    2010-06-01T23:59:59.000Z

    ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

  4. 1M. Panahi, S. Skogestad ' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances' Optimal Operation of a CO2 Capturing

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1M. Panahi, S. Skogestad ' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances Mehdi Panahi Sigurd Skogestad 18.10.2011 AIChE Annual Meeting #12;2M. Panahi, S. Skogestad ' Optimal Operation of a CO2

  5. Implications of ``peak oil'' for atmospheric CO2 and climate Pushker A. Kharecha1

    E-Print Network [OSTI]

    to exploit these reserves, especially unconventional fossil fuels and those located in extreme or pristine exceeding about 450 ppm by 2100, provided that emissions from coal, unconventional fossil fuels, and land or unconventional fossil fuels while clean technologies are being developed for the era ``beyond fossil fuels''. We

  6. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01T23:59:59.000Z

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  7. atmospheric co2 sensing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration,...

  8. atmospheric co2 consequences: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration,...

  9. atmospheric co2 signals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration,...

  10. atmospheric co2 emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration,...

  11. Annual energy review 2003

    SciTech Connect (OSTI)

    none,

    2004-09-30T23:59:59.000Z

    The Annual Energy Review 2003 is a statistical history of energy activities in the United States in modern times. Data are presented for all major forms of energy by production (extraction of energy from the earth, water, and other parts of the environment), consumption by end-user sector, trade with other nations, storage changes, and pricing. Much of the data provided covers the fossil fuelscoal, petroleum, and natural gas. Fossil fuels are natures batteries; they have stored the suns energy over millennia past. It is primarily that captured energy that we are drawing on today to fuel the activities of the modern economy. Data in this report measure the extraordinary expansion of our use of fossil fuels from 29 quadrillion British thermal units (Btu) in 1949 to 84 quadrillion Btu in 2003. In recent years, fossil fuels accounted for 86 percent of all energy consumed in the United States. This report also records the development of an entirely new energy industrythe nuclear electric power industry. The industry got its start in this country in 1957 when the Shippingport, Pennsylvania, nuclear electric power plant came on line. Since that time, the industry has grown to account for 20 percent of our electrical output and 8 percent of all energy used in the country. Renewable energy is a third major category of energy reported in this volume. Unlike fossil fuels, which are finite in supply, renewable energy is essentially inexhaustible because it can be replenished. Types of energy covered in the renewable category include conventional hydroelectric power, which is power derived from falling water; wood; waste; alcohol fuels; geothermal; solar; and wind. Together, these forms of energy accounted for about 6 percent of all U.S. energy consumption in recent years.

  12. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    CO 2 TRANSPORT IN CALIFORNIA EIA (2003), State energy dataBlasing et al. , 2004; EIA, 2003] for 2002. Fossil CO 2

  13. A Future for Fossil Fuel By JOHN DEUTCH and ERNEST MONIZ March 15, 2007; Page A17

    E-Print Network [OSTI]

    Deutch, John

    much "cleaner" generation of electricity from coal since the Clean Air Act of 1970. Global warming and economic technologies and policies that permit the continued use of coal without increasing CO2 emissions-generating capacity; and (3) new technology to reduce C02 emissions from coal combustion will become economic

  14. House Committee on Natural Resources The Future of Fossil Fuels: Geological and Terrestrial Sequestration of Carbon Dioxide

    E-Print Network [OSTI]

    and Terrestrial Sequestration of Carbon Dioxide Howard Herzog Principal Research Engineer Massachusetts Institute to the Technical Group of the Carbon Sequestration Leadership Forum (see www.cslforum.org). Just two weeks ago, thank you for the opportunity to appear before you today to discuss Carbon Dioxide (CO2) geological

  15. Post-Combustion and Pre-Combustion CO2 Capture Solid Sorbents

    SciTech Connect (OSTI)

    Siriwardane, R.V.; Stevens, R.W.; Robinson, Clark

    2007-11-01T23:59:59.000Z

    Combustion of fossil fuels is one of the major sources of the greenhouse gas CO2. Pressure swing adsorption/sorption (PSA/PSS) and temperature swing adsorption/sorption (TSA/TSS) are some of the potential techniques that could be utilized for removal of CO2 from fuel gas streams. It is very important to develop sorbents to remove CO2 from fuel gas streams that are applicable for a wide range of temperatures. NETL researchers have developed novel CO2 capture sorbents for low, moderate, and high temperature applications. A novel liquid impregnated solid sorbent was developed for CO2 removal in the temperature range of ambient to 60 C. The sorbent is regenerable at 60 80 C. The sorbent formulations were prepared to be suitable for various reactor configurations (i.e., fixed and fluidized bed). Minimum fluidization gas velocities were also determined. Multi-cycle tests conducted in an atmospheric bench scale reactor with simulated flue gas indicated that the sorbent retains its CO2 sorption capacity with a CO2 removal efficiency of approximately 99% and was unaffected by presence of water vapor. The sorbent was subsequently commercially prepared by Sd Chemie to determine the viability of the sorbent for mass production. Subsequent testing showed that the commercially-synthesized sorbent possesses the same properties as the lab-synthesized equivalent. An innovative solid sorbent containing mixture of alkali earth and alkali compounds was developed for CO2 removal at 200 315C from high pressure gas streams suitable for IGCC systems. The sorbent showed very high capacity for CO2 removal from a gas streams containing 28% CO2 at 200 C and at 20 atm during a lab scale reactor test. This sorbent can be regenerated at 20 atm and at 375 C utilizing a gas stream containing steam. High pressure enhanced the CO2 sorption process. Bench scale testing showed consistent capacities and regenerability. A unique high temperature solid sorbent was developed for CO2 capture at temperatures of 500 700C. Bench scale testing of the sorbent yielded very high CO2 capture capacity from a gas stream containing 10% CO2, 30% H2, 15% H2O, and 25% He. Regeneration of the sorbent is possible at 800 900 C.

  16. CO2 interaction with geomaterials.

    SciTech Connect (OSTI)

    Guthrie, George D. (U.S. Department of Energy, Pittsburgh, PA); Al-Saidi, Wissam A. (University of Pittsburgh, Pittsburgh, PA); Jordan, Kenneth D. (University of Pittsburgh, Pittsburgh, PA); Voora, Vamsee, K. (University of Pittsburgh, Pittsburgh, PA); Romanov, Vyacheslav N. (U.S. Department of Energy, Pittsburgh, PA); Lopano, Christina L (U.S. Department of Energy, Pittsburgh, PA); Myshakin, Eugene M. (URS Corporation, Pittsburgh, PA); Hur, Tae Bong (University of Pittsburgh, Pittsburgh, PA); Warzinski, Robert P. (U.S. Department of Energy, Pittsburgh, PA); Lynn, Ronald J. (URS Corporation, Pittsburgh, PA); Howard, Bret H. (U.S. Department of Energy, Pittsburgh, PA); Cygan, Randall Timothy

    2010-09-01T23:59:59.000Z

    This work compares the sorption and swelling processes associated with CO2-coal and CO2-clay interactions. We investigated the mechanisms of interaction related to CO2 adsortion in micropores, intercalation into sub-micropores, dissolution in solid matrix, the role of water, and the associated changes in reservoir permeability, for applications in CO2 sequestration and enhanced coal bed methane recovery. The structural changes caused by CO2 have been investigated. A high-pressure micro-dilatometer was equipped to investigate the effect of CO2 pressure on the thermoplastic properties of coal. Using an identical dilatometer, Rashid Khan (1985) performed experiments with CO2 that revealed a dramatic reduction in the softening temperature of coal when exposed to high-pressure CO2. A set of experiments was designed for -20+45-mesh samples of Argonne Premium Pocahontas No.3 coal, which is similar in proximate and ultimate analysis to the Lower Kittanning seam coal that Khan used in his experiments. No dramatic decrease in coal softening temperature has been observed in high-pressure CO2 that would corroborate the prior work of Khan. Thus, conventional polymer (or 'geopolymer') theories may not be directly applicable to CO2 interaction with coals. Clays are similar to coals in that they represent abundant geomaterials with well-developed microporous structure. We evaluated the CO2 sequestration potential of clays relative to coals and investigated the factors that affect the sorption capacity, rates, and permanence of CO2 trapping. For the geomaterials comparison studies, we used source clay samples from The Clay Minerals Society. Preliminary results showed that expandable clays have CO2 sorption capacities comparable to those of coal. We analyzed sorption isotherms, XRD, DRIFTS (infrared reflectance spectra at non-ambient conditions), and TGA-MS (thermal gravimetric analysis) data to compare the effects of various factors on CO2 trapping. In montmorillonite, CO2 molecules may remain trapped for several months following several hours of exposure to high pressure (supercritical conditions), high temperature (above boiling point of water) or both. Such trapping is well preserved in either inert gas or the ambient environment and appears to eventually result in carbonate formation. We performed computer simulations of CO2 interaction with free cations (normal modes of CO2 and Na+CO2 were calculated using B3LYP / aug-cc-pVDZ and MP2 / aug-cc-pVDZ methods) and with clay structures containing interlayer cations (MD simulations with Clayff potentials for clay and a modified CO2 potential). Additionally, interaction of CO2 with hydrated Na-montmorillonite was studied using density functional theory with dispersion corrections. The sorption energies and the swelling behavior were investigated. Preliminary modeling results and experimental observations indicate that the presence of water molecules in the interlayer region is necessary for intercalation of CO2. Our preliminary conclusion is that CO2 molecules may intercalate into interlayer region of swelling clay and stay there via coordination to the interlayer cations.

  17. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31T23:59:59.000Z

    This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100oC have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800oC. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  18. CO2 Sequestration short course

    SciTech Connect (OSTI)

    DePaolo, Donald J. [Lawrence Berkeley National Laboratory; Cole, David R [The Ohio State University; Navrotsky, Alexandra [University of California-Davis; Bourg, Ian C [Lawrence Berkeley National Laboratory

    2014-12-08T23:59:59.000Z

    Given the publics interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  19. Peak Oil Netherlands Foundation (PONL) was founded in May 2005 by a group of citizens who are concerned about the effects of a premature peak in oil and other fossil fuels production. The main aims of

    E-Print Network [OSTI]

    Keeling, Stephen L.

    are concerned about the effects of a premature peak in oil and other fossil fuels production. The main aims ----------------------------------------------------------------------------------------------------------- 5 - 1) INTRODUCTION PEAKING OF WORLD OIL PRODUCTION-------------------------------------------------------------------------------------------------- - 25 - 7) PEAK OIL NETHERLANDS OIL PRODUCTION & PEAKING OUTLOOK ---------------------------------- - 26

  20. Characterization of coal-derived liquids and other fossil-fuel-related materials employing mass spectrometry. Final report, September 30, 1976-September 29, 1980

    SciTech Connect (OSTI)

    Scheppele, S E

    1982-05-01T23:59:59.000Z

    A document was prepared which assessed the state-of-the art in the mass spectrometric characterization of fossil fuel materials and the relevance of these data to the fossil fuel industry. A Kratos DS50 SM data system was successfully interfaced to a CEC 21-110B mass spectrometer. Communications between the NOVA 3/12 computer in the data system and the OSU central computer were established. A Grant Comparator/Microdensitometer was acquired and made operational. Plans were developed and hardware acquired for interfacing the densitometer to the NOVA 3/12 computer. A quartz direct introduction probe was acquired for the CEC 21-110B. A temperature controller for the probe was acquired and interfaced to the slow speed ADC on the auxillary board in the data system/mass spectrometer interface. The combined FI/EI source was modified to operate in the FD mode and an apparatus was fabricated for conditioning FD emitters. A CSI supergrater 3 was interfaced to the PE 3920 gas chromatograph. The upgraded facility was used to develop mass spectrometric methods for the characterization of fossil fuel materials and to apply methods to the characterization of these materials. Activities included: (1) initial development of field-ionization mass spectrometry for the characterization of saturated hydrocarbons, (2) computerization of the technique of probe microdistillation/mass spectrometry, (3) initation of the development of a new method for the computer assisted assignment of formulas to ion masses, (4) characterization of neutral fractions from a hydrotreated tar-sands oil, and (5) characterization of coal-derived oils and asphaltenes.

  1. Why we need the and in CO2 utilization and storage.

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2013-01-01T23:59:59.000Z

    if our energy supply remains dominated by fossil fuels usedthe energy-climate crisis continues as fossil-fuel useFossil Energy, Office of Sequestration, Hydrogen, and Clean Coal Fuels,

  2. An Investigation of CO2 Sequestration

    E-Print Network [OSTI]

    Saldin, Dilano

    An Investigation of CO2 Sequestration through Mineralization Conference on Sustainable Construction area and increased availability of CO2 for rapid carbonation. The hardened and carbonated materials Slag #12;Carbonation Chemistry Dissolution of CO2 in water. CO2(g) CO2(aq) Formation of carbonic acid

  3. ENHANCING THE ATOMIC-LEVEL UNDERSTANDING OF CO2 MINERAL SEQUESTRATION MECHANISMS VIA ADVANCED COMPUTATIONAL MODELING

    SciTech Connect (OSTI)

    A.V.G. Chizmeshya; M.J. McKelvy; G.H. Wolf; R.W. Carpenter; D.A. Gormley; J.R. Diefenbacher; R. Marzke

    2006-03-01T23:59:59.000Z

    Fossil fuels currently provide 85% of the world's energy needs, with the majority coming from coal, due to its low cost, wide availability, and high energy content. The extensive use of coal-fired power assumes that the resulting CO2 emissions can be vented to the atmosphere. However, exponentially increasing atmospheric CO2 levels have brought this assumption under critical review. Over the last decade, this discussion has evolved from whether exponentially increasing anthropogenic CO2 emissions will adversely affect the global environment, to the timing and magnitude of their impact. A variety of sequestration technologies are being explored to mitigate CO2 emissions. These technologies must be both environmentally benign and economically viable. Mineral carbonation is an attractive candidate technology as it disposes of CO2 as geologically stable, environmentally benign mineral carbonates, clearly satisfying the first criteria. The primary challenge for mineral carbonation is cost-competitive process development. CO2 mineral sequestration--the conversion of stationary-source CO2 emissions into mineral carbonates (e.g., magnesium and calcium carbonate, MgCO3 and CaCO3)--has recently emerged as one of the most promising sequestration options, providing permanent CO2 disposal, rather than storage. In this approach a magnesium-bearing feedstock mineral (typically serpentine or olivine; available in vast quantities globally) is specially processed and allowed to react with CO2 under controlled conditions. This produces a mineral carbonate which (1) is environmentally benign, (2) already exists in nature in quantities far exceeding those that could result from carbonating the world's known fossil fuel reserves, and (3) is stable on a geological time scale. Minimizing the process cost via optimization of the reaction rate and degree of completion is the remaining challenge. As members of the DOE/NETL managed National Mineral Sequestration Working Group we have already significantly improved our understanding of mineral carbonation. Group members at the Albany Research Center have recently shown that carbonation of olivine and serpentine, which naturally occurs over geological time (i.e., 100,000s of years), can be accelerated to near completion in hours. Further process refinement will require a synergetic science/engineering approach that emphasizes simultaneous investigation of both thermodynamic processes and the detailed microscopic, atomic-level mechanisms that govern carbonation kinetics. Our previously funded Phase I Innovative Concepts project demonstrated the value of advanced quantum-mechanical modeling as a complementary tool in bridging important gaps in our understanding of the atomic/molecular structure and reaction mechanisms that govern CO2 mineral sequestration reaction processes for the model Mg-rich lamellar hydroxide feedstock material Mg(OH)2. In the present simulation project, improved techniques and more efficient computational schemes have allowed us to expand and augment these capabilities and explore more complex Mg-rich, lamellar hydroxide-based feedstock materials, including the serpentine-based minerals. These feedstock materials are being actively investigated due to their wide availability, and low-cost CO2 mineral sequestration potential. Cutting-edge first principles quantum chemical, computational solid-state and materials simulation methodology studies proposed herein, have been strategically integrated with our new DOE supported (ASU-Argonne National Laboratory) project to investigate the mechanisms that govern mineral feedstock heat-treatment and aqueous/fluid-phase serpentine mineral carbonation in situ. This unified, synergetic theoretical and experimental approach has provided a deeper understanding of the key reaction mechanisms than either individual approach can alone. We used ab initio techniques to significantly advance our understanding of atomic-level processes at the solid/solution interface by elucidating the origin of vibrational, electronic, x-ray and electron energy loss sp

  4. Conversion of CO2 into Commercial Materials Using Carbon Feedstocks

    SciTech Connect (OSTI)

    Shen, Jian-Ping; Peters, Jonathan; Lail, Marty; Mobley, Paul; Turk, Brian

    2014-05-31T23:59:59.000Z

    In this project, our research focused on developing reaction chemistry that would support using carbon as a reductant for CO2 utilization that would permit CO2 consumption on a scale that would match or exceed anthropomorphic CO2 generation for energy production from fossil fuels. Armed with the knowledge that reactions attempting to produce compounds with an energy content greater than CO2 would be thermodynamically challenged and/or require significant amounts of energy, we developed a potential process that utilized a solid carbon source and recycled the carbon to effectively provide infinite time for the carbon to react. During testing of different carbon sources, we found a wide range of reaction rates. Biomass-derived samples had the most reactivity and coals and petcoke had the lowest. Because we had anticipated this challenge, we recognized that a catalyst would be necessary to improve reaction rates and conversion. From the data analysis of carbon samples, we recognized that alkali metals improved the reaction rate. Through parametric testing of catalyst formulations we were able to increase the reaction rate with petcoke by a factor of >70. Our efforts to identify the reaction mechanism to assist in improving the catalyst formulation demonstrated that the catalyst was catalyzing the extraction of oxygen from CO2 and using this extracted oxygen to oxidize carbon. This was a significant discovery in that if we could modify the catalyst formulation to permit controlled the oxidation, we would have a very power selective oxidation process. With selective oxidation, CO2 utilization could be effective used as one of the process steps in making many of the large volume commodity chemicals that support our modern lifestyles. The key challenges for incorporating these functionalities into the catalyst formulation were to make the oxidation selective and lower the temperature required for catalytic activity. We identified four catalyst families that had the potential to meet these challenges. Initial screening of the catalyst families did show that the reduction/oxidation activity did occur at lower temperatures and that these catalysts were able to cause carbon chain growth as well as CC cleavage. A preliminary techno-economic feasibility of using petcoke/catalyst to produce a CO-rich syngas product was completed and showed significant economic promise. Testing of the different catalyst families demonstrated that Catalyst A was able to stably produce 5 sccm of ethylene/gram of catalyst at 900C for one hour. For dry methane reforming, our Catalyst 4 was able to achieve production rates of > 10 sccm of CO and > 3 sccm of H2 per gram of catalyst at 600C and 350 psig. Based on these developments, the potential for CO2 utilization in the production of large volume commodity chemicals is very promising.

  5. Surface CO2 leakage during the first shallow subsurface CO2 release experiment

    E-Print Network [OSTI]

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2008-01-01T23:59:59.000Z

    numbered 0-6. Plots of F CO2 measured along the surface wellin Figure 2. Figure 2. Log F CO2 maps for measurements madeof soil CO 2 flux (F CO2 ). The surface leakage onset,

  6. Capture and Sequestration of CO2 at the Boise White Paper Mill

    SciTech Connect (OSTI)

    B.P. McGrail; C.J. Freeman; G.H. Beeman; E.C. Sullivan; S.K. Wurstner; C.F. Brown; R.D. Garber; D. Tobin E.J. Steffensen; S. Reddy; J.P. Gilmartin

    2010-06-16T23:59:59.000Z

    This report documents the efforts taken to develop a preliminary design for the first commercial-scale CO2 capture and sequestration (CCS) project associated with biomass power integrated into a pulp and paper operation. The Boise Wallula paper mill is located near the township of Wallula in Southeastern Washington State. Infrastructure at the paper mill will be upgraded such that current steam needs and a significant portion of the current mill electric power are supplied from a 100% biomass power source. A new biomass power system will be constructed with an integrated amine-based CO2 capture plant to capture approximately 550,000 tons of CO2 per year for geologic sequestration. A customized version of Fluor Corporations Econamine Plus carbon capture technology will be designed to accommodate the specific chemical composition of exhaust gases from the biomass boiler. Due to the use of biomass for fuel, employing CCS technology represents a unique opportunity to generate a net negative carbon emissions footprint, which on an equivalent emissions reduction basis is 1.8X greater than from equivalent fossil fuel sources (SPATH and MANN, 2004). Furthermore, the proposed project will offset a significant amount of current natural gas use at the mill, equating to an additional 200,000 tons of avoided CO2 emissions. Hence, the total net emissions avoided through this project equates to 1,100,000 tons of CO2 per year. Successful execution of this project will provide a clear path forward for similar kinds of emissions reduction that can be replicated at other energy-intensive industrial facilities where the geology is suitable for sequestration. This project also represents a first opportunity for commercial development of geologic storage of CO2 in deep flood basalt formations. The Boise paper mill site is host to a Phase II pilot study being carried out under DOEs Regional Carbon Partnership Program. Lessons learned from this pilot study and other separately funded projects studying CO2 sequestration in basalts will be heavily leveraged in developing a suitable site characterization program and system design for permanent sequestration of captured CO2. The areal extent, very large thickness, high permeability in portions of the flows, and presence of multiple very low permeability flow interior seals combine to produce a robust sequestration target. Moreover, basalt formations are quite reactive with water-rich supercritical CO2 and formation water that contains dissolved CO2 to generate carbonate minerals, providing for long-term assurance of permanent sequestration. Sub-basalt sediments also exist at the site providing alternative or supplemental storage capacity.

  7. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01T23:59:59.000Z

    E EPM2- TIP4P2005 PPL- TIP4P2005 Predicted (f) a P ? CO2 2SE? CO2 2SE? CO2 2SE ? CO2 2SE ? CO2 2SE ? CO2 2SE a Surface excess CO

  8. 8, 73737389, 2008 Scientists' CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    ACPD 8, 73737389, 2008 Scientists' CO2 emissions A. Stohl Title Page Abstract Introduction Publications on behalf of the European Geosciences Union. 7373 #12;ACPD 8, 73737389, 2008 Scientists' CO2 substantial emissions of carbon dioxide (CO2). In this pa- per, the CO2 emissions of the employees working

  9. 6, 1092910958, 2006 Regional scale CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    ACPD 6, 1092910958, 2006 Regional scale CO2 flux estimation using radon A. I. Hirsch Title Page Chemistry and Physics Discussions On using radon-222 and CO2 to calculate regional-scale CO2 fluxes A. I (Adam.Hirsch@noaa.gov) 10929 #12;ACPD 6, 1092910958, 2006 Regional scale CO2 flux estimation using

  10. PUBLISHED ONLINE: 3 APRIL 2011 | DOI: 10.1038/NGEO1123 Mangroves among the most carbon-rich forests in

    E-Print Network [OSTI]

    Turner, Monica G.

    ­20% of global anthropogenic carbon dioxide (CO2) emissions, second only to fossil fuel combustion7,8 . Recent in Indonesia increased atmospheric CO2 enrichment by 13­40% over global annual fossil fuel emissions11 of coastal development, aqua- culture expansion and over-harvesting1­4 . Carbon emissions resulting from

  11. International Symposium on Site Characterization for CO2Geological Storage

    SciTech Connect (OSTI)

    Tsang, Chin-Fu

    2006-02-23T23:59:59.000Z

    Several technological options have been proposed to stabilize atmospheric concentrations of CO{sub 2}. One proposed remedy is to separate and capture CO{sub 2} from fossil-fuel power plants and other stationary industrial sources and to inject the CO{sub 2} into deep subsurface formations for long-term storage and sequestration. Characterization of geologic formations for sequestration of large quantities of CO{sub 2} needs to be carefully considered to ensure that sites are suitable for long-term storage and that there will be no adverse impacts to human health or the environment. The Intergovernmental Panel on Climate Change (IPCC) Special Report on Carbon Dioxide Capture and Storage (Final Draft, October 2005) states that ''Site characterization, selection and performance prediction are crucial for successful geological storage. Before selecting a site, the geological setting must be characterized to determine if the overlying cap rock will provide an effective seal, if there is a sufficiently voluminous and permeable storage formation, and whether any abandoned or active wells will compromise the integrity of the seal. Moreover, the availability of good site characterization data is critical for the reliability of models''. This International Symposium on Site Characterization for CO{sub 2} Geological Storage (CO2SC) addresses the particular issue of site characterization and site selection related to the geologic storage of carbon dioxide. Presentations and discussions cover the various aspects associated with characterization and selection of potential CO{sub 2} storage sites, with emphasis on advances in process understanding, development of measurement methods, identification of key site features and parameters, site characterization strategies, and case studies.

  12. Short communication Satellite-derived surface water pCO2 and airsea CO2 fluxes

    E-Print Network [OSTI]

    Short communication Satellite-derived surface water pCO2 and airsea CO2 fluxes in the northern for the estimation of the partial pressure of carbon dioxide (pCO2) and airsea CO2 fluxes in the northern South), respectively, the monthly pCO2 fields were computed. The derived pCO2 was compared with the shipboard pCO2

  13. Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong David W carbon underground), we derive analytic expressions for the value of leaky CO2 storage compared to perfect storage when storage is a marginal component of the energy system. If the annual leak rate is 1

  14. MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE

    E-Print Network [OSTI]

    Foss, Bjarne A.

    MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland Dagfinn Snarheim and control of a semi-closed O2/CO2 gas turbine cycle for CO2 capture. In the first part the process predictive control, Gas turbines, CO2 capture 1. INTRODUCTION Gas turbines are widely used for power

  15. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-08-01T23:59:59.000Z

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  16. Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil fuels such as coal, oil, and gas, have caused a substantial increase

    E-Print Network [OSTI]

    Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil-caused CO2 emissions and to remove CO2 from the atmosphere. 2.0 What is carbon sequestration? The term "carbon sequestration" is used to describe both natural and deliberate CARBON,INGIGATONSPERYEAR 1.5 Fossil

  17. Surface Studies of HSLA Steel after Electrochemical Corrosion in Supercritical CO2-H2O Environment

    SciTech Connect (OSTI)

    Ziomek-Moroz, M. Holcomb, G. Tylczak, J Beck, J Fedkin, M. Lvov, S.

    2011-10-01T23:59:59.000Z

    In aqueous phase saturated with CO2, X-65 sample underwent general corrosion with formation of FeCO3. In supercritical CO2 containing water phase, two major regions are present on the sample surface after the EIS experiment. One region covered with corrosion products identified as FeCO3 and the other containing Fe, oxygen, and carbon-rich islands embedded in metal matrix identified as {alpha}-Fe. Precipitation of FeCO3 from Fe2+ and CO3 2- is responsible for formation of passive layer in oxygen-deficient, CO2 rich aqueous environment. Mechanisms of corrosion degradation occurring in supercritical CO2 as a function. Transport of supercritical CO{sub 2} is a critical element for carbon capture from fossil fuel power plants and underground sequestration. Although acceptable levels of water in supercritical CO{sub 2} (up to {approx} 5 x 10{sup -4}g/dm{sup 3}) have been established, their effects on the corrosion resistance of pipeline steels are not fully known. Moreover, the presence of SO{sub 2}, O{sub 2} impurities in addition to the water can make the fluid more corrosive and, therefore, more detrimental to service materials. Also, in this case, limited data are available on materials performance of carbon steels. to advance this knowledge, other service alloys are being investigated in the high pressure high temperature cell containing impure CO{sub 2} fluids using reliable non-destructive in-situ electrochemical methods. The electrochemical results are being augmented by a number of surface analyses of the corroded surfaces.

  18. Weeks Island gravity stable CO2 pilot: Final report

    SciTech Connect (OSTI)

    Johnston, J.R.; Perry, G.E.

    1989-01-01T23:59:59.000Z

    The Weeks Island ''S'' sand Reservoir B (''S'' RB) gravity-stable CO2 field test was completed during February 1988. Injection started in October 1978 and production began in January 1981 in this high-permeability, steeply-dipping sandstone reservoir. About 264,000 barrels of oil or 65 percent of the starting volume has been recovered. A 24-percent pore-volume slug of CO2 mixed with about six mole percent of natural gas (mostly methane) was injected at the start of the pilot. Since 1983, produced CO2 plus hydrocarbon gases have been recycled. CO2 usage statistics are 9.34 MCF/BO with recycle and 3.24 MCF/BO based on purchased CO2. Previous annual reports document the pilot design, implementation, and early results for the 1977 to June 1981 time period. This report is a review of early pilot history and a more detailed account of the post June 1981 results and overall interpretation. A reservoir-simulation history match of pilot performance plus core and log data from a 1983 swept-zone evaluation well are described in this report. A brief description of the production facility and an account of the corrosion control program are also included. 11 refs., 34 figs.

  19. The Monitor Blue Skies A future for fossil fuels http://www.epolitix.com/EN/Publications/Blue+Skies+Monitor/132... 1 of 2 30/10/05 11:40 pm

    E-Print Network [OSTI]

    Haszeldine, Stuart

    (CCS) hovers around two percent of the adult population. Yet many key players in the fossil fuel energy. What if there was a third way forward? A way which could help the transition to a new energy, low 700 million tons of carbon dioxide. A group led by BP and Scottish and Southern Energy has plans

  20. Development of a Method for Measuring Carbon Balance in Chemical Sequestration of CO2

    SciTech Connect (OSTI)

    Cheng, Zhongxian; Pan, Wei-Ping; Riley, John T.

    2006-09-09T23:59:59.000Z

    Anthropogenic CO2 released from fossil fuel combustion is a primary greenhouse gas which contributes to global warming. It is estimated that stationary power generation contributes over one-third of total CO2 emissions. Reducing CO2 in the atmosphere can be accomplished either by decreasing the rate at which CO2 is emitted into the atmosphere or by increasing the rate at which it is removed from it. Extensive research has been conducted on determining a fast and inexpensive method to sequester carbon dioxide. These methods can be classified into two categories, CO2 fixation by natural sink process for CO2, or direct CO2 sequestration by artificial processes. In direct sequestration, CO2 produced from sources such as coal-fired power plants, would be captured from the exhausted gases. CO2 from a combustion exhaust gas is absorbed with an aqueous ammonia solution through scrubbing. The captured CO2 is then used to synthesize ammonium bicarbonate (ABC or NH4HCO3), an economical source of nitrogen fertilizer. In this work, we studied the carbon distribution after fertilizer is synthesized from CO2. The synthesized fertilizer in laboratory is used as a CO2 carrier to transport CO2 from the atmosphere to crops. After biological assimilation and metabolism in crops treated with ABC, a considerable amount of the carbon source is absorbed by the plants with increased biomass production. The majority of the unused carbon source percolates into the soil as carbonates, such as calcium carbonate (CaCO3) and magnesium carbonate (MgCO3). These carbonates are environmentally benign. As insoluble salts, they are found in normal rocks and can be stored safely and permanently in soil. This investigation mainly focuses on the carbon distribution after the synthesized fertilizer is applied to soil. Quantitative examination of carbon distribution in an ecosystem is a challenging task since the carbon in the soil may come from various sources. Therefore synthesized 14C tagged NH4HCO3 (ABC) was used. Products of ammonium bicarbonate (ABC) or long-term effect ammonium bicarbonate (LEABC) were tagged with 14C when they were synthesized in the laboratory. An indoor greenhouse was built and wheat was chosen as the plant to study in this ecosystem. The investigated ecosystem consists of plant (wheat), soils with three different pH values (alkaline, neutral and acid), and three types of underground water (different Ca2+ and Mg2+ concentrations). After biological assimilation and metabolism in wheat receiving ABC or LEABC, it was found that a considerable amount (up to 10%) of the carbon source is absorbed by the wheat with increased biomass production. The majority of the unused carbon source (up to 76%) percolated into the soil as carbonates, such as environmentally benign calcium carbonate (CaCO3). Generally speaking, alkaline soil has a higher capability to capture and store carbon. For the same soil, there is no apparent difference in carbon capturing capability between ABC fertilizer and LEABC fertilizer. These findings answer the question how carbon is distributed after synthesized fertilizer is applied into the ecosystem. In addition, a separate post-experiment on fertilizer carbon forms that exist in the soil was made. It was found that the up to 88% of the trapped carbon exists in the form of insoluble salts (i.e., CaCO3) in alkaline soils. This indicates that alkaline soil has a greater potential for storing carbon after the use of the synthesized fertilizer from exhausted CO2.

  1. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01T23:59:59.000Z

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James OBrien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  2. 5, 33133340, 2005 SCIAMACHY CO2 and

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    ACPD 5, 33133340, 2005 SCIAMACHY CO2 and aerosols S. Houweling et al. Title Page Abstract Evidence of systematic errors in SCIAMACHY-observed CO2 due to aerosols S. Houweling 1,2 , W. Hartmann 1 Commons License. 3313 #12;ACPD 5, 33133340, 2005 SCIAMACHY CO2 and aerosols S. Houweling et al. Title

  3. Options for Near-Term Phaseout of CO2 Emissions from Coal Use in the United States

    E-Print Network [OSTI]

    unconventional fossil fuels (e.g., oil shale and tar sands) are prohibited. This paper outlines technology

  4. Samenvatting CO2 is het meest belangrijke broeikasgas. The concentratie van CO2 in de atmosfeer

    E-Print Network [OSTI]

    van den Brink, Jeroen

    Samenvatting CO2 is het meest belangrijke broeikasgas. The concentratie van CO2 in de atmosfeer brandstoffen en veranderingen in landgebruik. Toenemende concentraties van CO2 in de atmosfeer zullen naar toename van CO2 in de atmosfeer op de dynamiek van de microbile gemeenschap in de directe omgeving van de

  5. MAC-Kaust Project P1 CO2 Sequestration Modeling of CO2 sequestration including parameter

    E-Print Network [OSTI]

    Turova, Varvara

    MAC-Kaust Project P1 ­ CO2 Sequestration Modeling of CO2 sequestration including parameter identification and numerical simulation M. Brokate, O. A. PykhteevHysteresis aspects of CO2 sequestration modeling K-H. Hoffmann, N. D. Botkin Objectives and methods of CO2 sequestration There is a popular belief

  6. How secure is CO2 storage? Leakage mechanisms of natural CO2 reservoirs

    E-Print Network [OSTI]

    How secure is CO2 storage? Leakage mechanisms of natural CO2 reservoirs Johannes Miocic, Stuart. The goal of CCS is to store carbon dioxide (CO2) in the subsurface for a long period of time (>10,000 yr).1 It is important that the stored CO2 does not leak from the reservoir to the surface . 3. Faults as leakage

  7. Surface controls on the characteristics of natural CO2 seeps: implications for engineered CO2 stores

    E-Print Network [OSTI]

    Haszeldine, Stuart

    of the CO2 seeps is most strongly governed by the flow properties of the outcropping rocks, and local emerge where valleys erode into CO2 aquifers, and these are typically high flux seeps. Seep type is knownSurface controls on the characteristics of natural CO2 seeps: implications for engineered CO2

  8. Health, safety, and environmental risks from energy production: A year-long reality check

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01T23:59:59.000Z

    CO 2 emissions from fossil fuel energy, but it also carriesassociated with fossil fuel and nuclear energy production.primarily use fossil fuels to create affordable energy for

  9. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01T23:59:59.000Z

    the shares of AIS electricity generation by fuel. AIS powerhistorical electricity generation by primary fuel. ThermalNon-Fossil Fuel Electricity Generation (kgce/kWh) ..

  10. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01T23:59:59.000Z

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  11. Modeling of CO2 storage in aquifers

    E-Print Network [OSTI]

    santos,,,

    Feb 6, 2011 ... atmosphere, increasing its temperature (greenhouse effect). To minimize climate change impacts, geological sequestration of CO2 is an...

  12. QGESS: CO2 Impurity Design Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    limits Component Unit (Max unless Otherwise noted) Carbon Steel Pipeline Enhanced Oil Recovery Saline Reservoir Sequestration Saline Reservoir CO 2 & H 2 S Co- sequestration...

  13. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins: Applied Studies in Reservoir Assessment and Dynamic Processes Affecting Industrial Operations

    SciTech Connect (OSTI)

    Nummedal, Dag; Sitchler, Alexis; McCray, John; Mouzakis, Katherine; Glossner, Andy; Mandernack, Kevin; Gutierrez, Marte; Doran, Kevin; Pranter, Matthew; Rybowiak, Chris

    2012-09-30T23:59:59.000Z

    This multitask research project was conducted in anticipation of a possible future increase in industrial efforts at CO2 storage in Colorado sedimentary basins. Colorado is already the home to the oldest Rocky Mountain CO2 storage site, the Rangely Oil Field, where CO2-EOR has been underway since the 1980s. The Colorado Geological Survey has evaluated storage options statewide, and as part of the SW Carbon Sequestration Partnership the Survey, is deeply engaged in and committed to suitable underground CO2 storage. As a more sustainable energy industry is becoming a global priority, it is imperative to explore the range of technical options available to reduce emissions from fossil fuels. One such option is to store at least some emitted CO2 underground. In this NETL-sponsored CO2 sequestration project, the Colorado School of Mines and our partners at the University of Colorado have focused on a set of the major fundamental science and engineering issues surrounding geomechanics, mineralogy, geochemistry and reservoir architecture of possible CO2 storage sites (not limited to Colorado). Those are the central themes of this final report and reported below in Tasks 2, 3, 4, and 6. Closely related to these reservoir geoscience issues are also legal, environmental and public acceptance concerns about pore space accessibilityas a precondition for CO2 storage. These are addressed in Tasks 1, 5 and 7. Some debates about the future course of the energy industry can become acrimonius. It is true that the physics of combustion of hydrocarbons makes it impossible for fossil energy to attain a carbon footprint anywhere nearly as low as that of renewables. However, there are many offsetting benefits, not the least that fossil energy is still plentiful, it has a global and highly advanced distribution system in place, and the footprint that the fossil energy infrastructure occupies is orders of magnitude smaller than renewable energy facilities with equivalent energy capacity. Finally, inexpensive natural gas here in North America is pushing coal for electricity generation off the market, thus reducing US CO2 emissions faster than any other large industrialized nation. These two big factors argue for renewed efforts to find technology solutions to reduce the carbon footprint (carbon dioxide as well as methane and trace gases) of conventional and unconventional oil and gas. One major such technology component is likely to be carbon capture, utilization and storage.

  14. Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong, David W. Keith

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong, David W carbon underground), we derive analytic expressions for the value of leaky CO2 storage compared to perfect storage when storage is a marginal component of the energy system. If the annual leak rate is 1

  15. NUCLEAR POWERED CO2 CAPTURE FROM THE ATMOSPHERE

    SciTech Connect (OSTI)

    Sherman, S

    2008-09-22T23:59:59.000Z

    A process for capturing CO{sub 2} from the atmosphere was recently proposed. This process uses a closed cycle of sodium and calcium hydroxide, carbonate, and oxide transformations to capture dilute CO{sub 2} from the atmosphere and to generate a concentrated stream of CO{sub 2} that is amenable to sequestration or subsequent chemical transformations. In one of the process steps, a fossil-fueled lime kiln is needed, which reduces the net CO{sub 2} capture of the process. It is proposed to replace the fossil-fueled lime kiln with a modified kiln heated by a high-temperature nuclear reactor. This will have the effect of eliminating the use of fossil fuels for the process and increasing the net CO{sub 2} capture. Although the process is suitable to support sequestration, the use of a nuclear power source for the process provides additional capabilities, and the captured CO{sub 2} may be combined with nuclear-produced hydrogen to produce liquid fuels via Fischer-Tropsch synthesis or other technologies. Conceivably, such plants would be carbon-neutral, and could be placed virtually anywhere without being tied to fossil fuel sources or geological sequestration sites.

  16. Capturing CO2 from Air Anca Timofte

    E-Print Network [OSTI]

    Fischlin, Andreas

    emissions through renewable fuels Storage of fluctuating renewable energies Short-term: Substitute concentrated CO2 from atmospheric air Renewable energy source for Climeworks and subsequent fuel synthesis in Greenhouses Beverage Carbonation CO2 Supply for Renewable Fuel Synthesis #12;5 Climeworks plant delivers

  17. Legal Implications of CO2 Ocean Storage

    E-Print Network [OSTI]

    Legal Implications of CO2 Ocean Storage Jason Heinrich Working Paper Laboratory for Energy the deployment of CO2 storage technologies used in the marine environment. This paper will address some of the legal issues involved in ocean storage of carbon dioxide from a US perspective. The following paragraphs

  18. 2, 711743, 2006 Glacial CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    CO2 change: a simple "hypsometric effect" on deep-ocean carbon sequestration? L. C. Skinner Godwin carbon sequestration, this mechanism may help to significantly reduce the "deficit" of explained glacialCPD 2, 711743, 2006 Glacial CO2 sequestration L. C. Skinner Title Page Abstract Introduction

  19. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z [University of Cincinnati; Dong, J. H. [University of Cincinnati

    2008-10-01T23:59:59.000Z

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  20. 4, 23852405, 2007 CO2 and climate

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    BGD 4, 23852405, 2007 CO2 and climate affect European carbon ballance R. Harrison and C. Jones Competing roles of rising CO2 and climate change in the contemporary European carbon balance R. Harrison and C. Jones Met Office, Hadley Centre for Climate Change, Exeter, EX1 3PB, UK Received: 13 April 2007

  1. CO2 Capture with Enzyme Synthetic Analogue

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-11-08T23:59:59.000Z

    Overview of an ongoing, 2 year research project partially funded by APRA-E to create a novel, synthetic analogue of carbonic anhydrase and incorporate it into a membrane for removal of CO2 from flue gas in coal power plants. Mechanism background, preliminary feasibility study results, molecular modeling of analogue-CO2 interaction, and program timeline are provided.

  2. Prospects for Subsurface CO2 Sequestration

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    Prospects for Subsurface CO2 Sequestration Abbas Firoozabadi and Philip Cheng Dept. of Chemical in Wiley InterScience (www.interscience.wiley.com). Keywords: CO2 sequestration, mixing, diffusion coal in the future. Coal has a high carbon to hydrogen ratio while natural gas, the premium fuel

  3. Study of CO2 Mobility Control in Heterogeneous Media Using CO2 Thickening Agents

    E-Print Network [OSTI]

    Al Yousef, Zuhair

    2012-10-19T23:59:59.000Z

    CO2 injection is an effective method for performing enhanced oil recovery (EOR). There are several factors that make CO2 useful for EOR, including promoting swelling, reducing oil viscosity, decreasing oil density, and vaporizing and extracting...

  4. Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release

    SciTech Connect (OSTI)

    Lewicki, J.L.; Hilley, G.E.; Dobeck, L.; Spangler, L.

    2009-09-01T23:59:59.000Z

    A field facility located in Bozeman, Montana provides the opportunity to test methods to detect, locate, and quantify potential CO2 leakage from geologic storage sites. From 9 July to 7 August 2008, 0.3 t CO2 d{sup -1} were injected from a 100-m long, {approx}2.5 m deep horizontal well. Repeated measurements of soil CO2 fluxes on a grid characterized the spatio-temporal evolution of the surface leakage signal and quantified the surface leakage rate. Infrared CO2 concentration sensors installed in the soil at 30 cm depth at 0 to 10 m from the well and at 4 cm above the ground at 0 and 5 m from the well recorded surface breakthrough of CO2 leakage and migration of CO2 leakage through the soil. Temporal variations in CO2 concentrations were correlated with atmospheric and soil temperature, wind speed, atmospheric pressure, rainfall, and CO2 injection rate.

  5. Geological Storage of CO2 from Power Niels Peter Christensen, Geological Survey of Denmark and

    E-Print Network [OSTI]

    can utilise its indigenous energy resources, such as coal - the EU`s largest reserve of fossil fuel technology for fossil fuels is badly needed, not just for Europe but worldwide, as coal use in electricity to increase generating capacity. Electricity demand continues to mount by around 1.5% each year, but existing

  6. Recovery and Sequestration of CO2 from Stationary Combustion Systems by Photosynthesis of Microalgae

    SciTech Connect (OSTI)

    T. Nakamura; C.L. Senior

    2005-04-01T23:59:59.000Z

    Most of the anthropogenic emissions of carbon dioxide result from the combustion of fossil fuels for energy production. Photosynthesis has long been recognized as a means, at least in theory, to sequester anthropogenic carbon dioxide. Aquatic microalgae have been identified as fast growing species whose carbon fixing rates are higher than those of land-based plants by one order of magnitude. Physical Sciences Inc. (PSI), Aquasearch, and the Hawaii Natural Energy Institute at the University of Hawaii are jointly developing technologies for recovery and sequestration of CO{sub 2} from stationary combustion systems by photosynthesis of microalgae. The research is aimed primarily at demonstrating the ability of selected species of microalgae to effectively fix carbon from typical power plant exhaust gases. This report covers the reporting period 1 October 2000 to 31 March 2005 in which PSI, Aquasearch and University of Hawaii conducted their tasks. This report discusses results of the work pertaining to five tasks: Task 1--Supply of CO2 from Power Plant Flue Gas to Photobioreactor; Task 2--Selection of Microalgae; Task 3--Optimization and Demonstration of Industrial Scale Photobioreactor; Task 4--Carbon Sequestration System Design; and Task 5--Economic Analysis. Based on the work conducted in each task summary conclusion is presented.

  7. Sustainable Carbon Sequestration: Increasing CO2-Storage Efficiency through a CO2-Brine Displacement Approach

    E-Print Network [OSTI]

    Akinnikawe, Oyewande

    2012-10-19T23:59:59.000Z

    CO2 sequestration is one of the proposed methods for reducing anthropogenic CO2 emissions to the atmosphere and therefore mitigating global climate change. Few studies on storing CO2 in an aquifer have been conducted on a regional scale. This study...

  8. Sustainable Carbon Sequestration: Increasing CO2-Storage Efficiency through a CO2-Brine Displacement Approach

    E-Print Network [OSTI]

    Akinnikawe, Oyewande

    2012-10-19T23:59:59.000Z

    CO2 sequestration is one of the proposed methods for reducing anthropogenic CO2 emissions to the atmosphere and therefore mitigating global climate change. Few studies on storing CO2 in an aquifer have been conducted on a regional scale. This study...

  9. co2 capture | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Capture Technology Meeting Dates: June 23-26, 2015 Registration Fee: 360.00 Venue: 300 West Station Square Drive Pittsburgh, PA 15219-1122 Phone: (412)261-2000...

  10. Tracking uncertainties in the causal chain from human activities to climate

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    CO 2 emissions from fossil-fuel burning, cement manufacture,CO 2 emissions due to fossil fuels, CO 2 emissions due to2 -equivalent per year. Fossil-fuel (FF) is used to describe

  11. Version 3.0 SOP 4 --p(CO2) October 12, 2007 (p(CO2))

    E-Print Network [OSTI]

    Version 3.0 SOP 4 -- p(CO2) October 12, 2007 91 SOP 4 (p(CO2)) - 1. . microatmospheres . (20C 250-2000 atm) (mole fraction) . 2. CO2 (mole fraction) . 2 2(CO ) (CO( ) . . Frit . #12;October 12, 2007 SOP 4 -- p(CO2) Version 3.0 92 CO2 CO2 2 . p(CO2) (1) . 4. 3

  12. Atmospheric CO2 concentrations during ancient greenhouse climates were similar

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Atmospheric CO2 concentrations during ancient greenhouse climates were similar to those predicted atmospheric CO2 concentrations (CO2atm) during Earth's ancient greenhouse episodes is essential for accurately predicting the response of future climate to elevated CO2 levels. Empirical estimates of CO2atm

  13. Growth, CO2 Consumption, and H2 Production of Anabaena variabilis ATCC 29413-U under Different Irradiances and CO2 Concentrations

    E-Print Network [OSTI]

    Berberoglu, Halil; Barra, Natasha; Pilon, Laurent; Jay, Jenny

    2008-01-01T23:59:59.000Z

    Phase Medium Irradiance ? H2 ? CO2 Maximum Reported Ratesa) Specific CO 2 uptake rate, ? CO2 (kg CO 2 /kg dry cell/h)

  14. Selection of coals of different maturities for CO2 Storage by modelling of CH4 and CO2 adsorption isotherms

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    rue de la Frollerie, 45072 Orlans Cedex, France Abstract CO2 injection in unmineable coal seams capacities on various coals for the future modelling of CO2 injection in coal seams. Keywords: CO2 storage is estimated from 3 up to 200 GtCO2 therefore CO2 storage in coal seams is one of the potential types

  15. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01T23:59:59.000Z

    of Geologic Storage of CO2, in Carbon Dioxide Capture forFormations - Results from the CO2 Capture Project: GeologicBenson, Process Modeling of CO2 Injection into Natural Gas

  16. Satellite remote sounding of mid-tropospheric CO 2

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    and Y. L. Yung (2006), CO 2 in the upper troposphere:derivatives with application to CO 2 , Geophys. Res. Lett. ,feasibility of monitoring CO 2 from high-resolution infrared

  17. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    WITH SITE SCREENING AND SELECTION FOR CO 2 STORAGE D. A.77 ASSESSING AND EXPANDING CO 2 STORAGE CAPACITY IN DEPLETEDFOR CO 2 GEOLOGICAL STORAGE IN CENTRAL COAL BASIN (NORTHERN

  18. Original article Soil CO2 efflux in a beech forest: dependence on soil

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Original article Soil CO2 efflux in a beech forest: dependence on soil temperature and soil water 1998) Abstract - Our objective was to quantify the annual soil carbon efflux in a young beech forest in north-eastern France (Hesse Forest, Euroflux site FR02) from measurements of soil CO, efflux. Soil CO

  19. Joint CO2 and CH4 accountability for global warming Kirk R. Smitha,1,2

    E-Print Network [OSTI]

    Silver, Whendee

    the causes of global warming, because the amount of global warming occurring at any time is ac- tually dueJoint CO2 and CH4 accountability for global warming Kirk R. Smitha,1,2 , Manish A. Desaia,1 for global warming is its current annual emissions of greenhouse gases (GHGs)*. The second most common

  20. Chapter 2: Sustainable and Unsustainable Developments in the U.S. Energy System

    E-Print Network [OSTI]

    Levine, Mark D.

    2008-01-01T23:59:59.000Z

    U.S. CO2 Emissions from Fossil Fuel Combustion by Sector (MtCO2/$ GDP Source: EIA, AER 2006; IEA, Carbon Emissions from Fossil Fuel Combustion;

  1. Annual energy review 1994

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    This 13th edition presents the Energy Information Administration`s historical energy statistics. For most series, statistics are given for every year from 1949 through 1994; thus, this report is well-suited to long-term trend analyses. It covers all major energy activities, including consumption, production, trade, stocks, and prices for all major energy commodities, including fossil fuels and electricity. Statistics on renewable energy sources are also included: this year, for the first time, usage of renewables by other consumers as well as by electric utilities is included. Also new is a two-part, comprehensive presentation of data on petroleum products supplied by sector for 1949 through 1994. Data from electric utilities and nonutilities are integrated as ``electric power industry`` data; nonutility power gross generation are presented for the first time. One section presents international statistics (for more detail see EIA`s International Energy Annual).

  2. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    CONSTRAIN CO2 INJECTION FEASIBILITY: TEAPOT DOME EOR PILOTEOR, and coupled process modeling will investigate the total system including preliminary estimates of CO2

  3. abiotic co2 flows: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into the potential behavior and the operational parameters of CO2 sequestration at CO2-EOR s... Dai, Zhenxue; Fessenden-Rahn, Julianna; Middleton, Richard; Pan, Feng; Jia,...

  4. af co2 fra: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into the potential behavior and the operational parameters of CO2 sequestration at CO2-EOR s... Dai, Zhenxue; Fessenden-Rahn, Julianna; Middleton, Richard; Pan, Feng; Jia,...

  5. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01T23:59:59.000Z

    F Monitoring studies above EOR-CO2 fields Weyburn-MidaleTexas ? Over 30 years of CO2-EOR ? Sampled outside of

  6. Modeling CO2 Sequestration in a Saline Reservoir and Depleted...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling CO 2 Sequestration in a Saline Reservoir and Depleted Oil Reservoir to Evaluate The Regional CO 2 Sequestration Potential of The Ozark Plateau Aquifer System,...

  7. Reaction of Water-Saturated Supercritical CO2 with Forsterite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water-Saturated Supercritical CO2 with Forsterite: Evidence for Magnesite Formation at Low Temperatures. Reaction of Water-Saturated Supercritical CO2 with Forsterite: Evidence for...

  8. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration. Abstract: A novel EOR method using...

  9. Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition. Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive...

  10. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  11. Geologic CO2 sequestration inhibits microbial growth | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    community and could improve overall efficiency of CO2 sequestration. The Science Carbon dioxide (CO2) sequestration in deep subsurface environments has received...

  12. numerical methodology to model and monitor co2 sequestration

    E-Print Network [OSTI]

    santos,,,

    CO2 sequestration is a means of mitigating the greenhouse effect [1]. Geologic sequestration involves injecting CO2 into a target geologic formation at depths...

  13. Variations in 13 C discrimination during CO2 exchange by

    E-Print Network [OSTI]

    as to differential diffusivities of 13 CO2 and 12 CO2 in air (Farquhar, O'Leary & Berry 1982; O'Leary 1984

  14. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect (OSTI)

    Turchi, Craig

    2014-01-29T23:59:59.000Z

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650C in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late in Phase 1 an opportunity arose to collaborate with another turbine-development team to construct a shared s-CO2 test facility. The synergy of the combined effort would result in greater facility capabilities than either separate project could produce and would allow for testing of both turbine designs within the combined budgets of the two projects. The project team requested a no-cost extension to Phase 1 to modify the subsequent work based on this collaborative approach. DOE authorized a brief extension, but ultimately opted not to pursue the collaborative facility and terminated the project.

  15. CO2 Compression | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccess Stories Siteandscience, and8Critical4CO2 Compression CO2

  16. Regional GHG Emissions Stat s Greenhouse Gas and the Regional

    E-Print Network [OSTI]

    Klamath CoGen (536 MW) (300 MW) #12;6/5/2013 4 CO2 Emissions from Electricity in PNW (1990-2010 ) 25,00070.0 Historical CO2 Emissions of the NW Power System CO2 Emissions Hydro Gen Fossil Fuel Gen (NG + Coal) Wind Gen (MWa) 7 0 5,000 0.0 10.0 20.0 Annual CO2 Annual En CO2 Emissions by Resource in PNW (1995-2010) 80

  17. Porous Hexacyanometalates for CO2 capture applications

    SciTech Connect (OSTI)

    Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

    2013-07-30T23:59:59.000Z

    Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

  18. Ocean Acidification: The Other CO2 Problem

    E-Print Network [OSTI]

    Childress, Michael J.

    reserved 1941-1405/09/0115-0169$20.00 Key Words biogeochemistry, calcification, carbon dioxide, climate of calcium carbonate saturation states, which impacts shell-forming marine organisms from plankton to benthic for marine organisms to adapt to increasing CO2 and broader implications for ocean ecosystems are not well

  19. Aquifer Management for CO2 Sequestration

    E-Print Network [OSTI]

    Anchliya, Abhishek

    2010-07-14T23:59:59.000Z

    Storage of carbon dioxide is being actively considered for the reduction of green house gases. To make an impact on the environment CO2 should be put away on the scale of gigatonnes per annum. The storage capacity of deep saline aquifers...

  20. A Framework for Environmental Assessment of CO2 Capture and Storage Systems

    E-Print Network [OSTI]

    Sathre, Roger

    2013-01-01T23:59:59.000Z

    demand for energy services, as well as the relative abundance of fossil fuelsdemand for energy services makes it improbable that the large quantity of energy stored underground in fossil fuels

  1. Optimal Process Design for Coupled CO2 Sequestration and Enhanced Gas Recovery in Carbonate Reservoirs

    E-Print Network [OSTI]

    Odi, Uchenna

    2013-12-09T23:59:59.000Z

    Increasing energy demand combined with public concern for the environment obligates the oil industry to supply oil and natural gas to the public while minimizing the carbon footprint due to its activities. Today, fossil fuels are essential...

  2. Optimal Process Design for Coupled CO2 Sequestration and Enhanced Gas Recovery in Carbonate Reservoirs

    E-Print Network [OSTI]

    Odi, Uchenna

    2013-12-09T23:59:59.000Z

    Increasing energy demand combined with public concern for the environment obligates the oil industry to supply oil and natural gas to the public while minimizing the carbon footprint due to its activities. Today, fossil fuels are essential...

  3. Northern California CO2 Reduction Project

    SciTech Connect (OSTI)

    Hymes, Edward

    2010-06-16T23:59:59.000Z

    C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO2 will be compressed and dehydrated at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO2 per year, so additional capacity will be available to accommodate CO2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO2 reduction requirements set forth in California?s Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas: ? Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO2 capture, CO2 compression and dehydration at the refinery, and surface facilities at the sequestration site ? Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design ? Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site ? Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO2

  4. CO2 Storage and Sink Enhancements: Developing Comparable Economics

    E-Print Network [OSTI]

    CO2 Storage and Sink Enhancements: Developing Comparable Economics B.R. Bock1 , R.G. Rhudy2 , and H technologies and practices under development for CO2 storage and sink enhancement, including options. For the geologic and ocean storage options, CO2 capture costs from another project were added to the costs of CO2

  5. Original article Limitation of photosynthetic activity by CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Original article Limitation of photosynthetic activity by CO2 availability in the chloroplasts to resistances opposing the CO2 fluxes in the mesophyll of tree leaves. To validate this assertion, values of CO2 CO2 assimilation and respiration rate measurement, and using the known electron requirements (four

  6. CO2 levels during the greenhouse of the Paleocene

    E-Print Network [OSTI]

    Shull, Kenneth R.

    CO2 levels during the greenhouse of the Paleocene Eocene Thermal Maximum (PETM) Francesca A. Mc, Boulder #12;Estimating paleopCO2 0 5 10 15 20 25 30 0 500 1000 1500 2000 2500 3000 Meter Level, start of CIE=0 pCO2 pCO2 values using different calculation methods Bulk nalk For the past 250 years human

  7. CO2 enrichment increases carbon and nitrogen input from

    E-Print Network [OSTI]

    CO2 enrichment increases carbon and nitrogen input from fine roots in a deciduous forest Colleen2 Ecological Society of America, 2008 #12;#12;#12;#12;#12;+ [CO2] #12;+ Net primary production + [CO2] #12;+ Net primary production + [CO2] + C and N storage in biomass #12;+ Net primary production

  8. Cost Assessment of CO2 Sequestration by Mineral Carbonation

    E-Print Network [OSTI]

    Yeboah, F. E.; Yegulalp, T. M.; Singh, H.

    2006-01-01T23:59:59.000Z

    Cost Assessment of CO2 Sequestration by Mineral Carbonation Frank E. Yeboah Tuncel M. Yegulalp Harmohindar Singh Research Associate Professor Professor Center for Energy Research... them carbon dioxide (CO 2 ). This paper assesses the cost of sequestering CO 2 produced by a ZEC power plant using solid sequestration process. INTRODUCTION CO 2 is produced when electrical energy is generated using conventional fossil...

  9. Cost Assessment of CO2 Sequestration by Mineral Carbonation

    E-Print Network [OSTI]

    Yeboah, F. E.; Yegulalp, T. M.; Singh, H.

    2006-01-01T23:59:59.000Z

    Cost Assessment of CO2 Sequestration by Mineral Carbonation Frank E. Yeboah Tuncel M. Yegulalp Harmohindar Singh Research Associate Professor Professor Center for Energy Research... them carbon dioxide (CO 2 ). This paper assesses the cost of sequestering CO 2 produced by a ZEC power plant using solid sequestration process. INTRODUCTION CO 2 is produced when electrical energy is generated using conventional fossil...

  10. CO2 Sequestration Modeling Using Pattern Recognition and Data Mining;

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    carbon dioxide (CO2) sequestration process is to ensure a sustained confinement of the injected CO2CO2 Sequestration Modeling Using Pattern Recognition and Data Mining; Case Study of SACROC field, USA Abstract Capturing carbon dioxide (CO2) from industrial and energy-related sources and depositing

  11. Renewable Energy, Nuclear Power and Galileo: Do Scientists Have a Duty to Expose Popular Misconceptions?

    E-Print Network [OSTI]

    Hansen, James E.

    ). The largest growth of CO2 emissions and energy use was in China, where provision of electricity expanded and energy data. #12;2 Fig. 1. (a) Global CO2 annual emissions from fossil fuel use and cement manufacture, (b) world energy consumption (excluding wood).4,5 Carbon (CO2) emissions did not decline following

  12. Using CO2 & Algae to Treat Wastewater and

    E-Print Network [OSTI]

    Keller, Arturo A.

    Using CO2 & Algae to Treat Wastewater and Produce Biofuel Feedstock Tryg Lundquist Cal Poly State of the Industry and Growth · Algae's Role in WW Treatment · CO2's New Role · Research at Cal Poly · Future Work/MG 0.3 MGD average flow per facility #12;Reclaimed Algae Bacteria O2 CO2 N Organics N P CO2 P CO2 Waste

  13. The response of soil CO2 ux to changes in atmospheric CO2, nitrogen supply and plant diversity

    E-Print Network [OSTI]

    Minnesota, University of

    The response of soil CO2 ux to changes in atmospheric CO2, nitrogen supply and plant diversity J O. Paul, MN 55108 USA Abstract We measured soil CO2 ux over 19 sampling periods that spanned two growing three major anthropogenic global changes: atmos- pheric carbon dioxide (CO2) concentration, nitrogen (N

  14. An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of atmospheric CO2

    E-Print Network [OSTI]

    Hoffman, Forrest M.

    An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of anthropogenic CO2 are presented. Approximating the seasonal CO2 emission cycle using a 2-harmonic Fourier series with regions of strong anthropogenic CO2 emissions. Citation: Erickson, D. J., III, R. T. Mills, J. Gregg, T. J

  15. Energy Efficiency in Regulated and Deregulated Markets

    E-Print Network [OSTI]

    Rotenberg, Edan

    2005-01-01T23:59:59.000Z

    annual public subsidies for fossil fuels range between $100public subsidies for the use of fossil fuels: budgetary

  16. Buildings, Commissioning, Efficiency, Comfort, and CO2

    E-Print Network [OSTI]

    Claridge, D. E.

    2006-01-01T23:59:59.000Z

    comfort, optimize energy use and identify retrofits for existing commercial and institutional buildings and central plant facilities. It includes the entire commissioning process from assessment through implementation and subsequent follow-up as necessary...Buildings, Commissioning, Efficiency, Comfort, and CO2 Asian Pacific Building Commissioning Conference ICEBONovember 8, 2006Shenzhen, ChinaPresented ByDavid E. ClaridgeEnergy Systems LaboratoryTexas A&M University Commissioning New Buildings...

  17. Continuous CO2 extractor and methods

    SciTech Connect (OSTI)

    None listed

    2010-06-15T23:59:59.000Z

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  18. 10-MW Supercritical-CO2 Turbine

    Broader source: Energy.gov [DOE]

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cyclethe supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  19. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect (OSTI)

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01T23:59:59.000Z

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  20. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Reid B. Grigg; Robert K. Svec; Zheng-Wen Zeng; Liu Yi; Baojun Bai

    2003-05-01T23:59:59.000Z

    A three-year contract for the project, DOE Contract No. DE-FG26-01BC15364, ''Improving CO{sub 2} Efficiency for Recovering Oil in Heterogeneous Reservoirs,'' was awarded and started on September 28, 2001. This project examines three major areas in which CO2 flooding can be improved: fluid and matrix interactions, conformance control/sweep efficiency, and reservoir simulation for improved oil recovery. This report discusses the activity during the six-month period covering October 1, 2002 through March 31, 2003 that covers the first and second fiscal quarters of the project's second year. During these two quarters of the project we have been working in several areas: reservoir fluid/rock interactions and their relationships to changing injectivity, and surfactant adsorption on quarried core and pure component granules, foam stability, and high flow rate effects. We also had a very productive project review in Midland, Texas. A paper on CO{sub 2}-brine-reservoir rock interaction was presented and included in the proceedings of the SPE International Symposium on Oilfield Chemistry, Houston, 5-8 February, 2003. Papers have been accepted for the Second Annual Conference on Carbon Sequestration in Alexandria, VA in May, the Society of Core Analysis meeting in Pau, France in September, and two papers for the SPE Annual Meeting in Denver, CO in October.

  1. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    Units Current Plant MEA CO 2 Recovery O 2 fired, Direct CO 2 Compression` MEA/MDEA CO 2 Recovery Steam

  2. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    SciTech Connect (OSTI)

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O'Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01T23:59:59.000Z

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  3. co2-transport | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :,2013 NETL CO2 CaptureTransport Cost

  4. Coupled reservoir-geomechanical analysis of CO2 injection and ground deformations at In Salah, Algeria

    E-Print Network [OSTI]

    Rutqvist, J.

    2010-01-01T23:59:59.000Z

    CO 2 sequestration; In Salah; geomechanics; ground surfaceCO 2 injection, geomechanics, and ground surface

  5. IMPLEMENTING A NOVEL CYCLIC CO2 FLOOD IN PALEOZOIC REEFS

    SciTech Connect (OSTI)

    James R. Wood; W. quinlan; A. Wylie

    2006-06-01T23:59:59.000Z

    Recycled CO2 is being used in this demonstration project to produce bypassed oil from the Silurian Dover 35 Niagaran pinnacle reef located in Otsego County, Michigan. CO2 injection in the Dover 35 field into the Salling-Hansen 4-35A well began on May 6, 2004. A second injection well, the Salling-Hansen 1-35, commenced injection in August 2004. Oil production in the Pomerzynski 5-35 producing well increased from 9 BOPD prior to operations to an average of 165 BOPD in December, 2004 and has produced at an average rate of 61 BOPD (Jan-Dec, 2005). The Salling-Hansen 4-35A also produced during this reporting period an average of 29 BOPD. These increases have occurred as a result of CO2 injection and the production rate appears to be stabilizing. CO2 injection volume has reached approximately 2.18 BCF. The CO2 injection phase of this project has been fully operational since December 2004 and most downhole mechanical issues have been solved and surface facility modifications have been completed. It is anticipated that filling operations will run for another 6-12 months from July 1, 2005. In most other aspects, the demonstration is going well and hydrocarbon production has been stabilized at an average rate of 57 BOPD (July-Dec, 2005). Our industry partners continue to experiment with injection rates and pressures, various downhole and surface facility mechanical configurations, and the huff-n-puff technique to develop best practices for these types of enhanced recovery projects. Subsurface characterization was completed using well log tomography and 3D visualizations to map facies distributions and reservoir properties in the Belle River Mills, Chester 18, Dover 35, and Dover 36 Fields. The Belle River Mills and Chester 18 fields are being used as type-fields because they have excellent log and/or core data coverage. Amplitude slicing of the log porosity, normalized gamma ray, core permeability, and core porosity curves are showing trends that indicate significant heterogeneity and compartmentalization in these reservoirs associated with the original depositional fabric and pore types of the carbonate reservoir rocks. Accumulated pressure data supports the hypothesis of extreme heterogeneity in the Dover 35. Some intervals now have pressure readings over 2345 psig (April 29, 2005) in the A-1 Carbonate while nearby Niagaran Brown intervals only show 1030 psig (March 7, 2005). This is a pressure differential over 1300 psig and suggests significant vertical barriers in the reef, consistent with the GR tomography modeling. Digital and hard copy data have been compiled for the Niagaran reefs in the Michigan Basin, including a detailed summary of 20 fields in the vicinity of the demonstration well. Technology transfer took place through technical presentations regarding visualization of the reservoir heterogeneity in these Niagaran reefs. Oral presentations were given at two Petroleum Technology Transfer Council workshops, a Michigan Oil and Gas Association Conference, a Michigan Basin Geological Society meeting, and the Eastern American Association of Petroleum Geologist's Annual meeting. In addition, we met with our industry partners several times during the first half of 2005 to communicate and discuss the reservoir characterization and field site aspects of the demonstration project. A technical paper was published in the April 2005 issue of the AAPG Bulletin on the characterization of the Belle River Mills Field.

  6. INFLUENCE OF CAPILLARY PRESSURE ON CO2 STORAGE AND MONITORING

    E-Print Network [OSTI]

    Santos, Juan

    volume - 1 + + = + - 1 + = : 2 solubility in brine : 2 formation volume factor : brine formation volume factor The Black-Oil formulation = - - = - - Darcy's Empirical Law + = 1 - = : capillary pressure brine brine CO2 CO2 #12;· The numerical solution was obtained

  7. atmospheric co2 face: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Duke Forest free-air CO2 enrichment (FACE) study. Rates of An Katul, Gabriel 11 Soil carbon sequestration in a pine forest after 9 years of atmospheric CO2 enrichment...

  8. air co2 enrichment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with increasing CO2 between ambient (1.0x California at Santa Cruz, University of 13 Soil carbon sequestration in a pine forest after 9 years of atmospheric CO2 enrichment...

  9. Formation Damage due to CO2 Sequestration in Saline Aquifers

    E-Print Network [OSTI]

    Mohamed, Ibrahim Mohamed 1984-

    2012-10-25T23:59:59.000Z

    Carbon dioxide (CO2) sequestration is defined as the removal of gas that would be emitted into the atmosphere and its subsequent storage in a safe, sound place. CO2 sequestration in underground formations is currently being considered to reduce...

  10. Near Miscible CO2 Application to Improve Oil Recovery

    E-Print Network [OSTI]

    Bui, Ly H.

    2010-07-26T23:59:59.000Z

    Carbon dioxide (CO2) injection for enhanced oil recovery is a proven technology. CO2 injection is normally operated at a pressure above the minimum miscibility pressure (MMP), which is determined by crude oil composition and reservoir conditions...

  11. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    157 WELL INTEGRITY IN CO 2 ENVIRONMENTS: PERFORMANCE, RISK,of CO 2 injection, wells integrity and long term behavior ofcan compromise the well integrity and thus its functional

  12. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of carbon dioxide (CO2). The minerals may affect the reservoir storage capacity as well as the integrity of its natural seals such as caprock formations. CO2 interaction...

  13. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that...

  14. Enhanced Geothermal Systems (EGS) with CO2 as Heat Transmission...

    Open Energy Info (EERE)

    problems of aqueous fluids, make heretofore inaccessible energy resources available for human use, and provide ancillary benefits by using and storing CO2. A CO2-based EGS is...

  15. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01T23:59:59.000Z

    projects based CO 2 enhanced oil recovery in the US. Energydeveloped for CO 2 -enhanced oil recovery. In: 16th SPE/DOEpurposes such as enhanced oil recovery (EOR) and enhanced

  16. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2007 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

  17. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

  18. Formation Damage due to CO2 Sequestration in Saline Aquifers

    E-Print Network [OSTI]

    Mohamed, Ibrahim Mohamed 1984-

    2012-10-25T23:59:59.000Z

    the amount of CO2 emitted into the atmosphere. However, a better understanding of the chemical and physical interactions between CO2, water, and formation rock is necessary before sequestration. These interactions can be evaluated by the change in mineral...

  19. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    WITH HETEROGENEITY IN OIL AND GAS RESERVOIRS APPLIED TO CO 2sedimentary basins, oil and gas fields, and industrial CO 2Harr, C.L. , 1996, Paradox oil and gas potential of the Ute

  20. CO2 capture processes in power plants - Le captage du CO2 dans les centrales thermiques

    E-Print Network [OSTI]

    Chakib Bouallou

    2010-08-12T23:59:59.000Z

    This review is devoted to assess and compare various processes aiming at recover CO2 from power plants fed with natural gas (NGCC) and pulverized coal (PC). These processes are post combustion CO2 capture using chemical solvents, natural gas reforming for pre-combustion capture and oxy-fuel combustion with cryogenic recovery of CO2. These processes were evaluated to give some clues for choosing the best option for each type of power plant. The comparison of these various concepts suggests that, in the short and medium term, chemical absorption is the most interesting process for NGCC power plants. For CP power plants, oxy-combustion can be a very interesting option, as well as post-combustion capture by chemical solvents.

  1. Investigation of Efficiency Improvements During CO2 Injection in Hydraulically and Naturally Fractured Reservoirs

    SciTech Connect (OSTI)

    Schechter, David S.; Vance, Harold

    2003-03-10T23:59:59.000Z

    The objective of this project was to perform unique laboratory experiments with artificial fractured cores (AFCs) and X-ray CT to examine the physical mechanisms of bypassing in HFR and NFR that eventually result in less efficient CO2 flooding in heterogeneous or fracture-dominated reservoirs. This report provided results of the second semi-annual technical progress report that consists of three different topics.

  2. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in India's Cement Industry

    E-Print Network [OSTI]

    Morrow III, William R.

    2014-01-01T23:59:59.000Z

    ModelInputs EmissionsFactors CO2EmissionfactorforgridtonneCO2/MWh) CO2Emissionfactorforfuel (tonneCO2/TJ)Improvements and CO2 Emission Reduction Potentials in the

  3. electroseismic monitoring of co2 sequestration: a finite element ...

    E-Print Network [OSTI]

    Fabio Zyserman

    Keywords: Electroseismic Modeling, Poroelasticity, CO2 sequestration, Finite element methods. 2000 AMS ... carbon dioxide emissisons into the atmosphere.

  4. Gravity monitoring of CO2 movement during sequestration: Model studies

    E-Print Network [OSTI]

    Gasperikova, E.

    2008-01-01T23:59:59.000Z

    form of enhanced petroleum production as CO 2 is injected.for monitoring production in petroleum reservoirs. The cost

  5. CO2 stabilization, climate change and the terrestrial carbon sink

    E-Print Network [OSTI]

    White, Andrew

    CO2 stabilization, climate change and the terrestrial carbon sink A N D R E W W H I T E , * M E L V, Hybrid v4.1, with a subdaily timestep, was driven by increasing CO2 and transient climate output from scenarios were used: (i) IS92a, giving 790 ppm CO2 by 2100, (ii) CO2 stabilization at 750 ppm by 2225

  6. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01T23:59:59.000Z

    potential CO 2 storage and water extraction projects based on the efforts findings DOEs Interagency CCS

  7. Gravity monitoring of CO2 movement during sequestration: Model studies

    E-Print Network [OSTI]

    Gasperikova, E.

    2008-01-01T23:59:59.000Z

    combined CO 2 enhanced oil recovery (EOR) and sequestrationMODEL The enhanced oil recovery (EOR)/sequestration

  8. Process development and techno-economic analysis of a novel process for MeOH production from CO2 using solar-thermal energy.

    SciTech Connect (OSTI)

    Henao, Carlos (University of Wisconsin); Kim, Jiyong (University of Wisconsin); Johnson, Terry Alan; Stechel, Ellen Beth; Dedrick, Daniel E.; Maravelias, Christos T. (University of Wisconsin); Miller, James Edward

    2010-11-01T23:59:59.000Z

    Mitigating and overcoming environmental problems brought about by the current worldwide fossil fuel-based energy infrastructure requires the creation of innovative alternatives. In particular, such alternatives must actively contribute to the reduction of carbon emissions via carbon recycling and a shift to the use of renewable sources of energy. Carbon neutral transformation of biomass to liquid fuels is one of such alternatives, but it is limited by the inherently low energy efficiency of photosynthesis with regard to the net production of biomass. Researchers have thus been looking for alternative, energy-efficient chemical routes inspired in the biological transformation of solar power, CO2 and H2O into useful chemicals; specifically, liquid fuels. Methanol has been the focus of a fair number of publications for its versatility as a fuel, and its use as an intermediate chemical in the synthesis of many compounds. In some of these studies, (e.g. Joo et al., (2004), Mignard and Pritchard (2006), Galindo and Badr (2007)) CO2 and renewable H2 (e.g. electrolytic H2) are considered as the raw materials for the production of methanol and other liquid fuels. Several basic PFD diagrams have been proposed. One of the most promising is the so called CAMERE process (Joo et al., 1999 ). In this process, carbon dioxide and renewable hydrogen are fed to a first reactor and transformed according to: H2 + CO2 <=> H2O + CO Reverse Water Gas Shift (RWGS) After eliminating the produced water the resulting H2/CO2/CO mixture is then feed to a second reactor where it is converted to methanol according to: CO2 + 3.H2 <=> CH3OH + H2O Methanol Synthesis (MS) CO + H2O <=> CO2 + H2 Water Gas Shift (WGS) The approach here is to produce enough CO to eliminate, via WGS, the water produced by MS. This is beneficial since water has been proven to block active sites in the MS catalyst. In this work a different process alternative is presented: One that combines the CO2 recycling of the CAMERE process and the use of solar energy implicit in some of the biomass-based process, but in this case with the potential high energy efficiency of thermo-chemical transformations.

  9. COMBUSTION-ASSISTED CO2 CAPTURE USING MECC MEMBRANES

    SciTech Connect (OSTI)

    Brinkman, K.; Gray, J.

    2012-03-30T23:59:59.000Z

    Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO{sub 2} from power plant flue gas. Here a modified MECC CO{sub 2} capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO{sub 2} driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO{sub 2} in the flue gas may be captured, and a compressed CO{sub 2} product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO{sub 2} capture system, and has the potential to meet U.S. DOE's goal that deployment of a CO{sub 2} capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

  10. Post-Combustion CO2 Capture 11 -13 July 2010

    E-Print Network [OSTI]

    Post-Combustion CO2 Capture Workshop 11 - 13 July 2010 Tufts European Center Talloires, France Institute | | Clean Air Task Force | | Asia Clean Energy Innovation Initiative | #12;Post-Combustion CO2 Capture Workshop 11 - 13 July 2010 Talloires, France PROCEEDINGS: Post-Combustion CO2 Capture Workshop

  11. ORIGINAL ARTICLE Navajo SandstonebrineCO2 interaction: implications

    E-Print Network [OSTI]

    Zhu, Chen

    ORIGINAL ARTICLE Navajo SandstonebrineCO2 interaction: implications for geological carbon to the injected CO2 is largely unknown. Experiments involving the reac- tion of Navajo Sandstone with acidic brine experiment examined sandstone interaction with CO2-impregnated brine; the second experiment examined

  12. A Numerical Investigation of Wettability Alteration during Immiscible CO2

    E-Print Network [OSTI]

    Hossain, M. Enamul

    A Numerical Investigation of Wettability Alteration during Immiscible CO2 Flooding Process, April 2012 #12;2 Table of Contest Abstract 3 Introduction 3 Literature Review 5 CO2 Flooding 7 New alteration during CO2 flooding. However, limited research on numerical and/or analytical modeling

  13. Original article Interactive effects of elevated CO2, O3,

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Original article Interactive effects of elevated CO2, O3, and soil water deficit on spring wheat of elevated carbon dioxide (CO2), ozone (O3), and soil water deficit on spring wheat (Triticum aestivum L. cv consisting of two O3levels (ambient and 1.5-times ambient) in combination with two CO2levels (ambient

  14. Cimpor inventa nova frmula para reduzir pegada de CO2

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    Cimpor inventa nova frmula para reduzir pegada de CO2 CIMENTO. A Cimpor descobriu uma nova frmula para produzir ci- mento que lhe permitir reduzir a pegada de CO 2 em 25%. Segundo as contas da as fbricas do grupo, seriam emitidos menos quatro milhes de toneladas de CO 2 por ano, o que permitiria uma

  15. results and benefits... Birmingham Cutting your CO2

    E-Print Network [OSTI]

    Everest, Graham R

    results and benefits... Birmingham Cutting your CO2 Birmingham City Council July 2007 c a s e s t u of the BirminghamCutting CO2 campaign, news items, display materials etc. · Advising on pledge gathering materials system was launched in July 2007 as part of the `Birmingham Cutting Your CO2' campaign. By the end

  16. Aquatic primary production in a high-CO2 world

    E-Print Network [OSTI]

    Fussman, Gregor

    Aquatic primary production in a high-CO2 world Etienne Low-Decarie, Gregor F. Fussmann, and Graham-Penfield, Montreal, QC, H3A 1B1, Canada Here, we provide a review of the direct effect of increas- ing CO2 on aquatic: the assessment of theories about limitation of productivity and the integration of CO2 into the co

  17. CO2 Emissions Mitigation and Technological Advance: An

    E-Print Network [OSTI]

    PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Updated Analysis of Advanced/2003) #12;PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Analysis of Advanced Technology of atmospheric CO2 concentrations at 450 parts per million by volume (ppmv) and 550 ppmv in MiniCAM. Each

  18. CO2-avskiljning med syrgasfrbrnning -nya tekniska mjligheter

    E-Print Network [OSTI]

    Lemurell, Stefan

    CO2-avskiljning med syrgasförbränning - nya tekniska möjligheter Klas Andersson Avd. Energiteknik Chalmers Tekniska Högskola Chalmers Energikonferens 14 december 2012 #12;· Combustion and CO2 capture with power and industrial sectors #12;Air-Fuel Combustion Air Fuel Flue gas CO2: 10-20 % N2: 60

  19. Central serotonin neurons are required for arousal to CO2

    E-Print Network [OSTI]

    Central serotonin neurons are required for arousal to CO2 Gordon F. Buchanana,b,1 and George B neurons are stimulated by CO2, and sero- tonin activates thalamocortical networks, we hypothesized any arousal response to inhalation of 10% CO2 (with 21% O2 in balance N2) but had normal arousal

  20. Center for By-Products Utilization CO2 SEQUESTRATION

    E-Print Network [OSTI]

    Saldin, Dilano

    climate change, reduced GHGs, improved air quality, CO2 reduction & sequestration, and carbon offsets. #12 for the development of a technology for the carbon dioxide (CO2) sequestration in non-air entrained concreteCenter for By-Products Utilization CO2 SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE By Tarun R. Naik

  1. Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Rainbolt, James E.; Zheng, Feng

    2010-11-10T23:59:59.000Z

    Current chemical CO2 scrubbing technology is primarily aqueous alkanolamine based. These systems rapidly bind CO2 (forming water-soluble carbamate and bicarbonate salts) however, the process has serious disadvantages. The concentration of monoethanolamine rarely exceeds 30 wt % due to the corrosive nature of the solution, and this reduces the maximum CO2 volumetric (?108 g/L) and gravimetric capacity (?7 wt%) of the CO2 scrubber. The ?30 wt % loading of ethanolamine also means that a large excess of water must be pumped and heated during CO2 capture and release, and this greatly increases the energy requirements especially considering the high specific heat of water (4 j/g-1K-1). Our approach is to switch to organic systems that chemically bind CO2 as liquid alkylcarbonate salts. Our CO2-binding organic liquids have higher CO2 solubility, lower specific heats, potential for less corrosion and lower binding energies for CO2 than aqueous systems. CO2BOLs also reversibly bind and release mixed sulfur oxides. Furthermore the CO2BOL system can be direct solvent replacements for any solvent based CO2 capture systems because they are commercially available reagents and because they are fluids they would not require extensive process re-engineering.

  2. Chemical Looping Combustion for inherent CO2 capture in a

    E-Print Network [OSTI]

    Evaluate CLC using syngas as fuel Effect of fuel Effect of operating conditions Use CLC for CO2-capture Reactor System O2,N2 CO2,H2O To CO2 recovery and compression #12;15 Clean syngas from different gasifiers

  3. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2006 Quarterly Progress the process for CO2 capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous.................................................................................................................................... 8 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  4. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing...................................................................................................................................11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  5. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Second Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing.................................................................................................................................. 10 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  6. Forest Research Annual Report and Accounts

    E-Print Network [OSTI]

    that power generators wishing to co-fire coal with non-fossil fuels will source at least a proportion

  7. Study of CO2 Mobility Control Using Cross-linked Gel Conformance Control and CO2 Viscosifiers in Heterogeneous Media

    E-Print Network [OSTI]

    Cai, Shuzong

    2011-10-21T23:59:59.000Z

    CO2 has been widely used as a displacement fluid in both immiscible and miscible displacement processes to obtain tertiary recovery from the field. There are several problems associated with the application of CO2 flooding, especially when...

  8. Directed Technical Change and the Adoption of CO2 Abatement Technology: The Case of CO2 Capture and Storage

    E-Print Network [OSTI]

    Otto, Vincent M.

    This paper studies the cost effectiveness of combining traditional environmental policy, such as CO2 trading schemes, and technology policy that has aims of reducing the cost and speeding the adoption of CO2 abatement ...

  9. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    E-Print Network [OSTI]

    Birkholzer, Jens

    2008-01-01T23:59:59.000Z

    Changes in Response to CO2 Leakage from Deep Geologicalstudy mineral trapping for CO2 disposal in deep arenaceousconstituents as function of P(CO2)? function of P(CO2)?

  10. Global Carbon Emissions in the Coming Decades: The Case of China

    E-Print Network [OSTI]

    Levine, Mark D.

    2008-01-01T23:59:59.000Z

    CO2 IEA estimate LBNL estimate ORNL estimate Sources: IEA, Carbon Emissions from Fossil Fuel Combustion

  11. INTEGRATING MEA REGENERATION WITH CO2 COMPRESSION AND PEAKING TO REDUCE CO2 CAPTURE COSTS

    E-Print Network [OSTI]

    Rochelle, Gary T.

    system with no compression heat recovery, CO2 vapor recompression heat recovery, and multipressure stripping with and without vapor recompression heat recovery. These configurations were simulated using of power for sale to the grid based on 500 MW unit ) clearly outweighed the modest increases in capital

  12. Rate Determination of the CO2* Chemiluminescence Reaction CO + O + M = CO2* + M

    E-Print Network [OSTI]

    Kopp, Madeleine Marissa, 1987-

    2012-10-15T23:59:59.000Z

    flame characteristics, such as fuel consumption rate, heat release rate, and H-atom concentration. In 2002, Kim et al. [2] made detailed spectral measurements in SI, HCCI, and SCCI engines from various excited state species and determined that CO2...

  13. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01T23:59:59.000Z

    within 15% of nominal P. EPM2-SPC/E DZ- SPC/E PPL-SPC/EEPM2- TIP4P2005 PPL- TIP4P2005 Predicted (f) a P ? CO2 2SE ?to C and O atoms (Table 1). The PPL model (In Het Panhuis et

  14. CINETIQUES DE SORPTION DU CO2 DANS LE CADRE DU STOCKAGE GEOLOGIQUE DU CO2 DANS LE CHARBON

    E-Print Network [OSTI]

    Boyer, Edmond

    PROCESSES OF CO2 SORPTION FOR CO2 STORAGE IN COAL SEAMS Delphine CHARRIERE1, 2 , Zbigniew POKRYSZKA1 storage in coal seams and the enhancement on coalbed methane production requires information on the gas sorption mechanism of kinetics. In this work, both sorption kinetics of CO2 and CH4 are studied onto a coal

  15. Electric power annual 1992

    SciTech Connect (OSTI)

    Not Available

    1994-01-06T23:59:59.000Z

    The Electric Power Annual presents a summary of electric utility statistics at national, regional and State levels. The objective of the publication is to provide industry decisionmakers, government policymakers, analysts and the general public with historical data that may be used in understanding US electricity markets. The Electric Power Annual is prepared by the Survey Management Division; Office of Coal, Nuclear, Electric and Alternate Fuels; Energy Information Administration (EIA); US Department of Energy. ``The US Electric Power Industry at a Glance`` section presents a profile of the electric power industry ownership and performance, and a review of key statistics for the year. Subsequent sections present data on generating capability, including proposed capability additions; net generation; fossil-fuel statistics; retail sales; revenue; financial statistics; environmental statistics; electric power transactions; demand-side management; and nonutility power producers. In addition, the appendices provide supplemental data on major disturbances and unusual occurrences in US electricity power systems. Each section contains related text and tables and refers the reader to the appropriate publication that contains more detailed data on the subject matter. Monetary values in this publication are expressed in nominal terms.

  16. Annual Energy Review 1993

    SciTech Connect (OSTI)

    Not Available

    1994-07-14T23:59:59.000Z

    This twelfth edition of the Annual Energy Review (AER) presents the Energy Information Administration`s historical energy statistics. For most series, statistics are given for every year from 1949 through 1993. Because coverage spans four and a half decades, the statistics in this report are well-suited to long-term trend analyses. The AER is comprehensive. It covers all major energy activities, including consumption, production, trade, stocks, and prices, for all major energy commodities, including fossil fuels and electricity. The AER also presents Energy Information Administration (EIA) statistics on some renewable energy sources. EIA estimates that its consumption series include about half of the renewable energy used in the United States. For a more complete discussion of EIA`s renewables data, see p. xix, ``Introducing Expanded Coverage of Renewable Energy Data Into the Historical Consumption Series.`` Copies of the 1993 edition of the Annual Energy Review may be obtained by using the order form in the back of this publication. Most of the data in the 1993 edition also are available on personal computer diskette. For more information about the diskettes, see the back of this publication. In addition, the data are available as part of the National Economic, Social, and Environmental Data Bank on a CD-ROM. For more information about the data bank, contact the US Department of Commerce Economics and Statistics Administration, on 202-482-1986.

  17. Sequestration of Dissolved CO2 in the Oriskany Formation

    SciTech Connect (OSTI)

    Dilmore, R.M.; Allen, D.E. (Salem State College, Salem, MA); McCarthy-Jones, J.R.; Hedges, S.W.; Soong, Yee

    2008-04-15T23:59:59.000Z

    Experiments were conducted to determine the solubility of CO2 in a natural brine solution of the Oriskany formation under elevated temperature and pressure conditions. These data were collected at temperatures of 22 and 75 C and pressures between 100 and 450 bar. Experimentally determined data were compared with CO2 solubility predictions using a model developed by Duan and Sun (Chem. Geol. 2003, 193, 257-271). Model results compare well with Oriskany brine CO2 solubility data collected experimentally, suggesting that the Duan and Sun model is a reliable tool for estimating solution CO2 capacity in high salinity aquifers in the temperature and pressure range evaluated. The capacity for the Oriskany formation to sequester dissolved CO2 was calculated using results of the solubility models, estimation of the density of CO2 saturated brine, and available geographic information system (GIS) information on the formation depth and thickness. Results indicate that the Oriskany formation can hold approximately 0.36 gigatonnes of dissolved CO2 if the full basin is considered. When only the region where supercritical CO2 can exist (temperatures greater than 31 C and pressures greater than 74 bar) is considered, the capacity of the Oriskany formation to sequester dissolved CO2 is 0.31 gigatonnes. The capacity estimate considering the potential to sequester free-phase supercritical CO2 if brine were displaced from formation pore space is 8.8 gigatonnes in the Oriskany formation.

  18. Supersonic Technology for CO2 Capture: A High Efficiency Inertial CO2 Extraction System

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    IMPACCT Project: Researchers at ATK and ACENT Laboratories are developing a device that relies on aerospace wind-tunnel technologies to turn CO2 into a condensed solid for collection and capture. ATKs design incorporates a special nozzle that converges and diverges to expand flue gas, thereby cooling it off and turning the CO2 into solid particles which are removed from the system by a cyclonic separator. This technology is mechanically simple, contains no moving parts and generates no chemical waste, making it inexpensive to construct and operate, readily scalable, and easily integrated into existing facilities. The increase in the cost to coal-fired power plants associated with introduction of this system would be 50% less than current technologies.

  19. Electric power annual 1997. Volume 1

    SciTech Connect (OSTI)

    NONE

    1998-07-01T23:59:59.000Z

    The Electric Power Annual presents a summary of electric power industry statistics at national, regional, and State levels. The objective of the publication is to provide industry decisionmakers, government policy-makers, analysts, and the general public with data that may be used in understanding US electricity markets. The Electric Power Annual is prepared by the Electric Power Division; Office of Coal, Nuclear, Electric and Alternate Fuels; Energy Information Administration (EIA); US Department of Energy. Volume 1 -- with a focus on US electric utilities -- contains final 1997 data on net generation and fossil fuel consumption, stocks, receipts, and cost; preliminary 1997 data on generating unit capability, and retail sales of electricity, associated revenue, and the average revenue per kilowatthour of electricity sold (based on a monthly sample: Form EIA-826, ``Monthly Electric Utility Sales and Revenue Report with State Distributions``). Additionally, information on net generation from renewable energy sources and on the associated generating capability is included in Volume 1 of the EPA.

  20. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs

    SciTech Connect (OSTI)

    Grigg, Reid B.; Schechter, David S.

    1999-10-15T23:59:59.000Z

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

  1. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in India's Cement Industry

    E-Print Network [OSTI]

    Morrow III, William R.

    2014-01-01T23:59:59.000Z

    Factors CO2Emissionfactorforgridelectricity (tonneCO2Savings Figure 6. 2010-2030 Electricity and Electricity-Base CO 2 Emissions

  2. Estimation of CO2 Emissions from China's Cement Production: Methodologies and Uncertainties

    E-Print Network [OSTI]

    Ke, Jing

    2014-01-01T23:59:59.000Z

    L. , 2006. Discussion of CO2 emission reduction in ChineseFurther discussion of CO2 emission reduction in Chinesecalculation method of CO2 emissions of cement production.

  3. Final Report - "CO2 Sequestration in Cell Biomass of Chlorobium Thiosulfatophilum"

    SciTech Connect (OSTI)

    James L. Gaddy, PhD; Ching-Whan Ko, PhD

    2009-05-04T23:59:59.000Z

    World carbon dioxide emissions from the combustion of fossil fuels have increased at a rate of about 3 percent per year during the last 40 years to over 24 billion tons today. While a number of methods have been proposed and are under study for dealing with the carbon dioxide problem, all have advantages as well as disadvantages which limit their application. The anaerobic bacterium Chlorobium thiosulfatophilum uses hydrogen sulfide and carbon dioxide to produce elemental sulfur and cell biomass. The overall objective of this project is to develop a commercial process for the biological sequestration of carbon dioxide and simultaneous conversion of hydrogen sulfide to elemental sulfur. The Phase I study successfully demonstrated the technical feasibility of utilizing this bacterium for carbon dioxide sequestration and hydrogen sulfide conversion to elemental sulfur by utilizing the bacterium in continuous reactor studies. Phase II studies involved an advanced research and development to develop the engineering and scale-up parameters for commercialization of the technology. Tasks include culture isolation and optimization studies, further continuous reactor studies, light delivery systems, high pressure studies, process scale-up, a market analysis and economic projections. A number of anaerobic and aerobic microorgansims, both non-photosynthetic and photosynthetic, were examined to find those with the fastest rates for detailed study to continuous culture experiments. C. thiosulfatophilum was selected for study to anaerobically produce sulfur and Thiomicrospira crunogena waws selected for study to produce sulfate non-photosynthetically. Optimal conditions for growth, H2S and CO2 comparison, supplying light and separating sulfur were defined. The design and economic projections show that light supply for photosynthetic reactions is far too expensive, even when solar systems are considered. However, the aerobic non-photosynthetic reaction to produce sulfate with T. crunogena produces a reasonable return when treating a sour gas stream of 120 million SCFD containing 2.5 percent H2S. In this case, the primary source of revenue is from desulfurization of the gas stream. While the technology has significant application in sequestering carbon dioxide in cell biomass or single cell proten (SCP), perhaps the most immediate application is in desulfurizing LGNG or other gas streams. This biological approach is a viable economical alternative to existing hydrogen sulfide removal technology, and is not sensitive to the presence of hydrocarbons which act as catalyst poisons.

  4. Uncertainty quantification for CO2 sequestration and enhanced oil recovery

    E-Print Network [OSTI]

    Dai, Zhenxue; Fessenden-Rahn, Julianna; Middleton, Richard; Pan, Feng; Jia, Wei; Lee, Si-Yong; McPherson, Brian; Ampomah, William; Grigg, Reid

    2014-01-01T23:59:59.000Z

    This study develops a statistical method to perform uncertainty quantification for understanding CO2 storage potential within an enhanced oil recovery (EOR) environment at the Farnsworth Unit of the Anadarko Basin in northern Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil-water flow and reactive transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major uncertainty metrics: net CO2 injection, cumulative oil production, cumulative gas (CH4) production, and net water injection. A global sensitivity and response surface analysis indicates that reservoir permeability, porosity, and thickness are the major intrinsic reservoir parameters that control net CO2 injection/storage and oil/gas recovery rates. The well spacing and the initial water saturation also have large impact on the oil/gas recovery rates. Further, this study has revealed key insights into the potential behavior and the operational parameters of CO2 sequestration at CO2-EOR s...

  5. Japan's Long-term Energy Demand and Supply Scenario to 2050 - Estimation for the Potential of Massive CO2 Mitigation

    E-Print Network [OSTI]

    Komiyama, Ryoichi

    2010-01-01T23:59:59.000Z

    scenario, electricity generation using non-fossil fuels willhome fuel cell and other electricity generation systemsFuel Cells The introduction of distributed generation sources is expected to help reduce investment in electricity

  6. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    SciTech Connect (OSTI)

    G. Fridley, David; Zheng, Nina; T. Aden, Nathaniel

    2010-07-01T23:59:59.000Z

    After rapid growth in economic development and energy demand over the last three decades, China has undertaken energy efficiency improvement efforts to reduce its energy intensity under the 11th Five Year Plan (FYP). Since becoming the world's largest annual CO{sub 2} emitter in 2007, China has set reduction targets for energy and carbon intensities and committed to meeting 15% of its total 2020 energy demand with non-fossil fuel. Despite having achieved important savings in 11th FYP efficiency programs, rising per capita income and the continued economic importance of trade will drive demand for transport activity and fuel use. At the same time, an increasingly 'electrified' economy will drive rapid power demand growth. Greater analysis is therefore needed to understand the underlying drivers, possible trajectories and mitigation potential in the growing industrial, transport and power sectors. This study uses scenario analysis to understand the likely trajectory of China's energy and carbon emissions to 2030 in light of the current and planned portfolio of programs, policies and technology development and ongoing urbanization and demographic trends. It evaluates the potential impacts of alternative transportation and power sector development using two key scenarios, Continued Improvement Scenario (CIS) and Accelerated Improvement Scenario (AIS). CIS represents the most likely path of growth based on continuation of current policies and meeting announced targets and goals, including meeting planned appliance efficiency standard revisions, fuel economy standards, and industrial targets and moderate phase-out of subcritical coal-fired generation with additional non-fossil generation. AIS represents a more aggressive trajectory of accelerated improvement in energy intensity and decarbonized power and transport sectors. A range of sensitivity analysis and power technology scenarios are tested to evaluate the impact of additional actions such as carbon capture and sequestration (CCS) and integrated mine-mouth generation. The CIS and AIS results are also contextualized and compared to model scenarios in other published studies. The results of this study show that China's energy and CO{sub 2} emissions will not likely peak before 2030, although growth is expected to slow after 2020. Moreover, China will be able to meet its 2020 carbon intensity reduction target of 40 to 45% under both CIS and AIS, but only meet its 15% non-fossil fuel target by 2020 under AIS. Under both scenarios, efficiency remains a key resource and has the same, if not greater, mitigation potential as new technologies in transport and power sectors. In the transport sector, electrification will be closely linked the degree of decarbonization in the power sector and EV deployment has little or no impact on China's crude oil import demand. Rather, power generation improvements have the largest sector potential for overall emission mitigation while mine-mouth power generation and CCS have limited mitigation potential compared to fuel switching and efficiency improvements. Comparisons of this study's results with other published studies reveal that CIS and AIS are within the range of other national energy projections but alternative studies rely much more heavily on CCS for carbon reduction. The McKinsey study, in particular, has more optimistic assumptions for reductions in crude oil imports and coal demand in its abatement scenario and has much higher gasoline reduction potential for the same level of EV deployment. Despite these differences, this study's scenario analysis of both transport and power sectors illustrate the necessity for continued efficiency improvements and aggressive power sector decarbonization in flattening China's CO{sub 2} emissions.

  7. Center for Nanoscale Control of Geologic CO2 (EFRC) - Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary The objective of the DOE Energy Frontier Research Center (EFRC) for Nanoscale Control of Geologic CO2 (NCGC) is to use new investigative tools, combined with experiments...

  8. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01T23:59:59.000Z

    The geomechanics of CO 2 storage in deep sedimentaryThis paper provides a review of the geomechanics andmodeling of geomechanics associated with geologic carbon

  9. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01T23:59:59.000Z

    CO 2 Geological Storage and Ground Water Resources U.S.and Ground Water Protection Council (GWPC) State and Federal Statutes Storage,

  10. Advanced Post-Combustion CO2 Capture Prepared for the

    E-Print Network [OSTI]

    Advanced Post-Combustion CO2 Capture Prepared for the Clean Air Task Force under a grant from...................................................................................... 3 2. Current Status of Post-Combustion Capture

  11. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01T23:59:59.000Z

    Soviet Union (Ukraine, Kazakhstan, Belarus, and Russia),kg CO 2 /$GDP FSS Ukraine Kazakhstan Iran East Asia BelarusAsia China South Africa Kazakhstan Malaysia Russia Thailand

  12. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01T23:59:59.000Z

    strain and microseismicity, well integrity, caprock sealingstrain and microseismicity, well integrity, caprock sealingactions. 7 WELLBORE INTEGRITY The well design of a deep CO 2

  13. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01T23:59:59.000Z

    Efforts Investigating Water Extraction ! LLNL ! Active CObenefits of various water extraction, treatment, and reuseof CO 2 storage and water extraction scenarios ! Technical

  14. Influence of capillary pressure on CO2 storage and monitoring

    E-Print Network [OSTI]

    gabriela

    solutions to mitigate the greenhouse effect. We are interested in analyzing the influence of capillary pressure on CO2 in- jection, storage and monitoring in saline...

  15. Micromodel Investigations of CO2 Exsolution from Carbonated Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of CO2 Exsolution from Carbonated Water in Sedimentary Rocks. Abstract: In this study, carbon dioxide exsolution from carbonated water is directly observed under reservoir...

  16. CO2 exposure at pressure impacts metabolism and stress responses...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the model sulfate-reducing bacterium Desulfovibrio vulgaris Abstract: Geologic carbon dioxide (CO2) sequestration drives physical and geochemical changes in deep...

  17. Enhanced Geothermal Systems (EGS) with CO2as Heat Transmission...

    Broader source: Energy.gov (indexed) [DOE]

    Program eere.energy.gov * The project started in FY10 * Collaboration between LBNL (Pruess) and INL (Redden) - Berkeley leads modeling, CO 2 -brine flow and heat...

  18. Quantum Alloys Offer Prospects for CO2 Management Technologies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    radical new catalysts capable of converting CO2 emissions into fuels, chemicals, and plastics. Their unique discovery involves shrinking gold into a system consisting of just 25...

  19. atmospheric co2 content: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  20. atmospheric co2 concentrations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  1. atmospheric co2 concentration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  2. atmospheric co2 laser: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  3. atmospheric co2 measurements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  4. atmospheric co2 variations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  5. atmospheric co2 mixing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  6. PHASING OUUT FOSSIL-FUEL SUBSIDIES

    E-Print Network [OSTI]

    In; A Roadmap; Fo Or; Prepared For The

    2010-01-01T23:59:59.000Z

    construed as interpreting or modifying any legal obligations under the WTO Agreements, treaty, law or other texts, or as expressing any legal opinions or havinng probative legal value in any proceedings. Table of Contents Page | 2 Executive Summary............................................................................................................ 3

  7. Disclosure of Permitted Communication Concerning Fossil Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    DOE 433 ex parte memo.pdf More Documents & Publications Disclosure of Permitted Communication Concerning Regional Standards Enforcement Framework Document -- Docket No....

  8. Statistical analysis of correlated fossil fuel securities

    E-Print Network [OSTI]

    Li, Derek Z

    2011-01-01T23:59:59.000Z

    Forecasting the future prices or returns of a security is extraordinarily difficult if not impossible. However, statistical analysis of a basket of highly correlated securities offering a cross-sectional representation of ...

  9. Fossil fuel combined cycle power system

    DOE Patents [OSTI]

    Labinov, Solomon Davidovich; Armstrong, Timothy Robert; Judkins, Roddie Reagan

    2006-10-10T23:59:59.000Z

    A system for converting fuel energy to electricity includes a reformer for converting a higher molecular weight gas into at least one lower molecular weight gas, at least one turbine to produce electricity from expansion of at least one of the lower molecular weight gases, and at least one fuel cell. The system can further include at least one separation device for substantially dividing the lower molecular weight gases into at least two gas streams prior to the electrochemical oxidization step. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  10. Fossil fuel combined cycle power generation method

    DOE Patents [OSTI]

    Labinov, Solomon D [Knoxville, TN; Armstrong, Timothy R [Clinton, TN; Judkins, Roddie R [Knoxville, TN

    2008-10-21T23:59:59.000Z

    A method for converting fuel energy to electricity includes the steps of converting a higher molecular weight gas into at least one mixed gas stream of lower average molecular weight including at least a first lower molecular weight gas and a second gas, the first and second gases being different gases, wherein the first lower molecular weight gas comprises H.sub.2 and the second gas comprises CO. The mixed gas is supplied to at least one turbine to produce electricity. The mixed gas stream is divided after the turbine into a first gas stream mainly comprising H.sub.2 and a second gas stream mainly comprising CO. The first and second gas streams are then electrochemically oxidized in separate fuel cells to produce electricity. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  11. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Biofuels vs Fossil Fuels

    Broader source: Energy.gov [DOE]

    This infographic was created by students from North Caddo Magnet High School in Vivian, LA, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME...

  12. US fossil fuel technologies for Thailand

    SciTech Connect (OSTI)

    Buehring, W.A.; Dials, G.E.; Gillette, J.L.; Szpunar, C.B.; Traczyk, P.A.

    1990-10-01T23:59:59.000Z

    The US Department of Energy has been encouraging other countries to consider US coal and coal technologies in meeting their future energy needs. Thailand is one of three developing countries determined to be a potentially favorable market for such exports. This report briefly profiles Thailand with respect to population, employment, energy infrastructure and policies, as well as financial, economic, and trade issues. Thailand is shifting from a traditionally agrarian economy to one based more strongly on light manufacturing and will therefore require increased energy resources that are reliable and flexible in responding to anticipated growth. Thailand has extensive lignite deposits that could fuel a variety of coal-based technologies. Atmospheric fluidized-bed combustors could utilize this resource and still permit Thailand to meet emission standards for sulfur dioxide. This option also lends itself to small-scale applications suitable for private-sector power generation. Slagging combustors and coal-water mixtures also appear to have potential. Both new construction and refurbishment of existing plants are planned. 18 refs., 3 figs., 7 tabs.

  13. Microsoft Word - Fossil Fuel EA Final EA

    Office of Environmental Management (EM)

    The National Academy of Sciences (NAS) estimates that 15,400 to 21,800 people in the United States die from lung cancer attributable to radon, although the number could be as...

  14. OpenEI Community - fossil fuels

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcernsCompany Oil and GasOff<div/0 en The Energy

  15. Factor CO2 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A PotentialJumpGerman AerospaceEfficiency Incentives andFVE BS sroFaconFactor

  16. Microsoft Word - CO2 Supplement.doc

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 3400,Information Administration2 U.S. Energy InformationAnnual9

  17. CO2 Europipe | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:Power LP Biomass Facilityin Charts Jump to:List Serve

  18. CO2 Tech | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:Power LP Biomass Facilityin Charts Jump to:List ServeGlobal Solutions

  19. CENIT CO2 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation inOpen Energy Information BurkinaButyl FuelCCCTCECGCEFEMCENIT

  20. CO2 | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation inOpen Energy InformationSeries Jump to:CMR FuelCNOOCEmissions

  1. ORNL/CDIAC-160 Climatological Distributions of pH, pCO2, Total CO2, Alkalinity,

    E-Print Network [OSTI]

    ORNL/CDIAC-160 NDP-094 Climatological Distributions of pH, pCO2, Total CO2, Alkalinity, and CaCO3, Alkalinity, and CaCO3 Saturation in the Global Surface Ocean. ORNL/CDIAC-160, NDP-094. Carbon Dioxide, total CO2 concentration (TCO2), and the degree of CaCO3 saturation for the global surface ocean waters

  2. A Theoretical Study of CO2 Anions on Anatase (101) Surface. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Anions on Anatase (101) Surface. A Theoretical Study of CO2 Anions on Anatase (101) Surface. Abstract: Binding configurations of CO2 and CO2 - on perfect and oxygen-deficient...

  3. Inducinga CO2 leak into ashallow aquifer (CO2FieldLab EUROGIA+ project): Monitoring the CO2 plume in groundwaters.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    (saline aquifer, depleted oil/gas reservoir), aquifers are ubiquitousin the overlying sedimentary pile in case of unwanted CO2leakages from a storage site. Independently from the nature of the reservoir

  4. Solid molecular basket sorbent for CO2 capture from gas streams with low CO2 concentration at ambient conditions

    SciTech Connect (OSTI)

    Wang, Xiaoxing [Pennsylvania State University; Ma, Xiaoliang [Pennsylvania State University; Schwartz, Viviane [ORNL; Clark, Jason C [ORNL; Overbury, Steven {Steve} H [ORNL; Zhao, Shuqi [Pennsylvania State University, University Park, PA; Xu, Xiaochun [Pennsylvania State University; Song, Chunshan [Pennsylvania State University

    2012-01-01T23:59:59.000Z

    In this paper, a solid molecular basket sorbent, 50 wt% PEI/SBA-15 was studied for CO2 capture from gas streams with low CO2 concentration at ambient conditions. The sorbent was able to effectively and selectively capture CO2 from a gas stream containing 1% CO2 at 75 C, with a breakthrough and saturation capacity of 63.1 and 66.7 mg/g, respectively, and a selectivity of 14 for CO2/CO and 185 for CO2/Ar. The sorption performance of the sorbent was influenced greatly by the operating temperature. The CO2-TPD study showed that the sorbent could be regenerated at mild conditions (50-110 C) and was stable in the cyclical operations for at least 20 cycles. Furthermore, the possibility for CO2 capture from air using the PEI/SBA-15 sorbent was studied by FTIR and proved by TPD. A capacity of 22.5 mg/g was attained at 75 C via TPD method using a simulated air with 400 ppmv CO2 in N2.

  5. Leakage and Sepage of CO2 from Geologic Carbon Sequestration Sites: CO2 Migration into Surface Water

    E-Print Network [OSTI]

    Oldenburg, Curt M.; Lewicki, Jennifer L.

    2005-01-01T23:59:59.000Z

    from geologic carbon sequestration sites: unsaturated zoneCO 2 from Geologic Carbon Sequestration Sites, Vadose Zoneseepage from geologic carbon sequestration sites may occur.

  6. EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2

    SciTech Connect (OSTI)

    Earl D. Mattson; Travis L. McLing; William Smith; Carl Palmer

    2013-02-01T23:59:59.000Z

    EGS using CO2 as a working fluid will likely involve hydro-shearing low-permeability hot rock reservoirs with a water solution. After that process, the fractures will be flushed with CO2 that is maintained under supercritical conditions (> 70 bars). Much of the injected water in the main fracture will be flushed out with the initial CO2 injection; however side fractures, micro fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolution/precipitation reactions in the resulting scCO2/brine/rock systems have the potential to significantly alter reservoir permeability, so it is important to understand where these precipitates form and how are they related to the evolving free connate water in the system. To examine dissolution / precipitation behavior in such systems over time, we have conducted non-stirred batch experiments in the laboratory with pure minerals, sandstone, and basalt coupons with brine solution spiked with MnCl2 and scCO2. The coupons are exposed to liquid water saturated with scCO2 and extend above the water surface allowing the upper portion of the coupons to be exposed to scCO2 saturated with water. The coupons were subsequently analyzed using SEM to determine the location of reactions in both in and out of the liquid water. Results of these will be summarized with regard to significance for EGS with CO2 as a working fluid.

  7. Novel CO2 Foam Concepts and Injection Schemes for Improving CO2 Sweep Efficiency in Sandstone and Carbonate Hydrocarbon Formations

    SciTech Connect (OSTI)

    Nguyen, Quoc; Hirasaki, George; Johnston, Keith

    2014-12-31T23:59:59.000Z

    We explored cationic, nonionic and zwitterionic surfactants to identify candidates that have the potential to satisfy all the key requirements for CO2 foams in EOR. We have examined the formation, texture, rheology and stability of CO2 foams as a function of the surfactant structure and formulation variables including temperature, pressure, water/CO2 ratio, surfactant concentration, salinity and concentration of oil. Furthermore, the partitioning of surfactants between oil and water as well as CO2 and water was examined in conjunction with adsorption measurements on limestone by the Hirasaki lab to develop strategies to optimize the transport of surfactants in reservoirs.

  8. Single photon ionization of van der Waals clusters with a soft x-ray laser: ,,CO2...n and ,,CO2...n,,H2O...m

    E-Print Network [OSTI]

    Rocca, Jorge J.

    Single photon ionization of van der Waals clusters with a soft x-ray laser: ,,CO2...n and ,,CO2...n 2006; published online 20 October 2006 Pure neutral CO2 n clusters and mixed CO2 n H2O m clustersV. The distribution of pure CO2 n clusters decreases roughly exponentially with increasing cluster size. During

  9. Greener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from the flue gases of coal-fired power plants would alleviate concerns

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    to remove CO2 from dilute gas streams because they have very high affinity for CO2. Unfortunately high solvents that balance high affinity for CO2 with ease of solvent recovery and reuse. Because the numberGreener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from

  10. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    E-Print Network [OSTI]

    Zhou, Nan

    2011-01-01T23:59:59.000Z

    Others* Air Conditioner Frozen Scenario Total CO2 EmissionsCO2 Emissions (million tonnes CO2)Improvement Scenario Total CO2 Emissions *Others include:

  11. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR57451 CleanFOR IMMEDIATE RELEASENovel CO 2

  12. Intercomparison of simulation models for CO2 disposal in underground storage reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten; Tsang, Chin-Fu; Law, David; Oldenburg, Curt

    2001-01-01T23:59:59.000Z

    oil recovery (EOR) using CO2 requires an understanding ofexperience with using CO2 for EOR projects (SPE, 1999), and

  13. Quantifying Regional Economic Impacts of CO2 Intensity Targets in China

    E-Print Network [OSTI]

    Zhang, Da

    2012-09-01T23:59:59.000Z

    To address rising energy use and CO2 emissions, Chinas leadership has enacted energy and CO2 intensity

  14. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01T23:59:59.000Z

    CO2 mitigation potential and costs in China's electricityCO2 mitigation potential and costs in China's electricity

  15. Detection of CO2 Seepage From Geological Sequestration Sites Using an Array of Downhole Pressure Gauges Jalal Jalali, Shahab D. Mohaghegh, Dept. of Petroleum & Natural Gas Engineering, West Virginia University

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    University 8th Annual Conference on Carbon Capture & Sequestration, May 4th 7th 2009, Pittsburgh, PA LongDetection of CO2 Seepage From Geological Sequestration Sites Using an Array of Downhole Pressure term monitoring of geologic sites used for CO2 sequestration is an environmental necessity while

  16. EIA - Annual Energy Outlook 2013 Early Release

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    share of total energy use, CO2 emissions per 2005 dollar of GDP decline more rapidly than energy use per 2005 dollar of GDP, falling by 56 percent from 2005 to 2040, at an annual...

  17. Uncertainty Analysis of Otway CO2 Sequestration Project Shohreh Amini 1,2

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    ,2, , Razi Gaskari3 , Grant Bromhal 1 (1 National Energy Technology Laboratory-Regional University Alliance with very low computational cost. Introduction Despite all the efforts in shifting the energy sources to the renewable and atmosphere friendly source of energy, fossil fuels are still the most essential source

  18. Cost Effectiveness of CO2 Mitigation Technologies and Policies in the Electricity Sector

    E-Print Network [OSTI]

    the professors at Rose-Hulman who inspired me and helped me pursue a career in the energy field: Mark Minster Foundation under Award no. SES-0949710 to the Climate and Energy Decision Making Center. I thank Jay Apt an engineering-economic analysis of hybridizing concentrating solar thermal power with fossil fuel. We examine

  19. Original article Responses to elevated atmospheric CO2 concentration

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Original article Responses to elevated atmospheric CO2 concentration and nitrogen supply of Quercus* School of Forest Resources and Conservation, University of Florida, 326 Newins-Ziegler Hall, Gainesville. Elevated [CO2] increased biomass production only in the high-N treatment. Fine root/foliage mass ratio

  20. Comprehensive Monitoring of CO2 Sequestration in Subalpine Forest Ecosystems

    E-Print Network [OSTI]

    Han, Richard Y.

    , carbon sequestration, ecosystem, multi-tier, multi-modal, multi-scale, self organized, sensor array to comprehensively monitor ecosystem carbon sequestration. The network consists of CO2, Weather (pressureComprehensive Monitoring of CO2 Sequestration in Subalpine Forest Ecosystems and Its Relation

  1. HYDROMECHANICAL CHARACTERIZATION FOR SITE SELECTION IN CO2 PERMANENT

    E-Print Network [OSTI]

    Politcnica de Catalunya, Universitat

    -BarcelonaTech), Barcelona, Spain 3 Energy City Foundation (CIUDEN), Spanish Government CO2 Geological Storage Programme (Vilarrasa et al., 2011, Energy Procedia) Trees killed by CO2 leakage in Mammoth Mountains (Farrar et al EQUATIONS Mass conservation equation Darcy's law Momentum balance Effective stress Hooke's law (linear

  2. The contribution of CO2 capture and storage

    E-Print Network [OSTI]

    The contribution of CO2 capture and storage to a sustainable energy system Policy brief the prospects of CO2 capture and storage (CCS) technologies in the power sector. Based on the results of 10. The uncertainties, particularly in storage capacities, are large. Using conservative estimates in line with the IPCC

  3. European and Global Perspectives for CO2 Capture and Storage

    E-Print Network [OSTI]

    European and Global Perspectives for CO2 Capture and Storage Heleen Groenenberg, Martine Uyterlinde, ECN Policy Studies, The Netherlands Abstract CO2 capture and storage (CCS) is increasingly mentioned a large point source, compression, transport and subsequent storage in a geological reservoir, the ocean

  4. Distribution of anthropogenic CO2 in the Pacific Ocean

    E-Print Network [OSTI]

    Distribution of anthropogenic CO2 in the Pacific Ocean C. L. Sabine,1 R. A. Feely,2 R. M. Key,3 J] This work presents an estimate of anthropogenic CO2 in the Pacific Ocean based on measurements from the WOCE tracers; 9355 Information Related to Geographic Region: Pacific Ocean; KEYWORDS: Pacific Ocean

  5. arbon dioxide (CO2 atmosphere has increased by

    E-Print Network [OSTI]

    responsive to rising atmospheric CO2 concentration than C3 species. In the southwestern United States substrate for photosynthetic energy acquisition by life, the process of using light energy to combine CO2 surface and scale up to affect the landscape water balance. Thus, through its impacts on plant water use

  6. The Energy and CO2 Emissions Impact of

    E-Print Network [OSTI]

    for developing renewable electricity--wind, solar, and biomass-- would require expansion on an unprecedentedThe Energy and CO2 Emissions Impact of Renewable Energy Development in China Xiliang Zhang, Tianyu://globalchange.mit.edu/ Printed on recycled paper #12;1 The Energy and CO2 Emissions Impact of Renewable Energy Development

  7. Oxidation in Environments with Elevated CO2 Levels

    SciTech Connect (OSTI)

    Gordon H. Holcomb

    2009-05-01T23:59:59.000Z

    Efforts to reduce greenhouse gas emissions from fossil energy power productions focus primarily on either pre- or post-combustion removal of CO2. The research presented here examines corrosion and oxidation issues associated with two types of post-combustion CO2 removal processesoxyfuel combustion in refit boilers and oxyfuel turbines.

  8. Falsification Of The Atmospheric CO2 Greenhouse Effects

    E-Print Network [OSTI]

    Learned, John

    Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3 Contents Abstract 2 1 Introduction 6 1.1 Problem background

  9. Chemical Impact of Elevated CO2on Geothermal Energy Production

    Broader source: Energy.gov [DOE]

    This is a two phase project to assess the geochemical impact of CO2on geothermal energy production by: analyzing the geochemistry of existing geothermal fields with elevated natural CO2; measuring realistic rock-water rates for geothermal systems using laboratory and field-based experiments to simulate production scale impacts.

  10. Variations in 13 C discrimination during CO2 exchange1

    E-Print Network [OSTI]

    exchange. Observed 13 were described well by the classical model of5 Farquhar, O'Leary & Berry (1982 enzymes, as well as to differential diffusivities of 13 CO2 and 12 CO2 in air9 (O'Leary, 1984; Farquhar, O'Leary

  11. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. Modeling.................................................................................................................................. 11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  12. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. In Campaign.................................................................................................................................... 9 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  13. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration

    SciTech Connect (OSTI)

    Zuo, Lin; Benson, Sally M.

    2013-01-01T23:59:59.000Z

    A novel EOR method using carbonated water injection followed by depressurization is introduced. Results from micromodel experiments are presented to demonstrate the fundamental principles of this oil recovery method. A depressurization process (1 MPa/hr) was applied to a micromodel following carbonated water injection (Ca ? 10-5). The exsolved CO2 in water-filled pores blocked water flow in swiped portions and displaced water into oil-filled pores. Trapped oil after the carbonated water injection was mobilized by sequentially invading water. This method's self-distributed mobility control and local clogging was tested in a sandstone sample under reservoir conditions. A 10% incremental oil recovery was achieved by lowering the pressure 2 MPa below the CO2 liberation pressure. Additionally, exsolved CO2 resides in the pores of a reservoir as an immobile phase with a high residual saturation after oil production, exhibiting a potential synergy opportunity between CO2 EOR and CO2 sequestration

  14. Diffusion of CO2 During Hydrate Formation and Dissolution

    SciTech Connect (OSTI)

    Franklin M. Orr, Jr.

    2002-08-20T23:59:59.000Z

    Experiments were performed to measure the rate of diffusion of CO2 through hydrate films. Hydrate films were created in a capillary tube, and the growth of the hydrate film was measured. Difficulties were encountered in creating hydrate repeatedly, and some non-uniform growth of the films was observed. Sufficient observations were obtained to demonstrate that hydrate growth occurs preferentially on the hydrate/water side of the interface, rather than at the hydrate/CO2 interface. Diffusion coefficients were estimated from observations of the rate of growth of the hydrate film along with estimates of the solubility of CO2 in water and of the concentration gradient across the hydrate layer. The experimental observations indicate that hydrate formation occurs much more rapidly at the hydrate water interface than at the hydrate/CO2 interface. Any growth of hydrate at the CO2/hydrate interface was too slow to be observed at the time scale of the experiments. That observation is consistent with the idea that CO2 can move more easily through the hydrate, presumably by hopping between hydrate cages, than water can move through the hydrate, presumably by lattice hopping. Estimated diffusion coefficients were in the range 1-3E-06 cm2/sec. Those values are about an order of magnitude lower than the diffusion coefficient for CO2 in liquid water, but four orders of magnitude larger than the value for diffusion of CO2 in a solid. The rate of diffusion through the hydrate controls both the creation of new hydrate at the hydrate/water interface and the rate at which CO2 dissolves in the liquid water and diffuses away from the hydrate layer. Formation of a hydrate layer reduces the rate at which CO2 dissolves in liquid water.

  15. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01T23:59:59.000Z

    Could Sequestration of CO2 be Combined with the DevelopmentTOUGH2 Code for Studies of CO2 Storage in Saline Aquifers,and J. Ennis- King. CO2-H2O Mixtures in the Geological

  16. Odors that Modify CO2 Receptor Activity in Insects and Their Effect on Innate CO2-Mediated Behavior and Neuronal Plasticity

    E-Print Network [OSTI]

    Turner, Stephanie

    2010-01-01T23:59:59.000Z

    Intermediates in Insect CO2 Sensory Systems. Science Certel,2007). The molecular basis of CO2 reception in Drosophila.J. (2004). Floral CO2 Reveals Flower Profitability to Moths.

  17. Annual energy review 1996

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    This report presents historical energy statistics on all major energy activities. The statistics cover consumption, production, trade, stock, and prices, for all major energy commodities including fossil fuels, electricity, and renewable energy sources.

  18. Navigating Fragmented Ocean Law in the California Current: Tools to Identify and Measure Gaps and Overlaps for Ecosystem-Based Management

    E-Print Network [OSTI]

    Ekstrom, Julia A.

    2008-01-01T23:59:59.000Z

    Ocean chemistry of the fossil fuel CO 2 signal: the halineand indirect use of fossil fuels and electricity in USAcommercial fishi* A-B Fossil fuel-carbon dioxide Fossil

  19. Rethinking wedges

    E-Print Network [OSTI]

    Davis, Steven J; Cao, Long; Caldeira, Ken; Hoffert, Martin I

    2013-01-01T23:59:59.000Z

    M I 2010 Farewell to fossil fuels? Science 329 1292 [10]Regional, and National Fossil-Fuel CO 2 Emissions (Oakdemands and dependence on fossil-fuel energy effectively

  20. The Australian terrestrial carbon budget

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    emissions from fossil-fuel com- bustion, Biogeosciences, 9,re- gional and national fossil-fuel CO 2 emissions, Carbontimes more carbon in fossil fuels than it emitted by burning