National Library of Energy BETA

Sample records for anhydrous hydrogen fluoride

  1. Recovery of anhydrous hydrogen iodide

    DOE Patents [OSTI]

    O'Keefe, Dennis R. (San Diego, CA); McCorkle, Jr., Kenneth H. (Del Mar, CA); de Graaf, Johannes D. (The Hague, NL)

    1982-01-01

    Relatively dry hydrogen iodide can be recovered from a mixture of HI, I.sub.2 and H.sub.2 O. After the composition of the mixture is adjusted so that the amounts of H.sub.2 O and I.sub.2 do not exceed certain maximum limits, subjection of the mixture to superatmospheric pressure in an amount equal to about the vapor pressure of HI at the temperature in question causes distinct liquid phases to appear. One of the liquid phases contains HI and not more than about 1 weight percent water. Often the adjustment in the composition will include the step of vaporization, and the distinct layers appear following the increase in pressure of the vapor mixture. Adjustment in the composition may also include the addition of an extraction agent, such as H.sub.3 PO.sub.4, and even though the adjusted composition mixture contains a significant amount of such an agent, the creation of the distinct liquid phases is not adversely affected.

  2. Process for converting magnesium fluoride to calcium fluoride

    DOE Patents [OSTI]

    Kreuzmann, A.B.; Palmer, D.A.

    1984-12-21

    This invention is a process for the conversion of magnesium fluoride to calcium fluoride whereby magnesium fluoride is decomposed by heating in the presence of calcium carbonate, calcium oxide or calcium hydroxide. Magnesium fluoride is a by-product of the reduction of uranium tetrafluoride to form uranium metal and has no known commercial use, thus its production creates a significant storage problem. The advantage of this invention is that the quality of calcium fluoride produced is sufficient to be used in the industrial manufacture of anhydrous hydrogen fluoride, steel mill flux or ceramic applications.

  3. Methods of controlling hydrogen fluoride pressure during chemical fabrication processes

    DOE Patents [OSTI]

    Solovyov, Vyacheslav (Rocky Point, NY); Wiesmann, Harold (Stony Brook, NY)

    2009-11-24

    The present invention is a method for producing a crystalline end-product. The method comprising exposing a fluoride-containing precursor to a hydrogen fluoride absorber under conditions suitable for the conversion of the precursor into the crystalline end-product.

  4. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

    DOE Patents [OSTI]

    Bartlett, Neil (Orinda, CA); Whalen, J. Marc (Corning, NY); Chacon, Lisa (Corning, NY)

    2000-12-12

    A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.

  5. Accident prevention and Clean Air Act Amendments of 1990 with particular reference to anhydrous hydrogen fluoride

    SciTech Connect (OSTI)

    Kaiser, G.D. (Science Applications International Corp., McLean, VA (United States))

    1993-07-01

    The sections of the Clean Air Act Amendments (CAAA) of 1990 that refer to accident prevention are to be found in Title III. Two significant requirements of the CAAA in this respect relate to the responsibilities of the Occupational Safety and Health Administration (OSHA), which has promulgated a new Process Safety Management (PSM) standard and the Environmental Protection Agency (EPA), which at the time of writing, is developing Risk Management Program (RMP) regulations. The focus of this paper is on how the requirements of the CAAA may affect the reasons for performing a Quantitative Risk Assessment (QRA) or may affect the results of QRA. In order to limit the discussion, this paper focuses on HF. First, the CAAA requires that the EPA assess the hazards associated with HF; the EPA's current draft report is discussed. Second, a generic assessment of the risks associated with the use of HF is given, with emphasis on alkylation units in refineries. The principal contributors to risk are listed. Finally, an assessment of OSHA's PSM standard 29 CFR 1910.119, the related requirements of state laws such as California's Risk Management and Prevention Program and the potential requirement of EPA's Risk Management Program are given, including an assessment of how these requirements may influence quantitative estimates of risk. 13 refs., 1 fig.

  6. Hydrogen desorption from hydrogen fluoride and remote hydrogen plasma cleaned silicon carbide (0001) surfaces

    SciTech Connect (OSTI)

    King, Sean W. Tanaka, Satoru; Davis, Robert F.; Nemanich, Robert J.

    2015-09-15

    Due to the extreme chemical inertness of silicon carbide (SiC), in-situ thermal desorption is commonly utilized as a means to remove surface contamination prior to initiating critical semiconductor processing steps such as epitaxy, gate dielectric formation, and contact metallization. In-situ thermal desorption and silicon sublimation has also recently become a popular method for epitaxial growth of mono and few layer graphene. Accordingly, numerous thermal desorption experiments of various processed silicon carbide surfaces have been performed, but have ignored the presence of hydrogen, which is ubiquitous throughout semiconductor processing. In this regard, the authors have performed a combined temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy (XPS) investigation of the desorption of molecular hydrogen (H{sub 2}) and various other oxygen, carbon, and fluorine related species from ex-situ aqueous hydrogen fluoride (HF) and in-situ remote hydrogen plasma cleaned 6H-SiC (0001) surfaces. Using XPS, the authors observed that temperatures on the order of 7001000?C are needed to fully desorb C-H, C-O and Si-O species from these surfaces. However, using TPD, the authors observed H{sub 2} desorption at both lower temperatures (200550?C) as well as higher temperatures (>700?C). The low temperature H{sub 2} desorption was deconvoluted into multiple desorption states that, based on similarities to H{sub 2} desorption from Si (111), were attributed to silicon mono, di, and trihydride surface species as well as hydrogen trapped by subsurface defects, steps, or dopants. The higher temperature H{sub 2} desorption was similarly attributed to H{sub 2} evolved from surface O-H groups at ?750?C as well as the liberation of H{sub 2} during Si-O desorption at temperatures >800?C. These results indicate that while ex-situ aqueous HF processed 6H-SiC (0001) surfaces annealed at <700?C remain terminated by some surface CO and SiO bonding, they may still exhibit significant chemical reactivity due to the creation of surface dangling bonds resulting from H{sub 2} desorption from previously undetected silicon hydride and surface hydroxide species.

  7. Temperature requirements and corrosion rates in combustion driven hydrogen fluoride supersonic diffusion lasers

    SciTech Connect (OSTI)

    Nordine, P.C.

    1983-08-01

    A maximum F-atom yield from F2 occurs in a combustion driven hydrogen fluoride supersonic diffusion laser (HFSDL) because the amount of fluorine reacted with hydrogen (or deuterium) continues to increase with temperature after most of the unreacted fluorine has been thermally dissociated. A small decease from the maximum combustor F-atom yield allows a significant decease in the required temperature and in the corrosion rates that uncooled laser nozzles would display. The temperatures that give F-atom yields equal to 95 percent of the maximum values were calculated for typical HFSDL combustor pressures and F-atom mole fractions and the corrosion rates of uncooled nozzles were evaluated at these temperatures. The corrosion rates of materials resistant to fluorine attack at the highest temperatures would allow HFSDL applications or test experiments up to several hours duration.

  8. Quantum mechanical force field for hydrogen fluoride with explicit electronic polarization

    SciTech Connect (OSTI)

    Mazack, Michael J. M.; Gao, Jiali

    2014-05-28

    The explicit polarization (X-Pol) theory is a fragment-based quantum chemical method that explicitly models the internal electronic polarization and intermolecular interactions of a chemical system. X-Pol theory provides a framework to construct a quantum mechanical force field, which we have extended to liquid hydrogen fluoride (HF) in this work. The parameterization, called XPHF, is built upon the same formalism introduced for the XP3P model of liquid water, which is based on the polarized molecular orbital (PMO) semiempirical quantum chemistry method and the dipole-preserving polarization consistent point charge model. We introduce a fluorine parameter set for PMO, and find good agreement for various gas-phase results of small HF clusters compared to experiments and ab initio calculations at the M06-2X/MG3S level of theory. In addition, the XPHF model shows reasonable agreement with experiments for a variety of structural and thermodynamic properties in the liquid state, including radial distribution functions, interaction energies, diffusion coefficients, and densities at various state points.

  9. Rotationally resolved spectroscopy of a librational fundamental band of hydrogen fluoride tetramer

    SciTech Connect (OSTI)

    Blake, Thomas A.; Sharpe, Steven W.; Xantheas, Sotiris S.

    2000-07-08

    The rotationally resolved spectrum of a fundamental band of hydrogen fluoride tetramer has been recorded using a pulsed slit-jet, diode laser spectrometer. The band has a parallel rotational structure and is assigned as the H-F out-of-plane libration fundamental with A{sub u} symmetry. Ninety-five ground state combination differences were fit to a symmetric top Hamiltonian to give the following ground state rotational constants: B{sup ''}=0.132 081(7) cm{sup -1}, D{sub J}{sup ''}=7.1(7)x10{sup -7} cm{sup -1}, D{sub JK}{sup ''}=-9(2)x10{sup -7} cm{sup -1}, H{sub JJJ}{sup ''}=6(2)x10{sup -10} cm{sup -1}, H{sub JJK}{sup ''}=9(7)x10{sup -10} cm{sup -1}, H{sub JKK}{sup ''}=-1.3(8)x10{sup -10} cm{sup -1}. A total of 190 transitions were fit to determine the upper state spectroscopic constants: v{sub 4}=714.7849(1) cm{sup -1}, B{sup '}=0.129 634(5) cm{sup -1}, {delta}(C-B)=0.001 344 cm{sup -1}, D{sub J}{sup '}=6.4(5)x10{sup -7} cm{sup -1}, D{sub JK}{sup '}=-4.5(6)x10{sup -7} cm{sup -1}, {delta}D{sub K}=2.92(8)x10{sup -6} cm{sup -1}, H{sub JJJ}{sup '}=3(1)x10{sup -10} cm{sup -1}, H{sub JKK}{sup '}=-1.55(6)x10{sup -8} cm{sup -1}; {delta}H{sub KKK}=-4.65(6)x10{sup -8} cm{sup -1}. Furthermore, a perpendicular band centered at 752.7 cm{sup -1} was observed. The band has a rotational line spacing that gives an approximate B{sup ''} value of 0.132 cm{sup -1}; it has been assigned as the E{sub u} symmetry, H-F in-plane libration fundamental of the HF tetramer. Finally, a parallel band was observed at 741.0 cm{sup -1} with B{sup ''}=0.076 cm{sup -1} and has been assigned as the A{sup ''} symmetry, H-F out-of-plane libration fundamental of the HF pentamer. Structural parameters and harmonic vibrational frequencies are estimated from first-principles, correlated MP2 and CCSD(T) calculations. These are the largest calculations performed to date for this system with respect to both orbital basis set and level of electron correlation. The CCSD(T) harmonic frequencies are, in particular, the first reported for the tetramer at this level of theory. Based on our results, we suggest ''best estimates'' of R{sub FF}=2.51 Aa, r{sub HF}=0.947 Aa, and {theta}{sub HFF}=9.7 degree sign for the structural parameters and a range for D{sub e} of 27.4 to 28.1 kcal/mol (D{sub 0}=19.7 to 20.4 kcal/mol) for the parameters and for the energy of the tetramer dissociating into four monomers. (c) 2000 American Institute of Physics.

  10. Chemistry control and corrosion mitigation of heat transfer salts for the fluoride salt reactor (FHR)

    SciTech Connect (OSTI)

    Kelleher, B. C.; Sellers, S. R.; Anderson, M. H.; Sridharan, K.; Scheele, R. D.

    2012-07-01

    The Molten Salt Reactor Experiment (MSRE) was a prototype nuclear reactor which operated from 1965 to 1969 at Oak Ridge National Laboratory. The MSRE used liquid fluoride salts as a heat transfer fluid and solvent for fluoride based {sup 235}U and {sup 233}U fuel. Extensive research was performed in order to optimize the removal of oxide and metal impurities from the reactor's heat transfer salt, 2LiF-BeF{sub 2} (FLiBe). This was done by sparging a mixture of anhydrous hydrofluoric acid and hydrogen gas through the FLiBe at elevated temperatures. The hydrofluoric acid reacted with oxides and hydroxides, fluorinating them while simultaneously releasing water vapor. Metal impurities such as iron and chromium were reduced by hydrogen gas and filtered out of the salt. By removing these impurities, the corrosion of reactor components was minimized. The Univ. of Wisconsin - Madison is currently researching a new chemical purification process for fluoride salts that make use of a less dangerous cleaning gas, nitrogen trifluoride. Nitrogen trifluoride has been predicted as a superior fluorinating agent for fluoride salts. These purified salts will subsequently be used for static and loop corrosion tests on a variety of reactor materials to ensure materials compatibility for the new FHR designs. Demonstration of chemistry control methodologies along with potential reduction in corrosion is essential for the use of a fluoride salts in a next generator nuclear reactor system. (authors)

  11. Does fluoride disrupt hydrogen bond network in cationic lipid bilayer? Time-dependent fluorescence shift of Laurdan and molecular dynamics simulations

    SciTech Connect (OSTI)

    Pokorna, Sarka; Jurkiewicz, Piotr; Hof, Martin; Vazdar, Mario; Cwiklik, Lukasz; Jungwirth, Pavel

    2014-12-14

    Time-dependent fluorescence shift (TDFS) of Laurdan embedded in phospholipid bilayers reports on hydration and mobility of the phospholipid acylgroups. Exchange of H{sub 2}O with D{sub 2}O prolongs the lifetime of lipid-water and lipid-water-lipid interactions, which is reflected in a significantly slower TDFS kinetics. Combining TDFS measurements in H{sub 2}O and D{sub 2}O hydrated bilayers with atomistic molecular dynamics (MD) simulations provides a unique tool for characterization of the hydrogen bonding at the acylgroup level of lipid bilayers. In this work, we use this approach to study the influence of fluoride anions on the properties of cationic bilayers composed of trimethylammonium-propane (DOTAP). The results obtained for DOTAP are confronted with those for neutral phosphatidylcholine (DOPC) bilayers. Both in DOTAP and DOPC H{sub 2}O/D{sub 2}O exchange prolongs hydrogen-bonding lifetime and does not disturb bilayer structure. These results are confirmed by MD simulations. TDFS experiments show, however, that for DOTAP this effect is cancelled in the presence of fluoride ions. We interpret these results as evidence that strongly hydrated fluoride is able to steal water molecules that bridge lipid carbonyls. Consequently, when attracted to DOTAP bilayer, fluoride disrupts the local hydrogen-bonding network, and the differences in TDFS kinetics between H{sub 2}O and D{sub 2}O hydrated bilayers are no longer observed. A distinct behavior of fluoride is also evidenced by MD simulations, which show different lipid-ion binding for Cl{sup ?} and F{sup ?}.

  12. Divalent fluoride doped cerium fluoride scintillator

    DOE Patents [OSTI]

    Anderson, David F. (630 Sylvan Pl., Batavia, IL 60510); Sparrow, Robert W. (28 Woodlawn Dr., Sturbridge, MA 01566)

    1991-01-01

    The use of divalent fluoride dopants in scintillator materials comprising cerium fluoride is disclosed. The preferred divalent fluoride dopants are calcium fluoride, strontium fluoride, and barium fluoride. The preferred amount of divalent fluoride dopant is less than about two percent by weight of the total scintillator. Cerium fluoride scintillator crystals grown with the addition of a divalent fluoride have exhibited better transmissions and higher light outputs than crystals grown without the addition of such dopants. These scintillators are useful in radiation detection and monitoring applications, and are particularly well suited for high-rate applications such as positron emission tomography (PET).

  13. Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Synthesis Reactor for Direct Production of Supercritical Steam | Department of Energy Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam UCLA Logo The University of California, Los Angeles (UCLA), through the Concentrating Solar Power: Efficiently Leveraging

  14. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  15. A Review Of Water Contents Of Nominally Anhydrous Natural Minerals...

    Open Energy Info (EERE)

    Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  16. Method and apparatus for synthesizing anhydrous HNO.sub.3

    DOE Patents [OSTI]

    Coon, Clifford L. (Fremont, CA); Harrar, Jackson E. (Castro Valley, CA); Pearson, Richard K. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

    1984-01-01

    A method and apparatus for electrochemically synthesizing anhydrous HNO.sub.3 from an aqueous solution of HNO.sub.3 includes oxidizing a solution of N.sub.2 O.sub.4 /aqueous HNO.sub.3 at an anode, while maintaining a controlled potential between the N.sub.2 O.sub.4 /aqueous HNO.sub.3 solution and the anode. A potential of about 1.80V vs. SCE is preferred. Anhydrous or aqueous HNO.sub.3 may be disposed at the cathode within the electrochemical cell. Aqueous HNO.sub.3 having a water content of up to about 12% by weight is utilized to synthesize anhydrous HNO.sub.3.

  17. hydrogen

    National Nuclear Security Administration (NNSA)

    3%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  18. hydrogen

    National Nuclear Security Administration (NNSA)

    3%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  19. Compact anhydrous HCl to aqueous HCl conversion system

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (S. Hamilton, MA)

    1993-01-01

    The present invention is directed to an inexpensive and compact apparatus adapted for use with a .sup.196 Hg isotope separation process and the conversion of anhydrous HCl to aqueous HCl without the use of air flow to carry the HCl vapor into the converter system.

  20. Compact anhydrous HCl to aqueous HCl conversion system

    DOE Patents [OSTI]

    Grossman, M.W.; Speer, R.

    1993-06-01

    The present invention is directed to an inexpensive and compact apparatus adapted for use with a [sup 196]Hg isotope separation process and the conversion of anhydrous HCl to aqueous HCl without the use of air flow to carry the HCl vapor into the converter system.

  1. Method of synthesis of anhydrous thorium(IV) complexes

    DOE Patents [OSTI]

    Kiplinger, Jaqueline L; Cantat, Thibault

    2013-04-30

    Method of producing anhydrous thorium(IV) tetrahalide complexes, utilizing Th(NO.sub.3).sub.4(H.sub.2O).sub.x, where x is at least 4, as a reagent; method of producing thorium-containing complexes utilizing ThCl.sub.4(DME).sub.2 as a precursor; method of producing purified ThCl.sub.4(ligand).sub.x compounds, where x is from 2 to 9; and novel compounds having the structures: ##STR00001##

  2. VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM

    Office of Scientific and Technical Information (OSTI)

    FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS (Technical Report) | SciTech Connect Technical Report: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS Citation Details In-Document Search Title: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS Authors: Sense, Karl A. ; Stone, Richard W. ; Filbert, Jr., Robert B. Publication Date: 1957-07-27 OSTI Identifier: 12484781 Report Number(s):

  3. VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM

    Office of Scientific and Technical Information (OSTI)

    FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS (Technical Report) | SciTech Connect Technical Report: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS Citation Details In-Document Search Title: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and

  4. Method for decontamination of nickel-fluoride-coated nickel containing actinide-metal fluorides

    DOE Patents [OSTI]

    Windt, Norman F. (Paducah, KY); Williams, Joe L. (Paducah, KY)

    1983-01-01

    The invention is a process for decontaminating particulate nickel contaminated with actinide-metal fluorides. In one aspect, the invention comprises contacting nickel-fluoride-coated nickel with gaseous ammonia at a temperature effecting nickel-catalyzed dissociation thereof and effecting hydrogen-reduction of the nickel fluoride. The resulting nickel is heated to form a melt and a slag and to effect transfer of actinide metals from the melt into the slag. The melt and slag are then separated. In another aspect, nickel containing nickel oxide and actinide metals is contacted with ammonia at a temperature effecting nickel-catalyzed dissociation to effect conversion of the nickel oxide to the metal. The resulting nickel is then melted and separated as described. In another aspect nickel-fluoride-coated nickel containing actinide-metal fluorides is contacted with both steam and ammonia. The resulting nickel then is melted and separated as described. The invention is characterized by higher nickel recovery, efficient use of ammonia, a substantial decrease in slag formation and fuming, and a valuable increase in the service life of the furnace liners used for melting.

  5. Method for converting UF5 to UF4 in a molten fluoride salt

    DOE Patents [OSTI]

    Bennett, Melvin R.; Bamberger, Carlos E.; Kelmers, A. Donald

    1977-01-01

    The reduction of UF.sub.5 to UF.sub.4 in a molten fluoride salt by sparging with hydrogen is catalyzed by metallic platinum. The reaction is also catalyzed by platinum alloyed with gold reaction equipment.

  6. Magnesium fluoride recovery method

    DOE Patents [OSTI]

    Gay, Richard L.; McKenzie, Donald E.

    1989-01-01

    A method of obtaining magnesium fluoride substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is contacted with an acid under certain prescribed conditions to produce a liquid product and a particulate solid product. The particulate solid product is separated from the liquid and treated at least two more times with acid to produce a solid residue consisting essentially of magnesium fluoride substantially free of uranium and having a residual radioactivity level of less than about 1000 pCi/gm. In accordance with a particularly preferred embodiment of the invention a catalyst and an oxidizing agent are used during the acid treatment and preferably the acid is sulfuric acid having a strength of about 1.0 Normal.

  7. Method and apparatus for synthesizing anhydrous HNO/sub 3/. [Patent application

    DOE Patents [OSTI]

    Coon, C.L.; Harrar, J.E.; Pearson, R.K.; McGuire, R.R.

    1982-07-20

    A method and apparatus for electrochemically synthesizing anhydrous HNO/sub 3/ from an aqueous solution of HNO/sub 3/- includes oxidizing a solution of N/sub 2/O/sub 4//aqueous HNO/sub 3/ at an anode, while maintaining a controlled potential between the N/sub 2/O/sub 4//aqueous HNO/sub 3/ solution and the anode. A potential of about 1.80V vs. SCE is preferred. Anhydrous or aqueous HNO/sub 3/ may be disposed at the cathode within the electrochemical cell. Aqueous HNO/sub 3/ having a water content of up to about 12% by weight is utilized to synthesize anhydrous HNO/sub 3/.

  8. Methods of using ionic liquids having a fluoride anion as solvents

    DOE Patents [OSTI]

    Pagoria, Philip (Livermore, CA); Maiti, Amitesh (San Ramon, CA); Gash, Alexander (Brentwood, CA); Han, Thomas Yong (Pleasanton, CA); Orme, Christine (Oakland, CA); Fried, Laurence (Livermore, CA)

    2011-12-06

    A method in one embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having a fluoride anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of about 90.degree. C. or less during the contacting. A method in another embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having an acetate or formate anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of less than about 90.degree. C. during the contacting.

  9. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Download the ...

  10. Method of making porous ceramic fluoride

    DOE Patents [OSTI]

    Reiner, Robert H. (Knoxville, TN); Holcombe, Cressie E. (Farragut, TN)

    1990-01-01

    A process for making a porous ceramic composite where fumed silica particles are coated with a nitrate, preferably aluminum nitrate. Next the nitrate is converted to an oxide and formed into a desired configuration. This configuration is heated to convert the oxide to an oxide silicate which is then react with HF, resulting in the fluoride ceramic, preferably aluminum fluoride.

  11. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

    1983-01-01

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  12. High Temperature Fluoride Salt Test Loop

    SciTech Connect (OSTI)

    Aaron, Adam M.; Cunningham, Richard Burns; Fugate, David L.; Holcomb, David Eugene; Kisner, Roger A.; Peretz, Fred J.; Robb, Kevin R.; Wilson, Dane F.; Yoder, Jr, Graydon L.

    2015-12-01

    Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels with 3 cm diameter graphite-based fuel pebbles slowly circulating up through the core. Molten salt coolant (FLiBe) at 700°C flows concurrently (at significantly higher velocity) with the pebbles and is used to remove heat generated in the reactor core (approximately 1280 W/pebble), and supply it to a power conversion system. Refueling equipment continuously sorts spent fuel pebbles and replaces spent or damaged pebbles with fresh fuel. By combining greater or fewer numbers of pebble channel assemblies, multiple reactor designs with varying power levels can be offered. The PB-AHTR design is discussed in detail in Reference [1] and is shown schematically in Fig. 1. Fig. 1. PB-AHTR concept (drawing taken from Peterson et al., Design and Development of the Modular PB-AHTR Proceedings of ICApp 08). Pebble behavior within the core is a key issue in proving the viability of this concept. This includes understanding the behavior of the pebbles thermally, hydraulically, and mechanically (quantifying pebble wear characteristics, flow channel wear, etc). The experiment being developed is an initial step in characterizing the pebble behavior under realistic PB-AHTR operating conditions. It focuses on thermal and hydraulic behavior of a static pebble bed using a convective salt loop to provide prototypic fluid conditions to the bed, and a unique inductive heating technique to provide prototypic heating in the pebbles. The facility design is sufficiently versatile to allow a variety of other experimentation to be performed in the future. The facility can accommodate testing of scaled reactor components or sub-components such as flow diodes, salt-to-salt heat exchangers, and improved pump designs as well as testing of refueling equipment, high temperature instrumentation, and other reactor core designs.

  13. Large-scale production of anhydrous nitric acid and nitric acid solutions of dinitrogen pentoxide

    DOE Patents [OSTI]

    Harrar, Jackson E. (Castro Valley, CA); Quong, Roland (Oakland, CA); Rigdon, Lester P. (Livermore, CA); McGuire, Raymond R. (Brentwood, CA)

    2001-01-01

    A method and apparatus are disclosed for a large scale, electrochemical production of anhydrous nitric acid and N.sub.2 O.sub.5. The method includes oxidizing a solution of N.sub.2 O.sub.4 /aqueous-HNO.sub.3 at the anode, while reducing aqueous HNO.sub.3 at the cathode, in a flow electrolyzer constructed of special materials. N.sub.2 O.sub.4 is produced at the cathode and may be separated and recycled as a feedstock for use in the anolyte. The process is controlled by regulating the electrolysis current until the desired products are obtained. The chemical compositions of the anolyte and catholyte are monitored by measurement of the solution density and the concentrations of N.sub.2 O.sub.4.

  14. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Download the presentation slides from Arkema at the July 17, 2012, Fuel Cell Technologies Program webinar, "Fuel Cells for Portable Power." PDF icon Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Webinar Slides More Documents & Publications

  15. Examination of Liquid Fluoride Salt Heat Transfer

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L

    2014-01-01

    The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

  16. Hydrogen sensor

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Cao, Wenqing (Katy, TX)

    2010-11-23

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  17. Hydrogenation apparatus

    DOE Patents [OSTI]

    Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

    1981-01-01

    Hydrogenation reaction apparatus comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1100.degree. to 1900.degree. C., while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products.

  18. Florida Hydrogen Initiative

    SciTech Connect (OSTI)

    Block, David L

    2013-06-30

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cell technology academic program at Florida Institute of Technology in Melbourne, Florida. Design and Development of an Advanced Hydrogen Storage System using Novel Materials ? E. Stefanakos, University of South Florida The goal of this project was to design and develop novel conducting polymeric nanomaterials for on-board hydrogen storage. The project approach was to examine synthesis of polyaniline solid state hydrogen storage materials. Advanced HiFoil ? Bipolar Plates ? J. Braun, M. Fuchs, EnerFuel, Inc. The goal of this project was to provide a durable, low cost bipolar plate for high temperature proton exchange membrane fuel cells. The project results produced a durable, low cost bipolar plate with very high in-plane thermal conductivity.

  19. Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

    2011-09-28

    This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

  20. Effects of fluoride emissions on enzyme activity in metabolism of agricultural plants

    SciTech Connect (OSTI)

    Moeri, P.B.

    1980-01-01

    The effects of fluoride on the activity of malatedehydrogenase (MDH) in rape seed and rye grass have been investigated. Fluoride, which has been absorbed from the air, seems to act differently from fluoride added to the soil. The action of airborne fluoride compounds resorbed by the plant on the activity of MDH significantly correlated with the distance from an aluminum plant, crop yield, and fluoride content. 5 references, 5 figures, 2 tables.

  1. Hydrogen Safety

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

  2. Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

  3. Hydrogen Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Hydrogen is an energy carrier, not an energy source-hydrogen stores and delivers energy in a usable form, but it must be produced from hydrogen- containing compounds. Hydrogen can be produced using diverse, domestic resources including fossil fuels, such as natural gas and coal (preferentially with carbon capture, utilization, and storage); biomass grown from renewable, non-food crops; or using nuclear energy and renewable energy sources, such as wind, solar, geothermal, and

  4. Formation of lithium fluoride/metal nanocomposites for energy storage through solid state reduction of metal fluorides

    SciTech Connect (OSTI)

    Amatucci, GG; Pereira, N; Badway, F; Sina, M; Cosandey, F; Ruotolo, M; Cao, C

    2011-12-01

    In order to utilize high energy metal fluoride electrode materials as direct replacement electrode materials for lithium ion batteries in the future, a methodology to prelithiate the cathode or anode must be developed. Herein, we introduce the use of a solid state Li(3)N route to achieve the lithiation and mechanoreduction of metal fluoride based nanocomposites. The resulting prelithiation was found to be effective with the formation of xLiF:Me structures of very fine nanodimensions analogous to what is found by electrochemical lithiation. Physical and electrochemical properties of these nanocomposites for the bismuth and iron lithium fluoride systems are reported. (C) 2011 Elsevier B.V. All rights reserved.

  5. Hydrogen Production

    SciTech Connect (OSTI)

    2014-09-01

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produce hydrogen. It includes an overview of research goals as well as “quick facts” about hydrogen energy resources and production technologies.

  6. Fluorination of amorphous thin-film materials with xenon fluoride

    DOE Patents [OSTI]

    Weil, R.B.

    1987-05-01

    A method is disclosed for producing fluorine-containing amorphous semiconductor material, preferably comprising amorphous silicon. The method includes depositing amorphous thin-film material onto a substrate while introducing xenon fluoride during the film deposition process.

  7. Fluorination of amorphous thin-film materials with xenon fluoride

    DOE Patents [OSTI]

    Weil, Raoul B. (Haifa, IL)

    1988-01-01

    A method is disclosed for producing fluorine-containing amorphous semiconductor material, preferably comprising amorphous silicon. The method includes depositing amorphous thin-film material onto a substrate while introducing xenon fluoride during the film deposition process.

  8. Hydrogenation apparatus

    DOE Patents [OSTI]

    Friedman, J.; Oberg, C. L.; Russell, L. H.

    1981-06-23

    Hydrogenation reaction apparatus is described comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1,100 to 1,900 C, while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products. 2 figs.

  9. An Overview of Liquid Fluoride Salt Heat Transport Technology

    SciTech Connect (OSTI)

    Cetiner, Mustafa Sacit; Holcomb, David Eugene

    2010-01-01

    Liquid fluoride salts are a leading candidate heat transport medium for high-temperature applications. This report provides an overview of the current status of liquid salt heat transport technology. The report includes a high-level, parametric evaluation of liquid fluoride salt heat transport loop performance to allow intercomparisons between heat-transport fluid options as well as providing an overview of the properties and requirements for a representative loop. Much of the information presented here derives from the earlier molten salt reactor program and a significant advantage of fluoride salts, as high temperature heat transport media is their consequent relative technological maturity. The report also includes a compilation of relevant thermophysical properties of useful heat transport fluoride salts. Fluoride salts are both thermally stable and with proper chemistry control can be relatively chemically inert. Fluoride salts can, however, be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report also provides an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize salt corrosion as well as providing a general discussion of heat transfer loop operational issues such as start-up procedures and freeze-up vulnerability.

  10. Hydrogen Scenarios

    Broader source: Energy.gov [DOE]

    Presentation by Frances Wood of OnLocation Inc. at the Joint Meeting on Hydrogen Delivery Modeling and Analysis, May 8-9, 2007

  11. Hydrogen Liquefaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Internationally 4-7 European Installations 4-6 Japanese Installations India Program ESA French Guiana (South America) 4 Satisfies ASME J-2719 (hydrogen ...

  12. Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search TODO: Add description Related Links List of Companies in Hydrogen Sector List of Hydrogen Incentives Hydrogen Energy Data Book Retrieved from...

  13. Sol-gel process of fluoride and fluorobromide materials

    SciTech Connect (OSTI)

    Poncelet, O.; Guilment, J.; Paz-Pujalt, G.

    1996-12-31

    The alkoxides M(OR{sub x}){sub n} wherein M is an alkaline-earth or rare-earth and OR{sub X} is a fluoroalkoxo or bromoalkoxo group exhibit the properties to form pure fluoride materials by hydrolysis at room temperature. Using this property, the authors synthesized pure barium and europium fluoride and pure alkaline-earth bromide. The hydrolysis of a heteroleptic species, Ba(OCH{sub 2}CH{sub 2}Br)[OCH(CF{sub 3}){sub 2}] allowed pure and crystalline BaFBr materials to be obtained at room temperature.

  14. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  15. Structural studies of magnesium nitride fluorides by powder neutron diffraction

    SciTech Connect (OSTI)

    Brogan, Michael A.; Hughes, Robert W.; Smith, Ronald I.; Gregory, Duncan H.

    2012-01-15

    Samples of ternary nitride fluorides, Mg{sub 3}NF{sub 3} and Mg{sub 2}NF have been prepared by solid state reaction of Mg{sub 3}N{sub 2} and MgF{sub 2} at 1323-1423 K and investigated by powder X-ray and powder neutron diffraction techniques. Mg{sub 3}NF{sub 3} is cubic (space group: Pm3m) and has a structure related to rock-salt MgO, but with one cation site vacant. Mg{sub 2}NF is tetragonal (space group: I4{sub 1}/amd) and has an anti-LiFeO{sub 2} related structure. Both compounds are essentially ionic and form structures in which nitride and fluoride anions are crystallographically ordered. The nitride fluorides show temperature independent paramagnetic behaviour between 5 and 300 K. - Graphical abstract: Definitive structures of the ternary magnesium nitride fluorides Mg{sub 3}NF{sub 3} and the lower temperature polymorph of Mg{sub 2}NF have been determined from powder neutron diffraction data. The nitride halides are essentially ionic and exhibit weak temperature independent paramagnetic behaviour. Highlights: Black-Right-Pointing-Pointer Definitive structures of Mg{sub 3}NF{sub 3} and Mg{sub 2}NF were determined by neutron diffraction. Black-Right-Pointing-Pointer Nitride and fluoride anions are crystallographically ordered in both structures. Black-Right-Pointing-Pointer Both compounds exhibit weak, temperature independent paramagnetic behaviour. Black-Right-Pointing-Pointer The compounds are essentially ionic with ionicity increasing with F{sup -} content.

  16. Storing Hydrogen

    SciTech Connect (OSTI)

    Kim, Hyun Jeong; Karkamkar, Abhijeet J.; Autrey, Thomas; Chupas, Peter; Proffen, Thomas E.

    2010-05-31

    Researchers have been studying mesoporous materials for almost two decades with a view to using them as hosts for small molecules and scaffolds for molding organic compounds into new hybrid materials and nanoparticles. Their use as potential storage systems for large quantities of hydrogen has also been mooted. Such systems that might hold large quantities of hydrogen safely and in a very compact volume would have enormous potential for powering fuel cell vehicles, for instance. A sponge-like form of silicon dioxide, the stuff of sand particles and computer chips, can soak up and store other compounds including hydrogen. Studies carried out at the XOR/BESSRC 11-ID-B beamline at the APS have revealed that the nanoscopic properties of the hydrogenrich compound ammonia borane help it store hydrogen more efficiently than usual. The material may have potential for addressing the storage issues associated with a future hydrogen economy. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  17. Hydrogen program overview

    SciTech Connect (OSTI)

    Gronich, S.

    1997-12-31

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  18. Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working Group Workshop: Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines Code for Hydrogen Piping and Pipelines. B31 Hydrogen...

  19. Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search <-- Back to Hydrogen Gateway Technical Reference for Hydrogen Compatibility of Materials KIA FCEV SUNRISE MG 7955 6 7.jpg Guidance on materials...

  20. Hydrogen Transition Infrastructure Analysis

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2005-05-01

    Presentation for the 2005 U.S. Department of Energy Hydrogen Program review analyzes the hydrogen infrastructure needed to accommodate a transitional hydrogen fuel cell vehicle demand.

  1. Separation of High Order Harmonics with Fluoride Windows

    SciTech Connect (OSTI)

    Allison, Tom; van Tilborg, Jeroen; Wright, Travis; Hertlein, Marcus; Falcone, Roger; Belkacem, Ali

    2010-08-02

    The lower orders produced in high order harmonic generation can be effciently temporally separated into monochromatic pulses by propagation in a Fluoride window while still preserving their femtosecond pulse duration. We present calculations for MgF2, CaF2, and LiF windows for the third, fifth, and seventh harmonics of 800 nm. We demonstrate the use of this simple and inexpensive technique in a femtosecond pump/probe experiment using the fifth harmonic.

  2. Hydrogen Production: Photobiological

    Broader source: Energy.gov [DOE]

    The photobiological hydrogen production process uses microorganisms and sunlight to turn water, and sometimes organic matter, into hydrogen.

  3. Hydrogen Technology Validation

    Fuel Cell Technologies Publication and Product Library (EERE)

    This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

  4. Hydrogen scavengers

    DOE Patents [OSTI]

    Carroll, David W. (Los Alamos, NM); Salazar, Kenneth V. (Espanola, NM); Trkula, Mitchell (Los Alamos, NM); Sandoval, Cynthia W. (Los Alamos, NM)

    2002-01-01

    There has been invented a codeposition process for fabricating hydrogen scavengers. First, a .pi.-bonded allylic organometallic complex is prepared by reacting an allylic transition metal halide with an organic ligand complexed with an alkali metal; and then, in a second step, a vapor of the .pi.-bonded allylic organometallic complex is combined with the vapor of an acetylenic compound, irradiated with UV light, and codeposited on a substrate.

  5. Metal oxide and metal fluoride nanostructures and methods of making same

    DOE Patents [OSTI]

    Wong, Stanislaus S. (Stony Brook, NY); Mao, Yuanbing (Los Angeles, CA)

    2009-08-18

    The present invention includes pure single-crystalline metal oxide and metal fluoride nanostructures, and methods of making same. These nanostructures include nanorods and nanoarrays.

  6. Photochemical oxygenation of a technetium fluoride using F{sub 2} and O{sub 2}

    SciTech Connect (OSTI)

    Beitz, J.V.; Williams, C.W.

    1996-10-01

    Photochemical conversion of technetium fluorides and oxyfluorides is largely uninvestigated. Because technetium was introduced into U.S. uranium enrichment plants, decommissioning and decontamination of these plants will involve technetium fluorides and oxyfluorides. Photochemical conversion of such compounds may facilitate waste minimization and cost avoidance goals during plant clean-up. Photochemical fluorination using ultraviolet photolysis of a mixture of fluorine and oxygen gases is an effective means of converting solid, nonvolatile fluorides of fight actinides, such as U, Np, and Pu, into volatile hexafluorides thereby removing surface radioactive contamination. Our studies involved the interaction of ultraviolet light, oxygen, and fluorine with technetium fluoride.

  7. Grout formulation for disposal of low-level and hazardous waste streams containing fluoride

    DOE Patents [OSTI]

    McDaniel, E.W.; Sams, T.L.; Tallent, O.K.

    1987-06-02

    A composition and related process for disposal of hazardous waste streams containing fluoride in cement-based materials is disclosed. the presence of fluoride in cement-based materials is disclosed. The presence of fluoride in waste materials acts as a set retarder and as a result, prevents cement-based grouts from setting. This problem is overcome by the present invention wherein calcium hydroxide is incorporated into the dry-solid portion of the grout mix. The calcium hydroxide renders the fluoride insoluble, allowing the grout to set up and immobilize all hazardous constituents of concern. 4 tabs.

  8. Hydrogen Sensor Testing, Hydrogen Technologies (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    Factsheet describing the hydrogen sensor testing laboratory at the National Renewable Energy Laboratory.

  9. Chemical Hydrogen Storage Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Troy A. Semelsberger Los Alamos National Laboratory Hydrogen Storage Summit Jan 27-29, 2015 Denver, CO Chemical Hydrogen Storage Materials 2 Objectives 1. Assess chemical hydrogen storage materials that can exceed 700 bar compressed hydrogen tanks 2. Status (state-of-the-art) of chemical hydrogen storage materials 3. Identify key material characteristics 4. Identify obstacles, challenges and risks for the successful deployment of chemical hydrogen materials in a practical on-board hydrogen

  10. Hydrogen detector

    DOE Patents [OSTI]

    Kanegae, Naomichi (Mito, JP); Ikemoto, Ichiro (Mito, JP)

    1980-01-01

    A hydrogen detector of the type in which the interior of the detector is partitioned by a metal membrane into a fluid section and a vacuum section. Two units of the metal membrane are provided and vacuum pipes are provided independently in connection to the respective units of the metal membrane. One of the vacuum pipes is connected to a vacuum gauge for static equilibrium operation while the other vacuum pipe is connected to an ion pump or a set of an ion pump and a vacuum gauge both designed for dynamic equilibrium operation.

  11. NREL Wind to Hydrogen Project: Renewable Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & ...

  12. Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Project Objectives: To gain basic understanding of hydrogen permeation behavior and its impact on hydrogen ...

  13. DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fuel Cells Program Record 11007: Hydrogen Threshold Cost Calculation DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold Cost Calculation The hydrogen ...

  14. Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrogen Vehicles and Fuels in China Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen Vehicles and Fuels in China Presentation given by Jinyang Zheng of ...

  15. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay ...

  16. Ovonic Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems...

    Open Energy Info (EERE)

    Hydrogen Systems LLC formerly Texaco Ovonic Hydrogen Systems LLC Jump to: navigation, search Name: Ovonic Hydrogen Systems LLC (formerly Texaco Ovonic Hydrogen Systems LLC) Place:...

  17. Mechanochemical hydrogenation of coal

    DOE Patents [OSTI]

    Yang, Ralph T. (Tonawanda, NY); Smol, Robert (East Patchogue, NY); Farber, Gerald (Elmont, NY); Naphtali, Leonard M. (Washington, DC)

    1981-01-01

    Hydrogenation of coal is improved through the use of a mechanical force to reduce the size of the particulate coal simultaneously with the introduction of gaseous hydrogen, or other hydrogen donor composition. Such hydrogen in the presence of elemental tin during this one-step size reduction-hydrogenation further improves the yield of the liquid hydrocarbon product.

  18. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Wensheng He, David Mountz, Tao Zhang, Chris Roger July 17, 2012 2 Outline Background on Arkema's polyvinylidene fluoride (PVDF) blend membrane technology Overview of membrane properties and performance Summary 3 Membrane Technology Polymer Blend * Kynar ® PVDF * Chemical and electrochemical stability * Mechanical strength * Excellent barrier against methanol * Polyelectrolyte * H + conduction and water uptake

  19. Ferroelectric fluoride compositions and methods of making and using same

    DOE Patents [OSTI]

    Halasyamani, P Shiv; Chang, Hong-Young

    2015-04-07

    A method for synthesis of a ferroelectric material characterized by the general formula A.sub.xB.sub.yF.sub.z where A is an alkaline earth metal, B is transition metal or a main group metal, x and y each range from about 1 to about 5, and z ranges from about 1 to about 20 comprising contacting an alkaline earth metal fluoride, a difluorometal compound and a fluoroorganic acid in a medium to form a reaction mixture; and subjecting the reaction mixture to conditions suitable for hydrothermal crystal growth.

  20. CTP Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    CTP Hydrogen Jump to: navigation, search Name: CTP Hydrogen Place: Westborough, Massachusetts Zip: 1581 Sector: Hydro, Hydrogen Product: CTP Hydrogen is an early stage company...

  1. George Andrew Olah - Patents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Patents - George Andrew Olah Olah Page * Resources with Additional Information US 4,394,247 LIQUEFACTION OF COALS USING RECYCLABLE SUPERACID CATALYST - Olah, George A.; July 19, 1983 This invention discloses a process for the liquefaction of coals and other predominantly hydrocarbonaceous materials by treating the same with a superacidic catalyst system consisting of anhydrous hydrogen fluoride and boron trifluoride in the presence of super-atmospheric hydrogen. US 4,433,192 CONDENSATION OF

  2. Time-dependent water dynamics in hydrated uranyl fluoride

    SciTech Connect (OSTI)

    Miskowiec, Andrew J.; Anderson, Brian B.; Herwig, Kenneth W.; Huq, Ashfia; Mamontov, Eugene; Rondinone, Adam; Trowbridge, Lee D.

    2015-09-15

    In this study, uranyl fluoride is a three-layer, hexagonal structure with significant stacking disorder in the c-direction. It supports a range of unsolved thermodynamic hydrates with 02.5 water molecules per uranium atom, and perhaps more. However, the relationship between water, hydrate crystal structures, and thermodynamic results, collectively representing the chemical pathway through these hydrate structures, has not been sufficiently elucidated. We used high-resolution quasielastic neutron scattering to study the dynamics of water in partially hydrated uranyl fluoride powder over the course of 4 weeks under closed conditions. The spectra are composed of two quasielastic components: one is associated with translational diffusive motion of water that is approximately five to six times slower than bulk water, and the other is a slow (on the order of 2300 ps), spatially bounded water motion. The translational component represents water diffusing between the weakly bonded layers in the crystal, while the bounded component may represent water trapped in subnanometre pockets formed by the space between uranium-centred polymerisation units. Complementary neutron diffraction measurements do not show any significant structural changes, suggesting that a chemical conversion of the material does not occur in the thermodynamically isolated system on this timescale.

  3. Time-dependent water dynamics in hydrated uranyl fluoride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miskowiec, Andrew J.; Anderson, Brian B.; Herwig, Kenneth W.; Huq, Ashfia; Mamontov, Eugene; Rondinone, Adam; Trowbridge, Lee D.

    2015-09-15

    In this study, uranyl fluoride is a three-layer, hexagonal structure with significant stacking disorder in the c-direction. It supports a range of unsolved ‘thermodynamic’ hydrates with 0–2.5 water molecules per uranium atom, and perhaps more. However, the relationship between water, hydrate crystal structures, and thermodynamic results, collectively representing the chemical pathway through these hydrate structures, has not been sufficiently elucidated. We used high-resolution quasielastic neutron scattering to study the dynamics of water in partially hydrated uranyl fluoride powder over the course of 4 weeks under closed conditions. The spectra are composed of two quasielastic components: one is associated with translationalmore » diffusive motion of water that is approximately five to six times slower than bulk water, and the other is a slow (on the order of 2–300 ps), spatially bounded water motion. The translational component represents water diffusing between the weakly bonded layers in the crystal, while the bounded component may represent water trapped in subnanometre ‘pockets’ formed by the space between uranium-centred polymerisation units. Complementary neutron diffraction measurements do not show any significant structural changes, suggesting that a chemical conversion of the material does not occur in the thermodynamically isolated system on this timescale.« less

  4. Why Hydrogen? Hydrogen from Diverse Domestic Resources

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Diverse Domestic Resources Hydrogen from Diverse Domestic Resources Distributed Generation Transportation HIGH EFFICIENCY HIGH EFFICIENCY & RELIABILITY & RELIABILITY ZERONEAR...

  5. Hydrogen Sensor Workshop

    Broader source: Energy.gov [DOE]

    On June 8, 2011, the Department of Energy's National Renewable Energy Laboratory hosted a hydrogen sensors workshop to survey emerging fuel cell and hydrogen infrastructure applications that...

  6. Hydrogen Threshold Cost Calculation

    Broader source: Energy.gov [DOE]

    DOE Hydrogen Program Record number11007, Hydrogen Threshold Cost Calculation, documents the methodology and assumptions used to calculate that threshold cost.

  7. Hydrogen Storage Challenges

    Broader source: Energy.gov [DOE]

    For transportation, the overarching technical challenge for hydrogen storage is how to store the amount of hydrogen required for a conventional driving range (>300 miles) within the vehicular...

  8. Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search Hydrogen Companies Loading map... "format":"googlemaps3","type":"SATELLITE","types":"ROADMAP","SATELLITE","HYBRID","TERRAIN","limit":1000,"o...

  9. Hydrogen Delivery Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Pathway," International Journal of Hydrogen Energy, 34 ... Chemical Economics Handbook. July 2010, http:chemical.ihs.comCEHPublicReports743.5000. 25 Hydrogen ...

  10. Hydrogen Safety Panel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or otherwise restricted information. Project ID: scs07weiner PNNL-SA-65397 2 IEA HIA Task 19 Working Group Hydrogen Safety Training Props Hydrogen Safety Panel Incident...

  11. Proximal renal tubular injury in rats sub-chronically exposed to low fluoride concentrations

    SciTech Connect (OSTI)

    Crdenas-Gonzlez, Mariana C.; Del Razo, Luz M.; Barrera-Chimal, Jonatan; Jacobo-Estrada, Tania; Lpez-Bayghen, Esther; and others

    2013-11-01

    Fluoride is usually found in groundwater at a very wide range of concentration between 0.5 and 25 ppm. At present, few studies have assessed the renal effects of fluoride at environmentally relevant concentrations. Furthermore, most of these studies have used insensitive and nonspecific biomarkers of kidney injury. The aim of this study was to use early and sensitive biomarkers to evaluate kidney injury after fluoride exposure to environmentally relevant concentrations. Recently weaned male Wistar rats were exposed to low (15 ppm) and high (50 ppm) fluoride concentrations in drinking water for a period of 40 days. At the end of the exposure period, kidney injury biomarkers were measured in urine and renal mRNA expression levels were assessed by real time RT-PCR. Our results showed that the urinary kidney injury molecule (Kim-1), clusterin (Clu), osteopontin (OPN) and heat shock protein 72 excretion rate significantly increased in the group exposed to the high fluoride concentration. Accordingly, fluoride exposure increased renal Kim-1, Clu and OPN mRNA expression levels. Moreover, there was a significant dose-dependent increase in urinary ?-2-microglobulin and cystatin-C excretion rate. Additionally, a tendency towards a dose dependent increase of tubular damage in the histopathological light microscopy findings confirmed the preferential impact of fluoride on the tubular structure. All of these changes occurred at early stages in which, the renal function was not altered. In conclusion using early and sensitive biomarkers of kidney injury, we were able to found proximal tubular alterations in rats sub-chronically exposed to fluoride. - Highlights: Exposure to low concentrations of fluoride induced proximal tubular injury Increase in urinary Kim-1, Clu, OPN and Hsp72 in 50 ppm fluoride-exposed group Increase in urinary B2M and CysC in 15 and 50 ppm fluoride-exposed groups Fluoride exposure increased renal Kim, Clu and OPN mRNA expression levels. Fluoride increased kidney injury biomarkers at stages where eGFR was unaltered.

  12. Hydrogen delivery technology roadmap

    SciTech Connect (OSTI)

    None, None

    2005-11-15

    Document describing plan for research into and development of hydrogen delivery technology for transportation applications.

  13. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  14. Hydrogen Compatibility of Materials

    Broader source: Energy.gov [DOE]

    Presentation slides from the Energy Department webinar, Hydrogen Compatibility of Materials, held August 13, 2013.

  15. Composition for absorbing hydrogen

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC); Wicks, George G. (Aiken, SC); Enz, Glenn L. (N. Augusta, SC)

    1995-01-01

    A hydrogen absorbing composition. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

  16. Composition for absorbing hydrogen

    DOE Patents [OSTI]

    Heung, L.K.; Wicks, G.G.; Enz, G.L.

    1995-05-02

    A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

  17. Removal of fluoride impurities from UF/sub 6/ gas

    DOE Patents [OSTI]

    Beitz, J.V.

    1984-01-06

    A method of purifying a UF/sub 6/ gas stream containing one or more metal fluoride impurities composed of a transuranic metal, transition metal or mixtures thereof, is carried out by contacting the gas stream with a bed of UF/sub 5/ in a reaction vessel under conditions where at least one impurity reacts with the UF/sub 5/ to form a nongaseous product and a treated gas stream, and removing the treated gas stream from contact with the bed. The nongaseous products are subsequently removed in a reaction with an active fluorine affording agent to form a gaseous impurity which is removed from the reaction vessel. The bed of UF/sub 5/ is formed by the reduction of UF/sub 6/ in the presence of uv light. One embodiment of the reaction vessel includes a plurality of uv light sources as tubes on which UF/sub 5/ is formed. 2 figures.

  18. Ytterbium-doped borate fluoride laser crystals and lasers

    DOE Patents [OSTI]

    Schaffers, Kathleen I.; DeLoach, Laura D.; Payne, Stephen A.; Keszler, Douglas A.

    1997-01-01

    A new class of solid state laser crystals and lasers are formed from Yb-doped borate fluoride host crystals. The general formula for the host crystals is MM'(BO.sub.3)F, where M, M' are monovalent, divalent aria trivalent metal cations. A particular embodiment of the invention is Yb-doped BaCaBO.sub.3 F (Yb:BCBF). BCBF and some of the related derivative crystals are capable of nonlinear frequency conversion, whereby the fundamental of the laser is converted to a longer or shorter wavelength. In this way, these new crystals can simultaneously serve as self-frequency doubling crystals and laser materials within the laser resonator.

  19. Ytterbium-doped borate fluoride laser crystals and lasers

    DOE Patents [OSTI]

    Schaffers, K.I.; DeLoach, L.D.; Payne, S.A.; Keszler, D.A.

    1997-10-14

    A new class of solid state laser crystals and lasers are formed from Yb-doped borate fluoride host crystals. The general formula for the host crystals is MM{prime}(BO{sub 3})F, where M, M{prime} are monovalent, divalent aria trivalent metal cations. A particular embodiment of the invention is Yb-doped BaCaBO{sub 3}F (Yb:BCBF). BCBF and some of the related derivative crystals are capable of nonlinear frequency conversion, whereby the fundamental of the laser is converted to a longer or shorter wavelength. In this way, these new crystals can simultaneously serve as self-frequency doubling crystals and laser materials within the laser resonator. 6 figs.

  20. Advantages of liquid fluoride thorium reactor in comparison with light water reactor

    SciTech Connect (OSTI)

    Bahri, Che Nor Aniza Che Zainul Majid, Amran Ab.; Al-Areqi, Wadeeah M.

    2015-04-29

    Liquid Fluoride Thorium Reactor (LFTR) is an innovative design for the thermal breeder reactor that has important potential benefits over the traditional reactor design. LFTR is fluoride based liquid fuel, that use the thorium dissolved in salt mixture of lithium fluoride and beryllium fluoride. Therefore, LFTR technology is fundamentally different from the solid fuel technology currently in use. Although the traditional nuclear reactor technology has been proven, it has perceptual problems with safety and nuclear waste products. The aim of this paper is to discuss the potential advantages of LFTR in three aspects such as safety, fuel efficiency and nuclear waste as an alternative energy generator in the future. Comparisons between LFTR and Light Water Reactor (LWR), on general principles of fuel cycle, resource availability, radiotoxicity and nuclear weapon proliferation shall be elaborated.

  1. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  2. Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

  3. Hydrogen Power Inc formerly Hydrogen Power International and...

    Open Energy Info (EERE)

    Power Inc formerly Hydrogen Power International and Equitex Inc Jump to: navigation, search Name: Hydrogen Power, Inc. (formerly Hydrogen Power International and Equitex Inc.)...

  4. Hydrogen permeability and Integrity of hydrogen transfer pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    permeability and Integrity of hydrogen transfer pipelines Hydrogen permeability and ... Presentation by 03-Babu for the DOE Hydrogen Pipeline R&D Project Review Meeting held ...

  5. Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bus Evaluation: Report for the 2001 Hydrogen Program Review Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen Program Review This paper, presented at the 2001 DOE...

  6. Method for removal of plutonium impurity from americium oxides and fluorides

    DOE Patents [OSTI]

    FitzPatrick, J.R.; Dunn, J.G.; Avens, L.R.

    1987-02-13

    Method for removal of plutonium impurity from americium oxides and fluorides. AmF/sub 4/ is not further oxidized to AmF/sub 6/ by the application of O/sub 2/F at room temperature thereto, while plutonium compounds present in the americium sample are fluorinated to volatile PuF/sub 6/, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride thereof.

  7. Method for removal of plutonium impurity from americium oxides and fluorides

    DOE Patents [OSTI]

    FitzPatrick, John R. (Los Alamos, NM); Dunn, Jerry G. (Los Alamos, NM); Avens, Larry R. (Los Alamos, NM)

    1987-01-01

    Method for removal of plutonium impurity from americium oxides and fluorides. AmF.sub.4 is not further oxidized to AmF.sub.6 by the application of O.sub.2 F at room temperature, while plutonium compounds present in the americium sample are fluorinated to volatile PuF.sub.6, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride.

  8. Hydrogen & Our Energy Future

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Program www.hydrogen.energy.gov Hydrogen & Our Energy Future  | HydrOgEn & Our EnErgy FuturE U.S. Department of Energy Hydrogen Program www.hydrogen.energy.gov u.S. department of Energy |  www.hydrogen.energy.gov Hydrogen & Our Energy Future Contents Introduction ................................................... p.1 Hydrogen - An Overview ................................... p.3 Production ..................................................... p.5 Delivery

  9. Hydrogen Pipelines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gaseous Hydrogen » Hydrogen Pipelines Hydrogen Pipelines Photo of a hydrogen pipeline. Gaseous hydrogen can be transported through pipelines much the way natural gas is today. Approximately 1,500 miles of hydrogen pipelines are currently operating in the United States. Owned by merchant hydrogen producers, these pipelines are located where large hydrogen users, such as petroleum refineries and chemical plants, are concentrated such as the Gulf Coast region. Transporting gaseous hydrogen via

  10. Development of fluoride reprocessing technologies devoted to molten-salt reactor systems

    SciTech Connect (OSTI)

    Uhlir, Jan; Marecek, Martin; Tulackova, Radka; Chuchvalcova Bimova, Karolina

    2007-07-01

    Main fuel processing and reprocessing technologies proposed for Molten Salt Reactor fuel cycle are pyrochemical or pyrometallurgical, majority of them are fluoride technologies. It is based on the fact that Molten Salt Reactor fuel is in the chemical form of molten fluorides and the reprocessing technology is needed to be an 'on-line' process. The corresponding pyrochemical separation processes proposed for MSR fuel processing and reprocessing are mainly fluoride volatilization processes, molten salt / liquid metal extraction processes, electrochemical separation processes from the molten salt media and gas extraction from the molten salt medium. Techniques based on fluoride volatilization and on electrochemical separation from fluoride molten salt media are under development in the Czech Republic. Whereas the Fluoride Volatility Method is proposed to be the main 'Front-end' technology of the MSR used as the actinide burner (transmuter), the electro-separation methods should be dedicated to the 'on-line' reprocessing of the circulating MSR fuel and should be used as for MSR incinerating transuranium fuel as for MSR working within the {sup 232}Th - {sup 233}U fuel cycle. (authors)

  11. Quasielastic neutron scattering with in situ humidity control: Water dynamics in uranyl fluoride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miskowiec, A.; Kirkegaard, M. C.; Herwig, K. W.; Trowbridge, L.; Mamontov, E.; Anderson, B.

    2016-03-04

    The authors confirm that water vapor pressure is the driving thermodynamic force for the conversion of the anhydrous structure to [(UO2F2)(H2O)]7 ? (H2O)4, and they demonstrate the feasibility of extending this approach to aqueous forms of UO2F2+ xH2O. This method has general applicability to systems in which water content itself is a driving variable for structural or dynamical phase transitions.

  12. Hydrogen transport membranes

    DOE Patents [OSTI]

    Mundschau, Michael V.

    2005-05-31

    Composite hydrogen transport membranes, which are used for extraction of hydrogen from gas mixtures are provided. Methods are described for supporting metals and metal alloys which have high hydrogen permeability, but which are either too thin to be self supporting, too weak to resist differential pressures across the membrane, or which become embrittled by hydrogen. Support materials are chosen to be lattice matched to the metals and metal alloys. Preferred metals with high permeability for hydrogen include vanadium, niobium, tantalum, zirconium, palladium, and alloys thereof. Hydrogen-permeable membranes include those in which the pores of a porous support matrix are blocked by hydrogen-permeable metals and metal alloys, those in which the pores of a porous metal matrix are blocked with materials which make the membrane impervious to gases other than hydrogen, and cermets fabricated by sintering powders of metals with powders of lattice-matched ceramic.

  13. Hydrogen Storage- Basics

    Broader source: Energy.gov [DOE]

    Storing enough hydrogen on-board a vehicle to achieve a driving range of greater than 300 miles is a significant challenge. On a weight basis, hydrogen has nearly three times the energy content of...

  14. Hydrogen Program Overview

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to the DOE Hydrogen Program. It describes the program mission and answers the question: “Why Hydrogen?”

  15. Hydrogen Safety Knowledge Tools

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Data Partners Best Practices - LANL, SNL, NREL, NASA, Hydrogen Safety Panel, and IEA HIA Tasks 19 and 22 Incident Reporting - NASA and Hydrogen Safety Panel 3 Objectives H2...

  16. Hydrogen Technologies Safety Guide

    SciTech Connect (OSTI)

    Rivkin, C.; Burgess, R.; Buttner, W.

    2015-01-01

    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  17. National hydrogen energy roadmap

    SciTech Connect (OSTI)

    None, None

    2002-11-01

    This roadmap provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development.

  18. Hydrogen | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Hydrogen December 22, 2015 The three reports released by the Energy Department highlight continued strength, progress and innovation in the U.S. fuel cell hydrogen technologies market. Energy Department Reports: U.S. Fuel Cell Market Production and Deployment Continues Strong Growth The Energy Department released three new reports today showcasing strong growth across the U.S. fuel cell and hydrogen technologies market - continuing America's leadership in clean energy innovation and

  19. Sensitive hydrogen leak detector

    DOE Patents [OSTI]

    Myneni, Ganapati Rao (Yorktown, VA)

    1999-01-01

    A sensitive hydrogen leak detector system using passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor.

  20. Sensitive hydrogen leak detector

    DOE Patents [OSTI]

    Myneni, G.R.

    1999-08-03

    A sensitive hydrogen leak detector system is described which uses passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor. 1 fig.

  1. Hydrogen separation process

    DOE Patents [OSTI]

    Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

    2011-05-24

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  2. Alternative Transportation Technologies: Hydrogen, Biofuels,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transportation Technologies: Hydrogen, Biofuels, Advanced Efficiency, and Plug-in Hybrid Electric Vehicles Alternative Transportation Technologies: Hydrogen, Biofuels, Advanced ...

  3. Alternative Fuels Data Center: Hydrogen

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen to someone by E-mail Share Alternative Fuels Data Center: Hydrogen on Facebook Tweet about Alternative Fuels Data Center: Hydrogen on Twitter Bookmark Alternative Fuels Data Center: Hydrogen on Google Bookmark Alternative Fuels Data Center: Hydrogen on Delicious Rank Alternative Fuels Data Center: Hydrogen on Digg Find More places to share Alternative Fuels Data Center: Hydrogen on

  4. Renewable Hydrogen | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Renewable Hydrogen Welcoming presentations at the Delivering Renewable Hydrogen Workshop: A Focus on Near-Term Applications, Nov. 16, 2009, Palm Springs, CA PDF icon renewable_hydrogen_workshop_nov16_remick.pdf More Documents & Publications National Hydrogen Learning Demonstration Status CoolCab Truck Thermal Load Reduction Hydrogen Transmission and Distribution Workshop

  5. Fluoride-elicited developmental testicular toxicity in rats: Roles of endoplasmic reticulum stress and inflammatory response

    SciTech Connect (OSTI)

    Zhang, Shun; Jiang, Chunyang; Liu, Hongliang; Guan, Zhizhong; Zeng, Qiang; Zhang, Cheng; Lei, Rongrong; Xia, Tao; Gao, Hui; Yang, Lu; Chen, Yihu; Wu, Xue; Zhang, Xiaofei; Cui, Yushan; Yu, Linyu; Wang, Zhenglun; Wang, Aiguo

    2013-09-01

    Long-term excessive fluoride intake is known to be toxic and can damage a variety of organs and tissues in the human body. However, the molecular mechanisms underlying fluoride-induced male reproductive toxicity are not well understood. In this study, we used a rat model to simulate the situations of human exposure and aimed to evaluate the roles of endoplasmic reticulum (ER) stress and inflammatory response in fluoride-induced testicular injury. SpragueDawley rats were administered with sodium fluoride (NaF) at 25, 50 and 100 mg/L via drinking water from pre-pregnancy to gestation, birth and finally to post-puberty. And then the testes of male offspring were studied at 8 weeks of age. Our results demonstrated that fluoride treatment increased MDA accumulation, decreased SOD activity, and enhanced germ cell apoptosis. In addition, fluoride elevated mRNA and protein levels of glucose-regulated protein 78 (GRP78), inositol requiring ER-to-nucleus signal kinase 1 (IRE1), and C/EBP homologous protein (CHOP), indicating activation of ER stress signaling. Furthermore, fluoride also induced testicular inflammation, as manifested by gene up-regulation of tumor necrosis factor-? (TNF-?), interleukin-1? (IL-1?), inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2), in a nuclear factor-?B (NF-?B)-dependent manner. These were associated with marked histopathological lesions including injury of spermatogonia, decrease of spermatocytes and absence of elongated spermatids, as well as severe ultrastructural abnormalities in testes. Taken together, our results provide compelling evidence that ER stress and inflammation would be novel and significant mechanisms responsible for fluoride-induced disturbance of spermatogenesis and germ cell loss in addition to oxidative stress. - Highlights: We used a rat model to simulate the situations of human fluoride (F) exposure. Developmental F exposure induces testicular damage related with oxidative stress. Endoplasmic reticulum stress is involved in testis disorder and germ cell apoptosis. Inflammatory response is implicated in impaired spermatogenesis and germ cell loss.

  6. Hydrogen Filling Station

    SciTech Connect (OSTI)

    Boehm, Robert F; Sabacky, Bruce; Anderson II, Everett B; Haberman, David; Al-Hassin, Mowafak; He, Xiaoming; Morriseau, Brian

    2010-02-24

    Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. The Freedom CAR and Freedom FUEL initiatives emphasize the importance of hydrogen as a future transportation fuel. Presently, Las Vegas has one hydrogen fueling station powered by natural gas. However, the use of traditional sources of energy to produce hydrogen does not maximize the benefit. The hydrogen fueling station developed under this grant used electrolysis units and solar energy to produce hydrogen fuel. Water and electricity are furnished to the unit and the output is hydrogen and oxygen. Three vehicles were converted to utilize the hydrogen produced at the station. The vehicles were all equipped with different types of technologies. The vehicles were used in the day-to-day operation of the Las Vegas Valley Water District and monitoring was performed on efficiency, reliability and maintenance requirements. The research and demonstration utilized for the reconfiguration of these vehicles could lead to new technologies in vehicle development that could make hydrogen-fueled vehicles more cost effective, economical, efficient and more widely used. In order to advance the development of a hydrogen future in Southern Nevada, project partners recognized a need to bring various entities involved in hydrogen development and deployment together as a means of sharing knowledge and eliminating duplication of efforts. A road-mapping session was held in Las Vegas in June 2006. The Nevada State Energy Office, representatives from DOE, DOE contractors and LANL, NETL, NREL were present. Leadership from the National hydrogen Association Board of Directors also attended. As a result of this session, a roadmap for hydrogen development was created. This roadmap has the ability to become a tool for use by other road-mapping efforts in the hydrogen community. It could also become a standard template for other states or even countries to approach planning for a hydrogen future. Project partners also conducted a workshop on hydrogen safety and permitting. This provided an opportunity for the various permitting agencies and end users to gather to share experiences and knowledge. As a result of this workshop, the permitting process for the hydrogen filling station on the Las Vegas Valley Water Districts land was done more efficiently and those who would be responsible for the operation were better educated on the safety and reliability of hydrogen production and storage. The lessons learned in permitting the filling station and conducting this workshop provided a basis for future hydrogen projects in the region. Continuing efforts to increase the working pressure of electrolysis and efficiency have been pursued. Research was also performed on improving the cost, efficiency and durability of Proton Exchange Membrane (PEM) hydrogen technology. Research elements focused upon PEM membranes, electrodes/catalysts, membrane-electrode assemblies, seals, bipolar plates, utilization of renewable power, reliability issues, scale, and advanced conversion topics. Additionally, direct solar-to-hydrogen conversion research to demonstrate stable and efficient photoelectrochemistry (PEC) hydrogen production systems based on a number of optional concepts was performed. Candidate PEC concepts included technical obstacles such as inefficient photocatalysis, inadequate photocurrent due to non-optimal material band gap energies, rapid electron-hole recombination, reduced hole mobility and diminished operational lifetimes of surface materials exposed to electrolytes. Project Objective 1: Design, build, operate hydrogen filling station Project Objective 2: Perform research and development for utilizing solar technologies on the hydrogen filling station and convert two utility vehicles for use by the station operators Project Objective 3: Increase capacity of hydrogen filling station; add additional vehicle; conduct safety workshop; develop a roadmap for hydrogen development; accelerate the development of photovoltaic components Project Objective 4:

  7. Hydrogen permeability and Integrity of hydrogen transfer pipelines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy permeability and Integrity of hydrogen transfer pipelines Hydrogen permeability and Integrity of hydrogen transfer pipelines Presentation by 03-Babu for the DOE Hydrogen Pipeline R&D Project Review Meeting held January 5th and 6th, 2005 at Oak Ridge National Laboratory in Oak Ridge, Tennessee. PDF icon 03_babu_transfer.pdf More Documents & Publications Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Proceedings of the 2005 Hydrogen Pipeline

  8. Ultrafine hydrogen storage powders

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Ellis, Timothy W. (Doylestown, PA); Pecharsky, Vitalij K. (Ames, IA); Ting, Jason (Ames, IA); Terpstra, Robert (Ames, IA); Bowman, Robert C. (La Mesa, CA); Witham, Charles K. (Pasadena, CA); Fultz, Brent T. (Pasadena, CA); Bugga, Ratnakumar V. (Arcadia, CA)

    2000-06-13

    A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

  9. Assessing Steel Pipeline and Weld Susceptibility to Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Documents & Publications Hydrogen permeability and Integrity of hydrogen transfer pipelines Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Hydrogen...

  10. Effect of temperature on the complexation of Uranium(VI) with fluoride in aqueous solutions

    SciTech Connect (OSTI)

    Tian, Guoxin; Rao, Linfeng

    2009-05-18

    Complexation of U(VI) with fluoride at elevated temperatures in aqueous solutions was studied by spectrophotometry. Four successive complexes, UO{sub 2}F{sup +}, UO{sub 2}F{sub 2}(aq), UO{sub 2}F{sub 3}{sup -}, and UO{sub 2}F{sub 4}{sup 2-}, were identified, and the stability constants at 25, 40, 55, and 70 C were calculated. The stability of the complexes increased as the temperature was elevated. The enthalpies of complexation at 25 C were determined by microcalorimetry. Thermodynamic parameters indicate that the complexation of U(VI) with fluoride in aqueous solutions at 25 to 70 C is slightly endothermic and entropy-driven. The Specific Ion Interaction (SIT) approach was used to obtain the thermodynamic parameters of complexation at infinite dilution. Structural information on the U(VI)/fluoride complexes was obtained by extended X-ray absorption fine structure spectroscopy.

  11. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  12. Dispersion of Hydrogen Clouds

    SciTech Connect (OSTI)

    Michael R. Swain; Eric S. Grilliot; Matthew N. Swain

    2000-06-30

    The following is the presentation of a simplification of the Hydrogen Risk Assessment Method previously developed at the University of Miami. It has been found that for simple enclosures, hydrogen leaks can be simulated with helium leaks to predict the concentrations of hydrogen gas produced. The highest concentrations of hydrogen occur near the ceiling after the initial transients disappear. For the geometries tested, hydrogen concentrations equal helium concentrations for the conditions of greatest concern (near the ceiling after transients disappear). The data supporting this conclusion is presented along with a comparison of hydrogen, LPG, and gasoline leakage from a vehicle parked in a single car garage. A short video was made from the vehicle fuel leakage data.

  13. Hydrogenation of carbonaceous materials

    DOE Patents [OSTI]

    Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

    1980-01-01

    A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000.degree. C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

  14. Hawaii Renewable Hydrogen Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Hydrogen Program State & Regional Initiatives Webinar 14 October 2009 Mitch Ewan Hydrogen Systems Program Manager Hawaii Natural Energy Institute Chenoa Farnsworth Partner Kolohala Holdings, LLP Overview * Hawaii's Energy Situation * Mitch Ewan * Hawaii Power Park Project * Mitch Ewan * The Renewables-to-Hydrogen Fund * Chenoa Farnsworth Hawaii - Most Petroleum Dependent State Petroleum dependence for electricity - top six states Highest Electricity Prices in U.S. Hawaii and US

  15. National hydrogen energy roadmap

    SciTech Connect (OSTI)

    None, None

    2002-11-01

    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development. Based on the results of the government-industry National Hydrogen Energy Roadmap Workshop, held in Washington, DC on April 2-3, 2002, it displays the development of a roadmap for America's clean energy future and outlines the key barriers and needs to achieve the hydrogen vision goals defined in

  16. Hydrogen powered bus

    ScienceCinema (OSTI)

    None

    2013-11-22

    Take a ride on a new type of bus, fueled by hydrogen. These hydrogen taxis are part of a Department of Energy-funded deployment of hydrogen powered vehicles and fueling infrastructure at nine federal facilities across the country to demonstrate this market-ready advanced technology. Produced and leased by Ford Motor Company , they consist of one 12- passenger bus and one nine-passenger bus. More information at: http://go.usa.gov/Tgr

  17. Hydrogen Contamination Detector Workshop

    Broader source: Energy.gov [DOE]

    Workshop report, agenda, and presentations from the Hydrogen Contamination Detector Workshop hosted by SAE International on June 12, 2014, in Troy, Michigan. Sponsored by the U.S. Department of Energy (DOE) Fuel Cell Technologies Office, the workshop was held to gather individual input from key stakeholders about suitable technologies and research and development (R&D) gaps and needs for hydrogen contamination detectors at hydrogen refueling stations.

  18. Materials for high-temperature hydrogen fluorine environments. Final report, June 1976-December 1978

    SciTech Connect (OSTI)

    Holcombe, C.E. Jr.; Kovach, L.

    1981-03-01

    A determination has been made of the stability of 35 materials under high-temperature, fluorine rich, hydrogen fluoride torch testing. Refractory materials tested included 4 borides, 3 carbides, 3 nitrides, 12 oxides, 1 oxynitride, 1 sulfide, 10 metals, and carbon (10 types). Three materials distinctly performed better than nickel: lanthanum hexaboride, calcium hexaboride, and lanthanum silicon oxynitride. Of these, lanthanum hexaboride is the best candidate tested since it has an estimated upper use temperature > 1726 K, which is above the melting point and more than 300 K above the upper use temperature of nickel.

  19. NREL: Learning - Hydrogen Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Basics Hydrogen is a clean-burning fuel, and when combined with oxygen in a fuel cell, it produces heat and electricity with only water vapor as a by-product. But hydrogen does not exist freely in nature: it is only produced from other sources of energy, so it is often referred to as an energy carrier, that is, an efficient way to store and transport energy. Hydrogen can be made directly from fossil fuels or biomass, or it can be produced by passing electricity through water, breaking

  20. Hydrogen ion microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.; Deb, S.K.

    1990-10-02

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing. 6 figs.

  1. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); Hoffheins, Barbara S. (Knoxville, TN); Fleming, Pamela H. (Oak Ridge, TN)

    1994-01-01

    A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed.

  2. Hydrogen Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.

  3. Hydrogen ion microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO); Deb, Satyen K. (Boulder, CO)

    1990-01-01

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing.

  4. Hydrogen Industrial Trucks

    Office of Energy Efficiency and Renewable Energy (EERE)

    Slides from the U.S. Department of Energy Hydrogen Component and System Qualification Workshop held November 4, 2010 in Livermore, CA.

  5. HYDROGEN TO THE HIGHWAYS

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  6. Hydrogen Generator Appliance

    Broader source: Energy.gov [DOE]

    Presentation by Gus Block, Nuvera Fuel Cells, at the Natural Gas and Hydrogen Infrastructure Opportunities Workshop held October 18-19, 2011, in Lemont, Illinois.

  7. Hydrogen Delivery and Fueling

    SciTech Connect (OSTI)

    2015-09-09

    This MP3 provides an overview of how hydrogen is delivered from the point of production to where it is used.

  8. Hydrogen purification system

    DOE Patents [OSTI]

    Golben, Peter Mark

    2010-06-15

    The present invention provides a system to purify hydrogen involving the use of a hydride compressor and catalytic converters combined with a process controller.

  9. Hydrogen Safety Knowledge Tools

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  10. Renewable Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Remick, R. J.

    2009-11-16

    Presentation about the United State's dependence on oil, how energy solutions are challenging, and why hydrogen should be considered as a long-term alternative for transportation fuel.

  11. President's Hydrogen Fuel Initiative

    Broader source: Energy.gov [DOE]

    Hydrogen Infrastructure and Fuel Cell Technologies put on an Accelerated Schedule. President Bush commits a total $1.7 billion over first 5 years

  12. Hydrogen permeation resistant barrier

    DOE Patents [OSTI]

    McGuire, J.C.; Brehm, W.F.

    1980-02-08

    A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

  13. California Hydrogen Infrastructure Project

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  14. California Hydrogen Infrastructure Project | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Infrastructure Project Jump to: navigation, search Name: California Hydrogen Infrastructure Project Place: California Sector: Hydro, Hydrogen Product: String...

  15. Massachusetts Hydrogen Coalition | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Coalition Jump to: navigation, search Logo: Massachusetts Hydrogen Coalition Name: Massachusetts Hydrogen Coalition Address: 100 Cummings Center Place: Beverly,...

  16. Electrochemical hydrogen Storage Systems

    SciTech Connect (OSTI)

    Dr. Digby Macdonald

    2010-08-09

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

  17. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Not Available

    1982-04-29

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the reusltant hydrogen.

  18. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Harrah, Larry A. (Albuquerque, NM); Mead, Keith E. (Peralta, NM); Smith, Henry M. (Overland Park, KS)

    1983-01-01

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  19. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Harrah, L.A.; Mead, K.E.; Smith, H.M.

    1983-09-20

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (1) a solid acetylenic compound and (2) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  20. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

    2013-02-12

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  1. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T. (Ann Arbor, MI); Li, Yingwel (Ann Arbor, MI); Lachawiec, Jr., Anthony J. (Ann Arbor, MI)

    2011-05-31

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  2. Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines

    Broader source: Energy.gov [DOE]

    Project Objectives: To gain basic understanding of hydrogen permeation behavior and its impact on hydrogen embrittlement of pipeline steels under high gaseous pressures relevant to hydrogen gas transmission pipeline

  3. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G.; Roberts, George W.

    1980-08-12

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  4. Green Hydrogen Company | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Company Jump to: navigation, search Logo: Green Hydrogen Company Name: Green Hydrogen Company Abbreviation: GH2 Address: Green Hydrogen Company, Head Office, 9...

  5. Safe Hydrogen LLC | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen LLC Jump to: navigation, search Name: Safe Hydrogen LLC Place: Lexington, Massachusetts Sector: Hydro, Hydrogen Product: Focused on hydrogen storage, through a 'slurry' of...

  6. Hydrogen Car Co | Open Energy Information

    Open Energy Info (EERE)

    Car Co Jump to: navigation, search Name: Hydrogen Car Co Place: Los Angeles, California Zip: 90036 Sector: Hydro, Hydrogen Product: The Hydrogen Car Company produces hydrogen...

  7. The Hydrogen Company | Open Energy Information

    Open Energy Info (EERE)

    Company Jump to: navigation, search Name: The Hydrogen Company Abbreviation: HydroGen Address: The Hydrogen Company, HydroGen Engineering and Consulting, Head Office, 9...

  8. Sandia Energy - Maritime Hydrogen Fuel Cell Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cell Project Home Transportation Energy Hydrogen Market Transformation Maritime Hydrogen & SF-BREEZE Maritime Hydrogen Fuel Cell Project Maritime Hydrogen Fuel Cell...

  9. NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage & Transportation | Department of Energy Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation Presented at the Renewable Hydrogen Workshop, Nov. 16, 2009, in Palm Springs, CA PDF icon renewable_hydrogen_workshop_nov16_ramsden.pdf More Documents & Publications Hour-by-Hour Cost Modeling of Optimized Central Wind-Based Water Electrolysis

  10. Membrane for hydrogen recovery from streams containing hydrogen sulfide

    DOE Patents [OSTI]

    Agarwal, Pradeep K.

    2007-01-16

    A membrane for hydrogen recovery from streams containing hydrogen sulfide is provided. The membrane comprises a substrate, a hydrogen permeable first membrane layer deposited on the substrate, and a second membrane layer deposited on the first layer. The second layer contains sulfides of transition metals and positioned on the on a feed side of the hydrogen sulfide stream. The present invention also includes a method for the direct decomposition of hydrogen sulfide to hydrogen and sulfur.

  11. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, B.S.; Lauf, R.J.

    1995-09-19

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors. 8 figs.

  12. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, Barbara S. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1995-01-01

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

  13. Hydrogen Fuel Quality

    SciTech Connect (OSTI)

    Rockward, Tommy

    2012-07-16

    For the past 6 years, open discussions and/or meetings have been held and are still on-going with OEM, Hydrogen Suppliers, other test facilities from the North America Team and International collaborators regarding experimental results, fuel clean-up cost, modeling, and analytical techniques to help determine levels of constituents for the development of an international standard for hydrogen fuel quality (ISO TC197 WG-12). Significant progress has been made. The process for the fuel standard is entering final stages as a result of the technical accomplishments. The objectives are to: (1) Determine the allowable levels of hydrogen fuel contaminants in support of the development of science-based international standards for hydrogen fuel quality (ISO TC197 WG-12); and (2) Validate the ASTM test method for determining low levels of non-hydrogen constituents.

  14. Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22, 2002-July 22, 2002 A report showing a comparative scooping economic analysis of 19 pathways for ...

  15. Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines

    Broader source: Energy.gov [DOE]

    Code for Hydrogen Piping and Pipelines. B31 Hydrogen Section Committee to develop a new code for H2 piping and pipelines.

  16. Why Hydrogen? Hydrogen from Diverse Domestic Resources | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overview of FreedomCAR & Fuels PartnershipDOE Delivery Program President's Hydrogen Fuel Initiative Hydrogen Posture Plan: An Integrated Research, Development and...

  17. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    60-42773 February 2009 Hydrogen Resource Assessment Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power Anelia Milbrandt and Margaret Mann National Renewable Energy...

  18. Renewable Resources for Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A. A.

    2010-05-03

    This presentation provides an overview of renewable resources for hydrogen. It was presented at the National Hydrogen Association Hydrogen Conference & Expo in Long Beach, CA, May 3-6, 2010.

  19. Radiolytic Effects on Fluoride Impurities in a U{sub 3}O{sub 8} Matrix

    SciTech Connect (OSTI)

    Icenhour, A.S.

    2000-05-01

    The safe handling and storage of radioactive materials require an understanding of the effects of radiolysis on those materials. Radiolysis may result in the production of gases (e.g., corrosives) or pressures that are deleterious to storage containers. A study has been performed to address these concerns as they relate to the radiolysis of residual fluoride compounds in uranium oxides.

  20. Nuclear quantum effects in water exchange around lithium and fluoride ions

    SciTech Connect (OSTI)

    Wilkins, David M.; Manolopoulos, David; Dang, Liem X.

    2015-02-14

    We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the water exchange reactions are unaffected by quantization, so a classical description of these reactions gives qualitatively correct and quantitatively reasonable results. We also find that the quantum effects in solutions of lithium are larger than in solutions of fluoride. This is partly due to the stronger interaction of lithium with water molecules, partly due to the lighter mass of lithium, and partly due to competing quantum effects in the hydration of fluoride, which are absent in the hydration of lithium. LXD was supported by US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

  1. Nuclear quantum effects in water exchange around lithium and fluoride ions

    SciTech Connect (OSTI)

    Wilkins, David M.; Manolopoulos, David E.; Dang, Liem X.

    2015-02-14

    We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the exchange processes are unaffected by quantization, so a classical description of these reactions gives qualitatively correct and quantitatively reasonable results. We also find that the quantum effects in solutions of lithium are larger than in solutions of fluoride. This is partly due to the stronger interaction of lithium with water molecules, partly due to the lighter mass of lithium and partly due to competing quantum effects in the hydration of fluoride, which are absent in the hydration of lithium.

  2. Dissolution of HTGR TRISO beads by the alkali fluoride fusion method

    SciTech Connect (OSTI)

    Byster, S.E.

    1980-07-01

    The alkali fluoride fusion method for the dissolution of HTGR TRISO fuel beads offers significant time advantage over other commonly used fusion procedures when applied to samples weighing less than three grams. The method is straightforward, utilizes standard analytical laboratory equipment, and yields solutions which may be utilized by customary procedures.

  3. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  4. Hydrogen Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resources Hydrogen Resources Hydrogen can be produced from diverse, domestic resources. Currently, most hydrogen is produced from fossil fuels, specifically natural gas. Electricity-from the grid or from renewable sources such as wind, solar, geothermal, or biomass-is also currently used to produce hydrogen. In the longer term, solar energy and biomass can be used more directly to generate hydrogen. Natural Gas and Other Fossil Fuels Fossil fuels can be reformed to release the hydrogen from

  5. Hydrogen Storage | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Hydrogen Storage The Fuel Cell Technologies Office (FCTO) is developing onboard automotive hydrogen storage systems that allow for a driving range of more than 300 miles while meeting cost, safety, and performance requirements. Why Study Hydrogen Storage Hydrogen storage is a key enabling technology for the advancement of hydrogen and fuel cell technologies in applications including stationary power, portable power, and transportation. Hydrogen has the highest energy per mass of any

  6. Hydrogen Data Book from the Hydrogen Analysis Resource Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Hydrogen Data Book contains a wide range of factual information on hydrogen and fuel cells (e.g., hydrogen properties, hydrogen production and delivery data, and information on fuel cells and fuel cell vehicles), and it also provides other data that might be useful in analyses of hydrogen infrastructure in the United States (e.g., demographic data and data on energy supply and/or infrastructure). Its made available from the Hydrogen Analysis Resource Center along with a wealth of related information. The related information includes guidelines for DOE Hydrogen Program Analysis, various calculator tools, a hydrogen glossary, related websites, and analysis tools relevant to hydrogen and fuel cells. [From http://hydrogen.pnl.gov/cocoon/morf/hydrogen

  7. Hydrogen Data Book from the Hydrogen Analysis Resource Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Hydrogen Data Book contains a wide range of factual information on hydrogen and fuel cells (e.g., hydrogen properties, hydrogen production and delivery data, and information on fuel cells and fuel cell vehicles), and it also provides other data that might be useful in analyses of hydrogen infrastructure in the United States (e.g., demographic data and data on energy supply and/or infrastructure). ItÆs made available from the Hydrogen Analysis Resource Center along with a wealth of related information. The related information includes guidelines for DOE Hydrogen Program Analysis, various calculator tools, a hydrogen glossary, related websites, and analysis tools relevant to hydrogen and fuel cells. [From http://hydrogen.pnl.gov/cocoon/morf/hydrogen

  8. Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    Energy Jump to: navigation, search Name: Hydrogen Energy Place: Surrey, England, United Kingdom Zip: KT13 0NY Sector: Carbon, Hydro, Hydrogen Product: Surrey-based BP subsidiary...

  9. Hydrogen Ventures | Open Energy Information

    Open Energy Info (EERE)

    Ventures Jump to: navigation, search Logo: Hydrogen Ventures Name: Hydrogen Ventures Address: 1219 N. Studabaker Road Place: Long Beach, California Zip: 90811 Region: Southern CA...

  10. Hydrogen Production Technical Team Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... hydrogen control to assure public safety and address ... pathway," International Journal of Hydrogen Energy 34 ... Texas: Center for Energy Economics, 2004), http:...

  11. Uranium hexafluoride liquid thermal expansion, elusive eutectic with hydrogen fluoride, and very first production using chlorine trifluoride

    SciTech Connect (OSTI)

    Rutledge, G.P.

    1991-12-31

    Three unusual incidents and case histories involving uranium hexafluoride in the enrichment facilities of the USA in the late 1940`s and early 1950`s are presented. The history of the measurements of the thermal expansion of liquids containing fluorine atoms within the molecule is reviewed with special emphasis upon uranium hexafluoride. A comparison is made between fluorinated esters, fluorocarbons, and uranium hexafluoride. The quantitative relationship between the thermal expansion coefficient, a, of liquids and the critical temperature, T{sub c} is presented. Uranium hexafluoride has an a that is very high in a temperature range that is used by laboratory and production workers - much higher than any other liquid measured. This physical property of UF{sub 6} has resulted in accidents involving filling the UF{sub 6} containers too full and then heating with a resulting rupture of the container. Such an incident at a uranium gaseous diffusion plant is presented. Production workers seldom {open_quotes}see{close_quotes} uranium hexafluoride. The movement of UF{sub 6} from one container to another is usually trailed by weight, not sight. Even laboratory scientists seldom {open_quotes}see{close_quotes} solid or liquid UF{sub 6} and this can be a problem at times. This inability to {open_quotes}see{close_quotes} the UF{sub 6}-HF mixtures in the 61.2{degrees}C to 101{degrees}C temperature range caused a delay in the understanding of the phase diagram of UF{sub 6}-HF which has a liquid - liquid immiscible region that made the eutectic composition somewhat elusive. Transparent fluorothene tubes solved the problem both for the UF{sub 6}-HF phase diagram as well as the UF{sub 6}-HF-CIF{sub 3} phase diagram with a miscibility gap starting at 53{degrees}C. The historical background leading to the first use of CIF{sub 3} to produce UF{sub 6} in both the laboratory and plant at K-25 is presented.

  12. An Experimental Test Facility to Support Development of the Fluoride Salt Cooled High Temperature Reactor

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Aaron, Adam M; Cunningham, Richard Burns; Fugate, David L; Holcomb, David Eugene; Kisner, Roger A; Peretz, Fred J; Robb, Kevin R; Wilgen, John B; Wilson, Dane F

    2014-01-01

    The need for high-temperature (greater than 600 C) energy exchange and delivery systems is significantly increasing as the world strives to improve energy efficiency and develop alternatives to petroleum-based fuels. Liquid fluoride salts are one of the few energy transport fluids that have the capability of operating at high temperatures in combination with low system pressures. The Fluoride Salt-Cooled High-Temperature Reactor design uses fluoride salt to remove core heat and interface with a power conversion system. Although a significant amount of experimentation has been performed with these salts, specific aspects of this reactor concept will require experimental confirmation during the development process. The experimental facility described here has been constructed to support the development of the Fluoride Salt Cooled High Temperature Reactor concept. The facility is capable of operating at up to 700 C and incorporates a centrifugal pump to circulate FLiNaK salt through a removable test section. A unique inductive heating technique is used to apply heat to the test section, allowing heat transfer testing to be performed. An air-cooled heat exchanger removes added heat. Supporting loop infrastructure includes a pressure control system; trace heating system; and a complement of instrumentation to measure salt flow, temperatures, and pressures around the loop. The initial experiment is aimed at measuring fluoride salt heat transfer inside a heated pebble bed similar to that used for the core of the pebble bed advanced high-temperature reactor. This document describes the details of the loop design, auxiliary systems used to support the facility, the inductive heating system, and facility capabilities.

  13. Extremely weak hydrogen flames

    SciTech Connect (OSTI)

    Lecoustre, V.R.; Sunderland, P.B. [Department of Fire Protection Engineering, University of Maryland, College Park, MD 20742 (United States); Chao, B.H. [Department of Mechanical Engineering, University of Hawaii, Honolulu, HI 96822 (United States); Axelbaum, R.L. [Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, St. Louis, MO 63130 (United States)

    2010-11-15

    Hydrogen jet diffusion flames were observed near their quenching limits. These involved downward laminar flow of hydrogen from a stainless steel hypodermic tube with an inside diameter of 0.15 mm. Near their quenching limits these flames had hydrogen flow rates of 3.9 and 2.1 {mu}g/s in air and oxygen, respectively. Assuming complete combustion, the associated heat release rates are 0.46 and 0.25 W. To the authors' knowledge, these are the weakest self-sustaining steady flames ever observed. (author)

  14. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T. (Livermore, CA)

    1981-01-01

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  15. Thermochemical method for producing hydrogen from hydrogen sulfide

    SciTech Connect (OSTI)

    Herrington, D.R.

    1984-02-21

    Hydrogen is produced from hydrogen sulfide by a 3-step, thermochemical process comprising: (a) contacting hydrogen sulfide with carbon dioxide to form carbonyl sulfide and water, (b) contacting the carbonyl sulfide produced in (a) with oxygen to form carbon monoxide and sulfur dioxide, and (c) contacting the carbon monoxide produced in (b) with water to form carbon dioxide and hydrogen.

  16. Advancing the Hydrogen Safety Knowledge Base

    SciTech Connect (OSTI)

    Weiner, Steven C.

    2014-12-01

    A White Paper of the International Energy Agency Hydrogen Implementing Agreement Task 31 - Hydrogen Safety

  17. Observation of Fractional Stokes-Einstein Behavior in the Simplest Hydrogen-bonded Liquid

    SciTech Connect (OSTI)

    Herwig, Kenneth W; Molaison, Jamie J; Fernandez-Alonso, F.; Bermejo, F. J.; Turner, John F. C.; McLain, Sylvia E.

    2007-01-01

    Quasielastic neutron scattering has been used to investigate the single-particle dynamics of hydrogen fluoride across its entire liquid range at ambient pressure. For T > 230 K, translational diffusion obeys the celebrated Stokes-Einstein relation, in agreement with nuclear magnetic resonance studies. At lower temperatures, we find significant deviations from the above behavior in the form of a power law with exponent xi = -0.71+/-0.05. More striking than the above is a complete breakdown of the Debye-Stokes-Einstein relation for rotational diffusion. Our findings provide the first experimental verification of fractional Stokes-Einstein behavior in a hydrogen-bonded liquid, in agreement with recent computer simulations.

  18. The Hydrogen Connection

    SciTech Connect (OSTI)

    Barilo, Nick F.

    2014-05-01

    As the world seeks to identify alternative energy sources, hydrogen and fuel cell technologies will offer a broad range of benefits for the environment, the economy and energy security.

  19. Biological Hydrogen Production Workshop

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory (NREL) held a Biological Hydrogen Production Workshop on September 24–25, 2013, in Golden, Colorado. The workshop...

  20. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Lauf, R.J.; Hoffheins, B.S.; Fleming, P.H.

    1994-11-22

    A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed. 6 figs.

  1. National Hydrogen Energy Roadmap

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy developme

  2. Hydrogen storage compositions

    DOE Patents [OSTI]

    Li, Wen; Vajo, John J.; Cumberland, Robert W.; Liu, Ping

    2011-04-19

    Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

  3. Hydrogen Fuel Cell Demonstration ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brothers, Ltd., at their facility in the Port of Honolulu. The pilot hydrogen fuel cell unit will be used in place of a diesel generator currently used to provide power for...

  4. Hydrogen Production: Coal Gasification

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically through the process of coal gasification with carbon capture, utilization, and storage.

  5. Hydrogen recovery process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

    2000-01-01

    A treatment process for a hydrogen-containing off-gas stream from a refinery, petrochemical plant or the like. The process includes three separation steps: condensation, membrane separation and hydrocarbon fraction separation. The membrane separation step is characterized in that it is carried out under conditions at which the membrane exhibits a selectivity in favor of methane over hydrogen of at least about 2.5.

  6. Hydrogen Compatibility of Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compatibility of Materials August 13, 2013 DOE EERE Fuel Cell Technologies Office Webinar Chris San Marchi Sandia National Laboratories Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000 SAND2013-6278P 2 Webinar Objectives * Provide context for hydrogen embrittlement and hydrogen

  7. Hydrogen Equipment Certification Guide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Equipment Certification Guide U.S. Department of Energy Fuel Cell Technologies Office December 10 th , 2015 Presenter: Nick Barilo Pacific Northwest National Laboratory (PNNL) Hydrogen Safety Program Manager DOE Host: Will James - DOE Fuel Cell Technologies Office 2 | Fuel Cell Technologies Office eere.energy.gov Question and Answer * Please type your questions into the question box 2 / / Hydrogen Equipment Certification Guide: Introduction and Kickoff for the Stakeholder Review Nick Barilo PNNL

  8. Method of producing hydrogen

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Wilding, Bruce M.; Zollinger, William T.

    2006-12-26

    A method of producing hydrogen is disclosed and which includes providing a first composition; providing a second composition; reacting the first and second compositions together to produce a chemical hydride; providing a liquid and reacting the chemical hydride with the liquid in a manner to produce a high pressure hydrogen gas and a byproduct which includes the first composition; and reusing the first composition formed as a byproduct in a subsequent chemical reaction to form additional chemical hydride.

  9. Purdue Hydrogen Systems Laboratory

    SciTech Connect (OSTI)

    Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng

    2011-12-28

    The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up. Efforts continued to explore existing catalytic methods involving nano catalysts for capture of CO2 from the fermentation process.

  10. Safetygram Gaseous Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is a colorless, odorless, tasteless, highly flammable gas. It is also the lightestweight gas. Since hydrogen is noncorrosive, special materials of construction are not usually required. The American Society of Mechanical Engineers (ASME) code and the American National Standards Institute (ANSI) Pressure Piping code specify vessel and piping design requirements for the pressures and temperatures involved. Applicable Dangerous Goods regulations specify requirements for vessels used for transportation.

  11. Cryogenic hydrogen release research.

    SciTech Connect (OSTI)

    LaFleur, Angela Christine

    2015-12-01

    The objective of this project was to devolop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. The necessary infrastructure has been specified and laboratory modifications are currently underway. Once complete, experiments from this platform will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  12. NREL: Hydrogen and Fuel Cells Research - Hydrogen Production and Delivery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Production and Delivery Learn how NREL is developing and advancing a number of pathways to renewable hydrogen production. Text Version Most of the hydrogen in the United States is produced by steam reforming of natural gas. For the near term, this production method will continue to dominate. Researchers at NREL are developing advanced processes to produce hydrogen economically from sustainable resources. NREL's hydrogen production and delivery R&D efforts, which are led by Huyen

  13. Hydrogen Material Compatibility for Hydrogen ICE | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Material Compatibility for Hydrogen ICE Hydrogen Material Compatibility for Hydrogen ICE 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon pm_04_smith.pdf More Documents & Publications Hydrogen Materials Compatibility for the H-ICE Engine Friction Reduction Through Surface Finish and Coatings Low-Friction Hard Coatings

  14. DOE Hydrogen and Fuel Cell Overview: 2011 Hydrogen Infrastructure Market

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Readiness Workshop | Department of Energy and Fuel Cell Overview: 2011 Hydrogen Infrastructure Market Readiness Workshop DOE Hydrogen and Fuel Cell Overview: 2011 Hydrogen Infrastructure Market Readiness Workshop Presentation by Sunita Satyapal, U.S. Department of Energy Fuel Cell Technologies Program Manager, at the Hydrogen Infrastructure Market Readiness Workshop, February 16, 2011, in Washington, D.C. PDF icon DOE Hydrogen and Fuel Cell Overview More Documents & Publications DOE

  15. Examining hydrogen transitions.

    SciTech Connect (OSTI)

    Plotkin, S. E.; Energy Systems

    2007-03-01

    This report describes the results of an effort to identify key analytic issues associated with modeling a transition to hydrogen as a fuel for light duty vehicles, and using insights gained from this effort to suggest ways to improve ongoing modeling efforts. The study reported on here examined multiple hydrogen scenarios reported in the literature, identified modeling issues associated with those scenario analyses, and examined three DOE-sponsored hydrogen transition models in the context of those modeling issues. The three hydrogen transition models are HyTrans (contractor: Oak Ridge National Laboratory), MARKAL/DOE* (Brookhaven National Laboratory), and NEMS-H2 (OnLocation, Inc). The goals of these models are (1) to help DOE improve its R&D effort by identifying key technology and other roadblocks to a transition and testing its technical program goals to determine whether they are likely to lead to the market success of hydrogen technologies, (2) to evaluate alternative policies to promote a transition, and (3) to estimate the costs and benefits of alternative pathways to hydrogen development.

  16. Hydrogen Distribution and Delivery Infrastructure

    SciTech Connect (OSTI)

    2008-11-01

    This 2-page fact sheet provides a brief introduction to hydrogen delivery technologies. Intended for a non-technical audience, it explains how hydrogen is transported and delivered today, the challenges to delivering hydrogen for use as a widespread energy carrier, and the research goals for hydrogen delivery.

  17. Hydrogen Delivery Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    The mission of the Hydrogen Delivery Technical Team (HDTT) is to enable the development of hydrogen delivery technologies, which will allow for fuel cell competitiveness with gasoline and hybrid technologies by achieving an as-produced, delivered, and dispensed hydrogen cost of $2-$4 per gallon of gasoline equivalent of hydrogen.

  18. Nanostructured materials for hydrogen storage

    DOE Patents [OSTI]

    Williamson, Andrew J. (Pleasanton, CA); Reboredo, Fernando A. (Pleasanton, CA)

    2007-12-04

    A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

  19. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.

    2011-08-10

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

  20. Hydrogen storage and generation system

    DOE Patents [OSTI]

    Dentinger, Paul M. (Sunol, CA); Crowell, Jeffrey A. W. (Castro Valley, CA)

    2010-08-24

    A system for storing and generating hydrogen generally and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses the beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  1. Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery Hydrogen Delivery A viable hydrogen infrastructure requires that hydrogen be able to be delivered from where it's produced to the point of end-use, such as a dispenser at a refueling station or stationary power site. Infrastructure includes the pipelines, trucks, storage facilities, compressors, and dispensers involved in the process of delivering fuel. Delivery technology for hydrogen infrastructure is currently available commercially, and several U.S. companies deliver bulk hydrogen

  2. SunLine Test Drives Hydrogen Bus: Hydrogen Fuel Cell & Infrastructure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Test Drives Hydrogen Bus: Hydrogen Fuel Cell & Infrastructure Technologies Program, Fuel Cell Bus Demonstration Projects Fact Sheet. SunLine Test Drives Hydrogen Bus: Hydrogen Fuel ...

  3. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, John P. (Boulder, CO); Way, J. Douglas (Boulder, CO)

    1997-01-01

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2. s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  4. Hydrogen-Selective Membrane

    DOE Patents [OSTI]

    Collins, John P. (Boulder, CO); Way, J. Douglas (Boulder, CO)

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2.s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  5. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2}s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  6. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1997-07-29

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2} s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  7. pH effect on the separation of uranium fluoride effluents by the reverse osmosis process

    SciTech Connect (OSTI)

    Yun Chen ); Min-Lin Chu; Mu-Chang Shieh , Lung-tan, )

    1992-04-01

    Ammonium fluoride solutions and uranium fluoride effluents (UFE) with solute concentrations from 0.101 to 7,920 kg/m{sup 3}, at pH 2.80 to 9.60, have been treated with a continuous feedback reverse osmosis (RO) process. The solute rejections of NH{sub 4}{sup +}, F{sup {minus}}, and U{sup 6+} depend heavily on the feed pH value. For ammonium fluoride solutions, the rejection ratio of NH{sub 4}{sup +} decreases sharply from ca. 90 to 44.2% with the feed pH increased from 3.30 to 9.60, while that of F{sup {minus}} increases abruptly from 44.8 to 99.9% at the same pH change. For UFE solutions, the rejection ratio of U{sup 6+} remains greater than 90% at pH 2.80-7.13, while that of F{sup {minus}} decreases steadily from 96.4 to 18.8% with decreasing feed pH. Accordingly, the fluoride ions can be separated from UFE solutions under acidic conditions. The changes of solute rejection with feed pH can be explained by the different solubilities of the solutes in the membrane at different pH values. The UFE solutions with {alpha} and {beta} activities at 20.4-53.7 and 8.99-21.3 ({times} 10{sup 5} Baq/m{sup 3}) can be reduced to a level lower than 2.41 and 3.37 ({times}10{sup 5} Baq/m{sup 3}), respectively, by the current RO process.

  8. Hydrogen production from carbonaceous material

    DOE Patents [OSTI]

    Lackner, Klaus S.; Ziock, Hans J.; Harrison, Douglas P.

    2004-09-14

    Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.

  9. Considerations of Alloy N for Fluoride Salt-Cooled High-Temperature Reactor Applications

    SciTech Connect (OSTI)

    Ren, Weiju; Muralidharan, Govindarajan; Wilson, Dane F; Holcomb, David Eugene

    2011-01-01

    Fluoride Salt-Cooled High-Temperature Reactors (FHRs) are a promising new class of thermal-spectrum nuclear reactors. The reactor structural materials must possess high-temperature strength and chemical compatibility with the liquid fluoride salt as well as with a power cycle fluid such as supercritical water while remaining resistant to residual air within the containment. Alloy N was developed for use with liquid fluoride salts and it possesses adequate strength and chemical compatibility up to about 700 C. A distinctive property of FHRs is that their maximum allowable coolant temperature is restricted by their structural alloy maximum service temperature. As the reactor thermal efficiency directly increases with the maximum coolant temperature, higher temperature resistant alloys are strongly desired. This paper reviews the current status of Alloy N and its relevance to FHRs including its design principles, development history, high temperature strength, environmental resistance, metallurgical stability, component manufacturability, ASME codification status, and reactor service requirements. The review will identify issues and provide guidance for improving the alloy properties or implementing engineering solutions.

  10. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Cheng, Yang-Tse (Rochester Hills, MI); Poli, Andrea A. (Livonia, MI); Meltser, Mark Alexander (Pittsford, NY)

    1999-01-01

    A thin film hydrogen sensor, includes: a substantially flat ceramic substrate with first and second planar sides and a first substrate end opposite a second substrate end; a thin film temperature responsive resistor on the first planar side of the substrate proximate to the first substrate end; a thin film hydrogen responsive metal resistor on the first planar side of the substrate proximate to the fist substrate end and proximate to the temperature responsive resistor; and a heater on the second planar side of the substrate proximate to the first end.

  11. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Cheng, Y.T.; Poli, A.A.; Meltser, M.A.

    1999-03-23

    A thin film hydrogen sensor includes a substantially flat ceramic substrate with first and second planar sides and a first substrate end opposite a second substrate end; a thin film temperature responsive resistor on the first planar side of the substrate proximate to the first substrate end; a thin film hydrogen responsive metal resistor on the first planar side of the substrate proximate to the fist substrate end and proximate to the temperature responsive resistor; and a heater on the second planar side of the substrate proximate to the first end. 5 figs.

  12. Hydrogen Storage System Challenges

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Challenges Advanced Composite Materials for Cold and Cryogenic Hydrogen Storage Applications in Fuel Cell Electric Vehicles October 29 th , 2015 Mike Veenstra Ford Research & Advanced Engineering Production fuel cell vehicles are being produced or planned by every major automotive OEM Toyota Honda Hyundai (credit: SA / ANL) Customer Expectations Driving Range Refueling Time Cargo Space Vehicle Weight Durability Cost Safety 0.0 2.0 4.0 6.0 8.0 10.0 Gasoline Hydrogen (700 bar) Natural

  13. The hydrogen hybrid option

    SciTech Connect (OSTI)

    Smith, J.R.

    1993-10-15

    The energy efficiency of various piston engine options for series hybrid automobiles are compared with conventional, battery powered electric, and proton exchange membrane (PEM) fuel cell hybrid automobiles. Gasoline, compressed natural gas (CNG), and hydrogen are considered for these hybrids. The engine and fuel comparisons are done on a basis of equal vehicle weight, drag, and rolling resistance. The relative emissions of these various fueled vehicle options are also presented. It is concluded that a highly optimized, hydrogen fueled, piston engine, series electric hybrid automobile will have efficiency comparable to a similar fuel cell hybrid automobile and will have fewer total emissions than the battery powered vehicle, even without a catalyst.

  14. Hydrogen production from microbial strains

    DOE Patents [OSTI]

    Harwood, Caroline S; Rey, Federico E

    2012-09-18

    The present invention is directed to a method of screening microbe strains capable of generating hydrogen. This method involves inoculating one or more microbes in a sample containing cell culture medium to form an inoculated culture medium. The inoculated culture medium is then incubated under hydrogen producing conditions. Once incubating causes the inoculated culture medium to produce hydrogen, microbes in the culture medium are identified as candidate microbe strains capable of generating hydrogen. Methods of producing hydrogen using one or more of the microbial strains identified as well as the hydrogen producing strains themselves are also disclosed.

  15. Hydrogen Production | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Hydrogen Production Hydrogen Production Hydrogen is the simplest element on earth-it consists of only one proton and one electron-and it is an energy carrier, not an energy source. Hydrogen can store and deliver usable energy, but it doesn't typically exist by itself in nature and must be produced from compounds that contain it. WHY STUDY HYDROGEN PRODUCTION Hydrogen can be used in fuel cells to generate power using a chemical reaction rather than combustion, producing only water and

  16. Regional Consumer Hydrogen Demand and Optimal Hydrogen Refueling Station Siting

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2008-04-01

    Using a GIS approach to spatially analyze key attributes affecting hydrogen market transformation, this study proposes hypothetical hydrogen refueling station locations in select subregions to demonstrate a method for determining station locations based on geographic criteria.

  17. 2nd International Hydrogen Infrastructure Challenges Webinar...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Infrastructure Challenges Workshop Summary - NOW, NEDO, and DOE Introduction to SAE Hydrogen Fueling Standardization Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling...

  18. Florida Hydrogen Initiative Inc | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Initiative Inc Jump to: navigation, search Name: Florida Hydrogen Initiative Inc Place: Florida Sector: Hydro, Hydrogen Product: Provides grants to aid the development of...

  19. Air Liquide Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Energy Jump to: navigation, search Logo: Air Liquide Hydrogen Energy Name: Air Liquide Hydrogen Energy Address: 6, Rue Cognacq-Jay Place: Paris, France Zip: 75321 Sector:...

  20. Hydrogen Solar Ltd | Open Energy Information

    Open Energy Info (EERE)

    Solar Ltd Jump to: navigation, search Name: Hydrogen Solar Ltd Place: Guildford, United Kingdom Zip: GU2 7YG Sector: Hydro, Hydrogen, Solar Product: Hydrogen Solar Ltd is...

  1. National Hydrogen Association | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Association Jump to: navigation, search Name: National Hydrogen Association Place: Washington, Washington, DC Zip: 20036 Sector: Hydro, Hydrogen Product: The source for...

  2. Highline Hydrogen Hybrids | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Hybrids Jump to: navigation, search Name: Highline Hydrogen Hybrids Place: farmington, Arkansas Zip: 72730-1500 Sector: Hydro, Hydrogen, Vehicles Product: US-based...

  3. Chevron Hydrogen Company LLC | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Company LLC Jump to: navigation, search Name: Chevron Hydrogen Company LLC Place: California Sector: Hydro, Hydrogen Product: California-based, subsidairy of Chevron...

  4. The London Hydrogen Partnership | Open Energy Information

    Open Energy Info (EERE)

    London Hydrogen Partnership Jump to: navigation, search Name: The London Hydrogen Partnership Place: London, United Kingdom Zip: SE1 2AA Sector: Hydro, Hydrogen Product: The London...

  5. Hunterston Hydrogen Ltd | Open Energy Information

    Open Energy Info (EERE)

    Hunterston Hydrogen Ltd Jump to: navigation, search Name: Hunterston Hydrogen Ltd Place: Anglesey, United Kingdom Zip: LL65 4RJ Sector: Hydro, Hydrogen, Wind energy Product:...

  6. German Hydrogen Association DWV | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Association DWV Jump to: navigation, search Name: German Hydrogen Association (DWV) Place: Berlin, Germany Zip: 12205 Sector: Hydro, Hydrogen Product: String...

  7. Hydrogen Engine Center HEC | Open Energy Information

    Open Energy Info (EERE)

    Engine Center HEC Jump to: navigation, search Name: Hydrogen Engine Center (HEC) Place: Algona, Iowa Zip: IA 50511 Sector: Hydro, Hydrogen Product: The Hydrogen Engine Center (HEC)...

  8. Hydrogen Fuel Quality - Focus: Analytical Methods Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results Hydrogen Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results...

  9. Hydrogen & Our Energy Future | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Future Hydrogen & Our Energy Future DOE overview of hydrogen fuel initiative and hydrogen production, delivery and storate hydrogenenergyfutureweb.pdf More Documents &...

  10. Ultrafine Hydrogen Storage Powders - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Find More Like This Return to Search Ultrafine Hydrogen Storage Powders Ames Laboratory Contact AMES ...

  11. Hydrogen Electrochemical Energy Storage Device - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Find More Like This Return to Search Hydrogen Electrochemical ...

  12. Hydrogen Safety Sensors Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Standards Issues related to Hydrogen Gas Detection Systems, NFPA 52 Hydrogen Sensor Placement Requirements, and the Committee Draft of the ISO TC197 WG13 on Hydrogen Detectors. ...

  13. NREL: Hydrogen and Fuel Cells Research - Hydrogen Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage Storing hydrogen for renewable energy technologies can be challenging, especially for intermittent resources such as solar and wind. Whether for stationary, portable, or transportation applications, cost-effective, high-density energy storage is necessary for enabling the technologies that can change our energy future and reduce greenhouse gas emissions. Hydrogen can play an important role in transforming our energy future if hydrogen storage technologies are improved. With

  14. Hydrogen Fuel Quality - Focus: Analytical Methods Development & Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Quality Results | Department of Energy Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results Hydrogen Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon scs_05_rockward.pdf More Documents & Publications Effects of Impurities on Fuel Cell Performance and

  15. NREL: Hydrogen and Fuel Cells Research - Hydrogen System Component

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation System Component Validation NREL's hydrogen system component validation studies focus on improving the reliability of compressors and other hydrogen system components. Reliable components are needed to ensure the success of hydrogen fueling stations and support the commercial deployment of fuel cell electric vehicles and material handling equipment. NREL's technology validation team is collaborating with industry to test and validate the commercial readiness of hydrogen system

  16. NREL: Hydrogen and Fuel Cells Research - Pathways to Renewable Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Video (Text Version) Pathways to Renewable Hydrogen Video (Text Version) Below is the text version of the Pathways to Renewable Hydrogen video. Voiceover: It is the most plentiful element in the universe and it's a key component in the suite of renewable options needed as we transition to a cleaner, more secure energy strategy. Keith Wipke: Hydrogen is a really important part of the portfolio of our energy in this country. Voiceover: In nature hydrogen is combined with other elements but,

  17. Hydrogen isotope separation

    DOE Patents [OSTI]

    Bartlit, John R. (Los Alamos, NM); Denton, William H. (Abingdon, GB3); Sherman, Robert H. (Los Alamos, NM)

    1982-01-01

    A system of four cryogenic fractional distillation columns interlinked with two equilibrators for separating a DT and hydrogen feed stream into four product streams, consisting of a stream of high purity D.sub.2, DT, T.sub.2, and a tritium-free stream of HD for waste disposal.

  18. Resistive hydrogen sensing element

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN)

    2000-01-01

    Systems and methods are described for providing a hydrogen sensing element with a more robust exposed metallization by application of a discontinuous or porous overlay to hold the metallization firmly on the substrate. An apparatus includes: a substantially inert, electrically-insulating substrate; a first Pd containing metallization deposited upon the substrate and completely covered by a substantially hydrogen-impermeable layer so as to form a reference resistor on the substrate; a second Pd containing metallization deposited upon the substrate and at least a partially accessible to a gas to be tested, so as to form a hydrogen-sensing resistor; a protective structure disposed upon at least a portion of the second Pd containing metallization and at least a portion of the substrate to improve the attachment of the second Pd containing metallization to the substrate while allowing the gas to contact said the second Pd containing metallization; and a resistance bridge circuit coupled to both the first and second Pd containing metallizations. The circuit determines the difference in electrical resistance between the first and second Pd containing metallizations. The hydrogen concentration in the gas may be determined. The systems and methods provide advantages because adhesion is improved without adversely effecting measurement speed or sensitivity.

  19. Detroit Commuter Hydrogen Project

    SciTech Connect (OSTI)

    Brooks, Jerry; Prebo, Brendan

    2010-07-31

    This project was undertaken to demonstrate the viability of using hydrogen as a fuel in an internal combustion engine vehicle for use as a part of a mass transit system. The advantages of hydrogen as a fuel include renew-ability, minimal environmental impact on air quality and the environment, and potential to reduce dependence on foreign energy sources for the transportation sector. Recognizing the potential for the hydrogen fuel concept, the Southeast Michigan Congress of Governments (SEMCOG) determined to consider it in the study of a proposed regional mass transit rail system for southeast Michigan. SEMCOG wanted to evaluate the feasibility of using hydrogen fueled internal combustion engine (H2ICE) vehicles in shuttle buses to connect the Detroit Metro Airport to a proposed, nearby rail station. Shuttle buses are in current use on the airport for passenger parking and inter-terminal transport. This duty cycle is well suited to the application of hydrogen fuel at this time because of the ability to re-fuel vehicles at a single nearby facility, overcoming the challenge of restricted fuel availability in the undeveloped hydrogen fuel infrastructure. A cooperative agreement between SEMCOG and the DOE was initiated and two H2ICE buses were placed in regular passenger service on March 29, 2009 and operated for six months in regular passenger service. The buses were developed and built by the Ford Motor Company. Wayne County Airport Authority provided the location for the demonstration with the airport transportation contractor, Metro Cars Inc. operating the buses. The buses were built on Ford E450 chassis and incorporated a modified a 6.8L V-10 engine with specially designed supercharger, fuel rails and injectors among other sophisticated control systems. Up to 30 kg of on-board gaseous hydrogen were stored in a modular six tank, 350 bar (5000 psi) system to provide a 150 mile driving range. The bus chassis and body were configured to carry nine passengers with luggage. By collecting fuel use data for the two H2ICE buses, with both written driver logs and onboard telemetry devices, and for two conventional propane-gasoline powered buses in the same service, comparisons of operating efficiency and maintenance requirements were completed. Public opinion about the concept of hydrogen fuel was sampled with a rider survey throughout the demonstration. The demonstration was very effective in adding to the understanding of the application of hydrogen as a transportation fuel. The two 9 passenger H2ICE buses accumulated nearly 50,000 miles and carried 14,285 passengers. Data indicated the H2ICE bus fuel economy to be 9.4 miles/ gallon of gasoline equivalent (m/GGE) compared to the 10 passenger propane-gasoline bus average of 9.8 m/GGE over 32,400 miles. The 23- passenger bus averaged 7.4 m/GGE over 40,700 miles. Rider feedback from 1050 on-board survey cards was overwhelmingly positive with 99.6% indicating they would ride again on a hydrogen powered vehicle. Minimal maintenance was required for theses buses during the demonstration project, but a longer duration demonstration would be required to more adequately assess this aspect of the concept.

  20. California Hydrogen Infrastructure Project

    SciTech Connect (OSTI)

    Edward C. Heydorn

    2013-03-12

    Air Products and Chemicals, Inc. has completed a comprehensive, multiyear project to demonstrate a hydrogen infrastructure in California. The specific primary objective of the project was to demonstrate a model of a “real-world” retail hydrogen infrastructure and acquire sufficient data within the project to assess the feasibility of achieving the nation’s hydrogen infrastructure goals. The project helped to advance hydrogen station technology, including the vehicle-to-station fueling interface, through consumer experiences and feedback. By encompassing a variety of fuel cell vehicles, customer profiles and fueling experiences, this project was able to obtain a complete portrait of real market needs. The project also opened its stations to other qualified vehicle providers at the appropriate time to promote widespread use and gain even broader public understanding of a hydrogen infrastructure. The project engaged major energy companies to provide a fueling experience similar to traditional gasoline station sites to foster public acceptance of hydrogen. Work over the course of the project was focused in multiple areas. With respect to the equipment needed, technical design specifications (including both safety and operational considerations) were written, reviewed, and finalized. After finalizing individual equipment designs, complete station designs were started including process flow diagrams and systems safety reviews. Material quotes were obtained, and in some cases, depending on the project status and the lead time, equipment was placed on order and fabrication began. Consideration was given for expected vehicle usage and station capacity, standard features needed, and the ability to upgrade the station at a later date. In parallel with work on the equipment, discussions were started with various vehicle manufacturers to identify vehicle demand (short- and long-term needs). Discussions included identifying potential areas most suited for hydrogen fueling stations with a focus on safe, convenient, fast-fills. These potential areas were then compared to and overlaid with suitable sites from various energy companies and other potential station operators. Work continues to match vehicle needs with suitable fueling station locations. Once a specific site was identified, the necessary agreements could be completed with the station operator and expected station users. Detailed work could then begin on the site drawings, permits, safety procedures and training needs. Permanent stations were successfully installed in Irvine (delivered liquid hydrogen), Torrance (delivered pipeline hydrogen) and Fountain Valley (renewable hydrogen from anaerobic digester gas). Mobile fueling stations were also deployed to meet short-term fueling needs in Long Beach and Placerville. Once these stations were brought online, infrastructure data was collected and reported to DOE using Air Products’ Enterprise Remote Access Monitoring system. Feedback from station operators was incorporated to improve the station user’s fueling experience.

  1. Hydrogen Storage Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    The mission of the Hydrogen Storage Technical Team is to accelerate research and innovation that will lead to commercially viable hydrogen-storage technologies that meet the U.S. DRIVE Partnership goals.

  2. Hydrogen Distribution and Delivery Infrastructure

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen delivery technologies. Intended for a non-technical audience, it explains how hydrogen is transported and delivered today, the challen

  3. High-Pressure Hydrogen Tanks

    Broader source: Energy.gov [DOE]

    Presentation on High-Pressure Hydrogen Tanks for the DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project Review Meeting held February 8-9, 2005 at Argonne National Laboratory

  4. Hydrogen Delivery Infrastructure Options Analysis

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report, by the Nexant team, documents an in-depth analysis of seven hydrogen delivery options to identify the most cost-effective hydrogen infrastructure for the transition and long term. The pro

  5. Oxidation resistant organic hydrogen getters

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Buffleben, George M. (Tracy, CA)

    2008-09-09

    A composition for removing hydrogen from an atmosphere, comprising a mixture of a polyphenyl ether and a hydrogenation catalyst, preferably a precious metal catalyst, and most preferably Pt. This composition is stable in the presence of oxygen, will not polymerize or degrade upon exposure to temperatures in excess of 200.degree. C., or prolonged exposure to temperatures in the range of 100-300.degree. C. Moreover, these novel hydrogen getter materials can be used to efficiently removing hydrogen from mixtures of hydrogen/inert gas (e.g., He, Ar, N.sub.2), hydrogen/ammonia atmospheres, such as may be encountered in heat exchangers, and hydrogen/carbon dioxide atmospheres. Water vapor and common atmospheric gases have no adverse effect on the ability of these getter materials to absorb hydrogen.

  6. Hydrogen Production: Photoelectrochemical Water Splitting

    Broader source: Energy.gov [DOE]

    In photoelectrochemical (PEC) water splitting, hydrogen is produced from water using sunlight and specialized semiconductors called photoelectrochemical materials, which use light energy to directly dissociate water molecules into hydrogen and oxygen.

  7. Hydrogen Materials Advanced Research Consortium

    Broader source: Energy.gov [DOE]

    An overview of the organization and scientific activities of the Hydrogen Materials—Advanced Research Consortium (HyMARC).

  8. Hydrogen Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis Hydrogen Analysis Presentation on Hydrogen Analysis to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of systems analysis in DOE Hydrogen Program. PDF icon 6_h2a_mann.pdf More Documents & Publications H2A Delivery Models and Results H2A Delivery Components Model and Analysis Hydrogen Delivery Analysis Plus Meeting: DTT, STT, HPTT, Other Analysts, Invited Guests

  9. Hydrogen Storage Materials Database Demonstration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Fuel Cell Technologies Program Source: US DOE 4/25/2011 eere.energy.gov Hydrogen Storage Materials Database Demonstration FUEL CELL TECHNOLOGIES PROGRAM Ned Stetson Storage Tech Team Lead Fuel Cell Technologies Program U.S. Department of Energy 12/13/2011 Hydrogen Storage Materials Database Marni Lenahan December 13, 2011 Database Background * The Hydrogen Storage Materials Database was built to retain information from DOE Hydrogen Storage funded research and make these data more accessible. *

  10. Hydrogen storage gets new hope

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen storage gets new hope Hydrogen storage gets new hope A new method for "recycling" hydrogen-containing fuel materials could open the door to economically viable hydrogen-based vehicles. September 1, 2009 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos

  11. Hydrogen Storage Materials Database Demonstration

    Broader source: Energy.gov [DOE]

    Presentation slides from the Fuel Cell Technologies Office webinar "Hydrogen Storage Materials Database Demonstration" held December 13, 2011.

  12. National Hydrogen Learning Demonstration Status

    Broader source: Energy.gov [DOE]

    Presentation slides from the Fuel Cell Technologies Program webinar "National Hydrogen Learning Demonstration Status" held February 6, 2012.

  13. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  14. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  15. HydroGen | Open Energy Information

    Open Energy Info (EERE)

    HydroGen Jump to: navigation, search Logo: HydroGen Name: HydroGen Address: Head Office, 9 GreenMeadows Place: Cardiff, Wales Country: United Kingdom Sector: Hydro, Hydrogen,...

  16. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop: Agenda and Objectives Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop:...

  17. A Photosynthetic Hydrogel for Catalytic Hydrogen Production ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production...

  18. Controlled Hydrogen Fleet and Infrastructure Demonstration and...

    Broader source: Energy.gov (indexed) [DOE]

    tv03veenstra.pdf More Documents & Publications Technology Validation Controlled Hydrogen Fleet & Infrastructure Analysis HYDROGEN TO THE HIGHWAYS...

  19. Controlled Hydrogen Fleet and Infrastructure Demonstration and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project Solicitation Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project...

  20. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis of Photoelectrochemical (PEC) Hydrogen Production Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production This report documents the engineering and cost...

  1. Novel Hydrogen Carriers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery » Novel Hydrogen Carriers Novel Hydrogen Carriers Hydrogen carriers store hydrogen in some other chemical state rather than as free hydrogen molecules. Additional research and analyses are underway to investigate novel liquid or solid hydrogen carriers for use in delivery. Carriers are a unique way to deliver hydrogen by hydriding a chemical compound at the site of production and then dehydriding it either at the point of delivery or once it is onboard the fuel cell vehicle.

  2. Liquid Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery » Liquid Hydrogen Delivery Liquid Hydrogen Delivery Hydrogen is most commonly transported and delivered as a liquid when high-volume transport is needed in the absence of pipelines. To liquefy hydrogen it must be cooled to cryogenic temperatures through a liquefaction process. Trucks transporting liquid hydrogen are referred to as liquid tankers. Liquefaction Gaseous hydrogen is liquefied by cooling it to below -253°C (-423°F). Once hydrogen is liquefied it can be stored at

  3. Solid evacuated microspheres of hydrogen

    DOE Patents [OSTI]

    Turnbull, Robert J. (Urbana, IL); Foster, Christopher A. (Champaign, IL); Hendricks, Charles D. (Livermore, CA)

    1982-01-01

    A method is provided for producing solid, evacuated microspheres comprised of hydrogen. The spheres are produced by forming a jet of liquid hydrogen and exciting mechanical waves on the jet of appropriate frequency so that the jet breaks up into drops with a bubble formed in each drop by cavitation. The drops are exposed to a pressure less than the vapor pressure of the liquid hydrogen so that the bubble which is formed within each drop expands. The drops which contain bubbles are exposed to an environment having a pressure just below the triple point of liquid hydrogen and they thereby freeze giving solid, evacuated spheres of hydrogen.

  4. Hydrogen Storage Fact Sheet | Department of Energy

    Energy Savers [EERE]

    Storage Fact Sheet Hydrogen Storage Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen storage. PDF icon Hydrogen Storage More Documents & Publications US DRIVE Hydrogen Storage Technical Team Roadmap Hydrogen & Our Energy Future Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials

  5. Thermochemical production of hydrogen

    DOE Patents [OSTI]

    Dreyfuss, Robert M.

    1976-07-13

    A thermochemical reaction cycle for the generation of hydrogen from water comprising the following sequence of reactions wherein M represents a metal and Z represents a metalloid selected from the arsenic-antimony-bismuth and selenium-tellurium subgroups of the periodic system: 2MO + Z + SO.sub.2 .fwdarw. MZ + MSO.sub.4 (1) mz + h.sub.2 so.sub.4 .fwdarw. mso.sub.4 + h.sub.2 z (2) 2mso.sub.4 .fwdarw. 2mo + so.sub.2 + so.sub.3 + 1/20.sub.2 (3) h.sub.2 z .fwdarw. z + h.sub.2 (4) h.sub.2 o + so.sub.3 .fwdarw. h.sub.2 so.sub.4 (5) the net reaction is the decomposition of water into hydrogen and oxygen.

  6. Reversible hydrogen storage materials

    DOE Patents [OSTI]

    Ritter, James A. (Lexington, SC); Wang, Tao (Columbia, SC); Ebner, Armin D. (Lexington, SC); Holland, Charles E. (Cayce, SC)

    2012-04-10

    In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

  7. advanced hydrogen storage materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hydrogen storage materials - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  8. National Hydrogen Learning Demonstration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Keith Wipke, Sam Sprik, Jennifer Kurtz, Todd Ramsden, Chris Ainscough, Genevieve Saur February 6, 2012 DOE's Informational Webinar Series National Hydrogen Learning Demonstration Status This presentation does not contain any proprietary, confidential, or otherwise restricted information NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy operated by the Alliance for Sustainable Energy, LLC v8 National Renewable Energy Laboratory 2

  9. Hydrogen Generation for Refineries

    Office of Environmental Management (EM)

    ADVANCED MANUFACTURING OFFICE PEER REVIEW MEETING May 5-6, 2014 DE-FG02-08ER85135 Hydrogen Generation for Refineries DOE Phase II SBIR Dr. Girish Srinivas P.I. gsrinivas@tda.com 303-940-2321 Dr. Steven Gebhard, P.E. Dr. Robert Copeland Mr. Jeff Martin TDA Research Inc. 1 This presentation does not contain any proprietary, confidential, or otherwise restricted information This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Overview *

  10. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D.

    1985-01-01

    The coal liquefaction process disclosed uses three stages. The first stage is a liquefaction. The second and third stages are hydrogenation stages at different temperatures and in parallel or in series. One stage is within 650.degree.-795.degree. F. and optimizes solvent production. The other stage is within 800.degree.-840.degree. F. and optimizes the C.sub.5 -850.degree. F. product.

  11. Polymer formulations for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, T.J.; Whinnery, L.L.

    1998-11-17

    A novel composition is described comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen. 1 fig.

  12. Polymer formulations for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy Jon (Livermore, CA); Whinnery, LeRoy L. (Livermore, CA)

    1998-11-17

    A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

  13. Polymer system for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy Jon (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Whinnery, LeRoy L. (4929 Julie St., Livermore, Alameda County, CA 94550)

    2000-01-01

    A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

  14. Fluoride adsorption on goethite in relation to different types of surface sites

    SciTech Connect (OSTI)

    Hiemstra, T.; Van Riemsdijk, W.H.

    2000-05-01

    Metal (hydr)oxides have different types of surface groups. Fluoride ions have been used as a probe to assess the number of surface sites. The authors have studied the F{sup {minus}} adsorption on goethite by measuring the F{sup {minus}} and H{sup +} interaction and F{sup {minus}} adsorption isotherms. Fluoride ions exchange against singly coordinated surface hydroxyls at low F{sup {minus}} concentrations. At higher concentrations also the doubly coordinated OH groups are involved. The replacement of a surface OH{sup {minus}} by F{sup {minus}} suggests that all F charge ({minus}1) is located at the surface in contrast to oxyanions which have a charge distribution in the interface due to the binding structure in which the anion only partially coordinates with the surface. Analysis of their F{sup {minus}} data with the CD-MUSIC approach shows that the formation of the fluoride surface complex is accompanied by a redistribution of charge. This is supposed to be due to a net switch in the H bonding as a result of the change of the type of surface complex from donating (FeOH, FeOH{sub 2}) to proton accepting (FeF). The modeled redistribution of charge is approximately equivalent with the change of a donating H bond into an accepting H bond. At high F{sup {minus}} concentrations precipitation of F{sup {minus}}, as for instance FeF{sub 3}(s), may occur. The rate of formation is catalyzed by the presence of high electrolyte concentrations.

  15. Anodic activation of niobium and tantalum in phosphate-fluoride solutions

    SciTech Connect (OSTI)

    Bairachnyi, B.I.; Stepanova, I.I.

    1988-01-10

    An analysis of the polarization curves for the anodic dissolution of niobium and tantalum in the coordinates showed they are described by Fafel's equation with a slop of the linear sections of -0.125 for niobium and -0.123 for tantalum. In solutions that contained hydrofluoric acid the anodic-anionic polarization of niobium and tantalum was accompanied by the destruction of the oxide film by the fluoride ions and dissolution of the metal phase. Effects of polishing and glossing of the surface of the investigated metals were observed at certain conditions.

  16. Hydrogen Fuel Pilot Plant and Hydrogen ICE Vehicle Testing

    SciTech Connect (OSTI)

    J. Francfort

    2005-03-01

    The U.S. Department Energy's Advanced Vehicle Testing Activity (AVTA) teamed with Electric Transportation Applications (ETA) and Arizona Public Service (APS) to develop the APS Alternative Fuel (Hydrogen) Pilot Plant that produces and compresses hydrogen on site through an electrolysis process by operating a PEM fuel cell in reverse; natural gas is also compressed onsite. The Pilot Plant dispenses 100% hydrogen, 15 to 50% blends of hydrogen and compressed natural gas (H/CNG), and 100% CNG via a credit card billing system at pressures up to 5,000 psi. Thirty internal combustion engine (ICE) vehicles (including Daimler Chrysler, Ford and General Motors vehicles) are operating on 100% hydrogen and 15 to 50% H/CNG blends. Since the Pilot Plant started operating in June 2002, they hydrogen and H/CNG ICE vehicels have accumulated 250,000 test miles.

  17. NREL: Hydrogen and Fuel Cells Research - Hydrogen Fueling Infrastructure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis Fueling Infrastructure Analysis As the market grows for hydrogen fuel cell electric vehicles, so does the need for a comprehensive hydrogen fueling infrastructure. NREL's technology validation team is analyzing the availability and performance of existing hydrogen fueling stations, benchmarking the current status, and providing feedback related to capacity, utilization, station build time, maintenance, fueling, and geographic coverage. Overview Composite Data Products Publications

  18. NREL: Hydrogen and Fuel Cells Research - Hydrogen Infrastructure Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Research Facility Hydrogen Infrastructure Testing and Research Facility Text Version The Hydrogen Infrastructure Testing and Research Facility (HITRF) at NREL's Energy Systems Integration Facility (ESIF) consists of hydrogen storage, compression, and dispensing capabilities for fuel cell vehicle fueling and component testing. The HITRF is the first facility of its kind in Colorado and will be available to industry for use in research and development activities. In addition to fueling

  19. NREL: Hydrogen and Fuel Cells Research - Hydrogen Production Cost Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Production Cost Analysis NREL analyzed the cost of hydrogen production via wind-based water electrolysis at 42 potential sites in 11 states across the nation. This analysis included centralized plants producing the Department of Energy (DOE) target of 50,000 kg of hydrogen per day, using both wind and grid electricity. The use of wind and grid electricity can be balanced either by power or cost, including or excluding the purchase of peak summer electricity. Current wind incentives-such

  20. DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells Program Record 9017: On-Board Hydrogen Storage Systems - Projected Performance and Cost Parameters DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen Storage ...

  1. NREL: Hydrogen and Fuel Cells Research - Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Basics Photo of vehicle filling up at renewable hydrogen fueling station. NREL's hydrogen fueling station dispenses hydrogen produced via renewable electrolysis. Photo by Dennis Schroeder, NREL NREL researchers are working to unlock the potential of hydrogen as a fuel and to advance fuel cell technologies for automobiles, equipment, and buildings. View the Hydrogen Program video on NREL's YouTube channel to learn more about the basics of NREL's hydrogen and fuel cell

  2. Hydrogen Pipeline Working Group | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pipeline Working Group Hydrogen Pipeline Working Group The Hydrogen Pipeline Working Group of research and industry experts focuses on issues related to the cost, safety, and reliability of hydrogen pipelines. Participants represent organizations conducting hydrogen pipeline research for the Department of Energy to better understand and minimize hydrogen embrittlement and to identify improved and new materials for hydrogen pipelines. Hydrogen Pipeline Working Group Workshops: September 25-26,

  3. Hydrogen Storage - Current Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage - Current Technology Hydrogen Storage - Current Technology Hydrogen storage is a significant challenge for the development and viability of hydrogen-powered vehicles. On-board hydrogen storage in the range of approximately 5-13 kg is required to enable a driving range of greater than 300 miles for the full platform of light-duty automotive vehicles using fuel cell power plants. Hydrogen Storage Technologies Current on-board hydrogen storage approaches involve compressed hydrogen gas

  4. Alternative Fuels Data Center: Hydrogen Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Basics to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Basics on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Basics on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Basics on Google Bookmark Alternative Fuels Data Center: Hydrogen Basics on Delicious Rank Alternative Fuels Data Center: Hydrogen Basics on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Basics on AddThis.com... More in this section... Hydrogen Basics Production

  5. Alternative Fuels Data Center: Hydrogen Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen Related Links to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Related Links on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Related Links on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Related Links on Google Bookmark Alternative Fuels Data Center: Hydrogen Related Links on Delicious Rank Alternative Fuels Data Center: Hydrogen Related Links on

  6. Effect of Phosphate, Fluoride, and Nitrate on Gibbsite Dissolution Rate and Solubility

    SciTech Connect (OSTI)

    Herting, Daniel L.

    2014-01-29

    Laboratory tests have been completed with simulated tank waste samples to investigate the effects of phosphate, fluoride, and nitrate on the dissolution rate and equilibrium solubility of gibbsite in sodium hydroxide solution at 22 and 40{degrees}C. Results are compared to relevant literature data and to computer model predictions. The presence of sodium nitrate (3 M) caused a reduction in the rate of gibbsite dissolution in NaOH, but a modest increase in the equilibrium solubility of aluminum. The increase in solubility was not as large, though, as the increase predicted by the computer model. The presence of phosphate, either as sodium phosphate or sodium fluoride phosphate, had a negligible effect on the rate of gibbsite dissolution, but caused a slight increase in aluminum solubility. The magnitude of the increased solubility, relative to the increase caused by sodium nitrate, suggests that the increase is due to ionic strength (or water activity) effects, rather than being associated with the specific ion involved. The computer model predicted that phosphate would cause a slight decrease in aluminum solubility, suggesting some Al-PO4 interaction. No evidence was found of such an interaction.

  7. Liquid Hydrogen Absorber for MICE

    SciTech Connect (OSTI)

    Ishimoto, S.; Suzuki, S.; Yoshida, M.; Green, Michael A.; Kuno, Y.; Lau, Wing

    2010-05-30

    Liquid hydrogen absorbers for the Muon Ionization Cooling Experiment (MICE) have been developed, and the first absorber has been tested at KEK. In the preliminary test at KEK we have successfully filled the absorber with {approx}2 liters of liquid hydrogen. The measured hydrogen condensation speed was 2.5 liters/day at 1.0 bar. No hydrogen leakage to vacuum was found between 300 K and 20 K. The MICE experiment includes three AFC (absorber focusing coil) modules, each containing a 21 liter liquid hydrogen absorber made of aluminum. The AFC module has safety windows to separate its vacuum from that of neighboring modules. Liquid hydrogen is supplied from a cryocooler with cooling power 1.5 W at 4.2 K. The first absorber will be assembled in the AFC module and installed in MICE at RAL.

  8. Hydrogen ICE Vehicle Testing Activities

    SciTech Connect (OSTI)

    J. Francfort; D. Karner

    2006-04-01

    The Advanced Vehicle Testing Activity teamed with Electric Transportation Applications and Arizona Public Service to develop and monitor the operations of the APS Alternative Fuel (Hydrogen) Pilot Plant. The Pilot Plant provides 100% hydrogen, and hydrogen and compressed natural gas (H/CNG)-blended fuels for the evaluation of hydrogen and H/CNG internal combustion engine (ICE) vehicles in controlled and fleet testing environments. Since June 2002, twenty hydrogen and H/CNG vehicles have accumulated 300,000 test miles and 5,700 fueling events. The AVTA is part of the Department of Energy’s FreedomCAR and Vehicle Technologies Program. These testing activities are managed by the Idaho National Laboratory. This paper discusses the Pilot Plant design and monitoring, and hydrogen ICE vehicle testing methods and results.

  9. Hydrogen Technologies Safety Guide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Technologies Safety Guide C. Rivkin, R. Burgess, and W. Buttner National Renewable Energy Laboratory Technical Report NREL/TP-5400-60948 January 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable Energy, LLC This report is available at no cost from the National Renewable Energy Laboratory (NREL) at www.nrel.gov/publications. Contract No. DE-AC36-08GO28308 National Renewable

  10. hydrogen | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hydrogen Why Coal to Hydrogen Syngas derived from most high pressure gasification processes already contains a significant amount of hydrogen (H2), which can be increased through water gas shift (WGS) and be readily separated into a pure H2 product meeting industry product quality standards. There are several conventional H2 separation processes, but modern installations preferentially choose pressure swing adsorption (PSA), which is a well-proven technology offering high availability and low

  11. Complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2006-08-22

    A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50.degree. C. and 90.degree. C.

  12. Hydrogen Turbines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Turbines Hydrogen Turbines Hydrogen Turbines The Turbines of Tomorrow Combustion (gas) turbines are key components of advanced systems designed for new electric power plants in the United States. With gas turbines, power plants will supply clean, increasingly fuel-efficient, and relatively low-cost energy. Typically, a natural gas-fired combustion turbine-generator operating in a "simple cycle" converts between 25 and 35 percent of the natural gas heating value to useable

  13. Hydrogen embrittlement of structural steels.

    SciTech Connect (OSTI)

    Somerday, Brian P.

    2010-06-01

    Carbon-manganese steels are candidates for the structural materials in hydrogen gas pipelines, however it is well known that these steels are susceptible to hydrogen embrittlement. Decades of research and industrial experience have established that hydrogen embrittlement compromises the structural integrity of steel components. This experience has also helped identify the failure modes that can operate in hydrogen containment structures. As a result, there are tangible ideas for managing hydrogen embrittement in steels and quantifying safety margins for steel hydrogen containment structures. For example, fatigue crack growth aided by hydrogen embrittlement is a key failure mode for steel hydrogen containment structures subjected to pressure cycling. Applying appropriate structural integrity models coupled with measurement of relevant material properties allows quantification of safety margins against fatigue crack growth in hydrogen containment structures. Furthermore, application of these structural integrity models is aided by the development of micromechanics models, which provide important insights such as the hydrogen distribution near defects in steel structures. The principal objective of this project is to enable application of structural integrity models to steel hydrogen pipelines. The new American Society of Mechanical Engineers (ASME) B31.12 design code for hydrogen pipelines includes a fracture mechanics-based design option, which requires material property inputs such as the threshold for rapid cracking and fatigue crack growth rate under cyclic loading. Thus, one focus of this project is to measure the rapid-cracking thresholds and fatigue crack growth rates of line pipe steels in high-pressure hydrogen gas. These properties must be measured for the base materials but more importantly for the welds, which are likely to be most vulnerable to hydrogen embrittlement. The measured properties can be evaluated by predicting the performance of the pipeline using a relevant structural integrity model, such as that in ASME B31.12. A second objective of this project is to enable development of micromechanics models of hydrogen embrittlement in pipeline steels. The focus of this effort is to establish physical models of hydrogen embrittlement in line pipe steels using evidence from analytical techniques such as electron microscopy. These physical models then serve as the framework for developing sophisticated finite-element models, which can provide quantitative insight into the micromechanical state near defects. Understanding the micromechanics of defects can ensure that structural integrity models are applied accurately and conservatively.

  14. High Pressure Hydrogen Tank Manufacturing

    Broader source: Energy.gov [DOE]

    Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop in Washington, DC, August 11-12, 2011.

  15. Hydrogen Embrittlement in Pipeline Steels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - BM Fatigue-probably, yes - Other properties or tests needed? Applied Chemicals & Materials Division Material Measurement Laboratory EXTERNAL CHALLENGES * Hydrogen degradation of ...

  16. hydrogen | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    hydrogen | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy...

  17. Hydrogen fracture toughness tester completion

    SciTech Connect (OSTI)

    Morgan, Michael J.

    2015-09-30

    The Hydrogen Fracture Toughness Tester (HFTT) is a mechanical testing machine designed for conducting fracture mechanics tests on materials in high-pressure hydrogen gas. The tester is needed for evaluating the effects of hydrogen on the cracking properties of tritium reservoir materials. It consists of an Instron Model 8862 Electromechanical Test Frame; an Autoclave Engineering Pressure Vessel, an Electric Potential Drop Crack Length Measurement System, associated computer control and data acquisition systems, and a high-pressure hydrogen gas manifold and handling system.

  18. Catalyzed borohydrides for hydrogen storage

    DOE Patents [OSTI]

    Au, Ming (Augusta, GA)

    2012-02-28

    A hydrogen storage material and process is provided in which alkali borohydride materials are created which contain effective amounts of catalyst(s) which include transition metal oxides, halides, and chlorides of titanium, zirconium, tin, and combinations of the various catalysts. When the catalysts are added to an alkali borodydride such as a lithium borohydride, the initial hydrogen release point of the resulting mixture is substantially lowered. Additionally, the hydrogen storage material may be rehydrided with weight percent values of hydrogen at least about 9 percent.

  19. Hydrogen Equipment Certification Guide Webinar

    Broader source: Energy.gov [DOE]

    Access the recording and download the presentation slides from the Fuel Cell Technologies Office webinar "Hydrogen Equipment Certification Guide" held on December 10, 2015.

  20. Hydrogen Technology Research at SRNL

    SciTech Connect (OSTI)

    Danko, E.

    2011-02-13

    The Savannah River National Laboratory (SRNL) is a U.S. Department of Energy research and development laboratory located at the Savannah River Site (SRS) near Aiken, South Carolina. SRNL has over 50 years of experience in developing and applying hydrogen technology, both through its national defense activities as well as through its recent activities with the DOE Hydrogen Programs. The hydrogen technical staff at SRNL comprises over 90 scientists, engineers and technologists. SRNL has ongoing R&D initiatives in a variety of hydrogen storage areas, including metal hydrides, complex hydrides, chemical hydrides and carbon nanotubes. SRNL has over 25 years of experience in metal hydrides and solid-state hydrogen storage research, development and demonstration. As part of its defense mission at SRS, SRNL developed, designed, demonstrated and provides ongoing technical support for the largest hydrogen processing facility in the world based on the integrated use of metal hydrides for hydrogen storage, separation, and compression. The SRNL has been active in teaming with academic and industrial partners to advance hydrogen technology. A primary focus of SRNL's R&D has been hydrogen storage using metal and complex hydrides. SRNL and its Hydrogen Technology Research Laboratory have been very successful in leveraging their defense infrastructure, capabilities and investments to help solve this country's energy problems. SRNL has participated in projects to convert public transit and utility vehicles for operation using hydrogen fuel. Two major projects include the H2Fuel Bus and an Industrial Fuel Cell Vehicle (IFCV) also known as the GATOR{trademark}. Both of these projects were funded by DOE and cost shared by industry. These are discussed further in Section 3.0, Demonstration Projects. In addition to metal hydrides technology, the SRNL Hydrogen group has done extensive R&D in other hydrogen technologies, including membrane filters for H2 separation, doped carbon nanotubes, storage vessel design and optimization, chemical hydrides, hydrogen compressors and hydrogen production using nuclear energy. Several of these are discussed further in Section 2, SRNL Hydrogen Research and Development.

  1. Hydrogen Knowledge and Opinions Assessment

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  2. Hydrogen Safety: First Responder Education

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  3. Solar Hydrogen Production

    SciTech Connect (OSTI)

    Koval, C.; Sutin, N.; Turner, J.

    1996-09-01

    This panel addressed different methods for the photoassisted dissociation of water into its component parts, hydrogen and oxygen. Systems considered include PV-electrolysis, photoelectrochemical cells, and transition-metal based microheterogeneous and homogeneous systems. While none of the systems for water splitting appear economically viable at the present time, the panel identified areas of basic research that could increase the overall efficiency and decrease the costs. Common to all the areas considered was the underlying belief that the water-to-hydrogen half reaction is reasonably well characterized, while the four-electron oxidation of water-to-oxygen is less well understood and represents a significant energy loss. For electrolysis, research in electrocatalysis to reduce overvoltage losses was identified as a key area for increased efficiency. Non-noble metal catalysts and less expensive components would reduce capital costs. While potentially offering higher efficiencies and lower costs, photoelectrochemical-based direct conversion systems undergo corrosion reactions and often have poor energetics for the water reaction. Research is needed to understand the factors that control the interfacial energetics and the photoinduced corrosion. Multi-photon devices were identified as promising systems for high efficiency conversion.

  4. Hydrogen iodide decomposition

    DOE Patents [OSTI]

    O'Keefe, Dennis R. (San Diego, CA); Norman, John H. (San Diego, CA)

    1983-01-01

    Liquid hydrogen iodide is decomposed to form hydrogen and iodine in the presence of water using a soluble catalyst. Decomposition is carried out at a temperature between about 350.degree. K. and about 525.degree. K. and at a corresponding pressure between about 25 and about 300 atmospheres in the presence of an aqueous solution which acts as a carrier for the homogeneous catalyst. Various halides of the platinum group metals, particularly Pd, Rh and Pt, are used, particularly the chlorides and iodides which exhibit good solubility. After separation of the H.sub.2, the stream from the decomposer is countercurrently extracted with nearly dry HI to remove I.sub.2. The wet phase contains most of the catalyst and is recycled directly to the decomposition step. The catalyst in the remaining almost dry HI-I.sub.2 phase is then extracted into a wet phase which is also recycled. The catalyst-free HI-I.sub.2 phase is finally distilled to separate the HI and I.sub.2. The HI is recycled to the reactor; the I.sub.2 is returned to a reactor operating in accordance with the Bunsen equation to create more HI.

  5. Advanced Hydrogen Turbine Development

    SciTech Connect (OSTI)

    Joesph Fadok

    2008-01-01

    Siemens has developed a roadmap to achieve the DOE goals for efficiency, cost reduction, and emissions through innovative approaches and novel technologies which build upon worldwide IGCC operational experience, platform technology, and extensive experience in G-class operating conditions. In Phase 1, the technologies and concepts necessary to achieve the program goals were identified for the gas turbine components and supporting technology areas and testing plans were developed to mitigate identified risks. Multiple studies were conducted to evaluate the impact in plant performance of different gas turbine and plant technologies. 2015 gas turbine technologies showed a significant improvement in IGCC plant efficiency, however, a severe performance penalty was calculated for high carbon capture cases. Thermodynamic calculations showed that the DOE 2010 and 2015 efficiency targets can be met with a two step approach. A risk management process was instituted in Phase 1 to identify risk and develop mitigation plans. For the risks identified, testing and development programs are in place and the risks will be revisited periodically to determine if changes to the plan are necessary. A compressor performance prediction has shown that the design of the compressor for the engine can be achieved with additional stages added to the rear of the compressor. Tip clearance effects were studied as well as a range of flow and pressure ratios to evaluate the impacts to both performance and stability. Considerable data was obtained on the four candidate combustion systems: diffusion, catalytic, premix, and distributed combustion. Based on the results of Phase 1, the premixed combustion system and the distributed combustion system were chosen as having the most potential and will be the focus of Phase 2 of the program. Significant progress was also made in obtaining combustion kinetics data for high hydrogen fuels. The Phase 1 turbine studies indicate initial feasibility of the advanced hydrogen turbine that meets the aggressive targets set forth for the advanced hydrogen turbine, including increased rotor inlet temperature (RIT), lower total cooling and leakage air (TCLA) flow, higher pressure ratio, and higher mass flow through the turbine compared to the baseline. Maintaining efficiency with high mass flow Syngas combustion is achieved using a large high AN2 blade 4, which has been identified as a significant advancement beyond the current state-of-the-art. Preliminary results showed feasibility of a rotor system capable of increased power output and operating conditions above the baseline. In addition, several concepts were developed for casing components to address higher operating conditions. Rare earth modified bond coat for the purpose of reducing oxidation and TBC spallation demonstrated an increase in TBC spallation life of almost 40%. The results from Phase 1 identified two TBC compositions which satisfy the thermal conductivity requirements and have demonstrated phase stability up to temperatures of 1850 C. The potential to join alloys using a bonding process has been demonstrated and initial HVOF spray deposition trials were promising. The qualitative ranking of alloys and coatings in environmental conditions was also performed using isothermal tests where significant variations in alloy degradation were observed as a function of gas composition. Initial basic system configuration schematics and working system descriptions have been produced to define key boundary data and support estimation of costs. Review of existing materials in use for hydrogen transportation show benefits or tradeoffs for materials that could be used in this type of applications. Hydrogen safety will become a larger risk than when using natural gas fuel as the work done to date in other areas has shown direct implications for this type of use. Studies were conducted which showed reduced CO{sub 2} and NOx emissions with increased plant efficiency. An approach to maximize plant output is needed in order to address the DOE turbine goal for 20-30% reduction o

  6. The hydrogenation of acetylene catalyzed by palladium: Hydrogen pressure dependence

    SciTech Connect (OSTI)

    Molero, H.; Bartlett, B.F.; Tysoe, W.T.

    1999-01-01

    The kinetics of acetylene hydrogenation catalyzed by a clean palladium foil at high pressures are measured and yield an activation energy of 9.6 {+-} 0.1 kcal/mol when using hydrogen. The rate exhibits a deuterium isotope effect such that the reaction activation energy is 9.0 {+-} 0.2 kcal/mol for reaction with deuterium. The hydrogen pressure reaction order is 1.04 {+-} 0.02 at 300 K with an acetylene pressure of 100 Torr and the acetylene order is {minus}0.66 at 300 K and with a hydrogen pressure of 100 Torr. These reaction kinetics closely mimic those of supported model catalysts. In addition, it is found that the rate of benzene formation is accelerated by the addition of hydrogen to the reaction mixture. This is rationalized by proposing that hydrogen enhances the coverage of acetylene under catalytic conditions. This notion can be used to successfully calculate the hydrogen pressure dependence for acetylene hydrogenation as a function of temperature, a value which varies between {approximately}1.05 and 1.3 as the temperature changes from 300 to 380 K. Possible origins for this effect are discussed.

  7. Hydrogen Demand and Resource Analysis (HyDRA) Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    cost and availability, hydrogen production potential, hydrogen production cost, resource consumption, hydrogen demand, infrastructure, and results from integration with other...

  8. Hawaii Hydrogen Energy Park | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hawaii Hydrogen Energy Park Hawaii Hydrogen Energy Park 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon tv_09_rocheleau.pdf More Documents & Publications Hawaii Renewable Hydrogen Program CX-002955: Categorical Exclusion Determination Supporting a Hawaii Hydrogen Economy

  9. Hydrogen Compatible Materials Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compatible Materials Workshop Hydrogen Compatible Materials Workshop Summary of the Hydrogen Compatible Materials Workshop held November, 3, 2010, at Sandia National Laboratories in Livermore, California. Summary includes the workshop agenda, an overview of the morning presentations, a discussion of the afternoon meeting, and a list of participants. PDF icon Hydrogen Compatible Materials Workshop More Documents & Publications Hydrogen Compatibility of Materials Hydrogen Transmission and

  10. Hydrogen Pipeline Discussion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Discussion Hydrogen Pipeline Discussion ASTM T.G. G1.06.08 Goals and Workshop, May 17, 2005. Formed on November 11, 2004. Identify major laboratory facilities and capabilities. PDF icon hpwgw_discission_zawierucha.pdf More Documents & Publications Hydrogen permeability and Integrity of hydrogen transfer pipelines Proceedings of the 2005 Hydrogen Pipeline Working Group Workshop Hydrogen Compatibility of Materials

  11. Hydrogen Release Behavior | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Release Behavior Hydrogen Release Behavior 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon scs_06_moen.pdf More Documents & Publications US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen.PDF Safetygram Gaseous Hydrogen

  12. Hydrogen Safety Panel | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Panel Hydrogen Safety Panel 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon scs_07_weiner.pdf More Documents & Publications Hydrogen Safety: First Responder Education Hydrogen Safety Knowledge Tools NanoCapillary Network Proton Conducting Membranes for High Temperature Hydrogen/Air Fuel Cells

  13. Nuclear Hydrogen R&D Plan

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nuclear Hydrogen R&D Plan March 2004 Nuclear Hydrogen R&D Plan March 2004 Department Of Energy Office of Nuclear Energy, Science and Technology CONTENTS 1. Hydrogen and The Role of Nuclear Energy ................................................................................. 1-1 1.1 The DOE Hydrogen Program ........................................................................................... 1-2 1.2 Energy Sources for Hydrogen - The Nuclear Connection

  14. Hydrogen purifier module with membrane support

    DOE Patents [OSTI]

    A hydrogen purifier utilizing a hydrogen-permeable membrane to purify hydrogen from mixed gases containing hydrogen is disclosed. Improved mechanical support for the permeable membrane is described, enabling forward or reverse differential pressurization of the membrane, which further stabilizes the membrane from wrinkling upon hydrogen uptake.

    2012-07-24

    A hydrogen purifier utilizing a hydrogen-permeable membrane to purify hydrogen from mixed gases containing hydrogen is disclosed. Improved mechanical support for the permeable membrane is described, enabling forward or reverse differential pressurization of the membrane, which further stabilizes the membrane from wrinkling upon hydrogen uptake.

  15. Metal salt catalysts for enhancing hydrogen spillover

    SciTech Connect (OSTI)

    Yang, Ralph T; Wang, Yuhe

    2013-04-23

    A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

  16. BP and Hydrogen Pipelines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BP and Hydrogen Pipelines BP and Hydrogen Pipelines BP Environmental Commitment: Green corporate philosophy and senior management commitment PDF icon hpwgw_bp_yoho.pdf More Documents & Publications Proceedings of the 2005 Hydrogen Pipeline Working Group Workshop EIS-0018: Final Environmental Impact Statement Hydrogen permeability and Integrity of hydrogen transfer pipelines

  17. Hydrogen Production Fact Sheet | Department of Energy

    Energy Savers [EERE]

    Production Fact Sheet Hydrogen Production Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen production. PDF icon Hydrogen Production More Documents & Publications Hydrogen Production Technical Team Roadmap US DRIVE Hydrogen Production Technical Team Roadmap FTA - SunLine Transit Agency - Final Report

  18. Hydrogen Sensor Workshop Agenda | Department of Energy

    Office of Environmental Management (EM)

    Sensor Workshop Agenda Hydrogen Sensor Workshop Agenda Agenda for the Hydrogen Sensor Workshop held June 8, 2011, in Chicago, Illinois.The workshop was hosted by the U.S. Department of Energy's National Renewable Energy Laboratory. PDF icon Hydrogen Sensor Workshop Agenda More Documents & Publications Hydrogen Codes and Standards and Permitting Hydrogen Safety Sensors 2012 Smart Grid Peer Review

  19. 2014 Hydrogen Student Design Contest to Design Drop-In Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Hydrogen Student Design Contest to Design Drop-In Hydrogen Fueling Station 2014 Hydrogen Student Design Contest to Design Drop-In Hydrogen Fueling Station December 16, 2013 - ...

  20. Hydrogen and OUr Energy Future

    SciTech Connect (OSTI)

    Rick Tidball; Stu Knoke

    2009-03-01

    In 2003, President George W. Bush announced the Hydrogen Fuel Initiative to accelerate the research and development of hydrogen, fuel cell, and infrastructure technologies that would enable hydrogen fuel cell vehicles to reach the commercial market in the 2020 timeframe. The widespread use of hydrogen can reduce our dependence on imported oil and benefit the environment by reducing greenhouse gas emissions and criteria pollutant emissions that affect our air quality. The Energy Policy Act of 2005, passed by Congress and signed into law by President Bush on August 8, 2005, reinforces Federal government support for hydrogen and fuel cell technologies. Title VIII, also called the 'Spark M. Matsunaga Hydrogen Act of 2005' authorizes more than $3.2 billion for hydrogen and fuel cell activities intended to enable the commercial introduction of hydrogen fuel cell vehicles by 2020, consistent with the Hydrogen Fuel Initiative. Numerous other titles in the Act call for related tax and market incentives, new studies, collaboration with alternative fuels and renewable energy programs, and broadened demonstrations--clearly demonstrating the strong support among members of Congress for the development and use of hydrogen fuel cell technologies. In 2006, the President announced the Advanced Energy Initiative (AEI) to accelerate research on technologies with the potential to reduce near-term oil use in the transportation sector--batteries for hybrid vehicles and cellulosic ethanol--and advance activities under the Hydrogen Fuel Initiative. The AEI also supports research to reduce the cost of electricity production technologies in the stationary sector such as clean coal, nuclear energy, solar photovoltaics, and wind energy.

  1. Infinity Fuel Cell and Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search Name: Infinity Fuel Cell and Hydrogen Place: Suffield, Connecticut Zip: 6078 Sector: Hydro, Hydrogen Product: A team of fuel cell, hydrogen and...

  2. Hydrogen Production: Natural Gas Reforming

    Broader source: Energy.gov [DOE]

    Natural gas reforming is an advanced and mature production process that builds upon the existing natural gas pipeline delivery infrastructure. Today, 95% of the hydrogen produced in the United States is made by natural gas reforming in large central plants. This is an important technology pathway for near-term hydrogen production.

  3. AN EXPERIMENT TO STUDY PEBBLE BED LIQUID-FLUORIDE-SALT HEAT TRANSFER

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Aaron, Adam M; Heatherly, Dennis Wayne; Holcomb, David Eugene; Kisner, Roger A; McCarthy, Mike; Peretz, Fred J; Wilgen, John B; Wilson, Dane F

    2011-01-01

    A forced-convection liquid-fluoride-salt loop is being constructed at Oak Ridge National Laboratory (ORNL). This loop was designed as a versatile experimental facility capable of supporting general thermal/fluid/corrosion testing of liquid fluoride salts. The initial test configuration is designed to support the Pebble Bed Advanced High-Temperature Reactor and incorporates a test section designed to examine the heat transfer behavior of FLiNaK salt in a heated pebble bed. The loop is constructed of Inconel 600 and is capable of operating at up to 700oC. It contains a total of 72 kg of FLiNaK salt and uses an overhung impeller centrifugal sump pump that can provide FLiNaK flow at 4.5 kg/s with a head of 0.125 MPa. The test section is made of silicon carbide (SiC) and contains approximately 600 graphite spheres, 3 cm in diameter. The pebble bed is heated using a unique inductive technique. A forced induction air cooler removes the heat added to the pebble bed. The salt level within the loop is maintained by controlling an argon cover gas pressure. Salt purification is performed in batch mode by transferring the salt from the loop into a specially made nickel crucible system designed to remove oxygen, moisture and other salt impurities. Materials selection for the loop and test section material was informed by 3 months of Inconel 600 and SiC corrosion testing as well as tests examining subcomponent performance in the salt. Several SiC-to-Inconel 600 mechanical joint designs were considered before final salt and gas seals were chosen. Structural calculations of the SiC test section were performed to arrive at a satisfactory test section configuration. Several pump vendors provided potential loop pump designs; however, because of cost, the pump was designed and fabricated in-house. The pump includes a commercial rotating dry gas shaft seal to maintain loop cover gas inventory. The primary instrumentation on the loop includes temperature, pressure, and loop flow rate measurement. Although techniques for all these measurements have improved, no commercial instrumentation was available for flow and pressure measurement that had been tested under these conditions. Instrumentation was tested and modified to meet both corrosion and temperature requirements. This paper discusses the issues encountered during the design and construction of the ORNL Liquid Salt Loop and should prove useful to those contemplating construction of similar high-temperature liquid-fluoride-salt facilities.

  4. A nanosized hydrogen generator | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen in H2O to produce free hydrogen. The commercial separation process uses natural gas to react with superheated steam to strip away hydrogen atoms producing hydrogen fuel,...

  5. Template:Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search This is the Hydrogen template. It is used to embed a custom Hydrogen banner, typically across the top of the page, which features a unique blue...

  6. High capacity hydrogen storage nanocomposite materials

    DOE Patents [OSTI]

    Zidan, Ragaiy; Wellons, Matthew S

    2015-02-03

    A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about 270.degree. C.

  7. Fluoride Salt-Cooled High-Temperature Reactor Technology Development and Demonstration Roadmap

    SciTech Connect (OSTI)

    Holcomb, David Eugene; Flanagan, George F; Mays, Gary T; Pointer, William David; Robb, Kevin R; Yoder Jr, Graydon L

    2013-11-01

    Fluoride salt-cooled High-temperature Reactors (FHRs) are an emerging reactor class with potentially advantageous performance characteristics, and fully passive safety. This roadmap describes the principal remaining FHR technology challenges and the development path needed to address the challenges. This roadmap also provides an integrated overview of the current status of the broad set of technologies necessary to design, evaluate, license, construct, operate, and maintain FHRs. First-generation FHRs will not require any technology breakthroughs, but do require significant concept development, system integration, and technology maturation. FHRs are currently entering early phase engineering development. As such, this roadmap is not as technically detailed or specific as would be the case for a more mature reactor class. The higher cost of fuel and coolant, the lack of an approved licensing framework, the lack of qualified, salt-compatible structural materials, and the potential for tritium release into the environment are the most obvious issues that remain to be resolved.

  8. Detailed optical characterization of a near diffraction limited xenon fluoride laser

    SciTech Connect (OSTI)

    Londono, C. ); Smith, M.J.; Trainor, D.W.; Itzkan, I. ); Berggren, R. ); Fulghum, S.F. )

    1988-12-01

    A 1 m gain length, electron beam pumped xenon fluoride laser (lambda = 353, 351 nm) utilizing two laser mixtures of lean and rich NF/sub 3/, with Xe and balance Ne, was operated with a confocal unstable resonator with magnification of 2.24. The resultant beam quality was diagnosed with both shearing interferometry to measure near-field phase and far-field focal spot evaluation techniques. These measurements resulted in a beam quality of <1.15 times the diffraction limit with no evidence of the wide angle energy loss. This laser device was fully characterized with regard to electron beam deposition uniformity, transient refractive index effects, and optical quality of the resonator and diagnostic components.

  9. Rare earth/iron fluoride and methods for making and using same

    DOE Patents [OSTI]

    Schmidt, Frederick A. (Ames, IA); Wheelock, John T. (Neveda, IA); Peterson, David T. (Ames, IA)

    1991-12-17

    A particulate mixture of Fe.sub.2 O.sub.3 and RE.sub.2 O.sub.3, where RE is a rare earth element, is reacted with an excess of HF acid to form an insoluble fluoride compound (salt) comprising REF.sub.3 and FeF.sub.3 present in solid solution in the REF.sub.3 crystal lattice. The REF.sub.3 /FeF.sub.3 compound is dried to render it usable as a reactant in the thermite reduction process as well as other processes which require an REF.sub.3 /FeF.sub.3 mixture. The dried REF.sub.3 /FeF.sub.3 compound comprises about 5 weight % to about 40 weight % of FeF.sub.3 and the balance REF.sub.3 to this end.

  10. NREL: Transportation Research - Transportation and Hydrogen Newsletter:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Technology Hydrogen and Fuel Cell Technology This is the May 2015 issue of the Transportation and Hydrogen Newsletter. May 28, 2015 Photo of a car refueling at a hydrogen dispensing station. DOE's H2FIRST project focuses on accelerating the acceptance of hydrogen infrastructure. Photo by John De La Rosa, NREL 33660 New H2FIRST Reports Detail Hydrogen Station Designs, Contaminant Detection Two new reports have been published by NREL and Sandia National Laboratories

  11. Hydrogen Delivery Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Roadmap Hydrogen Delivery Roadmap The mission of the Hydrogen Delivery Technical Team (HDTT) is to enable the development of hydrogen delivery technologies, which will allow for fuel cell competitiveness with gasoline and hybrid technologies by achieving an as-produced, delivered, and dispensed hydrogen cost of $2-$4 per gallon of gasoline equivalent of hydrogen. PDF icon hdtt_roadmap_june2013.pdf More Documents & Publications US DRIVE Hydrogen Delivery Technical Team Roadmap Delivery Tech

  12. Gaseous Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery Gaseous Hydrogen Delivery Gaseous hydrogen is most commonly delivered either by trucks or through pipelines. Because gaseous hydrogen is typically produced at relatively low pressures (20-30 bar), it must be compressed prior to transport. Learn more about gaseous hydrogen compression. Trucks that haul gaseous hydrogen are called tube trailers. Gaseous hydrogen is compressed to pressures of 180 bar (~2,600 psig) or higher into long cylinders which are stacked on the trailer that the

  13. Hydrogen Delivery Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery Related Links Hydrogen Delivery Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen delivery activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Delivery Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and

  14. Hydrogen Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Hydrogen & Fuel Cells » Hydrogen Fuel Basics Hydrogen Fuel Basics August 14, 2013 - 2:06pm Addthis Hydrogen is a clean fuel that, when consumed, produces only water. Hydrogen can be produced from a variety of domestic sources, such as coal, natural gas, nuclear power, and renewable power. These qualities make it an attractive fuel option for transportation and electricity generation applications. Hydrogen is an energy carrier that can be used to store, move, and deliver

  15. Hydrogen Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicles & Fuels » Fuels » Hydrogen Fuel Basics Hydrogen Fuel Basics August 19, 2013 - 5:45pm Addthis Hydrogen (H2) is a potentially emissions-free alternative fuel that can be produced from domestic resources. Although not widely used today as a transportation fuel, government and industry research and development are working toward the goal of clean, economical, and safe hydrogen production and hydrogen-powered fuel cell vehicles. Hydrogen is the simplest and most abundant element in the

  16. Hydrogen Tube Trailers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery » Gaseous Hydrogen » Hydrogen Tube Trailers Hydrogen Tube Trailers Trucks that haul gaseous hydrogen are called tube trailers. Gaseous hydrogen is compressed to pressures of 180 bar (~2,600 psig) or higher into long cylinders that are stacked on a trailer that the truck hauls. This gives the appearance of long tubes, hence the name tube trailer. Tube trailers are currently limited to pressures of 250 bar by U.S. Department of Transportation (DOT) regulations. Steel tube

  17. Alternative Fuels Data Center: Hydrogen Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Google Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Delicious Rank Alternative Fuels Data Center: Hydrogen Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fueling Stations

  18. California National Guard Sustainability Planning, Hydrogen Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Guard Sustainability Planning, Hydrogen Fuel Goals California National Guard Sustainability Planning, Hydrogen Fuel Goals Overview of California Guard Army Facilities, ANG ...

  19. Potential Strategies for Integrating Solar Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis Webinar Potential Strategies for Integrating Solar Hydrogen Production and ...

  20. Combinatorial Approaches for Hydrogen Storage Materials (presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Materials R&D Workshop Hydrogen Storage Lab PI Workshop: HyMARC and NREL-Led Characterization Effort Combinatorial Approach for Hydrogen Storage Materials...

  1. Autofermentative Biological Hydrogen Production by Cyanobacteria...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Hydrogen Production by Cyanobacteria Presentation by Charles Dismukes, Rutgers University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at...

  2. Maximizing Light Utilization Efficiency and Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon iih1melis.pdf More Documents & Publications Webinar: Photosynthesis for Hydrogen and Fuels Production Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 ...

  3. National Hydrogen Storage Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Hydrogen Storage Project National Hydrogen Storage Project In July 2003, the Department of Energy (DOE) issued a "Grand Challenge" to the global scientific community for...

  4. AVTA: Hydrogen Internal Combustion Engine Vehicle Specifications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Internal Combustion Engine Vehicle Specifications and Test Procedures AVTA: Hydrogen Internal Combustion Engine Vehicle Specifications and Test Procedures PDF icon HICEV ...

  5. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    is a promising renewable energy technology for generation of hydrogen for use in the future hydrogen economy. PEC systems use solar photons to generate a voltage in an...

  6. Dense, layered membranes for hydrogen separation

    DOE Patents [OSTI]

    Roark, Shane E.; MacKay, Richard; Mundschau, Michael V.

    2006-02-21

    This invention provides hydrogen-permeable membranes for separation of hydrogen from hydrogen-containing gases. The membranes are multi-layer having a central hydrogen-permeable layer with one or more catalyst layers, barrier layers, and/or protective layers. The invention also relates to membrane reactors employing the hydrogen-permeable membranes of the invention and to methods for separation of hydrogen from a hydrogen-containing gas using the membranes and reactors. The reactors of this invention can be combined with additional reactor systems for direct use of the separated hydrogen.

  7. Natural Gas and Hydrogen Infrastructure Opportunities Workshop...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities Workshop Agenda Natural Gas and Hydrogen Infrastructure Opportunities Workshop Agenda Agenda for the Natural Gas and Hydrogen Infrastructure Opportunities Workshop...

  8. Final Report - Hydrogen Delivery Infrastructure Options Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report - Hydrogen Delivery Infrastructure Options Analysis Final Report - Hydrogen Delivery Infrastructure Options Analysis This report, by the Nexant team, documents an in-depth...

  9. Materials Solutions for Hydrogen Delivery in Pipelines

    Office of Energy Efficiency and Renewable Energy (EERE)

    Overall goal of the project is to develop materials technologies that would enable minimizing the problem of hydrogen embrittlement associated with the high-pressure transport of hydrogen

  10. High-Pressure Hydrogen Tank Testing

    Broader source: Energy.gov [DOE]

    Many types of compressed hydrogen tanks have been certified worldwide and demonstrated in several prototype fuel cell vehicles. The following information discusses high-pressure hydrogen tank...

  11. Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon...

    Office of Scientific and Technical Information (OSTI)

    Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon Solar Cells: Preprint Bolen, M. L.; Grover, S.; Teplin, C. W.; Bobela, D.; Branz, H. M.; Stradins, P. 08 HYDROGEN; 14...

  12. International Hydrogen Infrastructure Challenges Workshop Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - NOW, NEDO, and DOE Webinar Slides More Documents & Publications Introduction to SAE Hydrogen Fueling Standardization Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling...

  13. Hydrogen, Fuel Cells and Infrastructure Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program FY2003 Merit Review and Peer Evaluation Report Hydrogen, Fuel Cells and ... U.S. Department of Energy Hydrogen, Fuel Cells and Infrastructure Technologies Program FY ...

  14. Hydrogen, Fuel Cells and Infrastructure Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program: 2002 Annual Progress Report Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report The Department of Energy's Hydrogen, Fuel Cells and ...

  15. Hydrogen Delivery Infrastructure Analysis, Options and Trade...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project Review ... DOE Hydrogen Delivery Analysis and High Pressure Tanks R&D Project Review Meeting ...

  16. Controlled Hydrogen Fleet and Infrastructure Demonstration and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project Citation Details In-Document Search Title: Controlled Hydrogen Fleet and Infrastructure...

  17. American Hydrogen Corporation | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Corporation Jump to: navigation, search Name: American Hydrogen Corporation Address: OU Innovation Center, 340 W State St. Unit 40 Place: Athens, Ohio Zip: 45701 Sector:...

  18. Hydrogen Fuel Initiative | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Fuel Initiative Jump to: navigation, search Contents 1 Introduction 2 Cost 3 Hydrogen Production Strategy 4 Objectives 5 Manufacturing Challenges 6 References Introduction...

  19. 2013 Biological Hydrogen Production Workshop Summary Report ...

    Broader source: Energy.gov (indexed) [DOE]

    summary report for the 2013 Biological Hydrogen Production Workshop. bioh2workshopfinalreport.pdf More Documents & Publications The Hydrogen Program at NREL: A Brief Overview...

  20. An Introduction to the Hydrogen Program

    SciTech Connect (OSTI)

    2015-09-09

    This MP3 provides an overview of the Hydrogen Program and the benefits and challenges to the widespread use of hydrogen and fuel cells.

  1. Where's the Hydrogen Economy? | Open Energy Information

    Open Energy Info (EERE)

    Where's the Hydrogen Economy? Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Where's the Hydrogen Economy? AgencyCompany Organization: Canada Library of Parliament...

  2. Molecular catalytic hydrogenation of aromatic hydrocarbons and...

    Office of Scientific and Technical Information (OSTI)

    hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Citation Details In-Document Search Title: Molecular catalytic hydrogenation of aromatic hydrocarbons and...

  3. Transportation and Stationary Power Integration with Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with Hydrogen and Fuel Cell Technology in Connecticut Transportation and Stationary Power Integration with Hydrogen and Fuel Cell Technology in Connecticut Overview of strengths, ...

  4. Hawaii Renewable Hydrogen Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Hydrogen Program Hawaii Renewable Hydrogen Program Presented at the State and Regional Initiatives Webinar, October 14, 2009 PDF icon hawaiirenewablehydrogenprogram....

  5. NREL Dedicates Advanced Hydrogen Fueling Station | Community...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Dedicates Advanced Hydrogen Fueling Station Ceremony Coincides With National Hydrogen and Fuel Cell Day October 8, 2015 The Energy Department's National Renewable Energy...

  6. Renewable Hydrogen Production from Biological Systems

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Production from Biological Systems Matthew Posewitz Colorado School of Mines DOE Biological Hydrogen Production Workshop September 24 th , 2013 H 2 production PSIIPSI...

  7. Hydrogen for Energy Storage Analysis Overview (Presentation)

    SciTech Connect (OSTI)

    Steward, D. M.; Ramsden, T.; Harrison, K.

    2010-06-01

    Overview of hydrogen for energy storage analysis presented at the National Hydrogen Association Conference & Expo, May 3-6, 2010, Long Beach, CA.

  8. Hydrogen Fuel Cells and Electric Forklift Trucks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Key Assumptions * Average battery change time 10 minutes - Includes occasional queue * Range of hydrogen fill time 2 - 4 minutes - If hydrogen fill rate 0.4 kgmin * ...

  9. Hydrogenases and Barriers for Biotechnological Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Barriers for Biotechnological Hydrogen Production Technologies Presentation by John Peters, Montana State University, at the Biological Hydrogen Production Workshop held...

  10. Microchannel Reactor System for Catalytic Hydrogenation

    SciTech Connect (OSTI)

    2004-07-01

    Energy-Efficient Catalytic Hydrogenation Reactions. Hydrogenation reactions are very versatile and account for 10% to 20% of all reactions in the pharmaceutical industry.

  11. Prediction of Novel Hydrogen Storage Reactions

    Broader source: Energy.gov [DOE]

    This presentation on the Prediction of Novel Hydrogen Storage Reactions was given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  12. Reorientation of the free OH group in the top-most layer of air/water interface of sodium fluoride aqueous solution probed with sum-frequency generation vibrational spectroscopy

    SciTech Connect (OSTI)

    Feng, Ran-Ran; Guo, Yuan; Wang, Hongfei

    2014-09-17

    Many experimental and theoretical studies have established the specific anion, as well as cation effects on the hydrogen-bond structures at the air/water interface of electrolyte solutions. However, the ion effects on the top-most layer of the air/water interface, which is signified by the non-hydrogen-bonded so-called free O-H group, has not been discussed or studied. In this report, we present the measurement of changes of the orientational angle of the free O-H group at the air/water interface of the sodium fluoride (NaF) solutions at different concentrations using the interface selective sum-frequency generation vibrational spectroscopy (SFG-VS) in the ssp and ppp polarizations. The polarization dependent SFG-VS results show that the average tilt angle of the free O-H changes from about 35.3 degrees 0.5 degrees to 43.4 degrees 2.1degrees as the NaF concentration increase from 0 to 0.94M (nearly saturated). Such tilt angle change is around the axis of the other O-H group of the same water molecule at the top-most layer at the air/water interface that is hydrogen-bonded to the water molecules below the top-most layer. These results provide quantitative molecular details of the ion effects of the NaF salt on the structure of the water molecules at the top-most layer of the air/water interfacial, even though both the Na+ cation and the F- anion are believed to be among the most excluded ions from the air/water interface.

  13. Hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S.; Niemann, Michael U.; Goswami, D. Yogi; Stefanakos, Elias K.

    2012-04-10

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  14. Technical Analysis of Hydrogen Production

    SciTech Connect (OSTI)

    Ali T-Raissi

    2005-01-14

    The aim of this work was to assess issues of cost, and performance associated with the production and storage of hydrogen via following three feedstocks: sub-quality natural gas (SQNG), ammonia (NH{sub 3}), and water. Three technology areas were considered: (1) Hydrogen production utilizing SQNG resources, (2) Hydrogen storage in ammonia and amine-borane complexes for fuel cell applications, and (3) Hydrogen from solar thermochemical cycles for splitting water. This report summarizes our findings with the following objectives: Technoeconomic analysis of the feasibility of the technology areas 1-3; Evaluation of the hydrogen production cost by technology areas 1; and Feasibility of ammonia and/or amine-borane complexes (technology areas 2) as a means of hydrogen storage on-board fuel cell powered vehicles. For each technology area, we reviewed the open literature with respect to the following criteria: process efficiency, cost, safety, and ease of implementation and impact of the latest materials innovations, if any. We employed various process analysis platforms including FactSage chemical equilibrium software and Aspen Technologies AspenPlus and HYSYS chemical process simulation programs for determining the performance of the prospective hydrogen production processes.

  15. Solar hydrogen for urban trucks

    SciTech Connect (OSTI)

    Provenzano, J.: Scott, P.B.; Zweig, R.

    1997-12-31

    The Clean Air Now (CAN) Solar Hydrogen Project, located at Xerox Corp., El Segundo, California, includes solar photovoltaic powered hydrogen generation, compression, storage and end use. Three modified Ford Ranger trucks use the hydrogen fuel. The stand-alone electrolyzer and hydrogen dispensing system are solely powered by a photovoltaic array. A variable frequency DC-AC converter steps up the voltage to drive the 15 horsepower compressor motor. On site storage is available for up to 14,000 standard cubic feet (SCF) of solar hydrogen, and up to 80,000 SCF of commercial hydrogen. The project is 3 miles from Los Angeles International airport. The engine conversions are bored to 2.9 liter displacement and are supercharged. Performance is similar to that of the Ranger gasoline powered truck. Fuel is stored in carbon composite tanks (just behind the driver`s cab) at pressures up to 3600 psi. Truck range is 144 miles, given 3600 psi of hydrogen. The engine operates in lean burn mode, with nil CO and HC emissions. NO{sub x} emissions vary with load and rpm in the range from 10 to 100 ppm, yielding total emissions at a small fraction of the ULEV standard. Two trucks have been converted for the Xerox fleet, and one for the City of West Hollywood. A public outreach program, done in conjunction with the local public schools and the Department of Energy, introduces the local public to the advantages of hydrogen fuel technologies. The Clean Air Now program demonstrates that hydrogen powered fleet development is an appropriate, safe, and effective strategy for improvement of urban air quality, energy security and avoidance of global warming impact. Continued technology development and cost reduction promises to make such implementation market competitive.

  16. Project Profile: Thermochemical Storage with Anhydrous Ammonia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    One of the key aims of the research is to design and build a synthesis reactor that is optimized for the direct production of supercritical steam at 650C. Approach Ammonia ...

  17. Insight into hydrogenation of graphene: Effect of hydrogen plasma chemistry

    SciTech Connect (OSTI)

    Felten, A.; Nittler, L.; Pireaux, J.-J.; McManus, D.; Rice, C.; Casiraghi, C.

    2014-11-03

    Plasma hydrogenation of graphene has been proposed as a tool to modify the properties of graphene. However, hydrogen plasma is a complex system and controlled hydrogenation of graphene suffers from a lack of understanding of the plasma chemistry. Here, we correlate the modifications induced on monolayer graphene studied by Raman spectroscopy with the hydrogen ions energy distributions obtained by mass spectrometry. We measure the energy distribution of H{sup +}, H{sub 2}{sup +}, and H{sub 3}{sup +} ions for different plasma conditions showing that their energy strongly depends on the sample position, pressure, and plasma power and can reach values as high as 45?eV. Based on these measurements, we speculate that under specific plasma parameters, protons should possess enough energy to penetrate the graphene sheet. Therefore, a graphene membrane could become, under certain conditions, transparent to both protons and electrons.

  18. NREL: Hydrogen and Fuel Cells Research - Hydrogen Fuel Cell Electric

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicle Learning Demonstration Fuel Cell Electric Vehicle Learning Demonstration Delve deeper into real-world performance data with our Interactive Composite Data Product demo Graphical thumbnail of the Interactive Composite Data Product demo map. Learn More Subscribe to the biannual Fuel Cell and Hydrogen Technology Validation newsletter, which highlights recent technology validation activities at NREL. Initiated in 2004, DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and

  19. Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Scheele, Randall D.; Casella, Andrew M.

    2010-09-28

    This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

  20. Fiber optic hydrogen sensor

    DOE Patents [OSTI]

    Buchanan, Bruce R.; Prather, William S.

    1992-01-01

    An apparatus and method for detecting a chemical substance by exposing an optic fiber having a core and a cladding to the chemical substance so that the chemical substance can be adsorbed onto the surface of the cladding. The optic fiber is coiled inside a container having a pair of valves for controlling the entrance and exit of the substance. Light from a light source is received by one end of the optic fiber, preferably external to the container, and carried by the core of the fiber. Adsorbed substance changes the transmissivity of the fiber as measured by a spectrophotometer at the other end, also preferably external to the container. Hydrogen is detected by the absorption of infrared light carried by an optic fiber with a silica cladding. Since the adsorption is reversible, a sensor according to the present invention can be used repeatedly. Multiple positions in a process system can be monitored using a single container that can be connected to each location to be monitored so that a sample can be obtained for measurement, or, alternatively, containers can be placed near each position and the optic fibers carrying the partially-absorbed light can be multiplexed for rapid sequential reading by a single spectrophotometer.

  1. Fiber optic hydrogen sensor

    DOE Patents [OSTI]

    Buchanan, B.R.; Prather, W.S.

    1991-01-01

    Apparatus and method for detecting a chemical substance by exposing an optic fiber having a core and a cladding to the chemical substance so that the chemical substance can be adsorbed onto the surface of the cladding. The optic fiber is coiled inside a container having a pair of valves for controlling the entrance and exit of the substance. Light from a light source is received by one end of the optic fiber, preferably external to the container, and carried by the core of the fiber. Adsorbed substance changes the transmissivity of the fiber as measured by a spectrophotometer at the other end, also preferably external to the container. Hydrogen is detected by the absorption of infrared light carried by an optic fiber with a silica cladding. Since the adsorption is reversible, a sensor according to the present invention can be used repeatedly. Multiple positions in a process system can be monitored using a single container that can be connected to each location to be monitored so that a sample can be obtained for measurement, or, alternatively, containers can be placed near each position and the optic fibers carrying the partially-absorbed light can be multiplexed for rapid sequential reading, by a single spectrophotometer.

  2. Fiber optic hydrogen sensor

    DOE Patents [OSTI]

    Buchanan, B.R.; Prather, W.S.

    1992-10-06

    An apparatus and method are described for detecting a chemical substance by exposing an optic fiber having a core and a cladding to the chemical substance so that the chemical substance can be adsorbed onto the surface of the cladding. The optic fiber is coiled inside a container having a pair of valves for controlling the entrance and exit of the substance. Light from a light source is received by one end of the optic fiber, preferably external to the container, and carried by the core of the fiber. Adsorbed substance changes the transmissivity of the fiber as measured by a spectrophotometer at the other end, also preferably external to the container. Hydrogen is detected by the absorption of infrared light carried by an optic fiber with a silica cladding. Since the adsorption is reversible, a sensor according to the present invention can be used repeatedly. Multiple positions in a process system can be monitored using a single container that can be connected to each location to be monitored so that a sample can be obtained for measurement, or, alternatively, containers can be placed near each position and the optic fibers carrying the partially-absorbed light can be multiplexed for rapid sequential reading by a single spectrophotometer. 4 figs.

  3. Hydrogen Production: Fundamentals and Case Study Summaries (Presentation)

    SciTech Connect (OSTI)

    Harrison, K.; Remick, R.; Hoskin, A.; Martin, G.

    2010-05-19

    This presentation summarizes hydrogen production fundamentals and case studies, including hydrogen to wind case studies.

  4. Overview of Hydrogen and Fuel Cell Activities: 6th International Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fuel Cell Expo | Department of Energy 6th International Hydrogen and Fuel Cell Expo Overview of Hydrogen and Fuel Cell Activities: 6th International Hydrogen and Fuel Cell Expo This presentation by DOE's Sunita Satyapal was given at the 6th International Hydrogen and Fuel Cell Expo on March 3, 2010. PDF icon Overview of Hydrogen and Fuel Cell Activities More Documents & Publications Hydrogen and Fuel Cells Program Overview: Hydrogen and Fuel Cells 2011 International Conference Fuel

  5. U.S. DOE Hydrogen and Fuel Cell Activities: 2010 International Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel and Pressure Vessel Forum | Department of Energy DOE Hydrogen and Fuel Cell Activities: 2010 International Hydrogen Fuel and Pressure Vessel Forum U.S. DOE Hydrogen and Fuel Cell Activities: 2010 International Hydrogen Fuel and Pressure Vessel Forum Presentation at the International Hydrogen Fuel and Pressure Vessel Forum on September 27-29, 2010, in Beijing, China. PDF icon U.S. DOE Hydrogen and Fuel Cell Activities More Documents & Publications DOE Hydrogen and Fuel Cell Overview:

  6. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay Keller of Sandia National Laboratories at the CNG and Hydrogen Lessons Learned Workshop on December 10, 2009 PDF icon cng_h2_workshop_2_keller.pdf More Documents & Publications US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen Release Behavior Workshop Notes from

  7. Hydrogen Technology Education Workshop Proceedings

    Fuel Cell Technologies Publication and Product Library (EERE)

    This document outlines activities for educating key target audiences, as suggested by workshop participants. Held December 4-5, 2002, the Hydrogen Technology Education Workshop kicked off a new educat

  8. National Hydrogen Vision Meeting Proceedings

    Fuel Cell Technologies Publication and Product Library (EERE)

    This document provides presentations and summaries of the notes from the National Hydrogen Vision Meeting''s facilitated breakout sessions. The Vision Meeting, which took place November 15-16, 2001, k

  9. Production of hydrogen from alcohols

    DOE Patents [OSTI]

    Deluga, Gregg A. (St. Paul, MN); Schmidt, Lanny D. (Minneapolis, MN)

    2007-08-14

    A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

  10. Compressed/Liquid Hydrogen Tanks

    Broader source: Energy.gov [DOE]

    Currently, DOE's physical hydrogen storage R&D focuses on the development of high-pressure (10,000 psi) composite tanks, cryo-compressed tanks, conformable tanks, and other advanced concepts...

  11. Status of Hydrogen Storage Technologies

    Broader source: Energy.gov [DOE]

    The current status in terms of weight, volume, and cost of various hydrogen storage technologies is shown below. These values are estimates from storage system developers and the R&D community...

  12. Negative hydrogen ion production mechanisms

    SciTech Connect (OSTI)

    Bacal, M.; Wada, M.

    2015-06-15

    Negative hydrogen/deuterium ions can be formed by processes occurring in the plasma volume and on surfaces facing the plasma. The principal mechanisms leading to the formation of these negative ions are dissociative electron attachment to ro-vibrationally excited hydrogen/deuterium molecules when the reaction takes place in the plasma volume, and the direct electron transfer from the low work function metal surface to the hydrogen/deuterium atoms when formation occurs on the surface. The existing theoretical models and reported experimental results on these two mechanisms are summarized. Performance of the negative hydrogen/deuterium ion sources that emerged from studies of these mechanisms is reviewed. Contemporary negative ion sources do not have negative ion production electrodes of original surface type sources but are operated with caesium with their structures nearly identical to volume production type sources. Reasons for enhanced negative ion current due to caesium addition to these sources are discussed.

  13. DOE Hydrogen & Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    t t 1 | Fuel Cell Technologies Program eere.energy.gov Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U S D f E Overview U.S....

  14. Hydrogen Systems Analysis Workshop (SAW)

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy sponsored a Hydrogen Systems Analysis Workshop (SAW) in Washington, DC, July 28-29, 2004. Attendees included government officials, analysts, and managers from DOE, the...

  15. Hydrogen Production: Thermochemical Water Splitting

    Broader source: Energy.gov [DOE]

    Thermochemical water splitting uses high temperatures—from concentrated solar power or from the waste heat of nuclear power reactions—and chemical reactions to produce hydrogen and oxygen from water.

  16. 2002 Hydrogen Program Review Meeting

    Broader source: Energy.gov [DOE]

    The U.S. DOE Hydrogen Program, the Fuel Cells for Transportation Program, and the Fuels for Fuel Cells Program held their inaugural combined Annual Program/Lab R&D Review May 6–10, 2002, in...

  17. Wind Electrolysis: Hydrogen Cost Optimization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrolysis: Hydrogen Cost Optimization Genevieve Saur and Todd Ramsden Technical Report NREL/TP-5600-50408 May 2011 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 1617 Cole Boulevard Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Wind Electrolysis: Hydrogen Cost Optimization Genevieve Saur, Todd

  18. Hydrogen Storage Technical Team Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Storage Technologies Roadmap May Hydrogen Storage Technical Team Roadmap June 2013 This roadmap is a document of the U.S. DRIVE Partnership. U.S. DRIVE (Driving Research and Innovation for Vehicle efficiency and Energy sustainability) is a voluntary, non-binding, and nonlegal partnership among the U.S. Department of Energy; USCAR, representing Chrysler Group LLC, Ford Motor Company, and General Motors; Tesla Motors; five energy companies -BP America, Chevron Corporation, Phillips 66

  19. Electrolysis - Hydrogen - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Find More Like This Return to Search Electrolysis - Hydrogen Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL has invented a process that leverages nuclear technology in combination with various carbon sources to produce synthetic gases for refinement into synthetic transportation fuels/chemicals. Using solid-state electrolysis, water is decomposed to hydrogen and oxygen in one process, while carbon dioxide is

  20. Hydrogen Production Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    The Hydrogen Production Technical Team Roadmap identifies research pathways leading to hydrogen production technologies that produce near-zero net greenhouse gas (GHG) emissions from highly efficient and diverse renewable energy sources. This roadmap focuses on initial development of the technologies, identifies their gaps and barriers, and describes activities by various U.S. Department of Energy (DOE) offices to address the key issues and challenges.

  1. Supporting a Hawaii Hydrogen Economy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supporting a Hawaii Hydrogen Economy Pete Devlin U.S. Department of Energy Fuel Cell Technologies Office 2 Question and Answer * Please type your question into the question box hydrogenandfuelcells.energy.gov Supporting a Hawaii Hydrogen Economy Mitch Ewan Hawaii Natural Energy Institute University of Hawaii at Manoa 29 July 2014 CHALLENGES Hawaii is Most Petroleum-Dependent State in US Highest/Most Volatile Electricity Rates in US Import 90% of Energy $11Billion leaves Hawaii economy* * Based

  2. Hydrogen Technical Publications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Information Resources » Technical Publications » Hydrogen Technical Publications Hydrogen Technical Publications Technical information about hydrogen published in technical reports, conference proceedings, journal articles, and websites is provided here. General Production Delivery Storage General 2014 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office (Fuel Cell Technologies Office, February 2015) Hydrogen Fueling Station in Honolulu,

  3. Hydrogen Storage Technologies Roadmap, November 2005

    Fuel Cell Technologies Publication and Product Library (EERE)

    Document describing plan for research into and development of hydrogen storage technology for transportation applications.

  4. Hydrogen Delivery Technology Roadmap, November 2005

    Fuel Cell Technologies Publication and Product Library (EERE)

    Document describing plan for research into and development of hydrogen delivery technology for transportation applications.

  5. Hydrogen Safety Sensors | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sensors Hydrogen Safety Sensors 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon scs_02_burgess.pdf More Documents & Publications Hydrogen Codes and Standards and Permitting DOE Vehicle Technologies Program 2009 Merit Review Report - Safety Codes and Standards Hydrogen Education for Code Officials

  6. Composition for absorbing hydrogen from gas mixtures

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC); Wicks, George G. (Aiken, SC); Lee, Myung W. (Aiken, SC)

    1999-01-01

    A hydrogen storage composition is provided which defines a physical sol-gel matrix having an average pore size of less than 3.5 angstroms which effectively excludes gaseous metal hydride poisons while permitting hydrogen gas to enter. The composition is useful for separating hydrogen gas from diverse gas streams which may have contaminants that would otherwise render the hydrogen absorbing material inactive.

  7. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  8. International Partnership for a Hydrogen Economy

    Broader source: Energy.gov [DOE]

    "Presentation summarizing the vision, mission, goals and plans for DOE's International Partnership for a Hydrogen Economy "

  9. President's Hydrogen Fuel Initiative | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation prepared by JoAnn Milliken for the 2005 Manufacturing for the Hydrogen Economy workshop PDF icon mfg_wkshp_plenary.pdf More Documents & Publications DOE Hydrogen Program Overview U.S. Department of Energy Hydrogen Program A Brief Overview of Hydrogen Storage Issues and Needs

  10. Proceedings of the Hydrogen Vision Meeting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proceedings NATIONAL HYDROGEN VISION MEETING Washington, DC November 15-16, 2001 "The President's Plan directs us to explore the possibility of a hydrogen economy..." Spencer Abraham, Secretary of Energy Proceedings for National Hydrogen Vision Meeting Table of Contents Introduction 1.0 Notes: Hydrogen Industry Drivers ................................................................ 1 2.0 Notes: Breakout Group

  11. Hydrogen production: Overview of technology options

    SciTech Connect (OSTI)

    None, None

    2009-01-15

    Overview of technology options for hydrogen production, its challenges and research needs and next steps

  12. Selective purge for hydrogenation reactor recycle loop

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA)

    2001-01-01

    Processes and apparatus for providing improved contaminant removal and hydrogen recovery in hydrogenation reactors, particularly in refineries and petrochemical plants. The improved contaminant removal is achieved by selective purging, by passing gases in the hydrogenation reactor recycle loop or purge stream across membranes selective in favor of the contaminant over hydrogen.

  13. Electrolytic Hydrogen Production: Potential Impacts to Utilities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolytic Hydrogen Production Potential Impacts to Utilities Electrolytic Hydrogen Production Workshop February 28, 2014 Frank Novachek Director, Corporate Planning 2 Electrolytic Hydrogen Production Potential Impacts - Electric System * Reliability * Capacity * Regulation * Generation Resources * On/Off Peak * Dispatchability Renewables Integration System Operations Electric Load Hydrogen Production * Ramp Control * Reserves * Plant Cycling 3 Unique Opportunities - Electric  Increased

  14. Ligand iron catalysts for selective hydrogenation

    DOE Patents [OSTI]

    Casey, Charles P. (Madison, WI); Guan, Hairong (Cincinnati, OH)

    2010-11-16

    Disclosed are iron ligand catalysts for selective hydrogenation of aldehydes, ketones and imines. A catalyst such as dicarbonyl iron hydride hydroxycyclopentadiene) complex uses the OH on the five member ring and hydrogen linked to the iron to facilitate hydrogenation reactions, particularly in the presence of hydrogen gas.

  15. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Analysis of Photoelectrochemical (PEC) Hydrogen Production Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production This report documents the engineering and cost characteristics of four PEC hydrogen production systems selected by DOE to represent canonical embodiments of future systems. PDF icon Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production More Documents & Publications Technoeconomic Boundary Analysis of Biological

  16. Carbide Coatings for Nickel Alloys, Graphite and Carbon/Carbon Composites to be used in Fluoride Salt Valves

    SciTech Connect (OSTI)

    Nagle, Denis; Zhang, Dajie

    2015-10-22

    The focus of this research was concerned with developing materials technology that supports the evolution of Generation IV Advanced High Temperature Reactor (AHTR) concepts. Specifically, we investigate refractory carbide coatings for 1) nickel alloys, and 2) commercial carbon-carbon composites (CCCs). Numerous compelling reasons have driven us to focus on carbon and carbide materials. First, unlike metals, the strength and modulus of CCCs increase with rising temperature. Secondly, graphite and carbon composites have been proven effective for resisting highly corrosive fluoride melts such as molten cryolite [Na?AlF?] at ~1000C in aluminum reduction cells. Thirdly, graphite and carbide materials exhibit extraordinary radiation damage tolerance and stability up to 2000C. Finally, carbides are thermodynamically more stable in liquid fluoride salt than the corresponding metals (i.e. Cr and Zr) found in nickel based alloys.

  17. Autothermal hydrogen storage and delivery systems

    DOE Patents [OSTI]

    Pez, Guido Peter (Allentown, PA); Cooper, Alan Charles (Macungie, PA); Scott, Aaron Raymond (Allentown, PA)

    2011-08-23

    Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.

  18. Physical Hydrogen Storage | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Storage » Physical Hydrogen Storage Physical Hydrogen Storage Physical storage is the most mature hydrogen storage technology. The current near-term technology for onboard automotive physical hydrogen storage is 350 and 700 bar (5,000 and 10,000 psi) nominal working-pressure compressed gas vessels-that is, "tanks." While low-pressure liquid hydrogen, near the normal boiling point of 20 K, is routinely used for bulk hydrogen storage and transport, there is currently little

  19. Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani (Morgantown, WV)

    2010-08-03

    Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

  20. National Hydrogen Energy Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Energy Roadmap National Hydrogen Energy Roadmap This roadmap provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development. PDF icon national_h2_roadmap.pdf More Documents & Publications Hydrogen Posture Plan: An Integrated Research, Development and Demonstration Plan US DRIVE Fuel Pathway Integration Technical Team Roadmap Framework for the International Partnership for the Hydrogen Economy

  1. Autofermentative Biological Hydrogen Production by Cyanobacteria |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Autofermentative Biological Hydrogen Production by Cyanobacteria Autofermentative Biological Hydrogen Production by Cyanobacteria Presentation by Charles Dismukes, Rutgers University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_dismukes.pdf More Documents & Publications 2013 Biological Hydrogen Production Workshop Summary Report Renewable Hydrogen

  2. Fuel cell using a hydrogen generation system

    DOE Patents [OSTI]

    Dentinger, Paul M. (Sunol, CA); Crowell, Jeffrey A. W. (Castro Valley, CA)

    2010-10-19

    A system is described for storing and generating hydrogen and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  3. Nanolipoprotein Particles for Hydrogen Production - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Nanolipoprotein Particles for Hydrogen Production Lawrence Livermore National Laboratory Contact LLNL About This Technology Technology Marketing Summary Lawrence Livermore National Laboratory has developed a method using nanolipoprotein particles (NLP) to solubilize and isolate membrane bound hydrogenases for the biological production of hydrogen. Hydrogen is a renewable energy carrier that has the

  4. Combinatorial Approaches for Hydrogen Storage Materials (presentation) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Approaches for Hydrogen Storage Materials (presentation) Combinatorial Approaches for Hydrogen Storage Materials (presentation) Presentation on NIST Combinatorial Methods at the U.S. Department of Energy's Hydrogen Storage Meeting held June 26, 2007 in Bethesda, Maryland. PDF icon ht_nist_bendersky.pdf More Documents & Publications High Througput Combinatorial Techniques in Hydrogen Storage Materials R&D Workshop Hydrogen Storage Lab PI Workshop: HyMARC and

  5. Detroit Commuter Hydrogen Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detroit Commuter Hydrogen Project Detroit Commuter Hydrogen Project 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon tvp_01_egleton.pdf More Documents & Publications DOE Vehicle Technologies Program 2009 Merit Review Report - Technology Validation hd_hydrogen_2007.xls Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase

  6. Electrochemical Hydrogen Compression (EHC) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrochemical Hydrogen Compression (EHC) Electrochemical Hydrogen Compression (EHC) This presentation by Pinakin Patel and Ludwig Lipp of Fuel Cell Energy was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop on March 20, 2013. PDF icon csd_workshop_4_patel.pdf More Documents & Publications Small Business Innovation Research (SBIR) Award Success Story: FuelCell Energy Inc. 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report Hydrogen

  7. Bacterial Fermentative Hydrogen Production | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bacterial Fermentative Hydrogen Production Bacterial Fermentative Hydrogen Production Presentation by Melanie Mormile, Missouri University of Science and Technology, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_mormile.pdf More Documents & Publications 2013 Biological Hydrogen Production Workshop Summary Report Autofermentative Biological Hydrogen Production by

  8. The Hydrogen Tax Incentive Act of 2008

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    THE HYDROGEN TAX INCENTIVE ACT OF 2008 Establishing the Infrastructure Foundation for the Hydrogen Economy Background The proposed hydrogen tax credit supports the market introduction of hydrogen for use in fuel cells and internal combustion engines in nearer-term applications, including forklifts, stationary power generation, buses, and early automotive field trials. A key challenge for these early commercialization opportunities is the upfront cost of hydrogen fueling infrastructure and the

  9. Hydrogen Production Basics | Department of Energy

    Office of Environmental Management (EM)

    Education » Increase Your H2IQ » Hydrogen Production Basics Hydrogen Production Basics Hydrogen is an energy carrier, not an energy source-it stores and delivers energy in a usable form, but it must be produced from hydrogen containing compounds. Diverse and Domestic Supply Resources Hydrogen can be produced using diverse, domestic resources, including fossil fuels, such as coal (preferentially with carbon sequestration), and natural gas; nuclear energy; biomass and other renewable energy

  10. Hydrogen Storage Basics | Department of Energy

    Office of Environmental Management (EM)

    Storage Basics Hydrogen Storage Basics Developing safe, reliable, compact, and cost-effective hydrogen storage technologies is one of the most technically challenging barriers to the widespread use of hydrogen as a form of energy. To be competitive with conventional vehicles, hydrogen-powered cars must be able to travel more than 300 miles between fills. This is a challenging goal because hydrogen has physical characteristics that make it difficult to store in large quantities without taking up

  11. Hydrogen Production Processes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processes Hydrogen Production Processes Hydrogen can be produced using a number of different processes. Thermochemical processes use heat and chemical reactions to release hydrogen from organic materials such as fossil fuels and biomass. Water (H2O) can be split into hydrogen (H2) and oxygen (O2) using electrolysis or solar energy. Microorganisms such as bacteria and algae can produce hydrogen through biological processes. Thermochemical Processes Some thermal processes use the energy in various

  12. Hydrogen Production Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Related Links Hydrogen Production Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen production activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Production Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and

  13. Hydrogen Production: Electrolysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    » Processes » Hydrogen Production: Electrolysis Hydrogen Production: Electrolysis Electrolysis is a promising option for hydrogen production from renewable resources. Electrolysis is the process of using electricity to split water into hydrogen and oxygen. This reaction takes place in a unit called an electrolyzer. Electrolyzers can range in size from small, appliance-size equipment that is well-suited for small-scale distributed hydrogen production to large-scale, central production

  14. Hydrogen Storage Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Links Hydrogen Storage Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen storage activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Storage Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and presentations from the latest

  15. Hydrogen from Coal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids » Hydrogen from Coal Hydrogen from Coal Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL researchers in the Office of Research and Development are testing different types of materials that might be used to separate hydrogen from other gases. Photo courtesy of NETL. Technicians make adjustments to equipment in the hydrogen membrane testing unit at FE's National Energy Technology Laboratory. NETL

  16. Chemical Hydrogen Storage Materials | Department of Energy

    Office of Environmental Management (EM)

    Storage » Materials-Based Storage » Chemical Hydrogen Storage Materials Chemical Hydrogen Storage Materials The Fuel Cell Technologies Office's (FCTO's) chemical hydrogen storage materials research focuses on improving the volumetric and gravimetric capacity, transient performance, and efficient, cost-effective regeneration of the spent storage material. Technical Overview The category of chemical hydrogen storage materials generally refers to covalently bound hydrogen in either solid or

  17. Hydrogen & Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency » Vehicles » Hydrogen & Fuel Cells Hydrogen & Fuel Cells Watch this video to find out how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. Learn more about hydrogen and fuel cell technology basics. Fuel cells produce electricity from a number of domestic fuels, including hydrogen and renewables, and can provide power for virtually any application -- from cars and buses to commercial

  18. Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes

    SciTech Connect (OSTI)

    Wang, Feng; Robert, Rosa; Chernova, Natasha A.; Pereira, Nathalie; Omenya, Fredrick; Badway, Fadwa; Hua, Xiao; Ruotolo, Michael; Zhang, Ruigang; Wu, Lijun; Volkov, Vyacheslav; Su, Dong; Key, Baris; Whittingham, M. Stanley; Grey, Clare P.; Amatucci, Glenn G.; Zhu, Yimei; Graetz, Jason

    2015-10-15

    Materials that undergo a conversion reaction with lithium (e.g., metal fluorides MF{sub 2}: M = Fe, Cu, ...) often accommodate more than one Li atom per transition-metal cation, and are promising candidates for high-capacity cathodes for lithium ion batteries. However, little is known about the mechanisms involved in the conversion process, the origins of the large polarization during electrochemical cycling, and why some materials are reversible (e.g., FeF{sub 2}) while others are not (e.g., CuF{sub 2}). In this study, we investigated the conversion reaction of binary metal fluorides, FeF{sub 2} and CuF{sub 2}, using a series of local and bulk probes to better understand the mechanisms underlying their contrasting electrochemical behavior. X-ray pair-distribution-function and magnetization measurements were used to determine changes in short-range ordering, particle size and microstructure, while high-resolution transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS) were used to measure the atomic-level structure of individual particles and map the phase distribution in the initial and fully lithiated electrodes. Both FeF{sub 2} and CuF{sub 2} react with lithium via a direct conversion process with no intercalation step, but there are differences in the conversion process and final phase distribution. During the reaction of Li{sup +} with FeF{sub 2}, small metallic iron nanoparticles (<5 nm in diameter) nucleate in close proximity to the converted LiF phase, as a result of the low diffusivity of iron. The iron nanoparticles are interconnected and form a bicontinuous network, which provides a pathway for local electron transport through the insulating LiF phase. In addition, the massive interface formed between nanoscale solid phases provides a pathway for ionic transport during the conversion process. These results offer the first experimental evidence explaining the origins of the high lithium reversibility in FeF{sub 2}. In contrast to FeF{sub 2}, no continuous Cu network was observed in the lithiated CuF{sub 2}; rather, the converted Cu segregates to large particles (5-12 nm in diameter) during the first discharge, which may be partially responsible for the lack of reversibility in the CuF{sub 2} electrode.

  19. Photoelectrochemical Hydrogen Production

    SciTech Connect (OSTI)

    Hu, Jian

    2013-12-23

    The objectives of this project, covering two phases and an additional extension phase, were the development of thin film-based hybrid photovoltaic (PV)/photoelectrochemical (PEC) devices for solar-powered water splitting. The hybrid device, comprising a low-cost photoactive material integrated with amorphous silicon (a-Si:H or a-Si in short)-based solar cells as a driver, should be able to produce hydrogen with a 5% solar-to-hydrogen conversion efficiency (STH) and be durable for at least 500 hours. Three thin film material classes were studied and developed under this program: silicon-based compounds, copper chalcopyrite-based compounds, and metal oxides. With the silicon-based compounds, more specifically the amorphous silicon carbide (a-SiC), we achieved a STH efficiency of 3.7% when the photoelectrode was coupled to an a-Si tandem solar cell, and a STH efficiency of 6.1% when using a crystalline Si PV driver. The hybrid PV/a-SiC device tested under a current bias of -3~4 mA/cm{sup 2}, exhibited a durability of up to ~800 hours in 0.25 M H{sub 2}SO{sub 4} electrolyte. Other than the PV driver, the most critical element affecting the photocurrent (and hence the STH efficiency) of the hybrid PV/a-SiC device was the surface energetics at the a-SiC/electrolyte interface. Without surface modification, the photocurrent of the hybrid PEC device was ~1 mA/cm{sup 2} or lower due to a surface barrier that limits the extraction of photogenerated carriers. We conducted an extensive search for suitable surface modification techniques/materials, of which the deposition of low work function metal nanoparticles was the most successful. Metal nanoparticles of ruthenium (Ru), tungsten (W) or titanium (Ti) led to an anodic shift in the onset potential. We have also been able to develop hybrid devices of various configurations in a monolithic fashion and optimized the current matching via altering the energy bandgap and thickness of each constituent cell. As a result, the short-circuit photocurrent density of the hybrid device (measured in a 2-electrode configuration) increased significantly without assistance of any external bias, i.e. from ?1 mA/cm{sup 2} to ~5 mA/cm{sup 2}. With the copper chalcopyrite compounds, we have achieved a STH efficiency of 3.7% in a coplanar configuration with 3 a-Si solar cells and one CuGaSe{sub 2} photocathode. This material class exhibited good durability at a photocurrent density level of -4 mA/cm{sup 2} (5% STH equivalent) at a fixed potential (-0.45 VRHE). A poor band-edge alignment with the hydrogen evolution reaction (HER) potential was identified as the main limitation for high STH efficiency. Three new pathways have been identified to solve this issue. First, PV driver with bandgap lower than that of amorphous silicon were investigated. Crystalline silicon was identified as possible bottom cell. Mechanical stacks made with one Si solar cell and one CuGaSe{sub 2} photocathode were built. A 400 mV anodic shift was observed with the Si cell, leading to photocurrent density of -5 mA/cm{sup 2} at 0VRHE (compared to 0 mA/cm{sup 2} at the same potential without PV driver). We also investigated the use of p-n junctions to shift CuGaSe{sub 2} flatband potential anodically. Reactively sputtered zinc oxy-sulfide thin films was evaluated as n-type buffer and deposited on CuGaSe{sub 2}. Ruthenium nanoparticles were then added as HER catalyst. A 250 mV anodic shift was observed with the p-n junction, leading to photocurrent density at 0VRHE of -1.5 mA/cm{sup 2}. Combining this device with a Si solar cell in a mechanical stack configuration shifted the onset potential further (+400 mV anodically), leading to photocurrent density of -7 mA/cm{sup 2} at 0VRHE. Finally, we developed wide bandgap copper chalcopyrite thin film materials. We demonstrated that Se can be substituted with S using a simple annealing step. Photocurrent densities in the 5-6 mA/cm{sub 2} range were obtained with red 2.0eV CuInGaS{sub 2} photocathodes. With the metal oxide compounds, we have demonstrated that a WO{sub 3}-based hybrid photoelectrode was feasible. Specifically, we showed that WO{sub 3} paired with an a-Si tandem solar cell can generate short circuit photocurrent density of 2.5 mA/cm{sup 2}, equivalent to STH efficiency of 3.1%. Long-term durability tests demonstrated WO{sub 3} ability to split water over extended periods, for up to 600 hours at current density levels of 2.0-2.5 mA/cm{sup 2}. Efforts have been done to decrease WO{sub 3} bandgap using foreign elements incorporation. We did not manage to reduce the bandgap of WO{sub 3} with this method. However, more promising results have been achieved with bilayered systems, where only the top part of WO{sub 3} films was modified. Also, we have demonstrated that alloying WO{sub 3} with CuO can form 2.2eV bandgap CuWO{sub 4}. Incorporating conductive carbon nanotubes in CuWO{sub 4} reduced its intrinsic bulk resistance. Saturation photocurrent densities in the 0.4-0.5 mA/cm{sub 2} range were achieved. Recently, in collaboration with University of Texas at Arlington, we have identified new quaternary metal oxides with CuWO{sub 4} as primary material host. Our experimental work on ceramics confirmed the theoretical calculations that crowned bismuth as a possible candidate to improve CuWO{sub 4} water splitting efficiency.

  20. Energy-Efficient, High-Color-Rendering LED Lamps Using Oxyfluoride and Fluoride Phosphors

    SciTech Connect (OSTI)

    Setlur, A.; Radkov, E; Henderson, C; Her, J; Srivastava, A; Karkada, N; Kishore, M; Kumar, N; Aesram, D; et al.

    2010-01-01

    LED lamps using phosphor downconversion can be designed to replace incandescent or halogen sources with a 'warm-white' correlated color temperature (CCT) of 2700-3200 K and a color rendering index (CRI) greater than 90. However, these lamps have efficacies of {approx}70% of standard 'cool-white' LED packages (CCT = 4500-6000 K; CRI = 75-80). In this report, we describe structural and luminescence properties of fluoride and oxyfluoride phosphors, specifically a (Sr,Ca){sub 3}(Al,Si)O{sub 4}(F,O):Ce{sup 3+} yellow-green phosphor and a K{sub 2}TiF{sub 6}:Mn{sup 4+} red phosphor, that can reduce this gap and therefore meet the spectral and efficiency requirements for high-efficacy LED lighting. LED lamps with a warm-white color temperature (3088 K), high CRI (90), and an efficacy of {approx}82 lm/W are demonstrated using these phosphors. This efficacy is {approx}85% of comparable cool-white lamps using typical Y{sub 3}Al{sub 5}O{sub 12}:Ce{sup 3+}-based phosphors, significantly reducing the efficacy gap between warm-white and cool-white LED lamps that use phosphor downconversion.

  1. Preliminary Demonstration Reactor Point Design for the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Qualls, A. L.; Betzler, Benjamin R.; Brown, Nicholas R.; Carbajo, Juan; Greenwood, Michael Scott; Hale, Richard Edward; Harrison, Thomas J.; Powers, Jeffrey J.; Robb, Kevin R.; Terrell, Jerry W.

    2015-12-01

    Development of the Fluoride Salt-Cooled High-Temperature Reactor (FHR) Demonstration Reactor (DR) is a necessary intermediate step to enable commercial FHR deployment through disruptive and rapid technology development and demonstration. The FHR DR will utilize known, mature technology to close remaining gaps to commercial viability. Lower risk technologies are included in the initial FHR DR design to ensure that the reactor can be built, licensed, and operated within an acceptable budget and schedule. These technologies include tristructural-isotropic (TRISO) particle fuel, replaceable core structural material, the use of that same material for the primary and intermediate loops, and tube-and-shell heat exchangers. This report provides an update on the development of the FHR DR. At this writing, the core neutronics and thermal hydraulics have been developed and analyzed. The mechanical design details are still under development and are described to their current level of fidelity. It is anticipated that the FHR DR can be operational within 10 years because of the use of low-risk, near-term technology options.

  2. Understanding Polymorphism Formation in Electrospun Fibers of Immiscible Poly(vinylidene fluoride) Blends

    SciTech Connect (OSTI)

    G Zhong; L Zhang; R Su; K Wang; H Fong; L Zhu

    2011-12-31

    Effects of electric poling, mechanical stretching, and dipolar interaction on the formation of ferroelectric ({beta} and/or {gamma}) phases in poly(vinylidene fluoride) (PVDF) have been studied in electrospun fibers of PVDF/polyacrylonitrile (PAN) and PVDF/polysulfone (PSF) blends with PVDF as the minor component, using wide-angle X-ray diffraction and Fourier transform infrared techniques. Experimental results of as-electrospun neat PVDF fibers (beaded vs. bead-free) showed that mechanical stretching during electrospinning, rather than electric poling, was effective to induce ferroelectric phases. For as-electrospun PVDF blend fibers with the non-polar PSF matrix, mechanical stretching during electrospinning again was capable of inducing some ferroelectric phases in addition to the major paraelectric ({alpha}) phase. However, after removing the mechanical stretching in a confined melt-recrystallization process, only the paraelectric phase was obtained. For as-electrospun PVDF blend fibers with the polar (or ferroelectric) PAN matrix, strong intermolecular interactions between polar PAN and PVDF played an important role in the ferroelectric phase formation in addition to the mechanical stretching effect during electrospinning. Even after the removal of mechanical stretching through the confined melt-recrystallization process, a significant amount of ferroelectric phases persisted. Comparing the ferroelectric phase formation between PVDF/PSF and PVDF/PAN blend fibers, we concluded that the local electric field-dipole interactions were the determining factor for the nucleation and growth of polar PVDF phases.

  3. Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Technical Targets | Department of Energy Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets Download presentation slides from the "Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets" webinar presented by the U.S. Department of Energy Fuel Cell Technologies Office on June 25, 2013. PDF icon Hydrogen

  4. 2014 Hydrogen Student Design Contest to Design Drop-In Hydrogen Fueling

    Energy Savers [EERE]

    Station | Department of Energy 4 Hydrogen Student Design Contest to Design Drop-In Hydrogen Fueling Station 2014 Hydrogen Student Design Contest to Design Drop-In Hydrogen Fueling Station December 16, 2013 - 12:00am Addthis The 10th annual Hydrogen Student Design Contest will challenge student teams to design a transportable, containerized hydrogen fueling station solution. Registration for the contest, supported by the U.S. Department of Energy's Office of Energy Efficiency and Renewable

  5. Overview of Indian Hydrogen Program and Key Safety Issues of Hydrogen Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Indian Hydrogen Program and Key Safety Issues of Hydrogen Fuel Overview of Indian Hydrogen Program and Key Safety Issues of Hydrogen Fuel Presentation given by Dilip Chenoy of the Society of Indian Automobile Manufacturers at the CNG and Hydrogen Lessons Learned Workshop on December 10, 2009 PDF icon cng_h2_workshop_9_chenoy.pdf More Documents & Publications Successful Adoption of CNG and Energing CNG-Hydrogen Program in India Workshop Notes from

  6. Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review | Department of Energy Bus Evaluation: Report for the 2001 Hydrogen Program Review Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen Program Review This paper, presented at the 2001 DOE Hydrogen Program Review, describes the prototype fuel cell bus, fueling infrastructure, and maintenance facility for an early technology adopter. PDF icon Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen Program Review More Documents & Publications Fuel Cell Transit

  7. Overview of Hydrogen and Fuel Cell Activities: February 2011 Hydrogen and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Technical Advisory Committee Meeting | Department of Energy February 2011 Hydrogen and Fuel Cell Technical Advisory Committee Meeting Overview of Hydrogen and Fuel Cell Activities: February 2011 Hydrogen and Fuel Cell Technical Advisory Committee Meeting Presentation by Sunita Satyapal at the Hydrogen and Fuel Cell Technical Advisory Committee meeting on February 17, 2011. PDF icon Overview of Hydrogen and Fuel Cell Activities More Documents & Publications Overview of Hydrogen

  8. DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold Cost

    Office of Environmental Management (EM)

    Calculation | Department of Energy 1007: Hydrogen Threshold Cost Calculation DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold Cost Calculation The hydrogen threshold cost is defined as the hydrogen cost in the range of $2.00-$4.00/gge (2007$), which represents the cost at which hydrogen fuel cell electric vehicles are projected to become competitive on a cost per mile basis with the competing vehicles (gasoline in hybrid-electric vehicles) in 2020. This record from the

  9. Method and System for Hydrogen Evolution and Storage

    DOE Patents [OSTI]

    Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

    2008-10-21

    A method and system for storing and evolving hydrogen employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

  10. Method and system for hydrogen evolution and storage

    DOE Patents [OSTI]

    Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

    2012-12-11

    A method and system for storing and evolving hydrogen (H.sub.2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

  11. Hydrogen-Powered Buses Brochure - 2010 | Department of Energy

    Energy Savers [EERE]

    Hydrogen-Powered Buses Brochure - 2010 Hydrogen-Powered Buses Brochure - 2010 This brochure outlines how the latest advances in hydrogen vehicles are expressed in these hydrogen-powered buses. PDF icon Hydrogen-Powered Buses More Documents & Publications Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fuel Cells Fact Sheet FutureGen -- A Sequestration and Hydrogen Research Initiative

  12. Polymer formulations for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy J. (330 Thrasher Ave., Livermore, CA 94550); Even, Jr., William R. (4254 Drake Way, Livermore, CA 94550)

    2000-01-01

    A novel method for preparing a hydrogenation composition comprising organic polymer molecules having carbon--carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces and particularly from atmospheres within enclosed spaces that contain air, water vapor, oxygen, carbon dioxide or ammonia. The organic polymers molecules containing carbon--carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble noble metal catalyst composition. High molecular weight polymers may be added to the organic polymer/catalyst mixture in order to improve their high temperature performance. The hydrogenation composition is prepared by dispersing the polymers in a suitable solvent, forming thereby a solution suspension, flash-freezing droplets of the solution in a liquid cryogen, freeze-drying the frozen droplets to remove frozen solvent incorporated in the droplets, and recovering the dried powder thus formed.

  13. Hydrogen Storage and Production Project

    SciTech Connect (OSTI)

    Bhattacharyya, Abhijit; Biris, A. S.; Mazumder, M. K.; Karabacak, T.; Kannarpady, Ganesh; Sharma, R.

    2011-07-31

    This is the final technical report. This report is a summary of the project. The goal of our project is to improve solar-to-hydrogen generation efficiency of the PhotoElectroChemical (PEC) conversion process by developing photoanodes with high absorption efficiency in the visible region of the solar radiation spectrum and to increase photo-corrosion resistance of the electrode for generating hydrogen from water. To meet this goal, we synthesized nanostructured heterogeneous semiconducting photoanodes with a higher light absorption efficiency compared to that of TiO2 and used a corrosion protective layer of TiO2. While the advantages of photoelectrochemical (PEC) production of hydrogen have not yet been realized, the recent developments show emergence of new nanostructural designs of photoanodes and choices of materials with significant gains in photoconversion efficiency.

  14. DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials- 2004 vs. 2006

    Broader source: Energy.gov [DOE]

    This program record from the Department of Energy's Hydrogen and Fuel Cells Program provides information about hydrogen storage materials (2004 vs. 2006).

  15. NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)

    SciTech Connect (OSTI)

    Ramsden, T.; Harrison, K.; Steward, D.

    2009-11-16

    Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

  16. Liquid-hydrogen-fueled passenger aircraft

    SciTech Connect (OSTI)

    Not Available

    1986-03-11

    This Chinese translation discusses the idea that passenger aircraft will eventually use liquid-hydrogen fuel. There is a large reserve of hydrogen and hydrogen poses no danger to the environment. Hydrogen has high calorific value, high specific heat, low density, and low temperature. Aircraft will have to have liquid fuel tanks to carry the hydrogen and will have to be partially redesigned. Lockheed and NASA have considered such designs. A problem remains in the planning--the high cost of large extraction of liquid hydrogen.

  17. Hydrogen Isotope Exchange Properties of Porous Solids Containing Hydrogen

    SciTech Connect (OSTI)

    HEUNG, LEUNGK.

    2004-08-18

    Porous solids such as activated alumina, silica and molecular sieves generally contain significant amounts of hydrogen atoms in the form of H2O or OH even at high temperature and low humidity environment. A significant amount of this hydrogen is available for reversible isotopic exchange. This exchange reaction is slow under normal conditions and does not render itself to practical applications. But if the exchange kinetics is improved this reaction has the potential to be used for tritium removal from gas streams or for hydrogen isotopic separation.The use of catalysts to improve the exchange kinetics between hydrogen isotope in the gas phase and that in the solid phase was investigated. Granules of alumina, silica and molecular sieve were coated with platinum or palladium as the catalyst. The granules were packed in a 2-cm diameter column for isotope exchange tests. Gas streams containing different concentrations of deuterium in nitrogen or argon were fed through the protium saturated column. Isotope concentration in column effluent was monitored to generate isotope break-through curves. The curves were analyzed to produce information on the kinetics and capacity of the material. The results showed that all materials tested provided some extent of isotope exchange but some were superior both in kinetics and capacity. This paper will present the test results.

  18. Joint Meeting on Hydrogen Delivery Modeling and Analysis Meeting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Documents & Publications Hydrogen Delivery Analysis Models Hydrogen Delivery Analysis Plus Meeting: DTT, STT, HPTT, Other Analysts, Invited Guests Joint Meeting on Hydrogen...

  19. 'Grand Challenge' for Basic and Applied Research in Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the following areas: New materials or technologies for hydrogen storage; Compressed and liquid hydrogen tank technologies; and Off-board hydrogen storage systems. Category 2 is...

  20. State and Regional Hydrogen Initiatives Meeting, Challenges for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Regional Hydrogen Initiatives Meeting, Challenges for State and Regional Hydrogen Initiatives State and Regional Hydrogen Initiatives Meeting, Challenges for State and Regional...

  1. The U.S. National Hydrogen Storage Project Overview (presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The U.S. National Hydrogen Storage Project Overview (presentation) The U.S. National Hydrogen Storage Project Overview (presentation) Status of Hydrogen Storage Materials R&D...

  2. High-Pressure Multi-Mbar Conductivity Experiments on Hydrogen...

    Office of Scientific and Technical Information (OSTI)

    on Hydrogen: The Quest for Solid Metallic Hydrogen ... due to the fascinating physics which arises from this ... hydrogen to the metallic state have stimulated the ...

  3. US DRIVE Hydrogen Codes and Standards Technical Team Roadmap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Codes and Standards Technical Team Roadmap US DRIVE Hydrogen Codes and Standards Technical Team Roadmap The Hydrogen Codes and Standards Tech Team (CSTT) mission is to ...

  4. Developing SAE Safety Standards for Hydrogen and Fuel Cell Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...pmaterialsveenstra.pdf More Documents & Publications Introduction to SAE Hydrogen Fueling Standardization CNG and Hydrogen Tank Safety, R&D, and Testing Hydrogen Tank Testing R&D

  5. Agenda for the Hydrogen Delivery and Onboard Storage Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage...

  6. Clean Hydrogen Producers Ltd CHP | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Producers Ltd CHP Jump to: navigation, search Name: Clean Hydrogen Producers Ltd (CHP) Place: Geneva, Switzerland Zip: 1209 Sector: Hydro, Hydrogen, Solar Product: Swiss...

  7. Hydrogen Storage Materials Requirements to Meet the 2017 On Board...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets...

  8. India National Hydrogen Energy Board NHEB | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Energy Board NHEB Jump to: navigation, search Name: India National Hydrogen Energy Board (NHEB) Place: New Delhi, India Zip: 110 003 Sector: Hydro, Hydrogen Product: Set...

  9. Spanish Hydrogen Association AeH | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Association AeH Jump to: navigation, search Name: Spanish Hydrogen Association (AeH) Place: Madrid, Spain Zip: 28760 Sector: Hydro, Hydrogen Product: Spanish conference...

  10. South Carolina Hydrogen and Fuel Cell Alliance | Open Energy...

    Open Energy Info (EERE)

    Hydrogen and Fuel Cell Alliance Jump to: navigation, search Name: South Carolina Hydrogen and Fuel Cell Alliance Place: Columbia, South Carolina Zip: 29201 Sector: Hydro, Hydrogen...

  11. Aiken County Center for Hydrogen Research | Open Energy Information

    Open Energy Info (EERE)

    Aiken County Center for Hydrogen Research Jump to: navigation, search Name: Aiken County Center for Hydrogen Research Place: South Carolina Zip: 29803 Sector: Hydro, Hydrogen...

  12. Evaluation of Natural Gas Pipeline Materials for Hydrogen Science...

    Office of Environmental Management (EM)

    Evaluation of Natural Gas Pipeline Materials for Hydrogen Science Evaluation of Natural Gas Pipeline Materials for Hydrogen Science Presentation by 04-Adams to DOE Hydrogen...

  13. List of Companies in Hydrogen Sector | Open Energy Information

    Open Energy Info (EERE)

    Companies in Hydrogen Sector Jump to: navigation, search Companies in the Hydrogen sector: Add a Company Download CSV (rows 1-196) Map of Hydrogen companies Loading map......

  14. International Partnership for Hydrogen Energy IPHE | Open Energy...

    Open Energy Info (EERE)

    for Hydrogen Energy IPHE Jump to: navigation, search Name: International Partnership for Hydrogen Energy (IPHE) Place: Washington, Washington, DC Zip: 20004 Sector: Hydro, Hydrogen...

  15. Workshop Notes from ""Compressed Natural Gas and Hydrogen Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overview of DOE - DOT December 2009 CNG and Hydrogen Fuels Workshop Safety and Regulatory Structure for CNG, CNG-Hydrogen Vehicles and Fuels in India International Hydrogen Fuel ...

  16. Hydrogen storage compositions (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Hydrogen storage compositions Citation Details In-Document Search Title: Hydrogen storage compositions Compositions for hydrogen storage and methods of making such...

  17. Solid-State Sensors for Monitoring Hydrogen | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solid-State Sensors for Monitoring Hydrogen Solid-State Sensors for Monitoring Hydrogen New Sensors Rapidly and Accurately Detect Hydrogen, Improving Industrial Safety and ...

  18. Overview of Hydrogen and Fuel Cell Activities: 6th International...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6th International Hydrogen and Fuel Cell Expo Overview of Hydrogen and Fuel Cell Activities: 6th International Hydrogen and Fuel Cell Expo This presentation by DOE's Sunita...

  19. Overview of Hydrogen and Fuel Cell Activities: February 2011...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    February 2011 Hydrogen and Fuel Cell Technical Advisory Committee Meeting Overview of Hydrogen and Fuel Cell Activities: February 2011 Hydrogen and Fuel Cell Technical Advisory...

  20. Hydrogen Fuel for Material Handling | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel for Material Handling Hydrogen Fuel for Material Handling Presented by Tom Joseph at the National Hydrogen Assocation Conference and Hydrogen Expo PDF icon...